United States Office of Solid Waste
Environmental Protection (5301)
Agency Washington, DC 20460 November 1993
Solid Waste __
&EPA Notification of Regulated Waste Activity
EPA Form 8700-12 (Rev. 11/30/93) Previous editions are obsolete.
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United States Environmental Protection Agency
Washington, D.C. 20460
Notification off Regulated Waste Activity
Forms and Instructions
TJhis package is designed to help you determine if you are subject to the
regulations under the Resource Conservation and Recovery Act (RCRA)
and, if so% to help you notify EPA or your authorized State of your
regulated waste activities and get a U.S. EPA Identification Number.
RCRA is a Federal law. If yqu are regulated but do not comply with the
RCRA notification requirements, you may be subject to civil penalties.
The following materials are contained in the indicated sections of this
booklet
I. Guidance on how to determine if you handle a hazardous waste
that is regulated under RCRA;
II. Guidance on how to determine if your waste activities are regulated
under U.S. EPA's Waste-As-Fuel provisions;
III. Guidance on how to determine if you must notify EPA of your used
t)il recycling activities;
IV. Guidance on how to file the Notification Form and a list of
contacts, alphabetized by State, where you can get information,
obtain more forms, and send your completed form;
V. Two copies of EPA Form 8700-12: "Notification of Regulated Waste
Activity" and complete line by line instructions for filling out the
Notification form;
VI. A list of definitions to help in understanding and completing the
Notification Form;
Pagel
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Notification of Regulated Waste Activity
VII. Guidance on EPA hazardous waste numbers for waste streams
commonly generated by small quantity generators, Appendix 1:
"Typical Waste Streams Produced by Small Quantity Generators"
and Appendix 2: "Typical Waste Streams and EPA Hazardous
Waste Numbers;" and
VIII. A reprint of Part 261 (July 1, 1993) from Title 40 of the Code of
Federal Regulations (CFR). This document contains the regulations
that U.S. EPA has developed, identifying and listing hazardous
waste.
To obtain a copy of 40 CFR Part 266 which discusses the waste-as-fuel
administrative standards, contact your EPA Regional Office listed later in
this package, or call the RCRA/Superfund Industry Assistance Hotline
at 1-800-424-9346 (or in the Washington, D.C. area at (703) 412-9810).
After your completed notification is received, you will be sent a written
acknowledgment that will include your U.S. EPA Identification Number.
You must use this number on all communications with U.S. EPA
regarding your activities.
It is important for you to understand that this package only addresses
the requirements of the Federal hazardous waste and used oil programs.
Many States may have requirements that are different from the Federal
requirements; those States may use this form or a similar form which
may require additional information not required on this form. It is up to
you, as the waste handler, to learn about all the requirements that affect
you.
Finally, we know that understanding these regulations and how they
affect your business is not an easy job. In Section IV of the instructions,
we have listed the addresses and phone numbers of the contacts for
each State who can answer your questions and help you understand the
Federal and State regulations that apply to you. In addition to those
contacts, the following contacts are also available to help with your
questions:
A. RCRA/Superfund Industry Assistance Hotline -- 1-800-424-9346
(If you are located in the Washington, D.C. area call (703)
412-9810)
B. EPA Small Business Ombudsman Hotline - 1-800-368-5888
C. Your Trade Association
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Notification of Regulated Waste Activity
I. How to Determine if You Handle a
Regulated Hazardous Waste
Persons who generate, transport, treat, store, or dispose of solid wastes
are responsible for determining if their solid waste is a hazardous waste
regulated under the Resource Conservation and Recovery Act (hereafter
referred to as RCRA). In addition, persons who recycle secondary
materials must also determine whether those materials are solid and
hazardous wastes under the provisions of RCRA. If you need help
making this determination after reading these instructions, contact the
addressee listed for your State in Section IV. C. of these instructions.
You will need to refer to Title 40, Part 261 of the Code of Federal
Regulations (hereafter referred to as CFR) to help you decide if the waste
you handle is regulated under RCRA.1 Section VIII is a reprint of 40
CFR Part 261. To determine if you are regulated under RCRA, ask
yourself the following questions:
A. Do I Handle A Solid Waste?
40 CFR 261.2 defines "solid waste" as any discarded material that is not
excluded under Section 261.4(a) or that is not excluded by variance
granted under Sections 260.30 and 260.31. A discarded material is any
material which is:
1. abandoned, as explained in §261.2(b); or
2. recycled, as explained in §261.2(c); or
3. considered inherently waste-like as explained in §261.(c).
B. Has My Solid Waste Been Excluded From The Regulations Under
Section 261.4?
The list of general exclusions can be found in 40 CFR 261.4. If the solid
waste that you handle has been excluded, either by rule or special
variance, then you do not need to notify U.S. EPA for that waste.
1 Many States have requirements that vary from the Federal regulations. These
State regulations may be more strict than the Federal requirements by identifying
additional wastes as hazardous, or may not yet include all wastes currently regulated
under RCRA. It is your responsibility to comply with all regulations that apply to you.
For more information on State requirements, you are strongly urged to contact the
appropriate addressee listed for your State in Section IV of these instructions.
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Notification of Regulated Waste Activity
If your solid waste was not excluded from regulation, you need to
determine if it is a hazardous waste that U.S. EPA regulates. The U.S.
EPA regulates hazardous waste two ways:
1. by specifically listing the waste and assigning it a unique EPA
Waste Code Number; or
2. by regulating it because it possesses any of four hazardous
characteristics and assigning it a generic EPA Waste Code Number.
C. Is My Solid Waste Specifically Listed as a Hazardous Waste?
Sections 261.31 -- 261.33 of 40 CFR identify certain solid wastes that
U.S. EPA has specifically listed as hazardous. Persons who handle listed
hazardous waste are subject to regulation and must notify U.S. EPA of
their activities unless they are exempted as discussed below. Refer to
this section of the CFR (enclosed as Section VIII) to see if your waste is
included as a "listed waste."
D. Does My Solid Waste Possess a Hazardous Characteristic?
Even if your waste is not specifically listed as a hazardous waste, it may
still be hazardous because it exhibits certain hazardous characteristics.
These characteristics are:
1. Ignitability;
2. Corrosivity;
3. Reactivity; and
4. Toxicity.
Sections 261.20 through 261.24 of 40 CFR explain what each of the
characteristics is and outlines the testing procedures you should use to
determine if your waste meets these characteristics. Persons who handle
characteristic waste that is regulated must notify U.S. EPA of their
activities unless they are exempted, as discussed below. If you are
handling a newly regulated waste and have already notified EPA prior to
that activity and already have an EPA Identification Number, no
re-notification is required.
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Notification of Regulated Waste Activity
E. Has My Hazardous Waste Been Exempted From The Regulations
The list of exemptions can be found in 261.5 and 261.6(a)(3) of 40 CFR.
If the hazardous waste that you handle has been exempted, then you do
not need to notify U.S. EPA for that waste.
II. How To Determine if You Must Notify U.S. EPA of
Your Waste-as-Fuel Activities
Persons who market or burn hazardous waste (and any material
produced from or otherwise containing hazardous waste) for energy
recovery are required to notify U.S. EPA (or their State agency if the
State is authorized to operate its own hazardous waste program) and
obtain a U.S. EPA Identification Number unless they are exempt as
outlined below (see Subpart H of 40 CFR Part 266). Hazardous waste is
considered to be burned for energy recovery if it is burned in a boiler or
industrial furnace that is not regulated as a hazardous waste incinerator
under Subpart O of 40 CFR Parts 264 or 265.
Even if you have previously notified U.S. EPA of hazardous waste
activities and have a U.S. EPA Identification Number, you must renotify
to identify your waste-as-fuel activities. (You do not have to renotify for
those activities you previously notified for, only for any newly regulated
activities.) If you have previously notified, be sure to complete Item I
"First or Subsequent Notification," by marking an "X" in the box for
subsequent notification. Fill in your U.S. EPA Identification Number in
the spaces provided. (Your U.S. EPA Identification Number will not
change.)
Who is exempt from hazardous waste-as-fuel notification
requirements?
1. Ordinary generators (and initial transporters): Generators (and
initial transporters who pick up hazardous waste from generators)
are not marketers subject to the notification requirement if they
do not market hazardous waste fuel directly to a burner. In
such situations, it is the recipient of that fuel who makes the
decision to market the materials as a fuel, (typically after
processing or blending), and it is the recipient who must notify.
2. Specific exemptions provided by 4O CFR 261.6: The rules
provide conditional exemptions for several specific waste-derived
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Notification of Regulated Waste Activity
fuels under 261.6(a)(3), including fuels produced by petroleum
refineries that recycle refinery hazardous waste, and coke and coal
tar derived from coal coking wastes by the iron and steel industry.
Marketers and burners of these exempted fuels are not subject to
the notification requirement.
111. How to Determine if You Must Notify U.S. EPA of
Your Used Oil Recycling Activities
Persons who transport, process, re-refine, market or burn off-
specification used oil for energy recovery are required to notify U.S. EPA
(or their State agency if the State is authorized to operate its own
hazardous waste program) and obtain a U.S. EPA Identification Number
unless they are exempt as outlined below (see 40 CFR Part 279). Used
oil is considered to be burned for energy recovery if it is burned in an
industrial furnace, boiler, or hazardous waste incinerator subject to
regulation under Subpart O of 40 CFR Parts 264 or 265.
Used oil transporters, off-specification burners, processors, re-refiners
and marketers who have not previously notified EPA of their hazardous
waste activities or notified under 40 CFR Part 266, Subpart E must
notify to identify their used oil recycling activities.
Who is exempt from used oil notification requirements?
1. Persons who burn on-specification used oil fuel: Used oil that is
to be burned for energy recovery and that meets the specification
provided under 40 CFR 279.11 is essentially exempt from the
regulations. However, the person who first claims that the used
oil meets the specification is subject to notification as a used
oil fuel marketer and certain other requirements (see 4O CFR
Part 279, Subpart H). The burner of on-specification fuel is not
required to notify.
2. Used oil generators are not subject to the notification
requirements.
3. Used oil generators operating used-oil-fired space heaters:
Persons who only burn used oil that they generate (or used oil
received from household do-it-yourselfer used oil changers) in
used-oil-fired space heaters are exempt from the notification
requirement provided that the device is vented to the outdoors and
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Notification of Regulated Waste Activity
the device is not designed to have a capacity greater than 0.5
million Btu/hour.
IV. How to File EPA Form 8700-12, "Notification of
Regulated Waste Activity"
If your waste activity is regulated under RCRA, you must notify the U.S.
EPA of your regulated waste activities and obtain a U.S. EPA
Identification Number. You can satisfy both of these requirements by
completing and signing the enclosed notification form and mailing it to
the appropriate address listed in Part C of this section.
Per the Hazardous Waste Import Regulations, 40 CFR 262.60, foreign
generators should not apply for a Federal I.D. number. These regulations
state that when filling out a U.S. manifest, you must include the name
and address of the foreign generator, and the name and address and
EPA I.D. number of the importer. Please contact the U.S. firms involved
with your shipments and determine which firm will serve as the
importer.
If this is a subsequent notification, you need to complete Items I, II, IV,
VI, VII, VIV and X and any other sections that are being added to (i.e.,
newly regulated activities) or altered (i.e., installation contact). All other
sections may be left blank.
A. How Many Forms Should I File?
A person who is subject to the hazardous waste regulations, used oil
regulations, and/or the waste-as-fuel regulations under RCRA should
submit one notification form per site or location. If you conduct
hazardous waste or used oil activities at more than one location, you
must submit a separate form for each location. (If you previously notified
for hazardous waste activities and are now notifying for waste-as-fuel
activities at the same location, you must submit a second form, but your
U.S. EPA Identification Number will remain the same).
If you only transport hazardous waste and do not generate, market,
burn, treat, store, or dispose of these wastes, you may submit one form
which covers all transportation activities your company conducts. This
form should be sent to the appropriate address (listed in Part C) that
serves the State where your company has its headquarters or principal
place of business. However, if you are a transporter who also generates,
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Notification of Regulated Waste Activity
treats, stores, or disposes of hazardous wastes, you must complete and
submit separate notification forms to cover each location.
B. Can I Request That This Information Be Kept Confidential?
All information you submit in a notification can be released to the
public, according to the Freedom of Information Act, unless it is
determined to be confidential by U.S. EPA pursuant to 40 CFR Part 2.
Since notification information is very general, the U.S. EPA believes it is
unlikely that any information in your notification could qualify to be
protected from release. However, you may make a claim of confidentiality
by printing the word "CONFIDENTIAL" on both sides of the Notification
Form and on any attachments.
EPA will take action on the confidentiality claims in accordance with 40
CFR Part 2.
C. Where Should I Send My Completed Form?
Listed alphabetically in Table 1 are the addresses and phone numbers of
the proper contacts in each State where you can get additional
information and more forms, and where you should mail your completed
forms. As shown in Table 1, U.S. EPA and many States have arranged
for the States to answer your questions and receive completed forms. In
a few instances, the workload is shared between U.S. EPA and the State,
or handled by U.S. EPA alone. To avoid delay and confusion, follow the
directions for your State very carejully.
Estimated Burden: Public reporting burden for this collection of
information is estimated to be 4.35 hours, including time for reviewing
instructions, searching existing data sources, gathering and main-
taining the data needed, and completing and reviewing the collection
of information. Send comments regarding the burden estimate or any
other aspect of this collection of information, including suggestions for
reducing this burden, to Chief, Information Policy Branch, 2136, U.S.
Environmental Protection Agency, 401 M St., S.W., Washington, D.C.
20460; and to the Paperwork Reduction Project (2050-0028), Office of
Management and Budget, Washington, D.C. 20503.
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Notification of Regulated Waste Activity
Table 1
Alphabetized State Listing of Contacts for
Obtaining and Submitting the Notification Form
Alabama
Obtain information or forms from, and mail
completed forms to:
Land Division
Alabama Department of
Environmental Management
1751 Cong. Wm. L. Dickinson Drive
Montgomery, Alabama 36130
(205) 271-7730
Alaska
Obtain information or forms from:
Department of Environmental Conservation
41 OWilloughby Avenue, Suite 105
Juneau, Alaska 99801-1795
(9O7) 465-5ISO
Mail completed forms to:
U.S. EPA Region 10
Waste Management Branch, HW-105
1200 Sixth Avenue
Seattle, Washington 98101
(206) 553-0151
American Samoa
Obtain information from:
Environmental Quality Commission
Government of American Samoa
Pago Pago, American Samoa 96799
Overseas Operator Commercial call (684)
Country Code 663-2304
Obtain forms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074
Arizona
Obtain information or forms from:
Office of Waste Programs
Arizona Department of
Environmental Quality
3033 N. Central Avenue
Phoenix, Arizona 85012
(602) 207-4108
MaiZ completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074
Arkansas
Obtain information or forms from, and mail
completed forms to:
Arkansas Department of Pollution
Control and Ecology
8001 National Drive
P.O. Box 8913
Little Rock, Arkansas 72219-8913
(501) 570-2872
California
Obtain in/brmation or forms from, and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074
Colorado
Obtain information or forms from, and mail
completed forms to:
Colorado Department of Health
4300 Cherry Creek Drive, South
HMWMD-HWC-B2
Denver, Colorado 80222-1530
(303) 692-3300
Connecticut
Obtain information or forms from, and mail
completed forms to:
Hazardous Material Management Unit
Department of Environmental Protection
State Office Building
165 Capitol Avenue
Hartford, Connecticut 06106
(203) 566-4869
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Notification of Regulated Waste Activity
Table 1 (continued)
Delaware
Obtain in/brmatton orjbrms from, and mail
completed forms to:
Delaware Department of Natural Resources
& Environmental Control
Division of Air and Waste Management
Hazardous Waste Management Branch
P.O. Box 1401, 89 Kings Highway
Dover, Delaware 19903
(302) 739-3689
(302) 739-3672
District of Columbia
Obtain in/brmatton or forms from, and mail
completed forms to:
Department of Consumer and
Regulatory Affairs
Environmental Regulation Administration
Hazardous Waste Branch
2100 Martin Luther King Jr. Ave., S.E.
Washington, D.C. 2002O
(202)404-1167
Florida
Obtain information orjbrms from, and mail
completed forms to:
Hazardous Waste Regulation Section
Department of Environmental Regulation
Twin Towers Office Building
2600 Blair Stone Road
Tallahassee, Florida 32399-2400
(904) 488-0300
Georgia
Obtain in/brmatton or forms from, and mail
completed forms to:
Land Protection Branch
Industrial and Hazardous
Waste Management Program
1154 East Tower
205 Butler Street, S.E.
Atlanta, Georgia 30334
(404) 656-7802
Guam
Obtain in/ormationjrom:
Guam Environmental Protection Agency
Harmon Plaza
Complex Unit B-107
103 Orjas Street
Harmon, Guam 96911
Obtain forms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074
Hawaii
Obtain in/ormationjTOm;
Hawaii Department of Health
Solid and Hazardous Waste Branch
Five Waterfront Plaza, Suite 250
500 Ala Moana Boulevard
Honolulu, Hawaii 96813
Obtain/orms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street H-3-4
San Francisco, California 94105
(415) 744-2074
Idaho
Obtain in/brmatton or forms from, and mail
completed forms to:
Department of Environmental Quality
1410 N. Hilton, Third Floor
Boise, Idaho 83706
(208) 334-5879
Illinois
Obtain in/brmatfon or forms from, and mail
completed forms to:
Illinois Environmental Protection Agency
Division of Land Pollution Control
2200 Churchill Road
Springfield, Illinois 62706
(217) 785-8452
Obtain in/brmation or forms from:
Indiana Department of
Environmental Management
1O5 S. Meridian Street
P.O. Box 60 15
Indianapolis, Indiana 46225
(317)232-8925
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Notification of Regulated Waste Activity
Table 1 (continued)
MaH completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. Box A3587
Chicago, IL 60690
(312) 886-4001
Iowa
Obtain information or forms from, and mail
completed forms to:
U.S. EPA Region 7
RCRA Branch
Attn: WSTM/RCRA/IOWA
726 Minnesota Avenue
Kansas City, Kansas 66101
(913) 551-7646
Kansas
Obtain information or forms from, and mail
completed forms to:
Department of Health and Environment
Attn: Hazardous Waste Section
Forbes Field, Building 740
Topeka, Kansas 66620
(913)296-1600
Kentucky
Obtain information or forms from, and mail
completed forms to:
Division of Waste Management
Department of Environmental Protection
Cabinet for Natural Resources
& Environmental Protection
Fort Boone Plaza, Bldg. #2
14 Reilly Road
Frankfort, Kentucky 40601
(502) 564-6716
Louisiana
Obtain information or forms from, and mail
completed forms to:
Louisiana Department of
Environmental Quality
Department of Solid and Hazardous Waste
P.O. Box82178
Baton Rouge, Louisiana 70884-2178
(504) 765-0332
Maine
Obtain information or forms from, and mail
completed forms to;
Bureau of Oil and
Hazardous Materials Control
Department of Environmental Protection
State House Station #17
Augusta, Maine 04333
(207) 289-2651
Maryland
Obtain information or forms from, and mail
completed forms to:
Maryland Department of the Environment
Waste Management Administration
Hazardous Waste Program
2500 Broening Highway
Baltimore, Maryland 21224
(410)631-3343
(410) 631-3344
Massachusetts
Obtain information or forms from, and mail
completed forms to:
Division of Solid and Hazardous Waste
Massachusetts Department of
Environmental Protection
One Winter Street, 5th Floor
Boston, Massachusetts 02108
(617) 292-5851
Michigan
Obtain information or forms from:
Waste Management Division
Michigan Department of Natural Resources
Box30241
Lansing, Michigan 48909
(517) 373-2730
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Notification of Regulated Waste Activity
Table 1 (continued)
Mail completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, IL 60604
(312) 886-4001
Minnesota
Obtain information or forms from:
Solid and Hazardous Waste Division
Minnesota Pollution Control Agency
520 Lafayette Road, North
St. Paul, Minnesota 55155
(612) 297-8330
Mail completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, IL 60604
(312) 886-4001
Mississippi
Obtain information or forms from, and mail
completed forms to:
Department of Environmental Quality
Attn: Jerry Banks
P.O. Box 10385
Jackson, Mississippi 39289-0385
(601) 961-5171
Missouri
Obtain information or forms from, and mail
completed forms to:
Waste Management Program
Department of Natural Resources
Jefferson Building
205 Jefferson Street (13/14 floor)
P.O. Box 176
Jefferson City, Missouri 65102
(314) 751-3176
Montana
Obtain information or forms from, and mail
completed forms to:
Solid and Hazardous Waste Bureau
Department of Health and
Environmental Sciences
Cogswell Building
Helena, Montana 59620
(406) 444-1430
Nebraska
Obtain information or forms from, and mail
completed forms to:
Hazardous Waste Management Section
Department of Environmental Quality
State House Station
P.O. Box 98922
Lincoln, Nebraska 68509-8922
(402) 471-2186
Nevada
Obtain information or forms from:
Waste Management Program
Division of Environmental Protection
The Bureau of Waste
Management Permits Branch
333 West Nye Lane
Carson City, NV 89710
(702) 687-5872
Mafl completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074
New Hampshire
Obtain information or forms from, and mail
completed forms to:
Division of Public Health Services
Office of Waste Management
Bureau of Hazardous Waste
Classification & Manifests
Department of Health and Welfare
Health and Welfare Building
6 Hazen Drive
Concord, New Hampshire 03301
(603) 271-2900
New Jersey
Obtain information from:
New Jersey Department of Environmental
Protection and Energy
Bureau of Manifests and
Information Systems
Hazardous Waste and Regulation Program
401 East State Street, CN-421
Trenton, New Jersey 08625-0421
(609) 292-8341
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Notification of Regulated Waste Activity
Table 1 (continued)
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn: RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212)264-9883
New Mexico
Obtain information and forms from:
Hazardous Waste Bureau
525 Camino De Loss Marquez
Sante Fe, New Mexico 87501
(505) 827-4358
Mail completed forms to:
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, Texas 75202-2733
(214) 655-6750
New York
Obtain information from:
New York Department of
Environmental Conservation
Solid and Hazardous Waste
Manifest Section
50 Wolfe Road
Albany, New York 12212
(518)457-6858
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn: RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212) 264-9883
North Carolina
Obtain information or forms from, and mail
completed forms to:
Solid and Hazardous Waste
Management Branch
Division of Health Services
Department of Human Resources
P.O. Box 27687
Raleigh, North Carolina 27611-7687
(919) 733-2178
North Dakota
Obtain information or forms from, and mail
completed forms to:
Division of Waste Management
Department of Health and
Consolidated Laboratories
1200 Missouri Avenue
P.O. Box 5520
Bismarck, North Dakota 58502-5520
(701) 221-5166
Northern Mariana Islands
Obtain information from:
Department of Public Health and
Environmental Services
Division of Environmental Quality
Saipan, Mariana Islands 96950
Overseas Operator: (676) 234-6984
Cable Address: Gov. NMI Saipan
Obtain forms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H:3-4
San Francisco, California 94105
(415) 744-2074
Ohio
Obtain information or forms from, and mail
completed forms to:
Ohio Environmental Protection Agency
1800 WaterMark Drive
Columbus, Ohio 43215
(614) 644-2977
Oklahoma
Obtain information or forms from:
Department of Environmental Quality
Hazardous Waste Quality
Management Service
1000 Northeast 10th Street
Oklahoma City, Oklahoma 73117-1212
(405) 271-5338
Mail completed forms to:
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, Texas 75202-2733
(214) 655-6750
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Notification of Regulated Waste Activity
Table 1 (continued)
Oregon
Obtain information or forms front, and mail
completed forms to:
Oregon Department of
Environmental Quality
Hazardous Waste Operations
811 Southwest 6th Avenue
Portland, Oregon 972O4
(503) 229-5356
Pennsylvania
Obtain information from:
Pennsylvania Department of
Environmental Resources
Bureau of Waste Management
Market Street State Office Building
400 Market Street, 14th Floor
Harrisburg, Pennsylvania 17105-8471
(717) 787-6239
Obtain forms from and mail
completed forms to:
U.S. EPA Region 3
RCRA Programs Branch
Pennsylvania Section (3 HW51)
841 Chestnut Street
Philadelphia, PA 19107
(215) 597-1230
Puerto Rico
Obtain information from:
Puerto Rico Environmental Quality Board
Land Pollution Control Area
Inspection, Monitoring and Surveillance
P.O. Box 11488
Santurce, Puerto Rico 00910-1488
(809) 722-0439
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Divison
Attn: RCRA Notifications
26 Federal Plaza. Room 505
New York, New York 1O278
(212) 264-9883
Rhode Island
Obtain information or forms from, and mail
completed forms to:
Solid Waste Management Program
Department of Environmental Management
204 Canon Building 75 Davis Street
Providence, Rhode Island 02908
(401) 277-2797
South Carolina
Obtain information or forms from, and mail
completed forms to:
Bureau of Solid and Hazardous
Waste Management
Department of Health and
Environmental Control
2600 Bull Street
Columbia, South Carolina 29201
(803) 734-5214
South Dakota
Obtain information or forms from, and mail
completed forms to:
Department of Environment and
Natural Resources
Office of Waste Management
319Coteau
c/o 500 E. Capital Avenue
Pierre, South Dakota 57501-5070
(605) 773-3153
Tennessee
Obtain information or forms from, and mail
completed forms to:
Division of Solid Waste Management
Tennessee Department of Public Health
401 Church Street
LNC Tower, 5th Floor
Nashville, Tennessee 37243"-153 5
(615) 532-0780
Texas
Obtain information or forms Jrom:
Industrial and Hazardous Waste Division
Waste Evaluation Section
P.O. Box 13087, Capitol Station
Austin, Texas 78711-3087
(512) 908-6832
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Notification of Regulated Waste Activity
Table 1 (continued)
Mai! completed forms to;
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, Texas 75202-2733
(214) 655-6750
Utah
Obtain information or forms from, and mail
completed forms to:
Division of Solid and Hazardous Waste
Department of Environmental Quality
P.O. Box 144880
Salt Lake City, Utah 84114-4880
(801) 538-6170
Vermont
Obtain information or forms from, and mail
completed forms to:
Waste Management Division
Agency of Environmental Conservation
103 South Main Street
Waterbury, Vermont 05676
(802)241-3888
Virgin Islands
Obtain information from:
Virgin Islands Department of Planning &
Natural Resources
Division of Environmental Protection
179 Altona and Welgunst
St. Thomas, Virgin Islands 00801
(809) 774-3320
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn: RCRA Notifications
26 Federal Plaza, Room 505
New York, New York 10278
(212)264-9883
Virginia
Obtain information or forms from, and mail
completed forms to:
Virginia Department of Waste Management
Monroe Building, 1 Hh Floor
101 North 14th Street
Richmond, Virginia 23219
(804) 225-3863
Washington
Obtain information or forms from, and mail
completed forms to:
Department of Ecology
P.O. Box 47658
Olympia, Washington 98504-7658
(206) 459-6316
West Virginia
Obtain information or forms from, and mail
completed forms to:
Department of Commerce, Labor and
Environmental Protection
Division of Environmental Protection
Office of Waste Management
1356 Hansford Street
Charleston, West Virginia 25301
(304) 558-5393
Wisconsin
Obtain information or forms from:
Bureau of Solid Waste
Department of Natural Resources
P.O. Box 7921
Madison, Wisconsin 53707
(608)266-1327
Mail completed farms to:
U.S. EPA Region 5
RCRA Activities
P.OBoxA3587
Chicago, IL 60690
(312) 886-4001
Wyoming
Obtain information or forms from, and mail
completed forms to:
U.S. EPA Region 8
Hazardous Waste Management Division
(8HWM-ON)
999 18th Street Suite 500
Denver, Colorado 80202-2405
(303) 294-1361
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Notification of Regulated Waste Activity
Table 2
U.S. EPA Regional Contacts for the Notification Form
U.S. EPA Region 1
RCRA Support Section
JFK Federal Building
Boston, MA 02203-2211
(617) 573-5750
Connecticut, Maine,
Massachusetts, New Hampshire,
Rhode Island, Vermont
U.S. EPA Region 2
Air and Waste Management Division
Attn: RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212)264-9883
New Jersey, New York, Puerto
Rico, Virgin Islands
U.S. EPA Region 3
RCRA Programs Branch (3 HW50)
841 Chestnut Street
Philadelphia, PA 19107
(215) 597-1230 (PA, DC)
(215) 597-3884 (VA, WV, DE, MD)
Delaware, District of Columbia,
Maryland, Pennsylvania, Virginia,
West Virginia
U.S. EPA Region 4
Hazardous Waste Management Division
RCRA Permitting Section
345 Courtland Street, NE
Atlanta, GA 30365
(404) 347-3433
Alabama. Florida, Georgia,
Kentucky, Mississippi, North
Carolina, South Carolina,
Tennessee
U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, 1L 60690
(312) 886-4001
Illinois, Indiana, Michigan,
Minnesota, Ohio, Wisconsin
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, TX 75202-2733
(214) 655-6750
Arkansas, Louisiana, New Mexico,
Oklahoma, Texas
U.S. EPA Region 7
RCRA Branch, Permitting Section
726 Minnesota Avenue
Attn: WSTIN/RCRA/PRMT
Kansas City, KS 66101
(913) 551-7654
Iowa, Kansas, Missouri, Nebraska
U.S. EPA Region 8
Hazardous Waste Management Division
999 18th Street, Suite 500
Denver, CO 80202-2405
(303) 294-1361
Colorado, Montana, North Dakota,
South Dakota, Utah, Wyoming
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street H-3-4
San Francisco, CA 94105
(415) 744-2074
Arizona, California, Hawaii,
Nevada, American Samoa, Guam,
Northern Mariana Islands
U.S. EPA Region 10
Waste Management Branch, HW-105
1200 Sixth Avenue
Seattle, WA 98101
(206) 553-0151
Alaska, Idaho, Oregon,
Washington
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Notification of Regulated Waste Activity
V. Line-by-Line Instructions for Completing EPA Form
8700-12
Type or print in black ink all items except Item X, "Signature," leaving a
blank box between words. The boxes are spaced at 1/4" intervals which
accommodate elite type (12 characters per inch). When typing, hit the
space bar twice between characters. If you print, place each character in
a box. Abbreviate if necessary to stay within the number of boxes
allowed for each Item. If you must use additional sheets, indicate clearly
the number of the Item on the form to which the information on the
separate sheet applies.
Note: When submitting a subsequent notification form, notifiers must
complete in their entirety Items I, II, IV, VI, VII, VTV and X. Other
sections that are being added to (i.e., newly regulated activities) or
altered (i.e., installation contact) must also be completed. All other
sections may be left blank.
Item I - Installations EPA ID Number:
Place an "X" in the appropriate box to indicate whether this is your first
or a subsequent notification for this site. If you have filed a previous
notification, enter the EPA Identification Number assigned to this site in
the boxes provided. Leave EPA ID Number blank if this is your first
notification for this site.
Note: When the owner of an installation changes, the new owner must
notify U.S. EPA of the change, even if the previous owner already
received a U.S. EPA Identification Number. Because the U.S. EPA ID
Number is site-specific, the new owner will keep the existing ID number.
If the installation moves to another location, the owner/operator must
notify EPA of this change. In this instance a new U.S. EPA Identification
Number will be assigned, since the installation has changed locations.
Items II and IV -- Name and Location of Installation:
Complete Items II and IV. Please note that the address you give for Item
IV, Location of Installation, must be a physical address, not a post office
box or route number.
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Notification of Regulated Waste Activity
County Code and Name: Give the county code, if known. If you do not
know the county code, enter the county name, from which EPA can
automatically generate the county code. If the county name is unknown
contact the local Post Office. To obtain a list of county codes, contact
the National Technical Information Service U.S. Department of
Commerce, Springfield, Virginia, 22161 or at (703) 487-4650. The list of.
codes is contained in the Federal Information Processing Standards
Publication (FIPS PUB) number 6-3.
