U.S. ENVIRONMENTAL PROTECTION AGENCY NATIONAL EUTROPHICATION SURVEY WORKING PAPER SERIES REPORT ON OTTER LAKE CAYUGA COUNTY NEW YORK EPA REGION II WORKING PAPER No, 164 PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY An Associate Laboratory of the NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVAILIS, OREGON and NATIONAL ENVIRONMENTAL RESEARCH CENTER - LAS VEGAS, NEVADA ------- REPORT ON OTTER LAKE CAYUGA COUNTY NEW YORK EPA REGION II WORKING PAPER No, 164 WITH THE COOPERATION OF THE NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION AND THE NEW YORK NATIONAL GUARD DECEMBER, 1974 ------- CONTENTS Page Foreword 1i List of New York Study Lakes 1v Lake and Drainage Area Map v Sections I. Conclusions 1 II. Lake and Drainage Basin Characteristics 3 III. Lake Water Quality Summary 4 IV. Nutrient Loadings 8 V. Literature Reviewed 12 VI. Appendices 13 ------- 11 FOREWORD The National Eutrophication Survey was initiated in 1972 in response to an Administration commitment to Investigate the nation- wide threat of accelerated eutrophlcation to fresh water lakes and reservoirs. OBJECTIVES The Survey was designed to develop, in conjunction with state environmental agencies, information on nutrient sources, concentrations, and Impact on selected freshwater lakes as a basis for formulating comprehensive and coordinated national, regional, and state management practices relating to point-source discharge reduction and non-point source pollution abatement in lake watersheds. ANALYTIC APPROACH The mathematical and statistical procedures selected for the Survey's eutrophlcation analysis are based on related concepts that: a. A generalized representation or model relating sources, concentrations, and impacts can be constructed. b. By applying measurements of relevant parameters associated with lake degradation, the generalized model can be transformed into an operational representation of a lake, its drainage basin, and related nutrients. c. With such a transformation, an assessment of the potential for eutrophication control can be made. LAKE ANALYSIS In this report, the first stage of evaluation of lake and water- shed data collected from the study lake and its drainage basin is documented. The report is formatted to provide state environmental agencies with specific information for basin planning [§303(e)l, water quality criteria/standards review [§303(c)L clean lakes [§314(a,b)], and water quality monitoring [§106 and §305(b}] activities mandated by the Federal Water Pollution Control Act Amendments of 1972. ------- ill Beyond the single lake analysis, broader based correlations between nutrient concentrations (and loading) and trophic condi- tion are being made to advance the rationale and data base for refinement of nutrient water quality criteria for the Nation's fresh water lakes. Likewise, multivariate evaluations for the relationships between land use, nutrient export, and trophic condition, by lake class or use, are being developed to assist in the formulation of planning guidelines and policies by EPA and to augment plans implementation by the states. ACKNOWLEDGMENT The staff of the National Eutrophication Survey (Office of Research & Development, U. S. Environmental Protection Agency) expresses sincere appreciation to the New York Department of Environmental Conservation for professional involvement and to the New York National Guard for conducting the tributary sampling phase of the Survey. Henry L. Diamond, Commissioner of the New York Department of Environmental Conservation, and Leo J. Hetling, Director, and Italo