EPA-R2 73-191 April 1973 Environmental Protection Technology Series Systems Study of Conventional Combustion Sources in the Primary Aluminum Industry Office of Research and Monitoring U.S. Environmental Protection Agency Washington. D.C. 20460 ------- EPA-R2-73-191 Systems Study of Conventional Combustion Sources in the Primary Aluminum Industry by J. Goldish, G. Margolis, J. Ehrenfeld, and R. Bernstein Walden Research Corporation 359 Allston Street Cambridge, Massachusetts 02139 Contract No. EHSD 71-21 Program Element No. 1A2014 EPA Project Officer: G. B. Martin Control Systems Laboratory National Environmental Research Center Research Triangle Park, North Carolina 27711 Prepared for OFFICE OF RESEARCH AND MONITORING U. S. ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D. C. 20460 April 1973 ------- This report has been reviewed by the Environmental Protection Agency and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. ii ------- TABLE OF CONTENTS Section Title Page I SUMMARY 1 A. Background, Definitions and Assumptions 1 B. Boiler Inventories 1 C. Fuel Consumption and Boiler Emission 3 D. Process Emissions 4 E. Comparison of Boiler and Process Emissions 4 F. Control Strategies 5 G. Recommendations 5 II INTRODUCTION 7 III INVENTORIES OF BOILER CAPACITIES, FUEL USE, AND EMISSIONS 10 A. Definitions 10 1. Size 10 2. Regions 10 3. Fuels 12 4. Firing Type 13 B. Methodology 13 1. The Sampl e 13 2. The 1970 Boiler Inventory 16 3. Operating Factors 16 4. Projections 17 5. Fuel Use 20 6. Emissions 20 C. Results 23 1. Boiler Inventories 23 2. Fuel Consumption by Boilers 23 3. Boiler Emissions 24 4. Discussion of Results 26 IV. PROCESS EMISSIONS 31 V COMPARISON OF BOILER EMISSIONS TO PROCESS EMISSIONS .. 34 Hi WALDEN RESEARCH CORPORATION ------- TABLE OF CONTENTS (Cont.) Section Title Page VI STRATEGIES 36 VII RECOMMENDATIONS 37 APPENDIX A HEATING PLANTS - SINGMASTER & BREYER 38 APPENDIX B HEATING PLANTS - WALDEN RESEARCH CORPORATION 42 WALDEN RESEARCH CORPORATION ------- I. SUMMARY A. BACKGROUND, DEFINITIONS AND ASSUMPTIONS This study determines the contribution to air pollution by the conventional fossil fuel combustion equipment installed in the Primary Aluminum Industry. It compares the boiler emissions to the process emis- sions in this industry and considers the importance of controlling these sources. In order to obtain the current inventory of boilers in the Pri- mary Aluminum Industry, an incomplete sample was obtained from question- naires sent out by Singmaster & Breyer under EPA Contract No. CPA 70-21. These data were supplemented by telephone interviews conducted by Walden Research Corporation. The total sample was summarized by state,and the employment figure for each available plant was determined and also summarized [1-1]. These figures and the total state employment in the Primary Aluminum In- dustry were used to proportion the final sample to provide a complete 1970 inventory, which was then summarized by six regions (see Figure 1-1). These geographical regions are exactly the same as those used in the Inter- mediate Size Boiler Study [1-3]. The rationale behind the choice of these regions was two-fold. First, the states in each area are considered to have similar air pollution conditions, and secondly, such a regional grouping allowed comparison with air pollution resulting from boilers in U.S. industries in general. B. BOILER INVENTORIES The total estimated capacity of boilers installed in the Primary Aluminum Industry in 1970 was 8,267,800 pounds of steam an hour, repre- senting approximately 50 units. This result is diminished to 767,800 pounds per hour if one plant, which generates its own power by means of four large coal-burning boilers,is left out. WALDEN RESEARCH CORPORATION ------- I--; -J.1JJ-. . ,__^^ ;.__"_' L z_ t " v^= FWS ---_-. Figure 1-1. Regional Boundaries ------- This anomolous plant was eliminated from the study, since it was found to be the only plant in the Primary Aluminum Industry to produce its own power. Thus, all further statistics in this report refer to the Pri- mary Aluminum Industry excluding this plant. It is suggested that this plant be included in a survey of emissions resulting from power require- ments for the Primary Aluminum Industry. Projections were made by applying the annual growth rates of 8.2% for the period of 1970 to 1975, and 2% for the period of 1975 to 1980. The estimated boiler capacities for 1975 and 1980 are 1,060,000 and 1,166,000 pounds per hour, respectively. C. FUEL CONSUMPTION AND BOILER EMISSION Natural gas is the most commonly used fuel for boilers in the Pri- mary Aluminum Industry. In 1970, the fuel distribution for fuels burned under boilers was as shown in Figure 1-2. Figure 1-2. 