oEPA
         United States      Industrial Environmental Research  EPA-600/7-78-166
         Environmental Protection   Laboratory         August 1978
         Agency        Research Triangle Park NC 27711
Design and
Construction of a
Fluidized-bed
Combustion
Sampling and
Analytical Test Rig

Interagency
Energy/Environment
R&D Program Report

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination of traditional grouping was consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.   Environmental Health Effects Research
      2.   Environmental Protection Technology
      3.   Ecological Research
      4.   Environmental Monitoring
      5.   Socioeconomic Environmental Studies
      6.   Scientific and Technical  Assessment Reports (STAR)
      7.   Interagency Energy-Environment Research and Development
      8.   "Special" Reports
      9.   Miscellaneous Reports

This report has been assigned to the INTERAGENCY ENERGY-ENVIRONMENT
RESEARCH AND DEVELOPMENT series.  Reports in this series result from the
effort funded  under the 17-agency Federal Energy/Environment Research and
Development Program. These studies relate to EPA's mission to protect the public
health and welfare from adverse effects of pollutants associated with energy sys-
tems. The goaf of the Program is to assure the rapid development of domestic
energy supplies in an environmentally-compatible manner by providing the nec-
essary environmental data and control technology. Investigations include analy-
ses of the transport of energy-related pollutants and their health and ecological
effects;  assessments of, and development of, control technologies for energy
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 This report has been reviewed by the participating Federal Agencies, and approved
 for publication. Approval does not signify that the contents necessarily reflect the
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tion Service, Springfield, Virginia 22161.

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                                    EPA-600/7-78-166

                                          August 1978
   Design  and Construction of a
      Fluidized-bed Combustion
Sampling and Analytical Test Rig
                         by

                       H. Dehne

            Acurex Corporation/Energy and Environmental Division
                     485 Clyde Avenue
                 Mountain View, California 94042
                   Contract No. 68-02-2170
                  Program Element No. EHE623A
                 EPA Project Officer: John H. Wasser

              Industrial Environmental Research Laboratory
                Office of Energy, Minerals, and Industry
                 Research Triangle Park, NC 27711
                       Prepared for

              U.S. ENVIRONMENTAL PROTECTION AGENCY
                Office of Research and Development
                    Washington, DC 20460

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                                DISCLAIMER
       This report has been reviewed by the Environmental Protection Agency
and approved for publication.  Approval does not signify that the contents
necessarily reflect the views and policies of the Environmental Protection
Agency, nor does mention of trade names or commercial products constitute
endorsement or recommendation for use.

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                                  ABSTRACT

       A Flu1d1zed-Bed Coal  Combustion Sampling and Analytical  Test Rig was
designed, fabricated and installed in the High Bay area (Wing G)  of the
Industrial Environmental Research Laboratory (IERL) at Research Triangle Park,
North Carolina to be used by IERL for research programs.   It is a research
tool where the design philosophy was based on considerations of flexibility,
accuracy and utility.  The system operating ranges are:
       Coal feedrate       - 10 to 50 kg/hr (22 to 110 Ibm/hr)
       Sorbent feedrate    -  0 to 25 kg/hr (0 to 55 Ibm/hr)
       Excess air          - 10 to 300 percent
       Bed temperature     - 750°C to 1100°C (1380°F to 2010°F)
       Fluidizing velocity - 1 to 5 mps (3 to 16 fps)
The purpose of this project was to provide EPA with the capability to investigate
the emission characteristics of fluidized-bed combustors.
       The program was completed in three phases:   preparation  of the  conceptual
design; preparation of the final design;  purchase, fabrication, installation, and
checkout, testing and documentation.
       During  the conceptual design phase the capability of sampling the
composition of all process streams was especially  considered.  Recommendations
were made for  sampling  and analytical procedures  and equipment to measure
pollutants of  interest.  At least four particulate control devices were to be
incorporated in the  design.  They were a  conventional  inertial separator, a
"tornado-type" cyclone, a fabric filter and an electrostatic precipitator.
Emphasis was placed  on  the approximation  of full-scale conditions as closely
as  possible and to minimize the manpower  required to conduct tests and  change
conditions between tests.
                                       VI

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       The final design was carried out in sufficient detail to enable the
purchase, fabrication and installation of the unit.
       The equipment was procured, fabricated and installed in accordance with
the requirements set forth in the drawings and specifications in Phase II of
the program.

       Upon completion of the installation an acceptance test was conducted
to demonstrate that the system was completed in accordance with the approved
design and that all equipment was properly installed to serve its intended
purpose.
       An operating manual and as-built drawings have been submitted.
       This work was submitted in fulfillment of Contract Number 68-02-2170
by Acurex Corporation, Energy and Environmental Division under sponsorship of
the Environmental Protection Agency.

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                             TABLE OF CONTENTS

Section

           ABSTRACT	    iv

           ILLUSTRATIONS 	    viii

           TABLES  	    x

           ACKNOWLEDGMENT  	    xiv

   1       INTRODUCTION  	    1-1

   2       EQUIPMENT DESCRIPTION . .	    2-1

           2.1   General Arrangement  	    2-1
           2.2   Combustor	    2-8
           2.3   Air System	    2-13
           2.4   Solid Feed System	    2-16

           2.4.1  Introduction	    2-16
           2.4.2  Storage Bins	    2-20
           2.4.3  Feeders	    2-20
           2.4.4  Loadcells	    2-21
           2.4.5  Vibrators	    2-21
           2.4.6  Pressure Relief	    2-22

           2.5   Gas Cleanup System	    2-22

           2.5.1  Primary Cyclones	    2-22
           2.5.2  Tornado Cyclone	    2-23
           2.5.3  Electrostatic Precipitator 	.    2-24
           2.5.4  Baghouse	    2-25

           2.6   Flue Gas Heat Exchangers and Soot Blowing
                Lance	    2-26
           2.7   Control System	  .    2-29

           2.7.1  Introduction	    2-29
           2.7.2  Control Systems ~ Panels  	    2-31
           2.7.3  Process Variables ~ Oxygen and Combustibles
                  Analyzer	    2-45
           2.7.4  Safety Interlocks  	    2-47
           2.7.5  Instrument Listings  	    2-47

   3       FACILITY OPERATION  	    3-1

           3.1  System Characteristics 	    3-1

           3.1.1  Operating Preparations and Configurations   .  .  .    3-10
           3.1.2  Startup	    3-14
           3.1.3  Shutdown	    3-21


                                   viii

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                       TABLE OF CONTENTS (Concluded)


Section                                                               Page

           3.2  Combustor Operation  	    3-22
           3.3  Air System Operation	    3-26
           3.4  Solid Feed System	    3-31

           3.4.1  Safety Considerations  .	    3-31
           3.4.2  Solid Feed System Calibration and Setup   ....    3-35

           3.5  Gas Cleanup System Operation 	    3-40
           3.6  Flue-Gas Heat Exchanger and Soot-Blowing Lance
                Operation	    3-42
           3.7  Emergency Shutdown 	    3-43

   4       FBC TEST RIG SAMPLING AND ANALYSIS	    4-1

   5       TRAINING AND ACCEPTANCE TEST	    5-1

   6       RAW MATERIALS SOURCES, HANDLING, AND PRICES  .......    6-1

   7       SAMPLING SUPPORT FEATURES 	    7-1
                                     ix

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                           LIST OF ILLUSTRATIONS

Figure                                                                Page
 2-1       General arrangement drawing 	    2-2
 2-2       General arrangement drawing 	    2-3
 2-3       General arrangement drawing 	    2-4
 2-4       General arrangement drawing 	    2-5
 2-5       Combustor	    2-9
 2-6       Air system schematic	    2-14
 2-7       Solids  feed system	    2-17
 2-8       Solids  feed system	    2-18
 2-9       Flue gas heat exchanger	    2-27
 2-10      Soot blowing lance	    2-28
 2-11      P&ID	    2-32
 2-12      Control console	    2-33
 2-13      Main control console — solids feed system panels .  .  .    2-37
 2-14      Pneumatic  diagram 	    3-38
 2-15      Air ejector nomenclature	    3-40
 2-16      Ejector pressure rise vs.  air flow	    2-41
 2-17      Pneumatic  control console 	    2-42
 3-1       Air flowrate versus coal flowrate	    3-5
 3-2       Fluidizing velocity versus total gas flowrate 	    3-6
 3-3       FBC test rig system schematic	    3-9
 3-4       Main air flow versus pressure drop	    3-16
 3-5       Coolant flow versus pressure drop	    3-19
 3-6       Secondary air and FGR versus pressure drop	    3-27
 3-7       Air flowmeter AP versus sdnr/min (scfm) 	    3-28

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                     LIST OF ILLUSTRATIONS (Concluded)

Figure                                                                Page
 4-1       FBC test rig sampling locations	    4-9
 4-2       Typical analyzer conditioning system  	    4-15
 4-3       High volume stack sampler (HVSS)	    4-21
 4-4       Tenax module and vaporous trace element impinger
           train	    4-23
 4-5       SASS train sampling and analysis	    4-25
 7-1       FBC test rig sampling locations . .	    7-2
                                   XI

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                               LIST OF TABLES

Table                                                                 Page
 2-1       Air Supply System Instrumentation 	    2-35
 2-2       Solids  Feed System Instrumentation  	    2-43
 2-3       Fluidized  Bed  Combustion Unit  Instrumentation  	    2-44
 2-4       Flue Gas Cleanup  System  Instrumentation 	    2-46
 2-5       Safety  Interlocks 	    2-48
 2-6       Instrument Nomenclatures  	    2-49
 2-7       Temperature Selector  Switch Indication   	    2-54
 3-1       Design  Point Conditions  	    3-2
 3-2       Combustor  Design  Point Energy  Balance  kJ/hr
           (Btu/hr)	    3-3
 3-3       Flow and Temperature  Design Ranges	    3-7
 3-4       Design  Point Pressure Distribution  	    3-8
 3-5       Distributor Plate Flow Range  	    3-11
 3-6       Solids  Feed System Specifications 	    3-32
 3-7       Suggested  Vibrator Timer Setpoints  	    3-39
 4-1       Sampling Services Contractors  	    4-2
 4-2       Potential  Analytical  Contractors   	    4-4
 4-3       Example List of Chemical and Physical  Forms  of
           Pollutants of  Concern:   Pollutant Chemical  Forms  ...    4-5
 4-4       Sampling and Analytical  Methods  Summary 	    4-10
 4-5       Sampling Locations and Requirements 	    4-12
 4-6       Online  Pollutant  Analyzers  	    4-16
 4-7       Coal and Ash Analyses	    4-29
                                Xll

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                         LIST OF TABLES (Concluded)

Table                                                                 Page
 6-1       Sunroary of Selected Coals	     6-3
 6-2       Coal  Transportation Costs from Mine to Cincinnati  .  .  .     6-5
 6-3       Typical Analyses of Limestones and Dolomites  	     6-7
 6-4       Source and Cost of Sorbent Materials	     6-9
 7-1       Sampling Locations and Requirements 	     7-3

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                              ACKNOWLEDGMENTS

       The  author wishes to express his appreciation  to the many
individuals who contributed to this program at Acurex Corporation.   I  wish
to thank the members of the design team; Hal Williams, Jim Gotterba,
Bob Fulton, George Deutsch, for the special efforts expended.   Particular
thanks also go to Robert Larkin and Carlo Castaldini  for their
contributions to the reports and special thanks to the publications
department.
       The personnel of the Industrial Environmental  Research Laboratory
of the EPA are recognized for their role in achieving this goal.  Special
thanks go to J. Wasser the EPA Project Officer and Walt Steen.
                                  xiv

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                                 SECTION  1
                                INTRODUCTION

       The need for environmentally acceptable coal-based  steam  and  power
generation processes gave rise to this project.  As stated  in the Scope  of
Work.
       "Fluidized-bed combustion (FBC) offers the potential for  coal-based
       steam and power generation with low environmental impact, and  at
       the same time with improved thermal efficiency and  reduced manpower
       costs in comparison with conventional boilers.   It  is important to
       completely characterize emissions  from FBC units.   The purpose of
       this project is to provide EPA with the capability  to investigate
       the emission characteristics of fluidized-bed combustors.  The
       major goals of the test rig schedule are:
       0   Sampling the wide range of potential contaminants
       t   Testing alternative sampling and analytical  techniques
       •   Testing alternative control devices."
       The contract called for the design, fabrication  and  installation  in
the High Bay area (Wing G) of the Industrial Environmental  Research
Laboratory (IERL) at Research Triangle Park, North Carolina of a
fluidized-bed combustion sampling and analytical test rig  and auxiliary
equipment that would be used for IERL in-house research programs.  The
test rig was to be a research tool  and the design philosophy should stress

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 operational feasibility,  accuracy and utility.   Flexibility was required
 to allow the operation in a wide range of interest,  accuracy to be able to
 draw significant conclusions from the experiments and utility to allow
 economic operation  of  the facility.
        The program  called for a  program in  three phases.
        Phase I   :   Determination  of  Conceptual  Design
        Phase II  :   Preparation of Final  Design  and
        Phase III:   Purchase,  Fabrication and  Installation
        The conceptual  design  considered specifically the  identification of
requirements and  based  upon  these requirements  a conceptual  design was
prepared.   The requirements  were  the approximation of full-scale
conditions,  the  capability to sample the composition of  all  process input
and output streams, recommendations  of  sampling and  analytical  procedures,
the inclusion of  four  particulate control devices, the ease  of  subsequent
additions  and testing  of  control  devices, the flue and combustion
conditions  and considerations of  solids handling.
        Based upon the  requirements identified a conceptual  design was
prepared and submitted.   Included in the design package were schematic
drawings and flow sheets,  drawings and  specifications of  key components,
material and heat balances,  equipment and instrument lists  and  discussions
of methods  of solids handling and subsequent  addition of  add-on control
devices.
        Upon  completion  and approval  of  the  conceptual design the final
design  was  generated.   Detailed component and construction  drawings were
prepared along with equipment duty and  performance specifications.  The
final process flow  analysis  verified the material and energy balance.  The
                                     1-2

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fate of all input and output streams was  determined  and  a  survey of  new
material sources and prices was conducted.
       The final design was approved and  the Phase III begun  and
completed.  Tasks completed under the Phase III program  were  the hardware,
fabrication and installation, the preparation of  an  operating manual,
personnel training, the acceptance test and as-built drawings.
       The objective of the program was accomplished.  Section  2 of  the
report details the fluidized-bed sampling and analytical test rig
construction and Section 3 the operation  of the test rig.
       The procedures and equipment to be used for sampling and analysis
are discussed in Section 4.
       Section 5 discusses the acceptance test and results and  Section 6
the raw material sources and prices.
                                     1-3

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                                SECTION 2
                          EQUIPMENT DESCRIPTION

2.1    GENERAL ARRANGEMENT
       The FBC Test Rig located at Research Triangle Park in the Wing G
Facility was built to allow the evaluation of a number of different pollu-
tion control devices for fluidized bed flue gas control  applications.  The
fluidized bed essentially provides the flue gases to be controlled.  To
permit comparison studies to be conducted, control devices can be exchanged
by connecting these devices onto convenient locations in the system.  All
major components in the system were placed along the Wing G mezzanine floor
to allow easy access to the flue gas ducting for sampling and servicing.
The following requirements were considered important in the design:
       •   Size of components
       •   Reconfiguration capability
       •   Normal traffic patterns
       0   Solids handling and storage
       •   Forklift accessibility
       0   Sampling port location and sampling convenience
       The general arrangement drawings presented in Figures 2-1 through
2-4 show the FBC Test Rig major components.  The major features of the sub-
systems are briefly presented below.
       0   Combustion unit
           -   38 x 38 cm (15 x 15 in) combustor area
           -   20.3 cm (8 in) refractory
                                     2-1

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ro
i
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                                                                                                     GENCRM. ARRANGEMENT

                                                                                                        TEST «fc
                                        Figure  2-1.  General arrangement  drawing.

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                                                                                                        GENERAL ARRANGEMENT
                                                                                                        F.B.C TEST wo
                                         Figure 2-2.   General arrangement  drawing.

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                                            fertSni... .. ...!..*..
                                                             GENERAL ARRANGEMENT
                                                             F BC TEST ME
•      I       »-     T

  Figure  2-3.  General arrangement  drawing.

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rvs
01
                                                                                                                 ARRANGEMENT
                                                                                                          F8 C TfST RIG
                                          Figure  2-4.  General  arrangement drawing.

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 -   3.05 m (10 foot)  freeboard
 -   122 cm (48 in)  bed height
 -   Perforated plate distributor
 -   Ash removal — through distributor plate
 -   Automatic  bed height control
 Air  system
-   Spencer blower 7080 sdm3/min, 93°C, 34.5 kPa
     (250 scfm, 200°F, 5 psi), low noise
—   96  kW preheater
—   FGR mixing chamber
—   Staged combustion capability
Coal, sorbent and ash feed system
—   8 hour service bins (three)
-   Vibratory feedrate controllers
-   Pneumatic injection
—   Bin weight monitors
Primary cyclone
—   Refractory lined
-   Nominal collection size 7y at facility design point
Secondary cyclone
-   Aerodyne "tornado" cyclone
-   Externally insulated stainless steel 310
ESP
—   Double chamber design
-   Temperature rating to 260°C (500°F)
Baghouse
-   Reverse pulse
                           2-6

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           -   6.8  m2  (73  ft2)  teflon  felt  material
           -   Temperature rating  to 260°C  (500°F)
       •   Flue gas heat exchangers
           -   Refractory-lined housing
           -   Water-cooled cooling modules
           -   Bare tube design
           -   First two modules with  double pitch  to  prevent clogging by
               flyash
           -   Manual  soot blowing lance
       0   Control  system
           -   Manual  control
           -   Safety  interlocks
           —   Alarm lights
           -   Automatic  heater temperature control
           -   Pressure and temperature readouts
           -   Weight  readouts
       The FBC test rig is designed to take full advantage of the available
space.  The 122 cm (4  foot) bed height and the 3.05 m (10 foot)  freeboard are the
maximum that could be  accommodated below the false ceiling in the EPA Wing G
Laboratory.  The components of the rig are placed to allow access to the
combustor and other heavy  parts by forklift for servicing or for a con-
figuration change.   All major components are placed along the mezzanine.
By placing the flue gas ducting along  the mezzanine, the design  allows
sampling from that floor without requiring inconvenient, costly, and dan-
gerously high platforms.
       In addition, the unit is designed to be used with all or  only some
of the components onstream.  Provisions have been made to enable the opera-
tor to bypass or change the flow through the secondary cyclone by adjusting
three damper valves to the appropriate positions.  The secondary control
devices can also be evaluated in parallel, series, or separately by
                                     2-7

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 connecting them 1n  the desired configuration with flexible ducting.  Four
 exit ports are provided on the flue gas heat exchanger to connect secondary
 control  devices.  The  stack Is equipped with several equipment ports and
 sampling ports to gain  this versatility.
       The baghouse has been designed to be placed on rollers to enable the
 operator to clear the central area quickly should access from the outside
 be  required.   This would normally not be the case while the facility 1s
 operating.  Access by forkllft Is only required for configuration changes
 and  servicing  of the feed bins; both of these activities can be accomplished
 by entering the area from the other side.
       All components of the FBC test rig  have been designed to reduce the
 Tabor and minimize the chance of injury to the operator.  Controls and ser-
 viced components are easily accessible, and all high-temperature surfaces
are insulated to reduce heat loss and make them safe for personnel.

2.2    COMBUSTOR
       The major component in the FBC test rig is the combustor.  As shown
in Figure 2-5, it consists of the following elements:
       •    Combustor section
       •    Freeboard chamber
       •    Distributor plate
       0    Heat exchangers
       •    Air plenum box
       •    Bed height and temperature sensors
       •    Sampling  and view ports
       •    Injection ports
       •    Ash removal  system

Combustor Section
       The combustor section houses the fluidized bed during operation.  The
combustor shell measures 91.5 cm (36 inches) wide, 79 cm (31 inches) deep, and
 152 on (60 inches)  high.  The shell is lined with mineral wool and refractory
 of minimum 20  cm (8 inch) thickness.  The refractory used is Harbison Walker

                                      2-8

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Figure 2-5.   Corribustor.
             2-9

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 40-64.  It features a maximum operating temperature of 1430°C (2600°F)» low
 iron oxide content and a small  linear change of -0.2 to -0.6 percent at 815°C
 (1500°F).   The shell  has been designed to permit the casting of different com-
                                                      22             7
 bustor cross  sections.   The principal sizes are 968 cm , 1451 cm, and 1935 cm
        22             ?
 (150 in ,  225 in  ,  and  300 in').  These sizes are optimum for the noted heat
 release rate  of the combustor.  Rectangular openings in two opposing sides
 allow the  installation  of either heat exchangers or sight, sampling or injec-
 tion ports.   The third  side contains ports for pressure and temperature measure-
 ment instrument installations.  Sizes and locations of the ports are noted on
 the  respective  facility drawings.

 Freeboard  Chamber
       The freeboard chamber consists of the upper two sections of the com-
 bustor.  The modules are constructed similarly to the combustion chamber but
 consist of a 152 cm (60 inch) and 122 cm (48-inch high module with 1935 cm
       2
 (300 in )  cross sectional area.  The cross sectional area of the freeboard
 chamber was chosen in anticipation of the largest combustor cross sectional
 areas to be used.   This will reduce particulate carryover due to lower free-
 board gas  velocities.  The modules are carbon steel, mineral wool insulated
 and refractory lined.  The top module is referred to as the exit module and
 the lower  freeboard module as the intermediate module.
           With the exception of its large cross-sectional area and its lack
of a solids injection port, the intermediate module is identical to the
combustor section.   This configuration allows for the insertion of free-
board heat exchangers which will be installed to maintain the gas tempera-
 tures within the specified limits if a high portion of the combustion takes
 place in the freeboard due to staged combustion.  More importantly, the
configuration allows for the installation of staged combustion air ports and
 sight and sampling ports.  Not all openings are effectively usable because
 of the location of the mezzanine floor and structural steel.  The exit mod-
 ule, otherwise similar in construction, has no rectangular access ports for
 service modules; however, it is equipped with the 15 cm (6 inch) exit ports
 for  the mounting of flue gas ducting or particulate control devices.  The top
 of the module is covered with a refractory-lined lid.

                                      2-10

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Distributor Plates
       To simulate  full-scale facilities  and to fluidize the bed properly,
a distributor plate must have a pressure  drop of approximately 30 percent of
the bed weight.   For this combustor,  it is  in the range of 0.98 to 3.92 kPa
(4 to 16 inches)  of water.   To allow  for  the wide variation in operating con-
ditions from 1133 sdm3/min at 21°C (40 scfm at 70°F)  to 7080 sdm3/min at
427°C (250 scfm at  800°F), six to seven plates are required.  This number
allows for some overlap, and covers the entire range  but does not represent
optimum design for  all  operating conditions in this range.  A perforated plate
design has been selected for this combustor to accommodate the flow range at
an economical cost.  The plates are made  of stainless steel 310 for tempera-
ture and corrosion  resistance, reinforced by 0.82 cm (1/8 inch) by 1.27 cm
(1/2 inch) flat stock ribs to reduce  warpage.  The edges of the plates
have been slotted to reduce the thermal stresses introduced due to tempera-
ture gradients in the plate.  The plate when mounted is "floating" in its
seal, again reducing internal stresses.  Since the plate is only slightly
larger than the cross-section of the  maximum bed, it will attain a fairly
uniform temperature which also helps  to minimize distortion.