G. Carclch, Senior Sanitary Engineer, Environmental Quality Research, Department of Environmental Conservation, provided invaluable lake documentation and counsel during the Survey. Major General John C. Baker, the Adjutant General of New York, and Project Officer Lieutenant Colonel Fred Peters, who directed the volunteer efforts of the New York National Guardsmen, are also gratefully acknowledged for their assistance to the Survey. ------- IV NATIONAL EUTROPHICATION SURVEY STUDY LAKES STATE OF NEW YORK LAKE NAME Allegheny Reservoir Black Canadaigua Cannonsvilie Carry Falls Cassadaga Cayuga Champlain Chautauqua Conesus Cross Goodyear Huntington Keuka Long Lower St. Regis Otter Owasco Raquette Pond Round Sacandaga Res. Saratoga Schroon Seneca Swan Swinging Bridge Res COUNTY Cattaraugas, NY; McLean, Warren, PA St. Lawrence Ontario Delaware St. Lawrence Chautauqua Seneca, Tompkins Clinton, Essex, NY; Addison, Chittenden, Franklin, VT Chautauqua Livingston Cayuga, Onondaga Otsego Sullivan Ontario Kami 1 ton Franklin Cayuga Cayuga Franklin Saratoga Fulton, Saratoga Saratoga Essex, Warren Seneca, Schyler, Yates Sullivan Sullivan ------- OTTER LAKE ® Tributary Sampling Site x Lake Sampling Site f Direct Drainage Area Boundary V2Mi. Scale "X/ 43-07 — 76-33' 76'31 ------- OTTER LAKE STORET NO. 3625 I. CONCLUSIONS A. Trophic Condition: Survey data show that Otter Lake 1s eutrophic. Of the 26 New York lakes sampled in the fall of 1972, when essentially all were well-mixed, 18 had less mean total phosphorus, 11 had less mean dissolved phosphorus, and 10 had less mean In- organic nitrogen. For all New York data, 20 lakes had less mean chlorophyll a_, and 24 had greater mean SeccM disc trans- parency. Survey limnologists noted turbid water on all sampling dates with moderate algae blooms 1n progress during the July and October sampling periods. B. Rate-Limiting Nutrient: The results of the algal assay Indicate phosphorus limitation at the time the sample was collected. The lake data also Indicate phosphorus limitation at all sampling times; I.e., N/P ratios were greater than 20/1, and phosphorus limitation would be expected. C. Nutrient Controllability: During the sampling year, there was an apparent loss of phos- phorus from Otter Lake; I.e., more phosphorus was measured leaving the lake than can be accounted for by all measured and estimated ------- Inputs. The cause of the Imbalance 1s not known, but It Is unlikely that phosphorus "wash-out" occurred or that a direct- discharge point source was overlooked. Considering the rather small phosphorus loads involved (see page 9), the imbalance could have been due to the accuracy of the flow estimates provided by the U.S. Geological Survey (see page 3). Considering the phosphorus load leaving the lake to be at least equivalent to the input loads, it is calculated that Otter Lake received a total phosphorus load at a rate approximately that proposed by Vollenweider (in press) as "permissible"; i.e., an oligotrophic rate (see page 11). However, in view of the eutrophic condition of the lake, the calculated loading rate is likely in error. There are no known point sources impacting the lake, and the entire phosphorus load was contributed by non-point sources. ------- II. LAKE AND DRAINAGE BASIN CHARACTERISTICS A. Lake Morphometry: t 1. Surface area: 282 acres : 2. Mean depth: unknown 3. Maximum depth: unknown 4. Volume: unknown B. Tributary and Outlet: (See Appendix A for flow data) 1. Tributaries - Name Unnamed Creek (B-l) Minor tributaries & immediate drainage - Totals 2. Outlet - Unnamed Creek (A-l) C. Precipitation: 1. Year of sampling***: 52.8 inches. 