ENVIRONMENTAL PROTECTION AGENCY OFFICE OF ENFORCED VI REPORT ON INVESTIGATION OF THE EFFECTS OF THE WASTE DISCHARGES FROM THE GREAT WESTERN SUGAR MILL AT OVID, COLORADO ON WATER QUALITY CONDITIONS IN THE SOUTH PLATTE RIVER NATIONAL FIELD INVESTIGATIONS CENTER-DENVER DENVER.COLORADO AND REGION VII KANSAS CITY.MISSOURI REGION DENVER.COLORADO JUNE 1972 tLEAl ------- ENVIRONMENTAL PROTECTION AGENCY OFFICE OF ENFORCEMENT EFFECTS OF WASTE DISCHARGES FROM THE GREAT WESTERN SUGAR MILL AT OVID, COLORADO ON WATER QUALITY CONDITIONS IN THE SOUTH PLATTE RIVER National Field Investigations Center - Denver Denver, Colorado and Region VII Region VIII Kansas City, Missouri Denver, Colorado ------- TABLE OF CONTENTS Title Page GLOSSARY OF TERMS ii LIST OF TABLES ill LIST OF FIGURES ill I. INTRODUCTION 1 II. SUMMARY AND CONCLUSIONS 2 III. RECOMMENDATIONS 4 IV. APPLICABLE WATER QUALITY REQUIREMENTS 5 A. Water Quality Standards 5 B. Enforcement Conference Requirements 6 First Session 6 Second Session 7 Reconvened Second Session 7 V. WASTE SOURCES 9 A. Great Western Sugar Company Mill at Ovid. . . 9 B. Ovid Wastewater Treatment Plant 12 C. Julesburg Wastewater Treatment Plant 12 VI. STREAM SURVEYS 15 A. September 27-29, 1971 15 B. November 29-December 3, 1971 18 C. Low Flow Conditions 20 REFERENCES 21 APPENDIX A - COLORADO WATER QUALITY STANDARDS APPENDIX B - NEBRASKA WATER QUALITY STANDARDS FOR THE PROTECTION OF CLASS "C" WATERS APPENDIX C - WATER QUALITY OBJECTIVES RECOMMENDED TO THE CONFERENCE AS A RESULT OF STUDIES CONDUCTED BY THE SOUTH PLATTE RIVER BASIN PROJECT ------- GLOSSARY OF TERMS BOD - Biochemical Oxygen Demand, 5-Day COD - Chemical Oxygen Demand DO - Dissolved Oxygen TOC - Total Organic Carbon SS - Suspended Solids RM - river mileage cfs - flow rate given in cubic feet per second gpm - flow rate given in gallons per minute mgd - flow rate given in million gallons per day mg/1 - concentration given in milligrams per liter ymhos/cm - unit of specific conductance (mho — the inverse of the standard unit of electrical resistance, the ohm) measured over a 1-centimeter distance, conven- ventionally made at 25°C. ii ------- LIST OF TABLES Table No. Title Page 1 Results of Bacteriological Analyses - 10 South Platte River (SPR) from Ovid, (Colorado) Downstream to the 1-30 Highway Bridge (Nebraska) (November 29-December 3, 1971) 2 Summary of Field Measurements and 13 Analytical Results - South Platte River (SPR) from Ovid (Colorado) Downstream to the 1-80 Bridge (Nebraska) (November 29-December 3, 1971) 3 Results of Bacteriological Analyses - 16 South Platte River (SPR) from Ovid (Colorado) Downstream to the 1-80 Highway Bridge (Nebraska) (September 27-29, 1971) 4 Seven-Day Flow Periods for Each Year 20 LIST OF FIGURES Figure No. Title Follows Page 1 Location Map Water Quality Invest!- 15 pations in the South Platte River Ovid, Colorado iii ------- I. INTRODUCTION The Great Western Sugar Company (subsidiary of the Great Western United Corporation) operates a sugar-beet processing mill at Ovid, Colorado, on the South Platte River near the Colorado-Nebraska state line. Inadequately treated industrial wastes from this mill are discharged to the River about 11 miles upstream from Nebraska. Small volumes of municipal wastes from the Colorado communities of Ovid and Julesburg are also discharged to this reach of the river. Investigations of the water quality in the reach of the South Platte River affected by the sugar mill waste discharges were conducted, by the National Field Investigations Center-Denver of the Environmental Protection Agency (EPA) from September to December 1971, in order to define conditions prior to and during the sugar-beet processing season. Waste sources were also evaluated. This report summarizes the results of these investigations. Observed water quality conditions are compared to applicable water quality regula- tions. Violations of water quality standards are defined. A comparison is also made to water quality conditions existing in 1963. Remedial measures to abate existing interstate pollution that is in violation of water quality standards are recommended. ------- II. SUMMARY AND CONCLUSIONS Although there has been a reduction in the waste loads discharged from the Great Western Sugar Company mill at Ovid, adequate waste treat- ment is not being provided. The compliance date set at the Enforcement Conference for meeting the water quality standards has not been achieved. The coliform bacteria densities in the South Platte River, downstream from the plant, are similar to those observed in 1963 when the flow con- ditions were approximately the same. The Colorado and Nebraska Water Quality Standards for