xvEPA
United States
Environmental Protection
Agency
Research and
Development
EPA-600/7-87-010b
March 1987
ENVIRONMENTAL ASSESSMENT
OF A WOOD-WASTE-FIRED
INDUSTRIAL FIRETUBE BOILER
Volume II. Data Supplement
Prepared for
Office of Air Quality Planning and Standards
Prepared by
Air and Energy Engineering Research
Laboratory
Research Triangle Park NC 27711
-------
RESEARCH REPORTING SERIES
Research reports of the Office of Research and Development. U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:
1. Environmental Health Effects Research
2. Environmental Protection Technology
3. Ecological Research
4. Environmental Monitoring
5. Socioeconomic Environmental Studies
6. Scientific and Technical Assessment Reports (STAR)
7. Interagency Energy-Environment Research and Development
8. "Special" Reports
9. Miscellaneous Reports
This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series. Reports in this series result from the
effort funded under the 17-agency Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goal of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects; assessments of. and development of, control technologies for energy
systems; and integrated assessments of a wide range of energy-related environ-
mental issues.
EPA REVIEW NOTICE
This report has been reviewed by the participating Federal Agencies, and approved
for publication. Approval does not signify that the contents necessarily reflect
the views and policies of the Government, nor does mention of trade names or
commercial products constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Informa-
tion Service. Springfield, Virginia 22161.
-------
EPA-600/7-87-010b
March 1987
ENVIRONMENTAL ASSESSMENT OF A
WOODWASTE-FIRED INDUSTRIAL FIRETUBE BOILER
Volume II. Data Supplement
by
R. DeRosier and L. R. Waterland
Acurex Corporation
Environmental Systems Division
485 Clyde Avenue
P.O. Box 7444
Mountain View, California 94039
EPA Contract No. 68-02-3188
Project Officer: R. E. Hall
Air and Energy Engineering Research Laboratory
Research Triangle Park, North Carolina 27711
for
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON, DC 20460
-------
ACKNOWLEDGMENTS
The authors wish to extend their gratitude to P. .B. Wainright of the
North Carolina Department of Natural Resources and Community Development.
The cooperation of D. B. Harris and J. Montgomery of EPA/AEERL was also
instrumental to the success of the test program. Special recognition is also
extended to the Acurex field test team under the supervision of B. C. DaRos,
assisted by P. Kaufman, R. Best, and J. Holm.
11
-------
TABLE OF CONTENTS
Section Page
1 INTRODUCTION 1-1
2 PRELIMINARY TESTS 2-1
3 BOILER OPERATING DATA 3-1
3.1 OPERATING DATA 3-3
3.2 BOILER THERMAL EFFICIENCY CALCULATION 3-5
4 SAMPLING DATA SHEETS 4-1
4.1 CONTINUOUS EMISSIONS MONITORING DATA 4-3
4.2 FIELD DATA SHEETS FOR EPA METHOD 5, SASS, AND
CONTROLLED CONDENSATION . . .' 4-7
5 ANALYTICAL RESULTS 5-1
5.1 FUEL ANALYSIS 5-3
5.2 SASS PARTICULATE EMISSIONS 5-5
5.3 EPA METHOD 5 PARTICULATE EMISSIONS 5-11
5.4 SULFUR OXIDES EMISSIONS FROM CONTROLLED
CONDENSATION SAMPLES 5-19
5.5 TRACE ELEMENT ANALYSIS 5-23
5.6 Ci TO C6 HYDROCARBONS BY GAS CHROMATOGRAPHY .... 5-35
5.7 TOTAL CHROMOTOGRAPHABLE ORGANICS (TCO),
GRAVIMETRIC ORGANICS (GRAV), IR SPECTRA, AND GAS
CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS) 5-71
5.8 RADIOMETRIC ANALYSIS RESULTS 5-81
5.9 BIOASSAY REPORTS 5-85
iii
-------
SECTION 1
INTRODUCTION
The purpose of this data supplement is to document data in greater
detail than was possible in Volume I (Technical Results) of this report. It
is intended to provide sufficient detail for researchers to perform their own
analysis of the data obtained. Readers are referred to the technical volume
for objectives, description of source emission results, interpretation, and
conclusions.
The remaining sections of this data supplement contain the following
information:
Section 2 — Preliminary Tests: stack velocity traverse and gas composition
tests
Section 3 -- Boiler Operating Data: steam flow, drum pressure, feedwater
pressure, furnace pressure, outlet pressure, collector pressure,
stack temperature, and boiler efficiency calculations
Section 4 — Sampling Data Sheets: continuous emission monitoring data,
operating data tables for EPA Method 5 (for particulate mass
emissions), controlled condensation (for SOg and $03 sampling),
and SASS (for trace element and organic sampling)
Section 5 — Analytical Laboratory Results: fuel analysis, Method 5
particulate emissions, SASS particulate emissions, sulfur oxides
emissions from controlled condensation samples, trace element
1-1
-------
emissions by spark source mass spectrometry (SSMS) analysis and
atomic absorption spectroscopy (AAS) analysis; C^ to Cg
hydrocarbons by gas chromatography; total chromatographable
organic (TCO) and gravimetric (6RAV) results; infrared (IR)
spectra; determination of organic compounds by gas
chromotography/mass spectrometry (GC/MS); radiometric analysis
results, and biological assay reports on the SASS train samples,
1-2
-------
SECTION 2
PRELIMINARY TESTS
2-1
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCT:
PLANT JC^LJ |f i f** c-,-mvx-> , '/JILL roTf 2 £y •y^TT'tO AJ t_
DATE >-2«J->>/
SAMPLING I nCATinN ^TV^
INSIDE OF FAR WALL TO
OUTSIDE OF NIPPLE. (DISTANCE A)
INSIDE OF NEAR WALL TO
OUTSIDE OF NIPPLE, (DISTANCE B)
STACK I.D., (DISTANCE A - DISTANCE E
NEAREST UPSTREAM DISTURBANCE
NEAREST DOWNSTREAM DISTURBANCE
CALCIII ATOP £60
->.~>r"
/or "
) ?r^ •'
—>
=>«: —
/
TRAVERSE
POINT
NUMBER
/
£_
3
4^
5'
G
7
$
q
/b
//
l>
fZ>
If
1$
/(,
ll
it
H
T-0
^/
,v^
^
m
FRACTION
OF STACK I.D.
*OI.I
n^l_
0^
•^1
^^ 1 ^
•11
tttii,
%~*)°l
t<%(j%
,S?1^
^.)
,,^c
t/T y ^ jf
^
STACK I.D.
36'
PRODUCT OF
COLUMNS 2 AND 3
(TO NEAREST 1/8 INCH)
O&d C/'Q)
/JS
Z.db
Z^
^,"jy>
a'rtS
5i%b
7.00
55.3-^
"f.^0
// 60
/ *-"-"-— *
3-J.ol
0^.31
"^-^ /C^
'i^ /9
'3V, ^
&%
IL.0%
.21.U.Z
56, /i;
27.76
,2*7, V"7
In.Vl
3./. 75
?>S,^t)
35,17
* V.7/
.^, Zh
36.^
?i»7^
EPA(Dur)232 0 0
4/72 ^'^
-------
PRELIMINARY VELOCITY TRAVERSE
PLANT Jifc£
DATE i
LOCATION _
STACK I.D. ~*>(j.
BAROMETRIC PRESSURE, in. I
STACK GAUGE PRESSURE, in. H,0
OPERATORS.
TRAVERSE
POINT
NUMBER
7
H
.16
AVERAGE
EPA (Dur) 233
4./72
VELOCITY
HEAD
ps), in.H20
,37
70
,•75"
. 7D
STACK
TEMPERATURE
.3
¥
5
(l
7
fr
f
/D
i!
f3-
».3
lu
IS
!/,
n
i*
/^
£o
M
•tA-
^ 2s
<*-C
c7^
C-V/ j
AVERAGE
VELOCITY
HEAD
fcps), in.H20
^
STACK
TEMPERATURE
(Ts), eF
-------
Ptant_
Date
ISOKINECTIC SAMPLING WORKSHEET
Reformed by
&£
Sample Location
Test No./Type ?tf'/c;
~ •'
K = 782.687 (Cp)2 (1-BWO)2 Ps Md
Ko2 Ms Pm
where: K - Contant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimensionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Md(l-Bwo) + 18(8^)
Abo lute meter pressure (in. Hg)
782.687 (tfl>£fl
2-4
-------
Plant_
Date
» Z/
ISOKINECTIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
VUJA
Performed by
Sample Location /O
Test No./Type Uf ^ /
25
where:
Nozzel diameter (inches)
Average pressure differential across the
orifice meter (in. ^0)
Temperature stack gas, average (°F)
Temperature of gas meter, average (°F)
Stack gas velocity pressure (in h^O)
/ ( ) ( + 460) \-25
\( ) ( +460)( )/
AH
Ts
Tm
AP
Nd
/,^
S^LO
$s
,-70
*£?/
A m
AH = K (Nd)4 ^ (AP)
where: AH * Pressure differential across the orifice meter (in H20)
Nozzel diameter
Temperature of
Temperature of
, actual (inches)
gas meter (°F)
stack gas (°F)
Stack gas velocity pressure (in HgO)
(( ) (_
Magic number
x4 ( + 460) , A
' ( + 460) * */
( )4
Nd
Tm
Ts
AP
AH
K(N ,4
,30*6
7, Sft'2-,
2-5
-------
Plant \ .... ' >
Date vj...--
ISOKINECTIC SAMPLING WORKSHEET
\- - • _y - — Reformed by p. c v,..:W 0.
Sample Location
Test No./Type / -
K = 782.687 (Cp)2 (1-BWO)2 Ps Md
Ko2 Ms
where: K = Contant of fixed and assumed parameters (dimensionless)
Pitot coefficient (dimensionless)
Water vapor in the gas stream
(proportion by volume)
Absolute stack gas pressure (in. Hg)
Molecular weight, stack gas dry
(Ib/lb-mole)
Orifice coefficient (dimensionless)
Molecular weight, stack gas wet
(Ib/lb-mole) Md(l-Bwo) + 18(BWQ)
Abo lute meter pressure (in. Hg)
782.687 ( )2 (i- )2 ( ) ( )
( )2 ( ) ( )
CP
Bwo
PS
Md
KO
MS
Pm
K
"*\ ~»
i t
'~* r
" * "' _^
s~ _
.-. /,
-*% .' •
X- -. - • .. ••- ,
-•
2?,~'i-
2t.*i¥
j5.ci>ci
2-6
-------
ISOKINECTIC NOZZLE CALCULATION
AND
SAMPLING RATE CALCULATION
PI ant g .n
Date
Performed by f z-^j
-2 -
Sample Location_
Test No./Type
AH Ts \-25
where: N
-------
SECTION 3
BOILER OPERATING DATA
3-1
-------
3.1
OPERATING DATA
CO
I
to
Time:
SU-acn (low (ini)0lb/hr)
Drum pressure (pllg)
Foedwator proisuro (pilg)
Furnace pressure (In. MjO)
Out lot pressure (In. lljfl)
Collector prossuro (In. HjO)
Stack temperature (°F)
9:30
9.5
\?.n
162
0
1.1
2.25
650
10:0(1
11.2
120
157
0
1.0
2.2
650
10:30
13.0
122
162
0
0.9
2.2
660
11:00
13.0
124
165
0
1.25
2.2
650
11:30
13.7
122
160
0
1.0
2.1
650
12:00
13.5
122
165
0
1.0
2.1
650
12:30
13.5
120
155
0
0.9
2.1
620
1:00
14.5
124
165
0
0.9
2.1
670
1:30
14.5
124
163
0
1.2
2.1
600
2:00
14.2
124
162
0
1.2
2.1
eno
2:30
14.6
in
162
0
1.0
2.1
670
3:00
15.0
I2r>
122
0
1.0
2.1
620
3:30
14. B
121
165
0
1.0
2.1
690
4:00
14. fl
122
162
0
o.n
2.1
700
4:3fl
14.5
122
IBS
0
0.9
2.1
630
', : 00
M.O
122
160
0
1.0
2.1
620
Average
13.6
122
158
0
1.0
2.1
r.5n
-------
3.2 BOILER THERMAL EFFICIENCY CALCULATION
3-3
-------
SUMMARY SHEET
A.SME TEST FORM
FOR ABBREVIATED EFFICIENCY TEST
PTC 4.1-0(1964)
TEST NO. / BOILER NO. / 0 A T E el'*i OBJECTIVE OF TEST /^.^^JtsAfei*.
DUHATION^V-
BOILER MAKE 4 TYPE JHtT ' Kr^futt^ RATED CAPACITCXTA«^/U.
STOKER. TYPE 4 SIZE /tfC-fi'^iy
PULVERIZER. TYPE 4 SIZE A^n-f - * BURNER. TYPE
FUEL USED JtJeelfl fff-Te «»•* COUNTY STATE
~ /
4 SIZE
SIZE AS FIRED
PRESSURES 4 TEMPERATURES FUEL DATA
1
2
3
4
i
7
,
,
10
II
13
1]
14
STEAM PRESSURE IN BOILER DRUM
STEAM PRESSURE AT S. N. OUTLET
STEAM PRESSURE AT R. H. INLET
STEAM PRESSURE AT R. H. OUTLET
STEAM TEMPERATURE AT S. H. OUTLET
STEAM TEMPERATURE AT R.H. OUTLET
WATER TEMP. ENTERING (ECON HBOILER)
STEAM QUALITY^ MOISTURE OR P. P.M.
