EPA-600/2-77-023b
February 1977
Environmental Protection Technology Series
                  INDUSTRIAL  PROCESS  PROFILES  FOR
                     ENVIRONMENTAL  USE:  Chapter  2.
                                  Oil  and Gas  Production
                                                    Industry
                                   Industrial Environmental Research Laboratory
                                        Office of Research and Development
                                        U.S. Environmental Protection Agency
                                                Cincinnati, Ohio 45268

-------
                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have  been grouped  into five series. These five  broad
categories were established to facilitate further development and application of
environmental technology. Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related  fields.
The five series are:
     1.    Environmental Health Effects Research
     2.    Environmental Protection Technology
     3.    Ecological Research
     4.    Environmental Monitoring
     5.    Socioeconomic Environmental Studies

This report  has  been  assigned  to the ENVIRONMENTAL PROTECTION
TECHNOLOGY series. This series describes research performed to develop and
demonstrate  instrumentation, equipment, and methodology to repair or prevent
environmental degradation from point and non-point sources of pollution. This
work provides the new  or improved technology  required for the control and
treatment of pollution sources to meet environmental quality standards.
This document is available to the public through the National Technical Informa-
tion  Service, Springfield, Virginia 22161.

-------
                                            EPA-600/2-77-023b
                                            February  1977
        INDUSTRIAL PROCESS PROFILES

           FOR ENVIRONMENTAL USE

                  CHAPTER 2

      OIL AND GAS PRODUCTION INDUSTRY
                     by

             Glynda E. Wilkins
            Radian Corporation
           Austin, Texas  78766
          Contract NO.  68-02-1319
              Project Officer
               Alfred B.  Craig
   Metals and Inorganic Chemicals Branch
Industrial Environmental  Research Laboratory
           Cincinnati,  Ohio   45268
INDUSTRIAL ENVIRONMENTAL RESEARCH LABORATORY
     OFFICE OF RESEARCH AND DEVELOPMENT
    U.S.  ENVIRONMENTAL PROTECTION AGENCY
           CINCINNATI, OHIO  45268

-------
                                 DISCLAIMER

     This report has been reviewed by the Industrial  Environmental  Research
Laboratory - Cincinnati, U.S. Environmental Protection Agency, and  approved
for publication.  Approval does not signify that the contents necessarily
reflect the views and policies of the U.S. Environmental Protection Agency,
nor does mention of trade names or commercial products constitute endorsement
or recommendation for use.

-------
                               ACKNOWLEDGEMENTS
This chapter was prepared for EPA by Radian Corporation under Contract
No. 68-02-1319, Task 42.  Glynda E. Wilkins was the author.  Significant
contributions were also made by Tommy D. Raye, Larry D. Short, and
Teresa Sipes.  Program administration was directed by Eugene C. Cavanaugh,

Helpful  review comments from James H. Gary were received and incorporated
into this chapter.
                                     ill

-------
                             TABLE OF CONTENTS
                                 CHAPTER 2
                                                                       Page
INDUSTRY DESCRIPTION.  .... 	     1
    Products	     3
    Companies 	     3
    Environmental  Impact	     4
    Bibliography	     5

INDUSTRY ANALYSIS  .....  	     6
    Exploration and Site Preparation. .  	     7
        Process No. 1.  Exploration ..... 	     8
        Process No. 2.  Site Preparation	    10
    Well Drilling  and Completion	    12
        Process No. 3.  Drilling	    13
        Process No. 4.  Mud Circulation	    16
        Process No. 5.  Format Evaluation 	    19
        Process No. 6.  Well Completion	    21
    Crude Processing	    24
        Process No. 7.  Water Removal	    25
        Process No. 8.  Gas-Oil Separation	    28
        Process No. 9.  Crude Storage	    30
    Natural Gas Processing	    32
        Process No. 10.  Liquid Hydrocarbon Recovery	    34
        Process No. 11.  Acid Gas Removal	    37
        Process No. 12.  Sulfur Recovery	    39
        Process No. 13.  Dehydration	    41
        Process No. 14.  Production Separation	    43
        Process No. 15.  LPG Storage	    46
        Process No. 16.  Gasoline Storage 	    48

-------
                      TABLE OF CONTENTS (Cont.)
                                                                 Page
Secondary and Tertiary Recovery Techniques	.  . 50
    Process No. 17.  Displacement	 51
    Process No. 18.  Fracturing	53
    Process No. 19.  Acid Treatment	  . 55
    Process No. 20.  Thermal Treatment	57
Appendix A - Characteristics of U. S. Crude Oils	59
Appendix B - Geographical  Location of Oil and Gas Production
  Activities	79
Appendix C - Partial  Listing  of Domestic  Producers	99
Appendix D - Materials  for Drilling  Fluid Systems	115
                                  vi

-------
                            LIST OF FIGURES



                              CHAPTER 2
1       The Oil and Gas Production Industry ............    2





2       Crude Processing ................             24





3       Natural Gas Processing ...............         33
                                   vi i

-------
                               LIST OF TABLES
                                CHAPTER 2

 Tab1e                                                                  Page
   1       Yearly  Volumes of Acids Used for Well Treatment	   22

   2       Disposition of Waste  Brine  	   26

   3       Hydrocarbon Emission  Factors for Crude Storage 	   30

   4       Hydrocarbon Emission  Factors for Gasoline Storage	   48

 A-l       Properties of United  States Crude Oils . .	   60

 A-2       Trace Element Content of United States Crude Oils.  .....   67

 A-3       Sulfur  and Nitrogen Content of the Giant U. S. Oil  Fields. .   72

 B-l       Production of Crude Oil and Lease Condensate by
           States, 1973	   30

 B-2       Production of Natural Gas by States, 1973	   82

 B-3       Location of Large Domestic Oilfields 	   84

 B-4       Natural  Gas Processing Plants  in the United States,
           January, 1972	  90

 B-5       Wells Drilled in the U. S	  97

C-l      Partial  Listing of Domestic  Producers	100

D-l      Materials  for  Drilling Fluid Systems  	  ....  116

-------
                     OIL AND GAS PRODUCTION INDUSTRY


INDUSTRY DESCRIPTION

The oil and gas production industry is involved in locating  and  retrieving
oil and gas from underground formations and preparing  the  well streams  for
use by consumers or refiners.   Production activities begin with  exploration
and end with storage or sales.

The industry has been divided into  five segments for consideration.

       (1)  Exploration and Site Preparation - This segment  includes
            those operations necessary for selection and preparation
            of a drilling site.

       (2)  Drilling - The drilling segment is comprised of  all
            operations involved in  digging a well  and  preparing
            it for production.

       (3)  Crude Processing -  Several process modules are described
            for preparing crude for refinery use.

       (4)  Natural Gas Processing  - This segment includes widely
            used processes for  preparing natural gas for sales.

       (5)  Secondary or Tertiary Recovery - Methods for stimulating
            well production are included in this segment.

Figure 1 is a schematic representation of the industry segments  and their
i nterrelationshi ps.

Process descriptions have been  prepared for all necessary operations
involved in each segment, but flowsheets were deemed appropriate in only
two segments:  Crude Processing and Natural Gas Processing.

The petroleum production industry is very large and diverse.  On December
31, 1973, there were 497,378 producing oil wells and 124,168 producing  gas
wells in the U.S.  Industry figures indicated that 1,460,000 cubic meters
(9,209,000 barrels) of crude and lease condensate and  1,867  million cubic
meters (65,940 million cubic feet)  of natural  gas  were produced  daily.  The
drilling segment of the industry completed 33,373 oil  wells, gas wells, dry
holes, and service wells in 1974.  The entire industry employed  291,900
people in 1974.

Crude oil and natural gas are produced in 32 states-of the U.S., but
Louisiana, Texas, California, and Oklahoma accounted for 79  percent of  the
domestic crude production in 1973.   Of the domestic gas production for  1973,
Louisiana and Texas accounted for 74 percent.   Drilling activities in 1974
were centered in California, Louisiana, Kansas, Oklahoma,  and Texas with 64
percent of the total wells drilled  in those states. Appendix B  contains
several correlations of production  data with geographical  location.   Included
are tables of production by state;  gas plants, locations and throughput;
locations of the largest oil fields in the U.S.; and drilling data presented
by state.

                                     1

-------
   EXPLORATION
       AND
SITE  PREPARATION
DRILLING
                                                                             CRUDE
                                                                           PROCESSING
                                                                               i
SECONDARY
    OR
 TERTIARY
RECOVERY
                                                                                I
                                                                          NATURAL GAS
                                                                           PROCESSING

-------
The high growth trends established by the petroleum industry  in  the late
1960's and early 1970's have been interrupted and  are  still fluctuating.
Although predicting the future at this time is a difficult  task,  it appears
that for the near future U.  S. crude production will be  declining 2 to  3%
yearly while domestic petroleum demands and refining capacity will be
increasing 2 to 3%.  Natural gas production became almost constant in the
1970's, and the trend in gas processing has been toward  fewer processing
facilities with larger capacities.  Despite staggering costs  involved in
drilling wells, drilling operations have seen a sharp  increase  since 1971.
The limiting factor in drilling activities in the  next few  years is expected
to be the availability of rotary rigs.
Products

Crude oil is composed chiefly of hydrocarbons (paraffins,  naphthenes,  and
aromatics) in a typical carbon to hydrogen ratio between 6 and 8  together
with small amounts of trace elements and organic compounds containing  sulfur,
nitrogen, and oxygen.  The appearance and consistency of crude is determined
by the molecular types and sizes of hydrocarbon present.  Common  colors  are
green, brown, black, and occasionally light yellow.   Specific gravities  are
usually 0.80 to 0.95; viscosities of most crudes range from 0.023 to 0.23
stokes at 38°C.  Appendix A contains chemical analyses and physical  proper-
ties of some domestic crude productions.  A typical  domestic crude contains
83-85% carbon, 11-14% hydrogen, 0.05-2% sulfur, 0.1-2% nitrogen and 0.2%
oxygen.


Natural  gas is about 95% saturated hydrocarbons.  The principal  hydrocarbon
is methane.  Also present, in decreasing proportions, are ethane, propane,
butanes, pentanes, hexanes, and heptanes.  The remaining 5% is usually
nitrogen, carbon dioxide, and sometimes hydrogen sulfide and helium.  After
being processed to remove the natural gas liquids, the natural gas becomes
dry natural gas and consists chiefly of methane.  The heavier hydrocarbons
are separated and/or liquefied to become ethane, propane (LPG), butanes,
and natural gasoline.


Companies

Some of  the companies  involved in oil production engage in only one facet  of
the industry and are known as nonintegrated companies.  Those companies  that
are involved in all phases of the petroleum industry are called integrated
companies.  In between are the semi-integrated companies that engage in  two
or more  types of operation.

Another  often  used  classification system is  division  into two classes:
majors and  independents.   The differentiation  is  rather vague, so that a
strict definition  is  impossible.  Most  independents are of modest resources
and are  nonintegrated.   There are some  integrated companies with  large
international  holdings that  consider themselves  independents, however.

-------
The  independents are extremely important to oil and gas production, as they
are  responsible for drilling nearly 80 percent of the producing, domestic wells.

A list of oil and gas producers proved unavailable and impractical, as there
are  over 9,000 crude oil producers alone.  To add to the problem, the produc-
tion industry is very fluid; companies appear and disappear rapidly due to
mergers and acquisitions.  Appendix C contains a listing of integrated companies
and  some of the large independents in the U. S. with production data (when
available) and office locations.

Environmental Impact

The  major waste streams encountered in the oil and gas production industry
contain hydrocarbons, oily brine, sulfides and other sulfur compounds  and
glycols.

Blowouts during drilling operations may cause hydrocarbon emissions to air,
land, and water.  Offshore operations also contend with the danger of storms
and  shipping accidents causing uncontrolled flow from producing wells   Tech-
nology is constantly improving the situation, however, and is  decreasing the
potential threat of uncontrolled flow or blowouts.

Gaseous hydrocarbon emissions are significant environmental  problems in the
industry.  Storage tank breathing and filling losses;  fugitive leaks in valves
vents, pumps, pipes, and vessels; and vented natural  gas  in remote locations
contribute to the emission problem.  However, the increased prices of hydro-
carbons are making prevention of their loss more economically  attractive,  and
this pollution problem should be decreasing in the near future.

Atmospheric emissions of gases other than hydrocarbon  gases  are  also encountered
in oil and gas production.   In producing sour crudes or gases  hydrogen sulfide
emissions may occur from fugitive sources, and other sulfur  compounds may  be
emitted in the tail  gas from sulfur recovery units or  from flaring sulfide
gases.  The quantities of sulfur emitted as sulfides or as oxides  of sulfur
are not well  defined at this time.   The problem is addressed in  Reference  12,
but the variability of sulfur concentrations in the well  productions and  the
inconsistencies  in reporting procedures seem to have prevented any reliable
estimates of nationwide emissions.   Large steam or waste  water streams  con-
taminated with glycols are  also encountered in the natural  gas processing
segments.                                                                s

A huge waste water stream is a by-product of oil  and  gas  production.  Disposal
of large quantities of brines produced with oil and gas presents a problem of
great magnitude.  The brine presents a threat to fresh water supplies,  and
the associated oil  presents a threat to water, land,  and  air.   References  7
and 8 are EPA funded documents which treat the problem of brine  disposal  in
the oil industry in depth.

Another source of environmental concern is the contamination of  aquifer zones
by drilling fluids, brines, or hydrocarbons in secondary  recovery  and drilling
operations.

-------
Bibliography
(3)

       Inc., 1969.
        Annual Statistical Review. Petroleum Industry Statistics. 1965-1974.
        Washington, D. C., American Petroleum Institute, 1975.

  (2)    "Forecast/Review, An Oil and Gas Journal Special Report", Oil and
        Gas_Jouni. 71  (4), 103-118 (1975).                        	

        Chilingar, George V. and Carrol M. Beeson, eds., Surface Operations
        in Petroleum Production, New York, American Elsevier Publishing Co ,
        Inc., 1969.

        An Appraisal of the Petroleum Industry of the United States. PB188865,
        Washington, D. C., United States Department of the Interior, 1965.

  (5)    Environmental  Conservation, Vol. II, Washington, D. C., The National
        Petroleum Council, 1972.

  (6)    Radian Corporation, Study on Control of Hydrocarbon Emissions from
        Petroleum Liquids. EPA Contract No. 68-02-1319, Task 12, Austin
        Texas, 1975.

  (7)    Reid, George W., et al., Brine Disposal  Treatment Practices
        Relating to the Oil Production Industry, EPA 660/2-74-037
        Norman, Oklahoma, 1974.

  (8)    Reid, George W. and Leale E.  Streebin,  Evaluation of Waste Waters
        from Petroleum and Coal Processing. EPA R2-72-001, Ada, Oklahoma,


 (9)    "Independents Widen Lead in U.  S.  Oil and Gas  Search",  Oil  and  Gas
        Journal,  72 (26), 11-15 (1974).                         	'

(10)    Kantor,  Richard H., Trace Pollutants from Petroleum and Natural Gas
        Processing, EPA Contract No.  68-02-1308,  I ask  8,  Houston,  Texas, 1974.

(11)    Bland,  William F.  and  Robert  L.  Davidson,  eds.,  Petroleum  Processing
        Handbook,  New York,  McGraw-Hill, 1967.           	

(12)    Ecology Audits, Inc.,  Sulfur  Compound Emissions of the  Petroleum
        Production  Industry, EPA  Publication No. 650/2-75-030,  Dallas, Texas,

-------
INDUSTRY ANALYSIS
The oil and gas production industry is  discussed in five segments:   (1)
Exploration and Site Preparation,  (2)  Drilling,  (3) Crude Processing,
(4) Natural Gas Processing, and.(5) Secondary and Tertiary Recovery.   The
discussion of the above five segments  includes process  descriptions  of the
various processing steps used in producing and preparing crude,  natural
gas liquids, and natural gas for use by consumers or refineries.

An attempt was made to present the process steps in sequence.  The problem
encountered in the Crude Processing and Natural  Gas Processing segments was
the diversity of the operations involved.   The sequences of processing steps
are not at all the same from place to  place;  moreover,  some processes  may
be absent and additional processes present to deal  with the local conditions
and composition of the production.  This catalog entry  cannot be considered
an all-encompassing survey, but only a  summary of some  of the most commonly
used methods in domestic production.

Within each process description data have been presented on operating  para-
meters, utility requirements, input materials, and waste streams when  they
were applicable and available.  Input materials  were confined to chemical
substances added; items such as drill  bits and drill pipes were  disregarded.
Operating parameters include process variables and do not include such things
as downhole temperatures.  Waste streams have been indicated even when no
quantitative data were found.  Information and data were taken from  authori-
tative sources and are considered reliable and accurate.  Process flowsheets
have been provided for Crude Processing and Natural Gas Processing,  but were
considered inappropriate for the other segments.

-------
EXPLORATION AND SITE PREPARATION


Process descriptions for the two modules (1)  Exploration and (2)  Site
Preparation are presented in this segment.  A large portion of the total
oil and gas production budget goes into these acitivites which are becoming
increasingly necessary and more expensive each year as the industry is  forced
to produce oil from more remote or inaccessible formations.

-------
EXPLORATION AND SITE PREPARATION                              PROCESS  NO.  1
                               Exploration
1.     Function - The objective of oil  exploration procedures  is  defining
       and describing geological structures which are often  associated  with
       oil accumulation in the earth's  crust.

       Geological surveys of the surface are made using aerial  photographs,
       satellite photographs, and mappings of surface outcrops.   Offshore
       geological surveys include mapping of the bottom using  acoustic
       sounding methods and bottom sampling.  Core sampling  is  performed
       in both onshore and offshore operations.

       Subsurface geological  surveys are made by geophysical methods.
       Seismic methods, the most widely used of the geophysical methods,
       yield information about the times required for shock  waves to  travel
       through rock formations.  These  data help characterize  the subsurface
       strata with respect to the depth and nature of the formations.   The
       monitored shock waves are generated by explosive charges set at  or
       near the surface or by dropping  a 2700 kg (6000 Ib.)  steel  slab  3
       meters (nine feet) to the ground (thumping).

       Offshore seismic operations generate shock waves to penetrate  the
       earth's crust in a variety of ways.  The traditional  source was  dynamite,
       but today electric discharges, encapsulated explosives,  gas guns,
       and electromechanical  and mechanical transducers are  used.   In marine
       geophysical surveys the sources  and receivers are operated over  the
       side of or close behind a ship.

       Gravimetric methods depend on the measurements of slight variations in
       the force of gravity on the surface of the earth or ocean  floor.  Mag-
       netic methods measure local variations in the intensity  of the earth's
       magnetic field.  These measurements may give indications of the  depth
       and nature of subsurface rock formations.

2.     Input Materials - Not applicable

3.     Operating Parameters - Not applicable

4.     Utilities - Very small energy usage

5.     Waste Streams - There is a minimal  danger of pollution  due to a
       blowout during core drilling operations when a shallow  pocket of
       gas or oil is encountered.

-------
       Uncased seismic shot holes can cause pollution of shallow freshwater
       streams.  Strong shock waves generated offshore by explosives  have
       resulted in killing fish.


       On the whole, this part of the industry has little chance for
       pollution.


6.     EPA Source Classification Code - None exists

7.     References -


       0)   Environmental  Conservation.   The Oil  and Gas Industries. Vol  II
             Washington,  D. C., The National  Petroleum Council,  1972.


       (2)   The Petroleum Handbook. London,  Shell  International  Petroleum
             Company Limited, 1966.


       (3)   Petroleum Extension Service  Industrial  and Business  Training
             Bureau, A Primer of Oil  Well  Drilling.  3rd.  ed., Austin, Texas,

-------
EXPLORATION AND SITE PREPARATION                              PROCESS  NO.  2
                             Site Preparation
1.     Function - Site preparation activites include those operations
       necessary to prepare the drilling site and "rig-up" the equipment.
       The operations are necessarily different for onshore and offshore
       Vocations and will be dictated somewhat by local  conditions.

       For land operations earth-moving machinery clears,  grades,  and  levels
       the site.  Earthen pits are dug for circulating fluid and for waste,
       and access roads are built and surfaced with a variety of materials
       including caliche, oyster shells, or wooden timbers.   Water must be
       furnished to the site by digging water wells or installing pumps
       and water lines.  The drilling rig may be transported overland  on
       skids almost completely assembled, or if the distance is great  and/or
       the terrain is rough, the rig must be dismantled and hauled to  the
       site on heavy trucks.  Remote drilling locations may require trans-
       port of rig pieces by air freight or by helicopter.  The derrick is
       usually of the cantilevered type and is raised into position after
       being assembled horizontally using power from the drawworks.  Connec-
       tions are made for the pumps, mud tanks, and pipe lines and the crown
       block, hoisting line, and travelling block are installed.  Auxiliary
       equipment is installed and the mouse and rat holes  are dug before
       drilling can begin.

       Preparations for drilling offshore differ widely because of the many
       types of rigs available.  The drilling rigs may be  floating or  fixed
       in place on the ocean floor.  They may be self-contained, or they
       may require barge tenders which contain the auxiliary components
       necessary to the drilling derrick.  In all cases the pumps, pipelines,
       and machinery must be connected, and in the case of submersible rigs
       the platform must be settled firmly on the bottom.   For disassembled
       rigs "rigging-up" may require large barges with hoisting capacities
       of 450 metric tons (500 tons) to raise the derrick  and to prepare  the-
       rig for drill ing.

2.     Input Materials - Not applicable

3.     Operating Parameters - Not applicable

4-     Utilities - Fuel  required for earth-moving and transportation equipment

5.     Waste Streams - Top soil may be eroded from land operations where
       earth-moving machinery has removed vegetation.

6.     EPA Source Classification Code - None exists
                                      10

-------
7.      References  -
       (1)    Petroleum Extension  Service  Industrial  and Business Training
             Bureau,  A Primer of  Oil  Well  Drilling.  3rd. ed.,  Austin,  Texas,
             1970.

       (2)    Environmental  Conservation.  The  Oil  and Gas Industries. Vol.  II,
             Washington, D.  C., The National  Petroleum Council, 1972.

       (3)    The Petroleum Handbook, London,  Shell  International Petroleum
             Company  Limited, 1966.
                                       11

-------
WELL DRILLING AND COMPLETION
The segment of the oil industry concerned with drilling and completing an
oil well includes all of those operations necessary to digging the hole and
readying it for production.

There are four main processes involved in this segment.  Drilling is the
process of actually cutting through the earth's crust to form a hole.   Mud
circulation is a facilitative process which aids in drilling and provides a
safety measure against blowouts.  Formation evaluation concerns gathering
data about the formations being penetrated and assessing their commercial
value.  Well completion includes those steps necessary to prepare the  drilled
hole for production.

-------
DRILLING                                                      PROCESS  NO.  3
                                 Drilling
1.     Function - Drilling is the process  of actually  cutting  through  the
       earth's crust to form a well  and is accomplished  by  rotating  and
       hoisting operations performed at the derrick.   The cutting  and
       grinding through the earth's  surface is  accomplished by rotating
       the drilling string with the  required weight on the  drill bit affixed
       to the end of the drill  string.   Additional  lengths  of  drill  pipe are
       attached as the drilling proceeds.   When a worn drill bit has to be
       replaced, the entire string of pipe must be  hoisted.  The pipe  lengths
       are removed as the string is  slowly raised until  the drill  bit  is
       brought to the surface and changed  out.   The new  bit and the  drill
       string are slowly lowered, and the  lengths of pipe are  replaced until
       the bottom is reached,  at which  time rotation begins  again.

       The rotation equipment consists  of  a swivel  which sustains  the weight
       of the drilling string, permits  rotation, and affords a passageway
       for circulation of drilling fluid;  the kelly which transmits  torque
       from the rotary to the drilling  string,  permits vertical movement
       of the string, and transmits  drilling fluid  down  the string;  the
       rotary table which drives the kelly bushing  and accommodates  tapered
       slips for holding pipe when making  or breaking  connections.   The drill
       bit is on the end of the rotating string and is designed to break,
       dislodge, or fragment formation  material. Different bits are available
       for different applications; they may be  steel,  carbide-tipped,  or
       diamond tipped.

       Hoisting equipment consists of the  drawworks, a crown block fixed at
       the top of the derrick, and a travelling block  to which is  attached
       a hook.  The drawworks is a power hoist  provided  with a series of
       clutches, gearing systems, and braking systems  to hoist and lower as
       much as 450 metric tons  (500  tons)  of weight in a controlled manner.

2.     Input Materials - Not applicable

3.     Operating Parameters - Not applicable

4.     Utilities - Heavy duty rigs for  deep wells require about 2200 kW
       (3000 hp)  for rotation,  hoisting, and circulation.   The power is
       routinely supplied by diesel  or  gas  engines.
                                     13

-------
 5.     Waste Streams  -

        .   Cuttings  -  168 m3 (1059 barrels) of cuttings are generated in
           drilling  a  4600 m (15,000 foot) hole 22 cm (8% in.) in diameter.
           On land the cuttings are separated from the mud and discharged in
           waste  pits.  Offshore the cuttings may be dumped into the ocean
           if they are mixed with water-based muds.  Those cuttings contam-
           inated with oil-based muds or hydrocarbons from a formation may
           be treated  to separate the oil before disposal in the sea, or the
           cuttings  may be pumped into a barge for transport to shore when
           the waste is treated and discarded.

        .   Drilling  fluid - Excess or contaminated mud is pumped into waste
           pits,  into  the ocean (when water-based mud is used), or into
           barges for  transport to shore.  Earthen mud pits are subject to
           a certain amount of leaching which may threaten fresh water zones.
           Mud may also escape into porous formations and into fresh water
           aquifers  during drilling operations.  Modern drilling operations
           employ techniques to protect fresh water aquifers; oil-based muds
           are not used while drilling these formations, and often casing
           will be set in that zone.

       .   Hydrocarbons - Oil  brought to the surface with drilling mud is
           separated and disposed of in open pits  or pumped into barges  for
           onshore disposal.   Excess oil-based muds are treated in~the same
           manner.  At any point that the oil  is open to the air, atmospheric
           emissions result.   Hydrocarbon gas  brought to the surface with
           drilling  fluid is  separated from the mud and may be vented or
           flared at a safe distance from the  drilling operation.

           Blowouts  are considered a very serious  hydrocarbon waste stream
          which may affect air,  land,  and water.   Blowouts  occurred in  106
          of 273,000 wells drilled from 1960  through 1970  in "eight states.
          Of 9000 wells  drilled  on the outer  continental shelf,  blowouts
           1n 25 wells occurred.   Along with the hydrocarbon emission to the
           land,  air, and sea,  there are dangers of a blowout establishing
           communication between  the producing formation and a fresh water
          aquifer.   Blowout  prevention measures are practiced routinely
           throughout the industry.   Drilling  rigs  are equipped with blowout
           preventers which  can close a well  in 15  seconds.   Downhole pres-
           sures and mud  circulation volumes are constantly  monitored during
          drilling  operations  for indications  of well  fluid entering the
          hole.   Drilling muds are weighted to keep the downhole  pressure
          under control.

6.     EPA Source Classification  Code  -  None
                                       14

-------
(7)     References  -
       (1)    Environmental  Conservation.  The Oil and Gas Industries. Vol. II,
             Washington,  D.  C., The National Petroleum Council, 1972.

       (2)    The Petroleum  Handbook,  London, Shell  International Petroleum
             Company Limited,  1966.

       (3)    Petroleum Extension  Service  Industrial and Business Training
             Bureau, A Primer  of  Oil  Well Drillings. 3rd. ed., Austin, Texas,
             1970.

       (4)    Rogers, Walter F., Composition and  Properties of Oil Well
             Drilling Fluids.  Houston,  Texas, Gulf  Publishing Company, 1963.

       (5)    Collins, Gene, "Oil  and  Gas  Wells-Potential  Polluters of the
             Environment?", J. of WPCF  43 (12),  2383-93 (1971).
                                        15

-------
DRILLING                                                      PROCESS NO. 4
                              Mud Circulation
       Function - Drilling fluid is  pumped  through  the  drill  pipe  and drill
       bit to the bottom of the hole and returned to  the  surface through
       the annul us outside the drill  bit during  drilling  operations.  The
       purposes of the fluid are to  remove  cuttings made  by  the bit, to
       cool and lubricate the bit and drill  string, to  control formation
       pressure,  to support and protect the wall of the hole, and  to facilitate
       formation evaluation procedures.

       The drilling fluid is pumped  under high pressure from a suction  tank
       or pit, up a standpipe, through the  rotary hose  and swivel  to the
       hollow kelly and drilling string. After  leaving the  drill  bit,  the
       fluid, carrying drilling cuttings, ascends through the space between
       the drill  string and wall of  the borehole.   At the surface  the fluid
       passes through shale shakers, desanders,  desilters, and degassers  to
       remove impurities.  The mud then returns  to  the  suction tank for
       recycling unless it is contaminated.   Contaminated mud is jetted into
       reserve pits or barges along  with cuttings,  excess mud made by the
       hole, and other waste streams from the drilling  site.  In addition to
       the basic circulation equipment mentioned there  are agitators for  the
       tanks* mud weight and pit level indicating and recording devices,
       chemical testing and treating apparatus,  and mud storage and handling
       facilities.

       The actual composition of the drilling fluid will  vary with the  forma-
       tion being drilled and the activity  on the drilling rig.  Drilling
       fluids include gases, liquids, and solids suspended in liquids.  The
       solids suspended in liquids type, the most widely  used, consists of a
       colloidal  suspension of clay  in water, usually bentonite for fresh
       water and attapulgite for salt water.  Suspensions of solids in  oil
       and oil emulsions are also used, especially  in drilling through  for-
       mations that swell and slough in the presence  of water.  Chemicals
       of various types are used to  further control the physical and chemical
       properties of the drilling fluid. The viscosity is adjusted with
       quebracho and tannin; the density is controlled with  weighting agents,
       usually barite.  When drilling through highly  permeable formations,
       fibrous, flaky, or granular material  may  be  added  to  stop mud circula-
       tion losses.  A partial list  of the  substances used in drilling  fluids
       includes lignosulfonates, calcium, chromium  compounds, acrylonitriles,
       sodium salts of phosphoric acids, natural gums,  dehydrated  phosphates,
       subbituminous products, protocatechuic acid, lignins, sugar cane fibers,
       lime, ground nutshells, cotton seed  hulls, cellophane flakes, corn
       starch, salt water, carboxymethyl-cellulose, crude oil, surfactants,
       soaps, lecithin, and asbestos.  A list of some drilling fluids and
       their descriptions is included in Appendix D.
                                       16

-------
2.     Input Materials - A well  2600 to 3500 m (8500  to  11,500  feet)  deep
       will  require 190 to 400 m3  (1200 to 2500 barrels)  of mud to  circulate
       and fill  the hole.  This does not allow for volumes  of chemical addi-
       tions made as drilling progresses or for mud lost to porous  formations
       Chemical  additions generally range from 20 to  140 kg (50 to  300 Ib.)
       per day,  but may go as high as 900 kg (2000 Ib.)  per day.

