&EPA
United States
Environmental Protection
Agency
Research and
Development
EPA-600/7-86-Ol4b
April 1986
ENVIRONMENTAL ASSESSMENT OF
A RECIPROCATING ENGINE
RETROFITTED WITH
SELECTIVE CATALYTIC REDUCTION
Volume II. Data Supplement
Prepared for
Office of Air Quality Planning and Standards
Prepared by
Air and Energy Engineering Research
Laboratory
Research Triangle Park NC 27711
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development. U S Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields
The nine series are:
1 Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5 Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7 Interagency Energy-Environment Research and Development
8 "Special" Reports
9 Miscellaneous Reports
This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series Report^ m this series result from the
effort funded under the 17-agency Federal Energy/Environment Research and
Development Program These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects; assessments of, and development of. control technologies for energy
systems: and integrated assessments of a wide range of energy-related environ-
mental issues.
EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161
-------
EPA-600/7-86-014b
April 1986
ENVIRONMENTAL ASSESSMENT OF A
RECIPROCATING ENGINE RETROFITTED WITH
SELECTIVE CATALYTIC REDUCTION
Volume II
Data Supplement
By
Carlo Castaldini and Larry R. Waterland
Acurex Corporation
555 Clyde Avenue
P.O. Box 7555
Mountain View, CA 94039
EPA Contract 68-02-3188
EPA Project Officer: J. A. McSorley
Air and Energy Engineering Research Laboratory
Research Triangle Park, North Carolina 27711
for
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Research and Development
Washington, DC 20460
-------
ABSTRACT
Comprehensive emission measurements and 15-day continuous emis-
sion monitoring was performed for a 1. 500 kW (2000 hp) gas-fired, four-
stroke turbocharged reciprocating engine equipped with an ammonia-based
selective catalytic reduction system for NOX control. Emission reductions
were held at about 80 percent using an ammonia-to-NO ratio of about 1.0.
NOX levels at the catalyst inlet ranged from 2.200 to 2.600 ppm at an exhaust
gas oxygen level of about 11 percent. NOX levels at the catalyst outlet ranged
between 65 and 120 ppm. The catalyst had relatively minor effect on CO and
particulate emissions, but increased total cyanides by three orders of magni-
tude (from 7 pg/dscm to 2.4 mg/dscm) across the catalyst. Total organics
decreased about 70 percent from 4.9 mg/dscm to 1. 5 mg/dscm. Analyses
showed benzene and toluene as the major organic constituents in the cata-
lyst exhaust. Polycyclic aromati.cs also decreased across the catalyst. The
15-day continuous monitoring tests showed that the catalyst was generally
able to maintain NQg reductions at about 80 percent. Departures from these
levels occurred only during brief load surges and ammonia flowrate spikes.
11
-------
CONTENTS
Section Page
1 Introduction 1-1
2 Engine Operation Data 2-1
3 Sampling Data Sheets 3-1
3.1 Preliminary Stack Measurements 3-2
3.2 Operating Data Tables for SASS 3-9
3.3 Operating Data Tables for HCN Sampling Train ... 3-20
3.4 Operating Data Tables for NHs Sampling Train . . . 3-25
3.5 Operating Data Table for VOST 3-30
4 Analytical Laboratory Results 4-1
4.1 Total Chromatographable Organlcs (TCO), Gravimetric
Organics (GRAV), Gas Chromatography/Mass Spectrometry
(GC/MS), and Infrared (IR) Spectra of Total SASS
Sample Extracts 4-2
4.2 Gas Chromatography/Mass Spectrometry (GC/MS) of VOST
Traps 4-11
4.3 Ammonia, Cyanide, and ^2° Analyses 4-14
ill
-------
SECTION 1
INTRODUCTION
The purpose of this data supplement Is to document data in greater
detail than was possible in Volume I (Technical Results) of this report. It
is intended to provide sufficient detail for researchers to perform their own
analysis of the data obtained. Readers are referred to the technical volume
for objectives, description of source emission results, interpretations, and
conclusions.
The remaining sections of this data supplement contain the following
information:
• Section 2, Engine Operating Data
— Engine load, compressor output, fuel flow, pressures, and
temperatures
• Section 3, Sampling Data Sheets
— Preliminary stack measurements; operating data tables for SASS
(for solid particulate and organics sampling), and impinger
sampling systems for HCN and NH3 sampling
• Section 4, Analytical Laboratory Results
— Total chromatographable organic (TCO) and gravimetric (GRAY)
results, determination of semivolatile organic compounds by gas
1-1
-------
chromatography/mass spectrometry (GC/MS) and Infrared (IR)
spectra of total sample extracts; determination of volatile
organlcs by GC/MS of VOST sample traps; ammonia, cyanide, and
analysis results.
1-2
-------
SECTION 2
ENGINE OPERATION DATA
2-1
-------
ENGINE TEST DATA ~ COMPREHENSIVE TESTING
ro
Time (August 3, 1984)
Natural gas meter (ft*)
Engine rpm
1 Fuel header pressure (pslg)
! Cooling water pressure (pslg)
Lube oil pressure (pslg)
Exhaust manifold temperature (*F)
Manifold gas pressure (pslg)
Air manifold pressure (pslg)
Air manifold temperature (*F)
Cylinder exhaust temperature CF):
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
No. 6
No. 9
No. 10
NO. 11
No. 12
Turbocharger out temperature, L CF)
Turbocharger out temperature, R CF)
NH3 flowrate (scfh)
Compressor suction (pslg)
Compressor Intermediate (pslg)
Compressor discharge (pslg)
Suction temperature CF)
No.l A 2 discharge CF)
Interstage temperature CF)
No. 3 & 4 discharge CF)
Catalyst Inlet temperature CF)
8:15
12.114.600
322-331
25
36
57
718
17
4.0
150
680
820
800
720
760
550
710
680
720
705
690
750
740
700
565
587
1.110
2.850
80
222/225
84
194/190
750
9:00
12.123,400
320-330
25
36
57
719
17
4.0
152
670
825
800
720
770
580
715
680
720
700
695
745
730
710
575
583
1.130
80
225/230
82
190/195
740
10:18
12.139.000
325-332
24.5
36.5
56.5
716
16.8
3.85
153
650
840
810
720
780
620
720
680
730
700
700
760
740
720
590
585
1.140
2.890
82
230/235
86
195/195
760
11:30
12.151.900
325-330
24.5
36.5
55.4
720
17.0
3.85
154
610
840
810
720
780
620
700
760
720
740
585
1.140
2.895
82
235/240
91
195/200
12:55
12.178,100
325-330
24.2
36.2
56
716
17.0
3.85
157
600
840
810
725
780
650
730
700
740
730
700
760
730
725
610
587
1,140
2.900
85
235/245
91
200/205
14:25
12.186.100
320-330
24.2
36.2
56
715
17.0
3.80
158
560
850
820
730
780
660
730
690
740
730
700
760
730
740
620
583
1.150
2.899
84
245
95
200/205
15:36
12,199.500
320-333
24
36.5
56
762
17.2
3.60
158
600
845
815
730
780
660
730
700
740
730
720
762
730
730
620
583
1.150
2.898
740
-------
UN IT No.