AIR TEMP. AROUND BOILER (AMBIENT)
TEMP AIR FOR COMBUSTION
(Thit It R»f«r«nc« TafUMOiuf*) f
TEMPERATURE OF FUEL
GAS TEMP. LEAVING IE cut.) (Ait Mir.)
GAS TEMP. ENTERING AH (II u«4ill«nt I* k«
••I.
Ml.
M>«
o.i.
F
F
F
F
F
F
F
F
F
/"3~7
/^9*
77
77
£•*£&'
UNIT QUANTITIES
IS
14
|7
If
It
30
31
a?
23
24
2)
ENTHALPY OF SAT. LIQUID (TOTAL HEAT)
ENTHALPY OF (SATURATED) (SUPERHEATED)
STM.
ENTHALPY OF SAT. FEED TO (BOILER)
(ECON.)
ENTHALPY OP REHEATED STEAM R.H. INLET
ENTHALPY OF REHEATED STEAM R. H.
OUTLET
HIAT ABl/LI OF STEAM (ITEM U-ITEU HI
HEAT Atl/LB R.N. STEAM (ITEM 19-ITEM It)
BUY REFUSE (ASH PIT » FLY ASH) PER LB
AS FIRED FUEL
Bh PER LB IN REFUSE (WEIGHTED AVERAGE)
CARBON BURNED PER LB AS FIRED FUEL
DRY GAS PER LB AS FIRED FUEL BURNED
HOURLY QUANTITIES
24
27
21
39
30
II
33
33
14
IS
36
ACTUAL WATER EVAPORATED
REHEAT STEAM FLOW
RATE OF FUEL FIRING (AS FIRED -i)
TOTAL HPAT IMPUT (!'•<•. 2* * .!••«• ll«» 20)>(li«* 27.li.-x 11) Hun 30
OUTPUT 1000
3h,/lk
Btu/lk
Bin/Ik
Blu/'l k
Blu/lk
Bta/lk
9iu/lk
Ik/Ik
Bi»/lk
Ik/Ik
Ik/ Ik
Ik/kr
Ik/fcf
Ik/hr
ka/H,
kB/T>,
k8/l«
~3/J
f/*n
93
1/C0
o&'Z'
M.3*t
J140C
7o~)l
^k^ltf/*(
JJ/f^S
n%a
FLUE GAS ANAL. (BOILER) (ECON) (AIR HTR) OUTLET
CO,
0,
CO
N, (BY DIFFERENCE)
EXCESS AIR
XVOL
% VOL
% VOL
% VOL
*
7,7
O.I
T^f /
I/J&
COAL AS FIRED
PROX. ANALYSIS
37
31
39
40
MOISTURE
VOL MATTER
FIXED CARBON
ASH
TOTAL
4)
42
BH. ~. Ik AS FIRED
ASH SOFT TEMP.-
ASTM METHOD
*wt
^,i(e
0,¥~)
$?(¥<&
COAL OR OIL AS FIRED
ULTIMATE ANALYSIS
43
44
4S
46
47
40
37
CARBON
HYDROGEN
OXYGEN
NITROGEN
SULPHUR
ASH
MOISTURE
TOTAL
WfD/
-srya
y?-"53
a, it
0.0^
^•V"?
I^TA/
te0.ffa
COAL PULVERIZATION
41
49
SO
44
GRINDABILITY
INDEX*
FINENESS XTHRU
SOM-
FINENESS X THRU
200 M*
SI
53
S3
44
41
OIL
FLASH POINT F*
Sp.Graoltr O.j. API-
VISCOSITY AT SSU*
BURNER SSF
TOTAL
% -I
BlM p*f
HYDROGEN
Ik
CAS
54
SS
54
»
58
}9
60
61
CO
CH. METHANE
C,H, ACETYLENE
C,H. ETHYLENE
C,H. ETHANE
H,S
CO,
H,
HYDROGEN
TOTAL
6]
63
41
TOTAL HYDROGEN
X.t
SVOL
DENSITY 61 f
ATM. PRESS.
Bte PERCU FT
Biv PER LB
INPUT-OUTPUT ITEM 31 . 100 j,—. t
EFFICIENCY OF UNIT K ITEM 29 l{> • 1
HEAT LOSS EFFICIENCY
4S
44
47
61
69
70
71
n
HEAT LOSS DUE TO DRY CAS
HEAT LOSS DUE TO MOISTURE IN FUEL
HEAT LOSS DUE TO H,0 FROM COMB. OF H,
HEAT LOSS CUE TO COMBUST. IN REFUSE
HEAT LOSS DUE TO RADIATION
UNMEASURED LOSSES
TOTAL
Bin/ Ik
A. F. FUEL
/flfjYJ
7t£<7
£ R.«ui..4 IM Ellicimcf T.nioj
1 FM Feint «l U**«u»*M S» Pw. 7.2.1. 1-PTC 4.1-1964
16
3-4
-------
CALCULATION SHEET
ASME TfST FORM
FOR ABBREVIATED EFFICIENCY TEST
PTC 4.1-b (1964)
Revised September, J965
OWNER OF PLANT ^Itf^f^"^ TEST NO. /
30
24
25
J»
45
<4
<7
68
49
70
71
n
.... rf
HEAT OUTPUT IN BOILER SLOW-DOWN WATER -LB OF WATER BLOW.OOWN PER HR
If impractical to weigh refuse, this
item eon be estinated as follows
ont itcruic rrn LO or AI nitto rucL , * A5H IN AS "HEO CO*L
DRY RCI-USC PER LO Of AS TIRED TUCL - ,„ _ % <-„„„ |N REFUSE JAMPLE
ITEM 43 [TTEM22 ITEM23~|
r^PZcD , ***'• » *•«*"
FUEL 10° L IOM J
ORY CAS PER LB 11CO, « 10, » 7(N, « CO)
BURNED KCO. » CO) ~, 7""
(ITEM 33 ITEM 34 \
.7.1..* <3/..)
EXCESS °> ' -T- S6*,33 ~ •!I¥2
J.IH1 .2A82N,-(o, _ TO.,
^ ~ .2412 (ITEM 35) - (ITEM 33 .
BOILER NO. / DATE ^jfy-Sl
ITiM IS ITEM 17"
1000
U/t,.
NOTEi IF FLUE DUST I ASH
PIT REFUSE DIFFER MATERIALLY
IN COMBUSTIBLE CONTENT, THEY
SHOULD BE ESTIMATED
SEPARATELY. SEE SECTION 7.
COMPUTATIONS.
S FIRED FUEL • _2- S)
["]
*/5- * .j&$. /y43
2«7 J
•a~~ „
. •"" 3» ,
HEAT LOSS EFFICIENCY
HEAT LOSS DUE LB DRY CAS ITEM 7S (ITEM13I-(ITEM1I)
TO DRY CAS « PERLBAS XC x ('!., - 'rt,) » . XO.J4 .,— . «T_ '
FIRED FUEL ' O,,, /f^.^. . 6fS.. .77..
- (ENTHALPY OF LIQUID AT T AIRll • ITEM 37 K[(gnTHALD
IOO.J-T46 " t/J<
AT 1 PSIA « T ITEM 13) -(ENTHALPY OF LIQUID AT T ITEM 1
IS LVC)
r^OF VAPOR
n— ^"^ '
HEAT LOSS DUE TO H,O FROM COMB. OF H, • 9H, X ((ENTHALPY OF VAPOR AT 1 PSIA 1 T CAS
»CSVZ / /SAfl —•J'^i LVG| ' ^HTHALPY OF LIQUID AT T AIR)]
. 9 X ITEM U X ((ENVrtiLPY OF>APOR AT 1 PSIA I T ITEM 13) - (ENTHALPY OF LIQUID AT
100 T ITEM ID] «
HEAT LOSS DUE TO ITEM 22 ITEM 23
COMBUSTIBLE IN REFUSE * * *
HEAT LOSS DUE TO TOTAL BTU RADIATION LOSS PER HR
RADIATION* LB AS FIRED FUEL - ITCH 21
UNMEASURED LOSSES "
TOTAL
EFFICIENCY « (100 - ITEM 71)
./&>...
AS FIRED
FUEL
f?7o
"744
/'•ft
m
—
LOSS x
HHV
100 i
?i xtoon
41
*t XIOO«
41
JLxlOO*
41
4?
WX!00,
H
41
LOSS
-?y,2
e*
K.
..O..
/.o
AS:
i^.
u&
For r««aroui d«*«fl««n«tloi» «f ••€••• «fr «•• App«*dlB 9.2 • PTC 4.1*1964
II !•(••• «r. n«f «mi>~d, <••« ABMA Si»«~-l*"J '•• W •••Ifnlxt
«• •'•In* b> "•<" 70.
17
3-5
-------
SECTION 4
SAMPLING DATA SHEETS
4-1
-------
4.1
CONTINUOUS EMISSIONS MONITORING DATA
Time
10:00
10:03
10:06
10:09
10:12
10:15
10:18
10:21
10:24
10:27
10:30
10:33
10:36
10:39
10:42
10:45
10:48
10:51
10:54
10:57
11:00
11:03
11:06
11:09
11:12
11:15
11:18
11:21
11:24
11:29
11:30
11:33
11:36
11:39
11:42
11:45
11:48
11:51
11:54
11:57
12:00
12:03
12:06
Dry, Unconnected
02
(%)
12.8
13.5
13.3
12.0
11.8
13.8
12.8
13.0
12.3
12.3
12.5
12.3
13.0
16.6
14.5
12.8
14.3
12.5
14.5
12.0
13.5
11.0
14.8
11.8
12.3
13.3
13.5
12.8
12.5
14.0
16.8
19.5
12.8
15.0
13.3
13.3
15.3
13.5
12.5
14.5
13.5
13.0
15.3
CO
(ppm)
148
118
1,545
118
79
216
177
118
235
138
118
89
167
2,248
1,105
69
274
196
294
89
98
79
304
59
333
118
323
79
128
196
479
108
313
743
274
98
1,798
684
69
235
127
69
2,257
NO
(ppm)
145
143
143
178
148
120
138
144
159
162
154
142
122
83
134
124
104
144
106
163
138
173
136
141
158
130
130
130
157
116
142
2.7
140
118
140
132
105
139
134
129
125
132
93
Corrected to 3% 02
CO
(ppm)
324
284
3,611
236
155
540
388
266
487
285
250
184
375
9,196
3,059
152
737
415
814-
177
236
142
881
116
689
275
775
173
270
504
2,054
1,296
687
2,229
641
229
5,678
1,642
146
650
306
155
7,128
NO
(ppm)
317
343
332
356
288
299
302
293
327
332
326
291
274
339
371
270
277
304
294
326
332
311
392
273
325
303
313
284
333
297
603
33
305
353
324
307
329
334
285
358
299
296
290
Comments
Start of Method 5 train
Start of SASS train
CM down for repairs
CM down for repairs
CM down for repairs
CM down for repairs
CM down for repairs
CM down for repairs
CM down for repairs
4-2
-------
4.1
CONTINUED
Time
12:09
12:12
12:15
12:18
12:21
12:24
12:27
12:30
12:33
12:36
12:39
12:42
12:45
12:48
12:51
12:54
12:57
13:00
13:03
13:06
13:09
13:12
13:15
13:18
13:21
13:24
13:27
13:30
13:33
13:36
13:39
13:42
13:45
13:48
13:51
13:54
13:57
14:00
14:03
14:06
14:09
14:12
Dry, Unconnected
°2
(%)
12.3
13.5
143
12.0
15.0
12.0
14.0
12.5
14.0
11.8
12.5
14.5
11.8
13.8
14.0
11.5
13.0
15.0
11.5
13.0
15.3
12.0
11.3
16.0
11.5
12.0
16.3
11.3.
12.3
14.3
15.3
14.3
11.0
14.3
12.5
12.6
13.5
12.2
14.0
11.5
13.5
14.5
CO
(ppm)
78
332
723
176
1,115
88
381
59
303
49
108
440
117
469
196
59
156
1,104
59
117
1,544
59
225
1,270
59
156
1,710
0
117
156
674
146
78
205
58
78
78
137
117
68
68
205
NO
(ppm)
124
136
100
139
93
114
112
112
124
121
143
92
140
126
109
128
142
85
154
171
125
139
178
99
144
182
84
120
151
108
0.6
103
143
141
138
136
122
121
117
169
135
140
Connected to 3% 02
CO
(ppm)
162
798
1,943
352
3,345
176
980
125
779
96
228
1,218
230
1,173
503
111
352
3,312
111
264
4,875
117
417
4,572
111
313
6,548
0
242
420
2,128
393
140
551
124
167
187
279
301
129
164
567
NO
(ppm)
256
327
266
277
277
228
287
236
318
236
302
255
273
312
280
242
320
234
292
384
392
279
328
355
273
364
319
221
310
287
2
274
258
375
292
292
292
249
300
320
325
388
Comments
4-3
-------
4.1
CONTINUED
Time
14:15
14:18
14:21
14:24
14:27
14:30
14:33
14:36
14:39
14:42
14:45
14:48
14:51
14:54
14:57
15:00
15:03
15:06
15:09
15:12
15:15
15:18
15:21
15:24
15:27
15:30
15:33
15:36
15:39
15:42
15:45
15:48
15:51
15:54
15:57
16:00
16:03
16:06
16:09
16:12
16:15
16:18
16:21
Dry, Unconnected
02
(X)
9.8
14.0
11.5
13.3
12.5
12.5
15.0
11.0
14.5
10.8
14.4
9.3
14.0
15.0
11.3
14.3
12.3
14.8
11.4
14.8
10.0
14.3
10.8
11.5
14.8
11.0
14.0
12.0
13.3
14.5
11.8
14.8
11.0
14.5
10.0
14.0
11.3
14.3
10.0
13.3
13.8
12.6
13.8
CO
(ppm)
58
68
68
68
107
58
351
48
146
48
87
127
78
488
48
166
. 58
136
48
175
38
78
58
78
146
87
77
87
97
234
68
234
97
107
38
77
85
107
97
77
97
68
77
NO
(ppm)
171
131
178
133
189
142
123
144
135
167
125
174
120
118
134
148
125
122
141
122
155
130
164
164
117
177
117
161
114
110
107
91
121
107
142
132
174
116
173
130
157
136
143
Corrected to 3% 02
CO
(ppm)
94
175
129
159
227
123
1,054
87
405
85
239
195
200
1,464
90
445
120
396
91
509
63
208
102
147
424
157
199
174
227
647
132
679
174
295
63
199
158
286
158
181
242
145
193
NO
(ppm)
274
336
336
308
400
300
369
259
373
294
338
267
310
353
248
395
257
352
262
351
253
347
287
310
337
319
300
321
266
304
209
262
218
297
232
340
321
309
284
301
390
292
355
Comments
4-4
-------
4.1
CONCLUDED
Time
16:24
16:27
16:30
16:33
16:36
Dry, Unconnected
02
(%)
13.5
13.0
15.0
10.3
14.5
CO
(ppm)
146
67
263
77
136
NO
(ppm)
166
134
120
168
127
Corrected to 3% 03
CO
(ppm)
350
152
789
130
376
NO
(ppm)
398
301
360
281
351
Comments
End of SASS train
4-5
-------
4.2' FIELD DATA SHEETS FOR EPA METHOD 5, SASS, AND CONTROLLED CONDENSATION
4-6
-------
Plant.
