February 1979                                            EPA-600/8-79-005
      GUIDELINES FOR ADJUSTMENT OF ATMOSPHERIC GAS BURNERS
           FOR RESIDENTIAL AND COMMERCIAL SPACE HEATING
                            AND WATER  HEATING
                 Adjustment Procedures to Minimize Air Pollution
                       and to Achieve Efficient Use of Gas
                      Service guide for skilled service
                      technicians in adjustment of gas
                      burners.
                      Training guide for advanced
                      burner service courses.
                      Supplement to manufacturers'
                      service instructions.

                      Incorporates suggestions of reviewers
                      from industry, including:
                          Gas Appliance Manufacturers Association
                          American Gas Association
                          Independent Service Organizations
                          Air Pollution Control Association
                                  SEPA
                   U.S. ENVIRONMENTAL PROTECTION AGENCY
                         Office of Research and Development
                     Industrial Environmental Research Laboratory
                         Research Triangle Park, N. C. 27711

-------
               RESEARCH REPORTING SERIES

 Research reports of the Office of Research and Development, U.S. Environmental
 Protection Agency, have been grouped into nine series. These nine broad cate-
 gories were established to facilitate further development and application of en-
 vironmental technology. Elimination  of traditional grouping was consciously
 planned to foster technology transfer and a maximum interface in related fields.
 The nine series are:
      1.  Environmental Health Effects Research
      2.  Environmental Protection Technology
      3.  Ecological Research
      4.  Environmental Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency Energy-Environment Research and Development
      8.  "Special" Reports- >
      9.  Miscellaneous Reports

 This report has been assigned to the SPECIAL REPORTS series. This
 series is reserved for reports which are intended to meet the
 technical information needs of specifically targeted user
 groups. Reports in this series include Problem Oriented
 Reports, Research Application Reports, and Executive
 Summary Documents.  Typical of these reports include  state-
 of-the-art analyses, technology assessments, reports on the
 results of major research and development efforts,  design
 manuals, and user manuals.
                   EPA REVIEW NOTICE

This report has been reviewed by  the U.S. Environmental
Protection Agency, and approved for publication.  Mention of
frade names or commercial products does not constitute
endorsement or recommendation for use.
 This document is available to the public through the National Technical Informa-
 tion Service, Springfield, Virginia 22161.

-------
                             TABLE OF CONTENTS

                                                                             Page

PURPOSE OF THESE GUIDELINES	      1

    Scope   	      1

RECOMMENDED ADJUSTMENT PROCEDURES FOR GAS BURNERS	      3

    Preparation Steps	      3

    Combustion Adjustment Steps	      7

    Combustion Diagnosis Steps	     11

    Final Checks	     13

APPENDIX:  BACKGROUND INFORMATION

    A.  Pollutants of Main Concern	     18

    B.  Field-Type Instruments and Significance of Measurements	     21

    C.  Typical Emission Characteristics of Residential Gas Burners	     25

    D.  References & Bibliography	     28
                               ACKNOWLEDGMENTS
               These Guidelines were prepared by D. W. DeWerth and R. L. Himmel
         of the American Gas Association Laboratories and D. W.  Locklin of Battelle-
         Columbus under contract from the U.S. Environmental Protection Agency
         (Contract 68-02-2653).  R.  E. Hall was Project Officer for the EPA.  Sugges-
         tions from many industry reviewers have been included — representing the
         gas industry, the appliance manufacturing industry, and the appliance servicing
         industry. These significant contributions are acknowledged.

-------
The contents of this manual are offered as guidance.  The United States
Government, its employees, and its research contractors, Battelle-Columbus
and A.G.A.  Laboratories, do not assume responsibility or liability for con-
sequences arising from the implementation or failure to implement the
guidance contained  herein.

-------
        GUIDELINES  FOR ADJUSTMENT OF ATMOSPHERIC GAS BURNERS
              FOR RESIDENTIAL AND COMMERCIAL SPACE  HEATING
                                AND WATER HEATING
                            PURPOSE OF THESE GUIDELINES


       The most important reason for adjusting a gas burner is to provide safe reliable opera-
tion.  A second important reason is to provide for efficient fuel utilization, which helps to
minimize operating costs.  Effective means of meeting these goals include: (1) keeping the
burner and pilot orifices, and the burner ports, free of dirt and lint; (2) properly adjusting the
burner aeration; and  (3) maintaining an acceptable CO level.

       Recently, minimizing air  pollution has become an additional  important reason for
proper adjustments.  Of course, burner adjustments for this purpose must also meet the
former objectives.  Fortunately, adjusting for low air-pollutant emissions is consistent with
adjusting for reliable performance and efficient operation.

       These Guidelines have been prepared for use by service managers in training of tech-
nicians and by skilled technicians in their gas-burner service work.*  By following the step-by-
step procedures outlined in these Guidelines, the skilled gas-burner service technician will  be able
to adjust residential and commercial heating equipment and water heaters to minimize air pollu-
tion, attain optimum efficiency,  and provide safe reliable operation.

Scope

       These procedures are intended for adjustment of atmospheric-type gas burners for
residential and commercial space heating and water heating systems. The procedures are sup-
plemental to manufacturers' installation instructions, the National  Fuel Gas Code2, and other
installation codes or handbooks3-4-5.** They apply to burners fired  with either natural gas or
liquefied petroleum (LP) gases.***                  	
  'Similar Guidelines for oil-fired space-heating equipment are cited in Reference 1.
 "Attention is called to the series of American Gas Association publications on fundamentals of appliance servicing, listed in
   the Bibliography.
 "Information in these Guidelines pertaining specifically to LP gases is in italics.