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13
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ALISO CANYO.. - STATION 23
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ALISO CANYO.. - STATION 23
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ALISO CANYO.^- STATION 23
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TIME
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12
13
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-------
UNIT No.
ALISO CANYO._ - STATION 23
MAIN COMPRESSOR ENGINE LOG
DATE -
TIME
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7/6
11
12
13
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DATE y-J -JV
1
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I
1
1
I
1
i
1
1
TIME
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TIME
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TURB. OIL
F.W.
-70
•;-^
37
O.P.
^
-*in
3M
LOW
SUCT.
£81
1>OI
stt'Z
INTER
STAGE
/ /m
\\foQ
tf/o
HIGH
DISCH.
46,!£
Wot
^76-1
AIR
MTR.
52.
LS
TO
i
TEMPERATURES
TURB. WTR.
F.W.
14r>
• i
/VV
O.P. '
14*-
;%
LUBE OIL
IN-
?o
^/N
/25"
OUT
13,0
\6b
/3$
JKT. WTR.
IN
|-2>|
\ ^^\
y ? G.
OUT
13
7
1^9
/^3
LOW
SUCT.
<^
<6
._-
72r
No. 4
DISCH.
/92_
"!"/•.'•'
f°fZ
No. 3
DISCH.
|<^o
2.Cf~>
/$3
INTER
STAGE
93
\fjA
It,
No. 2
DISCH.
212
;?^(£
^aL
No. 1
DISCH.
Z2/5
j.^rt
7'L^
INF.
STEP
•
PYROMETER READINGS
1
Tlo
ft to
&~o
2
^Ifc
8 I/O
Zlo
1 OPERATING HOURS
PREVIOUS
; TODAY
TOTAL
8 AM OIL FILTER Af
HEMARKS:_£&1<2.
3
•BOO
£70
. ^
**7 t.^/
7 /*"-
-12
3
4
720
-770
5
7^c>
~1$O
-f£O
6
5dso
Liln
rvo
7
72.o
"*-/<")
720
8 9
&><2£> 7*2. o
*7dJ9 ~7*/O
-7CO 7lt)
10
"fcr.
7,; ^
-7/0
CRANKCASE OIL
PRESENT i)Av
PREVIOUS .
TOTAL GALS- •
I.S.C. OIL.
ft .' ^ «*.,.,•
-^-*
' •/-/'
11
W^iQ
IL/&
^7$
COMP. CYL. OIL
PRESENT /v>.
PREVIOUS -r>-~
TOTAL GALS
V
f^r /2*%,>,-7/fc/
/
7
12
750
74 v
7t->0
13
*7io
V] ;
73o
14
"7/o
"r'<^
7/0
BIJUR LUBRICATOR
DAY
EVE | fi,T.
MID |
TOTAL 2
r ~ j
X' i *
-------
UNIT No.
ALISO CANYO.. - STATION 23
MAIN COMPRESSOR ENGINE LOG
DATE *' V V V
-
TIME
8AM
4PM
12 MID
RPM
3-=x3-
U* -
' PRESSURES
LUBE OIL
PUMP
/OQ
9*
BRNG.
£5-
i'Y
FUEL
HDR.
1$
-
-------
ro
UNIT No
ALISO CANYO,. - STATION 23
MAIN COMPRESSOR ENGINE LOG
DATEAUG_1?M
-
TIME
BAM
4PM
12 MID
TIME
BAM
4PM
12 MID
TIME
BAM
4PM
12 MID
RPM
•5"5/
A3O
PRESSURES
LUBE OIL
PUMP
*2tf
an
BRNG.
•
£>¥
5"V
FUEL
HDR.
c?y.4*
r&J
MAN.
/%
11
MAN.
AIR
//, /
.375-
JKT.
WTR.
76.1?
\3(f
TURB. OIL
F.W.
'3<%
19
«jfl
O.P.
3/?
t3)? "
LOW
SUCT.
97?
INTER
STAGE
1190
/fiXO
HIGH
OISCH.
J?£?0
^^/^?
AIR
MTR.
#3
50
TEMPERATURES
TURB. WTR.
F.W.
/ 7<^
/5&
O.P.
/JLJ
XT/.
LUBE OIL
IN
y//y
/3O
OUT
/£-/
X59
JKT. WTR.
IN
/S~7
rt(.
OUT
/^^
/3"3
LOW
SUCT.
<%tj
No. 4
DISCH.
^x / ^^
^^ ' v_X
<#oo
No. 3
DISCH.
/^*7
/77
INTER
STAGE
/r>7
^
No. 2
DISCH.
P. 1C"
{??3C>
No. 1
DISCH.
2*/O
39o
•V-Vo
i
746
13o
8
"7?O
6>?0
9
7-fh
v^o
10
7^a
7OO
11
"7Jb
^^rO
12
7^C>
75"O
13
7&O
7VO
14
"7S"t>
*fo
OPERATING HOURS
PREVIOUS
TODAY
TOTAL
8 AM OIL FILTER AP
*
REMARKS: ,0/1 /
;?*!*/. ,
.
CRANKCASE OIL
PRESENT
PREVIOUS
TOTAL QALS
Of
.S.C. OIL
00
COMP. CYL. OIL
PRESENT pM
PREVIOUS^
TOTAL QALS^'1
(
Jk &M
\ &«i-
1 Vl frAf-S.
», -.*£-- /S»r,«^
BIJUR LUBRICATOR
DAY
EVE
MID
TOTAL
fa. Q\-
j
1 /J QTi.
t/Y* /
-------
UNIT No.
k-L.
ALISO CANYON- STATION 23
MAIN COMPRESSOR ENGINE LOG
JTIME
8AM
4PM
DATE
RPM
PRESSURES
LUBE OIL
PUMP
BRNG.
s?C
FUEL
HDR.
MAN.
/7
MAN.
AIR
JKT.
WTR.
TURB. OIL
F.W.
O.P.
1
LOW
SUCT.
57?
INTER
STAGE
1176
HIGH
DISCH.
AIR
MTR.
(O
to
12 MID
37
jr«ME_
8AM
4J»M
12 MID
TEMPERATURES
TURB.WTR.
F.W.
JiL
O.P.
LUBE OIL
IN
OUT
J3£_
/J'J
IN
JKT. WTR.
OUT
LOW
SUCT.
_2o_
No. 4
DISCH.
,206
No. 3
DISCH.
INTER
STAGE
No. 2
DISCH.
No. 1
OISCH.
INF.
STEP
^IME
JLAM_
4PM
12 MID
PYROMETER READINGS
8
6
-L^.._L>±: LZL
OPERATING HOURS
PREVIOUS
TODAY
TOTAL
8 AM OIL FILTER AP P_
CRANKCASE OIL
PRESENT °eJe
PREVIOUS fin*
TOTAL GALS
~3OM&.
JQo'Ai-i.
I.S.C. OIL .:..":. -. . .
COMP. CYL. OIL
PRESENT %?;
PREVIOUS ff'o
TOTAL GALS
-T>5~5rtZT
^* orf£ • _ *
_$•*"* O^*»*
BIJUR LUBRICATOR
DAY
EVE
MID
TOTAL
•e-
/ <^-h
4? or.
