U.S. ENVIRONMENTAL PROTECTION AGENCY NATIONAL EUTROPHICATION SURVEY WORKING PAPER SERIES REPORT ON ROUND LAKE SARATOGA COUNTY NEW YORK EPA REGION II WORKING PAPER No, 166 PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY An Associate Laboratory of the NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVALLIS, OREGON and NATIONAL ENVIRONMENTAL RESEARCH CENTER - LAS VEGAS, NEVADA ------- REPORT ON ROUND LAKE SARATOGA COUNTY NEW YORK EPA REGION II WORKING PAPER No, 166 WITH THE COOPERATION OF THE NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION AND THE NEW YORK NATIONAL GUARD DECEMBER, 1974 ------- CONTENTS Page Foreword i i List of New York Study Lakes 1v Lake and Drainage Area Map v Sections I. Conclusions 1 II. Lake and Drainage Basin Characteristics 3 III. Lake Water Quality Summary 4 IV. Nutrient Loadings 8 V. Literature Reviewed 13 VI. Appendices 14 ------- ii FOREWORD The National Eutrophication Survey was initiated in 1972 in response to an Administration commitment to investigate the nation- wide threat of accelerated eutrophication to fresh water lakes and reservoirs. OBJECTIVES The Survey was designed to develop, in conjunction with state environmental agencies, information on nutrient sources, concentrations, and impact on selected freshwater lakes as a basis for formulating comprehensive and coordinated national, regional, and state management practices relating to point-source discharge reduction and non-point source pollution abatement in lake watersheds. ANALYTIC APPROACH The mathematical and statistical procedures selected for the Survey's eutrophication analysis are based on related concepts that: a. A generalized representation or model relating sources, concentrations, and impacts can be constructed. b. By applying measurements of relevant parameters associated with lake degradation, the generalized model can be transformed into an operational representation of a lake, its drainage basin, and related nutrients. c. With such a transformation, an assessment of the potential for eutrophication control can be made. LAKE ANALYSIS In this report, the first stage of evaluation of lake and water- shed data collected from the study lake and its drainage basin is documented. The report is formatted to provide state environmental agencies with specific information for basin planning [§303(e)], water quality criteria/standards review [§303(c)], clean lakes [§314(a,b)], and water quality monitoring [§106 and §305(b)] activities mandated by the Federal Water Pollution Control Act Amendments of 1972. ------- iii Beyond the single lake analysis, broader based correlations between nutrient concentrations (and loading) and trophic condi- tion are being made to advance the rationale and data base for refinement of nutrient water quality criteria for the Nation's fresh water lakes. Likewise, multivariate evaluations for the relationships between land use, nutrient export, and trophic condition, by lake class or use, are being developed to assist in the formulation of planning guidelines and policies by EPA and to augment plans implementation by the states. ACKNOWLEDGMENT The staff of the National Eutrophication Survey (Office of ' Research & Development, U. S. Environmental