bacteria are being violated as a result of the discharge from the Great Western mill at Ovid — with the log mean fecal- and total-coliform bacteria densities both being 60 times greater than the Nebraska Standards, and the log mean fecal coliform bacteria levels being about 90 times greater than the present Colorado standards at the state line. During the November-December survey, the Great Western Sugar Company mill at Ovid was discharging into the South Platte River, an average of 10,200 Ib of BOD and 3,800 Ib of suspended solids per day, thus greatly exceeding the waste loads attainable by the base-level treatment practices for the sugar beet industry (1400 Ib/day each of 5-day BOD and suspended solids for present plant operation). The Great Western mill at Ovid provides marginal primary treatment in its sedimentation ponds — detention time decreasing as the pond fills up with solids. Requirements of the State of Colorado that wastewaters ------- receive a minimum of secondary treatment with 80 percent removal of BOD plus disinfection were not being met. A higher degree of treatment should be required if necessary to protect designated uses listed in approved State-Federal water quality standards. In view of the observed low flows that have occurred during the past ten years it is clear that the discharges from the Great Western Sugar Company mill at Ovid have caused serious recurring water quality problems in the receiving waters. In the absence of satisfactory treatment un- acceptable conditions may be expected to recur during each sugar-beet pro- cessing season. Reduction of discharge waste loads to levels attainable with base-level treatment (0.5 Ib each of 5-day BOD and suspended solids per ton of beets processed) could be expected to provide adequate protec- tion of the receiving waters. Municipal waste discharges from the Ovid and Julesburg treatment plants contributed insignificant waste loads and bacterial populations; however, on October 6, 1971, the latter facility was not operating at the efficiency required by the Colorado Water Pollution Control Commission. In addition to violations of established standards, the water quality objectives recommended by the South Platte River Basin Project were not being met [Appendix C]. The biological studies indicated that algal and slime growths occurred in the South Platte River downstream from Ovid as a result of waste discharged bv the Great Western mill. Violations of Sections B & D of the Basic Standards Applicable to all Waters of the State were occurring. ------- III. RECOMMENDATIONS In order to achieve early abatement of pollution of the interstate waters of the South Platte River caused by discharges of inadequately treated industrial wastes from the Great Western sugar-beet processing mill at Ovid, Colorado (owned and operated by the Great Western Sugar Company, subsidiary of the Great Western United Corporation), it is recommended that: 1. The Great Western Sugar Company develop a schedule for implemen- tation of necessary waste treatment facilities and practices at its Ovid mill to provide adequate treatment of all wastes dischareed during the 1972-73 sugar beet processing campaign. This implementation schedule should be submitted to the Environmental Protection Aeency for approval within 60 days of the 180-day Notice He.irinn. 2. Condenser and transport waters be separated; transport and gen- eral plant wastes be completely recycled and re-used. 3. The combined waste discharges from the Great Western mill at Ovid contain not greater than 0.5 Ib each of BOD and suspended solids/ton of beets sliced with the total load of each not to exceed 1,400 Ib/day, whichever is less. A. The number of fecal coliform orpanisms in the combined dis- charges not exceed 75 x 10 organisms per ton of beets or a density of 1,000/100 ml, whichever is less. ------- IV. APPLICABLE WATER QUALITY REQUIREMENTS A. WATER QUALITY STANDARDS Water quality standards applicable to the South Platte River and its tributaries in Colorado were established in June 1967 by the Colorado Water Pollution Control Commission — in accordance with pro- visions of the Federal Water Pollution Control Act, as amended.