Date
Sample Location
Sample Type
Run Number
Operator
Ambient Temperature_
Barometric Pressure
Static Pressure. fHg01 —
Filter Number(s)
Leak Check; Initial at /ft • Hg.«££7_ CFM
Final at // • Hg. .oo^CFH
FIELD DATA
Implnger Volumes
Initial Final
"Q— 11—'
Silica Gel
Page j_ of
e<-3
Probe Length and Typ
Nozzel I.D. (No.) /3off<£ /*~/K>
Assuned Moisture fe*
Molecular Height. Dry. (MH)_
Meter Box Number
Meter Coefficient . 7/^
a Factor
K »
K(Nd)4 • -^ "
AH =» K(Nd)4 fe) (AP)
Traverse
Point
Number
Clock Time
(24-hr)
Clock
Sampling
Time, mln
Gas Meter
Reading ,
I nit.
Velocity
Head
(&PS).
In. H20
Orifice Pressure
Differential
(VH), In. H20
Desired
Actual
Stack
Temperature °F
Probe
Implnger
Organic
Module
Oven
Gas Meter
In
Out
Pump
Vacuun
In. Hg
Av
y-
.75*
-5*
7,5"
3,5*0
2-25
55?-
2.
2£L
Comments:
-------
Page 2_ of
Traverse
Point
Number
Clock Time
(24-hr)
Clock
Sampling
Time, mln
Gas Meter
Reading ,
Inlt.
Velocity
Head
(APS).
In. H20
Orifice Pressure
Differential
(AH), In. HjO
Desired
Temperature °F
Stack
Probe
Impl nger
Organic
Module
Gas Meter
Oven
In
Out
Pump
Vacuum
In. Hg
Avg.
to
3
d.Tfl
336
W7
/a.
. o
,275
7
r//
6
1L
27'
00
n
Q
^75
to
$7
ft
,20
sr
ft
2-06
87
5
3
-------
Page 3 of
Traverse
Point
Number
Clock Time
(24-hr)
Clock
Sampling
Time, rain
Gas Meter
Reading
(Vra). ft 3
Inlt.
Velocity
Head
(APS).
In. H20
Orifice Pressure
Differential
(AH), 1n. H20
Desired
Actual
Temperature °F
Stack
Probe
Implnger
Organic
Module
Gas Meter
Oven
In
Out
Pump
Vacuum
In. Hg
Avg.
I
57
2
96
9-6
^53
^70_
27*>x2
«D
•7
•7^0
ZTS
rr
ZLS.
,7.5
175
JSL
&D.
,70
87
sr
j70_
5^2
85
fa)
j2£-
528
90
&
T^r
527
fD
/oo.O
Run No.
Date
Sampling Location
Conments:
-------
Page fy of £/
Traverse
Point
Number
Clock Time
(24-hr)
Clock
Sampling
Time, win
Gas Meter
Reading
(Vm), ft 3
Inlt.
Velocity
Head
(APS).
In. H20
Orifice Pressure
Differential
(AH). In. H20
Desired
Actual
Temperature °F
Stack
Probe
Implnger
Organic
Module
Oven
Gas Meter
In
Out
Pump
Vacuum
In. Hg
Avg.
9
/ft
2O
^ a-
a/
5VJL
f/
/o
761
X?
y
, 0
rs
i
5
»$*
/JO
Run No.
Date
Sampling Location
Comments:
-------
PI ant
Date
i g 1
*• r
~-r*V\ C
Sample Location
Sample Type
Run Number /*
FIELD DATA
Implnger Volumes
Initial Final
Page j of 2.
Probe Length and Type.
Nozzel 1.0. (No.)
Assumed Moisture
( (5 ffi
Operator i^
Ambient Temperature_
Barometric
Silica Gel
Static Pressure, (H«0) -t
Filter Number(s)
ak 5
Molecular Height, Dry, (Md)_
Meter Box Number__
Meter Coefficient
a Factor_
K -
K(Nd)4 «
x(_)4
Leak Check; Initial a
Final at
; Hg,
.' Hg,
CFM
(AP)
Traverse
Point
(lumber
Clock Time
(24-hr)
Clock
Sampling
Time, mln
10
/-o
75
'-VI
Gas Meter
Reading „
(Vm), ft 3
, S
30^,30
Velocity
Head
(&PS).
In. H20
(fbeslredY ^Actual)
—•—-2*~ -.^—-^
(7-
0-
Orifice Pressure
Differential
M). In. H20
«**. .
Temperature °F
Stack
Probe
Implnger
Organic
Module
66
?
Oven
326
-
Gas Meter
In
Out
7f
Pump
Vacuum
In. Hg
*\vg.
^Sp
t?<>7
ds3_
Comments:
-------
Page ^- of 2.
Traverse
Point
Number
Clock Time
(24-hr)
Clock
Sampling
Time, mln
Gas Neter
Reading
(»•). « 3
Inlt.
Velocity
Head
(APS).
In. H20
Orifice Pressure
Differential
(AH). In. H20
Desired
Actual
Temperature °F
Stack
Probe
Implnger
Organic
Module
#7
534
5/7
7^7. ^
0,5
li
ns
0,4,
f/1
6.4
V/7
ASS
0-3
AS.
£25 £&
i
i—«
bo
. 077
/.
Run Ho. ,,SBSS-\
Date
?,
Sampling Location
Comments:
-------
CONTROLLED CONDENSATION SYSTEM (CCS)
FIELD DATA SHEET
Date
Sample Location
Run No. /
Operator
Ambient Temperature
Barometric Pressure
Meter Box Number
Meter Orifice Coefficient ,1/2.
Meter a Factor .
Clock Time
(24-hr)
clock
Sam-
pling
Time,
min
q5~
Gas
Meter
Reading
(V«). «3
Init.
Temperature (°F)
Stack
Probe
Filter
Skin
Out
Recirc
Water
Exit
Coil
Dry Gas
Meter
In
Out
10
V
/s-o
<=!!
0
12*1
Average
4-13
-------
CONTROLLED CONDENSATION SYSTEM (CCS)
FIELD CHECKPOINT SHEET
Checkpoint
Initials
Supervisor
QA
Inspector
Remarks
LABORATORY PREPARATION
• Inspect and clean CCC. Both filter holder and CCC
are cleaned with hot chromic acid solution and
D.I. H20.
• Rinse with acetone and air dry CCC.
• Place Tissuequartz filter in filter housing.
• Check seal between end of joint and filter.
• Do not use grease on Joints.
• Inspect and clean all glass joints.
SITE SETUP
• Rinse the inside of probe prior to run.
• Rinse probe with acetone until rinse solution Is
clear.
• Perform leak test.
• Leak rate must be less than 80 ml/min (0.003 cfm).
• Thermocouple leads attched to probe and filter.
t CCC water bath held at 60°C (140°F) +1°C.
* Leak test train.
• Probe temperature maintained at 316°C (600°F)
• Sas temperature out of filter holder held at
228°C (550°F).
• Fresh solutions placed 1n 1mp1ngers.
• Fresh absorbent replaced In final implnger.
• Adjust flowrate 1n system to 8 1pm.
4-14
-------
CONTROLLED CONDENSATION SYSTEM (CCS)
FIELD CHECKPOINT SHEET ~ Continued
Checkpoint
Initials
upervisor
QA
Inspector
Remarks
SAMPLING RUN
t Turn vacuum pump on just before Inserting probe
in stack.
• Check seal between probe and port to prevent any
outside air from entering stack.
9 Run test for 1 hour or until colls are frosted to
1/2 or 2/3 their length.
• After run, cap both ends of probe and lay 1n
horizontal position.
• Rinse the CCC coils into the modified Erlenmeyer
flask with a maximum of 40 ml D.I. H20.
• Was any of the solution lost (jf ml estimated)?
• After probe has cooled, it Is rinsed with a maximum of
40 ml D.I. HaO into a 25-ml Erlenmeyer flask.
- Was any solution lost ( o/ml estimated)?
- Clean support equipment priot to next run.
- Save filter for titration.
Comments:
4-15
-------
SECTION 5
ANALYTICAL RESULTS
5-1
-------
•5.1 FUEL ANALYSIS
LABORATORY CERTIFICATE
CURTIS & TOMPKINS,LTD.
- /• x ; >
--*"'.'
XnraMjannt MT*
ANALYTICAL-
-CONSULTING
KCMISTS
/O» «M*^IH» FCK MAM*
IT* AMO TltADC O»OAMIIATlO«lft
•AMPLKRS — INSPECTORS
1»O DIVISION STREET
SAN FRANCISCO. CALIF. 94IO3
U.S.A.
TaMphon* (416) 881-1863
o. SlhlOO
PreKmhuryNo. 6h&7
For ACUREX CORPORATION
«c*t»»CH — INVESTIGATIONS
"»•-" *»*"«- "ocMiM..t,
»«ei«».l*T« IN BULK CO-MOOITIt.
Reported 8/13/81
$*>»/>/«* ......
Received 7/07/8!
Report on 5 samples of Fuel Product
Project No. 773^.12, 7/06/81, Blanket Subcontract RB59186A,
Release No. 2.
DRY BASIS EXCEPT AS NOTED
813690
1st 2nd 3rd
Test Test Test
Carbon (c),
Hydrogen (H),
Oxygen (0), (by
difference),^
Nitrogen (N),
Sulfur (S), %
Heating Value:
BTU/Pound
Specific Gravity,
75°P (as rec'd) .....
Ash, % ...............
Moisture, $
(as rec'd)
hj.60
5.75
U5.93 —
0.18 0.22 0.15
0.0^ O.O^r- 0.03
8,630
16.25
0.50
5.66
SAMPLES DISCARDED 3CPAYS AFTER RECEIPT UNLESS OTHERWISE REQUESTED
5-2
-------
5.2 SASS PARTICIPATE EMISSIONS
5-3
-------
P1 ant flu,//„*£,,
Date ^-2.?-
ISOKINETIC PERFORMANCE WORKSHEET & PARTICULATE CALCULATIONS
Performed by
Sample Location
Test No./Type
Barometric Pressure (in. Hg)
Meter volume (std),
™^4^
\UATm+460/
/tox*A /(**•») + <^\
17 fifll H 13'6 )
I/>D Yp.rau/u».y) * «6o /
Volume of liquid collected (grams)
Volume of liquid at standard condition (scf)
Vlc x 0.04707
Stack gas proportion of water vapor
vw std , ( )
Vw std + Vm std < J 4 l '
Molecular weight, stack gas dry y
(Ib/lb-mole)
(X C02x 0.44) + (X 02x 0.32) + (X N£+ X CO x 0.28)
(7v7 x 0.44) + Q7.<7y x 0.32) + (77.ff/+ x 0.28
Molecular weight, stack gas wet
(Ib/lb-mole)
Md(i-Bwo) + 18(BWO), fry.7y)(i-aw^ + is(o.wv)
Absolute stack pressure (in. Hg)
r , pst«k <1"- H2°) (-n,,,'^'
pb 13.6 * l^^-j 13.6
Pb
vm std
Vlc
vw std
Bwo
Md
Ms
Ps
*?. ?#
IOH,.?^?'
1073, &
s°-j-iy
0,09?
-------
Temperature stack gas, average (°F)
Stack velocity (fps)
' /MV9 + 460
85 /! fi/3P \ / .-
Bb.10 (CpJ IV4PS ayg) I p^ ^
I(S&.3) + 460
85 /I9 fo ">fcf UJ?" ' " \ 1 -
85.19 fcMK^) Jtg^bj^
Total sample time (minutes)
Nozzle diameter, actual (inches)
Percent isokinetic (%)
17.33 (Ts + 460) (Vw std + Vffl std)
e Vs Ps Nd2
17.33 (525.3+ 460) ((^22) + (/^3K?))
