oEPA
          United States
          Environmental Protection
          Agency
           Industrial Environmental Research
           Laboratory
           Research Triangle Park NC 27711
MAY 80
          Research and Development
Report
Abstracts
Industrial
Environmental
Research Laboratory
RTP

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        I        UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
        /              INDUSTRIAL ENVIRONMENTAL RESEARCH LABORATORY
                                RESEARCH TRIANGLE PARK
                                 NORTH CAROLINA 27711
                                     May 1980
   The attached abstracts (EPA Forms 2220-1)  represent reports
that have been issued through EPA's Industrial Environmental
Research Laboratory during the past month.   They are sent to you
because of the indication that you are interested in our multimedia
activities relating to the control of environmental pollution.

   If any of these abstracts  interest you (and you desire the full
reports). they should be available prepaid in about 6 weeks from
the National Technical Information Service, 5285 Port Royal Road,
Springfield, VA 22151 (phone 703/321-8543).

   If you desire either to discontinue receiving these monthly
abstracts, or to nominate additional recipients, please fill in the
required information below, as well as the return address block
on the reverse hereof,  and  return the  sheet to us.
                                  Sincerely yours,
                                    mnAC. Bur chard
                                  Director
Encl:  (16)

{  )  Please discontinue sending these abstracts to me.

(  )  Please start sending your monthly abstracts to the addressees
     indicated below (complete addresses, please):
                               -1-

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(Please include ZIP code)
                                                                        PLACE
                                                                        STAMP
                                                                        HERE
                      To:  U.S. Environmental Protection Agency
                           Office of Research and Development
                           Industrial Environmental Research Laboratory
                           Research Triangle Park, N.C.  27711

                      Attn: Technical Information Coordinator
                           Mail Drop 64
                   (Fold OB dotted lines and seal before nulling)
                                    -2-

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                                TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-600/2-80-055
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
4. TITLE ANDSUBTITLE
Closed-cycle Textile Dyeing: Full-scale
 Hyperfiltration Demonstration (Design)
             5. REPORT DATE
              March 1980
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

Craig A. Brandon (Carre, Inc.)
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
LaFrance Industries
LaFrance,  South Carolina  29656
                                                      10. PROGRAM ELEMENT NO.
             1BB610
             11. CONTRACT/GRANT NO.

             Grant No. S805182
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                                      13. TYPE OF REPORT AND PERIOD COVERED
                                                      Phase: 9/77-4/79
             14. SPONSORING AGENCY CODE
               EPA/600/13
15. SUPPLEMENTARY NOTES J.ERL-RTP project officer is Max Samfield,  Mail Drop 62, 919/
541-2547.  EPA-600/2-76-060 is a related report.
is. ABSTRACT
               report des cribes the first (design) phase of a full-scale demonstration
 of hyperfiltration for closed-cycle operations of a LaFrance Industries dye house.
 (The remaining three phases are installation, operation, and maintenance.) The
 decision to demonstrate the process was based  on earlier projects that showed hyper
 filtration to be potentially economical for recycle /reuse of energy, water,  and chem-
 icals in textile preparation, dyeing, and wet finishing. On-site pilot tests of three
 hyperfiltration modules led to the selection of the Mott-Brandon ZOPA module.
 Representative wash waters from LaFrance dyeing operations were  characterized as
 a basis for demonstration equipment design. The dye range is to be  converted to
 counterflow with a water flow rate of 50 gpm at 82 C , with 96% of the wash water
 recovered as permeate for direct recycle.  Reuse and/or disposal of the concentrate
 and dye pad residuals will require further study. Payback period, without credit for
 chemicals recovery, is estimated to be 5.2 years.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                            COS AT I Field/Group
 Pollution
 Textile Finishing
 Dyeing
 Filtration
 Regeneration
  Pollution Control
  Stationary Sources
  Closed Cycle Systems
  Hyperfiltration
13B
13H

07D
18. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (This Report)
                                          Unclassified
                                                                   21. NO. Of PAGES
                              100
 20. SECURITY CLASS (Thispage)
  Unclassified
                          22. PRICE
EPA Form 2220-1 (9-73)
-3-

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                                TECHNICAL REPORT DATA
                          (Please read Inunctions on the reverse before completing)
 1. REPORT NO.
 EPA-600/7-79-178f
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
 4. TITLE AND SUBTITLE
 Technology Assessment Report for Industrial Boiler
  Applications: NOx Combustion Modification
                                                     5. REPORT DATE
                                                     December 1979
                                                     6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
 /. «w I nwrn^j
 K.J.Lim, R.J.Milligan, H.I.Lips, C.Castaldini,
  R.S. Merrill, and H. B. Mason	
                                                      8. PERFORMING ORGANIZATION REPORT NO.
 9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Acurex Corporation
 485 Clyde Avenue
 Mountain View, California  94042
                                                      10. PROGRAM ELEMENT NO.
                                                      TNE624
                                                      11. CONTRACT/GRANT NO.

                                                      68-02-3101, Task B
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                                      13. TYPE OF REPORT AND PERIOD COVERED
                                                      Task Final: 6/78-6/79
                                                     14. SPONSORING AGENCY CODE
                                                       EPA/600/13
15. SUPPLEMENTARY NOTES
                              project officer is Robert  E. Hall,  Mail Drop 65, 919/
 16. ABSTRACT
                      gjves results of an assessment of current and developing
 combustion modification NOx control technology for coal-, oil-, and natural-gas-
 fired industrial boilers.  Control effectiveness and applicability, reliability and
 availability , process  impacts ,  capital and operating costs , energy  impacts , and
 environmental impacts are evaluated. Currently available techniques are capable of
 moderate (10-25%) NOx reductions for coal- and residual- oil-fired  boilers and major
 (40-70%) reductions for distillate -oil- and gas-fired units with minimal adverse
 operating impacts. Combustion modifications are estimated to increase the cost of
 steam by only 1-2%, but  could increase the initial capital cost of a boiler by 1-20%.
 Analysis of measured or postulated incremental emissions, other than NOx, indi-
 cates that these emissions are generally unaffected when preferred NOx controls are
 implemented, although further testing is warranted.
 7.
                             KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                                                                  c. COS AT I Field/Group
 Air Pollution
 Assessments
 Combustion Control
 Nitrogen Oxides
 Boilers
 Capitalized Costs
                    Operating Costs
                    Fossil Fuels
                    Dust
                    Aerosols
                    Trace Elements
Air Pollution Control
Stationary Sources
Particulate
Combustion Modification
Industrial Boilers
Emission Factors
13B
14B
21B
07B
13A
14A,05A
21D
11G
07D
06A
 B. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (This Report)
                                          Unclassified
                                                                   21. NO. OF PAGES
                                                                      497
                                         20. SECURITY CLASS (Thispage)
                                          Unclassified
                                                                  22. PRICE
EPA Form 2220-1 (9-73)
                                         -4-

