EPA-650/2-75-058-a July 1975 Environmental Protection Technology Series JOHNS-MANVILLE CHEAF EVALUATION U.S. Off ------- EPA-650/2-75-058-Q JOHNS-MANVILLE CHEAF EVALUATION by Seymour Calvert, Joel Rowan, and Charles Lake Air Pollution Technology, Inc. 4901 Morena Boulevard, Suite 402 San Diego, California 92117 Contract No. 68-02-1496 ROAP No. 21ADL-004 Program Element No. 1AB012 EPA Project Officer: Dale L. Harmon Control Systems Laboratory National Environmental Research Center Research Triangle Park, North Carolina 27711 Prepared for U.S. ENVIRONMENTAL PROTECTION AGENCY OFFICE OF RESEARCH AND DEVELOPMENT WASHINGTON, D. C. 20460 July 1975 ------- EPA REVIEW NOTICE This report has been reviewed by the National Environmental Research Center - Research Triangle Park, Office of Research and Development. EPA, and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Environmental Protection Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. RESEARCH REPORTING SERIES Research reports of the Office of Research and Development, U.S. Environ- mental Protection Agency, have been grouped into series. These broad categories were established to facilitate further development and applica- tion of environmental technology. Elimination of traditional grouping was consciously planned to foster technology transfer and maximum interface in related fields. These series are: 1. ENVIRONMENTAL HEALTH EFFECTS RESEARCH 2. ENVIRONMENTAL PROTECTION TECHNOLOGY 3. ECOLOGICAL RESEARCH 4. ENVIRONMENTAL MONITORING 5. SOCIOECONOMIC ENVIRONMENTAL STUDIES 6. SCIENTIFIC AND TECHNICAL ASSESSMENT REPORTS 9. MISCELLANEOUS This report has been assigned to the ENVIRONMENTAL PROTECTION TECHNOLOGY series. This series debcribcs research performed to develop and demonstrate instrumentation, equipment and methodology to repair or prevent environmental degradation from point and non- point sources of pollution. This work provides the new or improved technology required for the control and treatment of pollution sources to meet environmental quality standards. This document is available to the public for sale through the National Technical Information Service, Springfield, Virginia 22161. Publication No. EPA-650/2-75-058-a 11 ------- TABLE OF CONTENTS Page Abstract List of Figures iv List of Tables Sections Introduction 1 Source and Control System 3 Test Method 5 Operating Conditions 13 Particle Data 15 Particle Penetration 23 Opacity 27 Economics 29 Manufacturer's Description of Device 31 Operational Problems 33 Conclusions 35 Appendix A 37 Appendix B 45 111 ------- LIST OF FIGURES No. Page 1 Schematic Drawing of CHEAP System 4 2 Modified E.P.A. Sampling Train with Heated Precutter and Cascade Impactor 6 3 Modified E.P.A. Sampling Train with Precutter and Heated Cascade Impactor with Attached Final Filter 10 4 Modified E.P.A. Sampling Train with Precutter, Cascade Impactor, and Heated Final Filter . . .11 5 Inlet Size Distributions 16 6 Inlet and Outlet Size Distributions 17 7 Run 18 Wet and Dry Size Distributions 20 8 Run 19 Wet and Dry Size Distributions 21 9 Theoretical Power and Pressure Drop Vs. Aero- dynamic Cut Diameter 30 B-l Cumulative Inlet Mass Concentration for Run #10 47 B-2 Cumulative Outlet Mass Concentration for Run #10 47 B-3 Cumulative Inlet Mass Concentration for Run #11 48 B-4 Cumulative Outlet Mass Concentration for Run #11 48 B-5 Cumulative Inlet Mass Concentration for Run #12 49 B-6 Cumulative Outlet Mass Concentration for Run #12 49 IV ------- No. Page B-7 Penetration Versus Dry Particle Diameter for Run #10 50 B-8 Penetration Versus Dry Particle Diameter for Run #11 51 B-9 Penetration Versus Dry Particle Diameter for Run #12 52 ------- LIST OF TABLES No. A-l Inlet and Outlet Total Particulate Loading for Runs 4 and 5 39 A-2 Inlet and Outlet Sample Particle Data for Run #6 39 A-3 Inlet and Outlet Sample Particle Data for Run #7 40 A-4 Inlet and Outlet Sample Particle Data for Run #8 40 A-5 Inlet and Outlet Sample Particle Data for Run #9 40 A-6 Inlet and Outlet Sample Particle Data for Run #10 41 A-7 Inlet and Outlet Sample Particle Data for Run #11 42 A-8 Inlet and Outlet Sample Particle Data for Run #12 42 A-9 Inlet and Outlet Total Particulate Loading for Runs #13 and #14 Using E.P.A. Method 5. . . 43 A-10 Dry and Wet Sample Particle Data for Run #17. . 43 A-ll Dry and Wet Sample Particle Data for Run #18. . 44 A-12 Dry and Wet Sample Particle Data for Run #19. . 