( 3^?5- )(5^.(?jJ)(^S'.f-r Jt^I//^)"
Area of stack (ft2) »= 3.1416
nr2-*-144, ir( W )2-i-144
Stack gas volume at standard conditions (dscfm)
60 (1 - BWQ)Vs A. / 528 \ / Ps \
wo avg - f TS avg + 460 1 (29.92J
60 (1 -^)(5?.o;)(7.«?)/ 528 \ / (&&\
\S9*.* + 460 / y29.92)/
Particulate matter concentration, dry (gr/dscf )
15.432 Mp(9rams), 15.432 <£££>
Vm «. j den. it?- )
Emission rate of particulate matter (Ib/hr)
0.00857 (QJ C, , 0.00857 ( )( )
* "(std)
Ts
Vs(avg)
0
Nd
XI
AS
QS
Cs, %
s(std)
ED
V
522,3
f ? /n r- z
o -5 , <7 5>
Z7-T
O.lUt
\n.i
7.M?
Hit*
0 n$>3
U'j UO — '
7602/5/81/Rev 1
5-5
-------
01
en
ACUREX
Corporation
ANALYSIS LABORATORIES
DATA REPORTING FORM
CMEA
OATE July 13. 1981
cus
RES
AC
I
TOMER COt
JLTS REPOI
innpss
^JTRACT NO
TT TO L.
307736.22
Waterl and
ACUREX C(
TELEPHONI
3NTHACT N
n A81 -05-031
•
iurllnqton
SAMPLE ID (CUSTOMER)
SAMPLE ID (LAB)
PARAMETER
Weight
Probe
761
H
0.9750
lu
768
H
0.5720
3u
767
0.8459
lOu
766
=
0.2846
Filter
770
_ l_.ll._r;.^,,^____
"• " • -•""-
' 1 - ~-~ - — - '
2.7803
XAD
760
='•=—-"'•••'•' — -
:::-::^::.^^~-~~,:~.
- ™i^8"_" _•""•.""
130
•
FotmEED-067 4/80
•————•• — _,.
— — — ~' ''="'-"" -""••
™" ;••-———
— :.•.; --..— ~
;•• _j'i-B' a ——"
' .:...— s =„„', -,— -=
~ -j
UNITS
^^—^—~^~^^^^
qram
ftNAlYsT J- Labash
QCU™« G. Nlcoll
-------
5.3 EPA METHOD 5 PARTICIPATE EMISSIONS
5-7
-------
ISOKINET1C PERFORMANCE WORKSHEET fc PARTICIPATE CALCULATIONS
Plant xSc/r/Mc^w flh/laft Performed by #. <5
Date
Sample
Test No. /Type _ /
Barometric Pressure (1n. Hg)
Meter volume (std),
i7.« /i\Ab«.|$u
\a/u»«460/
ri/3jW«»\
''•' y*i22i yuivy) * *6° /
Volume of liquid collected (grams)
Volume of liquid at standard condition (scf)
Vlc * 0.04707
Stack gas proportion of 'water vapor
vw std . fc20
v« std 4 vm std *££> 4 ^^
Molecular weight, stack gas dry
(Ib/lb-mole)
(% C02x 0.44) + (* 02x 0.32) + (1 N2* % CO x 0.28)
( 7 x 0.44) 4 (/2 x 0.32) * ()Pb+ x 0.28)
Molecular weight, stack gas wet
(Ib/lb-mole)
Md(l-Bwo) * 18(8^), Q2£f)(^i^> * 18(££2J)
Absolute stack pressure (1n. Hg)
^tack^1"' H2°> <-/(b)
* + S18CK * , fV^-j^ + T-
^b 13.6 • QL21I * U.6
'6
v«n std
Vlc
vw std
Bwo
Md
"s
p,
a
^.%>
/fo^ .TVS
/^.y
C>-&i(
ro. osvy
P^y
p^.^7
! 1
?^r
7602/5/81/Rev 1
5-8
-------
Temperature stack gas, average (°F)
Stack velocity (fps)
85.49 (Cp)
85.49
/$avg 4 460
"fr~v
r$(«vg)
4 460
Total sample time (minutes)
Nozzle diameter, actual (Inches)
Percent isokinetic (X)
17.33 (T$ 4 460)(Yw std 4 V^ $td)
17.33
( >Qc> )( 5^.
Area of stfck (ft2) »«W3.1416
ifr?-^-144. ^(/V )2-ri-144
7 06*7
Stack gas volume at standard conditions (dscfm)
» «' - «»»"..9 », fagty (afej
60
Particulate matter concentration, dry (gr/dscf)
C2D -
15.432
15.432
C
"ltd
Emission rate of particulate matter (Ib/hr)
0.00857 «L) C. , , 0.00857 033*3. )(
s s(std)
7602/5/Bl/Rev 1
5-9
-------
TRr
I
s
102.1*3
PB
.12.
-------
ACUREX
ANALYTICAL REPORT
Sample of:
Sample
Requested By:
I.D. Number: _
Analytical Method:
Date of Analysis:
Lab I.D. Number
Component
Analytical Result
Unit
V
0,73-
Analysis py
5-11
5.S'
-------
ACUREX
ANALYTICAL REPORT
Sample
Sample
Requested By:
I.D. Number: ^.351 ^JL
Analytical Method:
Date of Analysis:
Lab I.D. Number
Component
Analytical Result
Unit
Analysis
5-12 Date—„
Form EED--082 \5/81'
-------
ACUREX
ANALYTICAL REPORT
Sample of:
Sample Date:.
Requested By:
I.D. Number:
Analytical Method:
Date of Analysis:
Lab I.D. Number
Component
Analytical Result
Unit
/.0&99S
tier
Analysis
5-13 Date.
Form EED- 062 5 5'
-------
5.4 SULFUR OXIDES EMISSIONS FROM CONTROLLED CONDENSATION SAMPLES
5-14
-------
PI ant /w(/.<
Date :r
CONTROLLED CONDENSATION SYSTEM (CCS)
LABORATORY DATA SHEET
Analyst
Sample Location .*•-#) r.
Run No. f
Date Lab Analysis Completed
Method
Titrant
Tltratlon Data
^2. Normality
Indicator
Sample
Description
Sample No.
Vol. of Sample
Vol. of Aliquot
Vol. of Titrant
Used
Average Vol. of
Titrant Used
Probe,
Nozzle
and
Filter
Rinse
?W
er
5"
/,«- XT
l(,o
i.bff
G/R
Coil
Rinse
Of 7 -T, (j f*
2 )
;«.<
«u
C5"-.
ir
f
<-
>,«5 r-
""7
/
JT
'J
32
H202
Blank
C?/ t x" & <
o l*s " £ «^-
rt / ? ti^tf?
to tf* /
e.& ^
r
C.IO O-lts O'fo
Calculations
Meter Pressure (P^)
"Hg, Meter a
48.15
PPM
S04 96 (
Factor c.-tfl dimensionless
( , MgS04)( , TM+460)
, VHK , PH) ( lj
ppm $04 =
48.15
PPM _
SO, 64 (
£ ~~
( , MgS02)( , TM*460)
, VM)l , PH) v ' ;
ppm S02 s
5-15
-------
Plant filltl;Jh di
Date 7
Date
Sample Location _£
Run No.
CONTROLLED CONDENSATION SYSTEM "(CCS)
LABORATORY DATA SHEET
Analyst
Date Lab Analysis Completed
Method
Tltrant
Tltratlon Data
_~~Normality
Indicator
Sample
Description
Sample No.
Vol. of Sample
Vol. of Aliquot
Vol. of Tltrant
Used
Average Vol. of
Tltrant Used
Probe,
Nozzle
and
Filter
Rinse
O/ 2 rr u/
Q ( S f T V
Si
.or
.or
G/R
Coll
Rinse
m 7vr
l-o
0.0*
*
Impinger
Contents
and
Rinse
W i*
3f
*r
.tf
H20
Blank
ft 3673
o.»r
e.of
3%
H20?
Blank
tlHfl
«- *r
Calculations
Vol. of Gas Sampled (VM)/£^r(_ ft3, Avg. Meter Temp (Ti«)f/.< °F.
Meter Pressure (P^) "Hg, Meter a Factor o.qfr ditnenslonless
48.15 ( , MgSOd)(
PPM *
50, 96 ( . Vu)(
_. TM4460)
i \
ppm $04 -
ppM 48.15 (_, MgS02)(_
50, 64 ( , VM)l
_, TM+460)
• ''M^ — '
ppm S02 -
5-16
-------
5.5 TRACE ELEMENT ANALYSIS
5-17
-------
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES. 93B NORTH LA SALIE STREET, CM1CAQO, ILLINOIS 90*01 • AREA CODE 31? 73*-t43«
Reply tO INSTRUMENTAL ANALYSIS DIVISION. !4MS WIST «4TH AVENUE GOICEN. COKMAOO «0'OI. PHONE JO] 37!-«JI
To: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94942
A
Date August 24, 1981
Analyst: J. Oldham
Release No. 5
P. O. No.: Subcontract SW59159A
Sample No.flai.05-031-759 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS IAD No. 97-G852-116-25
Lexington Filter Blank . ,
M CONCENTRATION IN yg/cm2
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead 0.002
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
ia£Ct-l*»-'i-
Erbium ..,. OcRECD
Hoi mi urn , „,
ACUKfcA
Dysprosium
STO - Internal Standard
NR — Not Reported
All elements not detected <
MC - Meior Component >
INT — Interference
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium < 0.001
Cerium 0.001
Lanthanum 0.001
Barium 0.03
Cesium
Iodine <0.001
Tellurium
Antimony NR
Tin
Indium STD
Cadmium
.Silver 0.005
Palladium
O.OOlug/cm2
1 Opg/cmZ
ELEMENT
Ruthenium
Molybdenum
Ni obi urn
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
CONC
<0.001
0.001
0.007
<0.001
0.008
<0.001
0.04
NR
0.002
0.007
0.002
0.004
<0.001
0.07
0.003
0.001
-~ ^M!!?
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
Z~
CONC.
0.002
0.3
<0.001
6
0.2
0.06
0.2
0.2
>8
>0.1
5
>0.3
=0.2
NR
NR
NR
0.7
<0.001
<0.001
NR
^
5-18
-------
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES 23S NORTH LA 8ALLE STREET. CHICAGO ILLINOIS 00901 AREA COOC 3<3 73S-S434
Reply tO INSTDUMINtAl ANALYSIS DIVISION >AMS WES1 44TH AVENUE GOIOIN COlOBAOO S0401 PHONE X) 27I433I
To: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94942
Release No. 5
P. o. NO.: Subcontract SW59159A
Sample No.:A81-05-031-784 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS IAO No 97-G852-115-25
Lexington XAD blank CONCENTRATE IN PPM WEIGHT
Date August 25, 1981
An"*" J' Oldham
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead 0.3
Thallium
Mercury NR
Gold
Platinum 4
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
STD — Internal Standard
NR - Not Reported
ELEMENT CONC.
Terbium
Gadolinium
Europi urn
Samarium
Neodymi urn 0. 2
Praseodymi urn 0. 3
Cerium 1
Lanthanum 2
Barium 2
Cesium
Iodine <0.1
Tellurium
Antimony NR
Tin
Indium STD
Cadmi urn
Silver
Palladium
"^tgtEiVKD
%Sl'r Oc-inu-U
ELEMENT
Ruthenium
Molybdenum
"Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromi urn
CONC.
0.9
1
0.3
0.1
0.7
NR
<0.1
4
3
13
<0.1
5
1
*3
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC
0.1
2
<0.1
15
21
2
1
0.4
12
1
7
10
=0.3
NR
NR
NR
*0.5
*<0.1
NR
ACurtu-5. *He*fepogeneous .~
All elements not detected < 0. Ippm
MC — Major Component
INT — Interference
Approved:
5-19
-------
COMMERCIAL TESTING & ENGINEERING CO.
GENERAL OFFICES 9>e NORTH LA SALLE STREET. CHICAGO. ILLINOIS «oeo> • AREA CODE in Tit-t'3*
Reply tO INSTIUMfNIAl ANALYSIS DIVISION. '4335 WfST *4lx AVINUE. GOIOIN. COLORADO eO«OI. »MONf 303.27«-95ai
T°: Mr. Roy A. Belletto jft*
Acurex Corporation Ma-*Y*?~^
485 Clyde Avenue
Mountain View, CA 94942
Release No. 5
p. o. No.: Subcontract
Sample No.: A81-05-031
Lexington Imp 1
ELEMENT CONC.
Uranium
Thorium
Bi smuth
Lead 0.008
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
5U59159A
Date August
20, 1981
Analyst: J. Oldham
-"4SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
Blank
CONCENTRATION IN vi2
=3
NR
NR
NR
0.004
0.003
NR
STD - Internal Standard
NR - Not Reported
All elements not detected< 0.00lug/ml
MC - Major Component >
INT — Interference
Approved:
5-20
-------
COMMERCIAL TESTING & ENGINEERING CO.
Reply to iNSttuwlNTM ANAITSIS DIVISION. 'O1S WIST tax AVENUE OOICIN eoiO«oo
To: Mr. Roy A. Belletto J^\\
Acurex Corporation A^fth
485 Clyde Avenue
Mountain View, CA 94942
UM' PHONE 303-171-952!
Date August
Release No. 5
P. O. No.: Subcontract SW59159A
Sample No.:A81-05-030-690 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
Lexington fuel
CONCENTRATION IN PPM WEIGHT
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead 0.2
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbi um
Thul 1 um
Erbj£CB..Vti0
Holmiunj^' ^ r
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymi um
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodi um
CONC.
