U.S. ENVIRONMENTAL PROTECTION AGENCY
        NATIONAL EUTROPHICATION SURVEY
                  WORKING PAPER SERIES
                                        REPORT
                                         ON
                                       LONG LAKE
                                     HAMILTON COUNTY
                                       NEW YORK
                                     EPA REGION II
                                  WORKING PAPER No, 161
   PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY
                  An Associate Laboratory of the
      NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVALLIS, OREGON
                           and
NATIONAL ENVIRONMENTAL RESEARCH  CENTER - LAS VEGAS, NEVADA

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                                           REPORT
                                             ON
                                          LONG LAKE
                                       HAMILTON COUNTY
                                          NEW YORK
                                        EPA REGION II
                                    WORKING PAPER No,  161
              WITH THE COOPERATION OF THE
NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION
                        AND THE
                NEW YORK NATIONAL GUARD
                    DECEMBER, 1974

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                               CONTENTS
                                                           Page
  Foreword                                                  ii
  List of New York Study Lakes                              iv
  Lake and Drainage Area Map                                 v

  Sections
  I.  Conclusions                                            1
 II.  Lake and Drainage Basin Characteristics                3
III.  Lake Water Quality Summary                             4
 IV.  Nutrient Loadings                                      8
  V.  Literature Reviewed                                   13
 VI.  Appendices                                            14

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                                11
                         FOREWORD
    The National Eutrophication Survey was initiated in 1972 in
response to an Administration commitment to investigate the nation-
wide threat of accelerated eutrophication to fresh water lakes and
reservoirs.

OBJECTIVES

    The Survey was designed to develop, in conjunction with state
environmental agencies, information on nutrient sources, concentrations,
and impact on selected freshwater lakes as a basis for formulating
comprehensive and coordinated national, regional, and state management
practices relating to point-source discharge reduction and non-point
source pollution abatement in lake watersheds.

ANALYTIC APPROACH

    The mathematical and statistical procedures selected for the
Survey's eutrophication analysis are based on related concepts that:

        a.  A generalized representation or model relating
    sources, concentrations, and impacts can be constructed.

        b.  By applying measurements of relevant parameters
    associated with lake degradation, the generalized model
    can be transformed into an operational representation of
    a lake, its drainage basin, and related nutrients.

        c.  With such a transformation, an assessment of the
    potential for eutrophication control can be made.

LAKE ANALYSIS

    In this report, the first stage of evaluation of lake and water-
shed data collected from the study lake and its drainage basin is
documented.  The report is formatted to provide state environmental
agencies with specific information for basin planning [§303(e)], water
quality criteria/standards review [§303(c)]» clean lakes [§314(a,b)],
and water quality monitoring [§106 and §305(b)] activities mandated
by the Federal Water Pollution Control Act Amendments of 1972.

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                                • • *
                                m
    Beyond the single lake analysis, broader based correlations
between nutrient concentrations (and loading) and trophic condi-
tion are being made to advance the rationale and data base for
refinement of nutrient water quality criteria for the Nation's
fresh water lakes.  Likewise, multivariate evaluations for the
relationships between land use, nutrient export, and trophic
condition, by lake class or use, are being developed to assist
in the formulation of planning guidelines and policies by EPA
and to augment plans implementation by the states.

ACKNOWLEDGMENT

    The staff of the National Eutrophication Survey (Office of
Research & Development, U. S. Environmental Protection Agency)
expresses sincere appreciation to the New York Department of
Environmental Conservation for professional involvement and to
the New York National Guard for conducting the tributary sampling
phase of the Survey.

    Henry L. Diamond, Commissioner of the New York Department of
Environmental Conservation, and Leo J. Hetling, Director, and
Halo G. Carcich, Senior Sanitary Engineer, Environmental Quality
Research, Department of Environmental Conservation, provided
invaluable lake documentation and counsel during the Survey.

    Major General John C. Baker, the Adjutant General of New York,
and Project Officer Lieutenant Colonel Fred Peters, who directed
the volunteer efforts of the New York National Guardsmen, are also
gratefully acknowledged for their assistance to the Survey.

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                                IV
                  NATIONAL EUTROPHICATION SURVEY

                            STUDY LAKES

                         STATE OF NEW YORK
LAKE NAME
Allegheny Reservoir

Black
Canadaigua
Cannonsville
Carry Falls
Cassadaga
Cayuga
Champ!ain

Chautauqua
Conesus
Cross
Goodyear
Huntington
Keuka
Long
Lower St. Regis
Otter
Owasco
Raquette Pond
Round
Sacandaga Res.
Saratoga
Schroon
Seneca
Swan
Swinging Bridge Res.
COUNTY

Cattaraugas, NY; McLean,
 Warren, PA
St. Lawrence
Ontario
Delaware
St. Lawrence
Chautauqua
Seneca, Tompkins
Clinton, Essex, NY; Addison,
 Chittenden, Franklin, VT
Chautauqua
Livingston
Cayuga, Onondaga
Otsego
Sullivan
Ontario
Hanri 1 ton
Franklin
Cayuga
Cayuga
Franklin
Saratoga
Fulton, Saratoga
Saratoga
Essex, Warren
Seneca, Schyler, Yates
Sullivan
Sullivan

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        LONG  LAKE
   Tributary Sampling Site
X  Lake  Sampling Site
   Direct  Drainage Area  Boundary
            '               3 Ml.

