EVALUATION OF AIR EMISSIONS TRENDS
USING TRI DATA
OFFH
OFFICE OF AIR QUA! NDARDS
Re*
ENERGY AN
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EVALUATION OF AIR EMISSIONS TRENDS
USING TRI DATA
Prepared for:
OFFICE OF POLICY ANALYSIS AND REVIEW
U.S. Environmental Protection Agency
Washington, DC 20460
and
OFFICE OF AIR QUALITY PLANNING AND STANDARDS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
Prepared by:
ENERGY AND ENVIRONMENTAL ANALYSIS, INC.
1655 North Fort Myer Drive, Suite 600
Arlington, VA 22209
November 1992
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Table Of Contents
1. INTRODUCTION
2. TRENDS IN TOXIC AIR EMISSIONS
3. ANNUAL TOXIC AIR EMISSIONS
4. DATA HANDLING PROCEDURES
APPENDIX A: DATA FROM LINKED DATA SET
APPENDIX B: 1990 DATA FROM BASIC DATA SET
APPENDIX C: 1989 DATA FROM BASIC DATA SET
APPENDIX D: 1988 DATA FROM BASIC DATA SET
APPENDIX E: 1987 DATA FROM BASIC DATA SET
Page
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11
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List Of Figures
Page
1987-1990
Figure 2-1: Three Year Change in Emissions (EPA Regions) 2-2
Figure 2-2: Three Year Change in Emissions (Top 10 States) 2-3
Figure 2-3: Three Year Change in Emissions (Top 10 3-Digit ZIP Codes) 2-4
Figure 2-4: Three Year Change in Emissions (Top 10 Counties) 2-5
Figure 2-5: Top 10 Chemicals 2-6
Figure 2-6: Top 10 Hazardous Air Pollutants 2-7
Figure 2-7: Top 10 EPA 33/50 Program Chemicals 2-8
Figure 2-8: Top 10 High Risk/Early Reduction Chemicals 2-9
Figure 2-9: Top 10 Carcinogenic Chemicals in TRI Database 2-10
Figure 2-10: Ozone Depleting Chemicals in TRI Database 2-11
1990
Figure 3-1: EPA Regional Hot Spots 3-2
Figure 3-2: Toxic Air Emissions by State 3-3
Figure 3-3: 20 ZIP Code Areas with Greatest Toxic Air Emissions 3-4
Figure 3-4: 20 Counties with Greatest Toxic Air Emissions 3-5
Figure 3-5: Toxic Air Emissions by U.S. Industry 3-6
Figure 3-6: Number of Release Reports by U.S. Industry 3-7
Figure 3-7: Toxic Air Emissions by SIC Code 3-8
Figure 3-8: U.S. Air Toxics Emissions 3-9
1989
Figure 3-9: EPA Regional Hot Spots 3-12
Figure 3-10: Toxic Air Emissions by State 3-13
Figure 3-11: 20 ZIP Code Areas with Greatest Toxic Air Emissions 3-14
Figure 3-12: 20 Counties with Greatest Toxic Air Emissions 3-15
Figure 3-13: Toxic Air Emissions by U.S. Industry 3-16
Figure 3-14: Number of Release Reports by U.S. Industry 3-17
Figure 3-15: Toxic Air Emissions by SIC Code 3-18
Figure 3-16: U.S. Air Toxics Emissions 3-19
111
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List Of Figures
(Continued)
Page
1988
Figure 3-17: EPA Regional Hot Spots 3-22
Figure 3-18: Toxic Air Emissions by State 3-23
Figure 3-19: 20 ZIP Code Areas with Greatest Toxic Air Emissions 3-24
Figure 3-20: 20 Counties with Greatest Toxic Air Emissions 3-25
Figure 3-21: Toxic Air Emissions by U.S. Industry 3-26
Figure 3-22: Number of Release Reports by U.S. Industry 3-27
Figure 3-23: Toxic Air Emissions by SIC Code 3-28
Figure 3-24: U.S. Air Toxics Emissions 3-29
1987
Figure 3-25: EPA Regional Hot Spots 3-32
Figure 3-26: Toxic Air Emissions by State 3-33
Figure 3-27: 20 ZIP Code Areas with Greatest Toxic Air Emissions 3-34
Figure 3-28: 20 Counties with Greatest Toxic Air Emissions 3-35
Figure 3-29: Toxic Air Emissions by U.S. Industry 3-36
Figure 3-30: Number of Release Reports by U.S. Industry 3-37
Figure 3-31: Toxic Air Emissions by SIC Code 3-38
Figure 3-32: U.S. Air Toxics Emissions 3-39
IV
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List Of Tables
Page
1987-1990
Table 2-1: Regional Hot Spots (EPA Regions) 2-2
Table 2-2: Regional Hot Spots (Top 20 States) 2-3
Table 2-3: Regional Hot Spots (Top 20 3-Digit ZIP Codes) 2-4
Table 2-4: Regional Hot Spots (Top 20 Counties) 2-5
Table 2-5: Top 20 Chemicals 2-6
Table 2-6: Top 20 Hazardous Air Pollutants 2-7
Table 2-7: EPA 33/50 Program Chemicals 2-8
Table 2-8: Top 20 High Risk/Early Reduction Chemicals 2-9
Table 2-9: Top 20 Carcinogenic Chemicals in TRI Database 2-10
Table 2-10: Ozone Depleting Chemicals in TRI Database 2-11
1990
Table 3-1: Regional Hot Spots (EPA Regions) 3-2
Table 3-2: State Total Emissions 3-3
Table 3-3: 3-Digit ZIP Codes 3-4
Table 3-4: Counties 3-5
Table 3-5: Air Emissions by U.S. Industry 3-6
Table 3-6: No. of Release Reports by U.S. Industry 3-7
Table 3-7: Top Industrial Emitters (3-Digit SIC Codes) 3-8
Table 3-8: Top Industrial Emitters (4-Digit SIC Codes) 3-8
Table 3-9: Chemicals Emitted in Greatest Amount 3-9
Table 3-10: Major Sources 3-10
Table 3-11: HAPs Emitted in the Greatest Amount 3-10
Table 3-12: 33/50 Chemicals Emitted in the Greatest Amount 3-10
Table 3-13: High Risk/Early Reduction Chemicals Emitted in the Greatest Amount 3-11
Table 3-14: TRI Carcinogens Emitted in the Greatest Amount 3-11
Table 3-15: TRI Ozone Depletors Emitted in the Greatest Amount 3-11
1989
Table 3-16: Regional Hot Spots (EPA Regions) 3-12
Table 3-17: State Total Emissions 3-13
Table 3-18: 3-Digit ZIP Codes 3-14
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List Of Tables
(Continued)
Table 3-19: Counties
Table 3-20: Air Emissions by U.S. Industry
Table 3-21: No. of Release Reports by U.S. Industry
Table 3-22: Top Industrial Emitters (3-Digit SIC Codes)
Table 3-23: Top Industrial Emitters (4-Digit SIC Codes)
Table 3-24: Chemicals Emitted in the Created Amount
Table 3-25: Major Sources
Table 3-26: HAPs Emitted in the Greatest Amount
Table 3-27: 33/50 Chemicals Emitted in the Greatest Amount
Table 3-28: High Risk/Early Reduction Chemicals Emitted in the Greatest Amount
Table 3-29: TRI Carcinogens Emitted in the Greatest Amount
Table 3-30: TRI Ozone Depletors Emitted in the Greatest Amount
1988
Table 3-31: Regional Hot Spots (EPA Regions)
Table 3-32: State Total Emissions
Table 3-33: 3-Digit ZIP Codes
Table 3-34: Counties
Table 3-35: Air Emissions by U.S. Industry
Table 3-36: No. of Release Reports by U.S. Industry
Table 3-37: Top Industrial Emitters (3-Digit SIC Codes)
Table 3-38: Top Industrial Emitters (4-Digit SIC Codes)
Table 3-39: Chemicals Emitted in the Greatest Amount
Table 3-40: Major Sources
Table 3-41: HAPs Emitted in the Greatest Amount
Table 3-42: 33/50 Chemicals Emitted in the Greatest Amount
Table 3-43: High Risk/Early Reduction Chemicals Emitted in the Greatest Amount
Table 3-44: TRI Carcinogens Emitted in the Greatest Amount
Table 3-45: TRI Ozone Depletors Emitted in the Greatest Amount
Page
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VI
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List Of Tables
(Continued)
Page
1987
Table 3-46: Regional Hot Spots (EPA Regions) 3-32
Table 3-47: State Total Emissions 3-33
Table 3-48: 3-Digit ZIP Codes 3-34
Table 3-49: Counties 3-35
Table 3-50: Air Emissions by U.S. Industry 3-36
Table 3-51: No. of Release Reports by U.S. Industry 3-37
Table 3-52: Top Industrial Emitters (3-Digit SIC Codes) 3-38
Table 3-53: Top Industrial Emitters (4-Digit SIC Codes) 3-38
Table 3-54: Chemicals Emitted in the Greatest Amount 3-39
Table 3-55: Major Sources 3-40
Table 3-56: HAPs Emitted in the Greatest Amount 3-40
Table 3-57: 33/50 Chemicals Emitted in the Greatest Amount 3-40
Table 3-58: High Risk/Early Reduction Chemicals Emitted in the Greatest Amount 3-41
Table 3-59: TRI Carcinogens Emitted in the Greatest Amount 3-41
Table 3-60: TRI Ozone Depletors Emitted in the Greatest Amount 3-41
1987-1990
Table 4-1:. Variable List 4-2
Table 4-2: Delisted Chemicals 4-3
Table 4-3: 1990 Chemicals Additions 4-3
Table 4-4: Data File Characteristics 4-4
Table 4-5: Hazardous Air Pollutants 4-4
Table 4-6: EPA 33/50 Program Chemicals 4-6
Table 4-7: High Risk/Early Reduction Chemicals 4-6
Table 4-8: Carcinogenic Chemicals in TRI Database 4-7
Table 4-9: Ozone Depleting Chemicals in TRI Database 4-7
1987-1990
Table A-1: Regional Hot Spots (EPA Regions) A-1
Table A-2: Regional Hot Spots (Top 20 States) A-1
Table A-3: Regional Hot Spots (Top 20 3-Digit ZIP Codes) A-2
Table A-4: Regional Hot Spots (Top 20 Counties) A-2
vu
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List Of Tables
(Continued)
Table A-5: Top 20 Chemicals
Table A-6: Top 20 Hazardous Air Pollutants
Table A-7: EPA 33/50 Program Chemicals
Table A-8: Top 20 High Risk/Early Reduction Chemicals
Table A-9: Top 20 Carcinogenic Chemicals in TRI Database
Table A-10: Ozone Depleting Chemicals in TRI Database
1990
Table B-1: Regional Hot Spots (EPA Regions)
Table B-2: State Emissions
Table B-3: Regional Hot Spots (3-Digit ZIP Codes)
Table B-4: Regional Hot Spots (Counties)
Table B-5: Air Emissions by U.S. Industry
Table B-6: Industrial Emissions
Table B-7: Air Emissions for the U.S. Chemical Industry
Table B-8: Top Industrial Emitters (4-Digit SIC Codes)
Table B-9: National Emissions of HAPs
Table B-10: National Emissions of 33/50 Chemicals
Table B-l 1: National Emissions of High Risk/Early Reduction Chemicals
Table B-l2: National Emissions of Carcinogens in TRI Database
Table B-l3: National Emissions of Ozone Depletors in TRI Database
Table B-14: All Chemicals Reported
1989
Table C-1: Regional Hot Spots (EPA Regions)
Table C-2: State Emissions
Table C-3: Regional Hot Spots (3-Digit ZIP Codes)
Table C-4: Regional Hot Spots (Counties)
Table C-5: Air Emissions by U.S. Industry
Table C-6: Industrial Emissions
Table C-7: Air Emissions for the U.S. Chemical Industry
Table C-8: Top Industrial Emitters (4-Digit SIC Codes)
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List Of Tables
(Continued)
Table C-9: National Emissions of HAPs
Table C-10: National Emissions of 33/50 Chemicals
Table C-11: National Emissions of High Risk/Early Reduction Chemicals
Table C-12: National Emissions of Carcinogens in TRI Database
Table C-13: National Emissions of Ozone Depletors in TRI Database
Table C-14: All Chemicals Reported
1988
Table D-1: Regional Hot Spots (EPA Regions)
Table D-2: State Emissions
Table D-3: Regional Hot Spots (3-Digit ZIP Codes)
Table D-4: Regional Hot Spots (Counties)
Table D-5: Air Emissions by U.S. Industry
Table D-6: Industrial Emissions
Table D-7: Air Emissions for the U.S. Chemical Industry
Table D-8: Top Industrial Emitters (4-Digit SIC Codes)
Table D-9: National Emissions of HAPs
Table D-10: National Emissions of 33/50 Chemicals
Table D-11: National Emissions of High Risk/Early Reduction Chemicals
Table D-12: National Emissions of Carcinogens in TRI Database
Table D-13: National Emissions of Ozone Depletors in TRI Database
Table D-14: All Chemicals Reported
1987
Table E-1: Regional Hot Spots (EPA Regions)
Table E-2: State Emissions
Table E-3: Regional Hot Spots (3-Digit ZIP Codes)
Table E-4: Regional Hot Spots (Counties)
Table E-5: Air Emissions by U.S. Industry
Table E-6: Industrial Emissions
Table E-7: Air Emissions for the U.S. Chemical Industry
Table E-8: Top Industrial Emitters (4-Digit SIC Codes)
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IX
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List Of Tables
(Continued)
Page
Table E-9: National Emissions of HAPs E-14
Table E-10: National Emissions of 33/50 Chemicals E-16
Table E-11: National Emissions of High Risk/Early Reduction Chemicals E-16
Table E-12: National Emissions of Carcinogens in TRI Database E-17
Table E-13: National Emissions of Ozone Depletors in TRI Database E-17
Table E-14: All Chemicals Reported E-18
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Evaluation Of Air Emissions
Trends Using Tri Data
SECTION 1
Introduction
Industrial releases of toxic chemicals to the
air, water, or ground and transfers of these
chemicals from one site to another are report-
ed to EPA annually and maintained in the
Toxic Release Inventory (TRI) database.
Data from 1987,,1988,1989, and 1990 cur-
rently is available to the public in the TRI
database. This data can be used to evaluate
toxic releases on a national, regional, or local
basis and idendfy emission trends over time.
This report reviews the data on emissions of
industrial chemicals to the air for all four
years.
Section 2 - Trends In Toxic Air Emissions
compares the change in emissions from year
to year. Generally, total emissions have fall-
en over time. To better understand this
reduction, change in total emissions for a
variety of geographic areas, such as EPA
Regions, states, and counties, are reviewed
highlighting areas that have shown the most
significant emission reductions.^ Similar
changes are shown for individual industries
and chemicals.
Toxic chemical emissions for individual
years are summarized in Section 3 - Annual
Toxic Air Emissions. Again, emissions are
shown for EPA Regions, states, counties,
l-l
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industries, and individual chemicals. These
yearly summaries are useful for understanding
the variation in emissions from area to area
and industry to industry. The chemicals also
are grouped to define the emissions target for
various environmental programs, notably
those being developed by EPA in response to
the Clean Air Act Amendments of 1990.
To create the emission summaries shown in
Sections 2 and 3, two sets of data were creat-
ed from the original TRI data. The Basic set
contains quality reviewed data. The Linked
set contains air emissions data from the Basic
set that can be linked for facilities that report-
ed in all four years. A description of the pro-
cedures followed to produce the two sets of
data is included in Section 4 - Data Handling
Procedures.
Each year, shortly after a new TRI data set is
released to the public, EPA's Office of
Pesticides and Toxic Substances publishes a
report providing detailed summaries of the
data. Reports have been published for 1987,
1988, and 1989. A report summarizing 1990
releases was published in May 1992. A more
detailed analysis of national toxic releases
will be published by the end of 1992. These
reports cover releases to air and water and
transfers to other sites. Readers interested in
media other than air may find these reports
very helpful.
1-2
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SECTION 2
Trends In
Toxic Air Emissions
This section describes changes in toxic air emis-
sions between 1987 and 1990, the four years for
which data on industrial toxic releases is available.
Since 1987 the number of facilities reporting each
year has increased. This is due to the fact that
more facilities realized they were required to
report and the chemical use threshold for reporting
was progressively lowered, among other reasons.
Also, some facilities may shutdown or make some
change to their processes so they fall below the
threshold. In this case they would have reported in
an early year but not in later years. To identify
trends in air toxic emissions the facilities used for
the analysis in this section were held constant. As
noted in Section 1, TRI data for the four years was
linked to create a separate data set of facilities that
reported all four years. This Linked data set cov-
ered about 88% of the total reported emissions.
The discussion of emissions in this section are
based on analysis of that data. Industrial air toxic
emissions in progressively smaller geographic
divisions are presented followed by a review of
emissions of specific chemicals and chemical
groups. Section 3 describes emissions for each
year separately, based on the complete TRI data
set for that year.
For each of the charts or tables presented in this
section, more detailed data can be found in the
appendix. Also, it should be noted that toxicity of
the specific chemicals was not considered in this
report. The actual toxicity of the chemicals cov-
ered by the TRI database ranges from slight to
extreme and no attempt was made to adjust for
differential toxicity.
2-1
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Totel Emissions- In Million Pounds Per Year
750
700
650
600
550
500
450
400
350
300
250
200
150
100
50
0
RQUI« 24
Three Year Change In Era!sslons
Regions
fligton Z
Regkm9
R«0ton10
Reflkxi)
1987
1988
1989
1990
REGIONAL HOT SPOTS
EPA Regions
Figure 2-1 shows the emissions
reported in the ten EPA regions.
Table 2-1 provides the same infor-
mation numerically. Nine of the
ten regions showed emission
reductions over the four year peri-
od. Regions 4,5, and 6 have the
largest concentration of industry
and largest reported emissions.
Together they represent about 65%
of the national total. Each of these
regions had emission reductions of
100 million pounds or more over
four years. While some of the
reduction may reflect refinements
in emissions reporting it is likely
that real reductions in toxic air
emissions have occurred.
Because of the size of the EPA
regions they generally are not
influenced by changes at a single
facility. The one exception is
Region 8, which does not have a
high concentration of industry but
does have one very large facility in
Utah. That facility largely was
responsible for the reported
increase in emissions between
1987 and 1990.
Table 2-1
Regional Hot Spots
—EPA REGIONS-1987BASIS-
EPA
Region 1987
04
05
06
03
07
621,664.527
530,990,282
462.251,285
234,398,214
121,612,041
Amount MM (WM
1988 1989 1990
589,758,062
484.808,375
379,362,209
215,559,165
131.919,474
592,344,907 523,726,327
474,447.160 405,212,823
347,131,355 293,108,331
194,486356 174,020,016
130,441,146 117,592,501
Three Year Chjnge
(Ib/yr) Pd
-97,938,200
-125,777,459
-169.142,954
-60,378,198
-4,019,540
-15.75
-23.68
-36.59
-25.76
-131
EPA
Region 1967
02
08
10
09
01
120,764,704
104,844.500
95,094.041
93,296,592
85,027,725
Amounl Emitted (ItVyr)
1988 1969
113533,786
136,753,217
74,641,562
92,153.542
78,167,971
97352,883
143,467.996
69,961,153
84^32,151
67,286,110
1990
86,133.023
123,164.214
63.425.609
77.975.810
55,806,962
Thrae Year Change
(MM Pet
-34,631,681 -28.68
18,319,714 17.47
-31,668,432 -33.30
-15,320,782 -16.42
-29,220,763 -34.37
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REGIONAL HOT SPOTS
States
Figure 2-2 and Table 2-2
show the change in emis-
sions for the states that
reported the greatest emis-
sions in 1987. Going from
regions to states and subse-
quently to smaller geograph-
ic areas, individual facilities
have more of an impact on
the combined emissions.
Among the top states,
Tennessee and Utah both
showed increased emissions
between 1987 and 1990. In
both cases, increases at a few
very large facilities influ-
enced the total. Reported
emissions decreased for all
of the other states. Texas,
which reported the greatest
emissions in each of the four
years, showed a reduction of
about 90 million pounds dur-
ing that period. That repre-
sents a reduction of about
38% in four years.
Total Emissions - In Million Pounds Per Year
250 ;
Figure 2-2
Three Year Change in Emissions
TOPWUPSTATES--
1987
Table 2-2
Regional Hot Spots
— TOP20STATES- 1987BASIS -
1988
1989
Texat
Tennessee
1990
Stale
TX
LA
OH
TN
IN
Ml
AL
IL
NC
UT
1987
238,275,406
144,359,410
133,572,741
126,736,161
108,148,431
106,051,124
100,431221
96,633,375
93,569,598
85,741,098
AimBtEflMQMM
1986 1989 1990
175,429,432
126,006,706
127,788,785
127,396,894
97,047,492
82,748,534
100,051,930
91,370,375
84,592,816
120,424,480
167,991,897 147,628,675
116,401,665 94,039,252
117,995,184 97,115,443
140,392,040 128,562.788
96,167.777 87.978,942
61,639,845 67,479.479
100,368,744 94,162.974
87,447,210 76.428,660
79,814,411 71,319,077
126,722,058 108,620,776
TtiraeYoirClnnge
(Ib/M Pel
-90,646,731
-50,320,158
-36,457,298
1,826,627
-20.169,489
-38,571.645
-6,268247
-20,204,715
-22,240,521
22,879,678
-38.04
-34.86
-2729
1.44
-18.65
-36.37
-624
-20.91
-23.77
26.68
State
GA
PA
VA
CA
NY
SC
MS
KY
Ft
AR
1987
85,090,791
84,518,628
83,986,937
75,257,676
70,027,865
61,061,327
56,258,233
51,144,009
47,383,187
47,215,941
Amount Emitted (livyr)
1988 1989
77,489,631
78,088,092
80,402,424
75,713529
64,414,892
61,736,939
56,028,443
45,141,616
37,319,591
44,528,771
69,226,759
69,539,063
71,550,633
71,153,056
57,604,582
64,785,378
55,603,780
40,395,235
41,758,560
38,069,603
1990
63,607295
61,662,671
68,460,561
64,695,866
49,641242
54,801,677
49,664,068
32,710,735
28,697,713
27,231,347
Three Year Change
(wy) pa
-21,283,496 -25.01
-22,855,957 -27.04
-15,526,376 -18.49
-10,361,810 -13.77
-20,386,623 -29.11
-6,259,650 -1025
-6,594,165 -11.72
-18,433274 -36.04
-18,685,474 -39.43
-19,984,594 -4233
2-3
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Total Emissions - In Million Pounds Per Year
150 ;:„
140
130
120
110
100
90
80
70
60
50
40
30
20
10
•• figure M "':':
Three Year Change In Emissions
2p Cote 376-IN
zip code 775-ix
2p Code 365-Al
2)pC*l«707-lA
Zip Code 996-AK
Zip Code 365-Al
1987
1988
1989
1990
REGIONAL HOT SPOTS
ZIP Code Areas
The linked data set was
reviewed to identify regional
"hot spots" that report high
levels of emissions. Figure 2-
3 and Table 2-3 show the three-
digit ZIP Code areas reporting
the greatest emissions. The
Post Office assigns ZIP Codes
roughly in proportion to the
population of a geographic
area. The first three digits of
the ZIP Code are assigned to
transportation hubs that also
are centers of economic activi-
ty. Evaluating emissions by
three-digit ZIP Code may then
identify areas where large
emissions and population cen-
ters are coincident.
Since three-digit ZIP Code
areas are relatively small geo-
graphically, their total emissions
often are dominated by a single
facility. Among the ten top
areas only 775 in Texas and 481
in Michigan had more than 100
reporting facilities. About 70%
of the emissions reported in
area 840 in Utah were reported
Table 2-3
Regional Hot Spots
— TOP 20 3-DIGITZIP CODES -1987 BASIS—
Wigii
Zip
Code SHU
840 UT
775 TX
376 TN
365 AL
703 LA
700 LA
996 AK
797 TX
776 TX
707 LA
Amount Emitted (Ib/yr)
1987
80.260,510
74,200,063
53,031.565
46,542,835
44,019,671
30,737,521
30,551,825
29,033,876
25,731.849
22,255,031
1988
115,533,035
62,055,500
53,865,615
49,644,636
56.378,839
14,436,097
20,958,860
3,825,542
24,876,096
21,217,431
1989
121,797,804
65,001,349
56,589,700
49,486,002
53,648,655
8,182,294
18,604,215
5,273,633
21,189,721
18,298,938
1990
97,449,460
52,315,406
52,673,030
50,923,247
23,047,199
20,364,832
13,835,648
5,107,048
20,068,027
16,505,353
lira Year Change 3-digit
Zip
(iwyr)
17,188,950
-21,884,657
-358,535
2,380,412
-20,972,472
-10,372,689
-16,716,177
-23,926,830
-5,663,822
-5,749,678
Pa
21.42
-29.49
-0.68
4.90
-47.64
-33.75
-54.71
-82.41
-22.01
-25.84
Code Stale
480 Ml
779 TX
286 NC
706 LA
377 TN
314 GA
356 AL
244 VA
371 TN
723 AR
1967
21,428,949
21,265,124
20,699,329
20,015,906
19,455,819
19,188,412
18,905,338
18,476,345
17,753,155
17,304,014
Amount Emitted (Ibftr)
1988
15,440,706
8,073,149
18,415,056
15,985.729
19,587,362
19,318,987
15,611.697
19,602,514
17,921,402
16,182,296
1969
14,385,269
5,315,839
17,070,188
14,634,086
28,107,058
16,326,594
17,966,859
13,326,394
17,677.507
14,355.290
1990
6,944,729
4,831.852
15,452,553
11,418,692
26,41£907
13.124,755
15,440,808
11,582.074
16.491,564
5,509,033
T h me Y« Change
(KM Pd
-14,484,220 -67.59
-16.433.272 -7758
-5,246,776 -25.35
-8,597,214 -4195
6,957,088 35.76
-6,063,657 -31.60
-3,464,530 -18.33
-6,894,271 -37.31
-1.261.591 -7.11
-11.794,981 -68.16
2-4
-------
by a single facility. Area 703 in
Louisiana, number five on the
list, included only 16 facilities,
the fewest number of facilities
for any ZIP Code area.
REGIONAL HOT SPOTS
Counties
Counties, more familiar bound-
aries, typically cover a smaller
geographic area than three-digit
ZIP Codes. Figure 2-4 and Table
2-4 show the counties reporting
the greatest emissions. Counties
most frequently are dominated by
only one or two facilities. Asa
result, it is more difficult to dis-
cern trends. One very large facil-
ity with large emission increases
or decreases can mask significant
changes taking place in several
other facilities in the same coun-
ty. Ascension Parish, Louisiana,
Kenai Peninsula, Alaska, and
Ector County, Texas all reported
emission decreases of more than
16 million pounds. The decrease
in Ector County, an 88% drop,
probably reflects a reporting error
in 1987 rather than a true
decrease in emissions.
Coutrty SUt
1M7
Amour* Emitted (bta)
1US 1MO
Three Year Change In Emissions
Total Emissions- In Million Pounds Per Year
1DU •XVX-XVM-X.M.X.XV:-:-:-:-:
140
130
120
110
100
90
80
70
60
50
40
30
20
10
0
T«»t«,UT
Mobile. H. •
1987
1988
1989
1990
Table 2-4
Regional Hot Spots
— TOP20 COUNTIES -1987BASIS—
1000
ThryeVMrCtunfle
Pet
County SWe
1M7
Amount Emitted (H/yrt
1888 18N
1MO
Three YMrOunge
(Ibiyr) Pel
Tooele UT
Ascension LA
Mobile AL
Hants TX
Sullivan TN
Cook IL
Kenai
Peninsula AK
Los Angeles CA
Edor TX
Jeflercon TX
76,989,600
53,169,833
49,936,678
49,047,229
42,058.444
30,816,250
30,551,825
30,499,813
27,421.333
22,003,740
109,867272
51,213273
50,479,785
45,473,832
42,634,881
29,376,092
20,958,860
32,129,171
2,211.643
18,392,433
119207,748
62,454,882
50,212,530
43,689,922
42,365,300
32,489,055
18,604,215
29,691,926
3,473,153
16,679.190
95.171,481
30,789,313
50,619233
31,618,810
37,656,526
29,626,135
13,835,648
25,486,075
3,315,692
15,826,602
18,181,881 23.62
-22,380.520 -42.09
682,555 1.37
-17,428,419 -35.53
-4,401.916 -10.47
-1.190,115 -3.86
-16,716,177 -54.71
-5,013,738 -16.44
-24,105,641 -87.91
-6,177,138 -28.07
Brazoria TX
Chatham GA
Calcasieu LA
Calhoun TX
Alleghany VA
Mississippi AR
sum LA
Hambten TN
McLeod MN
Lake IN
21.623.595
19.188.412
18.788,259
18.123,053
17.845.769
17242.395
16.239.492
16,181.264
15.591.355
15,025.811
17.972,406
19,318,987
15,225,083
5,369,523
19,009264
16,125232
15,408,007
16,294219
16,567.333
11,021,400
18,053,425
16,326,594
13,916,509
3,588,587
10,042,999
14,288,567
931,727
24,916,031
25,782,061
10.069,351
15,784,026
13,124,755
10,673,131
3,018,795
8,177,060
5,424,839
15,084,391
23,604,411
20208,526
11229,390
-€,039,569 -27.67
-6,063,657 -31.60
-8,115,128 -43.19
-15,104258 -83.34
-9,668,709 -54.18
-11,817,556 -68.54
-1,155,101 -7.11
7,423,147 45.87
4,617,171 29.61
-3,796,421 -2527
2-5
-------
Table 2-5
Top 20 Chemicals
—1987 BASIS—
Amount Emitted (Ityr)
Chemical
Ammonia
Toluene
Metanol
Acetone
1.1.1-TikNoralMe
MeWBylKetoM
Xytene
(Mixed homers)
OtchkxomefHne
Chlorine
Carbon Disullide
Aluminum
(Fume Or Oust)
Hydnxhlonc Acid
Etylene
Freon 113
TritHorotthylene
fSrmi itfmm
PropyMne
GrycdEtas
Benzene
n-BuKd Alcohol
Tetrachkxoetiylene
1987
277,388,831
251,982,231
196,559,936
177,750,109
140,163,526
138,251,483
126,876,481
110,954.722
105.001,108
85,913,732
81,574,716
70,395,841
59.766,006
49,479,901
47,484,928
38,686,477
37,515,524
30,633,229
29,157,749
28,769,776
1988
237,606.361
243.792,436
203,806,647
175.215.296
145,564,167
118,087,703
131,418.148
102.158.498
132,890,733
88,522.526
2,831.694
65.104,444
42,394,117
57,244,514
45,722,543
23,807,387
42,985,363
28.548,426
32,376,359
29,736,927
1989
226,977.094
229,026,603
184,231.445
175,168.870
138,238,967
117,346.230
129,162.509
93,270,030
132.027,251
98,431.764
1.527,480
69.358,736
41,853,869
52,248,201
41.277,631
23.898,179
42.329,635
25.070,583
32.149,145
22.362,024
1990
181,697,260
199,512,073
165.049,027
157,837,161
124,183,587
105,467,819
115.499,330
79,038,482
104,239,889
96,954,830
1,315.171
67,294,145
34,588,353
35,911,342
32,616,922
21,014,890
39,409,230
23.226,968
28,264,184
17,574,604
It™ Yar Change
(IbAr) Pd
-95.691,571
-52.470,158
-31,510,909
-19,912.948
-15,979.939
-32,783,664
-13,377.151
-31.916240
-761219
11,041.098
-80^59,545
-3,101,696
-25,177,653
-13.568,559
-14,868,006
-17,671,587
1,893,706
-7.406.241
-873,565
-11,195,172
-34.50
-20.82
-16.03
-11.20
-11.40
-23.71
-10.38
-28.77
-0.72
12.85
-9839
-4.41
-42.13
-27.42
-31.31
-45.68
5.05
-24.18
-3.00
-38.91
Chemicals
Figure 2-5 and Table 2-5
show reported emissions of
the individual chemicals
reported in the greatest
amounts. The emission quan-
tities represent national totals.
The chemicals listed general-
ly are common industrial
feedstocks and solvents. For
most of them reported emis-
sions are steadily decreasing
between 1987 and 1990.
Emissions of two of the top
chemicals shown in Figure 2-
5, chlorine and carbon disul-
fide, show little or no
decrease over the four-year
period. Emissions of both of
these chemicals are dominat-
ed by a single large facility.
In both cases, more than 50%
of the national total is report-
ed by a single location.
Total Emissions in Million Lbs/Year
300
Figure 2-5
Top 10 Chemicals
—1987 BASIS —
Atmonii
• Methyl Ethyl Ketone
" Mixed homers
Toluene
Melhanol
Acetone 1.1.1-Tridiloroetrar*
Xylene* Dichloromethine Chlorine Clrton Deulfide
2-6
-------
Hazardous
Air Pollutants
The Clean Air Act
Amendments of 1990 listed 189
individual chemicals as haz-
ardous air pollutants (HAP).
All 189 chemicals are listed in
Table 4-5 in Section 4 (As
noted in Table 4-5,16 of the
HAP chemicals are not covered
byTRI). Figure 2-6 and Table
2-6 show the HAPs with the
largest reported emissions.
Major sources of emissions of
each of these chemicals will be
regulated under the Clean Air
Act in the future. The emis-
sions reported to date serve as a
useful baseline to measure
future reductions once the new
regulations are in place. While
most of the chemicals already
are showing a downward trend,
significant reductions are
expected in the future.
Table 2-6
Top 20 Hazardous Air Pollutants
—1987 BASIS —
Amount EmitW(lb/yr)
Chemiol
Toluene
Mdhanol
1,1.1-Trichlw octane
Metiyl Etiyl Ketone
Xytene (Mixed Isomers)
DKhkxometane
Chlorine
Carbon Disulfide
Hydrochloric Acid
TricHoroetiylene
GlycolElBn
Benzene
TtMtooetyM
MdhyllsobutylKelone
Slyrene
Mantua
CarbonylSulfide
ElytoieGlycol
Fonraldchydc
Chkxomdhane
1967
251,962.231
196.SS9.936
140.163.S26
138,251,483
128.876.461
110.954.722
105,001.106
85.913.732
70,395.841
47,484.928
37,515.524
30,633,229
28.769.776
27,189,624
26,438.085
24.034.760
22.459.520
14.378.138
12,359.020
12,068.836
1988
243,792,436
203,806,647
145,564,167
118,087,703
131.418,148
102,158,498
132,890,733
88.522.526
65,104.444
45,722,543
42,985,363
28,548,426
29,736,927
27,905,037
24,556.434
23.256,805
19.554.837
12.565,574
10,338,268
10.837.852
1989
229,026,603
184,231.445
138,238,967
117.346,230
129,162.509
93,270,030
132,027,251
98,431,764
69,358.736
41.277,631
42,329,635
25,070,583
22.362,024
28,030,679
21.937,401
24,438,028
17.798.541
11,756.072
11.398.634
9,318.569
1990
199,512,073
165.049,027
124,183.587
105,467,819
115,499.330
79,038,482
1W.239.889
96,954,830
67,294,145
32,616,922
39,409,230
23,226,988
17,574,604
24,025,550
21,164,693
21,549,202
18,463,675
8,159,622
10,664,037
7,326.285
ThiwYar Change
(Ityr) Pd
-52,470.158
-31,510,909
-15,979.939
-32,783,664
-13,377,151
-31,916.240
-761,219
11,041,096
-3.101,696
-14,868,006
1,893,706
-7,406,241
-11.195,172
-3,164,074
•5,273.192
-2.485,558
-3.995.845
-6,218.516
-1,694,983
-4,742,551
-20.82
-16.03
-11.40
-23.71
-1038
-28.77
-0.72
12.85
-4.41
-31.31
5.05
-24.18
-38.91
-11.64
-1995
-10.34
-17.79
-4325
-13.71
-39.30
Figure 2-6
Top 10 Hazardous Air Pollutants
—1967 BASIS —
Total Emissions in Million Lbs/Yn
300 aBse^smsffiffissffiM
1987
1966
D 1989 D 1990
Toluene
• Methyl Ethyl Mone
" Mixed toners
1.1,1-Tridilorrjethine
MET
Xylene" DichtoromeOane Chlorine Cjrtxxi Diulfide Hydrochloric Add Trichtoraethylene
2-7
-------
Table 2-7
EPA 33/50 Program Chemicals
-1987 BASIS-
Chtmol
Toluene
UI-TiUtaMlMe
MetyEtylKelone
XytenefMaed boron)
DKNorometane
TrichkHoetiylene
Baiwie
Tetrachlofoet>ylene
Metyl totally! Ketone
Chtorotoim
p-Xyto*
Carbon Tetrachlonde
o-Xytene
m-Xylene
Cyanide Compounds
Lad
Lad Compounds
Chromium Compounds
Nickel
Chromium
Nickel Compounds
Cadmium Compounds
Merany
Cadmium
Mocury Compounds
1967
251,962,231
140,163.526
138,251,483
128,876,481
110,954,722
47.484,928
30,633,229
28,769,776
27.189,624
24.034,760
7.437.936
4,334,230
3.606.212
2,995.819
1.402,741
1.233,373
1.104,599
730.014
332,126
334.776
296,704
151.547
23.158
11.021
1,586
Amount Emi
1MB
243,792,436
145,564.167
118,087,703
131,418.148
102,158.498
45.7Z2.543
28,548,426
29.736.927
27,905,037
23.256,805
6,003.302
3,640.586
2,064,641
2.194,146
878,066
961,328
1.379,549
684,338
244,249
367,520
221.064
86,443
23.145
15.472
1,616
WOhfyr)
19B9
229.026,603
138,238,987
117,346,230
129,162,509
93,270,030
41.277,631
25,070,583
Z2.362.024
28.030,679
24.438,028
4.933,722
3,290,440
1.808,306
1,200,771
814,061
756.502
1,326.054
1,250.261
253,515
265,936
202,245
73,745
24,007
22,414
3254
1990
199,512,073
124,183.587
105,467,819
115,499,330
79,038,482
32.616.9Z2
23.226.988
17,574,604
24.025,550
21.549202
4.752.672
1,646,835
1.904,571
1202.284
1.127,652
769,669
1,515,828
570.905
289245
175,764
187,392
84,596
21.639
6.721
898
Three Year Change
(ihfyr) Pa
-52.470.158
-15.979,939
-32.783,664
-13,377,151
-31,916.240
-14,868.006
•7.406241
•11.195.172
-3,164,074
-2,485,558
-2,685264
-2,687.395
-1,703.641
•1,793.535
-275.089
-463.704
411229
-159.109
-102.881
-159,012
-109,312
-66.951
•1.519
-4.300
-688
-20.82
-11.40
31.08
-10.38
-28.77
-31.31
-24.18
-3891
-11.64
-10.34
-36.10
-62.00
-47.22
-59.87
-24.39
-37.60
27.13
•27.87
-2624
•47.50
-58.33
-79.14
•6.56
-39.02
-7662
33/50 Program
Chemicals
Under a voluntary program,
the EPA Administrator has
asked industry to reduce the
emissions of seventeen chemi-
cals, mostly solvents and met-
als. Figure 2-7 shows the
reported emissions for the top
ten chemicals between 1987
and 1990. Table 2-7 lists the
reported emissions for all of
the chemicals covered by the
program. Under this program,
companies were asked to
reduce their emissions of these
chemicals 33% by 1992 and
50% by 1995. Again, the data
presented represents a base-
line of emissions rather than
the impact of the program
since significant results are
not expected before 1992.
Total Emissions in Million Lbs/Year
300 :,.*.:.
250
Figure 2-7
Top 10 EPA 33/50 Program Chemicals
—1987 BASIS —
Toluene 1,1.1-Ti
' Miudlumn
" Methyl tobulyl Kflone
Xylene' OcMoromettane Tnchfcroetnylene Benxne lelrxhloraettiyiene MK"
CNorakmn p-Xytene
2-8
-------
High Risk/Early
Reduction
Figure 2-8 and Table 2-8
show emissions of those
HAPs that EPA has prelimi-
narily identified as high risk
substances for the purpose of
theEarly Reduction Program.
These high risk substances
receive a higher weighting in
determining whether a
source has met its 90%
reduction target. The 35
high risk substances are list-
ed in Table 4-7. Like the
other chemical groupings
discussed in this report, there
are no regulations, specific to
this group, currently in place
that require industry to
reduce their emissions. As
such this data serves as a
baseline for evaluating pro-
gram progress in the future.
Table 2-8
Top 20 High Risk/Early Reduction Chemicals
-1987 BASIS—
Amount Emitted (Ib/yr)
Cherried
Beiuene
1.3-BularJene
Acrytonibile
Bhylene Oxide
Vinyl Chloride
Acrylic Acid
(Phenylisocyanale)
ChromuTi Compounds
Tokjene-2,4-Diisocyanale
Vinylidene Chloride
Chloroprene
Arsenic Compounds
Cadmium Compounds
Meliyllsocyanale
1,1,2,2-Telrachlorodhane
Phosgene
U-Dibromoetene
Actotdn
Asbestos (Friable)
NbHriuM
1987
30.633.229
9.383.347
5.380.510
4,183.635
1.568.004
821.770
792.813
730.014
611.310
465.969
282.135
270.853
151.547
143.237
103.740
83.534
65.119
48.654
42,266
36,158
1968
28,548,426
6,622,693
4,182,336
3,747.481
1.292.466
784,265
144,864
684,338
141,009
295.745
423,513
198,821
86,443
9,425
43,685
21,532
63277
33,596
35225
36,227
1989
25,070,563
5.664,918
4.106.690
2.646.726
1.132,240
348,271
183,698
1,250,261
71,133
220,042
303,087
154,185
73,745
13,948
34,778
8261
59,167
20,075
28,607
41,140
1990
23,226,988
4,955.664
2.877.318
1,967,894
1.064.839
396,046
280.237
570,905
33,062
301,292
172,692
154,516
84,596
14,123
34,452
4.853
57.830
22.017
13,313
26,468
Three Year Chinoe
(|b/yr) Pa
-7,406,241
-4,427,683
-2.503.192
-2215.741
-503.165
-425,724
-512,576
-159,109
-578,248
-164,697
-109,443
-116,337
-66,951
-129,114
-69288
-78,681
-7289
-26,637
-28,953
-9,690
-24.18
-47.19
-46.52
-52.96
-32.09
-51.81
•64.65
-21.80
-94.59
-35.34
-38.79
-42.95
-44.18
•90.14
-66.79
•94.19
-11.19
-54.75
•68.50
-26.80
Figure 2-8
Top 10 High Risk/Early Reduction Chemicals
—1987 BASIS—
Total Emissions in Million Lbs/Year
35 «
Benzene
1.3-Buttdier*
Aoylonitrile
Elhylene Oxide Vinyl Monde
Acrylic Acid
Melhylenebis
(Ptienyhsocyjfiite)
Chromium
Compounds
Toluene-2,4- Vinylidene Chloride
Brsocyinjle
2-9
-------
Table 2-9
Top 20 Carcinogenic Chemicals In TRI Database
—1987 BASIS —
Amount Emitted (KM
ChHHBB
DUtaoMfaM
TrkHwoetiytate
Benzene
Tetnetikxodhyleite
Styiene
Chloroform
Fonrakfchyde
ChJoromotww
OBuhfcM
U-DkrtoroetBne
Acrytonitrile
Carbon Tdiachkxide
Ettylm Oxide
t.U-Tridtoatlm
Vinyl Chloride
Uietane
VinylKkne Chloride
Epichlorohydriii
CnVMMI
2-Ntoopropane
1967
110,954,722
47,484,928
30,633,229
28,769,776
26,438,065
24,034,760
12,359,020
12,068,636
9,383,347
6,196,495
5,360,510
4,334,230
4,183.635
1.975,207
1.568,004
796.000
465.989
420.988
334,776
275,202
1968
102.158,498
45.722,543
28.548,426
29.736,927
24.556,434
23,256,805
10,338,268
10,837,852
6.622,693
4.280,244
4.182,336
3.640,586
3,747,481
1,710,892
1.292.466
144.373
295,745
464,009
367,520
274.360
1989
93.270,030
41,277,631
25,070,583
22,362.024
21,937,401
24,438.028
11.398,634
9.318,569
5,664,918
4,107,894
4,106,690
3,290,440
2,646,726
742.098
1,132,240
3,450
220.042
471,099
265,936
225.222
1990
79,038,482
32,616,922
23,226,988
17,574,604
21.164,893
21,549,202
10,664,037
7,326,285
4,955,664
5,059,732
2,877,318
1,646.835
1,967,894
579,198
1.064,839
3,310
301.292
383,522
175,764
16.258
Thru Var Chinge
(Ityr) Pd
•31.916.240
-14.868.006
-7,406,241
-11.195.172
-5,273,192
-2,485,558
-1,694,983
•4,742,551
-4,427,683
-1,136,763
-2,503,192
-2,687,395
-2.215.741
-1,396,009
•503,165
-792,690
-164.697
-37,466
-159,012
-258,944
-28.77
-31.31
-24.18
-38.91
-19.95
-10.34
-13.71
-39.30
-47.19
-18.35
-46.52
-62.00
-52.96
-70.68
•32.09
-99.58
-35.34
-8.90
-47.50
-94.09
Carcinogens
Fifty three of the chemicals
in the TRI database are
known or suspected human
carcinogens. Figure 2-9 and
Table 2-9 summarize the car-
cinogens emitted in the
greatest amount. There is a
clear downward trend of car-
cinogen emissions over the
four year period. Since
many of these chemicals are
or will be covered by specif-
ic EPA programs designed to
reduce chemical emissions,
further reductions are expect-
ed in the future.
Total Emissions in Million Lbs/Year
120 .X^MWKKKWKSKMWMI^
Figure 2-9
Top 10 Carcinogenic Chemicals In TRI Database
—1987 BASIS —
1987
Trictitoraelriylene Beirene letrachloroethylene Slyrene Chloroform Formaldehyde Chloromahane 1,3-ButJdiene U-Dirtloraetrane
2-10
-------
Ozone Depleting
Chemicals
The TRI database covers three sub-
stances that react with stratospheric
ozone to contribute to destruction of
the ozone layer carbon tetrachlo-
ride, 1,1,1 trichloroethane, and freon
113. Figure 2-10 and Table 2-10
show the reported emissions of these
substances. Several other chemicals,
which are known to attack the ozone
layer, such as halons and other freons,
are not covered by the TRI database.
Several of these additional substances
were added to the TRI reporting list
after the 1989 reports were submitted.
The first reports of these additional
chemical will appear in the 1991 data.
Production and use of these sub-
stances are being phased out by
Executive Order and as a result of
regulations from the Clean Air Act
The 1987 to 1990 data serves as a
baseline against which future emis-
sion reductions can be measured.
Table 2-10
Oione Depleting Chemicals In TRI Database
-1987 BASIS—
Chemkal
1967
Amount MM (JMM
1968 1989
Three Year Change
1990
UMHEHMUfaM 140,163,526 145,564,167 138,238.987 124.183.587 -15,979,939 -11.40
Freon 113 49.479,901 57,244,514 52,248,201 35.911.342 -13,568,559 -27.42
Carbon TetocMori* 4,334.230 3,640,586 3,290.440 1,646.835 -2,687,395 -62.00
Figure 2-10
Ozone Depleting Chemicals In TRI Database
-1987 BASIS-
Total Emissions in Million Lbs/Year
160
1.1,1-Irichloroelhjne Freon113 Carton Isnctiloride
2-11
-------
-------
SECTION 3
Annual
Toxic Air Emissions
This section summarizes the TRI reported
emissions for 1990,1989,1988, and 1987.
The same data is reported for each year for
easy reference and comparison. As noted
in Section 1, the Basic data set was used
for the analysis in this section. This is
different from the Linked set used for
Section 2 analysis.
Emission "hot spots" are reported first by
EPA region, followed by successively
smaller geographic areas; states, three-
digit ZIP Code areas, and county. Data on
emissions by industry type (SIC Code) is
presented next. Emissions of groups of
individual chemicals also are shown.
These groups are intended to highlight
targets of EPA programs. Special attention
has been paid to the 189 hazardous air
pollutants listed in Title ffl of the Clean
Air Act Amendments of 1990. (Only 172
of the 189 listed chemicals are covered by
the TRI data. Fewer than 172 HAPs are
listed in these tables because no air
emissions were reported for approximately
25 chemicals each year.). Each chart or
table is accompanied by a table in the
appendix providing additional detail.
3-1
-------
1990 EMISSIONS
EPA Regions
Figure 3-1 and Table 3-1 break out the reported
emissions by EPA region. Nationally, 2.2 billion
pounds of toxics were emitted by 20,270
facilities. Regions 4,5, and 6 reported the
greatest emissions with 28%, 22%, and 15% of
the total respectively. These three regions
also had the greatest number of facilities
reporting, although Region 6 was only
slightly ahead of Regions 2,3, and 9 in
number of facilities.
Figure 3-1
EPA Regional Hot Spots
— 1990—
Itoglral
1.876 195 8.9%
Hllkonltt OTMI
100-150
150-250
250-500
500-670
Table 3-1
Regional Hot Spots
—1990 EPA REGIONS —
EPA
Region
04
05
06
03
08
No. Of
Reports
12.272
17.882
8.125
6.292
1.220
No. Of
FKilitiM
3,911
5,350
1,954
1,876
404
HAP
EnMaM
(MM
451,979,692
377,044,718
165,785,506
146,070,884
120,591,961
Totil
EtniMiora C
(iwyr)
604,078,286
464,261,829
329,950,107
194,601,413
130,841,870
Region %
it Total THI
EmiMionf
2752
22.06
15.03
8.87
5.96
EPA
Region
07
02
09
10
01
No Of
Release
Report!
3,900
5,224
5,270
1,816
3,675
fSCTfi
No. Of
FjciStiet
1,229
1,697
1,852
613
1.364
9fl 970
HAP
EmiHiane
WlO
89.394,965
73.735,183
64.451.597
OC OCQ 4CQ
OO,JO9,£D:f
50.291,721
1 <;7<; 71 s toe
Totil
Emiswont 0
(itcy)
127,925,832
97,668,390
93.125,814
67.120,142
65,348,914
9101 on «MT
Region %
TotelTRI
imiKiont
5.83
4.45
4.24
106
2.98
imnn
3-2
-------
1990 EMISSIONS
States
Toxic air emissions reported
in the states are shown in
Figure 3-2 and Table 3-2.
Generally the states
reporting the greatest
emissions are the industrial
states in the Northeast,
Great Lakes, Middle
Atlantic, and Gulf Coast,
along with California. The one
exception is Utah, which is
dominated by one facility with
very large emissions. Texas
ranked first with reported
emissions of 162 million
pounds, equivalent to 7%
of the national total.
Figure 3-2
Toxic Air Emissions By State
—1990—
Table 3-2
State Total Emissions
—1990—
Stite
AK
AL
AR
AS
AZ
CA
CO
CT
DE
FL
GA
HI
IA
ID
IL
IN
KS
KY
LA
MA
MD
ME
Ml
MN
MO
MS
MT
No. Of
fielMW
Report!
44
1.423
979
2
452
4,683
463
1.067
234
1.214
1.847
57
952
144
4.051
2.713
739
1.334
1.441
1.513
623
305
2.964
1.163
1.790
895
113
NO. a
fjcihtw
7
404
329
2
161
1,640
168
392
64
471
622
12
332
48
1.220
806
226
348
266
566
193
97
615
432
SIS
264
25
HAP
Emwtwra
(Wl
1,258,970
91,462,935
22,229,372
0
6,826,457
56,627,360
4,317,672
14,502,096
5,348,155
20,179,293
57.094,042
395,800
24,692,826
2,163,610
68,051,331
84,601,343
17.806.915
32.764,624
42,444,330
15,910,439
10,895,032
9,352,842
63,784,825
43,124,619
35,582,816
37,795,682
1,748,256
Total
Emwiont
(Ib/yr)
14,974,077
100,003,159
31,198.124
19,300
12,982,871
78,720,752
6.720,962
17.163.S46
6.017,850
45,146,178
7Z373.750
680.611
38,069,638
5,684,535
67,820,948
107,618,816
28,818.281
40,537,717
105.855,063
20.472,219
12,907,327
13,696,471
84,475,079
49,643,597
44,258,618
55,446,967
2,476,359
State %
OITotilTRI
Emissions
0.68
4.56
1.42
0.00
0.59
3.59
031
0.78
027
2.06
330
0.03
1.74
026
4.00
4.90
131
1.85
4.82
0.93
0.59
0.62
3.85
226
2.02
2.53
0.11
State
NC
ND
NE
NH
NJ
NM
NV
NY
OH
OK
OR
PA
PR
Rl
SC
SD
TN
TX
UT
VA
VI
VT
WA
W1
wv
WY
No. Of
RelMM
Report!
2,428
75
419
311
2,449
146
76
2,322
. 4,887
656
679
3,487
432
389
1,458
79
1,673
4,903
394
1,379
21
90
949
2,104
569
96
65,676
No. Of
Ficjlrti«
846
28
156
132
732
41
37
815
1,411
217
230
1,079
149
160
408
46
548
1.101
115
424
1
37
328
664
116
22
20,270
HAP
Ernissions
OHM
70.146,608
1,561,291
11,312,408
5,690,259
17,454,952
936,351
601,960
45,809,849
84,313,441
14,426,664
13,353,144
55,755,117
9,484,611
4,110,106
48,778,408
2,046,948
93,758,100
85,748,789
110,211,863
53,166,029
985,771
725,977
19,593,545
33,169,159
20,906,551
705,931
1,575,715,496
Total
Emitsions
(IWyr)
86,595,680
2,006,352
16,759,295
7,937,403
24,304,137
2,465,120
722,280
56.886,344
113,594,102
28,046,095
18,313.715
72.487,569
15,265,444
5,197.873
64,757,916
2,884,555
139,216,919
162,385,705
112,435,864
75,291,739
1.212,465
881,402
28,147,815
41,109,287
27,896,928
4,317,778
£194,922,597
Stall %
Of Total TRI
Emitciom
3.95
0.09
0.76
0.36
1.11
0.11
0.03
2.59
5.18
1.28
0.83
3.30
0.70
0.24
2.95
0.13
6.34
7.40
5.12
3.43
0.06
0.04
1.28
1.87
1.27
0.20
100.00
3-3
-------
1990 EMISSIONS
Three-Digit ZIP Code Areas
Since ZIP Codes are assigned generally
according to population, three-digit ZIP
Code areas represent convenient geographic
areas smaller than states. Figure 3-3 and
Table 3-3 show the top 20 ZIP Code areas.
Area 840 in Utah reported the greatest
emissions with nearly 5% of the national
total. The top 20 areas together reported
25% of the national total.
Figure 3-3
20 ZIP Code Areas With Greatest Toxic Air Emissions
—1990 —
STATE t WJKS/TZF CODE
1.UT...840 4.AL...365 7. MN... 553
2.TX...775 5.TN...377 8. LA.. TOO
3.TN...376 6. LA... 703 9.TX...776
10.NC...286
11. TN... 371
12. LA... 706
13. L... 606
14. LA... 707
15. MS... 391
16.AL...356
17.VA...241
18. W... 465
19.NC...284
20.AK...996
State
Table 3-3
3-Digit ZIP Codes
—1990-
No. 01 HAP
Rttom No. Of Emwont
R«port» haitm (tVyr>
Totil ZIP%
Emtennt 0) Total TRI
840
775
376
365
377
703
553
700
776
286
UT
TX
TN
AL
TN
LA
MN
LA
TX
NC
163
1,234
158
191
89
70
189
328
246
451
43
137
32
31
36
14
69
53
28
144
99,536,894
25,902,429
18,697209
50,256,060
26,827,726
1,055,326
21,554,465
4,412,128
8,957230
15,420,673
100,849,411
57,469,488
53,092,595
51,037,042
27,019,504
23,143,897
22,511,087
21,760,019
20,150,787
18,602,667
4.59
2.62
2.42
2.33
1.23
1.05
1.03
0.99
0.92
0.85
ZlP&xto
371
706
606
707
391
356
241
465
284
996
Slit*
TN
LA
IL
LA
MS
AL
VA
IN
NC
AK
No. 01
Rrtette
Report*
181
203
904
352
49
199
117
352
106
22
No. Of
FadlitiM
50
28
285
38
21
49
33
137
27
4
HAP
EmMon)
(IkWD
16.527,463
6,470,824
12,679,529
9.647290
3,101298
13,921,610
3,624,169
13,275,575
13,043,199
327,394
Total
EntiMtom «
(IWyO
18,117,226
16,862,650
16,822,780
16,621,716
16,371.227
15,956,127
15,762,380
15,376,861
14,305,755
13,835,898
ZIP*
Total TRI
.m»fwni
0.83
0.77
0.77
0.77
0.75
0.73
0.72
0.70
0.65
0.63
5,604 1.259 365,238,491 555,869.117
25.33
3-4
-------
1990 EMISSIONS
Counties
Figure 3-4 and Table 3-4 show the 20
counties with the greatest emissions. Again,
Utah had the county reporting the greatest
emissions. Together the top 20 counties
reported 23% of the total national emissions.
Four of these counties included more than
100 facilities while six had fewer than ten.
The distribution of counties reporting the
largest emissions generally reflects the same
geographic concentration as the state and
ZIP Code areas, with the large emission
reports coming from the industrial areas.
Figure 3-4
20 Counties With Greatest Toxic Air Emissions
COUNTY AHD STATE
1.Tooele,UT 4. Harris, TX
2. Mobile, AL 5. Cook, L
3. Sullivan, TN 6. Ascension, LA
7. Los Angeles, CA
8. Hambten.TN
10. BrazoriaJX
11.Calcasieu.LA
12. Jefferson, TX
13. St. James, LA
14. Kenai-Cook
Inlet. AK
15. Chatham, GA
16. Wayne, Ml
17. Salt Lake, UT
16.Yazoo, MS
19. Giles, VA
20. Lake, IN
Table 3-4
Counties
— 1990—
County State
Tooele
Mobile
Sullivan
Harris
Cook
Ascension
Los Angeles
Hamblen
Me Leo)
Brazoria
Ul
Al
TN
TX
IL
LA
CA
TN
MN
TX
No. Of
fW«M
Reportt
a
205
102
1.348
1.800
146
1,900
60
35
232
No. Of
Facilities
4
40
14
234
551
13
634
21
8
22
HAP
Emissions
95,211,736
49,891,576
5,597,485
20,723,405
26,669,597
4,142,097
23,825,820
24,814,689
19,816,689
7,257324
Total County*
EmiKions Ot Total TRI
(Uttyr) Emiujon
95,211,991
50,811,215
37,869,166
37,102,085
33,785,348
30,789,313
30,547,084
25.102,702
20,221,634
16,945,486
4.34
2.31
1.73
1.69
1.54
1.40
1.39
1.14
0.92
0.77
County 1
Cslcasieu
Jefferson
SI James
Kenai Peninsula
Chatham
Wayne
Sail Lake
Yen
Giles
Lake
State
LA
TX
LA
AK
GA
Ml
UT
MS
VA
IN
No. 01
Release
Reports
181
298
38
21
89
608
186
2
a
225
No. Of
Pacilrtie.
22
31
7
3
24
145
48
1
1
42
HAP
Emisikms
(IWyr)
5,740.333
7250.901
246.853
327,394
11,050,637
10,112,592
11,089,889
3,800
1,038,003
9,908,093
Total
EmMom 01
(IWM
16.022,164
15,853,701
15,106,674
13,835,648
13,368,437
12,878,736
12,625,358
12,287,721
11,608,003
11,431,419
County%
Total THI
EmMom
0.73
0.72
0.69
0.63
0.61
0.59
0.58
0.56
0.53
0.52
7,492 1,865 334,719,413 513,403,905
23.39
3-5
-------
Food I
Tobacco [|
Textiles .
Apparel j
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
Figure 3-5
Toxic Air Emissions
—BY U.S. INDUSTRY-1990—
Number Of Emitters
500 1.000 1,500 2,000 2,500 3.000 3,500 4,000
D NaOIEmltirs
• Total Emissions
200 300 400 500 600 700
Total Emissions- In Million Pounds Per Year
800
1990 EMISSIONS
Industries By
2-Digit SIC Code
As shown in Figure 3-5
and Table 3-5, the chem-
icals industry is by far
the largest industrial
emitter with nearly one
third of total national
emissions. Together
with the Pulp & Paper
and Primary Metals
industries, three indus-
tries reported more than
50% of the total. Figure
3-5 shows a comparison
of total emissions with
number of facilities.
This shows that the Pulp
& Paper facilities gener-
ally report high emis-
sions per facility (almost
400,000 pounds per
facility) compared to
2-Digit
SIC Co* U.S. InduiHy
Table 3-5
Air Emissions By U.S. Industry
—7990—
No. Of
Emitters
TotilEmitiwns Indutfiy % Of Total
(bfyr) TRI Emiuioni
2-Digit
SIC Code
U.S. Indmtiy
No. Of
Total Emintora Indmtw % Of Totil
TRIEmiMiora
70
21
??
?1
?4
?5
?fi
?7
?8
29
Food
Tobacco „
Textiles
Apparel
Lumber
Furniture _
Pulp & Paper
Printing
Chemicals
Petroleum Refining
1.245
18
370
38
578
559
618
382
3,988
368
26,825,739
2.475,256
33965,968
1 600,203
35,331,018
60,050,069
243,894677
52033362
691,856,635
70,736,360
1.22
0.11
155
007
161
2.74
11.11
237
31.52
3.22
30
31
32
33
34
35
36
37
38
39
Rubber Plastics
leather „
Stone Clay Glass
Primary Metals
Fabricated Metals
Non-Elecl Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manufacturing
1737
124
573
1746
2.911
1075
1649
1 285
445
381
192,270,498
11845521
21844026
221,864,484
129161415
52614164
81808173
193232254
32456885
24,442,174
876
054
1.00
1011
588
2.40
373
880
148
1.11
3-6
-------
Figure 3-6
Number Of Release Reports
— BY U.S. INDUSTRY-1990—
fabricated metals, for
example, which report a
relatively small amount
per facility (44,000
pounds per facility).
Figure 3-6 and Table 3-
6 show the number of
release reports submit-
ted to EPA for TRI
reporting. Again the
chemicals industry has
nearly one third of the
national total. Each
report represents one
chemical released at a
single facility. Because
the chemicals industry
is such a large part of
the total, additional
details on the industry
are presented below.
U.S. INDUSTRY
Food
Tobacco
Textiles
Apparel j
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather
Stone, Clay. Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments |
Misc. Manufacturing |
0
2,500
5,000
7,500 10.000 12,500 15,000 17,500 20.000
Number Of Release Reports
Table 3-6
2-Doit
SlCCwk U.S. Indwtiy
20
21
22
23
24
25
26
27
28
29
Food
TobXGO,. ., ,
Textiles
Apparel
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
nu. HI n
No. Of
Reteue
R«port»
1,963
24
721
90
1,459
1,842
2,129
723
19,948
2,868
iwpuns uy u.a. innusuy
— 1990—
lndintry%
Of Total 2-Ooit
TRI Report* SICCode U.S. Indintry
1.22
an
1.55
0.07
1.61
2.74
11.11
£37
31.52
3.22
30
31
32
33
34
35
36
37
38
39
Rubber Plastics
Leather... .
Stone Clay Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manulaclurina
No. Of
RebtM
Report!
3,996
302
1,538
5,969
7,511
Z573
4,561
4,686
1,026
942
InduttryX
afoui
TRI Report*
8.76
0.54
1.00
10.11
5.88
240
3.73
8.80
1.48
111
3-7
-------
Chemicals And Allied Products
Industrial Inorganic
Chemicals
Plastics Materials &
Synthetic Resins/Rubber,
Cellulose & Other Man-
made Fibers, Except Glass
Drugs
Soap, Detergents, &
Cleaning Preparations;
Perfumes, Cosmetics, &
Other Toilet Preparations
Paints, Varnishes, Lacquers, aeo- I
Enamels, & Allied Products
Industrial Organic
Chemicals
Agricultural Chemicals
Miscellaneous
Chemical Products
•H
Toxic Mr Emissions By
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200
Total Emissions - In Million Pounds Per Year
1990 EMISSIONS
Industries By
3 And 4-Digit
SIC Code
To subdivide the indus-
trial sector further,
Tables 3-7 and 3-8 pre-
sent the top industries
by 3-digit SIC codes
and 4-digit SIC codes
respectively. The top
ten industries as shown
in Table 3-7 represent
more than 50% of total
emissions. By breaking
it down one level fur-
ther, die top ten 4-digit
industries, as shown in
Table 3-8, reported
37% of the total
Figure 3-7 shows the
toxic air emissions
reported by all of the 4-
digjt chemical indus-
tries. Plastic materials,
industrial organic
chemicals, and agricul-
tural chemicals are the
segments of the indus-
try reporting the majori-
ty of the industry's
emissions.
Table 3-7
Top Industrial Emitters - 1990
3-DIGIT SIC CODES
Mkjt
Rink
1
2
3
4
5
6
7
6
9
10
Code
282
286
287
333
308
371
261
291
281
267
U.S. Industry
Plastics Materials & Synthetic Resins,
Synthetic Rubber, Cellulosic & Other
Manmade Fibers, Except Glass
Industrial Organic Chemicals
Agricultural Chemicals.....
Primary Smelling
& Refining of Nonlerrous Metals
Miscellaneous Plastics Products....
Motor Vehicles &
Motor Vehicle Equipment
Pulp Mills
Petroleum Refining
Industrial Inorganic Chemicals
Converted Paper & Paperboard Products,
Except Containers & Boxes
Total
EmflSy?)
193,055,771
174,560,422
141,278,647
116,063,690
114,405,418
108,166,438
80,195,837
66,770,890
66,563.751
54,084.477
1.115,145.341
012-Oiait
SIC Total
27.90
25.23
20.42
52.31
59.50
55.98
32.88
94.39
9.62
22.18
mdu*tiy%
OfTotalTRI
Emitter*
8.80
7.95
6.44
5.29
5.21
4.93
3.65
3.04
3.03
2.46
50.81
4-001
siir
Rank Code
Table 3-8
Top Industrial Emitters-1990
4-DIGIT SIC CODES
Total IndiBhy* SIGN
EmMm MZ-Oiflit OfTotalTRI
U.S. Indufty (Ibfrr) SIC Code En
1 2869
2 2873
3 3339
Industrial Organic Chemicals,
Not Elsewhere Classified
Nitrogenous Fertilizers
Primary Smelting & Refining of
Nonlerrous Metals, Except Copper
& Aluminum
149,570,880
119,866.933
21.62
17.33
101.574.712 45.78
4 2821 Plastics Malerials.Synlhellc Resins,
6.81
5.46
4.63
s
B
7
8
g
10
7fi11
2911
3711
2823
2621
3089
Pulp Mills.-
Petroleum Refining _ „
Motor Vehicles & Passenger Car Bodies
Cellulosic Manmade Fibers
Paper Mills
Plastics Products,
Not Elsewhere Classified
79,159.992
66,740,635
56,399,188
54,666,806
49492015
42.963.419
821.380,449
32.46
94.35
29.19
7.90
2029
22.35
3.61
3.04
2.57
2,49
2.25
1.96
37.42
3-8
-------
Table 3-9
Chemicals Emitted In the Greatest Amount
—1990 —
Choniol
Toluene
Ammonia
Methane*
Acetone
1.1.1-Trldiloraelhane
Xylene (Mixed Isomers)
Methyl ElhylKelone
Chlorine
Carbon DisullUe
Didibromelnane
No. Of
Emittn
3,943
Z927
uzr
2,683
3,854
3.488
2,494
1.310
79
1,333
ToUl
Emissions
WM
233.183,332
206.585,542
181.736,117
180.207,465
161.300,622
139.944,280
121.284,483
104.888,670
96.222,679
92,469,428
Chemical %
ffl Total TRI
Emissions
10.62
9.50
8.28
8.21
7.35
6.38
5.53
4.78
4.47
4.21
Cumulative
Chemical X
10.62
20.12
26.40
36.61
43.96
50.34
55.87
60.65
65.12
69.33
Ctnmical
Hydrochloric Add
Glycol Ethers
Freonm
Elhylene
Trichloroelhylene
n-Bulyl Alcohol
Slyrene
Methyl Isooulyl Kelone
Benzene
SulluricAad
No. 01
Emitters
2,495
1,704
1,293
263
741
1,185
1,343
1,061
484
3,091
Total
Emissions
-------
Table 3-10
Major Sources
— 1990—
The Number of Facilities Emitting
1 0 TPY of Any One HAP or 25 TPY of Any HAPs
Total %0f NAP*
lOTpy 25 Toy 10 Or 25 EmasKsa Total HAP 01 Total
01 One HAP OtAnyHAPi Toy (Ibtyr) EITOSKTO TnEmssions
6.269
Chemical
Toluene
Melhanol
1.1.1-Trlchloroelhane
Xylene (Mixed Isomers)
Melhyl ElhylKelone
Chlotlne
Carbon Dlstilflde
Dlchloromelhane
Hydrochloric Add
Glycol Ethers
4,230
No 01
Emitteis
3.943
2.427
3.854
3.488
2,494
1.310
79
1.333
2,495
1.704
6,291 1,505.539.990
Table
HAPs Emitted In thi
Total Chemical % '
Emissions OITotll '
(Ib/yi) TRI Emissions ;
233.183,332
181.736,117
161,300,622
139.944,280
121.284,483
104.888.670
98.222.679
92.469.428
73.444,872
46,896,269
1062
828
735
638
553
478
447
421
335
214
9555
3-11
• Greatest Anioi
Chemical
Trlchloroelhylene
Slyrene
Melhyl Isobulyl Ketone
Benzene
Chloroform
Tetrachloroelhylene
CarbonylSulllde
Formaldehyde
Ethylene Glycol
Ethyl benzene
7179
mt
No 01
En tiers
741
1.343
1,061
484
184
598
36
807
1.002
761
Hazardous i
Air Act Ame
chemicals fo
Major source
emit 10 tons
tons of total
imum availa
Table 3- 10 si
ties that wou
according to
tioned earliei
ified in the C
Total Chemical %
Emissions Of Total
(Ib/rr) TRI Emissions
37,849.923
31,630,955
27,311,372
24,013,998
21,762,461
21,624,949
18.634.864
ia765.498
9,375,633
8,604,518
1.466,944,923
172
144
124
109
099
099
085
058
043
039
6683
Table 3-12
33/50 Chemicals Emitted
In Ite Greatest Amount
— 1990—
Chemical
Toluene
1.1.1-Trlchloroelhane
Xylene (Mixed Isomers)
Melhyl ElhylKelone
Dlchloromethane
Trlchloroethylene
Melhyl Isobutyl Ketone
Benzene
Chloroform
Telrachloroelhylene
p-Xylene
o-Xylene
Carbon Tetrachlorlde
No 01
Emitters
3.943
3.854
3.488
2.494
1,333
741
1.061
484
184
598
42
77
88
ton
Emissions
(WO
233.183.332
161,300,622
139.944,280
121.284.483
92.469.428
37.849,923
27.311.372
24,013,998
21.762.461
21.624.949
4.752,672
1,904.571
1.671.092
Chemical * •
Of Total In
Emissions
10.62
735
638
553
421
172
124
1.09
0.99
099
022
009
008 '
Chemical
Lead Compounds
m-Xylene
Cyanide Compounds
Lead
Chromium Compounds
Chromium
Nickel
Nickel Compounds
Cadmium Compounds
Mercury
Cadmium
Mercury Compounds
No 01
Emitteis
647
52
192
611
999
843
840
468
102
34
53
14
8
Totll
Emissions
(IWyr)
1,623.709
1,202.284
1,138,102
860.573
769.517
737,710
654,459
265,421
90.013
22.404
17.037
1.158
96455570
Chemical %
01 Total In
Emissions
007
0.05
005
004
004
003
003
001
000
000
000
000
4083
eredbyTRI). These
6,291 facilities, which
is equivalent to 31% of
the total facilities
reporting, represent
96% of the total HAP
emissions and 72% of
all TRI chemical emis-
sions. Table 3-11 show
the twenty HAPs emit-
ted in the greatest
amount. They repre-
sent two thirds of the
total national toxic
emissions.