44 VI ------- ABSTRACT Fine particulate collection efficiency as a function of dry particle size has been computed from data taken on Johns-Manville's CHEAP system. The CHEAP controls emissions from a diatomaceous earth calcining and drying process with an overall collection efficiency of 95%. The unit was operating at a capacity of 710 Am3/min (25,000 ACFM), at 63°C (145°F), with a pressure drop of approximately 50 to 53 cm water column (19.5 to 21 inches W.C.). Initial test results showed inlet and outlet size dis- tributions to be identical with a mass mean diameter of 0.82 ymA and a geometric standard deviation of 3.9. The data analysis indicates that particle penetration is rela- tively independent of particle diameter. Further testing revealed that particle growth occurs prior to the CHEAP system. Simultaneous heated and unheated impactor runs provided dried particle size distribution and actual (or wet) size distribution existing inside the scrubber, re- spectively. Particle growth was then determined and showed that particles grew as much as three times their original size in the submicron range and less for larger sizes. This particle growth to a more uniform size can explain why penetration is relatively independent of inlet dry particle size. vn ------- INTRODUCTION Air Pollution Technology, Inc. (A.P.T.), in accord- ance with E.P.A. Contract No. 68-02-1496, "Experimental Tests of Novel Fine Particulate Collection Devices", con- ducted a performance evaluation on Johns-Manville's Clean- able High Efficiency Air Filtration System (CHEAP) . From November 5 through November 15, 1974, the A.P.T. sampling team performed simultaneous inlet and outlet particle sampling measurements on the CHEAP system. After the data were analyzed, further testing was scheduled to determine whether particle growth was occurring prior to the CHEAP system. Therefore, on March 17 through March 21, 1975, the sampling team returned to the test site. Simul- taneous heated and unheated cascade impactor tests were performed on the upstream side of the CHEAP to determine whether particle growth occurred due to a condensation nuclei effect. The results of these series of tests on Johns-Manville's CHEAP are presented in the text. ------- SOURCE AND CONTROL SYSTEM The CHEAP system is primarily a rotary air filter system which consists of: 1. Water sprays to wet and clean filter medium 2. Rotary drum containing filter medium 3. Water bath reservoir for cleaning the rotary filter 4. Dual induced blowers used to exhaust the gas to the stack. Figure 1 is a schematic drawing of this system. Prior to the CHEAP, there is a cyclonic precleaner with water sprays which performs the primary function of removing the majority of large particles in the inlet stream. The scrubber is installed to control the emissions from a diatomaceous earth calcining and drying process. Emissions enter the precleaner, saturated at a temperature of approximately 75°C, where they are acted upon by water sprays and centrifugal forces which collect the large particles in the stream. The gas exiting the precleaner, saturated at 63°C, then enters the CHEAP. Water sprays again contact the gas as it is drawn through the rotating filter drum where the final cleansing action takes place. The gas then leaves through the end of the drum while the particles collected on the filter media are washed as the drum rotates into the water bath reservoir. With the help of two blowers, the gas is forced up the stack and flows into the atmosphere as a saturated plume at approxi- mately 60°C. The particle laden water in the reservoir is periodically drained into the plant's main water purifica- tion system and then refilled. ------- OUTLET SAMPLE PORTS o INLET SAMPLE PORTS STACK DUAL BLOWER UNIT WATER SPRAYS ROTATING FILTER DRUM WATER LEVEL s J> t y^— DRAIN STRAIGHTEN ING VANES SAMPLE PORT FOR PARTICLE GROUTII ThSTS TO ROTOCLONE CYCLONIC PRECLEANER DIATOMACFOUS l.ARTII CALCI \I.\G AND DRYING PROCESS CHEAP UNIT Figure 1 - Schematic drawing of CHEAP system ------- TEST METHOD The performance characteristic of the CHEAP was determined by measuring the particle size distribution and mass loading of the inlet and outlet gas sample simul- taneously. For the first series of tests performed in November, 1974, a modified E.P.A. type sampling train with a heated in-stack University of Washington Mark III (U.W.) cascade impactor was used for particle measurements. Figure 2 shows a schematic drawing of this sample train. In-stack filter samples were also taken to obtain total particulate loading and overall efficiency of the system. Due to saturated inlet and outlet streams, an in-stack impaction precutter was attached prior to the cascade impactors and filters in order to prevent water plugging and particle runoff through the impactor stages. Greased aluminum substrates were used in the impactor to prevent particle bounce and minimize wall losses. An E.P.A. Method 5 Test was also performed to obtain an unbiased sample of the total particulate loading throughout the duct and to determine overall efficiency of the system. Diffusion battery measurements of very fine particulates were attempted, but the apparatus could not cope with the excessive moisture content of the gas. Gas flow rates were determined by means of a cali- brated type "S" pitot tube along with the necessary temp- erature and pressure measurements. Due