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                             LONG  LAKE
                          STORE! NO.  3619

I.   CONCLUSIONS
    A.   Trophic  Condition:
            Survey  data  indicate that Long  Lake  is mesotrophic.  Of the
        26  New York lakes  sampled  in  the fall of 1972,  four had less mean
        total phosphorus,  only  one had  less mean dissolved phosphorus, and
        five had less mean  inorganic  nitrogen.   For  all New York data, four
        lakes had less mean chlorophyll a_,  and seven had greater Secchi disc
        transparency.
    B.   Rate-Limiting Nutrient:
            Significant  losses  of  nutrients occurred in the assay  sample
        from the time of collection to  the  beginning of the assay, and the
        results  are not  indicative of lake  conditions when the sample was
        collected.   However,  the lake data  indicate  that the lake  was limi-
        ted  by phosphorus  (i.e., N/P  ratios on all occasions were  equal to
        or  greater  than  36/1).
    C.   Nutrient Controllability:
            1.   Phosphorus  "loss"—During the sampling year, there was an
        unexpected  apparent loss of phosphorus from  Long Lake; i.e., nearly
        20%  more phosphorus  was measured leaving the lake than can be ac-
        counted  for by all  measured and estimated inputs (see page 10).
            The  cause of the  marked phosphorus imbalance is not known, but
        it  not likely that  a  phosphorus "wash-out" occurred or that a direct-
        discharge point  source  contributing 3,200 Ibs of phosphorus during

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 the year was overlooked.  Some portion of the  "loss" may have been
 due to the location of the  "outlet" sampling station some five+
 stream miles below the actual lake outlet or to the limits of accuracy
 of the flow estimates provided by the U.S. Geological Survey, or both.
    2.  Point source loads—Considering the phosphorus load leaving
 the lake to be at least equivalent to combined input loads, it is
 calculated that Long Lake received a total phosphorus load at a rate
           9
 of 0.54 g/m /yr which is less than that proposed by Vollenweider (in
 press) as "permissible"; i.e., an oligotrophic rate (see page 12).
 It will be noted that an even more favorable loading rate results
 when calculated on the basis of the input loads.
    Since the only known point-sources (shoreline septic tanks) con-
 tributed less than 2% of the estimated total phosphorus load during
 the sampling year, it is concluded that point-source control would
 have little effect on the trophic condition of Long Lake.
    3.  Non-point source loads (see page 12)--During the sampling
year, the phosphorus exports of the Long Lake tributaries were rela-
 tively low and compared favorably to the exports of unimpacted New
 York streams studied elsewhere.
    In all, it is calculated that non-point sources contributed
 nearly 99% of the total  phosphorus load to Long Lake.

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     LAKE  AND DRAINAGE  BASIN  CHARACTERISTICS
     A.  Lake Morphometry  :
        1.   Surface  area:  4,090  acres.
        2.   Mean depth:  unknown.
        3.   Maximum  depth:   >17 feet.
        4.   Volume:  unknown.
        5.   Mean hydraulic retention time:  unknown.
     B.  Tributary and  Outlet:
        (See  Appendix  A for  flow data)
    1.  Tributaries -
        Name
        Raquette River
        South Pond Outlet
        Shaw Brook
        Unnamed stream (D-l)
        Big Brook
        Cold River
        Pine Brook
        Minor tributaries &
         immediate drainage -
                     Totals
    2.  Outlet -
        Raquette River
C.  Precipitation***:
    1.  Year of sampling:  49.0 inches.
    2.  Mean annual:   40.0 inches.
                                              Drainage area* Mean flow*
191.0 mi2,
21.3 ml.
5.5 mi«
0.7 mi.
40.0 mi.
84.6 mi.
4.8 mr
116.7 mi2
381.2 cfs
42.5 cfs
11.1 cfs
1.3 cfs
79.7 cfs
168.8 cfs
9.5 cfs
245.5 cfs
                                                464.6 mi*    939.6 cfs
                                                471.0 mi2**  939.6 cfs
1" Greeson and Robison, 1970.
  Drainage areas are accurate within ±5%, except for small  basins (±10%);
  mean daily flows are accurate within ±5 to 25%; and normalized mean
  monthly flows are accurate within ±15%.
 * Includes area of lake.
 ** See Working Paper No. 1, "Survey Methods".