33/50 Chemicals -
EPA initiated a volun-
tary emissions reduc-
tion program targeting
17 specific chemicals
(or groups of related
chemicals in some
cases). Reported emis-
sions of these chemicals
are shown in Table 3-
12. Together this group
of chemicals is equiva-
lent to 35% of the total
toxic emissions.
3-10
-------
High Risk/Early Reduction
Chemicals - Table 3-13 lists 20 high
risk/early reduction chemicals.
These chemicals are considered high
risk because of their toxicity.
Together they represented less than
2% of the total national toxics
emissions in 1990.
Carcinogens - Table 3-14 summarizes the
emissions of the 20 carcinogens emitted in
the greatest amount as reported to the TRI.
Their significance is due to their
carcinogenicity. Together the top twenty
represent 12% of total emissions with the
largest carcinogen, dichloromethane or
methylene chloride, just over 4%.
Table 3-13
High Risk/Early Reduction Chemicals
Emitted In the Greatest Amount
Table 3-14
TRI Carcinogens Emitted In
The Greatest Amount
— 1990—
Total Chemical %
No Of Emissions Of Total
Chemical Emitters (IWyr) TRI Emissions
Benzene 484 24.013,998
1.3-Butadlene 158 5.037,331
Aoylonllrile 113 3,147,995
Elhylene Oxide 179 2,447,494
Vinyl Chloride 47 1,135,809
Chromium Compounds 999 769,517
Chromium 843 737,710
Methylenebls
(Phenyllsocyanale) 374 660,906
Acrylic Add 163 426,854
Vlnylldene Chloride 20 303,602
Chloroprene 5 175,134
Arsenic Compounds 215 165,805
Cadmium Compounds 102 90,013
1,2-Dlbfomoelhane 25 58,070
To)uene-2.4-Diisocyanale 97 57,312
Aoylamlde 53 49,968
1.1.2.2-Telrachloroelhane 16 44,596
Dibenzoluran 43 30,225
Hydrazlne 41 27,859
Mercury 34 22,404
39.402,602
Table 3-15
TRI Oione Depletors Emitted
The Greatest Amount
— 1990—
109
023
014
011
005
004
003
003
002
001
001
001
000
000
000
000
000
000
000
000
177
In
Total Chemical %
No 01 Emissions Of Total
Chemical Emitters (Ib/yr) TRI Emissions
1,1,1-Trtchloroelhane 3,854 161,300,622
Freon113 ) 1,293 45.208,966
Carbon Telrachjorlde 88 1.671.092
735
206
008
Total Chemical %
No 01 Emissions Of Total
Chemical Emitters (IrVyr) TRI Emissions
Dlcfiloromelhane 1,333 92.469.428
Trlcriloroelhylene 741 37.849.923
Slyrene 1.343 31.630.955
Benzene 484 24.013.998
Chloroform 184 21.762.461
Tetrachloroethylene 598 21.624,949
Formaldehyde 807 1Z765.498
! Chloromelhane 88 7,373.241
1,2-Dichloroelhane 97 5.595.973
1.3-Buladlene 158 5.037.331
i Acrylonllrlle 113 3,147,995
Elhylene Oxide 179 2.447.494
• Carbon Tetrachlortde 88 1.671.092
Vinyl Chloride 47 1.135,809
Chromium 843 737,710
: 1.1.2-Trlchloroelhane 27 598,704
Eplchlorohydnn 81 427.361
Vlnylldene Chloride 20 303,602
2-Nllropropane 8 84,258
1.2-Dlbromoethane 25 58.070
270.735,852
Ozone Depletors - In 1990,
only three ozone depletors
were included in the TRI
database. Table 3-15
summarizes their emissions,
which are just under 10% of
all toxic emissions.
4.21
1.72
144
109
099
099
058
034
025
023
014
011
008
005
003
003
002
001
000
000
1Z33
208.180.680
948
3-11
-------
1989 EMISSIONS
EPA Regions
Figure 3-9 and Table 3-16 break out the
reported emissions by EPA region. Nation-
ally, 2.5 billion pounds of toxics were emit-
reported the greatest emissions with 27%,
22%, and 16% of the total respectively.
These three regions also had the greatest
number of facilities reporting, although
Region 6 was only slightly ahead of Regions
ted by 19,856 facilities. Regions 4,5, and 6 2,3, and 9 in number of facilities.
Figure 3-9
EPA Regional Hot Spots
— 1X9—
Table 3-16
Regional Hot Spots-1989
EPA REGIONS
EPA Region
04
05
06
03
06
No. 01
Release
R«port»
12,033
17,327
7,926
6,299
1.205
No. 01
Ficilitw
3,773
5,220
1,916
1,827
391
HAP
Emissions
(iwyr)
486.738,842
431,831,837
187,821,464
162,562,157
139,094,578
Total
Emissions
(Hvyr)
665,365,019
555,506,402
389,086.006
219,298,500
151,593,721
Region
% 01 Total
TRI EmiMiont
26.59
22.20
15.55
8.76
6.06
EPA Region
07
02
09
01
10
No. 01
Release
Rtporti
3,796
5,397
5,298
3,809
1,694
No. 01
FecMtiee
1,174
1,706
1,859
1,416
574
HAP
Emissions
Wrt
96,435,573
98,229,642
67,253,139
60,550,456
36,145,225
Total
Emissions
(*W
141,290,321
127,884.290
99.370,754
79.396.378
73.201,682
Region
\OlTolal
TRIEmWom
5.65
5.11
3.97
3.17
2.93
64,786
19,856 1,768,662,913 2,501,993,075
100.00
3-12
-------
1989 EMISSIONS
States
Toxic air emissions
reported in the states are
shown in Figure 3-10
and Table 3-17.
Generally the states
reporting the greatest
emissions are the
industrial states in the
Northeast, Great Lakes,
Middle Atlantic, and Gulf
Coast, along with California.
The one exception is Utah,
which is dominated by one
facility with very large
emissions. Texas ranked
first with reported
emissions of 183 million
pounds, equivalent to 7% of
the national total.
Figure 3-10
Toxic Air Emissions By State
—1989—
>100
TaUi 3-17
State Total Emissions
—1989-
State
AK
AL
AR
AS
A2
CA
CO
CT
DE
FL
GA
HI
IA
ID
IL
IN
KS
KY
LA
MA
MD
ME
Ml
MN
MO
MS
MT
No Ot
RtteiM
Reports
39
1,432
916
2
487
4,666
467
1,072
227
1,163
1,793
49
906
127
3,952
2,607
716
1,293
1,466
1,602
642
307
2,873
1,083
1,792
851
98
NO. a
Facilities
6
394
318
2
180
1,631
177
393
61
456
603
11
311
40
1,226
776
212
328
264
584
200
99
786
386
507
261
19
HAP
Emissions
(lo/yr)
1,193,700
95,761,435
24,082,264
0
6,470,110
59,892,466
5,906.644
17,996,787
6,686,219
23,744,549
60,961,376
404.834
27,918,680
1,955,278
79,618,395
87,415.663
20,117.391
35,312,975
47,064,354
16,607.404
14,622,314
10,041,210
81,301.259
53.779,107
36,976,715
40,509.692
1,847.758
Total
Emits ions
(iwyr)
19,726.823
105,116.859
43,381.301
27.750
13,006.486
84,962,457
10,627.629
21,235.167
7,452,834
58,901,883
76,709,164
685,263
43,926,521
5,335,187
101,017,785
111,562,812
32,535,187
44,671,560
129,815,300
24,530.731
18,207,890
15,228,499
104,212,897
62,439,015
48,054,400
60,563,826
2,460,425
State %
Ot Total TRI
Emissions
0.79
420
1.73
0.00
0.52
3.40
0.42
0.85
030
2.35
3.07
0.03
1.76
021
4.04
4.46
1.30
1.79
5.19
0.96
0.73
0.61
4.17
2.50
1.92
2.42
0.10
State
NC
NO
NE
NH
NJ
NM
NV
NY
OH
OK
OR
PA
PR
Rl
SC
SO
TN
TX
UT
VA
VI
VT
WA
Wl
wv
WY
No. 01
Release
Reports
2,462
64
362
324
2,531
140
72
2,424
4,799
614
642
3,511
425
391
1.411
65
1,626
4,790
374
1,348
17
113
686
2,013
571
97
64,786
No. 01
Facilities
828
24
144
133
735
37
35
823
1,399
197
212
1,031
147
164
387
44
516
1,100
107
428
1
43
316
645
107
20
19,656
HAP
Emissions
(Ib/yr)
75,624,236
805.146
11.422,787
8.400,546
22.659,965
1.215,153
485,729
65,334,526
96,560,893
15,753,154
13,911,012
61,348,901
9,116,691
4,541,852
53,676,743
1,946,419
101.127,834
99,706,519
127,513,509
56,195,999
1,116,460
962,657
19,085,235
33,156,500
23,708,724
1,072,902
1,768,662,913
foui
Emissions
(Ib/yr)
93,295,294
1,333,448
16,774,213
11,005,803
30,742,704
2,896,052
686,796
82,377,212
134,725,162
29,491,904
19,728,276
80,256,710
13.604,972
6,241,265
71,150,804
3,201,645
154,953,629
183,501,451
130,290,872
79,727,662
1,159,402
1,154,913
26,411,396
41,548.731
33,653,404
3,659.502
2,501,993.075
State%
Ot Total TRI
Emissions
3.73
0.05
0.67
0.44
1.23
0.12
0.03
3.29
5.38
1.18
0.79
3.21
0.54
0.25
2.64
0.13
6.19
7.33
5.21
3.19
0.05
0.05
1.14
1.66
1.35
0.15
100.00
3-13
-------
1989 EMISSIONS
Three-Digit ZIP Code Areas
Since ZIP Codes are assigned generally
according to population, three-digit ZIP
Code areas represent convenient geographic
areas smaller than states. Figure 3-11 and
Table 3-18 show the top 20 ZIP Code areas.
Area 840 in Utah reported the greatest
emissions with nearly 5% of the national
total. The top 20 areas together reported
almost 27% of the national total.
figure 3-11
20 ZIP Code Areas With Greatest Toxic Air Emissions
—1989-
STATE tUMGITZP CODE
1.UT...MO 4. LA... 703 7.MN...S63
£TX...7T5 5.AL...356 8. Ml... 481
3.TN...376 6.TN...377 9.TX... 776
10. LA... 707
11. NC... 286
12. NY... 146
13. TN... 371
14.AK...996
15.AL..356
16. L... 606
17. MS... 391
18. VA... 241
19 GA.. 314
20. LA... 706
Table 3-18
3-Digit ZIP Codes
— 1989—
3-Diart
ZlPCode
840
775
376
703
365
377
553
481
776
707
State
UT
TX
TN
LA
AL
TN
MN
Ml
TX
LA
NO. a
RtlMM
Report!
151
1,193
166
76
166
78
162
426
246
338
No Of
FicilrtiM
35
133
32
16
23
35
59
112
30
41
HAP
Enmttiorre
(«Vyr)
123.499,332
33,834,153
18,8+4,269
710.280
48,742,819
28,733,800
27,664,355
21,564,884
9,782,964
12,391,681
Total ZIP%
Eminioni 01 Total TRI
(Ibfyr) Emntjont
124,926,334
67,514,934
57,433,650
53,769,804
49,583,284
29,040,910
28,586,651
25,582,830
23,726,475
20,282,437
4.99
2.70
2.30
2.15
1.98
1.16
1.14
1.02
0.95
0.81
3-Digit
ZlPCode
286
146
371
996
356
606
391
241
314
706
State
NC
NY
TN
AK
AL
IL
MS
VA
GA
LA
No. 01
(Went
Report!
476
210
148
18
203
923
45
115
84
222
No. Of
facilities
143
54
42
3
48
294
•21
32
23
28
HAP
Emiaaiora
(ft/VO
17,024,781
15,062.668
16,138,146
274,365
15,587,429
13,952,172
3,933,733
4,060,002
14,050,378
6,273,448
Total
Enwiioni 01
(iWyr)
20,118,360
19.979,701
18.667,116
18.604,215
18,566,446
18,489,888
18,397,399
17.057,985
16,612,517
16.477,335
ZIP*
Total TRI
:niiMion$
0.80
0.80
0.75
0.74
0.74
0.74
0.74
0.68
0.66
0.66
5,446 1,204 432115,659 663.418,271
26.52
3-14
-------
1989 EMISSIONS
Counties
Figure 3-12 and Table 3-19 show the 20
counties with the greatest emissions. Again,
Utah had the county reporting the greatest
emissions. Together the top 20 counties
reported 25% of the total national emissions.
Four of these counties included more than
100 facilities while three had fewer than ten.
The distribution of counties reporting the
largest emissions generally reflects the same
geographic concentration as the state and
ZIP Code areas, with the large emission
reports coming from the industrial areas.
figure 3-12
20 Counties With Greatest Toxic Mr Emissions
1.Tooete,UT 4. Harris. TX
2. Ascension, LA 5. Sullivan. TN
3. Mobile, AL 6. Cook, L
County
Tootle
Ascension
Mobile
Harris
Sullivan
Cook
Los Angeles
Hambten
Mcleod
Monroe
State
UT
LA
AL
TX
TN
IL
CA
TN
MN
NY
No. Of
Relate
Reports
9
148
183
1,301
109
1,751
1,967
G9
30
248
No. Of
facilities
5
17
30
237
14
552
632
21
6
66
HAP
Emissions
(fc/yr)
119,265,478
4,568,353
49,433,531
28,918,090
6,966,709
31,057,015
26,940242
26,448,675
25,496,692
15,494,023
-V^J
7. Los Angeles, CA 10. Monroe, NY 12 Brazoria TX
8. Hambton. TN 11. Kenai-Cook 13. Jefferson, TX
9. McLeod, MN Inlet, AK }4. Chatham, GA
Total
EmiNiofW
(Ityr)
119,265,728
62,477,679
50,399,718
46,891.805
43.146.461
39,033,046
35,440,773
26,714,640
25,782.081
20,558,791
Table 3-19
Counties
-1990-
CountyX
Of Total TRI
HMMlOM
4.77
2.50
2.01
1.87
1.72
1.56
1.42
1.07
1.03
0.82
County
Kenai Peninsula
Brazoria
Jellerson
Chatham
Calcasleu
Wayne
Mississippi
Washlenaw
Shelby
Jellerson
State
AK
TX
TS
GA
LA
Ml
AR
Ml
TN
KY
No. 01
Release
Reports
18
233
301
84
194
600
48
65
266
337
15.Calcasieu, LA
16. Wayne, Ml
17, Mississippi, AR
No. Of
Facilities
3
22
35
23
21
143
15
19
72
71
HAP
Emissions
(IWyr)
274.365
6,192.620
6,422.442
14,050.378
5,593.804
11.421.941
3,080.502
12,934,557
6,192.969
12,097.905
18. Washtenaw, Ml
19. Shelby, TN
20. Jefferson, KY
Total
Emissions
(IWyr)
18,604,215
18,572,338
18,038,473
16,612,517
15,664,609
14.782,936
14,458,523
14,197,992
13,537,600
13,403,053
County %
01 Total TRI
Emm ions
0.74
0.74
0.72
0.66
0.63
059
0.58
057
054
0.54
7,961
Z004 416,850,291 627,582,978
25.08
3-15
-------
500 1,000
Figure 3-13
Toxic Air Emissions
—BY U,S. INDUSTRY-1989—
Number Of Emitters
1,500 2,000 2.500 3,000
3,500 4,000
Tobacco f||!!!
Textiles i|pl
Apparel
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather j
Stone. Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing ^
NaOIEmlters
Tobl Emissions
mmm
0 100 200 300 400 500 600 700
Total Emissions - In Million Pounds Per Year
1989 EMISSIONS
Industries by
2-Digit SIC Code
As shown in Figure 3-13
and Table 3-20, the
chemicals industry is by far
the largest industrial
emitter with nearly one
third of total national
emissions. Together with
the Pulp & Paper and
Primary Metals industries,
three industries reported
more than 50% of the total.
Figure 3-13 shows a
comparison of total
emissions with number of
facilities. This shows that
the Pulp & Paper facilities
generally report high
emissions per facility
(more than 431,000 pounds
BOO
Table 3-20
Air Emissions By U.S. Industry
—1989 —
SCI
20
21
??
n
24
?S
26
27
"W
29
wfe U.S. IndiMby
Food
Tobacco
Textiles-
Apparel _ _
Umber _
Fumilure _
Pulp & Paper
Pr inline
Chemicals
Petroleum Refining
No. 01
EmMwt
1105
17
371
42
537
536
626
379
3967
362
Total Emiuionf li
owyo
28,598,439
1725798
37,462,074
4,381,856
37,255.402
63,961,987
269,765,941
58.174,976
793130665
73,472,974
Khntiy%OfToti!
TRI EmiHions
1.14
007
150
0.18
1.49
256
10.78
2.33
3170
2.94
2-Dia
SICC
30
31
32
33
34
35
36
37
38
39
xta U.S. InduKry
Rubber, Plastics _
Leather
Stone, Clay, Glass
Primary Metals .„
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transport. Equipment
Instruments
Misc. Manufacturing
No. Of
Emitter;
1,636
124
563
1.692
2.877
1.060
1.704
1.278
427
390
Totil Emwiofw
(Hrfyr)
200,229,247
13206920
26,123,954
262,280,892
144,606,396
62,068,033
104,774.079
225.302,351
54,641,638
27,567,074
lndu«try%OfTotil
THIEmMofli
8.00
0.53
1.04
10.48
5.78
2.48
4.19
9.00
2.18
1.10
3-16
-------
Figure 3-14
Number Of Release Reports
- BY U.S. INDUSTRY-1989—
per facility) compared to
fabricated metals, for
example, which report a
relatively small amount per
facility (about 50,000
pounds per facility).
Figure 3-14 and Table 3-21
show the number of release
reports submitted to EPA
for TRI reporting. Again
the chemicals industry has
nearly one third of the
national total. Each report
represents one chemical
released at a single facility.
Because the chemicals
industry is such a large
pan of the total, additional
details on the industry are
presented below.
U.S. INDUSTRY
Food
Tobacco
Textiles |
Apparel [
Lumber jj
Furniture |
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber. Plastics
Leather |
Stone, Clay, Glass |
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
0
2,500 5,000 7,500 10,000 12,500 15,000 17,500 20,000
Number Of Release Reports
Table 3-21
No. of Release Reports by U.S. Industry
—1989 —
m
?n
"n
•n
•ft
?4
•x,
Tfi
77
28
?9
ode U.S. IndMUy
Food
Tobacco
Textiles
Award
Lumber
Furniture
PU!D& Pacer. ..
Printing -
Chemicals
Petroleum Rcllnina
No. Of
Reteaw
Reports
1654
22
TOO
89
1416
1,856
2,070
709
19717
2.856
Industry*
Of Total
TRI Report!
1.14
0.07
1.50
0.18
149
2.56
10.78
2.33
3170
2.94
sicJ
30
31
32
33
34
35
36
37
38
39
ode U.S. Industry
Rubber, Plastics
Leather
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transport. Equipment
Instruments
Misc. Manufacturing. ...
No Ot
Heloisc
Reports
3,978
334
1,537
5,891
7,371
2,587
4,788
4,582
1010
951
Industry*
01 Total
TRI Reports
BAD
053
1.04
10.48
5.78
2.48
4.19
9.00
218
1.10
3-17
-------
Chemicals And Allied Products
Industrial Inorganic
Chemicals
Plastics Materials &
Synthetic Resins/Rubber,
Cellulosic & Other Man-
made Fibers, Except Glass
Drugs
Soap, Detergents, &
Cleaning Preparations;
Perfumes, Cosmetics, &
Other Toilet Preparations
Paints. Varnishes, Lacquers.
Enamels, & Allied Products
Industrial Organic
Chemicals
Agricultural Chemicals
Miscellaneous
Chemical Products
Toxic Air Emissions By SIC Code
;
40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
Total Emissions - In Million Pounds Per Year
1989 EMISSIONS
Industries by
3 and 4-Digit
SIC Code
To subdivide die
industrial sector fur-
ther, Tables 3-22 and
3-23 present the top
industries by 3-digit
SIC codes and 4-digit
SIC codes respectively.
The top ten industries
as shown in Table 3-22
represent more than
50% of total emissions.
By breaking it down
one level further, die
top ten 4-digit indus-
tries, as shown in Table
3-23, reported 37% of
the total.
Figure 3-15 shows the
toxic air emissions
reported by all of the
4-digit chemical indus-
tries. Plastic materials,
industrial organic
chemicals, and agricul-
tural chemicals are the
segments of the in-
dustry reporting the
majority of the indus-
try's emissions.
Table 3-22
Top Industrial Emitters
Table 3-23
Top Industrial Emitters
1989
3-ftflit
»"
Rink
1
2
3
I
E
6
7
6
9
10
Code
282
286
?87
vn
W1
308
?R1
281
M1
331
J-UIWI O/l/ I/O
U.S. Indutty
Plastics Materials &Synlhelic Resins,
Synthetic Rubber Cellulosic & Other
Marinade Fibers,' Except Glass
Industrial Organic Chemicals
Agricultural Chemicals
Relinlng ot Nonlerrous Metals
Motor Vehicles &
Motor Vehicle Equipment
Miscellaneous Plastics Products
Pulo Mills
Industrial Inorganic Chemicals
Petroleum Relinlng
Steel Works, Blast furnaces,
& Rolling & Flninshlng Mills
UEO
Totoi
Emissions
(iwyo
204,380,119
201,108,955
182,700,303
142,982,873
130,738,054
108,845,145
87,401,871
83,391,117
68,283,704
58,231,095
lnd«t™%
OMWI
SIC Tobl
25.77
25.36
23.04
54.52
58.03
54.36
32.40
10.51
92.94
22.20
Industry*
OIToUITRI
Emiwbm
8.17
8.04
7.30
5.71
5.23
4.35
3.49
3.33
2.73
2.33
4-Dig
air
Rink
1
2
3
4
,
6
8
10
t
Code
2869
2873
3339
2821
2611
3711
2823
9fi91
3079
t-uiuii on/ i/i/i
U.S. Induftiy
Industrial Organic Chemicals,
Nol Elsewhere Classllied
Nilrogenoo Fertilizers
Primary Smelling & Relining of
Nonlerrous Melals, Except Copper
& Aluminum
Plastics Materials, Synlhelic Resins.
& NonvulcanizablB Elastomers
Pulp Mills
Motor Vehicles & Passenger Car Bodies
Cellulosic Manmade Fibers
Paper Mills
Miscellaneous Plastics Products
xa
Tout
r—,!--]— __
cnVNIOni
(IWW
173358,318
145049237
127008798
108.733,357
85.945112
69,171,476
53,853,875
51 135635
45,820,041
012-ftgit
SIC Tout
21.86
18.29
48.42
13.71
3186
30.70
6.79
1895
22.88
lnduMn%
OfTotalTBI
EflMffcm
6.93
580
5.08
4.35
344
2.76
9 TO
2.15
204
1.63
3-18
-------
Table 3-24
Chemicals Emitted in the Greatest Amount
—1989—
Chemical
Toluene
Ammonia
Methane*
Acetone
1,1,1-Trichtoroethane
Xylene (Mixed Isomers)
Chlorine
Methyl BhylKelone
Dichtorameltiane
Carbon DlsuilkJe
No. 01
Emitters
3,970
2,799
2,429
£743
3,669
3,532
1,253
2,480
1,539
78
Emission:
(IbM
261,960,919
251,967.696
206,396.868
202,624.803
172,745.485
152,001.772
132,643,321
131,116.266
122,809.412
99,983.802
a TotH
TRI Emissions
10.47
10.07
8.25
8.10
6.90
6.08
5.30
5.24
4.91
4.00
CumulitrYB
Chemical X
10.47
20.54
28.79
36.89
43.79
49.87
55.17
60.41
65.32
69.32
Cternal
Hydrochloric Acid
Fran 113
Glycol Ethers
Trfchloroelhylene
Elhylene
n-Bulyl Alcohol
Styrene
Methyl Isobulyl Kelone
Telrachloroelhylene
Benzene
No. 01
Fmitters
2,416
1,492
1.637
832
267
1.173
1,319
1,049
663
475
Emissions
Mfl
73,204,206
64,010,405
47,977,093
47,501.723
42.466,462
36,603,123
34,102,196
30,895,812
27,006,973
25,863,548
Of Total
TRI Emissions
2.93
2.56
1.92
1.90
1.70
1.46
1.36
1.23
1.08
1.03
Cumulative
Chemical %
72.25
74.81
76.73
78.63
80.33
81.79
83.15
84.38
85.46
86.49
2,163,883,927
86.49
1989 EMISSIONS
Individual Chemicals
Figure 3-16 and Table 3-24
show the individual chem-
icals emitted in the greatest
amount. The 10 top chem-
icals represent nearly 70%
of the total emissions while
the 20 top chemicals
represent almost 87% of
the total. Toluene and
ammonia emissions each
represent more than 10%
of the national total.
1989 EMISSIONS
Groups of Chemicals
It is useful to look at
groups of chemicals whose
emissions are targeted by
EPA programs. None of
these programs were
underway during 1989 so
the effect of the program
does not show up in the
reported emissions.
Figure 3-16
U.S. Air Toxics Emissions
—1989 —
80 §
70 IIJ
60 IIJ
:£££:£££
£:$:;:-S-:£$:!
50 |
40 I
30 j
20 IIJI
10
Others
Carbon Disulfide
Dichloromethane
Methyl Ethyl Ketone
Chlorine
Xylene (mixed isomers)
1,1,1-Trichloroethane
Methanol
Toluene
3-19
-------
Table 3-25
Major Sources
—1989—
The Number of Facilities Emitting
10TPY of Any One HAP or 25 TRY of Any HAPs
lOTpy
01 Or* HUP
aAnyHAPS
IDOrZS
Tot*
Enssons
«0 HAP«
total HAP 01 Total
Emissions In Emissions
6521
4.470
6.550 1.599546.730
7069
Table 3-26
HAPs Emitted In the Greatest Amount
—1989—
No 01
Chemical Emilten
Toluene 3,970
Melhanol 2.429
1.1.1-Trichloroemane 3.189
Xylene (Mixed Isomers) 3.532
Chlorine 1,253
Methyl Ethyl Kelone 2,480
Dfchloromelriane 1.539
Carbon DlsullkJe 78
HydrochlorlcAcid 2,416
Glycol Ethers 1,637
Total Chemical *
Emissions Of Total
(Ib/yr) TRI Emissions
261.960.919 1047
206.396.888 825
172.745.485 690
152.001.772 608
132.643.321 530
131.116.286 524
122.809.412 491
99.983.802 400
73.204.206 293
47.977.093 1 92
No 01
Chemical Emitters
Trlchloroelhylene 832
Slyrene 1,319
Methyl Isobulyl Kelone 1,049
Telrachlorcemylene 663
Benzene 475
Chloroform 186
CarbonylSulllde 32
Elhylene Glycol 938
Formaldehyde 840
Hydrogen Fluoride 455
Total Chemical %
Emissions 01 Total
(Ib/yr) TRI Emissions
47.501.723 1 90
34.102.196 1 36
30.895.812 1 23
27.006.973 1 08
25.863.548 1 03
25.269.682 1 01
18.075.606 072
13.197.795 053
12.925,115 0.52
10,006,434 040
1,645,684,068 6577
33/50
No 01
Chemical Eminen
Toluene 3,970
1,1,1-Trlchloioelhane 3,869
Xylene (Mixed Isomers) 3.532
Methyl Ethyl Kelone 2.480
Didiloromelhane 1.539
Trichloroethylene 832
Methyl IsobulylKetom 1.049
Tetrachloroelnylene 663
Benzene 475
Chlorolorm 186
p-Xylene 37
Carbon Telracfilortde 95
o-Xylene 69
Table 3-27
Chemicals Emitted in the Greatest Amount
— 1989 —
Total Chemical % •
Emissions 01 Total : No 01
(Ib/yr) TBI Emissions • Chemical Emitters
261.960,919 1047 Lead Compounds 569
172,745,485 690
152.001,772 608
131.116.286 524
122.809.412 491
47,501.723 1 90
30,895,812 1 23
27.006.973 1 08
25.863,548 1 03
25.269,682 1 01
4.933,722 020
3.369,248 013
1.808.306 007
Chromium Compounds 846
m-Xylene S3
Chromium 819
Nickel 776
Lead 637
Cyanide Compounds 199
Nickel Compounds 396
, Cadmium Compounds 88
Cadmium 57
Mercury 38
Mercury compounds 12
Total Chemical*
Emissions Ol Total
(Ib/yr) TRI Emissions
1,570,821 006
1,409,098 006
1,200,771 005
1,139.201 005
1,116,287 004
861,598 003
824.908 003
272.689 001
85,004 000
35,267 000
25,085 000
4,009 000
1.015.827.626 4060
Hazardous Air Pollutants - The Clean
Air Act Amendments of 1990 listed
189 chemicals for control under Tide
m. Major sources, defined as facilities
that emit 10 tons per year of one HAP
or 25 tons of total HAPs, must apply
the maximum available control technol-
ogy. Table 3-25 shows the number of
facilities that would qualify as major
sources according to the TRI reports
(As mentioned earlier, 17 of the 189
HAPs specified in the
Clean Air Act are not
covered by TRI). These
6,550 facilities, which is
equivalent to 33% of the
total facilities reporting,
represent 96% of the
total HAP emissions
and 71% of all TRI
chemical emissions.
Table 3-26 show the
twenty HAPs emitted in
the greatest amount
They represent about
two thirds of the total
national emissions.
33/50 Chemicals-EPA
initiated a voluntary
emissions reduction pro-
gram targeting 17 spe-
cific chemicals (or
groups of related chemi-
cals in some cases).
Reported emissions of
these chemicals are
shown in Table 3-27.
Together this group of
chemicals is equivalent
to 40% of the total toxic
emissions.
3-20
-------
High Risk/Early Reduction
Chemicals - Table 3-28 lists 20 high
risk/early reduction chemicals. These
chemicals are considered high risk
because of their toxicity. Together they
represented less than 2% of the total
national toxics emissions in 1989.
Carcinogens - Table 3-29 summarizes the
emissions of the 20 carcinogens emitted in
the greatest amount as reported to the TRI.
Their significance is due to their
carcinogenicity. Together the top twenty
represent 13% of total emissions with the
largest carcinogen, dichloromethane or
methylene chloride, almost 5%.
Table 3-28
High Risk/Early Reduction Chemicals
Emitted In the Greatest Amount
-1989-
Table3-29
TRI Carcinogens Emitted In The
Greatest Amount
—1989—
No 01
Chanol Emitters
Benzene 475
1.3-Bubdiene 157
Aoylonllrile 112
Elhylene Oxide 194
Manganese Compounds 466
Chromium Compounds 646
Vinyl Chloride 49
Chromium 819
Chloroprene 7
Melhytenebls
(Phenylisocyanale) 296
Acrylic Add 155
Vlnylldene Chloride 23
Arsenic Compounds 133
Toluene-2.4-rjlisocyanate 240
Cadmium Compounds SB
Dlbenzoiuran 106
1,2-Dlbromoeltiane 25
Arsenic 37
Asbestos (Friable) 66
1.1.2.2-TelradiloroelhaiK 16
Cadmium 57
Totil
Emissions
(Ib/yr)
25,663,548
5,700,676
4,387,467
3,235,634
1,833,491
1.409.098
1.269.032
1.139.201
1.006.341
380.213
357.523
220,632
175.584
90.946
85.004
64.510
59.167
58.150
38.435
35.401
35.267
45,611,829
Chemical *
01 Total
TRI Emissions
103
023
018
013
007
006
005
005
004
002
001
001
001
000
000
000
000
000
000
000
000
182
Chemical
Dichloramelhane
Trichloroelhylene
Slyrene
Tetrachloroelhylene
Benzene
Chloroform
Formaldehyde
Chloromelhane
l,3-8uladlene
• Acrylonllrlle
: 1.2-Dlcrtloroethane
Carbon Telrachlortde
Elhylene Oxide
Vinyl Chloride
Chromium
1,1,2-Trlchloroelhane
Epichlorohydrln
2-Nitropropane
Vinylidene Chloride
2.4-Dimlrololuene
No 01
Emitters
1,539
832
1,319
663
475
186
840
83
157
112
98
95
194
49
819
28
76
10
23
9
Totll
Emissions
W)
122.809,412
47,501.723
34.102.196
27.006,973
25,863.548
25.269.682
1*925.115
9.707.459
5,700.676
4.387.467
4.284.066
3.369.248
3.235,634
1.269.032
1.139,201
786,898
472.548
225.222
220,632
87,293
330,364.025
Chemical %
01 Total
TRI Emissions
491
190
136
108
103
101
052
039
023
018
017
013
013
005
005
003
002
001
001
000
1320
Table 3-30
TRI Ozone Depletors Emitted In
The Greatest Amount
—1989—
Cheninl
No B
Emitters
Tottl Chcmial %
Emissions 01 Total
(IWyr) TRI Emissions
1.1,1-Trichloroelhane 3.889 172.745,485 690
Freon113 1.492 64.010,405 256
Carbon Tetrachlorlde 95 3.369,248 013
240.125,138
960
Ozone Depletors - In 1989, only
three ozone depletors were included in
the TRI database. Table 3-30
summarizes their emissions, which are
just under 10% of all toxic emissions.
3-21
-------
1988 EMISSIONS
EPA Regions
Figure 3-17 and Table 3-31 break out the
reported emissions by EPA region. Nationally,
2.6 billion pounds of toxics were emitted by
18,300 facilities. Regions 4,5, and 6 reported
the greatest emissions with 25%, 21%, and
16% of the total respectively. These three
regions also had the greatest number of
facilities reporting, although Region 6 was
only slightly ahead of Regions 2,3, and 9
in number of facilities.
Figure 3-17
EPA Regional Hot Spots
—1988—
Table 3-31
Regional Hot Spots
—1988 EPA REGIONS —
EPA
Region
04
05
06
03
02
No 01
RllMM
Report!
10,461
15,460
7,270
5,737
5,044
No. Of
Facilities
3,371
4,760
1,777
1,671
1,665
HAP
Emissions
(MM
486,490,666
423,571,319
206,782.960
218,116.013
118,230,274
Total
Emissions
(lu/yo
652.133,885
553,441,733
409,689,743
277,038,496
151,907,179
Region %
01 Total Tri
Emissions
25.02
2123
15.72
10.63
5.83
|PA.
Region
07
08
09
01
10
NO. a
Release
Reports
3,334
1,067
4,882
3,592
1,490
No. «
Facilities
1,079
357
1,749
1,351
520
HAP
"Tow
105,162,263
131,115,812
70,952,794
70,710.157
38,476,943
Total
Emissions
(iwyr)
143,589,419
142,579,669
107,971,558
90,868,669
77,422,408
Regions
OtToUITRI
Emissions
5.51
5.47
4.14
3.49
£97
58,337
18,300 1.869,609,203 2,606,642.759
100.00
3-22
-------
1988 EMISSIONS
States
Toxic air emissions reported
in the states are shown in
Figure 3-18 and Table 3-32.
Generally the states
reporting the greatest
emissions are the industrial
states in the Northeast,
Great Lakes, Middle
Atlantic, and Gulf Coast,
along with California. The one
exception is Utah, which is
dominated by one facility with
very large emissions. Texas
ranked first with reported
emissions of 192 million
pounds, equivalent to 7%
of the national total.
Figure 3-18
Toxic Air Emissions By State
—1988 —
Table 3-32
State Total Emissions
— 1988—
State
AK
Al
AR
AS
AZ
CA
CO
CT
DC
DE
FL
GA
HI
IA
ID
IL
IN
KS
KY
LA
MA
MD
ME
Ml
MN
MO
MS
No. Of
Relate
R«port«
35
1.254
823
2
399
4.375
417
1,033
1
202
1.031
1.564
52
806
119
3.541
2.349
630
1.143
1.389
1,458
588
290
2.581
931
1.550
680
No. a
Ficilrtiee
6
346
286
2
156
1.549
154
381
1
56
426
527
12
287
40
1,145
696
191
288
250
546
177
91
728
334
469
221
HAP
rm • _• _ ,
tmi**K)n»
(IWyr)
1,036.096
94,303.060
26,410.535
0
7,266,840
62,703.045
6,704.871
22,005.204
0
7,026.193
23,952.711
69,278.574
477.308
30,204.138
2,142,879
80,464.431
90,018,161
22,234,103
39,284,340
45,789,138
20,908,305
13,965,343
11,468,966
76,487,500
45,044,858
40,695,324
39.460,265
Tottl
Emissions 0
(IWyr)
21,749,696
104,488,067
48,403.262
29,500
16,190,594
90,188,611
12,078,387
25,351,278
250
7,564,595
50,237,247
86.120,168
874,145
43.294,129
5.358,683
106.865,656
109.393,235
31.728,063
47.941,452
131.964,769
27.235,140
17.978,759
17.048,429
98,046,366
54,216,230
49.949,105
59.606,700
State %
Total TRI
:missiont
0.83
4.01
1.86
0.00
0.62
3.46
0.46
0.97
0.00
023
1.93
3.30
0.03
1.66
021
4.10
420
122
1.84
5.06
1.04
0.69
0.65
3.76
2.08
1.92
229
Stilt
MT
NC
ND
NE
NH
NJ
NM
NV
NY
OH
OK
OR
PA
PR
N
SC
SD
TN
TX
UT
VA
VI
VT
WA
Wl
wv
WY
No. Of
Release
Report!
100
2,189
58
346
314
2,360
117
54
2,274
4,196
569
562
3,179
396
373
1,182
59
1,418
4,372
351
1,219
14
124
774
1,862
548
82
No. 0)
FiciMw
19
752
25
132
130
736
32
30
787
1,264
165
168
950
141
160
335
36
476
1,024
105
363
1
43
266
593
104
18
HAP
Eminion*
(IWyr)
1,765,493
79,951,258
869,603
12,026,698
9,344,282
27,671,897
730,744
505,601
78,124,619
95,245,924
19,450,279
14,356,631
70,116,859
10,980,728
5,704,543
49,858,705
1.709,532
90,401.735
114,402,264
118,682,667
100,366,868
1,453,030
1,278,857
20,941,335
36,310,445
26,620,750
1,383,446
Total State %
EmiMion. OITotllTRI
(Ityr) Emmiom
2,365,977
96,842,867
1,267.924
18.618.102
11,952.622
38,568.974
2,133.198
688.708
96,167,936
139,344.996
35,615.898
20,891,887
91,607.673
15,679.477
7,761.907
66,722.597
2,499,867
140,172.787
191.552.596
121,476,450
123.292,360
1,490,792
1,519.293
29,422.142
45,573.250
36,594.859
2,891,064
0.09
172
0.05
0.71
0.46
1.48
0.08
0.03
3.69
5.35
1.37
0.60
3.51
0.60
0.30
2.56
0.10
5.38
7.35
4.66
4.73
0.06
0.06
1.13
1.75
1.40
0.11
58,337
18,300 1,869,609,203 a606.642.759
100.00
3-23
-------
1988 EMISSIONS
Three-Digit ZIP Code Areas
Since ZIP Codes are assigned general-
ly according to population, three-digit
ZIP Code areas represent convenient
geographic areas smaller than states.
Figure 3-19 and Table 3-33 show the top
20 ZIP Code areas. Area 840 in Utah
reported the greatest emissions with more
than 4% of the national total. The top 20
areas together reported almost 26% of the
national total.
figure 3-19
20 ZIP Cote Areas With Greatest Toxic Air Emissions
*•*,....
STATE 13DKHTZP CODE
1.UT...840 4.TN...376 7.TX...776
^TX...775 5.AL...365 8. NY... 146
3. LA... 703 6. VA... 226 9. LA... 707
10.VA...244
11. Ml... 480
12.AK...996
13.NC...286
14.TN...377
15.GA...314
16. L... 606
17.TN...371
18.NC...284
19. MS... 301
20. MN... 553
Table 3-33
3-Diglt ZIP Codes
-1988-
3-Digit
ZIPCode
MO
775
703
376
365
226
776
146
707
244
State
UT
TX
LA
TN
AL
VA
TX
NY
LA
VA
No Of
Release
Reports
1S4
1.143
66
143
163
61
241
215
337
60
No. 01
Facilities
37
125
14
30
23
17
26
52
39
21
HAP
Emitsiom
(•VyO
114,570,350
36,279,834
1,418,606
19,288,620
48,844.932
39,641,648
14,164,991
19,961,588
12,236,944
20,113,830
Total ZIP*
EmMont Of Total TRI
(10/yt) EmiMion*
115,881,488
64,007,392
56,473,822
54,538,069
49,687,881
40,129,374
26,766,399
25,270.117
21,406.062
21,085,475
4.45
2.46
2.17
2.09
1.91
1.54
1.03
0.97
0.82
0.81
3-Digil
ZIP Code
480
996
266
377
314
606
371
284
391
553
Stitc
Ml
AK
NC
TN
GA
IL
TN
NC
MS
MN
No. Of
Release No. Of
Report* Facilities
371
18
415
77
78
788
142
100
34
137
100
3
127
33
22
274
38
23
16
60
NAP
Emission*
OHM
18^37,968
276,935
17,779,009
19,903,936
17.306,213
14,920,127
15.991,370
16331.178
3.049.386
17,518,991
Total ZIP*
Emiatioi* Of Total TRI
(tofrr) Eminiont
20.978,288
20.958,860
20,591,196
20,146,764
19.619,444
19,362,897
19.000,092
18.714,468
18,665,403
18.320,048
0.80
0.80
0.79
0.77
0.75
0.74
0.73
0.72
0.72
0.70
4,743 1.080 468,036,456 671.603.559
25.77
3-24
-------
1988 EMISSIONS
Counties
Figure 3-20 and Table 3-34 show the 20
counties with the greatest emissions. Again,
Utah had the county reporting the greatest
emissions. Together the top 20 counties
reported almost 25% of the total national
emissions. Three of these counties included
more than 100 facilities while six had fewer
than ten. The distribution of counties report-
ing the largest emissions generally reflects
the same geographic concentration as the
state and ZIP Code areas, with the large emis-
sion reports coming from the industrial areas.
Figure 3-20
20 Counties With Greatest Toxic Air Emissions
—1988—
COUNTY AND STATE
VTooele, UT 4,Hams,TX 7. Los Angeles, CA 10. Kenai-Cook 12. Chatham, GA 15. HamUen, TN 18. Si. James, LA
2. Ascension, LA 5. Sullivan, TN 8. Warren, VA Inlet, AK 13. Jefferson, TX 16.McLeod,MN 19.Calcasieu.LA
3.Mobile,AL 6,Cook,L 9. Monroe, NY 11. Brazoria, TX 14. Allegheny, VA 17. Mississippi, AR 20. Jefferson. KY
Table 3-34
Counties
-1988-
County
Tooele
Ascension
Mobile
Harris
Sullivan
Cook
Los Angeles
Warren
Monroe
Kenal Peninsula
Stale
UT
LA
AL
TX
TN
IL
CA
VA
NY
AK
No. Of
RtlMtt
Report!
e
137
179
1,158
103
1,536
1,868
27
245
18
No. Of
Facilities
4
15
27
223
14
517
624
4
61
3
HAP
Emission*
(ib/yr)
109,668,022
5,614,188
49,711,651
29,203,555
9,074,646
29,546,827
28,879,726
34.579,400
20,640,798
276,935
Total
Emissions
(IhM
109,868,272
51,237,547
50,581,637
47,859,672
42,806,100
38.078,024
37,733,455
34,639,208
26,091,597
20,958,860
County*
Of Total TRI
EmiMtons
4.21
1.97
1.94
1.84
1.64
1.46
1.45
1.33
1.00
0.80
County
Brazoria
Chatham
Jetlerson
Alleghany
HamtXen
Me Leod
Mississippi
SUames
Calcasleu
Jefferson
State
TX
GA
TX
VA
TN
MN
AR
LA
LA
KY
No. Of
Release
Reports
232
78
308
15
50
26
39
46
186
300
No. Of
Facilities
22
22
32
3
19
7
13
8
21
61
HAP
Emiiiwons
-------
500
Figure 3-21
Toxic Air Emissk
— BY U.S. INDUSTRY-1988 —
Number Of Emitters
1,500 2,000 2.500 3,000
3,500 4.000
Apparel ||
Lumber ^ '
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
NaOlEmlters
Total Emissions
200 300 400 500 600 700
Total Emissions - In Million Pounds Per Year
800
1988 EMISSIONS
Industries by
2-Digit SIC Code
As shown in Figure 3-21
and Table 3-35, the
chemicals industry is by
far the largest industrial
emitter with nearly one
third of total national
emissions. Together with
the Pulp & Paper,
Primary Metals, and
Transportation
Equipment industries,
four industries reported
more than 60% of the
total. Figure 3-21 shows
a comparison of total
emissions with number
of facilities. This shows
that the Pulp & Paper
facilities generally report
high emissions per
facility (more than
2-rjMit
SIC Code
U.S. Indintn
Table 3-35
Air Emissions By U.S. Industry
No. Of
Emittws
Total Emuwora InduKiv % Of Totil
(Ib/yr) THI Emiolont
U.S. Indmtry
No. Of
Emitters
Total Emiwiont Indwtry % Of Totil
(tofrr) THI EmMom
20
21
22
n
2<\
?S
26
?7
28
29
Food
Tobacco
Textiles
Lumber
Furniture
Pulo& Pacer
Prinllno -
Chemicals
Petroleum Helming
960
19
320
38
507
490
595
339
3,729
334
22,350,401
1 ,817,354
43,684,491
1665803
33,142,943
64.818,870
270,398,044
64,998,394
854,587,986
75,530,418
0.86
0.07
1.68
0.06
127
2.49
1037
2.49
32.79
2.90
30
31
32
33
34
35
36
37
38
39
Rubber, Plastics
Leather
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transport. Equipment
Instruments
Misc. Manufacturing
1,437
121
497
1,518
2,664
994
1,630
1,173
378
384
192,919,849
14,850,396
28,603.514
253,267.435
142,788,595
70,091,651
127.625.211
236.353,758
58,384,902
32,306,637
7.40
0.57
1.10
9.72
5.48
2.69
4.90
9.07
224
1.24
3-26
-------
Figure 3-22
Number Of Release Reports
—BY U.S. INDUSTRY-1988 —
450,000 pounds per
facility) compared to
Fabricated Metals, for
example, which report a
relatively small amount
per facility (about 54,000
pounds per facility).
Figure 3-22 and Table 3-
36 show the number of
release reports sub-
mitted to EPA for TRI
reporting. Again the
chemicals industry has
about 30% of the
national total. Each
report represents one
chemical released at a
single facility. Because
the chemicals industry is
such a large pan of the
total, additional details
on the industry are
presented below.
U.S. INDUSTRY
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather |
Stone, Clay, Glass |
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
0
2,500 5,000 7,500 10,000 12,500 15,000 17.500 20,000
Number Of Release Reports
Table 3-36
No. if Release Reports by U.S. Industry
—1988 —
sicl
?n
n
7?
7\
74
7S
9fi
77
?fi
29
od* U.S. Indwtry
Food
Tobacco
Textiles „
Apparel
Lumber
Furniture
Pulp* Paper
Printing
Petroleum Refining ...
No. 01
RriMM
Report;
1399
40
589
66
1,321
1733
1952
621
17676
2.623
InduftiyN
0) Total
TRI Reportt
086
0.07
168
0.06
1.27
249
10.37
249
3279
2.90
ajcj
30
31
32
33
34
35
36
37
38
39
ode U.S. Industry
Rubber Plastics
Leather
Stone Clay Glass
Primary Metals
Fabricated Metals
Non-Elect Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manulacturina
No. Of
R0I6U0
Report!
3404
328
1254
5073
6629
2,301
4517
4296
937
662
InduitryX
OITotll
TRI Report!
740
057
1 10
972
548
269
4.90
007
224
124
3-27
-------
Chemicals And Allied Products
Industrial Inorganic
Chemicals
Plastics Materials &
Synthetic Resins/Rubber,
Cellulosic & Other Man-
made Fibers, Except Glass
Drugs
Soap, Detergents, &
Cleaning Preparations;
Perfumes, Cosmetics, &
Other Toilet Preparations
2WT §
Paints, Varnishes, Lacquers,
Enamels, & Allied Products 2167 J
on l:::
Fiflure3-23
Toxic Mr Emissions By SIC Code
^CHEMICAL iNDUSW^
Industrial Organic
rhofrurali
Agricultural Chemicals
Miscellaneous
Chemical Products
aW liSv- ;-:'.;
ati • ;•.,:.
a»r 1%:;::? ::•;••: .• •• , :
ax Is _ ••.••••...:• ••
a/oillJ^:.,,;:
an [;:*: -:: : . .
an ••§
are • ',<>v .
are iM ; ••
»B9 tW::?.;:?::." :.'.'": ::::Vr;/?
2BO- 1
ati • •-.
awl*--.-.
2MS •••';;:a;:;;;:;:.:-::SH;::
a»r is;;;-,: ;.:;;;;;;:•;'•. , :;.i •
>',•' '• ::v,^' ' : %
• ' illlllllllylll
^SC Code fri not listed iri; the Standard
itMMfial CiassilMion Manual, 1987
'•'. :•_'.•
1
0 10 20 30 W 50 60 70 80 90 100 110 120 130 140 150 160 170 160
Total Emissions - In Million Pounds Per Year
1983 EMISSIONS
Industries by
3 and 4-Digit
SIC Code
To subdivide the indus-
trial sector further,
Tables 3-37 and 3-38
present the top industries
by 3-digit SIC codes and
4-digit SIC codes
respectively. The top ten
industries as shown in
Table 3-37 represent
almost 50% of total
emissions. By breaking
it down one level fur-
ther, the top ten 4-digit
industries, as shown in
Table 3-38, reported
38% of the total
Figure 3-23 shows die
toxic air emissions
reported by all of the 4-
digit chemical indus-
tries. Plastic materials,
industrial organic chem-
icals, and agricultural
chemicals are the seg-
ments of the industry
reporting the majority of
the industry's emissions.
3-Digit
sitr
Rank Code
Table 3-37
Top Industrial Emitters -1988
3-DIGIT SIC CODES
Total li
EmiMum
U.8. Indmtry (ItVyr)
lndwtry%
Of Tottl TRI
SIC Total EmlMiont
1 282 Plastics Materials & Synthetic Resins,
Synthetic Rubber, Cellulosic & Other
Manmade Fibers, Except Glass 228,273,763
2 286 Industrial Organic Chemicals 216.651,476
3 287 Agricultural Chemicals 185.966,845
4 333 Primary Smelling
& Refining of Nonferrous Metals 133,011.750 52.52
26.71
25.35
21.76
8.76
8.31
7.13
5.10
5
fj
7
8
q
10
371
281
307
291
308
Motor Vehicles &
Motor Vehicle Equipment
Industrial Inorganic Chemicals
Pulp Mills... „
Miscellaneous Plastics Products
Petroleum Refining
Miscellaneous Plastics Products
125,713,309
96854744
90,471,927
73,342,769
71236633
69,235,509
53.19
11.33
33.46
38.02
9432
35.89
4.82
3.72
3.47
2.81
273
2.66
Table 3-38
Top Industrial Emitters -1988
4-DIGIT SIC CODES
4-Di
SIC^
Rant
1
2
3
4
s
6
7
8
9
10
lit
Code
2869
2873
3339
2821
2611
2823
3079
3711
U.S. Indurty
Industrial Organic Chemicals,
Not Elsewhere Classified
Nitrogenous Fertilizers
Primary Smelling & Refining of
Nonlerrous Metals, Except Copper
& Aluminum _ _ . _.
Plastics Materials, Synthetic Resins &
NonvulcanizaMe Elastomers _
Pulp Mills - _.
Cellulosic Manmade Fibers ...... ....
Miscellaneous Plastics Products....
Pelroleurn Refining
Motor Vehicles & Passenger Car Bodies
Paper Mills „.
_ ToUl 1
""flSJr)
179381453
159,132,268
115557844
101,363,368
88,574.443
87,327427
71.505.551
71225233
68,315,256
54,756,547
riufty%
012-001 0
SIC Cod*
2099
18.62
45.63
11.86
32.76
1022
37.06
9430
28.90
20.25
SIC%
Total TRI
rmiwcne
688
6.10
443
3.89
3.40
335
2.74
273
2.62
2.10
1,290,758,725
49.52
997,139,390
38.24
3-28
-------
Table 3-39
Chemicals Emitted In the Greatest Amount
—1988 —
Chemical
Toluene
Ammonia
Melhanol
Acetone
1. 1,1 -Tried toroelhane
Xylene (Mixed Isomers)
Chlorine
Methyl Ethyl Kelone
Dicrilofomelhane
Carbon Dlsullkle
No. 01
f miners
3,766
2,448
2,283
2,624
3,630
3.240
1,244
2,373
1,577
79
loui
Emissions
(iwyr)
285,303,917
252,273,912
226,096,844
203,280,215
173,920,989
151,187,866
133,751,760
131,808,179
125,849.987
123,893,704
Chemical %
01 Total
TRI Emissions
10.95
9.68
8.67
7.80
6.67
5.80
5.13
5.06
4.83
4.75
Cumulative
Chemical %
10.95
20.63
29.30
37.10
43.77
49.57
54.70
59.76
64.59
69.34
Chemical
Freon113
Hydrochloric Add
Trichloroelhylene
Glycol Elhers
Elhylene
n-Buryl Alcohol
Telrachlofoelhylene
Styrene
Methyl Isobulyl Kelone
Benzene
No. 01
Emitters
1,372
2,253
892
1,354
261
1,062
683
1,140
970
459
Total
Emissions
(Ihryr)
68,514,249
69,264,605
52,645.060
47,937,703
43,233,377
37,365,557
35,555,545
32,460,559
31,435,711
30,226,580
Chemical %
Of Total
TRI Emissions
2.63
2.66
2.02
1.84
1.66
1.43
1.36
1.25
1.21
1.16
Cumulative
Chemical %
74.63
72.00
76.65
78.49
80.15
81.58
82.94
84.19
85.40
86.56
2,256,006,319
86.56
1988 EMISSIONS
Individual Chemicals
Figure 3-24 and Table 3-39
show the individual
chemicals emitted in the
greatest amount. The 10
top chemicals represent
nearly 70% of the total
emissions while the 20 top
chemicals represent almost
87% of the total. Toluene
emissions alone represent
more than 10% of the
national total.
1988 EMISSIONS
Groups of Chemicals
It is useful to look at groups
of chemicals whose
emissions are targeted by
EPA programs. None of
these programs were
underway during 1988 so
the effect of the program
does not show up in the
reported emissions.
Figure 3-24
U.S. Air Toxics Emissions
— 1988-
PERCENT
100
Others
Carbon Disulfide
Dichloromethane
Methyl Ethyl Ketone
Chlorine
Xylene (mixed isomers)
1,1,1-Trichloroethane
20
10
n
Acetone
Methanol
Ammonia
Toluene
3-29
-------
Table 3-40
Major Sources
— 1988—
The Number of Facilities Emitting
10 TPY of Any One HAP or 25 TPY of Any HAPs
Total %OI HAP%
10 Toy 25 Tw 10O25 Emissions Total HAP a Total
aOmHAP OAnyHAFs Tpy (ItvVr) Emissions TnEmissmis
6,424
4.487
6.455
1.606.014.829 9660
nn
nazaraous
Air Act Air
189chemic
m. Major
that emit 1C
or 25 tons c
the maximi
ogy. Table
facilities th
sources ace
.. . ( As mentio
Table 3-41
\
HAPs Emitted In the Greatest Amount
Chemical
Toluene
Melhanol
1,1,1-Trldiloroelhane
Xylene (Mixed Isomers)
Chlorine
Methyl Elhyl Kelorn
Dicftloromelhane
Carbon Dlsulllde
HydrodtloricAdd
Trlchloroemylene
No 01
Emitters
3.766
2.283
3,630
3,240
1.244
2373
1.577
79
2253
892
Total
Emissions
(IkW
285,303.917
226,096.844
173,920,989
151,187,866
133.751,760
131.808.179
125,849.987
123,893,704
69.264.605
52645.060
— 1988 —
Chemical %
01 Total
TRI Emissions
1095
867
667
5.80
513
506
483
475
266
202
Chemical
Glycol Enters
Tetrachloroelhylene
Slyrene
Methyl IsoburylKetone
Benzene
Chloroform
CarbonylSullide
Bhylene Glycol
Hydrogen Fluoride
Formaldehyde
No 01
Emitters
1.354
683
1,140
970
459
164
30
858
423
724
Total
Emissions
(ib/yr)
47.937,703
35.555.545
32.460.559
31.435.711
30,226,580
23,871.504
20,183,072
13,569,932
12114.046
11.891,313
1.732.968.876
Chemical %
Of Total
TRI Emissions
184
136
125
121
1.16
092
077
052
046
046
6648
Table 3-42
33/50 Chemicals Emitted In the Greatest Amount
—1988—
Chemical
Toluene
1.1.1-Trlchtoroethane
Xylene (Mixed Isomers)
Melhyl Elhyl Kelone
Dldiloromelhane
Trlchioroelhylene
Tetrachloroelnylene
Methyl IsobulylKetone
Benzene
Chloroform
p-Xylene
Carbon Tetrachtoride
m-Xylene
No. 01
Emitters
3,766
3.630
3.240
2373
1.577
892
683
970
459
164
46
87
66
Total
Emissions
-------
High Risk/Early Reduction
Chemicals - Table 3-43 lists 20 high
risk/early reduction chemicals. These
chemicals are considered high risk
because of their toxicity. Together they
represented less than 2% of the total
national toxics emissions in 1988.
Carcinogens - Table 3-44 summarizes the
emissions of the 20 carcinogens emitted in
the greatest amount as reported to the TRI.
Their significance is due to their carcino-
genicity. Together the top twenty represent
14% of total emissions with the largest car-
cinogen, dichloromethane or methylene
chloride, almost 5%.
Table 3-43
Table 3-44
Emitted In the Greatest Amount
-1988-
Noffl
ChGfnml EmittBn
Benzene
1.3-Buladlene
Elhylene Oxide
Aoylonlblle
Vinyl Chloride
Chlorcprene
Acrylic Add
Chromium Compounds
Chromium
Vlnylldene Chloride
Arsenic Compounds
Melhyfenebts
(Phenyllsocyanate)
Toluene-2.4-OHsocyanate
Cadmium Compounds
Dibenzoluran
1.2-0lbromoeltiane
Heptadilor
Asbestos (Friable)
1.1,2,2-Telrachloroelhane
Aaoleln
459
145
193
100
47
12
139
713
659
21
123
228
228
65
99
28
2
65
13
12
Total Chcmial %
Emissions 01 Total
(Ib/yr) 1RI Emissions
30.226.580
6.654.123
4.762.901
4.195.6S7
1.436.427
1,218.426
799.178
791.922
547.745
296.353
267.252
247.319
196.977
100.487
71.054
63.327
49.055
• 47.615
43.855
33,652
52,049.914
116
026
016
016
006
005
003
003
002
001
001
001
001
000
000
000
000
000
000
000
^oo
iiu uarwnugvns cnmiea in
The Greatest Amount
— 1988—
Chemical
Dtchloromelhane
Trlchloroelhylene
Telrachloroelhylene
Slyrene
Benzene
Chlorolorm
Formaldehyde
Chloromelhane
1.3-Buladlene
Ethylene Oxide
i 1,2-Dlchloroelhane
Acrylonltrile
Carbon Telrachloilde
. 1.1.2-Trlcriloroethane
1 Vinyl Chloride
Chromium
; Eplchlorohydnn
2-Nllropropane
• Vlnylldene Chloride
Urelhane
NO a
Eminers
1.577
892
683
1.140
459
164
724
77
145
193
100
100
87
29
47
659
70
12
21
6
Total Chemical %
Emissions Of Total
(m/|rr) TRI Emissions
125.849.987
52.645.060
35.555.545
32.460,559
30.226,580
23,871.504
11,891,313
11,290.415
6,654.123
4,762.901
4.524.929
4,195.667
3.715.421
1,741,342
1,436.427
547.745
465.268
389,385
296.353
145,373
352.665.897
483
202
136
125
116
092
0.46
0.43
026
018
0.17
016
014
007
006
002
002
001
001
001
1353
Table 3-45
TRI Ozone Depletors Emitted In
The Greatest Amount
—1988—
CnGflllQl
1,1.1 -111141107061118116
Freon113
Carbon Telrachlorlde
No Of
Emiltera
3,630
1.372
87
Total Chemical %
Emissions Of Total
(lay) TRI Emissions
173.920.989
68.514,249
3.715.421
246.150.659
667
263
014
944
Ozone Depletors - In 1988, only
three ozone depletors were
included in the TRI database.
Table 3-45 summarizes their
emissions, which are just under
10% of all toxic emissions.
3-31
-------
1987 EMISSIONS
EPA Regions
Figure 3-25 and Table 3-46 break out the
reported emissions by EPA region. Nation-
ally, 2.8 billion pounds of toxics were emit-
ted by 16,929 facilities. Regions 4,5, and 6
reported the greatest emissions with 24%,
21%, and 18% of the total respectively.
Regions 4 and 5 also had the greatest
number of facilities reporting, although
Region 9 was slightly ahead of Region 6
in number of facilities.
Figure 3-25
EPA Regional Hot Spots
— 1987—
65-75 | |
75-100
100-150
150-250
250-500
500-670
2 . .
Puerto Rico/ Virgil Wands (P
Table 3-46
Regional Hot Spots
— 1987 EPA REGIONS —
EPA
Region
04
05
06
03
02
No. Of
Ritauc
Reports
9.714
14,167
6,705
5,257
4,957
No. a
Facilities
3,116
4,358
1,597
1,535
1,594
HAP
Emissions
OhM
484,205,004
443,314,672
206,796,870
238,691,177
120,925,228
Total
Emissions
(IWVO
665,126,546
584,526,605
492,164,503
306,424,076
158,459,472
Region %
Of Total TRI
Emissions
24,16
2123
17.88
11.13
5.76
EPA
Region
07
08
09
01
10
No. Of
Release
Reports
3,040
1,009
4.513
3,494
1,493
No. Of
1,009
327
1,610
1,267
516
HAP
Emissions
94.833.132
94.515,847
70.282.879
76.502,385
39.522.651
Total
Emissions
(Ibfrr)
132,308,699
109,693,895
108,421,610
98,141,764
97,466,442
Region*
Of Total TRI
Emissions
4.81
3.98
3.94
3.57
3.54
54.349
16,929 1.869.589.845 2,752,733,632
100.00
3-32
-------
1987 EMISSIONS
States
Toxic air emissions reported
in the states are shown in
Figure 3-26 and Table 3-
47. Generally the states
reporting the greatest
emissions are the industrial
states in the Northeast,
Great Lakes, Middle
Atlantic, and Gulf Coast,
along with California. The one
exception is Utah, which is
dominated by one facility with
very large emissions. Texas
ranked first with reported
emissions of 250 million
pounds, equivalent to 9% of the
national total.
Figure 3-26
Toxic Air Emissions By State
—1987—
301) 80 [Ml
Mb 100
>too
Table 3-47
State Total Emissions
—1987—
Stile
AK
AL
AR
AS
AZ
CA
CO
CT
DB
FL
GA
HI
IA
ID
IL
IN
KS
KY
LA
MA
MD
ME
Ml
MN
MO
MS
MT
No. Of
Retain
Report!
43
1.141
749
2
373
4,036
395
1,023
181
666
1,440
47
723
116
3,206
Z071
573
1,106
1,312
1,439
518
256
2,453
834
1,432
645
113
No 01
FicilitiM
7
311
261
2
140
1,427
147
355
51
354
492
13
256
40
1,036
648
184
267
219
532
152
79
683
271
447
215
24
HAP
MMm
(IH*r)
1,319,895
90,774,819
28,069,292
0
8,186.317
61,088,527
5,941,487
24,432,969
8,505,907
17,824,654
77,076,554
386,315
29,124,492
1,742,093
80,426,499
93,609,775
18,497,764
38,538,236
50,895,973
23,700,028
13,177,965
11,622,816
93,837,027
41,952,806
38.603,617
40,787,633
2,009,046
Total
Eminent
(IWyr)
31.538,413
102,358,308
53,042,954
27,750
17,665,050
88,989,864
10,575,961
27,889,433
9,155,948
51,005,159
93,139,842
966,550
40,333,436
5,040,834
106,191,820
116,145,318
28,048,660
53,956,980
148,837,096
32,319,851
20,544,923
16,186,678
119,780,329
50,174,935
49,462,906
58,807,963
5,675,133
State %
OITotilTRI
Eminent
1.15
3.72
1.93
0.00
0.64
323
038
1.01
0.33
1.85
3.38
0.04
1.47
0.18
3.86
422
1.02
1.96
5.41
1.17
0.75
0.59
4.35
1.82
1.60
2.14
021
State
NC
ND
NE
NH
NJ
NM
NV
NY
OH
OK
OR
PA
PR
Rl
SC
SD
TN
TX
UT
VA
VI
VT
WA
Wl
wv
Wf
No. 01
Release
Reports
2,055
56
312
317
2,370
102
55
2,193
3,945
528
527
2,931
377
343
1,148
54
1,311
4,014
311
1.082
17
114
807
1,658
545
80
54,349
NO. a
FiciMin
709
25
122
117
725
32
28
737
1.153
178
185
889
131
143
331
28
437
907
86
345
1
41
284
567
98
17
16,929
HAP
Emneiont
(ib/yr)
82,087.503
610,023
8,607,259
9,644,847
30,866,552
1,632,541
619,720
79,033,904
95,546,373
18,871,589
14,964,242
69.118,767
9,309,172
6,155,456
51,418,664
1,789,295
85,696,941
107,327,475
82,862,166
118,887,942
1.715,600
946.269
21,496.421
37.942.192
29.000,596
1.303,830
1,869,589,845
Total
Emttuont
(Ib/yr)
102.293,456
1,666.024
14,463,697
12,593,688
43,791,313
3,898,634
772.396
100.183.463
142.697.406
37.158,341
21,525,234
93.706,968
12.710.823
7.881.481
66.178.001
2,514,080
137.386.837
249.227.478
86,323,243
141.289.197
1,773,873
1,270,453
39,361,961
49.536.797
41.727.020
2.939,454
2.752,733.632
State %
Of Total TRI
Emmione
3.72
0.06
0.53
0.46
1.59
0.14
0.03
3.64
5.18
1.35
0.78
3.40
0.46
0.29
2.40
0.09
4.99
9.05
3.14
5.13
0.06
0.05
1.43
1.80
1.52
0.11
100.00
3-33
-------
1987 EMISSIONS
Three-Digit ZIP Code Areas
Since ZIP Codes are assigned generally
according to population, three-digit ZIP
Code areas represent convenient
geographic areas smaller than states.
Figure 3-27 and Table 3-48 show the top
20 ZIP Code areas. Area 840 in Utah
reported the greatest emissions with more
than 4% of the national total. The top 20
areas together reported almost 26% of the
national total.