to complex duct- work, straightening vanes were inserted upstream of the inlet sample ports in order to cause a uniform flow pattern, The inlet sample port was located between the precleaner ------- I.LAFIN3 JACK1-T TIIFRMOMETER I IMPINGER TRAIN' IMPACTION C-\SCADr PRrCUTITR IMPACTOR STACK V.ALL L LIT. RATH I TIICRMOMT.TER lOTOMETtR ORIFICE METER CRY GAS MiiTER VACUUM PUMP Figure 2 - Modified E.P.A. sampling train with heated precuttcr and cascade inpactor ------- and the CHEAP unit. The outlet sample port was located on the main stack downstream of the fans. Velocity tra- verses of the inlet and outlet were performed according to the E.P.A. standards and average velocity points sel- ected for one point sampling. Sample flow rates were measured with the usual E.P.A. train instruments so as to obtain isokinetic sampling. Continuous velocity head and temperature readings were taken during sampling in order to detect any changes in the overall system. CONDITIONS FOR RUNS A total of 14 simultaneous inlet and outlet sampling runs were conducted during the first series of tests on the CHEAP system. One-point sampling was employed for all runs except Runs 13 and 14, which were E.P.A. Method 5 Tests. The first five tests were in-stack filter sample runs to determine total particulate loading and overall penetration. Runs 1, 2, and 3 were allowed to heat up to stack temperature before the samples were taken. However, due to heavy water entrainment, even after the precutter, the filters became plugged, causing high pres- sure drops in the sampling system. These runs were dis- carded due to the short sample time incurred by the plug- ging. In Runs 4 and 5, the precutters and filters were wrapped in electrical heating tape and preheated for approximately thirty minutes before sampling. The temp- erature was controlled by means of a variac on the heating circuit. The moisture problem was then solved and repre- sentative samples were obtained for these runs. Runs 6 through 12 were heated in-stack impactor runs. ------- The precutter and impactor were preheated for a period of thirty minutes before sampling. In Run 6 the outlet impactor collected large amounts of moisture, causing particle runoff through the impactor stages. Therefore test data for the outlet of Run 6 were discarded. The heating temperature was increased to combat this problem. During Run 7 problems developed in the outlet sample train, which made it necessary to abort the test. No problems occurred on the inlet side. Run 8 ran smoothly, however, it was discovered that a plant change occurred earlier than scheduled. The plant process changed from an oil fired furnace for drying to a gas fired furnace. The outlet sample was affected by the plant change, whereas the inlet sample was finished prior to the change. Run 9 was taken in a high velocity region to deter- mine if uniform size distribution existed throughout the inlet and outlet ducts. Large amounts of moisture were found in the outlet impactor. It was decided that the water in the impactor was a direct result of the increased sample flow rate, i.e. increased entrainment of water due to higher jet impaction velocities in the precutter. Previous positions of average flow were taken for the remaining tests. Runs 10, 11, and 12 were run under identical plant conditions with no moisture problems encountered. Runs 13 and 14 were E.P.A. Method 5 Tests. Due to high grain loading and a saturated stream at the inlet, sample time at each traverse point was shortened. Results of the Method 5 confirmed the validity of one point sam- pling for the performance testing of the CHEAP. 8 ------- PARTICLE GROWTH Further testing was performed from March 17 through March 21, 1975 to determine if particle growth occurred in the cyclonic precleaner prior to the CHEAP. The CHEAP was inoperable at the time of testing and therefore was bypassed. Testing was done after the cyclonic precleaner and prior to a rotoclone (See schematic of CHEAP system). In the determination of the extent of particle growth, two identical U.W. cascade impactors were used side by side to sample the effluent. Both impactors were preceded by identical impaction precutters to prevent moisture entrainment. The final filters of both impactors were removed and located in separate filter holders following the impactor. Then, to sample the dry particle size, one impactor and its final filter were heated in order to drive off any condensate on the particle. The actual (or wet) particle size was measured by the unheated impactor with only its final filter heated to prevent moisture build-up. The same modified E.P.A. sampling trains were used for the particle growth tests. Figures 3 and 4 show schematics of the dry particle size and wet particle size sampling trains, respectively. The dry particle size sampling was comparable to the first series of tests done on the CHEAP in which both inlet and outlet impactors were heated. Sampling flow rates again were measured with the usual E.P.A. train instruments to obtain isokinetic sam- pling. The inlets of both nozzles were set at nearly the same position to assure identical aerosol conditions and the sample flow rates through both impactors were identical. ------- HEATING JACKET .