1970 Fuel Used Under Boilers in the Primary Aluminum Industry Emissions were calculated according to the following equations: cn /. x fuel consumption (Btu) x emission factor Ob/ Btu) x % sulfur* bU2 irons; 2000 (Ib/ton) ~~~~ = fuel consumption (Btu) x emission factor (Ib/Btu) 2000 (Ib/ton) Only in the case of coal- or oil-fired boilers WALDEN RESEARCH CORPORATION ------- Participates (tons) = fue1 consumption x emission factor x % ash The emission factors and sulfur and ash percentages used were those de- veloped in the Systems Study of Intermediate-Size Boilers [1-3]. The emissions are summarized in Table 1-1. TABLE 1-1 1970 BOILER EMISSIONS IN THE PRIMARY ALUMINUM INDUSTRY (tons) Totals so2 1,905 NOX 1,007 Parti culates 2,941 D. PROCESS EMISSIONS The process emissions were provided by Singmaster & Breyer in the form of pounds of pollutants per ton of aluminum produced [1-4]. In 1970, this would mean about 119,000 tons of S02 and 182,500 tons of particulate emissions. Using Maiden's projected production figures, the 1975 figures would be 174,000 tons of S02 and 266,000 tons of particulate emissions. In 1980 the emissions would be 191,000 tons of S02 and 294,000 tons of particulates. Process emissions of NO from the Primary Aluminum A Industry were considered trivial. E. COMPARISON OF BOILER AND PROCESS EMISSIONS Comparison of the boiler emissions to total industrial emissions and to the process emissions in the Primary Aluminum Industry shows that the boiler emissions are not only small in comparison to boiler emissions in other industry, but also in comparison to process emissions in the Primary Aluminum Industry (see Table 1-2). Only in the case of coal-fired boilers. WALDEN RESEARCH CORPORATION ------- TABLE 1-2 COMPARISON OF CURRENT AND PROJECTED BOILER AND PROCESS EMISSIONS (tons) 1970 Boilers Process so2 NOX Participates 1,905 1,007 2,941 119,000 negl . 183,000 1975 Boilers Process 205 1,155 189 174,000 negl . 267 ,000 1980 Boilers Process 222 1,251 204 191,000 negl . 292,000 F. CONTROL STRATEGIES The only control strategy considered was fuel switching to dis- tillate oil by 1975 for the coal-burning boilers. The emissions from boilers are already very low and are not significant enough to warrant expensive control equipment. This fuel switching results in an annual cost of about $700,000 expressed in 1967 fuel prices. G. RECOMMENDATIONS It is recommended that a brief study be done to determine the air pollution indirectly caused by the Primary Aluminum Industry through the purchase of power from power plants not located on the site of the pri- mary aluminum plant and run by outside groups. The single plant in the Great Lakes region which still produces its own power should be included in this new study. Appropriate control should be required for these power-producing boilers, but except for the above-mentioned plant, the control strategy is to be carried out by the utility industry. WALDEN RESEARCH CORPORATION ------- REFERENCES TO SECTION I 1-1. Dun & Bradstreet, Metal working Directory, 1971, Dun & Bradstreet, Inc., New York. 1-2. County Business Patterns, U.S. Bureau of Labor Statistics, 1969. 1-3. Systematic Study of Air Pollution from Intermediate-Size Fossil- Fuel Combustion Equipment, Wai den Research Corporation. Cambridge. Mass., 197T. 1-4. Personal Communication with Mr. Reid Iverson, Contract Manager of EPA Contract No. CPA 70-21, based on preliminary reports provided by Singmaster & Breyer. WALDEN RESEARCH CORPORATION ------- II. INTRODUCTION This report describes the results, methodology, and data base for a study of air pollution from conventional combustion sources in the Primary Aluminum Industry. This work has been carried out under Contract No. EHS-D-71-21, sponsored by the Office of Research and Monitoring of the U.S. Environmental Protection Agency. The purpose of this system study was: (1) to obtain a complete and current inventory of conventional sta- tionary fossil fuel combustion equipment installed in the Primary Aluminum Industry, (2) to project into the future the boiler inventory installed in this industry, (3) to calculate SOV, NO and particulate emissions resulting from /\ /\ these conventional fossil fuel combustion equipment for the present and the future, (4) to compare these emissions to total process emissions in the Primary Aluminum Industry, (5) to study the cost effectiveness and program required for con- trol strategies applicable to the boilers in the Primary Aluminum Industry. The work was divided into the following phases: I. Identification of the 1970, 1975, and 1980 boiler inventories. II. Calculation of the fuel consumed by these boilers and the air pollution resulting therefrom. III. Comparison of these boiler emissions to the process emissions calculated under EPA Contract No. CPA 70-21. IV. Techno-economic evaluation of air pollution control. V. Recommendations The boiler data for this study were obtained from a summary provided by the contractor of Contract No. CPA 70-21, Singmaster & Breyer, and were expanded by telephone interviews conducted by Wai den Research Corporation with various primary aluminum plants. WALDEN RESEARCH CORPORATION ------- Fuel consumption and emission figures were derived from these boiler capacity data, using operating characteristics, gathered by Singmaster & Breyer [2-1] and the Maiden interviews, as well as data used in the Sys- tems Study of Intermediate-Size Fossil-Fuel Combustion Equipment [2-2], The process emissions were provided by Singmaster & Breyer in the form of emissions in pounds per ton of aluminum produced in the Primary Aluminum Industry. Process emissions from the Primary Aluminum Industry are quite low on a national level. Comparison between the boiler emissions and the process emissions indicated that the boiler emissions are less than 2% of the process emissions in the Primary Aluminum Industry. Most of the boiler emissions are caused by a few small coal-burning boilers, and fuel switching is suggested for these boilers. 