Figure 3-27
20 ZIP Code Areas With Greatest Toxic Air Emissions
STATE tS&GtTZF CODE
1.UT...840 4.TN...376
2.TX...775 5.AL...365
3. VA... 226 6. LA... 703
7. LA... 700
8.AK...996
9.TX...797
10.TX... 776
11. Ml... 480
12. NY...146
13. LA... 707
14. VA... 244
15. NC... 286
16.TX...779
17. LA... 706
18.TN...377
19, At... 356
20.GA...314
Table 3-48
3-Digit ZIP Codes
— 1987—
3-Oigit
ZIP Code
840
775
226
376
365
703
700
996
797
776
State
UT
TX
VA
TN
AL
LA
LA
AK
TX
TX
No Of
n-t
nvmw
Rtportt
127
1,076
45
129
165
48
280
18
70
237
No. Of
FicilltMi
30
114
12
27
21
11
35
3
14
26
HAP
CTTMWOIM
<«»W
79,693.562
37,447,3%
53,864,892
17,509,812
47,688,861
2,643,110
7,073563
348,025
2,126,028
10,555268
Total ZIP*
Emiwiom OfTotilTRI
(lU/Vr) EmittJont
80,404,209
75,638,519
54,112,601
53.276,986
48,562,188
44,101,738
32,340,914
30,551,825
29,039,058
27,844,287
2.92
2.75
1.97
1.94
1.76
1.60
1.17
1.11
1.05
1.01
3-Dioit
ZIP Code
480
146
707
244
286
779
706
377
356
314
State
Ml
NY
LA
VA
NC
TX
LA
TN
AL
GA
No. 01
Retowe
Reports
387
197
337
50
363
95
215
64
165
68
No. Of
FiciMin
106
47
36
17
118
13
25
24
39
20
HAP
EmiMioni
(»*r)
24,133,692
21,079,005
12,961.101
20,896,673
19,925,968
2,893,857
7,680,927
19,402,905
15,290,163
17,199,190
Total
EmiMioni 0
(IWyr)
26,516,990
26,235,492
22,374,031
21,947,671
21.843,602
21,295,388
20,034,371
19,715764
19,249,498
19,194,300
ZIP%
Total TRI
[mwHon*
0.96
0.95
0.81
0.80
0.79
0.77
0.73
0.72
0.70
0.70
4.136
738 420,613,997 694,278,932
25.22
3-34
-------
1987 EMISSIONS
Counties
Figure 3-28 and Table 3-49 show the 20
counties with the greatest emissions. Again,
Utah had the county reporting the greatest
emissions. Together the top 20 counties
reported 24% of the total national emissions.
Three of these counties included more than
100 facilities while seven had fewer than ten.
The distribution of counties reporting the
largest emissions generally reflects the same
geographic concentration as the state and
ZIP Code areas, with the large emission
reports coming from the industrial areas.
figure 3-28
20 Counties Witt Greatest Toxic Air Emissions
COUNTY AND STATE
1.Tooete,UT 4. Hams, TX
2 Ascension, LA 5. Mobile, AL
3. Warren, VA 6. Sullivan, TN
7. Los Angeles, CA
8. Cook, L
Q.Kenai-Cooklniet.AK
10. Ector.TX
11. Monroe, NY
12. Jefferson, TX
13. Brazona.TX
14. Chatham, GA
15. Calcasieu, LA
16.Calhoun,TX
17. Allegheny, VA
16. Mississippi, AR
19. St. James, LA
20. HamWen, TN
Table 3-49
Counties
— 1987—
County Still
Tooele
Ascension
Warren
Harris
Mobile
Sullivan
Los Angeles
Cook
Kenal Peninsula
Eclor
UT
LA
VA
TX
AL
TN
CA
IL
AK
TX
No. Of
HtlMM
Rtports
7
137
16
1,063
179
87
1,733
1,455
18
39
No. 01
Ficilrtwi
3
14
2
195
25
10
590
485
3
6
HAP
CnMmminnm
L (TV* BIO TO
<«i/yr>
76,990,850
7,138,666
51,049,650
31,423,089
48,860,435
8,824,570
27,847,064
28,941,283
348,025
1,314,626
Total County%
Emissions Of Total TRI
(IWyr) Emissions
76,990,850 2.80
53,192,833 1.93
51,098,900 1.66
51,013,127 1.85
50,131,309 1.82
42,157,825
37,142,886
36,451,718
30,551,825
27,426,263
.53
.35
.32
.11
.00
County Stitt
Monroe
Jefferson
Brazoria
Chatham
Calcasieu
Calhoun
Alleghany
Mississippi
SUames
Hamblen
NY
TX
TX
GA
LA
TX
VA
AR
LA
TN
No. 01
Release No. Of
Reports FaeilitM*
225
321
192
68
192
64
19
42
45
36
57
32
16
20
20
7
4
12
6
17
HAP
F*nlmmi*.mM
tmlitWnS
(IbM
21,879,315
9.245,670
9,061,338
17,199,190
6,686,739
1,731,973
17,081,669
2,980.128
1,062,259
16,728,883
Tottl County \
Emotions OUoUITRI
(IWyO Emtoiora
27,147,265
23,474,705
22,300,923
19,194,300
18,805,514
18,123,053
17,845,769
17,257,687
17,252,819
16,793,737
0.99
0.85
0.81
0.70
0.68
0.66
0,65
0.63
0.63
0.61
5.958 1,526 386,415,422 654,353,308
23.77
3-35
-------
Figure 3-29
Toxic Air Emissions
- BY U.S. INDUSTRY -1987-
800
Number Of Emitters
1,600 2,400
3,200
4,000
Food jjip
Tobaoo
Textiles (jjjjip
Apparel i|||
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather jj
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
D No. Of Bullets
• Total Emissions
200 400 600 800
Total Emissions- In Million Pounds Per Year
1,000
1987 EMISSIONS
Industries by
2-Digit SIC Code
As shown in Figure 3-
29 and Table 3-50, the
chemicals industry is by
far the largest industrial
emitter with more than
one third of total nation-
al emissions. Together
with the Pulp & Paper,
Primary Metals, and
Transportation Equip-
ment industries, four
industries reported 64%
of the total. Figure 3-29
shows a comparison of
total emissions with
number of facilities.
This shows that the
Pulp & Paper facilities
generally report high
emissions per facility
(more than 470,000
pounds per facility)
2-Digit
SlCCode
US Indmtry
Table 3-50
Air Emissions By U.S. Industry
—1987—
No. Of
Emittm
ToUIEmitsioni Indwtiy % Of Totil
Wit) THI E
U.S. Indurtiy
No. 01
Emitters
Tom EmMont Indwtiy % Of Total
THI Eimoiom
70
7\
7?
n
?4
?S
26
?7
?fl
29
Food
Tobacco
Textiles
Apparel
Lumber „
Furniture »
Pulp4Pap«r
Printing
Chemicals
Petroleum Refining
6S3
24
323
35
464
426
569
309
3,517
305
21 128 105
6,768,722
46,050449
2,753,619
29259,256
56,978226
268,281,645
63,330,437
966,334,064
105,111,872
077
025
167
0.10
1.06
207
9.75
230
35.83
3.82
30
31
32
33
34
35
36
37
38
39
Rubber Plastics
Leather „
Stone Clay Glass
Primary Metals
Fabricated Metals
Non-Elect Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manufacturing
1253
118
545
1414
2.458
882
1,519
1023
338
341
180609219
14,847,725
32.320624
267773,799
135399921
60023399
128,165,761
240892,720
61 074 605
26,624,846
656
054
117
973
492
2.18
4.66
875
222
1.05
3-36
-------
figure 3-30
Number Of Release Reports
—BY U.S. INDUSTRY-1987—
compared to Fabri-
cated Metals, for
example, which report
a relatively small
amount per facility
(about 55,000 pounds
per facility).
Figure 3-30 and Table
3-51 show the num-
ber of release reports
submitted to EPA for
TRI reporting. Again
the chemicals indus-
try has about 30% of
the national total.
Each report repre-
sents one chemical
released at a single
facility. Because the
chemicals industry is
such a large part of
the total, additional
details on the industry
are presented below.
U.S. INDUSTRY
Food
Tobacco
Textiles Jjjj
Apparel ||
Lumber |
Furniture |
Pulp & Paper |
Printing |
Chemicals
Petroleum Refining
Rubber, Plastics
Leather |
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transportation Equip.
Instruments
Misc. Manufacturing
0
2,500 5.000 7.500 10,000 12,500 15,000 17.500
Number Of Release Reports
20,000
Table 3-51
Mo. if Release Reports by U.S. Industry
—1967—
lie"!
2(1
21
??
71
?4
K
ffi
'7
?fl
?fl
ode U.S. Industry
Food
Tobacco
Textiles _
Apparel
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Rellnlna ...
No. 01
RrtMM
Repoitt
1278
42
577
51
1,228
1412
1,880
538
16,324
2.593
Industry %
a tini
TRI Reports
0.77
025
1.67
0.10
1.06
2.07
9.75
2.30
35.83
3.82
2-Dic
sec
30
31
32
33
34
35
36
37
38
39
ode U.S. Indwtry
Rubber, Plastics
Leather
Stone, Clay, Glass
Primary Metals
Fabricated Metals
Non-Elect. Machinery
Electrical Equipment
Transport. Equipment
Instruments
Misc. Manulaclufina
No. Of
RetaM
Reports
2,839
341
1,349
4,792
6,296
2,034
4,258
3,932
847
770
Industry %
01 nw
TRI Reports
656
054
1.17
9.73
4.92
2.18
4.66
8.75
222
1.05
3-37
-------
Chemicals And Allied Products
Industrial Inorganic
Chemicals
Plastics Materials &
Synthetic Resins/Rubber,
made Fibers, Except Glass
Drugs
Soap, Detergents, &
Cleaning Preparations;
Perfumes, Cosmetics, &
Other Toilet Preparations
a i
aw 1
nor i
2102 1
2tOS 1
2110 1
2(12 1
2813
wis-
2816
»ir
2t19 1
2121
2«20
2122
»4
net
MM
2K
283•:>:: QlSii: •<•••••• ,
mmm • ••••.'.-. ;.::.•.;,;. -.•:::.,::•:"
is;;;;; m± mi m< mm m-. ;Sk' |i i; 1 i ill |lf:; 1$ :;:
i::-' ::;: ••••: ;. v •'•: : : • mmmmf mmsm ;::
=— "
: :• • •"••<• •'•..•,:•• V%Z :j:j|$ :*:*:• igjpi xfiS S;:;:;:- ^^ :;B:W :ijx:- !:S;
•;. ;•..;• '
WS iilji SSS;: ;i;i;i;S ;||;i; isio !il? il*:r.:'' ' •
•
Paints, Varnishes. Lacquers,
Enamels, & Allied Products
Industrial Organic
Chemicals
Agricultural Chemicals
2871
* SlO'Codem/wt* listed
M&rijA'Classification tAsmft
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200
Total Emissions - In Million Pounds Per Year
1987 EMISSIONS
Industries by
3 and 4-Digit
SIC Code
To subdivide the indus-
trial sector further,
Tables 3-52 and 3-53
present the top indus-
tries by 3-digit SIC
codes and 4-digit SIC
codes respectively. The
top ten industries as
shown in Table 3-52
represent 54% of total
emissions. By breaking
it down one level fur-
ther, the top ten 4-digit
industries, as shown in
Table 3-53, reported
41% of the total
Figure 3-31 shows the
toxic air emissions re-
ported by all of the 4-
digit chemical indus-
tries. Plastic materials,
industrial organic
chemicals, and agricul-
tural chemicals are die
segments of die indus-
try reporting die major-
ity of die industry's
emissions.
3-Digtt
sirT
Rank Code
1
2
3
4
5
6
7
8
9
10
282
286
287
371
333
281
307
261
291
331
Table 3-52
Top Industrial Emitters • 1987
3-DIGIT SIC CODES
Tout Industry % Industry %
EmMont Ot2-Digit Of Total TO
U.S. Imkntry (Ihfyr) SIC Total Eminiom
Plastics Materials & Synthetic Resins.
Synthetic Rubber, Cellulosic & Other
Manmade Fibers, Except Glass
Industrial Organic Chemicals
Agricultural Chemicals
Motor Vehicles &
Motor Vehicle Equipment
Primary Smelting
& Refining of Nonlerrous Metals
Industrial Inorganic Chemicals
Miscellaneous Plastics Products
Pulp Mills
Petroleum Refining
Steel Works, Blast Furnaces,
& Rolling (Finishing Mills
281,787.«7
236,052,679
219,969,105
142,480,452
139,831,819
112,801,463
109,982,387
97,442,223
95,244,002
63,879,798
1.499,471.415
28.57
23.93
22.30
59.15
52.22
11.44
60.90
36.32
90.61
23.86
10.24
8.58
7.99
5.18
5.08
4.10
4.00
3.54
3.46
2.32
54.47
4-Digit
SIC
Rink Code
1
2
3
4
5
6
7
8
9
10
2869
2873
2821
3079
2823
2911
3711
2611
3339
2819
Table 3-53
Top Industrial Emitters • 1987
4-DIGIT SIC CODES
Total lndmtry% SIC%
EmMom Ot2-OK)it OfToUITRI
U.S.Inducby (Ibfyr) SjCCod* EmMom
Industrial Organic Chemicals,
Not Elsewhere Classified
Nitrogenous Fertilizers
Plastics Materials, Synthetic Resins,
& Nonvulcanlzable Elastomers
Miscellaneous Plastics Products
Hplliilnsir MannurlP Pltorc
Petroleum Refining
Motor Vehicles & Passenger Car Bodies
Pulp Mills
Primary Smelling &
Retinlrtg of Nonterrous Metals.
Except Copper & Aluminum....
Industrial Inorganic
Chemicals, Not Elsewhere Classified....
197,709,781
180,745,494
140,064.943
108,153,975
102,156.702
95,243,502
85,315,599
84.607,366
83,513,443
58,764.259
1.136.365.064
20.04
18.32
14.20
59.88
10.36
90.61
35.42
31.57
31.19
5.96
7.18
6.57
5.09
3.93
3.71
3.46
3.10
3.08
3.03
2.13
41.28
3-38
-------
Table 3-54
Chemicals Emitted in the Greatest Amount
—1987—
Chemial
Ammonia
Toluene
Melhanol
Acetone
1,1,1-Tricfiloroelhane
Methyl ElhylKelone
Xylene (Mixed Isomers)
Carbon DlsullMe
Dichloro methane
Chlorine
Mo. a
Emitttn
2,174
3,370
2,006
2,230
3,235
2,230
2.878
75
1,474
1.210
Total
Emissions
(IWM
268,662,920
287.852,372
215,232,880
195,382,721
162.870,224
152.253,887
147.727.850
135,392,401
131,093,612
107.179,298
Chemical %
Of Total
TRI Emissions
10.52
10.46
7.82
7.10
5.92
5.53
5.37
4.92
4.76
3.89
Cumulative
Chemical %
10.52
20.96
28.80
35.90
41.82
47.35
52.72
57.64
62.40
66.29
Ctumical
No. 01
Emitted
Aluminum (Fume Or Dust)1 ,149
Hydrochloric Acid
Elhylene
Freon113
Trichloroelhylene
Glycol Ethers
Propylene
Telrachloroelhylene
n-Bulyl Alcohol
Slyrene
2,088
236
1,107
888
995
283
651
911
923
Total
Emissions
(iwyr)
90,852.286
7Z783.444
60,011.146
56,946.595
53,740.241
41,994,951
38,906.600
32,701,045
32,572,937
32,076,780
Chemical %
01 Total
TRI Emissions
3.30
2.64
2.18
£07
1.95
1.53
1.41
1.19
1.16
1.17
Cumulative
C hernia! %
69.59
72.23
74.41
76.48
78.43
79.96
81.37
82.56
83.74
84.91
2,337,234,190
84.91
1987 EMISSIONS
Individual Chemicals
Figure 3-32 and Table 3-
54 show the individual
chemicals emitted in the
greatest amount. The 10
top chemicals represent
about 66% of the total
emissions while the 20
top chemicals represent
almost 85% of the total.
Toluene and ammonia
emissions each represent
more than 10% of the
national total.
1987 EMISSIONS
Groups of Chemicals
It is useful to look at
groups of chemicals
whose emissions are tar-
geted by EPA programs.
None of these programs
were underway during
1987 so the effect of the
program does not show up
in the reported emissions.
PERCENT
100 mm
90
Figure 3-32
U.S. Air Toxics Emissions
—1987—
Others
Chlorine
Dichloromethane
Carbon Bisulfide
Xylene (mixed isomers)
Methyl Ethyl Ketone
1,1,1-Trichloroettiane
Acetone
Methanol
Toluene
Ammonia
3-39
-------
Table 3-55
Major Sources
— 1987—
The Number of Facilities Emitting
1 0 TRY of Any One HAP or 25 TPY of Any HAPs
10 Toy 25 Tn
OOnaHAP 01 Any HAPs
5.M6
4.212
10 Or 25
5.962
Emosiora
1JB15.1SS.7S
tdf HAP%
Tom HAP Of Total
Emissions Tn Emissions
9709
6792
Hazardous A
Air Act Amen
chemicals for <
Major sources
emit 10 tons p
tons of total H
mum available
3-55 shows th<
1 J 1 * £
would qualify
to the
TRIrepi
17 of the 1891
Clean
Air Act
Table 3-56
HAPs Emitted In the Greatest Amount
Chemical
Toluene
Methanol
1.1,1-Tricnloroelhane
Melhyl Elhyl Kelone
Xylene (Mixed Isomers)
Carbon Dlsullide
Dlcntoromeihane
Chlorine
HydrocfitorlcAcId
Trlchloroelhylene
No 01
Emittas
3.370
2.006
3.235
2,230
2,878
75
1.474
1.210
£088
888
Total
Emissions
(Ib/yr)
287,852,372
215.232,880
162,870,224
152,253,887
147,727,850
135,392,401
131,093,612
107,179,298
72.783,444
53,740,241
—
Chemical %
01 Total
TRI Emissions
1046
782
592
553
537
492
476
389
264
195
1987—
i Chemical
: Glycol Ethers
• Tetrachloroethylene
; Styrene
! Benzene
i Methyl Isobutyl Kelone
Chlorolorm
. CarbonylSul'lde
. Elhylene Glycol
Formaldehyde
! Chloramethane
No 01
Emitters
995
651
923
460
778
157
24
746
686
79
Total
Emissions
(Ib/yr)
41.994.951
32,701,045
32,076,780
31,203.577
29.595.348
24,674,317
22,487,005
15,428.233
13.455.716
13,134.398
1.722,877.579
Chemical %
Of Total
TRI Emissions
153
119
117
113
108
090
082
056
049
048
6259
Table 3-57
33/50 Chemicals Emitted in the Greatest Amount
— 1987—
Chemical
Toluene
1,1,1-Tnchloroelhane
Melhyl Ethyl Kelone
Xylene (Mixed Isomers)
Dichloromelhane
Trichloroelhylene
Telrachloroelhylene
Benzene
Melhyl IsobulylKetone
Chlorolorm
p-Xylene
Carbon Tetrachtoride
o-Xylene
No 01
Emitters
3.370
3,235
Z230
2,878
1,474
888
651
460
778
157
52
87
90
Total
(H&r)
287,852,372
162,870,224
152.253,887
147,727,850
131,093,612
53,740,241
32,701,045
31,203,577
29.595,348
24.674,317
7.437,936
4,378,209
3,660,212
Chemical %
01 Total
TRI Emissions
1046
592
553
537
476
195
119
113
108
090
027
016
013
•
. Chsrflittl
m-Xylene
: Lead
: Cyanide Compounds
Lead Compounds
Chromium Compounds
Nickel
Chromium
Nickel Compounds
Cadmium Compounds
Mercury
Cadmium
: Mercury Compounds
No Of
Emilten
67
472
205
384
546
464
558
251
52
29
42
5
Total
Emissions
(lb/yi
2.995,819
1.469.218
1.419.188
1.158.164
775.139
419.585
407.195
306.365
163.918
23.409
14.119
2.336
1,078,363,185
Chemical %
01 Total
TRI Emissions
0.11
005
005
004
003
002
001
001
001
000
000
000
3918
These 5,962 facilities,
which is equivalent to
35% of the total facili-
ties reporting, repre-
sent 97% of the total
HAP emissions and
68% of all TRI chemi-
cal emissions. Table
3-56 show the twenty
HAPs emitted in the
greatest amount. They
represent almost two
thirds of the total
national emissions.
33/50 Chemicals -
EPA initiated a volun-
tary emissions reduc-
tion program targeting
17 specific chemicals
(or groups of related
chemicals in some
cases). Reported
emissions of these
chemicals are shown
in Table 3-57.
Together this group of
chemicals is equiva-
lent to 339% of the
total toxic emissions.
3-40
-------
High Risk/Early Reduction
Chemicals - Table 3-58 lists 20 high
risk/early reduction chemicals. These
chemicals are considered high risk
because of their toxicity. Together
they represented about 2% of the total
national toxics emissions in 1987.
Carcinogens - Table 3-59 summarizes the
emissions of the 20 carcinogens emitted in the
greatest amount as reported to the TRI. Their
significance is due to their carcinogenicity.
Together the top twenty represent 13% of total
emissions with the largest carcinogen,
dichloromethane or methylene chloride,
almost 5%.
Table 3-58
Table 3-59
• ••MH •••«•«( IIDVlI
Emitted In
• • •*wwiw««WM w •• w"" WBW
the Greatest Amount
- 1987-
NoOl
Total
Emissions
Chemicil Emifleis (ili/yo
Benzene
1,3-Buladlene
Acrylonllrlle
Elhylene Oxide
Vinyl Chloride
Chloroprene
MeUiylenebis
(PhenyllsocyanatB)
Acrylic Add
Toluene-2,4-Dllsocyanate
Chromium Compounds
Vlnylldene Chloride
Chromium
Melhyllsocyanate
Arsenic Compounds
Cadmium Compounds
1.1.2.2-Telraehloroethane
Phosgene
Dlbenzoluran
1,2-01 bromoelhane
Asbestos (Friable)
460
140
95
190
46
12
151
127
207
546
21
558
5
105
52
16
30
98
34
60
31,203,577
9,413,317
5,387,496
5,184,403
1.794,472
1,064.028
834.270
831.599
788.742
775,139
466,859
407.195
286,544
284,221
163,918
126,289
83,640
76,545
65,669
51,461
59.289,384
Chemical t
Otlotil
TRI Emissions
113
034
020
019
007
004
003
003
002
003
002
001
001
001
001
000
000
000
000
000
Z15
The Greatest Amount
: - 1987—
Chemical
Dichlofomelhane
Trichloroelhylene
; Telrachioroelhylene
Slyrene
Benzene
Chloroform
i Formaldehyde
Chloromelhane
; 1,3-Buladiene
: 1.2-Dichloroelhane
Acrylonllrile
i Elhylene Oxide
: Carbon Telrachloride
j 1,1.2-Trlchloroelhane
: Vinyl Chloride
: Urelhane
; Vlnylldene Chloride
2-Nilropropane
Epichlorohydrin
Chromium
No 01
Emitters
1,474
888
651
923
460
157
686
79
140
112
95
190
87
51
46
7
21
13
67
558
Total
Emissions
131.093,612
53.740,241
32.701,045
32.076,780
31,203.577
24.674.317
13.455.716
13.134,398
9.413,317
6,368,587
5.387,496
5.184,403
4.378.209
2.139.959
1,794.472
797.000
466.859
466.252
423,522
407,195
369.306,957
Chemical *
01 Total
TRI Emissions
476
1.95
119
117
113
090
049
048
034
023
020
019
016
008
007
003
002
002
002
001
1342
Table 3-60
TRI Dane Depletors Emitted In
The Greatest Amount
—1987—
Chemical
1,1,1-Trtchloroelhane
Freon113
Carbon Telrachloride
Mo Of
Emitters
3,235
1,107
87
Total Chemical %
Emissions 01 Total
(Ityr) TRI Emissions
162,870,224
56,946.595
4,378.209
592
207
016
Ozone Depletors - In 1987, only
three ozone depletors were included
in the TRI database. Table 3-60
summarizes their emissions, which
about 8% of all toxic emissions.
224,195.026
814
341
-------
SECTION 4
Data Handling
Procedures
This section describes the data handling pro-
cedures used to create the Basic and Linked
data sets on which the analyses in this report
are based. Since the report's focus is on air
emissions, several of the data fields in the
master database were not used. For each
year's data, two sets were created: first, a
quality-reviewed set of all air emissions data
and second, a subset of that data, which rep-
resented emissions reported by facilities that
responded in all four years. The first set
(Basic Set) was used for the analysis of each
year's air emissions and the second (Linked
Set) was used to compare changes from year
to year. This section explains how each data
set was created.
4-1
-------
Data Management
The latest versions of the TRI data tapes
were obtained for 1987, 1988, 1989, and
1990. The tapes used for this report were
created March 21,1992. Any data revisions
made to EPA's master data files before
March 21,1992 are included in this data set.
Data revisions include quality control modi-
fications made by EPA or data revisions vol-
untarily submitted by an individual facility.
The tapes were obtained from: TRIS User
Support/Public Data Branch in EPA's Office
of Pollution Prevention and Toxics. The
1989 TRI tape documentation was obtained
from the National Technical Information
Service (NTIS), (PB91-187500) Springfield,
VA. TRI tapes also are available for pur-
chase from NTIS.
Data Extraction
and Handling Procedures
Selected variables were extracted from the
TRI data tapes for each of the four years.
The data was used to develop a new set of
four data files in Statistical Analysis System
(S AS). The new set of data files was labeled
the Basic set. The variables selected are list-
ed in Table 4-1.
Substance name, CAS number, and air emis-
sion quantities for each year were quality
reviewed for misspellings and outliers.
Unique substance names and CAS numbers
were reviewed for typographical errors and
inconsistencies. The substance names were
standardized by making various modifica-
tions. For example, some companies simply
reported 'Xylene.' These repors were
included as 'Xylene (mixed isomers)' rather
than the individual names of o-Xylene, m-
Xylene, or p-Xylene. Some substances, such
as antimony compounds, do not have CAS
numbers. The CAS number may have been
reported as a blank or NA. If the CAS num-
ber was reported as NA, it was modified to a
blank for data processing consistency.
Table 4-1
Variable List
• Document Control
Number
• Reporting Year
• Last Revision Date
• EPA Region
• Covered Facility
• Facility Name
• Facility Street
Address
• Facility City
• Facility County
• Facility State
• Facility ZIP Code
• Parent Company
Name
• TRI Facility ID
• CAS Registry Number
• Substance Name
• Trade Secret Status
• Maximum Amount
Onsite
• Waste Minimization
Modification
• Waste Minimization
Current Year Quantity
• Waste Minimization
Prior Year Quantity
• Waste Minimization
Percent Change
• Waste Minimization
Ratio of Production
• Waste Minimization
Reason for Action
• SIC Codes
(1 through 4)
• Release Medium
• Release Transfer
Amount
• Basis for Estimate
• Sum of Air Releases
• Sum of Water
Releases
• Sum of Land Releases
• Sum of All Releases
• SumolPOTW
Transfers
• SumofOffsite
Transfers
• SumolPOTW and
Otfsite Transfers
• Sum of All Releases
and Transfers
4-2
-------
The list of substances required to be report-
ed to EPA and contained in the TRI data
files have been revised over the four years.
Several substances were dropped from the
TRI data collection because of low toxicity.
A few substances also were added to TRI
after 1989 reporting that affected 1990
reporting. Substances that were not required
to be reported in all four years were deleted
from the data files for ease in comparing
results. Delisted chemicals that were delet-
ed from the data files are listed in Table 4-2.
The chemicals added to TRI after
1989 were deleted from the 1990 data
file and are listed in Table 4-3.
Reports missing a substance name
(i.e. blank or NA) or with zero air
emissions for a specific substance
were suppressed.
A single report should be contained in
the data file for each chemical report-
ed by a particular facility. If a chemi-
cal was reported more than once at a
facility, only the report with the great-
est air emissions for that chemical
were retained in the data file.
Exceptionally large emissions were
identified by substance and facility
and checked for reasonableness.
Also, a report for a chemical can list
up to six four-digit SIC codes. The
first SIC code listed for each chemical
was assumed to be the primary SIC
code and, therefore, the only SIC
code used in subsequent analysis.
Each industrial facility required to
report its emissions to EPA is
assigned a unique TRI facility identi-
fication. The TRI facility identifica-
tion for a particular facility remains
constant from reporting year to
reporting year. The Linked set of data
files was created by matching the TRI facili-
ty identification variable from year to year.
Since the TRI facility identification variable
was used in linking the data files, the proce-
dure was not affected by ownership or name
changes that may have occurred over the
four years. Facilities that did not submit
data in all four reporting years were exclud-
ed from the data files. The Linked set of
data files was used for analyzing changes in
emissions over the four years to identify
possible trends.
Table 4-2
Delisted Chemicals
Chemical
Delistmgs to TRIS made prior
to 1989 reporting:
CAS No
Aluminum Oxide (Non-Fibrous Forms)
CI Acid Blue 9, Diammonium Salt
Cl Acid Blue 9. Disodium Salt
Melamme Crystal
Sodium Hydroxide (Solution)
Sodium Sullate (Solution)
Titanium Dioxide
1344-28-1
2650-18-2
3844-45-9
108-78-1
1310-73-2
7757-82-6
13463-67-7
Chemical
Delistmgs to TRIS made after
1989 reporting (affected 1990 reporting);
CAS No
TerephthalicAcid
CI Pigment Green 7
Cl Pigment Blue 15
CI Pigment Green 36
100-21-0
N/A
N/A
N/A
Table 4-3
1990 Chemical Additions
Chemical
CAS No
Allyl Alcohol
Creosote
2,3-Dichloropropene
m-Dmitrobenzene
o-Dimtrobenzene
p-Dinrtrobenzene
Dinitrotoluene (mixed isomers)
Isosafrole
Toluene Dnsocyanate (mixed isomers)
107-18-6
8001-58-9
78-88-6
99-65-0
528-29-0
10-25-4
25321-14-6
120-58-1
26471-62-5
4-3
-------
The data sets created fol-
lowing quality review and
linking are summarized in
Table 4-4. There are three
sets of data files:
• Original - The latest
EPA version of the data
files as of March 21,
1992 with no modifica-
tions.
• Basic - The quality
reviewed and modified
Original data file.
• Linked -The Basic data
files reduced to only
those facilities that occur
in all four reporting
years.
Table 4-4
Data File Characteristics
1987
Ho. Of Panat Companies
Original 5,563
Basic 5.547
Linked N/A
Ho. Of Facilities
Original
Basic
Linked
Linked % of Basic
Ho. Of Reports
Original
Basic
Linked
Linked % of Basic
16,978
16,929
12,114
72%
55,813
54,349
44,200
81%
Total Air Emissions (Ib/yr)
Original 2,808,860,778
Basic 2 752.733,632
Linked 2,469,943,911
Linked % of Basic 90%
1988
4,369
4.307
N/A
18,693
18,300
12.114
66%
62,512
58,337
45.654
78%
2,713,310,406
2.606,642.759
2.296,357.362
88%
4.880
4,876
N/A
19.871
19.856
12,114
61%
65,441
64,786
48,659
75%
2,561.151,806
2,501,993.075
2.201,351.417
1990
5,354
5,336
N/A
20,366
20.270
12,114
60%
66.170
65.676
48.410
74%
2.203,511,260
2.194,922.597
1.920.165.616
87%
As can be seen from Table 4-4, the quali-
ty control modifications were quite small,
generally affecting less than 2% of the
original data. Linking facilities over the
four year period also required little dele-
tion of data. The linked data set included
about 88% of the basic data set.
A final change made to the data sets for
use in analyzing the data was the addition
of chemical type identifiers. These includ-
ed: Hazardous Air Pollutant (HAP), EPA's
33/50 Program, High Risk/Early Reduction,
Carcinogen, and Ozone Depletor. The chemicals
listed under each category are provided in Tables
4-5 through 4-9. A chemical type category, such
as High Risk/Early Reduction, may contain
chemicals that are not required to be reported
under the TRI system. These chemicals are
included in the tables to provide a complete list.
Summary tables are provided in the appendix that
list all of the chemicals reported each year with
CAS number, and amount emitted. The chemical
type identifiers also are listed.
Table 4-5
Hazardous Air Pollutants
Chemical
1,1,1-Tnchloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trchloroethane
1.1-Dichloroethane*
1,1 -Dimethyl Hydrazine
1,2,4-Tnchlorobenzene
1,2-Butylene Oxide
1 ,2-Dibromo-3-Chloropropane
Cast
000071556
000079345
000079005
000075343
000057147
000120821
000106887
000096128
Chemical
1 ,2-Oibromoethane
1,2-Dichloroethane
1 ,2-Dichloropropane
1 ,2-Diphenylhydra7ine
1,3-Butadiene
1 ,3-Dichloropropylene
1,3-PropaneSultone
1,4-Dichlorobenzene
Cast
000106934
000107062
000078875
000122667
000106990
000542756
001120714
000106467
Chemical
Casl
1.4-Dioxane 000123911
2,2,4-Trimethylpentane" 000540841
2,3,7,8-Tetrachlof odibenzo-p-Oioxin- 001746016
2,4,5-Tnchlorophenol 000095954
2,4,6-Trichlorophenol 000088062
2,4-D 000094757
2.4-Diaminotoluene 000095807
2,4-Dimtrophenol 000051285
4-4
-------
Chemical
Cas/
2,4-Dimtrotoluene
2-Acetylammofluorene
2-Chloroacetophenone
2-Nitropropane
3,3-Dichlorobenzidene
3.3-Dimethoxybenzidme
3,3'-Dimethylbenzidine
4.4-Methylene Bis(2-Chloroamlme)
4,4'-Methylenedianiline
4,6-Dimtro-o-Cresol
4-Ammobiphenyl
4-Nitrobiphenyl
4-Nitrophenol
Acetaldehyde*
Acetamide
Acetonitnlle
Acetophenone*
Acrolein
Acrylamrde
Acrylic Acid
Acrylonitnle
Allyl Chloride
Aniline
Antimony Compounds
Arsenic Compounds
Asbestos (Friable)
Benzene
Benzidme
Benzoic Trichloride
Benzyl Chloride
Beryllium Compounds
Beta-Propiolactone
Biphenyl
Bis(2-Chloroethyl) Ether
Bis(Chloromethyl) Ether
Bromoform
Bromomelhane
Cadmium Compounds
Calcium Cyanamide
Caprolactam*
Captan
Carbaryl
Carbon Disulfide
Carbon Tetrachlonde
Caibonyl Sulfide
Catechol
Chloramben
Chlordane
Chlorine
000121142
000053963
000532274
000079469
000091941
000119904
000079447
000101144
000101779
000534521
000092671
000092933
000100027
000075070
000060355
000075058
000098862
000107028
000079061
000079107
000107131
000107051
000062533
001332214
000071432
000092875
000096077
000100447
000057578
000092524
000111444
000542881
000075252
000074839
000156627
000105602
000133062
000063252
000075150
000056235
000463581
000120809
000133904
000057749
007782505
Table 4-5
Hazardous Air Pollutants
(CONTINUED)
Chemical Cas /
Chloroacetic Acid
Chlorobenzene
Chlorobenzilate
Chloroform
Chloroethane
Chloromethane
Chloromethyl Methyl Ether
Chloroprene
Chromium Compounds
Cobalt Compounds
Coke Oven Emissions*
Cresol (Mixed Isomers)
Cumene
Cyanide Compounds
DDE*
Diazomethane
Di(2-Ethylhexyl) Phthalate
Dibenzoluran
Dibutyl Phthalate
Oichloromethane
Oichlorvos
Oietnanolamine
Diethyl Sulfate
Dimethyl Aminoazobenzene
Dimethyl Carbamoyl Chloride
Dimethyl Formamide*
Dimethyl Phthalate
Dimethyl Sulfate
Epichlorohydrin
Ethyl Acrylate
Ettiylbenzene
EthyleneGlycol
Ethylene Oxide
EthyleneThiourea
Ethyleneimine
Fine Mineral Fibers*
Formaldehyde
Glycol Ethers
Heptachlor
Hexachloro-1,3-Butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
Hexamethylene-1 ,6-Dusocyanate*
Hexamethylphosphoramide
Hexane*
Hydrazme
Hydrochloric Acid
Hydrogen Fluoride
000079118
000108907
000510156
000067663
000075003
000074873
000107302
000126998
001319773
000098828
003547044
000334883
000117817
000132649
000084742
000075092
000062737
000111422
000064675
000060117
000079447
000068122
000131113
000077781
000106898
000140685
000100414
000107211
000075218
000096457
000151564
000050000
000076448
000087683
000118741
000077474
000067721
000822060
000680319
000110543
000302012
007647010
007664393
Chemical
Hydroqumone
Isophorone*
Lead Compounds
lindane
m-Cresol
m-Xylenes
Maleic Anhydride
Manganese Compounds
Mercury Compounds
Methanol
Methoxychlor
Methyl Ethyl Ketone
Methyl Hydrazme
Methyl Iodide
Methyl Isobutyl Ketone
Methyl Isocyanate
Methyl Methacrylate
Methyl Tert-Butyl Ether
Methylenebis (Phenylisocyanate)"
n-Nitroso-N-Methylurea
n-Nitrosodimethylamine
n-Nitrosomorphohne
N.N-Dimethylamline
Naphthalene
Nickel Compounds
Nitrobenzene
o-Anisidine
o-Cresol
o-Toluidine
o-Xylene
p-Cresol
p-Phenylenedamme
p-Xylene
Parathion
Pentachlorophenol
Phenol
Phosgene
Phosphme*
Phosphorus (Yellow Or White)
Phthalc Anhydride
Polychlonnated Biphenyls
Polycylic Organic Matter*
Proptonaldehyde
Propoxur
Propylene Oxide
Propyleneimine
Quinolme
Quinone
Quintobenzene
87-90
Cas/
000123319
000078591
000058899
000108394
000108383
000108316
000067561
000072435
000078933
000060344
000074884
000108101
000624839
000080626
001634044
000101688
000684935
000062759
000059892
000121697
000091203
000098953
000090040
000095487
000095534
000095476
000106445
000106503
000106423
000056382
000087865
000108952
000075445
007603512
007723140
000085449
001336363
000123366
000114261
000075569
000075558
000091225
000106514
000082688
4-5
-------
Table 4-5
Chemical
Radionuclides"
Selenium Compounds
Styrene
Styrene Oxide
Tetrachloroethylene
Titanium Tetrachloride
Toluene
Toluene-2.4-Dnsocyanate
Cast
000100425
000096093
000127184
007550450
000108883
000584849
Hazardous Air Pollutants
(CONTINUED)
Chemical
Toxaphene
Tnchloroetnylene
Triethylamme*
Trilluralm
Urethane
Vinyl Acetate
Vinyl Bromide
Vinyl Chloride
Cast
008001352
000079016
000121448
001582098
000051796
000108054
000593602
000075014
Chemical
Vinyhdene Chloride
Xylene (Mixed Isomers)
Cas*
000075354
001330207
• Not Reported in TRI Database
" Also known as Methylene Diphenyl
Onsocyanate
Table 4-6
EPA 33/50 Program Chemicals
Chemical
1,1,1-Tnchloroethane
Benzene
Cadmium
Cadmium Compounds
Carbon Tetrachloride
Chloroform
Chromium
Chromium Compounds
Cyanide*
Cast
000071556
000071432
007440439
000056235
000067663
007440473
Chemical
Cyanide Compounds
Dichloromethane
Lead
Lead Compounds
Mercury
Mercury Compounds
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Nickel
Cast
000075092
007439921
007439976
000078933
000108101
007440020
Chemical Gas/
Nickel Compounds
Tetrachloroethylene 000127184
Toluene 000108883
Trtehloroethylene 000079016
Xylene (Mixed Isomers) 001330207
• Not Reported in TRI Database
Table 4-7
High Risk/Early Reduction Chemicals
Chemical Cas*
1.1.2.2-Tetrachloroethane 000079345
1,2-Dibromoetnane 000106934
1,3-Butadiene 000106990
2,3.7.8-Tetrachlorodibenzo-p-Dioxm* 001746016
Acrolem 000107028
Acrylamide 000079061
Acrylic Acid 000079107
Acrylomtnle 000107131
Arsenic 007440382
Arsenic Compounds
Asbestos (Friable) 001332214
Benzene 000071432
Benzidme 000092875
Benzoic Trichloride 000098077
Beryllium 007440417
Beryllium Compounds '
Chemical
Bis(2-Chloroethyl) Ether
Bis(Chloromethyl) Ether
Cadmium
Cadmium Compounds
Chlordane
Chloromethyl Methyl Ether
Chromium
Chromium Compounds
Chloroprene
Coke Oven Emissions*
Dibenzofuran
Ethylene Oxide
Heptachlor
Hexachloroberaene
Hydrazine
Mercury
Casf
000111444
000542881
007440439
OOOOS7749
000107302
007440473
000126998
000132649
000075218
000076448
000118741
000302012
007439976
Chemical Gas/
Mercury Compounds
Methyl Isocyarate 000624839
Methylenebis(Phenyhsocyanate)" 000101688
Phosgene 000075445
Propyleneimme 000075558
Toluene-2,4-Onsocyanate 000584849
Vinyl Chloride 000075014
Vinyhdene Chloride 000075354
• Not Reported in TRI Database
" Also known as Methylene Diphenyl
Diisocyanate
4-6
-------
Table 4-8
Carcinogenic Chemicals In TRI Database
Chemical Cas/
1,1,2,2-Tetrachloroethane 000079345
1,1,2-Tnchloroethane 000079005
1.1-DimethylHydiazme 000057147
1.2-Dibromoethane 000106934
1,2-Ddiloroethane 000107062
1,3-Butadiene 000106990
2.4,6-Tnchlorophenol 000088062
2.4-Oiammotoluene 000095807
2.4-Dmitrotoluene 000121142
2,6-Dinrtrotoluene 000636202
2-Nitropropane 000079469
3,3-Dichlorobenzidine 000091941
4,4'-Methylenebis(2-Chloroaniline) 000101144
Acrylomtnle 000107131
Alpha-Naphthylamme 000134327
Arsenic 007440382
Asbestos (Friable) 001332214
Benzene 000071432
Benzyl Chloride 000100447
Beiylhum 007440417
Chemical
Bis(2-Chloroethylj Ether
Bis(Chloromethyl) Ether
Cadmium
Carbon Tetrachlonde
Chlordane
Chlorobenzilate
Chloroform
Chloromethane
Chloromethyl Methyl Ether
Chromium
Dichloromethane
Dimethyl Sullate
Epichlorohydrin
Ethylene Oxide
EthyleneThiourea
Ethyleneimme
Formaldehyde
Heptachlor
Hexachloro-1,3-Butadiene
Hexachlorobenzene
Cas/
000111444
000542881
007440439
000056235
000057749
000510156
000067663
000074873
000107302
007440473
000075092
000077781
000106898
000075218
000096457
000151564
000050000
000076448
000087683
000118741
Chemical Cas*
Hexachloroethane 000067721
Hydrazine 000302012
Lindane 000058899
Methyl Iodide 000074884
o-Toluidme 000095534
PolychlonnatedBiphenyls 001336363
Propane Sultone 001120714
Propyleneimine 000075558
Qumtozene 000082688
Saccharin (Manufacturing Only) 000081072
Safrole 000094597
Styrene 000100425
Tetrachloroethylene 000127164
Thiourea 000062566
Trichloroettiylene 000079016
Urethane 000051796
Vinyl Chloride 000075014
Vmylidene Chloride 000075354
Table 4-9
Ozone Depleting Chemicals In TRI Database
Chemical
Cas/
1.1,1-Trichloroethane
Carbon Tetrachlonde
Freon113
000071556
000056235
000076131
4-7
-------
4-8
-------
Appendix A
Data from Linked Data Set
-------
TABLE A-1
Regional Hot Spots
EPA REGIONS —ISP7 BASIS
EPA Region
04
05
06
03
07
02
08
10
09
01
1987
(iVfrl
621.664.527
530.990.262
462.251.285
234398214
121.612.041
120.764,704
104.844.500
95,094.041
93.296.592
85.027.725
Amount Emitted
1988 _ 1989
PVfl
589.758.062
484.808.375
379362.209
215.559 165
131.919.474
113.233.785
136.753,217
74.641.562
92.153,542
78,167.971
WJ
592.344.907
474.447.160
347.131.355
194.486.556
130.441,146
97,552.883
143.467.996
69.961.153
84,232.151
67.286.110
1990
ptfri
523.726.327
405.212.823
293.108.331
174.020.016
117.592.501
86.133.023
123.164.214
63.425.609
77.975.810
55.806.962
1987-1988
pvp)
-31 906.465
-46.181.907
-82.889.076
-18.839.049
10.307.433
-7.530.919
31.908.717
-20,452.479
-1,143.050
-6.859.754
lea)
-513
-870
-1793
-804
848
-624
3043
-2151
-123
-807
Amount Of Change
1988-1989
tivpl
2.586.845
-10.361.215
-32.230.854
-21.072.609
-1.478.328
•15.680.902
6.714.779
-4.680,409
-7,921.391
-10.881.861
(#1
044
-214
•850
-976
-1 12
-1385
491
-627
-860
-1392
1989-1990
)
-68.618.560
•69.234 337
•54.023024
-20466540
•12.848.645
•11.419660
-20.303.782
-6.535544
-6.256.341
•11,479.148
W
-1158
-1459
•1556
•1052
-985
-1171
-MIS
•934
-743
•1706
TABLE A-2
Regional Hot Spots
TOP20 STATES— 1987 BASIS
Slate
TX
LA
OH
TN
IN
Ml
AL
IL
NC
UT
GA
PA
VA
CA
NY
SC
MS.
KY
FL
AR
1987
IWI
238,275,406
144.359.410
133.572.741
126.736.161
108.148.431
106.051.124
100.431.221
96.633.375
93.559.598
85.741.098
85.090.791
84.518.628
83.986.937
75.257.676
70.027.865
61.061.327
56.258.233
•51.144.009
47.383.187
47.215.941
Amount Emitted
1988 1989
IWI
175,429.432
128.008.706
127.788.785
127.396.894
97 047.492
82 748.534
100.051.930
91.370.375
84.592.816
120,424,480
. 77,489.831
78.088.092
80.402.424
75.713.529
64.414.892
61.736.939
56.028.443
45.141.618
37.319.591
44.528.771
w;
167.991,897
116.401.665
117.995,184
140392.040
96.167777
81 639.845
in.36B.744
87.447.210
79.814.411
126.722.058
69,226759
69.539,063
71,550,633
71.153,056
57,604,582
64.785,378
55.603.780
40,395,235
41,758.560
38,069.603
1990
WW
147,628.675
94.039.252
97,115.443
128.562.788
67.978.942
67.479.479
94 162.974
76.428.660
71.319.077
108.620.776
63.807.295
61.662671
68.460.561
64.895.866
49.641.242
54.601.677
49.664.068
32.710.735
28.697.713
27.231.347
1987-1938
flaw
-62845.974
-16350.704
-5,783956
660733
-11.100939
-23302590
-379.291
•5.263.000
-8.966.782
34.683.382
-7.600960
-6.430.536
-3.584.513
455.853
-5.612973
675.612
-229.790
-6.002391
-10.063.596
-2.687 170
(10)
•2638
•1133
-433
052
-1026
-2197
•038
-545
-958
4045
•893
-761
-427
061
-802
111
-041
-1174
-2124
-569
Amount Of Change
1988-1989
-------
County
TABLE A-3
Regional Hot Spots
TOP 20 3-DIGIT ZIP CODES- 1987 BASIS
3-digil Zip code
840
775
37S
365
703
700
996
797
776
707
480
779
286
706
377
314
356
244
371
723
UT
TX
TN
AL
LA
LA
AK
TX
TX
LA
Ml
TX
NC
LA
TN
GA
AL
A
TN
AR
1987
Wn)
80260.510
74200,063
53.031.565
48.542.835
44.019.671
30.737,521
30.551.925
29033.878
25731.849
22.255,031
21,428,949
21.265,124
20.699.329
20.0t5.906
19,455.819
19.188.412
18,905.338
18,476.345
17,753.155
17,304.014
Amount Emitted
1988 1989
Wf)
115.533.035
62.055.500
53.885.615
49.644,636
56.378.839
14.436.097
20.958.860
3,825,542
24.876,096
21.217.431
15.440.706
8.073.149
18,415,056
15.985.729
19.587.362
19.318.987
15.611,697
19.602.514
17.921,402
16.182.296
(IH/fl)
121.797.804
65.001.349
56589.700
49.486.002
53.648.655
8.182.294
18.604.215
5,273.633
21,189.721
18,298,938
14,385,269
5315.839
17070,188
14.634.086
28.107,058
16.326.594
17.966,859
13.326.394
17,677,507
14,355,290
1990
(HW)
97 449.460
52.315,406
52673.030
50.923.247
23.047.199
20.364.832
13.835.648
5,107.048
20.058.027
16.505,353
6,944.729
4,831,852
15,452.553
11.418.692
26.412,907
13.124.755
15.440.806
11.582.074
16,491 564
5,509,033
1967-1988
flat')
35,272,525
-12144563
854,050
1.101.801
12.359.168
-16.301.424
-9.592.965
-25.208.336
-855.753
-1.037,600
•5986,243
-13,191,975
•2.284.273
-4030.177
131.543
130.575
•3,293,641
1.126.169
168,247
•1.121.718
tod)
4395
-1637
161
227
2808
-5303
-3140
-8682
-333
-466
-2794
-6204
-1104
•2013
068
068
-1742
610
095
-648
Amount Of Change
1988-1989
w;
6.264.769
2.945.849
2.704.085
•158634
-2,730.184
-6.253.603
-2.354.645
1,448.091
-3.686.375
-2,918.493
-1,055.437
-2,757.310
-1,344.868
-1,351.643
8,519.696
•2.992.393
2.355.162
•€.276.120
-243.895
-1.827.006
(10)
542
475
502
-032
•484
-4332
-1123
3785
-1482
-1376
-684
-3415
-730
-846
4350
-1549
1509
-3202
-136
-1129
1969-1990
It/in
-24.348 344
-12.685.943
-3.916.670
1,437.245
-30.601.456
12.182.538
-4.768.567
-166.585
-1.121.694
-1.793.585
-7440.540
-483.987
-1.617,635
-3.215394
-1,694.151
-3.201,839
-2.526.051
-1.744.320
•1.185,943
-8.846.257
IW
•1999
•1952
•692
290
-5704
14869
-2563
-316
-529
•980
•5172
•910
-948
-2197
-603
•1961
-1406
•1309
-671
-6162
TABLE A-4
Regional Hot Spots
Top 20 Counties -1987 Basis
Amount Emitted
Amount Of Chenge
1987
1990
1987-1988
1989-1990
TOOELE
ASCENSION
MOBILE
HARRIS
SULLIVAN
COOK
KENAI PENINSULA
LOS ANGELES
ECTOR
JEFFERSON
BRAZORIA
CHATHAM
CALCASIEU
CALHOUN
ALLEGHANY
MISSISSIPPI
ST JAMES
HAMBLEN
MC LEOD
LAKE
UT
LA
AL
TX
TN
IL
AK
CA
TX
TX
TX
GA
LA
TX
VA
AR
LA
TN
MN
IN
CW
76.989,600
53,169.833
49,936,678
49.047.229
42.058.444
30,816.250
30.551.825
30,499.813
27.421.333
22,003.740
21,823.595
19.188,412
18.788.259
18.123.053
17.845769
17.242.395
16,239.492
16.181.264
J 5.591 .355
15.025.811
flftW
109.867,272
51.213.273
50,479.785
45,473,832
42.634,881
29,376.092
20.958.860
32.129,171
2.211.643
18.392.433
17.972.406
19,318.987
15,225,083
5,389,523
19,009,264
16.125.232
15.408.007
16.294.219
16.567.333
11.021.400
(tup)
119207.748
62.454.882
50212.530
43.689.922
42,365.300
32,489.055
18.604.215
29,691.926
3.473,153
16.679,190
18.053,425
16,326.594
13,916.509
3,588.587
10,042.999
14,288.567
931,727
24.916.031
25,782.081
10.069.351
Wf)
95.171,481
30.789.313
50.619,233
31.618,810
37.656,528
29,626.135
13835.648
25.486.075
3.315.692
15.826.602
15.784.026
13,124.755
10,673.131
3,018,795
8,177.060
5.424.839
15,084,391
23.604.411
20,208.526
11.229.390
Utffll
32.877,672
-1.956.560
543,107
-3,573,397
576.437
•1.440158
•9592.965
1.629358
-25209.690
•3.611.307
•3.851,189
130,575
-3.563,176
•12.733,530
1,163,495
-1.117.163
-831.485
112.955
975,978
-4,004,411
(pel)
4270
•368
109
•729
137
•467
-3140
534
-9193
-1641
-1765
068
-1896
•7026
652
-648
-512
070
626
•2665
w;
9,340.476
11.241.609
-267.255
-1.783.910
•269.581
3,112,963
-2.354.645
•2,437.245
1.261.510
-1.713.243
61,019
-2.992.393
-1.308,574
-1,800.936
-8,966.265
•1.836.665
-14.476,280
8,621.812
9,214,748
-952.049
/PCI)
850
2195
-053
-392
-063
1060
-1123
-759
5704
-931
045
-1549
-859
•3342
-4717
-1139
-9395
5291
5562
-864
w;
-24.036.267
-31.665.569
406.703
-12.071.112
•4.708.772
-2.862.920
-4.768.567
-4,205.851
-157.461
-852.568
-2.269.399
-3.201.839
-3.243.378
-569.792
-1.865.939
-8,863.728
14.152.664
-1.311.620
-5.573.555
1.160.039
(&)
-2016
-5070
081
-2763
-11 11
•881
-2563
-1416
-453
-511
-1257
-1961
-2331
-1588
-1858
-6203
151897
-526
-2162
1152
A-2
-------
TABLE A-5
Top 20 Chemicals
— 1987BASIS-
Chemical
Ammonia
Toluene
Melhanol
Aceione
1,1.1-Tnchlofoelhane
' Methyl ElhyiKetone
Xylene (Mixed Isomers)
Oicnioromeihane
Ctilotine
Carton Disunite
Aluminum
(Fume Or Oust)
Hydrochloric Acid
Elhyiene
FreonllS
Trichloroelhyiene
Propylene
Glycql Ethers
Benzene
n-Bulyl Alcohol
Telrachloroelhylene
1987
r'W
277.388831
251.982.231
196.559,936
177.750,109
140.163,526
138.251,483
128.676.481
110.954.722
105.001,108
85.913,732
81.574,716
70.395,841
59.766.006
49.479,901
47.484.928
38.686.477
37,515,524
30.633.229
29.157,749
28.769.776
Amount Emitted
1988 1989
flM»J
237.606.361
243.792.436
203.806.647
175.215.296
145.564.167
118.087.703
131.418.148
102.158.498
132.890.733
88.522.526
2.831.694
65 104.444
42.394.117
57.244.514
45.722.543
23.807.387
42.985.363
28.548.426
32.376359
29.736.927
(win
226.977.094
229,026,603
184,231.445
175,168.870
138,238.987
117,346.230
129,162.509
93,270,030
132,027.251
98,431.764
1. 527.480
69,358.736
41,853.869
52,248.201
41277.631
23,898,179
42329.635
25.070.583
32,149.145
22.362.024
1990
fUM
181.697.260
199,512.073
165.049.027
157,837.161
124,183,587
105.467.819
115.499.330
79.038.482
104.239.889
96.954.830
1.315,171
67.294,145
34.588.353
35,911.342
32.616.922
21.014.890
39.409.230
23.226.988
28.284.184
17.574.604
1987-1988
V6W
•39782470
-8 189.795
7.246.711
-2.534.813
5.400.641
-20.163.780
2.541.667
-8.796.224
27.889.625
2.608794
-78743.022
-5291.397
-17.371.889
7.764.613
-1.762385
-14.879090
5.469.839
•2.084.803
3.218,610
967.151
fail
•1434
-325
369
-143
385
-1458
197
-793
2656
304
•9653
•752
•2907
1569
•371
•3846
1458
•681
1104
336
Amount 01 Change
1988-1989
WW
•10.629.267
•14,765.833
•19,575.202
-46,426
•7,325180
•741.473
•2,255.639
•8.888.468
-863.482
9.909.238
-1.304.214
4,254.292
•540.248
-4,996,313
-4.444.912
90.792
-655.728
•3,477.843
-227.214
•7.374.903
(pa)
-447
-606
-960
-003
-503
•063
-172
-870
-065
11 19
-4606
653
-127
-873
-972
038
-153
-1218
-070
-2480
1989-1990
PWI
-45.279.834
-29514.530
-19.182418
-17.331.709
•14.055.400
-11.87841)
-13,663.179
-14.231.548
-27.787.362
-1.476.934
-212309
-2.064 591
•7.265.516
-16.336,859
-8.660.709
-2.883.289
-2.920.405
-1.843.595
-3.864.961
-4.787.420
loai
-1995
•1289
-1041
-989
-1017
•1012
•1058
•1526
•2105
•ISO
-1390
•298
-1736
•3127
•2098
•1206
•690
-735
•1202
•2141
TABLE A-6
Top 20 Hazardous Air Pollutants
— 1987BASIS-
Chemical
Toluene
Melhanol
1,1.1-Tiichloroeihane
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
Oichloromelhane
Chlorine
Car Don Disullide
Hydrochloric Acid
Tnchioroelhylene
Glycol Ethers
Benzene
Telrachlorcelhyiene
Methyl isobulyl Kelone
Slyrene
Chloroform
Carbonyl Sullide
Elnyiene Glycol
Formaldehyde
Chloromelhane
1987
r«w
251.982.231
196.559.936
140.163526
138.251.483
128.876,481
110.954,722
105.00i;i08
85.913.732
70.395.841
47.484.928
37.515.524
30.633229
28.769.776
27.169.624
26,438.085
24.034.760
22.459.520
14.378.138
12.359.020
12.068.836
Amount Emitted
1988 1989
P»>f)
243.792.436
203.806.647
145,564,167
118.087.703
131.418.148
102.158.498
132.890.733
88.522.526
65.104.444
45.722.543
42.985.363
28.548.426
29.736.927
27.905.037
24.556.434
23.256.805
19.554,837
12.565.574
10.338,268
10.837.852
(Wfl)
229.026.603
184.231.445
138238.987
117.346.230
129.162.509
93.270.030
132.027,251
98.431.764
69.358.736
41.277,631
42.329.635
25.070.583
22.362.024
28.030,679
21.937.401
24.438.028
17.798.541
11.756.072
1t.398.634
9.318.569
1990
CW
199.512.073
165.049.027
124.183,587
105467.819
115499330
79.038.482
104239.889
96.954830
67.294.145
32.616,922
39.409.230
23.226.988
17.574.604
24.025.550
21.164.693
21.549.202
18.463.675
8.159.622
10.664.037
7,326.285
1987-1
fl»W
-8.189.795
7.246,711
5400641
-20.163780
2541.667
-8796224
27.889625
2.608,794
-5,291,397
-1 762,385
5.469.839
-2084803
967.151
715.413
-1.881.651
-777,955
-2,904,683
-1.812.564
-2.020,752
-1.230.984
Amount Of Chango
988 1988-1989
IfCII
•325
369
385
•1458
197
-793
2656
304
-752
-371
1458
-681
336
263
•712
-324
-1293
•1261
-1635
-1020
W)
•14,765.833
•19,575,202
•7,325.180
•741.473
-2,255.639
•8.888.468
-863.482
9,909.238
4,254.292
-4,444.912
•655.728
-3,477,843
-7,374.903
125.642
-2.619.033
1,181.223
•1,756.296
•809.502
1,060.366
-1.519.283
(W
-606
-960
-503
-063
-172
-870
-065
1119
653
-972
-153
-1218
-2480
045
-1067
508
-898
-644
1026
-1402
1989-1990
i»W
-29,514.530
-19.182.418
-14.055.400
-11.878.411
-13.663.179
-14.231.548
-27.787.362
-1.476,934
•2.064.591
•8,660.709
-2.920.405
-1.843,595
-4,787,420
-4.005.129
-772.508
-2.888.826
665.134
-3.596.450
-734.597
-1.992.284
Ipai
-1289
•1041
-1017
•1012
-1058
•1526
-2105
-150
-298
•2098
•690
-735
•2141
-1429
•352
-1182
374
•3059
•644
-2138
A-3
-------
TABLE A-7
EPA 33/50 Program Chemicals
—1987 BASIS —
Chemical
Toluene
1,1,1 -Tried loroelhane
Melhyl Ethyl Kelone
Xylene (Mixed Isomers)
Oictiloramelhane
Trichloroelhylene
Benzene
Telrachloroelhylene
Melhyl IsoDulyl Kelone
Chlorolorm
p-Xylene
Carbon Teliachlonde .
o-Xylene
m-Xylene
Cyanide Compounds
Lead
Lead Compounds
Chromium Compounds
Nickel ,
Chromium
Nickel Compounds
Cadmium Compounds
Mercury
Cadmium
Mercury Compounds
mr
(IIWI
251.962231
140.t63.S26
138.251,483
128,876.481
110.954.722
47.484928
30,633.229
28.769.776
27.139.624
24.034.760
7.437.936
4.334.230
3.680.212
2.99S.819
1. 402.741
1. 233.373
1.104.599
730.014
392.126
334,776
296,704
151.547
23.158
11.021
1,586
Amount Emitted
1988 1989
(74W
243.792.436
145.564.167
118.087.703
131.418.148
102.158.498
45.722.543
28.548,426
29.736.927
27905,037
23,256.805
6.003.302
3.640.586
2.064.641
2,194,146
878,066
961.328
1.379.549
684.338
244.249
367.520
221.064
86.443
23.145
15.472
1.616
ffc/W
229.026,603
138.238,987
117,346,230
129.162.509
93,270,030
41,277.631
25.070,583
22.362.024
28.030.679
24.438.028
4.933,722
3.290.440
1,808,306
1,200.771
814,061
756,502
1,326,054
1.250,261
253,515
265,936
202245
73,745
24,007
22.414
3254
1990
f»W
199.512,073
124.183,587
105,467,819
115.499.330
79.036,482
32.616.922
23,226.988
17.574.604
24.025,550
21.549,202
4.752,672
1.646,835
1.904,571
1.202.284
1.127.652
769,669
1.515,828
570.905
289,245
175,764
187,392
84.596
21,639
6,721
898
1987-1988
flaw
-8.189.795
5.400.641
-20,163.780
2541.667
-8,796224
-1.762385
-2.084,803
967.151
715.413
-777.955
-1.434.634
•693.644
-1.615,571
-801.673
-524,675
-272.045
274.950
•45.676
-147,877
32.744
-75,640
-65.104
-13
4.451
30
IfCII
-325
385
•1706
197
-793
-371
-681
336
263
-324
•1929
•1600
•4390
•2676
•5975
•2206
1993
•667
•3771
978
•3422
-7531
•006
4039
186
Amount 01 Change
1988-1989
flfcW
-14.765.833
•7.325.180
-741.473
-2255639
-8.888.468
-4.444.912
-3.477,843
-7.374.903
125.642
1.181.223
-1.069.580
-350.146
-256.335
-993.375
-64,005
-204.826
-53,495
565,923
9266
-101.584
-18,819
-12.698
862
6.942
1,638
(pa)
•606
-503
-063
-172
-670
-972
•1218
•2480
045
508
•1782
•962
•1242
•4527
786
•2131
-4.03
4526
379
•2764
-931
-1722
372
4487
5034
1969-1990
w;
-29,514.530
-14.055,400
-11,878,411
-13.663.179
-14.231 548
•8.660709
•1.643,595
•4,787,420
-4.005 129
' -2.888.826
-181.050
-1.643.605
96.265
1.513
313,591
13,167
189,774
-679,356
35,730
•90,172
•14,853
10,851
-2.368
•15,693
-2.356
(fa)
•1289
•1017
•1126
•10S8
,-1526
-2098
•735
-2H1
•1429
-1182
•367
-4995
532
013
2781
174
1252
-11899
1409
-3391
-792
1283
•986
•7001
-26236
TABLE A-8
Top 20 High Risk/Early Reduction Chemicals
—1987 BASIS-
Chemical
Benzene
1,3-Bulafliene
Acrylomlrile
Elhyiene Oxide
Vinyl Chloride
Acrylic Acid
Meihylenebis(Phenyiisocyanale)
Chromium Compounds
Toluene-2.4-Dnsocyanate
Vmylidene Chloride
CMoroprene
Arsenic Compounds
Cadmium Compounds
Melhyl Isocyanate
U.2.2-Tetrachloroelhane
Phosgene
1,2-Oibromoelhane
Acrolem
Asbestos (Friable)
OiDenzoluran
1987
raw
30,633.229
9,383347
5.380.510
4.183.635
1.568,004
821,770
792,813
730,014
611,310
465.989
282,135
270,853
151,547
143,237
103,740
83,534
65,119
48.654
42,266
36,158
Amount Emitted
1988 1989
fl*W
28.548.426
6,622,693
4.182.336
3,747.481
1,292.466
784,265
144,864
684,338
141.009
295.745
423,513
198,821
86,443
9,425
43,685
21,532
63277
33,596
35225
36.227
flW
25.070,583
5.664,918
4,106,690
2,646,726
1,132.240
348271
183,698
1.250,261
71,133
220,042
303,087
154,185
73,745
13,948
34,778
8,261
59,167
20,075
28,607
41,140
1990
f/aw
23.226,988
4.955,664
2.877.318
1,967,894
1.064,839
396,046
280,237 •
570,905
33,062
301,292
172,692
154.516
84,596
14,123
34,452
4,853
57,830
22.017
13,313
26.468
A-4
1987-1988
flUW
-2.084,803
-2,760,654
-1.198,174
-436.154
•275.538-
-37.505
-647.949
-45.676
•470.301
-170.244
141.378
-72.032
-65.104
-133,812
•60.055
-62,002
-1.842
-15.058
-7.041
69
(PCI)
-681
•2942
-2227
•1043
•1757
•456
-8173
-626
•7693
•36.53
5011
•2659
-4296
-9342
-5789
•7422
-283
-3095
-1666
019
Amount Of Change
1988-1989
fl&W
•3.477,843
-957.775
-75.646
•1.100.755
-160.226
-435.994
38.834
565.923
-69.876
•75.703
-120,426
-44.636
-12,698
4.523
-8.907
-13271
-4,110
-13.521
-6.618
4.913
tW
•1218
-1446
-181
•2937
•1240
•5559
2681
8270
-4955
•2560
-2844
•2245
-1469
4799
•2039
•6163
-650
•4025
-1879
13S6
1989-1990
I»W
-1,843,595
-709,254
-1,229,372
-678.832
•67,401
47,775
96,539
-679,356
-38,071
81,250
-130,394
331
10,851
175
•326
-3,408
-1,337
1,942
-15,294
-14.672
(pel
•735
-1252
-2994
-2565
-595
1372
5255
-5434
-5352
3692
•4302
021
1471
125
•094
•4125
-226
967
-5346
•3566
-------
TABLE A-9
Top 20 Carcinogenic Chemicals In TRI Database
—1987 BASIS —
Chemical
Dichloromelhane
Tncnlorcelriylene
Benzene
Telrachloroelhylene
Slyrene
Chloroform
Formaldehyde
Chlofomelhane
1,3-Buladiene
1,2-Dichioroeinane
Acrylonilrile
Caroon Telrachlonde
Elhylene Oxide
1 1.2-Tnchloroelliane
Vinyl Chloride
Urelhane
Vinyhdene Chloride
Epichlorahydnn
Chromium
2-Nilropropane
1387
(Wl
110.954.722
47.484.926
30.633.229
28.769.776
26.438.085
24.034.760
12.359.020
12.068.836
9.383.347
6,196.495
5.380.510
4.334.230
4.183.S35
1,975,207
1.568.004
796.000
465.989
420.988
334,776
275.202
Amount Emitted
1988 1989
(to>W
102.158.498
45,722.543
28.548.426
29.736.927
24.556.434
23256,805
10.338.268
10.837.852
6.622.693
4,280.244
4.182.336
3.640.586
3.747.481
1,710,392
1,292.466
144,373
295.745
464009
367.520
274.360
-870
-972
•1218
-2480
-1067
508
1026
-1402
-1446
•403
-181
•962
-2937
-5663
-1240
-9761
-2560
153
-2764
-1791
1989-1990
f*W
•14.231.548
•8.660,709
•1.843595
-4,787,420
-772.508
-2.868,826
-734.597
-1.992284
-709.254
951.838
-1.229.372
-1.643.605
•678.832
-162.900
-67.401
-140
81250
-87,577
-90.172
-208,964
(pal
-1526
-2098
-735
•2141
-352
-1182
-644
-2138
•1252
2317
•2994
•4995
-2565
•2195
-595
-406
3692
-1859
-3391
•9278
Chemical
1987
TABLE A-10
Ozone Depleting Chemicals In TRI Database
—1987BASIS-
Amount Emitted
1988 198
1990
1987-1988
Amount 01 Change
1988-1989
1989-1990
1,1,1-Tnchioroelnane
Fieonii3
Caruon Teiracnionae
140,163526 145,564,167
49.479.901 57.244.514
4.334.230 3.640.586
(Win) PUP)
138,236.987 124.133.587
52.248.201 35.911.342
3.290.440 1.646,835
tit*) (pal
5.400,641 385
7.764.613 1569
•693,644 -1600
tup) (pal
-7,325.180 -503
-4996.313 -873
-350.146 -962
-14.055.400 -1017
-16.336.859 -3127
-1.643.605 -4995
A-5
-------
A-6
-------
Appendix B
Data from Basic Data Set -
-------
TABLE B-1
Regional Hot Spots
—1990EPA REGIONS-
Par<
1
2
3
4
5
. a Region %
EPA E.T. ssions Of tail
Region (lo/yi) IRIEnuioni Ran<
4 604.076286 2752 1
2
3
4
5
6
7
8
9
10
5 484.261.829 2206 1
2
3
4
5
6
7
8
9
10
6 329.950.107 1503 1
2
3
4
5
E
7
a
9
10
3 194.601.413 887 1
2
3
4
5
6
7
a
9
10
8 130841.870 S96 1
2
3
4
5
E
7
8
9
10
C"6rciQi
Melhanol
Cartoon Oisulliite
Acetone
Toluene
Ammonia
Methyl Ethyl Kelone
1.1.1-Trichloroelhane
Xylene (Mixed isoreis)
Dichloromelhane
Hydrochloric Acidmelhanol
Toluene
Xylene (Mixed Isomers)
l.M-Trahtonelhane
Melhyl Elhyl Ketone
Aostone
Dichloromelhane
Ammonia
Melhanol
Giycoi Einers
HydrochloncAcid
Ammonia
Elhytene
Melhanol
Toluene
Acetone
Propytene
Xylene (Mixed Isomers)
Melhyl Ethyl Kelone
1.1.1-Trichioroeihane
Caroon Oisullide
Toluene
Acetone
Melhanol
Methyl Elhyl Ketone
Xylene (Mixed Isomers)
Hydrochloric Acid
1.1.1-Trichloroelhane
Ammonia
Dichloromelhane
Benzene
Chionne
Hydrochloric Acid
Xylene (Mixed Isomers)
U.i-Tnctiloroelrane
Toluene
SuiluricAcjd
FreonH3
Oichloramelhane
Ammonia
Melhanol
iciai
Emissions
I'Wrt
81.580.189
76.259.382
70,081.476
63,727.693
46.309,830
30744.593
28.881,839
28.062.870
24,167,720
21,858,069
72.200.418
50.089.051
45965.323
41.840.483
38.287.719
26.743.035
24.989.385
21206.220
16646513
13139.337
75.015.260
28.750.622
22.414.496
18.887.953
16.722.418
15.326.522
14.331.573
10.760.792
iai26.636
9,939,002
26.330.516
22,990.567
21,809.028
13,511,435
12614.012
11,950,539
11.429,765
7.901.050
7,351.150
5,025.976
88.312080
a589.489
8,497.725
4.845481
2425.143
2378.965
2009923
1.660427
1.463.968
1.194,714
EPA
Ra-< fetor
6 7
7 2
8 9
9 10
10 1
loin Reg'cn %
£-assons 01 loai
(lo/yi) In Emissions Ra«
127.925,832 583 1
2
3
4
5
6
7
a
9
10
97.668.390 4 45 1
2
3
4
5
6
7
8
9
to
93.125.814 424 1
2
3
4
5
6
7
a
9
10
67.120.142 306 1
2
3
4
5
6
7
8
9
10
65.348.914 298 1
2
3
4
5
6
7
8
9
10
C.iemicai
Ammonia
Toluene
Xylene (Mined Isomers)
1.1.1-Tnchloroelliane
Melhyl Elhyl Kelone
Meinand
Acetone
Dcniorcmeinane
Tnchloroeltiylene
Glycol Elders
Toluene
Acetone
Dichloromelhane
1,1.1-Tncnioroethane
Melhanol
Hydrochloric Add
Xylene (Mixed Isomers)
Freonns
Methyl Ethyl Kelone
Tnchloroeltiylene
i.l.t-Tnchloroeiriane
Amrnono
Melhanol
Freonli3
Acetone
Dchloromelhane
Telrachloroethylene
Toluene
Methyl Elhyl Ketone
Glycol Einers
Ammonia
Melhanol
Acetone
Toluene
CMorolorm
Methyl Elhyl Kelone
1,1.1-Tnchloroelriane
Xylene (Mixed Isomers)
Freonn3
Hydrogen Fluoride
t.l.l-Tnchkvoelhane
Toluene
Freonl13
Dchloromethane
Melhanol
Methyl Elhyl Kelone
Acetone
SulluncAad
Trlcnlorccuiyiene
Glycol Ethers
toa>
ET.ISWS
(iivyl
19,708,178
19,649.573
14,965837
9,314.547
8.732685
7,203176
5.958.516
5,129.199
3.802.974
3363.988
13.199.701
10.984.138
8,950567
8,059.131
7847.596
7.357,243
5,080.218
4538.407
3.988.539
3,556.207
25.515.424
9,888,315
7,685962
6268.234
6,217.525
6,121.068
3,901,750
3.649.506
3,270.373
2.693,136
20.219,832
D,oo9,o9b
4,963,761
4,905.926
3,739.619
3,651.806
2.194.173
2.173.580
2.114.945
1,818.012
14,968.303
8.206.903
4,723.831
4.196.633
4.105.041
3.942.373
3210.549
2.826.814
2,291.673
2.227.714
B-1
-------
TABLE 8-2
State Emissions
-1990-
State Rank
AK 1
2
3
4
5
6
7
8
9
10
AL 1
2
3
4
5
6
7
8
9
10
AR 1
2
3
4
S
S
7
8
9
10
Chemeal
Ammonia
Hydrochloric Acid
Methanol
Chloroform
SulfuncAcid
Benzene
Xylene (Mixed Isomers)
Toluene
Acetone
Cyclohexane
Carbon Oisulflde
Methanol
Methyl Ethyl Ketone
Toluene
Xylene (Mixed Isomers)
Hydrochloric Acid
Chloroform
1,1.1-Trlchloroethane
Ammonia
Acetone
Ammonia
Toluene
Methanol
Acetone
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
1,1.1-Tnchloroethane
Carbon Oisulflde
Dichloromethane
Freonl13
Tolll
Eminent No 01
(Ih/yr) Emitter!