— These standards were subsequently revised and fully approved as Federal standards. They consist of three components: 1) Stream classifications that designate water uses to be protected; 2) Water quality criteria that specify water quality conditions which must be maintained; 3) An implementation plan that establishes time schedules for providing adequate treatment or control facilities for all sources of pollution. Colorado classified the South Platte River from the Denver area downstream to the Nebraska state line for industrial and agricultural water uses (Class C and D). In order to achieve compatability with Nebraska water quality standards, Colorado classified the River at the Nebraska State Line as a warm-water fishery (Class B-2) and for irrigation (Class D-l). [Water quality criteria applicable to these classifications are summarized in Appendix A.] An implementation schedule was established that required the Ovid sugar-beet processing mill to be in compliance with the water quality standards by December 31, 1968. Water quality standards applicable to the South Platte River were also established by Nebraska in June 1967. These standards were subse- quently revised and fully approved as Federal standards. Nebraska classi- fied the South Platte River downstream from the Colorado state line for ------- agricultural and industrial uses, partial body contact sports, and for fish and wildlife (Class C). [Applicable water quality criteria are summarized in Appendix B.] B. ENFORCEMENT CONFERENCE REQUIREMENTS First Session In 1963, the First Session of the Conference in the Matter of Pollution of the South Platte River Basin in the State of Colorado was called, under provisions of the Federal Water Pollution Control Act, by the U. S. Department of Health, Education, and Welfare at the request of Colorado Governor, John Love. The Session reviewed existing water pollution and pollution-abatement practices in the South Platte River Basin and formulated objectives calling for studies to develop plans for the control and abatement of water pollution therein. To carry out the objectives laid down by the First Session, a South Platte River Basin Project was established. A study, to be conducted jointly with the State of Colorado, was undertaken to determine legitimate water uses and locate the sources of pollution having an adverse effect on those uses; through field investigations to determine the physical, chemical, and biological responses of the South Platte River to pollution and to evaluate the previously located sources of pollution with respect to the conditions in the River; and to compute the waste»load reductions necessary to obtain desired water quality and to recommend the water quality control measures needed to effect the desired-waste load reductions. ------- Second Session The Second Session of the Conference, held in April 1966, was largely devoted to presentation of the results of the Project's studies, including water quality objectives that were recommended for the South Platte River and waste treatment requirements for the Ovid sugar beet mill [Appendix C]. These recommendations called for a high level of waste-load reduction to be achieved by the Ovid mill by September 30, 1968. The Conference adjourned without formulating specific pollution abatement recommendations in order to allow the new Colorado Water Pollution Control Commission sufficient time to study and evaluate the Project's report and to develop a program for implementation of remedial measures as well as a time schedule. Reconvened Second Session At the reconvening of the Second Session of the Conference in the Matter of Pollution of the South Platte River Basin in November 1966, the Conferees recommended that the final compliance date for providing adequate treatment of all waste discharges in the Basin be extended from the Project's recommended date of September 30, 1968, to June 30, 1971. "All discharges into the South Platte River Basin shall have adequate remedial or control facilities in full operation by June 30, 1971, so as to comply with water quality standards established by the Colorado Water Pollution Control Commission as approved 21 by the Secretary of the Interior."- ------- The Conferees did not specifically adopt the water quality objec- tives or waste treatment requirements recommended by the Project although a number of these recommendations were subsequently incorporated in the Colorado Water Quality Standards. ------- V. WASTE SOURCES A. GREAT WESTERN SUGAR COMPANY MILL AT OVID This mill processes approximately 2,800 tons of beets per day. The wastewaters (after screening) are discharged to two settling ponds (approxi- mately 750 ft by 75 ft). Only one pond is used at a time; when it has filled with solids, the other pond is used. The detention time is short — a matter of several hours depending upon the level of solids buildup in the ponds. The observed discharge during the 3-day sampling period (November 30 - December 3, 1971) averaged 4.9 mgd. The average dailv BOD and suspended-solids loads discharged were 10,200 and 3,800 Ib, res- pectively. This corresponds to a waste production of 