3.     Operating Parameters - The minimum critical velocity is  usually 37
       to 55 meters per minute (120 to 180 feet per minute).

4.     Utilities - A typical 41  cm (16 in.) mud pump for a  heavy duty rig
       is driven by 750 kW (1000 hp).  With an efficiency of 0.36 the pump
       requires  0.025 m3 (6.50 gallons) of diesel per hour.  Additional
       power 1s  required for various smaller motors,  pumps, and agitators
       involved in the mud circulation system.

5.     wast6 Streams  -

          Drilling fluid  - Excess or contaminated mud is pumped into
          waste pits,  into the ocean (when water-based mud  is  used), or
          into barges  for  transport  to  shore.   Drilling mud may threaten
          fresh water zones  by leaching from earthen pits  and  by escap-
          ing into  porous  formations during  drilling operations.  Modern
          drilling  operations  include  practices  to protect fresh water
          zones.   Oil-based  muds  are not used while drilling these for-
          mations,  and often casing will  be  set in that  zone.

          Hydrocarbons - Oil  brought to the surface with drilling  mud
           is  separated and disposed of in open pits or  pumped  into
          barges  for disposal  onshore.   Excess oil-based muds  are
           treated in the same manner.   At any point  that the oil is
           open  to the air, atmospheric emissions result.

           Hydrocarbon gas brought to the surface with  drilling fluid
           is separated from the mud and may be vented  or flared at a
           safe  distance from the drilling operations.

 6.     EPA Source Classification Code - None

 7.     References -

        (1)  Petroleum Handbook, London, Shell International
             Petroleum Company Limited, 1966.

        (2)  Petroleum Extension Service  Industrial and Business
             Training  Bureau, A Primer of Oil Well Drilling, 3rd.
             ed., Austin, Texas, 1970.

        (3)  Environmental Conservation.  The  Oil and Gas  Industries,
             Vol.  II,  Washington, D. C.,  The  National Petroleum Council,
             1972.
                                        17

-------
(4)   Lynch,  Edward  J.,  Formation Evaluation. New York, Harper and
     Row,  1962.

(5)   Rogers, Walter F.,  Composition and Properties of Oil Well
     Drilling Fluids, Houston, Texas, Gulf Publishing Company, 1963,

(6)   Collins, Gene, "Oil  and Gas Wells-Potential Polluters of the
     Environment?", J.  of WPCF 43  (12), 2383-93 (1971).
                               13

-------
DRILLING                                                      PROCESS NO.  5
                           Formation Evaluation
1.     Function - Formation evaluation involves  the use of tools  and  methods
       that are capable of locating producing formations and  evaluating
       their commercial significance.  There are two broad categories of
       formation evaluation methods:  those used while drilling  is  in pro-
       gress and those used after drilling or a  portion of the drilling  is
       completed.  Core analysis and evaluation  of drilling fluid and drill
       cuttings are in the first group, while wireline logging methods such
       as electric logging, radioactivity logging, and acoustic  velocity
       logging are in the second category.  Drill stem testing may  be used
       in either classification.

       In coring the drill bit is replaced by a  core barrel and  a core head
       by means of which a cylinder of the formation being penetrated passes
       through the core head and into the core barrel where it is retained
       and brought to the surface.  Sidewall coring is accomplished by
       shooting several hollow cylinders into the walls of the uncased hole.
       The cylinders are then pulled to the surface by steel  wires  attached
       to the carrier.  The core samples are analyzed for porosity, per-
       meability, and the saturation of oil, water, and gas.

       Evaluation of the drill cuttings and the drilling fluid involves
       continuous monitoring of these streams for traces of oil, gas, or
       saltwater.

       Wireline logging methods require that various special  tools run into
       the well on multi-conductor wireline are placed in the well  to study
       and evaluate the formation.  These special devices may measure the
       electrical, magnetic, radioactive, or acoustic properties of the
       formations.  The measured information is displayed continuously as
       a function of depth on a strip chart.

       If a formation  looks promising, a drill stem  test is made.  Drill
       stem testing seeks to reproduce conditions existent in a producing
       well.  A simplified description of the process is that a producing
       formation is sealed off with packers, and the formation is opened
       to the surface.  Formation fluid then enters  the drill pipe and is
       brought to the  surface for evaluation.

       The data gathered  from the formation evaluation processes will
       determine whether  the casing is set and the well completed or plugged.

 2.     Input Materials -  Not applicable
                                      19

-------
3.     Operating Parameters - Not applicable
4.     Utilities - The amount of power required  is  small  compared  to  the  power
       required for other drilling operations.
5.     Waste Streams - None
6.     EPA Source Classification Code - None  exists
7.     References -
       (1)   Lynch, Edward 0., Formation Evaluation, New York, Harper
             and Row, 1962.
       (2)   Petroleum Extension Service Industrial and Business Training
             Bureau, A Primer of Oil Well Drilling, 3rd. ed., Austin,
             Texas, 1970.
       (3)   Environmental Conservation.  The Oil and Gas Industries, Vol.
             II, Washington, D. C., The National Petroleum Council,  1972.
       (4)   The Petroleum Handbook, London,  Shell  International Petroleum
             Company Limited, 1966.
                                       20

-------
DRILLING                                                      PROCESS NO. 6
                             Well  Completion
       Function - Well  completion encompasses  all  of those  activities
       required in preparing the drilled hole  for  production.

       According to the nature of the producing  formation,  different
       completion methods are used,  but a string of casing  is  always
       run into the hole and cemented,  at least  as far  as the  top of the
       producing layer.  When the producing  formation is firm,  the casing
       may be cemented  immediately above it, leaving the producing zone
       unsupported.  If the producing formation  is judged to be in danger
       of caving or sloughing, it must be supported.  The most  common way
       of completing a  well  with a structurally  weak production zone is by
       perforating (comprising 95% of well completions).  Casing is run
       through the producing layer to the bottom and cemented,  after which
       holes are shot through the casing and cement in  the  producing layer
       with a perforator.  Perforators either  contain charges  which  fire
       steel bullets, or they employ small shaped  charges that  blow holes
       through the casing and cement.  An alternative to perforating is the
       practice of hanging a small perforated  pipe (liner)  from the bottom
       of the set casing.  The presence of sand  formations  may  necessitate
       the use of a mesh liner or fine gravel  to prevent abrasive particles
       from entering the production  fluid.

       After the cement has hardened, a relatively small diameter production
       tubing is installed inside the casing.  Multiple production zones
       require multiple strings of production  tubing to produce several
       zones simultaneously but separately.

       There are various things that may be  done to encourage  the fluid from
       the formation to enter the production tubing and travel  to the sur-
       face.  If the producing formation is  carbonate rock  and  has low
       permeability, acid is pumped  under pressure down the tubing and
       into the formation to open it and allow production fluid to enter
       the tubing (see  Process 19).   If the  producing formation is sandstone
       of low permeability,  fracturing may be  used to increase  the perme-
       ability and to encourage production.  Fracturing is  accomplished by
       forcing a sand and fluid suspension into  the formation and literally
       cracking it open (see Process 18).  Additionally, the well may be
       swabbed by lowering a rubber-faced hollow cylinder into  the hole and
       withdrawing it,  creating a vacuum and pulling oil to the surface.

       The last step of completing a well  is the installation of a Christmas
       tree (a series of valves)  for freely  flowing wells or a  pump to bring
       the production to the surface.
                                     21

-------
2.     Input Materials - See Processes 18 and 19.

3.     Operating Parameters - See Processes 18 and 19.

4.     Uti1 i ti es - Power is required for (1)  the draw works  and  (2) pumping
       solutions and cement into the hole.
5.     Haste Streams -

       .  Acid - Treating formations with acid results  in  salt-enriched
          acid solutions which present a disposal  problem  because of
          their low pH and high solids content.   The amount  of acid
          used for well  treatment procedures  is  summarized in  Table 1.


          Table 1.   YEARLY VOLUMES OF ACIDS  USED FOR WELL TREATMENT
                                                 Volume
          	Acid	 Gal/Yr.       mVYr. '	
                 Hydrochloric            8.7  x  107     3.3  x 10s

                 Formic                  2.0  x  105     7.6  x 102

                 Acetic                  1.0  x  105     3.8  x 102

          An additional possibility for pollution exists  in the corrosive
          nature of the acid solutions toward pipe in  the  well.  When
          corrosion causes pipe failure, adjacent strata  (which may  be
          aquifers) are contaminated.

6.     EPA Source Classification Code  - None  exists

7.     References -

       (1)  Petroleum Extension Service Industrial  and Business  Training
            Bureau, A Primer of Oil Well Drilling.  3rd. ed., Austin, Texas, 1970,

       (2)  Environmental Conservation.  The  Oil  and Gas  Industries. Vol.  II,
            Washington, D. C., The National Petroleum  Council,  1972.

       (3)  The Petroleum Handbook. London, Shell  International  Petroleum
            Company Limited, 1966.

       (4)  Lynch, Edward J., Formation Evaluation. New York, Harper and
            Row, 1962.

       (5)  Rogers, Walter F., Composition and  Properties  of Oil Well
            Drilling Fluids, Houston,  Texas,  Gulf Publishing Company, 1963.

       (6)  Collins, Gene, "Oil  and Gas Wells - Potential  Polluters of the
            Environment?", J.  of WPCF  43 (12),  2383-93 (1971).


                                      22

-------
CRUDE PROCESSING


The distinction between oil  wells and gas wells  is  rather arbitrary.  There
are very few wells producing oil  or gas  alone; most produce  both.   In addition
most wells produce a certain amount of water or  brine.   The  well  is often
called an oil well when crude is the major volume of production  or when
crude is the production of interest such as in  locations very distantly
located from a gas plant or refinery.

This segment of the industry is concerned with the operations necessary  in
preparing the crude oil for refinery use.  Figure 2 is  a representative
flowsheet for crude processing which includes water removal  by "knock-out"
and emulsion breaking, gas removal  by two or three phase separation, and
storage.  These process descriptions are presented sequentially, but the
oil production industry is very diverse, and the process steps may be
altered to suit specific location and production needs.  Most of the crude
processing steps take place in the field, at the well  head,  or at a central
gathering station.  In offshore operations, the  entire  production (gas,  oil,
water) may be shipped ashore by barge or pipeline for processing.   Alter-
natively, a centralized processing platform may  serve several wells in  the
same area.

A  major liquid waste stream in this segment is  production water or oily
brine.  There are also hydrocarbon and acid gas  emissions from gases
entrained in the crude which may escape upon exposure to air.  If sour
gases from separators are flared, an emission of SO  also results.
                                                   /\
                                      23

-------
["FROM OIL WELL!     ^
ro
                                                                                                         TO GAS PROCESSING
                                                                                                        pro REFINERYj
                                                                                                         TO WASTEWATER
                                                                                                         TREATMENT
                                                                                                         AND DISPOSAL
                                    FIGURE 2. CRUDE PROCESSING

-------
CRUDE PROCESSING                                              PROCESS  NO.  7
                              Water Removal
1.     Function - The purpose of crude separation is  to remove the  oily
       brine from crude oil.  Water is always pumped  with  oil, and  most  of
       it must be removed before the oil  is shipped to the refinery.   The
       two major separation processes used are free water  knock-out and
       emulsion breaking.

       Free water knock-out is the settling out of the free water in a large
       tank equipped with baffles to minimize the amount of turbulence and
       mixing.

       Emulsions are formed when water and oil  systems are violently mixed
       in the presence of impurities which impede the settling out  of the
       water.  This water can be removed  by one of several  means  (1)  heat,
       (2) chemical destabilization, (3)  electrical coalescence,  and (4)
       gravitational settling.

       Heat alone is not used as much today as  it once was, but it  is  used
       in conjunction with other methods.  Chemical destabilization causes
       the emulsion to break up by removing the effects of the impurities
       that stabilize it.  In electrical  coalescence, an electrical  field
       is passed through the emulsion. When the polar molecules  holding the
       emulsion stable turn to follow the lines of the electric field, the
       droplets combine and fall out by the force of  gravity.   If an emulsion
       is not too strong, it may settle out if allowed to  sit  for some time;
       this process is gravitational settling.

       The required water disposal may be difficult,  especially offshore.
       If water cleaning facilities are available, offshore production water
       is cleaned before it is pumped into the sea.  Otherwise the  oily
       waste is pumped into tankers or pipelines for  treatment onshore.

2.     Input Material - Production from an oil  well

3.     Operating Parameters - Electric dehydrators are 2-4 meters (6-12  ft.)
       in diameter and 4-24 meters (12-80 ft.)  long.   Capacities  are 160 to
       16,000 cu m per day (1000-100,000  bpd).   Operating  voltages  are 440v
       at the switchboard and 16,500v at  the electrode. Residence  time  is
       about 20 minutes.

       Heater treaters are normally operated at 99°C  (210°F).

4.     Utilities - Utilities required include fuel for heaters, power to run
       equipment to inject chemicals for  chemical treatment, and  power for
                                     25

-------
       electrical  treaters.   For  electric treaters, electric power consumption
       varies with the  conductivity of  the crude oil.  The least conductive
       crudes, ordinarily  of the  high API gravity, require about 0.5 kW for
       each 160 cu m (1000 barrels) per day  capacity, while heavy crudes may
       require 1.5 kW per  160 cu  m (1000 barrels) per day capacity.

       Heater treaters  are powered by fuel gas.  They require 5 to 70 normal
       cu m of gas per cubic meter of crude  processed (3 to 40 x 101* SCF
       per 1000 barrels) depending on the amount of water present in the
       production.

5.     Waste Streams -

       .   Brine - On the average, two to  three cubic meters of water are
          produced per cubic meter of oil.   This amounts to up to 4.0
          million cubic meters (25 million barrels) of oily salt water
          produced daily in the U.S.   This waste  contains  an  average  con-
          centration of solids seven times  that of sea water.  The  disposi-
          tion of waste brine is shown  in Table 2.

                     Table 2.   DISPOSITION  OF WASTE BRINE
          Amount	Disposal  Site	
            72%                     Underground formations or injection
                                    for secondary recovery.

            12%                     Non-potable water sites, approved
                                    disposal sites, or used in irriga-
                                    tion or for livestock.

            12%                     Unlined pits

             4%                     Rivers
          Hydrocarbons - Oil carried along with the brine is a source of
          emissions to the air and to water supplies.  Current disposal
          practices allow the possibility of evaporative emissions as
          well as the possibility of water and land contamination.

          In  isolated locations dregs from the heater treaters may be
          dumped into open pits and burned.  This practice causes air
          emissions from combustion.

          Waste water separators are in themselves sources of hydrocarbon
          emissions.  An estimated 33 metric tons (36 short tons) of hydro-
          carbons are emitted daily from these operations.
                                      26

-------
6.     EPA Source Classification  Code  -  None  exists

7.     References -

       (1)   Bansback,  P.  L.,  "The  How and Why of Emulsions", Oil and Gas
             Journalt  68 (36)  87-93 (1970).

       (2)   Waterman,  L.  C. and  R. L. Pettefer, "Oil  Field Emulsions and
             Their Electrical  Resolution", Surface Operations in Petroleum
             Production, George V.  Chilingar  and Carrol M. Beeson, eds.,
             New York,  American Elsevier Publishing  Company, Inc., 1969,
             pp.  29-45.

       (3)   Radian Corp., Study  on Control of Hydrocarbon Emissions from
             Petroleum Liquids. EPA Contract  No. 68-02-1319, Task 12, Austin,
             Tx., 1975.

       (4)   Environmental Conservation. The Oil and  Gas  Industries, Vol.  II,
             Washington, D. C., The National  Petroleum Council,  1972.

       (5)   MSA Research Corp.,  Hydrocarbon  Pollutant Systems Study. Vol.  I,
             APTD-1499, PB 218073,  Evans City, Pa.,  1972.

       (6)   Processes Research,  Inc., Screening Report.  Crude Oil and
             Natural  Gas Production Processes. EPA  Contract No.  68-02-0242,
             Cincinnati, Ohio, 1972.

       (7)   Booz-Allen Applied Research, Inc., A Study of Hazardous Waste
             Materials. Hazardous Effects and Disposal  Methods.  Vol. Ill,
             PB-221467, Bethesda, Md., 1973.

       (8)   Cavanaugh, E. C., et al., Atmospheric  Environmental  Problem
             Definition of Facilities  for Extraction,  On-Site Processing.
             and Transportation of Fuel  Resources.  EPA Contract  No. 68-02-1319,
             Task 19,  Austin,  Tx.,  1975.

       (9)   Reid, George W. and  Leale E. Streebin,  Evaluation of Waste
             Waters from Petroleum and Coal  Processing, EPA-R2-72-001,
             Washington, D. C., 1972.
                                      27

-------
 CRUDE PROCESSING                                             PROCESS N(h 8
                           Gas-Oil Separation
 1.      Function  -  The  purpose of this  process is to separate entrained
        gases  from  crude oil.

        There  are two types of separators:  two-phase for separating gas
        and oil and  three-phase for separating gas, oil, and water.  Non-
        solution  gases  can be separated by settling, agitation, baffling,
        heat,  or  chemicals.  Most separators of vertical, spherical, or
        horizontal  configuration employ a series of baffles to separate the
        gases  from  the  crude.  The horizontal separator is usually used when
        the gas oil  ratio is large, the vertical separator is used when the
        gas oil ratio is low, and the spherical separator is used when the
        gas oil ratio is in an intermediate range.

        A stage separation procedure may be used in which a series of separators
        are operated to perform two or more flash vaporizations at sequentially
        reduced pressures.  This is particularly useful  when well-head pressure
        is high.

        The gas produced is sent to a gas processing plant and the separated
        crude  is  ready for storage.

2-      Input Materials - Oil  containing light hydrocarbon gases

3-     Operating Parameters - The operating temperatures  and pressures  will
       generally begin with the well-head temperature and pressure and  drop
       step-wise to ambient conditions.  Separator retention times of 1  to
       3 minutes are generally adequate,  but 5  to 20  minutes  may be required
       for difficult separations.

4.     Uti 1 i ti es -  The well-head pressure does most of  the  work.

5.     Waste  Streams -

       .  Hydrocarbons  -  At remote  locations where  there  is  no need for
          recovered gases  to maintain  formation  pressure  or when  there  is
          no  economical way to  transport  them to  a  processing  plant,  the
          hydrocarbon  gases may  be  vented or flared.  An  estimated  1.34
          billion cu m/yr  (50  billion cu  ft/yr) of  natural gas is  lost to
          the atmosphere from  venting,  flaring, and fugitive losses.
                mhi"  *! Sour ugas  from the sePa™tor must be disposed
                must  be  flared to change the highly toxic H2S to SOV which
                                                                   A
                                    28

-------
          IwJ!         !he  ?tmosPhere W1'th combustion wastes.  Assuming an
          average concentration of 0.5 mole percent sulfur in domestic
          naturaVgas,  7.08  million cu m/yr (250 million cu ?t/yr) of gas-
                                                    s an °11y bHne waste
6-     EPA Source Classification Code - None exists

7.     References -

       (1)    Chilingar, George V. and Carrol M. Beeson, "Separation  of
             Gas  and Oil   Surface Operations in Petroleum Production.
             George V. Chilingar and Carrol M.  Beeson, eds.,  New York
             American Elsevier Publishing Company, Inc.,  1969,  pp. 15-28.
            l^riCv' yho»a^ C" ed" Petroleum Production Handbook.  Vol   I,
            New York, McGraw-Hill, 1962.  -- ' -

       (3)   Processes Research, Inc., Screening Report  Crude  Oil and
                                29

-------
CRUDE PROCESSING                                              PROCESS NO. 9
                              Crude Storage
1.     Function - Crude is stored in tanks to await shipment to the refinery.
       The tanks are fixed or floating-roof types with capacities  up to
       40,000 cubic meters (250,000 barrels).  Newer technology provides  for
       vapor recovery systems to capture the lighter hydrocarbons  evaporating
       from the crude in the tanks.

       Storage tanks also serve the purpose of a settling tank, as they allow
       additional production water to separate.

2.     Input Materials - Crude oil

3.     Operating Parameters - Atmospheric conditions

4-     Utilities - Those required  in pumping the crude

5.     Waste Streams -

        .   Brine  - 12 liters per cubic meter  stored crude

        .   Hydrocarbons - Emissions from storage  tanks are of two  types:
           working losses from loading operations and  breathing losses
           resulting  from expansion and  contraction of the vapor space
           due  to temperature cycles.  Emission factors are  given  below.
            Table 3.    HYDROCARBON EMISSION FACTORS  FOR  CRUDE STORAGE
              Type of Tank	Emission Factor	

            Fixed Roof
              Breathing Loss          40 g/day-103fc capacity
                                      (0.3 lb/day-103 gal  capacity)

              Working loss            1000 g/day-103& throughput
                                      (8.0 lb/day-103 gal  throughput)

            Floating Roof
              Breathing loss          14,000-73,000 g/day-tank
                                      (30-160 Ib/day-tank)

              Working loss            Negligible
                                     30

-------
6.     EPA Source Classification Code -  None  exists

7.     References -

       (1)   Nack, H., et al.,  Development  of an  Approach  to  Identification
             of Emerging Technology and  Demonstration  Opportunities, EPA
             650/2-74-048, Columbus, Ohio,  Battelle-Columbus  Labs., 1974.

       (2)   Radian Corporation, A Program  to Investigate  Various  Factors
             in Refinery Siting, Final Report, Contract No.  EQC  31y, Austin,
             Tx., 1974.

       (3)   Environmental Protection Agency, Compilation  of Air Pollutant
             Emission Factors.  2nd ed.,  AP-42, Research Triangle Park,  N  C
                                   31

-------
NATURAL GAS PROCESSING
Natural gas is composed of methane with decreasing  amounts  of ethane,  propane,
butane, and heavier hydrocarbons.   It is normally saturated with  water vapor
and may contain nitrogen, helium,  carbon dioxide, hydrogen  sulfide,  and mer-
captans.  The purpose of natural  gas processing is  to  produce a natural gas
for pipeline sales and to recover heavier hydrocarbons for  refinery, petro-
chemical, or fuel  use.  Common sales specifications for natural gas  include a
gross heating value of not less than 8,900 kcal per cu m (1,000 Btu  per cu
ft.), a maximum of 0.6 g H2S per 100 normal  cu m (0.25 grains of  H2S per
100 SCF), with a maximum of 1.3 grams (20 grains) total  sulfur, and  a  water
content low enough so that line freeze-ups will not occur.

The processes used to meet these sales requirements are presented in this
segment.  Although the process steps are presented  sequentially in Figure
3, they are by no means intended to be in a prescribed order. Variations
in sequences, operating conditions, and physical  locations  occur  throughout
the industry with local production conditions and geographical locations
dictating the particular processing methods.

Hydrocarbon liquids are separated from raw gas from wells and oil-gas
separators.  The gas is then sweetened in an acid gas  removal process,
dehydrated, and separated into its hydrocarbon components in  the  product
separation process.  Recovered hydrocarbon liquids  are also processed
in the product separation module.   The acid gas stream when processed
by the sulfur recovery unit provides by-product sulfur.  These processing
steps may be accomplished in the field, at a gas processing plant, or  in
a refinery depending on the location of the production with respect  to
processing facilities.

Hydrocarbon losses encountered in natural gas processing are  mainly  in the
form of fugitive emissions.  At any point that the  system is  open to the
atmosphere, hydrocarbon emissions occur.  These losses were estimated  at
3 kg per 103 normal cu m (190 Ibs per 10r' SCF) of natural  gas processed or
about 6,280 metric tons (6,920 short tons) per day  in 1973.  Emissions of
H2S, S02, elemental sulfur, and glycols are also encountered.
                                      32

-------
SALES
                                                                                  S]
                                                                               SALES
                                                                               SALES  |
                                                                             OR REFINERYJ
                                                                                    Y]
FIGURE 3.  NATURAL GAS  PROCESSING

-------
NATURAL GAS PROCESSING                                        PROCESS NO.  10
                        Liquid Hydrocarbon Recovery
       Function - The purpose of liquid hydrocarbon recovery is the separation
       of condensable hydrocarbons from the natural gas stream.  This  first
       liquid separation step often takes place in the field to facilitate
       pipeline transport to a processing center.  The process usually involves
       a water knockout step to remove any liquid water formed in transporting
       the gas from the well, and there may be a further dehydration dictated
       by the requirements of the particular recovery process.  The recovery
       is generally accomplished by changing conditions of the gas so that the
       equilibrium between the various components is upset causing the heavier
       hydrocarbons to condense.  The equilibrium change may be caused by change
       in temperature, change in pressure, introducing a new material, or a
       combination of these.  Fairly wet or very dry gas may be produced,
       depending on the efficiency of the recovery process.  This process
       description deals with the case of the fairly wet gas which must be
       further separated in the product separation process before it is sold
       to pipeline companies.  There are three major types of liquid recovery-
       processes used singly or in combination to effect the necessary
       separation.


       Adsorption  is  accomplished  in  towers  filled with activated  alumina or
       charcoal  which  adsorbs  the  heavier hydrocarbons.  After the adsorbing
       material  has  been  saturated, heated gas or steam is  passed  through
       the  bed  to  desorb  the  hydrocarbons which  are  condensed and  ultimately
       fractionated.

        In the absorption  process  the  gas  is  passed through  an absorber unit
       where absorber oil  removes  propane and  heavier components.   The methane
       and  ethane  are allowed to  pass up  through the absorber tower in the
       gaseous  phase,  while the enriched  absorber oil  is sent to  a stripper.

        Refrigeration processes involve decreasing the temperature  of  the  gas
        to promote  condensation of the heavier  hydrocarbons.   Of the combina-
        tions of processes the most often  used  is a combination refrigeration/
       absorption  process.

        One of the  newer technologies  involves  the use of a  turboexpander  in
       which the natural  gas  is expanded  through a turbine  compressor from
       which it exhausts  at extremely low temperatures; most of the gas
        except methane is  condensed.

        The wet sour gas produced is sent to  the acid gas  removal  process
        and the recovered liquids are  sent to the product separation step.
                                       34

-------
2.     Input Streams - Production gas  and gas  from oil  separators.

3.     Operating Parameters - Liquid recovery  processes  vary significantly
       in their operating requirements.   Temperatures  as low as  minus 40°C
       (-40°F) and pressures as high as  3 x 10s  kg/square meter  (400 psi)
       are encountered.

       In the oil  absorption process stripping is  generally done at low
       pressure.  The stripped crude is  then pumped up to high pressure  to
       act as an absorbent, and the enriched crude is  then reduced to atmo-
       spheric pressure.   The absorption factor  increases as the temperature
       decreases;  low pressures are conducive  to good  stripping, but high
       pressure aids condensation of the light ends.   The molecular weight
       of the lean oil used in the absorber depends on the average tower
       temperature.  Near minus 18°C (0°F), oil  with a molecular weight  of
       120-140 is  commonly used; near  38°C (100°F), molecular weights of
       180-200 are used.

       Turboexpanders operate with feed  gas pressures  from 8 x 101* to 2  x 106
       kg/square meter (100 to 3000 psig) with capacities of 8 x 105 to
       42 x 106 cu m per  day (30 to 1500 MMscfd).   Outlet temperatures may
       be as low as minus 250°C (-420°F).

4.     Utilities - In general about 3.2% of the  gas produced is  used in
       compression procedures.

       Turboexpanders require 0.1 to 2.0% of the feed  gas depending upon
       compression requirements.

       Refrigerated absorption units consume about 0.75% of the  produced
       gas energy.

5.     Waste Streams - Fugitive emissions only

       .   Hydrocarbons -  Emissions result from leaks in pumps, valves,
          compressors, and other equipment.

       .   Hydrogen Sulfide - If the gas  is a sour  gas, the above mentioned
          sources  will provide hydrogen  sulfide  emissions.

6.     EPA Source  Classification Code  -  None exists

7.     References  -

       (1)   Campbell, John M., "Absorption and  Fractionation  Fundamentals",
             Gas Conditioning and Processing.  John M.  Campbell,  Norman,
             Oklahoma, 1970.

       (2)   Cotterlaz-Rennaz, "New French Gas Cooler  Recovers 120 BPD
             Gasoline", World Oil 177  (2), 57-59 (1973).
                                      35

-------
(3)   Eckerson, B. A., A,  L.  Johnson,  "Natural  Gas  and  Natural  Gas
      Liquids". Surface Operations in  Petroleum Production.  George
      V. Chilingar and Carrol  M.  Beeson,  eds.,  New  York, American
      Elsevier Publishing  Company, Inc.,  1969.

(4)   "NG/LNG/SNG Handbook",  Hydrocarbon  Processing, April  1973.

(5)   Processes Research,  Inc., Screening Report, Crude Oil  and
      Natural  Gas Production  Processes, PB-222718,  Cincinnati,  Ohio,
      I J I £ •

(6)   Petroleum Extension  Service, Field  Handling of Natural Gas,
      3rd. ed., Austin,  Texas, The University of Texas  at Austin, 1972

(7)   Houghton, J.  and J.  D.  McLay,  "Turboexpanders Aid Condensate
      Recovery", Oil  and Gas  Journal.  76-79  (March  5, 1973).
                              36

-------
 NATURAL GAS PROCESSING                                        PROCESS  NO   11
                             Acid Gas Removal
 V-     Function - The acid gas  removal  unit is  designed  to  remove hydrogen
        sulfide from hydrocarbon gases  by  absorption  in some aqueous
        regenerative sorbent.  A number of gas treatment  processes are
        available, and they are  distinguished primarily by the  regenerative
        sorbent employed.   Amine-based  sorbents,  however, are most commonly
        used.                                                             J

        The feed to the unit is  contacted  with the sorbent,  such as diethanol-
        amine,  in an absorption  column  to  selectively absorb H2S from the
        hydrocarbon gases.   Hydrogen  sulfide is  then  removed from the sorbent
        in a regeneration step.   The  products are a sweet hydrocarbon gas and
        a  concentrated hydrogen  sulfide  stream.   The  sweet gas  may either be
        further processed in light end  recovery  processes or may be charged
        as a raw material to petrochemical  processes.  The hydrogen sulfide
        stream  is normally  routed to  a  sulfur plant for recovery of its sulfur
        content   If there  is  no  sulfur  recovery  plant available, the sulfide
        gas  must be flared  to  produce the  less toxic sulfur oxides.

 2>      Input Materials  - The  sour wet  gas  from  the liquids  recovery process.

