EPA-670/2-75-025
February 1975              Environmental  Protection  Technology Series
          HIGH-TEMPERATURE  VORTEX  INCINERATOR
                                      National Environmental Research Center
                                        Office of Research and Development
                                       U.S. Environmental Protection Agency
                                                 Cincinnati, Ohio 45268

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                                       EPA-670/2-75-025
                                       February 1975
     HIGH-TEMPERATURE VORTEX INCINERATOR
                     By

  Robert C.  Thurnau and Donald A. Oberacker
Solid and Hazardous Waste Research Laboratory
         Program Element No. 1DB063
   NATIONAL ENVIRONMENTAL RESEARCH CENTER
     OFFICE OF RESEARCH AND DEVELOPMENT
    U.S. ENVIRONMENTAL PROTECTION AGENCY
           CINCINNATI, OHIO  45268

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                 REVIEW NOTICE
     The National Environmental Research Center-
Cincinnati has reviewed, this report and approved
its publication.  Mention of trade names or com-
mercial products does not constitute endorsement
or recommendation for use.
                      11

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                     FOREWORD
     Man and his environment must be protected from
the adverse effects of pesticides, radiation, noise
and other forms of pollution, and the unwise manage-
ment of solid waste.   Efforts to protect the
environment require a focus that recognizes the
interplay between the components of our physical
environment—air, water, and land.  The National
Environmental Research Centers provide this multi-
disciplinary focus through programs engaged in

       studies on the effects of environmental
       contaminants on man and the biosphere,
       and

       a search for ways to prevent contamin-
       ation and to recycle valuable resources.

     The research efforts described herein repre-
sents a valiant attempt to advance the state-of-
the-art of solid waste incineration.  In addition
to the goals of improved combustion efficiency,
volume reduction, and mechanical reliability, this
program sought to drastically reduce or eliminate
completely the well-known environmental insults
associated with many incineration practices.
                     Andrew W.  Breidenbach, Ph.D.
                     Di rector
                     National Environmental
                     Research Center, Cincinnati
                        m

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                                  CONTENTS
                                                                    Page No.
Review Notice                                                          ii
Foreword                                                              iii
Contents                                                               iv
Acknowledgement                                                         v
Conclusion                                                              1
Introduction                                                            2
Incinerator Concept and Design                                          3
Experimental Apparatus and Methods                                      4
Experimental Results                                                    6
     Conditions in the Combustion Chamber                               6
     Conditions in the Stack                                           13
Discussion                                                             18
References                                                             19
Appendix A                                                             20
Appendix B                                                             22

                                   Figures
No.
1.   Vortex Incinerator                                                 5
2.   Average Temperature vs. Burning Rate                               8
3.   Volume Percent Greater Than Stated Size vs. Particle Diameter     12

                                   Tables
1.   Burning Rate for Typical  Run                                       7
2.   Furnace Emissions Based on Design                                 10
3.   Stack Participate Analysis                                        11
                                     iv

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                  ACKNOWLEDGMENT

     Although this report was  written  by  Bob  Thurnau
and Don Oberacker, many others had a significant  in-
put into the concept, testing, or actual  fabrication
of the equipment.   We acknowledge and  thank,
Russ Creager, Mark Dornhelm, Stan Graydon,  Don  King,
Ken McHaffey, Boyd Riley, and  John Sliter.

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                            CONCLUSION
     It was demonstrated that the experimental  incinerator's  design
accomplished all of its anticipated goals except one.   The main  con-
clusion of this study was that efficient air pollution control  devices
are needed with incinerators, regardless of how well  the combustion
chamber is performing.

     It was found that significant amounts of oxides  of nitrogen were
formed during the incinerators high temperature operation.  These
emissions could be controlled somewhat by allowing them to disinter-
grate automatically, and possibly be eliminated by installing a taller
stack or extra duct work.

     The feelings of those closely connected with this project indicate
that the project was a significant step forward in advancing the art
of incineration, particularly that of combustion chamber design.

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                         INTRODUCTION
      Problems of solid waste and its  disposal are not new to
 mankind.   When society was  agrarian,  the waste was simply
 stored out of the way or scattered about the landscape and
 nature took care of disposal.

      As industrialization took  over,  however, and people be-
 gan to concentrate in small geographical areas, the problems
 of waste  management became  quite pronounced.  The move to the
 cities, coupled with a change in buying habits (hence disposal),
 magnified this problem to the point that it took political
 overtones.

      Many communities followed  earlier practices of letting
 nature take care of disposal and employed open-buring dumps as
 their answer to solid waste management.  Communities with more
 foresight began to investigate  composting, sanitary landfilling
 or incineration as better alternatives.  These alternatives did
 not always  live up to their expectations.  Sanitary landfills
 began to  resemple the old open  dump,  composting operations were
 expensive and an additional disposal  method had to be used to
 account for the inorganic fraction  of the waste, and incinera-
 tors produced a very poor quality residue, with associated smoke
 and odor  problems.   All  in  all,  solid waste management techniques
 were quite  poor.

      The  state-of-the-art for incineration progressed very little
 from its  beginning in 1880  to the end of World War II.  A short
 time after  the war the age  of one-way containers and other lux-
 ury items began in earnest.  The character of the waste changed
 dramatically as  did its volume.  By the sixties, solid waste
 management  had become  a national problem as evidenced by the
 Solid Waste Act  of 1965.  Under the act, the disposal practices
 of  the Nation were  to be upgraded, and obviously one of the
ways  to accomplish  this was to upgrade incineration practices.
To  help fill  the gap between antiquated incinerators and the
 solid waste problem, work was initiated on a new type of in-
cinerator- -a high-temperature vortex incinerator.   The project
was sponsored by the U.S. Environmental Protection Agency,
National Environmental Research Center-Cincinnati, Solid and
Hazardous Waste Research Laboratory.  Specifically, the incin-
erator was designed and built at the Center Hill Pilot Plant
of SHWRL, and used only untreated municipal waste as its fuel.
The project was initiated in 1967 and terminated in 1970.