3.6 Ib of BOD and 1.4 Ib of suspended solids per ton of beets processed per dav. (These values are approximately 700 and 300 percent above the waste loads attainable by base-level treatment methods for the sugar beet industry.) Bacteriological analysis indicated there were extremely high counts [Table 1] of fecal coll forms and fecal streptococci in the effluent (lop or geometric means > 1.9 x 10 /100 ml and > 5 x 10 /100 ml, respectively). In 1963 the only wastewater treatment provided at the Great Western mill was impoundment of lime muds. Studies by the South Platte River Basin Project revealed that wastewaters discharged to the South Platte River contained a BOD load of about 35,000 Ib/day. Screening was subse- quently installed, but the present settling ponds were not constructed until after the 1970-71 sugar-beet processing season. ------- TABLE 1 RESULTS OF BACTERIOLOGICAL ANALYSES SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) DOWNSTREAM TO 1-80 HIGHWAY BRIDGE (NEBRASKA) (November 29-December 3, 1971) Total Coliform Count/100 ml Station Number Station Description Fecal Coliform Count/100 ml Maximum Log Mean Minimum Maximum Log Mean Minimum Fecal Streptococci Count/100 ml Log Maximum Mean Minimum SP-1 SPR at 1-80 bridge down- stream Colo-Nebr. state line (Rm 81.1) SP-2 SPR at Jules- burg USGS gage d owns t earn f rom US 385 flow (RM 86.9) JULES-1 Effluent from Julesburg VJastewater Treatment Plant (RM 86.6) SP-3 SPR downstream Western dis- charge at Ovid, Colo. (RM 94.0) 1.6 x 10 610,000 370,000 1 x 10 1.8 x 106 790,000 400,000 210,000 2.5 x 106>1.4 x 106 120,000 40,000 >800,000 >150,000 36,000 93,000 45,000 >800,000 M50.000 15,000 310,000 160,000 53,000 580,000 910,000 290,000 160,000 >1 x 10 >680,000 110,000 ------- TABLE 1 (Cont.) RESULTS OF BACTERIOLOGICAL ANALYSES SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) DOWNSTREAM TO 1-80 HIGHWAY BRIDGE (NEBRASKA) (November 29-December 3, 1971) Total Coliform Fecal Coliform Fecal Streptococci Count/100 ml Count/100 ml Count/100 ml Station Number Station Description Log Maximum Mean Log Minimum Maximum Mean Minimum Maximum LOR Mean Minimum OVID-1 Effluent from Treat Western mill settling pond (RM 94.8) LD-1 Liddle Ditch at overflow struc- ture downstream of Lodgepole Creek (RM 95.1) SP-4 SPR at Colo. 23 bridge south of Ovid (RM 95.A) 4.3 x 106 >1.9 x 106 >600,000 >10 x 106 >5 x 106 >1 x 106 39,000 20,000 27,000 1,400 980 760 5,900 51,000 2,100 190 240 180 70 6,000 5,900 3,900 2,100 920 ------- B. OVID WASTEWATER TREATMENT PLANT This facility, an aerated lagoon followed by a polishing pond, should afford good secondary treatment. No evaluation of the Ovid plant was made. Owing to the small volume and location of the effluent, the discharge from the plant is not considered a significant source of pollution in the study reach. The effluent flows to Lodgepole Creek and subsequently to Liddle Ditch. Bacteriological samples and field measure- ments were made, during the stream surveys, at the overflow structure on Liddle Ditch immediately downstream of the Lodgepole Creek confluence [see Station LD-1, Tables 1 and 2]. The flow at the Liddle Ditch over- flow structure was estimated to be 25 cfs. C. JULESBURG WASTEWATER TREATMENT PLANT The plant was evaluated during the period October 3-6, 1971. The facility here includes primary sedimentation, a trickling filter, separ- ate sludge digestion, and a polishing lagoon. BOD removal varied from about 40 to 80 percent at an average daily flow of 0.2 mgd. The BOD and suspended-solids loads discharged were approximately 80 to 100 lb/ day. During the November 29 - December 3 stream survey, samples of the plant effluent were collected for bacterial analyses and field measure- ments only [Tables 1 and 2]. During this time the waste flow was esti- mated at 0.3 mgd. (BOD and suspended-solids loads and bacteria contribu- tions by the Julesburg waste treatment plant are insignificant.) 12 ------- JULES-1 SP-3 TABLE 2 SUMMARY OF FIELD MEASUREMENTS AND ANALYTICAL RESULTS SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) DOWNSTREAM TO THE 1-80 BRIDGE (NEBRASKA) (November 29-December 3, 1971) Station Number SP-1 SP-2 Description SPR at 1-80 (RM 81.1) SPR at Jules- Avg Flow (cfs) */ 330 pH Range 8.1 8.0-8.2 Cond. Range pmhos/cm 1500-1650 1500-1650 Temp. Range °F 33-36 33-37 DO Range 10.5-11.6 10.4-11.0 BOD mg/1 Range 3-5.4 3-5.4 Solids Total Avg 3.5 3.9 Range 1560-1690 1300-1600 Avg 1610 1500 , mg/1 Suspended Range Avg 120-185 150 95-150 120 burg USGS gage (RM 36.9) Effluent from 0.31 7.5-7.7 1650-1700 Julesburg waste- (est) water treatment plant (RM 86.6) SPR downstream Great Western discharge at Ovid (RM 94.0) 