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                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
 . REPORT NO.
 EPA-600/7-79-199C
                                                     3. RECIPIENT'S ACCESSION'NO.
«. TITLE AND SUBTITLE Survey of Flue Gas Desulfurization
Systems: Cane Run Station, Louisville Gas and Elec-
tric Co.
                                                     6. REPORT DATE
                                                      August 1979
                                                     S. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Bernard A. Las eke, Jr.
                                                     B. PERFORMING ORGANIZATION REPORT NO.

                                                     PN 3470-1-C
}. PERFORMING ORGANIZATION NAME AND ADDRESS
PEDCo Environmental, Inc.
[1499 Chester Road
 incinnati, Ohio  45246
                                                     10. PROGRAM ELEMENT NO.
                                                     EHE624
                                                     11. CONTRACT/GRANT NO.

                                                     68-02-2603, Task 24
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Industrial Environmental Research Laboratory
Research Triangle Park, NC 27711
                                                     13. TYPE OF REPORT AND PERIOD COVERED
                                                     Final; 7/78 - 12/78   	
                                                     14. SPONSORING AGENCY CODE
                                                       EPA/600/13
15.SUPPLEMENTARY NOTES jjiRL-RTP project officer is Norman Kaplan, Mail Drop 61, 919/
541-2556.
16. ABSTRACT
              report gives results ofa survey of operational Hue gas aesullurization
(FGD) systems on coal-fired utility boilers in the U.S. The FGD systems installed on
Units 4,5, and 6 at the Cane Run Station are  described in terms of design and perfor-
mance.  The Cane Run No. 4 FGD system is a two-module (packed tower) carbide
lime scrubber, retrofitted on a 178 MW (net) coal-fired boiler.  The system, supplied
3y American Air Filter , commenced initial operation in August 1976.  The Cane Run
No. 5 FGD system is a two-module (spray tower) carbide lime scrubber, retrofitted
on a 183 MW  (net)  coal-fired boiler. The system , supplied by Combustion Engineer-
ing, commenced initial operation in December 1977.  The Cane Run Unit 6 FGD system
is a two-module (tray tower) dual alkali (sodium carbonate/lime) scrubber, retrofit-
ted on a 278 MW (net) coal-fired boiler. The system, supplied by A.D.  Little/Com-
bustion Equipment Associates , commenced initial operation in December 1978.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                                                                  c. COSATI Field/Group
Air Pollution
Flue Gases
Desulfurization
Fly Ash
Limestone
Slurries
Ponds
                  Scrubbers
                  Coal
                  Combustion
                  Cost Engineering
                  Sulfur Dioxide
                  Dust Control
Air Pollution Control
Stationary Sources
Wet Limestone
Particulate
13B
21B
07A,07D
                        11G
                        08H
21D

14A
07B
18. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (ThisReport)
                                          Unclassified
                                                                  21. NO. OF PAGES
                                                                        192
                                          20. SECURITY CLASS (This page)
                                          Unclassified
                                                                  22. PRICE
EPA Form 2220-1 (8-73)
                                        -5-

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                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-79-248
                           2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
 Treatairility and Assessment of Coal Conversion
 Wastewaters: Phase I
                                                    5. REPORT DATE
                                                     November 1979
                                                    6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 P.C.Singer, J.C.Lamb m, F.K. Pfaender, and
   R. Goodman
                                                     8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 University of North Carolina—Chapel Hill
 Department of Environmental Sciences and
  Engineering
 Chapel Hill, North Carolina  27514
                                                     10. PROGRAM ELEMENT NO.
                                                     EHE623A
                                                     11. CONTRACT/GRANT NO.

                                                     Grant No. R804917
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                                     13. TYPE OF REPORT AND PE
                                                     Final; 9/78 - 9/79
                                                                     PERIOD COVERED
                                                     14. SPONSORING AGENCY CODE
                                                      EPA/600/13
 15. SUPPLEMENTARY NOTES JERL-RTP project officer is N. Dean Smith, Mail Drop 61,  919/
 541-2708.
16. ABSTRACT
              repOrt gives Phase I results of (1) an assessment of the environmental
 impact of wastewaters originating from the production of synthetic fuels from coal,
 and (2) an evaluation of alternative technologies for treating these wastewaters .
 Work on coagulation, adsorption, and preliminary biological treatment studies is
 continuing.  Future reports, representing successive phases, will update these
 results. The major focus is on aerobic biological treatment which is projected to be
 the principal means of removing organic impurities from these wastewaters and a
 cornerstone of any overall wastewater treatment program. A synthetic wastewater,
 designed to simulate a real conversion process wastewater,  was fed to a series of
 aerobic biological reactors. Design and operation of the reactors is described,
 along with performance data spanning two 6-month operating periods. In addition to
 TOC, BOD, and COD data, the treated wastewaters were analyzed for phenolic con-
 tent and residual organics, using chromatographic techniques.  Aquatic bioassays
 and mammalian cytotoxicity tests were performed on the raw and treated wastewa-
 ters  to evaluate their potential environmental impact.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b.lDENTIFIERS/OPEN ENDED TERMS
                                                                   COSATI Field/Group
 Pollution
 Coal
 Coal Gasification
 Waste Water
 Assessments
 Water Treatment
 Aerobic Processes
                    Organic Compounds
                    Bioassay
                    Toxicity
                    Cytology
Pollution Control
Stationary Sources
Coal Conversion
Synthetic Fuels
13B
08G,21D
131