Item IV - Installation Mailing Address:
Please enter the Installation Mailing Address. If the Mailing Address and
the Location of Installation (Item IV) are the same, you can print "Same"
in the box for Item IV.
Item V - Installation Contact:
Enter the name, title, and business telephone number of the person who
should be contacted regarding information submitted on this form.
Item VI - Installation Contact Address:
A. Code: If the contact address is the same as the location of
installation address listed in Item IV or the installation mailing
address listed in Item IV, place an "X" in the appropriate box to
indicate where the contact may be reached. If the location of
installation address, the installation mailing address, and the
installation contact address are all the same, mark the "Location"
box. If the contact address is not the same as those addresses in
either Item III or IV, place an "X" in the "Other" box and complete
Item VLB. If an "X" is entered in either the location or mailing box,
Item VLB. should be left blank.
B. Address: Enter the contact address only if the contact address is
different from either the location of installation address (Item IV) or
the installation mailing address (Item IV), and if Item VI.A. was
marked "Other."
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Notification of Regulated Waste Activity
Item VII - Ownership:
A. Name: Enter the name of the legal owner(s) of the installation,
including the property owner. Also enter the address and phone
number where this individual can be reached. Use the comment
section in XI or additional sheets if necessary to list more than one
owner.
B. Land Type: Using the codes listed below, indicate in VII.B. the
code which best describes the current legal status of the land on
which the installation is located:
F = Federal
S = State
1 = Indian
P = Private
C = County
M = Municipal*
D = District
O = Other
*Note: If the Owner Type is best described as Indian, County or
District, please use those codes. Otherwise, use Municipal
C. Owner Type: Using the codes listed below, indicate in VII. C. the
code which best describes the legal status of the current owner of
the installation:
F = Federal
S = State
I = Indian
P = Private
C = County
M = Municipal*
D = District
O = Other
*Note: If the Owner Type is best described as Indian, County or
District, please use those codes. Otherwise, use Municipal
D. Change of Owner Indicator: (If this is your installations jirst
notification, leave Item VII. D. blank and skip to Item VIII. If this is a
subsequent notification, complete Item VII.D. as directed below.)
If the owner of this installation has changed since the installation's
original notification, place an "X" in the box marked "Yes" and enter
the date the owner changed.
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Notification of Regulated Waste Activity
If the owner of this installation has not changed since the
installation's original notification, place an "X" in the box marked
"No" and skip to Item VIII.
If an additional owner(s) has been added or replaced since the
installation's original notification, place an "X" in the box marked
"Yes." Use the comment section in XI to list any additional owners,
the dates they became owners, and which owner(s) (if any) they
replaced. If necessary attach a separate sheet of paper.
Item VIII - Type of Regulated Waste Activity:
A. Hazardous Waste Activity: Mark an "X" in the appropriate box(es)
to show which hazardous waste activities are going on at this
installation.
1. Generator: If you generate a hazardous waste that is identified
by characteristic or listed in 40 CFR Part 261, mark an "X" in
the appropriate box for the quantity of non-acutely hazardous
waste that is generated per calendar month. If you generate
acutely hazardous waste please refer to 40 CFR Part 262 for
further information.
2. Transporter: If you transport hazardous waste, indicate if it is
your own waste, for commercial purposes, or mark both boxes
if both classifications apply. Mark an "X" in each appropriate
box to indicate the method(s) of transportation you use.
Transporters do not have to complete Item IX of this form, but
must sign the certification in Item X. The Federal regulations
for hazardous waste transporters are found in 40 CFR
Part 263.
3. Treater/Storer/Disposer: If you treat, store or dispose of
regulated hazardous waste, then mark an "X" in this box. You
are reminded to contact the appropriate addressee listed for
your State in Section III.C. of this package to request Part A of
the RCRA Permit Application. The Federal regulations for
hazardous waste installation owners/operators are found in 40
CFR Parts 264 and 265.
4. Hazardous Waste Fuel: If you market hazardous waste fuel,
place an "X" in the appropriate box(es). If you burn hazardous
waste fuel on-site, place an "X" in the appropriate box and
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Notification of Regulated Waste Activity
indicate the type(s) of combustion devices in which hazardous
waste fuel is burned. (Refer to the definition section for
complete descriptions of each device).
Note: Generators are required to notify for waste-as-fuel
activities only if they market directly to the burner.
"Other Marketer" is defined as any person, other than a
generator marketing hazardous waste, who markets hazardous
waste fuel.
5. Underground Injection Control: If you generate and/or treat,
store or dispose of hazardous waste, place an "X" in the box if
an injection well is located at your installation. "Underground
Injection" means the subsurface emplacement of fluids
through a bored, drilled or driven well; or through a dug well,
where the depth of the dug well is greater than the largest
surface dimension.
B. Used Oil Recycling Activities: Mark an "X" in the appropriate
boxfes) to indicate which used oil recycling activities are taking
place at this installation.
1. Used Oil Fuel Marketer: If you market off-specification used
oil, mark an "X" in box la. If you are the first to claim the
used oil meets the used oil specification established in 40 CFR
Part 279.11, mark an "X" in box Ib. If either of these boxes
are marked, you must also notify (or have previously notified}
as a used oil transporter, off-specification used oil fuel burner,
or used oil processor/re-refiner, unless you are a used oil
generator. (Used oil generators are not required to notify.)
2. Used Oil Burner: If you burn off-specification used oil fuel,
place an "X" in the box(es) to indicate the type(s) of combustion
device(s) in which off-specification used oil fuel is burned.
(Refer to the definition section for complete descriptions of
each device.)
3. Used Oil Transporter: If you transport used oil and/or
own/operate a used oil transfer facility, place an "X" in the
appropriate boxfes) to indicate this used oil recycling activity.
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Notification of Regulated Waste Activity
4. Used Oil Processor/Re-refiner: If you process and/or re-
refine used oil, place an "X" in the appropriate box(es) to
indicate this used oil activity.
Item IX - Description of Hazardous Wastes:
Note: Only persons involved in hazardous waste activity (Item VIII.A.)
need to complete this item. Transporters requesting a U.S. EPA
Identification Number do not need to complete this item, but must sign
the "Certification" in Item X.
You will need to refer to 40 CFR Part 261 (enclosed as Section VII) in
order to complete this section. Part 261 identifies those wastes that EPA
defines as hazardous. If you need help completing this section, please
contact the appropriate addressee for your State as listed in Section IV.
C. of this package.
A. Characteristics of Nonlisted Hazardous Wastes: If you handle
hazardous wastes which are not listed in 40 CFR Part 261,
Subpart D, but do exhibit a characteristic of hazardous waste as
defined in 40 CFR Part 261, Subpart C, you should describe these
wastes by the EPA hazardous waste number for the characteristic.
Place an "X" in the box next to the characteristic of the wastes that
you handle. If you mark "4. Toxicity Characteristic," please list the
specific EPA hazardous waste number(s) for the specific
contaminant(s) in the box(es) provided. Refer to Section VTV to
determine the appropriate hazardous waste number(s).
B. Listed Hazardous Wastes: If you handle hazardous wastes that
are listed in 40 CFR Part 261, Subpart D, enter the appropriate
4-digit numbers in the boxes provided.
Note: If you handle more than 12 listed hazardous wastes, please
continue listing the waste codes on the extra sheet provided at the
end of this booklet. If it is used, attach the additional page to the
rest of the form before mailing it to the appropriate EPA Regional or
State Office.
C. Other Wastes: If you handle other wastes or State regulated wastes
that have a waste code, enter the appropriate code number in the
boxes provided.
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Notification of Regulated Waste Activity
Item X - Certification:
This certification must be signed by the owner, operator, or an
authorized representative of your installation. An "authorized
representative" is a person responsible for the overall operation of the
installation (i.e., a plant manger or superintendent, or a person of equal
responsibility). All notifications must include this certification to be
complete.
Item XI -- Comments:
Use this space for any additional comments.
VI. Definitions
The following definitions are included to help you to understand and
complete the Notification Form:
Act or RCRA means the Solid Waste Disposal Act, as amended by the
Resource Conservation and Recovery Act of 1976, as amended by
the Hazardous and Solid Waste Amendments of 1984, 42 U.S.C.
Section 6901 et seq.
Authorized Representative means the person responsible for the
overall operation of the installation or an operational unit (i.e., part
of a installation), e.g., superintendent or plant manager, or person
of equivalent responsibility.
Boiler means an enclosed device using controlled flame combustion and
having the following characteristics:
1. The unit has physical provisions for recovering and exporting
energy in the form of steam, heated fluids, or heated gases;
2. The units combustion chamber and primary energy recovery
section(s) are of integral design (i.e., they are physically formed
into one manufactured or assembled unit);
3. The unit continuously maintains an energy recovery efficiency
of at least 60 percent, calculated in terms of the recovered
energy compared with the thermal value of the fuel;
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Notification of Regulated Waste Activity
4. The unit exports and utilizes at least 75 percent of the
recovered energy, calculated on an annual basis (excluding
recovered heat used internally in the same unit, for example,
to preheat fuel or combustion air or drive fans or feedwater
pumps); and
5. The unit is one which the Regional Administrator has
determined on a case-by-case basis, to be a boiler after
considering the standards in 40 CFR 260.32.
Burner means the owner or operator of any boiler or industrial furnace
that bums hazardous waste fuel for energy recovery and that is not
regulated as a RCRA hazardous waste incinerator.
Disposal means the discharge, deposit, injection, dumping, spilling,
leaking, or placing of any solid waste or hazardous waste into or on
any land or water so that such solid waste or hazardous waste or
any constituent thereof may enter the environment or be emitted
into the air or discharged into any waters, including ground
waters.
Disposal Installation means a installation or part of a installation at
which hazardous waste is intentionally placed into or on any land
or water, and at which waste will remain after closure.
EPA Identification (I.D.) Number means the number assigned by EPA
to each generator, transporter, and treatment, storage, or disposal
installation.
Generator means any person, by site, whose act or process produces
hazardous waste identified or listed in 40 CFR Part 261.
Hazardous Waste means a hazardous waste as defined in 40 CFR 261.3.
Hazardous Waste Fuel means hazardous waste and any fuel that
contains hazardous waste that is burned for energy recovery in a
boiler or industrial furnace that is not subject to regulation as a
RCRA hazardous waste incinerator. However, the following
hazardous waste fuels are subject to regulation as used oil fuels:
1. Used oil fuel burned for energy recovery that is also a
hazardous waste solely because it exhibits a characteristic of
hazardous waste identified in Subpart C of 40 CFR Part 261;
and
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Notification of Regulated Waste Activity
2. Used oil fuel mixed with hazardous wastes generated by a
small quantity generator subject to 40 CFR 261.5.
Hazardous Waste Fuel Marketer is a person who markets hazardous
waste fuel. However, generators and initial transporters (i.e.,
transporters who receive hazardous waste directly from generators
including initial transporters who operate transfer stations) who do
not market directly to persons who burn the fuels are not subject
to waste-as-fuel requirements (including notification) under
Subpart D of 40 CFR Part 266.
Industrial Boiler means a boiler located on the site of a installation
engaged in a manufacturing process where substances are
transformed into new products, including the component parts of
products, by mechanical or chemical processes.
Industrial Furnace means any of the following enclosed devices that are
integral components of manufacturing processes and that use
controlled flame combustion to accomplish recovery of materials or
energy: cement kilns, lime kilns, aggregate kilns (including asphalt
kilns), phosphate kilns, coke ovens, blast furnaces, smelting
furnaces, refining furnaces, titanium dioxide chloride process
oxidation reactors, methane reforming furnaces, pulping liquor
recovery furnaces, combustion devices used in the recovery of
sulfur values from spent sulfuric acid, and other devices as the
Administrator may add to this list.
Installation means all contiguous land, structures, other
appurtenances, and improvements on the land, used for treating,
storing, or disposing of hazardous waste. A installation may consist
of several treatment, storage, or disposal operational units (e.g.,
one or more landfills, surface impoundments, or combinations of
them).
Municipality means a city, village, town, borough, county, parish,
district, association, Indian tribe or authorized Indian tribal
organization, designated and approved management agency under
Section 208 of the Clean Water Act, or any other public body
created by or under State law and having jurisdiction over disposal
of sewage, industrial wastes, or other wastes.
Off-Specification Used Oil Fuel means used oil fuel that does not meet
the specification provided under 40 CFR 279.11.
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Notification of Regulated Waste Activity
On-Specification Used Oil Fuel means used oil fuel that meets the
specification provided under 40 CFR 279.11.
Operator means the person responsible for the overall operation of a
installation.
Owner means a person who owns a installation or part of a installation,
including landowner.
Processing means chemical or physical operations designed to produce
from used oil, or to make used oil more amenable for production of
fuel oils, lubricants, or other used oil-derived product. Processing
includes, but is not limited to: blending used oil with virgin
petroleum products, blending used oils to meet the fuel
specification, filtration, simple distillation, and chemical or physical
separation.
Small Quantity Exemption means small quantities of hazardous waste
that are exempt from the requirements of 40 CFR 266.108.
Smelter Deferral means that the mandate in section 3000(g) to regulate
facilities burning hazardous waste for energy recovery as may be
necessary to protect human health and the environment does not
apply to devices burning for the purpose of material recovery.
Storage means the holding of hazardous waste for a temporary period,
at the end of which the hazardous waste is treated, disposed of, or
stored elsewhere.
Transportation means the movement of hazardous waste by air, rail,
highway, or water.
Transporter means a person engaged in the off-site transportation of
hazardous waste by air, rail, highway, or water.
Treatment means any method, technique, or process, including
neutralization, designed to change the physical, chemical, or
biological character or composition of any hazardous waste so as to
neutralize such waste, or so as to recover energy or material
resources from the waste, or so as to render such waste
nonhazardous, or less hazardous; safer to transport, store or
dispose of; or amenable for recovery, amenable for storage, or
reduced in volume. Such term includes any activity or processing
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Notification of Regulated Waste Activity
designed to change the physical form or composition of hazardous
waste so as to render it nonhazardous.
Underground Injection Control means the subsurface emplacement of
fluids through a bored, drilled or driven well; or through a dug
well, where the depth of the dug well is greater than the largest
surface dimension.
Used Oil means any oil that has been refined from crude oil, or any
synthetic oil, that has been used, and as a result of such use, is
contaminated by physical or chemical impurities.
Used Oil Burner means a facility where used oil not meeting the
specification requirements in 40 CFR 279.11 is burned for energy
recovery in devices identified in Section 279.61 (a).
Used Oil Processor means a facility that processes on- or off-
specification used oil.
Used Oil Recycling Activities, for the purposes of this form, include
used oil transportation, processing, and re-refining; burning off-
specification used oil fuel; and used oil fuel marketing.
Used Oil Re-refiner is a person who produces lubricating oils and
greases, industrial fuel, asphalt extender, gasoline, and other
products from on- or off-specification used oil.
Used Oil Transfer Facility means any transportation related facility
including loading docks, parking areas, storage areas, and other
areas where shipments of used oil are held for more than 24 hours
during the normal course of transportation and not longer than 35
days. Transfer facilities that store used oil for more than 35 days
are subject to regulation under 40 CFR Part 279, Subpart F.
Used Oil Transporter means any person who transports used oil, any
person who collects used oil from more than one generator and
transports the collected oil, and owners and operators of used oil
transfer facilities. Used oil transporters may consolidate or
aggregate loads of used oil for purposes of transportation but, with
the following exception, may not process used oil. Transporters
may conduct incidental processing operations that occur in the
normal course of used oil transportation (e.g., settling and water
separation), but that are not designed to produce (or make more
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Notification of Regulated Waste Activity
amenable for production of) used oil-derived products or used oil
fuel.
Used Oil Fuel Marketer means any person who conducts either of the
following activities:
1. Directs a shipment of off-specification used oil from their
facility to a used oil burner; or
2. First claims that used oil that is to be burned for energy
recovery meets the used oil fuel specifications set forth in 40
CFR279.11.
Utility Boiler means a boiler that is used to produce electricity, steam or
heated or cooled air or other gases or fluids for sale.
VII. EPA Hazardous Waste Numbers for Waste Streams
Commonly Generated by Small Quantity
Generators
The Environmental Protection Agency recognizes that generators of small
quantities of hazardous waste, many of which are small businesses, may
not be familiar with the manner in which hazardous waste materials are
identified in the Code of Federal Regulations. This insert has been
assembled in order to aid small quantity generators in determining for
their wastes the EPA Hazardous Waste Numbers that are needed to
complete the "Notification of Regulated Waste Activity," Form 8700-12.
This insert is composed of two appendices. Appendix 1 lists eighteen
general industry categories that contain small quantity generators. For
each of these categories, commonly generated hazardous waste streams
are identified. Appendix 2 lists EPA Hazardous Waste Numbers for each
waste stream identified in Appendix 1.
To use this insert:
1. Locate your industry in Appendix 1 to identify the waste streams
common to your activities.
2. Find each of your waste streams in Appendix 2, and review the
more detailed descriptions of typical wastes to determine which
waste streams actually result from your activities.
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Notification of Regulated Waste Activity
3. If you determine that a waste stream does apply to you, report the
4-digit EPA Hazardous Waste Number in Item IX, B. of Form
8700-12, "Notification of Regulated Waste Activity."
The industries and waste streams described here do not provide a
comprehensive list but rather serve as a guide to potential small quantity
generators in determining which of their wastes, if any, are hazardous.
Except for the pesticide category, this insert does not include EPA
Hazardous Waste Numbers for commercial chemical products that are
hazardous when discarded unused. These chemicals and their EPA
Hazardous Waste Numbers are listed in 40 CFR 261.33.
If the specific Hazardous Waste Number that should be applied to your
waste stream is unclear, please refer to 40 CFR Part 261, reprinted in
Section VIII of this notification package. In those cases where more than
one Hazardous Waste Number is applicable, all should be used. If you
have any questions, or if you are unable to determine the proper EPA
Hazardous Waste Numbers for your wastes, contact your state
hazardous waste management agency as listed in Section IV of these
notification instructions, or the RCRA/Superfund Hotline at
1-800-44-9346 (or in the Washington, D.C. area at (703) 412-9810).
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Notification of Regulated Waste Activity
VIII. Reprint of Part 261 from Title 40 of the Code of
Federal Regulations (July 1,1992).
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Environmental Protection Agency
§261.1
PART 261—IDENTIFICATION AND
LISTING OF HAZARDOUS WASTE
Subparl A—General
Sec.
261.1 Purpose and scope.
261.2 Definition of solid waste.
261.3 Definition of hazardous waste.
261.4 Exclusions.
261.5 Special requirements for hazardous
waste generated by conditionally
exempt small quantity generators.
261.6 Requirements for recyclable materi-
als.
261.7 Residues of hazardous waste in
empty containers.
261.8 PCB wastes regulated under Toxic
Substance Control Act.
Subparl B—Criteria for Identifying the Charac-
teristics of Hazardous Waste and for List-
ing Hazardous Wastes
261.10 Criteria for identifying the charac-
teristics of hazardous waste.
261.11 Criteria for listing hazardous waste.
Subpart C—Characteristics of Hazardous
Waste
261,20 General.
261.21 Characteristic of ignitability.
261.22 Characteristic of corrosivity.
261.23 Characteristic of reactivity.
261.24 Toxicity characteristic.
Subpart D—Lists of Hazardous Wastes
261.30 General.
261.31 Hazardous wastes from non-specific
sources.
261.32 Hazardous wastes from specific
sources.
261.33 Discarded commercial chemical
products, off-specification species, con-
tainer residues, and spill residues there-
of.
261.35 Deletion of certain hazardous waste
codes following equipment cleaning and
replacement.
APPENDICES TO PART 261
APPENDIX I—REPRESENTATIVE SAMPLING
METHODS
APPENDIX II—METHOD 1311 TOXICITY CHAR-
ACTERISTIC LEACHING PROCEDURE (TCLP)
APPENDIX III—CHEMICAL ANALYSIS TEST
METHODS
APPENDIX IV—[RESERVED FOR RADIOACTIVE
WASTE TEST METHODS]
APPENDIX V—[RESERVED FOR INFECTIOUS
WASTE TREATMENT SPECIFICATIONS]
APPENDIX VI—[RESERVED FOR ETIOLOGIC
AGENTS]
Sec.
APPENDIX VII—BASIS FOR LISTING HAZARD-
OUS WASTE
APPENDIX VIII—HAZARDOUS CONSTITUENTS
APPENDIX IX—WASTES EXCLUDED UNDER
§§260.20 AND 260.22
APPENDIX X—METHOD OF ANALYSIS FOR
CHORINATED DIBENZO-P-DIOXINS AND -Di-
BENZOFURANS
AUTHORITY: 42 U.S.C. 6905, 6912(a), 6921,
6922, and 6938.
SOURCE: 45 FR 33119, May 19, 1980, unless
otherwise noted.
Subpart A—General
§ 261.1 Purpose and scope.
(a) This part identifies those solid
wastes which are subject to regulation
as hazardous wastes under parts 262
through 265, 268, and parts 270, 271,
and 124 of this chapter and which are
subject to the notification require-
ments of section 3010 of RCBA. In
this part:
(1) Subpart A defines the terms
"solid waste" and "hazardous waste",
identifies those wastes which are ex-
cluded from regulation under parts
262 through 266, 268 and 270 and es-
tablishes special management require-
ments for hazardous waste produced
by conditionally exempt small quanti-
ty generators and hazardous waste
which is recycled.
(2) Subpart B sets forth the criteria
used by EPA to identify characteris-
tics of hazardous waste and to list par-
ticular hazardous wastes.
(3) Subpart C identifies characteris-
tics of hazardous waste.
(4) Subpart D lists particular haz-
ardous wastes.
(b)(l) The definition of solid waste
contained in this part applies only to
wastes that also are hazardous for pur-
poses of the regulations implementing
subtitle C of RCRA. For example, it
does not apply to materials (such as
non-hazardous scrap, paper, textiles,
or rubber) that are not otherwise haz-
ardous wastes and that are recycled.
(2) This part identifies only some of
the materials which are solid wastes
and hazardous wastes under sections
3007, 3013, and 7003 of RCRA. A mate-
rial which is not defined as a solid
waste in this part, or is not a hazard-
ous waste identified or listed in this
27
-------
§261.2
part, is still a solid waste and a hazard-
ous waste for purposes of these sec-
tions if:
(i) In the case of sections 3007 and
3013, EPA has reason to believe that
the material may be a solid waste
within the meaning of section 1004(27)
of RCRA and a hazardous waste
within the meaning of section 1004(5)
of RCRA; or
(ii) In the case of section 7003, the
statutory elements are established.
(c) For the purposes of §§ 261.2 and
261.6:
(DA "spent material" is any materi-
al that has been used and as a result
of contamination can no longer serve
the purpose for which it was produced
without processing;
(2) "Sludge" has the same meaning
used in § 260.10 of this chapter;
(3) A "by-product" is a material that
is not one of the primary products of a
production process and is not solely or
separately produced by the production
process. Examples are process residues
such as slags or distillation column
bottoms. The term does not include a
co-product that is produced for the
general public's use and is ordinarily
used in the form it is produced by the
process.
(4) A material is "reclaimed" if it is
processed to recover a usable product,
or if it is regenerated. Examples are
recovery of lead values from spent bat-
teries and regeneration of spent sol-
vents.
(5) A material is "used or reused" if
it is either:
(i) Employed as an ingredient (in-
cluding use as an intermediate) in an
industrial process to make a product
(for example, distillation bottoms
from one process used as feedstock in
another process). However, a material
will not satisfy this condition if dis-
tinct components of the material are
recovered as separate end products (as
when metals are recovered from
metal-containing secondary materials);
or
(ii) Employed in a particular func-
tion or application as an effective sub-
stitute for a commercial product (for
example, spent pickle liquor used as
phosphorous precipitant and sludge
conditioner in wastewater treatment).
40 CFR Ch. I (7-1-92 Edition)
(6) "Scrap metal" is bits and pieces
of metal parts (e.g.,} bars, turnings,
rods, sheets, wire) or metal pieces that
may be combined together with bolts
or soldering (e.g., radiators, scrap auto-
mobiles, railroad box cars), which
when worn or superfluous can be recy-
cled.
(7) A material is "recycled" if it is
used, reused, or reclaimed.
(8) A material is "accumulated spec-
ulatively" if it is accumulated before
being recycled. A material is not accu-
mulated speculatively, however, if the
person accumulating it can show that
the material is potentially recyclable
and has a feasible means of being recy-
cled; and that—during the calendar
year (commencing on January 1)—the
amount of material that is recycled, or
transferred to a different site for recy-
cling, equals at least 75 percent by
weight or volume of the amount of
that material accumulated at the be-
ginning of the period. In calculating
the percentage of turnover, the 75 per-
cent requirement is to be applied to
each material of the same type (e.g.,
slags from a single smelting process)
that is recycled in the same way (i.e.,
from which the same material is recov-
ered or that is used in the same way).
Materials accumulating in units that
would \js exempt from regulation
under § 261.4(c) are not be included in
making the calculation. (Materials
that are already defined as solid
wastes also are not to be included in
making the calculation.) Materials are
no longer in this category once they
are removed from accumulation for re-
cycling, however.
[45 FR 33119, May 19, 1980, as amended at
48 FR 14293, Apr. 1, 1983; 50 FR 663, Jan. 4,
1985; 51 FR 10174, Mar. 24, 1986; 51 FR
40636, Nov. 7, 1986]
§ 261.2 Definition of solid waste.
(aXI) A solid waste is any discarded
material that is not excluded by
§ 261.4(a) or that is not excluded by
variance granted under §§ 260.30 and
260.31.
(2) A discarded material is any mate-
rial which is:
(i) Abandoned, as explained in para-
graph (b) of this section; or
28
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Environmental Protection Agency
§261.2
(ii) Recycled, as explained in para-
graph (c) of this section; or
(iii) Considered inherently waste-
like, as explained in paragraph (d) of
this section.
(b) Materials are solid waste if they
are abandoned by being:
(1) Disposed of; or
(2) Burned or incinerated; or
(3) Accumulated, stored, or treated
(but not recycled) before or in lieu of
being abandoned by being disposed of,
burned, or incinerated.
(c) Materials are solid wastes if they
are recycled—or accumulated, stored,
or treated before recycling—as speci-
fied in paragraphs (c)(l) through (4)
of this section.
(1) Used in a manner constituting
disposal, (i) Materials noted with a "*"
in Column 1 of Table I are solid wastes
when they are:
(A) Applied to or placed on the land
in a manner that constitutes disposal;
or
(B) Used to produce products that
are applied to or placed on the land or
are otherwise contained in products
that are applied to or placed on the
land (in which cases the product itself
remains a solid waste).
(ii) However, commercial chemical
products listed in § 261.33 are not solid
wastes if they are applied to the land
and that is their ordinary manner of
use.
(2) Burning for energy recovery, (i)
Materials noted with a "*" in column 2
of Table 1 are solid wastes when they
are:
(A) Burned to recover energy;
(B) Used to produce a fuel or are
otherwise contained in fuels (in which
cases the fuel itself remains a solid
waste).
(ii) However, commercial chemical
products listed in § 261.33 are not solid
wastes if they are themselves fuels.
(3) Reclaimed. Materials noted with
a "*" in column 3 of Table 1 are solid
wastes when reclaimed.
(4) Accumulated speculatively. Mate-
rials noted with a "*" in column 4 of
Table 1 are solid wastes when accumu-
lated speculatively.
TABLE 1
Sludges (listed in 40 CFR part 261 31 or 261 32)
By-products (listed in 40 CFR part 261 31 or 261 32)
By-products exhibiting a characteristic of hazardous waste
Use
constituting
disposal
(§261.2(c)(1))
0)
(")
C)
C)
(*)
(*)
C)
n
Energy
recovery/fuel
(|261.2
-------
§261.3
40 CFR Ch. I (7-1-92 Edition)
(3) The Administrator will use the
following criteria to add wastes to that
list:
(i)(A) The materials are ordinarily
disposed of, burned, or incinerated; or
(B) The materials contain toxic con-
stituents listed in appendix VIII of
part 261 and these constituents are
not ordinarily found in raw materials
or products for which the materials
substitute (or are found in raw materi-
als or products in smaller concentra-
tions) and are not used or reused
during the recycling process; and
(ii) The material may pose a sub-
stantial hazard to human health and
the environment when recycled.
(e) Materials that are not solid waste
when recycled. (1) Materials are not
solid wastes when they can be shown
to be recycled by being:
(i) Used or reused as ingredients in
an industrial process to make a prod-
uct, provided the materials are not
being reclaimed; or
(ii) Used or reused as effective sub-
stitutes for commercial products; or
(iii) Returned to the original process
from which they are generated, with-
out first being reclaimed. The material
must be returned as a substitute for
raw material feedstock, and the proc-
ess must use raw materials as principal
feedstocks.
(2) The following materials are solid
wastes, even if the recycling involves
use, reuse, or return to the original
process (described in paragraphs (e)(l)
(i) through (iii) of this section):
(i) Materials used in a manner con-
stituting disposal, or used to produce
products that are applied to the land;
or
(ii) Materials burned for energy re-
covery, used to produce a fuel, or con-
tained in fuels; or
(iii) Materials accumulated specula-
tively; or
(iv) Materials listed in paragraph
(d)(l) of this section.
(f) Documentation of claims that
materials are not solid wastes or are
conditionally exempt from regulation.
Respondents in actions to enforce reg-
ulations implementing subtitle C of
RCRA who raise a claim that a certain
material is not a solid waste, or is con-
ditionally exempt from regulation,
must demonstrate that there is a
known market or disposition for the
material, and that they meet the
terms of the exclusion or exemption.
In doing so, they must provide appro-
priate documentation (such as con-
tracts showing that a second person
uses the material as an ingredient in a
production process) to demonstrate
that the material is not a waste, or is
exempt from regulation. In addition,
owners or operators of facilities claim-
ing that they actually are recycling
materials must show that they have
the necessary equipment to do so.
[50 FR 664, Jan. 4, 1985, as amended at 50
FR 33542, Aug. 20, 1985; 56 FR 7206, Feb.
21, 1991; 56 FR 32688, July 17, 1991; 56 FR
42512, Aug. 27, 1991]
§ 261.3 Definition of hazardous waste.
(a) A solid waste, as defined in
§ 261.2, is a hazardous waste if:
(1) It is not excluded from regula-
tion as a hazardous waste under
§ 261.4(b); and
(2) It meets any of the following cri-
teria:
(i) It exhibits any of the characteris-
tics of hazardous waste identified in
subpart C except that any mixture of
a waste from the extraction, beneficia-
tion, and processing of ores and miner-
als excluded under § 261.4(b)(7) and
any other solid waste exhibiting a
characteristic of hazardous waste
under subpart C of this part only if it
exhibits a characteristic that would
not have been exhibited by the ex-
cluded waste alone if such mixture
had not occurred or if it continues to
exhibit any of the characteristics ex-
hibited by the non-excluded wastes
prior to mixture. Further, for the pur-
poses of applying the Toxicity Charac-
teristic to such mixtures, the mixture
is also a hazardous waste if it exceeds
the maximum concentration for any
contaminant listed in table I to
§ 261.24 that would not have been ex-
ceeded by the excluded waste alone if
the mixture had not occurred or if it
continues to exceed the maximum
concentration for any contaminant ex-
ceeded by the nonexempt waste prior
to mixture.
(ii) It is listed in subpart D of this
part and has not been excluded from
the lists in subpart D of this part
30
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Environmental Protection Agency
§261.3
under §§ 260.20 and 260.22 of this
chapter.
