SEPA
            United States
            Environmental Protection
            Agency
                          EPA-600/7-86-005a

                          February 1986
Research and

Development

ENVIRONMENTAL ASSESSMENT OF
NHg INJECTION FOR AN
INDUSTRIAL PACKAGE BOILER
Volume I. Technical Results
            Prepared for
            Office of Air Quality Planning and Standards
            Prepared by
            Air and Energy Engineering Research
            Laboratory
            Research Triangle Park NC 27711

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                 RESEARCH REPORTING SERIES


Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination  of traditional  grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

    1. Environmental Health Effects Research

    2. Environmental Protection Technology

    3. Ecological Research

    4. Environmental Monitoring

    5. Socioeconomic Environmental  Studies

    6. Scientific and Technical Assessment Reports  (STAR)

    7. Interagency Energy-Environment Research and Development

    8. "Special" Reports

    9. Miscellaneous Reports

This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports in this series result from the
effort funded  under  the 17-agency Federal  Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport  of energy-related pollutants and their health and ecological
effects;  assessments of, and development of. control technologies for energy
systems; and integrated assessments  of a wide range of energy-related environ-
mental issues.
                       EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication. Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.

This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                                    EPA-600/7-86-005a
                                    February 1986
ENVIRONMENTAL ASSESSMENT OF NH3
      INJECTION  FOR AN  INDUSTRIAL
               PACKAGE BOILER
                       Volume I
                   Technical Results
                           by
             C. Castaldini, R. DeRosier, and L. R. Waterland
                      Acurex Corporation
                 Energy & Environmental Division
                      555 Clyde Avenue
                       ROJ Box 7555
                 Mountain View, California 94039
                  EPA Contract No. 68-02-3188
                  EPA Prbject Officer: R. E Hall
            Air and Energy Engineering Research Laboratory
             Research Triangle Park, North Carolina 27711
                          for

             US. ENVIRONMENTAL PROTECTION AGENCY
                Office of Research and Development
                    Washington, DC 20460

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                               ACKNOWLEDGMENTS

       The authors wish to extend their gratitude to Gordon Turl of
Getty-Mohawk Region in Bakersfield, California who agreed to volunteer the
boiler for the test program and provided valuable technical information.  The
support of E. R. Rudio of Getty-Mohawk in operating the ammonia injection
system is also appreciated.  Special recognition is also extended to the
Acurex field test team under the supervision of B. C. DaRos, assisted by J. S,
Steiner, R. Rape, R. Best, J. Holm, and M. Chips.
                                      fi

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                              TABLE OF CONTENTS



Section                                                                 Page

   1     EXECUTIVE SUMMARY  	      1-1

   2     INTRODUCTION   	      2-1

   3     PROCESS DESCRIPTION AND  PERFORMANCE  	      3-1

         3.1  PROCESS PERFORMANCE  	      3-1
         3.2  TEST CONDITIONS	      3-2

   4     EMISSION RESULTS   	      4-1

         4.1  SAMPLING  AND  ANALYSIS PROTOCOL  	      4-1
         4.2  CRITERIA  POLLUTANTS AND  OTHER VAPOR  SPECIES
              EMISSIONS	      4-4
         4.3  TRACE  ELEMENT ANALYSES  	      4-7
         4.4  ORGANIC SPECIES EMISSIONS   	      4-9

         4.4.1  GI to Cg  Hydrocarbons, TCO, and  GRAV Analysis   .  .      4-14
         4.4.2  Infrared  Spectra  of Total  Sample Extracts   ....      4-16
         4.4.3  GC/MS Analysis  of Total  Sample Extract  	      4-16
         4.4.4  Column  Chromatography   	      4-16

         4.5  RADIOMETRIC EMISSIONS   	      4-20

   5     ENVIRONMENTAL  ASSESSMENT  	      5-1

         5.1  EMISSIONS ASSESSMENT 	      5-1
         5.2  BIOASSAY  RESULTS  	      5-2

         APPENDIX A  —  SAMPLING AND ANALYSIS  METHODS 	      A-l
         APPENDIX B  —  TRACE ELEMENT CONCENTRATIONS  AND  MASS
                        BALANCES	      B-l
         APPENDIX C  —  FLOWRATE AND COLLECTION DATA	      C-l
                                    iii

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                               LIST OF  FIGURES

Figure                                                                   Page
 1-1     Typical Package Boiler Thermal DeNOx Injector  Design.  .  .       1-3
 1-2     Thermal DeNOx Performance on the  Packaged  Industrial
         Boiler	       1-8
 3-1     Thermal DeNOx Performance on Packaged  Industrial
         Boiler	       3-3
 A-l     Schematic for Continuous, Extractive Sampling  System.  .  .       A-2
 A-2     Schematic of Particulate Sampling Train  	       A-5
 A-3     Schematic of Ammonia Sampling  Train  	       A-6
 A-4     Controlled Condensation System	       A-7
 A-5     Source Assessment Sampling Train  Schematic	       A-9
 A-6     Flue Gas Analysis Protocol for SASS  Samples	       A-ll
 A-7     Exhaust Gas Analysis Protocol  	       A-12
 A-8     Organic Analysis Methodology	       A-13
 A-9     CI-GS Hydrocarbon Sampling System 	       A-14
 A-10    Schematic of Sampling Cylinder Construction  	       A-17
                                     iv

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LIST OF TABLES
Table
1-1
1-2
1-3
1-4

1-5
1-6
2-1
3-1
3-2
3-3
4-1
4-2
4-3
4-4
4-5
4-6
4-7
4-8

4-9
4-10
4-11
5-1

5-2

Boiler Operating Conditions 	

Criteria and Other Gas Species Emissions 	
Organic Extract Summary — Test 1 (Baseline) (XAD)
Extract 	
Summary of Flue Gas Emissions, pg/dscm 	
Bioassay Results 	

Boiler Operating Conditions 	
Fuel Compositions 	
Boiler Thermal Efficiency 	
Criteria and Other Gas Species Emissions 	
Particulate Emissions — EPA Method 5/17 	


Trace Element Flowrates — Test 2 NHs Injection .....
Summary of Total Organic Emissions in the Flue Gas ...
Summary of IR Spectra of Total Sample Extracts 	
Compounds Sought in the GC/MS and Their Detection
Limits 	
Results of GC/MS Analyses 	

Radiometric Activity of SASS Particulate 	
Flue Gas Species in Concentrations Exceeding 0.1 of
an Occupational Exposure Limit 	

Page
1-4
1-6
1-10

1-12
1-14
1-15
2-5
3-4
3-6
3-7
4-5
4-8
4-9
4-10
4-12
4-15
4-17

4-18
4-19
4-19
4-20

5-3
5-3

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                                LIST OF TABLES  (Concluded)
Table                                                                   Page
 A-l     Continuous Monitoring Equipment  in the  Mobile
         Laboratory	       A-4
 A-2     Gas Chromatograph Specifications	       A-16

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                                  SECTION  1
                              EXECUTIVE SUMMARY

       This  report  describes  emission  results obtained from field testing of a
oil- and  gas-fired  industrial boiler equipped with the Exxon's Thermal DeNOx
Process for  NOX  reduction.  This work  was  performed  for the Air and Energy
Engineering Research Laboratory (-AEERL) of the Environmental Protection
Agency (EPA) under  the  Combustion Modification  Environmental Assessment (CMEA)
program,  EPA contract  number  68-02-3188.   The objective of the tests was to
evaluate  criteria and  noncriteria pollutant emission in the flue gas during a
baseline  (uncontrolled) condition and  a low-NOx  (with NH3 injection)
condition.
1.1    SOURCE DESCRIPTION
       The boiler tested in the program was a packaged two-drum Zurn keystone
steam generator  equipped with an economizer and  having a maximum design
capacity  of 7.57 kg/s  (60,000 Ib/hr) superheated steam at 2.51 MPa (350 psig).
This unit, installed in 1979  at a southern California oil refinery, was
equipped  with the manufacturer's sidefire  air injection and the Thermal DeNOx
Process developed by the Exxon Research and Engineering (ER&E).
       The Thermal DeNOx Process involves  the injection of NH3 into the
convective passes of boilers for the selective noncatalytic reduction of NO in
the presence of 02-  NO reduction takes place over a temperature range of
870° to 1,200°C  (1,600° to 2,200°F).  Hydrogen can be added along with the
                                     1-1

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to lower the range of reaction temperature to  as  low  as  700°C  (1,330°F).
Multiple NH3 injection grids can also be  used  to  allow  sustained  NOX  reduction
performance with boiler load swings.
       The boiler tested in this program  utilized  only  one  injection  grid.
Details of the injection grid were not available  because they  were  considered
ER8E proprietary.  However, a typical two-drum boiler installation  of a single
grid NHs/Hg injection system is shown in  figure 1-1.  Saturated steam was
utilized to carry the NH3 to the boiler passes.   Hg injection  capability was
also available.
       Primary environmental concerns with this NOX control  technology on
full-scale combustion sources focus on the breakthrough  of  NH3, and when
sulfur-bearing fuels are burned, NH3 byproducts of ammonium sulfate,  (NH3)2 $04
and ammonium bisulfate, NfyHStty.
1.2    BOILER OPERATION AND FUELS
       The test program for this unit called for  emissions  evaluation during a
baseline test (without NH3 injection) and a test  with NHs injection for
significant NOX reduction.  Table 1-1 summarizes  the  boiler and NH3 injection
system operations during these two test conditions.   During both  tests the
boiler manufacturer's sidefire air injection was  operational.  Boiler
operation was maintained relatively constant to allow a  direct comparison
between tests and to isolate the effect of NH3 injection on emissions.
       Boiler steam flowrate was approximately 4.0 kg/s  (32,000 Ib/hr) for
both tests corresponding to a total heat  input of about  13  MW
(45 million Btu/hr).  The boiler was fired with refinery gas and  residual oil.
The refinery gas contributed about 44 percent  of  the  total  heat input.
Typically, refinery gas contributes up to 2/3  of  the  total  heat input for this
                                      1-2

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l
oo
                             (Rear View)
                                                                                                         (Plan View)
                                                                                 FIIIIIICO     Tub. UanK
                                                                                                       llortionlvl lujaclui
                                                                                          —	-V	—— _	ou>—X
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    Table 1-1.   Boiler  Operating  Conditions
Parameter
Steam:
Steam fl curate
Drum pressure
Superheater
outlet pressure
Superheater
temperature
Fuels:
Fuel oil flowrate
Refinery fuel
gas flowrate
Fuel oil heat
rate
Refinery fuel
gas heat rate
Total heat rate
Oil /gas heat
Input
Burner Settings:
Fuel oil pressure
Fuel oil
temperature
Atomizing steam
pressure
Refinery fuel gas
pressure
Swirl setting
Furnace Draft:
Window pressure
Furnace pressure
Boiler outlet
pressure
NH^ Injection System:
NH3 flowrate
NH3 header
pressure
Steam carrier
Steam carrier
pressure
Units

,"g/s
(103 Ib/hr)
MPa
(psig)
MPa
(psig)
K
cn

l/s
(gpn)
Si;3/s
(103 scfn)
MW
(10s Btu/hr)
, MW
(IDS Btu/hr)
MW
(106 Btu/hr)
Percent
MPa
(psig)
X
(-F)
MPa
(psig)
kPa
(psig)
kPa
(in. H20)
kPa
(in. H20)
Pa
(in. H20)
S/s
(Ib/hr)
MPa
(psig)
kg/s
(Tb/hr)
MPa
(psig)
Test 1«
(Baseline)

4.04
(32.0)
1.96
(270)
1.83
(250)
530
(495)

0.184
(175)
0.166
(21.3)
7.39
(25.2)
5.86
(20.0)
13.2
(«S.2)
56/44
0.41
(45)
366
(198)
0.56
(66)
120
(2.S)
4
0.85
(3.4)
0.35
(1.4)
80
(0.32)

0.105
(832)
0.410
(59.5)
Test 2
(»H3 Injection)

4.00
(31.7)
1.96
(270)
1.83
(250)
530
(495)

0.184
(175)
0.167
(21.2)
7.51
(25.6)
3.86
(ZO.O)
13.4
(45.6)
56/44
0.38
(41)
367
(200)
0.53
(62)
120
(2.5)
4
0.37
(3.5)
0.40
(1.6)
92
(0.37)
1.53
(12.1)
>1.72
(>250)
0.105
U32)
0.410
(59.5)
'Baseline test was performed over a 2-day period.  Operating data
 represent average values for these 2 days.

                            1-4

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boiler.  NHs injection  rate during test 2 was  1.53 g/s  (12.1  Ib/hr)
corresponding to a NH3/NO molar  ratio  of  about 2.5.
       Residual oil and  refinery  gas analysis  results  are  summarized  in
table 1-2.  Specific gravity  of  refinery  gas varied  from about 0.44 to 0.50
due to variations in the level of hydrogen  doping  resulting  from  refinery
process conditions.
1.3    TEST PROGRAM
       The program for  emission  measurements at the  two test  conditions
conformed to a modified  EPA level 1 protocol (reference 1-2). In  addition,
measurements for NH3 flue gas emissions were performed  to  calculate the  amount
of unreacted NH3 being  emitted under boiler and control system operations
investigated.  Flue gas  measurements were made at  the  stack  downstream of  the
boiler economizer where  the gas  temperature was approximately 188°C (370°F).
Flue gas measurement included:
       •   Continuous monitors for NOX, CO, C02,  and 02
       •   Source assessment  sampling  system (SASS)  train  sampling for organic
           and inorganic pollutant species
       •   EPA Method 5  with  water impingers and  an  EPA Method 17  backup for
           solid and condensible  particulate mass  emissions
       •   Controlled condensation system (CCS)  for  S02 and  $03
                               i
       •   Grab sample  for onsite analysis  of  gaseous  C^ to  CQ hydrocarbon by
           gas chromatography
       «   EPA Method 17 with HC1 impinger  solutions for ammonia  sampling
       In addition to this detailed test  program,  short-term  tests varying
NO molar ratio, hydrogen injection, and oil/gas  fuel ratio were performed.
The objective of these  short-term tests was to map the  performance of the
Thermal DeNOx Process over a  wide range of  system  and  boiler  operating
                                     1-5

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             Table 1-2.   Boiler  Operating  Conditions
Fuel Component/Properties
Residual Oil (Weight Percent)
Carbon, C
Hydrogen, H
Nitrogen, N
Sulfur, S
Oxygen, 0
Specific gravity
Higher heating value MO /kg
(Btu/lb)
Refinery Fuel Gas (Mole Percent)
Hydrogen, H
Methane, CH4
Ethane, C2Hg
Propane, £3^3
Butane, C^JQ
Pentane, £5^12
C6+
N2
C02
H2S
Specific gravity
Higher heating value MJ/m^
(Btu/ft3)
Combined Fuel (Weight Percent)
Carbon, C
Hydrogen, H
Nitrogen, N
Sulfur, S
Oxygen, 0
Higher heating value MJ/kg
(Btu/lb)
Test ia
(Baseline)

86.53
11.50
0.65
0.47
0.71
0.94
43.87
(18,900)

53.09
28.31
5.94
5.33
4.39
1.57
0.93
0.23
0.20
0.002
0.496
35.32
(948)

81.90
16.69
0.36
0.26
0.40
50.06
(21,570)
Test 2
(NHs Injection)

86.01
12.18
0.63
0.47
0.65
0.94
44.49
(19,170)

53.62
29.70
5.90
5.63
3.58
0.81
0.29
0.24
0.22
0.003
0.455
32.90
(883)

81.50
17.03
0.37
0.28
0.38
50.70
(21,845)
aBaseline test was performed  ober a 2-day period.  Fuel  data
 represent average values  of  fuel  analyses for each of the 2 days,
                                1-6

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parameters.  For these tests,  only  continuous  monitoring of NOX and 02 was
performed.  Results  of these  short-term tests  are illustrated in figure 1-2.
       Baseline NOX  emissions  averaged 235  ppm at 3 percent Q£ for two oil/gas
fuel mixtures  investigated.   The  figure shows  that NOX reduction with NH3/NO
ratio depends  on the fuel  mixture.   The system was less effective at the
oil/gas ratio  of 56/44 percent heat input  basis than at the lower oil/gas
ratio of 37/63 percent  (closer to the typical  operation of the unit and the
design basis for the NH3  injection  grid installed).  The addition of hydrogen
did not improve system performance  at the  lower oil/gas ratio, but resulted in
significant, further NOX  reduction  to levels below 100 ppm at the higher
oil/gas ratio.
       This can be explained  by the fact that  firing the higher oil/gas ratio
led to lower boiler  convective section gas  temperatures at the grid location,
thereby decreasing the effectiveness of NH3 alone.  Hydrogen injection to
shift the temperature window  for  the reduction reaction was effective at this
higher oil/gas ratio. For both fuel mixtures, the NOX reduction performance
appears to peak at a NHs/NO  ratio of about  2.5 with little or no additional
reduction gained with further increase in  NHs  injection rate.
       Figure  1-2 also indicates  the two test  conditions where detailed
emissions measurements were  performed.  These  test conditions, indicated by an
                               I
"X," correspond to the baseline and the low-NOx test.  The NHs/NO ratio during
the low-NOx test was  about 2.5 with the boiler oil/gas ratio of
56/44 percent.
       It is evident  that  the  ldw-NOx, Thermal DeNOx Process operation
selected for in-depth emission evaluation did  not correspond to optimum NQX
reduction performance for  which the.NHs injection system was designed and is^
capable of delivering.  However,  the test is representative of maximum
                                      1-7

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00
            ,250
                                             Legend

                         Boiler heat input = ~13 MW (45 million Btu/hr)
                         Stack Op = 2.5 to 2.8 percent

                                O  44 percent refinery gas
                                    56 percent residual oil

                                D  63 percent refinery gas
                                    37 percent residual oil

                              • •  Hydrogen injection numbers
                                    specify H9/NH-> molar ratio
                                    if known c   J

                                ®  Test points for detailed
                                    emission measurements
                        0.5
1.0      1.5      2.0      2.5      3.0       3.5

      NH3/NO (molar ratio based on inlet NO)
                        Figure  1-2.   Thermal  DeNOx  Performance  on  the Packaged Industrial  Boiler

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performance for the boiler  and  NH3  injection  operating  condition  indicated
here.  The following  section  summarizes  the  results  of  these  detailed  tests.
1.4    TEST RESULTS
       Table  1-3  summarizes criteria  and other  gas  species  emissions measured
during the two in-depth  tests.   The NH3  injection  rate  of 1.53 g/s
(12.1 Ib/hr), corresponding to  a NH3/NO  molar ratio  of  2.52,  resulted  in  a
41 percent NOX reduction.   CO emissions  showed  no  significant change;  however,
indications of'higher gaseous hydrocarbons  especially in  the  €4 to  Cg  range
were recorded.  Speculations  can only be made as to  whether these emission
increases were due to burner  conditions  (i.e.,  coking of  the  oil-burner tip
required nozzle cleaning at each operating  shift),  change in  fuel properties,
or quenching  of boiler convective flue gas  with NH3  carrier steam.
Conclusions with  regard  to  SOg  and  $03 cannot be made because of  loss  of
sample during the baseline  test.  Test 2, S02 and  503 results account  for
about 60 percent  of the  sulfur  in the fuel  with the  remainder possibly
undetected because of ammonium  sulfate formation.
       Baseline NHs emissions ranged  between  3  to  25 ppm  averaging  11  ppm
(0.23 Ib/hr).  During If^ injection,  unreacted  NH3  emissions  from two
consecutive measurements ranged between  200  and 600  ppm averaging 430  ppm
(8.4 Ib/hr).  A third measurement resulted  in NH3 concentrations  of 840 ppm
(16.0 Ib/hr).  This measurement was considered  erroneous  because  it resulted
in more 1% emitted than actually injected through the  grid.   Analyses of the
EPA Method 5  and  17 impinger  solutions also  indicated a high  concentration of
NH3 corresponding to  a stack  concentration of about  6 ppm (0.12 Ib/hr) for
baseline and  360  ppm  (7  Ib/hr)  for  the NHs injection test.  These results lend
credence to results obtained  with the ammonia emission  sampling system.
                                      1-9

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Table  1-3.   Criteria  and Other  Gas  Species  Emissions

Pollutant
As Measured By:
Continuous gas
analyses
Og. percent
063, percent
NOX , ppm
CO, ppm
Wet chemical
methods
S02, ppm
S03, ppm
NH3, ppm
Offsite gas
chromatography
N20
Onsite gas
chromatography
Cj., ppm
C2, ppm
C3, ppm
CA, ppm
Cg, ppm
Cg, ppm
Corrected Emissions
N0xe
CO
S02
S03f
NH39
NTO
Cl
C2
C3
C4
C5
C6
Total Cj to Cg
Participate Mass
Emissions:
Method 5/17 solid
Method 5/17
condensible
Inorganic
Method 5/17
condensible
organic
Method 5/17 total
SASS solid
Test 1
(Baseline)



2.6
11.7
239
31


NA
NA
U«


53


NO
NO
2.6
Ml
NO
NO
pome
234
30
MA
NA
U
52
—
—
2.5
—
—
—
2.5


-
«.


