EPA-600/2-77-018
JANUARY 1977
Environmental Protection Technology Series
 INDUSTRIAL  WASTE AND PRETREATMENT  IN  THE
                        BUFFALO  MUNICIPAL SYSTEM
                              Robert S. Kerr Environmental Research Laboratory
                                       Office of Research and Development
                                      U.S. Environmental Protection Agency
                                              Ada, Oklahoma 74820

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                   RESEARCH REPORTING SERIES

     Research reports of the Office of Research and Development, U.S. Environmental
     Protection  Agency, have been grouped into five series. These five broad
     cateqories were established to facilitate further development and application of
     environmental technology. Elimination of traditional grouping was consciously
     planned to  foster technology transfer and a maximum interface in related fields.
     The five series are:
         1.    Environmental Health Effects Research
         2.    Environmental Protection Technology
         3.    Ecological Research
         4.    Environmental Monitoring
         5.    Socioeconomic Environmental Studies
     This report has been assigned to the ENVIRONMENTAL PROTECTION
     TECHNOLOGY series. This series describes research performed to develop and
     demonstrate instrumentation, equipment, and methodology to repair or prevent
     environmental  degradation from point and non-point sources of pollution. This
     work provides the new or improved technology required  for the control and
     treatment of pollution sources to meet environmental quality standards.
                             NOTE
To  order this publication, MCD-31,  Industrial Waste
and Pretreatment in  the  Buffalo  Municipal System,
write:


            General Services Administration  (8FFS)
            Centralized Mailing Lists  Services
            Bldg.  41,  Denver Federal  Center
            Denver, Colorado   80225

Please  indicate  the  MCD  number and  title of publication,

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        INDUSTRIAL WASTE AND PRETREATMENT

         IN  THE  BUFFALO MUNICIPAL SYSTEM
                Grant No.  R803005
                 Project Officer
              Thomas E.  Short, Jr.
            Source Management Branch
Robert S.  Kerr Environmental Research Laboratory
                 Project Advisor
                   Gary Otakie
           Municipal Technology Branch
       Office of Water Program Operations
             Washington, D.C. 20460
ROBERT S. KERR ENVIRONMENTAL RESEARCH LABORATORY
       OFFICE OF RESEARCH AND DEVELOPMENT
      U.S. ENVIRONMENTAL PROTECTION AGENCY
               ADA, OKLAHOMA 74820
                                                MCD-31

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                             ABSTRACT


      The  requirements  and  effects  of  combined  treatment of indus-
 trial and domestic  wastewater were investigated for the Buffalo
 Sewer Authority's sewerage  system.  The objectives of the study
 were:   Ij^to  establish an  industrial  waste  control program; 2)
 to  establish  an  equitable  cost  recovery and user charge system-
 and 3)  to evaluate  the effects  of  the local, state and federal
 requirements  on  the industrial  users  of Buffalo's sewerage system,

      A comprehensive industrial waste survey was performed to ob-
 tain the  required background information on industrial dis-
 charges.   This was  accomplished in three phases:  Phase I identi-
 fied the  industrial users and their types of discharges (ie
 domestic  and  process);  Phase II determined  the quality and quant-
 ity of wastewater from 85 of the larger industries in Buffalo-
 and Phase  III determined the quality  and quantity of wastewater
 from an additional  79  industries.

      Material balances were performed on Buffalo's sewerage sys -
 tern in  order  to  define  the volume  and waste characteristics of
 each class of user  (residential, industrial, inflow and infiltra-
 tion; .  This  data is essential  in  developing equitable cost re-
 covery  and user  charge programs and to properly establish incom-
 patible pollutants  discharge limits.

      Based upon  the findings of the Industrial Waste Survey and
 the  material balances, an industrial  waste  control program was
 developed.  Buffalo's program included revised sewer use regula-
 tions  coupled with  a permit system and monitoring program.

     A combination of ad valorem tax  and wastewater service
 charges, based on waste strength and  volume were used to recover
 the  cost of treatment.  In addition,  for industries discharging
 high strength wastes, surcharges were used to recover the in-
 creased cost of  treatment incurred.  An economic evaluation of
 these programs on the industrial users was then performed.  Eval-
uated were:  the economics of reducing incompatible pollutant
 loadings  (pretreatment vs joint treatment, and pretreatment vs
dilution)  and the economics of reducing compatible pollutant load-
 ings  (surcharge vs dilution and surcharge vs pretreatment).

     A 95,000 liter/day activated sludge pilot study was con-
ducted to  evaluate the effects that industrial users will  have on
                              111

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the treatment processes.  The metal concentrations in the effluent
and waste sludges were defined and the potential of credits for
the incidental removals of metals was explored.

     In the study area, three potential options were found for
the disposal of the sludge generated by Buffalo sewage treatment
plant:  soil conditioning, landfill, and co-disposal with refuse.
The industrial contributions of metals to the waste treatment
plant could affect the use of the first two options.  However, the
enforcement of Buffalo's Sewer Use Regulations will result in a
sufficient reduction of metal loadings to minimize the sludge
disposal problems due to its metal content.

     This report was submitted in fulfillment of Grant R803005-
01-2 by McPhee, Smith, Rosenstein Engineers for the Buffalo
Sewer Authority under the partial sponsorship of the Environmen-
tal Protection Agency.  This report covers the period from April
1, 1974 to December 31, 1975 and work was completed as of January
31, 1976.
                                IV

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                            CONTENTS
Abstract ..............................................       iii
Figures [[[   vii
Tables [[[    ix
Acknowledgments
   1 .   Introduction
   2 .   Conclusions
   3 .   Recommendations ...............................          12
   4.   Industrial Waste Survey .........................        15
   5.   Material Balance Around the Sewage System ...........    36
   6.   Development of an Industrial Waste Program ..........    43
   7.   Economic Assessment of Buffalo's  Joint Treatment ____    53
   8.   Combined Domestic and Industrial  Waste Treatment ____    76
   9 .   Municipal Sludge Disposal ...........................    93
  10 .   References .................................            !Q2
  11.   Bibliography ........................................   104
  12.   Appendices ..........................................   107
       A.   Characteristics of SIC  Categories ...............   108

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                             FIGURES


Number                                                      Page

   1    Development of an Industrial Waste Control Program..  18
   2    BSA Industrial Waste Survey Questionnaire - Page 1..  20
   3    BSA Industrial Waste Survey Questionnaire - Page 2..  21
   4    XYZ Example	  26
   5    Contributors to BSA's System	  37
   6    Organization Chart - Proposed Industrial Waste
        Section	  51
   7    Cost Recovery § User Charge System Under PL 92-500..  55
   8    Electroplater's Annual Costs for Meeting Effluent
        Limitations	  69
   9    Dilution Costs vs. Surcharges for the BSA System....  72
  10    Annual Costs for Pretreatment of Compatible
        Pollutants	  74
  11    Pilot Flow Diagram	  78
  12    BSA Process Diagram	  95
  B-1   BSA' s Sewer User Regulations	124
  C-l   Daily Cadmium Variation	171
  C- 2   Daily Chromium Variation	172
  C-3   Daily Copper Variation	173
  C-4   Daily Cyanide Variation	174
  C-5   Daily Lead Variation	175
  C-6   Daily Nickel Variation	176
  C- 7   Daily Zinc Variation	177
                              vn

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                             TABLES


Number

   1    Industrial Occurrence by SIC Divisions	  23
   2    Industrial Distribution by Volume	  23
   3    Toxic Pollutants - Wet vs. Dry Weather	'..'.  40
   4    Material Balances on the Buffalo Sewerage  System	  42
   5    BSA's Limited Discharge Limits	  46
   6    Summary of Pretreatment and Monitoring Schedule	  49
   7    Distribution of BSA's Construction Cost by Design
        Parameters	  59
   8    Distribution of BSA's 0§M Costs by Design	
        Parameters	  60
   9    First Year Cost Distribution - BSA System...........  61
  10    Application of Industrial Waste Rate  Formula	  64
  11    Cost of Pretreatment Facilities by SIC Category	  66
  12    Requirements for Municipal Heavy Metal Treatment	  67
  13    Tertiary Two-Stage Lime Treatment Costs	  68
  14    Electroplater's Options for Meeting Effluent
        Limitations	  70
  15    Cost of Dilution vs.  Surcharge - Examples	  71
  16    Reductions from Pretreatment	  73
  17    Example of Industrial Surcharges	  75
  18    Trace Element Balances on BSA's Pilot Plant	  81
  19    Characteristics of Pilot Exit Streams - Summary	  84
  20    Average Influent Cone.  § Removals for Pilot Plant
        Operation	  85
  21    Surchargeable Loadings in the BSA System	  87
  22    Summarized Sludge Quantities from Pretreatment	  89
  23    Pretreatment Effects  on BSA's Sludge	  90
  24    Examples  of Industrial Sludge Characteristics	  91
  25    Annual  Costs for Solid Waste Disposal Facility	100
  A'l    Characteristics of SIC Categories	109
  C-l    November's Pilot Plant Operational  Data	157
  C-2    December's Pilot Plant Operational  Data	160
  C-3    Daily Trace Element  Concentrations	163
  C-4    Waste Primary Sludge  Characteristics	169
  C-5    Waste Secondary Sludge Characteristics	170
                              IX

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                         ACKNOWLEDGMENTS


     We gratefully acknowledge the contributions to the overall
project by the staff of McPhee, Smith, Rosenstein Engineers in
particular Mr. Irwin Rosenstein for his overall direction and
supervision, and Miss Deborah Brody for the physical preparation
of this report.

     The assistance and cooperation of the Buffalo Sewer Author-
ity; Mr. Gillman Laehy, General Manager, Mr. Richard Kressin,
Mr. Daniel Tattenbaum, and Mr. Norbert Gonglewski is gratefully
acknowledged.

     Dr. Thomas E. Short of the Robert S.  Kerr Environmental
Research Laboratory, Project Officer and Mr. Gary Otakie of the
Municipal Construction Division, U.S.  Environmental Protection
Agency, provided valuable guidance throughout the project.  Ap-
preciation is expressed to Mr. Charles H.  Sutfin and Mr. William
A. Whittington of the Municipal Construction Division and to
Mr. Thomas Shannon of Region II, U.S.  Environmental Protection
Agency for all their cooperation and assistance.

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                           SECTION  1

                          INTRODUCTION
PURPOSE AND SCOPE

     Buffalo, like many other industrialized communities,  treats
both industrial and residential wastewaters at its sewage  treat-
ment plant.  While combined treatment can be mutually beneficial
to both the users and the treatment agency, it can also result
in the need for additional planning and administration to  operate
the facility.  In addition, the publicly owned treatment works
is subjected to more stringent discharge criteria.  A publicly
owned treatment works, which accepts industrial waste, must
1) define the cost of treatment then equitably proportionate it
to its users; 2) define what is acceptable for discharge to its
sewerage system then enforce it; and 3) insure that the methods
used in items 1 and 2 are in compliance with its National Pol-
lutant Discharge Elimination System (NPDES) permit and EPA's
requirements resulting from the acceptance of federal aid for
the facility's construction.

     In concert with these requirements, the objectives of this
study were: 1) to establish an industrial waste control program,
including the revision of Buffalo's existing sewer use regula-
tions; 2) to establish an equitable cost recovery and user charge
system; and 3) to evaluate the effects of the local, state and
federal requirements on the industrial users of Buffalo's sewer-
age system.

     The first task was to obtain a data base from which these
programs could be developed.  Extensive information relative
to industrial discharges was obtained through a comprehensive
industrial waste survey.  In addition, analyses were performed
on composite samples from outside sewer districts tributary to
the system and on a residential section of the city to determine
their contributions.  The treatment plant's influent waste char-
acteristics were determined and the effluent and sludge charac-
teristics were projected for Buffalo's secondary treatment
plant, from data obtained during the pilot study on the Buffalo
Sewer Authority's new treatment facility which is slated for
completion in 1980.

     An industrial waste control program was developed which

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 included the revision of the existing sewer use regulations and
 the adoption of a permit and monitoring program to enforce the
 regulations.  In establishing this program, consideration was
 given to the various alternatives for controlling industrial
 discharges and to the legal authority necessary to enforce the
 control measures.  In addition, the use of the proposed Federal
 Standards of performance and pretreatment standards for indus-
 trial discharges into publicly owned treatment works was evalu-
 ated for use in the Buffalo Sewer Use Regulations.

      The use of ad valorem tax and wastewater service charges,
 based on waste strength and volume,  were evaluated to establish
 an equitable cost recovery and user charge system for Buffalo.
 In addition, the economics for reducing the compatible and in-
 compatible pollutants loadings from industry were evaluated.

      The joint treatment of industrial  and residential waste-
 water can offer  both advantages  and  disadvantages to a publicly
 owned treatment  works.   As  part  of this  study,  an investigation
 was  made into  the  effect that  various  industrial  discharges  have
 on the overall  system.   Three  of the effects given special con-
 sideration in  the  study  were:   1)  the  anticipated reduction  in
 pollutants  loading  due  to  the  enforcement  of Buffalo's Sewer
 Use  Regulations;  2)  the  possibility  of  granting credits  to in-
 dustrial users based on  the incidental  removals of incompatible
 pollutants  at  Buffalo's  waste  treatment  plant;  and 3)  the  effect
 that the inclusion  of industrial waste  has  on Buffalo's  sludge
 disposal options.

 THE  BUFFALO SEWER AUTHORITY SYSTEM

      The City  of Buffalo is  located  in northwestern  New  York
 State,  CErie County)  encompassing  42.7  square miles  along  the
 northern end of  Lake  Erie  and  the  Niagara  River.   The  city
 and  surrounding  area  has a  gentle  slope  with a  maximum elevation
 of 698.95  ft.  in the  northeast and a minimum of 571.84  ft. at
 lake  level.

     The  city is approximately 89.5 percent  developed  accord-
 ing  to the  1963 Land  Use Survey,   The majority  of  the  undevel-
 oped area is comprised of inland waterways  and  vacant  land.

     The Great Lake's Water  Basin, in particular Lake  Erie  and
 the Niagara River, is used by Buffalo and the surrounding  com-
munities as both a source of drinking water  and wastewater dis-
posal.  Tributary to  the Basin and flowing  through Buffalo are
 three other waterways which are  used to  convey wastewater:
the Buffalo River, the Cazenovia Creek and the  Scajaquada  Creek.

     The population of the City  of Buffalo has decreased from
 Vts peak of almost 600,000 during the  1950's to its present

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level of 460,000.  Population projections by various state and
local agencies show Buffalo's population to remain essentially
unchanged over the next thirty years.   On the other hand,  the
population of the metropolitan area has followed the national
trend by increasing to its present level of 1.3 million persons.
Only a slight increase is projected for the future.

     Buffalo and its surrounding area can be considered to be
highly industrialized.  The type of industries range from  steel
mills and oil refineries to flour mills and dairy processors.
As can be expected, the waste generated varies widely in volume
and complexity.  While generally the larger industries treat
and discharge directly to waterways, substantial industrial
wastewater is discharged to the Buffalo Sewer Authority's  system
for conveyance and treatment.

     In 1935, the Buffalo Sewer Authority was formed to manage
and regulate the City's wastewater disposal efforts.  Soon
thereafter, in July of 1938, the Bird Island Treatment Plant
went on stream.  At the present time,  a secondary treatment
plant with facilities for the removal of phosphorus is under
construction.  Its completion date is set for early 1980.   The
present flow averages 643 megaliters/day (170 MGD) and the de-
sign flow for the new plant is 681 megaliter/day  (180 MGD).

     Erie County undertook a county-wide sewerage study to de-
velop a master plan for the construction of sanitary sewage
treatment and collection systems.  A sub-regional plan was
adopted whereby adjacent sewer districts are combined for treat-
ment at one plant.  Under this plan the Buffalo Sewer Authority
will treat wastewater from certain outside sewer  districts.  At
the present time, the Authority is treating approximately 113.6
megaliters per day from communities outside of Buffalo.  The
projected plan has some of these communities dropping out of
the Buffalo system as new plants are constructed, and others
joining the system once their interceptor sewers  are built.

     An average of 75.7 megaliters per day of extraneous flow
enters the Authority's system via the Scajaquada  Creek.  The
creek is a natural waterway flowing westward through the city and
terminating at the Niagara River.  Originally, the creek re-
ceived only overflows during wet weather, however, direct dis-
charges were gradually made as storm, relief projects were im-
plemented.  The Authority enclosed the creek at the city line
and now utilizes it as an integral part of its sewer system.
The Buffalo Sewer Authority presently has a project underway
and others on the drawing board, to eliminate this source of
extraneous flow.

     The collection system of the Buffalo Sewer Authority is
largely combined sewers.  The most recent comprehensive sewer-

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 age study,  found that  96%  of  the  city's  sewers  were of the
 combined type.  In addition, 603 of  the sewers were  constructed
 prior to 1910 with only 8%  installed since  1941.   Many of the
 sewers were installed at a  minimum grade  and  as  a  result, solids
 tend to settle out in them  during  dry weather.

      As can be expected, after considering  the age of the sewers,
 the area's relatively   flat topography, and the  high water table,
 infiltration is a problem.  The Authority's consultants have
 estimated that ground water infiltration  city-wide,  to average
 1380 liters per hectare per day.

      Ground water infiltration is  not the only source of ex-
 traneous flow in the Authority's system.  River  water,  on oc-
 casion,  enters the system through  overflows which  either have
 no backwater gates or through gates  which are jammed open by
 debris.   The city presently has seventy outfalls to  open water-
 ways.   The average yearly inflow from these overflows is approx-
 imately 4.2 megaliters per day.
Leonard S, Wegman Co., Inc,  Comprehensive Sewer Study for the Buffalo
 Sewer Authority,  Buffalo, New York,  1973.  p.IV 1 - IV 22.

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                            SECTION 2

                           CONCLUSIONS
INDUSTRIAL WASTE SURVEY

     1.   To satisfy the federal construction grant and National
Pollutant Discharge Elimination System permit's  requirement,
an industrialized community must perform an industrial waste
survey.

     2.   The industrial waste control, cost recovery and user
charge programs as well as the industrial waste  survey itself,
can be facilitated by conducting the industrial  waste survey  in
phases.   In the Buffalo survey, the first phase  was identifica-
tion of all industrial users, the second phase was sampling of
the most significant industrial contributors, and the third phase
was follow-up sampling of the remaining significant industries.

     3.   Industries using the municipal system can be identified
by using existing sewer files, city and state industrial direc-
tories,  tax and water records, and telephone yellow pages.

     4.   Industrial waste questionnaires were sent out to obtain
background data.  However, 90% of these had  to be followed up
by phone calls or scheduled plant visits to  obtain questionnaires
which were accurately completed.

     5.   An effective method  for improving  the efficiency in
obtaining reliable data from  the questionnaires, particularly
those sent to non-manufacturing establishments, was to  include a
cover letter with the questionnaire explaining how the question-
naire relates to specific types of establishments.  The  letter
would direct their attention  to significant  areas of  concern
thus aiding in  the completion of the  questionnaire.

     6.  The identification phase of  the industrial waste survey
identified  1020 of  the 1466  industries  as  being  "dry"  (no pro-
cess water) and an additional 26 as being  either  out  of  business
or synonymical with  other firms.

     7.  A public relations program is  an  important part of  an
industrial waste survey.  It  should be  initiated  as soon as  pos-
sible and maintained at all  times since  it  stimulates  industrial

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 cooperation and provides additional input for the entire indus-
 trial waste program.

      8.  The Buffalo Sewer Authority determined that because of
 the large amount of resources, expertise and short time duration
 required for the initial sampling and analysis program, it was
 cost effective to utilize a consultant to perform the work under
 the Authority's supervision.

      9.  The initial sampling and analysis of the industries dis-
 charging into the sewerage system was conducted by the city, in-
 stead of utilizing industrial self-monitoring for three reasons;

          A.   This would provide  more reliable data to serve as
 a baseline  for its continuing program.
          B.   The data obtained would be  more consistent in that
 the same sampling and analytical procedures  would be used.
          C.   Economy of scale can be realized by having one cen-
 tral organization conduct  all the sampling and analysis required.

     10.   The  results  of the sampling and analysis program  pro-
 vides  the data necessary to develop  cost recovery,  user charges
 and industrial  waste  control  programs.

     11.   An  in-plant  investigation which physically locates  dis-
 charge  points,  water  sources  and sampling locations  is  essential
 to  the  success  of the  sampling phase of  the  industrial  waste
 survey.

     12.   Industries  generally have more  than one  connection  to
 a sewerage system, which is an important consideration  in  plan-
 ning an industrial sampling program.   In Buffalo,  the  average
 for the  initial  85 industries sampled was  2.3  connections/indus-
 try.

     13.   It  is  important to obtain more  than one  composite  sam-
 ple per  industry  to  insure that  the  data obtained accurately
 estimates the  industry's normal  discharge.   For  the  85  indus-
 tries initially  sampled in Buffalo's survey,  the  average number
 of  daily  composite samples/connection was  3.1.

     14.  Although  only  85 out of  Buffalo's 420 wet  (process
wastewater) industries  were sampled, this  amounted  to 851 of
 the  industrial  flow and  served as a  good  basis for projecting
 loadings for the  remaining industries.

     15.  The total cost  for developing Buffalo's  industrial
waste program was  approximately  $450,000.  The manpower alloca-
tion for each phase was:

         Phase  I  - 6450  hours or  4.5 hours/industry to  identify
the  1466 industrial users at  an estimated  cost of $75/industry.

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         Phase II - 11,600 hours or 138 hours/industry to  sample
and analyze 600 composite samples for 85 industries  at an  esti-
mated cost of $2,100/industry,  plus capital expenditures.

         Phase III - Similar to Phase II, however there are
only minor capital expenditures.

    The manpower allocation for developing the Industrial  Waste
Control Program was:

         Sewer Use Regulation - 400 hours at an estimated  cost
of $11,000.

         Cost Recovery and User Charge System - 800 hours  at an
estimated cost of $22,170.

         Monitoring Program - 100 hours at an estimated cost of
$2,400.

MATERIAL BALANCE

    16.  In order to establish meaningful discharge limits and
to equitably  distribute  the cost of treatment to all users of
its sewerage  system, a publicly owned  treatment works must de-
fine the volume  and waste characteristics of each class of user,
both point source and non-point source.  This can be accomplished
through a sampling program for  industrial and domestic discharges
and stormwater.

    17.  The  industrial  sampling,  residential sampling, and the
sampling at the  treatment plant provided the basis  for a mater-
ial balance on Buffalo's sewerage  system.  The  following are  the
results of the material  balances for  dry weather flow:

         Over 83%  of the arsenic,  cyanide, cadmium, chromium,
copper, lead, nickel and zinc  are  contributed by industry.
Although only 5% of the  mercury present was  attributed to  indus-
try, the  57%  contributed by  the Scajaquada Creek may  be of an
industrial origin.

          Industry contributes  34%  of the BOD,  40% of  the COD,
27% of the SS,  and  38% of the  phosphorus loadings.

     18.   Based on an analysis  of the sewerage  treatment paint's
influent  during  wet and  dry  weather,  it was  concluded that
stormwater did contribute significant quantities of lead and
zinc.   However,  the stormwater was not found to contribute
measurable quantities  of Cd,  Cr,  Cu,  Ni, CN.

     19.   The  heavy metal content of the sewage  could  result in
high metal  concentrations in the sludges and could  have an ef-
fect  on Buffalo's digestion process and sludge  disposal options.

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 Accordingly, any operational problems caused by these metals would
 have to be reduced by an effective industrial waste program.

 INDUSTRIAL WASTE CONTROL PROGRAM

     20.  It is necessary for a publicly owned treatment works in
 an industrial community to have a comprehensive industrial waste
 control program in order to meet today's more stringent require-
 ments.

     21.  An enforceable sewer use regulation coupled with a
 permit system and a self-monitoring schedule was adopted as a
 most practical and economical industrial waste control program
 for Buffalo's needs.

     22.  Once an industrial waste control program has been estab-
 lished, it is essential  that the publicly owned treatment works
 conduct or require a  scheduled  monitoring program.

     23.  Self-monitoring by each industry is more effective when
 the municipality has  conducted  the  industrial waste sampling to
 establish a baseline  for comparison with subsequent self-monitor-
 ing data.   Buffalo's  monitoring program  includes self-monitoring
 by industry as  a basis  for  its  continuing cost and  control pro-
 grams.   The treatment agency must periodically spot check the
 industrial  discharges to insure that  the information being sup-
 plied by the  industrial  self-monitoring  program is  accurate.

     24.   Based  on the evaluation of the  proposed federal  stan-
 dards of performance  for industrial discharges  into publicly
 owned treatment  works, the  use  of production to  establish efflu-
 ent criteria was  not  recommended because it  is  complicated,  ad-
 ministratively  difficult to handle, time consuming,  and  not  com-
 pletely understood  by all the personnel  that would  be  frequently
 using it.   The use  of concentration as a base  for establishing
 discharge limits  is more practical  from  an administrative  point
 of  view, however,  it  requires a more  rigid system of  control  to
 include monitoring  and plant  inspections.

    25.  In Buffalo,  the  use of a wastewater service  charge
 based upon the waste's volume and strength was found  to be the
most equitable method for recovering  the  cost of treatment from
 all the classes of users.

    26.   Since Buffalo's treatment plant construction  is regu-
 lated by PL 84-660, the use of  an ad valorem tax in conjunction
with the wastewater service charge,  was  found to be a good method
for distributing the costs  for  that portion  of the treatment
plant set aside for future use and extraneous flow.

    27.   It was found to be cost effective to use one rate for

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the domestic strength waste rather than charge  each user  based
on their individual waste strengths.    A surcharge  would  be
levied on those users having waste strengths  in excess  of normal
domestic waste.

    28.  It was found to be cost effective for  industries to  pre-
treat individually rather than having Buffalo expand its  treat-
ment capability to remove incompatible pollutants.

    29.  For seven of the nine electroplaters investigated in the
Buffalo system, the economics favored pretreatment  rather than
dilution for meeting incompatible pollutant discharge limits.
For the other two electroplaters, dilution was  favored  since  they
were only slightly in excess of the discharge limits.

    30.  The publicly owned treatment works will be able  to  re-
cognize the industries using non-contaminated water for dilution
purposes by comparing an industry's present water consumption to
its historical usage.

    31.  For the Buffalo system, it was found to be cost  effec-
tive for industries discharging high strength compatible  waste,
to pay the surcharges, rather than dilute their waste.

    32.  It is cost effective for some of the industries  using
the Buffalo system to use pretreatment of compatible pollutants
and reduce or eliminate their surcharges.

    33.  From the results of the industrial waste survey, it
was concluded that many industries could reduce or eliminate
their surcharges by making simple, low cost, in-plant process
modifications.

    34.  The cost effectiveness of pretreatment or dilution by
industries either to meet sewer use regulations for  incompatible
pollutants or to reduce user charges and or surcharges for com-
patible pollutants will vary with each case.  Important criteria
are:  quantity discharged, strength of waste and the correspond-
ing dilution required, land availability for pretreatment faci-
lities, and sludge disposal problems resulting from pretreatment.

    35.  For some industries that presently discharge directly
to a receiving stream, it will be cost effective for them to
discharge all or portions of their wastewaters to a publicly
owned treatment works.  Since this study was initiated, one in-
dustry that previously had a direct discharge to a receiving
stream has entered the Buffalo system and two others are nego-
tiating to redirect substantial portions of their discharges to
the Buffalo system.

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 REMOVAL OF METALS

     36.   The results  of the pilot plant  study  indicated  that
 better than 601  removals could be expected  for lead, chromium,
 and copper.   Smaller,  but significant  removals, were also ob-
 tained for zinc  and cadmium while the  removals of nickel and
 cyanide were insignificant.

     37.   Based on these removals,  the  Buffalo  Sewer Authority
 has a  basis  for  predicting credits  for industries that will
 reduce the degree of  pretreatment required.

     38.   During  the pilot study,  significant incidental  removals
 of  heavy metals  were  obtained,  however,  the results were highly
 variable with the standard deviations  of the removals ranging
 from 17.8 for nickel  and 29.9  for lead.

     39.   This incidental removal  of heavy metals will result in
 high metal concentrations in the  sludge  and could have an effect
 on  Buffalo's  digestion  process  and sludge disposal options.

     40.   Since Buffalo's new secondary treatment plant was de-
 signed for combined treatment,  the industrial  contribution of
 compatible pollutants  is necessary for its efficient and econ-
 omical operation.

     41.   The  enforcement of  Buffalo's  sewer use regulations will
 result in a  substantial  reduction of the metal content in the
 influent to  the  waste  treatment plant  due to industrial pre-
 treatment and reduce  the likelihood of any operating problems
 caused by metals.  The  projected  decrease will be greater than
 48%  for  copper,  lead, nickel,  zinc, chromium and cadmium.

 SLUDGE

     42.   The  projected  decrease iji the influent's metal concen-
 tration   due  to  industrial pretreatment will result in an im-
proved sludge quality which  may be suitable for disposal as a
 soil conditioner.  The  quantities of copper, lead, nickel,  zinc,
chromium  and  cadmium in  the  sludge will be reduced by at least
 501 due  to industrial pretreatment.

    43.  The  sludges resulting from industrial pretreatment will
have high metal  concentrations and proper disposal methods  will
have to be employed.   At  the present time in Buffalo, landfill
disposal of this  type of  sludge is broadly utilized.

    44.  Buffalo  has  three options for its sludge disposal:
landfill, soil conditioning, co-disposal  with refuse.

    45.  Of these three options, the industrial metal contribu-
                              10

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tion^significantly affects only the use  of  the  sludge as a soil
conrli ti onpT .
                              11

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                            SECTION  3

                         RECOMMENDATIONS
INDUSTRIAL WASTE SURVEY

      1.  Where possible, an industrial waste survey should be
conducted before the design of the treatment plant has been com-
pleted so that problem areas can be solved during the design
stage rather than during the operation.

      2.  In-plant investigations should be an integral part of
an industrial waste survey.  They should be conducted far enough
in advance of the sampling stage so that problems located by the
in-plant investigation can be solved without interfering with
sampling.

      3.  When time and money permit, the publicly owned treat-
ment works should conduct on its own, the detailed sampling and
analysis stage of the industrial waste survey to insure that
the results obtained are accurate.

      4.  Before sampling and analysis is undertaken, strict
quality control procedures should be adopted for taking and anal-
yzing the samples.  This will help to avoid legal problems stem-
ming from the contesting results.

      5.  The sampling and analysis program for each industry
should cover more than one day.  This will help to insure that
the data obtained, accurately estimates an industry's normal
discharge.

MATERIAL BALANCES

      6.  The publicly owned treatment works should define the
waste strength and volume for all classes of users, both point
source and non-point source in its sewerage system.  These are
important considerations in establishing the discharge limits
and an equitable cost recovery and user charge system.

      7.  Publicly owned treatment works can conserve their
financial and manpower resources by approaching the problem
systematically and by only performing detailed investigations
on those users which have an effect on the sewerage system.  For

                               12

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example, the BSA initially sampled only 85 of the 420 wet indus-
tries and used the resulting data to develop its cost and indus-
trial waste control programs.  The 85 industries sampled repre-
sented 851 of the industrial flow and provide a good data base
for establishing these programs.

INDUSTRIAL WASTE CONTROL PROGRAM

      8.  Publicly owned treatment works in industrialized
communities  should develop a comprehensive industrial waste
control program.  This program should not only establish dis-
charge criteria, but also  include a  method  for  insuring  that
these criteria  are  met.

      9.  Every publicly owned treatment works should have the
power and authority to enforce its regulations on all users of
its system.

     10.  When industry performs  the monitoring function, the
publicly owned treatment works should spot check the industrial
discharges to insure that the data supplied is accurate.

     11.  The use of production units to establish discharge
limits is not recommended.  Based on an evaluation of the pro-
posed federal standards of performance for industrial discharges
to publicly owned treatment works, it was felt that  the use of
production units would result in  greater administrative problems,
paper work, and cost than would a concentration basis.

     12.  When using concentrations  to define discharge criteria,
the publicly owned treatment works should strictly enforce its
control program through monitoring and inspections to identify
diluters.

METALS REMOVAL

     13.  A publicly owned treatment works should evaluate its
potential for credits for the incidental removal of  incompatible
pollutants in its treatment plant.   These credits can be used
to lower the industrial pretreatment requirements.

     14.  If the heavy metal removals obtained in Buffalo's
system are to be used to establish credits, then the high degree
of variability in the results should be taken into consideration
in establishing these credtis.

     15.  In establishing a credit,  the publicly owned treatment
works should evaluate the effects of the incidental  removals
on their sludge process and disposal options.
                               13

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SLUDGE

     16.  The sludges resulting from industrial pretreatment
should be disposed of properly.  Necessary safe guards should
be established where they are lacking, to insure that the sludge
disposal is environmentally sound.  Publicly owned treatment
works should be  cognizant of industrial pretreatment sludge
disposal practices and should coordinate with the various solid
waste agencies.

     17.  In light of the increasing fuel costs and air pollution
requirements, the Buffalo Sewer Authority should re-evaluate its
present sludge treatment and disposal methods.

     18.  A detailed investigation should be performed to deter-
mine which sludge treatment process and disposal method will be
cost effective for Buffalo's secondary treatment plant.  The
scope of this investigation should be much broader than this
study's investigation of how industrial waste effects the sludge
disposal options.

     19.  From the data obtained during the industrial waste
survey, it is recommended that more research efforts should be
directed in the following two areas:

          A.  Development of more accurate and instantaneous
methods of making analytical determinations of toxic materials.

          B.  Development of more data on removal mechanisms
for heavy metals.  With the data already compiled by this and
other work, studies should be made on a full sized secondary
plant for at least a year.
                              14

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                             SECTION 4

                      INDUSTRIAL WASTE  SURVEY
INTRODUCTION
     In addition to sewage from residential sources, many of the
country's publicly owned treatment works (POTW) also accept in-
dustrial wastewaters.  Because industrial wastes exhibit wide
variations in strength and toxicity, the inclusion of these waste
waters into a POTW necessitates additional planning and restric-
tions on the use of the sewerage system in order to protect the
sophisticated advanced treatment processes.  When a POTW treating
industrial wastewaters accepts Federal Aid for the upgrading or
construction of its sewerage facility, additional requirements
are placed on that POTW.  Three of these requirements are:

     1.  Pretreatment:  Pretreatment of industrial waste is re-
quired in varying degrees to protect the sewerage system from
damage and upset and also to insure that pollutants do not pass
through the treatment works untreated.

     2.  Recovery of Construction and 0§M Costs:  The intent of
this requirement is to insure that every user of- a sewerage sys-
tem pays his fair share of the treatment costs and that industry
is not subsidized in the construction of the sewerage facility.
This is accomplished by recovering costs in two areas: 1) con-
struction or capital, and 2) operation and maintenance costs
(0§M).   Under Public Law 92-500, industrial users of the POTWs
must repay their share of the construction costs funded by feder-
al grants over a defined period of time not to exceed 30
years.   In some instances, the portion of the construction costs
funded by state grants may also require recovery.   In addition to
the construction costs, the annual 0§M costs must be recovered by
some type of user charge system whereby each user or class of
user pays their proportional share of the 0§M costs.  Since the
inclusion of industrial waste in a POTW system usually creates
more than one class of user, the user charge system, in order to
be equitable, must take into account the variance in waste char-
acteristics of its users.   This is normally accomplished by bas-
ing the charge on flow rate, waste strength, and volume.

     3.  NPDES Permit:  All POTWs must secure a NPDES permit to
legally discharge their treated effluent.   In cases where the
                               15

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POTW treats  industrial waste,  an  additional section  (IV) entitled
"Industrial  Waste  Contribution to Municipal System"  is required
for every major  contributing industry.  A major contributing in-
dustry is defined  as one  that:  1) has a flow of 50,000 gallons
or more per  work day; 2)  has a flow greater than 5%  of the total
flow received at the treatment plant; 3) has a toxic material in
its waste stream;  or 4) has a  significant impact, either singly
or in combination  with other contributing industries on a public-
ly owned treatment work or on  its effluent.  Included on the form
is production information as well as the industry's waste strength
and volume.

     In order for  the public treatment works to meet these re-
quirements,  it must define who uses the system and the magnitude
of the industrial  contribution.  To accomplish this, the POTW
performs an  industrial waste survey (IWS) which can be approached
in three ways.  Common to all  three approaches, is the identifi-
cation of the industries using  the system.  Once identified, the
first method then  estimates the specific industrial contributions
from waste characteristics published in literature.  The second
method goes one step further by requiring that all major con-
tributing industries submit to  the POTW analysis of their waste
streams for review.  The  third method differs from the second in
that the POTW itself samples and analyzes each major contributing
industry's discharge.

     The Buffalo Sewer Authority  (BSA) elected to use the third
method in performing its  industrial waste survey for two reasons.
The first was that while  estimates may be used to satisfy Part
IV of its NPDES permit, for the first year, specific analytical
data is then required by  the second year and therefore the first
method is only appropriate initially.  The second reason for
using method three was the questionable reliability of the re-
sults obtained from method two.  By the BSA scheduling, sampling
and analyzing the  industrial waste stream themselves, they mini-
mized the possibility of  the results being obtained on non-
typical production days or having some of the discharge and flow
data omitted.

     Shown in Figure 1 is the  flow diagram the BSA used in devel-
oping its industrial waste control program.  The IWS segment,
outlined in dashed lines  in Figure 1, was completed in three
phases:   identification,  cross  section sampling, and follow-up
sampling.

PHASE I - IDENTIFICATION  OF CONTRIBUTING INDUSTRIES

     This first phase of  Buffalo's IWS was an inventory stage
and defined the magnitude of the following two phases.  The first
step was to compile a complete  list of all types of non-residen-
tial users of the  BSA system.  The types of industries ranged
from restaurants and laundries  to steel mills and oil refineries,

                               16

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and included establishments in sewer districts outside the city
limits, but tributary to the Authority's system, as well as the
establishments within the city's boundaries.

     Establishing the list of contributors was complex and time
consuming.  Through contacting various organizations and agencies,
five primary sources were identified and subsequently used to
establish the list of contributors.  These were:

     1.  Existing sewer authority files
     2.  City and State industrial directories
     3.  Water records
     4.  Tax records
     5.  Telephone yellow pages

     From these sources, a complete list consisting of 343 com-
mercial and 1,123 industrial establishments was obtained.  By
preliminarily screening this list for known inconsequential con-
tributing establishments, it was possible to reduce the number
of establishments requiring further investigation  to 631.

     The next task was to evaluate further the remaining indus-
tries  in order to estimate the characteristics of  the waste dis-
charged to the sewer.  This screening process would allow a de-
cision to be made as to which industries would require sampling
and analysis.  To obtain the specific data required to make this
evaluation, an industrial waste questionnaire was  developed for
circulation to the selected industries.  To stimulate cooperation
and so that the industries would be acquainted with the  IWS, a
news release explaining the purpose and goals of the program,
as well as the federal regulations requiring  it, was published
for one week in the local newspapers and included  with the three
page questionnaire sent to the 631 industries.

     The first two pages of the questionnaire,  Figures 2 and 3,
requested information regarding production, employment,  water
use and number and location of sewer connections.  The third
page was for the chemical analysis of the plant's  discharge and
was only to be completed if a previous  analysis had been per-
formed.

     While waiting for the return  of the completed questionnaires,
water  data was obtained from the various water  agencies  for all
the establishments.  In addition,  the establishments were pre-
liminarily placed in Standard Industrial Classifications^  (SIC)
and a  map atlas and coordination system for locating the estab-
lishments and their points of discharge was prepared.  In order


^ecutive Office of the President.  Standard Industrial Classification
 Manual. Washington B.C.  1972 edition.  649p.


                                17

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                               FIGURE I-DEVELOPMENT  OF  AN
              EVALUATE
              LEGAL a
              FINANCIAL
           CONSIDERATIONS
                              EVALUATE
                               P. 0. T. W.
                              AUTHORITY
                               REVIEW
                               EXISTING
                              ORDINANCE
   PROJECT
REQUIREMENTS
 COMPILE
 MASTER
 LIST OF
INDUSTRIES
                              COMPILE
                             WATER DATA
                               OBTAIN
                             INDUSTRIAL
                             BACKGROUND
                             DATA THROUGH
                            QUESTIONNAIRE
  INDUSTRIAL
CATEGORIZATION
     (SIC)
                                       PREPARE
                                     PRELIMINARY
                                      MAP ATLAS
CLASSIFICATION
OF INDUSTRIES
 (WET, DRY)
                  REVIEW
                 E. P. A. a
                 N.Y.D.E.C.
                GUIDELINES
                                  18

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INDUSTRIAL WASTE  CONTROL PROGRAM
                            DEVELOPMENT
                                OF
                           COST RECOVERY
                            a USER CHARGE
                              SYSTEM
       i
DEVELOPMENT
OF INDUSTRIAL
   WASTE
 ORDINANCE
      COMPILATION
         OF
       RESULTS
               IN-PLANT
             INVESTIGATION
SAMPLING
   a
ANALYSIS
                          RECOMMENDATION
                          (SURCHARGE OR
                          PRETREATMENT)
                                                  1
                                     RECOMMENDATIONS
               COMPLETE
                 MAP
                ATLAS

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                                     Figure 2.                 Sic #
                             BUFFALO SEWER AUTHORITY        Map*
                               INDUSTRIAL WASTE SURVEY       Loc#
                                    Sheet 1 of 3                S.D.
                                                                (For BSA use only)

Company Name_		___	_	.	