/%ors.
iss* ///,:„ r^i r wL*, ^,r
-------
ro
i-»
on
ALISO CANYOVT- STATION 23
MAIN COMPRESSOR ENGINE LOG
T"TF
DATE
J1ME
BAM
4PM
12 MID
RPM
230
LUBE OIL
PUMP
BRNG.
FUEL
HDR.
MAN.
PRESSURES
MAN. JKT.
AIR WTR.
.-36.Q.
TURB. OIL
F.W.
O.P.
37
LOW
SUCT.
INTER
STAGE
HIGH
DISCH.
222
AIR
MTR.
TIME
BAM
4PM
12 MID
TURB. WTR.
F.W.
O.P.
Hto
LUBE OIL
IN
OUT
TEMPERATURES
JKT. WTR. LOW
IN
^L.-^—^'J
OUT
SUCT.
No. 4
DISCH.
No. 3
DISCH.
INTER
STAGE
No. 2
DISCH.
030
No. 1
DISCH.
235-
INF.
STEP
TIME
BAM
4PM
12 MID
PYROMETER READINGS
6 7 T 8
koo_2$o
10
JO'I
IS'O \130 \~1/0 \~7gO
11
12
13
14
OPERATING HOURS
PREVIOUS
TODAY
TOTAL
CRANKCASE OIL
PRESENT
PREVIOUS K|&v
TOTAL GALS
COMP. CYL
PRESENT^
PREVIOUS^, .„._,.
TOTAL QALS
OIL
^T, •;—-
f? V:--
8 AM OIL FILTER AP _
REMARKS;.^?
I.S.C. Oil ______
BIJUR LUBRICATOR
DAY
EVE
MID
TOTAL
-------
r NO._/T_:
ALISO CANYO,. - STATION 23
MAIN COMPRESSOR ENGINE LOG
DATE
TIME
SAM
4PM
12 MID
RPM
-01
1
PRESSURES
LUBE OIL
PUMP
)QO
BRNG.
*^
FUEL
HDR.
2*}
MAN.
/?
MAN.
AIR
Ll L
JKT.
WTR.
3S.f
TURB. OIL
F.W.
3*
O.P.
?*
LOW
SUCT.
ZIL
INTER
STAGE
/no
HIGH
DISCH.
2927
AIR
MTR.
rc»
TIME
SAM
4PM
12 MID
TEMPERATURES
TURB.WTR.
F.W.
IS*.
O.P.
y38
LUBE OIL
IN
//fr
OUT
ft-?
JKT. WTR.
IN
1^
OUT
/73
LOW
SUCT.
77
No. 4
DISCH.
y?0
No. 3
DISCH.
Jt7
INTER
STAGE
7?
No. 2
DISCH.
Z/7
No. 1
DISCH.
-/£<:
INF.
STEP
•
ro
TIME
SAM
4PM
12 MID
PYROMETER READINGS
1
&S3
•
2
£?<=>
3
•%t>0
4
73o
5
770
6
r/o
i
C.7&
8
C.S&
9
7?0
10
7/0
11
7Oe3
12
yf/>
13
-?.'//)
14
7OO
OPERATING HOURS
PREVIOUS
TODAY
TOTAL
CRANKCASE OIL
PRESENT ^
,PREVIOUSm|n.
TOTAL GALS
COMP.CYL. OIL
PRESENT ^J
PREVIOUSm;n.
TOTAL GALS
~3
-------
SECTION 3
SAMPLING DATA SHEETS
3.1 PRELIMINARY STACK MEASUREMENTS
3.2 OPERATING DATA TABLES FOR SASS
3.3 OPERATING DATA TABLES FOR HCN SAMPLING TRAIN
3.4 OPERATING DATA TABLES FOR NH3 SAMPLING TRAIN
3.5 OPERATING DATA TABLE FOR YOST
3-1
-------
3.1 PRELIMINARY STACK MEASUREMENTS
3-2
-------
PRELIMINARY VELOCITY TRAVERSE
PLANT ALISO dflW
DATE AufrJ ! (QP V
LOCATION PRUT (»
STACK I.D. l^1'
BAROMETRIC PRESSURE, in. HI.
STACK GAUGE PRESSURE, in. H;n "
- S C fcr
SCHEMATIC OF TRAVERSE POINT LAYOUT
TRAVERSE
POINT
NUMBER
Id
n
ISL
\d
1
AVERAGE
EPA (Durt 233
472
VELOCITY
HEAD
dp,), in.HjO
.n
. 05-
STACK
TEMPERATURE
(Ts). *F
tJtt)
•Un
TRAVERSE
POINT
NUMBER
AVERAGE
vELOcrrr
HEAD
bps). in.HjO
STACK
TEMPERATURE
3-3
-------
Plant
ISOKINETIC SAMPLING WORKSHEET
SC6- Peformed by.
Sample Location
Test No./Type (_
K = 782.687 (Cp)2 (1-BWO)2 Ps Md
M
where: K = Constant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimensionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Md(l-Bwo) + 18(BWO)
Abolute meter pressure (in. Hg)
782.687 ( )2 (1- )2 ( ) ( )
( )2 ( ) ( )
CP
Bwo
*fr
Md
K0
oL
Ms
Pm
K
o#{
&13-
-,6
CCh 5"
Oz II
A)a «4
3.5S^>
/,O3
-------
ISOKINETIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
P1 ant
Date
Performed by feLU-ftM(XV\VV
Sample Location
Test No./Type |_
d
where: Nj = Nozzle diameter (inches)
Average pressure differential across the
.orifice meter (in. HgO)
Temperature stack gas, average (°F)
Temperature of gas meter, average (°F)
Stack gas velocity pressure (in ^0)
/ ( ) ( + 460) \-25
V( ) ( + 460) ( )/
AH
TS
Tm
AP
Nd
/.«
7^0
no
1.0 3
crcTO
,5o-k
AH = K (Nd) J2 (AP)
where: AH - Pressure differential across the orifice meter (in H20)
Nozzle diameter
Temperature of
Temperature of
, actual (inches)
gas meter (°F)
stack gas (°F)
Stack gas velocity pressure (In HgO)
(._. L
Magic number
,4 ( + 460) ( }\
' ( + 466) l >)
( )4
Nd
Tm
TS
AP
AH
K(Nd)<
,«r
^.3«6
3-5
-------
PRELIMINARY VELOCITY TRAVERSE
PLANT.