__


—
—
ng/jd
US
9.0
NA
NA
2.0
25
_
~
1.3
—
~
_
1.3


4.6
10.0


2.9


17.7
2.2
lb/106 Btud
0.263
0.02
NA
NA
0.005
0.056
—
—
0.003
—
—
—
0.003


0.01
0.023


0.007


0.042
O.OOS
Test Z
(MH3 Injection)



2.5
11. S
141
24


82
13
440b


17


0.8
0.6
NO
6.2
S.I
5.0
ppm
137
23
80
13
430
17
0.8
0.6
—
6.0
5.0
4.9
17.0


—
	


„


-
—
ng/J
67
6.9
55
13
78
8.0
0.15
0.21
—
3.2
4.3
5.0
13.0


1.8
180


0.2


182
2.6
lb/106 8tu
0.16
0.02
0.13
0.03
0.18
0.019
0.0003
0.0005
-.
0.007
0.010
0.012
0.030


0.004
0.42


0.0004


0.43
0.006
      emissions ranged from 3 to 25  ppm from three separate flue gas
  measurements
 bNH3 emissions ranged from 280 to 600 ppn from two separate flue gas
  measurements
 cDry ppm at 3 percent 02
 dOn heat input basis
 eAs N02
 fAs H2S04
 9Arithmetic average
 NA — Sample lost  in transit
 NO — Not detected
                                 1-10

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       Nitrous oxide  (^0)  averaged  about  50  ppm during  baseline  and  dropped
to 17 ppm during the  second test.  This  68 percent  reduction  in ppm  ^0
compares with the  41  percent  reduction  in  ppm NOX.
       Total particulate  matter  during  the NH3 injection test increased  by
more than one order of  magnitude.  The  largest contribution to this  increase
was from the inorganic  condensate  matter collected  in  the impinger  section.
This can be in part explained by ammonia sulfate and  bisulfate formed either
in the stack or through the particulate  sampling system.
       SASS samples were  analyzed  for organic content  and inorganic  trace
elements.  Total chromatographable organics,  hydrocarbons in  the  boiling range
of 100° to 300°C (210 to  570°F), measured  0.023 ng/J  (90 wg/dscm) for the
baseline and 0.01  ng/0  (40  ug/dscm)  for  the NH3 injection test.   Organics
measured by gravimetry  (SRAV) analysis  for hydrocarbons  having boiling points
greater than 300°C  (>570°F) were 0.29 ng/J (1,300 ng/dscm) for the  baseline
and 0.059 ng/J (240 ug/dscm)  for the NH3 injection  test.  Infrared  spectra of
the gravimetric residue suggests the pressure of aliphatic hydrocarbons  and
alcohols for both  tests.
       The XAD-2 extract  of the  baseline test, which  contained the  highest
organic content, was  also subjected  to  liquid chromatography  separation.
Table 1-4 summarizes  these  results.  There were no  discernable peaks  from
fractions 2 through 4.  These spectra indicate that,  of  the 1.2 mg/dscm  of
organic matter in the total  sample,  about  70  percent  is  aliphatic
hydrocarbons, 20 percent  is alcohols, and  10  percent  is  carboxylic acids.
       Gas chromatography/mass spectrometry analysis  of  sample extracts  was
performed to determine the  presence  and  concentration  of 58 semivolatile
organic priority pollutants.  Of these,  the only ones  detected were
                                     1-11

-------
                 Table  1-4.   Organic  Extract Summary -- Test 1 (Baseline) XAD Extract
Total GRAV
Organics3
mg
mg/dscm
Category'5
Aliphatic
hydrocarbons
Alcohols
Carboxylic
acids
LCI
3.9
0.16
LC2
<0.6
<0.02
LC3
1.2
0.05
LC4
1.9
0.08
LC5
1.6
0.06
LC6
2.5
0.10
LC7
1.6
0.06
Total
12.7
0.51
Assigned Intensity — (mg/dscm)
100 — (0.16)











100 -- (0.16)


100 -- (0.16)
100 -- (0.16)

100 -- (0.16)
100 -- (0.16)
100 -- (0.16)
0.27
0.07
0.02
aTotal GRAV sample of 31 mg; 20 mg taken  for  LC  with 8.1 mg recovered.  Total
 mg corrected in LC fractions corrected back  to  total  sample.
bSummary of organic emissions based on  IR  results

-------
naphthalene, phenanthrene, and phenol In amounts corresponding to flue gas
concentrations generally <1 yg/dscm.
       Results of spark source mass  spectrometry (SSMS) and atomic absorption
spectrometry (AAS) indicated that  inorganic trace  elements were not affected
by NHs injection.  Major elements  having flue-gas  concentrations exceeding
50 mg/dscm for both tests  included:  sulfur,  copper,  nickel,  silicon,
titanium, vanadium, zinc,  potassium, cobalt,  fluorine,  and iron.  These
emissions are most likely  the result of:
       •   Inorganic elements in the fuel  oil
       •   Erosion of metal surfaces in the hot combustion gases in the boiler
           passes including the NHs  injection  grid
       «   Erosion of sampling equipment metal  parts
1.5    ENVIRONMENTAL ASSESSMENT
       Emission Concentrations (flue gas stream species)  from both tests  were:
       »   Compared to occupational  exposure  guidelines as a  rough index  of
           the need for further monitoring
       •   The flue gas samples collected  were subjected  to bioassays
       Table 1-5 lists those pollutants emitted in the  flue gas at levels
greater than 10 percent of their respective guidelines.  NOX  emissions are
reduced at the expense of  increased  NH3 emissions.  Emissions of several
metals were above their respective guideline  limits,  however, these emissions
were not impacted by the NOX control technology.
       Bioassay tests for  health effects were  performed on the organic (XAD-2)
extracts collected by SASS.  These tests included  (reference  1-4):
       •   Ames assay, based on the  property  of Salmonella typhimurium
           mutants to revert due to  exposure  to various classes of mutagens
                                     1-13

-------
            Table 1-5.  Summary of Flue Gas  Emissions,  Mg/dscm
Species
Criteria Pollutants
and Total Organic
Emissions
CO
NOX (as N02)
SO?
c
Solid particulate
Condensable organic
particulate
Condensable inorganic
particulate
Total volatile
organics (Cj to Cg)
Total chromatographable
organics (Cy to C^g)
Total GRAV organics
Trace Elements
Silver, Ag
Platinum, Pt
Cobalt, Co
Nickel , Ni
Copper, Cu
Calcium, Ca
Beryllium, Be
Chromium, Cp
Phosphorus, P
Tungsten, W
Vanadium, V
Potassium, K
Test 1
(baseline)



36 x 103
457 x 103
NA
7.8 x 103
17 x 103
11 x 103

37 x 103

4.8 x 103

90
f\
1.3 x 103

2.13 x 103
15.7
>50.9
>82.3
>122
551
>0.619
10.3
16.2
103
51.4
72.8
Test 2
(NH3 injection)



28 x 103
270 x 103
218 x 103
307 x 103
6.7 x 103
740

670 x 103

48 x 103

40

240

75
35.7
>61.9
>63.1
>69.3
ND
ND
7.73
13.6
ND
>60.0
498
Occupational
Exposure
Guideline3



55 x 103
6 x 103
5 x 103
18 x 103
1.4 x 104
—

—

__

—

•"•

10
2
50
100
200
1.4 x 103
2
50
100
1 x 103
500
2 x 103
aThreshold limit value, reference  1-3
ND = Not detected
NA = Not available
                                     1-14

-------
       «   Cytotoxicity assay (CHO) with mammalian cells in culture to measure
           cellular metabolic impairment and death from exposure to soluble
           toxicants
Table 1-6 summarizes these results which indicate that the XAD-2 organic
extracts were of moderate or less mutagenicity and toxicity.

                        Table 1-6.  Bioassay Results
Sampl e
Baseline XAD extract
NH3 injection XAD extract
Ames
Mutagenicity
Ma
Ub
CHO
Cytotoxicity
Ijb
L|b
         aModerate mutagenicity
         ^Insufficient  sample to  evaluate,  test  results  indicate
          moderate mutagenicity  (toxicity)  or  less
                                      1-15

-------
                          REFERENCES FOR SECTION 1
1-1.  Hurst, B. E. and C. E. Schlecksen, Jr., "Applicability of Thermal  DeNOx
      to Large Industrial Boilers," Proceedings of the Joint Symposium on
      Stationary Combustion NOX Control, Volume V, Environmental  Protection
      Agency, EPA-600/9-81-028e. NTIS PB 81-236150, July 1981.

1-2.  Lentzen, D.  E., et al.,  "IERL-RTP Procedures Manual:   Level  1
      Environmental  Assessment (Second Edition)," Environmental  Protection
      Agency, EPA-600/7-78-201, NTIS  PB 293795, October 1978.

1-3.  American Conference of Governmental  Industrial  Hygienists,  Threshold
      Limit Values for Chemical Substances  and Physical  Agents  in  the Work
      Environment  With Intended Changes for 1982, Cincinnati,  Ohio, 1982.

1-4.  Brusick, 0.  J., et al.,  "IERL-RTP Procedure Manual:   Level  1
      Environmental  Assessment, Biological  Tests," EPA-600/18-81-024, NTIS
      P8 228966, October 1981.
                                     1-16

-------
                                  SECTION 2
                                 INTRODUCTION

       This report describes and presents results for a set of environmental
assessment tests performed for the Air and Energy Engineering Research Labora-
tory  (AEERL)   of EPA under the Combustion Modification Environmental
Assessment (CMEA) program, EPA Contract No. 68-02-3188.  The CMEA started in
1976 as part of EPA's Conventional Combustion Environmental Assessment (CCEA)
program with a 3-year study (NOX EA), EPA Contract No. 68-02-2160, having the
following objectives:
       «   Identify potential multimedia environmental effects of stationary
           combustion sources and combustion modification technology
       •   Develop and document control application guidelines to minimize
           these effects
       •   Identify stationary source and combustion modification R&D
           priorities
       «   Disseminate program results to intended users
       During the first year of the  NOX EA, data and methodologies for the
environmental  assessment were compiled.  Furthermore, priorities for the
schedule and level of effort for developing emission data for the various
source/fuel/control combinations were identified.  This effort revealed major
data gaps, particularly for noncriteria pollutants (organic emissions and
trace elements) for virtually all combinations of stationary combustion
                                     2-1

-------
sources and combustion modification techniques.  Consequently, a series of
seven environmental field test programs was undertaken to  fill these data
gaps.  The results of these tests are documented in seven  individual reports
(references 2-1 through 2-7) and in the final NOX EA  report summarizing the
entire 3-year effort (reference 2-8).
       The current CMEA program has, as major objectives,  the continuation of
multimedia environmental field tests initiated in the original NOX EA program.
These new tests, using standardized sampling and analytical procedures
(reference 2-9) are aimed at filling remaining data gaps and addressing the
following priority needs:
       •   Advanced NOX controls
           —  Evaluation of controls with regard to  projected New Source
               Performance Standards (NSPS)
           —  Evaluation of controls designated Best Available Control
               Technology (BACT)
       •   Alternate fuels
       «   Secondary sources
       •   EPA program data needs
           —  Residential oil combustion
           —  Wood firing in residential, commercial, and industrial sources
           --  High interest emissions determination
       •   Nonsteady-state operations
       Stringent NOX regulations in California have led  to the application of >
advanced controls  which  are capable of significant  reductions in NOX emission
from stationary combustion  sources.  Among these controls, noncatalytic
ammonia (NHs)  injection, developed  by Exxon  Research  and Engineering Company
(ER&E) as the  Thermal DeNOx Process, has  been  installed  on a number of process
                                      2-2

-------
heaters and industrial boilers in Southern California where NOX abatement
requires the application of the best  available  control technology  (BACT)
(reference 2-9).
       The Thermal DeNOx Process involves the  injection  of NH3 into  hot  flue
gas in a prescribed temperature range from about 870°C (1,600°F) to  about
1,200°C (2,200°F).  The chemical reaction of NH3 with NOX in  the presence  of
02 can be summarized  by the following two equations  (reference 2-9):

       NOX + NH3 + 02 + (H2) * N2 +  H20                                     (1)

       NH3 + 02 * NOX + H20                                                 (2)

At temperatures above approximately  1,200°C  (2,200°F), NH3 oxidizes  to  form
NOX as shown by equation 2.  At temperatures below approximately 870°C
(1,600°F) the  rates of both reactions are low,  causing the NH3 to  leave
unreacted.  At the lower range of flue gas temperature,  however, the
decomposition  of NOX  by NH3 can be accomplished by the simultaneous  injection
of H2.  The addition  of H2 together  with NH3 tends to extend  the effective
temperature range of  NOX decomposition to about 700°C (1,300°F).
       In industrial  and utility boilers, NH3  injection  takes place  in  the
convective tube banks where single or multiple  injection grids are located.
                                i
Although NOX reduction efficiencies  of over 90  percent have been achieved  in
the laboratory, full-scale applications have resulted in a maximum of 60 to
70 percent efficiency.  Temperature  and gas velocity gradients, low  residence
time at temperature,  and degree of mixing are the  primary factors  which  tend
to reduce process performance in full-scale applications.
       Potential environmental impacts resulting from application  of this
process are primarily associated with emissions of unreacted  NH3 and formation
of ammonium sulfate which adds to the total particulate  emission from the

                                      2-3

-------
source.  Other concerns such as cyanide  (HCN)  and  nitrous  oxide (N20)
formation have been addressed by  ER&E  in  the  laboratory;  however,  limited data
exists on full-scale combustion sources.   In  response  to  these  concerns,  a
medium-size industrial watertube  boiler  designed with  NH3  injection  was
selected for testing under the CMEA program.   The  objective  of  the tests  was
to quantify multimedia emission from the  boiler operating  with  and without MH3
injection, thus providing a measure of the  environmental  benefit of  NOX
reduction and potential risks associated  with  the  process.   The data presented
in this report quantify flue gas  emission  and  identify pollutants  of potential
concern using results from standardized  sampling and analytical procedures
(reference 2-10).
       Table 2-1 lists all the tests performed in  the  CMEA effort, outlining
the source tested, fuel used, combustion  modifications implemented and  the
level  of sampling and analysis performed  in each case. Results of these  test
programs are discussed in separate reports.
                                      2-4

-------
                              Table 2-1.   Completed Tests During the Current  Program
TO
en
Source
Spark-Ignited, natural -
gas-fired reciprocating
Internal combustion
engine
Compression Ignition,
dlesel-ftred,
reciprocating Internal
combustion engine
Lovr-N0x, residential,
condensing-heating
system furnished by
Karl sons Blueburner
Systems Ltd. of Canada
Rocketdyne/EPA
low-NOx residential
forced warm air furnace
Description
Large bore, 6-cy Under,
opposed piston, 186-kN
(250 Bhp)/cyl , 900-rpm
Model 38TDS8-1/8
Large bore, 6-cy Under
opposed piston, 261-kW
(35.0 Bhp)/cyl, 900-rpn
Hoder38TDD8-l/8
Residential hot water
heater equipped with
H.A.N. low-NOx burner,
0.55 ml/s (0.5 gal/hr)
firing capacity, con-
densing flue gas
Residential warm atr
furnace with modified
high-pressure burner and
firebox, 0.83 ml/s
(0.75 gal/hr) firing
capacity
Test Points
Unit Operation
-- Baseline (pre-NSPS)
— Increased air-fuel
ratio aimed at
meeting proposed
NSPS of 700 ppm
corrected to IS
percent Oj and
standard atmospheric
conditions
— Baseline (pre-NSPS)
— Fuel Injection retard
aimed at meeting pro-
posed NSPS of 600 ppm
corrected to IS per-
cent 0? and standard
a tmospner 1 c cond 1 1 1 ons
Low-NOv burner design
by H.A.N.
Low-N0x burner design
and Integrated furnace
system
Sampling Protocol
Engine exhaust:
- SASS
— Method 5
— Gas sample (CI-CR HC)
— Continuous NO, NOX> CO,
CO?, 02, CHa, TUIIC
Fuel
Lube oil
Engine exhaust:
— SASS
- Method 8
— Method 5
- Gas sample (Ci-Cg HC)
— Continuous NO, NOX, CO,
C02, 02, CH*. TUHC
Fuel
Lube oil
Furnace exhaust:
- SASS
- Method 8
— Method 5
~ Gas sample (Cj-Cj HC)
— Continuous NO, NOX, CO,
C02, 02. CH4, TUHC
Fuel
Waste water
Furnace exhaust:
— SASS
— Method 8
— Controlled condensation
— Method S
— Gas sample (Cj-Cs HC)
— Continuous NO, NOX, CO,
C02, 02, CH4, TUHC
Fuel
Test Collaborator
Fairbanks Morse
Division of Colt
Industries
Fairbanks Morse
Division of Colt
Industries
New test
New test

-------
                                               Table 2-1.   Continued
ro
a\
Source
Pulverized coal-fired
utility boiler,
Conesville station
Nova Scotia Technical
College Industrial
boiler
Adelphi University
industrial boiler
Pittsburgh Energy
Technology Center (PETC)
Industrial boiler
Description
400-HM tangent (ally
fired; new NSPS
design aimed at
meeting 301 ng/J
NOX limit
1.14 kg/s steam
(9,000 Ib/hr) firetube
fired with a mixture
of coal -oil -Mater (COM)
1.89 kg/s steam
(15.000 Ib/hr)
hot water
firetube fired with a
mixture of coal-oil-
water (COM)
3.03 kg/s steam
(24,000 Ib/hr) water tube
fired with a mixture of
coal -oil (COM)
Test Points
Unit Operation
ESP Inlet and outlet,
one test
-- Baseline (COM)
-- Controlled S02
emissions with
limestone Injection
— Baseline (COM)
— Controlled SO?
emissions with
Na2C03 Injection
— Baseline test only
with COM
Sampling Protocol
ESP inlet and outlet
— SASS
— Method 5
— Controlled condensation
— Gas sample (Ci-C6 KC)
— Continuous NO, NOX. CO.
C02, 02
Coal
Bottom ash
ESP ash
Boiler outlet
- SASS
— Method 5
— Method 8
— Controlled Condensation
-- Gas sample (C^Cs HC)
— Continuous 62, CO?.
CO. NOX
Fuel
Boiler outlet
— SASS
— Method 5
— Method 8
— Controlled Condensation
— Gas Sample (C,-C6 HC)
— Continuous 03, cbz. NOX,
CO
Fuel
Boiler outlet
— SASS
- Method S
— Controlled Condensation
— Continuous Oo, 0)9. NOX,
TUHC. CO
— NjO grab sample
Fuel
Test Collaborator
Exxon Research and
Engineering (ERSE)
conducting cor-
rosion tests
Envirocon per-
formed participate
and sulfur
emission tests
Adelphi University
PETC and General
Electric (GE)

-------
                                               Table 2-1.  Continued
PO
Source
TOSCO Refinery vertical
crude oil heater
Mohawk -Getty Oil
Industrial boiler
Industrial boiler
Industrial boiler
Description
2.54 Ml /day
(16,000 bbl/day) natural
draft process heater
burning oil/refinery gas
8.21 kg/s steam
(65.000 Ib/hr)
watertube burning
mixture of refining gas
and residual oil
2.52 kg/s steam
(20,000 Ib/hr) watertube
burning wood waste
3.16 kg/s steam
(29,000 Ib/hr)
ftretube with refractory
firebox burning wood waste
Test Points
Unit Operation
— Baseline
— Staged combustion
using air Injection
lances
-- Baseline
-- Ammonia Injection
using the noncatalytic
Thermal DeNOx
Process
— Baseline (dry wood)
— Wet (green) wood
— Baseline (dry wood)
Sampling Protocol
Heater outlet
— SASS
— Method 5
— Controlled condensation
— Gas sample (Cj-Cj HC)
— Continuous (h, NOX, CO,
CO,, HC
-- Nju grab sample
Fuel oil
Refinery gas
Economizer outlet
« SASS
- Method 5. 17
— Controlled condensation
-- Gas Sample (Cj-C6 HC)
— Ammonia emissions
-- N20 grab sample
— Continuous 0?, NO,,
CO, C02
Fuels (refinery gas and
residual oil)
Boiler outlet
- SASS
— Method 5
-- Controlled condensation
— Gas sample (Ci-Cg HC)
-- Continuous 0%, NOX, CO
Fuel
Flyash
Outlet of cyclone parttculate
collector
— SASS
— Method 5
-- Controlled condensation
— Gas sample (C(-Cg HC)
— Continuous 0?, NOX, CO
Fuel
Bottom ash
Test Collaborator
KVB coordinating
the staged com-
bustion operation
and continuous
emission monitoring
New test
North Carolina
Department of
Natural Resources,
EPA IEHL-RTP
North Carolina
Department of
Natural Resources,
EPA IERL-RTP

-------
                                                 Table  2-1.   Concluded
IN3
00
Source
Enhanced oil recovery
steam generator
Pittsburgh Energy
Technology Center
(PETC) Industrial
boiler
Description
IS MM (SO nil) ton Btu/hr)
steam generator burning
crude oil equipped with
MHI low-NOx burner
3.03 kg/s steam
(24.000 Ib/hr) watertube
fired with a mixture of
coal -water (CUM)
Test Points
Unit Operation
— Performance mapping
-- Low NO), operation
— Baseline test only
with CUM
Sampling Protocol
Steamer outlet
— SASS
— Method 5
-- Method 8
— Gas sample (Ci - C6 IIC)
-- Continuous 02, NOX, CO,
COo
-- H?0 grab sample
Fuel
Boiler outlet
— SASS
- Method 6
- Method B
— Gas sample (C, . C6 HC)
— Continuous 0?, NO., CO,
CO?. TUHC
-- N?0 grab sample
Fuel
Bottom ash
Collector hopper ash
Test Collaborator
Getty Oil Company,
CE-Natco
PETC and General
Electric

-------
                           REFERENCES FOR SECTION 2
2-1.   Larkin, R. and E. 8. Higginbotham, "Combustion Modification Controls
       for Stationary Gas Turbines:  Volume II.  Utility Unit Field Test,"
       EPA-600/7-81-122b, July 1981.

2-2.   Higginbotham, E. B., "Combustion Modification Controls for Residential
       and Commercial Heating Systems:  Volume II.  Oil-fired Residential
       Furnace Field Test," EPA-600/7-81-123b, July 1981.

2-3.   Higginbotham, E. B. and P. M. Goldberg, "Combustion Modification NOX
       Controls for Utility Boilers:  Volume  I.  Tangential Coal-fired Unit
       Field Test," EPA-600/7-81-124a, July 1981.

2-4.   Sawyer, J. W. ami E. B. Higginbotham,  "Combustion Modification NOX
       Controls for Utility Boilers:  Volume  II.  Pulverized-coal Wall-fired
       Unit Field Test," EPA-600/7-81-124b, July 1981.

2-5.   Sawyer, J. W. and E. B. Higginbotham,  "Combustion Modification NOX
       Controls for Utility Boilers:  Volume  III.  Residual-oil Wall-fired
       Unit Field Test," EPA-600/7-81-124c, July 1981.

2-6.   Goldberg, P. M. and E. B. Higginbotham, "Industrial Boiler Combustion
       Modification NOX Controls:  Volume II.  Stoker Coal-fired Boiler Field
       Test — Site A/ EPA-600/7-81-126b, July 1981.

2-7.   Lips, H. I. and E. B. Higginbotham, "Industrial  Boiler Combustion
       Modification NOX Controls:  Volume III.  Stoker  Coal-fired Boiler Field
       Test — Site B/ EPA-600/7-81/126c, July 1981.

2-8.   Water!and, L. R., et al., "Environmental Assessment of Stationary
       Source NOX Control Technologies ~ Final Report," EPA-600/7-82-034,
       May 1982.

2-9.   Hurst, B. E. and C. E. Schlecksen, Jr., "Applicability of Thermal DeNOx
       to Large Industrial Boilers," Proceedings of the Joint Symposium on
       Stationary Combustion NOX (Control — Volume V,  EPA-600/9-8l-028e,
       July 1981.

2-10.  Lentzen, D. E., et al., "IERL-RTP Procedures Manual:  Level 1
       Environmental Assessment  (Second Edition)," EPA-600/7-78-201,
       October 1978.
                                     2-9

-------
                                  SECTION 3
                     PROCESS DESCRIPTION AND  PERFORMANCE

       The boiler tested  in the  program was a packaged  two-drum  Zurn Keystone
steam generator equipped  with  an economizer and  having  a maximum design
capacity of 7.57 kg/s  (60,000  Ib/hr)  superheated steam  at  2.51 MPa  (350  psi)
and 260°C (500°F).  The boiler is designed to burn  residual  low-sulfur fuel
oil and refinery process  gas.  A typical mix  of  these fuels  is 30 percent  oil
and 70 percent gas on  a heat input  basis.  This  unit was installed  in 1979  at
a southern California  oil  refinery  and equipped  with the manufacturer's
si define air injection and the ER&E Thermal DeNOx Process.
       The NH3 injection  grid  was designed for injection of  NH3  and H£ with
steam as the carrier.  A  one-grid injection system  was  utilized.  Details  of
the grid are considered proprietary by ER&E and  thus were  not available  for
this study.  However,  the design is based on  pre-1981 technology.   Recent
improvements in the process available following  this test  program permit the
                                i
attainment of higher NOX  reduction  efficiencies  and better boiler load
following capabilities (reference 3-1).
3.1    PROCESS PERFORMANCE
       As indicated in section 2, the NOX reduction performance  of  the Thermal
DeNOx Process depends  on  the reaction temperature,  the  NHs/NO ratio, and the
addition of Hg, among  other factors.  This performance  was mapped during the
test program by conducting several  short-term tests varying  NH3/NO  molar
                                     3-1

-------
ratio, hydrogen injection and the oil/gas heat input  ratio.  For these  tests,
only continuous monitoring of NOX and Og was performed.  Results are
illustrated in figure 3-1.
       Baseline NOX emissions averaged 235 ppm at 3 percent Og.  The  figure
shows that NOX reduction with NH3/NO ratio depends on the fuel mixture.   The
system was less effective at the oil/gas ratio of 56/44 percent heat  input
basis than at the lower oil/gas ratio of 37/63 percent (more nearly the
typical operation of the unit and the design basis for the NH3 injection  grid
installed).  The addition of hydrogen did not improve system performance  at
the lower oil/gas ratio, but resulted in significant, further NOX  reduction to
levels below 100 ppm at the higher oil/gas ratio.  This can be explained  by
the fact that firing the higher oil/gas ratio led to  lower boiler  convective
section gas temperatures at the grid location, thereby decreasing  the
effectiveness of the ammonia alone.  Hydrogen injection to shift the
temperature window for the reduction reaction was effective at this higher
oil/gas ratio.  For both fuel mixtures investigated,  the NOX reduction
performance appears to peak at a NH3/NO ratio of about 2.5 with little  or no
additional reduction gained with further increase in  NH3 injection rate.
3.2      TEST CONDITIONS
         Two test conditions were selected for detailed testing and emission
evaluation.  Table 3-1 summarizes the boiler and NH3  injection system
operations during two tests conditions investigated in this study. Flue  gas
emissions were evaluated for the baseline condition,  no NHs injection but with
sidefire air injection, and for a low-NOx condition with NH3 injected at  a
rate leading to significant NOX reduction from the baseline level. Boiler
operation, including fuel mixture, was maintained relatively constant between
                                     3-2

-------
co

CO
                                                                               Legend

                                                           Boiler heat  Input =  "13 MVJ (45 million Btu/hr)
                                                           Stack  Op  = 2.5 to 2.8 percent

                                                                  O 44 percent refinery gas
                                                                     56 percent residual oil

                                                                  D 63 percent refinery gas
                                                                     37 percent residual oil

                                                               • • Hydrogen  Injection numbers
                                                                     specify H-/NH, molar ratio
                                                                     1f known  c   J
                                                                      Test points
                                                    2.0       2.5       3.0

                                                         (molar ratio)
3.5
4.0
                           N
                          Figure 3-1.  Thermal  DeNOx Performance on Packaged Industrial  Boiler

-------
   Table  3-1.   Boiler  Operating Conditions
Parameter
Steam:
Steam flowrate
Drum pressure
Superheater
outlet pressure
Superheater
temperature
Fuels:
Fuel oil flowrate
Refinery fuel
gas flowrate
Fuel oil heat
rate
Refinery fuel
gas heat rate
Total heat rate
011 /gas heat
input
Burner Settings:
Fuel oil pressure
Fuel oil
temperature
Atomizing steam
pressure
Refinery fuel gas
pressure
Swirl setting
Furnace Draft:
Window pressure
Furnace pressure
Boiler outlet
pressure
Nfh Injection System:
NH3 flowrate
NH3 header
pressure
Steam carrier
Steam carrier
pressure
Units

,kg/s
(10* ib/nr)
MPa
(psig)
MPa
(psig)
K
(°F)

I/s
(gpn)
si?3/*
(103 scfh)
MM
(10« Btu/hr)
MU
(10* Btu/hr)
MM
(10° Btu/hr J
Percent
MPa
(psig)
K
(°F)
MPa
(psig)
kPa
(psig)
—
kPa
(in. HZ0)
kPa
(in. H20)
Pa
(in. H20)
9/s
(Ib/hr)
MPa
(psig)
kg/s
(Ib/hr)
MPa
(psig)
Test 1»
(Baseline)

4.04
(32.0)
1.96
(270)
1.83
(250)
530
(495)

0.134
("5)
0.166
(21.3)
7.39
(2S.2)
5.86
(20.0)
13.2
(45.2)
56/14
0.41
(45)
366
(198)
0.56
(66)
120
(2.S)
4
0.85
(3.4)
0.35
(1.4)
80
(0.32)
—
—
0.105
(832)
0.410
(59.5)
Test 2
(NH3 Injection)

4.00
(31.7)
1.96
(270)
1.33
(Z50)
530
(495)

0.184
(175)
0.167
(21.2)
7.51
(25.6)
3.86
(20.0)
13.4
(«.6)
56/44
0.38
(*«
367
(200)
0.53
(62)
120
(2.5)
4
0.37
(3.5)
0.40
(1.6)
92
(0.37)
1.53
(12.1)
>1.72
(>250)
0.10S
(332)
0.410
(59.5)
'Baseline test was performed over a 2-day period.  Operating data
 represent average values for these 2 days.