        The  sorbent used to  remove hydrogen  sulfide is also a feed to this
        unit.   It is  usually regenerable, and make-up rates are generally
        quite low.  Also required,
       1.2 kg of 5 x 10* ^_ steam per kg of aci(J gas removed-


3-     Operating Parameters - The following conditions are typical  of
       absorber operations:

       Pressure :  10.5 kg/sq cm

       Temperature:  38°C

4.     Utilities -

       Electricity:  .022 kWh/kg removed gas

       Cooling Water:  45-82 liters/kg removed gas

5. .     Waste Streams  -

       .   Sulfur Compounds  - No  atmospheric  emissions,  other  than fugitive
          losses,  are produced from this unit  if  it is  used in  conjunct on
          with a sulfur recovery unit.   If the acid gas  is flared"0there are


                                     37

-------
           atmospheric  emissions of sulfur oxides.  Current information neces-
           sary  for  estimating  the amount of sulfur oxides and other sulfur
           compounds emitted to the atmosphere from acid gas removal processes
           proved  unavailable.

        .   Amine Solutions  - Liquid effluents are produced as spent amine
           solutions which  must be replaced; about 4 liters per 159 m3 (1 gal/
           1000  bbl) for diethanolamine.  The impact on the water treating
           system  may be severe, however, since 40,000 to 80,000 liters may
           be  drained at once.  The amount of waste is proportional to the
           amount  of hydrogen sulfide removed from the gas.


6.     EPA Source  Classification  Code  -  None exists

7.     References  -

       (1)   Nack, H.,  et  al.,  Development of an Approach  to Identification
             of Emerging Technology and  Demonstration Opportunities. EPA
             650/2-74-048,  Columbus, Ohio, Battelle-Columbus Labs., 1974.

       (2)   Radian  Corporation, A Program to Investigate  Various Factors
             in  Refinery Siting.  Final Report, Contract No. EQC  319, Austin,
             Tx.,  1974.

       (3)   "Hydrocarbon  Processing Refining Processes Handbook", Hydro-
             carbon  Proc.  53 (9), (1974).                         .	

       (4)   Processes Research, Inc., Screening Report, Crude Oil  and
            Natural   Gas Production Processes.  PB-222718.  Cincinnati.
            Ohio, 1972.

       (5)   Ecology Audits, Inc., Sulfur Compound Emissions of the Petro-
            leum  Production Industry.  EPA Publication No. fabtyy-JH-nxn,  rialias
            Texas,  1974.
                                     38

-------
NATURAL GAS PROCESSING                                        PROCESS NO. 12
                              Sulfur Recovery
1.     Function - A sulfur recovery plant converts hydrogen sulfide  to
       elemental sulfur by controlled combustion and reactions  occurring
       in a series of catalytic beds.  The feed is first combusted with
       substoichiometric amounts of air to form sulfur and water.  The
       off gas is cooled, and sulfur is condensed as a liquid.   About 60
       to 70 percent conversion occurs in the furnace.

       The remaining gases are reheated and passed through catalytic
       reactors.  Each reactor has an effluent condenser where the elemental
       sulfur  is recovered.  Reheat of reactor effluent is necessary for
       sulfur  recovery in subsequent reactors.  The number of reactors  varies
       with the conversion desired and with the acid gas concentration.
       Normally, two to four reactors are used as only fifty to sixty percent
       of the  remaining sulfur is converted in each reactor stage.

       The unconverted acid gas leaves the process in a tail gas stream and
       is either further  processed or incinerated to remove the last traces
       of reduced sulfur  compounds.  The sulfur recovered by this process
       is sold as a by-product.

 2.     Input Streams - Acid gases from the acid gas removal plant are the
       feed to the sulfur plant.

 3.     Operating Parameters -  The following conditions are  typical of those
       found  in the reactors:

        Temperature:   245°C

        Pressure:   1-2  Atm

        A bauxite catalyst is  most commonly  employed for this process.

 4.      Utilities:

        Heater:  2220  kcal/kg  sulfur

       Steam:   4 kg/kg  sulfur  -  generated in  a waste  heat  boiler

 5.     Waste  Streams  -  The tail  gas  from this unit  represents  the major
        sulfur emissions  in a  gas  processing plant.   Possible sulfur  emissions
       are S02, H2S, COS, CS2, and mercaptans.  After  reaction, most of the
       sulfur  emissions  are in the form  of S02; sulfur dioxide  concentration
        in  the  effluent  tail gas  is approximately  15,000  ppm.   Tail gas clean-
        up  processes are  commercially available  to reduce sulfur emissions.

        Disposal of  the  spent  bauxite catalyst creates  a  solid  waste  problem.
        The magnitude of  this  problem depends  upon the design conversion and
        operating capacity of  the sulfur  plant.

                                    39

-------
6.     EPA Source Classification  Code  -  None exists

7.     References -

       (1)   Radian Corporation,  A Program to  Investigate Various Factors
             in Refinery Siting,  Final  Report,  Contract No.  EQC  31^, Austin,
             Tx., 1974.
       (2)   Nack, H., et al., Development of an  Approach  to  Identification
             of Emerging Technology and Demonstration  Opportunities.  EPA
             650/2-74-048, Columbus, Ohio, Battelle-Columbus  Labs., 1974.
                                     40

-------
NATURAL GAS PROCESSING                                        PROCESS  NO.  13
                                Dehydration
1.     Function - Dehydration removes water from the gas after the acid
       gas removal process.  The required water content is specified as
       the dew point, the temperature at which the water begins to condense.
       The excess water is removed by refrigeration, absorption, or adsorp-
       tion.  Refrigeration processes decrease the temperature below the
       required dew point; the condensed moisture is collected for disposal.
       Absorption processes allow the moist gas to flow over hygroscopic
       materials, usually di- or tri-ethylene glycol.   The use of a solid
       dessicant to remove the water is called adsorption.  Sometimes higher
       molecular weight hydrocarbons are removed in adsorption as well.

2.     Input Materials - Moist wet gas from the acid gas removal process.

       Two to five kilograms of glycol are circulated per kilogram of
       water to be removed in absorption processes.

3.     Operating Parameters - For condensation processes, temperature and
       pressure are interdependent.  For example, if the required dew
       point is 10°C (50°F) at 105,500 kg/sq m (135 psig), and the best
       available cooling is 27°C (80°F), pressures of 33,400 kg/sq m (460
       psig) will give the desired water content.

       For absorption processes using di- or triethylene glycol absorption
       temperatures must be kept below the temperature at which the glycol
       decomposes (164°C for DEG, 207°C for TEG).  Dew point depressions
       of 22-28°C (40-50°F) can be obtained using DEG at atmospheric pres-
       sure and reboiltfr temperatures of 143-160°C (290-320°F); depressions
       of 33-42°C (60-75°F) can be obtained with TEG at reboiler temperatures
       of 177-191°C (350-375°F).  Temperatures in the regenerator, which
       separates the absorbed water from the glycol, usually range from
       190-204°C (375-400°F).  The pH is controlled at 6.0 to 7.5, as low
       pH accelerates decomposition of the glycol.

       Regeneration temperatures for solid dessicants are 249 to 260°C
       (480-500°F).

4.     Utilities - A glycol absorption process requires about 0.1% of the
       fuel produced.

5.     Waste Streams -

       .  Glycol  - An estimated 0.01 m3 of triethylene glycol per 106
          normal m3 of gas processed  (0.1 gal per 106 cu ft.) is emitted
          by the glycol absorption process in vented water vapor.


                                     41

-------
       .   Water - Water contaminated with glycol  may  be  vented as  steam
          or it may be disposed of as a  liquid.

6.     EPA Source Classification Code -  None exists

7.     References -

       (1)   Campbell, John M., "Absorption and  Fractionation Fundamentals",
             Gas Conditioning and Processing, John M.  Campbell, Norman,
             Oklahoma (1970)7

       (2)   Cotterlaz-Rennaz, "New French Gas Cooler Recovers 120 BPD
             Gasoline", World Oil 177 (2), 57-59  (1973).

       (3)   Eckerson, B.  A., A.  L. Johnson, "Natural  Gas  and Natural Gas
             Liquids", Surface Operations in Petroleum Production. George
             V. Chilingar  and Carrol  M.  Beeson,  eds.,  New  York, American
             Elsevier Publishing Co., Inc., 1969.

       (4)   "Gas Dehydration", from "Dehydration and Treating", Engineering
             Data Book, Natural Gas Producers Suppliers  Association  (1972).

       (5)   Hammerschmidt, E. G., K. R.  Knapp,  and C. L.  Perskin  "Gas
             Hydrates and  Gas Dehydration", Gas  Engineers  Handbook.  New
             York, Industrial Press,  1969.

       (6)   Patterson, E. 0. Jr., "Get  Low Dewpoints with Solid Dessicants",
             Oil and Gas Journal  67 (9),  (108-109) 1969.

       (7)   "NG/LNG/SNG Handbook", Hydrocarbon  Processing, April  1973.

       (8)   Processes Research,  Inc., Screening  Report. Crude Oil and
             Natural  Gas Production Processes. PB-222718,  Cincinnati,
             Ohio, 1972.
                                      42

-------
NATURAL GAS PROCESSING                                       PROCESS NO. 14
                            Product Separation
1.     Function - The purpose of this  process  step is  the  separation  of  the
       hydrocarbon components of the dehydrated  gas and  the  hydrocarbon
       liquids from the liquid recovery process.

       Methane is piped to sales; ethane,  propane, and butane  are  stored
       under pressure until  they are shipped to  the refinery as  LPG;  the
       remainder of the hydrocarbons,  known as natural gasoline, are  stored
       at atmospheric pressure to await shipment to the  refinery for
       processing.

       There are several different methods used  in accomplishing this
       separation.  Commonly used processes involve absorption,  refrigerated
       absorption, refrigeration, compression, and adsorption.

       In an absorption process the wet field gas is contacted with an
       absorber oil in a packed or bubble tray column.  Propane and heavier
       hydrocarbons are absorbed by the oil while most of the  ethane and
       methane pass through the absorber.   The enriched absorber oil  is
       then taken to a stripper where the absorbed propane and heavier
       compounds are stripped from the oil.

       The natural gas feed to a refrigerated absorption process must be
       dehydrated to a minus 40°C dew point prior to entering  the  unit.   All
       hydrocarbons except methane are absorbed  by absorber oil  operating
       at this temperature.  These absorbed hydrocarbons and the oil  are passed
       through a series of fractionation columns from which ethane, propane,
       and heavier hydrocarbons are removed as product streams.

       In refrigeration, a cryogenic process, the natural  gas  must be dried
       to a dew point of minus 101°C or lower  using molecular sieve beds.
       The dry gas is then passed through a heat exchanger where it is cooled
       to minus 37°C.  Condensed hydrocarbons are removed in a gas-liquid
       separator.  The gas from  the separator is cooled to minus 93°C and
       passed through a second separator where more condensed liquids drop
       out.  The liquids from two separators  are fed to a series of distil-
       lation columns where methane, ethane,  propane, butanes, natural
       gasoline, and other products are recovered.

       A compression process uses two stages  of compression, each  followed
       by cooling  and gas-liquid separation,  to produce a wet natural gas
       product and natural gasoline.  This  is not a widely  used process.
                                     43

-------
       The adsorption processes consist of two or more beds  of activated
       carbon.  The beds are used alternatively,  with one  or more  beds  on
       stream while the others are being regenerated.  The activated  carbon
       adsorbs all hydrocarbons except methane.   The bed is  regenerated by
       means of heat and steam, which remove the  adsorbed  hydrocarbons  as a
       vapor.  This vapor is then condensed permitting the water to be
       separated from the liquid hydrocarbons. The resulting hydrocarbon
       product is fed to a fractionation process  where the various components
       are separated.

2.     Input Material - Liquid hydrocarbons from  the liquids recovery process
       and wet gas from the dehydrator.

3.     Operating Parameters - Inlet gas and oil temperatures for absorbers
       and refrigerated absorbers:

           Water cooled:  32-38°C

           Propane cooled:  minus 40° - minus 18°C

           Pressures in the absorbers may be as high as
           2.8 x 10  kg/sq m (400 psi), but are usually lower.

           The temperatures, pressures, and molecular weights of absorber
           oils are generally controlled to give  maximum recovery.

       The refrigeration process temperature is minus 37°C to minus 93°C.

4.     Utilities - 2-3% of the methane produced.

5. "    Waste Streams - Fugitive emissions only from leaking  pumps  and
       valves.

6.     EPA Source Classification Code - None exists

7.     References -

       (1)   Houghton, J. and J. D. McLay, "Turboexpanders Aid Condensate
             Recovery", Oil and Gas Journal 71 (10), 76-79 (1973).

       (2)   Eckerson, B. A. and A. L. Johnson, "Natural  Gas and Natural
             Gas Liquids", Surface Operations in  Petroleum Production,
             George V. Chilingar and Carroll M. Beeson, eds., New  York,
             American Elsevier Publishing Company, Inc., 1969.

       (3)   "NG/LNG/SNG Handbook", Hydrocarbon Processing,  April, 1973.

       (4)   Petroleum Extension Service, Plant Processing of Natural Gas,
             Austin, Texas, The University of Texas at Austin, 1974.
                                     44

-------
(5)    Cavanaugh,  E.  C.  et al., Atmospheric Environmental Problem
      Definition  of  Facilities for  Extraction, On-Site Processing,
      and Transportation of Fuel  Resources, EPA Contract No.
      68-02-1319, Task  19, Austin,  Texas, 1975.
                             45

-------
NATURAL GAS PROCESSING                                        PROCESS  NO.  15
                                LPG Storage
1.     Function - The purpose of LPG storage is  to store  the  liquified
       petroleum gas (LPG) before it is shipped  to the  refinery  or  to
       sales.  Because the vapor pressure of LPG is high  enough  that it
       could vaporize at atmospheric pressures,  it must be  held  in  pressure
       vessels.  The ethane, propane, and butane from the separation process
       may be stored together or separately.  LPG is generally propane,  but
       it may contain some ethane and butane.

       An alternative to storing LPG under pressure is  handling  it  at
       reduced temperatures.  Refrigerated LPG may be stored  in  insulated
       pits or in underground formations.

2.     Input Materials - The ethane, propanes, and butanes  from  the gas
       separation process

3.     Operating Parameters -

       Pressure vessels:

           Temperature:   ambient

           Pressure:  1.0 x 10s kg/sq m (250 psigv)

4.     Utilities - Those required to pump the LPG.

5.     Haste Streams - Loading and unloading losses encountered

6.     EPA Source Classification Code - None exists

7.     References -

       (1)   Eckerson, B. A. and A.  L.  Johnson,  "Natural  Gas  and Natural
             Gas Liquids", Surface Operations  in Petroleum  Production,
             George V. Chilingar and Carrol  M. Beeson,  eds.,  New York,
             American Elsevier Publishing Company, Inc.,  1969.

       (2)   Nack H., et al., Development of an  Approach  to Identification
             9f-E?e-^-9_Te_nPo1ogy and Demonstration Opportunities, EPA
             650/2-74-048, Columbus, Ohio, Battelle-Columbus  Labs., 1974.

       (3)   Environmental Protection Agency,  Compilation of  Air Pollutant
             Emission Factors, 2nd.  ed.,  AP-42,  Research  Triangle Park,  N. C.,
             T973~:
                                     46

-------
(4)    Radian  Corporation, Study on  Control of Hydrocarbon Emissions
      from Petroleum Liquids, EPA Contract No. 38-02-1319, Task 12,
      Austin, Texas,  19/5.
                              47

-------
NATURAL GAS PROCESSING                                        PROCESS  NO,  16
                             Gasoline Storage
1.     Function - The purpose of gasoline storage is  to  store  the natural
       gasoline from the product separation process before it  is  shipped  to
       sales or to the refinery.  The capacity of the storage  tanks  used
       varies with the size of lease concerned.   The  tanks may be fixed
       roof, floating roof, or variable vapor space types.

2.     Input Materials - Natural gasoline from gas separation

3.     Operating Parameters - Temperature and pressure are usually ambient.

4.     Utilities - Those required to pump the gasoline.

5.     Waste Streams - Gasoline storage emission factors are given in
       Table 4.

       Table 4.   HYDROCARBON EMISSION FACTORS FOR GASOLINE STORAGE
         Type of Tank       	Emission Factor
       Floating Roof

         Standing losses                   10.5 g/day-103&
                                           (0.088 lbs/day-103 gal)

       Fixed Roof

         Breathing losses                  30 g/day-103
                                           (0.25 lbs/day-103 gal)
         Filling losses                    1.1  g/2,
                                           (9.0 lb/103 gal)

       Variable Vapor Space
         Filling losses                    1.2 g/£
                                          .(10.2 lb/103 gal)

       Vapor recovery systems are available for compressing and recycling
       gaseous emissions from tanks.

6.     EPA Source Classification Code - None exists
                                      48

-------
7.      References -
       (1)    Eckerson, B. A. and A. L. Johnson, "Natural Gas and Natural
             Gas Liquids", Surface Operations in Petroleum Production,
             George V. Chi linger and Carrol M. Beeson, eds., New York,
             American Elsevier Publishing Co., Inc., 1969.

       (2)    Nack, H. et al., Development of an Approach to Identification
             of Emerging Techno"!pgy and Demonstration Opportunities, EPA
             650-2-74-048, Columbus, Ohio, Battelle-Columbus Labs., 1974.

       (3)    Environmental Protection Agency, Compilation of Air Pollutant
             Emission Factors, 2nd. ed., AP-42, Research Triangle Park,
             N. C., 1973,
                                     49

-------
SECONDARY AND TERTIARY RECOVERY TECHNIQUES


When a producing well  decreases its production it is  either plugged  and  its
production stopped, or stimulated so that production  will  be increased.   The
problems causing loss  of production fall  into three major  areas.   One  major
problem, loss of formation pressure, is  solved by displacement  processes.
A second problem, low permeability of the formation,  occurs when  the forma-
tion is packed so tightly that the oil  cannot flow through it.  This is
corrected by an acid treatment or by fracturing to increase the permeability.
The third major problem occurs when the  oil  is too thick,  or viscous,  to
flow easily.  The viscosity of oil depends strongly on temperature,  however,
and when the oil is heated, the viscosity drops so that the oil can  flow
easily.  These four methods of treatment, displacement, fracturing,  acid
treatment, and thermal treatment, are discussed in this section.
                                       50

-------
SECONDARY AND TERTIARY RECOVERY TECHNIQUES                    PROCESS NO.  17
                               Displacement
1.     Function - After reservoir pressures have dropped, the displacement
       method is used to.increase production by injecting water or gas  into
       the formation under pressure.  In 1968, an estimated 33% of the  oil
       production in the United States was by water flooding, and it has
       been further projected that by 1980 this figure will rise to 50%.

       In water flooding, water is injected into the formation under pressure
       via an injection well.  Production water may be used, but it must
       first be treated to prevent corrosion and chemical deposits from
       occurring in pipes or machinery.

       In gas injection, gas is injected under high pressure via the injection
       wells to displace the crude out into the production well.  The gas
       supply is often production gas.

 2.     Input Materials - Not applicable

 3.     Operating Parameters  -

       .  Pressure - often about 1.8 x 10" kg/m2 (25 psi) + formation
          pressure, but variable.

       Phillips Petroleum Co., at their North Sea Ekofisk field complex,
       injects up  to 1.4 x 107 m3 (5 x 108 cu ft.) per day of gas at
       6.5 x 106 kg/m2 (9200 psi), but this is an unusually high pressure.

       Shell Co.,  at their Ventura  field waterflood program, uses a four
       plant system with a 3.5 x 10" cu m/day  (220,000 b/d) capacity at
       injection pressures of 1.4 -  3.5 x  106  kg/m2 (2000-5000 psi).

 4.     Utilities - At  Ekofisk, Phillips Petroleum uses for compression
       equipment six units,  totalling  82,000  kW  (110,000  hp), driven by
       gas  turbines.   At  the separation plant are two multi-stage com-
        pressors, each  connected  to  7600 kW (10,200 hp) General Electric
        frame  3,  two shaft  gas  turbines.   At  the  injection platform  are
        four compressors,  each  driven by a  geared GE frame 5  gas  turbine
        rated  at 16,000 kW  (22,000 hp)  each.   Main and spare  seal oil pumps
        each require  a  186  kW (250 hp)  motor.

        At the Shell  Co.  Ventura  field Waterflood Plant 4 (WP-4),  two 3400 kW
        (4500 hp)  electric motor  driven double cased diffuser centrifugal
        pumps are used  to  give  a  designed  capacity of  9500 cu m/day  (60,000
        b/d)  at 3.5 x  106  kg/sq m (5000 psi).   At WP-2, eight 447 kW (600 hp)
        vertical  quintuplex plunger  pumps  give a  designed capacity of 9500
        cu m/day (60,000  b/d) at  2.8 x 106  kg/sq  m (4000  psi).

                                      51

-------
5.     Waste Streams - None

6.     EPA Source Classification Code  -  None exists

7.     References -

       (1)   "Pioneering Ekofisk System  to  Inject  Gas  at 9200  psi",
             Petroleum Engineer International,  Vol. 46, No.  2,  February,
             1974, pp. 32-34,  36.:

       (2)   Blanton, M.  L. "Shell  Extends  Ventura Flood to  5000 psi",
             Petroleum Engineer International,  Vol. 46, No.  9,  August,
             1974, pp. 24-26.  	                   y

       (3)   Petroleum Extension Service Industrial and Business Training
             Bureau, A Primer  of Oil Well Drilling, Austin,  Texas (1975).
                                     52

-------
SECONDARY AND TERTIARY RECOVERY TECHNIQUES                    PROCESS  NO.  18
                                Fracturing
1.     Function - The fracturing technique is used to increase production of
       oil from sandstone by increasing the permeability of the formation.
       This is done by forcing a sand and fluid suspension into the formation
       under high pressure, literally cracking it open.   After the formation
       has been opened, the fluid is pumped out, leaving the sand to hold
       the cracks open.  This process increases the permeability of the for-
       mation, enabling oil and gas to flow into the well.

2.     Input Material - Usually a sand and fluid suspension.  In three wells
       in West Texas, for example, the following input materials were used.
       Well A, Crocket County, Texas:  9.5 cu m (2500 gal) LPG-C02 as pad
       volume, then  130 cu m  (34,000 gal) 1:1:1 Gas Frac fluid containing
       11,000 kg  (24,000 Ib)  of 20-40 mesh sand, then flushed with 9.5 cu m
       (2500 gal) 1:1:1 Gas Frac  fluid with no sand.

       Well B, Sutton County, Texas:  7.6 cu m  (2000 gal) LPG-C02 pad volume,
       85  cu m (22,500 gal) 1:1:1 Gas Frac fluid containing 900 kg (2000
       Ibs) 40-60 mesh sand and 10,000 kg (22,800  Ibs) 20-40 mesh sand, then
       flushed with  LPG-C02 mixture.

       Well C, McCullough  County, Texas:  17 cu m  (4500 gal) LPG-C02 mixture
       pad volume, 53 cu m  (14,000  gal)  1:1:1 Gas  Frac fluid containing
       7000 kg (15,000 Ibs) 20-40 mesh sand,  flushed with  17  cu m  (4500 gal)
       LPG-C02 mixture.

3.     Operating Parameters -

       .    Pressure - variable

           For example, in three West Texas wells mentioned above the fol-
           lowing pressures  were  used:


          Well  A - Average injection rate 3 cu m/min (19 bbl/min)  at
                   3.5 x 10s kg/sq m

          Well  B - Average injection rate 2 cu m/min (12.5 bbl/min)  at
                   2.1 x 106 kg/sq m

          Well  C - Average injection rate 1.9 cu m/min (12 bbl/min)  at
                   8.4 x 105 kg/sq m


4.     Utilities - Power for compressors
                                    53

-------
5.     Waste Streams - The danger of groundwater contamination exists  if the
       casing fractures, or if the formation  forms  a  communication with a
       water bearing formation.

6.     EPA Source Classification Code - None  exists


7.     References -

       (1)   Hurst, Robert E., "Designing  Successful  Gas Frac Treatments",
             Petroleum Engineer International,  Vol. 45, No. 7, July, 1972,
             pp. 67 ff.

       (2)   Petroleum Extension Service Industrial and Business Training
             Bureau, A Primer of Oil  Well  Drilling, Austin, Texas (1975).
                                     54

-------
SECONDARY AND TERTIARY RECOVERY TECHNIQUES                    PROCESS  NO.  19
                              Acid Treatment
1.     Function - Acid treatment is used to increase production by increasing
      .the porosity of carbonate rock formations.   In the process, quantities
       of acid ranging from fifty to thousands of  gallons are pumped into
       the well under pressure.  The acid then travels out into the forma-
       tion, dissolving the rock to allow the oil  to travel  into the well
       more easily.

2.     Input Materials - HC1 and sometimes other acids.  An example of a
       mixture might be 12% HC1 with 3% HF.  Proposed acid volume:  if 28%
       HC1 is used, 1.5 times the volume contained within the fracture be-
       tween the well bore and maximum acid penetration distance; if 15%
       HC1 is used, three times the fracture volume.  Increasing acid
       concentration from 15-28% HCT increases penetration distance.  At
       93°C (200°F), dolomite formation distance can be increased from 38
       to 54 m (127 to 178 ft.) by using 28% HC1 instead of 15%.

3.     Operating Parameters - Pressure is approximately 1.8 x 10* kg/sq m
       (25 psi) +  formation pressure.  The temperature at which the acid
       reaction occurs affects the depth of acid penetration.  For example,
       an increase in temperature 38 to 140°C  (100 to 220°F) could decrease
       penetration for 15% HC1 from 37 to 25 m  (120 to 82 ft.) in limestone.
       and from 87 to 37 m  (285 to 120 ft.) in dolomite.  Similarly, a pad
       that would  reduce the reaction temperature of 28% HC1 in a dolomite
       treatment from 140 to 66°C (220 to 150°F) would increase the penetra-
       tion distance from 54 to 67 m (177 to 220 ft.).

       Increased injection  rate increases acid  penetration, but at rates
       greater than approximately 0.5 cu m/min/m (1.0 bbl/min/ft.), penetra-
       tion distance approaches a maximum.


4.     Utilities  - Power for  compressors

5.     Waste  Streams  - The  corrosive nature of the  fluid  used  causes  an
       increased  possibility  that  casings  may  fracture and  allow  ground-
       waters  to  become contaminated.

6.     EPA Source  Classification Code  -  None  exists

7.     References

        (1)    Petroleum Extension Service Industrial  and  Business  Training
              Bureau,  A Primer of Oil Well  Drilling,  Austin, Texas (1975).
                                      55

-------
(2)    Williams, B. B., and D. E. Nierode, "Design of Acid Fracturing
      Treatments", Journal of Petroleum Technology, Vol.  24,  July,
      1972,  pp. 849-859.
                                56

-------
 SECONDARY AND TERTIARY RECOVERY TECHNIQUES                    PROCESS NO. 20
                             Thermal Treatment


 1.     Function - Thermal treatment increases production by heating the oil
       through processes such as steam injection, hot water injection, and
       in situ combustion..  The heat reduces the viscosity of the oil  so
       that it can flow more easily.

       Hot water and steam injection heat the oil by direct contact
       and also displace the oil, causing higher flow rates.

       In situ combustion is accomplished by pumping air down the hole and
       then setting fire to the oil.  This process burns 5-10% of the  oil,
       causing temperatures as high as 1,500°C and increasing production
       from 10% to more than four times primary production levels.

 2.     Input Materials -

       For hot water injection - heated water

       For steam injection - steam from on site boiler, about 0.8-0.95 quality

       For in situ combustion - air

 3-     Operating Parameters - For steam or hot water injection, the temperature
       used depends on the properties of the oil  in the formation.   The pres-
       sure used also varies,  but will  generally  be 1.8 -  2.1  kg/m2 (25-30
       psi)  greater than the formation pressure for all  the thermal  processes.
       For example, CIA Shell  de Venezuela uses average well-head steam injection
       pressures of 6.7 - 70  x 10s  kg/m2  (950-1000 psi)  from their high-pressure
       plant and 5 - 6 x 10s  kg/m2  (700-800 psi)  from their low pressure plant
       at a temperature of 260°C (500°F),  while Amoco  Production in Winkleman
       Dome,  Fremont County, Wyoming,  uses a normal  injection  pressure  of  8 1 x
       10s kg/sq m (1150 psi).

4.     Utilities - For in situ  combustion, compressors  for injecting air are
       needed.For steam and  hot water injection,  power for compressors and
       boilers  is  required;  for example,, for their  steam project at Lombardi,
       Mobil uses  approximately  79 cu m of fuel oil, or crude,  for each 1000
       cu  m of steam  generated  (80 bbl/1000  bbl steam).  For a  rate of 3000
       cu  m (20,000 bbl) steam/day,  fuel consumption is around  254 cu m/day
       (1600 b/d).
                                      57

-------
       Amoco Production at Winkleman  Dome  uses one steam generator rated
       at 9000 kg/hr {20,000  Ib/hr) and  two  at 10,000  kg/hr  (22,000 Ib/hr),
       for a total  capacity equivalent to  664 cu m water/day  (4180 bw/d).

5.      Waste Streams - Fugitive  emissions  from boilers and compressors.

6.      EPA Source Classification Code -  None exists

7.      References -

       (1)   Bleakly, W. B.,  "Mobile  Eyes  Steaming Success at San Ardo",
             Oil  and Gas Journal, Vol. T[, No. 52, December  24, 1973,
             pp.  40-43.

       (2)   Giusti, Luis E., "CSV Makes Steam Soak Work in  Venezuela
             Field", Oil and  Gas Journal,  Vol. 7^, No. 44, November 4,
             1974,  pp. 88-93.

       (3)   "Winkleman Dome  Steam-Drive Project Expands", Oil and Gas
             Journal, Vol. 72, No. 42, October 21, 1974, pp.  114-120.

       (4)   Smith, C. R., Secondary  Oil Recovery, Reinhold  Publishing
             Co., New York (1966).

       (5)   Petroleum Extension Service Industrial and Business Training
             Bureau, A Primer of Oil  Well  Drilling, Austin,  Texas  (1975).
                                      53

-------
            APPENDIX A




CHARACTERISTICS OF U. S.  CRUDE OILS
                59

-------
       Table  A-l.    PROPERTIES  OF UNITED STATES CRUDE OILS
State
Field
' Alabama
Citronelle (Rodessa, L. Cre.)
Alaska
Swanson River (Hemlock, Eoc.) 	 	
Arkantat
Magnolia (Reynolds-Sraackover, Jur.) 	
Midway (Sraackover, Jur.) 	
Scliuler (Jones & Cotton Valley Jur.)
Sroackover (U. Cre.)
California
Belgian Anticline (Oceanic, Olig.) 	
belriilice. South (Tulare, Plio.-Pleist.)
Br™ Olinda (Mio.) . .
Bueno Vista (27-B Banal Etchegoin. Plio.)
Castaio Junction (Zone 10, Mohnian, Mio.)
Coalinga, East (Main Gatchell, Eoc.) 	
Coalinga Nose (Gatchell, Eoc.) 	
Coalinga, West (Temblor, Mio.)
Coles Levee, North (Mio.) 	
Coyote, West (Emery, Repetto, Plio.) ....
Cuyama, South (Dibblee, Mio.) 	
Cymric (McKtttrick Croup, Tulare, Plio.-
Pleiat.) 	