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               INCINERATOR CONCEPT AND DESIGN

     The power generating industry has explored the  combustion
of fossil fuel quite extensively.  Although numerous texts and
handbooks on fuels and combusion have been published, very little
is published on using solid waste  as a fuel or the characteris-
tics of its combustion.  Utilities use the heat derived from
combustion to generate their product, and hence, they try to
maximize the amount of heat that can be obtained from the fuel.
Incinerators, on the other hand, are more interested in process-
ing a prescribed amount of refuse  per day without trying to
maximize their heat release.  In fact, many incinerators are
designed to operate at relatively  low temperatures,  and effi-
cient heat release would damage the combustion chamber.  Thus,
borrowing from the power companies,  the intent of this  project
was to maximize the amount of heat released by the refuse while
not damaging the combustion chamber, thus burning solid waste
in an efficient manner with minimal air pollution.

     If temperature is no longer a restraining force, then con-
sideration must be given to other areas of the incinerator that
will be affected by the increase in temperature.  Changes in
refractory type and design, elimination or modification of the
grates, slag formation and removal, charging  and stoking mech-
anisms, and air pollution control equipment would have to be
made if the idea of improved incineration by increased heat re-
lease were to become reality.

     The final concept envisioned a horizontal refractory-lined
cylinder into which refuse was  fed by a hydraulic ram.  The
stoking action would be accomplished  by the incoming refuse
pushing the burning refuse across the floor of the  incinerator
and finally out the other side  into the residue pit.  This kind
of stoking would also eliminate the need for grates.  Any slag
that was formed would flow or be pushed into the residue pit.
The combustion air would be delivered to the combustion cham-
ber via a manifold, and distributed in such a manner as to set
up a circular or vortex action.  This, in  addition  to providing
mixing and turbulence, would also aid the  stoking mechanism by
exposing more burning  surface to combustion.  Since high temper-
ature  was one of the design objectives, heating the incoming
combustion air was necessary.   This was accomplished by a coun-
ter-current heat exchanger where  the  hot exhaust  gases pass
through a refractory-lined cyclone and were finally delivered
to the atmosphere by a 15-foot-high  stack.

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                      EXPERIMENTAL  APPARATUS  AND  METHODS


      Construction of the incinerator proceeded with  very few changes  in
 the original  concept.   The finished unit was a horizontal  cylinder  3.66  in
 (12 ft) and 1.83 m (6  ft)  in  diameter.   The  inside diameter  was  1.22  m
 (4 ft) with 0.3048 m (1  ft)  of fire brick and castable  refractory ,       o
 surrounding the combustion chamber.  Refuse  was  stored  in  a  2.29 m3 (3 ft.  )
 hopper and was  charged to  the incinerator by a hydrolyic system  through  a
 rectangle opening whose  cross sectional  area was 0.372 m2  (4 ft2).  The
 combustion air  was supplied by two manifolds with 15 nozzels each.  The
 manifolds were  located on  the incinerator to produce a cyclonic  or  vortex-
 ing action when suppling air.   The nozzels were  1.27 cm  (1/2"),  1.59  (5/8)
 and 1.91  (3/4)  and were  used  to regulate velocity and volume of  the pre-
 heated combustion air.   A  blower capable of  suppling 42.48 standard cubic
 meters (1500  ft3) of air per  minute at a pressure of 1.397 m (55")  of
 water was used  as the  source  of the combustion air.   A counter current
 heat exchanger  of 12,  7.62 cm (3")  tubes was over the exit of the incin-
 erator and used to preheat the incoming  air  to about 260°  C  (500°F).   The
 desired burning rate was 453.6 Kg/hr (1000 lbs/hr) with  a  90% volume  re-
 duction and an  QQ% weight  reduction.  The cyclonic movement  of the  gases
 down the  combustion chamber was to  provide at least  1/2  second residence time
 at temperatures in excess  of  1315°C (2400°F).  Figure  1   shows  the final
 design of the incinerator.

      The  main parameter measured was  temperature.  By viewing temperature
 profiles  during  operation  one  could observe  how  efficiently  the  unit was
 operating.  Chromel-alumel thermocouples  were  used in all  locations ex-
 cept for  directly over the burning  face.  The  extreme temperatures  of  the
 primary combustion  area necessitated  a Rodium  type thermocouple.    Tempera-
 tures  cited during  the text of  the  paper  refer to this thermocouple
 unless  stated otherwise.

     Gas  sampling  for carbon monoxide, carbon dioxide, oxygen, nitrogen,
oxides  of nitrogen, and HC1 were carried out using the proportion sampling
techniques.  A sample rate of about 1 1/min.  was  employed for both  intre-
grated  bag samples as well  as on line infarred analyzers.

     Particulate sampling was done  in accord  with the methods and techniques
published in the  Federal  Register Volume 36,  Number 247, December 23, 1971.
This method is commonly known as the "EPA Method."

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Figure 1. VORTEX INCINERATOR

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                           EXPERIMENTAL RESULTS


     The results observed in operating the experimental  vortex incinerator
will be discussed in two groups, conditions in the combustion  chamber,  and
conditions in the stack.