13.483.804
548,500
329.005
206.991
182,010
81.923
37.818
33,012
22.510
21.650
46,577.271
8.052,654
6,364.473
5.401.636
4,778,967
4,503.002
2.751.919
2.695.436
2,330,419
1,578,781
3.911,743
3,327,557
3.250.676
2.918.514
2.854,124
2.798.597
2.656.401
1.689,195
1.480.148
1.055.540
5
2
3
2
2
3
3
3
1
3
4
46
41
70
77
54
11
49
72
44
61
85
35
SO
75
46
47
3
24
18
SOI
Sine
Total
9005
366
220
138
122
055
025
022
015
014
4658
805
636
540
478
450
275
270
233
158
1254
1067
1042
935
915
897
851
541
474
338
AS
AZ
CA
CO
Ammonia
19.300
100
1
2
3
4
5
6
7
3
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Acetone
1,1.1-Tnchloroethane
Methanol
Freontl3
Copper Compounds
Methyl Ethyl Ketone
Toluene
Ammonia
Aluminum Oxide (Fibrous Form)
Glycol Ethers
2.729.278
2.562.221
1.300.000
1,250.434
771.972
712.140
482.275
479,810
391.777
274.423
1,1.1-Tnchloroethane 22.924.095
Ammonia
Methanol
Oichlorornethane
FreonH3
Tetrachioroethylene
Acetone
Toluene
Methyl Ethyl Ketone
Glycol Ethers
1.1,1-Trichloroe thane
Freonl13
Methanol
n-Butyl Alcohol
Glycol Ethers
Toluene
Acetone
Methyl Ethyl Ketone
Tetrachioroethylene
Dichloromethane
9,352.400
6,348.393
5,828.439
5,012.280
3.718,016
3,393,865
2,694,066
2.529,013
2.337.188
1.017.010
963.019
677.907
655.718
625.526
561.363
449.777
280.197
271.598
200.052
24
56
18
34
13
19
17
22
1
13
527
252
114
102
171
81
213
185
171
134
28
27
14
6
10
21
17
12
S
11
2102
1974
1001
963
595
549
371
370
302
211
2912
1188
806
740
637
472
431
342
321
297
1513
1433
1009
976
931
835
669
417
404
298
Slate
CT
OE
FL
GA
HI
IA
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
1.1,1-Tnchloroethane
Dichloiomethane
Freon113
Toluene
Methanol
Tetrachioroethylene
Methyl Ethyl Ketone
Acetone
Ammonia
Glycol Ethers
Methanol
Hydrochloric Acid
Xylene (Mixed Isomers)
Carbonyl Sulflde
Tnchloroethylene
Methyl Ethyl Ketone
Acetone
Toluene
Oichloromethane
Vinyl Chloride
Ammonia
Acetone
Methanol
Toluene
Styrene
Sulfunc Acid
Freon113
1,1.1-Tnchloroethane
Hydrochloric Acid
Cyclohexane
Methanol
Acetone
Hydrochloric Acid
Toluene
Ammonia
1,1.1-Tnchloroethane
Xylene (Mixed Isomsrs)
Dichloromethane.
Methyl Ethyl Ketone
Chloroform
Propylene
Toluene
Glycol Ethers
Benzene
n-Butyl Alcohol
m-Xyiene
Cyclohexane
Oichlorornethane
o-Xylene
1,2,4-Tnmethyl benzene
Ammonia
Toluene
Xylene (Mixed Isomers)
Methanol
1,1,1-Tnchloroethane
Methyl Ethyl Ketone
Acetone
Tetrachioroethylene
Ethylene
Glycol Ethers
Total
EmiKione No 01
(iwyr) Emmet*
7.204,314
2.180.645
1.445,598
889.009
788.025
747,334
681,548
407,160
368,253
317,571
1,298.889
737,688
591,360
582,000
412,000
2B8.653
231,111
230,627
176.813
158,091
12.935.122
5.425,898
4.942,216
2.688,839
2.106,702
2,013.270
1,929,518
1.922,728
1.661,853
1.263,252
20.729,459
6.531,231
5,240.176
5.216,463
4.693,299
3.817.247
3,699,771
3.399,193
2,469,898
2,052.000
119,100
95,500
82.320'
72.400
72,400
50,300
35.800
28,924
24,000
18,450
8,367,744
6.896,867
3.677,125
2.698,900
2.552,320
2.536,460
2.042,387 •
1,223,571
992.000
875,884
151
47
40
36
33
22
43
27
55
24
14
15
6
1
1
9
12
14
7
2
79
106
35
S3
80
68
52
76
49
3
83
75
60
100
110
82
108
49
63
S
2
2
1
2
1
2
2
1
2
2
63
70
89
22
58
27
35
9
2
20
%ot
Slate
Total
41 97
1271
842
518
459
435
397
237
215
185
2158
1226
983
967
685
480
384
383
294
263
2865
1202
1095
596
467
446
427
426
368
280
2864
902
724
721
648
527
511
470
341
284
1750
1403
1210
1064
1064
739
526
425
353
271
2197
1811
965
709
670
666
536
321
260
230
B-2
-------
Table B-2 (Continued)
State Emissions —1990
Slate
ID
IL
IN
KS
KY
LA
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S •
6
7
8
9
10
Clcmcal
Ammonia
Chloroform
Mettianol
Freon113
Acetone
SulfuncAcid
Chlorine Oioxidi
1,1.1-Tncnloroethane
Hydrogen Fluonde
Formaldehyde
Toluene
1,1,1-Tnchloroettiane
Xylene (Mixed isomers)
Ammonia
Methyl Ethyl Ketone
Chlorine
Carbon Oisulfide
Tnchloroethylene
Hydrochloric Acid
Acetone
Toluene
Acetone
Oichloromethane
1.1,1-Tnchloroethane
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Vemanol
Tnchloroethylene
Ammonia
Benzene
Ammonia
Toluene
Tnchloroethylene
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Propylene
Carbon Disulflde
1,1.1-Tncnloroethane
Acetone
Ethylene
Toluene
Xylene (Mixed isomers)
Methanol
Acetone
1,1.1-Tncnloroethane
Ethylene
Glycol Ethers
Oicnlorometnane
Methyl Ethyl Ketone
Hydrochloric Acid
Ammonia
Methanol
Carbon Oisulflde
Ethylene
Toluene
Propylene
Xylene (Mixed Isomers)
Styrene
Hydrochloric Acid
Carbonyl Sulflde
Total
Emmano
(Ih/yr)
2.705.209
904.000
785,656
268.622
231.096
153.293
114.250
106.398
87.756
87.463
12.697.019
9.049.746
6.573.182
6.151.226
5.468.171
4,116.039
4,110,750
3,557.260
3.401.225
3.383.423
16.082.285
14.629.409
11.995.822
11,214,621
9.636,929
5.664.080
3.890.193
3.678.230
2.984.621
2.745.138
5.322.560
2.863.093
2,385.290
2.043.250
1.982.115
1.824.27S
1.638.076
1.434,684
1.364.253
1.070,444
8.476.610
4.597.087
4.394.941
2.604,518
2.215.042
2.024.170
1,660.761
1.515.355
1.404.847
1.280.147
48.927.723
7,018.912
6.392.429
6.103.489
4.055.942
3.086.981
2.192.927
2.161.963
1.989,805
1.831.628
No 01
Emitter*
20
1
6
4
9
15
1
4
4
5
233
230
224
141
167
52
3
104
162
108
208
130
69
159
21'0
118
94
51
67
16
44
59
11
49
29
6
2
33
34
S
75
73
37
41
46
7
25
18
46
42
67
73
9
37
74
29
61
24
.59
7
%OI
Stan
Total
4759
1590
1382
473
407
270
201
187
1
154
1446
1030
748
700
623
469
468
405
387
385
1494
1359
11 15
1042
895
526
361
342
277
255
1847
993
828
709
688
633
568
498
473
371
2091
1134
1084
642
546
499'
410
374
347
316
4622
663
604
577
383
292
207
204
188
173
Slate
MA
MO
ME
Ml
MN
MO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
•3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Toluene
1.1.1-Tnchloroe thane
F,reon1l3
Methyl Ethyl Ketone
Tnchloroethylene
Oicnioromethane
Acetone
Methanol
Xylene (Mixed Isomers)
Glycol Ethers
Toluene
Hydrochloric Acid
1.1.1-Tnchioroethane
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
Ammonia
Qichloromethane
Methanol
Glycol Ethers
Sulfunc Acid
Sulfurrc Acid
Methanol
Glycol Ethers
Chlorine '
1.1,1-Tnchloroethane
Chloroform
Acetone
Chlorine Dioxide
Hydrochloric Acid
Toluene
Toluene
Xylene (Mixed Isomers)
Acetone
Methyl Ethyl Ketone
Dichioromethane
1.1.1-Tnchloroethane
Methanol
Glycol Ethers
Ammonia
Methyl isobutyl Ketone
Methyl Ethyl Ketone
Toluene
Xylene (Mixed Isomers)
1,1.1-Tnchloroethane
Freon1l3
Methanol
Acetone
Dichiorornethane
Formaldehyde
Tnchloroethylene
Xylene (Mixed Isomers)
Toluene
1.1,1-Tnchloroethane
Methanol
Methyl Ethyl Ketone
Dicniorometnane
n-Butyl Alcohol
Acetone
Glycol Ethers
Ammonia
Total
Emaiom
(m/yi)
4,041.280
3,853,563
1.998,703
1,949,369
1,567,610
1,339,295
1.069,764
819.363
446.348
365.940
2,649,726
1,761,624
1,336.243
811.641
'713,267
628.035
627.017
601.710
552.297
516.096
2.463.498
1,993.113
1,405.302
1,326.828
1,323.702
1,082.487
795.621
566.204
511.628
468.360
14,217.008
11,806.955
9,474,537
5,957,423
5,349.093
5,059.027
4,578.987
3,484,346
2.992,218
2,975.936
12,786.476
12,758.642
4,754.197
3,098.528
1,880.315
1,701.799
1,556.487
1.447.317
1,147.802
793.907
7,689.499
4,855.804
4.209.923
3,191,803
3,002.844
2,615,397
2,259.036
2,175.820
2,110.808
1,996.580
No Of
Efliitttn
103
141
70
58
43
47
55
63
52
33
36
25
33
23
27
37
10
17
25
33
19
13
5
14
24
7
23
7
15
17
196
167
139
133
50
143
97
108
87
71
47
88
76
86
52
30
63
34
18
26
110
127
83
61
80
SO
46
71
59
61
\01
State
Total
1974
1882
976
952
766
654
523
400
218
179
2053
1365
1035
629
553
487
486
466
428
400
1799
1455
1026
969
966
790
582
413
374
342
1683
1398
1122
70S
633
5.99
542
412
354
352
2576
2570
958
624
379
343
314
292
231
160
1737
1097
951
721
678
591
510
492
477
451
B-3
-------
Table B-2 (Continued)
State Emissions —1990
Sla»
MS
MT
NC
MO
NE
HH
'Rank
1
2
3
4
S
6
7
t
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chimcal
Ammonia
ToTuene
Caroonyl Sulfide
QieMoromethane
Metnyl Etnyl Keione
Xylene (Mixed isomers)
Metnanoi
1,1 1-Tnchloroethane
Acetone
Hydrochloric Acid
Hydiogen Fluonde
Ammonia
Xylene (Mixed Isomers)
Formaldehyde
Toluene
MetJiancl
Prooylene
Lean Compounds
Chlordorm
Etnyiane
Methanol
Toluene
Metnyl Ethyl Ketone
Dichloromelhane
Acetone
1.1.1-Tnctiloroethane
Ammonia
Hydrochloric Acid
n-Butyl Alconoi
Chloroform
Toluene
Xylene [Mixed Isomers)
Metnyl Ethyl Ketone
1,2,4-rnmethyltXinzene
Benzene
Ammonia
1,1.1-Tnchtoroe thane
Freont13
Sryrene
Piopylene
Toluene
Ammonia
Xylene (Mixed isomers)
Dchioromethant
Metnyl Ethyl Ketone
1.1,1-TflchlorM thane
Freon113
Acetone
Ammonium Nitrate (Solution)
Me man oi
Toluene
1.1,1-Trtchloroethane
FreoniT3
Methyl Etnyl Ketone
Cnionne
Chlonne Dioxide
Dicnioromethane
Xylene (Mixed isomers)
Acetone
Metnyl (sobulyl Ketone
Tom
Emitter* No Ot
(Ibtyr) EmiRert
H0i6.no
6.173.170
5.821 000
4,797,880
4,660,687
4.432.183
2.425,499
2201.067
1.493.641
1.451,540
536.200
297,120
233,100
197,192
152.876
141,550
119.490
110,975
80.500
75.200
14,380,492
14.168,480
7,994,627
7.208,757
6.600.879
5,379.024
3,538,595
3,360.712
2,322.493
1234,250
480.445
367,999
319.794
127.451
116.540
116.498
87.825
63.675
56.261
54.704
5.033.309
4.021.294
1,555963
1.233.162
1,211.266
1,117.620
412.651
176,066
325,200
299.135
1.123,514
1.051.257
898.550
847.260
690.750
640,250
503.897
350.209
338.297
289.651
57
65
2
22
29
63
35
44
31
22
5
7
4
6
5
2
4
4
1
3
195
201
136
49
1S1
168
132
63
87
S
2
6
4
1
1
5
4
1
4
1
27
39
40
4
18
30
7
18
1
8
19
37
24
19
2
1
13
11
15
3
%a
Slate
Total
2528
11 13
1050
865
841
799
437
397
269
262
2165
12
941
796
617
572
483
448
325
304
1661
1636
923
832
762
621
409
388
268
258
2395
T834
1594
635
581
581
438
317
280
273
3004
2399
928
736
723
667
246
224
194
1 78
1415
1337
1132
1067
870
807
635
441
426
365
Slalt
NJ
MM
NV
NY
OH
OK
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
a
9
10
i
2
3
4
5
6
7
8
9
10
1
2
3
t
5
6
J
8
9
10
Chemical
Toluene
Acetone
Methinoi
Xylene (Mixed Isomers)
Metnyl Ethyl Ketone
1.1,1-Trichioroetnane
n-Butyl Alcohol
Glycol Ethers
Tnchloroettiylene
Dicnioromethane
Suttunc Acid
Cop per Compounds
Freon113
1,1,1-Tncfiioroe inane
Toluene
Acetone
Hydrochloric Acid
Xylene (Mixed isomers)
Formaldehyde
Benzene
Toluene
Acetone
Xylene (Mixed Isomeis)
Methanol
Metnyl Ethyl Ketone
1.1,1-Tncnioroetnane
Ammonia
Chlonne
Manganese Compounds
Stymie
Toluene
Hydrochloric Ac: d
1.1.1-TncMoroelhane
Acetone
Methane!
Oichlorome thane
Xylene (Mixed Isomers)
Tnchloroethylene
Freon113
Methyl Ethyl Ketone
Xylene (Mixed Isomers}
Toluene
1.1.1-Tnchloroe thane
Ammonia
Methyl Ethyl Keione
Acetone
Methanol
GlycDl Ethers
Oichloromettiane
n-Butyl Alcodo!
Ammonia
Methanol
Toluene
Dicnioromethane
Xylene (Mixed isomers)
Methyl Ethyl Ketone
1,1,1-Tnchloroemane
Tetrachloroethylene
Caroon Oisuifiaa
SfyTgne
Total
Emcuorn No 01
(lo/yr) Emitter*
4.161.854
3,306.492
2.311. 76S
2,075.891
1,727.391
1,366.264
1,118.522
991,581
878,938
840.840
681,387
343,510
238,181
234,361
212.717
151.733
137.957
120.012
87.172
59.119
377.665
34,710
75.949
37.314
29.220
29.108
21.145
19,983
12.900
10.243
7,560.295
7,056.179
6.237,309
4.809,828
4.639,404
4.154,054
2.690.313
2.666,709
2,390.274
1,968,162
12.851.774
11.945.107
11.859.212
H. 183.947
8,676,114
7.234.299
6,864,148
4.S17.963
3,223.389
3,010.729
10489.047
3,465.979
2,192.812
1,529.447
1,136.673
1,105,030
946,137
787.682
588.965
S79.9S5
169
94
108
134
104
105
64
77
14
51
11
3
8
9
10
8
7
5
1
4
4
3
S
1
2
3
3
6
1
1
160
114
159
38
97
61
116
60
73
87
229
288
270
156
195
153
131
132
99
87
24
18
39
11
34
27
36
8
1
to
\01
State
Total
1712
1360
951
854
711
5S2
460
408
362
346
2754
1393
966
951
863
616
560
437
354
240
5229
1173
1052
517
405
403
293
277
179
142
1329
1240
1096
846
816
730
473
469
420
346
1131
1052
1044
985
764
637
604
398
284
265
3740
1236
782
545
405
394
337
281
210
207
8-4
-------
Table 8-2 (Continued)
State Emissions —1990
Slate
OR
PA
PR
Rl
SC
SO
Rank
1
2
3
4
5
6
7
a
g
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
a
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemcal
Methanol
Acetone
Toluene
Methyl Ethyl Ketone
Ammonia
Formaldehyde
Tnchioroetnyiene
Xylene (Mixed Isomers)
FreonH3
1,1,1-Tnchloroethane
Toluene
1.1,1-Tnchloroethane
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
Ammonia
Hydrochloric Acid
Olchloromethane
Acetone
Methanol
Benzene
Olchloromethane
Acetone
F reotil 13
Toluene
Methanol
Carbon Disulfide
n-Butyl Alcohol
1.1,1-Tncnioroetnane
Methyl Ethyl Keione
Ediylene Oxide
Toluene
1,1.1-Tifchloroethane
Acetone
Freonl13
Methanol
Methyl Ethyl Ketone
Tnchloroethylene
Xylene (Mixed Isomers)
Ammonia
Dichlorofliethane
Methanol
Acetone
Toluene
Methyl Ethyl Keione
1,1.1-TricMoroeOune
Ammonia
Hydrochloric Acid
Xylene (Mixed Isomers)
Dichioromethane
Glycol Ethers
Xylene (Mixed Isomers)
Toluene
Cyclohexane
Freon113
1.1,1-Tnchloroethane
Lead Compounds
Methyl Ethyl Ketone
Methanol
Ammonia
Formaldehyde
Total
EmiBoni
fjwyo
3,530.666
2.440.476
2.152,560
1.137.231
1.0S7.S78
783.703
749.757
729,177
698.572
686.68S
12.042,062
7,648.281
4.SS8.396
4.419.802
4.160.426
4.097.918
3.669.467
3.178.S69
2.834.233
2,622,503
3,955.673
2.867.828
1.432.023
1.233.652
895.733
841,100
776,141
446.808
292.986
270.918
1.510.520
1.198.226
524.882
305.053
290.426
245.419
213.794
159.237
159.048
143.794
14.777,023
8,975,199
8.243.082
4.507.065
4.460.809
2.778.976
2.723.426
2.442.364
1.685.964
1.289,166
700.446
466.547
440.872
224.495
212.634
183,506
155.611
141.907
107.501
89.000
No 01
Emitters
31
46
39
31
43
33
14
31
13
25
202
190
121
198
129
116
58
127
122
19
21
25
31
23
26
1
8
23
9
6
15
48
17
17
It
15
15
13
26
12
76
55
69
48
67
69
47
67
27
38
, 11
7
1
3
7
1
6
3
7
1
%OI
State
Total
1928
1333
1175
621
577
428
409
398
381
375
1661
1055
629
610
574
565
506
438
391
362
2591
1879
938
808
587
551
508
293
192
177
2906
2305
1010
587
559
472
411
306
306
277
2282
1386
1273
696
689
429
421
377
260
199
2428
1617
1528
778
737
636
539
492
373
309
Slate
TN
TX
UT
VA
VI
vr
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Acetone
Carbon Disulfide
Toluene
Methanol
Carbonyl Sultlde
1,1,1-Tnchloroethane
Ammonia
Xylene (Mixed Isomers)
Dichloromethane
Methyl Ethyl Ketone
Ethylene
Acetone
Propylene
Ammonia
Toluene
Methanol
Xylene (Mixed Isomers)
Cyclohexane
Methyl Ethyl Ketone
1,1,1-Tnchloroethane
Chlorine
Hydrochloric Acid
Xylene (Mixed Isomers)
1,1,1-Tnchloroelhane
Dichloromethane
Fr eon 113
Sulfunc Acid
Toluene
Acetone
Methanol
Acetone
Methanol
Toluene
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
Hydrochloric Acid
Ammonia
1.1,1-Tnchloroethane
Oicnlorometnane
Methyl Isobutyl Ketone
p-Xylene
Toluene
Xylene (Mixed Isomers)
Benzene
Propylene
Ethylbenzene
Ethylene
Cyclohexane
i ,2.4-Tnmethylbenzene
1,1.1-Tnchloroethane
1,1.1-Tnchloroethane
Toluene
Methyl Isobutyl Ketone
Acetone
Methanol
Sulfunc Acid
Xylene (Mixed Isomers)
Freon113
Methyl Ethyl Ketone
HydrochloncAcid
Total
Etnnune
(I6JVO
36.871.329
29.679.416
13,359.413
11.877.905
8.500,000
6.190.496
5.180.326
5.051.692
3,124,319
2,242,72V
22,312.265
12.161.384
11,979.030
11681.687
9,098,925
8.673.336
8,027,837
6,727,724
5.604.068
5,485.510
88.220,193
8.565.279
6.862.828
3.527.494
1,460,375
758,734
556,509
545,535
250.243
203.187
15.517.240
15.410.500
9,184.718
7.216.535
5,832.803
3,672.516
1,849.153
1.823.511
1.697,659
1.399.026
253.500
243.900
226,800
160.500
116.000
78,000
58,000
31.120
14,132
8.750
327.241
174.220
87,582
73.825
47.286
35,212
32.066
30.701
26,350
6.211
No 01
Emmen
83
S
131
72
1
90
59
111
40
64
82
162
86
205
240
197
242
63
127
156
13
20
22
22
4
15
24
22
15
10
78
82
116
86
105
41
59
71
29
30
12
5
3
4
4
8
3
3
2
4
sot
State
Toial
2648
2132
960
853
611
445
372
363
224
161
1374
749
738
719
560
534
494
414
345
338
7846
762
610
314
130
067
049
049
022
018
2061
2047
1220
958
775
488
246
242
225
186
2091
2012
1871
1324
957
643
478
257
1 17
072
37.13
1977
994
838
536
399
364
348
299
070
B-5
-------
Table B-2 (Continued)
State Emissions —1990
State Rank
WA 1
2
3
4
5
6
7
8
9
10
Wl 1
2
3
4
5
6
7
8
9
10
Chemical
Ammonia
Toluene
Methyl Ethyl Ketone
Acetone
Methanol
Chloroform
Hydrogen Fluoride
Xylene (Mixed Isomers)
1.1.1-Trichloroethane
Fraonm
1,1,1-Tnchloroethane
Toluene
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Glycol Ethers
Hydrochloric Acid
Methanol
Acetone
Oichloromethane
n-Butyl Alcohol
Total
Emistoni No 01
(Ih/yr) Emmnt
2.973,241
2.720.104
2.510.425
2.269.679
2.044.388
2.022.502
1.515.497
1.406.335
1.401.090
1,147.751
5.684,189
4.500.357
4.467,014
3.288.219
3.007.905
2.738.902 •
2.019.119
2,009.564
1.445.916
1,254.524
61
55
44
65
35
12
14
47
39
27
148
126
121
94
82
79
65
71
45
41
%OI
State
Total
1056
966
892
806
726
719
538
500
498
408
1383
1095
1087
800
732
666
491
489
352
3.05
State Bank
WV 1
2
3
4
5
6
7
8
9
10
WY 1
2
3
4
5
6
7
8
9
10
Chemical
Acetone
Toluene
Hydrochloric Acid
Methanol
Benzene
Elhylene Glycol
Ammonia
Dichloromethane
1,2-Dichloroethane
Styrene
Sulfunc Acid
Ammonium Nitrate (Solution)
Ammonia
Xylene (Mixed Isomers)
Toluene
n-Butyl Alcohol
Phosphoric Acid
Glycol Ethers
Cyclohexane
Benzene
Total
Emmoni No 01
(lotyrl Emittere
3.847.856
2.223.383
1.680.793
1.663.696
1.640.814
1.341.722
1.192.136
1,180.194
1.104.911
1.072.824
1.762.473
721,890
692.181
227.285
218.377
138.489
80.068
77,810
64.784
55.969
16
25
24
18
8
12
23
6
1
10
6
1
8
7
5
^2
2
2
3
4
%0t
State
Totil
1379
797
603
596
588
481
427
423
396
385
4082
1672
1603
526
506
321
185
180
150
130
B-6
-------
TABLE B-3
Regional Hot Spots
— 19903-DIGITZIP CODES-
3-Dail
2IPCW8
840
775
376
365
377
703
553
700
776
266
371
706
606
707
391
356
241
465
284
996
314
481
6
244
463
294
473
479
315
402
480
388
476
440
490
604
441
395
630
430
458
29S
232
756
457
641
672
494
708
619
Sans
UT
TX
TN
AL
TN
LA
MN
LA
TX
NC
TN
LA
IL
LA
MS
AL
VA
IN
NC
AK
GA
Ml
PR
VA
IN
SC
IN
IN
GA
KY
Ml
MS
IN
OH
Ml
IL
OH
MS
MO
OH
OH
SC
VA
TX
OH
UT
KS
Ml
LA
IL
No 01
Reese No 01
Reoora Facilities
163
1234
158
191
89
70
189
328
246
451
181
203
904
352
49
199
117
352
106
22
83
426
234
47
337
155
205
138
104
367
288
105
56
479
292
463
657
207
236
188
234
142
150
189
79
133
168
327
156
57
43
137
32
31
36
14
69
53
28
144
SO
28
285
38
21
49
33
137
27
4
22
116
84
20
67
42
60
38
25
78
86
44
9
141
101
107
194
22
64
48
61
51
47
40
14
37
37
86
20
17
HAP
Emuon]
(WM
99.536,894
25,902.429
18,697209
50.256.060
26,827.726
1.055.326
21.554.465
4.412.128
8.957.230
15.420.673
16.527.463
6.470.824
12.679529
9.647,290
3,101,298
13,921.610
3,624.169
13.275.575
13.043.199
327.394
11.050.607
10.079,341
7.853.998
10.898.012
10.719.300
9.569.068
6.878.389
8.832.738
8.774.284
9,350.609
9.759.594
9.810.747
7,988.435
8,769.442
8.068.355
6.776.005
7.454.064
7,993,394
7.754,645
6.287.223
5.129.532
6,824,570
7,499.214
3.589,998
4.833.428
7,919.372
7.722.269
6.089,639
5,123,816
6.850,748
tow ZIPS
Emsions 01 Totll IRI
(ln/yt) Emissions
100.849,411
57.469.466
53.092595
51.037.042
27.019.504
23.143,897
22.511.087
21.760.019
20.150.787
18,602.667
18,117,226
16,862.650
16.822.780
16.821,716
16,371,227
15.956.127
15.762.380
15,376.361
14.305,755
13.835.898
13.368.392
13.076.896
12.857.474
11.635.315
11.814.123
11.237.403
11.022.348
10.996.949
10.979.639
10.855.534
10.707687
10.435.696
10,347.389
9.867259
9.683.069
9.555.324
9.401.692
9.269.335
9.267,374
9.178,104
9,099.944
9,083.792
9.077.450
8.832.115
8.670.306
8,435.448
8.385.318
8.31 1.285
8.179.382
8.115.903
459
262
242
233
123
105
103
099
092
085
083
077
077
077
075
073
072
070
065
063
061
060
059
054
054
051
050
050
050
049
049
048
047
045
044
044
043
042
042
042
041
041
041
040
040
038
038
038
037
037
3 Den
ZIP Case
381
420
551
272
777
296
70
299
297
605
317
456
768
260
226
740
601
945
705
342
495
397
370
902
483
452
527
852
926
278
281
261
150
143
631
238
292
712
770
723
132
467
338
287
550
190
293
737
245
462
SB'e
TN
KY
MN
NC
TX
SC
NJ
SC
SC
IL
GA
OH
TX
WV
VA
OK
IL
CA
LA
FL
Ml
MS
TN
CA
Ml
OH
IA
AZ
CA
NC
NC
WV
PA
NY
MO
VA
SC
LA
TX
AR
NY
IN
FL
NC
MN
PA
SC
OK
VA
IN
No 01
Rnease No 01
Reoora FiaMes
216
147
230
282
152
358
724
32
133
211
100
108
21
109
81
151
486
411
52
SO
291
80
166
389
138
409
118
178
224
164
224
121
243
99
482
101
77
72
523
109
78
212
117
128
155
198
204
11
176
289
60
26
78
99
13
116
213
4
33
. 55
36
25
5
28
16
35
164
103
IB
26
75
24
54
138
39
114
33
57
98
69
67
18
S3
20
129
29
21
21
127
31
27
84
46
41
35
59
54
5
56
80
HAP
Emissions
ObA/r)
3,532.260
5,211,007
6,112.556
6.561.785
3,267.749
6,217,705
5.503.147
5.744.330
3.474.192
5.852.316
5,849.431
3.978.222
5.545.032
6.318 151
6.877.847
3.712.635
5,833.413
3,649.710
7.004.599
716,462
5,725.474
6.381,807
5.934.885
5.365.097
5.019.751
5.430.605
Z973.084
Z 704,211
4.790.094
3.609.489
5.704.103
5.636,380
Z8S6.720
6,108,507
5.455,765
4.170.291
5.669.013
5.200.597
3.882.632
3.281.754
2,880,519
4.950,688
702.022
4.678.673
5,049,158
4.082.359
4,834.161
1.755,075
5,034,159
4,291.313
Toill Dfl,
Ewssions 01 loin IN
(In/yr) Emissions
7,851.866
7.838,917
7.776.532
7.727.861
7.638.579
7.625.586
7.591.723
7.585.138
7.463.647
7.328,580
7,309,692
7306.541
7.295,966
7,254.611
7,233.208
7.197.638
7.173.195
7.022.044
7.010.644
6.980.389
6.975.577
6.896.815
6.889,981
6.843.448
6.712.416
6.702.997
6.621.773
6.586.337
6.487.602
6.383.933
6.363,539
6.272.145
6.246.441
6.241.702
6.218,364
6.143,991
6.143,451
6.094.697
6.080,868
6,046,717
5,941,733
5.938,490
5,918.325
5.650,207
5.826.232
5.771.402
5,700.003
5.535.587
5.532.441
5.516.490
036
036
035
035
035
035
035
035
034
0.33
033
033
033
033
033
033
033
032
032
032
032
031
031
0.31
031
031
030
030
030
029
029
0.29
028
028
028
028
028
028
028
028
027
027
027
027
027
026
026
025
025
025
22136 5904 836,620.262 1.192.516,623 5433
B-7
-------
TABLE B-4
Regional Hot Spots
— 1990 COUNTIES-
Cocrry
Tooeie
Mobile
Sullivan
Harris
Cook
Ascension
Los Angeles
Hamblen
McLeM
Brazona
Calcasieu
Jetlerson
SI James
Kenai Peninsula
Chatham
Wayne
Sail Lake
Yazoo
Giles
Lake
Galveslon
Jefferson
Orange
Humphreys
Cuyahoga
Orange
Oakland
Easl Salon Rouge
Colbert
Caiawoa
Washington
Sedgwick
IiDpe canoe
Alleghany
Barcelonela
Posey
Shelby
King
SI Louis
Hampton
Niagara
Ken!
Brown
Hamilton
Kanawna
Harrison
Allegheny
Union
Glynn
Manatee
sate
UT
AL
TN
TX
IL
LA
CA
TN
MN
TX
LA
TX
LA
AK
GA
Ml
UT
MS
VA
IN
TX
KY
CA
TN
OH
TX
Ml
LA
AL
NC
OH
KS
IN
VA
PR
IN
TN
WA
MO
SC
NY
Ml
TX
OH
WV
TX
PA
OH
GA
FL
No Of
Reese
No 01
Rears fx es
8
205
102
1348
1800
146
1900
60
35
232
181
298
38
21
89
608
186
2
8
225
191
368
579
16
669
83
261
176
59
145
79
173
82
16
42
39
233
318
323
19
169
325
19
443
136
73
365
43
32
39
4
40
14
234
551
13
634
21
a
22
22
31
7
3
24
145
48
1
1
42
19
79
230
4
198
13
65
22
15
56
14
40
18
4
8
3
67
116
82
3
37
83
3
120
12
12
81
7
7
18
HAP
Emisions
IBM
95,211 736
49,891.576
5,597485
20.723405
26.669.597
4,142.097
23.825.820
24,814.689
19.816,689
7,257,824
5.740,333
7.250,901
246,853
327394
11.050637
10.112.592
11.089889
3,800
1 038,003
9908,093
2903589
9,350,683
7,579.612
9.137601
7.521.413
3.302.878
7.076,414
6,068.059
7.640,176
7,724,051
4,833428
7,726159
6,303577
7671.402
5,073.200
5.817.341
3.662.099
6.120,704
6.436,164
5,738,687
6,930,580
6.037,181
5.498,737
5.776,350
2.939,294
2.273.932
4.386.199
4,370,876
5715,117
631,134
rain County %
Elusions Of ton ffll
(I0/yr) Enssiors Ceo
95,211991
50,811,215
37,869,166
37,102,085
33.785348
30.789,313
30.547.084
25.102,702
20.221,634
16.945,486
16.022,184
15,853.701
15,106,674
13,835648
13.368437
12,878736
12,625,358
12287,721
11608,003
11,431.419
11 160,733
10855,608
10542.116
9,653.259
9,499205
9,468755
9,262.735
9.237.842
9214.714
8,912.005
8670.306
8.389708
8.362.412
8,188.157
8.161,835
8125943
8,047,729
7 849,151
7,580.479
7,553,642
7,549479
7424719
7249,171
7,146,242
7,005.916
6.974651
6.957.273
6.905.049
6871032
6.847.842
434
231
1 73
169
154
140
139
1 14
092
077
073
072
069
063
061
059
058
056
053
052
051
049
048
044
043
043
042
042
042
041
040
038
038
037
037
037
037
036
035
034
034
034
033
033
032
032
032
031
031
031
Marshall
Brunswick
Charleston
Kaiamazoo
Frederick
York
Elkhart
Ononoaga
Richland
Milwaukee
Harrison
Hawkins
Ramsey
Caioweii
St Mary
Lee
Middlesex
Maricooa
New Haven
MISSISSIPPI
Gartieid
Marion
Forsyth
Polk
Rid! mono
Tarranl
Lowndes
Morgan
Henry
Richmond City
Kosciusko
Lancaster
Hamilton
Douglas
Spartanburg
Lancaster
Erie
Sebastian
Manon
Washlenaw
Dallas
Montgomery
Nueces
Caner
Washington
Middlesex
Bucks
Lane
Franklin
Blacktoro
Saie
KY
NC
SC
Ml
VA
SC
IN
NY
SC
Wl
MS
TN
MN
NC
LA
MS
NJ
AZ
CT
AR
OK
IN
NC
FL
GA
TX
MS
AL
VA
VA
IN
PA
TN
IL
SC
NE
NY
AR
IA
Ml
TX
OH
TX
TN
TN
MA
PA
OH
OH
IN
No Of
Release
Reocrs 1
91
30
68
97
37
77
195
124
83
483
20
27
167
136
39
S3
486
314
334
43
11
293
102
104
74
280
39
106
92
54
59
192
108
16
174
54
220
98
24
65
451
209
147
9
23
366
162
176
240
22
No 01
jolil.es
9
5
17
23
11
19
82
45
24
134
6
10
62
31
5
23
128
115
112
16
5
32
39
41
27
99
9
21
24
20
19
69
37
2
40
22
92
30
6
20
142
49
18
3
8
133
48
46
65
3
HAP
Tout Ccj."V \
faiumni 01 Iniat IRI
(IB^rl ~ (livyt) E-IIMTI
4651.410
6.659319
5482416
5531.324
6.286.337
Z 967,991
5,553261
3088.293
5.743.427
4.860774
5958589
3935.604
4.577.068
4654.031
5475604
5,618,220
4.523.314
3.895.843
4,746,186
£783.525
1,755.075
4,295030
4,868.891
523.989
3,420.161
3.815.400
5.076.984
5.089.567
4,791.871
4,075653
4.805,028
4,309859
4,742529
4,092.021
4,299,712
4,829,456
4.151 ISO
3.944.988
4.191.195
3.552.720
3,899.448
3.614.223
3,501.173
4.622.755
4563,222
3.395.645
4.147.688
4.484.591
3,661 473
2.600.706
6722.956
6722276
6.669449
6.631.679
6572538
6542.379
6511274
6434286
6233.875
6.165.775
6.070955
6.045845
S899417
5.828751
S.651 704
5.651,071
5,616.057
5.580.836
5,565.891
5.540753
5.535.587
5.520235
5.496.460
5.450,110
5.428.094
5363.148
5,348,298
5341777
5321,569
5.319,175
5,289.163
5.169041
5117001
5103467
5.012.387
4.979861
4961,570
4952.072
4833.027
4,811.383
4.749658
4691.773
4.676.342
4.654.590
4,636,839
4,627974
4.621.287
4,602706
4.575,781
4.547.585
031
031
030
030
030
030
030
029
028
028
028
028
027
027
026
026
026
025
025
025
025
025
025
025
025
024
024
024
024
024
024
024
023
023
023
023
023
023
022
022
022
021
021
021
021
021
021
021
021
021
19881 5397 723,087.289 1,036,467340 4722
B-8
-------
TABLE B-5
Air Emissions By U.S. Industry
—1990 —
2-Oigil
SIC Can
• 0
0
1
2
3
10
12
14
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
42
43
44
45
46
47
49
SO
51
52
56
57
63
65
73
75
76
78
80
84
85
87
89
91
96
97
98
99
NA
TN
ZO
US Incus*
Food
Tobacco
Tallies
Apparel
Lumber
Furniture
Pulp 8 Paper
Printing
Chemicals
Petroleum Refining
Rubber. Rashes
Leather
Stone. Clay. Glass
Primary Metals
Fabricated Metals
Non-Elect Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manufacturing
Nod
Er.icn
48
1
12
2
5
5
1
1
7
11
6
2
2
1.245
18
370
38
578
559
618
382
3.988
368
1,737
124
573
1.746
2.911
1,075
1.649
1.285
445
381
1
1
3
2
2
1
1
11
20
51
1
1
1
2
1
21
5
5
4
2
1
1
8
2
1
1
6
2
2
12
1
1
1
Moot
Re'BSB
Rexr;s
90
1
39
3
10
20
2
1
12
20
7
6
11
1.963
24
721
90
1.459
1.842
2.129
723
19.948
2.868
3.996
302
1.538
5.969
7.511
2.573
4.561
4.686
1.026
942
1
1
16
12
14
13
2
32
40
224
3
4
4
2
1
37
8
6
4
2
8
1
46
2
1
SO
19
2
2
23
1
1
1
HAP
E-ssons
(b/vrt
664.275
126000
148.131
0
522748
763652
0
32.000
270
17.776
49.215
1.330
130.815
7.518.680
962.244
27934.842
1.463.725
31.631.074
51,388.137
201.760.929
50,151.702
379.708.920
47.083.706
161.355.068
9,071,126
16.653,601
183,411.554
103737.952
42654.617
56.496.845
153414.532
19.594.178
18.597711
1.000
19.000
27855
21.839
331.528
625.000
53,207
5041.913
396.219
472.524
4.786
295,760
760
0
23.864
108,649
83574
53,105
5.836
4250
23.200
1
10.132
0
229
5.325
237.711
451
0
784.423
0
36.000
0
Total ir.oua.y*
Emissions 01 loai
(ID/yr) FRI Emissions
991.463
126.000
166.594
30,960
524.496
858.042
932.221
32.000
7.873
43.110
49.951
1.835
182.815
26,825.739
2.475.256
33,965.968
1.600.203
35,331.018
60.050.069
243,894.677
52,033,362
69l!856!635
70.738.380
192270.498
11,845.521
21,844.026
221,864.484
129,161.415
52.614.164
81.808,173
193.232.254
32.456.885
24,442.174
1.000
19.000
31.223
263.871
341.738
704,015
53,207
5.083,595
584,372
1.059.482
4,786
308,409
1,260
7.900
23.864
142.687
94.060
75.110
5.846
19.250
26.700
1
265.186
4.409
229
9.600
382.146
451
47,004
974,537
39.168
36.000
54,228
005
001
001
on
002
004
004
000
000
000
000
ox
001
122
Oil
155
007
161
274
11 11
237
3152
322
876
054
100
1011
588
240
373
880
148
1 11
000
000
000
001
002
003
000
023
003
005
000
001
000
000
000
001
000
000
000
000
000
000
0.01
000
000
000
002
000
000
004
000
on
000
20.368
(Note Only SICs 20-39 are required to report to TRI)
65.676 1.575.715,496
2.194,922.597
10000
B-9
-------
TABLE B-6
Industrial Emissions
— 1990 —
2 Oigu
sccoce
23
26
33
37
30
34
36
29
25
35
27
24
22
38
20
39
32
31
49
21
23
51
NA
10
3
46
50
2
97
45
56
87
No 01
E -liners
3.988
618
1.746
1,285
1,737
2.911
1,649
368
559
1,075
382
578
370
445
1,245
381
573
124
11
18
38
51
48
12
1
5
1
20
5
6
2
1
8
HAP
Eifl'SSions
(la/yr)
379.708.920
201.760,929
183,411,554
1S3.414.S32
161,355,068
103.737.952
56.496,845
47.083.706
51.388,137
42.654,617
50.151.702
31.631.074
27,934,842
19,594.178
7.518.680
18.597.711
16.653.601
9.071.126
5.041.913
962.244
1,463.725
472,524
664.275
784,423
0
763.652
625,000
396.219
522.748
237711
331528
295.760
10,132
loai
Emissions
(IBM
691,856.635
243,894,677
221,864.484
193.232,254
192,270,498
129.161.415
81,808.173
70.738.380
60,050.069
52,614,164
52,033,362
35,331,018
33,965,968
32,456.885
26,825.739
24,442.174
21,844.026
11,845,521
5.083.595
2,475,256
1.600,203
1,059.482
991.463
974.537
932.221
858.042
704.015
584.372
524,498
382.146
341.738
308.409
265,186
Incus-yl
Oi lam mi
Enssions
3152
11 11
1011
880
876
588
373
322
274
240
237
161
155
148
122
1 11
100
054
023
011
007
005
005
004
004
004
003
003
002
002
002
001
001
2 Oif
SICCcce
44
19
0
73
0
75
76
47
17
99
16
TN
ZO
12
43
1
84
65
80
42
96
63
14
78
52
89
18
57
40
98
91
85
NO 01
E-^ers
2
2
12
21
1
5
5
1
1
6
2
11
1
1
1
3
2
1
1
2
1
1
2
7
4
1
2
2
1
1
2
1
1
HAP
Emissions
VOi')
21,839
130815
148.131
108,649
126.000
83.574
53,105
0
53,207
49,215
0
17.776
0
36.000
32.000
27,855
0
23.200
23.864
4.250
19.000
5.325
0
270
5,836
4.786
0
1.330
760
1.000
451
229
1
loui
Emissions
llB/yrl
263871
182815
166,594
142.687
126.000
94060
75,110
54.228
53.207
49.951
47.004
43.110
39,168
36.000
32.000
31,223
30.960
26.700
23.864
19.250
19.000
9.600
7.900
7,873
5.846
4.786
4.409
1.835
1260
1.000
451
229
1
moasiiv \
0 Tom m
Earners
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
20.368
1 S7S.715.496
2.194.922.597
10000
B-10
-------
TABLE B-7
Air Emissions For The U.S. Chemical Industry
— 1990 —
IOBI fsai foai
4 Oieii Emissions 4 DIM E-'Sic-s 4 Oicn Enisionj
SCCoce Pn/V'l SiCCooe (lay) SCCoct (ia/yr)
2800 2.153,209 2834 27267400 2864 3.925
2801 1.510 2835 17463 2865 20.769.711
2812 14.743.529 2836 298378 2869 149.570.880
2813 3.321466 2839 47.251 2873 119.866.933
2815 158.819 2840 16849 2874 14.125.378
2816 17,928.301 2841 2097,446 2875 2.307.809
2818 11,308 2842 1.014064 2879 4,978,527
2819 30,400,328 2843 4,364436 2890 12.963
2821 100.945.869 2844 282070 2891 4500.138
2822 20.104.714 2846 2.770 2892 5.102.444
2823 54.666.806 2650 107169 2893 2.347,463
2824 17.338.382 2851 22107124 2895 14,233.375
2830 383.798 2852 34,000 2898 2.102
2831 293.915 2860 141526 2899 7.848,728
2633 21.861974 2861 4.074380
B-11
-------
TABLE B-8
Top Industrial Emitters
- 1990 4-DIGITSIC CODES-
Rin< SC
1 2869
2 2873
3 3339
4 2621
5 2611
6 2911
IOBI « 01
Enissions 2 Dijil
(ft/yr) SCCooe Ran,
149,570.880 21 62 1
2
3
4
5
6
7
8
9
10
119,866.933 1733 1
2
3
4
5
6
7
8
9
10
101.574.712 4578 1
2
3
4
5
6
7
8
9
10
100,945.869 1459 1
2
3
4
S
6
7
a
9
10
79,159992 3246 1
2
3
4
5
6
7
8
9
10
66.740.635 94 35 1
2
3
4
5
6
7
8
9
10
total SOIIotii
Emission 2 Owl
ft'cr-ial (luyr) SC
Aceione
Melhanol
Elhyiene
Propylene
Ammonia
Toluene
Chloromelhane
Hydrochloric Acid
Benzene
1.2-Oichloroelhane
47.816.155
16.248.289
15.394.973
5,985.871
5.679.983
5.488.463
5.184,807
4,285,313
3,794,851
3,008,122
Ammonia 109.851,760
Melhanol
Ammonium Nitrate (Solution)
NilncAod
SulluricAcid
Propylene
Acrylonilnle
Acelomlnle
Oielhanolamme
Phosphoric Add
Chlorine
Hydrochloric Acid
Ammonia
Methyl IsobulylKetone
Zinc Compounds
Lead Compounds
Teirachloroeihyiene
Melhanol
SulluricAcid
1.1.1-Tricnioroeinane
Carbon Disullide
Elhyiene
Aceione
Melhanol
Dichlorornelnane
Propylene
Sfyrene
Toluene
Chlorobenzene
Vmyi Acetate
Methanoi
Chloroform
Hydrochloric Acid
SulluricAcid
Aceione
Chlorine
Chlorine Dioxide
Ammonia
Toluene
n-Bulyl Alcohol
Xylene (Mixed Isomers)
Toluene
Ammonia
Propylene
Benzene
Methyl Elhyl Kelone
Elhyiene
Cydohexane
Melhyl Ten-Butyl Ether
Elhylbenzene
6,995.370
1,589.759
721.913
163,712
153.100
98,000
93.000
42,432
33.979
88.172.906
6,983.785
3.149,072
1.000.095'
878.366
596.567
183.393
130,740
66,821
62.281
23640.447
13.564.250
9871.796
9,636.721
6.645.291
4.276.119
3,793,176
3.555.097
2964.069
2.296.907
35.483.069
11,196,552
8.700.721
6.138.487
6,056.215
4 705.481
3.874.787
1,575.990
955.000
185.250
12,410.594
10.515,366
7,711.697
7.117.324
5.991.763
3.624.133
3.289.001
1.904,229
1.666,914
1.599,383
691
235
223
087
082
079
075
062
055
043
1588
101
023
010
002
002
001
001
001
000
3974
315
142
045
040
027
008
006
003
003
342
196
143
139
096
062
055
051
043
033
1455
459
357
252
248
193
159
065
039
008
1754
1487
1090
1006
847
512
465
269
236
226
lo:ai \ Of
E-mssiors 2 Ogil
Rar< SIC Co/yr) SIC Code Rink Clemicai
7 3711 56399188
8 2823 54.666,806
9 2621 49492.015
10 3089 42963,419
11 2672 39.319,382
12 2511 38,805,171
2919 1 Xylene (Mixed isomers)
2 Glycol Ethers
3 n-Bulyl Alcohol
4 Methyl Isoouiyl Kelone
5 Toluene
6 Aceione
7 Methyl Ethyl Kelone
8 Melhanol
9 1.1.1-Tnchioroelhane
10 Elhylbenzene
79 1 Carton Disullide
2 Aceione
3 Methyl Elhyl Kelone
4 Benzene
5 Oichloromelhane
6 Methanoi
7 Formaldehyde
8 Ammonia
9 Vinyl Acetate
10 Sulf uric Add
2029 1 Melhanol
2 Hydrochloric Add
3 Chloroform
4 SulluricAcid
S Aceione
6 Chlorine
7 Ammonia
8 Chlorine Dioxide
9 1.1.1-Tnchloroelhane
10 Toluene
2235 1 Carbon Oisulllde
2 Aceione
3 Methyl Elhyl Kelone
4 Slyrene
5 Toluene
6 I.t.l-Trichloroelhane
7 Oichloromelhane
8 Xylene (Mixed isomers)
9 Melhanol
10 Methyl isotaulyl Kelone
16 12 1 Toluene
2 Methyl Elhyl Kelone
3 Melhanol
4 Xylene (Mixed Isomers)
5 Oichloromelhane
6 Cydohexane
7 Aceione
8 Telrachloroeltiylene
9 U.l-Tncriloroelrane
10 Formaldehyde
6462 1 Toluene
2 Melhanol
3 Xylene (Mixed isomers)
4 Methyl Elhyl Kelone
5 Aceione
6 n-Bulyl Alcohol
7 Methyl isobulyl Kelone
8 1.1.1-TncMotoelhane
9 isopropyl Alcohol (Manutad)
10 Glycol Ethers
faai % 0 loai
Emission 2 DIG;
(tiff) SIC
20.968.720
6.125.943
4,821.814
4.586.837
4.533,736
3,920695
3,690.011
2.401.216
2.013.003
1,566006
50.112.000
' 2,921.778
767.476
528.431
159.132
79.616
50.078
34.200
4.773
2.750
15,716,088
13.228.381
6,276.935
5.614.805
2.33S.637
1.221.636
1.161.024
928,773
768,981
564,977
9,111,829
7.707.623
4.761.091
4.615367
4.252.974
3,555.979
2.438.943
1.352.485
1.048.171
940,614
19,160,105
12.461,369
2.221.780
1,269.886
1.041.346
980.073
666,335
421.400
293.637
120.226
11.453.337
8,206,801
5,763.047
3.838,082
3,723.200
2.086.1S9
1.356.543
750.404
548,444
528,630
1085
317
250
237
235
203
191
124
104
081
724
042
Oil
008
002
001
001
000
000
000
644
542
257
230
096
050
048
038
032
023
474
401
248
240
221
185
127
070
055
049
786
511
091
052
043
040
027
017
012
005
1907
1367
960
639
620
347
226
125
091
088
B-12
-------
Table B-8 (Continued)
Top Industrial Emitters —1990 4-Digit SIC Codes
lOBl %OI
Emissions 2 Digil
Rjn< SC (ID/y) SCCooe fer,< Cnerac*
13 3086 38,764.514
14 3312 37,738,966
15 3411 37,340.435
16 3079 35.421.635
2016 1
2
3
4
S
6
7
8
9
10
1703 1
2
3
4
5
6
7
8
9
10
2891 1
2
3
4
5
6
7
8
9
10
1842 1
2
3
4
S
6
7
8
9
10
Dictiloromelhane
1 1 1-Tndiloroelhane
Chloroelhane
Acetone
Toluene
Methyl Ethyl Kelone
Naphthalene
Freon 113
Tetrachloroelhytene
Banum Compounds
Benzene
Ammonia
1.1.1-Tnchloroellane
Hydrochloric Add
Zinc Compounds
Xyiene (Mixed Isomers)
Toluene
Elhyiene
Naphthalene
Manganese Compounds
Glycol Ethers
n-Bulyl Alcohol
Xyiene (Mixed Isomers)
Melhyl Ethyl Kelone
Toluene
Melhyl isobutyl Kelone
Cyctohexane
1,1.1-Tricnloroelhane
Dimethyl Phlhalale
Tnchioroelhylene
Acetone
Melhanol
Dicnloromelhane
Carbon Oisuilide
Melhyl Ethyl Kelone
Toluene
Ammonia
Slyrene
1.1.1-TncMoroetrane
Xyiene (Mixed Isomers)
toui nouoiai
Emissions 2 O'QiI
(ia/yr) sfc
24.672.546
9,670.502
1.645.900
1.056.474
519.764
518.094
219.923
131.886
48.250
40.970
11.074.169
6,624.133
3.909.398
2.383.878
1.332.164
1.318.318
1.268.027
1.024,210
385,209
827.108
16,655,739
11,438,941
3.736.498
1.304.417
1. 2801875
853,210
733.792
496.953
244.000
228.340
7.297.365
5.975.345
3.403.872
3.100.750
2.620.594
2.295.180
2.038,975
1.966.907
1.731.885
1.676,459
1283
503
086
055
027
027
Oil
007
003
002
499
299
176
107
060
059
OS7
046
040
037
1290
886
289
101
099
066
057
038
019
018
380
311
177
161
136
119
106
102
090
087
Rai» SIC
17 3714
18 2754
19 2631
20 2819
IQUI tOf
Elisions 2 Digil
(iB/yr) SC Cooe Rin<
33.310.990 1724 1
2
3
4
5
6
7
8
9
10
32884.905 632 1
2
3
4
5
6
7
8
9
10
31.872.016 1307 1
2
3
4
5
6
7
8
9
10
30.400.328 4 39 1
2
3
4
S
6
7
8
9
10
Cfemca,
Xyiene (Mixed Isomers)
1 1 1-Tnchloroelhane
Melhyl ElhylKetone
Toluene
FreonH3
Tnchloroelhylene
Acetone
Slyrene
Glycol Ethers
TelracMoroeihylene
Toluene
Melhyl Ethyl Kelone
Xyiene (Mixed Isomers)
l.i.l-Tnchloroelhane
Melhanol
Acetone
Glycol Ethers
Melhyl IsoDuryl Kelone
Cydohexane
n-Sulyl Alcohol
Melhanol
Hydrochloric Acid
Acetone
Sullunc Aad
Chloroform
Ammonia
Chlonne Oionde
Chlonne
Melhyl ElhylKetone
Toluene
Ammonia
Chlonne
Melhanol
Sullunc Add
Elhyiene
HydrochloncAcid
Carbon Disulllde
Toluene
Elhyiene Glycol
Phosphoric Add
mi i
Emissions
(in/V)
4.776.655
4,449.505
4,081.272
3,479.197
2.646.119
2.639.929
2,425.501
1,957.272
1 249.671
1,075.087
26,058.409
3.459.532
1.039248
736.902
399122
298.700
284,206
198.498
122.000
63.417
15.556.943
7,736.284
3,389,568
1,600.749
1.249.705
604.384
472,835
468,858
311.728
123.173
8.609.037
4,760,133
4,285.900
2.590.244
1,124.759
1,004,461
987,274
835.900
686.123
598.062
i 0 loai
"S
2*7
230
211
180
137
137
126
101
065
056
5008
665
200
142
077
057
055
038
023
012
638
317
139
066
051
025
019
019
013
005
124
069
062
037
016
015
014
012
010
009
B-13
-------
TABLE B-9
National Emissions 01 HAPs
-1990 —
Chemical
Toluene
Melhanot
1,1 1-Tncnioroelhane
Xylene (Mixed Isomers)
Melhyl Elhyl Kelone
Chlonne
Carbon Disullide
Dichiofomethane
Hydrochloric Acid
Giycm Ethers
Tnchloroelhylene
Slyrene
Melhyl Isobulyl Ketone
Benzene
Chlorolorm
Telrachloroelhylene
CartonylSullide
Formaldehyde
ElhyleneGlycol
Elhyibenzene
Hydrogen Fluonde
Phenol
Chloromelhane
Acelaldehyde
1,2-Oichloroelhane
vinyl Acetate
1,3-Buladiene
p-Xylene
Chlorobenzene
Cumene
Ctiloroelhane
Naphthalene
Acrylonilnle
Melhyl Tert-Bulyl Elher
Elhylene Oxide
Manganese Compounds
Bromomelhane
Methyl Meinacrylale
o-Xylene
Carbon Teirachionde
Acelontlnle
Lead Compounds
Propylene Oxide
Di(2-Elhylhexyl)Phlhalate
m-Xylene
Cyanide Compounds
Vinyl Chlonde
Biphenyl
Propionaldehyde
1.4-Oichlorobenzene
No 01
E.TIIMS
3.943
2,427
3.854
3,488
2,494
1,310
79
1,333
2.495
1,704
741
1.343
1.061
484
184
598
36
807
1.002
761
458
581
88
76
97
146
158
42
62
172
47
363
113
110
179
607
42
240
77
88
72
647
123
236
52
192
47
131
17
18
loai
Emissions
233.183,332
181.736.117
161.300622
139.944,280
121.284.483
104,888,670
98,222,679
92,469.428
73,444.872
46.896,269
37.849,923
31.630,955
27,311,372
24.013,998
21.762.461
21,624.949
18,634.864
12.765.498
9.375.633
8.604.518
8.546,064
7.641.485
7.373.241
6.709,663
5.595,973
5.556.759
5.037,331
4,752,672
4.046,799
4.012.113
3.942.078
3,706,121
3,147,995
2.784.624
2.447.494
2252.644
2205.819
2.116.153
1.904.571
1.671.092
1.663.517
1.623.709
1.359.996
1344.695
1202.284
1.138,102
1.135.809
1.119.120
988.986
818.133
HOI Cmrioi%
total HAPs 01 loin IRI
E.rissionj Elisions
1480
1153
1024
888
770
666
623
587
466
298
240
201
173
152
138
137
116
081
060
055
054
048
047
043
036
035
032
030
026
025
025
024
020
018
016
014
014
013
012
011
011
010
009
009
008
007
007
007
006
005
1062
828
715
638
553
478
447
421
335
214
172
144
124
109
099
099
085
058
043
039
039
035
034
031
025
025
023
022
018
018
018
017
014
013
Oil
010
010
010
009
008
008
007
006
006
005
005
005
005
005
004
NO a
C'ltr.ai Eminn
Chromium Compounds
Cresd (Mixed Isomers)
Phinaiic Anhydride
Methyienebis(Phenylisocyanate)
1,2-Dichloroprooane
1.1.2-Trichlorcelhane
1,4-Oioxane
Maleic Anhydride
Aniline
Epichiorohydnn
Acrylic Acid
Oielhanolamine
1.2.4-Tnchtorobenzene
Dimethyl Pullulate
Vmyiidene Chloride
Nickel Compounds
D-Cresol
Ally) Chlonde
Ethyl Acrylate
Chioroprene
Arsenic Compounds
Antimony Compounds
. Dibulyi Phthalate
Cadmium Compounds
Heiachlorocyclopenladiene
2-Nitropropane
1.2-Bulytene Oxide
Nitrobenzene
1.3-Oichloropropylene
1.2-Dibromoeltiane
2.4-Dimlrololuene
Toluene-2.4-Olisocyanate
Titanium Teiracnionde
Cooall Compounds
N.N-Oirnetnylaniline
Acryiamide
Bromolorm
i.i.2.2-Telrachioroelhane
o-Cresol
Benzyl Chloride
Selenium Compounds
Dibenzoluran
Melhyl iodide
Hydrazine
Calechol
Ouinolme
ChioroaceiicAcid
Phosphorus (Yellow Or While)
Penlachlorcphenol
Acrdem
999
112
157
374
10
27
79
179
61
81
163
226
45
45
20
468
14
21
98
5
215
242
94
102
4
8
19
16
7
25
7
97
27
128
19
53
2
16
27
43
31
43
4
41
23
26
22
33
44
14
tan
£ mi si oiu
769.517
731.961
687470
660,906
630.513
598.704
598.328
493.069
474339
427.361
426.854
383.664
376.866
333.555
303.602
265.421
239.004
206.024
204,190
175.134
165,805
145.951
108.277
90.013
84.585
84,258
79.465
66,260
59.473
58.070
57.583
57.312
54,360
51.734
50.715
49.968
48.205
44,596
39.146
33,545
30.612
30225
29,816
27859
27,737
27,690
25,404
24223
23,206
22.029
%OF (.