Protection Agency) expresses sincere appreciation to the New York Department of Environmental Conservation for professional involvement and to the New York National Guard for conducting the tributary sampling phase of the Survey. Henry L. Diamond, Commissioner of the New York Department of Environmental Conservation, and Leo J. Hetling, Director, and Italo G. Carcich, Senior Sanitary Engineer, Environmental Quality Research, Department of Environmental Conservation, provided invaluable lake documentation and counsel during the Survey. Major General John C. Baker, the Adjutant General of New York, and Project Officer Lieutenant Colonel Fred Peters, who directed the volunteer efforts of the New York National Guardsmen, are also gratefully acknowledged for their assistance to the Survey. ------- IV NATIONAL EUTROPHICATION SURVEY STUDY LAKES STATE OF NEW YORK LAKE NAME Allegheny Reservoir Black Canadaigua Cannonsville Carry Falls Cassadaga Cayuga Champ!ain Chautauqua Conesus Cross Goodyear Huntington Keuka Long Lower St. Regis Otter Owasco Raquette Pond Round Sacandaga Res. Saratoga Schroon Seneca Swan Swinging Bridge Res. COUNTY Cattaraugas, NY; McLean, Warren, PA St. Lawrence Ontario Del aware St. Lawrence Chautauqua Seneca, Tompkins Clinton, Essex, NY; Addison, Chittenden, Franklin, VT Chautauqua Livingston Cayuga, Onondaga Otsego Sullivan Ontario Hami1 ton Franklin Cayuga Cayuga Franklin Saratoga Fulton» Saratoga Saratoga Essex, Warren Seneca, Schyler, Yates Sullivan Sullivan ------- New York Map Location ® Tributary Sampling Site X Lake Sampling Site £ Sewage Treatment Facility s\ Direct Drainage Area Limits Sit Indirect Drainage Area "Mi. Scale Ft outlet 4 2 ° 5 5 " — 73 51 73°47' ------- ROUND LAKE STORET NO. 3630 I. CONCLUSIONS A. Trophic Condition: Survey data indicate that Round Lake is eutrophic. Of the 26 New York lakes sampled in the fall of 1972, 24 had less mean total phosphorus, 23 had less mean dissolved phos- phorus, and 19 had less inorganic nitrogen. For all New York data, 23 lakes had less mean chlorophyll a_, and 23 had greater Secchi disc transparency. B. Rate-Limiting Nutrient: A significant loss of nutrients occurred in the assay sample from the time of collection to the beginning of the assay, and the results are not indicative of conditions in the lake. The lake data indicate that the lake was phosphorus limited in the fall (the N/P ratio was 16/1) but nitrogen limited at the other sampling times (the N/P ratios were 7/1 or less). C. Nutrient Controllability: 1. Point sources—During the sampling year, Round Lake received a total phosphorus load at a rate more than five times the rate proposed by Vollenweider (in press) as "dangerous"; i.e., a eutrophic rate (see page 12). It is estimated that the Village of Round Lake contributed about 15% of that load. How- ever/even complete removal of phosphorus at this source would o still leave a loading rate of 4.44 g/m /yr (in excess of four ------- times the eutrophic rate), and it is concluded that point-source phosphorus control would have little effect on the existing trophic condition of Round Lake. 2. Non-point sources (see page 12)—The phosphorus exports of Round Lake tributaries were quite high as compared to