(iii) It is a mixture of a solid waste
and a hazardous waste that is listed in
subpart D of this part solely because it
exhibits one or more of the character-
istics of hazardous waste identified in
subpart C of this part, unless the re-
sultant mixture no longer exhibits any
characteristic of hazardous waste iden-
tified in subpart C of this part or
unless the solid waste is excluded from
regulation under § 261.4(b)(7) and the
resultant mixture no longer exhibits
any characteristic of hazardous waste
identified in subpart C of this part for
which the hazardous waste listed in
subpart D of this part was listed.
(iv) It is a mixture of solid waste and
one or more hazardous wastes listed in
subpart D of this part and has not
been excluded from paragraph (a)(2)
of this section under §§260.20 and
260.22 of this chapter; however, the
following mixtures of solid wastes and
hazardous wastes listed in subpart D
of this part are not hazardous wastes
(except by application of paragraph
(a)(2) (i) or (ii) of this section) if the
generator can demonstrate that the
mixture consists of wastewater the dis-
charge of which is subject to regula-
tion under either section 402 or sec-
tion 307(b) of the Clean Water Act (in-
cluding wastewater at facilities which
have eliminated the discharge of
wastewater) and:
(A) One or more of the following sol-
vents listed in § 261.31—carbon tetra-
chloride, tetrachloroethylene, trichlor-
oethylene—Provided, That the maxi-
mum total weekly usage of these sol-
vents (other than the amounts that
can be demonstrated not to be dis-
charged to wastewater) divided by the
average weekly flow of wastewater
into the headworks of the facility's
wastewater treatment or pretreatment
system does not exceed 1 part per mil-
lion; or
(B) One or more of the following
spent solvents listed in § 261.31—meth-
ylene chloride, 1,1,1-trichloroethane,
chlorobenzene, o-dichlorobenzene, cre-
sols, cresylic acid, nitrobenzene, tolu-
ene, methyl ethyl ketone, carbon di-
sulfide, isobutanol, pyridine, spent
chlorofluorocarbon solvents—provided
that the maximum total weekly usage
of these solvents (other than the
amounts that can be demonstrated not
to be discharged to wastewater) divid-
ed by the average weekly flow of
wastewater into the headworks of the
facility's wastewater treatment or pre-
treatment system does not exceed 25
parts per million; or
(C) One of the following wastes
listed in § 261.32—heat exchanger
bundle cleaning sludge from the petro-
leum refining industry (EPA Hazard-
ous Waste No. K050); or
(D) A discarded commercial chemi-
cal product, or chemical intermediate
listed in § 261.33, arising from de mini-
mis losses of these materials from
manufacturing operations in which
these materials are used as raw mate-
rials or are produced in the manufac-
turing process. For purposes of this
paragraph (a)(2)(iv)(D), "de minimis"
losses include those from normal ma-
terial handling operations (e.g., spills
from the unloading or transfer of ma-
terials from bins or other containers,
leaks from pipes, valves or other de-
vices used to transfer materials);
minor leaks of process equipment,
storage tanks or containers; leaks from
well maintained pump packings and
seals; sample purgings; relief device
discharges; discharges from safety
showers and rinsing and cleaning of
personal safety equipment; and rin-
state from empty containers or from
containers that are rendered empty by
that rinsing; or
(E) Wastewater resulting from labo-
ratory operations containing toxic (T)
wastes listed in subpart D of this part,
Provided, That the annualized average
flow of laboratory wastewater does not
exceed one percent of total wastewater
flow into the headworks of the facili-
ty's wastewater treatment or pre-treat-
ment system, or provided the wastes,
combined annualized average concen-
tration does not exceed one part per
million in the headworks of the facili-
ty's wastewater treatment or pre-treat-
ment facility. Toxic (T) wastes used in
laboratories that are demonstrated
not to be discharged to wastewater are
not to be included in this calculation.
(b) A solid waste which is not ex-
cluded from regulation under para-
graph (a)(l) of this section becomes a
31
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§261.3
40 CFR Ch. I (7-1-92 Edition)
hazardous waste when any of the fol-
lowing events occur:
(1) In the case of a waste listed in
subpart D of this part, when the waste
first meets the listing description set
forth in subpart D of this part.
(2) In the case of a mixture of solid
waste and one or more listed hazard-
ous wastes, when a hazardous waste
listed in subpart D is first added to the
solid waste.
(3) In the case of any other waste
(including a waste mixture), when the
waste exhibits any of the characteris-
tics identified in subpart C of this
part.
(c) Unless and until it meets the cri-
teria of paragraph (d) of this section:
(DA hazardous waste will remain a
hazardous waste.
(2)(i) Except as otherwise provided
in paragraph (c)(2Xii) of this section,
any solid waste generated from the
treatment, storage, or disposal of a
hazardous waste, including any sludge,
spill residue, ash, emission control
dust, or leachate (but not including
precipitation run-off) is a hazardous
waste. (However, materials that are re-
claimed from solid wastes and that are
used beneficially are not solid wastes
and hence are not hazardous wastes
under this provision unless the re-
claimed material is burned for energy
recovery or used in a manner consti-
tuting disposal.)
(ii) The following solid wastes are
not hazardous even though they are
generated from the treatment, stor-
age, or disposal of a hazardous waste,
unless they exhibit one or more of the
characteristics of hazardous waste:
(A) Waste pickle liquor sludge gener-
ated by lime stabilization of spent
pickle liquor from the iron and steel
industry (SIC Codes 331 and 332).
(B) Waste from burning any of the
materials exempted from regulation
by § 261.6(a)(3)(v) through (viii).
(C) Nonwastewater residues, such as
slag, resulting from high temperature
metals recovery (HTMR) processing of
K061 waste, in units identified as
rotary kilns, flame reactors, electric
furnaces, plasma arc furnaces, slag re-
actors, rotary hearth furnace/electric
furnace combinations or industrial
furnaces (as defined in 40 CFR
260.10(6), (7), and (12), that are dis-
posed in subtitle D units, provided
that these residues meet the generic
exclusion levels identified below for all
constituents, and exhibit no character-
istics of hazardous waste. Testing re-
quirements must be incorporated in a
facility's waste analysis plan or a gen-
erator's self-implementing waste anal-
ysis plan; at a minimum, composite
samples of residues must be collected
and analyzed quarterly and/or when
the process or operation generating
the waste changes. The generic exclu-
sion levels are:
Constituent
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium (total)
Lead
Nickel
Selenium
Silver
Thallium
Vanadium
Maximum
for any
single
compos-
ite
sample
(mg/1)
0.063
0.055
6.3
0.0063
0032
0.33
0.095
0009
063
0.16
0.30
0013
1.26
For each shipment of K061 HTMR
residues sent to subtitle D unit that
meets the generic exclusion levels for
all constituents, and does not exhibit
any characteristic, a notification and
certification must be sent to the ap-
propriate Regional Administrator (or
delegated representative) or State au-
thorized to implement part 268 re-
quirements. The notification must in-
clude the following information: (1)
The name and address of the subtitle
D unit receiving the waste shipment;
(2) the EPA hazardous waste number
and treatability group at the initial
point of generation; (3) treatment
standards applicable to the waste at
the intital point of generation. The
certification must be signed by an au-
thorized representative and must state
as follows: "I certify under penalty of
law that the generic exclusion levels
for all constituents have been met
without impermissible dilution and
that no characteristic of hazardous
waste is exhibited. I am aware that
32
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Environmental Protection Agency
§261.4
there are significant penalties for sub-
mitting a false certification, including
the possibility of fine and imprison-
ment."
(d) Any solid waste described in
paragraph (c) of this section is not a
hazardous waste if it meets the follow-
ing criteria:
(1) In the case of any solid waste, it
does not exhibit any of the character-
istics of hazardous waste identified in
subpart C of this part. (However,
wastes that exhibit a characteristic at
the point of generation may still be
subject to the requirements of part
268, even if they no longer exhibit a
characteristic at the point of land dis-
posal.)
(2) In the case of a waste which is a
listed waste under subpart D of this
part, contains a waste listed under sub-
part D of this part or is derived from a
waste listed in subpart D of this part,
it also has been excluded from para-
graph (c) of this section under
§§ 260.20 and 260.22 of this chapter.
(e) Sunset provision. Paragraphs
(a)(2)(iv) and (c)(2)(i) of this section
shall remain in effect only until April
28, 1993.
[57 FR 7632, Mar. 3, 1992; 57 FR 23063,
June 1, 1992]
EFFECTIVE DATE NOTE: At 57 FR 7632, Mar.
3, 1992 § 261.3 was revised, effective Febru-
ary 18, 1992. Paragraphs (a)(2)(iv) and
(c)(2)(i) will expire on April 28, 1993.
§ 261.4 Exclusions.
(a) Materials which are not solid
wastes. The following materials are
not solid wastes for the purpose of this
part:
(l)(i) Domestic sewage; and
(ii) Any mixture of domestic sewage
and other wastes that passes through
a sewer system to a publicly-owned
treatment works for treatment. "Do-
mestic sewage" means untreated sani-
tary wastes that pass through a sewer
system.
(2) Industrial wastewater discharges
that are point source discharges sub-
ject to regulation under section 402 of
the Clean Water Act, as amended.
[Comment: This exclusion applies only to
the actual point source discharge. It does
not exclude industrial wastewaters while
they are being collected, stored or treated
before discharge, nor does it exclude sludges
that are generated by industrial wastewater
treatment.]
(3) Irrigation return flows.
(4) Source, special nuclear or by-
product material as defined by the
Atomic Energy Act of 1954, as amend-
ed, 42 U.S.C. 2011 et seg.
(5) Materials subjected to in-situ
mining techniques which are not re-
moved from the ground as part of the
extraction process.
(6) Pulping liquors (i.e., black liquor)
that are reclaimed in a pulping liquor
recovery furnace and then reused in
the pulping process, unless it is accu-
mulated speculatively as defined in
§ 261.l(c) of this chapter.
(7) Spent sulfuric acid used to
produce virgin sulfuric acid, unless it
is accumulated speculatively as de-
fined in § 261.l(c) of this chapter.
(8) Secondary materials that are re-
claimed and returned to the original
process or processes in which they
were generated where they are reused
in the production process provided:
(i) Only tank storage is involved, and
the entire process through completion
of reclamation is closed by being en-
tirely connected with pipes or other
comparable enclosed means of convey-
ance;
(ii) Reclamation does not involve
controlled flame combustion (such as
occurs in boilers, industrial furnaces,
or incinerators);
(iii) The secondary materials are
never accumulated in such tanks for
over twelve months without being re-
claimed; and
(iv) The reclaimed material is not
used to produce a fuel, or used to
produce products that are used in a
manner constituting disposal.
(9)(i) Spent wood preserving solu-
tions that have been reclaimed and are
reused for their original intended pur-
pose; and
(ii) Wastewaters from the wood pre-
serving process that have been re-
claimed and are reused to treat wood.
(10) EPA Hazardous Waste No.
K087, and any wastes from the coke
by-products processes that are hazard-
ous only because they exhibit the Tox-
icity Characteristic specified in Sec-
tion 261.24 of this part, when, subse-
quent to generation, these materials
33
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§261.4
40 CFR Ch. I (7-1-92 Edition)
are recycled to coke ovens, to the tar
recovery process as a feedstock to
produce coal tar or are mixed with
coal tar prior to the tar's sale or refin-
ing. This exclusion is conditioned on
there being no land disposal of the
wastes from the point they are gener-
ated to the point they are recycled to
coke ovens or the tar refining process.
(11) Nonwastewater splash condens-
er dross residue from the treatment of
K061 in high temperature metals re-
covery units, provided it is shipped in
drums (if shipped) and not land dis-
posed before recovery.
(b) Solid wastes which are not haz-
ardous wastes. The following solid
wastes are not hazardous wastes:
(1) Household waste, including
household waste that has been collect-
ed, transported, stored, treated, dis-
posed, recovered (e.g., refuse-derived
fuel) or reused. "Household waste"
means any material (including gar-
bage, trash and sanitary wastes in
septic tanks) derived from households
(including single and multiple resi-
dences, hotels and motels, bunk-
houses, ranger stations, crew quarters,
campgrounds, picnic grounds and day-
use recreation areas). A resource re-
covery facility managing municipal
solid waste shall not be deemed to be
treating, storing, disposing of, or oth-
erwise managing hazardous wastes for
the purposes of regulation under this
subtitle, if such facility:
(i) Receives and burns only
(A) Household waste (from single
and multiple dwellings, hotels, motels,
and other residential sources) and
(B) Solid waste from commercial or
industrial sources that does not con-
tain hazardous waste; and
(ii) Such facility does not accept haz-
ardous wastes and the owner or opera-
tor of such facility has established
contractual requirements or other ap-
propriate notification or inspection
procedures to assure that hazardous
wastes are not received at or burned in
such facility.
(2) Solid wastes generated by any of
the following and which are returned
to the soils as fertilizers:
(i) The growing and harvesting of
agricultural crops.
(ii) The raising of animals, including
animal manures.
(3) Mining overburden returned to
the mine site.
(4) Fly ash waste, bottom ash waste,
slag waste, and flue gas emission con-
trol waste, generated primarily from
the combusion of coal or other fossil
fuels, except as provided by § 268.112
of this chapter for facilities that burn
or process hazardous waste.
(5) Drilling fluids, produced waters,
and other wastes associated with the
exploration, development, or produc-
tion of crude oil, natural gas or geo-
thermal energy.
(6)(i) Wastes which fail the test for
the Toxicity Characteristic because
chromium is present or are listed in
subpart D due to the presence of chro-
mium, which do not fail the test for
the Toxicity Characteristic for any
other constituent or are not listed due
to the presence of any other constitu-
ent, and which do not fail the test for
any other characteristic, if it is shown
by a waste generator or by waste gen-
erators that:
(A) The chromium in the waste is
exclusively (or nearly exclusively) tri-
valent chromium; and
(B) The waste is generated from an
industrial process which uses trivalent
chromium exlcusively (or nearly exclu-
sively) and the process does not gener-
ate hexavalent chromium; and
(C) The waste is typically and fre-
quently managed in non-oxidizing en-
vironments.
(ii) Specific wastes which meet the
standard in paragraphs (b)(6)(i)(A),
(B) and (C) (so long as they do not fail
the test for the charactristic of EP
toxicity, and do not fail the test for
any other characteristic) are:
(A) Chrome (blue) trimmings gener-
ated by the following subcategories of
the leather tanning and finishing in-
dustry: hair pulp/chrome tan/retan/
wet finish; hair save/chrome tan/
retan/wet finish; retan/wet finish; no
beamhouse; through-the-blue; and
shearling.
(B) Chrome (blue) shavings generat-
ed by the following subcategories of
the leather tanning and finishing in-
dustry: Hair pulp/chrome tan/retan/
wet finish; hair save/chrome tan/
retan/wet finish; retan/wet finish; no
beamhouse; through-the-blue; ana
shearling.
34
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Environmental Protection Agency
§261.4
Buffing dust generated by the
following subcategories of the leather
tanning and finishing industry; hair
pulp/chrome tan/retan/wet finish;
hair save/chrome tan/retan/wet
finish; retan/wet finish; no beam-
house; through-the-blue.
(D) Sewer screenings generated by
the following subcategories of the
leather tanning and finishing indus-
try: Hair pulp/crome tan/retan/wet
finish; hair save/chrome tan/retan/
wet finish; retan/wet finish; no beam-
house; through-the-blue; and shear-
ling.
(E) Wastewater treatment sludges
generated by the following subcategor-
ies of the leather tanning and finish-
ing industry: Hair pulp/chrome tan/
retan/wet finish; hair save/chrome
tan/retan/wet finish; retan/wet
finish; no beamhouse; through-the-
blue; and shearling.
(F) Wastewater treatment sludes
generated by the following subcategor-
ies of the leather tanning and finish-
ing industry: Hair pulp/chrome tan/
retan/wet finish; hair save/chrome-
tan/retan/wet finish; and through-
the-blue.
(G) Waste scrap leather from the
leather tanning industry, the shoe
manufacturing industry, and other
leather product manufacturing indus-
tries,
(H) Wastewater treatment sludges
from the production of TiO2 pigment
using chromium-bearing ores by the
chloride process.
(7) Solid waste from the extraction,
beneficiation, and processing of ores
and minerals (including coal, phos-
phate rock and overburden from the
mining of uranium ore), except as pro-
vided by § 266.112 of this chapter for
facilities that burn or process hazard-
ous waste. For purposes of
§ 261.4(b)(7), beneficiation of ores and
minerals is restricted to the following
activities: Crushing; grinding; washing;
dissolution; crystallization; filtration;
sorting; sizing; drying; sintering; pelle-
tizing; briquetting; calcining to remove
water and/or carbon dioxide; roasting,
autoclaving, and/or chlorination in
preparation for leaching (except
where the roasting (and/or autoclav-
ing and/or chlorination)/leaching se-
quence produces a final or intermedi-
ate product that does not undergo fur-
ther beneficiation or processing); grav-
ity concentration; magnetic separa-
tion; electrostatic separation; flota-
tion; ion exchange; solvent extraction;
electrowinning; precipitation; amalga-
mation; and heap, dump, vat, tank,
and in situ leaching. For the purpose
of § 261.4(b)(7), solid waste from the
processing of ores and minerals in-
cludes only the following wastes:
(i) Slag from primary copper proc-
essing;
(ii) Slag from primary lead process-
ing;
(iii) Red and brown muds from baux-
ite refining;
(iv) Phosphogypsum from phosphor-
ic acid production;
(v) Slag from elemental phosphorus
production;
(vi) Gasifier ash from coal gasifica-
tion;
(vii) Process wastewater from coal
gasification;
(viii) Calcium sulfate wastewater
treatment plant sludge from primary
copper processing;
(ix) Slag tailings from primary
copper processing;
(x) Fluorogypsum from hydrofluoric
acid production;
(xi) Process wastewater from hydro-
fluoric acid production;
(xii) Air pollution control dust/
sludge from iron blast furnaces;
(xiii) Iron blast furnace slag;
(xiv) Treated residue from roasting/
leaching of chrome ore;
(xv) Process wastewater from pri-
mary magnesium processing by the an-
hydrous process;
(xvi) Process wastewater from phos-
phoric acid production;
(xvii) Basic oxygen furnace and open
hearth furnace air pollution control
dust/sludge from carbon steel produc-
tion;
(xviii) Basic oxygen furnace and
open hearth furnace slag from carbon
steel production;
(xix) Chloride process waste solids
from titanium tetrachloride produc-
tion;
(xx) Slag from primary zinc process-
ing.
(8) Cement kiln dust waste, except
as provided by § 266.112 of this chap-
35
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§261.4
40 CFR Ch. I (7-1-92 Edition)
ter for facilities that burn or process
hazardous waste.
(9) Solid waste which consists of dis-
carded wood or wood products which
fails the test for the Toxicity Charac-
teristic solely for arsenic and which is
not a hazardous waste for any other
reason or reasons, if the waste is gen-
erated by persons who utilize the ar-
senical-treated wood and wood prod-
ucts for these materials' intended end
use.
(10) Petroleum-contaminated media
and debris that fail the test for the
Toxicity Characteristic of § 261.24
(Hazardous Waste Codes D018
through D043 only) and are subject to
the corrective action regulations under
part 280 of this chapter.
(11) Injected groundwater that is
hazardous only because it exhibits the
Toxicity Characteristic (Hazardous
Waste Codes D018 through D043 only)
in § 261.24 of this part that is reinject-
ed through an underground injection
well pursuant to free phase hydrocar-
bon recovery operations undertaken at
petroleum refineries, petroleum mar-
keting terminals, petroleum bulk
plants, petroleum pipelines, and petro-
leum transportation spill sites until
January 25, 1993. This extension ap-
plies to recovery operations in exist-
ence, or for which contracts have been
issued, on or before March 25, 1991.
For groundwater returned through in-
filtration galleries from such oper-
ations at petroleum refineries, market-
ing terminals, and bulk plants, until
[insert date six months after publica-
tion]. New operations involving injec-
tion wells (beginning after March 25,
1991) will qualify for this compliance
date extension (until January 25,
1993) only if:
(i) Operations are performed pursu-
ant to a written state agreement that
includes a provision to assess the
groundwater and the need for further
remediation once the free phase recov-
ery is completed; and
(ii) A copy of the written agreement
has been submitted to: Characteristics
Section (OS-333), U.S. Environmental
Protection Agency, 401 M Street, SW.,
Washington, DC 20460.
(12) Used chlorofluorocarbon refrig-
erants from totally enclosed heat
transfer equipment, including mobile
air conditioning systems, mobile re-
frigeration, and commercial and indus-
trial air conditioning and refrigeration
systems that use chlorofluorocarbons
as the heat transfer fluid in a refriger-
ation cycle, provided the refrigerant is
reclaimed for further use.
(13)—(14) [Reserved]
(15) Non-terne plated used oil filters
that are not mixed with wastes listed
in subpart D of this part if these oil
filters have been gravity hot-drained
using one of the following methods:
(i) Puncturing the filter anti-drain
back valve or the filter dome end and
hot-draining;
(ii) Hot-draining and crushing;
(iii) Dismantling and hot-draining;
or
(iv) Any other equivalent hot-drain-
ing method that will remove used oil.
(c) Hazardous wastes which are ex-
empted from certain regulations. A
hazardous waste which is generated in
a product or raw material storage
tank, a product or raw material trans-
port vehicle or vessel, a product or raw
material pipeline, or in a manufactur-
ing process unit or an associated non-
waste-treatment-manufacturing unit,
is not subject to regulation under
parts 262 through 265, 268, 270, 271
and 124 of this chapter or to the noti-
fication requirements of section 3010
of RCRA until it exits the unit in
which it was generated, unless the
unit is a surface impoundment, or
unless the hazardous waste remains in
the unit more than 90 days after the
unit ceases to be operated for manu-
facturing, or for storage or transporta-
tion of product or raw materials.
(d) Samples. (1) Except as provided
in paragraph (d)(2) of this section, a
sample of solid waste or a sample of
water, soil, or air, which is collected
for the sole purpose of testing to de-
termine its characteristics or composi-
tion, is not subject to any require-
ments of this part or parts 262
through 268 or part 270 or part 124 of
this chapter or to the notification re-
quirements of section 3010 of RCRA,
when:
(i) The sample is being transported
to a laboratory for the purpose of test-
ing; or
36
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Environmental Protection Agency
§261.4
(ii) The sample is being transported
back to the sample collector after test-
ing; or
(iii) The sample is being stored by
the sample collector before transport
to a laboratory for testing; or
(iv) The sample is being stored in a
laboratory before testing; or
(v) The sample is being stored in a
laboratory after testing but before it is
returned to the sample collector; or
(vi) The sample is being stored tem-
porarily in the laboratory after testing
for a specific purpose (for example,
until conclusion of a court case or en-
forcement action where further test-
ing of the sample may be necessary).
(2) In order to qualify for the ex-
emption in paragraphs (d)(l) (i) and
(ii) of this section, a sample collector
shipping samples to a laboratory and a
laboratory returning samples to a
sample collector must:
(i) Comply with U.S. Department of
Transportation (DOT), U.S. Postal
Service (USPS), or any other applica-
ble shipping requirements; or
(ii) Comply with the following re-
quirements if the sample collector de-
termines that DOT, USPS, or other
shipping requirements do not apply to
the shipment of the sample:
(A) Assure that the following infor-
mation accompanies the sample:
(1) The sample collector's name,
mailing address, and telephone
number;
(2) The laboratory's name, mailing
address, and telephone number;
(.3) The quantity of the sample;
(4) The date of shipment; and
(5) A description of the sample.
(B) Package the sample so that it
does not leak, spill, or vaporize from
its packaging.
(3) This exemption does not apply if
the laboratory determines that the
waste is hazardous but the laboratory
is no longer meeting any of the condi-
tions stated in paragraph (d)(l) of this
section.
(e) Treatability Study Samples. (1)
Except as provided in paragraph (e)(2)
of this section, persons who generate
or collect samples for the purpose of
conducting treatability studies as de-
fined in section 260.10, are not subject
to any requirement of parts 261
through 263 of this chapter or to the
notification requirements of Section
3010 of RCRA, nor are such samples
included in the quantity determina-
tions of § 261.5 and § 262.34(d) when:
(i) The sample is being collected and
prepared for transportation by the
generator or sample collector; or
(ii) The sample is being accumulated
or stored by the generator or sample
collector prior to transportation to a
laboratory or testing facility; or
(iii) The sample is being transported
to the laboratory or testing facility for
the purpose of conducting a treatabil-
ity study.
(2) The exemption in paragraph
(e)(l) of this section is applicable to
samples of hazardous waste being col-
lected and shipped for the purpose of
conducting treatability studies provid-
ed that:
(i) The generator or sample collector
uses (in "treatability studies") no more
than 1000 kg of any non-acute hazard-
ous waste, 1 kg of acute hazardous
waste, or 250 kg of soils, water, or
debris contaminated with acute haz-
ardous waste for each process being
evaluated for each generated waste
stream; and
(ii) The mass of each sample ship-
ment does not exceed 1000 kg of non-
acute hazardous waste, 1 kg of acute
hazardous waste, or 250 kg of soils,
water, or debris contaminated with
acute hazardous waste; and
(iii) The sample must be packaged so
that it will not leak, spill, or vaporize
from its packaging during shipment
and the requirements of paragraph A
or B of this subparagraph are met.
(A) The transportation of each
sample shipment complies with U.S.
Department of Transportation (DOT),
U.S. Postal Service (USPS), or any
other applicable shipping require-
ments; or
(B) If the DOT, USPS, or other
shipping requirements do not apply to
the shipment of the sample, the fol-
lowing information must accompany
the sample:
(1) The name, mailing address, and
telephone number of the originator of
the sample;
(2) The name, address, and tele-
phone number of the facility that will
perform the treatability study;
(3) The quantity of the sample;
37
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§261.4
(4) The date of shipment; and
(5) A description of the sample, in-
cluding its EPA Hazardous Waste
Number.
(iv) The sample is shipped to a labo-
ratory or testing facility which is
exempt under § 261.4(f) or has an ap-
propriate RCRA permit or interim
status.
(v) The generator or sample collec-
tor maintains the following records for
a period ending 3 years after comple-
tion of the treatability study:
(A) Copies of the shipping docu-
ments;
(B) A copy of the contract with the
facility conducting the treatability
study;
(C) Documentation showing:
(1) The amount of waste shipped
under this exemption;
(2) The name, address, and EPA
identification number of the laborato-
ry or testing facility that received the
waste;
(3) The date the shipment was made;
and
(4) Whether or not unused samples
and residues were returned to the gen-
erator.
(vi) The generator reports the infor-
mation required under paragraph
(eXvXC) of this section in its biennial
report.
(3) The Regional Administrator, or
State Director (if located in an author-
ized State), may grant requests, on a
case-by-case basis, for quantity limits
in excess of those specified in para-
graph (e)(2)(i) of this section, for up to
an additional 500 kg of non-acute haz-
ardous waste, 1 kg of acute hazardous
waste, and 250 kg of soils, water, or
debris contaminated with acute haz-
ardous waste, to conduct further treat-
ability study evaluation when: There
has been an equipment or mechanical
failure during the conduct of a treat-
ability study; there is a need to verify
the results of a previously conducted
treatability study; there is a need to
study and analyze alternative tech-
niques within a previously evaluated
treatment process; or there is a need
to do further evaluation of an ongoing
treatability study to determine final
specifications for treatment. The addi-
tional quantities allowed are subject to
all the provisions in paragraphs (e)(l)
40 CFR Ch. I (7-1-92 Edition)
and (e)(2Xii)(vi) of this section. The
generator or sample collector must
apply to the Regional Administrator
in the Region where the sample is col-
lected and provide in writing the fol-
lowing information:
(i) The reason why the generator or
sample collector requires additional
quantity of sample for the treatability
study evaluation and the additional
quantity needed;
(ii) Documentation accounting for
all samples of hazardous waste from
the waste stream which have been
sent for or undergone treatability
studies including the data each previ-
ous sample from the waste stream was
shipped, the quantity of each previous
shipment, the laboratory or testing fa-
cility to which it was shipped, what
treatability study processes were con-
ducted on each sample shipped, and
the available results of each treatabil-
ity study;
(iii) A description of the technical
modifications or change in specifica-
tions which will be evaluated and the
expected results;
(iv) If such further study is being re-
quired due to equipment or mechani-
cal failure, the applicant must include
information regarding the reason for
the failure or breakdown and also in-
clude what procedures or equipment
improvements have been made to pro-
tect against further breakdowns; and
(v) Such other information that the
Regional Administrator considers nec-
essary.
(f) Samples Undergoing Treatability
Studies at Laboratories and Testing
Facilities. Samples undergoing treat-
ability studies and the laboratory or
testing facility conducting such treat-
ability studies (to the extent such fa-
cilities are not otherwise subject to
RCRA requirements) are not subject
to any requirement of this part, part
124, parts 262-266, 268, and 270, or to
the notification requirements of Sec-
tion 3010 of RCRA provided that the
conditions of paragraphs (f) (1)
through (11) of this section are met. A
mobile treatment unit (MTU) may
qualify as a testing facility subject to
paragraphs (f) (1) through (11) of this
section. Where a group of MTUs are
located at the same site, the limita-
tions specified in (f) (1) through (11)
38
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Environmental Protection Agency
§261.4
of this section apply to the entire
group of MTUs collectively as if the
group were one MTU.
(1) No less than 45 days before con-
ducting treatability studies, the facili-
ty notifies the Regional Administra-
tor, or State Director (if located in an
authorized State), in writing that it in-
tends to conduct treatability studies
under this paragraph.
(2) The laboratory or testing facility
conducting the treatability study has
an EPA identification number.
(3) No more than a total of 250 kg of
"as received" hazardous waste is sub-
jected to initiation of treatment in all
treatability studies in any single day.
"As received" waste refers to the waste
as received in the shipment from the
generator or sample collector.
(4) The quantity of "as received"
hazardous waste stored at the facility
for the purpose of evaluation in treat-
ability studies does not exceed 1000 kg,
the total of which can include 500 kg
of soils, water, or debris contaminated
with acute hazardous waste or 1 kg of
acute hazardous waste. This quantity
limitation does not include:
(i) Treatability study residues; and
(ii) Treatment materials (including
nonhazardous solid waste) added to
"as received" hazardous waste.
(5) No more than 90 days have
elapsed since the treatability study for
the sample was completed, or no more
than one year has elapsed since the
generator or sample collector shipped
the sample to the laboratory or testing
facility, whichever date first occurs.
(6) The treatability study does not
involve the placement of hazardous
waste on the land or open burning of
hazardous waste.
(7) The facility maintains records
for 3 years following completion of
each study that show compliance with
the treatment rate limits and the stor-
age time and quantity limits. The fol-
lowing specific information must be in-
cluded for each treatability study con-
ducted:
(i) The name, address, and EPA
identification number of the generator
or sample collector of each waste
sample;
(ii) The date the shipment was re-
ceived;
(iii) The quantity of waste accepted;
(iv) The quantity of "as received"
waste in storage each day;
(v) The date the treatment study
was initiated and the amount of "as
received" waste introduced to treat-
ment each day;
(vi) The date the treatability study
was concluded;
(vii) The date any unused sample or
residues generated from the treatabil-
ity study were returned to the genera-
tor or sample collector or, if sent to a
designated facility, the name of the fa-
cility and the EPA identification
number.
(8) The facility keeps, on-site, a copy
of the treatability study contract and
all shipping papers associated with the
transport of treatability study samples
to and from the facility for a period
ending 3 years from the completion
date of each treatability study.
(9) The facility prepares and submits
a report to the Regional Administra-
tor, or State Director (if located in an
authorized State), by March 15 of
each year that estimates the number
of studies and the amount of waste ex-
pected to be used in treatability stud-
ies during the current year, and in-
cludes the following information for
the previous calendar year:
(i) The name, address, and EPA
identification number of the facility
conducting the treatability studies;
(ii) The types (by process) of treat-
ability studies conducted;
(iii) The names and addresses of per-
sons for whom studies have been con-
ducted (including their EPA identifica-
tion numbers);
(iv) The total quantity of waste in
storage each day;
(v) The quantity and types of waste
subjected to treatability studies;
(vi) When each treatability study
was conducted;
(vii) The final disposition of residues
and unused sample from each treat-
ability study.