36-39 7.6-8.1 1550-1600 36-39 9.5-10.0 10-23 13 1570-3910 130-200 155 OVID-1 Effluent from Great Western at Ovid (RM 94.8) 7.6 6.3-7.1 1500-1750 81-86 180-290 250 1600-1690 1650 85-98 93 ------- LD-1 SP-4 TABLE 2 (Cont.) SUMMARY OF FIELD MEASUREMENTS AND ANALYTICAL RESULTS SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) DOWNSTREAM TO THE 1-80 BRIDGE (NEBRASKA) (November 29-December 3, 1971) Station Number Description Avg Flow (cfs) PH Range Cond. Range U mhos /cm Temp. Range °F Solids, mg/1 DO Range BOD mg/1 Range Avg Total Range Avg Suspended Range Avg 25 7.7-10.8 (est) Liddle Ditch at overflow structure down- stream Lodgepole Creek (RM 95.1) SPR at Colo. 23 c/ 8.0-8.2 1500-1650 bridge (RM 95.4) 1500-1550 35-38 10.8-11.2 33-37 10.8-11.6 2-3 2.7 1570-1670 1620 110-150 106 a./ Flow would be expected to increase between SP-2 and SP-1 at this time of year due to groundwater accretions. b/ BOD and solids are results of three 24-hr composite samples. All other stations, grab sampled once daily for five days. c/ Flow is expected to be less than at Julesburg by the amount of groundwater accretion between SP-4 and SP-2 and the Liddle Ditch overflow and Great Western discharge. Studies by the USGS have shown an increase of 1-2 cfs/mile between Sedgwick (upstream at RM 103.0) and Julesburg. ------- VI. STREAM SURVEYS A. SEPTEMBER 27-29. 1971 A limited stream survey was conducted during this period in the South Flatte River from Ovid (Colorado) to 1-80 (in Nebraska) [Figure 1] in order to determine bacterial conditions prior to the Fall 1971 sugar- beet campaign. Flow in the study reach was above normal during the survey owing to heavy precipitation about 10 days prior to the investigation. The flow at the Julesburg USGS gage was as follows: September 27 - 725 cfs September 28 - 650 cfs September 29 - 540 cfs Irrigation diversions and groundwater accretions cause variations upstream and downstream from Julesburg. For example, the Western Canal (in Nebraska, about one-third the distance between the state line and the intersection of 1-80 and the South Platte River) diverted an average of 90 cfs during this September period of investigation. No diversions occurred between Ovid and Julesburg. Thus, it is assumed that the flow was increasing downstream from Ovid — to near the state line because of the accretions. 'The DO levels at all stream stations were 80 to 110 percent saturation (7.4 - 10.4 mg/1) during the sampling carried out in this period. [Results of the bacterial analyses for this period are in Table 3.] Bacterial densities well below the limits specified by the Nebraska and Colorado Water Quality Standards were observed at all stream stations. 15 ------- JULESBURG JULES 1 SM SP 4 STP OVERFLOW STRUCTURE COLO.23 SP-3 RIVER *^ \ U.S.385 SP-2 STATION LOCATIONS Figure 1 Location Map Water Quality Investigations in the South Platte River Ovid, Colorado. ------- TABLE 3 RESULTS OF BACTERIOLOGICAL ANALYSES SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) TO THE 1-80 BRIDGE (NEBRASKA) (September 27-29, 1971) Station Number SP-1 SP-2 JULES-1 Station Description SPR at 1-30 bridge just be- low Colo-Nebr. state line (RM 31.1) SPR at USGS gage downstream of US 385 bridge- Julesburg, Colo. (RM 86.9) Julesburg Waste- water Treatment Plant effluent (RM 86.6) Total Coliform Count/100 ml Log Maximum Mean T'inimum 2,2005-/ 1,500 1,100 a/ a/ a/ 1 , 300— 800— 400-1 >800,000 >280,000 >80,000 • Fecal Coliform Count/300 ml Log Maximum Mean ?finimum 530 220 100 520 <80 <10 260,000 33,000 20,000 Fecal Streptococci Count/100 ml Log Maximum Mean Minimum 3,400 1,500 490 4,200 1,800 520 LC-1 Lodgepole Creek at U.P.R.R., bridge in Ovid (RM 95.2/0.8) 3,400^ 1,600^ 600^ 500 240 50 4,600 1,800 620 ------- TABLE 3 (Cont.) RESULTS OF BACTERIOLOGICAL ANALYSES SOUTH PLATTE RIVER (SPR) FROM OVID (COLORADO) TO THE 1-80 BRIDGE (NEBRASKA) (September 27-29, 1971) Total Coliform Count/100 ml Fecal Coliform Count/100 ml Fecal Streptococci Count/100 ml Station Number Station Description Maximum Log Mean Minimum Maximum Lop Mean Minimum Maximum Log Mean Minimum LD-1 Liddle Ditch at diversion struc- ture below mouth of Lodgepole Creek (RM 95.1) (4 samples only) SP-4 SPR at high- way bridge south of Ovid (RM 95.4) 1,800^ 1,300 600*' 370 200 110 4,100 1,500 120 3,000^ 1,800^ 1.2002-' 290 220 170 4,100 1,500 300 a/ Total coliform results estimated because of high background colonies, ------- B. NOVEMBER 29 - DECEMBER 3. 