14B

06C
07C
06A
06T
 3. DISTRIBUTION STATEMENT
 Release to Public
                                         19. SECURITY CLASS (This Report)
                                         Unclassified
                        21. NO. OF PAGES
                            192
                                         20. SECURITY CLASS (Thispage)
                                         Unclassified
                                                                 22. PRICE
EPA Form 2220-1 (9-73)
                                        -6-

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                                TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-80-014
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
 Development Study of a Novel Continuous-flow
 Impactor
             5. REPORT DATE
             January 1980
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                      8. PERFORMING ORGANIZATION REPORT NO.
E.F.Brooks,'N.Gat, M.E.Taylor, T.E. Chamberlain,
 R. J. Golik, and R. Watson	
9. PERFORMING ORGANIZATION NAME AND ADDRESS
TRW Systems and Energy
One Space Park
Redondo Beach, California 90278
              10. PROGRAM ELEMENT NO.
              EHE624
              11. CONTRACT /GRANT NO.

              68-02-2165, Task 12
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
              13. TYPE OF REPORT AND PERIOD COVERED
              Task Final; 7/76 - 11/78
              14. SPONSORING AGENCY CODE
               EPA/600/13
is. SUPPLEMENTARY NOTES T£RL-RTP project officer is D. Bruce Harris, Mail Drop 62,
919/541-2557.
is. ABSTRACT rj-,ne report gives results of a development study involving feasibility veri-
fication of a novel particle impactor in which the impaction surface is the interface
between two opposing jets. Particles (which would impact a solid surface in a stan-
dard impactor) cross the interface betweeii the aerosol-laden gas and a previously
particle-free gas, are entrained in the latter, and are conveyed out for analysis.
Work consisted of an initial literature search and analysis to determine the likeli-
hood of success,  followed by design, fabrication, and testing of a laboratory unit.
A good particle separation capability was demonstrated. Upon completion of the
laboratory tests, a design effort showed the feasibility of a staged in situ particle
monitoring subsystem to give semicontinuous (nominal 1 minute cycle time) output of
particle size distribution, among other applications.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                           b.lDENTIFIERS/OPEN ENDED TERMS
                             COSATI Field/Group
Pollution
Dust
Aerosols
Impactors
Monitors
Particle Size Distribution
  Pollution Control
  Stationary Sources
  Particulate
  Particle Impactors
13B
11G
07D
131
14B
18. DISTRIBUTION STATEMENT

 Release to Public
  19. SECURITY CLASS (ThisReport)
  Unclassified
21. NO. OF PAGES
     123
  2O. SECURITY CLASS (This page)
  Unclassified
                           22. PRICE
EPA Form 2220-1 (S-73)
-7-

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                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing]
1. REPORT NO.
EPA-600/7-80-017b
                           2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE Advanced Combustion Systems for
 Stationary Gas Turbine Engines: Volume 2.  Bench
 Scale Evaluation
             5. REPORT DATE
             January 1980
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
 R.M.Pierce, S.A.Mosier, C.E.Smith, and
 B.S.Hinton	
                                                     8. PERFORMING ORGANIZATION RSPORT NO.
              FR-11405
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 Pratt and Whitney Aircraft Group
 United Technologies Corporation
 P.O. Box 2691
 West Palm Beach, Florida  33402
             10. PROGRAM ELEMENT NO.

              INE829
              11. CONTRACT/GRANT NO.
              68-02-2136
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
              13. TYPE OF REPORT AND PERIOD COVERED
              Final; 9/76 - 1/78	
              14. SPONSORING AGENCY CODE
               EPA/600/13
 is. SUPPLEMENTARY NOTES IERL-RTP project officer is W.S.
 541-2432.
             Lanier, Mail Drop 65, 919/
 16.ABSTRACTThe j-gpoj.^ describe an exploratory development program to identify, eval-
 uate,  and demonstrate dry techniques for significantly reducing NOx emissions from
 stationary gas turbine combustors. (Volume 1 documents the research activities lea-
 ding to selection of 26 combustor design concepts which could potentially meet the
 program goals.) Volume 2 documents the Phase n bench-scale evaluation of those
 concepts to experimentally evaluate their emission reduction potential. Results from
 the testing program identified two design approaches capable of significant emission
 reduction. A staged centertube design, relying on burner operation near the lean
 blowout limit, gave low NOx and CO emissions on clean No. 2 fuel oil, but was inef-
 fective for fuels containing bound nitrogen. A rich-burn/quick-quench (RB/QQ) de-
 sign,  producing a fuel-rich primary zone and quickly quenching the effluent from
 that region to the high overall excess  air conditions required by the gas turbine cy-
 cle, successfully controls NOx from both thermal and fuel-bound sources while main
 taining low CO emissions for high thermal efficiency. The RB/QQ concept was selec-
 ted for scaleup to full size hardware in Phases HI and IV.
 7.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                          c. COSATI Field/Group
 Pollution             Combustion Cham-
 Gas Turbine Engines    bers
 Stationary Engines    Flammability
 Nitrogen Oxides
 Carbon Monoxide
 Hydrocarbons
 Combustion	
Pollution Control
Stationary Sources
Unburned Hydrocarbons
Combustor Design
Staged Combustion
Dry Controls
   >T Nltrntrpn  	
                          13B
                          21E
                          21K
                          07B

                          07C
                          2m
 3. DISTRIBUTION STATEMENT

 Release to Public
  19. SECURITY CLASS (ThisReport)
  Unclassified
                        21. NO. OF PAGES
                           350
  20. SECURITY CLASS (Thispage)
  Unclassified
                          22. PRICE
EPA Form 2220-1 (9-73)
-8-