(10) The facility determines whether
any unused sample or residues gener-
ated by the treatability study are haz-
ardous waste under § 261.3 and, if so,
are subject to parts 261 through 268,
and part 270 of this chapter, unless
the residues and unused samples are
returned to the sample originator
under the § 261.4(e) exemption.
39
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§261.5
40 CFR Ch. I (7-1-92 Edition)
(11) The facility notifies the Region-
al Administrator, or State Director (if
located in an authorized State), by
letter when the facility is no longer
planning to conduct any treatability
studies at the site.
(Approved by the Office of Management
and Budget under control number 2050-
0088)
[45 PR 33119, May 19, 1980]
EDITORIAL NOTE: For FEDERAL REGISTER ci-
tations affecting § 261.4, see the List of CFR
Sections Affected in the Finding Aids sec-
tion of this volume.
§261.5 Special requirements for hazard-
ous waste generated by conditionally
exempt small quantity generators.
(a) A generator is a conditionally
exempt small quantity generator in a
calendar month if he generates no
more than 100 kilograms of hazardous
waste in that month.
(b) Except for those wastes identi-
fied in paragraphs (e), (f), (g), and (j)
of this section, a conditionally exempt
small quantity generator's hazardous
wastes are not subject to regulation
under parts 262 through 266, 268, and
parts 270 and 124 of this chapter, and
the notification requirements of sec-
tion 3010 of RCRA, provided the gen-
erator complies with the requirements
of paragraphs (f), (g), and (j) of this
section.
(c) Hazardous waste that is not sub-
ject to regulation or that is subject
only to §262.11, §262.12, §262.40(0,
and § 262.41 is not included in the
quantity determinations of this part
and parts 262 through 266, 268, and
270 and is not subject to any of the re-
quirements of those parts. Hazardous
waste that is subject to the require-
ments of § 261.6 (b) and (c) and sub-
parts C, D, and F of part 266 is includ-
ed in, the quantity determination of
this part and is subject to the require-
ments of parts 262 through 266 and
270.
(d) In determining the quantity of
hazardous waste generated, a genera-
tor need not include:
(1) Hazardous waste when it is re-
moved from on-site storage; or
(2) Hazardous waste produced by on-
site treatment (including reclamation)
of his hazardous waste, so long as the
hazardous waste that is treated was
counted once; or
(3) Spent materials that are generat-
ed, reclaimed, and subsequently reused
on-site, so long as such spent materials
have been counted once.
(e) If a generator generates acute
hazardous waste in a calendar month
in quantities greater than set forth
below, all quantities of that acute haz-
ardous waste are subject to full regula-
tion under parts 262 through 266, 268,
and parts 270 and 124 of this chapter,
and the notification requirements of
section 3010 of RCRA:
(DA total of one kilogram of acute
hazardous wastes listed in §§261.31,
261.32, or 261.33(e).
(2) A total of 100 kilograms of any
residue or contaminated soil, waste, or
other debris resulting from the clean-
up of a spill, into or on any land or
water, of any acute hazardous wastes
listed in §§ 261.31, 261.32, or 261.33(e).
[Comment: "Full regulation" means those
regulations applicable to generators of
greater than 1,000 kg of non-acutely hazard-
ous waste in a calendar month.]
(f) In order for acute hazardous
wastes generated by a generator of
acute hazardous wastes in quantities
equal to or less than those set forth in
paragraph (e)(l) or (2) of this section
to be excluded from full regulation
under this section, the generator must
comply with the following require-
ments:
(1) Section 262.11 of this chapter;
(2) The generator may accumulate
acute hazardous waste on-site. If he
accumulates at any time acute hazard-
ous wastes in quantities greater than
those set forth in paragraph (eXl) or
(e)(2) of this section, all of those accu-
mulated wastes are subject to regula-
tion under parts 262 through 266, 268,
and parts 270 and 124 of this chapter,
and the applicable notification re-
quirements of section 3010 of RCRA.
The time period of § 262.34(a) of this
chapter, for accumulation of wastes
on-site, begins when the accumulated
wastes exceed the applicable exclusion
limit;
(3) A conditionally exempt small
quantity generator may either treat or
dispose of his acute hazardous waste
in an on-site facility or ensure delivery
to an of f-site treatment, storage or dis-
40
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Environmental Protection Agency
§261.6
posal facility, either of which, if locat-
ed in the U.S., is:
(i) Permitted under part 270 of this
chapter;
(ii) In interim status under parts 270
and 265 of this chapter;
(iii) Authorized to manage hazard-
ous waste by a State with a hazardous
waste management program approved
under part 271 of this chapter;
(iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
(v) A facility which:
(A) Beneficially uses or reuses, or le-
gitimately recycles or reclaims its
waste: or
(B) Treats its waste prior to benefi-
cial use or reuse, or legitimate recy-
cling or reclamation.
(g) In order for hazardous waste gen-
erated by a conditionally exempt small
quantity generator in quantities of less
than 100 kilograms of hazardous waste
during a calendar month to be ex-
cluded from full regulation under this
section, the generator must comply
with the following requirements:
(1) Section 262.11 of this chapter;
(2) The conditionally exempt small
quantity generator may accumulate
hazardous waste on-site. If he accumu-
lates at any time more than a total of
1000 kilograms of his hazardous
wastes, all of those accumulated
wastes are subject to regulation under
the special provisions of part 262 ap-
plicable to generators of between 100
kg and 1000 kg of hazardous waste in a
calendar month as well as the require-
ments of parts 263 through 266, 268,
and parts 270 and 124 of this chapter,
and the applicable notification re-
quirements of section 3010 of RCRA.
The time period of § 262.34(d) for ac-
cumulation of wastes on-site begins for
a conditionally exempt small quantity
generator when the accumulated
wastes exceed 1000 kilograms;
(3) A conditionally exempt small
quantity generator may either treat or
dispose of his hazardous waste in an
on-site facility or ensure delivery to an
off-site treatment, storage or disposal
facility, either of which, if located in
the U.S., is:
(i) Permitted under part 270 of this
chapter;
(ii) In interim status under parts 270
and 265 of this chapter;
(iii) Authorized to manage hazard-
ous waste by a State with a hazardous
waste management program approved
under part 271 of this chapter;
(iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
(v) A facility which:
(A) Beneficially uses or reuses, or le-
gitimately recycles or reclaims its
waste; or
(B) Treats its waste prior to benefi-
cial use or reuse, or legitimate recy-
cling or reclamation.
(h) Hazardous waste subject to the
reduced requirements of this section
may be mixed with non-hazardous
waste and remain subject to these re-
duced requirements even though the
resultant mixture exceeds the quanti-
ty limitations identified in this section,
unless the mixture meets any of the
characteristics of hazardous waste
identified in subpart C.
(i) If any person mixes a solid waste
with a hazardous waste that exceeds a
quantity exclusion level of this sec-
tion, the mixture is subject to full reg-
ulation.
(j) If a conditionally exempt small
quantity generator's wastes are mixed
with used oil, the mixture is subject to
subpart E of part 266 of this chapter if
it is destined to be burned for energy
recovery. Any material produced from
such a mixture by processing, blend-
ing, or other treatment is also so regu-
lated if it is destined to be burned for
energy recovery.
[51 PR 10174, Mar. 24, 1986, as amended at
51 FR 28682, Aug. 8, 1986; 51 FR 40637, Nov.
7, 1986; 53 PR 27163, July 19, 1988]
§261.6 Requirements for recyclable mate-
rials.
(aXI) Hazardous wastes that are re-
cycled are subject to the requirements
for generators, transporters, and stor-
age facilities of paragraphs (b) and (c)
of this section, except for the materi-
als listed in paragraphs (a)(2) and
(a)(3) of this section. Hazardous
wastes that are recycled will be known
as "recyclable materials."
(2) The following recyclable materi-
als are not subject to the requirements
41
-------
§261.6
40 CFR Ch. I (7-1-92 Edition)
of this section but are regulated under
subparts C through H of part 266 of
this chapter and all applicable provi-
sions in parts 270 and 124 of this chap-
ter:
(i) Recyclable materials used in a
manner constituting disposal (subpart
C);
(ii) Hazardous wastes burned for
energy recovery in boilers and indus-
trial furnaces that are not regulated
under subpart O of part 264 or 265 of
this chapter (subpart H);
(iii) Used oil that exhibits one or
more of the characteristics of hazard-
ous waste and is burned for energy re-
covery in boilers and industrial fur-
naces that are not regulated under
subpart O of part 264 or 265 of this
chapter (subpart E);
(iv) Recyclable materials from which
precious metals are reclaimed (subpart
P);
(v) Spent lead-acid batteries that are
being reclaimed (subpart G).
(3) The following recyclable materi-
als are not subject to regulation under
parts 262 through parts 266 or parts
268, 270 or 124 of this chapter, and are
not subject to the notification require-
ments of section 3010 of RCRA:
(i) Industrial ethyl alcohol that is re-
claimed except that, unless provided
otherwise in an international agree-
ment as specified in § 262.58:
(A) A person initiating a shipment
for reclamation in a foreign country.
and any intermediary arranging for
the shipment, must comply with the
requirements applicable to a primary
exporter in §§ 262.53. 262.56 (a)(l)-(4),
(6), and (b), and 262.57, export such
materials only upon consent of the re-
ceiving country and in conformance
with the EPA Acknowledgment of
Consent as defined in subpart E of
part 262, and provide a copy of the
EPA Acknowledgment of Consent to
the shipment to the transporter trans-
porting the shipment for export;
(B) Transporters transporting a
shipment for export may not accept a
shipment if he knows the shipment
does not conform to the EPA Acknowl-
edgment of Consent, must ensure that
a copy of the EPA Acknowledgment of
Consent accompanies the shipment
and must ensure that it is delivered to
the facility designated by the person
initiating the shipment.
(ii) Used batteries (or used battery
cells) returned to a battery manufac-
turer for regeneration;
(iii) Used oil that exhibits one or
more of the characteristics of hazard-
ous waste but is recycled in some other
manner than being burned for energy
recovery;
(iv) Scrap metal;
(v) Fuels produced from the refining
of oil-bearing hazardous wastes along
with normal process streams at a pe-
troleum refining facility if such wastes
result from normal petroleum refin-
ing, production, and transportation
practices;
(vi) Oil reclaimed from hazardous
waste resulting from normal petrole-
um refining, production, and transpor-
tation practices, which oil is to be re-
fined along with normal process
streams at a petroleum refining facili-
ty;
(viiXA) Hazardous waste fuel pro-
duced from oil-bearing hazardous
wastes from petroleum refining, pro-
duction, or transportation practices, or
produced from oil reclaimed from such
hazardous wastes, where such hazard-
ous wastes are reintroduced into a
process that does not use distillation
or does not produce products from
crude oil so long as the resulting fuel
meets the used oil specification under
§ 266.40(e) of this chapter and so long
as no other hazardous wastes are used
to produce the hazardous waste fuel;
(B) Hazardous waste fuel produced
from oil-bearing hazardous waste from
petroleum refining production, and
transportation practices, where such
hazardous wastes are reintroduced
into a refining process after a point at
which contaminants are removed, so
long as the fuel meets the used oil fuel
specification under § 266.40(e) of this
chapter; and
(C) Oil reclaimed from oil-bearing
hazardous wastes from petroleum re-
fining, production, and transportation
practices, which reclaimed oil is
burned as a fuel without reintroduc-
tion to a refining process, so long as
the reclaimed oil meets the used oil
fuel specification under § 266.40(e) of
this chapter; and
42
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Environmental Protection Agency
§261.7
(viii) Petroleum coke produced from
petroleum refinery hazardous wastes
containing oil at the same facility at
which such wastes were generated,
unless the resulting coke product ex-
ceeds one or more of the characteris-
tics of hazardous waste in part 261,
subpart C.
(b) Generators and transporters of
recyclable materials are subject to the
applicable requirements of parts 262
and 263 of this chapter and the notifi-
cation requirements under section
3010 of RCRA, except as provided in
paragraph (a) of this section.
(c)(l) Owners or operators of facili-
ties that store recyclable materials
before they are recycled are regulated
under all applicable provisions of sub-
parts A through L, AA, and BB of
parts 264 and 265, and under parts
124, 266, 268, and 270 of this chapter
and the notification requirements
under section 3010 of RCRA, except as
provided in paragraph (a) of this sec-
tion. (The recycling process itself is
exempt from regulation except as pro-
vided in § 261.6(d).)
(2) Owners or operators of facilities
that recycle recyclable materials with-
out storing them before they are rcy-
cled are subject to the following re-
quirements, except as provided in
paragraph (a) of this section:
(i) Notification requirements under
section 3010 of RCRA;
(ii) Sections 265.71 and 265.72 (deal-
ing with the use of the manifest and
manifest discrepancies) of this chap-
ter.
(iii) Section 261.6(d) of this chapter.
(d) Owners or operators of facilities
subject to RCRA permitting require-
ments with hazardous waste manage-
ment units that recycle hazardous
wastes are subject to the requirements
of subparts AA and BB of part 264 or
265 of this chapter.
[50 PR 49203, Nov. 29, 1985, as amended at
51 FR 28682, Aug. 8, 1986; 51 PR 40637, Nov.
7, 1986; 52 FR 11821, Apr. 13, 1987; 55 FR
25493, June 21, 1990; 56 FR 7207, Feb. 21,
1991; 56 FR 32692, July 17, 1991]
§261.7 Residues of hazardous waste in
empty containers.
(a)(l) Any hazardous waste remain-
ing in either (i) an empty container or
(ii) an inner liner removed from an
empty container, as defined in para-
graph (b) of this section, is not subject
to regulation under parts 261 through
265, or part 268, 270 or 124 of this
chapter or to the notification require-
ments of section 3010 of RCRA.
(2) Any hazardous waste in either (i)
a container that is not empty or (ii) an
inner liner removed from a container
that is not empty, as defined in para-
graph (b) of this section, is subject to
regulation under parts 261 through
265, and parts 268, 270 and 124 of this
chapter and to the notification re-
quirements of section 3010 of RCRA.
(b)(l) A container or an inner liner
removed from a container that has
held any hazardous waste, except a
waste that is a compressed gas or that
is identified as an acute hazardous
waste listed in §§261.31, 261.32, or
261.33(e) of this chapter is empty if:
(i) All wastes have been removed
that can be removed using the prac-
tices commonly employed to remove
materials from that type of container,
e.g., pouring, pumping, and aspirating,
and
(ii) No more than 2.5 centimeters
(one inch) of residue remain on the
bottom of the container or inner liner,
or
(iiiXA) No more than 3 percent by
weight of the total capacity of the
container remains in the container or
inner liner if the container is less than
or equal to 110 gallons in size, or
(B) No more than 0.3 percent by
weight of the total capacity of the
container remains in the container or
inner liner if the container is greater
than 110 gallons in size.
(2) A container that has held a haz-
ardous waste that is a compressed gas
is empty when the pressure in the con-
tainer approaches atmospheric.
(3) A container or an inner liner re-
moved from a container that has held
an acute hazardous waste listed in
§§ 261.31, 261.32, or 261.33(e) is empty
if:
(i) The container or inner liner has
been triple rinsed using a solvent capa-
ble of removing the commercial chemi-
cal product or manufacturing chemi-
cal intermediate;
(ii) The container or inner liner has
been cleaned by another method that
has been shown in the scientific litera-
43
-------
§ 261.8
40 CFR Ch. I (7-1-92 Edition)
ture, or by tests conducted by the gen-
erator, to achieve equivalent removal;
or
(iii) In the case of a container, the
inner liner that prevented contact of
the commercial chemical product or
manufacturing chemical intermediate
with the container, has been removed.
[45 PR 78529, Nov. 25, 1980, as amended at
47 PR 36097, Aug. 18, 1982; 48 FR 14294,
Apr. 1, 1983; 50 FR 1999, Jan. 14, 1985; 51
FR 40637, Nov. 7, 1986]
§ 261.8 PCB wastes regulated under Toxic
Substance Control Act
The disposal of PCB-containing di-
electric fluid and electric equipment
containing such fluid authorized for
use and regulated under part 761 of
this chapter and that are hazardous
only because they fail the test for the
Toxicity Characteristic (Hazardous
Waste Codes D018 through D043 only)
are exempt from regulation under
parts 261 through 265, and parts 268,
270, and 124 of this chapter, and the
notification requirements of section
3010 of RCRA.
[55 FR 11862, Mar. 29, 1990]
Subport B—Criteria for Identifying
the Characteristics of Hazardous
Waste and for Listing Hazardous
Waste
§ 261.10 Criteria for identifying the char-
acteristics of hazardous waste.
(a) The Administrator shall identify
and define a characteristic of hazard-
ous waste in subpart C only upon de-
termining that:
(DA solid waste that exhibits the
characteristic may:
(i) Cause, or significantly contribute
to, an increase in mortality or an in-
crease in serious irreversible, or inca-
pacitating reversible, illness; or
(ii) Pose a substantial present or po-
tential hazard to human health or the
environment when it is improperly
treated, stored, transported, disposed
of or otherwise managed; and
(2) The characteristic can be:
(i) Measured by an available stand-
ardized test method which is reason-
ably within the capability of genera-
tors of solid waste or private sector
laboratories that are available to serve
generators of solid waste; or
(ii) Reasonably detected by genera-
tors of solid waste through their
knowledge of their waste.
§261.11 Criteria for listing hazardous
waste.
(a) The Administrator shall list a
solid waste as a hazardous waste only
upon determining that the solid waste
meets one of the following criteria:
(1) It exhibits any of the character-
istics of hazardous waste identified in
subpart C.
(2) It has been found to be fatal to
humans in low doses or, in the absence
of data on human toxicity, it has been
shown in studies to have an oral LD 50
toxicity (rat) of less than 50 milli-
grams per kilogram, an inhalation LC
50 toxicity (rat) of less than 2 milli-
grams per liter, or a dermal LD 50 tox-
icity (rabbit) of less than 200 milli-
grams per kilogram or is otherwise ca-
pable of causing or significantly con-
tributing to an increase in serious irre-
versible, or incapacitating reversible,
illness. (Waste listed in accordance
with these criteria will be designated
Acute Hazardous Waste.)
(3) It contains any of the toxic con-
stituents listed in appendix VIII and,
after considering the following factors,
the Administrator concludes that the
waste is capable of posing a substan-
tial present or potential hazard to
human health or the environment
when improperly treated, stored,
transported or disposed of, or other-
wise managed:
(i) The nature of the toxicity pre-
sented by the constituent.
(ii) The concentration of the constit-
uent in the waste.
(iii) The potential of the constituent
or any toxic degradation product of
the constituent to migrate from the
waste into the environment under the
types of improper management consid-
ered in paragraph (a)(3)(vii) of this
section.
(iv) The persistence of the constitu-
ent or any toxic degradation product
of the constituent.
(v) The potential for the constituent
or any toxic degradation product of
the constituent to degrade into non-
44
-------
Environmental Protection Agency
§261.21
harmful constituents and the rate of
degradation.
(vi) The degree to which the constit-
uent or any degradation product of
the constituent bioaccumulates in eco-
systems.
(vii) The plausible types of improper
management to which the waste could
be subjected.
(viii) The quantities of the waste
generated at individual generation
sites or on a regional or national basis.
(ix) The nature and severity of the
human health and environmental
damage that has occurred as a result
of the improper management of
wastes containing the constituent.
(x) Action taken by other govern-
mental agencies or regulatory pro-
grams based on the health or environ-
mental hazard posed by the waste or
waste constituent.
(xi) Such other factors as may be ap-
propriate.
Substances will be listed on appendix
VIII only if they have been shown in
scientific studies to have toxic, carci-
nogenic, mutagenic or teratogenic ef-
fects on humans or other life forms.
(Wastes listed in accordance with
these criteria will be designated Toxic
wastes.)
(b) The Administrator may list class-
es or types of solid waste as hazardous
waste if he has reason to believe that
individual wastes, within the class or
type of waste, typically or frequently
are hazardous under the definition of
hazardous waste found in section
1004(5) of the Act.
(c) The Administrator will use the
criteria for listing specified in this sec-
tion to establish the exclusion limits
referred to in § 261.5(c).
[45 PR 33119, May 19, 1980, as amended at
55 FR 18726, May 4, 1990; 57 FR 14, Jan. 2,
1992]
Subpart C—Characteristics of
Hazardous Waste
§ 261.20 General.
(a) A solid waste, as defined in
§ 261.2, which is not excluded from
regulation as a hazardous waste under
§ 261.4(b), is a hazardous waste if it ex-
hibits any of the characteristics identi-
fied in this subpart.
[Comment: § 262.11 of this chapter sets
forth the generator's responsibility to deter-
mine whether his waste exhibits one or
more of the characteristics identified in this
subpart]
(b) A hazardous waste which is iden-
tified by a characteristic in this sub-
part is assigned every EPA Hazardous
Waste Number that is applicable as sot
forth in this subpart. This number
must be used in complying with the
notification requirements of section
3010 of the Act and all applicable rec-
ordkeeping and reporting require-
ments under parts 262 through 265,
268, and 270 of this chapter.
(c) For purposes of this subpart, the
Administrator will consider a sample
obtained using any of the applicable
sampling methods specified in appen-
dix I to be a representative sample
within the meaning of part 260 of this
chapter.
[Comment. Since the appendix I sampling
methods are not being formally adopted by
the Administrator, a person who desires to
employ an alternative sampling method is
not required to demonstrate the equivalency
of his method under the procedures set
forth in §§ 260.20 and 260.21.]
[45 FR 33119, May 19, 1980, as amended at
51 FR 40636, Nov. 7, 1986; 55 FR 22684,
June 1, 1990; 56 FR 3876, Jan. 31, 1991]
§ 261.21 Characteristic of ignitability.
(a) A solid waste exhibits the charac-
teristic of ignitability if a representa-
tive sample of the waste has any of
the following properties:
(1) It is a liquid, other than an aque-
ous solution containing less than 24
percent alcohol by volume and has
flash point less than 60°C (140"F), as
determined by a Pensky-Martens
Closed Cup Tester, using the test
method specified in ASTM Standard
D-93-79 or D-93-80 (incorporated by
reference, see § 260.11), or a Setaflash
Closed Cup Tester, using the test
method specified in ASTM Standard
D-3278-78 (incorporated by reference,
see §260.11), or as determined by an
equivalent test method approved by
the Administrator under procedures
set forth in §§ 260.20 and 260.21.
(2) It is not a liquid and is capable,
under standard temperature and pres-
sure, of causing fire through friction,
absorption of moisture or spontaneous
45
-------
§261.22
40 CFR Ch. I (7-1-92 Edition)
chemical changes and. when ignited,
burns so vigorously and persistently
that it creates a hazard.
(3) It is an ignitable compressed gas
as defined in 49 CFR 173.300 and as
determined by the test methods de-
scribed in that regulation or equiva-
lent test methods approved by the Ad-
ministrator under §§ 260.20 and 260.21.
(4) It is an oxidizer as defined in 49
CFR 173.151.
(b) A solid waste that exhibits the
characteristic of ignitability has the
EPA Hazardous Waste Number of
D001.
[45 PR 33119, May 19, 1980, as amended at
46 PR 35247. July 7. 1981; 55 PR 22684. June
1,19903
§ 261.22 Characteristic of corrosivity.
(a) A solid waste exhibits the charac-
teristic of corrosivity if a representa-
tive sample of the waste has either of
the following properties:
(1) It is aqueous and has a pH less
than or equal to 2 or greater than or
equal to 12.5, as determined by a pH
meter using either an EPA test
method or an equivalent test method
approved by the Administrator under
the procedures set forth in §§260.20
and 260.21. The EPA test method for
pH is specified as Method 5.2 in "Test
Methods for the Evaluation of Solid
Waste, Physical/Chemical Methods"
(incorporated by reference, see
§ 260.11).
(2) It is a liquid and corrodes steel
(SAE 1020) at a rate greater than 6.35
mm (0.250 Inch) per year at a test tem-
perature of 55°C (130'F) as determined
by the test method specified in NACE
(National Association of Corrosion En-
gineers) Standard TM-01-69 as stand-
ardized in "Test Methods for the Eval-
uation of Solid Waste, Physical/
Chemical Methods" (incorporated by
reference, see § 260.11) or an equiva-
lent test method approved by the Ad-
ministrator under the procedures set
forth in §§ 260.20 and 260.21.
(b) A solid waste that exhibits the
characteristic of corrosivity has the
EPA Hazardous Waste Number of
D002.
[45 PR 33119, May 19, 1980, as amended at
46 PR 35247. July 7.1981; 55 PR 22684, June
1.1990]
§ 261.23 Characteristic of reactivity.
(a) A solid waste exhibits the charac-
teristic of reactivity if a representative
sample of the waste has any of the fol-
lowing properties:
(1) It is normally unstable and read-
ily undergoes violent change without
detonating.
(2) It reacts violently with water.
(3) It forms potentially explosive
mixtures with water.
(4) When mixed with water, it gener-
ates toxic gases, vapors or fumes in a
quantity sufficient to present a danger
to human health or the environment.
(5) It is a cyanide or sulfide bearing
waste which, when exposed to pH con-
ditions between 2 and 12.5, can gener-
ate toxic gases, vapors or fumes in a
quantity sufficient to present a danger
to human health or the environment.
(6) It is capable of detonation or ex-
plosive reaction if it is subjected to a
strong initiating source or if heated
under confinement.
(7) It is readily capable of detona-
tion or explosive decomposition or re-
action at standard temperature and
pressure.
(8) It is a forbidden explosive as de-
fined in 49 CFR 173.51, or a Class A
explosive as defined in 49 CFR 173.53
or a Class B explosive as defined in 49
CFR 173.88.
(b) A solid waste that exhibits the
characteristic of reactivity has the
EPA Hazardous Waste Number of
D003.
[45 PR 33119. May 19. 1980, as amended at
55 PR 22684, June 1.19901
§ 261.24 Toxicity characteristic.
(a) A solid waste exhibits the charac-
teristic of toxicity if, using the test
methods described in appendix II or
equivalent methods approved by the
Administrator under the procedures
set forth in §§ 260.20 and 260.21, the
extract from a representative sample
of the waste contains any of the con-
taminants listed in table 1 at the con-
centration equal to or greater than the
respective value given in that table.
Where the waste contains less than 0.5
percent filterable solids, the waste
itself, after filtering using the method-
ology outlined in appendix II, is con-
46
-------
Environmental Protection Agency
sidered to be the extract for the pur-
pose of this section.
(b) A solid waste that exhibits the
characteristic of toxicity has the EPA
Hazardous Waste Number specified in
Table I which corresponds to the toxic
contaminant causing it to be hazard-
ous.
TABLE 1—MAXIMUM CONCENTRATION OF CON-
TAMINANTS FOR THE TOXICITY CHARACTERIS-
TIC
EPA HW
No.1
••
1
D004
D005
D018
D006
D019
D020
D021
D022
D007
D023
D024
D025
D026
D016
D027
D028
D029
D030
D012
D031
0032
D033
D034
D008
D013
D009
D014
D035
D036
D037
0038
D010
D011
nnoo
D015
D040
D041
D042
D017
D043
Contaminant
Arsenic
Barium
Benzene
Cadmium
Carbon tetrachloride
Chlordane
Chlorobenzene
Chloroform
Chromium
o-Cresol
m-Cresol
Cresol
24-D
1,4-Dichlorobenzene
1,2-Dichloroethane
1 , 1 -Dichloroethylene
2,4-Dinitrotoluene
Heptachlor (and its
epoxide).
Hexachlor obenzene
Hexachlorobutadiene
Lead
Methoxychlor
Methyl ethyl ketone
Pentrachlorophenol
Silver
Trichloroethylene
2,4,5-Trichtorophenol
2,4,6-Trichlorophenol
2 4 5-TP (Silvex)
CAS No *
7440-38-2
7440-39-3
71-43-2
7440-43-9
56-23-5
57-74-9
108-90-7
67-66-3
7440-47-3
95-48-7
108-39-4
106-44-5
94-75-7
106-46-7
107-06-2
75-35-4
121-14-2
72-20-8
76-44-8
118-74-1
87-68-3
67-72-1
7439-92-1
58-89-9
7439-97-6
72-43-5
78-93-3
98-95-3
87-86-5
110-86-1
7782-49-2
7440-22-4
127-18-4
• 8001-35-2
79-01-6
95-95-4
88-06-2
93-72-1
75-01-4
L_ .._„.
Regula-
tory
Level
(mg/L)
5.0
100.0
0.5
1.0
0.5
0.03
100.0
6.0
5.0.
4 200.0
4 200.0
4 200.0
4 200.0
10.0
7.5
0.5
0.7
30.13
0.02
0.008
30.13
0.5
3.0
5.0
0.4
0.2
10.0
200.0
2.0
100.0
3 5.0
1.0
5.0
0.7
0.5
0.5
400.0
2.0
1.0
0.2
1 Hazardous waste number.
2 Chemical abstracts service number.
3 Quantitation limit is greater than the calculated regulatory
level. The quantitation limit therefore becomes the regulatory
level.
§261.30
4 If o-, m-, and p-Cresol concentrations cannot be differen-
tiated, the total cresol (D026) concentration is used. The
regulatory level of total cresol is 200 mg/l.
[55 FR 11862, Mar. 29, 1990, as amended at
55 FR 22684, June 1, 1990; 55 FR 26987,
June 29, 1990]
Subpart D—Lists of Hazardous
Wastes
§ 261.30 General.
(a) A solid waste is a hazardous
waste if it is listed in this subpart,
unless it has been excluded from this
list under §§ 260.20 and 260.22.
(b) The Administrator will indicate
his basis for listing the classes or types
of wastes listed in this subpart by em-
ploying one or more of the following
Hazard Codes:
Ignitable Waste (I)
Corrosive Waste (C)
Reactive Waste (R)
Toxicity Characteristic Waste (E)
Acute Hazardous Waste (H)
Toxic Waste (T)
Appendix VII identifies the constitu-
ent which caused the Administrator to
list the waste as a Toxicity Character-
istic Waste (E) or Toxic Waste (T) in
§§261.31 and 261.32.
(c) Each hazardous waste listed in
this subpart is assigned an EPA Haz-
ardous Waste Number which precedes
the name of the waste. This number
must be used in complying with the
notification requirements of Section
3010 of the Act and certain record-
keeping and reporting requirements
under parts 262 through 265, 268, and
part 270 of this chapter.
(d) The following hazardous wastes
listed in § 261.31 or § 261.32 are subject
to the exclusion limits for acutely haz-
ardous wastes established in § 261.5:
EPA Hazardous Wastes Nos. FO20,
PO21, FO22, PO23, FO26, and FO27.
[45 FR 33119, May 19, 1980, as amended at
48 FR 14294, Apr. 1, 1983; 50 FR 2000, Jan.
14, 1985; 51 FR 40636, Nov. 7, 1986; 55 FR
11863, Mar. 29, 1990]
47
-------
§261.31
40 CFR Ch. I (7-1-92 Edition)
§ 261.31 Hazardous wastes from non-specific sources.
(a) The following solid wastes are listed hazardous wastes from non-specific
sources unless they are excluded under
dix IX.
260.20 and 260.22 and listed in appen-
Industry and EPA hazardous
waste No.
Generic:
F001...
F002..
F003..
F004..
F005..
F006..
FOOT..
F008..
F009..
F010..
F011..
F012..
F019..
F020..
F021,
Hazardous waste
The following spent halogenated solvents used in degreasmg: Tetrachloroethylene,
tnchloroethylene, methylene chloride, 1,1,1-trichloroethane. carbon tetrachloride,
and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreas-
ing containing, before use, a total of ten percent or more (by volume) of one or
more of the above halogenateo solvents or those solvents listed in F002, F004,
and F005; and still bottoms from the recovery of these spent solvents and spent
solvent mixtures.
