WATER POLLUTION CONTROL RESEARCH SERIES
12090EUX10/70
             Reuse of
 Chemical Fiber Plant Wastewater
   and Cooling Water Slowdown
ENVIRONMENTAL PROTECTION AGENCY • WATER QUALITY OFFICE

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           WATER POLLUTION CONTROL RESEARCH SERIES

The Water Pollution Control Research Series describes the
results and progress in the control and abatement of pollu-
tion of our Nation's waters.  They provide a central source
of information on the research, development, and demon-
stration activities of the Water Quality Office, Environ-
mental Protection Agency, through inhouse research and grants
and contracts with Federal, State, and local agencies, re-
search institutions, and industrial organizations.

Inquiries pertaining to the Water Pollution Control Research
Reports should be directed to the Head, Project Reports
System, Office of Research and Development, Water Quality
Office, Environmental Protection Agency, Washington, D.C. 20242.

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                  REUSE OF

           CHEMICAL FIBER  PLANT

  WASTEWATER AND COOLING  WATER SLOWDOWN
                    BY-
     FIBER INDUSTRIES, INCORPORATED
     CHARLOTTE,  NORTH CAROLINA 28201

      DAVIS &  FLOYD ENGINEERS,  INC.
     GREENWOOD,  SOUTH CAROLINA 29646
                   FOR THE
      ENVIRONMENTAL PROTECTION AGENCY
           WATER QUALITY OFFICE
          PROGRAM NO. 12090 EUX
         GRANT  NO. WPRD-100-01-68
                OCTOBER 1970
For sale by tlie Superintendent of Documents, U.S. Government Printing Olliec
           Washington, D.C., 20402 - Price 70 cents

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             EPA Review Notice
This report has been reviewed by the Water
Quality Office of the Environmental Protection
Agency and approved for publication.  Approval
does not signify that the contents necessarily
reflect the views and policies of the Environmental
Protection Agency.
                    11

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                           ABSTRACT
Demonstration studies were conducted to determine the feasibility  of
reusing industrial  and domestic wastewaters from a FORTREL Polyester
manufacturing plant.   The wastewaters consisted of organic chemical
process wastes, cooling system blowdown and domestic wastewaters
from the plant.  Selected unit processes and operations were super-
imposed on an existing activated sludge system in an effort to
improve the quality of the treated discharge.   The cooling system
blowdown was pretreated with sulfur dioxide in an acidic environment
to remove the chromium.  The cooling water biocides which passed
through the chromium reduction unit were observed for their possible
effect on the biological treatment system.  A plastic media trickling
filter was evaluated for its effectiveness as a roughing filter ahead
of an activated sludge unit.  The effluent from the secondary treat-
ment system was filtered through a microscreen, and treated with
polymers and/or carbon to remove color, COD, dissolved and suspended
solids.

The results of these studies indicate that chromium can be removed
from the cooling tower blowdown for 21
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                             CONTENTS
Section
                                                            Page
  I          Results and Conclusions                          1
  II         Recommendations                                  5
  III        Introduction                                     7
  IV         Research  and Development Project                 9
  V          Engineering Approach and Operational
             Plan                                             11
  VI         Operational  and Experimental  Aspects
             of the  Project                                  29
  VII         Operation  of the  Treatment  System
             on a  Production Basis                            51
  VIII        Acknowledgements                                 53
  IX         References                                       55
  X           Appendices                                       57

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                           FIGURES
                                                            Page

 1.   Overall Schematic of the Wastewater and
     Water  Reuse  Facility                                    14
 2.   Aerial  View  of  Fiber Industries,  Inc.,
     Shelby, North Carolina                                  15
 3.   Schematic  of Continuous Operation  Chromate
     Reduction  System                                        16
 4.   Schematic  of Plastic Media  Trickling  Filter
     Showing Structural  Members  and  Media  Bundle
     Arrangement                                             17
 5.   Photograph of  Plastic Media Trickling Filter           18
 6.   Schematic  of North  Microscreen  (Algae Screen)           19
 7.   Photograph of  500,000 gpd  North Algae Screen
     Installed  Between  Polishing Pond and  Carbon
     and Flocculant  Treatment  Unit                           20
 8.   Schematic  of Flocculant and Carbon Units                21
 9.   Exterior  View  of Permutit  Carbon and  Flocculant        22
10.   The Automatic  Valveless Gravity Final Filter
      Installed  Downstream of Settling Tank                  23
11.   Location  of  Sampling Points in  Treatment  Plant          39
12.    Plastic Media  Trickling Filter, Operational  Mode
      B & C - Sludge Recycle Hydraulic Loading
40
13.   Plastic Media Trickling Filter, Operational Mode
      A - No. Sludge Recycle Hydraulic Loading                41
14.   Plastic Media Trickling Filter, Operational Mode
      B & C - Sludge Recycle                                  42
15.   Plastic Media Trickling Filter, Operational Mode
      A - No Sludge Recycle                                   43
                              vn

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                            TABLES

No.
                                                             Page
 1         Typical  Hydraulic and Organic Loadings
           for Plastic Media Trickling Filters                27

 2         Chromate Reduction Unit Operational Data           33

 3         Data from Microscreening and Chemical
           Treatment Unit                                     35

 4         Data from Microscreening and Chemical
           Treatment Unit                                     37

 5          Effectiveness  of Polishing  Ponds  as A
           Tertiary Treatment Unit                            38

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                            SECTION  I

                     RESULTS AND  CONCLUSIONS


Many  conclusions can be drawn from  the evaluation of each of the
various research and development units installed in the treat-
ment  plant as a part of this grant.  These conclusions are pre-
sented on a unit by unit basis as they pertain to the grant.

Chromate Reduction Unit

1.    It has been demonstrated that the removal of hexavalent chrom-
      ium from cooling tower blowdown can be accomplished by chemical
      reduction and precipitation  utilizing sulfur dioxide in an
      acidic media followed by neutralization and settling.

2.   The biocides which are normally used in cooling water systems
     and which may be contained  in  the effluent from the reduction
     unit are  accounted for as  follows:

     a.    Sodium pentachlorophenate  when  used as  a  biocide  in  cool-
          ing  water will  pass through  the chromate  reduction  unit
          and  enter the waste water  treatment plant.   It  has  no
          adverse  effect  on the plant  and does  not  appear in  the
          effluent  from the clarifier.

     b.    Methylene bis  thiocyanate  is similar  to sodium  penta-
          chlorophenate  in  that it passes  through the chromate  system
          and  enters the waste treatment  plant.   It has no adverse
          effect on the plant and does not  appear in the clarifier
         effluent.

    c.    1, 3 dichloro -5, 5-dimethylhydantoin is riot stable with-
         in the cooling system and  dissipates within six hours of
         introduction.  It has not  been detected in the cooling
         tower blowdown.                                      3

    d.   N-alkyl dimethyl benzyl  ammonium chloride is destroyed in
         the reduction process  and therefore is not a problem in
         the waste treatment plant.

    e.   Sodium dimethyl thiocarbamate and disodium ethylene bis-
         thiocarbamate are destroyed in  the chromate  reduction pro-
         cess  and therefore have  no  effect on the waste  treatment
         plant.

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Plastic Media Trickling Filter

3.   Chemical and sanitary wastes generated in the production of
     FORTREL Polyester can be treated using a tower packed with
     plastic media.  BOD5 reductions in the range of 40 percent
     have been attained using a single tower and utilizing sludge
     recycle from the clarifier.

4.   The percent reduction in BOD5 appears to be constant at
     approximately 40 percent over a loading range of 300 to 950
     pounds BOD5 per 1000 cubic feet of media per day using a
     sludge recycle mode.   With no sludge recycle the percent
     BODc reduction tends  to be constant at 25 percent over a
     loading range of 300 to 700 pounds per 100 cubic feet of
     media per day.

5.   The percent reduction of BOD^ at these loadings is not sig-
     nificantly changed by variations in hydraulic loadings ranging
     from 0.95 to 6.75 gallons per square foot per minute.

6.   Recycle rates up to 5:1 appear to have minor and insignificant
     effect upon BODc percent reduction.  At ratios ranging from
     5:1 up to 9:1 there appears to be a five percent improvement
     in the 6005 reduction.   It must be concluded that increasing
     recycling ratios in these ranges has no significant effect on
          reduction.
7.   Sludge recycle over the tower, together with sanitary and
     chemical waste, results in a net BOD5 reduction increase of
     a nominal 10 percent as compared to no sludge recycle under
     the same conditions.

8.   A comparison of the treatment of waste water from the manufac-
     ture of polyester utilizing plastic media as a roughing filter
     versus mechanical aeration indicates that costs of construction
     for equivalent treatment capacities are equal.  Therefore the
     two systems must be compared and selected on a basis other than
     cost.

9.   Plastic media trickling filters will freeze and become inoper-
     ative  at ambient temperatures of 10°F. (waste influent tem-
     perature 45°F.)

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 Mlcroscreens and  Chemical Treatment Unit

 10.   It has been  observed that the microscreen  (algae screen) per-
      formed well  in warm weather but tended to  become clogged with
      slime growth during periods corresponding  to algae blooms in
      the ponds.   In winter the spray nozzles froze when the ambient
      temperature  dropped below freezing.

 11.   Polishing pond effluent waters can be chemically treated to
      achieve water suitable for reuse as cooling tower make-up.
      The cost for chemicals for such treatment  is as low as $0.08,
      per 1000 gallons of water treated.  This is typical for the
     many flocculants and carbons evaluated.

12.  Clarifier effluent waters can be chemically treated to achieve
     water suitable for reuse as  cooling tower make-up.   The cost
     for chemicals for this  treatment is $0.11 per 1000  gallons.

13.  The BOD5 reduction and  the COD reduction for the secondary
     treatment  system was  in  excess of 95% during the grant period.

14.  Sludge disposal  from  the secondary treatment system as well  as
     spent  powdered carbon  from the tertiary system and  screenings
     from the microscreen were lagooned.  This  is considered to  be
     the ultimate  disposal of the  sludge.   When  the  lagoon  is  full
     another will  be  established  and  the present one  will be covered
     with  dirt.

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                            SECTION  II

                          RECOMMENDATIONS
The conclusions presented in this  report are  the basis  on  which  these
recommendations are made.  It should be  noted that  they are  based  on
ajinimum of one years  full  scale  operation of the  various treatment


                                     further  stud^  of the  chromate
      rMrt,                  er su^ o  te chroma
      reduction unit.  The design and operation were satisfactory
      and the unit is now in permanent use.  The potential for
      chromium pollution of the receiving stream from deliberate
      cooling tower blowdown has been removed.   A system of this
      type is recommended for use at other installations havinq
      similar cooling water blowdown problems.

 2.    It is  recommended that the cooling water  blowdown  with  heavy
      metals  removed and containing  the  type  and concentration  of
      biocides  evaluated in  this study and normally  used in such

      treatment^ fants    treated 1n  activated sludge waste water


 3.    It is recommended that  studies  be  instituted to develop an
      oxidation-reduction  potential  (ORP)  probe  that will operate
      under the conditions encountered with this cooling water  for
      longer  periods  of time  without  loss  of  sensitivity.

 4.    The  use of a plastic media trickling  filter for polyester waste
      is  recommended  as  a  roughing filter  ahead of an activated sludge
      ?JSnL!!aSer *reatment s^stem when additional treatment capacity
      s needed and when space for construction of a treatment facility
      s at a premium   The use of the plastic media is not recommended
      in areas where it will be placed in the open and where Sent
      temperatures be ow freezing occur as the unit may freeze and
      c^AT6^6-  (WaSte water temperatures  must be con-
     effect }           ^ °V6r rule the ambient
5.   It is recommended that studies  be undertaken  to determine  the
     effects of commonly used biocides and dispersants  in  shock load
     concentrations  on activated sludge systems.   This  type  infor-
     mation  would be valuable for overcoming the effects of  spills

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6.    The installation of a microscreen between a polishing pond
      and a chemical  treatment unit is recommended.   This unit
      serves the primary purpose of removing algae clumps and mats
      and other macroscopic debris and by so doing protects the
      chemical  treatment system.