Heat Exchangers
       The combustion zone heat exchangers are bare tube and water-cooled.
To accommodate the large turndown  requirement, heat exchanger modules can
be independently added and removed to  attain the cooling requirement for
the  required mode  of operation.
       The heat exchangers consist of  a plenum, an insulating cover, and
hairpin cooling tubes.  The  tubes  and  the  insulating cover  are manufactured
from SS 310  and the cooling  plenum from low  carbon steel.   Because a re-
fractory  plug would have been  too  sensitive  to cracking,  the  insulating
cover forms  the sidewall of  the fluidized  bed when the  heat exchanger  is
installed.   The sidewalls of the cover are made of RA 330 expanded metal to
minimize  the transfer of energy to the outside wall of  the  FBC.  The cool-
ing  tubes may be operated without  coolant,  particularly  during startup when
all  the energy available should be used to  bring  the facility up to tem-
perature  (up to 871°C  (1600°F)).   The  heat  exchangers  are  vented if no flow
is passing through them.
                                      2-11

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 Air Plenum Box
        The air plenum  box serves as the retainer for the distributor plate,
 guides the air through the plate and holds the standpipe for the ash removal
 system.   The box  is designed so that it can be easily removed.  Although
 blanket insulation is  used rather than refractory lining in order to keep
 the weight of the box  down, it is still heavy and requires some support
 (e.g., a  forklift) for servicing.  The air pipe connected to the plenum box
 is  mounted on a flexible line and misalignment problems have been minimized.
 The inner chamber is made of stainless steel 304, and the outside shell is
 carbon steel.

 Bed  Height  and Temperature Sensors
       The  bed height is  measured via three pressure ports by two differential
 pressure measurements.   One measurement will give the indication of bed
 density and the other of bed height.
       Two  temperature probes are provided in the bed and two in the free-
 board.  Additional thermocouples can be added if desired.

 Sampling and View Port
       The combustor and  the intermediate section both have rectangular
openings for the mounting of heat exchangers, sampling, view or injection
ports.  As described above in the discussion of heat exchangers, view or
sampling ports are mounted on carbon steel plates equipped with a cover to
form the wall of the bed  section or the freeboard.  Purge air is provided
to keep these ports free  of combustion materials.

Injection Ports
       Solids injection is accomplished pneumatically.  A special entry port
has been designed for the inlet pipe to allow the injection of materials
close to the distributor plate.  If it becomes desirable to change the loca-
 tion of this port, a special  injection port could be built to be installed
 in a heat exchanger slot.  The material of construction for the injection
 tube is stainless steel 310.
                                      2-12

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       A second type of port has been designed and is standard for the
staged combustion system with various configurations to satisfy the require-
ments of tangential  and center injection.   Very substantial  injection
velocities can be achieved with these ports if as much as 30 percent of the
air is injected at one location by one tube, resulting in very high imping-
ing rates on the opposite side in the combustor.  Since these high impinging
rates cause local hot spots and wear, it is recommended that the injection
rates at any one location be kept low to minimize this problem.

Ash Removal System
       The ash removal system consists of a 5 cm (2 inch) diameter pipe that
extends through the distributor plate and is held in place by the plenum box.
An air operated slide gate valve is operated when the bed height exceeds a
preset upper limit initiating a sequence and sounding an alarm of 0 to 5
seconds duration.  The valve is opened for 0 to 10 seconds and the actuation
is limited to once every 6 to 60 minutes.  The ash is discharged into an open
container that can accommodate  the material from an 8-hour full load test run.
The operation of the  valve is automatic, with manual override.  After the test
run,  the bin should be emptied  to insure the proper operation on the next
succeeding test.

2.3    AIR SYSTEM
       The air  system supplies  the fluidized bed combustor with combustion air.
In order  to  burn  10  to  50  kg/hr (22  to  110  Ibs/hr)  coal  as planned, 1133 to
7080  sdm  /min  (40 to  250  scfm)  of combustion air is  required.  The system is
capable  of heating  the  air to 427°C  (800°F) during  startup to preheat the sys-
tem  and  ignite  the  coal.   High  excess air  conditions  also require preheated
air  to maintain  combustion temperatures.   With  flue  gas  recirculation, up to
25 percent of combustion  products may be recirculated.
        For staged combustion, the air system  is  also designed  to allow air
injection  in various  locations  above the distributor plate.
        Figure 2-6 shows  the  schematic of the air system.
       As  shown  in  the  flow  diagram, air enters  the system through a filter/
silencer  and passes  through  a  throttling valve.  This  valve  is normally
open, but can be used to  establish a vacuum condition  to draw  flue gases
                                      2-13

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                                                                                                          0-538"C

                                                                                                          (0-1,000»F)
                              5 cm (2")
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                                                                             To c«ri>ustor
                                              Figure 2-6.   A1r system schematic.

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into the mixing chamber when  flue  gas  recirculation  is  utilized.  The  air
passes then through the mixing  chamber and  mist  eliminator  and  is metered
for total flow.  The inlet valve upstream of the blower is  used to  regulate
the total flowrate.  This valve has been placed  upstream of the blower to
reduce blower surge in  low flow conditions.  The air is then passed through
the blower and the preheater  and into  the air distribution  network. Staged
air is metered in each  branch.
       As the schematic shows,  it  is possible to draw only  flue gases  into
the blower by closing the throttling valve.  This will  initiate a fault
condition due to overtemperature.   Under normal  conditions  the  inlet tem-
perature should not exceed 93°C (200°F).  It has been verified  that no con-
densation of SO  components will occur at the concentrations expected  and no
damage to the blower will result.
       A number of safety interlocks have been provided in  the  air  system.
These interlocks are discussed in  greater detail in  the controls section.
       The specifications of the major air system components are as follows:
Control Valves
       V-orifice for good flow control at  low flowrates
        5 cm  (2 inch) and 10  cm (4  inch)  valves
Blower
        Spencer turbine  5010-H
        7080  sdm3/min at 34.5 kPa  (250  scfm at 5  psi) pressure, low noise
        93°C  (200°F)  inlet temperature
        15-hp motor, 480 V, 30, 60  cycle
Orifices
        Maximum pressure drop at rated  flow:  2.49 kPa  (10 inch) H20
Heater
        96-kW duct  type  design
        34.5  kPa  (5 psi)  airtight
                                      2-15

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       SCR control with over-temperature  shutoff  (815°C  (1500°F))
       480 V/30
       Magnetic contact Isolation
       The air system utilizes a low-noise Spencer turbine blower, a  high
 reliability device.
 2.4    SOLID FEED SYSTEM
 2.4.1  Introduction
       The solids feed system meets  the  following requirements:
       t   Coal  feedrate - 10 to 50  kg/hr  (22  to 110 Ibs/hr)
       •   Sorbent feedrate - 0 to 22 kg/hr  (0 to 50 Ibs/hr)
       a   Ash feedrate - 0 to 10 kg/hr  (0 to  22 Ibs/hr)
       •   Air injection flowrate -  less than  15 percent  (by  weight)  of
           total  combustion air
       •   Continuous operation
       •   Solids particle diameter  - 0.63 cm  (1/4  inch)
       t   Pressure at injection point - nominal 117 kPa  (17  psia)
       The system is shown in Figures 2-7  and  2-8.   The major components
are:
       a   Solid feed bins (three) for 8-hour  service
       a   Support frame
       a   Load cells and readouts on the  control console
       a   Vibratory feeders  (3)
       a   Pressure controlled mixing chamber
       a   Jet ejector
       a   Pneumatic transport line
       a   Service air compressor
       a   Various gauges  and  regulators
                                        2-16

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Figure 2-7.  Solids feed system.

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                                               Figure 2-3.   Solids  feed system.

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       Following is a discussion of the injection mechanism methodology.
       The coal, sorbent, and flyash is stored in three 8-hour service  bins,
from which it passes through downspouts onto the base of three vibrating
feeders.  The feedrate of each feeder can be adjusted at the control  console
by varying the voltage applied.  The mouth of each feeder delivers the
materials into a common mixing hopper.  The mixing hopper and the vibrating
feeders are enclosed in a housing that may be pressurized, if necessary,  at
high flowrates and pressures.  The common hopper guides the materials
through a jet ejector that accelerates the particles toward the combustor
for injection.  A number of gauges, regulators, and valves allows proper
adjustment of injection air flowrates.
       The bins are supported by load cells that deliver an analog signal
to the control console, where a direct readout indicates the respective bin
levels.  This output can be converted into solids flowrates and gives an
accurate indication of mass flowrate.  This direct reading method has the
advantage of giving accurate results for different materials.
       The transport line has been sized to permit flow without saltation over
the specified range of solids loading.  For a single 2.5 cm (1 inch)  inner dia-
meter transport line, using 10 percent of the total combustion gas, it  is pos-
sible to convey from 16 to 81.5 kg/hr (35 to 180 Ibs/hr) of coal/sorbent/ash
without saltation (50y to 0.32 cm (1/8 inch)).  Theoretically, at transport
velocities greater than the saltation velocity, all solids will be transported.
As the transport velocity falls below the saltation velocity, solids  begin to
drop out of the airstream to roll and slide along the bottom of the transport tube.
       In this system, saltation is a problem only if it leads to plugging of the
line or excessive pressure fluctuations.  If this occurs, a 50 percent  increase  in
transport air flow (or 15 percent of the total combustion gas) will eliminate any
saltation in this particle size range.  If this alternative proves unattractive,
a 1.9 cm (3/4 inch) diameter transport line can be used instead of the  2.5 cm
(1 inch) line.  This will provide solids flow capability down to 11.3 kg/hr
(25 Ibs/hr) with 10 percent air flow.  Nearly twice the transport velocity, or
four times the pressure drop, is required.  Maximum transport velocities  for  the
                                      2-19

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2.5 cm  (1  inch)  line would be 30.5 mps (100 fps), using about 906 sdm3/min
(32 scfm)  of air.
        The soltds  feed system consists of subsystems accomplishing storage,
metering,  mixing,  and pneumatic transport of coal, sorbent,  and flyash to
the FBC.   Controls and instrumentation are included to assure constant flow
and easy regulation of solids feedrate and air flow to the combustor.
        Detailed  descriptions of the individual components are given in the
following  subsections.
2.4.2   Storage Bins
        Each bin  has been sized to allow more than 8 hours supply of material
at maximum feedrate.
        The 60° cone-bottom, cylindrical bins are each suspended at two
points  just below  the top flange.  One of the supports is a radiused load-
cell, and  the other (on the opposite side of the bin) is a Vlier pivot
mount.  Horizontal constraint is provided by a rubber restraining grommet
located below and at 90°  to the pivot line.
        Each bin  is sealed to a common "mixing box" below by a 7.6 cm (3 inch)
rubber  sleeve.   Each bin  is also sealed at the top with a gasketed lid.
        An  adjustable feed nozzle at the outlet of each bin provides cross-
flow regulation.   Adjustment of these nozzles is addressed in Section 3.

2.4.3   Feeders
        The  solids feedrates are individually controlled with three specially
modified Eriez Model  ISA  vibratory feeders.  By regulating the input voltage
of each feeder (through individual auto transformers), the vibration ampli-
tude of each feeder tray  is controlled, and hence, the feedrate of each
solid.
        Each  feeder has been modified to prevent particle size segregation
due to  vibration, and to control the amount of solids on the tray (which is
important  for uniformity of flow).  Because of differences in particle size
distribution, and other dust characteristics (density, sphericity, etc.),
                                      2-20

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the flyash feeder requires a slightly different tray  design  than  the  coal
and sorbent feeders.

2.4.4  Loadcells
       BLH Electronics Type C2M1  strain gage loadcells  are used as  the
primary measurement of individual solids feedrate.  Each bin is supported
(on one side only) by a loadcell  of the appropriate range, a 900  kg (2000  Ib)
model for the coal bin, a 450 kg  (1000 Ib) model for  the sorbent  bin, and  a
225 kg (500 Ib) model for the flyash bin.
       As mentioned,  each loadcell supports only half the total bin weight.
But, because each loadcell circuit has a span adjustment, each has  been
adjusted to read actual total weight (in Ibs.).  Also,  through an adjust-
able zero level, the weight of an empty bin can be set to be zero (or some
other convenient number if zero is out of range).
       There are several possible sources of error in the loadcell  reading
that can be avoided through proper action.  Because only one loadcell is
used, it is important to load the bin evenly to distribute the weight
equally.  Secondly, the loadcell  reading has a slight dependence  on bin
pressure, hence, a change in air flow can affect weight readings  if con-
stant bin pressure is not maintained.  These and other possible sources of
error in weight readings are discussed further in Section 3.

2.4.5  Vibrators
       To assure smooth and continuous flow of solids to the feeder
(especially at low bin levels), and to prevent  "ratholes and bridges" in
each of the materials, it is necessary to provide external agitation.  For
this purpose, the bins are equipped with Vibco Model  VS-130 turbine
vibrators.  Both the coal and sorbent are fairly easy to handle solids and
therefore need only one vibrator each.  The vibrator is located on the cone
section of the bin and is used primarily at near-empty conditions.
       The flyash, however, being less dense,  smaller, and stickier has a
vibrator mounted on the outlet downcomer in addition to one on the cone.
                                       2-21

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        Controls exist to vary the inlet  pressure to all vibrators and to
 vary the duty cycle of each vibrator.  They are discussed in the controls
 section.

 2.4.6  Pressure Relief
        The solids feed system comes equipped with two, redundant Circle-seal
 model 559 pressure relief valves.
        Without pressure relief,  if the transport tube clogged, the bin would
 be quickly pressurized to the ejector supply pressure - as high as 689 kPa
 (100 psi).  Obviously, the bins  and mixing box are not designed to withstand
 this pressure.  The relief valves will insure that the bin pressure does not
 exceed a preset level.
        For adjustment  instructions, see Section 3 and the manufacturer's
 instructions.

 2.5    GAS CLEANUP  SYSTEM
        The gas cleanup  system can be divided into two categories:  high-
 temperature devices and low-temperature devices.  The high-temperature
 devices are the primary and secondary (or "tornado") cyclones (540°C to 1080°C)
 (1000°F to 2000°F).  The low-temperature devices are the electrostatic pre-
 cipitator (ESP)  and the baghouse (149°C to 260°C) (300°F to 500°F).  Each of
 these is discussed  in further detail in the following subsections.

        Other kinds of cleanup devices can easily be evaluated by rerouting
 the  ducting or bolting  the devices in place of the installed equipment.
The  low-temperature systems can be particularly easily adapted with flexible
hoses.

2.5.1   Primary Cyclones
        Experience with FBC units has shown that a small portion (^10 per-
cent) of the coal carbon is not combusted during the first combustion cycle.
These unburned materials are usually collected in vertical separators or
cyclones  and recycled to the combustor or fed into special burnup cells for
combustion.

                                     2-22

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       The primary cyclone collector has been designed to have a cut size
of 7y at the typical  operating condition of 18,400 adm /min (650 acfm).
       Since this facility will be used over a wide range of operating  con-
ditions, some of the components have been oversized.   This is particularly
true of the blower.  A higher than normal pressure drop in the cyclone  can
thereby be tolerated.  Higher pressure drops or velocities through a cyclone
also imply smaller cut sizes - a desirable feature.  The cyclone has, there-
fore, been slightly undersized for the design point,  in order to allow  col-
lection of materials at low flowrates.  Higher pressure drops (to a maximum
pressure drop of 2.49 kPa (10 inches H20) at higher operating flowrates must
be accepted.  The cyclone must also operate at elevated temperatures.
       Two methods of construction were considered for the primary cyclone:
(1) Hastelloy X lined construction with high-temperature insulation on  the
outside, and (2) refractory-lined construction of carbon steel.  The
refractory-lined carbon steel shell construction was selected because refrac-
tory is not as sensitive to corrosion or limited to a maximum operating con-
dition of 1080°C (2000°F).  Some pilot scale facilities have also experienced
fires in the cyclones during upset conditions and this was considered in the
design.

2.5.2  Tornado Cyclone
       For the collection of particles not captured by the primary cyclone,
a tornado-type cyclone is provided and placed in series with and immediately
downstream of the primary cyclone.  Gas  flow from  the primary cyclone can
be directed through the tornado device.
       The unit installed is an Aerodyne Model 400SV dust collector.  It is
reported to have greater collection efficiencies for small particles than
conventionally designed cyclones due  to  the  increased vorticity within the
cyclone body.  This added swirl results  from the provision of a secondary
airstream directed in such a way as to  increase the tangential velocity of
the  flow within the cyclone body.
       The unit is constructed from SS  310 and is  externally  insulated with
a ceramic fiber felt for heat  retention  and  personnel safety.  For this unit
                                      2-23

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to operate properly, the pressure drop between the secondary inlet and outlet
duct must be adjusted by dampers during operation.  The pressure drop must be
on the order of 30.5 kPa (12 inches H,0).  At this pressure drop, the flowrate
                                3
in the secondary leg is 7530 adm /min (266 acfm).  The primary flow can then
be adjusted to make up for the difference in flow, to a maximum of 11,330
adm /min  (400 acfm).  A portion of the flow may be bypassed should the
capacity  of the unit be exceeded.

2.5.3  Electrostatic Precipitator
       The combustion gases are initially cleaned by the two inertial col-
lectors immediately downstream of the FBC.  The gas is then cooled, in order to
allow for the use of commercially available electrostatic precipitators (ESP)
and fabric filters (baghouse).   Several  full-scale industrial ESP's have been
operated at temperatures of about 427°C (800°F).  Temperature limits for
fabric filters, however, are established by the temperature limits of the
filter materials now available.   Teflon, fiberglass, and Nomex are recog-
nized to be state-of-the-art high-temperature filter materials.  Their
maximum allowable temperature limit is in the range of 232°C to 260°C (450°F
to 500°F).  In order to provide a cost-effective solution to the need for
evaluating both ESP and filter technology, the gas will be cooled to approx-
imately 260°C (500°F) by using the flue gas heat exchanger.
       Full-scale industrial  electrostatic precipitators are of the single-
stage design.  A two-stage design was, however, the only design available in
the size required for this project (11,300 adm /min at 260°C) (400 acfm at
500°F).  The design point represents the nominal midpoint in the flow range for
the FBC.  This value has also been used in the selection of the baghouse.  On
the average, efficiency will  increase for lower flow and will decrease for
higher flow values.
       ESP's in the 11,330 to 14,200 adm /min (400 to 500 acfm) size range are
typically designed for cleaning air circulating through heating and air-
conditioning systems or for cleaning the effluent from grease cookers.  Due to
cost, weight and ease of fabrication, aluminum is generally used in constructing
ESP's of this kind.   Aluminum, however, is not acceptable for the 260°C (500°F)
inlet condition specified above.  Therefore, a special design using 304 SS was
selected for this project.   The unit was fabricated by Beltran Associates using
                                     2-24

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                                                 o
their standard design dimensions  for a 11,330 adm /min  (400 acfm)  unit.  The
unit consumes less than 100 watts of power and collects  70 to  95  percent of
the particles that are not collected by the upstream collectors.   (Ninety
percent of the particle sizes passing through these  inertia! devices  are pre-
dicted to be less than 2 um; achieving high overall  collection efficiencies
is made difficult by these smaller particles.)

2.5.4  Baghouse
       In order to evaluate the compatibility of available fabric filtration
technology with the combustion products generated by an  FBC, a fabric filter
(baghouse) was installed in series with the ESP. Although the inlet  grain
loading and the mass median diameter of incoming particles is  significantly
reduced (approximately 0.023 gm/fm  (0.01 grains/scf) and 0.8  to  0.9  um),  the
provision of this unit allows for the evaluation of  filtration devices on
FBC effluents.
                                                         o
       Commercially available baghouses in the 11,330 adm /min (400 acfm)  range
offer any of the following techniques for cleaning  the accumulated dust cake
from the filter surface:
       •   Reverse flow
       t   Mechanical shake
       •   Reverse pulse
Multiple units would be required for either of  the first two mechanisms due
to the need for removing the filter from the  process during fabric cleanup.
Moreover, the gradually increasing pressure drop followed by a sudden drop
(as one unit is taken off stream and another  is put back online) is undesir-
able for the air system being designed.
       The reverse pulse technique of fabric  cleaning is not burdened with
either of these limitations.  The reverse pulsing technique is accomplished
by rapidly pulsing (^0.1 sec) the tubular bags  with compressed air.  The
shock wave, as it travels the length of  the filter, dislodges the accumu-
lated dust cake.  The interval between pulsing  is usually determined by the
inlet grain loading, and is  preprogrammed so  that the pulsing of various
bags  is continuous.
                                       2-25

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       A reverse pulse unit with a virtually static pressure differential
has been procured for this program.  The unit is a Young Industries
vertical/modular "UniCage" filter collector, Model Number VM 42-16.  The
design of this unit allows for the easy replacement of the filter tubes for
the evaluation of various high-temperature fabrics.  The VM 42-16 is constructed
                                   p
of carbon steel and contains 6.78 m  (73 square feet) of teflon felt.   The unit
requires 57 sdm3/min (2 scfm) of dry, oil-free air at 620 kPa (90 psig) for
the reverse pulse cleaning.

2.6    FLUE GAS HEAT EXCHANGERS AND SOOT BLOWING LANCE
       The flue gas heat exchanger cools the high-temperature exhaust gases
from up to 1094°C (2000°F) to approximately 204°C (400°F).  At this temperature,
no condensation will occur in the ESP or baghouse.  Thus, severe corrosion will
be avoided.  The flowrate is 1133 to 7080 sdm3/min (40 to 250 scfm) and the
heat transfer requirement is 42,400 kJ (40,000 Btu/hr) to 594,000 kJ
(560,000 Btu/hr).
       The heat exchanger installed (Figure 2-9) consists of a refractory-
lined carbon steel shell.   Ten bare tube heat exchangers provide the large
turndown required.  During operation, only those units required for cooling are
turned on.  All other units are connected to a drain.  The tubes themselves
are made out of 1.6 cm (5/8-inch) outer diameter SS 304 tubing mounted in
carbon steel plenums.
       Experience with the heat exchangers in multifuel furnaces has shown
that considerable solid material can collect on the tubes.  This calls for
wider spacing of the first heat exchanger tubes than of the later  tubes.  To
clean the tubes without requiring the removal of  the heat exchangers, a soot
blowing lance (Figure 2-10) has been provided.  The lance can be used to
clean the tubes while the unit is in operation.   Entry ports for the probe
have also been provided.  Through these, the probe can be inserted and an
air spray jet be directed onto the tubes.  The soot material falls to the
bottom of the heat exchanger, where  it is collected in an ash drawer that
can be easily removed and emptied.
                                     2-26

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Figure 2-9.   Flue gas heat exchanger.
                 2-27

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                                                  Figure 2-10.   Soot blowing  lance.

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2.7    CONTROL SYSTEM

2.7.1   Introduction
       The controls  and  instrumentation of the FBC  test  rig  serve four basic
subsystems:
       •   Fluidization  air supply system
       0   Coal/sorbent  storage and transport  system
       0   Fluidized-bed combustion unit
       §   Flue gas  cleanup system
       Each of these subsystems has distinct measurement capabilities which
are equipped with special  alarms or interlocks.   These alarm systems have
adjustable set-points and are interlocked with the  process safety and inter-
lock system.
       Three of the  above systems are essentially always used in a  similar
configuration and represent the heart of the FBC.  The flue  gas cleanup  sys-
tem, however, will be arranged into many different  configurations to suit the
needs  of the test.   These devices are also relatively passive and require
little control.  The philosophy followed here is to provide  "plug in" capa-
bility to measure the desired temperatures and pressures, and to provide the
required alarm capability.

Fluidization Air Supply  System
       The fluidization  air input to the combustor  is controlled by separately
controlling the total air flowrate and the flue gas recirculation  (FGR)  rate.
Each of these is controlled by the operation of manual valves. The total
fluidization air flowrate and the FGR flowrate are  derived  by measuring  the
differential pressure across orifices.  The absolute  pressure and temperature
are measured for mass flowrate computations.  The amount of  excess  air  is
measured indirectly  by measuring the oxygen content in the  flue gas.  The
excess air is controlled by adjusting the ratio of  ambient  air to flue gas.
                                       2-29

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Coal/Sorbent  Storage and Transport System
       The  coal, sorbent, and ash feedrates are controlled by manually ad-
justing  a variac controller on the control console.  The voltage variation
in  turn  causes  a more or less severe vibration of the vibratory feeders.
Direct-reading  mass transducers give indications of the various amounts of
materials being fed into the FBC.
       When coal, sorbent, or ash is fed, the pneumatic transport air is
controlled  by manual valves and measured by means of a laminar flow element
in  the line.  As before, absolute pressure and temperature are measured for
mass flowrate computations.
       Each supply bin is equipped with a status alarm to indicate a low
supply.  Because of the abrasive nature of coal, erosion of pneumatic trans-
port lines  can  cause problems.   These have been minimized by design.