-------
       The adjustment procedures apply to atmospheric-type gas burners of the single-port and
multiported types such as ribbon, slotted-port, and drilled-port burners (see Figure 1) as used in
in manufacturer-designed burner/furnace units, burner/boiler units, or complete water heaters.
Although the principles apply to conversion-type gas burners, these burners require special ad-
justment procedures.   For conversion burners, the burner manufacturer's instructions should be
followed.6

       Retrofit modifications, such as those under study in the gas industry's Space  Heating
Efficiency  Improvement Program (SHEIP)  for improving seasonal efficiency, are not included
in these Guidelines.  Inquiries can be directed to the American Gas Association, 1515 Wilson
Boulevard,  Arlington, Virginia  22209.
                                          1. Single Port
                                           2. Ribbon
                                          3. Slotted Port
                                           4. Drilled Port
 Figure 1.  Types of gas burners frequently used in space-heating and water-heating appliances.

-------
           RECOMMENDED ADJUSTMENT PROCEDURES FOR GAS BURNERS
       The following steps are emphasized from the viewpoint of minimizing air-pollutant emis-
sions and maintaining peak efficiency and safe reliable operation.  Fourteen steps are described;
they cover preparation steps, combustion adjustment steps, diagnosis, and final checks.
PREPARATION STEPS

    1.  Clean Burner      The most common malfunction attributed to main burners and
       and Pilot          pilots is caused by excess dirt, lint, or other debris.  Blockage
                         of primary air openings can cause the burner to operate with in-
       complete combustion and can lead to soot and excess CO formation.  Orifice block-
       age also can cause burner ignition problems.  See Figure 2 for sketch and description
       of primary  and secondary air.

       WARNING: Shut off all gas to appliance. Valve should be "tagged" to prevent its
       being inadvertently opened while system is being worked on.  Remove  burners and
       clean the burner ports, burner and pilot orifices, and primary air openings.  Ports
       can be cleaned by passing a wooden dowel through the ports or by running water
       into the ports.  If grease is present, wash with detergent.  Make sure the burners are
       thoroughly dry before reinstalling.  Shake out debris through burner mixing tube.
       Replace burners. Be sure that they are properly installed and that the  orifice is
       centered within the mixing tube.

       Before reinstalling burner, visually inspect combustion chambers, furnace heat ex-
       changers, and appliance flue ways to determine if there are any leaks.  For conversion-
       burner installations, leaks between sections of many cast-iron furnaces can be re-
       paired with furnace cement.  If  there are cracks or holes in steel heat exchangers,
       the heat exchanger must be replaced.

       Make preliminary adjustment of the primary air shutters, if any, by following
       Step 6. Turn on the gas and relight the appliance, following lighting instructions
       on the appliance.

-------
                                           MIXING TUBE
                                              PRIMARY AIR — aspirotes  into burner
                                                             air openings  and mixes
                                                             with  gas
                                                           FUEL  GAS
                                    T  ^SECONDARY
                                    J        AIR — enters thru combustion
                                                    chamber openings provided
                                                    and  surrounds flame
                          Figure 2. Definitions for burner air/fuel mixing.
   2.  Adjust Manifold    Adjust pressure regulators to deliver gas to burners at the proper
      Pressure            pressure.*  If the appliance rating plate specifies a manifold
                          pressure, adjust to that pressure.   If not specified, set pressure for
      natural gas appliances with regulators at 3.5 inches water column.**

      For LP gases, set at 11 inches water column.  Regulator may be at tanks.  (In some
      cases,  it may not be possible to adjust the pressure.)
   3.  Adjust Pilot        The pilot flame should be soft blue in color.  A propane pilot
                          flame may  have a slightly yellow tip.  The flame should sur-
       round the tip of the thermocouple or flame sensor.  If there is a separate ignition
       port, the flame should  reach the  main burners.  There may be an adjusting screw for
       pilot gas on the main gas valve or pilot shut-off valve.
•Measured at manifold pressure tap, with main burners operating.
•Although it is EPA policy to use metric units in its publications, nonmetric units are used here to reflect standard field
 practice.

-------
4. Adjust Main       a. Using a gas meter.  After the unit has been operating at
   Burner Input       least 10 minutes, check the gas  input rate by timing one
                      revolution of the gas meter test dial, making sure that no
   other gas burning appliance is operating.  Note the number of seconds for one
   full revolution, and calculate input as follows:


             ,nput. etu/hr = cu ft  per rev°lution x 3600 sec/hr x HV
                             sec per revolution

             where HV = gross heating value of gas, Btu/cu ft.

   Obtain the heating value from the local gas company or the LP gas supplier.

                      b. Not using  a gas meter.  Measure the orifice size using a
   drill index and determine the input using Table 1 for utility gas  or Table 2 for LP
   gases.

   If necessary, adjust the gas input to within  ±5 percent  of the value noted on the
   manufacturer's rating plate, as follows.  To adjust the input rate of an appliance
   with an adjustable pressure regulator, first remove the cap covering the pressure
   regulator adjustment.  Turn the adjustment clockwise to increase manifold pressure
   and input rate.  Caution:  Do not change manifold  pressure more than ±0.3 inch
   water column. To make larger  input changes, resize the orifice.

   If the appliance is not equipped with an adjustable  pressure regulator, replace orifice
   with resized orifice using Table  1  for utility gas  or Table 2 for LP gases.
    Check              Allow the burner to cool and check operation of ignition
    Ignition            system by cycling several times while the burner is cold to
                       ensure prompt ignition on cold start.  Then operate the
    burner at least 10 minutes (or until thoroughly hot) and repeat several ignition
    cycle checks to ensure prompt ignition on hot start.  (Wait approximately
    5 seconds between cycles.)

-------
                                               TABLE 1.  ORIFICE SIZING FOR DIFFERENT GAS PRESSURES - NATURAL GAS2

                                                        Values in table represent flow of gas. cubic feet per hour at sea level.