Elk Hilla (Shallow U. Plio )
Fruitvale (Chanac, Plio. -Mio.) 	 	
Gosford, East (Middle & Lower-Stevens,
Mio.) 	
Greeley (Rio Bravo- Vedder Mio)
Guijarral Hills (Leda Olig.) 	

Huntington Beach (S. Main area, Mio.) . . .
Kern Front (Chanac Plio.-Mio.) 	
Kern River 1 Kern River, Plio.-Pleist.) 	
Kettlernan North Dome (Temblor, Mio.) . .
Long Beacli (Alamitos, Repetto, Plio.) ....
Midway-Sunset (Plio.-Pleist.) 	
Montalvo, West (Colonia, Sespe, Olig.) . . .
Newhall-Potrero (Modelo, Mio.) 	
Oxnanl (Mclnnes, Sespe, Olig.) 	
Rincon (Plio.) 	

Russell Ranch (Dibblee, Vaqueros, Mio.)..


Santa Fe Springs (Buckbee, Plio.) 	

Seal Beach (McGrath Mio.) 	


Torrance (Del Amo Mio )
Ventura (Pico-Repetto, Plio.) 	
Wheeler Ridge (Eoc )
Wilmington (Harbor area, Terminal, Mio.)
Colorado
AJena (Dakota "J", Cre.) 	



Grav-
ity,
'API
43 6
29 7
38.4
36 6
32 8
22 5
35.0
1.1 0
24 0
30.6
19.0
17 5
28.8
31.5
20 2
34.0
32.3
32.5
12 7
29 9
25.2
22 8
17.5
34.0
37 2
36.8
37.6
22.6
18 1
14.8
12.6
34.0
22.6
21.6
17.3
16.0
32.7
25 . 7
22 6
28.2
38.6
35.2
11.1
29.7
28 6
32.8
14.7
31.7
23 3
40.0
23 8
31.3
37.0
22.3
44.7
34 8
48.1

Sulfur,
wt.
per cent
0 38
0 16
0.90
1 36
1 55
2 10
0.59
0 23
0 75
0 . 59
3.40
5 07
0.31
0.25
0 55
0 39
0.82
0.42
1 16
0 40
0 2O
0 68
0.93
0.57
0.31
0.63
0.40
1.57
2.50
0.85
1.19
0.40
1.29
0.89
4.10
0.68
0 . 56
1.72
1 86
1.40
0.35
0.35
2.25
0.83
0.87
0.33
4.99
0.55
2.79
0.16
1.84
0.94
0.29
1.33
<0.10
0 5G
0.12

Viscos-
ity,
SU5 at
100'F
40
61
38
42
52
220
40
2 440
135
46
1,230
3 000
67
48
195
43
50
49
6 000
60
US
135
1,750
51
41
40
37
210
680
5,100
6,000
44
208
210
7,648
1,900
46
95
230
80
38
43
6,000
59
63
47
6,000
52
220
35
160
56
38
210
36
48
33

Source:
From Petroleum Processing Handbook edited by W.  F.  Bland
and R. L. Davidson, Copyright (Q 1967 by McGraw-Hill,  Inc.
Used by permission of McGraw-Hill  Book Company.
                              60

-------
Table A-l (Continued).  PROPERTIES OF UNITED STATES CRUDE OILS
State C
Field
Illinois
Clay City (Miss ) 	





Salem (Aux Vases Miss ) 	
Indiana
Kan sat




Seely-Wick (BartlcsviUe Pean.) 	


Louisiana


Rftv Mnivhand 13900' Mio ) 	


Black Bay West (730CK Mio.) 	
Black Bay West (8050' Mio.) 	
Black Bay West (8300' Mio ) 	













Eugene Island (Block 32. 7500', Mio.) . . .
Eugene Island (Block 188, 9080', Mio.) . .


Grand Isle (Block 16. B-l, Seg. E, Plio.) .











Little Lake (Textularia Panamengis 1, Mio
Little Lake (Textularia Panamensis 2, Mio
Little Lake (Textularia Panamensia 6, Mio
3rav-
ity.
'API I
38.6
36.4
35.6
36.2
36.0
37.4
37.2
35.2
34.6
38.8
36.8
39.4
43.0
41.1
23.5
39.2
34.4
38.2
33.6
20.2
33.6
36.2
30.0
23.0
30.6
34.4
35.2
34.4
36.8
35.4
39.2
33.6
40.6
31.9
41.7
35.6
36.4
31.0
39.2
36.2
27.1
34.8
37.6
35.0
. 36.4
. 34.6
. 33.6
. 31.3
. 54.9
. 36.2
. 40.4
. 34.6
. 35.4
. 28.2
. 35.4
. 32.1
. 32. J
.) 31.7
.) 36.2
.) 46.:
1
Sulfur,
wt. £
jer cent
0.19
0.15
0.21
0.22
0.23
0.20
0.17
0.20
0.57
0.44
0.18
0.34
0.27
0.23
0.93
0.41
0.12
0.15
0.27
0.46
0.39
0.16
0.27
0.36
0.26
0.18
0.17
0.19
0.37
0.23
<0.10
0.16
<0.10
0.38
<0.10
0.26
0.14
0.20
<0.10
0.19
0.35
0.22
0.18
0.31
0.18
0.22
0.23
0.29
<0.10
0.30
0.14
0.21
0.14
0.37
0.2C
0.27
0.28
0.27
O.lf
\ 
-------
Table A-l (Continued).  PROPERTIES OF UNITED STATES CRUDE OILS
Sinli
Field
Little Lake, South (Textularia PanamensiB
1 "D", Mio.) 	
Main Pass (Block 69, Mio.) 	



Ship Shoal (Block 154 Mio.) 	
South Pane (Block 24. Mio.) 	
Timbulier Bay (Mio.) 	

Weeks laland (Mio.) . . . . . . .
West Bay (Mio.) 	
West Delta (Block 30, Mio.) 	
West Delta (Block 53, KE, U. Mio.) 	
West Delta (Block 83 KE, U. Mio.) 	
Michigan
Albion (Trenton- Black River Ord.)
Afiifftaaippt
Baxter vi lie (L. Tuscalooaa, U. Cre.)

Bryan (Rodessa L. Cre ) ...
Heidelberg (U Tuacalooaa U. Cre.)
Little Creek (L. Tuacaloosa, U. Cre.) 	
Raleigh (Hoaston, L. Cre.) 	 	
8oao U 1.701 Bailey, Rodeaaa, U Cre.) 	
Tinstey (Selma U. Cre ) 	
Montana
Cut Bank (Cut Bank L Cre ) ....
Pine (Dev.) 	


New Mexico
Biati (Gallup Cre.) 	 	
Caprock. East (Wolfcacop, Perm.) 	
Eunice-Monument (Grayburg, Perm.). . .
Hobbs (San Andres Perm.) 	
Jalraat (Yates Perm.) 	







North Dakota
Beaver Lodge-Tioga (MiBaion-Canyon,
Ord ) . 	
Blue Butte (Madison Miss.) 	

Oklahoma
Bradley (Springer. Peon. & Cunningham
Mi*ui ) • - • •

Ctmenl (If. Melton. Ftnn.). 	 	 	 	 	
Kulu-Krjbberaon (Hmml'le, M. Ord.) 	
K/>la-l{itbl»»wjn (Oil Creek. L. Ord.) 	
Gulden Trend
Antioch. Southwest (Gibovn, Miw.) . . .
Grav-
ity,
"API
34.8
30.6
36 0
31.9
37 4
2V. 1
32.3
34.4
37.6
33.2
32.1
27.0
32.3
35.0
41.9
17.1
35.0
37.2
23.3
38.0
45.8
41.1
30.4
33.4
39.0
33.8
39.6
29 . 6
37.6
43.2
46.0
28.8
42.1
37.4
36.2
36.4
28.9
39.4
38.6
41.7
35.0
39.6
42.8
46.0
41.1
41.3
35.0
30.6
3.1.2
42.1
:t!l.8
3H.O
37.4
42.1
Sulfur,
wt.
per cent
0.26
0.25
0 23
0.27
0 ^0
0.36
0.26
0.33
0.24
0.19
0.27
0.33
0.43
0.37
0.10
2.71
0.43
1.47
3.75
0.16
0.43
0.89
1.02
0.60
0.85
0.36
0.32
0.6S
0.18
0.17
0.17
0.97
0.10
1.41
1.22
0.12
1.65
0.36
0.70
0.11
0.95
0.12
<0.10
0.23
0.52
0.31
0 22
0.24
0.47
0.22
O..T.ri
O.U7
O.31
0.11
Viscos-
ity,
SUSat
100°F
49
61
41
52
44
78
Gl
43
41
51
64
02
66
48
44
1,480
50
47
370
43
58
41
79
47
38
55
38
72
40
35
35
54
35
41
47
35
64
36
37
34
42
39
32
34
34
35
56
43
56
38
41
VI
VI
39
                               62

-------
Table A-1 (Continued).  PROPERTIES OF UNITED STATES CRUDE OILS
Stall
Field

NRW Hope. Southeast (fiibnon. Miau.) ...


Joiner City (Bois D'Arc. Sil.-Dcv.) 	
Knox (Dornick HHIa Penn ) 	


Sho-Vel-Tum District

Milroy (Deese Penn.) 	
Sholem. A lee hem (Springer. Perm.) 	
Velma (L. Dornlck Hills, Springer. Penn.)
Pennsylvania
Bradford (U Dev ) 	
Texo*
Anahuac (Marg No I Olig.) 	



Andrews North (Dev.) 	



Bakke (l>*v ) 	

Dakke (Penn ) 	
Bakke (Wolfcamj> Perm ) 	

Block 3L (Dev ) 	


Borregoa (N-1*! Frio Olig.) 	
Borregos (R-13 Vicksburg Olig.) ....





Cowden, South (Grayburg, Perm.) 	

Diamond "M" (Canyon Reef, Perm.)...
Dollar hide (Clear Fork Perm ) 	
Dollar-hide (Dov.) 	

Dollarliide (Sil ) • 	
Dollarhkle, Kast (Ellen.. Cambro-Ord.) ,
Kant 'IVxas (Woodbine U Ore.) .....


Km inn ((*rnybur(fr-Sun Andrw*. l'«rm.) . . .
Kmiieror, !>M:II (S*t»:n Uivcru, Quettn.
jVrtn ) 	


art , m mrne ( em,
Fuhnnan-Mascho (Grayburg. Perm.) . . . .

Fullcrtoii, South (Wolfcamp. Perm.).. • •
— T
rav-
ity,
API
42.1
41.1
40 . 5
28. «
37.0
40.4
43.0
39.8
37.6
28.0
36.0
30.0
26.8
21.0
29.1
41.1
33.2
43.2
39.0
36.8
44.3
4S.2
44.7
30.8
44.7
45 C
39.4
37.4
41.5
44.5
42.1
40.6
42.3
38.2
39.0
41.7
37.0
30.4
36.6
34.6
36.6
36.8
45.4
37.4
38.2
41.5
41.3
42.3
29.7
37,4
45. U
4U.2
4!l.O
35 . 0
. 45.0
44.1
. 34.2
. 31.3
. 39 . 6
. 41.5
. 43.4
	 |-
Sulfur,
wt.
;>er cent
0.14
O.l'.i
0.14
0.112
0.00
0.47
<0.10
0.25
0.16
1.41
0.57
1.73
1.44
1.68
1.36
0.11
0.23
0.22
0.11
0.78
0.30
0.11
<0.10
0.10
0.1A
0 2t
<0.10
0.41
0.23
0.18
<0.10
<0.10
<0.10
<0.10
<0.10
0.38
<0.10
1.89
0.96
1.77
0.76
0.78
0.20
0.42
0.57
0.23
0.36
0.10
3.11
0.25
<0.10
<0.10
:<
37
44
47
40
38
36

-------
Table A-1 (Continued).  PROPERTIES OF UNITED STATES CRUDE OILS
State
Field
Gillock (HudKinga Frio, Olig.) . ...
Gillock, South (Frio, Olig.) 	
Goldsmith (5600', 0. Clear Fork. Perm.)..
Goldsmith (Clear Fork-Tubb. Perm.) 	
Goldsmith (Dev.) 	

Goldsmith, East (Holt, Perm.) 	
Goldsmith, North (Kllea, Cam.-Ord.) 	
Goldsmith, West (U. Clear Fork, Perm.) . .
Goldsmith, West (Ellen. Cam.-Ord.)
Goldsmith, West (Fusselrnan, Sil.) 	
Goldsmith, West (San Andres. Perm.) 	
Goose Creek (Frio, Oils.) 	

Hastings, East (Frio, Olig.) 	
Hastings, West (Frio Olig )
Hawkins (Eagle Ford, V. Cre.) 	 	
Headlee (Dev.) 	
Headlee (Ellen. Cam -Ord )
High Island (Mio.) 	
Howard-Glasscock (Yates Perm.) 	
Hull (Caprock, Mio.) 	
Jameson (Strawn, Penn.) 	
Jameson (Strawn Reef, Penn.} . 	
Jo-Mill (Spraberry, Perm.) 	
Jordan (Ellen., Cam.-Ord.)
Jordan (San Andrea, Perm.) 	
Kelly-Snyder (Canyon Reef, Penn.)
Kelny (Frio, Olig.) 	
Kelsey South (18-A. Frio Olig )
Kermit (Ellen.. Cam.-Ord.) 	 	
Kermit (Yates and Seven Rivers, Perm.)..
Kermit, South (Dev.) 	
Keystone-Colby (Queen, Perm.) 	

Keystone- Ellenburger (Ellen., Cam.-Ord.).
Keystone-Silurian (Sil.) 	
KMA (Strftwn Penn.) 	
Lake Pasture (FT-569, Frio-Sinton, Olig.).
Lake Pasture (H-440, Greta, Olig.) 	

Liberty. South (EY, Olig.) 	 	 	

Magutex (Dev.) 	
Magutex (Ellen. Cam.-Ord.) 	



Means East (Strawn, Penn.) 	
Midland Farms (Ellen., Cam.-Ord.) 	


Midland Farms, North (Grayburg, Perm.).
Midland Farms, Northeast (Ellen., Cam.-
Ord.) 	
Old Oc*an (Armstrong Frio Olig.) 	
Old Ocean (Chenuult, Frio Olig.) 	


1'eKORus (Penn.) 	

Pen well (Ellen., Com.-Ord.) . . : 	
Penwell (Ban Andres, Perm.) 	

Plymouth (610CK Frio, Olig,) 	


Grav-
ity,
"API
45 2
38 0
38.0
38 0
40 9
38 4
36 4
37 0
37.4
42 6
37 4
34.4
35.0
31 5
31.0
30 2
26.8
47 4
81 1
27.3
30 6
31 1
40 9
44 3
37 4
43 1
33 2
30.8
40 0
43 4
41.8
36.8
32.3
34.2
32.7
42.1
37.8
35 4
40 0
37.2
23.7
31.1
36.4
28.6
40.2
46.9
31.5
30.0
35.6
43.0
50.6
31 7
39.6
30.0
49.2
36.8
25.4
40.4
53.0
4S.4
35.6
41.7
33.2
37.2
42.3
40.6

Sullur,
wt.
per cent
<0 10
0 11
0.52
0 57
0 16
1 16
0 15
0 58
0.53
0 32
0 96
1.38
0.13
0 15
0.15
0 17
2.19
<0 10
<0 10
0.26
1 18
0 35
<0 10
<0 10
0 11
0 28
1 4g
0 22
0 13
<0 10
0.19
0.94
0.79
0.95
0.69
0.13
0.63
0 49
0.31
0.13
0.20
2.12
0.14
0.86
0.30
0.12
2 37
2.40
1.11
O.JO
<0.10
2 04
0. 13
2.37
<0.10
0.14
0.21
0.55
<0.10
<0.10
0.17
0.24
1.69
0 12
0 12
0.13

Viscos-
ity,
SVS at
100°F
34
38
46
44
40
40
5y
44
44
39
43
43
42
48
55
58
135
37
35
79
61
41
34
36
43
38
46
37
33
34
39
42
81
48
68
40
43
51
39
35
60
48
40
90
38
39
53
54
46
35
34
46
40
53
38
43
71
47
33
36
48
40
45
39
3-1
37

                              €4

-------
Table A-l (Continued).  PROPERTIES OF UNITED STATES CRUDE OILS
State
Field
Plymouth (Greta, Frio, Olig.) 	
Plymouth (Main Greta, Frio, Olig.) 	
Portilla (7100', Frio. Olig.) 	
I'ortilla (7300', Frio. Olift.) ... .
Portilla (7400', Frio, Olig.) 	
Portilla (8100', Frio, Olii?.)
1'rentice (B70O', Clear Fork, Perm.) 	
Prentice (Glorieta, Perm.) 	

Quitrnan (Sub-Clarkaville, U. Cre.) 	
Quitmau (Trinity, L. Cre.) 	
Robertson (L. Clear Fork, Perm.) 	
Robertson (San Angelo-Clear Fork, Perm.)
Robertson, North (7100', Clear Fork,
Perm.) . . .
Russell (6100' Glorieta, Perm.)
Rysaell (7000* Clear Fork, Perm.) 	
Russell, North (Dev.) 	
Salt Creek (Canyon, Penn.) 	
Sand Hills (Ellen., Cam.-Ord.) .
Sand Hills (McKnight, San Andres, Perm.)
Sand Hills (Tubb, Perm.) 	
Scarborough (Yates, Perm.)
Seeligson (Zone 14-B, Frio, Olig.) ....
Seeligsoo (Zone 19-B, Frio, Olig.) 	
Seeligson (Zone 19-C, Frio Olig.)
Seeligson (Zone 20, Frio, Olig.) 	
Seeligson (Zone 21-D, Frio, Olig.)
Seminole (San Andres, Perm.) 	
Seminole, West (San Andres, Perm.) 	
Shatter Lake (Dev.) 	
Shafter Lake (San Andres Perm.)
Sharon Ridjje (1700' Kan Andres. Perm.). .
Sharon Ridge (2400' San Anfcelo, Perm.) . .
Hhiiron Urine (Clear Fork Perm )


Spraberry Trend nrea (Spraberry, Perm.) . .
Taft (Frio. Olix.) 	
Tulco (Trinity L. Cre )
Tliompnon CIBOO', Miu.) 	
Thompson, North (Vick«hur(?. Oli«.)
Thompson, tjouth (Mio.) 	


TXL (Dev.) . .
TXL (Ellen., Cam.-Ord.) 	
TXL (San Andres Perm.)
TXL (Tubb, Perm.) 	
University-Block 9 ( Dev.)
University-Block 9 (Penn.) . ...
University-Block 9 (Wolfcamp, Perm.) 	
Van (Woodbine- Dexter, U. Cre.) 	
Waddell (Grayburg Perm )
Walnut Rend (Hudspeth, Strawn, Penn.)..
Walnut Bend (U. Strawn, Penn.) 	
Walnut Bend (Winger, L. Strawn, Penn.). .
Wnrd-Kstes, North (Yates Perm.)
Ward South (Yatea Perm )

Wiisnon flfi (Cloar Fork Perm )
WusMon 72 (Clear Fork, Perm.) . . ....
W»jbHti:r (M unfit) ulina, l''rit>, Olig.) 	
W«l«li (San Aii'lres Perm.) 	
Went Columbia ("7. " Frio. O!ii<.)
W«»t Columbia New (Krio, Otij{.) 	
Wt^it Uam:li (41 -A. Krio, OliK-) 	

Grav-
ity.
"API
23.5
28 8
40 4
39 8
39 0
30 0
25.9
28 6
20 3
1(1 2
43 8
34 0
29.9
34 8
32 7
34 6
40 2
36 8
37 0
31.7
36 8
34 0
41 5
41.3
41 9
40 2
41 5
33 6
31 7
38 6
37 4
27.1
28 2
2'J 1
36 0
31 1
35.0
21 K
20 5
23 8
36 4
25 7
40 5
34 8
38 6
42 3
30 8
36 4
44 7
36 4
37.0
35 4
33 6
46.0
44.1
31.0
34 0
35 8
32 8
31 9
33.2
29. 3
'.Vi. 3
28 0
2H.fl
31 5

Sulfur,
wt.
per cent
0.19
0 15
<0 10
<0 10
0 14
0 12
2.60
2 68
2 06
3 64
0 92
1 31
1.95
0 79
1 20
1 23
0 31
0 63
0 73
3.33
0 92
1 00
<0 10
20
140
46
64
35
39
41
39
49
47
30
45
39
51
46
38
38
77
45
42
43
44
42
fit
45
(>.r>
c>:t
41

                             65

-------
 Table A-1  (Continued).   PROPERTIES OF UNITED STATES CRUDE OIL
Slot*
Field
Wert Ranch <9S-A , Frio. Olio) 	
Wont Ranch (Gt&Mcock* Frio Olig } 	
Wait Ranch (Greta. Olig.) 	
Weet Ranch (Ward Frio, Ollg.) 	
Whita Point. Eut (5800' Oreta. Olig.) 	
White Point. Eaat (5600' Brigh»m. Frio.
dig.) 	
Yalea (8aa AndrM Perm.) . 	 	
Via*
Aneth (Kermoaa, Peon*) 	 	

Ratherford (Par&doi, Penn.) 	
White Mas (Paradox. Penn.) 	
Wyoming
Beaver Creek (Steele. U. Cre.) 	
Big Muddy (Frontier. U. Cre.) 	
Big Saad Draw (Tenaleep, Peon.) 	 	

Byron (Tenaleep, Peno.) 	 	 	

Coyote Creek (Minneliua, Peon.) 	 	 	

Elk Buio (Frontier U Cre)
Four Beer (Madiran. Mia*.) 	

Oertand (Axnadea. Peao.) 	 	 	
Glearoek (Dakota* L* Cre.) . . 	

Grieve (L. Cre.) 	 	
Hamilton Dome (Tenelet p. Peao.) .' 	
Little Buffalo Baaio (Phoephoria, Perm.) . .


Oregon Bum (Enbar-Teadeep-Madiaoa,
Salt Creek (Wall Creek, U. Cre.) 	



Winklemoa Dome (Phosphoria, Perm.)...
Grav-
ity,
'API
39.8
31.0
24. 9
30.8
27.3
38.4
30 2
40.4
40.0
41.3
41.1
33.8
35.8
34.2
3S.S
24.3
28. S
40.9
39.4
43 3
13. 8
Z7.S
22.0
34.4
44.8
38.2
22. 8
SO. 7
15.2
38.8
34.0
20. i
36.9
28.2
39.0
33.8
25.7
Sulfur,
wt.
Mr cent
0.11
0.13
0.16
0.15
0.13
0.13
1.54
0.20
<0.10
<0.10
0.10
0.20
0.12
1.35
1.87
2.50
2.52
<0.10
0.12
<0 10
3.58
3.43
2.88
0.16
<0.10
<0.10
2.98
3.31
1.23
0.12
1.70
3.25
0.12
2.18
0.37
1.32
2.59
Viscos-
ity,
SUSaX
100°F
39
41
57
40
44
35
59
38
37
37
36
48
47
43
37
140
63
38
37
35
6.000
as.
ISO.
55
35
42
230
340
41
39
43
360
43
86
33
43
93
Geologic age names are abbreviated as  follows: Cambrian, Cam.;
Cambro-Ordovician, Cam.-Ord.;  Cretaceous,  Cre.; Lower Cretaceous,
L. Cre.; Upper Cretaceous,  U.  Cre.; Devonian,  Dev.; Upper
Devonian, U. Dev.; Eocene,  Eoc.;  Jurassic,  Jr.; Miocene, Mio.;
Lower Miocene, L.  Mio.; Upper  Miocene,  U.  Mio; Mississippian,
Miss.; Oligocene,  Olig.; Ordovician, Ord.;  Lower Ordovician,
L. Ord.; Middle Ordovician, M.  Ord.; Pennsylvania, Penn.;
Permian, Perm.; Pliocene, Plio.;  Pliocene-Miocene, Plio.-Mio.;
Pliocene-Pleistocene, Plio.-Pleist.; Upper Pliocene, U. Plio.;
Silurian, Sil.; Pre-Cambrian,  Pre-Cam.
                               66

-------
Table A-2.  TRACE ELEMENT CONTENT OF UNITED STATES  CRUDE  OILS

Stata aad Field
ALABAMA
Toxey
Toxey
ALASKA
Kuparuk, Prudhoe Bay
Kuparuk, Prudhoe Bay
McArthur River, Cook Inlet
Prudhoe Bay
Put River, Prudhoe Bay
Redoubt Shoal, Cook Inlet
Trading Bay, Cook Inlet
ARKANSAS
Brlster, Columbia
El Dorado, East
Schuler
Smackover
Stephens-Smart
Tubal, Union
West Atlanta
CALIFORNIA
Ant Hill
Arwln
Bradley Sands
Cat Canyon
Cat Canyon
Coal Inge r
Coal Oil Canyon
Coles Levee
Coles Levee
Cuyaaa
Cymric
Cymric
Cymric
Cymric

Cymric

Cymric
Edison
Elk Hills
Elwood South
Gibson
Cots Ridge
Helm
Helm
Huntlngton Beach
Inglewood
Kettleman
Kettleman Hills
Las Florea
Loropoc
Lompoc
Lost Hills
Midway
Nlcolal
North Bel ridge
North Bel ridge
North Bel ridge
Nortn Belridge
Orcuct \
Oxnard
Purlsma
Raisin City

V
9
10
32
28 •
ud
31
In
nd
nd

nd
12
15.2
' nd
18.5
nd
41

14.3
9.0
134.5
128
209
5.1
6.0
11.0
2.2
10.0
30.0
0.8

0.6



1.0
6.0
8. 3
nd
37
188
14.0
2.5
29
125.7
34.0
11.0
106.5
37. A
199
39.0
82.6
246.5
—
--
—
23
162.5
403.5
218.5
8.0
Trace \ElesicaL. p
Nl Fe Ba Cr Hn
14
16
13
12
nd
11
6
4
nd

nd
11
10.3 1.2 <1 <1 <1
4
22.7 6.3 <1 <1 <1
nd
<1 <1 <1 <1 <1

66.5 28.5 <1 <1 nd
28 ,0
—
75
102
21.9 5.1 <1 <1  Emission spectroscopy
2.9J
Emission spectroscopy
Emission spect
-------
Table A-2 (Continued).   TRACE ELEMENT CONTENT OF UNITED STATES CRUDE OILS
State and Field
Rio Bravo
Rio Sravo
Rio Bravo
Russell Ranch
San Joaqula
Santa Marl*
Santa Maria
Santa Maria
Santa Maria
Santa Maria Valley
Santa Maria Valley
Santa Maria Valley
Santa Haxla Valley
Signal Hill
Signal Hill
Tejon Hills
Ventura
Ventura
Ventura Avenua
Wheeler Rtdge
Wilmington
Vllalaglon
Wilmington
Ullntngtan
Wilmington
U liming ton
UUnlngton
COLORADO
Badger Creek
Badger Creek
Cramps
Cramp
Hlavatha
Hoffat Dome
Rangely
Rangely
Rangely
Seep
White River Area
FLORIDA
Jay
IU.1N01S
tendon
Laud on
KANSAS
Brewster
arswster
Brock
Coffeyvllie
Cunningham
Cunningham
lola
lela
"Kanaas-1"
"Kansas-2*
Me Lout h
Otis Albert
Otts Albert .
rawnee Rock
Rhodes
Rliodes
Rhodes
fttiodea
Rhodes
Rhodes
Solomon
irac. Ela— cr »
V Ml Fe fta Cr «n
2.2
— — 2.6
— — 2.5
12.0 26.0
44.8 —
223 97 17
202 —
ISO 106
280 130
207 97
240 —
280 —
174 174 1.7 <1 1.7 <1
28 —
25 57
64 44
42 SI
49 33 31
15.2 —
7 1.9
43 «1
41 46 28
53 51
— 53
— 60
46 60
36.0 84 36 3.6 <1 nd

<1 5
— >21
<1 6.3 <1 <1 <1 <1
21.3 6.0 <1 <1 
-------
Table  A-2  (Continued).    TRACE  ELEMENT  CONTENT OF  UNITED  STATES.  CRUDE OILS
State and Field
LOUISIANA
Bay Marchard
Colqultt, Clalrborne
Colqultt, Clalrborne
Colqultt, Callrborne
(Saackover B)
Delta (West) Offshore,
Block 117
Delta (West) Block 27
Delta (West) Bluck 41
lugene Island, Offshore.
Block 276
Eugene Island, Offshore.
Block 238
Lake Washington
Mala Pass, Block 6
Main Past, (lock 41
Olla
Ship Shoal. Offshore.
Block 176
Ship Shoal, Offshore,
Block 176
Ship Shoal, Block 208
Shoagaloo, H. Red Rock
South Pass, Offshore,
Block 62
Tlnballer. S., Offshore,
Block 94
MICHIGAN
Trent

V

nd
nd .
nd

od
nd
nd
ad

4
Bd
ad
Bd
• nd
• <1

ad

ad
nd
ad

nd

ad

—
Trace Uamaac. oa» •
Nl Pe Be Cr Hn . Mo Sn As

2
nd
nd

nd
2
2
2

nd
nd
4
1
J.56 0.07

nd

nd
2
ad

4

nd

0.23
Analytical Method

Emission spectroscopy
Emission spectroscopy
Emission sptfctfodcopy

Emission spec t rtiscopy
Emission spectroscopy
Emission spectroscopy
Emission spectroscopy

Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
Imlsslon spectroscopy
talsslon spectroscopy
emission spectroscopy

Emission spectroscopy

Emission spectroscopy
Emission spectroscopy
Emission spectroscopy

Emission spectroscopy

.Emission :pectroseopy

Emission spectroscopy
Year

1971
1971
1971

1971
1971
1971
1971

1971
1971
1971
1971
1971
1952

1971

1971
1971
1971

1971

1971

1956
     MISSISSIPPI
       Baxtervllla, Lamer and
         Merlon
       Beldelberg
       Mississippi
       TallhalU Creek. Smith
       Tellhella Creek, Smith
       TallhalU Creek. Smith
         (Saackover)
       Tlngley. Yasoo
 40    15
 15.3J  6.02 1.78
'  —     .7
nd    nd
nd    ad
nd
      nd
      Eaisslon spectroscopy
      Emission speccroscopy
S.OQ3 Emission spectroscopy
      Emission spectroscopy
      Emission spectroscopy