Fluidized-Bed Combustion Unit
       Temperature in the fluidized bed combustion unit is measured at
multiple locations within the bed and the freeboard.  Although any one of the
temperatures  could be controlled, only bed temperature is controlled.  This
is  done  by  controlling the water flowrate in the cooling coils and by adding
or  removing heat exchanger surface area.  Cooling water flowrate and inlet/
outlet temperatures are measured for energy balance computations.  The bed
height can  be controlled by installing an overflow port at the appropriate
location.   Ash  can be removed automatically through the removal tube to main-
tain the bed  height within a certain height tolerance band.  Bed height is
measured by noting the pressure differential between three known points -
two in the  bed  region and one in the freeboard.  In the same way, bed density
is measured by  reading the pressure differential between two points a known
distance apart  within the bed,  and the bed height in proportion to a third
point.   Other pressures measured are inlet pressure, freeboard pressure,  and
distributor pressure differential.
       Safety interlocks include low air velocity, bed overtemperature and
heat exchanger  overtemperature.
                                       2-30

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Flue Gas Cleanup System
       For each cleanup device,  three measurements  are made;
       t   Pressure differential  inlet/outlet
       •   Inlet pressure
       •   Inlet temperature
Of these, only the first inlet temperature after the chiller  is  controllable.
This control  is achieved by adjusting the water flowrate in one  or more of
the chiller banks, using manual  valves.   The inlet  and outlet bulk tempera-
tures on each bank are measured.   To provide the required flexibility,  out-
let boxes for the measurement umbilicals are provided near these devices.
This allows the setup in any required configuration.
       Safety interlocks include a cleanup device inlet  overtemperature
warning light and a high differential pressure warning.   Figure  2-11  shows
the system P&ID.

2.7.2  Control Systems - Panels
       The control system is divided into four major sections corresponding
to the functional systems (see Figure 2-12).
       t   Air supply system instrumentation
       t   Coal/sorbent storage and transport'system instrumentation
       t   Fluidized-bed combustion unit instrumentation
       •   Flue gas cleanup system instrumentation
       The controls and meters are on standard 48.2 cm (19 inch) panels mounted
in vertical twin rack assemblies which are bolted together.  Each panel is
assigned to a specific subsystem, thus simplifying console operation and
providing minimum disruption if maintenance or modification is required on  a
given subsystem.
                                     2-31

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                                                Figure 2-11.  P&ID.

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               2-33

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Measurement Methods
       Process Variables - Pressure
       Pressure measurements in all areas of the FBC are made using  magne-
helic pressure gauges.  These gauges have proven their accuracy and  economy
in many applications.

       Process Variables - Temperature
       Temperature measurements within the system are designed to be within
the range of 0 to 1204°C (0°F to 2200°F)  in an oxidizing atmosphere.   Acurex
has selected ISA Type K thermocouples in  a closed tip stainless steel  sheath
for these measurements.

2.7.2.1  Air Supply System Instrumentation
       The air system provides the primary and secondary air at a con-
trolled temperature and flowrate to the combustion chamber.   Flue gas re-
circulation of up to 25 percent is also possible.  The primary air supply
system consists of manual  flow control valves, flow measurement devices,  the
blower, heater and controllers.  The secondary air system provides air for
staged combustion at desired flowrates to three combustor locations.   The
flow is controlled by manual  valves and flowrates are indicated indirectly
by pressure and temperature measurements.  The same control  philosophy ap-
plies to the flue gas recirculation loop.  Table 2-1 lists the measurements,
ranges and identification  numbers for the air system.  Controls located on
the air system panel are the:
       •   Blower power controls
       •   Heater power controls
       •   Heater controllers
       •   Temperature sensing selector switch and
       •   Heater lights for the blower,  heater, blower inlet temperature,
           heater overtemperature and air flowrate.
Two temperature controllers are provided  to control the air preheat tempera-
ture and protect the heater from sheath overtemperature.  The heater was

                                      2-34

-------
TABLE 2-1.  AIR SUPPLY SYSTEM INSTRUMENTATION
Measurement
FGR & air mixing
screen diff. pr.
Main orifice inlet pr.

Main orifice diff. pr.

Main orifice inlet temp.

Blower trip temp.

FGR inlet pressure

FGR orifice diff. pr.

FGR inlet temperature

Low air velocity switch

Air heater sheath temp.

Air heater outlet temp.

Secondary air inlet pr.

Secondary air LEG I
orifice diff. pressure
Secondary air LEG I
inlet temperature
Secondary air LEG II
orifice diff. pressure
Secondary air LEG II
inlet temperature
Secondary air LEG III
orifice diff. pressure
Secondary air LEG III
inlet temperature
Range
0-1.25 kPa
(0.5" H20)
0-5 kPa
(0-20" H20)
0-2.5 kPa
(0-10" H20)
0-93°C
(0-200°F)
93°C
(200°F)
0-2.5 kPa
(0-10" H20)
0-2.5 kPa
(0-10" H20)
0-316°C
(32°F-600°F)
0-0.125 kPa
(0-0.5" H20)
0-871 °C
(0-1600°F)
0-649°C
(0-1200°F)
0-37.3 kPa
(0-150" H20)
0-25 kPa
(0-10" H20)
38-538°C
(100-1000°F)
0-2.5 kPa
(0-10" H20)
38-538°C
(100-1000°F)
0-2.5 kPa
(0-10" H20)
38-538°C
(100-1000°F)
P&ID Identification
7255-101D

DPI-100

PI-100

DPI-101

TE-100/TI-100-1



PI-105

DPI-108

TE-115/TI-100-2

DPS- 100

TE-101/TY-101

TE-102/TIC-102

PI-102

DPI-102

TE-103/TI-102-2

DPI-103

TE-104/TI-102-3

DPI-104

TE-105/TI-102-4
P&ID Loc.
7255-101 D

D-7

D-7

D-7

D-7



A-4

A-4

A- 3

D-6

D-6

D-6

C-6

C-6

C-6

C-6

C-6

C-6

C-6
                       2-35

-------
 designed to deliver up to 427°C (800°F)  air  to  the combustor.  This  requirement
 dictates slightly higher temperatures  at the heater outlet of approximately
 454°C  (850°F).  The sheath temperature must  not exceed 871°C (1600°F) and  in
 order  to insure that this does  not occur, should be controlled to  a  maximum
 of 815°C (1500°F) at the sensing  location.   Tests have verified  that 538°C
 (1000°F) heater outlet temperatures are  safely  achievable.

 2.7.2.2  Solids  Feed System Instrumentation
        The  solids  feed system controls are divided into two sections.  All
 pneumatic controls are located on the solids feed frame control  panel,
 whereas electrical controls and interlocks are  located on the main control
 panel.   Figure 2-13 clearly identifies those controls located on the solids
 feed system and  those located on the main control console.
        There are two panels on the main control console used in  controlling
 and monitoring the air and solids flow (Figure  2-14).
        The air flowmeter panel is located at the top right of the console.
 It shows air flowmeter inlet pressure and differential pressure  across the
 flowmeter.
       The solids control panel  is located on the lower right side.  It pro-
vides the following functions:
       •   Feeder controls —on/off control  only
       •   Bin weight monitors - load cell readout and selector  switch
       •   Low bin level  indicator lights

Ejector
       It is advantageous, for two reasons,  to be able to control the air
flowrate and bin pressure independently.   First, it allows continuous load-
cell  readings while varying air flowrate.  Secondly, the bins can be loaded
without stopping the airflow (.by depressurizing the bins).  Normally (with a
plain transport line), the bin pressure will  vary with the square of the air
 flowrate, and will also vary directly with the combustor inlet pressure.
                                      2-36

-------
             AIR FLOWMETER
             INLET PRESSURE
ro
i
co
COAL BIN LOW

    LOADCELL
    SELECTOR
      SWITCH
                  SORBENT
                   BIN LOW


                    SOLIDS
                 FEEDRATE
                    ON/OFF
                 CONTROLS
                                                                    AIR FLOWMETER YP
                                                                                 LOADCELL READOUT
                                                                    FLYASH BIN LOW
                                                                                 SOLIDS FEED OFF
                                                                    BIN VIBRATOR
                                                                    ON/OFF CONTROLS
                                                              SOLIDS
                                                              FEEDRATE
                                                              CONTROLLERS
                       Figure 2-13.  Main control console -~ solids feed  system panels.

-------
ro

co
03
                                                                                                                             ?'
                                                                                            «.t i£Pt£ATt nwrr* u^r
                                                                                                          D 907M 776^-04-  A
                                                  Figure  2-14.   Pneumatic  diagram.

-------
       By adding an Air-Vac engineering Model  TORH-750 air ejector to the
transport line, the air flowrate and bin pressure are decoupled.   This can
be seen by noting that the air flow can be made up of virtually any com-
bination of Inlet air and supply air (as shown in Figure 2-15), and by not-
ing that as the supply air increases, so does  the pressure rise across the
ejector.  Figure 2-16 shows the map of values  that the ejector can cover in
this system.

Local Control  Panel
       The local  control  console is located at the right edge of the solids
feed system structure.   It is mounted on a swivel  to permit viewing and
access from either the  main control console or from the front of the solids
feed system.
       The local  pneumatic control panel, shown in Figure 2-17,  provides
nearly all of the control and instrumentation to regulate and monitor the
air flow, bin pressure, and vibrator pressure.  FBC inlet pressure is also
provided on the local  control console.
       Operation and specific function descriptions are contained in
Section 3.  Table 2-2 identifies all measurements, identification and
locations for the solids  feed system.

2.7.2.3  Fluidized Bed  Combustion Unit Instrumentation
       The active control subsystems in the FBC test rig are the air system
and the solids feed system.  Although the combustion actually takes place
in the combustor, it is otherwise a rather passive element.  The instru-
mentation associated with the combustor consists primarily of overtempera-
ture protection devices and temperature and pressure measurement devices.
Temperature alarms alert the operator and simultaneously shut down the
solids feed.  Measurements are listed in Table 2-3.  The temperature in the
bed is primarily controlled by the amount of heat exchanger surface sub-
merged in the bed and secondarily by the water flowrate.  The water flow-
rate control can only achieve a 2:1 heat transfer turndown and is therefore
not viable for temperature control.  The temperature is primarily controlled
through excess air and coal feed rates.
                                     2-39

-------
              AIR
              INLET
                                  AIR
                                  SUPPLY
             L_J
                t
             OUTLET
             (TO FBC)
Figure 2-15.  Air ejector nomenclature.
                 2-40

-------
ro
•ts.
                        z
                        m
                           WG

                            50
I
~2  40-f 10.0
 CO
0.
                        o
                        m
                       cc
                       o
                       LU
                       3
5
111
(A
E
                       cc

                       (O
                       £
                            10-
     kPa

     12.5
                            30- • 7.5
                                               276 kPa (40
                                          206 kPa (30 PSI)
20- •  5.0
         138 kPa (20


     69 kPa (10 PSI)

     2.5

       AP @551 kPa INLET PRESSURE
       ("WG @80 PSI INtET PRESSURE)
              0.5         1.25     1.75
              (2)          (5)     (7)
                                                                                     0 kPa
                                                                                    (0 PSI)
                                                                                 6.89 kPa
                                                                                  (1  PSI)


                                                                                   13.8 kPa
                                                                                   (2 PSI)
                                                                                   20.6 kPa
                                                                                   (3 PSI)
                                                                                                                         ill
                                                                                                                         cc
                                                                                   34.5 kPa
                                                                                      PSI)
                                                                                         48.2 kPa
                                                                                            PSI)
                                                                                                                  68.9 kPa
                                                                                                                  (10 PSI)
                                          (5)
                         (10)
                                          (15)
(20)
(25)
(30)
(35)
(SCFM)
0
1
100
200
300
400
I
500
I
600
700
I
800
1
900
1000
SDM3/MIN
                                                                       AIR FLOW
                                         Figure 2-16.    Ejector pressure  rise vs.  air  flow.

-------
ro
i
ro
                PRIMARY
             REGULATOR
                 PCV-118
    SECONDARY
    REGULATOR
       PCV-119

  BIN VIBRATOR
    AIR SUPPLY
    REGULATOR
       PCV-117

TRANSPORT AND
  VIBRATOR AIR
       ON/OFF
          V-120

     PURGE AIR
    REGULATOR
       PCV-122

     PURGE AIR
       ON/OFF
          V-112
                                 s.   PI-11C
                                    X)
                            PI-116    PI-117     PI-113
                                       |      PI-111    PM12
                                             o     o-
                                                         PURGE AIR
                                                         FLOW CONTROL
                                                                      EJECTOR
                                                                      AIR SUPPLY
                                                                      REGULATOR
                                                                      PCV-120
EJECTOR
INLET
REGULATOR
PCV-121
                                                                                BIN PRESSURE

                                                                                FBC INLET
                                                                                PRESSURE
                                 Figure 2-17.  Pneumatic control console.

-------
TABLE 2-2.  SOLIDS FEED SYSTEM INSTRUMENTATION
Measurement
Coal feedrate
Sorbent feedrate
Ash feedrate
Bin coal weight
Bin sorbent weight
Bin ash weight
Coal bin vibrator timer
Sorbent bin vibrator
timer
Ash bin vibrator timer
Vibrator supply air pr.
Primary air supply reg.
Secondary air sply. reg.
flow element inlet pr.
Flow element air temp.
Flow element diff. pr.
Ejector supply pressure
Mixer supply pressure
Pneumatic inlet FBC pr.
Purge air
Range
0-50 kg/hr
22-110 Ibs/hr
0-22 kg/hr
0-50 Ibs/hr
0-8 kg/hr
0-20 Ibs/hr
0-906 kg/hr
0-2000 Ibs
0-453 kg/hr
0-1000 Ibs
0-226 kg/hr
0-500 Ibs
3-120 sec
3-120 sec
3-120 sec
0-1102 kPa
0-160 psi
0-1102 kPa
0-160 psi
0-1102 kPa
0-160 psi
0-93°C
32-200°F
0-7.5 kPa
0-15" H20
0-1102 kPa
0-160 psi
0-34.5 kPa
0-5 psi
0-34.5 kPa
0-5 psi
0-1102 kPa
0-160 psi
P&ID Identifica-
tion 7255-1 01 D
HRC-100
HRC-101
HRC-102
WE-100/WI-100-1
WE-101-WI-100-2
WE-102/WI-100-3
HS-113/LV-113
HS-114/LV-114
HS-115/LV-115
PI-m/PEV-117
PI-116/PEV-117
PI-117/PEV-119
FE-118/TI-100-3
DPI-113
PEV-120/PI-113
PCV-121/PI-112
PI-115
FI-100/FI-101
P&ID Loc.
7255-101D
C-7
C-7
B-7
C-8
C-8
B-8
C-8
C-8
B-8
A-8
A-8
A-8
A-7/3-7
A- 7
B-6
B-7
B-5
B-6
                       2-43

-------
TABLE 2-3.  FLUIDIZED BED COMBUSTION UNIT INSTRUMENTATION
Measurement
Air plenum box pressure

Air plenum box temp.

AP distributor

AP bed density

AP bed height

Freeboard pressure

Bed temperature probes


Freeboard temp, probes

Heat exchanger bulk
water inlet temperature
Heat exchanger water
inlet pressure
Differential Orifice I
pressure
Differential Orifice II
pressure
Heat exchanger bulk
outlet temperature



Heat exchanger -1 outlet
temperature

n H _2 H
H II O II
"•*
:: ;; -,4 :;
» -
" -10 "
Range
0-37 kPa
0-150" H20
0-538°C
32-1000°F
0-5 kPa
0-20" H20
0-7.5 kPa
0-30" H20
0-7.5 kPa
0-30" H20
0-25 kPa
0-100" H20
0-1204°C
32-2200°F

0-1204°C
32-2200° F
16-38°C
60-1 00°F
0-689 kPa
0-100 psi
0-7.5 kPa
0-30" H20
0-7.5 kPa
0-30" H20
16-100°C
60-21 2°F
Adjust to
60°C
140°F

16-100°C
60-212°F





P&ID Identification
7255-101 D

PI-103

TE-300/TI-300-1

DPI-107

DPI-107

DPI-106

PI-104
TE-301/TI-300-2
TE-305/TI-300-3
TE-302/TAH-302
TE-303/TI-300-3
TE-304/TI- 300-4

TE-200/TI-200-1

PI-200

DP 1-200

DP I -201

TE-202/TI-200-2





TE-201-A/TI-200-3
-B -4
-C -5
-D -6
1 1
-J -12
P&ID Location
7255-101D

B-5

B-4

B-5

C-5

C-5

D-5
B-4
C-4
C-4
D-4
D-4

D-6

D-5

D-5

C-5

C-4





D-4
D-4


i '

                             2-44

-------
       The heat exchanger water supply system has been provided with a high
and low water flowrate orifice.  This configuration allows for accurate
measurements and a minimum changeover service requirement.  The two branches
of the water supply system can be installed and used in separate cooling
circuits such as a freeboard heat exchanger circuit and the bed heat ex-
changer circuit.  Each branch flow can be monitored independently.

2.7.2.4  Flue Gas Cleanup System Instrumentation
       The flue gas cleanup system instrumentation consists principally of
temperature and pressure sensors and indicating devices located on the flue
gas ducting and control console respectively.  The only controls are valves
controlling the flowrate through the secondary cyclone and thereby setting
the pressure drops and the coolant control valves for the flue gas cooler.
Like the heat exchanger coolant manifold for the combustor, the coolant
manifold for the flue gas cooler has a high and low flow orifice branch to
permit accurate flow measurements to be made while accommodating a high turn-
down capability.  The flue gas exhaust temperature is principally controlled
by adding and subtracting heat exchanger surface.  The temperature and pres-
sure measurement capabilities of the provided flue gas cleanup system are
listed in Table 2-4.
       Certain operating modes are undesirable because they may result in
equipment damage.  These modes of operation are indicated to the operator by
warning lights on the control console.  Undesirable operating conditions are
excess coolant water temperatures, high baghouse inlet temperatures and high
differential pressures across the baghouse.

2.7.3  Process Variables — Oxygen and Combustibles Analyzer
       To gain close control over the combustion process, the oxygen concen-
tration (excess air) must be monitored.  A Teledyne combustion process
analyzer Moder 9700 has been provided for this purpose.  The analyzer can be
divided into the oxygen and combustibles monitoring sections.
       The oxygen analyzer employs an electrochemical transducer to provide
an electrical signal that is directly proportional to the oxygen concentra-
tion in the gas phase immediately adjacent to its sensing surface.
                                       2-45

-------
TABLE 2-4.  FLUE GAS CLEANUP SYSTEM  INSTRUMENTATION
Measurement
Primary Cyclone
Inlet temperature
AP primary cyclone
Downspout temperature
Secondary Cyclone
Inlet temperature
Inlet static pressure
AP primary to secondary inlet
AP secondary inlet to outlet
Downspout temperature
Outlet temperature
Flue Gas Heat Exchanger
Gas inlet temperature
Flue gas cooler outlet 1
Flue gas cooler outlet 2
Heat exchanger bulk water inlet temp.
Differential Orifice I pressure
Differential Orifice II pressure
Heat exchanger bulk outlet temperature
Heat exchanger -1 outlet temperature
H * _? " "
U N 1 N M
" " -10 " "
Electrostatic Precipitator
Inlet gas temperature
Baghouse
AP inlet-outlet
Inlet gas temperature
Pulse plenum pressure
Range

0-1094°C
(32-2000°F)
0-3.8 kPa
(0-15" H20)
0-816°C
(32-1500'F)

0-927°C
(32-1700°F)
0-7.5 kPa
(0-30" H20)
0.75 kPa
(0-30" H20)
0-3.8 kPa
(0-15" H20)
0-816'C
(32-1500eF)
0-3.8 kPa
( 32-2000° F)

0-3.8 kPa
(32- 2000° F)
0-288°C
(32-550°F)
0-2888C
(32-550°F)
16-38°C
(60-100°F)
0-7.5 kPa
(0-30" H20)
0.7.5 kPa
(0-30" H20)
16-38°C
(60-212-F)
16-388C
(60-212°F)
1
0-288°C
(32-550-F)

0-2.5 kPa
(0-10" H20)
0-260°C
(32-500°F)
o-no2
(0-160 psi)
P&ID Identifica-
tion 7255-1 01 D

TE0304/TI-300-3
OPI-109
TE-109/TI-102-6

TE-107/TI-102-5
PI-106
DPI-111
DPI-110
TE-110/TI-102-8
TE-108/TI-102-7

TE-116/TI-102-9
TE-117/TI-100-4
TE-lll/TI-100-5
TE-203/TI-201-1
DPI -202
DPI-203
TE-205/TI-201-2
TE-201-A/TI-201-3
-B/TI-201-3
-J/TI-201-12
TE-113/TI-102-10

DPI-112
TE-112/TI-100-6
PI-108
P&ID Location
7255-101D

D-4
D-3
D-3

D-3
D-3
D-3
D-3
D-3
D-2

C-l
B-2
B-2
C-3
C-3
C-3
B-2
C-l

B-3

B-2
B-2
B-2
                                                           T-808
                          2-46

-------
       One of the three available ranges of analysis is 0 to 25 percent so
that air (2.9 percent oxygen) may be used to calibrate the sensitivity of
the analyzer.  It is equipped with an exceptionally accurate 12.7 cm (5 inch)
panel meter for direct readout of the analysis.  An output signal of 0 to
1 V D.C. is also available.
       The combustibles monitor consists of controls, readout meters, alarm
relays, sensors, flowmeters, valves and heaters.  A prominent meter displays
the gas concentration at the detection point as a percentage of the com-
bustible gases and is graduated from 0 to 5 percent combustibles.  An alarm
bell will  sound off should the concentration exceed a predetermined value.
       The complete description of the equipment, operation and service re-
quirements is given in the instruction manual  for the oxygen and combustibles
system Model  9700.

2.7.4  Safety Interlocks
       The following system safety interlocks  are provided to reduce the
danger of failure.   Attended operation, however, is required to monitor the
operation  of the facility.  All circuits are protected by circuit breakers
for overload conditions.  The devices are listed in Table 2-5.