                                                    Specific Gravity =  0.60
                                                    Orifice Coefficient = 0.90
                                                    For utility gases of another specific gravity, select multiplier from Table 2-a.
0)
Oifffc*
or Drill
Stm
80
79
78
77
76
75
74
73
72
71
70
69
68
67
66
65
64
63
62
61
60
59
58
57
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
•^AABM^Bt 
-------
COMBUSTION ADJUSTMENT STEPS
    6.  Adjust Burner      To adjust primary air, allow at least 10 minutes for the burners
                          to heat up; close primary air shutter until yellow flame tips
       appear, then open air shutter until all yellow completely disappears.  The flame should
       be clear blue.

       LP gas burner flames and large single-port natural-gas burner flames may have slightly
       yellow tips; these are satisfactory  if  no soot forms and there is no flame impinging
       on the heat exchanger. Single-port  burner flames may have an orange quality; these
       are satisfactory. Any  burner flame  may have an orange quality,  caused by dust;
       these, too, are satisfactory.

       The primary air setting for  matched units  has a relatively narrow range of adjustment.
       (Some burners, particularly on water heaters, do not have air shutters.)

       Too much primary air causes noisy  hard flames which could result in  flame lifting,
       flashback, and emission of unburned hydrocarbons.   Too  little primary air
       causes yellow flames which could produce high CO and soot emissions.  Fig-
       ure 3 illustrates the desired adjustment region for a  typical gas burner, consider-
       ing variables of input rate  and primary air.

       Secondary air is controlled  by the burner and appliance design; they should not
       need modification.  Conversion burners, however, may need secondary air adjust-
       ment; the manufacturer's instructions should be followed.6
    7. Sampling           Flue gas samples for analysis* should be taken from inside
                           the appliance approximately 1  inch ahead of the draft hood
       inlet.  (See Figure 4.) If several flue outlets are provided, individual samples
       should be taken from each, or a partial sample should  be taken from each outlet
       to make up the full sample.  For example,  if there are four outlets, 25  percent
       of the sample should be taken by inserting  and traversing the probe in each
       outlet.
"CO2 is usually measured with a wet-chemical analyzer. CO is usually identified by using a color-sensitive chemical-indicator tube.
 (See Appendix. Section B, for instruments and their use.)

-------
       TABLE 2.  ORIFICE SIZING FOR DIFFERENT GAS PRESSURES - LP GASES2
             Values in table represent flow of gas. cubic feet per hour at sea level.
                                                                                                         TABLE 2. (Continued)
00

Ssw per Cubic Foot'
Soecific Gravity
tenure at Orifice, Inchei Water
O-fice Coefficient



Column

Propane Butane
2,500 3,175
1.53 2.00
11 11
0.9 0.9
For altitudes above 2,000 feet, firit telect the
equivalent orifice lize at tea

Orifice or
Drill the
.008
.009
.010
.011
.012
80
79
78
77
76
75
74
73
72
71
70
69
68
67
66
65
64
63
62
il
60
55
SB
£7
56
55
54
53
52
51
50
£9
*B
A7
*4
A;
level from Table 1-C4.


Propane
500
641
791
951
1.130
1,430
1,655
2.015
2.545
3.140
3.465
3.985
4,525
4.920
5,320
6.180
6,710
7.560
8,040
8.550
9^30
10.200
10.800
11,360
11.930
12.570
13.220
13.840
14.550
16,990
21,200
23.850
27.790
31.730
35430
38.500
41.850
45,450
48.400
51.500
52,900

Butane or
Butane Propane
Mixture*
554
709
875
1.053
1.250
1,590
1,830
2,230
2,815
3/480
3340
4/410
5.010
5/450
5,900
6,830
7,430
8,370
8,910
9,470
10,670
11,300
11,900
12,530
13,280
13,840
14.630
15.300
16,090
18.790
23.510
26.300
30430
35,100
39,400
42,800
45,350
50.300
53.550
57,000
58,500
Orifice or
Drill Siie
44
43
42
41
40
39
38
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
19
18
Prepane
58,050
62,200
68,700
72,450
75,400
77,850
81.000
85.000
89.200
95.000
97.000
101,000
105.800
113,200
129.700
145,700
154.700
163.100
169.900
175,500
181,700
186.800
193,500
198,600
203,700
217,100
225.600
Butane or
Butane-Propane
Mixture!
64,350
69,000
76,200
80,200
83.500
66.200
89.550
94.000
98.800
105.300
107,200
111,900
117,000
125/400
143,600
163/400
171,600
180,000
187,900
194,600
201,600
206,400
214,500
220,200
225,000
241.900
249,800
                                                                                           TABLE 2-a.  MULTIPLIERS FOR UTILITY GASES OF
                                                                                                      ANOTHER SPECIFIC GRAVITY
Specific Gravity
0.45
0.50
0.55
0.60
0.65
0.70
0.75
0.80
0.85
0.90
Multiplier Specific Gravity
1.155 0.95
1.095 1.00
1.045 1.05
1.000
0.961
0.926
0.894
0.866
0.840
.10
.15
.20
.25
.30
.35
0.817 1.40
Multiplier
0.795
0.775
0.756
0.739
0.722
0.707
0.693
0.679
0.667
0.655

-------
          4J
          
-------
    LOCATION FOR
    FLUE SAMPLING

   1/4" Die.
    Hole
                                                 Vent
                                                ^or
                                                 Chimney
     ==> . _ Draft
             Hood
n-1
Typical Boiler
  Gas	
  Burner
                            Relief Opening for
                           "Dilution Air
-j mtrm
-^=c	1
               a. Vertical flue outlet
   Typical
   Furnace"
    urner
                      LOCATION FOR
                      FLUE SAMPLING
                       Draft
                              I	Dilutii
                     Dilution
                     Air
                                          Vent
                                          • or
                                          Chimney
              b.  Horizontal flue outlet
 Figure 4. Location for sampling flue outlet of gas-fired appliances.
                       10