      Emission spectroscopy
      Emission spectroscopy
                                                                           1971
                                                                           1952
                                                                           1966
                                                                           1971
                                                                           1971

                                                                           1971
                                                                           1971
     MONTANA
       Bell Creak
       Big Wall
       Soap Creek
nd      2                                     Emission spectroscopy
 24    13.2        <1   <1  <1    <1  ad        Emission spectroscopy
132    13.2        <1   <1  <1    <1  nd        Eaisslon spectroscopy
                                                                           1971
                                                                           1961
                                                                           1961
     MEW MEXICO
       Rattlesnake
       Rattlesnake
       Table Mesa
                                   <1
                                         <1
                                                9.9  <1   <1  <1
                                <1  nd       Emission spectroscopy
                                
-------
Table A-2 (Continued).   TRACE ELEMENT CONTENT OF UNITED STATES CRUDE OILS

State and Field
Crist Creek
Havklns
Hawkins
Horns Corner
Katie
Katie
Katie
Katie
Kendrfck
Konawa
Laf foon
Little River
Middle Cllllland
Naval Reserve
Hex England
H. Dill
N. Z. Castle Ext.
N. E. Elmore
N. E. Elmore
N. Okenab
N. V. Horns Corner
Olympia
Osage City
S. W. Maysvllle
S. W. Mayavllle
Tatuas
Ta turns
Tatuus
Weleetka
W. Holdenvllle
W. Wewoka
Wewoka
Weuoka Lake
Wowoka Lake
Uewoka Lake
Ulldhorse
Wynona
Hynona
TEXAS
Anahiiac
•rant ley-Jackson , Hopkins
Brant ley-Jackson, Snachover
Conroe
Bast Texas
East Teicas
East Texas
East Texas
Bdgewood, Van Zandt
Floley
Jackson
Lak,e Trammel/Nolan
Hlrando
Panhandle, Carson
Panhandle, Hutchlnson
Panhandle, West Texas
Kefuglo
KafuRlo, Light
Sale Flat
Scurry County
Sweden
Talro
Talro
Waffiton
Went Toxiift
U • f. «-„
* ttl rt'XJlti
Wertroncopy
Emission spectroscopy
Emission spectroscopy
nd nd Emission spectroscopy
Emission spectroscopy
nd nd Emission spectroscopy
Emission spectroscopy
nd nd Emission spectroscopy
nd nd Emission spectroscopy
nd nd Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
•Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
nd nd Emission spectroscopy
Emission spectroscopy
Emission spectroscopy
X-ray fluorescence
Emission spertroscopy
X-ray fluorescence («xt. etd.)
Emission spectroscopy
Enlsslon spectroscopy
Emission spectroscopy
Emission spertroscopy
Emission spectroscopy
Emission spr-.ttroscopy
Emission spcutroscopy
nd nd Kralfiflion spectroscopy
nd :i!nn spcrl ro-'*rnpy
Kt&lsslou fipct. troscilpy
(1)
CoH)rlmeTric
Clu-mlr.il
Cheralt-ol

Year
1956
1956
1956
1956
1956
1956
1956
1956
1961
1956
1961
1956
1961
1961
1961
1956
1956
1956
1956
1956
1956
1956
IQCl
1 ?D1
1956
1956
1959
1959
1960
1956
1956
1956
1956
1956
1956
1956
1941
1961
1961

1958
1971
1971
1952
1971
1952
1952
1952
1971
1961
1952
1971
1952
1971
1971
1952
1952
1958
1952
1952
1956
1952
1958
1971
J960

1152

1958
115R

1952
1952
                                      70

-------
Table A-2 (Continued).  TRACE  ELEMENT CONTENT OF UNITED STATES CRUDE OILS
Trace PI rnnnf ppm
State and Field
UTAH
Duchesne
Duchesae
Duchesne County
Red Wash
Red Wash
Roosevelt
Roosevelt
Virgin
Virgin
Wflflt FieSflAeUlC VetHtty
Wildcat
WYOMIKC
Beaver Creek
Big Horn Mix
Blaon Basin
Circle Ridge
Corral Creek
Crooks Cap
Dallas
Dallas
Derby
Elk Begin
Elk Basin
Garland
Crass Creak
Half Moon
Half Moon
Hamilton Done
Hamilton Dome
Hamilton Domo
Little Mo
Lost Soldier
Lost Soldier
Lost Soldier
Mitchell Creek
North Oregon Basin
North Oregon Basin
. Oil Mountain
Pilot Butte
Pilot Butte
Pltie Bldge
Prescott So. 3
Recluse
Roe 11s
Salt Creek
Salt Creek
Salt Creek
Salt Creek
Skull Creek
South Casper Creek
South Fork
South -Spring Creek
South Spring Creek
Steamboat Butte
Uashakle
Ulnkleiun Done
V

..1
<1
<1
ad
nd
<1
<1
14.4
8.1
Uj
.4
0.14

nd
15.97
1.1
59
2.1
66
66
39
38
8.4
36
106.4
98.6
50.6
106.4
55.2
106.4
83
<1
<1
<1
72.0
77.0
72.0
"jLrt n
Ov.U
144.0
45.0
24.0
nd
21.0
nd
88
84.0
1.4

<1
__
12.9
21.9
HI

<1
<1
12.3
ad
nd
3.2
5.4
14.4
8.1
•i 7 I
J 1 Li
7.5

ad
3.6
2.7
11.2
11
2.2
.15.4
66
39
9.2
2
24
28.9
27.8
<1
26.6
8.6
24.3
16
<1
<1

-------
Table A-3.   SULFUR AND NITROGEN CONTENT OF THE GIANT  U.S.  OIL FIELDS
              Stat«/Region  and  Field
                                           Sulfur,
                                           Weight
                                           Percent
Nitrogen,
 Weight
 Percent
            ALABAMA
              Citronelle                    0-38        0.02

            ALASKA
              Granite Point                 0.02        0.039
              McArthur  River               0.16        0.160
              Middle  Ground  Shoal          0.05        0.119
              Prudhoe Bay (North Slope)     1.07        0.23
              Swanson River                 0.16        0.203

            APPALACHIAN
              Allegany                      0.12        0.028
              Bradford                      0.11        0.010

            ARKANSAS
              Magnolia                       0.90       0.02
              Schuler and East              1.55       0.112
              Smackover                     2.10       0-08

            CALIFORNIA
             SAN JOAQUIN VALLEY
              Belridge South
              Buena Vista
              Coalinga
              Coalinga Nose
              Coles Levee North
              Cuyaraa South.
              Cymric
              Edison
              Elk Hills
              Frultvale
              Greeley
              Kern Front
              Kern River
              Kettleman  North Dome
              Lost Hills
              McKittrick -  Main Area
              Midway Sunset
              Mount  Poso
              Rio Bravo
              COASTAL AREA
              Carpenteria Offshore          —
              Cat Canyon West               5.07         0.54
              Dos Cuadras                   •—          ~~
              Elwood                        —
0-23
0.59
0.43
0.25
0,39
0.42
1.16
0-20
0.68
0.93
0.31
0.85
1.19
0.40
0.33
0.96
0.94
0.68
0.35
0.773
' —
0.303
0.194
0.309
0.337
0.63
0.446
0.472
0.527
0.266
0.676
0.604
0.212
0.094
0.67
0.42
0.475
0-158
                                     72

-------
Table A-3  (Continued).   SULFUR  AND  NITROGEN CONTENT OF THE GIANT U.S.  OIL FIELDS
jitate/Reglori and Field
Orcutt
Rincon
Sah Ardo
Santa Ynez***
Santa Maria Valley
South Mountain
Ventura
LOS ANGELES BASIN
Beverly Kills
Urea Olinda
Coyote East
Coyote West
Dominguez
Huntington Beach
Inglewood
Long Beach
Montebello
Richfield
Santa Fe Springs
Seal Beach
Torrance
Wilmington
COLORADO
Range ly
FLORIDA
Jay
ILLINOIS
Clay City
Dale
Loudon
New Harmony
Salem
KANSAS
Bemis-Shutts
Chase-Silica
Eldorado
Hall-Curney
Kraf t-Prusa
Trapp
LOUISIANA
NORTH
Black Lake
Caddo-Plnc Island
Delhi
Haynesville (Ark. -La.)
Homer
Lake St. John
Rodcssa (La. -Tex.)
Sulfur.
Weight
Percent
2.48
0.40
2.25
—
4.99
2.79
0.94

2.45
0.75
0.95
0.82
0.40
1.57
2.50
1.29
0.68
1.86
0.33
0.55
1.84
1.44

0.56

0.32

0.19
0.15
0.27
0.23
0.17

0.57
0.44
0.18
0.34
0.27
0.41


—
0.37
0.82
0.66
0.83
0.17
0.46
Nitrogen,
Weight
Percent-
0.525
0.48
0.913
—
0.56
—
0.413

0.612
0.525
0.336
0.347
0.360
0.648
0.640
0.55
0.316
0.575
0.271
0.394
0.555
0.65

0.073

0.002

0.082
0.080
0-097
0.158
0 .102

0.162
0.13
0.085
0.108
0.-171
0.076


—
0.026
0.053
0.022
0.081
—
0.032
                                         73

-------
Table A-3 (Continued).  SULFUR AND NITROGEN CONTENT OF THE GIANT U.S. OIL FIELDS
State/Region and Field
OFFSHORE
Bay Marchand Block 2
(Incl. onshore)
Eugene Island Block 126
Grand Isle Block 16
Grand Isle Block 43
Grand Isle Block 47
Main Pass Block 35
Main Pass Block 41
Main Pass Block 69
Ship Shoal Block 208
South Pass Block 24
(Incl. onshore)
South Pass Block 27
Timbalier S. Block 135
Timbalier Bay
(Incl. onshore)
West Delta Block 30
West Delta Block 73
SOUTH, ONSHORE
Avery Island
Bay De Chene
Bay .St. Elaine
Bayou Sale
Black Bay West
Caillou Island
(Incl. offshore)
Cote Blanche Bay West
Cote Blanche Island
Delta Farms
Garden Island Bay
Golden Meadow
Grand Bay
Hackberry East
Hackberry West
Iowa
Jennings
Lafitte
Lake Barre
Lake Pelto
Lake Salvador
Lake Washington
(Incl. offshore)
Leeville
Paradls
Quarantine Bay
Rome re Pass
Venice
Vinton
Weeks Island
~W«»st Bay
Sulfur,
Weight
Percent


0.46
0.15
0.18
—
0.23
0.19
0.16
0.25
0.38

0.26
0.18
0.66

0.33
0.33
.—

0.12
0.27
0.39
0.16
0.19

0,23
0.16
0.10
0.26
0.22
0.18
0.31
0.30
0.29
0.20
0.26
0.30
0.14
0.21
0.14

0.37
0.20
0.23
0.27 <
0.30
0.24
0.34
0.19
0.27
Nitrogen,
Weight
Percent


0.11
0.030
0.04
—
0.04
0.071
0.025
0.098
0.02

0.068
0.049
0.088
-•-.
0.081
0.09
— .—

— — .
0.060
0.04
_.—
0.04

0.04
0.033
0.01
0.055
0.06
— — .
__
0.054
__
0.039
«
— .
0.02
0.035
0.02

0.146
0.019
—
0.061
__
__
0 .044
— —
0 .071
                                       74

-------
Table A-3 (Continued).   SULFUR AND NITROGEN CONTENT OF THE  GIANT U.S.  OIL  FIELDS
State/Region and Field
MISSISSIPPI
Baxterville
Heidelberg
Tins ley
MONTANA
Bell Creek
Cut Bank
NEW MEXICO
Caprock and East
Denton
Empire Abo
Eunice
Hobbs
Maljamar
Monument
Vacuum
NORTH DAKOTA
Beaver Lodge
Tloga
OKLAHOMA
Allen
Avant
Bowlegs-
Burbank
Cement
Gushing
Earlsboro
Edmond West
Eola-Robberson
Fitts
Glenn Pool
Golden Trend
Healdton
Hewitt
Little River
Oklahoma City
Seminolo, Greater
Sho-Vel-Tum
Sooner Trend
St. Louis
Tonkawa
Sulfur,
Weight
Percent

2.71
3.75
1.02

0.24
0.80

0.17
0.17
0.27
1.14
1.41
0.55
1.14
0.95

0.24
0.31

0.70
0.18
0.24
0.24
0.47
0.22
0.47
0.21
0-35
0.27
0.31
0.15
0.92
0.65
0.28
0 .16
0.30
1.18
—
0.11
0.16
Nitrogen,
Weight
Percent

0.111
0.112
0.08

0.13
0.055

0.034
0.014
0.014
0.071
0.08
0.062
0.071
0.075

0.019
0,016

0.21
—
0.140
0.051
0.152
0.08
—
0.045
0.115
-.-
0.096
0.15
0.15
0.148
0.065
0.079
0.016
0.27
—
0 . 04
0.033
                                       75

-------
Table A-3 (Continued).   SULFUR AND NITROGEN  CONTENT OF  THE GIANT U.S. OIL FIELDS
.State /Region and Field
tEXAS
•DISTRICT 1
Big Wells
Darst Creek
Luling-Branyon
DISTRICT 2
Greta
Refuglo
Tom O'Connor
West Ranch
DISTRICT 3
Anahuac
Barbers Hill
Conroe
Dickison-Gillock
Goose Creek and East
Hastings E&W
High Island
Hull-Merchant
Humble
Liberty South
Magnet Withers
Old Ocean
Raccoon Bend
Sour Lake
Spindletop
Thompson
Webster
West Columbia
DISTRICT 4
Agua Duke-Stratton
Alazan North
Borregas
Government Wells N.
Kelsey
La Gloria and South
Plymouth
Seeligson
Ti j er ina-Canales-Blucher
White Point East
DISTRICT 5
Mexia
Powell
Van and Van Shallow
Sulfur,
Weight
Percent


—
0.78
0.86

0.17
0.11
0.17
0.14

0.23
0.27
0.15
0.82
0.13
0.20
0.26
0.35
0.46
0.14
0.19
0.14
0.19
0 .14
0.15
0.25
0.21
0.21

<.l
0.04
<.l
0.22
0,13
<.l
0.15
<.l
<.l
0.13

0.20
0.31
0.8
Nitrogen,
Weight
Percen^


—
0.075
0.110

0.038
0.027
0.038
0.029

0.041
0.06
0.022
0.014
0.028
0.03
0.048
0-081
0.097
0.044
0.033
0.029
0.048
0.016
0.03
0.029
0.046
0.055

0.015
0.014
0,029
0.043
0.008
0.008
0.049
0.015
0.010
0.02

0.048
0.054
0.039
                                        76

-------
Table A-3  (Continued).  SULFUR AND NITROGEN CONTENT OF THE GIANT U.S. OIL FIELDS
^State/Region and Field
DISTRICT 6
East Texas
Fairway
Hawkins
Neches
New Hope
Quitman
Talco
DISTRICT 7-C
Big Lake .
Jameson
McCamey
Pegasus
DISTRICT 8
Andector
•JSlock.31
Cowden North
Cowden South, Foster,
Johnson
Dollarhide
Dora Roberts
Dune
Emma and Triple N
Fuhrman-Mascho
Fullerton
Goldsmith
Headlee and North
Hendrick
Howard Glasscock
latan East
Jordan
Kermit
Keystone
McElroy
Means
Midland Farms
Penwell
Sand Hills
Shafter Lake
TXL
Waddell
Ward South
Ward Estes North
Yates
Sulfur,
Weight
Percent

0.32
0.24 :
2.19
0.13
0.46
0.92
2.98

0.26
<.l
2.26
0.73

0.22
0.11
1.89

1.77
0.39
<.l
3.11
<.l
2.06
0.37
1.12
<.l
1.73
1.92
1.47
1.48
0.94
0.57
2.37
1.75
0.13
1.75.
2.06
0.25
0.36
1.69
1.12
1.17
1.54
Nitrogen,
Weight

0.066
—
0.076
0.083
0-007
0.036
—

0-071
0.034
0.139
0.200

0.033
0.032
0.095

0.127
0.074
0.023
0.111
0.025
0.085
0.041
0.079
0.083
0.094
0.096
0.120
0.10
0.092
0.042
0.080
0.205
0 .080
0 .205
0.085
0 . 04 1
0.067
0 .098
0 .08
0 .107
0 .150
                                        77

-------
Table A-3 (Continued).  SULFUR AND NITROGEN CONTENT OF THE GIANT U.S.  OIL  FIELDS
                  State/Region and Field
Sulfur,
Weight
Percent
Nitrogen,
 Weight
 Percent,
                 DISTRICT 8-A
                  Cogdell Area
                  Diamond M
                  Kelly-Snyder
                  Levelland
                  Prentice
                  Robertson
                  Russell
                  Salt Creek
                  Seminole
                  Slaughter
                  Spraberry Trend'
                  Wasson

                 DISTRICT 9
                  KMA
                  Walnut Bend
                 DISTRICT 10
                  Panhandle

                UTAH
                  Greater Aneth
                  Greater Redwash

                WYOMING
                  Elk Basin (Mont.-Wyo.)
                  Garland
                  Grass. Creek
                  Hamilton Dome
                  Hilight
                  Lance Creek
                  Lost Soldier
                  Oregon Basin
                  Salt Creek
 0.38
 0.20
 0.29
 2.12
 2.64
 1.37
 0.77
 0.57
 1.98
 2.09
 0.18
 1.14

 0.31
 0.17

 0.55
  0.20
  0.11
  1.78
  2.99
  2.63
  3.04

  0.10
  1.21
  3.44
  0.23
 0 .063
 0 .131
 0 .066
 0 .136
 0 .117
 0 .100
 0 .078
 0 .094
 0 .106

 0 .173
 0 .065

  0.068
  0.05

  0.067
  0.059
  0.255
  0.185
  0.290
  0.311
  0.343

  0.055
  0.076
  0.356
  0.109
                Source:   Magee,  E.M.,  H.  J.  Hall, and G.  M. Varga, Or,
                         Potential  Pollutants in Fossil  Fuels, PB 225
                         039,  EPA-R2-249, Contract No.  68-02-0629,
                         Linden, N.J., Esso Research and Engineering
                         Co.,  1973.
                                          78

-------
             APPENDIX B

GEOGRAPHICAL LOCATION OF OIL AND GAS
       PRODUCTION ACTIVITIES
                      79

-------
Table B-l.  PRODUCTION OF CRUDE OIL AND LEASE CONDENSATE  BY  STATES,  1973
States and Districts
Florida
New York
Pennsylvania
West Virginia
DISTRICT I
Illinois
Indiana
Kansas
Kentucky
Michigan
Nebraska
North Dakota
Ohio
Oklahoma
South Dakota
Tennessee
DISTRICT II
Alabama
Arkansas
Louisiana
Mississippi
New Mexico
Texas
DISTRICT III
Colorado
Montana
Utah
Wyomi ng
DISTRICT IV
Volume Produced, 1000 bbl1
90
2
9
7
108
84
15
181
24
40
20
55
24
524
1
1
969
32
49
2278
154
277
3547
6337
100
95
90
389
674
                                   80

-------
Table  B-l  (Continued).   PRODUCTION OF CRUDE OIL AND LEASE CONDENSATE BY STATES, 1973
States and Districts
Alaska
Arizona
California
Nevada
DISTRICT V
Total U.S.
Volume Produced, 1000 bbl l
198
2
921
_
1121
9209
              Volumes  in thousands  of 42 gallon  barrels.
                  1  gallon - 3.785 liters.
               Source:   Annual  Statistical  Review,  Petroleum Industry
                        Statistics.  1965-1974.   Washington,  D.C.,
                        American Petroleum Institute,  1975.
                                       81

-------
Table B-2.  PRODUCTION OF NATURAL GAS BY STATES,  1973.
State
Alabama
Alaska
Arizona
Arkansas
California
Colorado
Florida
Illinois
Indiana
Kansas
Kentucky
Louisiana
Maryland
Michigan
Mississippi
Missouri
Montana
Nebraska
New Mexico
New York
North Dakota
Ohio
Oklahoma
Pennsylvania
South Dakota
Total Production, Million SCF*
36
612
1
437
1,407
387
93
4
1
2,458
171
23,264
1
125
323
--
167
13
3,352
12
138
256
5,177
215
--
                            82

-------
Table B-2 (Continued).  PRODUCTION OF NATURAL GAS BY STATES,  1973.
  State                       Total Production, Million SCF1
Tennessee
Texas
Utah
Virginia
West Virginia
Wyomi ng
TOTAL U. S.
1
25,452
215
14
572
1,033
65,937
Volumes in millions of standard cubic feet.
 Iscf = 0.0267 normal cubic meters

Source:  Annual Statistical Review,  Petroleum Industry  Statistics,
         1965-1974*   Washington, D.  C., American  Petroleum  Institute,
         1975.
                           83

-------
Table B-3.   LOCATION OF LARGE DOMESTIC OILFIELDS
Est. Est.
1974 Prod. 'CUM. Prod. Reserves1 No
State & Field 10000 bbl }000 bbl 1000 bb.1 "ells
ALABAMA
Citronelle 	
ALASKA
Granite Point 	
McArthur River 	
Middle Ground Shoal
Prudhoe Bay 	
Swanson River 	
APPALACHIAN
Allegany
Bradford 	
ARKANSAS
Magnolia 	
Schuler and East
Smackover 	
CALIFORNIA
SAN JOAQUIN VALLEY
Belridge South 	
Buena Vista 	
Coalinga 	
Coalinga Nose 	
Coles Levee North 	
Cuyama South 	
Cymric
Edison : 	 	
Elk Hills 	 	
Fruitvale
Greeley 	
Kern Front . 	
Kern River . . .
Kettleman North Dome
Lost Hills 	
McKittrick 	
Midway Sunset 	
Mount Poso
Rio Bravo 	
COASTAL AREA
Cat Canyon East and West
Dos Cuadras 	
Elwood
Orcutt 	
Rincon 	
San Ardo 	
Santa Ynez* 	
Santa Maria Valley
South Mountain 	
Ventura 	

LOS ANGELES BASIN
Beverly Hills 	
Brea Olinda
Coyote East
Coyote West 	
Oominguez
Huntinglon Beach
Inglewood 	
long Beach
Montebello
Richfield

4,866

4,233
39,191
9,033
2,181
9,741

400
2,600

446
613
2,860


8,544
4,003
6,483
3,504
1,218
1,471
2919
1,206
789
1016
677
3,235
26,765
643
2,165
6,538
4,920
2,527
170

6,064
14,990
40
1,776
3,319
12,877
3,558
1,640
11,393

4,656
3388
674
2,143
1,110
19,035
3,588
2,598
558
1,476

112,122

56,131
253,387
87,695
6,674
154.297

166,400
658,695

152,870
105,736
508,507


194,803
617,240
632,959
432,473
140,848
208,617
131 500
113.339
283,788
101817
107*973
134,691
635,757
452,104
119,092
206,314
1,197,423
168,357
113,139

174,126
102,488
103,266
148,789
123,549

37,877

34,321
136.748
97.000

416

25
52
33
10-20 million 3
51,197

1,415
19,774

7,130
4,264
21,493


77,900
32,427
65,887
30,959
12,766
11,002
24405
12*500
1,031,000
11,400
3 100
30i300
850,000
3,756
21,700
43,022
420,191
20,620
1,731

48,100
73,247
479
13,035
20.209
274.160 1031800
- 1-3 million -
159.363
130,617
793,393

78,834
343585
98*135
232,141
258,272
923,820
296,656
878,213
184,500
164,852
26,612
16,142
. 88,500

31,384
24 919
«.*TjC Li.
5,300
. 18,361
10,162
118,800
25,100
20,605
5,120
16,372
42

2,100
17,300

56
108
2,611


2,667
1,137
2219
' 74
116
135
746
/f U
527
93
349
• J*t3
47
^/
952
4,531
129
1,149
952
6,027
498
48

590
123
12
176
312
913
214
441
809

128
771
/£!
67
161
131
1,118
432
733
178
304
                     84

-------
Table  B-3  (Continued).    LOCATION  OF  LARGE DOMESTIC  OILFIELDS
                State & Field
                                    .   Est.    Est.
                   1974 Prod.1 CUM. Prod.Reserves1  No
                    10000 bbl  1000 bbl 1000 bt>l  He^s
  Santa Fe Springs
  Seal Beach  	
  Tprrance  	
  Wilmington  	


COLORADO
   Rangely	

FLORIDA
                                        753    600,697    11,218   242
                                       1,236    187,989    11,900   176
                                       2,747    182,332    17,591   364
                                      65,382  1,681,810   697,935  2,335
20,284   513,615    158,379
                                                               369
                                      33,166    75,383   237,617    85
ILLINOIS
Clay City .
Dale 	 V
Lawrence 	
Loudon 	
Main 	
New Harmony
Salem 	
KANSAS
Bemis-Shutts
Chase-Silica
Eldorado 	
Hall-Gurney
Kraft-Prusa
Trapp 	
LOUISIANA
Avery Island
Bay DeChene
Bay St. Elaine
Bayou Sale
Black Bay West
Calliou Island
Cote Blanche Islai
Delta Farms
Garden Island Bay
Golden Meadow
Grand Bay
Hackberry East .
Hackberry West
Iowa
Jennings
Lafitte
Lake Barre
Lake Pelto
Lake Salvador
Lake Washington
Leeville 	
Paradis '. 	
Quarantine Bay
Romere Pass . . .
Timbalier Bay .
Venice 	
Vinton 	
Weeks Island
West Bay
W. Cote Blanche

2,713
	 389
812
2,693
	 870
1,380
2,783

	 1,933
1,185
	 1,085
	 1,821
	 866
	 1,332
, ONSHORE
1,252
5,464
4,804
2,793
7,068
18,023
id 6,982
916
. ... 8,403
2,256
3,934
	 1,753
. 2,944
1,250
280
5,727
4,613
3,110
1,662
6,488
	 2,419
	 4,057
	 3,523
	 2,218
	 7,985
	 4,400
	 2,994
	 6,446
6,679
Bay 7,880

307,937
100,403
362,201
363,553
223,974
155,355
355,773

218,408
250,429
279,932
127,244
117,824
207,023

78,808
74,815
143,406
145,141
91,538
516,898
78,996
110,053
174,829
115,299
152,533
93,492
117,896
92,363
111,689
212,532
170,632
100,747
75,472
198,674
125,226
103,213
149,648
80,347
234,619
158.185
122,886
200,175
176,543
147.316

17,063'
4,597
4,600
21,447
2,100
14,645
14,227

16,592
9,571
10,058
12,756
7,176
12,977

31,192
52,165
56,494
29,859
58,462
183,102
51,004
9,947
81,508
19,701
52,467
16,508
22,104
7,637
3,311
45,463
49,368
34,253
34,528
76,326
24,774
26,131
35,352
24,653
192,126
46,815
17,114
89,825
63,457
102,684

2,138
495
2,631
1,234
3,101
980
1,228

925
1,033
760
1,175
590
919

38
80
95
91
145
361
58
41
249
207
161
85
158
37
84
244
119
66
50
144
92
75
122
37
355
115
177
82
198
322
                                    85

-------
Table B-3  (Continued).   LOCATION OF  LARGE DOMESTIC OILFIELDS
               State ft Field
1974 Prod.'CUB.  Prod!Reserves1 No
 10000 bbl  looo bbl  1000 bb.1
LOUISIANA, NORTH
Caddo-Pine Island 3 .34ft
Delhi 	
Haynesville (Ark.. La.)
Homer 	
Rodessa, (La., TexJ . .
6,583
. 1,644
. 318
. 351
313,014
165 956
171,874
92,227
175,474
26,986
44044
13,126
8,005
4,526
7,370
105
190
153
145
LOUISIANA, OFFSHORE
Bay Marchand Blk. 2
(Incl. onshore)
Eugene Island Blk. 126
Eugene Island Blk. 175
Eugene Island Bik. 276
Eugene Island Blk. 330
Grand Isle Blk. 16 ....
Grand Isle Blk. 43 	
Grand Isle Blk. 47
Main Pass Blk. 35 .
Main Pass Blk. 41
Main Pass Blk. 69
Main Pass Blk. 306 .
Ship Shoal Blk. 204 ...
Ship Shoal Blk. 207 ...
Ship Shoal Blk. 208 .
South Marsh Island
Blk. 73
South Pass Blk. 24
(Incl. onshore) 	
South Pass Blk. 27 .
South Pass Blk. 62
South Pass Blk. 65 ...
Timbalier Bay Blk. 21 . .
West Delta Blk. 30 ...
West Delta Blk. 58
West Delta Blk. 73
MISSISSIPPI
Baxterville 	
Heidelberg 	
Tinsley 	
MONTANA
Bell Creek .
Cut Bank 	
Pine : 	
NEW MEXICO
Caprock and East 	
Denton 	
Empire Abo 	
Eunice 	
Hobbs .
Maljamar 	
Monument 	
Vacuum 	

32,632
4,429
8,059
4,687
19,747
13,156
20,999
3,972
. 2,155
10,396
7,973
5,573
5,732
6,223
10,559

5020

15,223
. 11,568
. 6,446
10,105
. 9,449
22,586
10,035
. 7,654

6,853
5,039
2,543

9.345
3,189
2,904

484
1,561
12,267
,4,079
4,722
5,854
387
13,152

429,534
89,207
37,300
46,769
40,488
211,052
163,669
65,069
79,768
144,519
191,010
31,942
27,140
44,419
92,506

40,848

371,476
258,926
48,402
46,193
159,698
312,462
38,091
128,219

167,013
115,229
196,017

68,819
138,439
78,601

92,810
124,675
111,171
126,215
221 451
104,105
210,412
274,986

220,466
35,803
82,700
118.231
190,754
138,948
206,403
34,931
20,232
135,481
68,990
118,058
77,860
130,581
132,494

64,152

118,524
126,074
141,598
143,807
100,111
137,538
111,909
146,781

67,987
34,771
23.983

47,126
58,718
21.416

7,190
15,325
88,829
31,776
33232
60,895
29,588
125,014

293
53
76
60
120
92
230
71
77
100
132
134
58
53
86

37
V*
436
342
64
62
221
216
81
98

198
263
184

228
839
112

614
188
251
806
412
"t*t
819
114
972
NORTH DAKOTA
Beaver Lodge
Tioga 	
OKLAHOMA
Allen
Avant
3,117
953