unim- pacted New York streams elsewhere (e.g., the mean annual export of 11 tributaries of nearby Sacandaga Reservoir* was 53 Ibs P/ 2 mi ). The nutrient exports of the unnamed streams at stations D-l and E-l were exceptionally high (particularly E-l) and it is likely that those streams were impacted by point sources. In all, it is estimated that non-point sources contributed about 85% of the total phosphorus load to Round Lake during the sampling year. * Working Paper No. 167. ------- II LAKE AND DRAINAGE BASIN CHARACTERISTICS A. Lake Morphemetry : 1. Surface area: 320 acres. 2. Mean depth: unknown. 3. Maximum depth: >16 feet. 4. Volume: unknown. 5. Mean hydraulic retention time: unknown. B. Tributary and Outlet: (See Appendix A for flow data) 1. Tributaries - Name Unnamed Creek (A-l) Unnamed Creek (B-l) Ballston Creek Unnamed Creek (D-l) Unnamed Creek (E-l) Minor tributaries & immediate drainage - Totals 2. Outlet - Anthony Kill Creek C. Precipitation***: 1. Year of sampling: 50.9 inches. 2. Mean annual: 46.1 inches. Drainage area* Mean flow* 2.9 ml. 0.9 mi. 17.8 mi; 0.6 m1« 2.2 mr 2.1 ml2 4.2 cfs 1 .3 cfs 25.7 cfs 0.9 cfs 3.2 cfs 3.2 cfs 26.5 mi' 39.0 cfs 27.0 mr** 39.0 cfs** t Greeson and Robison, 1970. * Drainage areas are accurate within ±5%, except for small basins (±10%); mean dally flows are accurate within ±5 to 25%; and normalized mean monthly flows are accurate within ±15%. ** Includes area of lake; values adjusted to actual lake outlet. *** See Working Paper No. 1, "Survey Methods". ------- III. LAKE WATER QUALITY SUMMARY Round Lake was sampled three times during the open-water season of 1972 by means of a pontoon-equipped Huey helicopter. Each time, samples for physical and chemical parameters were collected from two or more depths at one station on the lake (see map, page v). During each visit, a single depth-integrated (near bottom to surface) sample was collected for phytoplankton identification and enumeration; and a similar sample was taken for chlorophyll a_ analysis. During the last visit, a five-gallon depth-integrated sample was collected for algal assays. The maximum depth sampled was 16 feet. The results obtained are presented in full in Appendix B, and the data for the fall sampling period, when the lake was essentially well- mixed, are summarized below. Note, however, the Secchi disc summary is based on all values. For differences in the various parameters at the other sampling times, refer to Appendix B. ------- A. Physical and chemical characteristics: Parameter Minimum Temperature (Cent.) 13.7 Dissolved oxygen (mg/1) 7.0 Conductivity (ymhos) 253 pH (units) 7.6 Alkalinity (mg/1) 81 Total P (mg/1) 0.078 Dissolved P (mg/1) 0.028 N02 + NO- (mg/1) 0.120 Ammonia fmg/1) 0.400 FALL VALUES (10/10/72) Mean Median Maximum 13.8 7.2 261 7.6 82 0.094 0.033 0.127 0.403 13.8 7.2 260 7.6 82 0.082 0.035 0.130 0.400 13.9 7.4 270 7.7 83 0.122 0.037 0.130 0.410 ALL VALUES Secchi disc (inches) 30 46 36 72 ------- B. Biological characteristics: 1. Phytoplankton - Sampling Date 05/28/72 07/25/72 10/10/72 Dominant Genera 1. AsterionelU 2. Synedra 3. label!aria 4. Cryptomonas 5. Stephanodiscus 6. Cyclotella Other genera Total 1. Merismopedia 2. Anabaena 3. Polycystis 4. Fragilaria 