-------
       Typical CO values for properly adjusted appliances, operating at rated  input, range
       from 25 to 100 ppm (0.0025 to 0.010 percent); however, values as high as
       300 ppm may be encountered in the flue-gas sample, since this is equivalent to
       the maximum value of 400 ppm (air-free) at a C02 level of  8.5 percent, allowed
       by the ANSI standards2.  See Step 10 for proper adjustment methods.
COMBUSTION DIAGNOSIS STEPS
   10.  Check             A well-adjusted gas burner should be capable of operating
       Performance       with a CO level not greater than 100 ppm in the flue gases
                         with a CO2  level between 6.0 and 8.5 percent for natural
       gas and 7.0 to 10.0 percent for LP gases.  If these values cannot be  reached,
       check the following:

            a. Too low a CO2 level could mean circulating air leakage into the com-
              bustion air due to a faulty seal around the secondary air opening of
              the unit.  Seal such leaks by tightening the screws or bolts or replac-
              ing the sealing gasket.

              Too low a C02 level could be caused by a defect in the furnace heat
              exchanger.  If the CO2  levels obtained with and without the blower
              operating differ by more than 0.4 percent, make a repeat check of the
              combustion chamber and heat exchanger; if a leaking heat exchanger
              is found,  repair or replace it.

            b. If the CO2 and/or CO levels are too  high, this could  mean an improper
              combustion air supply.  Spillage from the appliance draft hood can be
              detected by placing a lighted match at the edge of the hood relief open-
              ing.  If the match flame is not drawn into the hood,  spillage is occurring.
              A negative pressure in the appliance room also can indicate inadequate
              air supply.  Spillage can result from a blocked chimney or vent.

              If inadequate air supply is suspected, refer to Section 1.3.4 of the
              National  Fuel Gas Code ANSI Z223.1 or comparable provisions in
              local codes for specific detailed recommendations for providing air for
              combustion and ventilation.2  If this does not solve the problem, there
              may be internal blockage.
                                           11

-------
42
o

•o
o
o
o
o

I
0>
o
o

 CM
O
o
      60   40   20
0   20  40X60X80.
         y//////
          /  Proper
           Adjustment^
          /f  Region   /
o
o
20



 16



 12


 8



 4
           NATURAL GAS
                                           100
      60   40   20   0   20   40   60   80   100
         Deficiency of
         Air, percent
                     Excess Comb. Air, percent
                                                     Desirable air  adjustment

                                                     for  best  efficiency
                                                     approx. 10.0 percent C02
                                                  Limit of good  practice
                                                  approx. 7.0 percent C02
                               Desirable  air adjustment

                               for best  efficiency
                               approx. 8.5 percent CO2



                               Limit of good  practice

                               approx. 6.0 percent C02
        Figure 5.  Effect of fuel/air ratio on CO and CO2 concentration for

                  typical natural gas and LP gas burners, showing proper

                  adjustment region.
                                    12

-------
  11.  Efficiency         To determine the steady-state thermal efficiency of the
       Checks            furnace/burner or boiler/burner unit, follow this step.  Mea-
                         sure the flue gas temperature, after at least 10 minutes of
       operation, at the same point that the CO2 sample was taken.  Determine the net
       flue gas temperature by subtracting the room temperature from the flue gas tem-
       perature reading.  Using  this net temperature value and the percent C02 (see
       Step 8), determine the appliance flue loss from Figure 6 for natural gas or
       Figure  7 for LP gases.1  The appliance thermal efficiency is equal to 100 — flue
       loss. Use  the values  shown  in Table 3 to determine if the unit is operating at a
       satisfactory efficiency level.  (See Appendix B.)
FINAL CHECKS
  12.  Ignition           Check operation over several repeated cycles, at about
                         5 second intervals, to ensure prompt ignition.
   13.  Controls           Check settings of all operating and limit controls before
                         leaving installation.  For practical performance and good
       efficiency for modern forced-warm-air systems, usual practice is to set the fan
       control at 115-125°F ON and 90-100°F OFF. The water heater thermostat
       should be set to WARM or 120°F; where the water heater serves a dishwasher,
       settings up to 140°F may be needed.  Higher settings reduce efficiency and
       shorten life of the storage tank.
   14.  Regular           An annual burner checkup is recommended, with at least a
       Checkup          visual inspection by a trained service technician, plus cleaning
                         as necessary.  Furnace blowers and motors and boiler circu-
       lating pumps should be lubricated before  each heating season according to manu-
       facturers' instructions.  Furnace filters should be cleaned or replaced at least every
       60 days during the heating season.
                                            13

-------
                                 FOR  NATURAL GAS
        \5^r
Example:   8.2 percent
 22 percent flue loss '
(78 percent efficiency)
440 F net
 Figure 6.  Nomograph for determining flue loss and steady-state efficiency
           from CO2 and flue-gas temperature — firing natural gas7.
           Limited to use with natural gas as follows:
               Heating  value, gross:  970 — 1100 Btu/standard cubic foot
               Specific gravity:       0.57 - 0.70
               Ultimate CO2:        11.7 - 12.2 percent
                                 14

-------
                    TABLE 3. TYPICAL INSTALLED STEADY-STATE THERMAL
                             EFFICIENCIES OF CONVENTIONAL GAS-FIRED
                             DOMESTIC AND COMMERCIAL FURNACES,
                             BOILERS. OR WATER HEATERS
                                                   Thermal Efficiency*8*, percent
System
Forced Air Heating
Gravity Heating
Hot Water or Steam Boiler
Hot Water Heater
Excellent
75 or more
70 or more
75 or more
72 or more
Acceptable
72-75
67-70
72-75
68-72
              (a) Overall thermal efficiency = 100 — flue loss, percent, where flue loss is expressed as a
                 percent of the gas input (gross heating value) that is lost up the flue. This assumes that
                 any jacket loss is useful heat.
       Experienced service technicians will observe that these principles and/or procedures are
essentially the same as recognized good practice. Adjustment of gas burners by these procedures
will help to ensure safe and reliable operation, to minimize emissions, and to provide efficient
use of fuel.
                                             15

-------
                     FOR  PROPANE  HD-5  GASES
     CO
  u
  vi
  <
  o
     m
  o
                                                        o
                                                        o
Uj   UJ  O

z   o  «v»


Q.   UJ

°   °-  «

K     .  N

°-   OT
                       o
                       x
                           °  8
UJ

3
                              O
                              <0
                                                    •I
                                                    K
                                                    U
                                                    a.
                                                    O
                                                    O
                                                    tr
                              E
                              UJ
                              a.


