AIR POLLUTANT EMISSION INVENTORY OF NORTHWEST INDIANA A PRELIMINARY SURVEY 1966 U.S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE PUBLIC HEALTH SERVICE ------- AIR POLLUTANT EMISSION INVENTORY OF NORTHWEST INDIANA A PRELIMINARY SURVEY 1966 by G. Ozolins C. Rehmann CONDUCTED FOR NORTHWEST INDIANA AIR RESOURCE MANAGEMENT PROGRAM U. S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE Public Health Service Bureau of Disease Prevention and Environmental Control Durham, North Carolina April 1968 ------- National Center for Air Pollution Control Publication APTD-68-4 ------- FOREWORD The Northwest Indiana Air Resource Management Program is a. cooperative effort initiated in March, 1965, by the cities of Gary and East Chicago, the State of Indiana, and the U. S. Public Health Service. The primary purpose of this program is to assist and strengthen local agencies in developing and implementing an area-wide air resource management plan. This study was prepared at the request of the Program Executive Committee. Its purpose is threefold: (1) to provide a preliminary but comprehensive inventory of the air pollutant emissions from the entire area; (2) to help initiate the air resource management programs in Hammond and Whiting, Indiana; and (3) to provide guidelines for future, more detailed surveys, similar to those presently conducted by the cities of Gary and East Chicago. This report is the result of a joint effort by the air pollution control agencies and health departments of East Chicago, Gary, Hammond, Whiting, and the National Center for Air Pollution Control. As in all emission surveys, the data presented here are estimates and should not be interpreted as actual values. They are, however, of sufficient accuracy and validity to allow their use in developing and improving an air resource management program. 111 ------- ABSTRACT Sources of air pollutant emissions were surveyed to quantify the total pollution load emitted to the air over the Northwest Indiana communities of East Chicago, Gary, Hammond, and Whiting. The emissions are reported on an annual basis and subdivided into the five major pollutants: particulates, sulfur oxides, nitro- gen oxides, hydrocarbons, and carbon monoxide. The four major source cate- gories that were utilized in reporting emissions from area and point sources are: fuel combustion in stationary sources, fuel combustion in mobile sources, com- bustion of refuse, and industrial process losses. The results of this survey are reported by city and illustrated on the grid system established by the Northwest Indiana Air Resource Management Program. ------- CONTENTS INTRODUCTION 1 STUDY AREA 2 SUMMARY OF RESULTS 6 Emissions by Category 3 Fuel Combustion in Stationary Sources 8 Industry 13 Steam-Electric Utilities 13 Residential 14 Other 15 Fuel Combustion in Transportation Vehicles 15 Combustion of Refuse Material 15 Industrial Process Emissions 18 Steel Manufacturing 21 Oil Refineries 21 Chemical Industry 21 Cement Manufacturing 21 Foundries 21 Emissions by Geographical Area 22 SUMMARY 34 ------- AIR POLLUTANT EMISSION INVENTORY OF NORTHWEST INDIANA A PRELIMINARY SURVEY 1966 INTRODUCTION This report presents the results of a rapid emissions inventory of air pollu- tant sources in Northwest Indiana. The objectives of this study are to determine the total quantities of the various air pollutants emitted and to estimate, as accurately as possible, the geographical variation in air pollutant emissions. To accomplish this, the study area was divided into a grid system and the emission quantities are reported in terms of tons of pollutant per grid on an annual basis. The pollutants considered in this survey carbon monoxide, hydrocarbons, nitrogen oxides, sulfur oxides and particulates - are those emitted in large quantities from the variety and multitude of sources dispersed throughout the area. The emissions of pollutants not considered herein are generally associated with a specific process or operation and, in general, are not distributed through- out the community. The sources of air pollution, as used in this report, are subdivided into the following four categories: 1. Fuel combustion in stationary sources. 2. Fuel combustion m transportation vehicles. 3, Combustion of refuse material. 4.- Industrial process emissions. ------- STUDY AREA The study area, shown on Figure 1, includes the Northwest Indiana com- munities of East Chicago, Gary, Hammond, and Whiting. The total land area involved in the study is approximately 85 square miles. The 1960 population was 355, 824. According to census figures the population in the study area has increased by 24. 6 percent from 1950 to I960, and in the Gary-Hammond-East Chicago Standard Metropolitan Statistical Area, which includes Lake and Porter Counties, the population has increased by 40. 5 percent. The population of the area outside the central cities has increased by 70. 5 percent. Of the four cities, Gary has had the largest increase in population, 33 percent, and Whiting has the only decrease in population, 15. 