2.7.5  Instrument Listings
       The FBC Test Rig has  been instrumented with temperature, pressure and
other sensors to allow measurements to be made for purposes of safety,
energy and mass balance's trend analysis and to generate those conditions of
interest for pollution control tests.  The following Tables 2-6 and 2-7 list
the instruments, their function and the location on the system P&ID.  The
tables, together with the P&ID, allow for quick identification during tests.
                                       2-47

-------
                      TABLE  2-5.  SAFETY INTERLOCKS
        Condition
 High  blower Inlet
  temperature
 Low air velocity
 Bed over-temperature
 Coolant overtemperature
 High baghouse AP
 High cleanup device
 temperature
 Low water pressure-bed
 Low water pressure cooler
Solids level  Indicator
            -  low  -
High combustibles
  Device
Temp, switch
AP switch
Temp, switch
Temp, switch
AP switch
Temp, switch
AP switch
AP switch
Transducers
Analyzer
   Response
Power off/heater off/
solids off
Solids off/heater off
Solids off
Solids off
Red light
Red light
Red light
Red light
Red light
Bell
                                     2-48

-------
TABLE 2-6.  INSTRUMENT NOMENCLATURES
Identification
Temo. Element
TE-100
TE-101
TE-102
TE-103
TE-104
TE-105
TE-106
TE-107
TE-108
TE-109
TE-110
TE-111
TE-112
TE-113
TE-114
TE-115
TE-116
TE-117
TE-118

TE-200
TE-201A
B
" C
11 D
11 E
11 'F
" G
" H
I
11 J
TE-202
TE-203
TE-204A
B
11 C
11 D
" E
11 F
" G
11 H
11 I
" J
TE-205
Location

D-7
D-6
D-6
C-6
C-6
C-6
D-6
D-3
D-2
D-3
D-2
B-2
B-2
B-2
B-3
A- 3
C-2
B-2
B-7

D-6
D-4
H
M
H
ii
H
u
n
n
it
C-4
C-3
C-2
ii
u
n
u
H
n
n
ii
n
B-l
Indication

TI-100-1
TI-101
TIC-102
TI-102-2
TI-102-3
TI-102-4
TI-102-1
TI-102-5
TI-102-7
TI-102-6
TI-102-8
TI-100-5
TI-100-6
TI-102-10
TI-102-11
TI-100-2
TI-102-9
TI-100-4
TI-100-3

TI-200-1
TI-200-3
11 4
" 5
" 6
" 7
11 8
11 9
11 10
11 n
„ 12
TI-200-2
TI-201-1
TI-201-3
11 4
11 5
" 6
" 7
11 8
11 9
11 10
11 11
„ 12
TI-201-2
Function

Main orifice inlet
Heated sheath T. contr.
Heater air temp, contr.
Sec. air temp, leg 1
II II II II 0
II II II II 0
Main air temperature
Pr. cyclone outlet gas temp.
Sec. " " " "
Primary cyclone dipleg
Sec. cyclone dipleg
Flue gas cooler outlet 1
Baghouse inlet
ESP inlet
Stack temp.
FGR orifice inlet
Flue gas cooler inlet
Flue gas cooler outlet 2
Flow element inlet, air
temp, solid feed system
Fluid, bed exchanger water in
Fluid, bed exchanger 1 " out
ii n n y " "
II II II o " H
n ii n A ii ii
II II II C II II
II II II C II II
II II II 1 II II
II II II O II II
ii ii ii n n n
ii ii u iQ u n
	 bulk out
Water inlet FG cooler
Water outlet exchanger 1
II II II n
II II II -j
4
5
6
M n M y
ii H n p
M ii ii Q
" " 10
Water bulk out FG cooler
                   2-49

-------
TABLE 2-6.   Continued
Identification
TE-300
TE-301
TE-302
TE-303
TE-304
TE-305
Temp. Switch
TS-100
TS-200
TS-201
TS-102
Flow Orifice
FO-200
FO-201
Location
B-4
B-4
C-4
D-4
D-4
C-4

D-7
C-3
B-l
B-2

C-3
C-3
Indication
TI-300-1
TI-300-2
TAH-302
TI-300-4
TI-300-5
TI-300-3


TAH-200
TAH-201
TAH-102



Function
Air plenum temperature
Fl . bed temperature I
Fl . bed overtemperature alarm
Lower freeboard temperature
Upper freeboard temperature
Fl. bed temperature II

Blower overtemperature
Water out overtemp. /light
Water out overtemp. cooler
Baghouse overtemp. alarm light

Water restr. dipleg primary
secondary
Hand Rheostat Contr
HRC-100
HRC-101
HRC-102
HS-113
HS-114
HS-115
HS-116
Pressure Indicator
PI-100
PI-102
PI-103
PI-104
PI-105
PI-106
PI-107
PI-108
PI-109
PI-110
PI-111
PI-112
PI-113
PI-114
PI-115
PI-116
PI-117
C-7
C-7
B-7
C-8
C-8
B-8
B-8

D-7
C-6
B-5
D-5
A-4
D-3
B-3
B-2
A-8
A- 7
A-8
B-7
B-6
B-7
B-5
B-7
B-7

























Auto-transf. vibrators coal
	 . sorbent
flyash
Timer-coal bin vibrator
Timer-sorbent bin vibrator
" ash
11 ash

Main orifice inlet pressure
Sec. air plenum pressure
Plenum box pressure
Freeboard pressure
FGR-orifice inlet pressure
Sec. cyclone inlet pressure
Stack pressure
Baghouse air plenum pressure
Compressor supply pressure
Purge air pressure
Vibrator line pressure
Reg. mixing chamber pressure
Ejector pressure
Mixing chamber pressure
Injection outlet pressure
Regulator pressure
Flow element inlet pressure
           2-50

-------
TABLE 2-6.  Continued
Identification Location
PI-200
PS-200
PS-201
Diff. Pressure
DPI-100
DPI-101
DPI-102
DPI-103
DPI-104
DPI-105
DPI-106
DPI-107
DPI-108
DPI-109
DPI-110
DPI-111
DPI-112
DPI-113
DPI-200
DPI-201
DPI-202
DPI-203
Diff. Pres. Sys.
DPS- 100
DPSH-106
DPSL-106
DPS-107
Flow Alarm
FAL-100
Pres. Contr. Valve
PCV-117
PCV-118
PCV-119
PCV-120
PCV-121
PCV-122
PCV-123
D-5
C-3
C-3

D-7
D-7
C-6
C-6
C-6
B-5
C-5
C-5
A-4
D-3
D-3
D-3
B-2
A- 7
D-5
C-5
C-2
C-2

D-6
C-6
C-6
B-2

D-6

A-8
A- 7
A- 7
B-7
B-7
A-7
A- 7
Indication Function
Water inlet pressure
PAL-200 Low-pr; alarm light dip! eg 1
PAL-201 Low pr. alarm light dipleg 2

Mixing ch. AP
Main orifice indicator
Secondary air leg 1
H it ii p
II II II o
Distributor plate
Bed height pressure
Bed density
FGR orifice
Primary cyclone
Sec-outlet-sec, cyclone
Prim-secondary-sec, cyclone
Baghouse diff.
Flow element diff. pr.
Bed exchanger main water
sec.. "
Cooler-exchanger main water
Cooler-exchanger sec. water

Low air flow sensor
Bed height control
Bed height control
Baghouse high AP height

Low air flow light

Vibrator pressure regulator
Transport air line pr. reg.
n H H n n
Ejector pressure regulator
Mixing chamber pr. regulator
Purge air pressure regulator
Baghouse pulse pressure
           2-51

-------
TABLE 2-6.   Continued
Identification Location Indication Function
Pr. Safety Valve
PSV-100
PSV-101
Valve
v-m
V-112
V-113
V-114
V-115
V-120
V-121
V-204
V-205
Flow Contr. Valves
FCV-100
FCV-101
FCV-102
FCV-103
FCV-104
FCV-105
FCV-106
FCV-107
FCV-108
FCV-109
FCV-110
FCV-200
FCV-201
FCV-206
FCV-207
Selector Valve
SV-202A
" B
11 C
11 D
" E
" F
11 G
" H
" I
" J

C-7
B-7

D-8
A- 7
A-7
B-5
B-a
A-7
B-5
C-3
C-3

D-7
D-6
C-6
C-5
C-5
C-5
D-3
D-3
0-3
B-5
D-8
D-5
C-5
C-2
C-2

D-5
n
M
n
n
n
n
M
n
H

Bin pr. relief valve
Mixing chamber pr. rel valve

Mixing chamber inlet
Air supply shutoff
Air supply shutoff
Air shutoff ash valve
Ash valve
Air supply shutoff
Solids transport shutoff
Pr. dipleg water
Sec. dipleg water

Main air flow
Secondary air
Secondary air heater bypass
Secondary air leg 1
n ii n p
„ „ 3
Secondary cyclone bypass dampr
11 sec. inlet
Secondary cyclone prim, inlet

Flue gas recirculation contr.
Bed exch. prim. wtr. control
" " sec. "
Cooler exchr. prim. wtr. contr
Cooler exchr. sec. wtr. contr.

Bed exchanger selector valve
n n it n
n n n ii
n n n n
n n n n
H n M n
n n n M
n M n n
n n n n
n n n n
            2-52

-------
TABLE 2-6.  Continued
Identification
SV-208A
" B
" C
" D
11 E
" F
" G
" H
" I
11 0
NV-203A
" B
" C
11 D
11 E
11 F
11 G
11 H
" I
" 0
NV-209A
11 B
" C
11 D
" E
11 F
11 G
11 H
11 I
" J
Solenoid Valve
SOV-113
SOV-114
SOV-115
SOV-116
SOV-117
EC-100
WE-100
WE-101
WE-102
FI-100
FI-101
Location
C-2
"
ii
11
"
"
11
11
11
"
D-A
II
II
II
II
11
II
II
II
II
C-l
n
n
n
n
n
11
n
n
M

C-8
B-8
B-8
A- 5
B-8
D-7
C-8
C-8
B-8
B-6
B-6
Indication Function
Bed exchanger selector valve
n n ii n
n n H n
n n M n
n n n n
n n n n
ii n n n
ii ii n ii
H II II II
II II II II
Bed check valves exchanger
n n n n
n n n n
n n n n
n n H n
n n n n
n n n n
n n n ii
n n n n
n n n n





















Cooler check valves exchanger
n M n n
n n n M
n n n n
II M II II
n n n n
n » n n
n ii ii ii
n n n n
n n n M

Vibrator contr. solenoid val
n n n n
n n M n
ES-116 Bed height sol. contr. valve
Vibrator contr. sol. valve
Blower contactor.










ve





WI-100-1 WAL 100 coal wt. ind/alarm log
WI-100-2 WAL 101 sorbent " " "
WI-100-3 WAL 102 ash " ' 	
Purge flow meter
n n n




            2-53

-------
TABLE 2-7.  TEMPERATURE  SELECTOR SWITCH INDICATION
Temperature
Indicator
TI-100-1
TI-100-2
TI-100-3
FI-100-4
TI-100-5
TI-100-6
TI-102-1
2
3
4
5
6
7
8
9
10
11 11
TI-200-1
2
3
4
5
6
7
8
9
" 10
" 11
11 12
TI-201-1
2
3
4
5
6
7
8
9
11 10
11 11
11 12
Temperature
Element
TE-100
TE-115
TE-118
TE-117
TE-111
TE-112
TE-106
TE-103
TE-104
TE-105
TE-107
TE-109
TE-108
TE-110
TE-116
TE-113
TE-114
TE-200
TE-202
TE-201A
" B
11 C
" D
11 E
" F
11 G
11 H
11 I
" J
TE-203
TE-205
TE-204A
" B
11 C
11 D
11 E
" F
" G
" H
11 I
" J
Description
Main orifice inlet
FGR orifice inlet
Flow element inlet-solids feed
Flue gas cooler outlet
n H H H
Baghouse inlet
Heater air temperature
Secondary air inlet I
Secondary air inlet II
Secondary air inlet III
Primary cyclone outlet
Primary cyclone dip! eg
Secondary cyclone outlet
Secondary cyclone diplet
Flue gas cooler inlet temperature
ESP inlet temperature
Stack temperature
Fluidized bed heat exchanger water in
Fluidized bed heat exchanger water out
Heat exchanger 1 out
n n f) n
3 "
n ii ^ n
II II C II
6 "
ii n -i n
M n n 'I
n n q ii
"10 "
Flue gas cooler water inlet
Flue gas cooler water outlet
Heat exchanger 1 out
1 II O It
1 II -J I'
1 II ^ II
I 'I C H
6 "
n n -j n
8 "
n n n n
10 "
                        2-54

-------
                                 SECTION 3
                             FACILITY OPERATION

       This section describes the operation and operating characteristics of
the system and subsystems.  The operation of the overall  system depends on
many variables and conditions.  Not all variables are independent, and a
judicious choice of the principal variables must be made to obtain the de-
sired test operation.  System characteristics are described in Section 3.1,
whereas subsystems are described in the various following sections.

3.1    SYSTEM CHARACTERISTICS
       The FBC test rig has been designed and constructed to operate in the
following basic ranges:
       •   Coal feedrate              - 10 to 50 kg/hr (22 to 110 Ibm/hr)
       •   Sorbent feedrate           - 0 to 25 kg/hr (0 to 50 Ibm/hr)
       •   Excess air                 — 10 to 300 percent
       •   Bed temperature            - 750°C to 1110°C (1380°F to 2010°F)
       •   Fluidizing velocity        — 1 to 5 mps (3 to 16 fps)
The facility is capable of attaining these ranges, but since the variables
listed above are not independent of each other, the ranges may not all be
attainable at the same time.
       The facility has been sized for an optimum operating condition.  This
condition was selected near the upper  limits of the given ranges to give the
test rig the greatest possible accuracy.  The design point conditions are
shown in Table 3-1.  The  resulting energy balance in the combustor is shown
in Table 3-2.  The basic  operating ranges define the operating envelope to
the degree that a bed cross-sectional  area can be selected.  For this
                                  3-1

-------
                   TABLE 3-1.   DESIGN  POINT  CONDITIONS
Coal feed rate (m )
Heating value (hy)
Air rate (ifr) (20% excess air)
           a
Sorbent feed rate (msorb)
  /limestone = 50% CaO by wt
 I Cals = 3
 \3% sulfur coal
Bed temperature (T)
Fluidizing velocity (U )
Heat removal by cooling (Q*.ukes)
Top particle size
31.7 kg/hr (70 Ibm/hr)
23,400 kJ/kg (10,000 Btu/lbm)
289 kg/hr (3990 sdm3) 638 Ibm/hr (141 scfm)
9.98 kg/hr (22 Ibm/hr)
843°C (1,550°F)
1.83 m/sec (6 ft/sec)
455,800 kJ (430,000 Btu/hr)
0.159 cm (1/16 inch)
                                    3-2

-------
      TABLE 3-2.   COMBUSTOR DESIGN POINT ENERGY BALANCE kJ/hr (Btu/hr)


Energy content of coal                        742,000               (700,000)
Energy added to fluidizing air     241,680             (228,000)
Energy removed by cooling tubes    455,800             (430,000)
Energy lost through insulated
   walls                            31,800             ( 30,000)
Energy lost to offtake ash           4,240             (  4,000)
Energy lost to elutriated solids     8,480             (  8,000)
                                   742,000   742,000   (700,000)   (700,000)
                                      3-3

-------
                                                   2               2
facility, the area has been sized as 968 to 1935 cm  (150 to 300 in )  in  order to
meet all specified conditions for fluidizing velocity and excess air.   Figure  3-1
(Air flowrate versus coal flowrate) and Figure 3-2 (Fluidizing velocity
versus total gas flowrate) show the effects of changing a particular variable.
Figure 3-2 also shows that at least two combustor cross-sectional areas are
required to accommodate the entire range of superficial velocities specified.
This was a necessary compromise, since not all components can tolerate the
high turndown specified and still perform their function.  Sizing of the
test rig and its components was based on the design point conditions and the
effects of varying the operating parameters.  The values shown in Table 3-3
reflect the maximum and minimum conditions.  Table 3-4 shows the pressure
distribution at the design point; Figure 3-3 shows the locations where tem-
perature, pressure, and flow are measured in the system.
       Since the flow and temperature ranges are not independent of each
other,  setting the flow or temperature at any one location will preclude the
attaining of the entire listed range at other locations.  It is noted also
that the total mass air flowrate is composed of two components.  They are
the main air flow and the solids transport air.  To achieve a desired air
preheat rate the composite temperature must be calculated to arrive at an
accurate value.
       Initial tests have indicated that all variables specified as basic
operating ranges can be obtained.  The ranges specified, however, were such
that they cannot be obtained without requiring the reconfiguration of at
least the combustor section and the exchange of the distributor plate.  The
fluidizing velocity is perhaps the variable causing the greatest inconve-
nience, particularly during startup, if low velocities are desired.  The
attainable fluidizing velocity is dependent on the bed material density and
size, the distributor pressure drop, the combustor size and the desired
operating temperature.  Low initial actual gas volume flowrates due to low
temperature cause the bed not to fluidize.  Increasing the flowrates with
high preheat temperatures results in high pressure drops across the distri-
butor which may limit the maximum attainable flow.  Should it not be possible
to inject sufficient air through the distributor, a secondary air port may be
utilized for this purpose during startup.

                                      3-4

-------
   1000 i-
Ol
4->
10
    100  -
                                                  60

                                               (Ibm/hr)
                                                      I
                               10
20         30
       mc kg/hr
                                                                40
50
                                  hy = 23,400 kJ/kg  (10,000 But/1bm)

                                  9  = Design point
                  Figure  3-1.   Air flowrate versus coal  flowrate.
                                            3-5

-------
o
o
01  O
>  91
    0 »-
             16-
             12-
o
at
           ^  8-
                             Desiqn   T = 1092°C2
                                          '8 on
              V  range    A =96
                                        T =  760° C
                                        A =  968 cm2
                                                          1098°C
                                                          1451 cn.2
                            500
                                                                    =  1451 cm?

                                                                    T  =  760°C
                                                                    A  =  1451 cm2
                                                            T = 843° C
                                                            A = 1935 cm2
                                                                  ©Design point
       1,000         1,500

Total  gas mass flowrate  (Ibm/hr)
                                                                     2,000
                                                                     2,500
                     I
                            I
                                       I
                                             1
                     100   200    300   400   500   600

                                             kg/hr
                                             700  800    900   1000
      Figure  3-2.   Fluidizing velocity versus  total  gas flowrate.
                                          3-6

-------
                                    TABLE 3-3.   FLOW AND TEMPERATURE DESIGN RANGES
OJ
I
Location
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
a
1133
1133
1133
569
0
0
0
10
0
0
97.5
3.6
79
0
78
0
78
78
78
0
78
Flow
0
- 7080 sdm/min
- 7080 sdm3/min
- 7080 sdm3/min
- 3414 sdm3/min
- 853 sdm3/min
-1133 sdm3/hr
-1416 sdm3/hr
- 50 kg/hr
- 148 kg/hr
- 378 dm3/min
- 654 kg/hr
- 18 kg/hr
- 650 kg/hr
-1.4 kg/hr
- 650 kg/hr
-114 dm3/min
- 650 kg/hr
- 650 kg/hr
- 650 kg/hr
- 1700 sdm/min
- 650 kg/hr
(40
(40
(40
(20
( o
( o
( o
(22
( o
( o
(215
( 8
(175
( o
(172
( o
(172
(172
(172
( o
(172
- 250 scfm)
- 250 scfm)
- 250 scfm)
- 120 scfm)
- 30 scfm)
- 40 Ibm/hr)
- 50 Ibm/hr)
-110 Ibm/hr)
- 326 Ibm/hr)
- 100 gpm)
- 1442 Ibm/hr)
- 40 Ibm/hr)
- 1434 Ibm/hr)
- 3 Ibm/hr)
- 1434 Ibm/hr)
- 30 gpm)
- 1434 Ibm/hr)
- 1434 Ibm/hr)
- 1434 Ibm/hr)
- 60 scfm)
- 1434 Ibm/hr)
0°C -
0°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
15°C -
150°C -
15°C -
Temperature
50
170°C
454°C
454°C
65°C
50°C
50°C
50°C
50°C
60°C
1204°C
1093°C
1204°C
1093°C
1149°C
60°C
260°C
260°C
260°C
260°C
260°C
( 30°F -
( 30°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
( 60°F -
(300°F -
( 60°F -
120°F)
340°F)
850°F)
850°F)
150°F)
120°F)
120°F)
120°F)
150°F)
140°F)
2200°F)
2000°F)
2200°F)
2000°F)
2100°F)
140°F)
500°F)
SOOT)
500T)
500T)
500T)
              See  Figure  3-3

-------
TABLE 3-4.  DESIGN POINT PRESSURE DISTRIBUTION
  Location3       kPa        Pressure (psia)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
99.90
121.95
121.95
121.95
118.51
101.28
101.28
101.28
118.51
406.51
113.00
111.62
110.24
108.86
107.48
413.4
106.80
105.42
104.04
103.35
103.35
(14.5)
(17.7)
(17.7)
(17.5)
(17.2)
(14.7)
(14.7)
(14.7)
(17.2)
(59)
(16.4)
(16.2)
(16.0)
(15.8)
(15.6)
(60)
(15.5)
(15.3)
(15.1)
(15.0)
(15.0)
     aSee Figure 3-3
                        3-8

-------
OJ
vo
                                    Figure 3-3.  FBC test rig system schematic.

-------
       The operating limitations are indicated in the following subsections.

3.1.1  Operating  Preparations and Configurations
       To accommodate a  test plan and obtain the desired operating para-
meters,  the  facility will  have to be set  up in the appropriate configuration.
The principal subsystems requiring configuration adjustments are the com-
bustor section and the flue gas cleanup system.
       Variables  that affect the combustor configuration are the coal feed-
rate, bed temperature, fluidizing velocity and bed height.  Figure 3-2 shows
the gas  mass flowrate restrictions for a  particular  combustor size for the
range of fluidizing velocities or operating temperatures.  The total gas mass
flowrate will dictate a  coal flowrate for a certain  excess air condition
(Figure  3-1).  The coal  flowrate in turn  will dictate the bed energy removal
rate and the amount of heat exchanger surface area.
       The first  component that must be selected after  the combustor cross-
sectional area has been determined is the distributor plate.  The guideline to
be followed here  is to have a pressure drop across the  plate of 0.996 to 3.98 kPa
(4 to 16 inches) of H~0 or 30 percent of  the bed pressure drop.  The pressure
drop is  influenced by the gas mass flowrate, the gas temperature and slightly by
absolute pressure.  The distributor plates provided  are perforated plates with
varying  numbers of holes per area.  Four  plates are  provided with the following
                               2        2
number of holes for the 1451 cm  (225 in  ) combustor area covering the indicated
flow ranges.   The flow capability is obviously proportional with the number of
holes.   The effect of preheat temperatures can be approximated by treating the
holes  as  orifices.  The flow through one  0.254 cm (0.100 inch) diameter hole at
21 °C (70°F)  and 101.3 kPa (14.7 psia) has been measured to correspond to 10.8 to
21.54  dm3/min (0.38 to 0.75 cfm) for the  0.996 to 3.98  kPa (4 to 16 inch) H20
pressure drop.   (See Table 3-5.)
       Select the appropriate plate and install it into the air plenum chamber.
Be sure to use a Fiberfrax or similar gasket at the  interface as shown in the
drawing to minimize side leakage.
       The next items to be determined are the number of heat exchanger tubes
required to remove the excess bed energy.   Bed energy removal is a function of
excess air, air preheat, coal  flowrate and energy/kg, facility heat loss,

                                      3-10

-------
                                      TABLE 3-5.   DISTRIBUTOR PLATE FLOW RANGE
CO
I
Plate
1

2

3

4

Holes/Plate
1935 cm2 Area
(300 1n2)
n
848

564

376

252

Holes
2
1451 cm Area
(225 in2)
n
632

420

280

160

0
Flow Range 1n dcm /m1n (cfm)
for 1451 cm2 at 15°C
(225 in2 at 70°F)
0.996 to 3.98 kPa AP
(4 1n - 16 in)
6797 - 13424
(240 - 474)
4531 - 8921
(160 - 315)
3001 - 5947
(106 - 210)
1727 - 3398
(61 - 120)

-------
 energy lost to  the offtake ash, energy lost to elutriated solids and the
 reaction of the sorbent with S02.  A good approximation, however, can be
 made by simply  considering three of these components miscellaneous and assign-
 ing 9376 watts  regardless of operating conditions.  This reduces the energy
 equation to:
        q tubes  - q coal - q air - 9376 watts

        hnAtube  {tbed " ttube) = "coalh/ '"air (tair in ' W bed* ' 9376

          .  "c ' hv - "air "air in "W bed* " 9376
                    h atube (tbed ' ttube)

 Some. of the values to be used in this equation are still not known accurately
 since only few test runs have been made,   h must be estimated to lie in the
 range of 255.6 to 368 W/m2K (Btu/ft2 - °F-hr), increasing with fluidizing
                                                             2    2
 velocity.  The area of each cooling tube is equal to 0.0403 m  (ft ) and the
 maximum t.  .   should not exceed 93°C (200°F) to prevent boiling.   Heat exchangers
 with five and seven tubes have been provided.   Some small adjustment in the heat
 transfer is possible by varying the water flowrate; however, the  principal
 temperature control of the bed rests with the coal  feedrate.  After determining
 how many cooling tubes are required to establish the appropriate  test condition,
 the heat exchangers should be installed in the desired locations.
       The  remaining ports are available to mount secondary air injection
 ports and sight or sampling ports.
       The  air injection ports provide the user with the capability to inject
air in the  desired location of the combustor or into the freeboard.  The
secondary air supply panel is very versatile and allows for the insertions
of tubes of various lengths at almost any location.
       The  view and sampling ports are also designed and constructed to pro-
 vide versatility.   Care must be exercised to use them as intended to avoid
 injury.   The panel provides access to the bed or freeboard via a  7.6 cm (3
 inch) pipe (SS 330).  This pipe can be blocked by a 7.6 (3 inch)  slide gate
 valve to maintain the view glass clear or while installing a sampling adapter.
 Low pressure purge air (34.5 kPa (5 psi)) may be applied to blow  debris from
                                    3-12

-------
the port through an adapter on the side of the access pipe.  Two sizes of view
ports are provided, a 3.8 cm (1-1/2 inch) and a 7.6 cm (3 inch) peepsight.  The
The 3.8 cm (1-1/2 inch peepsight is rated at 689 kPa at 38°C (100 psi at
100°F) and 413 kPa at 204°C (60 psi at 400°F).  The large view port is rated
for 69 kPa (10 psi).   The small peepsight is intended to be used in the bed
area whereas the large unit may be used in the freeboard.
       All remaining combustor and freeboard ports must be closed by install-
ing a refractory plug and installing a cover plate.
       The configuration of the flue gas cleanup devices is prescribed by
each test.  It is anticipated that the primary cyclone will always be used
to accomplish the preliminary collection of particulates.  From the  primary
cyclone the flue gases may be routed to the secondary cyclone  via damper
control or to the flue gas heat exchanger.  The baghouse or the ESP  may be
connected to the flue gas heat exchanger in parallel or in series.   Other
control devices can be installed and connected utilizing the supplied flex-
ible ducting.  Since the flue gas ducting is  under slight  positive pressure
to expel the gas out of the stack, the configuration of the cleanup  devices
will change the pressure drop characteristics of this part of  the system.
For sampling purposes positive pressure is not desirable since the probe
entry ports would have to be sealed to reduce the hazard of high-temperature
exhaust gases.  A damper-controlled stack draft fan may be the ultimate
solution to this drawback.
       The test plan further calls for the type of coal and sorbent  to be
used in the FBC Test Rig.  These materials must be loaded  into their re-
spective feed bins.  Both the coal and sorbent must be screened for  particles
larger than .63 cm (1/4 inch).  Loading of the bins is discussed in  greater
detail in the Solids Feed System Subsection.
       Before the  system can be started,  a bed of  fine inert material mixed
with 5-10 percent  coal must be loaded  into the combustor.  The material can be
either from a previous run or  shale of the appropriate size.   It can be loaded
into the combustor in two modes.   Material can be  loaded through a sampling
port, or it can be fed pneumatically  from the third solids feed bin  when  it is
not  used to  recycle  ash from the  primary cyclone.  The second  method has  the
advantage of being able to raise  the  bed height faster during  startup.