7.    The reuse of chemically treated polishing pond effluent is
      recommended over the reuse of chemically treated clarifier
      effluent as cooling water makeup since the former is less
      effected by treatment plant upsets and also has less phos-
      phates and nitrates in the final treated water.

8.    Studies centered around the reuse of polishing pond effluent
      for recreational purposes is recommended.  Such data is avail-
      able for effluent from the treatment of municipal wastes, but
      is lacking for industrial waste.

9.    It is recommended that the treatment system be operated on a
      production basis using chromate reduction, equalization,
      roughing filter, mechanical aeration, clarification, polishing
      ponds, algae screens, polymer addition and final filter at an
      estimated cost of operation of 40^/1000 gallons.

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                           SECTION  III

                          INTRODUCTION
 Background

 The  Fiber  Industries,  Incorporated,  FORTREL  Polyester  plant at
 Shelby,  North  Carolina,  has  been  in  operation since  1960.  The
 initial  manufacturing  plant  was small and the sanitary and
 industrial wastes were treated in an  Imhoff  Tank.  As  the FORTREL
 Polyester plant  grew,  the waste water treatment  facility expanded
 and  changed until in 1968 it consisted of a  very large and modern
 extended aeration activated  sludge system and final  polishing
 lagoons.

 In parallel with the growth  of the FORTREL plant there was a
 general  awakening of interest in pollution abatement technology
 throughout the country.  Fiber Industries, Incorporated, recognizing
 the  potential  for reusing effluent as cooling tower  makeup, retained
 Davis &  Floyd  Engineers, Inc. to perform a reuse feasibility study.
 When this study  indicated an  apparent gap between desire and tech-
 nology, application was made  to the United States Department of the
 Interior, Federal Water Quality Administration for a Research and
 Development Grant.  The proposed project was to include pre-treat-
 ment of the cooling water to  remove heavy metals, in-plant modifi-
 cations and additions to the treatment plant to increase the treatment
 capacity, and  finally a post treatment system to polish the effluent
 prior to selected reuse.

 Fiber Industries, Incorporated was awarded Research and Development
 Grant 12090 EUX by the Federal Water Quality Administration early in
 1968.  The project was basically a water reuse project utilizing the
existing activated sludge waste treatment plant onto which the various
 grant units to be studied were superimposed.

The project was funded on April  4, 1968.   Construction started early
in August.   The first unit of the  grant was  placed in operation in
December 1968, and by February 1969  all  units were in operation.   The
plant was operated under  the terms of the grant until June 4,  1970
at which time the operational phase  was  completed.

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                            SECTION  IV

                 RESEARCH  AND DEVELOPMENT  PROJECT
  APPROACH

  Effluent  from the existing waste water treatment facility, as
  mentioned previously was of high quality.  Specifically, the 8005
  was generally less than 25 mg/1, the COD was less than 300 mg/1,
  and the dissolved solids were in the range of 500 mg/1.  Dissolved
  oxygen and suspended solids content varied continuously as a
  result of an ever changing quantity of algae growth in the polish-
  ing lagoons.  Thus, in order to reuse this water, facilities for
  handling obvious quality deficiencies and/or waste treatment
  problems which could arise had to be installed.

  Suspended solids, primarily algae growths, and dissolved nutrient
 materials had to be removed or reduced in quantity so that cooling
 tower sludge and slime problems would not be unduly aggravated.
 After consideration of various alternatives,  microscreening followed
 by powdered  carbon-chemical  coagulant-dual  media  filtration process-
 ing was selected to pretreat  effluent waters  before their reuse  in
 the tower.

 Dissolved solids in  the  effluent water were  known  to be  much  higher,
 500 mg/1  as  compared  to  100 mg/1, than in  the  potable  water normally
 used for cooling tower makeup.   It  was expected,  therefore,  that
 blowdown  from the tower  would  be increased markedly.   Increased
 blowdown  added two new requisites;  namely, a  facility  for handling
 tower  system treatment chemicals; i.e., chromates and  biocides and
 a facility for handling  increased biological  loads  from  organic
 contaminants; e.g., ethylene glycol.

 A review of  industrial practices revealed that chromates  could be
 effectively separated  from an aqueous stream by chemically reducing
 the hexavalent chromium to its trivalent form and then precipitating
 the trivalent chromium as chromium hydroxide.  A process using sulfur
 dioxide as the reducing agent and sodium hydroxide as the precip-
 itating alkali was chosen because of the  greater ease of handling
 and immediate availability of these chemicals.

A plastic media trickling filter was selected to supply the added
biological treatment capacity required to handle increased tower
blowdown.  This sanction,  which followed review of various poten-
tial treatment processes, was  made primarily because promixing data
appearing in  the  literature indicated substantial  cost savings over
other methods.  Space and arrangement features also permitted

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relatively quick evaluation  of this  equipment's  efficiency when  used
as a roughing treatment preceding the  existing activated sludge  unit.

Scope and Objectives

The objectives of this research and  development  project were "to
treat synthetic fiber manufacturing  waste and cooling water blow-
down by such methods as chemical  reduction,  sedimentation, plastic
media trickling filters, polishing ponds, algae  microscreening,
carbon absorption and/or organic polymer flocculation, such that
the treated waters can be reused as  a  process water makeup stream".

In order to accomplish this, a general plan  for the grant was
adopted as follows:

1.    Install a chromium reduction system in the cooling tower blow-
      down system which will remove  hexavalent chromium from the waste
      stream and evaluate the various  biocides which are used to
      control biological growth in cooling towers to determine if
      they can be introduced into the  waste  treatment systems without
      significantly reducing or changing the treatment capability
      of the system.

2.    Install a plastic media trickling filter in the treatment
      plant  influent stream and evaluate the following:

      a.   BOD5 and hydraulic loadings and recirculation rates for
           the treatment of waste water from polyester fiber
           manufacture.

      b.   The efficiency and economics of using plastic media as
           compared to  mechanical aeration for waste water treatment
           as  it  pertains to this particular plant.

      c.   The efficiency of land usage for waste water treatment
           systems  utilizing plastic  media as compared to mechanical
           aeration for waste water treatment.

 3.     Install  a  final  treatment  system consisting of  a micro-screen
       (algae screen),  and a powdered  carbon  and  flocculant treatment
       system_in  the effluent stream to accomplish the  following
       objectives:                                             3

       a.    Demonstrate that  a  chemical fiber waste  which  has  been pre-
            treated in  a waste  treatment  plant can be  post-treated by
            screening  and/or activated carbon  and/or flocculants  and
            reduce the  color,  BOD, COD and total  solids  to such  a degree
            that it can be used as process makeup water
                               10

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                            SECTION  V

            ENGINEERING APPROACH AND OPERATIONAL PLAN
 Description of Treatment Plant Components

 The wastewater treatment facility serving Fiber Industries, Inc.,
 Shelby, North Carolina, is located on Company property and is for
 the exclusive use of the plant.  Both domestic and chemical ef-
 fluent are treated.  The design flow of the wastewater treatment
 plant is 325,000 gallons per day at a BOD^ loading of 6000 pounds
 per day.  The chemical waste is composed of ehtylene glycol,
 dimethyl terephthalate, long chain fatty acids such as oleic, 1ino-
 lei c, 1 auric and their derivatives, quality control laboratory
 waste, boiler blowdown, Dowtherm, methyl alcohol and cooling water
 blowdown.  The wastewater is routed to the treatment facility as
 shown in Figures 1 and 2.  The units in the system are described
 as follows:

 A.    Chromate reduction unit (Grant Unit).  The chromate reduction
      unit is rated at 120 gpm at Cr04 concentrations up to 300 mg/1.
      It is designed for continuous operation.  The reduction tank
      is designed for ten minutes retention; the neutralization tank
      for twenty minutes retention.  Both tanks are lined with poly-
      vinyl chloride.  The tanks and all the instrumentation for a
      typical  installation are shown in Figure 3.   They are housed
      in a 20'  x 30'  building, which is located immediately behind
      the cooling tower.

B.    Equalization basins.   The chemical waste is  routed through
      three series connected equalization basins.   These basins have
      a total  capacity of 190,000 gallons and are  equipped with
      mixers  to prevent stratification and short circuiting.   In
      addition  to the chemical  process waste, cooling tower blowdown
      is routed to this system after it passes through the chromate
      reduction system.  These basins  serve to minimize the effects
      of spills or intermittant waste  loads  containing high concen-
      tration  of organic materials.

C.    Plastic  Media Trickling Filter (Grant Unit).   The plastic media
      trickling filter is  shown schematically in Figure 4.  A photo-
      graph of  the unit is  shown in Figure 5.   The  filter consists of
      two tiers of media each ten  feet thick and twenty-five  feet in
      diameter.   Each tier is composed of five two-foot thick  layers
      of polyvinyl  chloride  media.   The geometrical  arrangement of
      the media,  each module  measuring 2 ft.  x 2 ft.  x 4 ft.,  is
                              11

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     critical both for strength and distribution and the arrange-
     ment, as shown, is as required.  There is a two foot air
     space between the tiers.  The tower is covered on the exterior
     by galvanized siding except for a two foot air opening around
     the bottom circumference.  The tower is fitted with a four-
     armed reaction type rotary distributor with variable flow
     orifice nozzles.  The tower rests on a sloped and curbed con-
     crete pad which is connected to a sump which is equippad
     with a  recirculation pump.  The pump used to circulate the
     waste over the tower is  variable speed and is rated up to
     900  gpm @ 40  ft.  TDH.   The filter media used in the tower  is
     Koroseal Vinyl Core manufactured by the B. F. Goodrich Company.
     A schematic  and a photograph  of this unit  is shown  in  Figures
     4 and 5.

U.    Aeration basin.   Following the plastic media tower  is  an
      aeration basin equipped with  three  mechanical  aerators;  two
      rated  at  75  HP and  one  rated at  25  HP.   The  detention  time in
      the aeration basin  is  30 hours based  on  325,000 gpd flow and
      100% recycle of the clarifier sludge.   The Eimco Simcar
      Aerators were tested in and  are rated at 3.5  pounds of oxygen
      per horsepower hour at standard conditions using water as a
      test media.

E-    Clarifier.  The  clarifier follows the aeration basin and is of
      the peripheral flow type.  Detention time is 3.6 hours at plant
      design flow  and  a 100% sludge recirculation rate.  Surface
      overflow rate is 2125  gallons per day per square foot.  Weir
       overflow rate is 145 gallons  per day per linear foot.

 F.     Polishing ponds.  There  are two series connected ponds having
       a total detention time  of 25  days at design flow.  The sides of
       these  ponds  have a 3:1 slope  and are operated  at a 5  ft.  depth.
       (These two  ponds are stocked  with catfish, bream and  bass).

 G.     Micro  screen or  algae  screen  (Grant Unit).  A  portion of  the
       effluent  from the  polishing  pond is  routed through  a  rotary
       drum  microscreen to the flocculant and/or carbon treatment unit.
       This  screening unit has a rated  maximum flow  of 500,000  gpd.
       It is  equipped with  a 40 micron  (120  x  400  mesh)  stainless steel
       screen.   The backwash is routed  to the  sludge  pond.   (Figures
       6 and 7.)

 H.     Flocculant and/or carbon unit (Grant Unit).   This  unit is oper-
        ated jointly with  Item F above and is a packaged unit designed
        by Permutit.  It consists of a dry carbon feeder, a liquid
                                12

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      chemical addition system consisting of two 30 inch diameter
      x 42 inches high mixing tanks to which is connected double
      feed pumps.  These systems feed into a contact tank which is
      followed by a clarifier.  The contact tank measures 6 ft. in
      diameter by 9 ft. high and is equipped with a mixer.  The
      clarifier, a Permutit Permu-Jet measures 20 ft.  in diameter
      and 12 ft. deep.  A Permutit 10 ft. diameter 12 ft. high
      valveless filter packed with sand and anthracite serves as
      a final filter.  The system is shown on the schematic in
      Figure 8.  Photographs of the unit appear as Figures  9 and
      10.