Addre s s	—	   ._

Representative	__Title	Phone  No.	

Hours of operation/day	Days of operation/week	
No. of employees:  Shift No. 1	Shift No. 2	Shift No. 3_

Type of Business: (Manufacturer,  Distributor or Retail)	
           RAW MATERIALS                            AMOUNT PER YEAR
             PRODUCTS                              AMOUNT PER YEAR
Type of Process:   Continuous	   Batch	

Industrial Wastes:

  What waste products are disposed to:  Sewer	 Other_

  Is discharge to sewer:         Intermittent	      Steady	
                             Quantity/day	 Est. or measured	

  Are wastes pretreated?  If so, which and how:	

Plant Sewer Connections to BSA

       Size & Shape         Material       Location in Plant       Connected To

(1)     _____	.	
(2)     __	,	
(3)	
Are maps showing sewer connections available?.
ADDITIONAL INFORMATION TO BE SUPPLIED ON YOUR LETTERHEAD.

                                       20

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                                       Figure 3.
                               BUFFALO SEWER AUTHORITY
                               INDUSTRIAL WASTE STTRVEV
                                     ^ Sheet 2 of 3
 ANNUAL VARIATION IN OPERATION

 Is there a scheduled  shutdown?	

 Is production seasonal?	
   If so:
Period of full production
   If not:

 WATER USE

 Source (s) of water
Period of limited production.

Period of no production    _

Employees  (No.)  Max.	

                 Min.	

Average # of employees	
 If from an agency. Account #_

 Water used for:

                Sanitary
                Air Conditioning
                Process water

                Jacketed cooling water
                Othdr	
Period of max. water use.

Period of min. water use
Water disposal other than sewer.

Is water consumed in product?
Type and number of air pollution devices.
                                      When?
                                                               to
                                                               to
                                                              _to_
                                                       % of time at max..

                                                       % of time at min._
                                                        Recirculated
                                            . gpd
                                            . gpd
                                      Amount.

                                      Amount.
                                     % of total.
                                     Amounl/day_
Have the waste streams been previously analyzed?

Are radioactive isotopies used in your process?	

                                        21
                                    , Specify:.

-------
 to minimize  any confusion which may arise with industries having
 similar names or  locations,  the coordination system was used to
 reference all industries.  This was accomplished by assigning
 each  industry a code number  consisting of:  the number of the
 map atlas sheet on which it  was located and its location number
 on that sheet.  When a distinction was to be made between an
 industry's various connections to the BSA's system, each connec-
 tion  was assigned a number which was included in the code.  For
 example, code number 24-12-3, refers to connection number 3 of
 industry number 12 on the 24th sheet of the map atlas.

      The response to the questionnaire was very poor and slow;
 one month after the initial mailing, only 251 of the industries
 had returned the forms.  Of  this 25%, approximately 601 were re-
 turned incorrectly completed or with much of the important data
 omitted.  A particular problem was encountered with the non-
 manufacturing establishments.  Many of these either did not re-
 turn  the questionnaire or returned them marked "non applicable".
 Many  of these firms did not consider their waste industrial in
 nature.   However,  service type establishments such as laundries,
 car washes,  barrel reclaimers and hospitals have wastes which
 may have high organic loadings, toxic materials or both and it
 is important to include these in the sampling and analysis phase
 of the survey.   To obtain the remaining questionnaires and the
 omitted data, it was necessary to follow up on 90% of the
 questionnaires  sent out.   Phone calls, sometimes repeated phone
 calls, and scheduled plant visits, where an engineer had to help
 the firm complete the forms, were utilized to obtain the data.
 In the case of non-manufacturing establishments, one method
 which was found to be effective in obtaining completed question-
 naires was to tailor the cover letter, included with the ques-
 tionnaire, to specific classes of establishments and thereby
 direct their attention to areas we considered significant in
 completing the questionnaire.  In retrospect, it was found that
 approximately 40% of the establishments returned the question-
 naire with some reminding by phone; 30% of the questionnaires
were  completed over the phone, and 30% of the questionnaires
were completed by plant visits.

     As completed questionnaires with production data were re-
 ceived,  their SIC classifications were finalized.   A small num-
ber of companies surveyed were found to be either out of business^
moved out of the service area, or were synonymical with other
firms.  This reduced the number of establishments to 605.  Table
 1, below,  shows the breakdown of industrial users of the BSA
system.
                              22

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         Table  1.   INDUSTRIAL OCCURRENCE BY SIC DIVISIONS
             Major Title
                              Occurrence
Division A
Division C
Division D
Division E

Division F
Division G
Division I
- Agriculture, Forestry, and Fishing
- Construction
- Manufacturing
- Transportation, Communiciations, Electric,
Gas, and Sanitary Services
- Wholesale Trade
- Retail Trade
- Services
2
4
417
14

35
31
102
                                                 Total
                                 605
     From the quantity of water used, the number of people em-
ployed, and the production data, the industries were classified
as wet (process wastewater) or dry (non-process wastewater),  of
which 185 were classified as dry.  The wet industries were then
further analyzed as to the type of raw materials used, the
quantity of water consumed and whether the discharges consisted
of process water or cooling water.  The industries' wastewaters
were then categorized into organic (toxic and non-toxic) and
inorganic (toxic and non-toxic).  Of the 420 industries classified
as wet, it was postulated that 309 should be investigated further.
The recommendations for further investigation is based on the
industry's potential as a revenue source or the industry's poten-
tial for violation of the existing or future sewer use regula-
tions.  Shown in Table 2 is the distribution of the 420 industries
by water usage.

            Table 2.  INDUSTRIAL DISTRIBUTION BY VOLUME
            Water Usage-MGD
                        Number
             >1 MGD
             >0.5
             >0.2
             < 0.05
             <0.05
.5
.2
.1
  4
  5
 19
 29
 32
331
     From these 309 industries, 85  (representing a cross-section
of the significant types of industries found in the Buffalo ser-
vice area) were selected for sampling in the next phase.  These
85 industries were the largest in their respective SIC categories
                                23

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 PHASE II - CROSS-SECTION SAMPLING

      The backbone of any industrial waste survey, is the sampling
 and analysis program.  The sampling and analysis of wastes from
 the major contributing industries within a large municipal system
 provides the data necessary to make sound engineering judgements
 and decisions with respect to:

      1.   Locating and identifying the major industrial discharges.
      2.   Locating and identifying violators of the Sewer Regula-
 tions .
      3.   Development of a  system of protection for the municipal
 treatment works to include the enforcement of a Sewer Regulation.
      4.   Recommending pretreatment systems which will satisfy the
 the POTW's  requirements;  and
      5.   The development  of an equitable cost recovery system for
 capital  as  well as operating costs.

      Phase  II  was  designed to  be a cross-section sampling program
 to speed up the development of the new Sewer Regulation,  cost
 recovery system and method for controlling the discharges into
 the BSA  system.   Even though the number of industries sampled was
 reduced  from 309 to 85  for this phase of the project, 11
 months were required for  completion.   For the 85 industries  sam-
 pled, 600 composite samples were analyzed and the data compiled
 for use  in  developing the  above programs.

      Since  the Phase II sampling program included 84% of  the
 total flow  from  Buffalo's  industrial community,  it  was  felt  that
 these results  would provide a  good background for estimating
 BSA's total  industrial  and commercial loadings.   The estimate
 was completed  by using  the  sampled results  in each SIC  category
 as an average  loading for  other industries  not sampled  but in the
 same  category.   If all  309  industries  were  to have been  included
 in this  phase,  the development of the above  mentioned programs
 would have  been  delayed a  year to eighteen  months.   The sampling
 and analysis program was carried out  in  four  stages  as  follows:

     1.    In-plant  investigation
     2.    Scheduling  of  industries  for  sampling
     3.    The sampling and  analysis
     4.    Reporting

     Each industry was handled as  an  individual case  and passed
 systematically from one stage  to  the next thereby providing con-
 tinuity to the program and  at  the  same time allowing  for any
 delays in the program due to poor weather, equipment  breakdown,
 and curtailment of production  by  industry.  A  map was used to
 divide the industries into  groups according to their  location
within the study area to minimize travel time  between locations.

     The in-plant  investigation played a major role  in the suc-

                               24

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cess of the sampling program.   Investigative teams,  consisting
of an engineer and technician,  revisited each industry to  deter-
mine the following:

     1.  The number of discharge lines to the BSA system and the
type of waste being discharged  through them:

         Because of the age of  most of the industrial buildings
in Buffalo and the lack of information with regard to the  loca-
tion of their waste discharge lines, it became necessary to inves-
tigate thoroughly  each plant's sewer system.  In many cases dye
was used to locate and isolate  the various points of discharge.
If it could be determined that  any particular lateral conveyed
solely sanitary waste, that lateral was eliminated from the pro-
gram.  This determination, however, could be made in only a
few cases. Where possible, the production processes using each
lateral were determined as well as the pretreatment methods used,
if any.

     2.  The accessibility of the discharge point for sampling
and flow measurement:

         At locations where accessibility to discharge lines was
limited, samples were secured through vent pipes or cleanouts.
Where  transmission lines were accessible, "V" notch weirs or
other  flow measuring devices were fabricated to suit the needs
at that particular location.  It was  found  that many industries,
even those discharging large volumes, used multiple "Y" type
connections to the street sewer rather  than  consolidating their
discharges through one or two manhole connections.  Approximately
701 of the 85 industries sampled used "Y" type connections.

     3.  Location and number of water sources:

         Water meters played an extremely  important  role  in the
determining of plant  flow.   In  cases  where  it was  impossible to
make direct flow measurement,  the  total waste consumption was
used to estimate the  plant  discharges.   The inspectors  tried to
determine  if  the industry was  receiving water from  any  sources
other  than the city water department.   However,  in  some cases,
this could not be determined until  after the flows  were measured.
      Upon  completion  of  the  in-plant  investigation,  a  sketch  of
 the  plant  locating  the points  of  discharge  and water meters was
 prepared.   From  the previous data obtained  on the  industrial
 waste forms,  a preliminary analysis sheet outlining  the  analysis
 to be performed  on  the sample  was completed and  the  number of
 sampling days and compositing  times were assigned  (see Figure 4).
 In most cases, the  duration  of the composite time  for  each sam-
 ple  coincided with  the normal  work day for  the particular  indus-
 try  to be  sampled.  Composite  rather  than grab samples,  were  used
 even for determining  heavy metal  concentrations,  since a grab

                                25

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                            FIGURE 4. XYZ EXAMPLE
                              RECOMMENDATION
                                 APPENDIX "A"

 Company                                         SIC No.     3325
                                                  Map Loc.     67-24
        XYZ Company                              Sample Points   3
        112 Park Lane                              Production Hrs.  24
        Lancaster,  New York                       Compositing Hrs.  24
 Surcharge
        Primary - Test results Indicated that when E.C.S.D. #4 becomes tributary
        to the Buffalo system, XYZ Company should pay an Industrial waste
        surcharge for excess  suspended solids.

        Secondary - When the new treatment plant goes on stream, no additional
        surcharges should be added unless the character of XYZ's waste changes.

 Ordinance Violations

        During the  sampling program, the waste from XYZ's sample point #1
        was in violation of the sewer ordinance's grease and oil provisions.  In
        addition, concentrations of lead and phenols were measured at higher
        than acceptable levels.

 Water Balance

       Allowance - None

       Discharge - 450,000 gpd

          Cooling
            &    -414,000 gpd
          Process

          Sanitary - 36,000 gpd

Special Requirements

       Pretreatment - Before entrance into the Buffalo system is permitted, XYZ
       Company must pretreat its waste to eliminate the above  ordinance violations.

       Control Manholes - We recommend that XYZ provide control manholes on
       their discharges equipped with continuous monitoring equipment to pro-
                                      1
                                    26

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                        Figure 4 continued. XYZ EXAMPLE
                        B.S.A.  INDUSTRIAL WASTE SURVEY
                              PRELIMINARY ANALYSIS
                                     SHEET	
Company XYZ Company
Code  67-24-01

Date
Sampling Point   #1
                              Map Loc. fr     67^24
                              No.  of Samples	3_
                              Type of Sample  Composite
                              Hrs of Sampling    24
                              No. of Sample Points	3_
Parameters


PH

BOD I

COD

Chlor:

Color

Total

TSS

Settle

Greas

Phenols

Chloride

Sulfate

Sulfides

Total   i

Cyanid*

T.O.C.
Analyze For
                                                Parameters
Analyze For

Sdavi 	



>olids 	


. & Oil 	

je 	





la Nitrogen . . .
X
X
X
X
X
X
X

X
X



X
X


                          Arsenic 	

                          Cadmium	

                          Chromium hexavalent

                          Chromium-total .  . .

                          Copper	

                          Lead	

                          Iron	

                          Manganese 	

                          Mercury	

                          Nickle  	

                          Zinc	
    X

    X
                                      27

-------
                                             Figure 4 continued. XYZ EXAMPLE
                                                  SAMPLE COLLECTION
                                            	    FIELD SHEET     	
'..ulusLry    XYZ Company
:ode No.   67-24-01
Time of Installation    10:30 AM
Date of Installation    Day 1
Collector
DSB
Type of Sample  Composite
Method of Sampling  Dipper & DC
Hrs of Sampling	24	
                                                                                  Grab Sample Required	
                                                                                  Size of Outlet	Weir
                       yes
DATE:
Weather
Waste Stream Temp.
Time Sample Collected
Volume Sample
Time Grab Sample #1
Time Grab Sample #2
Time Grab Sample #3
Initial Depth of flow
Flow Meter Range
Flow Meter Base Reading
Initial Water Meter Reading
Time of Initial Reading
Final Water Meter Reading
Time Final W.itftr Motor Reading
REMARKS
Day 1
Cloudy
6°C
Installed

10"30 AM


l\ " over weir
15"
set at 12
Refer to Supple


10:15
i
Day 2
C loudy

8:00 AM
3/4 gal






mental Field Sheet


8:15
Remove equipment
Day 3
Cloudy

Installed




1" over weir
7j"
set at 5



10:30

Day 4
Clear
1°C
9:30 AM
ligal
9:35 AM


1\" over weir
7i"
set at 5



9:45

Day 5
Clear

10:10 AM
0 gal



1 3/8" over wei
7i"
set at 5



10:00
Motor battery
DOA, sample

-------
    Company:   XYZ Company

    Sample Point:  #1
                                              Figure 4 continued.  XYZ EXAMPLE
                                                 SUMMARY ANALYSIS SHEET
                           Certified Correct
Code:  67-24-01
Type of Sample: Composite
Hrs. of Sampling:  24
Map Loc.# 67-24
No. of Samples:  3
No. of Sample Points:  3
Parameters Date :
PH
BOD (5 day)
COD
Chlorine Demand
Phenol
Total Solids
TSS
Grease & Oil
NH, - N
Total Phosphorous
Arsenic
Cyanide
Cadmium
Chromium Hex.
Chromium Total
Copper
Iron
Lead
Manganese
Mercury
Nickel
Zinc
Discharge
Flow Measured MGD



* Average Value
Day 1
8.1
17.2
722
5.55
0.210
2688
2340
8.31
15.0
5.4

0




35.90
0.19


0.06
0.23

.2985




Day 2
9.4
45
1042.2
12.10
0.155
5412
5160
2.38
10
5R.5

0




88.10
0.44


0.11
0.51

.2711




Day 3
6.7
7.5
446
16.5
0.02
1916
1850
101.9
1.0
2.0

0











*.2652



i
Day 4
















76.0
0.20


2.2
0.13

*.2652




Day 5























.2260






























































tsJ

-------
                                                                                                    FORM APPROVED
                                                                                                    OMB No. 138-ROIOO
                                     Figure 4 continued.   XYZ EXAMPLE
                                        STANDARD FORM A-MUNICIPAL

                    SECTION 1Y.  INDUSTRIAL WASTE CONTRIBUTION TO MUNICIPAL SYSTEM
                                                                                                     PON AOINCV USE
 Submit * description of each major Industrial facility discharging to the municipal lystam, using a separate Section IV for each facility descrip-
 tion. indlcat* the 4 digit Standard Industrial Classification (SIC) Code for the Industry, the major product or raw material, the flow (In thou-
 sand gallons per day), and the characteristics of the wastewater discharged from the Industrial facility Into the municipal system. Consult Table
 III for standard measures of products or raw material!, (see Instructions)
 < •  Major Contributing Facility
    (lee Instructions)
    Name
    Number*. Street

    City

    County

    State

    Zip Code


1.  f>rlmiry standard Industrial
    Classification Code  (see
    Instructions)

J.  Principal Product or Maw
    Material  (see Instructions)

    Product
    Raw Material
4.  Flew  Indicate the volume of water
    discharged Into the municipal sys-
    tem In thousand gallons per day
    and whether this discharge Is Inter-
    mittent or continuous.

S.  Fretreatment Provided Indicate If
    pretreatrmnt Is provided prior to
    entering the municipal system


«.  Characteristics of Wastewator
    (see Instructions)
40U




401b


40IC


4Otd


4O1e


4011


401
                                     4O3a
                                    40Jb
                                    404b
                                    40S
         XYZ Company
                                              112 Park Lane
                                              Lancaster
                                              Erie
                                              New York
                                              00000
        Castings
                                                                                           Quantity


                                                                                              8
                                                                       Units (See
                                                                       Table III!
_&fi.
                                             450
                                                       .thousand gallons per day
       Q Intermittent (Int) QJ Continuous (con)
                                            QYes
                        B)No
\
-4
4**«
_«**•,
/ v A>
' * -a
406
406
Parameter
Parameter
value
BOD
00310
45
COD
00340
852
T. Solid
00500
3572
S.S.
00530
2320
P
00665
12.2
Phenol
32730
0.88
CN
00720 .
ND
Parameter Fe Pb Ni Zn G&O
a 01045 01051 01067 01092 00550
b 59.0 0.48 1.05 0.56 83.8
                                                      30

-------
                         Figure 4:  CONTINUED  XYZ  EXAMPLE
                  MH*3
                                                   SMITH  ST.
                                                MH*»I
N
XYZ   CO.
                                                                            SP*I
                                                                             •o
                                                            DRIVEWAY
                                                                               DC.
                                                                               CD

-------
sample can give misleading information unless the industry's dis-
charge is always the same, both in volume and strength.  In most
cases, automatic samplers were employed to obtain the necessary
samples.  Wherever possible, flow proportionate samples (ie. fre-
quency of sampling was proportional to flow) were obtained.  How-
ever, this amounted approximately to 30% of the total due to the
use of "Y" connections to the sewer (ie. no manholes for flow
measurement).  The remaining 701 were time composite samples where
a fixed volume was taken at fixed time intervals over the pro-
duction day.  The time intervals varied from one every ten minutes
to one every  thirty minutes.  To insure that the data obtained
was not severely biased due to the particular production activity,
industries were sampled from a minimum of two days to a maximum
of seven days.  The average for the 85 industries was 3.1 samples
per industry.

     The majority of the industries surveyed had more than one
discharge line to the BSA system.   The average for the 85 indus-
tries sampled was 2.3 connections per industry with a range of
from one to seven connections.

     The number of discharge points an industry uses greatly
affects the effort required to sample and analyze its discharges.
Multiple discharge points and abnormal production hours place
heavy demands on equipment and manpower which_require good prior
planning and scheduling to minimize difficulties.

     One of the problems which was encountered during the Phase
II sampling was in obtaining reasonably accurate flow data for
each sampling location of a particular industry.  For an industry
having one discharge point, flows could be estimated from their
water meter(s) readings, however, this method could not normally
be used for industries having multiple discharge points unless
it could be established that the water meter serviced only that
portion of the plant drained by the discharge point in question.
For these "problem" industries, flow data was obtained by plant
inspections whereby plant and BSA personnel estimated the per-
centage of water used by each process and which discharge line
it drained to.  In this manner, a rough approximation of an in-
dustry's discharge could be obtained.  Control manholes, in which
flows could be accurately measured, were then required for those
industries which had either potentially surchargeable wastewater
or sewer regulation violations.

     Industries were scheduled for sampling according to location
rather than by similarities in waste characteristics, to minimize
travel time.  Two variables affected establishing the initial
schedule; equipment requirements and the number of discharge
points at each industry.  Since the physical characteristics of
the various sampling locations varied widely from location to
location, some adjacent industries being sampled were initially
by-passed until the proper piece of equipment was freed for that

                               32

-------
 installation.   The  number  of  discharge points at a particular in-
 dustry also  affected  the sample  scheduling  since all discharge
 points of a  particular  industry  should He sampled at the same
 time.   In cases where industries had  five or six discharge points,
 they were initially by-passed and  returned  to when all discharge
 points could be analyzed at the  same  time.

     Samples and flow data were  collected on a routine basis at
 the  end of each work  day for  the particular industries being sam-
 pled.   Field sheets were kept by the  field  crew for each sampling
 point.   The  field sheet contained  all pertinent information with
 respect to the  samples being  collected and  flow measurement (see
 Figure 4).   To  insure that errors  as  to  the origin of each sample
 could  not be made,  each sample was  labeled  with a code number and
 date which keyed it to the field sheet,  preliminary analysis
 sheet  and industrial  waste map atlas.  The  use of the map atlas
 location  number,  as the sample code number, made a very conven-
 ient cross reference.

     After being received  in  the laboratory, the lab crew matched
 the  coded numbers on  the sample containers  to the codes on the
 anlaysis  sheets  which told them which analysis to perform on that
 particular sample.  The routine analysis consisted of such para-
 meters  as  BOD,  COD, TSS, phosphorus and  chlorine demand.  For
 approximately 451 of  the industries, heavy  metal parameters were
 also included.

     In order that  the recommendations for  each individual indus-
 try  would be instituted as soon as possible, monthly preliminary
 reports were prepared.  Each  report contained sufficient informa-
 tion to document  the  survey,  characterize plant operations, indi-
 cate problem areas  in sampling or analysis  and make recommenda-
 tions  regarding  cost  recovery  and ordinance violations. Figure 4
 gives  an  example of a report  prepared for a fictitious industry.
 By utilizing this cross section sampling, the cost recovery,
 sewer use control and sewer regulation programs could be developed
while  the remaining recommended industries were sampled.

 PHASE  III - FOLLOW-UP SAMPLING

     This phase was designed  to provide the required information
on the remaining 224  industries not yet sampled and at the same
 time mate with the  industrial waste program being developed from
 the Phase II  study.   Approximately one year from the completion
of the Phase  II study, the  Buffalo industrial waste program was
functioning and staffed.   By  this time,  79 additional industries
had been sampled and final  recommendations were made for these
and the 85 initially completed.  Since Buffalo now has its own
functioning industrial waste section,  the remaining 145 indus-
tries will be sampled as part of their permit requirements es-
tablished for the control  portion of their industrial waste pro-
gram.

                               33

-------
MANPOWER AND DIRECT COST PLANNING

     The total cost for developing Buffalo's industrial waste
program was approximately $450,000 or $0.75 per person served by
the sewerage system.  This cost can be misleading when applied
to other POTWs since the program was designed to satisfy the
specific needs of Buffalo.  So that Buffalo's experiences can
be related to other POTWs, an approximate manpower effort for
each stage of the industrial waste control program's development
was made.

Phase I

     The first phase of the Buffalo IWS took approximately five
months to complete and did not incur any direct costs.  The man-
power requirements occurred primarily on four levels:  Project
Engineer, Engineer, Engineering Aid and Clerical.  An approxi-
mation of the effort for each level is as follows:

         Project Engineer - 1450 hrs. or 1.0 hr./industry
         Engineer         - 2000 hrs. or 1.4 hr./industry
         Engineering Aid  - 2000 hrs. or 1.4 hr./industry
         Clerical         - 1000 hrs. or 0.7 hr./industry

         Total            - 6450 hrs. or 4.5 hr./industry

     It must be kept in mind that the manhours/industry total
shown is an average based upon the more detailed investigation
of the 631 industries sent questionnaires and the remaining 835
industries eliminated in the preliminary screening.  At an aver-
age hourly rate of $16.75/hour, the cost/industry would be $75.38,

Phase II

     The second phase of the IWS involved inspection, sampling,
analysis and data compiling for 600 composite samples from 85
industries and was completed in approximately eleven months.
Assuming existing laboratory facilities, direct costs are in-
curred for such items as:

         Vehicle                    - $4,000 - $ 6,000
         Safety Equipment and Tools - $  750
         Sampling Equipment         - $3,000 - $ 9,000
         Flow Measuring Equipment   - $2,800 - $10,000

     If an existing laboratory  hatd to  purchase additional
equipment to analyze the industrial samples, direct costs would
increase by $20,000 to $35,000.

     The minimum manpower requirements for inspection, sampling,
analysis and data compilations, would be approximately:
                               34

-------
        Clerical
        Field  Crew  (2 man  crew)
        Chemists
        Field  Engineer
        Project Engineer
        Total
                                  1500 hrs
                                  3000 hrs
                                  3500 hrs
                                  3000 hrs
of 2.5 hr./comp.
or 5.0 hr./comp.
or 5.8 hr./comp.
or 5.0 hr./comp.
                                   600 hrs.  or 1.0 hr./comp.
                                11,000 hrs.    19.3 hr./comp,
 2 3 connections/^ J1 av!Jage °f 3'1 Composites/connection and
 1^7 fi £?!  /• 3 7i ndustry, the manpower requirements averaged

  7n
Phase III

TT  ,^third.Phas\manPower requirements were similar to Phase

dlrecHosts
Development of the Industrial Waste Control Program

     As previously mentioned, the information generated by the
first two phases of the IWS was used to develop a sewer regula-
tion and cost recovery system.  The approximate effort required
to develop these programs was as follows:

Sewer Regulation:                    Project Engineer - 200 hrs.
                                     Engineer         - 150 hrs.
                                     Clerical         -  50 hrs.

                                     Total Hours      - 400 hrs.
                                     Total Cost       - $11,000

                                em:   Project Engineer - 400 hrs.
                                     Engineer         - 325 hrs.
                                     Clerical         -  75 hrs.

                                     Total Flours      - 800 hrs.
                                     Total Cost       - $22,200

                                     Project Engineer -  30 hrs.
                                     Engineer         -  50 hrs.
                                     Clerical         -  20 hrs.

                                     Total Hours      - 100 hrs.
                                     Total Cost       - $  2,400
Cost Recovery § User Charge Syst
Monitoring Program:
                              35

-------
                            SECTION 5

             MATERIAL BALANCE  AROUND THE SEWAGE SYSTEM
INTRODUCTION
     In order to develop an equitable cost recovery and surcharge
system for all classes of users (ie. industrial  commercial  and
residential)  and to properly establish incompatible pollutants
discharge limits, the POTW must first know the volume and waste
characteristics of each class of user.  The industrial waste sur-
vey described in the previous chapter provides the data for one
class of user.  In addition, the loadings from other sources
such as residential, infiltration and inflow must also be deter-
mined.
     By performing material balances on its sewerage system, the
POTW gains the needed additional information on the various com-
ponents of its system to accurately proportion  the costs of
Providing treatment fairly.  In addition, the results of the
balances indicate what additional restrictioning is required and
what effect these restrictions will have on the performance of the
waste treatment facility.  For example, in the Buffalo system,
prior to this study, it was not known what portion of the organic
loading received at the treatment plant was contributed from in-
dustrial sources.  It was also not known whether or not the in-
dustrial contribution was a benefit or a hinderance to Buffalo's
treatment system.  In addition, there were questions about the
magnitude of the domestic and stormwater contributions of trace
elements should be restricted in order for Buffalo to meets its
NPDES requirements.  It is important to know the answers to all
of these questions when developing an industrial waste control
program.

     In performing the balances, the BSA's system  was broken
down into five types of contributors as shown in Figure 5, with
the following parameters investigated.

nrm                         Cadmium                        Mercury
*°°                         Chromium                       Nickel
LU                          frmnpr                          Zinc
Tco                         i.oppei
lb                          Pvanirlp                         FlOW
Phosphorus                  Lyanide
                            Lead
Arsenic


                                36

-------
        Domestic
      Industrial
Scajaquada Creek
Infiltration and
River Inflow

Stormwater
             Figure 5.  CONTRIBUTORS TO BSA'S SYSTEM

ESTIMATION OF DOMESTIC CONTRIBUTION

     Domestic waste from approximately 700,000 persons is re-
ceived by the Sewer Authority from residential sources both within
the city and from outside districts.  While fairly good estimates
can be made for BOD and SS loadings from literature, the same can-
not be said for trace elements.  To obtain an estimate of the
trace element loadings, a sector of Buffalo's residential com-
munity was examined.  To enhance the accuracy, flow proportion
samples were obtained and analyzed for three days.  Of the trace
elements, only lead, mercury and zinc were found in measurable
quantities above what is normally found in Buffalo's drinking
water.

     In order to get the domestic contribution of the loading to
the treatment facilities, a water balance had to be developed.
This was accomplished by obtaining the average amount of water
supplied daily by Buffalo's water department and subtracting the
industrial consumption and the system's losses.  Based upon 1974
population figures, the resulting per capita consumption was
610 liters/day (161 grid) which is reasonable for unmetered sources
such as is the case in Buffalo.

ESTIMATION OF INDUSTRIAL CONTRIBUTIONS

     The information obtained during Phase II of the BSA's indus-
trial waste survey was used to estimate the industrial portion
of the total loading received at the Bird Island Treatment Plant.
The first step was to classify the 420 wet industries into 210 SIC
subcategories covering seven major SIC divisions.  The second
step was to obtain an average loading of the sampled industries
in each subcategory.  The average loading was then applied to the
remaining industries in each subcategory.  The loading for each
sampled subcategory was then totaled and an average industrial
loading rate established.  Since the sampled industries accounted
                                37

-------
for 84% of the total industrial flow contributed to the BSA sys-
tem, the application of the average industrial loading rate to
those subcategories which did not include any sampled industries
provided a good estimate of their contribution.  The totalization
of all the categories established the estimate of the total in-
dustrial contribution.

     A summary of the characteristics of SIC categories investi-
gated, Table 26, can be found in the appendix.  The summary
shows not only the quality of waste which can be expected from
industries in the same SIC category and their estimated loading,
but also indicates areas of concern for cost recovery and sewer
use regulations.  For example, of the industrial loading to the
treatment plant, the electroplaters category (#3471) contributes
58% of the cadmium, 39% of the nickel, and 21% of the cyanide.
Discharge controls for this category would result in significant
reductions in the overall loadings of these parameters received
at the Authority's Bird Island plant.  If in the future, problems
arise with regard to these parameters, the electroplaters cate-
gory would be a prime candidate for investigation.   The much lower
but still significant contributions of other trace elements in-
dicate that the Authority must have a much more detailed program
of surveillance.

ESTIMATION OF SCAJAQUADA CREEK CONTRIBUTION

     The Scajaquada Creek is a natural waterway flowing westward
to the City of Buffalo.  As Buffalo was developing, more and
more sewage entered the creek through overflows until finally it
was enclosed at the city line and made an integral part of the
sewer system.  The Buffalo Sewer Authority has a long term pro-
ject underway to divorce the stream from its sewer system, how-
ever for planning, it was included as a contributor.

     While organic analytical data is available on the stream's
quality where it enters the city's sewerage system, metals con-
centrations had to be obtained from grab samples.  Flow data was
readily available from the USGS gaging station at the city line.

     The results of the Scajaquada Creek sampling indicated that
there were three parameters present in quantities that should
cause concern:  phosphorus, cyanide and mercury.  Approximately
56% of the mercury, 21% of the phosphorus and 10% of the cyanide
loadings received at the Bird Island plant are contributed by
the Scajaquada Creek.  Industries upstream of the Scajaquada
Creek's connection to the BSA system are probably the sources of
these substantial loadings.  This raises a serious legal ques-
tion as to whether the BSA has the jurisdiction to control these
industrial discharges to meet their NPDES permit requirements.
                               38

-------
ESTIMATION OF STORMWATER CONTRIBUTION

     In estimating the stormwater contributions  to  a sewerage
system such as Buffalo's, there are many  factors which should be
considered, such as the variation in precipation due to the geo-
logical location of the study area.  In Buffalo  the influencing
factor is Lake Erie.  Rain and snow squalls  may  fall in one por-
tion of the city while other portions  remain dry.   Storm fre-
quency is an important factor since during  extended dry periods,
large quantities of pollutants may build  up  in the  sewers and on
the streets.  Thus, the next substantial  storm brings higher than
normal concentrations of the various pollutants  to  the treatment
plant.  It is very possible that these concentrations could read
toxic or inhibiting levels causing upset  or loss of efficiency at
the facility.  All these factors should be  carefully examined and
evaluated in making an analysis of the effects the  stormwater has
on the system.

     The method used to investigate Buffalo's stormwater contri-
bution was to compare the concentrations  and loadings for wet and
dry days found at the treatment plant  during the pilot operation.
While exact values cannot be obtained  by  this method, it was used
to show general patterns since time and money did not permit a
more detailed investigation.  Of particular interest to this
study were the stormwater loadings for trace elements since these
loadings could have a bearing on the pretreatment requirements
imposed on the industry.  From the information supplied by lit-
erature,' »4>^ it would seem that during  storms preceded by dry
weather, the concentrations of metals  during the initial wet
period would increase due to the quantities washed from the
streets and sewers.  However,  in general, this was not found to
be true.  For all the pollutants other than lead, the average
and mean concentrations for wet weather  were less than those for
dry weather.  This  indicated that  the  stormwater diluted the
quantities found in the dry weather  sewage.  Further confirmation
was obtained by comparing the  concentrations of the plant's  in-
fluent on wet days which are preceded  by  four or five dry days
(first flush), to the influent  concentrations obtained on  the
remaining days.  Since a first  flush occurrence
build-up of pollutants in the  system,  the concentrations measured
on a first flush occurrence should  be  significantly higher  than
those measured on other days.   Unfortunately, the study period


3Toxic Materials Analysis of Street  Surface Contaminants. EPA-82-73-233.

4Sarton J., Boyd G., and Agardy F.  Water Pollution Aspects of Street Con-
 taminants.  Journal WPCF. Vol. 46. No. 3.  March 1974.  p458-467.

Newton C.D., Shephard W.W.,  Coleman M.S. Street Runoff as a Source of Lead
 Pollution.  Journal WPCF. Vol. 46.  No. 5.   May 1974.  p999-1000.


                               39

-------
was generally wetter  than normal  and only  two days could be con-
sidered a  first  flush: November 18th and December 7th.  Lead was
the only parameter  investigated which definitely showed a higher
concentration on  the  first flush  days.  The first flush results
for zinc,  the only  other trace element which had a wet weather
loading higher than its dry weather loading, were not conclusive
since the  increases on the first  flush days could be attributed
to higher  industrial  activity as  was observed on dry days.  In
addition,  the wet weather loadings, Table  3, with the exception
of lead and zinc, followed the same pattern as was observed for
the wet and dry concentrations.   This indicated that stormwater
was only contributing measurable  quantities of lead and zinc
during the study period.  Stormwater was not found to contribute
measurable quantities of cadmium, chromium, copper, nickel or
cyanide.

    Table 3.  TOXIC POLLUTANTS LOADINGS -  WET vs. DRY WEATHER
Parameter
Cadmium
Chromium-T
Copper
Lead
Nickel
Zinc
Cyanide
Flow-mg/day
Wet Loading - kg/day
Avg.
0.0013
0.0131
0.0128
0.0126
0.0045
0.0363
0.0046
801.7
non-exceedance
501
0.0011
0.0142
0.0117
0.0075
0.0038
0.0142
0.0036
755.1
90%
0.0023
0.0331
0.0227
0.0318
0.0115
0.0682
0.0087
1105.2
Dry Loading - kg/day
Avg.
0.0020
0.0232
0.0129
0.0072
0.0050
0.0291
0.0049
723.8
non-exceedance
504
0.0016
0.0229
0.0125
0.0075
0.0043
0.0235
0.0045
658.2
904
0.0041
0.0402
0.0238
0.0112
0.0110
0.101
0.0079
752.5
     It should be noted that, due to the numerous overflows in
the Buffalo Sewer System, during times of heavy rain significant
quantities of rain diluted sewage overflows into the lake and
rivers.  If the quantity of the overflows were included in the
wet weather balance, the metal loadings would increase, however,
since Buffalo Sewer System is largely combined sewers, the con-
centration of metals at the plant would probably remain the same.

ESTIMATION OF INFILTRATION AND INFLOW CONTRIBUTIONS

     During the study, economics and time did not allow for
direct measurements to establish the infiltration and inflow
contributions to the system.  Therefore, it was necessary to make
estimates from other sources.  While in fact, the quantity and
quality of infiltration and inflow varied widely across the city,
for this balance, it was assumed to be constant.  For the Buffalo
system, inflow may occur during dry weather due to the lake or
river levels being higher than the overflow chamber's inverts,
causing these waters to flow into the BSA system.  Based on the
Authority's average infiltrate rate, 70.8 million liters/day was
                               40

-------
 theiaua?ftv°nftIieiflrW-COntribUtion-   T°  simPli£y the  balances,
 the  quality  of Lake  Erie  water  was  assumed to  be  a good estimate

                   1"""*1011  ^  infl°W ^  WaS Jed t0
 RESULTS  OF  THE MATERIAL  BALANCES

      Summarized  in  Table 4,  are the  results  of  the material bal-
 ances  for four of the  five types  of  contributors  to  the Buffalo
 system.  These balances  apply only to dry weather conditions since
 the uncertainty  of  storm occurrences preclude considering the
 stormwater  contributions in  the balances.  The  balances clearly
 indicate some important  characteristics of the  Buffalo system
 which  must  be taken  into account  not only in  developing cost
 recovery and sewer use programs,  but also in  future  planning.
 One o± the  most  important areas identified by the balances is
 that,  with  the exception of mercury, over 82% of  each of  the
 trace  elements loading is contributed by industry.   This  indicates
 that an industrial waste control  program will effectively reduce
 these  loadings to an acceptable minimum.

     A second important  area identified was compatible pollutant
 loadings for use in an equitable  cost recovery  and user charge
 system.  In addition to  establishing the loadings attributed to
 each class  of user, the  balance showed that 231 of the flow and
 21% of the phosphorus loadings were contributed by non-point
 sources.   This clearly pin-points an area where the Authority
 should direct its efforts and thus reduce the sizable operation
 and maintenance costs of those non-point source contributions
which at present must be recovered from the point source users.
 (ie.  residential and industrial).
                               41

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Table 4.  DRY WEATHER MATERIAL BALANCES ON THE BUFFALO SEWERAGE SYSTEM
Parameter
BOD
Kg/day
\ of Total
Cone. -mg/1
COD
Kg/day
1 of Total
Cone. -mg/1
TSS
Kg/day
1 of Total
Cone. -mg/1
Phosphorus
Kg/day
1 of Total
Cone. -mg/1
Arsenic
Kg/day
\ of Total
Cone. -mg/1
Cyanide
Kg/day
* of Total
Cone. -mg/1
Cadmium
Kg/day
\ of Total
Cone. -mg/1
Chromium
Kg/day
\ of Total
Cone. -mg/1
Copper
Kg/day
% of Total
Cone. -mg/1
Lead
Kg/day
% of Total
Cone. -mg/1
Mercury
Kg/day
1 of Total
Cone. -mg/1
Nickel
Kg/day
% of Total
Cone. -mg/1
Zinc
Kg/day
% of Total
Cone . -mg/1
Flow
Megaliters/day
% of Total
Domestic

50,400
60
123

114,390
54
280

46,000
68
112

590
40
1.44

__
0
£0.01

1.04
3
0.003

—
0
£0.01

-
0
<0.01

2.96
2.2
0.007

4.09
13.9
0.01

1.18
39.3
0.003

—
0
£0.01

50.4
15.0
0.123

409
63.5
Industrial

28,900
34
327

83,570
40
944

18,300
27
207

570
39
6.44

0.018
100
0.0002

26.5
87
0.299

4.02
100
0.045

126.6
100
0.43

128.0
97.3
1.45

24.6
83.3
0.278

0.15
5.0
0.002

63.9
100
0.722

283.0
84.2
3.20

88.5
13.7
Infiltration
and Piver Inflow

2,300
3
32.5

5,500
2.5
78

600
1
8.5

0
0



~0
£0.01

—
0
£0.02

—
0
<0.01

—
0
<0.01

0.7
0.5
0.01

0.07
0.2
0.001

—
0
£0.001

-
0
£0.01

2.82
0.8
0.04

70.8
11.0
Scajaquada
Creek

2,500
3
33.3

7,380
3.5
98.4

2,600
4
34.7

300
21
4.00


0
£0.01

3.03
10
0.04


0
£0.01

__
0
£0.01

_
c
£0.01

0.76
2.6
0.01

1.67
55.7
0.022

_
0
£0.01

—
0
£0.01

75.7
11.8
                                42

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                            SECTION 6

           DEVELOPMENT OF AN INDUSTRIAL WASTE PROGRAM
INTRODUCTION

     Of all public utilities,  wastewater collection and  treatment
systems are probably the most  abused.   This abuse stems  from the
common misbelief that a sewer  can carry any unwanted material
that can be put in it.   This misuse of the public sewerage system
can affect the efficiency of the system, as well as increase the
operating and replacement costs to the users.