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                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing/
i. REPORT NO.
EPA-600/7-80-017C
                          2.
                                                     3. RECIPIENT'S ACCESSION NO.
4 T1TLEANDSUBTITLE Advanced Combustion Systems for
Stationary Gas Turbine Engines: Volume 3.
Combustor Verification Testing
             5. REPORT DATE
              January 1980
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

R.M. Pierce, C.E. Smith, andB.S. Hinton
                                                     8. PERFORMING ORGANIZATION REPORT NO.
              FR-11405
3. PERFORMING ORGANIZATION NAME AND ADDRESS
Pratt and Whitney Aircraft Group
United Technologies Corporation
P.O. Box 2691
West Palm Beach, Florida 33402
                                                     10. PROGRAM ELEMENT NO.
              INE829
              11. CONTRACT/GRANT NO.
              68-02-2136
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Industrial Environmental Research Laboratory
Research Triangle Park, NC 27711
              13. TYPE OF REPORT AND PERIOD COVERED
              Final; 1/78 - 4/79	
              14. SPONSORING AGENCY CODE
               EPA/600/13
15. SUPPLEMENTARY NOTES IERL-RTP project officer is W.S.
2432.
            Lanier, Mail Drop 65, 919/541-
16. ABSTRACT
                     describe an exploratory development program to identify, eval-
uate, and demonstrate dry techniques for significantly reducing NOx from stationary
gas turbine engines.  (Volume 1 describes Phase I research activities to compile a
series of combustor design concepts which could potentially meet the program goals,
and Volume 2 describes the Phase n bench-scale evaluation of those techniques: the
rich-burn/quick-quench (RB/QQ) concept was found to be effective in limiting pollu-
tant emissions when burning either clean fuels or fuels containing significant amounts
of chemically bound nitrogen. ) Volume 3 describes the scaleup of the RB/QQ model
to a full-scale (25 MW) gas turbine combustor, and documents test results from the
full-scale evaluations.  Test results were very positive, showing that the RB/QQ
concept can reduce NOx to approximately 45 ppm  (at zero % O2) for clean distillate
oil and to approximately 75 ppm for a distillate oil doped to 0. 5% nitrogen, as pyri-
dine. CO emissions below the 100 ppm program goal were also demonstrated. These
tests also indicate  that the new combustor concept may be capable of low emission
performance on petroleum residual oil and synthetic liquid fuels such as SRC II or
shale oil. Results from testing on those fuels is included in Volume 4, an addendum.
17.
                            KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b.lDENTIFIERS/OPEN ENDED TERMS
                          c. COS AT I Field/Group
Pollution             Atomizing
Gas Turbine Engines  Shale Oil
Stationary Engines
Nitrogen Oxides
Carbon Monoxide
Combustion
Combustion Chambers	
  Pollution Control
  Stationary Sources
  Combustor Design
  Staged Combustion
  Dry Controls
  Fuel Preparation
  Fuel-bound Nitrogen
13B
2 IE
21K
07B

2 IB
13H
21D
13. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (ThisReport)
                                          Unclassified
                          21. NO. OF PAGES
                               152
  20. SECURITY CLASS (This page)
  Unclassified
                          22. PRICE
EPA Form 2220-1 (9-73)
-9-

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                               TECHNICAL REPORT DATA
                         {Please read Inunctions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-80-017d
                          2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE Advanced Combustion Systems for
Stationary Gas Turbine Engines: Volume 4.
Combustor Verification Testing (Addendum)
                               5. REPORT DATE
                                January 1980
                               6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

R.M.  Pierce,  C.E. Smith, andB.S. Hinton
                                                     8. PERFORMING ORGANIZATION REPORT NO.
                                FR-11405
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pratt and Whitney Aircraft Group
United Technologies Corporation
P.O. Box 2691
West Palm Beach, Florida 33402
                                10. PROGRAM ELEMENT NO.
                                INE829
                                11. CONTRACT/GRANT NO.
                                68-02 -2136
 12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                13. TYPE OF REPORT AND. PERIOD COVERED
                                Final: 7/79 - 10/79	
                                14. SPONSORING AGENCY CODE -
                                 EPA/600/13
 15. SUPPLEMENTARY NOTES JERL-RTP project officer is W.S. Lanier, Mail Drop 65, 919/541-
 2432.
 is. ABSTRACTTlie j-gpQj^g describe an exploratory development program to identify, eval-
 uate, and demonstrate dry techniques for significantly reducing NOx from stationary
 gas turbine engines. (Volume 1 describes Phase I research activities to compile a
 series of combustor design concepts which could potentially meet the program's low
 emission goals. Volume 2 covers the Phase n bench-scale testing program which
 experimentally singled out the rich-burn/quick-quench (RB/QQ)  combustor concept
 as being capable of low NOx and CO operation on both clean fuels and fuels containing
 significant amounts of bound nitrogen. Volume 3 covers the Phase in and IV scaleup
 and full-scale testing of the RB/QQ concept, documenting the fact that all emission
 goals could be met with the RB/QQ combustor.) Volume 4 describes an additional
 series of tests to evaluate the performance of the combustor on heavy fuels such as
 petroleum or shale residual oil and solvent refined coal (SRC). Results from the
 tests show that all exhaust emission goals were met while burning three test fuels:
 a middle-cut distillate SRC, a residual shale oil, and an Indonesian/Malaysian
 residual oil. It was also demonstrated that the exhaust emission goals were met
 when operating a RB/QQ combustor at a high turbine inlet temperature (1426 C
 design) firing No. 2 fuel oil.
 7.
                            KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b. IDENTIFIERS/OPEN ENDED TERMS
                                            c. COSATi Field/Group
 Pollution
 Gas Turbine Engines
 Stationary Engines
 Nitrogen Oxides
 Combustion
 Combustion Chambers
Residual Oils
Shale Oil
Coal
Liquefaction
Pollution Control
Stationary Sources
Combustor Design
Staged Combustion
Dry Controls
Fuel-bound Nitrogen
13B
21E
21K
07B
21B
21D
07D
 3. DISTRIBUTION STATEMENT
 Release to Public
                                         19. SECURITY CLASS (ThisReport)
                                          Unclassified
                                            21. NO. OF PAGES
                                                116
                    20. SECURITY CLASS (Thispage)
                    Unclassified
                                            22. PRICE
EPA Form 2220-1 (9-73)
                  -10-

