4>EPA
United Stales
Environmental Protection
Agency
EPA-600/7-86-004b
February 1986
Research and
Development
ENVIRONMENTAL ASSESSMENT OF
A WATERTUBE BOILER
FIRING A COAL/WATER SLURRY
Volume II. Data Supplement
Prepared for
Office of Air Quality Planning and Standards
Prepared by
Air and Energy Engineering Research
Laboratory
Research Triangle Park NC 27711
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports in this series result from the
effort funded under the 17-agency Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects; assessments of, and development of, control technologies for energy
systems; and integrated assessments of a wide range of energy-related environ-
mental issues.
EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication. Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.
-------
EPA-600/7-86-004b
February 1986
ENVIRONMENTAL ASSESSMENT OF
A WATERTUBE BOILER FIRING
A COAL-WATER SLURRY
Volume II
Data Supplement
By
R. DeRosier and L R. Waterland
Acurex Corporation
Energy & Environmental Division
555 Clyde Avenue
P.O. Box 7555
Mountain View, California 94039
EPA Contract No. 68-02-3188
EPA Project Officer: R. E. Hall
Air and Energy Engineering Research Laboratory
Research Triangle Park, North Carolina 27711
For
US. ENVIRONMENTAL PROTECTION AGENCY
Office of Research and Development
Washington, DC 20460
-------
CONTENTS
Section Page
1 Introduction 1-1
2 Preliminary Results 2-1
3 Boiler Operating Data 3-1
4 Sampling Data Sheets 4-1.
5 Analytical Results 5-1
5.1 Fuel Analysis 5-3
5.2 SASS Particulate Emissions 5-11
5.3 EPA Method 5 Particulate Emissions 5-17
5.4 EPA Method 8 Analyses (Sulfur Oxides) 5-25
5.5 Trace Element Analyses .... 5-29
5.6 GI to CQ Hydrocarbons by Gas Chromatography .... 5-47
5.6.1 From June 11, 1982 5-49
5.6.2 From June 17, 1982 5-63
5.7 N£0 by Gas Chroma tography 5-81
5.8 Total Chromatographable Organics (TCO), Gravimetric
Organics (GRAY), IR Spectra, Gas Chromatography/Mass
Spectrometry (GC/MS), Liquid Chromatography (LC),
and Low Resolution Mass Spectrometry (LRMS) .... 5-109
5.9 Bioassay Reports 5-165
ii
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SECTION 1
INTRODUCTION
The purpose of this data supplement is to document data in greater
detail than was possible in Volume I (Technical Results) of this report. It
is intended to provide sufficient detail for researchers to perform their own
analysis of the data obtained. Readers are referred to the technical volume
for objectives, description of source emission results, data interpretation,
and conclusions.
The remaining sections of this data supplement contain the following
information:
Section 2 — Preliminary Tests: stack velocity traverse and gas composition
tests
Section 3 ~ Boiler Operating Data: continuous monitors, pressures,
temperatures, and flowrates
Section 4 — Sampling Data Sheets: operating data tables for EPA Method 5/8
(for particulate mass emissions, S02 and 503 sampling), and SASS
(for trace element and organic sampling)
Section 5 -- Analytical Laboratory Results: fuel analysis, SASS particulate
emissions; Method 5 particulate emissions; Method 8 sulfur
oxides emissions; trace element emissions by spark source mass
spectrornetry (SSMS) and atomic absorption spectroscopy (AAS); Cj
to CQ hydrocarbons by gas chromatography; N£0 by gas
chromatography; total chromatographable organic (TCO) and
1-1
-------
gravimetric (GRAV) results; infrared (IR) spectra; determination
of organic compounds by gas chromotography/mass spectrometry
(GC/MS); liquid chromatography (LC) separation results; low
resolution mass spectrometry (LRMS) analyses; and biological
assay reports.
1-2
-------
SECTION 2
PRELIMINARY RESULTS
2-1
-------
(This page intentionally blank.)
2-2
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
PLANT ~'' L V C
DATE ,. -
SAMPLING LOCATION *N^-r
INSIDE 01 FAR WALL TO
OUTSIDC OF NIPPLE. (DISTANCE A) _
INSIDE OF NEAR WALL TO
OUTSIDE OF NIPPLE, (DISTANCE B) _
STACK I.D., (DISTANCE A - DISTANCE B).
NEAREST UPSTREAM DISTURBANCE
NEAREST DOWNSTREAM DISTURBANCE.
CALCULATOR '' '• ~~ =
'.-;, ft (j.- \ \
U
SCHEMATIC OF SAMPLING LOCATION
TRAVERSE
POINT
NUMBER
y
'•?'
U-
>
« )
^
t<
\
ft
W
L^
'-*~4.
~\
^
f -\
I
FRACTION
OF STACK I.D.
; s ZL-
.S^M
. 704
-c'^lO
,11U
,c?4H
•• Sf ;>7-
, -V'JM
. 7t'V
<7 Hr-
, N4>
• OH'-f
STACK I.D.
3M-"
f
*5n
cl^f''
a-''
SLS-"
-a*-;- "
&r^ "
^H-"
.V
*(
a^
J^"
5v"'
PRODUCT OF
COLUMNS 2 AND 3
(TO NEAREST 1* INCH)
^5r^3
->(• 5
"t ' -;
5 \.L"
--J ! •'
t
.'-, -> "
•^ J
•si '- ' j
,• •'
1 i. '•'.
7- '
=:. 5"
i
DISTANCE B
';,
]•
1
':
].-...
i
i
"-> '
'"17
>^}
i
-t-
TRAVERSE POINT LOCATION
FROM OUTSIDE OF NIPPLE
(SUM OF COLUMNS 4 & 5)
~ -
31 ''
-<1"
^ • J>
i 'i V •
) ' • i
C- '->
-r
;PA (Our) 232
4.72
2-3
-------
PRELIMINARY VELOCITY TRAVERSE
PLANT ' : '-
DATE - -
LOCATION -
STACK I.D.
BAROMETRIC PRESSURE, in. H»
STACK GAUGE PRE
OPERATORS
SSURE. in. H,0 -• ^ '" :
TRAVERSE
POINT
NUMBER
-
^..
i
i
i
AVERAGE
VELOCITY
HEAD
(4p$), in.H20
.,•
••s ;->
'-- ^:
- ' ,- )
-:
~
' C. ";
STACK
TEMPERATURE
(Ts>, "F
-
i
i
i
!
1
I
i
|
EPA (Our) 233
472
SCHEKATIC OF TRAVERSE POINT UYOUT
2-4
TRAVERSE
POINT
NUMBER
AVERAGE
VELOCITY
HEAD
fcp$), in.H20
STACK
TEMPERATURE
-------
Plant.
Date
ISOK1NECT1C SAMPLING WORKSHEET
Peformed by_
Sample Location_
Test No./Type
K = 782.687 (Cp)2 (1-BWO)2 P
Ms Pm
where: K = Contant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimensionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Mdd-Bwo) + 18(8^)
Abolute meter pressure (in. Hg)
782.687 (:- vl)2 (1-^)2 (^^) (^AJ
(c_^)2<^ (£-J
CP
Bwo
PS
J\
Ko
MS
Pm
K
"V , . "
f." /-.•' I
.
— :.; ., ' . ' "-•
A- z
c- ;//
^^.;.r
c-V / ?
Sim
2-5
-------
ISOKINECTIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
Plant _
Date
Performed by_
Sample Location
Test No./Type
~OC '.-! ».
AH
25
where:
Nozzel diameter (inches)
Average pressure differential across the
orifice meter (in. HgO)
Temperature stack gas, average (°F)
Temperature of gas meter, average (°F)
Stack gas velocity pressure (in HgO)
/ (;-Q ( ' -'i + 460) V25
U:; ) (.-: ^460)(:;^)/
AH
TS
Tm
AP
. Nd
[
..-
.- = ,.
J ' —
0--1- V
j-i,r-f
AH = K (Nd)4 (AP)
where: AH » Pressure differential across the orifice meter (in
Nozzel diameter
Temperature of
Temperature of
, actual (inches)
gas meter (°F)
stack gas (°F)
Stack gas velocity pressure (in H£0)
§ »,- — . % *
Magic number :•
.4 (f-.: + 460) / A
— i '-+ *60) l-^y
--:-.•• {..:',)«
D
m
TS
AP
AH
K(Nd)4
.- - • ~?
>.-o
-/ -' --
-^ — —
C"' V ri.
; i -;•
^ -- ..^,
2-6
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
PLANT Pt'TC /Dot
DATE C- 1, 7/x'',J
SAMPLING LOCATION ">.
CO H\-' iJ,, ;(ei . t>^. n\v. ;C
INSIDE 01 FAR WALL TO
OUTSIDL OF NIPPLE. (DISTANCE A) _
INSIDE OF NEAR WALL TO
OUTSIDE OF NIPPLE, (DISTANCE B) _
STACK I.D.. (DISTANCE A • DISTANCE B).
NEAREST UPSTREAM DISTURBANCE
NEAREST DOWNSTREAM DISTURBANCE.
CALCULATOR '^ '-'-' *^T
II
Sd&
SCHEMATIC OF SAMPLING LOCATION
TRAVERSE
POINT
NUMBER
.;,
^
•^
"5
^
i
'
;-
-
>
1
1
FRACTION
OF STACK 1.0.
C-9SL,
'" \ C*w
^ "0 ->
c.. ;ov
. .^q^
C-.^L-
d.C'4-^
C-9S%
A ,V • v/
v^ '6 i ^
C- /v-i
CyJ,^
o. (Ho,
C" -C '-? ^
STACK 1.0.
0(f''
\1
'
i
PRODUCT OF
COLUMNS 2 AND 3
(TO NEAREST 1 1 INCH)
3?''
A- r '
it- / '
t/
_ t <
/ "
ay
PC, sr v
/6--9 lf
• 7 / "
?'-b~y
/ "
DISTANCE B
K"
1
4
v> r'
V
f
TRAVERSE POINT LOCATION
FROM OUTSIDE OF NIPPLE
(SUM OF COLUMNS 4 & 5)
3V "
3i- ^
5?-f
/^ /
/v« T
/ ^
^C
%?>r
/?- f
/o./
C- ^'
• i
EPA (Our) 232
472
2-7
-------
PRELIMINARY VELOCITY TRAVERSE
PLANT Pbl"C /DOt
DATE 6 In /s--;x
LOCATION 700
STACK I.D.
e-. ,
i c-
BAROYURIC PRESSURE, in. Hf _
STACK GAUGE PRESSURE, in. H20.
- 3-Q " H ? o
OPERA! DRS
Plu<4:.ff
SCHB'-ATIC OF TRAVERSE POINT UYOUT
TRAVERSE
POINT
NUMBER
i
-,
'~f
(,
~\
V
vf
AVERAGE
VELOCITY
HEAD
Cips), in.H20
C 3 ?
£- V 5
6-
-------
Plant_
Date
ISOKINECTIC SAMPLING WORKSHEET
^^______ Reformed by
Sample Loc at 1 on
Test No. /Type
K = 78Z.687 (Cp)2 (1-BWO)2 P
M
where: K = Contant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimer.sionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Md(l-Bw£)) + 18{BWQ)
Abolute meter pressure (in. Hg)
782.687 (£#!)2 (1-_£L)2 (ff;*?) (££i)
(ff'/n )2 (>/y) p^ti)
CP
BWO
- 51. o"i-< i o
PS
Md
rfi^arip ( <* 7.tO<_
•J -?• O i_
S'27c .^-i_
KO
MS
Pm
K
^ - ?r?
^•09,
/^iSixAe 1 H
2-9
-------
Plant
Date
ISOKINECTIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
Performed by_
Sample Location ~7oo HP
Test No. /Type £*. /Pi
.. te*
hc
25
T
where: NJJ = Nozzel diameter (inches)
Average pressure differential across the
orifice meter (in. HgO)
Temperature stack
Temperature of gas
Stack gas velocity
/ (/__, (_
gas, average (°F)
meter, average (°F)
pressure (in H20)
^_ + 460} V25
\ (.'•••"> -) ( ><- + 460)(:-- )/
AH
TS
Tm
a
.*
s?°.
TO
P-S'g
—
AH
= K (Nx)4 J2 (Ap)
Q I
where: AH « Pressure differential across the orifice meter (in H20)
Nozzel diameter, actual (inches)
Temperature of gas meter (°F)
Temperature of stack gas (°F)
Stack gas velocity pressure (in HgQ)
r
(r-o,vi f -,c \4 (^C + 460) f A
^-' (^-' 1 c-c ..* 460) l^-^ j
Magic number _( )
Nd
Tm
TS
AP
AH
K(Nd)4
C->T;J.
%<:?
5" 3 o -
-^e-
0 - b~Sf
I.Ob"
? ?/y
2-10
-------
SECTION 3
BOILER OPERATING DATA
3-1
-------
(This page intentionally blank.)
3-2
-------
Key to Operating Data Tables
Column No. Parameter measured
6 C02 volume fraction in dry flue gas after furnace (percent)
7 02 volume fraction in dry flue gas after furnace (percent)
8 Taylor 02 analyzer after furnace (percent)
9 CO volume fraction in dry flue gas after furnace (ppm)
10 CHx volume fraction in dry flue gas after furnace (ppm)
11 NOx volume fraction in dry flue gas after furnace (ppm)
12 SOx volume fraction in dry flue gas after furnace (ppm)
13 C02 volume fraction in dry flue gas after baghouse (percent)
14 02 volume fraction in dry flue gas after baghouse (percent)
15 CO volume fraction in dry flue gas after baghouse (ppm)
16 CHx volume fraction in dry flue gas after baghouse (ppm)
17 NOx volume fraction in dry flue gas after baghouse (ppm)
19 Mass flowrate of fuel from micromotion meter (Ib/min)
22 Barometric pressure (psia)
23 Furnace pressure (in. 1^0)
24 Pressure of steam in boiler (psia)
25 Pressure of fuel before preheater (psia)
29 Pressure of atomizing steam to burner (psia)
30 Pressure of CWS loop at pipe bend (psia)
31 Pressure drop of CWS loop across bend (in H£0)
32 Pressure of CWS loop after straight section (psia)
33 Pressure of CWS loop at end of test section (psia)
34 Combustion air pressure at brandt meter (in. 820)
35 Coal/water pressure at nozzle (psia)
36 Coal/water pressure at pump (psia)
37 Atomizing air pressure at orifice (psia)
38 Atomizing air pressure at nozzle (psia)
39 Natural gas pressure (psia)
40 Center tube pressure (in. ^0)
41 Scani zero reference (approximately 3 psig) (psig)
42 Scani span reference (approximately 9 psig) (psig)
43 Pressure drop of atomizing steam (in. I-^O)
44 Pressure drop of steam from boiler (in. H?0)
45 Pressure drop of makeup water at orifice (in. ^0)
46 Pressure drop of combustion air (annubar) (in. H20)
47 Pressure drop of CWS across straight section (in. H20)
48 Pressure drop of CWS across the test section (in.
49 Atomizing air flow (in.
50 Natural gas flowrate (in.
51 Center tube delta P (in.
52 Combustion air flow (brandt total air) (in.
53 Temperature of flue gas after cooler (°F)
54 Temperature at flue gas cooler (°F)
55 Temperature at fuel after preheater (°F)
56 Temperature at bottom of coal supply hopper (°F)
57 Temperature of dust collector (°F)
58 Temperature at bottom of proportioning feeder tank (°F)
3-3
-------
Key to Operating Data Tables (concluded)
Column No. Parameter measured
59 Temperature at bottom of coal slurry hold tank (°F)
60 Temperature of fuel oil at storage tank (1 ft from bottom)
61 Temperature of fuel oil at storage tank (6 ft from bottom)
62 Temperature of fuel oil at storage tank (12 ft from bottom)
63 Temperature of fuel oil at storage tank (18 ft from bottom)
64 Temperature of fuel oil at storage tank outlet (°F)
65 Temperature of fuel before preheater (°F)
66 Temperature of fuel to burner (°F)
67 Temperature at baghouse no. 1 (°F)
68 Temperature at stack blower inlet (°F)
69 Temperature at stack blower outlet (°F)
70 Temperature of combustion air to furnace (°F)
71 Temperature of flue gas after cooler (°F)
72 Temperature of atomizing steam (°F)
74 Temperature of steam from boiler (8F)
75 Coal/water temperature at nozzle (°F)
76 Boiler skin temperature (front west) (°F)
77 Boiler skin temperature (top center east) (°F)
78 Boiler skin temperature (top center west) (°F)
79 Atomizing air temperature at orifice (°F)
80 Entrance of convection bank temperature (°F)
81 Boiler skin temperature (right side east rear) (°F)
82 Natural gas temperature (°F)
83 Water outlet temperature (°F)
84 Boiler skin temperature (left side west front) (°F)
85 Combustion air temperature at brandt meter (°F)
86 North wall temperature (°F)
87 Temperature of flue gas after furnace (°F)
88 Temperature at makeup water orifice (°F)
89 Temperature of duct exit of boiler (°F)
90 Temperature of condensate return line at D A (°F)
91 Temperature of CWS loop after pump (°F)
92 Temperature of CWS loop at pipe bend (°F)
93 Temperature of CWS loop at test section inlet (°F)
94 Temperature of CWS loop at end of test section (°F)
95 Center tube air temperature (°F)
96 Refractory temperature taper block (°F)
97 Refractory temperature top of convulsion (°F)
98 Refractory temperature bottom of convulsion (°F)
99 Thermocouple reference junction temperature ( F)
3-4
-------
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-------
SECTION 4
SAMPLING DATA SHEETS
4-1
-------
(This page intentionally blank.)