                              UJ
                              K


                              0)


                              (9
                             O

                             O
                             CM
                             O
                             O
                             10
                                                        O
                                                        O
                             o
                             o
                             m
                                                        c
                                                        o
                                                        <0
                                                        o
                                                        o
                                                        8-il
                                                        CO

                                                        o
                                                        o
                                                        ffl
Figure 7.  Nomograph for determining flue loss and steady-state efficiency

          from CO2 and flue-gas temperature — firing LP gases7.


          Limited to use with LP propane gases as follows:

              Heating value, gross:  2466 — 2542 Btu/standard cubic foot

              Specific gravity:      1.522 — 1.574

              Ultimate CC^:       13.7 -  13.8  percent
                               16

-------
                      APPENDIX:  BACKGROUND INFORMATION
       Information on the air-pollutant effects of residential burner adjustments has been
developed in recent investigations8'14.  The findings of these investigations, combined with
good practice, are the basis for the Guidelines.

       This Appendix contains additional  background information:
           A.   Pollutants of Main Concern

           B.   Field-Type  Instruments and Significance of Measurements

           C.   Typical Emission Characteristics of Residential Gas Burners

           D.   References/Bibliography
                                          17

-------
                         A.  POLLUTANTS OF MAIN CONCERN
Pollutants and Their Measurement

       Air pollutants of main concern for the purposes of these Guidelines can be divided into
two broad classes, depending upon how much the service technician can control them by
adjustment:

       Class 1.  Pollutants that may result from incomplete combustion and are
                generally strongly affected by burner adjustment:

                     - Carbon monoxide, CO

                     - Hydrocarbons, HC

                     - Aldehydes

                     - Particulates (smoke or soot).

       Class 2.  Pollutants only  partially affected  or unaffected by burner adjustment
                (and not recommended as adjustment criteria):

                     — Nitrogen oxides: NO and N02 (usually considered together
                       and identified as NOX)

                     - Sulfur oxides:  S02  and 803 (usually considered together
                       and identified as SOX).

       The following comments describe each of the Class 1 pollutants from the viewpoints
of its definition, hazards associated with it, how it is detected or measured, and how its
emissions are affected by service adjustments. (The Class 2 pollutants are not discussed
further, because service adjustments  have little or no control over them.)
Carbon Monoxide, CO

       CO is a toxic gas formed by incomplete combustion. When gas burning equipment is
properly  adjusted, the CO emission level is extremely low.  When the low levels of CO emitted

                                          18

-------
by properly operating residential gas-heating equipment are diluted in the atmosphere, CO is
not considered dangerous and is depleted with time in the atmosphere by being oxidized to
C02-  With improper combustion, and if flue gases leak into living spaces, CO levels in living
spaces can be dangerous.

       For field adjustment of gas-fired equipment by methods suggested in these Guidelines,
CO should  be measured, using a color-sensitive tube or portable electrochemical device.
Yellow flames, smoke, and  "smelly" combustion  (as indicated by the presence of aldehydes),
indicate incomplete combustion. However, these are  not always reliable indicators:  if the
primary air adjustment is too far open, flame lifting could occur, and CO levels could increase
rapidly without smoke or odor.
Hydrocarbons, HC

       Emissions of hydrocarbons, which consist of unburned or partially burned fuel, occur
when combustion is incomplete.  Incomplete combustion can occur at very fuel-gas-rich
settings (because of a  lack of air) or at very fuel-gas-lean conditions (because of lifting
flames).

       Large amounts of unburned fuel  gas emitted from an improperly operating installation
can be detected by odor.  (An odorant is added to fuel gases for safety  purposes.) At lower
levels of HC emissions, too low to be detected by smell, the emissions generally follow trends
of CO emissions; hence, CO measurements are usually good indicators of hydrocarbon emis-
sions.  An exception  may occur at extremely  high primary air settings, where HC emissions
may be higher than normal, while CO  readings may be low.

       Although HC emissions are generally not toxic  to the same extent as CO,  they can
be accompanied by unpleasant odors and can  contribute to photochemical smog in the atmo-
sphere. Extremely low levels of  HC are  emitted when  gas-fired equipment is properly
adjusted.

       For routine adjustment of residential gas burners, it is not necessary to  measure HC
because stable burner  flames adjusted to acceptable CO levels will emit essentially no HC.
Aldehydes

       Aldehydes, especially formaldehyde, are formed when fuel gas combustion is in-
complete.  The aldehyde smell is responsible for the strong penetrating odor generally asso-
ciated with incomplete combustion.  During incomplete combustion, however, the level of
concentration of aldehydes is not as significant as the CO and HC which also are present.

                                           19

-------
Participate and Smoke

       Smoke consists mainly of tiny unburned particles of carbon and is an important in-
dicator of severe maladjustment of gas-burning equipment.  It can block flue passages and
foul  heat-transfer surfaces with soot.  Fuel utilization efficiency is very poor and an unsafe
condition may exist if smoke is present.