DATE_
VDNJ
STACK U)._l2_
BAROMETRIC PRESSURE, in. H(
STACK GAUGE PRESSURE, in.
an
SCHEMATIC OF TRAVERSE POINT LAYOUT
TRAVERSE
POINT
NUMBER
1
z
/o
IA
/M
av
AVERAGE
EPA (Out) 233
472
VELOCITY
HEAD
I.5O
/.V5
A/7)
/. /o
STACK
TEMPERATURE
(T,). T
3LI
TRAVERSE
POINT
NUMBER
AVERAGE
VELOCITY
HEAD
<&ps).in.H20
STACK
TEMPERATURE
FomAM
3-6
-------
ISOKINETIC SAMPLING WORKSHEET
Plant AlUl^Q *bC& '_ Reformed by_
Date
[ al
Sample Location
Test No./Type (
K 782.687 (Cp)2 (1-BWO)2 Ps Md
Ko2 Ms
where: K = Constant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimensionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Md(l-BWQ) + 18(BWQ)
Abolute meter pressure (in. Hg)
782.687 ( )2 (1- )2 ( ) ( )
( )2 ( ) ( )
CP
BWO
«^-c
«d
*
Ms
Pm
K
•*<
^/x
*4
cGx -S-
Ox-ll
Wa, ^
S-S37
/.ntfe
ff&S'
31.3^3
3-7
-------
ISQKINETIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
PI ant
SfA-
Pate ft/3
Performed bv
Sample Location^
Test No./Type I
where: NJ
Maaic number ( )4
Nd
Tn
TS
AP
AH
K(Nd)4
,w
-------
3.2 OPERATING DATA TABLES FOR SASS
3-9
-------
CO
I
FIELD DATA
Page j of _3
Flint.
Data
6C<5
Staple Location ^
Sample Type 5f\f£>
Run Number
Implnger Volumes
Initial Final
/:
Met Cain
Probe Length and Type
Motile Site I 1.0. 0
_aL
i
Operator
Ambient Temperature v ^
Barometric Pressure _____
Static Pressure, »HjO)
Filter Number!s) A [
PI tot Coefficient t I.D.
Assumed Moisture _
Molecular Height, Dry,
Heter Box Number _ 'BI
Meter Coefficient,
a Factor A QJ6
Lttk Check: Initial at
Flnit at
PI tot Leak Check: V
Hg. /OI5IFH
Ha. Q3C CfM
.%ft
SASS Condensate
Total VoluM
Traverse
Point
HueMr
dock T1«e
1 14-hr)
Clock
Swpllna
Tlae, Bin
6as Meter
Reading
9/0. /O
Velocity
Head
ltf<).
in. fljo
/.I
/.a
7.2
Orifice Presiure
Differential
(AHl. In. H20
Desired
/.so
/.30
MS
Actual
Temperature *F
Stack
7^7
731
Probe
Ivplnger
60
Organic
Module
335%
6/
Oven
331^
33*
Gas
Heter
In
€6
Out
10
Pu*p
Vacuui
In. Hg
/o
/=»-
/a
-------
Page Jj^ of 3
Orifice Pressure
Differential
(&H). In. H20
Run No. _
CoMents:
pate
Suple Location
-------
Page -^ of 3
U)
»-*
ro
Orifice Pressure
Differential
UH), In. HjO
Run Ho.
COMMfltS:
Fan* 434 3/84
-------
ISOKINETIC PERFORMANCE WORKSHEET & PARTICIPATE CALCULATIONS
Plant SC6- -4i'fa GMVaJ Performed by _
&- *-
Date
Sample Location
Test No. /Type
JTJc£r
Barometric Pressure (in. Hg)
Meter volume (std),
»•« /M/",, • T&\
vu/\V4H)/
/(SBA/to.^
1 '" yi£!4)yy_L2i) + 460 1
Volume of liquid collected (grams)
Volume of liquid at standard condition (scf)
Vlc x 0.04707
Stack gas proportion of water vapor
Vw Std . U*fl
vw std * vm std <«U + ^S^
Molecular weight, stack gas dry
(Ib/lb-mole)
(% C02x 0.44) + (% 02x 0.32) * (X N2+ X CO x 0.28)
(£.5 x 0.44) + (/{.Z x 0.32) * («*.»+4a*«ttx 0.28)
Molecular weight, stack gas wet
(Ib/lb-mole)
Md(l-BWQ) + 18(8^,). (2|3)(1-Afi2) + 1BWtt )
Absolute stack pressure (in. Hg) ,
pstack (in' H20) ,?«r (-2-}
p t 5l...._ ,..^. (JuS) + ._
pb 13.6 * l^iii; * 13.6
pb
Vm std
Vic
vwstd
Bwo
Md
Ms
Ps
j&.s-
fO/.£
J1**f
//
-------
Temperature stack gas, average (°F)
Stack velocity (fps) /— — — .......
/T.avg + 460
85 49 (C ) (v*2P ) ! n '«r
v s s
'•'T 1(7*1 ) + 460
85 49 (&£^]tfl -x* ) 1 — —.. .
~~^ v (^'"'W ("R8*)
Total sample time (minutes)
Nozzle diameter, actual (inches)
Percent isokinetic (*)
17.33 (T$ + 460) (Vw std + Vm std)
0 Vs Ps Md2
17.33 (J5/ + 460) ((//Ki) + $<£})
(_3oo_){J2L_)(^21)(^i«_)
Area of stack (ft2) »» 3.1416
»r2 H- 144 , * ( ^—144
Stack gas volume at standard conditions (dscfm)
60 (1 - B )Vs A / 528 \ / Ps \
MO avg ., i T ^ 46fl i 1 29 92 )
Vs / \ /
\^SL_*460/ \IZ9.9Z)/
Particulate matter concentration, dry (gr/dscf )
1C A^*) *«« 1 9^ flfflS I ICJI^ll I
15.432 piy ', 15.432 * '
vmstd I )
Emission rate of particulate matter (Ib/hr)
0.00857 (Q ) C. , 0.00857 ( )( )
S(std)
TS
Vs(avg)
9
Nd
tl
•s
<>
cs
S(std)
ED
P
7s i
102.
3 oo
A/*
W.7
1.7?
/
3-14
-------
CO
i
Flant
Oate
S&fr
3/6/6*1
Staple Location
Saaple Type
Run Hunter
Operator
FIELD DATA
Implnger Volumes
Initial Final Met Cain
ts& .E>
., «ngT -JS.Q
^55" .535" "g^o
Page \ of 6
Probe Length and Type
Mozzle Size I I.D.
Pilot Coefficient 1 I.D.
AssuMd Moisture
Ambient Temperature -«-
Barometric Pressure
SUtU Pressure, (ibOl -Q/5"
Filter Humberts)
Molecular Weight, Dry. (Hj)
Meter Box Number _
Meter Coefficient
a Factor
3-
SUtci Gel
Lcik Check: Initial
Flntl
Fltot Leak Check:
1 at (2 • H9. .65*1
•t T^T* m./ctfSi
CFH
CFN
SASS Condensate
Total Volume
Traverse
Folnt
NwOier
Clock TlM
(Z4-hr»
Clock
Gas Miter
Reading
1VB). ft>
313-51
33S./JI
Velocity
Head
(4FR).
In. 830
-
'/.s
/•H
Orifice Pressure
Differential
(&H), In. HjO
Desired
(-3
/•60
/.SS"
JJ21
A6S-
Actual
Teaperature *F
Stack
JO
Frobe
55?