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III.   LAKE WATER QUALITY SUMMARY
      Long Lake was sampled three times during the open-water season
  of  1972 by means of a pontoon-equipped Huey helicopter.   Each time,
  samples for physical  and chemical  parameters were collected from
  two stations on the lake and from  two or more depths  at  each station
  (see map, page v).   During each visit, a single depth-integrated
  (15 feet or near bottom to surface)  sample was composited from the
  two stations for phytoplankton identification and enumeration; and
  during  the last visit, a single five-gallon depth-integrated sample
  was composited for  algal assays.   Also, the first two visits, a
  depth-integrated sample was collected from each of the stations for
  chlorophyll  a_ analysis.  The maximum depths sampled were 11  feet
  at  station 1  and 17 feet at station  2.
      The results obtained are presented in full in Appendix B, and
  the data for the fall  sampling period, when the lake  essentially
  was well-mixed, are summarized below.   Note, however, the Secchi
  disc summary is based on all  values.
      For differences in the various parameters at the  other sampling
  times,  refer to Appendix B.

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A.  Physical and chemical characteristics:
    Parameter               Minimum

    Temperature (Cent.)      11.6
    Dissolved oxygen (mg/1)   8.8
    Conductivity (ymhos)    <50
    pH (units)                6.6
    Alkalinity (mg/1)       <10
    Total  P (mg/1)            0.006
    Dissolved P (mg/1)         0.003
    N02 + N03 (mg/1)          0.090
    Ammonia Tmg/1)            0.060
    Secchi  disc (inches)     96
 FALL VALUES

 (10/06/72)

Mean       Median
11.7
9.0
<50
6.7
0.009
0.004
0.090
0.068
ALL VALUES
116
11.7
9.1
<50
6.7
0.008
0.004
0.090
0.070

108
Maximum

 11.9
  9.1
<50
  6.8
                        0.014
                        0.005
                        0.100
                        0.080
                      166

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B.  Biological characteristics:

    1.  Phytoplankton -
        Sampling
        Date

        05/20/72
    2.
        07/25/72
        10/06/72
Domi
nant
Genera
1.
2.
3.
4.
5.


1.
2.
3.
4.
5.


1.
2.
3.
4.
5.

Dinobryon
Peri dini urn
label! aria
Flagellates
Anabaena
Other genera
Total
Chroococcus
Merismopedia
Raphidiopsis
Flagellates
Scenedesmus
Other genera
Total
Flagellates
Chroococcus
Cyclotella
Anabaena
Melosira
Other genera
                                          Total
                                                 Number
                                                 per ml

                                                   211
                                                   175
                                                    93
                                                    51
                                                    45
                                                    34

                                                   609

                                                   265
                                                   127
                                                    66
                                                    63
                                                    45
                                                    85

                                                   651
                                                 1,613
Chlorophyll a^ -
(Because of instrumentation problems during the 1972 sampling,
the following values may be in error by plus or minus 20 percent.)
        Sampling
        Date

        05/20/72

        07/25/72
                     Station
                     Number

                       01

                       01
                       02
Chlorophyll a_
(yg/1)

    5.8

    2.3
    2.3

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C.  Limiting Nutrient Study:
        Because of nutrient loss in the sample,  the algal  assay
    results are not representative of lake  conditions  at the  time
    the sample was collected.   The lake data  indicate  that the
    lake was limited by phosphorus; i.e., N/P ratios at  all samp-
    ling times were 36/1  or greater,  and phosphorus limitation
    would be expected.

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                                  8
IV.   NUTRIENT LOADINGS
     (See Appendix C for data)
     For the determination of nutrient loadings,  the New York National
 Guard collected monthly near-surface grab samples  from each  of the
 tributary sites indicated on the map (page v), except for the high
 runoff months  of April  and May when  two samples  were collected.   Samp-
 ling was begun in November, 1972, and was completed in June, 1973.
     Through an interagency agreement, stream flow  estimates  for  the
 year of sampling and a  "normalized"  or average year were provided by
 the  New York District Office of the  U.S.  Geological  Survey for the
 tributary sites nearest the lake.
     In this report,  nutrient loads for sampled tributaries were
 determined by  using  a modification of a U.S.  Geological  Survey computer
 program for calculating stream loadings*.   Nutrient loadings for unsam-
 pled "minor tributaries and immediate drainage"  ("ZZ" of U.S.G.S.) and
 tributaries F-l  and  G-l  were estimated by using  the means  of the nu-
                        2
 trient loads,  in  Ibs/mi  /year,  in South Pond  outlet,  Shaw  Brook,  Unnamed
 Brook,  and Big  Brook at stations  B-l,  C-l,  D-l,  and E-l  and  multiplying
                                              2
 by the  ZZ or appropriate tributary area in  mi  .
     The original  outlet sampling  site  for Long Lake  was  at Axton  Landing,
 approximately  ten miles  north  of  the  actual  lake outlet  location.  One
 tributary sampled, Cold River,  does  not impact Long  Lake but does con-
 tribute to the  Raquette River  outlet  loadings.   Nutrient loadings from
* See Working Paper No. 1.

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this tributary, plus estimated loadings from the watershed surrounding
the ten miles to Axton Landing, were subtracted from the outlet loading
figures which originally had been computed by the program noted above.
    Other than septic tanks, there were no known point sources impacting
Long Lake during the sampling year.