4-2
-------
FIELD DATA
Paoe i of
Plant r». i ''. ,/i-Vi .
Date .,//!/'"»
Imptnger Volumes
Initial Final Net Gain
Probe Length and Type _ ' !_
Norzel Sire A 1.0. < ' '
Sample Location ^.'-\ • -•_
Sample Type \~> i *> /'V'
Run Number i
Oper a tor t- ^-- i k (
Ambient Temperature .''.. ' '
Pitot Coefficient & I.D.
Assumed Moisture
Barometric Pressure -'•"(• ' **
Static Pressure, (H;0) •>_ ;_'j 'I * c
Filter Number(s) fjV I H^ ~' ;) ^ ^"
Leak Check: Initial at IL- • Hg, £^-^ CFM
Final at 7F~" Hg, ~7~i7Z CFM
Pitot Leak Check: c~
Molecular Ueiqht, Dry, (Mrf)_
Meter Box Number •, •'
Silica Gel
Meter Coefficient__<_
<* Factor_
K •
/
SASS Condensate
Total Volume
K(Nd)'1 - * ( }A
i
CO
Gas Meter
Reading
(vm). rt 3
In'*.
Velocity
Head
(-Pc).
In. R20
Orifice Pressure
Differential
{AH), InJ H?0
Desired
Actual
Temperature °F
Stack
Probe
Impinger
Organic
Module
Oven
Gas Meter
In
Out
Pump
Vacuum
in. Hg
Avg.
i Tl
7602/5/.81/Rev 1
fnmmcnts:
-------
Page - of
Traverse
Point
Number
'i
1 1' '<
^\^ Clock Time
\. (24-hr)
N. Clock
Sampling x^
Time, mln >v
^-\^
- -,
' j l >- • ••. '-' f ',
'/l«^>'
Gas Meter
Reading
(««). » 3
Inlt.
- J ':' •> li \ <:\
; J 3 : -. s
.^'
Pump
Vacuum
in. Hg
1 1
Awg.
AP~
* ;
Run No.
Date
Sampling Location :_
Coinnents:
-------
FIELD DATA
Paoe
_/-
"'
Ptant_?CTC
Date
/ / 7 /
Sample location^
Sample Type
Run Number „
HP. e^iUv
Impinger Volumes
Initial Final
arvU •
. ?// /3t
Hg. _£_£/CFM
Hg,
-------
Page c_ of
Traverse
Point
NiMber
Clock Time
(Z«-hr)
Clock
Sampling
Ti»e,
Gts Neter
Reading
(V.). ft 3
Lit.
Velocity
Head
in, H20
Orifice Pressure
Differential
(AH), in. HjO
Desired
Actual
Temperature °F
Stack
Probe
Inplnger
Organic
Nodule
Oven
Gas Heter
In
Out
Piwp
Vacuu*
In. Hg
Avg.
/yr
7?
7?
7*
77
v
/", -9 *
O
7?
7-7
-er
O F F ,
V 0
G-E
D
Run No.
Date
Sampling Location
-t
Comments:
-------
FJELD DATA
Paqe ' of
Plant
Date
Sample Location
Sample Type_
Run Number
Operator P. I
Impinger Volumes
Initial Final Net Gain
~TST)
Probe Length and
Nozzel Size ft 1.0.
Pilot Coefficient & 1.0.
Assumed Moisture \ >s
Ci
Silica Gel
Molecular Weiqht, Dry, (Mrf)_
Meter Box Number f
Meter Coefficient^.
<* Factor l'<">:!'(
K *
K(N)
( _ )"
( P)
Leak Check: Initial at
F4M4 at
Pitot Leak Check:
" Hg, 0 (\S CFM
—
SASS Condensate
Total Volume
Gas Meter
Reading
-------
Page __ of
Traverse
Point
Number
•C.W,
;Jo
NS
\ Clock Time
\ (24-hr)
N. Clock
Sampling N.
Time, min \
7^-^
?b
lH*3 \ £0
^a \&
Ho
i^v, \ 9*7
>fs34 \<&
'05*
//r
Gas Meter
Reading
(»•>. « 3
Inlt. y,-^.{.<(/
Y^",'1
-^.^,7
~n.~^')
^5 • «S
r74.O, Oljx..
'J'^o.^lX
^b - i.c>
x/7 . WO
i
Velocity
Head
(AP5).
in. H20
0-1
oc\
0-7
c'J.7
o,7
c3,~/
Orifice Pressure
Differential
(AH), in. HjO
Desired
Actual
/ • ^
f>,<
\-"7
0,7
/•7
/. 0
M
Temperature °F
Stack
"T ' '(
"h
-;.;•-',
J ..-***"
r - x
'"> '">' ,'.v'
Probe
;/ft^-
Vfti
^^
'K^C)
'//f
-// !•
Impinger
-' ...
72L
7!
VJ
^
77
Organic
Module
^
6'^
?>.(-,
/v"
At.
^ ».««
^^
Oven
•A'JO
-''/
'f
-A');:
r>7
4f.^
Gas Heter
In
77
/{
73
'M
r/
?'7
Out
77
//
'/,::
-Y
7-7
^
Pump
Vacum
tn. Hg
-'/'(
.-^•/i^
••••/'i
^ -/JO
V'l
-•-//rl
•
Avg.
VST"
I
oo
Run Ha.
Coinnents:
Date
Sampling Location "
-------
SECTION 5
ANALYTICAL RESULTS
5.1 FUEL ANALYSIS
5.2 SASS PARTICIPATE EMISSIONS
5.3 EPA METHOD 5 PARTICIPATE EMISSIONS
5.4 EPA METHOD 8 ANALYSES (SULFUR OXIDES)
5.5 TRACE ELEMENT ANALYSES
5.6 Cj TO C6 HYDROCARBONS BY GAS CHROMATOGRAPHY
5.6.1 FROM JUNE 11, 1982
5.6.2 FROM JUNE 17, 1982
5.7 N20 BY GAS CHROMATOGRAPHY
5.8 TOTAL CHROMATOGRAPHABLE ORGANICS (TCD), GRAVIMETRIC ORGANICS (GRAV), IR
SPECTRA, GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS), LIQUID
CHROMATOGRAPHY (LC), AND LOW RESOLUTION MASS SPECTROMETRY (LRMS)
5.9 BIOASSAY REPORTS
5-1
-------
(This page intentionally blank.)
5-2
-------
5.1 FUEL ANALYSIS
5-3
-------
(This page intentionally blank.)
5-4
-------
September 10, 1982
Mr. Robert DeRosier
Project Engineer
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Dear Mr. DeRosier:
At your request, I am sending you four copies of the laboratory analyses for the
following samples:
1. Coal used during the coal-water mixture (CWM) test on June 17, 1982.
2. Fly ash (2) collected during the same test.
3. Furnace ash collected from the boiler after the test.
The CWM used on June 17 contained 59.4 percent dry coal, 0.5 percent Lomar D,
and the remainder was water.
Sincerely,
Dr. Y. S. Pan
Mechanical Engineer
Combustion Technology Branch
4 Enclosures
5-5
-------
Department of Energy
COAL-ANALYSIS REPORT
LAB HO
1.14787
ORGANIZATION: COKBUSTION TECHNOLOGY
SAKPLE ID: COK8 *UC2-4-27-12; 2*4 ASH Vft.
OPR:
STATE: -
TOIN: -
"COUHTY: . -
CAM HO: -
KIKE: -
BED:
DATE OF SAHPLIHG? 4-27-82
COLLECTOR: T. SROVH
DATE RECEIVED' 5-18-82 DATE OF REPORT: 6- 4-82;!
"•• COAL :
CAS RECD.3
V",, COAL
CKOIST FREE3
PROXIMATE ANALYSIS
HCISTURE '
VOLATILE HATTER
FIXED CARBOH
ASH
ULTIMATE AHALYSIS
HYDROGEN
CARBOH
NITROGEH
SULFUR
OXYCEH EIHD3
ASH
HEATIHG VALUEtBTU/LB3
HAJOR ELEKEHTS IH ASH
SILICA
AL2 03
FE2 03
TI 02
CA 0
rc o
KA2 0
K2 0
SULFITES
1.92
39.97
55.54
2.57
80
1
1
8
70
65
57
17
34
2.57
14544
33.88
32.97
18. 79
I .56
5.49
. 48
1.47
1 68
I . 36
H/A
40.76
56.62
2.62
5.60
82.23
1. 60
1. 19
6.76
2.62
14829
•'--^- COAL .-
CMOIST/ASH FREE! *
H/A
41 .85
58. 15
H/A
5.75
84.45
1 .65
1 .22
6.95
H/A
15228
5-6
-------
Department of Energy
COAL-ANALYSIS REPORT
.-
! *« m_4«^_'«_».IM •* *. ^ « J.. ^..te.^..^.^..^ ^ J» •- J*. M- • .« ^«_i.
5S=;
S3J
» ^^'^j^r^'"
lasssa-jx-a
LflB NO
LI 53 16
ORGANIZATION: COMBUSTION TECHNOLOGY
SAMPLE ID: COMB; *150-T5-C; FLYASH 700 HP
OPR:
STATE: -
TOUN: -
COUNTY:
CAN NO
MINE :
BED:
G
•El
s
ip
Cl
DATE OF SAMPLING: 6-17-82
COLLECTOR; T. BROUN
DATE RECEIVED
>ATE OF REPORT
7-14-32
to
ct
EftS
COAL
REDD,]
COAL
[KOIST FREE]
COAL
CHOIST/ASH FREE]
MOISTURE
ASH
3. 13
35. 58
N/A
36.73
N/ft
N/ft
i
HYOROGEH
CARBON
SULFUR
.73
53.25
.34
.40
. 13
.87
.63
95 .05
1 .37
»
act
S3
is
s
El
Ct
(t
a
Et
ti
!»
«
El
;;
*<
ti
LI
M
t«
r.i
El
5-7
-------
Department of Energy
COAL-ANALYSIS REPORT
ORGANIZATION: COMBUSTION TECHNOLOGY
SAMPLE ID: COMB; S150-70-C; FLYASH 700 HP
OPR: -
STATE: -
TOWN: -
COUNTY:
CAN NO: -
HIHE: -
BED:
A
DATE OF SAMPLING: 6-17-32 DATE RECEIVED: 7-12-82 DATE OF REPORT: 7-14-82
COLLECTOR: T. BROUN
COAL
CAS RECD.]
COAL COAL
CMOIST FREE1 CMOIST,ASH FREE] Jj
MOISTURE
ASH
3.27
32.92
N/A
34.03
N/A
H/A
HYDRO GEM
CARBON
SULFUR
.94
60.94
.81
.60
63.00
.84
.90
95.50
1.27
5-8
-------
Department of Energy
533
LAB NO.
L15825
ORGANIZATION: COMBUSTION TECHHOLOGY
SAMPLE ID: COMB; »ASH 6-22-1; FURNACE ASH 700 HP
CAN NO
OPR:
STATEJ -
TOWN:
COUHTY:
HIHE :
BED:
£
is
DATE OF SAMPLING: 6-17-82
COLLECTOR: T. BROUN
DATE RECEIVED: 7-12-32 DATE OF REPORT: 7-15-32
COAL
CAS RECD.]
COAL
CMOIST FREE]
COAL
[MOIST, ASH FREE]
MOISTURE
ASH
HYDROGEN
CARBON
SULFUR
1 . 34
54.53
I .90
35.23
2. 62
N/A
55.27
1.78
35.71
2.66
H/A
N/A
3.97
79 .84
5.95
IS
:tJ
p
in
tl
u
a
u
L1
LI
n
LI
u
LI
U
n
D
u
LI
u
u
11
»
!L!
te
IL.
X'
,i'
»*
n
5-9
-------
SOUTHERN DIVISION
4Oi Canal Street
Wilmington. CA BO748
213-54»674O
TWX 8IO 34S-682O
ANALYST WILN
LABORATORY CERTIFICATE
CURTIS & TOMPKINS, LTD.
ESTABLISHED 1878
Bulk OH & Chemical Surveyors. Samplers & Weighers
Analytical & Consulting Chemists
3^//
FOOD TECHNOLOGISTS
29O Division Street
San Francisco. CA 941O3
415-861-1863
Telex: 171042
CABLE: ANALYST SFO
ENVIRONMENTAL ANALYSTS
MEMBERS. OFFICIAL CHEMISTS
AND/OR SAMPLERS FOR GOVERNMENT
AGENCIES AND TRADE ORGANIZATIONS
Laboratory No. 8 2m 3 3
Preliminary No. 0684
Reported
Sampled
Received
11/3/82
10/26/82
For
ACUREX CORPORATION
Repon on
2 samples of Compost
Mark
1) Job #307735.41, Pele/DOF Date 6-17-82, Coal Water
2) Fuel Composite 2A + 2B, A82-04-043
Subcontract No. RB59186A, Release No. 4, Purchase Order
No. EM 93331A.
Carbon (C),%
Hydrogen (H),%
Oxygen (0) (by difference),%
Sulfur (S):
First Run,%
Second Run,%
Third Run,% —
Nitrogen (N) it
First Run,% --
Second Run,% • •
Third Run,%
Specific Gravity 60°F
Higher Heating Value:
BTU per Pound •
Moisture (as received),% -—-—
Specific Gravity (as received)
72°F/72°F
13.49
1.
1.
1,
1.
1.
1.
20
30
28
62
56
62
14,451
36.45
1.1655
5-10
SAMPLES DISCARDED 3O DAYS AFTER RECEIPT UNLESS OTHERWISE REQUESTED
-------
5.2 SASS PARTICJLATE EMISSIONS
5-11
-------
(This page intentionally blank.)
5-12
-------
Plant
Date
ISOKINETIC PERFORMANCE WORKSHEET & PARTICULATE CALCULATIONS
Performed by
Sample Location /Q?t
Test No./Type {_ — £ffi>^>
Barometric Pressure (in. Hg)
Meter volume (std),
^ /ttBA/teU.^X
\ (/-<>O / \ (7S-^) + 460 /
\ / \
Volume of liquid collected (grams)
Volume of liquid at standard condjtion (scf)
Vlc x 0.04707
Stack gas proportion of water vapor
V ^j + V_ ^.j.j (Vif J\J + S/'^J1'-/
wstd mstd "• — •"* • •" /
Molecular weight, stack gas dry
(Ib/lb-mole)
(% C02x 0.44) + (% 02x 0.32) + (% N2+ % CO x 0.28)
(/Sr-t>^ 0.44) + UoVx 0.32) + (t).'<>c'+ x 0.28)
Molecular weight, stack gas wet
(Ib/lb-mole)
Absolute stack pressure (in. Hg)
Pb ' 13.6 ' 21-i> + 13.6
pb
Vm std
Vlc
vw std
p
Md
Ms
Ps
^.^
•KM
^s-
^.^-
y ^^ Ni
'
7o.,rv
X-V
>*oi
5-13
Form 440 3/84
-------
Temperature stack gas, average (°F)
Stack velocity (fos)
n"savg + 460
3-« / / /^a^'^V^ ( *^Rf "7\
*J .X ' I\J VV«»/ ^» / \i?^^ '»
Total sample time (minutes)
Nozzle diameter, actual (inches)
Percent isokinetic (%)
17.33 (T + 460)(V,, std + Vm std)
S W fit
0 Vs Ps Nd2
17.33 (OV- 460)(f?^->T+ ^""-W
(/ J ^. i / / 1 t ^i 1 i ^''•^ ^^ k-^ 1 i *tl^ *^~t ™~^^
/ ' ^S / \Sn^* " ' • -£. / \ i^^ '5 t * iS, / \ j j ^^ /
Area of stack (ft2) T= 3.1416
ir r 2 -r- 1 44 , n ( /X)2-f-1 44
Stack gas volume at standard conditions (dscfm)
60 (1 - Bwo)Vs3vg A- / 528 \ / Ps \
60 (1 -y^3)Qc^.?-^/ 528 \ /$&$\
1 O<^" + 4607 \( 29.92)7
\
Particulate matter concentration, dry (gr/dscf)
15 432 MD(9rains) 15 /i?? f^^^i
Vm . , ( ^/^, *>»c)
Emission rate of participate matter (Ib/hr)
0.00857 (QJ Cc , 0.00857 KV^ )(«^C5^V )
(std)
TS
Vs(avg)
e
Nd
XI
AS
'.
r
^c
S(std)
E_
P
<&<
O-^
ii<
o- -^
^'C- V
S/v/<.