8 percent. Figure 2 shows the distribution of the population of the study area by grids. The area included in this study has a variety of industries, but three large steel mills and four large petroleum refineries located near or on the shores of Lake Michigan dominate the industrial complex. Other industries in the area tend to be support activities for the steel and petroleum industries. Foundries, steel fabricators, and chemical plants are the largest group of support industries while two large power utilities and a large cement manufacturing plant make up the large single industries not directly supported by these two major industries. The study area also includes some industry that is divorced from the petroleum and steel industries. The printing and publishing, grain, soap, textile, and building material industries are well represented. Various types of small manufacturing plants are also located in the four communities. Almost 200 of the 400 industrial plants-in-_the area .employ more than 20 employees. The total number of employees in the study area is approximately 100, 000; approximately 60 percent of them are in the primary metals industry, and 9 percent are employed in both the petroleum and metal fabrication industries. The automobile traffic in the study area is handled by a number of major arteries. The Indiana toll road and the Tri-State Highway, which bound the study area on the north and south, handle most of the east-west traffic, Indianapolis Boulevard, Calumet Avenue, Kennedy Avenue, Grant, and Broadway handle a large portion of the north-south traffic. 2 ------- 380 385 390 395 LAKC CJ>LUHir 1530 1525 1515 CAIUMET CITY 1505 1500 1495 1490 1485 1480 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 1505 380 385 390 395 400 405 410 415 420 1470 1465 425 430 435 440 445 MILES Figure 1. Location map of study area. ------- 380 385 390 395 1 Ltff C4iUMfT CALUMET CITY 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 POPULATION DENSITY, persons/mi^ [ ;[ 1,000 -" 5,000 5,000 - 10,000 10,000 - 15,000 385 390 395 400 405 410 415 420 1470 1465 450 455 460 465 1475 HOBART 1470 1465 I N 425 430 435 440 445 MILES Figure 2. Population densities in Northwestern Indiana communities. ------- In the development of the Northwest Indiana Air Resource Management Program, the Executive Committee adopted a grid system encompassing the entire study area covered in this report. The grid system consists of 10, 000- foot squares designated on the United States Coast and Geodetic Survey maps of the Northwest Indiana Area. The grid system used throughout this report is the same grid system as that adopted by the Northwest Indiana Air Resource Management Program except that this grid system is subdivided into 5, 000- foot squares. ------- SUMMARY OF RESULTS The following is a brief summary of pollutant emissions and sources in the study area: 1. Particulate matter is emitted primarily from industrial processes, coal combustion, and refuse disposal. Particulate emissions from industrial processes contribute 76 percent, from coal combustion contributes 20 percent, and from refuse disposal contributes 1 percent of the total emissions. 2. The burning of fossil fuels contributes approximately 86 percent of the total amount of sulfur oxides emitted in the study area. The combustion of coal accounts for 66 percent, and the combustion of fuel oils contributes 19 percent to the total amount of sulfur oxides emitted. Industrial process emissions account for 14 percent of the total amount of sulfur oxide emissions, but lack of data on certain industrial processes does not give a complete picture of this source. 3. Oxides of nitrogen are emitted primarily from two sources, combustion of fuels and transportation. The combustion of coal accounts for 38 percent of the total emissions and the combustion of fuel oils accounts for 40 percent of the total. The combustion of natural gas accounts for 13 percent, and the combustion of gasoline in automobiles accounts for 8 percent of the total amount of nitrogen oxides emitted. 4. The emission of hydrocarbons is accounted for in three major sources industrial processes, transportation, and refuse disposal. Industrial processes account for 58 percent of the total emissions, the motor vehicle accounts for 24 percent, and the disposal of refuse contributes 15 percent to the total emission of hydrocarbons. 5. Industrial process emissions account for 24 percent of the total amount of carbon monoxide emitted, and motor vehicles account for 72 percent of the total. The emissions of pollutants discharged in the study area are listed in Table 1. The accuracy of the results depends on the accuracy and applicability of the ( available emission factors and the information available concerning the specific processes in which large quantities of pollutants are emitted. The emission factors, for the most part, represent the average emission rates for a particular 6 ------- Table 1. SUMMARY OF AIR POLLUTANT EMISSIONS IN NORTHWEST INDIANA (tons/year) Partic- Source category ulates Transportation Combustion of fuels Stationary sources Industry Steam-electric utilities Residential Other Subtotal Refuse disposal City dumps On-site burning Subtotal Industrial process emissions Totals 780 39,260 13,390 1, 520 1,170 60,340 280 2,680 2,960 208,800 272,880 Sulfur oxides 630 138,960 149,500 10,180 2,320 300,960 10 50 60 49,000a 350,650a Nitrogen oxides 7,910 58,930 25,330 2,920 430 87,610 -- 30 30 840 96,390 Hydro- carbons 27,700 1,080 230 610 230 2, 150 1,680 15,960 17 , 640 66,800 114,290 Carbon monoxide 204,000 2,000 570 2,840 1, 120 6,530 500 4,785 5,285 66,800 282,615 Does not include sulfur oxide emissions from 3 refineries. industry or fuel group. Because of the differences in emissions rates among the plants or fuel users within a given category, the application of the emission \ factors, as applied to an individual plant, could result in a considerable dis- crepancy between the actual and calculated emissions. The incompleteness of data relating to pollutant emissions from some processes and fuel uses has resulted in the omission of some air pollutants and air pollution sources in the area. These omissions have primarily been confined to area sources or to sources contributing a relatively small amount of pollu- tants. The emissions inventory should therefore be fairly representative of total area emissions of the principal pollutants. ------- EMISSIONS BY CATEGORY For purposes of compiling basic data and calculating emission quantities, the air pollution sources are grouped into four categories: 1. Fuel combustion in stationary sources. 