Nutrient Concentrations in Streams from Nonpoint Sources by James M. Omernik* Introduction The enclosed maps (3) and graphs (2) were compiled to provide a national overview of nutrient concentrations in streams from nonpoint sources. These materials are being incorporated into an Ecological Research Series (U.S. Environmental Protection Agency, Office of Research and Development) report to be issued this summer. Meanwhile, we hope they will be useful to water resource planners and managers for making general assessments of stream nutrient levels attributable to nonpoint sources. The enclosed materials are based on (1) the mean annual nutrient concen- trations from a nationwide set of 928 National Eutrophication Survey (NES) stream sites associated with watersheds impacted only by nonpoint sources and (2) the relationships of the NES nonpoint data to general land use categories and other macro-watershed characteristics. Although there is considerable disagreement about what exactly comprises a "point source" as compared to a "nonpoint source", very generally speak- ing, point sources are considered to be municipal and industrial waste discharges and nonpoint sources are everything else. Exceptions, which are roughly defined in section 502 of Public Law 92-500 (U.S. Congress, 1972), include concentrated animal feeding operations and also other operations which are or may be discharging pollutants through a pipe, ditch, channel, etc. For the purpose of this study, nonpoint source watersheds are those without municipal and industrial waste discharges and animal feedlots identified as point sources. It should be clearly understood that the values illustrated on the maps are those of mean annual concentrations representative of existing non- point source areal characteristics, which include both natural and anthro- pogenic sources. The NES stream samples were taken on the average of once a month for one year (see map insert for years of sampling initiation and distribution of sites). Land use and other drainage area characteristics data were compiled from available aerial photography and other materials dated as closely to the sampling years as possible. Sampling and laboratory methods were uniform throughout the entire data set. For more detailed information on the sampling and laboratory methods, the history, objectives and overall design of the NES, and the land use study appendage to the NES, * Corvallis Environmental Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, Corvallis, OR 97330 ------- see the following publications: NES Working Paper No. 175 (U.S. Environ- mental Protection Agency, 1975), and The Influence of Land Use on Stream Nutrient Levels (Omernik, 1976). Map Development Basically, the development of each of the three stream nutrient concentra- tion maps involved several preliminary processes. First, the actual mean annual nutrient concentrations were assigned to the representative posi- tions of their true sampling site locations on a 1:3,168,000 scale base map. Then, an enlargement of Anderson's Major Land Uses map (U.S. Geologi- cal Survey, 1970) was prepared in color at the 1:3,168,000 scale. It should be noted that the land use category scheme used on Anderson's map is compatible, with some transposition, with that used for the enclosed graphs. Next, a blank drafting film overlay was attached to the base map on which the actual concentrations for a given nutrient form had been annotated. These in turn were superimposed on, and registered to, the enlarged land use map. Then a 1:3,168,000 map illustrating all of the study watersheds by color coded dots, indicating their respective land use categories, was compared to the above map to enable the compiler to determine whether or not data points were representative of typical general land use in their respective regions. By studying these mapped data and knowing the general relationships shown by the graphs, one could visualize the general land use patterns and the spatial relationships between observed stream nutrient concen- trations and land use. Additional help in .understanding the part other macro-watershed characteristics play was provided by comparison with various other maps including: distribution maps of fertilizer expendi- tures, cattle and other agricultural products or activities, (U.S. Dept. of Commerce, Bureau of Census, 1973); isometric maps of acid precipita- tion observations (Likens, 1975); and an "ecoregions" map, which in itself provides a regional breakdown of a synthesis of the macro-water- shed characteristics relative to forest and rangeland resources (Bailey, 1976). Therefore, the actual drawing of the stream nutrient concentra- tion map units was guided to a great extent by the alignment of Anderson's land use map units. However, as the observed values and their apparent relationships and interrelationships with existing land use and other phenomenon varied regionally, the map units were drawn to reflect these variations. The nutrient concentration map units (each representing a range of concen- trations) were determined mainly by analysis of the frequency distributions of the 928 values for each nutrient form. The objective was to obtain a fairly even distribution of values (observations) throughout each map's range of map units. Understandably, the map unit sizes were adjusted