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                                 10
    A.   Annual  Total  Phosphorus Loading - Average Year:
        1.  Inputs -
                                              IDS P/         % of
            Source                            %r	         total
            a.   Tributaries (non-point load) -
                Raquette River                 7,620          46.5
                South Pond Outlet                420           2.6
                Shaw  Brook                       420           2.6
                Unnamed Brook (D-l)               30           0.2
                Big Brook                      1,570           9.6
                Pine  Brook                       200           1.2
            b.   Minor tributaries & immediate
                 drainage (non-point load) -   5,300          32.3
            c.   Known municipal - None
            d.   Septic tanks* -                  200           1.2
            e.   Known industrial - None
            f.   Direct precipitation** -         640           3.8
                         Total                16,400         100.0
        2.  Outputs -
            Lake outlet - Raquette River      19,600
        3.  Net annual P loss - 3,200 pounds
* Estimate based on 316 lakeside residences; see Working Paper No. 1
** See Working Paper No. 1.

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                                 11
    B.   Annual  Total  Nitrogen Loading - Average Year:
        1.   Inputs -
                                              Ibs  N/         % of
            Source                            yr	         total
            a.   Tributaries (non-point load)  -
                Raquette River                654,540          44.2
                South Pond Outlet              79,620           5.4
                Shaw  Brook                     22,310           1.5
                Unnamed Brook (D-l)              3,040           0.2
                Big Brook                     156,890          10.6
                Pine  Brook                     19,180           1.3
            b.   Minor tributaries &  immediate
                 drainage (non-point load)  -   497,080          33.6
            c.   Known municipal  - None
            d.   Septic tanks* -                  7,430           0.5
            e.   Known industrial  - None
            f.   Direct precipitation** -       39,400           2.7
                         Total              1,479,490         100.0
        2.   Outputs -
            Lake outlet - Raquette River    1,422,100
        3.   Net annual N accumulation - 57,390 pounds
* Estimate based on 316 lakeside residences; see Working Paper No. 1
** See Working Paper No. 1.

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                                 12
    C.  Mean Annual Non-point Nutrient Export by Subdrainage Area:
        Tributary                             Ibs P/mi2/yr   Ibs N/mi2/yr
        Raquette River                              40           3,427
        South Pond Outlet                           20           3,738
        Shaw Brook                                  76           4.056
        Unnamed Brook (D-l)                         43           4,343
        Big Brook                                   39           3,922
    D.  Yearly Loading Rates:
            In the following table, the existing phosphorus loading
        rates, based on input loads, are compared to those proposed
        by Vollenweider (in press).  Essentially, his "dangerous"
        rate is the rate at which the receiving water would become
        eutrophic or remain eutrophic; his "permissible" rate is that
        which would result in the receiving water remaining oligotro-
        phic or becoming oligotrophic if morphometry permitted.  A
        mesotrophic rate would be considered one between "dangerous"
        and "permissible".
                                   Total  Phosphorus       Total Nitrogen
Units
Ibs/acre/yr
grams/m2/yr
Total
4.0
0.45
Accumulated
loss*
Total
361.7
40.5
Accumulated
14.0
1.6
        Vollenweider loading rates for phosphorus
         (g/m2/yr) based on surface area and mean
         outflow of Long Lake:
            "Dangerous"  (eutrophic rate)       1.36
            "Permissible"  (oligotrophic rate)  0.68
* See discussion on pages 1 and 2.

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                                 13
V.  LITERATURE REVIEWED

    Greeson, Phillip E., and F.  Luman Robison,  1970.   Characteristics
        of New York lakes.  Part 1  - Gazateer of lakes,  ponds,  and
        reservoir.  Bull. 68, U.S.  Dept.  Int. and NY  Dept.  Env.  Cons.,
        Albany.

    Vollenweider, Richard A. (in press).   Input-output models.   Schweiz,
        A. Hydro!.

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VII.  APPENDICES
                            APPENDIX A
                        TRIBUTARY FLOW DATA