2. Fuel combustion in transportation vehicles. 3. Combustion of refuse material. 4. Industrial process emissions. Each of these categories is, in turn, subdivided in a number of subgroups some according to type or size to allow estimates of the geographical variation in pollutant emissions. In the following discussion the various information sources are documented, assumptions made are cited, and the resulting emission quantities are summarized. Fuel Combustion in Stationary Sources The combustion of fuels is one of the principal sources of air pollutant emissions in urban areas. The combustion of fuels releases various products that deteriorate the quality of the urban air. The major fuels used in the study area are coal, fuel oil, natural gas, and process gas. The primary consumers of the three major fuels are: industry, steam-electric utilities, and residential dwellings.* Table 2 summarizes the annual fuel consumption for the study area, and Table 3 subdivides the annual fuel consumption into use category and political subdivisions. The fuel consumption data for the study area were obtained through the use of a variety of techniques and from numerous information sources. Where possible, data have been cross-checked by using different techniques and other sources of information. The annual consumption of natural gas was furnished by the local utility, and Bureau of Census data for 1962 were used for annual consumption of coal and fuel oil. *To more accurately define the sources of pollution and provide better estimates of emissions, a fourth category, Other Consumers, was used. Included in this category are commercial sources that primarily use fuel for space heating. ------- Table 2. ANNUAL FUEL CONSUMPTION IN NORTHWEST INDIANA Fuel Coal, tons /yr Fuel oil, gal/yr Gas, million ft /yr Consumer category a Industry Steam-electric utilities Residential Other Total Industry Steam-electric utilities Residential Other Total Industry Steam -electric utilities Residential Other Total Annual consumption 1,306, 000 2,290,000 111,000 45,000 3,752,000 271,656,000 54,600,000 b na 326,256, 000 79,445 12,461 9,534 4,487 105, 927 Percent of total 34.8 61.0 3.0 1.2 100.0 83.3 -- 16.7 b na 100.0 75.0 11.8 9.0 4.2 100.0 aAn additional 12, 488, 000 tons is used in the production of coke. na - Information not available or not reported. Table 4 specifically locates the major fuel consumer categories in the study area and gives total consumption of each of the specific fuels used in both process | heating and area or space heating. The steam - electric utilities, the major users of coal, consume 61 percent of the area total annually. Industry consumes 83 percent of the fuel oil and 75 percent of the natural gas. Industry, consuming 35 percent annually, is also the second largest user of coal. The Mid-West Coal Producers Institute provided the quantities of coal of Midwestern origin that was shipped into this area. Table 5 shows the distribu- tion , usage, and chemical composition of this coal. This information was not made available until after the calculations were completed. The sulfur and ash ------- Table 3. ANNUAL FUEL CONSUMPTION BY POLITICAL SUBDIVISIONS OF NORTHWEST INDIANA, 1966 Fuel Coal, tons/yr Fuel oil, gal/yr Gas, million ft3/yr Jurisdiction Hammond East Chicago Gary Whiting Totals Hammond East Chicago Gary Whiting Totals Hammond East Chicago Gary Whiting Totals User category Industry 115,870 726,060 308,850 125,000 1,275,780 3,798,700 308,247,400 96, 886,300 9,430,000 418,862,400 4,334 48, 178 22,407 4,526 79,445 Steam -electric plants 1,161,000 1, 129,000 2,290,000 -- -- 11,561 900 12,461 Residential 33,520 25, 900 47,630 3,950 111,000 15,558,000 8, 030,000 30,070,000 942,000 54,600,000 3,273 1, 103 4,963 195 9,534 Other 15,000 7,000 22,000 1,000 45,000 na 1,311 775 2,288 113 4,487 Totals 3,752, 000 326,256,000 105,929 na - Information not available or not reported. ------- Table 4. MAJOR FUEL CONSUMERS IN STUDY AREA BY INDUSTRIAL CATEGORY City East Chicago Gary Hammond Whiting Category Chemical and allied products Stone, clay, glass products Primar y_metals industries Petroleum and coal products Totals Chemical and allied products Stone, clay, glass products Primary metals industries Transportation equipment Power utilities Totals Chemical and allied products Stone, clay, glass products Primary metals industries Power utilities Food and kindred products Printing and publishing Paper and allied products Totals Petroleum and coal products Chemical and allied products Totals Area totals Annual fuel consumption Coal, tons 92, 500 5, 561 628,000 726, 061 280,000 34,856 1, 129,000 1,443,856 5,876 1, 161,000 110,000 1,276,876 125, 000 125, 000 3,571,793 Fuel oil, gallons Residual 211,800 63, 900 242,270, 000 64, 364, 000 306, 909, 700 520, 000 2, 000, 000 91,389,700 392, 000 94,301, 700 389, 200 1, 725, 000 854, 000 400, 000 3, 368,200 9,500, 000 430, 000 9, 930, 000 414, 509, 600 Distillate 31,700 1, 306,000 1,337,700 4, 585, 000 4,585,000 388,000 42, 500 430, 500 — — -- 6, 353,200 Gas, 106ft3 Natural 1, 307 412 36,617 38,336 3 921 22,557 900 24, 381 1, 585 264 912 11, 561 170 310 14,802 4 2, 500 2, 504 80, 023 Process 43, 000 26,460 69,460 382,931 382,931 -- 16, 000 2, 000 18, 000 470, 391 ------- Table 5. MIDWEST COAL ASSOCIATION SUMMARY OF MIDWESTERN COAL SHIPPED TO NORTHWEST INDIANA AREA To Whiting from: Western Kentucky Southern Illinois Western Kentucky Total and Averages To Hammond from: Southern Illinois Indiana Fulton County DuQuoin Indiana Western Kentucky Belleville and South Illinois Total and Averages To Gary from: Central Illinois Southern Illinois Indiana Western Kentucky Danville Belleville Southern Illinois Indiana Western Kentucky Belleville DuQuoin Total and Averages To East Chicago from: Fulton County Central Illinois Belleville Southern Illinois Indiana Western Kentucky Southern Illinois Total and Averages a Use RT IN IN RT RT IN IN IN IN UT RT RT RT RT IN IN IN IN IN UT UT IN IN IN IN IN IN MT Coal shipped, tons 101 36, 900 165,814 252,815 108 1,453 6,234 371 2, 098 1,469 1, 673, 944 . 