-THERMOMETER \t IMPACTIOX CASCADE IMPINGER TRAIN PRECUTTER IMPACTOR FINAL STACK WALL ORIPICE METER | THER?v!OMF.TFR ROTOMETER VACUUM GAUGE DRY GAS METER VACUUM PUMP SILICA GF.L DUY'.R I:igurc 3 - Mouii'ied I-.P.A. sampling train with precuttcr ami hoatcd cascade ir.pactor with attached final filter ------- THERMOMETER IMPINGER TRAIN IMPACTION PRECUTTER CASCADE IMPACTOR FINAL FILTER STACK WALL ORIFICE METER | I.CE JJATH | THERMOMETER ROTOMETER DRY GAS METER VACUUM PUMP SILICA GEL DRYER Figure 4 - Modified E.P.A. sampling train with precutter, cascade impactor, and heated final filter ------- Five test runs (Rims 15 through 19) were performed for particle growth determination. Large amounts of moisture were accumulated in Runs 15 and 16 on the ini- tial stages of the impactors which caused stage flooding and particle run off. After an investigation of the inside of the duct, it was discovered that the sample nozzles were directly downstream of a central water spray nozzle. The spray nozzle was turned off and Runs 17, 18, and 19 were taken. Both impactors on Run 17 were loaded heavily, which resulted in plugging several jet holes on the lower stages. Although visual inspection revealed similar loading characteristics, as in Runs 18 and 19, the data were considered invalid due to the jet hole plugging. Sample times for Runs 18 and 19 were decreased and ideal loadings were obtained. Results of all test runs are presented in the Particle Data Section of this report. 12 ------- OPERATING CONDITIONS The CHEAP operating conditions during the initial test period were as follows: 1. Gas flow rates and related parameters as shown in tabulation below: DUCT Temperature Velocity Am3 /rain ACFM DN m3/min @0°C DCFM @70°F Vol. %H20 vapor Pressure INLET 63°C 12.2 m/sec 710 25,000 480 18,300 17 -7.6 cm W.C. OUTLET 60°C 5.8 m/sec Same as inlet Same as inlet Same as inlet Same as inlet 17 0.2 cm W.C. 2. Water flow rate to the CHEAP system was reported as approximately 0.053 m3/min (14 GPM) . 3. Pressure drop through the CHEAP system was approxmiately 48-53 cm W.C. (19-21 inches W.C.) during the test period. 4. The L/G ratio during the test period was approximately 0.11 £/m3. 13 ------- PARTICLE DATA Four separate sets of data were obtained from the CHEAP system during the first test period. The first two data sets (Runs 4 and 5 and Runs 6, 7, and 8) were obtained at identical one-point sampling locations and identical plant conditions. The third set of data points (Runs 9 through 12] was obtained at the previous sample locations but the plant was switched from an oil-fired to a gas-fired drying process. Finally, the fourth data set was obtained from two E.P.A. Method 5 Tests (Runs 13 and 14). All particle data for Runs 4 through 14 are given in Appendix A. Particle concentration and sample flow rates for Runs 4 and 5 are given in Table A-l. Particle concen- tration and size for Runs 6, 7, and 8 are tabulated in Tables A-2 through A-4. Size distribution for these runs is shown in Figure 5. Runs 9 through 12 are represented in Tables A-5 through A-8, while the size distribution plots for these runs are illustrated in Figure 6. Finally, the particle concentrations for the last data set, Runs 13 and 14 (Method 5) are presented in Table A-9. In this report, the symbol "d " refers to aerodynamic diameter, which is equal to the particle diameter (d ) in microns (ym) times the square root of the particle density (p ) in grams per cubic centimeter (g/cm3) times the square root of the Cunningham slip correction factor (C1). The symbol "pmA" represents the units of aerodynamic size, dpa= dp( Pp0')"2' ^ CD 15 ------- 10,0 O RUN #6 A RUN #7 RUN #8 0.1 20 40 60 80 90 MASS PERCENT UNDERSIZE 98 Figure 5 - Inlet size distributions 16 ------- 10.0 5.0 I cd 0.5 0.4 0.3 0.2 0.1 Inlet Run # Outlet 10 20 40 60 80 MASS PERCENT UNDERSIZE Figure 6 Inlet and outlet size distributions 17 90 98 ------- As seen in Figures 2 and 3, the following aerodynamic mass median diameters and standard deviations were found: RUN NO. 6, 7, 8 9, 10, 11, 12 INLET dpg,ymA 0.82 0.82 "g 4.2 3.9 OUTLET dpg,pmA 0.82 ag 3.9 Average sample times for the inlet were five to ten minutes depending on the grain loading while the outlet sample time averaged approximately forty-five minutes. Isokinetic sampling was undertaken for all the test runs, however, isokinetic conditions are not that crucial for sampling fine particles. For example, the error caused by sampling 4 ymA particles at a velocity 501 higher or lower than the gas stream velocity would only be about 2 or 