xvEPA United States Industrial Environmental Research EPA-600/7-79-118 Environmental Protection Laboratory May 1979 Agency Research Triangle Park NC 27711 In-stack Plume Opacity from Electrostatic Precipitator/Scrubber System at Harrington Unit 1 Interagency Energy/Environment R&D Program Report ------- RESEARCH REPORTING SERIES Research reports of the Office of Research and Development, U.S. Environmental Protection Agency, have been grouped into nine series. These nine broad cate- gories were established to facilitate further development and application of en- vironmental technology. Elimination of traditional grouping was consciously planned to foster technology transfer and a maximum interface in related fields. The nine series are: 1. Environmental Health Effects Research 2. Environmental Protection Technology 3. Ecological Research 4. Environmental Monitoring 5. Socioeconomic Environmental Studies 6. Scientific and Technical Assessment Reports (STAR) 7. Interagency Energy-Environment Research and Development 8. "Special" Reports 9. Miscellaneous Reports This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT RESEARCH AND DEVELOPMENT series. Reports in this series result from the effort funded under the 17-agency Federal Energy/Environment Research and Development Program. These studies relate to EPA's mission to protect the public health and welfare from adverse effects of pollutants associated with energy sys- tems. The goal of the Program is to assure the rapid development of domestic energy supplies in an environmentally-compatible manner by providing the nec- essary environmental data and control technology. Investigations include analy- ses of the transport of energy-related pollutants and their health and ecological effects; assessments of, and development of, control technologies for energy systems; and integrated assessments of a wide-range of energy-related environ- mental issues. EPA REVIEW NOTICE This report has been reviewed by the participating Federal Agencies, and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Government, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. This document is available to the public through the National Technical Informa- tion Service, Springfield, Virginia 22161. ------- EPA-600/7-79-118 May 1979 In-stack Plume Opacity from Electrostatic Precipitator/Scrubber System at Harrington Unit 1 by Leslie E. Sparks U. S. Environmental Protection Agency Industrial Environmental Research Laboratory Paniculate Technology Branch Research Triangle Park, N. C. 27711 Program Element No. EHE624A Prepared for U.S. ENVIRONMENTAL PROTECTION AGENCY Office of Research and Development Washington, DC 20460 ------- ABSTRACT Results of theoretical modeling of particulate emission and in-stack plume opacity for the electrostatic precipitator (ESP)/scrubber system at Southwestern Public Service Company's Harrington Unit 1 are presented. The theoretical results of an emission rate of 17.8 ng/J and opacity of 35% are in good agreement with data from compliance testing of the unit. The calculations indicate that 20% opacity can be achieved (1) by increasing specific collector area (SCA) of the ESP by 25% and leaving the scrubber pressure drop alone, (2) by increasing scrubber pressure drop by a factor of 4 and leaving the ESP alone, (3) by replacing the existing marble bed scrubber with a venturi scrubber, increasing the pressure drop by 20%, and leaving the ESP alone, or (4) by doubling the SCA of the ESP and removing the scrubber. Calculations showing the impact of high in-stack opacity on the downwind appearance of plume are also included. n ------- TABLE OF CONTENTS Page Abstract ii List of Figures iv List of Tables iv Nomenclature v Acknowledgements