T*o^
y 3 / xx
-------
ACUREX
Corporation
ANALYSIS LABORATORIES
DATA REPORTING FORM
tn
I
i— '
cus-
cus
RESt
AC
TOMFR UT-" DATF
TOMER COf
JLTS REPOf
(DRESS „._
^TRACT NO
IT TO
307736.42
L. Waterland
ACUREX C(
TELEPHON
DNTRACT N
n A82-06-026
PETC-DOE
SAMPLE ID (CUSTOMER)
SAMPLE ID (LAB)
PAHAMtTEH
Weight
Probe
1.1798
15M
37.5322
10M
.
3.4069
3y
_ . — ___.
10.5965
Filter
rr-— -"-: •..-•_—.-
8.1185
-Tr--:---r-:=
^~^- '-1=^-
— — -— —---.
-T— —-- ^-^~ =
.: -i_u.^-^^^_-j
fram
FormEED-057 4 BO
ANALYST J. La bash
REVIEWER _G.
-------
(This page intentionally blank.)
5-16
-------
5.3 EPA METHOD 5 PARTICIPATE EMISSIONS
5-17
-------
(This page intentionally blank.)
5-18
-------
ISOKINETIC PERFORMANCE WORKSHEET & PARTICIPATE CALCULATIONS
Plant r.. r... />,.. ^ Performed by .• -•••- ^
Date ___^__jj_i_- _v
Sa-nple Location :'-L;
Test No./Type )•
Barometric Pressure (in
Meter volume (std),
17 64 1 -I- ll
• Hg)
«r-*v>*&\
\a/vm + 460/
13.6 j
;<;/-) + 460 /
/
Volume of liquid collected (grams)
Volume of liquid at standard condition (scf)
Vlc x 0.04707
Stack gas proportion of
Vw std
water vapor
vw std + vm std (i;^ * (^,
Molecular weight, stack
(Ib/lb-mole)
(X C02x 0.44) + (X 02x
( x 0.44) + ( x
Molecular weight, stack
(Ib/lb-mole)
Md(l-Bwo) + 18(BWO), (_
Absolute stack pressure
P /(in. H
p stack
'b 13.6
gas dry
0.32) + (X N2+ X CO x 0.28)
0.32) + (..'? + - x 0.28)
gas wet
(in. Hg)
2°) r ... (^1)
.. i '••'• • ' \ + _ _
» l_J + 13.6
s
Vm std
«e
vw std
wo
Md
Ms
Ps
">',"• i — J
U ~ --i,'"
Jc-? i
^ 1 ,*
,S34,
?v --:-,
3--J" Cff
x ,s"- H "{'
7602/5/81/Rev 1
5-19
-------
Temperature stack gas, average (°F)
velocity (fps)
avg + 460
85.49 (Cp) (V2Ps avg) 1^—MV
(-,-') + 460
~
Total sample time (minutes)
Nozzle diameter, actual (inches)
s(avg)
B
Percent isokinetic (%)
17.33 (T. + 460)(VW std + Vm std)
S W ill
0v^P^f^2
17.33 (£ii-i + 460)((T-^y) + (y?*&;
XI
Area of st?ck (ft2) ^= 3.1416
'
Stack gas volume at standard conditions (dscfm)
Wn-Bw^.vgS / 528 ^ ' "
vs av9 + / \^,
60
/5>Y) fes*;) QJ%)/ 528 \
I o/-r •*• 460;
Particulate matter concentration, dry (gr/dscf)
15.432 V9ra"*), 15.432 ( >
'(std)
Emission rate of particulate matter (Ib/hr)
C. 00857 (QJ Ce , t 0.00857 ('-,^3^ )(
'S' S
(std)
7602/5/81/Rev 1
5-20
-------
1SOKINETIC PERFORMANCE WORKSHEET & PARTICIPATE CALCULATIONS
Plant fgrC Ibo^ ____ Performed by f^ur4-vf4"
Date £ j fiT?-..
Sample Location Jco H-P fio^«-fef ,
Test No. /Type Si f*\
f
Barometric Pressure (In. Hg)
Meter volume (std),
"•«^b*^A
VaATm+460/
/Wte/)\ /«**)* (-^i)\
17 61 II 13** )
\(/£2.)/y^z.) + 46° /
Volume of liquid collected (grans)
Volume of liquid at standard condition (scf)
Vlc x 0.04707
Stack gas proportion of water vapor
Vw std . (2*&
\ std + vm std &®3 4 ^&&
Molecular weight, stack gas dry
(Ib/lb-raole)
(X C02x 0.44) + (X 02x 0.32) + (X N2+ X CO x 0.28)
(_il_ x °-445 * (-2L x 0-32^ * t83 * — * °-28)
Molecular weight, stack gas wet
(lb/lb-mole)
Mdd-B^J + 18(BWQ), (2*J(1-^2D * 18('/gy?)
Absolute stack pressure (in. Hg)
pstack 41fu H20) r . tH.}
« siacK ^ f^r-f}-) + , _,
'b 13.6 • v—-!—1 13.6
Pb
vm std
Vlc
vw std
Bwo
Md
Ms
Ps
>
SS"-^^
Bt'lW
\S~!,< ^~
"7-^5^
/ S". SI *?
-------
Temperature stack gas, average (°F)
Stack velocity (fps)
85.49 (Cp) (V2PS flvg)
/avg + 460
s Ms
460
Total sample time (minutes)
s(avg)
0
Nozzle diameter, actual (inches)
Percent 1 so-kinetic (X)
17.33 (T$ + 460)(VW std
std)
XI
17.33
Area of st?ck (ft2) »« 3.1416
»r 2 -i- 1 44 . ir (__ _ iz^r-l 44
/- _ .
Stack gas volume at standard conditions (dscfm)
60 (1 - Bwo)Vsavg A. / 528 '
\savg + / v07
60
528
SCflt-O
Particulate matter concentration, dry (gr/dscf)
15.432 V9rams). 15.432
'(std)
Emission rate of particulate matter (Ib/hr)
0.00857 (QJ C, , , 0.00857 (
)(
7602/5/81/Rev 1
5-22
-------
ACUREX
ANALYTICAL REPORT
Sample of:
Sample nate- (clip - £/// Jl -
Requested By c
I.D. Number:
/ & . & .a
Analytical Method:
Date of Analysis:
-------
(This page intentionally blank.)
5-24
-------
5.4 EPA METHOD 8 ANALYSES (SULFUR OXIDES)
5-25
-------
(This page intentionally blank.)
5-26
-------
ACUREX
ANALYTICAL REPORT
Sample of:
Sample Pat*-
- fef
Requested By: t • /-<
I.D. Number:
Analytical Method:
Date of Analysis:
a/ Zffl 6'/S'
Form EED 082 5/31
-------
5-28
-------
5.5 TRACE ELEMENT ANALYSIS
5-29
-------
(This page intentionally blank.)
5-30
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919SOUTH HIGHLAND AVE..SUITE210-B, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION. 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
TO! R. Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
P. O. NO.:
REVISED
Date: December 3, 1982
Analyst: G> Meagner
Sample No.: 815223
PETC Fuel
SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
CONCENTRATION IN PPM WEIGHT
IAD No.:
97_K776_ii6-li
ELEMENT
Uranium
Thori urn
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rheni urn
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
CONC.
0.5
0.5
0.03
2
0.2
NR
0.1
0.1
^0.3
0.01
0.1
£0.02
0.1
0.1
0.2
ELEMENT
Terbi urn
Gadolinium
Europium
Samarium
Neodymium
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi urn
Si 1 ver
Palladium
Rhodi urn
CONC.
0.06
0.2
0.07
0.3
0.6
0.3
1
2
25
0.2
0.2
0.2
0.4
0.04
STD
£0.04
0.2
ELEMENT
Ruthenium
Molybdenum
Ni obi urn
Zirconium
Yttri urn
Strontium
Rubidium _
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
Note: Sample thermally ashed @
CONC.
1
0.5
2
4
34
0.2
1
0.3
1
0.5
2
2
3
2
1
MC
2
2
450°C
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
3
63
0.3
MC
MC
3
MC
37
MC
>53
MC
>14
=5
NR
NR
NR
0.5
0.4
0.7
NR
STD — Internal Standard
NR - Not Reported
All elements not detected< 0.01 ppm
MC - Major Component >100 ppm
INT — Interference
for =2 hrs. prior to analyses
Approved:
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-8, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9S21
To: Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue °™c"""
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
P. O. No.:
Sample No.: Parr Bomb Blanj[pARK SOURCE ^55 SPECTROGRAPHIC ANALYSIS
CONCENTRATION IN yC|/ml
Date:
November 16, 1982
Analyst: G- Meagher
IA° N°-: 97-K776-116-11
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thai 1 i um
Mercury
Gold
Platinum
Iridium
Osmi um
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europium
<0.02 Samarium
Neodymi um
NR Praseodymium
Cerium
Lanthanum
Barium 0.09
Cesium
Iodine
Tellurium
*°«7 Antimony
Tin
Indium STD
Cadmi um
Silver
Palladium
Rhodi um
* Possible contamination
ELEMENT
Ruthenium
Molybdenum
Ni obi um
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
CONC. ELEMENT
Vanadium
0.04 Titanium
<0.01 Scandium
0.03 Calcium
<0.002 Potassium
0.008 Chlorine
<.0.002 sulfur
0.03 Phosphorus
Silicon
0.003 Aluminum
Magnesium
0-02 Sodium
0-2 Fluorine
0.06 Oxygen
O-02 Nitrogen
±0.005 carbon
0.2 Boron
0.007 Beryllium
Chromi um 0. 01 |_i ttn um
from the source.
Hydrogen
CONC.
0.006
0.3
<0.004
3
0.4
0.8
0.05
<0.01
0.5
0.02
0.1
0.3
=0.1
NR
NR
NR
0.007
0.005
NR
STD — Internal Standard
NR - Not Reported
All elements not detected< 0.003
MC - Major Component > 10 pg/ITll
INT — Interference
5-
32 ( ) 0 >J? 21 /?
Approved: N^VvM*--* \s* • (^~jl<**J6\s\
I 9 M , '&? S\
I / Pw o»/ 5 c^ \^_j
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERALOFFICES: 1919SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 6014B AREA CODE 312953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
To: Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue »••««••<••
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
p. o. No.:
Sample No.: A82-06-026-8 spARK SOURCE ^55 SPECTROGRAPHIC ANALYSIS
CONCENTRATION IN PPM WEIGHT
Date:
November 16, 1982
Analyst: G- Meagher
IAD No.: 97-K776-116-11
ELEMENT CONC.
Uranium
Thorium
Bi smuth
Lead 0.1
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum *1
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium *
STD — Internal Standard
NR - Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
ELEMENT CONC. ELEMENT
Terbi urn
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Ceri urn
Lanthanum
Bari urn
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodi urn
Ruthenium
Molybdenum
Niobium
Zirconium
0.07 Yttrium
0.3 Strontium
0.6 Rubidium
0.9 Bromine
1 Selenium
0.01 Arsenic
0.1 Germanium
Gallium
Zinc
Copper
STD Nickel
Cobal t
0.1 Iron
Manganese
Chromi urn
CONC.
0.6
0.9
0.04
0.3
<0.01
0.2
0.06
<0.01
0.3
1
0.4
0.6
0.05
22
0.2
0.4
Possible contamination from the source.
0.01 ppm
100 ppm
5-33 C)
Approved: \£*£
U^
l 9 M
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
€(^L
w rz-ci
CONC.
0.04
0.8
0.03
18
8
4
6
0.5
5
0.5
3
2
*" 1
NR
NR
NR
0.03
0.02
NR
2U
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919SOUTH HIGHLAND AVE., SUITE 210-8, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490ORCHARD STREET, GOLDEN, COLORADO «M01, PHONE: 303 278-9521
To: Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Subcontract ISW59159A
Release #8
P. O. NO.:
SiNCf HOB
Sample
SPARK SOURCE AAASS SPECTROGRAPHC ANALYSIS
CONCENTRATION IN PPM WEIGHT
Date-. November 16, 1982
Analyst: G. Meagher
IA° N°-= 97-K776-116-11
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thai 1 i urn
Mercury
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thul i urn
Erbium
Hoi mi urn
Dysprosium
CONC. ELEMENT CONC.
Terbium
Gadolinium
Europium
0.07 Samarium
Neodymi urn
NR Praseodymi urn
Cerium
Lanthanum
Barium 0.7
Cesium <0.01
Iodine <0.01
Tellurium
*2 Antimony
Tin 0.09
Indium STD
Cadmium
Silver 0.02
Palladium
Rhodi urn
* Possible contamination
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromi urn
CONC.
0.06
<0.01
0.3
0.4
<0.01
0.06
<0.01
0.1
0.3
0.3
0.2
<0.01
3
0.03
0.1
from the source.
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC.
<0.01
0.2
<0.01
17
2
1
2
<0.02
4
0.1
0.5
0.9
=0.2
NR
NR
NR
<0.01
<0.01
NR
STO — Internal Standard
NR - Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
/ 9 N
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-8, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
TO: R. Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Subcontract ISW59159A
Release #8
P. o. No.:
4-h
as
Date:
November 12, 1982
Sample
Analyst: G- Meagher
&ARK SOURCE MASS SPECTROGRAPHIC ANALYSIS "AD No.: 97-K776-116-11
>n
CONCENTRATION IN PPM WEIGHT
ELEMENT
Uranium
Thori um
Bi smuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
r
Lutetium
Ytterbium
Thul i um
Erbium
Holmium
CONC
16
31
150
NR
9
15
4
2
6
0.3
4
6
Dysprosium 9
STD — Internal Standard
NR - Not Reported
All elements not detected <
AAC — Major Component >
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymi um
Praseodymi um
Cerium
Lanthanum
Ban" um
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi um
Silver
Palladium
Rhodi um
CONC.
3
5
2
17
16
21
85
75
MC
3
4
1
11
1
STD
6
<0.6
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromi um
CONC.
20
19
230
79
MC
39
35
15
30
4
15
*88
110
30
14
MC
92
170
* Heterogeneous
5-35 /O |
0.2 ppm Approved: VY-trA/--*^
1000 ppm , <3 K
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesi um
Sodi um
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
£.<^fc*+A
l^J
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION. 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
T0. Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue *'""""
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
P. O. No.:
Sample No.: A82-06-026 SpAR|< SOURCE ^55 SPECTROGRAPHIC ANALYSIS
PETC 3 urn + filter
CONCENTRATION IN PPM WEIGHT
Date- NoveRlber 16> 1982
Analyst: 6- Meagher
IAD No.= 97-K776-116-11
ELEMENT
Uranium
Thori urn
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
CONC.
8
9
2
77
6
NR
3
4
0.8
0.6
3
0.4
1
2
Dysprosium 3
STD — Internal Standard
NR - Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymi urn
Cerium
Lanthanum
Bari urn
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi urn
Silver
Palladium
Rhodium
0.1 ppm
1000 ppm
0.6
2
1
5
6
6
61
54
MC
0.3
3
0.4
18
6
STD
3
4
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromi urn
5-36 /O
Approved: \g^<$
CONC.
26
9
45
120
MC
18
30
29
440
53
430
73
710
480
270
MC
>530
170
iJt
I 9
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryl 1 i urn
Lithium
Hydrogen
--P ^
AA- '(^/b+A
A/.fct &-iLt
CONC.
400
MC
61
MC
MC
MC
>330
MC
MC
MC
HC
MC
= 180
NR
NR
NR
120
4
74
NR
^
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHIAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
To: Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
^^^^9p|^L
^^^^^nRW^^k
SiNCC i»OB
Subcontract ISW59159A
Release #8
P. O. NO.:
Sample No.: 815237
PETC Imp.l
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead 0.02
Thai 1 i um
Mercury ^R
Gold
Platinum
Iridium
Osmi um
Rheni um
Tungsten
Tantalum °-02
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
STD — Internal Standard
NR — Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
SPARK SOURCE MASS SPECTROGRAPHIC
CONCENTRATION IN yg/ml
ELEMENT CONC. ELEMENT
Terbi um
Gadolinium
Europium
Samarium
Neodymi um
Praseodymium
Cerium
Lanthanum
Bari um
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi um
Silver
Palladium
Rhodium
0.002 yg/ml
10 yg/ml
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri um
Strontium
Rubidium
Bromine
0.06 Selenium
Arsenic
0.004 Germanium
0.009 Gallium
0.009 zinc
0.03 Copper
STD Nickel
Cobalt
0.01 iron
Manganese
Chromium
5-37 S~
Approved: \£-
Date: N°ve™
Analyst: S.
3er 16, 1982
Meagher
ANALYSIS IAD No-: 97-K776-116-11
CONC. ELEMENT
Vanadium
0.3 Titanium
0.01 Scandium
Calcium
0.02 Potassium
0-04 Chlorine
0.02 sulfur
0.09 Phosphorus
0.2 Silicon
0.002 Aluminum
0.002 Magnesium
0-03 Sodium
0.4 Fluorine
0.2 Oxygen
1 Ni trogen
0.05 Carbon
MC Boron
0.9 Beryllium
0-3 Lithium
Hydrogen
isi^Jr^. (^^\
CONC.