31 of the concentration. Single point sampling is also generally sufficient when measuring fine particle size and concentration. The fine particles will be well distributed in the gas stream, except in cases where streams with different particle con- centrations have not had sufficient time to mix. To illustrate that one point sampling is sufficient for fine particles, we may note that Stokes stopping distance of a 3 pmA particle with an initial velocity of 15 m/sec (50 ft/sec) is about 0.04 cm (0.016 inches) and for a 1 ymA diameter particle is one ninth of that. Since the stopping distance is the maximum that a particle can be 18 ------- displaced from a gas streamline by going around a right angle bend, it becomes apparent that fine particle dis- tribution in the gas stream will be negligibly affected by flow direction changes. Particle data for the particle growth tests are given in Appendix A also. Particle concentration and size for Runs 17, 18, and 19 are given in Tables A-10 through A-12. Size distributions for Runs 18 and 19 are given in Figures 7 and 8, in which the particle size Cwet or dry) is plot- ted against the cumulative mass percentage of dry solids. The amount of particle growth is then related to the dif- ference between the two curves at each mass percent solids. These figures show that the small particles grow proportion ately more than the large ones; as would be the case if the particles acted as condensation nuclei with a small fraction of soluble material in a super-saturated gas. The aerodynamic mass mean diameter of the dry particle size is almost doubled after particle growth occurs. Aero- dynamic mass median diameters and standard deviations for Runs 18 and 19 are given below: RUN NO. 18 19 DRY PARTICLE SIZE V pmA 1.4 1.1 °g 3.2 3.1 WET PARTICLE SIZE dpg,vjmA 2.2 2.1 °g 2.3 2.0 The impaction precutters used during the particle growth tests had cut diameters of approximately 7 microns aerodynamic. This explains the effect the precutters 19 ------- Run 18 Wet Size Run 18 Dry Size .1 5 10 20 50 SOLIDS MASS PERCENT UNDERSIZE Figure 7 - Run 18 wet and dry size distributions 90 20 ------- 19 Wet Size 19 Dry Size 5 10 20 50 80 SOLIDS MASS PERCENT UNDERSIZE Figure 8 - Run 19 wet and dry size distributions 90 21 ------- have on the size distribution curves. If the precutters had not been used, more particles and therefore more weight would have been collected on the first three stages of the U.W. impactor. This would tend to shift the upper data points downward and in line with the straight line curves drawn. See Tables A-ll and A-12 for data on particles larger than 10 ymA diameter. 22 ------- PARTICLE PENETRATION Cumulative mass concentration versus aerodynamic particle diameter was plotted for Runs 10, 11, and 12 and placed in Appendix B. From the analysis of these curves (Figures B-l through B-6), and noting that the inlet and outlet size distributions are identical, we can con- clude that particle penetration is relatively independent of particle diameter. The penetration is approximately 5% throughout the size distribution. Particle penetration versus dry particle size for Runs 10, 11, and 12 are plotted in Figures B-7 through B-9. The penetration curves are flat and show a relatively constant penetration over the particle size. Particle growth appears to have a beneficial effect on particle penetration, especially in the submicron range. Particles in this range grow up to as much as three times their original diameter. They, in turn, are more easily captured by inertial impaction and thus a lower particle penetration occurs. Instead of particle penetration in- creasing for submicron particles, it remains constant due to the particle growth and thus the penetration curves appear flat. It is important to characterize the CHEAP performance in such a way that it can be compared to other devices or evaluated for possible use for the collection of particles which do not grow. In order to do this, the penetration data obtained for dried particles were treated in the fol- lowing way: 1. Determine the wet particle diameter to which a dry particle would grow by means of Figures 7 and 8. 23 ------- 2. For a typical scrubber, find the cut diameter which would be consistent with the penetration versus particle diameter data obtained experimen- tally and converted to "wet" size by step 1 above The cut diameter for an equivalent scrubber is computed by means of equation (2), which is appropriate for the inertial impaction collection regieme. Pt = exp [-Ad2pa] (2) 3. Compute the scrubber "equivalent" cut diameter corresponding to a given penetration for a dried particle size by means of the relationships found in steps 1 and 2. The results of the procedure described above are as shown in the tabulation below: Dried dpa, ymA 0.5 0.7 1.0 2.0 Pt.