I.    Sludge pond.   The earthern sludge pond measures  250' x 500'
      and operates  at a 5' depth.   The sides of this pond have a
      3:1 slope.

J-    Digester.  The aerobic digester basin has a capacity of
      67,000 cubic  feet ans is equipped with a 75 HP and a 25 HP
      mechanical aerator.   The oxygen transfer per horsepower hour
      is comparable to that for the aerators in the aeration basin
      as described  previously.
                              13

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                                                                                                              AEROBIC DIGESTER
                                                                                                               AERATION  BftSIN
                                                                                                  linn ijiH i li in I mi n i ii i£i	li iiiiii [i nfl
                          EQUALIZER BASINS
HOLDING LAGOON     CHROMATE REDUCTION
                                                                                          TREATMENT TANK

                                                                                               I    TREATMENT CHEMICAL
                                                                                                    STORAGE a SOLUTIONS
                                                                                                                                   POLISHING  PONDS
                                                                         CARBON
                                                                       SLUD« POND     CLARIFLOCCULATOR
COOLING  TOWKR
                                                          OUTFALL
                                                     (OUMMG «-USE
                                                                                                                             NOTE:
                                                                                                                               GRANT  UNITS  SHOWN WITHIN
                                                                                                                               BLOCKED AREAS.
                                                                                                                                          OVERALL  SCHEMATIC
                                                                                                                                                 of the
                                                                                                                                 WASTEWATEft and WATER REUSE FACILITY
                                                                                                                                                  at
                                                                                                                                  FIBER INDUSTRIES. INC, SHELBY N C

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                                    FIGURE  2

Aerial view of Fiber Industries, Inc., Shelby, North Carolina
shown in the foreground is at the rear of the plant.
The Treatment facility

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L
                                                                                                                                         T
SCHEMATIC of CONTINUOUS OPERATION
 CHROMATE REDUCTION SYSTEM

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\
                                                                                            FIGURE 4
                                                                                    SCHEMATIC of PLASTIC MEDIA
                                                                                         TRICKLING  FILTER
                                                                                              Mtorag
                                                                                   STRUCTURAL MEMBERS and MEDIA
                                                                                       BUNDLE ARRANGEMENT

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                               FIGURE  5

Photograph of plastic media trickling  filter.   Variable  speed
shown on the left.   Samples of plastic media  tower  packing  is
the foreground.
pump is
shown in
                                  18

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    SCHEMATIC
        of
NORTH' MICROSCREEN
  (ALGAE SCREEN)

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no
                                                  FIGURE  7
          Photograph of 500,000 GPD North algae screen installed between polishing pond and carbon and
          flocculant treatment unit.

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               POWDERED
               CARBON FEEDER
               BY WALLACE 8
               TIERNAN
               MODEL OF 60
FROM ALGAE  SCREEN
                                                                CHEMCIAL FEED TANKS
                                                                BY PERMUTIT
                                                                                                                                     TO  REUSE
                                                 CONTACT TANK
                                                                                                                 10'  DIA, VALVELESS
                                                                                                                 GRAVITY FILTER
                                                                                                                 BY PERMUTIT
                                                                              20' DIA. PERMUJET
                                                                                                                            FIGURE 8
                                                                                                                            SCHEMATIC
                                                                                                                                of
                                                                                                                   FLOCCULAHT «nd CARBON UNITS

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ro
ro


                                                     FIGURE 9

           Exterior view of Permutit carbon and flocculant treatment unit.
           feed unit, the liquid additive mixing tanks and feed pump.  The
           of the photograph.
 The building houses the dry carbon
settling tank appears to the right

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                           FIGURE 10

The automatic valveless gravity final filter is installed down-
stream of the settling tank.   Filtered water is pumped to the
plant cooling tower for use as makeup water.
                              23

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                           PRIOR ART
Micro-Screening

Screening devices of various types have been in use for many years
in removing suspended materials from water.  These uses include
the removal of paunch from meat processing waste, solids removal
from domestic sewage, lint removal from textile and woolen mill
waste.  In recent years, screening devices commonly called "algae
screens" or "micro-screens" have also been used for the removal
of fine suspended materials as a first step in the treatment of
water for potable or process use.  This type use has been rather
extensive in the paper industry where large volumes of "raw water"
are required.

A micro-screen is generally a device in which a wire mesh covers  a
rotating cylinder and through which the liquid to be filtered flow.
The residue is deposited on the screen as the liquid passes through.
The residue is removed from the screen and deposited in a trough  as
it rotates past spray nozzles which backwash the screen.  Size and
amount of suspended material removed depends upon screen size and
pattern of weave.  Obviously, a finer screen has a better removal
capability; however, the finer screens are known to be "blind" and
become inoperative (15).

Chemical Treatment

The removal of soluble organic and finely dispersed insoluble organic
and inorganic materials by flocculation or by the use of activated
carbon has received a great deal of attention in recent years.  Crook
and Poll is (14) have extensively investigated the use of polyelectro-
lytes, both cationic and anionic, for use in the removal of such
materials from water.  They have found that by the use of a polyamine
bisulfate salt and similar polymers having molecular weights of 3 x
105, significant quantities of soluble organic and insoluble organic
materials from domestic and industrial waste can be removed.  This
has been proven in field tests by this group.  This technique has
been applied directly to the treatment of waste water by the Federal
Water Quality Administration at Lebanon, Ohio (15) with very promising
results.  Much of this work was directed towards the use of polymers
for pretreatment of wastewater prior to normal secondary treatment.
Carbon on the other hand was used by this group for the most part
to reduce the BOD5, COD, color and other parameters as a form of post
treatment after secondary treatment.  There has been very little work
accomplished in the area of post treatment of the waste water using
these two methods after the waste has been reduced in 8005 by 95
                              24

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percent or more in a biological treatment system.  The water obtained
from the 95 percent treatment process is naturally of a much higher
quality than that from only secondary treatment and any significant
improvement in its quality would be of major interest for those
interested in water reuse.

Chromate Reduction

A variety of reducing agents are employed for the reduction of hexa-
valent chromium (1, 2).  Listed below in their order of importance
are the most common agents:

1.    Sulfur Dioxide (S02)  (Used in 12090 EUX)

2.    Sodium Bisulfite  (NaHS03)

3.    Sodium Sulfite  (Na2S03)

4.    Sodium Metabisulfite

5.    Ferrous Sulfate  (FeSO/j)

Of these, sulfur dioxide, ferrous sulfate, and sodium metabisulfite
are the most generally used.  Typical reactions are illustrated below.

1.    2Cr03 + 3S02-*-Cr2 (S04)3  (Used in 12090 EUX)

2.    4Cr03 + 6NaHS03 + 3H2S04~»-3Na2S04 + 2Cr2 (S04)3 + 6H20

3.    2Cr03 + 3Na2S03 + 3H2S04 -*-3Na2S04 + Cr2 (S04) + 3H20

4.    4Cr03 + 3Na2S205 + 3H2S04->-3Na2S04 + 2Cr2 (S04)3 + 3H2

5.    2Cr03 + 6FeS04 .7H20 + 6H2S04-*-3Fe2 (S04)3 +Cr2 (S04)3 + 48H20

All of the above reactions occur in acidic media, some necessitating
the addition of an acid such as sulfuric to insure a rapid reaction
rate and minimum quantities of reducing agent.  All of the procedures
convert hexavalent chromate to trivalent chromium and must therefore
be followed by a supplementary step to remove trivalent chromium from
solution.  This is accomplished by elevating the pH of the waste stream
to 8.0 - 9.0 and precipitating the chromium as chromic hydroxide.
Lime is most often utilized for this purpose.  Sodium hydroxide or any
other available alkali may be preferred in smaller installations be- .
cause of the greater ease of handling and its immediate availability.
The precipitation reaction is as follows:

      Cr2 (S04) Cr2 (S04)3 + 3Ca(OH)2-»-2Cr(OH)3 + 3CaS04
                              25

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Adequate time must be provided for the settling of the chromic hy-
droxide precipitate to assure its removal.

Ferrous sulfate is one of the early chemicals used and is still
applicable today for smaller systems or where improved settling
rates are especially desirable.   The ferrous ion formed in the re-
duction reaction precipitates in the alkaline solution forming
ferric hydroxide which serves as a coagulant to assist in bringing
down the slow settling chromic hydroxide.   Generally, ferrous sulfate
would be supplemented by one of the other reducing agents in larger
systems due to economic considerations.

PI asti c Hedi a Trickl i n g Fi Her

Trickling filters in themselves  are not new, in fact, they have
been used quite extensively for the treatment of wastewater for
many years.  Early designs consisted of merely discharging waste
over a pile of rocks.  Micro-organisms in  the form of a slime layer
developed on the rock pile and the waste in some manner and to some
degree was treated.

Many refinements have been made  as experience has been gained and
the standard trickling filter of today consists of a distribution
system which sprays waste over a uniform bed of rock or slag or some
other inorganic media.  The bed  is fitted  with a ventilation system,
tile underdrain and possibly recirculation pumps.  These traditional
systems are limited in both hydraulic and  organic loading due to the
limited surface area of the media and free space between units of
the media.

Recently, progress has been made in the use of synthetic materials
as media in trickling filters.  Process systems have been developed
wherein a polyvinyl chloride honeycomb has been formed and used as
the media.  Such a system is referred to as a plastic media trickling
filter, and it has distinct advantages over the conventional filter.
Some of the major advantages are as follows:

1.   The plastic media provides  more surface area per cubic foot
     than traditional inorganic  media.

2.   The plastic media possesses approximately 97 percent void
     space as compared with 45 percent for slag and rock.

3.   Plastic media requires less land area because of its vertical
     construction.

4.   Plastic media requires less structural support.
                               26

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5.   No elaborate or expensive tile underdrain system is
     necessary.

6.   A preformed media of uniform and controlled quality is
     assured as compared to the randomness of rock or slag.

Various literature references in the past few years have contained
loading data for plastic media filters and the subsequent BOD re-
duction.  Some typical data on this work is as follows:
                           TABLE  1
            TYPICAL HYDRAULIC AND ORGANIC LOADINGS

       FOR PLASTIC MEDIA TRICKLING FILTERS (11, 12, 13)
Type of                      Organic Loading      Percent BOD
Waste	#/day/1000 c.f.	Reduction	

Domestic                           92                  72
Domestic                          370                  57
Textile                            65                  60
                                  106                  58
Pulp & Paper                      600                  43
Frozen Foods
  Processing                      600                 .53
Fruit & Vegetable
  Processing                      102                  80
Brewery Wastes	             126	  80	


Unusual and sometimes unexpected results have been obtained by the
use of these filters.  In an attempt to explain some of the phenomena
many persons have presented their observations.  Chipperfield's
(12, 13) work and his extensive review of other work suggests that
since "there is a constant percentage removal of BODs from solution
with increasing load that the biological filtration process at high
loadings is similar to the absorption process, and thus, in a given
unit, the only limitation to the amount of BOD removed per unit volume
of filter would be the availability of the treatment bios to the
substrate".  With Chipperfield's work as background it would appear
that under a given set of loading conditions a situation would
develop wherein the bios become the limiting factor.  If more bios
could be introduced then the amount of BOD removal could be increased.
Such a situation could be produced if mobile biota, activated sludge
for example, could be introduced into the system to supplement the
stationary bios present on the trickling filter structure.  This can
be accomplished by placing the filter ahead of an activated sludge
                               27

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system and recycling sludge directly to the trickling filter.  The
effluent from the tower would then discharge into the aeration basin
and then to the clarifier.  Such an arrangement was a part of this
project and will be discussed in the experimental section.