5. Chroococcus Other genera Total 1. Flagellates 2. Cyclotella 3. Di nobyron 4. Fragilaria 5. Dictyosphaerium Other genera Total Number per ml 4,623 1,266 497 309 226 166 445 2,909 7,849 ------- 2. Chlorophyll a. - (Because of instrumentation problems during the 1972 sampling, the following values may be in error by plus or minus 20 percent.) Sampling Station Chlorophyll a_ Date Number (yg/1) 05/28/72 01 35.9 07/25/72 01 24.8 10/10/72 01 24.3 C. Limiting Nutrient Study: The algal assay results are not considered indicative of lake conditions because of nutrient losses in the sample during shipping. However, the lake data indicate phosphorus limitation in October (the N/P ratio was 16/1). At the other sampling times, the data indicate nitrogen limitation (i.e., N/P ratios were 7/1 or less, and nitrogen limitation would be expected). ------- 8 IV. NUTRIENT LOADINGS (See Appendix C for data) For the determination of nutrient loadings, the New York National Guard collected monthly near-surface grab samples from each of the tributary sites indicated on the map (page v), except for the high runoff months of April and May when two samples were collected. Samp- ling was begun in November, 1972, and was completed in October, 1973. Through an interagency agreement, stream flow estimates for the year of sampling and a "normalized" or average year were provided by the New York District Office of the U.S. Geological Survey for the tributary sites nearest the lake. In this report, nutrient loads for sampled tributaries were deter- mined by using a modification of a U.S. Geological Survey computer program for calculating stream loadings*. However, the "outlet" of Round Lake as sampled at station F-l (see map, page v) included 25.9 square miles of additional drainage, and the nutrient loads measured were adjusted by subtracting the areal contributions of the excess drainage area which were estimated in the same way as the ZZ area. Nutrient loadings for unsampled "minor tributaries and immediate drainage" ("ZZ" of U.S.G.S.) were estimated using the means of the nu- 2 trient loads, in Ibs/mi /year, at stations B-l, C-l, and D-l and 2 multiplying the means by the ZZ area in mi . The Village of Round Lake did not participate in the Survey, and nutrient loads were estimated at 2.5 Ibs P and 7.5 Ibs N/capita/year. * See Working Paper No. 1. ------- A. Waste Sources: 1. Known muncipal - Pop. Mean Flow Receiving Name Served Treatment (mgd) Water Round Lake 886* prim. 0.089** Round Lake clarifier 2. Known industrial - None t Anonymous, 1972. * 1970 Census. ** Estimated at 100 gal/capita/day. ------- 10 B. Annual Total Phosphorus Loading - Average Year: 1. Inputs - Ibs P/ % of Source yr total a. Tributaries (non-point load) - Unnamed Creek (A-l) 350 2.3 Unnamed Creek (B-l) 240 1.6 Ballston Creek 2,580 17.3 Unnamed Creek (D-l) 530 3.6 Unnamed Creek (E-l) 8,020 53.8 b. Minor tributaries & immediate drainage (non-point load) - 910 6.1 c. Known municipal - Round Lake 2,220 14.9 d. Septic tanks - Unknown e. Known industrial - None f. Direct precipitation* - 5£ 0.3 Total 14,900 100.0 2. Outputs - Lake outlet - Anthony Kill Creek 12,260 3. Net annual P accumulation - 2,640 pounds. * See Working Paper No. 1. ------- 11 C. Annual