-------
                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-80-02 6
                          2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Assessment of Corrosion Products from Once-through
 Cooling Systems with Mechanical Antifouling Devices
                                 . REPORT DATE
                                 January 1980
                                6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

 Charles M. Spooner
                                                      . PERFORMING ORGANIZATION REPORT NO.
3. PERFORMING ORGANIZATION NAME AND ADDRESS
 GCA/Technology Division
 Burlington Road
 Bedford, Massachusetts  01730
                                                     10. PROGRAM ELEMENT NO.
                                 INE827
                                11. CONTRACT/GRANT NO.

                                68-02-2607, Task 28
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                 13. TYPE OF REPORT AND PERIOD COVERED
                                 Task Final; 1-4/79  	
                                 14. SPONSORING AGENCY CODE
                                  EPA/600/13
is.SUPPLEMENTARY NOTES IERL-RTP project officer is Theodore G. Brna, Mail Drop 61,
 919/541-2683.
16. ABSTRACT The report gives results of an assessment of corrosion products from
 steam-electric power plant once-through cooling systems equipped with mechanical
 antifouling devices.  (About 67% of the currently operating plants in the U.S. use
 once-through cooling systems. Various cleaning mechanisms, used to minimize the
 reduction of the thermal efficiency of heat exchange in the  condenser tubes—caused
 by corrosion and biofouling—include chemical and off- and on-line mechanical
 methods.) On-line mechanical cleaning may lead to increased levels of metals in the
 effluent due  to abrasion of the condenser tubes.  Since some abraded metals at suf-
 ficiently high concentrations  harm aquatic organisms and lead to other environmen-
 tal damage,  metal concentrations in cooling water discharges which stem from on-
 line mechanical condenser tube cleaning systems need to be determined. This report
 addresses the significance of this effect, based  mainly on comments from utilities
 experienced with the Amertap system and from  the manufacturer. The industry
 generally does not keep a close account of the causes and magnitude of condenser
 tube corrosion; however, based on observations offered by the utilities, the Amertap
 and other systems do not appear to contribute to loss of metal through abrasion in
 any measurable way. Further evaluation is recommended.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                                               COS AT I Field/Group
 Pollution
 Steam Electric
  Power Generation
 Cooling Systems
 Corrosion Products
 Biodeterioration
Assessments
Condenser Tubes
Cooling Water
Pollution Control
Stationary Sources
Biofouling
Mechanical Antifouling
 Devices
13B

10A
13A
11M
06A
14B
13. DISTRIBUTION STATEMENT

 Release to Public
                     19. SECURITY CLASS (ThisReport)
                     Unclassified
                                                                  21. NO. OF PAGES
                             48
                     20. SECURITY CLASS (Thispage)
                     Unclassified
                                             22. PRICE
EPA Form 2220-1 (9-73)
                   -11-

-------
                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-80-036
                          2.
                                                    3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Investigation  of NO2/NOx Ratios in Point Source
 Plumes
                                 5. REPORT DATE
                                 February 1980
                                 6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
J.P.Blanks, E.P.Hamilton m,  B.R.Eppright, and
 N.A.Nielsen
                                                    B. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Radian Corporation
P.O. Box 9948
Austin, Texas  78766
                                                     10. PROGRAM ELEMENT NO.
                                 TNE624
                                 11. CONTRACT/GRANT NO.

                                 68-02-2608, Task 63
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                 13. TYPE OF REPORT AND PERIOD COVERED
                                 Task Final; 12/78 - 12/79
                                 14. SPONSORING AGENCY CODE
                                   EPA/600/13
is. SUPPLEMENTARY NOTES IERL-RTP project officer is J. David Mobley, Mail Drop 61,
919/541-2915. EPA-600/7-78-212 is a related report.
 s. ABSTRACT
              repOrt gjves results of a study to relate ground level NO2 concentra-
tions to NOx emissions (NO2/NOx ratio) in plumes from six large power plants in the
Chicago area, using a  photos tationary state reactive Gaussian plume model. The aim
of the study was to assess the level of NOx control required to meet a probable short-
term NO2 national ambient air quality standard (NAAQS).  The major uncertainty of
an earlier study (EPA-600/7-78-212) was its assumption of uniform, fixed NO2/NOx
ratios of 0,5 (summer) and 0.25 (winter). The reactive model used in this study pre-
dicted significantly higher NO2/NOx ratios at the point of  maximum  plume impact
(0. 93 for worst case) with high ambient ozone levels (0.2  ppm).  Average NO2/NOx
ratios for all high ozone cases studied were 0. 76-0. 9. The reactive model predicts
significantly higher ground level NOx impacts from the six plants. These results
indicate that the threshold short-term NO2 NAAQS level requiring NOx flue gas treat-
ment technology could  increase by 40%. The previous study indicated that most of the
six plants could meet a 500 microgram/cu m short-term  NO2 standard using NOx
combustion modification techniques (50% NOx control); this study indicates NOx flue
gas treatment technology (90% control) may be required on these plants to meet a
750 microgram/cu m standard, and most certainly for 500 micrograms/cu m.
17.
                            KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b.lDENTIFIERS/OPEN ENDED TERMS
                                             c.  COSATl Field/Group
Pollution
Combustion
Nitrogen Oxides
Nitrogen Dioxide
Mathematical Modeling
Normal Density Functions
Flue Gases
Electric Power Plants
Ozone
Pollution Control
Stationary Sources
Gaussian Models
13B
21B
07B