653
65^
on
taplnger
67
Organic
Module
7-2
76
Oven
,573
36
Gas
Meter
In
Out
/o£95-
Fu*p
Vacuum
In. Kg
lO
K>
/o
l\
II
rat
Cements:
-------
Page 3. of 3
CO
i-«
en
Orifice Pressure
Different111
(AH). In. H;0
Coenents:
Fomi434 3M4
-------
Page S of 3
I
!-•
*«4
Orifice Pressure
Differential
. In. H20
Dun Ho. \ SAfe€>
Cements:
Fonn43
-------
ISOKINET1C PERFORMANCE WORKSHEET & PARTICULATE CALCULATIONS
Plant SCG- - /kuo ^HytoJ Performed by _
Date £-3 -84 ____
Sample Location f
Test No. /Type s& SS
Barometric Pressure (in. Hg)
Meter volume (std),
17-6a\02>2)yyj2Sj
1)A>*^
°i\
+ 4^6 /
Volume of liquid collected (grams)
Volume of liquid at standard
VI c x 0.04707
condition (scf)
Stack gas proportion of water vapor
ui c*-H m e*rf \ // / / \E& 7 i
If 3 LU III 3 t»U ^^^^^^ ^^^^^^
Molecular weight, stack gas
(Ib/lb-mole)
(X C02x 0.44) * (X 02x 0.32)
(£.S x 0.44) + (/^.x 0.32)
Molecular weight, stack gas
(Ib/lb-mole)
Mdd-B,.,,.) + 18(8,1, (g?.3)(
wo wo •
Absolute stack pressure (in.
Pstack (1n« H20)
b 13.6 '
dry
+ (X N2+ X CO x 0.28)
+ (8i.1+ 0.0£* 0.28)
wet
~\ -0.il ) + 18(P»/i.)
Hg)
pb
vm std
Vic
vw std
8wo
Md
Ms
Ps
**.S
«
//fi
in
M
*
M
J6.S"
Fon»440 3/M
3-18
-------
Temperature stack gas, average (°F)
Stack velocity (fps)
/T.avg + 460
85 49 (C ) t/AP ) I-~T, —
V s s
l(fel) + 460
85 49 (O 8"/\lJ~ t ,j \ 1 ~~~~
* »j (J&.S"} Ve/.l )
Total sample time (minutes)
Nozzle diameter, actual (inches)
Percent isokinetic (X)
17.33 (Ts + 460)(VW std + Vm std)
0 Vs Ps Nd2
17.33 (fa + 460) ((fft) + {.BS7_\}
( 32o )( lot. )( ie.r )( V,i* )
Area of stack (ft2) *= 3.1416
Stack gas volume at standard conditions (dscfm)
60 (1 - B^JVS...- A. / 528 \ / Ps \
9 ('• "• * m] (»•«)
60 (1 -0.il )(t*l )(!.??}/ 528 \ /^M
\
Particulate matter concentration, dry (gr/dscf )
Vmrtd ( - - }
Emission rate of particulate matter (Ib/hr)
0.00857 (0.) C. . 0.00857 ( )( )
J J(std)
Ts
Vs(avg)
9
Nd
XI
AS
«•
cs
S(std)
£
^J
/^
3.o
aft?
S3
f-17
#*•
Fonn44oa
3-19
-------
3.3 OPERATING DATA TABLES FOR HCN SAMPLING TRAIN
3-20
-------
FIELD DATA
Plant
Date
Inplnger Volumes
Initial Final
'1/KJlTb-
Stmple Location
Swple Type
Run Number. t
Operator __
tablent Temperature,
BaroMtrlc Pressure
Static Pressure. (HjO)
Filter Hurt«r(s|
Leak Check: Initial at
Final at
PI tot Uak Check:
O/l/-
Hi,
Hi.
Net Cain
Silica Gel
CFM
SASS Condensate
Total Volum
Probe Length and Type
Nozzle Size • 1.0.
Pltot Coefficient i 1.0.
Asiuaed Moisture
Page I of I
Molecular Weight. Dry. (Mj)
Heter Box Nuaber
Heter Coefficient
a Factor
K •
(T?)
to
I
ro
Travtrte
Point
Clock TlM
U4-hr)
Mock
Gat Iteter
Reading
.tAl
Velocity
Head
-------
Plant
Pit*
/U/.Sfl
Saeyle Location
Sample Type __
Run Number
Operator ___
I1AJJT
Ambient Temperature
BaroMtrlc Pressure
Static Pressure.
Filter Nunbor(t)
FIELD DATA
laplnger ¥oli»«s
Initial Final Hat Cain
(trn
Silica Gel
Leak Check: Initial at Q ' Hg. it
Final at rT* Hg. j<
Pilot Leak Check:
30tCFH
2&CFM
MSS Condensate
Total VoluM
Page / of /
Probe Lmgth and Type
Site I I.D.
Pilot Coefficient a 1.0.
Naliure
Molecular Height. Dry, (Hd>
Heter Box Itaber n
Meter Coefficient
• Factor .
K •
C,
/Tm\
IT?)
»« •
(PI
to
ro
ro
Traverse
Point
Number
Clock TIM
(M-hr)
Clock
Cat Meter
Velocity
Head
llffe
Orifice Pressure
Differential
(AH). In. H20
Desired Actual
Cti
Teaperature *F
Stack
Probe
baplnger
Organic
Module
Oven
Gas
Meter
In
Out
03
qo
_ea
Q)
96
Pueip
Vac wit
In. Hg
Coaaents:
Fem4ai an*
-------
PUnt
Date
ON'
Location AiJT?
Sample Type.
Run Nu«ber _
Operator
tablent Temperature __
Barometric Pressure
Static Pressure. (H20)
Filter NMber(s)
-le
Leak Check: Initial
Final
Pltot Leak Check:
l it 13' Hg.
«t lp* Hg.
FIELD DATA
t«p
-------
Date fltlrt 3,>q?H
. . .. » f\ ivrt if
Staple Location
Sample Type
Hun MMber.
Operator _
- U
Aablent Temperature ..
laroMtrlc Pressure __
Static Pressure, (HfOI
Filter Humberts)
Leak Check: Initial at 11 ' Hg, .OlbCfM
final at "^ Hg, ~ CFM
PI tot Leak Check:
FIELD DATA
VolUMS
Initial Final Met Gain
177
101
Slllce Gel
SASS CondtnttU
Tottl VoluM
Page \ of \
Probe Length tnd Type
HozzU Stz* I 1.0.
Pltot Coefficient I 1.0.
Assueed Moisture
Molecular Height, Dry. IK,
Meter Box Nuaber Q
Meter Coefficient
• Factor
IP)
CO
ro
Tr«v«rt«
Point
U:
Clock TtM
CM-hr)
Clock
Gts Heter
5*1.660
59 /
Velocity
He«d
(tf.l.
In. Bid
Orifice Pressure
Olfferentlel
(AH). In. HjO
Desired
•If
Actual
_ti£
Tcapertture *F
suck
Probe
taplnger
Orgwilc
MoSule
Oven
fet
Niter
In
ft
Out
i
Vtcuuei
In. Hg
901634
IP
to
10
/if
If
fa
fora 461 3/04
-------
3.4 OPERATING DATA TABLES FOR NH3 SAMPLING TRAIN
3-25
-------
PMSQ
0«te fl,i)& t
Staple Location
Staple Type
I
Operetor
Teapereture ,
Beroaetrlc Pressure __
SUtlc Pressure, (NjO)
Filter NuMborU)
ChKkt InltUI
riMl i
pitot Utk Clwckt
-ra
. x^lcfM
Hi. .(*=£CfM
FIELD DATA
Imptngtr Volum
InltUI
Mtt toln
$11 let GtV,
SASS CondMMU _
ToUl VoluN 30-0
I of }
Probf Length «nd Type
NOHU Size I I.D.