     There is certainly no question that many  problems  experienced
in sewage treatment can be eliminated or to a  great extent con-
trolled by the proper regulation of the use of the sewerage sys-
tem.  In an industrial  area this control can only be brought by
an effective industrial waste  program which includes not only
regulations on the use of sewers but also a method of enforce-
ment.

     Based on the finding of the Industrial Waste Survey and the
resulting material balances, the Buffalo Sewer Authority elected
to use sewer use regulations coupled with a permit system and
monitoring program to establish its industrial waste controls.

LEGAL AUTHORITY

     Before any municipality,  Authority, or treatment and col-
lection agency can control the waste being discharged into its
system, it must first have the power and authority to enforce
such a regulation.  In the case of the BSA, they do have the
power and authority of control under Item No.  8, Section SS1403
of the Laws of New York State - by Authority.   To provide a
means of control over other municipalities wishing to use the
Authority's sewage system, a contractual agreement is used.  In
order to meet today's requirements for equitable cost recovery
and pretreatment, the power to control industrial discharges
must not stop at the point where the outside municipalities inter-
ceptor sewer enters the Authority's sewerage system, but rather
should extend to the industry's front door.  Thus the BSA re-
quires compliance with its sewer use regulations and cost re-
covery and user charge system.  Every outside sewer district is
required to enter into a contractual agreement with the BSA.


                               43

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 The  BSA's  ordinance and cost  recovery program  are  specifically
 made a  part  of these contractual  agreements.   In this manner, the
 industrial users  outside of the  city  limits, like  the industrial
 users inside the  city,  are  required to obtain  permits and parti-
 cipate  in  the cost  recovery and monitoring programs as well as
 allow access to the BSA,  EPA,  County  and  State officials for dis-
 charge  inspection.

 DETERMINATION OF  DISCHARGE  LIMITS  REQUIREMENTS

     Before  a POTW  can  develop its sewer  use regulations, it
 should  evaluate the federal,  state and local requirements to
 insure  compliance with  the  most stringent.  At the time BSA's
 study was  undertaken, it  was  anticipated  that  the  standards of
 performance  and pretreatment  standards  for the majority of in-
 dustrial discharges  into  POTWs would  be promulgated and that the
 Best Practical Control  Technology Currently Available (BPCTCA)
 would establish the  federal effluent  criteria.  However, as of
 this writing, most  of the standards for discharge  into POTWs are
 only proposed.  In  addition, EPA is considering amending its de-
 termination  of the  discharge criteria from a loading per pro-
 duction unit  basis  to a concentration basis.

     New York State's requirements are on a concentration basis
 but  they have not established any firm guidelines  since each
 POTW is evaluated based upon the magnitude of its  industrial dis-
 charges, the  type of treatment process employed, and the water
 quality standards of its  receiving stream.  Since  New York State
 had no applicable guidelines, the proposed Federal requirements
 for discharge into  POTWs were evaluated to determine their ap-
 plicability  for use  in controlling industrial dischargers served
 by the BSA.

     In making this  evaluation, three major problem areas were
 encountered.   The first was that in general, industries did not
 keep the type of production records required to determine their
 allowable  discharge.  Many  industries were  even reluctant to
 give an estimate based on the required production units since
 they felt  that the production basis for determining discharge
 was too complex and  it was  information which was confidential
 and they did not want to  impart it.  The  second problem area was
 how to handle plants having a varied product line.   Many of the
 industrial users of  the Buffalo system have either more than
 one product  line or  associated processes  such as captive plating
 lines.  To further complicate this problem, the waste streams
 from the various production lines are often discharged through
 common sewer laterals.  The third problem was that there was not
 enough information available in the published effluent guidelines
 to determine  the allowable discharges.  Even with the aid of the
Development Documents used to establish the guidelines,  the de-
 termination of what was specifically included was difficult and


                               44

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sometimes not possible.

     Based on this evaluation,  the BSA had adopted the  concen-
tration method of expressing discharge limits  because  it  was
felt that the use of'production units to establish effluent
criteria would result in greater administrative time,  paperwork
and cost on the part of the Authority.  For example, using the
production basis, when the BSA monitors the discharge  from a  job
shop plater to insure compliance with the regulations,  it could
easily spend four or five manhours just in determining the allow-
able discharge limits for the sampled period since this type  of
plater not only changes its quantity and type  of plating  from
day to day, but also the type of pieces plated.

SEWER USE REGULATIONS

     The BSA's sewer use regulations were established  to  provide
for the maximum possible beneficial public use of the  Authority's
facilities through regulations of sewer construction,  sewer use
and industrial wastewater discharges.

     The results from the Phase II IWS indicated areas of con-
cern which were not covered under its old sewer regulations.
Thus, from the old regulations, a new regulation was developed
to meet BSA's expanding needs and match the sophistication of
the new secondary treatment plant.  The new regulation, coupled
with a monitoring program enforced by the BSA's industrial
waste staff provides the tools necessary to control the wastes
discharged into the system.

     Buffalo's sewer use regulations were developed around four
major requirements, control of the construction of sewers and
connections,  establishment of prohibited and  limited  discharge
criteria, control of industrial discharges, and establishment
of  an enforcement procedure for violations of  the regulation.
Two of  these  requirements,  establishment of prohibited and
limited  discharges  and  controlling industrial  discharges, were
greatly  expanded  over  the old regulation.

      In  establishing the prohibited  and  limited waste  discharge
criteria,  a  distinction had to be made between which wastes
would not  be  allowed at all and which would be allowed in limited
concentrations.   The prohibited wastes  section, in general terms
included  all  wastes which would be hazardous  or harmful  to
either  the  sewerage  system, public health  or  the  receiving
stream.   Since  the  BSA's  limits were established  in concentra-
tion  terms  rather than production units,  an antidilution clause
was  included to  prohibit  the  discharge  of  any water for  the
purpose of diluting wastes  which  would normally exceed applic-
able  maximum concentration limits.   This  clause established  the
basis  for the illegality  of dilution to  meet  discharge limits.


                               45

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 The limited discharge concentrations,  Table 5 below,  was  estab-
 lished by initially setting the limits based on the  applicability
 of other existing ordinance limits on  the BSA system then re-
 fining them to meet New York State Requirements.   A  copy  of  the
 entire Sewer Use Regulations can be found in the  appendix.

            Table 5.   BSA's  LIMITED DISCHARGE LIMITS
            Parameter             Concentration  mg/1
Chromium (total)
Chromium (trivalent)
Chromium (hexavalent)
Copper
Zinc
Nickel
Cadmium
Arsenic
Barium
Lead
Manganese
Silver
Boron
Mercury
Selenium
Cyanide
Phenolics
Grease and Oil
2.0 mg/1
1.0 mg/1
0.1 mg/1
0.4 mg/1
0.6 mg/1
1.0 mg/1
0.2 mg/1
0.1 mg/1
1.0 mg/1
0.1 mg/1
1.0 mg/1
.05 mg/1
1.0 mg/1
.01 mg/1
.05 mg/1
0.8 mg/1
0.1 mg/1
50.0 mg/1
     The BSA's NPDES permit establishes certain discharge limits
which must be met.  To meet these limits, the Authority must
not only operate its treatment plant efficiently, but must also
control industrial discharges to insure that they do not either
upset the treatment plant or pass through untreated.  In formu-
lating the control method that best suited the Buffalo system,
four alternatives were evaluated and ultimately utilized, to
varying degrees, in Buffalo's Industrial Waste Control program.

     1.  Enforcement of Sewer Regulations:

         In the past, with only a primary system, the "Enforce-
ment of the Sewer Regulations" has been a satisfactory method
for controlling discharges.  However, a more sophisticated
treatment process, increasingly demanding federal and state re-
quirements and a fluctuating industrial community, this system
alone no longer provides an adequate level of control.  Under
this method, the industries are not required to report changes
in their production methods or flow rates.  In short,, the Sewer
Authority has no way of monitoring changes in the waste charac-
teristics.   In addition, by simply enforcing the sewer regula-
tions,  the BSA is not providing a convenient means by which they
can obtain production data and waste characteristics.  When the

                              46

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new treatment plant is completed and in operation,  this  data will
become essential for evaluation of industrial waste surcharges
and to insure BSA's compliance with Part IV of their NPDES per-
mit.

     2.  Contractual Agreements:

         Contractual agreements with each industry  would offer
the BSA the maximum possible control.  The reason for this being
that a contract is a specific and legally binding agreement be-
tween two parties and is readily enforced in a court of  law. As
one would imagine, to negotiate a contract with each major con-
tributing industry in a city the size of Buffalo would be obvious-
ly far too expensive and time consuming.  However,  it may be
advisable for the Sewer Authority to consider having contractual
agreements with isolated problem industries.

     3.  Continuous Monitoring Program:

         The third method would be a continuous monitoring pro-
gram to insure that each industry is complying with the sewer
regulations.  This method has, in the past, been proven to be
very effective.   However, it would require  a  large staff  of
chemists and engineers to collect ana analyze tne samples from
each industry.  Here again, the cost associated with such a pro-
gram would be excessive.

     4.  Permits:

         The permit system  seemed to be the most practical and
workable method;  however, permits alone will  not insure  adequate
control.  It must be coupled with a  strong  enforceable sewer use
regulation and an industrial self-monitoring program.  This
means  that industries would be  required to  sample  and analyze
their  own waste  streams and report the results  to  the BSA on a
routine schedule.  To insure that the data  being supplied to
them is accurate,  the POTWs could spot check  the waste from the
industries in question.

     As previously mentioned,  a sewer regulation alone  is not
going  to control  the wastes being discharged  to a  municipal sys-
tem.   Therefore,  a program of  enforcement  and specific monitor-
ing procedures were developed.  As  called  for in the new regula-
tions,  the permit system coupled with  an  industrial  self-monitor-
ing program  was  adopted as the most  practical,  economical and
workable method  to  adequately  satisfy  Buffalo's needs.

BUFFALO'S PERMIT SYSTEM

     Upon enactment of  the new sewer regulations,  every  indus-
trial  and commercial  establishment  is  given six months  to obtain
an industrial waste permit.   A completed  application would  con-

                                47

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 tain all  the  information  the  BSA would require to evaluate the
 industry's waste  stream.  Based on  the questionnaire, the Sewer
 Authority will decide:

     1.   Whether  or not the discharge is of a surchargeable
 nature.
     2.   Whether  or not the discharger will be required to pro-
 vide pretreatment.
     3.   Whether  or not the discharger should self-monitor.
     4.   Whether  or not further investigation is required.

     After the BSA's industrial waste staff has evaluated the ap-
 plications and has made its recommendations as to which indus-
 tries should: 1) pretreat their wastes; 2) pay an industrial
 waste surcharge;  3) install a control manhole; and/or 4) self-
 monitor;  a formal letter stating the conditions under which the
 waste would be accepted will be sent to the discharger.  In some
 cases the Authority may ask the discharging industry to submit an
 industrial wastewater facilities report, to insure that the pre-
 treatment which is proposed will be adequate and a time table for
 achieveing acceptance will be agreed upon by the applicant and
 the Authority.

     After all the requirements for the permit are met, a second
 letter, formally accepting the waste would constitute the permit.
 In addition, industry may be required to self-monitor to insure
 compliance with their permit.   This requirement will be discussed
 in more detail in the following subsection.

 BUFFALO'S MONITORING PROGRAM

     The monitoring program is an essential part, of an industrial
waste control program.  The IWS conducted by the Authority pro-
vided an  accurate data base and check enabling the use of indus-
 trial self-monitoring to provide the required data in the con-
 tinuing program to reduce the expense and work load on the Author-
 ity.  However, spot checks by the Authority will be used to main-
 tain the  integrity of the self-monitoring program.  A preliminary
schedule has been drawn up, see Table 6, establishing the fre-
quency of both industrial and BSA monitoring.   In addition to es-
tablishing a monitoring schedule, Table 6 also summarizes the
industries': pretreatment requirements,  flow and SIC code; there-
by providing the pertinent data for each industry in one refer-
ence.  The frequency of the required monitoring was based upon
the quantity and characteristic of the wastes  discharged by each
industry.  If an industry did not have any violations or sur-
charges, then self-monitoring was not required, however, the BSA
will periodically spot check industries which do not self-monitor
for changes in their waste characteristics.

     Since the results of the monitoring program are used to es-
tablish:  user charges, compliance with sewer use regulations,

                              48

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Table 6. SUMMARY OF PRETREATMENT AND MONITORING SCHEDULE
Industry
44-7
44-24
44-6
44-5
38-11
45-2
38-12
37-7
32-13
S6-6
33-13
34-13
24-2
23-6
23-10
9-2
27-9
SIC #
2011
2011
2011
2013
2013
2013
2013
2013
2021
2022
2024
2026
2026
2047
2051
2051
2079
Flow
Ipd
101,800
39,400
73,800
1.018 MLD
210,100
424,300
275,200
901,200
103,700
111,700
839,900
1.098 Mil
709,300
157,500
186,600
243,400
1.540 MIX
Control
M.H.

X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Improved House-
keeping Required For

Solids, G & O
Solids
Solids

G & O
G & O




Solids





Pre treatment
Update




G & O

pH. solid:
PH









New








G & O
G & O
G & 0

G SO

GTA O
pH

G & O
Monitoring Schedule
Self

Annually
Annually

Bl-annually

Quarterly
Quarterly

Quarterly
Bl-annually
Monthly
Quarterly

Annually

Quarterly
B.S.A.
Spot check
Every two years
Every two years
Annually
Annually
Annually
Annually
Annually
Every two years
Annually
Annually
Bl-annually
Annually
Spot check
Annually
Annually
Annually
Applicable Unit Processes
These unit processes also apply to SIC
codes 2014 and 2077.
1 . Improve in-plant control practices
a) blood recovery
b) handling of paunch manure as
solid waste
2. Course solid separator
3. Removal of all floating oil and grease
4 . Ne utra liza tion
These unit process also apply to SIC
code 2023.
1. Improve in-plant control practices
by recycling of by-product
2. Removal of grease and oils
3. Equalization
4. Neutralization

-------
 or a combination of both,  the monitoring requirements are strin-
 gent.  Samples  taken  in proportion  to  flow are preferred and
 required in some cases.  However, samples composited over the work
 day are usually acceptable.  To allow  for normal production
 variations, analysis  is required on samples collected over three
 to five consecutive work days.  Registration is required of all
 laboratories performing analysis for industrial self-monitoring
 to insure that all the analytical procedures, quality control,
 and sample preservation methods being used are uniform and in'
 accordance with BSA standards.  In addition, to minimize con-
 flicting results between the industrial analysis and the BSA
 spot checks, the Authority provides the opportunity for the in-
 dustry to split samples taken during the monitoring period.

 PRETREATMENT

      Some of the industries will be required to pretreat their
 waste.   From an industrial point of view,  the pretreatment of
 waste streams  will  serve two purposes:   (1)  to eliminate viola-
 tion of the  sewer  regulations,  and (2)  to  reduce industrial
 waste surcharges.

      From a  municipal  point of view, the pretreatment  of indus-
 trial waste  will reduce loadings at  the treatment  plant,  mini-
 mize the  chance of  process upset due to toxic pollutants,  and
 improve the  quality of the sludge.   This requirement is  outlined
 in the  Federal Register,  Issue  40  CFR  128,  and is  further  elab-
 orated  on in the Federal Guidelines,  entitled "Pretreatment  of
 Pollutants  Introduced  into Publicly  Owned Treatment Works,"
 published by the U.S.  Environmental  Protection Agency  in  October
 1973.   Therefore, using the above  as a  guide,  the  BSA  formulated
 its  own pretreatment policy.

      After reviewing the  federal and state policies concerning
 pretreatment,  the following policies were adopted  by Buffalo.

      1.   Joint  treatment  of domestic wastewater and adequately
 pretreated industrial  wastewater is  encouraged where it  is
 economically advantageous.
      2.   In-plant measures  to reduce the quantity and strength
 of industrial wastewater  flows would be  beneficial  to joint
 treatment, and  should  be  encouraged.
     3.  Pretreatment  requirements should be based  on an indi-
 vidual analysis of  the  permitted effluent limitations placed on
 an industry and on  the  potential for adverse effects to the
 treatment works.

 INITIAL WORKINGS OF BUFFALO'S INDUSTRIAL WASTE PROGRAM

     Buffalo's industrial waste program was finalized approxi-
mately one third of the way through Phase III of the IWS and was
 staffed according to the Organization Chart present  in Figure  6.

                              50

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                                    Figure    6
                             ORGANIZATION  CHART
                  PROPOSED  INDUSTRIAL   WASTE  SECTION
                               BUFFALO SEWER  AUTHORITY
                                   GENERAL  MANAGER
  SEWERS
DEPARTMENT
INDUSTRIAL  WASTE
   ENGINEERING
ADMINISTRATIVE
  DEPARTMENT
SEWAGE TREATMENT
   DEPARTMENT
                                INDUSTRIAL  WASTE  SECTION
                                 ASSOCIATE  ENGINEER OR
                                 ASSOCIATE  CHEMIST  (I)
                                       TO PRESENT LEGAL INVESTIGATOR
                                             8 BILLING DIVISION
                    OFFICE OPERATION
                     ENVIRONMENTAL
                     COORDINATOR (I)
                            FIELD  OPERATION
                               SENIOR
                              ENGINEER (I)
     CLERICAL TYPING  (I)
              INVESTIGATING
            SAMPLING 8 GAGING
             ENGINEERING  AID
           JUNIOR ENGINEERING (2)
                  LABORATORY
              SENIOR SANITARY AND
              SANITARY  CHEMISTS (2)

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The Authority felt that even though additional requirements were
to be placed on the industrial users of their system, the tran-
sition to and acceptance of the new program could be harmonious.
To facilitate the implementation of the new program, the Authority
approached the change over in the following manner:  to approach
the industries with an attitude of cooperation and to solicit
ideas thereby stimulating public participation.  Instead of de-
manding compliance, the industries were asked to work along side
the BSA so that together they would be able to meet BSA's NPDES
permit requirements.

     A series of public meetings were held to explain the new
program and to obtain an exchange of ideas.  This method has
been successful and has stimulated an attitude of cooperation
between the BSA and the industries it serves.  The initial feel-
ing of industry is that the public meetings were extremely help-
ful in gaining a good understanding of the program.
                              52

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                              SECTION 7

       ECONOMIC ASSESSMENT OF BUFFALO 'S COMBINED TREATMENT
INTRODUCTION

     The  starting point in assessing the economics of combined
treatment is to estimate what the  capital  (construction)  and
operation and maintenance (0§M)  costs will be.   Once a good
estimate  is obtained,  methods for  the recovering of the costs of
providing treatment  can be developed.

     In  order to qualify for participation in  the federal govern-
ment's financing program for grant funds to  POTW's and where the
considered project  includes treatment of industrial waste,  the
grantee  must assure  the granting agency that it  has or will have
in effect an equitable cost recovery and user  charge system.
The Environmental Protection Agency promulgated specific  require-
ments with respect  to  establishing and implementing these systems
in the Federal Register, Volume  39, Number 29,  40 CFR, Part 35,
State and Local Assistance, February 11, 1974.   The requirements
are as follows:

     § 35.925-11 User Charges

     That, in the case  of grant assistance awarded after March 1, 1973,
     a project involving Step 2 or Step 3, an approvable plan and
     schedule of implementation have been developed  for a system of
     user charges to assure that each recipient of waste treatment ser-
     vices within the applicants service area will pay its proportionate
     share of the cost  of operation and maintenance  (including replace-
     ment as defined in § 35.905^17) of all waste treatment service pro*
     vided by the applicant and the applicant must agree that such sys-
     tems will be maintained.

     §  35.925*12  Industrial Cost Recovery

     (a)  That, in the  case of any grant assistance awarded after March
     1, 1973, for a project involving Step 2 or Step 3, signed letters
     of intent have been received by the applicant from each signifi*
     cant industrial user to pay that portion of the grant amount air
     locable to the treatment of its waste. Each such letter shall
     also include a statement of the industrial user's intended period
     of use of the treatment works.  A significant industrial user  is


                                 53

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      one that will contribute greater than 10 percent of the design
      flow or design pollutant loading of the treatment works.  In
      addition, the applicant must agree to require all industrial
      users to pay that portion of the grant amount allocable to the
      treatment of wastes from such users.

     Shown in Figure 7,  is  a graphical  representation of  the cost
recovery and  user  charge system  required under PL 92-500.
     Once an  industrial  cost recovery and user charge system has
been established,  the  industrial user can evaluate it in conjunc-
tion with the pretreatment  requirements to determine the most
economical solution  for  their specific needs.  This evaluation may
indicate that an industry should pretreat its compatible pollu-
tants rather  than  pay  a  surcharge or that minor production changes
or better housekeeping procedures should be instituted to lower
surcharges or pretreatment  requirements.  In systems using a con-
centration basis for discharge limits the potential exists for
industry to use dilution to either meet discharge limits or to
reduce or eliminate  surcharges.   During this study, as will be
discussed later in this  section, consideration was given to these
areas to indicate  their  effects  on the Buffalo system.

BACKGROUND - COST  RECOVERY  AND USER CHARGE SYSTEM FOR BUFFALO

     Since Buffalo secured  their grant prior to March 1, 1973,
the regulations governing the industrial cost recovery and user
charges are those  of PL  84-660 rather than PL 92-500.  There are
two basic differences  between these two laws: first,_PL 84-660
does not require the recovery of the industrial portion of the
Federal grant, and second,  the use of ad valorem tax will not
satisfy the Federal  requirement  for user charges for PL 92-500.
PL 84-660 requires the applicant demonstrate the use of ad val-
orem tax as the base for user charge.  This is based on a de-
cision made by the Comptroller General of the United States.0

     The problems  involved  in developing a method by which the
BSA should distribute  its financial obligation to those that
benefit from  it is quite complex.  The system must be based on
the principle that the total annual revenue required for the
operation of  the sewage  works should be distributed to the users
and non-users for  whose  use, need and benefit the facilities are
provided, approximately  in  proportion to the cost of providing
the use and the benefits of that works.

     In the past,  the  most  commonly accepted method for raising
6Agee, James L.  User Charge Systems.  Program Guidance Memorandum.  EPA.
 pg. 38.  July 16, 1974.  lp.
                                54

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en
t/i
     Figure : 7     COST  RECOVERY 8 USER  CHARGE SYSTEM  UNDER  PL  92-500
      TOTAL
      REVENUE
    REQUIREMENTS
                  OPERATING
                    FUNDS
          USER   CHARGES
                     CONSTRUCTION
                         FUNDS
                    (BONDS AND NOTES)
FEDERAl
 GRANT
 FUNDS
                                      STATE
                                      GRANT
                                      FUNDS
                 NON-INDUSTRIAL  a
                INDUSTRIAL  PORTION
                 COST RECOVERY
NON-INDUSTRIAL  PORTION
     NO  RECOVERY
   INDUSTRIAL  PORTION
    COST RECOVERY
                  NO  RECOVERY

-------
  revenue has been based on assessed valuation.7  Historically
  communities, as they developed to the state of providing wast*
  water services, tended to use this means of raising revenue sinmlv
  t?nnT6 T! WS-  ^^ti^Hy used to support governmental Lnc P 7
  tions.   The simplicity of the system makes it very desirable since
  it requires no monitoring or sampling to determine charges and the
  accounting and billing work is minimal.  In addition, ?eal estate
  taxation provides  means of financial contributions from unde-
  veloped property for the benefits received from having a wastP
  water system available and ready to  serve.   From a tax payer's"
  point of view,  the ad valorem tax takes preference over the ser
  vice  charge since  the former is  a tax deductable expense.   Ovlr-
  shadowing the above described benefits  of an ad valorem tax are
  the inadequacies and special problems that  are  encountered in it*
  use.  One  objection to  an ad valorem based  on  a taxation system
  for wastewater  treatment  is  that  the  users  do  not  pay in proper
  tion  to  their use  of the  system.   For example,  in  industrialized
  areas such  as Buffalo,  the cost recovery system that  favors  the
  property tax places  a disproportionately large  charge  for  waste
  water treatment on  those  industrial or commerical  properties
  that produce little  or no industrial  wastewater.   Similarily
  those industries with a large volume  of  wastewater in  proportion
  to their property investment would pay less than their fair share.

      On the other hand, wastewater service charges can provide
 for financial support of collection and  treatment  systems when

 sys?em?nsucheasf6me ^ re£lects the actual Physical use of the

      1.   Volume  of wastewater as  determined by water meters
 hv Rnn'  cV?1Um\?f wastewater plus pollutant load as measured
 by BOD,  S.S., chlorine demand, phosphorus, etc.
     3.   Number  and size of sewer connections
 manufacturSI.°f ^°^"^ 5uch as residential,  commercial or

     5.   Number  and types  of  plumbing fixtures.
     6.   Uniform rates per dwelling unit,etc.

     The  philosophy used here is  that  the cost  is being distri-
 buted  according  to  the benefit and use made  of  the  system   Com
 munity benefit,  readiness  to  serve, and  ability  to  pay factors
 are not considered.   One of the advantages of the service charts
 system is that it permits  fair charges to churches, schools   or-
ganizations  and  other governmental  units  that are exempt  for
property taxes.



 Financing and charges for Wastewater Systems.  American Public Works Assc
 American Society of Civil Engineers. Water  Pollution  Control Federation''
 1973.  p37-40.                                            erdtion.
                               56

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     An additional benefit that the wastewater  service  charge
tends to provide is the reduction of wastewater being discharged
from industries.  When industry is paying  for every liter,  gm of
BOD, S.S. and P, that is discharged, they  may find that is  has
become more economical to improve the  quality and/or reduce the
quantity of their discharge.   Such a reduction  in wastewater
volume or pollutant loading  is generally advantageous to both
the industry and the community.

     On  the negative side,  the point can be raised that such a
system does not provide for  payment by undeveloped property as
for the  benefits of having  facility  capacity available  whether
used or  not.   It also does  not consider the benefits the com-
munity derives  as  a result  of having wastewater collection and
treatment adequate for health protection, nuisance elimination
and aesthetic  enjoyment of  waterways.   In addition, how can the
lost associated with  infiltration,  inflow and future use be
equitably apportioned  since these costs are not a function of a
user's loading?

     Thus,  it  is  obviously  unfair to raise the  annual  revenues
reauired entirely  by  the  ad valorem tax method.   Similar ily,
I?qis  unfair  to expect the  present users  to pay the  entire  cost.
Consequently,  the  best system to meet the revenue   requirement
for p?oviding secondary wastewater treatment in an  industrial
community under PL 84-660 would be a  combination  of the two
methods  previously discussed, where part  of the cost of the treat
mint workTis obtained from charges to  property or  an  ad valorem
?ax! special assessments and/or a special wastewater treatment
 surcharge.8

      For the Buffalo system,  a volume and loading base was used
 -For the costs resulting from  point source discharges,  Ue.





 COST RECOVERY  AND USER CHARGE SYSTEM  FOR BUFFALO

                    mentioned, Buffalo cost recovery and user
 Suitable Recovery of Industrial Waste Treatment Costs in Municipal Systems.
  EPA.  October 1971.  p5.

 9Stoats  E B  Decision - Use of Ad Valorem Tax to Satisfy Statutory Require
  menf forB;BUsereSaS System for Water Treament Works. Comptroller
  General of the United States.  B-166505.  July 2, 1974.  p2.
                                 57

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 valorem tax was used as a base for non-point source contributions

      The BSA's secondary treatment plant has a number  of  design
 considerations (flow,  BOD,  S.S.,  P04)  and the relative propor-
 tions charged to users and  property owner,  differ for  the various
 unit processes.  For example,  the pump station,  final  settling
 tank, chlorine tank, plant  outfall and modification to the gate
 chamber were all designed based on flow.   Consequently, the costs
 should be distributed  based on flow.   On the other hand,  the grit
 disposal facility,  the modification of the  primary tanks  and the
 primary digesters were designed based  on the suspended solids
 loading.  Since the capital as well as the  0§M costs of the treat-
 ment facility are directly  related to  the parameters for  which it
 was  designed, the allocation of the relative proportion of the
 works to the users  of  the system  or the property owners should
 be based on these same parameters.

      To derive the  formula  for the allocation of capital  costs,
 the  new plant was broken down  into the twenty individual  facili-
 ties with each being assigned  its  portion of the total cost rela-
 tive to the appropriate design parameters.   Table 7  shows  the
 distribution for  the estimated construction costs of BSA's  new
 secondary treatment plant.   This  breakdown  resulted  in:   41.6%
 of the  total construction costs being  attributed to BOD removal;
 30.8?  to flow;  25.3% to S.S. removal;  and 2.31  to P04  removal.

      The allocation of the  estimated first  year  0£jM costs  were
 arrived at in much  the same manner with the  costs of the  fifteen
 unit operations being  apportioned  according  to design parameters
 as shown in Table 8.   This  apportionment  resulted in:  411  of
 the  total 0§M cost  assigned to  S.S. removal;  25.5% to  flow;  17.5%
 to BOD  removal;  and 161  to  P04  removal.

      Based upon the material balances  discussed  in Section  V, and
 the  plant's  design  criteria, the  loadings received at  the plant
 were  distributed  to the  users  as  shown in Table  9.  Nineteen
 percent  of the  first year's  costs,  both capital  and 0§M will be
 collected from  all  taxable  real property with  the remaining  81%
 collected from  users.

     The  preceding  paragraphs  laid  the groundwork for the deter-
mination  of  unit  rates,  rate formulas  and charges.  The alloca-
 tion of  capital and  operating  and maintenance costs as shown in
Table 9,  relate   the unit costs of  waste  treatment of each  indi-
vidual user  based on the waste characteristics actually being
discharged.

     It is neither administratively nor economically feasible to
measure the  strength and  charge each individual  user of a  sewer-
 age  system.   Therefore  the  BSA established  as  a  standard  for
 domestic  strength waste  250 mg/1 BOD,  250 mg/1 S.S. and 15.35 mg/1


                               58

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           Table 7.   DISTRIBUTION OF BSA'S CONSTRUCTION COSTS BY DESIGN PARAMETERS
t/l
tO

Facilities
Modifications to Primary
Grit Disposal Facilities
Settled Wastewater Pump Station
Secondary Treatment Units
Blower Building
Final Settling Tanks
Chlorine Contact Tanks
Sludge Concentration Tanks
Sludge Disposal Facilities
Plant Outfall Sewer
Gate Chamber
Phosphate Removal Facilities
Preliminary Site Preparation
Roadways and Grading
New Electric Service
Heating and Ventilation
Administration Building
Miscellaneous Structures
Maintenance Shop
Technical and Legal Costs
Total
Percent of Total
Breakdown By Design Parameters
Flow
$ -
7,698,680
18,587,080
5,750,810
656,600
331,440
3,875,580
1,109,790
445,450
1,299,220
574,440
1,612,970
459,370
7,255,840
$49,657,270
30.8%
S.S.
$ 2,410,430
170,660
6,836,410
17,610,860
™
3,183,520
911,610
365,900
1,067,220
471,860
1,324,940
377,340
5,960,150
$40,690,900
25.3%
BOD
$ -
34,066,760
7,841,010
721,620
1,858,920

5,234,550
1,498,940
601,650
1,754,790
775,870
2,178,550
620,450
9,800,090
$66,953,200
41.6%
P
$
1,808,670

647,920
289,410
82,870
33,260
97,020
42,900
120,450
34,300
541,830
$3,698,630
2.3%

Total
$ 2,410,430
170,660
7,698,680
34,066.760
7,841,010
18,587,080
c yen R1 n
7,558,030
21,278,450
656 600
m440
647,920
12,583,060
3,603,210
1,446,260
4,218,250
1,865,070
5,236,910
1,491,460
23,557,910
$161,000,000
100%

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Table 8.  DISTRIBUTION OF BSA'S 0§M COSTS BY DESIGN PARAMETERS

Facilities
Raw Wastewater Pump Station
Administration Building
Grit Tank and Building
Sedimentation Tank and Building
Settled Wastewater Pump Station
Thickener and Filter Building
Incinerator Building
Blower Building
Chemical Building
Aeration Tank and Building
Final Tank and Building
Chlorine and Traveling Screen Building
Digester Control Building
Laboratory
Miscellaneous
Total
Percent of Total
Breakdown By Design Parameters
Flow
I 267,300
162,100
-
409,700
-
-
-
1,905,900
-
-
235,600
16,400
-
573,400
£3,570,400
25.5%
S.S.
$ -
139,000
137,900
98,500
-
1,078,500
3,255,700
-
79,400
_
92,400
54,300
131,500
93,800
573,400
$5,734,400
41%
BOD
$
139,000
34,500
98,500

_
_
985,400

301,700
92,400
72,500
16,400
147,400
573,400
$2,461,200
17.5%
P
$ -
$ 23,100

4,100

_
_
1,985,300

_
_
_
26,800
191,200
$2,230,500
16%
Total
$ 267,300
463,200
172,400
197,000
413,800
1,078,500
3,255,700
985,400
3,970,600
301,700
184,800
362,400
164,300
268,000
1,911,400
$13,996,500
100%

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    Table  9.  FIRST YEAR COST DISTRIBUTION - BSA SYSTEM
Capital Cost Distribution 0$M Costs Distribution
Parameter
BOD
S.S.
P04
Flow
Total
A
27.7
50.4
34.7
5.6
26.8
B
2.0
0.5
-
10.4
5.1
C
2.2
1.9
13.6
11.1
4.2
D
43.1
33.8
25.8
59.9
45.5
E
25.0
13.4
25.9
13.0
18.4
B
3
1
0
11.0
3.6
C
3
4
21
11.8
8.2
D
60
68
40
63.5
59.0
E
34
27
39
13.7
29.2
Chargeable to Property

A.  Future Use -  %
B.  Infiltration -  %
C.  Scajaquada Creek -  I
Chargeable to Users

D.  Residential -  I
E.  Industrial -  %
                            61

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 PO*  to be used in establishing the basic sewer use charge.  In
 addition, since high strength wastes are directly responsible
 for  increased costs at the treatment plant, an extended charge
 or surcharge, over and above the basic sewer use charge, is
 levied against industries discharging wastes with strengths
 above the domestic waste standard.

      The individual users of the Authority's facility have been
 broken down into four groups or classes as follows:

      1.   Domestic users  residing in Buffalo
      2.   Industrial and  commercial users in Buffalo
      3.   Domestic users  outside of Buffalo
      4.   Industrial and  commercial users outside of  Buffalo

      Each one of these groups  that avails themselves of the ser-
 vices  of the  Sewer Authority will pay an identical basic unit
 rate  for flow,  BOD,  S.S.,  and  P04 concentrations.  However, the
 0§M rate charged to the  industrial users has been adjusted to
 take  into account the additional  administrative  and  engineering
 costs  associated with the  industrial  waste program described in
 the previous  sections.
are:
     Those special  industrial  rates  for  the  first  year  0§M costs
                   Flow  -  $0.017/1000  liters
                   BOD   ^  $0.090/kg.
                   S.S.  ,  $0.260/kg.
                   P04   -  $1.573/kg.

     Based on the allocation of loading previously described
and shown in Table 9, rate formulas were developed.  There  are
two basic formulas, the  first for computing the  charge  to the
customers who discharge  only domestic  strength waste and the
second for computing the rates charged to the industrial user.
The domestic rate formula  consists of  two terms  and is  stated
as thus:

    Domestic Treatment Charge  = Domestic User Charge + Property Charge

     Each of the above terms contains  a portion  of the  capital
as well as the operating and maintenance costs.

     The unit rates which apply to the above formula and all users for
their share of the capital and OfTM costs are as  follows:

     Rates For Capital Costs        Rates For 0§M Costs
    Flow - $0.008/1000 liters    Flow  - $0.015/1000 liters
    BOD  - $0.062/kg.             BOD   - $0.081/kg.
    S.S.  - $0.031/kg.             S.S.  - $0.233/kg.
    P04  - $0.060/kg.             P04   - $1.401/kg. -

                              62

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     By using the domestic strength waste characteristics,  all
the unit rates for user charge can be expressed  in  terms  of flow
as follows:

          Domestic User Charge   = $0.078/1000 liters
          Industrial User Charge = $0.106/1000 liters

     Using the appropriate unit cost and  the  total  assessed
valuation of taxable property in the City of  Buffalo,  a property
rate of $2.32/$1000 and $1.75/$1000 of  assessed  valuation for
the capital and operations portions, respectively,  was derived.
It must be kept in mind that the formula  equates charges in
dollars to water consumption in thousands of  liters.

     The industrial rate formula is only  an expanded  version of
the formula for domestic discharges just  described.  It consists
of three basic terms,  as follows:

Industrial Waste Treatment Charge = Domestic User Charge + Property Charge +
Surcharge

     The simple addition of  the surcharge term makes  the formula
broadly applicable  to  all  industries.   When applying  it to an
industry that discharges only domestic  strength waste, the last
term just  drops out and  the  formula becomes that of a domestic
user.  The  surcharge  portion, as  stated below, provides an ad-
ditional charge for each milligram of  BOD,  S.S., and PO. being
discharged  over and above  what  is  considered domestic strength
waste:

Surcharge = Q(0.152(BOD - 250) + 0.291(SS - 250)  + 1.63CPO. - 15.35) )
where:     Q =  average annual discharge  rate expressed in million liters/year

     The determination of  waste characteristics that would de-
fine an upper limit for  domestic  strength waste required a great
deal of  investigation.  We reviewed ordinances  from other  muni-
cipalities  across  the country and it was found  that the  range
of values  adopted varied from 250 mg/1 to 350 mg/1 for  BOD and
suspended  solids.   Since the Buffalo metropolitan  area  has al-
w^ys had what would be considered a weak waste,  it was  deemed
appropriate to use the low values.  Therefore,  250 mg/1  was
 selected  to define the concentrations  of BOD  and suspended solids
 in Buffalo's  domestic waste.  The typical domestic concentrations
 of phosphorus was established at 15.35 mg/1  as  P04, or  5 mg/1
 as P.   Shown in Table 10 is an example of  the application  of the
 industrial waste formula.

 ECONOMICS OF REDUCING INCOMPATIBLE POLLUTANTS LOADING

      In the Buffalo system, three areas  were investigated  for
 the pretreatment of incompatible pollutants:   industrial pre-
 treatment, municipal  treatment^ and dilution.   It should be

                               63

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0\
-£»
                      Table 10.  APPLICATION OF INDUSTRIAL WASTE RATE FORMULA

    Formula:  Industrial Waste Treatment Charge - Q(1000 liters)(0.106) + A(4.071) )

              Q(MLY)(°-152(BOD - 25°) + 0.291(SS - 250) + 1.63(P04 - 15.35) )
              Where A = Assessed Valuation in $1000
                             Industrial User

Let's assume Industry "X" has an assessed valuation of $1,087,740
When surveyed, this company was found to discharge 8,703,200 ipd
BOD was measured at 384 mg/1, but SS and P04 were below their re-
spective limits of 250 mg/1 and 15.35 mg/1.

                       QC1000 liters) = 3»176,679

                       VLY)= 3>177

                       A = $1,087.74

                       BOD = 384

Applying the Industrial Rate Formula:

Sewage Treatment Charge = 3,176,679(0.106) + $1,087.740(4.071) +
                          3,177(0.152)(384 - 250)

Sewage Treatment Charge = $405,860

-------
stressed that the results of these investigations apply specifi-
cally to Buffalo and other systems completing the same analysis
could have different results.