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                                   TRIBUTARY FLOW INFORMATION FOR NEW YORK
                                                                       11/26/74
LAKE CODE 3619
LONG LAKE
     TOTAL DRAINAGE AREA OF LAKE   ATI.00
         SUB-DRAINAGE
TRIBUTARY    AREA
      JAN
FEB
MAR
                              APR
                        MAY
                          NORMALIZED FLOWS
                        JUN     JUL     AUG
                                                                      SEP
                                                                OCT
                                                                                      NOV
DEC
MEAN
3619AI
3619A2
3619B1
3619C1
3619D1
3619E1
3619FI
3619G1
3619ZZ
191.00
471.00
21.30
5.55
0.68
40.00
84.60
4.75
123.12
229.00
563.68
25.50
6.65
0.81
47.90
101.00
5.69
147.00
17ft. 00
437.75
19.80
5.17
0.63
37.20
78. PO
4.42
115.00
349.00
860.51
38.90
10.10
1.24
73.10
155.00
8.68
225.00
1170.00
2878.38
130.00
33.90
4.16
244.00
517.00
29.00
752.00
866.00
2138.79
96.50
25.20
3.08
181.00
384.00
21.50
558.00
336.00
828.53
37*50
9.77
1.20
70.40
149*00
8.36
217.00
183.00
450.75
20.40
5.32
0.65
38.30
81.10
4.55
118.00
153.00
377.79
17.10
4.46
0.55
32.10
68.00
3.82
98.90
185.00
455.74
20.60
5.37
0.66
38.70
81.90
4.60
119.00
264.00
651.63
29.50
7.68
0.94
55*40
117.00
6.57
170.00
371.00
915.48
41.40
10.80
1.32
77.80
164.00
9.24
239.00
288.00
710.60
32.20
8.38
1.03
60.40
128.00
7.17
186.00
381.19
939.64
42.47
11.07
1.36
79.73
168.82
9.47
245.53
                                                                   SUMMARY
                        TOTAL DRAINAGE AREA OF LAKE -    471.00
                        SUM OF SUB-DPAINAGE AREAS   =    471.00
                                                           TOTAL FLOW IN
                                                           TOTAL FLOW OUT
                                                               11269.96
                                                               11269.61
     MEAN MONTHLY FLOWS  AND DAILY FLOWS
TRIBUTARY   MONTH   YEAR
 3619A1
         MEAN FLOW  DAY
                  FLOW  DAY
                                                                     FLOW  DAY
                                                                    FLOW
 3619A2
11
12
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
4
5
6
7
8
9
10
72
72
73
73
73
73
73
73
73
73
73
73
72
72
73
73
73
73
73
73
73
73
73
73
536.00
310.00
440.00
330.00
925.00
1160.00
919.00
340.00
258.00
135.00
170.00
99.70
1320.00
764.00
1080.00
812.00
2280.00
2870.00
2270.00
839.00
637.00
335.00
419.00
246.00
4
2
5
6
4
15
5
3
14
18
7
13
4
2
6
3
3
15
5
2
7
18
8
13
617.00
326.00
632.00
740.00
110.00
370.00
865.00
420.00
133.00
120.00
132.00
89.60
1520.00
805.00
1200.00
971.00
253.00
913.00
2130.00
1210.00
746.00
297.00
351.00
221.00
                                                           18
                                                1240.00
                                                           19
                                                6130.00

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                                   TRIBUTARY FLOW INFORMATION FOR NEW YORK
                                                                                           11/26/74
LAKE CODE 3M9
                   LONG LAKE
     MEAN MONTHLY FLOWS AND DAILY FLOWS
TRIBUTARY   MONTH   YEAR    MEAN FLOW  DAY
361981
3619C1
361901
3619E1
11
12
1
•>
3
4
5
6
7
8
9
10
11
12
1
•>
3
4
5
6
7
a
9
10
11
i
?
3
4
5
6
7
8
9
10
11
12
1
?
3
4
5
6
7
8
9
10
72
72
73
73
73
73
73
73
73
73
73
73
72
72
73
73
73
73
73
73
73
73
73
73
72
73
73
73
73
73
73
73
73
73
73
72
72
73
73
73
73
73
73
73
73
73
73
FLOW  DAY
59.80
34.60
49.00
36.70
103.00
129.00
102.00
38.00
28.80
IS. 10
18.90
11.10
15.60
9.01
12.80
9.59
26.80
33.80
26.70
9.89
7.51
3.94
4.93
?.90
1.91
1.11
1.57
1.17
3.28
4.14
3.27
1.21
0.92
0.48
0.61
0.36
11?. 00
64.90
9?. 10
69.00
194.00
243.00
192.00
71.20
54.10
?«.40
35.50
?0.90
4
2
5
6
4
15
5
3
14
18
7
13
4
2
6
6
4
15
5
3
14
18
7
13
4
2
5
6
4
15
5
3
14
19
7
13
4
2
5
6
4
15
5
3
14
19
7
13
86.50
45.60
38.50
104.00
15.50
44.50
83.50
39.00
19.70
18.80
19.40
16.40
19.20
10.20
15.20
23.00
3.50
8.90
3.60
9.40
5.92
5.75
5.95
5.20
2.17
1.15
2.22
2.64
0.39
1.30
3.04
1.48
0.47
0.41
0.47
0.31
129.00
68.30
132.00
155.00
23.10
77.50
181.00
87.90
?7.90
24.60
27.70
18.70
                  FLOW  DAY
                                    FLOW
                                                          18
                115.00
                                                          18
                 17.00
                                                          16
                                                                     4.38
                                                          16
                                                                   260.00

-------
                                   TRIBUTARY FLOW INFORMATION FO* NEW YORK
                                                                        11/26/7
LAKE CODE
LONG LAKE
     MEAN MONTHLY FLOWS AND DAILY FLOWS