Pilot CotfrtclMt » 1.0.
ASSUMd HDlltUM
HalKuUr *loht. Dry. (Ntfl __
Httor Box Nuri»r /\fjft~
H*t«r CMfflclMt
a Ftctor _
K •
CO
ro
at
Trtvertt
Point
SwplUa
TIM, •!•
DtS:
6» Miter
Wf.
Velocity
HMd
Or Ulce Pressure
OlfferentUl
UN), I*. «20
Desired
,16
Actuel
Stick
Probe
taplnger
Orgtnlc
Nodule
Oven
(Ul
Meter
In
Out
$3
^
VUUUB
1*. HI
8:
1?
901593
ronxei VM
-------
CO
ro
FIELD DATA
Page / of /
Tint 5C.& f\U^O OfVMlfOIV)
late kliC 3 , WR-*-!
iample Local
Sample Type
lun Number
Ion "'€ iN t f-T — (t
fvJTJ-a''
fl ~/KM.?T X/H/*
Operator Kfr£KO<; ' "
Implnger Volumes
Initial Flna
iftf. ]aa
mn jef
Q. _A
Probe Length and Type
[ Met Cain
•
tablent Temperature %f
Barometric Pressure ^^-gD
Static Pressure. (H?0l
^ Silica
Gel
Noizle Size I I.D.
Pltot Coefficient 1
Assuwd Moisture
1.0.
Molecular Height, Dry, |H
Heter Box Number '£&$&
i)
•*- rf*£s/tl, /)£*
Heter Coefficient
a Factor
K •
Filter Number! s) fj.^l.^ kSV,O MNd»< • »« )< •
Leak Check:
Pltot Leak
Traverse
Point
Number
•^
Initial at lO * Ha. .C&ICFM SASS Condensate '
Final at tT^1 Hg. .flcTj CFN
Check: Total Volume
N. Clock Time
NV" (24-hr)
N< Clock
Sampling >v
Time, mln \
^-4^
^"^-— ^
^lo" — ---^
1?^~*-— - ~_
3(5 — -~-^__
J% — --— ^
^o^-— ~~^
-^^_
~-^~-^^_
^-— ^_
Gas Heter
Heading
(«.>. ft'
wtsr».5w
•^ji j^
•D,^ .sn
5l')3V.
6/% .y&c
•&D.352
5d2.0fd\
A/'/9S
Velocity
Head
(APt).
U. RjO
•
Orifice (
01 f fen
(«H). U
Desired
.15"
,75
^7/r
XI •*
i7^
;7^
ressure
ntlal
. H20
Actual
n*>
sri
tf$
,14
tf
rt
(?^><
H • (t(Ndl4 (ff)
P)
Temperature *F
Stack
Probe
Imptnger
Organic
Module
Oven
Cas
Heter
In
ft
17
%
Oj(e
Cf?
?
Out
9?
95
ft
%'
9r^
7
Pump
Vacuum
ft. H)
^
^
5
^
JO
•IQ
fSf
CoaBcnts:
^01595
-------
Plant 5CC,
Data (\J
&L\=>0
Sanpla Location
Saipla Typa
Run Munbar
Operator
Atblant Teaperetura,
laroMtrlc Prauurt,
Static Prauurt, (H{0)
FUtar NMfcarls)
Laak Ckacki Initial at
Final at
Pttot Laak Chaek:
=U
-US' H
• nj« (rl
O*
CFH
FIELD DATA
iKtlnacr Voluaet
initial Final
ifl
Silica Gal
SASS Condmtito
Tout VoliM
Page 1 of [
Probe length and Typa
NQizta SlM I 1.0.
Pi tot Coefficient I 1.0.
AtiuMd Itolstura
Holeciilar Uatgnt. Dry. (Hd>
Hatar Box Nwfear D^U
Meter Coefficient
a Factor ___________
K •
KIN.)4
R I
CO
ro
oo
Velocity
Haad
OrtfUi Prasturo
Oirr«rontfi1
|JM), In. «20
toll red
Actual
Suck
Probi
Orgtutc
NoduU
Ovcn
fits
Mettr
In
Out
J?i
VKUH
U. Ht
nr
II
I
II
CoMentt:
901594
FamMI 3/M
-------
Plant
Data
SCfer
Location frJTLZf -/.
Sample Type WK
Run Number _ A- DUTLtT
Operator R,
tabtant Temperature $
BiroMtrtc Prtnurt
SUtle Pressure. (HjO)
Filter MuaberU)
Leak Check! Initial at & ' Hg. £\CFH
Final at \£~* Hg. jfi^CFM
PItot Leak Check:
FIELD DATA
luptnger Voluaei
Initial Final
no
icrp tO?
Silica Gel
5.^f
SASS Condentate
Total VoluM
Page / of /
Probe Length and Type
Howie Size I 1.0.
Pltot Coefficient I I.D.
Asswed Moisture
Molecular Height. Dry. (Mjl
Meter Box Muter
Meter Coefficient
a Factor
K •
K(Ndl« • _
AH • K(Md)*
x (
(W
(PI
CO
I
ro
ID
Traverse
Point
NiMber
7
Gas Meter
Reading
(V.). ft>
Velocity
Head
(AM.
In. fl^O
Orifice Pressure
Differential
(AH). In. HjO
Desired Actual
»
Temperature *F
Stack
Probe
laiplnger
Organic
Module
Oven
Gas
Meter
In
?
Out
Pu-p
Vicuua
1*. Hg
10
/o
/o
11
JL
ConenU:
FonB46l
-------
3.5 OPERATING DATA TABLE FOR VOST
3-30
-------
CO
I
CO
VoUtlll Orgtnlc Staling Supllng Inln (VOSI) Diti Slwit
Hut £C6l -fan* GJ/»V"»«-
.... f- > -rf
Swplt Locittm
Run Ma.
^>>«/ >f-6. aun.tr -srHie.
/
Ati 5 Amftts "TWJZ** Jvir
Int
Sit
A
1
C
0
E
r
Saury
Trip
14).
^
/(>/)
7
f0/4
f
^
X
Clock TIM
24 Hour
"""/Mr
"•"AJ/*
St«rt:
X
K"!x
"mVJ¥/
s""//^/
Slirti
stopt
inrti
ittf:
itirt:
Jiop:
X
tur.jy/
x-
// 7/r
TMp*r?
ft/74
^^
fO/lG
;»//*•
UtOWtM-
Stttlng
-&•
4JL
^
^
40
V3
»«»
VMim
(In. Ht)
SL.
*-
^
/^
/->-
&
m./n fHutfl/tj
Frtttun (In. H
nvtrttor* Cf)
,) .~J*J'
/0O
le«k »•)•
LTN it Viciu
«..Jc/»^i(W
/f " H V
^- ' „
s
O.e>2Sl/>sl
@ /7 *Ak
X
CUMHtl
^U./Wft •«-
AII r i. r
^a/tf B/rf«»<.