Pretreatment vs. Joint Treatment

     At the present time, EPA's regulations governing industrial
discharges into POTWs has not been finalized.  Therefore, Buf-
falo's sewer regulations were used to determine which industries
would require pretreatment.  A review of the IWS's results pro-
duced a total of 30 industries that would require substan-
tial pretreatment of heavy metals before discharge to Buffalo's
system.  It is anticipated that those industries which have
waste characteristics only slightly in excess of the limits es-
tablished by the regulations, will make in-plant or product line
changes to meet the new discharge limits.  With the exception of
one industry, the method proposed for pretreatment was single
stage lime precipitation.  It was anticipated that the remain-
ing industry would meet the limitations required by the sewer
regulations by increasing the efficiency of its present clari-
fication process.

     The minimum total capital cost required to meet the new
discharge limits was approximately 4.5 million dollars.  Table
11, Cost of Pretreatment Facilities by SIC Category, shows the
breakdown for the industries affected by SIC category.  Approxi-
mately half of the four million dollars will be used for the
pretreatment of discharges from plating processes.  In addition
to  12  electroplating  industries,  Buffalo has  four  industries
in the Motor Vehicle Parts category whose pretreatment require-
ments are primarily a result of captive plating operations.

     Equipment costs were based on the data presented in the
Electroplating Point Source Category.1°  Labor, chemicals and
sludge disposal costs were based on the rates being charged in
the Buffalo area for 1974.  Land costs were not included in
these estimates, and process discharges were segregated where
possible, to reduce the quantity of wastewater requiring treat-
ment.

     The potential reductions in surcharge levies were not taken
into consideration in the cost estimates since the reduction will
vary from industry to industry depending on the magnitude of the
surchargeable parameters being discharged.

     An alternative to having industries pretreat their waste
individually would be to expand BSA's proposed treatment plant
to provide the required treatment for incompatible pollutants.

 Common and Precious ^tals Segment of the Electroplating Point Source Cate-
 gory.  EPA-440/1-75/040.  April 1975.  p!53-179.


                              65

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     Table  11.   COST  OF  PRETREATMENT  FACILITIES  BY  SIC CATEGORY
# of
SIC Category Industries
Converted Paper Prod.
(2649)
Cylic Crudes
(2865)
Pottery Products
(3269)
Steel Wire
(3315)
Copper Rolling
(3351)
Hand and Edge Tools
(3423)
Plating
(3471)
Steel Springs
(3493)
Refrigeration Equipment
(3585)
Motor Vehicle Parts
(3714)
Industrial Supplies
(5085)
Industrial Laundries
(7218)
1

1

1

1

1

1

12

1

1

4

3

3

Total
Capital Cost
$ 0

0

84,580

310,000

657,140

292,790

1,010,280

50,850

80,450

1,064,500

147,280

267,480

Total
Annual Cost
$ 15,400

1,300

53,000

188,200

296,900

145,200

719,000

23,900

62,500

558,400

66,100

140,700

Totals
30
$3,965,350    $2,270,600
                              66

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For industry to have all pretreatment requirements waived, the
BSA would have to remove the  same  quantity of pollutants as would
be achieved by the sum  of  individual  industry pretreatment facil-
ities.  Table 12, below, shows  the quantity of heavy metals that
would have to be removed,  the projected plant influent, and the
required effluent quality.

   Table 12.  REQUIREMENTS FOR  MUNICIPAL HEAVY METAL TREATMENT
Parameter    Kg/day  Removed
                                 Calculated
                                 Influent  mg/1
  Required
Effluent mg/1
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
2.5
100.0
104.0
19.3
40.5
205.0
0.008
0.254
0.198
0.044
0.096
0.514
0.004
0.104
0.041
0.015
0.035
0.207
     The ability  of a municipality to meet these required  effluent
limits without using advanced treatment methods is very question-
able; however, some industrial treatment plants have reached
these low  levels  for soluble chromium, copper, nickel and  zinc
by using chemical precipitation.    The cadmium and lead limits
required effluent concentrations far below what could be ex-
pected by  chemical precipitation.

     For the  purposes of comparing costs, it was assumed that
chemical precipitation could remove the required quantities of
heavy metals.  Any advanced treatment processes that may be re-
quired would  result in an even higher cost for heavy metal treat-
ment at the BSA plant.  The Buffalo Sewer Authority would  most
likely use a  tertiary system to achieve the necessary removals
since the  organic portion of Buffalo's influent is already weak,
a further  reduction before biological treatment would not  be  de-
sired.  Therefore, it was assumed that a two-stage tertiary lime
treatment  system  would be employed.  Costs from The Guide^to  the
Selection  of  Cost Effective Wastewater Treatment Systems   , ad-
justed by  a factor of 2 as per An Analysis of Construction Cost
Experience For Wastewater Treatment Plants1-5, was used  for es-


nMetal Finishing Segment of the Electroplating Point Source Category. EPA-
  440/1-75-040-a.  April 1975.  Table 24.  plOO.

 'A Guide to the Selection of Cost Effective Wastewater Treatment  Systems.
  EPA 430/9-75-002.  July 1975. pB-1.

 !An Analysis of Construction Cost Experience for Wastewater Treatment Plants.
  EPA 430/9-76-002.  February 1976.  p44.
12
13
                                67

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  tablishing  the capital costs  shown  in Table 13.

         Table 13.  TERTIARY TWO-STAGE LIME TREATMENT COSTS

         Description                               Costs

         Capital Cost                           $21,900,000
         Annual Cost
            Amortized Capital                     2,334,900
            Labor                                   341,200
            Maintenance, Power and Heat             175,900
            Chemicals                             6,575,300
            Savings in Phosphate Removal       -  2,520,100
         Total Annual Cost                        6,907,200

                            Assumptions

                         101 interest
                         30 year amortization
                         400 mg/1 lime dosage

      The costs  for a municipal treatment of heavy metals  as  shown
 above,  would be  approximately  three  times what the total  cost
 would be for individual industrial pretreatment.   The  large  di-
 lution the industrial waste receives in  Buffalo's system  and re-
 sulting quantities of chemicals  required, make it uneconomical
 for the BSA to attempt treatment.  If advanced treatment  methods
 •should be required, then  this  would  result in  an  even  greater
 economic favorability for individual industrial pretreatment faci-
 lities .

      Even  though  the  BSA  has an  anti-dilution  clause in its  Sewer
 Use Regulations  (Section  VI),  a  concentration  based discharge
 criteria creates  the  potential for industry  to dilute  its  waste
 streams  prior to  discharge  to  avoid  the  need for  pretreatment.

 Pretreatment vs Dilution

      In  evaluating the  economics of  dilution versus pretreatment
 it  was found that  many  of the  industries  requiring pretreatment
 do  not have surchargeable pollutant  loadings and  would therefore
 only be  required to pay the domestic  rate  for  their discharges
 to  the sewerage system.  Figure  8, Electroplating Annual Costs
 for Meeting Effluent Limitations,  was developed to show the po-
 tential  for using  dilution as  a method for pretreating incompat-
 ible pollutants.    The unit costs for pretreatment were adopted
 from the electroplater's (SIC  3471) cost estimates as previously
discussed, using a minimum pretreatment plant  size of 6000 1/hr.
The costs for using dilution included the domestic rate of
$0.106/1000 liters and an average  cost for water of $0.224/1000
liters.
                               68

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       (A
       
       v>
       Q>
       U
       O
      O
      O
      O
      4*
       I


      CO
      O
      U
                         COST  TO PRETREAT
BASIS:
    5 YEARS AT  11%
    INCLUDES SLUDGE
    DISPOSAL.
                     20         40         60         80

                     PLANT  DISCHARGE - 1,000 liters/hr.
       CO
       « 15
       CO
       (A
       Q>
       U
       O
      O
      O
      O
         10
      CO
      O
      O
                   COST TO DILUTE
                      10          20         30         40         50

                      REQUIRED  NUMBER OF DILUTIONS

Figure  8 - Electroplaters Annual Cost  Options For Meeting  Effluent Limitations
                                   69

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      There  may  be  an economic  incentive  for  some  industries
 to use dilution as opposed  to  pretreatment.  For  example, an in-
 dustry with  a copper discharge 3.2 mg/1, presently would have to
 meet  a discharge limit of 0.4  mg/1 under the BSA  Sewer Regulations
 This  industry would  require  8  dilutions to reduce the 3.2 mg/1
 of copper to 0.4 mg/1 at a  cost of $1.79/1000 process liters.
 Pretreatment would be cost  effective if the industry's discharge
 rate  was 30,000 1/hr. since  the cost of pretreatment would be
 $1.60/1000 process liters.   However, if the industry's discharge
 rate  was 20,000 1/hr., the  cost of pretreatment would then be
 $1.92/1000 process liters and  dilution would be cost effective.
 This  clearly indicates that  the cost effectiveness of dilution
 versus pretreatment  of incompatible pollutants is a function of
 the quantity of water necessary to reduce the pollutants concen-
 tration to an acceptable level and the size of the pretreatment
 plant that would be  required.  While this indicates an area of
 potential problems,  the BSA will be able to recognize those in-
 dustries using dilution by the sudden increase in their water
 consumption.

     For the nine platers sampled, Table 14 shows their costs for
using dilution and pretreatment to reduce their discharge metal
 concentrations to the Sewer Regulation1 s limits. For seven of the
 nine  platers, the economics  favored pretreatment  with only two
 industries,  45-1 and 44-2,  showing dilution to be more economical
 than pretreatment.    In both these cases,  the BSA will recognize
 the use of dilution by the large increase (five and seven fold,
respectively) over their historical water consumption.

Table 14.  ELECTROPLATER'S OPTIONS FOR MEETING EFFLUENT LIMITATIONS


Plant
44-28
20-16
9-7
27-10
45-1
20-12
32-1
16-16
44-2

Discharge
1000 1/hr
19.5
18.0
45.5
4.9
20.2
11.2
12.8
10.9
18.8

Dilution
Required
15
36
19
43
5
217
30
13
7
Cost of
Dilution
$/1000 1
3.25
7.99
4.13
9.48
1.02
48.20
6.70
2.97
1.60
Cost of
Pretreatment
$/1000 1
1.96
1.67
1.29
3.05
1.90
2.36
2.23
2.38
1.95
                              70

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ECONOMICS FOR REDUCING COMPATIBLE POLLUTANT LOADING
Surcharge vs Dilution

     Some industries using the Buffalo treatment facilities will
be paying substantial surcharges for excess loadings once the
secondary treatment plant goes on stream.  With the higher costs
resulting from secondary treatment, surcharged industries may-
choose to reduce their loadings to the sewerage system by either
installing pretreatment equipment or diluting their discharge to
reduce concentration. As was previously mentioned, the use of di-
lution to reduce discharge concentrations is a violation of Buffalo's
Sewer Use Regulation. However, as was the case for incompatible
pollutants, there could be a potential for industries  to use di-
lution as a method of pretreatment to reduce surcharges. Figure 9
was developed to evaluate this potential. Shown are the surcharge
unit rates for various concentrations of BOD, SS, and  P04, as well
as unit  costs for dilution. In all cases, the cost for using dilu-
tion far exceeded the cost for paying surcharges. This is illus-
trated in the examples shown in Table 15. This data and an effec-
tive public relations program should eliminate any attempt by in-
dustry to dilute  its waste instead of paying  the  surcharge.

       Table  15.  COST OF DILUTION vs SURCHARGE  - EXAMPLES
        Industry  "X"
Surcharge Rate
        400  mg/1  S.S.
        300  mg/1  BOD
        10 mg/1 P0d
        Total     H
        Dilution  Rate
                     Decision:   Pay Surcharge
        Industry "Y"

        800 mg/1 S.S.
        600 mg/1 BOD
        38 mg/1 P04
        Total
        Dilution Rate
                     Decision:  Pay Surcharge
$0.045/1000 1.
$0.008/1000 1.

$0.053/1000 1.
$0.132/1000 1.
*

Surcharge  Rate

$0.160/1000 1.
$0.052/1000 1.
$0.040/1000 1.
'$0.252/1000 1.
$0.492/1000 1.
        Industry
        800 mg/1 S.S.
        1000 mg/1 BOD
        38 mg/1 PO,
        Total
        Dilution Rate
 Surcharge Rate
 $0.160/1000 1.
 $0.101/1000 1.
 $0.040/1000 1.
 SO.301/1000 1.
 $0.815/1000 1.
                     Decision:  Pay Surcharge
                                71

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     0.7 -
                                                MAXIMUM  SURCHARGE
                                           MINIMUM SURCHARGE
                            234
                 REQUIRED  NUMBER  OF  DILUTIONS
Figure 9-  Dilution  Costs Vs  Surcharges  For  The B.S.A.  System
                                 72

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Surcharge vs Pretreatment

     Because industries have such varied product lines and waste
characteristics, even within the same SIC category,  the evaluation
of the economics for pretreatment versus payment of  surcharges
would be done on an individual basis.  Therefore, Figure 10 was
developed only as a guide to indicate whether pretreatment of
compatible pollutants would be economically justified before dis-
charge to a municipal system.  Costs were developed  for three
unit processes:  clarification, chemical precipitation, and bio-
logical treatment.  The costs and process efficiencies were ob-
tained from the manufacturers of the various types of equipment.
Amortization of the capital costs was based on a five-year payback
at an 11% interest rate.  It must be kept in mind that on a case
by case basis, the economics may favor a different type of pro-
cess or any combination thereof.  The removals that  might be ex-
perienced from these processes are shown in Table 16.

              Table 16.  REDUCTIONS  FROM PRETREATMENT
Process
Clarification
Chemical Treatment
Biological Treatment
Percent Removal
BOD SS P04
30 45 5
60 80 80
85 85 10
      The  removals  shown  in Table  16  are  a  generalization, and it
 should  be pointed  out  that in practice,  the removals  shown above
 may  vary  depending upon  the  specific waste characteristics.  _For
 example,  an industry having  a high  concentration  of S.S.  in  its
 discharge, the majority  of which  is  settlable, will undoubtedly
 obtain  better than 45% removal  with a  properly sized  clarifier.

      In general,  clarification  was  the least  expensive  method for
 pretreatment; however, it  is obvious that  if  an  industry  is  only
 surcharged for BOD, unless the  waste stream  contains  a  I*****
 percentage of insoluble  BOD, clarification may not• be cost effec
 tive, versus payment  of  the  surcharge.  Therefore Before design
 ing  a pretreatment facility, an industry should  thoroughly inves
 ti|ate  all possible alternatives  including the possibility of
 segregating sources of its waste  streams to  reduce flow quanti-
 ties .

      In order to obtain  an idea of the relative  costs of  ^treat-
 ment versus the cost of  BSA's  surcharges,  the discharges  from
 three specific industries were evaluated.   The  surcharges and
 waste characteristics for these industries can be found in Table
 17.
                                73

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175
150 -
                                          BIOLOGICAL  TREATMENT
                                 CHEMICAL TREATMENT,
                                         CLARIFICATION
            200
1000
                             400        600       800
                             DISCHARGE - 1000 liters/day
Figure  10 -  Annual  Cost  For  Pretreatment  Of  Compatable  Pollutants
NOTE: Capital  Costs Obtained From Vendors  Quotas
                           74

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           Table 17.   EXAMPLE OF INDUSTRIAL SURCHARGES
Industry
29-3 Converted Paper
Surcharge
17-9 Fats and Oils
Surcharge
37-7 Sausages
Surcharge
Flow-
Megaliters
0.341
1.540
0.901
BOD-mg/1
191
None
908
$56,238
1990
$59,577
SS-mg/1
5486
$189,347
215
None
423
$11,332
P04-mg/l
3.1
None
5.23
None
562.3
$201,135
     Looking first at Industry 29-3,  the computed surcharge
amounts to $189,347 per year as a result of the discharge of ex-
cess suspended solids.   The installation of a clarification pre-
treatment unit would normally result  in a 45% removal of the
S.S.; however, data from the IWS indicated that clarification
with the addition of polyelectrolite  would remove enough S.S.
to eliminate any surcharge.  From Figure 10, the annual cost for
clarification was approximately $30,000 and $7,000 for polyelec-
trolite addition, for a total annual  cost of $37,000.  Comparing
this cost to Industry 29-3's surcharge in Table 15, shows that
the use of pretreatment would result  in a savings of $152,000
per year.  For Industry 27-9, the economics favor the payment of
the surcharge.  In this case, the surcharge of $56,238 per year
was less than the annual cost of installing clarification equip-
ment which would only remove 30% of the BOD.  Industry 37-7's
waste discharge is surchargeable in all three categories re-
sulting in a total surcharge of $272,040 per year.  Pretreatment
consisting of chemical precipitation would eliminate the sur-
charges for S.S. and P04 at a cost of $80,000 per year and the
BOD surcharge would be reduced to $18,695. In this case, the
installation of pretreatment will result in an annual savings
to the industry of $173,345.

     As shown, pretreatment of compatible pollutants can be
economical for some of the industries.  Again, each industry
should be evaluated individually to determine the economics of
pretreatment.
                               75

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                             SECTION 8

        COMBINED  DOMESTIC  AND INDUSTRIAL WASTE TREATMENT
INTRODUCTION

     Combined  treatment  of  industrial and domestic type wastes is
often economically  beneficial  to the treatment agency and its
users.  However,  as  discussed  in earlier sections, the discharge
of industrial  wastes  into POTWs  must be controlled so that the
treatment plant  can  function at  maximum efficiency with a mini-
mum of cost.

     POTWs accepting  industrial  wastes, especially those upgrad-
ing from primary  treatment  or  those who have not yet received
their NPDES permits must carefully evaluate their entire sewer-
age system before establishing industrial waste control policies.
One significant  area  which  should be examined is the operation
and efficiency of the treatment  plant.   Treatment plants are de-
signed and operated  to remove  specific  pollutants, such as BOD
and S.S. However, other  pollutants may  also be removed, to a
lesser degree, in the treatment  processes.  The removals of in-
soluble phosphorus  and metals  in the clarifiers are typical
examples of incidental removals.   It would be beneficial to its
industrial users  if  the  treatment agency could reduce the pre-
treatment requirements by taking advantage of these incidental
removals.  However,  the  treatment agency must keep in mind that
when incidental  removals are achieved the decrease in pollutant
levels in the  liquid  or  effluent stream will result in an in-
crease in the  pollutant  level  in the sludges, thus possibly
limiting their~sludge disposal options.  Therefore, the treat-
ment agency must  carefully  evaluate their specific conditions to
insure that the benefits gained  are greater than the problems
that may arise.   The  Environmental Protection Agency has pro-
vided for the allowance of a credit to industries for incidental
removals.  This policy is described in  the following quotation
from Section 128.133  of  40  CFR 128:

     "...Provided,  that, if  the  publicly owned treatment works which
     receives the pollutants is  committed, in  its NPDES permit, to
     remove a specified percentage of any incompatible pollutant,
     the pretreatment standard applicable to users of such treatment
                              76

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      works shall be correspondingly reduced for that pollutant..."14

DESCRIPTION OF PILOT PLANT INVESTIGATIONS

      Since the upgrading of Buffalo's primary treatment plant to
secondary treatment is only in the initial stages of construction,
a 95,000 liter/day pilot study was conducted to evaluate the ef-
fects the industrial users will have  on the treatment  processes.
This investigation was primarily concerned with three  areas: de-
fining the metal concentrations in the sludges, exploring the
possibilities of credits for the incidental removals of heavy
metals, and to compile background data for finalizing  Buffalo's
NPDES permit.

      So that the data generated by the pilot study would have the
maximum applicability to the Buffalo  sewerage system,  a package
treatment plant was modified to simulate  as closely as possible
the characteristics and operation of  Buffalo's new plant.   In
order to incorporate the daily fluctuations in waste strength and
volume normally experienced in a full scale plant, the influent
to the pilot plant was varied in direct proportion to  the flow
received at the Authority's primary plant.  As shown in Figure 11,
the process piloted was a conventional activated  sludge with the
addition of the chemical precipitation of phosphorus in the
aeration tank.

      It took 43 days for the process to  reach a  steady state
condition.  The pilot plant was then  monitored for a period of
30 days to trace the movement of heavy metals  through  the
system.  This was accomplished by daily analyzing flow proportion
samples of the  influent and secondary effluent.   The primary
effluent, waste primary, and waste secondary  sludge were  sampled
daily and weekly composites analyzed  for  heavy metals.

      During  the beginning of the acclimation period,  the  food/
mass  ratio was  quite high due to the  low  quantities of mixed
liquor volatile suspended solids.  This was attributed to  the
slow  acclimation of the biomass to the wastewater.  The  extended
period of  time  required for acclimation was a result of  the un-
usually wet weather Buffalo was experiencing.  During  the  opera-
tion  of the pilot plant, precipitation fell approximately  501  of
the time.  Since 96% of the Buffalo's collection  system  is  com-
bined, the dilution from the  storm water  inflow  created  an ex-
tremely weak  waste.  During this start-up period, the  influent
BOD varied from 19.5 mg/1 to  a  high  of 97.5 mg/1.  In  order to
provide additional  food for the biomass  during this period, the
primary clarifier was by-passed and  the  influent  was  fed  directly
into  the  aeration  tank.  As the plant became  acclimated,


14Pretreatment Standards, Part 128.  Federal Register. Vol. 38.  No.  215.
  EPA.  November 8, 1973.  p30984.

                                77

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      INFLUENT
      95,000 liter/«QV
oo
                        SETTLING RATE-
                          37,000 l/m%Qy
   CLARIFIER
WEIR RATE-
    103,6001/m^
 DETENTION -
                              SLUDGE
                           WASTE
                           SLUDGE
                                                                    COAGULANT  AID ADDITION
                                            FeCl2
                                 RECYCLE
                                 SLUDGE
                                                             t
DETENTION - 2.86 hf.
Ft* -  I2.8IRQ/I

AERATION UNIT

COA8ULANT- 0.6m9/l
                                                           SETTLING -
                                                              £6,500 t/m7do/

                                                            CLARIFIER
                         Figurelh  B.SA*S  ACTIVATED  SLUDGE  PILOT  FLOW  DIAGRAM

-------
the primary clarifier  was put back in operation.   Additional
quantities of secondary sludge were recycled to the aeration tank
to compensate for the weak influent.

     New York State standards require that the concentration of
phosphorus in a POTWs effluent average 0.5 mg/1 with a maximum
concentration not to exceed 1 mg/1.  Ferric chloride (FeCl^) was
used to achieve the required phosphorus removals.   Commercial
FeCls diluted to the proper concentration was fed by means of a
metering pump to the head  of the aeration tank.  By locating the
FeCls addition at this point, proper mixing of the FeCls and
mixed liquor was insured.  To allow for the pilot plant to sta-
bolize, the addition of FeCls was started one week prior to the
heavy metal monitoring of the system.

     On the 18th of November, monitoring of trace quantities of
heavy metals began.  The pilot plant was well acclimated and oper-
ated efficiently in spite of the lower than desired level of mixed
liquor suspended solids.

     In the first two weeks of the monitoring period, the sus-
pended solid removals were below the desired level.  It was felt
that this was caused by a pin point floe that is created by the
vigorous mixing occuring in the aeration tank.  During the third
week of the monitoring period, an attempt was made to correct
this condition by changing the single feed location of the FeCls
to two points.  This did increase the suspended solids capture
but did not bring it up to the desired level.   In the fourth
week, the second FeCls point was replaced with  a polymer addition.
This resulted in a greater suspended solids capture than was pre-
viously achieved, however, it was still .below the desired remov-
als.

DISCUSSION OF RESULTS

     The  level of treatment  achieved by  the pilot plant was
slightly  lower than  that which will be required of Buffalo's
secondary  treatment  plant.   This was attributed to the  low  in-
fluent concentrations  and poor performance of  the  secondary  clar-
ifier.  It is expected that  the  full scale plant will average
higher BOD and suspended  solids  removals  since  the treatment
units  are more precisely  designed.  A  summary  of the operational
data can  be  found  in the  appendix.

     The  monitoring  of toxics  in the pilot plant,  was conducted
to  indicate  the  removals  that  could  be  expected and  the quantity
of metals  which  build up  in  the  sludges.   While their determina-
tion was  beyond  the  scope of the project,  some  comments on  tne
possible  removal mechanisms  are  pertinent for  interpreting  the
data.  Many  of  the  metal's  removals  varied with influent  concen-
trations.   However,  the large degree of variation in the  removal
indicate  that  other factors, such as  complexing ligands,  ionic

                               79

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 strength and volatile suspended solids  concentrations,  affect
 the  removals obtained.  Adsorption of metals  onto  the  solid
 phase and the removal of insoluble metals by  settling  probably
 accounted for the majority of the removals  obtained.   The  contri-
 bution from metal precipitation was thought to  be  minimal  due  to
 the  pll and relatively low metal concentrations  in  the  influent.

      To establish the criteria that would enable the BSA to pre-
 dict the metal removals that could be expected  and the  metal con-
 centrations that would be found in the  sludges, balances were
 performed on the pilot plant as shown in Table  18.  The background
 data for these balances, Pilot Sludge Characteristics  and  Daily
 Trace Element Concentrations can be found in  the appendix.   Due
 to weekly instead of daily sludge analysis  and  also to  periodic
 freezing and leakage of the waste sludge lines, the results on the
 primary and secondary unit balances were not  as accurate as the
 balances around the entire pilot plant, since the  influent  and
 effluent streams were analyzed daily.   Based  on the results of
 the  balances,  the heavy metal concentrations  for the pilot  plant's
 effluent and waste sludge streams were  projected as shown  in
 Table 19.   To  investigate the effects these metal  concentrations
 will  have on the BSA sludge disposal options, projections were
 made  for sludge concentrated to 20% solids  and  for ash.  This
 will  be discussed in more detail later  in this  section.

      The balances for the various metals indicated that better
 than 60% removals could be expected for lead, chromium  and  cop-
 per.   Less,  but significant,  removals were  also obtained for zinc
 and  cadmium,  while nickel and cyanide exhibited insignificnat  re-
 movals.   This  information,  together with the data  previously de-
 veloped for the sewerage system, enabled the BSA to develop sewer
 use  regulations which suits its system.  For example, the dis-
 charge  limits  for lead need not be as stringent as those for
 nickel  since a larger percentage of lead is removed at  the  Auth-
 ority's plant.   Other investigations across  the country  have also
 shown that significant roftal  removals could be obtained by  muni-
 cipal treatment plants.   '   '    Based on actual removals being
 obtained by their treatment plant, the municipality of  Metro-
 politan Seattle has already requested that consideration should
 be given to  these removals  in determining Metro's  NPDES permit.
 The  removals  achieved during  Buffalo's pilot study were lower


 15Cheng M.H, Patterson J.W., and Minear R.A.  Heavy Metals Uptake by Activated
  Sludge.  WPCF Journal.  Vol. 47.   No. 2.  Feb. 1975.  p362-276.

 16Brunner C.A.  EPA Correspondence to John T. Rhett.  Removal Capability of
  Wastewater Treatment Processes for Metals and Other Pollutants.  8/20/74.
  pl-12.

17Esmond S.E., Petrosek A.  Dallas Water Utilities Dept.  Removal of Heavy
  Metals by Wastewater Treatment Plants.  March 1973.  pl-16.

                               80

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Table 18.  TRACE ELEMENT BALANCES ON BSA'S PILOT PLANT
Description

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall % Removed


Influent Sewage
x Primary Effluent
-> Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall % Removed

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall % Removed
-4
Weekly Quantities - Kg/day x 10
Week 1

78.58
384.13
0.15
increase
98.16
—
74.50
125.10
increase


1096.8
853.3
12.2
22.2
458.9
46.2
43.0
58.2

561.5
527.1
0.0
: 6.1
| 406.3
22.9
; 72.4
27.6
Week 2 Week 3
Cadmium Balance
155.22
145.33
0.59
6.40
71.34
40.86
50.90
73.00
54.00
139.81
148.41
1.41
increase
74.41
10.90
49.90
62.00
47.00
Chromium Balance

1094.9
1211.0
10.3
increase
455.0
1024.2
62.4
136.0
58.4
2049.6
2091.4
27.1
increase
553.2
294.6
73.5
42.7
73.0
Week 4

64.33
65.29
1.68
increase
47.60
8.63
27.10
90.00
26.00


885.6
1044.6
23.4
increase
512.3
219.3
51.0
85.3
42.2
Copper Balance ;
715.7
484.4
4.3
32.3
275.8
653.8
43.1
130.0
61.5
1002.3
877.0
17.9
12.5
274.5
384.9
68.7
40.0
i 72.6
795.3
783.4
18.9
1.5
261.7
397.4
66.6
52.0
67.1
Week 5

90.09
86.98
1.20
3.45
44.81
6.81
48.50
59.00
50.00


1062.7
1381.5
15.9
increase
243.3
143.5
82.4
37.9
77.1
Study
Period

528.03
830.14
11.06
increase
336.31
67.20
59.50
78.50
36.30


6189.6
6581.8
88.9
increase
2222.7
1681.6
66.2
64.5
64.1
j
1038.8
921.0
16.5
11.3
332.1
136.7
63.9
47.0
68.0
4113.6
3592.9
57.6
12.7
1550.4
1572.8
56.8
77.3
62.3

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Table .18 continued.  TRACE ELEMENT BALANCES ON BSA'S PILOT PLANT
Description

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
\ Removed in Secondary
Overall 1 Accounted For
Overall % Removed

Influent Sewage
oo Primary Effluent
t° Primary Sludge
\ Removed in Primary
Secondary Effluent
Secondary Sludge
1 Removed in Secondary
Overall % Accounted For
Overall % Removed

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall 1 Removed
Weekly Quantities - K>/r1ay x 1P~4
Week 1

282.6
430.0
3.4
increase
297.9
-
30.7
106.6
increase

1036.8
843.1
2.7
18.7
223.5
-
73.5
21.8
78.4

20.700
179.500
0.018
increase
37.600
-
79.100
181.700
increase
Week 2
Week 3
Cyanide Balance
205.5
N.D.
4.6
100.0
176.9
217.9
increase
194.4
13.9
408.4
1045.7
3.5
increase
339.8
78.1
67.5
103.2
16.8
Lead Balance
326.7
213.2
5.7
34.7
138.5
517.6
35.0
202.6
57.6
726.6
74.2
22.2
89.8
143.4
173.0
increase
46.6
80.3
Mercury Balance
2.000
N.D.
0.018
100.000
7.230
1.500
increase
437.400
increase
N.D.
20.20
0.14
increase
N.D.
0.77
100.00
Gain
-
Week 4

291.7
404.8
3.5
increase
338.2
65.4
16.5
139.6
increase

546.7
652.9
35.1
increase
140.4
250.6
78.5
77.9
74.3

N.D.
N.D.
0.059
_
N.D.
78.500
_
Gain
-
Week 5

222.7
547. 5
3. 1
increase
220.6
38.1
59.7
117.6
0.9

524.2
460.5
23.8
12.2
114.0
215.2
75.2
67.3
78.3

N.D.
N.D.
N.D.

N.D.
N.D.
_
_
-
Study
Period

1410.9
2428 .0
18. 1
increase
1373.4
399 . 5
43.4
126.9
2.7

3161.0
2243.9
89. 5
29.0
759.8
1156.4
66. 1
63.5
76.0

22.7
199.7
0.2
increase
44.8
80.8
77.6
554.2
increase

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                Table  18 continued.  TRACE ELEMENT  BALANCES  ON  BSA'S  PILOT  PLANT
Description

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall 1 Removed

Influent Sewage
Primary Effluent
Primary Sludge
% Removed in Primary
Secondary Effluent
Secondary Sludge
% Removed in Secondary
Overall % Accounted For
Overall 1 Removed
- 4
Weekly Quantities - Kg/day x 10
Week 1

291.7
351.5
23.2
increase
291.4
-
17.1
107.9
0.1

5313.2
2356.8
30.5
55.7
2957.8
-
increase
56.2
44.3
Week 2
Week 3
Nickel Balance
258.5
242.2
0.6
6.4
226.7
81.7
6.4
119.4
12.4
26.0
N.D.
2.7
100.0
8.1
21.8
increase
125.4
68.9
Zinc Balance
1532.2
1501.7
10.6
2.0
986.5
762.7
34.3
114.9
35.6
242.6
202.4
4.4
16.6
201.1
49.5
0.6
105.1
17.1
Week 4

608.3
522.3
3.7
14.1
563.1
31.3
increase
98.3
7.4

1902.3
1697.4
62.0
10.8
1026.1
357.3
39.6
76.0
46.1
Week 5

398.7
358.2
4.0
10.2
314.6
46.8
12.2
91.7
21.1

1494.0
1432.6
4.9
4.1
783.2
241.5
45.3
68.9
47.6
Study
Period

1583.5
1474.2
34.2
6.9
1403.9
181.6
4.8
102.3
11.3

10484.3
7190.9
112.4
31.4
5954.7
1411.0
17.2
71.3
43.2
CO

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                   Table  19.   CHARACTERISTICS  OF PILOT EXIT  STREAMS  -  SUMMARY
oo
Parameter

Lead

Chromium

Copper

Zinc

Cadmium

Nickel

Cyanide
A
Cone.
mg/1
0.099
0.210
0.140
0.340
0.018
0.050
0.051
B
Cone.
mg/1
0.025
0.074
0.050
0.200
0.011
0.047
0.046
%
Rem.
76
64
62
43
36
11
3
C
Cone.
mg/1
8.78
8.44
5.48
14.80
0.45
3.25
1.71
*
Rem.
6
5
5
4
2.5
2
1
D
Cone.
mg/1
7.64
11.11
6.85
9.32
0.44
1.20
2.64
\
Rem.
70
59
57
39
33.5
9
2
Ei-0.6% Solids
Cone.
mg/1
7.72
10.9
6.74
9.77
0.44
1.37
2.56
1
Rem.
76
64
62
43
36
11
3
E7-20% Solids
Cone.
mg/1
360
508
314
455
20
63
120
Cone.
mg/kg
2660
3760
2325
3360
150
460
890
£3 -Ash
Cone.
mg/kg
2660
3760
2325
3360
150
460
0
       INFLUENT  /'PRIMARY
                   CLARIFIER
                                      AERATION  TANK
                                                                                   EFFLUENT
             PRIMARY
             SLUDGE f
                      V

                                                                           SECONDARY
                                                                            SLUDGE
                                                      TOTAL SLUDGE

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than those reported by other investigators.  This is probably
due to the low influent concentrations in the Buffalo wastewater.

     The policy of crediting the removals obtained at the POTWs
in establishing discharge limits must be carefully considered in
light of removal variability and potential limitations for sludge
disposal.  Considering that sludge treatment and disposal costs
are typically 30% - 35% of a plant's annual costs, the metal
concentrations in the sludge should be considered not only in
developing the Sewer Use Regulations but also in the design of
the plant.  For example, if a POTW planned to dispose of its
sludge as a soil conditioner, they would have to require more
stringent discharge limits to insure that the metal levels would
be low enough so as not to inhibit the plant's digesters and be
acceptable for use as a soil conditioner.  However, if incinera-
tion was to be the chosen method for sludge treatment, a higher
metal content could be tolerated.  The controlling limitations
would be those imposed by regulations for the disposal of ash
and water quality.

VARIABILITY OF RESULTS

     The influent concentrations and the removal efficiencies
exhibited by the pilot plant had a high degree of variability.
This variability should be taken into account when establishing
discharge limits or determining credits.

     Summarized in Table 20 below, are the average removals, and
the influent concentrations with their respective standard devi-
ations for the trace elements measured during the study.  The
average removals shown below differ slightly from those presented
in Table 19.  The reason for this is that the removals shown be-
low were calculated from concentrations and do not include a
factor for the variations experienced in flow.  Whereas the re-
movals shown in Table 20 account for these flow variations.

Table 20.  AVERAGE INFLUENT CONG. § REMOVALS FOR PILOT OPERATION
Parameter
Lead
Copper
Chromium
Zinc
Cadmium
Cyanide
Nickel
Daily Removals - %
Avg. *
73.8
61.0
62.2
41.3
37.7
6.5
11.0
Std. Deviation
29.9
23.0
27.4
21.6
26.4
18.6
17.8
Influent Cone.
Avg.- mg/1
0.099
0.137
0.208
0.337
0.018
0.046
0.050
Std. Deviation
0.087
0.075
0.131
0.311
0.015
0.024
0.044
*Does not include a factor for flow variations.
                              85

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     From the daily graphs of metals influent concentrations and
removals, see Appendix, it was obvious that one of the major vari-
ables effecting the removals was the specific metal concentration
in the influent.   It was also found that there were specific con-
centration limits, below which, factors other than influent con-
centration  controlled the removals obtained.  For example,
Figure C-7, shows  the daily variations in zinc removals and in-
fluent concentrations.  Between December 9 and December 20, the
removal efficiencies seem to be directly related to the influent
concentrations.  However, between December 1 and December 8, the
influent concentrations were low and fairly constant while the
removals varied from 0 to a high of 71.4 percent removed.  Ob-
viously, some factor other than the variation in concentrations,
was affecting the  removals obtained.

IMPACT OF REGULATIONS ON THE BSA'S COMBINED TREATMENT

     The BSA, in establishing its industrial waste control pro-
gram, evaluated both Federal and New York State's pretreatment
requirements.  It  was.found that there were no federal require-
ments presently in effect and those that were proposed were being
re-evaluated.  New York State's published requirements are of a
general nature with the specifics being established on a case
by case basis, depending upon the water quality standards for the
POTWs receiving stream and their method of treatment.  Since
there were no firm guidelines available from either of the two
regulator agencies, the BSA established what they considered
stringent discharge limits for specific incompatible pollutants
and submitted them to EPA and New York State for approval.  Ap-
proval was obtained from EPA.  However, New York State required
that the discharge limits for chromium (hexavalent), copper,
zinc, cadmium, arsenic and cyanide be lowered.  While the dis-
charge limits were revised and incorporated into the Sewer Use
Regulations (Section VI), the BSA is presently working with
New York State to  re-evaluate  their imposed discharge limits in
order to reduce the pretreatment loading on industry.  Due to
today's poor economic conditions existing in the Buffalo area
which has already  been hard hit by plant closures, the BSA feels
that their discharge limits should not only be environmentally
sound but also have some relative stringency as the discharge
limits for other areas of the country.  The importance of having
uniform standards  was illustrated in the BSA's public meetings
when the point was brought up by a few industries that the dis-
charge limits being imposed by BSA are more stringent than those
in some other areas of the country.  This could provide the ad-
ditional incentive for these industries to relocate all or por-
tions of their plant operations in other areas of the country
having less stringent regulations.  One of the methods the BSA
would like to use  to reduce industry's pretreatment requirements
is to incorporate  into its discharge limits, a credit for re-
movals achieved at the BSA plant.  This would effectively raise


                              86

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the discharge limits while still maintaining the same discharge
quality.

     While the control of discharges of pollutants in toxic or in-
hibitory quantities from industry is important,  industry is also
an important contributor of compatible pollutants. Since the BSA's
new secondary treatment plant was designed for joint treatment,
the industrial contribution is necessary for efficient operation.
In addition to being a significant flow contributor,(17.7%) indus-
try contributes approximately 39% of the phosphorus, 34% of the
BOD, and 27% of the S.S. loadings. As discussed in Section 7, in-
dustry will pay for the expanded portions of the treatment facil-
ity required to treat its contribution at no additional cost to
the public.  The cost to each user will be equitable since the
charges are based on each user's waste characteristics. Practices
such as separate rates for industry and volume discounts will not
be allowed once the new treatment plant goes on stream.

     In the near future, two factors will affect the characteris-
tics of the industrial contributions to the BSA system. The adop-
tion and enforcement of the sewer regulations will reduce the a-
mounts of potentially toxic or inhibitory contaminents entering
the Sewer Authority's system. In addition, once industries install
pretreatment to meet the requirements, reductions would also occur
for BOD, suspended solids and phosphorus loadings. A rough esti-
mate of those reductions would be 1.5% of the BOD, 9.9% of S.S.,
and 4.5% of phosphorus loadings. The second factor affecting the
characteristics of the industrial contributions will be the sur-
charge levels. The cost recovery system requires an additional
charge be paid by industries discharging wastes with concentrations
in excess of 250 mg/1 of BOD and S.S. and 5 mg/1 of phosphorus.
Industries that will be levied high surcharges will probably in-
vestigate pretreating their wastewater prior to discharge into the
BSA's system. Estimates of those that may install pretreatment
cannot realistically be made at this time since other factors such
as the availability of land and money affect the ability of any
given industry to install the necessary equipment. A more detailed
discussion of the economics of pretreatment vs surcharge can be
found in Section 7.  The quantities of BOD, S.S. and phosphorus
contributed at  surchargeable levels is substantial.  Summarized
below, are the loadings arid percent of the total plant loadings,
contributed by wastewater having strenghts exceeding the limits
previously described for surcharge.