2. Mean annual: 37.6 inches. Drainage area* Mean flow* ,2 0.4 mi' 2.1 mi' 2.5 mi' 0.5 cfs 3.3 cfs 3.8 cfs 2.9 mic** 3.8 cfs t Greeson and Robison, 1970. * Drainage areas are accurate within ±5%, except for small basins (±10%); mean daily flows are accurate within ±5 to 25%; and normalized mean monthly flows are accurate within ±15%. ** Includes area of lake. *** See Working Paper No. 1, "Survey Methods". ------- 4 III. LAKE WATER QUALITY SUMMARY Otter Lake was sampled three times during the open-water season of 1972 by means of a pontoon-equipped Huey helicopter. Each time, samples for physical and chemical parameters were collected from two depths at a single station on the lake (see map, page v). During each visit, a depth-Integrated (near bottom to surface) sample was col- lected for phytoplankton Identification and enumeration; and during the last visit, a five-gallon depth-integrated sample was collected for algal assays. Also each time, a depth-integrated sample was col- lected for chlorophyll a_ analysis. The maximum depth sampled was 6 feet. The results obtained are presented in full in Appendix B, and the data for the fall sampling period, when the lake essentially was well- mixed, are summarized below. Note, however, the Secchi disc summary is based on all values. For differences in the various parameters at the other sampling times, refer to Appendix B. ------- A. Physical and chemical characteristics: Parameter Minimum Temperature (Cent.) 11.2 Dissolved oxygen (mg/1) 10.4 Conductivity (vimhos) 265 pH (units) 8.2 Alkalinity (mg/1) 129 Total P (mg/1) 0.027 Dissolved P (mg/1) 0.009 N0« + NO- (mg/1) 0.100 Ammonia fmg/1) 0-130 FALL VALUES (10/13/72) Mean Median Maximum 11.2 10.4 268 8.2 130 0.044 0.010 0.105 0.130 11.2 10.4 268 8.2 130 0.044 0.010 0.105 0.130 11.2 10.4 270 8.2 131 0.061 0.012 0.110 0.130 ALL VALUES Secchi disc (inches) 24 45 41 70 ------- B. Biological characteristics: 1. Phytoplankton - Sampling Date 05/17/72 07/24/72 10/13/72 Domi nant Genera 1. Fragilarla 2 . Di nobryon 3 . Lyngbya 4. Cyclotella 5. Flagellates Other genera Total 1 . Lyngbya 2. Polycystis 3. Fragilaria 4 . Chroococcus 5. Melosira Other genera Total 1 . Lyngbya 2 . Synedra 3. Chroococcus 4. Flagellates 5. Oscillatoria Other genera Total 2. Chlorophyll a - (Because of Instrumentation problems during the following values may be in error by plus Sampl 1 ng Date 05/17/72 07/24/72 10/13/72 Station Number 01 01 01 Number per ml 904 754 497 482 113 468 3,218 14,130 6,812 3,333 978 580 1,377 27,210 16,616 2,632 2,481 1,278 1,278 2,783 27,068 the 1972 sampling, or minus 20 percent.) Chlorophyll a (ug/1 ) 4.6 15.6 19.8 ------- 0.007 0.017 0.027 0.057 0.057 0.057 0.007 0.125 0.125 0.125 0.125 5.125 10.125 10.125 1.1 3.1 3.8 4.2 18.5 18.4 0.3 C. Limiting Nutrient Study: 1. Autoclaved, filtered, and nutrient spiked - Ortho P Inorganic N Maximum yield Spike (mg/1) Cone, (mg/1) Cone, (mg/1) (mg/1-dry wt.) Control 0.010 P 0.020 P 0.050 P 0.050 P + 5.0 N 0.050 P + 10.0 N 10.0 N 2. Discussion - The control yield of the assay alga, Selenastrum capri- cornutum, indicates that the potential primary productivity of Otter Lake was moderate at the time the algal assay sam- ple was collected. The addition of orthophosphorus (to about 20 yg/1) pro- duced significant Increases in the assay yield. However, the addition of only nitrogen did not produce a significant response in yield as compared to the control yield, thus Indicating phosphorus limitation at the time the sample was collected. The lake data also Indicate phosphorus