Art ii-vo
iu. noU b
^xC
Noli., «j e^ Al e«mU«.»<.. *V k.«». ^'- j .»' 0^ chU*-rM «..h^< o. t^den^t, rTa_.
y «u^-0. -U*»,L OUAC..4 ^j 4,^ ^ ^y.^v.t^ ^.ay/, f
90162G 901628 901630 901632
901627
901629
901631
-------
SECTION 4
ANALYTICAL LABORATORY RESULTS
4.1 TOTAL CHROMATOGRAPHABLE ORGANICS (TCO), GRAVIMETRIC ORGANICS (GRAY),
GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS), AND INFRARED (IR) SPECTRA
OF TOTAL SASS SAMPLE EXTRACTS
4.2 GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS) OF VOST TRAPS
4.3 AMMONIA, CYANIDE, AND N20 ANALYSES
4-1
-------
4.1 TOTAL CHROMATOGRAPHABLE OR6ANICS (TCO), GRAVIMETRIC ORGANICS (GRAV), GAS
CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS), AND INFRARED (IR) SPECTRA OF
TOTAL SASS SAMPLE EXTRACTS
4-2
-------
ACUREX
Corporation
Energy & Environmental Division
Acurex/CEU October 9, 1984
MS 2-2260 Acurex IDI: 8408-032
Client POI: 307736.92
Page 1 of 4
Attention: Larry Waterland
Sample: Aliso Canyon, 1 SASS Train;
Received 8/17/84
The above samples were analyzed by Level 1 protocol. The XAD and OHC extracts
were combined per your instruction. Organic extracts were also analyzed for
the semivolatile priority pollutants by gas chromatography/mass spectrometry
employing a J&W SE-54 30 meter capillary column. The column was held at 30"C
for 2 minutes, then ramped at 10*C per minute to 270*C. In addition to the
priority pollutants, benzo(c)phenanthrene, dibenzo(c,g)carbazole,
7,12-dimethylbenzo(a)anthracene, 3-methylcholanthrene, and perylene were sought
employing the computerized library search and manual interpretation. The
assignment and quantitation of these organics is tentative since analytical
standards of these compounds were not available for analysis.
Benzo(c)phenanthrene, dibenzo(c,g)carbazole, 7-12-dimethy1benzo(a)anthracene,
3-methylcholanthrene and perylene were not detected in any of the samples at
levels above 100 vg per train.
After extraction of the XAD field blank, the same resin was spiked with
400 vg each of dodecane, naphthalene, phenanthrene, and pyrene, 10 mg of
bis(2-ethylhexyl)phthalate and 40 mg of hexadecane. The samples were then
analyzed for TCO, GRAV, and PAH. Results are presented in Tables 1 through 3.
Chromatograms and spectra are attached.
Submitted by:
1 Viorica Lopez-Avila, Ph.D.
Inorganic Chemistry Technical Director
GN/VLA/atS
Attachments
555 ClytMAvomit.P.a Box 7555. Mountain Vlmr.CA 94039 (415)964-3200 Telex: 34-6391 TWX: 910-7798593
4-3
-------
Acurex/CEU
8408-032
Page 2 of 4
Table 1. TCO and BRAV Results
Sample
XAD-Inlet
XAD-Outlet
XAD-Blank
Separatory Extraction Blank
XAO-Spike level
XAD-Sp1ke recovery
TCO
44 rag/train
21. 24* nig/train
<0.1 rag/train
0.3 rag/train
41 ing
71X
GRAV
83 ing/train
16 mg/train
<2 mg/tra1n
<2 mg/tra1n
51 rag
76X
Duplicate Injection
4-4
-------
Acurex/CEU
8408-032
Page 3 of 4
Table 2. EC/MS Results, vg/train
Analyte XAD-Inlet XAD-Outlet* Spiked XAD. Recovery
Naphthalene 220 10. 10 782
2-N1trophenol 140 <10, <10
Oi-n-butyl phthalate 80 160. 120
B1s(2-ethylhexyl)phthalate 50 30. 20 70Z
Phenanthrene 10 <10, <10 85X
Pyrene <10 <10. <10 62X
Other Priority Pollutant BNAs <10 <10, <10
* Duplicate Injection
4-5
-------
Table 3. Sample Disposition
Acurex/CEU
8408-032
Page 4 of 4
Sample ID
901643
901640
901648
901645
901646
Type
XAD-Inlet
OHC-Inlet
XAD-Outlet
OMC-Outlet
XAD Blank
XAD Spike
C»f Riant
Initial S
130 g
1.822 ml
130 g
2.000 ml
130 g
125 g
i i
;ubconti
5 9
—
5g
—
sg
—
Remainder
125 g 87t*
to XAD 2.040 mi. Inorganic
125 g 87X*
to XAD 2.250 ml inorganic
125 g 87Z*
125 g 9OT*
1 L 90S*
* As extract
4-6
-------
KAMPU:
8408-032-1 XAD-Inlet
WMlbMtar
- to'1!
3350
2955
2920
2850
157.;
1460
1340
. 1260
1055
950
880
770
700
635
(ramify
W
s
s
s
s
s
W
M
M
U
M
W
U
U
AoipuiMNt ComflMfta
OH Hydrogen bonding Broad
CH Aliphatic
CH Aliphatic
CH Aliphatic
Not Assigned
CH Tentative Assignment
CH Tentative
CO Tentative
CO Tentative
CH
CH
CH
CH
CH
Aliohatic
4-7
-------
SAMPLE:
8408-032-3 XAO-Outlet
!*hST"
2955
2920
2850
1710
1450
1410
1255
. 800
Immiiy
S
S
S
S
H
W
S
M
•
taipuMMt CmiuJiMiti
CH Aliphatic
CH Aliphatic-
CH Aliphatic
C«0
CH Tentative Assiqnment
CH Tentative
CO Tentative
CH
Aliphatic
4-8
-------
SAMPLE: 8408-032-5 XAD Blank
Intimity
No Peaks
Comnuna
4-9
-------
KAMfLI: 8408-032-7 Seoaratorv Funnel Extraction Blank
XV
1?fiO
inqn
1075
800
bnmiiy
S
M
M
S
**— .— -
CO Tentative Assignment
Not Assigned
Not Assigned
CH
4-10
-------
4.2 GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS) OF VOST TRAPS
4-11
-------
ACUREX
Corporation
Acurex/ES
Attention: Larry Waterland
Energy & Environmental Division
October 1. 1984
Acurex IDI: 8408-008
Client POI: 307736.92
Page 1 of 2
Subject: EC/MS Analysis of Three Pairs of Tenax/Tenax Charcoal Traps;
- Received 8/6/84
The above referenced traps were analyzed for volatile priority pollutants
according to the EPA VOST Protocol. Field blank traps were received with
broken nut connectors. Results of our analysis are listed in Table 1.
If you have any questions, please call.