* 0.065 0.05 0.046 0.045 Wet dpa,** Vim A 1.2 1.5 1.9 2.9 *••* d^ V 2.0 2.1 2.1 2.1 Predicted dpc, wmA 0.6 0.71 0.9 1.4 Notes: *Average penetration for Runs 10, 11 5 12 **Average wet diameter for Runs 18 $ 19 ***Computed by equation (2) 24 ------- The predicted cut diameters are not constant so it is necessary to use some judgement in interpreting the results of the computation above. As can be seen in Figures B-7, B-8, and B-9, the "dry" penetrations for the three runs are in close agreement for dry particle dia- meters larger than 0.8 ymA. The cut diameter corresponding to dry particles larger than 0.8 ymA could be as low as 0.7 to 0.9 ymA and an estimate of d = 0.8 ymA seems reasonably optimistic in view of the poorer performance for larger particles. Thus, a typical scrubber, such as a venturi, which had an 0.8 ymA cut diameter would give about the same performance on wet particles as the CHEAP. 25 ------- OPACITY Plume opacity of the CHEAP system averaged 10% during the test period. The visual observation method was used for all opacity measurements which were taken by a Johns- Manville employee who was a certified observer trained in a California Air Resources Board "Smoke School". According to the observer, visible measurements were taken on a hill above the stack approximately fifteen meters away. A detached plume enabled the observer to read opacity at the stack. 27 ------- ECONOMICS Cost data for the CHEAP were not provided by the manufacturer. According to the manufacturer, technology is not yet sufficiently well established that reliable capital and operating costs can be presented. The CHEAP system uses inertial impaction mechanisms for collection of particles. Figure 9 represents a plot of pressure drop (cm W.C.) and theoretical power (KW/Mm3/min) versus aerodynamic cut diameter. The CHEAP system with a pressure drop of 50 cm W.C. and a cut diameter of about 0.8 umA can Be compared to different scrubber systems using Figure 9. "F" is froth density for the plates, "f" is an empirical constant which is influenced by particle wettability and other factors for Venturis,'^11 equals the sieve plate hole diameter, and "d " is the packing diameter. 29 ------- 3.0 < 2.0 3. UJ u u I—I 2 Q § W 0.1 THEORETICAL POWER, KW/Mm3/min 10 50 100 500 NO, la Ib 2a 2b 3 4 SCRUBBER Sieve, F=0.4, d,=0.5 cm Sieve, F=0.4, d"=0.3 cm Venturi, f=0.25 (non-wettable) Venturi, f=0.5 (wettable) Impingement Plate Packed Column, d =2.5 cm 10 20 50 100 PRESSURE DROP, AP, cm W.C. 300 Figure 9 - Theoretical power and pressure drop vs. aerodynamic cut diameter 30 ------- MANUFACTURER'S DESCRIPTION OF DEVICE CHEAP is a patented system for removal of fine parti- culate matter from air or gas streams. It was developed through R$D efforts of the Johns-Manville Corporation over the past three years. The system provides continuous fil- tration through polymeric foam media at high velocities. These velocities bring into dominant effect the inertial impaction mechanisms of particle capture and make feasible relatively compact designs. The CHEAP unit tested by A.P.T. was tailored to the specific needs for control of emissions from the diato- maceous earth processing plant. In this case the control- ling regulation is that requiring plume opacity no greater than 20 percent. It was assumed that reduction of dust loading of the plume to about 50 mg/Am3 would suffice, but some safety factor was built into the device. Its efficiency could readily be increased should an increase in average dust load from the plant or a change in control regulations engender the need. While this system was operating with pressure drops of 50-53 cm W.C. (19.5 to 21 inches W.C.) in the course of the A.P.T. testing pro- gram, it has since been modified (by simple changes in filter medium configuration and in face velocity) to reduce the pressure drop to 43 cm (17 inches). It should be noted that no mist eliminator was employed in the unit as tested. Such a device will be installed in some additional units now under construction. This should reduce the amount of condensed moisture reaching the stack and collect that portion of solid paniculate retained in the collected water drops. 31 ------- The precleaner mentioned in the body of the report is a low-pressure-drop, wet cyclonic separator which had been used as one stage of the dust control system employed before installation of the CHEAP unit. It was deempd appropriate to leave it in the train as protection against excessive thermal excursions, which may occur occasionally in the diatomite-processing line. While performing this function it does collect some of the coarser particulate present and, thus, relieves the CHEAP of some of the dust loading. The CHEAP has been operated with the pre- cleaner deactivated. 