12A
10B
18. DISTRIBUTION STATEMENT

 Release to Public
                      19. SECURITY CLASS (ThisReport)
                      Unclassified
                        21. NO. OF PAGES
                            71
                      20. SECURITY CLASS (This page)
                      Unclassified
                                              22. PRICE
EPA Form 2220-1 (9-73)
                    -12-

-------
                                TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before, completing)
1. REPORT NO.
 EPA-600/7-80-037
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Pilot-scale Field Tests of High-gradient Magnetic
 Filtration
                                5. REPORT DATE
                                 March 1980
                                E. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

Charles H. Gooding
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Research Triangle Institute
P.O. Box  12194
Research Triangle Park, North Carolina 27709
                                 10. PROGRAM ELEMENT NO.
                                 EHE624A
                                 11. CONTRACT/GRANT NO.
                                 68-02-2650
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
                                                       13. TYPE OF REPORT AND PEI
                                                       Final; 9/77 - 12/79
                                                                         RIOD COVERED
                                 14. SPONSORING AGENCY CODE
                                  EPA/600/13
15. SUPPLEMENTARY NOTES jjERL-RTP project officer is Dennis C. Drehmel, Mail Drop 61,
919/541-2925.
is. ABSTRACT The report gives results ol using a blUU cu m/hr mobile pilot plant to eval-
uate the effectiveness and economics of applying high-gradient magnetic filtration
(HGMF) to particulate emission control. A 4-1/2 month test program was conducted
at a Pennsylvania sintering plant to characterize the performance of the pilot plant
and to demonstrate its practicality under long-term operation. The pilot plant col-
lected approximately 90% of the iron-bearing particulate under practical operating
conditions but achieved lower overall collection because the windbox gas  contained an
unexpectedly  high concentration of fine alkali-chloride aerosol. To collect the non-
magnetic aerosol, a finer filter had to be used under conditions that were conducive
to plugging. Under the practical conditions, the pilot plant operated over 450 hours
without significant problems.  Analysis of the results indicates that high-efficiency
collection can be achieved economically if HGMF is applied to steel industry dusts
that are more homogeneous and more strongly magnetic than the tested sinter dust.
The report describes laboratory pilot-plant work that demonstrated collection effic-
iencies greater than 99% with basic oxygen furnace and electric arc furnace dusts.
The development of a filter cleaning system and the design and construction of the
pilot plant are discussed. Experimental data are reported.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                 DESCRIPTORS
                                           b.lDENTIFIERS/OPEN ENDED TERMS
                                             c.  COSATI Field/Group
Pollution
Filtration
Magnetic Properties
Magnetic Separators
Testing
Dust
Aerosols
Sintering  Furnaces
Iron and Steel In-
 dustry
Pollution Control
Stationary Sources
High-gradient Magnetic
 Filtration
Particulate
13B
07D
20C
131
14B
11G
13A

11F
18. DISTRIBUTION STATEMENT
 Release to Public
                     19. SECURITY CLASS (ThisReport)
                     Unclassified
                         21. NO. OF PAGES
                             141
                     20. SECURITY CLASS (Thispage)
                     Unclassified
                                             22. PRICE
EPA Form 2220-1 (»-73)
                   -13-

-------
                                TECHNICAL REPORT DATA
                         (Please reed Instructions on tht reverse before completing)
1. REPORT NO.
 EPA-600/7-80-038
                           2.
                                                      3. RECIPIENTS ACCESSION NO.
4. TITLE AND SUBTITLE
 Photochemical Study of NOx Removal from
 Stack Gases
            6. REPORT DATE
             March 1980
            6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

John R. Richards and Donald L. Fox
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 University of North Carolina
 School of Public Health
 Chapel Hill, North Carolina 27514
                                                      10. PROGRAM ELEMENT NO.
            INE623
            11. CONTRACT/GRANT NO.

            Grant No. R804740
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
            13. TYPE OF REPORT AND P
            Final; 1/77 - 3/79
                                                                      PERIOD COVERED
            14. SPONSORING AGENCY CODE
             EPA/600/13
is. SUPPLEMENTARY NOTES JERL-RTP project officer is Joseph A.  McSorley, Mail Drop 63,
 919/541-2745.
is. ABSTRACT
              repOrt gjygg TQS^I^ of an evaluation of the technical feasibility of a
 photochemical pretreatment system for NOx control at coal-fired boilers.  The ap-
 proach utilizes reaction mechanisms similar to those responsible for photochemical
 oxidant incidents. The reactions are initiated under controlled conditions while
 the pollutants are at high concentration and while the reaction products can be remo-
 ved.  Results indicate  that, under time- and light-limited conditions, it is possible to
 quench the photochemical reactions at the NO2 peak and prior to the formation of
 ozone, aerosols, and  other secondary products. Energy and hydrocarbon require-
 ments were estimated in a series of 159 experimental runs . The optimal operating
 conditions were identified as a NOx/C3H6 stoichiometric ratio of 1 and an NO2 photo-
 lysis rate of 1 to 1. 5 reciprocal minutes (equivalent to 3 to 5% station power). These
 conditions allowed for an 83% oxidation of NO with an exit concentration of NO less
 than 100 ppm. Variation of the energy input levels or the propylene  injection  rates
 resulted in NO oxidation efficiencies of 10 to 99%. Photochemical oxidation of NO
 was insensitive to SO2 concentration and CO2 concentration. The photochemical sys-
 tem appears compatible with conditions resulting from combustion modifications
 to suppress NOx generation'
 7.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                        c.  COSATI Field/Group
Pollution            Combustion
Photochemical Reactions
Oxidation            Boilers
Flue Gases          Propylene
Nitrogen Oxides
Coal
Pollution Control
Stationary Sources
13B
07E
07B,07C
21B

21D
                                    ISA
18. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (ThisReport)
                                          Unclassified
                         21. NO. OF PAGES
                            200
20. SECURITY CLASS (Thispage)
Unclassified
                         22. PRICE
EPA Form 2220-1 (9-73)
                                        -14-

-------
                                TECHNICAL REPORT DATA
                         (Please read Inunctions on the reverse before completing)
1. REPORT NO.
 EPA-600/7-80-042
                           2.
                                                      3. RECIPIENT'S ACCESSION NO.
4. TITLE ANDSUBTITLE
Performance of a High-velocity Pulse-jet
Filter, H
               ,. REPORT DATE
               March 1980
              6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
David Leith, M.J.Ellenbecker, M.W.First,
 J.M. Price. Anthony Martin, and D. G. Gibson
                                                      8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Harvard School of Public Health
665 Huntington Avenue
Boston, Massachusetts  02115
              10. PROGRAM ELEMENT NO.
              EHE624
              11. CONTRACT/GRANT NO.