\S»mmi 4L
Tom HAM 01 loin m
Emissions Esisiors
005
005
004
004
004
004
004
003
003
003
003
002
002
002
002
002
002
001
001
001
001
001
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
004
003
003
003
003
003
003
002
002
002
002
002
002
002
001
001
001
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
'000
000
000
B-14
-------
.Table B-9 (Continued)
National Emissions OfHAPs -1990
NO of
Cneracj! [miners
4.4'-Melliylenedianiline
Caplan
Asbestos (Fnable)
Tnlluralm
Meihyl Isocyanale
Calcium Cyanamide
Hydroquinone
Vinyl Bromide
OimeltiylSullale
Carbaryl
Benzoic Trichloride
Hexachloroelhane
2,4-0
4-Nilrophenol
m-Cresol
o-Toiuidme
OielhyiSullale
Hexacnioro-l.3-Buladiene
Phosgene
Chlordane
UrelHane
2.4-Oiammololiiene
Heplachlor
Bis(2-Chloroelhyl)Eller
4.4'-Melhylenebis(2-Chlon»niline)
Slyrene Oxide
22
19
57
19
4
1
41
2
26
22
4
12
IB
4
11
IS
28
7
28
2
6
3
1
8
7
5
loai
E missions
(l*V)
19.523
19.252
17,327
15.606
14.373
12.620
11.387
10.105
9,739
9.170
8.315
8,041
7.742
7.653
7.567
7,442
5.493
4.906
4.853
4.422
4.070
3.928
3.797
3.778
2.765
2.423
«0f C.iemiai%
loai HAPS Oi loin IRl
Emsions E.-ussiora
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000,
000
000
000
000
000
000
000
Crern'cii
o-Anisidine
Melhoxychior
Oumone
Ufiaane
Hexacfticrobenzene
Dichlorvos
Mercury Compounds
p-Phenylenediamine
Parattiion
Propyleneimme
1.1-OlmelhylHydrazme
Qumlozene
Propoxur
Beryllium Compounds
Cnioromelriyl Melftyl Elher
a46-Tncnloroohenol
4 6-Oimlro-o-Cresol
Acelamide
ElhyieneThourea
W-OicniorownzidirB
Chloramben
Bis(Chloroneihyi) Elher
PdyOilonnaled Biphenyls
3,3'-Oimelho>yoen;idine
Meinyi Hydrazine
NO a
Emiiin
4
5
2
9
7
9
14
4
10
6
4
2
3
2
2
1
5
1
5
3
1
2
1
1
1
1
Tool
ElBS&OU
CWyr)
1841
1.602
1.602
1,549
1,468
1.310
1.158
768
613
612
463
271
270
212
124
78
47
35
35
25
10
5
5
4
1
,575.715.496
SOI O-jait
Iain HAPi Oi lain nil
Emissions . Ems&ors
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
ox
000
000
000
000
000
000
10000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
7179
B-15
-------
TABLE 8-10
National Emissions Of 33/50 Chemicals
— 1990 —
C.ieroo
Toluene
1,1.1-Tricriloroelhane
Xylene (mixed Isomers)
Methyl Elhyl Ketone
Didiloromelhane
Methyl Isobutyl Kelone
Chromium Compounds
Chromium
Nickel
Trichloraelhylene
Lead Compounds
Lead
Telrachloroelhylene
No Of
Emnera
3.943
3854
3.488
2.494
1,333
1.061
999
843
840
741
647
611
598
Tool
Emiaons
IIBAO
233.183.332
161 300.622
139944.280
121 284.483
92,469428
27311.372
769,517
737.710
6S4459
37.849.923
1,623,709
860.573
21.624.949
% 01 denial \
Io»l 3MO 01 lotii IRI
Cnemais Elusions
2601
1799
1561
1353
1032
305
009
006
007
422
016
010
241
1062
735
638
553
421
124
004
003
003
172
007
004
099
C'e- ai
Benzene
Nickel Compounds
Cyanide Compounds
Chloroform
Cadmium Compounds
Carbon Telractilonde
o-Xyiene
Cadmium
m-xylene
p-Xyiene
Mercury
Mercury Compounds
No 0
ETISBS
484
468
192
184
102
88
77
53
52
42
34
14
ten
Emsions
da/yo
24013998
265.421
1.138,102
21,762461
90,013
1671092
1,904,571
17,037
1.202.284
4,752.672
22404
1,158
896,455,570
* 01 Cue-iai \
Toil! 3360 01 loin mi
Crenias E.riiicrs
268
003
013
243
001
019
021
000
013
053
000
000
10000
109
001
005
099
000
008
009
000
005
022
000
000
4083
TABLE B-11
National Emissions Of High Risk/Early Reduction Chemicals
-1990 —
NO a
Cseraal Entires
Benzene
i.3-8uladiene
Acrylonilnle
Elhylene Oxide
Vinyl Chloride
Chromium Compounds
Chromium
Melhylenepis(Phenylisccyanale)
Acrylic Add
Vinylidene Chlonde
Chloroprene
Arsenic Compounds
Cadmium Compounds
1 2-Oibromoelhane
Toluene-2.4-Onsocyanale
Acryiamide
1.1.2.2-Telrachloroelhane
Oi benzoin ran
Hydrazme
484
158
113
179
47
999
843
374
163
20
5
215
102
25
97
53
16
43
41
tai
Emisions
(iDfrr)
24.013.998
5.037.331
3.147.99S
2447.494
1.135.809
769.517
737.710
660,906
426.854
303,602
175.134
165605
90,013
58.070
57.312
49.968
44,596
30.225
27.859
loal Hign
Risrfiny Cranial %
Reoucion 01 lota IRI
C ficiTiicii s E n* i si ons
6078
1275
797
619
287
195
187
167
108
077
044
042
023
015
015
013
011
008
007
109
023
014
Oil
005
004
003
003
002
001
001
001
OX
OX
OX
OX
OX
ox
ox
Ciemai
Mercury
Aaoiein
Asbestos (Friable)
Cadmium
Methyl isocyanale
Benzoic Trichloride
Arsenic
Phosgene
cniordane
Heplachlor
Bis(2-Ctiloroelhyl) Ether
Hexacnlorobenzene
Beryllium
Mercury Compounds
Propyleneimine
Beryllium Compounds
Chloromelhyi Methyl Ether
BisiChloromelhyl) Elder
No 01
EmmeT
34
14
57
53
4
4
34
28
2
1
8
7
6
14
6
2
2
2
Tmi
Emissions
22.404
22.029
17327
17,037
14.373
8.335
5.836
4,853
4.422
3797
3.778
1.468
1.370
1,158
612
212
124
5
39.509,338
total Hign
Risrfvty C.ienal
-------
TABLE 8-12
National Emissions Of Carcinogens In TRI Database
—1990-
CliST.ial
Dichloromelhane
Tnchlorcelhylene
Slyrene
Benzene
Clilorolomi
Telrachloroelhylene
Formaldehyde
CMoromelhane
1.2-Ochloroelliane
l,3-8uladiene
Acrylonilnle
Elnylene Oxide
CarDontelracnionde
Vinyl Chlonde
Chromium
1.1,2-Tnchioroelhane
Eoichlorohyarm
Vmylriene Chlonde
2-Niliopropane
l.2-0bromoeinane
2,4-Oimlraloiuene
1.1.2.2-Telracnloroeihane
Benzyl Chlonde
Melhyl iodide
Hydrzme
2.5-Oinilrololuene
NoO
Emmets
1.333
741
1.343
484
164
596
807
88
97
158
113
179
86
47
843
27
81
20
8
25
7
16
43
4
41
4
loai
Emissions
(IBM
92.469.428
37.849.923
31.630.955
24.013.998
21.762.461
21.624.949
12.765.498
7,373.241
5,595,973
5.037,331
3.147.995
2.447.494
1.671.092
1.135,809
737,710
598,704
427.361
303.602
64.258
58.070
57,583
44.596
33,545
29.616
27.659
17,737
\0t Csamal*
Tail 0! Ian in
Ci FQ flOQ&n s t (Ti issi ons
3412
1397
1167
866
8 '03
796
471
272
206
186
116
09
062
042
027
022
016
Oil
003
002
002
002
001
0.01
001
001
421
172
144
109
099
099
058
034
025
023
014
011
008
005
003
003
002
001
000
000
000
000
on
000
000
000
Cltemiai
Cadmium
Dimelhyl Sullale
Hexachloroelhane
o-Toiuioine
Arsenic
Hexacnloro-i 3-6uladiene
Chlordane
Ureihane
2.4-Diaminoloiuene
Heplachlor
8is(2-Cliloioeihyi) Elder
Ihiourea
Undane
HenchloroDenzene
Beryllium
Pronyleneimine
Alpha-NaDhlhylamne
1,1-OimelhylHydrazine
Oumluene
Cnioromeinyi Melhyl Elher
Z4,6-Tnchlorophenol
FJhylene Thiourea
3,3'-OicnloroDenzidine
8ls(Chloromeihyi) Elher
PoiycfilonnatM Bipnenyis
Salrole
No 0
Enilin
53
26
12
15
34
7
2
6
3
1
8
18
9
I
6
6
1
4
2
2
1
S
3
2
1
1
low
Emiionj
(IWrr)
17.037
9.739
8.041
7.442
5.836
4.906
4.422
4.070
3.928
3.797
3.778
2.86S
1.549
1,468
1.370
612
500
463
271
124
78
35
25
5
5
5
\a cncno*
Tan a Tan mi
CiirnajBii Einsionj
001
000
000
000
000
000
000
000
000
000
on
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
ox
000
000
000
000
000
000
ox
000
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
271.029.359
1XX
1235
TABLE B-13
National Emissions Of Ozone Depletors
In TRI Database
-1990-
ChGflMQl
1.1.1-TricMoroethane
Freonin
Carton Tetradilonde
NO. a
Efniitn
3,854
1.293
88
Tan
Emssons
(ID/Y'l
161.300.622
45208.966
1.671.092
10 CDemal*
ToiiiOane 01 Tail TRI
OeoiGHn ERtissoni
7746
2172
080
735
Z06
008
208.180.680
1XX
948
B-17
-------
TABLE B-14
All Chemicals Reported
—1990 —
Care
X
X
X
X
X
X
X
X
X
X
X
X
Ozone
Depl HAP
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HR/ER Chamcal
X 1.1.1-Trichloroethane
X 1.1.2.2-Tetrachloroethane
1.1,2-Tnchloroethane
1.1 -Dimethyl Hydrazine
1 ,2,4-Trichloro benzene
1 ,2,4-Tnmethylbenzene
1 ,2-Butylene Oxide
X 1 ,2-Dibromoethane
1 ,2-Dichlorobenzene
1 ,2-Ochloroethane
1.2-Dichloroethylene
1 ,2-Ochloropropane
X i.3-Butadiene
1 ,3-Dichlorobenzene
1 ,3-Dichloropropylene
1 ,4-Dichlorobenzene
i ,4-Dwxane
2.4.6-Tnchlorophanol
2.4-0
2,4-Diammoanisole
2.4-Oiaminoioluene
2.4-OcMorophenol
2,4-Oimeihylphenol
2.4-Oimirophenol
2.4-Dinitroioluene
2,6-Dimtrotoluene
2.6-Xyhdine
2-Ethoxyetfianol
2-Meinoxyeihanol
2-Nitrophenol
2-Nitropropane
2-Phenylphenol
S.S'-Ochlorobenzidme
3,3'-Dimethoxybenzidme
4,41-Oaminodiphenyl Ether
4,4'-lsopropylidenediphenol
4,4--Methylenebis
(2-ChKxoanihne)
4,4'-Mettiylenedianiline
4.6-Dimtrc-o-Cresol
4-Nitrophenol
5-Nitro-o-Anisidine
Acetaldehyde
Acetarnide
Acetone
Acetonitrile
X Acrotem
X Acrylamide
X Acrylic Acid
CasNo
000071 556
000079345
000079005
000057147
000120821
000095636
000106887
000106934
000095501
000107062
000540590
000078875
000106990
000541731
000542756
000106467
000123911
000088062
000094757
000615054
000095807
000120832
000105679
000051285
000121142
000606202
000087627
000110805
000109864
000088755
000079469
000090437
000091941
000119904
000101804
000080057
000101144
000101779
000534521
000100027
000099592
000075070
000060355
000067641
000075058
000107028
000079061
000079107
Emitted To Air
(byr)
161,300.622
44.596
598.704
463
376.866
4.408.182
79.465
58.070
323.948
5.595.973
124.499
630.513
5,037.331
8.682
59.473
818.133
598.328
78
7.742
26
3.928
820
7.326
24.697
57.583
17,737
17
958.135
2,472.081
4
84.258
9.910
25
4
905
182.899
2.765
19.523
47
7,653
10
6.709.663
35
180.207,465
1.663.517
22,029
49,968
426,854
Erntted To All
Madia (Wyr)
161,381.336
48.620
600.301
713
388.487
4.454.300
84.095
58.330
383.539
6.478.751
125.031
634.576
5.155.028
9.467
59.783
822.338
772,200
157
10.351
26
4.178
21.315
37.877
116.511
136.441
37.153
1.923
1.000.150
2.518.794
33
172.358
10.585
25
4
1.318
763.955
2.765
77,130
48
8.884
10
8.781.171
35
186.191.822
21.119.751
125.098
3.853,566
22,090,070
B-18
-------
Table B-14 (Continued)
All Chemicals Reported —1990
Care
X
X
X
X
X
X
X
X
X
X
X
Ozone
Old HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
33/50 HH/EH
X
X
X
X
X X
X
X
X
X
X
X X
X X
X
X
Chamieal
Acrylonitnle
Allyl Chloride
Alpha-Naphthylamme
Aluminum (Fume Or Dust)
Aluminum Oxide (Fibrous Form)
Ammonia
Ammonium Nitrate (Solution)
Ammonium Sullate (Solution)
Aniline
Anthracene
Anomony
Antimony Compounds
Arsenic
Arsenic Compounds
Asbestos (Friable)
Banum
Banum Compounds
Benzal Chloride
Benzene
Benzoic Trichloride
Benzoyl Chloride
Benzoyl Peroxide
Benzyl Chloride
Beryllium
Beryllium Compounds
Biphenyl
Bis(2-Cnloroethyl) Ether
Bis(2-Ethylhexyl) Adipate
Bis(Cnloromethyl) Ether
Bromoform
Bromomethane
Butyl Acrylate
Butyl Benzyl Phthalate
Butyraldehyde
Cl Basic Green 4
C 1. Disperse Yellow 3
Cl Food Red 15
Cadmium
Cadmium Compounds
Calaum Cyanamide
Captan
Carbaryl
Carbon Osuldde
Carbon Tetrachlonde
Carbonyl Sulfide
Catechol
Chloramben
Chlordane
Chlorine
Gas No
000107131
000107051
000134327
007429905
001344281
007664417
006484522
007783202
000062533
000120127
007440360
007440382
001332214
007440393
000098873
000071432
000098077
000098884
000094360
000100447
007440417
000092524
000111444
000103231
000542881
000075252
000074839
000141322
000085687
000123728
000569642
002832408
000081889
007440439
000156627
000133062
000063252
000075150
000056235
000463581
000120809
000133904
000057749
007782505
EmmodToAn
(ftvyr)
3.147.995
206.024
500
2 122.375
756.067
208.585.542
2.707.134
374.567
474.839
65,438
52.358
145.951
5.836
165.805
17.327
78.211
1,188,261
1.755
24.013.998
8.335
23.324
14.630
33.545
1.370
212
1.119.120
3.778
106.128
5
48.205
2.205.819
294,815
227.693
525.676
16
364
2
17,037
90.013
12.620
19.252
9.170
98,222,679
1.671.092
18.634.864
27,737
10
4.422
104.888.670
Emitted To All
Madia (htyt)
8.077.416
207.359
500
3.391.612
1.262.572
518.383.181
14.223.722
2.082.396
2.949.513
71.593
237.304
1.312.848
25.594
2.794.502
131.362
317,030
6,523.261
1.755
25.372.624
8.335
91.085
14.660
34.145
7.924
40.235
1.186.106
3.788
115.313
5
120.205
2.233.819
323.114
232.871
531.407
16
1.233
2
107.364
386,447
52.620
25,762
15.230
98.267.500
1,706.778
18.634.864
117.781
10
4.423
106.044,139
B-19
-------
Table B-14 (Continued)
All Chemicals Reported—1990
C«FC
X
X
X
X
Ozone
Owl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HR/ER Chemcal
Chlorine Dioxide
Chloroacenc Acid
Chlorobenzene
Chtoroethane
X Chloroform
Chtoromethane
X Chloromethyl Methyl Ether
Chlorophenols
X Chloioprene
Chlorothalonil
X X Chrofniuni
X X Chromium Compounds
Cobalt
Cobalt Compounds
Copper
Copper Compounds
Cresol (Mixed Isomers)
Cumene
Cumene Hydroperoxide
Cupferron
X Cyanide Compounds
Cyctohexane
Decabromodiphenyl Oxide
Di(2-Ethylhexyl) Phthalate
Diaminotoluene (Mixed Isomers)
X Dibenzofuran
Dibutyl Phthalate
Gas No
010049044
0000791 18
000108907
000075003
000067663
000074873
000107302
000126998
001897456
007440473
007440484
007440508
001319773
000098828
000080159
000135206
000110827
001163195
000117817
025376458
000132649
000084742
Dichlorobenzene (Mixed lsomers)025321226
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Owhlorobromomethane
X Dichloromethane
Dwhlorvos
Dieotol
Diethanolamine
Oethyl Phthalate
Oethyl Sulfate
Dimethyl Phthalate
Dimethyl Sulfate
Epichloronydnn
Ethyl Acrylate
Ethyl Chtoroformate
Ethylbenzene
Ethylene
EthyleneGlycol
X Ethylene Oxide
Ethylene Thiourea
Fluometuron
Formaldehyde
FreonHS
Qlycol Ethers
000075274
000075092
000062737
000115322
000111422
000084662
000064675
000131113
000077781
000106898
000140885
000541413
000100414
000074851
000107211
000075218
000096457
002164172
000050000
000076131
EmKtod To Air
(Wyr)
5.411.551
2S.404
4.046.799
3.942.078
21.762.461
7.373,241
124
4,931
175.134
12.454
737.710
769.517
36.324
51.734
1.261.185
3.908,941
731.961
4.012.113
110.421
485
1.138.102
17,135.545
64,300
1,344,695
25.714
30.225
108.277
89.524
632
92,469.428
1.310
268
383.664
96.397
5.493
333.555
9.739
427,361
204.190
1.822
8.604.518
38,543.316
9.375.633
2.447.494
35
45
12.765.498
45.208.966
46.896.269
Emm«d To All
M«da(Hyyf)
5,412.371
27.095
4,171.865
3.978.278
22.909.752
7.809.253
124
179.584
175.134
12.463
1,774.814
14,610,427
51,534
135.954
12,650,108
54,117.322
2.372.386
4.046.552
162.760
485
1,303.162
17,521.657
73.128
1,363.874
115.934
31.654
218.449
89.558
632
93,523.989
1.310
273
617,318
98.584
5.538
334238
10,114
524.868
205.859
1.822
8,892.077
38,593,309
11,662.056
2,529,727
35
45
21,897.756
45.258,386
47,371,703
B-20
-------
Table B-14 (Continued)
All Chemicals Reported —1990
Care
X
X
X
X
X
X
X
Ozone
D«pl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33,50 HR/ER Chemical
X Heptachlor
Hexachloro-1 ,3-Butadiene
X Hexachlorobenzene
Hexachkxocydopentadiene
Hexacfitoroethane
X Hydrazme
Hydrazine Sulfate
Hydrochloric Acid
Hydrogen Cyanide
Hydrogen Fluoride
Hydroquinone
Isobuiyraldehyde
laopropyl Alcohol
(Manufacturing)
X Lead
X Lead Compounds
Lindane
m-Cresol
X m-Xylene
Malsic Anhydride
Maneb
Manganese
Manganese Compounds
X X Mercury
X X Mercury Compounds
Methanol
Methoxychlor
Methyl Acrylale
X Methyl Ethyl Ketone
Methyl Hydrazine
Methyl Iodide
X Methyl Isobuiy! Ketone
X Methyl Isocyanaie
Methyl Methacrylate
Methyl Tert-Buiyl Ether
Methylene Bromide
X Methylenebis(Phenyhsocyanate)
Molybdenum Tnoxide
N.N-Omethylaniline
n-Butyl Alcohol
n-Dioctyl Phthalate
Naphthalene
X Nickel
X Nickel Compounds
NitncAod
Nitntoiriacetic Acid
Nitrobenzene
Nitroglyeenn
o-Anisidme
CasNo
000076448
000087683
000118741
000077474
000067721
000302012
010034932
007647010
000074908
007664393
000123319
000078842
000067630
007439921
000058899
000108394
000108383
000108316
012427382
007439965
007439976
000067561
000072435
000096333
000078933
000060344
000074884
000108101
000624839
000080626
001634044
000074953
000101688
001313275
000121697
000071363
000117840
000091203
007440020
007697372
000139139
000098953
000055630
000090040
Emitted To Air
-------
Table B-14 (Continued)
All Chemicals Reported — 1990
Caic
X
X
X
X
X
X
X
X
Ozone
Dool HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HfVER Chemcal
o-Cresol
o-Toluidme
X o-Xylene
p- Am si dine
p-Cresidme
p-Cresol
p-Nitrosodiphenylamme
p-Phenylenediamme
X p-Xylene
Parathon
Peniachlorophenol
Peraceoc Aad
Phenol
X Phosgene
Phosphoric Acid
Phosphorus (Yellow Or White)
Phthalic Anhydride
Picric Aod
Polychlormaied Biphenyls
Propionaldehyde
Propoxur
Propylene
Propylene Oxide
X Propyieneimine
Pyndme
Quinolme
Quinone
Qumtozene
Saccharin (Manufacturing Only)
Safrole
Sec-Butyl Alcohol
Selenium
Selenium Compounds
Silver
Silver Compounds
Styrene
Siyrene Oxide
SulfuricAcid
Ten-Butyl Alcohol
X Tetrachkxoethylene
Tetractitorvmphos
Thallium
Thallium Compounds
Thiourea
Thonum Dioxide
Titanium Tetrachlonde
X Toluene
X Toluene-2.4-Diisocyanate
Toluene-2.6-Oiisocyanate
CasNo
000095487
000095534
000095476
000104949
000120718
000106445
000156105
000106503
000106423
000056382
000087865
000079210
000108952
000075445
007664382
007723140
000085449
000088891
001336363
000123386
000114261
000115071
000075569
000075558
000110861
000091225
000106514
000082688
000081072
000094597
000078922
007782492
007440224
000100425
000096093
007664939
000075650
000127184
000961115
007440280
000062566
001314201
007550450
000108883
000584849
000091087
E mined To Ar
(*»»r)
39.146
7.442
1.904,571
15
2690
239.004
24
768
4,752672
613
23.206
5,832
7,641.485
4.853
1 .602.644
24.223
687.470
2
5
988.986
270
21.499.910
1 .359,996
612
112490
27,690
1,602
271
326
5
681 179
2.059
30.612
12.346
11.209
31 630.955
2.423
23553119
1.567016
21 .624.949
754
750
255
2.865
860
54.360
233.183.332
57,312
25.446
Emitted To All
M«tia(ltyyr|
39,437
7,944
1.908.954
15
2.940
245.801
24
768
4,754,716
633
26.974
5.950
1 1 .847 862
4.898
74 529.921
28.628
696.677
2
5
991,871
275
21,501.005
1.554.661
612
634.306
27.905
1,607
271
326
5
687029
173,352
156.818
13,111
32.923
31.860558
2.423
1 40.532.037
2.858.122
21 .658 469
754
755
510
8.246
860
54.360
235.140.891
57,317
25.456
B-22
-------
Table B-U (Continued)
Ail Chemicals Reported — 1990
Ozona
Can; Depl
X
X
X
X
HAP
X
X
X
X
X
X
X
X
3360 HR/ER Chemeal
Tnchlorton
X Tnchloroeihylene
Tnfluralm
Urethane
Vanadium (Fume Or Dust)
Vinyl Acetate
Vinyl Bromide
X Vinyl Chloride
X Vinybdene Chloride
X Xylene (Mixed Isomers)
Zinc (Fume Or Oust)
Zinc Compounds
Zineb
Emitted To Air
CasNo
000053686
000079016
001582098
000051796
007440622
000108054
000593602
000075014
000075354
001330207
007440666
012122677
Ernttod To All
-------
B-24
-------
Appendix C
Data from Basic Data Set -
-------
TABLE C-1
Regional Hot Spots
-1989EPA REGIONS-
EPA
Rant Region
1 4
2 5
3 6
4 3
5 8 •
Foul Ration %
Emissions Of loni
(lay) IW Emissions Ran<
665.365.019 2659 1
2
3
4
5
6
7
8
9
10
555,506,402 222 1
2
3
4
5
6
7
8
9
10
389.086.008 1555 1
2
3
4
5
6
7
8
9
10
219.298.500 876 t
2
3
4
5
6
7
8
9
10
151.593.721 606 1
2
3
4
5
6
7
8
9
10
Chcmcii
Melhanol
Carbon Disullide
Acelone
Toluene
Ammonia
Methyl Elnyl Kelone
1.1.1-Trldiloroelriane
xylene (Mixed isomers)
Oicrnoromelhane
Hydrochloric Acid
Toluene
Xytene(Mlxedlsomers)
1.1.1-Trichloroethane
Melhyl Ethyl Kelone
Acetone
Dichloromelhane
Ammonia
Melhanol
GlyoU Ethers
Tncnloroelhylene
Ammonia
Elhytene
Melhanol
Toluene
Acetone
Propytene
Xylene (Mixed Isomers)
Melhyl Elhyl Kelone
1.1.1-Trichloroelhane
Carton Disullide
Toluene
Acetone
Melnanol
1.1.1-Trictilonxltiane
Xylene (Mixed isomers)
Methyl Ethyl Kelone
Hydrochloric Add
Olchlorofnethane
Ammonia
Benzene
Chlorine
Hydrofluoric Acid
0.1,1-Tridiloroelhane
Fmn 113
Toluene
Oichloromelhane
Xylene (Mixed Isomers)
SuNuricAcid
Melhanol
loin
Emissions
in*')
92.713.166
77.454,753
76.823.859
7a978.725
55.357.443
30,464.571
30,360.462
30.163.529
25.624.551
22.116.694
78,969,391
56.742.864
49.743.043
49.493.642
44,299,458
40691,686
25,430,361
24,905.011
18.475.774
16,875.293
103.147.311
29.996.571
24,720.071
21.383,469
17,956.581
16.657,308
16.472.900
12.284.107
10.404,562
. 9.936.390
30.144.521
25.747.215
24.592.640
14.110.644
13.690.686
1Z801.664
10.081.995
9.981.965
9.533,106
5,267,516
110,350.583
10.497,432
5.502.853
Z 838,295
i 460,718
1,990,670
1.967.858
1.951.703
1.266,165
Ammonium Wlrale (Solution) 1.183000
lutai Region \
EPA Emissions 01 loal
Ram Region (Iwyr) IRIEmiaons Rim
6 7 141.290.321 565 1
2
3
4
5
6
7
8
9
10
7 2 127.884,290 511 1
2
3
4
5
6
7
8
9
10
8 9 99.370,754 397 1
2
3
4
5
6
7
8
9
10
9 1 79.396.378 317 1
2
3
4
5
6
7
B
9
10
10 10 73.201.682 293 1
2
3
4
5
6
7
8
9
10
CtiefniQi
Toluene
Ammonia
Xylene (Mixed Isomers)
1.1.1-Tnchloraelhane
Melhyl Elhyl Ketone
Melhanol
Oichloromelhane
Acelone
Tnchloroethytene
Elhylene
Toluene
Dichloromelnane
Acelone
Methanol
1,1,1-Tnchloroelriane
Hydrochloric Aod
Freonll3
Xylene (Mixed Isomers]
Melhyl Elhyl Kelone
Tnchloroethylene
1,1.1-Trlchloroelhane
Ammonia
Freon.113
Dichloromelhane
Acelone
Melhanol
Toluene
Telrachloroelhylene
Melhyl Elhyl Kelone
Xylene (Mixed isomers)
1,1,1-Trtcnioroeihane
Toluene
Fn»nil3
Dlchiorometnane
Melhanol
Methyl Elhyl Ketone
Acelone
SulluncAdd
Trtchioroelhylene
Telrachloroelhylene
Ammonia
Melnanol
Acelone
Toluene
Chloroform
Melhyl Elhyl Ketone
1,1.1-Tnchloroelhane
Freon113
xylene (Mixed Isomers)
Dlchloromeinane
roai
Emss.nns
(in/vn
21.580917
19.912446
17.555.472
9.000576
8.787.355
8.297.929
6.306.971
6.115.461
4.466.012
3.828.253
17.206.599
16.735.457
13.549.732
12.202.933
8.839.810
7.408349
6.497.384
5.932.496
5.159512
3.929.547
25.250.165
9.320.576
8.723.810
7.238.779
7.039.260
5.508.366
4.641.822
4.304.824
3.706.867
3.047,879
17.116.782
9,447.945
6,834.855
6.184.517
5,236,498
4.591.212
4,122.568
3.051.210
2.955.770
2,450,045
24.603.998
6.954.109
5.811.570
5,146.812
3,874.240
3.146,508
2.416.588
2,400.951
2.271.908
1,737,291
C-1
-------
Stale
AK
AL
AR
AS
AZ
CA
CO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Cherneal
Ammonia
Hydrochloric Acid
Methanol
Chloroform
Suifunc Acid
Xylene (Mixed Isomers)
Toluene
Benzene
Acetone
Cyclohexane
Carbon Disulflde
Methanol
Methyl Ethyl Ketone
Toluene
Xylene (Mixed Isomers)
Hydrochlonc Acid
1,1, 1-Tnchloroe thane
Chlorine
Chloroform
Ammonia
Ammonia
Toluene
Xylene (Mixed Isomers)
Memanoi
Acetone
Methyl Ethyl Ketone
Carbon Disulflde
Freon 113
Dichloromethane
1.1.1-Tnchloroethane
Ammonia
Acetone
Freon 1 13
1,1, 1-Tnchloroe thane
Methanol
Toluene
Copper Compounds
Methyl Ethyl Ketone
Ammonia
Dichloromethane
Xylene (Mixed Isomers)
1.1.1-Trichioroetnane
Ammonia
Dichloromethane
Freon 113
Methanol
Acetone
Tetrachloroethylene
Toluene
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
1.1.1-Thchloroemane
Freon 113
n-Butyl Alcohol
Memanoi
Glycol Ethers
Toluene
Acetone
Dichloromethane
Ammonium Nitrate (Solution)
Tetracnloroethylene
Total
Eminent
No Of
(Ib/yO E mitten
18.309,250
553,500
334,856
194,161
179,000
31.708
29.966
29,105
22.510
17,636
45,472,676
8,157,907
7,489.611
5.510,732
5,341,671
4.383.445
3,072.711
3,033.375
2.817.618
2. 103.561
12.714,275
4.345,873
3.598,735
3.533.410
3,450.257
2.933.286
1,930.406
1.784.616
1,773,896
1,771,035
27,750
2.479.940
2,022.441
2,016.507
931.506
656.199
628.416
432,677
424,249
423.408
333.145
23,181.664
8.836.677
6,772,370
6,683,733
4,576.360
4.451.837
3,984,562
3.600.153
3.221.456
2.660.034
1,590.471
1,352.654
857.572
836.591
682.993
667,203
538,000
503,020
441.000
409.379
4
2
3
2
1
3
3
3
1
3
3
50
41
79
83
55
48
40
10
73
67
83
71
35
45
47
3
18
28
43
2
28
47
51
15
19
9
21
25
15
15
502
232
123
192
118
241
93
202
188
187
31
34
6
12
8
21
21
14
3
6
TABLE C-2
State Emissions
— 1989 —
not
Slan
Total
9281
281
1 70
098
091
016
015
015
011
009
4326
776
712
524
508
417
292
289
268
200
2931
1002
830
815
795
676
445
411
409
408
100
1906
1555
1550
716
504
483
333
326
325
256
2728
1040
797
787
539
524
469
424
379
313
1497
1273
807
787
643
628
506
473
415
385
Slat! Hank
CT 1
2
3
4
5
6
7
8
9
to
OE 1
2
3
4
5
6
7
8
9
10
FL 1
2
3
4
5
6
7
8
9
10
GA 1
2
3
4
S
6
7
8
9
10
HI 1
2
3
4
5
6
7
8
9
10
IA 1
2
3
4
5
6
7
8
9
10
Chemical
1,1,1-Tnchioroe mane
Oichioromethane
Freon 113
Tetrachloroethylene
Toluene
Methyl Ethyl Ketone
Memanoi
Ammonia
Acetone
Chloroethane
Xylene (Mixed Isomers)
Hydrochlonc Acid
Carbonyl Suifide
Tnchloroethyiene
Toluene
Methyl Isobutyl Ketone
Methyl Ethyl Ketone
Acetone
Methanol
Vinyl Chloride
Ammonia
Methanol
Acetone
Toluene
Freon 113
Slyrene
Oichioromethane
1,1, 1-Tnchloroe thane
Suifunc Acid
Cyclohexane
Methanol
Acetone
Toluene
Hydrochlonc Acid
Ammonia
Xylene (Mixed Isomers)
1,1, 1-Tnchloroe thane
Dichloromethane
Methyl Isobutyl Ketone
Methyl Ethyl Ketone
Propylene
Toluene
Glycol Ethers
n-8utyl Alcohol
Benzene
m-Xylene
Dichloromethane
1,1,1-Tnchloroethane
Cyclohexane
o-Xylene
Ammonia
Toluene
Xylene (Mixed Isomers)
1,1. 1-Tnchloroe thane
Methyl Ethyl Ketone
Methanol
Acetone
Tetracnloroethylene
Ethyiene
Glycol Ethers
Total
Emowoni
No 01
(Ifoyi Emnere
8,310.458
2.299,686
1.858.766
1.516.313
1,139.226
955.879
882.590
479,211
417,522
373914
1,840,473
819,603
680.000
462000
413.696
385.810
378.242
352.393
227.537
170,680
21.249,340
7,559,658
6,226,371
2.648.812
2.307.774
2.281,385
2,213.687
2.145,843
1.599.811
1,332.668
23.974.226
7.173.974
S.77S.133
5,254,856
3,974,259
3,913.583
3,549,286
3.290.640
2.550.916
2.318.834
124,700
90.000
68.638
59.774
47,100
45,430
41.701
41.694
35.800
26.500
9.841.037
7.730.072
4.017.718
3,289.656
2.817.187
2.764,894
2.488,728
1,414,012
1.306.000
1.075.431
155
51
48
29
42
42
28
47
25
2
6
16
1
1
13
2
9
10
14
2
72
39
106
53
58
78
34
76
61
2
85
73
104
60
96
115
85
53
28
56
2
2
1
1
2
2
1
1
2
2
59
70
87
60
29
23
35
13
1
25
%0t
Stile
Total
3914
1083
875
714
536
450
416
226
197
1 76
2469
11
912
620
555
518
508
473
305
229
3608
1283
1057
450
392
387
376
364
272
226
3125
935
753
685
518
510
463
429
333
302
1820
1313
1002
872
687
663
609
608
522
387
2240
1760
915
749
641
629
567
322
297
245
C-2
-------
Table C-2 (Continued)
State Emissions —1989
State
ID
IL
IN
KS
KY
LA
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
A
5
6
7
8
9
10
1
2
3
4
5
6
7
a
9
10
i
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
a
9
10
1
2
3
4
S
6
7
8
9
10
Chemcal
Ammonia
Metftanoi
Chloroform
Chlorine Dioxide
Freon113
Acetone
SulfuncAcid
Chlorine
Formaldehyde
Hydrogen Fluoride
Toluene
1.1.1-Trichioroetnane
xyiene (Mixed isomers)
Ammonia
Methyl Ethyl Ketone
Chlorine
Tnchloroettiylene
Carbon Oisulfide
Hydrochloric Acid
Dichlorome'thane
Toluene
Acetone
Dichloromethane
1.1,1-Tnchloroethane
Xyiene (Mixed isomers)
Tnchloroettiylene
Methyl Ethyl Ketone
Methanol
Ammonia
Benzene
Ammonia
Tricnioroethylene
Toluene
Xyiene (Mixed Isomers)
Ethylene
Methyl Ethyl Ketone
Propyiene
Methanol
Tetrachloroethylene
Carbon Oisulfide
Toluene
Xyiene (Mixed Isomers)
Methanol
Ethylene
Acetone
1,1.1-Trlchloroethane
Hydrochloric Acid
Glycoi Ethers
Dichloromethane
Methyl Ethyl Ketone
Ammonia
Methanol
Carbon Oisulflde
Ethylene
Toluene
Styrene
Propyiene
Xyiene (Mixed Isomers)
Hydrochloric Aad
Benzene
Tottl
EiraiaiB No 01
(It/yr) Emitter!
1.821, 752
739.677
640,500
540,250
391.049
263.358
227,989
152.503
118,936
91.210
16,371,789
10.434.828
6.689,773
6,359,266
5.356.468
4,693.355
4.430.619
4.334.374
4.322.950
4,134.132
16.167.532
14.298.129
13,236.206
10.685,842
9.473.480
6,354,134
6.298.371
3.989.505
2.833.520
2.617.343
4.763.963
2.787.475
2.770.333
2,544,679
2,523,253
2.451.527
2.283.558
1.505.580
1.359.325
1.277.205
8.979.794
5,115,714
4.944.187
2.739.867
2,351,619
2.118.814
1.894,502
1.504.874
1.497,892
1.220.360
67.955.654
7.851.584
5.894.610
5,642,601
4.392.145
3,858.522
3.594,881
2.557.382
2.098.543
1.820.799
19
6
2
1
4
7
11
9
7
4
230
238
214
132
153
52
104
5
173
98
192
123
78
148
198
61
112
86
69
16
41
14
56
49
5
31
5
23
9
2
74
77
31
5
44
47
38
28
21
39
68
71
9
38
71
17
32
65
63
38
%0f
Sun
Total
3415
1386
1201
1013
733
494
427
286
223
171
1621
1033
662
630
530
465
439
429
428
409
1449
1282
1186
958
849
570
565
358
254
235
1464
857
851
782
776
754
702
463
418
393
2010
1145
1107
613
526
474
424
337
335
273
5235
605
454
435
338
297
277
197
162
140
Sine
MA
MO
ME
Ml
MN
MO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10 '
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Toluene
1.1,1-Tncnioroethane
Freon1l3
Dichloromethane
Methyl Ethyl Ketone
Tnchloroettiylene
Methanol
Acetone
Xyiene (Mixed Isomers)
Ammonia
Methanol
Toluene
1,1,1-Tnchioroettiane
Hydrochlonc Acid
Ammonia
Chlorine
Methyl Ethyl Ketone
Xyiene (Mixed Isomers)
Oichloromethane
1 SulfuncAcid
Sullunc Acid
Methanol
1,1,1-Tnchloroettiane
Chlorine
Acetone
Chloroform
Glycoi Ethers
Toluene
Chlorine Dioxide
Xyiene (Mixed Isomers)
Xyiene (Mixed Isomers)
Oichloromethane
Toluene
Acetone
Methyl Ethyl Ketone
1,1,1-Tnchloroetnane
Methanol
Glycoi Ethers •
n-Butyl Alcohol
Methyl Isobutyl Ketone
Methyl Ethyl Ketone
Toluene
Xyiene (Mixed Isomers)
1,1,1-Tnchloroethane
Methanol
Freon113
Dicniorometnane
Acetone
Glycoi Ethers
Cyclohexane
Xyiene (Mixed Isomers)
Toluene
Methanol
1,1,1-Tnchloroethane
Oichloromethane
Methyl Ethyl Ketone
n-Butyl Alcohol
Acetone
Glycoi Ethers
Ammonia
Total
Emame No 01
(lo/yi) Enutan
4.458.891
4,035.792
3,034.100
2.030.674
1.947.809
1.851.429
1.415,806
1.293,599
656.263
427.747
2.833.558
2,215.315
2.091.024
1.675.580
1.642.830
866.230
830.726
774.682
736.865
602.785
2.691,789
2.604,312
1.699.604
1.313,798
1.114.494
1.106.426
1.047,608
574.827
537.049
418.986
17.069.038
15.754.245
12.820.356
10,276,277
7,229.357
5.964.731
5.093.282
3.923.7SS
3.310.887
2.880.395
18.126.913
15,397.747
5,482,908
2.750,250
2.664.499
2.660,829
2.425.221
2,242.932
1.084,991
873.823
9.367.330
5.588.523
3.823.796
3,545,510
3.424,717
2,970,507
2.443.508
2.191.125
1.965.746
1.887,895
104
149
81
56
64
46
68
72
60
72
17
36
36
26
33
11
23
30
10
30
19
13
27
15
23
7
5
16
7
16
170
59
209
145
133
149
100
95
74
78
39
75
68
76
32
53
40
63
26
6
115
128
58
98
59
79
45
76
55
61
not
Sute
Total
1818
1645
1237
828
794
755
577
527
268
174
1556
1217
1148
920
902
476
456
425
405
331
1768
1710
11 16
863
732
727
688
377
353
275
1638
1512
1230
986
694
572
489
377
318
276
2903
2466
878
440
427
426
388
359
174
140
1949
1163
796
738
713
618
508
456
409
393
C-3
-------
Table C-2 (Continued)
State Emissions —1989
Slate
MS
MT
NC
NO
NE
NH
flank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
I
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
Clwneal
Ammonia
Toluene
Cartjonyl Sulfide
Xytene (Mixed isomers)
Methyl Etnyl Kttone
DKhlorometlune
Methanol
Tnchloroetnylene
Acetone
1,1,1-Trichloroethane
Hydrogen Fluoride
Xylene (Mixed Isomers)
Propyline
Formaldehyde
Toluene
Methanol
Ammonia
Ethyiene
Lead Compounds
Chloroform
Methanol
Toluene
Dichloroniethane
Methyl Ethyl Ketone
Acelone
1,1,1-Tnchloraethane
Ammonia
HydrochloncAcid
Xylene (Mixed Isomers)
n-Butyl Alcohol
Xylene (Mixed Isomers)
Acelone
Toluene
Freon113
Methyl Isobutyl Ketone
1.1.1-Tnchioroetnane
Styrene
Propylene
Methyl Ethyl Ketone
1,2,4-Trimelhyl benzene
Toluene
Ammonia
Xylene (Mixed Isomers)
DKhioromethane
t,1,l-Trlchloroethane
Freon113
Methyl ElhylKMoiw
Acetone
Ammonium Nitrate (Solution)
Methyl Isobulyl Ketone
Toluene
1.1.1-Trichloroethane
Oichloromelhafte
FreoniU
Methyl Ethyl Ketone
Ctilonne
Chlonne Dioxide
Xylene (Mixed Isomers)
Tnchloroelhylene
Acetone
ToUl
EmnuiiB No Of
-------
Table C-2 (Continued)
State Emissions —1989
SHU
OR
PA
PR
Rl
SC
SO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
ChemEil
Methanol
Acetone
Toluene
Ammonia
Methyl Ethyl Ketone
Formaldehyde
Tnchloroetnylene
1.1.1-Tnchloroethane
Freon1l3
Xylene (Mixed Isomers)
Toluene
1.1.1-Tnchloroettune
Oichloromethane
Ammonia
Methyl Ethyl atom
Xylene (Mixed Isomers)
Acetone
Benzene
Tnchloroethylera
Methanol
Dicnioromethane
Acetone
Freon113
Carbon Disuifide
Toluene
Methanol
1,1,1-Trichloroethane
Ethylene Oxide
Formaldehyde
Cydohexana
1,1,1-Trlchloroethane
Toluene
Acetone
Freonii3
Oichlorornethane
Tnchloroethylene
Methyl Ethyl Ketone
Tetrachloroethylene
Xylene (Mixed Isomers)
Ammonia
Methanol
Toluene
Acetone
1,1,1-Tnchloroe thane
Methyl Ethyl Ketone
Ammonia
Xylene (Mixed Isomers)
Hydrochloric Add
Oichloromethane
FreonH3
Freon113
Xylene (Mixed Isomers)
Toluane
Cyclohexam
1.1.1-Tnchloroethane
Methyl Ethyl Ketone
Methanol
Formaldehyde
Methyl isobutyi Ketone
Acetone
Totil
Emitter* No Of
(Ib/yr) Ermrtert
3.883.2S5
3,029.330
2,451 .645
1.129.122
980.704
900,513
802.624
791.696
780,681
701.615
15.405.083
8.742.064
5,823,392
5,036,396
4.925310
4.482,443
3.316.487
2.890.061
2,880.260
2,594,968
3.903,597
2.503,112
1.412,034
1.101.000
1,087.634
691,357
447,970
239,992
238,558
207,717
1.164,015
1.092,318
988,054
465,366
431,696
427,553
409,710
395.016
222,696
167,336
14,638,298
10.112.517
9.052,446
5.391,553
4.689,500
2.756,317
2.740,253
2.480,324
2.119,482
1.676.234
662,995
631,047
626,215
454,623
151,922
119,416
115,669
89,200
84,165
81,562
32
46
40
39
26
29
14
26
17
32
213
186
69
130
124
203
128
22
59
120
23
29
31
1
24
28
26
7
3
4
47
19
22
22
14
22
16
13
16
24
76
67
S3
75
46
63
64
47
31
22
5
13
5
1
7
6
3
1
2
4
%OI
Slltt
Total
1968
1536
1243
572
497
456
407
401
396
356
1919
1089
726
628
614
559
413
360
359
323
2869
1840
1038
809
799
508
329
176
175
153
1865
1750
1583
746
692
685
656
633-
357
268
2057
1421
1272
758
659
387
385
349
298
236
2071
1971
1956
1420
474
373
361
279
263
255
Slate
TN
TX
UT
VA
VI
VT
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Clwnical
Acetone
Carton Oisulfide
Toluene
Methanol
Carbonyl Sulflde
1,1.1-Tnchloroetnane
Ammonia
Xylene (Mixed Isomers)
Dichloromethane
Hydrochloric Acid
Ethylene
Acetone
Propylene
Ammonia
Methanol
Toluene
Xylene (Mixed Isomers)
Cyclohexane
Methyl Ethyl Ketone
1.1,1-Tnchloroethane
Chlorine
Hydrochloric Acid
1,1,1-Tnchloroe thane
Oichlorornethane
SulfuncAcid
Freon113
Toluene
Ammonia
Xylene (Mixed Isomers)
Acetone
Acetone
Methanol
Toluene
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
HydrochloncAcid
1.1.1-Tnchloroethane
Oichlorornethane
Methyl isobutyi Ketone
Ammonia
Benzene
Toluene
p-Xylene
Xylene (Mixed Isomers)
Ethylbenzene
Cyclohexane
1 ,2.4-Tnmethylbenzene
Naphthalene
Anthracene
Carbon Tetrachlonde
1.1.1-Tnchloroethane
Toluene
Xylene (Mixed Isomers)
Methyl Isobutyi Ketone
Methanol
Methyl Ethyl Ketone
Freon113
SulfuncAcid
Acetone
Formaldehyde
Tout
Emaiont
(Ib/yr)
42.032,395
31.979,416
14.248,159
13,936,641
7.800.000
6.651.855
5.785.655
4.309.215
3.479.685
2.420.381
24.098.669
12.990.322
12.838.341
11.952.096
10.003.643
9.888.118
8.627.712
7.654,543
6.662.826
6.216.319
110.230.301
10.441.697
3.647.423
1.487.650
888.054
717.897
528.080
341.655
323.252
286,535
16.537,804
16.092.437
9.858,501
6.139.525
5.530.010
3.792.461
2.649.476
1.738.139
1.502.767
1.499,921
329,000
280.000
234.000
207,000
59.000
28.700
11,490
2,880
2.502
1.700
304.239
259,148
118.440
73.652
68.180
57.080
55,897
40,476
37.707
31,077
No 01
.mnai
88
S
120
66
1
89
55
106
42
48
87
160
85
210
192
247
249
58
122
171
12
19
23
7
20
17
19
15
20
18
90
80
117
77
91
38
73
36
31
61
13
9
7
4
4
4
3
11
2
2
%01
SUK
TOUI
2713
2064
920
899
503
429
373
278
225
156
1313
708
700
651
545
539
470
417
363
339
8460
801
280
1 14
068
055
041
026
025
022
2074
2018
1237
770
694
476
332
218
188
188
2838
2415
2018
1785
509
248
099
025
022
015
2634
2244
1026
638
590
494
484
350
326
269
C-5
-------
Table C-2 (Continued)
State Emissions'—1989
Slate
WA
Wl
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemeal
Ammonia
Toluene
Acetone
Chloroform
Methyl Ethyl Ketone
Mettunol
1,1,1-Tnchloroethane
Xylene (Mixed Isomers)
• Dichloromeftane
Hydrogen Fluoride
1,1,1-Tncnloroethane
Toluene
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Glycol Ethers
Mer^ano!
Aceisne
Dichloromediane
HydrochloncAcid
Freon113
Ton)
Emmons
(HXVO
3.343.874
2.664.951
2.496.372
2.372.430
2.165.804
1.996.321
1.538.922
1.527,335
1.238.481
1.233.572
5.816.410
5.284.114
4.491.643
3.209.013
2,869.410
2.465.381
1.851.206
1,574.733
1.427.455
1.345.541
No Of
Emitton
S3
52
66
12
43
31
39
47
21
13
-154
122
117
92
70
60
66
51
73
32
%OI
Slate
Total
1177
938
879
835
762
703
542
538
436
434
14
1272
1081
772
691
593
446
379
344
324
State Rank
WV 1
2
3
4
5
6
7
8
9
10
WY 1
2
3
4
5
6
7
8
9
10
Totll
Emmora No 01
Chemical (ll/yr) Emitter*
Acetone
Methanol
Toluene
Benzene
Dichloromethane
Acrylonitnle
Ethylene Glycol
Hydrochlonc Acid
Ammonia
Styrene
Sulfunc Acid
Ammonium Nitrate (Solution)
Ammonia
Toluene
Xylene (Mixed Isomers)
Glycol Ethers
n-Butyl Alcohol
Methyl Tert-Butyl Ether
Propylene
Benzene
5.278.423
2.844.140
2.251.926
1.662.419
1.521,218
1.449.451
1.294.916
1.260,040
1.231,087
1,115,888
944.763
742.000
387,479
292,785
213,167
179,000
151,000
138,050
111,114
78,665
17
20
23
6
9
4
12
24
24
13
7
1
5
5
7
2
1
2
4
4
soi
Slate
Total
1568
845
669
494
4 52
431
385
374
366
332
2582
2028
1059
800
583
489
413
377
304
215
C-6
-------
TABLE C-3
Regional Hot Spots
- 19893-DIGITZIP CODES-
3Dcu
ZIPCoce
840
775
376
703
365
377
5S3
481
776
707
286
146
371
996
356
606
391
241
314
706
465
284
480
723
244
402
473
381
338
440
6
463
630
490
315
479
430
700
295
294
551
756
476
441
388
604
395
601
420
494
Sas
UT
TX
TN
LA
AL
TN
MN
Ml
TX
LA
NC
NY
TN
AK
AL
IL
MS
VA
GA
LA
IN
NC
Ml
AR
VA
KY
IN
TN
FL
OH
PR
IN
MO
Ml
GA
IN
OH
LA
SC
SC
MN
TX
IN
OH
MS
IL
MS
IL
KY
Ml
No Of
Raose
Rewra
151
1,193
166
76
166
78
162
426
246
338
476
210
148
18
203
923
45
US
84
222
335
105
328
89
53
336
198
241
129
474
260
322
253
288
102
156
181
355
134
134
217
182
50
627
37
438
190
472
150
311
NO Of
35
133
32
16
23
35
59
112
30
41
143
54
42
3
48
294
21
32
23
28
118
24
101
27
20
70
61
63
50
1 43
94
69
64
95
24
38
48
49
41
34
72
41
8
185
40
104
24
160
26
87
HAP
E-nsions
123499.332
33834.153
18844269
710.280
48.742.819
28.733.800
27.664355
21.564.884
9.782,964
12.391,681
17.024.781
15.052668
16.138146
274365
15,587.429
13.952.172
3,933.733
4,060,002
14050.378
6.273.448
13.067.141
14.348.187
13.157.202
3523.060
12.518.320
12.097.765
9.666,107
5.956.825
917.884
10.679.947
8.139.016
10.299.993
9.503,760
9339.777
9.219,505
7809.097
7,677.373
5,347223
8,218.572
8.829.162
8.044.051
4.553.485
8,987,089
8219,319
9.474,791
7.242.479
7,984.807
7.880285
5.892.935
6.755.885
lom ZIPS
Erasscrs 01 Tom IRI
(IJ/Y'I EmiB.ors
124 926.334
67.514934
57.433650
53769.804
49,583.284
29040.910
28586651
25.582.330
a.726.475
20,282437
20.118.360
19.979,701
18,667,116
18,604,215
18566,446
18,489,386
18397,399
17,057,985
16,612517
16,477,335
16.011799
15.718.980
15.197 783
14.907.032
13.529729
13402.913
13.354082
13,207808
13.193.145
11948.667
11 773975
11686.210
11,537.573
11,401.143
11.385406
11.139502
10.988.303
10.817.470
10,758,335
10,641,714
10,557.276
10.332.598
10.239,282
10.149258
10.083.136
9.814660
9.769310
9765667
9.741 603
9.464.211
499
270
230
215
198
116
1 14
102
095
031
030
080
075
074
074
074
074
068
066
066
064
063
061
060
054
054
053
053
053
048
047
047
046
046
046
045
044
043
043
043
042
041
041
041
040
039
039
039
039
038
ZIPCoce
452
458
261
296
770
672
70
397
457
605
278
619
232
902
299
550
456
272
317
495
945
342
712
708
292
740
ISO
527
297
260
777
251
763
370
673
238
467
631
293
226
610
532
852
245
64
215
281
374
287
191
Sa-e
OH
OH
WV
SC
TX
KS
NJ
MS
OH
IL
NC
IL
VA
CA
SC
MN
OH
NC
GA
Ml
CA
FL
LA
LA
SC
OK
PA
IA
SC
WV
TX
WV
TX
TN
KS
VA
IN
MO
SC
VA
IL
Wl
AZ
VA
CT
MD
NC
TN
NC
PA
No Of
HC'QSB
Rears
421
225
124
340
484
164
690
68
74
180
156
53
135
432
29
162
101
309
102
265
405
30
71
136
78
118
228
111
122
118
146
68
21
162
48
107
209
475
202
68
130
405
197
178
302
16
234
123
125
264
No 01
121
54
14
117
125
35
209
25
13
55
59
16
46
128
4
33
25
99
37
67
106
18
20
20
20
32
50
31
30
28
19
5
4
S3
12
31
86
133
51
18
44
112
66
57
99
4
66
33
40
66
HAP
EIISS.OHS
7237749
5063214
7635272
7,750,031
5,721 125
8479911
6566,095
7,971,043
4041,971
7,151,592
4014.181
7.356.83S
7,378,647
6275,302
6241,520
6.921356
4.293.137
6861.209
6120.432
6.379.122
4056.215
798.364
6792.625
4.706.483
6.956.527
4.045.119
3,134.105
3,134,438
3.396.155
5830317
2963122
2.122550
5,172078
5829863
1369605
4.844069
5300.251
5735622
5.375880
5837,103
5.350.749
4.536.892
£571.184
5,707485
5.208.933
5 183.728
5,527.722
5829,241
5,053.399
4.463.324
Tan ZIP v
E-iss,om oi loin mi
(I3AO E~i»iOrs
9,381114
9,300.559
9,261.171
9225332
9.178,320
9137579
8.927,004
8.81 1 871
8,797699
8,743,697
8.707845
8627372
8,393176
8.365,680
8.319520
8.297.600
8133.753
8,113259
8062.363
7947.211
7935.782
7.893.699
7.866097
7.643751
7.522405
7.451.540
7.387.951
7.346015
7.327.046
7.284,755
7.074.297
6.908,079
6807,115
6.794.212
6728491
6719.908
6670.378
6610.252
6434.070
6,339,373
6.326,209
6,266,003
6,260,904
6.205529
6202.987
6.146,443
6,131.053
6.097.178
6.072.304
6.040273
037
037
037
037
037
037
036
035
035
035
035
034
034
033
033
033
033
032
032
032
032
032
031
031
030
030
030
029
029
029
028
028
027
027
027
027
027
026
026
025
025
025
025
025
025
025
025
024
024
024
22.074 5.822 953,809593 1.394.163.565 5572
C-7
-------
TABLE C-4
Regional Hot Spots
— 1989 COUNTIES-
COLT.'Y
Tooele
Ascension
Mobile
Harris
Sullivan
Cook
Los Angeles
Hamblen
McLeod
Monroe
Kenai Peninsula
Brazona
Jelterson
Chatham
Calcasieu
Wayne
Mississippi
Washienaw
Shelby
Jellerson
Yazoo
Galveslon
Polk
Giles
Colbeit
Orange
Cuyahoga
Kanawha
Calawoa
Oakland
Ramsey
Lake
Alleghany
Hamillon
SI LOUIS
Orange
Sodgwick
Humphreys
Washington
Easl Baton Rouge
Kenl
Macomb
Hampton
Harrison
Middlesex
Kaiamazoo
King
Niagara
Marshall
Posey
SBK
UT
LA
AL
TX
TN
IL
CA
TN
MN
NY
AK
TX
TX
GA
LA
Ml
AR
Ml
TN
KY
MS
TX
FL
VA
AL
TX
OH
wv
NC
Ml
MN
IN
VA
OH
MO
CA
KS
TN
OH
LA
Ml
Ml
SC
TX
NJ
Ml
WA
NY
KY
IN
No 01
Re ease
Recois
9
148
163
1301
109
1751
1967
69
30
248
18
33
301
64
194
600
48
65
266
337
2
194
116
8
59
77
632
129
157
242
195
214
16
461
315
560
168
18
74
156
300
187
17
86
518
96
316
159
87
33
No 01
FaOllilH
5
17
30
237
14
552
632
21
6
66
3
22
35
23
21
143
15
19
72
71
1
16
45
1
14
12
186
10
55
62
60
40
3
128
64
208
37
4
13
22
75
46
3
14
127
22
118
35
8
2
HAP
Ensions
(larf)
119265478
4568,353
49.433531
28.918.090
6966709
31.057015
26940242
26.448.675
25496.692
15.494023
274.365
8.192.620
8.422442
14,050.378
5.593.804
11.421,941
3.080.502
12.934,557
6.192.969
12.097.905
3.800
3.356,714
706,597
982204
9.701 843
2.929.244
6,320.820
4,776,482
9,403.019
7,622.942
7.786.738
8 709.422
9.441.999
7.666,729
8.045.074
5.715,742
6480661
8.476,847
4.041,971
5,710939
6,744,559
7.592.963
6,234,220
3.210.129
6,809.034
6735.806
6.307.642
7.081,868
4,886,504
6,601,329
Imai Cot.-* \
E.TISSKIS 01 loui 1RI
(Ityr) Emssiors
119265728
62477.679
50399.718
46.891805
43,146,461
39.033.046
35.440773
26.714640
25.782.081
20.558.791
18.604,215
18,572.338
18,038.473
16.612.517
15.664,609
14,782.936
14.458.523
14.197.992
13.537.600
13.403.053
12947.936
12.761.642
12701,712
12.423.113
12 184.818
10566.299
10,297,759
10,261,485
10,254.552
10,178.002
10.176555
10.117944
10042999
9,968201
9.564447
9.365.347
9138.829
9011.514
8797699
8.771,344
8.433.812
8.298.691
8.292720
6.2S5.818
8.244.549
8.220.275
8200,376
7,980.475
7,800.172
7.791.732
477
250
201
187
172
156
142
107
103
082
074
074
072
066
063
059
058
057
054
054
052
051
051
050
049
042
041
041
041
041
041
040
040
040
038
037
037
036
035
035
034
033
033
033
033
033
033
032
031
031
CC.-V
Union
Ricniand
Milwaukee
Allegheny
TiDDecanoe
Brunswick
Erie
Glynn
Manatee
Barceionela
Davidson
New Haven
Lownoes
Middlesex
Brown
iberville
Mancopa
Tarranl
York
Ononnaga
Ouacnila
Elkhan
Monigomery
Kosciusko
Harrison
Dallas
Lancaster
Hamillon
Douglas
Broome
Monigomery
Si Cnaries
Allegany
Frederick
Newcastle
San Diego
Philadelphia
Caldwell
Hawkins
Cosnoclon
Salt Lake
Henry
Spananburg
Marion
Ricnmonc
Forsyth
Carter
Hartlord
Jellerson
Sebastian
Sa.e
OH
SC
Wl
PA
IN
NC
NY
GA
FL
PR
TN
CT
MS
MA
TX
LA
AZ
TX
SC
NY
LA
IN
KS
IN
MS
TX
PA
TN
IL
NY
OH
LA
MO
VA
DE
CA
PA
NC
TN
OH
UT
VA
SC
IN
GA
NC
TN
CT
AL
AR
No 01
Reiax No 01
Renra Fic.iies
40
89
491
371
90
32
244
37
19
47
97
354
43
424
20
107
354
262
58
139
33
189
33
57
30
486
163
123
22
59
198
95
11
34
175
202
253
153
21
24
183
93
170
296
71
84
7
270
264
102
7
24
132
80
19
4
93
8
11
8
31
109
9
145
3
12
128
100
IB
55
3
73
7
16
7
156
65
35
3
22
49
10
3
11
39
73
64
33
6
7
45
21
39
61
29
32
2
104
73
32
HAP
Emissions
(Ifl/V'l
4878463
7,084977
5,266314
4517745
4,620.780
7,369.146
6.160.730
6032.021
491664
5,351.748
6251.659
5900655
6,321.955
5,006,540
5,098.484
4,764.393
3,939.380
4,335523
2795140
3,119666
5,407.555
4.891.258
982.927
5552,296
5954,599
4.969.981
5482.932
5.831.292
5,033.463
4,670,791
4,940.095
1.489726
4.986.428
5465.099
5,253968
4,699,022
4,277,424
4,575,325
3,393.719
599.145
4321.284
5,142.277
4,812.186
4490.731
3865.733
4.857.187
5,422258
4.169.161
4.758.991
4.529.124
lotll Cfljr.-y >fc
Emssior.s 01 Tan IRI
(iD/yr) E-ISS.CPS
7.707057
7669,105
7.583583
7568.335
7545352
7.492.078
7.397,787
7.237069
7.156799
7.115735
7.068.808
6978560
6852.461
6.847208
6.733521
6.526,055
6.443.668
6.417699
6.373.767
6.345,660
6.313.455
6.309.285
6296.560
6,194.419
6.167790
6.145675
6105.130
6099,489
6078,782
6.044184
6,009.005
5969000
5.918,443
5.854,239
5828.035
5.821.069
5,795,504
5.784,815
5.777.768
5.771.437
5,755,023
5,725.145
5,709,704
5.675.075
5609205
5.577.867
5,486.293
5484.715
5.418,849
5,366.696
031
031
030
030
030
030
030
029
029
028
026
028
027
027
027
026
026
026
025
025
025
025
025
025
025
025
024
024
024
024
024
024
024
023
023
023
023
023
023
023
023
023
023
023
022
022
022
022
022
022
20777 5598 835,339.094 1,235.808762 4939
C-8
-------
TABLE C-5
Air Emissions By U.S. Industry
— 1389 —
2 D'gu
SIC Cue
0
1
2
3
7
10
13
14
15
16
17
IB
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
42
43
44
45
46
47
49
SO
51
52
57
73
75
76
84
87
89
96
97
98
99
NA
US Inousiy
Food
Tobacco
Textiles
Apparel
Lumber
Furniture
Pulp & Paper
Printing
Chemicals
Petroleum Refining
Rubber, Plastics
Leather
Stone. Clay. Glass
Primary Metals
Fabricated Metals
Non-Elect Machinery
Electrical Equipment
Transport Equipment
Instruments
Misc. Manufacturing
No 01
Emirers
47
8
1
3
9
2
2
1
7
1
9
15
2
1
1.105
17
371
42
537
536
626
379
3.957
362
1.636
124
563
1,692
2,877
1,060
1.704
1.278
427
390
2
3
2
7
1
2
7
18
40
1
1
21
3
7
2
12
2
1
6
1
4
13
No 01
Re'aue
Rents
95
11
2
9
17
3
2
1
14
1
9
15
2
1
1.654
22
700
89
1,416
1.856
2.070
709
19.717
2.856
3.978
334
1.S37
5.891
7.371
2.587
4.788
4.582
1.010
951
2
It
22
23
1
4'
16
32
160
3
5
31
5
11
8
55
2
32
20
1
19
23
HAP
Emissions
(lo/yi)
657,252
147.698
0
583.518
654,577
47.000
0
0
1.500
250
17.151
39.876
334,268
0
10.937.545
1.070.545
31.852.194
4.150,538
32,281,433
55,216227
224.151,583
55,376,057
421.719,800
44.915,917
161.097.931
10,193.871
19.722,844
217,849.681
111.749,083
49.330,854
70,607,653
178,359.935
36.146,247
.21,865,925
0
238.920
28,960
242,902
8
42100
4,969,886
291.274
377,228
1.250
1.750
74,022
65,710
157,519
62.950
23.880
430
5,750
282.982
1,463
340.519
174,457
Tuai
Emssioru
(IBM
873,169
148.568
500
584.518
918.060
47.100
1.260.463
10,425
10,583
250
41.367
39.876
334.268
28.000
28.598.43S
1.725.798
37.462.074
4,381.856
37.255.402
63.961,987
269.78S.941
58.174.976
793.130.665
73.472.974
200.229.247
13.206.920
26.123.964
262.280.892
144.606.396
62,068.033
104,774.079
225.302.351
54.641.638
27.567.074
1.085
266.420
318,238
253.270
8
48,450
4.987.646
422.772
831.333
1.250
3,250
91.875
65.710
158,019
65.950
230.583
10,763
10.0)0
481.244
1.463
461.834
234.049
Influsiivl
a ran
FBI Enssons
003
001
000
002
004
000
005
000
' 000
000
000
000
001
000
114
007
ISO
018
149
256
1078
233
3170
294
800
053
104
1048
578
248
419
900
218
110
000
001
001
001
000
000
020
002
003
000
000
OX
on
001
000
001
ox
000
002
000
002
001
19.957 64.786 1.768.662,913
2,501.993,075
10000
(Note Only SICs 20-39 are required to report to TRI)
C-9
-------
TABLE C-6
Industrial Emissions
— 1989 —
2-Dign
SCCoce
26
26
33
37
30
34
36
29
25
35
27
38
22
24
20
39
32
31
49
23
21
10
3
SI
2
97
99
No 01
Enmers
3.967
626
1,692
1.278
1,636
2,877
1.704
362
S36
1,060
379
427
371
537
1,105
390
563
124
7
42
17
2
9
47
40
3
6
4
HAP
Ens&ons
291274
334268
28.960
238.920
242902
174,457
23.880
157,519
147,698
74,022
62,950
65,710
42,100
47,000
17,151
39,876
0
430
1,500
5,750
1,750
1.463
1,250
0
0
250
8
loai
EnisiQRs
(16/yr)
422,772
334.268
318,238
266.420
253.270
234.049
230,583
158019
148.588
91.875
65.950
65710
46.450
47,100
41,367
39.876
28.000
10.763
10.583
10.425
10.000
3.250
1.463
1.250
1.085
500
250
8
IrC'.s.-Y*
01 loui IRI
E-T'B.cns
002
001
001
ODI
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
19.957
1.768,662.913
2.501.993.075
10000
C-10
-------
TABLE C-7
Air Emissions For The U.S. Chemical Industry
— 1989 —
loai Ic.ii
missions « Dgil E-.ss.c-
SlcCoct _ (la/yi) SIC CMC _ 03/yl
.
t Dicil Emissions « Dgil E-.ss.c-s 4-Digit Enisions
cCoct _ (la/yi) SIC CMC
2800 2.211.338 2834 29687198 2865 22.820.883
2801 436 2835 17.538 2866 427.727
2810 1700 2836 383061 2869 173,351318
2811 250 2839 94170 2870 1.29S383
2812 24.116.075 2840 16.948 2871 31.916
2813 8.560.794 2841 1,263.711 2873 145,049,237
2815 176,310 2842 597266 2874 26.940.745
2816 17,875.700 2843 5.116054 2875 '2.591,972
2818 9.396 2844 189352 2879 6.791,050
2819 '32,650.892 2846 2.544 2890 12.074
2821 108.733.357 2850 152.969 2891 4.886.707
2822 21,943.488 2851 . 22.317332 2892 5.562.622
2823 53.853875 2852 262.250 2893 2.722.315
2824 19.849,399 2859 265 2895 13.384.043
2830 341.006 2860 260.290 2898 25.300
2831 358,783 2861 4.139.686 269 _ 8.801 ,840
2833 23,143,049 2864 102.051 793130665
C-11
-------
TABLE C-8
Top Industrial Emitters
— 1989 4-Digit SIC Codes —
Rii» SC
1 2869
2 2873
3 3339
4 2821
5 2611
6 3711
loui %OI
Emissions 2 Digit
llb/yr) SCCne Rink
173.35fi.318 2186 1
2
3
4
5
6
7
8
9
10
145,049.237 1829 1
2
3
4
5
6
7
8
9
10
127.008.798 4842 1
2
3
4
5
6
7
8
9
10
108.733.357 1371 1
2
3
4
5
6
7
8
9
10
85.945,112 3186 1
2
3
4
5
6
7
8
9
to
69.171,476 307 1
2
3
4
5
6
7
8
9
10
Cil&RUI
Acetone
Methand
Elhylene
Propylene
Toluene
Chloromelhane
Ammonia
Benzene
Elhylene Glycd
Hydrochloric Add
rum •
Emissions
52.899.672
26,239384
15,800.518
6.465.567
6,148,637
6,125.432
5,404.568
4,621,317
4,484.781
4.060,723
Ammonia 135,517,735
Melhand
Ammonium Nitrate (Solulion)
Propylene
NilncAdd
SuttuncAad
Acetomlnte
Aaylonilnle
QhyleneGlycol
Hydrogen Cyanide
6.431.074
1.774.319
384,400
248,795
157,223
122.000
103.000
94.000
56,400
Chlonne 1 10.179.401
Hydrochloric Add
Ammonia
Methyl Isobulyl Kelone
Lead Compounds
Hydrogen Fluoride
Tebachloroethylene
Zinc Compounds
1,1.1-Tnchloroethane
Melhand
Carbon Oisullide
Elhylene
Melhand
Dichloromethane
Acetone
Propylene
Slyrene
Toluene
ChioroDenzene
Aaylonilnle
Melhand
Chtorotorm
Chlonne
Hydrochloric Add
SurluncAdd
Acetone
Chlonne Dioxide
Armenia
Tduene
Ammonium Sutlale (Solution)
Xylene (Mind Isomers)
Grycoi Ethers
Tduene
n-Buly) Alcohol
Melhyl Isobulyl Kelone
Melhyl Qhyl Kelone
Melhand
Acetone
1.1,1-Tnchkwoethane
Elhyibenzene
9.000,511
4.901.455
1.248.413
623.927
325,797
143.519
100.608
95137
86.806
24.938,053
13.236.940
8.769.900
8.588,147
8,567.946
4.951.442
4.477.751
4.125.466
2.736.248
2.349.201
38.055,599
13.360.095
6,922,362
6,552.248
6.377.345
6.136.405
4822.386
1,367,019
1.169.500
406,000
25,220.040
7.778347
7.141.190
6.683.853
4.973.656
4,279.916
3.704.126
3.450.681
2.8SI.177
1,103,685
1 01 lo-ii
2^'
667
331
199
082
078
077
068
058
057
051
1709
081
022
005
003
002
002
001
001
001
4201
343
187
048
• 024
012
005
004
004
003
314
167
1 11
108
108
062
056
052
034
030
1411
495
257
243
236
227
179
051
043
015
11 19
345
317
297
221
190
164
153
127
049
teal
Emissions
Ra-< SIC (lj/y)
7 2911 68,257091
8 2823 53.853875
9 2621 51135.635
10 3079 45.820041
11 3312 41.915.089
12 2511 41.790.092
%OI
20.5ii
SIC Cone Rink
929 1
2
3
4
5
6
7
8
9
10
679 1
2
3
4
5
6
7
8
9
10
1895 1
2
3
4
5
6
7
8
9
10
2288 1
2
3
4
5
6
7
8
9
10
1598 1
2
3
4
5
6
7
8
9
10
6534 1
2
3
4
5
6
7
8
9
10
Cnemicai
Tduene
Ammonia
Propylene
Xylene (Mixed Isomers)
Benzene
Elhylene
Methyl Ethyl Kelone
Cyclohexane
1.2.4-Tnmeihyi benzene
Elhyibenzene
Carbon Oisullide
Acetone
Methyl Ethyl Kelone
Benzene
Dtchloromelhane
Melhanol
Ammonia
Formaldehyde
SulluncAod
Phenol
Melhand
Hydrochloric Add
Chloroform
SultuncAad
Acetone
Chlonne
Ammonia
Chlonne Dnxrie
Oichloromelhane
1.1,1-Tnchloroethane
Acetone
Melhand
Dlchtoromelnane
Melhyl Ethyl Ketone
Carbon Oisullide
Tduene
Slyrene
Ammonia
Xylene (Mixed Isomers)
1.1.1-Tnchloroelhane
Benzene
Ammonia
1.1.1-Tnchlcroelhars
Hydrochloric Acid
Xylene (Mixed Isomers)
Toluene
Zinc Compounds
Zinc (Fume Or Oust)
Elhylene
Tnchtoroelhylene
Tduene
Melhand
Xylene (Mixed Isomers)
Melhyl Ethyl Kelone
Acetone
n-Bulyl Alcohol
Methyl Isoouryl Kelone
Glycd Ethers
1.1.1-Tnchloroethane
isopropyi Alcohol (Manulad)
loai % 0 foai
Emissions 2 O'W
(in/yo Sic
11.450.602
8318.366
•8.092.688
6.586.051
5.849.179
5.152.991
5,094,696
1,747.462
1,674.136
1.653.957
49,092.000
3.117.964
820,828
480,733
161.897
76,116
64.750
30.156
2.450
1.773
17.410.572
12.501,509
5,778,067
5.574,049
2.51Z663
2,335,971
1.126.394
1.058.526
452.915
428.704
9.499.462
8.835.451
4.847.131
3.732.220
3.388.384
2.935.724
2.733,506
1,972.826
1,667,641
1.196,371
11.805.641
5.010.668
4,781.151
2.547.603
1.995.295
1.463.256
1,344.093
1.340.587
1.215.496
1.082,792
12,360522
8,731,600
6.130.008
4,360528
3,858969
2,210.364
1.638.602
776,062
684,838
460,701
1558
1132
1101
896
796
701
693
238
228
225
619
039
010
006
002
001.