32 ------- OPERATIONAL PROBLEMS The CHEAP, although a temporary installation, operated very smoothly during the testing period, however, plant process shutdowns delayed testing on schedule. The major problem in this CHEAP installation is operating under a corrosive atmosphere. Residual chlorides from the dia- tomaceous earth process and sulfates from the oil-fired furnace, together with a saturated gas stream, tend to accelerate corrosion on the internal parts of the CHEAP. Carbon steel fans in both of the blowers were gradu- ally eroding, causing an imbalance in the units. This, in turn, caused considerable vibrational problems and excessive wear on the motors' main shaft bearings. 33 ------- CONCLUSIONS According to the test results obtained on the CHEAP (Cleanable High Efficiency Air Filter) system, particle penetration is relatively independent of dry particle size. Penetration is approximately 5% with the mean dry particle diameter equal to 0.82 ymA. This aerodynamic diameter is equivalent to an actual size of 0.45 microns (ym) when the density for diatomaceous earth is assumed to be 2.5 g/cm3. The CHEAP appears to be a reasonably efficient device for fine particulate control of saturated emissions from a diatomaceous earth calcining and drying process. Par- ticle growth occurring in the precleaner prior to the CHEAP is beneficial to the fine particle collection effi- ciency of the system to a certain extent. Particle growth tests could not be performed on the outlet of the CHEAP and therefore the extent to which particle growth increases collection efficiency was predicted but not quantitatively 'onfirmed. Results from the E.P.A. Method 5 Tests are comparable to the results obtained in the one-point total mass loading tests. We can therefore conclude that one-point sampling of the CHEAP system was sufficient and representative for the testing performed. 35 ------- APPENDIX A 37 ------- Table A-l. INLET AND OUTLET TOTAL PARTICULATE LOADING FOR RUNS 4 and 5 RUN NUMBER 4 5 INLET (mg/DNm3) 492 372 OUTLET Og/DNm3 ) 22.5 31.3 Pt % 4.6 8.4 SAMPLE VOLUMES DNm3 IN OUT 0.061 0.57 0.081 0.57 Table A-2. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #6 IMPACTOR STAGE NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Volume (DNm3) INLET M cum (mg/DNm3) 401 356 356 356 356 304 214 126 95.4 d pc (ymA) 20 8.9 4.0 1.7 0.97 0.54 0.33 - 0 20 OUTLET M d cum pc (mg/DNm3) (ymA) High Moisture Entrainment Causing Particle Runoff - Outlet Data Invalidated Mcum V pmA = Cumulative mass collected on that stage and those below = Cut diameter (aerodynamic) for that stage = Microns, aerodynamic = d (C' p ) 1/2 39 ------- Table A-3. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #7 IMP ACTOR STAC.f-. I\UML-;I:R Prccuttcr 1 2 3 4 5 6 7 Filter Sample Volume (DNin3) INLl.T M cum Cmg/DNm3) 569 501 501 501 500 439 329 252 225 d pc (pmA) 20 9.0 4.2 1.8 0.98 0.53 0.35 ~ 0.095 oun i.r M d CUIl! pC (iag/FJMin3) (pmA) Outlet Sample Train Malfuntion- No data obtained Table A-4. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN *8 IMPACTOR STAGE NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Volume (DKm3) INLET Mcum Cmg/DNm3) 423 355 355 355 355 309 216 148 114 d pc CpiiiA) 21 9.1 4.3 1.8 1.0 0.55 0.33 - 0.077 OUTLET M cum Cmg/DNm3) Change in V (pmA) Plant Operation- Outlet Data Invalidated 40 ------- Table A-5. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #9 1MPACTOR STAGE NUMBER Precutter 1 2 3 . 4 5 6 7 Filter Sample Volume (DNm3) INLET Mcum (mg/DNm3) 303 272 270 268 265 235 154 103 87 V (ymA) 20 8.5 4.1 1.7 0.95 0.52 0.32 - 0.11 OUTLET M d cum pc (mg/DNm3) (ymA) Particle Runoff Due to Moisture Accumulation- Outlet Data Invalidated Table A-6. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #10 IMPACTOR STAGE NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Vo lume (DNm3) INLET Mcum (mg/DNm3) 320 298 298 298 298 254 178 127 95 d pc (ymA) 21 9.1 4.3 1.8 1.0 0.55 0.33 ~ 0.082 OUTLET "cum (mg/DNm3) 21.1 17.3 17.3 17.2 17.0 14.6 11.9 9.5 6.5 V (ymA) 23 10 3.8 2.0 1.1 0.62 0.39 - 0.61 41 ------- Table A-7. INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #11 1MPACTOR STAGT. NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Volume (DNm3) INI.KT M cum (mg/DNm3) 266 225 225 225 224 193 133 91 68 d pc frimA) 20 8.8 4.1 1.7 0.96 0.53 0.32 0.12 OUTLKT M cum (mg/DNm3) 15.1 11.3 11.3 11.3 11.3 9.8 7.7 6.3 3.1 d pc (umA) 23 10 3.7 1.9 1.1 0.61 P. 35 0.64 Table A-8.INLET AND OUTLET SAMPLE PARTICLE DATA FOR RUN #12 IMPACTOR STAGE NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Volume (DNm3) INLET Mcum (mg/DNm3) 265 238 238 238 237 203 139 89 66 d pc (ymA) 20 8.8 4.1 1.7 0.96 0.53 0.32 0.089 OUTLET M cum (mg/DNm3) 17.6 12.7 12.7 12.7 12.7 11.9 9.9 8.3 6.0 V (umA) 23.2 10.3 3.8 2.0 1.1 0.62 0.39 0.64 42 ------- Table A-9. INLET AND OUTLET TOTAL PARTICULATE LOADING FOR RUNS #13 AND #14 USING E.P.A. METHOD 5 RUN NUMBER 13 14 INLET (mg/DNm3) 466 389 OUTLET (mg/DNm3) 20.6 20.8 Pt% 4.4 5.3 SAMPLE VOLUMES DNm3 IN 0.058 0.053 OUT 0.62 0.64 Table A-10. DRY AND WET SAMPLE PARTICLE DATA FOR RUN #17 IMPACTOR STAGE NUMBER Precutter 1 2 3 4 5 6 7 Filter Sample