1971 The study reach was sampled for five consecutive days. Significant inflows were sampled at the same time [Tables 1 and 2]. During this period of the investigation no diversions occurred between Ovid and the 1-80 bridge. Water quality data at the background station (SP-4) indicate both low fecal-coliform bacteria levels and BOD [Figure 1, Tables 1 and 2]. (A survey, conducted by the South Platte River Basin Project during December 1963, also showed low densities of fecal coliform bacteriaa (<300/100 ml) and low levels of BOD (<3 mg/1) at SP-4 during similar flow conditions.) The river was clear and the sand bottom free from sludge deposits. The benthos was limited to eight kinds of organisms because the shifting sand bottom was a poor habitat. However, the benthos commun- ity included pollution-sensitive forms, such as caddisflies and mayflies, indicating this reach was free from serious pollution. Log mean concentrations of fecal conforms, from samples taken down- stream from the discharge of the Great Western mill (SP-3), were more than 1,600 times the log mean values found at SP-4. The instream BOD and suspended-solids levels were increased by the Great Western mill (Ovid) discharge — with average BOD and suspended solids values at 13 mg/1 and 155 mg/1, respectively. (When compared with the BOD values — consistently above 20 mg/1, observed during the December 1963 survey downstream from Ovid, a slight improvement is evident.) The Great Western mill discharge stimulated algal and slime growth. Blanketing portions of the sandy 18 ------- stream bed were sludge deposits composed of organic materials. These deposits provide habitat and feed for the sludgeworm-dominated benthic community. Therefore, in this reach violations of Sections B & D of the Basic Standards Applicable to all Waters of the State were occurring. There was, during this investigation, no significant decrease in the bacterial levels measured at the Julesburg gage (SP-2) from the values found at SP-3. The SP-2 station is upstream of the discharge from the Julesburg wastewater treatment plant and approximately three miles upstream of the Colorado-Nebraska state line. The BOD at SP-2 had decreased to background levels. (Compared with the 1963 survey data, there was an improvement in water quality.) At this station algal and slime growths were reduced. Data obtained at the 1-80 highway bridge (SP-1) indicated the geo- metric mean fecal collform densities were 120,000 per 100 ml, or 60 times greater than the Nebraska standards (2,000/100 ml), i.e., a violation of the Nebraska Water Quality Standards for bacteria. Log mean total coli- form values were 610,000 per 100 ml, more than 60 times greater than the allowable limit of 10,000/100 ml (log mean). Dense algal growth bordered 2 the stream bed. Benthos numbered more than 5,900/ft of which more than 4,900 were pollution-tolerant sludgeworms. Observed log or geometric mean fecal-coliform bacteria densities both upstream and downstream from the Colorado-Nebraska state line (SP-1 and SP-2) were more than 90 times greater than the Colorado Standards for bacteria applicable to the South Platte River at the state line. Viola- tions of the Colorado Water Quality Standards were thus also occurring. 19 ------- C. LOW FLOW CONDITIONS [Flow data are shown in Table 2 for selected stations during the survey.] The annual processing of sugar beets (often termed a campaign) is normally conducted during the period October 1 through February 1. Because low flows are experienced during at least part of this period and are significant in water quality, NFIC-Denver made an examination of the records in order to compare data and obtain a profile over a 10- * year period. Review of the flow records for the USGS station at Julesburg indicates that the average flow during the month of December — for the years 1961-70 — was about 360 cfs. The 7-day low flow (during the October-February period) for each year during this 10-year period occurred in the month of October 70 percent of the time. TABLE 4 SEVEN-DAY FLOW PERIODS FOR EACH YEAR Water Year 1961 1962 1963 1964 1965 1966 1967 1968 1969 1970 Dates 10/1-10/7 10/1-10/7 10/25-10/31 11/1-11/7 10/1-10/7 1/21-1/27 1/24-1/30 10/1-10/7 10/1-10/7 10/1-10/7 7-Day Low Flow Oct. 1 - Feb. 1 (cfs) 26.7 889 219 126 20.5 447 114 66 113 107 (10-year, 7-day low flow) 20 ------- REFERENCES 1. Water Quality Standards for Colorado, State of Colorado, Department of Health, Water Pollution Control Commission, Denver, Colorado, 1970. 2. Summary of Reconvened Second Session, Conference in the Matter of Pollution of the South Platte River Basin, Colorado, U. S. Department of the Interior, Federal Water Pollution Control Administration, November 10, 1966. 