Total Nitrogen Loading - Average Year: 1. Inputs - kg N/ % of Source yr total a. Tributaries (non-point load) - Unnamed Creek (A-l) 8,060 7.7 Unnamed Creek (B-l) 2,760 2.6 Ballston Creek 46,460 44.4 Unnamed Creek (D-l) 2,910 2.8 Unnamed Creek (E-l) 27,340 26.1 b. Minor tributaries & immediate drainage (non-point load) - 7,370 7.1 c. Known municipal - Round Lake 6,650 6.4 d. Septic tanks - Unknown e. Known industrial - None f. Direct precipitation* - 3,080 2.9 Total 104,620 100.0 2. Outputs - Lake outlet - Anthony Kill Creek 181,670 3. Net annual N loss - 77,050 pounds * See Working Paper No. 1. ------- 12 D. Mean Annual Non-point Nutrient Export by Subdrainage Area: Tributary IPS P/mi2/yr IDS N/mi2/yr Unnamed Creek (A-l) 121 2,779 Unnamed Creek (B-l) 267 3,067 Ballston Creek 145 2,610 Unnamed Creek (D-l) 883 4,850 Unnamed Creek (E-l) 3,645 12,427 E. Yearly Loading Rates: In the following table, the existing phosphorus loading rates are compared to those proposed by Vollenweider (in press). Essentially, his "dangerous" rate is the rate at which the receiving water would become eutrophic or remain eutrophic; his "permissible" rate is that which would result in the receiving water remaining oligotrophic or becoming oligotrophic if morphometry permitted. A mesotrophic rate would be consid- ered one between "dangerous" and "permissible". Total Phosphorus Total Nitrogen Units Ibs/acre/yr grams/m2/yr Total 46.6 5.22 Accumulated 8.2 0.92 Total 326.9 36.6 Accumulated loss* Vollenweider loading rates for phosphorus (g/m2/yr) based on surface area and mean outflow of Round Lake: "Dangerous" (eutrophic rate) 1.00 "Permissible" (oligotrophic rate) 0.50 * There was an apparent loss of nitrogen during the sampling year. This may have been due to nitrogen fixation in the lake, solubilization of previously sedimented nitrogen, recharge with nitrogen-rich ground water, unknown and unsampled point sources discharging directly to the lake, or underestimation of the nitrogen load from the Village of Round Lake. Whatever the cause, a similar nitrogen loss has occurred at Shagawa Lake, Minnesota, which has been intensively studied by EPA's National Eutrophication Research and Lake Restoration Branch. ------- V. LITERATURE REVIEWED Anonymous, 1972, Municipal S.T.W. inventory. NY Dept. of Env. Cons., Albany. Greeson, Phillip E., and F. Luman Robison, 1970. Characteristics of New York Lakes. Part 1 - Gazateer of lakes, ponds, and reservoirs. Bull. 68, U.S. Dept. of Int. and NY Dept. of Env. Cons., Albany. Vollenweider, Richard A. (in press). Input-output models. Schweiz. A. Hydrol. ------- VII. APPENDICES APPENDIX A TRIBUTARY FLOW DATA ------- TRIBUTARY FLOW INFORMATION FOR NEW YORK 11/26/74 LAKE CODE 3630 ROUND LAKE TOTAL DRAINAGE AREA OF LAKE 52.94 SUB-DRAINAGE TRIBUTARY AREA JAN FE8 MAR MAY NORMALIZED FLOWS JUN JUL AUG SEP OCT NOV DEC TOTAL DRAINAGE AREA OF LAKE = 52.94 SUM OF SUB-DRAINAGE AREAS = 51.97 MEAN MONTHLY FLOWS AND DAILY FLOWS TRIBUTARY MONTH YEAR MEAN FLOW DAY FLOW DAY 3630A1 3630 til 11 12 1 ? 3 4 5 6 7 fl 9 10 11 1? 1 ? 3 4 S f> 7 <* 9 10 72 72 73 73 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 73 73 9.45 6.51 10.50 6.3? 12.90 10.50 9.26 4.63 ?.A4 1.17 1.14 1.6H 2.80 1.93 3.1? l.flfl 3.86 3.15 ?.76 1.3B 0.85 0.35 0.34 0.3? 