Chipperfield also states that at loadings of 260-370 pounds per 1000
cubic feet per day, removals lie between 40 and 65% depending on the
waste.  It was also stated by Chipperfield that recycle in sufficient
amount to maintain the minimum wetting rate for the filter was opti-
mum since excess recirculation above this rate may cause some decrease
in percentage BOD removal.
                               28

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                          SECTION VI

     OPERATIONAL AND EXPERIMENTAL ASPECTS OF THE PROJECT



                           OPERATION


Chromate Reduction Unit

The chromate reduction system was designed to receive effluent
from the cooling tower at rates of up to 120 gpm.  The influent to
the unit contains up to 30 mg/1 chromium (VI) as chromate and the
effluent from the unit contains chromium (III).  Internally the
system has two tanks in which reactions occur.  The first tank is
the reduction tank and it is equipped with an oxidation reduction
potential electrode (ORP electrode) and a pH electrode.  The
electrical signal generated by the ORP electrode is directed to a
potentiometer type recorder equipped with pneumatic control.  The
output from this controller is fed to a pneumatically positioned
flow regulator valve within a sulfonator which in turn automatically
proportions the feed rate of SO? to the system in accordance with
the demands of the ORP electrode.  This feed rate is, therefore, a
function of the unreduced chromium (VI) in the system since the ORP
cell measures the potential difference in the chromium (VI) and
chromium (III) in the system.  The pH system operates similarly but
in this case controls an acid feed pump.  The second tank or neu-
tralization tank is series connected to the first and is equipped
with a pH system which operates an alkali pump in a similar manner.

Based on the day to day demands for cooling tower operation and blow-
down, the operating personnel preset the rate of flow and the ORP
and pH set points.  In addition, they replace the chemical drums
and gas cylinders as necessary.

During the grant period a number of minor operational difficulties
were encountered.  They are as follows:

1.   Flow fluctuations.   The chromate reduction system is fed from
     the cooling tower riser.  This riser is subject to the pressure
     fluctuations and this in turn results in flow fluctuations to
     the chromate reduction unit.  This was a minor problem and was
     resolved by the installation of a feed pump.
                              29

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2.   Electrode poisoning.   After about eight weeks of operation,  it
     was found that the ORP system was slowly becoming insensative.
     The cause was investigated and it was concluded that Dowtherm,
     which had been inadvertantly spilled into the cooling system,
     was coating the dip type electrodes.  This problem continues
     to occur and ORP electrodes must be changed every three to four
     months as a result.

PIastic Medja Trickling Fi 1 ter

The plastic media trickling filter was designed and constructed in
such a manner as to allow a 10 ft. deep tier of media to be readily
removed or a 10 ft. tier of media to be readily added.  The 10,000
cubic foot unit as constructed had a 25 ft. diameter and was hex-
agonal in shape.  It was fitted with a standard rotary distributor.
The recirculation pump was installed in the sump and a capacity
ranging up to 900 gpm.  Valving and piping arrangements to the tower
were designed so that sanitary and chemical waste could be fed to
the tower and treatment of these wastes could be observed as a slime
layer built up on the tower.  An alternate method of operation was
provided where in return sludge could be blended with this waste
and the blend pumped across the tower for observation.  Operational
problems associated with this unit are as follows:

1.   Freezing.  At ambient temperatures below 10°F the wastewater
     freezes when it is sprayed out of the rotary distributor.
     During the early part of 1970 the unit was shut down no less
     than sixty days due to freezing.  Once the interior of the tower
     within the media is frozen, it takes approximately ten days  of
     above freezing temperatures (during daylight hours) to thaw.
     Placing the tower within a heated building or warehouse would
     alleviate this problem, but it may be economically unattractive.
     It should be noted that the surface of the aerator basin con-
     taining the mechanical aerators freezes under the same ambient
     conditions with the resulting overloading and shutting down  of
     the aerators.  However, the aeration basin thaws in about one-
     tenth of the time required for the plastic media tower.  No
     structural damage to the media or to the twoer structure occurred
     during the freeze.  The mechanical effect of the freeze thaw cycle
     on the media should be closely observed in the future, however,
     in order to gain knowledge in this area.

2.   Rotary Distributor Orifice Plugging.  When the rotary distribu-
     tor was first placed in operation, the comminutor in the sani-
     tary sewer at the head of the plant was out of order.  It was
     thought that the solids materials might tend to plug the
     orifices of the distributor.  Such was not the case.  No plugging
     was noted.
                              30

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Microscreeping and Chemical Treatment Unit Operation

Influent to this system comes from the polishing ponds.   The water
first passes through the microscreen into a piping system fitted
with an in-line mixer and then into a contact tank.   From the con-
tact tank the water continues on through a clarifier to a final
filter and then is pumped back to the cooling tower for use.  Back-
wash from the microscreen, waste sludge from the clarifier and back-
wash from the final filter are pumped to the treatment plant sludge
pond.  The operator regulates the rate of flow by utilizing a valve
and rotometer.  Chemicals either powdered or liquid are introduced
into the water prior to the contact tank.  Sludge wasting from the
clarifier is accomplished on a daily basis as necessary by the
operator.  Backwashing of the final filter is automatic and is con-
trolled by pressure drop across the final filter.

Equipment problems encountered during the study are as follows:

1.   The backwash spray nozzles on the microscreen became frozen
     during below freezing ambient conditions.  This problem can
     be resolved by placing the filter in a protected area.

2.   The rotor assembly in the clarifier is impulse driven by pumped
     recirculated water.  As the sludge blanket built up in the
     clarifier, there was a tendency for the rotor to stall.  This
     in turn caused a major sludge build-up and the entire clarifier
     system became inoperative.  A permanent resolution for this
     problem is the installation of a direct motor drive on the
     rotor assembly of the clarifier since the impulse drive does
     not appear to be sufficient.

3.   During summer operation slime growth developed on the screens
     of the microscreen and impaired flow thereby necessitating
     cleaning.  This became rather common and time consuming and was
     at its peak during algae bloom periods in the polishing ponds.
     This was deliberately allowed to happen in order to observe its
     effect on the operation of the filter.  The microscreen is  fitted
     with a steam tap so that the backwash nozzles can be utilized
     for steam cleaning of the screen under such conditions; therefore,
     a permanent fix is contained on the unit itself.
                               31

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                         EXPERIMENTAL
The basic concept in this demonstration project was to install  the
grant units in the existing treatment plant in such a manner that all
of the wastes, including cooling tower blowdown, would be routed to
the treatment plant, treated to a high degree and discharged with
up to 25 percent being reused for cooling tower makeup.  The grant
units were to be operated and evaluated as appropriate over their
operational ranges.  Sampling points were to be established at  such
locations and taken at such frequencies as to evaluate the operation
of the plant.  The sampling points are shown in Figure 11.  These
points are located before and after each unit operation and/or  before
and after each point of combination or recirculation of waste,  sludge
or effluent.

Chromate Reduction

The chromate  reduction unit was placed in operation and evaluated
initially for hydraulic capacity and then for efficiency of chromate
reduction.  The evaluation consisted of operating the system at
selected blowdown rates and observing the adequacy of the operation
of the various components.  It was established that the unit would
operate properly over the design range of flows and chromate con-
centrations.   Thereafter the unit was operated on a day to day  basis
at various blowdown rates as dictated by cooling water solids con-
centrations adjustment requirements.  This ranged from no blowdown
during some winter periods to 100 gpm blowdown on some summer days.
All effluent  from the chromate reduction unit was directed to a
settling pond which also served as a surge pond.  Effluent from
this pond was directed to the treatment plant at a constant rate
by valving so that shock loading of the treatment plant would not
occur.  The effluent ultimately entered the treatment plant through
the chemical  sewer system wherein it was diluted.  Data collected
during these  evaluation periods is presented in Table 2.
                               32

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                                                      TABLE 2

                                     CHROMATE REDUCTION UNIT OPERATIONAL DATA
CO
co
Influent to
Chromate Unit

Blowdown
Rate, gpm
48
80

5-94
25-60

21-91

Duration of
Test (Days)
34
39

30
41

30
Cr "
Range
mg/1
10-20
10-20

10-20
8-26

9-20
Biocide
Range
mg/1 & Type
36 (Note 1)
8-19 (Note 2)
0-37 (Note 3)
30 (Note 4)
8-17 (Note 2)
0-37 (Note 3)
0-57 (Note 5)
Influent to
Waste
Treatment Plant
Cr+0
Range
mg/1
0
0
0
0
0
0
0
Biocide
Range
mg/1
5-7
0-9
(Note 7)
(Note 6)
0-6
(Note 7)
(Note 6)
Effluent
From
Treatment Plant
Biocide
Range
mg/1
0
0
0
0
0
0
0
             (1)  Betz C-30 bis  (trichloromethyl) sulfone and methylene bisthiocyanate blend.
             (2)  Betz A-9  sodium pentachlorophenate.
             (3)  Betz C-5  1,3  dichloro-5, 5-dimethylhydantoin.
             (4)  Betz J-12 N-alkyl dimethyl benzyl ammonium chloride.
             (5)  Betz C-34 sodium dimethyl dithiocarbamate and disodium ethylene bisdithiocarbamate.
             (6)  Destroyed in reduction tanks.
             (7)  Dissipates  in  cooling tower in six hours and is not contained in blowdown.

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Plastic Media Trickling Filter

The plastic media trickling filter was evaluated in a manner similar
to that described by Egan (14), Chipperfield (12, 13), and contained
in the Sewage Treatment Plant Design Manual  (11).  These methods
are considered standard for the art and are  summarized as follows
as they apply to this project:

1.   Mode A.  In this mode the combined sanitary and chemical  waste
     including cooling tower blowdown were routed across the tower.
     The efficiency of the plastic media was established by the
     evaluation of data from samples taken before and after the
     tower.  8005 was determined on the settled effluent and not on
     a completely mixed sample.

2.   Mode B.  Mode B is identical to Mode A except that the return
     sludge from the clarifier is combined with the sanitary waste,
     chemical waste and cooling tower blowdown and this composite is
     pumped across the tower.  The 6005 reduction (as well as  other
     parameters) under this mode of operation is derived by calcu-
     lations using the volume and BODg concentration in the combined
     sanitary waste, chemical waste and cooling tower blowdown with
     similar data on effluent from the unit  which includes the be-
     fore mentioned streams plus the sludge  recycle.

3-   Mode C.   Mode C is a special mode of operation and evaluation
     wherein only a portion of the plastic media tower is used with
     the same waste volume.  Higher hydraulic and organic loadings
     per unit area and per unit volume respectively can be obtained.
     BOD^ reduction (as well as other parameters) was determined
     as in Mode B above.

The BOD5 reduction data obtained during each of the modes described
is presented in Figures 13, 14, 15 and 16.  In operating at these
modes and in presenting the data the following terms are used as
they apply to this project.

1.   Hydraulic loading.  Hydraulic loading is expressed in gallons
     per square foot per minute.  It is based on the actual cali-
     brated pumping rate.

2.   Organic loading.  This is expressed in  pounds per cubic foot
     of media per day.  It is based on the BOD5 of the treatment
     plant influent and does not include BODg contained in recycle,
     if any, from the clarifier.
                              34

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3.    Recycle rate.  Recycle is expressed as the ratio of the trickl-
      ing filter pump output to total treatment plant influent.
      Instances where sludge return from the clarifier is being
      combined with the treatment plant influent and treated across
      the tower, the recycle ratio is the ratio of the trickling
      filter pump output to the combined treatment plant influent
      and sludge return.