0.02
0.1
0.04
1
1
0.04
MC
0.2
1
0.1
0.3
>7
-1
NR
NR
NR
0.01
0.002
NR
0*
I
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-8. LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
zk
To: Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue "•""
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
P. O. NO.:
Sample No.: 815541 SPARK SOURCE AAASS SPECTROGRAPHIC
PETC Imp. 1 Blank
CONCENTRATION IN
Date: November 16, 1982
Analyst: S. Meagher
ANALYSIS IADNO..-97-K776-116-11
ELEMENT CONC.
Uranium
Thori urn
Bismuth
Lead 0.1
Thai 1 i urn
Mercury NR
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum 0.3
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
STD — Internal Standard
NR - Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
ELEMENT
Terbi urn
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymi urn
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmi urn
Silver
Palladium
Rhodi urn
0.002 yg/ml
10 yg/ml
CONC. ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
0.002 Strontium
0.003 Rubidium
0.008 Bromine
0.08 Selenium
Arsenic
0.008 Germanium
0.009 Gallium
Zinc
Copper
STD Nickel
Cobalt
10.05 Iron
Manganese
Chromium
5-38 s~J
Approved: \^(L-tJ
CONC. ELEMENT
Vanadium
0.05 Titanium
0.002 Scandium
0.02 Calcium
0.001 Potassium
0.005 Chlorine
<0.001 Sulfur
0.02 Phosphorus
0.004 Silicon
Aluminum
Magnesium
0.005 Sodium
0.05 Fluorine
0.02 Oxygen
0.01 Nitrogen
0.002 Carbon
0.2 Boron
0.002 Beryllium
0.009 Lithium
Hydrogen
•C^jt u- C2**\
I 0 A,
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490 ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
To: R- Schroeder
Acurex Corporation
485 Clyde Avenue "~cr'°' Date. November 12, 1982
Mountain View, CA 94042
Subcontract ISW59159A r M .
Release #8 Ana|yst: G" Mea9ner
P. O. No.:
Sample No: A82-06-026-16 SPARK SOURCE ^55 SPECTROGRAPHIC ANALYSIS "A& No.: 97- K776-116-11
PETC Bottom Ash
CONCENTRATION IN PPM WEIGHT
ELEMENT
Uranium
Thorium
Bi smuth
Lead
Thai 1 i urn
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thul i urn
Erbium
Hoi mi urn
Dysprosium
CONC.
18
22
3
MC
7
NR
9
8
5
0.8
4
0.2
4
5
8
STD — Internal Standard
NR - Not Reported
All elements not detected <
MC — Major Component >
INT — Interference
ELEMENT
Terbi urn
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymi urn
Cerium
Lanthanum
Barium
Cesium
Iodine
Tel 1 uri urn
Antimony
Tin
Indium
Cadmi urn
Silver
Palladium
Rhodi urn
0.2 ppm
1000 ppm
CONC.
2
5
1
9
23
11
120
93
MC
1
4
1
21
41
STD
9
I3
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromi urn
5-39 /"
Approved: \Jf-
CONC.
57
35
130
270
MC
39
8
11
110
5
45
MC
270
190
21
MC
MC
620
? .
frAM^C^
\9 fu*
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryl 1 i urn
Lithium
Hydrogen
*nh)
CONC.
MC
MC
47
MC
MC
110
MC
MC
MC
MC
MC
MC
=71
NR
NR
NR
54
7
38
NR
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES: 1919SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, ILLINOIS 60148 AREA CODE 312 953-9300
INSTRUMENTAL ANALYSIS DIVISION, 490ORCHARD STREET, GOLDEN, COLORADO 80401, PHONE: 303 278-9521
TO: R- Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Subcontract #SW59159A
Release #8
P. O. NO.:
Sample No.= A82-06-026-17 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
PETC Baghouse Ash
CONCENTRATION IN PPM WEIGHT
Date. November 12, 1982
Analyst: G. Meagher
IAD No-: 97-K776-116-11
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
CONC.
19
42
0.8
450
3
NR
12
*100
2
1
6
0.3
3
4
Dysprosium 6
STD — Internal Standard
NR - Not Reported
All element* not detected <
MC — Major Component >
INT — Interference
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium
Lanthanum
Ban' urn
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodi urn
CONC.
2
7
4
21
55
51
140
200
MC
2
5
0.6
13
9
STD
4
<2
* Heterogeneous
0.2 ppm
1000 ppra
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
5-40 s~\
Approved: VjU<&-
i
CONC.
28
51
160
320
MC
21
85
44
100
22
160
160
330
60
190
MC
500
230
6 /^ —
t^AT%
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
f^/2^
x^ ^^>
CONC.
MC
MC
32
MC
MC
620
MC -
MC
MC
MC
MC
MC
=86
NR
NR
NR
51
16
35
NR
<«-
-------
COMMERCIAL TESTING & ENGINEERING CO.
SINCE 19O8
Reply to
Instrumental Analysis Division ,,„ ,,„„ o, 100- Phone:303-278-9521
490 Orchard Street January 21, 1983
Golden, CO 80401
Mr. R. Schroeder
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Re: IAD #97-K914-116-07
Subcontract #SW 59159A
Release #8
Analytical Report
Eleven (11) samples were received for analysis on October 28, 1982. These
samples were assigned our IAD identification I97-K776-116-11 and were analyzed
by spark source mass spectrometry (SSMS) for trace elements. Analytical reports
were mailed on November 12, 1982.
Per the request of Mr. Larry Waterland of Acurex Corporation, elements
found to be major components were to be quantified by other analytical methods.
Seven (7) of the samples were relogged and reassigned our IAD identification
#97-K914-116-07.
Except for Phosphorus and Sulfur, all elements were determined by flame
atomic absorption/emission spectrophotometry. Phosphorus was determined
colorimetrically. Sulfur was determined turbidimetrically except for sample
#815223 where X-ray fluorescence spectrometry was used.
The results of these determinations are presented in Table No. I and
Table No. II and are reported in weight per cent (wt.%) on an "as received"
basis except as noted.
5-41
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-8, LOMBARD, IL 60148 AREA CODE 312 953-9300
BALTIMORE, MO • BILLINGS. MT • BIRMINGHAM, AL • BYESVILLE, OH • CHARLESTON, WV . CLARKSBURG, VW . CLEVELAND,OH . CONNEAUT.OH
DENVER, CO • GOLDEN, CO • HELPER. UT . HENDERSON. KY . HOUSTON. TX • JASPER, AL • MIODLESBORO, KY . MOBILE. AL • NEW BETHLEHEM, PA
NEW ORLEANS. LA > NORFOLK, VA • PALISADE, CO • PIKEVILLE, KY > SALINA. UT • SO. HOLLAND. IL • TOLEDO. OH • NO. VANCOUVER. B.C. CAN.
-------
Page 2
K914-116-07
Table No. I
(Concentrations in Wt%)
Parameter
Sodium
Magnesium
Aluminum
Si 1i con
Phosphorus
Sulfur
Potassium
Calcium
Titanium
Vanadium
Iron
Strontium
Barium
Manganese
Lead
Zinc
A82-06-026-17
Baghouse Ash
1.16
0.19
4.30
6.30
0.23
0.25
0.83
<0.5
<0.3
3.61
0.03
<0.10
A82-06-026-16
Bottom Ash
1.33
0.28
6.07
10.43
0.60
0.50
T.42
<0.4
<0.3
4.35
0.03
<0.10
0.05
0.52
0.46
A32-06-026-4&5
PETC 10+15ym Ash
0.82
0.12
3.13
6.06
0.16
_
0.21
0.44
2.41
0.01
<0.10
A82-06-026-3A&B
PETC 3um •»• Filter
37-46
0.45
7.33
12.37
0.28
_
0.45
2.38
<0.7
4.05
0.03
0.16
5-42
COMMERCIAL TESTING & ENGINEERING CO.
Original Copy Watermarked
For Your Protection
F-466
-------
Page 3
K914-116-07
Table No. II
(Concentrations in Wt.
Parameter
Sodium
Iron
Aluminum
Silicon
Potassium
Calcium
Nickel
Vanadium
Sulfur
815223
PETC Fuel
0.01
0.07
815237
PETC Imp. 1
0.003
34
92
1.03
3.81
0.44
If you have any questions concerning these results, please call.
Harold A. Connell
Asst. Lab Supervisor
cl
IT. L. Taylor, Ph.D., Mrtfr.
Instrumental Analysis Div.
5-43
COMMERCIAL TESTING & ENGINEERING CO.
rigmal Copy Watermarked
For Your Protection
•465
-------
COMMERCIAL TESTING & ENGINEERING CO.
Reply to
Instrumental Analysis Division
490 Orchard Street
Golden, CO 80401
Mr. Larry Water land
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
RE: IAD #97-1494-116-01
Subcontract ISW59159A
Release #8
Phone: 303-278-9521
March 31, 1983
Analytical Report
One sample, originally received for analysis on October 28, 1982,
was re-logged on March 16, 1983. This sample, previously assigned our IAD
identification #97-K776-116-ll, was re-assigned #97-1494-116-01.
Per the telephone conversation between Mr. Water! and of Acurex Corporation
and Mr. Wilson of our IAD laboratory, the sample was analyzed for Chlorine.
An accurately weighed portion of the sample was fused with sodium hydroxide.
The fusion melt was put in solution using sulfuric acid and then diluted to an
appropriate volume using deionized water. The resulting solution was analyzed
for Chlorine by selective ion electrode methodology.
The result of this determination is presented in Table No. I and is
reported in micrograms per gram (vg/g) on an "as received" basis.
Table No. I
( yg/g-As Received )
Sample I.D.
A82-06-026-3A & B
PETC 3 ym + filter
Chlorine
8,400 (0.84%)
If you have any questions concerning this. result, please call.
Harold A. Connell
Assistant Lab Manager
Robert L. TaytxTr, PhMT., Mngr.
Instrumental Analys-is^Div.
5-44
GENERAL OFFICES: 1919 SOUTH HIGHLAND AVE., SUITE 210-B, LOMBARD, IL 60148 AREA CODE 312 953-9300
BALTIMORE. MO . BILLINGS. MT . BIRMINGHAM. AL • BYESVILLE. OH . CHARLESTON. WV . CLARKSBURG. WV . CLEVELAND, OH . CONNEAUT OH
DENVER, CO > GOLDEN. CO • HELPER, UT . HENDERSON. KV • HOUSTON. TX . JASPER, AL • MIODLES8ORO. KV > MOBILE, AL • NEW BETHLEHEM PA
NEW ORLEANS. LA • NORFOLK. VA . PALISADE. CO • PIKEVILLE. KY . SALINA. UT • SO. HOLLAND. IL • TOLEDO.OH .NO. VANCOUVER 8.C CAN
,_;-'«»>«•
. W.S-&.
•j//,\-~lr
'*s!fr
/ttS:/l\ii
s;ii i /.-.!«n
i".i, —ja
-------
ACUREX.
Corporation
ANALYSIS LABORATORIES
DATA REPORTING FORM
CUSTOMER
CMEA
307736.42
CUSTOMER CONTRACT NO.
RESULTS REPORT TO I. Waterland
ADDRESS
DATE —
ACUREX CONTRACT NO. _A82-06-026. -10-025
TELEPHONE
PETC-DOE
SAMPLE IO (CUSTOMER)
SAMPLE 10 (LAB)
PAHAMtltH
Mercury Aliquot
Mercury Blank Aliquot
Mercury
Arsenic Aliquot
Arsenic Blank Aliquot
Arsenic
Antimony Aliquot
Antimony Blank Aliquot
Antimony
Fuel
6
<0.05*
<1
<0.05*
__
__
--
--
__
--
1632a**
NBS Coal
12
0.09*
<1
0.09*
__
—
--
--
__
--
9
15u+10u
4
0.23*
<1
9.4
-_
--
—
--
__
--
3u+Filter
1
0.85*
<1
16
_.
--
--
—
_-
--
XAD
8
<0.03*
<0.03*
<4
__
--
--
—
__
--
Imp 1
15
5
<3
8
__
--
--
--
—
--
Imp 2+3
9
<3
<3
<3
<3
<2
<3
<6
<1
<6
Bottom
Ash
16
<2
<1
<2
__
--
--
__
__
__
Baghouse
Ash
17
0.55*
<1
0.55*
__
-_
._
__
_ w
__
U9/L
ug/L
pg/train
JJ9/L
yg/L
yg/train
*•
ug/L
yg/L
yg/train
01
-pi
*Um"ts are mg/kg
**True value is 0.13 mg/kg
ANALYST
J. Labash
FormEED-057 4/60
REVIEWER
G. Nicoll
-------
(This page intentionally blank.)
5-46
-------
5.6 GI TO C6 HYDROCARBONS BY GAS CHROMATOGRAPHY
5-47
-------
(This page intentionally blank.)
5-48
-------
5.6.1 FROM JUNE 11, 1982
5-49
-------
(This page intentionally blank.)
5-50
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client
, U
o€ » Location
. Job No.
, Time
Injection Date
Recorder/Printout Reference No. /_
Purpose of Run
•'/$, Instrument ID_
, Recorder ID
Sample Description & / c^J & 6-
Amount Injected
GC CONDITIONS
_, Inj. Port or Sample Loop Used
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Detector Attenuation Z. , Amplifier or Range /<£ *" /& "x/
Column: Liquid Phase , Soflid Phase fiJS&/)*c]z Q ,
' , 1.0.
, Material 55
Length Q • t O.D. _
Temperature: Injector ftp °C, Oven I&O ° C. Detector
Temperature Program /
•SAMPLE RUN.
Sampling Method g//r#(-t
RT
Area
Peak Height
Amount ( )
Component
O,1
C,
0-
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/toy
Cr
2T3/2.
Name of Operator
ffAfi-K
, Date ,
19
5-51
-------
GAS CHROMA!. .APH OPERATING CONDITIONS AND FIELD LOG
Client ferc. /W . Location //rr£/gfr/e.6-. Job No.
Injection Date
f2. , Time
Recorder/Printout Reference No. £_
Purpose of Run f, -i^l CsJ/^ff,-//^
, Instrument ID_
, Recorder ID
Sample Description (S_/_
6C CONDITIONS
Amount Injected Z.£C , Inj. Port or Sample Loop Used
Detector Used: FID if , ECD , FPO , TCD (Current
Detector Attenuation 1 , Amplifier or Range /£* /0~tl
Column: Liquid Phase
Length 6 ': , O.D.
Temperature: Injector /1O°C, Oven /^° ?r-(.f
Area
Peak Height
Amount ( )
Component
c,'
7f /7
££.
i
Name of Operator
, Date
19
5-52
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client r~Tc. . //?*-. Location in-TrS/git/*•*-* Job No.
Injection Date &'f/'&2 . Time ^ffv£?//3. Instrument ID_
Recorder/Printout Reference No. 3 , Recorder ID _
Purpose of Run •+-' '*-*>
Sample Description
C'«/ #6-V2$
GC CONDITIONS
, inj. Port or Sample Loop Used
Amount Injected £ ci
Detector Used: FID _£_, ECO , FPD , TCO (Current
Detector Attenuation 'Z. , Amplifier or Range &*fO~r'
)
Column: Liquid Phase , Solid Phase/#/••*/
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client r^TTs. .£W". Location &rr!>£4/tZ * Job No.
Injection Date o-//" c-xj.
Sample Description CzJ C"~/
GC CONDITIONS
C1 • /
Amount Injected <+•£-*•... , Inj. Port or Sample Loop Used £j
Detector Used: FID y . ECO t FPD , TCO (Current )
Detector Attenuation 'Z, t Amplifier or Range /6?^fO"f/
Column: Liquid Phase , Solid Phase jQerg££*.$£ Q ,
Length
, O.D. '{*•
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Temperature: Injector 10.0 ° ', Oven / ^O ° C, Detector ?SO j
Temperature Program /5n
Area
?
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOS
Client
. Location nrrsjtt/tb. . Oob No.
Injection Date '//'#2 . Time /y>'j7/A5. Instrument ID_
Recorder/Printout Reference No. _ -? , Recorder ID
Purpose of Run S^kc £ ^5 5•? -**?*?///? ^
Sample Description ays? /f c^.
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SC CONDITIONS
, Inj. Port or Sample Loop Used
Amount Injected
Detector Used: FID JC_, ECD _ , FPD _ , TCD _ (Current
Detector Attenuation ?„ _ , Amplifier or Range j ^ ""
Column: Liquid Phase
Len9th ^ f • °-- '/ ? ''
, Solid Phase &&/&.<£
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Area
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Cz
Name of Operator
• Date , /c//?£- /T-19
•f—:jja--s— •
5-55
-------
GAS CHROMA:. ,APH OPERATING CONDITIONS AND FIELD LOG
Client
V, Location
. Job No.
Injection Date Q "ff'^L . Time f/iff: 3 6 . Instrument ID_
Recorder/Printout Reference No. 6 , Recorder ID __
Purpose of Run s-^-^g C*J
Sample Description
jT
GC CONDITIONS
, Inj. Port or Sample Loop Used
Amount Injected ^____
Detector Used: FID£ , ECO , FPD , TCD (Current
Detector Attenuation *3L , Amplifier or Range /$<
Column: Liquid Phase , Solid
^ «iMIHHB^^>^i^«IIIIIHIHBI^^^^HHM^^HBBiaiai^H^NB
Length 6 ' , O.p. f^ff . I.D.