vi Conclusions 1 Recommendations 1 Introduction 2 Possible Reasons for Excessive Opacity 3 Description of the System 4 Particle Si2e Data 4 Models 4 ESP Model 4 Scrubber Model 11 Opacity Model 11 Modeling Technique 12 Steps Necessary to Achieve 20% Opacity 14 Opacity if a Venturi Scrubber Were Used 14 Accuracy of the Calculations 18 Possible Environmental Impact of Failure to Meet the Opacity Standard 19 References 21 iii ------- FIGURES Number Page 1 Comparison of measured and predicted ESP performance 10 2 Predicted plume opacity versus scrubber pressure drop for Harrington #1 16 3 Comparison of graded penetration curve predicted by venturi model program with field data for a variable throat venturi scrubber operating at a venturi pressure drop of 48 cm w.c. collecting fly ash 17 4 Predicted downwind opacity for 300 MW plant with indicated emission rates and in-stack opacities 22 TABLES Number Page 1 Analysis of Coal Burned at Harrington #1 5 2 Design Specifications for Particulate Control System at Harrington #1 6 3 Performance of Particulate Control System at Harrington #1 7 4 Particle Size Data for Harrington #1 8 5 Input Data for ESP Modeling of Harrington #1 9 6 Comparison of Predicted and Measured Emissions and Opacity for Harrington #1 13 7 Calculated Emissions and Opacity at Various Scrubber Pressure Drops 15 8 Calculated Emissions and Opacity for ESP with Venturi Scrubber 15 9 Estimated Range of Opacities for Existing ESP and Various Scrubber Pressure Drops 20 ------- NOMENCLATURE d - Geometric mass mean particle diameter, ym f - Empirical factor in scrubber model H - Effective height of emission, m I - Intensity of light transmitted through aerosol I - Intensity of light source 3-3-1 K - Light scattering parameter, cm m m L - Optical path length, m m - Particle refractive index OQ - Downwind.plume opacity 0_ - In-stack plume opacity 3 Q - Gas flow rate, m /s u - Wind speed, m/s 3 W - Mass concentration of particulate, g/m 5 - Plume transmittance dispersion parameter, m" y 3 p - Particle density, g/cm a - Geometric standard deviation o - Verticle plume dispersion coefficient ------- ACKNOWLEDGEMENTS The assistance of Dr. Phil Lawless with the ESP modeling is gratefully acknowledged. The cooperation of Southwestern Public Service Company and the willingness of SWPS to provide data for this study are greatly appreciated. vi ------- CONCLUSIONS The results reported in this report show that the opacity measured at Southwestern Public Service Company's Harrington Unit 1 is what one should expect from an electrostatic precipitator (ESP)/marble bed scrubber system. The results are consistent with the calculations of Sparks et al. who showed that the particle size distribution created by ESP/ venturi scrubber systems is likely to be optically active. The steps that can be taken to achieve 20% opacity at Unit 1 are: 1. Increase ESP specific collector area (SCA) by 25% and leave scrubber pressure drop the same. 2. Increase scrubber pressure drop by a factor of 4 and leave the ESP alone. 3. Double the ESP SCA and remove the scrubber. 4. Replace the marble bed scrubber with a venturi scrubber, increase pressure drop by 20%, and leave the ESP alone. None of these steps appear economically attractive. Future installations that use ESP/scrubber systems should select venturi scrubbers to minimize the energy consumption necessary to meet opacity standards. A plant with particulate emissions that meet the mass standard but exceed the opacity standard will emit more fine particulate matter and have a greater impact on visibility downwind from the plant than will a plant with particulate emissions that meet both standards. RECOMMENDATIONS More research on the plume opacity from ESP/scrubber systems is needed. Although the results at Harrington Unit 1 are consistent with model predictions, the possible effects of particle creation or growth due to combined effects of S02» S03, and moisture cannot be ignored. These effects will likely be important and, in fact, may be dominant in situations where high sulfur coal is burned. 