2,540
360
78,510
56,253

126,921
106,602
21,506
29,480

13,079
2,398
138
215

1,500
645
                                  86

-------
Table B-3 (Continued).  LOCATION OF LARGE DOMESTIC OILFIELDS
1974 Prod.1
State & Field 10000 bbl
Bowlegs 	
Burbank 	
Cement 	
Cushing
Earlsboro 	
Edmond West 	
Eola-Robberson 	
Fitts 	
Glenn Poo! 	
Golden Trend 	
Healdton 	
Hewitt 	
Little River 	
Oklahoma City
Postle
Seminole Greater
Sho-Vel-Tum 	
Sooner Trend
St. Louis .
Tonkawa 	
TEXAS
District 1
Darst Creek 	 	
Luling-Branyon 	
District 2
Greta All 	
Lake Pasture 	
Refugio All 	
Tom O'Connor
West Ranch 	
District 3
Anahuac 	
Barbers Hill 	
Conroe 	
Dickinson-Gillock
Goose Creek & East
Hastings E&W
High Island all 	
Hull-Merchant
Humble all 	
Magnet Withers all
Old Ocean 	
Oyster Bayou
Raccoon Bend 	
Sour Lake 	
Spindletop 	
Thompson all 	
Tombal! 	
Webster 	
West Columbia 	
District 4
Aqua Dulce-Stratton . .
Borregas all 	
Kelsey all 	
Plymouth 	
Seeligson all 	
Tijerina-Canales-Blucher
White Point East 	
District 5
Mexia .,
Powell 	
Van and Van Shallow
1,665
3,685
1,280
2,965
620
625
3,720
2,565
1,980
8,135
7,575
6,595
330
2,000
6,780
1,010
34,250
9,810
1,100
275


1,731
. 1,345

4,476
. 4,439
314
25,667
14,560

. 8,949
497
21,737
1,839
760
27,912
1,204
1,521
1,473
. 3,025
577
5,520
2,002
925
171
. 16,319
2,932
24,762
1,018

2,122
2,072
2,125
802
2,453
3,867
. 909

129
92
16,264
Cum. Prod.
1000 bbl
158,492
504,039
140,236
463,182
216,424
155,147
107,977
150,873
309,421
402,011
294,240
218,986
159,901
733,896
70,560
199,456
1,002,456
199,414
216,145
135,212


141,384
147,162

116,951
65,537
95,160
496,410
76,469

248,759
124,529
540,659
107,953
130,749
502,991
130,859
193,909
161,839
80,931
121,307
94,837
91,721
117,386
153,741
370,071
103,647
412,958
157,514

138,000
108,293
107,518
116,718
263,203
100,528
99,681

107,353
130,063
419,384
Est. Est.
Reserves1 No
1000 bb.1 «ells
6,508
36,961
14,764
21,818
3,576
'4,853
32,023
12,127
10,579
97,989
25,760
31,014
5,099
16,104
60 102
10,544
247,544
50586
8'855
l',788


18,616
12,838

43,049
44,112
4,840
203,590
298,531

106,241
10,471
134,341
42,047
9,251
172,009
19,141
11,091
28,161
44,069
8,693
51,667
33,279
7614
3,259
129,929
32,217
162,042
12,486

32,000
26,707
42,482
8,282
61,797
64,472
10,319

2,64/
937
130,616
175
1,070
1,465
1,700
200
450
485
635
1,035
1,200
1,460
1,180
165
265
285
255
8,040
2,975
610
205


864
1,403

191
212
67
830
624

234
100
588
70
221
439
98
385
413
286
37
35
135
334
72
305
216
148
193

393
502
344
103
433
182
154

97
37
427
                             87

-------
Table B-3 (Continued).  LOCATION OF LARGE DOMESTIC OILFIELDS


State & Field
District 6
East Texas
Fairway 	
Hawkins 	
Neches
Quitman all 	
Talco 	
District 7-B
Eastland County . .
Stephens County
District 7-C
Big Lake 	
MeCamey 	
Pegasus
District 8
Andector 	
Block 31 	
Cowden North
Cowden South,
Foster Johnson
Dollarhide 	
Dune 	
Emma & Triple N
Fullerton all 	
Goldsmith all 	
Hendrick
Howard Glasscock
Tatan East 	
Jordan 	
Kermit 	
Keystone 	
McElroy 	
Means all
Midland Farms all
Penwell 	 	
Sand Hills ...
Shatter Lake
TLX all 	
Waddell ....
Ward South
Ward Estes North
Yates

District 8-A
Anton
Anton Irish
Cogdell Area
Diamond M
Kelly-Snyder 	
Levelland 	
Prentice 	
Russell all 	
Salt Creek 	
Seminole all 	
Slaughter 	
Spraberry Trend .
Wasson all
Welch 	
District 9
Archer County
Cooke County . .
, KMA 	
Walnut Bend
Wichita County . .
Wilbarger County
Young County
District 10
Panhandle

1974 Prod.1
10000 bbl

72,312
13,741
	 39,630
4,819
... 3,360
3,773

241
	 1,877

. . 500
794
2,568

. . . . 6,538
	 6,267
	 14,954

16,714
	 5,843
	 7,448
	 1,993
	 6,756
	 17,431
654
6,902
4.197
3.426
934
5,101
11,820
6,644
6,396
1,485
5,092
2,325
3.656
2,788
546
. 6,170
. 18,192


	 7,443
	 4,800
10,237
	 6,864
	 76,433
	 12,391
	 5.932
2,697
	 13.093
	 20.102
	 47,033
	 18,190
. 86,784
6,160

	 2,640
	 2,106
2,051
4,711
	 4,787
	 1,976
1,563

12,347

Est.
Cum. Prod. Reserves L
1000 bbl 1000 bb.1

4,241,715
123,703
535,697
60,132
80,205
237,534

120,482
169,155

124,664
124,089
113,008

128.037
143,861
276,320

299,613
150,205
126,476
96,694
238,417
578,658
252,215
310,153
86,412
102,424
112,374
272,902
309,518
146,249
176,039
84,967
189,105
72,033
236.342
81,605
96,643
310,174
605,446


78,354
73,727
187,918
197,028
616,472
232,508
93,846
112,041
126,663
219,347
595,465
379,633
703,095
88,531

238,970
94.713
167.376
101,145
504,852
159,717
142,237

1,283,585

1,758,285
76,234
289,303
39,868
29,469
32,466

12,410
18,002

10,336
5.911
26,992

56,963
46,139
48,180

100,387
59,795
73,524
18,306
61,583
96,342
2,785
64,847
38,588
27,576
17,626
47,098
50.482
63,751
48,961
15,033
55,895
27,967
28,658
28,395
3,357
64,826
994,556


31,646
41,112
132,082
77,972
491,640
92,492
46,154
22,959
103,337
95,653
194.535
130,367
629,453
61,469

20,411
18,642
17,624
38,855
41.675
21,112
19,666

131,415
Est.
No
Wells

13,360
97
464
166
246
608

294
558

101
884
181

93
120
1,042

1,310
147
899
259
579
2,761
196
1,892
873
336
469
792
1,970
376
337
472
1,069
436
730
425
472
1,966
584
t

177
146
386
461
680
1,617
308
224
119
375
2,526
3,669
2,117
391

4,119
1,981
899
278
6,875
1.782
2,483

10,268

-------
Table B-3  (Continued).  LOCATION OF LARGE  DOMESTIC OILFIELDS
              State & Field
        ,       ,  Est.   Est.
1974 Prod.1Cun. Prod.Reserves1  No
 10000 bbl loop bbl 1000 bb.1  Wei 1 s
               UTAH
                 Greater  Altamont    21,898    46,197
                 Greater  Aneth  .     7,927   259 554
                 Greater  Red Wash     3,364    90.433
                228,435
                 55,558
                 45.511
223
403
215
WYOMING
Elk Basin
(Wyo.-Mont.) .
Garland . . . .
Grass Creek
Hamilton Dome
Hilight 	
Lance Creek 	
Lost Soldier 	
Oregon Basin
Salt Creek
8,887
3,441
2,764
. 4,454
. 7,358
348
. 3,425
11,354
. 13,284
448,442
112,260
140,295
218,253
48,299
104 632
141,618
240,315
542.518
69,759
25,863
24,605
35,527
85,552
2 359
23,659
79,651
82,113
255
207
248
246
165
44
62
321
1,329
            A
             Volumes in  thousands of 42 gallon barrels.
             1  gallon  =  3.785  liters.


             Source:   "Here  are the  Big U.  S. Reserves",
                       Oil  and Gas  Journ.  73, 116-118
                       (1975).
                                  89

-------
Table B-4.   NATURAL GAS PROCESSING  PLANTS  IN
        THE UNITED STATES,  JANUARY,  1972
State
County
Alabama
Mobile
Alaska
Kenai Burducjh
Arizona
Apache
Arkansas
Columbia
LaFayette
California
Fresno
Kern
Kings and Fresno
Los Angeles
Orange
Santa Barbara
Ventura
Colorado
Arapahoe
l.aPlatta
Logan
Mesa
Morgan
Rio Blanca
Florida
Bradford
Illinois
Dougl as
Kansas
Barber
Ellsworth
Fi nney
Ford
Grant
Harper
Harvey
Kearney
Kingman
Morton
Pratt
Reno
Rush
Scott
Sedgewick
Seward
Stanton
Total Number
of Plants

1
2

1

1
2
1
16
1
17
5
7
6
1
1
1
1
3
4
1
V
1
2
1
1.
5
1
1
1
2
4
1
1
1
1
1
4
f\f>
Total Gas
Capacity1 ,
MMSCFD

2.0
45.0

2.5

75.0
71.0
46.0
833.5
100.0
404.0
140.0
250.0
180.0
8.0
300.0
10.0
20.0
39.0
60.5
900.0
560.0
30.0
1426.0
200.0
25.0
1325.0
85.0
3.0
215.0
125.0
217.5
12.0
--
24.0
' 200.0
130.0
1350.0
7.0
Total Gas
Throughput1 ,
MMSCFD

1.3
34.2

--

40.0
--
53.0
368.7
44.0
225.9
73.9
115.0
60.6
7.6
206.4
6.0
14.3
16.1
34.7
680.0
545.0
..
1360.0
195.0
—
1246.4
44.0
0.9
96.0
126.5
--
--
--
24.0
173.0
116.0
1237.0
5.1

-------
Table B-4 (Continued).    NATURAL GAS PROCESSING PLANTS IN
           THE UNITED  STATES,  JANUARY, 1972
State
County
Kentucky
Floyd
Green
Greenup
Louisiana
Acadia
Allen
Ascension
Assumption
.Avoyelles
Beau regard
Bossier
Caddo
Calcasieu
Cameron
Clai borne
Concordia
East Baton Rouge
Evangel ine
Iberia
IberviHe
Jefferson
Jefferson Davis
Lafayette
Lafourche
Lincoln
Mo rehouse
Natchitoch.es
Quachita
Plaquemines
Pointe Coupee
Richland
St. Bernard
St. Charles
St. James
St. Landry
St. Martin
St. Mary
Tensas
Terrebonne
Vermilion
Webster
North Big Island Field
Total Number
of Plants

1
1
1
7
1
2
3
1
3
5
1
6
13
3
1
1
2
3
1
1
4
1
4
3
1
1
2
7
3
1
4
'2
4
5
6
8
1
14
6
5
1
Total Gas
Capacity1,
MMSCFD

50.0
925.0
—
626.0
24.0
--
--
7.0
21.0
450.0
25.0
--
2269.5
--
7.0
8.0
140.0
165.0
71.0
100.0
425.0
32.0
211.0
330.0
500.0
150.0
140.0
2620.0
130.0
. 15.0
3165.0

75.5
312.0
--
3436.0
120.0
2615.5
2200.0
333.5
1.5
Total Gas
Throughput1 ,
MMSCFD

50.2
--
--
438.5
12.6
--
--
--
17.9
90.1

--
--
76.7
3.3
5.0
118.0
92.0
69.0
76.0
--
33.3
135.0
90.0
500.0
154.0
41.0
—
"—
17.4
2904.0
--
. 32.8
297.0
--
--
60.0
--
--
189.4
0.8
                            91

-------
Table B-4 (Continued).   NATURAL GAS PROCESSING PLANTS IN
           THE UNITED STATES, JANUARY, 1972
State
County
Michigan
Crawford
Hillsdale
Osceola
St. Clair
Washtenau
Mississippi
Adams
Clarke
Forrest
Jasper
Marion
Pike
Smith
Montana
Fall on
Glacier
Mussel shell
Powder River
Richland
Roosevel t
Nebraska
Cheyenne
Kimball
New Mexico
Eddy
Lea
McKinley
Rio Arriba
Roosevel t
San Juan
North Dakota
Burke
Williams
Oklahoma
Alfalfa
Beaver
Beckham
Blaine
Caddo
Canadian
Carter
Cimarron
Cleveland
Total Number
of Plants

1
1
1
1
1

1
2
1
1
2
1
1
1
1
1
1
1
1
1
1
5
23
1
1
1
5
'2
1
1
7
1
2
1
1
2
1
2
Total Gas
Capacity1 ,
MMSCFD

1.5
38.0
54.0
35.0
600.0

4.0
40.0
60.0
10.0
29.0
20.0
15.0
5.8
30.0
4.0
25.0
6.0
2.5
12.5
12.0
330.0
—
—
95.0
56.5
1368.0
32.0
105.0
45.0
310.0
225.0
70.0
7.0
125.0
80.0
50.0
__
Total Gas
Throughput1 ,
MMSCFD

1.0
30.5
52.0
29.0
600.0

0.7
26.0
11.8
--
10.5
7.2
8.0
5.0
20.0
1.0
9.5
4.0
0.8
7.0
6.1
__
•--
--
68.4
36.7
1271.2
....
76.2
33.1
264.7
95.0
47.5
--
105.8
72.4
42.0
_.
                            92

-------
Table B-4 (Continued):   NATURAL GAS PROCESSING PLANTS IN
           THE UNITED STATES, JANUARY, 1972
State
County
Creek
Custer
Dewey
Ellis
Garfield
Garvin
Grady
Grant
Harper
Hughes
Kay
Kingfisher
Lincoln
Logan
Love
Major
Marshall
McLean
Noble
Okfuskee
Oklahoma
Pontotoc
Semi no le
Stephens
Texas
Woodward
Pennsylvania
Elk
Venango
South Dakota
Butte
Texas
Anderson
Andrews
Aransas
Atacosa
Bee
Bexar
Brazoria
Brooks
Calhoun
Callahan
Carson
Cass
Chambers
Total Number
of Plants
2
2
6
1
5
4
2
3
1
1
4
4
3
1
• 2
3
1
4
1
1
4
2
3
5
6
3

1
1
1

1
8
1
4
3
1
10
7
4
1
1
2
4
Total Gas
Capacity1,
MMSCFD
26.0
58.0
195.0
50.0
203.0
--
--
50.0
225.0
25.0
388.7
248.0
37.0
35.0
73.0
162.0
27.0
65.0
3.0
1.0
186.0
6.5
60.0
--
369.0
321.0

4.0
4.0
38.0

15.0
422.0
75.0
--
207.0
150.0
2509.7
714.0
273.0
5.0
10.0
85.0
__
Total Gas
Throughput1 ,
MMSCFD
•: "? - •
50.0
152.0
10.0
152.9

72.0
39.2
206.5
. -_
338.7
201 .4
--
14.4
--
--
19.7
M.4
2.0
0.6

5.6
15.5
'
315.4
-- .

2.5
0.8
30.0

6.0
176.2
64.0
, 160.1
134.0
105.0
1661.9
558.9
173.2
3.0
7.0
55.0
__
                               93

-------
Table B-4 (Continued).   NATURAL  GAS PROCESSING PLANTS IN
           THE UNITED STATES,  JANUARY,  1972
State
County
Cherokee
Cochran
Colorado
Comanche
Concho
Cooke
Crane
Crockett
Dawson
Dewi tt
Dimmitt
Duval
Eastland
EC tor
Erath
Fisher
Fort Bend
Franklin
Frio
Gaines
Galveston
Gray
Grayson
Gregg
Hale
Hans ford
Hardeman
Hard in
Harris
Harrison
Henderson
Hidalgo
Hockley
Hopkins
Houston
Howard
Hutchinson
Irion
Jack
Jackson
Jefferson
Jim Hogg
Jim Wells
Karnes
Kenedy
Total Number
of Plants
1
1
4
1
1
2
6
6
2
1
1
2
4
8
1
2
3
1
1
3
4
6
3
5
1
2
1
3
5
4
3
11
. 3
1
1
1
9
2
3
5
7
2
5
1
1
Total Gas
Capacity1 ,
MMSCFD
30.0
25.0
595.0
5.0
14.0
33.0
--
183.0
8.0
150.0
15.0
105.0
23.3
811.0
25.0
30.0
132.0
50.0
20.0
113.0
93.0
245.0
75.0
--
16.0
510.0
15.0
139.0
--
360.0
235.0
639.0
122.0
--
40.0
55.0
1093.0
30.6
19.0
--
--
108.0
826.0
60.0
210.0
Total Gas
Throughput1
MMSCi'.i
15.1
20.0
391.7
0.7
10.7
21.6
--
155.?,
--
130.0
18.0
62.6
18.6
--
6.0
29.6
108.6
41.0
9.0
52.5
53.7
--
--
61.1
16.0
--
6.0
81.2
--
116.6
170.4
311.3
99.7
13.0
30.0
--
—
26.5
14.6
--
233.8
74.7
--
49.0
203.6
                                94

-------
Table B-4 (Continued).    NATURAL  GAS PROCESSING PLANTS IN
           THE UNITED STATES,  JANUARY,- 1972
State
County
Kent
Kleberg
Lavaca
Leon
Liberty
Live Oak
McClennan
McMul 1 en
Madison
Marion
Martin
Matagorda
Maverick
Midland
Montague
Montgomery
Moore
Navarro
Nolan
Nueces
Ochiltree
Palo Pinto
Panel a
Parker
Pecos
Potter
Reagan
Reeves
Refugio
Runnels
Rusk
San Patricio
Schleicher
Scurry
Shackleford
Smith
Starr
Stephens
Stonewall
Taylor
Terry
Tom Green
Upton
Van Zandt
Victoria
Total Number
of Plants
1
2
3
1
4
5
1
2
1
1
2
9
1
7
1
5
7
1
3
10
2
3
6
2
9
2
3
2
5
1
4
8
•1
4
2
2
7
6
1
1
1
2
6
3
3
Total Gas
Capacity1,
MMSCFD
16.0
1759.0
275.0
10.0
152.0
267.0
60.0
47.0
20.0
3.2
23.0
1001.0
5.0
—
25.0
160.0
1590.0
12.0
36.0
938.0
250.0
120.0
--
135.0
--
230.0
198.0
38.0
386.5
1.1
58.5
—
56.0
303.0
25.0
13.0
252.0
—
16.0
8.0
5.0
7.0
--
105.0
149.0
Total Gas
Throughput' ,
MMSCFD
12.0
1760.5
132.5
1.7
76.2
137.2
46.4
?6.0
19.7
2.5
19.0
--
2.2
--
6.8
105.6
666.0
11.0
24.9
776.6
—
85.0
--
106.7
--
129.1
106.6
—
179.1
0.2
—
247.7
; .50.4
--
17.0
4.6
246.0
--
9.8
2.5
4.7
3.9
--
57.1
89.5
                                95

-------
         Table B-4 (Continued).   NATURAL GAS PROCESSING PLANTS IN
                    THE UNITED STATES, JANUARY, 1972
State
County
Waller
Ward
Webb
Wharton
Wheeler
Wilbarger
Willacy
Kinkier
Wise
Wood
Yoakum
Young
West Panhandle Field
San Juan
Uintah
West Virginia
Kanawha
Wayne
Wetzel
Wyomi ng
Campbel 1
Carbon
Converse
Crook
Fremont
Johnson
Lincoln
Natrona
Park
Sublette
Sweetwater
Uinta
Washakie
Volumes in million standard
1 SCF = 0.0267 normal cubic
Source: Process Research, Ii
Total Number
of Plants
1
4
1
2
2
1
2
7
2
5
2
3
1
2
1

1
1
1

9
2
2
2
2
1
1
1
2
1
2
1
1
cubic feet per day.
meters .
rtc.. Screening Report, Crude Oil
Total Gas
Capacity1 ,
MMSCFD
1260.0
--
190.0
130.0
--
1.4
119.0
--
--
--
237.0
23.0
90.0
180.0
38.0

35.0
170.0
80.0

151.6
222.5
108.0
J7.0
94.6
15.0
250.0
80.0
22.7
20.0
40.0
100.0
50.0


and Natural
Total Gas
Throughput1 ,
MI4SCFD
1076.0
--
130.0
67.5
21 .0
0.7
49.9
--
239.4
"0
226.5
15.6
45.0
103.8
17.6

29.0
104.0
82.5

129.8
195.1
"
9.0
77.4
4.7
190.6
60.0
18.7
12.4
36.5
28.5
31.5



Gas Production Processes,  PB-222718, Cincinnati. Ohio, 197T7
                                       96

-------
Table B-5.   WELLS DRILLED IN THE U.  S.
State
Alabama
Alaska
Arizona
Arkansas
California
Colorado
Florida
Georgia
Idaho
Illinois
Indiana
Iowa
Kansas
Kentucky
Louisiana
Mary! and
Michigan
Mississippi
Missouri
Montana
Nebraska
Nevada
New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Total
1974
95
32
11
300
1,993
823
48
5
2
740
403
2
3,066
734
3,001
2
390
463
55
648
228
2
1,138
311
10
134
1,785
3,063
Wells Drilled
1975 Forecast
124
119
8
306
2,199
901
96
0
0
773
407
0
3,117
766
3,387
0
526
534
24
691
262
4
1,237
327
0
198
1,765
3,147
                   97

-------
 Table B-5 (continued).   WELLS  DRILLED  IN  THE  U.  S.
                                      TOTAL WELLS DRILLED
  State                             1974     1975 Forecast
Pennsylvania
South Dakota
Tennessee
Texas
Utah
Virginia
West Virginia
Wyoming
1,327
10
no
10,309
187
52
822
1,072
1,281
17
112
10,952
212
48
816
1,147
TOTAL U. S.                       33,373        35,503
Source:  "Drillers Sank More Wells than Considered in Early-
         Year Planning". Oil and Gas Journal  73(4), 110-111
         (1975).
                            98

-------
             APPENDIX C





PARTIAL LISTING OF DOMESTIC PRODUCERS
               99

-------
                             Table C-l.   PARTIAL LISTING OF DOMESTIC PRODUCERS
            Company
              Production
      Office Location
Integrated Oil  Companies
Amerada Hess Corp.
American Petrofina,  Inc.

Ashland Oil, Inc.

Atlantic Kichfield  Co.

Champ!in Petroleum  Co.
Cities Service Co.
Colorado Interstate Corp.
Continental Oil Co.
Crown Central Petroleum Corp.
Diamond Shamrock Oil and Gas Co.

El Paso Natural Gas Co.

Exxon Corp.

Getty Oil Co.

Gulf Oil Corp.

Hunt Oil Co.
Husky Oil,  LTD.

Kerr-McGee  Corp.

Marathon Oil Co.

Mobil Oil Corp.

Murphy  Oil  Corp.

National Cooperative Refinery
Association
Pennzoil Co.
Phillips Petroleum  Co.

Quaker  State Oil Refining Corp.
Shell  Oil  Co.

The Signal  Companies,  Inc.
 Skelly Oil  Co.
 Standard Oil Co. of California

 Standard Oil Co. (Indiana)
 The Standard Oil Co.  (Ohio)

 Sun Oil Co.
229,000 bpd crude
19,000 bpd crude and condensate  and
55 HMscfd natural gas in USA and
Venezuela
23,000 bpd crude and 32 MHscfd
natural gas - mid 1973
Worldwide figures for 1972 - 651,900
bpd crude and 2 billion scfd natural
gas
1972 - 4,400 bpd crude and 16,600 bpd
natural gas liquids
1972 - 1.85 trillion cubic feet
delivered to sales
1972 U. S. Production - 1,073,000 bpd
crude and natural gas liquids
1973 Worldwide Production - 420,000 bpd
crude and natural gas liquids
1971 Worldwide Production - 3,282,200
bpd crude and natural gas liquids

1972 - 39,272 bpd crude and natural
gas liquids and 81,462 Mcfd natural gas
1971 Net Production - 15.2 million
barrels of crude and natural gas liquids
1972 domestic production - 189,600 bpd
crude and natural gas liquids and 442.9
million cfd natural gas
1972 - 2 million bpd crude and natural
gas
1971 - 49,000 bpd crude and natural gas
liquids and 66,000 Mcfd natural gas
1973 - 8,500 bpd crude
 1972 - 363,100  bpd  crude and  natural
 gas  liquids
 1971 - 2,710 bpd  crude
 1972 - 629,000  bpd  crude and  natural
 gas  liquids
 1972 Worldwide Production  -  3,3.24,000
 hpd crude and natural  gas  liquids
 1972 - 50,055 bpd crude  and  natural
 gas liquids
   72 - 369,007 bpd crude and 49,598  bpd
   tural. gas liquids
                   100
New York, New York
Dallas, Texas

Ashland, Kentucky

Los Angeles, California

Fort Worth, Texas
New York, New York
Colorado Springs, Colorado
Houston, Texas
Baltimore, Maryland
Amarillo, Texas

El Paso, Texas

New York, New York

Los Angeles, California

Pittsburgh,  Pennsylvania

Dallas,  Texas
Calgary, Alta,  Canada

Oklahoma City,  Oklahoma

Findlay, Ohio

New  York, New York

El Dorado,  Ark.

McPherson,  Kansas

Houston, Texas
Bartlesville,  Oklahoma

Oil  City,  Pennsylvania
Houston, Texas

Beverly Hills,  California
Tulsa, Oklahoma
San  Francisco,  California

 Chicago, Illinois
 Cleveland,  Ohio

 St.  Davids, Pennsylvania

-------
                      Table C-l  (Continued).-.  PARTIAL LFSTING OF DOMESTIC PRODUCERS
             Company
               Production
                                                                                        Office Location
 Integrated Oil  Companies (Cont.)
 Tenneco Inc.

 Texaco, Inc.

 Texas Eastern Transmission Corp.
 Union Oil  Company of California
 1972 - 81,778 bpd crude and natural  gas
 liquids and 938 MMcfd natural  gas
 1972 - 4,021,000 bpd crude and natural
 gas liquids
 1971  - 326,800 bpd crude  and  1.6  billion
 scfd  natural  gas
 Large Independents
 A.  L. Abercrombi
 J.  S. Abercrombi  Mineral  Co.,  Inc.
 Ada Oil  Co.
 Adobe Corp.
 J.  W. Akin
 Aladdin  Petroleum Corp.
 Alpar Resources,  Inc.

 Allen and Shumate,  Inc.
 Altex Oil Corp.
 Aluminum Company  of America
 Amarex,  Inc.
 Amax  Petroleum Corp.
 American Independent Oil  Co.
 American Natural  Gas Production
 Co.
 American Pacific  International,
 Inc.
 American Trading  and Production
 Corp.
 Ames  011 and Gas
 Anchor Production,  Co.
 Ancora-Verde Corp.
 James K. Anderson
 Richard  S. Anderson, Inc.
 A&N Producing Services, Inc.
 Anschutz, Corp.
 An-Son Corp.
 Antelope Gas Products Co.
 Morris R. Antweil
 Apache Corp.

 Apco 011  Corp.
 Apexco,  Inc.
Appleton Oil Co.
Aquitainc Oil  Corp.
Aracca Petroleum Corp.
Ard Drilling Co.
Argo Petroleum Corp.
Armer Oil Co.
 Monthly Production  -  37,000 bbl crude,
 500 MHcf natural  gas
Proven Reserves Dec., 1972 - 99,790,450
Mcf natural gas; 7,826,000 barrels crude
 Houston,  Texas

 New York, New York

 Houston,  Texas
 Los Angeles,  California
Wichita,  Kansas
Houston,  Texas
Houston,  Texas
Midland,  Texas
Wichita  Falls, Texas
Wichita,  Kansas
Perryton, Texas

Alice, Texas
Vernal, Utah
Pittsburgh, Pennsylvania
Oklahoma  City, Oklahoma
Houston,  Texas
New York, New York
Detroit,  Michigan

Los Angeles, California

Baltimore, Maryland

Houston, Texas
Tulsa, Oklahoma
San Francisco, California
Midland, Texas
Midland, Texas
Jackson, Mississippi
Denver, Colorado
Oklahoma City, Oklahoma
Midland, Texas
Hobbs, New Mexi co
Minneapolis, Minnesota

Houston, Texas
Minneapolis, Minnesota
Oklahoma City, Oklahoma
Houston, Texas
New York, New York
Midland, Texas
Los Angeles, California
Fort Worth,  Texas
                                                      101

-------
                      Table C-l (Continued).    PARTIAL  LISTING OF DOMESTIC PRODUCERS
            Company
             Production
      Office. Location
Large Independents (Cont.)
Armour Properties
Atlantic International  Oil Corp,
Atlantic Oil Co.
Austral  Oil Co., Inc.
Aztec Oil and Gas Co.

Bailey Gas Systems, Inc.
Barber Oil Exploration, Inc.
Barber Oil Inc.
J. C. Barnes Oil Co.
Barnwell Drilling Co.,  Inc.
Basin Oil Co.
Basin Petroleum Corp.
H. W. Bass and Sons,  Inc.
Perry R. Bass
Murphy H. Baxter
Bay Rock, Corp.
Beard Oil Co.
Beaver Mesa Exploration Co.
Belco Petroleum Corp.