8 WALDEN RESEARCH CORPORATION ------- REFERENCES TO SECTION II 2-1. Summary provided to Maiden by Singmaster & Breyer, see Appendix A. 2-2. Systematic Study of Air Pollution from Intermediate-Size Fossil - Fuel Combustion Equipment, Walden Research Corporation, Cambridge, Mass., 1971. WALDEN RESEARCH CORPORATION ------- III. INVENTORIES OF BOILER CAPACITIES, FUEL USE. AND EMISSIONS A. DEFINITIONS This section defines the various categories used to identify and classify fossil-fuel burning equipment and to note some of the coding used in this report. Fossil fuel combustion equipment is broken down according to: (1) Size (2) Region (3) Fuel (4) Firing type (for coal only) 1. Size The watertube boilers in this study fall in the size category of less than or equal to 100,000 Ib per hour (pph), indicated by WT,. 2. Regions Six regions were used in this study (Figure 3-1). A sum- mary description of these regions follows. Atlantic Coastal Megalopolis (AT) - A very dense, nearly continuous band of large, mature, urban areas. The urbanization is sup- ported by an exceptionally broad economic base including a wide variety of types and sizes of manufacturing enterprises as well as the nation's educational, financial, and government centers. The region experiences moderately cold winters and uses oil for most of its space heating. The pollution problem is aggravated by shallow atmospheric mixing depths but relieved by relatively high wind speeds and the frequency of low-level stability. Industrial Great Lakes (GL) - A second group of large, mature, urban areas, different only in degree from the Atlantic coastal megalopolis, having slightly less dense surroundings, somewhat wider spacing of urban centers, and an economy more characterized by large, mass-production 10 WALDEN RESEARCH CORPORATION ------- Ll FWS E^E="^r Figure 3-1. Regional Boundaries ------- industry. The two regions also differ in fuel use, with the Great Lakes region dividing its consumption among coal, oil, and gas. Although the region is characterized by relatively favorable atmospheric dilution, the population and industrial load results in high pollution levels. Far West and South (WS) - A group of large, new, fast- growing, urban areas which are widely scattered over otherwise sparsely- settled territory. Relatively little manufacturing and warm climate tend to mitigate pollution from stationary combustion units. The large, disperse urban areas, however, generate high volumes of automobile ex- haust, which in several areas are concentrated by poor atmospheric con- ditions. Central Urban (CU) - Medium-size, widely-separated, rela- tively new, metropolitan areas supported by manufacturing and the sur- rounding rural and town populations. Because of the relative concentra- tions of population in urban areas, these states rank surprisingly high in the Census definition of "urban" population. Gas is the principal fuel for space heating in this cold-winter region. Atmospheric con- ditions are relatively good except in Colorado and Utah. South East (SE) - A region with cities whose size and dis- tribution are similar to those in the central urban region. But the cities are more mature, are surrounded by denser statewide population, and have slightly more manufacturing. The warmer climate reduces the emissions from space heating but frequent atmospheric stagnation con- centrates the pollutants which are emitted. Rural North (RN) - An area of low density, with only a few small metropolitan areas and with little manufacturing. Although it in- cludes some of the nation's coldest territory, pollution is relatively low because of the low density. The New England states included in this region have somewhat higher densities and some manufacturing. 3. Fuels The fuels used by boilers in the Primary Aluminum Industry are: coal (CL), distillate oil (DO), and natural gas (GS). WALDEN RESEARCH CORPORATION ------- 4. Firing Type (for coal only) The small boilers using coal were of the overfed stoker type (OF). Firing types reflect differences in emission and were identi- fied in the questionnaire used. B. METHODOLOGY This section describes the methodology used to arrive at the boiler inventories, the fuel consumed by these boilers, and the resulting emissions. 1. The Sample Singmaster & Breyer provided Walden with a summary of boiler data for 15 primary aluminum plants in the U.S. (see Appendix A). The capacities and number of boiler units from this sample are summarized in Table 3-1. TABLE 3-1 SAMPLE OF BOILERS IN THE PRIMARY ALUMINUM INDUSTRY by Singmaster & Breyer Region # of Units Capacity (103 Ib/hr) Atlantic (AT) 1 20.6 Great Lakes (GL) West and South (WS) 12 Central Urban (CU) 2 South East (SE) 10 Rural North (RN) J_ 26 Walden also received a list of the companies which did not report data to Singmaster & Breyer. These companies are shown in Table 3-2 with production capacity [3-1, 3-2] and employment estimates [3-3] for each plant. 13 WALDEN RESEARCH CORPORATION 98.0 (+ 4 for which ------- TABLE 3-2 COMPANIES FOR WHICH NO DATA WERE AVAILABLE End of 1968 Production Capacities (1) Company (thousand tons) Employment (2) Alcoa Evansville, Indiana 175 700 Massena, New York 125 3,000 Point Comfort, Texas 175 2,100 Conalco New Johnsonville, Tennessee 140 600 Intalco Ferndale, Washington 270 1,300 Kaiser Chalmette, Louisiana 260 2,620 Mead, Washington 206 1,450 Tacoma, Washington 61 385 Ormet Hannibal, Ohio 240 2,500 Eastalco Frederick, Maryland 85 500 Noranda New Madrid, Missouri 75 n.a. Revere Scottsboro, Alabama 72 n.a. Gulf Coast Aluminum Lake Charles, Louisiana 35 n.a. Sources: (1) Minerals Yearbook 1968. and Metals Week (July 15, 1968). (2) Dun & Bradstreet, Metal working Directory. 