TRIBUTARY   MONTH   YEAR    MEAN FLOW  DAY




3619F1
3619G1
3619ZZ
11
12
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
A
S
6
7
8
9
10
11
12
1
?
3
4
5
6
7
8
9
10
72
72
73
73
73
73
73
73
73
73
73
73
72
72
73
73
73
73
73
73
73
73
73
73
72
72
73
73
73
73
73
73
73
73
73
73
                                FLOW  DAY
P37.00
138.00
194.00
146.00
411.00
515.00
407.00
151.00
114.00
60.20
75.20
44.20
13.30
7.71
10.90
8.19
23.00
28.90
22.80
8.46
6.40
3.38
4.22
2.48
345.00
200.00
283.00
213.00
596.00
749.00
592.00
?20.00
167.00
87.50
109.00
64.20
4
2
5
6
4
15
5





4
2
5
6
4
15
5





4
2
5
6
4
15
5
3
14
18
7
13
273.00
145.00
280.00
328.00
48.90
164.00
383.00





15.30
8.10
15.70
18.40
2.75
9.19
21.50





398.00
210.00
407.00
477.00
71.20
239.00
557.00
271.00
85.90
77.60
85.30
57.70
FLOW  DAY
FLOW
                                                                   551.00
                                                           18
                                                  30.90
                                                           18
                                                 802.00

-------
        APPENDIX B
PHYSICAL and CHEMICAL DATA

-------
STORET RFTRIFVAL OATF 74/11/?6
                                                                  361901
                                                                 43 58 12.0 074 26 00.0
                                                                 LONG LAKE
                                                                 36      NErt YOkK
  DATE   TIME DEPTH  WATER
  FROM    OF
   TO    DAY  FEET

7P/05/20 09 05 0000
         09 05 0011
72/07/25 1? 00 0000
         12 00 0004
         12 00 0010
72/10/10 la 14 0000
         14 14 0004
                                                                 11F.PALES
                                                                 3
 2111202
0016 FEET
DEPTH
01
ER
MP
NT
13
10

?3
?3

1 1
0



.4
,<5

>w
.7

.6
00300
DO

MG/L
9.6
9.6

7.2
6.6

«.8
00077
TRANSP
SECCHI
INCHES
99

108


96

00094
CNDUCTVY
FIELD
MICROMHO
50
50
50K
50K
50K
50K

00400
Pri

SU

5.40
7.30
7.10
7.10
6.65

00410
T ALK
CAC03
MG/L
10K
10K
10K
10K
10K
10K
10K
00630
NO?*.N03
N-TOTAL
MG/L
0.300
0.330
0.150
0.140
0.100
0.090
0.100
00610
NH3-N
TOTAL
MG/L
0.070
0.080
0.080
0.100
0.040
0.070
0.080
00665
PHOS-TOT

MG/L P
0.008
0.008
0.008
0.006
0.007
0.008
0.009
00666
PHOS-DIS

MG/L P
0.005
0.005
0.005
0.005
0.005
0.004
0.005
                       3?217
  DATE - TIME DEPTH ChLRPHYL
  FHOM    OF            A
   TO    DAY  FEET     UG/L

 7P/05/20 09 05 0000       5.8J
 7?/07/25 12 00 0000       2.3J
                 VflLUE KNOWN TO BE LESS
                 THIN INDICATED
              J  VaLUt KNO^N TO BE IN ER^OR

-------
STORET RETRIEVAL DATE  74/1l/?6
                                                                    361902
                                                                   44 02 30.0 074 21  06.G
                                                                   LONG LAKE
                                                                   36
                                                                   ll^PALES
                                                                   3
DATF
FROM
TO
7P/05/20

7?/07/?5


7?/10/10


00010
TIME DEPTH *4TER
OF TtMP
DAY FFET
09
09
11
11
11
13
13
13
34
34
40
40
40
45
45
45
0000
0017
0000
0004
0010
0000
0004
0011
CENT
13.
6.

23.
23.

11.
11.
00300
no
00077 00094
TRANSP CNDUCTVY
SECCHI FIFLO
MG/L INCHES MIC^OMHO
4
5

2
0

9
7
9.
10.

7.
7.

Q.
9.
5 120
6
108
4
4
166
1
1
50
50
50K
50K
50K
SOK
50K
SOK
00400
f H
su
5.
5.
7,
7.
7.
6.
6.
6.

40
40
80
80
80
60
70
75
                                                               8111202
                                                              00?0 FEET
                                                                                                   DEPTH
00410
T ALK
CAC03
MG/L
10K
IOK
10K
10K
10K
10K
10K
10K
00630
NOP&N03
N-TOTAL
MO/L
0.300
0.360
0.150
0.150
O.lf>0
0.090
0.090
0.090
OOMO
NH3-N
TOTAL
MG/L
0.080
0.090
0.070
0.060
0.090
0.060
0.060
0.070
0066S
PHOS-TOT

MG/L P
0.007
0.006
0.012
0.009
0.007
0.006
0.008
0.014
00666
PHOS-i>IS

MG/L P
0.004
0.005
0.008
0.005
0.006
0.005
0.003
0.003
  DATE   TIME DEPTH CHL^DHVL
  FROM    OF            A
   TO    DAY  FFFT     tir,/|_
7P/07/25 11 40 0000
2.3J
              K  VALU-  ^^JO*M  TO  dC
                       IMOICflTFt)
              J  VGLUE  Ki^OWN  TO  HE  I*