Chemical Treatment and Microscreening

The experimental portion of the chemical treatment including the
microscreening unit was broken into two phases.  The first phase
utilized polishing pond water as feed and the second phase utilized
clarifier water as feed.  In both instances jar tests were conducted
utilizing alum, various polymers and polymer combinations and
powdered carbon.  Materials that showed promise in jar tests were
evaluated on a full scale trial.  Each chemical additive that was
evaluated on a full scale trial is presented in Table 3 and Table
4.  The manufacturers data sheet for each additive used appears in
the appendix.

Sampling

Initially sampling was conducted daily by use of automatic continuous
non-proportional dipper samplers at the points shown on sampling plan
(Figure 11).  The use of the automatic samplers was discontinued and
daily grab samples were taken after it was established that the two
methods gave comparable results.  Sampling points were selected so
that each unit operation could be bracketed and its performance
evaluated on a daily basis throughout the grant period.  The data pre-
sented in the tables and figures which follow was compiled using grab
samples.  The data obtained was grouped into classes, the mean and
standard deviation for each class was determined; the mean was then
evaluated and plotted.   Each point on the graph in the figures which
follow represents a class consisting of not less than ten analyses.
                              35

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                                                                                      TABLE 3

                                                               DATA FROM HICROSCREENING AND CHEMICAL TREATMENT  UNIT

                                           UTILIZING POLISHING POND EFFLUENT -  TREATMENT ACROSS MICROSCREEN  AND CHEMICAL  TREATMENT  UNIT
CO
COO
Initial Final
Treatment Type mg/1 rnq/1
and Dosage (1,2) (% Reduced)
1. Alum 85.5 mg/1 161 90
Aqua Nuchar A
60 mg/1 (44)
2. Alum 102 mg/1 174 89
Aqua Nuchar A
120 mg/1 (49)
C-25 8 mg/1
3. Alum 43.5 rag/1 197 172
Aqua Nuchar A
84 mg/1 (13)
Poly Floe 1160
1 mg/1
4. Alum 200 mg/1 100 78
Aqua Nuchar A
182 mg/1 (22)
Poly Floe 1160
1 mg/1
5. Alum 163 mg/1 140 117
Aqua Nuchar A
128 mg/1 (16)
Poly Floe 1160
1 mg/1
6. C-225 6.3 ng/1 124 90
C-25 15 mg/1
(27)
7. Aqua Rid 49-701 100 90
13 mg/1
Aqua Rid 96-549 (10)
30 mg/1
8. Alum 44 mg/1 140 80
Poly Floe 1160
4 mg/1 (43)
9. C-2Z5 13 mg/1 126 87
C-25 15 mg/1
Aqua Nuchar (31)
180 mg/1
Total Phosphate
Initial Final
mg/1 mg/1
(% Reduced)
3.6 0.9
(75)
4.3 1.0
(77)
2.9 1.9
(34)
1.7 0.7
(58)
3.9 1.7
(56)
2.5 2.4
( 2)
7.3 7.3
( 0)
3.3 3.2
( 3)
4.6 0.8
(82)
Total Nitrogen
Initial Final
mg/1 mq/1
(% Reduced)
0.23 0.14
(39)
0.12 0.08
(33)
0.0 0.0
(0)
0.0 0.0
( o)
1.3 0.0
(100)
0.0 0.0
( 0)
0.09 0.06
(33)
0.13 0.08
(39)
0.0 0.0
(0)
Turbidity
Initial Final
Units Units
(% Reduced)
( -)
53 22
(63)
88 84
( 5)
36 17
(53)
163 38
(77)
51 17
(67)
50 21
(58)
53 14
(74)
90 30.
(30)
Color
Initial Final
Units Units
(% Reduced)
200 60
(70)
245 80
(67)
260 248
( 5)
124 60
(52)
163 112
(31)
114 50
(56)
90 49
(46)
179 42
(77)
300 98
(67)
Fixed Solids
Initial Final
mg/1 mg/1
(% Reduced)
241 292
( 0)
237 305
( 0)
403 413
( 0)
326 372
( 0)
338 369
( Q)
354 386
( 0)
( -)
346 419
( 0)
352 359
( o)
Notes
19 Days
May 1969
24 Days
May -
June 1969
12 Days
July 1969
8 Days,
August 1969
12 Days.
July -
August 1969
13 Days,
October 1969
8 Days,
October 1969
11 Days,
Nov. 1969
7 Days,
Sept. 1969
                Notes:  (1)  See appendix II for trade name product identification.

                        (2)  Preliminary jar tests gave indication of dosage which was verified and refined by actual  plant operation.  The actual dosage used
                             under refined conditions of operation is presented in this table.

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                                                                     TABLE 4

                                              DATA FROM MICROSCREENINS AND CHEHICAl TREATMENT UNIT

                                               CLARIFIER EFFLUENT - TREAWNT ACROSS CHEMICAL UNIT
Treatment Type
and Dosage (1,2)
1. Control, No
Chemical Treat-
ment, screened
& filtered
Z. Alum 75 mg/1
3. Alum 75 mg/1
C-225 3 mg/1
4. Aluia 45 mg/1
C-225 2 mg/1
Aqua Nuchar A
250 mg/1
5. Alum 36 mg/1
C-225 2 mg/1
Oarco S-51
200 mg/1
6. Alum 100 mg/1
Oarco S-51
200 mg/1
COD
Initial Final
mg/1 mg/1
(% Reduced)
320 470
(0)
350 255
(27)
250 223
(11)
160 90
(44)
139 75
(46)
" (-)
Total Phosphate
Initial Final
mg/1 mg/1
(% Reduced)
5.7 2.0
(71)
9.0 1.0
(88)
5.4 5,1
( 6)
10.9 9.2
(16)
6.2 5.9
( 5)
7.5 3.3
(56)
Total Nitrogen
Initial Final
mg/1 mg/1
(Z Reduced)
1.3 0.18
(86)
0.20 0.20
( 0)
5.5 7.1
( 0)
0.52 0.18
(65)
2.3 4.4
(0)
2.7 1.6
(40)
Turbidity
Initial Final
Units Units
(X Reduced)
160 70
(56)
120 45
(63)
54 38
(30)
38 37
( 4)
48 50
( 0)
20
COLOR
Initial Final
Units Units
(% Reduced)
422 183
(57)
193 139
(28)
135 105
(22)
97 85
(12)
120 128
( 7)
60 60
(0)
Fixed Solids
Initial Final
mg/1 mg/1
(% Reduced)
442 392
(11)
489 440
(10)
492 502
( 0)
540 516
( 4)
264 272
( 0)
" (-)
NOTES
7 Days,
Feb. 1970
12 Days,
Feb. i
March 1970
16 Days,
March 1970
8 Days,
March 1970
15 Days,
April 1970 !
8 Days,
April 1970
Notes:  (1)  See appendix II for trade name product Identification.

        (2)  Preliminary jar tests gave indication  of dosage  which was  verified and refined by actual plant operation.  The actual dosage used
             under refined conditions of operation  Is presented  In this title.

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                                                                                      TABLE 5



                                                           EFFECTIVENESS OF POLISHING PONDS AS A TERTIARY TREATMENT UNIT



                                                   (TWO PONDS, SERIES CONNECTED. THIRTY DAYS DETENTION, FIVE FOOT OPERATION DEPTH)
CO

March- April -Hay
1969
June -July-August
1969
September-Octobe r-
November
1969
December - 1969
January - February
1970
BOD
Initial Final
rng/1 mg/1
(% Reduced)
25 13
(48)
12 12
( 0)
16 9
(44)
75 77
( 0)
COD
Initial Final
.mg/1 mg/1
(% Reduced)
189 164
(13)
149 161
( 0)
160 129
(19)
516 389
(25)
	 	 _ - _ _ _ — 	
Total Nitrogen
Initial Final
mg/1 mg/1
(% Reduced)
0.24 0.19
(21)
1.70 0.23
(86)
1.69 0.10
(94)
1.02 0.22
(78)
TbtaT Phosphate
Initial Final
mg/1 mg/1
(% Reduced)
2.7 1.3
(52)
5.0 3.1
(38)
5.3 2.6
(50)
6.1 3.6
(41)
Fixeci SoTids
Initial Final
mg/1 mg/1
(% Reduced)
249 230
( 8)
436 317
(27)
464 383
(17)
420 349
(17)

-------
CO
vo
        COOLING
         TOWER
                         CHEMICAL WASTE
                    WASTE
                  TREATMENT
                    PLANT
                 EQUALIZATION
                    BASINS
                        SLUDGE
                         POND
   DOMESTIC WASTE

       SLUDGE RETU
SLUDGE WASTE
\
I
POLISHING
POND NO. 1



POLISHING
POND NO. 2
/^PV,
\5/

ALGAE
SCREEN
— 1
-
-------






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FIGURE 12
PLASTIC MEDIA TRICKLING FILTER
OPERATIONAL MODE B 8 C - SLUDGE RECYCLE

HYDRAULIC LOADING
O 0.95 goNoru por *qmro foot por mtairtt
Q 1. 10 folton* por f^tatt fool por minut*
^ 1. 99 galtora por naoro foot por minuto
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-------
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50
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FIGURE 13
PLASTIC MEDIA TRICKLING FILTER
OPERATIONAL MODE A - NO SLUDGE RECYCLE
HYDRAULIC LOADING-
0 1.70 t*U«M
GJ t.90 grtfcm



	 	
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	 B


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-------
                                                                                         FIGURE   14
                                                                                   PLASTIC MEDIA TRICKLING FILTER
                                                                             OPERATIONAL MODE  BaC- SLUDGE RECYCLE

                                                                                       RECYCLE RATE
                                                                                         0 i.l:
                                                                                         Q 1.9 •
fO
                            100
                                      ZOO
300        400        500        «00        TOO
  >9 Loading, Pounds per tOOO Cubic Fe«t of Media, p«r Doy
                                                                                                      loo

-------
CM





60
90
e
•i
o
£ 40
1
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V
5
                                                      80D5 Loading, Pounds per  IOOO Cubic Feet of Media, per Day

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                      ECONOMIC EVALUATION
This section contains selected cost data on the construction and
operation of the waste treatment facility during the grant.  The
waste water treatment plant as constructed, but not including the
grant units, cost in excess of $600,000.  The cost of construction
of the grant units (1968 basis) is summarized on a unit basis as
fol1ows :
Construction Costs


A.    Summary of Final Construction Costs

      Chromate Reduction Unit                     $ 39,410.26
      Trickling Filter-                             57,029.80
      Algae Screen                                  16,378.47
      Carbon Unit                                   56,010.44
      Site and Distribution Requirements            10,542.03
      Engineering                                   19,136.65

      TOTALS                                      $198,507.65


B.    Unit Cost Details

      1.    Chromate Reduction Unit

           a.   Building Foundations               $    585.00
           b.   Building Structure                    8,110.00
           c.   Equipment                            21,863.00
           d.   Equipment Foundations                   325.00
           e.   Electrical                             4,004.26
           f.   Piping                                2,903.00
           g.   Paving (Gravel)                         250.00
           h.   Grading (Lagoon)                      1,370.00

               Direct Cost                        $ 39,410.26
               Engineering & Site Allocation         6.927.00

               TOTAL COST                          $ 46,337.26
                              44

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2.    Trickling Filter

      a.    Equipment                $27,000.00
      b.    Equipment Foundations     15,470.00
      c.    Painting                     705.00
      d.    Electrical                 2,730.00
      e.    Piping                    11,124.80

            Direct Cost              $57,029.80
            Engineering &
              Site Allocation         10,025.46

      TOTAL COST                     $67,055.26

3.    Algae Screen

      a.    Equipment                $10,140.68
      b.    Equipment Foundations      2,040.00
      c.    Electrical                   475.00
      d.    Piping                     3,722.79

            Direct Cost              $16,378.47
            Engineering &
              Site Allocation          2.878.83
TOTAL COST
Carbon Unit
a. Building Structure
b. Equipment
c. Equipment Foundations
d. Electrical
e. Piping
f. Grading (Lagoon)
$19,257.30

$ 1,804.00
42,670.03
3,081.00
911.16
6,142.65
1,401.60
            Direct Cost              $56,010.44
            Engineering &
              Site Allocation          9,847.39

      TOTAL COST                     $65,857.83
                         45

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      5.    Site and Distribution

            a.    Electrical                $ 4,521.91
            b.    Piping                     5,112.75
            c.    Paving (Gravel)              907.37

            TOTAL COST                     $10,542.03

      6.    General  Requirements (Overheads)

            a.    Preliminary Plans
                    and Specifications     $ 3,995.76
            b.    Final Plans and
                    Specifications           8,825.00
            c.    Construction Super.         6,315.89

            TOTAL COST                     $19,136.65

NOTE: Miscellaneous  piping changes were made durinq the experi-
      mental portion of the grant for  evaluation purposes.   These
      costs are not  included  above since they could be considered
      duplication.
                               46

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Selected Comparative Costs Including Operating Costs
Some selected comparative cost, including operating costs for the
treatment plant and grant units under selected conditions, are as
follows:

1.   Cost of treatment plant operation before       $0.35/1000 gallons
     grant (1967)                                   of waste treated

     This includes electricity, maintenance,
     operator salary and all other operation
     and maintenance costs.  No capital costs
     are included.