1 ------- Research on prediction of plume opacity from particulate control devices should be encouraged. INTRODUCTION Particulate air pollution control regulations generally limit both the mass of particulate that can be emitted and the opacity of the plume. It is generally assumed that the two regulations are compatible; i.e., if a plant meets the mass emission standard it will also meet the plume opacity standard. Recent theoretical results and laboratory scale experiments with a particulate control system which consisted of an electrostatic precipitator (ESP) followed by a scrubber indicate that the mass emissions required to meet a given opacity limit may be very much lower than the mass emission standard. Recent compliance tests of the ESP/scrubber system at Southwestern Public Service Company's (SWPS) Harrington Unit 1 showed a mass emission of about 19.4 ng/J (0.045 lb/10 Btu) and an opacity of over 30%: this is in line with results of Sparks et al. The mass emission is well under the current New Source Performance Standard (NSPS) of 43 ng/J (0.1 lb/10 Btu) but the opacity exceeds the standard of 20%. SWPS has requested an adjustment of the opacity standard as it applied to Unit 1. EPA's Division of Stationary Source Enforcement (DSSE) has requested assistance from the Particulate Technology Branch of EPA's Industrial Environmental Research Laboratory, Research Triangle Park (IERL-RTP) to determine the reasonableness of the SWPS request. This report is the result of that request. A theoretical study of the particulate control system at Harrington Unit 1 was undertaken to: 1. Estimate the opacity of emissions from the existing system. 2. Estimate the scrubber pressure drop required to meet the 20% opacity standard with the existing ESP specific collector area. 2 ------- 3. Estimate the ESP specific collector area required to meet the 20% opacity standard with the existing scrubber pressure drop. 4. Estimate the ESP specific collector area required to meet the 43 ng/J mass standard and 20% opacity standard if the scrubber were eliminated. Additional calculations not specifically related to SWPS were performed to: 1. Estimate the impact on downwind plume opacity if the in-stack opacity standard is not met. 2. Estimate the scrubber pressure drop required to meet the 20% opacity standard if a venturi scrubber were used instead of a marble bed scrubber. Data necessary to carry out the theoretical calculations were provided by Southwestern Public Service Company. POSSIBLE REASONS FOR EXCESSIVE OPACITY Several possible explanations of the high opacity at Harrington 1 have been suggested. The most plausible are: 1. Creation of submicron particles due to inefficient entrainment separation. 2. Creation of submicron particles due to reactions of SO, or SO, with water in the plume. L. *5 3. Creation of submicron particles due to water con- densation. Although the above three factors may influence the opacity at Unit 1, it seemed likely that the opacity/mass concentration relationship at Harrington Unit 1 was similar to that reported by Sparks et al. in their theoretical analysis of particle collection by ESP/scrubber systems. ------- Therefore, extensive modeling of the ESP/scrubber system was undertaken to predict the plume opacity of the current system and to estimate what changes in the system would be necessary to achieve an opacity of less