-------
  APPENDIX C
TRIBUTARY DATA

-------
STORET RETRIEVAL DATE 74/11/26
                                                                  3619A1          LS3619A1
                                                                 A3 55 30.0 074  28  30.0
                                                                 RAQUETTE RIVER
                                                                 36       15 BLUE MTN
                                                                 I/LONG LAKECHAMILTON  CO)
                                                                 BAN* OF LOT DUTY RD
                                                                 IIE^ALES              2111204
                                                                 4                   0000  FEET
DEPTH
DATE
FROM
TO
72/11/04
72/12/02
73/01/05
73/02/06
73/03/04
73/03/31
73/04/15
73/05/05
73/05/18
73/06/03
73/07/14
73/08/18
73/09/07
73/10/13
00630 00625
TIME DEPTH N02R.N03 TOT KJEL
OF N-TOTAL N
DAY FEET
11
09
10
09
10
15
09
11
19
12
14
14
16
11
15
30
40
45
30
00
30
00
00
00
00
00
30
30
MG/L
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
104
147
220
294
360
310
273
252
470
231
132
085
160
070
MG/L
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
1.
0.
230
440
730
190
270
520
630
270
400
P20
390
200
680
420
00610 00671 00665
NH3-N PHOS-DIS PHOS-TOT
TOTAL ORTHO
MG/L
0.
0.
0.
0.
0.
0.
035
024
060
036
044
023
0.014
0.
0.
0.
0.
0.
0.
0.
022
007
019
082
147
920
095
MG/L P
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.005K
.005K
.OObK
.006
.005K
.005K
.005K
.005K
.005K
.005K
.005K
.005K
.008
.005K
MG/L P
0.022
0.017
0.005K
0.006
0.010
0.005K
0.005K
0.015
0.005K
0.014
0.010
0.010
0.010
0.010
                 K  VALUE KNOW"! TO riF
                 LESS  THAN INDICATED

-------
STORE! RETRIEVAL DATE 74/H/?6
                                                                  3619A2          LS3619A2
                                                                 44 12 00.0 074 19 30.0
                                                                 RAOUETTE RIVER
                                                                 36      15 LONG LAKE
                                                                 0/LONG LAKE
-------
STORET RETRIEVAL DATE 74/11/26
                                                                  3619B1          LS3619B1
                                                                 43 56 00.0  074  28  00.0
                                                                 SOUTH POND  OUTLET
                                                                 36       IS  BLUE MTN
                                                                 T/LONG LK(HAMILTON CO)
                                                                 MFD DUTY RD BROG IN  DEERLANO
                                                                 11EPALES              2111204
                                                                 4                    0000  FEET
DEPTH
DATE
FROM
TO
72/11/04
72/12/02
73/02/06
73/03/04
73/03/31
73/04/15
73/05/05
73/05/18
73/06/03
73/0 7/1 A
73/08/18
73/09/07
73/10/13
00630 00625
TIME DEPTH N02&N03 TOT KJEL
OF N-TOTAL N
DAY FEET
11
09
10

15
09
11
19
12
14
12
16
13
40
45
04

00
30
00
00
00
30
00
30
00
MG/L
0,
0,
0,
0,
0,
0,
0.
0,
0,
0,
0,
0,
0,
,117
,280
,5^0
,690
,730
,720
,540
,470
,440
.250
,170
,147
,126
MG/L
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
230
310
200
050
300
840
660
600
940
210
660
540
690
00610 00671 00665
NH3-N PHOS-DIS PHOS-TOT
TOTAL ORTHO
MG/L
0
0
0
0
0
0
0
0
0
0
0
0
0
•
•
•
•
•
•
*
•
•
•
•
*
•
075
038
094
083
032
033
012
018
023
039
126
120
240
MG/L P MG/L P
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.005K
0.006
0.005
0.005K
0.005K
0.005K
0.005
0.005K
0.005K
0.005K

0.005K
0.005K
                        K  VALUE KNOWM  TO  <-<£
                        LFSS  TH;\fg

-------
STORET RETRIEVAL DATE 74/1l/?6
                                                                  3619C1          LS3619C1
                                                                 43 58 00.0 074 25 30.0
                                                                 SHAW BROOK
                                                                 36      15 BLUE MTN
                                                                 T/LONG LAKE(HAMILTON C0>
                                                                 ST HWY 30 8RDG IN LONG LAKE
                                                                 11EPALES             2111204
                                                                 4                   0000 FEET
DATE
FROM
TO
72/11/04
72/12/02
73/01/06
73/02/06
73/03/04
73/03/31
73/04/15
73/05/05
73/05/18
73/06/03
73/07/14
73/08/18
73/09/07
73/10/13
00630 00625
TIME DEPTH N02S.N03 TOT KJFL
OF N-TOTAL N
DAV FEET
13
11
10
10
10
14
10
11
19
12
14
13
16
11
15
15
50
15
15
30
00
00
00
00
00
00
00
00
MG/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.260
.357
.480
.510
.440
.440
.370
.280
.340
.180
.154
.168
.120
.132
MG/L
0.270
0.540
0.420
1.050
0.420
0.240
1.050
0.585
0.630
1.100
0.450
1.000
1.980
0.540
00610 00671 00665
NH3-N PHOS-DIS PHOS-TOT
TOTAL ORTHO
MG/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
•
•
•
•
•
•
•
*
•
•
•
•
•
*
069
110
056
080
100
054
069
029
016
052
050
044
730
105
MG/L
0.
0.
0.
C.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
p
005K
Oil
006
007
008
005K
005K
006
005K
007
005K
006
006
005K
MG/L P
0.010
0.018
0.009