       If smoke is suspected, check for visible signs from the vent or chimney (or from the
draft hood of the appliance, using a flashlight). Low levels of smoke below the visible range
can be detected using a smoke tester commonly used in adjusting oil burners.15  Do not mis-
take condensed water vapor for smoke during cold weather.

       A smoky condition should be remedied immediately.  Shut down the unit and clean
the carbon formation completely from all surfaces including the heat exchanger, burners,
orifices, ignition system, and flue outlet.  Check the complete venting  system, and clean it
as necessary.  Then readjust the burner to correct the problem.
                                            20

-------
        B.  FIELD-TYPE  INSTRUMENTS AND SIGNIFICANCE OF MEASUREMENTS
       For the adjustment procedures outlined in these Guidelines, it is assumed that the gas
burner service technician is familiar with field-type instruments.  Typical instruments include:
           • Flue-gas analysis

                   - usually a simple wet-chemical absorbent-type CC>2 analyzer

                   - Orsat or similar device

           • Flue-gas analysis (CO)

                   - usually color-sensitive chemical in tubes or

                   — portable electrochemical device

           • Flue-gas temperature

                   - usually a continuous reading meter using thermocouples or
                     resistance thermometer sensor

                   - can be a  dial-type thermometer or a liquid thermometer,
                     although accuracy may deteriorate

           o Manifold pressure

                   - usually a water-type U-tube manometer.

Instruments, combining several of these functions in one device, are being introduced.*


The Significance of CC>2  Measurements

       CO 2 readings are  used to identify the  amount of combustion air being supplied to the
burner, compared to the  theoretical amount required for combustion.  It is seldom possible
*One valid approach is to base adjustments on 02 readings, in which the 02 reading is a more reliable indicator of the ad-
 justment relative to stoichiometric air than is a CO2 reading. 16
                                           21

-------
to burn a fuel completely and cleanly unless air in excess of the theoretical amount is pro-
vided.  The tabulation below illustrates the relationship between excess air supplied for com-
bustion and the CO2 concentration in the flue gas for  residential gas burners operating on
natural or  LP gases.
    Air/Fuel Mixture
        Settings

Theoretical or
 "Chemically Correct"
 resulting in  ultimate C02
Excess Air Supply
 (Percent Above
  Theoretical)
   Typical CC*2 in
  Flue Gas. percent
Nat. Gas
                     12.0
LPCas
             13.8
Comments on Combustion
 Performance (Assuming
 Satisfactory CO Levels)

Stoichiometric mixture
(Cannot be achieved for
reliable operation in
practice)
Typical for Residential
  Gas Burners (including
  conversion burners)
      37

      55

      90
8.5
7.5
6.0
70.0
8.6
7.0
Excellent
Average
Lower lin
                                                                       performance within proper
                                                                       adjustment region
The efficiency of fuel utilization is lowest at the low levels of C02 (high excess air), because
the greater the amount of excess combustion  air, the larger the amount of heat carried up the
stack.
The Significance of Fuel-Gas Temperature:
Its Effect on  Efficiency

        Temperature of gases at the flue outlet ahead of any dilution air (see Figure 4) is
significant in  determining the effectiveness of fuel utilization because it (together with the
flue outlet CC>2 reading)  is an indicator of the amount of heat lost up the stack.7  Temper-
ature must be measured at the same point as .the C02 sample is taken.  The best way to
take this measurement is with a small  bead (24 gauge)  iron-constantan thermocouple and
suitable potentiometer, although currently available equipment of this type may be more
expensive than thermometers. An effort should be made to obtain a representative flue gas
temperature.

        Net flue'outlet gas temperature* can be.considered abnormally high  for air heating or
water heating units if it exceeds 480°F.  A high temperature may indicate one  or more of the
following conditions:
•Net flue gas temperature is the observed temperature minus room temperature.
                                             22

-------
            1.  Excessive firing rate for available heat-exchanger surface of the
                appliance.

            2.  Dirty or soot-covered heating surfaces.

            3.  Excessive sediment in bottom of water heater.

            4.  Deterioration of baffles in flue passageways.

            5.  Insufficient air or water flow over  heat exchanger.

These points should be checked and remedied if temperatures are abnormally high.

       Thermal efficiency of heating equipment is  the percent of heat released from burning
the gas which  is actually transferred to the circulating air or water that is used to heat the
dwelling  (or, in the case  of water heaters, to heat the stored water).  Normally this efficiency
is determined  under steady-state conditions; e.g., with continuous burner operation after allow-
ing the equipment to heat up for at least 10 minutes.

       Thermal efficiency is equal to  100 percent minus the heat losses up the stack.  These
stack losses are generally referred to as flue losses.  Other losses can include appliance jacket
heat losses if these  losses do not contribute to heating the dwelling.  (The jacket losses
usually will only amount to 1 or 2 percent.)

       Two measurements are needed to determine flue losses and, therefore,  thermal
efficiency:

            - Net  flue gas  temperature (average flue-gas temperature minus room
               temperature).

            - Percent C02 in the flue gas.

       Figures 6 and 7  show the combined effects  of these two factors on  flue losses:
Figure 6  for natural gas, and Figure 7 for LPgas.  These flue-loss charts, based on steady-state
operation, .apply only for the specific  fuel gases indicated.  To use the nomographs, place a
straight edge on the chart with one edge crossing the CC>2 in flue gases scale at the observed
level and the flue-gas temperature — room temperature scale at the observed net flue-gas
temperature.  Read the flue loss at the point where the straight edge crosses the middle
(flue loss) scale.