I.  Conditions in the Combustion Chamber:

        A.  Burning Rate:

                Municipal incinerators are usually identified  by  the  amount
            of waste they can burn during  a twenty-four  hour day.   Typical
            municipal units  are rated at about 226.8  m-tons/day (250  tons/
            day).  Thus  the  identification of  a unit  is  also its  burning
            rate and this parameter becomes one of the standard criteria  in
            incinerator  design and construction.   If  the burning  rate is
            overloaded,  the  combustion chamber cannot effectively handle
            the load resulting in  poor combustion, excessive particulate
            entrainment, and  poor  residue  quality. If the  incinerator  is
            underloaded, the  pollution problems might not be as severe,
            but it may become uneconomical  to  run  and could generate
            vaporous odors.

                The experimental vortex incinerator was  designed  to burn
            about 454.6  Kg/hr (1000  lbs/(hr) of untreated municipal refuse.
            Table 1  is a summary of  the burning rates for a typical run.
            After a warm-up period of  about 3  to 4 hours, steady  state
            conditions appear to exist and  the  incinerator burned  on  the
            average 616  Kg/hr (1240  Ibs/hr)  with a maximum of  757  Kg/hr
            (1730 Ibs/hr) and a minimum of  494  Kg/hr  (1090 Ibs/hr).   When
            compared  with the designed  burning  rate,  the  actual burning
            rate  is  about 24  percent higher.

               After preheating the unit,  it was  expected that the burn-
            ing rate would be  constant.  This assumes, however, that  the
            other operating parameters  are  reasonably constant, and that
            maximum heat  is being released.  However, as  the temperature
            varies, so does the burning rate.   If  the data from Table 1
          j[s plotted (Fig.   2), the burning increases as the temperature

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   Table 1.  BURNING RATE FOR TYPICAL RUN
Hopper Weight Charged Burning Time Average Temp
No. Kg Min. Cc
8
9
10
11
12
13
14
15
16
17

174
211
251
247
283
219
227
202
162
237

20
23
22
30
25
22
18
19
19
20
Average burning rate
1189
1239
1211
1244
1194
1250
1333
1319
1319
1341
=
. Burning Rate
Kg/hr
527
550
685
494
679
597
757
638
512
718
616
increases and levels off at about 650 Kg/hr (1430 Ibs/hr).
This is to be expected because at this point the amount of
oxygen delivered to the combustion chamber becomes the  limit-
ing factor in this relationship.   Using 1.293 g/1 (0.0808 Ibs/
ft3) as the density of air and assuming oxygen to be twenty
percent of the air it is found that oxygen is being supplied
at a rate  of 660 Kg/hr (1454 Ibs/hr) or being used as  fast
as it was supplied.

    Once the burning rate has been established, the size of
the combustion chamber, and hence the overall size of the
incinerator will also be known.  This is very important

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00
          o
          o

          UJ
          CC
CC
LU
Q_


LU
I-

LU
O

CC
LU
                1400--
                1300--
                1200--
                1100--
                1000-v
                 900
                   400
              —I	1	1	1	h—
              500    600   700   800   900

                  BURNING RATE (KG/HR)
         Figure 2. AVERAGE TEMPERATURE VS. BURNING RATE

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    especially since the costs  seem to be exponentially related
    to the size.   Presently,?the guideline used by many grate
    designers is  293 Kg/hr/nf (60 lbs/hr/ft2).   The grate  area
    of the vortex incinerator was 1.48 m2 (16 ft2) anc|  if  the
    average burning rate is used, the burning rate per  square
    meter of grate was 413.7 Kg/hr (77.5 lbs/hr/ft2).

B.  Combustion Chamber Efficiency:

         In addition to the burning rate, the design of the com-
    bustion chamber can greatly influence the efficiency of com-
    bustion.  A poorly designed combustion chamber will allow
    particulates  and gaseous combustion products a direct  route
    to the atmosphere.  To insure superior combustion,  the experi-
    mental incinerator was specifically designed to increase
    turbulance in the combustion zones, increase the residence
    time of both  solids and gases, and increase the agglomeration
    of the refuse while burning.  The evaluation of combustion
    efficiency can be conducted in several ways.

         One measurement of combustion efficiency is the concentra-
    tion of carbon dioxide in the combustion chamber and throughout
    the incinerator system.  Initially, the carbon dioxide, measured
    as percent by volume, was distributed in the incinerator as:

                   Combustion Chamber  	 2.75
                   Midstack            	10.3
                   Top stack           	10.7

         It appeared as though  the oxidation of combustion gases to
    carbon dioxide was taking place outside the primary combustion
    chamber.  This was not the  design condition since some of  the
    heat release  was outside the primary chamber.  To alleviate  the
    incomplete combustion of carbon dioxide in the combustion  chamber,
    a baffle wall that caused additional mixing and turbulence was
    added.  After the baffle wall was added, carbon dioxide distri-
    bution improved:

                   Combustion Chamber  	  10.2
                   Midstack            	  11.5
                   Top stack           	  11.7

    These relatively high carbon dioxide levels indicate that  the
    combination efficiency of the vortex incinerator's  combustion
    chamber was quite good, and with the slight modification of  a
    baffle wall meet the design specifications.

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      A second method  for  judging  combustion  efficiency  is to
 observe the  amount of unburned  organic material  in  the  exhaust
 gas.   Poor combustion efficiency  will result in  high concentra-
 tions of organic  pollutants,  and  usually  reflect the, inefficient
 design of the combustion  chamber.   Data taken from  the  vortex
 incinerator  showed that the organic fraction varied between 1.1
 and 2.0 weight percent of the total.  Data presented at the 1970
 National  Incinerator  ConferenceCU  showed that a pilot  scale
 unit  utilizing a  scrubber and an  afterburner had about  a 10 per-
 cent  by weight organic fraction,  and full scale  commercial units
 averaged about 14.6 percent by  weight.  These data  clearly show
 that  the vortex incinerator was efficiently  burning municipal
 waste by its  low  output of organics.