1,685,677 54 306 576 584 13,619 52,864 32, 117 79,236 121,821 996,987 249,424 1,547, 588 101,570 6, 146 633 44, 175 5,834 18, 078 351, 632 528, 068 Moisture, % 10. 10 7.90 8.34 8. 19 7.22 13.00 14.78 10.00 13.77 8.34 13.66 13.66 12.00 7.22 13.00 10. 10 13.35 10.68 7.90 13.77 8.34 10.60 9.80 10.43 14.74 13.40 10.68 7.90 13.77 8.34 9.20 10.23 Ash, % 6.00 7.84 6.36 6.87 7. 90 7.50 7.03 8.60 6.47 6.36 10.26 10.24 8. 10 7. 90 7. 50 6. 00 7. 51 9.71 7.84 6.47 6.36 9.93 15. 10 10.23 7. 18 8. 60 9.71 7.84 6.47 6. 36 5. 90 6.37 Sulfur, % 2.95 1.88 2.91 2.56 1.86 2.72 2.77 2. 72 2.29 2.91 3.38 3.38 3.44 1.86 2.72 2.95 2.67 3.27 1.88 2.29 2.91 2. 87 2. 60 2.79 2.52 3.40 3.27 1.88 2.29 2.91 1.03 1.50 aRT coal used for retail purposes; IN - coal used for industrial purposes; UT - coal used for electric utility purposes; MT coal used for metallurgical purposes. 12 ------- contents of the coal were assumed when they were not made available by the parti- cular consumers of coal, and the sulfur contents of the residual and distillate fuel oil were also assumed and used under the same circumstances. A sulfur content of 2. 7 percent and an ash content of 10 percent for coal, and a sulfur content of 0. 4 percent for distillate (number 1 and 2 oil) and a sulfur content of 1. 5 percent for residual (numbers 4 and 5 oil) fuel oil were assumed for the fuels that did not have their composition reported. A weighted average of all the re- ported fuels with their respective compositions was calculated to estimate the assumed composition of the other fuels. Pollutants should be recalculated to be comparable with the analysis as stated in Table 5. Air pollutant emissions from fuel combustion in stationary sources are summarized in Table 6 by user category. The combustion of coal accounts for over 70 percent by weight of all the pollutants emitted from this source category. Coal combustion accounts for 99 percent of the carbon monoxide, 93 percent of the particulates, 77 percent of the sulfur oxides, 42 percent of the nitrogen oxides, and 77 percent of the hydrocarbons emitted from fuel combustion. Fuel oil accounts for 23 percent of the sulfur oxides and 44 percent of the nitrogen oxides emitted. Gas accounts for only 14 percent of the nitrogen oxides emitted from fuel combustion. Industry - Industry consumes 1, 306, 000 tons of coal, 271, 656, 000 gallons of fuel oil (mostly residual), and 79,445 million cubic feet of gas for process heat, power generation, and space heating and 12, 488, 000 tons of coal for coking annually. The emissions from the combustion of fuel amount to 39, 260 tons of particulates, 138, 965 tons of sulfur oxides, 58, 930 tons of nitrogen oxides, 2, 000 tons of carbon monoxide, and 1, 080 tons of hydrocarbons annually. The following percentages of the total amount of pollutants emitted from fuel combus- I tion in the study area are attributed to industrial fuel combustion: particulate 65 percent sulfur oxides 46 percent nitrogen oxides 67 percent hydrocarbons 50 percent carbon monoxides 30 percent Steam-Electric Utilities Utilities are the major user of coal; they consume 2, 290, 000 tons annually. They also consume 12, 460 million cubic feet of gas 13 ------- Table 6. AIR POLLUTANT EMISSIONS FROM COMBUSTION OF FUELS IN STATIONARY SOURCES IN NORTHWEST INDIANA (tons/year) Fuel Coal Fuel oil Gas User category Industrial Steam-electric Residential Others Totals Industrial Steam- electric Residential Others Totals Industrial Steam-electric Residential Others Totals Total emissions Carbon monoxide 2, 000 570 2,780 1, 120 6,470 5 -- 55 -- 60 n n 2 n 2 6, 532 Hydro- carbons 650 230 560 225 1,665 430 -- 55 -- 485 n n n -- n 2, 150 Nitrogen oxides 13,060 22,900 400 180 36,540 36,490 — 1,970 — 38,460 9,380 2,430 550 245 12,605 87,605 Sulfur oxides 74, 150 149, 500 6, 750 2, 320 232, 720 64,800 -- 3,430 -- 68,230 15 2 2 n 19 300, 970 Particulates 35,625 18, 300 1, 100 1, 125 56, 150 2,920 -- 330 -- 3,250 715 90 90 40 935 60,335 n Negligible. annually as a secondary fuel. The use of electrostatic precipitators in both of the power plants reduces the emission of particulates to 18,390 tons annually. Steam generating plants are one of the major sources of sulfur oxides, however, with annual emissions of 149,500 tons. The amounts of nitrogen oxides, carbon monoxides, and hydrocarbons emitted annually from, fuel combustion for power generation are, respectively, 25,330 tons, 570 tons, and 230 tons. Residential - The combustion of fuels in residential dwellings accounts for 111, 000 tons of coal, 54, 600, 000 gallons of fuel oil (mostly distillate), and 9, 500 million cubic feet of gas. Annual emissions from the combustion of this 14 ------- fuel are: 1, 545 tons of particulates, 10, 180 tons of sulfur oxides, 2, 610 tons of nitrogen oxides, 620 tons of hydrocarbons, and 2,840 tons of carbon monoxide. Others The commercial establishments use 45, 000 tons of coal and 4, 500 million cubic feet of gas primarily for space heating. The quantity of fuel oil consumed by commercial establishments is not available from the sources con- tacted. This quantity of fuel should be defined to complete the fuel balance for the study area. The amount of pollution from this source is not as great in quantity as from residential fuel combustion; but the