<0.01
0.01
<0.01
0.05
0.02
0.06
0.6
0.5
21
<0.01
0.03
<0.01
NR
0.02
STD
0.09
<0.01
Dysprosftr»utys^ Note: Sample low
ELEMENT CONC
Ruthenium
Molybdenum
"Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromium
temperature oxygen
0.02
0.01
0.3
0.07
3
0.4
0.2
0.06
NR
0.01
0.04
3
2
0.2
0.09
12
17
0.03
25, 1981
Analyst 0- Oldham
IAD No 97-G852-116-25
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC
0.04
3
<0.01
MC
>62
22
6
57
17
2
MC
43
=0.4
NR
NR
NR
0.2
<0.01
0.07
NR
STO - Internal Stmdard
NR - Not Reported
All elementi not detected < O.Olppm
MC - Major Component >100ppm
INT — Interference
plasma ashed prior to analysis
Approved:
5-21
-------
COMMERCIAL TESTING & ENGINEERING CO.
Reply to INSIIUMENTAI ANALYSIS DIVISION. 'O3i WEST UTH AVENUE GOLDEN. COIOOADO eotti >HONE »l.J76.«Ji
To: Mr. Roy A. Belletto >^tt
Acurex Corporation ^faELc^.
485 Clyde Avenue Da,e August 25, 1981
Mountain View, CA 94942
Release No. 5 Analyst J. Oldham
P.O. No.: Subcontract SW59159A
S8mpleLeNx0i:n5?on°bo?tom7asrARK SOURCE "** SPECTROGRAPHIC ANALYSIS
CONCENTRATION IN PPM WEIGHT
ELEMENT CONC.
Uranium 0.4
Thorium 0.9
Bismuth
Lead 82
Thai 1 i urn
Mercury NR
Gold
Platinum
Indium
Osmium
Rheni urn
Tungsten 25
Tantalum
Hafnium 0.3
Lutetium <0. 1
Ytterbium 0.5
Thulium <0. 1
Erbium 0.4
Hoi mi urn 1
Dysprosium 2
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodium
WtCti
' -. r r* t ': •_
0.9
2
1
9
22
10
66
120
MC
0.7
0.5
0.3
NR
2
STD
0.8
nrr-'n
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
CONC.
13
1
7
15
MC
260
4
2
NR
0.3
7
240
61
75
3
MC
>460
52
IAD No. 97-6852-116-25
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryl 1 i urn
Lithium
Hydrogen
CONC
15
MC
1
MC
MC
110
MC
MC
MC
MC
MC
MC
=160
NR
NR
NR
280
0.2
65
NR
STD - Internal Standard
NR - Not Reported
All elementi not detected < 0. Ippm
MC — Major Component
INT - Interference
Approved:
5-22
-------
COMMERCIAL TESTING & ENGINEERING CO.
«ENCS*I. OFFICES: 111 MOUTH LA SALIC STUEET. CHICAGO ILLINOIS I0«0> • ABE* CODE 312 72f-S«34
Reply to INSTIUMINIAI ANAIVSIS DIVISION. 14319 west HTM AVENUE. GOICEN. COIOBAOO sum. PHONE Mi-37>-9S2i
T0: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94942
Date. August 25, 1981
Release No. 5
P. o. NO.: Subcontract SW59159A
Ssmple No.: A81-05-031-761SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
Lexington Probe Wash CONCENTRAT|ON |N PPM WEIGHT
Analyst J. Oldharn
IAD No 97-G852-116-25
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmi urn
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
CONC.
<0.9
1
0.1
240
31
NR
4
<1
0.8
0.3
1
0.4
1
2
6
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodi urn
CONC.
1
4
3
12
14
27
170
140
MC
0.9
2
NR
5
STD
10
24
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobal t
Iron
Manganese
Chromium
CONC.
15
2
8
19
930
110
11
7
NR
1
4
MC
78
120
10
MC
MC
120
rttCtlV'tiD
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC
25
MC
0.8
MC
MC
MC
MC
MC
MC
MC
MC
MC
MC
NR
NR
NR
310
<0.1
1
NR
STD — Internal Standard
NR - Not Reported
All elementi not detected < 0.
MC — Major Component \ Ifinn
INT - Interference ' ~°
•Jt.i- 0 >j RECTj
Approved:
5-23
-------
Reply tO
COMMERCIAL TESTING & ENGINEERING CO.
aCNCKAL OFFICES 33« MOUTH I* SALLE STBEET. CHICAGO ILLINOIS «O«OI • A«EA CODE 313 73»-«4J4
INiWUMtNTAl ANALYSIS DIVISION '4335 WIST 44tH AVINUE. GOICIN. COIO»AOO 80401 PHONE 303-27«.«52I
To: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94942
Date August 25, 1981
Analyst- J. Old ham
Release No. 5
p. O. NO.: Subcontract SW59159A
Sample No.:A81-05-031-766 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS IAD No- 97-G852-116-25
Lexington 10p + 3V CONCENTBAT.ON IN PPM WEIGHT
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Luteti urn
Ytterbium
Thul i urn
Erbium
Holmium
Dysprosium
CONC.
<0.6
1
0.6
170
0.6
NR
89
3
0.4
2
0.3
2
3
4
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodi urn
IrtKCfc
- i. 'r a
CONC.
2
5
2
19
25
21
240
240
MC
1
3
0.7
NR
8
STD
17
17
... ,.
1 W MV 1
h PIC'D
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttri urn
Strontium
Rubidium
Bromine
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
~,_ Chromium
••»
CONC.
20
2
15
40
MC
520
21
28
NR
2
7
MC
170
300
17
MC
>920
100
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC
9
MC
-------
COMMERCIAL TESTING & ENGINEERING CO.
orriecs lit NORTH LASALLE STUEET. CHICAGO ILLINOIS «oeo< A»EA coo£ ju 7j«.«434
Reply to INSTRUMENTAL ANAIVSIS DIVISION. >aii WEST 44TM AVENUE GOIBEN COIOIAOO «o«oi PHONE jo*37«.»sji
To: Mr. Roy A. Belletto £*\ \
Acurex Corporation ArLh.i-'i
485 Clyde Avenue " " Date August 25, 1981
Mountain View, CA 94942
Release No. 5 ' An"*sf J' Oldham
P. O. No.: Subcontract SW59159A
Sample No.:A81-05-031-768 CPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS
Lexington 1 w + filter ?
CONCENTRATION IN ug/cm*
ELEMENT
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Hoi mi urn
Dysprosium
STO — Internal
CONC.
<0. 001
<0.001
<0. 001
0.5
NR
0.04
<0.001
<0.001
<0.001
<0. 001
<0.001
<0.001
<0. 001
<0.001
Standard
ELEMENT
Terbium
Gadolinium
Europium
Samarium
Neodymium
Praseodymium
Cerium
Lanthanum
Barium
Cesium
Iodine
Tellurium
Antimony
Tin
Indium
Cadmium
Silver
Palladium
Rhodium
Irtfcd
CONC.
<0.001
<0.001
<0.001
0.001
0.003
0.001
0.01
0.01
2
<0.001
0.001
<0. 001
NR
0.002
STD
0.002
0.01
= iVfc.C
i d RK'O
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
j Chromium
CONC
0.006
0.003
0.007
0.002
0.1
0.1
0.02
0.001
NR
0.001
0.002
1
0.03
0.03
0.002
0.2
>0.3
0.01
IAD NO 97-G852-116-25
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Nitrogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
CONC
0.002
0.1
<0.001
MC
>0.3
3
>0.2
>0.8
>2
>0.02
>2
>0.06
=0.6
NR
NR
NR
0.5
0.003
NR
-•»
MC — Major Component
INT — Interference
>10Ug/Cm
Approved:
KK
5-25
-------
Reply to
COMMERCIAL TESTING & ENGINEERING CO.
SENEOAl OFFICES 991 NORTH lA »AtLE 5TBEET. CHICAGO ILLINOIS >0«0< • AHEA CODE 313 7J«-«494
INSIIUWiNIAl ANALYSIS DIVISION. "43)5 WEST «4tN AVENUE OOICEN COIO»OO 10401. PHONE 30J.J7I.9SJ1
To: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue " " o»te. August 25, 1981
Mountain View, CA 94942
Release No. 5 AnalYsf' J- Oldham
P. o. No.: Subcontract SW59159A
Sample No.:A81-05-031-760 SPARK SOURCE MASS SPECTROGRAPHIC ANALYSIS IAD N° 97-G852-116-25
Lexington XAD
CONCENTRATION IN PPM WEIGHT
ELEMENT CONC.
Uranium
Thorium
Bismuth
Lead
Thallium
Mercury NR
Gold
Platinum 0.3
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lutetium
Ytterbium
Thulium
Erbium
Holmium
Dysprosium
STD — Internal Standard
NR - Not Reported
ELEMENT CONC.
Terbium
Gadolinium
Europi urn
Samar i urn
Neodymi urn
Praseodymi urn
Cerium
Lanthanum
Barium 0.8
Cesium
Iodine <0.1
Tellurium
Antimony NR
Tin
Indium STD
Cadmi urn
Silver
Palladium
SfglfetelVED
vj ObRffi'D
n , ACUKRi
ELEMENT
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
CONC.
0.4
2
0.1
0.3
NR
<0.1
2
5
48
<0.1
18
0.4
*4
ji /
ELEMENT
Vanadium
Titanium
Scandium
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryllium
Lithium
Hydrogen
^fetaf'ogeneous
CONC
<0.1
<0.9
<0.1
76
93
34
*6
*3
57
2
3
4
=0.7
NR
NR
NR
0.3
*0.1
NR
All elements not detected < 0.1
MC — Major Component Q
INT — Interference
Approved:
5-26
-------
COMMERCIAL TESTING 8. ENGINEERING CO.
-SZSXS.-SZ•s»s.=^rt^s-sr =sr
TO: Mr. Roy A. Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94942
Release No. 5
p. o. No.: Subcontract SW59159A
Sample No.: A81-05-031-762SPARK SOURCE AAASS SPECTROGRAPHIC
Lexington Imp 1 CONCENTRATION IN
ANALYSIS
Date August 25, 1981
Analyst J. Oldham
IAD No 97-G852-116-25
Uranium
Thorium
Bi smuth
Lead 0.01
Thallium
Mercury NR
Gold
Platinum
Iridium
Osmium
Rhenium
Tungsten
Tantalum
Hafnium
Lute ti urn
Ytterbium
Thulium
Erbium
Hoi mi urn
Dvsorosium
ELEMENT CONC.
Terbium
Gadolinium
Europium
Samarium
Neodymi urn
Praseodymi urn
Cerium
Lanthanum
Barium O-01
Cesium <°-°01
Iodine 0.003
Tellurium 0.004
Antimony NR
Tin O-03
Indium STD
Cadmi urn
Silver 0.002
Palladium
Rhodi urn
Ruthenium
Molybdenum
Niobium
Zirconium
Yttrium
Strontium
Rubidium
Bromi ne
Selenium
Arsenic
Germanium
Gallium
Zinc
Copper
Nickel
Cobalt
Iron
Manganese
Chromi urn
i3
CONC
0.01
0.002
0.003
0.002
0.003
0.01
<0.03
NR
0.02
0.8
0.2
0.2
<0.001
0.2
0.05
0.03
ELEMENT
Vanadium
Titanium
Scandi urn
Calcium
Potassium
Chlorine
Sulfur
Phosphorus
Silicon
Aluminum
Magnesium
Sodium
Fluorine
Oxygen
Ni trogen
Carbon
Boron
Beryl 1 i urn
Lithium
Hydrogen
CONC.
0.002
0.04
0.4
0.6
0.3
>8
0.02
0.2
0.03
0.06
>3
=0.1
NR
NR
NR
0.001
<0.001
NR
STD - Internal Standard
NR - Net Reported
MC - Major Component
INT - Interference
0 b RBCD
0.001yO/mlr\CUKI=A Approved:
>10ljg/ml
5-27
-------
5.6 Cj TO C6 HYDROCARBONS BY GAS CHROMATOGRAPHY
5-28
-------
TO C6 6C SUMMARY
Run
No.
1
1
1
2
2
2
2
3
3
3
Bulb
I.D.
A
A
B
A
B
A
B
A
B
A
Sample
Time
1225
1225
1235
1402
1408
1402
1408
1630
1640
1630
Approximate
Bulb
Temperature
(°F)
518
518
518
520
520
520
520
517
508
517
Recorder/
Print -Out
Reference
No.
10
11
13
14
15
16
il
19
20
21
Cl
3.1
4.8
4.1
NO
NO
NO
ND
1.9
2.1
2.0
C2
0.6
2.0
2.0
ND
ND
ND
ND
ND
ND
ND
C3
2.3
ND
2.0
1.8
1.6
1.6
1.8
1.0
1.0
1.5
C4
1.2
ND
0.8
ND
ND
ND
ND
ND
ND
ND
C5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
C6
—
—
—
—
—
—
—
—
—
—
5-29
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /.,«?>..Mi,,rrv^-. iQ.^.» Job No. iTf
Injection Date ^--jy* >> , Time i^i-^y.t?. , Instrument I
Recorder/Printout Reference No. (^ _ , Recorder ID
Purpose Of Run fr.r r.r.5^\'.
O r ;="
Sample Description C c^r. rfv T
/
•*^ ' r"\ * _,
M-
Amount Injected • j ^.,
GC CONDITIONS
, Inj. Port or Sample Loop Used ,^.^, _ff.,^
Detector Used: FID x . ECD , FPD , TCD (Current )
Y , Amplifier or Range /c."~"
, Solid Phase Pr ^
Detector Attenuation
Column: Liquid Phase
Length (n ' , O.D. _^
Temperature: Injector | %o **<-* . Oven _^_o__ °C-, Detector :< .777 j:
Temperature Program \^
, I.D.