                                      3-13

-------
Limestone should not be  used  to start the bed since it requires a great deal
of time to neutralize  it and  stabilize the reaction after startup.
       The system  is now ready for startup.

3.1.2  Startup
       After  the equipment  has been prepared, a final visual check should
be made of the system  to verify the proper test configuration and that
everything is properly installed and fastened down.  The following described
startup sequence can then begin.
       Step 1
           Close the water  system drain valve.
       Step 2
           Open the main water valves for water supply and discharge.   Note
           the differential pressure on the two local gages.  The inlet
           pressure is typically between 206 kPa (30 psi) and 276 kPa  (40 psi)
           and the discharge  pressure between 138 kPa (20 psi) and 172 kPa
           (25 psi).   A  minimum differential pressure of 41  to 69 kPa  (6 to
           10 psi) is  required for proper heat exchanger operation.
       Step 3
           Turn the coolant flow to all heat exchangers off by turning the
           three-way inlet valves to the vent position.  Observe the flow
           indicator gages on the control console for zero differential
           pressure.   (A pegged gage may indicate air in the instrument
           line —  bleed the  line if this is the case.)  The waterflow
           indication  system  responds slowly to any flow adjustments and
           adequate time must be allowed.
       Step 4
          Check  the power circuit breaker panel and insure that all breakers
          are in the  on  position  for startup.
       Step 5
          Close  the air line  valves to the solid feed system (2) and the
           ash dump valve.
                                     3-14

-------
Step 6
    Start the air compressor by placing the wall switch in the on
    position.  Observe the air line pressure on the gage mounted on
    the wall over the blower.
Step 7
    Push the power on button on the control console.
Step 8
    Open the main air valve located near the blower approximately
    one turn.
Step 9
    Start the blower by pushing the blower-on button and establish
                                        3
    a high air flowrate (5664 to  7080 dm /min (200 to 250 scfm)) by
    adjusting the main air valve.  (See Figure 3-4.)
Step 10
    Check the solid injection tube valve near the combustor to insure
    it is closed.  Turn the baghouse on.
Step 11
    Turn power to the main air temperature controllers on.  Set
    the sheath temperature controller to 815°C (1500°F) and the
    air temperature controller to 538°C (1000°F).  "Reset" the
    controllers by pushing the reset button until the blinking
    light goes out.
Step 12
    Push the heater on power button and hear the contactor close.
    Observe  the temperature rise  on the sheath temperature indicator.
Step 13
    If no or little bed material  is in the combustor, start feeding
    the material  from the small bin by the following procedure.
Step 14
    Turn the valves located on the pneumatic control panel for the
    purge air (V-112) and transport and vibrator air (V-120) on.
Step 15
    Set the  primary regulator  (PCV-118) to 620 kPa (90 psig).

                               3-15

-------
                    0
                    I
                                   10
                                   I
IS
 I
20
 I
30
 I
30
 I
                                                 "SKJ
o
100





200





300





400





500


550
               -10   0    10   20   30   40  SO   flO   70   80   90  100   110   120  130  140

                               f> * 0.048 (0.03) —
                                         ig AIR DENSITY - P IN QLDM'(LBM/FP) R
                                                         PIPE ID  10.2 CM (4.0M-)
                                                   ORIFICE DIA.
                                                  4.12 CM (1 825")
                                                                     ORIFICE OIA.
                                                                    6.03 CM (2.375")
  2.00
   1.50
   1.00
  0.75
  050
  0251—
                                                                        P - 1.6 (0.1)

                                                                        « 1.44(0.0*)

                                                                     P = 1.28 (0.08)

                                                                      > 1,12 "(0.07)
                                           3      4     56789

                                        X 100 LBS/HH FLOWRATE
                   25   30
                              40    SO   SCFM  80 90100   12S   150,175,200  250  300
                                               kg/or
                SO
                          75     100
                                           150    200
                                                             300     400   500   600
              Figure  3-4.   Main  air  flow  versus  pressure  drop.

                                                  3-16

-------
Step 16
    Set the secondary  regulator  (PCV-119) to 482 kPa (70 psig).
Step 17
    Set the purge air  regulator  to 68 to 136 kPa (10 to 20 psi) and
    the rotameters to  2.8 sdm3/min (0.1 scftn) (Fl-100, Fl-101).
Step 18
    Set the ejector inlet regulator  (PCV-121) to 13.8 kPa (2 psi).
Step 19
    Open the solid injection  tube  valve near the FBC.
Step 20
    Set the ejector air supply regulator (PCV-120) to the required
    pressure for the needed pressure rise across the ejector.
    See Figure 2-16.
Step 21
    Set the bin vibrator air  supply  regulator (PCV-117) to ss344 kPa
    (si50 psig).
Step 22
    Note the loadcell  readout in the small bin position.  Turn the
    potentiometer to zero and turn the solids feedrate for the
    vibrator on.  Increase the solids flow and observe the feeding
    through the sight  glass.
Step 23
    Stop the feeding of solids when  the desired amount is in the
    combustor.
Step 24
    The system has been heating  up and will have reached 343 to 371 °C
    (650 to 700°F) in  1 hour  sufficient for lightoff.  If 5 to 10
    percent coal is present in the bed material, lightoff will occur
    automatically; otherwise  coal feed must be started for this to  occur.
Step 25
    Lightoff can be observed  through one of the 3.8 cm (1-1/2 inch)
    sight ports.   Be sure to  purge the sight glass  with 207  kPa (30 psi)
    purge air.

                              3-17

-------
 Step 26
     Open the air shutoff valve to the ash  dump  valve.  Set the
     upper limit on the bed level  control  gage.
 Step 27
     Include the solids feed and check the timing cycles  in the back
     of the control consoles on the bin vibrators.   Switch on only
     those vibrators required.
 Step 28
     Lightoff results in a rapid increase  in the bed temperature
     observed on the bed temperature probe indicator.  A  decrease in
     the airflow will result in faster increases in temperature as
     well as an increase in coal feed.
 Step 29
     When the bed reaches 1200°F turn on the water flow to the lowest
     heat exchanger in the bed.   Do this gradually to cool the tubes
     slowly.  Turn on the water flow to the  diplegs also.  (See Figure 3-5.)
 Step 30
     Further increase the coal  feed and turn on  the next  heat
     exchanger, etc.
 Step 31
     Check the cooler temperature  and turn  on coolers  starting from the
     top  to maintain  an outlet  temperature  of less  than 260°C (500°F).
 Step 32
     Start the sorbent feed.
Step 33
     Adjust the coal  feed and reduce the air preheat temperature to
     the  desired value.
Step  34
     If the bed was  low on startup,  allow  the bed to increase in
     height growing  into the  heat  exchanger cooling tubes.  Further
     increase  the coal  feedrate  to maintain the  temperature of the
     bed.
                                3-13

-------
     10.00

      7.50


      5.00

      3.75


kPa   2.50

      2.00
AP
      1.25

      1.00

      0.75


      0.50
     0.25
                          Orifice Flowrate vs.  Pressure Drop
                              I
0.907
Orifice
1.61" Line
                                                                                   in
                                                                                   T~



                                                                                   I
1.625"
Orifice
2.469" Line
                                     1.250"
                                     Orifice
                                     2.469" Line
                             2     3   4   5678910      20    30  40  50 60 708(90 100
                                                        Gpm
                                10
         20
                                                    40   60   80 100  150  200
                      Figure  3-5.   Coolant  flow versus pressure drop.
                                             3-19

-------
       Step  35
           Adjust  the  timing  cycle on the ash dump valve.  Timer one adjusts
           the  buzzer  before  the valve opens (0 to 5 seconds).   Timer two
           adjusts the closing  time  after the buzzer starts to operate
           (0 to 10 seconds)  and timer three adjusts the cycle time between
           actuation (minimum 6 minutes/maximum 60 minutes).
       Step  36
           Check and make final adjustments until the desired operating
           condition has  been obtained.

       Several  comments are made here to help in successfully starting the
combustion unit and minimizing  any damage.
       The heat exchangers were designed for water cooling only.  Reducing
the flow  to  the flash  point is  undesirable.  Quenching of the bed during
startup should  be  avoided by not allowing the tubes to be submerged or by
not establishing any flow in the tubes.  The energy removal capability of a
submerged exchanger is 4  to 5 times  that of one in the freeboard.  The tubes
are made  from SS 310.   The tubes should be exposed to temperatures in the 427
to 482°C  (800°  to  900°F)  range  for short periods only to prevent sensitization or
carbide precipitation  to  the grain boundary.  Higher or lower temperatures
are acceptable.
       Prolonged operation of the blower without flow should be avoided.  It
is therefore recommended  to open the main air valve at least one turn.
       The air  heater  will not  operate without a certain minimum flow.
       The ash  recycle bin may  be used to store inert material if ash feed
is not required for a  test condition.
       During startup  the pressure drop across the distributor plate will be
exceptionally high and particularly  with high preheat temperatures.  This is
normal.   Fluidization  of  the bed is  also not likely to occur until a minimum
fluidization velocity  with increasing temperature has been achieved.
       Until lightoff  has occurred it is suggested to operate the unit
adiabatically as much  as  possible -  no heat exchanger surface submerged.
The unit  should be brought on line gradually to minimize damage to the
refractory.
                                      3-20

-------
       The baghouse should be bypassed until the exhaust gas temperature is
high enough to prevent condensation (122°C (252°F)).  This is not necessary
with preheated air.
       The method suggested to start the combustion has been successfully
employed but requires many adjustments before the final operating condition
can be acquired.  Large volumes of preheated air would be required to speed
up this process or to withdraw heat at the same time via heat exchanger.
Should it not be possible to start the combustion in the outlined fashion due
to a particular test configuration, a lit butane or natural gas lance may be
inserted in the lower portion of the bed for the additional energy required.

3.1.3  Shutdown
       Shutdown of the system is extremely simple.  The only concerns rest
with the protection of the refractory components and minimizing thermal shock.
The steps to be followed are the following:
       Step 1
           Reduce the coal feed rate gradually and  reduce the temperature of
           the combustor to s;425°C (^800°F).
       Step 2
           Discontinue coal and sorbent feed.
       Step 3
           Cool the unit further with air, minimizing  thermal shock for
           refractory protection.
       Step 4
           If the heater was on, turn if off.
       Step 5
           Turn all heat exchanger coolant flows off and vent the heat
           exchangers.
       Step 6
           Turn the air supply to the dump valve off.
       Step 7
           When the combustor has cooled to 600°F,  turn the blower off.
                                      3-21

-------
        Step 8
            Adjust the ejector air supply  pressure  to zero and close the
            solids feed line valve.
        Step 9
            Turn the transport vibrator air and purge air valves to off.
        Step 10
            Turn the control console  power off.
        Step 11
            Close the main water valves and open  the drain valve.
        Step 12
            Turn the circuit breakers  on the  power  panel to off.

        Operator judgement should be  used  in  the  speed with which the system is
shut down.   Fast shutdown will  result in  higher  refractor repair requirements.
        The  facility is equipped with  a number of safety interlocks designed
either to warn the operator or to automatically  shut off subsystems.  The con-
trol  console power-off knob will  shut down all electrically controlled systems,
principally the solids feed system,  the air  preheater, the blower, the bag-
house and the ESP.  The severity of  the malfunction of course dictates the
action.   To prevent slug formation the bed will  be dumped when the air flow
is too low  for fluidization or upon  a power  failure.

3.2     COMBUSTOR OPERATION
        The  combustor itself is  primarily  a passive element although it houses
the  combustion.   Few controls are located on or  near the combustor.  The fol-
lowing paragraph will  therefore describe  the expected conditions of normal
operation of its components.

Combustor and Freeboard Sections
       The  combustion  chamber is refractory  lined  and sensitive to high-
temperature  fluctuations over short  periods  of time.  To minimize thermal
shock, one  to two hours are required  for  warmup  and cool down.  The expected
surface temperature of the combustion chamber at 900°C (1650°F) operating
combustion  temperature is 100°C (212°F).
                                       3-22

-------
       During the operation the combustor is under positive pressure.  The
extent of pressurization depends on the flowrates and the gas cleanup system
configuration.   This feature, however, requires frequent verification that
packings  and seals on the combustor are airtight.  Small leaks tend to grow
larger because  they cause high-temperature gases to pass to the combustor
shell  and cause seal erosion.

Distributor Plate
       The distributor plate pressure  drop should be approximately 30 per-
cent of the bed pressure drop.  The combustor  has been  designed to accom-
modate a maximum  122 cm  (48  inch)  bed  depth  and 0.8  kg/dm3  (50 lbm/ft3)
solids density this results  in a maximum 4.5 kPa  (18 inch h^O) pressure
drop requirement  for the distributor plate.  Solid to fluidized bed expansion
is assumed to be  ^1:2.  The operation of the  distributor plate must be
anticipated to allow the proper selection.   The distributor plate operates
near the bed operating  temperature and could experience two modes of failure:
plugging or breakthrough.  Both failure modes  can be detected by the change
in pressure drop  across  the  plate.  A  higher than normal pressure drop
indicates plugging  and  a lower than normal pressure  drop breakthrough.
Both failure modes  require the shutdown of the facility and correction of
the problem.
       The distributor  plate can  be operated at a lower temperature  by
introducing a  layer of  large inert pebbles  (0.95 cm  (3/8 inch) in  diameter)
into the bed.  This  layer of pebbles  (2.5  to 7.5 cm  (1  to  3  inches)  thick)
acts as  an effective insulation layer  in which little combustion takes place.
This may be a  desirable  mode of operation  for  some high-temperature  tests.
Rapid  corrosion  rates have been witnessed  for  material  temperatures  above
900°C  (1650°F) resulting in  damage to  the  distributor at other facilities.
Heat Exchangers
       Two  types  of heat exchangers  are provided for the combustion  section  --
five and seven tube modules.   The heat exchangers can be inserted  in the
desired  location  of the bed.   The design  requires that  they  be operated  in
the liquid  coolant phase.   Flashing can be prevented by establishing a
minimum  heat exchanger  tube  flow  of 2.7 kg/min (6 Ibm/min).   A five-tube
bundle therefore requires  13.5 kg/min (30 Ibm/min) and  a seven-tube  bundle
 32.6  kg/min  (42  Ibm/min) minimum  flow.
                                        3-23

-------
       Each heat  exchanger outlet  is equipped with a thermocouple.   Should
the outlet temperature of a heat exchanger exceed 82°C (18Q°F),  the flowrate
should be increased.   The bulk water outlet temperature should not  exceed
60°C (140°F)  to protect the cooling tower.  An alarm light will  indicate
the overtemperature  condition and  cause the solids flow to be discontinued.
       Flowrates  to  the heat exchangers can be controlled by two control
valves across two orifices of low  and high flow capacity.  For low  flow re-
quirements the 3.8 cm (1-1/2 inch) diameter Schedule 40 line is  equipped
with a 2.30 cm (0.907 inch) diameter orifice plate.   The 6.35 cm (2-1/2 inch)
diameter Schedule 40 line is equipped with a 3.27 cm (1.250 inch) diameter
orifice.  A spare 4.13 cm (1.625 inch) diameter orifice for higher  flow
capabilities  for  a 7.5 kPa (30 inch) HoO pressure differential has  been
delivered.  Flow  characteristics are shown in Figure 3-4.  These curves
apply to the  combustor coolant flow circuits as well as the flue gas
coolant circuits.  These curves are generated from the general orifice
equation
                          =  KaYFa  /2g   (Ap) p
where
           = 0.5930  +  0.4S1
       K
       a
       Y
       Fa
       gc
       Ap
       p
       6
                    (0.0015^+ 0.012BH),rjP-
                                          D
= gravimetric  flowrate
= orifice coefficient
= orifice area
= expansion factor
- coefficient  for thermal expansion of the orifice  plate
= scaling factor
= differential pressure across the orifice
= density as a function of temperature
= diameter ratio
       Rn  = Reynolds number
                                      3-24

-------
       When  a  heat  exchanger is  mounted in the combustor  but has no estab-
 lished coolant flow it  must be vented to the drain.   This is done automatic-
 ally when  the  three-way valve is turned to close  the  flow off.  It is im-
 portant, however, to turn  the valve handle completely so  as not to block
 flow in both directions.   The drain hose to the drain header must also be
 secured and  all open drain openings plugged to prevent splashing.

 Bed Height and Temperature Sensors
       Pressure and temperature  measurements are  made in  various locations
 of the combustion and freeboard  sections.   All  thermocouples are Type K,
 whereas the  temperature switches are of the capillary type.  The pneumatic
 signal lines may plug on occasions  and may have to be cleared by purging.
 Pressure measurements are  made with magnehelic gages  that require little
 maintenance.   To insure accuracy of the measurements,  the "zeros" should be
 checked before a run.

 Sampling, View, and Secondary Air Ports
       The sampling and view ports  can be  mounted in  the  unused access ports
of the combustion or freeboard sections.   The  7.62 cm  (3  inch)  peepsights are
intended for use in  the freeboard area where the 3.81  cm  (1-1/2 inch)  units are
to be used in  the fluidized  bed  region.  Care must be  used to apply safe purge
air pressures  to these  ports  while  the slide gate valve is closed.   The large
units are rated for 69  kPa  (10 psi)  purge  air whereas  the small units  may be
used with up to 689 kPa at 38°C  (100  psi at  100°F) and 413 kPa at 204°C (60 psi
at 400°F).   A  regulator with  adjustment  capability up  to  413 kPa (60 psi),  hose,
quick connects  and shutoff valves is  provided.
       Secondary air ports are provided  that allow injection of air into the
fluidized bed  or into the  freeboard  region.  Flexible  metallic  hoses connect
to these ports  and essentially allow  the bypass of the distributor plate.
The operation  and control of the air  quantities is discussed in the section
for the air system.

 Ash Removal  System
       The bed height is controlled by removing excess quantities of bed
material through the  5.08  cm (2  inch) diameter  ash dump pipe located in the
 center of the  distributor.

                                     3-25

-------
        Bed height is measured by noting the pressure differential  between
 three known points — two  in the bed region and one in the freeboard.   The
 bed density is measured by noting the pressure differential  between  two
 points, a known distance  apart within the bed, and the bed height  by pro-
 portion to the third port.  The bed density measurement is made  and  indicated
 by gage DP1-107.  The connection of the pressure tabs should be  verified at
 the time of the test to insure reliable bed height data.
        The bed height is  indicated by Photohelic gage DPI-106.   The  Photo-
 he! ic gage controls a solenoid valve between two manually adjustable set-
 points that direct the opening or closing of the bed dump  valve.   The  upper
 setpoint needle triggers  a timing circuit that will  sound  an alarm,  open the
 valve for up to 10 seconds and limit the dumping of bed material to  once every
 6  to 60 minutes.  The duration of the alarm,  opening and closing of  the valve and
 the repeat cycle are independently variable.   This  feature allows  the  automatic
 bed height control of the fluidized bed within a very close  tolerance  band.

 3.3    AIR SYSTEM OPERATION
        The air system supplies the required  combustion  air to the  combustor
 at the various desirable locations at the desired preheat  temperature.  It is
 also possible to recirculate up to 25 percent of the flue  gas for  flue gas
 recirculation.  The prime gas mover is a Spencer turbine blower.   The  system
 is  easy to understand and operate.  The flow  is  controlled by manual valves
 at  the various strategic locations.   Flow measurements  are indicated by
 pressure  and  temperature measurements  across  orifices.  Figures 3-5, 3-6 and
 3-7  show  the  flowrates  for a number of limited cases.   The general orifice
equation  shown in  Section  3.2 should be used  to  compute the  accurate flow
measurement for the  specific desired operating condition.
       The various air  supply lines  have been  equipped with orifices of the
following indicated  sizes.   Several  plates have  been  provided for some lines
for high and low flow capabilities.
                                        3-26

-------
    250
    2.00
    1.50
                                                                                ORIFICE
                                                                           3.34 CM (1 312") DIA
 kPl
    1.00
    0.50
    025




    250


    2.00




    1.50





    100
            PIPE I.D 5.25 CM (2.067-)
      ORIFICE
2.22 CM (0.675") DIA
            ORIFICE
        3.5 CM (1.375") OIA.
kPa
            Q
    050
    0.25
                                              789                 20

                                                  X 100 LBS/HR FLOWRATE
                                              I
                         6  7  8  9 10   125  15
  20  SCFM  30
 I
40
     I    I  I   I   I     I
90   60  70  80  00 100  125
                       10    15
                                   20
                                            38
                                                       50

                                                      KG/MR
                                                                 75
                                                                        100
                                                                                  150   200
                  Figure 3-6.    Secondary  air  and  FGR  versus  pressure  drop.