       Table.21.  SURCHARGEABLE LOADINGS IN THE BSA SYSTEM

                      Surchargeable Loading
Parameter                    kg/day            % of Plant Loading

   BOD                       12,530                    10.8
   S.S.                       4,222                     3.1
   P                            289                    13.3

                               87

-------
     It is expected that these quantities will be reduced by in-
plant control measures, product changes, and pretreatment.

     In some instances, the economics may favor a combination of
a direct discharge to waterways and a discharge to a municipal
sewerage system.  With the segregation of process stream, an
industry could discharge its pretreated incompatible pollutants
to a waterway and only discharge its compatible pollutants to
the municipal system, thereby lowering their sewer use charges.
Since this study was initiated, one industry has entered Buffalo's
system rather than pretreat for direct discharge.  In addition,
two other industries, a petroleum refiner and an inorganic chemi-
cal plant, are negotiating to redirect the compatible pollutant
portions of their waste discharged to the BSA's system.  In the
surrounding area, other industries are also expressing interest
in entering POTWs.

     It is difficult to predict, beyond a few years, what the
impact of the Industrial Wastes Characterisitcs will have on the
treatment plant since it is not known what the future require-
ments will be.  The new plant was designed to include the indus-
trial portion, their inclusion in the future would remain an
important factor from both a cost distribution and treatment ef-
ficiency point of view.

     One of the immediate impacts of the enactment and enforce-
ment of the BSA Sewer Regulations will be a reduction in the
quantity of potentially toxic material received at the treatment
plant.

     The primary toxic problem in the Buffalo system can be cate-
gorized as "heavy metals".  Another problem area, minor in nature,
was the industrial contributions of phenol, however, industries
contacted indicated this problem could largely be solved through
better in-plant control measures.  Insecticides and pesticides
were not found in measureable quantities at the treatment works
nor are they produced nor used to any great extent in the areas
served by the BSA system.

    Table A-l,  Characteristics of SIC Categories Summary,  in-
dicated twelve categories that contribute substantial quantities
of heavy metals.  The 12 categories consisted of 30 industries
which will require pretreatment.  For 30 of the 30 industries
requiring pretreatment, the method used in this analysis was
lime precipitation with CN destruction and Cr reduction, where
required.

     It should be recognized that alternative methods may be em-
ployed to achieve the necessary reductions.  The process used
for these determinations was single stage lime precipitation with
polymer addition which would generate 5% solids and could be de-
watered to a 20% cake.  The assumption was made with some reser-

                               88

-------
vation, that this unit process would produce an effluent meeting
the Sewer Regulation's limits.  The remaining industry can meet
the limits prescribed by the sewer regulations by clarification.
The quantities of metals that would be removed by this type of
pretreatment were totalized to obtain an estimate of the kilo-
grams per day of metals removed by pretreatment.  Each metal the
total quantity removed, was then contrasted against that metal's
present loading at the Authority's Bird Island Treatment plant
to show the reductions which could be obtained by pretreatment.
Summarized in the following table are the findings for each of
the parameters investigated.

     Table 22.  SUMMARIZED SLUDGE QUANTITIES FROM PRETREATMENT
Parameter
Copper
Lead
Nickel
Zinc
Chromium
Cadmium
Mercury
Present Ind.
Contribution
mg/1
0.198
0.044
0.096
0.514
0.254
0.008
0.0049
Removed*
Kg/day
104.0
19.3
40.5
205.0
100.0
2.5
0.04
Resulting Influent
mg/1
0.04
0.01
0.04
0.21
0.11
0.004
0.0048
% of BSA's
Plant Load.
79.0
66.3
63.4
60.1
59.1
48.1
1.3
*Quantities removed from plant influent if industries pretreated
 to the existing discharge limits.

     With the exception of mercury, pretreatment will substantial-
ly reduce the metal loadings received at the Bird Island Treat-
ment Plant.  In the case of mercury, only 1.3% reduction in the
treatment plant's loading was projected due to the pretreatment
of mercury.  It should be pointed out that only a few industrial
discharges exhibited mercury levels in excess of BSA's discharge
limits and over 89% of the mercury loading was from other sources.
Thus, little can be achieved by pretreatment.  The high contri-
bution of mercury from the Scajaquada Creek (56%) may be attri-
buted to industrial contributors outside of Buffalo's limits.
Once all of the required pretreatment facilities are established,
the Bird Island Plant could have a reduction in the present
loading ranging from 48.1% for cadmium to 79.0% for copper.  This
reduction in loading to the treatment plant would reduce the
metal content in the sludges.  A greater degree of reduction
would occur in the sludges metal content since the plant's metal
removal efficiency would be less due to the decrease in the in-
fluent concentrations.  Shown in Table 23, is a comparison of
the estimated sludge concentrations with and without industrial
pretreatment.
                              89

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         Table 23.  PRETREATMENT EFFECTS ON BSA'S SLUDGE

                      Without Pretreatment      With Pretreatment
Parameter                 mg/kg (dry)              mg/kg (dry)

Copper                        1570                      330
Lead                          1800                      605
Nickel                         315                      115
Zinc                          2275                      364
Chromium                      2540                     1040
Cadmium                        100                       50

     As shown in Table 24, the industrial sludges will have high
metal concentrations and proper disposal methods will have to be
employed.

     Sludge disposal options in the Buffalo metropolitan area,
are limited for this type of sludge.  Research into the methods
for reclaiming and recycling metals are presently being conducted.
However, when compared to the level of pretreatment required, it
is not economically justifiable with the methods available today.
Potentially, there are five disposal options which are widely
used for the ultimate disposal of sludges.  The following is a
brief discussion of each relative to its use in this area for the
disposal of sludges from chemical precipitation processes.

     1.  At the present time, landfill disposal of this type of
sludge is broadly utilized in the Buffalo area.  The relative
cost of this disposal method makes it the most economical option
presently available to industries.  However, increasing restric-
tions on the allowable metal content may force the creation of
specialized landfills to handle metal sludges.

     2.  The use of a scavenger is another option open to the
industries investigated.  In addition to accepting sludges, the
scavenger may also accept the waste as a liquid and then pretreat
it.  While the ultimate sludge disposal method  used by the
scavenger most often falls into one of the other four options,
it was included because the potential for reclaiming and recycl-
ing the metals is present.  For example, one scavenger located
in the Buffalo area is seriously looking into recovering metals
on a large scale.  In fact, he has already recovered copper from
a highly concentrated wastewater.  However, unless the sludges
require additional treatment or specialized storage in the land-
fill, it is more economical to use the conventional landfill
approach.

     3   Ocean dumping is not a serious consideration for dis-
posal of the metal sludges since EPA will not approve it and
even if they did, the transportation costs from Buffalo would be
prohibitive.  Sludges are also prohibited from being dumped off-
shore in Lake Erie.

                              90

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Table 24.  EXAMPLES OF INDUSTRIAL SLUDGE CHARACTERISTICS
SIC Category
Cyclic Crude
(2865)
Solids
Zn
Steel Wire
(3315)
Solids
Cd
Cr
Cu
Pb
Ni
Zn
Fe
Plating
(3471)
Solids
Cd
Cr
Cu
Fe
Zn
Ind. Laundry
(7218)
Solids
Cd
Cu
Fe
Pb
Hg
Zn
Kg/day Removed
Dry


9.8
0.64


2383.5
0.10
6.45
15.03
0.50
0.41
1.00
53.12


1184.9
1.86
15.89
10.99
14.44
7.17


1162.7
0.18
3.31
69.05
11.58
0.01
3.86
Cone @ 5% Solids
mg/1


5%
3405.0


5%
2.2
142.0
331.0
11.0
9.0
22.0
1170.0


5%
82.5
704.0
486.8
639.6
317.8


5%
8.2
149.6
3118.0
522.7
0.6
174.2
Cone @ 20% Solids
mg/1


20%
23,314.7


20%
25.1
973.5
2269.2
75.4
61.7
150.8
8021.0


20%
567.7
4846.0
3350.7
4402.9
2187.6


20%
56.2
1026.1
21,380.3
3584.5
4.2
1194.8
                           91

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     4.  The use of metal sludges for land reclamation in high
ground water areas or near lakes and streams would only cause a
greater problem with water contamination.  While land reclamation
may be used at selected sites, it is not forseen to be a major
method of disposal for this area.

     5.  Sludges, in general, have been used both as fertilizer
and soil conditioner.  However, little benefit is seen from using
the metal sludges for this purpose.  The high metal concentra-
tions, as shown in Table 24, would severely limit its applica-
tion.
                               92

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                            SECTION 9

                    MUNICIPAL SLUDGE DISPOSAL
 INTRODUCTION
     It has been shown in the preceding chapters, that the com-
 bined  treatment of  industrial and domestic wastes has many econ-
 omic advantages.  However, combined treatment imposes the need
 for the careful consideration of the effect the  industrial waste
 has on the entire system.  Many of the effects have already been
 discussed in detail.  This section deals with the effect the
 c£™     i K^   o?rge has on POTW's sludge disposal options.  As
 shown  in Table  23, the effects of industrial waste on sludge
 quality can be  significant.                               *

     In an area such as Western New York, there are only three
major options of ultimate disposal open to the POTW.  Those
being:

     1.  Disposal in a landfill;
     2.  Disposal or recycling for agricultrual purposes; and
     3.  Co-disposal with solid waste or refuse by incinerator.

     It must be kept in mind that in addition to industrial
wastes, there are many other factors that will ultimately effect
a POTW's decision as to which disposal option best suits their
needs, for example:

     1.  Normally, the sludge process selected by the POTW will
not^effect their sludge disposal options since ideally, these
options are taken into account when the method of processing is
selected.   In areas where the POTW is still in the planning stage
this is essential.  However, in today's rapidly changing market,
things such as power and fuel, that were economically advanta-
geous to use four years ago, are not today.  This is the case in
Buffalo, therefore, the BSA must re-evaluate its option, taking
into consideration the additional sludge process factor.

     2.  The geological location of the POTW will affect their
option.

     3.  The location of the other POTWs and large industries
with large volumes of sludges and solid waste to be disposed of


                              93

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 will  affect  their option,

      4.   The availability  of land  disposal  sites  will  affect  their
 option.

      5,   The location  of acceptable  landfill  sites will  affect
 their option,

      6,   Federal,  State and  local  regulations will affect  their
 options,  etc.

      Since all  of the  above  are non^industrial  related factors,
 they  will not be  discussed in this report.

      All  of  the information,  conclusions  and  recommendations
 presented here  have been taken from  data  obtained for a  larger
 study performed by EPA on  sludge disposal problems.  That  report
 will  be published separately  at a  later date.

 BACKGROUND INFORMATION

      The Buffalo  Sewer Authority's upgraded Bird  Island  Treatment
 plant will be the  largest  in  Erie  County.   It will produce 17,900
 kkg of ash per  year which  is  43% of  the total quantity of  sludge
 disposed of  in  the county.

      In addition  to the quantity of  sludge produced, the quality
 of its sludge will also affect Buffalo's  options.  The high
 metal concentrations presently in  Buffalo's sludge (Section 7,
 Table 23) may eliminate any agricultural  options  such as using
 the sludge for  soil conditioner or fertilizer.  However, the
 enforcement  of  the BSA Sewer  Regulations  could  lower these metal
 concentrations  to  levels where the agricultural options  could be
 a viable alternative.

      As shown in  Figure 13, initially the Authority will use
 both  digestion  and incineration in its sludge processing.  It is
 not generally common practice for a  POTW  to provide both diges<-
 tion  and incineration.  However, Buffalo  requires digested sludge
 for operating its  activated sludge process in the Kraus mode and
 incineration to further reduce the sludge volume  for disposal.
 When  the BSA plant was in  the design stage, it was found that
 their  present location for ash disposal would no  longer be availr
 able.  New disposal sites were scarce.  Fuel costs were much
 lower  than they are today  and air pollution regulations were less
 stringent.   In  light of todayrs economy, the BSA  is re-evaluating
 its options and investigating alternatives to its present sludge
 treatment and disposal method.

     Since Buffalo utilizes both the digestion and incineration
processes in its new plant, they have the options of, using either


                              94

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RAW
WASTEWATER
GRIT
TANKS


Ln
MULTI
HEARTH
INCINERATORS
-*

VACUUM
FILTERS
                                                        AIR
                                                     ACTIVATED
                                                      SLUDGE
           t
                                                     SECONDARY
                                                     CLARIFIER
                            CHLORINE
                            CONTACT
                                                                                 TO
                                                                                RIVER
          ASH
                                 B.S.A.
 Figure 12
PROCESS DIAGRAM

-------
 one or both in treating their sludge.  The  decision  on  which
 sludge treatment process to use will be based upon an economic
 evaluation of all the combinations of processes  and  disposal
 methods available to them.  While this is beyond the scope  of
 this project, the potential can be briefly  illustrated  by looking
 at Buffalo's present primary system.  In the fiscal  year ending
 on June 30, 1975, the Sewer Authority's costs for sludge incin-
 eration was $175.59/kkg of dried solids burned.18 Since diges-
 tion and dewatering is also utilized by the Authority,  and  if
 adequate sites were available, a substantial savings could  be
 seen by disposing of the digested, dewatered sludge  in  a landfill
 or land reclaiming area.  The resulting cost to  the  Authority
 would be far less than the $175.59/kkg presently being  paid for
 incineration.  Although a detailed study was not made of long
 term landfill availability, at the present landfill  tipping costs,
 it is estimated that approximately $250,000 per  year would  be
 saved if this option could be used.

      The presence of industrial waste in Buffalo's treatment
 plant may create problems in both the use of digesters  and  in-
 cinerators.  However,  the problems caused by the metal  laden
 sludge in the digestor can be solved through the enforcement of
 sewer use regulations.   On the other hand, the problem  of metal
 laden sludges in the incinerators are air pollution  oriented.
 Mercury poses the most serious metal problem during  incineration
 since substantial quantities will be vaporized during the de-
 struction process.  EPA does not feel that an appreciable quanti-
 ty of other metals will appear in stack gases because of vola-
 tilization. 19  A study20 on the incineration of  sludges contain-
 ing mercury indicated 9.7 percent of the mercury entering a
 mulitple-hearth incinerator, enters  the atmosphere,  59  percent
 was found in the ash and the remainder was removed by the scrub-
 ber water.   Considering the actual influent concentration,  this
 level of performance for existing and planned sewage treatment
 plants in Erie Coundy woul4 meet the  national emsission  standard
 for mercury,  considering the actual  influent concentration.  A-
 nother area of concern is that toxic organic substances, such
 as  PCB (polychlorinated-biphenyl) may enter the  atmosphere,
 New regulations promulgated by the New York State Department of
 Environmental Conservation requires  after-burners on all multiple
 hearth sludge incinerators to insure the complete destruction of
 the PCBs.   While little is known about PCB concentrations in


18Laehy, G.  Annual Report of the Buffalo Sewer Authority.  Buffalo Sewer
 Authority.  1974-1975.  p41.

19Process Design Manual for Sludge Treatment and Disposal.  Environmental
 Protection Agency.  October 1974.  p8-43 - 8-54.

20Air Pollution Aspects of Sludge Incineration.  Environmental  Protection
 Agency. 625/4-75-009.  June 1975.  p9.

                               96

-------
sludges, New York State is particularly concerned about their
destruction due to the tendencies for PCBs to concentrate in the
food chain.  For example, just recently, most of the Hudson River
was closed to all types of fishing since high levels of PCBs
have been detected in stock taken from this source.

AGRICULTURAL DISPOSAL OPTION

     Environmental groups and other sectors of the public in
Erie County have been calling for the use of sewage sludge to
either reclaim land or for use as fertilizers.  At the present
time in Erie County, there are no long term plans or needs for
land reclamation.  The costs of transportation to other areas
outside of Erie County for this purpose, such as reclaiming strip
mines, make it economically unattractive.  As a fertilizer, sew-
age sludges are relatively poor being deficient in the proper 21
balance of nitorgen, phosphorus and potassium. Dr. J.D. Mendies
has rated an average sewage sludge as being 2-1-0.2  (nitrogen,
phosphorus, potassium) fertilizer.  Coupled with the handling
problems the farmers have scheduling it and spreading it  in
large quantities, there  is not much of a market for  it.   Some
other cities in the country have successfully marketed their
sludge as a low grade fertilizer.  However, their  sludge  is
either high in nitrogen, or they fortify it with chemicals before
sale.  There are also other cities which have been unsuccessful
in  selling their sludge  as fertilizer, mainly because of  the
lack of an adequate market.

     Sewage sludge  is particularly useful  as  a  soil  conditioner.
Stabilized sewage contains 45-50 percent organic materials which
improves the soil tilth  and permeability with the  added benefit
of  having  a low  fertilization value.  There are  two  constraints
to  the use of Buffalo's  present  sewage  sludge on crop  lands:
1)  its heavy metals concentration, and  2)  the presence  of patho-
gens.  Heavy metals,  especially  zinc, copper, cadmium  and nickel
are potentially  toxic  to crops and may  be  introduced into the
food chain.  The New York State  Department of Environmental  Con-
servation  requires  proof that hazardous  levels  of  metals  will not
be  present in crops grown for human consumption in sludge condi-
tioned soil.  The second constraint is  the level of  pathogens
and their  potential for  contamination of  surface water, ground
water,  the air,  and crops.  It is recommended that land condi-
tioned with sludge  not be used for human consumable  vegetable
crops,  at  least  during the first year,  unless the  sludge  has
been pasteurized or efficiently  composted.

      In  light  of the  above discussion,  Buffalo's  agricultural


21Mendies, J.D.  Composition  and Properties of  Sewage  Sludge Cropping Up.
  New York State College of Agriculture.  Cornell University.  XVIII:5.
  Sept. 1974. pl-3.

                               97

-------
option would be limited to soil conditioning.   Their Sewer Use
Regulation would have to be strictly enforced  so that the metal
concentrations in the sludges were at the levels compatible with
its use as a soil conditioner.  By enforcement of the sewer regu-
lations, the BSA could reduce the metal concentrations in its
waste as shown in Section 8, Table 23.

     Presently, in Erie County, there is a need for approximately
2800/kkg/yr of dried solids to be used as a soil conditioner.
Even with three out of the four new secondary  treatment plants
in the area utilizing incineration as their sludge reduction pro-
cess, the present demand for soil conditioning does not exceed
the supply if Buffalo exercises this option.  Thus, the BSA
would have to expand the present market, which largely consists
of home owners, to include more usage on farm, parks, and recre-
ational area.

LANDFILL OPTION

     The sanitary landfill is presently being  used for the dis-
posal of both sludge and ash.  Under present landfilling methods,
these sludges are incorporated either into the face of the fill
matter or combined with the cover material.  Since the pH of the
material in a sanitary landfill is normally acidic, this creates
the problem of the resolublization of metals which during wet
weather would leach out into the groundwater or drainage system.
Therefore, it is recommended, since new regulations are present-
ly being established, that these regulations be carefully con-
sidered in the design stages.  For example, as a result of re-
quests made by county health authorities, one  of the larger land-
fills in the area recently sent to its customers a notice indi-
cating substances which will not be accepted for disposal;
included were the metals found in Buffalo's sludges.  Since the
request was not specific by including limiting concentrations,
this implies that Buffalo's municipal sludge would be prohibited.
Since all waste even domestic, will contain some metals, the
lack of specific limits in the regulations prevents us from
determining what, if any, effect the industrial control of metals
has on thl's option. The costs for the use of landfills ranged
from $6.00 to $11.00/kkg, plus the cost of transportation.
However  many landfills have not yet established fixed charges
for sludges.  In most cases they would rather not handle it be-
cause of the equipment problems it produces.

     In evaluating the landfill option, the POTW must consider
both the transportation costs and the costs charged by the land-
fill   For long term projects, incineration of the sludge before
disposal in the landfill may prove to be cost-effective since  it
would drastically reduce both costs by reducing the volume.  For
example, assuming a POTW has to process and dispose of 1,500,000
kkg/year of wet sludge containing 50% volatiles of 2% solids,
                              98

-------
 one  of  two methods  could be  used:   1}  digestion followed by
 dewatering to  20S by  weight, and 2)  dewatering, followed by in-
 cineration.  If  the digestion process  were to be used, approxi-
 mately  102,000 kkg/yr of wet sludge  would be generated.  If in-
 cineration were  to  be used,  only 15,000 kkg/yr of ash would have
 to be disposed of.  If the reduction in transportation and land-
 fill costs resulting  from the use  of incineration exceeds the
 difference in  0$M and amortization costs between incineration and
 digestion, then incineration  would  be the cost effective method.

 CO- DISPOSAL OF REFUSE AND SEWAGE SLUDGE

     Co-disposal of refuse and sewage  sludge is being evaluated
 by Erie County's Southtowns  Sewage Agency for use at its new
 sewage  treatment plant. LL The concept is to locate pyrolysis
 oxygen  furnaces, oxygen generation facilities and wastewater
 facilities at  a  common location.   Each process would augment the
 other,  the pyrolysis  units disposing of the sewage sludge, the
 wastewater treatment  plant supplying cooling and flushing water
 as well as treating the contaminated wastewater, and the oxygen
 facilities supplying  oxygen  to both  facilities.  The new savings
 in the  cost of constructing  the wastewater treatment facility
 would be  approximately 3.6 million dollars.

     The  solid waste  facilities would  include shredding, ferrous
 metal separation and  pyrolysis units.   The manufacturer, Union
 Carbide,  estimated  that  the  quantity of sludge that could be
 handled jointly with  the  refuse is 20-30 percent of the total
 capacity  of the  incinerator.   The  sludge dewatered to 25 percent
 would result in negligible losses  of energy.   Sludge with higher
 solids content could  produce enough  energy to make it a market-
 able commodity. New York  State has expressed an interest in a
 facility  of this nature  and  grant  funds are available to pay up
 to 50 percent  of the  construction  costs.   In addition, EPA and
 NYDEC will provide  751  and 12.5 %  of the funds necessary for that
 portion of the facility  for  wastewater treatment.   The annual
 conceptual cost estimates for the  solid waste facility are shown
 in Table  25.

     Generally, the use of landfills which are relatively close
 to the refuse  source  was  found to  be more economical than co-
 disposal.   However, as  the distance  to the landfill increases,
 the increase in transportation costs make the pyrolysis method
more attractive.   The Lancaster Sanitary Landfill  would be avail-
 able for  refuse for some  time.   Tipping costs are  presently $5.70
        Smith, Rosenstein Engineers.  Technical Memorandum on Solid Waste
 Disposal Facilities Being Combined With Wastewater Treatment Facilities at
 the Southtowns Site.  Erie County's Southtowns Sewage Agency. February
 j.y /o •  p / •


                               99

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Table22 25 . ANNUAL COSTS FOR SOLID WASTE DISPOSAL FACILITY
                     Net Annual Costs
Operating and Maintenance
Debt Service
Wastewater Debt Credit
                  Total
Annual Tonnage
Cost per Ton
   1980
$3,712,000
 1,600,000
   (43.000)
$5,269,000
   197,830
$    26.63
   2000
$5,294,000
 1,600,000
   (45,000)
$6,851,000
   385,000
$    18.76
                 Credit for Sale of Metals
Gross Cost per Ton
Credit for Metal
Net Cost per Ton
Credit for Sale
Gross Cost per Ton
Credit for Metal
Credit for Gas
Net Cost per Ton
Credit for Sale
Gross Cost per Ton
Credit for Metal
Credit for Gas
Net Cost per Ton
1980
$26.63
(2.50)
$24.13
of Metals and Gas @ $0.
1980
$26.63
(2.50)
(5.63)
$18.50
of Metals and Gas @ $1.
1980
$26.63
(2.50)
(11.25)
$16.25
2000
$18.77
(2.50)
$16.26
75/106 BTU
2000
$18.77
(2.50)
(5.63)
$10.63
50/106 BTU
2000
$18.76
(2.50)
(11.25)
$ 5.01
                           100

-------
per ton of refuse with sludge tipping charges being four times
that amount, depending on the handling problems encountered.   To
be cost effective, compared to the use of the Lancaster Landfill,
the solid waste co-disposal facility would have to operate at
near capacity and sell all its off-gases at $1.50/10° BTU.  The
industrial contribution to Buffalo's waste treatment system
would not be a hindrance to the utilization of this option.  In
fact, if co-disposal were to become a reality, the POTW would
neither have to digest or incinerate, merely dewater.
                              101

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                            SECTION  10

                            REFERENCES


  1.   Leonard  S. Wegman Co.,  Inc.  Comprehensive Sewer Study for
      the  Buffalo  Sewer Authority.   Buffalo, New York.  1973.
      p.IV 1 -  IV  22.

  2.   Executive Office of the President.  Standard Industrial
      Classification Manual.  Washington, B.C.  1972 edition.
      649p.

  3.   Toxic Materials Analysis of Street Surface Contaminants.
      EPA-82-73-233.

  4.   Sarton, J.,  Boyd, G.,  and Agardy, F.  Water Pollution Aspects
      of Street Contaminants.  Journal WPCF.  Vol. 46.  No. 3
      March 1974.  p458-467.

  5.   Newton, C.D., Shephard, W.W.,  Coleman, M.S.  Street Runoff
      as a Source  of Lead Pollution.  Journal WPCF.  Vol.  46.
      No.  5.  May  1974.  p999-1000.

  6.   Agee, James  L.  User Charge Systems.  Program Guidance
      Memorandum.  EPA.  p38.  July  16, 1974.  Ip.

  7.   Financing and Charges  for Wastewater Systems.  American
      Public Works Assc., American Society of Civil Engineers.
      Water Pollution Control Federation.   1973. p37-40.

  8.   Equitable Recovery of  Industrial Waste Treatment Costs in
     Municipal Systems.  EPA.  October 1971.  p5.

  9.   Stoats, E.B.  Decision - Use of Ad Valorem Tax to Satisfy
     Statutory Requirement  for a User Charge System for Water
     Treatment Works.   Comptroller General of the United States.
     B-166505.  July 2, 1974.  p2.

10.  Common and Precious Metals Segment of the Electroplating
     Point Source Category.  EPA-440/1-75/040.  April 1975.
     p!53-179.

11.  Metal Finishing Segment of the Electroplating Point  Source
     Category. EPA-400/l-75-040-a.  April  1975. Table 24.  plOO.


                               102

-------
12.   A Guide to the Selection of Cost Effective Wastewater Treat-
     ment Systems.   EPA 430/9-76-002.  July 1975.   pB-1.

13.   An Analysis of Construction Cost Experience for Wastewater
     Treatment Plants.   EPA 430/9-76-002.   February 1976.   p44.

14.   Pretreatment Standards, Part 128.  Federal Register.   Vol.
     38.  No. 215.   EPA. November 8,  1973.   p30984.

15.   Cheng, M.H. , Patterson, J.W.,  and Minear,  R.A. Heavy Metals
     Uptake by Activated Sludge.  WPCF Journal.  Vol. 47.  No.  2
     Feb. 1975.  p362-276.

16.   Brunner, C.A.   EPA Correspondence to John T.  Rhett.   Removal
     Capability of Wastewater Treatment Processes for Metals and
     Other Pollutants.   8/20/74.

17.   Esmond, S.E., Petrosek, A.  Dallas Water Utilities Dept.
     Removal of Heavy Metals by Wastewater Treatment Plants.
     March 1973.  pl-16.

18.   Laehy, G.  Annual Report of the Buffalo Sewer Authority.
     Buffalo Sewer Authority.  1974-1975.  p41.

19.   Process Design Manual for Sludge Treatment and Disposal.
     Environmental Protection Agency.  October 1974.  p8-43 -
     8-54.

20.   Air Pollution Aspects of Sludge  Incineration.  Environmental
     Protection Agency.  625/4-75-009.  June 1975.  p9.

21.  Mendies, J.D.  Composition and  Properties of  Sewage  Sludge
     Cropping Up.  New York  State College  of Agriculture.
     Cornell University.  XVIII:5.   Sept.  1974.  pl-3.

22.  McPhee, Smith, Rosenstein Engineers.  Technical Memorandum
     on Solid Waste Disposal  Facilities Being  Combined With
     Wastewater Treatment Facilities at the Southtowns Site.
     Erie  County's  Southtowns  Sewage Agency.   February 1976.   p7.
                               103

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                             SECTION 11

                            BIBLIOGRAPHY


  1.  Earth, E.F., Ettinger, M.G., Salotto, B.V., and McDermott,
      G.N.  "Summary Report on the Effects of Heavy Metals on the
      Biological Treatment Processes".   Journal WPCF.  37-1:  86-96
      January 1965.

  2.  Board of Supervisors of Weschester County, County Public
      Works Sewer Ordinance No.  1, 27-1968.  16p.

  3.  Buffalo Sewer  Authority,  Sewer Regulations of the Buffalo
      Sewer Authority.   1967.   12p.

  4.  Carnes,  B.A.   "Laboratory  Simulation and Characterization
      for Water  Pollution  Control".   Chemical  Engineering.  97-104
      December 11, 1972.

  5.  Cheng,  M.H., Patterson, J.W.,  and  Minear,  R.A.   "Heavy  Metals
      Uptake  by  Activated  Sludge".   Journal WPCF.   47-2:  362-376
      February 1975.

  6.  City of  Cincinnati,  Ordinances, Rules and  Regulations of  the
      Metropolitan Sewage  Disposal System.  1962.  23p.

  7.   County of  Onondaga,  N.Y.   Rules and  Regulations  Relating  to
      the  Use  of  the Public  Sewer  System.   Nov.  15,  1972.  19p.

  8.   Erie  County Dept. of Public Works, Rules and Regulations  for
      Erie  County Sewer Districts.   December 21,  1971.  28p.

  9.   Esmond,  S.E. and Petrasek Jr., A.C.   "Removal of Heavy Metals
      by Wastewater Treatment Plants". Texas A§M University (pre-
      sented at Industrial Water and Pollution Conference and Ex-
     position. Chicago, Illinois. March 14-16, 1973).  16p.

10.   Impact of Environmental Regulations on Capital Markets and
     on Industry Capital  - Raising Problems.  EPA.  PM-219.
     December 1975.   14p.

11.  Interaction of  Heavy Metals and Biological Sewage Treatment
     Processes.   U.S.  Dept.  of Health,  Education, and Welfare.
     May 1965.  199p.


                               104

-------
12.   Irvine,  R.L.,  Keegan,  R.T.,  Langley,  W.D.  and Catchings,
     R.C.   "Specific Removal Patterns  in Activated Sludge System
     Design".  Journal WPCF.   4_5  - 8:  1771-1782.  August 1973.

13.   Klein, L.A.,  Lang,  M.,  Nash, N.,  and Kirschner,  S.L.
     "Sources of Metals  in  New York  City Wastewater".  (Presented
     at New York Pollution  Control Association.  Jan.  21,  1974).
     18p.

14.   Kroner,  R.C.   "The  Occurrence of Trace Metals in Surface
     Waters".  EPA - 902/9-74-001.  311-322p.

15.   Mandel,  J.  "The Statistical Analysis of Experimental Data".
     Interscience Publishers.  1964.   410p.

16.   Maryuama, T., Hannah,  S.A., and Cohen, J.M.  "Removal of
     Metals by Physical  and Chemical Treatment Processes". EPA.
     February 1974.  35p.

17.   McPhee, Smith, Rosenstein Engineers. "Industrial Waste Sur-
     vey Phase II Engineering Report".  Buffalo Sewer Authority.
     December 1975.  Vol. I § II.  87p.

18.   McPhee, W.T., Rosenstein, I.  "Municipal Disposal Contracts
     for Industrial Users".  (Presented at New York Pollution Con-
     trol Associations's Annual Meeting. Jan. 1973.). 14p.

19.   Metropolitan Sanitary District of Greater Chicago.  Sewage
     and Waste Control Ordinance.  Sept. 18, 1969.  12p.

20.   Metropolitan Sanitary District of Greater Chicago.  Industrial
     Waste Surcharge Ordinance.  Dec.  31, 1970.  9p.

21.  Model Industrial Waste  Ordinance.  Environmental Improvement
     Agency.   Santa  Fe, New  Mexico. 1971.  9p.

22.  Nebolsine, Toth, McPhee  Associates.   Industrial  Waste Survey
     Engineering Report.  Buffalo Sewer Authority.  Jan.  1973.
     50p.

23.  Nevfeld,  R.D.  and  Hermann,  E.R.   "Heavy Metal Removal by
     Acclimated Activated Sludge". Journal  WPCF.   47-2 :310-329.
     Feb.  1975.

24.  Patterson, J.W., Shimada,  P.,  and Haas,  C.N.  "Heavy Metals
     Transport Through  Municipal Sewage  Treatment Plants".
      (Presented at  the  Second National Conference on  Complete
     Water Reuse.   Chicago,  Illinois.  May 5,  1975.).  15p.

25.  Peterson, F.L.  and Hargis,  D.R.  "Subsurface  Disposal  of  Storm
     Runoff".  Journal WPCF.   45-8:  1663-1670.  Aug.  1973.
                                105

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26.  Regulation of Sewer Use.  WPCF Manual of Practice No. 3
     Journal WPCF.  45-9,10.  1973.

27.  Rubin, A.J.  (Ed.) "Aqueous-Environmental Chemistry of Metals"
     Ann Arbor Science.  1974.  381p.

28.  St. Paul Metropolitan Sewer Board, Sewage and Waste Control.
     Rules and Regulations for the Metropolitan Disposal System
     Dec. 1, 1971. 13p.

29.  Sanitation Districts of Los Angeles County.  An Ordinance
     Regulating Sewer Construction, Sewer Use and Industrial
     Wastewater Discharges.  April 1, 1972.  48p.

30.  Texas Water Quality Board.   Suggested Industrial Waste Ordi-
     nance.   72-04.   31p.

31.  Treatment of Mixed Domestic Sewage and Industrial Wastewaters
     in Germany.  Organization for Economic Co-operation and De-
     velopment.   No.  20215.  Dec.  1966.   113p.
                              106

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                           SECTION  12
                           APPENDICES
A   Characteristics of SIC Categories
B   Sewer Use Regulations
C   Pilot Plant Investigation's Background Data
                                107

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           APPENDIX A



CHARACTERISTICS OF SIC CATEGORIES
              108

-------
Table A'l  CHARACTERISTICS OF S.I.C.  CATAGORIES

Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Meat Packing (2011J 	
Kg /day
339
706
16.2
595
128.6
23.8
D.78










0.1115
7
60.6

nd. Total
1.4
1.2
0.6
0.3
0.7
0.4
0.1










0.6
3.1


mg/1
802
1671
38.4
1410
305
56.4
1.83










0.1115
7


Prepare
S.I.C.
Kg /day
2495.9
4198.3
54.18
8,841
830.1
88.9
541.1










0.9145
13
89.8

d Meats (20
Ind. Total
10.4
7.3
2.0
4.6
4.7
1.6
38.5










4.7
5.8


~3) T
mg/1
721
1213
15.6
2553
240
25.7
156










0.9145
13


Creamery Butter (2(
SIC % of
Kg /day
44.53
80.81
0.52
60.39
15.95
18.82
0.15










0.0363
1
100

Ind. Total
0.2
0.1
<0.1
<0.1
0.1
0.3
<0.1










0.2
0.4


)21)
Cone.
mg/1
324
588
3.8
439
116
137
1.1










0.0363
1


Cl
S.I.C.
Kg./day
736.5
1552.2
2.6
1039.8
34.24
13.54
6.24










0.0335
2
88.0
leese (2022
% of
Ind. Total
3.1
2.7
0.1
0.5
0.2
0.2
0.4










0.2
0.89

Cone.
mg/l
5803
12,338
20
8193
270
107
49










0.0335
2



-------
Table A'l  Continued  CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Ind.
Weight %
S.I.C. Sampled
Ice Cream (2024)
S.I.C.
Kg /day
104.7
235.5
8.25
417.3
68.5
394.0
21.0










0.225
1
100
% of
Ind. Total
0.4
0.4
0.3
0.2
0.4
7.0
1.5










1.1
0.44

Cone.
mg/1
122
277
9.7
490
80
463
25










0.225
1

Fluid Milk (2026)
S.I.C.
Kg/day
6,990
9,251
34.35
8,054
1,261
123
290










0.5147
3
91.8
% of
Ind. Total
29,2
16.2
1.2
4.2
7.1
2,2
20.7










2.6
1.33

Cone.
mg/1
3579
4747
18
4133
647
63
149










0.5147
3

Pickles (2035)
S.I.C.
Kg /day
1843.7
2297.0
24.43
6,390
38.1
5.93
4.76










0.1030
1
100
% of
Ind. Total
7.7
4.0
0.9
3.3
0.2
0.1
0.3










0.5
0.44

Cone.
mg/1
4725
5887
63
16,377
98
15
12










0.1030
1

Flour (2041)
S.I.C.
Kg/day
3.21
9.6
0.365
55.1
5.06

0.25










0.0619
2
66.4
% of
Ind. Total
<0.1
<0.1
<0. 1
<0 . 1
<0.1

<0.1










0.30
0.89

Cone.
mg/1
13.67
41.1
1.6
235
22

1.1










0.0619
2


-------
Table A'l  Continued  CHARACTERISTICS OF S.I.C. CATAGORIES

Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled

Pel
S.I.C.
Kg/day
40.5
101.6
0.75
138.6
20.3
2.31
2.26










0.0549
2
45.7
fooa izu*/
%of
Ind. Total
0.2
0.2
<0.1
0.1
0.1
<0.1
0.2










0.3
0.89
_
;
Cone.
mg/1
195
489
3.6
666
98
11
11










0.0549
2
—

S.I.C.
Kg/day
750
1040
8.2
993
415
81.9
11.51










0.2013
15
50.7
%of 1
Ind. Total
3.1
1.8
0.3
0.5
2.3
1.4
0.8










1.0
6.67

Cone.
mg/1
984
1364
11
1303
546
108
15










0.2013
15

Animal F»t & on 12077)
S.I.C. I
Kg/day
110.1
630
6.5
594
444
5.2
0.56










0.0455
1
100
% of
Ind. Total
0.5
1.1
0.2
0.3
2.5
0.1
0.1










0.2
0.44

Cone.
mg/1
645
3674
37.8
3470
2587
32.7
3.5










0.0455
1


S.I.C.
Kg/day
1399.1
1927
4.7
1378.4
331.5
103.8
8.05










0.4070
1
100
% of
Ind. Total
5.8
3.4
0.2
0.7
1.9
1.8
0.6










2.1
0.44

Cone.
mg/1
1068
1471
3.6
1052
253
79
6.1










0.4070
1


-------
Table A-I  Continued CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled

S.I.C.
Kg/day
107.45
196.9
6.30
170.4
39.01
0.64
7.03










0.0704
1
100

Walt (2083)
% of
Ind. Total
0.4
0.3
0.2
0.1
0.2
<0.1
0.5










0.4
0.44


Cone.
rog/1
403
739
23
639
146
2.4
26










0.0704
1


Soft Drinks (2086)
S.I.C.
Kg /day
9.42
21.9
0.51
125.1
10.19
1.37
0.229










' O.OS61
8
75.3

%of
Ind. Total
<0.1
<0.1
<0.1
0.1
0.1
<0.1
<0.1










0.3
3.6


Cone.
mg/1
44
103
2.4
589
48
6.0
1.1










0.0561
8


Macaroni & Spaghetti (2098)
S.I.C.
Kg/day
71.2
115.7
0.92
178.9
12.5
1.8
5.3










0.0451
1
94.7

% of
Ind. Total
0.3
0.2
<0.1
0.1
0.1
<0.1
0.4










0.2
0.4


Cone.
mg/1
417
677
5.4
1048
73
10.9
31










0.0451
1


Narrow Fabric Mills (2241 )
S.I.C.
Kg/day
16.06
144.3
1.61
146.3
44.73
12.19
1.02










0.4478
2
70.5

%of
Ind. Total
0.1
0.3
0.1
0.1
0.3
0.2
0.1










2.3
0.89


Cone.
mg/1
9.47
85.1
0.95
86.3
26.4
7.19
0.60










0.4478
2



-------
Table A-1  Continued CHARACTERISTICS OF S.I.C. CATEGORIES

Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex

C hrom ium- tota 1
Copper
Lead
Mercury
Nickel

Zinc
Discharge-MGD
No. of Industrie

Weight %
S.I.C. Sampled
Converted Paper Products (2649)
S.I.C.
Kg/day
41.16
726.7