, Material
SAMPLE RUN
Sampling Method is-'
RT
/•^/'•^
c-.r^
Area
V& it "20
Peak Height
Amount (PJXV)
'.CH-
Component
^V^ — v^ T_
i
Name of Operator v/-*->.; j
_, Date ;£?- j 19^;
5-30
-------
1.4$
ice?
STOP
en Z
IP
r
o
O OH O
m > m o
ww-{i-o»a,-
CB o rn \< ^ SB to
=> g O Q. g ••• ^
: 5 " 2 S I
i ? « p^yj i
jp;
i 2
^. o
3*: w
o-
•n-
Pi
-D
3 0 =
i>
± n» * o o : 2 ; L^
• =f° i ? i if
3 :
E- O O:
? O O :
RUN I 6
ID 1
HO ML IE PEAKS FOUND
APR/28/81 19=38-43
AREA*
RT
9 21
9 58
3.41
AREA TYPE
12933 D BP
481489 D PB
3444 BB
144419 BB
ARtfT
9.981
9 98?
9 373
3.914
74 9"
9 536
TOTAL AREA=
KUL FACTOR= 1.98e9E+96
5-31
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client c./» f~ A * Location//g^/^^trvO.AJ.CJ. Job No.
Injection Date v|-2fr-fr\ , Time or-.ftV. 12.» Instrument
Recorder/Printout Reference No. ^ , Recorder ID
Purpose of Run 1
,vvr
Sample Description
GC CONDITIONS
Amount Injected J^.>M , Inj. Port or Sample Loop Used 2,Mi
Detector Used: FID X « ECD 9 FPD , TCD (Current
Detector Attenuation y , Amplifier or Range /£-'*
Column: Liquid Phase
Length k '
_, Solid Phase .
^
, O.D. y.20
Area
^iTi^O
Peak Height
Amount (ppr^
io&
Component
>^\ - O-r
1
Name of Operator ^ c- tt>o rVc. u.v
_, Date ; r -a i 19 •/.
5-32
-------
rtl Wr
7 ec
STOP
RUN I 7
ID t
HO CM. IB PEAKS FOUND
AREA*
RT
e 22
8.4?
I 46
3.42
4.ee
7. se
AREA TYPE
26C9 D BP
33716 0 PB
22487 PB
U45f BV
951639 VB
5561 BV
AR/HT
e 43)
e 917
B.269
3 ?6<
2 189
1.115
9£ «?9
e.53"1
5-33
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /
.c. » Oob No. -;-? ^
Injection Date
Recorder/Printout Reference No.
Purpose of Run c»*nl> g.:
, Time j?r-. •g.r'.frCe- . Instrument ID rc
% _ , Recorder ID
( -g.xj'.T-.'A.. \
Sample Description ^. .
C . — C. . t A-i •
.\ ••? ^r\ — c.."-*v\ <=> .
GC CONDITIONS
Amount Injected ^,V\L_ » Inj. Port or Sample Loop Used ^_
Detector Used: FID y , ECD , FPD , TCD (Current
Detector Attenuation y , Amplifier or Range /Q'
Column: Liquid Phase
Length k '
, Solid Phase ?~ e.«\ ;>.>«..<. Q
& O.D.
Temperature: Injector
Temperature Program
]/," > I.D.
, Material >
° e» Oven / 40 ° o> Detector
SAMPLE RUN
Sampling Method
RT
Area
Peak Height
Amount
Component
• ST.
J1
1ST. 2.
T- ' •
Name of Operator
.» Date
5-34
-------
1 ! V
12 46
Zt'to
a 41
STOP
RUN « 8
ID 1
NO CALIB PEAKS FOUND
OPR'JS/Sl
AREflX
RT
e ?7
8 59
1 46
4 19
7 '3
7.98
IS 48
AREA 1YPE
41484 D BP
71398 0 PB
124178 PB
145156 VB
5714 W
1867(8
AR/H1
B 886
8.88?
8.177
8 438
8.343
8 43$
1.287
IS 37T
El 538
as is?
e 9<>8
I 4M
31.389
TOTAL AREA° 576979
MJL FACTOR^ i eeeet+ee
5-35
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
.? A- > Location
. Job No. ~? l ^> L\
Injection Date V-2.V-fr( , Time i i: oS';5"i . Instrument 1
Recorder/Printout Reference No. °\ , Recorder ID
Purpose of Run c &i\ ft
-3-?u/r. i»i\
Sample Description S
M_^
oc-rrv
HiH^.^_^.^Bl
T.
GC CONDITIONS
, Inj. Port or Sample Loop Used ,*.CK_ ^
Length (ne O.D. V»" I.D. , Material >s
Temperature: Injector 1^
Temperature Program T^n Trr ^"«»»3
1>tffi
i iSJTto
i '-*• i(e>» 0
11*^,1 0
Peak Height
Amount (fp,v)
(5", t
, >.u
1 <>~.(e'
*5,L
*5"'(»
Component
c.,
c,.
C-?
c>
^r
Name of Operator
, Date
• 2. i
19
5-36
-------
S v>
PI J* ^^
HX-05»2WO
3«8XSi&^€8
2f
= 5
2 O
O O
STOP
RUN I 9
ID 1
NO CAL1B PEAKS FOUND
ftPR/2S/8t 31-
• 5?
AREAt
RT
6.24
e 57
1.43
4.1£
7 88
13.45
14.8(1
22.7*
AREA TYPE
45613 BV
74852 VV
123546
142OG
16838
176641*
742
1328
AR'HT
8.977
0 867
8 16*
8.424
8 867
1.211
8.177
8 286
AREA;:
7.845
I? 8"1?
El 248
24 51?
?.?57
3« 38?
0 128
8 227
T01AI AREA- 581488
NUL FACTOR* 1.8ee8E+88
5-37
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client ^-n^'
, Location icf,,\/>^r~J
No. "> / 'iC,
Injection Date q -i-j-^
Recorder/Printout Reference No. 10
. Time i2\>l: ^^ . Instrument
, Recorder ID n-^j'S v A.
Purpose of Run c. -C- /4 vD-^riiy.^^.
..-.-..
Sample Description
NT-c /
GC CONDITIONS
Amount Injected ^ .-_\ . Inj. Port or Sample Loop Used
Detector Used: FID x . BCD _ , FPD _ , TCD _ (Current
Detector Attenuation ±> _ , Amplifier or Range {•-
Column: Liquid Phase _ , Solid Phase f>,
Length fe ' O.D. V* " I.D. _ , Material ^.
Temperature: Injector / -2 p °o , Oven /-?/-. Oc. , Detector ) r:
Temperature Program T>>?
SAMPLE RUN
Sampling Method G.-ZT
RT
* ^N \Gf
'^
* t
* ' •* *
x? ?> r*
_* «Xv
•7.X?
Area
% 'l>(*
^•.•5"
M *t
O.to
^.5
/.2.
—
Component
*.—
C. -.
>
{-m ••^f,
1
c. CN^T^«*- \* A>-^r •«* "T"
Name of Operator .T-.
» Date it'--;, 19 V,
5-38
-------
5-39
RUN 1 18
ID 1
ESTD
RT
8.19
8 86-
8 49.
8 K '
1 .32
T56
8.83
3 86
7.88
14.96
15 13
15 36
IS 56
13 98
16 81
16 42
16.68
16 96
17.81
17.43
17 68
17 84
18.89
18.34
18. S^
84 5£
84 75
TOTAL «REA=
HUL FACTOR=
APR/89'
hFia TYPE CALI
1385 BV
8856 VV 1R
2615 V8
11418 BB
858 PV
4885 VP
5518 PP
1458 PV
748898 W
832 PV
1183 VP
t64 PV
i419 W
1386 VV
1216 W
188? VV
1892 W
1381 VV
1875 W
1174 VV
1374 W
117R VV
1447 PV
1887 W
861 PV
981 VP
1896 PP
799848
1 8888E-»ee
1? S7-19
AMOUNT
0 M«
« eee
e.eee
9. em
fl.ees
A eee
e eee
e.we
e eee
P 808
I? CPP
A »ep
a e«e
8 888
8 eee
8 88«
8 888
8 888
8 098
8 eee
fl 888
fl 880
P 808
fl 98"
8 808
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
.c» Job No.
Injection Date vt-3«y-fr\ , Time \"J>\>C-\ g"7 • Instrument ID
Recorder/Printout Reference No. yy , Recorder ID
Purpose of Run C^.-C, M
Sample Description
v^ .<-_
GC CONDITIONS
Amount Injected a ML. • Inj. Port or Sample Loop Used 2r»i.
Detector Used: FID X » ECD _ , FPD _ , TCD _ (Current
Detector Attenuation g _ , Amplifier or Range )p"t(
Column: Liquid Phase
Length k'
, Solid Phase
0.0. Vx" 1.0.
Material
Temperature: Injector /2o C^t Oven 13 n C » Detector \.<>o
Temperature Program rr^o
SAMPLE RUN
Sampling Method
RT
. ^ ; —
«^x'
"/ . '•/
Area
>± •?*
>c-cn
1 1 ^-VKT ?
Peak Height
Amount (t»p^4
^t.^
2.0
—
Component
•%. ;
Cy_
_-^T^-v' •-' "•-' "
Name of Operator
., Date
199:/
5-40
-------
ZEPC'
trv>
M'B3
STOP
(A
wSwwHiTja}
o^
«F_£
o o
&1
w!
Pi
ioi
?L fi Ii
d> ri • : : **.»
r «; i ?r?
o W
o LP
F; Fo'o3! ;
RUN I
ID 1
ESTD
RT
8.25
8 68
7.88
APR/29'51 13 38 57
AREA TYPE CAll AHOUNT
18758 PB 1R 5 8823M8
18859 P8 a.888
BB A 888
TOTAL AREA= 799478
Ma FACTOR^ 1.8888E488
5-41
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
d.c^. Job No. -?13S'.'Z\
Injection Date ^-
Recorder/Printout Reference No.
Purpose of Run CL. -C,
. Time iv.cT. gz , Instrument ID
\3 _ * Recorder ID
Sample Description
GC CONDITIONS
Amount Injected a. /v»t_ » Inj. Port or Sample Loop Used
Detector Used: FID X . ECD , FPD , TCD (Current
Detector Attenuation g , Amplifier or Range )£>*t(
Column: Liquid Phase , Solid PhasePoftA.ft*M<.
Length
O.D.
" 1.0.
, Material
_
Temperature: Injector /2o °<^i Oven ,3 p °c » Detector jJS"Q
Temperature Program
TH e:/g.r^ cv L
SAMPLE RUN
Sampling Method
RT
• AT
• s.
. S":i
1 to~t
1 • ">^
2. £^~
1'-
Area
it '!T ,
**' " ' ''^ i
Ic^'S^i
•>
-------
TOTAL AREA- 401620
ML FACTOR- i 88eeE+ee
1224
o o
RUM i 13
ID 1
APR/eS/81 M 97-53
ESTD
RT AREA TYPE CALI
8.59 W88 W a 4
TOTAL AREA*
mJL FACTOR^ ,
M99
Run t
10 1
AREA*
RT
8 21
8.27
8 51
8.59
8 69
1 53
2 25
7.91
12 24
IS. 43
13
APR/29/81 14 87-53
AREA TYPE
1253 PV
18741 VB
3031
6288
18439
2988
4748
792148
2489
2185 PV
AR/HT
8.835
8 865
8.856
6 856
8 136
8 188
e'?86
8 224
8 389
ARFA*
A tS8
1.385
8.363
8.743
1.24«
8.347
9 ?67
94.74S
9.SC8
8.261
TOTAL AREA= 836958
HUL FACTOR' 1 8888E*88
5-43
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
_, Location
.o» Job No. -7T3S'.'2V
Injection Date M-
, Time i••»-;;i•.5^ » Instrument ID
i H- » Recorder ID
Recorder/Printout Reference No. \ s-
Purpose of Run C^.~(L, Mvt->c>,oi*g.RmO
Sample Description
GC CONDITIONS
. Inj. Port or Sample Loop Used
Amount Injected
Detector Used: FID X , ECD , FPD , TCD (Current _
Detector Attenuation g , Amplifier or Range Jp"t(
Column: Liquid Phase .
Length (p*
» Solid Phase
O.D.
I.D.
Temperature: Injector /go c>. Oven
Temperature Program
_, Material
, Detector
Sampling Method
SAMPLE RUN
*?r>ot^.L (>^
RT
Area
Peak Height
Amount
Component
Name of Operator
_, Date
5-44
-------
^ g: =. i
3 : : SJ : : :
s. A A • : . r
? 00: : : :
[ins
STOP
RUN « 14
HO CftLlB PEflKS FOUHD
ftPR/29/81
RT
6 29
8.63
ftREfl TYPE ORfHT
2884 PV 8 852
S179 PB
8.122
t« 583
81.49-
11263
5-45
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client <
, Location
.c» Job No.
Injection Date 4-
.fr\ . Time
Recorder/Printout Reference No.