Volume (DNm3) DRY PARTICLE SIZE cum (mg/DNm3) 686 660 660 660 634 554 449 317 290 d pc (vmA) • 26.7 11.8 4.5 2.3 1.4 0.72 0.42 0.09 WET PARTICLE SIZE M cum (mg/DNm3) 475 475 449 449 449 343 71.3 31.7 5.3 V (ymA) 26.3 11.5 4.3 2.2 1,3 0.70 0.39 0.14 43 ------- Table A-ll. JRY AND WtT SAMPLE PARTICLE DATA FOR RUN' #18 IMP ACTOR STACK NUMHHR Prccutter 1 2 3 4 5 6 7 Filter Sample Volume (DNm3) DRY M cuu (mg/DNm3) 467 394 369 369 344 320 202 108 64 d pc (ymA) 26.3 11.5 4.3 2.2 1 .3 0.70 0.39 0.059 Wl.T M cum (mg/DNm3) 369 569 514 544 295 201 95.9 27.1 d pc (ymA) 26.6 1] .7 4.4 2.3 1.3 0.71 0.5Q 0.058 Table A-12. LiRY AND WET SAMPLE PARTICLE DATA FOR RUN IMl'ACTOR STACK NUMBIiR Precutter 1 2 3 4 5 6 7 Filter Sample Volume (UNm1) DRY Mcum (mg/DNm3) 295 219 219 219 216 204 160 88.6 49.2 d pc (ymA) 25.8 11.3 4.3 2.2 1.2 0.69 0.39 0.080 WET cum (my/DNm3) 194 194 189 187 170 101 41.8 11.8 V (ymA) 26.6 11.7 4.4 2.3 1.3 0.71 0.41 0.077 44 ------- APPENDIX B 45 ------- 400 1 co in 1-1 u 300 200 100 0 012345 AERODYNAMIC DIAMETER, ymA Figure B-l - Cumulative inlet mass concentration for Run #10 20 15 oo CO w I—I t-l J L 10 012345 AERODYNAMIC DIAMETER, ymA Figure B-2 - Cumulative outlet mass concentration for Run #10 ------- 00 240 200 * CO C/) w > 100 0 01234 AERODYNAMIC DIAMETER, umA Figure B-3 - Cumulative inlet mass concentration for Run #11 to H < 01 34 AERODYNAMIC DIAMETER, ymA Figure B-4 Cumulative outlet mass concentration for Run #11 ------- 260 01234 AERODYNAMIC DIAMETER, ymA Figure B-5 - Cumulative inlet mass concentration for Run #12 e z: Q hH H 01234 AERODYNAMIC DIAMETER, ymA Figure B-6 - Cumulative outlet mass concentration for Run #12 ------- .10 2 o t-l H U PL, 2 O 2 W a, u i— i i 01 0.3 0.5 1.0 2.0 3.0 AERODYNAMIC PARTICLE DIAMETER, ymA Figure B-7 - Penetration versus dry particle diameter for Run 10 50 ------- o I—I H U o l-t H H PJ W 0< W u HH £ < 0.3 0.5 1.0 2.0 3.0 AERODYNAMIC PARTICLE DIAMETER, ymA Figure B-8 - Penetration versus dry particle diameter for Run 11 51 ------- H U PH .05 2 O W w — .03 .01 iiiiiiii iiiiiiiiii iiiii iiiii iiiii iiiii ••••••••« iniiiiiii iniiin »'"" 0.3 0.5 1.0 2.0 3.0 AERODYNAMIC PARTICLE DIAMETER, ymA Figure B-9 - Penetration versus dry particle diameter for Run 12 52 ------- TECHNICAL REPORT DATA (Please read faUfuelions on the reverse before completing) 1 REPORT NO EPA-650/2-75-058-a 3 RECIPIENT'S ACCESSION NO. 4 TITLE AND SUBTITLE Johns -Manville CHEAP Evaluation 5 REPORT DATE July 1975 6. PERFORMING ORGANIZATION CODE 7 AUTHOR(S) Seymour Calvert, Joel Rowan, and Charles Lake 8 PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORSANIZATION NAME AND ADDRESS Air Pollution Technology, Inc. 4901 Morena Boulevard, Suite 402 San Diego, CA 92117 10. PROGRAM ELEMENT NO. 1AB012; ROAP 21ADL-004 11. CONTRACT/GRANT NO. 68-02-1496 12 SPONSORING AGENCY NAME AND ADDRESS EPA, Office of Research .and Development Industrial Environmental Research Laboratory Research Triangle Park, NC 27711 13. TYPE OF REPORT AND PERIOD COVERED Task Final: 11/74-6/75 14. SPONSORING AGENCY CODE 15 SUPPLEMENTARY NOTES . ABSTRACT The pepol!t gives resuits of an evaluation of the Johns-Manville CHEAP sys- tem for controlling particulate emissions. Fine particulate collection efficiency as a function of dry particle size was computed from data taken on the CHEAP system, a system used to control emissions from a diatomaceous earth calcining and drying process with an overall collection efficiency of 95%. The unit was operating at a cap- acity of 710 A cu m/min (25,000 acfm), at 63C (145F), with a pressure drop of approx- imately 50-53 cm (19. 5-21 inches) water column. Initial tests showed inlet and outlet size distributions to be identical with a mass mean diameter of 0. 82 micrometers A and a geometric standard deviation of 3. 9. The data analysis indicates that particle penetration is relatively independent of particle diameter. Further tests revealed that particle growth occurs prior to the CHEAP system. Simultaneous heated and unheated impactor runs provided dried particle size distribution and actual (or wet) size distr- ibution existing inside the scrubber, respectively. Particle growth was then determ- ined, showing that particles grew as much as three times their original size in the submicron range, and less for larger sizes. This particle growth to a more uniform size can explain why penetration is relatively independent of inlet dry particle size. 7. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS b.lDENTIFIERS/OPEN ENDED TERMS c COSATI Field/Group Air Pollution Dust Diatomaceous Earth Roasting Drying Impactors Scrubbers Air Pollution Control Stationary Sources Fine Particulate CHEAP Systems Collection Efficiency 13B 11G 08G 13 H 07A 18 DISTRIBUTION STATEMENT Unlimited 19 SECURITY CLASS (This Report) Unclassified 21 NO OF PAGES 63 20 SECURITY CLASS (Thispage/ Unclassified 22. PRICE EPA Form 2220-1 19-73) 53 ------- |