14 WALDEN RESEARCH CORPORATION ------- These plants add up to about 49% of the total production capacity in the Primary Aluminum Industry 1n 1970, and 51% of the total employment in the Primary Aluminum Industry in 1969 [3-4]. A sample representing about half of the Primary Aluminum Industry is satisfactory on a national scale. On a regional basis, however, it was considered necessary to contact a few more plants by means of telephone interviews. The results of these interviews are shown in Appendix B. Steam is being used in the Primary Aluminum Industry for process and space heating purposes only, with the exception of one plant. The boilers at this plant were clearly power boilers and not considered representative of the fossil-fuel combustion equipment presently in- stalled in primary aluminum plants. All other plants buy their power and have no need for very large boilers. This power-generating primary aluminum plant was excluded from this study. Table 3-3 summarizes the - total sample used. TABLE 3-3 COMBINED WALDEN AND SIN6MASTER & BREYER SAMPLE OF BOILERS IN THE PRIMARY ALUMINUM INDUSTRY Region AT GL US CU SE RN * Based on working # of Units 5 2 12 4 13 1 Capacity (103 Ib/hr) 142.1 56.0 155.6 19.4 261.6 10.0 employment figures from Dun & Directory and County Business Est. % of Total* 100 100 60 100 93 100 Bradstreet's Metal - Patterns. 15 WALDEN RESEARCH CORPORATION ------- 2. The 1970 Bo Her Inventory Regional employment figures of the Primary Aluminum Indus- try (SIC 3334) were obtained from County Business Patterns [3-4]. Individual plant employment figures were available from the Dun & Brad- street Metal working Directory 1*3-3]. For the plants available in the final sample, employment was summarized by region, and the boiler cap- acities and number of units were multiplied by the inverse of the ratio between this figure and the total number of employees in the Primary Aluminum Industry in that region. The 1970 boiler inventory thus obtained is summarized in Table 3-4. TABLE 3-4 ESTIMATES OF INSTALLED BOILERS IN THE PRIMARY ALUMINUM INDUSTRY - 1970 Region AT GL WS CU SE RN TOTAL # of Units 5 2 20 4 14 J_ 46 Capacity (103 142.1 56.0 259.0 19.4 281.3 10.1 767.8 Ib/hr) The boilers are used for process heating and space heating purposes only, requiring small units and a load which varies according to the season. The average boiler capacity is about 16.600 Ib/hr. 3. Operating Factors The load factors for the boilers were available in the questionnaire returns and from telephone interviews. Where necessary, they were weighted by region according to capacity. The efficiency factor used was .73 £3-5]. The complete 1970 boiler inventory showing the operating factors is summarized in Table 3-5. 16 WALDEN RESEARCH CORPORATION ------- TABLE 3-5 1970 BOILER INVENTORY FOR THE PRIMARY ALUMINUM INDUSTRY Region AT AT GL GL GL CU SE SE RN Size WT, WT, WT, "Tl WT, WT, WT, WT, WT1 Fuel GS CL GS DO GS GS GS CL GS Firing Capacity 22.1 OF 120.0 55.0 1.0 259.0 19.4 279.3 OF 2.0 10.0 767.8 Load .87 1.00 .75 .75 .94 .74 .99 1.00 .98 4. Projections The Aluminum Statistical Review 1969. published by the Aluminum Association, provided data on installed capacity in the Pri- mary Aluminum Industry (see Figure 3-2), and commented: "There were nine domestic primary producers as of December 31, 1969. They are Aluminum Company of America, Anaconda Aluminum Company, Con- solidated Aluminum Corporation, Harvey Alumi- num (Incorporated), Intalco Aluminum Corpora- ation (owned jointly by Amax Aluminum Company, Howmet Corporation and Pechiney Enterprises, Inc.), Kaiser Aluminum & Chemical Corporation, National Southwire Aluminum Company, Ormet Corporation (jointly owned by 01 in Mathieson Chemical Corporation and Revere Copper and Brass Incorporated) and Reynolds Metals Company. As of December 31, 1948 there were three producers of primary aluminum in the United States with a combined annual capacity of 641,500 tons. Capacity increases were fre- quent through 1959, when total annual capacity stood at 2,402,750 tons at year end and three new producers had entered the field. 17 WALDEN RESEARCH CORPORATION ------- 7000 6000 5000 - 4000 00 3000 . Source: Aluminum Statistical Review, 1969 2000 o TO m 1000 - 8 TO s JO O 1950 1955 I960 1965 1970 1975 Figure 3-2. Production of Primary Aluminum with Projections to 1980 1980 ------- During the next five years through 1964, total annual capacity increased only 8.2 percent and only one new producer appeared. During the last five years since 1964 capacity increased 49.6 percent, an average annual rate of 8.4 percent. During 1969 capacity increased 202,300 short tons to 3,888,300 short tons, a gain of 5.5 percent over 1968. This compared with an ex- pansion of 365,000 short tons or 11.0 percent in the preceding year. Among existing pro- ducers contributions to the increase in capacity during 1969 were as follows: Alcoa 125,000 tons; Reynolds 40,000 tons, Kaiser 20,000 and Intalco 10,000 tons. National Southwire Aluminum Company came on stream in 1969 as the ninth primary producer, with in- stallation of a portion of a plant with planned capacity of 180,000 tons. The percentage distribution of U.S. primary capacity by company at the end of 1969 was as follows: Alcoa 34.1; Reynolds 24.0; Kaiser 18.3; Intalco 6.8; Ormet 6.2; Anaconda 4.5; Consolidated 3.6; Harvey 2.3 and National Southwire 0.2. Alcoa, Harvey, Kaiser and Reynolds have an- nounced plans for additional capacity or modern- ization in future years. Four new firms are planning to begin primary production within the next two years." Based on the above it was assumed that production