                           3-4

-------
between both tests to allow a direct  comparison  between  tests  and  to  single
out the effects of NH3 injection  on emissions.
       These two test conditions  are  also  denoted  in  figure  3-1  by an "X".
The higher oil/gas ratio was selected for  these  tests to increase  levels  of
potential pollutants  (particulate,  sulfur, etc.) thus improving  the
detectability levels  of the sampling  and analytical  techniques described
earlier.  It is evident, then,  that the  low-NOx  operation selected for
in-depth emission evaluation did  not  correspond  to optimum NOX reduction
performance for which the  NH3 injection  system was designed  and  is capable  of
achieving.  However,  the test is  representative  of maximum performance for  the
boiler and NH3 injection operating  conditions indicated  here.
       Table 3-2 summarizes analysis  results for both residual oil and
refinery fuel gas.  Specific gravity  of  refinery gas varied  from about 0.44 to
0.50 due to variations in  the level of hydrogen  doping resulting from refinery
process conditions.   Boiler thermal efficiency,  measured by  the  heat  loss
method, averaged about 85  percent for both tests.   As shown  in table  3-3, the
largest loss is attributed to the latent heat of water from  combustion of
hydrogen contributed  primarily  by the refining gas.
                                      3*5

-------
                  Table 3-2.  Fuel Compositions
Fuel Component/Properties
Residual Oil (Weight Percent)
Carbon, C
Hydrogen, H
Nitrogen, N
Sulfur, S
Oxygen, 0
Specific gravity
Higher heating value MJ/kg
(Btu/lb)
Refinery Fuel Gas (Mole Percent)
Hydrogen, H
Methane, CH4
Ethane, C2Hg
Propane, C^Hg
Butane, CA^IQ
Pentane, C^H^
Cft*
No
C02
H2S
Specific gravity
Higher heating value MJ/m3
(Btu/ft3)
Combined Fuel (Weight Percent)
Carbon, C
Hydrogen, H
Nitrogen, N
Sulfur, S
Oxygen, 0
Higher heating value MJ/kg
(Btu/lb)
Test la
(Baseline)

86.53
11.50
0.65
0.47
0.71
0.94
43.87
(18,900)

53.09
28.31
5.94
5.33
4.39
1.57
0.93
0.23
0.20
0.002
0.496
35.32
(948)

81.90
16.69
0.36
0.26
0.40
50.06
(21,570)
Test 2
(NH3 Injection)

86.01
12.18
0.63
0.47
0.65
0.94
44.49
(19,170)

53.62
29.70
5.90
5.63
3.58
0.81
0.29
0.24
0.22
0.003
0.455
32.90
(883)

81.50
17.03
0.37
0.28
0.38
50.70
(21,845)
aBaseline test was performed ober a 2-day  period.   Fuel  data
 represent average values of fuel analyses for  each of the 2 days,
                                3-6

-------
Table 3-3.  Boiler Thermal Efficiency
Heat Loss Efficiency
Heat loss due to dry gas
Heat loss due to moisture in the fuel
Heat loss due to water from H2 combustion
Heat loss due to combustible in flyash
Heat loss due to radiation
Unmeasured losses
Total loss
Efficiency (percent)
Test 1
(Baseline)
5.5
—
8.1
—
0.7
0.5
14.8
85.2
Test 2
(NH3 Injection)
5.6
—
8.2
—
0.7
0.5
15.0
85.0
                 3-7

-------
                           REFERENCES FOR SECTION 3
3-1.   "Improved Exxon Thermal DeNOx Process," Technical Brochure, Exxon
       Research and Engineering Company, Florham Park, New Jersey,
       April  1982.
                                     3-8

-------
                                   SECTION 4
                               EMISSION RESULTS

       The objective  of  this  test program was to measure the change in organic
and inorganic  solid and  gas emissions  as  a result of NH3 injection to reduce
NOX.  Therefore,  stack gas  sampling  was performed during two test condtions:
baseline with  no  NH3  injection  and a low-NOx test with NH3 injection.  Boiler
operation and  fuel mix was  kept constant  throughout the two test conditions
investigated.
4.1    SAMPLING AND ANALYSIS  PROTOCOL
       The sampling and  analysis procedures used in this test program
conformed to a modified  EPA level  1  protocol  (reference 4-1).  In addition,
measurements for  HH%  flue gas  emissions were performed to calculate the amount
of unreacted NH3  being emitted  under boiler and control  system operations
investigated.  All emission measurements  were made in  the stack flue gas
downstream of the boiler economizer  where the gas temperature was
approximately 188°C (370°F).  Flue gas measurements included:
       «   Continuous monitors  for NOX, CO,  C02» and 02
       •   Source assessment  sampling  system  (SASS) train sampling
       •   EPA Method 5 with water impringers and an EPA Method 17 backup for
           solid  and  condensible  participate  mass emissions
       •   Controlled condensation system (CCS)  for S02 and  $03
                                     4-1

-------
       •   Grab sample for onsite analysis of gaseous C^ and Cg hydrocarbon by
           gas chromatography with flame ionlzation detection
       «   EPA Method 17 with HC1 impinger solutions for ammonia sampling
       »   Grab sample for offsite analysis of ^0 by gas chromatography with
           electron capture detection
The SASS train collects several kinds of samples for subsequent laboratory
analysis.  For these tests, flue gas particulate was collected on a heated
232°C (450°F) filter; flue gas semivolatile organics (nominally Cy+) were
adsorbed onto a porous polymer resin (XAD-2).packed into an organic sorbent
module, volatile inorganic species are trapped in impingers, and nonvolatile
inorganic species collect with the particulate on the filter and in the XAD-2
sorbent.  Description and additional information on the SASS and other
sampling systems are presented in appendix A.
       The analysis protocol for SASS train samples included:
       •   Analyzing the filter catch, ashed XAD-2 resin, and the first
           impinger solution for 73 elements using spark source mass
           spectrometry (SSMS) and for mercury using a cold vapor atomic
           absorption spectrometry (AAS) technique
       •   Analyzing the second and third impinger solutions for arsenic and
           antimony using furnace AAS techniques, and for mercury using cold
           vapor AAS
       •   Extracting the XAD-2 sorbent resin in a Soxhlet apparatus using
           methylene chloride, concentrating the extract to 10 ml, then
           determining the organic content of the extract in two boiling point
           ranges:  boiling point between 100°C  (212°F) and 300°C (570°F) by
           total chromatographable organics  (TCO) analysis and boiling point
           greater than 300°C  (570°F) by gravimetry
                                     4-2

-------
       •   Further concentrating  the  extract  to  1  ml  and  analyzing  for  the
           58 semi volatile organic  priority  pollutants  by gas  chromatography/
           mass spectrometry  (GC/MS)
       The XAD-2  sorbent  resin  extract  was also  subjected to  liquid
chromatography separation into  seven  polarity fractions on silica  gel  to  give
compound category composition  information.   In addition,  infrared  spectra were
obtained for the  gravimetric  residues of  the  extract  samples  (whole samples
and liquid chromatography fractions), and mutagenicity  and toxicity were
evaluated using the  level 1 Ames  mutagenicity and  CHO cytotoxicity  tests.
       Particulate mass emissions were  evaluated with the EPA Method 5
extractive system utilizing a  EPA Method  17  in-stack  filter.   This
configuration was selected over the conventional  EPA  Method 5, which relies
entirely on an out-of-stack heated  filter, to ensure  that collected solid
particulate would not  be  affected by  possible contribution of ammonium sulfate
and bisulfate particle deposition in  the  sampling  probe.   Particulate
emissions were measured on the  in-stack filter and by the front half EPA
Method 5 catch (probe  rinse and filter  for solid particulate)  and  by the  back
half EPA Method 5 catch (impinger section for condensible particulate).  Both
the organic and inorganic fractions of  the condensible  particulate  were
measured using ethyl ether and  chloroform extraction  of impinger solutions.
       Breakthrough  ammonia levels  were measured by passing filtered flue gas
through a solution of  0.1N hydrochloric acid  to  form  ammonium  chloride.
Ammonia levels were  measured by specific  ion  electrodes.   The  sampling system
is similar to EPA Method  17 with  the  exception of  the impinger solutions  which
contain HC1 instead  of distilled  water.
                                     4-3

-------
4.2    CRITERIA POLLUTANTS AND OTHER VAPOR SPECIES EMISSIONS
       Table 4-1 summarizes gaseous and particulate emissions measured during
the baseline and ammonia injection tests.  Baseline NOX emissions averaged
234 ppm at 3 percent 03.  The HH^ injection rate of 1.53 g/s (12.1 Ib/hr),
corresponding to a NHs/NO molar ratio of 2.52, resulted in a 41 percent NOX
reduction.  CO emissions showed no significant change.  The effect on sulfur
oxide species cannot be ascertained because emissions were not available for
the baseline test.  The average combined sulfur concentration in the two fuels
was 0.28 percent by weight corresponding to an emission rate of 110 ng/J
(0.26 Ib/million Btu) as S02«  Gaseous sulfur oxides (S02 + $03) emissions
measured during the NH3 injection test were 73 ng/J (0.17 ID/million Btu) as
SOg accounting for 67 percent of the total sulfur input.  The remaining
33 percent was not detected possibly because of ammonium sulfate formation.
       Three NH3 samples were taken for each test.  Baseline levels ranged
from "3 to 25 ppm with an arithmetic average of 11 ppm (2.1 ng/J).  Selective
ion electrode analysis of EPA Method 5 and 17 impinger solutions also
indicated that NH3 was present in the flue gas at a concentration of about
6 ppm (1.2 ng/J).  These baseline NH3 emissions were suprising in that no NH3
was injected in the flue gas during this test.  However, since some carrier
steam was flowing during the baseline test, it is possible some residual NH3
was injected in the flue gas stream, causing a minor breakthrough as well as a
possible reduction in NOX.  This explanation is highly speculative at this
time, however.
       During the NH3 injection test, unreacted NH3 emission measurements
ranged from 280 to 600 ppm (52 to 110 ng/J) with an arithmetic average of
about 430 ppm (81 ng/J).  The corresponding selective ion electrode analysis
of EPA Method 5 and 17 impinger solutions  indicated a stack NH3 concentration
                                     4-4

-------
 Table 4-1.   Criteria  and  Other Gas  Species Emissions

Pollutant
As Measured By:
Continuous gas
analyses
0?, percent
C02, percent
NOX, ppm
CO, ppm
Wet chemical
methods
S02, ppm
S03, ppm
NH3 , ppm
Offsite gas
chromatography
N20

Corrected Emissions
N0xf
CO
SO?
S039
NH3h
N20
Particulate Mass
Emissions
Method 5/17 solid
Method 5/17 condensible
inorganic
Method 5/17 condensible
Method 5/17 total
SASS solid
Test 1
(Baseline)



2.3 to 3.3 (2.6)a
10.9 to 11.9 (11.7)
232 to 248 (239)
18 to 57 (31)


NA
NA
3 to 25 (ll)b


53

ppmd
234
30
NA
NA
11
52


_ _

—
.-
..
— —

ng/je
115
9.0
NA
NA
2.0
25


4.6

10.0
2.9
17.7
2.2
Ib/million
Btue
0.268
0.02
NA
NA
0.005
0.056


0.010

0.023
0.007
0.042
0.005
Test 2
(NH3 Injection)



2.4 to 2.7 (2.5)
11.4 to 1.8 (11.6)
134 to 152 (141)
19 to 40 (24)


82
13
280 to 600 (440) c


17

ppm
137
23
80
13
430
17


._

—
~
«
— ""

ng/J
67
6.9
55
13
81
8.0


1.8

180
0.2
18c
2.6
Ib/million
Btu
0.16
0.02
0.13
0.03
0.19
0.019


0.004

0.42
0.004
0.43
0.006
^Numbers  in parentheses are  arithmetic averages  of individual  measurements
bRange of NH3 emissions from three separate flue gas measurements
cRange of NH3 emissions from two  separate flue gas measurements
dOry ppm  at 3 percent 02
eOn heat  input basis
f As N02
9AS H2S04
"Arithmetic average
NA — Sample lost in transit
                                4-5

-------
of 360 ppm (66 ng/J).  This result tends to support the high NH3 levels
measured with the NH3 sampling system (280 to 600 ppm) keeping in mind that
the HC1 solution of the NH3 sample is more effective in trapping NH3 than the
distilled water of the EPA Method 5 and 17.
       An additional NH3 emission measurement made during the low-NOx test
indicated a NH3 concentration of 840 ppm (154 ng/J).  However, this result was
disregarded as unjustifiable and was not considered in the estimation of the
average NH3 emission rate.  An explanation of the reasoning used in making
this determination follows.
       Since in the Thermal DeNOx Process one mole of NH3 is required to
decompose one mole of NO to N£ and h^O, a reduction of 30 ng/J (3.2 Ib/hr) of
the NO, as measured in test 2, would require 17 ng/J (1.8 Ib/hr) of NH3«  This
would leave about 95 ng/J (10 Ib/hr) of NHs unreacted, which should be the
upper limit of NH3 breakthrough.  This assumption is based on a gas
temperature at the injection grid sufficiently low that the rate of NHs
oxidation would be insignificant.  A low gas temperature at the injection grid
was evident from the interpretation of the hydrogen injection test results
shown in figure 3-1.  The maximum emission rate of 95 ng/J excludes the
possibility of an emission rate of 154 ng/J measured during one of three
measurements made.
       Total particulate matter measured by the EPA Method 5 and 17 increased
by more than one order of magnitude during the NH3 injection test.  The
largest contribution to this increase was from the inorganic condensate matter
collected in the impinger section.  Although this large increase of inorganic
condensate is not entirely accountable from a mass conservation viewpoint,
ammonium sulfate and bisulfate formed either in the stack or through  the
particulate sampling system contributed to this increase.
                                     4-6

-------
       Table 4-2 gives a more detailed summary of particulate emissions.  As
indicated, only the probe catch and the inorganic phase of the condensate
showed an increase during the NH3 injection test.  All other particulate
catches showed a decrease in emissions.  However, the  increase in the
inorganic condensate portion of the impingers catch was so significant that
the overall particulate emission increased by about 900 percent.  Apart from
the nozzle and in-stack filter^ which are at stack temperature (about 190°C),
the entire sampling system  is maintained at or below  120°C (250°F).  At these
temperatures, ammonium bisulfate is a liquid which can be trapped in the
sampling system as inorganic matter.
       Solid particulate matter sampled with the SASS  measured 2.1 ng/J
(0.005 Ib/million Btu) for  the baseline test and 2.3  ng/J (0.005 Ib/million
Btu) for the NHs injection  test.  These emissions are  comparable to the sum of
probe and out-of-stack filter results of the Method 5/17 sampling system.
       The increase in particulate captured by the Method 5/17 train during
NH3 injection is compatible with the results of analysis of those samples for
NH3.  Table 4-3 shows that  most of the NH3 capture occurs in the inorganic
condensate.  In the NH3 injection test, the total quantity of NH3 recovered
from the inorganic condensate increased by two orders  of magnitude.  Taken as
a whole, the Method 5/17 analyses indicate that the NH3 is in the vapor phase
of stack temperature and that the increase in condensible particulate agrees
qualitatively with the increase of vapor phase NH3 captured.
4.3    TRACE ELEMENT ANALYSES
       The oil and the SASS train samples from exhaust gas were analyzed for
65 trace elements using spark source mass spectrometry (SSMS) and atomic
absorption spectroscopy (AAS).  From these analyses, trace element flowrates
normalized to the heat input (ng/J) were calculated for both tests.
                                     4-7

-------
                                     Table 4-2.  Participate Emissions  -- EPA Method 5/17a
f
00
Test
Baseline •
HI <3
Injection
Percent
change
from
baseline
Solid Participate
Nozzle
Catch
0.557
(3.14)b
0.145
(0.08)
-74
In-stack
Filter
1.52
(8.58)
0.687
(0.36)
-56
Probe
Catch
0.191
(1.08)
0.912
(0.50)
377
Out-stack
Filter
2.44
(13.8)
0.053
(0.03)
-98
Inorganic
Condensate
Iroplnger
Rinse
0.835
(4.72)
0.425
(0.23)
-49
Aqueous
Phase
9.21
(52.0)
179.6
(98.7)
1,900
Organic Condensate
Organic
Phase
2.09
11.8)
0.073
(0.039)
-97
Aqueous
Hash
Organic
Phase
0.871
(4.92)
0.089
(0.049)
-90
Total
Participate
17.71
(100)
182
(100)
4930
                    alln1ts  are ng/J

                    bNumbers  1n parentheses represent  percent of total  emissions

-------
  Table 4-3.  Ammonia Recovery  From  EPA  Method  5/17  Train  (ug/dscm  as
Test
Basel ine
NH3 injection
Solid
Participate
38
367
Inorganic
Condensate
1,580
165,950
Organic
Condensate
968
71
Tables 4-4 and 4-5  show  the  results  of these calculations.  A mass balance,
based on the oil input and flue  gas  emissions as  the only output, is also
                         1
presented.  However, the oil  and flue gas  flowrates are presented in slightly
different units.  Trace  element  analytical  results from the oil  are presented
based on the heating value of the oil, while the  trace element analytical
results from the SASS train  are  based upon  the total heat input (oil and gas)
to the unit.  The mass balance numbers are  based  upon the flowrates (ug/s) as
listed in appendix  B.
       Some elemental concentrations are listed as either less than or greater
than a given concentration.   The less than  signs  result from reporting the
element as less than the detection limit for some or all components in the
SASS train.  Elements not detected in the  fuel oil are listed as ND.  The
greater than signs  result from a concentration in the sample greater than the
upper quantification limit of the test method.
       For the baseline  test, Ca, Br, Cl,  Cu, F,  Si, Ag, S, and W were
detected at concentrations exceeding 100 mg/dscm.  For the ammonia injection
test, only K and S  exceeded  concentrations  of 100 mg/dscm.
4.4    ORGANIC SPECIES EMISSIONS
       Organic analyses  were performed on  flue gas samples according to the
EPA level 1 protocol (reference  4-1) as outlined  in appendix A.   Volatile
                                      4-9

-------
 Table 4-4.  Trace Element Flowrates — Test 1 Baseline


El ement
Aluminum
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmi urn
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Hafnium
Hoi mi urn
Iodine
Iron
Lanthanum
Lead
Lithium
Concentration (pg/J)
Fuel
Oil
569
—
—
ND
ND
ND
6.82
15.9
ND
1,320
ND
ND
227
20.5
ND
5,230
ND
ND
ND
68.2
ND
9.1
ND
ND
ND
ND
933
ND
13.6
45.5
Output
Flue Gas
7.80
0.0311
<1.64
4.01
<0.152
<0.152
0.223
38.4
<0. 00466
135
3.6
<0. 00311
109
2.52
>12.5
>30.1
<0.152
<0.152
<0.152
105
<0.152
1.91
0.014
<0.152
<0.152
<0. 00621
21.2
<0.152
<0.971
0.518
Mass Balance
Out/ In
0.0243
—
—
>3.13
—
MM
0.0581
4.28
>0. 00364
0.182
>2.81
0.00243
0.850
0.219
>9.77
>0.0102
—
__
--
2.74
^ ^
0.373
>0.0109
__
—
>0. 00485
0.0404
_-
<0.134
0.0202
aDashes indicate trace element concentration was below
 the detection limit or had concentrations in the blank
 greater than the sample.  See appendix B for
 detectability levels applicable to each stream.
                           4-10

-------
                  Table 4-4.  Concluded
Element
Lutetium
Magnesium
Manganese
Mercury
Molybdenum
Neodymi urn
Ni ckel
Niobium
Phosphorus
Potassium
Praseodymium
Rubidium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
Concentration (pg/J)
Fuel
Oil
NO
751
45.5
0.455
ND
NO
1,230
ND
751
2,120
ND
ND
ND
ND
ND
1,480
ND
ND
2.27
5,460
ND
ND
ND
ND
ND
ND
ND
ND
205
ND
523
ND
ND
114
11.4
Output
Flue Gas
<0.152
1.28
2.13
<0.0491
6.15
<0.152
>20.2
<0.176
3.99
17.9
<0.152
<0.540
<0.152
<0.176
<0.177
>148
523
—
2.98
>252
<0.154
<0.0249
<0.152
<0.152
<0.152
<0. 00155
<0.128
13.2
25.4
<0.152
>12.6
<0.014
<0.0243
18
0.688
Mass Balance
Out/ In

0.00302
0.0832
<0.572
>4.80
«•«
>0.0293
—
0.00944
0.0150
__
—
--
--
>0.0885
>0.178
>408
--
2.32
>0.0821
— ^
>0.0194
—
—
—
>0. 00121
—
0.115
>2.83
— -
>0.0429
>0.0109
>0.0189
0.280
0.107
aDashes indicate trace element concentration was below
 the detection limit or had concentrations in the blank
 greater than the sample.  See appendix B for
 detectability levels applicable to each stream.
                           4-11

-------
Table 4-5.  Trace Element Flowrates ~ Test 2
                                                 Injection


El ement
Al umi num
Antimony
Arsenic
Barium
Beryllium
Bismuth
Boron
Bromine
Cadmi urn
Calcium
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Dysprosium
Erbium
Europium
Fluorine
Gadolinium
Gallium
Germanium
Hafnium
Hoi mi urn
Iodine
Iron
Lanthanum
Lead
Li thi urn
Concentration (pg/J)
Fuel
Oil
561
—
--
ND
ND
ND
ND
22.4
ND
583
ND
ND
135
44.8
ND
2,240
ND
ND
ND
15.7
ND
6.73
ND
ND
ND
ND
1,030
ND
13.5
6.73
Output
Flue Gas

0.0471
0.624
7.6
—
0.00157
—
0.282
0.00784
—
0.314
--
__
1.96
>15.7
>17.6
0.0314
0.0157
0.0157
11.7
— —
1.54
0.0110
__
—
0.00314
—
._
1.43
0.110
Mass Balance
Out/ In
..
—
—
>5.8
—
>0.0012
--
0.0215
>0. 00598
—
>0.239
--
__
0.0746
>12.0
>0.0134
>0.0239
>0.0120
>0.0120
1.28
— —
0.391
>0. 00837
__
—
>0. 00239
—
—
0.181
0.0279
aDashes indicate trace element concentration was below
 the detection limit or had concentrations in the blank
 greater than the sample.  See appendix B for
 detectability levels applicable to each stream.
                           4-12

-------
                  Table 4-5.   Concluded
El ement
Lutetium
Magnesium
Manganese
Mercury
Molybdenum
Neodymi urn
Nickel
Niobium
Phosphorus
Potassium
Praseodymium
Rubidium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantal urn
Tellurium
Terbium
Thallium
Thorium

Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Ytterbium
Yttrium
Zinc
Zirconium
Concentration (pg/J)
Fuel
Oil
NO
336
89.7
0.224
ND
ND
6,050
ND
135
2,240
ND
ND
ND
ND
ND
14,600
ND
20.2
2.24
> 10, 500
ND
ND
ND
ND
ND
\
ND
ND
202
ND
ND
314
ND
ND
44.8
ND
Output
Flue Gas
0.00157
—
0.473
<0.294
0.0157
0.0471
>16
—
3.45
114
__
0.0157
—
0.0314
0.0991
>14.4
19.0
—
~
>321
— —
0.00157
«
..
--

0.157
0.0628
17.6
—
0.0471
>15.2
0.0298
—
4.28
— ™
Mass Balance
Out/ In
>0. 00120
—
0.00901
<2.24
>0.0120
>0.0359
>0. 00451
—
0.0438
0.0866
__
>0.0120
—
>0.0239
>0.0756
>0. 00169
>14.5
—
~
—
__
>0. 00120
—
—
--

>0.0012
>0.0478
0.149
—
>0. 00359
>0.0829
>0.0227
—
0.163
""
aDashes indicate trace element concentration was below
 the detection limit or had concentrations in the blank
 greater than the sample.  See appendix B for
 detectability levels applicable to each stream.
                           4-13

-------
organic gas phase species having boiling points in the nominal Cj to Cg range
of -160° to 100°C (-260 to 210°F) were measured by multiple analyses of flue
gas samples using onsite gas chromatography.  SASS samples were extracted with
methylene chloride in a Soxhlet apparatus.  Volatile organic matter with
boiling points in the nominal Cj to C^g range of 100° to 300°C (210° to 570°F)
were determined in the laboratory by total chromatographable organic (TCO)
analysis of the organic module sorbent (XAD-2) and condensate sample extracts.
Nonvolatile organic species with boiling points in the nominal >C^g ran9e °f
>300°C (>570°F) were measured by gravimetric (GRAV) analysis of SASS sample
extracts including filter and probe catches.
       Infrared spectrometry (IR) was also performed on GRAV residues to
identify organic functional groups.  If total organic content in the sample
exceeded 15 mg, as determined by TCO and GRAV procedures, further analyses by
liquid chromatography (LC), with TCO, GRAV, and IR analyses of the fractions
eluted from the column were performed.  Analyses of whole extract samples on
LC fractions by low resolution mass spectrometry (LRMS) were performed in TCO
and GRAV results indicated a stream organic emission concentration of greater
than 0.5 mg/dscm.  In addition, gas chromatography/mass spectrometry (GC/MS)
analysis of total sample extracts was performed to identify specific
polynuclear aromatic and other organic compounds.  A discussion of the
analytical results follows.
4.1.1  Ci to Cfi Hydrocarbons, TCO. and GRAV Analysis
       Table 4-6 summarizes total organic emission results for the onsite GC,
TCO and GRAV analyses.  The ranges in emission for volatile hydrocarbons shown
reflect the multiple onsite GC analyses performed during each test.  The
second test showed a tenfold increase in Cj to Cg emissions from an average
                                     4-14

-------
                                Table  4-6.   Summary  of  Total Organic  Emissions  in  the Flue Gas
-P.