The following spent halogenated solvents: Tetrachloroethylene, methylene chloride,
trichloroethylene. 1,1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro-1.2,2-trifluor-
oethane, ortho-dichlorobenzene. trichlorofluoromethane, and 1,1.2-trichloroethane;
all spent solvent mixtures/blends containing, before use, a total of ten percent or
more (by volume) of one or more of the above halogenated solvents or those
listed in F001, F004, or F005, and still bottoms from the recovery of these spent
solvents and spent solvent mixtures.
The following spent non-halogenated solvents: Xylene, acetone, ethyl acetate, ethyl
benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, and
methanol; all spent solvent mixtures/blends containing, before use, only the above
spent non-halogenated solvents; and all spent solvent mixtures/blends containing,
before use, one or more of the above non-halogenated solvents, and, a total of
ten percent or more (by volume) of one or more of those solvents listed in F001,
F002, F004, and F005; and still bottoms from the recovery of these spent solvents
and spent solvent mixtures.
The following spent non-halogenated solvents: Cresols and cresylic acid, and
nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of
ten percent or more (by volume) of one or more of the above non-halogenated
solvents or those solvents listed in F001, F002, and F005; and still bottoms from
the recovery of these spent solvents and spent solvent mixtures.
The following spent non-halogenated solvents: Toluene, methyl ethyl ketone, carbon
disulfide, isobutanol, pyridine, benzene, 2-ethoxyethanol. and 2-nitropropane; all
spent solvent mixtures/blends containing, before use, a total of ten percent or
more (by volume) of one or more of the above non-halogenated solvents or those
solvents listed in F001, F002, or F004; and still bottoms from the recovery of
these spent solvents and spent solvent mixtures.
Wastewater treatment sludges from electroplating operations except from the
following processes: (1) Sulfuric acid anodizing of aluminum; (2) tin plating on
carbon steel; (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or
zinc-aluminum plating on carbon steel; (5) cleaning/stripping associated with tin,
zinc and aluminum plating on carbon steel; and (6) chemical etching and milling of
aluminum.
Spent cyanide plating bath solutions from electroplating operations
Plating bath residues from the bottom of plating baths from electroplating operations
where cyanides are used in the process.
Spent stripping and cleaning bath solutions from electroplating operations where
cyanides are used in the process.
Quenching bath residues from oil baths from metal heat treating operations where
cyanides are used in the process.
Spent cyanide solutions from salt bath pot cleaning from metal heat treating
operations.
Quenching waste water treatment sludges from metal heat treating operations where
cyanides are used in the process.
Wastewater treatment sludges from the chemical conversion coating of aluminum
except from zirconium phosphating in aluminum can washing when such phosphat-
ing is an exclusive conversion coating process.
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
from the production or manufacturing use (as a reactant, chemical intermediate, or
component in a formulating process) of tri- or tetrachlorophenol, or of interme-
diates used to produce their pesticide derivatives. (This listing does not include
wastes from the production of Hexachlorophene from highly purified 245-
trichlorophenol.).
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
from the production or manufacturing use (as a reactant chemical intermediate, or
component in a formulating process) of pentachtorophenol, or of intermediates
used to produce its derivatives.
Hazard
code
(T)
(T)
(I)'
(T)
(T)
(R.T)
(R, T)
(R.T)
(R, T)
(R.T)
(T)
(T)
(H)
48
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Environmental Protection Agency
§261.31
Industry and EPA hazardous
waste No.
F022..
Hazardous waste
Hazard
code
F023..
F024..
F025
F026..
F027..
F028..
F032 '
F034
F035 '
F037..
Wastes (except wastewater and spent carbon Irom hydrogen chloride purification)
from the manufacturing use (as a reaclant, chemical intermediate, or component in
a formulating process) of tetia-, penta-, or hexachlorobenzenes under alkaline
conditions.
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
from the production of materials on equipment previously used for the production
or manufacturing use (as a reactant, chemical intermediate, or component in a
formulating process) of tri- and tetractilorophenols. (This listing does not include
wastes from equipment used only for the production or use of Hexachlorophene
from highly purified 2,4,5-trichlorophenol.).
Process wastes, including but not limited to, distillation residues, heavy ends, tars,
and reactor clean-out wastes, from the production of certain chlorinated aliphatic
hydrocarbons by free radical catalyzed processes. These chlorinated aliphatic
hydrocarbons are those having carbon chain lengths ranging from one to and
including five, with varying amounts and positions of chlorine substitution. (This
listing does not include wastewaters, wastewater treatment sludges, spent cata-
lysts, and wastes listed in §261.31 or §261.32).
Condensed light ends, spent fillers and filter aids, and spent desiccant wastes from
the production of certain chlorinated aliphatic hydrocarbons, by free radical
catalyzed processes. These chlorinated aliphatic hydrocarbons are those having
carbon chain lengths ranging from one to and including five, with varying amounts
and positions of chlorine substitution.
Wastes (except wastewater and spent carbon from hydrogen chloride purification)
from the production of materials on equipment previously used for the manufactur-
ing use (as a reactant. chemical intermediate, or component in a formulating
process) ol tetra-, penta-. or hexachlorobenzene under alkaline conditions.
Discarded unused formulations containing tri-. tetra-, or pentachlorophenol or dis-
carded unused formulations containing compounds derived from these chlorophen-
ols. (This listing does not include formulations containing Hexachlorophene sythe-
sized from prepurified 2,4,5-tnchlorophenol as the sole component.)
Residues resulting from the incineration or thermal treatment ol soil contaminated
with EPA Hazardous Waste Nos F020, F021, F022. F023. F026, and F027.
Wastewaters. process residuals, preservative drippage, and spent formulations from
wood preserving processes generated at plants that currently use or have
previously used chlorophenolic formulations (except potentially cross-contaminated
wastes that have had the F032 waste code deleted in accordance with §261.35
of this chapter and where the generator does not resume or initiate use of
chlorophenolic formulations). This listing does not include K001 bottom sediment
sludge from the treatment of wastewater from wood preserving processes that use
creosote and/or pentachlorophenol. (NOTE: The listing of wastewaters that have
not come into contact with process contaminants is stayed administratively. The
listing for plants that have previously used chlorophenoltc formulations is adminis-
tratively stayed whenever these wastes are covered by the F034 or F035 listings.
These stays will remain in effect until further administrative action is taken.).
Wastewaters, process residuals, preservative drippage, and spent formulations from
wood preserving process generated at plants that use creosote formulations. This
listing does not include K001 bottom sediment sludge from the treatment of
wastewater from wood preserving processes that use creosote and/or pentachlor-
ophenol. (NOTE: The listing of wastewaters that have not come into contact with
process contaminants is stayed administratively. The stay will remain in effect until
further administrative action is taken.).
Wastewaters, process residuals, preservative drippage, and spent formulations from
wood preserving process generated at plants that use inorganic preservatives
containing arsenic or chromium. This listing does not include K001 bottom
sediment sludge from the treatment of wastewater from wood preserving process-
es that use creosote and/or pentachlorophenol. (NOTE: The listing of wastewaters
that have not come into contact with process contaminants is stayed administra-
tively. The stay will remain in effect until further administrative action is taken.).
Petroleum refinery primary oil/water/solids separation sludge—Any sludge generated
from the gravitational separation of oil/water/solids during the storage or treat-
ment of process wastewaters and oily cooling wastewaters from petroleum
refineries. Such sludges include, but are not limited to, those generated in: oil/
water/solids separators; tanks and impoundments, ditches and other conveyances;
sumps; and stormwater units receiving dry weather flow. Sludge generated in
stormwater units that do not receive dry weather flow, sludges generated from
non-contact once-through cooling waters segregated for treatment from other
process or oily cooling waters, sludges generated in aggressive biological treat-
ment units as defined in § 261.31(b)(2) (including sludges generated in one or
more additional units after wastewaters have been treated in aggressive biological
treatment units) and K051 wastes are not included in this listing.
(H)
(H)
(T)
(T)
(H)
(H)
(T)
(T)
(T)
(T)
(T)
49
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§261.31
40 CFR Ch. I (7-1-92 Edition)
Industry and EPA hazardous
waste No.
Hazardous waste
Hazard
code
F038..
F039..
Petroleum refinery secondary (emulsified) oil/water/solids separation sludge—Any
sludge and/or float generated from the physical and/or chemical separation of oil/
water/solids in process wastewaters and oily cooling wastewaters from petroleum
refineries. Such wastes include, but are not limited to. all sludges and floats
generated in: induced air flotation (IAF) units, tanks and impoundments, and all
sludges generated in OAF units. Sludges generated in stormwater units that do not
receive dry weather flow, sludges generated from non-contact once-through
cooling waters segregated for treatment from other process or oily cooling waters,
sludges and floats generated in aggressive biological treatment units as defined in
§261.31(b)(2) (including sludges and floats generated in one or more additional
units after wastewaters have been treated in aggressive biological treatment units)
and F037, K048, and K051 wastes are not included in this listing.
Leachate (liquids that have percolated through land disposed wastes) resulting from
the disposal of more than one restricted waste classified as hazardous under
subpart D of this part. (Leachate resulting from the disposal of one or more of the
following EPA Hazardous Wastes and no other Hazardous Wastes retains its EPA
Hazardous Waste Number(s): F020. F021, F022. F026, F027, and/or F028.).
(T)
(T)
1 The F032, F034, and F305 listings are administratively stayed with respect to the process area receiving drippage of these
wastes provided persons desiring to continue operating notify EPA by August 6, 1991 of their intent to upgrade or install drip
pads, and by November 6, 1991 provide evidence to EPA that they have adequate financing to pay for drip pad upgrades or
installation, as provided in the administrative stay. The stay of the listings will remain in effect until February 6, 1992 for
existing drip pads and until May 6, 1992 for new drip pads.
*(I,T) should be used to specify mixtures containing ignitable and toxic constituents.
(b) Listing Specific Definitions: (1) For the purposes of the P037 and P038 list-
ings, oil/water/solids is defined as oil and/or water and/or solids.
(2) (i) For the purposes of the F037 and F038 listings, aggressive biological
treatment units are defined as units which employ one of the following four
treatment methods: activated sludge; trickling filter; rotating biological contac-
tor for the continuous accelerated biological oxidation of wastewaters; or high-
rate aeration. High-rate aeration is a system of surface impoundments or tanks,
in which intense mechanical aeration is used to completely mix the wastes, en-
hance biological activity, and (A) the units employs a minimum of 6 hp per mil-
lion gallons of treatment volume; and either (B) the hydraulic retention time of
the unit is no longer than 5 days; or (C) the hydraulic retention time is no
longer than 30 days and the unit does not generate a sludge that is a hazardous
waste by the Toxicity Characteristic.
(ii) Generators and treatment, storage and disposal facilities have the burden
of proving that their sludges are exempt from listing as F037 and F038 wastes
under this definition. Generators and treatment, storage and disposal facilities
must maintain, in their operating or other onsite records, documents and data
sufficient to prove that: (A) the unit is an aggressive biological treatment unit as
defined in this subsection; and (B) the sludges sought to be exempted from the
definitions of F037 and/or F038 were actually generated in the aggressive bio-
logical treatment unit.
(3) (i) For the purposes of the F037 listing, sludges are considered to be gener-
ated at the moment of deposition in the unit, where deposition is defined as at
least a temporary cessation of lateral particle movement.
(ii) For the purposes of the F038 listing,
(A) sludges are considered to be generated at the moment of deposition in the
unit, where deposition is defined as at least a temporary cessation of lateral par-
ticle movement and
(B) floats are considered to be generated at the moment they are formed in
the top of the unit.
[46 PR 4617. Jan. 16, 1981]
EDITORIAL NOTE: For FEDERAL REGISTER citations affecting § 261.31, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
50
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Environmental Protection Agency
§261.32
§ 261.32 Hazardous wastes from specific sources.
The following solid wastes are listed hazardous wastes from specific sources
unless they are excluded under §§ 260.20 and 260.22 and listed in appendix IX.
Industry and EPA hazardous
waste No.
Hazardous waste
Wood preservation: K001 1 Bottom sediment sludge from the treatment of wastewaters from wood preserving
processes that use creosote and/or pentachlorophenol.
Inorganic pigments:
K002
K003.
K004.
K005.
K006.
K007
K008
Organic chemicals:
K009
K010
K011
K013
K014
K015
K016
K017
Wastewater treatment sludge from the production of chrome yellow and orange
pigments.
Wastewater treatment sludge from the production of molybdate orange pigments
Wastewater trealment sludge from the production of zinc yellow pigments
Wastewater treatment sludge from the production of chrome green pigments
Wastewater treatment sludge from the production of chrome oxide green pigments
(anhydrous and hydrated).
Wastewater treatment sludge from the production of iron blue pigments
Oven residue from the production of chrome oxide green pigments
K018.
K019.
K020.
K021 ....
K022....
K023....
K024....
K025....
K026....
K027....
K028 ....
K029.
K030.
K083
K085
K093
K094
K095
K096
K103.
K104.
K105.
K107.
K108.
K109.
K110.
K111 .
K112.
K113.
K114.
Distillation bottoms from the production of acetaldehyde from ethylene
Distillation side cuts from the production of acetaldehyde from ethylene
Bottom stream from the wastewater stripper in the production of acrylonitrile
Bottom stream from the acetonitnle column in the production of acrylonitrile
Bottoms from the acetonitnle purification column in the production of acrylonitrile
Still bottoms from the distillation of benzyl chloride
Heavy ends or distillation residues from the production of carbon tetracnloride
Heavy ends (still bottoms) from the purification column in the production of
epichlorohydrin.
Heavy ends from the fractionation column in ethyl chloride production
Heavy ends from the distillation of ethylene dichloride in ethylene dichloride
production.
Heavy ends from the distillation of vinyl chloride in vinyl chloride monomer
production.
Aqueous spent antimony catalyst waste from fluoromethanes production
Distillation bottom tars from the production of phenol/acetone from cumene
Distillation light ends from the production of phthatic anhydride from naphthalene
Distillation bottoms from the production of phthalic anhydride from naphthalene
Distillation bottoms from the production of nitrobenzene by the nitration of benzene....
Stripping still tails from the production of methy ethyl pyridines
Centrifuge and distillation residues trom toluene dusocyanate production
Spent catalyst from the hydrochlorinator reactor in the production of 1,1,1-trichlor-
oethane.
Waste from the product steam stripper in the production of 1,1,1-trichloroethane
Column bottoms or heavy ends from the combined production of trichloroethylene
and perchloroethylene.
Distillation bottoms from aniline production
Distillation or fractionation column bottoms from the production of chlorobenzenes
Distillation light ends from the production of phthalic anhydride from ortho-xylene
Distillation bottoms from the production of phthalic anhydride from ortho-xylene
Distillation bottoms from the production of 1,1,1-trlchloroethane
Heavy ends from the heavy ends column from the production of 1,1,1-trichloroeth-
ane.
Process residues from aniline extraction from the production of aniline
Combined wastewater streams generated from nitrobenzene/aniline production
Separated aqueous stream from the reactor product washing step in the production
of chlorobenzenes.
Column bottoms from product separation from the production of 1,1-dimethyl-
hydrazine (IJDMH) from carboxylic acid hydrazine?
Condensed column overheads from product separation and condensed reactor vent
gases from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid
hydrazides.
Spent filter cartridges from product purification from the production of 1,1-dimethylhy-
drazine (UDMH) from carboxylic acid hydrazides.
Condensed column overheads from intermediate separation from the production of
1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides.
Product wash waters from the production of dinitrotoluene via nitration of toluene
Reaction by-product water from the drying column in the production of toluenedia-
mine via hydrogenation of dinitrotoluene.
Condensed liquid light ends from the purification of toluenediamine in the production
of toluenediamine via hydrogenation of dinitrotoluene.
Vicinals from the purification of toluenediamine in the production of toluenediamine
via hydrogenation of dinitrotoluene.
Hazard
code
(T)
(T)
(T)
(T)
(T)
(T)
CD
(T)
(T)
(T)
(R, T)
(R, T)
(T)
(T)
(T)
(T)
(T)
(T)
m
(T)
(T)
(T)
(T)
(T)
(R, T)
(T)
(T)
(T)
(T)
(T)
m
(T)
(T)
(T)
(T)
(T)
(T)
(C,T)
d.T)
(T)
(T)
(C,T)
(T)
(T)
(T)
51
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§ 261.32
40 CFR Ch. I (7-1-92 Edition)
Industry and EPA hazardous
waste No.
K115
K116
K117
K118
K136
Inorganic chemicals:
K071
K073
K106
Pesticides:
K031
K032
K033
K034
K035
K036
K037
K038
K039
K040
K041
K042
K04S
K097
K098
K099
K123
K124
K125
K126
K131
K132
Explosives:
K044
K045 .. .
K046
K047
Petroleum refining:
K048
K049
K050
K051
K052
Iron and steel:
K061
K062
Primary copper:
K064
Hazardous waste
Heavy ends from the purification of tofcjenediamine m the production of toluenedia-
mme via hydrogenation of dinitrotoluene.
Organic condensate from the solvent recovery column in the production of toluene
dfeocyanate via phosgenation of toluenediamine.
Wastewater from the reactor vent gas scrubber in the production of ethytene
dibromide via brommatton of ethene.
Spent adsorbent solids from purification of ethytene dibromide in the production of
Still bottoms from the purification of ethytene dibromide in the production of ethytene
dibromide via brominatkxi of ethene.
Brine purification muds from the mercury cell process in chlorine production, where
separately prepurified brine is not used.
Chlorinated hydrocarbon waste from the purification step of the diaphragm cell
process using graphite anodes in chlorine production.
Wastewater treatment sludge from the mercury cell process in chlorine production
By-product salts generated in the production of MSMA and cacodyltc acid
Wastewater treatment sludge from the production of chlordane
Wastewater and scrub water from the chlorinatkxi of cyclopentadiene in the
production of chlordane.
Filter solids from the filtration of hexachlorocyclopentadiene in the production of
chlordane.
Wastewater treatment sludges generated in the production of creosote
Still bottoms from toluene reclamation distillation in the production of disulfoton
Wastewater treatment sludges from the production of disulfoton
Wastewater from the washing and stripping of phorate production
Filter cake from the filtration of diethylphosphorodithioic acid in the production of
phorate.
Wastewater treatment sludge from the production of phorate
Wastewater treatment sludge from the production of toxaphene
Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the
production of 2.4.5-T.
2 6-Dtchtorophenol waste from the production of 2.4-D
Vacuum stripper discharge from the chlordane chlorinator in the production of
chlordane.
Untreated process wastewater from the production of toxaphene
Untreated wastewater from the production of 2,4-D
Process wastewater (including supemates. filtrates, and washwaters) from the
production of ethytenebisdithiocarbamic acid and its salt.
Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid
and its salts.
Filtration evaporation, and centrifugation solids from the production of ethylenebis-
dithiocarbamic acid and its salts
Baghouse dust and floor sweepings in milling and packaging operations from the
production or formulation of ethytenebisdithiocarbamic acid and its salts.
Wastewater from the reactor and spent sulfuric acid from the acid dryer from the
production of methyl bromide.
Spent absorbent and wastewater separator solids from the production of methyl
bromide.
Wastewater treatment sludges from the manufacturing and processing of explosives ..
Spent carbon from the treatment of wastewater containing explosives
Wastewater treatment sludges from the manufacturing formulation and loading of
lead-based initiating compounds.
Pink/red water from TNT operations
Dissolved air flotation (DAF) float from the petroleum refining industry
Slop oil emulsion solids from the petroleum refining industry
Heat exchanger bundle cleaning sludge from the petroleum refining industry
API separator sludge from the petroleum refining industry
Tank bottoms (leaded) from the petroleum refining industry
Emission control dust/sludge from the primary production of steel in electric
furnaces.
Spent pickle liquor generated by steel finishing operations of facilities within the iron
and steel industry (SIC Codes 331 and 332).
Acid plant btowdown slurry/sludge resulting from the thickening of blowdown slurry
from primary copper production.
Hazard
code
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
0")
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(C, T)
(T)
(T)
(C, T)
m
(R)
(R)
(T)
(R)
(T)
(T)
(T)
(T)
(T)
(T)
(C.T)
(T)
52
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Environmental Protection Agency
§261.33
Industry and EPA hazardous
waste No.
Primary lead:
K065
Primary zinc:
K066.. .
Primary aluminum:
K088..
Ferroalloys:
K090
K091
Secondary lead.
K069
K100
Veterinary Pharmaceuticals:
K084
K101
K102
Ink formulation:
K086
Coking:
K060
K087
Hazardous waste
Surface impoundment solids contained in and dredged from surface impoundments
at primary lead smelting facilities
Sludge from treatment of process wastewater and/or acid plant blowdown from
primary zinc production.
Spent potliners from primary aluniinunr reduction
Emission control dust or sludge from ferrochromiumsiiicon production
Emission control dust or sludge from ferrochromium production
Emission control dust/sludge from secondary lead smelting. (NOTE: This listing is
stayed administratively for sludge generated from secondary acid scrubber sys-
tems. The stay will remain in effect until further administrative action is taken. If
EPA takes further action effecting this stay, EPA will publish a notice of the action
in the Federal Register.
Waste leaching solution from acid leaching of emission control dust/sludge from
secondary lead smelting.
Wastewater treatment sludges generated during the production of veterinary Pharma-
ceuticals from arsenic or organo-arsenic compounds.
Distillation tar residues from the distillation of aniline-based compounds in the
production of veterinary Pharmaceuticals from arsenic or organo-arsenic com-
pounds.
Residue from the use of activated carbon for decolorization in the production of
veterinary Pharmaceuticals from arsenic or organo-arsenic compounds.
Solvent washes and sludges, caustic washes and sludges, or water washes and
sludges from cleaning tubs and equipment used in the formulation of ink from
pigments, driers, soaps, and stabilizers containing chromium and lead.
Ammonia still lime sludge from coking operations
Decanter tank tar sludge from coking operations
Hazard
code
(T)
(T)
(T)
(T)
(T)
ft)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
[46 FR 4618, Jan. 16, 1981]
EDITORIAL NOTE: For FEDERAL REGISTER citations affecting § 261.32, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
§261.33 Discarded commercial chemical
products, off-specification species, con-
tainer residues, and spill residues
thereof.
The following materials or items are
hazardous wastes if and when they are
discarded or intended to be discarded
as described in § 261.2(a)(2)(i), when
they are mixed with waste oil or used
oil or other material and applied to
the land for dust suppression or road
treatment, when they are otherwise
applied to the land in lieu of their
original intended use or when they are
contained in products that are applied
to the land in lieu of their original in-
tended use, or when, in lieu of their
original intended use, they are pro-
duced for use as (or as a component
of) a fuel, distributed for use as a fuel,
or burned as a fuel.
(a) Any commercial chemical prod-
uct, or manufacturing chemical inter-
mediate having the generic name
listed in paragraph (e) or (f) of this
section.
(b) Any off-specification commercial
chemical product or manufacturing
chemical intermediate which, if it met
specifications, would have the generic
name listed in paragraph (e) or (f) of
this section.
(c) Any residue remaining in a con-
tainer or in an inner liner removed
from a container that has held any
commercial chemical product or man-
ufacturing chemical intermediate
having the generic name listed in
paragraphs (e) or (f) of this section,
unless the container is empty as de-
fined in § 261.7(b) of this chapter.
[Comment. Unless the residue is being bene-
ficially used or reused, or legitimately recy-
cled or reclaimed; or being accumulated,
stored, transported or treated prior to such
use, re-use, recycling or reclamation, EPA
53
-------
§261.33
considers the residue to be intended for dis-
card, and thus, a hazardous waste. An exam-
ple of a legitimate re-use of the residue
would be where the residue remains in the
container and the container is used to hold
the same commercial chemical product or
manufacturing chemical intermediate it pre-
viously held. An example of the discard of
the residue would be where the drum is sent
to a drum reconditioner who reconditions
the drum but discards the residue.]
(d) Any residue or contaminated soil,
water or other debris resulting from
the cleanup of a spill into or on any
land or water of any commercial
chemical product or manufacturing
chemical intermediate having the ge-
neric name listed in paragraph (e) or
(f) of this section, or any residue or
contaminated soil, water or other
debris resulting from the cleanup of a
spill, into or on any land or water, of
any off-specification chemical product
and manufacturing chemical interme-
diate which, if it met specifications,
would have the generic name listed in
paragraph (e) or (f) of this section.
[Comment The phrase "commercial chemi-
cal product or manufacturing chemical in-
termediate having the generic name listed
in ..." refers to a chemical substance
which is manufactured or formulated for
commercial or manufacturing use which
consists of the commercially pure grade of
40 CFR Ch. I (7-1-92 Edition)
the chemical, any technical grades of the
chemical that are produced or marketed,
and all formulations in which the chemical
is the sole active ingredient. It does not
refer to a material, such as a manufacturing
process waste, that contains any of the sub-
stances listed in paragraph (e) or (f). Where
a manufacturing process waste is deemed to
be a hazardous waste because it contains a
substance listed in paragraph (e) or (f), such
waste will be listed in either §261.31 or
§ 261.32 or will be identified as a hazardous
waste by the characteristics set forth in sub-
part C of this part.]
(e) The commercial chemical prod-
ucts, manufacturing chemical interme-
diates or off-specification commercial
chemical products or manufacturing
chemical intermediates referred to in
paragraphs (a) through (d) of this sec-
tion, are identified as acute hazardous
wastes (H) and are subject to be the
small quantity exclusion defined in
§ 261.5(e).
[Comment For the convenience of the regu-
lated community the primary hazardous
properties of these materials have been indi-
cated by the letters T (Toxicity). and R (Re-
activity). Absence of a letter indicates that
the compound only is listed for acute toxici-
ty.]
These wastes and their correspond-
ing EPA Hazardous Waste Numbers
are:
Haz-
ardous
waste
No.
P023
P002
P067
P058
P002
P003
P070
P004
POOS
P006
P007
P006
P009
P1 19
P099
P010
P012
P011
P011
P012
P038
P036
P054
P067
P013
am*
Chemical
abstracts No.
107-20-0
591-08-2
640-19-7
62-74-8
591-08-2
107-02-8
116-06-3
309-00-2
107-18-6
20859-73-8
2763-46-4
K/14 44 C
SO4-24-S
131-74-8
7803-55-6
506-61-6
7778-39-4
1327-53-3
1303-28-2
1303-28-2
1327-53-3
692-42-2
696-28-6
151-56-4
75-55-8
542-62-1
ino_47_a
Substance
Acetaldenyde, chtoro-
A in uli.i.ifflu ftl •*ik..k.M»iM«im]jLjui-aJliLjl\
Acetarrade, N-(anwK>tnioxometnyi)-
Acetamkfe, 2-fluoro-
Acetic add, fluoro-, sodium salt
l-Acety<-2-thiourea
Acrotan
AKScarb
AkJrin
ASy! alcohol
Aluminum phosphide (R.T)
5-{Arnirx>methyQ-3-isoxazolol
A AjmliuullHlllilll'l
4-Amnopyrane
Ammonium pfcrate (H)
Ammonium vanadate
ArgentateU-). bis(cyano-C)-, potassium
Arsenic add H>AsO4
Arsenic oxide AStOi
Aisenic oxide As>Oi
Arsenic pentoxide
Arsenic trioxide
Arsine, dtalhyl-
Arsonous dKNoride, phenyt-
Azmtne
Aariome, 2-methyl-
Barium cyanide
54
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
P077
P028
P042
P046
POM
P001
P028
P015
P017
P018
P045
P021
P021
P022
P095
P023
P024
P026
P027
P029
P029
P030
P031
P033
P033
P034
P016
P036
P037
P038
P041
P040
P043
P004
P060
P037
P051
POM
P046
P047
P048
P020
P065
P111
P039
P049
P050
P088
P051
P051
P042
P031
P066
P101
P054
P097
P056
P057
P058
P085
P059
P082
Chemical
abstracts No.
100-01-6
100-44-7
51-43-4
122-09-8
108-98-5
1 81-81-2
100-44-7
7440-41-7
598-31-2
357-57-3
39196-18-4
592-01-8
592-01-8
75-15-0
75-44-5
107-20-0
106-47-8
5344-82-1
542-76-7
544-92-3
544-92-3
460-19-5
506-77-4
506-77-4
131-89-5
542-88-1
696-26-6
60-57-1
692-42-2
311-45-5
297-97-2
55-91-4
309-00-2
465-73-6
60-57-1
'72-20-8
60-51-5
122-09-8
•534-52-1
51-28-5
88-85-7
152-16-9
107-49-3
296-04-4
541-53-7
115-29-7
145-73-3
72-20-8
72-20-8
51-43-4
460-19-5
16752-77-5
107-12-0
151-56-4
52-85-7
7782-41-4
640-19-7
62-74-8
626-86-4
76-44-8
757-58-4
Substance
Benzenamine, 4-nitro-
Benzene, (chtorometfiyl)-
1,2-Benzenediol. 4-t1-hydroxy-2-(methylamino)ethyl]-, (R)-
Benzeneethanamine. alpha.alpha-dimethyl-
Benzenethiol
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present at concentrations
greater than 0.3%
Benzyl chloride
Beryllium
Bromoacetone
Brutine
2-Butanone. 3.3-o*netfiyM-(rnethyNhioh
O-Cmethylamino)carbonyli oxime
Cakaum cyanide
CaWum cyanide Ca(CN)»
Carbon disuffide
Carbonic dwhtoride
p-CMoroanifine
HoOptorophenyQthiourea
3-unloropropionrirHe
Copper cyanide
Cyanogen
2-CyctohexyM.6-dinrtrophenol
DicNonxnelhyl ether
DMdrin
Dtethyiaraine
O.O-Oietriyi O-pyrazinyl phosphorothioate
1,4.5.8«rnetrianonaprithalene. 1^.3,4,10,10-hexa- chtofo-l.4.4a,5.8.8a.-hexahydro-,
1,4.5.^Oimethanonaphthatene. lA3,4,l0.10-h*xa- chtoro-1,4.4a,5.8,e»nexariydro-.
(1 alpha,4alpha,4abeta,5beta,8beta3abeta)-
2.7:3,6-Dimethanonaphth C2,3-blox»ene. 3.4,5.6,9.»-hexachtoro-1a^^a,3,6,6a.7,7a-octanydro-.
OMnetnoate
4.6-Oinrtro-o-cre«o(, A salts
2,4-Oinitrophenol
Oinoseb
UapfKMpnoranwie, ocwnemyt-
nkilvMUahnrir Arkl t Atf*Attnil mmtat
Dfeurfoton
Drthiobiuret
Endosultan
EndothaN
Endrin
Endnn, & metaboWes
Epviephnne
r^[C(methyamino)carbonyl}oxy3-, methyl ester
Ethyl cyanide
cthyfooeifnne
Famphur
Fluorine
Fluoroacetamide
Fluoroacetic acid, sodum salt
Fuhninic acid, mercury(2-t-) aalt (R,T)
Heptachtor
55
311-147 O—92-
-------
§ 261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
P116
P068
P063
P063
P096
P060
P007
P092
P065
P082
P064
P016
P112
P118
P050
P059
P066
P068
P064
P069
P071
P072
P073
P073
P074
P074
P075
P076
^&\w
P077
P078
P076
P078
P081
P082
•mfc«« *
P084
P065
P067
P087
P068
P069
P034
P048
P047
P020
P009
P092
P093
P094
P09S
P096
P041
P039
P094
P044
P043
P089
P040
P097
P071
P110
P098
P098
P099
P070
Chemical
abstracts No.