              Grant R804700
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC 27711
              13. TYPE OF REPORT AND PERIOD COVERED
              Final; 9/76-9/79	
              14. SPONSORING AGENCY CODE
                EPA/600/13
is. SUPPLEMENTARY NOTES jjERL-RTP project officer is James H. Turner,  Mail Drop 61,
919/541-2925.  EPA-600/7-78-131 includes related work.
is. ABSTRACT
              repOrt gives results of a study of the performance of a high-velocity
pulse -jet filter. Such filtration has distinct advantages over low- velocity filtration
in that the equipment required to clean a gas stream is reduced in size and initial
cost as velocity increases.  Although high filtration velocity causes a number of pro-
blems , many of them are dealt with in the report.  Location of the gas inlet to the
filter was found to affect penetration and pressure drop; both were higher for inlets
near the bottom of the filter housing. Fabric type was also found to affect perfor-
mance by affecting the amount and characteristics of the dust deposit  accumulated.
Fabric surface properties help explain the nature of this deposit. These ideas and
others were used to develop a mathematical model for pressure  drop  in a pulse-jet
cleaned filter.  The model can be used to predict pressure drop under stable or
variable operating conditions , and to predict operating conditions that cause unstable
filter operation. An understanding of particle/fiber interactions  is essential to
understanding the collection characteristics of a felt fabric. Under certain condi-
tions , particles bounce on impact with fibers. An adhesion probability was deter-
mined and found to depend on incident particle kinetic energy.
17.
                             KEY WORDS AND DOCUMENT ANALYSI.S
                DESCRIPTORS
                                          b.IDENTIFIERS/OPEN ENDED TERMS
                           c. COSATI Field/Group
 Pollution            Felts
 Filtration           Adhesion
 Pulsation
 Jets
 Fabrics
 Mathematical Models
   Pollution Control
   Stationary Sources
   Fabric Filters
   Pulse-jet Filters
13B
07D
14B
20D
HE
12A
13. DISTRIBUTION STATEMENT
 Release to Public
  19. SECURITY CLASS (ThisReport)
   Unclassified
                                                                   21. NO. OF PAGES
                                                                       72
  20. SECURITY CLASS (Thispage)
   Unclassified
                           22. PRICE
EPA Form 2220-1 (9-73)
-15-

-------
                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
i. REPORT NO.
 EPA-600/7-80-043
                          2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Pilot Scale Combustion Evaluation of Waste and
 Alternate Fuels: Phase m Final Report
                                 5. REPORT DATE
                                 March 1980
                                 6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

R. A. Brown and C. F. Busch
                                                     8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Acurex Corporation
Energy and Environmental Division
485 Clyde Avenue
Mountain View, California 94042
                                 10. PROGRAM ELEMENT NO.
                                 EHE624A
                                 11. CONTRACT/GRANT NO.

                                 68-02-1885
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                                     13.1 YPE OF REPORT AND PERIOD COVERED
                                                     Phase IE Final; 2-8/78
                                 14. SPONSORING AGENCY CODE
                                   EPA/600/13
15. SUPPLEMENTARY NOTES IERL-RTP project officer is David G. Lachapelle, Mail Drop 65,
919/541-2236. EPA-600/7-79-132 was the Phase H final report; there was no Phase I
final report.		
is. ABSTRACTThe report gives results of three studies at EPA's Multifuel Test Facility.
The first evaluated a distributed-air staging concept for NOx control in pulverized-
coal-fired systems. The results showed that minimum NO levels of 140 ppm were
achieved at overall residence times similar to those used during conventional sta-
ging tests. However, the NO levels achieved with the distributed-air concept were
no lower than those achievable with conventional staging.  The second evaluated com-
bustion control techniques and NO emissions when firing coal/oil mixtures. NO emis
sions for a given burner and nozzle were generally proportional to the fuel-nitrogen
content of the fuel. Additionally, combustion control technology currently used for
NOx control from pulverized coal was found to be effective with coal/oil mixtures,
but to differing degrees, depending on the coal/oil mixture ratios and compositions.
The third evaluated emissions and combustion characteristics of refuse-derived fuel
(RDF) co-fired with either natural gas or pulverized coal. Four RDF materials were
evaluated for gaseous,  particulate, trace metal, and organic emissions. In general:
CO and UHC emissions were low; NOx and SOx emissions decreased with increasing
RDF content when co-fired with coal; particulate levels did not substantially increase
with the RDF; and no trace metal emissions correlation was found.
7.
                            KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b.lDENTIFIERS/OPEN ENDED TERMS
                                                cos AT I Field/Group
Pollution
Nitrogen Oxides
Combustion Control
Refuse
Wastes
Coal
Fuel Oil
Pollution Control
Stationary Sources
Staged Combustion
Refuse-derived Fuel
Coal/Oil Mixtures
Alternate Fuels
13B
07B
21B
                                              21D
13. DISTRIBUTION STATEMENT
 Release to Public
                     19. SECURITY CLASS (ThisReport)
                      Unclassified
                                                                  21. NO. OF PAGES
                                                                      227
                     20. SECURITY CLASS (Thispage)
                      Unclassified
                                              22. PRICE
EPA Form 2220-1 (9-73)
                                        -16-

-------
                               TECHNICAL REPORT DATA
                         (Please read Inunctions on the reverse before completing)
1. REPORT NO.
EPA-600/7-80-049
                          2.
                                                     3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
 Residual Oxidants Removal from Coastal Power Plant
 Cooling System Discharges: Field Evaluation of SO2
 Addition System	
           5. REPORT DATE
            March 1980
           6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                     8. PERFORMING ORGANIZATION REPORT NO.
 K. Scheyer and G. Houser
9. PERFORMING ORGANIZATION NAME AND ADDRESS
 TRW, Inc.
 One Space Park
 Redondo Beach, California  90278
           10. PROGRAM ELEMENT NO.
           INE624A
            11. CONTRACT/GRANT NO.