Organic Emission
Volatile Organic Gases
Analyzed by Qnslte GC:
Cl
C2
C3
C4
CB
C6
Total GI to Ce
Volatile Organic
Material Analyzed by
TCO Procedure:
XAD-2 cartridge and
organic module
condensate
Total C; to GIS
Nonvolatile Organic
Material Analyzed by
GRAV Procedure:
Filter
XAD-2 cartridge and
organic module
condensate
Total >Ci6
Total organlcs
Test 1
Baseline
(mg/dscm)


m
m to 0.7 (0.26)
1.4 to 11 (4.8)
ND
NP
ND
1.4 to 12 (5.1)



0.09


0.09



0.2
1.1


1.3
2.8 to 13 (6.5)
(ng/J)


ND
ND to 0.13 (0.05)
0.34 to 2.6 (1.2)
ND
ND
ND
0.34 to 2.7 (1.3)



0.023


0.023



0.006
0.28


0.29
0.65 to 3.0 (1.6)
Test 2
NM3 Injection
(mg/dscra)


ND to 3.0 (0.55)
0.27 to 1.9 (0.81)
4.2 to 7.3 (5.8)
ND to 81 (16)
ND to 82 (17)
1.9 to 66 (18)
6.4 to 240 (58)



0.04


0.04



0.08
0.16


0.24
6.7 to 240 (58)
(ng/J)


ND to 0.73 (0.13)
0.07 to 0.46 (0.20)
1.0 to 1.8 (1.4)
ND to 20 (4.0)
ND to 20 (4.1)
0.46 to 16 (4.4)
1.5 to 59 (14)



0.01


0.01



0.02
0.039


0.059
1.6 to 59 (14)
                    ND — not detected

-------
5.1 to 58 mg/dscm.  The  increase was composed  primarily  of €4 to CQ compounds.
No 04 to Cs compounds were detected during  the baseline  test.
       Volatile organic  emissions as analyzed  by  the  TCO procedure dropped to
half the baseline concentrations during the second  test.  TCO emissions are
much lower than the volatile emissions measured by  onsite GC  by approximately
two orders of magnitude.
       Nonvolatile organic emissions as analyzed  by gravimetric analysis also
decreased from the baseline test to the second test.   Total nominal  CIG+
emissions were 1.3 mg/dscm for the baseline and 0.24  mg/dscm  for the second
test.
4.4.2  Infrared Spectra  of Total Sample Extracts
       IR spectroscopy was used to identify organic functional  groups present
in the SASS samples.  The results of the  IR analysis  of  the total  extract
samples are summarized in table 4-7.  Only  the presence  of aliphatic
hydrocarbons were suggested by the IR spectra  in  the  filter and XAD extracts
from both tests.
4.4.3  GC/MS Analysis of Total Sample Extract
       Capillary column  GC/MS analyses of the  extracts of flue gas samples
collected by SASS were performed to detect  and quantify  specific POM and other
organic compounds.  The  compounds sought  in the analyses and  their respective
detection limits are listed in table 4-8.  The results of the GC/MS analysis
are summarized in table  4-9.  The only compounds  detected were naphthalene in
the baseline and naphthalene* phenanthrene  and phenol  in the  second test.
Overall, POM emissions were higher during the  second  test.
4.4.4  Column Chromatography
       Only the GRAY portion of the XAD-2 extract from the baseline test had a
high enough organic concentration to warrant LC fractionation.  The results of

-------
          Table 4-7.  Summary of  IR  Spectra  of  Total  Sample  Extracts
Test
Number
1
(baseline)

2
(NH3
injection)
Sample
Filter
XAD
Filter
XAD
Wave Number
(cm-1)
2,980
1,190
2,850
2,990
2,830
2,850
2,900
2,820
Assignment
CH alkane
C-0
C-H alkane
CH alkane
CH alkane
CH alkane
CH alkane
CH alkane
this analysis are presented  in  table  4-10.   With  the exception of fraction 2,
the fractionation indicates  a  relatively  even  distribution of organics through
all 7 fractions.  No comparison with  the  NH3 injection test is possible for
these results since no  other organic  analysis  yielded enough material  to
subject to LC fractionation.
       IR spectra were  obtained on  the  GRAV  residue of the four fractions of
the LC fractionation of the  XAD-2 extracts  from the baseline test.  Table 4-10
also summarizes those results.  There were  no  discernable peaks from fractions
2 through 4.  These spectra  indicate  primarily the presence of alphatic
hydrocarbons  (80 percent  of  recovered organics),  alcohols (20 percent) and
carboxylic acids 10 percent.   Such  interpretation agree with the expected
results of LC fractionation  which predict aliphatics in fraction 1 and
oxygenates in fractions 5 to 7.  The  IR of  the total  sample extract for this
GRAV residue  indicates  only  aliphatic hydrocarbons.
                                     4-17

-------
   Table 4-8.  Compounds Sought In the GC/MS and Their Detection Limits
               (ng/pl Injected)
                              Acid Compounds
2,4,6-trichlorophenol
p-chloro-m-cresol
2-chlorophenol
2,4-di chlorophenol
2,4-dimethylphenol
1,2,4-trichlorobenzene
                                    5      2-nitrophenol
                                    5      4-nitrophenol
                                    5      2,4-dinitrophenol
                                    5      4,6-dinitro-o-cresol
                                    5      pentachlorophenol
                                           phenol
                          Base Neutral Compounds
1,
1,
                                    1
  2-dichlorobenzene                 1
  2-diphenylhydrazine               1
  (as azobenzene)
1,3-dichlorobenzene                 1
1,4-dichlorobenzene                 1
2,4-dinitrotoluene                  1
2,6-dinitrotoluene                  1
2-chloronaphthalene                 1
3,3'-dichlorobenzidine              5
3-methyl cholanthrene               40
4-bromophenyl phenyl ether          1
4-chlorophenyl phenyl ether         1
7,12-dimethyl benz(a)anthracene     40
N-nitrosodi-n-propylamine           5
N-nitrosodimethylamine              MA
N-nitrosodiphenylamine              1
acenaphthene                        1
acenaphthylene                      1
anthracene                          1
benzo(ghi)perylene                  5
benzidine                           20
benzo(b)fluoranthene                1
benzo(k)fluoranthene                1
benzo(a)anthracene                  1
benzo(a)pyrene                      1
benzo(c)phenanthrene
bi s(2-chloroethoxy)methane
bi s(2-chloroethyl)ether
bis(2-chloroisopropy!)ether
bi s(2-ethylhexyl)phthalate
butyl benzyl phthalate
chrysene
di-n-butyl phthalate
di-n-octyl phthalate
di benzo(a,h)anthracene
dibenzo(c,g)carbazole
diethyl phthalate
dimethyl phthalate
fluoranthene
fluorene
hexachlorobenzene
hexachlorobutadi ene
hexachlorocyclopentadi ene
hexachloroethane
indeno(l,2,3-cd) pyrene
isophorone
naphthalene
nitrobenzene
perylene
phenanthrene
pyrene
                             5
                             20
                             20
                             20
                             5
                             1
40
1
1
1
1
1
1
1
1
5
40
1
1
1
1
1
1
1
1
5
1
1
1
40
1
1
                                   4-18

-------
                        Table 4-9.   Results  of GC/MS  Analyses

Naphthalene
Phenanthrene
Phenol
Baseline
(yg/dscm)
0.2
<0.04
<0.04
(pg/J)
0.05
<0.01
<0.01
NHs Injection
(wg/dscm)
0.43
0.1
1.2
(pg/J)
0.11
0.03
0.30
    Table  4-10.   Organic Extract Summary —  Test  1  (Baseline)  XAD  Extract
Total UltAV
Organ Ics*
mg
mg/dscm
Category11
Aliphatic
hydrocarbon
Alcohols
Carboxyllc
acids
LCI
3.9
0.16
LC2
<0.6
<0.02
LC3
1.2
0.05
LC4
1.9
0.08
LC5
1.6
0.06
LC6
2.5
0.10
IC7
1.6
0.06
Assigned Intensity — (mg/dscm)
100— (0.16)











100— (0.06)


100— (0.05)

100— (0.05)
100— (0.02)
100— (0.02)
100— (0.02)
Total
12.7
0.51

0.29
0.02
0.07
«Total  GRAV sample of 31 mg; 20 ng taken for LC with 8.1 mg recovered.  Total mg collected 1n LC fractions corrected
 back to total sample.
^Summary of organic emissions based on  IR results
                                             4-19

-------
4.5    RADIOMETRIC EMISSIONS
       Radiometric activities of the particulate catch from the SASS train  are
presented in table 4-11.  With the exception of alpha emissions from the  NH3
injection filter, all activities were very close to those from the filter
blank.

            Table 4-11.  Radiometric Activity of SASS Particulate
Sample
Filter blank
Baseline filter
NH3 injection filter
Activity (pCi/filter)a
Alpha
24 ± 19
23 ± 18
165 ± 39
Beta
130.8 ± 5.8
133.6 ± 7.9
108.2 ± 47.8
Gamma
<142
~145
<145
          aThe ± values are the two sigma Poisson standard deviation
           of the counting error
                             REFERENCES FOR SECTION 4
   4-1.   Lentzen,  D.  E.,  D.  E.  Wagoner,  E.  D.  Estes, and W. F. Gutknecht,
         "IERL-RTP Procedures Manual:   Level  1 Environmental  Assessment (Second
         Edition)," Environmental  Protection  Agency, EPA-600/7-78-201, October
         1978.
                                     4-20

-------
                                   SECTION  5
                            ENVIRONMENTAL ASSESSMENT

       This section discusses the  environmental  considerations  on  the
industrial boiler tested and discusses  the results  of bioassay  testing  of the
flue gas sample collected.  Flue gas  stream  species were  compared  to
occupational exposure guidelines as a rough  index to rank species  discharged
for possible further monitoring consideration.   Bioassay  analyses  were
conducted as a more direct  measure of the  potential  health effects of effluent
streams.
5.1    EMISSIONS ASSESSMENT
       To obtain a measure  of the  potential  significance  of the discharge
streams analyzed in this test program,  discharge stream concentrations  were
compared to indices which reflect  potential  for  adverse health  effects.   For
the flue gas discharge, the indices used for comparison were occupational
exposure guidelines, specifically  the time-weighted-average threshold limit
values (TLV's) defined by the American  Conference of Governmental  Industrial
Hygienists (ACIGH) (reference 5-1) were used.
       Table 5-1 lists those pollutant  species emitted in  the flue gas  at
levels greater than 10 percent of  an  occupational exposure guideline.
Emissions of silver in the baseline test were almost  two  orders  of magnitude
higher.  Platinum and cobalt were  also  higher.
                                     5-1

-------
Table 5-1.  Flue Gas Species In Concentrations Exceeding 0.1 of an
            Occupational Exposure Limit



Species
Silver, Ag
NO
S02
Platinum, Pt
Cobalt, Co
Nickel, Ni
CO
Copper, Cu
Ammonia, NH3
Calcium, Ca
Beryllium, Be
Chromium, Cr
Phosphorus, P
Tungsten, W
Vanadium, V
Potassium, K
Concentration (yg/dscm)


Baseline
2,130
457,000
NA
15.7
>50.9
>82.3
36,000
>122
7,800
551
<0.619
10.3
16.2
103
>51.4
72.8

NH3 Injection
75
270,000
218,000
35.7
>61.9
>63.1
28,000
>69.3
309,000
ND
ND
7.73
13.6
ND
>60.0
498

Occupational
Exposure
Gui del i nea
10
6,000
5,000
2
50
100
55,000
200
18,000
1,400
2
50
100
1,000
500
2,000
  threshold limit value, reference 5-1
  ND — Not detected
  NA -- Not available
                               5-2

-------
5.2    BIOASSAY RESULTS
       Bioassay tests were  performed on  the  organic  sorbent  (XAD-2)  extracts
collected by SASS.  Bioassay  results reported  here are  for health  effects
(reference 5-2).  A detailed  description of  the  biological analyses  performed
is presented in volume II  (Data  Supplement)  of this  report.   The  health
effects tests were:
       »   Ames assay, based  on  the property of  Salmonella typhimurium mutants
           to revert due to exposure to  various  classes  of mutagens
       •   Cytotoxicity assay  (CHO) with mammalian cells in  culture  to measure
           cellular metabolic  impairment and death resulting from  exposure  to
           soluble toxicants
       Table 5-2 summarizes the  results  from the Ames and CHO assays.  The
results suggest that the XAD-2 extracts  were of  moderate or  less  mutagenicity
and toxicity.

                         Table 5-2.  Bioassay  Results
Sampl e
Baseline XAD extract
NH3 injection XAD extract
Ames
Mutagenicity
Ma
CHO
Cytotoxicity
l(b
UD
         aModerate mutagenicity
         blnsufficient sample to evaluate, test results  indicate
          moderate mutagenicity (toxicity) or less
                                     5-3

-------
                           REFERENCES FOR SECTION 5
5-1.  "Threshold Limit Values for Chemical Substances and Physical Agents  in
      the Work Environment with Intended Changes for 1982," American
      Conference of Governmental Industrial Hygienists.  Cincinnati, OH,
      1982.

5-2.  Brusick, D. J., et al., "IERL-RTP Procedures Manual:  Level  1
      Environmental Assessment, Biological Tests," EPA-600/18-81-024,  NTIS
      PB22B966, October 1981.
                                     5-4

-------
                                  APPENDIX  A
                         SAMPLING AND  ANALYSIS  METHODS

       Emission test equipment was  provided by Acurex  Corporation.   Onsite
equipment included a continuous monitoring  system  for  emission measurements of
gaseous criteria pollutants  sulfur  analysis train  (controlled condensation
equipment), the SASS train for particulate  sizing  and  organic species
collection, EPA Method  17 sampling  train  for total  particulate emissions, a
modified EPA Method 5 train  for ammonia analysis,  and  GC/FID for  gaseous  (Cj
to Cg) hydrocarbon analyses.  All flue gas  emission sampling was  performed at
the stack.
       The following sections briefly describe the  equipment and  sampling
procedures used during  the evaluation of  the industrial  package boiler.
A.I    CONTINUOUS MONITORING SYSTEM
       Rack-mounted monitors and recorders  located  in  a  mobile emission
laboratory were used for continuous measurement of  NOX,  CO, C02,  and 02.
Figure A-l illustrates  the continuous flue  gas extractive sampling system and
monitors arrangement.   Flue gas was drawn through an in-stack filter and a
heated stainless steel  probe.  From the probe  the gas  was passed  through an
impinger containing an  HC1 solution.  This  was done to remove traces of NH3
thus preventing erroneous NOX reading.  From the impinger the sample passed
through a gas conditioning and refrigeration system designed to remove water.
An unheated line was then used to bring the conditioned  gas to the monitors.
                                     A-l

-------
 1.  In situ fitter 0.6u. 99.9999 percent efficient
 2.  Buct
 3.  316 stainless steel probe
 4.  Four pass conditioner-dryer, 316 stainless  steel Internals
 5.  3/8-Inch unheated Teflon
 6.  Teflon-lined sample pump
 7.  3/8-inch unheated Teflon
 8.  Rotameter
 9.  1/4-Inch Teflon tubing
10.  Calibration gas manifold
11.  Calibration gas selector valve
12.  Calibration gas cylinders
13.  Backpressure regulator
14.  Auxiliary analysis port
                                                            Duct
  Sampling
  location
Figure  A-l.   Schematic  for  Continuous, Extractive  Sampling System
                                           A-2

-------
Calibration gases were used to monitor and correct the drift in the
instruments.  The calibration gases follow the same path as the flue gas being
monitored in that both are conditioned at the stack prior to analysis.
Table A-l lists the instrumentation constituting the continuous monitoring and
flue gas extractive sampling system used in this test program.  A molybdenum
NO to NOX converter was used instead of the stainless steel converter to
prevent any residual NH3 from converting to NO.
                  \
A.2    PARTICULATE TESTS
       Particulate mass emission tests were performed using a modified EPA
Method 17 train.  The modification consisted of the addition of a 142-nm
filter in a heated oven in line between the probe  and impinger train.  A
schematic of the sampling train used is presented  in figure A-2.
A.3    AMMONIA EMISSION
       Ammonia emissions were measured using the ammonia sampling train
illustrated in figure A-3.  The train consists of  a modified EPA Method 17
train with the addition of a heated filter after the probe and the use of
0.1 N HC1 in the first two impingers instead of water.  The filters, probe
wash, sample line wash, and impinger solutions were analyzed for ammonia using
a method based upon a specific ion electrode.
A.4    SULFUR EMISSIONS
       Sulfur emissions (S02 and 503) were measured using the controlled
condensation system illustrated in figure A-4.  This sampling system, designed
primarily to measure vapor phase concentration of  503 as HgSO/^, consists of a
heated quartz probe, a Goksoyr/Ross condenser (condensation coil), impingers,
a pump, and a dry gas test meter.  Using the Goksoyr/Ross condenser, the gas
is cooled to the dew point where 503 condenses as  h^SO^  S02 interference is
prevented by maintaining the temperature of the gas above the water dew point.
                                     A-3

-------
Table A-l.  Continuous Monitoring Equipment in the Mobile Laboratory
Instrument
NO
NOX
CO
C02
02
Sample gas
conditioner
Strip chart
recorder
Principle of
Operation
Chemi 1 umi nescence
Nondispersive
infrared (NDIR)
Nondispersive
infrared (NOIR)
Fuel eel 1
Refrigerant
dry-condenser
Dual pen analog
Manufacturer
Thermo Electron
ANARAD
ANARAD
Teledyne
Hankinson
Linear
Instrument
Model
10 AR
500R
AR500

E-4G-SS
400
Range
0-100 ppm
0-500 ppm
0-1,000 ppm
0-5,000 ppm
0-1,000 ppm
0-20 percent
0-5 percent
0-25 percent
10 scfm
1-10 mV
1-100 mV
0-1 V
0-10 V
                                A-4

-------
in
-Sample nozzle

   .37 nun (diameter)
    filter
//-Probe T.C.
                                                    Probe
                                                         142 liiu  (diameter)
                                                         filter
                                                     Teflon
                                                     connecting
                                                     line
                                                                                                           Empty
                              "S"  type
                              pilot tube
                                              Ice/water
                                              bath
                                                  100 ml
                                                 each
                                                                  Snii th-Greenberg
                                                 Proportional
                                                 tehipe nature
                                                 controllers
                         AP Magnehenc
                         gauge
                                             Gas meter thermocouples
                                                                                             Fine adjustment
                                                                                             bypass valve
                                                                                                      \
                        AH orifice
                        plate      ~\
                            Digital temperature
                            indicator
                                                  Orifice All
                                                  Magnehelic
                                                                         Dry test meter
Control  module
                                                                                                                 Impinger
                                                                                                                 thermocouple
                                                                                                                        Silica  gel
                                                                                                                        dessicant
                                                                                                                    Snii th-Greenberg
                                                                                                                    inpinger
                                                                                        Vacuum  line

                                                                                        Vacuum  gauge
                                                                                     4— Coarse adjustment valve
                                                                                                                 Airtight vacuum pump
                                         Figure  A-2.   Schematic of  Participate Sampling Train

-------
f
Ok
                           Sample nozzle
                            Probe T.C.
                                                  Probe
                      \_  "S"  type
                            pilot  tube
                       AP Magnehelic
                       gauge
                                                        It' nil) (diameter)
                                                       filter
                                               Proportional
                                               tei.iperaturc
                                               controllers
                                               AH orifice
                                               plate
                          Digital  temperature
                          indicator
         Teflon
          jnnectinij
         line
                                                                                                          Empty
 Ice/viater
 bath

  100 ml
  0.1N HCL
Modified
Smi th-Greenberg
implnger
~1
   I
   I
                                                                                                                linpinyer
                                                                                                                thermocouple
                                                                                                                      Silica gel
                                                                                                                      dessicant
                                              Smi th-Greenbcrg
                                              iiiipinger
Gas meter thermocouples

          .            Fine adjustment
       ^ \  l~^     /"bypass valve
                       Control  module
                                                Orifice All
                                                Magnehelic
  Dry test meter
                                           Vacuum line
                                           Vacuum gauge
                                        4—Coarse adjustment valve

                                           Airtight vacuum pump
                                        Figure A-3.   Schematic  of  Ammonia  Sampling Train

-------
  -l/h"  quart! noitle

     316 stainless steel union
                                              -lll'lh temperature
                                                HIM tint) mantle
                                                                     Coksoyr/Ross
                                                                      condenser
          Quartz filter holder
                     Probe l.C.
       S/8" quarti prohe  V Y
                                                              Heavy Hall
                                                              1/4" 1.0.
                                                             latex tuulnq

                                                               I
                                  Heater T.C.
                        Ihernorenulalor/
                        reclrcuUlor 'O.I"C
                                    I
                                               Submersible Miter
                                               circulation
                          Condenser water hath (tl)"C;


                                            YY Yf  YY YY
                                              OlijIUl l.C.
                                                readout
       Proportional temperature
             controllers      Gas meter T.C.     flue adluslnent
                                                          Ive
                                                                    Vacuum (In;

                                                             Vacuum qauqe
                                                                          Stainless steel
                                                                          condenser heat
                                                                             enckmqer
                                                         Coane adjustment
                                                            valve
   Orifice AP
maqnehellc gauge
                                               Air tight vacuum pump
    Smith-Oreenberg
Iraplnger (100 irl 31 11

  Empty modified Smllh-
 •Grcenheri) Implnner
                                                                                                  Silica  go1 dcslcant trap
I	
                           Control module
                  Figure  A-4.   Controlled Condensation System

-------
Sulfur dioxide is collected in a 3 percent  hydrogen  peroxide  solution.   Both
S02 and 863 (as ^$04) were measured by titration with  a  0.02 N  MaOH  using
bromphenol blue and barium/thorin as the  indicators.  A more  detailed
discussion of the controlled condensation sampling system is  given  in
reference A-l.
A.5    N20 EMISSIONS
       The stack gas grab samples were extracted into stainless  steel cylinders
for laboratory analysis for ^0.  For analysis each  sample  cylinder was
externally heated to 120°C (250°F), then  a  1-ml sample  was  withdrawn  with  a
gas-tight syringe for injection into a gas  chromatograph.   The analytical
equipment consisted of a Van'an 3700 gas  chromatograph  equipped  with  a  63^
electron capture detector and a 3.65-m (12-ft) stainless  steel column packed
with Poropak Super Q, 80/100 mesh.  The injector temperature  was kept at 80°C,
the detector at 350°C, and the column temperature at 33°C.  Elution time for
N20 was approximately 5 min, with a flowrate of 20 ml/min  of  nitrogen.
A.6    TRACE ELEMENTS AND ORGANIC EMISSIONS
       Emissions of inorganic trace elements and organic  compounds  were  sampled
with the source assessment sampling system  (SASS).   Designed  for level  1
environmental  assessment (reference A-2). the SASS collects large quantities of
gas and solid samples required for subsequent analyses  of inorganic and  organic
emissions as well as particle size measurement.
       The SASS, illustrated in figure A-5, is generally  similar to the  system
utilized for total particulate mass emission tests (HVSS)  with the  exception
of:
       •   Particulate cyclones heated in the oven with the filter  to 230°C
           (450°F)
                                      A-8

-------
                                                                   Filter
10
                      Stainless
                        steel
                        sample
                        nozzel
                                    Stack T.C.
                                  Stainless steel
                                  probe assembly
                                  1/2" Tefloi)
                                    Hne
                                  Isolation
                                  ball  valve
Jaeb	
                Oven T.C.
    Sorbent cartridge
                                                           Heater controller              	
                                                                                   11  , [collector vessejl
                       Stack    I
                     velocity "TV.
                   AP magnehelic,
                      gauges
                                           Orifice All
                                          magnehelic
                                           gauge
                                                    Organic module   _^



                                                   Gas  temperature T.C.