1364.2
1184.5
6.1
0.67






0.138

<0. 00028



0.0570
1

100

% of
Ind. Total
0.2
1.3

0.7
6.7
0.1
<0.1






0.1





0.3
0.44



uonc.
mg/1
191
3369

6318
5485
28
3.1






0.64





0.0570
1



Corrugated Boxes (2653)
. l.C .
Kg /day
93.4
522.2
3.49
439.6
334.9
91.0
1.04


0.0094





0.00023



0.1039
3

65.7

7o 01
Ind. Total
0.4
0.9
0.1
0.2
1.9
1.6
0.1


0.2





0.2



0.5
1.33



mg/1
237
1327
8.9
1117
851
231
2.6


0.024





0.0006



0.1039
3



New
S.I.C.
Kg /day
25.1
103.7
1.21
141.1
39.5

2.53










0.2

0.1160
5
66.7


spa per s (27
% of
Ind. Total
0.1
0.2
<0.1
0.1
0.2

0.2










0.6

0.6
2.22


LI)
Cone.
mg/1
57.3
236
2.8
321
90

5.8










0.62

0.1160
5


S.I.C.
Kg/day
0.39
15.2
0.26
112.7
17.51
1.66
0.74




0.0272



0.00005



0.0378
6
38.4

% of
Ind. Total
<0.1
<0.1
0.1
0.1
<0.1
0.1




<0.1



<,0.1

0.1

0.2
2.67


Cone.
mg/1
2.7
107
1.8
788
122
12
5.2




0.19



0.0004

0.28

0.0378
6




-------
Table A-1  Continued CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide

Cadmium
Chromium-hex
Chromium-total

Copper
Lead
Mercury
Nickel

Zinc

Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Manifold E
S.I.C.
Kg /day
38.15
108.1
15.07
280-0
29.0
23.24
10.60

0.032






0.0374
0.0031




0.1715
1
100
uslness For
% of
Ind. Tota:
0.2
0.2
0.5
0.1
0.2
0.4
0.8

0.1






0.2
2.1




0.9
0.44

ms (2761)
mg/1
59
167
23.0
432
45
36
16

0.05






0.06
0.005




0.1715
1

Pharmaceutical (2834)
Kg/day
1118.6
3306.7
4.65
1564
196.3
91.7
1.851
0.0172






0.0292


-------
Table A'l Continued CHARACTERISTICS OF S.I.C. CATEGORIES

Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel

Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled

KgYday
3.31
19.3
0.67
122.4
6.37
22.12
0.33











0.0923
3
9.8

ubber Produ
% of
Ind. Total
<0.1
<0.1
<0.1
0.1
<0.1
0.4.
<0.1











0.5
1.33


cts (3069)
Cone.
mg/1
9.5
55
1.9
350
18
63
0.94











0.0923
3


Purchased. Glass Produ
S.I.C.
Kg /day
4.64
34.49
0.9
223.1
71.4
3.87
"6.54



-------
Table A-I  Continued  CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex

C hromium-tota 1

Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Ste
S.I.C.
Kg /day
475.9
928.9
1605.3
36,467
201.1
8.05
20.41

2.4
0.16
199.2

277.5

58.1
4.3

3.7
7.6
0.1776
1
100
el Wire (33
% of
Ind. Total
2.0
1.6
58.2
18.9
1.1
0.1
1.5

9.4
4.1
76.9

70

33
17.2

5.9
2.7
0.9
0.44

15)
Cone .
mg/1
707
1381
2387
54,243
299
12
30

3.6
0.24
296

412

86
6.4

5.5
11
0.1776
1

Cold FinJ
sir
Kg/day
12.19
44.09
1.14
228.3
14.05
3.9
2.35










0.0163

0.2230
1
100
shing of Ste
Ind. Total
0.1
0.1
<0.1
0.1
0.1
0.1
0.2










<0.1

1.1
0.44

el (3316)
mg/1
14
52
1.3
271
17
4.7
2.8










0.02

0.2230
1

Gray Iron Foundaries (3321)
Kg/day
14.29
107.5
3.79
213.3
125.9
4.9
1.37








0.0451

0.0233
0.054
0.1211
3
81.8
7b OI
Ind. Total
0.1
0.2
0.1
0.1
0.7
0.1
0.1








0.2

<0.1
<0.1
0.6
1.33

cone.
mg/1
31
234
8.3
465
275
11
3.0








0.10

0.05
0.12
0.1211
3

Malleable Iron Foundaries (3322)
S.I.C.
Kg /day
14.03
37.76
1.26
319.9
63.6
0.78
3.7




0.015

0.083



0.108
33.43
0.0558
1
100
% of
Ind. Total
0.1
0.1
<0.1
0.2
0.4
<0.1
0.3




<.0.1

<0.1



0.2
11.9

0.44

Cone.
mg/1
66
179
6.0
1514
301
3.7
17.6




0.07

0.40



0.52
158
0.0558
1


-------
Table A'l  Continued  CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
C hromium - hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Steel Foundarles (3325)
S.I.C.
Kg /day
67.62
1190.0
17.14
5,140
4,653
45.9
17.96






0.45

1.770
0.54
0.5518
4
66.7
% of
Ind. Total
0.3
2.1
0.6
2.7
26.2
0.8
1.3






1.8

2.8
0.2
2.8
1.78

Cone.
mg/1
24
582
8.5
2571
2360
23
8.9






0.23

0.90
0.25
0.5518
4

Copper Rolling (3351)
S.I.C.
Kg /day
176.5
1370.3
20.64
4,512
457.1
91.83
8.25


0.206


12.38


0.309
79
2.2728
2
100
% of
Ind. Total
0.7
2.4
0.7
2.3
2.6
1.6
0.6


5.2


7.1


0.5
28.3
0.89
0.89

Cone.
mg/1
21
159
2.4
524
53
11
0.96


0.02


1.4


0.04
9.23
2.2728
2

Hand & Edge Tools (3423)
S.I.C.
Kg/day
49
269.7

1266.8
178.1
84.1
19.55


0.0089
5.19
5.44



3.95
1.24
0.5450
3
97.0
% of
Ind. Total
0.2
0.5

0.7
1.0
1.5
1.4


0.2
2.0
1.4



6.2
0.4
2.8
1.33

Cone.
mg/1
24
131

614
86
41
9.5


0.004
2.5
2.6



1.9
0.6
0.5450
3

Fabricated Plate Work (3443)
S.I.C.
Kg /day
94.6
365.6
7.31
2849.5
640.8
34.41
13.54









1.29
0.4737
7
92.2
% of
Ind. Total
0.4
0.6
0.3
1.5
3.6
0.6
1.0









0.5
2.4
3.11

Cone.
mg/1
53
204
4.1
1589
357
19
7.6









0.72
0.4737
7


-------
                                               Table A- 1 continued. CHARACTERISTICS OF SIC CATEGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
C hrom ium - tota 1
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Metal Stampings (3469)
S.I.C.
Kg/day
85.4
476.8
4.42
670.0
65.2
26.99
13,91
0.0058
0.0280

0.126
0.216
0.108
0.0034

0.117
0.126
0.1989
7
91.9

% of
Ind. Total
0.4
0.8
0.2
0.3
0.4
O.S
1.0
75.9
0.1

<0.1
<0.1
0.1
<0.1

0.2
<0.1
1.0
3.11


Cone.
mg/1
113
633
5.9
890
87
36
18
0.0078
0.037

0.17
0.29
0.14
0.0046

0.16
0.17
0.1989
7


Plating & Polishing (3471)
S.I.C.
Kg/day
15.7
125.4
3.09
1277
132.0
11.48
11.74

5.41
2.32
18.04
18.22
11.99
0.039
0.00366
24.92
8. 51
0.6309
13
70.2

% of
Ind. Total
0.1
0.2
0.1
2.2
0.7
0.2
0.8

20.7
57.9
7.0
4.6
6.9
0.2
2.5
39.2
3.0
3.2
5.78


Cone.
mg/1
6.6
52.5
1.3
535
55
4.8
4.9

2.3
0.97
7.6
7.6
5.0
0.017
0.0015
10.4
3.6
0.6309
13


Steel Springs (3493)
S.I.C.
Kg/day
4.39
25.02
2.17
123.8
4.07
2.76
2.48

0.63
0.40
<0.016
0.011
0.033
0.026
0.0003


0.1389
1
100

% of
Ind. Total
<0.1
<0.1
0.1
0.1
<0.1
<0.1
0.2

2.4
10.1

<0.1
<0.1
0.1
0.2


0.7
0.44


Cone.
mg/1
8.4
48
4.2
235
7.8
5.3
4.7

1.2
0.8

0.02
0.063
0.05
0.0006


0.1389
1


Machine Tools (3541)
S.I.C.
Kg/day
1.53
5.38
0.11
32.57
2.8
7.73
0.303


0.0038



0.047



0.0304
4
95.8

% of
Ind. Total
<0.1
<0.1
<0.1
<,0.1
<0.1
0.1
<0.1


0.1



0.2



0.2
1.78


Cone.
mg/1
13.3
47
1.0
283
24
67
2.6


0.03



0.41



0.0304
4


CO

-------
Table  A"l  Continued CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil \
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium -total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Blowers & Fans (3564)
S.I.C.
Kg/day
4.84
26.5
0.88
116.8
31.6
0.79
1..53
0.0018





0.046



0.1026
1
100
% of
Ind. Total
<0.1
<0.1
<0.1
0.1
0.2
<0.1
0.1
24.1





0.2



0.5
0.44

Cone.
mg/1
12.5
68
2.3
301
82
2.0
4.0
0.0048





0.12



0.1026
1

Refrig. & Heat. Equip. (3585)
S.I.C.
Kg/day
25.1
134.6
4.95
1117.8
88.8
6.54
28.12









113.2
0.3896
3
95.9
% of
Ind. Total
0.1
0.2
0.2
0.6
0.5
0.2
2.0









40.3
2.0
1.33

Cone.
mg/1
17
91
3.36
758
60
4.4
19









76.7
0.3896
3

Motor Vehicle Parts (3714)
S.I.C.
Kg/day
309.7
170.0.6
71.8
6,783
1,401
2896
89.5

14.13
0.1187
36.51
95.5
69.5
0.847

25.78
10.13
2.5941
6
75.4
% of
Ind. Total
1.3
3.0
2.6
3.5
7.9
51.2
6.4

54.0
3.0
14.1
24
39.9
3.4

40.5

13.2
2.67

Cone.
mg/1
31.5
173
7.3
691
143
295
9.1

1.4
0.01
3.7
9.7
7.1
0.086

2.6
1.03
2.5941
6

Manufacturing Industries (3999)
S.I.C.
Kg /day
249.5
521.6
5.06
1353.8
309.1
27.58
7.96










0.1702
3
97.7
% of
Ind. Total
1.04
0.9
0.2
0.7
1.7
0.5
0.6










0.9
1.33

Cone.
mg/1
387
809
7.9
2101
480
43
12










0.1702
3


-------
Table A-1  Continued  CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B .O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
l_t Cyanide
^ Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Gas Production (4925)
S.I.C. 1 ' "
/day
101.08
683.3
22.44
1623.3
199.42
11.2
5.0
<0. OO'SO
0.64








0.2364
3
100
% oi
Ind. Total
0.5
1.2
0.8
0.8
1.1
0.2
0.4

2.5








1.2
1.33

Cone.
mg/1
122
763
25
1814
223
12.5
5.6

0.72








0.2364
3

Poultry Products (5144) '
S.I.C.
/day
18.12
46.37
0.87
50.57
16.97
1.16
1.43










0.0258
1
100
% of
Ind. Total
0.1
0.1
<0.1
<0.1
0.1
<0.1
0.1










0.1
0.44

Cone.
mg/1
186
475
8.9
518
173
12
15










0.0258
1

Industrial Supplies (5085)
S.I.C. 1
/day
245.9
1156
3.06
925
228
260.5
7.18


0.040

0.040
0.087
3.01
0.024
0.0082
2.51
0.0369
5
25.5
% of
Ind. Total
1.0
2.0
0.1
0.5
1.3
4.6
0.5


1.0

<0.1
0.1
12.2
16.0
s.0.1
0.9
0.2
2.22

Cone.
mg/1
1760
8277
22
6623
1635
1864
51.4


0.29

0.29
0.62
21.6
0.17
0.059
18
0.0369
5

Eatina Places (581?
S.I.C.
Kg/day
185.4
396.2
1.65
352.7
158.3
81.7
2.24










0.0865
16
38.6

Ind. Total
0.8
0.7
0.1
0.2
0.9
1.4
0.2










0.4
7.11

Co
mg/1
566
1210
5
1077
483
249
6.8










0.0865
16


-------
                                          Table A'l Continued  CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease & Oil
Phosphate
Arsenic
Cyanide
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Power Laundries (7211)
S.I.C.
Kg /day
79.6
173.4
1.18
255.6
38.6
3.48
5.51










0.0843
4
76.9
% of
Ind. Total
0.3
0.3
<0.1
0.1
0.2
0.1
0.4










0.4
1.78

Cone.
mg/1
249
543
3.7
801
121
10.9
17










0.0843
4

Linen Supply (7213)
S.I.C.
Kg /day
194.6
354.2
2.3
615.4
58.1
36.28
12.7










0.0999
3
84.5
% of
Ind. Total
0.8
0.6
0.1
0.3
0.3
0.6
0.9










0.5
1.33

Cone.
mg/1
514
936
6.0
1627
153
96
34










0.0999
3

Dry Cleaning Plants (7216)
S.I.C.
Kg/day
5.09
19.2
0.46
104.1
11.6
3.65
1.58










0.0724
15
49.4
% of
Ind. Total
<0.1
<0.1
<0.1
0.1
0.1
0.1
0.1










0.4
6.67

Cone.
mg/1
19
69
1.7
373
42
13
5.8










0.0724
15

Industrial Launderers (7218)
S.I.C.
Kg /day
1419
6,411
13.33
5,849
1,253.8
568.3
117.3


0.58*

0.90*
4.13*
11 . 7*
0.0316*

5.1*
0.7779
6
94.9
% of
Ind. Total
5.9
11.2
0.5
3.0
7.1
10.0
8.4


14.6

0.2
2.4
47.2
21.4

1.8
4.0
2.67

Cone.
mg/1
482
2176
4.6
1986
426
193
40


0.29*

0.44*
2.04*
5.8*
0.016*

2.5*
0.7779
6

* Note:  Heavy metal loadings include only three industries having a total flow of 535,494 gpd.

-------
Table A'l  Continued CHARACTERISTICS OF S.I.C. CATAGORIES
Parameters
B.O.D.
C.O.D.
Chlorine Demand
Total Solids
Total S.S.
Grease &Oil
Phosphate
Arsenic
I-* Cyanide
ts)
Cadmium
Chromium-hex
Chromium-total
Copper
Lead
Mercury
Nickel
Zinc
Discharge-MGD
No. of Industries
Weight %
S.I.C. Sampled
Photofinish
S.I.C.
Kg/day
35.90
77.2
7.1
105.5.
4.0

0.034

0.00085



0.0083



0.011
0.0452
1
100
ing Lafoorato
Ind. Total
0.2
0.1
0.3
0.1
<0. 1

<0.1

<0.1



<0.1



<0.1
0.2
0.44

ries (7395
mg/1
210
452
36
617
24

0.2

0.005



0.048



0.066
0.0452
1

Car Washes (7542)
Kg/day
3.56
21.4
0.74
47.3
13.17
1.26
0.092










0.0248
3
42.6
7a UI
Ind. Total
<0.1
<0. 1
<0.1
<0.1
0.1
<0.1
<0.1










0.1
1.33

Lone.
mg/1
38
228
7.9
504
140
13.4
0.98










0.0248
3

General Medical Hospitals (8062)
S.I.C.
Kg/day
737.0
2088.8
68.6
4,938
587.3
197.0
59.8


0.147




0.084


2.7468
15
37.8
% of
Ind. Total
3.1
3.6
2.5
2.6
3.3
3.5
4.3


3.7




57.4


14.0
6.67

mg/1
71
201
6.6
475
56
19
5.8


0.014




0.0082


2.7468
15


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     APPENDIX B



SEWER USE REGULATIONS
         123

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       Figure B-l


    SEWER REGULATIONS

         OF THE

 BUFFALO  SEWER AUTHORITY
Buffalo Sewer Authority
Room 1038     City Hall
Buffalo, N.Y.    '14202
         124

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INTRODUCTION

     WHEREAS the Buffalo Sewer Authority was  created by Chapter
349 of the Laws of 1935 (now Title 8 of Article 5 of Chapter 870
of the Laws of New York of 1939,  Sections 1175 to 1195  of the
Public Authorities Law,) and

     WHEREAS upon the completion of the "Project" as defined in
Section 1176, sub-division 8 of the Public Authorities  Law, the
Buffalo Sewerage System theretofore constructed by the  City of
Buffalo was assigned, transferred and dedicated to the  use and
was thereafter in the possession of and under the jurisdiction,
control and supervision of the Buffalo Sewer  Authority, and

     WHEREAS, the Buffalo Sewer Authority has, since the com-
pletion of the "Project" constructed additions and betterments
to the public sewerage system including stormwater and  sanitary
sewers, and

     WHEREAS the Federal Government has enacted Public  Laws
84-660 and Public Laws 92-500, and the Buffalo Sewer Authority
desires to remain in compliance therewith, and

     WHEREAS, the Buffalo Sewer Authority desires to assure that
the use of the public sewerage system operated by it will con-
form to the best sanitary engineering practices, and desires to
regulate the use of the facilities of the Buffalo Sewer Authority,
and

     WHEREAS, the Plumbing Code, the Building Code and the Health
Ordinances of the City of Buffalo regulate to a substantial de-
gree, the construction and use of building service sewers and
the disposal of the sewage and wastes:

     NOW, THEREFORE, the following Regulations, which shall be
considered supplementary to the Plumbing Code, the Building
Code and the Health and other applicable ordinances of the City
of Buffalo, are hereby adopted by the Buffalo Sewer Authority:
                              125

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                            ARTICLE I

                           DEFINITIONS


         Unless the context specifically indicates otherwise,
the meaning of terms used in these Regulations shall be as fol-
lows :

Sec.  1  "ABNORMAL STRENGTH SEWAGE" shall mean any waste having
a suspended solid, BOD, chlorine demand or total phosphate con-
centration in excess of that found in normal strength sewage, but
which is otherwise acceptable into a public sewer under the terms
of these Regulations,

Sec,  2  "A.S.T.M." shall mean the American Society for Testing
and Materials,

Sec,  3  "BOD" (denoting Biochemical Oxygen Demand) shall mean
the quantity of oxygen utilized in the biochemical oxidation of
organic matter under standard laboratory procedure in five (5)
days at 20°C, expressed in milligrams per liter.

Sec,  4  "BSA, THE AUTHORITY, SEWER AUTHORITY" shall mean the
Buffalo Sewer Authority.

Sec.  5  "BUILDING DRAIN" is that part of the horizontal piping
of a building drainage system which receives the discharge of
all soil, waste and other drainage from inside the walls of any
building and conveys the same to the building service sewer five
feet outside the foundation wall of such building.

Sec.  6  "BUILDING SERVICE SEWER" is that part of the horizontal
piping of a building drainage system beginning five feet from
the foundation wall and terminating at its connection with the
main sewer, cesspool,  bacterial tank or other disposal terminal.

Sec.  7  "CHLORINE DEMAND" shall mean the difference between the
amount of chlorine added to water, sewage or industrial wastes
and the amount of residual chlorine remaining at the end of a
fifteen (15) minute contact period.

Sec.  8  "COLLECTING SEWER" shall mean a sewer that receives
wastewater and discharges into a main sewer serving more than
one (1) collecting sewer.


                              126

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Sec.   9  "COMBINED SEWER"  is  a public  sewer or drain intended to
receive domestic sewage,  industrial  water carried wastes,  as  well
as surface, and storm waters.

Sec.  10  "COMMON SEWER" shall mean a building service sewer or
building drain that receives  wastewater from more than one (1)
discharger before it empties  into a collecting sewer.

Sec.  11  "COMPATIBLE POLLUTANT" shall  mean Biochemical Oxygen
Demand (BOD), total suspended solids (TSS), pH, fecal coliform
bacteria, chlorine demand, phosphorus  and phosphorus compounds,
fats, oils and greases of animal or vegetable origin, except  as
prohibited herein or identified on Buffalo Sewer Authority's
National Pollution Discharge Elimination System Permit.

Sec.  12  "COMPOSITE SAMPLE" shall mean a sample consisting of
several  effluent portions collected during a specific time
period and combined to make a representative sample.

Sec.  13  "COMPOSITE SEWAGE" shall mean sewage consisting of
several effluent portions collecting from various discharge lines
at a common point.

Sec.  14  "COOLING WATER" shall mean the water discharged from
any system of condensation such as air conditioning, cooling
or refrigeration.

Sec.  15  "DIRECT DISCHARGE" shall mean the conveyance  of waste
from a building  service sewer, uninterupted to a BSA public  sewer.

Sec.  16  "DOMESTIC  SEWAGE" shall mean a  combination  of the water
carried normal  strength sewage from residences, business build-
ings,  institutions  and industrial establishments.

Sec. 17  "DOMESTIC  USER"  shall mean any  user  not  covered under
the definition  of  "Industrial User" or "Commercial  User".

Sec. 18  "EPA"  shall mean the United  States Environmental  Pro-
tection Agency.

Sec. 19  "GARBAGE"  shall  mean  solid wastes  from  the domestic and
commercial preparation, cooking  and dispensing of food,  and  from
the handling,  storage  and sale of produce.

Sec. 20  "GENERAL  MANAGER" shall  mean the Chief  Executive Officer
of the Buffalo  Sewer Authority or his authorized deputy,  agent
or representative.

Sec. 21  "GROUNDWATER" shall mean water  within the earth that
supplies wells  and springs.

Sec. 22  "INCOMPATIBLE POLLUTANT" shall  mean any pollutant which

                               127

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 is not a compatible pollutant.

 Sec.  23  "INDIRECT DISCHARGE"  shall  mean the  conveyance  of waste
 to a  public BSA sewer by any means  other than that  defined in
 Section 13  of this Article.

 Sec.  24  "INDUSTRIAL USER"  shall  mean  any industrial  or  commercial
 establishment with a classification  as designated in  the "Stan-
 dard  Industrial Classification  Manual" 1972 edition,  as  published
 by the Executive Office  of  the  President and  who utilizes the
 services of the Buffalo  Sewer Authority.

 Sec.  25  "INDUSTRIAL WASTE"  means the  liquid,  solid,  and gaseous
 waste,  including suspended  solids resulting from the  processes
 employed in industrial or commercial establishments.

 Sec.  26  "INDUSTRIAL WASTE PERMIT" shall  mean a permit to deposit
 or discharge  industrial  waste into any sanitary sewer under
 jurisdiction  of the  BSA.

 Sec.  27  "INDUSTRIAL WASTE SURCHARGE"  shall mean a  charge, as
 outlined in the latest edition  of the  Buffalo  Sewer Authority
 Sewer  Rent  Schedule,  levied  on  industrial users of  the sewerage
 treatment works for  the  additional cost  of treating waste dis-
 charges of  abnormal  strength sewage.   This charge includes
 capital,  as well  as  operating and maintenance  costs.

 Sec.  28  "LATERAL  SEWER" shall  mean a  sewer that discharges into
 a  collecting  sewer or other  sewers and has no  other common sewer
 tributary to  it.

 Sec.  29  "MAIN  SEWER" shall  mean a sewer  that  receives waste-
 water  from  the  collecting sewer.

 Sec. 30  "MAJOR CONTRIBUTING INDUSTRY" shall mean an  industrial
 user of the publicly owned treatment works that: (a)  has a flow
 of 50,000 gallons  or more per average  work day; or  (b) has a
 flow greater  than  five percent  of the  flow carried by the muni-
 cipal  system  receiving the waste; or (c) has  in its waste a toxic
 pollutant in  toxic amounts as defined  in standards issued under
 section 307(a)  of  the Federal Water Pollution  Control Act Amend-
ments of 1972;  or  (d) is found  by the  Buffalo  Sewer Authority,
 in  connection with the issuance of a National  Pollution Discharge
Eliminations System  Permit at the publicly owned treatment
works receiving the waste, to have significant impact, as set
forth in these  Regulations,   either singly or in combination with
other contributing industries,   on that treatment works or upon
the quality of  effluent from that treatment works.

Sec. 31  "mg/1" shall mean milligrams per liter.
                              128

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Sec. 32  "MINOR CONTRIBUTING INDUSTRY" shall mean an industrial
user of the publicly owned treatment facility that has a total
discharge of less than 50,000 gallons per day on every day of
the year and does not come under any of the provisions of Section
23 of this Article.

Sec. 33  "NATURAL OUTLET" shall mean any outlet into a water-
course, pond, ditch, lake or other body of surface or ground-
water.

Sec. 34  "NORMAL STRENGTH SEWAGE" shall mean sewage which, when
analyzed, by the BSA, shows by weight a daily average of not
more than 2085 pounds per million gallons (250 parts per million)
of suspended solids, and not more than 2085 pounds per million
gallons (250 parts per million) of BOD and not more than 75.1
pounds per million gallons (9.0 parts per million) of chlorine
demand, and 41.7 pounds per million gallons (5.0 parts per mil-
lion) of phosphorus, and which is otherwise acceptable into a
public sewer under the terms of these Regulations.

Sec. 35  "NPDES" shall mean the National Pollution Discharge
Eliminations System.

Sec. 36  "OBJECTIONABLE WASTE" shall mean any wastes that can
harm either the sewers, sewer treatment process, or equipment,
have an adverse effect on the receiving stream, or otherwise
endanger life, health, or property, or constitutes a nuisance.

Sec. 37  "P" (Total Phosphorus) shall mean the total quantity of
phosphorus contained in a particular waste as determined by
acceptable laboratory procedures, as set forth in Article VI,
Section 11 hereof.

Sec. 38  "PERSON" shall mean any individual, firm, company,
association,  society, corporation or group, including a City,
County, Town, Village, or Sewer District.

Sec. 39  "pH" shall mean the logarithm of the reciprocal of  the
weight of hydrogen  ions in gram moles per liter of solution  as
determined by acceptable laboratory procedures as set forth  in
Article VI, Section  11 hereof.

Sec. 40  "POINT OF  DISCHARGE"  shall mean any discernible,  con-
fined and discrete  conveyance  or vessel  from which pollutants
are or may be discharged into  a public waterway or public  sewer
system.

Sec. 41  "POLLUTED  WATER OR WASTE" shall mean any water,  liquid
or  gaseous waste  containing any of the following: soluble  or
unsoluble substances of organic or inorganic nature which  may
deplete the dissolved  oxygen content  of  the  receiving  stream;
settleable solids that may form sludge deposits;  grease  and  oils;

                              129

-------
 floating solids which may cause unsightly appearance;  color;
 phenols and other substances to an extent which would  impart  any
 taste or odor to the receiving stream; and toxic or poisonous
 substances in suspension, colloidal state, solution or gasses.

 Sec.  42 "ppm" shall mean parts per million.

 Sec.  43  "PRETREATMENT" shall mean the treatment of wastewater
 before introduction into a publicly owned sewerage  system.

 Sec.  44  "PROPERLY SHREDDED GARBAGE" shall mean the wastes  from
 the preparation,  cooking, and dispensing of foods that have
 been shredded to  such a degree that all  particles will be
 carried freely under the flow conditions normally prevailing  in
 public sewers, with no  particle greater  than one-half  (^) inch
 (1.27 centimeters)  in any dimension.

 Sec.  45  "PUBLIC  SEWER" means a publicly-owned  sewer,  storm
 drain, sanitary sewer or combined  sewer.

 Sec.  46  "RECEIVING WATERS"  shall  mean a natural water course or
 body  of water into  which treated or untreated sewage is dis-
 charged.

 Sec.  47  "SANITARY  SEWER" shall mean a sewer intended  to receive
 domestic sewage and admissible  industrial  waste  but  to which
 storm, surface and  groundwaters are not  intentionally  admitted.

 Sec.  48  "SEWAGE"  shall mean  a  combination of the water-carried
 wastes from residences,  business buildings,  institutions and
 industrial establishments,  together with  such ground,  surface,
 and stormwaters as  may  be present.

 Sec.  49  "SEWER"  shall  mean a pipe  or  conduit for carrying  sew-
 age.

 Sec.  50  "SEWERAGE  TREATMENT  PLANT"  shall  mean any arrangement
 of devices and  structures  used  for  treatment  of sewage.

 Sec.  51   "SEWERAGE WORKS"  shall mean all facilities for collect-
 ing, pumping,  treating  and disposing of sewage.

 Sec.  52   "SHALL" is mandatory.  "MAY" is permissive.

 Sec. 53  "SLUG" shall mean any  discharge of water, sewage or
 industrial waste which  in  concentration of any given constituent
 or in quantity of flow exceeds  for  any period of duration longer
 than fifteen  (15) minutes more  than five  (5)  times the average
 twenty-four hour concentration or flow during normal operation.

Sec. 54  "STANDARD METHODS" shall mean "Standard Methods for the


                              130

-------
Examination of Water and Wastewater" prepared and published
jointly by the American Public Health Association, American
Waterworks Association and the Water Pollution Control Federation
latest edition.

Sec. 55  "STORM DRAIN" (sometimes  termed "storm sewer")  shall
mean a public sewer which carries storm and surface waters  and
drainage, but is not intended to carry sewage and industrial
wastes, other than unpolluted cooling water.

Sec. 56  "STORMWATER" shall mean excess water which is derived
from precipitation.  This wuld include surface water.

Sec. 57  "SUSPENDED SOLIDS" shall mean solids that either float
on the surface of, or are in suspension in water, sewage, or
other liquids, and which are removable by acceptable laboratory
procedures as set forth in Article VI, Section 11 hereof.

Sec. 58  "SURFACE WATER" shall mean the source of water which
occurs when the rate of precipitation exceeds the rate at which
water may infiltrate inot the soil.

Sec. 59  "THE ACT" shall mean Public Law 92-500.

Sec. 60  "TOXIC SUBSTANCES" shall mean any substance whether
gaseous, liquid or solid which, when discharged to a public
sewer in sufficient concentrations, may in the opinion of the
General Manager, be hazardous to sewer maintenance and per-
sonnel, tend to interfere with any sewage treatment process,  or
to constitute a hazard to human beings or animals, or to inhibit
aquatic life, or to create a hazard to recreation in the re-
ceiving waters of the effluent from a sewerage treatment plant.

Sec. 61  "TRUNK SEWER" shall mean a sewer constructed, maintained
and operated by the Authority that conveys wastewater to the
Authority's treatment facilities and into which lateral  and
collecting sewers  discharge.

Sec. 62  "UNPOLLUTED WATER" shall mean water which is free of
any polluted water or waste as described in Section 34 of this
Article.

Sec. 63  "USER CHARGE" shall mean a charge leveid on users of
sewerage treatment works for the capital cost,  as well as the
operation and maintenance of such works as outlined in the
latest edition of the Buffalo Sewer Authority Sewer Rent Sched-
ule.

Sec. 64  "WATERCOURSE" shall mean a channel  in  which  a flow  of
water occurs, either  continuously or  intermittently.

Sec. 65  "WPCF" shall mean the Water Pollution Control Federation.

                             131

-------
Sec. 66  "FLOW RATE" shall mean the quantity of waste or liquid
that flows in a certain period of time.

Sec. 67  "FLOW VOLUME" shall mean the quantity of wastes or
liquid.
                            132

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                           ARTICLE II

                       GENERAL PROVISIONS
Sec.  1  PURPOSE
         The purpose of these Regulations is to provide for the
maximum possible beneficial public use of the Authority's facili-
ties through regulations of sewer construction, sewer use and in-
dustrial wastewater discharges to provide for equitable distri-
bution of the Authority's costs,  and to provide procedures for
complying with the requirements contained herein.

Sec.  2  SCOPE

         These Regulations shall  be interpreted in accordance
with the definitions set forth in Article I hereof.  The pro-
visions of these Regulations shall apply to the direct or in-
direct discharge of all liquid carried wastes to facilities of
the Authority.  These Regulations, among  other things provide
for the regulation of sewer construction in areas  within the
jurisdiction of the BSA, the quantity and quality  of discharged
wastes, the degree of waste pretreatment required, the setting
of waste discharge fees to provide for equitable distribution of
costs, the approval of plans for sewer construction, the issuance
of Permits for Industrial Wastewater Discharge and of other mis-
cellaneous permits, and the establishment of surcharges and
other procedures in cases of violaton of these Regulations.

Sec.  3  AREA AFFECTED

         These Regulations shall apply to the City of Buffalo
and those users outside the city who are by contract or agree-
ments with the Buffalo Sewer Authority, users of the Authority's
sewerage treatment works.

Sec.  4  ADMINISTRATION

         Except as otherwise provided herein, the  General Manager
of the Buffalo Sewer Authority shall administer, implement and
enforce the provisions of these Regulations.

Sec.  5  VIOLATION

         Every person violating any provision of these Regula-

                              133

-------
tions, including the failure to pay any fees, charges or sur-
charges imposed hereby, or any condition or limitation of a
permit or plan approval issued pursuant hereto, shall be assessed
a special surcharge of five hundred dollars ($500), as provided
in the Buffalo Sewer Authority Schedule of Sewer Rents and Other
Charges.

         Each day during which any violation continues shall con-
stitute a separate violation.  A day shall consist of a twenty-
four hour period beginning at 12:01 AM and ending the following.
12:01 AM.

         The Buffalo Sewer Authority may, upon authorization of
its Board, sue to recover any amounts due the Authority under
the provisions of these Regulations.

         Any person, who violates any provision of these Regula-
tions pertaining to the subject matter of either subparagraphs
(A) or (B) below, or any condition of limitation of a permit or
plan approval related thereto shall be assessed a special sur-
charge as provided in the Buffalo Sewer Authority Schedule of
Sewer Rents and Other Charges, in a sum not to exceed six
thousand dollars ($6,000) for each day during which such viola-
tion continues.

         (A)  Under these Regulations, the pretreatment of any
industrial waste which would be detrimental to the treatment
works, or its proper and efficient operation and maintenance, is
required as set forth in Article VI, Section 2, hereof.

         (B)  Under these Regulations, the prevention by the user
of the entry of such untreated wastewater into the collecting
system and treatment works is required.

         When, in the opinion of the General Manager, or the
Governmental Agencies, having jurisdiction in the matter, a
violation of these Regulations is of such a nature as to be
likely to cause damage to sewerage systems of the Buffalo Sewer
Authority, or a menace to the health or safety of the inhabitants
of any areas served, the Buffalo Sewer Authority may forthwith
continue and sever any connections with its sewerage system
without any liability for prosecution or damages.

Sec.   6  NOTICE

         Any person found in violation of these Regulations or
of any limitation or requirement of a permit issued hereunder,
may be served, by the General Manager, with a written notice
stating the nature of the violation and providing a reasonable
time limit for the satisfactory correction thereof.  If satis-
factory correcting action is not taken in the time allotted by
the General Manager, action to implement Section 5 of this

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Article shall be taken.

         Unless otherwise provided herein,  any notice required
to be given by the General Manager under these Regulations  shall
be in writing and served in person or by registered or certified
mail.  The notice shall  be sent to the last address of the  vio-
lator known to the General Manager.  Where  the address is un-
known, service may be made upon the owner of record of the  prop-
erty involved.

Sec.  7  TIME LIMITS

         Any time limit  provided in any written notice or  in any
provision of these Regulations may be extended only by a written
directive of the General Manager.

Sec.  8  APPROVAL OF PLANS, ISSUANCE OF PERMITS AND CERTIFICA-
         TION OF FINAL INSPECTION

         The General Manager will approve plans for sewerage
works construction, issue a Permit for Industrial Wastewater
Discharges or any other permit under these Regulations only if
the sewerage construction, sewer connection, industrial waste-
water discharge or other procedure conforms to the requirements
of these Regulations.

         The approval of plans, waste pretreatment process  or the
issuance of a permit by the General Manager, shall not relieve
the discharger of his responsibility to maintain such pretreat-
ment facilities so that its discharge meets all effluent require-
ments contained in these Regulations.

         All required fees and charges shall be paid, before ap-
proval of plans or issuance of a permit will be made.

         The General Manager reserves the right to inspect all
work being constructed for the purpose of complying with these
Regulations.

Sec.  9  FEES AND CHARGES

         All fees and industrial waste charges payable under
the provisions of these Regulations shall be paid  to  the Buffalo
Sewer Authority.  These charges  shall be as outlined  in the
latest edition of the Buffalo Sewer Authority  Sewer Rent Sched-
ule.

Sec. 10  ESTIMATED QUANTITIES AND  VALUES

         Unless otherwise provided herein, whenever  the fees
and charges  required by these Regulations  are  based  on  estimated
values or  estimated quantities the General Manager shall make

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 such determinations  in accordance with estimating practices here-
 tofore used by  the Buffalo Sewer Authority.

 Sec. 11  PAYMENT OF  CHARGES AND DELINQUENT CHARGES

         All fees and charges imposed under the provisions of
 these Regulations, are due and payable upon receipt of the notice
 of charges.  Unpaid  charges shall become delinquent 45 days
 after mailing or delivering the notice of charges.  A basic
 penalty charge  of 10 percent of the unpaid amount shall be added
 to any fee or charge that becomes delinquent.  Interest at the
 rate of one (1) percent per month shall accrue on the total of
 all delinquent  charges including the 10% charge provided for
 herein.

 Sec. 12  NEW INDUSTRIAL WASTEWATER DISCHARGES

         All persons desiring to discharge industrial wastewater
 to the Buffalo  Sewer Authority system must first obtain an In-
 dustrial Wastewater Discharge Permit issued by the General
 Manager of the  Buffalo Sewer Authority.

 Sec. 13  EXISTING INDUSTRIAL WASTEWATER DISCHARGES

         All persons discharging industrial wastewater directly
 or indirectly to the Buffalo Sewer Authority sewerage system
 prior to the effective date of these Regulations and who have ob-
 tained prior approval of that industrial wastewater discharge
 are hereby granted a temporary permit to continue that discharge.
 This temporary  permit shall expire six months after notification
 by the General  Manager that a new permit must be obtained, or
 after two (2)  years for the effective date of these Regulations,
 whichever shall occur first.  Prior to the expiration of the
 temporary permit, the industrial wastewater discharger shall
 apply for and obtain a new permit for industrial wastewater dis-
 charge.

 Sec. 14  PRETREATMENT STANDARDS

         In compliance with Public Laws 84-660 and 92-500 of the
Water Pollution Control Acts and amendments hereto, these
 Regulations adopt and use as a guide the national pretreatment
 standards and the Environmental Protection Agency's (EPA) pre-
 treatment Guidelines.  The Buffalo Sewer Authority recognizes
 that in some cases these pretreatment standards may not be suf-
ficient to protect the operation of its treatment works, or
make it unable  to comply with the terms of its NPDES permit.  In
such cases,  the Buffalo Sewer Authority reserves the right to
impose more stringent pretreatment standards, than those speci-
fied in the EPA regulations.
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Sec. 15  INSPECTIONS

         The General Manager of the Buffalo Sewer Authority,  EPA,
County and State Environmental Conservation Department represen-
tives, bearing proper credentials and identification shall be
permitted to enter upon all properties for the purpose of inspec-
tion, observation, measurements, sampling and testing in accor-
dance with the provisions of these regulations.

Sec. 16  EFFECTIVE DATE OF REGULATIONS

         The effective date of these Regulations is 	.

Sec. 17  SUPERSEDING PREVIOUS REGULATIONS

         These Regulations governing Sewer Construction, Sewer
Use and Industrial Wastewater Discharges shall supersede all
previous regulations of the Buffalo Sewer Authority.
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                            ARTICLE III

                   SANITARY FACILITIES REQUIRED

 Sec.  1  CONNECTIONS

          Sanitary facilities  for  all  structures  in  the  City  of
 Buffalo shall be provided in  accordance  with  Chapter  XI  of the
 Ordinances of the City of Buffalo "Buffalo  Housing  and  Property
 Code",  Chapter XII of the Ordinances  of  the City of Buffalo
 "Buffalo Building Code" and Chapter XXV  of  the Ordinances of the
 City of Buffalo "Buffalo Health Ordinance"  and shall  be  connected
 with the facilities  of the Authority.

 Sec.  2  BUILDING CONNECTIONS

          Building service sewers  to residential,  commercial  or in-
 dustrial buildings shall be required  in  accordance  with  applicable
 ordinances and with  the Plumbing  Code  of the  City of  Buffalo a-
 dopted  by the Examining Board of  Plumbers on  February 4, 1957, and
 approved by the Erie County Health Department  on April  2, 1957,
 as  the  same may be amended from time  to  time,  and all other  sewer
 construction shall be  governed by said Code and  other Ordinances.