001
000
000
000
645
463
214
207
093
087
042
039
017
016
474
441
242
186
169
147
137
099
083
060
450
191
182
097
076
056
051
051
046
041
1933
1365
958
632
603
346
256
121
107
072
C-12
-------
Table C-8 (Continued)
Top Industrial Emitters —1989 4-Digit SIC Codes
foai SOI
E.-.iss.ors Z-Dign
Rar« SIC (iD/yr) SCCooe *«
13 3714 41.606.927
14 3089 40.913,834
15 3411 38.929.936
16 2672 37.943.221
1847 1
2
3
4
5
6
7
8
9
10
2043 1
2
3
4
5
6
7
8
9
10
2692 1
2
3
4
5
6
7
8
9
10
1406 1
2
3
4
S
6
7
8
9
10
C-emcal
1,1.1-Tncfiloroeihane
Xylene (Mixed Isomers)
Tnchloroelhylene
Toluene
Meihyl Elhyl Kelone
Slyrene
Freon 113
Aceione
Telrachloroelhylene
Glycol Elhers
Carbon Disultide
Aceione
Toluene
Slyrene
Meihyl Elhyl Kelone
Dichloromelhane
1.1.1-TndiloroellBne
Melhanol
Tnchloroelhylene
Xylene (Mixed Isomers)
Glycol Ethers
n-Bulyl Alcohol
Xylene (Mixed Isomers)
Meihyl Elhyl Kelone
Toluene
Cyclohexane
Meihyl Isobulyl Kelone
1.1,1-Tnchloroelhane
SulluncAcid
Trichloroelhytene
Toluene
Meihyl Elhyl Kelone
Meihanol
Aceione
Xylene (Mixed Isomers)
Hydrochloric AarJ
1.1.1-Tndiloroelrene
Cyclohexane
Formaldehyde
Naphthalene
Tom lOMoin
Emissions 2 OICH
(ID/yr) Sfc
5.445.705
5,444,556
4.846.941
4.416,942
3,885,462
3.758.989
3.661,010
2.355.727
1.469.119
1.273.690
9,597,250
8.068.724
4.417.794
3,689.355
3.161.579
2.520.290
2.516.377
1.451,634
1.030.409
897,342
16.418,117
11.620.953
3.924.190
1.562.024
1.378597
892.711
885.452
700.804
528.813
266.145
17,343,087
16,337,667
2.150,901
552,236
526,159
270,000
149.401
102.000
99,623
92.750
242
242
215
196
172
167
162
105
065
057
479
403
221
184
158
126
126
072
051
045
1135
804
271
108
095
062
061
048
037
018
643
606
080
020
020
010
006
004
004
003
Bar. SIC
17 2754
IB 3861
19 2631
20 2819
loui S 01
E-IISS.OHS 2 den
(ls/yr) SC Cooe Rani
36.903,713 63 44 1
2
3
4
5
6
7
8
9
10
35.402200 6479 1
2
3
4
5
6
7
8
9
10
34.301,409 12 71 1
2
3
4
S
6
7
8
9
10
32.650,892 4 12 1
2
3
4
5
6
7
8
9
10
Caeracai
Toluene
Methyl Elhyl Kelone
xylene (Mued isomers)
i.U-Tncniorcelhane
Glycol Ethers
Meihanol
Aceione
Meihyl Isobulyl Kelone
Cydohexare
Zlnc(FumeOrDusl)
Didtloromeihane
Aceione
Melhanol
Toluene
Methyl Ethyl Kelone
1.2-Oichloropropine
Freon 113
Cydonexane
n-Butyl Alcohol
1,1,1 -Tnchlofoelhane
Melhanol
Hydrochloric Acid
Acetone
Chloroform
SulluncAcid
Chlorine
Ammonia
Chlonne Dioxide
Toluene
Meihyl Elhyl Kelone
Ammonia
Chlorine
Melhanol
SulluncAofl
Carton Disulllde
Hydrochloric Acid
Elhylene Glycol
Phosphoric Add
Elhytene
Toluene
loai % Oi leai
Ervsscrs 20oi
(KM &
31.268.282
1.869.170
1.228.413
596.817
418002
358.046
351.719
281.433
145.400
69199
13,227.225
7.384039
6.453.756
2,545.352
1.789.559
620000
490378
391023
380.482
299.846
17.374,259
5.566.472
4.341,380
2.116689
1. 650.584
867,538
561.626
510.050
377.687
295,183
9.653,027
5,656.581
3,969.710
1.962.691
1.756.535
1,485,767
720.317
711.929
677.893
624.889
5375
321
211
103
072
0.62
060
048
. 025
012
24.21
1351
1181
466
328
113
090
072
070
055
644
207
161
078
061
032
021
019
014
Oil
122
071
050
025
022
019
009
009
009
008
C-13
-------
TABLE C-9
National Emissions Of HAPs
- 1989 -
Cre-ai
Toluene
Meihanol
l.l 1-Tricnloroelhane
Xylene (Mixed isomers)
Chlorine
Melhyl Ethyl Kelone
Dichloromelhane
Carbon Disullide
Hydrochloric Acid
Giycd Ethers
Tricniorcethylene
Styrene
Melhyl Isobutyl Kelone
Telrachloroelhylene
Benzene
Chloroform
Caroonyl Sullide
ElhyieneGiycot
Formaldehyde
Hydrogen Fluoride
Chloromelhane
Ethyl benzene
Phenol
Acelaidenyde
i.3-Buiapiene
Vinyl Actlaie
p-Xylene
Chloroelhane
Cumene
Acrylonilnle
1 2-Oichloroelhane
Chlorobenzene
Naphthalene
Carbon Telracnlonde
Elhytene Oxide
Melhyl Melhacryiale
Methyl Ten-Butyl Elher
Bromomeihane
Propyiene Oxide
Manganese Compounds
o-Xylene
1.4-Oichtorobenzene
Lead Compounds
Aceiomirile
Chromium Compounds
Vinyl Chloride
1,2-Oichloropropane
m-Xylene
1.24-Tnchiorobenzene
Bionenyl
Di(2-Elhyihexyi) Phlhalale
Propipnaldenyde
Chloroprene
Cresol (Mixed isomers)
1 4-Oioxane
1,1,2-Trichioroetnane
Phlhahc Anhydnde
Aniline
NO Oi
ETOtn
3,970
2.429
3.889
3532
1253
2.480
1.539
78
2.416
1.637
832
1.319
1,049
663
475
186
32
938
840
455
83
687
585
74
157
146
37
48
152
112
98
61
412
95
194
234
105
33
123
466
69
21
569
72
846
49
12
S3
49
149
208
15
7
112
87
28
142
67
loai
Emissions
W)
261.960,919
206396,888
17274S48S
152.X1.772
132.643321
131.116.286
122809.412
99.983,802
73,204,206
47,977,093
47,501,723
34.102.196
30.895,812
27.X6.973
25.863.548
25.269,682
13,075606
13,197,795
12.925,115
10.006434
9.707459
9.062 195
9,023,094
7,769993
5,700,676
5504693
4,933,722
4.788171
4,400,247
4387467
4284066
4051,144
3456537
3.369248
3235,634
3.149,059
3,008,160
2.594.426
2050182
1.833491
1,808.306
1592229
1.570,821
1,459.180
1.409.098
1.269032
1,233,330
1,200,771
1,151,473
1,089079
1078940
1.077,469
1006,341
897,744
821,020
786,898
650151
504,140
Icji HAPs 01 Iciai IRI
E-issors
1481
1167
977
359
750
741
694
565
414
271
269
193
175
153
146
143
102
075
073
057
055
051
051
044
032
031
028
027
025
025
024
023
020
019
018
018
017
015
012
010
010
009
009
008
008
007
007
007
007
006
006
006
006
005
005
004
004
003
E-iSOi-S
1047
825
690
606
530
524
491
400
293
192
190
136
123
108
103
101
072
053
052
040
039
036
036
031
023
022
020
019
018
018
017
016
014
013
013
013
012
010
008
007
007
006
006
006
006
005
005
005
005
004
004
004
004
004
003
003
003
002
C-e-cj' E
Dieinanoiamine
Erjicnloronydnn
Maleic Anhydride
MeihyieneDis(Phenyiisocyanale)
Dimethyl Phlhalale
Acrylic Acid
Nickel Compounds
p-Cresol
Dibulyl Phlhalale
2-Nilropropane
vmyiidene Chloride
Ethyl Acrylale
Ally! Chlonde
Arsenic Compounds
Anhmony Compounds
1 2-Bulyiene Oxide
N N-Dimelhylaniline
Toiuene-2 4-Onsocyanaie
Hexacniorocyciopentadiene
2 4-Omilrololuene
Cadmium Compounds
Cobalt Compounds
Dibenzoluran
Ouinolme
o-Cresol
1,2-Dibromoelhane
Titanium Telrachlonde
1 3-DicnlororjroDylene
4 4'-Melhylenedianiline
Niirooenzene
Asbestos (Friable)
1,122-Telrachloroetnane
Hydrazme
Benzyl Chlorine
o-Toluidme
Acrylamide
Melhyl iodide
Benzoic Trichloride
Caplan
ChloroaceticAcid
Hexactiloroelhane
Selenium Compounds
Acroiein
Phosphorus (Yellow Or While)
Methyl Isocyanale
Dimelhyl Sullale
Hydrodumone
Calcium Cyanamide
m-Cresoi
Peniachioropnenoi
Canary!
Dielnyl Sullale
Phosgene
4-Nilropheno1
2,4-0
Bis(2-Chioroeinyl) Elher
Hexacnlorobenzene
2 4-Diaminololuene
No 0
-l!B5
222
76
166
296
38
155
396
17
IX
10
23
107
19
133
201
16
16
240
4
9
88
112
106
58
25
25
27
8
24
17
66
16
42
47
18
50
4
4
20
19
17
28
12
30
5
26
32
1
14
43
19
21
32
5
16
9
9
3
tail
Ermors
(lay-)
484958
472548
451062
380213
363,430
357,523
272689
255484
234380
225,222
220632
195685
175603
175584
166,372
119,679
91,759
90,946
89.246
87.293
85004
79 IX
64.510
64.224
59666
59.167
57.287
50917
47.760
38,791
38435
35.401
31.669
27118
25849
25.496
25.472
25.275
25.222
24.845
22.342
20,721
20,075
16.174
14.948
13.817
13060
12.620
12.601
11.123
10.081
8.717
8.263
7.754
7.206
4.888
4.591
4,426
% 01 Cfe'-icii ^
lom HAPs 0! loin FBI
E fissions
003
003
003
002
002
002
002
001
001
001
001
001
001
001
001
001
001
001
001
on
ox
ox
ox
ox
ox
ox
ox
ox
ox
on
ox
on
on
on
on
ox
ox
ox
on
on
on
on
ox
ox
ox
ox
ox
ox
ox
ox
on
ox
on
ox
ox
ox
ox
on
E-isicrs
002
302
002
002
001
001
001
001
001
001
001
001
001
001
001
on
on
on
on
on
on
on
on
on
on
on
on
ox
ox
on
ox
on
on
on
on
on
on
ox
ox
on
on
ox
on
on
ox
ox
ox
on
on
ox
on
on
on
on
ox
ox
on
on
C-14
-------
Table C-9 (Continued)
National Emissions OfHAPs —1989
Nl
Cnemtcai Eni
p-Pfienylenediamme
Mercury Compounds
Calechol
Tnlluralm
Chlordane
Hexacnioro-t,3-Butadiene
Urelhane
Hepiacnior
o-Anisidme
Oumtozene
Slyrene Oxide
Quiflone
ParaDiion
4,4'-Melhylenebis(2-Chlon)amline)
Oichlorvos
Beryllium Compounds
>OI
i»s
4
12
11
13
1
8
2
2
6
5
3
1
7
5
7
5
toai
Emissions
(IBM
4.083
4009
3.962
3,932
3,753
3.S37
3.450
3.41 T
2.048
2.040
2.025
1.760
1.595
1,511
1,325
962
% 0 CKGRIiai *
loai HAPs 01 tout IRI
Elisions Emss.oos
OX
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
ox
C-e-icai
1 1 -Dimethyl Hyorazme
linuane
Vinyl Bromide
Elnyiene Thiourea
Propyleneimme
Melhoxycnior
Propoxur
3.3'-DimeinoxylKiuiaine
4.6-Oiniiro-o-Cresol
3.3'-Oichloro6enzidine
245-Tnchlorophenol
Chioromelhyl Methyl Elder
2 4.6-Tricriloropnenol
MelhylHydrazine
Bis/Cnloromdhyl) Elher
4-AminoODnenyl
Nod
l-
-------
TABLE C-10
National Emissions of 33/50 Chemicals
—1989-
CilCfRCll
Toluene
1,1,1-Trichloroelhane
Xylene (Mixed Isotners)
Methyl Elhyl Kelone
Dlchloromelhane
rnctiloroelhyiene
Methyl Isobulyl Kelone
Teirachiorainyiene
Benzene
Chloroform
p-Xylene
Carbon Telrachlonde
o-Xylene
No 01
[miners
3.970
3.989
3.532
2.460
1,539
832
1.049
663
475
166
37
95
69
row
Emissions
(IBVO
261,960919
172,745.465
152.00t.772
131,116.286
122,609.412
47,501.723
30,695,612
27,006,973
25,663.546
25,269.662
4,933.722
3,369.248
1,608.306
% 01 Chemical %
rain 31/50 0 loai
Cnemais IN Emissions
2578
1701
1496
1291
1209
466
304
266
255
249
049
033
018
1047
690
608
524
491
190
123
108
103
101
020
013
007
C.temai
Lead Compounds
Chromium Compounds
m-Xylene
Chromium
Nickel
Lead
Cyanide Compounds
Nickel Comppunds
Cadmium Compounds
Cadmium
Mercury
Mercury Compounds
NO a
Emmas
569
846
53
819
776
637
199
396
86
57
38
12
rot*
Ermsiods
(«*')
1.570,821
1.409.098
1.200,771
1.139.201
1 116,287
861,598
824908
272.689
85.004
35,267
25,085
4,009
1,015,827,626
% 01 Cftrmif t
tall 33/SO 01 loiai
C'lerciais mi Easier*
015
014
012
Oil
011
006
008
003
001
000
000
000
10000
006
006
005
005
'004
003
003
001
000
000
000
000
4060
TABLE C-11
National Emissions Of High Risk/Early Reduction Chemicals
— 1989 —
No 01
Chemical Emmets
Benzene
1 3-Buladiene
Acrylomlnle
Elhyiene Oxide
Chromium Compounds
Vinyl Chloride
Chromium
Chloroprene
Methylenebis(Phenylisocyanale)
Acrylic Add
Vinylidene Chloride
Arsenic Compounds
Toluene-2.4-Ousocyanale
Cadmium Compounds
Dibenzoluran
1,2-Oibromoelhane
Arsenic
Asbestos (Friable)
1.122-Tetrachloroelhane
475
157
112
194
846
49
819
7
296
155
23
133
240
68
106
25
37
66
16
Toai
EffllfilOTS
(Ib/YO
25,663.548
5,700.676
4,367.467
3,235.634
1,409,098
1269.032
1,139.201
1,006.341
360.213
357.523
220.632
175,564
90.946
85.004
64.510
59.167
56.150
36.435
35.401
%0f
loal Hign
Risk/Einy Chemical %
Reoucion 01 loin TRI
C hcrniol s Em i ssi ons
5649
1245
958
707
308
277
249
220
083
078
048
038
020
019
014
013
013
008
008
103
023
018
013
006
005
005
004
002
001
001
001
000
000
000
000
000
000
000
Chemical
Cadmium
Hydrazine
Acrytamide
Benzoic Trichloride
Mercury
Acrdein
Methyl isocyanate
Phosgene
Bis(2-Chlofoelnyl) Ether
Hexactiloroberaene
Mercury Compounds
Chiordane
Heplachior
Beryllium
Beryllium Compounds
Propyleneimme
Chloromelhyl Methyl Ether
Bis(Chloromelliyl) Ether
No 01
Emitters
57
42
50
4
38
12
5
32
9
9
12
1
2
8
5
4
3
1
Foul
Emissions
(in/M
35,267
31.669
25,496
25275
25,065
20,075
14,948
8,263
4,888
4,591
4,009
3,753
3.411
2,395
962
540
130
3
45,787,322
%0t
Fotii High
Risttmy Chemical %
Reftciion 01 Foal 1HI
Cheniais Emissions
008
007
006
006
006
004
003
002
001
001
001
001
001
000
000
000
000
000
10000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
183
C-16
-------
TABLE C-12
National Emissions Of Carcinogens In TRI Database
-1989-
Cneraoi
Dicrtioramethane
Tnchioroeihyiene
Slyrene
relracMoroeltiylene
Benzene
Chlorolorm
Formaldehyde
Chioromelhane
l.3-8uladiene
Acrylomtnle
1,2-Dichloroelhane
CatDon Telrachionde
Elhylene Oxide
Vinyl Chloride
Chromium
l.l.2-Trichloroeiriane
Epichlororiydrin
2-Nilropropane
Vinyhdene Chlonde
2,4-Oiniirotoiuene
2,6-Omilrololuene
l.2-0irjromoelhane
Arsenic
Asbestos (Friable)
1,1,2.2-Telrachloroelhane
Cadmium
Hydrazme
No 01
E.-nintu
1.S39
832
1,319
663
47S
186
840
83
157
112
98
95
194
49
819
28
76
10
23
9
6
25
37
66
16
57
42
low
Emissions
flO/M
122.809,412
47501.723
34.102.196
27.006,973
25.863.548
25.269.682
12.925.115
9,707,459
5.700.676
4,387,467
4284.066
3369.248
3235.634
1.269,032
1,139.201
786.898
472.548
225222
220.632
87.293
83.914
59.167
58.150
38.435
35.401
35.267
31.669
HOI Ciimat
Icai 01 loai IRI
CitCttoQcrs Emissions
3712
1436
1031
816
782
764
391
293
172
133
129
102
098
038
034
024
014
007
007
003
003
002
002
001
001
001
001
491
190
136
108
103
101
052
039
023
018
017
013
013
005
005
003
002
001
001
000
000
000
000
000
000
000
000
NO a
Cnem-cii E.-un
Benzyl Chloride
o-Toluidine
Methyl iodide
HexacnloroBlhane
Dimelhyl Sullale
8is(2-Chloroelhyi) Ether
Hexachlorotienane
2.4-Oiarninololuene
Chlordane
Thiourea
Hexacnloro-i.3-Buladiene
Urelhane
Heplacnior
Beryllium
Oumlozene
44--MeinyieneDis(2-Cnioroaniline)
Saccharin (Manufacturing Only)
1.1-DimelhyiHydrazine
Undane
Etnyiene Thiourea
Alpha-Naphlhylamme
Propyleneimine
3,3'-Oictilorcbenzi
-------
TABLE C-14
All Chemicals Reported
— 1989-
Care
X
X
X
X
X
X
X
X
X
X
X
X
X
Ozone
Deol HAP
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HH/ER Chemeal
X 1,1,1-Trichloroethane
X 1,1.2.2-Tetrachloroethane
1,1.2-Tnchloroethane
1,1 -Dimethyl Hydrazme
1 ,2.4-Trchlorobenzene
1 ,2.4-Trimethylbenzene
1,2-Butylene Oxide
X 1 ,2-Dibromoethane
1 ,2-Dehlorobenzene
1 ,2-Dichloroelhane
1 ,2-Dichloroethylene
1 ,2-Ochloropropane
X i,3-Butadiene
1 ,3-Oichlorobenzene
1 ,3-Dichloropropylene
1 ,4-Oichlorobenzene
1 ,4-Dioxane
2,4.5-Trichlorophenol
2,4.6-Tnchlorophenol
2,4-0
2,4-Otammoanisole
2,4-Diammotoljene
2.4-Dicnlofophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Omitrotoiuene
2.6-Omitrotoluene
2.6-Xylidme
2-Ethoxyethanoi
2-Methoxyettianol
2-Nitrophend
2-Nitropropane
2-Ptionyl phenol
3,3'-OichlorobenzKline
3,3'-Oimethoxybenzidme
4,4<-Oiaminadiphenyl Ether
4,4'-l30propylidenediphenol
4,4'-Methylenebi5
(2-Chloroaniline)
4,4'-Meihylenfldianiline
4,6-Dinitro-o-Cresol
4-Aminobiphenyl
4-Nitraphenol
5-Nitro-o-Amsidine
Acetaldehyde
Acetone
Acetomtrile
X Acrotem
X Acrylamide
CasNo
000071 556
000079345
000079005
000057147
000120821
000095636
000106887
000106934
000095501
000107062
000540590
000078875
000106990
000541731
000542756
000106467
000123911
000095954
000088062
000094757
000615054
000095807
000120832
000105679
000051285
000121142
000606202
000087627
000110805
000109864
000088755
000079469
000090437
000091941
000119904
000101804
000080057
000101144
000101779
000534521
000092671
000100027
000099592
000075070
000067641
000075058
000107028
000079061
Emitted To An
(ttvyr)
172,745,485
35,401
786,898
804
1.151,473
4.862.850
119,679
59.167
377,728
4.284,066
185.992
1,233,330
5,700,676 '
11,398
50,917
1.592.229
821,020
250
116
7,206
250
4,426
1,553
1,680
13,652
87293
83.914
44
1 ,655,035
2,690,364
4,405
225,222
8.052
254
500
630
227,255
1,511
47.760
271
1
7.754
500
7.769,993
202.624,803
1,459.180
20.075
25.496
Eimtad To All
Med» (b/yr)
172,843,753
40,839
795,098
1,054
1.168.684
4.919.245
123,818
63.963
488,417
5,557.255
186.775
1.244,912
5,860,433
11,420
51,257
1,599,350
1,121,994
250
131
11,288
250
4.676
8,220
27.556
178,216
167,575
102.997
1,950
1,751,155
2,740,904
4,411
464,922
8,186
254
500
1,225
1,009.141
1.511
144.215
276
10
9.554
500
9.790.308
208,394,872
19,585,226
46.537
3.373.860
C-18
-------
Table C-14 (Continued)
All Chemicals Reported — 1989
Otona
Care Oeol HAP
X
X X
X
X
X
X
X
X
X X
X X
X
X X
X
X
X
X X
X X
X
X
X
X
X
X
X
33<50 HfVEB Chamcai
X Acrylic Acid
X Acrylomtnle
Allyl Chloride
Alpha-Naphthylamine
Aluminum (Fume Or Oust)
Aluminum Oxide (Fibrous Form)
Ammonia
Ammonium Nitrate (Solution)
Ammonium Sullaie (Solution)
Aniline
Anthracene
Antimony
Antimony Compounds
X Arsenic
X Arsenic Compounds
X Asbestos (Fna&ie)
Banum
Banum Compounds
Benzal Chloride
Benzamide
X X Benzene
X Benzoic Tnchlonde
Benzoyl Chtonde
Benzoyl Peroxide
Benzyl Chloride
X Beryllium
X Beryllium Compounds
Biphenyl
Bis(2-Chloro-1-
Methylethyl) Ether
X Bis(2-Chloroetriyl) Ether
Bis(2-Ethylhexyl) Adipate
X Bis(Chlorometnyl) Ether
Bromomethane
Butyl Acrylate
Butyl Benzyl Phthalate
Butyraldehyde
C 1 Basic Green 4
C 1 Basic Red 1
C 1 Direct Black 38
C I Disperse Yellow 3
Cl Food Red 15
C I Solvent Yellow 14
X X Cadmium
X X Cadmium Compounds
Calcium Cyanamide
Cap tan
Carbaryl
Carbon Qsulfide
CasNo
000079107
000107131
000107051
000134327
007429905
001344281
007664417
006484S22
007783202
000062533
000120127
007440360
007440382
001332214
007440393
000098873
000055210
000071432
000098077
000098884
000094360
000100447
007440417
000092524
000108601
000111444
000103231
000542881
000074839
000141322
000085687
000123728
000569642
000989388
001937377
002832408
000081889
000842079
007440439
000156627
000133062
000063252
000075150
Emitted To Air
(toyr)
357523
4.387,467
175603
672
2.952.898
1.552,712
251 .967.698
3.453.887
860261
504,140
94,950
103,969
166,372
58.150
175.584
38.435
279.226
735.231
5.456
500
25.863.548
25,275
36.896
5.074
27.118
2.395
962
1 .089.079
3.359
4.888
65.407
3
2.594.426
312.076
273.922
1.540.346
750
250
500
359
250
500
35,267
85.004
12.620
25,222
10,081
99,983,802
Emitted To Al
Madia (tyyr)
19,097,983
10,186969
177,467
672
6,416,195
13.946.756
351.422.895
23.550.830
9.373,978
3.789.074
113676
196.078
1.077.569
85.744
4.227.086
836395
665 242
4.911.340
5,456
1.000
26.8 15.255
25,275
205.396
5.074
28.019
34289
36,984
1.144.208
15.359
6.440
98.331
3
2.660,951
318.940
275.537
1.552.483
750
250
500
1,229
250
500
113.078
334.379
16.220
31.222
44,533
100.033.224
C-19
-------
Table C-14 {Continued)
All Chemicals Reported — 1989
Care
X
X
X
X
X
X
X
X
X
X
O?on«
Dool HAP
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HH/EB Clmmcal
X Carbon Tetrachlonde
Carbonyl SulMe
Catechol
X Chtordane
Chlorine
Chlorine Dioxide
Chloroacenc Acid
Chtoro benzene
Chloroethane
X Chloroform
Chloromethane
X Chtoromethyl Methyl Ether
Chlorophenols
X Chloroprene
Chloromalonil
X X Chromium
X X Chromium Compounds
Cobalt
Cobalt Compounds
Copper
Copper Compounds
Cresol (Mixed Isomers)
Cumene
Cumene Hydroperoxide
Cupferron
X Cyanide Compounds
Cyclohexane
Decabromodiphenyl Oxide
Dt(2-Ethyiriexyi) Pntnalaie
Diaminotoluene
(Mixed Isomers)
X Obenzofuran
Obuiyi Phthalate
Ochloro benzene
(Mixed Isomers)
X Ochtorometnane
Ochkjrvos
Ocolol
Dwthanolamme
Diethyl Phthalaie
Oeihyl Sullate
Dimethyl Phthalate
Dimethyl Sullate
Epichlorohydrin
Ethyl Acrylate
Ethyl Chlorolormate
Ettiylbenzene
Ethylene
Ethylene Glycol
X Ethylene Oxide
CaiNo
000056235
000463581
000120609
000057749
007782505
010049044
000079118
000108907
000075003
000067663
000074873
000107302
000126998
001897456
007440473
007440484
007440508
001319773
000098828
000080159
000135206
000110827
001163195
000117817
025376458
000132649
000084742
025321226
000075092
000062737
000115322
000111422
000084662
000064675
000131113
000077781
000106898
000140885
000541413
000100414
000074851
000107211
000075218
Ennad To Air
(bfyr)
3.369.248
18.075.606
3.962
3.753
132.643.321
7.021.391
24.845
4.051,144
4.788,171
25.269.682
9,707,459
130
4564
1.006,341
29.497
1.139.201
1.409.098
48,002
79,100
2.255.291
3,812,785
897,744
4.400.247
115.621
1.500
824.908
17684.695
49.957
1 .078.940
19.723
64,510
234.380
137.912
122809.412
1,325
1,329
484 958
92.610
8.717
363.430
13.817
472.548
195.685
8642
9.062,195
42,468,462
13.197.795
3.235.634
Erntttd To All
Media (Myr)
3,508.313
18.075.606
83.914
3.757
135.163021
7,022.641
26.379
4.203.273
4.860.070
26.586,615
9.996,108
130
142402
1.164533
29,750
2,317,631
30.666.944
91.069
143.460
7,544.114
44.662.855
2975,174
4.441.236
250.487
1.500
957,839
18,108.716
55.752
1.087.122
117.271
72.701
558.902
138.097
124.987.494
1.325
1.579
731,739
102.010
8.967
364,995
14,367
676.504
200.154
8.642
9.227.781
42.518.182
25.154,849
3.295.032
C-20
-------
Table C-14 (Continued)
Care
X
X
X
X
X
X
X
X
X
Ozona
0«pl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
All Chemicals Reported — 1989
XkSO HFVER ChcncaJ CaiNo
Elhylene Thiourea
Fluometuron
Formaldehyde
Freonns
Glycol Ethers
X Heptachlor
Hexachkxo-1 ,3-Butadiene
X Hexachlorobenzene
Hexachkxocydopentadiene
Hexachkxoethane
X Hydrazine
Hydrazme Sulfaie
Hydrochloric Add
Hydrogen Cyanide
Hydrogen Fluoride
Hydroquinone
Isobuiyraktehyde
Isoprooyl Alcohol
(Manufaciunng)
X Lead
X Lead Compounds
Lindane
m-Cresol
X m-Xylene
Maleic Anhydride
Maneb
Manganese
Manganese Compounds
X X Mercury
X X Mercury Compounds
Methanol
MBthoxychlor
Methyl Acrylate
X Methyl Ethyl Ketone
X Methyl Hydrazine
Methyl Iodide
X Methyl Isobutyl Ketone
X Methyl Isocyanate
Methyl Methacrylate
Methyl Tert-Butyl Ether
Methylene Bromide
X Methylenebis(Phenylisocyanate)
Mchler'S Ketone
Molybdenum Tnoxide
N,N-Dimethylaniline
n-Buryl Alcohol
n-Ooctyl Phthalate
Naphthalene
X Nickel
X Nickel Compounds
000096457
002164172
000050000
000076131
000076448
000087683
000118741
000077474
000067721
000302012
010034932
007647010
000074908
007664393
000123319
000078842
000067630
007439921
000058899
000108394
000108383
000108316
012427382
007439965
007439976
000067561
000072435
000096333
000078933
000060344
000074884
000108101
000624839
000080626
001634044
000074953
000101688
000090948
001313275
000121697
000071363
000117840
000091203
007440020
Emitted To Air
»W
764
540
12.925.1 15
64.010.405
47,977.093
3.411
3.637
4.591
89.246
22.342
31.669
1
73.204.206
771,587
10.006.434
13.060
559.749
5.S78.738
861.598
1.570.821
787
12.601
1.200.771
451.062
1.781
3.020.671
1.833.491
25.085
4.009
206.396.888
536
194,201
131.116,286
73
25.472
30.895.812
14,948
3.149.059
3.008.160
36.364
380.213
144
100.669
91,759
36.603.123
523.344
3.456,537
1.116,287
272.689
EmttedToAII
Media (bryr)
764
540
22.341,763
64.051.985
48.583.092
3.413
4.590
5.305
89,252
23.534
33.963
1
348.510.982
4.311.595
10.052.295
114,313
561.543
5.609.844
5,752.274
15.810.824
1,037
12.636
1.209.144
454.132
1.781
10.053.073
87.121.399
31.582
4.263
254.329.158
1.036
195.818
131.325.040
73
30.558
31,447,960
15.262
3.379.675
3,066,189
36.364
524.857
144
228.750
106.196
39.068,682
523.614
3.741,110
2.002.953
2.429.302
C-21
-------
Table C-14 (Continued)
Ozon*
Care Dapl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
All Chemicals Reported— 1989
33/50 HR/ER Chwncal Ca No
Nitric Add
Nitrilotriacenc Acid
Nitrobenzene
Nurcglycerin
o-Anisidine
O-ClBSOl
o-Toluidine
X o-Xykme
p-Anisidine
p-Cresidine
p-Creaol
p-Nitrosodiphenylamine
p-Phenylenediamine
X p-Xytone
ParattiKxi
Pentachlorophenol
Peraceoc Aad
Phenol
X Phosgene
Ptwsphoric Acid
Phosphorus (Yellow Or White)
Phftalic Anhydride
Picric Aad
Propionsjdehyde
Propoxur
Propylene
Propylono Oxide
X Propyteneimine
Pyndine
Quinolme
Ouinone
Qumtozene
Saccharin (Manufacturing Only)
Sec-Butyl Alcohol
Selenium
Selenium Compounds
Silver
Silver Compounds
Styrene
Slyrene Oxide
SulfuncAcid
Ten-Butyl Alcohol
X Tetraenkxoethylene
Tetrachlorvinphos
Thallium
ThaJtium Compounds
Thwurea
Thonum Dioxide
Titanium Tetrachlonde
X Toluene
007697372
000139139
000098953
000055630
000090040
000095487
000095534
000095476
000104949
000120718
000106445
000156105
000106503
000106423
000056382
000087865
000079210
000108952
000075445
007664382
007723140
000085449
000088891
000123386
000114261
000115071
000075569
000075558
000110861
000091225
000106514
000082688
000081072
000078922
007782492
007440224
000100425
000096093
007664939
000075650
000127184
000961115
007440280
000062566
001314201
007550450
000108883
Emitted To A»
-------
Table C-14 (Continued)
Ozone
Care Ded HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
All Chemicals Reported — 1989
33/50 HR/ER Chemeal CuNo
X Toluene-2.4-Diisocyanate
Toluene-2,6-Diisocyanate
Tnchkxfon
X Tnchkxoethylene
Tnfluralin
Urethane
Vanadium (Fume Or Dust)
Vinyl Acetate
Vinyl Bromide
X Vinyl Chloride
X Vmyhdene Chloride
X Xylene (Mixed Isomers)
Zinc (Fume Or Dust)
Zinc Compounds
Zineb
000584849
000091087
000052686
000079016
001582098
000051796
007440622
0001080S4
000593602
000075014
000075354
001330207
007440666
012122677
EmmodToAir
<*>W
90.946
51.357
847
47.501.723
3,932
3.450
9.347
5.504.693
770
1 ,269,032
220.632
152.001.772
3.529,302
4,742.696
500
Emttad To Ml
Madia (b/yr)
94,516
63.537
848
47.525.746
5.224
3.450
17,502
6.828.896
1.040
1.276.291
224.583
152.646.551
'iJ.052.034
95.686.717
500
2.501.993.075 3.573.226.573
C-23
-------
C-24
-------
Appendix D
Data from Basic Data Set -
-------
TABLE D-1
Regional Hot Spots
— 1988EPA REGIONS-
EPA
Rar.< Region
1 4
2 5
3 6
4 3
5 2
loin toon %
Emissions 01 total
(lo/yr) miExissnns Ran<
652133.885 2502 1
2
3
4
5
6
7
8
9
10
553,441.733 21 23 1
2
3
4
5
6
7
8
9
10
409.689,743 1572 1
2
3
4
5
6
7
8
9
10
277,038.496 10 S3 1
2
3
4
S
6
7
8
9
10
151.907.179 583 1
3
4
5
6
7
8
9
10
Clienal
Methanol
Acetone
Toluene
Carton Dlsuilide
Ammonia
Xylene (Mixed Isomers)
i.U-Tridiloioeihane
Methyl Ethyl Kelone
Dlcnloromethane
Hydrochloric Acid
Toluene
Xylene(Mixed Isomers)
1.1.1-Tnchloioelhane
Methyl Ethyl Kelone
Acetone
Dichtoromelhane
Ammonia
Melhanol
Glycol Ethers
Tnchtorcclhylene
Ammonia
Elnytere
Methanol
Toluene
Xytene (Mixed Isomeis)
Propytene
Acetone
Methyl ElhylKetone
1.1.1-Tncfilotoelhane
Carton Disultide
Carbon Olsullide
Metnanol
Toluene
Acetone
1.1.1-TrKhlonelhane
Methyl Elhyl Kelone
Xylene (Mixed Isomers)
Ammonia
Dichloroflielhane
Hydrochloric Acid
Toluene
Dichloromelhane
Acetone
Metnanol
1.1.1-Trlctilofoelrane
Methyl ElhylKetone
From 113
Xylene (Mixed Isomers)
Hydrochloric Acid
Tncfiloroelriylene
Total
Emissions
(in*')
94.637.255
75692.429
73.561.782
67.670.727
45.194.518
29.062.164
28.432.275
27.658.144
27.224.961
21.500.343
78,490.646
52.881.418
47,305.603
46.656.380
44.235.241
34.855.051
27.750.409
25,843,471
19,558.414
16.665.650
107.664,241
29.550.610
28.083.568
27.714608
19.993.500
15.323,839
1Z927.616
12,420.281
10.766.165
9.763.186
35.116.931
34,461.663
34,221 901
26.794.011
16.613,664
14,669,970
13912.900
1Z317.5B1
11,081,451
9.206.041
23.419.719
in mi A\7
20.01 4,41 r
16.372.840
14.577.599
9,744601
8.087.378
7.492.175
6,692,209
6.183.416
4.485,069
Total Rec'on %
EPA Enrnons 01 loai
Rjr» Rej'cr (lo/yr) IRI Emission] Ram
6 7 143.589,419 551 1
2
3
4
5
6
7
8
9
10
7 8 142.579.669 547 1
2
3
4
5
6
7
8
9
10
8 9 107,971.558 414 1
2
3
4
5
6
7
8
9
10
9 1 90.868.669 349 1
2
3
4
5
6
7
8
9
10
10 10 77.422.408 297 1
3
4
S
6
7
8
9
10
Ciicnim
Toluene
Xylene (Mixed Isomers)
Ammonia
Methyl Ethyl Kelone
l.t.i-Tnchioroemane
Methanol
Telrachloraelhylene
Acetone
Dlcnlororneihane
Tncnioroelhylere
Chlorine
Hydrochloric Aod
1.1.1-Tnchkxoelhane
Frconm
Toluene
Dichloroinetnane
Xylene (Mixed Isomers)
Acetone
Ammonia
Meihanol
U.i-Tnchkxoeuune
Freonin
AfflfflOflQ
Acetone
Dichloromelhane
Toluene
Methanol
Telrachioroelhylene
Methyl ElhylKetone
Xylene (Mixed Isomers)
1.1.1-Tnchtonxlhane
Toluene
Dichloromelhane
Freonin
Acetone
Meihanol
Methyl Elhyl Kelone
Chlorine
Tnchloroemylene
Telrachioroelhylene
Ammonia
Uafh^nnt
Meinanoi
Acetone
Toluene
Methyl ElhylKetone
Chloroform
Tricfiloroelhylene
Xylene (Mixed Isomers)
1,1,1-Trtchloroelhane
Slyrene
Toai
ETISIOHS
(ia/yi)
23.292.560
18.489.775
18.172,917
8.81 1.930
8.700.961
8.687.331
6.866653
6.746,466
6.244,763
4.638,457
102408134
9,271,940
5,436,487
2.930.769
2,578,218
2.207.302
2.071,769
1,437,802
1.338.571
1.254.540
25.889,602
10.062.729
9.519,741
7,901,541
7.405,776
5639,533
5.568.738
4.685.383
4.229.644
3.068.127
18.876.892
11.162.157
8.115.563
7.332.435
5.220,644
5.199,251
5.170,215
3.549,462
3,477.945
3,405,479
26.745,610
7 701 400
r,ro3.42I
5.951,425
5.222,793
3.150,974
3.104.021
2.278.701
2175,089
2,154,739
2.081,759
D-1
-------
TABLE D-2
State Emissions
-1988-
Slate Rank
AK 1
2
3
4
5
6
7
8
9
10
AL 1
2
3
4
5
6
7
8
9
10
AR 1
2
3
4
5
6
7
8
9
10
Clwncil
Ammonia
Hydrochloric Acid
Methanol
Chloroform
Xylene (Mixed Isomers)
SulfuncAcid
Toluene
Benzene
Cyclohexane
Ethyl benzene
Carbon Disulflde
Methyl Ethyl Ketone
Methand
Xylene (Mixed Isomers)
Hydrochloric Add
Toluene
Chlorine
Chloroform
Chlorine Dioxide
1,1,1-Trichloroettiane
Ammonia
Toluene
Methand
Xyltne (Mixed Isomers)
Acetone
Methyl Ethyl Ketone
Carbon Disulflde
Freon113
Dlchloromethane
1,1,1-Tnchloroethane
Total
Emttton. No 01
flNyr) Smitten
20.660.635
490,250
254.991
180,300
32.200
29.200
29.144
29.071
18,740
13,975
44.948.000
7.137,478
6.484.155
4.971,533
4.904,351
4.727.058
4.240.035
3.054,254
3.034,379
2,561.748
14.523.735
4.664,579
3.889,788
3,730,906
3.527.423
2.671.626
2.049.570
2,039.951
1.789.437
1,592,489
4
1
2
1
3
1
3
3
3
3
3
34
49
73
55
72
39
11
10
43
59
75
35
72
47
36
3
19
25
40
%OI
Slite
Total
9499
225
117
083
015
013
013
013
009
006
4302
683
621
476
469
452
406
292
290
245
3001
964
804
771
729
552
423
421
370
329
AS
AZ
CA
CO
Ammonia
29.500
100
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Acetone
Freon 1 13
1,1,1-Trichloroethane
Copper Compounds
Ammonia
Toluene
Methanol
Oichloromethane
Methyl Ethyl Ketone
Copper
1.1,1-Trfchloroethane
AfTlfflOfltt
Freon 113
Oichloromethane
Acetone
Methand
Tetrachloroethylene
Toluene
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
1.1.1-Trichloroelhane
Freon 113
Acetone
Glycol Ethers
n;Butyl Alcohol
Toluene
Methand
Oichlorometnane
Aluminum (Fume Or Dust)
Tetrachloroethylene
2.551.806
2.485,998
2.460.595
1.908.690
894.926
832.597
701.353
485,791
451.137
387.040
23.392.167
8,435.859
7.534.059
6.844.190
5,259.950
4.866.885
4.612.922
4,479.653
3.751,693
2.864.267
1.743.775
1.576.790
903,416
838,096
810,366
784.535
770,647
746,770
583.357
374,927
26
44
43
5
21
12
IS
13
18
2
456
201
186
129
244
131
103
223
192
180
36
31
23
7
7
19
13
13
6
6
1576
1535
1520
1179
553
514
433
300
279
239
2594
935
835
759
583
540
511
497
416
318
1444
1305
748
694
671
650
638
618
483
310
State
CT
DC
DE
FL
GA
HI
IA
Rink
1
2
3
4
5
6
7
8
9
10
1
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
1,1,1-Tnchloroethane
Oichloromethane
Tetracnloroethylene
Freonm
Toluene
Methanol
Methyl Ethyl Ketone
Acetone
Xylene (Mixed Isomers)
Chloroethane
Copper Compounds
Metnanol
Xylene (Mixed Isomers)
Hydrochloric Acid
Carbonyl Suifide
Methyl Ethyl Ketone
Trichloroethylene
Methyl Isobutyl Ketone
Vinyl Chloride
Carbon Tetrachlonde
Toluene
Ammonia
Acetone
Methanol
Dlchloromethane
Toluene
Freonm
1.1,1-Tnchloroethane
Styrene
Chlorine
Cyclohexane
Methanol
Acetone
Toluene
Hydrochloric Acid
Xylene (Mixed Isomers)
Ammonia
Dlchloromethane
1,1,1-Tnchloroethane
Tnchloroethyiene
Methyl Isobutyl Ketone
Ammonia
Propylene
Toluene
m-Xybne
Oichloromethane
Glycol Ethers
n-Butyl Alcohol
Benzene
o-Xylene
1,1,1-Trlchloroeihane
Toluene
Ammonia
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
1,1,1-Tnchloroetharo
Tetrachloroethylene
Methanol
Acetone
Ethylene
Dlchloromethane
Total
Emmont No 01
(In/yr) Emitter
9,908.702
2.809.094
2.348.032
2.033.250
1.634.831
1,298.043
965,168
425.803
409,040
407.750
250
1,454,126
1,201,581
900.001
840.000
425.155
301.000
236.400
176,927 .
170.000
165.278
10.940.681
8.679.725
6,425,844
3.436.020
2.742.899
2,198.136
2.101.721
1.856.055
1.656.026
1,171.546
27:650.789
7.637.171
6.829.183
5.297.951
4.232.468
3.911.347
3.686.220
3,271.889
2.966.079
2.681.647
141.100
111.800
97.400
72.700
68.945
64.129
56,629
40,400
37,500
35.840
8.807.952
6.845,792
3.814.251
3.166.768
3.135,719
2.827.552
2.779.641
2.555.297
2.000.000
951,414
149
SO
31
45
48
27
40
29
35
2
1
14
6
14
1
8
1
2
3
1
14
70
98
34
34
48
S3
66
61
32
3
67
65
88
51
101
77
50
79
15
29
5
2
2
2
1
1
1
2
2
2
66
52
83
27
59
16
23
34
1
17
%01
Sute
Total
3909
iros
926
802
645
S12
381
168
1S1
161
100
1922
1588
1190
11 10
S62
398
313
234
225
218
2178
1728
1279
684
546
438
418
369
330
233
3211
887
793
615
491
4S4
428
380
344
311
-1614
1279
11 14
832
789
734
648
462
429
410
2034
1581
881
731
724
653
642
590
462
220
D-2
-------
Table 0-2 (Continued)
State Emissions —1988
State
ID
IL
IN
KS
KY
LA
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
Chemcal
Ammonia
Chloroform
Methanol
Chlorine Dioxide
Formaldehyde
Freon113
Acetone
SuHuncAcid
Chlorine
1,1,1-Trtchloroettiane
Toluene
1,1.1-Trtchioroeinane
Ammonia
Xylene (Mixed Isorrars)
Etnylene
Methyl Ethyl Ketone
Chlorine
Dichloromethane
Tnchloroethylene
Acetone
Toluene
Dichloromethane
1.1,1-TrlchloroettHne
Acetone
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Tnchloroettiylene
Methanol
Benzene
Carbon Oisufflde
Ammonia
Toluene
Tetrachloroethylene
Xylene (Mixed Isomers)
Tnchioroetnylene
Methanol
Methyl Ethyl Ketone
Carbon Disulflde
Acetone
Propylene
Toluene
Methanol
Xylene (Mixed Isomers)
1,1.1-Tnchloroethane
Etnylene
Hydrochloric Acid
Acetone
Glycol Ethers
Dichloromethane
Methyl Ethyl Ketone
Ammonia
Methanol
Toluene
Ethylene
Carbon Olsulflde
Propylene
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Hydrochloric Acid
Benzene
Totll
Eminent No 01
(Ib/yr) Emitter!
1.895.667
700.000
636.143
540.250
260.407
252.289
211.956
191.414
153.001
122,650
18.169.523
10.509.459
7.582.468
6.585.293
5.415.520
5.038.220
4.391.243
4.223.386
4,159.306
3.617.824
16,026.510
13,933.992
10,482,348
10.273.759
9.145.786
7,388.014
5.100.863
3.302.760
3.292.165
2.976,627
5.296.601
3.121.419
3.074,561
2.879.182
2.530,285
2,228,337
1.712.653
1.385.500
1.154.190
897.648
10.219.305
6,607.884
5.018.432
2,562.103
2.459.861
2.196.660
2.121.527
1.833.386
1.381.160
1.004.818
71.535.550
7.093.996
6.870.011
5.540.190
5.247.818
3,773,019
2.566.876
2.012.907
1,948.480
1.810.313
17
1
6
1
7
3
8
12
11
3
213
226
106
197
15
139
54
106
105
113
183
81
141
113
179
110
65
86
16
3
36
53
7
45
13
18
24
2
28
6
67
32
65
48
5
36
41
24
22
32
59
65
71
38
8
30
55
36
53
38
%0f
Slate
Totll
3538
1306
1187
1008
486
471
396
357
286
2.29
17
983
710
616
507
4.71
411
395
389
339
1465
1274
958
939
836
675
466
302
301
272
1669
984
969
907
797
702
540
437
364
283
2132
1378
1047
534
513
458
443
382
288
210
5420
537
521
420
398
286
194
153
148
137
State
MA
MO
ME
Ml
MN
MO
flank
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Toluene
1 1,1-Tnchloroethane
FreonH3
Oichloromethane
Methyl Ethyl Ketone
Tnchloroethylene
Acetone
Methanol
Xylene (Mixed Isomers)
2-Methoxyetnanoi
Methanol
Ammonia
Toluene
1.1.1-Tnchloroethane
Hydrochloric Acid
Methyl Ethyl Ketone
Chlorine
Oichloromethane
Chloroform
Chlorine Dioxide
Chlorine
Methanol
1,1,1-Tncnioroetnane
Chlorine Dioxide
Acetone
Chloroform
2-Methoxyethanol
SulTuncAcid
Xylene (Mixed Isomers)
Toluene
Toluene
Xylene (Mixed Isomers)
Acetone
Dichloromethane
Methyl Ethyl Ketone
Methanol
1.1.1-Tnchloroethane
Glycol Ethers
Trlchloroethylane
n-Butyl Alcohol
Methyl Ethyl Ketone
Toluene
Xylene (Mixed Isomers)
Freon113
1.1.1-Tnchloroethane
Dicniorometnane
Acetone
Methanol
Glycol Ethers
n-Butyl Alcohol
Xylene (Mixed Isomers)
Toluene
1,1.1-Tnchloroethane
Oichloromethane
Methyl Ethyl Ketone
Methanol
Glycol Ethers
Acetone
n-Butyl Alcohol
Tnchloroethylene
Total
Emnwfli No 01
flVyr) Emittere
4.917,993
4.630.088
3,319.147
2.279,665
2.144,178
2.116,074
1.526,689
1.415,501
779,034
533,211
3.153.038
2.059,928
1,793.075
1,644,290
1.396.962
1.066,540
1.008.258
713,659
680,000
640,034
2.849,654
1.989,774
1.736,434
1.653,837
1.536,358
1.397,157
865,967
656,779
652.809
650,434
14,952,510
13.712,129
10.819,803
8,168,600
7.922,942
5,483,234
5.064,585
4.614,750
3.236,570
2.875,713
13.278,594
11.275,176
4,988,351
3.412,090
3.038,744
2.691,096
2.638.627
2.303.642
1.246,963
958,482
10.576.998
6.087,211
3.801,918
3.443,877
3.242,472
3,159,647
2.812,957
2.497.292
2.391,795
1.870.424
104
138
77
59
66
51
71
68
56
10
16
29
26
36
26
24
12
IS
1
1
14
12
22
7
22
7
2
19
16
14
188
150
140
73
125
89
149
89
48
58
39
68
52
49
67
40
52
26
25
20
106
125
87
54
72
56
45
69
35
30
%0f
Sute
Total
1806
17
1219
837
787
777
561
520
286
196
1754
1146
997
915
777
593
561
397
378
356
1672
1167
1019
970
901
820
508
335
383
382
1525
1399
1104
8.33
808
5.59
517
471
330
293
2449
2080
920
629
560
496
487
425
230
1 77
21 18
1219
761
689
649
633
563
500
479
374
D-3
-------
Table 0-2 (Continued)
State Emissions —1988
Slate
MS
MT
NC
NO
NE
NH
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
3
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
Chemcil
Ammonia
Toluane-
Cartwnyl Sulfide
Methyl Efflyi Ketone
Xylene (Mixed isomers)
Dichloromemane
TnchloroeOiylene
Median*
1,1,1-Tnchloroelhane
Methyl isobutyi Ketone
Hydrogen Fluoride
Xylene (Mixed Isomers)
Toluene
Propytene
Methanol
Formaldehyde
Chlorine
Lead Compounds
Ehyiene
Ammonia
Methanol
Toluene
Oichloromethane
Acetone
Methyl Ethyl Ketone
1,1,1-Trichloroethane
Hydrochloric Acid
Ammonia
Xylene (Mixed Isomers)
p-Xylera
Methyl Ethyl Ketone
Xylene (Mixed Isomers)
Toluene
Acetone
Freonm
1,1,1-Trlcnioroethane
Styrene
Methyl Isobutyi Ketone
Ammonia
Propytone
Toluene
Ammonia
Dichlorometnane
Xylene (Mixed Isomers)
Freon1l3
1,1,1-Titchioroethane
Methyl Ethyl Ketone
Acetone
Methanol
Methyl Isobutyi Ketone
Oicnlorane thane
Toluene
1.1,1-Tnehloroethane
Freon113
Methyl Ethyl Ketone
Chlorine
Chlorine Dioxide
Xylene (Mixed Isomers)
Methyl isobutyi Ketone
Trichloroeihylene
Total
Ennnon No 01
(Ib/yr) Enntten
16,271,827
7,567,434
6.498,000
5.005,205
4.463,188
3.655,832
2,612,609
1.747,770
1,291,750
1.182,594
433,639
296.060
199,890
183.400
151,040
126.421
105,790
84.250
79.300
78.650
18.703.269
18.327.060
8.026.515
7.458.996
6,349.686
6.078.814
3.583.078
3.324,979
2.657.280
2.197.200
226.511
203.073
148.094
134,695
99,245
80,872
46.500
44.681
40.250
35.281
5.275.978
4,165.167
1.417.869
1.219.344
997.787
984,064
690.037
539.687
519,706
491.764
2.279,520
1.905.223
1.450.686
1.308.103
944,199
690.500
640,000
496,820
473,610
334.646
41
58
2
20
56
19
9
28
32
14
5
5
5
3
4
4
4
2
3
5
188
187
57
ISO
136
ISO
52
103
120
2
S
6
3
1
1
3
3
2
2
1
24
28
6
28
8
26
13
16
7
10
15
21
42
30
21
2
1
12
6
4
%OI
SliU
~ Total
2730
1270
1090
840
749
613
438
293
217
198
1833
1251
845
775
638
534
447
356
335
332
1931
1892
829
770
656
628
370
343
274
227
1786
1602
1168
1062
783
638
367
352
317
278
2834
2237
762
655
536
529
371
290
279
264
1907
1594
1214
1094
790
S78
S3S
416
396
280
State
NJ
MM
NV
NY
OH
OK
flank
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemol
Toluene
Acetone
Methyl Ethyl Ketone
Methanol
Xylene (Mixed isomers)
n-Butyl Alcohol
1,1,1-Tnchloroethane
Oichloromethane
Glycol Ethers
Freonn3
Sullunc Acid
Freon113
Copper Compounds
1,1,1-Tnchloroethane
Toluene
Acetone
m-Xylene
Benzene
Methyl Ethyl Ketone
Formaldehyde
Toluene
Chlorine
Acetone
Xylene (Mixed isomers)
Freon113
Methyl Ethyl Ketone
Hydrochloric Acid
Ammonia
Silver
Manganese
Oichloromethane
Toluene
Methanol
Acetone
1,1,1-Tnchloroethane
Hydrochlonc Acid
Freonm
Xylene (Mixed Isomers)
Tnchloroethyiene
Methyl Ethyl Ketone
Ammonia
Acetone
Toluene
Xylene (Mixed Isomers)
1,1,1-Tnchloroethane
Methyl Ethyl Ketone
Methanol
Glycol Ethers
Hydrochlonc Acid
n-Butyl Alcohol
Ammonia
Toluene
Methanol
Nitric Acid
Xylene (Mixed Isomers)
1.1,1-Trichlonetham
Methyl Ethyl Ketone
Hydrochloric Acid
Tetrachloroetnylene
Dichloromethane
Total
Emanni No 01
(IWVO Emani
7,882.440
5.435.248
4.152.677
2.658.2S7
2.497,172
1. 596.554
1.508.132
1.345,484
1.273,828
1.173,926
591,841
331,688
329,475
322.700
181.575
106.787
41,501
35.784
27,700
20.335
229,883
149.791
79.479
54.700
42,662
26,814
20,370
18.356
14.968
9.200
14,999.968
13,548,213
11,165.504
8.383.721
7.868.722
5.830.336
4.844,357
3,733,808
3.710.267
3.589.746
15.423.842
14.311.045
13.293.096
13.219,899
12.268.881
9,799.267
8,314.645
5.563.155
4,596560
4.306.727-
9,653,541
3.505,819
3.272.368
3,250,779
2.625,949
1,691.142
1.482,394
1.195,682
1,093,767
1.015,085
183
107
101
107
116
68
111
64
69
38
9
6
2
7
8
7
1
3
1
1
4
3
4
3
1
1
8
2
1
2
70
163
99
91
169
103
81
126
74
87
123
140
270
236
266
180
113
102
161
84
27
39
18
13
36
41
26
10
9
12
SOI
Slate
Total
2044
1409
1077
689
647
414
391
349
330
304
2774
15 55
1545
1513
851
501
195
168
130
095
3338
2175
1154
794
619
389
296
267
217
134
1560
1409
1161
872
818
606
504
388
386
373
1107
1027
954
949
880
703
S97
399
3.30
309
2710
984
919
913
737
475
416
336
307
285
D-4
-------
Table 0-2 (Continued)
State Emissions —1988
Slate
OR
PA
PR
Rl
SC
SO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemcal
Metnanol
Acetone
Toluene
Ammonia
Chlorine
Tncnioroetnyiene
Slyrene
Methyl Ethyl Ketone
Freon 113
1,1.1-Tricnloroetnane
Toluene
1,1,1-Tnchioroethane
Ammonia
OicMorometnane
Metnyi Ethyl Katone
Xyiene (Mixed isomers)
Acetone
Benzene
Tnchloroelhylene
Methanol
Dicniorometnane
Acetone
Toluene
Freon 113
Carbon Disunite
Metnyi Tert-Butyl Effier
Mettianol
Benzene
1.1,1-Tnchloroettiane
Metnyi Ethyl Ketone
Toluene
Acetone
1.1,1-Tnchloroettiane
Methyl Ethyl Ketone
Tnchloroethyiene
Oichloromethane
Freon 113
Xyiene (Mixed Isomers)
Tetrachloroetnylene
Styrene
Methanol
Toluene
Acetone
1.1,1-Tnchioroetnane
Methyl Ethyl Ketone
Oichiorome thane
Ammonia
Xyiene (Mixed Isomers)
Hydrochloric Acid
2-Memoxyetnanol
Xyiene (Mixed Isomers)
Freon 113
Toluene
1.1.1-Tnchloroe thane
Metnanol
Methyl Ethyl Ketone
Ammonia
Acetone
Formaldehyde
Styrene
Tout
Eminem No 01
(Ibfyr) Eminem
3.765,394
3.225,301
2.357.909
1.238.005
1.055.850
986,373
924.211
895.277
745.622
709.976
17,372,493
11,948.334
7,092.473
6,441,277
5.652.515
5.029,541
3.643,633
3.189,504
2.941,983
2.901.776
3.668.965
2.553 871
1.724,066
1,473.892
1.101.100
778,271
753.838
513484
367.497
344,955
1.562,939
1.433,776
890.105
703,371
679.495
548.342
389.229
319.048
307.799
227.569
15.418.860
8.372.412
8.146,426
4.977.776
3.188.075
2.688.533
2.686.257
2.461.812
2.178.824
1.976,000
589.152
527.316
459.958
156.252
149.269
146.603
131.800
128.261
89.200
52.238
27
40
41
31
18
12
13
24
15
24
204
178
113
72
128
188
127
23
60
107
22
30
23
25
1
2
33
4
22
10
19
24
37
16
35
15
18
14
15
7
69
60
42
61
39
32
54
57
40
2
12
5
4
5
3
4
3
3
1
3
\OI
Sine
Total
1802
1S44
11 29
593
505
472
442
429
357
340
1896
1304
774
703
617
549
398
348
321
317
2340
1629
11
940
702
496
481
327
234
220
2014
1847
1147
906
875
706
501
411
397
293
2311
1255
1221
746
478
403
403
369
327
296
2357
2109
1840
625
597
586
527
513
357
209
Slate
TN
TX
UT
VA
VI
VT
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Acetone
Caroon Bisulfide
Toluene
Metnanol
Caroonyl Sulfide
i.i.i-Tnchioroethane
Ammonia
Xyiene (Mixed isomers)
Oichloromethane
Tnchloroethyiene
Ethyiene
Methanol
Toluene
Ammonia
Propyiene
Xyiene (Mixed isomers)
Acetone
1,1,1-Tnchloroethane
Benzene
Metnyi Ethyl Ketone
Cnionne
Hydrochloric Acid
1.1,1-Tnchlo methane
Dichloromethane
Freon 113
Sulfunc Acid
Ethyiene Oxide
Toluene
Xyiene (Mixed Isomers)
Ammonia
Caroon Disulflde
Metnanol
Acetone
Toluene
Methyl Ethyl Ketone
Xyiene (Mixed Isomers)
Hydrochloric Acid
1,1.1-Tnchloroethane
Dicniorometnane
Chloroform
Benzene
p-Xylene
Toluene
Xyiene (Mixed Isomers)
Ethyioenzene
Cyciohexane
1 ,2.4-Tnmethyl benzene
Naphthalene
Anthracene
Cobalt Compounds
Toluene
1.1,1-Tnehioroethane
Xyiene (Mixed Isomers)
Freon 113
Metnanol
Metnyi Ethyl Ketone
Methyl isobutyl Ketone
Acetone
n-Butyl Alcohol
Oichloromethane
ToUl
Emmoni
(Ibn/r)
39.420,815
22.720.568
14.776,431
11.598.684
8.500.000
5,586.474
4.858.248
4.331 548
2.741.210
2.104,305
23,603.963
13.825.728
12.492.624
11.937.810
11.310.113
11,065.051
7.803.883
6,480,182
6,465.129
6.225.654
102.220.100
9.247,610
3.425,628
1.460.532
727.418
724.949
617.080
577.199
383.836
355,179
34.053.000
22.326,101
17.298,179
12.447,609
6,883.313
6.079.291
3.649,752
2.295.936
2.010.524
1.804.850
600.000
270.000
265.000
240.000
74.000
24.600
10.560
2.450
2.102
500
490.737
260.877
184.164
116.847
103.259
90.391
80.984
51,917
27.393
16.906
No 01
iminera
77
5
110
59
1
73
52
99
34
19
83
184
226
199
83
230
138
153
86
126
10
17
22
8
15
18
2
18
20
9
2
76
81
108
77
82
32
62
27
4
1
1
1
10
14
8
5
5
6
5
6
3
2
%OI
Stale
Total
2812
1621
1054
827
606
399
347
309
196
150
1232
722
652
623
590
578
407
338
338
325
8415
761
282
120
060
060
051
048
032
029
2762
1811
1403
1010
558
493
296
186
163
146
4025
1811
1778
1610
496
165
071
016
014
003
3230
1717
1212
769
680
595
533
342
184
1 11
D-5
-------
Table 0-2 (Continued)
State Emissions —1988
Stile Rank
WA 1
2
3
4
S
6
7
8
9
10
Wl 1
2
3
4
5
6
7
8
9
10
Chemcil
Mettianol
Ammonia
Toluene
Acetone
Methyl Ethyl Ketone
Hydrogen Fluoride
Chloroform
Xylena (Mixed Isomers)
Dfchlorometfiane
1,1,1-Titchloroetriane
1,1,1-Tncmoroettiane
Xylene (Mixed Isomers)
Toluene
Methanol
Methyl Ethyl Ketone
Glycol Ethars
Acetone
Hydrochloric Acid
Dlchloromethane
n-Butyl Alcohol
Toul
Emmm No Of
(Ib/yr) EmiflBn
3.126.900
2.951.303
2,835,490
2.514,163
2.255.697
1,760.020
1.611.980
1.528.904
1,388.395
1.322.113
5.941.586
5,229,960
4.773,831
3,531,867
3.229.343
2.859.223
2.574.183
2.300.334
1.615.333
1,393.770
31
45'
44
61
42
14
10
39
21
33
141
107
121
60
79
63
64
68
51
38
%«
sun
Toul
1063
1003
964
855
767
605
548
520
472
449
1304
1148
1048
775
709
627
565
SOS
354
306
Slate Rank
WV' 1
2
3
4
5
6
7
8
9
10
WY 1
2
3
4
5
6
7
8
9
10
Chemical
Acetone
Methanol
Toluene
Dichloromettiane
Ammonia
Benzene
Hydrochloric Acid
Chloroform
Ethylene Glycol
Styrene
Ammonia
Ammonium Nitrate (Solution)
Toluene
Xylene (Mixed Isomers)
Methyl Tert-Butyl Ether
Propylene
1,2,4-Tnmetriylbenzene
Benzene
Phosphoric Acid
Glycol Ethers
Total
Eflwum No Of
(IWyr) Emflera
5.401.774
4,626.622
2.443,446
1.788.397
1.679,157
1,540.199
1.256.145
1.194.396
1.163,041
1.018,642
598,411
426,722
408,542
364.604
217.750
95,930
94,148
83,597
78,499
74,500
17
21
24
9
27
5
25
3
12
9
4
1
5
7
2
4
3
4
1
2
SOI
SUM
Total
1476
1264
658
489
459
421
343
326'
318
278
2070
1476
1413
1261
753
332
326
289
272
258
D-6
-------
TABLE D-3
Regional Hot Spots
— 19883-DIGITZIP CODES-
3 fail
ZIP Cooe
840
775
703
376
365
226
776
146
707
244
480
996
286
377
314
606
371
284
391
553
241
723
356
706
465
700
402
481
6
440
630
458
452
315
604
463
490
420
601
381
395
SSI
473
70
756
476
261
ISO
430
672
SOB
UT
TX
LA
TN
AL
VA
TX
NY
LA
VA
Ml
AK
NC
TN
GA
IL
TN
NC
MS
MN
VA
AR
AL
LA
IN
LA
KY
Ml
PR
OH
MO
OH
OH
GA
IL
IN
Ml
KY
IL
TN
MS
MN
IN
NJ
TX
IN
WV
PA
OH
KS
No 01
Raeee No 01
Reocia fasMes
1S4
1.143
66
143
163
61
241
215
337
60
371
18
415
77
78
788
142
100
34
137
100
94
184
211
254
319
299
377
240
425
226
209
338
101
418
306
248
126
414
206
153
206
187
664
166
49
123
205
168
147
37
125
14
30
23
17
26
52
39
21
100
3
127
33
22
274
38
23
16
60
26
27
43
27
94
40
60
103
81
128
61
45
114
26
100
65
87
21
1S8
63
21
57
56
213
40
7
14
47
44
31
Dig
EiTvs&ons
(«M
114570.350
36.279.834
1.418.606
19.288.620
48.844.932
39,641.648
14.164.991
19,961.588
12.236,944
20.113.830
18,237,968
276.935
17.779,009
19.903,936
17.305.213
14.920,127
15.991.370
16.531.178
3.049,386
17.518,991
3.979,558
3.376,051
14.129,186
6.586.010
12.847.654
8.284.614
13.660.771
11.167,672
9.430,574
11,434,806
10,613,249
5.422.771
8.197,277
10.569,427
6,505,152
10.651,136
9.708,030
8.219.498
8.219.047
5,352,513
9,675.363
9.029.635
6.420,665
8.115.684
5.196.015
10.231.228
9.273.001
4.749,926
6.416.322
9,801.662
loial ZIPS
Emisions 01 folii IRI
(13/yl Elisions
115.881,488
64.007.392
56.473,822
54,538.069
49,687,881
40,129374
26.766399
25.270,117
21.406,082'
21.085,475
20,978.288
20.958.860
20,591,196
20.146,764
19.619.444
19.362897
19.000,092
18,714,468
18.665.403
18,320.048
17,041,405
16.822360
16,681 444
16.004.134
15.327.031
15.249346
15.080.789
14,991.052
13,266284
12.883278
12.877361
12.765117
12.647,686
12.520.175
12.004279
11.964.373
11,888,821
11.780,417
11,586281
11.518.473
11.141.724
11.08S.546
11.020,420
10.983,882
10,935,175
10.891,949
10,814,62$
10.562,357
10.518,779
10.374,392
445
246
217
209
191
154
103
097
082
081
080
080
079
077
075
074
073
072
072
070
065
065
064
061
059
059
058
058
051
049
049
049
049
048
046
046
046
045
044
044
043
043
042
042
042
0.42
041
041
040
040
3 O'Jil
ZIP Cone
441
479
295
190
494
294
388
902
299
550
619
740
232
191
397
317
768
852
456
770
779
296
238
945
631
297
64
681
467
287
495
777
272
245
333
527
251
610
260
729
438
215
486
18
462
370
457
600
622
544
Saw
OH
IN
SC
PA
Ml
SC
MS
CA
SC
MN
IL
OK
VA
PA
MS
GA
TX
AZ
OH
TX
TX
SC
VA
CA
MO
SC
CT
NE
IN
NC
Ml
TX
NC
VA
FL
IA
WV
IL
WV
AR
OH
MD
Ml
MA
IN
TN
OH
IL
IL
Wl
No 01
Release No 01
HBDOrs FiQIiltGS
534
156
122
211
279
112
76
395
25
147
52
93
119
246
76
94
18
159
91
431
101
271
95
361
414
112
291
105
179
127
231
141
245
155
118
98
73
135
107
111
35
22
ISO
216
261
138
63
479
102
113
173
40
36
57
80
30
33
133
4
29
16
27
40
63
24
33
4
55
22
123
13
97
25
100
127
28
105
33
73
39
60
18
83
53
46
28
5
43
26
37
11
4
27
72
73
48
12
162
26
38
HID
Emissions
o«w
8.114501
9.029.850
7.502.765
7,075.882
6.180.158
8,124.704
8,697.818
6,408.825
6,494.945
7,010.264
7.474.508
4.485.330
7.641.029
6.905.982
7.961.485
6.663.441
6.735.875
Z980.983
5.525,396
4,859.905
3,201,284
6.976.541
5.790.741
4.044.616
7.234.719
3.758.799
6,581.455
3,995.562
6.778.432
6.597,271
5.065.747
3.095.783
6,480.338
6,838,448
1.042.863
3,584,410
Z033.708
5.792.802
5.899.671
5,993.786
730,626
5.754.379
5.905.372
5.096.883
4.704,043
5,585,148
3.596.757
5.137,159
5,081,398
5,278.059
ran i\r\
Emissions (K loin IN
(IWyi) Eniss.ors
10001.259
9.868.296
9.760.995
9,579.330
9.377.375
9.363.488
9,234.642
9.195.969
9.130.741
8.860521
8.842.188
8.736.807
8.604,479
8,566.811
8.551.668
8.543,500
8.517.569
8.445,774
8,398,661
8.341.255
8237,163
8.180.931
7.998.412
7,983,561
7.951.595
7,823,312
7,725.420
7.656.474
7630.580
7.579.561
7.563,897
7.479365
7.454.921
7.278.323
7.096,668
6,960,563
6,909,486
6.846.394
6.827.096
6,821.243
6.817,017
6.751.081
6.724.163
6,686.532
6,578.291
6,495,668
6.493.644
6.394.520
6.353.397
6.338.398
038
038
037
037
036
036
035
035
035
034
034
034
033
033
033
033
033
032
032
032
032
031
031
031
031
030
030
029
029
029
029
029
029
028
027
027
027
026
026
026
026
026
026
026
025
02S
025
025
024
024
20,441 5,513 1,009,831,401 1,450,411,718 5564
D-7
-------
TABLE 0-4
Regional Hot Spots
—1988 COUNTIES-
Couniy
Tooele
Ascension
Mobile
Hams
Sullivan
Cook
Los Angeles
warren
Monroe
Kenai Peninsula
Brazona
Chatham
Jelterson
Aileghany
Hamblen
Mcleod
Mississippi
SI James
Caicasieu
JeKerson
Yazoo
Wayne
Hamilton
Giles
Shelby
Kanawna
SI Louis
CoiDefl
Lake
Calawba
Orange
Ramsey
Seagwick
Cuyanoga
Orange
Allegheny
Marshall
Middlesex
Humphreys
Hampton
Oakland
Kalamazoo
Philadelphia
New Haven
Brown
Niagara
Mammb
King
Harrison
Allen
Siaie
UT
LA
AL
TX
TN
IL
CA
VA
NY
AK
TX
GA
TX
VA
TN
MN
Afl
LA
LA
KY
MS
Ml
OH
VA
TN
WV
MO
AL
IN
NC
CA
MN
KS
OH
TX
PA
KY
NJ
TN
SC
Ml
Ml
PA
CT
TX
NY
Ml
WA
TX
OH
No 01
Release
Reams
8
137
179
1,158
103
1.S36
1.868
27
245
18
232
78
308
15
50
26
39
46
186
300
2
529
423
7
222
140
363
55
213
138
553
189
149
548
61
359
78
443
18
16
221
80
245
346
17
155
180
260
79
85
No 01
Faci lines
4
15
27
223
14
517
624
4
61
3
22
22
32
3
19
7
13
8
21
61
1
130
119
1
69
13
110
13
42
51
206
51
33
178
to
74
7
116
4
3
52
20
62
108
3
37
43
109
12
16
HAP
Emissions
(IB/M
109.868,022
5.614,188
49.711.651
29.203,555
9,074,646
29.546.827
28.879,726
34.579,400
20.640,798
276,935
10.555,741
17,306,213
9.172,464
18.228,664
17.099,246
16.302.055
2.888,492
440,575
5,877,986
13,660821
1800
11.100,822
8.679,783
999,900
5.683,233
5.843,650
9.547,624
9.191,987
9,931,779
9.924,097
6,743,562
8.817,749
9,601,662
8.269.742
3,957,757
6,287,812
6.984,461
8.083,889
9.147.621
6,483,210
7.448,081
7.327,296
6.905,982
7.220,616
6.664,738
7.084,094
7.635.864
6,505,866
3.453.737
1,535.294
TOBI
County H
Emiuors 01 Toll! IRI
(in/YD
109.868.272
51,237547
50.581.837
47,859.672
42.806.100
38.078.024
37.733.455
34.639.208
26.091.597
20.958,860
19.938.165
19.619.444
19.581.551
19.009.264
17,253.775
16.567.333
16.140,137
15.594.639
15.242.628
15.080,839
14,370.800
13.899.067
13.284,590
12.014.901
11.909.741
11,820.317
1t.521.3SO
11.244.143
11.095.184
10.821,531
10.744,289
10.740.798
10,374.867
10.215828
10,085.761
9,985.323
9,880.380
9.737.716
9.726.988
9.114,210
8.812.980
8.678.797
8.584.933
8.505.570
8.446.432
8,437,803
8.317.747
8,294.019
8.287.857
8.258.674
Emis.ons
421
197
194
184
164
146
145
133
too
080
076
075
075
073
066
064
062
060
058
058
OSS
053
051
046
046
045
044
043
043
042
041
041
040
039
039
038
038
037
037
035
034
033
033
033
032
032
032
032
032
032
Couny
Kent
Posey
East Baton Rouge
Erie
Gaiveston
Broome
Giyrm
Dallas
SI Charles
Brunswick
Middlesex
Milwaukee
Tarranl
Onondaga
Yoik
Bucks
Maricopa
Harrison
Coshocfon
Barceionela
Lowndes
Allegany
Manon
Polk
Lucas
Washington
New Hanover
Harttord
iberviiie
Union
Richiand
Sebaslian
Kosciusko
New Castle
Richmond
San Diego
Hennepm
Davidson
Hamilton
Forsylh
Tippecanoe
Franklin
Sail Lake
Ollawa
Henry
Santa Clara
Gmndy
Peona
Lancaster
Frederick
Sait
Ml
IN
LA
NY
TX
NY
GA
TX
LA
NC
MA
Wl
TX
NY
SC
PA
AZ
MS
OH
PR
MS
MO
IN
FL
OH
OH
NC
CT
LA
OH
SC
AR
IN
OF.