                                                     1/2" Teflon line
                                                                                             -valve   I

                                                                                             W'Tefbnlihe
                                                                                             inrlanCAta  *
                                                                                       Imp/cooler trace
                                                                                     element collector •
                                                                                                                                Impinger
                                                                                                                                  T.C.
                                                                    -Ice bath
                                                                      600 grams
                                                                  ^—silica gel
                        Vacuum pumps
                      (10 ftJ/M each)
Heavy wall
vacuum line
                               |	Control jnodUlV-^1  J^J^^1
                                         Figure  A-5.   Source  Assessment  Sampling  Train Schematic

-------
       9   The addition of a gas cooler and organic sampling module
       •   The addition of necessary vacuum pumps
       Schematics outlining the sampling and analytical procedures using the
SASS equipment are presented in figures A-6 and A-7.  The following briefly
describe analytical procedures used in measuring stack outlet trace elements
and organic emissions.
       Inorganic analyses of solid and liquid samples from the SASS train were
performed with spark source mass spectroscopy (SSMS) for most of the trace
elements.  Atomic Absorption Spectrometry (AAS) was used for analyses of
volatile mercury (Hg), antimony (Sb), and arsenic (As).
       Quantitative information on total organic emissions was obtained by gas
chromatography for TCO and by 6RAV of particulate, XAD-2, and condensate trap
organic extracts.  IR and GC/MS were used for identification of organic
functional groups and POM and other organic species in extract samples.  LC
into seven polarity fractions, followed by IR, and LRMS of fractions containing
>0.5 mg/dscm were performed to better quantify specific organic species.
Figure A-8 illustrates the organic analysis methodology followed during the
current program.
A.7    G! TO C6 HYDROCARBON SAMPLING AND ANALYSIS
       Samples of flue gas for C^ to 65 hydrocarbon analysis were collected
using a grab sampling procedure.  Flue gas was extracted from upstream of the
induced draft fan at the same location used for the controlled condensation
sampling system.
       Samples for gaseous hydrocarbon analysis were collected using the
apparatus illustrated in figure A-9.  The equipment consisted of a heated,
0.64-cm (1/4-in.) OD pyrex-lined, stainless-steel probe fitted with a 7M
sintered stainless steel filter at the probe  inlet.  The outlet of the probe
                                     A-10

-------
                                                                                                             =    n
SAMPLE

3- CYCLONE
ICYtiOMF - 	 - 	 -'

PRCIR? WA?U err —

SOnBENT CARTRIDGE
AQUEOUS CONOENSA7E
£1RCT IMPIMTPH
SECOND AND THIRD
M 2
So 2
$ r§ i
i si § S
i si « I
5 »g S §
M O O O M



^^SpCir
	 	


*
\ ,
^x
SPLIT \_
S GRAMS
^ AOUSOUS PORTION
\. ORGANIC EXTRACT


> GRAV
TCO
> LC in tnMS
PAnn/ACID DIGESTION
SSMS


• ^
»m
«, . .. • _

«__ -eV—
COMBINE
x
s~~







   TOTALS
                                                                                2   S
                                                                                                            6    1
 • If required tuple should be m isldi for btologlcil intlysts tt tins point.

1Tli(i sttp Is rewind to define the toul MSS of pirtlcutttt ntelt.  If tke suvle eioeds
 10> of the toul cyclone 
-------
ro
                                       Figure  A-7.   Exhaust Gas Analysis Protocol

-------
                             Organic Extract
                                   or
                           Jeat Organic Liquid
                                                         TCO Analysis
                                Concentrate
                                  Extract
GC/MS Analysis,
POM, and other
organic species
Infrared  Analysis
Gravimetric
                             Aliquot containing
                                 15-100  mg
 Repeat TCO
  Analysis
if necessary
                                                        o\

                                                        
-------
0.7 yni sintered stainless-steel  filter
      1/4-in.  stainless-steel
        probe
                                                    Teflon diaphragm pump

                                                       Pressure gauge
                                                            Inlet valve
                                          500-cm  stainless-steel
                                            sample cylinder
                             _l\\\\\\\\\\t\tt\\V\\\\\Xl\I
                                                                /
                                            Ceramic insulation -/
                                              and heat tape

                                                    Resistive heat tape
                                                                                                       Outlet
                                                                                                         valve
                                                                                                          1
                                                                                              Thermocouple
                                                                             Proportional
                                                                             voltage
                                                                             controller
Figure A-9.
                                                Hydrocarbon Sampling System

-------
was directly attached to a diaphragm vacuum pump which was in turn attached to
a 500-ml stainless steel heated  sampling cylinder.  The  sampling bulb was
insulated with heat tape powered by a varying  voltage controller.  The  heating
jacket kept the sample gas above the dew point to minimize sample loss  due to
water condensation.  A detailed  schematic  of the sampling bulb  is shown in
figure A-10.
       Prior to sampling, the gas  bulb was purged with stack gas for 3-min and
then sealed.  The trapped flue gas was then analyzed onsite with a Varian Model
3700 gas chromatograph  (GC)  equipped with  flame  ionization detector.  Table A-2
lists the design specifications  of the Varian  GC.   A 1.85-m (6-ft) long,
0.32-cm (1/8-in.) diameter stainless-steel column packed with  Porapak Q 60/80
mesh was used to separate the hydrocarbons into  their respective components
(GI to Cg).  The GC was calibrated with repeated injections of  a Scott
Specialty standard gas containing  Cj to CQ hydrocarbons  (each  having a
concentration of 15 ppm).  The chromatographic responses for the standards and
the samples were recorded on a Hewlett Packard Model 3390A reporting
integrator.
                                     A-15

-------
           Table A-2.  Gas Chromatograph Specifications
Varian Model 3700 Gas Chromatograph
    Sensitivity
    Zero range
    Noise (input capped)
    Time constant
    Gas required
1 x 10~12 A/mV at attenuation 1 and
range 10~12 A/mV
-lO'11 to 10'9 A (reversible with
internal switch)
5 x lO"15 A; 0.5 uV peak to peak
220 ms on all ranges (approximate Is
response to 99 percent of peak)
Carrier gas (helium), combustion air,
fuel gas (hydrogen)
                               A-16

-------






               Ceramic fiber insulation
                   *-••-*•'•'•'-**••"•"*••"-''•«'•* ••>>••' • *>r-"*.-aJ*-~<.->.'Z ............. .i-".-.^s-...


                                              Thprmnrnunlo  -»
Thermocouple
                  Heat tape
Stainless-steel  sample valve
                                                                                                           Stainless-steel
                                                                                                           sample valve
                           Figure A-10.  Schematic of  Sampling Cylinder Construction

-------
                           REFERENCES FOR APPENDIX A
A-l.  Maddalone, R., and N. Gainer.  "Process Measurement Procedures:
      Emissions," EPA-600/7-79/156, July 1979.

A-2.  Lentzen, 0. E., et al.s "IERL-RTP Procedures Manual:  Level 1
      Environmental Assessment (Second Edition)," EPA-600/7-78-201, October
      1978.
                                     A-18

-------
                                   APPENDIX B
                 TRACE ELEMENT CONCENTRATIONS AND MASS BALANCES

        Symbols  appearing in the tables:
            dscm   Dry standard cubic meter at 1 atm and 20°C
            meg     Microgram
            ppm     Parts  per million by weight
            ng/J   Nanogram per joule heat input
            <       Less  than
            >       Greater than
            N       Element not analyzed
            U       Unable to determine
        Trace  elements having concentrations less than the detectable limit or
having  a blank  value  greater than  the sample value were given an arbitrary
concentration of zero.   Values in  the form A < x < B were determined by letting
elements reported  as  less than concentration be represented by a concentration
of zero for the low value and the  reported concentration as the high value.
        Detectability  limits  for the various samples were the following:
        •    Particulate      <0.001  wg/cm2
        •    Filter  XAD-2     <0.2 ug/g
        o    Impingers        <0.002  ug/ml
        •    Fuel  oil         <0.1 ug/g
At standard conditions of 20°C  (68°F)  and  1 atm,  one  gram  mole of an ideal  gas
occupies 24.04  liters.
                                      B-l

-------
      PPM

      ELEMENT

      ALUPINUM
      ANTIMCNV
      ARSENIC
      BARIUM
      BERYLLIUM

      BISMUTH
      BORON
      BRCMINE
      CADMIUM
      CALCIUM

      CERIUM
      CESIUM
      CHLORINE
      CHROMIUM
      COBALT
                                    MLHAnK
                                  UASLLIUE
                             PPM
                     FUEL  OIL

                     .25CE+02
                     .0  6*00
                     .0  E + 00
                    <.1COE+00
                    <.1COE+00

                    <.1GOE+00
                     .3COE+00
                     .7COE+00
                    <.IGOE+00
                     .5EOE+02

                    <. IOOE+00
                    <. 1006*00
                     .ICOE+02
                     .9 00 E+00
                    <. IOOE+00
                      FILTER

                    U.C  E*00
                      .162E»02
                     .0  E»CO
                     .0  E*00

                     .0  E+00
                     ..803E«-04
                     .0  E*CO

                     .0  E+00
                     .0  E+00
                     .810E+02
                     .0  E+00
                    U.O  E+00
                     XAG-2
                                   1ST  IPPINGER  C UMC   2NU (. 3RD  IMPINOLKS
  .610E+01
  .0   E+00
  .0   E+00
  .200E+C1
 <.1COE+00

 <.IOOE+00
  .0   E+00
  .300E+02
 <.IOOE+00
  .110E+02

  .2UOE+01
 <.IOOE+00
  .130E+02
  .0   E+00
 <.IOOE+00

  .^OOE+OL
 <.IOOE+00
 <.IOOE+00
 <.IOOE+00
  .700E+OL

 <.IOOE+00
  .400E+00
 <.IOOE+00
 <.IOOE+00
 <.IOOE+00

 <.IOOE+00
 <.IOOE+00
 <.IOOE+00
  .500E+01
 <.IOOE+00

 <.IOOE+00
  .300E+00
 <.IOOE+00
  .100E+01
  .160E+01

 <.150E+00
  .310E+01
<.IOOE+00
  .200E+01
 <.IOOE+00

 <.IOCE+00
 <.IOOE+00
 .300E+01
 .300E+01
  .0   E+00
  .0   E+OQ
  .0   E+00
  .600E-01
<.1CCE-02

<.1CCE-02
  .600E-02
  .0   £+00
<.10CE-02
  .50CE+01

<.ICOE-02
<.100E-02
  .380E+01
  .720E-01
  .40CE-02

  .390E+00
<.10CE-02
<.IOOE-02
<.100E-02
  .39IE+01

<.100E-02
  .90CE-02
<.100E-02
<.IOOE-02
<.100E-02

<.100E-02
<.IOOE-02
<.100E-02
0.6 ICE+00
<.IOOE-02

  .400E-01
  .300E-02
<.10CE-02
  .0   E+00
  .100E-02

  .10CE-02
  .900E-01
<.100E-02
  .94CE-Q1
<.200E-02

<.1CCE-C2
<.1CCE-02
  .0   E+00
<.ICC£-02
  .0   E+00
                                                           N.O   E+CO
                                                           <.5006-02
                                                           <.iCOE-Cl
                                                           N.O   E+CC
                                                           N.O   £+00
N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.G
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O
E+00
E + CO
E + 00
E+00
E + CC

E+00
E + 00
E + CO
E+00
E + CC

E+00
E+00
E + CC
E + GO
E+00

E+00
E+00
E+CO
E+CO
E+00

E+00
E+00
E+OC
E+CO
E+CO

E+OG
E+00
E+00
E+00
E+CC
                                                            .100E-02
                                                           N.G  E+CC
                                                           N.O  E+OC
                                                           N.O  £+00
                                                           N.O  E+CO
                                                           N.O
                                                           N.O
                                                           N.O
                                                           N.O
     E+00
     E + CC
     E+CO
     E+OG
     E + CC

-------
    PPM

    ELEMENT

    PRASEODYMIUM
    RHENIUM
    RHCDIUM
    RUBIDIUM
    RUTHENIUM

    SAMARIUM
    SCANDIUM
    SELENIUM
    SILICON
    SILVER

    SCDIUM
    STRONTIUM
    SULFUR
    TANTALUM
    TELLURIUM

    TERBIUM
    THALLIUM
    THORIUM
    THULIUM
    TIN

_   TITANIUM
 I   TUNGSTEN
"   URANIUM
    VANADIUM
    YTTERBIUM

    YTTRIUM
    ZINC
    ZIRCONIUM
         PPM
                MbhAnK
              OASELINE
 FUEL OIL

<.1COE+00
<.ICOE«-00
<.IOOE+00
<.IOOE+00
<.KCE + 00

<.ICOE+00
<.ICOE»00
<.100E+00
 .650E+02
<.1CCE»00

<.200E+00
 .IOOE+00
 .2AOE+03
<.ICOE»00
<.1COE+00

<.UOE+00
<.100E+00
<.700E+00
<.100E+00
<.IOOE+00

 .900E+01
<.7COE+00
<.5COE»00
 .230E*02
<.100E+00

<.100E«-00
 .5COE+01
 .500E*00
 FILTER

 .0  E»00
 .0  E+CO
 .0  E*00
 .0  E*00
 .0  E*CO

 .0  E*00
 .0  EtOO
 .5S1E<-02
U.O  E*CO
 .0  E+00
<.eic£+co
 . 130E*02

 .0  E*CO
 .0  EtOO
 .0  E+00
 ,aioE*cc
 .0  E*00

U.O  E*00
<.891E*01
 .0  E»00
 .729E*01

 .0  E*00
 .0  E«CO
 .0  E»00
  XAD-2
1ST IKPINCEK C CMC  2ND C 3KO  IHP1NGEHS
<.100E*l)0
<.100E«-00
<.IOCE+GO
<.100E»00
<.IOOE+00

<.ICOE*00
<.100E»00
<.10QE*00
 .103E+03
 .37TE*03

 .0  E*00
 .2lOE»Ol
 .600£f01
<. 1COE«-00
<.100E*00

<.100E«-00
<.10CE*00
<.tOOE*00
<.10QE*00
<.100E+00

 .900E*01
 . 198E*02
<.100E*00
 .500E*00
<.10CEK)0

<.100E»00
 .0  E«-00
 .500E«00
     <.10CE-C2
     <.100E-02
     <.ICCE-02
     <.17CE-C1
     <.100E-02

     <.ICCE-02
     <.200E-02
      .0  E+00
      .100E»OC
      .LTOE+Ol

     U.O  E+00
      .12CE-01
     >.990E+Ol
     <.ICCE-02
     <.LOCE-02

     <.100E-02
     <.IOCE-02
     <.IOOE-02
     <.IOOE-02
      .0  E+00

      .700E-01
     <.1COE-02
     <.IOOE-02
      .100E-02
     <.1COE-02

      .1OOE-02
      .7
-------
CD
I
 MASS/HRAT INPUT

 ELEMENT

 ALUMINUM
 ANTIMONY
 ARSENIC
 BARRM
 BEPHLIUP

 BISMUTH
 BGRCM
 BRCKIK'E
 CAOfIUM
 CALCIUM

 CERIUM
 CESIUM
 CHLORINE
 CHROMIUM
 CQOALT

 COPPER
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GADCLIMUM
 GALLIUM
 GERMANIUM
 GOLD
 HAFNIUM

 HOLMIUM
 IODINE
 IRIOIUM
 IRCf>,
 LANTHANUM

 LEAD
 LITHIUM
 LUTETIUM
 MAGNESIUM
 MANGANESE

 MERCURY
 MOLYBDENUM
 NEGDYHIUH
 NICKEL
 NIOBIUM

OSMIUM
 PALLADIUM
 PHCSPHCRUS
 PLATINUM
 POTASSIUM
                                  NG/J
                                          MCHAnK
                                       BASELINE
                           FILTER
                             .0  E+00
                             .311E-04
                             .1406-02
                             .0  E+GC
                             .C  E+CC

                             .0  E+OC
                             .777E-C4
                             .4666-04
                             .4666-05
                             .0  E+00

                             .0  E+00
                             .3116-05
                             .0  E+00
                             .777E-C3
> .155E-01
  .0  E+OC
  .0  E+OC
  .0  E+ac
  .0  E+ac

  .0  E+00
  .I18E-02
                            .0  E+OC
                            .C  E+CC

                            .0  E+00
                            .621E-05
                            .C  E+00
                         U  .0  E+00
                            .0  E+00

                            .0  E+00
                            .621E-04
                            .0  E+00
                         J  .0  E+CC
                            .621E-04

                          < .311E-05
                            .0  E+00
                            .0  E+00
                          > .154E-01
                            .0  E+CC

                            .C  E+CC
                            .0  E+CC
                            .155E-C3
                            .0  E+OC
                         li  .C "E
  XAD-2

   .780E-02
   .0  E+00
   .0  E+00
   .2566-02
 <  .128E-03

 <  . 128E-03
   .0  E+00
   ,38«E-01
 <  .128E-03
   .141E-01

   .358E-02
 <  .120E-03
   .1666-01
   .0  E+00
 <  .1286-03

   .5UE-02
 <  .128E-03
 <  .1286-03
 <  . 128E-03
   .8956-02

 <  . 128E-03
   .5116-03
 <  .1286-03
 <  .128E-03
 <  .128E-03

 <  .1286-03
 <  .1286-03
 <  .1286-03
   .639E-02
<  .1286-03

<  .128E-03
   •384E-03
<  .1266-03
   .128E-02
   .2056-02

<  .192E-03
   .3966-02
<  .1286-03
   .256E-02
<  .128E-03

<  .12BE-03
<  .1286-03
   .3B4E-02
  .384E-02
   .179E-01
1ST IMP1NGER & CMC

        .0  E+00
        .0  E+00
        .0  E+00
       . .1466-02
      < .243E-04

      < .243E-04
        .146E-03
        .0  E+00
      < .243E-04
        .1216+00

      < .243E-04
      < .2436-04
        .9226-01
        .175E-02
        .971E-04

        .946E-02
      < .243E-04
      < .2436-04
      < .2436-04
        .9636-01

      < .2436-04
        .2186-03
      < .2436-04
      < .243E-04
      < .2436-04

      < .2436-04
      < .243E-04
      < .243E-04
     0  .148E-01
      < .243E-04

        .971E-03
        .7286-04
                                          .0  E+00
                                          .2436-04

                                          .2436-04
                                          .218E-02
                                        <  .2436-04
                                          .2286-02
                                        <  .4856-04

                                        <  .243E-04
                                        <  .2436-04
                                          .0  E+00
                                        <  .2436-04
                                          .0  E+00
2ND 6
K
3RD 1
.C
MPINUI
E+00
< .124E-U3
< .49UE-03
K
N
K
N
N
K
to
N
K
K
K
k
tt
K
N
N
N
N
N
N
K
*
*
K
N
N
N
N
N
N
N
K
.0
.0
.0
.0
.0
.C
.C
.C
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
-.0
.C
.C
.0
.C
.C
.0
.0
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
.2496-04
h
K
K
N
K
K
|v
K
.0
.0
.0
.0
.0
.0
.0
.C
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
                            .0   E+00
    STACK GAS

       .78Qt-02
.3UE-C4O<.i:>5E-03
.140E-02 .125E-01

     > .301E-01
     < .152E-03
     < .1526-03
     < .152E-03
       .105E+00

     < U52E-03
       .1S1E-02
.140E-04 .2C2E-01
     < .176E-03

     < .152E-03
     < .152E-03
       .399E-02
       .386E-02
       .17SE-01

-------
CD
I
cn
MASS/HEAT INPUT

ELEMENT

PRASEODYMIUM
RHENIUM
RHODIUM
RUBIDIUM
RUTHENIUM

SAMARIUM
SCANDIUM
SELENIUM
SILICON
SILVER

SCCI UP
STFCMIUH
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THORIUM
THULIUM
TIN

TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

YTTRIUM
ZINC
ZIRCONIUM
                                      HOHAViK
                                    BASELINE
                               NG/J
                       FILTER
                         .0  E+00
                         .0  E + OC
                         .0  E+CO
                         .0  E+OC
                         .0  E+CC

                         .0  E+CO
                         .0  E+OC
                         .113E-02
                       > .U3E-CI
                         .0  E+CC
                         .0  E+00
                         .435E-02
                         .155E-05
                         .249E-04

                         .0  E+00
                         .0  E+00
                         .0  E+00
                         .155E-C5
                         .0  E+00
U  .0  E+OC
 < .171E-04
   .0  E+OC
 > .120E-OI
   .UOE-04

   .0  E+00
   .0  E+00
   .0  E+00
                      XAC-2

                       .128E-03
                       .12BE-03
                       .128E-03
                       .128E-03
                       .128E-03
                     < .128E-OJ
                     < .128E-03
                     < .128E-03
                       .132E+00
                       .482E+CO

                       .0  E+00
                       .2686-02
                       .767E-02
                     < .128E-03
                     < .1286-03
                     < .128E-03
                     < .128E-03
                     < .128E-03
                     < .128E-03
< .128E-03

  .115E-01
  .253E-01
< .128E-03
  .639E-03
< .128E-03

< .128E-03
  .0  E+00
  .639E-03
              1ST IMPINCER I OMC  2ND C  3R0  IMPINUERS
                    < .243E-04
                    <
                    < .413E-03
 < .2*36-04
 < .'iU5E-0'i
   .0  E+00
   .243E-02
   .413E-01

U  .0  E+00
   .291E-03
 > .24CE+CO
 < .243E-04
 < .243E-04

 < .243E-04
 < .243E-04
 < .243E-04
 < .243E-04
   .0  E+00

   .170E-02
 < .243E-04
 < .243E-04
   .243E-04
 < .243E-04

   .2436-04
   .180E-01
   .485E-04
N
N
N
K
N
N
iv
iv
N
N
N
N
N
N
N
N
K
K
K
N
K
N
N
N
N
N
N
ft
.C
.C
.0
.0
.0
.0
.0
.0
.0
.C
.0
.C
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.C
.0
.0
.C
E + CO
6*00
E+00
E+00
£ + 00
E+00
E-»00
E + 00
E+00
E+00
E+00
E + 00
E + 00
E + 00
E + 00
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E + 00
E + 00
E+00
E+00
E+00
E+00
    STACK GAS