            68-02-2613, Task 23
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
            13. TYPE OF REPORT AND PERIOD COVERED
            Task Final: 1-11/79  	
            14. SPONSORING AGENCY CODE
             EPA/600/13
15. SUPPLEMENTARY NOTES jERL-RTP project officer is Julian W. Jones, Mail Drop 61, 919/
 541-2489.
i6. ABSTRACT
              report gives results of an evaluation of the performance of a dechlor-
 ination system that uses SO2 to remove residual oxidants from chlorinated sea
 water in a power plant cooling system. Samples of unchlorinated , chlorinated, and
 dechlorinated cooling water were obtained at Pacific Gas and Electric 's Potrero
 power plant in San Francisco. The samples were  collected during 28 sampling per-
 iods--14 at flood tide and 14 at ebb tide--and analyzed for several chemical and
 physical constituents. An amperometric titrator was used for field  analysis of total
 oxidant residual (TOR) and free oxidant residual (FOR). Analytical  results, plant
 operating data, and laboratory experiments were  used to evaluate the dechlorination
 system. Major conclusions  include: (1) the dechlorination system studied showed
 effective removal of residual oxidants from chlorinated sea water used in the  power
 plant cooling system; (2) the dechlorination system proved reliable  (no measurable
 oxidant residual was found at the effluent outfall); and (3) due to the effectiveness of
 the dechlorination system in removing all measurable oxidant residual, average and
 maximum levels of dechlorination cannot be determined.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                          b.lDENTIFIERS/OPEN ENDED TERMS
                        c. COSATI Field/Group
 Pollution            Oxidizers
 Dechlorination
 Cooling Systems
 Sea Water
 Electric Power Plants
 Sulfur Dioxide
Pollution Control
Stationary Sources
Oxidant Removal
13B       11G
07A,07B,07C
13A
08J
10B
18. DISTRIBUTION STATEMENT
 Release to Public
19. SECURITY CLASS (This Report}
Unclassified
21. NO. OF PAGES
   38
20. SECURITY CLASS (Thispage)
Unclassified
                        22. PRICE
EPA Form 2220-1 (9-73)
                                        -17-

-------
                               TECHNICAL REPORT DATA
                         (Please read Instructions on the reverse before completing)
1. REPORT NO.
  EPA-600/9-80-012
                           2.
                                                     3. RECIPIENT'S ACCESSION NO.
Proceedings: First Symposium on Iron and Steel
Pollution Abatement Technology (Chicago,  IL,
10/30-11/1/79)	
             5 REPORT DATE
              February 1980
             6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                     8. PERFORMING ORGANIZATION REPORT NO.
 Franklin A. Ayer, Compiler
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Research Triangle Institute
P.O. Box 12194
Research Triangle Park, North Carolina  27709
             10. PROGRAM ELEMENT NO.
             1AB604
              11. CONTRACT/GRANT NO.

              68-02-2630, Task 6
12. SPONSORING AGENCY NAME AND ADDRESS
 EPA, Office of Research and Development
 Industrial Environmental Research Laboratory
 Research Triangle Park, NC  27711
                                                      13. TYPE OF REPORT AND PERIOD COVERED
                                                      Proceedings; 3/79 - 2/80
              14. SPONSORING AGENCY CODE
               EPA/600/13
15. SUPPLEMENTARY NOTES jERL-RTP project officer is Robert C. McCrillis, Mail Drop 62,
919/541-2733.
is. ABSTRACT
              repOrj- documents presentations at the first EPA-sponsored symposium
devoted solely to pollution abatement technology for the iron and steel industry, held
in Chicago, IL, October 30 - November 1, 1979. The symposium was organized into
air, water, and solids sessions. Air pollution topics included: emission standards,
assessment of coke quench tower and by-product recovery plant emissions, sealing
of coke-oven doors , volatilization of hydrocarbons in steel rolling operations , devel-
opment of a coke-oven air pollution control cost effectiveness model,  control of sin-
ter plant emissions utilizing recirculation of windbox gases , estimating fugitive con-
tributions to ambient particulate levels near  steel mills , foreign technology for EOF
fugitive emission control, and fugitive particulate emission factors for BOF oper-
ations.  Water topics included emission standards, total recycle of water in integra-
ted steel mills, use of spent pickle  liquor in  municipal sewage treatment, physical/
chemical treatment of steel plant wastewaters using mobile pilot units, foreign tech-
nology forcontrolling coke plant and blast furnace wastewaters , and formation and
structure of water-formed scales. Solid waste topics included emission standards ,
environmental and  resource conservation considerations of steel industry solid
waste, and de-oiling and utilization of mill scale.
17.
                            KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                         b.IDENTIFIERS/OPEN ENDED TERMS
                            COS AT I Field/Group
Pollution           Mathematical Models
Iron and Steel Industry
Emission           Sintering
Assessments       Dust
Coking             Waste Disposal
Hydrocarbons       Chemical Cleaning
  Pollution Control
  Stationary Sources
  Emission Standards
  Fugitive Dust
13B
11F

14B
13H
07C
12A
11G
18. DISTRIBUTION STATEMENT
 Release to Public
                                          19. SECURITY CLASS (ThisReport)
                                          Unclassified
                                                                  21. NO. OF PAGES
                             510
  20. SECURITY CLASS (Thispage)
  Unclassified
                          22. PRICE
EPA Form 2220-1 (9-73)
-18-

-------