4 1 5 5 5 7 8 5 9 5 6 8 <* 1 5 5 9 7 fl 5 9 5 6 8 6.31 7.40 9.00 10.60 115.00 6.40 4.12 4.20 3.50 3.20 3.3* 3.oa 2.40 2. IS 2.60 3.05 ?.83 2.23 1.00 0.94 0.52 0.21 0.33 0.13 15 20 15 20 SUMMARY TOTAL FLOW IN = 467.08 TOTAL FLOW OUT s 918.70 FLOW DAY FLOW 5.00 6.20 1.44 2.02 MEAN 3630A1 363081 3630C1 363001 3630E1 3630^1 3630ZZ 2.92 0.87 17.80 0.60 ?.19 52.94 27.59 3.66 1.15 23.50 0.79 2.90 70.00 3.37 4.07 1.21 24. PO 0.84 3.05 73.80 3.56 8.41 2.51 51.30 1.73 6.31 152.00 7.34 10.80 3.23 66.00 2.23 8.12 196.00 9.46 5.31 1.58 32.40 1.09 3.96 96.30 4.64 3.15 0.94 19.20 0.65 2.37 57.20 2.76 2.10 0.63 12.80 0.43 1.57 38.10 1.63 1.43 0.43 8.72 0.29 1.07 25.90 1.25 1.77 0.53 10.60 0.37 1.33 32.20 1.55 2.23 0.67 13.60 0.46 1.68 40.50 1.95 3.78 1.12 23.00 0.78 2.83 69.50 3.30 3.71 1.10 22.60 0.76 2.78 67.20 3.24 4.21 1.26 25.69 0.87 3.16 76.45 3.68 ------- TRIBUTARY FLOW INFORMATION FOR NEW YORK 11/26/7* LAKE CODE 3630 ROUND LAKE MEAN MONTHLY FLOWS AND DAILY FLOWS TRIBUTARY MONTH YEAR MEAN FLOW DAY 3630Cl 363001 3630E1 3630F1 11 1? 1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12 \ 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 72 72 73 73 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 73 73 72 72 73 73 73 73 73 73 73 73 73 73 57.50 39.60 63.70 38.50 78.90 64.40 56.50 28.20 17.30 7.12 6.94 7.66 1.94 1.34 2.15 1.30 2.66 0.18 1.90 0.95 0.58 0.24 0.24 0.26 7.0« 4.88 7.86 4.73 9.70 7.92 6.94 3. 4ft 2.12 0.87 0.86 0.95 209.00 144.00 231.00 140.00 286.00 191.00 168.00 84.10 51.60 21.20 ?0.70 ?2.80 4 1 5 9 7 8 5 9 5 6 a 4 i 5 6 9 7 8 5 9 5 6 8 4 1 5 5 9 7 8 5 9 5 6 8 4 1 5 5 7 7 8 5 9 5 6 8 FLOW DAY FLOW DAY FLOW 11.50 10.20 12.40 286.00 114.00 8.00 11.00 3.50 0.81 1.60 0.38 1.14 1.00 1.23 1.30 6.00 2.04 0.49 0.54 0.29 0.10 0.16 0.10 2.30 2.04 2.48 2.93 15.70 4.15 1.20 13.30 0.71 0.50 0.60 0.43 83.10 74.00 90.00 106.00 165.00 332.00 62.00 64.00 21.00 13.50 19.20 9.90 15 20 15 20 15 20 15 20 28.80 91.00 0.96 1.87 2.30 4.40 144.00 308.00 ------- TRIBUTARY FLOW INFORMATION FOR NEW YORK 11/26/74 LAKE CODE 3630 ROUND LAKE MEAN MONTHLY FLOWS AND DAILY FLOWS TRIBUTARY MONTH YEAR MEAN FLOW DAY 3630ZZ 11 1? 1 2 3 4 S 6 7 8 9 10 72 72 73 73 73 73 73 73 73 73 73 73 H.?5 S.6B 9.13 5.52 11.30 9.23 ft. 09 4.06 2.48 1.02 l.CO 1.10 4 1 5 5 9 7 8 5 9 5 ft 8 FLOW DAY 6,40 5.69 6.91 8.16 20.70 12.00 15 3.34 20 3.65 2.04 1.16 1.47 0.96 FLOW DAY FLOW 6.12 11.20 ------- APPENDIX B PHYSICAL and CHEMICAL DATA ------- STORE! RETRIEVAL DATE 74/11/26 363001 42 56 03.0 073 47 00.0 ROUND LAKE 36 NEW YORK 00010 00300 DATE TIME OEPTH WATER DO FROM OF TEMP TO DAY FEET CENT MG/L 72/05/28 14 55 0000 22.4 11.1 14 55 0010 14.9 9.7 72/07/25 19 35 0000 19 35 0004 27.5 10.6 19 35 0015 15.9 0.0 7?/10/10 16 20 0000 16 20 0004 13.9 7.4 16 20 0016 13.7 7.0 00077 TRANSP SECCH1 INCHES 72 36 30 00094 CNDUCTVY FIELD MICROMHO 280 280 245 ?50 260 253 ?70 260 11EPALES 3 00400 PH SU B.flO 7.60 9.3" 9.20 7.40 7.55 7.65 7.60 00410 T ALK CAC03 MG/L 68 68 75 75 77 83 82 81 2111202 0012 00630 "J02S.N03 N-TOTAL MG/L 0.030 0.030 0.050 0.070 0.040 0.120 0.130 0.130 FEET DEPTH 00610 NH3-N TOTAL MG/L 0,070 0.040 0.060 0.090 0.420 0.400 0.410 0.400 00665 PHOS-TOT MG/L P 0.041 0.075 0.033 0.044 0.112 