concentration of the commercial sources is confined to specific areas within the four cities and their contribution is, therefore, significant. Pollutants from commercial sources amount to 1, 170 tons of particulates, 2, 320 tons of sulfur oxides, 425 tons of nitrogen oxides, 225 tons of hydrocarbons, and 1, 120 tons of carbon monoxide emitted annually. Fuel Combustion in Transportation Vehicles The transportation sources of air pollution include any vehicles that are powered by the combustion of fuels. The lack of traffic surveys and the lack of data on gasoline and dies el fuel consumption limited this category to automobile emissions in the total study area. The total emissions from automobiles were estimated by using gasoline sales in the area and converting this figure to gallons of gasoline. Although only an estimate, the results correlated well with similar surveys conducted in other areas. Automotive exhaust is estimated to contribute 204, 000 tons of carbon mo- noxide, 27,700 tons of hydrocarbons, 7, 910 tons of nitrogen oxides, 630 tons of sulfur oxides, and 780 tons of particulates. This amounts to 72 percent of the total emission of carbon monoxide and 24 percent of the total emission of hydro- carbons from all sources in the study area. Since traffic flow maps were not available for the entire area, no attempt was made to distribute the emissions from transportation throughout the study area. Combustion of Refuse Material Most of the refuse generated in the study area is disposed of in three ways: city-controlled landfills, industrial dumps, and on-site burning. On-site means 15 ------- that the refuse is disposed of on the premises on which it is produced. Certain industries, large apartments, and some commercial establishments are equipped with incineration facilities; but this factor was not considered because of the lack of specific data. Municipal landfills are subject to intermittent burning, which along with on-site burning, constitutes a substantial source of pollution. Estimating air pollutants emitted annually from open burning and incineration of refuse was difficult because accurate data on the quantities of refuse burned was unknown. To estimate air pollutants from solid wastes, information from local sani- tation and health agencies was gathered to determine the amount of wastes generated. This total amount was subdivided among the different modes of disposal. Certain assumptions and estimates had to be made in order to determine the quantity of refuse generated and disposed in the area. National averages of 1. 0 pound per capita per day for noncombustible and 3. 5 pounds per capita per day for combustible 'were used to determine the quantity of refuse generated in the four communities. As shown in Table 7, the total quantity was estimated to be 290, 500 tons of refuse per year. The refuse is composed of 227, 000 tons of combustible refuse and 63, 500 tons of noncombustible refuse. The location of this refuse in the communities was accomplished by using information received from the local sanitation agencies. From this information the amount of refuse disposed of by on-site burning was estimated by taking the difference between the amount of refuse generated in the area and the amount of refuse taken to the city dumps. On-site disposal was assumed to be exclusive- ly by burning. The amount of refuse burned openly in the city landfills is unknown. Calcu- lation of the pollutants emitted from the city landfills was based on burning of an estimated 10 percent of the combustible material received. This estimate is an arbitrary assumption and should be interpreted as such. Table 8 shows the amounts of pollutants emitted from the burning of refuse from the different modes of disposal. Disposal by on-site burning accounts for approximately 40 percent of the total refuse generated in the study area. This method of disposal accounts for over 80 percent of the pollutants emitted in each 16 ------- Table 7, REFUSE DISPOSAL IN NORTHWEST INDIANA " Location Hammond E. Chicago Gary Whiting Population 111, 648 57,669 178, 320 8, 137 Total Refuse Types and quantities of refuse generated Type Combustible Noncombustible Combustible Noncombustible Combustible Noncombustible Combustible Noncombustible Quantity, tons/yr 71, 000 20,000 37, 000 10, 000 114,000 32,000 5, 000 1, 500 290, 500 Mode of disposal City dump Landfill 28, 000 20,000 27, 000 10,000 43, 000 32,000 3,000 1, 500 164,500 Burned 3, 000 -- 3, 000 -- 5, 000 -- 1, 000 -- 12,000 On- c site 40,000 -- 7,000 -- 66,000 -- 1, 000 -- 114,000 Quantities of refuse generated were based on observed national averages of 3. 5 pounds per capita per day for combustibles and 1.0 pound per capita per day for noncombustible. Quantities of refuse taken to city dumps are based on estimates from local ^sanitation agencies. "On-site quantity was taken as the difference between refuse generated and de- posited at city dumps. Table 8. AIR POLLUTANT EMISSIONS FROM REFUSE BURNING Location Hammond E. Chicago Gary Whiting Totals Source City dump On-site City dump On-site City dump On-site City dump On-site Pollutants, tons/yr Particulates 70 9,40 70 20 120 1,550 20 20 2,810 Sulfur oxides 2 16 2 3 3 26 n n 52 Nitrogen oxides n 10 n 1 1 16 n n 28 Hydro- carbons 420 5,600 420 980 700 9,240 140 140 17,640 Carbon monoxide 125 1,630 125 295 210 2,770 40 40 5,285 n Negligible. ------- category from refuse burning. The amounts of each pollutant from on-site burn- ing were distributed by population densities throughout the study area. Since these totals were obtained by differences, any error in the assumed per capita generation or in the quantities handled at the collective disposal sites will be reflected in these figures. Although 60 percent of the total