/g Q .
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Temperature: Injector _/20__°ct Oven (%G °^ , Detector
Temperature Program /so
SAMPLE RUN.
Sampling Method
()
RT
//*» ,- «0
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Area
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<^250
Peak Height
»
Amount ( )
Component
C,'
Ci
Name of Operator
, Date
//. 19
5-56
-------
GAS CHROMAT. APH OPERATING CONDITIONS AND FIELD LOG
Client
£
, Location //rrj .
* /_.
•SAMPLE RUfJ
Sampling Method
• r RT
^/•*vj
^,K
0
-------
GAS CHROMA:. APH OPERATING CONDITIONS AND FIELD LOG
Client
,
' , O.p.
Q ,
, I.D.
, Material
Length _ £p
Temperature: Injector /2o °Ct Oven ffOQ C, Detector _?_
Temperature Program /Jo/X^/^yyi &J
•SAMPLE RUN.
Sampling Method
' JX ^
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0,71
fj, 2,?
Area
r$&0
V8%
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Peak Height
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Name of Operator
(WtS , Date 7
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client
/I ~ /;
Cvc » Location ir.-rr; /?»? x? •?
-
GC CONDITIONS
Amount Injected '/-C< , Inj. Port or Sample Loop Used
Detector Used: FID £_, ECO , FPD , TCO (Current
Detector Attenuation 2-. t Amplifier or Range _
, Solid Phase /
, I.D.
, Material
Column: Liquid Phase __
Length ^ O.D.
Temperature: Injector /2cP^ t Oven f ?Q ° C, Detector
Temperature Program
r£ Q .
Sampling Method
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5AMPLE RUN
. JIT
^ /*£
3<1£>
a. 7*1
Area
'55V
<££
Peak Height
•
Amount { )
Component
c;
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Name of Operator
frfif
5-59
, Date
-------
GAS CHROMAT. APH OPERATING CONDITIONS AND FIELD LOG
s*\ j
Client A^Ti lii-^'~'t Location
. Job No.
Injection Date 6~ff~£2. . Time /&2? / ?£ . Instrument ID_
Recorder/Printout Reference No. /Q , Recorder ID ___
Purpose of Run S^"< ,**<^-~ f
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0.£Q
Area
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Peak Height
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Amount { )
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C,
G.
Name of Operator
. Date .J.MAf If 19
5-60
-------
GAS CHROMAT. APH OPERATING CONDITIONS AND FIELD LOG
Client T^'~T"~ . 'Jcf. . Location rrr:/?^^^ . Job No.
Injection Date n~f/-!>2 . Time /ZtfelOX. Instrument ID
Recorder/Printout Reference No. //
Purpose of Run (_// -£$ -/*$ /.:*/•
, Recorder ID
Sample Description ,^,/ c •„ /
Amount Injected
GC CONDITIONS
, Inj. Port or Sample Loop Used
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Detector Used: FID <* . ECO , FPD , TCO (Current
Detector Attenuation "2L , Amplifier or Range /•£ ;<
Column: Liquid Phase
Length 6 /
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.. O.p. ffa".. I.D. , Material _$$
Temperature: Injector y2£ °C t Oven
Temperature Program /
C , Detector .
C
5AMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
r,
7X0 to
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Name of Operator
I /A-ft? if
fffflj
Date
5-61
-------
GAS CHROMA! APH OPERATING CONDITIONS AND FIELD LOG
F r n
Client .rtrc i/'3?._ , Location rttSW? . Job No.
Injection Date 6'/:-22. . Time /^/xrP/fff Instrument ID_
Recorder/Printout Reference No. 12- » Recorder ID
^,-~ ^ M-.-II— -r-ii.r--r-.vn __ .M
Purpose of Run --~ /__
. e w
Sample Description C*L cm.
GC CONDITIONS
^""^ j
Amount Injected ^ £^ , Inj. Port or Sample Loop Used (-00f*
Detector Used: FID '< , ECD , FPD , TCD (Current )
Detector Attenuation ,2- , Amplifier or Range /a ^//)~"
Column: Liquid Phase , Solid Phase fted/WC£ Q ,
Length £ ' O.D. 'fo" . I.D. t Material
Temperature: Injector ,/2£ °d. Oven f&O °<^t Detector
Temperature Program /So T,
•SAMPLE RUN.
Sampling Method D/#*rr7 //t/7g-CT/£/v
RT
Area
Peak Height
Amount { )
Component
c,
M/Z
C
£.0%
Name of Operator
Date 3!**&// 19
5-62
-------
5.6.2 FROM JUNE 17, 1982
5-63
-------
(This page intentionally blank.)
5-64
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client
. Location
r!TK &?# 6 .
Job No.
Injection Date 6-/9-/, 6m •//
_, Instrument ID_
, Recorder ID
Sample Description
c*,/ ?r= £ -
-------
GAS CHROMA!. .APH OPERATING CONDITIONS AND FIELD LOG
Client
. Location
t Job No-
Injection Date
. Time
Recorder/Printout Reference No. 2.
Purpose of Run £•' - £*> ^ /'"
Instrument ID_
, Recorder ID ___
Sample Description
<$ - t-fl
Amount Injected ',
GC CONDITIONS
, Inj. Port or Sample Loop Used
Detector Used: FID /f , ECD _ , FPD _ , TCD _ (Current
Detector Attenuation '"Z- » Amplifier or Range
Column: Liquid Phase _ , Solid Phase
Len9th
-------
GAS CHROMA:. ,APH OPERATING CONDITIONS AND FIELD LOG
Client ftrc ,/W . Location f'tftlfib/jis . Job No.
Injection Date £'f7*&~L. . Time /) -'^/:(tf. Instrument I0_
Recorder/Printout Reference No. _^ , Recorder ID
Purpose of Run 5^r.4 -c^x;
Sample Description
/ &*** &s //*.<<)?*( L
c_c
GC CONDITIONS
Inj. Port or Sample Loop Used
Amount Injected
Detector Used: FID AT . ECD _ , FPD _ , TCD _ (Current
Detector Attenuation "2- Amplifier or Range
Column: Liquid Phase
Length /< ' O.p. '/gft I.D.
t Solid Phase
Temperature: Injector / 1 0 ° t Oven
Temperature Program / L ft ^ £>r/r?i C
, Material
. Detector ISP
Sampling Method
6
•SAMPLE
RT
•*i/>k
^' 3^
^. ^0
Area
/ftr
2fK<
Peak Height
t
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Amount ( }
Component
c,.
CT.
Name of Operator /%/e/c d/tlP S
5-67
• Date .
19
-------
GAS CHROMAT. APH OPERATING CONDITIONS AND FIELD LOG
Client fere Pc£ . Location rrrr$£URC- . Job No.
Injection Date 7-/7 ~«f Z.. Time /3"2.-'V/ . Instrument ID_
Recorder/Printout Reference No. 4- , Recorder 10 __
Purpose of Run Sf'z'.k
Sample Description
Amount Injected ^
GC CONDITIONS
Inj. Port or Sample Loop Used
Detector Used: FID A , ECO , FPD , TCD (Current _
Detector Attenuation "2. . , Amplifier or Range //?x/
Column: Liquid Phase . Solid Phase_
fjf . O.D.
, I.D. '/* " . Material _£5
Length /? '
Temperature: Injector /2C°C. Oven /%O °C. Detector *2SO °
/
Temperature Program
•SAMPLE RU(i
Sampling Method
5V?
RT
(^/y\)
/)?'-!-
'/is •
0
. Date
19
5-68
-------
GAS CHROMA!. ,APH OPERATING CONDITIONS AND FIELD LOG
C11ent Pf fc.,$>(* . Location firrs^agtr- . Job No.
Injection Date <5~/7- ° t Detector 2fO *
Temperature Program ,
, Solid Phase jpvir»t/Get.cf<.
, I.D. , Material JS
5AMPLE RUfj
Sampling Method
Area
Peak Height
Amount ( )
Component
Name of Operator
f Date .
19
5-69
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client /
. Location
j- . Job No.
Injection Date .£-/?-? 2. . Time /903VO , Instrument ID_
Recorder/Printout Reference No. & _ , Recorder ID __
Purpose of Run 5^-? r,f c*~
<* <=,
Sample Description
GC CONDITIONS
Amount Injected Z<^c , Inj. Port or Sample Loop Used
Detector Used: FID > , ECO _ , FPD _ , TCO _ (Current
Detector Attenuation 7^ _ , Amplifier or Range
Column: Liquid Phase _ , Solid Phase
Len9th
"
. 1.0.
, Material f.r
_
Temperature: Injector / 10 ° . Oven /<£) ° . Detector 2.J
Temperature Program /(^ -f.A &
/ c.
5AMPLE RUfJ
Sampling Method
• ^
(t*1t'f^
&i<;
0,7q
Area
J15&
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Peak Height
•
Amount ( )
Component
c,
c*
Name of Operator
. Date
19 (f i
5-70
-------
GAS CHROMAT. ..APH OPERATING CONDITIONS AND FIELD LOG
Client ?
. Location
. Job No.
Injection Date ^ V7-/J t ji
Recorder/Printout Reference No. "J
Purpose of Run C/ ~C&
, Instrument I0_
, Recorder ID
Sample Description *c £«,/ r
GC CONDITIONS
Amount Injected 2 £-C , Inj. Port or Sample Loop Used
Detector Used: FID * , ECO , FPD , TCO (Current
Detector Attenuation Z. » Amplifier or Range /6*/0'''.
Column: Liquid Phase , Solid
Length £ '
_« °-P-
, I.D.
, Material ^
Temperature: Injector /2
, Detector ?J~O °
Sampling Method
5AMPLE RUfj
L~f
RT
Area
Peak Height
Amount ( }
Component
C
/I
3x63
?,$
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client -r-T^. L'??, . Location
's. . Job No.
Injection Date £"'?•?2- , Time ./T2Z/?/. Instrument I0_
Recorder/Printout Reference No. ,? , Recorder ID __
Purpose of Run /a*?X
Len9th ^- . O.D. x/^ " . I.D. . Material ££
Temperature: Injector /IP ° C Oven /1/A
/7 T^
iX'' >>
Area
/6/b
Peak Height
•
Amount ( )
Component
di; :
Name of Operator
5-72
-------
GAS CHROMA!. ..APH OPERATING CONDITIONS AND FIELD LOG
Client /-T
&£ * Location
, Job No.
- . Time
Injection Date
Recorder/Printout Reference No.
/" /
Purpose of Run ,^?r*cc.
. Instrument 10.
, Recorder ID __
Sample Description c
GC CONDITIONS
Amount Injected C cc t Inj. Port or Sample Loop Used
Detector Used: FID r . ECO _ , FPD _ t TCD _ (Current _ )
Detector Attenuation 2, _ , Amplifier or Range /6
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client />'--rr.
% Location .firr;/scitC c/nt.
Sample Description /!?//>*/ T
GC CONDITIONS
, Inj. Port or Sample Loop Used
Amount Injected __£
Detector Used: FID /? . ECD , FPD , TCD (Current
Detector Attenuation 2- , Amplifier or Range l£tfd""
Column: Liquid Phase , Solid
LenSth ^ '• . O.D. '/* " I.D. , Material £S
Temperature: Injector ^/^O ,°Ct Oven /frO °C8 Detector 7SO °_C
Temperature Program /Jo
5AMPLE RUfj
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
130
C, l
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Cc
Name of Operator
5-74
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
cll"ent r
? . Location
. Job No.
Injection Date£V7-f£ . Time /£&; 2£ . Instrument ID_
Recorder/Printout Reference No. // , Recorder ID
Purpose of Run 6/ -€&
Sample Description
*, /
GC CONDITIONS
_, Inj. Port or Sample Loop Used
Amount Injected Zen
Detector Used: FID A ECO , FPD , TCD (Current
)
Detector Attenuation
2_
, Amplifier or Range /^ rfQ'ff
, Solid Phase ptfPz/^cl-c Q t
, Material
Column: Liquid Phase
Len9th f•' • * °-P- "/^/x l'®' _ _
Temperature: Injector /JO °C . Oven /f O °C . Detector Pj^O ° C
Temperature Program X^b ^y??
-SAMPLE RUN,
Sampling Method ^v/"f c/ x/i /Vg // /^/?
RT
Area
Peak Height
Amount ( )
Component
c;
f,00
KXV
Ct
Name of Operator
, Date
5-75
-------
GAS CHROMA7. ,APH OPERATING CONDITIONS AND FIELD LOG
Client
_ r' ' r1'
f<...:L£t % Location A-v'?
± , Job No.
£ , Time
Injection Date t>~f <
Recorder/Printout Reference No. /2_
Purpose of Run }fe
_^/3/ i Instrument ID_
, Recorder ID
Sample Description
/>i .
Amount Injected ^CC , Inj. Port or Sample Loop Used
Detector Used: FID ^ . ECD _ , FPD _ , TCD _ (Current
Detector Attenuation 2- _ ^ Amplifier or Range /6
Column: Liquid Phase _ , Solid Phase
Length o '
, O.D. 'fee/ , I.D.
, Material
Temperature: Injector
Temperature Program /
>. Oven /%O ° C, Detector
Q t
5AMPLE RUN
Sampling Method Ts~«t 6. /$
Area
Peak Height
Amount ( }
Component
c. •'
Name of Operator
-« Date ''..
/•?_
5-76
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client /irTc. . Lt'z' ,
Location
, Job No.
Injection Date &Y?y3L . Time [?/¥.'// . Instrument I0_
Recorder/Printout Reference No. /3 , Recorder ID _
.-*••
Purpose of Run
Sample Description
>
-.*-. x?
GC CONDITIONS
Amount Injected £.c.C t Inj. Port or Sample Loop Used
Detector Used: FID ^ , ECO _ , FPD _ , TCD _ (Current
Detector Attenuation 2_ _ , Amplifier or Range £> * CO "*
, Solid Phase
Column: Liquid Phase
C O.D.
f
f
. I.D.
, Material
Len9th
Temperature: Injector /2O°C, Oven / °C. Detector
Temperature Program _ / ic>
-SAMPLE RUfj
Sampling Method
• /-RT «
O'«J
o/jy
Orfq
Area
^f2&
¥? ^
Peak Height
r
Amount ( )
Component
C
r,
Name of Operator
/%M/c
_, Date
/ 7
5-77
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client r^c, #r . Location
. Job No.
Injection Date 6'fl-^ . Time /7?7/ f?, Instrument ID_
Recorder/Printout Reference No. _{_'^~_ , Recorder ID
Purpose of Run Ct ••-£
Sample Description £•- c. /r- 6 ' ¥ ?
T-?
r u
r'f
c&
Name
of Operator If 4 ft K Lfr
. Date
5-78
-------
GAS CHROMAT. ,APH OPERATING CONDITIONS AND FIELD LOG
Client Pert. ,£?€ . Location n'ir'ff'sttf'l- , Job No.
Injection Date /->-f7~#2 . Time /7J//f/X Instrument ID
Recorder/Printout Reference No.
Purpose of Run
~
ۥ&?,' OA/
, Recorder ID
Sample Description />»/ C~ f ?
Amount Injected ~L
GC CONDITIONS
, Inj. Port or Sample Loop Used
Detector Used: FID * , ECD , FPD , TCD (Current
Detector Attenuation 1- , Amplifier or Range ^^/^ ~ijf
Column: Liquid Phase
Length *
, Solid Phase
$ ,
t • , O.p. _
Temperature: Injector J_
Temperature Program ,
°
, 1.0.
Ct Oven
, Material
c. Detector 2_TZ2 °c
I a-f-A -err* *J
5AMPLE RUfJ
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
O,
40 f 7
G
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lot to
Name of Operator
. Date
5-79
-------
(This page intentionally blank.)
5-80
-------
5.7 M20 BY GAS CHROMATOGRAPHY
5-81
-------
(This page intentionally blank.)
5-82
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location p£"7
, Job No.
Injection Date 7//V/A2- . Time
Recorder/Printout Reference No.
Purpose of Run '. /-.. ^.'
_, Instrument I0_
, Recorder 10
Sample Description
Amount Injected / c.
GC CONDITIONS
. Port or Sample Loop Used
Amount Injected / c. C _ » Inj. Port or Sample Loop Used
Detector Used: FID _ , ECO \s , FPD _ , TCD _ _ (Current
~ "
Detector Attenuation id, \-j0
Column: Liquid Phase
Length /.2' -f 6' . O.D. Y? (l I.D.
Temperature: Injector i :,-• ^'_t Oven
Temperature Program ______________„___
, Amplifier or Range
, Solid Phase ^/
, Material
0 c, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
Form 435 3/84
5-83
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//V//.2-.. Time
Recorder/Printout Reference No.
Purpose of Run / .••• ./•: ....