      A third  method of judging  combustion chamber efficiency is
 to observe the concentration  of particulate  being emitted from
 the furnace.   It  was  found that the particulate  loading for a
 typical  run was 2.243 g/sm3 (0.98 grains/sft3).   Furnace.emissions
 for a 226.8 Kg/hr (500 Ibs/hr)  incinerator pilot plantt2) showed
 a somewhat larger value of 2.816 g/sm3 (1.23 grains/5ft3).  Fur-
 nace  emissions from three  types of  municipal incinerators are
 presented  for comparative  purposes.  Because the  data were not
 taken in  the  government-endorsed manner (i.e., the  condensable
 fraction was  not  collected) only the dust loadings  from the
 combustion chamber before  entering  apy»of the air pollution con-
 trol  devices  are  compared  (Table 2).13)

           Table 2   Furnace Emissions Based on Design

           Type   	Gram Loading Per /5m3
           Experimental vortex incinerator      0.757
           250  T/D  traveling grate              1.265
           250  T/D  reciprocating grate          1.587
           120  T/D rocking  grate                0.778

The results indicate  that  the furnace emissions from the experi-
mental incinerator are lower than either the pilot  scale incin-
erator or  full scale  commercial  units.

     Another facet of furnace emissions is the size of the
emitted particle.   Under normal  conditions the more complete the
combustion the smaller the particulate.   To better  understand
the overall combustion characteristics, the particle size of the
particulate being  emitted  from the experimental  incinerator were
determined (Table  3).
                                10

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                  Table 3.   STACK PARTICULATE 'ANALYSTS
Source of
particles
(filter #)
0246
0153
0156
0158
Lab. Wt. of
sample particles
no. analyzed
164
160
162
163
32.9
89.2
92.3
6.8
Percent by weight, in specified fraction
A
(>125 y)
3.95
2.58
1.84
0.00
B
(<125 y
>105 y)
0.00
0.67
0.00
4.41
C
(<105 y
3.04
6.06
4.11
7.35
D
(<47 y i
>12 v)
1.22
4.37
1.74
0.00
E
(<12 y)
91.79
86.32
92.31
88.24
It can be easily seen that most of the parti oil ate was 12 y or less.   To
understand the particle size of the 12 y fraction its distribution was
studied. ( igure 3).  At least 50 percent of the sample was less than 2
microns.  It should be noted that the particle size distribution was
carried out on material collected after the air pollution control device,
and not on the dust emitted directly from the combustion chamber.  It is
believed that the data is representative and the vortex incinerator is
responsible for the small particle size.

     The more classical approach to evaluating incinerator combustion
chambers revolved around volume and weight reductions of the fuel, and heat
release rates.

     Refuse is a bulky fuel with low density, and the volume reduction or
densification is a standard criteria for measuring efficiency.  When  50.5
cubic meters (66 yd3) of refuse was burned in the vortex incinerator, the
resulting residue occupied 2.29 cubic meters (3 yd3), a 95 percent volume
reduction.  Conventional incinerators are usually designed for volume re-
duction of 80 to 90\4) percent.  In comparison to conventional incinera-
tors the volume reducing ability of the vortex incinerator was very good.

     Weight reduction of the waste is also of interest to incinerator
designers and operators.  The weight of the residue is compared with  the
weight of the refuse, and the difference is the overall weight reduction.
For the case sited above, the weight reduction was 70 percent; this com-
pares favorably with published data on incinerator design.(5)

     Another parameter used to design incinerators is the heat release
rate per cubic meter (ft3) of chamber volume.  If too much heat is released,
                                     11

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LU
N
Q
lU
      100--
CC
LU
1LI
OC
O
UJ
       50--
O
0.5    1.0
  PARTICLE SIZE (MICRONS)
                                                 10.0
Figure 3. VOLUME PERCENT GREATER THAN STATED SIZE
        VS. PARTICLE DIAMETER

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              serious  damage  could  be  caused  to  the  metal  sections  of  the
              combustion chamber, and  if  too  little  heat  is  released,  poor
              combustion will  result.   A  common  value  employed  as the  heat
              release  rate design standard  is  106,855  K cal/hr/m3 (12,000
              BTU/hr/ft3).(6)   Using a calorific value of 3365  cal/g
              (6057 BTU/lb) for the refuse  and 850 cal/g  (1530  BTU/lb)  for
              the residue, the heat release rate for the  vortex incinerator
              was 384,000 K cal/hr/m3  (43,132  BTU/hr/ft3).   This heat  release
              rate is  about 3  times the accepted value and demonstrated that
              high heat release rates  could be used  with  municipal  solid
              waste.

II.   Conditions  in the Stack:

         The underlying aim of the  vortex incinerator  project was to develop
     and test an incinerator  that would burn  untreated municipal refuse
     efficiently at high temperatures  with  a  minimum amount  of  air  pollution.
     As discussed earlier the  combustion  chamber performed were, but oddly
     enough the  efficient burning resulted  in  several  emission  problems.

     Particulates:

         An earlier point was  that  the better the combustion, the finer the
     resulting ash. This type of ash  is  desirable when considering combustion
     efficiency  but undesirable from an air pollution  control standpoint.