limitation at all sampling times; N/P ratios were greater than 20/1, and phosphorus limitation would be expected. ------- 8 IV. NUTRIENT LOADINGS (See Appendix C for data) For the determination of nutrient loadings, the New York National Guard collected monthly near-surface grab samples from each of the tribu- tary sites Indicated on the map (page v), except for the high runoff months of March and April when two samples were collected. Sampling was begun in November, 1972, and was completed In June, 1973. Through an Interagency agreement, stream flow estimates for the year of sampling and a "normalized" or average year were provided by the New York District Office of the U.S. Geological Survey for the tributary sites nearest the lake. In this report, nutrient loads for sampled tributaries were deter- mined by using a modification of a U.S. Geological Survey computer program for calculating stream loadings*. Nutrient loadings for unsam- pled "minor tributaries and immediate drainage" ("ZZ" of U.S.G.S.) were 2 estimated using the means of the nutrient loads, in Ibs/mi /year, at 2 station B-l and multiplying the means by the ZZ area in mi . There are no known point sources affecting Otter Lake. A. Waste Sources: 1. Known municipal - None 2. Known Industrial - None * See Working Paper No. 1. ------- B. Annual Total Phosphorus Loading - Average Year: 1. Inputs - IDS P/ % of Source y_r total a. Tributaries (non-point load) - Unnamed Creek (B-l) 20 11.1 b. Minor tributaries & immediate drainage (non-point load) - 110 66.7 c. Known municipal - None d. Septic tanks - Unknown e. Known industrial - None f. Direct precipitation* - 40 22.2 Total 170 100.0 2. Outputs - Lake outlet - Unnamed Creek (A-l) 390 3. Net annual P loss - 210 pounds See Working Paper No. 1. ------- 10 C. Annual Total Nitrogen Loading - Average Year: 1 . Inputs - Ibs N/ % of Source r total a. Tributaries (non-point load) - Unnamed Creek (B-l) 2,180 12.6 b. Minor tributaries & immediate drainage (non-point load) - 11,440 71.7 c. Known municipal - None d. Septic tanks - Unknown e. Known industrial - None f. Direct precipitation* - 2,720 15.7 Total 16,340 100,0 2. Outputs - Lake outlet - Unnamed Creek {A-l ) 14,110 3. Net annual N accumulation - 2,230 pounds See Working Paper No. 1, ------- 11 D. Mean Annual Non-point Nutrient Export by Subdrainage Area: Tributary Ibs P/mi2/yr Ibs N/mi2/yr Unnamed Creek (B-l) 50 5,450 E. Yearly Loading Rates: In the following table, the existing phosphorus loading rates are compared to those proposed by Vollenweider (in press). Essentially, his "dangerous" rate is the rate at which the receiving water would become eutrophic or remain eutrophic; his "permissible" rate is that which would result in the receiving water remaining oligotrophic or becoming oligotrophic if morphometry permitted. A mesotrophic rate would be consid- ered one between "dangerous" and "permissible". Total Phosphorus Total Nitrogen Units 1 bs/acre/yr grams/m2/yr Total 1.4 0.16 Accumulated loss Total 57.9 6.5 Accumulated 7.9 0.9 Vollenweider loading rates for phosphorus (g/m2/yr) based on the surface area and mean outflow of Otter Lake: "Dangerous" (eutrophic rate) 0.34 "Permissible" (oligotrophic rate) 0.17 ------- 12 V. LITERATURE REVIEWED Greeson, Phillip E., and F. Luman Robison, 1970. Characteristics of New York lakes. Part 1 - Gazateer of lakes, ponds, and reservoirs. Bull. 68, U.S. Dept. Int. and NY Dept. of Env. Cons., Albany. Vollenweider, Richard A. (1n press). Input-output models. Schweiz, A. Hydrol. ------- 13 VII. APPENDICES APPENDIX A TRIBUTARY FLOW DATA ------- TRIBUTARY FLOW INFORMATION FOR NEW YORK 11/26/74 LAKE CODE 3625 OTTER LAKE TOTAL DRAINAGE AREA OF LAKE 2.91 SUB-DRAINAGE TRIBUTARY AREA 3625A1 3625B1 3625ZZ 2.91 0.37 2.54 JAN 4.00 0.50 3.50 FEB 5.90 0.70 5.20 MAR 12.00 1.40 11.00 APR 9.20 1.10 a.10 TOTAL DRAINAGE AREA OF LAKE SUM OF SUB-DRAINAGE AREAS MEAN MONTHLY FLOWS AND DAILY FLOWS TRIBUTARY MONTH YEAR MEAN FLOW DAY 3625A1 3625B1 3625ZZ 11 1? 