, Instrument ID_
, Recorder ID
Sample Description
GC CONDITIONS
Amount Injected / c C , Inj. Port or Sample Loop Used
Detector Used: FID , ECD ^, FPD , TCD (Current )
Detector Attenuation /£>-?/?"" , Amplifier or Range
Column: Liquid Phase
i ,.' f^cfit K
, Solid Phase &/ sJr-'r <£
Length /I' 4 (,' . O.D. Yf l! I.D.
, o
Temperature: Injector
Temperature Program
, Oven
__, Material _
, Detector ;
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( }
Component
Name of Operator Or//
, Date
19
Form 435 3/84
5-84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location fBT'C.
, Job No.
Injection Date 'J-j/v/JZ-, Time
Recorder/Printout Reference No.
Purpose of Run /, ,- y .......
_, Instrument ID_
, Recorder ID
Sample Description
GC CONDITIONS
j- Port or Sample Loop Used
Amount Injected let, ,
Detector Used: FID , ECD jX_, FPD , TCD (Current )
Detector Attenuation jf,'^a~" . Amplifier or Range . ._
_, Solid Phase [l< s£r,. a? .
~~ •• ""--*- r"1IlJ—y^i-i "rauar V-~ —.. - —
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Length /j/ •/ g / . O.D. Y? " I.D.
Temperature: Injector
Temperature Program
, Oven
, Detector -
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
Form 436 3/84
5-85
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location f>S7
, Job No.
Injection Date J-//<-//J2- , Time
Recorder/Printout Reference No.
Purpose of Run /, /•• c-,., •:..., /
, Instrument ID_
, Recorder ID
Sample Description <-/
GC CONDITIONS
j. Port or Sample Loop Used
Amount Injected / ££.....
Detector Used: FID _ , ECD >s , FPD _ , TCD _ (Current
Detector Attenuation }(, \-jn " "
Column: Liquid Phase
, Amplifier or Range
, Solid Phase
/ I1
Length /J' v (,< . O.D. '/? " I.D.
Temperature: Injector / :
Temperature Program
, Oven
__, Material
, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
Form 435 3/84
5-86
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//V//.2- . Time
Recorder/Printout Reference No.
Purpose of Run
Sample Description
Q,
_, Instrument ID_
, Recorder ID
Amount Injected /
GC CONDITIONS
» I"J- Port or Sample Loop Used
Detector Used: FID _ , ECD j/_, FPD _ , TCD _ (Current
Detector Attenuation /£ >-//?
Column: Liquid Phase
. Amplifier or Range
, Solid Phase
/ I t f'o ' -V
Length ft' 4 &' . O.D. '/? lf I.D.
Temperature: Injector
Temperature Program
, Oven
__, Material
, Detector
/?
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount { )
Component
O •
Name of Operator CH.tf.5..
, Date
19
5-87
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//V/1.2- » Time
Recorder/Printout Reference No.
Purpose of Run g
, Instrument ID_
, Recorder ID
Of
Sample Description
O
Amount Injected /
GC CONDITIONS
•> Inj. Port or Sample Loop Used
Detector Used: FID _ , ECD i/ . FPD _ , TCD _ (Current _ )
Detector Attenuation /^y//?"" . Amplifier or Range _
Column: Liquid Phase _
i ti fo-csi.t.
, Solid Phase (.< sj,.,,r
Length /j' v g' , O.D. J<
Temperature: Injector /_;,-
Temperature Program
., I.D.
Oven
, Material
, Detector
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
-<-* 84-
/foo
Name of Operator
, Date
19
5-88
Form 435 3/64
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date ^//y/j'jL. , Time
Recorder/Printout Reference No.
Purpose of Run _ /Vj<9 X7/i
, Instrument ID
3*? » Recorder ID
Sample Description /?/.«//£.
/a/?<
GC CONDITIONS
j- Port or Sample Loop Used
Amount Injected / c C .
Detector Used: FID , ECD _iX_, FPD , TCD (Current )
Detector Attenuation j(,\/n~" , Amplifier or Range
, Solid Phase *le s^f <$ ,
•^•^•••••^^^^•••••••••^mHHIM^^ ^«M«1»^«»^»™—^•"•^M^^™^—i^B^—^^»
Y? ll I.D. , Material
Column: Liquid Phase
Len9th &' * &' » °'D< ^ U
Temperature: Injector / L/ ° _, Oven
Temperature Program
, Detector
SAMPLE RUN
Sampling Method ZQtfg C
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
5-89
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location fig7C
, Job No.
Injection Date 7//y/^j2- , Time
Recorder/Printout Reference No. 3O
Purpose of Run
, Instrument ID_
, Recorder ID
Sample Description 8
GC CONDITIONS
_..„ , „ _ . Inj. Port or Sample Loop Used t-oc/~
Detector Used: FID , ECD >/ , FPO , TCD (Current )
Amount Injected J_
Detector Attenuation /£y/,?"" . Amplifier or Range
Column: Liquid Phase , Solid Phase_
Length t3.' 4 g' t O.D. '/f (( I.D.
Temperature: Injector , :. ° , Oven _
Temperature Program
I j.' fc.ta/
'
__, Material
, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( ) Component
/ ~78.it.
Name of Operator
, Date
19
5-90
Form 435 3/84
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7/A//A2- , Time
Recorder/Printout Reference No. <3/
Purpose of Run
_, Instrument ID_
, Recorder ID
Sample Description
#^e>
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location pe~7 C
, Job No.
Injection Date 7//V/f,2- » Time
Recorder/Printout Reference No.
Purpose of Run
Sample Description 81 ££.*.<» (2-
, Instrument ID_
, Recorder ID
GC CONDITIONS
Amount Injected / £ C , Inj. Port or Sample Loop Used
Detector Used: FID , ECD tX . FPD , TCD (Current
Detector Attenuation ft,>-//?~" , Amplifier or Range
Column: Liquid Phase .
/ I/f
, Solid Phase V s
Length ii' 4 (,< , O.D. Y'
Temperature: Injector / : -
Temperature Program _,
I.D.
, Oven
_, Material
, Detector
SAMPLE RUN
Sampling Method £(?/«•// f,/z
RT
Area
Peak Height
Amount ( )
Component
3 363 2.
O
Name of Operator
, Date
19
5-92
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
jL- , Time
, Instrument ID
Injection Date '
Recorder/Printout Reference No. 33 , Recorder ID
Purpose of Run AAn
Sample Description 8/££/£=
GC CONDITIONS
- Port or Sample Loop Used
Amount Injected / c C »
Detector Used: FID , ECD j/_, FPD , TCD (Current )
Detector Attenuation /£ >-//?"" » Amplifier or Range
Column: Liquid Phase
Temperature: Injector J__
Temperature Program .
_, I.D.
, Oven
, Solid Phase g/ sj,.f,
m ^H«MMiWB«to«BMH^^i^la
, Material
0 , Detector - -.- °
SAMPLE RUN
Sampling Method BO/^S f,
RT
Area
Peak Height
Amount ( )
Component
/.Sif
S.-7J-7 "7
Name of Operator
, Date
19
5-93
Form 43S 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location pB'J C
, Job No.
Injection Date 7//y/>,:2- . Time
Recorder/Printout Reference No.
Purpose of Run
, Instrument ID
J/f- , Recorder ID
Sample Description 8/55/&
GC CONDITIONS
Amount Injected / £ C , Inj. Port or Sample Loop Used i~c-c/~
Detector Used: FID , ECO _./_, FPD , TCD (Current )
Detector Attenuation }(,yrn~" . Amplifier or Range
Column: Liquid Phase
, Solid Phase
/ I.' ffiOf
lt
Length /J' 4 (,' . O.D. '/?
Temperature: Injector / •-,
Temperature Program
_, 1.0.
Oven
, Material
, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
5-94
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location f>e~7C
, Job No.
. Time
Injection Date
Recorder/Printout Reference No.
Purpose of Run /IAn /3/v#i-^ s&
_, Instrument ID_
, Recorder ID
Sample Description ff/.5xv:3
/sx
GC CONDITIONS
Amount Injected / c C . I"j« Port or Sample Loop Used _£
Detector Used: FID , ECO iX , FPD , TCD (Current
Detector Attenuation }(,y//?"" , Amplifier or Range
Column: Liquid Phase
Length /,%/ •/ g
^ , . . «.
, Solid Phase
/
v g/ , O.D.
Temperature: Injector ' ^
Temperature Program
f/
1.0.
Oven
_, Material
, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
7,4.8
/v? o
Name of Operator
, Date
19
5-95
Form 436 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 'lllLi/32- , Time
Recorder/Printout Reference No.
Purpose of Run
_, Instrument I0_
, Recorder ID
Sample Description
GC CONDITIONS
Amount Injected / C C , Inj. Port or Sample Loop Used
Detector Used: FID , ECD ^ , FPD , TCD (Current )
Detector Attenuation /£ >-//?"" , Amplifier or Range
Column: Liquid Phase ____^_
^ -. . «,
, Solid Phase
Length i3L' -/ g / , O.D. _£
Temperature: Injector ;
Temperature Program
_, I.D.
Oven
, Material
, Detector
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
/a O
Name of Operator
, Date
19
5-96
Form 435 3/84
-------
GAS CHROMATOGRAPK OPERATING CONDITIONS AND FIELD LOG
Client
, Location f87 C
, Job No.
Injection Date ^//y/i.2- . Time
Recorder/Printout Reference No.
Purpose of Run /]/? n
_, Instrument ID_
, Recorder ID
Sample Description
GC CONDITIONS
Amount Injected / £ C , Inj. Port or Sample Loop Used L&*/~
Detector Used: FID , ECD *s . FPD , TCD (Current )
Detector Attenuation jfay/o'" , Amplifier or Range
Column: Liquid Phase __
/ L'
, Solid Phase V
(t
Temperature: Injector /•: ' °_ , Oven
Temperature Program
__, Material
, Detector "?'--,
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
9-7-3
o n
Name of Operator
, Date
19
5-97
Form 435 3/84
-------
GAS CHROMATOGRAPh OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date "7-//V/J2- , Time
Recorder/Printout Reference No.
Purpose of Run /Yzfi
J%
, Instrument ID_
, Recorder ID
Sample Description
< £5 Z3y"7
Amount Injected /
GG CONDITIONS
« Port °r Sample Loop Used
Detector Used: FID , ECD *s , FPO , TCD (Current
Detector Attenuation l^wo"" * Amplifier or Range
Column: Liquid Phase , Solid Phase *\< /'
Length /J?' 4 & ' . O.D. Y?" I.D. , Material
0 t Detector
,-?r
Temperature: Injector ..';•;•
Temperature Program _
I.D.
, Oven _
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount { )
Component
. £,
O
Name of Operator
, Date
19
5-98
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date "]• llLfl$ 2- , Time
Recorder/Printout Reference No.
Purpose of Run
_, Instrument ID_
, Recorder ID
Sample Description #/&_•
GC CONDITIONS
Amount Injected j c C. , Inj. Port or Sample Loop Used
Detector Used: FID , ECO j/_, FPD , TCD (Current )
Detector Attenuation /^*to"ff , Amplifier or Range
Column: Liquid Phase
/ >•'
^ , . . r,. •
, Solid Phase
Length /%' -t &' ,0.0.
Temperature: Injector ;
'/?" , I.D.
-•-•• ° , Oven
, Material
0 , Detector :- u °
Temperature Program
SAMPLE RUN
Sampling Method
RT
J.gz
£*•£%
-?,£*)
Area
37^S 3
%o33
•70283
Peak Height
Amount ( )
#£•£
Component
/v$o
Name of Operator
, Date
19
5-99
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//y/l.2- . Time
Recorder/Printout Reference No.
Purpose of Run
/d?
, Instrument ID_
Recorder ID __
g p
Sample Description gj£'£i'7
'SSL
Amount Injected / c
GC CONDITIONS
. Inj. Port or Sample Loop Used
Detector Used: FID , ECD j/_, FPD , TCD (Current
Detector Attenuation J^^/o'" , Amplifier or Range
Column: Liquid Phase
Length /
~ , ».
_, Solid Phase
>•'
v g' , O.D.
Temperature: Injector
Temperature Program
., I.D.
Oven
__, Material
, Detector
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( }
Component
O
Name of Operator (Hi? 5"
, Date
19
5-100
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location fe~7
, Job No.
Injection Date . 7//Y//.2- , Time
Recorder/Printout Reference No.
Purpose of Run /tyo
_, Instrument ID_
, Recorder ID
Sample Description
GC CONDITIONS
Amount Injected / £ C > Jnj« Port or Sample Loop Used
Detector Used: FID , ECD ^ , FPD , TCD (Current )
Detector Attenuation /^>-//?"" » Amplifier or Range
Column: Liquid Phase , Solid Phase l\i s'{f,-<>r ")
, Date
19
5-101
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//V/^.^- , Time
Recorder/Printout Reference No.
Purpose of Run /YoQ X?/^
_, Instrument ID_
, Recorder ID
<.
Sample Description §'53 3k
/&2.P.
GC CONDITIONS
Amount Injected I dC. , Inj. Port or Sample Loop Used
Detector Used: F.ID , ECD jX_, FPD , TCD (Current
Detector Attenuation j^'x/n'" » Amplifier or Range
Column: Liquid Phase , Solid Phase llt '?£?,
Length /,2' * £' . O.D. V? (l I.D. , Material _
Temperature: Injector .' :• :~
Temperature Program
Oven
, Detector
SAMPLE RUN
Sampling Method
RT
J'G*
f>tf
7 ¥•(*
Area
Zs-f&b
9 ^^-7
3f> %/<£.
Peak Height
Amount ( )
UiL-'Z
Component
A^n
Name of Operator
, Date
19
5-102
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//V//2- » Ti
Recorder/Printout Reference No.
Purpose of Run /?6 n
, Instrument ID_
>^3 , Recorder ID
Sample Description
Amount Injected /
GC CONDITIONS
, Inj. Port or Sample Loop Used
Detector Used: FID , ECO j/_, FPD , TCD (Current )
Detector Attenuation }£, r/n ~ff , Amplifier or Range
Column: Liquid Phase
, Solid Phase
Length /j/ v ,g/ , O.D. fr
Temperature: Injector .'_
Temperature Program
_, I.D.
Oven
__, Material
, Detector
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
3-75*3^
US* 1
Name of Operator
, Date
19
5-103
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
, Instrument ID
Injection Date 7-//V/A2- . Time
Recorder/Printout Reference No. JJ-IL. . Recorder ID
Purpose of Run ft/a n
Sample Description
js&sr> /X-? G iO-u.'O*
/o
/I/-?
GC CONDITIONS
Amount Injected / c C- » Inj- Port or Sample Loop Used
Detector Used: FID, ECD
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7//v/-f jZ- » Time
Recorder/Printout Reference No.
Purpose of Run
_, Instrument ID_
, Recorder ID
Sample Description
/Q.JI.*?, rta-.
GO CONDITIONS
Amount Injected / c C » Inj« Port or Sample Loop Used i-&p/~
Detector Used: FID , ECO _•/_, FPD , TCD (Current )
Detector Attenuation )b*/o~" , Amplifier or Range
, , Solid Phase /{/ sj^?, c< _ _ ,
Column: Liquid Phase
Length ij' 4 g' , O.D. '/ftf I.D.
Temperature: Injector
Temperature Program
, Oven
_, Material
, Detector
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount ( )
Component
//
"7*1
Name of Operator CHif
, Date
19
5-105
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
, Job No.
Injection Date 7-///'<. t. K.
, Solid Phase V sj,.,, &
m ^^M^MmMV*M«^Hi^^B^i^H«IMMBH
, I.D. __, Material
Oven
, Detector
o
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
5-106
Form 435 3/84
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location p£T7
, Job No.
Injection Date y-//y//.2- , Time
Recorder/Printout Reference No.
Purpose of Run /Xb o
Sample Description /
, Instrument ID_
, Recorder ID
GC CONDITIONS
Amount Injected / c C » Inj. Port or Sample Loop Used _
Detector Used: FID , ECD */ , FPD , TCO (Current )
Detector Attenuation j£ y/,-? ~" , Amplifier or Range
_ i J> - _ _ A S9
Column: Liquid Phase , Solid PhaseJ
Length /J' •/ $' , O.D. */? ll I.D. , Material
•
sjr.,r c<
Temperature: Injector /£_
Temperature Program
, Oven
, Detector 5 v <
Sampling Method
SAMPLE RUN
RT
Area
Peak Height
Amount ( )
Component
Name of Operator
, Date
19
5-107
Form 435 3/84
-------
(This page intentionally blank.)
5-108
-------
5.8 TOTAL CHROMATOGRAPHABLE ORGANICS (TCO), GRAVIMETRIC ORGANICS (GRAV),
IR SPECTRA, GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS), LIQUID
CHROMATOGRAPHY (LC), AND LOW RESOLUTION MASS SPECTROMETRY (LRMS)
5-109
-------
(This page intentionally blank.)