         In Table 4, the data  from  two stack  tests are presented so that the
     relative amounts  of the solid, water soluble, and organic  fraction of
     the total particulate can be observed.   The emission rate  endorsed by
     the Government at the time of  the test was  0.458  grams  per standard
     cubic  meter corrected to  12 percent  carbon  dioxide (0.2 grains/scf at
     12% C02).   It can be seen that on both occasions  the  incinerator
     failed to meet the emission regulations with the  best effort being
     1.428  grams per standard  cubic meter corrected  to 12  percent carbon
     dioxide.

         In conjunction with the second test,  the removing efficiency of the
     cyclone was determined.   The ratio of  the amount  of  dust removed to the
     total  incident dust loading is defined as efficiency.   It  was  found
     that only 0.81 grams  per  standard cubic meter corrected to 12  percent
     carbon dioxide (0.35  grains/scf @ 12% C02)  was  collected out of 1.646
     grams  per standard cubic  meter corrected  to  12  percent carbon  dioxide
     (0.709 grains/scf @ 12% C02) or 50 percent  efficiency.

     Gases:

        In  addition to  the particulate problems originating in the combustion
     chamber, the  elevated temperature  and excellent oxidizing  conditions
                                      13

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Table 4  STACK INVENTORY

July 1970
Jan. 1971
July 1970
Jan. 1971
July 1970
Jan. 1971
CONCENTRATION
EXPRESSION
grams/son
(grains/set)
g rams /s cm
(grains/scf )
grams/son @
(grains/scf @)
12% C02
grams/son @
12% C02
(grains/set @)
12% C02
grams/scm @
50% Excess Air
(grains/scf @
50% Excess Air
grams/scm @
50% Excess Air
grains/scf @
FRACTION
PARTICULATE WATER SOLUBLE
(PROBE & FILTER) (CYCLONE & IMPINGERS)
0.727
(0.313)
0.834
(0.359)
0.873
(0.376)
0.817
(0.352)
0.715
(0.308)
0.887
(0.382)
0.506
(0.218)
0.625
(0.269)
0.601
(0.259)
0.615
(0.265)
0.492
(0.212)
0.662
(0.285)
ORGANIC CONDENSABLE TOTAL
(IMPINGERS)
0.021
(0.009)
0.019
(0.008)
0.030
(0.013)
0.016
(0.007)
0.030
(0.013)
0.019
(0.008)
1.254
(0.540)
1.477
0.636
1.483
(0.648)
1.428
(0.624)
1.233
(0.531)
1.567
(0.675)

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                                                Table 4 (Continued)
en
FRACTION

July 1970

Jan. 1971

CONCENTRATION
EXPRESSION
grams/cm @
stack conditions
grains/cf @
stack conditions
grams/cm @
stack conditions
grains/cf @
PARTICULATE
(PROBE & FILTER)
0.176
(0.076)
0.239
(0.103)
WATER SOLUBLE
(CYCLONE & IMPINGERS)
0.121
(0.052)
0.183
(0.079)
ORGANIC CONDENSABLE
(IMPINGERS)
0.023
(0.010)
0.005
(0.002)
TOTAL
0.320
(0.138)
0.427
(0.184)
                 stack conditions

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 produced  several  undesirable  gaseous emissions.

     Oxides  of  nitrogen occur  in most combustion processes.  The
 general belief is  that they result from the direct fixation of
 atmospheric oxygen and nitrogen at elevated temperatures, and are
 monitored because  they are quite toxic.  The experimental incinerator
 attempted to control oxides of nitrogen by controlling the combustion.
 If  refuse were burned stoichiometrically, there would be no oxygen
 left to be  fixed with the nitrogen.  The incinerator, however, was not
 consistently run at stoichiometric conditions and significant amounts
 of  oxides of nitrogen were produced.

     In Table 5, the oxide of  nitrogen data are presently chronologically,
 and the results show a trend  toward decreased emissions.  The reason
 proposed for this  trend is that better combustion conditions were
 achieved, i.e., closer to stoichiometric and less available oxygen for
 reaction with  nitrogen.  Initially, the incinerator ran at about 80
 percent excess air, but as work continued on the unit this figure
 dropped to  about 50 percent.

     It was  clear that oxides  of nitrogen were not controllable by con-
 trolling the combustion, and  therefore another method of control was
 employed.   Oxides  of nitrogen are unstable compounds and the reverse
 reaction (i.e., going to oxygen and nitrogen) is favored over the for-
 ward  reaction.   As long as the reaction is not quenched (sudden drop
 in  temperature) the reverse reaction continues and lessens the nitrogen
 oxide concentration.  A typical  oxide of nitrogen profile for the vortex
 incinerator  is  shown below.   The emissions from the combustion chamber
 were  the highest,  but dropped significantly as the gas passed through
 the system  to the atmosphere.

                            Combustion chamber 	  113 ppm
                            Midstack           	   80 ppm
                            Top  stack          	   49 ppm

    At the time of the project there were  no oxides of nitrogen emission
 regulations, but if the project  was to continue for a long period of
 time an alternate method of oxides  of nitrogen control would be desired.