2.   Cost of treatment plant operation during       $0.64/1000 gallons
     grant period                                   of waste treated

     This includes all items in 1 above in
     addition to extra operating personnel
     required by the grant experimental
     phase, additional electrical require-
     ments, chemicals and flocculants.  It
     does not include the mobile laboratory
     operation.

3.   Estimated cost of treatment plant              $0.40/1000 gallons
     operation in the future utilizing              of waste treated
     selected grant units on a production
     basis as compared to experimental
     basis in 2 above.

     This includes the operation of the
     trickling filter, microscreen and a
     greatly reduced operation of the
     chemical treatment unit in line with
     the findings of this project.

4.   The average market value of polyester
     produced in the Fiber Industries, Inc.,
     Shelby plant during the grant period
     was $0.88 per pound.  During this
     period 0.604 gallons of waste con-
     taining 0.0056 pounds of 6005 was produced
     per pound of polyester produced.  The
     cost of treatment of the waste from the
     production of one pound of polyester, using
     item 2 above as a basis, is $0.00039.  This
     is the operational cost and does not
     include any capital  cost considerations.
                              47

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5.    The chromate reduction unit chemical costs are based on the
      chemicals required to treat one pound of chromate.  The
      theoretical and actual costs are as follows:

      Theoretical cost per pound of CrCL =

      0.85 pounds S0?   @ 0.075  =   $0.064
      0.30 pounds H2S04 @ 0.027  =    0.008

      1.10 pounds NaOH  @ 0.060  =    0.066

      TOTAL THEORETICAL COST         $0.138

      In actual operation about 50 percent excess chemicals are
      required to assure complete reaction.  The actual cost of
      treating one pound of Cr04 =

      Actual Total Cost =   0.138 x 1.5  =  $0.21

6.    The chemical and./or flocculant costs must be based on the
      water quality desired and the flocculant selected for use.
      A typical cost for chemical post treatment at the Fiber
      Industries, Inc., Shelby operation is as follows:

                                           Cost per 1000 gallons

      Aqua Rid 49-701          13 mg/1              $0.022
      Aqua Rid 96-549          30 mg/1               0.025

                                                   $0.047

7.    The cost of the plastic  media trickling filter unit as  com-
      pared to an equivalent mechanical  aeration unit may be  de-
      rived by comparing the tower, complete with pump and sump,
      with a single 75 HP aerator installation complete.

      Plastic media trickling  filter (see Items 1,  5 and 6,  above)

            Construction Contract                    $57,029.80
            Prorated site,  distribution  and
            General  Requirements                      10,025.46
                                                     $67,055.26
                              48

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Mechanical Aerator Installation

      Aerator                                  $17,000.00
      Platform and Miscellaneous Structures      6,500.00
      Electrical                                  6,000.00
      Basin                                     30,000.00
      Prorated site and distribution             2,000.00
      Prorated general  requirements              4,000.00

                                               $65,500.00
                        49

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                          SECTION  VII
    OPERATION OF THE TREATMENT SYSTEM ON A  PRODUCTION  BASIS
The waste treatment system can be operated on a  full scale basis
with water reuse at 0.1 MGD using the following  treatment units at
the below listed estimated costs:
Pre Treatment
      Chromate Reduction and Equalization         $0.034 /  1000  gallons
Primary and Secondary Treatment
      Roughing Filter                              0.019 /  1000  gallons
      Aeration and Clarification                   0.300 /  1000  gallons
T_e_r_tj_ary_ Treatment
      Polymer Addition and Final Filter            0.047 /  1000  gallons
ESTIMATED TOTAL OPERATING COST                    $0.400 /  1000  gallons

The estimated total capital cost for such a treatment facility,  using
design criteria contained in Section V of this report, is $800,000
(1968 basis).
                              51

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                         SECTION VIII

                       ACKNOWLEDGEMENTS
The support of Mr. J. B. Phelps, Vice President and Mr. Richard
Shalie, Director of Engineering of Fiber Industries, Incorporated
is acknowledged with sincere thanks.

Mr. W. J. Day and Mr. E. C. Burrell of Davis & Floyd, Inc.,
Consulting Engineers, directed the design and operation of the
Grant and prepared this report.  Mr. C. E.  Steinmetz, Engineering
Associate, Fiber Industries, Incorporated,  functioned as Project
Coordinator on this project.

The support of the project by the Federal Water Quality Adminis-
tration and the timely guidance of Dr. Ray  Thacker, Mr. William Lacy
and Mr. Charles Ris is acknowledged.
                              53

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                          SECTION  IX

                          REFERENCES
  1.   Udy, Marvin J.,  "Chromium, Volume 1", Reinhold Publishing
      Company, New York  (1956).

  2.   Sienko, Michel!  J. and Plane, Robert A., "Chemistry", Third
      Edition, McGraw  Hill, New York (1966).

  3.   "Interaction of  Heavy Metals and Biological Sewage Treat-
      ment Processes", Robert A. Taft Sanitary Engineering Center,
      Cincinnati (1965).

  4.   Anonymous, "Removal of Chromate from Coolinq Tower Slowdown,"
      Betz Laboratories, Inc., Philadelphia (1967).

  5.   "Manual on Industrial Water and Industrial  Waste Water",
      ASTM Special  Technical Publication No. 148-H, American
      Society for Testing and Materials, Philadelphia (1965).

  6.   "Water Quality Criteria", Federal Water Pollution Control
      Administration, Washington (1967).

  7.   Hesler, J. C., The Ion Exchange Recovery Process, Proceedings
      International  Water Conference, Engineers Society of Western
      Pennsylvania,  Pittsburgh (1964).

 8.   Puckorius, P.  R. and Farnsworth,  N.  B.,  The Role of the Pro-
      cess in Cooling Water Technology.  Proceedings International
      Water Conference, Engineers  Society of Western Pennsylvania,
      Pittsburgh (1964).

 9.   McKee and H.  W. Wolf, "Water Quality Criteria", 2nd Edition,
      California State Water Quality Board, Publication No. 3-A
      (1963).

10.   Sewage Treatment Plant Design, Water Pollution Control
      Federation, Washington,  D.  C.  (1967).

11.   Chipperfield,  P. N. J.  "The  Use of Plastic  Media in Biological
      Treatment of Sewage and  Industrial  Waste",  Fifteenth Canadian
      Chemical  Engineering Conference,  Universite Laval,  Quebec
      (1965).

12.   Chipperfield,  P. J. J.  "Experiences  in Great Britain by
      Imperial  Chemical Industries  Limited with Plastic Filter
      Media", Annual  Conference of the  Water Pollution Control
      Federation, Kansas  City,  Missouri   (1966).
                              55

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 13.    Egan, John T. and Sandlin, M., "The Evaluation of Plastic
       Trickling Filter Media", Fifteenth Industrial Waste Con-
       ference, Purdue University, Lafayette, Indiana (1961).

 14.    Crook, E. H. and Pollio, F. X. "Removal of Soluble Organic
       and Insoluble Organic and  Inorganic Materials by Flocculation",
       Twenty Sixth Annual Meeting of the International Water Con-
       ference, Pittsburgh, Pennsylvania (1965).

15.     Summary Report,  Advanced Waste Treatment  (July 1964  -  July 1967)
       U. S.  Department of the  Interior,  Federal  Water Pollution Control
       Administration,  Publication WP-20-AWTR-19.
                             56

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                           SECTION X

                          APPENDIX I

               LABORATORY ANALYTICAL PROCEDURES
The basic analytical procedures used for the determination of Bio-
chemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD), dissolved
oxygen (DO), pH, solids, nitrogen, phosphorus, temperature, color,
turbidity, alkalinity, hardness, sulfate, chloride, were taken from
Standard Methods for the Examination of Water and Wastewater, Twelfth
Edition, American Public Health Association, Inc., New York.   Secon-
dary procedures and reagents used for these same determinations were
taken from Methods Manual, Fifth Edition, Hach Chemical  Company, Ames,
Iowa.  Special procedures for determinations not contained in Standard
Methods were as fol1ows:

Chromium (Total, Hexavalent, Trivalent)

Total chromium - A Beckman Atomic Absorption system Model  930 utiliz-
ing a Beckman DB-G Grating Spectrophotometer was used for this deter-
mination.  The procedure was in accordance with Beckman  Instruments,
Inc., Flame Notes, Vol. 1, No.  2, July 1966, pages 49 and 50.

Hexavalent chromium - this procedure was taken from Standard  Methods
for the Examination of Water and Wastewater, Twelfth Edition, American
Public Health Association, Inc., New York, pages 123 and 124.

Coagulation - Flpeculation Jar Test

This procedure used for flocculation jar tests is presented in Part
23, Industrial Water; Atmospheric Analysis. American Society  for
Testing and Materials, Philadelphia, Pa., (1967), pages  523 - 525.

Zinc

A Beckman Atomic Absorption system Model 979 utilizing a Beckman DB-G
Grating Spectrophotometer was used for this determination. The pro-
cedure was in accordance with Beckman Instruments, Inc., Flame Notes,
Vol. 1, No. 3, September 1966,  page 91.
                              57

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Determination of Sodium Pentachlorophenates (Betz A-9) in Hater

This procedure was furnished by Betz Laboratories and is a colormetric
analysis for sodium pentachlorophenate through an extraction and color
development.

A representative 5 ml. sample is pipetted into a 125 ml. separator
funnel.  To this is added 10 ml. of ethylene dichloride.  Immediately
add 0.25 grams of sodium bicarbonate and 0.5 ml. safranine "A"
reagent (Matheson Coleman & Bell).  Proceed to shake for 30 seconds
and allow to stand for one minute.  Draw off the bottom layer into
a 100 ml. beaker and add 0.25 to 1.00 grams sodium sulfate while
swirling the sample after the addition of each 0.25 grams portion
until the solution is crystal clear.  Transfer the solution to a
cell and with the use of a spectrophotometer read percent transmission.
Ethylene dichloride is used in a cell to establish the zero reference
point.

Determination of Methyl  and Ethyl  Bis-dilthiocarbamate (Betz C-34) in
Water

This method was also furnished by Betz Laboratories.  It is based on
the fact that methyl and ethyl bis-dithiocarbamate decomposes to
liberate carbon disulfide when boiled in sulfuric acid.   The gas is
then swept through several scrubbers to remove interferences and then
through a scrubber containing Viles reagent (a copper amino solution).
The intensity of the color resulting from the reaction between the
carbon disulfide and Viles reagent is used to quantitate the amount
of active carbamates present.