Belden and Blake Oil  Production
Bell Brothers
J. Ainslic Bell
Kelly Bell
Bell Petroleum Co.
Bel ridge Oil Co.
Benedum-Trees Oil Co.
Bengal Producing Co.
Bennett, Mills, Estate
Bennett Production Corp.
Beren Corp.
Berry and Ewing
Thomas N. Berry and Co.
Bertman Gas and Oil Corp.
Big 6 Drilling Co.
Big Four Petroleum Co.
Blackrock Oil Co.
Blackwood and Nichols Co.
Blaik Oil Co.
B. B. Blair
BKG,  Inc.
Bock  and Bacon
Bolin Oil Co., A Partnership
Bond  Operating Co.
Bonray  Oil  Co.
Daily Production  - 3,000  bbl  crude;
103 MMcf natural  gas
1970 - 90.1  MMcfd  natural  gas;
33,762 bpd crude and condensate
Wichita  Falls,  Texas
Columbus,  Ohio
Los Angeles,  California
Houston, Texas
Dallas,  Texas

Tulsa, Oklahoma
Houston, Texas
Carlesbad,  New  Mexico
Midland, Texas
Shreveport, Louisiana
Big Springs,  Texas
Oklahoma City,  Oklahoma
Dallas, Texas
Fort Worth, Texas
Houston, Texas
San Antonio,  Texas
Oklahoma City,  Oklahoma
Denver,  Colorado
New York,  New York

Canton, Ohio
.Robinson,  Illinois
Los Angeles,  California
Midland, Texas
Encino,  California
Los Angeles,  California
Pittsburgh, Pennsylvania
Dallas,  Texas
Houston, Texas
Bowie, Texas
Denver,  Colorado
Taft, California
Stillwater, Oklahoma
Houston, Texas
Houston, Texas
Cashing, Oklahoma
Midland, Texas
Oklahoma City,  Oklahoma
Oklahoma City,  Ofcla.
Tulsa, Oklahoma
Independence, Kansas
Houston, Texas
Wichita  Falls,  Texas
Dallas,  Texas
Oklahoma City,  Oklahoma
                                                      102

-------
                     Table C-l  (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
            Company
             Production
                                                                                         Office Location
 Bounty Production Co.
 BP Alaska Inc.
 BP North America, Inc.
 Bracken Oil Co.
 Bradco Oil and Gas Co.
 The Bradley Producing Corp.
 Brea Canon Oil Co.
 T.  S. Bridges Oil Operating Co.
 Brldwell Oil Co.
 Bright and Schiff Oil and Gas
 Producers
 Brooks Hall Oil Corp.
 H.  L. Brown, Jr.
 Maurice L. Brown Trust
 BTA Oil Producers
 George L. Buckles Company
 Burk Royalty Company
 Burlington Northern Inc.
 Burmah Oil Development, Inc.

 R.  L. Burns Corp.
 Buttes Gas and Oil Co.
 W.  K. Byrom
 Cabeen Exploration Corp.
 Cabot Corp.
 Cactus Operating Co.
 Caddo Oil  Co., Inc.
 Gallery Properties,  Inc.
 Cal-Mon Oil  Co.
 Calvert Funds, Inc.
 Capataz Corp.
 Cardinal  Petroleum Co.
 Carlsberg Petroleum Corp.
 F. William Carr
 Carter and Mandel Co.
 Caul kins  Oil  Co.
 Cayman Corp.

 Cenard Oil  and Gas Co.
 Cenex (Farmers Union  Central
 Exchange,  Inc.)
 Century Petroleum, LTD.
 Chambers  Mauren
Champlin  Exploration, Inc.
Chandler  and Associates, Inc.
Chanslor-Western Oil  and
Development  Co.
Charter Oil  Co.
4,000 bpd crude; 24 MMscfd natural
gas
                                                     103
San Antonio, Texas
New York, New York
New York, New York
Tyler, Texas
Houston, Texas
Wellsvilie, New  York
Brea, California
Fort Worth, Texas
Wichita Falls, Texas
Dallas, Texas

Oklahoma City, Oklahoma
Midland, Texas
Kansas City, Missouri
Midland, Texas
Monahans, Texas
Wichita Falls, Texas
Billings, Montana
New Orleans, Louisiana

San Bernardino, California
Oakland, California
Hobbs, Mew Mexico
North Hollywood, California
Boston, Massachusetts
Wichita Falls, Texas
Shreveport, Louisiana
Houston, Texas

Tulsa, Oklahoma
Midland, Texas
Billings, Montana
Los Angeles, California
Corpus Christi, Texas
Lubbock, Texas
Denver, Colorado
Palos Verdes Peninsula,
California
Dallas, Texas
St. Paul, Minnesota

Fort Worth, Texas
Coalinga, California
Enid, Oklahoma
Denver, Colorado
Chicago, Illinois

Jacksonville, Florida

-------
                   Table C-l (Continued).    PARTIAL LISTING OF DOMESTIC PRODUCERS
            Company
Production
Office Location
Chartiers LTD.
Chase Production Co.
D. C. Cheesman and Son
Cheyenne Petroleum Co.
Chorney Oil Co.
Citronelle Unite
.City of Long Beach
C&K Petroleum, Inc.
Clarcan Petroleum Corp.
Cleverock Energy Corp.
Clinton Oil Co.
Coal Oil and Gas Co.
Estate of George H. Coates
Collier Diamond C Oils, Inc.
C. G. Collins Petroleum Corp.
Columbia Drilling Co.
Columbia Oil Corp.
Condor Operating Co.
Connally Oil Co., Inc.
Consolidated Oil and Gas, Inc.
Cooper and Brain, Inc.
Cordele Operating Co.
Cornell, Drew, Inc.
Cornell Oil Co.
Coronado Oil Co.
Edwin L. Cox
Creslenn Oil Co.
Crestmont Oil Co.
Houston Petroleum Co.
Crystal Oil Co.
Cummins and Walker Oil Co., Inc.
Da Mac Drilling Co., Inc.
Damson 011 Corp.
Danoil, Inc.
The Daube Co.
Davis Investment Co.
Davis Oil Co.
Dearing Inc.
Deck Oil Co.
Depco Inc.
Delhi International Oil Corp.
Delta Drilling Co.
Diamond M. Drilling Co.
Ray J.  Diekemper, Jr.
Dorchester Exploration,  Inc.
0.  L. Dorland
                               Midland,  Texas
                               Oxnard,  California
                               Houston,  Texas
                               Oklahoma  City,  Oklahoma
                               Denver,  Colorado
                               Citronelle,  Alabama
                               Long Beach,  California
                               Houston,  Texas
                               Denver,  Colorado
                               Denver,  Colorado
                               Wichita,  Kansas
                               Ardmorc!,  Oklahoma
                               San Antonio, Texas
                               Fort Worth,  Texas
                               Campbellsvilie, Kentucky
                               Houston,  Texas
                               San Angelo,  Texas
                               Odessa,  Texas
                               Abilene,  Texas
                               Denver,  Colorado
                               Wilmington,  California
                               Corsicana, Texas
                               Lafayette, Louisiana
                               Dallas,  Texas
                               Denver,  Colorado
                               Dallas,  Texas
                               Dallas,  Texas
                               San Marino,  California
                               Houston, Texas
                               Shreveport,  Louisiana
                               Corpus Christi, Texas
                               Great Bend,  Kansas
                               New York, New York
                               Fort Worth,  Texas
                               Ardmore, Oklahoma
                               Long Beach,  California
                               Denver,  Colorado
                               Dallas,  Texas
                               Tulsa, Oklahoma
                               Denver,  Colorado
                               Dallas,  Texas
                               Tyler, Texas
                               Houston, Texas
                               Lubbock, Texas
                               Midland, Texas
                               Midland, Texas
                                                       104

-------
                   Table C-l  (Continued).    PARTIAL LISTING OF DOMESTIC PRODUCERS
           Company
             Production
                                                                                      Office Location
The Dow Chemical Co.
Drilling and Production Co.
Dugan Production Corp.
Halter Duncan Oil Properties
Eason Oil. Co.
Edinger Inc.
Eldorado Oil and Gas, Inc.
Elf Petroleum Corp. - U.S.A.
Elk Oil Co.
Engineered Operating Company
Equity Oil Co.
Exchange Oil and Gas Corp.
Expando Production  Co.
Fair Oil Co.
Falcon Petroleum Co.
Falcon Seaboard,  Inc.
Olen F. Featherstone
Felmont Oil  Corp.
Bob Ferguson
Ferguson and Bosworth
Bert G.  Fields
Fikes, Leland,  Estate
Five Resources, Inc.
Flag-Redfern
Florida  Gas  Exploration Co.
Fora Co.
Forest Oil  Corp.
Formax Oil  Co.
Fortune Drilling Corp.
Fortune Production Co.
Francis Oil  and Gas, Inc.
Freeport Oil Co.
Frost Oil  Co.
Galaxy Oil Co.
Samuel Gary, Oil Producer
General  American Oil Co.
of Texas
General Crude Oil  Co.
General Exploration Co.
The GHK Co.
GilUland 011 and  Land Co.
Warren Ginther and Co.
Goldking Production Co.
Goldston Oil Corp.
Grace Petroleum Corp.
Graham - Michaelis Corp.
1971  - 30,000 bpd crude  and  condensate;
183,000 Mcfpd natural  gas
Houston, Texas
Torrance, California
Farmington, New Mexico
La Salle, Illinois
Oklahoma City, Oklahoma
Oklahoma City, Oklahoma
Dallas, Texas
New York, New York
Roswell, New Mexico
Wichita Falls, Texas
Salt Lake City, Utah
New Orleans, Louisiana
Wichita Falls, Texas
Tyler,  Texas
Coalinga, California
Houston, Texas
Roswell, New Mexico
New York, New  York
Los Angeles,  California
Bakersfield,  California
Dallas, Texas
Dallas, Texas
Houston, Texas
Midland, Texas
Jackson, Mississippi
Borger, Texas
 Bradford,  Pennsylvania
 Irvine, California
 San Angelo, Texas
 Fort Worth, Texas
 Tulsa, Oklahoma
 New Orleans, Louisiana
 San Antonio, Texas
 Wichita Falls, Texas
 Denver, Colorado
 Dallas, Texas

 Houston, Texas
 Los Angeles, California
 Oklahoma City, Oklahoma
 Santa Maria, California
 Houston, Texas
 Houston, Texas
 Houston, Texas
 New York,  New York
 Wichita, Kansas
                                                       105

-------
                     Table C-l (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
              Company
                                                    Production
                                                                                          Office Location
 Graner Oil Co.
 Gray Operating Co., Inc.
 Great Basins Petroleum Co.
 Great Expectations Oil  Corp.
 Great Plains Land Co.
 Great Western Drilling  Co.
 Great Yellowstone Corp.
 Green & Michael son Producing  Co.
 H.  J.  Gruy and Associates,  Inc.
 Gulf Interstate  Overseas  Ltd.
 Henry H.  Gungoll  & Associates
 Hadson Ohio Oil  Co.
 Michel  T.  Halbouty
 Halliburton Oil  Producing Co.
 Claude B.  Hanill,  Independent Producer
 Hamilton  Bros. Oil  Co.
 Jake L. Hamon
 Hanagan Petroleum  Corp.
 Roger  C.  Hanks
 Hanover Planning Co. Inc.
 Hanson Oil  Corp.
 Harding Oil  Co.
 Har-Ken Oil  Co.
 Harkins & Co.
 Wayne Harper
 Dan J. Harrison, Jr.
 Sam G. Harrison
 Hathaway Co.
 Estate of William G. He!is
Helmerich & Payne, Inc.
 Herley Kelly Co.
 Herman Geo. Kaiser, Oil  Producer
Herndon Drilling Co.
A. E. Hermann Corp.
 Hewit & Dougherty
 Estill S.  Heyser, Jr.
Highland Resources, Inc.
A. G. Hill
Hilliard Oil & Gas, Inc.
W. B. Hinton Drilling Co.,  Inc.
Hissom Drilling Co.
 HNG Oil Co.
Holder Petroleum Corp.
Holloway Dynamics, Inc.
W. W. Holmes, Operator
 Long Beach, California
 Ardmore, Oklahoma
 Los Angeles, California
 Fort Worth, Texas
 Dallas, Texas
 Midland, Texas
 Tulsa, Oklahoma
 Midland, Texas
 Dallas, Texas
 Houston, Texa',
 Enid, Oklahoma
 Oklahoma City, Oklahoma
 Houston, Texas
 Oklahoma City, Oklahoma
 Houston, Texas
 Denver, Colorado
 Dallas, Texas
 Roswell, New Mexico
 Midland, Texas
 New York, New York
 Roswell, New Mexico
 Dallas, Texas
 Owensboro,  Kentucky
 Alice,  Texas
 Dallas, Texas
 Houston,  Texas
 Houston,  Texas
 Santa  Fe Springs,  California
 New Orleans,  Louisiana
 Tulsa,  Oklahoma
 Long Beach,  California
 Tulsa,  Oklahoma
 Tulsa,  Oklahoma
 Amarillo, Texas
 Beeville, Texas
 Dallas,  Texas
 Houston,  Texas
 Dallas, Texas
 Menlo Park, California
 Mt. Pleasant, Texas
 Midland, Texas
 Midland, Texas
 Lovington, New Mexico
Austin, Texas
Merced, California
                                                     106

-------
                     Table C-l  (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
            Company
                                                   Production
                                                                                         Office Location
Home Stake  Production  Co.
Houston  Oil  and  Minerals Corp.
Houston  Production Co.
Howell  Drilling, Inc.
H & S Oil  Co.
J. M. Huber Corp.
William A.  & Edward R. Hudson
Roy M.  Huffington, Inc.
Hughes & Hughes Oil & Gas
Hughes & New Oil Co., Inc.
Thomas D.  Humphrey, Oil Properties Ltd.
Indiana Farm Bureau Cooperative
Associates  Inc.
Industrial  Development Associates
Inexco Oil  Co.
Tom L.  Ingram
Inlet Oil Corp.
Intercontinental  Energy Corporation
International Energy  Co.
Invent, Inc.
The Iron Mountain Oil  Co.
L.  B. Jackson Co.
T.  L. James & Co., Inc.
Jefferson  Lake  Sulphur Co.
 Jenkins Drilling  & Supply Co.
 Jenney  Oil  Co., Inc.
 Jernigan  Oil  Company
 F. T.  Johnson,  Jr.
 A. V.  Jones & Sons
 Jones - B'Brien,   Inc.
 Josey Oil  Co.
 J - W Operating Co.
 G. E. Kodane & Sons
 Kaiser - Francis  Oil Company
 Kathol Petroleum,  Inc.
 Katz Oil  Co.
 Kentucky Drilling and Operating  Corp.
 Kewance Oil Co.
 S.  H.  Killingswdrth
  Kllmarnock Oil Co.
  Kilroy Co. of  Texas,  Inc.
  Klmball Production Co.
  Kimbell Oil Company
  Kingery  Drilling Co., Inc.
  King Oil  Co.
500 bpd oil  & gas production
Tulsa, Oklahoma
Houston, Texas
Houston, Texas
San Antonio, Texas
Artesia, New Mexico
Houston, Texas
Fort  Worth, Texas
Houston, Texas
Beeville, Texas
Natchez, Mississippi
Dallas, Texas
Indianapolis,  Indiana

Sante Fe  Springs,  California
New York,  New York
 Roswell,  New Mexico
 Dallas, Texas
 New York,  New York
 Dallas, Texas
 Houston, Texas
 Forth Worth, Texas
 Tulsa, Oklahoma
 Ruston, Louisiana
 Houston, Texas
 Oklahoma City, Oklahoma
 Chestnut Hill, Massachusetts
 Oklahoma City, Oklahoma
 Wichita Falls, Texas
 Albany, Texas
 Shreveport,  Louisiana
 Houston, Texas
 Dallas, Texas
 Wichita  Falls,  Texas
 Tulsa, Oklahoma
 Wichita,  Kansas
  San Antonio., Texas
  Lexington, Kentucky
  Bryn Mawr, Pennsylvania
  Longview, Texas
  New Orleans, Louisiana
  Houston, Texas
  Houston, Texas
  Fort Worth, Texas
  Ardmore, Oklahoma
  Tulsa, Oklahoma
                                                         107

-------
                       Table C-l (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
             Company
             Production
          Office Location
King Resources Co.
Kirby Petroleum Co.
Kissinger Petroleum Corp.
KKA Corp.
K & K Oil Co.
Knight & Miller Oil Corp.
Knox Industries, Inc.
Koch Industries, Inc.
KRM Petroleum Corp.
Krumme Oil Co.
Laco Oil Co.
Ladd Petroleum Corp.
Lake Konel Oil Co.
Lamb Oil & Gas
Lano Oil & Gas Co.
Forrest C. Lattner
Laymac Corp.
Lear Petroleum Corp.
Lloyd Corp. LTD.
Lofton Oil Co.
Logue & Patterson, Inc.
Lohman - Johnson Drilling Co. Inc.
Lone Star Gas Co.
Nipak, Inc.
Long Beach Oil Development Co.
Longhorrt Production Co.
Longstreet 011 Corp.
Louisiana Land & Exploration Co.
Louisiana - Pacific Resources,  Inc.
Ralph Lowe Estate
Lubell Oil Co.
Luling Oil & Gas Co., Inc.
LVO Corp.
Lyons Petroleum Corp.
Mabee Petroleum Corp.
MacDonald 011 Corp.
MacKellar, Inc.
Mack Oil Co.
MACPET
Madison Oil Co.
Magellan Petroleum Corp.
Magness Petroleum Co.
Hagulre 011 Co.
Mallard Exploration, Inc.
1971 total  production - 119 MMcf
natural gas; 3,882,589 bbl  crude;
205.4 million gallons natural  gas
liquids
Denver, Colorado
Houston, Texas
Denver, Colorado
Houston, Texas
Los Angeles, California
Denver, Colorado
Midland, Texas
Wichita, Kansas
Denver, Colorado
Bristow, Oklahoma
Abilene, Texas
Denver, Colorado
Tyler, Texas
Portland, Texas
Wichita, Kansas
San Antonio, Texas
Bakersfield, California
Dallas, Texas
Beverly Hills, California
Wichita Falls, Texas
Dallas, Texas
Evansville, Indiana
Dallas, Texas
                                         Dallas, Texas
                                         Long Beach,  California
                                         Dallas, Texas
                                         McAllen, Texas
                                         Now Orleans, Louisiana
                                         Palo Alto, California
                                         Midland, Texas
                                         Tulsa, Oklahoma
                                         San Antonio, Texas
                                         Tulsa, Oklahoma
                                         Shreveport,  Louisiana
                                         Tulsa, Oklahoma
                                         Dallas, Texas
                                         Oklahoma City, Oklahoma
                                         Duncan, Oklahoma
                                         St. Paul, Minnesota
                                         Wichita Falls, Texas
                                         Hartford, Connecticut
                                         Oklahoma City, Oklahoma
                                         Dallas, Texas
                                         Midland, Texas
                                                       108

-------
                     Table C-l (Continued).   .PARTIAL LISTING OF DOMESTIC PRODUCERS
               Company
                                                     Production
                                                                                            Office Location
 Manziel  Interests
 Marrion  Corp.
 Mark Production Co.
 The Mayflower Co.
 Maynard Oil Co.
 The Mayronne Co.
 McAlester Fuel Co.
 W. C. McBride, Inc.
 McClellan Oil Corp.
 McCormick Oil & Gas Corp.
 McCulloch Oil Corp.

 McMahon - Bullington Drilling Co.
 McMoran Exploration Co.
 McRae Oil Corp.
 Meadco Properties
 John W.  Mecom
 Medders  Petroleum Corp.
 Mesa Petroleum Corp.
 Miami  Oil  Producers,  Inc.
 Michigan  Oil  Co.
 Midwest Oil  Corp.
 Minerals  Management,  Inc.
 George Mitchell  & Associates,  Inc.

 M.  J. Mitchell
 Mohoma Petroleum  Corp.
 Moncrief  Oil  Interests
 Monsanto  Co.
 Moranco
 E.  F. Moran,  Inc.
 Morgan Brothers
 Mormac Oil & Gas Co.
 Robert Mossbacher
 Moss Petroleum Co.
 MWJ Producing Co.
 National Oil Co.
 Natol Petroleum Corp.
 Natomas Co.
 Natural Resources Corp.
 Newmont Oil Co.
 North American Resources Corp.
 North American Royalties, Inc.
 Northern Pump Co.
Northwest 011 Co.
Northwest Production Corp.
Nueve Operating Co. of Texas
1968 total production - 1,412,028 bbl
crude; 1,371,117 Mcf natural gas
200 Mcfd gas; 15,000 bpd oil,
distillates, plant products
                                                       109
 Tyler, Texas
 Mobile, Alabama
 Tyler, Texas
 Oklahoma City, Oklahoma
 Dallas, Texas
 Harvey, Louisiana
 McAlester, Oklahoma
 St Louis, Missouri
 Roswell, New Mexico
 Houston, Texas
 Los Angeles, California

 Wichita Falls, Texas
 Dallas, Texas
 Houston, Texas
 Midland, Texas
 Houston, Texas
 Wichita Falls, Texas-
 Amarillo,  Texas
 Abilene, Texas
 Alma,  Michigan
 Denver, Colorado
 Casper, Wyoming
 Houston, Texas

 Dallas, Texas
 Fort Lauderdalc,  Florida
 Fort Worth,  Texas
 St  Louis, Missouri
 Hobbs,  Mew Mexico
 Evansville,  Indiana
 Wichita Falls,  Texas
 Corpus  Christi,  Texas
 Houston, Texas
 Dallas, Texas
 Midland, Texas
 Los Angeles, California
 Oklahoma City, Oklahoma
 San Francisco, California
 Denver, Colorado
 Houston, Texas
 Houston, Texas
 Chattanooga, Tennessee
 Minneapolis, Minnesota
 Dallas, Texas
 El Paso, Texas
Abilene, Texas

-------
                   Table C-l  (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
               Company
                                                   Production
            Office Location
Oakland Corp.
Occidental Petroleum Corp.
Ocean Drilling & Exploration Co.
Oceanic Exploration Co.
Estate of Gladys 0'Donne 11
Offshore Exploration Oil Co.
Oilfield Consultants, Inc.
Oil, Gas and Minerals Corp.
Oil & Gas Futures, Inc.
Oil Management Corp.
Oil Ventures International   Inc.
Oleum, Inc.
Charles W. Oliphant
Joseph I O'Neill Properties
Onyx Oil Co.
W. B. Osborn, Operator
Pacific Lighting Exploration Co.
Pacific Oil  & Gas  Co.
Pan Ocean Oil Corp.
Pantepec  International,  Inc.
Pardue Oil
Patoil Corp.
Pauley Petroleum  Inc.
Payne  - Johnston
Pearson -  Sibert Oil  Co. of Texas
Peet Oil  Co.
Pel-Tex.  Inc.
Perkins & Cull urn
Perkins Production Co.
Perkins Production Co.
 Perkins - Prothro  Co.
 Perryman  Operating Co., Inc.
 Petro Grande, Inc.
 Petroleum Corporation of Texas
 Petroleum, Inc.
 Petroleum International, Inc.
 Petroleum Management, Inc.
 Petroleum Research Corp.
 Petroleum Resources Co.
 Petrox Development Corp.
 Pexamin, Inc.
 B. R. Phillips, Jr.
 The Pickens Co.,  Inc.
 D. W. Pickett
 Daniel J.  Pickrell
 Pip  Petroleum  Corp,
Shreveport, Louisiana
Los Angeles, California
New Orleans, Louisiana
Denver, Colorado
Wilmington, California
Newport Beach, California
Houma, Louisiana
Woodland Hills, California
New Orleans, Louisiana
Dallas, Texas
New York, New York
Longview, Texas
Tulsa, Oklahoma
Midland, Texas
Abilene, Texas
San Antonio, Texas
Los Angeles, California   .
Oklahoma City, Oklahoma
New York,  New York
Hartford,  Connecticut
Breckenridge, Texas
San Antonio, Texas
Los Angeles, California
Tyler,  Texas
Beverly Hills,  California
San Antonio, Texas
Houston,  Texas
Wichita Falls,  Texas
Wichita Falls,  Texas
Duncan, Oklahoma
Wichita Falls,  Texas
Athens, Texas
 Dallas, Texas
 Breckenridge,  Texas
 Wichita, Kansas
 Tulsa, Oklahoma
 Laurel, Mississippi
 Littleton, Colorado
 Cushing, Oklahoma
 Great Nick, New York
 Houston, Texas
 Dallas, Texas
 Dallas, Texas
 Corpus Christi, Texas
 Burlingame, California
 Bloomfield Hills, Michigan
                                                        110

-------
                      Table C-l (Continued).    PARTIAL  LISTING OF DOMESTIC PRODUCERS
                Company
                                                    Production
                                                                                            Office Location
Pitcock, Inc.
Polaris Production Corp.
Prewitt Oil Corp.
Prochemcho Exploration Co.
Prudhoe Production, Inc.
Publishers Petroleum
Pyramid Oil Co.
Quintana Petroleum Corp.
Rancho Oil Co.
Ray Resources Corp.
Reading & Bates  Oil & Gas Co.
Relco  Exploration Co.,  Inc.
Reserve Oil  and  Gas Co.

Riddle & Gotlieb
Roark  & Hooker
Robbins Petroleum  Corp.
Rocket Oil Co.
Royal  International  Petroleum Corp.
Royal  Oil  &  Gas  Corp.
James  E.  Russell Petroleum,  Inc.
Rutherford Oil  Corp.
 Ryder  Scott  Management Co.
 Sabine Royalty Corp.
 Sage Oil  Co. Inc.
 Samedan Oil  Corp.
 Samson Resources Co.
 Corey  arid Josey Schneider, Inc.
 Scoggins Petroleum Corp.
 Scope  Industries
 Seitz  & Comegys Oil Co.
 Serio Exploration Co.
 Shaheen Natural Resources Co., Inc.
 Sheldon Petroleum Co.
 Shenandoah Oil  Corp.
 Fred  W. Shield
 S. &  J. Operating Co.
 Sklar & Phillips & Associated  Co.
 R. E.  Smith
 Southern  Hydrocarbons  Production
 Co.,  Inc.
 Southern  States Oi1  Company
 Southland Royalty  Co.
 South Louisiana Production Co.i  Inc.
  Ralph Spence
  SRG Oil  Corp.
  Staley Oil  Co.
1973 - 10,306 bpd crude &
condensate; 35,302 Mcfd
natural gas
Graham, Texas
Midland, Texas
Abilene, Texas
Houston, Texas
McAllen, Texas
Oklahoma City, Oklahoma
Santa Fe, California
Houston, Texas
Dallas, Texas
Charleston, West  Virginia
Tulsa,  Oklahoma
Monroe, Louisiana
Los  Angeles,  California

San  Antonio,  Texas
Abilene, Texas
Longview,  Texas
Duncan, Oklahoma
New Orleans,  Louisiana
 Indiana,  Pennsylvania
Abilene,  Texas
 Houston,  Texas
Wichita Falls,  Texas
 Dallas, Texas
 Los Angeles, California
 Ardmore,  Oklahoma
 Tulsa, Oklahoma
 Dallas, Texas
 Dallas, Texas
 Los Angeles, California
 Wichita Falls, Texas
 Natchez, Mississippi
 New York, New York
 Lubbock, Texas
 Fort Worth, Texas
 San Antonio, Texas
 Wichita Falls, Texas
 Shreveport, Louisiana
 Houston, Texas
 New Orleans, Louisiana

 Jackson, Mississippi
 Fort Worth,  Texas
 Alexandria,  Louisiana
 Tyler, Texas
 Abilene,  Texas
 Wichita  Falls,  Texas
                                                          111

-------
                      Table C-1  (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
                Company
Production
                                                                                             Office Location
C. R. Starnes, Et Al
Albert Stevenson, Estate
J. B. Stoddard, Estate
Stroube Development Co.
Suburban Propane Gas Corp.
Sullivan and Co.
Summitt Energy, Inc.
Sundance Oil Co.
Sunrise Oil, Inc.
The Superior Oil Co.
Sylvan Oil Operating Co.
Tamarack Petroleum Co., Inc.
Tonnehill Oil Co.
Teal Petroleum Co.
Paul C. Teas
The Termo Co.
Tesoro Petroleum Corp.
Texas American Oil Corp.
Texas Crude Oil Inc.
Texas International  Co.
Texas Oil & Gas Corp.
Texas Pacific Oil Co., Inc.
Texfel Petroleum Corp.
J. Cleo Thompson
Thums Long Beach Co.
Tipperary Corp.
J. D. Tompkins
Traders Oil Company of Houston
Transocean Oil, Inc.
Trend Exploration Ltd.
Triad Oil and Gas Co., Inc.
Trico Industries, Inc.
Trinidad Petroleum Corp.
Triton Oil & Gas Corp.
Allen K.  Trobaugh
True Oil  Co.
Trumpter Petroleum Corp.
Tucker Drilling Co., Inc.
Twin Montana, Inc.
Union Texas Petroleum Division
United Oil Corp.
Universal Resources  Corp.
Upham Oil & Gas Co.
U. S. Natural Resources, Inc.
U - Tex Oil Co.
UV Industries Inc.
                                                     112
                            Gladewater, Texas
                            Los Angeles, California
                            Dallas, Texas
                            Corsicana, Texas
                            San Antonio, Texas
                            Tulsa, Oklahoma
                            Dallas, Texas
                            Denver, Colorado
                            Fort Lauderdale, Florida
                            Los Angeles, California
                            Tulsa, Oklahoma
                            Milwaukee, Wisconsin
                            Monterey, California
                            Houston, Texas
                            Dallas, Texas
                            Long Beach, California
                            San Antonio, Texas
                            Midland, Texas
                            Fort Worth, Texas
                            Oklahoma City, Oklahoma
                            Dallas, Texas
                            Dallas, Texas
                            Los Angeles, California
                            Dallas, Texas
                            Long Beach, California
                            Midland, Texas
                            Abilene, Texas
                            Houston, Texas
                            Houston, Texas
                            Denver, Colorado
                            Jackson, Mississippi
                            Gardena, California
                            Birmingham, Alabama
                            Dallas, Texas
                            Midland, Texas
                            Casper, Wyoming
                            Fort Worth, Texas
                            San Angelo, Texas
                            Graham, Texas
                            Houston, Texas
                            Oklahoma City, Oklahoma
                            Dallas, Texas
                            Mineral Wells, Texas
                            Menlo Park, California
                            Salt Lake City, Utah
                            Salt Lake City, Utah

-------
                        Table C*l (Continue)!}'.   PARTIAL LISTING OF DOMESTIC PRODUCERS
                 Company
            Production
           '  Office Location
Vanderbllt Resources Corp.
Van Dyke Oil  Co.
Varn Petroleum Co.
Vaughey & Vaughey
Vaughn Petroleum, Inc.
Venus Oil Co.
W. D. Vestal  011  Co.
Victory Oil Co.
Viersen & Cochran
Vincent & Welch,  Inc.
Ralph II. Viney & Associates
A. J. Vogel,  Inc.
Wadsworth Oil Co.
W. T. Waggoner Estate
Keith F. Walker
Walsh & Watts, Inc.
0. F. Warren & Co., Inc.
Warrior Oil Co.
Watson Oil Co.
Webb Resources
R. P. Webb
Weco Development Corp.
Weeks Natural Resources, Inc.
Wei law Corp.
Westates Petroleum  Co.
West Coast Oil Co.
Western Oil Shale Corp.
Western States Producing Co.
Westheimer - Neustadt Corp.
Westland Oil Development Corp.
W. Ridley Wheel  Estate
White Shield Oil &  Gas  Corp.
Whitestone Corp.
M. H. Whittier Corp.
Whittington Operating Co.
Wise Operating,  Inc.
The  Wiser Oil  Co.
Witco Chemical Corp.
Wollfson Oil  Co.
Woodbine Production Corp.
Woods Petroleum  Corp.
Yates Petroleum  Corp.
J. Lee  Youngblood
250 MMscf per month gas
Dallas, Texas
Houston, Texas
Wichita, Kansas
Jackson, Mississippi
Dallas, Texas
San Antonio, Texas
Iowa Park, Texas
Long Beach, California
Okmulgee, Oklahoma
Lake Charles, Louisiana
Midland, Texas
Midland, Texas
Houston, Texas
Vernon, Texas
Ardmorei Oklahoma
Fort Worth, Texas
Tulsa, Oklahoma
Denver, Colorado
Shreveport, Louisiana
Denver, Colorado
Vernon, Texas
Denver, Colorado
Westport, Connecticut
Midland, Texas
Los Angeles,  California
Oildale, California
Midland, Texas
San Antonio,  Texas
Ardmore, Oklahoma
Houston, Texas
Fort  Worth, Texas
Tulsa, Oklahoma
Greenwich,  Connecticut
Los Angeles,  California
Houston,  Texas
Tyler, Texas
Sisterville,  West  Virginia
New York,  Mew York
Dallas, Texas
 Kilgore,  Texas
Oklahoma  City,  Oklahoma
Artesia,  New Mexico
 Dallas, Texas
                                                       113