    Hydrochloric acid was  also determined  with oxides of nitrogen.  On
 the average, hydrochloric  acid was  found  to be 150 parts per million
by volume.   No  correlation  was found between the operating parameters
and the acid concentration,  but  it  is suspected that  relationship be-
 tween fuel  composition and  acid  concentration could be found if studied.
                                   16

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Table 5.   OXIDES OF NITROGEN CONCENTRATIONS
Date
1/29/70




2/4/70


2/20/70




3/4/70



4/2/70


4/7/70


5/16/70


NO concentration
142
132
125
152

173
216

140
177
128
131

146
128
106
132
129
184
158
240
73

171
184
266
Date NO concentration
/\
5/26/70 158
237
182

6/9/70 122
100
193
160
104

7/14/70 102
146
86

9/24/70 93
47
43
10/1/70 58
93
21
10/10/70 94
68
79



                17

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                               DISCUSSION
     The data collected on the vortex incinerator's combustion chamber
 indicated that it did a very effective job in burning untreated munici-
 pal refuse.  Low particulate concentration, small particle size, high
 heat release rates, and high carbon dioxide concentrations indicated
 the combustion chamber did the job for which it was designed.  The
 burning rate was higher than the design specifications, but was necessary
 to sustain high combustion temperatures.  The result of the elevated
 burning rate was a poorer quality residue even though the volume and
 weight reductions were acceptable.

     Conditions in the stack are what led to the termination of the
 project.  On the two occasions that a complete stack test was conducted,
 the concentration of particulate (as defined by EPA) was in excess of
 the established regulation.  There are several reasons why the incinera-
 tor failed the particulate emission regulations.  First, was the selec-
 tion of a large diameter [1.37 m (4-1/2 ft] cyclone.  This was initially
 selected because it could be refractory lined and withstand the hot
 temperatures [815 C, (1500 F],  It is common knowledge that the larger
 the diameter of a cyclone, the more inefficient it becomes.  As stated
 earlier, the cyclone had an efficiency of about 50 percent and this is
 just not good enough to meet federal  regulations.

     The second reason why the incinerator failed to meet the emission
 regulations revolves around how particulate is defined.  At the time of
 the test "Any material  that was a solid or liquid at 760 mm @21.1  C
 (29.92 inches Hg @70°F) was considered particulate."  Table 4 shows the
 breakdown of the data in relation to  where it was caught, and how it is
 expressed.   The particulate fraction  refers to the actual solid material
 caught in the probe, in the cyclone and on the filter.  The water soluble
 fraction is determined by what is left after evaporation of the water
 collected in the cyclone and impingers.   The organic fraction is extracted
 from the collected water with chloroform and ether and evaporated.  Total
 particulate is then (by definition) the sum of these three fractions.  A
close inspection of the data in Table 4 shows about 40 percent of the
 particulate to be present in the water of the combustion gas.  Since the
cyclone usually doesn't disintrain gases (for moisture), 40 percent of the
accountable particulate is escaping untouched.  Thus, this condition makes
 it almost impossible to meet any regulations.

     A combination of poor cyclone efficiency and a large water soluble
fraction of particulate led to unsatisfactory levels of particulate in
the stack.


                                   18

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                           REFERENCES


1.  Achinger and Daniels, "An Evaluation of Seven Incinerators"
    Proceedings of 1970 National Incinerator Conference, pp 32-64.

2.  Ibid

3.  Walker, A. B., and Schmitz, F. W., "Characteristics of Furnace
    Emissions from Large Mechanically Stoked Incinerators."
    Proceedings of 1964 National Incinerator Conference, pp 126-27
    ASME, New York (1969).

4.  DeMarco, J., Keller, D., Leekman, I., and Newton, I.
    "Municipal-Scale Incinerator Design and Operation," U.S.  Dept.
    of Health, Education and Welfare, Public Health Service,  Consumer
    Protection and Environmental Health Service, Environmental  Control
    Administration, Bureau of Solid Waste Management, Cincinnati, Ohio
    (1969).

5.  Ibid

6.  Ibid
                                19

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                                APPENDIX A
      The  concept  of  this  vortex  incinerator may seem straight forward,
 but  its design, development,  and  fabrication was far from trouble free.
 It  is not the  intent of this  report  to belabor the project's mistakes
 and  failures,  but some of the larger problems and their solutions bear
 some mention.

      Probably  the biggest problem associated with the incinerator was
 the  existence  of  a large, positive pressure in the combustion chamber.
 This positive  pressure resulted from a combination of the high-velocity
 inflow of combustion air  necessary for the stoking and vortex action
 and  the frictional pressure losses of the heat exchanger and cyclone.
 The  positive pressure forced  a change from continuous operation to batch
 operation.  For the  incinerator to run at all, the combustion chamber
 had  to be sealed  off at the feed  end.  This was accomplished by a
 charging  chute cover.  Gaskets and clamps on this cover helped to seal
 the  pressure in,  but we found  it  impossible to prevent some smoke leakage
 from the  charging chute.   Leakage meant that whenever we wanted to add
 refuse to  the  charging chute,  the pressure had to be reduced by (1)
 shutting  the combustion air off and  then (2) opening the charging chute
 cover.  This interruption  caused many problems, including the overheating
 of our heat exchanger and  a severe,  combustion-chamber temperature drop.
 This  batch operation  undoubtedly affected the stack samples that were
 taken  during the  various  tests.

      Problems were also experienced with the materials handling system.
 A plug of compacted  refuse would not keep the smoke from backing out
 unless the plug was  packed so tight that it jammed the chute.  In addition,
 problems of insufficient stoking and unreliable residue removal  were encoun-
 tered.  Materials such as  cardboard and large pieces of plastic would not
 be sheared by the ram and  would bind in the hopper.   Every time a jam
 occurred,  the operation had to be shutdown and the jam broken manually.
Adding a system of blades, cables, and pulleys inside the hopper later
solved this problem.   Whenever the ram was pushed forward, a blade was
 pulled up  the back of the  hopper freeing up any materials that had a
 tendency to bridge.  On the ram's back stroke, the blade would return
downward forcing the  refuse in front of the ram into the chute for charging.
This technique was very effective and eliminated about 90 percent of the
binding problems.