79-19-6
60-34-4
74-90-8
74-90-8
7803-51-2
465-73-6
2763-96-4
62-38-4
628-86-4
62-75-9
624-83-9
542-88-1
509-14-8
75-70-7
115-29-7
76-44-8
16752-77-5
60-34-4
624-83-9
75-86-5
298-00-0
m»po_4
OO"OO~^
13463-39-3
13463-39-3
557-19-7
557-19-7
'54-11-5
10102-43-9
< A/\rt4 *»
1UU-U1-O
10102-44-0
10102-43-9
10102-44-0
55-63-0
62-75-9
jlCjtQ Af\_f\
454»— 4O-O
152-16-9
20816-12-0
20816-12-C
145-73-3
56-38-2
131-89-5
51-28-5
'534-52-1
88-85-7
131-74-8
62-38-4
103-85-5
298-02-2
75-44-5
7803-51-2
311-45-5
296-O4-4
298-02-2
60-51-5
55-91-4
56-38-2
297-97-2
52-85-7
298-00-0
78-00-2
151-50-8
151-50-8
506-61-6
116-06-3
Substance
Hydrazinecarbothioamide
Hydrazine, methyl-
Hydrocyanic acid
Hydrogen cyanide
Hydrogen phosphide
sodrin
3(2H)-lsoxazotone, 5-(aminomethyl)-
Mercury, (acetato-O)phenyl-
Mercury fulminate (R,T)
Methanamine. N-methyl-N-nitroso-
Methane, isocyanato-
Methane, oxybistchkxo-
Methane, tetranitro- (R)
Methanethiol, trichtoro-
6,9-Methano-2,4.3-benzodioxathiepin. 6,7.8,9.10,10-
hexachkxo-1l5.5a.6,9.9a-hexahydro-, 3-oxide
4,7-Methanc-1H-indene, 1.4,5,6,7.8,8-heptachloro-
3a,4.7.7a-tetrahydro-
Methomyl
Methyl hydrazine
Methyl isocyanate
2-Methyllactonitrile
Methyl paratnion
alpha-Naphthytthiourea
Nickel carbonyl
Nickel carbonyl NKCO),, (T-4)-
Nickel cyanide
Nickel cynakte NKCN),
Nicotine, & salts
Nitric oxide
p-Nitroanihne
Nrtrogen dwxide
Nitrogen oxide NO
Nitrogen oxide NOi
Nrtroglycenne (R)
N-Nitrosodimethytamine
N*NilmsomethylvinylarrHoe
C)ctarnethylpyrophospnoramide
Osmium oxide OsO4, (T-4)-
Osmium tetroxide
7-C)xatiicy<^[22.11twptane-2.3-dKart>oxylic acid
Paratnion
Phenol. 2-cyctohexyM,6K»nrtro-
Phenol. 2,4-dinitro-
Phenol. 2-methyl-4.6-dinitrc-. & salts
Phenol, 2-(1-rr«thylpropyl)-4.6-o1nitro-
Phenol, 2,4,6-trinitro-, ammonium salt (R)
Phenyhnercury acetate
Phenytthiourea
Phorate
Phosgene
PhospNne
Phosphoric acid, dtethyl 4-nrtropnenyl ester
Pnosphorodrthioic acid. O.O-diethyl
S-C2-(ethylthio)ethyl] ester
nil ml, ilumtjlilltijiij'i tt/*fH C\ fl llillllllll
pnospnoroonreoic acxi. (j.ixaeinyi
S-C(ethytthio)methyl) ester
Pnosphorodrthioic acid. O.O-dimethyl S-[2-(methylarnino)-2-oxoetfiylJ ester
Phosphorofluoridic acid. bis(1-methylethyl) ester
Phospnorothioic acid, O.O-diethyl O-<4-nrtrophenyl) ester
Phosphorothioic acid. O.O-diethyl Opyrazinyl ester
Phospnorothioic acid,
O-[4-[(dimethylamino)sulfonyl]phenyl] O.O-dwnethyl ester
Phosphorothioic acid, O.O,-dimethyl O-(4-nrtrophenyt) ester
Ptumbane, tetraettiyl-
Potassium cyanide
Potassium cyanide K(CN)
Potassium silver cyanide
Propanal. 2-methyl-2-(methytthio)-,
O-t(methylamino)carbonyl]oxime
56
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
P101
P027
P069
P081
P017
P102
P003
POOS
P067
P102
P008
P075
P114
P103
P104
P104
P105
P106
P106
P108
P018
P108
P116
P109
P110
P111
P112
P062
P113
P113
P114
P115
P109
P045
P049
P014
P116
P026
P072
P093
P123
P118
P119
P120
P120
P084
P001
P121
P121
P122
Chemical
abstracts No.
107-12-0
542-76-7
75-86-5
55-63-0
598-31-2
107-19-7
107-02-8
107-18-6
75-55-8
107-19-7
504-24-5
'54-11-5
12039-52-0
630-10-4
506-64-9
506-64-9
26628-22-8
143-33-9
143-33-9
1 57-24-9
357-57-3
1 57-24-9
7446-18-6
3689-24-5
78-00-2
107-49-3
509-14-8
757-58-4
1314-32-5
1314-32-5
12039-52-0
7446-18-6
3689-24-5
39196-18-4
541-53-7
108-98-5
79-19-6
5344-82-1
86-88-4
103-85-5
8001-35-2
75-70-7
7803-55-6
1314-62-1
1314-62-1
4549-40-0
'81-81-2
557-21-1
557-21-1
1314-84-7
Substance
Propaneratnle
Propanenitrite, 3-chkxo-
Propaneortrite, 2-hydroxy-2-methyl-
1,2,3-Propanetriol. trinitrate (R)
2-Propanone, 1-bromc-
Propargyl alcohol
2-Propenal
2-Propen-1-ol
1 ,2-Propylenimine
2-Propyn-1-ol
4-Pyrtdinamine
Pyridine. 3-(1-mettiyl-2-pyrroltdinyl)-, (S)-, & salts
Selenkxis acid, dithallium(l +) salt
Selenourea
Silver cyanide
Silver cyanide Ag(CN)
Sodium azkte
Sodium cyanide
Sodium cyanide Na(CN)
Strychnidin-10-one, & salts
Strychnidin-10-one, 2.3-dimethoxy-
Strychnine, & salts
Sulfuric acid. ditnallium(1 +) salt
Tetraethyldithiopyrophosphate
Tetraethyl lead
Tetraethyl pyrophosphate
Tetranitromethane (R)
Tetraphosphoric acid, hexaethyl ester
Thallic oxide
Thallium oxide TUO,
Thallium(l) selenite
Thallium(l) sulfate
Thiodiphosphoric acid, tetraethyl ester
Thiofanox
Thioimidodicarbonic diamide [(H2N)C(S)LNH
Thiophenol
Thiosemicarbazide
Thiourea, (2-chlorophenyl)-
Thkxirea, 1-naphthalenyl-
Thiourea, phenyt-
Toxaphene
Trichloromethanethiol
Vanadic acid, ammonium salt
Vanadium oxide ViOs
Vanadium pentoxide
Vinylamine, N-methyl-N-nitroso-
Warfarin, & salts, when present at concentrations greater than 0.3%
Zinc cyanide
Zinc cyanide Zn(CN)2
Zinc phosphide ZnjP2, when present at concentrations greater than 10% (R,T)
1 CAS Number given for parent compound only.
(f) The commercial chemical prod-
ucts, manfacturing chemical interme-
diates, or off-specification commercial
chemical products referred to in para-
graphs (a) through (d) of this section,
are identified as toxic wastes (T),
unless otherwise designated and are
subject to the small quantity genera-
tor exclusion defined in § 261.5 (a) and
(g).
[Comment.1 For the convenience of the regu-
lated community, the primary hazardous
properties of these materials have been indi-
cated by the letters T (Toxicity), R (Reac-
tivity), I (Ignitability) and C (Corrosivity).
Absence of a letter indicates that the com-
pound is only listed for toxicity.]
These wastes and their correspond-
ing EPA Hazardous Waste Numbers
are:
57
-------
§ 261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
Chemical
abstracts No.
Substance
U001
U034
U187
U005
U240
U112
U144
U214
see
F027
U002
U003
U004
U005
U006
U007
U008
U009
U011
U012
U136
U014
U015
U010
U157
U016
U017
U192
U018
U094
U012
U014
U049
U093
U328
U353
U1S8
U222
U181
D019
U038
U030
U035
U037
U221
U028
U069
U088
U102
U107
U070
U071
U072
U060
U017
U223
U239
U201
U127
U056
U220
U105
U106
U05S
U169
U183
U185
U020
U020
75-07-0
75-87-6
62-44-2
53-96-3
1 94-75-7
141-78-6
301-04-2
563-68-8
93-76-5
67-64-1
75-05-8
98-86-2
53-96-3
75-36-5
79-O6-1
79-10-7
107-13-1
61-82-5
62-53-3
75-60-5
492-80-8
115-02-6
50-07-7
56-49-5
225-51-4
98-87-3
23950-58-5
56-55-3
57-97-6
62-53-3
492-80-8
3165-93-3
60-11-7
95-53-4
106-49-0
101-14-4
636-21-5
99-55-8
71-43-2
510-15-6
101-55-3
305-03-3
108-90-7
25376-45-8
117-81-7
84-74-2
84-66-2
131-11-3
117-84-0
95-50-1
541-73-1
106-46-7
72-54-8
98-87-3
26471-62-5
1330-20-7
108-46-3
118-74-1
110-82-7
108-88-3
121-14-2
606-20-2
98-82-8
98-95-3
608-93-5
82-68-8
98-09-9
98-09-9
Acetaktehyde (I)
Acetaldehycte, trichkxo-
Acetamkte, N-(4-ethoxyphenyl)-
Acetamide, N-9H-fluoren-2-yl-
Acetic acid, (2,4-dichlorophenoxy)-, salts & esters
Acetic acid ethyl ester (I)
Acetic acid, lead(2+) salt
Acetic acid, thallium(1 +) salt
Acetic acid. (2,4,5-trichlorophenoxy)-
Acetone (I)
Acetonitrite (I,T)
Acetophenone
2-Acetylaminofluorene
Acetyl chloride (C.R.T)
Acrylamkte
Acrylic acid (I)
Acrytonitrile
Amrtrote
Aniline (I,T)
Arsinic acid, dimethyl-
Aurarrune
Azaserine
Azirino[2<,3':3.4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-t[(aminocarbonyl)oxy]methyl]-
1,la,2,8,8a,8b-hexahydro-8a-metnoxy-5-methyl-, [1aS-(laalpha, 8beta,8aalpha,8balpha)]-
Benztjlaceanthrylene, 1,2-dihydro-3-methyl-
Benz[c]acridine
Benzal chloride
Benzamide, 3.5-dichloro-N-(1.1 -dimethyl-2-propynyl)-
BenzCalanthracene
BenzCalanthracene, 7,12-dimethyl-
Benzenamine (I.T)
Benzenamine, 4,4'-carbonimidoylbis[N,N-dimethyl-
Benzenamine, 4-chloro-2-methyl-, hydrochtoride
Benzenamine, N.N-dimethyl-4-(phenylazo)-
Benzenamine, 2-methyl-
Benzenamine, 4-melhyl-
Benzenamine, 4,4'-methytenebis[2-chloro-
Benzenamine, 2-methyl-, hydrochloride
Benzenamine, 2-methyl-5-nitro-
Benzene (I.T)
Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-t ethyl ester
Benzene, 1-bromo-4-phenoxy-
Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-
Benzene, chtoro-
Benzenediamine, ar-methyl-
1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
1,2-Benzenedicarboxylic acid, dibutyl ester
1,2-Benzenedicarboxylic acid, diethyl ester
1,2-Benzenedicarboxylic acid, dimethyl ester
1,2-Benzenedicarboxylic acid, dioctyl ester
Benzene, 1,2-dichloro-
Benzene. 1,3-dichloro-
Benzene, 1,4-dichkxo-
Benzene, 1,1 '-(2,2-dichloroethylidene)bis[4-chloro-
Benzene. (dichloromethyl)-
Benzene, 1,3-diisocyanatomethyl- (R.T)
Benzene, dimethyl- (I.T)
1,3-Benzenediol
Benzene, hexachloro-
Benzene, hexahydro- (I)
Benzene, methyl-
Benzene. 1-methyl-2.4-dinitro-
Benzene, 2-methyl-1,3-dinitro-
Benzene, (1-methylethyl)- (I)
Benzene, nitro-
Benzene, pentachloro-
Benzene, pentachkxonitro-
BenzenesuWonic acid chloride (C.R)
Benzenesulfonyl chloride (C.R)
58
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
Chemical
abstracts No.
Substance
Haz-
ardous
waste
No.
U207
1)061
U247
U023
U234
U021
U202
U203
U141
U090
U064
U248
U022
U197
U023
U085
U021
U073
U091
U095
U225
U030
U128
U172
U031
U159
U160
U053
U074
U143
U031
U136
U032
U236
U178
U097
U114
U062
U215
U033
U1S6
U033
U211
U034
U035
U036
U026
U037
U038
U039
U042
U044
U046
U047
U04B
U049
U032
U050
U051
U052
U053
U055
U246
U197
UOS6
Chemical
abstracts No.
95-94-3
50-29-3
72-43-5
98-07-7
99-35-4
92-87-5
1 81-07-2
94-59-7
120-58-1
94-58-6
189-55-9
'81-81-2
50-32-8
106-51-4
98-07-7
1464-53-5
92-87-5
91-94-1
119-90-4
119-93-7
75-25-2
101-55-3
87-68-3
924-16-3
71-36-3
78-93-3
1338-23-4
4170-30-3
764-41-0
303-34-4
71-36-3
75-60-5
13765-19-0
51-79-6
615-53-2
79-44-7
1 111-54-6
2303-16-4
6533-73-9
353-50-4
79-22-1
353-50-4
56-23-5
75-87-6
305-03-3
57-74-9
494-03-1
108-90-7
510-15-6
59-50-7
110-75-8
67-66-3
107-30-2
91-58-7
95-57-8
3165-93-3
13765-19-0
218-01-9
1319-77-3
4170-30-3
98-82-8
506-68-3
106-51-4
1 10-82-7
Benzene, 1,2,4,5-tetrachloro-
Benzene, 1,1 '-(2,2,2-trichloroethy1idene)bis[4-chloro-
tenzene, 1,1'-(2,2,2-trichloroethylidene)bis[4- methoxy-
lenzene, (trichloromethyl)-
tenzene, 1,3,5-trinitro-
lenzidine
,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, & salts
,3-Benzodioxole, 5-(2-propenyl)-
,3-Benzodioxole, 5-(1 -propenyl)-
,3-Benzodioxole, 5-propyl-
Benzo[rst]pentaphene
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present at concentrations
of 0.3% or toss
3enzo[a]pyrene
Benzoquinone
Benzotrichloride (C,R,T)
2,2'-Bioxirane
1,1 '-Biphenyl]-4,4'-diamine
1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dichloro-
1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-
1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
Jromoform
4-Bromophenyl phenyl ether
1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
1-Butanamine, N-butyl-N-nitroso-
1-Butanol (I)
2-Butanone (I.T)
2-Butanone, peroxide (R,T)
2-Butenal
2-Butene, 1,4-dichloro- (I.T)
2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-
2-(1 -methoxyethyl)-3-methyl-1 -oxobutoxy] methyl ]-
2,3,5,7a-tetrahydro-1 H-pyrrolizin-1 -yl ester,
[ 1 S-[ 1 alpha(Z),7(2S* ,3R*),7aalpha] 1-
n-Butyl alcohol (I)
Cacodylic acid
Calcium chromate
Carbamic acid, ethyl ester
Carbamic acid, methylnitroso-, ethyl ester
Carbamic chloride, dimethyl-
Carbamodithioic acid, 1,2-ethanediylbis-,
salts & esters
Carbamothioic acid, bis(l-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester
Carbonic acid, dithallium(1 +) salt
Carbonic difluoride
Carbonochloridic acid, methyl ester (I.T)
Carbon oxyfluoride (R,T)
Carbon tetrachloride
Chloral
Chlorambucil
Chlordane, alpha & gamma isomers
Chlornaphazin
Chlorobenzene
Chlorobenzilate
p-Chloro-m-cresol
2-Chloroethyl vinyl ether
Chloroform
Chloromethyl methyl ether
beta-Chloronaphthalene
o-Chlorophenol
4-Chloro-c-toluidine, hydrochloride
Chromic acid H2CrO4, calcium salt
Chrysene
Creosote
Cresol (Cresylic acid)
Crotonaldehyde
Cumene (I)
Cyanogen bromide (CN)Br
2,5-Cyclohexadiene-1,4-dione
Cyclohexane (I)
59
-------
§ 261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
U129
U057
U130
U058
U240
U059
U060
U061
U062
U063
U064
U066
U069
U070
U071
U072
U073
U074
U075
U078
U079
U025
U027
U024
U081
UOB2
U084
U085
U10B
U028
U086
U067
U088
U089
U090
U091
U092
U093
U094
U095
U096
U097
U098
U099
U101
U102
U103
U105
U106
U107
uioe
U109
U110
VM1
U041
U001
U174
U155
U067
U076
U077
U131
U024
U117
U02S
U184
U206
U209
i iA«a
Chemical
abstracts No.
58-89-9
108-94-1
77-47-4
50-18-0
'94-75-7
20830-81-3
72-54-8
50-29-3
2303-16-4
53-70-3
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
91-94-1
764-41-0
75-71-8
75-35-4
156-60-5
111-44-4
108-60-1
111-91-1
120-83-2
87-65-0
542-75-6
1464-53-5
123-91-1
117-81-7
1615-60-1
3288-58-2
84-66-2
56-53-1
94-58-6
119-90-4
124-40-3
60-11-7
57-97-6
119-93-7
80-15-9
79-44-7
57-14-7
540-73-8
105-67-9
131-11-3
77-78-1
121-14-2
606-20-2
117-84-0
123-91-1
122-66-7
142-84-7
621-64-7
106-89-8
75-07-0
55-18-5
91-80-5
106-93-4
75-34-3
107-06-2
67-72-1
111-91-1
60-29-7
111-44-4
76-01-7
630-20-6
79-34-5
CO CC C
Substance
Cyclohexane, 1,2,3,4,5,6-hexachloro-,
(1alpha,2alpha,3beta,4alpha,5alpha,6beta)-
Cyctohexaoone (I)
,3-Cydopentadiene, 1,2,3,4,5,5-hexachloro-
Cyclophosphamtde
2.4-0, salts & esters
Daunomycin
ODD
DOT
Diallate
Dibenz[a,h]anthracene
Dibenzo[a,i]pyrene
1 ,2-Dibrorno-3-chloropropane
Dibutyl phthalate
o-Dichtorobenzene
m-Dichlorobenzene
p-Oichlorobenzene
3,3'-Dichlorobenzidine
1,4-Oicrikxo-2-butene (I.T)
Dichkxodifluorometriane
1.1-Dichkxoetriytene
1,2-Dichloroethylene
Dichloroethyl ether
Dtehtoroisopropyl ether
Ochkxomethoxy ethane
2,4-Dichlorophenol
2,6-Dichlorophenol
1 ,3-Dichkxopropene
1.2:3.4-Oiepoxyt>utane (I,T)
1,4-DiethyleneoxKJe
Diethylhexyl phthalate
N,N'-Diethylhydrazine
O.O-Dtethyt S-methyl dithiophosphate
Diethy) phthalate
OiethylstHbesterol
Oinydrosafrole
3.3'-Oimethoxybenzidine
Dimethyiamine (I)
p-Oimethylaminoazobenzene
7.1 2-Dimethytt)en2[a]anthracene
3.3--Dimethylbenzidine
alpha,alpha-Dirnetnylbenzylhydroperoxide (R)
Dimetnytcafbamoyl cnkxide
1 ,1-Oimethylnydrazine
1 ,2-Oimethylhydrazine
2,4-Dimetriytphenol
Dimethyl phthalate
Dimethyl sutfate
2.4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,4-Dioxane
1 ^-Diphenylnydrazine
Dioropylamine (I)
DMvpropytaitrosanvne
Epicnkxohydrin
Ethanal(l)
Ethanamine, N-ethyl-N-nitroso-
1,2-Ethanediamine, N,N-«fimethyl-N^2-pyrklinyl-N'-(2-thienylmethyl)-
Etharte, 1.2-dtofomo-
Ethane. 1.1-dichkxo-
Ethane, 1,2-<*chkxo-
Etnane. hexachtoro-
Ethane, l.1'-[metnylenebis(oxy)]bis[2-chloro-
Ethane. l,1'-oxybis-(l)
Ethane, 1.1'-oxybisl2-chtoro-
Ethane, pentachloro-
Ethane, 1.1.1^-tetrachloro-
Ethane, 1.1^^-tetrachtoro-
l~tln»«il>llli
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
U226
U&7
U359
U173
U004
U043
U042
U078
U079
U210
U228
U112
U113
U238
U117
U114
U067
U077
U359
U115
U116
U076
UJ18
U119
U120
U122
U123
U124
U125
U147
U213
U125
U124
U206
U206
U126
U163
U127
U128
U130
U131
U132
U243
U133
UOB6
U098
U099
U109
U134
U134
U135
U135
U096
U116
U137
U190
U140
U141
U142
U143
U144
U146
U145
U146
U129
U163
U147
U148
U149
Chemical
abstracts No.
71-55-6
79-00-5
110-80-5
1116-54-7
90-86-2
75-01-4
110-75-8
75-35-4
156-60-5
127-18-4
79-01-6
141-78-6
140-88-5
51-79-6
60-29-7
1 111-54-6
106-93-4
107-06-2
110-80-5
75-21-8
96-45-7
75-34-3
97-63-2
62-50-0
206-44-0
50-00-0
64-18-6
110-00-9
98-01-1
108-31-6
109-99-9
98-01-1
110-00-9
18883-66-4
18883-66-4
765-34-4
70-25-7
116-74-1
87-68-3
77-47-4
67-72-1
70-30-4
1888-71-7
302-01-2
1615-80-1
57-14-7
540-73-8
122-66-7
7664-39-3
7664-39-3
7783-06-4
7783-06-4
80-15-9
96-45-7
193-39-5
85-44-9
78-83-1
120-58-1
143-50-0
303-34-4
301-04-2
1335-32-6
7446-27-7
1335-32-6
58-89-9
70-25-7
108-31-6
123-33-1
109-77-3
Substance
Ethane, 1,1,1-trichloro-
Etfwne, 1,1,2-trichtoro-
Ettianol, 2-etrtoxy-
Ethanol, 2,2'-(nitrosoimino)bis-
Ethanone, 1-phenyl-
Ethene, chloro-
Ethene, (2-chloroethoxy)-
Ethene, 1,1-dicti(oro-
Ethene, 1 ,2-dichloro-, (E)-
Ethene, tetracriloro-
Ethene, trictiloro-
Ethyl acetate (1)
Ethyl acrylate (1)
Ethyl carbamate (urethane)
Ethyl ether (1)
Ethylenebisdithiocarbamic acid, sails & esters
Ethylene dibromide
Elhylene dichtoride
Ethytene glycol monoethyl ether
Ethylene oxide (I,T)
Ethytenethiourea
Ethylidene dichloride
Ethyl methacryjate
Ethyl methartesulfonate
-luoranthene
Formaldehyde
Formic acid (C,T)
Furan (1)
2-Furancarboxaldehyde (!)
2.5-Furandione
Furan. tetrafiy*o-(l)
Furfural (1)
Furfuran (1)
Glucopyranose, 2-deoxy-2-(3-methy1-3-nitrosoureido)-, D-
D-Glucose. 2-
-------
§261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
Chemical
abstracts No.
Substance
U1SO
U151
U152
U092
U029
U045
U046
U068
U080
U075
U138
U119
U211
U153
U225
U044
U121
U036
U154
U155
U142
U247
U154
U029
U186
U045
U156
U226
U157
U158
U068
U080
U159
U160
U138
U161
U162
U161
U164
U010
U059
U167
U168
U026
U165
U047
U166
U236
U166
U167
U168
U217
U169
U170
U171
U172
U173
U174
U176
U177
U17B
U179
U180
U181
U193
U058
U115
148-82-3
7439-97-6
126-98-7
124-40-3
74-83-9
74-87-3
107-30-2
74-95-3
75-09-2
75-71-8
74-88-4
62-50-0
56-23-5
74-93-1
75-25-2
67-66-3
75-69-4
57-74-9
67-56-1
91-80-5
143-50-0
72-43-5
67-56-1
74-83-9
504-60-9
74-87-3
79-22-1
71-55-6
56-49-5
101-14-4
74-95-3
75-09-2
78-93-3
1338-23-4
74-88-4
108-10-1
80-62-6
106-10-1
56-04-2
50-07-7
20830-81-3
134-32-7
91-59-8
494-03-1
91-20-3
91-58-7
130-15-4
72-57-1
130-15-4
134-32-7
91-59-8
10102-45-1
98-95-3
100-02-7
79-46-9
924-16-3
1116-54-7
55-18-5
759-73-9
684-93-5
615-53-2
100-75-4
930-55-2
99-55-8
1120-71-4
50-18-0
75-21-8
Melphalan
Mercury
Methacrylonitrile (I, T)
Methanamine, N-methyl- (I)
Methane, bromo-
Methane, chloro- (I. T)
Methane, chkxomethoxy-
Methane, dibromo-
Methane, dichtoro-
Methane, dichlorodifluoro-
Methane, todo-
Methanesulfonic acid, ethyl ester
Methane, tetrachloro-
Methanethiol (I, T)
Methane, tribromo-
Methane, trichloro-
Methane, trichlorofluoro-
4.7-Methano-1H-indene. 1,2.4,5.6.7,8,8-octachloro-2,3.3a.4,7.7a-hexahydro-
Methanol (I)
Methapyrilene
1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1 a,3.3a,4,5.5.5a,5b.6-decachtorooctahydro-
Methoxychtor
Methyl alcohol (I)
Methyl bromide
1-Methylbutadiene (I)
Methyl chloride (I,T)
Methyl chtorocarbonate (I.T)
Methyl chloroform
3-Methyteholanthrene
4,4--Methytenebis(2-chloroaniline)
Methytene bromide
Methytene chloride
Methyl ethyl ketone (MEK) (I,T)
Methyl ethyl ketone peroxide (R.T)
Methyl iodide
Methyl isobutyl ketone (I)
Methyl methacrylate (I.T)
4-Methyl-2-pentanone (I)
Methytthiouracil
-Mrtomycin C
5.12-Naphthacenedione, 8-acetyl-10-[(3-amirK>-2,3,6-trideoxy)-alpha-L-lyxo-hexopyranosyl)oxy]-
7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
1-Naphthalenamine
2-Naphthalenamine
Naphthatenamine, N.N'-bis(2-chkxoettiyl)-
Naphthalerie
Naphthalene, 2-crtloro-
1,4-Naphthalenedk>ne
2.7-Naphthalenedisulfonic acid, 3.3'-[(3,3'-
dimethylll.l'-biDhenyll-4,4'-diyt)bis(azo)btsC5-arnino-4-nydroxy]-, tetrasodium salt
1.4-Naphthoquinone
alpha-Naphthylamine
beta-Naphthylamme
Nitric acid, tnallium(l +) salt
Nitrobenzene (I,T)
p-Nitrophenol
2-Nitropropane (I.T)
N-Nrtrosodi-n-butylamine
N-Nrtrosodietrianolamine
N-Nrtrosodtetrtylamine
N-Nitroso-N-ettiylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosopiperidine
N-Nitrosopyrrolidine
5-Nitro-o-toluidine
1,2-Oxathk>lane, 2,2-dioxide
2H-1,3,2-Oxazaphosphorin-2-amine,
N.N-bis(2-chloroethyl)tetrahydro-, 2-oxide
Oxirane (I.T)
62
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
U126
U041
U182
U183
U184
U185
See
F027
U161
U186
U187
U188
U048
U039
UOB1
U082
U089
U101
U052
U132
U170
SM
F027
SM
F027
SM
F027
SM
F027
U1SO
U145
UOB7
U189
U190
U191
U179
U192
U194
U111
U110
U066
U063
U149
U171
U027
U193
SM
F027
U235
U140
U002
U007
U064
U243
U009
U152
UOOB
U113
U118
U162
U194
U063
U146
U198
U191
U237
U164
U180
U200
Chemical
abstracts No.
765-34-4
106-69-8
123-63-7
608-93-5
76-01-7
82-68-8
87-86-5
108-10-1
504-60-9
62-44-2
108-95-2
95-57-8
59-50-7
120-83-2
87-65-0
56-53-1
105-67-9
1319-77-3
70-30-4
100-02-7
87-66-5
58-90-2
95-95-4
86-06-2
146-62-3
7446-27-7
3286-56-2
1314-80-3
65-44-9
109-06-8
100-75-4
23950-58-5
107-10-8
621-64-7
142-84-7
96-12-6
78-87-5
109-77-3
79-46-9
106-60-1
1120-71-4
93-72-1
126-72-7
76-63-1
67-64-1
79-06-1
542-75-6
1888-71-7
107-13-1
126-96-7
79-10-7
140-66-5
97-63-2
80-62-6
107-10-6
78-87-5
123-33-1
110-86-1
109-06-6
66-75-1
56-04-2
930-55-2
50-55-5
Substance
Oxiranecarboxyaldehyde
Oxirane, (chtoromethyl)-
Paraldehyde
'entachlorobenzene
Pentachloroethane
Pentachloronitrooenzene (PCNB)
Pentachlorophenol
Pentanol, 4-methyl-
1,3-Pentadiene (I)
Phenacetin
Phenol
Phenol, 2-chkxo-
Phenol. 4-cMoro-3-methyl-
Phenol. 2.4-dfchtoro-
ttenol, 2,6-dtehloro-
Phenol. 4^4X1 .2-<»etrryM,2-ethenedryl)bis-. (E)-
Phenol. 2,4-oTmethyf-
TMnoi, iiNtlnyl
Phenol. 2,2--methytenebi»[3,4,6-trichloro-
Phanol. 4-nNro-
Phenol. pantachtoro-
Phenoi. 2,3.4.6-teWchtorc-
Phenol, 2,4.5-Wehloro-
Phenol. 2,4.6-trichtorc-
L-Phenytaiartna, 4-tbis(2-chloroethyl)arnirK>J-
Phosphoric acid. «ead(2+) salt (2:3)
Phosphorus suffide (R)
Phthafir AnhwrkirlA
2-Picoline
pjperidne. 1-nilroso-
Pronamide
-ptopanarnioe |i, ij
Propane, l^-dkromo-3-chloro-
Propane. 1^-dkWoro-
ropanaonvM
Propane, 2-nitro- (I.T)
Propane. 2^-oxybist2-chlofo-
PrrvyHVhir arirl ?.l? 4 S IrifihlQfOOhllfKmvW
1-Propanol. 2^-dferomo-. phosphate (3:1)
1-Prapmol. 2-methyt- (I.T)
1 -Propsna, 1 . * ,2l3«9.9"ne)(vcfiioio*
^-rropui MM *u in
2-fnUpWMIMfM, Z-rnaOTyi- |l, 1 )
2-Propanoic acid (0
2-Propenoic add. ethyl ester (1)
2-Propanoic acid. 2-mamyl-. ethyl aster
2 Proponoic acid 2-m*1hy4- m^hyi «fi^ (I T)
n-Piopylamina (t.T)
Pyntfcw
Pyricfine, 2-fiwlhyl-
PyrroAcSno, 1-fli1fo>o-
63
-------
§261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
U201
U202
U203
U204
U204
U205
U205
U015
See
F027
U206
U103
U189
See
F027
U207
U206
U209
U210
See
F027
U213
U214
U215
U216
U216
U217
U218
U153
U244
U219
U244
U220
U221
U223
U328
U353
U222
U011
U227
U228
U121
See
F027
See
F027
U234
U182
U235
U236
U237
U176
U177
U043
U248
U239
U200
U249
Chemical
abstracts No.