capacity will continue to grow at the annual rate shown between 1964 and 1969, about 8.2% up to 1975. This would set the expected 1975 capacity at about 5,800 short tons. Considering the decrease in investment in plant and equipment due to the economic depression of the early 1970's, it seems reasonable to expect another slowdown in growth after 1975 as was experi- enced after 1959. Walden assumed a 2% annual increase in capacity between 1975 and 1980, setting the 1980 total capacity at 6,380 short tons. Using the 1970 boiler capacity-production rates, Walden ar- rived at the projected boiler capacities of 1,060,000 pph in 1975 and 1,166,000 pph in 1980, with all boilers using gas or distillate oil. This fuel use assumption is based on conversations with Alcoa [3-6]. Walden was told that in most plants, conversions from coal to distillate oil burners 19 WALDEN RESEARCH CORPORATION ------- are taking place or have already taken place at this time. Though it has usually meant an increase in boiler operation costs, the expense has been justified as a public relations effort. The projected inventories are shown 1n Table 3-6. The as- sumption has been made that coal-burning boilers in the Atlantic region and South East will switch to distillate oil by 1975, and furthermore, that no new coal-burning boilers will be installed in the Primary Aluminum Industry. The added capacity in each region was expected to follow the 1970 fuel use pattern for that region as far as the distillate oil-gas ratio is concerned, and the West and South and the South East were as- sumed to be expanding slightly faster than the other four regions. The latter assumption was based on: (1) The general economic growth of these regions (see Intermediate Boiler Study [3-5]). (2) The past expansion trend in the Primary Aluminum Industry [3-7]. (3) The much lower cost of power in these regions; in the West and South due to hydroelectric power around Washington and Oregon where several plants are located, and in the South East due to the TVA plants [3-7]. 5. Fuel Use Fuel use was calculated for the 1970, 1975, and 1980 boiler inventories by using the formula: _ capacity (Ib/hr) x 975 (Btu/lb) x 8760 (hours) x load (fraction) boiler efficiency (fraction) 6. Emissions Emissions were calculated for the 1970, 1975, and 1980 boiler inventories according to the following equations: 2Q WALOEN RESEARCH CORPORATION ------- TABLE 3-6 PROJECTED BOILER CAPACITIES IN THE PRIMARY ALUMINUM INDUSTRY (103 pph) Region AT AT GL GL WS CU SE SE RN TOTAL Fuel GS DO GS DO GS GS GS DO GS 1975 Capacity 30 162 69 2 363 26 392 3 13 1,060 1980 Capaci ty 32 175 75 2 402 28 434 4 14 1,166 /,x en /* \ - fuel consumption (Btu) x emission factor Qb/Btu) x % sulfur (1) S02 I tons) 2000 (Ib/ton) /o\ MO /* \ fuel consumption (Btu) x emission factor (Ib/Btu) (2) NOX (tons) - * N2006 (lb/ton) ,« n ... . . fuel consumption (Btu) x emission factor Qb/Btu) x % ash (3) Paniculate = 2000 (lb/ton) (tons) The emission factors and sulfur and ash contents used are listed in Tables 3-7 and 3-8 and are the same as those developed in the Study of Intermediate Boilers [3-5]. ** ** Only in the case of coal- or oil-fired boilers Only in the case of coal-fired boilers 21 WALDEN RESEARCH CORPORATION ------- TABLE 3-7 EMISSION FACTORS USED IN CALCULATIONS OF AIR POLLUTANT EMISSIONS FROM BOILERS IN THE PRIMARY ALUMINUM INDUSTRY Pollutant so2 so2 so2 NOV x NOX NOV x Particulates Particulates Particulates Emission factors: Size Fuel all GS all DO all CL WT1 GS WT] DO all CL WT] GS WT, DO I wij CL GS - pounds of DO - pounds of CL - pounds of Firing Type OF OF pollutant per million pollutant per thousand pollutant per thousand Factor* 0 .5838 x 104 P .3800 x 10s j .1676 x 10J .2071 x 104 c .1500 x 10° .1800 x 102 .6300 x 103 .1300 x 105 cubic feet barrels tons TABLE 3-8 Region AT GL WS CU SE RN SULFUR AND Fuel DO CL DO CL DO CL DO CL DO CL DO CL ASH CONTENTS % Sulfur 0.220 1.830 0.247 2.380 0.263 2.060 0.274 2.480 0.182 1.670 0.300 1.210 % Ash 0.0 8.07 0.0 8.57 0.0 7.89 0.0 8.86 0.0 7.72 0.0 9.14 22 WALDEN RESEARCH CORPORATION ------- C. RESULTS This section describes the results of the current and projected boiler inventories, fuel consumption and boiler emissions in the Primary Aluminum Industry. 1. Boiler Inventories The summary of the 1970, 1975, and 1980 boiler capacities are shown in Table 3-9. TABLE 3-9 BOILER CAPACITY INVENTORIES FOR THE PRIMARY ALUMINUM INDUSTRY 1970-1980 (103 lb/hr) Region AT GL US CU SE RN TOTALS 1970 142.1 56.0 259.0 19.4 281.3 10.1 767.9 1975 192 71 363 26 395 13 1,060 1980 207 77 402 28 438 14 1,166 2. Fuel Consumption by Boilers The fuel use estimates are shown in Table 3-10. Fuel switching has been considered part of the present trend and it has been assumed that the coal boilers still in use in 1970 for process and space heating will all have converted to distillate oil by 1975. The fuel use pattern of these boilers is shown in Figure 3-3. This continuation of present trends will mean an increase in the annual fuel cost of approximately $700,000 expressed in 1967 prices for the plants with small coal-burning boilers [3-5]. 23 WALDEN RESEARCH CORPORATION ------- TABLE 3-10 FUEL CONSUMPTION BY BOILERS IN THE PRIMARY ALUMINUM INDUSTRY 1970-1980 (109 Btu) Region AT GL MS CU SE RN 100 8Q «> 6Q 03 C i. 2Q l 1 8 1970 1975 19 1,629 2,200 2, 492 623 2,849 3,992 4, 168 225 3,258 4,576 5, 115 149 TOTALS 7,511 11,765 12, i i i i i i GS CL ' -^___ | DO 970 1975 19 S% CL 17% DO 17 1% GS 83% GS 83 80 374 676 221 242 074 161 748 80 % DO % GS Figure 3-3. Fuel Use Pattern of Boilers in Primary Aluminum Industry 3. Boiler Emissions The emissions for 1970 are shown in Table 3-11. 