     The residue and  its  removal  from the combustion chamber presented
another problem.   Since there were no grates,  we had to rely on  the in-
coming fuel to push the residue out.   As the temperature increased, the


                                     20

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metal cans and glass bottles began to soften and fuse together.  When
pushed toward the residue pit, they began to bind and catch in the
opening and thus, closed off the residue removal.  To overcome this
problem, an extension of the ram was added so that it would push any
bridged material into the residue hopper.  This extension was water
cooled so that it could exist at the elevated temperatures.  The ram
extension performed quite well.
                                21

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                       APPENDIX  B.   HEAT  EXCHANGER DESIGN
I.   Design Conditions
         The principle  of preheating  combusion air is called either
    "recuperation"  or "regeneration"  in the coal-fired, boiler field.
    In the case of  this incinerator,  the principle is recuperation
    since the heat  is transferred directly to the air.Regeneration,
    by contrast,  involves an  intermediate heat storage material such as
    pebbles or heat storage liquids.

         The heat exchanger design was based on the following condi-
    tions:

         -  Combustion air flow rate:  71.22 kilograms per minute
           (157 pounds  per minute) or 58.34 cubic meters per minute
           (2,060 cubic feet  per minute) at standard conditions.
         -  Blower heating effect:  ambient air is friction-heated to
           65.6°C (150°F).
         -  Heat-exchanger air side-pressure drop:  approximately 8.89
           centimeters  (3.5 inches) of water.
         -  Air temperature desired at heat exchanger outlet:  315°C
           (600°F)  up to  426°C (800°F).

         The  conditions on the flue gas side of the heat exchanger are:

         -  Flue gas  flow  rate:  198.2 cubic meters per minute (7,000
           cubic  feet per minute).
         -  Flue gas  temperature:  1,204°C (2,200°F), average.
         -  Allowable pressure drop:  0.51  centimeters (0.2 inches) of
           water.

         Other considerations in the heat exchanger design were:

         -  Physical  size:  space approximately 40.6 centimeters (16
           inches) x 48.3 centimeters (19 inches) x 182.9 centimeters
           (72 inches).   The 182.9 centimeter dimention was a horizontal
           plane.  A counterflow design for maximum recuperative heat
           transfer.
         - Materials of Construction:  mild, structural  grade steel for
           reasons of minumum cost ana maximum availability.  Future units
          would require a material  with optimum high-temperature service
           qualities; for the experimental  units, a short service life
          was considered acceptable.


                                    22

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II.   Design Calculation,  Round Tube Heat  Exchanger

          The first heat  exchanger unit tried was a bank of 12 round
     tubes.  Each  tube  was  a  1.83 meter (6  feet) length and 7.62 centi-
     meters (3 inches)  black-iron pipe.   Combustion air flowed on the
     inside of the 12 pipes while the  flue  gases flowed over the outside.
     The design calculations  for this  first unit are:

          - Tube size:  1.83  meters (6 feet) length os 7.62 centimeters  !
            (3 inches)  block-iron pipe; outside diameter 8.89 centimeters
            (3.5 inches): inside diameter 7.793 centimeters (3.068 inches).
          - Combustion  air  velocity:   17.77 meters per second (58.3 feet
            per second) inside the tubes.
          - Reynolds number inside tube:  36,600.
          - Air-to-air  heat transfer coefficient:  61.52 kilocalories per
            hour per square meter per  degree Centigrade (10.7 BTU per
            hour per square feet degrees  Fahrenheit)  based on Nu = 0.02
            (Re)0-8.
          - Flue qas velocity over outside  of pipe:   51.56 kilometers per
            hour (47 feet per second).
          - Flue gas Reynolds number:  24,300.
          - Flue gas heat transfer coefficient: 87.98 kilocalories per
            hour per square meter per  degree Centigrade (15.3 BTU per
            hour per square feet per degrees Fahrenheit) based on Nu ~ 0,02
            (Re)0-8
          - Overall heat  transfer coefficient 34.5 kilocalories per hour
            per square  meter  per degree Centigrade (6.0 BTU per hour per
            square feet degrees Fahrenheit).
          - Heat transfer area:  145,152  kilocalories per hour (576,000
            BTU's  per hour) at approximately one-half of design air flow.
          - Heat transfer area:  5.44  square meters  (58.5 square feet)
            (actually,  about  11.24 square meters  (121 square feet) would
            be required at  full design air  flow).
          - Combustion  air  outlet temperature:  315.5 degrees Centigrade
            (600 degrees  Fahrenheit) predicted at half of design air flow.

          This first heat exchanger with  twelve 7.62  centimeters (3 inches)
     pieces was operated  for  approximately  50 hours at which time the pipe
     material disintegrated.  The condition of the pipes is shown in the
     following pictures.  Metallurgical analysis determined that the dis-
     integration was caused by high-temperature oxidation.

          The thermal performance of the  first heat exchanger was unsatis-
     factory.  The combustion air temperatures leaving the heat exchanger
     were only 148.9 to 204.4°C  (300 to 400°F) for air flows between 42.48
     and 56.64 cubic meters per minute (1500 to 2000  cubic feet per minute).
     The 12-pipe configuration  lacked  sufficient  heat transfer area, 5.44
     square meters (58.5  square feet)  compared with  the required 11.24
     square meters (121 square  feet) needed when  full air flow exists.
                                     23

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     The design selected for the second heat exchanger was also a
bank of tubes with the combustion air flowing inside the tubes,
Flue gases passed over the outside of the tubes in counterflow
fashion.  This time, the tubes were 3.81  centimeters (1-1/2 inches)
(outside dimension) square tubes with a wall thickness of 0.476
centimeters (3/16 inches).  Seventy tubes were stacked in seven
vertical columns, 10 tubes hich with a 3.81  centimeters (1-1/2
inches) spacing between each column.  This design, shown in the
following pictures, effectively increased the air preheating.   The
air-side heat transfer area increased by a factor of 3 and the flue
gas-side area increased by a factor of 2.  In addition, this design
effectively lowered the tube material operating temperature, and
thereby increased the heat exchanger life.