     < .15 .148E+00
       .523E+00

       .0  E + 00
       .2S8E-02
     > .2526*00
     < .154E-03
.249E-04OK.177E-03

     < .152E-03
     < .152E-03
     < .152E-03
.155E-05 .I26E-01
. 140E-04
-------
         .i Ml A?
                                       'IAM.LI .1
                                  NC/J
00
 ALUMINUM
 ANT IMC-NY
 ARSENIC
 SAP! UN
 BEKtLLlL-M

 UISMLTH
 BCJKON
 8RCMINE
 CADMIUM
 CALCIUM

 CERIUM
 CESIUM
 CHLCPINE
 CHRCHIUP
 CCBALT

 CCPPEP
 DYSPRCSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GACGUN1UM
 GALLIUM
 GERMANIUM
 GCLD
 HAFNIUM

 HCLMIUH
 IODINE
 1RIDIUM
 IRCN
 LAMHANUH

 LEAD
LITHIUM
LUTE1IUM
MAGNESIUM
MANGANESE
                          FUEL CIL

                            .S69E»OC
                            .0  L*00
                            .C  E»OC
                          <  .227E-02
                          <  .22/E-C2

                          <  .227E-02
                            .6t)2E-C2
                            .159E-CI
                          <  .227E-02
                            .132E»01

                          <  .227E-02
                          <  .227E-C2
                            .227£»00
                            .205E-01
                          <  .227E-02
                           .523E»Ol
                         < .227E-Q2
                         < .227E-02
                         < .2276-02
                           .682E-CI
                         < .227E-02
                           .9IOE-02
                         < .227E-02
                         < .227E-02
                         < .227E-Q2

                         < .227E-Q2
                         < .227E-C2
                         < .227E-02
                           .933E+00
                         < .227E-02

                           .136E-01
                           .455E-C1
                         < .227E-02
                           ,751E*CC
     STACK  GAS

        ./60E-02
 .311E-0'V  .125E-01

     >  .301E-01
     <  .1526-03
     <  .1526-03
     <  .152E-03
        .105E*00

     <  .152E-03
        .1916-02
.140E-04C1
       .615E-02
     < .152E-C3
     > .2026-01
     < .1766-03
       .I52E-03
       .152E-03
       .JS9E-02
       .38CC-02
       .17SE-CI

-------
MASS HEAT INPUT

ELEMENT

PRASECCYP1UP
RHEMUM
RHCCIUM
RUBIDIUM
RUTHENIUM

SAMARIUM
SCANDIUM
SELENIUM
SILICON
SILVER

SODIUM
STRONTIUM
SULFLR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
TMCPIUM
THULIUM
TIN

TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

YTTRIUM
ZINC
ZIRCONIUM
               MUHAWK
             BASELINE
        NG/J
FUEL CIL

< .227E-02
< .227E-02
< .227E-02
< .227E-02
< .227E-02

< .227E-02
< .227E-02
< .227E-02
  .14BE+01
< .227E-C2
   .-455E-OZ
   .227E-02
   .546E+C1
   .227E-C2
   .227E-02
 <  .227E-02
 <  .227E-02
 <  .159E-01
 <  .227E-02
 <  .227E-02
   .2056+00
   .L59E-C1
   .U4E-01
   .523E+00
   .227E-02

   .22TE-02
   .114E+OC
   .114E-OI
    STACK GAS

     <  .IS2E-03
     <  .152E-03
     <  .152E-03
     <  .5<»OE-03
     <  .152E-03

     <  .1526-03
     <  .176E-03
,113E-03  .148E+00
       -523E+CC

       .0  E*00
       .2SBE-02
     >  .252E+00
     <  .154E-03
     < .152E-03
     < .IS2E-03
     < .152E-03
     < .12BE-03
       .132E-01
       .254E-01
       .152E-03
       .126E-01
.1*OE-04
-------
    CONCENTRATION

    ELEMENT

    ALUMINUM
    ANTIMONY
    ARSENIC
    BAR I If
    BERYLLIUM

    BISMUTH
    BCRCN
    BRDHINE
    CADMIUM
    CALCIUM

    CERIUM
    CESIUM
    CHLORINE
    CHROMUM
    COBALT

    COPPER
    OVSPRCSIbM
    ERBIUM
    EOPCPIUN
    FLUORINE

_   GADCLINIUM
i   CALLIUM
00   GERMANIUM
    GOLD
    HAFNIIM

    HOLMIOM
    IODINE
    IRICIUM
    IRON
    LANTHANUM

    LEAD
    LITHIUM
    LUTETIUM
    MAGNESIUM
    MANGANESE

    MERCURV
    MOLYBDENUM
    NEUDYKIUM
    NICKEL
    MCBIUH

    CSPIUM
    PALLADIUM
    fHCSPhCRUS
    PLATINUM
    POTASSIUM
              HASEL1NE
         MCG/OSCM
 MLTER
U
.0  E+00
.126E+CC
.5686*01
.C  E + CC
.C  E + CC

.0  E+CC
.316E+00
.190E+00
.190E-01
.0  E+00
   .0  E+00
   .126E-01
   .0  E+OC
   .316E+C1
 > .506E+C2

 ) .6326+02
   .0  6+OC
   .0  E+00
   .0  6+00
   .0  E«00

   .0  E*00
   .4806+01
   .S69E-01
   .0  E + CO
   .0  E+OC

   .0  6+00
   .253E-C1
   •0  E+00
J  .0  E+00
   .0  E+00

   .0  E*00
   .253E+00
   .0  E«OQ
J  .0  E+OG
   .253E+CG

 < .126E-Q1
   .0  E»CC
   .0  E+OC
 > .627E+02
   .0  E+00

   .0  E+00
   .0  E+CO
   .632E+00
   .0—E*.OC
J  .C  E+00
  XAD-2

   .317E+02
   .0  E+00
   .C  E+00
   .104E+02
<  .520E+00

<  .52CE+00
   .0  E+00
   .156E+03
<  .S20E+00
   .572E+02

   .146E+02
<  .520E+00
   .676E+02
   .C  E+00
<  .52CE+00

   .20BE+02
<  .52C6+00
<  .52CE+00
<  .52CE+00
   .364E+02

<  .5206*00
   .2086+01
<  .520E+00
<  .52CE+CO
<  .52CE+00

<  .5206+00
<  .520E+00
<  .520E+00
  .260E+02
<  .520E+00

<  .5206*00
   .156E+01
<  .520E+00
   •520E+01
   .8326+01

<  .780E+00
   .161E+02
<  .52CE+00
                  <  .52CE+CO

                  <  .52CE+CO
                  <  .520E+JO
                    .1S6E+02
                    .156E+02
                    .72UE+02
                                   1ST IMPINUER C CMC  2ND G 3ft 0 IMPINGERS
   .0  E+00
   .0  E+00
   .0  E+00
   .593E+C1
 < .988E-01

 < .988E-01
   .593E+00
   .0  E+00
 < .98BE-01
   .494E+03

 < .988E-01
 < .986E-0-1
   .375E+03
   .7UE+01
   .395E+00

   .385E+02
 < .988E-01
 < .96BE-01
 < .98BE-01
   .3926+03

 < .9886-01
   .889E+00
 < .988E-01
 < .988E-01
 < .9886-01

 < .9B8E-01
 < .9B8E-01
 < .9886-01
0  .6026+02
 < .988E-01

   .395E+01
 .  .2966+00
 < .9886-01
   .0  E+00
   .988E-01

   .9886-01
   .U89E+01
 < .9886-01
   .9286+01
 < .198E+00

 < .988E-01
 < .9886-01
   .0  E+00
 < .988E-CI
   .0  E+00
K
<
<
N
N
,N
ft
K
K
N
K
fc
N
N
N
H
N
N
N
N
N
K
K
ft
N
N
N
h
N
*
N
b
ft
fi
K
.0
E+00
.506E+00
.202E+01
.0
.0
.0
.G
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.C
.C
.0
.C
.0
.0
.0
.0
.0
.0
.C
.C
.0
.0
.C
.0
.0
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
6+00
E+00
E+00
E+00
E+00
E+00
E + 00
E+00
6+00
E+00
6+00
E+00
6+00
E+00
6+00
6+00
6+00
6+00
E+00
E+00
6+00
6+00
E+00
.1016+00
Ik
It
N
*
N
N
N
N
N
.0
.0
.C
.0
.C
.C
.C
.C
.C
6+00
E+00
6+00
6+00
6+00
6+00
E+00
6+00
E+00
    STACK GAS

       .317E+02
.126E+00 .5CSE+02/

     > .122E+03/
     < .619E+00/
     < .619E+00
     < .6196+00
       .4286+03 •

     < .61SE+00
       .777E+01/
,569£-01 .823E+02/
     < .716E+00/

     < .619E+GO
     < .619E+00
       .151E+02
       .72BE+02/

-------
cp
CONCENTRATION

ELEMENT

PRASEOOtHIUM
RHEMUH
RHCDIUM
RUBIDIUM
RUTHEMUH

SAMARIUH
SCANOIUH
SELEMUH
SILICON
S IL VER

SODIUM
STRONTIUM
SULFUR
T AN 1 ALUM
TELLURIUM

TERBIUM
THALLIUM
THCRIUM
THULIUM
TIN

TITAMUN
TUNGSTEN
URANIUM
VANACIUM
YTTERBIUM

YTTRIUM
ZINC
ZIRCONIUM
                                      MOHAWK
                                    BASELINE
                               HCG/DSCM
                       FILTER               XAO-2
   .C  E«-QC
   .C  E + CC
   .C  E + CC
   .0  E + 00
   .0  E+00

   .0  E + CC
   .0  E+00
   .462E+OC
 > .582E+C2
   .120E+OC

U  .0  E+00
   .0  E+OC
 > .L77E+02
 < .632E-02
   .101E+CC

   .0  E + CC
   .C  E+CC
   .0  E+OC
   .632E-02
   .0  E+00

U  .0  E+00
 < .695E-01
   .0  E+OC
 > .487E+02
   .569E-01

   .0  E+00
   .0  E + 00
   .0  E + 00
                                            <  .52CE+00
                                            <  .52CE+00
                                            <  . 52CE»CO
                                            <  . 520E*CO
                                            <  .5206*00

                                            <  . 5ZCE*00
                                            <  .520E*00
                                            <  .520E+00
                                              .0   E*00
                                              .109E+02
                                              .312E*02
                                            <  .52CE+00
                                            <  .52CE»CO

                                            <  . 52CE*CO
                                            <  .52CE+00
                                            <  .520E+CO
                                            <  .52CE+00
                                            <  .520E+00
                                              .103E+03
                                            <  .S20E+00
                                              .260E+01
                                            <  .5206*00

                                            <  .520E+00
                                              .0   E*CO
                                              . 26CE*01
                                   1ST IMP1NGER C CMC  2ND  C  3RD  IMPINGEKS
 < .988E-01
 < .9H8E-01
 < .988E-01
 < .16BE*01
 < .988E-01

 < .988E-01
 < .198E+00
   .0  E*00
   .988E+01
   . 168E+03
U
   0  E*00
  .119E*01
> .97BE+03
< .988E-01
< .988E-01

< .988E-01
< .988E-C1
< .988E-01
< .988E-01
  .0  E+00

  .691E*01
< .988E-01
< .988E-01
  .988E-01
< .988E-01

  .98BE-01
  .731E*02
  .IS8E+00
N
M
N
N
N
N
N
N
N
It
N
N
N
N
N
N
N
N
N
N
N
K
N
N
IS
N
N
N
.0
.0
.0
.C
.0
.0
.C
.C
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.C
.C
.0
.C
.0
.C
.0
.0
.0
.0
E*00
E*00
E*00
E*QO
E+00
E + 00
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
                                        STACK  GAS

                                         <  .619E+00"'
                                         <  .6196*00
                                         <  .6lSE*00 /
                                         <  .22CE*01-'
                                                   7
                                         <  .M8E+00
                                                                                                          .213E*04 .
                                            .121E«02 ^
                                         >  .IC3E*0'« S
                                         <  .625E*OOy
                                     .101E«00  .SI4E + 02/
                                     .569E-01OK.676E+00

                                     .988E-01OK.619E+00*
                                            .731E + 02A
                                            .280E»Ol/

-------
                                      I'A Ml INI
                        U   .C   F»CC
CO
I
 4MICCNV
 AHSEMC
 BAM KM
 BEPVIUUM

 BISMUTH
 BOPC^
 BROMINE
 CADMIUM
 CALCIUM

 CERIUM
 CESIUP
 CHLCRINE
 CHOCMIUH
 CCBALT

 CCPPEB
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GACCLIMUM
 GALLIUM
 GERMANIUM
 GOLD
 HAFNIUM

 HOLMIUH
 ICOIKE
 IRIDIUM
 IRCK
 LANTHANUM

 LEAD
LITHIUM
LUTETIUM
MAGNESIUM
MANGANESE

MERCtRtr
 MOLYBDENUM
NECDVPIUN
NICKEL
NIOBIUM

OSMIUM
 PALLADIUM
 PHCSFHCRUS
 PLATINUM
PCJTASS1UM
                       U
    .l«9E»02
    .0   E*GC
    .0   E+00

    .0   E+CC
    .105E+01
    .631E+CO
    .631E-01
    .0  E+00
   .0  E+OC
   .421E-C1
   .0  E+CC
   .105E+02
 5 .168E+03

 > .210E+03
   .0  E+OC
   .0  E+CO
   .0  E+00
   .0  E+00

   .0  E+00
   .160E+02
   •I89E+GC
   .0  E+OG
   .C  E+00

   .0  E+OC
   .842E-01
   .0  E+00
U  .0  E+00
   .0  E+00

   .0  E+00
   .842E+OC
   .0  E+00
J  .0  E+CC
   .842C+CC

 < .421E-01
   .C  E+QO
   .0  E+CC
 > .2C9E+C3
   .C  E+CC

   .C  E+CC
   •C_ E+CC
   .210E+01
   .0  E+00
J  .0  E+CC
  XAO-2

   . lCtC»03
   .0   E+QO
   .C   E*00
   .346E*02
 <  .173EKH

 <  .1I3E+C1
   .0   E+00
   .519E+03
 <  .173E+01
   .1SCE+C3

   .485E+02
 <  .173E+C1
   .22EE+03
   .C   E+GO
 <  .173E+01

   .692E+02
 <  .173E+01
 <  .1736+01
 <  .173E+01
   .121E+03

 <  .173E+01
   .692E+01
 <  .173E+01
 <  .173E+01
 <  .173E+01

 <  . 173E+01
 <  .173E+01
<  .173E+01
   .866E+02
 <  .173E+01

<  .173E+01
   .519E+01
 <  .173E+01
   .173E+02
   .277E+C2

<  .26CE+01
   .537E+C2
<  .173E+OL
   .344E+C2
<  .173E+01

<  .173E+C1
<  .113E+G1
   .51SE+02
   .519E+02
   .242E+03
                                                          ISI IHIMNliEH C CMC  2ND t 3K 0 IMflNGERS
   .0  E+00
   .0  E+00
   .0  E+00
   .II9FE+02
 < .32SE+CO

 < .329E+00
   .197E+01
   .0  E+00
 < .329E+00
   .164E+04

 < .329E+00
 < .329E+00
   .125E+04
   .237E+02
   .131E+C1

   .128E+03
 < .329E+00
 < .329E+00
 < .329E+00
   .130E+04

 < .329E+00
   .296E+01
 < .329E+00
 < .329E+00
 < .329E+00

 < .329E+00
 < .329E+00
 < .329E+00
0  .200E+03
 < .329E+00

   .131E+02
   .986E+00
 < .329E+00
   .d  E+00
   .329E+00

   .329E+00
   .296E+Q2
 < .329E+00
   .309E+02
 < .657E+CO

 < .329E+00
 < .329E+CO
   .0  E+00
 < .329E+CC
   .0  E+00
N
.0
E+00
< .1686*01
N
N
N
N
N
N
N
N
N
H
N
N
N
N
N
fv
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
K
.0
.0
.0
.c
.0
.0
.0
.0
.0
.0
.c
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.c
.0
.0
.0
.0
tc ^w i
E + 00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E + CO
E+GO
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
.337E+00
N
N
N<
N
N
N
N
N
N
.0
.0
.0
.0
.0
.c
.0
.c
.c
E+00
E+00
E + 00
E+00
E+00
E+00
E + 00
E + 00
E+00
    STACK UAS

       .IC6E+03
.42lE«00 .4C6E+03
     < .2G6E+01
     < .2C6£*Ol
     < .206E+01
       .1436*04

     < .2UE + 01
       .25SE+02
.189E*00 .274E+03
     < .239E+01

     < .20t£*0l
     < .2C6E+01
       .51CC+02
       .5J3E+C2
       .242E+03

-------
HASS/TIKE

ELEMENT

PRASEODYMIUM
RHENIUM
RHCOIUM
RUHIOIUK
RUThEMUM

SAMARIUM
SCA^CIUM
SELEMUM
SILICON
SILVER

SODIUM
S1RCNTIUM
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THORILM
THULIUM
 TIN

 TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

YTTRIUM
 ZINC
 ZIRCONIUM
                MUHAHK
              UASELINE
         PCU/SEC
 FILTER                XAD-2
.0  E+CG
.0  E+00
    E+CC
    E+CC
    E+00
   .C
   .C
   .0
   .0  E+00
   .0  E+00
   .154E+OL
 > .I94E+03
   .400E+OC

U  .0  E+00
   .0  E+00
 > .589E+C2
 < .210E-01
   .337E+OC

   .0  E+OC
   .0  E+OC
   .0  E+OC
   .210E-01
   •0  E+CO

U  .0  E+OC
 < .231E+OC
   .0  E+OC
 7 .162E+03
   U89E+00

   .0  E+00
   .0  E+00
   .0  E+00
< .173E+C1
< .173E+01
< .173E+CI
< .173E+01
< .173E+C1

< .173E+C1
< .173E+01
< .173E+01
  .176E+04
  .653E+04

  .0  E+00
  .364E+C2
  .10"»E*03
< .I73E+01
< .173E+01

< .IT3E+01
< .173E+01
< .173E+01
< .173E+C1
< .173E+01

  . 156E+C3
  .343E+03
< .1736+01
  .866E+01
< .173E+01

< .173E+01
  .0  E+00
  .B66E+01
                                1ST IMPINGEft C CMC  2ND C 3RD  1HPINGEPS
 < .32SE+00
 < .32VE+00
 < .329E+00
 < .559E+C1
 < .329E+CO

 < .329E+00
 < .657E+00
   .0  E+00
   .329E+02
   .559E+03

U  .0  E+CO
   .394E+01
 > .325E+C4
 < .329E+00
 < .329E+00

 < .329E+00
 < .329E+00
 < .329E+00
 < .329E+00
   .0  E+ 00

   .230E+02
 < .329E+00
 < .329E+00
   .329E+CO
 < .329E+CO

   .329E+CO
   .243E+03
   .657E+00
N
N
N
N
N
N
N
K
h
H
N
N
N
It
N
fc
N
N
N
N
N
N
N
N
N
M
K
K
.0
.0
.0
.C
.C
.C
.C
.C
.C
.C
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
E»00
E+00
E+00
E*-GO
E*00
E*CO
E + 00
E + 00
E + 00
E+CO
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E + 00
E+00
E + 00
E+00
£+00
E+00
STACK GAS

 < .206E+01
 < .206E+01
 < .20£E+Ol
 < .722E+01
 < .2C6E+01

 < .2C6E+01
 < .23SE+CI
       . 3276*01
 > .2CIE+0*
                                                                                 .0  E + 00
                                                                                 .4C3E+C2
                                                                              >  .3<2E+04
                                                                              <  .2CGE+01
                                                                          .337E+00  .IUE + 03
                                                                          , 189E+00
-------
                                        HI HAWK
7"
                                 HCli/MC
  CLtMCKT

  ALUMINUM
  ANTIriCNV
 ARSENIC
 BARUM
 BERVLLIUM

 8ISHLTH
 BORON
 BRCMINE
 CADM IUM
 CALCIUM

 CERIUM
 CESIUM
 CHLORINE
 CHROMIUM
 COBALT

 COPPER
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLtGRINE

 GADOLINIUM
 GALLIUM
 GERMANIUM
 GCLD
 HAFNIUM
   i
 HCLHIUM
 ICCINE
 IRIQ1UM
 IRON
 LANTHANUM

 LEAD
 LITHIUM
 LUTE MUM
 MAGNESIUM
 MANGAKESE

 MERCURY
 f> OL VBOENUM
 NEOCYMIUH
 NICKEL
ft ICBIUM

 CSKIUH
 PALLADIUM
 PHQ5PHQKUS
 PLATINUM
 POTASSIUM
                         FUEL  CIL
                           .0  E*00
                           .0  E«CC
                           .173E*C2
                           .173E*C2
                          .520E*C2
                          .173E»02
                          .101E»05

                          .173E*02
                          .173E*02
  .156E+C3
< .173E*C2

  .399E*05
< .173E*C2
< ,173E*Q2
< .173E+C2
  •920E+C3

< .173E«-02
                        <  .I73E+02
                        <  .173E»02
                        <  .173E*02

                        <  .173E+02
                        <  .1736*02
                        <  .173E*02
                        <  .173E*C2

                          .10AE+03
                          .3*7E*03
                        <  .173E*02
                          .572E*C*
                          .3 .274E«03
                    < .239E*J1

                    < .206E01
                    < .206E«01
                      .5*0£»02
                      .523E+02
                      .2«2E*C3

-------

MASS/TIME

ELEMENT

PRASECCVPIUH
RhEMUM
RHCCIUM
RU6ICIUM
RUTHENIUM

SAMARIUM
SCANDIUM
SELENIUM
SILICON
SILVER

SODIUM
STRONTIUM
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THORIUM
THULIUM
TIN

TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

YTTRIUM
ZINC
ZIRCCNIUM
               MOHAWK
             BASELINE.
        MCG/SEC
FUEL GIL           STACK GAS
< .173E*02
< .173E*02
< .173E*02
< .1736*02
< .113E+C2

< .17JE+C2
< .l?3E*C2
< .173E+02
  .U3E + C5
< .173E»C2

< .347E+02
  .173E+02
  .416E+05
< .173E*C2
< .173E*02

< .113E+C2
< ,173E*02
< .121E+03
< .173E»02
< .173E+02
   .121E»03
   .867Ei02
 <  .173E*C2

 <  .173E+C2
   .867E*C3
   .867E*02
     <  .2CtE»Cl
     <  .206E01
     <  ,206E»01
     <  .732E»Ol
     <  .20tE»01

     <  .206E»01
     <  .239E+01
.15  . 20lE»0'i
       .70SE4-04

       .0  E«00
     > .242E+04
     < .208E+C1
. 337E«-GO .171E+C3
.189E*00
-------
                                    POHAVtK
                                  UASELINE
 ELEMC-NI
                   HEATLK NASS UALANCE
IN  =  FUEL CH        CUT = STACK GAS     KEf-JNERY G«S NUT SAMPLED
              TUTAL IN                    TUTAL OUT
                                                                                MASS  UALANCE(CUT/lNi



OD
1
1™"*
•fe




ALCMlf.'U'l
ANTIMCMY
AKSENIi:
BAH IUM
BEHrLLlUM
OISPUTH
6CKN
URCPINE
CAOM1L-M
CALCIUM
CEMUK
CESIUM
CHLCRINE
CHKCMIUM
CCBALT
CCPPEP
DYSPROSIUM
ERBIUM
EUROPIUM
FLUCP1NE
GADCLIN11M
GALLIUM
GERMANIUM
COLO
HAFNIUM
HCLMRM
IQJINE
I R 1 .) 1 U'l
IHLtl
LANTHANUM
LEAD
LITHUH
LUTETIUH
MANGANESE
MEKCURY
NCLYfiCCNUM
NELCYM1UM
NICKEL
N1G011M
OSMIUM
PALLADIUM
PhCSPHCRUS
5J:!JS:S!
X<.173£»02
.*121E + 03
.1016+05
X<.173E»02
.I5t£*03
.3SSE+05
X<.173E+C2
X<.173EtC2
X<.i73E»02
.520E+03
X<.173E*02
X<.173Ei02
X<.173E»02
X<. 173E*02
X
-------
            IN
   ELEMENT
as
i
en
PRASEODYMIUM
RHENIUM
RHODIUM
RUBIDIUM
RUTHENIUM