21 ------- APPENDIX A COLORADO WATER QUALITY STANDARDS ------- COLORADO WATER QUALITY STANDARDS Waters of the State, the quality of which exceeds the limits set in these standards, will be maintained at existing quality unless and until it can be demonstrated to the State that a change in quality is justified to provide necessary economic or social development. In that case, the best practicable degree of waste treatment to protect the current classification of such waters will be required. The appropriate Federal authority will be provided with information, from time to time, required to discharge his responsibilities under the Federal Water Pollution Control Act, as amended. (Adopted October 13, 1970.) I. BASIC STANDARDS APPLICABLE TO ALL WATERS OF THE STATE: A. All wastes capable of treatment or control prior to discharge into any waters of the State, shall receive secondary treatment with disinfection or its industrial waste equivalent, as deter- mined by the State Water Pollution Control Commission. Lesser decrees of treatment or control may be permitted only where it can be demonstrated that the standards applicable to the classi- fied use of the water can be attained. Greater degrees of treatment or control will be required where it can be demonstrated that it is necessarv to comply with the standards applicable to the classified use of the water. B. Free from substances attributable to municipal, domestic, or industrial wastes, or other controllable sources that will either settle to form unsightly, putrescent, or odorous bottom deposits, or will interfere with the classified use of the water. C. Free from unsightly floating debris, oil, grease, scum, and other floating material attributable to municipal, domestic, or industrial wastes, or other controllable sources. D. Free fron materials attributable to municipal, domestic or industrial wastes, or other controllable sources that will produce objectionable odor, color, taste, or turbidity in the water, or objectionable aquatic life which may result in eutrophication or other conditions that interfere with the classified use of the water. E. Free from high temperatures, biocides, toxic, or other deleterious substances attributable to municioal, domestic, or industrial wastes, or other controllable sources in levels, concentrations, or combinations sufficient to be harmful to human or animal life. A-l ------- F. Radioactive materials attributable to municipal, industrial or other controllable sources will be minimum concentrations that are physically and economically feasible to achieve. In no case shall such materials in the stream exceed the limits estab- lished in the current edition of the U. S. Public Health Service Drinking Water Standards or the limits approved by the Federal Radiation Council, or, in the absence of any limits specified by the U. S. Public Health Service or the Federal Radiation Council, 1/30 of the 168-hour-week values for other radioactive substances specified in the National Bureau of Standards Handbook 69. II. SPECIFIC STANDARDS ESTABLISHED BY THE STATE OF COLORADO; CLASS B-2 - The following standards shall apply to waters classified for fish and wildlife (Warm Water Fishery): a. Bacteria: Wastes or substances from controllable sources shall not be discharged into these waters in amounts which will cause the number of organisms of the fecal coliform group, as determined by either multiple tube fermentation or membrane filter techniques, to exceed a log mean of 1000 per 100 milliliters or exceed 2000 per 100 milliliters in more than 10 percent of the samples collected in any 30-day period. b. Dissolved Oxygen; In warm water fisheries, dissolved oxygen content shall in mo case go below 5 milligrams per liter. c. pH; pH shall be maintained between 6.5 and 8.5. No control- lable pH change will be permitted which will interfere with fish and aquatic life. d. Turbidity; No turbidity shall exist in concentrations that will impair natural and developed fisheries. e. Temperature; In warm water fisheries the temperatures shall not exceed 90°F. No controllable temperature change will be permitted which will interfere with spawning and other aspects of fish life. Limits on temperature change have not been established due to lack of historical temperature data and lack of conclusive temperature change criteria for the aquatic biota of waters of the state. An abrupt change in temperature must be avoided and the normal pattern of diurnal and seasonal changes must be preserved. The maximum allowable temperature increase due to waste dis- charges in streams will be 5°F. A-2 ------- f. Toxic Material; Free from biocides, toxic, or other dele- terious substances attributable to municipal, domestic, or industrial wastes, or other controllable sources in levels, concentrations, or combinations sufficient to be