2 3 4 5 6 7 8 9 11 12 2 3 4 5 6 7 8 9 11 1? 1 ? 3 4 5 6 7 8 9 72 72 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 73 A.OO 12.00 8.80 13.00 12.00 4.80 2.20 0.60 0.30 0.20 1.00 1.60 1.00 1.50 1.40 0.50 0.30 0.10 0.10 0.0 6.90 11.00 9.20 7.70 12.00 11*00 4.30 1.90 0.50 0.20 0.20 4 2 3 3 13 31 9 23 25 15 4 2 3 3 13 31 9 23 25 15 MAY 3.60 0.40 3.20 NORMALIZED FLOWS JUN JUL AUG 1.60 0.20 1.40 0.70 0.10 0.60 0.30 0.10 0.20 SEP 0.50 0.10 0.40 OCT 1.00 0.10 0.90 NOV 3.10 0.40 2.70 DEC 3.90 0.50 3.40 MEAN 3.60 0.46 3.37 SUMMARY 2.91 2.91 FLOW DAY , TOTAL FLOW IN TOTAL FLOW OUT 46.20 45.80 5.10 8.60 32.00 4.00 6.50 3.20 2.10 0.30 0.30 0.10 0.60 1.10 3.90 .50 .80 .40 .30 .0 0.0 0.0 31 29 31 29 FLOW DAY 3.60 9.20 FLOW 0.40 1.00 ------- APPENDIX B PHYSICAL and CHEMICAL DATA ------- STORE! RETRIEVAL DATE 74/11/26 362501 43 08 24.0 076 32 02.0 OTTER LAKE 36 NEW YORK 00010 00300 00077 00094 DATE TIME DEPTH WATER DO TRANSP CNDUCTVY FROM OF TEMP SECCHI FIELD TO DAY FEET CENT MG/L INCHES MICROMHO 72/05/17 18 25 0000 17.7 9.3 70 340 18 25 0006 17.7 7.8 260 72/07/24 17 50 0000 41 280 72/10/13 15 35 0000 24 270 15 35 0004 11.2 10.4 265 HEPALES 3 00400 PH SU 8.00 8.10 8.60 8.20 8.20 00410 T ALK CAC03 MG/L 118 122 115 131 129 2111202 0010 00630 N02&N03 N-TOTAL MG/L 0.340 0.340 0.100 0.110 0.100 FEET DEPTH 00610 NH3-N TOTAL MG/L 0.310 0.350 0.090 0.130 0.130 00665 PHOS-TOT MG/L P 0.025 0.233 0.043 0.027 0.061 00666 PHOS-DIS MG/L P 0.011 0.012 0.008 0.009 0.012 32217 DATE TIME DEPTH CHLRPHYL FROM OF A TO DAY FEET UG/L 72/05/17 18 25 0000 4.6J 72/07/24 17 50 0000 15.6J 72/10/13 15 35 0000 19.8J J VALUE KNOWN TO BE IN ERROR ------- APPENDIX C TRIBUTARY DATA ------- STORE! RETRIEVAL DATE 74/11/26 3625A1 LS3625A1 43 09 30.0 076 33 00,0 UNNAMED CREEK 36 7.5 CATO 0/OTTER LAKE SHORT CUT ROAD 1 Ml SW OF MERIDIAN 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/02 73/02/03 73/03/03 73/03/31 73/04/13 73/04/29 73/05/31 73/06/09 TIME DEPTH OF DAY FEET 09 45 14 15 12 28 14 00 15 50 15 35 12 15 19 30 12 10 00630 NO?&N03 N-TOTAL MG/L 0.195 0.490 0.420 0.870 0.154 0.100 0.034 0.060 0.013 00625 TOT KJF.L N MG/L 0.660 0.520 0.820 3.360 1.890 0.840 0.810 1.980 3.200 00610 NH3-N TOTAL MG/L 0.094 0.032 0.069 0.220 0.066 0.042 0.138 0.074 0.115 00671 PHOS-DIS OPT HO MG/L P 0.066 0.010 0.008 0.008 0.009 0.005K 0.022 0.033 0.080 00665 PHOS-TOT MG/L P 0.090 0.030 0.025 0.030 0.055 0.025 0.045 0.050 0.095 LESS TH3N INDICATE.) ------- STORET RETRIEVAL DATE 74/11/36 3IS25B1 LS3625B1 43 08 30.0 076 31 30.0 UNNAMED CREEK 36 7.5 CATO T/OTTER LAKE AT BONTA BRIDGE ROAD BRIDGE 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/0? 73/02/03 73/03/03 73/03/31 73/04/13 73/05/31 73/06/09 TIME DEPTH OF DAY FEET 09 20 14 30 12 20 10 50 14 00 15 45 15 23 19 40 12 00 00630 N02&N03 N-TOTAL MG/L 2.400 1.660 1.960 2.300 2.040 1.000 1.140 1.000 1.720 00625 TOT KJEL N MG/L 1.000 0.260 0.400 0.390 0.580 0.440 0.790 1.260 0.380 00610 NH3-N TOTAL MG/L 0.058 0.010 0.039 0.031 0.036 0.027 0.033 0.030 0.033 00671 PHOS-DIS ORTHO MG/L P 0.008 0.005K 0.011 0.008 0.017 0.005K 0.006 0.005K 0.020 00665 PHOS-TOT MG/L P 0.018 0.014 0.050 0.050 0.017 0.015 0.010 0.010 0.020 K VALUE KNOW TO dŁ LE5S THflN INDICATED ------- |