108-46-3
1 81-07-2
94-59-7
7783-00-8
7783-00-8
7488-56-4
7488-56-4
115-02-6
93-72-1
18883-66-4
77-78-1
1314-80-3
93-76-5
95-94-3
630-20-6
79-34-5
127-18-4
58-90-2
109-99-9
563-68-8
6533-73-9
7791-12-0
7791-12-0
10102-45-1
62-55-5
74-93-1
137-26-8
62-56-6
137-26-6
108-88-3
25376-45-8
26471-62-5
95-53-4
106-49-0
636-21-5
61-82-5
79-00-5
79-01-6
75-69-4
95-95-4
88-06-2
99-35-4
123-63-7
126-72-7
72-57-1
66-75-1
759-73-9
684-93-5
75-01-4
'81-81-2
1330-20-7
50-55-5
1314-84-7
Substance
Resofctnol
Saccharin. & salts
Safrote
Setenious acid
Selenium dioxide
Selenium sulfide
Selenium sulfide SeSj (R,T)
L-Serine, diazoacetate (ester)
Silvex (2,4,5-TP)
Streptozotocin
Sulfuric acid, dimethyl ester
Sulfur phosphide (R)
2,4,5-T
1 ,2,4.5-TetracMorobenzene
1 ,1 ,1 ,2-Tetrachkxoethane
1,1 ,2.2-Tetrachloroethane
Tetrachkxoetnytene
2.3.4.6-Tetrachlorophenol
Tetrahydrofuran (1)
ThalKurrKI) acetate
ThaltiumO) carbonate
ThaHium(l) chloride
Thallium chloride Tld
ThalNum(l) nitrate
Tnioacetamide
TNomethand (I.T)
Thioperoxydicarbonic diamide t(H,N)C(S)]»S,. tetramethyl-
Thiourea
Thiram
Toluene
Tohjenediamine
Toluene diisocyanate (R,T)
o-Toluidine
p-Toluidine
o-Toluidine hydrochloride
1 H-1 ,2,4-Triazol-3-amine
1,1 ,2-Trichloroethane
Trichloroethytene
Trichkxornonofluoromethane
2,4,5-Trichkxophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene (R.T)
1,3,5-Trioxane, 2,4,6-trimethyl-
Tris(2,3-dioromopfOpyl) phosphate
Trypan blue
Uracil mustard
Urea, N-ethyl-N-rntroso-
Urea, N-methyl-N-nitroso-
Vinyt chloride
Warfarin, & salts, when present at concentrations of 0.3% or less
Xytene(l)
Yohimban-16-carboxylic acid, H,l7-dimethoxy-l8-[(3,4,5-trimethoxybenzoyl)oxy]-, methyl ester.
(3beta,l6beta,17alpha,18beta,20alpha)-
Zinc phosphide Zn,Pi, when present at concentrations of 10% or less
1 CAS Number given for parent compound only.
(Approved by the Office of Management and Budget under control number 2050-0047)
[45 FR 78529, 78541, Nov. 25, 1980]
EDITORIAL NOTE: For FEDERAL REGISTER citations affecting i 261.33, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
64
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Environmental Protection Agency
§ 261.35
§261.35 Deletion of certain hazardous
waste codes following equipment clean-
ing and replacement.
(a) Wastes from wood preserving
processes at plants that do not resume
or initiate use of chlorophenolic pre-
servatives will not meet the listing def-
inition of F032 once the generator has
met all of the requirements of para-
graphs (b) and (c) of this section.
These wastes may, however, continue
to meet another hazardous waste list-
ing description or may exhibit one or
more of the hazardous waste charac-
teristics.
(b) Generators must either clean or
replace all process equipment that
may have come into contact with
chlorophenolic formulations or con-
stituents thereof, including, but not
limited to, treatment cylinders, sumps,
tanks, piping systems, drip pads, fork
lifts, and trams, in a manner that
minimizes or eliminates the escape of
hazardous waste or constituents,
leachate, contaminated drippage, or
hazardous waste decomposition prod-
ucts to the ground water, surface
water, or atmosphere.
(1) Generators shall do one of the
following:
(i) Prepare and follow an equipment
cleaning plan and clean equipment in
accordance with this section;
(ii) Prepare and follow an equipment
replacement plan and replace equip-
ment in accordance with this section;
or
(iii) Document cleaning and replace-
ment in accordance with this section,
carried out after termination of use of
chlorophenolic preservations.
(2) Cleaning Requirements.
(i) Prepare and sign a written equip-
ment cleaning plan that describes:
(A) The equipment to be cleaned;
(B) How the equipment will be
cleaned;
(C) The solvent to be used in clean-
ing;
(D) How solvent rinses will be tested;
and
(E) How cleaning residues will be dis-
posed.
(ii) Equipment must be cleaned as
follows:
(A) Remove all visible residues from
process equipment;
(B) Rinse process equipment with an
appropriate solvent until dioxins and
dibenzof urans are not detected in the
final solvent rinse.
(iii) Analytical requirements.
(A) Rinses must be tested in accord-
ance with SW-846, Method 8290.
(B) "Not detected" means at or
below the lower method calibration
limit (MCL) in Method 8290, Table 1.
(iv) The generator must manage all
residues from the cleaning process as
P032 waste.
(3) Replacement requirements.
(i) Prepare and sign a written equip-
ment replacement plan that describes:
(A) The equipment to be replaced;
(B) How the equipment will be re-
placed; and
(C) How the equipment will be dis-
posed.
(ii) The generator must manage the
discarded equipment as P032 waste.
(4) Documentation requirements.
(i) Document that previous equip-
ment cleaning and/or replacement was
performed in accordance with this sec-
tion and occurred after cessation of
use of chlorophenolic preservatives.
(c) The generator must maintain the
following records documenting the
cleaning and replacement as part of
the facility's operating record:
(1) The name and address of the fa-
cility;
(2) Formulations previously used
and the date on which their use ceased
in each process at the plant;
(3) Formulations currently used in
each process at the plant;
(4) The equipment cleaning or re-
placement plan;
(5) The name and address of any
persons who conducted the cleaning
and replacement;
(6) The dates on which cleaning and
replacement were accomplished;
(7) The dates of sampling and test-
ing;
(8) A description of the sample han-
dling and preparation techniques, in-
cluding techniques used for extrac-
tion, containerization, preservation,
and chain-of-custody of the samples;
(9) A description of the tests per-
formed, the date the tests were per-
formed, and the results of the tests;
65
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Pt. 261, App. I
40 CFR Ch. I (7-1-92 Edition)
(10) The name and model numbers
of the instrument(s) used in perform-
ing the tests;
(11) QA/QC documentation; and
(12) The following statement signed
by the generator or his authorized rep-
resentative:
I certify under penalty of law that all
process equipment required to be cleaned or
replaced under 40 CFR 261.35 was cleaned
or replaced as represented in the equipment
cleaning and replacement plan and accom-
panying documentation. I am aware that
there are significant penalties for providing
false information, including the possibility
of fine or imprisonment.
[55 FR 50482, Dec. 6, 1990, as amended at 56
PR 30195, July 1, 1991]
EFFECTIVE DATE NOTE: At 55 FR 50482,
Dec. 6, 1990, § 261.35 was added. Paragraph
(c) contains information collection and rec-
ordkeeping requirements and will not
become effective until approval has been
given by the Office of Management and
Budget. A notice will be published in the
FEDERAL REGISTER once approval has been
obtained.
APPENDICES TO PART 261
APPENDIX I TO PART 261—
REPRESENTATIVE SAMPLING METHODS
The methods and equipment used for
sampling waste materials will vary with the
form and consistency of the waste materials
to be sampled. Samples collected using the
sampling protocols listed below, for sam-
pling waste with properties similar to the in-
dicated materials, will be considered by the
Agency to be representative of the waste.
Extremely viscous liquid—ASTM Standard
D140-70 Crushed or powdered material—
ASTM Standard D346-75 Soil or rock-like
material—ASTM Standard D420-69 Soil-
like material—ASTM Standard D1452-65
Fly Ash-like material—ASTM Standard
D2234-76 [ASTM Standards are available
from ASTM, 1916 Race St., Philadelphia,
PA 19103]
Containerized liquid wastes—"COLIWASA"
described in "Test Methods for the Eval-
uation of Solid Waste, Physical/Chemical
Methods," * U.S. Environmental Protec-
* These methods are also described in
"Samplers and Sampling Procedures for
Hazardous Waste Streams," EPA 600/2-80-
018, January 1980.
tion Agency, Office of Solid Waste, Wash-
ington, D.C. 20460. [Copies may be ob-
tained from Solid Waste Information, U.S.
Environmental Protection Agency, 26 W.
St. Clair St., Cincinnati, Ohio 45268]
Liquid waste in pits, ponds, lagoons, and
similar reservoirs.—"Pond Sampler" de-
scribed in "Test Methods for the Evalua-
tion of Solid Waste, Physical/Chemical
Methods." "
This manual also contains additional in-
formation on application of these protocols.
APPENDIX II TO PART 261—METHOD
1311 TOXICITY CHARACTERISTIC
LEACHING PROCEDURE (TCLP)
1.0 Scope and Application
1.1 The TCLP is designed to determine
the mobility of both organic and inorganic
analytes present in liquid, solid, and multi-
phasic wastes.
1.2 If a total analysis of the waste dem-
onstrates that individual analytes are not
present in the waste, or that they are
present but at such low concentrations that
the appropriate regulatory levels could not
possibly be exceeded, the TCLP need not be
run.
1.3 If an analysis of any one of the liquid
fractions of the TCLP extract indicates that
a regulated compound is present at such
high concentrations that, even after ac-
counting for dilution from the other frac-
tions of the extract, the concentration
would be equal to or above the regulatory
level for that compound, then the waste is
hazardous and it is not necessary to analyze
the remaining fractions of the extract.
1.4 If an analysis of extract obtained
using a bottle extractor shows that the con-
centration of any regulated volatile analyte
equals or exceeds the regulatory level for
that compound, then the waste is hazardous
and extraction using the ZHE is not neces-
sary. However, extract from a bottle extrac-
tor cannot be used to demonstrate that the
concentration of volatile compounds is
below the regulatory level.
2.0 Summary of Method
2.1 For liquid wastes (i.e., those contain-
ing less than 0.5% dry solid material), the
waste, after filtration through a 0.6 to 0.8
ftm glass fiber filter, is defined as the TCLP
extract.
2.2 For wastes containing greater than or
equal to 0.5% solids, the liquid, if any, is
separated from the solid phase and stored
for later analysis; the particle size of the
solid phase is reduced, if necessary. The
solid phase is extracted with an amount of
extraction fluid equal to 20 times the weight
66
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Environmental Protection Agency
Pt. 261, App. II
of the solid phase. The extraction fluid em-
ployed is a function of the alkalinity of the
solid phase of the waste. A special extractor
vessel is used when testing for volatile ana-
lytes (see Table 1 for a list of volatile com-
pounds). Following extraction, the liquid ex-
tract is separated from the solid phase by
filtration through a 0.6 to 0.8 jim glass fiber
filter.
2.3 If compatible (i.e., multiple phases
will not form on combination), the initial
liquid phase of the waste is added to the
liquid extract, and these are analyzed to-
gether. If incompatible, the liquids are ana-
lyzed separately and the results are mathe-
matically combined to yield a volume-
weighted average concentration.
3.0 Interferences
3.1 Potential interferences that may be
encountered during analysis are discussed in
the individual analytical methods.
4.0 Apparatus and Materials
4.1 Agitation apparatus: The agitation
apparatus must be capable of rotating the
extraction vessel in an end-over-end fashion
(see Figure 1) at 30 ±2 rpm. Suitable devices
known to EPA are identified in Table 2.
4.2 Extraction Vessels.
4.2.1 Zero-Headspace Extraction Vessel
(ZHE). This device is for use only when the
waste is being tested for the mobility of
volatile analytes (i.e., those listed in Table
1). The ZHE (depicted in Figure 2) allows
for liquid/solid separation within the
device, and effectively precludes headspace.
This type of vessel allows for initial liquid/
solid separation, extraction, and final ex-
tract filtration without opening the vessel
(see section 4.3.1). The vessels shall have an
internal volume of 500-600 mL, and be
equipped to accommodate a 90-110 mm
filter. The devices contain VITON* l O-rings
which should be replaced frequently. Suita-
ble ZHE devices known to EPA are identi-
fied in Table 3.
For the ZHE to be acceptable for use, the
piston within the ZHE should be able to be
moved with approximately 15 pounds per
square inch (psi) or less. If it takes more
pressure to move the piston, the O-rings in
the device should be replaced. If this does
not solve the problem, the ZHE is unaccept-
able for TCLP analyses and the manufac-
turer should be contacted.
The ZHE should be checked for leaks
after every extraction. If the device contains
a built-in pressure gauge, pressurize the
device to 50 psi, allow it to stand unattended
for 1 hour, and recheck the pressure. If the
device does not have a built-in pressure
gauge, pressurize the device to 50 psi, sub-
'VITON* is a registered trademark of
DuPont.
merge it in water, and check for the pres-
ence of air bubbles escaping from any of the
fittings. If pressure is lost, check all fittings
and inspect and replace O-rings, if neces-
sary. Retest the device. If leakage problems
cannot be solved, the manufacturer should
be contacted.
Some ZHEs use gas pressure to actuate
the ZHE piston, while others use mechani-
cal pressure (see Table 3). Whereas the vola-
tiles procedures (see section 7.3) refers to
pounds per square inch (psi), for the me-
chanically actuated piston, the pressure ap-
plied is measured in torque-inch-pounds.
Refer to the manufacturer's instructions as
to the proper conversion.
4.2.2 Bottle Extraction Vessel. When the
waste is being evaluated using the nonvola-
tile extraction, a jar with sufficient capacity
to hold the sample and the extraction fluid
is needed. Headspace is allowed in this
vessel.
The extraction bottles may be constructed
from various materials, depending on the
analytes to be analyzed and the nature of
the waste (see section 4.3.3). It is recom-
mended that borosilicate glass bottles be
used instead of other types of glass, espe-
cially when inorganics are of concern. Plas-
tic bottles, other than polytetrafluoroethy-
lene, shall not be used if organics are to be
investigated. Bottles are available from a
number of laboratory suppliers. When this
type of extraction vessel is used, the filtra-
tion device discussed in section 4.3.2 is used
for initial liquid/solid separation and final
extract filtration.
4.3 Filtration Devices: It is recommended
that all nitrations be performed in a hood.
4.3.1 Zero-Headspace Extractor Vessel
(ZHE): When the waste is evaluated for vo-
latiles, the zero-headspace extraction vessel
described in section 4.2.1 is used for filtra-
tion. The device shall be capable of support-
ing and keeping in place the glass fiber
filter and be able to withstand the pressure
needed to accomplish separation (50 psi).
NOTE: When it is suspected that the glass
fiber filter has been ruptured, an in-line
glass fiber filter may be used to filter the
material within the ZHE.
4.3.2 Filter Holder: When the waste is
evaluated for other than volatile analytes,
any filter holder capable of supporting a
glass fiber filter and able to withstand the
pressure needed to accomplish separation
may be used. Suitable filter holders range
from simple vacuum units to relatively com-
plex systems capable of exerting pressures
of up to 50 psi or more. The type of filter
holder used depends on the properties of
the material to be filtered (see section 4.3.3).
These devices shall have a minimum inter-
nal volume of 300 mL and be equipped to ac-
commodate a minimum filter size of 47 mm
67
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Pt. 261, App. II
40 CFR Ch. I (7-1-92 Edition)
(filter holders having an internal capacity
of 1.5 L or greater, and equipped to accom-
modate a 142 mm diameter filter, are recom-
mended). Vacuum filtration can only be
used for wastes with low solids content
(<10%) and for highly granular, liquid-con-
taining wastes. All other types of wastes
should be filtered using positive pressure fil-
tration. Suitable filter holders known to
EPA are shown in Table 4.
4.3.3 Materials of Construction: Extrac-
tion vessels and filtration devices shall be
made of inert materials which will not leach
or absorb waste components. Glass, polyte-
trafluoroethylene (PTFE), or type 316 stain-
less steel equipment may be used when eval-
uating the mobility of both organic and in-
organic components. Devices made of high
density polyethylene (HDPE), polypropyl-
ene (PP), or polyvinyl chloride (PVC) may
be used only when evaluating the mobility
of metals. Borosilicate glass bottles are rec-
ommended for use over other types of glass
bottles, especially when inorganics are ana-
lytes of concern.
4.4 Filters: Filters shall be made of boro-
silicate glass fiber, shall contain no binder
materials, and shall have an effective pore
size of 0.6 to 0.8 jon, or equivalent. Filters
known to EPA which meet these specifica-
tions are identified in Table 5. Pre-filters
must not be used. When evaluating the mo-
bility of metals, filters shall be acid-washed
prior to use by rinsing with IN nitric acid
followed by three consecutive rinses with
deionized distilled water (a minimum of 1 L
per rinse is recommended). Glass fiber filter
are fragile and should be handled with care.
4.5 pH Meters: The meter should be ac-
curate to ± 0.05 units at 25°C.
4.6 ZHE Extract Collection Devices:
TEDLAR® * bags or glass, stainless steel or
PTFE gag-tight syringes are used to collect
the initial liquid phase and the final extract
of the waste when using the ZHE device.
The devices listed are recommended for use
under the following conditions:
4.6.1 If a waste contains an aqueous
liquid phase or if a waste does not contain a
significant amount of nonaqueous liquid
(i.e., <1% of total waste), the TEDLAR®
bag or a 600 mL syringe should be used to
collect and combine the initial liquid and
solid extract.
4.6.2 If a waste contains a significant
amount of nonaqueous liquid in the initial
liquid phase (Le.. >1% of total waste), the
syringe or the TEDLAR® bag may be used
for both the intitial solid/liquid separation
and the final extract filtration. However,
analysts should use one or the other, not
both.
* TEDLAR® is a registered trademark of
Dupont.
4.6.3 If the waste contains no initial
liquid phase (is 100% solid) or has no signifi-
cant solid phase (is 100% liquid), either the
TEDLAR® bag or the syringe may be used.
If the syringe is used, discard the first 5 mL
of liquid expressed from the device. The re-
maining aliquots are used for analysis.
4.7 ZHE Extraction Fluid Transfer De-
vices: Any device capable of transferring the
extraction fluid into the ZHE without
changing the nature of the extraction fluid
is acceptable (e.g, a positive displacement or
peristaltic pump, a gas tight syringe, pres-
sure filtration unit (see section 4.3.2), or
other ZHE device).
4.8 Laboratory Balance: Any laboratory
balance accurate to within ± 0.01 grams
may be used (all weight measurements are
to be within ± 0.1 grams).
4.9 Beaker or Erlenmeyer flask, glass,
500 mL.
4.10 Watchglass, appropriate diameter to
cover beaker or erlenmeyer flask.
4.11 Magnetic stirrer.
5.0 Reagents
5.1 Reagent grade chemicals shall be
used in all tests. Unless otherwise indicated,
it is intended that all reagents shall con-
form to the specifications of the Committee
on Analytical Reagents of the American
Chemical Society, where such specifications
are available. Other grades may be used,
provided it is first ascertained that the rea-
gent is of sufficiently high purity to permit
its use without lessening the accuracy of the
determination.
5.2 Reagent water. Reagent water is de-
fined as water in which an interferant is not
observed at or above the methods detection
limit of the analyte(s) of interest. For non-
volatile extractions, ASTM Type II water or
equivalent meets the definition of reagent
water. For volatile extractions, it is recom-
mended that reagent water be generated by
any of the following methods. Reagent
water should be monitored periodically for
impurities.
5.2.1 Reagent water for volatile extrac-
tions may be generated by passing tap water
through a carbon filter bed containing
about 500 grams of activated carbon
(Calgon Corp., Filtrasorb-300 or equivalent).
5.2.2 A water purification system (Milli-
pore Super-Q or equivalent) may also be
used to generate reagent water for volatile
extractions.
5.2.3 Reagent water for volatile extrac-
tions may also be prepared by boiling water
for 15 minutes. Subsequently, while main-
taining the water temperature at 90 + 5 de-
grees C, bubble a contaminant-free inert gas
(e.g., nitrogen) through the water for 1
hour. While still hot. transfer the water to a
narrow mouth screw-cap bottle under zero-
68
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Environmental Protection Agency
Pt. 261, App. II
headspace and seal with a Teflon-lined
septum and cap.
5.3 Hydrochloric acid (IN), HC1, made
from ACS reagent grade.
5.4 Nitric acid (IN), HNO3, made from
ACS reagent grade.
5.5 Sodium hydroxide (IN), NaOH, made
from ACS reagent grade.
5.6 Glacial acetic acid, CH3CH2OOH, ACS
reagent grade.
5.7 Extraction fluid.
5.7.1 Extraction fluid #1: Add 5.7 mL gla-
cial CH3CH2OOH to 500 mL of reagent
water (See section 5.2), add 64.3 mL of IN
NaOH, and dilute to a volume of 1 liter.
When correctly prepared, the pH of this
fluid will be 4.93 ±0.05.
5.7.2 Extraction fluid #2: Dilute 5.7 mL
glacial CHsCH2OOH with reagent water
(See section 5.2) to a volume of 1 liter.
When correctly prepared, the pH of this
fluid will be 2.88±0.05.
NOTE: These extraction fluids should be
monitored frequently for impurities. The
pH should be checked prior to use to ensure
that these fluids are made up accurately. If
impurities are found or the pH is not within
the above specifications, the fluid shall be
discarded and fresh extraction fluid pre-
pared.
5.8 Analytical standards shall be pre-
pared according to the appropriate analyti-
cal method.
6.0 Sample Collection, Preservation, and
Handling
6.1 All samples shall be collected using
an appropriate sampling plan.
6.2 The TCLP may place reQuirements
on the minimal size of the field sample, de-
pending upon the physical state or states of
the waste and the analytes of concern. An
aliquot is needed for preliminary evaluation
of which extraction fluid is to be used for
the nonvolatile analyte extraction proce-
dure. Another aliquot may be needed to ac-
tually conduct the nonvolatile extraction
(see section 1.4 concerning the use of this
extract for volatile organics). If volatile or-
ganics are of concern, another aliquot may
be needed. Quality control measures may re-
quire additional aliquots. Further, it is
always wise to collect more samples just in
case something goes wrong with the initial
attempt to conduct the test.
6.3 Preservatives shall not be added to
samples before extraction.
6.4 Samples may be refrigerated unless
refrigeration results in irreversible physical
change to the waste. If precipitation occurs,
the entire sample (including precipitate)
should be extracted.
6.5 When the waste is to be evaluated for
volatile analytes, care shall be taken to min-
imize the loss of volatiles. Samples shall be
collected and stored in a manner intended
to prevent the loss of volatile analytes (e.g.,
samples should be collected in Teflon-lined
septum capped vials and stored at 4 °C.
Samples should be opened only immediately
prior to extraction).
6.6 TCLP extracts should be prepared
for analysis and analyzed as soon as possible
following extraction. Extracts or portions of
extracts for metallic analyte determinations
must be acidified with nitric acid to a pH
<2, unless precipitation occurs (see section
7.2.14 if precipitation occurs). Extracts
should be preserved for other analytes ac-
cording to the guidance given in the individ-
ual analysis methods. Extracts or portions
of extracts for organic analyte determina-
tions shall not be allowed to come into con-
tact with the atmosphere (i.e., no head-
space) to prevent losses. See section 8.0 (QA
requirements) for acceptable sample and ex-
tract holding times.
7.0 Procedure
7.1 Preliminary Evaluations. Perform
preliminary TCLP evaluations on a mini-
mum 100 gram aliquot of waste. This ali-
quot may not actually undergo TCLP ex-
traction. These preliminary evaluations in-
clude: (1) Determination of the percent
solids (section 7.1.1); (2) determination of
whether the waste contains insignificant
solids and is, therefore, its own extract after
filtration (section 7.1.2); (3) determination
of whether the solid portion of the waste re-
quires particle size reduction (section 7.1.3);
and (4) determination of which of the two
extraction fluids are to be used for the non-
volatile TCLP extraction of the waste (sec-
tion 7.1.4.).
7.1.1 Preliminary determination of per-
cent solids: Percent solids is defined as that
fraction of a waste sample (as a percentage
of the total sample) from which no liquid
may be forced out by an applied pressure, as
described below.
7.1.1.1 If the waste will obviously yield
no liquid when subjected to pressure filtra-
tion (i.e., is 100% solids) proceed to section
7.1.3.
7.1.1.2 If the sample is liquid or multi-
phasic, liquid/solid separation to make a
preliminary determination of percent solids
is required. This involves the filtration
device described in section 4.3.2 and is out-
lined in sections 7.1.1.3 through 7.1.1.9.
7.1.1.3 Pre-weigh the filter and the con-
tainer that will receive the filtrate.
7.1.1.4 Assemble the filter holder and
filter following the manufacturer's instruc-
tions. Place the filter on the support screen
and secure.
7.1.1.5 Weigh out a subsample of the
waste (100 gram minimum) and record the
weight.
7.1.1.6 Allow slurries to stand to permit
the solid phase to settle. Wastes that settle
69
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Pt. 261, App. II
40 CFR Ch. I (7-1-92 Edition)
slowly may be centrifuged prior to filtra-
tion. Centrifugation is to be used only as an
aid to filtration. If used, the liquid should
be decanted and filtered followed by filtra-
tion of the solid portion of the waste
through the same filtration system.
7.1.1.7 Quantitatively transfer the waste
sample to the filter holder (liquid and solid
phases). Spread the waste sample evenly
over the surface of the filter. If filtration of
the waste at 4 °C reduces the amount of ex-
pressed liquid over what would be expressed
at room temperature then allow the sample
to warm up to room temperature in the
device before filtering.
NOTE: If waste material (>1% of original
sample weight) has obviously adhered to
the container used to transfer the sample to
the filtration apparatus, determine the
weight of this residue and subtract it from
the sample weight determined in section
7.1.1.5 to determine he weight of the waste
sample that will be filtered.
Gradually apply vacuum or gentle pres-
sure of 1-10 psi, until air or pressurizing gas
moves through the filter. If this point is not
reached under 10 psi, and if no additional
liquid has passed through the filter in any 2
minute interval, slowly increase the pres-
sure in 10 psi increments to a maximum of
50 psi. After each incremental increase of 10
psi, if the pressurizing gas has not moved
through the filter, and if no additional
liquid has passed through the filter in any 2
minute interval, proceed to the next 10 psi
increment. When the pressurizing gas
begins to move through the filter, or when
liquid flow has ceased at 50 psi (i.e., filtra-
tion does not result in any additional fil-
trate within any 2 minute period), stop the
filtration.
NOTE: Instantaneous application of high
pressure can degrade the glass fiber filter
and may cause premature plugging.
7.1.1.8 The material in the filter holder is
defined as the solid phase of the waste, and
the filtrate is defined as the liquid phase.
NOTE: Some wastes, such as oily wastes
and some paint wastes, will obviously con-
tain some material that appears to be a
liquid. Even after applying vacuum or pres-
sure filtration, as outlined in section 7.1.1.7,
this material may not filter. If this is the
case, the material within the filtration
device is defined as a solid. Do not replace
the original filter with a fresh filter under
any circumstances. Use only one filter.
7.1.1.9 Determine the weight of the
liquid phase by subtracting the weight of
the filtrate container (see section 7.1.1.3)
from the total weight of the filtrate-filled
container. Determine the weight of the solid
phase of the waste sample by subtracting
the weight of the liquid phase from the
weight of the total waste sample, as deter-
mined in section 7.1.1.5 or 7.1.1.7.
Record the weight of the liquid and solid
phases. Calculate the percent solids as fol-
lows:
Percent solids =
Weight of solid (section 7.1.1.9)
Total weight of waste (section 7.1.1.5 or 7.1.1.7)
xlOO
7.1.2 If the percent solids determined in
section 7.1.1.9 is equal to or greater than
0.5%, then proceed either to section 7.1.3 to
determine whether the solid material re-
quires particle size reduction or to section
7.1.2.1 if it is noticed that a small amount of
the filtrate is entrained in wetting of the
filter. If the percent solids determined in
section 7.1.1.9 is less than 0.5%, then pro-
ceed to section 7.2.9 if the nonvolatile TCLP
is to be performed and to section 7.3 with a
fresh portion of the waste if the volatile
TCLP is to be performed.
7.1.2.1 Remove the solid phase and filter
from the filtration apparatus.
7.1.2.2 Dry the filter and solid phase at
100 ± 20°C until two successive weighings
yield the same value within ± 1%. Record
the final weight.
NOTE: Caution should be taken to ensure
that the subject solid will not flash upon
heating. It is recommended that the drying
oven be vented to a hood or other appropri-
ate device.
7.1.2.3 Calculate the percent dry solids as
follows:
i dry solids =
(Weight of dry waste+filter)—tared weight of filter
Initial weight of waste (section 7.1.1.5 or 7.1.1.7)
xlOO
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7.1.2.4 If the percent dry solids is less
than 0.5%, then proceed to section 7.2.9 if
the nonvolatile TCLP is to be performed,
and to section 7.3 if the volatile TCLP is to
be performed. If the percent dry solids is
greater than or equal to 0.5%, and if the
nonvolatile TCLP is to be performed, return
to the beginning of this section (7.1) and,
with a fresh portion of waste, determine
whether particle size reduction is necessary
(section 7.1.3) and determine the appropri-
ate extraction fluid (section 7.1.4). If only
the volatile TCLP is to be performed, see
the note in section 7.1.4.
7.1.3 Determination of whether the
waste requires particle size reduction (parti-
cle size is reduced during this step): Using
the solid portion of the waste, evaluate the
solid for particle size. Particle size reduction
is required, unless the solid has a surface
area per gram of material equal to or great-
er than 3.1 cm1, or is smaller than 1 cm in
its narrowest dimension (i.e., is capable of
passing through a 9.5 mm (0.375 inch)
standard sieve). If the surface area is small-
er or the particle size larger than described
above, prepare the solid portion of the
waste for extraction by crushing, cutting, or
grinding the waste to a surface area or par-
ticle size as described above. If the solids are
prepared for organic volatiles extraction.
special precautions must be taken (see sec-
tion 7.3.6).
NOTE: Surface area criteria are meant for
filamentous (e.g., paper, cloth, and similar)
waste materials. Actual measurement of sur-
face area is not required, nor is it recom-
mended. For materials that do not obviously
meet the criteria, sample-specific methods
would need to be developed and employed
to measure the surface area. Such method-
ology is currently not available.
7.1.4 Determination of appropriate ex-
traction fluid: If the solid content of the
waste is greater than or equal to 0.5% and if
the sample will be extracted for nonvolatile
constituents (section 7.2), determine the ap-
propriate fluid (section 5.7) for the nonvola-
tiles extraction as follows:
NOTE: TCLP extraction for volatile con-
stituents uses only extraction fluid #1 (sec-
tion 5.7.1). Therefore, if TCLP extraction
for nonvolatiles is not required, proceed to
section 7.3.
7.1.4.1 Weigh out a small subsample of
the solid phase of the waste, reduce the
solid (if necessary) to a particle size of ap-
proximately 1 mm in diameter or less, and
transfer 5.0 grams of the solid phase of the
waste to a 500 mL beaker or Erlenmeyer
flask.
7.1.4.2 Add 96.5 mL of reagent water to.
the beaker, cover with a watchglass, and stir
vigorously for 5 minutes using a magnetic
stirrer. Measure and record the pH. If the
pH is <5.0, use extraction fluid #1. Proceed
to section 7.2.
7.1.4.3 If the pH from section 7.1.4.2 is
>5.0. add 3.5 mL IN NCI, slurry briefly,
cover with a watchglass, heat to 50°C, and
hold at 50°C for 10 minutes.
7.1.4.4 Let the solution cool to room tem-
perature and record the pH. If the pH is
<5.0, use extraction fluid #1. If the pH is
>5.0, use extraction fluid #2. Proceed to sec-
tion 7.2.
