SEPA United Stales Environmental Protection Agency Enforcement and Compliance Assurance (2201 A) EPA 520-F-97-002 Spring 1997 Superfund At Work Hazardous Waste Cleanup Efforts Nationwide Site Description: Abandoned chemical storage facility and petro- leum refinery Site Size: Almost six acres Primary Contaminants: Sulfuric acid, hydrogen sulfide, sulfur dioxide, and heavy metals Potential Range of Health Effects: Corrosive effects on lungs, skin, and internal organs; central nervous system disorders Ecological Concerns: Three rivers polluted in 1968 spill Nearby Population: 35 people in adjacent properties; 700 locally Year Listed on NPL: 1983 EPA Region: 3 State: Pennsylvania Congressional District: 4 Included on the first NPL, Bruin Lagoon shared a fence line with several houses and Bear Creek. Success in Brief Lagoon Wastes Meet Quiet Demise When Congress first passed environmental legislation in 1980, EPA began by asking the states what hazardous waste sites needed cleanup first. At that time, the primary means to get federal dollars and immediate attention, was a score on the Hazard Ranking Sys- tem (MRS). Originally developed in 1982, the HRS evaluated the risk to the environment over five "pathways" or routes of exposure. The resulting score was based on contaminant migration through ground water, surface water, and air. The other two pathways, direct contact and fire or explosion potential, determined whether substantial endangerment required emergency removal actions. Scores could range from 0 to 100, but a score of 28.5 was the cutoff point for the first National Priorities List (NPL) comprised of 400 sites. In 1990, ER^ revised the HRS to add a new pathway, soil exposure. Another mechanism to place sites on the NPL allows States or Territories to designate one top-priority site regardless of score. Of the 57 States or Territories, 40 have nominated their worst site. A third mechanism allows for listing a site if a health advisory recom- mends dissociation for nearby residents, the site poses a significant threat, and site conditions dictate long-term remediation instead of emergency removal. Bruin Lagoon in Butler County, Pennsylvania was added to the NPL with a score in the 90s. The cleanup embodied a common sense approach to immobilize the wastes, commu- nity involvement, and perma- nent closure with little fanfare. The Site Today A multi-layer cap entombs the lagoon and its stabilized sludge behind a chainlink fence. An occasional weed or wild flower takes hold in the grassy surface. Not much else will ever grow here and no one will build anything here again. ------- Superfund At Work • Bruin Lagoon Site, Butler County, PA • Spring 1997 A Site Snapshot The Bruin Lagoon site covers almost six fenced acres in Bruin Borough, Butler County, Penn- sylvania. The site was an abandoned chemical storage facility and former petroleum refinery located roughly 45 miles northeast of Pittsburgh. The site is partially situated in the 100-year floodplain of the South Branch of Bear Creek, seven miles upstream of the Allegheny River. Operations at the site began in the 1930s when the Bruin Oil Company, located on adjacent property to the south, used a chemical storage lagoon to dispose of mineral oil produc- tion wastes and motor oil reclamation wastes. Disposal operations continued for a period of 40 years. Materials mixed in the lagoon formed lethal organic gases that eventu- ally erupted through vents in the surface. An abandoned coal mine located a half mile northeast of the site was a primary contribu- tor to poor ground water quality in the area. Ground water contaminants included sulfuric acid, hydrogen sulfide, sulfuric dioxide, and acidic sludges. Several homes for 35 people had been built adjacent to the site, and another 700 people reside in the community. A breached dike caused a major fish kill downriver, and flooding thor- oughly contaminated one neighbor's property. No re- ported health effects were docu- mented from the population at large. !co-disasters and Fish Kill Affects Thousands Downstream In 1968, Bruin Lagoon re- ceived national attention when 3,000 gallons of acidic sludge spilled into the South Branch of Bear Creek through a breach in the dike. The contaminants entered the Allegheny River and eventually the Ohio River, traveling as far as Cincinnati. An estimated 4,000,000 fish died in river ecosystems spanning more than 100 miles. Many more uncounted birds, water mammals, and amphibians were killed or poisoned along the way. State officials cited the Bruin Oil Company for dam- ages and hurried repairs to the earthen dike were made. But Bruin Lagoon Timeline • Second round of field studies Toxic gas release • Removal actions stabilize lagoon, surface tanks removed • Site added to NPL USAGE and State begin field work c EPA begins probe of site