Prepared
usan H. Kraska
Staff Chemist
Approved by:
Richard Scott
Manager, GCMS Operations
SHK/VLA/ats
555 dyd.Awnue.P.0. Box 7555. Mountrin VMw CA B4039 (415)964-3200 IWn: 344391 1WX: 910-7796693
4-12
-------
Acurex/ES
8408-008
Page 2 of 2
Table 1. Volatile Organics Results
Sample IDI
Priority Pollutants
Benzene
Chlorobenzene
l,2-01chloroethane
1,1,1-Trlchloroethane
1,1,2,2-Tetrachloroethane
Chloroethane
Chloroform
1,1-Dichloroethene
Trans-l,2-Dichloroethene
Ethylbenzene
Methylene chloride
Chloromethane
Bromomethane
Tetrachloroethene
Toluene
Trlchloroethene
Vinyl chloride
All Other Priority Pollutants
Nonprlority Pollutants
Acetone
Total Xylenes
901626 901628 901630
901627 901629 901631
Concentration (nq/trap)
NO
1,700
ND
NO
60
56
11
31
7
700
1.200
155
6
NO
6,000
NO
11
ND
720
ND
ND
ND
ND
45
ND
ND
ND
ND
ND
ND
1,205
111
5
ND
NO
ND
ND
ND
5
ND
32.000
720
5
101
11
16
10
26
ND
127
1,700
130
5
85
3,700
3
5
ND
ND
3,000
Blank
Trap
13
5
ND
ND
9
ND
NO
ND
ND
5
38
58
2
ND
31
ND
ND
ND
ND
10
Detection Limit
Surrogate Recoveries
Toluene-ds
61
Percent (*)
97
74
114
ND - Not Detected
Note: Field Blank Traps were received broken at nut connections.
4-13
-------
4.3 AMMONIA, CYANIDE, AND N20 ANALYSES
4-14
-------
/N ACUREX
'^ ^ Corporation
Acurex/ES (CHEA)
Attention: Larrry Water!and
Energy & Environmental Division
August 23, 1984
Acurex ID*: 8408-022
Client POI: 307736.92
Page 1 of 1
Subject: Chemical Analysis of 6 Hydrochloric Acid Impinger Solutions
and 6 Sodium Hydroxide Impinger Solution, Received 8/9/84
The six sodium hydroxide impinger solutions were analyzed for cyanide content
using EPA Method 335.2. Ammonia content for the hydrochloric acid impinger
solutions was determined by ion selective electrode with EPA Method 350.3.
Results are presented below.
Sample
901593
901594
901595
901596
901705
901633
Inlet
Outlet
Inlet
Outlet
Outlet
Blank
Run 1
Run 1
Run 2
Run 2
Run 3
Ammonia Content. mg/L
1,800
150
2.400
78
380
Sample
901590
901598
901592
901597
901706
901634
Inlet
Outlet
Inlet
Outlet
Outlet
Blank
Run 1
Run 1
Run 2
Run 2
Run 3
Cyanide Content, mg/1
0.016
4.0
0.008
4.1
0.36
<0.005
Prepared by
JSL/GN/ats
Approved by:.
Greg Ni
Inorganic Chemistry
555 Oydt Avenue. P.O. Box 7555. Mountain Vie* CA 94039 (41S) 964-3200 Telex 3*-6391 TWX: 910-7796593
4-15
-------
A
ACUREX
Corporation
Energy & Environmental Division
Acurex/ES September 27. 1984
Acurex ID*: 8408-039
Cl<->nt POI: 307736.92
Page 1 of 1
Attention: Larry Waterland
Subject: Analysis of 6 Gas Bombs for Nitrous Oxide by 6C/ECD
The above referenced samples were analyzed by GC/ECO according to the
previously reported method.
Results are listed in the table below:
Sample ID ^0 (ppm)
901104 56
901105 52
901106 20
901107 65
901108 10
901109 220
If you have any questions, please call.
Prepared by: ^xA^Uc *• Approved by:
ticharcKWood Viorica Lopez-AviTSr Ph.D
Staff-Theorist Technical Director
RW/VLA/ats
555ayO»Av<«x». PQ Box 7S55. Mountlln VHw, CA 04039 (415)984^200 TWwc 34-4381 TWX: 910-7796583
4-16
-------
TECHNICAL REPORT DATA
(Meat ntd Iiuauction on tfit rtvene be fan comptetbtgf
1.H6PORTNO. '
EPA-600/7-86-Ol4b
2.
3. RECIPIENT'S ACCESSIOWNO.
AND SUBTITLE
Environmental Assessment of a Reciprocating Engine
Retrofitted with Selective Catalytic Reduction;
Volume n. Data Supplement
7. AUTHQR(S)
8. HI PORT DATE
April 1986
B. PERFORMING ORGANIZATION COOC
C. Castaldini and L. R. Water-land
ft. PERFORMING ORGANIZATION REPORT NO.
». PERFORMING ORGANIZATION NAME AND ADDRESS
A cur ex Corporation
Energy and Environmental Division
P.O. Box 7555
Mountain View, California 94039
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3188
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air and Energy Engineering Research Laboratory
Research Triangle Park, NC 27711
13. TYPE Of REPORT AND PERIOD COVERED
Final; 3-12/84
14. SPONSORING AGENCY CODE
EPA/600/13
is. SUPPLEMENTARY NOTES AEERL project officer is Joseph A. McSorley, Mail Drop 65.
919/541-2920. Volume I gives the technical results.
10. ABSTRACT
The report gives results of comprehensive emission measurements and
15-day continuous emission monitoring for a 1,500 kW (2000 hp) gas-fired, four-
stroke turbocharged reciprocating engine equipped with an ammonia-based selective
catalytic reduction system for NOx control. Emission reductions were held at
about 80% using an ammonia/NO ratio of about 1.0. NOx levels at the catalyst inlet
ranged from 2,200 to 2.600 ppm at an exhaust gas oxygen level of about 11%. NOx
levels at the catalyst outlet ranged from 65 to 120 ppm. The catalyst had relatively
minor effect on CO and participate emissions, but increased total cyanides by 3
orders of magnitude (from 7 micrograms/dscm to 2.4 mg/dscm) across the cata-
lyst. Total organics decreased about 70%, from 4.9 to 1.5 mg/dscm. Analyses
showed benzene and toluene as the major organic constituents in the catalyst exhaust.
Polycyclic aromatics also decreased across the catalyst. The 15-day continuous
monitoring tests showed that the catalyst was generally able to maintain NOx reduc-
tions at about 80%. Departures from these levels occurred only during brief load
surges and ammonia flowrate spikes.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lOENTIFIERS/OPEN ENDED TERMS
c. COSATi Fidd/Cnup
Pollution
Assessments
Reciprocating Engines
Gas Engines
Catalysis
Reduction (Chemistry)
Ammonia
Nitrogen Oxides
Pollution Control
Stationary Sources
Environmental Assess-
ment
Selective Catalytic Re-
duction
13B
14B
21G
07D
07B.07C
19. SECURITY CLASS /TMf £«porfT
Unclassified
21. NO. OF PAGES
18. DISTRIBUTION STATEMENT
Release to Public
2O. SECURITY CLASS fTTUi
Unclassified
22. PRICE
•PA
4-17
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