0.082 0.122 0.078 00666 PHOS-DIS MG/L P 0.023 0.016 0.016 0.019 0.074 0.037 0.035 0.028 32P17 DATE TIME DEPTH CHLRPHYL FROM OF A TO DAY FEET UG/L 72/05/2R 14 55 0000 35.9J 72/07/25 19 35 0000 24.9J 72/10/10 16 ?0 0000 24.3J J VALUE KNOWN TO BE IN ERROR ------- APPENDIX C TRIBUTARY DATA ------- STORET RETRIEVAL DATE 74/11/26 3630A1 LS3630A1 42 56 30.0 073 47 00.0 UNNAMED CREEK 36 7.5 ROUND LAKE T/POUND LAKE MALTAVILLE RD BRIDGE IN MALTAVILLE 11EPALES 2111304 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/01 73/01/05 73/02/05 73/03/05 73/04/07 73/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/OB/05 73/09/06 73/10/09 00630 006?5 TIME DEPTH N02S.N03 TOT KJEL OF N-TOTAL N DAY FEET 12 11 12 14 10 11 17 20 20 16 ?? 12 19 21 14 10 40 50 37 10 00 45 00 <»0 00 10 05 40 MG/L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 .247 .330 .330 .310 .270 .280 .220 .210 .210 .250 .252 .180 .198 .ISO MG/L 0 0 0 0 2 .250 .870 .210 .290 .100 0.560 0 0 0 0 1 0 1 0 .850 .390 .7RO .610 .630 .120 .150 .190 00610 00671 00665 NH3-N PHOS-DIS PHOS-TOT TOTAL ORTHO MG/L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 .056 .034 .025 .038 .050 .031 .020 .021 .027 .011 .038 .018 .032 .017 MG/L 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. p 010 008 009 010 Oil 010 OOB 010 010 012 005K Oil 014 008 MG/L P 0.019 0.026 0.02B 0.045 0.300 0.075 0.040 0.060 0.040 0.055 0.030 0.025 0.035 0.0?5 ; KUO"** T~» N INOIC ------- STORE! RETRIEVAL DATE 74/11/36 3630B1 L53630B1 42 56 30.0 073 46 30.0 UNNAMED CREEK 36 7.5 ROUND LAKE T/ROUND LAKE ST HWY 67 BRIDGE 1 MI SE OFMALTAVILLE 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/01 73/01/05 73/02/05 73/03/09 73/04/07 73/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/08/05 73/09/06 73/10/03 00630 00625 TIME DEPTH N02&N03 TOT KJEL OF N-TOTAL N DAY FEET 1? 11 12 14 10 11 16 20 20 16 21 1? 19 21 10 ?0 45 35 35 00 50 10 21 30 55 00 40 35 MG/L 0.310 0.290 0.400 0.300 0.350 0.160 0.140 0.089 0.138 0.052 0.044 0.017 0.036 0.017 MG/L 0 0 0 1 2 1 1 1 1 0 0 0 0 0 .380 .300 .160 .380 .300 .000 .500 .540 .100 .335 .910 .750 .920 .630 00610 00671 00665 NH3-N PHOS-DIS PHOS-TOT TOTAL ORTHO MG/L 0.034 0.010 0.024 0.132 0.115 0.022 0.06B 0.052 0.040 0.014 0.032 0.273 0.130 0.029 MG/L P 0 0 0 0 0 0 0 0 0 0 0 0 0 ^o .021 .013 .013 .046 .014 .009 .015 .019 .022 .021 .018 .038 .028 .048 MG/L P 0.046 0.029 0.027 0.195 0.400 0.065 0.03S 0.065 0.04Q 0.050 0.095 0.077 0.100 0.135 ------- STORE! RETRIEVAL DATE 74/11/36 3630C1 LS3630C1 42 56 30.0 073 47 30.0 BALLSTON CREEK 36 7.5 ROUND LAKE T/90UND LAKE MALTAVILLE RD BRIDGE NE OF ROUND LAKE 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 7?/ 12/0 1 73/01/05 73/02/05 73/03/09 73/04/07 71/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/08/05 73/0-5/06 73/1 0/0« 00630 00625 TIMF DE^TH M02&N03 TOT KJEL OF N-TOTAL N DAY FEET 11 1? 15 10 11 17 20 16 22 12 16 21 05 50 00 40 45 20 20 50 15 20 40 50 MG/L 0 0 0 0 0 0 0 0 0 0 0 0 0 n .140 .132 .2BO .273 .231 .098 .105 .110 .046 .315 .280 ,16« .740 .240 MG/L 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 1. 0* 0. 0. 500 365 360 390 900 200 670 640 750 P70 100 480 965 420 00610 00671 00665 NH3-N PHOS-OIS PHOS-TOT TOTAL QPTHO MG/L 0. 0. 0. 0. 0. 0. 0. 0. C. 0. 0. 0. 0. 