24 WALDEN RESEARCH CORPORATION ------- TABLE 3-11 1970 EMISSION INVENTORY FOR BOILERS IN THE PRIMARY ALUMINUM INDUSTRY (tons) Region AT AT GL GL WS CU SE SE RN Size wr. WTi WTi WTi WTi WTi WTi WTi WTi Fuel Firing GS CL GS DO GS GS GS CL GS TOTALS The projected so2 0 OF 1 ,878 0 1 0 0 NOX 19 405 40 2 239 14 Parti culates 2 0 '271 OF 28 0 7 10 1 ,905 1 ,007 emissions TABLE PROJECTED EMISSIONS FROM are shown 3-12 2 2 ,833 4 0 26 2 29 44 1 ,941 in Table 3-12. BOILERS IN THE PRIMARY ALUMINUM INDUSTRY (tons) Region AT AT GL GL WS CU SE SE RN Fuel Type GS DO GS DO GS GS GS DO GS TOTALS S02 0 200 0 2 0 0 0 3 0 205 1975 NOX 26 322 51 3 335 19 381 6 12 1,155 Part. 3 98 5 1 36 2 41 2 1 189 S02 0 216 0 2 0 0 0 4 0 222 1980 NOX 27 349 55 3 354 20 421 8 14 1,251 Part. 3 106 6 1 38 2 45 2 1 204 25 WALDEN RESEARCH CORPORATION ------- The national air pollution from boilers in the Primary Aluminum Industry 1s shown in Figure 3-4. 4. Discussion of Results This study has revealed that the Primary Aluminum Industry uses boilers primarily for process heating and space heating. Except for one plant, all power requirements are met by the utilities in the neighborhood of the aluminum plant. The Primary Aluminum Industry uses about 15,000 kwh per ton of aluminum produced [3-8], and it is obvious that indirectly a lot of air pollution could be caused by this industry's power requirements. The boilers necessary to generate this power are not, however, located at the site of the plant, nor are they owned by the Primary Aluminum Industry, except for the plant mentioned above. A 1964 survey of the industry conducted by the American Gas Association (AGA) shows furthermore that as far back as 1964, gas and hydroelectric power were most common in this industry Involving rela- tively little air pollution [3-9]. Table 3-13, taken from the AGA study, shows five companies using coal for power generation. All these plants are included in the combined Singmaster & Breyer-Walden sample, and only one reported large coal-burning boilers used to generate power. It is understood that if. the Primary Aluminum Industry had been generating power on the plant location, emissions from boilers would have been enormous, depending on the fuel used and the controls applied to the combustion process. The findings of this study are, how- ever, that the boiler emissions are not significant enough to warrant sophisticated control strategies: (1) because of the small size of these boilers (average capacity is about 16,600 pph) (2) because of the fuel trend to switch to gas and distillate oil (3) because of the tendency of the industry to buy its power instead of generating it. WALDEN RESEARCH CORPORATION ------- M 1,905 1,007 1,155 1,251 2,941 O m m m 5 o 3 yj o 205 222 1970 1975 1980 so2 Figure 3-4. 1970 1975 NO.. 1980 189 204 1970 1975 1980 Particulates Air Pollution from Boilers in the Primary Aluminum Industry (tons) ------- TABLE 3-13 PRIMARY ALUMINUM PRODUCTION CAPACITY IN THE U.S. BY COMPANIES (short tons per year) Aluminum Co. of America: Alcoa, Tenn. Badin, N.C. Evansville, Ind. Massena, N.Y. Point Comfort, Texas Rockdale, Texas Vancouver, Wash. Wenatchee, Wash. Total Reynolds Metals Co. : Arkadelphia, Ark. Jones Mills, Ark. Listerhill, Ala. Longview, Wash. Massena, N.Y. San Patrico, Texas Troutdale, Ore. Total Kaiser Aluminum and Chemical Corp: Chalmette, La. Mead, Wash. Ravenswood, W. Va. Tacoma, Wash. Total Power3 2 2 3 2 1 3 2 2 1 1 3 2 2 1 2 1 2 3 2 Actual , end of 1964 157,100 52 ,000 35,000 118,000 140,000 150,000 97,500 108,500 858,100 55,000 109,000 194,500 65,000 115,000 95,000 91 ,500 725,000 247,500 176,000 145,000 41 ,000 609,500 Capacity Being built Total actual in 1964 and planned 157,100 52,000 140,000 175,000 32,000 150,000 140,000 150,000 97,500 108,500 172,000 1,030,100 55,000 109,000 194,500 65,000 115,000 95,000 91 ,500 725,000 247,500 176,000 145,000 41,000 609,500 28 WALDEN RESEARCH CORPORATION ------- TABLE 3-13 (Cont.) Power3 Anaconda Aluminum Co.: Columbia Falls, Mont. 2 Consolidated Aluminum Corp. : New Johnsonville, Tenn. 2 Harvey Aluminum, Inc.: The Dalles, Ore. 2 Ormet Corp.: Hannibal, Ohio 3 Intalco Aluminum Corp.: Bel ling ham, Wash. 2 GRAND TOTAL Actual of 1 67, 32, 87, , end 964 500 000 000 Capacity Being built in 1964 32,500 30,000 - 180,000 = mmma 2,559,100 76,000 310,500 Total actual and planned 100,000 62,000 87,000 180,000 76.000 2,869,600 aThe number after the plant location indicates the means of power genera- tion: 1 - natural gas; 2 - hydro-electric; 3 - coal. 29 WALDEN RESEARCH CORPORATION ------- REFERENCES TO SECTION III 3-1. Minerals Yearbook 1968. Volumes I-II, U.S. Bureau of Mines, 1968. 3-2. Metals Week. July 15, 1968. 3-3. Dun & Bradstreet Metalworking Directory, 1971, Dun & Bradstreet, Inc., New York. 3-4. County Business Patterns, U.S. Bureau of Labor, 1969. 3-5. Systematic Study of Air Pollution from Intermediate-Size Fossil-Fuel Combustion Equipment. Walden Research Corporation, Cambridge, Mass., WT 3-6. Personal communication with Mr. Taylor of Alcoa. 3-7. Aluminum Statistical Review.1969. 3-8. McGraw, M.J., and Duprey, R.L., Air Pollutant Emission Factors, Preliminary Document, EPA Research Triangle Park, North Carolina, April 1971. 