refuse is estimated to be disposed at the city landfills, only approximately 10 percent of the total pollutants are ascribed to this method of disposal. The amounts burned at these locations is only an estimate, and the air pollution estimates are, therefore, thought to be conservative. Additional information on amounts of refuse burned at the landfills at specific industrial dumps, and at commercial and domestic incinerators is needed to refine the emission quantities from refuse disposal. Emissions from refuse disposal are small in comparison with most of the other types of sources, but the proximity of these sources (on-site disposal) to the individual citizen can cause irritation and concern. Industrial Process Emissions The quantities of the various pollutants discharged to the atmosphere from industrial and commercial establishments are generally attributable to two types of operations, the combustion of fuels and industrial processes. Unfortunately, emission factors are available for only a small number of processes and industries. Data relating to the industrial processes and the materials handled in these processes were collected through questionnaires distributed by local air pollu- tion agencies and by personal contact with a number of industrial groups. Several smaller sources did not have the necessary information, and these exceptions are noted where applicable. In the Northwest Indiana area the two predominant types of industry are petroleum refining and steel manufacturing. Allied industries in the area are chemical plants, foundries, and metal fabricators. As stated previously, the petroleum and steel industries employ approximately 60 percent of the 100, 000 workers in the study area. A summary of the emissions from the industrial processes in the study area is shown in Table 9. Because of insufficient data, not all existing industrial processes are listed in this table. The data on this table are subject to change when more specific process information is available.. 18 ------- Table 9. SUMMARY OF INDUSTRIAL PROCESS EMISSIONS IN NORTHWEST INDIANA, 1966 (tons/yr) Pollutant and sources Particulates Refineries Cement plants Chemical plants Foundries Steel Grey iron Other Other sources Steel mills Blast furnace Open hearth Basic oxygen furnace Sintering plant Coke plant Total Sulfur oxides Refineries Sulfuric acid manu- facturing Other sources Total Hydrocarbons Refineries Storage Slowdown system Waste water separator Leakage Catalytic cracking Vacuum distillation Other sources Total Carbon monoxide Refineries Total S.Chicago 900 na -_ na na -- 3, 380 40,600 36, 400 6, 050 87, 300 na 18, 000a 18,000 -- 20,075 i 8,400 ' 9,860 2,560 2, 190 1,095 6,220 50,400 60,200 60, 200 Gary 26,600 182 1,420 — na 3,800 26, 900 450 53, 100 7, 500 120,000 -- -- -- -- — -- -- -- -- Hammond ~ ™* __ 10 20 20 -- 50 na 18,000 18,000 -- -- -- -- -- -- Whiting 1,500 -_ — -- -- 1,500 13,000 -- 13,000 16,400 -- -- 16,400 6,600 6,600 Study area 2,400 26,600 182 1,420 10 20 17 7, 180 67, 500 450 88,500 13,550 208,800 13,000 36,000 49,000 16,400 20,075 8,400 9,860 2,560 2, 190 1,095 6,220 66,800 66,800 66,800 aEstimated figure. na - Information not available or reported. 19 ------- Steel Manufacturing Three major steel plants within the boundaries of the study area operate a full line of equipment including: blast furnaces, oxygen-lanced and nonoxygen-lanced open hearths, sintering plants, coke plants, basic oxygen furnaces, and individual power plants. As shown in Table 10, the steel manufacturing industry emits 186, 780 tons of particulates per year, which amounts to 89.4 percent of the total particulates from industrial processes and 68. 5 percent of the total particulates emitted in the study area. Oil Refineries The study area has four complete oil refineries and a number of storage and distribution centers. The most important air pollution consider- ations with respect to refinery emissions are crude oil processing capacity, the processing techniques employed, types of fuels used and their composition, maintenance and housekeeping, and the air pollution control measures used. Hydrocarbons, oxides of sulfur and nitrogen, carbon monoxide, and odors are the primary pollutants emitted from these operations. Table 11 shows the different sources and amounts of pollutants emitted from the petroleum refineries. Of the hydrocarbons emitted in the study area, 62 percent are from the industrial processes of the refineries. Chemical Industry - A number of large chemical plants are located in the study area, but lack of emission factors and production data for most of the plants make it impossible to estimate emissions from the chemical industry's opera- tions. Sulfuric acid is produced at two of the chemical plants. Information for one plant permitted an emission estimate of 18,000 tons of sulfur dioxide per year. Cement Manufacturing - A large cement manufacturing plant in the area has an annual capacity of 8. 