harmful to aquatic life. g. Other Material; Free from materials attributable to munici- pal, domestic, or industrial wastes, or other controllable sources that will produce off-flavor in the flesh of fish. CLASS C - The following standards shall apply to waters classified for industrial uses: a. Dissolved Oxygen; Dissolved oxygen content shall not go below 3 milligrams per liter. b. pH: pH shall be maintained between 5.0 and 9.0. c. Turbidity; No turbidity shall exist in concentrations that will interfere with established levels of treatment. d. Temperature; The temperature shall not exceed 90°F. CLASS D-l - The following standards shall apply to waters classified for irrigation: a. Total Dissolved S_olids_(^S^t)__Con_c_e_ntr_at_ion; A time-weighted monthly mean at a monitoring station which exceeds the time-weighted monthly mean for a base period established by the Commission by more than two standard deviations shall be subject to review by the Commission. b. Sodium Adsorption Ratio; A time-weighted monthly mean at a monitoring station which exceeds the time-weighted monthly mean for a base period established by the Commission by more than two standard deviations shall be subject to review by the Commission. c. Toxic Material; Free from biocides, toxic, or other dele- terious substances attributable to municipal, domestic, industrial wastes, or other controllable sources in concen- trations or combinations which are harmful to crop life. A-3 ------- APPENDIX B NEBRASKA WATER QUALITY STANDARDS FOR PROTECTION OF CLASS "C" WATERS ------- NEBRASKA WATER QUALITY STANDARDS FOR PROTECTION OF CLASS "C" WATERS. Temperature - Trout Waters - Allowable change 5°F (maximum limit 65°F). Warm Waters - Allowable change 5°F, May-October; 10°F, November- April; maximum limit 90°F; maximum rate of change limited to 2° per hour. PH - The hydrogen ion concentration expressed as pH shall be maintained between 6.5 and 9.0, with a maximum total change of 1.0 pH unit from the value in the receiving stream. Dissolved Oxygen - Shall not be lower than 5 mg/1 in warm waters and 6 mg/1 in trout waters. Bacteria - Colifonn group and fecal coliform organisms shall not exceed a geometric mean of 10,000 total coliform organisms or 2,000 fecal coliform organisms per 100 ml. No more than 20 percent of the samples shall exceed 20,000 total or 4,000 fecal coliform bacteria. B-l ------- APPENDIX C WATER QUALITY OBJECTIVES RECOMMENDED TO THE CONFERENCE AS A RESULT OF STUDIES CONDUCTED BY THE SOUTH PLATTE RIVER BASIN PROJECT ------- WATER QUALITY OBJECTIVES RECOMMENDED TO THE CONFERENCE AS A RESULT OF STUDIES CONDUCTED BY THE SOUTH PLATTE RIVER BASIN PROJECT. 1. In the main stem of the South Platte River from -just below the discharge from the Great Western Sugar Company mill in the City of Brighton to the Colorado-Nebraska State Line: a. Dissolved Oxyeen (DO) content be maintained at not less than 4 mg/1. b. The 5-day 20°C BOD level not be allowed to exceed 15 mg/1. c. The total and fecal coliform levels not be allowed to exceed 5,000 and 1,000 bacteria per 100 ml, respectively. 2. The Sugar Beet Industry provide treatment of wastes so that the total 5-day BOD load discharged any given day in the total effluents entering basin streams or waterways shall not exceed the given value. Residual wastes could be discharged over an extended period of the year if necessary. The limit set for the Ovid plant was 2,300 pounds of BOD per day. 3. There be no settleable solids contained in the total effluents and that suspended solids loads in these effluents not exceed the numerical level prescribed above for the 5-day BOD. A. Disinfection be provided for each waste discharge so that the receiving stream or waterway directly below each mill shall not show an increase of more than 5,000 total coliform bacteria per 100 ml and 1,000 fecal coliform bacteria per 11° ml over the corresponding densities upstream of the mill discharge. 5. Dissolved oxypen in the treated waste effluent shall not be less than 2 mg/1 at any time to insure minimum dissolved oxveen concentrations of 4 mg/1 in the receiving streams or waterways. 6. There be absence of grease, oil, floating solids, slime or sludee banks in the receiving streams or waterways as the result of waste discharges from the sugar beet mill. 7. There be no disagreeable odors or other nuisances in the areas outside of and immediately adjacent to the plant sites. 8. The waste abatement measures given above for the sugar beet industry in the South Platte River Basin shall be completed by September 30, 1968, to provide full capacity for total plant wastes in the 1968-69 campaign and all subsequent campaigns. C-l ------- |