0.020
0.020
0.025
0.015
0.010
0.015
0.025
0.020
0.030
0.035
                                                                            DEPTH
K
LESS
                             KNOWN TO ar;

-------
STORE! RETRIEVAL DATE 74/11/26
                                                                   361901           LS3619D1
                                                                  43  59  30.0  074 24 00.0
                                                                  UNNAMED  CREEK
                                                                  36       15  SLUE MTN
                                                                  T/LONG LAKE

-------
STORET RETRIEVAL DATE 74/11/26
                                                                  3619E1          LS3619E1
                                                                 44 00 00.0 074 29 00.0
                                                                 BIG BROOK
                                                                 36      15 LONG LAKE
                                                                 T/LONG LAKE(HAMILTON CO)
                                                                 ST HWY 10 8RDG
                                                                 11EPALES             2111204
                                                                 4                   0000 FEET  DEPTH
DATE
FROM
TO
72/11/04
72/12/02
73/01/05
73/0?/06
73/03/04
73/04/01
73/04/15
73/05/05
73/05/18
73/06/03
73/07/14
73/08/19
73/09/07
73/10/13
00630 00625
TIME DEPTH N02^N03 TOT KJEL
OF N-TOTAL N
DAY FEET
16
11
14
10
11
10
10
11
19
14
09
15
16
10
00
30
00
30
00
00
15
00
00
00
00
00
00
00
MG/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.091
.ISO
.315
.380
.430
.378
.320
.010*
.190
.231
.0^6
.044
.036
.066
MG/L
0
0
0
0
0
0
0
0
0
1
0
1
1
1
.340
.720
.440
.230
.370
.520
.880
.560
.580
.400
.540
.600
.850
.320
00610 00671 00665
NH3-N PHOS-DIS PHOS-TOT
TOTAL ORTHO
MG/L
0.
0.
0.
0.
0.
0.
0.
063
038
039
038
061
019
050
0.011
0.
0.
0.
0.
0.
0.
016
029
066
054
840
590
MG/L
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
P
005K
005K
005K
005K
005K
005K
005K
005K
005K
005K
005K
005K
005K
006
MG/L P
0.007
0.005K
0.010
0.010
0.010
0.020
0.005K
0.005K
0.010
0.010
0.015
0.010
0.015
0.010
               K VALUE KNOrtN TO HE
               LESS THAN

-------
STORE! RETRIEVAL DATE 74/11/26
                      00630
  DATE   TIME DEPTH NO?f.N03
  FROM    OF        N-TOTAL
   TO    DAY  FEET    MG/L
72/11/04 14 35
0.480
                                                                   3619F1          LS3619F1
                                                                 44 05 30.0  074  16  00.0
                                                                 COLD RIVER
                                                                 36       15  LONG LAKE
                                                                 T/LONG LAKE(HAMILTON  CO)
                                                                 WOLF LAKE RO  8ROG
                                                                 11EPALES              2111204
                                                                 4                  0000 FEET
                                                                         DEPTH
00625
TOT KJEL
N
MG/L
0.120
00610
NH3-N
TOTAL
MG/L
0.034
00671
PHOS-DIS
ORTHO
MG/L P
0.005K
00665
PHOS-TOT
MG/L P
0.005K
                          K  y/flLUF  KNOWN  TO  P£
                          LESS  TH/sN  INDICATED

-------
STORET RETRIEVAL DATE 74/11/26
                      00630
  DATE   TIME DEPTH N02S.N03
  FROM    OF        N-TOTAL
   TO    DAY  FEET    MG/L
72/11/04 15 00
0 , 19-R
  006?«5
TOT KJEL
   N
  MG/L

   0.325
 00610
NH3-N
TOTAL
 MG/L

  0.053
                                                                  3619G1          LS3619G1
                                                                 44 04 00.0 074 15 30.0
                                                                 PINE BROOK
                                                                 36      IS LONG LAKE
                                                                 T/LONG LAKE(HAMILTON C0>
                                                                 WOLF LAKE RD BRDG
                                                                 11EPALES             2111204
                                                                 ^                   0000 FEET
                                                                         DEPTH
  00671
PHOS-DIS
 ORTHO
 MG/L P

   0.005K
  00665
PHOS-TOT

 MG/L P

   0.007
                     K VALUE KNOWN in HE
                     LESS  THAN  INDICATED

-------