       In the  example shown in Figure 6 (for natural gas), the flue loss is 22  percent for an
observed 8.2 percent CO2 in the flue gas and a net flue-gas temperature of 440° F.
Thermal  efficiency  is  100 percent minus the 22 percent flue loss; or 78 percent.
                                            23

-------
Seasonal Efficiency and Its
Potential for Improvement

       Seasonal thermal efficiency is less than the continuous or steady-state thermal
efficiency calculated from Figures 6 and 7 because the efficiency is lowered during cyclic
operation by additional losses up the stack from the unit during OFF periods.17  Seasonal
efficiency will be highest for units that:

               1.  Have high overall thermal efficiency during continuous operation.

               2.  Have firing rates matched to the design load.  (Overfiring results in
                  excessively long shutdown periods.)

               3.  Have vents properly sized for burner input.

               4.  Have Intermittent  Ignition Devices (IID's) instead of continuously
                  burning pilots.

               5.  Have means to minimize the OFF cycle losses, other than I ID.

        In 1976, the gas industry initiated a Space Heating Efficiency Improvement Program
(SHEIP) to  accelerate the industry's continuing effort to  help its customers increase the
seasonal efficiency of heating equipment. The purpose of SHEIP is to determine the energy
savings possible and  to encourage implementation  of useful  and safe options for improving
the energy efficiency of residential central heating systems.   Procedures are being developed
for implementing options that are most cost effective.  The status of this program can be
obtained by writing  to the American Gas Association, 1515 Wilson Boulevard, Arlington,
Virginia 22209.
                                            24

-------
                       C.  TYPICAL EMISSION CHARACTERISTICS
                            OF RESIDENTIAL GAS BURNERS
       When main burners are properly adjusted, the flue products from the combustion of
gaseous fuels contain relatively harmless nitrogen, carbon dioxide (C02), and water
vapor.  When the main burner is operating with incomplete combustion, because of dirty
conditions, or with an improper air-shutter adjustment, the flue products may also contain
carbon monoxide (CO), soot, and  hydrocarbons (HC).  A by-product of the combustion re-
action  is the formation of nitrogen oxides (NOX)  due to the high-temperature flames in the
presence of nitrogen and oxygen.

       Figure 5  illustrates the effects of combustion air on CO and  CO2 concentrations.  It
demonstrates that the CO is  very low within the proper C02 adjustment region.  The figure
also shows that the C02 reading does not always predict the CO level.  With a deficiency of
air, it is still possible to obtain a reasonable CO2  level, but with an undesirable CO level.
Therefore, the C02 level cannot be used as an indication of CO concentration.  For this
reason, it is  important to measure the CO concentration to ensure that it is at an acceptable
level.

       Figure 8  demonstrates the  expected effect of excess air on CO, HC, and NOX emissions
of a gas burner by showing the relationship of these emissions to excess-air supply (or C02
value). This figure shows the normal operating region of excess air for natural and LP gas
appliances.  As noted in the  discussion of the CO/CO2 relationship,  CO emission levels are at
unacceptable levels under a deficiency of combustion air.  HC  emissions also are high with a
deficiency of combustion air and may increase under very high excess-air conditions because
of lifting flames.   The NOX emissions reach a peak very near a stoichiometric air/gas mixture
(zero percent excess air) because this is the condition of maximum flame temperature.

       Figure 8  shows that  it is desirable to operate under an  excess-air condition of 37—90
percent in order  to minimize the pollutant emission levels.

       Most gas  burners will perform as shown in Figure 8.8-9-10  For some burners the
normal region will be wider or narrower; a few burners will operate  outside the region
shown.  The overall trend of the pollutant emissions, however, will be similar to that shown
by the figure.  In general, conversion burners will have a wider range of adjustment available
to the  service technician and will require greater care than designed  units.6

                                          25

-------
M
C
_g
'5
0>

1


UJ
o
o
a
o
a:
                                       Increasing Combustion Air
         60    40     20    0

        Air Deficiency, percent
20     40///60^/80/^   100    120

   Excess  Combustion Air, percent  	
                                        CO-, percent (natural gas)
                                   10.7    9.8    8.5   7.8    6.7

                                 -*—    CCg, percent (LP  Gas)
     Figure 8.  Effect of excess air on CO, HC, and NOX burner emission for a

               typical natural and LP gas fired heating appliance.
                                       26

-------
       The service technician should visualize the interaction of the various pollutants to
develop an appreciation that the CO/C02 relationship is basic to setting a burner for minimum
emissions by use of field measurements.  Judging the combustion adjustment  by using only
CO2 measurements could result in high CO and  HC. This can be avoided by  measuring both
the C02 and CO levels.

       Additional information on emission levels from various types of gas-fired equipment
is contained in APCA papers by the staff of the American Gas Association Laboratories.8'9'10
                                           27

-------
                         D.  REFERENCES & BIBLIOGRAPHY
References Cited

 1.  Locklin, D. W., and R. E. Barrett, Guidelines for Residential Oil-Burner Adjustments,
    Environmental Protection Agency, Report No. EPA-600/2-75-069-a (NTIS No. PB 248292),
    October 1975.

 2.  National Fuel Gas Code, American National Standard Z223.1-1974, American Gas Associa-
    tion, Arlington, Virginia, 1974.

 3.  Shnidman, L, Gaseous Fuels, American Gas Association, New York, New York, 1954.

 4.  Fundamentals of Gas Combustion, American Gas Association, Catalog No. XH0373,
    Arlington, Virginia, 1973.

 5.  Gas Engineers Handbook, Industrial Press Inc., New York, New York, 1969.

 6.  Installation of Domestic Gas Conversion Burners, American National Standard Z21.8-1971,
    American Gas Association, Arlington, Virginia, 1971.

 7.  Griffiths, J. C., Method of Calculating the Flue  Loss of Gas-Fired Equipment, American Gas
    Association Laboratories Research Report No. 1509, Catalog No. U07176, Cleveland, Ohio,
    1976.

 8.  DeWerth, D. W., and R.  L. Himmel, An  Investigation  of Emissions from Domestic  Natural
    Gas-Fired Appliances, SP-8 Proceedings, 67th Annual APCA Meeting, Denver, Colorado,
    June 1974.