3-9. "Process Energy Requirements in the Non-Ferrous Metals Industry", American Gas Association, Inc., 1964. WALDEN RESEARCH CORPORATION ------- IV. PROCESS EMISSIONS The process emissions were provided by Singmaster & Breyer in the form shown in Table 4-1 [4-1]. TABLE 4-1 PROCESS EMISSION FACTORS IN THE PRIMARY ALUMINUM INDUSTRY* Emission Factor Ib/ton Aluminum S02 60 Particulates 92 NOV negligible * Source: Singmaster & Breyer's Systems Study of Air Pollution in the Primary Aluminum Industry (preliminary) The process emission factor shown 1n Table 4-1 for particulate emis- sions falls within the range reported in the compilation of air pollutant emission factors published by the Environmental Protection Agency [4-2]. SO emissions from the primary aluminum production process are not indl- A cated in these publications. The calculated process emissions based on the production of aluminum are shown below in Table 4-2. Vlalden does not agree with the projections made for aluminum production by Singmaster & Breyer. The U.S. Industrial Outlook for 1970 [4-3] projects a 40% Increase of aluminum shipments be- tween 1970 and 1975. Singmaster & Breyer show almost a 6525 increase for that period. The U.S. Industrial Outlook for 1972 [4-4] indicates a de- cline in primary aluminum exports, a weakening demand, and excess supply for the period between 1975 and 1980. Therefore, the process emissions used 1n this study for comparison purposes are slightly lower for the projected years than might be found in the Singmaster & Breyer study. 31 WALDEN RESEARCH CORPORATION ------- TABLE 4-2 PROCESS EMISSIONS IN THE PRIMARY ALUMINUM INDUSTRY (103 tons) Singmaster & Breyer Wai den Research Corp. 1970 1975 1980 1970 1975 1980 Aluminum 3,971 5,900 8,000 3,971 5,800 6,380 S02 119 177 240 119 174 191 Particulates 183 271 368 183 267 292 32 WALDEN RESEARCH CORPORATION ------- REFERENCES TO SECTION IV 4-1. Personal Communication with Mr. Reid Iverson, Contract Manager of EPA Contract No. CPA 70-21, based on preliminary reports provided by Singmaster & Breyer. 4-2. McGraw, M.J., and Duprey, R.L., Air Pollutant Emission Factors, Preliminary Document, EPA Research Triangle Park, North Carolina, April 1971. 4-3. U.S. Industrial Outlook 1970, U.S. Department of Commerce. 4-4. U.S. Industrial Outlook 1972, U.S. Department of Commerce. 33 WALDEN RESEARCH CORPORATION ------- V. COMPARISON OF BOILER EMISSIONS TO PROCESS EMISSIONS It was noted before that the boiler emissions 1n the Primary Aluminum Industry are quite small. Table 5-1 shows the 1970 emissions 1n comparison to U.S. emissions from industrial boilers [5-1]. TABLE 5-1 COMPARISON OF EMISSIONS FROM BOILERS IN THE PRIMARY ALUMINUM INDUSTRY TO INDUSTRIAL BOILERS Primary Aluminum All Industrial (tons) 1970 1970 1970 so2 NOX Part. 1,905 1,007 2,941 1967 1967 1967 so2 NOX Part. 4,270,000 1 ,040,000 2,390,000 Considering air pollution from the Primary Aluminum Industry as a whole, it is found that S02 and particulate emissions from boilers represent less than 2% of the total emissions (see Table 5-2). TABLE 5-2 COMPARISON OF CURRENT AND PROJECTED BOILER AND PROCESS EMISSIONS IN THE PRIMARY ALUMINUM INDUSTRY (EXCLUDING POWER PRODUCING PLANT) (tons) 1970 Boilers Process so2 N0x Parti culates 1,905 1,007 2,941 119,000 negl. 183,000 1975 Boilers Process 205 1,155 189 174,000 negl. 267,000 1980 Boilers Process 222 1,251 204 191,000 negl. 292,000 34 WALDEN RESEARCH CORPORATION ------- REFERENCES TO SECTION V 5-1. Systematic Study of Air Pollution from Intermediate-Size Fossil- fuel Combustion Equipment. Maiden Research Corporation. Cambridge. Mass., 1971. 35 WALDEN RESEARCH CORPORATION ------- VI. STRATEGIES The only strategy recommended for the boilers 1n use in the Primary Aluminum Industry is the banning of coal stokers by 1975 and a suggested { fuel switching policy for the boilers which were burning coal in 1970. This trend to replace coal-burning boilers by oil burners is already ap- parent and should not require much further research. 36 WALDEN RESEARCH CORPORATION ------- VII. RECOMMENDATIONS It is necessary to look into possible strategies for the plants pro- ducing power for the Primary Aluminum Industry. This research is not in- cluded in the scope of this report. It is therefore recommended that a study be done to determine the air pollution indirectly caused by the Primary Aluminum Industry, through the purchase of power from power plants, not located at or owned by the primary aluminum plant. It 1s suggested that the single primary aluminum plant, which still produces its own power, be included In this new study. Appropriate control should be required for the air pollution resulting from these large power-producing boilers, but except for the above- mentioned plant, the control strategy will have to be carried out by the utility industry. 37 WALDEN RESEARCH CORPORATION ------- APPENDIX A HEATING PLANTS - SINGMASTER & BREYER 38 WALDEN RESEARCH CORPORATION ------- - WEW1HR VINKTS CO 10 n m v> i o 8 TO 3 TO Boiler Designation Location Region Age or Year Installed Manufacturer Rated Capacity (Ib steam/hr) Use: Power, Process, Heating Est. Load Factor - % Fuel* Coal Firing Method 16 Oil Natural Gas MCFD Blast Furnace Gas Coke Oven Gas Other Flue Gas Control Equip. Type (if any) Est. % Efficiency Ht. of Stack Top Above Grade Indicate approximate (a "yes" or "no", at **NR - Not Reported A SE 1953 Todd Eng. 16,000 Heating Process 95 No No 174.9 No No No 50' % of total annual Btu \ least). B CU 1953 Webster Eng. 4,600 Heating Process 95 No No 50 No No No 30' 's fired, C RN 1954 D US 1968 Comb. Eng. Cleaver Brooks 10,000 Heating Process 98 No No 260 No No No 30' or total 