5-110
-------
ACUREX
Corporation
Energy & Environmental Division
Acurex/ES (CMEA) November 15, 1982
M/S 2-2260 Acurex ID#: A82-06-026, A82-10-025
Client P0#: 307736.42
Attention: Larry Waterland Page 1 of 5
Sample: PETC SASS Train; Received 6/18/82
The above-referenced samples were analyzed by Level 1 protocol. Organic
extracts were also analyzed for the semivolatile priority pollutants by gas
chromatography/mass spectrometry employing a J&W SE-54 30 meter capillary
column. The column was held at 30°C for 2 minutes, then ramped at 10°C per
minute to 270°C. In addition to the priority pollutants, other organics
including benzo(c)phenanthrene, dibenzo(c,g)carbazole, 7,12-dimethylbenzo(a)
anthracene, 3-metnylcholanthrene, and perylene were sought employing the com-
puterized library search and manual interpretation. The assignment and
quantisation of these organics is tentative since analytical standards of
these compounds were not available for analysis. Benzo(c)phenanthrene,
dibenzo(c,g)carbazole, 7,12-dimethylbenzo(a)anthracene, 3-methylcholanthrene
and perylene were not detected in any of the samples at levels above 40
ug/mL of extract.
The XAO and OMC extract was concentrated to 11 ml. It would not concen-
trate further without loss of material. Two phases were observed at this
point. For analysis, the extract was mixed by sonification.
If you have any questions, please call.
Submitted by:^sC>La&,SZ>eZcv*?:' Approved by:
Greg fitfcollViorica Lopez-
Chefinst Technical Director
GN/VLA/sIa
5-111
485 CLYDE AVENUE. MOUNTAIN VIEW, CA 94042 PHONE (415) 964-3200 TELEX: 34-6391 TWX: 910-3796593
-------
/N ACUREX
T ^ Corporation
ANALYSIS LABORATORIES
DATA REPORTING FORM
CUSTOMER
CMEA
DATE November 12. 1982
307736.42
CUSTOMER CONTRACT NO.
RESULTS REPORT TO I. Materland
ADDRESS
ACUREX CONTRACT NO.
TELEPHONE
A82-06-026
PETC-DOE
SAMPLE ID (CUSTOMER)
SAMPLE ID (LAB)
p* p A fcJFTFP
GRAV Aliquot
6RAV Blank Aliquot
GRAV
TCO Aliquot
TCO Blank Aliquot
TCO
15y+10M
4
4
<2
6
__
--
__
3u+Fi1ter
1
3
<2
4
--
--
--
t
XAD+OMC
8
267
4
285
4#0ft4,100
<10
57;49
Bottom
Ash
16
163
2
6,400*
3,900
<10
1 ,600*
Baghouse
Ash
17
4
2
<100*
18
<10
0.72*
UNITS
mg
mg
mg/train
ng/nL
ng/yL
mg/train
*
en
i
*mg/kg
ANALYST J. Labash
Form EED-OSt 4.'6O
REVIEWER
6. NlCOll
-------
|ft
tAMPU:
A82-06-026-4
15y
tires raity
No peaks
Commons
5-113
-------
IH REPORT
SAMPLE:
A82-06-026-1
Filter + 3u
tm»n«ity
Command
No peaks
5-114
-------
tK
(AMPLE:
A82-06-026-16
Bottom Ash
tow Hmfc*
. fa.'1)
3400
2940
2860
1730
1610
1460
1380
1280
820
750
lm»mity
W
s
s
M
M
M
W
W
W
W
A*»ignm«n Cemmtntt
0-H stretch (COOH) Broad
C-H Aliphatic
C-H Aliphatic
C=0 {COOH)
C- --C Aromatic Tentative assignment
C-H
C-C
C-0 (COOH)
Not assigned
C-H
5-115
-------
REPORT
A82-06-026-17 Baghouse Ash
tmtmity
Arignmwit
No peaks
5-116
-------
Ill
A82T-Q6-Q26-8
XAD and OMC
Ww Hwwitaf
.- <-•')
3600 - 3000
1640
1410
1160 - 1060"
1000.
!m»mity
S
S
W
M
W
Aoignmwtt C»mnMnti
0-H stretch Broad
C=C* With shoulder
0-H bend
C-0
Not assigned
tentative assignment -~ not supported by
other" absorbances
5-117
-------
IK
IAMPUE:
A82-06-026-2
Filter Blank
Ira natty
CemrMfiti
No peaks
5-118
-------
IH REPORT
tAMPU:
A82-06-026-11
XAD Blank
AccignmMt
Cemnwrttt
No peaks
5-119
-------
lit REPORT
SAMPLE:
A82-06-026-13
Shake-Out Blank
Imamity
No peaks
5-120
-------
IR RIPORT
SAMPLE:
A82-06-026-14
6RAV Blank
Utttmity
Comm«nti
No peaks
5-121
-------
CONCENTRATION IN SAMPLE ALIQUOTS (pg/mL)
Acurex/CMEA
A82-06-026, A82-10-025
Page 2 of 3
Priority Pollutants
Naphthalene
Benzo ( j +k ) f 1 uoranthenes
Chrysene
Benz(a)anthracene
Pyrene
Fluoranthene
Phenanthrene
Anthracene
Fluorene
Acenaphthene
Acenaphthylene
2, 4-Dimethyl phenol
B1s(2-ethylhexyl Jphthalate
Butylbenzylphthalate
Di ethyl phthal ate
Final Volume
lOM+ISp
5
*
*
. *
*
*
*
*
*
*
*
<5
2
1
*
1 ml
Filter+3y
i
47
*
*
*
*
*
*
*
*
*
*
<5
48
5
5
1 ml
Bottom
Ash
104
1
2
1
5
4
28
3
5
3
5
13
213
298
*
10 ml
Baghouse
Ash
8
*
*
*
*
*
*
*
*
*
*
<5
11
2
*
1 ml
Filter
Blank
*
*
*
*
*
*
*
*
*
*
*
<5
4
2
*
1 ml
XAD+
OMC
* *
>
* *
>
* *
>
* *
>
* *
»
* *
>
* *
>
* *
>
* *
>
* *
>
* *
•
<5,<5
6,6
3,<1
* it
>
11 ml
XAD
Blank
3
*
*
*
*
*
*
*
*
*
*
<5
3
2
*
1 ml
Shakeout
Blank
*
*
*
*
*
*
*
*
*
*
*
<5
1
*
*
1 ml
ui
I
ro
ro
*Not detected, detection limit = 1 pg/mL
-------
Acurex/CMEA
A82-06-026, A82-10-025
Page 3 of 5
CONCENTRATION (yg/Train)
Compound
" Naphthalene
* Benzo(j-H0fluoranthenes
Chrysene
Benz(a)anthracene
Pyrene
Fluoranthene
Phenanthrene
Anthracene
Fluorene
Acenaphthene
Acenaphthylene
2 ,4-Dimet hyl phenol •
Bis(2-ethylhexyl )phthalate
Butyl benzyl phthal ate
Dlethylphthalate
10y+15y
8
<2
<8
;6
3
<2
Filter+3y
69
<1
<7
69
7
7
Bottom Ash*
42
0.4
0.8
0.4
2
2
n
1
2
1
2
5
85
120
<0.4
Baghouse Ash*
0.3
<0.04
<0.2
0.3
0.08
<0.04
XAD+OWC**
<10,<10
•
r
<60,<60
70,70
<30,<20
<10,<10
*Untts are mg/kg
**Dupl1cate injections
5-123
-------
Acurex/CMEA
A82-06-026, A82-10-
Page 4 of 5
APPROXIMATED CONCENTRATION OF TENTATIVELY'IDENTIFIED COMPOUNDS (yg/Train)
Sample
10u+15y
Filter+3y
Bottom Ash
Baghouse Ash
XAD + OMC
Compound /
Octamethylcyclotetrasiloxane
C3~Alkyl benzene
Tri methyl benzene
C4-A1 kyl benzene
Benzothiazole
Sulfur
4-Methyldibenzofuran
Trimethyl naphthalene (second)
Trimethyl naphthalene (first)
Dibenzofuran
Dimethyl naphthalene
Ethyl naphthalene
Methyl naphthalene (second)
Methyl naphthalene (first)
No Peaks Identified
Ethyl benzoic acid
Benzole acid
Ethyl benzal dehyde
Concentration
120
88
37
15
73
100*
17*
33*
14*
13*
29*
14*
48*
64*
--
520
2,600
150
*Units are mg/kg
5-124
-------
GCHS Detection Limits
21A
22A
24A
3TA
34A
57A
58A
59A
60A
64A
65A
ACID COMPOUND
2.4,6-trlchlorophenol
p-chloro-m-cr«so1
2-chlorophenol
2t4-d1chlorophenol
2,4-d1methylphenol
2-nitrophenol
4-nitrophenol
2,4-d1nitrophenol
4t6-din1tro-o-creso1
pentachlorophenol
phenol
21
5
5
5
5
5
5
20
20
20
S
1
BASE/NEUTRAL COMPOUNDS
13
58
38
98
123
188
208
258
268
27B
288
35B
368
378
398
408
acenaphthene
benzidine
1 ,2,4-trichlorobenzene
hexachlorobenzene
hexachloroe thane
b1s(2-chloroethyl)ether
2-chloronaphthalene
Ij2-d1chlorobenzene
1 ,3-d1chlorobenzene
Ij4-d1chlorobenzene
3,3'-d1chlorobenz1dine
2, 4-din1tro toluene
2,6-dinitrotoluene
1 ,2-d1phenylhydrazine
(as azobenzene)
fluoranthene
4-chlorophenyl phenyl ether
1
20
1
1
1
1
1
1
1
1
5
1
1
1
1
1
41B 4-bromophenyl phenyl ether
428 bis{2'-chloroisopropyl)ether
438 b1s(2-chloroethoxy)methane
52B hexachlorobutadiene
53B hexachlorocyclopentadtene
S48 isophorone
55B naphthalene
56B nitrobenzene
61 B N-n1trosodimethyla?Rine
628 N-nltrosodiphenyTamine
638 N-nitrosod1-n-propylam1ne
668 b1s(2-ethylhexyl)phthalate
67B butyl benzyl ph thai ate
688 di-n-butyl phthalat*
698 di-n-octyl phthalate
708 diethyl phthalate
718 dimethyl phthalate
72B benzo(a}anthracene
738 benzo(a)pyrene
748 3,4-benzofluoranthene
758 benzo(k)fluoranthene
768 chrysene
77B acenaphthylene
788 anthracene
79B benzo(gh1)perylen*
808 fluorene
81B phenanthrene
82B dibenzo(a,h}anthracene
838 1ndeno(1»2.3-cd)pyrene
84B pyrene
1
1
1
1
1
1
1
1
NA
1
5
1
1
1
1
1
1
1 '
1
1
1
1
1
. 1
5
1
1
5
5
1
5-125
-------
AACUREX
. Corporation
Acurex/ES
Attention:
Reference:
Larry Waterland
Samples PETC Bottom Ash and XAD Plus
OMC Extracts; Received 11/22/82
Energy & Environmental Division
December 20, 1982
Acurex ID# A82-11-029
Client P0# 307736.42
Page 1 of 28
The above referenced samples were subjected to Level 1 liquid chromatography.
The seven resulting fractions for each sample were subjected to gravimetric,
TCO, and infrared analyses using Level 1 methodology. The results of these
analyses are presented in the attached data forms.
The low recovery of the XAD plus OMC liquid chromatography fractions appears
to be due to material being retained within the LC column.
Prepared by:
Approved by:
Viorica Lopez-AvilayPh.D.
Technical Director
GN/VLA/sla
Attachments
5-126
485 CLYDE AVENUE. MOUNTAIN VIEW. CALIFORNIA 94042 PHONE (415) 964-3200 TELEX: 34-6391 TWX: 910-3796593
-------
SAMPLE: PETC XAD & OMC A82-11-029-2 (29% of Extract)
en
«_i
ro
1.
Z.
TCO
53
15
0.16
flftAV
285
83
15.8
TtO+OftAV
338
98
16
Acurex/ES
A82-11-029
Page 2 of 28
mg/dscm
fmtfM
1
1
1
4
I
1
I
SM
Tea (MM*
NMrffc
ft*!!*
<0.02
-pO^l
<0.01
0.13
Q. 03
<0.01
<^p.oi
0.16
VIMNi
<0.02
<0.01
<0.01
<0.01
^q .0,1
<0,01
0,01
<0,08
e^
tMMl
<0.02
<0.01
<0,Q1
0.13
ft O"1
<0,01
<0,P1
,0,16
W
<0.07
<0.0.1
<0.03
0.45
n.in
<0.03
xO.Q3
0.55
ONAVhMI
Pt«m«li
Fnctln
0.8
0.4
0.6
0.6
, n 4
0.6
12.4
15.8
Mb*
<0.5
<0.4
<0.4
<0.4
-------
SAMPLE: PETC Bottom Ash A82-11-029-3 (50% of Extract of 25g)
Acurex E/S
A82-11-029
Page 3 of 28
I***.'
TAMfwlC1
fl^tt^M^)
tea
Ml
40
20
3.6
CWAV
••I
160 '
80
115.8
TtO*flMV
r*tf
-------
tR
(AMPLE
A82-11-29-3
LCF1
Bottom Ash
PETC
Acurex E/S
A82-11-029
Page 8 of 28
ritaTitai —
"tS*"
2950
2870
1610
1460
1390
880
820
760
tm»mity
S
M
W
M
W
W
W
W
JUugnrnwrt Comnunti
G-H Aliphatic w/shoulder
C-H Aliphatic
C=C
C-H Aliphatic
C-H Aliphatic
C-H
C-H
C-H
5-129
-------
Ift REPORT A82-11-29-3
(AMPLE:
LCF2
Bottom Ash
PETC
Acurex E/S
A82-11-029
...Prpp 9 nf ,28
"IS*"
2950
1460
880
820
760
•
liraraity
S
M
W
W
M
•
A»i|nm«Tt Comments
C-H Aliphatic Weak spectrum
C-C
C-H
C-H
C-H
-
5-130
-------
-------
IR REPORT A82-11-29-3
.CF4
Bottom Ash
PETC
Acurex E/S
A82-11-029
Page 11 of 28
**•**»«*«
- f1)
3420
2950
1720
1610
1480
1390
1290
1140
1080
1040
820
760
/IU
ifrtftnutv
W
s
M
W
M
W
M
W
W
W
W
W
M
AwJywtwot - * Cemmtnti
0-H Broad
C-H Aliphatic Doublet w/shoulder
C=0
C=C
C-H
C-H
C-0
C-0
C-0
C-0
C-H
C-H
Not Assigned
•>. •
5-132
-------
I*
SAMPLE:
A82-11-29-3
L.CF5
Bottom Ash
PETC
Acurex E/S
A82-11-029
Paoe 12 of 28
IVlPVl tLMMhftMV
. <-•')
3420
2950
1730
1610
1460
1380
1290
1140
1080
1040
820
750
710
Intimity
M
S
S
M
M
W
M
H
M
W
W
W
W
i
An^tmtnt "v Cemm«nti
0-H (COOH) Broad
C-H Alfohatic - -Doublet w/shoulder
C=0 (COOH)
OC
C-H
C-H
C-0 (COOH)
C-0
C-0
C-0
CH
CH
Not Assigned
*•
-
5-133
-------
I* REPORT A82-11-29-3
(AMPLE:
.CF6
Bottom Ash
PETC
Acurex E/S
A82-11-029
Page 13 of 28
**^X*
3450
2950
1740
1620
1460
1380
1270
820
750
710
iRtftfttirp
M
S
M
M
M
M
M
W
W
W
fetognfMRt * * Common
0-H (COOH) Broad
C-H Aliphatic -Doublet w/shoulder
C=0 (COOH)
C=C
C-H
C-H
C-0 (COOH)
C-H
C-H
C-H
•
«»
5-134
-------
I* REPORT A82-11-29-3
SAMPLE:
LCF7
Bottom Ash
PETC
Acurex E/S
A82-11-029
Page 14 of 28
VIM >»nfc»
- to.-1)
3300
2950
1620
1460
1380
1270
750
Intimity
W
s
M
M
W
W
W
•
Alignment - * Commend
0-H Broad
C-H .. Doublet
C=C
C-H
C-H
c-o
C-H
-
«^>
-
5-135
-------
IH REPORT A82-11-29-4
tAMPL£:
.cn
XAD Blank
PETC
Acurex E/S
A82-11-029
Page 15 of 28
Conurwna
No peaks
5-136
-------
IH REPORT A82-11-29-4
LCF2
XAD Blank
Acurex E/S
A82-11-029
Page 16 of 28
Intimity
Cemmcna
No oeaks
5-137
-------
IH REPORT A82-11-29-4
1AMPLE: _ ___
LCF3
XAD Blank
Acurex E/S
A82-11-029
PETC Page 17 of 28
oea ks
5-138
-------
tft REPORT A82-11-29-4
XAD Blank
PETC
Acurex E/S
A82-11-029
Page 18 of 28
CORUTMRtl
No peaks
5-139
-------
IR REPORT A82-11-29-4
IAMFLE: LCF5
XAD Blank PETC
Acurex E/S
A82-11-029
Page 19 of 28
tmvmity
No oeaks
5-140
-------
IH
SAMPLE:
A82-11-29-4
LCF6
XAD Blank PETC
Acurex E/S
A82-11-029
Page 20 of 28
V**
No peaks
5-141
-------
IR REPORT A82-11-29-4
SAMPLE:.