SAMARIUM
SCANCIUM
SELEMUM
SILICON
SILVER

SODIUM
STRONTIUM
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THCRIUM
THULIUM
 TIN

TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

YTTRIUM
ZINC
 ZIRCONIUM
                     MUHAHK
                   BASELINE

              HEATER MASS BALANCE
FUEL CIL       CUT = STACK GAS
         TCTAL IN

            X<.173E»02
            X<.173E»02
            X<.173E*02
            X<.173E*02
            X<.173E+02

            X<.173E+02
            X<.173E«02
            XC.173E+02
                     .113E+05
                     .173E+02
                     .4I6E+05
                             X<.173E+02

                             X<.347E»02
                     .847E+03
                     .867E*02
            X<.173E»02
            X<.173E*02

            X<.173E+02
            X<.173E+02
            X<.121£*03
            X<.173E»02
            X<.I73E+02
                             X<.121E»03
                             X<.867Et02
                            ',
                             X<.173E*02

                                173E*C2
 REFINERY CAS NOT SAMPLED
   TOTAL (JUT

        X<.206E*01
        X<.206E«-01
        X<.206E*01
        X<.732E*01
        X<.206E*01

        X<.206E»Ol
        X<.239E»01
.154E+Ol
-------
CD
 I
CT>
 PPM

 ELEMENT

 ALUMINUM
 ANTIMONY
 ARSENIC
 BARIUM
 BERYLLIUM

 BISMUTH
 BORON
 BROMINE
 CADMIUM
 CALCIUM

 CER IUH
 CESIUM
 CNLCRINE
 CHRCMIUM
 COBALT

 COPPER
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GAOCLIN1UH
 GALLIUM
 GERMANIUM
 GOLD
 HAFNIUM

 HCLH1UH
 IODINE
 1RIDIUM
 IRCN
 LANTHANUM

 LEAD
 LITHIUM
 LUTETIUN
 MAGNESIUM
 MANGANESE

 MERCURY
 PCLYBDENUH
 NEUOYMIUM
 NICKEL
 NIOBIUM

OSMIUM
PALLACIUM
PASEODYMIUM
PHCSPHURUS
PLATINUM
  FUEL  OIL

  .2SOE+C2
  .0  E+00
  .0  E+00
 <.ICOE+00
 <.100E+00

 <.ICOE+00
 <.ICOE+OO
  .lOOE+Ol
 <.1COE*00
  .260E+02

 <•1COE+00
 <.100E+00
  .6COE+01
  .2COE+01
 <.1COE+00

  .IOOE+03
 «C.1C06+00
 <.100E+00
 <.IOOE+00
  .7COE+00

 <.100E+00
  .3COE+00
 <.1COE+00
<.UOE+OO
 <.1COE+00

<.1COE+00
<.100E+00
<.1CO£+00
  .4606+02
<.1006+00

  .6COE+00
  .3006*00
 <.1COE+OQ
  .1506*02
  .4COE»Ol

  .1COE-01
<.IOOE+OO
 <.1COE+00
  .270E+03
 <.ICOE*00

 <.1COE*00
 <.ICOE+00
 <.100E+00
  .tCCE+01
  •2COE+02
                                 PPM
   MOHAWK
NH3 INJECTION

        FILTER

       U.O  E*00
        .274E+C2
        .363E»03
                                             .0  E*00

                                             .913E»00
                                             .0  E«00
                                             .164E»03
                                            U.O  E*00

                                             ,183E»03
                                             .0  E*CO
                                             .0  E»00
                                             ,365E*03
        . 183E*02
        .S13E«01
        .913E*01
        .0   EtOO

        .0   E»00
        .876E*03
        .63SE*Ol
        .0   E+00
        .0   EtOO

        .0   E*00
        .1836+01
        .0   E+CO
      U.O   EtOO
        .0   E+00

        .831E+C3
        .639E+02
        .913E+00
      U.O   E*CO
        .128E+03

      <.146E+C2
        .913E+01
                                             .0  E«00

                                             .0  E*CO
                                             .C  E+CC
                                             .0  E*00
                                             .C  E*CO
                                                                   XAO-2
                                                                                 1ST IMPINUER t CMC .2ND £ 3RD  IfPINGERS
  .0   E*00
  .0   E+00
  .0   E+00
  .200E. + 01
  .0   E+00

  .0   E+00
  .0   E+00
  .0   E+00
  .0   E +00
  .0   E+00
 .0
 .0
 .0
 .0
 .0

 .0
 .0
 .0
 .0
 .0

 .0
0.0
 .0
 .0
 .0

 .0
 .0
 .0
 .0
 .0

 .0
 .0
 .0
 .0
 .0
E+00
E+00
E+00
E+00
E + 00

E+00
6+00
E+00
E+00
E+00

E+00
6+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00
<.1606+00
 .0  E+00
 .0  E+00
 .0  E+00
 .0  E+00

 .0  E+00
 .0  E+00
 .0  E+00
 .0  E+00
 .700E+01
  .0   E+00
  .0   E+00
  .0   £+00
  .100E-01
  .0   E+00
 .0
 .0
 .0
 .0
                                                     E+00
                                                     E+00
                                                     E+00
                                                     E+00
 .0  E+00

 .0  E+00
 .0  E+00
 .0  E+00
 .4206-01
 .0  E+00

 .60CE-01
 .0  E+00
 .0  E+00
 .0  E+00
 .3706+00

 .0  E+00
 .1006-02
 .0  E+00
 .0  E+00
 .0  E+00

 .0  E+00
 .0  E+00
 .0  E+00
     E+00
     E+00
                                                                                      .0
                                                                                      .0
 .0  E+00
 .0  E+00
 .0  £+00
 .0  E+00
 .8COE-02

<.120E-02
 .0  E+00
 .0  6*00
 .1406-01
 .0  E+00
.0
.0
.0
.0
.0
                                                    E+00
                                                    E + 00
                                                    E+00
                                                    E+00
                                                    E+00
N.O  E+GG
<.500E-d2
<.200E-01
N.O  E+00
N.O  E+00
N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O

N.O
N.O
N.O
N.O
N.O
                         E+00
                         E+00
                         E + CO
                         E + OO
                         E*00

                         E + 00
                         E«00
                         E + 00
                         E + 00
                         E«00

                         E + 00
                         E*00
                         E+00
                         E+00
                         E+00

                         E + 00
                         E + OC
                         f«00
                         E+00
                         E+CO

                         E+00
                         E + 00
                         6*00
                         E+00
                         E+00

                         E+00
                         E + 00
                         E + CO
                         E+00
                         f+00
<.100E-02
N.O  E+00
N.O  E*CO
N.O  E+OC
N.O  E+00
                    N.O
                    N.O
                    N.O
                    N.O
                    N.O
     E+CO
     E+00
     E*CC
     E«CC
     £*00

-------
CD
PPM

ELEMENT

POTASSIUM
RHCNIU1
RHODIUM
RUBIDIUM
RUTHENIUM

SAMARIUM
SCANDIUM
SELENIUM
SILICON
SILVER

SODIUM
STRONTIUM
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THCR I UN
THULIUM
TIN

TITANIUM
TUNGSTEN
URAMUM
VANADIUM
YTTERBIUM

VTTRIUM
ZINC
ZIKCCNIUH
                              PP1
 FUEL CIL

 .ICOE+03
<.ICOE+00
 .C  E+00
<.1COE+9Q
<.1C3E+00

<.1COE+00
<. 100 E+00
<.IOOE+00
 .t50E+03
<.ICOE«00

 .SCCE+OO
 .1COE+00
>.410E+03
<. 1COE+00
<.ICOE+OO

<.IOOE+00
<.UCE + 00
<.700E+00
<.IOOE+00
<.KO£*00

 .900E+01
<.1COE+00
<.100E+01
 .1406+02
   HUHAwK
NM3 INJECTION

        FILTER

       U.O  E*CO
        .0  E«00
        .0  E*00
        .913E»C1
        .0  E*00

        .0  E*CO
        .183E»C2
        .393E»02
                                          .0  E»CO

                                         U.O  E»00
                                          •0  E+CC
                                          .0  E»00
        .0  E»00
        .0  E*00
        .0  E+CO
        .913E>00
        .365E*02

       U.O  E«00
        .0  E+CO
        .2I4E+C2
                     <.100E+00
                      .2COE*01
                     <.ICOE*00
                     . 173E»02

                     .0  E»00
                     .175E+04
                     .C  E+CO
                                                               XAD-2
                                                         1ST  IMP1NGER & UHC 2ND C 3RD
.0  E+00
.0  e+oo
.0  E»QO
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00
                                                                  E+00
                                                                  E+00
.0
.0
.0  E+00
.0  E+00
.0  E+00

.700E+01
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
 .0  E+00
 .0  E+00
 .0  E+00
 .0  E+00
 .0  E+GO

 .0  E+00
 .0  E+00
 .IOCE-02
 .0  E+00
 .6CCE+CO

U.O  E+00
 .0  E+00
>.990E»Ol
 .0  E+00
 .0  E+00
.0
.0
.0
.0
.0
     E+00
     E+00
     E+00
     E+00
     E+00
 .27CE+00
 .0  E+00
 .0  E+00
 .0  E+00
 .0  E+00

 .0  E+00
 .400E-01
 .0  E+00
N.O
K.O
N.C
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
N.O
E + CO
t + CC
E + CO
E + OC
E+00
E+CC
E+00
E + CO
E + 00
E+00
E + CC
E+00
E + 00
E + CC
E+OC
E + 00
E + 00
£+00
E + CC
E+OC
E+00
E + CC
E+00
E + CO
E + CO
E+00
E+CO
E + CC

-------
CO
I
 M4SS/HCAT INW

 ELEMENT

 ALLPIKUP
 ANT1MCNY
 ARSENIC
 BARIUM
 BERYLLIUM

 BISMUTH
 00 RON
 BRCMINE
 CADMIUM
 CALCIUM

 CERIUM
 CESIUM
 CHLCRlJvE
 CHRCM1UM
 CCBALT

 CCPPER
 OYSPRCSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GADOLINIUM
 GALLIUM
 GERMANIUM
 GOLD
iHAFMUM

 HOLMIUM
 ICDINE
 IRIOIUM
 I RUN
 LANTHANUM

 LEAD
LITHIUM
LUTE1IUM
 MAGNESIUM
MANGANESE

MERCURY
 HCLYBOEMM
NECDYMIUP
MCKEL
NIOBIUM

OSMIUM
PALLACIUM
PASEOCYM1UM
 PHGSPHOKLS
PLATINUM
                           f ILTER
                                    NG/J
                 MCJHAMH
              NH3 INJECI I1JN

                      XAD-2
 U   .C  E + OC
    .471E-C4
    .624E-03
    .471E-02
    .0  E + OC

    .15TE-05
    .0  E + 00
    .282E-Q3
    .704E-CS
 U   .0  E»00

    .314E-03
    .0  E+00
    .0  E + CC
    .628E-03
 >  .157E-01

 >  .157E-01
    .314E-04
    .157E-C4
    .157E-04
    .0  E+OC

    .0  E+00
   .151E-C2
   .UOE-C4
   .0  E+CG
   .0  E+CC

   .0  E+QO
   .3L4E-05
   .0  E+00
J  .0  E+00
   .0  E+OC

   .U3E-02
   .UOE-03
   .157E-C5
J  .0  E+CC
   .220E-C3

 < .251E-C4
   .157E-C4
   .471E-C4
 >  .155E-01
   .0  E+00

   .0  E+00
   .0.  E+OG
   eO  E+00
   .345E-C2
   .C  E+OC
                                                 .C  E+00
                                                 .0  E+00
                                                 .C  E+00
                                                 .258E-02
                                                 .0  E+00
    E+00
    t+00
    E+00
.0  E+00
.0  E+00
                                                 .0
                                                 .0
                                                 .0
.0
.0
                                                     E+00
                                                     E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                     E + 00
                                                     E+00
                                                     E+00
                                                 .0  E+00
                                                 .0  E+00
.0
.0
.0
.0
.0
.0
                                                     E+00
                                                     E+00
                                                     E+00
                                                 .0  E+00
                                                 .0  E+00
.0
.0
.0
                                                  0  E+00
                                                  0  E+00
                                                     E+00
                                                     E+00
                                                     E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00

                                               < .207E-03
                                                 .C  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00

                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .0  E+00
                                                 .904E-02
              1ST  IMP1NGER & OMC 2NC C  3K C  IMPINGfcRS
 .0  E+00
 .3  E+00
 .0  E+CO
 .317E-03
 .0  E+00

 .0  E+00
 .0  E+00
 .0  E+00
    E+00
    E+00
                                                                      .0
                                                                      .0
.0  E+00
.0  E+00
.0  E+00
. 133E-02
.0  E+00

.190E-02
.0  E+00
.0  E+00
.0  E+00
.U7E-01

.0  E+00
.317E-04
.0  E+00
.0  E+00
.0  E+00

.0  E+CO
.0  E+00
.0  E+00
    E+00
    E+00
.0
.0
                    .0  E+00
                    .0  E+00
                    .0  E+00
                    .0  E+00
                    .253E-03

                  < .3BOE-04
                    .0  E+GO
                    .0  E+CO
                    .443E-C3
                    .0  E+00
.0
.0
                        E+00
                        E+00
                 r>   .0  E«OO
                  <  .121E-03
                  <  .4836-03
                 N   .C  E+00
                 K   .C  E+00

                 N   .C  E+00
                 N   .0  E+00
                 *   .0  E+00
                 A   .0  E+00
                 h   .0  E+00
                 K
                 N
                 N
                 N
                 N
.0  E+00
.0  E+00
.0  E+00
.0  E+CO
.C  E+00

.0  E+00
. 0  E+00
.C  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00
                 *  .0  E+00
                 It  .0  E+00
                 N  .0  E+00
                 ft  .0  E+00
                 N  .0  E+00

                  < .241E-04
                 N  .0  E+00
                 N  .0  E+00
                 N  .0  E+00
                 K  .C  E+00
                 K
                 N
                 N
                 N
                 N

                 N
                 N
.0
.C
                    .0  E+00
                    .0  E+00
                    .0  £+00
                        E+00
                        E+00
                    .C  E+00
                    .0  E+00
                    .0  E+00
    STACK  GAS

       .0   E+00
. .IUE-01
       .314E-04
       .157E-04
       .151E-04
       .117E-01

       .0   E+00
       .154E-02
       .UOE-04
       .0   E+00
       .0   E+00

       .0   E+00
       .3ME-05
       .0   E+00
       .0   E+00
       .0   E+00

       . U3E-02
       .UOE-03
       .157E-05
       .0   E+00
       .473E-03

     < .294E-03
       .157E-04
       .471E-04
     > .ItCE-Ol
       .0   E+00

       .0   E+00
       .0   E+00
       .0   E+00
       .345E-02
       .904E-02

-------
co
    MASS/hHAT IM'UT

    EU'«NT

    POTASSIUM
    RMMUM
    BHfClUM
    RUKIUIUM
    RUTHENIUM

    SAKAAIUH
    SCANDIUM
    SELENIU*
    SILICCN
    SILVER
SODILM
SIRCK1IUN
SULFLR
TANTALUM
TELLLRIUf

TEHDIliH
THALLIUM
THCRIUH
THULIUM
TIN

TITAMUM
TUNGSTEN
URANIUM
VANADIUM
VTIERB10M

YTTRIUM
ZINC
ZIHCCNIUM
                            NG/J
                   ULTER
   CCHAHK
NH2 1NJECT1DN

         XAO-2
U  .0  E+CC
   .0  C+00
   .0  E+00
   .157E-C4
   .0  E+00

   .0  E+00
   .3ME-04

 > *U<«E-01
   .0  E+OC

lj  .0  E+00
   .0  E+CC
 > .753E-C2
   .0  E+00
   .157E-C5

   .0  E+00
   .C  E+CC
   .0  E+CC
   .15TE-05
   .6286-04

U  .0  E+00
   .0  E+00
   .471E-C4
 > .1526-01
                          .0  E+CC
                          .301E-C2
                          .0  E+00
                                          .114E+00
                                          .0   E+CO
                                          .0   E+JO
                                          .0   E+JO
                                          .0   E+00
          .0
          .0
          .0
          .0  E+00
          .C  E+00
                                              E+JO
                                              E+00
                                              E+00
                                              .C
                                              .0
              E + CO
              E + 00
          .0  E+00
          .0  E+00
          .C  E+00
                                              .0  E+00
                                              .0  E+CO
                                                  E + 00
                                                  E+00
                                                  E+00
          .0
          .0
          .0
          .904E-02
          .0  E+00
          .0  E+00
          .0  E«00
          .C  E+CO

          .0  E+00
          .0  E+00
          .0  E+00
                                                       1ST IMPINGED G OMC 2NC  C  3RD  IMPlNbERS
                              .0
                              .0
                              .0
                              .0
                              .0
E+00
E + CO
E+00
E+00
E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .190E-01

U  .0  E+00
   .0  E+00
 > .314E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+CO
   .0  E+00
   .0  E+00

   .8556-02
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .127E-02
   .0  E+00
H
N
N
t-
K
N
K
N
t
N
N
N
N
rs
N
N
N
N
N
N
N
fv
N
K
N
N
N
N
.0
.C
.C
.C
.0
.0
.C
.0
.0
.0
.0
.0
.C
.0
.0
.0
.0
.C
.0
.C
.0
.0
.0
.0
.0
• 0
.0
.C
E + 00
E + CO
E + 00
E + 00
E+00
e+co
£+00
E+00
E+00
E + 00
E + 00
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E + 00
E + 00
STACK GAS

   .114E+00
   .0  E+CO
   .C  6+00
   .ISJE-O't
   .0  E + 00

   .0  E»CO
                                   >  .I'i'tE-Ol
                                     .190E-01

                                     .0   E+00
                                     .0   E»00
                                   >  .321E+00
                                     .0   £+00
                                     .157E-05

                                     .0   EiOO
                                     .0   E+00
                                     .0   E»00
                                     .157E-05
                                     .62BE-04

                                     . IUE-01
                                     .0   E + 00
                                  >  .1526-01
                                     .29BE-04

                                     .0   E + 00
                                     .428E-02
                                     .0   E+00

-------
    HASS/HEAT INPUT

    ELEMENT

    ALCCIKUM
    AMIPCNY
    ARSEMC
    BARIUM
    BERYLLIUM

    BISMUTH
    BORON
    BROMINE
    CADMIUM
    CALCIUM

    CERIUM
    CESIUM
    CHLORINE
    CHROMIUM
    COBALT

    COPPER
    DYSPROSIUM
    ERBIUM
    EUROPIUM
    FLUCRINE

DO  GAOCLIN1UM
",  GALLIUM
O
   GCLC
   HAFNIUM

   HCLMIUM
   ICOINE
   IRIOIUM
   IRON
   LANTHANUM

   LEAD
   L I THIUM
   LUTETIUM
   MAGNESIUM
   MANGANESE

   MERCURY
   MOLYBDENUM
   NECOYRlliH
   NICKEL
   NICBILM

   OSMIUM
   PALLADIUM
   PTSSEGDVMIUM
   PHCSPWmS
   PLATINUM
NC/J
FUEL CIL
.561E+00
.0 E+00
.0 E+00
< .224E-02
< .2246-02
< .224E-02
< .224E-02
< I224E-C2
< .224E-C2
< .224E-02
.135E+CC
.448E-01
< .224E-C2
.224E+01
< .224E-Q2
< .224E-02
< .224E-02
.15TE-01
< .224E-02
.673E-C2
< .224E-Q2
< .224E-02V
< .224E-02
< .224E-02
< . 2 24 6-02 -V
< .224E-027
.103E+01
< .224E-02
.135E-01
.673E-C2
< .224E-02
.336E+00
.897E-01
.224E-03
< .224E-02
< .224E-C2
.605E+01
< .224E-C2
< .224E-02 1
< .224E-C2 '
< .224E-.C2 "'
.135E+GC
NtJHAhK
NH3 INJECTION
STACK GAS
,C E+00
I624E-03 .157E-C1
> . 176E-CI
. 314E-04
. 157E-C4
.157E-04
. H7E-01
.0 E+00
. 154E-02
.110E-04
.0 E+00
.0 E+00
.0 E+00
.314E-05
.0 E+00
.0 E+00
.0 E+00
.143E-02
.110E-03
.157E-05
.0 E+00
.473E-C3
< .294E-C3
. 157E-C4
.471E-C4
> . ItCE-Cl
.0 E+00
.0 E+00
.0 E+00
.0 E+GO
.345E-02
.904E-02

-------
MASS/HCAT INPUT

ELEMENT

POTASSIUM
RHENIUM
RHCDIUM
RUB1DILM
RUTHENIUM

SAMARIUM
SCANDIUM
SELEMUP
SILICON
SILVER

SCCIUH
STRCKTIUM
SULFUR
TANTALUM
TELLURIUM

TERBIUM
THALLIUM
THORIUM
THULIUM
TIN

TITANIUM
TUNGSTEN
URANIUM
VANACIUM
VTTERBIUH

YTTRIUM
 ZINC
IIRCCNIUM
        NG/J
FUEL CIL
  .22*E+Ol
< .224E-C2 '
  .0  E + CC
< .224E-C2
< .224E-C2 +

< .224E-02
< .224E-C2
< .224E-02
  .146E+02
< .224E-02

  .202E-01
  .224E-02
> .105E+02
< .224E-C2
< .224E-02

< .224E-OZ
< .224E-02
< .15IE-01
< .224E-C2
< ..224E-02

  ,202E»OC
< .224E-02
   MCHAUK
NH3 INJ6CTICN

       STACK GAS

          .114E»00
          .0  E+00
          .0  E+CO
          .157E-04
          .0  E+00

          .0  E+00
  .3KE*00
< .224E-02

< .224E-02
  .-V4BE-01
< .224E-02
          .991E-04
          .144E-01
          .0  E»00
          .0  E«00
        > .321E+00
          .0  E+00
          .157E-C5

          .0  E+00
          .0  E+00
          .C  E+00
          .157E-05
          .62BE-04

          . 176E-01
          .0  E+CO
          .471E-04
        > . 152E-01
          .296E-04

          .0  E+CO
          .428E-02
          .0  E+00

-------
(X
ro
 CONCEMKAT ICN

 ELtMENT

 4LUCINUN
 ANTIMONY
 ARSENIC
 BARIUM
 BEMUIIM

 BISMUTH
 BORON
 BROMINE
 CADMIUM
 CALCIUM

 CERIUP
 CESIUM
 CHLORINE
 CHROMIUM
 COBALT

 COPPER
 DYSPROSIUM
 ERBKM
 EUROPIUM
FLUCfllNE

GADOLINIUM
GALLIUM
GERMANIUM
COLO
HAFNIUM

HdLMIUM
 IODINE
 IRIDIUM
IRON
     LEAD
     LITHIUM
     LUTETIUM
     MAGNESIUf
     MANGANESE

     MERCURY
     MCLYBCENUM
     NECOYP1UM
     NICKEL
     NIOBIUM

     OSMIUM
     PALLADIUM
     PASEODYMIUM
     PHCSPHCRLS
     PLATINUM
                        U
 ML TCP

I  .0  E+00
   .186E+GC
   .246E+01
   .186E+C2
   .C  E+CC

   ,ei9E-C2
   .0  E+GC
   aiiE+ci
   .310E-01
   .0  E+OG

   .124E+01
   .0  E+00
   .0  E+00
   .248E+01
 3  .619E+C2

 >  .618E+02
   .124E+CC
   .619E-OI
   .619E-C1
   .0  E+00

   .0  E+00
   .594E+01
   .433E-01
   .0   E+00
   .0   E+00

   .0   E+00
   .124E-OI
   .0   E+CC
I   .0   E+00
   .0   E+CO

   .563E+01
   .433E+CC
   .619E-02
I   .0   E+OC
   .867E+OC
                    < .<39CE-01
                      .619E-01
                      .186E+00
                    > .6UE+02
                      .0  E+CC

                      .0  E+OC
                      .0  E+CC
                      .0  E+CC
                      .136E+C2
                      .0  E+CC
                                     NII2 INJCCTION
                                        M
                                              XAU-2
   .0  E+00
   .0  E+00
   .0  E+00
   .102E»02
   .0  E+CO

   .0  E+00
   .0  E+00
   .0  E+00
   .C  E+CO
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
0  .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+CO
   .C  E+00