                                                     3-27

-------
SCFM
sdm3/m1n

  900 -




  soo -




  700-



  600 -



  500 —




  400 -



  300 -



  200 -



  100 -



    0 —
35-



32


30






25-






20-






15-






10-






 5-
                                 AIR FLOWMETER INLET PRESSURE
                      10
                                15
                                          20
                                                             25
           1.25
                                I
                               2.5
 I
3.74
                                           I
                                          5.0
6.23
                      AIR FLOWMETEH YP
                                                               30
75
                —  calibration pressure:   620  kPa (90 psi)
                —  temperature:   26.7°C (80°F)
                                             o
 Figure  3-7.   Air flowmeter AP versus sdm /min  (scfm)

                              3-28

-------
           Measurement              " P*  ?1 ze            Ori fi ce Si ze
                                   Schedule 40             cm (in)
           Main air               10.2 cm (4")          6.03 (2.375)
           Main air               10.2 cm (4")          4.13 (1.625)
           Hue gas                5.1 cm (2")          3.33 (1.312)
           Secondary air           5.1 cm (2")          3.50 (1.375)
           Secondary air           5.1 cm (2")          2.22 (0.875)
The measured pressure differentials are  indicated on the control console by
the appropriate gages.

Startup
       Step 1
           Open the mixing chamber valve.
       Step 2
           Open the main air valve one turn.
       Step 3
           Supply power to the control console.
       Step 4
           Push the blower start button.
       Step 5
           Adjust the main flow to the desired flowrate.
       Step 6
           Set the heater controllers to the desired air temperature.
           Check the sheath temperature  controller for proper setting.
       Step 7
           Apply power to the heater  by  turning the heater power switch on.
       Step 8
           Observe the air temperature indication.  To establish a  secondary
           air flow do the following.
       Step 9
           Insure the flexible air duct  is  connected to the air port and
           open the appropriate valve slowly.  Opening the valve too far
           may result in  the  loss  of  fluidization due to the loss of head
           at the distributor plate.
                                       3-29

-------
       Step 10
           For secondary temperature control, adjust the two mixing
           valves.  If more back pressure is required, throttle the flow
           with the 10.2 on (4 inch) valve before the air plenum.
       Step 11
           Adjust  the total flow to compensate for pressure and temperature
           changes.
       Step 12
           Flue gas recirculation  is established by opening the 5.1 cm
           (2 inch) FGR  line  valve.
       Step 13
           Slowly  close  the mixing chamber 10.2 cm (4 inch) valve until  the
           desired flowrate is established through the FGR line.

Shutdown
       Turn the heater and blower  power off.
       The air system has a number of safety interlocks that protect it from
damage and furthermore require the startup sequence to be followed.  The blower
is rated  for 7080  sdm3/min (250 scfm) and a pressure rise of 34.5 kPa (5 psi)
at up to  93°C (200°F) inlet temperatures.  The blower will shut off if this
temperature is exceeded.  If  the flowrate is exceeded the blower will thermally
overload  the motor and shutdown will also occur.  To keep the blower from
surging the flow should  never be blocked completely.  This is why it was re-
commended to crack the main air valve one turn.
       The heater  is protected by  two interlocks.  Low air flow and high
heater sheath temperature will both cause the heater to cut out.
       The interlock sensors  should be checked periodically to insure that
they indeed supply the expected protection.  Adjustments requirements are
discussed in the component literature.
       Service of  the air system components is minimal.  The blower needs to
be lubricated periodically as outlined in the Spencer service manual and
the Oemister screen and  inlet filter should be cleaned as required.
                                     3-30

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3.4    SOLID FEED SYSTEM
       The solid feed system has been designed and constructed to meet the
required performance characteristics listed in Table 3-6.
       Section 3.4.1 describes safety considerations, bin loading, startup,
steady-state operation, shutdown and bin unloading.  Calibration and setup
of the load cells, flowmeters, feeders, relief valves and timer is discussed
in Section 3.4.2.

3.4.1  Safety Considerations
       The safety precautions necessary to operate the solid feed system
are minimal and straightforward.
       The most important safety precaution is to verify the operation and
adjustment of the two pressure relief valves.  Adjustment of these valves is
covered in Section 3.4.2.
       Another necessary safety precaution is to insure that everything is
tight and in place, insure that the plexiglass viewport has been uniformly
tightened down, and that the handrails are installed and bolted securely.

Bin Loading
       The bins can be loaded in one of two modes.  They can be loaded with
the solid feed system operating, or without.  The actual loading procedure
is identical except for one additional step if the system is operating.
       During operation of the system, it is necessary to reduce the bin pres-
sure to atmospheric pressure.  To do this it is necessary to have at least
566 sdm3/min (20 scfm) of transport (primary) air flow.  If it is necessary  to
increase the transport air flow, total combustion air can be maintained (if  de-
sired) by decreasing the fluidization or secondary air.  To reduce the bin pres-
sure to atmospheric conditions, increase supply air (with the supply air regula-
tor on the local control console) to the value shown in Figure 2-16 correspond-
ing to the existing FBC inlet pressure and to zero inlet air pressure.  Follow-
ing, reduce the inlet air flow to zero (with the inlet air regulator on the
local control console).  It may be necessary to readjust the supply air now
to achieve atmospheric pressure in the bin.
                                      3-31

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              TABLE 3-6.  SOLIDS FEED SYSTEM SPECIFICATIONS

Dust Feedrates
       Coal	    10-50 kg/hr (22 - 110 Ib/hr)
       Sorbent   	     0-25 kg/hr (0-50 Ibs/hr)
       Ash	     0-  9 kg/hr (0-20 Ibs/hr)
Particle  Size	     0.63 cm (to 1/4") (max dia)
Bin Capacity
       Coal  -	              935 dm3 (33 cu ft)
       Sorbent	              396 dm3 (14 cu ft)
       Ash	              198 dm3 ( 7 cu ft)
Run Time  (at max. flowrate)
       Coal  (at  50 kg/hr) - - 15 hrs.  - assumes:  0.80 kg/dm3 (50 lbs/ft3)
       Sorbent	21 hrs.  - assumes:  1.2  kg/dm3 (75 lbs/ft3)
       Ash	12 hrs.  - assumes:  0.56 kg/dm3 (35 lbs/ft3)
Air Flowrate	           to 906 sdm /min (32 scfm)
       Air/Fuel  Ratio	from 1.25 kg (Ib) air/kg (Ib) solids
                                  3-32

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Example:  Given the following conditions —
       t   FBC inlet pressure            - 11.2 kPa (45 in WG)
       0   Air supply pressure           -68.9 kPag (10 psig)
       •   Inlet supply pressure         - 34.5 kPag (5 psig)
This would correspond to approximately 396 sdm3/min (14 scfm) air flowrate  and
9.2 kPa (+37 inch WG) bin pressure.  To load the bins, it is necessary to in-
                                  o
crease the air flowrate to 736 sdm /min (26 scfm) which corresponds  to approx-
imately 503 kPa (73 psi) supply air pressure and zero inlet air.
       Actual loading details are simple.  Remove the lid(s) or cap(s), attach
the funnel and add material.  Make absolutely sure that the maximum  particle
size is not in excess of 0.64 cm (1/4 inch) (maximum dimension).   It is easier
to screen the material before loading.  Replace lid(s) or cap(s)  and tighten
uniformly.

Startup
       Using Figure 2-16, pick a set of air inlet and supply pressures that
satisfy the air flowrate requirement.  It is usually to advantage to run as
much inlet air as possible, but some supply air should be used to avoid get-
ting dust into that section of tubing.
       •   With the FBC inlet valve closed, turn on the air and set  the
           desired inlet and supply pressures (on the local control  console).
       •   As the bin pressure reaches 12.45 to 14.94 kPa (50 to  60  inch WG),
           open the FBC inlet valve
       •   Set the purge air (on the local control console) to  approximately
           2.8 sdm3/min (0.1 scfm)
       •   Set each solids feedrate to the desired level.  Refer  to  Section
           3.4.2 for calibration procedures.
       •   Turn on flyash vibrators.  Also turn on coal and sorbent  vibrators
           if either bin is near empty.
       •   Recheck and fine-tune the air flowrate using Figure  3-7 and the
           flowmeter gages on the remote control  console.
                                       3-33

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       •   Fine-tune the solids feedrate by monitoring the loadcell readout
           of each.  The potentiometers have been equipped with a range
           control that can be adjusted from the back.

Steady-State Operation
       Duties required for steady-state operation are minimal.  They are:
       •   Solids  feedrate adjustment and monitoring - feedrate 1s computed
           by noting the change in loadcell reading over a known time span.
           However, it must be noted that the vibrators, or changes in bin
           pressure, may have a slight effect on the loadcell reading.  It
           is best (most accurate) to take readings at an arbitrary condition,
           e.g., take reading with the vibrators on, and with a bin pressure
           of 7.5  kPa (+30 inch WG).   It is possible to maintain a given bin
           pressure while changing air flowrate or FBC bed height by changing
           the  ratio of inlet air pressure to supply air pressure.  Consult
           Figure  2-16 for this information.
       •   Air  flowrate adjustment and monitoring — air flowrate is computed
           from flowmeter inlet pressure and differential pressure informa-
           tion (from the remote control console), and the flowmeter calibra-
           tion curves shown in Figure 3-7.  Temperature corrections can be
           made by multiplying the flowrate given in the figure by the ratio
           of the  calibration temperature 26.7°C (80°F) to the actual tem-
           perature (in absolute units).
       •   Loading — three indicator lights on the remote control console
           indicate when each of the bins are getting empty.  Loading
           instructions are given in this section to assure leak-tight
           operation.
       When  the air-flow ratio (between inlet air and supply air)  is varied
it is important to maintain the air flow in the transport line (to avoid
clogging).

Bin Unloading
       To  unload the dust from each bin, it is necessary to open the unloading
port (7.6  cm (3 inch) pipe plug) at the bottom of each cone, and let the material
                                      3-34

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fall along a chute, tray, or tube into a drum or barrel.  The plug can  be
easily replaced even with the bin partially full.

Shutdown
       Shutdown of the solids feed system is accomplished in the reverse
order of startup:
       •   Turn off bin vibrators
       •   Turn off vibratory feeders
       •   Shut FBC inlet valve
       •   Shut off purge air
       •   Shut off transport air

3.4.2  Solid Feed System Calibration and Setup
       This section covers the adjustment and/or calibration of all of the
applicable devices in the solids feed system.  Some devices like the flow-
meter and the loadcells need to be (or have been) calibrated only once.
Others like the feeders and vibrator timers change their characteristics
with any material change, and may have to be readjusted or recalibrated.
The pressure relief valve should be checked periodically and readjusted if
necessary.

Loadcells
       Raw output from the loadcell is conditioned by an Action-Pak Model
AP 4051 signal conditioner (located in the back of the control console).   The
Action-Pak unit is equipped with an adjustable span and zero.  This conve-
niently makes it possible to subtract the weight of the empty bin from the
total weight and indicate only the material.
       •   Set the zero value with each bin completely empty (with the lids
           and lid bolts on).  Make sure that the internal gage pressure  in
           the bin is zero, as this has a slight effect on the reading.  If
           the bin weight cannot be completely eliminated because the zero
           adjustment is not sufficient, choose a value of 100, 1000, or
           some other convenient number.
                                        3-35

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        •   To set the span, add a  known  weight of dust  to  each bin and ad-
            just the span to read this  value.   It Is  possible  that the span
            adjustment will  not have  the  range to reach  the required value.
            For this case It is necessary to increase or decrease the amount
            of excitation of the signal conditioner.   This  adjustment is also
            on the Action-Pak module.   If the excitation is changed, it is
            necessary to repeat the zeroing procedure above.
        The loadcell readout can be calibrated in virtually any units.  It
must be noted, however, that the decimal  point is not shown.  For example,
a  flyash readout of 1456 is actually 145.6 Ibs.   The coal  and sorbent, how-
ever, have the decimal at the extreme  right.
        The limit alarms, used to indicate a low bin-level  condition in any
bin, are Action-Pak Model 1020's.  These are also located  in  the back of the
control console.  The easiest way  to adjust these units is to add the amount
of material  that represents a near-empty condition,  and adjust the Action-
Pak module until the indicator light turns on.   An alternate  method is to
apply an adjustable voltage to the input of the  signal  conditioner to repre-
sent a loadcell  output.
        Recommended level alarms are:
        •   Coal  bin          --  50 kg (110  Ibs)
        •   Sorbent bin       --  22.6 kg  (50 Ibs)
        •   Ash bin           —  9.06 kg  (20 Ibs)
        These loads give a 1-hour warning to the  operator.

Flowmeter
        The flowmeter,  a Meriam Model  50MJ10 laminar  flow element, has been
calibrated in  its  present configuration.   The calibration was done at 620 kPa
(90  psig)  and  26°C (80°F) inlet  conditions.  The calibration curve is shown
in Figure  3-7.   Flowrates for  other inlet pressures have also been calculated
and  plotted  on the figure.
                                       3-36

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       Temperature corrections, as explained in Section 3.4.1,  can  be  made
by multiplying the value obtained in Figure 3-7 by the ratio of the calibra-
tion temperature (26.6°C (80°F)) to the actual  temperature usinq absolute
temperature units.

Feeders and Feed Nozzles
       To determine initial solids feedrate settings, it is necessary to have
at least a rough calibration of feeder performance.  Since  solids  feedrates
are dependent on material characteristics  (density, particle size distribu-
tion, etc.) it is necessary to  recalibrate it  for every change in dust
characteristics.
       Calibration of the feeders is a  simple  matter.  Feedrate is not a
function of bin pressure or air  flowrate.  The transport line can be removed
and the dust fed directly into  a bucket for subsequent weighing.
       If it should be necessary to change the characteristics of the feed-
rate curves (either because the  feeder  does not feed fast enough, or because
the feedrate control is too sensitive), some methods are:
       •   Nozzle height - the  clearance between the feed nozzle and the
           feeder tray can be  varied to increase or decrease the maximum
           solids feedrate.  The larger the clearance is, the larger the
           pile of material on  the tray will be, and hence  the higher the
           maximum feedrate will be.   However, as the pile  gets larger,
           the flow quality goes down.
       t   Nozzle gate position — nozzle gate  position has  the same effect
           on feedrate and flow  quality as nozzle position.  It has the
           additional drawback  of increasing the likelihood of clogging in
           the low position.
       •   Feeder tray inclination — as the feeder tray inclination increases,
           so does the feedrate  and flow quality.  The limiting factor is
           purely physical interference with the feed nozzle and with the
           mixing cone.  The feeder tray inclination is varied by changing the
           standoff height of  the feeder mount.  If the feeder tray inclina-
           tion is changed, insure that the standoff-box interface is airtight.
                                       3-37

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       Feeder  performance  is  optimized when the maximum design feedrate is
at roughly 90  to 95 percent actual maximum.  The nozzle gate should  be  as much
open as possible,  the  nozzle  as low as possible, and the feeder tray inclina-
tion as steep  as necessary.

Relief Valves
       To keep the bins from  ever being pressurized to more than 34.5 kPa
(5 psig), two redundant pressure relief valves are included in the solids
feed system.
       The  pressure relief valves are adjustable within certain limits.  They
must be checked and adjusted  at frequent intervals to assure safe operation
of the system.
       The  relief  pressure is set by adjusting the preload on the spring in-
side the  valve; higher preload results in a higher relief pressure.
       The  following steps outline the procedure used in setting the relief
pressure.
       Step 1
            Set the spring  preload to the minimum value.
       Step 2
            Pressurize  the  relief valve, and note the relief pressure.
       Step 3
            If the  relief pressure is less than the desired value, increase
            the spring  preload by a small amount.  Repeat Steps 2 and 3 until
            the relief  pressure is at the desired level.

Vibrator  Timers
       The  vibrator timers are located in the back of the control console.
They are  adjustable for both  on-time and off-time.  Suggested setpoints are
given in  Table 3-7 but, because dust-flow characteristics are so variable,
the final setpoints must be determined by experience.
                                        3-38

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             TABLE 3-7.  SUGGESTED  VIBRATOR TIMER SETPOINTS
On Time (seconds) Off Time
Coal Bin
(Cone Vibrator)
Sorbent Bin
(Cone Vibrator)
Ash Bin
(Cone Vibrator)
(Down -Comer
Vibrator)
30*
30*
10
10
3
3
5
20
Coal and sorbent should have to be  turned on only when the bins are nearly
empty.
                                     3-39

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        Vibrator tinting should be set to run as little as possible while
continuing to give satisfactory performance.  There are two reasons for this:
first,  it  will  minimize the air consumption, and second, it will also
minimize the chance of packing or segregating of any of the materials.

3.5     GAS CLEANUP SYSTEM OPERATION
        The gas cleanup system can be classified into two sections.  The high-
temperature sections employ two cyclones for particulate control and the
low- (260°C (500°F)J temperature cleanup section a baghouse and an electro-
static  precipitator.   Operation of these devices is outlined in the following
subsections.

Primary Cyclone
        The primary cyclone is a rather passive element once the basic con-
figuration has been established.  This particular unit is equipped with a
SS 310  outlet tube insert that may be changed to slightly alter its per-
formance characteristics  and pressure drops.
        The dipleg is equipped with a water jacket that can be utilized
should  the amount of solids collected require active energy removal.  A
manual  valve controls the flow to this jacket.  Care must be exercised to
prevent condensation in  the dipleg and cause problems such as plugging due
to wet  parti cul ate.
        The ash container  can be isolated by a slide-gate valve and emptied
during  operation.

"Tornado"  Cyclone
        The secondary cyclone differs from the primary cyclone in its con-
struction  and  has  a  reported higher collection efficiency for fine particu-
lates.  The  body  of  the cyclone, rather than being refractory lined, is of
SS 310  and externally insulated.  This construction method allows operation
to 927°C (1700°F)  unless  very high corrosion and erosion rates are acceptable.
Operations that encounter higher flue gas temperatures should bypass
this unit.   The cyclone can be bypassed by opening the main damper valve in
the flue gas duct and closing the inlets to the cyclone.

                                      3-40

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       To operate the unit, flow adjustments have to be made to cause the
pressure drop between the secondary inlet and outlet duct to be 2.25 kPa
(9 inch H20)  differential pressure.  This establishes the required vortex in
the cyclone.   The remaining flow is then introduced into the primary inlet.
       The pressure and temperature measurements are indicated on the con-
trol console.
       The dipleg configuration and service requirement are the same as
those for the primary cyclone.

Electrostatic Precipitator
       The service and operation requirements of the electrostatic pre-
cipitator are minimal.  To operate the  unit the inlet and outlet duct has
to be connected and power applied  to the unit from  the control unit.
       The plates of the ESP should be  inspected after each run to insure that
they are clean and the bottom trap should be emptied.

Baghouse
       The baghouse, a Young Model VM42-16, also requires very little service
and operating expertise.  The hoses have to be connected and power and air
have to be supplied.
                                                                 •3
       The dust collected in the bags is discharged into a 208 dm  (55 gallon)
drum through a slide-gate valve.  The drum can be exchanged during operation
with this feature.
       The teflon bags supplied with the unit are rated for up to 232°C  (450°F)
operation.  An overtemperature and overpressure sensor indicate and warn the
operator if the maximum ratings are exceeded so that they can be corrected.

       The equipment is further described in the manufacturer's literature.
       The flue-gas ducting can be rerouted to permit the reconfiguration of
the facility to meet the needs of  the test program.
                                       3-41

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3.6     FLUE-GAS HEAT EXCHANGER AND SOOT-BLOWING LANCE OPERATION
        The flue-gas heat exchanger's function 1s to  cool  the  flue gases to 149
to 204°C (300°F to 400°F).   The inlet gas  temperatures may vary substantially as
well  as the flowrates and a very high turndown ratio is  required to accomplish
this.   This flue-gas heat exchanger contains  10 heat exchanger modules that can
be individually brought on line.   The design  parallels that for the fluidized
bed  comb ustor with the exception that these heat exchanger modules always
remain mounted.  Flue gases are cooled as  they pass  through the maze of
bare tube from the top down.  The operation of the heat  exchanger requires,
therefore, that 10 heat exchangers be brought on line in sequence from the
top  until the desired exit temperature is  achieved.   The bare tube design
allows for particles to be removed from the tubes by soot blowing.  Coolant
outlet temperatures can be monitored on all modules  and  one measurement pro-
vides  a bulk outlet temperature measurement.   A second outlet temperature
sensor provides an alarm status light if the  bulk temperature rises above 60°C
(140°F).
        Coolant water flowrates are monitored  by measuring orifice differential
pressure drops in the same  fashion as for  the fluidized  bed.  Since the heat
transfer coefficients are substantially lower here than  in the bed, flashing
is not likely to be a severe problem.   Flowrates  can  therefore be kept sub-
stantially lower than in the combustor bed.   Each tube has a  heat transfer
                2         2
area of 0.060 m  (0.64 ft ).   The  top  base modules have  five  heat transfer tubes
whereas the remaining eight  have nine  tubes.   Due  to  the  highly varying flue gas
flowrates the outside heat  transfer varies  substantially.  A  1.8 kg/tube
(four-Ibm/tube) flowrate appears  to be sufficient to  limit the temperature rise
to acceptable limits.  Figure 3-4  may be used to  set  the flowrates.  Verifica-
tions  of the outlet temperature will  confirm  the  requirement.
        The flue gas contains particulate in the Sp-or-less category.  Some of
this ash will  deposit on the tubes  and needs  to be cleaned off periodically.
A manually operated soot-blowing lance can be inserted above  and below the
bare tube heat exchangers.   This task  can be  done while  the unit is operating
or when it is shut down.  An air jet  is  directed  at the  tubes cleaning them
^s the  lance is moved in and out.   The dust settles in the bottom ash pan or
                                      3-42

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is carried into the baghouse or ESP.  The ash pan can only be removed after  a
run has been completed.  Large dust accumulations on the tubes would indicate
ineffective heat transfer or a rise in the flue gas cooler outlet temperature
for no other apparent reason.