 Sec.  3  PRIVATE DISPOSAL SYSTEM

          Where a public sanitary  or combined  sewer  is not avail-
 able, a private sewage  disposal system shall be required, and
 shall be installed in  accordance  with all laws of the State of
 New  York,  Ordinances of the City  of Buffalo and regulations of
 the  Department of Health of the State of New York.  This instal-
 lation  shall  be  subject to  the approval  of the Commissioner of
 Health  of  the  County of Erie, and shall be maintained and oper-
 ated in a  sanitary manner.

 Sec.  4  EXISTING  CONNECTIONS

         Existing  connections to  the combined system will be
 allowed  to function in  their present form until such time as a
 separate sanitary  sewer  shall be  constructed,  at which time all
 sanitary sewer outlets  shall be required to be connected thereto.

         It is one explicit purpose of this Regulation,  by the
application and enforcement thereof to deter,  prevent  and elim-
 inate, as far as possible, the introduction of storm waters into


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the BSA trunk sewer system and all public sewers tributary there-
to.  However, it is recognized that in certain areas the immediate
and strict application and enforcement of these Regulations
against existing and established connections would not be feasible,

         This statement shall not be construed to mitigate in any
way the application and enforcement of these Regulations against
the construction of any new combined sewers and against any new
connections discharging storm water to the BSA trunk sewer system
and public sewers tributary thereto.  Nor shall this statement
of policy be construed to be used as a defense against any changes
which may be ordered by state or federal regulatory agencies.

Sec.  5  SEPTIC SYSTEMS

         Except as hereinafter provided, it shall hereafter be
unlawful to construct or maintain any privy, privy unit, septic
tank, cesspool, or other facility intended or used for the dis-
posal of sewage.  If application is made to the General Manager
of the Buffalo Sewer Authority for a temporary type toilet facil-
ity, and if said applicant has theretofore obtained the approval
of the Erie County Health Department, the said General Manager
of the Buffalo Sewer Authority may consent to the usage of the
same for a temporary period not to exceed 180 days.

Sec.  6  OTHER LAWS, RULES AND REGULATIONS

         These Regulations are in addition to the applicable
Ordinances of the City of Buffalo, the codes and regulations
of the County of Erie and the laws, rules and regulations of
the State of New York and the United States.  Where such laws,
codes, rules and regulations contain provisions more restrictive
than those contained in these Regulations, the former shall apply.
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                           ARTICLE IV

             CONSTRUCTION OF SEWERS AND CONNECTIONS
Sec.   1  PERMITS

         No person shall uncover, make any connections with or
opening  into, use, alter, or disturb any public sewer or appur-
tenance  thereof without first obtaining a written permit for the
City of  Buffalo, Division of Engineering, with the approval of
BSA endorsed thereon, for such connection and, if required, pay
either a permit fee or connection charge.

Sec.   2  PERMIT CHARGES

         A permit and inspection fee of $25.00 for a residential
or commercial building sewer permit, and, $50.00 for an indus-
trial building sewer permit shall be paid to the BSA at the time
the application for the permit is filed.  These charges are in-
tended to cover the administrative costs of processing the ap-
plication.  Other charges and fees are outlined in BSA's latest
edition  of "The Schedule of Sewer Rents and Other Charges".

Sec.  3  NOTIFICATION OF COMPLETION

         The applicant for the building sewer permit shall notify
the BSA   Principal Engineer  when the building sewer is ready
for inspection and connection to the public sewer. The  con-
nection shall be made under the supervision of the Buffalo Sewer
Authority.

Sec.  4  JOINTS

         Every joint in the connection to a sanitary sewer shall
conform to the New York State Department of Environmental Con-
servation requirements and be made water tight so that no leak-
age into or out of such connections shall occur.

Sec.  5  INSPECTION

         No sewerage facility,  other than building service sewers,
shall  be constructed in the City of Buffalo except by the Buffalo
Sewer  Authority,  or by others in accordance with plans and speci-
fications approved by the Buffalo Sewer Authority, and subject


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to inspection during construction by Engineers  and employees
of the Buffalo Sewer Authority.   No sanitary or storm' sewer  shall
be considered to be a part of the public sewerage  system of  the
City of Buffalo unless the Board of the Buffalo Sewer Authority
duly adopts a resolution of completion and acceptance thereof.

Sec.  6  EXPIRATION OF PLANS

         An approval of plans for construction  of  sewerage  facili-
ties shall expire one year after the date of approval unless  con-
struction has been initiated and completed within  a reasonable
time thereafter.

Sec.  7  SPECIAL DRAINS

         Drains receiving acid waste shall be constructed of acid
resisting material.  Such drains located outside of a building
shall be constructed of vitrified clay or earthenware pipe  or
other approved acid resisting material.  Joints shall be con-
structed by caulking with asbestos rope wicking and by pouring
a heated sulphur and carbon compound or a heated bituminous
compound in such a manner as to secure tight joints.

Sec.  8  CLASSES OF PERMITS

         There shall be two (2) classes of sewer permits: (a) for
residential and commercial service and (b) for  service to estab-
lishments producing industrial wastes.  In either case, the owner
or his agent shall make application on a special form furnished
by the Buffalo Sewer Authority.  The permit application shall be
supplemented by any plans, specifications, or other information
considered pertinent in the judgement of the General Manager.

Sec.  9  CONNECTION COSTS

         All costs and expense incident to the installation and
connection of the building service sewer shall be borne by the
owner.  The owner shall indemnify the City of Buffalo and the
Buffalo Sewer Authority from any loss or damage that may directly
or indirectly be occasioned by the installation of the building
service sewer.

Sec. 10  SEPARATE CONNECTIONS

         A separate and independent building service sewer shall
be provided for every building in residential and commercial
areas, except that where one building stands at the rear of
another on an interior lot, and no private sewer  is available,
or can be constructed to the rear building through an adjoining
alley, court, yard, or driveway, the building service sewer  from
the front building may be  extended to the rear building  and  the
whole considered as one building service sewer.

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 Sec.  11  USE  OF EXISTING SEWEPS

          Old  building  service  sewers  may  be  used  in  connection
 with  new buildings  only  when they  are found,  on examination by
 the BSA Principal Engineer, to meet all requirements of  these
 Regulations.

 Sec.  12  SPECIFICATIONS

          The  size,  slope,  alignment,  materials of construction
 of a  building service  sewer, and the  methods  to be used  in ex-
 cavating,  placing of the pipe, jointing,  testing and backfilling
 the trench, shall all  conform  to the  requirements of the build-
 ing and plumbing code  or other applicable rules and regulations
 of the  City of Buffalo.   In the absence of code provisions or in
 amplification thereof, the materials  and procedures set  forth in
 appropriate specifications of  the ASTM and WPCF Manual of Practice
 No. 9 (Design and Construction of Sanitary and Storm Sewers)
 shall apply.

 Sec.  13  ELEVATION  OF  SEWERS

          Whenever possible, the building service sewer shall be
 brought to the  building  at an  elevation below the basement floor.
 In all  buildings in which below floor  building drains are too low
 to permit  gravity flow to the  public  sewer, sanitary sewage
 carried by such building  drains shall  be lifted by means estab-
 lished  in standard  engineering practice to a suitable level and
 then  discharged to  the building service sewer, or the building
 drain may  be  hung on the  cellar wall  and shall not be less than
 four  (4)  inches  in  diameter.

 Sec.  14   CONNECTION OF ROOF AND FOUNDATION DRAINS

         No person .shall make  connection of roof downspouts, ex-
 terior  foundation drains, areaway drains, or any other sources
 of surface runoff or groundwater to a  building service sewer or
 building drain which in  turn is connected directly or indirectly
 to  a  public sanitary sewer.

 Sec.  15  PUBLIC SAFETY

         All excavations for building  service sewer installation
 shall  be adequately guarded with barricades and lights so as to
protect the public from hazard.  Streets, sidewalks, parkways
and other public property disturbed in the course of the work
shall  be restored by the Permittee in  a manner satisfactory to
the City of Buffalo.
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                            ARTICLE V

                      USE OF PUBLIC SEWERS

                             GENERAL


Sec.  1  INDUSTRIAL WASTEWATER DISCHARGES PROHIBITED

         No industrial wastewaters shall be discharged to a trunk
sewer or to a sewer discharging directly or indirectly to a trunk
sewer until a Permit for Industrial Wastewater Discharge has been
approved by the General Manager.

Sec.  2  DISCHARGE OF WATERS NOT CONTAINING SEWAGE

         The discharge of waters not containing sewage is pro-
hibited.  Except with the approval of the General Manager, or as
otherwise provided in these Regulations, no storm water connection
from any building or yard, nor any drain from any catch basin,
lake, swamp, pond, or swimming pool, nor any outlet for surface
water, storm water or ground water of any kind shall be connected
to the BSA trunk sewer system or any public sewer tributary there-
to or to any private sewer connected to any such public sewer.

         Within any area served by a separate sanitary sewer and
a storm sewer, no storm water shall be allowed to enter soil,
waste or vent pipes from any building.  Within any such area no
down spout, roof leaders, gutters, other pipes, or drains such
as channels which may at any time carry storm water surface
drainage derived from hydraulic pressure or from well points,
cooling water or lake water shall be connected with any sanitary
sewer, but must be connected to said storm sewer.

Sec.  3  DISCHARGE TO A NATURAL OUTLET

         It is prohibited to discharge to any storm sewers or
natural outlet within the area served by the Buffalo Sewer Author-
ity any sewage or other polluted waters, except where suitable
treatment has been provided in accordance with the provisions of
these Regulations, and except where a Federal National Pollutant
Discharge Elimination Systems (NPDES) permit has been duly issued
and is currently valid for such discharge.  A valid copy of such
a permit and any modifications thereof must be filed with the
General Manager for an exception under this section of these
Regulations.


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 Sec.   4  COOLING WATER DISCHARGE

          The discharge of industrial  cooling water or unpolluted
 process waters to a storm sewer, combined sewer or a natural  out-
 let without the approval of the General  Manager is prohibited.

 Sec.   5  PROHIBITED DISCHARGES

          No person shall discharge or cause  to  be  discharged  any
 of the following described waters  or  wastes  to  any public  sewers
 or natural  outlets:

          (a)   Any gasoline,  benzene,  maphtha, fuel oil, or other
 flammable or explosive liquid,  solid  or  gas.

          (b)   Any waters used  for  the purpose of diluting wastes
 which would exceed applicable  maximum concentrations  limitations.

          (c)   Any water  or wastes  having a pH lower than 5.5, or
 having a pH higher than  9.5- or  having any other corrosive
 property capable of  causing  damage or hazard  to structures,
 equipment of the sewer system,  or  personnel  employed  in its oper-
 ation.

          (d)   Solid  or viscous  substances in quantities or of
 such  size as  to  be capable of  causing, obstruction to  the flow in
 sewers  or otherwise  interfering  with  the proper operation of the
 sewage  works  such as,  but  not  limited to, ashes, cinders, sand,
 mud,  straw,  shavings,  metal, glass, rags, feathers, tar, plastics,
 wood,  unground garbage,  whole  blood,  paunch manure, hair and
 fleshings,  entrails,   paper  dishes, cups, milk containers, etc.,
 either  whole  or  ground by  garbage  grinders.

          Ce)   Any waters  or wastes  containing toxic or poisonous
 solids,  liquids,  or  gases  in sufficient  concentration  in the
 opinion  of  the General Manager either singly or by  interaction
 with  other wastes,  to  injure or  interfere with any  sewage treat-
 ment  process,  or  to  constitute a hazard  to humans  or animals or
 to create a public nuisance, or  to  create any hazards  in the re-
 ceiving waters of a  sewage treatment  plant effluent.

          (f)   Wastes,  other than domestic sewage,  from any hospi-
 tal, mercantile,  manufacturing or  irrhisfrip.l establishment, or
 any steam, hot gases or vapors,  grease fats, oils,   acids, carbon,
 iron or mineral wastes, or any other  wastes which would tend to
 obstruct the public  sewer, to be injurious to the public health,
 create odors, be  determental to  the sewerage works, or which
would interfere with the proper repair or maintenance of the
 sewerage system,  the operation and maintenance of  the disposal
works or the proper  treatment of domestic sewage, or which re-
 sults after treatemnt  in an effluent which is a menace to life or
health.

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Sec.  6  LIMITED DISCHARGES

         No person shall discharge or cause to be discharged into
the public sewerage system or into a natural outlet,  the follow-
ing described substances: materials, waters, or wastes, if it
appears likely in the opinion of the General Manager, that such
wastes are likely to harm the public sewers, sewage treatment
process, or equipment, have an adverse effect on the  receiving
stream, or is likely to otherwise endanger life, health or pro-
perty, or constitute a nuisance.  In forming his opinion as to
the acceptability of these wastes, the General Manager will give
consideration to such factors as the quantities of subject wastes
in relation to flows and velocities in the sewers, materials of
which the sewer is constructed, nature of the sewage  treatment
process, capacity of the sewage treatment plant, degree of treat-
ability of wastes in the sewage treatment plant and other factors
which are pertinent in the opinion of the General Manager.  The
substances prohibited are:

         (a)  Any liquid or vapor having a temperature higher than
one hundred fifty (150°?) (65°C).  if, in the opinion of the
General Manager, lower temperatures of such wastes could harm
either the sewers, sewage treatment process, or equipment, have
an adverse effect on the receiving stream, or could otherwise en-
danger life, health or property, or constitute a nuisance, the
General Manager may prohibit such discharges.

         (b)  Any water or waste containing fats, wax, grease,
or oils, whether emulsified or not, in excess of fifty (50) mg/1
or containing substances which may solidify or become viscous
at temperatures between thirty-two (32)op or (0)°C and one hun-
dred fifty  C150)°F and  C.65)oc.

         (c)  Any garbage that has not been properly shredded.
The installation and operation of any garbage grinder equipped
with a motor of three -fourths  (3/4) horse power  (0.76 hp metric)
or greater shall be subject to the review and approval of the
General Manager,

         (d)  Any waters or wastes containing heavy metals and
similar objectionable or toxic substances to such degree  that
any such material received in the composite sewage at the Point
of Discharge exceeds the limits established below:

                 Chromium (Total)           2.0 mg/1
                 Chromium (Trivalent)       1,0 mg/1
                 Chromium (Hexavalent)      0.1 mg/1
                 Copper                     0.4 mg/1
                 Zinc                       0,6 mg/1
                 Nickel                     1.0 mg/1
                 Cadmium                    0,2 mg/1
                 Arsenic                    0,1 mg/1

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                  Barium                    1.0  mg/1
                  Lead                       0.1  mg/1
                  Manganese                  1.0  mg/1
                  Silver                    .05  mg/1
                  Boron                      1..0  mg/1
                  Mercury                    .01  mg/1
                  Selenium                   .05  mg/1

 or any element  which will in  the  opinion' of  the General Manager,
 damage collection facilities  or be  detrimental  to  the treatment
 processes.   The limits  set  forth  above  amy be amended from time
 to time as  such amendment is  deemed necessary by the General
 Manager to  protect the  facilities or  life or health.

          (e)  Any water or  wastes that  contain  phenolics in ex-
 cess  of 0.1 parts per million by weight,  or  other  taste or odor
 producing substances in such  concentrations  exceeding limits
 established by  the  General  Manager.

          (f) Any  radioactive  wastes or  isotopes of such half-life
 or concentrations as may exceed limits  established by the General
 Manager in  compliance with  applicable State, Federal, or other
 public  agencies having  jurisdiction.

          (g)  Quantities of flow, concentrations, or both, which
 constitute  a "slug" as  defined herein.

          (h)  Materials which cause:

              1.   Unusual concentrations of  inert suspended
 solids  which are  defined as concentrations exceeding 250 ppm or
 dissolved solids  such as but  not limited to, sodium chloride in
 concentrations  greater  than 10,000  ppm  and sodium sulfate in
 concentrations  greater  than 500 ppm.

              2.   Unusual concentrations of BOD which are defined
 as  concentrations  exceeding 250 ppm, chlorine requirements ex-
 ceeding  9.0 ppm or phosphorus concentrations exceeding 5.0 ppm.

              3.  Discolorations, such  as, but not limited to
 dye waters  and vegetable tanning solution.

         In cases where the effluent characteristics of an indus-
 trial or commercial discharge exceeds the maximum permissible
 limits stated above, the acceptability  of such waste will be
 left to  the engineering judgement of the General Manager.  If
 in  the judgement  of the General Manager the admission of such
wastes will not overload the Authority's facilities, a permit
 to  discharge said waste may be granted.  However, the Authority
may require the payment of an industrial waste surcharge for
both capital and  operating and maintenance expenses to cover the
 cost of  treatment for the abnormal  strength sewage.

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         Ci)  Waters or wastes containing substances which are
not amenable  to treatment or reduction by the sewage treatment
processes employed, or are amenable to treatment only to such
degree that the sewage treatment plant effluent cannot meet the
requirements of State, Federal or other agencies having juris-
diction over discharge into the receiving waters.

         Cj)  Any waters or wastes which by interaction with
other waters or wastes in the public sewerage system release
odors, form suspended solids which interfere with the collection
system or create a condition deleterious to the sewerage works.

         (k)  Any waste with a concentration of cyanide in excess
of 0.8 mg/1.
              Any waste containing any substance that may pre-
         ,««idify» or become viscous at temperatures between
4U°r and 100UF.

Sec.  7  IMPROPER USE OF SEWERS

         The Buffalo Sewer Authority hereby reserves the right
to inspect any existing building service sewer and drain, lateral
or collecting sewers that discharge wastewater directly or in-
directly to the Authority's facilities.  If it is found that
such laterals or collecting sewers are used or maintained in
such a way as to cause discharge of septic wastewater or ground
water or debris which exceeds the design criteria of said sewer
or any other substance deemed objectionable by the General Mana-
ger, the General Manager will give notice of the unsatisfactory
condition to the discharger and shall direct that the condition
be corrected,

         In cases of continued  non-compliance with the General
Manager's directive, the Buffalo Sewer Authority may disconnect
the said sewer from the Authority's sewerage system without any
liability for prosecution or damages,

Sec,  8  EXCESSIVE SEWER MAINTENANCE EXPENSE

         No person shall discharge or cause to be discharged to
a trunk sewer, either directly or indirectly, any waste that
creates a stoppage, plugging, breakage, any reduction in sewer
capacity or any other damage to sewers or sewerage facilities of
the Authority.  Any additional sewer or sewerage maintenance
expenses caused by such a discharge, or any other expenses at-
tributable thereto will be charged to the discharger by the
Authority,

         Any refusal to pay the additional maintenance expenses
duly authorized by the General Manager shall constitute a viola-


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tion of these Regulations.   The charge shall be determined as
outlined in the latest edition of the BSA's Schedule of Sewer
Rents and Other Charges.
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                           ARTICLE VI

                      INDUSTRIAL WASTEWATER


Sec.  1  PERMIT FOR INDUSTRIAL WASTEWATER DISCHARGE

         No person shall discharge, or cause to be discharged,
any industrial wastewaters directly or indirectly to sewerage
facilities owned by the Buffalo Sewer  Authority without first
obtaining a Buffalo Sewer Authority Permit for Industrial Waste-
water Discharge.  As a condition for issuance of a Permit, the
BSA may require that any user of the Authority's facilities shall
enter into a contractual agreement for a period of one year with
provisions for renewal of such agreements as may be required by
the General Manager.

         If the volume or character of the waste to be treated  is
determined by the BSA not to cause overloading of the sewage
collection, treatment, or disposal facilities of the BSA, then
prior to approval, the General Manager and the person making the
discharge shall enter into an agreement which provides that the
discharger pay a sewer rent or industrial waste charge, as out-
lined in the latest edition of "The Schedule of Sewer Rents and
Other Charges".

         If the volume or character of the waste to be treated
by  the BSA requires that wastewater collection, treatment, or
other disposal facilities of the Authority be improved, expanded,
or  enlarged in order to treat the waste, then prior to approval,
the BSA and the person making the discharge shall enter into an
agreement which provides that the discharger pay in full all
added costs the Authority may incur due to acceptance of the
waste.

         The Permit for Industrial Wastewater Discharge may re-
quire pretreatment of industrial wastewaters before discharge,
restriction of peak flow discharges, discharge of certain waste-
waters only to specified sewers, relocation of points of  dis-
charge, prohibition of discharge of certain wastewater components
restriction of discharge to certain hours of the day, payment
of  additional charges to defray increased costs of  the Authority
created by the wastewater discharges and such other conditions
as  may be required to effectuate the purpose of these Regula-
tions.


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          No Authority Permit for Industrial Wastewater Discharge
 is transferable without the prior written consent of the General
 Manager.

          No person shall discharge industrial wastewaters in ex-
 cess of the quantity or quality limitations set by his Permit for
 Industrial Wastewater Discharge.  Any person desiring to dis-
 charge wastewaters or use facilities which are not in conformance
 with its Industrial Wastewater Permit must apply to the General
 Manager for an amended Permit.   Such amended Permit shall be
 granted provided its terms shall comply with these regulations.

          It is the explicit purpose of this Article to achieve
 the following:

          (a)   Protect the operation of the publicly owned sewer-
 age works,

          (b)   To prevent inadequately treated pollutants  from
 passing through said works,  and

          (c)   To insure the Buffalo Sewer Authority's  compliance
 with their NPDES Permit.

 Sec.   2  APPLICABILITY

          The  standards  and procedures  set forth in this Article
 apply to all  industrial users of the  Buffalo  Sewer Authority
 sewerage system.

          Where an industrial user qualifies  as  a  major contribut-
 ing industry,  EPA's  Effluent Guidelines  and Standards  will de-
 termine the characteristics  of  permissible  waste  discharges  and
 the degrees of pretreatment  required.   In cases where  the
 General Manager deems it  necessary  to  impose  more  stringent  re-
 quirements, or where  removals within  the  system permit  less
 stringent requirements,  and where no  EPA  guidelines  exists,  the
 provisions  of  Article V (Use of Public  Sewer-General)  of  these
 Regulations shall  apply.

 Sec.   3  PROCEDURE FOR  OBTAINING A  PERMIT FOR INDUSTRIAL WASTE-
          WATER DISCHARGE

          Applicants for  a  Permit  for  Industrial Wastewater Dis-
 charge  shall complete a Buffalo  Sewer Authority application  form
 available  in the appendix  of these  Regulations  or  at the Buffalo
 Sewer Authority offices, Room 1030, City  Hall.

         Upon  receipt of all required information,  the applica-
 tion shall be processed.  When properly executed by  the BSA,  the
 application form shall  constitute a valid Permit for Industrial
Wastewater Discharge.

                             150

-------
         The application shall  be approved if the  applicant  has
complied with all applicable requirements  of these Regulations.

Sec.  4  CHANGES OF INDUSTRIAL  WASTEWATER  PERMIT RESTRICTIONS

         As EPA adds or amends  specific pretreatment and effluent
guidelines, or as the Buffalo Sewer Authority deems necessary,
the restrictions or conditions  of a Permit for Industrial Waste-
water Discharge may require amendment, as  circumstances dictate.
The Buffalo Sewer Authority shall require  an industrial discharg-
er to establish an abatement time schedule to comply with any
changes in the Industrial Wastewater Permit.

Sec.  5  SUSPENSION OF PERMIT FOR INDUSTRIAL WASTEWATER DISCHARGE

         The General Manager may suspend a Permit  for Industrial
Wastewater Discharge when such suspension is necessary in the
opinion of the General Manager, in order to stop a discharge
which presents a hazard to the public health, safety or welfare,
to the environment, or the Authority's sewerage system.

         Any discharger notified of a suspension of his Indus-
trial Wastewater Permit shall immediately stop the discharge of
all industrial wastewater to the BSA system.  In the event of a
failure of the discharger to comply voluntarily with the sus-
pension order, the  General Manager shall take such steps per-
suant to Article II, Section 5 as he deems necessary to insure
compliance.

         The General Manager shall reinstate the  Industrial
Wastewater Permit upon proof of  satisfactory compliance with all
discharge requirements of these  Regulations.

Sec.  6  REVOCATION OF PERMIT FOR  INDUSTRIAL WASTEWATER DISCHARGE

         The General Manager may revoke a Permit  for Industrial
Wastewater Discharge upon a  finding that  the discharger has
violated any provision of these  Regulations.

         Any discharger whose  Industrial Wastewater Permit  has
been  revoked shall  immediately  stop all discharge of any  liquid
carried wastes  covered by the  Permit  to any public sewer  that
is  tributary to  a  sewer  or  sewerage system  of  the Authority.
The General Manager may  disconnect or permanently block from
such  public  sewer  the  industrial connection of any discharger
whose Permit has been  revoked,  if  such action is  necessary  to
insure  compliance  with the  order of revocation.

         Before any further discharge of  industrial wastewater
may be made  by the discharger,  he  must apply for  a new Permit
for Industrial Wastewater  Discharge,  pay  all charges  that would
be required upon initial  application  together with all delin-

                              151

-------
 quent fees, charges and such other sums as the discharger may owe
 to the Authority.  Costs incurred by the Authority in revoking
 the Permit and disconnecting the industrial sewer shall  be paid
 for by the discharger before issuance of a new Permit.

 Sec.   7  PROHIBITED WASTE DISCHARGES

          In most cases, the concentration or amounts  of  any par-
 ticular constituent which will be judged to be excessive or
 unreasonable cannot be foreseen,  but will depend on the  results
 of technical determination and action of regulatory agencies.
 A partial list of these constituents appear in Article V of these
 Regulations.  However, as new regulations and requirements are
 promulgated by Federal and State  authorities, they too will be-
 come part of these Regulations.

 Sec.   8  INDUSTRIAL WASTEWATER SURCHARGE

          As a condition of the Industrial Waste Permit,  an in-
 dustry may be required to pay an  industrial waste  surcharge.
 The payment of the surcharge  shall,  at  a minimum,  occur  annually.
 This  surcharge will be required from those industrial wastewater
 dischargers whose contribution of compatible pollutants  create
 costs  in  excess of that normally  created by a domestic user.   The
 surcharge shall be based on the Authority's annual  debt  service
 and total operating and maintenance  costs for providing  industrial
 wastewater collection,  treatment  and disposal services.   The
 actual charges and formula for determining these charges  are out-
 lined  in  the Buffalo Sewer Authority's  Schedule  of  Sewer  Rents
 and Other Charges.

 Sec.   9  PRETREATMENT OF INDUSTRIAL  WASTEWATERS

          An Industrial  Wastewater  Pretreatment  System may  be re-
 quired by the General Manager  to  treat  industrial flows prior  to
 discharge to  the  BSA system when  it  is  necessary to measure,
 sample, restrict  or prevent the discharge  to  the sewer of  certain
 waste  constituents,  to  more equally  distribute peak discharges
 of  industrial  wastewater,  or  to accomplish  any pretreatment re-
 sult required  by  the  General Manager.   All  pretreatment systems
 shall  be  subject  to  the  approval of  the  Sewer Authority, but such
 approval  shall  not  relieve  the industrial  dischargers of the
 responsibility  of meeting  any  required  industrial effluent  limit-
 ations.  All pretreatment  systems  shall  be  adequately engineered
 and designed  to the  satisfaction of  the  General Manager and all
 reports and plans shall  have been  prepared  and signed by a pro-
 fessional engineer  licensed in the State  of New York.

 Sec. 10  CONTROL MANHOLE

         As a condition  of  the Industrial Waste Permit, when re-
quired by the General Manager, the owner  of any property serviced

                               152

-------
by a building service sewer,  carrying wastewater shall  install  a
suitable control manhole together with such meters  and  other ap-
purtenances deemed necessary  by the General Manager to  adequate -
ly sample and measure the waste passing through the control  man-
hole.  This control manhole shall be located so as  to permit un-
restricted access by representatives of the Authority.   The  con-
trol manhole may be used as a junction manhole for  domestic
sewage and industrial waste providing the junction  occurs down-
stream of the sampling or flow measuring point.

Sec. 11  INDUSTRIAL WASTEWATER SAMPLING, ANALYSIS AND FLOW
         MEASUREMENTS

         Periodic measurements of flow rates, flow  volumes,  BOD,
P, chlorine demand and suspended solids for use in  determining
the annual industrial wastewater treatment charges, and such
measurements of other constituents deemed necessary by the
General Manager, shall be made on all industrial wastewater dis--
charges, unless specifically relieved of such obligation by the
Authority.  All sampling, analysis and flow measurements of in-
dustrial wastewaters shall be performed by an independent lab-
oratory, or by a laboratory of an industrial discharger, approved
by the General Manager.  If performed by the Sewer Authority per-
sonnel, an appropriate charge shall be paid by the discharger re-
questing the tests.  The charges are outlined in the latest
edition of the Schedule of Sewer Rents and Other Charges.  Prior
to submittal to the Authority of data developed in the laboratory
of an industrial discharger, the results shall be verified by a
responsible administrative official of the industrial firm or
corporation.

         All wastewater analysis shall be  conducted  in accordance
with the appropriate procedure contained in EPA's  "Methods of
Analysis of Water  and Wastes", 1971Cmost recent edition) or
"Standard Methods".  If no appropriate procedure is  contained
therein, the standard procedure of  the  industry, or  a procedure
judged satisfactory by the General Manager, shall  be used to
measure wastewater constituents.   Any independent laboratory
or discharger performing tests, shall furnish  the  required test
data or information on the test methods or equipment used, if
requested to do so by the General Manager.

         All dischargers making periodic measurements shall  fur-
nish and install at the control manhole, or other  appropriate
location, a calibrated flume, weir,  flow meter or  similar de-
vice approved by the General Manager,  and  suitable to measure
the  industrial wastewater  flow rate  and  total  volume.  A flow
indicating, recording, and totalizing  register may be  required
by  the  General Manager.   In  lieu  of wastewater flow  measurement,
the  General Manager may  accept records  of  water usage  and adjust
the  flow volumes by  suitable  factors to  determine  peak  and  aver-
age  flow rates  for the  specific  industrial wastewater  discharge.

                               153

-------
           The  sampling,  analysis  and  flow measurement procedures
  equipment and results  shall  be subject  at any  time  to  inspection
  of the Authority.

           When required  by  the General Manager, dischargers shall
  install  and maintain in proper order, automatic flow-proportional
  sampling equipment  and/or  automatic  analysis and recording equip-
  ment .

           Measurements to verify  the  quantities of waste flows and
  waste  constituents  reported by industrial discharges will be con-
  ducted on a random  basis by personnel of  the Authority.

  Sec. 12   DISCREPANCIES  BETWEEN ACTUAL AND REPORTED INDUSTRIAJ
           WASTEWATER DISCHARGE QUANTITIES

      ,.   ,In the event a discharger fails to report changes in
  his discharge characteristics to the General Manager,  and should
  measurements and other  investigations reveal that a discharger
  is discharging a flow rate, flow quantity, or waste exhibiting
  waste  characteristics in concentrations  in excess of that stated
  on their  Industrial Waste Permit, the discharger must  then apply
  for an amended Industrial Wastewater Permit.  If the erroneous
  data reported to the Authority by the discharger was used as  a
 basis for an industrial waste treatment  charge, the discharger
  shall be assessed for all delinquent charges together with the
 additional 10% charge and interest provided for in Article II
 Before additional charges  shall be assessed or  the permit amended
 at least two (2)  additional 24-hour samples and flow measurements
 shall be obtained by the Authority or by another  independent
 laboratory acceptable  to both parties, with all costs of  sampling
 and analysis  to be paid  by  the discharger.

          For  the  purpose of establishing the correct treatment
 surcharge, the data  obtained  in these samplings,  along  with any
 other relevant information  obtained by the Authority or presented
 by the  discharger,  shall be used  by the  General Manager in de-
 termining the  quantity parameters for use in the  formula.  An
 industrial discharger found in violation,  shall in  the  absence
 of other  evidence  by presumed to  have been discharging  at  the
 determined parameter values over  the  preceeding year, or  sub-
 sequent to the previous  Authority verification  of quantity
 parameters, whichever period is shorter.

 Sec. 13   DAMAGE CAUSED BY PROHIBITED  WASTEWATER DISCHARGE

         Any industrial  wastewater  discharger who discharges, or
 causes  the discharge, of prohibited wastewaters which cause dam-
 age to  the Authority's facilities,  detrimental  effects on  treat-
ment processes or any other damages resulting in costs to  the
Sewer Authority, shall be liable  for  all damages occasioned
thereby.

                              154

-------
Sec.  14  TRUCKERS DISCHARGE PERMIT

         All persons owning vacuum or "cesspool" pump trucks,  or
other liquid transport trucks,  and desiring to discharge septic
tank, seepage pit,' interceptor or cesspool contents,  industrial
liquid waste or other liquid wastes to sewerage facilities of
the Authority, or to facilities that discharge directly or in-
directly to such sewerage facilities, shall first have a valid
Sewer Authority Trucker's Discharge Permit.  All applicants for
a Trucker's Discharge Permit shall complete the application form,
pay the appropriate Permit fee, receive a copy of the Sewer
Authority Regulations governing discharge to sewers,  of liquid
wastes from trucks and shall agree, in writing, to abide by
these Regulations.

         Discharge of septic tank, seepage pit, interceptor or
cesspool contents or other wastes containing no industrial wastes,
may be made by truckers holding a Permit at any of the designated
public dumping manholes.  Truck transported industrial wastes
shall be discharged only at the locations specified by the
General Manager for the specific waste.  The Sewer Authority
shall require payment for treatment and disposal costs fo the
compatible  industrial waste, or may refuse permission to dis-
charge prohibited wastes.

         The Trucker's Discharge Permit shall be valid for one
(1) year from date  of issuance.

         Any person violating  the Authority's requirements for
liquid waste  discharges  from  trucks may have his Permit revoked
by the General Manager.
                               155

-------
                           APPENDIX C



           PILOT PLANT INVESTIGATIONS BACKGROUND DATA





Table




 C"1                   November's Pilot Plant Operational Data



 c"2                   December's Pilot Plant Operational Data



 c"3                   Daily Trace Element Concentrations



 c"4                   Waste Primary Sludge Characteristics



 C~5                   Waste Secondary Sludge Characteristics







Figure




 C-l                   Daily Cadmium Variation



 C-2                   Daily Chromium Variation



 C-3                   Daily Copper  Variation



 C-4                   Caily Cyanide Variation



 C-5                   Daily Lead Variation



 C-6                   Daily Nickel  Variation



 C-7                   Daily  Zinc Variation
                             156

-------
                                                Table C-l.   NOVEMBER'S PLANT OPERATIONAL DATA
D
A
T
E
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
D
A
Y
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Total C.O.D.
mg/1
Infl.
263.7
236.4
221.8
214.1
187.6
239.0
229.6
246.1
269.7
220.0
238.6
242.3
154.1
136.2
108.9
112.8
97.7
88.6
244.2
177.1
126.5
173.2
200.7
113.3
196.0
203.8
201.6
173.2
193.3
140.7
P.E.

-
-
-
-
-
-
-
-
_
-
_
-
-
-
-
-
_
194.0
102.0
118.6
153.5
145.6
86.0
176.4
173.6
155.0
100.0
148.6
117.7
S.E.
70.8
81.4
81.7
62.3
85.9
82.3
46.7
78.2
66.4
77.2
76.9
76.9
55.3
42.8
58.4
66.1
46.9
42.8
73.6
59.0
39.5
47.2
31.5
50.8
62.7
41.6
31.0
19.2
55.7
41.8
% Remova
Prim.

-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
20.6
42.4
6.2
11.4
27.5
24.1
10.0
14.8
23.1
42.3
23.1
16.2
Total
73.2
65.6
63.2
70.9
54.2
65.6
79.7
68.2
75.4
64.9
67.8
68.3
64.1
68.6
46.4
41.4
52.0
51.7
69.9
66.7
68.8
72.7
84.3
55.2
68.0
79.6
84.6
88.9
71.2
70.3
Soluble C.O.D.
mg/1
Infl.
114.1
96.9
81.7
105.1
93.8
113.7
-
132.9
78.2
100.4
92.4
115.4
79.1
54.5
77.8
73.9
54.7
54.5
89.1
59.0
75.1
90.5
-
62.5
117.6
101.9
96.9
34.6
107.8
60.8
P.E.
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
96.9
55.1
55.3
106.3
-
66.4
101.9
90.6
62.0
34.6
100.3
49.4
S.E.
59.0
50.4
50.6
46.7
46.9
51.0
-
46.9
27.4
42.5
46.2
57.7
39.5
35.0
46.7
50.6
31.3
27.2
46.5
39.4
19.8
23.6
-
39.1
47.0
30.2
15.5
3.8
40.9
11.4
% Removal
Prim.
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
6.6
26.4
-
-
-
13.4
11.1
36.0
0.0
7.0
18.8
Total
48.3
48.0
38.1
55.6
50.0
55.1
-
64.7
65.0
57.7
50.0
50.0
50.1
35.8
40.0
31.5
42.8
50.1
47.8
33.2
73.6
73.9
-
37.4
60.0
70.4
84.0
89.0
62.1
81.4
Flow
103
gpd
11.9
9.9
12.8
8.5
9.1
10.1
12.7
12.9
13.4
14.6
12.7
12.7
13.6
13.2
10.8
12.8
13.9
14.8
29.6
30.6
33.2
25.3
24.6
21.2
27.6
22.0
21.0
20.6
18.9
9.3
Precp
in.

