3 million barrels. By the nature of this process, particu- late material is the pollutant of prime concern. The amount of particulate matter emitted from the cement kilns was estimated by applying emission factors and control efficiency information from the local air pollution agency. An estimated 26, 600 tons of particulate is discharged annually from this plant. Foundries - The lack of process information on area foundries makes it virtually impossible to estimate their total emission contribution. Data were available for two foundries; one, a steel foundry, emitted approximately 1,420 tons of particulates annually, and the second, a grey iron foundry with a capacity of 20 ------- Table 10. AIR POLLUTANT EMISSIONS FROM STEEL INDUSTRY IN NORTHWEST INDIANA (tons/yr) Operation Blast furnaces Open hearths Basic oxygen furnaces Sintering plants Coking plants Combustion of fuel Total Number of units 23 101 3 5 3 -- Pollutants Particu- lates 7, 180 67, 500 450 88, 500 13,550 9,600 186,780 Sulfur oxides -- -- -- -- -- 77,850 77,850 Nitrogen oxides -- -- -- -- -- 54, 000 54, 000 Hydro- carbons -- -- -- -- -•- 820 820 Carbon monoxide -- -- -- -- -- 920 920 Table 11. POLLUTANT EMISSIONS FROM PETROLEUM REFINERIES IN NORTHWEST INDIANA (tons/yr) Pollutant source Storage a General Processes Catalytic cracking b Auxiliary equipment Fuel combustion Total Partic- ulates -- -- 2,240 -- 1,050 3,290 Sulfur oxides -- 13, 000 -- -- 51,990 64,990 Nitrogen oxides -- -- 840 -- 14,860 15, 700 Hydro- carbons 20, 070 23,720 2,200 20,840 -- 66,830 Carbon monoxides -- -- 66,825 -- -- 66,825 General processes include vacuum distillation, loading, cooling towers, etc. Auxiliary equipment includes blowdown systems, waste water separators, leak- age, etc. 21 ------- 12,500 tons of material per year, emits only 10 tons per year because of control equipment. More data should be collected because of the significant nature of this process in the quantities of pollutants emitted. EMISSIONS BY GEOGRAPHICAL AREA The Northwest Indiana communities of East Chicago, Gary, Hammond, and Whiting are geographically interrelated to the extent that each community borders two or more of the other communities. This factor adds to the com- plexity of the air resource management program because air pollution does not respect municipal boundaries. Figures 3 through 13 indicate the geographical locations of point and area source emissions. Point sources are those specific industries with total emissions above a particular figure, and area sources are domestic, com- mercial, manufacturing, and refuse burning sources that are below a specified amount of emissions and are reported in tons per year per grid. Not all sources that could be listed in the point source category are included on these maps because of the lack of specific data, mostly on process capacities, that would make it possible to calculate their emissions. The location of the point sources in the study area are illustrated on Figures 3, 4, and 5. Figure 3 shows the location of point sources that annually emit 250 tons or more of particulates. This map locates 20 such sources with a range of emissions from 250 tons per year to 92, 000 tons per year. Because of the location of these point sources, all but three of them could influence the air pollution problem in all of the four communities located in the study area. Sulfur oxide emissions from point sources are located in Figure 4. This map shows 17 point sources with a range of 250 to 75, 000 tons per year. Figure 5 shows the point sources that emit more than 250 tons of nitrogen oxides per year. The map locates 13 such sources; these emissions are in the range of 250 to 23, 000 tons per year. The Northwest Indiana study area includes over 400 manufacturing plants, over 102,000 domestic dwelling units, and numerous commercial establishments. Figures 6 through 12 illustrate the estimated geographical location of the pollu- tant emissions from these sources. The area manufacturing sources include 22 ------- t-Aff CALUHCT 380 385 390 395 1530 TT "^^" 40° 405 41° 415 Illfe Ny-^ . 1525 1525 LAKE MICHIGAN 1515 420 425 430 435 440 445 450 455 460 465 JL HAMMOND TRI-STATE CALUMET L CITY 1505 - 1500 1495 1490.-- 1485 1480 PARTICIPATES, 380 385 390 395 40Q 405 4,Q 415 tons/yr 250 - 1,000 1,000 - 5,000 5,000 - 10,000 OVER 25,000 -1505 1470 1465 450 455 460 465 1475 HOBART 1470 1465 1 N 425 430 435 440 445 MILES Figure 3. Particulate emissions from point sources. ------- tv itft tumuli CALUMET CITY LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 1505 HAMMOND TRI-STATE 380 385 390 395 400 405 410 415 420 SOX, tons/yr 250 - 1,000 1,000 - 10,000 10,000 - 20,000 20,000 - 50,000 OVER 50,000 425 430 435 440 445 MILES Figure 4. Sulfur oxide emissions from point sources. ------- 380 385 390 395 »• : Hire CALUHCT 1530 1525 CALUMET CITY 1515 15KI 1505 1500 1495 1490- 1485 1480 400 405 410 415 LAKE MICHIGAN 470 425 430 435 440 445 450 455 460 465 JL i i NOX EMISSIONS, tons/yr • 250-1,000 • 1,000 - 5,000 0 5,000 - 10,000 10,000 - 20,000 OVER 20,000 HAMMOND TRI-STATi , 380 385 390 395 400 405 410 415 420 425 430 435 440 445 MILES Figure 5. Nitrogen oxide emissions from point sources. ------- rv CT- 380 385 390 395 LttXl CALUUET 1530 I 1525 f CALUMET CITY 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 PARTICIPATES, tons/yr 380 385 390 395 400 405 410 415 420 50 - ' Ik ! 75-99 100 - 199 200 - OVER 425 430 435 440 445 MILES Figure 6. Participate emissions from area sources. ------- 380 385 390 395 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 CALUMET CITY 1505 SO EMISSIONS, 38° 385 39° 395 4°° 405 41° 41S 42° 1470 , .. 1465 tons/yr 3 50 - 99 100 - 299 300 - 600 . OVER 600 425 430 435 440 445 MILES Figure 7. Sulfur oxide emissions from area sources. IN, ------- 00 380 385 390 395 LtKC CiLVUtl 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 CALUMET L CITY 1505 380 385 390 395 400 405 410 415 420 NOX, tons/yr 50 - 7k OVER 200 425 430 435 440 445 MILES Figure 8. Nitrogen oxide emissions from area sources. ------- 380 385 390 395 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 1495 1490- 1485 1480 PARTICULATES, tons/yr n~-~i 50 - ik 75 - 99 100 - 200 OVER 200 H A MM ON D TRI-STATE 380 385 390 395 400 405 410 415 420 425 430 435 440 445 MUES Figure 9. Particulate emissions from commercial and area manufacturing sources. ------- U) o 380 385 390 395 1330 1S25 1515 CALUMET CITY 1505 1500 1495 1490- 1485 1480 SOX, tons/yr I I 50 - 99 100 - 199 200 - 299 OVER 300 400 405 410 415 LAKE MICHIGAN 470 425 430 435 440 445 450 455 460 