Record of Decision • Flood contaminates neighbor's property • Congress enacts Superfund • Fish kill into <( Allegheny. Monongahela, and Ohio Rivers Mineral oil and refinery wastes disposed 1 1 1930s 1968 1980 1981 1982 1983 1984 1985 1986 ------- Superfund At Work • Bruin Lagoon Site, Butler County, PA • Spring 1997 Public Outrage Force Closure of Hazardous Disposal Lai downstream communities, including Pittsburgh, had to temporarily close off water supply systems. The spill made major headlines and shortly thereafter, the company closed its doors and declared bank- ruptcy. In 1980, a flood caused the lagoon to overflow, contaminat- ing the property north of the lagoon. State authorities nomi- nated the site as a priority under the newly enacted "Superfund law", the Compre- hensive Environmental Re- sponse, Compensation, and Liability Act of 1980. Derived from exise taxes on chemical feedstocks and crude oil, the Superfund cleans up aban- Bruin Lagoon Site Butler County, PA The 1968 Bruin Lagoon spill contaminated more than 100 miles of waterway along three rivers. doned or uncontrolled hazard- ous waste sites and can be used for accidents, spills, and other emergency releases of pollut- ants into the environment. In July 1981, EPA began a probe of the various contami- nants at the site. An estimated 35,000 cubic yards of contami- nated sludge filled the open Continued on page 4 Public meetings to communicate progress y • USAGE administers formal design progress • Engineers complete remedial design project Crews install gas vents Water treatment plant operational Sludge stabilization efforts proceed until winter Video cameras and air monitoring equipment installed Stabilized sludge added to subgrade Multilayer cap installed State assumes operation and maintenance work Second 5-year review ------- Superfund At Work • Bruin Lagoon Site, Butler County, PA • Spring 1997 Continued from page 3 lagoon. The following June, the report of findings culmi- nated in a Record of Decision to cover the lagoon with an impermeable, multilayer cap. In September 1982, EPA signed a contract with the State, using the U.S. Army Corps of Engi- neers for support. Work began in August, 1983 to remove liquid floating on top, to stabi- lize the lagoon walls and dikes, and to remove scrap storage tanks and equipment. A chan- nel was constructed to prevent ground water from entering the site. That same year, Bruin La- goon was officially added to the National Priorities List (NPL), a roster of hazardous waste sites eligible for federal cleanup. Given the types of contaminants and the proxim- ity of the site to Bear Creek and several homes, EPA added Bruin Lagoon to the NPL. Since that time, more than 1200 other sites have been listed. EPA Controls Toxic Gas Leak Construction activities continued until May, 1984 when workers penetrated a previously unidentified crust layer, releasing a poisonous gas that contained high con- centrations of carbon dioxide, hydrogen sulfide, and sulfuric acid mist. EPA called in an emergency team of specialists to cover the hot spot with stabilized sludge and to install gas monitoring wells. A second investigation com- menced during the winter to reevaluate the site; field activi- ties continued all summer through October, 1985. While monitoring the gas, sludges, and ground water around the lagoon, EPA com- pleted analyses to select the best cleanup method. A public meeting and comment period in August 1986 evidenced a high degree of community involve- ment as well as Congressional and state concern. Following a formal decision to expand upon the remedy previously chosen, the Army Corps of Engineers prepared blueprints and awarded contracts for the reme- dial work. Before the start of construc- tion, EPA held a meeting at the Bruin Fire Hall with the Butler County Emergency Manage- ment Agency and local officials. Community members had requested a warning siren to detect a gas release or construc- tion accident. Following instal- lation of the siren, EPA estab- lished a 24-hour hotline with the fire department. A team of residents, township officials, and the fire department began regular meetings with EPA to discuss cleanup progress as well as concerns such as property values. EPA then asked the USACE to administer the formal design for the site in March, 1987 and a professional consulting team completed their report in July, 1988. Proposals for competitive contracts to conduct the actual construction took about nine months. In June 1989, crews installed 20 pre-construction gas vent wells to prevent a large pres- surized gas release. Sedimenta- tion ponds and diversion ditches served to control pre- cipitation, excess surface water, and silt. In order to neutralize the remaining sludge, crews excavated and hauled the la- goon wastes to mixing pits. An on-site water