0.0
0.27
0.99
0.10
0.00
0.00
0.74
0.00
0.00
0.00
0.10
0.00
0.00
Total B.O.D.
mg/1
Infl.
72.9
87.9
76.5
91.5
56.7
79.5
78.0
77.1
64.3
78.0
97.5
85.7
42.0
33.0
33.0
34.5
19.5
21.6
48.0
28.0
32.5
59.3
68.3
33.5
42.6
63.0
-
34.2
59.3
40.2
P.E.
_.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
51.0
27.6
33.0
36.0
33.0
24.8
30.6
65.3
-
31.1
41.5
40.1
S.E.
11.4
14.3
15.8
14.5
15.0
16.5
10.0
8.4
9.6
16.5
13.5
13.2
7.5
8.7
11.0
16.2
7.5
6.8
12.0
9.0
6.2
6.0
5.4
6.5
3.8
6.2
-
4.7
6.8
4.4
% Removal
Prim.
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
1.4
-
39.3
51.7
26.0
28.2
-
-
9.1
30.0
~
Total
84.4
83.7
79.3
84.2
73.5
79.2
87.2
89.1
85.1
78.8
86.2
84.6
82.1
73.6
66.7
53.0
61.5
80.6
75.0
67.4
80.9
89.9
92.1
80.6
91.1
90.2
-
86.3
88.5
89.1
Soluble B.O.D.
mg/1
Infl.
_
-
26.5
41.0
-
41.0
44 .T)
38.0
27.8
37.0
54.0
44.1
21.6
14.0
30.0
20.4
18.0
13.5
25.2
14.4
22.8
-
-
-
28.5
42.0
-
14.2
36.5
21.8
P.E.
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
33.0
14.3
24.4
-
-
-
19.9
40.2
-
21.8
31.5
21.9
S.E.
6.5
7.1
8.5
6.4
-
3.5
5.6
6.0
5.1
7.2
6.0
4.0
3.6
4.3
3.6
8.0
3.6
4.2
7. 5
4.2
6.6
-
-
-
2.3
4.0
-
1.7
1.4
2.2
% Removal
Prim.
_
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
0.7
-
-
-
-
30.2
4.3
-
-
13.7
_
Total
_
-
67.9
84.4
-
91.5
87.3
84.2
81.7
80.5
88.9
90.9
83.3
69.3
88.0
60.8
80.0
68.9
70.3
70.8
71.1
-
-
-
91.9
90.5
-
88.0
96.2
90.0
on

-------
                                           Table C-l.   Continued  NOVEMBER'S PIA NT OPERATIONAL DATA
L)
A
T
E
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
15
17
18
19
20
21
22
23
24
25
26
27
28
29
30
D
A
Y
Fr
Sa
Su
M
Tu
W
Th
Tr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Total Phosphorus
mg/1
Infl.
3.02
3.04
2.60
1.84
1.72
2.20
2.80
2.78
2.82
2.74
4.22
2.64
1.52
1.56
1.44
1.14
0.68
1.03
2.09
0.88
1.01
1.98
1.83
1.02
2.01
1.56
1.21
1.68
2.50
1.95
P.E.
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
2.05
0.90
1.14
1.67
1.79
1.05
1.63
1.94
0.98
1.65
2.08
1.69
S.E.
2.64
1.36
1.80
0.8.4
1.28
0.94
0.86
1.36
1.42
1.64
1.76
0.98
0.97
0.64
0.38
0.80
0.33
0.33
0.59
0.37
0.20
0.53
0.30
0.41
0.38
0.37
0.37
0.53
0.79
0.36
% Removal
Prim.
fc
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
1.9
Incr
in or
15.7
2.2
Incr
18.9
incr
19.0
1.8
16.8
13.3
Total
12.6
55.3
30.8
54.3
25.6
57.3
69.3
51.1
49.6
40.1
58.3
62.9
36.2
59.0
73.6
29.8
51.5
68.0
71.8
58.0
80.2
73.2
83.6
59.8
81.1
76.3
69.1
68.5
68.4
81.3
Soluble Phosphorus
mg/1
Infl.
1.64
1.04
1.08
0.92
0.86
1.26
1.62
1.64
1.62
1.56
2.82
1.26
0.60
0.40
0.60
0.40
0.12
0.50
0.85
0.06
0.55
0.02
-
0.51
0.86
1.48
0.22
0.94
0.97
1.21
P.E.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
0.97
0.17
0.90
1.11
-
0.47
0.98
1.24
0.23
0.86
1.20
1.05
S.E.
1.17
1.03
0.97
0.63
0.78
0.67
0.74
1.03
1.08
1.09
1.37
0.63
0.31
0.06
0.07
0.10
0.05
0.03
0.03
0.39
0.03
0.44
-
0.19
0.06
0.12
0.36
0.23
0.23
0.15
% Removal
Prim.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
incr
incr
incr
incr
-
7.8
Incr
16.2
incr
,8.5
incr
13.2
Total
28.7
0.9
10.2
31.5
9.3
46.6
54.3
37.2
33.3
30.1
51.4
50.0
48.3
85.0
88.3
75.0
58. 3
94.0
96.5
incr
94.5
56.9
-
62.7
93.3
92.0
incr
76.0
76.5
87.8
Total S.S.
mg/1
Infl.
116.0
76.0
152.0
120.0
164.0
94.0
70.6
152.0
152.0
52.0
88.0
108.0
162.0
136.0
68.0
42.0
26.0
32.0
184.0
184.0
76.0
40.0
72.0
45.0
61.0
82.0
42.0
48.0
58.0
89.3
P.E.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
84.0
152.0
82.0
41.0
42.0
32.0
53.0
70.0
26.0
20.0
46.0
78.6
S.E.
16.0
20.0
30.6
18.0
49.3
36.0
27.0
50.0
40.0
26.0
46.6
30.6
41.3
50.0
49.3
14.7
22.0
24.0
29.3
S6.0
16.0
12.0
3.5
11.5
16.5
20.5
56.0
12.0
25.5
39.0
% Removal
Prim.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
54.3
17.4
incr
incr
41.7
28.9
13.1
15.0
38.1
58.3
20.7
12.0
Total
86.2
73.7
79.9
85.0
69.9
61.7
61.8
67.1
73.7
48.8
47.0
71.7
74.5
63.2
27.5
65.0
15.4
25.0
84.1
69.6
78.9
70.0
95.1
74.4
73.0
75.0
Incr
75.0
56.0
56.3
Volatile S.S.
mg/1
Infl.
60.0
48.0
108.0
96.0
128.0
58.0
37.3
60.0
68.0
46.0
50.0
68.0
56.0
52.0
18.0
20.0
12.0
26.0
92.0
72.0
38.0
31.0
52.0
26.0
40.0
50.0
34.0
38.0
28.0
5.3
P.E.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
42.0
36.0
36.0
31.0
36.0
22.0
31.0
45.0
18.0
12.0
18.0
-
S.E.
1.3
2.0
22.6
18.0
38.6
20.0
13.0
8.0
21.3
25.3
16.0
17.3
25.3
2.0
9.3
1.3
12.0
23.0
17.3
26.0
8.5
6.5
10.0
6.0
10.0
8.5
46.0
8.0
11.5
13.0
pH
Infl.
7.66
7.72
7.78
7.86
-
7.71
7.85
7.60
7.75
7.92
7.82
7. 76
7.78
7.51
7.97
7.78
7.80
7.90
7.52
7.58
-
7.30
7.65
7.85
7.61
7.68
7.41
7.60
-
7.65
P.E.

-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
7.50
7.65
-
7.35
7.55
7.61
7.50
7.60
7.53
7.55
-
7.65
S.E.
7.93
7.83
7.89
7.82
-
7.86
7.88
7.70
7.75
7.80
7.84
7.70
7.80
7.83
8.01
7.71
7.76
7.72
7.41
7.32
-
7.35
7.60
7.61
7.42
7.61
7.49
7.50
-
7,60
NH3-N
Infl.

-
-
-
-
-
-
-
-
19.8
23.5
18.6
12.1
-
-
-
3.7
4.9
10.7
5.7
-
5.7
5.3
7.9
-
7.3
-
-
-
-
S.E.

-
-
-
_
-
-
-
-
18.2
25.8
21.2
18.0
-
-
-
5.6
5.8
17.8
5.2
-
5.0
4.8
11.9
-
-
6.1
-
-
-
oo

-------
                                              Table C-l.   Continued  NOVEMBER'S PLANT OPERATIONAL DATA
D
A
T
E
1
2
3
4
5
g
7
8
g
10
11
12
13
14
15
16
17
18
19
20
Ol
£l
7?
if tf
00
£l>
24
25
9 A
/D
27
28
OQ
£.7
30
D
A
Y
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
F/M
0.38
0.39
0.53
0.34
0.21
0.52
0.38
0.35
0.27
0.18
0.28
0.22
0.11
0.07
0.15
0.17
0.12
0.13
0.64
0.29
0.31

0.22
0.13
0.20
0.30

0.15
0.20
0.14
MLSS
mg/1
656
690
582
736
762
588
866
916
1,157
1,845
1,146
1,314
1,390
1,440
520
556
613
735
890
1,256
1,497

1,644
1,663
1,715
1,875
1 ,898
1,485
1,453
1,125
MLVSS
mg/1
528
524
426
530
578
444
608
654
736
1,440
876
956
970
1,000
367
325
331
403
538
680
817

852
940
979
1,107
1,102
966
910
605
Recycle
Flow
gpd
10,276
10,316
9,441
10,587
12,089
8,222

_
10,298
10,310
12,650
12,270
13,110
12,060
13,450
12,640
12,490
13,220
15,150
14,440
13,040
12,290
13,500
13,540
12,080
12,320
12,510
8,360
10,360
RAS
mg/1
2,587
1,300
1,530
1,540
1,590
930
2,545
3,685
2,920
4,560
2,700
3,830
3,775
2,253
223
1,577
1,278
1,633
3,189
3,315
5,162
-
7,850
2,998
6,107
4,605
3,974
6,146
4,211
1,750
RAS
Volatile
mg/1
2,024
980
1,180
1,135
1,215
760
1,805
2,725
2,010
3,435
1,967
2,789
2,610
1,547
150
935
750
1,039
1,983
1,806
2,861
-
3,570
1,728
3,528
2,688
2,439
3,893
2,456
963
Temp.
°C
18
16
17
15
14
14
15
15
15
14
16
15
14
11
8
10
10
10
12
12
10
11
12
12
10
12
11
10
10
10
FeCl3
Ib/day
_
-
-
-
-
-
0.624
0.990
1.039
1.904
2.015
2.717
1.855
2.178
2.299
2.415
2.420
1.901
1.683
1.980
1.668
2.127
1.966
1.717
1.591
1.647
0.651
Aeration
D.O.
Range
2.0 - 4.4
2.0 - 4.8
2.2 -4.2
3.4 - 6.3
2.4 - 4.8
1.6 - 5.8
1.2 - 5.6
1.6 - 5.8
2.8 - 4.0
1.9 - 6.5
1.2 - 4.2
2.4 - 4.4
1.2 - 4.8
2.6 - 5.4
3.8 - 7.6
4.8 - 8.6
4.0 - 7.3
1.8 - 4.6
1.8 - 3.7
2.2 - 4.6
2.4 - 6.6
1.5 - 4.6
1.8 - 4.6
2.4 - 5.0
1.8 - 4.2
2.0 - 5.0
2.2 - 5.4
1.5 - 5.0
1.2 - 5.3
3.2 - 5.0
Remarks
By-passing primary clarifier
Cut skimmings flow by 2/3
Recycle plugged, influent partially plugged
Influent pubp down 12 mid. to 8 AM
Recycle channel leaking - reclined
Inflow green 8 AM to 1 PM
Inflow green 8 AM to 1 PM

Start FeCla feed at 4 PM
Inflow colored at various times
Rebalanced effluent weir: Inflow pink 10 - 1 PM

Heavy snow
Heavy snow; Unmanned 3 PM - 11 PM


Switched back to primary clarifier
Slight chlorine residual in Inflow

Inflow colored at various times

Inflow green at 4 AM
Wasting and effluent lines frozen for 5 hours
Inflow green 8 AM - 9 PM
Wasted sludge: No samples for 8 AM
Unplugged inflow pump 4 PM
Inflow milky 1 PM - 7 PM
cn

-------
Table C-2.  DECEMBER'S PIANT OPERATIONAL DATA
D
A
T
E
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
D
A
Y
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Total C.O.D.
mg/1
Infl.
173,2
246.2
205.4
233.5
237.9
248.2
220.6
113.6
170,9
200.0
220.6
215.9
156.0
179.7
241.4
197.8
190.9
192.6
183.7
',24.8
P.E.
165.4
199.3
205.4
202.4
148.7
229.6
172.8
135.8
181,8
167,3
163.6
178.0
243,5
131,0
139.6
164,2
176,0
162,1
164.1
193,8
S.E.
43.3
66.4
65.9
66.9
59.5
55.6
58.8
87.8
65.5
72.3
68.5
49.2
57.1
56.2
45.3
44.8
48.7
27.0
50.8
50.4
% Removal
Prim.
4.5
19.0
0.0
13.3
37.5
7.5
21.7
incr
incr
16.4
25.6
17.6
incr
27.1
42.2
17.0
7.8
15.8
10.7
13.8
Total
75.0
73.0
67.9
71.3
75.0
77.5
73.3
22.8
61.7
63.9
68.9
77.2
63.4
68.7
81.2
77.4
74.5
86.0
72.3
77.6
Soluble C.O.D.
mg/1
Infl.
82.7
113.3
127.9
109.0
133.8
118.5
77.2
62.3
87.3
112.7
114.1
109.8
110.3
104.8
98.1
108.2
86.1
104.2
93.8
135.7
P.E.
78.7
109.4
124.0
109.0
111.5
103.7
73.5
69.6
105.5
101.8
106.5
94.7
110.3
67.4
79.2
89.6
82,4
84.7
89.9
108.5
S.E.
35.4
39.1
50.4
42. £
37.2
29.6
40.4
33.0
18.2
32.7
38.0
37.9
45.6
41.2
37.7
33.6
33.7
15.4
43.0
46.5
% Removal
Prim.
4.8
3.4
3.0
0.0
16.7
12.5
4.8
incr
incr
9.7
6.7
13.8
0.0
35.7
19.3
17.2
4.3
18.7
4.2
20.0
Total
57.2
65.5
60.6
60.7
72.2
75.0
47.7
47,0
79.2
71.0
66.7
65.5
58.7
60.7
61.6
68.9
60.9
85.2
54.2
65.7
Flow
103
gpd
17.95
22.97
25.51
17.44
24.57
21.58
28,78
37,44
26.95
24.68
24.46
25.42
25.24
22.37
23.37
25.56
32.32
24.76
28.80
23,78
Precp.
in.
0.10
0.89
0.00
0.00
0.00
0.00
0.10
0.05
0.05
0.00
0.08
0.00
0.00
0.00
0.28
0.33
0.24
0.03
0.15
0.00
Total B.O.D.
mg/1
Infl.
61.8
71.0
95.3
80.3
75.0
90.0
72.0
42.0
66.0
76.5
102.0
66.0
47.0
56.4
60.0
75.6
69.6
76.5
61.5
64.0
P.E.
52.5
61.8
70.2
71.3
69.5
72.0
60.0
25.2
72.0
68.0
71.0
69.0
66.0
46.5
55.2
67.0
53.0
70.8
52.8
73.2
S.E.
5.9
10.3
12.3
11.8
10.3
11.0
15.0
11.4
21.2
7.5
17.4
9.6
6.5
6.0
6.8
8.0
10.8
7.6
7.6
8.4
% Removal
Prim.
15.0
13.0
26.3
11.2
7.3
20.0
16.7
40.0
incr
11.1
30.4
incr
incr
17.6
8.0
11.4
23.9
/.5
14.1
incr
Total
90.5
85.5
87.1
85.3
86.3
87.8
79.2
72.9
67.9
90.2
82.9
85.5
86.2
89.4
88.7
89.4
84.5
90.1
87.6
86.9
Soluble B.O.D.
mg/1
Infl.
30.3
43.5
49.1
51.5
45.0
49.0
32.4
24.0
39.0
48.0
52.0
42.0
39.0
35.0
35.3
49.0
40.5
37.5
37.5
38.4
P.E.
16.8
41.6
45.5
46.9
45.5
49.0
29.5
24.6
40.0
44.0
50.0
39.0
41.0
34.5
34.2
40.5
36.0
34.0
36.0
39.0
S.E.
) .7
7.0
6,2
6.6
S.9
5.1
7.2
7.2
8.8
3.6
8.8
5.6
6.6
10.4
7.2
5.2
7.6
5.7
5.7
8.0
% Remova'
Mm.
44.6
4.4
7.3
8.9
incr
0.0
9.0
incr
incr
8.3
3.8
7.1
incr
1.4
2.5
17.3
11.1
9.3
4.0
incr
Total
94.4
83. 'J
87.4
87.2
86.9
89.6
77.8
70.0
77.4
92.5
83. 1
86. 7
83.1
70.3
79.6
89.4
8!. 2
84.8
34.8
79.2
21
22 END OF TEST RUN
23

-------
                                        Table C-2.   Continued  DECEMBER'S PLANT OPERATIONAL DATA
D
A
T
E
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
D
A
Y
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Total Phosphorus
mg/1
Infl.
2.22
2.27
2.42
2.39
2.90
2.90
1.12
1.05
2.94
2.28
2.39
2.07
2.08
1.82
2.58
2.07
1.55
1.85
1.85
2.19
P.E.
2.34
2.34
2.34
2.56
2.72
2.94
1.10
0.95
3.78
2.34
2.27
2.15
2.13
1.84
2.06
2.08
1.52
1.88
1.76
2.08
S.E.
0.708
0.922
-
0.680
0.660
0.756
0.384
0.454
0.910
0.552
1.240
0.505
0.413
0.280
0.390
0.490
0.330
0.260
0.275
0.425
% Removal
Prim.
incr
incr
1.7
Incr
6.2
incr
1.8
9.5
incr
incr
5.0
Incr
incr
incr
20.2
incr
1.9
incr
4.9
5.0
Total
68.1
59.4
-
71.5
77.2
73.9
65.7
56.8
69.0
75.8
48.1
75.6
80.1
84.6
84.9
76.3
78.7
85.9
85.1
80.6
Soluble Phosphorus
mg/1
Infl.
1.38
1.43
1.48
1.70
1.62
1.56
0.38
0.52
2.27
1.52
1.62
1.25
1.02
1.08
1.04
1.50
0.81
1.18
1.17
1.28
P.E.
1.30
1.25
1.46
1.48
1.68
0.92
0.41
0.58
3.44
1.48
1.38
1.18
1.02
0.88
1.27
1.42
0.72
1.05
1.02
1.18
S.E.
0.316
0.324
0.336
0.256
0.304
0.516
0.148
0.192
0.744
-
0.544
0.245
0.203
0.138
0.190
0.190
0.165
0.175
0.125
0.240
% Removal
Prim.
5.8
12.7
1.4
12.9
incr
41.0
incr
ncr
incr
2.6
14.8
5.6
0.0
18.5
incr
5.3
11.1
11.0
12.8
7.8
Total
77.1
77.3
77.3
84.9
81.2
66.9
61.1
63.1
67.2
-
66.4
80.4
80.1
87.2
81.7
b7.3
79.6
85.2
89.3
81.3
Total S.S
mg/1
Infl.
58.0
82.0
88.0
96.0
108.0
144.0
204.0
60.0
96.0
140.0
84.8
80.0
58.0
108.0
87.0
73.0
119.0
57.0
71.0
79.0
P.E.
57.0
63.0
60.0
86.0
76.0
86.0
176.0
50.6
100.0
80.0
68.6
80.0
83.0
48.0
61.0
52.0
107.0
49.0
67.0
67.0
S.E.
25.5
25.0
29.3
41.3
28.0
30.0
42.6
20.0
54.6
22.0
40.0
13.8
9.0
4.0
16.0
14.2
17.3
6.0
11.3
21.0
•
% Removal
Prim.
1.7
23.2
31.8
10.4
29.6
40.3
13.7
15.7
incr
42.9
19.1
-
incr
55.6
29.9
28.8
10.1
14.0
5.6
15.2
Total
56.0
69.5
66.7
57.0
74.1
79.2
79.1
66.7
43.1
84.3
52.8
82.8
84.5
96.3
81.6
80.5
85.5
89.5
84.1
73.4
Volatile S.S.

Infl.
42.0
60.0
20.0
82.0
56.0
116.0
92.0
42.0
52.0
12.0
60.0
51.0
24.0
54.0
65.0
62.0
70.0
38.0
34.0
67.0
mg/1
P.E.
37.0
48.0
18.0
74.0
44.0
64.0
72.0
34.6
48.0
16.0
46.0
50.0
45.0
26.6
46.0
45.0
63.0
31.0
32.0
52.0

S.E.
17.5
17.5
6.6
38.6
18.6
26.0
16.0
17.0
28.0
6.0
27.0
8.7
3.0
0.5
13.5
10.2
16.0
3.0
2.0
19.0
pH
Infl.
7.98
7.80
7.90
7.86
7.82
8.17
7.96
7.83
7.70
7.92
-
-
7.55
7.48
7.90
7.50
7.70
7.60
7.50
7.70
P.E.
7.73
7.88
7.80
7. 72
7.79
7.59
7.79
7.67
7.75
7.89
-
-
7.50
7.59
7. 72
7.50
7.65
7.70
7.40
7.80
S.E.
7.70
7.61
7.50
7.54
7.68
7.77
7. 52
7.56
7.50
7.82
-
-
7.65
7.54
7.60
7.55
7.40
7.50
7.35
7.70
NH3-N
Infl.
_
-
-
-
10.8
12.0
9.7
4.9
6.9
12.8
13.3
7.8
6.2
-
8.0
7.5
6.8
7.4
7.3
10.7
S.E.
-
-
-
-
10.0
10. n
10.3
6.6
6.8
10.6
14.9
8.1
5.8
-
9.0
7.8
7.5
6.2
6.6
9.8
21
22
23
END  OF  TEST RUN

-------
                                           Table C-2.   Continued  DECEMBER'S PLANT OPERATIONAL DATA
D
A
T
E
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
D
A
Y
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr
Sa
Su
M
Tu
W
Th
Fr

F/M
0.52
0.72
0.62
0.40
0.53
0.50
0.58
0.31
0.73
0.57
0.52
0.50
0.52
0.46
0.52
0.58
0.72
0.62
0.52
0.61

MLSS
mg/1
730
744
933
1,070
1,047
1,009
1,078
1,100
1,137
1,197
1,190
1,211
1,159
845
870
925
887
1,068
1,113
983

MLVSS
mg/1
423
459
666
717
739
723
691
702
613
681
771
806
741
527
579
681
549
655
673
661

Recycle
Flow
gpd
10,380
14,720
14,720
11,390
8,000
8,340
11,180
12,730
6,740
6,710
6,320
6,920
6,910
7,000
7,040
7,750
9,730
7,000
9,940
7,680

RAS
mg/1
1,378
1,515
2,009
2,205
2,780
3,723
4,775
4,297
5,355
5,355
5,441
5,057
4,213
4,320
4,023
2,485
2,938
3,549
3,332
4,176

RAS
Volatile
mg/1
808
1,043
1,468
1,579
1,874
2,665
3,216
2,871
2,975
2,994
3,310
3,368
2,707
2,855
2,743
1,813
1,806
2,154
2,001
2,769

SVI
.
-
-
-
_
-
-
-
100
97
94
107
-
134
116
117
98
98
116

Temp
°C
10
10
11
10
11
11
12
9
8
9
11
11
11
11
10
10
9
8
10
9
9
FeCl3
Ib/day
1.402
1.682
2.022
1.874
1.565
1.809
2.384
3.145
2 244
2.067
2.109
2.265
2.310
2.197
2.300
2.487
3 .031
2.363
2.616
2.234

Aeration
D.O.
Range
2.2 - 4.2
2.8 - 6.4
1.2 - 5.0
2.0 - 6.0
1.8-4.4
1.4 - 5.0
2.4 - 5.9
1.6 - 6.2
1.0 - 5.2
2.4 - 6.1
1.2 - 4.8
1.4 - 4.4
1.8 - 5.0
1.7 - 7.4
1.8 - 5.8
1.8 - 7.0
1.2-8.8
1.6 - 6.6
2.9 - 5.2
1.4 - 5.2
3.8
Remarks

Influent colored at times

Influent pink 10 AM - 1 PM
FeClg addition at two points
Inflow red 12 PM to 4 AM


All lines frozen 9 PM - 6 AM
Primary sludge line frozen
Thawed primary sludge valve SAM

Started polymer addition 6 PM


Influent colored at various times
Gasoline in influent- Blue color 3-7 AM
Influent blue 1 - 2 PM

Influent colored at various times
Shut down at 9 AM
22 END OF TEST RUN
h-*
0\
N)
      23

-------
Table C-3  DAILY TRACE ELEMENT CONCENTRATIONS
Day
November 18
Inflow
S.E.
% Removal
November 19
Inflow
S.E.
% Removal
November 20
Inflow
S.E.
% Removal
November 21
Inflow
S.E.
% Removal
November 22
Inflow
S.E.
% Removal
November 23
Inflow
S.E.
% Removal
Concentration - mg/1
As

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cd

0.007
0.010
incr

0.20
0.010
50.0

0.010
0.040
incr

0.010
0.007
30.0

0.020
0.020
0.0

0.007
0.010
incr
Cr-T

0.10
0.04
60.0

0.21
0.07
66.7

0.10
0.07
30.0

0.19
0.08
57.9

0.27
0.12
55.6

0.18
0.04
77.8
Cr-hex

0.02
< 0.01
50.0

0.07
<0.01
85.7

0.03
<0.01
66.7

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cu

0.08
0.03
62.5

0.02
0.14
incr

0.15
0.04
73.3

0.08
0.04
50.0

0.09
0.06
33.3

0.10
0.05
50.0
Pb

0.050
0.049
2.0

0.500
0.025
95.0

0.250
0.025
90.0

0.033
0.02
39.4

0.045
0.024
46.7

0.050
0.033
34.0
Ha

0.0011
0.0017
incr

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

O.0010
<0.0010
0.0

<0.0010
0.0020
incr

0.0010
0.0071
incr
Ni

0.04
0.04
0.0

0.02
0.05
incr

0.03
0.03
0.0

0.05
0.04
20.0

0.05
0.05
0.0

0.10
0.06
40.0
Zn

0.65
0.43
33.8

0.69
0.30
56.5

1.41
0.65
53.9

0.74
0.16
78.4

1.06
0.90
15.1

0.50
0.45
10.0
CN

0.033
0.054
incr

0.048
0.057
incr

0.040
0.070
incr

0.070
0.030
57.1

0.050
0.040
20.0

0.030
0.050
incr

-------
                     Table C-3  Continued  DAILY TRACE ELEMENT CONCENTRATIONS
         Day
   November 24
       Inflow
       S.E.
       % Removal
   November 25
       Inflow
       S.E.
       % Removal
^  November 26
o\      Inflow
"*      S.E.
       % Removal
   November 27
       Inflow
       S.E.
       % Removal
   November 28
       Inflow
       S.E.
       % Removal
   November 29
       Inflow
       S.E.
       % Removal

I
L
L
L
L
L

As
<0.01
<0.01
0.0
<0.01
<0.01
0.0
<0.01
<0.01
0.0
<0.01
<0.01
0.0
<0.01
<0.01
0.0
<0.01
<0.01
0.0
Cd
0.003
0.007
incr
0.020
0.010
50.0
0.070
0.009
87.1
0.030
0.020
33.3
0.050
0.020
60.0
0.010
0.020
incr
Concentration - mg/1
Cr-T
0.03
0.03
0.0
0.30
0.11
63.3
0.30
0.10
66.7
0.49
0.25
49.0
0.03
0.06
incr
0.09
0.10
.ncr
Cr-hex
<0.01
<0.01
0.0
<0.01
0.01
incr
<0.01
0.01
incr
<0.01
<0.01
0.0
<0.01
<0.01
0.0
0.01
0.01
0.0
Cu
0.05
0.04
20.0
0.16
0.05
68.8
0.13
0.04
69.2
0.14
0.07
50.0
0.26
0.07
73.1
0.12
0.07
41.7
Pb
0.035
0.075
incr
0.077
0.024
68.8
0.140
0.013
90.7
0.077
0.060
22.1
0.042
0.022
47.6
0.031
0.033
incr
Hg
0.0250
0.0250
incr
<0.0010
<0.0010
0.0
<0.0010
<0.0010
0.0
0.0010
0.0030
incr
<0.0010
<0.0010
0.0
0.0027
0.0063
incr
Ni
0.01
0.03
incr
0.09
0.06
33.3
0.09
0.06
33.3
<0.01
0.07
incr
<0.01
<0.01
0.0
0.04
0.05
incr
Zn
0.16
0.18
incr
0.45
0.26
42.2
0.35
0.19
45.7
0.32
0.22
31.3
0.11
0.18
incr
0.54
0.22
59.3
CN

_
-
0.036
0.035
2.7
0.047
0.025
47.3
0.053
0.048
9.4
0.005
0.014
incr
0.054
0.0481
11.9

-------
Table O3 Continued DAILY TRACE ELEMENT CONCENTRATIONS
Day
November 30
Inflow
S.E.
% Removal
December 1
Inflow
S.E.
% Removal
December 2
Inflow
S.E.
% Removal
December 3
Inflow
S.E.
% Removal
December 4
Inflow
S.E.
% Removal
December 5
Inflow
S.E.
% Removal
Concentration - mg/1
As

-
-
-

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cd

-
-
-

0.009
0.010
incr

0.014
0.012
14.3

0.016
0.009
43.8

0.040
0.012
70.0

0.030
0.009
70.0
Cr-T

-
-
-

0.08
0.06
25.0

0.27
0.08
70.4

0.45
0.10
77.8

0.42
0.12
71.4

0.35
0.10
71.4
Cr-hex

-
-
-

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.03
<0.01
0.0

<0.01
<0.01
0.0
Cu

-
-
-

0.06
0.04
33.3

0.12
0.05
58.3

0.17
0.05
70.6

0.14
0.05
64.3

0.14
0.04
71.4
Pb

-
-
-

0.020
0.021
incr

0.050
0.023
54.0

0.100
0.019
81.0

0.095
0.023
75.8

0.082
0.015
81.7
Hg

-
-
-

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0
NI

-
-
-

0.02
0.03
incr

< 0.01
< 0.01
0.0

0.01
<0.01
deer

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Zn

-
-
-

0.09
0.11
incr

0.055
0.098
incr

0.029
0.021
27.6

0.034
0.019
44.1

0.029
0.015
48.3
CN

-
-
-

0.0630
0.0495
21.4

0.0755
0.0550
27.2

0.0820
0.0790
3.7

0.0590
0.0510
13.6

0.0420
0.0670
incr

-------
Table  C-3  Continued DAILY TRACE ELEMENT CONCENTRATIONS
Day
December 6
Inflow
S.E.
% Removal
December 7
Inflow
S.E.
% Removal
December 8
Inflow
S.E.
% Removal
December 9
Inflow
S.E.
% Removal
December 10
Inflow
S.E.
% Removal
December 11
Inflow
S.E.
% Removal
Concentration - mg/1
As

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cd

0.044
0.012
72.7

0.011
0.014
incr

0.007
0.010
Incr

0.006
0.007
Incr

0.010
0.007
30.0

0.013
0.011
15.4
Cr-T

0.42
0.09
78.6

0.354
0.083
76.6

0.034
0.037
incr

0.12
0.15
incr

0.18
0.06
66.7

0.19
0.12
36.8
Cr-hex

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cu

0.30
0.06
80.0

0.14
0.07
50.0

0.08
0.04
50.0

0.16
0.03
81.3

0.22
0.02
90.9

0.10
0.16
incr
Pb

0.115
0.014
87.8

0.154
0.018
88.3

0.131
0.032
75.6

0.08
0.04
50.0

0.10
0.01
90.0

0.08
0.04
50.0
Hg

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

<0.0010
<0.0010
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0
Ni

0.02
0.01
50.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

0.12
0.10
16.7

0.08
0.10
incr

0.09
0.^8
11.1
Zn

0.063
0.018
71.4

0.037
0.023
37.8

0,018
0.021
incr

0.46
0.20
56.5

0.25
0.13
48.0

0.30
0.18
40.0
CN

0.0620
0.0355
42.7

0.0665
0.058
12.8

0.044
0.020
54.5

0.0040
0.0051
incr

0.0950
0.035
63.2

0.0620
0.1880
incr

-------
                     'Table C-3 Continued DAILY TRACE ELEMENT CONCENTRATIONS
Day
December 12
Inflow
S.E.
% Removal
December 13 ;
Inflow
S.E.
% Removal]
December 14
Inflow !
S.E. !
% Removal
December 15
Inflow '
S.E. i
% RemovaJ
December 16
Inflow
S.E.
% Removal
December 17
Inflow ;
S.E.
% Removal
Concentration - mg/1
As

< 0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cd

0.011
0.008
27.3

0.013
0.007
46.2

0.009
0.005
44.4

0.007
0.006
14.3

0.014
0.007
50.0

0.011
0.008
27.3
Cr-T

0.14
0.06
57.1

0.19
0.08
57.9

0.09
0.05
44.4

0.03
0.02
33.3

0.20
0.06
70.0

0.13
0.06
53.8
Cr-hex

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cu

0.14
0.03
78.6

0.09
0.02
77. 8

0.05
0.01
80.0

0.08
0.01
87.5

0.15
0.06
60.0

0.13
0.06
53.8
Pb

0.11
0.01
90.9

0.11
0.01
90.9

0.05
0.02
60.0

0.05
0.02
60.0

0.11
0.02
81.8

0.15
0.03
80.0
Hg

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0
Ni

0.17
0.13
23.5

0.09
0.08
11.1

0.04
0.08
incr

0.05
0.03
40.0

0.07
0.04
42.9

0.09
0.10
incr
Zn

0.27
0.15
44.4

0.34
0.15
55.9

0.22
0.16
27.3

0.17
0.13
23.5

0.31
0.16
48.4

0.33
0.16
51.5
CN

0.0490
0.0500
incr

0.0370
0.0270
27.0

0.0425
0.0405
4.7

0.0390
0.0220
43.6

0.0425
0.0345
18.8

0.0390
0.0210
46.2
ON

-------
Table  C-3  Continued DAILY TRACE ELEMENT CONCENTRATIONS
Day
December 18
Inflow
S.E.
% Removal
December 19
Inflow
S.E.
% Removal
M December 20
» Inflow
S.E.
% Removal

As

<0.01
< 0.01
0.0

< 0.01
<0.01
0.0

<0.01
<0.01
0.0
Concentration - mg/1
Cd

0.013
0.01
23.1

0.012
0.006
50.0

0.042
0.014
66.7
Cr-T

0.13
0.04
69.2

0.30
0.02
93.3

0.29
0.06
79.3
Cr-hex

<0.01
<0.01
0.0

<0.01
<0.01
0.0

<0.01
<0.01
0.0
Cu

0.10
0.06
40.0

0.34
0.06
82.4

0.30
0.09
70.0
Pb

0.08
0.02
75.0

0.08
0.02
75.0

0.08
0.02
75.0
Hg

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0

<0.0020
<0.0020
0.0
Ni

0.05
0.05
0.0

0.11
0.05
54.5

0.06
0.06
0.0
7n

0.21
0.15
28.6

0.28
0.14
50.0

0.32
0.16
50.0
CN

0.0480
0.0280
41.7

0.0360
0.0320
11.1

0.1310
0.1130
13.7

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                         Table C-4 WASTE PRIMARY SLUDGE CHARACTERISTICS
Parameter
Arsenic
Cadmium
Chromium-T
Chromium-hex
Copper
Cyanide
Lead
Mercury
Nickel
Zinc
T.S.S.
T.V.S.S.
Phosphorus-T
Discharge-gal.
Concentration - m
11/18 - 11/24
<0.01
0.090
7.60
<0.01
0.02
2.10
1.70
0.010
14.50
19.00
13,951
8,829
-
42.3
11/25 - 12/1
<0.01
0.320
5.60
<0.01
2.32
2.50
3.10
0.010
0.31
5.72
13,899
8,512
242.1
48.8
12/2 - 12/8
<0.01
0.670
12.90
<0.01
8.54
1.64
12.00
0.080
1.29
2.10
14,496
9,885
186.5
55.4
/I
12/9 - 12/15
<0.01
0.718
10.00
<0.01
8.10
1.49
15.00
0.025
1.60
26.50
16,897
10,809
236.2
61.8
12/16 - 12/20
<0.01
0.454
6.00
<0.01
6.26
1.18
9.00
<0.002
1.50
18.30
8,572
5,814
122.2
69.8
vo

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Table C-5  WASTE SECONDARY SLUDGE CHARACTERISTICS
Parameter
Arsenic
Cadmium
Chromium-T
Chromium -hex
Copper
^ Cyanide
5
Lead
Mercury
Nickel
Zinc
T.S.S.
T.V.S.S.
Phosphorus -T
Discharge-gal.
Concentration - mg/1
11/18 - 11/24




2
o
M
>
CO
H
M
d





11/25 - 12/1
<0.01
0.750
18.80
<0.01
12.00
4.00
9.50
0.027
1.50
14.00
3,835
2,318
78.8
980.0
12/2 - 12/8
<0.01
0.357
9.55
<0.03
3.58
2.53
5.60
0.025
0.70
1.60
4,027
2,742
84.5
537.5
12/9 - 12/15
<0.01
0.274
7.00
<0.01
4.33
2.09
8.00
2.5
1.00
11.40
4,833
2,997
132.9
685.5
12/16 - 12/20
<0.01
0.192
4.00
<0.01
3.81
1.06
6.00
<0.002
1.30
6.74
3,284
2,099
73.7
796.7

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                                                                   CONCENTRATION
                                                                   % REMOVAL
                                   -80
                                                                                                      O
                                                                                                      i
19 20 21  2? 23 24 25 26 27 28 29 30  I   2  3 4  5  6  7  8
           NOVEMBER
                             Figure  C-l  Daily  Cadmium  Variation
9  10 II  12
DECEMBER
13  14  15 16 17 18 19 20

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                                                           CONCENTRATION
                                                           % REMOVAL
                                                                                                  -100
                                                                                                    80
                                                                                                       1
18  19  20 21  22 23 24 25 26 27 28 29 30 I   2  3  4  5  6   7  8  9  10  11  12  13  14 15  16  17 18 19 20
              NOVEMBER                                          DECEMBER
                                 Figure  C-2 Doily Chromium Variation

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                                                                                                          -100
          CONCENTRATION
          % REMOVAL
04
                                                                                                          -80
                                                                                                          V60

                                                                                                          -40
                                                                                                          -20
IS  fo 20 21  2£ 23
2C Jifa 27 ?.& 29
                                               I   2  34  5  C  7  8
                    NOVEMBER
   IO  II  12  17-  14 lf» It  17  It.  lb»
DECEMBER
                                        Figure C~3 Oiily '-niper  Variation

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      .14
      J2
      .10 —
   r
   uf  .08
   Q



J


•^ z  nA
-P* £  -06
      .04
      .02
                                                                         CONCENTRATION

                                                                          % REMOVAL
             IS l» 2u ill  <£ kS 24 SiG i;C 27 28 2y  30 I  2  3  4  5  G  7  8  9  10 11   12  13  14 15  1C 17 18


                           NOVEMBER                                          DECEMBER

                                              Figure  C-4 Doily  Cyanide  Variation

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      0.
      0.-
   £0.3
   o
   <
   UJ
en
      O.2
      0.1
                                         CONCENTRATION


                                         %  REMOVAL
— 100
                                                                                                                      UJ
                                                                                                                      o:
-20
            18  19 20 21  22 23 24 25 26 27 28 29 30 I   2  3  4  5  6  7  8  9  10 11   12  13  14  15  16 17 18 19 20

                          NOVEMBER                                          DECEMBER

                                              Figure C-5  Daily  Lead   Variation

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                                                                                               -70
                                                                                               -60
                                                                                               -50
                                                                                              -40
CONCENTRATION

%  REMOVAL
                                                                                              -30
                                                                                              -Jt-20
                                          I
                                          i
18  19 20 21  22 2? 24 25

              NOVEMBER
                        27 28 29 ?O  I
                             Figure C~6  Daily  Nickel  Variation
8  9  10  ||  12  I?  14  1C  IG  17 16  19 2O

   DECEMBER

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1.4,—

                                                                CONCENTRATION
                                                                %  REMOVAL
                                                                                                     -100
                                                                                                     -80
     18  19 20 21  22 23 24 25 26 27 28 29 30 I  2  3  4  5  6  7  8  9  10  11  12  13  14  15  16  17  18 19 20
                   NOVEMBER                                        DECEMBER
                                     Figure  C-7 Daily  Zinc \toriation

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                                    TECHNICAL REPORT DATA
                             It lease read ImUructioiis on the reverse before completing!
    EPA-600/2-77-018
  4. TITLE AND SUBTITLE
   Industrial Waste  and Pretreatment in  the
   Buffalo Municipal  System
                                                         3. RECIPIENT'S ACCESSION-NO.
                                                         5. REPORT DATE

                                                            January  1977
                                                            . PERFORMING ORGANIZATION CODE
   Kenneth  Peck  and  John  C.  Horton,  Jr.
                                                           8. PERFORMING ORGANIZATION REPORT NO.
  9. PERFORMING ORGANIZATION NAME AND ADDRESS

   McPhee,  Smith,  Posenstein Engineers
   625  Delaware  Avenue
   Buffalo,  New  York   14202
                                                         10. PROGRAM ELEMENT NO.

                                                          1BB610
                                                         11. CONTRACT/GRANT NO.

                                                          R803005
  12 SPONSORING AGENCY NAME AND ADDRESS Office Uf  ,^u
   U.S. EPA - Robert S. Kerr Environmental Research
   Laboratory, P.O. Box 1198, Ada, Oklahoma  74820
                                                         13. TYPE OF REPORT AND PERIOD COVERED
                                                          Final - 4/74-6/76
                                                           14. SPONSORING AGENCY CODE


                                                            EPA-ORD
  15. SUPPLEMENTARY NOTES
  16. ABSTRACT
                                                                  •  A  * -  -,
                                                                       tri&1  ** domestic
      The requirements and affects of the combined treatment
 wastewaters were investigated for the Buffalo Sewer Authoril
      A  comprehensive industrial waste survey was performed
 background information on industrial discharges   This mimi^ ,n-*i,   «.   •-,',-,
 on  the  sewerage system provided the data nece^rv t« ^^   •  }th material balances
 and cost recovery programs.               necessary to develop industrial waste control
      The industrial waste control program for Buffalo -inrinri^    •   j
 lations  coupled with a permit system and monitoring prograrf   ™     ^^ U5G
      A combination of ad valorem tax and wastewater servir^'rV,-,™*   u   j
 strength and volume were used to recover the cost of treatment   A '       °n WaSte
 tion  of  the cost recovery and industrial waste control proerams  onth^
 users was performed.                                    i^Mcuiib  on tne
     A 95 000_liter/day activated sludge pilot study was conducted to
 affects  that industrial users  will have on the treatment processes
     Three potential  sludge disposal  options (soil conditioning   landfill and co dis-
posal with refuse) were investigated  for the disposal of th^  «I,,H™        ^ 5   u
 combined treatment of industrial  and  domestic Sewater In Buffalo.8         ^
 17.
                  DESCRIPTORS
                               KEY WORDS AND DOCUMENT ANALYSIS
                         ——^—^—————.—-^^_^_
  Activated Sludge, *Sewage Treatment,
  *Sludge Disposal, *Sludge Treatment,
  *Adimmstrative Agencies, *Cost Sharing
13. DISTRIBUTION STATEMENT


  RELEASE TO PUBLIC
EPA Form 2220-1 (9-73)
                                           b.lDENTIFIERS/OPEN ENDED TERMS

                                            Combined Industrial/
                                            Municipal, *Joint Treat-
                                            ment, *Pretreatment,
                                            Buffalo, NY
                                           19- SECURITY CLASS (This Re portI
                                             UNCLASSIFIED
c. COSATI Field/Group

  05D
  06A
  06C
21. NO. OF PAGES
     184
 U.S. Government Printing Office: 1977-778-489/116 Region 8

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