than 20%. DESCRIPTION OF THE SYSTEM The steam generator for Harrington Unit 1 is a Combustion Engineering, Inc. boiler, tangentially fired, capable of producing 1,219,265 kg of steam/hour at 170 atm and 540°C while firing approximately 180,000 kg/hour of pulverized coal. The primary fuel for this unit is a low- sulfur coal transported to Amarillo by rail from Gillette, Wyoming. A proximate/ultimate analysis is given in Table 1. The ESP/scrubber system at Unit 1 consists of a conventional ESP followed by a marble bed scrubber. The design data for the system are shown in Table 2. The full load compliance tests, Table 3, indicate that the system is performing somewhat better than designed. PARTICLE SIZE DATA SWPS provided particle size distribution data for the ESP inlet and ESP outlet, shown in Table 4. These data were used to estimate the empirical factors in the ESP and scrubber models. MODELS ESP MODEL 2 The ESP computer model described by McDonald was used to model the ESP. Input data for the model were provided by SWPS and are shown in Table 5. The performance data provided by SWPS were used to estimate sneakage, nonrapping reentrainment, and gas flow distribution factors in the model. The agreement between the model predictions and the data is good as shown in Figure 1. The empirical factors used in further modeling ------- Table 1. ANALYSIS OF COAL BURNED AT HARRINGTON fT Proximate Analysis - As Received Moisture Ash Volatile Fixed Carbon Cal/g Sulfur, % S02, ng/J Ultimate Analysis - As Received Moisture Carbon Hydrogen Nitrogen Chlorine Sulfur Ash Oxygen Equilibrium Moisture Cal/g at Equilibrium Moisture Hardgrove Grindability Index Typical ,2 28.26 4.74 32.00 35.00 100.00 4680 0.33 332 Typical t% 28.39 50.03 3.54 0.69 0.01 0.33 4.73 12.28 100.00 24.76 4910 53.27 Range, % 22.59 - 34.52 3.69 - 8.79 27.39 - 38.04 30.96 - 40.02 4314 - 5113 0.09 - 0.59 86 - 590 Range, % 23.40 - 34.52 45.26 - 53.70 2.84 - 4.13 0.41 - 1.02 0.00 - 0.16 0.09 - 0.59 3.69 - 6.64 10.25 - 15.00 19.23 - 27.33 4765 - 5427 37.00 - 67.80 *Data provided by Southwestern Public Service Company. ------- Table 2. DESIGN SPECIFICATIONS FOR PARTICULATE CONTROL AT HARRINGTON #1 Gas Flow Rate 2.571 x 106 Am3/h @/56°C 4 2 Electrostatic Precipitator Collector Area 4.067 x 10 m Electrostatic Precipitator Design Efficiency 95% Marble Bed Scrubber Pressure Drop (scrubber only) 17.8 cm H20 Marble Bed Scrubber Design Efficiency 50% Total System Design Efficiency 97.5% Liquid-to-Gas Flow Rate Ratio 4 x 10"3 m3/m3 Gas Velocity Through Marble Bed 1.98 m/s Reheat Entrance Temperature 52°C Reheat Exit Temperature 72°C Stack Diameter 8.23 m ------- Table 3. PERFORMANCE OF PARTICULATE CONTROL SYSTEM AT HARRINGTON #1 Flyash Concentration, ESP Inlet Flyash Concentration, ESP Outlet ESP Efficiency Flyash Concentration, Scrubber Inlet Flyash Concentration, Scrubber Outlet Scrubber Efficiency System Efficiency Particulate Emission Rate 4.03 g/dNnT3 0.18 g/dNm3 95.5% 0.18 g/dNm3 0.069 g/dNm' 62.5% 98.3% 19.4 ng/J dNm means dry normal cubic meter ------- Table 4. PARTICLE SIZE DATA FOR HARRINGTON #1 Load 350 MWb ESP Inlet Run #1 ESP Outlet0 Cumulative fraction Stage 1 2 3 4 5 6 7 1 2 3 4 5 6 7 dcn , ym — -ou — — — 27.5 12 5.25 2.1 1.25 0.59 0.31 ESP Inlet 19 8.5 3.9 1.6 0.85 0.45 0.22 less than 0.796 0.388 0.215 0.109 0.0709 0.0651 0.0616 Run #2 0.453 0.334 0.223 0.105 0.0481 0.0275 0.0206 Stage dco,wn ou 1 24 2 9.5 3 4.5 4 1.8 5 0.97 6 0.48 7 0.25 Cumulative fraction less than 0.777 0.744 0.576 0.296 0.0916 0.0191 0.00880 All data furnished by Southwestern Public Service Company bAll data for 350 MW C0nly one run at ESP outlet ------- Table 5. INPUT DATA FOR ESP MODELING OF HARRINGTON #1 Inlet Particle Size Distribution—as given in Table 