GA
CA
MN
TN
TN
NC
IN
OH
UT
Ml
VA
CA
IL
IL
PA
VA
No 0
Release
Rents
260
33
165
203
193
66
37
434
94
26
378
437
234
121
56
143
292
22
26
44
33
17
263
102
184
63
38
259
113
36
65
97
49
158
61
185
245
80
112
89
83
205
161
98
84
362
56
52
144
27
No Of
FlCllilB
68
2
22
83
16
20
7
146
9
3
137
124
93
49
16
44
114
6
7
7
10
3
74
41
48
12
10
93
13
6
17
29
16
38
23
61
113
28
34
30
18
62
44
27
20
133
9
18
63
10
HAP
Emssons
-------
TABLE D-5
Air Emissions By U.S. Industry
— 1388 —
2D:gil
SIC Co
0
1
2
2
3
6
«
7
10
12
13
14
16
17
18
19
20
21
22
23
24
25
26
27
23
29
30
31
32
33
34
35
35
37
39
39
oe US Inoiftjy
Food
Tobacco
Textiles
Apparel
Lumber
Rjmilure
Pulp A Paper
Punting
Chemicals
Petroleum Helming
Rubber. Plastics
leather'
Slone, Clay. Glass
Primary Melals
Fabricated Metals
Non-Elect Machinery
Electrical EQuipment
Transport Equipment
Instruments
Misc Manulacluring
No 01
Eiflitsra
50
21
1
1
4
9
1
1
1
1
1
1
7
2
4
3
1
960
19
320
38
507
490
595
339
3,729
334
1.437
121
497
1,518
2.664
994
1.630
1.173
378
384
No Of
tease
Room
97
49
2
1
6
12
1
1
1
1
6
1
13
2
6
9
1
1.399
40
589
66
1.321
1.733
1.952
621
17.676
2.623
3.404
328
1.254
5.073
6.629
2.301
4.517
4.296
937
862
HAP
Eraaions
Wl
1.493.056
235,986
0
0
630,327
584.441
3
818
48.011
0
101.700
83,300
500
11.989
44.300
348,774
0
7.225,204
1.173,552
39.088,693
1.369,400
28,983,286
55,982,415
225,084,584
61,232.186
478,456.946
51,796,460
154,291,452
10,271,508
21.351,025
209,395,306
112.359,513
56.034,135
93,874,770
182.815,299
39.924.633
26.853.075
loa tesy*
[mounts 01 FOBI
(la/yi) IRIf.-njsiors
1,675.147
403,921
500
1.405
696.327
814.147
3
818
48.011
1.061,192
104,200
83.300
224.894
11.989
84.300
388.330
25.000
22.350.401
1.817.354
43.684.491
1,665.803
33,142.943
64.818.870
270,398.044
64,998.394
854,587.986
75,530.418
192.919.849
14,850.396
28,603.514
253,267.435
142.788.595
70.091.651
127,625.211
236,353.758
58384.902
32306.637
006
002
000
000
003
003
000
on
ox
004
000
000
001
on
000
001
000
086
007
166
006
127
249
1037
249
3279
290
740
057
110
972
548
269
490
907
224
124
No 01
2 Ocu No 01
SIC Coot U S Inouuy ETJIEII
42
43
44
45
46
47
16
49
50
51
52
55
57
56
55
73
75
76
78
79
80
82
84
86
87
88
89
96
97
98
99
CO
NA
2
3
2
5
1
1
3
10
15
52
1
1
1
1
1
25
1
5
1
1
2
2
1
2
S
1
3
1
7
1
8
2
14
HAP
fleeze
ROD'S
2
4
19
15
1
1
3
20
23
193
1
1
3
5
1
54
2
13
1
2
2
2
6
12
37
2
12
5
21
4
19
2
18
hai
EnvaOTJ
(inflf'1
0
42.562
41,510
101,344
8
46.500
750
3.633.669
151,757
538.397
250
0
750
'1.031
20000
208.910
45.367
83.003
34.199
82.78)
8.300
17967
92.000
42.996
27,492
41.300
16.199
500
535.561
14.819
850.655
0
1.774.877
IrcisBjl
toilers Q! Icui
(lo/yr) IRI E.-iaofs
2.100
43062
325610
118512
a
46.500
750
3.633.379
199.968
1.063098
250
1872
Z2SO
1.233
20.000
370.965
45.367
110078
34.199
83.531
8,300
17,967
95.000
65.632
523,169
41,300
16.208
1,750
806,277
16,246
1.232,219
34.420
1.821.403
000
0,00
001
000
oco
oco
oco
014
001
004
oco
oco
oco
oco
000
001
000
oco
000
000
000
000
000
000
002
000
000
000
003
oco
005
000
007
18.418 56.337 1.869,609,203 2,606.642759
10000
(Note Only SiCs 20-39 are required to report to TRI)
D-9
-------
TABLE 0-6
Industrial Emissions
-1988 —
2 DIJII
SIC CMC
28
26
33
37
30
34
36
29
35
27
25
38
22
24
39
32
20
31
49
NA
21
23
99
51
10
3
97
2
87
0
18
73
44
14
No 0
Eminn
3,729
595
1.518
1,173
1,437
2,664
1.630
334
994
339
490
378
320
507
384
497
960
121
10
14
19
50
38
8
52
1
9
7
4
6
21
3
25
2
7
KAP
Eir ssiors
478,456946
225.084584
209,395.306
182,815,299
154,291.452
112.359.513
93.874.770
51,796.460
56.034.135
61,232,186
55,982.415
39.924,633
39,088,693
28,983.286
26,853.075
21,351,025
7,225,204
10,271.508
3.633.669
1.774,877
1,173.552
1.493.056
1.369.400
850.655
538.397
0
584.441
535,561
630,327
27492
235.986
348.774
208910
41.610
500
[mi
Emissions
(IB/YO
854,587,986
270.398,044
253267,435
236.353.758
192.919,849
142.788,595
127625.211
75.530,418
70.091,651
64.998.394
64,816.870
58.384.902
43.684.491
33.142.943
32.306.637
28,603,514
22.350.401
14.850.396
3.683.379
1.821,403
1.817.354
1.675.147
1.665803
1.232.219
1.063,098
1.061.192
814.147
806.277
696.327
523.169
403.921
388.330
370.965
325,610
224,894
Industry %
01 loin m
Emissions
3279
1037
972
907
740
548
490
290
269
249
249
224
168
127
124
110
086
057
014
007
007
006
006
005
004
004
003
003
003
002
002
001
001
001
001
2 D^
SCCoce
50
45
76
12
84
17
79
13
86
7
47
75
43
88
CO
78
19
65
82
98
89
16
80
57
42
55
96
2
58
'6
48
1
52
46
6
No 01
15
5
5
2
1
1
1
3
1
2
1
1
1
2
1
3
2
2
1
2
1
1
1
1
1
3
1
1
1
1
HAP
Emissions
151.757
108.344
83.003
101700
92.000
44.300
82.781
33,300
42.998
48.011
46.500
45.367
42.562
41.300
0
34.199
0
20,000
17,967
14,819
16,199
11.989
8,300
750
0
0
500
0
1,031
818
750
0
250
8
3
Emissions
199.968
118.512
110,078
104.200
95000
84.300
83.531
83.300
65.632
48,011
46.500
45.367
43.062
41.300
34.420
34.199
25.000
20,000
17,967
16,246
16,208
11.989
8.300
2.250
2.100
1,872
1.750
1.405
1.233
818
750
500
250
8
3
tacts, -yl
a tail m
Emsions
001
000
000
000
000
000
000
0,00
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
on
000
000
000
000
000
000
000
000
000
000
000
18,418
1,869,609,203
2.606.642,759
10000
D-10
-------
TABLE 0-7
Air Emissions For The U.S. Chemical Industry
-1988-
4 Oigu
SlCCoce
800
2810
2812
2813
2814
2815
2816
2818
2819
2820
2821
2822 ,
2823
Tout
5.447,588
69,439
27.869.604
8.437.048
1.500
179,411
20.407,659
11,000
39.879.083
97.206
101.363,368
22,648,216
87.327,427
4 Digit
SIC Con
2824
2830
2631
2832
2833
2834
2835
2836
2837
2840
2841
2842
2843
ion
Emissions
16.837.546
312388
579.511
2.147.642
23.272573
29.514.654
95,193
33,670
526
18.651
875,116
881,738
6.710.609
4D
-------
TABLE 0-8
Top Industrial Emitters
—1988 4-DIGIT SIC CODES-
Isai
E-issions
Rar< SIC l'3/yr)
1 2869 179381.453
2 2873 159,132268
101
2 Digit
SCCooe Rini C.iencai
2099 1 Acelone
2 Melhanol
3 Elhyiene
4 Toluene
5 Chloromelhane
6 Ammonia
7 Propylene
8 Elhyiene Glyool
9 Benzene
10 Hydrochloric Aod
1862 1 Ammonia
2 Melhanol
3 NilncAad
4 Prooylene
lo'ji lOiro.ai
E-'«iors 2 DICI'
(ivyr) Sfc
50289.650
28100.935
16520787
6870.401
6.365.690
6.245262
5215.010
4.627.869
4,301.205
3983.256
142.355441
7,196.576
3.835,677
2.707.400
5 Ammonium Nilrale (Solution) 1,942128
3 3339 115,557.844
4 2821 101 363.368
5 2611 88574443
6 2823 87,327.427
6 Aceioniinie
7 SulluncAdd
8 Acrylomlnle
9 Hydrogen Cyanide
10 Elhyiene Glycol
4563 1 Chlorine
2 HydrocnioncAdd
3 Ammonia
4 Melhyl isobutyl Kelone
5 Hydrogen Fluoride
6 Lead Compounds
7 Telracnioroeinyiene
8 1 1,1-Tnchloraelhane
9 Zinc Compounds
10 Lead
1166 1 Caroon Disunite
2 ElUylene
3 Oicnioromelhane
4 Melhanol
5 Propytene
6 Slyrene
7 Toluene
8 Chlorobenzene
9 Acelone
10 Chbroeinane
32 76 i Melhanol
2 Chlorine
3 Chloroform
4 Chlorine Dioxide
5 Acetone
6 Hydrochloric Add
7 SulluncAod
8 Toluene
9 Ammonia
10 Xylene (Mixed Isomers)
1022 1 Carbon Disullide
2 Acelone
3 Melhyl Ethyl Kelone
4 Benzene
5 Caroonyi Sullide
6 Oicnioromeinane
7 Ammonia
8 Memanoi
9 Formaldehyde
10 Vinyl Aceiaie
241,000
204.594
191000
132400
94250
102165.751
7731.376
1857631
1.745.035
54S.785
536.386
275.725
174.847
118.577
101.250
16.658.316
15601809
9336.923
9200.960
4.588.254
4488.242
4254783
2712769
2.695 195
2.137800
37.295846
12.322575
11.091.636
8.813.232
7036307
6.562.874
2,355.077
1.254500
991.496
365.500
81851.000
3,463.675
661.126
562.982
410.000
168434
100,000
66.322
31.211
2936
588
329
193
080
074
073
061
054
050
047
1666
034
045
032
023
003
002
002
002
001
4034
305
073
069
022
021
Oil
007
005
004
195
133
109
108
054
053
050
032
032
025
1379
456
410
326
260
243
087
046
037
014
958
041
008
007
005
002
001
001
000
000
Rar< SIC
7 3079
6 2911
9 3711
10 2621
11 3312
12 2511
Ten \a
E- ss.ors 2 Oi;n
i,a/V) SIC Cone Rin<
71505551 3706 1
2
3
4
5
6
7
a
9
10
71225233 943 1
2
3
4
5
6
7
8
9
10
68315256 289 1
2
3
4
5
6
7
a
9
10
54756547 2025 1
2
3
4
5
6
7
8
9
10
46701619 1844 1
2
3
4
5
6
7
3
9
10
41656.475 6427 1
2
3
4
5
6
7
a
9
10
C.ier.cai
Acelone
Melhanol
Dichloromelhane
Methyl Elhyl Kelone
Toluene
Slyrene
1 1 1-Tnchloroelhane
2-Melhoxyelhanol
Carbon Disultide
Ammonia
Toluene
Ammonia
Benzene
Methyl Elhyl Kelone
Xylene (Mixed Isomers)
Propylene
Elhyiene
Cyciohexane
Melhyl Ten-Butyl Elder
Elhylbenzene
Xylene (Mixed Isomers)
Glycol Ethers
n-Butyl Alcohol
Methyl Elhyl Kelone
Toluene
Melhanol
Acelone
Methyl isobutyl Kelone
1,1,1-Tnchloroeltiane
Oichloromelhane
Melhanol
Hydrochloric Acid
Chtorolorm
Cnlonne
Acelone
Chlorine Dioxide
SutluncAod
Ammonia
NilncAad
Xylene (Mixed Isomers)
Benzene
Ammonia
1 i.l-Tncniorcelhane
Hydrochloric Add
Zinc Compounds
Toluene
Xylene (Mixed Isomers)
Zinc (Fume Or Dust)
Manganese Compounds
Naphthalene
Toluene
Melnanol
Xylene (Mixed Isomers)
Melhyl Elhyl Kelone
Acelone
n-Bulyt Alcohol
Melhyl isobutyl Kelone
Glyool Ethers
1,1,1-Tnchloroelhane
DK2-Elhyihexyi)Phthaiale
loai '
Cruuiorj
(iir)
18415,183
10548393
8 771 651
8251654
5020505
3133366
2,763836
2442523
2287,750
1,835203
13558.439
8668.680
7.420850
7007 585
6,646.468
5744626
3.466610
2.211425
1.982123
1790.698
26,168.010
8474.423
6763.266
5,970,716
5.819611
3.750372
2689.139
2617516
2.543696
1.751057
19,060069
13,312889
5899.670
3.861 763
3,267341
2470,504
2.196.957
805,708
736750
547875
13.219.148
6.780.324
4.910.859
3,044.882
2.532.509
2,010,537
1 572.821
1.398.736
1 149769
1.103.290
12.757.917
9.072.028
5.902.095
4,551,578
3,939,136
1.977,450
1,345.334
524.978
516294
386,037
kdtai
2 O'Cii
955
547
455
428
250
162
143
127
1 19
095
1795
1148
982
928
380
761
459
293
262
237
1107
359
286
253
246
159
114
1 11
108
074
705
492
218
143
121
091
081
030
027
020
522
268
194
120
100
079
062
055
045
044
1968
14
911
702
608
305
208
081
080
060
D-12
-------
Table D-8 (Continued)
Top Industrial Emitters —1988 4-Digit SIC Codes
RlR< SC
13 2631
14 2754
IS 2B19
16 3714
Toal SOI
E.-ussions 2-Digr
(10/yr) SCCoce fcn«
41.573.638 1537 1
2
3
4
5
6
7
8
9
10
40.345,920 6207 1
2
3
4
5
6
7
a
9
10
39.879.083 467 1
2
3
4
S
6
7
a
9
10
37,650.645 1593 1
2
3
4
5
6
7
a
9
10
Cfenioi
Meihanoi
Hydrochloric tad
Acetone
Chloroform
Chlorine
SulluncAcid
Chlorine Dioxide
Ammonia
Toluene
Formaldehyde
Toluene
Methyl Ethyl Ketone
Zinc Compounds
Xylene (Mixed Isomers)
Glycol Elhers
MeinyiisoDuiyiKeione
Meihanoi
Acetone
Cyclohexane
Isopropyl Alcohol (Manutacl)
Ammonia
Meihanoi
Chlonne
SulluncAcid
Carbon Disullide
Toluene
HydiccnloncAad
Hydrogen Fluoride
Elhylene Glycol
Ptios phone Aad
Freon 113
1,1,1-Tnaiioioeinane
Xylene (Mixed Isomers)
Methyl ElhylKelone
Toluene
Tnchloroelhylene
Acetone
Tetrachloroelhyiene
Glycol Ethers
Melhyl Isobutyl Ketone
fall SOITotH
E-nissors 2-Dicil
(teW St
22.987.118
6.000.025
4.172.686
2.268.087
2.173.400
1.244.733
1.064.000
498.035
472.087
268.897
31.923.212
2.486.693
1.718.067
1.099.S6S
886,493
633.090
456.681
294.520
160.000
156.785
9.086.000
8.346473
4.653.446
2.924.446
1,877,290
-1.836.116
1.328.653
1.142462
899.837
649.911
5111961
5.048.871
4.147.695
3,913.059
3.788.574
3 168.428
2.813.385
2.123.440
1.889.477
1.105.295
850
222
154
084
080
046
039
018
017
010
4911
383
264
169
136
097
070
045
025
024
106
098
054
034
022
021
016
013
Oil
008
216
214
175
166
160
134
119
090
080
047
Rjn, SIC
17 3679
18 3861
19 3411
20 2641
loui
-------
TABLE 0-9
National Emissions Of Hazardous Air Pollutants
-1988-
Cimical
Toluene
Methanol
1.1,1-Tnchloroethane
Xylene (Mixed Isomers)
cnionne
Melhyl Ethyl Kelone
Oichloromelhane
Carbon Oisullide
Hydrochloric Add
Tnchtoroelhylene
Glycol Elhers
Telrachloroelhylene
Slyrene
Melhyl Isobutyl Kelone
Benzene
Chloroform
CarbonylSullide
Elhylene Glycol
Hydrogen Fluoride
Formaldehyde
CMoromelhane
Phenol
Ethyl benzene
1.3-Buladiene
Aceialdehyde
p-xyiene
Vinyl Acelale
Naphthalene
Cumene
Elhylene Oxide
Chloroelhane
Chlorobenzene
1.2-0ichloroelhane
Acrylonilrile
Carbon Teirachlonde
Melhyl Melhaoyiaie
Propylene Oxide
Melhyl Tert-Butyl Elher
m-Xylene
o-Xylene
Acelonnrile
Bromomelhane
M-Oichioiopenzene
1,1,2-Tncnioroelhane
Manganese Compounds
1,2,4-Tnchlorobenzene
Lead Compounds
Vinyl Chlonde
1 2-Dichloropropane
Propionaloehyde
Chloroprene
Biphenyl
Oi(2-Elhyihexyi)Phlhaiale
Cyanide Compounds
Acrylic Acid
Chromium Compounds
NO 01
Emirerj
3,766
2.283
3.630
3.240
1,244
2.373
1,577
79
2.253
892
1,354
683
1,140
970
459
164
30
858
423
724
77
530
526
145
64
46
141
373
114
193
48
64
100
too
87
206
124
86
66
63
66
33
18
29
358
47
489
47
12
14
12
150
180
210
139
713
Fotal
Emissions
285303.917
226.096.844
173.920.989
151.187,866
133,751,760
131,808.179
125,849.987
123,893.704
69,264.605
52.645,060
47,937.703
3S.S5S.S4S
32,460.559
31.435.711
30,226.580
23.871,504
20,183,072
13,569,932
12,114,046
11.891.313
11,290.415
10.363,219
7,011,058
6,654.123
6,588.209
6,003,302
5,908.341
5,086,028
4,829.829
4.762.901
4.619.442
4.569.513
4.524.929
4,195,667
3,715.421
3,427.572
3.250.269
2,896,781
2,194.146
2.064,641
2,061.891
1,941.462
1.891,419
1.741,342
1,669.121
1.533.291
1.518.309
1.436,427
1.365,844
1.296.839
1,218,426
1.210.272
1,120.956
907,726
799.178
791.922
% 0! tomical «
Tom HAPs 01 loai TRI
Emissions Emissions
1526
1209
930
609
715
705
673
663
370
282
256
190
174
168
162
128
108
073
065
064
060
OSS
038
036
035
032
032
027
026
025
025
024
024
022
020
018
017
015
012
Oil
Oil
010
010
009
009
008
008
008
007
007
007
006
006
005
004
004
1095
867
667
580
513
506
483
475
266
202
184
136
125
121
116
092
077
052
046
046
043
040
027
026
025
023
023
020
019
018
018
018
017
016
014
013
012
Oil
008
008
008
007
007
007
006
006
006
006
005
005
005
005
004
003
003
003
Cnericai E
Cresa (Mixed Isomers)
Aniline
Maieic Anhydride
p-Cresol
Oielhanolamme
1.4-Dioxane
Dimethyl Phihalale
Phlhalic Anhydride
Epicnlorohydrin
2-Nilropropane
vtnytidene Chloride
Melhoxychlor
Arsenic Compounds
Nickel Compounds
Ethyl Acrylale
Melhylenebis(Phenylisocyanale)
Toluene-2.4-Oiisocyanale
Dibuiyi Phihalale
Antimony Compounds
Allyl Chloride
Ureihane
4,4'-Melhylenedianiline
p-Phenylenediamme
Cadmium Compounds
12-Bulylene Oxide
N.N-Oimelhylanilme
2.4-Dmilrololuene
o-Cresol
Titanium Teirachlonde
Dibenzoturan
1.2-Dibromoelhane
Cobalt Compounds
1.3-Dichtoropropylene
Qumoline
Hepiachlor
Asbestos (Friable)
o-Toiuidine
1.1.2,2-Telrachloroelhane
Benzyl Chloride
Nitrobenzene
Acroiem
Hydrazme
Chloroacetic Add
Acrylamide
Benzoic Trichloride
Phosgene
Hexachtoroeihane
Phosphorus (Yellow Or While)
m-Cresol
Capian
Hexachlorocyclopenladiene
Selenium Compounds
Pentachlorophenol
Calcium Cyanamide
Ouinone
Dimethyl Sullale
No 01
91
60
154
IS
200
66
38
142
70
12
21
10
123
321
102
228
228
81
148
20
6
22
5
65
16
19
9
28
27
99
28
85
8
34
2
65
16
13
45
17
12
34
18
43
4
30
17
24
13
16
4
12
41
1
1
21
loin
Emissions
769.284
726.473
653.952
640.703
637.182
601.244
534.806
521.899
465.268
389.385
296.353
272.881
267,252
254.761
251.823
247.319
196.977
193.473
165.520
149.469
145.373
130.151
113,890
100,487
99.931
98,905
93.257
89,797
78,668
71.054
63.327
56,621
54,590
49.350
49 OSS
47.615
46.922
43,855
43.329
40.373
33.652
29.004
26,319
26,019
24,963
21.603
19.187
19.153
18.432
14.869
14.718
14.506
14,029
12,600
11,300
10,796
lOlllHAPs 01 Toil IRI
Emissions Emm.ons
004
004
003
003
003
003
003
003
002
002
002
001
001
001
001
001
001
001
001
001
001
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
on
000
000
000
000
000
000
000
000
000
000
000
000
000
000
003
003
003
002
002
002
002
002
002
001
001
001
001
001
001
001
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
•ooo
000
000
000
000
000
000
000
000
000
000
000
000
D-14
-------
Table D-9 (Continued)
National Emissions Of HAPs —1988
CSBTOI
DielhylSullaie
Hydroaumone
Mclhyl Isocyanate
Meinyiiooioe
Carbaryl
4-Nilropnenol
2,4-0
Hexachlorobennne
Vinyl Bromide
8is(2-C(i)oroelhyt)Elher
1,1-OimelnylHydrazine
Catechol
Tnlluralin
Paralhion
2.4-Oiammololuene
Methyl Hydraane
Hexachloro-t.3-Bu!adiene
Mercury Compounds
Slyrene Oxide
No 01
Erasers
18
21
3
3
16
6
15
8
2
6
4
10
11
.10
2
3
8
7
3
total
Eraiuons
(IWVO
10.627
10,334
10,175
8,944
7.923
7.8S5
7,020
4,994
4.950
4.922
4,323
3,589
3.277
3,265
2,988
2,927
2.556
2.366
2.314
HOI dismal %
lain HAPs Of IOBI mi
Emissions Emissions
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
on
000
000
000
000
ox
000
000
000
000
000
NO 01
Cwnira Ewers
o-Amsirjine
Chioramrjen
Qumtozene
Dictilorvos
Beryllium Compounds
4 4'-Meirryienebis|2-Cnioroaniline)
Chbrdane
Elhylene Thiourea
Elhyleneimme
Prooyieneimine
4.6-Dinilro-o-Cresol
undane
33'-Oicnlorobenzidine
£4,6-Tnchloroi>henol
Propoxur
Chbromelhyl Melhyl Ether
2.4,5-Tnchloroohenol
4-Aminobiphenyl
SislChloromelriyl) Ether
4
1
4
6
4
2
2
2
1
1
6
2
2
1
1
2
1
1
1
roai
Emissions
(IBM
2.293
1.418
1.064
1,050
862
750
575
500
500
500
274
258
2S5
250
250
122
91
10
1
%OI Orr/alt
Toai HAPs a IOBI mi
Emissions [miss.ors
000
000
000
000
000
000
ooo.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
1.869,609.203
10000
7172
D-15
-------
TABLE D-10
National Emissions Of 33/50 Chemicals
— 1988 —
Cnemicai
Toluene
1.1.1 Tnchioroeinane
Xylene (mixed Isomers)
Methyl Elhyl Kelcne
Dicfiloromelriane
MeltiyllsobutylKelone
Tnchlorcelhylene
Chromium Compounds
Telrachloroelhylene
Chromium
Nickel
Lead
lead Compounds
No 01
Emitters
3,766
3.630
3.240
2.373
1.577
970
692
713
683
659
590
559
489
Tool
Emission]
WO
285.303.917
173,920.989
151.187,866
131.808,179
125.849.987
31.435.711
52.645.060
791.922
35.555.545
547.745
421.570
1.168,231
1,518,309
% 01 Ciwroal %
tail 33/50 OHotlllRI
Cftcmcus Emissions
2688
1638
1424
1242
1186
296
496
007
335
005
004
Oil
014
1095
667
580
506
483
121
202
003
136
002
002
004
006
Clieiricai
Benzene
Nickel Compounds
Cyanide Compounds
Chloroform
Carton Tetrachlonde
m-Xylene
Cadmium Compounds
o-Xylene
p-xylene
Cadmium
Mercury
Mercury Compounds
NO a
Etniners
459
321
210
164
87
66
65
63
46
45
27
7
[OH
Emissions
(WW
30.226580
254.761
907,726
23.871.504
3.715.421
2.194.146
100.487
2.G64.641
6,003.302
21,925
23.395
2366
10£t 541285
% a CHerro %
loni 33*0 at lain rw
Cltcmiais Ensiors
285
002
009
225
035
021
001
019
057
000
000
000
innnn
i IS
001
003
092
014
008
000
008
023
000
000
000
inn
TABLE D-11
National Emissions Of High Risk/Early Reduction Chemicals
-1988 —
No 01
CtieniQl Eminem
Benzene
1.3-8utadiene
Elhylene Oxide
Acrylomlnle
Vinyl Chloride
Chloroprene
Acrylic Add
Chromium Compounds
Chromium
Vmylidene Chloride
Arsenic Compounds
MeinytenetjislPhenyiisocyanate)
Toluene-2,4-Dnsocyanate
Cadmium Compounds
Dibenzoluran
1.2-Oibromoelhane
Heptachlor
Asbestos (Fnabte)
1.1.2.2-Telrachloroelrane
459
145
193
100
47
12
139
713
659
21
123
226
228
65
99
28
2
65
13
Tot*
Emissions
(«*r)
30,226.580
6.654.123
4.762,901
4,195,667
1,436.427
1.218.426
799,178
791.922
547.745
296,353
267.252
247,319
196.977
100.487
71.054
63.327
49,055
47,615
43,855
%d
Foul Hign
HnWEiriy CntmoKt
Reduaon 01 Tail IB
Ctetniars Efflssons
5787
1274
912
803
275
233
153
152
105
057
051
047
038
019
014
012
009
009
008
116
026
018
016
006
005
003
003
002
001
001
001
001
000
000
000
000
000
000
Denial
Acrdein
Hydrazine
Acrylamide
Benzoic Trichloride
Mercury
Cadmium
Phosgene
Methyl isocyanale
Arsenic
Hexacniorooenzene
Bis(2-Chloroethyl)Elher
Beryllium
Mercury Compounds
Beryllium Compounds
Chlordane
Propyleneimine
Chloromelhyl Melhyl Ether
BislChlororrelhyl) Ether
NO 01
Emm
12
34
43
4
27
45
30
3
39
8
6
7
7
4
2
1
2
1
Toai
Emissions
(IUVO
33.652
29.004
26,019
24.963
23,395
21.925
21,603
10,175
8.437
4.994
4,922
3,763
2.366
862
575
500
122
1'
%a
taUvly Cranial*
Reduction 01 Toll TRI
ChcrniQis Enissions
006
006
005
005
005
004
004
002
002
001
001
001
on
000
000
000
on
on
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
52.233.541
10000
201
D-16
-------
TABLE D-12
National Emissions Of Carcinogens In TRI Database
— 1988 —
C-erai
Dicnloromeinane
Tncnioroeinyiene
Teiracnioroeinyiene
Slyrene
Benzene
Chloroform
Formaldehyde
Chioromethane
1.3-Buladiene
Elhyiene Oxide
1.2-Dicnioroelhane
Acrylonilnle
Carbon Telrachlonde
1 1,2-Tricnioroetnane
Vinyl Chloride
Chromium
Epicnlorotiydnn
2-Nilropropane
Vmylidene Chloride
Ureihane
2.4-Omilrololuene
2 6-Omilrololuene
1 2-Oibromoelhane
Hepiacnior
o-Toiuidme
1.1.2,2-Telrachloroelhane
No 01
E-iHiT
1577
892
683
1.140
459
164
724
77
14S
193
100
100
87
29
47
659
70
12
21
6
9
6
28
2
16
13
roai
Ension]
(in/VO
125849987
52 645 060
35.555545
32460559
30.226580
23.371 504
11.891,313
11290,415
6.654.123
4.762.901
4.324.929
4 195,667
3715.421
1.741.342
1.436,427
547,745
465268
389,385
296,353
145,373
93,257
87,597
63,327
49,055
46922
43.855
•H 01 Cflemai %
tool 01 Tan IRI
Ci^-cgf* Elisions
3563
1490
1007
919
856
676
337
320
138
135
128
119
IDS
049
041
016
013
Oil
008
004
003
002
002
001
001
001
483
202
136
125
116
092
046
043
026
018
017
016
014
007
006
002
002
001
001
001
000
000
000
000
000
000
C-e-ca
Benzyl Chlorine
Hydrume
Cadmium
Hexacnioroethane
Dimethyl Sullale
Methyl lodiae
Arsenic
Hexacntoroceroene
Bis(2-Criloroetriyl) Elder
1 1 -Dimethyl Hydrazine
Beryllium
2.4-Oiaminololuene
Hexacnloro-i,3-8uladiene
Thiourea
Ouinlozere
Alpna-NaDhinyiamine
Cniorflane
Elhylene Thiourea
Elhyleneimine
ProDyieneimme
Salrole
Lmdane
3,3'-OicnioroDeMicine
2 4 6-Tncnioroonenoi
CMoromelhyl Methyl Ether
BixCMoromolhyi) Ether
NO Oi
E-'ies
45
34
45
17
21
3
39
8
6
4
7
2
8
5
4
2
2
2
1
1
1
2
2
1
2
1
loin
Elusions
C»V)
43329
29004
21.925
19.187
10.796
8944
8437
4,994
4,922
4323
3763
2,988
2.556
2004
1064
590
575
500
500
500
500
258
255
250
122
1
\ Of Cnsniai \
loin 01 loui FRI
Cait.-oc.ens Emsiors
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
353.222197
10000
1355
TABLE 0-13
National Emissions Of Ozone Depletors
In TRI Database
enema
1.1,1-Tncnioroelhane
Freon113
CaiDon Telrachlonde
No 01
Enners
3.630
1.372
87
1988 —
loui
Erais.ons
(IO/YO
173920969
68,514.249
3,715421
tOI Onicilt
loni Oione 01 Toal IRI
Oesiam Emissions
7066
2783
151
667
263
014
246,150.659
10000
944
D-17
-------
TABLE D-14
All Chemicals Reported
— 1988-
Care
X
X
X
X
X
X
X
X
X
X
X
X
Onra
Deol HAP
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3360 HR/ER Crwmcal
X i 1,1-Tncfiloroetfiane
X 1.1 ,2.2-Tetrachtoroeffiane
1,1.2-TnchlOfoethane
1.1 -Dimethyl Hydrazme
1 ,2.4-Triehlor obenzene
1 ,2.4-Trimethylbenzene
1 .2-Buiylene Oxide
X 1 .2-Otbromoethane
1 ,2-Dchlorobenzene
1 .2-Dichtoroethane
1 ,2-Dichkxoethylene
1 ,2-Dichloropropane
X 1 ,3-Butadiene
1 ,3-Dichlorobenzene
1 ,3-Dchloropropylene
1 ,4-Ochlorobenzene
1 .4-Dioxane
2.4.5-Tnchlorophenol
2.4.6-Tnchlorophenol
2.4-0
2,4-Oiaminoioiuene
2.4-OichlOfOphenol
2.4-Di methyl phenol
2.4-Dinnrophenol
2.4-Dinitrotoluene
2.6-Oinitro toluene
2.6-Xylidine
2-Eihoxyethanol
2-Melhoxyethanol
2-Nitiophefiol
2-Nitropropane
2-Pnenylphenol
3.3'-Ochlorabenzidine
4.4'-Diaminodiphenyl E frier
4.4'-lsopropylidenediphenol
4,4>-Methylenebis
(2-Chtoroaniline)
CasNo
000071556
000079345
000079005
000057147
000120821
000095636
000106887
000106934
000095501
000107062
000540590
000078875
000106990
000541731
000542756
000106467
000123911
000095954
000088062
000094757
000095807
000120832
000105679
000051285
000121142
000606202
000087627
000110805
000109864
000088755
000079469
000090437
000091941
000101804
000080057
000101 144
4,41-Methylenebis (N.N-Dimeitiyl)OOOlOi6i 1
X
X
X
X
X
X
X
X
X
X
X
X
4,4'-Meihylenedianiiine
4 6-Oinitro-o-Cresol
4-Aminobiphenyl
4-Nitro phenol
AceaWehyde
Acetone
Acennitrile
X Acrolein
X Acrylamide
X Acrylic Acid
X Acrylonitrile
Alryl Chtonde
000101779
000534521
000092671
000100027
000075070
000067641
000075058
000107028
000079061
000079107
000107131
000107051
EmttBd Ta Air
(Hvyi)
173920,989
43,855
1 741 .342
4323
1.533.291
3,874,664
99.931
63.327
454,451
4.524.929
104.748
1.365.844
6.654.123
15.282
54.590
1.891.419
601 .244
91
250
7,020
2,988
1 403
10.788
20.825
93.257
87597
337
2.324.353
5.880880
33,689
389.385
10,630
255
216
224.896
750
250
130.151
274
10
7.855
6,588209
203.280 .215
2.061 .891
33.652
26,019
799,178
4.195,667
149.469
Emt«J To Al
Media (b/yr)
174.149092
44.696
1 ,746.734
4333
1.575.400
3953.504
103,681
71,479
498.544
6.019.696
104,844
1,393.029
7.075.694
16,563
54,840
1.902.872
810.256
91
300
11.358
3,238
1,512
35,495
120,534
223,381
115.554
1,874
2.444.559
5.922.157
33.692
650,685
11,110
255
382
769,91 1
750
7.250
593290
278
14
14.162
9.082.051
207.754.171
18.844,914
103.102
908.899
23.071.284
8.766.154
150.349
D-18
-------
Table D-14(Continued)
All Chemicals Reported —1988
Care
X
X
X
X
X
X
X
X
X
X
Ozone
Oapl MAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
33IX HH/ER Cltemcal
Alpha-Naphthylamine
Aluminum (Fume Or Dust)
Ammonia
Ammonium Nitrate (Solution)
Ammonium Sullata (Solunon)
Aniline
Anthracene
Antimony
Antimony Compounds
X Arsenic
X Arsenic Compounds
X Asbestos (Friable)
Banum
Banum Compounds
Benzal Chloride
Benzamide
X X Benzene
Benzoc Trichloride
X Benzoyl Chloride
Benzoyl Peroxide
Benzyl Chloride
X Beryllium
X Beryllium Compounds
Biphenyl
Bis
(2-Chloro-i-Memylethyl) Ether
X Bis(2-Chloroethyl) E trier
Bis(2-Ethylhexy1) Adipaie
X Bis(Chloromethyl) Ether
Bromometriane
Butyl Acrylate
Butyl Benzyl Phthalate
Butyraldehyde
C 1 Basic Green 4
Cl Disperse Yellow 3
Cl Food Red IS
Cl Solvent Yellow 3
X X Cadmium
X X Cadmium Compounds
Calcium Cyanamide
Captan
Carbaryl
Carbon Disullide
X Carbon Tetrachloride
Carbonyl Sulfide
Catechol
Chloramben
X Chlordane
Chlorine
Chlonne Doxide
CasNo
000134327
007429905
007664417
006484S22
007783202
000062533
000120127
007440360
007440382
001332214
007440393
000098873
000055210
000071432
000098077
000098884
000094360
000100447
007440417
000092524
000108601
000111444
000103231
000542881
000074839
000141322
000085687
000123728
000569642
002832408
000081889
000097563
007440439
000156627
000133062
000063252
000075150
000056235
000463581
000120809
000133904
000057749
007782505
010049044
Emitted To Air
(Wyr)
590
3,439.740
252.273.912
2,901 .807
720.826
726.473
202.113
69,206
165.520
8.437
267.252
47.615
265.811
993.367
5.258
500
30,226.580
24.963
33.014
6.294
43.329
3.763
862
1,210.272
1,140
4.922
74.442
1
1,941,462
411.653
291.248
2,257.110
750
398
250
250
21.925
100.487
12.600
14,869
7.923
123,893.704
3,715,421
20,183.072
3.589
1,418
575
133.751.760
13.402.987
Emrnad To All
M«Ja (Ibfyr)
691
6.331.400
328.537.542
43.448.063
3.731.229
4.330.882
216,101
211.862
1.975.356
22.424
5.245.917
8.966.069
598.289
6.254.677
5.258
1.000
31,213.435
24.963
163.014
7,544
44.219
41,087
12.879
1.429.263
31.140
6.273
84.732
1
1,943,008
415,793
295.142
2.262.950
750
700
250
250
96.146
398.162
78.600
21.719
8.923
123.981.687
3.643.901
20.183.072
29.559
1.668
4.841
140.136.041
13.405.337
D-19
-------
Table 0-14 (Continued)
All Chemicals Reported —1988
Can
X
X
X
X
X
X
X
X
X
X
X
X
Ozone
Depl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3*50 HfVEH ChemcaJ
Chloroaceac Acid
Chlorobenzene
Chtoroethane
X Chloroform
ChlofomettiAne
X Chtoromethyl Methyl Ether
Chlorophenols
X Chloroprene
Chtorothalonil
X X Chromium
X X Chromium Compounds
Cobalt
Cobalt Compounds
Copper
Copper Compounds
Cresol (Mxed Isomers)
Cumene
Cumene Hydroperoxide
Cuplerron
X Cyanide Compounds
Cydohexane
Decabromodiphenyl Oxide
Di(2-Ethylhexyl) Phttialate
Oiaminotoluene (Mxed Isomers)
X Oibenzofuran
Obutyl Phttialate
Dichloro benzene
(Mxed Isomers)
X Dtchbromethane
DKtitorvos
Dwotol
Diethanolamine
Diethyl Phthalate
Dwihyl Sulfate
Dimethyl Phttialate
Dimethyl Sulfate
Epichlorohydnn
Ethyl Acrylate
Ethyl Chtoroformate
Elhylbenzene
Ethylene
Ethylene Glycd
X Ethylene Oxide
Ethylene Thiourea
Ethyleneimine
Fluometuron
Formaldehyde
Freonns
Glycol Ethers
X Heptaehlor
Cas No
000079118
000108907
000075003
000067663
000074873
000107302
000126998
001897456
007440473
007440484
007440508
001319773
000098828
000080159
000135206
000110827
001163195
000117817
025376458
000132649
000084742
025321226
000075092
000062737
000115322
000111422
000084662
000064675
000131113
000077781
000106898
000140885
000541413
000100414
000074851
000107211
000075218
000096457
000151564
002164172
000050000
000076131
000076448
Ginned To Air
(feW
26.319
4.569.513
4.619.442
23.871.504
11.290.415
122
2.573
1.218.426
28.476
547.745
791.922
34.012
56.621
1.726.112
4.363.446
769.284
4,829.829
192.523
920
907.726
13.133.864
29.604
1.120.956
21.097
71,054
193.473
163,684
125.849.987
1.050
1.343
637.182
97.707
10.627
534.806
10.796
465.268
251.823
13.903
7,011,058
43,233.377
13.569.932
4.762.901
500
500
500
11.891.313
68.514,249
47,937.703
49.055
Emitted To All
MedulUyr)
26.929
4.756.451
4.648.400
25.064.706
11,571.650
122
74.399
1.287.505
28.726
8.705.510
29,409.219
94.228
88.417
7.801.219
47,021.736
2.581.810
4.871.286
564.807
920
1.011.868
13.528.159
32.146
1.130.742
198,679
82.493
562.749
163.724
127.836.050
1.050
1.343
942.273
108.707
10,877
539.535
11.456
540.559
253.299
13.903
7,301.269
43.279.044
23.096.141
4,873,577
500
500
500
22.999.438
68.580,392
48.589.613
49.057
D-20
-------
Table D-14 (Continued)
All Chemicals Reported —1988
Cue
X
X
X
X
X
X
Ozone
Depl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3380 HR/EH Chemcal
Hexachloro-1 ,3-Buiadiene
X Hexachlorobenzane
Hexachtorocydopemadiene
Hexachtoroe thane
X Hydrazine
Hydrazine Sullate
Hydrochloric Acid
Hydrogen Cyanide
Hydrogen Fluoride
Hydroquinono
laobutyraldehyde
Isopropyl Alcohol
(Manufacturing)
X Lead
X Lead Compounds
Lmdane
m-Cresol
X m-Xylene
Maleic Anhydride
Maneb
Manganese
Manganese Compounds
X X Mercury
X X Mercury Compounds
Methanol
Mertioxychlor
Methyl Acrylate
X Methyl Etfiyl Ketone
Methyl Hydrazine
Methyl Iodide
X Methyl Isobutyl Ketone
X Methyl Isocyanate
Methyl Meihacrylaie
Methyl Tert-Buiyl Ether
Methylene Bromide
X Methylenebis(Phenylisocyanate)
Mchler'S Ketone
Molybdenum Tnoxide
N.N-Dimettiylaniline
n-Buryl Alcohol
n-Dnctyl Phihalate
Naphthalene
X Nickel
X Nickel Compounds
NitncAad
NitnknriaceDC Acid
Nitrobenzene
Nitroglycerm
o-Anisidine
o-Cresol
CasNo
000067683
000118741
000077474
000067721
000302012
010034932
007647010
000074906
007664393
000123319
000078842
000067630
007439921
000058899
000108394
000108383
000108316
012427382
007439965
007439976
000067561
000072435
000096333
000078933
000060344
000074884
000106101
000624839
000080626
001634044
000074953
000101688
000090948
001313275
000121697
000071363
000117840
000091203
007440020
007697372
000139139
000098953
000055630
000090040
000095487
Emitted To Air
(Wyi)
2.556
4.994
14.718
19.187
29.004
1,172
69.264.605
1.392,777
12.114,046
10,334
809,260
1.935,267
1.168,231
1.518,309
258
18,432
2.194,146
653,952
2,265
1,791.163
1,669,121
23,395
2.366
226.096,844
272.881
429,335
131.808,179
2,927
8,944
31,435.711
10,175
3.427.572
2,896,781
57,723
247,319
1.100
103,019
98.905
37.365,557
69.532
5.066.028
421.570
254,761
8.576,460
2,500
40,373
51,383
2,293
89.797
E rutted To Ml
Media (fcfyr)
2.929
5.408
16855
19.719
31.161
1,172
470.624.493
3.134.438
12.312.112
148.294
810,094
1,937.121
6.532.544
21.619.966
258
19,170
2.214.757
906.532
2.515
20.519.087
88.836.71 1
37,737
2.366
279,542.921
273.381
461.153
132,155.176
2.928
9.199
32,346.212
10.239
3,790.996
2,933.050
57.723
319.256
1.100
257,330
119.122
40,593.763
70.052
5,259.533
1,139,907
1,925,509
14,046.538
12.700
862.579
58.370
2.828
91.913
D-21
-------
Table 0-14 (Continued)
Ozone
Care Dopl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
All Chemicals Reported— 1988
33/50 Hfl/ER Crrnnctf Cat No
o-Toluidme
X o-Xylone
p-Anisdine
p-Cresidine
p-Cresol
p-Nitrosodiphenylamme
p-Phenylenedamine
X p-Xytene
Parathnn
Pentachkxophenol
PeraceucAod
Phenol
X Phosgene
Phosphoric Acid
Phosphorus (Yellow Or White)
Phttiahc Anhydride
PicncAdd
Polybrommated Biphenyls
Propionalc'eriyde
PropOKur
Propylene
Propylene Oxide
X Propyteneimine
Pyndine
Quinoline
Quinone
Quintozene
Saccharin (Manufacturing Only)
Safrole
Sec-Butyl Alcohol
Selenium
Selenium Compounds
Silver
Silver Compounds
Styrene
Sty rene Oxide
SulfuricAcid
Tart-Butyl Alcohol
X Tetrachkxoethylene
Tetrachtorvinphos
Thallium Compounds
Thnacetamide
ThKKirea
Thorium Dioxide
Titanium Tetrachlonde
X Toluene
X Toluene-2,4-Diisocyanaie
ToJuene-2,6-Diisocyanate
Tnehlorlon
X Tnchloroethylene
000095534
0000954 76
000104949
000120718
000106445
000156105
000106503
000106423
000056382
000087865
000079210
000108952
000075445
007664362
007723140
000085449
000088891
000123386
000114261
000115071
000075569
000075558
000110861
000091225
000106514
000082688
000081072
000094597
000078922
007782492
007440224
000100425
000096093
007664939
000075650
000127184
000961115
000062555
000062566
001314201
007550450
000108883
000584849
000091087
000052686
000079016
EnMtod Te Air
<***')
46,922
2.064.641
10
7,080
640,703
IS
113,890
6.003.302
3.265
14.029
5,453
10.363.219
21.603
1.951,706
19.153
521.899
252
250
1.296.839
250
24.039.040
3.250.269
500
215.199
49.350
11,300
1.064
750
500
1.088,053
16,282
14.506
47.999
15.656
32,460,559
2.314
16.914.787
1.575.457
35,555.545
251
253
500
2,004
1,580
78.668
285,303.917
196.977
491.937
253
52.645.060
Errattod To All
Modilfbfyr)
54,098
2.090.138
10
8,080
651,994
15
119,432
6.055.728
4.265
38.419
5,508
15.455,310
22,103
36,189,144
201.009
523,434
753
250
1.298,925
250
24.049,043
4.488,182
500
710,257
50.740
11.440
1.064
750
500
1.212.944
144.704
63.656
88,809
34.221
32.755,596
2,314
166.641,036
2,265.812
35,756.720
251
503
500
25,394
1.580
80.068
287.709,754
198.017
492.447
253
52.672.070
D-22
-------
Table 0-14 (Continued)
Ml Chemicals Reported —1988
Care
X
X
X
Oiora
Oert HAP
X
X
X
X
X
X
X
33/50 HfVER Crwmcal
Tnfluralm
Urethane
Vanadium (Fume Or Dust)
Vinyl Acetate
Vinyl Bromide
X Vinyl Chloride
x Vmylidene Chloride
X Xylene (Mixed Isomers)
Zinc (Fume Or Oust)
Zinc Compounds
Zineb
CasNo
001582098
000051796
007440622
000108054
000593602
000075014
000075354
001330207
007440666
012122677
Emitted To Air
(b/yr)
3,277
145.373
17.664
5.908,341
4.950
1.436,427
296.353
151,187,866
3,394,558
7,225.958
1.250
Emitted To All
Madia (Ib/yr)
3.878
145.373
109.664
8.047.110
5,350
1,442.940
300.414
151.877,550
21.742.041
119.280.910
1.250
2.606.642.759 3.864.760.884
0-23
-------
D-24
-------
Appendix E
- Data from Basic Data Set -
-------
TABL£E-1
Regional Hot Spots
— 1987EPA REGIONS-
EPA
Hint Region
1 4
2 5
3 6
4 3
5 2
loa Rnion 1
E-ISSOTJ 01 loin
(I9/V>) 1HI Emissions fin
665.126.546 2416 1
j 2
3
4
5
6
7
8
9
10
584,526.605 21 23 1
2
3
4
5
6
J
a
9
10
49Z164.503 1788 1
2
3
4
5
6
7
a
9
10
306,424.076 11 13 t
2
3
4
5
6
7
a
9
10
156,459.472 576 1
2
3
4
5
6
7
8
9
10
dena
Meltiand
Toluene
Acetone
Carbon Oisulllde
Ammonia
Meitiyi Ethyl Kelone
Xylene (Mixed Isomers)
1.1,1-Tnchloroemane
Otchnromelhane
Hydrochloric Acid
Toluene
Methyl Elhyl Kelone
Xylene (Mixed Isomers)
1.1.1-Tfichloroelhane
Acetone
Dichioroineihane
Ammonia
Melhanol
Tndikxoethylene
Glycol Elhers
Ammonia
Elhytene
Aluminum (Fume Of Oust)
Propylene
Toluene
Metnanol
Acetone
Xylene (Mixed Isomers)
Methyl Ethyl Kelone
1,1.1-Tnchloroelhane
Carton Disullide
Toluene
Melhanol
Acetone
Methyl Elhyl Ketone
i.l.l-Tridilonxlhane
Dichloromelhane
Ammonia
Hydrochloric Acid
Xylene (Mixed Isomers)
Toluene
Oichioromelrane
Acetone
Median)
1.1.1-Tridiloioelhane
Methyl Elhyl Kelone
Xylene (Mixed Isomers)
Freonm
Hydnxhlonc Actf
Tnchloroeltiyleiw
Inn
Emissions
(IB*')
87.309.009
74.835.664
67.861.734
66.097.381
56415.788
30,251.939
29.006.177
24,912.620
24.492.296
22,220.252
83,911.566
58 867.923
55.717.879
44.713,520
4Z382.116
38.581.624
31.599.346
26.233.649
17.610.352
17.597.132
121.802,475
47.508.946
33 585 153
28,756.931
28063.953
27,571 820
18,448.251
16,479,648
U891.20B
9,597.982
50.448,918
35.146.033
31.911.110
23874.705
16.871.094
15.696.552
14.265.647
13,350.880
12585,788
U273.350
22.969.883
20.885.521
16.546.948
14.966.967
9,960,553
8,608,196
7,850.823
6.587.029
6,211.914
4.575.969
Total Raoor %
EPA Erauons 01 leal
Rs"» Repon (ID/yr) HUErtiss.an Rim
6 7 132.308,698 481 1
2
3
4
5
6
7,
8
9
10
7 8 109,693.896 398 1
2
3
4
5
6
7
8
9
10
8 9 108.421.610 394 1
2
3
4
5
6
7
8
9
10
9 1 98.141,784 357 1
2
3
4
5
6
7
8
9
10
10 10 97,466,442 354 1
2
3
4
5
6
7
8
9
10
Ctitmial
Toluene
Ammonia
Xylene (Mixed Isomers)
Methyl Elhyl Kelone
U.i-Tnchtoroelhane
Melharol
Dichloromelhane
Acelone
Tnchloroelhylene
Glycol Elhers
Chlorine
Hydrochloric Add
Aluminum (Fume Or Dust)
1.1.1-Tnchloroethane
Toluene
Xylene (Mixed Isomers)
Freonl13
Oidiloromelhane
Acelone
Ammonia
i.U-Tnchloroeinane
Freon113
Acetone
Ammonia
Oidiloromelhane
Toluene
Teliacfuoroelhylene
Methyl Elhyl Ketone
Melhanol
Xylene (Mixed Isomers)
i.U-Tnchloroelhane
Toluene
Oichloromelhane
Freonm
Methyl Elhyl Kelone
Meinanoi
Acelone
Telrachloroelhylene
Tnchlorodhylene
Chlorine
Ammonia '
Aluminum (Fume Or Oust)
Meltanol
Acelone
Toluene
Chloroform
Methyl Elhyl Kelone
I.l.t-Tnchloroelhane
Formaldehyde
Trictiloroethytere
loai
Ercissiors
(IW1
18280.371
16.786.366
16242482
9,296.207
8,427,767
7.710.845
6.206.383
6.037.989
5,533837
3.983776
68.499.623
9.936.613
7,017,973
3.831,680
2416585
2.323.150
2.154.877
1.781.837
1.267,911
1,144,301
22.983,146
9,618.502
8,802.529
8,331,251
6.877.109
6.086.280
5.768,271
5.758,268
4.765,579
3,100362
19.964.782
11,540.039
9.721.961
6,643.761
5.951.902
5.914.721
5.326.644
4.244.872
3,650,539
3.332.952
35,373.243
11,669.092
7.728.858
4.833.894
4.601.998
2.943.569
2.910.394
2.711.622
2.600.559
2.508.232
E-1
-------
TABLE E-2
State Emissions
- 1987—
Slate
AK
AL
AR
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemeal
Ammonia
Hydrochloric Acid
Methanol
Chloroform
Toluene
Xylene (Mixed isomers)
Benzene
1.1,1-Trichloroethane
Cyclohexane
Ethyibenzene
Carbon Oisulflde
Methyl Ethyl Ketone
Chlorine
Xylene (Mixed Isomers)
Toluene
Methanol
Hydrochloric Acid
Ammonia
Chloroform
Chlorine Dioxide
Ammonia
Toluene
Methanol
Xylene (Mixed Isomers)
Aluminum (Fume Or Dust)
Acetone
Methyl Ethyl Ketone
Dichloromemane
Carbon Oisulflde
Freon113
Totil
Emnon
(Ili/yr)
30,182.121
730.000
292.845
173.600
27.929
27.621
26.647
18.000
17,941
13.366
43.737.000
6,171.306
4,419.768
4,344.324
4,300.443
4,197,936
3,767.943
3,360.709
2,852.502
2,801,154
15,476.673
5,251.650
4,048.299
3,634.698
3,267,432
3,225.244
2,952.570
2.157.902
1,836.891
1,529.077
NO 01
EnuttBi
3
4
2
26
36
57
52
40
48
58
9
10
50
57
28
66
17
40
41
19
3
16
%OI
Slate
roial
9570
231
093
055
009
0.09
008
006
006
004
4273
603
432
424
420
410
368
328
279
274
2918
990
763
685
616
608
557
407
346
288
AS
a.