0. 06R 015 021 033 063 072 026 026 027 029 030 052 076 02W MG/L 0. 0. 0, 0. 0. 0. 0. 0. 0. 0. 0. 0. P 015 008 005K 010 013 005K OOS 018 014 056 046 02? 0.026 0. 012 MG/L P 0.032 0.020 0.015 0.035 0.100 0.040 0.020 0.065 0.045 0.095 0.080 0.055 0.070 0.035 K LFSS ------- STORET RETRIEVAL DATE 74/11/26 3*3001 LS363001 42 56 00.0 073 47 30.0 UNNAMED CREEK 36 7.5 ROUND LAKE T/ROUND LAKE ST HWY 9 8WIDGE SE OF ROUNDLAKE 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/01 73/01/05 73/03/09 73/04/07 73/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/08/05 73/09/06 73/10/03 00630 00625 TIME DEPTH N02&N03 TOT KJEL OF M-TOTAL N DAY FEET 1? il 12 10 12 17 20 20 17 22 12 18 22 25 00 55 43 00 30 20 52 00 20 30 00 00 MG/L 0 0 0 0 0 0 0 0 0 1 0 0 0 .815 .850 .790 .250 .610 .450 .550 .420 .670 .120 .710 .480 .840 MO/L 0. 0. 2. 0. 0. 1. 0. 1. 0. 0. 1. 1. 0. 920 670 095 780 910 050 970 260 970 690 780 000 940 00610 00671 00665 NH3-N PHOS-DIS PHOS-TOT TOTAL ORTHO MG/L 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 320 154 930 060 110 086 189 170 110 069 300 210 098 MG/L P 0.176 O.OB5 0.500 0.013 0.070 0.126 0.399 0.230 0.252 0.180 0.200 0.090 0.210 MG/L P 0 0 0 0 0 .294 .120 .690 .102 .165 0.230 0 0 0 0 0 0 0 .630 .460 .395 .260 .370 .150 .320 ------- STORET RETRIEVAL DATE 74/11/26 3630E1 LS3630E1 42 56 00.0 073 47 30.0 UNNAMED CREEK 36 7.5 ROUND LAKE T/ROUND LAKE ST HWY 9 BRIDGE .5 HI S OF ROUND LAKE 11EPALES 2111204 4 0000 FEET DEPTH OATE FROM TO 72/11/04 72/12/01 73/01/05 73/02/05 73/03/09 73/04/07 73/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/08/05 73/09/06 73/10/08 00630 00625 TIME DEPTH N026.N03 TOT KJEL OF N-TOTAL N DAY FEET 1? 30 10 55 13 00 15 10 10 47 1? 20 17 40 20 40 20 45 17 10 22 30 12 35 22 40 ?1 55 MG/L 0.937 1.040 1.440 1.100 n.370 0.350 0.850 1.020 0.820 1.200 0.550 2.400 0.460 0.650 MG/L 3.800 1.400 2.400 2.800 1.120 1.150 6.300 4.750 5.500 7.400 1.380 4.900 3.500 1.470 00610 00671 00665 NH3-N PHOS-OIS PHOS-TOT TOTAL ORTHO MG/L 0.300 0.180 0.670 1.160 0.160 0.210 2.900 2.100 3.200 0.145 0.430 0.390 0.176 0.160 MG/L o 0.270 1.260 1.100 0.700 0.061 0.110 1.047 0.060 0.790 1.200 0.460 1.470 0.270 0.310 MG/L P 2.600 1.680 1.250 1.200 0.210 0.280 1.710 1.720 1.150 1.800 0.575 2.JOO 0.93? 0.440 ------- STORET RETRIEVAL DATE 74/1l/?6 3630F1 LS3630F1 42 55 00.0 073 45 00.0 ANTHONY KILL CREEK 36 7.5 MECHANICSVIL T/ROUND LAKE MED DUTY RU BRIDGE NEAR COONS 11EPALES 2111204 4 0000 FEET DEPTH DATE FROM TO 72/11/04 72/12/01 73/01/05 73/02/05 73/03/07 73/04/07 73/04/15 73/05/08 73/05/20 73/06/05 73/07/09 73/08/05 73/09/06 73/10/08 TIME DEPTH OF OAY FEET 1? 05 11 20 12 40 14 40 10 30 10 05 16 40 20 00 20 16 16 ?0 21 50 11 45 20 35 21 20 00630 NOP&N03 N-TOTAL MG/L 0.540 0.280 0.400 0.500 0.440 0.273 0.250 0.320 0.330 0.320 0.320 0.680 1.260 0.880 00625 TOT KJEL N MG/L 0.580 0.600 0.750 2.100 1.150 P.310 1.600 0.850 1.150 1.7PO 1.100 2.000 1.000 00610 NH3-N TOTAL MG/L 0.072 0.075 0.032 0.068 0.063 0.168 0.099 0.056 0.054 0.147 0.126 0.063 0.590 0.078 00671 PriOS-DIS ORTHO MG/L P 0.084 0.014 O.Olfl 0.023 0.025 0.010 0.025 0.048 0.044 0.061 0.069 0.090 0.048 0.035 00665 PHOS-TOT MG/L P 0.168 0.044 0.040 0.105 0.550 0.040 0.090 0.110 0.125 0.160 0.195 0.175 0.240 0.140 ------- |