2-Units 23,000 Heating Process 100 No No 525 No No No 30' quantity of E WS 1941,1954 Ray (1941) B&W (1954) 2-Units 27,000 Heating Process 100 No No 740 No No No (1)135' (1)50' \ ' / **v each fuel fired F WS 1957 Gabriel & Union Iron Works 2-Units NR** Heating Process 70 NR NR NR NR NR NR NR in year ------- MEKUHfc PLMTCS I m TO m m 8 TO 3 TO Boiler Designation Location (Region) Age or Year Installed Manufacturer Rated Capacity (Ib steam/ hr) Use: Power, Process Heati ng Est. Load Factor - % Fuel* Coal Firing Method #6 Oil Natural Gas MCFD Blast Furnace Gas Coke Oven Gas Other Flue Gas Control Equip. Type (if any) Est. % Efficiency Ht. of Stack Top Above Grade Indicate approximate (a "yes" or "no", at **NR - Not Reported G SE 1958 Superior 30,000 Heating Process 100 No No 770 No No 50' % of total annual least). H WS 1952 Foster- NR** Heating Process 100 No No 513 No No 50' Btu's fired, I CU 1942 J WS 1942 E. Keeler E. Keeler 12,810 Heating Process 75 No No 395 No No 135' or total 10,000 Heati ng Process 100 No No 165 No No 135' quantity of each K WS 1952,1960 B&W 2-Units 33,000 Heating Process 100 No No 325 No No 41' fuel in year ------- HEATING PLANTS ICont.) o m t/i o o x o Boiler Designation Location (Region Age or Year Installed Manufacturer Rated Capacity (Ib steam/ hr) Use: Power, Process Heating Est. Load Factor - 1$ Fuel* Coal - Tons/Day Firing Method #6 Oil Natural Gas MCFD Blast Furnace Gas Coke Oven Gas Other Flue Gas Control Equip, Type (if any) Est. % Efficiency Ht. of Stack Top Above Grade * Indicate approximate (a "yes" or "no", at ** NR - Not Reported L SE 1916,1950, 1952 4-Units 2/ 78,000 Heating Process 100 3.3 Over Feed Stoker No 790 No No No 1916-142' 1950-60' 1952-60' % of total annual Btu's least). M SE 1970 Coppus 2-Units 47,600 Heating Process 100 No No 767 No No No 175' fired, or N AT 1958 Todd . Ship. 20,600 (1958) Heating Process 90 No No 406 No No No 1958-85', 1959- 90' & 165', 1959- 63 90' total quantity of 0 WS 1952 Webster 5,000 Heating Process 100 No No 141 No No No 30' each fuel in year ------- APPENDIX B HEATING PLANTS - WALDEN RESEARCH CORPORATION 42 WALDEN RESEARCH CORPORATION ------- N>?EHDW ft - HEAT1H& CO m in o o o TO 3 1 o Boiler Designation Location (State) Age or Year Installed Manufacturer Rated Capacity (Ib steam/hr) Use: Power, Process, Heating Est. Load Factor - % Fuel* Coal Firing Method #6 Oil Natural Gas AT 1968 Cleaver Brooks 45 hp Process Heating 50% Gas GL 1957 (2 units) 56,000 #/hr Process and Space Heating 100% for 1 50% for 2nd Gas (12 oil stdby about 7 days) CU 1970 (2 units) MO6 Btu/hr each Space Heating 19% Gas SE n.a. (3 units) 30,000 #/hr each Process and Space Heating 1 00% for 2 50% for 3rd Gas (#2 oil on stby) AT 1942 (2 units) 30,000 #/hr ^90% Coal Underfed Stoker AT 1956 (1 unit) 40,000 #/hr ^0% Coal Chain Grate Stoker Blast Furnace Gas Coke Oven Gas Other Flue Gas Control Equip. Type (if any) Est. % Efficiency Ht. of Stack Top Above Grade Indicate approximate % of total Btu's fired, or total quantity of each fuel fired in year /_ it II _ If U.A H * 4- 1 na e +" 1 (a "yes" or "no" at least) ------- BIBLIOGRAPHIC DATA SHEET 1. Report No. EPA-R2-73-191 4. I'ttle and Subtitle Systems Study of Convent! onal Combustion Sources in the Primary Aluminum Industry 3. Recipient's Accession No. 5. Report Date April 1973 6. r. Auchor(s) Margnlia .T F.hrPnfeld R Bernstein 8- Performing Organization Kept. No. 9. performing Organization Name and Address Walden Research Corporation 359 Alston Street Cambridge, Massachusetts 02139 10. Project/Taslc/Work Unit No. II. Contract/Grant No. EHSD 71-21 12. Sponsoring Organization Name and Address EPA, Office of Research and Monitoring NERC/RTP, Control Systems Laboratory Research Triangle Park, North Carolina 27711 13. Type ol Report & Period Covered Final 14. 15. Supplementary Notes 16. Abstracts The report provides an estimated inventory of boiler capacity and related pollutant emissions in the primary aluminum industry. Boiler capacity and pollutant emissions are projected to 1980. The report supplements a separate systems study of all process-related emissions from the aluminum industry. Significant findings include: the limited boiler capacity is used for process steam; and the vast majority of the boilers are natural-gas-fired. The large amount of electric power used in aluminum processing is supplied from outside sources, rather than being generated on site. It is concluded that the boiler emissions are insignificant, compared to process emissions. Key Words and Document Analysis. 17o. Descriptors Pollution * Aluminum Industry jjoilers Capacity j5miss ion Inventories forecasting |/b* Identifiers /Open-Ended Terms Stationary Sources COSATI Fie Id/Group ^Availability Statement Unlimited 19. Security Class (This Report) UNCL 4V. Security Class (his UNCLASSIFIED 21. No. of Pages 22. Price USCOMM-DC 14»82-P72 ------- INSTRUCTIONS FOR COMPLETING FORM NTIi-35 (10-70) (Bibliographic Data Sheet based on COSATI Guidelines to Format Standards for Scientific and Technical Reports Prepared by or for the Federal Government, PB-180 600). 1. Report Dumber. Each individually bound report shall carry a unique alphanumeric designation selected by the performing organization or provided by the sponsoring organization. Use uppercase letters and Arabic numerals only. Examples FASEB-NS-S7 and FAA-RD-68-09. 2. Leave blank. 3. Recipient's Accession Number. Reserved for use by each report recipient. 4. Title ond Subtitle. 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