3 Number of Electrical Sections—4 Plate Collector Area Per Section--!.018 x 104 m 4 2 Applied Voltage--2.345 x 10 volts; average current density—13.3 na/cm 4 2 Applied Voltage—2.446 x 10 volts; average current density--13.8 na/cm 4 2 Applied Voltage—3.080 x 10 volts; average current density--13.3 na/cm Section .1: Applied Section 2: Applied Section 3: Applied Section 4: 4 2 Applied Voltage--2.814 x 10 volts; average current density—13.2 na/cm Ion Mobility—2.826 x 10'V/V-s Wire Radius—1.284 x 10~3m Wire-to-Wire Spacing—0.228 m Plate-to-Plate Spacing—0.228 m Sneakage and Nonrapping Reentrainment Factor—0.1 Standard Deviation of Gas Velocity—0.50 ------- 0.01 0.05 0.1 0.2 0.5 1 2 30 40 50 60 70 I I I I I I I I LULU I 10 9 8 7 6 5 4 3 2 1 0.9 .0.7 0.6 0.5 0.4 PARTICLE DIAMETER, urn Figure 1. Comparision of measured and predicted ESP performance 0.3 10 ------- are also given in Table 5. SCRUBBER MODEL Scrubber performance was modeled by modifying a venturi scrubber model3'4 so that it fit the full load penetration data provided by SWP! A value of 0.2 for the empirical factor f gave the required agreement. The particle size distribution predicted by the scrubber model was compared with data supplied by SWPS for 300 MW operation. A log-normal fit was calculated for both the measured and predicted size distributions, The results were: d measured = 0.796 ym d predicted = 0.906 ym y y a measured =4.5 a_ predicted = 3.05 y y With all the uncertainties in both the data and the calculations, the agreement between the measured and predicted size distribution is good. The predicted values of d and q fall within the 90% confidence interval for the log-normal fit for the measured data. All scrubber calculations were performed using a Texas Instruments TI-59 calculator. OPACITY MODEL The opacity of the plume was estimated using a technique developed by Ensor. Ensor has shown that where I/I = transmittance through the plume (1 - opacity) 3 W = mass concentration of particles, g/m L = optical path length, m 3 p = particle density, g/cm ------- K = parameter describing effects of particle size distribution, wavelength of light, and refractive index of particles, cm mm The parameter K was calculated on a TI-59 using estimation procedures reported by Deirmendjian. K calculated by this technique is in good agreement with the results calculated by Ensor using complete solutions. MODELING TECHNIQUE The particle size distribution exiting the ESP was used as the input particle size distribution for the scrubber model. The predicted scrubber outlet size distribution was used to calculate parameter K which was then used to calculate the plume opacity from Equation 1. The refractive index and density of the particles were adjusted until agreement between model and measured data was obtained. o The density selected was 2.4 g/cm (which is in good agreement with fly- ash densities reported by others). The refractive index, m, selected was 1.38 - 0.02i. Changes in refractive index did not greatly change the calculated results. The model predictions for the existing system are shown in Table 6. As can be seen from Table 6, the plume opacity at Unit 1 is very close to the measured value. Thus, it is fair to say, that the plume opacity at Unit 1 is the opacity that would be expected from the particulate control system. The reason for the opacity at Harrington Unit 1 is the same as that discussed by Sparks et al. Namely, the particle size distribution created by an ESP scrubber system designed to give a given mass emission is much more optically active than the particle size distribution from an ESP alone. 