     Some representative design calculations for the 70-tube heat
exchanger are:

     - Heat exchanger tubes:  quantity 70; square; 3.81  centimeters
       (1-1/2-inch) outside diameter, 0.478  centimeter (0.188  inch)
       wall thickness, 182.9 centimeters  (72 inches)  long.
     - Combustion air flow area:  8.162 square centimeters  (1.265
       square inches) per tube, 571  square centimeters (88.5 square
       inches) total  (0.0571 square  inches).
     - Air flow velocity:   28.13 meters per  second (9.13 feet  per
       second).
     - Air Reynolds number 23,600, average.
     - Air pressure drop:   6,655 centimeters  (2.62 inches)  of  water
       (tube only).
     - Air side  heat  transfer area:   14.63 square  meters (157.5
       square feet).

             h  CDy 2/3  _  .023 0 ?
            ClGJL     'TEG]-0'2
             p  K           y

       h  =  64.407   kilocalories  per  hour  per  square meter per  degree
           Centigrade (11.2  BTU  per  hour  per  square feet of degree
           Fahrenheit).
     -  Flue gas-side  calculations:   gas-side  heat  exchanger aara
       9.755  square meters  (105  square  feet).
     -  Flue gas  heat  transfer coefficient:  h = 0.30 CpG 0<6

                                                    jyTTi*
     -  h =  71.883  kilocalories per hour per square meter per degree
       Centigrade  (12.5  BTU  per  hour per  square feet degrees Fahren-
       heit).
     -  Flue gas  temperature  entering  heat exchanger:   1,204°C
       (2,200°F).
     -  Flue gas  temperature  leaving  heat  exchanger:  782°C  (1,440°F).
                                24

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     - Log mean temperature:   793°C  (1,460°F).
     - Quantity of heat transferred:   277,200  kilocalories  per  hour
       (1,100,000 BTU's per hour).
     - Overall  heat conductance coefficient  401.5  kilocalories  per
       hour per degree Centigrade  (752 BTU's per hour per degree
       Fahrenheit).
     - Flue gas flow area:   0.116  square  meters  (1.25 square  feet).
     - Calculated combustion air preheat  temperature:  343.3°C
       (640°F).

     The upper four pictures (Views  A-l show the incinerator's
cyclone and stack area during a typical stack  sampling test.  View
E shows the incinerator feed hopper  and air  manifold.  View F,
inside the feed hopper, shows the  ram blade.
                                25

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                                     TECHNICAL REPORT DATA
                              (Please read Instructions on the reverse before completing}
  1. REPORT NO.
      EPA-670/2-75-025
                                                              3. RECIPIENT'S \CCESSION>NO.
 4. TITLE AND SUBTITLE


   HIGH-TEMPERATURE VORTEX  INCINERATOR
                5. REPORT DATE
                 February  1975; Issuing  Date
                6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)

   Robert C. Thurnau and Donald  A.  Oberacker
                8. PERFORMING ORGANIZATION REPORT NO
 9. PERFORMING ORGANIZATION NAME AND ADDRESS
   National Environmental Research Center
   Office of Research and Development
   U.S. Environmental Protection  Agency
   Cincinnati,  Ohio  45268
                10. PROGRAM ELEMENT NO.

                 1DB063;  ROAP  24ALL; Task 03
                11. CONTRACT/GRANT NO.
 12. SPONSORING AGENCY NAME AND ADDRESS
   Same as above
                                                              13. TYPE OF REPORT AND PERIOD COVERED
                                                              In-house
                                                              14. SPONSORING AGENCY CODE
 15. SUPPLEMENTARY NOTES
 16. ABSTRACT
  This study was  designed to help  fill  the gap  between antiquated incinerators  and
  the solid waste problem.  Work was  initiated  on  a  new type of  incinerator—a  high-
  temperature vortex  incinerator.   The  project  was sponsored by  the U.S. Environ-
  mental  Protection Agency, National  Environmental Research Center-Cincinnati,  Solid
  and Hazardous Waste Research Laboratory.  Specifically, the  incinerator was designed
  and built at the Center Hill Pilot  Plant of SHWRL   and used  only untreated municipal
  waste as its fuel.
 7.
                                 KEY WORDS AND DOCUMENT ANALYSIS
                   DESCRIPTORS
                                               b.IDENTIFIERS/OPEN ENDED TERMS
                             c.  COSATI Field/Group
  ^Incinerators
   Refuse
   Research
   Waste disposal
   Slagging
  Solid  waste
  High temperature  vortex
     incinerator
 *High volume reduction
13B
 8. DISTRIBUTION STATEMENT
   RELEASE TO  PUBLIC
                                               19. SECURITY CLASS (ThisReport)
                                                    UNCLASSIFIED
                             21. NO. OF PAGES
                                    32
  20. SECURITY CLASS (This pa ft)
      UNCLASSIFIED
                                                                           22. PRICE
EPA Form 2220-1 (9-73)
26
                                                    &U.S. GOVERNMENT PRINTING OfFICE: 1975-657-590/53*0 Region No. 5-1

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