CA
CO
1 Ammonia
27.750
100
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Acetone
1,1,1-Tnchioraethane
Freon 1 13
Copper Compounds
Styrene
Methanol
Copper
Ammonia
Dichloromethane
Methyl Ethyl Ketone
1,1,1-TricWoroethane
Ammonia
Freon 113
Oichloromethane
Acetone
Tetrachloroetftylene
Toluene
Methyl Ethyl Ketone
Methanol
Xylene (Mixed Isomers)
1.1,1-Trichloroethane
Freon 113
(Aluminum (Fume Or Oust)
Dichloromemane
Methanol
Acetone
Toluene
Glycol Ethers
Ammonium Nitrate (Solution)
n-Butyl Alcohol
3.166.158
2.679.078
2,234.414
1,967.930
741.260
705.685
657.290
633.991
622.646
614.513
20,265.948
7,376.210
7,360,837
6,249.613
5,566,721
5,293.329
5,257,738
5,108.254
4,069.144
2.789.419
1,558.119
1.302.266
1.044.830
775.387
724,572
692.489
540,562
539.619
529,200
500,098
23
43
40
4
9
12
3
13
14
21
389
160
145
123
218
92
190
192
105
156
27
24
12
14
11
19
17
4
3
6
1792
1517
1265
11 14
420
399
372
359
352
348
2277
829
827
702
626
595
591
574
4.56
313
1473
1231
988
733
685
655
511
510
500
473
Slate
CT
DE
FL
GA
HI
IA
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
3
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemicil
1,1.1-Tnchloroethane
Tetrachloroethylene
Dichloromemane
Toluene
FreonH3
Methanol
Methyl Ethyl Ketone
Acetone
Chloroethane
Xylene (Mixed Isomers)
Methanol
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Hydrochloric Acid
Carbonyl Sulfide
Urethane
Toluene
Tnchioroethyiene
Methyl isobutyl Ketone
Glycol Ethers
Ammonia
Ammonium Sultan (Solution)
Acetone
Methanol
FreonllS
Styrene
Toluene
1,1,1-Tnchloroethane
Chlorine
Dichloromethane
Methanol
Hydrochloric Acid
Toluene
Acetone
Ammonia
Xylene (Mixed Isomers)
Oichloromethane
Trichloroethytane
Methyl Ethyl Ketone
Methyl isoDutyl Ketone
Ammonia
Aluminum (Fume Or Oust)
Toluene
Glycol Ethers
n-Butyl Alcohol
Xylene (Mixed Isomers)
Benzene
1,1,1-Tnchloroethane
m-Xylene
Propylene
Toluene
Ammonia
Xylene (Mixed isomers)
Methyl Ethyl Ketone
1.1,1-Trichloroethane
Tetrachloroethylene
Methanol
Acetone
Ethylene
Oichloromethane
Total
Emmoni No 01
(Ibfyr) EmMen
11.116.549
3.125,359
2,749,958
1,644.952
1,583.513
1,502.660
832.256
742.557
563.148
476.273
1.678.218
1,014,367
943.477
899,898
827.000
419,450
388.258
277.180
212.000
196,750
15,527,543
5,800.000
4.984.447
3,889,377
2,646.998
2,481.292
2,026.802
1.935.806
1.636.946
1,439.066
32,838.572
8.200.415
7,337.385
6.984.923
4,467.519
4,297.930
3,865.677
2,926.425
2,865.927
2,694.838
255.700
150.610
97.000
61.445
60.325
50.000
40.100
38.120
34,000
34.000
8,640,094
5,912,942
3,502.156
3.206.734
3,039.530
2,823,554
2,303.372
1,990.787
1,560.000
1,090.945
139
32
46
39
35
29
37
25
2
31
12
. 5
10
12
1
1
14
2
1
2
66
1
63
23
43
41
38
51
31
32
54
49
77
52
73
86
50
15
54
23
5
2
2
1
1
1
2
2
1
2
59
44
67
28
55
12
17
32
1
18
%oi
State
Tout
3986
1121
986
590
568
539
298
266
202
171
1833
1108
1030
983
903
458
424
303
232
215
3044
1137
977
763
519
486
397
380
321
282
3526
880
788
750
480
461
415
314
308
289
2645
1558
1004
636
624
5.17
415
394
352
352
2142
1466
868
795
754
700
571
494
387
270
E-2
-------
Table E-2 (Continued)
State Emissions —1987
Slale
ID
IL
IN
KS
KY
LA
flank
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemcal
Ammonia
Chloroform
Chlorine Dioxide
Zinc Compounds
Methanol
Suttunc Acid
Freon113
Chlorine
Totll
Ernsuni No 01
(Ib/yr) E mitten
1.608.156
710.000
590,700
359.027
332.530
220.698
210,720
123,505
Isopropyl Alcohol (Manufacturing)! 15,085
Cadmium Compounds
Toluene
1,1,1-Tnchloroelhane
Ammonia
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Ethylene
Chlorine
Tnchloroetnylene
Metnanol
Dicniorome Diane
Dichloromettiane
Toluene
Acetone
1,1,1-Tnchloroettiane
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Tnchloroetnylene
Aluminum (Fume Or Oust)
Benzene
Caroon Disuiflde
Ammonia
Tnchloroetnylene
Metnanol
Xylene (Mixed Isomers)
Toluene
Methyl Ethyl Ketone
Canon Disufflde
Acetone
Aluminum (Fume Or Oust)
1,1,1-Tnchloroe thane
Toluene
Aluminum (Fume Or Dust)
Methanol
Xylene (Mixed Isomers)
1.1,1-Tnchloroe thane
Hydrochloric Acid
Ethylene
Acetone
Glycol Ethers
Dichiorometnane
Ammonia
Metnanol
Toluene
Ethylene
Propylene
Carbon Disuhlde
Aluminum (Fume Or Oust)
Methyl Ethyl Ketone
1,2-Oichloroethane
Xylene (Mixed Isomers)
109,340
19.665,886
10.976.637
8.410.664
6.470.373
5.509,691
5.456,509
4.980,561
4.381,783
3.609,488
3.347,402
16.904,178
16.033,508
10.205,870
9.409,478
9.303,193
8.075,292
6.629,884
5.122,839
4.429.161
3.564.075
5.153.475
3.267.523
2.169.260
2.104,768
1,908,132
1,731,891
1. 561.509
1.276,665
1.145,166
811,381
8.251,424
7,299.591
6.385,438
5.084.968
2.752.774
2.412.788
2.300.946
2.041.999
1.863.350
1.229.099
77.026,391
9.736.176
6.722.029
6,387.127
5.006,785
4.485.591
3.956.555
2.621.987
2.324.486
2.139.167
21
1
1
2
4
10
3
8
4
2
199
191
93
154
130
14
48
96
102
88
78
149
93
106
160
104
65
61
12
2
33
11
19
41
42
25
2
28
10
24
60
45
27
54
41
33
4
38
19
20
59
S3
62
36
28
9
26
29
20
49
SOI
Stilt
Totll
3190
1408
11 72
712
660
438
418
245
228
217
18 52
1034
792
609
519
514
469
413
340
315
1455
1380
879
810
801
695
571
441
381
307
1837
1165
773
750
680
617
557
455
408
289
1529
1353
1183
942
510
447
426
378
345
228
51 75
654
452
429
336
301
266
1 76
156
1 44
Slate
MA
MD
ME
Ml
MN
MO
tank
1
2
3
t
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
l
2
3
4
5
6
7
8
S
10
1
2
3
4
S
6
7
8
9
10
Chemical
Toluene
1,1,1-Tnchlofoe thane
Freon1l3
Dichiorometnane
Methyl Ethyl Ketone
Tnchioroetnyiene
Acetone
Methanol
2-Metnoxyetnanoi
i,i.2-Tnchioroetnane
Ammonia
Toluene
Aluminum (Fume Or Dust)
1,1,1-Tnchloroe thane
Hydrochloric Acid
Methyl Ethyl Ketone
Chlorine
Xylene (Mixed Isomers)
Chloroform
Chlorine Dioxide
Chlorine
1.1,1-Tnchloroetnane
Methanol
Chlorine Dioxide
Chloroform
Acetone
Xylene (Mixed Isomers)
Toluene
2-Methoxyethanoi
Glycol Ethers
Toluene
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Acetone
Dichloromettiane
Glycol Ethers
1.1,1-Tricnioroemane
Metnanol
Chlorine
n- Butyl Alcohol
Methyl Ethyl Ketone
Toluene
Xylene (Mixed Isomers)
1 U-Tnchloroetnane
Freonll3
Methanol
Oichloromethane
Acetone
Tnchloroethylene
n- Butyl Alcohol
Xylene (Mixed Isomers)
Toluene
Methyl Ethyl Ketone
1,1,1-Tncnioroetnane
Glycol Ethers
Metnanol
Oichloromethane
Acetone
Ammonia
n-Butyl Alcohol
Total
Emnioni No 01
(Ibty) Emneti
5.672,161
4.167.659
3322.273
2980.085
2.754 952
2.269084
1.998,682
1,913,175
1,161.014
845,657
3.604,099
2.020.931
1 748.678
1,725.489
1,522452
1.491.725
1,109.185
989.662
680,000
650250
2.633 323
2.211,866
1.996.22S
1.923.954
1.673.560
954.481
784.169
641.406
604.311
459.250
20.130.708
17.245.186
14.436.620
12.129.692
9.052.027
5 477,931
5.264,363
5.148.467
3.923.671
2.676.368
12.259.855
10.578.935
4.320.498
3.106.603
2.858.492
2.418.612
2.331.161
1.625.934
1.058.060
1.035.479
9.307.966
5.289,780
3,760.525
3,595,732
3.157,397
2.992.782
2.941.894
2.330.966
2.066.941
2.043.411
96
139
69
60
63
55
65
68
9
2
25
27
10
28
19
21
9
21
1
1
13
21
10
7
7
17
12
13
3
3
185
156
125
127
71
69
128
79
37
53
37
52
49
58
43
30
38
34
25
19
90
114
72
78
41
50
44
60
48
36
%0t
Stan
Total
1755
1290
1028
922
852
702
618
592
359
262
1754
984
851
84Q
741
726
S4Q
482
331
317
1627
1366
1233
1189
1034
590
484
396
373
284
1681
1440
1205
1013
756
457
440
430
328
223
2443
2108
861
619
570
482
465
324
211
206
1882
1069
760
727
638
605
595
471
418
413
E-3
-------
Table £-2 (Continued)
State Emissions —1987
Slate
MS
MT
NC
NO
NE
NH
Rank
1
2
3
4
s
6
7
8
9
10
1
2
3
A
S
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
3
9
10
Clerical
Ammonia
Toluene
Cartonyl Sulfide
Methyl Ethyl Ketone
Xylene [Mixed isomers)
Dehloromethine
Tnchlofoethylene
1.1,1-Tfichioro* thane
Memanol
Chlonne
Aluminum (Fume OrDusI}
Hydrogen Fluoride
Xylene (Mixed Isomers)
Formaldehyde
Toluene
Propylene
Memanol
Emyiene
Ammonia
Lead Compounds
Toluene
Memanol
Memyl Ettiyl Ketone
Denioromeinant
Ammonia
1.1. 1-Tnchloroe thane
Acetone
Hydrocnionc AeiD
Xylene (Mixed Isomers)
Chloroform
Aluminum (Fume Or Oust)
Xylene (Mixed Isomers)
Toluene
1,1,1-Tnchloroethane
Ammonia
Freon 1 13
Methyl Ethyl Ketone
Tetrachioroetnylene
Methanol
Benzene
Ammonia
Toluene
Qichioromeihane
Xylene (Mixed Isomers)
1.1,1-Tnchloroa thane
Freon 113
Methyl Ethyl Kelone
Acetone
Ammonium Nitrate (Solunon)
Memyl Isobutyi Helms
Dchloromemane
Toluene
1,1.1-Tnchloroetnane
Freon 113
Metnyl Ettryl Kelone
Chlonne
Chlonne Dioxide
Xylene (Mixed Isomers)
Acetone
2-MetDoxyethanol
Total
Eminem No 01
(D/yr) Ennnere
15.400739
8.688.005
7.589.000
6.172615
3.698.443
3,128,629
2,223,859
1,429,897
1,385,569
929.271
2,949,927
370,155
359,470
324,200
267,250
215.400
181.250
98.760
94.000
86.501
23.650,176
15.261,417
7.541.046
7.381.545
7.280.251
5.369.002
4,991,675
3.687,516
2.S25.701
2.414,986
890.000
216.618
113.268
94,445
60,500
53.587
33.481
32.000
22.506
22.000
3.653.008
2.442.365
1.705.269
1.327.592
981.124
872.891
597.067
439.571
390.000
282.408
3.162.981
1,597.081
1,419,479
1,104,651
916.746
690,500
640.000
538.825
444.495
383.900
37
49
2
21
41
14
8
32
20
19
7
5
4
4
6
3
3
3
3
3
176
169
128
51
74
128
117
58
114
S
1
7
2
4
3
1
4
1
5
1
26
22
8
27
25
6
14
11
2
5
17
19
39
23
18
2
1
12
12
1
SOI
Stall
Total
2619
1477
1290
1050
629
532
378
243
236
158
5198
652
633
571
471
380
319
1 74
166
152
2312
1492
737
722
712
525
488
360
217
236
5342
13
680
567
363
322
201
192
1 35
132
2526
1689
11 79
918
678
604
413
304
270
195
2512
1268
1127
877
728
548
508
428
353
305
Sine
NJ
NM
NV
NY
OH
OK
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chemical
Toluene
Acetone
Methyl Ethyl Kelone
Xylene (Mixed Isomers)
Memanol
Oichlorometfiane
1,1,1-Tnchloroe thane
n-Butyl Alcohol
Methyl isobutyi Ketone
Fraonm
Suifunc Acid
Freon 113
Toluene
Copper Com pounds
Xylene (Mixed Isomers)
l.l.i-Tnchloroetnane
Acetone
Benzene
Ethylbenzene
Hydrochlonc Acid
Toluene
Chlonne
Acetone
Xylene (Mixed isomers)
Ammonia
Hydrochlonc Acid
Methyl Ethyl Ketone
S tyrant
Fraon113
Manganese
Dichioromemane
Methanol
Toluene
Acetone
1,1.1-TnchloroelHane
Hydrochlonc Acid
Xylene (Mixed isomers)
Freon 113
Memyl Ethyl Kelone
Tncnioroethyiene
Ammonia
Methyl Ethyl Kelone
Acetone
Xylene (Mixed isomers)
Toluene
1,1,1-Tncnioroelnane
Memanol
Glycol Ethers
Ditiiiorometnane
Hydrochlonc Acid
Ammonia
Toluene
Memanol
Xylene (Mixed Isomers)
Methyl Ethyl Ketone
Hydrogen Fluoride
Tetrachiorcethylene
1,1,1-Tnchloroemane
Memyl Isobutyi Ketone
Aluminum (Fume Or Oust)
Total
Emnwtn No 04
(lD/yn Emnen
9.414.246
6,583.417
4.325.825
2.661,027
2.630,952
2.084.889
1,384.337
1.370.359
1.248,684
1.174.668
993.900
628.231
570.273
485.559
378,315
267.944
125.647
121.951
97.899
59.518
256.435
182,003
69.650
53.200
37.600
37.075
35,521
33.611
23.251
9.100
17.067.609
11.315.852
11.024.054
8.741,346
8,140.663
5,751.844
4.611.965
4.095.527
3.996.142
3.976.192
15.850.083
14,171,797
13,180.094
13,162,166
12.220.854
10.650.038
8.190,822
5.299.395
4.929.787
4.200.073
14,543,647
4.078.768
3.302.898
2.192.492
1.875,978
1.352,694
1,203.448
957,871
912.354
897,185
176
108
105
120
107
69
111
62
51
35
5
7
7
2
S
5
6
4
4
S
3
4
4
1
1
6
4
3
1
2
64
91
156
70
1S2
95
107
61
93
64
117
174
126
214
239
235
114
78
114
159
26
33
13
27
18
8
10
30
8
19
%0t
Slate
Total
21 SO
1503
988
608
601
476
316
313
285
268
2549
16 H
1463
1245
970
637
322
313
251
153
3320
2356
902
689
487
480
460
435
301
1 18
1704
1130
11
873
813
574
460
409
399
397
11 11
993
924
922
856
746
574
371
345
294
3914
1098
889
590
505
364
324
258
246
241
E-4
-------
Table E-2 (Continued)
State Emissions —1987
Stale
OR
PA
PR
Rl
SC
SO
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
Chcrnctl
Mettianol
Acetone
Formaldehyde
Toluene
Tnchloroetnyiene
Ammonia
Aluminum (Fume Or Oust)
Methyl Ethyl Ketone
Chlorine
FreonllS
Toluene
1,1,1-Trtchloroetnane
Dichlorometnane
Methyl Ethyl Ketone
Ammonia
xyiene (Mixed Isomers)
Hydrochloric Acid
Ammonium Nitrata (Soluoon)
Mettianol
Acetone
Toluene
Dichloromethane
Freon113
Acetone
Carton Disulfide
Methanol
Benzene
Cyciohexane
1,1,1-Tnchloroethane
Methyl Ethyl Kelone
Toluene
Acetone
Methyl Ethyl Ketone
1,1,1-Tnchloroethane
Oichloromethane
Tnchloroemyiene
Tetrachloroetnyiene
Freon113
Xyiene (Mixed Isomers),
Methanol
Methanol
Toluene
Acetone
U.t-Tnchloroethane
Xyiene (Mixed Isomers)
Methyl Ethyl Ketone
Ammonia
Oichloromethane
2-Methoxyetnanol
Hydrochloric Acid
Xyiene (Mixed Isomers)
Toluene
Freon113
Ammonia
Methyl Ethyl Ketone
Methanol
Acetone
1,1,1-Trichloroethane
Form aldehyde
Styrene
Tottl
Erranan No 01
(Ib/yr) Emnten
2.9SS.333
2.605,018
2.448,725
2.299,263
1.100,338
1.093.S73
999.405
813.232
780.660
718.552
15.800.174
10.040.763
8,084,944
6.5S3.449
6.419.669
5.085.288
4.915.873
4.834.450
2.978.369
2.849.922
2.151.583
1,733.023
1.316.834
1,222.185
1.101.100
1.019.463
697.785
508.977
435,303
286.229
1.703.924
1,150,879
1.141.389
784.258
626.573
576.417
464.990
275.662
265.284
180.923
17.216.556
7.444.646
6.285.758
4.786.005
2.866.137
2.818,824
2.583,511
2.444.091
1.972.633
1.879.795
702.367
452.348
410,722
188.861
158.718
134.585
106.555
89.689
89,200
51.510
28
30
28
33
13
25
6
18
17
15
189
160
65
113
101
172
98
4
98
108
19
21
22
27
1
29
3
5
23
9
20
19
13
37
13
35
19
13
14
14
68
57
38
61
59
36
43
28
3
40
7
5
3
2
5
2
3
4
1
2
%0f
Slate
Tout
1378
1210
1138
1068
511
508
464
378
363
334
1686
1072
863
699
685
543
525
516
318
304
1693
1363
1036
962
866
802
549
400
342
225
2162
1460
1448
995
795
731
590
350
337
230
2602
1125
950
723
433
426
390
369
298
284
2794
1799
1634
751
631
535
424
357
355
205
Stale
TN
TX
UT
VA
VI
VT
Rank
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
S
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
ChGfTltUl
Acetone
Carbon Disulfide
Toluene
CaiDonyl Sulfide
Ammonia
Metnanol
Xyiene (Mixed Isomers)
1,1,1-Tnchloroethane
Oichloromethane
Methyl Ethyl Ketone
Ethylene
Aluminum (Fume Or Oust)
Propylene
Ammonia
Acetone
Toluene
Methanol
Xyiene (Mixed Isomers)
1,1.1-Tnchloroethane
Benzene
Chlorine
Hydrochloric Acid
1,1.1-Tnchloroethane
Aluminum (Fume Or Oust)
Oichloromethane
Toluene
Xyiene (Mixed Isomers)
Acetone
Freonl13
Sultunc Acid
Carbon Oisulfide
Methanol
Acetone
Toluene
Methyl Ethyl Ketone
Oichloromethane
Hydrochloric Acid
Xyiene (Mixed Isomers)
1.1.1-Tnchloroethane
Chloroform
Benzene
Xyiene (Mixed Isomers)
Toluene
p-Xylene
Ethylbenzene
1,2,4-Tnmetnyl benzene
Cyciohexane
Naphthalene
Anthracene
Methanol
Toluene
1.1.1-Tnchloroeinane
Freontn
Xyiene (Mixed Isomers)
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Methanol
Acetone
Tetrachloroelhylene
Sodium Hydroxide
ToUl
Emmoni
-------
Table E-2 (Continued)
State Emissions —1987
Slate Rank
WA 1
2
3
4
5
6
7
8
9
10
Wl 1
2
3
4
S
6
7
8
9
10
Cternal
Aluminum (Fume Or Oust)
Methanol
Ammonia
Toluene
Acetone
Methyl Ethyl Ketone
1,1.1-Tricnloroethane
Chloroform
Otehloromethane
Tnchloroethylene
1,1,1-Trichloroethane
Toluene
Xylene (Mixed Isomers)
Mettiyl Ethyl Ketone
Methanol
'Ammonia
Hydrochloric Acid
Acetone
Dlchloromethane
Glycol Ethers
TOUI
Emiiuni No Of
(Ib/yr) Emmen
10.669.687
4.138.150
2.489.393
2.274.806
2.122.731
2.095.617
2.081.903
1.421,569
1,411,687
1.396.894
5,306,401
5,281 .675
5.216.463
4.414.668
3.700.430
2,935,083
2.750.788
2.563.408
2.017,069
1,887.154
21
27
51
41
57
36
39
9
24
16
120
99
97
70
44
76
65
51
44
37
%OI
Slate
Total
2711
1051
632
578
539
532
529
3.61
359
355
1071
1066
1053
891
747
5.93
555
517
407
381
Slale Rank
WV 1
2
3
4
5
6
7
8
S
10
WY 1
2
3
4
5
6
7
8
9
10
Chemical
Medianoi
Acetone
Toluene
Propyiene
Ammonia
Benzene
Aluminum (Fume Or Oust)
Cliloromeihane
Xylene (Mixed Isomers)
Acrylomtnle
Ammonia
Toluene
Aluminum (Fume Or Oust)
Xylene (Mixed Isomers)
Propyiene
1,2,4-Tnmediyibenzene
Benzene
Methyl Ethyl Ketone
Ethylbenzene
n-8utyl Alcohol
TOUI
Emniont No 01
(Ihiyi) Emmen
6.467.S98
4,956,513
3.084.547
2.228,290
1.501.938
1.463.213
1.321.670
1.302.356
1.296.781
1.210.538
639.307
509.278
421.919
374.157
167,000'
115,000
97.084
83.997
77.202
60,000
18
13
31
3
20
6
13
S
22
4
3
5
4
6
3
2
4
2
3
1
%OI
Slate
Total
1550
1188
739
534
360
351
317
312
311
290
2175
1733
1435
1273
568
391
330
286
263
204
E-6
-------
TABLE E-3
Regional Hot Spots
— 1987 3-DIGIT ZIP CODES-
3 anil
ZIP Cose
840
775
226
376
365
703
700
996
797
776
460
146
707
244
286
779
706
377
356
314
606
371
553
391
284
723
31S
481
241
490
476
338
440
381
604
261
232
190
453
465
70
463
402
756
452
420
479
397
473
ISO
Sue
UT
TX
VA
TN
AL
LA
LA
AK
TX
TX
Ml
NY
LA
VA
NC
TX
LA
TN
AL
GA
IL
TN
MN
MS
NC
AR
GA
Ml
VA
Ml
IN
FL
OH
TN
IL
WV
VA
PA
OH
IN
NJ
IN
KY
TX
OH
KY
IN
MS
IN
PA
NO a
RBB» No 01
Rcoors Fnhues
127
1.076-
45
129
165
48
280
18
70
237
387
197
337
SO
363
95
215
64
165
68
786
131
129
33
115
77
84
348
90
242
36
101
400
200
388
144
118
206
230
242
693
289
286
136
385
137
130
76
ISO
16S
30
114
12
27
21
11
35
3
14
26
106
47
36
17
118
13
25
24
39
20
253
37
48
12
25
18
20
95
28
87
7
43
115
67
100
18
40
51
47
96
204
68
57
35
97
20
35
25
51
40
HAP
Emissions
79.693.562
37447.395
53.864.892
17.509.812
47.688.861
2.843.110
7,073.563
348.025
2.126.028
10.555,268
24.133,692
21,079.005
12.961,101
20.896.673
19.925.963
2,893,857
7.680,927
19,402.905
15.290.163
17.199.190
13.776,120
16,047.046
16.991.955
2.879,568
15.208,939
3,035.909
14,826.112
9,441,349
4.143,659
12.705.255
11.958.070
2.072.994
12.513.300
5.648.928
6.913.182
11.077.280
11.793.489
8.768.233
5.008.260
11.489,046
9.245.446
10.823.397
11.174.823
4.679,895
8.316,589
8.713.272
10.305.483
11.211.743
7.957.190
3.691.549
Ian 2lf>%
Emissions 01 Iota mi
|uVyr) Ension
80.404,209
75.638.519
54,112.601
53,276.986
48,562.188
44,101.738
32.340.914
30.551,825
29,039,058
27,844,287
26.516,990
26.235.492
22.374.031
21.947.671
21.843.602
21.295,388
20.034,371
19.715,264
19.249.498
19.194.300
18.083.940
18.060.263
17.729.995
17.668.662
17.369.639
17.327.282
16.690,151
16.247,565
15,942,393
15.546.995
14.864.720
14,255.431
14.150.497
13.841.458
13.669.887
13.420.370
13.284.854
13.247.767
13.224.521
13,195.514
12.971.144
12.902.918
12.822.573
12.664.227
11.939,778
11,878.007
11,835,462
1t.752.787
11.485,201
10,889.791
292
275
197
194
176
160
117
111
105
101
096
095
081
080
079
077
073
072
070
070
066
066
064
064
063
063
061
059
053
056
054
052
051
050
0.50
049
048
048
048
048
047
047
047
046
043
043
043
043
042
040
3Doi
ZlPCoce
601
630
299
986
SSI
6
395
485
212
765
301
494
441
605
770
486
740
294
852
708
631
295
482
383
945
430
238
317
619
287
902
729
737
544
296
260
436
64
278
320
550
763
271
681
672
88
790
245
18
456
Sa:o
IL
MO
SC
WA
MN
PR
MS
Ml
MO
TX
GA
Ml
OH
IL
TX
Ml
OK
SC
AZ
LA
MO
SC
Ml
MS
CA
OH
VA
GA
IL
NC
CA
AR
OK
Wl
SC
WV
OH
CT
NC
FL
MN
TX
NC
NE
KS
NJ
TX
VA
MA
OH
NO a
tense No 01
Rigors Fialiues
395
187
19
120
178
240
136
72
321
39
139
263
520
147
388
146
92
127
156
147
360
125
296
74
356
137
94
90
32
109
356
102
8
110
264
94
170
292
126
43
118
20
80
81
137
396
104
141
231
96
148
55
3
28
46
76
25
13
76
11
47
75
153
45
104
20
28
33
54
18
. '21
37
67
30
97
37
26
28
12
39
118
35
3
40
98
23
39
93
47
12
21
3
30
26
33
109'
20
46
75
21
HAP
Emissions
8.706.905
8.977.413
3.939,581
6.008.001
7.947.374
7.572.000
9.068.303
7.894.360
5.531 .984
1.420.609
7.923.733
6.345,616
7.051.033
7.699.009
5.930.264
8,242.470
5.070,798
7.713.358
3.343.562
5.478,948
7,828,008
6,911,726
6.630.488
8.200.442
4.718,839
4.04S.2S6
6.287.825
6,485.685
7.496.108
7.093.065
5,790,674
7.712,112
1.818,920
6.544.893
6.204.386
6.095.127
6.936.40V -
6.859.837
£363.124
644,217
6.174.508
5,753.456
6.381.311
3.695.976
7,162.720
5,099,208
3,800.369
6.733.295
5.548.094
4.666.947
ran K?\
Emsions 01 [GUI in
(Ityr) Emissiors
10,850.026
10,709.048
10.551.331
10.328.592
10.324.872
10.093.133
9.846.078
9.730.136
9.581.052
9.542.697
9.438.9S5
9.336.555
' 9.150.519
9.071.900
9.046.126
9,031.737
9,029,950
9.028,678
9.004.824
8.966.935
8960.808
8.932.350
8.917.265
8.838.615
8.817.143
8,774.822
8,751 954
8,663,928
8,610.248
8.517.941
8,352,769
8.308,127
8.299,297
8,240.515
8,136.185
8,019.239
7.930.498
7,929.973
7.798.053
7,777,893
7.769,766
7.704,075
7.658,934
7,631,111
7,562.456
7.496,769
7,397,302
7.392.671
7.2S4.67S
7,162.106
039
039
038
038
038
037
036
035
035
035
034
034
033
033
033
033
033
033
033
033
033
032
032
032
032
032
032
031
031
031
0.30
030
030
030
030
029
029
029
028
028
028
028
028
028
027
027
027
027
026
026
19.197 5.021 1,011.786,418 1.559,518.366 5665
E-7
-------
TABLE E-4
Regional Hot Spots
— 1987COUNTIES —
County
Tooele
Ascension
Warren
Hams
Mobile
Sullivan
Los Angeles
Cook
Kenai Peninsula
Edor
Monroe
Jeflerson
Brazona
Chatham
Calcasieu
Calhoun
Allegheny
Mississippi
SI James
Hainblen
Wayne
Me Lew)
Lake
Calawtaa
Shelby
Polk
Galveston
Yazoo
Oakland
Glynn
Jeflerson
Colbert
Hamilton
Middlesex
Orange
Giles
Orange
East Baton Rouge
Kanawha
Humphreys
Macomb
SI Charles
Marshall
Hampton
Hamson
Ramsey
Broome
Kaianazoo
Genesee
Ene
Sate
UT
LA
VA
TX
AL
TN
CA
IL
AK
TX
NY
TX
TX
GA
LA
TX
VA
AR
LA
TN
Ml
MN
IN
NC
TN
FL
TX
MS
Ml
GA
KY
AL
OH
NJ
TX
VA
CA
LA
WV
TN
Ml
LA
KY
SC
TX
MN
NY
Ml
Ml
NY
No 01
Release
No W
HAP
Emission
ReooiB Faculties (law
7
137
16
1.083
179
87
1.733
1.455
18
39
225
321
192
68
192
64
19
42
45
36
499
22
201
130
209
92
179
2
232
36
286
48
402
464
68
8
470
165
131
14
175
93
82
12
65
163
58
67
75
200
3
14
2
195
25
10
590
485
3
6
57
32
16
20
20
7
4
12
8
17
126
7
45
45
72
38
13
1
56
6
57
11
99
122
11
1
160
20
11
3
44
9
7
2
10
40
17
15
15
78
76.990.850
7.138.666
51,049.650
31.423.089
48.860.435
8.824.570
27.847.064
28.941.283
348.025
1.314.626
21.879.315
9.245.670
9.081.338
17.199.190
6.686.739
1.731,973
17.081.669
2.980.128
1.062.259
16.728.883
10.726.251
15,339507
11,620.055'
13.371.583
5,741.962
1.749.446
3.883.304
3,800
10.905.140
11.867.322
11.174,823
9,486.995
8.781.633
9.313,497
4.747,308
1.191,803
7,244,052
7.299.798
5.713.245
10.646.027
10,313,245
2.257.264
7.913.593
8.929.680
3.296.943
7.909.734
8,373,661
8,579,962
7,901.572
7,525.755
Inn County %
tiuuiofls 01 iom T™
(ib/yr) Emsions
76.990.850
53.192.833
51.098,900
51.013.127
50.131.309
42.157.825
37.142.886
36.451.718
30.551.825
27.426,263
27,147,265
23,474.705
22.300.923
19.194.300
18.805,514
18.123.053
17.845.769
17,257.687
17,252.819
16,793.737
16,670.453
15.591.355
15,235,907
13.989761
13.982.251
13.664.486
13.426.072
13.253.300
13,079.686
12.969.176
12.822.573
12.593.374
12.575.144
11.788.121
11.341.190
11.221,804
11206,148
11.136,085
11,132.186
10.927.552
10.888.013
10.863.662
10.532.165
10.529.680
10.437.865
10226.316
10.167.909
10.071.262
9.737.348
9,674,472
280
193
186
185
182
153
135
132
1 11
too
099
085
081
070
068
066
065
063
063
061
061
057
055
051
051
050
049
048
048
047
047
046
046
043
041
041
041
040
040
040
040
039
038
038
038
037
037
037.
035
035
Couny
Cuyahoga
Allen
Middlesex
Lowndes
SI Louis
New Haven
Forsyin
Brunswick .
Bucks
Lucas
Milam
Gartieid
Posey
Hartford
Sebastian
Maricopa
Newcastle
Brown
Floyd
King
Sedgwick
Cowiilz
Tarranl
Tippecanoe
Baltimore City
Wood
Milwaukee
Niagara
Delaware
Dallas
Harrison
Marion
Onondaga
Warrin
Santa Clara
Coshocton
Union
Allegheny
Philadelphia
Washington
Grundy
R
-------
TABLE E-S
Air Emissions By U.S. Industry
-1987—
2 DICII
SIC Co
0
1
1
3
6
7
8
9
10
11
12
13
14
16
te
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
41
42
43
44
45
:e US moisry
'
Food
Tobacco
Textiles
Apparel
lumber
Furniture
Pulp & Paper
Pnnlmg
Chemicals
Petroleum Helming
Rubber, Plastics
Leather
Stone, Clay. Glass
Primary Metals
Fabricated Metals
Non-Elect Machinery
Electoral Equipment
Transport Equipment
Instruments
Misc Manufacturing
No Of
Eirites
105
8
3
1
2
4
7
2
3
853
24
323'
35
484
426
569
309
3,517
305.
1.253
118
545
1,414
2.458
882
1,519
1.023
338
341
1
3
3
1
7
No 01
Release
Re DOITS
216
15
1
1
4
1
1
2
1
3
1
6
8
13
2
7
1,278
42
577
51
1,228
1,412
1.880
538
16.324
2.593
2.839
341
1.349
4,792
6.296
2.034
4.258
3.932
847
770
1
3
5
1
13
HAP
Enissions
(in/y)
3,945.108
73.466
250
0
0
0
41.000
170
20
000
19.000
35.990
22.752
30
159.940
164.679
6.188,596
4.495.887
41,973.249
2,573.651
25,919.430
50,038.326
219,974,582
62,098.491
517,955.861
58,704,688
145,659,763
11208.672
22,350.131
176,779.405
105,680.827
47,456.040
94,290.600
194,285.098
46,197.297
23,534.343
0
5
76.602
000
106.288
Toai
Emissions
(law in
4.634.434
84.379
250
50.000
2.500
250
41,000
170
20
2.700
19.000
37.540
47.908
231.614
159.940
178.218
21.128.105
6.768.722
46.050.449
2.753,619
29,259.256
56.978.226
268.281,645
63.330.437
986,334.064
105.111.872
180,609,219
14,847.725
32.320.624
267,773,793
135.399,921
60.023,399
128.165.761
240.892.720
61.074.605
28.824.848
13.909
755
76.852
250
381.288
toons;} %
01 loai
E.-issiors
017
000
000
000
000
000
000
000
000
000
000
000
000
001
001
001
077
025
167
010
106
207
975
230
3583
382
656
054
117
973
492
218
466
875
222
105
000
000
000
000
001
2 Den No Of
SC Coca U S Irf.s.-y EmiRn
46
47
48
49
SO
51
52
54
55
56
57
58
61
65
66
67
71
72
73
75
76
78
79
80
82
83
85
87
89
91
95
96
97
98
99
C1
KO
NA
1
11
1
11
16
71
2
3
1
1
1
2
1
1
1
3
1
2
25
2
4
1
2
2
1
2
3
2
3
1
1
2
4
1
9
2
1
24
No 01
Release
Resois
1
18
5
39
22
301
2
4
1
2
3
2
1
1
1
3
1
3
83
2
14
1
11
2
1
2
4
30
8
1
2
6
10
4
28
2
1
41
HAP
Emssors
8
58.453
750
3.973,523
88.946
978,547
36.130
32.007
24,377
0
750
500
11.400
15.000
0
44.398
2.996
0
133.469
50.833
17.512
49.000
34.958
7.300
599
8.017
276.500
15.900
44.300
3.500
500
15.500
83.365
26.500
711.519
0
0
782.551
ran
Elusions
day) mi
8
75.468
1.750
5.746.810
123910
1.214.120
36.130
54.307
24.377
2.167
2.250
1800
11.400
15.000
12.000
44.898
2.996
24.697
164,963
50,833
75.249
49.000
85.736
8.800
599
13,343
312,250
602.650
45.300
3500
500
16.250
98.715
40.560
748.188
17,112
219.000
685.003
I-CJSIV %
a (cm
000
000
000
'021
000
004
000
000
000
000
000
000
000
000
000
000
000
000
001
000
000
000
000
000
000
000
001
002
000
000
000
000
000
000
003
000
001
003
17.116 54.349 1.869.589.845 2.752.733.632 10000
(Note Only SlCs 20-39 are required to report to TRI)
E-9
-------
TABLE E-6
Industrial Emissions
-1987 —
2 Oigii
SCCoce
28
26
33
37
30
34
36
29
27
38
35
25
22
32
24
39
20
31
21
49
23
51
NA
99
87
45
85
14
KO
16
73
16
50
97
79
0
43
47
76
No 01
EaiM
3,517
SS9
1.414
1,023
1253
2.4S8
1,519
305
309
338
882
426
323
545
484
341
8S3
118
24
11
105
35
71
24
9
2
7
3
7
1 '
3
25
2
16
4
2
8
3
11
4
NAP
Elusions
(loW
517,955,861
219,974,582
176,779.405
194,285,098
145,659,763
105.680.827
94,290,600
56704.688
62.098,491
46,197,297
47,456.040
50.038.326
41,973,249
22,350,131
25,919.430
23,534.343
6,188.596
11,208,672
4,495,887
3,973,523
3,945.108
2,573,651
978.547
782.551
711,519
15,900
106,288
276,500
30
0
164.679
133.469
159.940
88.946
83.365
84.958
73.466
76.602
58.453
17.512
rani
Emissions
-------
TABIIE-7
Air Emissions For The U.S. Chemical Industry
- 1987—
4 Doit
SIC Cue
28
2800
2801
2602
2805
2810
2812
2813
2815
2816
lotil
Emissions
(ID/V)
158.901
9.227.079
715
3.434
35.650
1.513
21.854.218
8.987.209
226,897
22.881.404
4thgii
SIC Com
2818
2819
282.
2820
2821
2822
2823
2824
2828
2829
loai
! Emissions
Ca/YO
85.963
58.764.259
479.270
156.848
140.064.943
21.454,022
102.156.702
17.402.646
1,056
72.000
4- Digit
SCCcoi
283
2830
2831
2832
2833
2834
2835
2836
2837
2839
rotn
! Emissions
(IB/yr)
141.674
481.618
1,983.537
519033
17,918.542
40.207.929
120,520
9,944
526
229,000
4-Digit
SIC Cone
284
2840
2841
2842
2843
2844
285
2850
2851
2852
loai
iEnissons
OIUV')
4.700
25.352
837.768
491.290
7,593,384
241,924
76,353
82.164
25,153.791
1.500
4 OiCl.
SCCoce
2658
266
2860
2861
2865
2866
2867
2868
2869
2870
loin
Emissions
oo/y)
1.250
5.000
105.559
4,956490
32.589.959
672.931
7659
4.300
197,709,781
1,471,720
4-OlCll
SICCooi
2873
2874
2875
2878
2879
2889
289
2890
2891
2892
rota!
) Emissions
(l&n/O
180,745,494
19.769.369
4.401.156
500
13.560.866
500
73,103
62,248
4,992.791
6.815.080
4- Digit
SIC Con
2893
2895
2898
2899
toiai
Emissions
(IB/*)
2064398
11.287,567
77,917
4.802,148
986,334.064
E-11
-------
TABLE E-8
Top Industrial Emitters
- 1987 4-DIGIT SIC CODES-
loai SOI
Emissions 2-Digil
Ran< SIC (In/yi) SIC Cage Rani
1 2669 I97.7G9.781
2 2873 160,745,494
3 2821 140,064.943
4 3079 108.153.975
5 2823 102.156.702
6 2911 95,243.502
2004 1
2
3
4
5
6
7
8
9
10
1832 1
2
3
4
5
6
7
8
9
10
142 1
2
3
4
5
6
7
8
9
10
5988 1
2
3
4
5
6
7
8
9
10
1036 1
2
3
4
5
6
7
8
9
10
9061 1
2
3
4
5
6
7
8
9
10
C'eniai
Acetone
Melhanoi
Elhyiene
Ammonia
Ptopytene
Chloromelhane
Toluene
Benzene
Elhyiene Glycol
Hydrochloric Add
Toial HOUom
Emissions 2 Dion
(IH/Vr) SC
50.041.563
26,322.642
18.777.666
11515.363
10.153.219
7,927.388
6,615,353
5,834.880
4,872.614
4,508.855
Ammonia 159,828,796
Melhanoi
Ammonium Nilrale (Solution)
Propytene
NitncAod
SulluncAcid
Aceionilnle
Acrylonilnle
Acrylic Acid
Hydrogen Cyanide
Elhyiene
Carbon Oisulfide
Propylene
Dichloromelhane
Melhanoi
Acetone
Toluene
Slyrene
Chlorodenzene
i.3-Buladiene
Acetone
Dicnloromelhane
Melhanoi
Carrjon Disuiiide
Melhyl Ethyl Kelone
1.1.1-rncftloroethane
Slyrene
Toluene
2-Melnoxyelhanol
Xylene (Mixed isomeis)
Carbon DisuNlde
Acetone
Chlorine
Melhyl Elhyl Kelone
Benzene
Ammonia
Dictiloromeihane
Melhanoi
Formaldehyde
Vinyl Acetate
Aluminum (Fume Or Oust)
Toluene
Ammonia
Xylene (Mixed Isomers)
Benzene
Propylene
Methyl Elhyl Kelone
Elhyiene
Cyciohexane
Elnyibenzene
9,247,121
6,055.900
3.312.000
547.450
294,466
249,300
165,000
160.000
152.400
32,103.301
16,358.650
14,365.315
12,545.969
10,838.970
8.924.197
5,718.987
4.818,265
2.581.234
2.499.716
19.505.899
15.985.519
12.274.666
11.563,725
10,192.177
7.950.605
5,913.805
5,170,321
3,751.355
2,920.850
96.776.COO
2,680.612
1,600,500
319,591
236.000
200.000
145,671
104.717
60,300
6,255
16,892.406
15,101.790
12.993.527
7,773.756
7.546,215
5.554.706
5.244.661
2,936.605
2.575366
2,007.157
507
267
190
117
103
080
067
059
049
046
1620
094
061
034
DOS
003
003
002
002
002
325
166
146
127
110
090
058
049
026
025
1080
885
680
640
564
440
327
286
208
162
981
027
016
003
002
002
001
001
001
000
1607
1437
1236
740
718
528
499
279
245
191
Toui % 01
E-.ss.ons 2 Digil
Ran. SIC (in/yr) SCCooe RIM
7 3711 85.315599
8 2611 84,697.366
9 3339 83.513.443
10 2819 SB 764.259
11 2621 51,231833
12 3312 49,987.449
3542 1
2
3
4
5
6
7
8
9
10
3157 1
2
3
4
5
6
7
8
9
10
3119 1
2
3
4
5
6
7
8
9
10
596 1
2
3
4
5
6
7
8
9
10
191 1
2
3
4
5
6
7
8
9
10
1867 1
2
3
4
5
6
7
8
9
10
C.iemical
Xylene (Mned Isomers)
Melhyl Elhyl Kelone
Toluene
Glycol Ethers
n-8ulyl Alcohol
Acetone
Melhanoi
Melhyl isooulyl Kelone
l.l.l-Tnchloroelnane
Dichloromelhane
Melhanoi
cnionne
Chloroform
Hydrochloric Acid
Cnlorme Dioxide
Ammonium Suitale (Solution)
Acetone
SuifuncAcx)
Ammonia
Sodium Hydroxide
Chlorine
Hydrochloric Acid
Ammonia
Melhyl isooutyl Kelone
Hydrogen Fluoride
Freonll3
Telrachloroelhylene
Lead Compounds
1,1.1-Tnchlofoethane
Zinc Compounds
Aluminum (Fume Or Dust)
Ammonia
Melhanoi
Chlorine
SulluncAod
Sodium Hydroxide
Hydrochloric Acid
Carton Disullide
1.1,1-Tnchloroelhane
Phosphoric Acid
Hydrcchlonc'Acid
Melhanoi
crilorolorm
Chlonne
Cnionne Dioxide
Ammonia
Acetone
Toluene
SulluncAod
Aluminum (Fume Or Dust)
Benzene
Ammonia
1.1.1-Tncnkmetnane
Aluminum (Fume Or Dusl)
Zinc Compounds
Hydrochloric Acid
Toluene
Zinc (Fume Or Dusl)
Manganese Compounds
Xylene (Mixed Isomers)
loai % a loai
Emissions 2 Dicil
(IWyr) SC
24.019.775
18.096.433
11.859.125
9.208.078
5.182.218
4.483.403
2.994.292
2.323295
2.130.966
1.941.284
31.369.292
12.648.742
8.797.499
8.377,238
8.059.441
5.800.000
5.055.654
1.576.481
747.880
544.834
68.129.251
9.190.762
2.3S2.29S
1.653.732
972.432
332.042
244.734
203.800
142.496
74.100
16.492.956
11.041.969
8,051.516
5.524.339
2.816.565
2.556,594
1.952.438
1,827,677
782.017
699.901
13,680.081
11.478.110
5.927.793
5.385,780
2.825.944
2.696.672
2.441.534
1.590.991
1.366.459
680.104
13.017.860
6.915.147
4.888.989
3,981,025
3.600.843
2.453.953
2.120.012
1.886,765
1,545.836
1.386,554
997
• 751
492
382
215
186
124
096
088
081
1169
471
328
312
300
216
188
059
028
020
2544
343
088
062
036
012
009
008
005
003
167
112
082
056
029
026
020
019
008
007
510
428
221
201
105
101
091
059
051
025
486
258
183
149
134
092
079
070
058
052
E-12
-------
Table E-8 (Continued)
Top Industrial Emitters —1987 4-Digit SIC Codes
Ran. SIC
13 3334
14 2754
15 2634
16 3861
total %0f
Emissions 2 Dign
(iwyrl SCCooe ftr.i
48.09S.819 1795 1
2
3
4
5
6
7
e
9
10
43,356.977 6846 1
2
3
4
5
6
7
8
9
10
40,207.929 4 OB 1
2
3
4
5
6
7
8
9
10
40,015.487 6552 1
2
3
4
5
6
7
8
9
10
C.tonia
Aluminum (Fume Or Dusl)
Hydrogen Fluoride
Chlorine
Methyl Elhyl Kelone
Toluene
1,1.1-Tnchloroelhane
Ammonia
Methyl isobulyl Kelone
Xylene (Mixed Isomers)
n-Bulyl Alcohol
Toluene
Melnyl Ethyl Kelone
Xylene (Mixed Isomeis)
GlyoU Ethers
Melhanol
1,1,1-Tnchloroelnane
2-Elhoxyethanol
Acetone
Melnyl Isobulyl Kelone
Elhylbenzene
Oichloromelhane
Acetone
Melhanol
Toluene
Methyl isotulyl Kelone
Xylene (Mixed Isomeis)
Acetonitrile
Chloromelhane
n-Bulyl Alcohol
Cycloheune
Oichloromelhane
Melhanol
Acetone
Toluene
Methyl Ethyl Kelone
ElhyleneGlycol
Xylene (Mixed Isomers)
i,l.l-Tncnloroelnane
Hydrochloric Aad
n-Bulyl Alcohol
total %01Ioiai
Emissions 2 Dion
(IB/yr) SB
38.823.156
5.943362
960.555
726.500
485.000
356.156
200.000
199.500
121.500
92.400
37.315.958
2575.263
1 168,018
1005.156
520.476
230.647
162.760
150.570
66.726
37.055
18.546.989
6.819.137
5.713.797
2.935.738
1.526.670
875.179
659.231
525.300
330.130
263.723
16.691.426
8.854.103
6.252,554
1.271.088
1.183,432
912.379
670.520
635.330'
556.108
371.851
1450
222
036
027
018
013
007
007
005
003
5892
407
184
159
082
036
026
024
011
006
1.88
069
058
030
015
009
007
005
003
003
2733
1450
1024
208
194
149
110
104
091
061
Ri-< SIC
17 2641
18 3714
19 2631
20 3679
loiai «OI
Emissions 2 Died
(iQ/y) SCCnc Ran.
39.835.213 1485 1
2
3
4
5
6
7
a
9
to
37.307.592 1549 1
2
3
4
5
6
7
8
9
10
36,025.347 1343 1
2
3
4
5
6
7
a
9
10
35.703.426 2786 1
2
3
4
5
6
7
8
9
10
Oemicai
Toluene
Melhanol
Methyl Elhyl Kelone
Hydrochloric Acid
Acetone
Xylene (Mixed Isomers)
Chloroform
n-Bulyl Alcohol
Ammonia
Methyl Isobulyl Kelone
Xylene (Mixed Isomers)
Tnchlorcelhylene
1,1.1-Tnchloroelhane
Toluene
Methyl Elhyl Kelone
Acetone
Freonm
Telrachloraelhylene
Oichloromelhane
Glycol Biters
Melhanol
Acetone
Chloroform
Hydrochloric Acid
Clilonne
Chlonne Dioxide
Toluene
SulluncAad
Methyl Elhyl Kelone
Ammonia
Methyl Elhyl Kelone
Toluene
Dicnioromelhane
Acetone
Freonm
1.1.1-Trichloroelhane
2-Methoxyemanol
1,1.2-Tnchloroelhane
Tetrachloroethytefle
Melhanol
toai % 01 loai
Effusions 2-0*11
(iay) sic
21.648.738
5.117.577
3.471.665
2.466,778
1.932.211
1.805.782
810.000
390,650
320.523
305.815
6.203.469
5.030.495
4.560.023
4181.689
3,991,538
3.118.801
2.529.016
1 268.174
1.155.508
811.340
18.841.108
3,580.140
3.162.250
3.029.834
2.222.351
1.453.850
1.434,589
680.760
568.759
380,090
11.096.169
5,071,063
5,015,085
3,428.042
3.193,778
2.882,260
1.452.695
814.852
633,753
477.852
807
191
129
092
072
067
030
015
012
Oil
258
209
189
174
166
129
105
053
048
034
702
133
1 18
113
083
054
053
025
021
014
866
396
391
267
249
225
113
064
049
037
E-13
-------
TABLE E-9
National Emissions of HAPs
- 1987 —
Cnemcai
Toluene
Melhanoi
1.1 i-Tricnioroeihane
Melhyl Ethyl Kelone
Xylene (Mixed Isomers)
Carbon Oisullide
Oicntoromethane
Chlonne
Hydrochloric Acid
Trichloroelhylene
Glycol Elhers
Telrachloroelhylene
Slyrene
Benzene
Melhyl isoDulyl Kelone
Chlorolorm
CarbonylSullide
Elhyiene Glycol
Formaldehyde
Chioromelhane
Hydrogen Fluoride
1,3-Buladiene
Phenol
p-Xylene
Vinyl Acelale
Elhylbenzene
1.2-0ichloroelhane
Acelaldenyde
Acrylonilnle
Elhyiene Oxide
Naphthalene
Chlorooenzene
Chloroelhane
Carbon Telracnlonde
o-Xylene
Melhyl Melltacrylale
Propyiene Oxide
Cumene
m-Xylene
Oimelhyl Phlhalale
Methyl Terl-Buiyi Elher
Bromomelrane
1,1,2-Tnchloroelhane
Manganese Compounds
Vinyl Chloride
Aceionnnie
Di(2-Elhylhexyl) Phlhalale
Bignenyl
i.2.4-Tnchlorooenzene
1,4-Dichioiobenzene
Lead Compounds
Propionaldehyde
Chloroprene
1.2-Oichloropropane
MaieicAnhydnde
Meinylenet»s(Phenyiisocyanale)
Acrylic Add
No 01
3,370
Z006
3235
2230
2.878
75
1,474
1,210
2.088
888
995
651
923
460
778
157
24
746
686
79
377
140
474
52
140
426
112
54
95
190
347
68
42
87
90
183
119
94
67
47
77
22
51
270
46
61
186
151
49
18
384
14
12
12
135
151
127
roai
Emisions
287.852.372
215.232.880
162.870,224
152.253.887
147.727.850
135.392.401
131.093.612
107.179.298
72.783.444
53,740.241
41.994.951
32,701,045
32,076,780
31.203577
29.595.348
24,674,317
22,487,005
15,428,233
• 13,455.716
13,134,398
11,753,891
9.413.317
8.165,985
7,437.936
6,860.626
6.513.347
6.368,587
6,363.086
5.387.496
5.184.403
4.591.734
4.577.763
4.400.509
4.378.209
3.680.212
3.636,833
3.606.194
3.396.957
2.995.819
2.347.449
2.326.574
2,191.755
2.139.959
1.974.094
1.794.472
1.766.266
1.625.907
1.586.032
1.388.982
1.244,833
1.158.164
1.111.191
1,064,028
1.017.620
918.611
834.270
831.599
% 01 CHemai 1
tool HAPs
Erasions
1540
1151
871
814
790
724
701
573
389
287
225
175
172
167
158
132
120
083
072
070
063
050
044
040
037
035
034
034
029
028
025
024
024
023
020
019
019
018
016
013
012
012
Oil
Oil
010
009
009
008
007
007
006
006
006
005
0,05
004
004
01 Total mi
Efro&ons
1046
782
592
553
537
492
476
389
264
195
153
119
117
113
108
090
082
056
049
046
043
034
030
027
025
024
023
023
020
019
017
017
016
016
013
013
013
012
011
009
008
008
008
007
007
006
006
006
005
005
004
004
004
004
003
003
003
C.-e-iai
Cresol (Mixed Isomers)
Urelnane
Toiuene-2 4-Onsocyanale
Chromium Compounds
Aniline
Phlhalic Anhydride
Dielhanolamme
Vinyiidene Chloride
2-Nilroprapane
Epichlorohydrin
i.4-0ioxane
Oiburyl Phlhalale
Nickel Compounds
Melhyl Isocyanale
Arsenic Compounds
Ethyl Acrylale
Ally) Chloride
Tilamum Telrachloride
Cadmium Compounds
N.N-Oimelhyiamline
1.1.2.2-Telracnioroelhane
p-Phenylenediamme
Nitrobenzene
Antimony Compounds
4 4'-Melhylenedianiline
2 4-Omilrololuene
p-Cresol
Phosgene
Diberuoturan
1,2-Bulyiene Oxide
1.2-Dibromoelhane
o-Cresol
Hexacniorocydopeniaoiene
o-Toluidine
Vinyl Bromide
Asbestos (FnatHe)
Cobalt Compounds
Benzyl Chloride
Acrolein
Acryiamide
i.3-0ichioropropyiene
Hydroqumone
Hydrazme
ChioroaceiicAad
Oumoiine
Captan
Phosphorus (Yellow Or White)
Benzoic Trichloride
m-Cresol
Penlachlorophenol
Caiaum Cyanamide
Oimelhyl Sullale
Dielnyl Sullale
Heplacnior
Chtordane
Canary!
3is|2-Chloroelhyl) Elher
No 01
Ernws
87
7
207
546
51
135
175
21
13
67
51
73
251
5
105
95
17
26
52
17
16
6
15
100
17
10
15
30
98
11
34
24
3
11
2
60
72
39
13
35
5
22
37
19
32
17
22
5
12
45
1
19
15
1
3
13
5
Tool
Emissions
797.542
797,000
788,742
775.139
676.574
597.648
490.090
466.859
466.252
423.522
375.436
349.201
306.365
286.544
284,221
262.675
177.776
169.165
163.918
129.829
126.289
117.362
115.893
111.064
101.811
99.498
66.584
83,640
76.545
66,050
65.669
57.382
55.779
54.254
53.700
51.461
49.681
48.832
48.710
35.694
34.070
30.968
29.041
28.612
27.405
27.365
26.252
24.010
20.450
16.740
12.750
10.836
10,829
8,178
7.158
6.944
6.627
%OI 1
loaiHAPs
Emissions
004
004
004
004
004
003
003
002
002
002
002
002
002
002
002
001
001
001
001
001
001
001
001
. 001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
0.00
000
on
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
"lenai %
ot tooi mi
003
003
003
003
002
002
002
002
'002
002
001
001
001
001
001
001
001
001
001
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
E-14
-------
Table E-9 (Continued)
National Emissions Of HAPs -m?
CRerc'tti
Hexachloroeltune
4-Nilrophenol
2.4-0
Selenium Compounds
o-Anisidine
Hexacn!oii>-i.3-Butadiene
2,4-Oiaminololuene
Heuchiorotenzene
Trifluralin
Parainion
Mercury Compounds
Acelamide
Methyl Hydrazme
Calectiol
OicMorvos
4.6-Oinilro-o-Cresol
Ouinone
Slyrene Oxide
No 01
Eminen
15
5
14
6
4
7
2
B
B
7
5
1
3
3
5
5
2
2
toai
Emissions
(IBM
5.656
5.452
5.366
5153
3,603
3.560
3.417
3.339
2.842
2.358
2.336
1.742
1.683
1491
1.491
1.066
1.053
1.023
\QI C1WT1K2I%
loalHAPs OUoailRI
Emssnr.s Enism]
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
NO a
Oei?.
-------
TABLE E-10
National Emissions Of 33/50 Chemicals
— 1987—
Csemical
Toluene
1.1.1-Tnchloroelhane
Melhyl Ethyl Kelone
Xylene (Mixed Isomers)
Diohloromelnane
Tnchiorcelhylene
Telrachloroelhylene
Benzene
Melhyl Isobutyl Ketone
Chloroform
CarDon Tetrachtonde
Lead
Cyanide Compounds
NO 01
Emitters
3,370
3.235
2.230
2.878
1,474
888
651
460
778
157
87
472
205
loal
Emissions
287.852.372
162.870.224
152.253.887
147.727.850
131.093,612
53.740.241
32.701.045
31,203.577
29.595.348
24.674,317
4.378,209
1.469,218
1.419,188
%OI Cranial %
total 33/50 0 total
Cnenas 1W Emissions C'e-'o
2669
1510
1412
1370
1216
498
303
289
274
229
041
014
013
1046
592
553
537
476
195
119
113
108
090
016
005
005
Lead Compounds
Chromium Compounds
Nicnei
Chromium
Nictel Compounds
o-Xylene
m-Xylene
Cadmium Compounds
p-xylene
Mercury.
Cadmium
Mercury Compounds
mot
Emiiin
384
546
464
558
251
90
67
52
52
29
42
5
lot*
1.158.164
775.139
419,535
407195
306.265
3.680,212
2.995.819
163,918
7.437.936
23.409
14,119
2.336
1.078.363.155
% 0 Csemo! \
total 33/50 01 lota
Cncmicaii IRIEns&crs
Oil
007
004
004
003
034
028
002
069
on
000
on
10000
004
003
002
001
001
013
Oil
001
027
on
on
on
•win
TABLE E-11
National Emissions Of High Risk/Early Reduction Chemicals
— 19B7—
No 01
Cnemical Emitters
Benzene
1,3-Buladiene
Aoyiomlnle
Eltiyiene Oxide
Vinyl Chlonde
Cnioroprene
Methyl enebis(Phenytisocyanale)
Acrylic Add
Toluene-2.4-Onsocyanale
Chromium Compounds
Vinylidene Chlonde
Chromium
Melhyl Isocyanale
Arsenic Compounds
Cadmium Compounds
1,1,22-Telrachioroethane
Phosgene
Oibenzoluran
1,2-Oibromoelhane
460
140
95
190
46
12
151
127
207
546
21
558
5
105
52
16
30
98
34
Toil
Emissions
(ItVV)
31.203,577
9.413,317
5.387,496
5.184,403
1.794,472
1.064,028
834,270
831,599
788,742
775,139
466,859
407.195
286,544
284.221
163,918
126,289
83.640
76,545
65.669
%0t
ToalHion
RiWEmy cnmai %
Reduaion 01 Tail IRJ
Citcnals Emissions
5242
1581
905
871
302
179
140
140
131
130
078
068
048
048
028
021
014
013
011
113
034
020
019
007
004
003
003
003
003
002
001
001
001
001
000
000
000
ox
Cnenci
Asbestos (Friable)
Acrolein
Acrylamide
Hydrazme
Arsenic
BenzoicTndiionde
Mercury
Cadmium
Heplachlor
cniorflane
Bis(2-Cnioroelhyi) Ether
Hexacniorocenzene
Beryllium
Mercury Compounds
Beryllium Compounds
Propyleneimine
Chloromelhyl Methyl Elher
BisfChlorometnyi) Ether
No 01
Emiflen
60
13
35
37
42
5
29
42
1
3
5
8
5
5
6
1
3
1
row
Emissions
(Ib/Vr)
51.461
48.710
35,694
29,041
27.431
24.010
23.409
14,119
8,178
7,158
6.627
3.339
2,501
2.336
504
500
351
1
M 523 293
%0f
rail Hign
RisWiny Cnenoi %
flfflaetion 0 tool IRI
Ci^cinali Erasjions
009
008
006
005
005
004
004
002
001
001
001
001
000
on
on
on
on
on
1000
on
000
000
on
on
on
on1
on
on
on
on
on
on
on
on
on
on
on
2 IB
E-16
-------
TABLEE-12
National Emissions Of Carcinogens In TRI Database
— 1987—
C.iemical
Dichloromelhane
Tnchloroelhylene
Telrachioroethyiene
Slyrene
Benzene
Chloroform
Formaldehyde
cnioromethane
1,3-Butadiene
1.2-Oichioroelhane
Acrylomlrile
Elhylene Oxide
Carbon Telrachionde
1.1.2-Tnchloroelhane
Vinyl Chloride
Urelhane
Vmylidene Chloride
2-Niiropropane
Epichlorohydnn
Chromium
1.1,2.2-Telrachloroelhane
2.4-Dimtrotoluene
2.6-Oiniiroioiuene
1,2-Oibromoelhane
o-Toluidme
Asbestos (Friable)
Benzyl Chloride
Alpha-Napnthyiamine
No 01
Eminem
1.474
888
651
923
460
157
686
79
140
112
95
190
87
51
46
7
21
13
67
558
16
10
6
34
11
60
39
3
[OBI
Emissions
(la/Y'l
131.093.612
53740.241
32.701.045
32.076.780
31.203.577
24.674.317
13.455.716
13.134.398
9.413.317
6.368,587
5.387.496
5.184.403
4.378.209
2.139.959
1,794.472
797.000
466.859
466.252
423.522
407.195
126.289
99.498
86.906
65,669
54.254
51,461
48,832
30,577
-------
TABLEE-14
All Chemicals Reported
-1987-
Care
X
X
X
X
X
X
X
X
X
X
X
X
X
Ozone
Oepl HAP
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3X90 HfVEfl Chemcal
X 1,1.1-Tnchloroethane
X 1,1.2.2-Tetrachlofoethane
l.l,2-Trichlofoetnane
l.l-Dchloraettiylene
1.1 -Dimethyl Hydrazine
1 ,2.4-Trichlorobenzene
1 ,2,4-Trimethylbenzene
1.2-Butylene Oxide
X 1 .2-Dibromoethane
1 ,2-Ochlorobenzene
1.2-Dichloroettiane
1.2-dehloroethytenc
1.2-Qchloropropane
X 1.3-Buladiene
1,3-Dichlorobenzene
1 ,3-Dichloropropylene
1 ,4-Dichlorobenzene
1 .4-Dwxare
2.4-0
2.4-Oaminoanisole Sulfate
2.4-Oiaminotoluene
2.4-Dichlorophenol
2.4-Dimeihylphenol
2.4-Oinitrophenol
2,4-Dinitrotoluene
2.6-Onitrotoluene
2.6-Xylidine
2-Chbroacetophenone
2-Ethoxyethanol
2-Metfwxyethartol
2-Nitrophenol
2-Nitropropane
2-Phenoxyethanol
2-Phenyl phenol
3,3'-OichtofOb«nzidin8
4.4>-Oaminodiphenyl Ether
4.4'-lsopropylidenediphenol
4.4'-Meihylenebis(2-Chloroanil
4,4'.Methylenebis
-------
Table E-14 (Continued)
All Chemicals Reported —1987
Cm
X
X
X
X
X
X
X
X
X
X
X
X
Ozone
Oepl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
X
33/50 HFVER Clmncal
X Acrylonilnle
Ally! Chloride
Alpha-Naphthylamine
Aluminum (Fume Or Dust)
Ammonia
Ammonium Nitrate (Solution)
Ammonium Sullate (Solution)
Aniline
Anthracene
Antimony
Antimony Compounds
X Arsenic
X Arsenic Compounds
X Asbestos (Friable)
Banum
Banum Compounds
Benzal Chloride
X X Benzene
X BenzoicTnchlonde
Benzoyl Chloride
Benzoyl Peroxide
Benzyl Chloride
X Beryllium
X Beryllium Compounds
Biphenyl
Bis
(2-Chloro-i-Methyleihyl) Ether
X Bis(2-Chloroethyl) Ether
Bis(2-Ethylhe«yl) Adipate
X Bis(Chloromethyl) Ether
Bromomethane
Butyl Acrylate
Butyl Benzyl Phthalate
Butyraldehyde
C 1. Basic Green 4
C 1. Solvent Yellow 14
X X Cadmium
X X Cadmium Compounds
Calaum Cyanamide
Captan
Carbaryl
Carbon Oisullide
X Carbon Tetrachloride
Carbonyl Sulfide
Cateehol
Chloramben
X Chlordane
Chlorine
Chlorine Dioxide
Chloroacenc Acid
Cos No
000107131
000107051
000134327
007429905
007664417
006484522
007783202
000062533
000120127
007440360
007440382
001332214
007440393
000098873
000071432
000098077
000098884
000094360
000100447
007440417
000092524
000108601
000111444
000103231
000542881
000074839
000141322
000085687
000123728
000569642
000842079
007440439
000156627
000133062
000063252
000075150
000056235
000463581
000120809
000133904
000057749
007782505
010049044
000079118
Emitted To Air
<»*y)
5,387.496
177.776
30,577
90,852.286
289,662.920
6.834.718
6.470.413
676.574
151.994
43,543
111,064
27,431
284.221
51.461
114.889
1.133.332
4.634
31.203.577
24.010
37.357
5.492
48,832
2.501
504
1.566.032
724
6,627
111.953
1
2,191.755
689.940
275.776
2,432.099
2
4
14.119
163.918
12.750
27.365
6.944
135,392.401
4.378.209
22.487.005
1.491
500
7.158
107,179,298
12.998.539
28.612
EmttadToAII
Medu(byr)
9.635.421
227.582
30.577
1.311.504.672
368,616.760
49,725.630
23.394.634
1,982.099
170,735
219.915
2,115.850
99.808
24,822.418
1,529.791
1,568.465
10,365.248
4.634
32,395.082
24,010
167,357
7.242
51.552
31,121
514
1,753.297
724
6.789
114.104
1
2.193.955
693.322
276.526
2.452.404
2
4
112.150
545.957
13.000
33.965
10.568
135,422,421
4,602.326
22,487.005
58.781
500
26.987
114,644,868
13,069.694
58.848
E-19
-------
Table E-14 (Continued)
All Chemicals Reported —1987
Care
X
X
X
X
X
X
X
X
X
X
X
X
X
Ozeno
Dap) HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3*50 Hfl/ER Chwncal
Critoro benzene
Chtorobenzilate
Chtoroe thane
X Chloroform
ClUoromeihane
X Chioromethyl Methyl Elher
Chtoro phenols
X Chloroprene
Chtoro thalonil
X X Chromium
X X Chromium Compounds
Cobalt
Cobalt Compounds
Copper
Copper Compounds
Cresol (Mixed Isomers)
Cumene
Cumene Hydroperoxide
Cupferron
X Cyanide Compounds
Cydohexane
Decabromodiphenyl Oxide
Di(2-Elhylhexyl) Phthalate
Diaminotoluene (Mixed Isomers)
X Obenzofuran
Dibuiyl Phthalate
Dichloro benzene
(Mixed Isomers)
Dichlorobramomethane
X Dicnlorometfiane
Dichlorvos
Dntharolamine
Dwthyl Phthalate
Diethyl Sullaie
Dimethyl Phthalate
Dimethyl Sulfate
Epiehlorohydrin
Ethyl Acrylate
Ethyl ChlorohxfTiato
Elhylbenzene
Ethylene
Etnylene Glycol
X Ethyiene Oxide
Fluometuron
Formaldehyde
Freonn3
Glycol Ethers
X Heptachlor
Hexachtoro-1 ,3-Butadiene
X Hexachlorobenzene
CaiNo
000108907
00051 01 56
000075003
000087663
000074873
000107302
000126998
001897456
007440473
007440484
007440508
001319773
000098828
000080159
000135206
000110827
001163195
000117817
025376458
000132649
000084742
025321226
000075274
000075092
000062737
000111422
000084662
000064675
000131113
000077781
000106898
000140885
000541413
000100414
000074851
000107211
000075218
002164172
000050000
000076131
000076448
000087683
000118741
Emitted To Air
(IVyr)
4,577.763
269
4,400.509
24,674.317
13,134.398
351
1.066
1 ,064,028
21.081
407.195
775.139
31.815
49.681
2,645.718
3,372.953
797.542
3,396.957
220.947
830
1,419.188
12,111.673
155.091
1,625.907
49.159
76.545
349.201
71,709
250
131,093.612
1,491
490.090
191.953
10,829
2,347.449
10.836
423.522
262.675
11.730
6,513.347
60,011.146
15,428.233
5,184.403
2.111
13,455,716
56,946.595
41,994,951
8.178
3,580
3.339
Emitted To All
M«d«(Uyf)
4.715,888
269
4,403.975
25.997,905
13.379.506
351
11.465
1.112.505
21.321
2.843,430
19.881.416
57.643
114.914
137.098.132
33.601.752
4.071.488
3.408.821
284.723
830
1.523.629
12.521.421
156.167
1.636,938
79.502
101.498
641.955
137.637
250
132,423.723
1.491
614,486
192.673
11.579
2.353.381
17,516
508.663
286.538
11.730
6.660.307
60.027,032
21.951.378
6.414.959
2.111
21,801.329
56.995.795
42.332.632
8.180
3.840
3.867
E-20
-------
Table E-14 (Continued)
All Chemicals Reported —1987
Care
X
X
X
X
X
Ozona
OaH HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
33/50 HH/EH CrwmeaJ
Henachkxccydopentadiene
Heiachloroethane
X Hydrazine
Hydrochloric Acid
Hydrogen Cyanide
Hydrogen Fluoride
Hydroquinone
Isobutyraldehyde
Isopropyl Alcohol
(Manufacturing)
X Lead
X Lead Compounds
Lindane
m-Cresol
X m-Xylene
Malaic Anhydride
Maneb
Manganese
Manganese Compounds
X X Mercury
X X Mercury Compounds
Meihanol
Meihoxychlor
Methyl Acrylate
X Methyl Ethyl Ketone
Methyl Hydrazme
Methyl Iodide
X Methyl Isobutyl Ketone
X Methyl Isocyanate
Methyl Methacrylate
Methyl Ten-Butyl Ether
Melhytene Bromide
X Meihylenebis
(Phenylisocyanate)
Mchler'S Ketone
Molybdenum Tnoxide
N.N-Omethylanihne
n-Butyl Alcohol
n-Ooctyl Phrhalate
n-Nitrosodi-n-Propylamme
Naphthalene
X Nickel
X Nickel Compounds
Nitnc Aod
Nitnlotnaceac Acid
Nitrobenzene
Nitroglycenn
>Amsidine
o-Cresol
o-ToluKJine
CasNa
000077474
000067721
000302012
007647010
000074908
007664393
000123319
000078842
000067630
007439921
000058899
000108394
000108383
000108316
012427382
007439965
007439976
000067561
000072435
000096333
000078933
000060344
000074884
000108101
000624839
000080626
001634044
000074953
000101688
000090948
001313275
000121697
000071363
000117840
000621647
000091203
007440020
007697372
000139139
000098953
000055630
000090040
000095487
000095534
Emitted To Air
(toW
55.779
5.656
29.041
72,783,444
642.340
1 1 .753,891
30,968
1,321.567
2,003.603
1 ,469 218
1.158.164
811
0.450
2.995.819
918,611
35930
882.570
1 ,974.094
23.409
2.336
215.232.880
252
435.489
152.253.887
1.683
500
29.595.348
286,544
3.636.833
2 326.574
38.955
834,270
400
104.316
129,829
32.572,937
32.455
2.700
4.591.734
419.585
306.365
4,467,114
1,752
115.893
49.246
3,603
57.382
54.254
Eimtad To All
Madia (lyyr)
65.724
6.362
61 597
500.918.788
1.701.347
12.352.986
47.787
1.322.356
2.006.775
20,758.687
1 1 .396 696
811
20.700
3.040.289
939.161
35.930
13.124.443
33,607,289
53787
2.338
278.198,247
502
437.566
152421,441
1.683
555
30.859.054
286.544
3.899.788
2.429.226
39.205
845.315
400
196.735
147.692
35.565.346
33.975
2.700
4.792.254
1.133.943
4,329,551
11,665.104
11,952
693.469
66,065
4,460
61,303
55.852
E-21
-------
Table E-14 (Continued)
All Chemicals Reported—1987
Care
X
X
X
X
X
X
X
X
X
X
Ozona
Depl HAP
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
3X50 HH/ER Chanted
X o-Xytone
p-Cresidme
p-Cresol
p-Nitrosodiphenylamme
p-Phenylenediamme
X p-Xytene
Parathnn
Pentachkxophenol
Peraceoc Acid
DkaMMj
rnenoi
X Ph09Q6ne
Phosphoric Acid
Phosphorus (Yellow Or White)
Phthalic Anhydride
Piaic Aad
Polychlonnated Biphenyls
Propionaldehyde
Propoxur
Propytone
Propytene Oxide
X Propytaneimine
Pyndine
Quinolme
Quinone
Qumtozene
Saccharin (Manufacturing Only)
Safrole
Sec-Butyl Alcohol
Selenium
Selenium Compounds
Silver
Silver Compounds
Sodium Hydroxide
Styrene
Siyrene Oxide
SulfuncAcid
Tert-Buiyl Alcohol
X Tetrachkxoethylene
Tetrachkxvinphos
Thallium
Thallium Compounds
Thnurea
Thorium Dioxide
Titanium Tetrachloride
X Toluene
X Toluene-2,4-Diisocyanaie
Toluene-2,6-Oiisocyanate
Tnchlorfbn
X Tnchloroethylene
Tnfluralm
Urethane
E-22
CaNo
000095476
000120718
000106445
000156105
000106503
000106423
000056382
000087865
000079210
000108952
000075445
007664382
007723140
000085449
000088891
001336363
000123386
000114261
000115071
000075569
000075558
000110861
000091225
000106514
000082688
000081072
000094597
000078922
007782492
007440224
001310732
000100425
000096093
007664939
000075650
000127184
000961115
007440260
000062566
001314201
007550450
000108883
000584849
000091087
000052686
000079016
001582098
000051796
Entftad To A»
(«Vyr)
3.680.212
2.528
86.564
250
117.362
7,437.936
2.358
16.740
8,500
8,165.965
83.640
1,644.719
26252
597.648
750
751
1,111,191
2
38.906,600
3,606.194
500
298.438
27.405
1.053
254
750
500
906.268
4.527
5.153
12.767
11.507
7,164,466
32,076.780
1.023
15,654.427
1,467.630
32,701.045
10.415
54.411
250
6,020
1,580
169.165
287,852,372
788,742
382,825
9,953
53.740,241
2.842
797,000
EflMtadToMI
Mtdn (bfyr)
3.702.947
4,376
200,464
250
131,418
7.450.927
2,858
92.839
8.523
16.422.193
84.140
48,977,547
212.002
600.756
1.750
751
1.115,024
2
38.908,036
4,131.846
500
633.474
28.263
1.163
254
750
500
1.024.322
12.054
10.233
15.705
30.658
137.443.792
32.472.409
1.802
173.863.305
1 ,992.090
33,220.495
10.415
54.411
250
28.010
1.580
169.940
291286.873
789.992
385.025
9.953
53.843.534
3.099
797.935
-------
Table E-14 (Continued)
All Chemicals Reported —1987
Care
X
X
Onxw
Oopl HAP
X
X
X
X
X
33/50 HR/Efl Crwmcal
Vanadium (Fume Or Ousi)
Vanadium Compounds
Vinyl Acetate
Vinyl Bromide
X Vinyl Chloride
X Vinylidene Chloride
X Xylene (Mixed Isomers)
Zinc (Fume Or Dust)
Zinc Compounds
Zineb
CM No
007440622
000106054
000593602
000075014
000075354
001330207
007440666
012122677
Emitted To Air
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E-24
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