3.7    EMERGENCY SHUTDOWN
       Should it ever become necessary to shut the system down due to an
emergency, the following control options exist.
       All electrical power to the system is cut off by pushing the control
console power-off button.  Coolant flow and the pneumatic transport air will
continue until shut off separately.  If the failure is not due to a heat
exchanger tube failure it will be desirable to continue the coolant flow to
reduce the system temperature as quickly as possible.
       To turn off the coolant flow and solid transport air flow close the
respective main valves.
       When the power to the system is cut off the bed will be dumped.
                                        3-43

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                                  SECTION 4
                      FBC  TEST  RIG SAMPLING AND  ANALYSIS

       This section  specifies  the sampling and  analysis techniques
recommended for application  to the subscale fluidized  bed  coal combustion
(FBC) test rig.  Many of  the techniques  and specific  equipment suggested
represent "state of  the art."   That equipment which does not  represent
state of the art, has been chosen to meet EPA's requirements  of  utility,
convenience, minimal  expense and  ease of operation. However,  all  decisions
were based on the following  criteria:
       •   Flexibility for a wide range  of operating  variables and
           equipment  configurations
       •   Accuracy
       •   Utility to minimize EPA manpower requirements
       Certain "ground rules"  were laid  down by EPA with regard  to the
sampling and analytical equipment.   First,  all  analysis (with the
exception of online  analysis instrumentation)  is  to be accomplished
offsite.  Second, online  analysis instruments are to  be strictly  limited
to those that are commonly available and straightforward in operation.
More complex measurements, such as those involving mass speetrometry or
gas chromatography,  are required  to be done offsite.
       These ground  rules have been strictly adhered  to.   Included in this
report is a tabulation of recommended analytical  labs  (Table 4-1)

                                     4-1

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               TABLE 4-1.  SAMPLING SERVICES CONTRACTORS
       Contractor
    Home Location
 Nearest Office
Acurex Corporation/
Aerotherm Division
Battelle Memorial
Institute
BETZ Environmental Eng.
George D. Clayton &
Associates
Commonwealth Laboratory,
Inc.
Engineering Science,  Inc.
Enthopy Environmentalists
Environmental Science and
Engineering
Gilbert Associates
Midwest Research Institute
Monsanto Research
Corporation
Pacific Environmental
Services
Rossnagel Associates
Scott Research Laboratory
TRW Systems Group
York Research Corporation
Mountain View, CA

Columbus, OH
Plymouth Meeting, PA
Southfield, MI

Richmond, VA
McLean, VA
RTP, NC
Gainesville, FA
Philadelphia, PA
Kansas City, MO
Dayton, OH

Santa Monica, CA
Cherry Hill, NJ
Plumbsteadville, PA
Los Angeles, CA
Stamford, CT
RTP, NC

OH

PA
MI

Greenville, SC

VA
RTP, NC
FA

PA
MO
RTP, NC

CA

GA
PA
CA
CT
                                  4-2

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including both institutional  and  private  laboratories.   Also  included
(Table 4-2) is a  list of  recommended source  sampling  companies which could
provide support for the FBC test  rig experiments.   As a  further  aid the
APCA 1976 Consultant Guide, published in  the APCA  (Air Pollution Control
Association) Journal in July  1976,  may be consulted.
       The onsite sampling and  analytical instruments chosen  are capable
of continuously monitoring such pollutants as S0?,  NO, NO  , CO,  C09,
                                                 £-        A         C.
02, low molecular weight  reduced  sulfur compounds,  and light
hydrocarbons (C^ to Cg).  Onsite  continuous  monitoring instrumentation
for the collection and analysis of  low molecular weight  reduced  sulfur
compounds (H2$, RSH, RSR, etc.) is  essential due to the  high  reactivity
of these species.  This mode  of analysis  eliminates the  transportation of
a large number of bulky samples and permits  additional sample analysis if
problem areas become apparent during initial sampling.
       The vast number of chemical  and physical  pollutant  forms  of
interest (Table 4-3 in Attachment No.  1 in the RFP) are  impractical to
consider individually.  Furthermore, many of them may be grouped and
considered as one species due to  their similarity with regard to sampling
and/or analytical technique.  Therefore,  a pollutant  species  grouping
approach has been taken in this portion of the report.   This  approach does
not, however, preclude analysis for specific components.  Table  4-4 is a
complete summary of sampling  and  analytical  methods recommended  for use
with the FBC test rig.  Figure 4-1  is  a flow diagram  of  the proposed FBC
test rig showing all sampling locations.   Table  4-5 relates the  sample
locations to their general sampling requirements.   The gaseous and
particulate sample requirements referred  to  in Table  4-4 will be
                                     4-3

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            TABLE  4-2.   POTENTIAL ANALYTICAL CONTRACTORS
                   Laboratory
    Location
Battelle Memorial  Institute
Commonwealth Laboratory, Inc.
Dow Chemical Interpreting Analytical Services
Environmental  Services Associates, Inc.
Galbraith Microanalytical Laboratories
Gilbert Associates
Gulf Energy and Environmental Systems
LFE Environmental Analysis Laboratories
Langston Laboratories
Arthur D. Little
Midwest Research Institute
Monsanto Research Corporation
Research Triangle Institute
Southern Research Institute
Southwest Research Institute
Stanford Research Institute
TRW Systems Group
Columbus, OH
Richmond, VA
Midland, MI
Burlington, MA
Knoxville, TN
Philadelphia, PA
San Diego, CA
Oakland, CA
Kansas City, MO
Boston, MA
Kansas City, MO
Dayton, OH
RTP, NC
Birmingham, AL
San Antonio, TX
Palo Alto, CA
Los Angeles, CA
                               4-4

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         TABLE 4-3.   EXAMPLE LIST OF CHEMICAL AND PHYSICAL FORMS  OF
                     POLLUTANTS OF CONCERN:  POLLUTANT CHEMICAL FORMS
Sulfur Compounds
       •   Elemental sulfur
       •   Oxidized (sulfur dioxide, sulfur trioxide, sulfites,  sulfates)
       •   Reduced (hydrogen sulfide, carbonyl sulfide, sulfides,
           disulfites)
Nitrogen Compounds
       t   Oxidized (nitric oxide, nitrogen dioxide, nitrates, nitrites)
       0   Reduced (ammonia, cyanides, cyanates, hydrazines)
Organic Compounds
       •   Hydrocarbons
           --  Aliphatics
           —  Olefins
           --  Aromatics (benzene, toluene, xylene, etc.)
           --  Polynuclear aromatic  (benzo(a)pyrene, etc.)
       •   Oxygenated Hydrocarbons
           —  Acids (acetic, benzoic, etc.)
           —  Anhydrides
           —  Ketones
           —  Epoxides
           —  Ethers
           --  Lactones
           --  Phenols (crosols, xylenols, etc.)

                                    4-5

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                TABLE 4-3.   Continued

--  Alcohols  (methyl,  etc.)
—  Peroxides
~  Polynuclear  (oxa  arenes, ring carbonyls)
—  Ozonides
—  Aldehydes  (formaldehyde, etc.)
Halogenated Hydrocarbons
—  Chloronated,  polychloronated
--  Fluorinated
Sulfur-containing Hydrocarbons
~  Mercaptans
—  Thiophenes
~  Heterocyclic/monocyclic (thio)
--  Polynuclear  (thio  arenes)
—  Alkyl sulfates
--  Sulfonic acids
—  SuIfoxides
—  Sulfones
Nitrogen-containing Hydrocarbons
—  Amines
--  Aliphatic
—  Aromatic (analines, naphthylamines,  etc.)
~  Heterocyclic  monocylcic (aziridines,  pyridiries,  pyrolles)
--  Nitro compoinds (Oimethylnitrosanrine,  etc.)
—  Polynuclear
--  Aza arenes (acradene, etc.)

                         4-6

-------
                           TABLE 4-3.   Continued

       •   Organometallics  (metal-containing hydrocarbons)
           --  Metal carbonyls
           --  Chelates
           —  Sulfonates
           —  Metal alkyls
Carbon Compounds
       t   Carbon
       •   Carbon monoxide
       t   Carbon dioxide
       •   Carbonates
Oxygen Compounds
       •   Ozone
Halogen Compounds
       •   Chlorides (HC1, etc.)
       •   Fluorides (HF, etc.)
Hydrogen Compounds
       •   Hydrogen ion (inorganic acids)
Trace Element Compounds
       •   Arsenic compounds
       •   Barium compounds
       •   Beryllium compounds
       •   Bismuth compounds
       t   Boron  compounds
       •   Cadmium compounds
       •   Chromium compounds
                                    4-7

-------
                    TABLE 4-3.  Concluded
•   Cobalt compounds
•   Copper compounds
•   Fluorine compounds
t   Gallium compounds
•   Germanium compounds
•   Lanthanum compounds
•   Lead compounds
•   Lithium compounds
•   Manganese compounds
•   Mercury compounds
•   Nickel compounds
•   Phosphorous compounds
•   Scandium compounds
•   Selenium compounds
t   Strontium compounds
•   Tin compounds
t   Vanadium compounds
•   Uranium compounds
•   Ytterbium compounds
•   Yttrium compounds
•   Zinc compounds
•   Zirconium compounds
                             4-8

-------
         COAL
         FEED
        SYSTEM
        SORBENT
         FEED
        SYSTEM
TRANSPORT
  AIR
  LOOP
                          FLUIDIZED
                            BED
                          COMBUSTOR
V.	

r	
       FLUIOIZING
       AIR LOOP
                                                              COMBUSTION PRODUCTS LOOP
                                                           PRIMARY
                                                           CYCLONE
                                   -©
                                                               FGR LOOP
                                                                                               ELECTROSTATIC
                                                                                               PRECIPITATOR
                                                                       BAGHOUSE
                                                                                                                      STACK
                                                                                                         Q-0
                                                                                                         5  I   ASH >
                                                                                                         *  '      '
                                                                                                                  o-
                                         Figure 4-1.  FBC  test  rig sampling locations.

-------
              TABLE 4-4.   SAMPLING AND ANALYTICAL METHODS SUMMARY
            Species
    Swpllng Method
         Analysis Method
Organic Compounds
   Total  light hydrocarbons
   Separate  light hydrocarbons
   
   Middle to heavy hydrocarbons
   (>C7)
NO/HOX
CO/CO,
Reduced sulfur compounds
(H2S, RSH, etc.)
SO,
Nitrates and nitrites

Sulfltes and sulfates
Reduced nitrogen compounds
(ammonia, cyanides, etc.)
Carbonates
Chlorides and fluorides

Hydrogen Ion (Inorganic acids)
Elemental sulfur
Carbon
Trace element compounds
   Arsenic
   Barium
   Beryllium
     Online analyzer

     Online analyzer

     SASS train XAD-2
       sorbent  trap
     Online analyzer
     Online analyzer
     Online analyzer

     Online analyzer
     Online analyzer
     SASS 1mp1ngers

SASS part leu late catch
     SASS Impingers

SASS partleulate catch
     SASS Impingers
     NaOH absorption
     SASS Impingers
SASS partleulate catch
SASS participate catch
     SASS  Impingers
     (quartz probe)
Flame lonlzatlon Detection
(FID)
Gas chromatography with FID

Gas chromatography -
Mass spectrometry
Cheml luminescence
Nondlsperslve Infrared
Absorption (NOIR)
Coulemetrlc tltratlon or
Gas chromatography -
Flame photometric detection
Fluorescence
Electrochemical  transducer
Calorlmetrlc or  Specific Ion
Electrode (SIE)
Co1or1metr1c or  SIE
Colorlmetrlc or  SIE

Colorimetrfc or  SIE
Colorlmetrlc or  SIE

ph meter
Spark Source Mass
Spectrometry (SSMS)
ASTM D3178
Calorlmetrlc
Atomic Absorption Spectroscopy
           (AAS)
AAS
                          T-913
                                             4-10

-------
TABLE 4-4.  Concluded
Species
Bismuth

Boron
Cadml urn
Chromium
Cobalt
Copper
Fluorine
Gallium
Germanium
Lanthanum
Lead
Lithium
Manganese
Mercury

Nickel
Phosphorous
Scandium
Selenium
Strontium
Tin
Vanadium
Uranium
Ytterbium
Yttrium
Zinc
Zirconium
Sampling Method
SASS impingers
(quartz probe)


























Analysis Method
AAS

Colorimetric
AAS
AAS
AAS
AAS
SIE
AAS
AAS
AAS
AAS
AAS
AAS
Flame! ess Atomic Absorption
Spectroscopy
AAS
AAS
AAS
Colorimetric
Colorimetric
AAS
AAS
AAS
AAS
AAS
AAS
AAS
                                            T-913
        4-n

-------
      TABLE 4-5.  SAMPLING LOCATIONS AND REQUIREMENTS
         Sampling Location
 Sampling Requirements
A — FBC coal feed
B —  FBC sorbent feed
C ~ Furnace bottom ash
D — Primary cyclone inlet
E — Primary cyclone ash
F ~ Primary cyclone outlet/
      Aerodyne cyclone inlet
G — Aerodyne cyclone ash
H — Aerodyne cyclone outlet/
      electrostatic precipitator
      inlet
I -- Electrostatic precipitator ash
J — Electrostatic precipitator
      outlet/baghouse inlet
K ~  Baghouse ash
L — Stack
         Grab
         Grab
         Grab
Gaseous and particulate
         Grab
Gaseous and particulate

         Grab
Gaseous and particulate
         Grab
Gaseous and particulate

         Grab
Gaseous, particulate,
opacity
                           4-12

-------
accomplished either by continuous  analyzers  and one or any combination of
SASS trains located throughout  the effluent  system.  The specific need
depends on the requirements of  the research  program.
Online Analysis Instrumentation
       The following general  remarks  apply to  all online sampling and
analysis monitors.
       Each pollutant species of  interest which lends itself to online
continuous monitoring,  is  capable  of  being measured with numerous
commercially available  instruments (90 or more in some cases).  In
addition, each family of  instruments  employs monitors using as many as ten
operational principles.   As an  example,  NO-NO   instruments number over
                                             ^
40.  Their principles of  operation include colorimetric, ion-selective
electrode, electrochemical cell, chemiluminescence, NDIR, nondispersive UV
and visible absorption, and absorption spectroscopy.  Naturally,
instruments vary  in price  depending on various factors such as measurement
method, reliability and durability.  In  many cases  it is necessary to
settle for less than maximum  reliability (i.e., accuracy, specificity and
sensitivity) because of limitations in time  available for inspection,
maintenance and repair  that highly reliable  instruments demand.  This is
especially true in stationary source  monitoring in  which the operating
conditions may be quite hostile.   However, this is  not anticipated to be
the case with the FBC test rig.
       Multiparameter capabilities are becoming a common attribute in
monitoring instrumentation.   Use of such instruments offer .the advantage
of lower procurement, operational  and maintenance costs compared with
using several individual monitors  each with  a  single pollutant measuring
capability.  However, due  to  the research-oriented  nature of this task, it

                                    4-13

-------
 Is  desirable to  be able to simultaneously measure  and  record  various
 pollutant  concentrations.   This  capability would enable researchers to
 observe  and  analyze relative pollutant concentration fluctuations  under
 identical  operating conditions.   Consequently,  separate instruments for
 each  pollutant species  to  be monitored are recommended.
       All recommended  monitors  require a certain  degree of sample
 conditioning in  which particles  and moisture are removed before  gases
 enter into the instrument.   In general, the system components  are:
 glass-fiber  filters internal  and  external to the sampled flue, heat-traced
 sample line, permeation drier for water removal, vacuum  source,  and
 analytical instrumentation.   Up to three monitors  could  use the  same
 conditioning unit.   Figure  4-2 details a typical system.  Table  4-6
 summarizes pertinent facts  regarding the online analyzers recommended.
       As  noted  in  Section  1, there are certain online sampling  and
 analysis instruments that are being strongly recommended  for use on the
 fluidized  bed combustor test  rig  due to their ease of operation, low cost,
 convenience  and  utility.  The pollutants measured  by these monitors are
 sulfur dioxide (S02), nitric  oxide (NO), nitrogen  dioxide (N02),
 carbon monoxide  (CO), carbon  dioxide (C02), oxygen (02),  and low
molecular  weight hydrocarbons (hydrocarbons 
-------
            Stack
      Calibration
            qases'

           Air in

        Parallel
      permeation
or refrigeration
           drier
         Air out
1
                               Probe with
                               fiberqlass cylindrical
                               tube filters
                              Heated
                              sample
                              1 ine
                               Purge valve


                               Select valve
                     Pump
                                            Vent
e




\
t

















NO-NO


SO
X


°2


— »



—*•



	

1

s .
J •


s +
J *


\ '
Electrica"
sianal
                                                      Electrical
                                                      signal
                                                                       Electrical
                                                                       signal
                                                            	\
               Figure  4-2.   Typical  analyzer conditioning  system.
                                         4-15

-------
                                           TABLE 4-6.   ONLINE POLLUTANT ANALYZERS
Pollutant
co/co2

HO/NOX
so2
°2

Total hydrocarbons
«C6)
Reduced sulfur
compounds
(H2S, RSH, RSR,
etc.)
Manufacturer
Beckman

TECO
TECO
Teledyne

Beckman

Barton ITT



Model
865

IDA
40
326A

400

342



Principle of Operation
NDIR

Cheml luminescence
UV fluorescence
Electrochemical
transducer
Flame lonlzatlon
detection
Coul metric
tltratlon


Mu It 1 parameter
Capability
CO (Hexane, CO^,
S02, NO)
MO, NOX (03)
so2
°2

THC

H2S; RSH + H2S;
H2S + RSH + RSR


Measuring
Range
0.25 ppm - 100X

0.1 - 10,000 ppm
1 - 5000 ppm
0 - 10OT

0.02 ppm - 5X

0 - 1000 ppm



Approximate
Cost $
3000 to 4000

5000
6000
1400

2000

5000



•£»
                                                                                                                   T-914

-------
Recording Sulfur Analyzer  equipped with the Barton  Model  302 Manual
Analytical Filter  is  recommended for onsite measurements  of the following
sulfur compound groups:  hydrogen sulfide;  mercaptans  and hydrogen
sulfide; and sulfides, mercaptans, and hydrogen  sulfide.   Thus, specific
determination can  be  made  of H2$, mercaptans,  sulfides, and residual
sulfur which includes sulfur dioxide.  Included  in  the approximate base
price of $5000 is  the titration  module, electronic  control modules, and
necessary accessories.   A  compatible external  recorder is available for
approximately $1100.
       If more specific  identification and  quantification of reduced
sulfur compounds is desired, an  online, multicolumn,  gas  chromatograph
would have to be used.   The  best detector for  this  purpose is  the flame
photometric type.  A  specific recommendation of  which instrument  is
preferable cannot  be  made  until  the research effort objectives are better
defined.  Low molecular  weight reduced sulfur  compounds (such  as  H?S,
COS, RSH and RSSR) demand  more complex online  sampling and analysis
instrumentation.   Anything other than online sampling and analysis is
precluded due to high reactivity.
co/co2
       Carbon monoxide  (CO)  and  carbon dioxide (CO,,)  are  best  measured
by the principle of nondispersive infrared  absorption (NDIR).  NDIR  is the
most commonly used method  with its accuracy and  dependability  well
established since  the early  1970's.  However,  NDIR  instruments are subject
to interference from  other gases, such as water  and aromatics.  The
problem is overcome by using auxiliary absorption cells or optical filters
which remove most  of  the radiation at wavelengths at  which the interfering
substances absorb.  Beckman  Instruments'  Model 865  is recommended for
                                     4-17

-------
application on the F8C test rig. This unit  is mainly  used for CO  detection
but it is also suitable for use  in measuring CCL, hexane, SO- and NO.
However, minor modifications to  the instrument become necessary for a
multiparameter capability.  The  need to have this capability cannot be
established until the research effort objectives are  better defined.
so2_
       Sulfur dioxide is best measured by Thermo Electron Corporation's
(TECO) Model 40  S02 Analyzer.  The principle of operation is based on
the fluorescent  emission of S02  molecules with ultraviolet light.  The
electromagnetic  radiation emitted is proportional to  the SO-
concentration in the gas sample.  The Model 40 is fully self-contained,
requiring no external gases or chemical for operation.  There is, however,
a requirement for a gas conditioning system which removes condensible
water and filters particulate matter.
Total Light Hydrocarbons (—Cfi)
       Flame lonization Detection (FID) has widespread acceptance as the
best method for  measurement of total light hydrocarbons (i.e., 
-------
NO.  For the  detection  of N0x (NO + N02),  conversion  of  N02  to NO  is
required.  N02  is  recorded as the difference between  the NO  and  NO
                                                                  /\
measurements.   The recommended Thermo Electron  Corporation's Model 10A NO
to N0x Chemi luminescent Analyzer, has this N02  to  NO  conversion
capability.   The unit  is self-contained and requires  only a  few  additional
items for operation.   They are:
       •   An 02 source (bottled  02 -- commercial  purity)
       •   NO calibration gas (no span or  zero  gas other than room air is
           required)
       •   A  vacuum source (~2 scfh)

       There  are a number of adequate oxygen (02)  analyzers  on the
market.  Acurex has experience with and recommends the Teledyne  Model
326A, an excellent general-purpose 02 analyzer.  The  heart of the  unit
is an 02 sensing cell.   It is an  electrochemical transducer  requiring no
attention other than periodic replacement  (approximately once each year).
Source Assessment  Sampling System
       The bulk of the  FBC test rig pollutant sampling should be done
using the Source Assessment Sampling System (SASS).   The capabilities of
this system are:
       •   Measurement  of particulate mass emission rate
       •   Particulate  sizing distribution into four  size ranges (i.e.,>
           10//m, 3f/m to lO^m, Ij/m to 3^m,  and /m)
       •   The collection of combined organic material
       •   The collection of volatile inorganic matter
       •   The collection of trace metals
                                    4-19

-------
 The  (SASS)  sampling train (Figure 4-3)  is  an  extension of Acurex's High
 Volume Stack Sampler (HVSS)  and is considered to be the state of the art
 in  source samplers.  All  of  the components in the HVSS train are found in
 the  SASS train with some  important additions;  they share the same probe,
 sample lines,  impinger system,  vacuum source,  and control  module.  The
 SASS train  has, in  addition,  particle size fractionating cyclones located
 in the filter  oven  (immediately following  the sample probe)  and an XAD-2
 sorbent trap module (Figure  4-4).   The  XAD-2  sorbent trap is a porous
 polymer resin  capable of  adsorbing a broad range of organic  species.   It
 is an integral part of the gas  treatment system  which comprises a gas
 conditioner, XAD-2  sorbent trap,  aqueous condensate collector,  and
 temperature controller.   After  adsorption  of  the organic species by the
 XAD-2 sorbent  trap,  various  organic fractions  are desorbed by pentane
 extraction  in  Soxhlet  apparatus.
        The  SASS train  will be an  indispensable research tool  in working on
 the  FBC test rig.   Measuring the  particulate  fractional  collection
 efficiencies of the various control devices can  be readily and  accurately
 performed with the  SASS by simultaneously  testing at the inlet  and outlet
 of the control  device.  In addition, from  just one test run,  data can be
 collected regarding particle mass  loadings  and size distributions, and the
 fate of both organic  and  inorganic  species  within the control  equipment.
        The  analytical methods required  for  the samples  collected in the
 SASS  train  vary greatly in complexity and  all  are required to  be done
offsite.  The  following paragraphs  deal with  those methods.   See Figure
4-5 for  the  SASS sampling and analysis  scheme.
                                    4-20

-------
                                                      25-FOOT UMBILICAL LINE
                                 OVEN WITH
                                 CYCLONE
                                 AND FILTER
            IMPINGER TRAIN
            AND ICE BATH
                                                            115V 15 AMP
                                                            POWER CORDS
— CONTROL UNIT
      25-FOOT SAMPLE HOSE
10 CFM VACUUM PUM
                                                    PUMP-CONTROL UNIT HOSE

-------
ro
CJ
                                                                                                               9
                            Figure 4-4.   Tenax module and vaporous trace element impinger train,

-------
tNJ
U1

Particulate
Matter

Source
*
Weigh in<
	
...



i — II Morgan ics S(


SASS Train | _f n P'~
Conditioner' |_ Orr^nics fr


SASS Train f 	 " A<
Impinger " ' | Inoi games Al

'* \ ] "L Ash 	 ^Inorganics se

M Extraction 	 1 Organic* ™

_j 3-10u* j 	 1

1 -3 * r
I - jy* . same as above



.
Organic Pass through SASS
Material < C^ unaffected

.,.-•> ,- - 	 „,..., F*trartion 	 	 _.
Malerla1>C6 absorber


Aliquot for
spectroscon"

,. .. , . , LC -Liquid chrom
iividual catches JR.. Infrared
r,CMS-r'as chroma to
Mass snectru
ements and
'lected anions
ysical separation into
actions LC/IH/MS
omic absorption
einents and
lected anions
vsical separation into
actions LC/IR/MS
,, . Aliquot for
rganics ^as cnroinatoqraphy
7 " 12 analysis

Oraanics Pnysica1 separation
organics 1ntQ fract1ons
12 LC/1R/GCMS

atoqraphy
•i
rjranh N
n Ss
                                      Figure 4-5.  SASS train  sampling and analysis.