A.    Reagents and Equipment.

       1.   Methanolic Potassium Hydroxide 2N

       2.   Lead Acetate Solution 10%

       3.   Sulfuric Acid 50%

       4.   Viles Reagent - In a liter flask containing 50 ml. distill-
            ed water add 0.060 gram of reagent grade copper acetate
            monohydrate, followed by 20 ml. USP triethanol amine and
            10 ml. of purified diethylamine.  Dilute to the 1 liter
            mark with reagent grade isopropanol and mix.  Store in a
            well capped amber bottle.

       5.   Copper Acetate Monohydrate - reagent grade

       6.   Triethanol Amine - USP

       7.   Diethylamine - purified
                                58

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 8.    Isopropanol - reagent grade

 9.    Absorption Train - as illustrated in sketch - all joints
       must be ground glass

10.    Spectrophotometer or Colorimeter - capable of isolating
       a reasonably small wavelength band at 420 nanometers

11.    Stock C-34 Solution - pipet 1.0 ml..of C-34 into a 1 liter
       volumetric flask and dilute to 1 liter with distilled water.

12.    Standard C-34 Solution - pipet 2.0 ml. of the stock sol-
       ution into a 1 liter volumetric flask and dilute to 1 liter
      with distilled water.

Sample Procedure.

 1.   Add 10 ml. of Viles reagent to the carbon disulfide
      scrubber, 20 ml. lead acetate solution to each hydrogen
      sulfide scrubber and 65 ml. of methanolic potassium hydro-
      xide to the air scrubber.

 2.   Turn on the condenser water.

 3.   Add 1 liter of test sample to the reaction flask followed
      by 100 ml. of the 50% sulfuric acid.

 4.    Immediately fasten the flask to the condenser, close all
      connections, and start the air flow through the system at
      a rate of approximately 40 ml. per minute.

 5.   Turn on the heating mantle and bring the sample to a gentle
      boil.

 6.   Reflux (with continual  air sweep) for one hour.

 7.   Discontinue heating and open the connections in the follow-
      ing order to avoid "back-up",   (a)  inlet to reaction flask;
      (b)  inlet to lead acetate scrubbers; (c) inlet to carbon
      disulfide scrubber containing the Viles reagent.

 8.   Shut off the air sweep and remove the graduated carbon
      disulfide scrubber containing the Viles reagent.

 9.   Make up the volume of the Viles reagent to 10 ml. with
      isopropanol.

10.   Transfer solution to a 1 cm. or equivalent cell and read
      the  color intensity at 420 nanometers.   Use isopropanol
      for the 100% T setting.
                         59

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      11.   Carry 1 liter of distilled water through the above steps.
            This will be used as the reagent blank.

      12.   Subtract the absorbance of the reagent blank and read
            the concentration of the C-34 from the standard curve.

C.    Preparation of the Standard Curve.

       1.   Pipet into clean beakers 0 (reagent blank), 10, 25, 50,
            75, 100 ml. of the standard C-34 solution.  This represents
            0, 0, 20, 0.50, 1.00, 1.50 and 2.00 parts per million of
            the biocide.

       2.   Transfer each sample, in turn, to a 1-1/2 liter round
            bottom flask and dilute to one liter with distilled water.

       3.   Continue on, starting with step (1) through step (7)
            under "Sample Procedure".

       4.   Subtract the absorbence of the reagent blank from each
            reading.

       5.   Plot absorbence against PPM C-34.

D.    Calculations.

       1.   If 1000 ml. sample
               PPM C-34 = PPM C-34 read from standard curve

       2.   If sample volume other than 1000 ml.
               PPM C-34 = (PPM C-34 from standard curve)(1000)
                                (Sample volume in mis.)

Determination of Methylene Bis Thiocyanate (Betz C-3Q) in Water

Methylene bis-thiocyanate (Betz C-30)  is converted to cyanide and thio-
cyanate by an alkaline hydrolysis.  After suitable sample cleanup the
cyanide and thiocyanate are converted  to their respective bromide com-
pounds, reacted with a pyridine - benzidine reagent and the color read
at 532 nm.  The intensity of the red color is an indirect measure of
the amount of methylene bis-thiocyanate present in the paper.  This
procedure was also provided by Betz Laboratories.

A.    Reagents and Equipment.

       1.   Arsenous acid - a 2.0% solution of arsenous acid is pre-
            pared by refluxing 2.0 gms of arsenous acid with distilled
            water until disolution is  complete.  It is then diluted
            to 100 ml.
                              60

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  2.    Bromine water - a standard solution of bromine distilled
       water.

  3.    Pyridine solution - a solution is prepared by adding 100
       ml. of concentrated hydrochloric acid to 1 liter of 60%
       pyridine in water (v/w).

  4.    Trichloroacetic acid - a solution of 20% trichloroacetic
       (w/v) in distilled water.

  5.    Benzidine De-Hydrochloride - reagent grade.

  6.    Pyridine-Benzidine Reagent - 0.2 grams of benzidine dihy-
       drochloride in 5 ml. of distilled water is added to 25 ml.
       of pyridine reagent.  This solution must be prepared
       fresh daily.

  7.    Stock "Standard Methylene Bis-Thiocyanate Solution" -
       0.200 gram of Stauffer N-948 is hydrolyzed for 60 minutes
       in 5 ml. of 20% NaOH at room temperature.  The solution is
       then filtered into a 1  liter volumetric flask and the
       filter paper is washed  several  times with 0.10 M NaOH.
       Dilute to 1 liter with  distilled water.

  8.    "Standard Methylene Bis-Thiocyanate Solution" - 10 mis. of
       stock solution is diluted to 1  liter with distilled water.
       This solution contains  a 2 micrograms of M-bis-Thiocyanate
       per mi Hi liter.

  9.    Pyridine - reagent grade.

10.   0.10 M Sodium Hydroxide (NaOH)  - Betz Code 206 or equi-
      valent.

11.   Sodium Hydroxide Solution  20% - dilute 20 gms of NaOH to
       100 ml.  with distilled  water.

12.   Hydrochloric acid -  reagent grade.

13.   n-Amyl Alcohol  - reagent grade.

14.   Filter paper - Munktell's  00  or equivalent.

15.   10 ml. Volumetric flasks.

16.   125 ml.  separatory funnels.

17.   Spectrophotometer or colorimeter -  capable  of isolating a
      reasonably  small  wavelength band at  532 manometers.
                         61

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Sample Procedure.

 1.   To 50 ml.  of sample add 10 ml.  of 0.1 NaOH and hydrolyze
      at room temperature for one hour.  The sample should be
      strongly alkaline prior to hydrolysis - if not add more
      0.1 M NaOH until  strongly basic, i.e., pH 12.

 2.   Filter the sample thru a Munktell 00 filter paper washing
      the paper two times with distilled water.

 3.   Add 5 ml.  of trichloroacetic acid followed by 3 ml.  of
      bromine water to  the filtrate.

 4.   Swirl the  beaker  contents for one minute.

 5.   Add 3 ml.  of the  arseneous acid to discharge the bromine
      color.  Blow off  any vapors of bromine above the solution.

 6.   Quantitatively transfer the contents to a clean 125  ml.
      separatory funnel and add 5 ml.  of pyridine-benzide  rea-
      gent.  Shake well and let sit 1/2 hour.

 7.   Add 5 ml.  of n-amyl alcohol and shake well.

 8.   When the phases separate drain the upper alcohol layer
      through a glass wool plug into a 10 ml. volumetric flask.
      Rinse the  funnel  several times with small portions of
      alcohol.

 9.   Dilute to make with alcohol and read the color intensity
      at 532 nanometers.  Use distilled water for the 100% T
      setting.

10.   Carry 50 ml. of the water sample through the above steps
      omitting the hydrolysis step.  This will be used as  the
      reagent - sample  blank.

11.   Subtract the absorbance of the reagent - sample blank and
      read the concentration of the M-bis-Thiocyanate from the
      standard curve.

Preparation of the Standard Curve.

 1.   Pi pet into clean  100 ml. beakers 0 (reagent blank),  1, 2,
      3, 4, and 5 ml. of the standard methylene bis-thiocyanate
      solution.   This is equivalent to 0, 2, 4, 6, 8, and 10
      micrograms of biocide.

 2.   Add 5 ml.  of the  0.1 M NaOH solution to each.
                          62

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       3.     Continue  on,  starting with step  (3) through  (14) under
             "Sample Procedure".

       4.     Subtract  the  absorbence of the reagent blank from each
             reading.

       5.     Plot  absorbence  against micrograms of methylene bis-
             thiocyanate.

 D.     Calculations.

       PPM    MBT                micrograms MBT read off of
         in           =              std. curve	.___
        water                    mi Hi liters of sample


       PPM    C-30*             PPM  MBT
         in           =
        Water                    ^5B

       * assuming  C-30 contains 5% methylene bis-thiocyanate

 E.     Comments.

       All operations  should be carried out under a hood.  None of the
       concentrated methylene bis-thiocyanate solutions should come in
       contact with acids.  All solutions should be pipetted using a
       rubber bulb, never by mouth.  Both cyanide and arsenous acid
       solutions are very poisonous and extreme care should be exercised
       when handling.

       Larger samples can be used simply by evaporating the sample to
       approximately 50 mis. only after make the solution basic to
       litmus with 0.1 N NaOH.

Determination of N-Alkyl Dimethyl Benzyl  Ammonium Chloride (Betz J-12)
in Water

A complete analytical  method for J-12 is not available.   However, an
atomic absorption method for tin in tributyl  tin oxide was used and
this was related the N-alkyl dimethyl  benzyl  ammonium chloride.   See
appendix II for product description and proportion of tributyl  tin in
J-12.

To a 50 ml. sample add with stiring,  20 ml.  perchloric-sulfuric mixture;
this is to destroy any organic matter which  may be present.   Allow to
stand  for 5 minutes and then extract  this solution with  50 ml.  of
chloroform.  The analysis may now be  completed on  the  extracted portion
using the atomic absorption method and procedures  of the Beckman
Instrument Company.
                               63

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                          APPENDIX II

              IDENTIFICATION OF TRADE NAME PRODUCTS


BIOCIDES

1.    Betz A-9.

      Sodium pentachlorophenate                              24.7%
      Sodium 2, 4, 5-trichlorophenate                         9.1%
      Sodium salts of other chlorophenates                    2.9%
      Sodium dimethyl dithiocarbamate                         4.0%
      N-Alkyl (C12-4%, (44-50%, C16-10%
         dimethyl benzyl ammonium chloride                    5.0%
      Inert ingredients (including solubilizing and
         dispersing agents)                                  54.3%

2.    Betz C-5.

      1, 3, dichloro-5, 5-dimethylhydantoin                  50  %
      Inert ingredients (including solubilizing and
         dispersing agents)                                  50  %

3.    Betz C-30.

      Bis (trichloromethyl) sulfone                          20.0%
      Methylene bisthiocyanate                                5.0%
      Inert ingredients (including solubilizing and
         dispersing agents)                                  75.0%

4.    Betz C-34.

      Sodium dimethyl dithiocarbamate                        15.0%
      Nabam(disodium ethylene  bisdithiocarbamate)             15.3%
      Inert Ingredients (including solubilizing and
         dispersing agents)                                  69.7%

5.    Betz J-12.

      N-Alkyl  (Ci2-5%, (44-60%, C16-30%,  C18-5%)
         dimethyl  benzyl  ammonium chloride                   24.0%
      Bis (tributyl tin) oxide                                  5.0%
      Inert Ingredients (including solubilizing and
         dispersing agents)                                  71.0%
                              64