   .0  E+00
   .G  E+00
   .0  E+00
   .0  E+00
   .0  E+00

 < .815E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .G  E+00
   .G  E+CC
   .35JE + C2
                 15.1  IMPINGER C OMC 2ND 6 3R 0
   .0   E+00
   .0   £+00
   .0   E+00
   .125E+01
   .0   £+00
   i
   .0   E+00
   .0   E+00
   .0   E+CO
   .0   E + 00
   .U   E + 00

   .0   E+00
   .0   E+00
   .0   E+00
   .525E+QI
   .0   E + 00

   .750E+01
   .0   E+00
   .0   E + 00
   .0   E+00
   .462E+02

   .0   E+QO
   .125E+CO
   .0   E+00
   .0   E + 00
   .0   E+00

   .0   E+00
   .0   E+00
   .0   E + 00
   .0   E+00
   .0   E+CO

   .0   E+00
   .0  E+00
   .0   E+00
   .0  E+00
   .100E+01

<  .150E+CO
   .0  E+00
   .0   E+00
   .175E+01
   .0   E+00

   .0   E+00
   .0   E+00
   .0  E+00
   .0  E+CO
   .0  E+00
N
.C
E+00
< .476E+00
< .190E+01
N
N
N
N
N
N
K
N
K
h
N
K
t,
N
K
N
N
N
ti
N
N
K
fc
N
K
N
N
K
N
N
N
N
<
K
N
K
*
K
K
t\
N
N
.0
.C
.0
.0
.C
.0
.0
.G
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
E+00
E + 00
E + 00
E+00
E + 00
E + 00
E + 00
E + 00
E + 00
E + 00
E+00
E+00
E+00
E+00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E + 00
E+00
E+00
.S52E-CI
.0
.0
• 0
.0
.0
.0
.0
•.0
.C
E + 00
E + 00
E + 00
E+00
E+00
E+00
E+00
E+00
E + CO
                                                                                                        S1ACK GAS

                                                                                                           .0  E+00 /
                                                                                                     186E*CO .619E+02 /
                                                                                                           .124E+00
                                                                                                           .619E-01
                                                                                                           .61SE-01
  .0  E + 00/
  .6G7E + OL/
  ,*33E-Ol/
  .0  E+CO*
  .0  E + 00/

  .0  E+00V
  .0
  .0  E+00/
  .0  E+00/

  .563E+01  .631E+02 «
  .0  E+00/
  .0  E + 00 »'
  .0  E+00 /
  .136E+02/
  .357E+C2 -

-------
I •'
   a i
   >,
   1C AM; ID*
   SILICON
   SHVtK

   SCC I IN
   SINCMIUM
   SUlfUB
   I AM HUM
   TELLURIUM

   TERBIUM
   THALLIUM
   THORIUM
   THULIUM
130
I
  TITANIUM
  TUNGSTEN
  URANIOM
  VANADIUM
  VTTER8IUM

  VTTRIUH
  /INC
  ZIRCONIUM
                                     CCHAWK
                                  NH3  INJECTION
                              HCG/USCM
                                          XAC-2
.0  E+00
.0  E+OC
.C  E»CC
.6I9E-C1
.0  e+cc

.0  E+00

.266E+CO
           .0   E»CC

        U  .0   E+CC
           .0   EtOO
         )  .297E+02
           .0   E«00
           .619E-02

           .0   E*00
           .0   E+OC
           .0   E+00
           .619E-C2
           .0   E+00.
           .C   E+CO
           .186E*CC
           .tCOE*02
           .118E«-OC

           .0   E*QO
           .U9E»02
           .0   E»00
                                            .0   E»00
                                            .0   E*00
                                            .0   E+OQ
                                            .a   E»OO
                               .0  E»00
                               .0  E*00
                               .C  E+CC
                               .0  E+CO
.0  E»CO

.0  E+00
.0  £*00
.0  E»00
.0  E»00
.0  E*00
.0
.0
.0
.0  E»00
,0  EtOO
    E*JO
    E+00
    E*00
.357E+C2
.C  E*00
.0  E*00
.0  E+00
.0  6*00

.0  E»00
.0  E»00
.0  EiOO
                                            1ST
                 U
                                                                       C OHC  2NU C 3RD IMPINGtflS
                     .0
                     .0
                     .0
                     .0
                     .0
                                                        E+00
                                                        E«00
                                                        E+00
                                                        E+JO
                                                        E+00
  .0  E+00
  .0  E+00
  .125E+00
  .0  E+00
  .750E+C2

  .0  E+QO
  .0  E+00
> .124E+G4
  .0  E+00
  .0  E+00
.0
.0
.0
.0
.0
      E+00
      E+00
      E+00
      E+00
      E+00
                     .337E+02
                     .0   E+00
                     .0   E+00
                     .0   E+00
                     .0   E+00

                     .0   E+00
                     .500E+01
                     .0   E+00
K
K
N
N
N
N
N
N
N
N
N
N
N
N
N
N
N
IV
N
N
N
N
N
N
N
N
N
N
.C
.0
.0
.0
.0
.0
.U
.0
.0
.C
.C
. C
.C
.C
.0
.C
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
E+00
E + 00
E + 00
E + CO
E+OJ
E+00
E+00
E + 00
E+00
E + 00
E + 00
E + 00
E + 00
E + 00
E + 00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E+00
E + 00
E+00
E+00
E+00
                                                                                                       iTACK  CAS
                                                              .0
                                                              .0   E*OJ'
                                                              .6I9E-01'
                                                              .0   E«0d'
                                                              .
                                                              .12  .12JE+C* /
                                                                                  .C   fc + CO^
                                                                                  .61SE-02 ^

                                                                                  .0   E+00
                                                                                  .0   E + 00./
                                                                                  .0   E + 00/
                                                                                  .619E-02
                                           .694E+02/
                                           .0  E+00 •
                                           .l86E»OOv/
                                         > .60CE+02/  .
                                           .11HE+00   4

                                           .0  £+00 ^
                                           .USE + 02 y
                                           .0  E + 00/

-------
 MASS/TINE

 ELEMENT

 ALUHINUN
 ANTIMONV
 ARSENIC
 BARIUM
 BERYLLIUM

 BISMUH
 BORON
 BRCMINE
 CADMIUH
 CALC IUH

 CERIUM
 CESIUM
 CHLORINE
 CHROMIUM
 COBALT

 COPPER
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLUCRINE

 GADOLINIUM
 GALLIUM
 GERMANIUM
 GOLD
 HAFNIUM

 HOLMIUH
 IODINE
 IRIOIUM
 IRON
LANTHANUM

LEAD
LITHIUM
LUTETIUM
MAGNESIUM
MANGANESE

MERCURY
MOLYBDENUM
NEOCVM1UM
NICKEL
NIOBIUM

OSMIUM
PALLADIUM
PASECOYMIUM
PHOSPHORUS
PLATINUH
                MOHAWK
             NH3 INJECTION
         MCG/SEC
 FILTER               XAD-Z
                                 1ST  IMPINGER C OMC  2ND t 3RD IMPINGERS
U
.0  E+00
.622E»00
.825E+01
.622E+02
.0  E + OC

.2Q7E-01
.0  E*00
.373E+01
.104E+00
.0  E+00
   .415E+01
   .0  E*00
   .0  E«00
   .B30E+01
 > .207E+03

 > .207E+03
   .419E+OC
   .207E+00
   .207E+00
   .0  E*00

   .0  E+00
   .199E*02
   .145E+00
   .0  E+00
   .0  E+00

   •0  E*00
   .4156-01
   .0  E+00
U  .0  E+00
   .0  E+Ofl

   .1B9E+02
   .1451*01
   .207E-01
U  .0  E+00
   .2906+01

 < .332E+00
   .207E+OG
   .622E+00
 > .206E+03
   .0  E+00

   .0  E+00
   .0  E+OC
   .0  E+00
   .456E+G2
   .0  E+OC
   .0  E+00
   .0  E+00
   .0  E+00
   .341E+02
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   •0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
0  .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   •0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

 < .273E+01
   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00

   .0  E+00
   .0  E+00
   .0  E+00
   .0  E+00
   .119E+03
  .0  E+00
  .0  E+00
  .0  E+00
  .419E+01
  .0  E+00

  .0  E+00
  .0  E+00
  .0  E+00
  .0  E+00
  .0  E+00

  .0  E+00
  .0  E+00
  .0  E+00
  •176E+02
  .0  E+00

  .2S1E+02
  .0  E+00
  .0  E+00
  .0  E+00
  .155E+03

  .0  E+00
  .419E+00
  .0  E+00
  .0  E+00
  .0  E+00

  •0  E+00
  .0  E+00
  .0  E+00
  .0  E+00
  .0  E+00

  •0  E+00
  .0  E+00
  .0  E+00
  .0  E+00
  .335E+01

< .502E+00
  .0  E+00
  .0  E+00
  .S86E+01
  .0  E+00

  .0  E+00
  .0  E+00
  .0  E+00
  .0  E+00
  .0  E+00
                                                            K  .0  E+00
                                                             < .159E+01
                                                             < .63BE+01
                                                            N  .0  E+00
                                                            N  .0  E+00
                                                            N
                                                            N
                                                            N
                                                         N
                                                         fc

                                                         N
                                                         N

                                                         N
                                                         N
                                                         N
                                                         N
                                                         N

                                                         N
                                                         N
                                                         N
                                                         N
                                                         N
                                                         N
                                                         N
                                                         N

                                                         N
                                                         N
                                                         N
                                                         N
                                                         N
.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0
.0
.0
.0
.0

.0
.0
.0
• 0
.0

.0
.0
.0
.0
.0

.0
.0
.0
.0
.0

.0
.0
.0
.0
• 0
E+00
E+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00

E+00
E+00
E+00
E+00
E+00
                                                         <  .319E+00
                                                         h   .0  E+00
                                                         N   .d  E+00
                                                         N   .0  E+00
                                                         K   .0  E+00

                                                         K   .0  E+00
                                                         K   .0  E+00
                                                         N   .0  E+00
                                                         K   .0  E+00
                                                         N   .0  E+00
    STACK  GAS

       .0   E+00
.622E+00  .207E+03

     >  .232E+03
       •41SE+00
       .207E+00
       •201E+00
       •195E+03

       .0   E+00
       •2G3E+02
       .14SE+00
       .0   E+00
       .0   E+00

       .0   E+00
       .4156-01
       .0   E+00
       .0   E+00
       .0   E+00

       .189E+02
       .145E+01
       .207E-01
       .0   E+00
       •625E+01

     <  .3fl8E»Ol
       .2C7E+00
       .622E+00
     )  .211E+03
       .0   E+00

       .0   E+00
       .0   E+00
       .0   E+00
       .4S6E+02
       .119E+03

-------
     MASS/HIE
                                   MCHAHK
                                NH3 INJECTION
                           MCG/SEC
                   FILTER               XAO-2
DC
I
re
ui
 MOO IUM
 RUBIDIUM
 HUIHENIUN

 SAMARIUM
 SCANDIUM
 SELENIUM
 SIIICCN
 SILVER

 SODIUM
 STRONTIUM
 SULFUR
 TAMALUH
 TELLURIUM

 TERBIUM
 THALLIUM
 THOR IUM
 TNUL IUM
 TIN

 TITANIUM
TUNGSTEN
URANIUM
VANADIUM
YTTERBIUM

VTTRIUM
ZINC
ZIRCONIUM
                       U
   .0   E+00
   .0   e»oo
   .0   E*00
   .2076*00
   .0   E+OC

   .0   E+00
   .415E+OC
   .B92E+OC
 >  .1916*03
   .0   E+00
                       U  .0  E+OC
                          .0  E+OC
                        > .995E+02
                          .0  E+00
                          .207E-01

                          .0  E+00
                          .0  E+00
                          .0  E+00
                          .207E-01
                          .830E+OC
U
   0  E+00
  .0  E+00
  .622E+OC
> .201E+03
  •394E+00

  .0  E+00
  .398E+02
  .0  E+00
.150E+04
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.I19E+03
.0  E+00
.0  E+00
.0  E+00
.0  E+00

.0  E+00
.0  E+00
.0  E+00
1ST IMPINGER £ OMC 2ND C 3RD  IMPINGERS       STACK  GAS

       .0  E+00         N  .C  E+00             .150E+04
       .0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         f.  .C  E+00             .0   E + 00
       .0  E+00         *  .0  E+00             .207E+00
       .0  E+00         ft  .0  E+00             .0   E+00

       .0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         K  .0  E+00             .M5E + 00
       .419E+00         N  .0  E+00             .1316+01
       .0  E+00         N  .0  E+00          >  .1S1E+03
       .2S1E+03         N  .0  E+00             .2516+03

    U  .0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         N  .0  E+00             .0   E+00
     > .415E+04         N  .0  E+00          >  .424E+04
       .0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         N  .0  E+00             .207E-01

       .0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         h  .0  E+00             .0   E+00
       .0  E+00         fc  .0  E+00             .0   E+00
       .0  E+00         N  .0  E+00             .2076-01
       .0  E+00         N  .0  E+00             .830E+00

       .1136+03         K  .0  E+00             .232E+03
       •0  E+00         N  .0  E+00             .0   E+00
       .0  E+00         N  .0  E+00             .622E+00
       .0  E+00         N  .0  E+00          >  .201E+03
       .0  E+00         N  .0  E+00             .394E+00

       .0  E+00         N  .0  E+00             .0  E+00
       .167E+02         N  .0  £+00             .566E+02
       .0  E+00         N  .0  E+00             .0  E+00

-------
ro
i
 MASS/TIME

 ELEMENT

 AlUKIMJH
 ANTINONV
 ARSENIC
 BARIUM
 BERYLLIUM

 BISMUTH
 BORON
 BROMINE
 CADMIUM
 CALCIUM

 CERIUM
 CESIUM
 CHLORINE
 CHROMIUM
 COBALT

 COPPER
 DYSPROSIUM
 ERBIUM
 EUROPIUM
 FLUORINt

 GADOLINIUM
 GALLIUM „
 GERMANIUM
 GOLD
 HAFNIUM

 HOLMIUM
 IODINE
 IRIDIUM
 IRON
LANTHANUM

LEAD
LITHIUM
LUTE1IUM
MAGNESIUM
MANGANESE

MERCURY
MOLYBDENUM
NECCYMIUM
NICKEL
N1CBIUM

OSMIUM
PALLADIUM
PASEOCYMIUM
PHOSPHORUS
 PLATINUM
                                       MOHAWK
                                    NH3  INJECTION
                                MCG/S6C
                        FUEL OIL           STACK GAS
   .4346*04
   .0  6*00
   .0  6*00
 < .1736*02
 < .1736*02

 < .1736*02
 < .1736*02
   .1736*03
 < .1736*02
   .4516*04

 < .1736*02
 < .1736*02
   .1046*04
   .347E*03
 < .1736*02

   .1736*05
 < .173E*02
 < .1736*02
 < .173E*02
   .121E*03

 < .1736*02
   .5206*02
 < «173E*02
 < .1T3E*02
 < ,173E*02

 < .173E*02
 <  .173E*02
 <  .173E*02
   .7986*04
 <  .1736*02

   *l046*03
   .5206*02
 <  .1736*02
   .2606*04
   .6946*03

   .173E*01
 <  .1736*02
 <  .1736*02
   .4686*05
<  .1736*02

<  .1736*02
<  .1736*02
 <  .1736*02
   .104E*04
   .347E*04
       .0  6*00
,6226*00  .2076*03

    >  .2326*03
       .4156*00
       .2076*00
       .2076*00
       .1556*03

       .0  E*00
       .2036*02
       .1456*00
       »0  6*00
       .0  6*00

       .0  6*00
       .415E-01
       .0  E*00
       .0  6*00
       .0  e*oo

       .1896*02
       .1456*01
       .2076-01
       .0  6*00
       .6256*01

    <  .3886*01
       .2076*00
       .6226*00
    )   .2116*03
       .0   6*00

       .0   6*00
       .0   6*00
       .0   6*00
       .4566*02
       .1196*03

-------
    MASS/TIME

    ELEMENT

    POTASSIUM
    RHEMUM
    RHCD1UH
    RUBIDIUM
    RUTHENIUM

    SAMARIUM
    SCANDIUM
    SELENIUM
    SILICON
    SILVER

    SODIbH
    STRONTIUM
    SULFUR
    TANTALUM
    TELLURIUM

    TERBIUM
    THALLIUM
    THORIUM
    THULIUM
    TIN

T  TITANIUM
£0  TUNGSTEN
^  URANIUM
    VANADIUM
    YTTERBIUM

    VITRIIM
    ZINC
    IIRCCNIUM
               MCHAWK
            NH3 INJECTION
        MCC/SEC
FUEL CIL           STACK GAS
  .173E+05
< .173E»02
  .0  E+CC
< .L73E+02
< .U3E + C2

< .173E+02
< .173E+02
< .173E+C2
  ,113E+Ct
< .173E+C2

  ,156E*C3
  ,173E»C2
< . 173E+02
< .173E*OZ
< .173E*02
< .121E»03
< .173E+Q2
< .173E*02

  .156E+04
< .173E*C2
< .173E»C3
< .173E+C2

< ,173E*02
  .3^7E*03
< ,173E*02
.150E»04
.0  E*00
.0  E»00
.207E»00
.0  E+00

.0  E»00
.
-------
cc
I
ro
          IN
 ELEMENT

 ALUMINUM
 ANTIMONY
 APSEMC
 BARIUM
 BERYLLIUM

 BISMUTH
 BCRCN
 BROMINE
 CADMIUM
 CALCIUM

 CERIUM
 CESIUM
 CHLCPINE
 CHPOHIUN
 COBALT

 COPPER
 OVSPBCSIUM
 ERBIUM
 EUROPIUM
 FLUORINE

 GADOLINIUM
 GALLIUM
 GERMANIUM
 GCLD
 HAFNIUM

 HCLMIUM
 IODINE
 IPIDIUM
 IRON
LANTHANUM

LEAD
 LITHIUM
LUTETIUM
 MAGNESIUM
 MANGANESE

MERCURY
MOLYBCENUM
NECDYMIUM
NICKEL
NIOBKM

OS"UUM
PALLADIUM
PASECDYH1UH
FHCSPHCkUS
                                       MCHAhK
                                    NM3 INJECTION

                                HEATER PASS BALANCE
                  FUEL OIL        OUT = STACK GAS     REFINERY CAS NOT  SAMPLED
                           TOTAL IN                    TOTAL  OUT
                      .1T3E+03
 X<.U3E + 02
 X<.173E+02

 X<.173£+02
 X<.173E»02
3
 X<.173E»02
                      .451E+04
                              X<.173E»OZ
                              X<.173E+02
                      .347E*03
                              X<.I73E*C2
                      .173E+05
                             X<.173E+02
                             X<.173E+02
                             X<. 173E+02
                     .121E+03
                             X<.173E+02
                     .520E+02
                     .798E«04
 X<.173E»02
 X<.173E»02
 X<.173E*02

 X<.173E»02
 X<.173E»02
 X<.173E»02
»
 X<.173E*02
                     .104E*03
                     .520E»02
                             X<.173E*02
                     .173E*01
                             X<.173E*C2
                             X<.173E*02
                             X<.173E*02
                             X<.172EtOZ
                             X<.I73E+02
                                                                    i
                       ,622E*00
-------
10
            IN =
   ELEMENT

   POTASSIUM
   RHENIUM
   RHOCIUM
   RUBIDIUM
   RUTHENIUM

   SAMARIUM
   SCANDIUM
   SELENIUM
   SILICON
   SILVER

   SOOltH
   STRONTIUM
   SULFUR
   TAN1ALUM
   TELLURllM

   TERBIUM
   THALLIUM
   THORIUM
TO  THULIUM
                     MOHAWK
                  NH3  INJECTION

              HEATER MASS BALANCE
FUEL OIL       CUI = STACK GAS
         TCTAL IN
    TITANIUM
    TUNGSTEN
    URANIUM
    VANADIUM
    VTTERBILH

    YTTRIUM
    ZINC
    2IPCCMUM
    ,173E*05
            X<.173E»02

            X<.173E«-C2
            X<.1T3E*02

            X<.173E+02
            X<.173E+C2
            X<.173E+02
    .U3E+06
            X<.173E«02

    .I56E+G3
    .173E+C2
    .815E+05 
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                                  APPENDIX  C



                         FLOWRATE AND COLLECTION  DATA

Fuel oil flowrate
Fuel gas flowrate
Heat input
Fuel oil
Refinery gas
Total
Flue gas flowrate
Gas collected
SASS
Method 5/17
02, percent dry
Moisture, percent
Units
g/sec
(Ib/hr)
M3/sec
(103 scfh)

MW
(million Btu/hr)
MW
(million Btu/hr)
MW
(million Btu/hr)
dscm/sec
(dscfm)

dscm
(dscf)
dscm
(dscf)


Baseline
173.5
(1,375)
0.166
(21.1)

7.39
(25.2)
5.86
(20.0)
13.2
(45.2)
3.328
(7,051)

24,992
(882.58)
1.9900
(70.277)
2.6
15.8
NH3 Injection
173.4
(1,375)
0.167
(21.2)

7.51
(25.6)
5.86
(20.0)
13.4
(45.6)
3.350
(7,098)

25,523
(901.34)
1.8382
(64.915)
2.5
17.7
       At standard conditions of 20°C (68°F) and 1 atm, one gram-mole of an



ideal gas occupies 24.04 liters
                                     C-l

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                                TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-86-005a
                           2.
                                                       3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
 Environmental Assessment of NHg Injection for an
 Industrial Package Boiler; Volume I. Technical
 Results                                	
                                        5. REPORT DATE
                                        February 1986
                                        6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 C. Castaldini,
R. DeRosier, and L. R. Waterland
                                                      8. PERFORMING ORGANIZATION REPORT NO.
            TR-83-139/EE
9. PERFORMING ORGANIZATION NAME ANO ADDRESS
 Acurex Corporation
 Energy and Environmental Division
 P.O. Box 7555
 Mountain View,  California  94039
                                                       10. PROGRAM ELEMENT NO.
                                        11. CONTRACT/GRANT NO.
                                         68-02-3188
T2. SPONSORING AGENCY NAME ANO AOORESS
 EPA, Office of Research and Development
 Air and Energy Engineering Research Laboratory
 Research Triangle Park, NC 27711
                                                       13. TYPE OF REPORT ANO PERIOD COVERED
                                                       Task Final; 1/83 -1/84
                                        14. SPONSORING AGENCY CODE
                                          EPA/600/13
15. SUPPLEMENTARY NOTES AEERL project officer is Joseph A.
919/541-2920. Volume II is a Data Supplement.
                                        McSorley, Mail Drop 65,
is. ABSTRACT
              repOrt discusses emission results from comprehensive flue gas sam-
 pling of a gas- and oil-fired industrial boiler equipped with Exxon's Thermal DeNOx
 Ammonia Injection Process for NOx reduction. Comprehensive emission measure-
 ments included continuous monitoring of flue gas emissions; source assessment sam-
 pling system (SASS) tests; EPA Method 5/17 for solid and condensible particulate
 emissions and ammonia emissions; controlled condensation system for SO2 and SO3;
 and N2O emission sampling. Ammonia injection at a NH3/NO molar ratio of 2. 52
 gave a NOx reduction of 41% from an  uncontrolled level of 234 ppm to a controlled
 level of 137 ppm.  NH3 emissions increased from 11 ppm for the baseline to an aver-
 age of 430 ppm for ammonia injection. Nitrous oxide, N2O, was reduced 68% from
 a 50 ppm baseline  level  to a 17 ppm controlled level. Total particulate emissions
 increased by an order of magnitude from a baseline of 17. 7 ng/ J to a controlled
 level of  182 ng/J. This increase is in part attributed to formation of ammonia sul-
 fate and bisulfate from residual ammonia and SOx. Total organic emissions were at
 a moderate level and showed a relative concentration in the nonvolatile category.
 Organic emissions of CO  and trace inorganic elements were not significantly affec-
 ted by  ammonia injection.
 7.
                             KEY WORDS ANO DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                                                     c.  COSATI Field/Group
 Pollution
 Nitrogen Oxides
 Ammonia
 Flue Gases
 Boilers
 Natural Gas
         Residual  Oils
         Sampling
Pollution Control
Stationary Sources
Package Boilers
Industrial Boilers
Thermal DeNOx
13B
07B

21B
ISA
21D
14B
13. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (This Report)
                                           Unclassified
                                                                   21. NO. OF PAGES
                                                         112
                            20. SECURITY CLASS (This page)
                            Unclassified
                                                     22. PRICE
EPA Form 2220-1 (9-73)
                          C-2

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