 9.  Belles, F. E.,  R. L. Himmel, and D. W. DeWerth, Measurement and Reduction of NOX Emis-
    sions from Natural Gas-Fired Appliances, 68th Annual APCA Meeting, Boston,
    Massachusetts, June 1975.
                                          28

-------
10.   Himmel, R. L, E. H. Tausch, and D. W. DeWerth, Further Measurements of Emissions from
     Gas-Fired Appliances, 70th Annual APCA Meeting, Toronto, Ontario, June 1977.

11.   Brookman, G. T., and P. W. Kalika, Measuring the Environmental  Impact of Domestic Gas-
     Fired Heating Systems,  SP-8 Proceedings, 67th Annual APCA Meeting, Denver, Colorado,
     June 1974.

12.   Barrett, R. E., S. E. Miller, and D. W. Locklin, Field Investigation of Emissions from Com-
     bustion Equipment for  Space Heating, Report No. EPA-R2-73-084a (NTIS No. PB 223148),
     June 1973.

13.   Hall, R. E., Status of EPA's Combustion  Research Program for Residential  Heating Equip-
     ment - June 1974, SP-8 Proceedings, 67th Annual APCA Meeting, Denver, Colorado,
     June 1974.

14.   Hall, R. E., Status of EPA's Residential Space Heating Research Program - 1976, ASME
     Paper No. 76-NA/FU-4, ASME Winter Annual Meeting, New York, December 1976.

15.   Standard Method of Test for Smoke Density in  Fuel Gases from Distillate Fuels, ASTM
     02156-65(70), ASTM Standards for Petroleum Products (Part 17).

16.   Torborg, R. H., and U.  Bonne, "Instrumentation for Adjusting Burners for Improved
     Efficiency", APCA Paper No.  78-49.6, APCA Annual Meeting, Houston, Texas, June 1978.

17.   Janssen, J. E., U. Bonne, R. H. Torborg,  and A.N.J. Pearman, Reduced Pollution Through
     Increased Seasonal Efficiency of Residential Furnaces, 68th Annual APCA Meeting, Boston,
     Massachusetts, June 1975.
Bibliography

       The following publications covering fundamentals of gas equipment servicing are excellent
general reference manuals and can be obtained from the American Gas Association, 1515 Wilson
Boulevard, Arlington, Virginia  22209.

a.    Fundamentals of Gas Combustion, by A.G.A. Laboratories and Gas Appliance Manufacturers
     Association.  American Gas Association Catalogue No. XH 0373  (January 1973).

b.    Fundamentals of Gas Appliances, by A.G.A. Laboratories  and Gas Appliance Manufacturers
     Association.  American Gas Association Catalogue No. XH 1076  (December 1976).
                                          29

-------
c.    Fundamentals of Gas Appliance Venting and Ventilation, by A.G.A.  Laboratories and Gas
     Appliance Manufacturers Association. American Gas Association Catalogue No. XH 0474
     (May 1974).

d.    Fundamentals of Gas Controls, by A.G.A. Laboratories and Gas Appliance Manufacturers
     Association.  American Gas Association Catalogue No. XH  1275 (December 1975).

e.    Fundamentals of Electricity, by A.G.A. Laboratories and Gas Appliance Manufacturers
     Association.  American Gas Association Catalogue No. XH  0175 (March 1975).

f.    Fundamentals of Service to the Customer, by A.G.A. Laboratories and Gas Appliance
     Manufacturers Association.  American Gas Association Catalogue No. XH 0177 (March
     1977).
                                          30

-------
                                TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/8-79-005
                           3.
                                                      3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
Guidelines for Adjustment of Atmospheric Gas Burners
for Residential and Commercial Space Heating and
Water Heating
                                                      6. REPORT DATE
                                                      February 1979
                                                      6. PERFORMING ORGANIZATION CODE
7. AUTHORIS)
D.W.DeWerth, R.L.Himmel, and D.W.Locklin
                                                      B. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Battelle-Columbus Laboratories
505 King Avenue
Columbus, Ohio 43201
                                                      10. PROGRAM ELEMENT NO.
                                                      EHE624
                                                      11. CONTRACT/GRANT NO.
                                                      68-02-2653
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                                      13. TYPE OF REPORT AND PERIOD COVERED
                                                      Final; 9/77 - 12/78	
                                                      14. SPONSORING AGENCY CODE
                                                       EPA/600/13
15. SUPPLEMENTARY NOTES TJERL.
2477.
                                     officer is Robert E. Hall, MD-65, 919/541-
16. ABSTRACT
          The guidelines contain recommended procedures for adjusting residential
and commercial atmospheric gas burners used for space heating and water heating
to minimize air pollution and for efficienct use of fuel. They are intended for use by
skilled service technicians in adjusting burners, and as a aid to service managers
engaged in training service technicians.  In addition to recommended steps for burner
adjustment, the guidelines also include appendixes of background material on pollu-
tants of main concern, field-type instruments and significance of measurements,
and emission characteristics of residential gas burners.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                        c.  COSATI Field/Group
Air Pollution
Space Heating
Water Heaters
Combustion
Nitrogen Oxides
Smoke
                      Boilers
                      Aldehydes
                      Carbon Monoxide
                      Hydrocarbons
                      Natural Gas
                      Residential Buildings
                      Conservation	
Air Pollution Control
Stationary Sources
Energy Conservation
Burner Tune-up
LP Gas
13 B
ISA

21B
07B

13H
07C
2 ID
13M
IS. DISTRIBUTION STATEMENT

 Unlimited
                                          19. SECURITY CLASS (ThisReport)
                                          Unclassified
                         21. NO. OF PAGES
                             33
                                          20. SECURITY CLASS (Thispage)
                                          Unclassified
                                                                   22. PRICE
EPA Form 2220-1 (9-73)
                                        31

-------