slightly to allow for even, easy-to-understand intervals. ------- The categories shown in the reliability map inset reflect several factors. The two most important are (1) the distribution of data points and (2) the types and homogeneity of land use in a given region together with the probable applicability of land use-stream nutrient concentrations rela- tionships to that region. Also important were the significance of surface runoff in determining stream nutrient concentrations and the distinguish- ability of nonpoint from point source impact on streams. Examples of where the latter becomes a problem can be found in the flat tidal reaches of the Atlantic Coastal Plain and throughout much of Florida. Obviously regions where NES stream sampling sites were concentrated and where land use and watersheds were well defined, the reliability would be categorized as good. On the other hand, arid areas where stream data (where streams exist) are difficult to obtain and/or where surface runoff is an insigni- ficant factor, the reliability would be categorized as poor. Areas cate- gorized fair were generally those where NES tributary sampling data were scarce or lacking, but where land use and other macro-drainage area charac- teristics were such that reasonable estimates could be made based on the relationships and interrelationships observed in similar areas. ------- Bibliography Bailey, R. G. 1976. Ecoregions of the United States. Map, scale - 1:7,500,000. U.S. Forest Service, Ogden, Utah. Likens, G. E. 1975. Acid Precipitation: Our Understanding of the Phenomenon. In: Acid Precipitation. Proceedings of a Conference on Emerging Environmental Problems. EPA-902/9-75-001, U.S. Environ- mental Protection Agency, Region II, New York, New York. pp. 45-75. Omernik, J. M. 1976. The Influence of Land Use on Stream Nutrient Levels. EPA Ecological Research Series, EPA-600/3-76-014. U.S. Environmental Protection Agency, Con/all is Environmental Research Laboratory, Corvallis, Oregon. 105 pp. U.S. Congress. 1972. An Act to Amend the Federal Uater Pollution Control Act. Public Law 92-500, 92nd Congress, Washington, D.C. U.S. Department of Commerce, Bureau of Census. 1973. 1969 Census of Agriculture; Graphic Summary Vol. V, Part 15. U.S. Government Print- ing Office, Washington, D.C. 145 pp. U.S. Environmental Protection Agency. 1975. National Eutrophication Survey Methods, 1973-1976. National Eutrophication Survey Working Paper No. 175. U.S. Environmental Protection Agency, National Eutro- phication Research Program, Corvallis, Oregon. 91 pp. • U.S. Geological Survey. 1970. The National Atlas of the United States, U.S. Government Printing Office, Washington, D.C. 417 pp. ------- .009 68 77 295 5 16 103 12 17 10 144 11 72 74 >90% Forest >75% Forest > 50% Forest > 75% Cleared Unproductive > 50% Cleared Unproductive Mixed >50% Range: Remainder predominantly forest > 75% Range > 50% Range: Remainder predominantly agriculture > 50% Agriculture >40% Urban > 75% Agriculture 590% Agriculture Land Use vs. Mean Total Phosphorus and Mean Orthophosphorus Stream Concentrations Data from 904 "Nonpoint source-type" watersheds distributed throughout the United States orthophosphorus concentration .034 4 I— total phosphorus concentration .02 .04 .06 .08 .10 .12 Milligrams per Liter .14 .16 .18 .20 ------- 68 >90% Forest 77 > 75% Forest 295 > 50% Forest > 75% Cleared 5 Unproductive > 50% Cleared Unproductive 103 Mixed £ 50% Range: 12 Remainder predominantly forest 17 £ 75% Range 250% Range: IQ Remainder predominantly agriculture 144 > 50% Agriculture 11 > 40% Urban 72 > 75% Agriculture 74 > 90% Agriculture .598 Land Use vs. Mean Total Nitrogen and Mean Inorganic Nitrogen Stream Concentrations Data from 904 "Npnpoint source-type" watersheds distributed throughout the United States inorganic nitrogen concentration .294 J839 L- total nitrogen concentration 4.233 ] 5.354 1.0 2.0 3.0 4.0 Milligrams per Liter 50 6.0 ------- ERRATA NOTICE A few errors are present on the total phosphorus and total inorganic nitrogen maps because the wrong negatives were used in printing. These mistakes will probably not affect your use of the maps since all of the errors except one involve less than 0.2% of the total area. Corrected maps will be included with the final project report which will be issued later this year. The more significant corrections are listed below: Total Inorganic Nitrogen (1) Map unit 6 is incorrectly represented by the same color as that used for map unit 7; therefore, use the unit number to differentiate between areas. This is the only error involving a significant portion of the map. (2) A few small areas are not categorized and there- fore appear as white. These will be categorized in the corrected maps. Total Phosphorus (1) There are no errors involving significant portions of the map. Great Salt Lake should appear as white rather than represented by map unit 7. (2) The white area shown for the western edge of Utah should be represented by map unit 7. (3) A small area in the extreme northwestern tip of Florida and southern edge of Alabama is incorrectly categorized. Any questions regarding the correction should be directed to James M. Omernik (FTS 420-4613 or 4611/Commercial 503-757-4613 or 4611) at the Corvallis Environmental Research Laboratory, 200 S. W. 35th St., Corvallis, Oregon 97330. ------- |