-------
Partleu late Mass
       The filter collection and residue left after rinsing and drying the
"front half  (those exposed sample surfaces upstream of the filter) are
determined gravimetrically.
Particle Size Distribution
       The particulate weight from each cyclone is determined
gravimetrically.  Cumulative size distribution curves can be generated
from the cyclone and filter collections.
XAD-2 Sorbent Trap
       As a first step, the XAD-2 sorbent material is homogenized and
physically separated into two portions.  A 2-gram aliquot of one portion
is used in Parr bomb combustion over HNO^ to destroy all constituents
but inorganics.  The inorganic components, including possible trace
elements, are then determined quantitatively by spark source mass
spectrometry  (SSMS).  The remaining portion of the sorbent is extracted
with pentane  in a Soxhlet extractor.  An aliquot of this organic
extraction is analyzed for C7 - C12 hydrocarbons by gas chromatography
(GC) using a flame ionization detector (FID).  An infrared (IR) spectrum
is then obtained on the remaining organic extract.  This enables
determination of which of the eight potential organic fractions are
present in the extract.  This step saves unnecessary time spent on
analyzing for fractions that are not present.
       The separate organic fractions are divided by subjecting the
extract to various solvents which exhibit an affinity for various organic
classes.  Silica gel liquid chromatography (LC) is the  technique used  in
the separation procedure.  Further identification of specific compounds
within each fraction is performed by infrared (IR) spectrometry.  To
                                     4-26

-------
quantify compounds  identified  in  a  particular fraction, the sample is
analyzed on a gas chromatograph-mass  spectrometer  (GC-MS).
2.1    LIQUIDS AND  SOLIDS  SAMPLING  AND  ANALYSIS
Solids
       A complete and  accurate material balance of the entire FBC test rig
system demands careful  solids  sampling  of  the coal/sorbent feeds and the
ash deposits from each  control device.   The  sampling  techniques, while
straightforward, must  be  done  correctly to ensure  a homogeneous
representative sample.  Material  size,  consistency, and sample site vary
widely so one method  is not  appropriate for  all samples.
       Manual grab  sampling  is required in all  instances.  Coal  and
sorbent can be sampled by taking  four shovels from different  locations in
the storage pile and  homogenizing.   If  possible,  a better  practice
procedure is to take  a shovelful  of each feed material from the  conveying
system.  This is more  desirable than storage pile sampling due to the
tendency in piles toward  settling by particle  size and  density.  A  series
of such grab samples  should  be taken over a period of time.   In  either
case, a sample splitter should be used  to reduce  the  size  of  the sample  to
a manageable level  and to assume  that a representative  sample has been
obtained.
       Ash samples  from the  collectors  are handled in much the same
manner.  If ash hoppers are  present, representative  samples should  be
taken periodically  with either a pipe borer or  auger  sampler  across  the
width of the hopper (or in some cases,  vertically down the hopper).
       Samples collected  should be stored in airtight,  high-density
polyethylene containers until  ready for analysis.  Large  samples should  be
placed in metal containers lined with polyethylene bags.
                                     4-27

-------
       Coal, sorbent, and ash analytical methodology and equipment  is
widely available.  Coal and ash analyses and methods are listed in  Table
4-7.  Preferred  sources are Commercial Testing and Engineering in Chicago
and Bituminous Coal Research in Washington.
Opacity Measurements
       Opacity of  the stack effluent gas has value as  a relative
measurement  tool when "tuning" the FBC for the cleanest emissions
visually.  Two options are available:
       •   Using a trained certified observer to read  opacity using the
           Ringelmann technique
       0    Installation of an opacity monitor which could continuously
           read  and record smoke opacity.  Numerous and comparable
           commercial units are readily available
                                     4-28

-------
TABLE 4-7.  COAL AND  ASH ANALYSES
Stream
Coal



Coal







Coal
Ash
from
bed



Analysis
Proximate



Ultimate







Size
Sulfur


Proximate
Trace
Size
Sample Producer
ASTM 02234



ASTM 02234







ASTM 0197





ASTM D197
Prep. Producer
ASTM D2013



ASTM D2013














Analysis
Moisture
Ash
Volatile Matter
Fixed Carbon
Overall
C, H
S
N
Ash
0
Moisture
Cl
Size
S



Trace Metals
Size
Analysis Procedure
ASTM 03173
ASTM 03174
ASTM 03175
ASTM 03172
ASTM 0271
ASTM 031 78
ASTM 03177
ASTM 03179
ASTM 03174
ASTM 03176
ASTM 03173
ASTM 02361
ASTM 0197-30
ASTM 01757 or
ASTM 0271

ASTM 02795
Section
ASTM 0197-30
                                                         T-915

-------
                                SECTION 5
                       TRAINING AND ACCEPTANCE TEST

       To demonstrate the capabilities of the FBC test rig and its proper
performance within the design parameters, an acceptance test was conducted
upon completion of construction.  Some minor operational problems were
encountered that have since been corrected.
       Prior to the training and test subsystems had been inspected and
checked out to the extent practical, and the system had been operated by
several hands.  The quality of workmanship, materials, and fabrication had
been verified to insure proper operation.
Training
       A training program was conducted at the EPA's Research Triangle Park
facility in which representatives of the EPA and Acurex Corporation partici-
pated.  The facility was discussed  in detail with reference made to the
operations manual and the procedure outlined to derive a particular set of
operating conditions.  On the following two days the facility was started
up, operated for several hours and  shut down.  On the second day of
operation the assigned laboratory technician was permitted under supervision
to operate the facility and gained  sufficient confidence to operate the
facility by himself.
                                     5-1

-------
Acceptance Test
       Three tests were conducted to demonstrate
       •   Startup, steady-state, and shutdown
       •   Firing at design point
       •   The operating range
Demonstration of Startup, Steady-State Operation and Shutdown
       The facility was started up, operated and shut down as described in
Section 4 of this report.  All systems performed as expected with the
exception of the solid feed system and the automatic bed height control.
       The solid feed system pneumatic transport tube plugged several times
and the sorbent and coal feed was not steady, resulting in substantial
temperature fluctuations in the bed.  The plugging of the pneumatic trans-
port line could be traced to some large (1.5 cm dia.) pieces of sorbent that
had not been removed by screening.  The coal and sorbent also had a high
moisture content and this was the cause of the uneven feed.  Dry, screened
material placed in the bin and run the next day substantially reduced these
problems.
       The automatic bed height control gage signal lines were clogged dur-
ing the first test run and the solids dump valve could only be operated
manually.  The lines were cleaned out and proper signals were recorded on
the second day.  Due to the action of the bed, oscillations in the gage
readings required signal damping.  Signal damping, however, also resulted
in slow response of the closing of the dump valve and substantial loss in
the bed height.
       The bed height control has since been modified in its logic.   Its
new timing contoller activates an alarm when the bed reaches a preset value
                                    5-2

-------
before the valve is opened.  Closing of the valve is set by a timer 2 to 10
seconds later.  This sequence can also only be activated once every 6 to 10
minutes.
       The ash dump valve will also be opened upon a power failure in the
Wing G facility to prevent  fusing of the bed.
       An air supply line to the valve burned through when a hot piece of
sorbent sprayed on the  line.  This  line was replaced with a copper tube.
Demonstration Firing at Design Point
       Operation at a constant coal feed rate and bed temperature is
vertical to obtain meaningful data  when samples are withdrawn from the
stack or other parts of the system.
       The performance  of the FBC test rig  to operate at approximately
32 kg/hr (70 Ibs/hr) and 873°C (1600°F) was relatively satisfactory within
a +_ 17°C (25°F) temperature band.   Closer control would require the use of
an automatic temperature feedback control on the coal feedrate.
       It is noted here that the energy capacitance of the bed is small and
that small variations in the coal feedrate  (> 1%) will have  larger effects
on the temperature variation than the +_ 14°C  (+_ 25°F) fluctuations observed.
The particle size of the coal sorbent and the moisture content influence the
feedrate and energy release rate due to bulk density  variations and the
latent heat of vaporization of water.   Since these  variables are very dif-
ficult to control or even undesirable to control, effective  control can only
be achieved by controlling  the secondary effects, namely temperature in the
bed.  A dual set point  controller  lowering  or raising the voltage for the
coal feeder would accomplish this at a  relatively low cost should this
be desirable.
                                   5-3

-------
       To increase the resolution on the solid feed rate controllers
additional rheostats have also been installed to control the span.
       Further test operations to date have shown the coal feed rtae to be
accurately controllable and plugging with well screened material to be no
problem.
Demonstration of Operating Range
       Operation of the FBC test rig over its entire operating range within
acceptable component operating conditions is only possible by reconfiguring
the facility.  Whether the facility can achieve all of the operating con-
ditions specified can however be inferred if a judicious set of operating
variables is selected and observed.  The critical operating parameters that
needed to be observed were maximum air, coal and sorbent flowrate and the
maximum combustor temperature.  The maximum air flow capability was verified
when the system was started up to preheat the bed.  Coal and sorbent flow-
rates had been verified before testing began and the bed was operated,
although only for short durations up to 1050°C (1925°F).  Since essentially
zero flow can be achieved by all solids flows the limiting factor is the
minimum flow through the blower.  Pulsations in the blower have been
observed only below the minimum required flow to meet all specified operat-
ing conditions.
       In conclusion, the demonstration test showed that the operating
condition specified in the statement of work can all be met although not
all at the same time or in the same test rig configuration.  Minor operating
problems have been corrected.  Certain procedures must be observed to insure
stable, reliable solids feed system operation.
                                   5-4

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                                 SECTION 6
                 RAW MATERIALS SOURCES, HANDLING, AND PRICES
Coal Selection
       Since changes in coal properties have marked effects on the combus-
tion process and on pollutant emissions, and since coal properties vary sig-
nificantly from coal type, the testing of several different coals is essential
to a good test program and to the understanding of combustion in the FBC.
Important properties of interest include:
       t   Fuel nitrogen content, which is expected to have an important
           effect on FBC NO  emissions and on NO  control techniques (as it
                           ^                    ^
           does in conventional combustors)
       •   Fuel sulfur, the retention of which by bed or fuel additives is
           usually a major goal, so  that a study of the retention effective-
           ness of various additives for various coals is a primary part of
           most research programs; here it may be necessary to distinguish
           pyritic sulfur from organically bound sulfur
       0   Ash content which influences flyash amounts and ash retention
       •   Ash properties, such as fusion temperatures and chemical consti-
           tuents, which affect ash  retention and combustion properties.
       t   Other coal composition parameters, especially contents of alkali
           metals and trace metals,  and acid base ratios, which influence
           fouling and corrosion
       •   General coal properties such as rank, volatiles content and heating
           value, which influence combustion behavior and ash retention
The selection of coals, however, cannot depend only on a "scientific" interest
in the effects of property variations, particularly in a research program of
specific objectives and limited scope, since the number of properties and effects
                                       6-1

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to be studied 1s very large.  Research programs 1n the FBC facility must con-
centrate on coals of present or future Importance In the power production and
Industrial steam raising markets.  This limits choices to three generic market
types, each with reasonable restricted ranges of variation 1n properties.
       •   Appalachian Region High-Volatile Bituminous - coals in this class
           represent the single most used steam-raising coals In the United
           States and are generally regarded as the finest for conventional
           combustion techniques; substantial production Increases are expec-
           ted; this coal dominates Eastern markets.
       •   Interior Province, Eastern Region Bituminous — this coal dominates
           the Midwestern market area of the United States and 1s prominent
           in steam-raising applications.
       •   Northern Plains Province Subb1tum1nous — economically the most
           attractive Western coal with substantial reserves; It has already
           achieved large market radius; substantial production increases
           are expected; It provides a low sulfur type.
To this list we added a lignite, which has a large market potential and re-
presents an interesting h1gh-ash, low-quality limit.
       Table 6-1 briefly describes these four coals, presents the rationale
for selecting each type, and identifies individual sources of supply and coal
cost.
                                       6-2

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                                                TABLE  6-1.  SUMMARY  OF SELECTED COALS
Class
Appalachian Hlgh-
Volatlle Bltuwl-
nous



Interior Province
(High- I Medluw-
Volatlle
BUimlnous)


Mountain Province
SubbltuMlnous



Mountain Province
Lignite



Type
PUtsburg Sean
IB (high-
volatile
bituminous)


Kentucky 19
Western Kentucky




Montana Subbltu-
•Inous Power
River Region


N. Dakota
Lignite



Source
Consolidation Coal
PUtsburg. E. Reich!
V.P. Research,
(412) 288-8700


Pea body Coal Co.,
0. Shelton, Hgr.,
M. Region. St. Louts
(314) 342-3400


Peabody Coal Co.»
0. Shelton, Hgr.,
W. Region, St. Louis
(314) 342-3400

Consolidation Coal
Co.. Western Dlv.
Velva Mine, Velva
N. Dakota
(303) 534-2100
Vol
38-40





30-42





44




43




PC
50-57





45-54





46




48




Typlca
ASH
5-8





7-12





9




9




1 Propertle
HV
13.4-14K





10-12*





B.6K




6.8K




1
S
1.5-4.5





2-5





1.0




0.5




N
1.3-1.8





1.2-1.8





1.0




—




Rationale
Highest Quality U.S.
Coal; Wide Distribu-
tion and Future Ex-
panded Production,
High Sulfur, Highly
Caking
In General Similar to
Appalachian Coal;
Widely Distributed;
Especially In Midwest-
ern State; High Sulfur,
Noncaklng
Increasing Distribu-
tion; Very Abundant;
Expected to be Even
More Available. LoM
In Sulfur; Noncaklng
High Ash Content; Lou
Heating Value; Low
Sulfur; Noncaklng


I/ton*
$26.50





$25. 75





$ 9.75




$ 6.05




en
i
CO
    *Cost refers to FOB mint and Includes state sovereign tax

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Coal Transport. Pulverization, and Storage

        The four coals can be transported by rail 1n bottom dump cars from
the respective mines to Cincinnati, Ohio for grinding by H111 and Griffith,
Inc.3
       Table  6-2 shows the railroads that have offered to transport the coal
to Cincinnati, and the cost for each respective transport.  H111 and Griffith
has expressed reservations about grinding lignite with their equipment. This
problem  can be avoided by grinding this high ash content coal at Smith Facing
in Cleveland, Ohio.

                Coal Type            Grinding Company        Cost

           Pittsburgh 18              H111 and Griffith
           Kentucky 19                Cincinnati, Ohio     $65/ton
           Montana Subbltuminous      (513) 921-1075
           North Dakota Lignite       Smith Facing
                                     Cleveland, Ohio      $60/ton
                                     (216) 861-6040

       The cost includes pulverization, bagging, and palletization.  Because
grinding does not include screening of the coal, a mixture of different size
coal 1s obtained.  This mixture usually consists of:

                         4 to  6 percent  - 20 mesh
                        20 to 25 percent  - 60 mesh
                        35 to 55 percent  - 100 mesh
                        15 to 40 percent  - 200 mesh
Aerotherm experience on similar programs Indicates that the selection of the
pulverizer subcontractor 1s critical.  Very few firms are prepared to handle
research amounts of widely varying coals In the careful and scientific
manner required by a research program.  Hill and Griffith appears to represent
the best selection from a very large number of firms considered in a multi-
state region 1n the neighborhood of Raleigh-Durham and of most of the coal
supply.
                                      6-4

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                        TABLE 6-2.  COAL TRANSPORTATION COSTS FROM MINE TO CINCINNATI
i
en
Minimum Load
Tons
60
60

60

25

Coal Type
PUtsburg #8
Kentucky#9

Montana
Subb1tum1nous
North Dakota
Lignite
Railroad
Monogahela
Illinois Central
Gulf
Burlington Northern

Soo Line

Mine Location
Fa1rv1ew, W.V.A.
Ohio County, KY
Fordsvllle
Col strip, MN

Velva, NO

Total
Cost
$
585
500

3,630*

1 ,245b

             Three routes Col strip MN
                          Minneapolis
                          Chicago
Minneapolis
Chicago
Cincinnati
$35.41/ton
$14.067ton
$11.01/ton
             }C1an note = $49.80/ton

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       A screening process permits uniform derived size of the pulverized
coal, but adds significantly to pulverization costs because of time Involved
and coal wastage.  Bagged coal would be transported to Raleigh-Durham by
truck at about $36 per ton.
       The Indicated tonnage of coal supply represents nominally a 2- to
4-year supply at expected testing schedules.   If less than this turns
out to be required, a modest amount of Improvisation usually succeeds 1n
selling the excess, either to the pulverization firm or to local users.

Sorbent Selection, Pulverization, and Storage
       The following criteria Influence the choice of sorbent stone:
       •   Acceptable properties for sulfur removal
       •   Attrition resistance
       t   Trace element emission characteristics
       •   Regeneration characteristics
       •   Suitability of spent sorbent for final processing and disposal
       t   Economic availability of the stone
Fluid1zed-bed experimentation and modeling has attempted to develop
quantitative guidelines for these criteria, relating these guidelines to
properties of the stone and to combustion and heat transfer conditions 1n
the fluidlzed bed.  The results to date provide no definitive Information,
however, and give very little practical guidance In stone selection.  For
sulfur capture, limestone 1s generally more effective than dolomite at 1
atmosphere, and partial or total calcining appears to be helpful In most
cases.  (For pressures greater than 1 atmosphere, calcining appears
required for limestone and very useful for dolomite 1n most, but not all,
cases.)  For the other criteria above, essentially no consistent guidance Is
available.
       For costing purposes, therefore, we select a single limestone and a
single dolomite, both of which have been extensively tested In earlier
programs:  Limestone 1359 and Dolomite 1357.  Table 6-3 gives relevant
properties.  Due to their different calcium content, each has a different

                                       6-6

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               TABLE 6-3.  TYPICAL ANALYSES OF LIMESTONES AND DOLOMITES
Component
CaO
MgO
H20 + C02
S102
FC2°3
S03
Total
Composition %
Dolomite
1337
28.9
22.9
47.4
0.5
0.2
	
99.9
U.K. Dolomite
29.3
21.5
46.3
	
	
0.1
97.2
Limestone
18
45.7
1.4
36.6
13.6
0.3

97.6
Limestone
1359
55.7
0.3
43.6
0.5
0.1
	
100.2
U.K. Limestone
55.4
0.3
43.5
0.7
0.1
_...
99.8
The sources of those materials were:

Limestone 18:  Supplied by Fuller Industries Inc., Fort Meyers, Florida.   This has been referred
to as "U.S. Limestone No. 18" or "T. 18" 1n Interim reports.

Limestone 1359;  Supplied by M. J.  Grove Lime Co., Stephens City, Virginia and prepared at the
Argonne National Laboratory.  This  has been referred to as "Argonne" limestone or "Limestone 1359"
1n Interim reports.

U.K. Limestone;  Supplied by J. Gregory & Sons, Kldsgrove, Stoke-on-Trent.

U.S. Dolomite 1337;  Supplied by Charles Pfizer 4 Co., Glbonsburg, Ohio.

U. K. Dolomite:  Supplied by Steetly (Manufacturing) Ltd., Worksop, Notts.

-------
effect on sulfur oxide retention.  Table 6-4 shows absorbent sources  with
cost of product and cost of shipping.  The dolomite sorbent, low calcium
content, can be furnished 1n three sizes.  The cost of pulverized size,
50 to 55 percent, 200 mesh has been reported In the table.   The sorbent  will
be bagged for storage and shipped to Raleigh-Durham, North  Carolina,  by
Charles Pfizer and Company.  The limestone sorbent 1s supplied by Grove
Lime Company 1n 95 percent, 100-mesh size, but transport would have to be
made 1n an enclosed truck, since the limestone Is not bagged.  Bagging the
limestone will bring the price to approximately $50/ton. Larger size lime-
stone (0.16 to 0.32 cm (1/16 to 1/8 inch)),  bagged, will  cost as  much  as
$100/ton, because it requires screening to obtain a uniform size.   Freight
cost of bulk material will be on a minimum of 20 tons transport;  therefore the
freight cost will be $400.
       Calcining or other pretreatment should be handled by EPA or the
research program contractor to assure appropriate control and characteriza-
tion.
                                     6-8

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             TABLE 6-4.   SOURCE AND COST OF SORBENT MATERIALS
    Absorbent
     Source
   Cost
Freight to N.C.
  Dolomite 1337
  Limestone 1359
Charles Pfizer & Co.
Gibsonburg, OH
(419) 637-2101
M.J. Grove L1me Co.
Stephen City, VA
(703) 869-2700
(301) 662-1181
$17.78/tona
for first
8 tons


$5.00/tonb
  -$30/ton
   $20/ton
Includes cost of bagging and pelletlzlng

 Bulk not bagged
                                      6-9

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                                 SECTION 7
                         SAMPLING SUPPORT FEATURES

       The basic purpose of the FBC test rig is to evaluate the effect of
changes in operating conditions on emissions.  To permit sampling at
significant locations, 3-inch ports are provided at the locations noted in
Figure 7-1 for the purpose elaborated in Table 7-1.
                                       7-1

-------
-•J
I
ro
               COAL
               FEED
              SYSTEM
       SOftBENT
              SORBENT
               FEED
              SYSTEM
     TRMSPMT
       AIR
       LOOT
            COMMESSOft
                                   HUlOUtO
                                      BCD
                                   CQWUSTM
                                                         ©-
FLUID1ZIN6
AIR LOOP
                                     FLUIDIZIM
                                       AIR
                                     MEHEATER
                                [     SLOMER    |
                 SILENCER
                                                                            COMBUSTION PRODUCTS LOOP
                                          
-------
        TABLE 7-1.  SAMPLING LOCATIONS AND REQUIREMENTS
      Sampling Location
 Sampling Requirements
A — Furnace coal feed
B - Furnace sorbent feed
C — Furnace bottom ash
D - Primary cyclone Inlet
E - Primary cyclone ash
F - Primary cyclone outlet/
    Aerodyne cyclone Inlet
G - Aerodyne cyclone ash
H - Aerodyne cyclone outlet/
    electrostatic precipitator
    Inlet
I - Electrostatic precipitator
J — Electrostatic precipitator
    outlet/baghouse Inlet
K - Baghouse ash
L - Stack
         Grab
         Grab
         Grab
Gaseous and parti oil ate
         Grab
Gaseous and particulate
         Grab
Gaseous and particulate

         Grab
Gaseous and particulate
         Grab
Gaseous, particulate,
opacity
                                7-3

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                                TECHNICAL REPORT DATA
                          (Please read Instructions on the reverse before completing)
 . REPORT NO.
  EPA-600/7-78-166
                             3. RECIPIENT'S ACCESSION-NO.
4. T.TLE AND SUBTITLE Design and Construction of a Fluidized-
bed Combustion Sampling and Analytical Test Rig
                             5. REPORT DATE
                              August 1978
                                                       6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)

H. Dehne
                             8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Acurex Corporation/Energy and Environmental Division
485 Clyde Avenue
Mountain View, California  94042
                             10. PROGRAM ELEMENT NO.
                             EHE623A
                             11. CONTRACT/GRANT NO.

                             68-02-2170
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Industrial Environmental Research Laboratory
Research Triangle Park, NC 27711
                             13. TYPE OF REPORT AND PERIOD COVERED
            13. TYPE OF REPORT ANC
            Final; 8/76-4/78
                             14. SPONSORING AGENCY CODE
                              EPA/600/13
is. SUPPLEMENTARY NOTES jERL-RTP project officer is John H. Wasser, Mail Drop 65, 919/
541-2476.
 . ABSTRACT
              report describes the design, construction,  and installation of a
fluidized-bed coal combustion sampling and analytical test rig in the High Bay Area
(Wing G) of EPA's Industrial Environmental Research Laboratory (IERL), Research
Triangle Park, North Carolina.  The rig,  to be used by IERL to investigate the
emission characteristics of fluidized-bed  combustors, was designed for maximum
flexibility, accuracy,  and utility. System  operating ranges  are: coal feedrate — 10 to
50 kg/hr; sorbent feedrate — zero to 25 kg/hr; excess air — 10 to 300%; bed temperature
— 750 to 1100 C; and fluidizing velocity — 1  to 5 mps.  The program included four phases:
conceptual design; final design; purchase, fabrication, and  installation; and checkout,
testing, and documentation. After installation, an acceptance test demonstrated that
the system had been completed in accordance with the approved design, and that all
equipment was properly installed and corrected to serve its intended purpose.
17.
                             KEY WORDS AND DOCUMENT ANALYSIS
                DESCRIPTORS
                                           b.lDENTIFIERS/OPEN ENDED TERMS
                                         c.  COSATI Field/Croup
Pollution
Fluidized Bed Processors
Fluidized Bed Processing
Test Equipment
Sampling
Analyzing
Coal
Pollution Control
Stationary Sources
13B
07A
13H
14B
2 ID
18. DISTRIBUTION STATEMENT

 Unlimited
                 19. SECURITY CLASS (This Report)
                 Unclassified
                        21. NO. OF PAGES
                                 156
                 20. SECURITY CLASS (This page)
                 Unclassified
                                         22. PRICE
EPA Form 2220-1 (9-73)
                                      7-4

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