465 HAWMOND TRI-STATE 380 385 390 395 400 405 410 415 420 425 430 435 440 445 MILES Figure 10. Sulfur oxide emissions from commercial and area manufacturing. ------- 380 385 390 395 1530 1515 CALUMET CITY 1505 1500 1495 1490 1485 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 PARTI CULATES, tons/yr "7~| 50 - Ik HI. 75 - 99 380 385 390 395 400 405 410 415 420 1470 1465 450 455 460 465 1475 HOBART 1470 1465 I N 425 430 435 440 445 MILES mim 100 - 200 OVER 200 Figure 11. Particulate emissions from domestic heating and on-site burning. ------- N 380 385 390 395 1,4*1 C4LVHI' 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 CAIUMJT cirr •as* 450 455 460 465 380 385 390 395 400 405 410 415 420 1470 1465 £0X, tons/yr 425 430 435 440 445 MILES Figure 12. Sulfur oxide emissions from domestic heating and on-site burning. ------- 380 385 390 395 400 405 410 415 LAKE MICHIGAN 420 425 430 435 440 445 450 455 460 465 HAMMOND tUl-StATf NITROGEN OXIDES, tons/yr 50 - 7k 75 - S3 100 - 130 OVER 130 380 385 390 395 400 405 410 415 420 425 430 435 440 445 Figure 13. Nitrogen oxide emissions from domestic heating and on-site burning. ------- those plants that were not considered as point sources, and the pollutants ascrib- ed to these sources were distributed by finding a percentage of the employees in the particular grids and assigning that particular percentage of the total pollutant load from area manufacturing to that grid or by actual location of the particular plant. The emissions from commercial sources were calculated, and this amount was distributed to the downtown sections of each of the four communities. There is probably notable error in this distribution; but since detailed data on commercial sources were not available, this method of distribution was used to incorporate this source of pollutant emissions. The domestic source of pollutant emission was distributed in the following manner. The census tracts in this Standard Statistical Metropolitan Area were available with information on the number of dwellings using specific fuels (see Table 12). These numbers were distributed into the grid system, and a percent- age of the total amount of dwellings for each fuel was taken. This percentage was then applied to the total emissions from this source and added to the partic- ular grid in question. Another source of pollution, on-site burning of refuse, was also distributed in a like manner. Table 12. SUMMARY OF DOMESTIC HEATING BY NUMBER OF DWELLING UNITS IN NORTHWEST INDIANA, 1960 All occupied units Heating fuel Utility gas Fuel oil, kerosene, etc. Coal or coke Electricity Bottled, tank, or LP gas Other fuel None East Chicago 16,837 4, 855 7,839 3,772 59 100 173 39 Gary 50,283 12,692 29,283 6,935 296 780 251 46 Hammond 32,997 12,271 15,272 4,881 59 470 20 24 Whiting 2,569 1, 035 929 575 -- 30 -- -- Study area 102,686 30,853 53,323 16, 163 414 1,380 444 109 Percent of total 100. 0 30. 1 52. 0 15.7 0.4 1. 3 0.4 0. 1 34 ------- Figures 6, 7, and 8 show the geographical variation of particulates, sulfur oxides, and nitrogen oxides, respectively, for area sources. Included in these area sources are area manufacturing and commercial, domestic and on-site burning. A breakdown of the geographical area source emissions is given in Figures 9 through 13. The commercial and area manufacturing sources in Figures 9 and 10 show emissions of particulates and sulfur oxides, respectively. Figures 11, 12, and 13 locate the emissions from domestic fuel combustion and on-site burn- ing throughout the study region. These figures show the amounts of particulates, sulfur oxides, and nitrogen oxides and their distribution throughout the study region. It should be noted that I960 census figures were used in the calculation of the domestic emissions and that the amounts of fuels used for domestic heating were up-dated to 1965 when the figures were available. SUMMARY The results of the emission inventory show the need for further study in certain areas. The fuel consumption by industries has been defined well in some areas and poorly in others. The consumption of coal and of natural gas have been defined to a fairly accurate degree from figures provided by area -wide associations. The lack of such an organization to provide fuel oil data has left an emission category that still must be evaluated. Also, as stated in the report, recalculation of some of the coal figures could be performed when more informa- tion on the chemical composition of the coal is received. This would help to increase the accuracy of the inventory. An inventory should be made to determine the locations of commercial establishments and the exact quantity of fuel burned at each. This information would complete the fuel combustion inventory. Comprehensive traffic flow maps of the four-city area are needed to com- pute the emissions from transportation on a vehicle-mile basis. Since emissions from transportation are approximately 25 percent of the total emission in this area, geographical distribution of these emissions is important and should be studied further. A detailed study is also needed to determine industrial process emissions. The lack of process information that can be used to estimate the emissions re- 35 ------- suiting from these sources impaired establishing an accurate inventory. Foundries, chemical plants, sulfuric acid manufacturing, and refineries are a few of the processes requiring collection of more detailed information. The last area of concern is refuse disposal. The quantities of refuse burned at the city dumps should be more accurately defined because of the size of this source of pollution. An inventory of the industrial and commercial incinerators should be made to define the on-site burning more precisely. 36 ------- |