Purpose of Run C^. -C, M
'. >c t Instrument ID
, Recorder ID
Sample Description
Mr
Amount Injected
GC CONDITIONS
_..v ^ ,,.^ . Inj. Port or Sample Loop Used grv>L Loof*
Detector Used: FID X . ECD , FPD , TCD (Current )
Detector Attenuation g , Amplifier or Range )p~{(
Column: Liquid Phase , Solid PhasePfrft^ppv
Length (p* , O.D. Vx" t I.D. , Material
Temperature: Injector ^20 °ct Oven ta0 PC, , Detector
Temperature Program _
Sampling Method
SAMPLE RUN
L. ( 5*p^
if*
Component
^» /*
Name of Operator
_, Date
5-46
-------
o
fTI
CO
2 w c/> H x -o ..
i- ?§ 2 813 2 £ :?•§ g 2 *
g£«<"§-Sma> S £ 3
O
>
so
o
§ 2 3
-toi i§?3
' • m ZJ t«
O
.
5 5"
PW1I
O
r
1.-32
STOP
RUN I 15
ID 1
NO CflLIS PEAKS FOUND
!5<92-38
RT
8.19
9 67
ARCA TYPE AR/HT
99 PB 8.88«
8936 PB 8.115
1.2P
98.783
TOTAL ftREA= 8135
NUL FACTOR= 1.88886+88
5-47
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location
.c. Job No.
Injection Date ^-.3«\-&-t . Time
Recorder/Printout Reference No.
Purpose of Run CL. -(Lt
,-i'-;o , Instrument ID
, Recorder ID
Sample Description
A.
GC CONDITIONS
Amount Injected a. ML. » Inj. Port or Sample Loop Used g,^ ^
Detector Used: FID X , ECD , FPD , TCD (Current
Detector Attenuation g , Amplifier or Range )o~t(
Column: Liquid Phase , Solid PhaseP0R<>,f>ps'
Length (p1 O.D. Vx" I.D. , Material
Temperature: Injector ^20 Oo, Oven t^n °c, Detector _
Temperature Program JTAD
SAMPLE RUN
Sampling Method
RT
» i»V
Area
fa " ^
Peak Height
Amount (^ p^
;.t
Component
f ""' -••*
Name of Operator
_, Date
19/
5-48
-------
n i w
STOP
RUN I 1€
ID 1
HO CAL1B PEAKS FOUND
APR'29/81
asm
RT
e i?
e ee
AREft TYPE
943 PB
8176 PB
6K13 PB
AR'HT
6.M2
e us
e.eee
AREA*
l.?69
IP.9??
TOTAL AREA=
MJL FACTOR=
7433?
5-49
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /.g«'nae.-nnJ.»l.C>. Job No.
Injection Date v+..3«\-y\» Time ;g. -;•..-.'--ji>""» Instrument ID
Recorder/Printout Reference No. i? , Recorder ID
Purpose of Run CL.-CL, M
Sample Description ^.y.y
M.~ ?„ eve.-?
GC CONDITIONS
Amount Injected a ^u » Inj. Port or Sample Loop Used
Detector Used: FID X . ECD _ , FPD _ , TCD _ (Current
Detector Attenuation g _ , Amplifier or Range jp
Column: Liquid Phase _ , Solid Phase
Length (p' O.D. % "
Temperature: Injector /go
Temperature Program
1.0.
Oven
, Material £..$.
°c » Detector
SAMPLE RUN
Sampling Method
RT
.t?
Area
Tcr^
Peak Height
Amount (t»p^
/.sr
Component
L^, -->
«_->
Name of Operator vTr>»H>j
, Date
19
5-50
-------
RUN I 1?
ID 1
NO :M.1B PEAKS FOUND
APR/29'81 15=43-85
RT
8.68
AREA TYPE
985(1 D PB
AR/HT
8.143
TOTAL AREA* 9858
WJL FACTOR i.eeeee+ee
5-51
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /.g«JMe.-r*ij.»l.c. Job No.
Injection Date y-ss-sa . Time rr. cv.s"P , Instrument ID
Recorder/Printout Reference No. »n _ , Recorder ID
Purpose of Run C-<1
Sample Description
Amount Injected &.
GC CONDITIONS
. Port or Sample Loop Used
Coop*
Detector Used: FID X » ECO _ , FPD _ , TCD _ (Current
Detector Attenuation g _ , Amplifier or Range )p->(
Column: Liquid Phase _ , Solid Phase PoRftf>M<. (TV
Length (px O.D. V* " I.D. _ , Material £.5
Temperature: Injector /go c*» Oven 13P C» Detector As"D
Temperature Program
Sampling Method
SAMPLE RUN
L (5*n
RT
r-\'( ^
• ^H-
• (^1
Area
•fVl ^T-
niu-
Peak Height
Amount ft»pr^
i.1
uo
Component
1**-"»
C. •;
Name of Operator
., Date
19
5-52
-------
PU . ft 4(
IS'78
RUN t 19
ID 1
APR/E9/81 17'84<53
ESTD
RT AREA TYPE CALI MW'WT
8.24 4994 re 1R 2.8677E+88
TOTflL AREfl*
KUL FACTOR^ I.
4?94
RUN I
ID .1
Nfttt
RT
9.24
6.69
19
APR/29/81 17-84-5
AREA TYPE
4994 PB
5376 PB
AR/HT
0.188
8 139
AREA.1!
48.158
51.842
TOTAL AREA= 18378
HDL FACTOR' 1.8888E+88
5-53
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /.g«iioe--n>u.»J.c. Job No.
Injection Date -
Recorder/Printout Reference No.
Purpose of Run gv -C.i_ H
, Time ', ;•. .'.>'•.>:•- , Instrument ID
.^ _ , Recorder ID
Sample Description
; ^-j-r-
GC CONDITIONS
Amount Injected a. ML. • Inj. Port or Sample Loop Used
Detector Used: FID JC_, ECD _ , FPD _ , TCD _ (Current
Detector Attenuation g _ f Amplifier or Range )p"t(
Column: Liquid Phase _ , Solid Phase Pft
Len9tn <*' O.D. y*"
loo/*
y*" I.D
Temperature: Injector 120 °C». Oven
Temperature Program
, Material £..$.
°C . Detector
Sampling Method
SAMPLE RUN
^L, (.T>'l
RT
Area
Peak Height
Amount
Component
Name of Operator
_, Date
19S:/
5-54
-------
N HI
STOP
RUN I ZB
ID 1
NO CftUB PEflKS FOUND
AREAV.
RT
B 36
8 68
AREA TYPE
S61B 68
4881 PB
AR/HT
8 185
« 183
5; 483
4f. 517
TOTAL «REA=
KJL FACTOR^
194?3
5-55
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client
, Location /.g»;M...-.->*!>l.o» Job No. ~n Z~.
Injection Date v^-p^-y- , Time : 1;v>1 V?" , Instrument ID ~-,!?o*v^
Recorder/Printout Reference No.
Purpose of Run _ c,. - C: H> fc a/
, Recorder ID
Sample Description
GC CONDITIONS
, Inj. Port or Sample Loop Used
Amount Injected
Detector Used: FID X , ECD , FPD , TCD (Current m
Detector Attenuation g , Amplifier or Range ,/->•*
Column: Liquid Phase
Length p'
_, Solid Phase
, O.D. %
, I.D.
_, Material
Temperature: Injector /2.z <-*, Oven ,xc C » Detector ^^"o j~.
Temperature Program T^O Tntr,-;
SAMPLE RUN
Sampling Method
RT
•x^
. U1!
Area
5*2 u-i.
1^19-'
Peak Height
Amount (t>prv4
^.0
),r
Component
/>
^,x
y-
Name of Operator
, Date
19
5-56
-------
2X.K' 5
.«
\-
is! ! P* ! f If! %v
3 i
ST
RUN I 21
ID 1
OPR/29/8I !?-45'45
ESTD
Rl AREA TYPE Cflll
624 532Z B8 1R
««OdHT
TOTftL flREfl= 5322
KUL FOCTOR= i eeeeE+ee
RUN I 21
ID 1
APR/29/81
AREA?
RT AREA TYPE AR/KT AREA*
B 24 5322 BB 8.11? 49.^S£
t'.6$ 7818 BB e.144 59.49«
TOTAL ftREA-
ML FACTOR=
13148
5-57
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client c«\rzt\ _ , Location /<•....
;.C.» Job No. \ i "j.^
Injection Date V--^i^7 , Time ±
Recorder/Printout Reference No. _
Purpose of Run g.Ai.'iegAT'rTTO
:_?£•• , Instrument
, Recorder ID ftp'!'5'^ »\
Sample Description
C. -C, (..v-7>,
y i
J^ a. g ,v->._
GC CONDITIONS
, Inj. Port or Sample Loop Used 7,
Detector Used: FID A . ECD _ , FPD _ , TCD _ (Current _ )
Detector Attenuation §" _ , Amplifier or Range /? -" _
Column: Liquid Phase _ , Solid Phase P^R^E. y...^ '. .
Length ^,x , O.D. Y? " . I.D. _ , Material >^
Temperature: Injector rin °<^. Oven / 2 o °o» Detector ^57?) j:
Temperature Program -r c,c.-r ri€g ^-\ A v—
SAMPLE RUN
Sampling Method
C.
C u c
-. 20
Name of Operator v I /•• ^-,0 'H-C- u ^\
_, Date
-------
1 I 4'.
IIKMt
STOP
RUN I 2Z
ID 1
ES10
RT
8.58
t 45
-t.ae
flPR/ES/81 1B'?4 38
(WEfl TYPE COll ftWUHT
68114 0 PB 2 4.86?7E+8«
116868 PB 3 1.44!3E»ie
138758 BB 4 3 8139E+18
TOTflL «REfl= 322938
NUL FACTOR^ 1 9«e8£->88
5-59
-------
GAS CHROMATOGRAPH OPERATING CONDITIONS AND FIELD LOG
Client c,v)CTA . Location j.^,^..-.0*0. K?.<_-. Job No. "n~5",?.i
Injection Date
Recorder/Printout Reference No.
Purpose of Run CAi..f^£A7l-vQ
v I A.£>
, Time jsx'.iv. gT) , Instrument ID •?. r
^i _ , Recorder ID
Sample Description ^L-.OTTV T. r-v?or\.-cr\A-\f>gjJiLVT
^^^™™ "^•^^^"— •"^"™^^™— ^"^""^ •" * ^~~^^™ "™^^^^^~~"^
C> , — C. /. L.,A_ * *
. Nj A
-V ' p
> V - \ O" D
Amount Injected :,^ .v^
GC CONDITIONS
, Inj. Port or Sample Loop Used .-?..,!,
Detector Used: FID x , ECD _ , FPD _ , TCD _ (Current
Detector Attenuation _ ^ _ , Amplifier or Range , >
Column: Liquid Phase _
Length k '
(o ' O.D. '/c''
Temperature: Injector / ^p
Temperature Program .fig-rv
, Oven ,^c C« Detector
)
, Solid Phase pTa*i>fv<.<, C »
, I.D. , Material Si.
°o
SAMPLE RUN
Sampling Method U )
RT
Area
Peak Height
Amount
Component
o.-z
i 5". i
C-.
Name of Operator CT7
.» Date r ,-2 IL 19 y\
5-60
-------
S10P
RUN I 23
ID 1
ES1gT AREA TYPE
g 59 68146 PB
1 46 H5638 PB
flPR/29/81 18=
.
I '4353E+18
TOTftL ftREfl=
nut F«cm= > .
RUN 1 23
ID 1
AREA*
RT
8 59
1 46
4.21
AREA
39514
6814K
115636
13891*
flP
ttPE
BB
PB
PB
1 PB
R/W81
AR'HT
8.871
8 865
8 166
8 427
flPR/?9/81 182459
.
3R. 352
TOTflL *REA=
KU.
342289
5-61
-------
5 7 TOTAL CHROMOTOGRAPHABLE .ORGANICS (TCO), GRAVIMETRIC ORGANICS (GRAV),
IR SPECTRA, AND GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
5-62
-------
en
CT>
CO
LACUREX
_ t Corporation
ANALYSIS LABORATORIES
DATA REPORTING FORM
CUSl
CUS1
flESt
AD
SAMPLE 10 (CUSTOMER)
SAMPLE tO (UA«)
PARAMETER
WAV Aliquot
GRAV (BUnk)
GRAY
TCO Aliquot
TOO (BUnk)
TCO
Mercury Aliquot
Mercury (Blink)
Mercury
Antimony Aliquot
Antlnony
Arsenic Aliquot
Arsenic
rOMER
roMER con
ILTS REPOF
rTRACTNO
IT Trt L»
307736.22
WaterUnd
ACUREX C<
TELEPHONI
3NTRACT N
P
^ A81 -05-031
Burlington 28.78 dscm
Probe
761
H
<4
<4
<0.2
<1
<1
< 0.00003
—
—
—
lOu + 3u
766
^H
<4
<0.2
•
m
< 1
< 1
< 0.00004
m
^
m
lu+F11tet
768
6
<4
0.4
^
m
m
<}
< 1
< 0.00005
„
„
m
m
XAD
760
H
7
<4
0.3
(120) 1.7*
(120) 1.4*
<0.01
< 1
-------
IR REPORT
SAMPLE:
Burlington Probe
Commona
No Peaks
5-64
-------
IR REPORT
•AMPLE- 766 Burlington lOu & 3u
tm»mity
No Peaks
5-65
-------
m
768 Burlington lu S Filter
lm»r»ity
A*iignm«nt
ComiTMnti
2900
OH Alkane
5-66
-------
1AMPLE: 759 Burlington Filter Blank
(••')
No Peaks
5-67
-------
ft REPORT
IAMPL1: 760 Burlington XAD
HOT* NWOTX
- \m\
2900
2820
•
tnttrwty
S
S
•
Anigrm«nt Cemmwiti
C-H Alkane
C-H Alkane
•
*
•
• * •
.
I
.