-------
                     Table C-l  (Continued).   PARTIAL LISTING OF DOMESTIC PRODUCERS
	Company	Production	Office  Location
Marshall R. Young Oil Co.               .                                       Fort Worth, Texas
Yucca Petroleum Co.                                                            Amarillo,  Texas
Zephyr Oil Co.                                                                 Tyler, Texas
Source:  U.S.A. Oil Industry Directory.  13th Ed.  Tulsa,  Oklahoma,
         The Petroleum Publishing Company, 1974.
                                                          114

-------
             APPENDIX D




MATERIALS FOR DRILLING FLUID SYSTEMS
                   115

-------
                               Table 0-1.   MATERIALS FOR DRILLING  FLUID SYSTEMS
                                               Fresh Water Muds
  Product Trade Name

Ala-Clay

Al-Gel
Ala-Lig
Ala-Phos
Ala-Tan
Ala-Thin
Alamo CMC
Alamo Quebracho
A. C. Quebracho
Anhydrox
Aid ay

Altan
Altan Pure
Alpine  Lignite
Alpine  Graphite
AP-25,  AP-44
Alkatan
Aquagel
Atlas Gel
Atlas Lig
Barafos
Barium  Carbonate
Barium  Carbonate
Barium  Carbonate
 Baroco
Benex
Bicarb, of Soda
 Caustic Soda
 Carbonox
 Control gel
 Caso
 Control M-D
 Control tan
 Controlcal
 Cellex
 Control old
 Control sol
 C-M-C
 Cronox 211
 Cypan
 Caltrol
 Calcium Chloride
 Dowcide G
 Driscose (Sev.  Grades)
 Oakol i te
 Emulsifier SMB
 Emulsite
 E  P  Mudlube
 Floxit
 Graphite
 Green  Band
  Gypsum
  High Yield
  Hydrogel
  Hexaphos
  Hydropel
  Hydrocarb
  Hydrotan
  H.Q.M. Starch
  Impermex
  Impermex Preservative
  Kero-X
  Kw1k-Thik
  Kemical
  Kembreak
  Kylo
          Description
Blended sodium montmorillinite
  and calcium mont.
Sodium montmorillinite
Caustic ligm'n
Sodium tetraphosphate
Caustic tannin
Mined lignite
Sodium carboxymethyl-cellulose
Quebracho extract
Quebracho-lignite compound
Barium carbonate
Sub-bentonite

Quebracho mixture
Pure quebracho
Mined lignite
Graphite
Caustic tannin
Caustic quebracho
Wyoming bentonite
Wyoming bentonite
Lignitic  compound
Sodium  tetraphosphate
Barium  carbonate
Barium  carbonate
Barium  carbonate
Sub-bentonite
Sodium polyacrylate
Bicarbonate of soda
Sodium hydroxide
Organic thinner
Bentonite
 Potassium stearate
 Drilling detergent
 Lignite
 Calcium lignosulfonate
 Sodium carboxymethyl-cellulose
 Pregelatinized starch
 Nonionic surfactant
 Sodium carboxymethyl-cellulose
 Fresh water corrosion inhibitor
 Sodium polyacrylate
 Calcium chloride
 Calcium chloride
 Bactericide
 Sodium carboxymethyl-cellulose
 Processed  lignite
 Inorganic  emulsifier
 Caustic  lignite
 Extreme  pressure lubricant
 Polyelectrolyte
 Graphite lubricant
 Sub-bentonite
 Gypsum
 Sub-bentonite
 Bentonite
 Phosphate
 Emulsified asphalt
 Caustic  carbonox
 Caustic  tannin
 Grain-based starch
  Pregelatinized starch
  Formaldehyde compound
  Defoaming  agent
  Extra high-yield bentonite
  Quick lime
  Calcium lignosulfonate
  Sodium polyacrylate

                     116
    Maker or Distributor

Alamo Lumber Co.

Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lumber Co.
Alamo Lurcher Co.
Baroid Div. National
  Lead Co.
Alpine Mud  Service
Alpine Mud  Service
Alpine Mud  Service
Alpine Mud  Service
Alpine Mud  Service
Alpine Mud  Service
Magcobar
Baroid Div. National  Lead Co.
Atlas Mud Company
Atlas Mud Company
Baroid Div. National  Lead Co.
Magcobar
Milwhite Mud  Sales  Company
Mud Control Laboratories
Baroid Div. National  Lead Co.
 1
 1
 1
 Baroid  Div. National  Lead Co.
 Mud Control Laboratories
 Mud Control Laboratories
 Mud Control Laboratories
 Mud Control Laboratories
 Mud Control Laboratories
 Baroid Div. National Lead Co.
 Mud Control Laboratories
 Mud Control Laboratories
 1
 United Engineering Corp.
 1
 Milwhite Mud Sales Co.
 1
 1
 1
 1
 Baroid  Div. National  Lead Co.
 Magcobar
 Baroid  Div. National  Lead Co.
 Magcobar
 1
 Milwhite Mud  Sales  Corp.
  1
 Magcobar
 Brown Mud Co.
  1
  1
  Baroid  Div.  National Lead Co.
  Baroid  Div.  National Lead Co.
  1
  Baroid  Div.  National Lead Co.
  Baroid  Div.  National Lead Co,
  Baroid  Div.  National Lead Co.
  Magcobar
  1
  Marathon Chemical  Corp.
  1

-------
                        Table 0-1  (Continued).    MATERIALS  FOR DRILLING  FLUID SYSTEMS
                                            Fresh Hater Muds  (Cont.)
  Product Trade Name

Llgco
L1me
Lube-Flo
Lubri-Film
Lignox
Llg-No-Sol
Maccogel
Kagcogel
Magcophos
Me Quebracho
May Gel
.May Clay
Haylig
Maystarch
May col
Maco-Hex, Maccoflos
Macco-Lig
Mikol Starch
Mil gel
Mil Graphite
Mil starch
Mil Flo
Mud-Bac
Mud Floe
Mil-Natan  1-2
Mil Quebracho
My-Lo-Jel
Palcotan
Palcotan 905
Pel tex
P-95
Polytone
Pyro, Anhydrous
Paraformaldehyde
   Preservative
 Phosphate
 Q8T
 Q-Broxin
 Q-X Quebracho
 Quebracho
 Qualex
 Quick-Gel
 Ray  Flo
 RD 111
 Ranger Pure Quebracho
 Sapp
 Spersene
 Shale-Ban
 Soda  Ash
 Sodium Bichromate
 Sol tex
 Super-Col
 Superllgco
 Shale-Rez
 Sodaphos
 Super ben
 Superyield
 Super Quebracho
 Super Thin
 Super Starch
 Smentox

 Tannex
 Tanco
 Tannathin
 Tower-Gel
 Treat
 TSPP
 T-8
 Uni-Cal
 Uni-Gel
          Descri pti on
     Maker or Distributor
Mineral lignite
Calcium hydroxide
Ground gilsonite
Extreme pressure lubricant
Calcium lignosulfonate
Modified lignosulfates
Wyoming bentonite
Uyonring bentonite
Sodium tetraphosphate
Quebracho
Wyoming bentonite
Sub-bentonite
Mineral lignite
Pregelatinized starch
Calcium chloride
Complex .phosphates
Mineral lignite
Pregelatinized starch
Wyoming bentonite
Graphi te
Pregelatinized starch
Modified polyflavinoid Comp,
TrisNitro (bactericide)
Flocculant.
Caustic quebracho
Quebracho (pure)
Pregelatinized starch
Lignosulfonate
Redwood bark extract
Modified lignosulfonate
California clay
Treated lignite
Pyrophosphate
Paraformaldehyde

Complex phosphates
Quebracho-based  thinner
Ferrochrome  lignosulfonate
Quebracho compound
Quebracho
Sodium carboxymethyl-cellulose
Extra high yield bentonite
Hemlock extract
Processes lignosulfonate
Pure  Quebracho
Sodium acid  pyrophosphate
Chrome lignosulfonate
Shale control  compound
Soda  ash
Sodium bichromate
Mud lubricant
 Extra high yield bentonite
 Caustic lignite
High  pressure lubricant
 Phosphate
 Wyoming bentonite
 Sub-bentonite
 Quebracho mixture
 Mineral  lignite
 Pregelatinized starch
 Cement contamination treating
   agent
 Quebracho compound
 Quebracho compound
 Lignite
 Wyoming bentonite
 Causticized lignite
 Tetra sodium pyrophosphate
 Shale control mud
 Modified alkyl aryl sulfonate
 Wyoming bentonite

                  117
Milwhite Mud Sales Co.
1
1
Milwhite Mud Sales Co.
Baroid Div. National Lead Co.
Alpine Mud Service
Macco Corp.
Magcobar
Magcobar
Magcobar
May Brothers, Inc.
May Brothers, Inc.
May Brothers, Inc.
May Brothers, Inc.
May Brothers, Inc.
Macco Corp.
Macco Corp.
1
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
1
Mud Control Laboratories
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Magcobar
 1
 1
Alamo Lumber Co.
Macco Corp.
 1
 1
 1

 1
 Mud Control  Laboratories
 Baroid  Div.  National  Lead Co.
 Magcobar
 1
 1
 Baroid  Div.  National  Lead Co.
 1
 1
 May Brothers,  Inc.
 1
 Magcobar
 Baroid  Div.  National  Lead Co.
 1
 1
 1
 Milwhite Mud Sales Co.
 Milwhite Mud Sales Co.
 Brown Mud Co.
 1
 Superbar Sales
 Superbar Sales
 Superbar Sales
 Superbar Sales
 Superbar Sales
 Baroid Div. National Lead Co.

 Baroid Oiv. National Lead Co.
 Milwhite Mud Sales Co.
 Magcobar
 Black Hills Bentonite
 Atlas Mud Co.
 1
 Magcobar
 Milwhite Mud Sales Co.
 United Engineering Corp.

-------
                        Table 0-1 (Continued).   MATERIALS FOR DRILLING FLUID SYSTEMS
                                           Fresh Water  Muds  (Cont.)
  Product Trade Name

Viz-Thin
Workover Clay
Wyo-Jel 200
X-Cor
XP-20
          Description
Lignite pitch
Low yield workover clay
Bentoni te
Corrosion inhibitor
Chrome lignite
     Maker or Distributor

1
Milwhite Mud Sales Co.
Archer-Daniels-Midland
Baroid Div. National Lead Co.
Magcobar
                                                 Salt Water Muds
Ala-Sol
Alpine Gel
Atlas Salt Gel
Atlosol S
Attapulgus 150
Ceox
Control foam
Cronox 609
Defoamer No. 23
Emulsifler S
F-S Clay
Florigel
Florigel H-Y
Heviwater
Maysal Clay
Salt
Salt Gel
Salt-Drill
Salt Water Gel
Super  Sal
Attapulgite clay
Attapulgite clay
Attapulgite clay
Anionic-noniom'c surfactant
Attapulgite clay
Emulsifier
Defoamer
Corrosion inhibitor
Mud defoamer
Nonionic emulsifier
Attapulgite clay
Attapulgite clay
Attapulgite clay
Mud dispersant
Attapulgite clay
Sodium chloride
Attapulgite clay
Hemlock bark extract
Attapulgite clay
Attapulgite clay
Alamo Lumber Co.
Alpine Mud Service
Atlas Mud Co.
Atlas Chemical Ind.
Min. & Chem. Philipp
Mud Control Laboratories
Mud Control Laboratories
United Engineering  Corp.
Baroid Div. National  Lead  Co.
1
United Engineering  Corp.
Floridin Co.
Floridin Co.
Dowel1 Div., Dow Chem.
May Brothers,  Inc.
1
Magcobar
1
Milwhite Mud Sales  Co.
Superbar Sales
                                           Air/Gas Drilling Materials
Afrox
Atlas Corrosion Inhibitor
100
Atlas Hi -Foam
AM-9
G-2
Gafen Fa-1
Foaming agent •
Polar organic

Nonionic surfactant
Chemical grout
Foaming agent
Foaming agent, fresh to mod.
1
Atlas Mud Co.

Atlas Mud Co.
1
Dowel 1 Div., Dow Chemical
Antara Chemical
 Gafen Fa-5

 Gafen Fa-7
 Halliburton-Sorb
 Howco-Suds
 Hydro-Lok
 Oilfos
 OK Liquid
 Synfoam
 Tergltol NP-35

 Tergitol NPX

 Tergitol TMN

 Well-Foam FS
 Well-Foam 3
 Well-Foam 917
 Well-Parch
   salt
 Foaming agent,  saturated
   salt
 Foaming agent,  fresh  and  saline
 Water absorbing agent
 Surfactant,  foaming agent
 Water Shutoff plastic slurry
 Deflocculating agent
 Foaming agent
 Foaming agent
 Nonyl phenyl  polyethylene
   glycol ether
 Nonyl phenyl.polyethylene
   glycol ether
 Trimethyl nonyl ether of
   polyethylene glycol
 Foaming agent
 Foaming agent
 Corrosion inhibitor
 Dryin and anti-ballin agent
 Antara  Chemical

 Antara  Chemical
 Halliburton Co.
 Halliburton Co.
 Halliburton Co.
 1
 1
 Mud Control Laboratories
 1
 Well  Completions, Inc.
 Well  Completions, Inc.
 Well  Completions, Inc.
 Well  Completions, Inc.
                                            Invert Emulsion  and Oil Muds
  Atlas-Invert 400
  Black Magic Supermix
  Black Magic Premlx
  •Chemical  V

  Chemical  W
  Control  Invert
 Polyoxyethylene product,
 Fluid for high temp,  wells
 Oil fluid, not high weight
 Additive to Black Magic, improve
   gel
 Treating agent for Black Magic
 Oil mud concentrate

                    118
 Atlas Mud Co.
 Oil  Base, Inc.
 Oil  Base, Inc.
 Oil  Base, Inc.

 Oil  Base, Inc.
 Mud Control  Laboratories

-------
                        Table  0-1  (Continued).   MATERIALS FOR DRILLING FLUID SYSTEMS
                                       Invert Emulsion and Oil  Muds (Cont.)
  Product Trade Name

Control Emulsion Oil
Driloil
Driltreat
Duratone
Economagic
E-Z Mul

Gel tone
Hot Lime
Invermul
Invertin
Jel-Oil
Ken Oil
Ken-X Concentrate 1
Ken-X Concentrate 2
Ken-X Concentrate 3
OB Mixflx
OB Gel
Petrotone
Peptomagic
Perm-Base
Perm-Wate
Protectomagic
Protecto-Mul
No-Bloc
Special  Additive  47
Special  Additive  58

Therm-oil
           Description
Nonionic surfactant
Oil mud concentrate
Oil mud stabilizer
Oil mud filtration control  agent
Crude-oil based completion  fluid
Emulsifier for CaCl solutions in
  oil
Oil mud gelling agent
Varifat lime
Oil mud emulsifier
Emulsifier
Oil mud
Oil mud
Invert emulsifier
Stabilizer (weight)
Stabilizer (temperature)
Viscosity reducer
To increase viscosity
Oil mud  suspending agent
Crude oil-based fluid
Oil mud  concentrate
Calcium  carbonate
Oil dispersed asphalt
Concentrate for invert emulsion
Invert emulsion fluid
To improve suspension properties
To improve suspension, gel
   properties
Invert emulsion concentrate
     Maker or  Distributor

Mud Control  Laboratories
Baroid Div.  National Lead Co.
Baroid Div.  National Lead Co.
Baroid Div.  National Lead Co.
Oil Base, Inc.
Baroid Div.  National Lead Co.

Baroid Div.  National Lead Co.
1
Baroid Div.  National Lead Co.
Dowell Div., Dow Chemical
Magcobar
1
1
1
1
Oil Base, Inc.
Oil Base, Inc.
Baroid Div. National Le.'id Co.
Oil Base, Inc.
Macco Corp.
Maceo Corp.
Oil Base, Inc.
Magcobar
Magcobar
 Oil Base, Inc.
 Oil Base, Inc.

 Milwhite Mud  Sales  Co.
                                                 Low Solids Muds
 Alloid
 Anti-Foam
 Atlas  Emulso 500
 Atlas  Drilling Surfactant
 Atlasfloc
 Barafloc
 Dril Hex
 Driscose
 Loloss
 Lube Flow
 Mac-0-Mul

 Mudfloc

 Separan
 Pregelatinized  starch
 Capryl  alcohol
 Non-ionic surfactant
 Anionic surfactant
 Flocculating gum
 Clay flocculant
 Guar gum
 Sodium carboxymethyl-cellulose
 Gum Guar
 Shale control
 Non-ionic surfactant,
   emulsifier
 Highly active flocculating
   agent
 Flocculating agent
 Alpine Mud Service
 Milwhite Mud Sales Co.
 Atlas Mud Co.
 Atlas Mud Co.
 Atlas Mud Co.
 Baroid Div. National  Lead Co.
 1
 1
 Baroid Div. National  Lead Co.
 1
 Macco Corp.

 Mud Control Laboratories

 Milwhite Mud Sales Co.
                                               Surface Active  Agents
 Aluminum Stearate
 Atlas Drilling Surfactant
   100
 Atlas Drilling Surfactant
   200
 Atlas Drilling Surfactant
   300
 Atlas Emulso 500
 Atlosol
 Ceox
 Con Det
 Control M-D
 Control Emulsion Oil

 Control Flow
 Control sol
 Aluminum s tea rate
 Anionic surface active
   emulsifier
 Petroleum sulfonate

 Nonionic surfactant

 Nonionic surfactant
 Mixed esters
 Soluble oil-type surfactant
 Anionic detergent
 Low solids mud additive
 Anionic surface active.
   emulsifier
 Oil-soluble surfactant
 Nonionic surfactant and
   emulsifier  ,

                    119
 i
 Atlas Mud Co.

 Atlas Mud Co.

 Atlas Mud Co.

 Atlas Mud Co.
 1
 Mud  Control  Laboratories
 Baroid Div.  National  Lead Co.
 Mud  Control  Laboratories
 Mud  Control  Laboratories

 Mud  Control  Laboratories
 Mud  Control  Laboratories

-------
                          Table D-l  (Continued).    MATERIALS FOR DRILLING FLUID SYSTEMS
                                         Surface Active  Agents  (Cont.)
  Product Trade Name

D-D
Drilling Milk
Drill Lube
DME
DMS
Emulsifier F
Emulsifier S
Maco-Mul
Maco-Lube
Magconate
Mil white M-D
Mi 1-01 ox
Olox
Santomerse
Seeco-Mul
Trimulso
White Magic
            Description
Mud detergent
0/W emulsifier
Surfactant, EP lubricant
For compounding surfactant muds
For compounding surfactant muds
Nonionic surfactant
Nonionic surfactant
Nonionic surfactant, emulsifier
Surfactant, EP lubricant
Petroleum sulfonate
Low-solids mud additive
Vegetable oil soap
Neutralized soap
Sodium alkyl aryl sulfonate
Vegetable oil soap
Emulsifier
Non-fluorescing emulsifier
     Maker or Distributor

Magcobar
Magcobar
1
1
1
1
1
Macco Corp.
Macco Corp.
Magcobar
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
1
1
1
Baroid Div. National Lead  Co.
Oil Base,  Inc.
                                               Weighting Materials
Ala-Bar
Albar
Atlas Bar
Baroid
Control bar
Dri-Job
Drilling Bar
G-7 Super Weight
Galena
Invertiri Wate
Maccowate
Magcobar
Maybar
Mil-Bar
OB  Hevywate
OB  Wate
Superbar
Uni-Bar
Yuba Barite
Barite (barium sulfate)
Barite
Barite
Bari te
Barite
Low gravity barite
Barite
Iron-arsenic compound
Lead sulfide
Acid-soluble material
Barite
Barite
Barite
Barite
Barite
Calcium  carbonate
Bari te
Barite
Barite
Alamo Lumber Co.
Alpine Mud Service
Atlas Mud Co.
Baroid Div. National  Lead Co.
Mud Control Laboratories
Macco Corp.
Drilling Mud,  Inc.
Magcobar
Baroid Div. National  Lead Co.
Dowel 1 Div., Dow  Chemical
Macco Corp.
Magcobar
May Brothers
Milwhite Mud Sales  Co.
Oil Base,  Inc.
Oil Base,  Inc.
Superbar Sales
United Engineering  Corp.
Yuba Milling Div.
                                             Lost Circulation Additives
 Ala-Fiber
 Ala-Flake
 Ala-Mica
 Ala-Plug
 Alseal
 Atlas Fiber
 Atlas Mica
 Ala-Shell
 Alflake
 Alpine Mica
 Aspun Fiber
 Bark-Seal
 Beaver Dam
 Bristex
 Bristex-Seal
 Cel-Flakes
 Cell-0-Phane
 Cell-0-Seal
 Cedar Seal
 Cert-N-Ceal

 Chek-Loss
 Chip-Seal
 Control  Fiber
 Fibrous  material
 Shredded cellophane  flakes
 Shredded mica
 Graded walnut  shells
 Cane,  wood fiber  blend
 Sugar  cane bagasse
 Sized  mica
 Pecan  shells-
 Shredded cellophate  flakes
 Graded mica
 Aspen  fibers
 Shredded tree  bark
 Ground gilsonite
 Hog bristles
 Hog bristles and  cotton lint
 Ground cellophane
 Shredded cellophane  flakes
 Shredded cellophane  flakes
 Cedar fibers
 Delayed action bentonite,
   gran.  mat.
 Sized neoprene rubber
 Shredded wood fiber
 Fibrous material
 Alamo Lumber Co.
 Alamo Lumber Co.
 Alamo Lumber Co.
 Alamo Lumber Co.
 Alpine Mud Service
 Atlas Mud Co.
 Atlas Mud Co.
 Alamo Lumber Co.
 Alpine Mud Service
 Alpind Mud Service
 1
 Alpine Mud Service
 Gibralter Minerals
 1
 1
 United Engineering Corp.
 1
 Magcobar
 1
 1

 Milwhite Mud Sales Co.
 Magcobar
 Mud Control  Laboratories
                                                          120

-------
                           Table D-l  (Continued).    MATERIALS  FOR  DRILLING FLUID SYSTEMS
                                        Lost Circulation Additives  (Cont.)
  Product Trade Name

Control Wool
Cottonseed Hulls
Chemical W
Chrome Leather
Dick's Mud Seal
Feather Stop
Fiber-Seal
Flbertex
Formaplug
Formaseal
Flaxseal
Hy-Seal
Jel flake
Ko-Seal
King Seal
Krevice Klog
Leather Floe
Leather Seal
Leath-0
Magco-Fiber
Magco-Mica
Masterbridge
Masterplug
Masterseal
Mayfiber
Mayflakes
Maymi ca
Micatex
Mil-Cedar Plug
Mil-Fiber
Mi If lake
Milmica
Mil-Plug
Mil Seal
Mil-Wool
Mud Fiber
Mica
Nut Plug
Oil Patch
Palco  Seal
Pheno-Seal
Polyflake
Poly-Plug
Poz-Plug
Plug-Git
Plastic Seal
Rubber Seal
Seal flakes
Silvacel
Stop-It
Strata-Seal
Super  Fiber
Super  Seal
Super  Mica
Superbridge
Tuffernel1
Tuf-Plug
Wall-Nut
Walnut Plug
Wool
           Description
Acid-soluble mineral  wool
Cottonseed hulls
Agent to form gel  pills
Shredded leather
Ground paper
Feathers
Blended fibers
.Cane fibers
Clay-cement
Air blown asphalt
Ground flax shive
Ground paper
Cellophane flakes
Granulated corn cobs
Textile fibers
Drop bags of granular bentonite
Leather fibers
Leather fibers
Leather fibers
Shredded wood fiber
Graded mica
Extra-course almond shells
Shaped rubber
Almond shells
Cane, wood fiber blend
Shredded cellophane flakes
Grade mica
Mica
Cedar wood-fibers
Sugar cane bagasse
Shredded cellophane flakes
Graded mica
Pulverized walnut shells
Wood chips
Fibrous mineral wool
Cane fibers
Sized mica
Ground walnut shells
Ground walnut shells
Processed redwood fibers
Ground plastic
Oil soluble film
Fibers and plastic
Wood chips
Wood fibers
Ground formica
Ground rubber
Fragmented cellulose
Fir and balsum  fiber
Cedar wood fibers
Expanded perlite
Cane, wood fibers
Shredded cellophane flakes
Graded mica
Expanded perlite
Walnut shells
Ground walnut shells
Nutshells
Walnut shells
Mineral wool
     Maker or Distributor

Mud Control Laboratories
1
Oil Base, Inc.
Alamo Lumber Co.
1
Mil white Mud Sales Co.
Magcbbar
Baroid Div. National  Lead  Co.
Magcobar
Oil Base, Inc.
Archer-Daniels-Midland
Baroid Div. National  Lead  Co.
1
Mud Control Laboratories
Alamo Lumber Co.
Baroid Div. National  Lead  Co.
Magcobar
Baroid Div. National  Lead  Co.
Milwhite Mud Sales Co.
Magcobar
Magcobar
Masterseal Sales Corp.
Masterseal Sales Corp.
Masterseal Sales Corp.
May Brothers
May Brothers
May Brothers
^Baroid Div. National  Lead  Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Milwhite Mud Sales Co.
Magcobar
1
Magcobar
Mud Control Laboratories
1
1
Baroid Div. National  Lead  Co.
Cherokee Laboratories
1
Baroid Div. National  Lead  Co.
Alamo Lumber Co.
Atlas Mud Co.
Mud Control Laboratories
1
1
1
Superbar Sales
Superbar Sales
Superbar Sales
Mud Control Laboratories
Ma ceo Corp.
1
Baroid Div. National  Lead  Co.
 i
 Several  distributing companies
Source:   Rogers,  Walter F.,  Composition and Properties of Oil Well Drilling Fluids
          Houston, Texas,  Gulf  Publishing Company, 1963.
                                                           121

-------
. P.tPOHl NO.
 EPA-600/2-77-023b
                                   Tf-CHNICAL RCl'OHT DATA
                           (I'll a\f rca-l lua.~.ifhoni on tin' AC' ' nt Itcjnrr cuinptctingi ^
                         —  J2''   :                     3. w.Cif'
.. TITLE A\D SUU7 ITI.E

Industrial Process  Profiles fcr Environmental Use:
Chapter 2.  Oil  and Gas Production  Industry
                                                           5. Rf-POHT DATE-
                                                              February 1977
                                                           6. PEI-iFORMJNG O H GA XlTZATfo N CODE
 GlynJa E. WilXins
7Pf RFQhM~INU OHGANI.JA1IGN NAME AND ADOmiSS
Radian Corporation
8500 Shoal Creek Boulevard
P.O. Box 99)»8
Austin, Texas  78766
12. SPONSORING Ant'NCY IJAMf /-NL' AOOFU.SS
Industrial Er;vi rorir/intnL Research  Laboratory
Office of Research  and Development
U.S EiTVIRONM'^rAL PROTF.CT'I ON AGENCY
Cincrl-.-ir-ritl, Ohio  V;xf,8
16. SUPPLKVU N I A»Y NO I I S
                                                                 IINT'S ACCtOSIOr*NO.
                                                            8. PERFORMING ORGANIZATION HM'C'HT NO.
                                                           10. 1'HOCjflAM ELLMti'JT NO.

                                                              3AB015
                                                           II.'CONI HACT/GRA'NT NO.
                                                              68-02-13.19, Task 3^1  &r;;i >:

                                                            13. I'YHt OF RLf'ORT AMD PLRIOD CCVi H

                                                              Initial.: 6/7.5=11/16... ......
                                                            14. SF'ONSORING AGtNCY CODE

                                                              KPA/600/12
                                                                                         i 0
 C. ABS1 RACT
The catalog of Industrial  Process Profiles  for Environmental  Use was developed as
aid ir,  defining the environmental Jr::pacts of ipr.v.ptri al  activity in the  United .f-l.
Entries for ?ach industry  are in consistent  for.T.aT, and form separate chapters cf
study.   Tha oil ^.nd gas production industry  is involved  in  locatinr and  ret.j-ievi'n
oil and gas from underground formations  and  preparing the veil streams  for use by
ccnsraers.   The industry is  discussed in five segments:   (l)   Exploration and ?:^
Preparation, (2) Drilling,  (3) Crude Processing, (10 Natural  Gas Processing, and
(5) Secondary &nd Tertiary Recovery.  Tv/o process flow .sheets and tv?nty pi-occss
Oescriutions have teen prepared to characterize the  industry.  Within each proces
description ava.ilab.Le data have been presented on input  materials, operating para.
utility requirements and vaste streams.   Data related to the subject matter, incl
ing company and prod-act dats.,' are included  as appendices.
                                                                                        •~r\
                                                                                       ii.--
                                                                                       -che
                                                                                       .rr.eter
                                                                                       ud-
 7.
.1.
                  fJhECniPVORS
                                KEY WORDS ANO DOCUr.'.ENT At-.'ALYSIS
                                                      IfeRS/OHEN ENDED TERMS
 Pollution
 Oil Production
 Ges Production
i Exploration
}Oil Drilling
 Crude 0.11  rroccssing
 Natural  Gas  Pro:-nt
Solid Waste Cun'-rol
T;nviror:riitntal li pact


 H; 'V; I '-;•>! ."'' Cl./.SS ;•;/ / H, parti
  l>;?n.'if-r.i fied

i
                                                                             COSATI l-ii'ld 'i<
                                                                            07C
                                                                            11H
                                                                            13B
                                                                            21D
                                                                           il, NO OF I-
                                                                                130
                                                                          i2.i'nlCE.
                                             V/2

-------