12 ------- Table 6. COMPARISON OF PREDICTED AND MEASURED EMISSIONS AND OPACITY FOR HARRINGTON #1 Measured Predicted3 Emission 19.4 ng/J 17.8 ng/0 Opacity 37% 35% Scrubber Pressure Drop 18 cm hLO 18 cm H20 Scrubber Efficiency 0.62 0.65 M Predictions based on f = 0.2, p = 2.4 g/cm , and m = 1.38 - 0.02i 13 ------- STEPS NECESSARY TO ACHIEVE 20% OPACITY The situation at Unit 1 was examined to determine what steps could be taken to comply with the 20% opacity limit. Three cases were examined. 1. Leaving the scrubber alone and modifying the ESP. 2. Removing the scrubber and modifying the ESP. 3. Leaving the ESP alone and increasing the pressure drop across the scrubber. The results of the calculations are: Case 1 - The model predictions indicate that a 25% increase in specific collector area would be required to meet the 20% opacity limit. Case 2 - The ESP model predicts that the SCA of the existing ESP would have to be doubled to comply with 40 ng/J and 20% opacity. Case 3 - The results of Case 3 studies are shown in Table 7 and Figure 2. Note that the pressure drop across the scrubber would have to be increased by more than a factor of 4 to meet 20% opacity. OPACITY IF A VENTURI SCRUBBER WERE USED Harmon and Sparks have reported that venturi scrubbers are the most energy efficient unaugmented type of scrubber. Thus it is of interest, at least for new installations, to determine the pressure drop necessary to give 20% opacity with a venturi scrubber instead of a marble bed scrubber. The venturi scrubber model with f = 0.5 accurately predicts the performance of venturi scrubbers as is shown in Figure 3 taken from Reference 7. The predicted particulate emissions rates and plume opacities for a system identical to that at Harrington #1 (except that the marble bed scrubber is replaced by a venturi scrubber) are shown in Table 8. T4 ------- Table 7. CALCULATED EMISSIONS AND OPACITY AT VARIOUS SCRUBBER PRESSURE DROPS FOR EXISTING MARBLE BED SCRUBBER9 Scrubber Pressure Drop, cm H^O 19 32 48 64 167 Penetration 0.350 0.278 0.226 0.192 0.101 Efficiency 0.650 0.722 0.774 0.808 0.899 Emission ng/J 17.8 14.2 11.5 9.8 5.1 Opacity % 35 30 25 20 12 aAll calculations based on f = 0.2, Pn = 2.4 g/cm3, and m = 1.38 - 0.02i Table 8. CALCULATED EMISSIONS AND OPACITY FOR ESP WITH VENTURI SCRUBBER3 Pressure Drop cm H20 19 36 Scrubber Penetration 0.0734 0.0355 Scrubber Efficiency 0.927 0.965 Emission ng/J 3.7 1.8 Opacity % 13 7 aAll calculations based on f = 0.5, P = 2.4 g/cm3, and m = 1.38 - 0.02i 15 ------- 0.50 a.48 5 < LKL30 0.18 i i i r PRESENT OPERATING POINT I I I I I 10 20 30 40 50 PRESSURE DROP, cm H20 60 70 Figure 2. Predicted plume opacity versus marble bed scrubber pressure drop for Harrington number 1. ------- 0.1 o (0 0.01 ai Z UJ Q. 0.001 0.0001 IN Nil I I I I Mill I I I I Mil SR-52 MODEL FULL SCALEVENTURI Q I III UNI i ill inn1 I I I Mill 0.1 1.0 10 AERODYNAMIC DIAMETER, 100 Figure 3.. Comparison of araded penetration curve predicted by venturi model program with field 4ata for a variable throat venturi scrubber operating at a venturi pressure drop of 48 cm w.c. collecting fly ash. 17 ------- These calculations indicate that, even if opacity standards must be met, an ESP/venturi scrubber system should be considered. ACCURACY OF THE CALCULATIONS The accuracy of the predicted plume opacity depends on two factors— the accuracy of the mathematical models and the accuracy of the data used in the models. These are two separate problems. Each is discussed below. The data used both to "calibrate" the models and as input to the models were provided by SUPS. There is no absolute way to assess the accuracy of these data. The data do seem reasonable. The inlet particle size distribution is within the range one would expect for coal fired boilers. The ESP outlet particle size distribution (the scrubber inlet particle