5-68
-------
IK
SAMPLE: 78° Burlington OMC
brantity
Anignrrwnt
Commantt
No Peaks
5-69
-------
C7I
ACUREX
Corporation
ANALYSIS LABORATORIES
CUSTOMER
DATA REPORTING FORM
CMEA
DATE July 31. 1981
CUSTOMER CONTRACT NO. 307736.22
RESULTS REPORT TO L. Water land
ADDRESS
ACUREX CONTRACT NO. A81-05-031
TELEPHONE
Burlington 28.78 dscm
limit of 1 ng
Form EED-057 4 60
ANALYST _
REVIEWER .
SAMPLE ID (CUSTOMER)
SAMPLE ID (LAB)
Naphthalene Aliquot
Acenaphthvlene Aliquot
Phenanthrene Aliquot
Fluoranthene Aliquot
Pvrene Aliquot
Phenol Aliquot
Napthalone.-
Acenapthylene
Phenanthrene
Fluoranthene
Pyrene
Phenol
Others withli detectic
Probe
761
t-_ — — •
< 1
< 1
< 1
< 1
< 1
< 1
<40
<40
<40
<40
<40
<40
n <40
lOu + 3u
766
1 =====
-BBSf....'. — =-=J ....SB A. J-.
*— ---— •";
<1
<1
<1
<1
<1
<1
<60
<60
<60
<60
£6Q
<60
<60
lu-t-Filter
768
======
<1
<1
<1
<1
<1
<1
<70
<70
-------
5.8 RADIOMETRIC ANALYSIS RESULTS
5-71
-------
SAFETY SPECIALISTS, Inc.
3284 F Edward Avenue, Santa Clara, California 95050 • Telephone (408) 988-1111
ASSAY REPORT
Acurex Corporation
Attn: Mr. Larry Waterland
485 Clyde Avenue
Mountain View, California 94042
Date: August 13, 1981
Date Samples Received: 6/29/81
Customer Order No.: RB59185A, Rel. 15
Activity*
SSI No.
81228H
Client Description
A81-05-030-766
Gross Alpha
pCI/g
Gross Beta
pCi/g
53.3 ± 37.2 328.1 ± 98.3
Analyst: Pamela S. Shreve
Approved: T. C. Noble, Director
Safety and Health Services Division
*The ± values are the two sigma Poisson standard deviation of the counting
error.
The <_ values are equal to or less than three sigma of the counting error.
5-72
-------
SAFETY SPECIALISTS, Inc.
3284 F Edward Avenue, Santa Clara. California 95050 • Telephone (408) 988-1111
ASSAY REPORT
Acurex Corporation
Attn: Mr. Larry Water!and
485 Clyde Avenue
Mountain View, California 94042
SSI No.
81228H
Client Description
A81-05-030-766
Date: August 13, 1981
Date Samples Received: 6/29/81
Customer Order No.: RB59185A, Rel. 15
Activity*
Gross Gamma Gross Gamma
pCi/L pCi/g
530 ± 1761
/ ,..-;r->v-c—Oi- i^* •—•* /•<-***•
Analyst: Pamela S. Shreve
Approved: T. C. Noble, Director
Safety and Health Services Division
*The ± values are the two sigma Poisson standard deviation of the counting
error
The <_ values are equal to or less than three sigma of the counting error.
5-73
-------
5.9 BIOASSAY REPORTS
5-74
-------
CB
Litton
B1ONET1CS
5516 Nicholson Lane. Kensington. Maryland 20795 301 881-5600 • Teiex 89-3369
November 20, 1981
Mr. Roy Belletto
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Dear Mr. Belletto:
Enclosed are five copies each of the final reports for the three samples from
the "Burl" sampling site submitted for .testing and evaluation in IERL-EPA
Level 1 environmental assessment bioassays. All studies were conducted and
evaluated under IERL-EPA Level 1 guidelines. Reports for the "EA-1" and
"EA-2" sampling sites will be sent the week of November 23, 1981.
No technical or interpretative problems were encountered with these samples
except for an insufficient amount of the XAD extract sample to assay up to
the recommended maximum applicable dose (MAD) based upon weight of organics
per plate. Ames testing was modified by eliminating less responsive tester
strains. Adequate evaluations were achieved using this modified testing
strategy.
If you have any questions or comments concerning the reports, please feel
free to contact me at (301)881-5600, extension 536.
Sincerely,
Robert R. .Youjig
Environmental Assessment Section
Department of Molecular Toxicology
RRY/mg
Enclosures:
Reports:
Ames
CHO
RAM
Rodent
5881, 5885, 5888
5881
5885, 5888
5888
5-75
-------
BIOASSAY SUMMARY TABLE
Technical Directive or Project NO. LBI PROJECT NUMBER 22064
Contract No. ACUREX SUBCONTRACT RB59178A, RELEASE NUMBER 3, 'BURL' SITE
I Health Effects Tests | Ecological Effects Tests
Aquatic , | Terrestrial
Sample Identification
A81 -05-031 -760
(BURL XAD EXTRACT)
A81 -05-031 -766
(BURL 1 0+3+1 +FILTER;
A81 -05-031 -765
(BURL FLYASH)
..M
ND
ND
L
L/ND
M
ND
Notes
ND = No Detectable Toxicity
L = Low Toxicity
M = Moderate Toxicity
H = High Toxicity
* Evaluation of Ames Salmonella test is based upon mutagenicity and not toxicity.
LBI-0468 R 11/80
5-76
-------
DEFINITION OF TOXICITY CATEGORIES FOR HEALTH EFFECTS ASSAYS
tn
I
-3
Assaya
Ames
RAM
CHO
WAT
Activity Measured
MEC
(mutagenesis)
EC50
(lethality)
EC50
(lethality)
LD50
(lethality and
toxic signs)
Sample
Type
S
AL.NAL
E
S
AL
NAL
E
S
AL
NAL
E
S
AL.NAL
MADd
5
200
5000
1
600
20
1000
1
600
20
1000
5
5
Units
mg/plate
Ml /pi ate
L/plate
ing/ml
Ml /ml
Ml /ml
L/ml
mg/ml
Ml /ml
Ml /ml
L/ml
gm/kg
ml /kg
Range of Concentration or Dosage
High
<0.05
<2
<50
<0.01
<6
<0.2
<10
<0.01
<6
<0.-2
<10
<0.05
<0.05
Moderate
0.05-0.5
2-20
50-500
0.01-0.1
6-60
0.2-2
10-100
0.01-0.1
6-60
0.2-2
10-100
0.05-0.5
0.05-0.5
Low Not Detectable
(ND)
0.5-5
20-200
500-5000
0.1-1
60-600
2-20
100-1000
0.1-1
60-600
2-20
100-1000
6.5-5
0.5-5
ND at >5
ND at >200
ND at >5000
ND at >1
ND at >600
ND at >20 •
ND at >1000
ND at >1
ND at >600
ND at >20
ND at >1000
ND at >5
ND at >5
o>
Standard test abbreviations are as follows:
Ames: Ames Salmonella/microsome mutagenesis assay
RAM: Rabbit alveolar macrophage cytotoxicity assay
CHO: Rodent cell clonal toxicity assay
WAT: Acute in vivo test in rodents (whole animal test)
Standard abbreviations for measured endpoints are as follows:
MEC: Minimum effective concentration
EC50: Calculated concentration expected to produce effect in 50 percent of population
LD50: Calculated dose expected to kill 50 percent of population
S = Solid, AL = Aqueous liquid, NAL = Nonaqueous liquid, E = Extract and/or concentrate of unknown organic content
(use equivalent volume of SASS train gas)
MAD = Maximum applicable dose
-------
TABLE
HEALTH EFFECTS CRITICAL DATA SUMMARY FORM8
Contract No. .ACUREX SUBCONTRACT Technical Directive or Project No. LBI PROJECT NO. 22064 cit^ Sampled_BURL_
RB59178A, RELEASE 3
CJI
i
-3
00
Sample Identification
A81 -05-031 -760
(BURL XAD EXTRACT)
A81 -05-031 -766
(BURL 1 0+3+1 +FILTER)
A81 -05-031 -765
(BURL FLYASH)
Ames CHO Clonal |
Mutageniclty Toxicity Viability ATP /Per
[MEC]b [ECsolc Viability Index ATP 106 Cells
80 yg
> 5 mg
> 5 mg
18.4 yg
>1000 yg
>1000 yg
500 yg
>1000 yg
360 yg
'x.lOOO yg
"X/IOOO yC
>1000 yg
LDsod Toxic Signs8
>5 g
"The assays, observed parameters and evaluation criteria are presented in jERkRTP Procedures ManuaU. Level 1 Environmental Assessment
Biological Tests. [EPA Contract No. 68-02-2681, Litton Bionetics, Inc., Kensington, Md., September 1980, in pressTj
MEC: Minimum Effective Concentration - Lowest concentration for any tester strain giving a mutagenic response
ECs0: Effective concentration that reduces the observed parameter to 50 percent of the appropriate negative control.
""CDso: The dose lethal to 50 percent of treated animals.
signs are identified in a numbered list in the Level 1 manual. Only the number is reported here
::Doses reported as.per plate for the Ames assay, per ml for the CHO and RAM assays', and per kg for the Rodent
LBi-0798 1/ai Toxicity assay.
-------
EGzG BIONOMICS
EG&G BIONOMICS, 790 MAIN STREET, WAREHAM, MASSACHUSETTS 02571 « TEL. (617) 295-2550
RECEIVED SEP Q 1331
September 2, 1981
Ms. Teri Lannon
Acurex Corporation
485 Clyde Avenue
Mountain View, CA 94042
Dear Ms. Lannon:
Enclosed please find three (3) copies of our report:
"The Acute Toxicity of Five Samples To Freshwater
Organisms" - Report #BW-81-7-966
I trust you shall find this report both complete and
satisfactory. If you should have any questions or
comments, please contact me.
Sijncerely
Geraidr A. LeBlanc
Aquatic Toxicologist
GAL:jeb
Enclosure
5-79
-------
Estimated LC50 values, confidence intervals and no discernible effect concentrations for I), magna
and P. promelas exposed to Acurex samples.
'Sample
Species
24 hour
LC50 (95% confidence interval)'
48 hour
72 hour
96 hour
No discernible
effect concentration
(mg/Jl)
en
i
oo
o
A81-05-031-765
(bottom ash)
13. magna
P. promelas
>1000
3:1000
740
(620-940)
>1000
>1000
>1000
220
1000
mg/A.
o
Estimated by the moving average angle method.
-------
Calculated 5-day EC50's and EC95's for Selenastrum capricornutum
exposed to the five samples provided by the Acurex Corporation.
The EC values were based on decrease of cell numbers on exposed
cultures as compared to the control. (The 95% confidence limits
are in parentheses). Concentrations were based on microliters
of A80-09-023-24 per liter of algal growth medium and milligrams
of the other samples per liter of algal growth medium.
Sample EC50 EC95
A81-05-031-765 169(118-242) 314(195-506)
5-81
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
. REPORT NO.
EPA-600/7-87-OlOb
2.
3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
Environmental Assessment of a Wood-Waste-Fired
Industrial Firetube Boiler; Volume II. Data Supple-
ment
5. REPORT DATE
March 1987
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
R. DeRosier and L. R. Waterland
8. PERFORMING ORGANIZATION REPORT NO.
TR-83-123/ESD
). PERFORMING ORGANIZATION NAME AND ADDRESS
Acurex Corporation
P. O. Box 7555
Mountain View, California 94039
1O. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-3188
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air and Energy Engineering Research Laboratory
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; 1/81 - 3/84
14. SPONSORING AGENCY CODE
EPA/600/13
is. SUPPLEMENTARY NOTESAEERL pr0].ect officerisRobert E> Halli MailDrop65, 919/541-
2477. Volume I contains the technical results of the study.
16. ABSTRACT,
The report gives emission results from field tests of a wood-waste-fired
industrial firetube boiler. Emission measurements included: continuous monitoring
of flue gas emissions; source assessment sampling system (SASS) sampling of the
flue gas with subsequent laboratory analysis of samples to give total flue gas orga-
nics in two boiling point ranges, compound category information within these ranges,
specific quantitation of the semivolatile organic priority pollutants, and flue gas con-
centrations of 65 trace elements; Method 5 sampling for particulates; controlled con-
densation system (CSS) sampling for SO2 and SO3; and grab sampling of boiler bot-
tom ash for trace element content determinations. Flue gas CO emissions were
quite variable during the tests, and often quite high (attributed to the high excess air
level at which the unit operated). NOx"emissions were relatively high for a wood-
fired boiler, although the fuel nitrogen content was relatively high for a wood fuel.
SO2 and SO3 emissions were less than 10 ppm, in keeping with the low sulfur content
of the wood-waste fuel. Total organic emissions from the boiler were 5.7 mg/dscm,
about 90% of which consisted of volatile compounds. Emission levels of five poly-
cyclic organic matter species and phenol were quantitated: except for naphthalene,
all were emitted at less than 0.4 microgram/dscm.
7.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Pollution Sulfur Oxides
Wood Wastes Nitrogen Oxides
Fire Tube Boilers Trace Elements
Flue Gases Carbon Monoxide
Assessments Organic Compounds
Particles Polycyclic Compounds
Pollution Control
Stationary Sources
Environmental Assess-
ment
Particulate
13B
HL
13A
21B
14B
14G
07B
06A
07C
8. DISTRIBUTION STATEMENT
Release to Public
19. SECURITY CLASS (ThisReport)
Unclassified
21. NO. OF PAGES
114
2O. SECURITY CLASS (This page)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73)
5-82
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