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 FLOCCULANTS

  1.    Coagulant Aid 25 - A pulverized clay, off white in color.
       Calgon Corporation, Pittsburgh, Pa.

  2.    Coagulant Aid 27 - A tan pulverized clay.
       Calgon Corporation, Pittsburgh, Pa.

  3.    Coagulant Aid 225 - A cationic polyelectrolyte.
       Calgon Corporation, Pittsburgh, Pa.

  4.    Coagulant Aid 226 - A cationic polyelectrolyte.
       Calgon Corporation, Pittsburgh, Pa.

  5.    Coagulant Aid 227 - A slightly cationic polyelectrolyte.
       Calgon Corporation, Pittsburgh, Pa.

  6.    Coagulant Aid 228 - A slightly cationic polyelectrolyte.
       Calgon Corporation, Pittsburgh, Pa.

  7.    Cat-Floe - A cationic polyelectrolyte.
       Calgon Corporation, Pittsburgh, Pa.

  8.    Primafloc A-10 - An anionic polyelectrolyte.
       Rohm and Haas Company, Philadelphia, Pa.

  9.    Primafloc C-3 - A polyamine cationic polyelectrolyte.
       Rohm and Haas Company, Philadelphia, Pa.

10.    Primafloc C-5 - A polyamine cationic polyelectrolyte.
       Rohm and Haas Company, Philadelphia, Pa.

11.    Primafloc C-7 - A cationic polyamine bisulfate polyelectrolyte.
       Rohm and Haas Company, Philadelphia, Pa.

12.   Aqua-Rid 49-700 - A cationic polyamine polyelectrolyte.
       Reichhold Chemicals, Inc., Tuscaloosa, Ala.

13.   Aqua-Rid 49-702 - A polyamine polyelectrolyte.
      Reichhold Chemicals, Inc., Tuscaloosa, Ala.

14.   Aqua-Rid 49-703 - A anionic poly-aromatic polyelectrolyte.
      Reichhold Chemicals, Inc., Tuscaloosa, Ala.

15.   Aqua-Rid 49-701 - A cationic polyamine polyelectrolyte.
      Reichhold Chemicals, Inc., Tuscaloosa, Ala.

16.   Aqua-Rid 96-549 - A correctant and catalyst for use with
      49-701,  49-702,  49-703,  or 49-700  Aqua Rids.
      Reichhold Chemicals, Inc., Tuscaloosa, Ala.
                              65

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17.   Natron 86 - A cationic polyelectrolyte.
      National Starch and Chemicals Corporation, New York, N.  Y.

18.   Resyn 3285 - A anionic polyelectrolyte.
      National Starch and Chemical  Corporation, New York, N.  Y.

19.   Poly-Floe 1160 - A copolymer of acrylamide.
      Betz Laboratories, Inc., Treuose, Pa.

20.   Magnifloc 900-N - A nonionic polyacrylamide.
      American Cyanamid Company, Wayne, New  Jersey.

21.   Magnifloc 905-N - A nonionic polyacrylamide.
      American Cyanamid Company. Wayne, New  Jersey.

22.   Magnifloc 865-A - A anionic polyacrylamide.
      American Cyanamid Company, Wayne, New  Jersey.

23.   Aluminum Sulfate.
      Allied Chemical Corporation.

CARBON

 1.   Aqua Nuchar "A"
      West Virginia Pulp and Paper Company,  New York,  N.  Y.

 2.   Darco S-51.
      Atlas Chemical Industries, Inc., Wilmington,  Delaware.
                               66

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BIBLIOGRAPHIC:

     Fiber Industries, Incorporated. Reuse of Chemical Fiber Plant
Uastewater and Cooling Water Slowdown, Final Report FWQA Grant
No.  12090 EUX 10/70.

ABSTRACT:

     Demonstration studies were conducted to determine the feasibility
of reusing Industrial and domestic wastnwaters from a FORTREL Poly-
ester  manufacturing plant.  The wastewaters consisted of organic
chemical process wastes, cooling system blowdown and domestic waste-
waters  from the plant.  Selected unit processes and operations were
superimposed on an existing activated sludge system In an effort to
Improve the quality of the treated discharge.  The cooling system
bloudown was pretreated with sulfur dioxide 1n an acidic environment
to remove chromium.  The cooling water blocldes which passed through
the  chromium reduction unit were observed for their possible effect on
the  biological treatment system.- A plastic media trickling filter was
evaluated for its effectiveness as a roughing filter ahead of an acti-
vated  sludge unit.  The effluent from the secondary treatment system
was  filtered through a mtcroscreen, and treated with polymers and/or
carbon to remove color, COD, dissolved and suspended solids*

The  results of these studies Indicate that chromium can be removed
from the cooling tower blowdown for 21* per pound of chromate and that
the  type and concentration of Dlocldes normally used 1n cooling water
are  either destroyed In the chromate reduction system or exhibit no
adverse effect on the secondary and tertiary treatment system.  The
plastic media trickling filter, operated with a sludge recycle from
the  clarlfier and reduced the BOD by 401.  The 0.33 ngd Industrial
and  domestic wastewater can be treated and reused at a rate of 0.10
mgd  for approximately 40«yiOOO gallons.

This report was submitted In fulfillment of project 12090 EUX under
partial sponsorship of the Federal Water Quality Administration.
                                                                                  ACCESSION NO.
KEY WORDS:
Cool Ing Water

Chromium  Reduction

Chemical  Precipitation

Trickling Filters

Filtration

Tertiary  Traatnnt

Water  Reuse
BIBLIOGRAPHIC:

     Fiber Industries, Incorporated, Reuse of Chemical  Fiber Plant
Wasttwater and Cooling Water Slowdown, Final  Report FNQA Srant
Na. 12090 EUX 10/70.

ABSTRACT:

     Demonstration studies were conducted to determine  the feasibility
of reusing Industrial and domestic Hastfiwaters from a FORTREL Poly-
ester manufacturing plant.  The wastewaters consisted of organic
chemical process wastes, cooling -ystem blowdown and domestic waste-
waters from the plant.  Selected unit processes and operations were
superimposed on an existing activated sludge system In  an effort to
Improve the quality of the treated discharge.  The cooling system
blowdown was pretreatad with sulfur dioxide in an acidic environment
to remove chromium.  The cooling water btoctdes which passed through
the chromium reduction unit were observed for their possible effect on
the biological treatment system.  A plastic media trickling filter was
evaluated for Its effectiveness as a roughing filter ahead of an acti-
vated sludge unit.  The effluent from the secondary treatment system
was filtered through a microscreen, and treated with polymers and/or
carton to remove color, COD, dissolved and suependcd solids

The results of these studies Indicate that chromium can be  removed
from the cooling tower blowdown for 2U per pound of chronate and that
the type and concentration of blocldes normally used In cooling water
are either destroyed 1n th« chromate reduction system or exhibit no
adverse effect on the secondary and tertiary  treatment  system.   The
plastic madia trickling filter, operated with a sludge  recycle from
the clarlfier and reduced the BOD by 40X.  The 0.33 mgd Industrial
and domestic wastewater can be treated and reused at a  rate of 0.10
•gd for approximately W/1000 gallons.

This report was submitted in fulfillment of project 12090 EUX under
partial sponsorship of the Federal  Water Duality Administration.
                                                                                  ACCESSION NO.
KEY WORDS:
Cooling Water

Chromium Reduction

Chemical Precipitation

Trickling Filters

Filtration

Tertiary Treatment

Water Reuse
BIBLIOGRAPHIC:

     Fiber Industries, Incorporated, Reuse of Che«1c,al  Fiber Plant
Wastewater and Cooling Hater Blowdown, Final  Report FUQA Grant
No. 12090 EUX 10/70.

ABSTRACT:

     Demonstration studies were conducted to determine  the  feasibility
of reusing Industrial and domestic wattmeters from a FORTREL Poly-
ester Manufacturing plant.  The wastewaters consisted of organic
chemical process wastes, cooling system blowdown and domestic waste-
waters from the plant.  Selected unit processes and operations were
superimposed on an existing activated sludge system in  an effort  to
improve the quality of the treated discharge.  The cooling  system
blowdown was pretreatad with sulfur dioxide in an acidic environment
to remove chromium.  The cooling water blocldes which passed through
the chromium reduction unit were observed for their possible effect  on
the biological treatment system.  A plastic media trickling filter was
evaluated for Its effectiveness as a roughing filter ahead  of an  acti-
vated sludge unit.  The effluent from the secondary treatment system
was filtered through a microscreen. and treated with polymers and/or
carbon to remove color, COO, dissolved and suspended solids

The results of these studies Indicate that chromium can be  removed
froet the cooling tower blowdown for 2U per pound of chromate and that
the type and concentration of blocldes normally used 1n cooling water
are either destroyed in the chromate reduction system or exhibit  no
adverse effect on the secondary and tertiary treatment  system. The
plastic media trickling filter, operated with a sludge  recycle from
the clarlfier and reduced the BOD by 40*.  The 0.33 ngd Industrial
and domestic wastewater can be treated and reused at a  rate of 0.10
mgd for approximately 40(71000 gallons.

This report was submitted In fulfillment of project 12090 EUX under
partial sponsorship of the Federal Water Quality Administration.
                                                                                 ACCESSION NO.
KEY WORDS:
Cooling Water

Chromium Reduction

Chemical Precipitation

Trickling Filters

Filtration

Tertiary Treatment

Water Reuse

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      Accession Number
                               Subject Field & Group
                                   05 D
                                                   SELECTED  WATER  RESOURCES ABSTRACTS
                                                          INPUT TRANSACTION FORM
      Organization
                 Fiber Industries,  Incorporated
                 P. O. Box 10038
                 Charlotte. North Carolina 28201
      Title
                 Reuse of Chemical Fiber Plant
                 wastewater and cooling water blowdown
10

Authors)
William J.
Da/
16

21
Project Designation
FWQA 12090 EUX
Note , . . . .
In conjunction with:
                                                 Davis & Floyd Engineers,  Inc
                                                 Greenwood,  South Carolina
  22
      Citation
 23
    Descriptors (Starred First)
                 Cooling water
                 Chromium
                 Chemical Reduction
                 Chemical Precipitation
                 Trickling Filters
                                                      Tertiary Treatment
                                                      Filtration
                                                      Water Reuse
 or Identifiers (Starred First)
     Abstract  - Uemonstration studies were conducted to determine the feasibility of reusing industrial and
      domestic wastewaters from a FORTREL Polyester manufacturing plant. The wastewaters consisted of
organic chemical process wastes, cooling system blowdown and domestic wastewaters from the plant.
Selected unit processes and operations were superimposed on an existing activated sludge system in an
effort to  improve the quality of the treated discharge.  The cooling system blowdown was pretreqted with
sulfur dioxide in an acidic environment to remove the chromium. The cooling water biocides which passed
through the chromium reduction unit were observed for their possible effect on the biological treatment
system. A plastic media trickling filter was evaluated for its effectiveness as a roughing filter ahead of an
activated sludge unit. The effluent from the secondary treatment system was filtered through a microscreen,
and treated with  polymers and/or carbon to remove color, COD, dissolved and suspended solids.
        The results of these studies indicate that chormium can be removed from the cooling tower blow-
down for 21$ per pound of chromate and that  the type and concentration of biocides normally used in
cooling water are either destroyed in the chromate  reduction system or exhibit no adverse effect on the
secondary and tertiary treatment system. The  plastic media trickling filter, operated with a sludge
recycle from   the clarifier  and reduced the BOD by 40%.  The 0.33 mgd  industrial  and domestic waste-
water can be treated and reused at a rate of 0.10  mgd  for approximately 40$/1000 gals.
        This report was submitted in fulfillment of project 12090 EUX under partial sponsorship of the
Federal Water Quality Administration  •
27
Abstractor
         W. J.  Day
                                 Institution
                                        Davis & Floyd Engineers,  Inc.
  WR: 102
  WRSIC
       (REV. JUL Y 1969)
                                                 SEND TO: WATER RESOURCES SCIENTIFIC INFORMATION CENTER
                                                         U.S. DEPARTMENT OF THE INTERIOR
                                                         WASHINGTON, D. C. 20240
                                                                                       GPO: 19Q9-3B9»33g

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