size distribution) is also reasonable. The scrubber model used in the calculations may be a source of error. Calvert's venturi scrubber model with a value of f = 0.2 was used. Although the venturi scrubber model with f = 0.2 predicted the overall penetration for full load of the existing system operated at a pressure drop of 18 cm HpO, there are no data to show that the venturi model with f = 0.2 would predict the performance of the marble bed scrubber at higher pressure drops. However, it is unlikely that the marble bed scrubber would be more efficient at higher pressure drops than predicted by the model. Probably the major source of uncertainty in the calculated results lies in the opacity predictions. The opacity predictions are based on a log-normal fit to the outlet particle size distributions. Unfortunately, the outlet particle size distributions were never log-normal. A rough estimate of the.uncertainty in the opacity predictions caused by the assumption of log-normal size distribution can be obtained by calculating opacity for log-normal size distributions with d and o values at the y y 90% confidence level of the fitted log-normal size distribution. 18 ------- The range of estimated opacity shown in Table 9 is not a true statistical 90% confidence limit for the predicted opacity. Rather it is an indication of the overall uncertainty in the predicted opacity. Methods of predicting opacity are under development which do not require the log-normal assumption. POSSIBLE ENVIRONMENTAL IMPACT OF FAILURE TO MEET THE OPACITY STANDARD For a given mass emission, stack diameter, and particle refractive index, the plume opacity from a source is a function of the particle size distribution: the higher the opacity, the finer the particle size distribution. Thus, a plant meeting the New Source Performance Standard for mass but exceeding the NSPS for opacity will emit more fine particulate matter than will a plant meeting both standards. The opacity of the plume at the stack also affects the downwind appearance of the plume (in the absence of secondary particulate formation) Ens by Q Ensor et al. have shown that the downwind opacity of a plume is given v 0D - 1 - exp [.=__* _ ] (2) ° PpKu where OD is downwind opacity as observed by an observer looking across the plume Q is the gas flow rate, m /s £ is a parameter based on plume dispersion, m" [ 1 + exp (- 2 H2/a2)] u is the wind speed, m/s 3 W is the mass concentration of parti cul ate, g/m 3 -3 -1 K is the light scattering parameter, cm m m H is the height of the emission, m a is the vertical plume dispersion coefficient 19 ------- Table 9. ESTIMATED RANGE OF OPACITIES FOR EXISTING ESP AND VARIOUS MARBLE BED SCRUBBER PRESSURE DROPS Scrubber Predicted Range of Opacity for 9Q% Confidence AP, on H20 Opacity, % Limits on Log-Normal Parameters, % 19 35 30-43 32 30 26 - 43 64 21 18-26 20 ------- Equation (1), which relates K to in-stack opacity, 0 , can be substituted into equation (2) to give 0D - 1 - exp [ gy Q In Q-QS) ] uL Calculations, using equation (3) for a 300 MW power plant with a particulate emission rate of 17 ng/J and an in-stack opacity of 40% and emissions of 34 ng/J and an in-stack opacity of 20%, are shown in Figure 4. The plume for the Case 0 = 0.2 will probably not be visible when the downwind distance exceeds say 0.5 km. However, the plume for the Case Og = 0.4 w exceeds 2-3 km. REFERENCES Case Og = 0.4 will probably be visible until the downwind distance 1. Sparks, L. E., Ramsey, 6. H., and Daniel, B. E., "Particle Collection by a Venturi Scrubber Downstream from an Electrostatic Precipitator," EPA- 600/7- 78- 193 (NTIS PB 288203), October 1978. 