treatment plant treated all water that came in contact with raw wastes from the open excavations. Decon- tamination water also was treated and the effluent dis- charged into a tributary of the South Branch of Bear Creek. Crews then scraped the bedrock of the lagoon, applied six inches of limestone aggregate, and backfilled with the stablized sludge until the onset of winter. Communications and Monitor- ing Ensure Safety Before resuming construction in May 1990, a second Emer- gency Response Meeting con- vened to better communicate with county and borough offi- cials. A new notification plan would keep the community current with progress through fact sheets, a radio talk show, and a site tour. In addition, a remotely controlled black and white video camera was in- stalled on a pole to record a Continued on page 5 ------- Superfund At Work • Bruin Lagoon Site, Butler County, PA • Spring 1997 "birds eye view" of the construction activities. A hand- held video camera also recorded milestones and provided close- up color documentation of various sludge types, mixing operations, and material place- ment such as the bedrock neu- tralization. To ensure continuous air quality for both the surround- ing neighborhood and on-site workers, continuous perimeter monitoring sampled for sulfur dioxide, hydrogen chloride, and dust. Work areas also were tested every half hour for or- ganics and explosiveness. De- spite the threat of off-gassing, crews finished the sludge stabi- lization without incident on November 1,1990. This addi- tional material was added to the subgrade layers as well as more rip-rap for embankment protec- tion. The surface was capped in the spring of 1991, including seeding for grass. On July 1992, the state of Pennsylvania as- sumed all responsibility for operations and maintenance, including annual inspections to ensure effective erosion control measures, routine mowing, maintenance of the perimeter fence, and periodic sampling of ground water monitoring wells. The Bullhead and the Sof tshell An uncounted number of species suffered or died when highly acidic, petroleum-based con- taminants from Bruin Lagoon spread through an already- compromised Ohio River eco- system in 1968. The softshell turtle and the bullhead were among the hardest hit. Both species are bottom feeders, preferring aquatic insects, crayfish, mollusks, and other fish in the food chain. Current scientific research suggests a connection between a wide range of animal disorders and industrial chemicals. Among the disorders which may be related to chemical exposure are decreased fertility, decreased hatching success, gross birth deformities, and behavioral abnormalities. Au- topsied bullhead, for example, have exhibited enlarged livers, various rumors, lesions on the mouth, and ulcers of the stom- ach, esophagus, and intestines. Changes in body mass and shell erosion have been found in the softshell turtle. Not until passage of the Clean Water Act in 1977 were effluent standards set for individual toxic pollutants and industries required to obtain discharge permits. Through water quality based permitting, chemical-specific standards as well as whole effluent testing have helped to reduce loads of toxic chemicals into the Ohio River ecosystem. Through these and related regulatory and environmental management initiatives, the ecosystem has improved dramatically and both species remain in the Ohio River. However, there remains the need to improve techniques to identify chemicals that may cause reproductive, devel- opmental, and syner- gistic effects and to test the effects of ------- Superfund At Work • Bruin Lagoon Butler County, PA • Spring 1997 Success at Bruin Lagoon We've had a long history in this country of burying our toxic and chemical wastes, only to have those graveyards erupt years later. The hours and dollars spent to clean up or remove the contaminants always far outweigh the costs of disposal on an order of magnitude in the mil- lions. Before these sites come to closure, wildlife suffers, sensitive species fail to reproduce, and some surrender to extinction. Because the U.S. has thousands of abandoned and uncontrolled hazardous waste sites, many worse than Bruin Lagoon, states, federal agencies, and responsible parties have formed a net- work of professionals who tackle the complex issues posed at each location. Each site has a specific set of destroyed variables in the ecosystem, synergistic effects in the food chain, and unique challenges for remedial technology. From reports on failures and successes alike, this information is now exchanged at public meetings, university seminars, national conventions, and on the Internet. Every community needs this information to intelligently design solutions for upcoming sites in the queue. 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