LCF7
XAD Blank
Acurex E/S
A82-11-029
PETC page 21 of 28
timmity
No peaks
5-142
-------
1* REPORT A82-11-29-2
SAMPUE: LCF1
XAD/OMC PETC
Acurex E/S
A82-11-029
Page 22 of 28
ImkraJty
2950
C-H
Weak spectrum
5-143
-------
IR REPORT A82-11-29-2
SAMPLE:
LCF2
XAD/OMC
PETC
Acurex E/S
A82-11-029
Page 23 of 28
IF****"**
- I-'1)
2950
2810
•
tmtnuty
S
M
Anlpmwrt " Cemmwitt
C-H Weak spectrum
C-H
, ,
•
».
5-144
-------
IR REPORT A82-11-29-2
LCF3
XAD/OMC
PETC
Acurex E/S
A82-11-029
Page 24 of 28
Cemmcna
No peaks
5-145
-------
tR REPORT A82-11-29-2
8AM? LE;_
LCF4 XAD/OMC PETC
Acurex E/S
A82-11-029
Page 25 of 28
Sirttntity
No peaks
5-146
-------
IH REPORT A82-11-29-2
SAMFU:
LCF5 XAD/OMC
PETC
A82-?l-029
Page 26 of 28
'1
Anigiwnwn
Cemmana
No peaks
5-147
-------
tR REPORT A82-11-29-2
LCF6 XAD/OMC PETC
Acurex E/b
A82-11-029
Page 27 of 28
No peaks
5-148
-------
I*
SAMPLE:
A82-11-29-2
LCF7
XAD/OMC
PETC
Acurex E/S
A82-11-029
Page 28 of 28
- fc»'!>
3400
1640
1550
1390
1220
mo
brarttity
S
S
w
M
W
W
Anlpwnwtt * * ContrMRtt
0-H ^ Broad
c-c -•
C-N02 (Not confirmed)
0-H x
C-0 ^
C-H ^
' •
*
«*•
•
5-149
-------
ACUREX
Corporation
Energy & Environmental Division
Acurex/ES
April 11, 1983
Acurex ID#: 8301-029
Client P0#: 307736.42
Attention: L. Water land
Sample: PETC extracts
The above referenced samples were analyzed by direct probe mass spectrometry.
Searches have been made for classes of compounds according to procedures
described in the "IERL-RTP Procedures Manual: Level 1 Environmental Assessment".
Losses of very volatile compounds such as naphthalene are normally observed
with this procedure. The following fragment ions used for the search are given
below:
Compound Class
Polycyclic aromatic hydrocarbons
Aliphatic hydrocarbons
Halogenated aliphatics
Aromatic hydrocarbons
Ethers
Alcohols
Phenols
Nitriles
Phthalate esters
Amines
Ketones
N-heterocyclics
Mercaptans, sulfides
Benzothiophenes
Carboxylic acids
Amides
Fragment ions (m/e)
178,202,216,228,252,276
57,71
49,63,79,81,93,95,107,109
50,51,77,78,79,91
45,59,73
45,59,61,73,75
51,77,94
54,68,82
149,167
44,58
51,71
117,129,167,179
47,61,75
57,58,59,69,70,85,97,111 ,125
60,73,149
58,72,86,100
Prepared
^i AAJKuEUl&A
jjusanM. Kras ka
Staff Chemist
pproved
vionca Lopez-Avila,
Technical Director
SMK/VLA/ats
5-150
485 CLYDE AVENUE MOUNTAIN VIEW, CALIFORNIA 94042 PHONE: (415) 964-3200 TELEX: 34-6391 TWX: 910-3796593
-------
REPORT
SAMPLE: 8301-QZ9-1 PETC Front Half
Major Cattsorits
Intensity
Cnt^ery MVV Rang*
None detected
.
-
Sub-Categories. Specific Compounds ,
Intensity
Category
'
m/t
Composition
.. .
; '
Othw
5-151
-------
LRMS REPORT
SAMPLE; 8301-029-2 PETC Baghouse Ash
Major Cattson't*
Inttntity
100
100
Cattfory
Alkyl benzenes
Halogenated aliphatics
•
.
MWRang*
106-148
Sub-Cawgori«. Sp«eifie Compounds
Inttnaty
Category
CompositJort
Othtr
5-152
-------
LRMS REPORT
SAMPLE: 8301-029-3 PETC XAD + Omc
Major Cittgorits
Intimity
Cxtt^ory MW Rang*
None detected
•
,
Sub-Cat«5ori«s. Specific Compounds
Intimity
Cannery
.
m/«
Composition
•
Gthw
5-153
-------
LRMS REPORT
SAMPLE:
8301-029-4 XAD + Omc LC Fractions 1 - 3
Major Catttorits
Inttnnty
Cattgory MWRang*
None detected
•
_
Sub-Cat»gori«, Specific Compounds <
InttmJey
Category
fc
i.
m/t
Composition
.. .
Oth«r
•
5-154
-------
LRMS REPORT
SAMPLE: 8301-029-8 XAD + Qmc LC Fraction*; 4-fi
Ma(of Cattgorits
tnunrity
Category MW R*ng«
None detected
•
(
Sub-Cattgor i«. SpceifTe Compounds ,
In tins ty
Category
w
m/«
Composition
..
: '
Othtr
5-155
-------
URMS REPORT
SAMPLE: 8301-029-11 XAD + Omc LC Fraction 7
Major Cittsorias
tnttmirp
Cm**y
None detected
•
p
MW Rang*
Sub-Ca»5ori«, Specific Compounds
Intimity
Cats^ory .
Composition
Other
5-156
-------
LSMS REPORT
SAMPLE; 8301-029-12 Bottom Ash LC Fraction 1
Major Cattgorin
Intimity
Ctt^ory MW Rang*
None detected
•
_
Sub-Cawgoriw, Specific Compounds ,
Intsraity
Cittgory
_
*»
m/t
Composition
_.
r
:•
Othtr
•
5-157
-------
REPORT
SAMPLE: 8301-029-14 Bottom Ash LC Fraction 2
Major Cittgoriw
Intansity
Category W B»fl»
None detected
-
.
Sub-Ca«gori«, Specific Compounds .
Intimity
<
Cangory
•
»
m/t
Composition
..
Other
•
5-158
-------
LflMS REPORT
SAMPig; 830k-029-T5 Bottom Ash 1C Fraction 3
Majof Cittgoriw
Intensity
Cattgory MW Rang*
None detected
.
•
Sub-Ca«sori«, Specific Compounds
Intensity
Catigory
•
m/t
Composition
_.
Oth«r
•
5-159
-------
LflMS REPORT
SAMPLE: 8301-029-16 Bottom Ash LC Fraction 4
Major Catvqorit*
Intro tity
Cattsory
None detected
•
_
MWRang*
•
Sub-Categoriw, Sptesfte Compound*
Inttnsty
Category
Composition
Other
5-160
-------
LRMS REPORT
SAMPLE; 8301-029-17 Bottom Ash 1C Fraction 5
Major Cmgorits
IntMisity
100
Category MW Range
Alkvl benzenes 106-148
•
_
Sub-Categorm, Specific Compounds ,
tnttntity
Category
^
m/t
Cornpoiition
'
"' f !
Oth«r
•
5-161
-------
LHWS REPORT
; 8301-029-18 Bottom Ash LC Fraction 6
Major CattgoriM
tntanstty
TOO
TOO
Cattgorf MW R»*9»
Alkvl benzenes 106-148
Carboxylic acids
•
Sub-Categori«, Specific Compounds
tnttnaty
Category
.
m/«
C^mposittoA
-.
r •
Oth«r
•
5-162
-------
URMS REPORT
8301-029-19 Bottom Ash LC Fraction 7
Major Cttigortar
Intanrity
Ctttgory MW Rang*
None detected
•
_
SutyCategariw. Sp«tifTc Compounds ,
Intimity
Can^ory
•
m/«
Composition
.. •
. *
: •
Other
•
5-163
-------
(This page intentionally blank.)
5-164
-------
5.9 8IOASSAY REPORTS
5-165
-------
(This page intentionally blank.)
5-166
-------
DiONETlCS 5516 Nicholson Lane. Kensington, Maryland 20895 301 881-5600'Telex 89-8369
Litton
March 22, 1983
Mr. Chris Mann
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Re: Acurex Subcontract No. RB59178A,
Release No. 5
Dear Mr. Mann:
Enclosed are five bound, and one unbound, copies of the final reports for the
one XAD resin extract and four particulate ash samples submitted for testing
and evaluation in IERL-EPA Level 1 Ames/Salmonella mutagenesis and CHO cyto-
toxicity bioassays. All studies were conducted and evaluated under IERL/EPA
Level 1 guidelines.
Sample CWM XAD + OMC (A82-11-29-2) could not be tested up to the recommended
maximum applicable dose (MAD) based upon weight of organics per plate because
of limited amount of test material. Testing with this sample was modified by
eliminating less responsive tester strains in the Ames assay and eliminating
the highest recommended dose in the CHO clonal toxicity assay.
The ranking of the five samples, the criteria used to evaluate the results,
and the critical data upon which the evaluations were based are summarized in
three attached tables.
If you have any questions or comments concerning the reports, please feel free
to contact me at (301) 881-5600, extension 536,
Sincerely,
LITTON BIONETICS, INC.
Robert R>
-------
TABLE 1
BIOASSAY SUMMARY TABLE
Technical Directive or Project No. LBI Tier Numbers 20988 and 20993
Contract NO. EPA No. 68-02-3188; Acurex Subcontract No. RB59178A. Release No. 5.
(Health Effects Tests I Ecological Effects Tests
Aquatic J Terrestrial
Freshwater/ Marine
Sample Identification
Notes
CWM
XAD + OMC
(A82-1 1-29-2)
CWM
10 + 15 um Ash
(A82-06-026-4 + 5)
CWM
3 urn + Filter Ash
(A82-06-026-3 A + B)
CWM
Bottom Ash
(A82-6-26 815534)
CWM
Baghouse Ash
(A82-5-26 815234)
L
NO
ND
ND
ND
Ua
M/L
ND/t
L/M
L
*
<* Test results. could not be evaluated and ranked because of Insufficient samole
amount supplied. Test resulted indicate low (L) toxicity or less s>ampie
ND = No Detectable Toxicity J
L - Low Toxicity
M = Moderate Toxicity
H = High Toxicity
U = Undetermined. Exact toxicity range could not be determined due to insufficient
LBi-0463 pit/so amount of sample.
5-168
-------
TABLE 2
DEFINITION OF TOXICITY CATEGORIES FOR HEALTH EFFECTS ASSAYS
01
IO
Assay3 Activity Measured
Ames
RAM
CHO
WAT
MEC
(mutagenesis)
EC50
(lethality)
EC50
(lethality)
LD50
(lethality and toxic signs)
Sample
Type
S
AL.NAL
E
S
AL
NAL
E
S
AL
NAL
E
S
AL.NAL
MADd
'5,
200
5000
1
600
20
1000
1
600
20
1000
5
5
Range of Concentration or Dosaqe
Units
rag/plate
pi/plate
L/plate
mg/ml
Ml /ml
pi /ml
L/ml
mg/ml
Ml /ml
Ml /ml
L/ml
gm/kg
ml /kg
High
<0.05
<2
<50
<0.01
<6
<0.2
<10
<0.01
<6
<0.2
<10
<0.05
<0.05
Moderate
0.05-0.5
2-20
50-500
0.01-0.1
6-60
0.2-2
10-100
0.01-0.1
6-60
0.2-2
10-100
0.05-0.5
0.05-0.5
Low Not Detectable
(ND)
0.5-5
20-200
500-5000
0.1-1
60-600
2-20
100-1000
0.1-1
60-600
2-20
100-1000
0.5-5
0.5-5
ND at >5
ND at >200
ND at >5000
ND at >1
ND at >600
ND at >20
ND at >1000
ND at >1
ND at >600
ND at >20
ND at >1000
ND at >5
ND at >5
Standard test abbreviations are as follows:
Ames: Ames Salmonella/microsome mutagenesis assay
RAM: Rabbit alveolar macrophage cytotoxicity assay
CHO: Rodent cell clonal toxicity assay
WAT: Acute J_n vivo test in rodents (whole animal test)
^Standard abbreviations for measured endpoints are as follows:
MEC: Minimum effective concentration
EC50: Calculated concentration expected to produce effect in 50 percent of population
)qft: Calculated dose expected to kill 50 percent of population
LD.
CS = Solid, AL = Aqueous liquid, NAL = Nonaqueous liquid, E = Extract and/or concentrate of unknown organic content
(use equivalent volume of SASS train gas)
dMAD = Maximum applicable dose
-------
TABLE 3
HEALTH EFFECTS CRITICAL DATA SUMMARY FORM8
Contract MB. EPA No. 68-02-3188 T^hniMi Directive or Project Mo.LBI Tier No. 20988 and site Sample CWM site code.
Acurex Subcontract No. RB59178A, 20993
Release No. 5 RAM Cylotoxicity (EC50]C Rodent Toxicity
Sample Identification
Ames CHO Clonal |
Mulagenicity Toxicity Viability
(MEC]b [ECsolc Viability Index
ATP
ATP/ Per
106 Cells
Toxic Signs'
CWM XAD + OKC
(A82-11-29-2)
CWM 10 + 15 urn Ash
(A82-06-026-4 + 5)
CWM 3 urn + Filter Ash
(A82-06-026-3 A + B)
CWM Bottom Ash
(A82-6-26 815534)
CWM Baghouse Ash)
(A82-6-26 815234)
2300 ygf
> 10 mg
> 10 mg
> 10 mg
> 10 mg
>230 ug
97 ug
1200 ug
110 ug
600 ug
nThe assays, observed parameters and evaluation criteria are presented in JERL-RTP Procedures Manual; Levei £ Environmental Assessment
Biological Tests, [EPA Contract No. 68-02-2681, Litton Bionetics, Inc., Kensington, Md.l
bMEC: Minimum Effective Concentration - Lowest concentration for any tester strain giving a mutagenic response.
CEC50: Effective concentration that reduces the observed parameter to 50 percent of the appropriate negative control.
dLDso: The dose lethal to SO percent of treated animals.
"Toxic signs are identified in a numbered list in the Level 1 manual. Only the number is reported here.
fConcentrations are per plate for the Ames assay and per milliliter of culture medium for the CHO assay.
LBI-0798 1/81
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
. REPORT NO
EPA-600/7-86-004b
2.
3. RECIPIENT'S ACCESSION NO.
•». TITLE AND SUBTITLE
Environmental Assessment of a Watertube Boiler
Firing a Coal/Water Slurry; Volume II. Data
Supplement
5. REPORT DATE __„
February 1986
6. PERFORMING ORGANIZATION CODE
. AUTHOH(S)
R. DeRosier and L. R. Waterland
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
A cur ex Corporation
P. O. Box 7555
Mountain View, California 94039
10. PROGRAM ELEMENT NO7
ii1'.' COOJTRACT/GRANT NO™
68-02-3188
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air and Energy Engineering Research Laboratory
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; 1/84 - 3/85
14. SPONSORING AGENCY CODE
EPA/600/13
is. SUPPLEMENTARY NOTES AEERIj project officer is Robert E. Hall, Mail Drop 65, 919/541-
2477. Volume I gives technical results of the work.
16. ABSTRACT
repOrj. j_s a compendium of detailed test sampling and analysis data ob-
tained in field tests of a watertube industrial boiler burning a coal/water slurry
(CWS). Test data included in the report include preliminary stack test data, boiler
operating data, and complete flue gas emission results. Flue gas emission measure-
ments included continuous monitoring for criteria pollutants; onsiSe gas chromato-
graphy (GC) for volatile hydrocarbons (C1-C6); Methods 5/8 sampling for particulate,
SO2, and SO3 emissions; source assessment sampling system (SASS) for total orga-
nics in two boiling point ranges (100 to 300 C and > 300 C), organic compound cate-
gory information using infrared spectrometry (IR)» liquid column (LC) chromato-
graphy separation, and low resolution mass spectrometry (LRMS), specific quanti-
tation of the semivolatile organic priority pollutants using gas chromatography/mass
spectrometry (GC/MS), and trace element emissions using spark source mass spec-
trometry (SSMS) and atomic absorption spectroscopy (AAS); N2O emissions by gas
chromatography electron capture detector (GC/ECD); and biological assay testing of
SASS and ash stream samples.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COSATl Field/Group
Pollution
Water Tube Boilers
Slurries
Coal
Sampling
Pollution Control
Stationary Sources
Test Data
Industrial Boilers
Analyzing
13B
ISA
11G
08G, 21D
14B
13. DISTRIBUTION STATEMENT
Release to Public
19. SECURITY CLASS (This Report/
Unclassified
21. NO. OF PAGES
213
20. SECURITY CLASS (Thispage)
Unclassified
22. PRICE
EPA Form S220-1 (9-73)
5-171
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