2. McDonald, J. R., "A Mathematical Model of Electrostatic Precipitation (Revision 1): Volume I. Modeling and Programming," EPA-600/7- 78-11 la (NTIS PB 284614), June 1978. 3. Calvert, S, Goldshmid, J., Leith, D., and Meta, D., "Scrubber Handbook— Volume I of Wet Scrubber System Study," EPA-R2-72-118a (NTIS PB 213016), August 1972. 4. Sparks, L. E., "SR-52 Programmable Calculator Programs for Venturi Scrubbers and Electrostatic Precipitators," EPA-600/7- 78-026 (NTIS PB 277672), March 1978. 5. Ensor, D. S., "Smoke Plume Opacity Related to the Properties of Air Pollutant Aerosols," Ph.D. Dissertation, University of Washington, 1972. 6. Deirmendjian, D., Electromagnetic Scattering on Spherical Polydispersions. American Elsevier Publication, New York, N. Y. 1969. 21 ------- i mm I i MUM i i 11 \m METEOROLOGICAL CONDITIONS: STABLE— WIND SPEED: 5mr1 — EMISSION HEIGHT: 500m — 0.4 EMISSION RATE = 17 ng/J 0$ = 0.2 EMISSION RATE = 34 ng/J I i ! HUH i I I 1 1111 I i Mill OJW1 0.2 0.4 0.6 0.8I1J) 2 4 6 8 10 DOWNWIND DISTANCE, km 20 40 60 80 100 Figure 4. Predicted downwind opacity for 300 MW plant with indicated emission rates and in-stack opacities. 22 ------- 7. Harmon, D. L. and Sparks, L. E., "Conclusions from EPA Scrubber R&D," in Symposium on the Transfer and Utilization of Particulate Control Technology: Volume 3.» pp 193-218, EPA-600/7-79-044b, February 1979. 8. Ensor, D. S., Sparks, L. E., and Pilat, M. J., "Light Trans- mittance Across Smoke Plumes Downwind from Point Sources of Aerosol Emissions," Atmos. Envir. 7, 1267, 1973. 23 ------- TECHNICAL REPORT DATA (Please read InOructiom on the reverse before computing) 1. REPORT NO. EPA-600/7-79-U8 2. 3. RECIPIENT'S ACCESSION NO. 4. TITLE AND SUBTITLE En-stack Plume Opacity from Electrostatic Precipitator/Scrubber System at Harrington Unit 1 5. REPORT DATE May 1979 5. PERFORMING ORGANIZATION CODE 7. AUTHORIS) Leslie E. Sparks 8. PERFORMING ORGANIZATION REPORT NO. >. PERFORMING ORGANIZATION NAME AND ADDRESS See block 12, below. 1O. PROGRAM ELEMENT NO. EHE624A 11. CONTRACT/GRANT NO. N.A. 12. SPONSORING AGENCY NAME AND ADDRESS EPA, Office of Research and Development Industrial Environmental Research Laboratory Research Triangle Park, NC 27711 13. TYPE OF REPORT AND PERIOD COVERED Inhouse; 8-9/78 14. SPONSORING AGENCY CODE EPA/600/13 is. SUPPLEMENTARY NOTES Author Sparks' phone is 919/541-2925. . ABSTRACT Tne report g&QB results of theoretical modeling of particulate emission and in-stack plume opacity for the electrostatic precipitator (ESP)/scrubber system at Southwestern Public Service Company's Harrington Unit 1. The theoretical results of an emission rate of 17.8 ng/J and opacity of 35% are in good agreement with data from compliance testing of the unit. The calculations indicate that 20% opacity can be achieved (1) by increasing specific collector area (SCA) of the ESP by 25% and leaving the scrubber pressure drop alone, (2) by increasing scrubber pressure drop by a factor of 4 and leaving the ESP alone, (3) by replacing the existing marble bed scrub- ber with a venturi scrubber, increasing the pressure drop by 20%, and leaving the SP alone, or (4) by doubling the SCA of the ESP and removing the scrubber. Cal- culations showing the impact of high in-stack opacity on the downwind appearance of the plume are also included. 17. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS b.tDENTIFIERS/OPEN ENDED TERMS COSATI Field/Group Pollution Gas Scrubbing Flue Gases Dust Opacity Mathematical Plumes Modeling Electrostatic Precipitators Scrubbers Pollution Control Stationary Sources Particulate 13B 21B 14B 131 07A 13H 11G 12A 18. DISTRIBUTION STATEMENT Unlimited 19. SECURITY CLASS (Thi* Report) Unclassified 21. NO. Or PAGES 30 20. SECURITY CLASS (This page) Unclassified 22. PRICE EPA Form 2220-1 (>-73) 24 ------- |