7.1.5 If the aliquot of the waste used for
the preliminary evaluation (sections 7.1.1-
7.1.4) was determined to be 100% solid at
section 7.1.1.1, then it can be used for the
section 7.2 extraction (assuming at least 100
grams remain), and the section 7.3 extrac-
tion (assuming at least 25 grams remain). If
the aliquot was subjected to the procedure
in section 7.1.1.7, then another aliquot shall
be used for the volatile extraction proce-
dure in section 7.3. The aliquot of the waste
subjected to the procedure in section 7.1.1.7
might be appropriate for use for the section
7.2 extraction if an adequate amount of
solid (as determined by section 7.1.1.9) was
obtained. The amount of solid necessary is
dependent upon whether a sufficient
amount of extract will be produced to sup-
port the analyses. If an adequate amount of
solid remains, proceed to section 7.2.10 of
the nonvolatile TCLP extraction.
7.2 Procedure When Volatiles are not In-
volved. A minimum sample size of 100 grams
(solid and liquid phases) is recommended. In
some cases, a larger sample size may be ap-
propriate, depending on the solids content
of the waste sample (percent solids, See sec-
tion 7.1.1), whether the initial liquid phase
of the waste win be miscible with the aque-
ous extract of the solid, and whether inor-
ganics, semivolatile organics, pesticides, and
herbicides are all analytes of concern.
Enough solids should be generated for ex-
traction such that the volume of TCLP ex-
tract will be sufficient to support all of the
analyses required. If the amount of extract
generated by a single TCLP extraction will
not be sufficient to perform all of the analy-
ses, more than one extraction may be per-
formed and the extracts from each com-
bined and aliquoted for analysis.
7.2.1 If the waste will obviously yield no
liquid when subjected to pressure filtration
(i.e., is 100% solid, see section 7.1.1), weigh
out a subsample of the waste (100 gram
minimum) and proceed to section 7.2.9.
7.2.2 If the sample is liquid or multipha-
sic, liquid/solid separation is required. This
Involves the filtration device described in
section 4.3.2 and is outlined in sections 7.2.3
to 7.2.8.
7.2.3 Pre-weigh the container that will
receive the filtrate.
7.2.4 Assemble the filter holder and filter
following the manufacturer's instructions.
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40 CFR Ch. I (7-1-92 Edition)
Place the filter on the support screen and
secure. Acid-wash the filter if evaluating the
mobility of metals (see section 4.4).
NOTE: Acid-washed filters may be used for
all nonvolatile extractions even when metals
are not of concern.
7.2.5 Weigh out a subsample of the waste
(100 gram minimum) and record the weight.
If the waste contains <0.5% dry solids (sec-
tion 7.1.2), the liquid portion of the waste,
after filtration, is defined as the TCLP ex-
tract. Therefore, enough of the sample
should be filtered so that the amount of fil-
tered liquid will support all of the analyses
required of the TCLP extract. For wastes
containing >0.5% dry solids (sections 7.1.1
or 7.1.2), use the percent solids information
obtained in section 7.1.1 to determine the
optimum sample size (100 gram minimum)
for filtration. Enough solids should be gen-
erated by filtration to support the analyses
to be performed on the TCLP extract.
7.2.6 Allow slurries to stand to permit
the solid phase to settle. Wastes that settle
slowly may be centrifuged prior to filtra-
tion. Use centrifugation only as an aid to fil-
tration. If the waste is centrifuged, the
liquid should be decanted and filtered fol-
lowed by filtration of the solid portion of
the waste through the same filtration
system.
7.2.7 Quantitatively transfer the waste
sample (liquid and solid phases) to the filter
holder (see section 4.3.2). Spread the waste
sample evenly over the surface of the filter.
If filtration of the waste at 4 °C reduces the
amount of expressed liquid over what would
be expressed at room temperature, then
allow the sample to warm up to room tem-
perature in the device before filtering.
NOTE If waste material (> 1% of the origi-
nal sample weight) has obviously adhered to
the container used to transfer the sample to
the filtration apparatus, determine the
weight of this residue and subtract it from
the sample weight determined in section
7.2.5, to determine the weight of the waste
sample that will be filtered.
Gradually apply vacuum or gentle pres-
sure of 1-10 psi. until air or pressurizing gas
moves through the filter. If this point is
reached under 10 psi, and if no additional
liquid has passed through the filter in any 2
minute interval, slowly increase the pres-
sure in 10 psi increments to a maximum of
SO psi. After each incremental increase of 10
psi, if the pressurizing gas has not moved
through the filter, and if no additional
liquid has passed through the filter in any 2
minute interval, proceed to the next 10 psi
increment. When the pressurizing gas
begins to move through the filter, or when
the liquid flow has ceased at 50 psi (i.e., fil-
tration does not result in any additional fil-
trate within a 2 minute period), stop the fil-
tration.
NOTE: Instantaneous application of high
pressure can degrade the glass fiber filter
and may cause premature plugging.
7.2.8 The material in the filter holder is
defined as the solid phase of the waste, and
the filtrate is defined as the liquid phase.
Weigh the filtrate. The liquid phase may
now be either analyzed (See section 7.2.12)
or stored at 4°C until time of analysis.
NOTE: Some wastes, such as oily wastes
and some paint wastes, will obviously con-
tain some material that appears to be a
liquid. Even after applying vacuum or pres-
sure filtration, as outlined in section 7.2.7,
this material may not filter. If this is the
case, the material within the filtration
device is defined as a solid and is carried
through the extraction as a solid. Do not re-
place the original filter with a fresh filter
under any circumstances. Use only one
filter.
7.2.9 If the waste contains <0.5% dry
solids (see section 7.1.2), proceed to section
7.2.13. If the waste contains >0.5% dry
solids (see section 7.1.1 or 7.1.2), and if parti-
cle size reduction of the solid was needed in
section 7.1.3, proceed to section 7.2.10. If the
waste as received passes a 9.5 mm sieve,
quantitatively transfer the solid material
into the extractor bottle along with the
filter used to separate the initial liquid from
the solid phase, and proceed to section
7.2.11.
7.2.10 Prepare the solid portion of the
waste for extraction by crushing, cutting, or
grinding the waste to a surface area or par-
ticle size as described in section 7.1.3. When
the surface area or particle size has been ap-
propriately altered, quantitatively transfer
the solid material into an extractor bottle.
Include the filter used to separate the ini-
tial liquid from the solid phase.
NOTE: Sieving of the waste is not normally
required. Surface area requirements are
meant for filamentous (e.g., paper, cloth)
and similar waste materials. Actual meas-
urement of surface area is not recommend-
ed. If sieving is necessary, a Teflon-coated
sieve should be used to avoid contamination
of the sample.
7.2.11 Determine the amount of extrac-
tion fluid to add to the extractor vessel as
follows:
Weight of
extraction
fluid
20 x percent solids (section
7.1.1 )x weight of waste
filtered (section 7.2.5 or
7.2.7)
100
Slowly add this amount of appropriate ex-
traction fluid (see section 7.1.4) to the ex-
tractor vessel. Close the extractor bottle
72
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Environmental Protection Agency
Pt. 261, App. II
tightly (it is recommended that Teflon tape
be used to ensure a tight seal), secure in
rotary agitation device, and rotate at 30 ± 2
rpm for 18 ± 2 hours. Ambient temperature
(i.e., temperature of room in which extrac-
tion takes place) shall be maintained at 23
± 2°C during the extraction period.
NOTE: As agitation continues, pressure
may build within the extractor bottle for
some types of wastes (e.g., limed or calcium
carbonate containing waste may evolve
gases such as carbon dioxide). To relieve
excess pressure, the extractor bottle may be
periodically opened (e.g., after 15 minutes,
30 minutes, and 1 hour) and vented into a
hood.
7.2.12 Following the 18 ± 2 hour extrac-
tion, separate the material in the extractor
vessel into its component liquid and solid
phases by filtering through a new glass
fiber filter, as outlined in section 7.2.7. For
final filtration of the TCLP extract, the
glass fiber filter may be changed, if neces-
sary, to facilitate filtration. Filter(s) shall
be acid-washed (see section 4.4) if evaluating
the mobility of metals.
7.2.13 Prepare the TCLP extract as fol-
lows:
7.2.13.1 If the waste contained no initial
liquid phase, the filtered liquid material ob-
tained from section 7.2.12 is defined as the
TCLP extract. Proceed to section 7.2.14.
7.2.13.2 If compatible (e.g., multiple
phases will not result on combination), com-
bine the filtered liquid resulting from sec-
tion 7.2.12 with the initial liquid phase of
the waste obtained in section 7.2.7. This
combined liquid is defined as the TCLP ex-
tract. Proceed to section 7.2.14.
7.2.13.3 If the initial liquid phase of the
waste, as obtained from section 7.2.7, is not
or may not be compatible with the filtered
liquid resulting from section 7.2.12, do not
combine these liquids. Analyze these liquids,
collectively defined as the TCLP extract,
and combine the results mathematically, as
described in section 7.2.14.
7.2.14 Following collection of the TCLP
extract, the pH of the extract should be re-
corded. Immediately aliquot and preserve
the extract for analysis. Metals aliquots
must be acidified with nitric acid to pH <2.
If precipitation is observed upon addition of
nitric acid to a small aliquot of the extract,
then the remaining portion of the extract
for metals analyses shall not be acidified
and the extract shall be analyzed as soon as
possible. All other aliquots must be stored
under refrigeration (4 °C> until analyzed.
The TCLP extract shall be prepared and
analyzed according to appropriate analytical
methods. TCLP extracts to be analyzed for
metals shall be acid digested except in those
instances where digestion causes loss of me-
tallic analytes. If an analysis of the undi-
gested extract shows that the concentration
of any regulated metallic analyte exceeds
the regulatory level, then the waste is haz-
ardous and digestion of the extract is not
necessary. However, data on undigested ex-
tracts alone cannot be used to demonstrate
that the waste is not hazardous. If the indi-
vidual phases are to be analyzed separately,
determine the volume of the individual
phases (to ± 0.5%), conduct the appropriate
analyses, and combine the results mathe-
matically by using a simple volume-weight-
ed average:
Final Analyte
Concentration
Vi+V,
where:
Vi=The volume of the first phase (L).
Ci=The concentration of the analyte of
concern in the first phase (mg/L).
V2=The volume of the second phase (L).
C2=The concentration of the analyte of
concern in the second phase (mg/L).
7.2.15 Compare the analyte concentra-
tions in the TCLP extract with the levels
identified in the appropriate regulations.
Refer to section 8.0 for quality assurance re-
quirements.
7.3 Procedure When Volatiles are In-
volved. Use the ZHE device to obtain TCLP
extract for analysis of volatile compounds
only. Extract resulting from the use of the
ZHE shall not be used to evaluate the mo-
bility of nonvolatile analytes (e.g., metals,
pesticides, etc.).
The ZHE device has approximately a 500
mL internal capacity. The ZHE can thus ac-
commodate a maximum of 25 grams of solid
(defined as that fraction of a sample from
which no additional liquid may be forced
out by an applied pressure of 50 psi), due to
the need to add an amount of extraction
fluid equal to 20 times the weight of the
solid phase.
Charge the ZHE with sample only once
and do not open the device until the final
extract (of the solid) has been collected. Re-
peated filling of the ZHE to obtain 25 grams
of solid is not permitted.
Do not allow the waste, the initial liquid
phase, or the extract to be exposed to the
atmosphere for any more time than is abso-
lutely necessary. Any manipulation of these
materials should be done when cold (4°C) to
minimize loss of volatiles.
7.3.1 Pre-weigh the (evacuated) filtrate
collection container (See section 4.6) and set
aside. If using a TEDLAR* bag, express all
liquid from the ZHE device into the bag,
whether for the initial or final liquid/solid
separation, and take an aliquot from the
liquid in the bag for analysis. The contain-
ers listed in section 4.6 are recommended for
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40 CFR Ch. I (7-1-92 Edition)
use under the conditions stated in sections
4.6.1-4.6.3.
7.3.2 Place the ZHE piston within the
body of the ZHE (it may be helpful first to
moisten the piston O-rings slightly with ex-
traction fluid). Adjust the piston within the
ZHE body to a height that will minimize the
distance the piston will have to move once
the ZHE is charged with sample (based
upon sample size requirements determined
from section 7.3, section 7.1.1 and/or 7.1.2).
Secure the gas inlet/outlet flange (bottom
flange) onto the ZHE body in accordance
with the manufacturer's instructions.
Secure the glass fiber filter between the
support screens and set aside. Set liquid
inlet/outlet flange (top flange) aside.
7.3.3 If the waste is 100% solid (see sec-
tion 7.1.1). weigh out a subsample (25 gram
maximum) of the waste, record weight, and
proceed to section 7.3.5.
7.3.4 If the waste contains <5% dry
solids (section 7.1.2), the liquid portion of
waste, after filtration, is defined as the
TCLP extract. Filter enough of the sample
so that the amount of filtered liquid will
support all of the volatile analyses required.
For wastes containing >5% dry solids (sec-
tions 7.1.1 and/or 7.1.2), use the percent
solids information obtained in section 7.1.1
to determine the optimum sample size to
charge into the ZHE. The recommended
sample size is as follows:
7.3.4.1 For wastes containing <5% solids
(see Section 7.1.1), weigh out a 500 gram
subsample of waste and record the weight.
7.3.4.2 For wastes containing >5% solids
(see Section 7.1.1), determine the amount of
waste to charge into the ZHE as follows:
Weight of waste to charge ZHE =
25
percent solids (section 7.1.1)
xlOO
Weigh out a subsample of the waste of the
appropriate size and record the weight.
7.3.5 If particle size reduction of the solid
portion of the waste was required in section
7.1.3, proceed to section 7.3.6. If particle size
reduction was not required in section 7.1.3,
proceed to section 7.3.7.
7.3.6 Prepare the waste for extraction by
crushing, cutting, or grinding the solid por-
tion of the waste to a surface area or parti-
cle size as described in section 7.1.3.1.
Wastes and appropriate reduction equip-
ment should be refrigerated, if possible, to
4°C prior to particle size reduction. The
means used to effect particle size reduction
must not generate heat in and of itself. If
reduction of the solid phase of the waste is
necessary, exposure of the waste to the at-
mosphere should be avoided to the extent
possible.
NOTE: Sieving of the waste is not recom-
mended due to the possibility that volatiles
may be lost. The use of an appropriately
graduated ruler is recommended as an ac-
ceptable alternative. Surface area require-
ments are meant for filamentous (e.g.,
paper, cloth) and similar waste materials.
Actual measurement of surface area is not
recommended.
When the surface area or particle size has
been appropriately altered, proceed to sec-
tion 7.3.7.
7.3.7 Waste slurries need not be allowed
to stand to permit the solid phase to settle.
Do not centrifuge wastes prior to filtration.
7.3.8 Quantitatively transfer the entire
sample (liquid and solid phases) quickly to
the ZHE. Secure the filter and support
screens onto the top flange of the device
and secure the top flange to the ZHE body
in accordance with the manufacturer's in-
structions. Tighten all ZHE fittings and
place the device in the vertical position (gas
inlet/outlet flange on the bottom). Do not
attach the extract collection device to the
top plate.
NOTE: If waste material (>1% of original
sample weight) has obviously adhered to
the container used to transfer the sample to
the ZHE, determine the weight of this resi-
due and subtract it from the sample weight
determined in section 7.3.4 to determine the
weight of the waste sample that will be fil-
tered.
Attach a gas line to the gas inlet/outlet
valve (bottom flange) and, with the liquid
inlet/outlet valve (top flange) open, begin
applying gentle pressure of 1-10 psi (or
more if necessary) to force all headspace
slowly out of the ZHE device into a hood. At
the first appearance of liquid from the
liquid inlet/outlet valve, quickly close the
valve and discontinue pressure. If filtration
of the waste at 4 °C reduces the amount of
expressed liquid over what would be ex-
pressed at room temperature, then allow
the sample to warm up to room temperature
in the device before filtering. If the waste is
100% solid (see section 7.1.1), slowly in-
crease the pressure to a maximum of 50 psi
to force most of the headspace out of the
device and proceed to section 7.3.12.
7.3.9 Attach the evacuated pre-weighed
filtrate collection container to the liquid
inlet/outlet valve and open the valve. Begin
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Environmental Protection Agency
Pt. 261, App. II
applying gentle pressure of 1-10 psi to force
the liquid phase of the sample into the fil-
trate collection container. If no additional
liquid has passed through the filter in any 2
minute interval, slowly increase the pres-
sure in 10 psi increments to a maximum of
50 psi. After each incremental increase of 10
psi, if no additional liquid has passed
through the filter in any 2 minute interval,
proceed to the next 10 psi increment. When
liquid flow has ceased such that continued
pressure filtration at 50 psi does not result
in any additional filtrate within a 2 minute
period, stop the filtration. Close the liquid
inlet/outlet valve, discontinue pressure to
the piston, and disconnect and weigh the fil-
trate collection container.
NOTE: Instantaneous application of high
pressure can degrade the glass fiber filter
and may cause premature plugging.
7.3.10 The material in the ZHE is defined
as the solid phase of the waste and the fil-
trate is defined as the liquid phase.
NOTE: Some wastes, such as oily wastes
and some paint wastes, will obviously con-
tain some material that appears to be a
liquid. Even after applying pressure filtra-
tion, this material will not filter. If this is
the case, the material within the filtration
device is defined as a solid and is carried
through the TCLP extraction as a solid.
If the original waste contained <0.5% dry
solids (see section 7.1.2), this filtrate is de-
fined as the TCLP extract and is analyzed
directly. Proceed to section 7.3.15.
7.3.11 The liquid phase may now be
either analyzed immediately (See sections
7.3.13 through 7.3.15) or stored at 4°C under
minimal headspace conditions until time of
analysis.
Determine the weight of extraction fluid
#1 to add to the ZHE as follows:
Weight of extraction
fluid
20 x percent solids (section
7.1.1) xweight of waste filtered
(section 7.3.4 or 7.3.8)
100
7.3.12 The following sections detail how
to add the appropriate amount of extraction
fluid to the solid material within the ZHE
and agitation of the ZHE vessel. Extraction
fluid #1 is used in all cases (See section 5.7).
7.3.12.1 With the ZHE in the vertical po-
sition, attach a line from the extraction
fluid reservoir to the liquid inlet/outlet
valve. The line used shall contain fresh ex-
traction fluid and should be preflushed with
fluid to eliminate any air pockets in the
line. Release gas pressure on the ZHE
piston (from the gas inlet/outlet valve),
open the liquid inlet/outlet valve, and begin
transferring extraction fluid (by pumping or
similar means) into the ZHE. Continue
pumping extraction fluid into the ZHE until
the appropriate amount of fluid has been
introduced into the device.
7.3.12.2 After the extraction fluid has
been added, immediately close the liquid
inlet/outlet valve and disconnect the extrac-
tion fluid line. Check the ZHE to ensure
that all valves are in their closed positions.
Manually rotate the device in an end-over-
end fashion 2 or 3 times. Reposition the
ZHE in the vertical position with the liquid
inlet/outlet valve on top. Pressurize the
ZHE to 5-10 psi (if necessary) and slowly
open the liquid inlet/outlet valve to bleed
out any headspace (into a hood) that may
have been introduced due to the addition of
extraction fluid. This bleeding shall be done
quickly and shall be stopped at the first ap-
pearance of liquid from the valve. Re-pres-
surize the ZHE with 5-10 psi and check all
ZHE fittings to ensure that they are closed.
7.3.12.3 Place the ZHE in the rotary agi-
tation apparatus (if it is not already there)
and rotate at 30 ± 2 rpm for 18 ± 2 hours.
Ambient temperature (i.e., temperature of
room in which extraction occurs) shall be
maintained at 22 ± 3°C during agitation.
7.3.13 Following the 18 ± 2 hour agita-
tion period, check the pressure behind the
ZHE piston by quickly opening and closing
the gas inlet/outlet valve and noting the
escape of gas. If the pressure has not been
maintained (i.e., no gas release observed),
the device is leaking. Check the ZHE for
leaking as specified in section 4.2.1, and per-
form the extraction again with a new
sample of waste. If the pressure within the
device has been maintained, the material in
the extractor vessel is once again separated
into its component liquid and solid phases.
If the waste contained an initial liquid
phase, the liquid may be filtered directly
into the same filtrate collection container
(i.e., TEDLAR* bag) holding the initial
liquid phase of the waste. A separate filtrate
collection container must be used if combin-
ing would create multiple phases, or there is
not enough volume left within the filtrate
collection container. Filter through the
glass fiber filter, using the ZHE device as
75
-------
ft. 261, App. II
40 CFR Ch. I (7-1-92 Edition)
discussed in section 7.3.9. All extract shall
be filtered and collected if the TEDLAR*
bag is used, if the extract is multiphasic, or
if the waste contained an initial liquid phase
(see sections 4.6 and 7.3.1).
NOTE: An in-line glass fiber filter may be
used to filter the material within the ZHE if
it is suspected that the glass fiber filter has
been ruptured.
7.3.14 If the original waste contained no
initial liquid phase, the filtered liquid mate-
rial obtained from section 7.3.13 is defined
as the TCLP extract. If the waste contained
an initial liquid phase, the filtered liquid
material obtained from section 7.3.13 and
the initial liquid phase (section 7.3.9) are
collectively defined as the TCLP extract.
7.3.15 Following collection of the TCLP
extract, immediately prepare the extract for
analysis and store with minimal headspace
at 4°C until analyzed. Analyze the TCLP ex-
tract according to the appropriate analytical
methods. If the individual phases are to be
analyzed separately (i.e., are not miscible),
determine the volume of the individual
phases (to 0.5%), conduct the appropriate
analyses, and combine the results mathe-
matically by using a simple volume-weight-
ed average:
Final Analtye
Concentration
(ViKC.WViXCs)
V,+V2
where:
V,=The volume of the first phases (L).
Ci=The concentration of the analyte of
concern in the first phase (mg/L).
Vj=The volume of the second phase (L).
C»=The concentration of the analyte of
concern in the second phase (mg/L).
7.3.16 Compare the analyte concentra-
tions in the TCLP extract with the levels
identified in the appropriate regulations.
Refer to section 8.0 for quality assurance re-
quirements.
8.0 Quality Assurance
8.1 A minimum of one blank (using the
same extraction fluid as used for the sam-
ples) must be analyzed for every 20 extrac-
tions that have been conducted in an extrac-
tion vessel.
8.2 A matrix spike shall be performed for
each waste type (e.g., wastewater treatment
sludge, contaminated soil, etc.) unless the
result exceeds the regulatory level and the
data is being used solely to demonstrate
that the waste property exceeds the regula-
tory level. A minimum of one matrix spike
must be analyzed for each analytical batch.
The bias determined from the matrix spike
determination shall be used to correct the
measured values. (See sections 8.2.4 and
8.2.5.) As a minimum, follow the matrix
spike addition guidance provided in each an-
alytical method.
8.2.1 Matrix spikes are to be added after
filtration of the TCLP extract and before
preservation. Matrix spikes should not be
added prior to TCLP extraction of the
sample.
8.2.2 In most cases, matrix spikes should
be added at a concentration equivalent to
the corresponding regulatory level. If the
analyte concentration is less than one half
the regulatory level, the spike concentration
may be as low as one half of the analyte
concentration, but may not be not less than
five times the method detection limit. In
order to avoid differences in matrix effects,
the matrix spikes must be added to the
same nominal volume of TCLP extract as
that which was analyzed for the unspiked
sample.
8.2.3 The purpose of the matrix spike is
to monitor the performance of the analyti-
cal methods used, and to determine whether
matrix interferences exist. Use of other in-
ternal calibration methods, modification of
the analytical methods, or use of alternate
analytical methods may be needed to accu-
rately measure the analyte concentration of
the TCLP extract when the recovery of the
matrix spike is below the expected analyti-
cal method performance.
8.2.4 Matrix spike recoveries are calculat-
ed by the following formula:
%R (% Recovery)=100 (X.-XU)/K
where:
X,=measured value for the spiked sample,
Xu=measured value for the unspiked
sample, and
K= known value of the spike in the sample.
8.2.5 Measured values are corrected for
analytical bias using the following formula:
X€=100(XU/%R)
where:
Xj=corrected value, and
Xu=measured value of the unspiked sample.
8.3 All quality control measures de-
scribed in the appropriate analytical meth-
ods shall be followed.
8.4 Samples must undergo TCLP extrac-
tion within the following time periods:
SAMPLE MAXIMUM HOLDING TIMES (DAYS)
Vdatites
Semivola-
tites .
Mercury
From:
Field
collection
to: TCLP
extraction
14
14
28
From:
TCLP
extraction
to:
Prepara-
tive
extraction
NA
7
NA
From:
prepara-
extraction
determi-
native
analysis
14
40
28
Total
elapsed
time
28
61
56
76
-------
Environmental Protection Agency
Pt. 261, App. II
SAMPLE MAXIMUM HOLDING TIMES (DAYS)-
Continued
TABLE 2—SUITABLE ROTARY AGITATION
APPARATUS l
Metals,
except
mercury
From:
Field
collection
to: TCLP
extraction
180
From:
TCLP
extraction
to:
Prepara-
tive
extraction
NA
From:
prepara-
extraction
to:
determi-
native
analysis
180
Total
elapsed
time
360
NA=Not applicable.
If sample holding times are exceed-
ed, the values obtained will be consid-
ered minimal concentrations. Exceed-
ing the holding time is not acceptable
in establishing that a waste does not
exceed the regulatory level. Exceeding
the holding time will not invalidate
characterization if the waste exceeds
the regulatory level.
TABLE 1—VOLATILE ANALYTES 1
-------
PI. 261, App. II
40 CFR Ch. I (7-1-92 Edition)
TABLE 4—SUITABLE FILTER HOLDERS 1—
Continued
Company
Micro
Filtration
Systems.
Mtfpore
Corpora-
lion.
Location
Dublin, CA.
(800)
334-
7132,
(415)
828-
6010.
Bedford.
MA,
(800)
225-
3384.
Model/catalogue
No.
302400
311400
YT30142HW
XX1004700
Size
142 mm.
47 mm.
142 mm.
47 mm.
lyzed. Plastic devices (not listed above) may be used when
only inorganic anatytes are of concern. The 142 mm size
filter holder is recommended.
TABLE 5—SUITABLE FILTER MEDIA l
Any device capable of
th9 mst0 is
writli ttw
the iquid from me toM
ttMt it is ch0fnicaty
the cmnlitusnlt to bs ana-
Company
Millipore
Corporation.
Nucteopore
Corporation.
Whatman
Laboratory
Products, Inc..
Micro FittrBbon
Systofns.
Location
Bedford, MA,
(800) 225-3384.
Pteasanton, CA.
(415) 463-2530.
Clifton. NJ. (201)
773-5800.
Dublin. CA, (800)
334-7132. (415)
828-«010.
Model
AP40
211625
GFF
GF76
Pore
Size
(ftm)
0.7
0.7
0.7
0.7
4.4 of
78
-------
Environmental Protection Agency
Pt. 261, App. II
Motor
(30 ± 2 rpm)
1 Extraction VMM! Holder
f
Figure 1. Rotary Agitation Apparatus
79
-------
Pt. 261, App. II
Top Range—»
Support Screen/
Filter
Support Seme
Vfton o-rings-
Bottom Range
Pressurized Gas
Inlet/Outlet Valve
40 CFR Ch. I (7-1-92 Edition)
Liquid Inlet/Outlet Valve
t
"• ••
:/
••;•'•:•.
#••'
Sample
- «•*?••:•
Piston
Gas
Figure 2. Zero-Headspace Extractor (ZHE)
80
-------
Environmental Protection Agency
METHOD 1311
TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
Pt. 261, App. II
f START J
( ;
t
* )
Separate
liquids from
solids with
0.6 - 0.8 urn
glass fiber
filter
i
i
<0.5%
Discard
solids
Use a
sub-sample of
waste
1
t
What is
the %
solids in the
waste?
1
100%
f
CD
i
Liquid
Separate
. liquids from
>0.5% solids with
0.6 - 0.8 urn
glass fiber
filter
Examine
solids
Solid
Must the
solid be
milled?
Yes
Extract with
appropriate fluid
1) Bottle extractor
for non-volatiles
2) ZHE device for
volatile*
Reduce
particle size
fo <9.5 mm
81
-------
Pt. 261, App. II
40 CFR Ch. I (7-1-92 Edition)
METHOD 1311 (CONTINUED)
TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
Store liquid
at 4C
Separate
extract from
solids with
0.6 - 0.8 urn
glass fiber
filter
Solid
Discard
solids
Combine
extract with
liquid phase
of waste
Measure amount of
liguid and analyze
(mathematically
combine result with
result of extract
analysis)
Analyze
liquid
[
STOP
[55 FR 26987, June 29, 1990]
82
-------
Environmental Protection Agency
Pt. 261, App. Ill
APPENDIX III TO PART 261—CHEMICAL
ANALYSIS TEST METHODS
Tables 1, 2. and 3 specify the appropriate
analytical procedures, described in "Test
Methods for Evaluating Solid Waste, Physi-
cal/Chemical Methods," (incorporated by
reference, see § 260.11) which shall be used
to determine whether a sample contains a
given appendix VII or VIII toxic constitu-
ent.
Table 1 identifies each appendix VII or
VIII organic constituent along with the ap-
proved measurement method. Table 2 iden-
tifies the corresponding methods for inor-
ganic species. Table 3 summarizes the con-
tents of SW-846 and supplies specific sec-
tion and method numbers for sampling and
analysis methods.
Prior to final sampling and analysis
method selection the analyst should consult
the specific section or method described in
SW-846 for additional guidance on which of
the approved methods should be employed
for a specific sample analysis situation.
TABLE 1—ANALYSIS METHODS FOR ORGANIC
CHEMICALS CONTAINED IN SW-846
TABLE 1—ANALYSIS METHODS FOR ORGANIC
CHEMICALS CONTAINED IN SW-846—Contin-
ued
Compound
AoetonttrHe
Acrotein
AcryiamkJe
Acrylonrtrite
2.Amino-l-methylbenz6n6 (o-Toluidine)
4-Amino-l-metnylbenzene (p-Toluidine)
Aniline
Benz(a)anthracene
Benzo(a)pyrene
Benzotrichloride
Benzyl chloride
Benzo(b)fluoanthene
Bis(2-chloroethoxymethane)
Bis(2-cnloroethyt)etner
Bis(2-chloroisopropyl)ether
Carbon bisulfide
Carbon tetracntoride
Chlordane
Chlorinated dibenzo-p-dioxins
Chlorinated dibenzofurans ••••-
Chloroform
2-Chkxopnenol
Creosote '
Method
Numbers
8030, 8240
8030, 8240
8015. 8240
8030, 8240
8250
8250
8250
8020, 8024
8100, 8250,
8310
8100, 8250,
8310
8120. 8250
8120, 8250
8100, 8250,
8310
8100, 8250,
8270, 8310
8010, 8240
8010, 8240
8010, 8240
8015, 8240
8010, 8240
8080, 8250
8080, 8250
8280
8280
8010, 8240
8020, 8240
8010, 8240
8010, 8240
8040, 8250
8100, 8250,
8310
8100, 8250
Compound
Cresol(s)
Cresylic Acid(s)
Dichlorobonzene(s)
Dichlofoethane(s)
Dichloromethane
Dichloropnenoxyacetic acid
Dichtoropropanol
Dimethyl sulfate
1 l-Dimethylhydrazine (UDMH)
2 4-Dimethytpnenol ... .
Dinitrobenzene ... .
4 6-Dinrtro-o-cresol ... •
2 4-Dinttrotoluene .. .
2 6-Dinitrotoluene
Endrin . ..
2-Ethoxyethanol ... .
Ethyl ether
Ethylene dibromide
Ethylene truourea
Formaldehyde
Formic add
Heptachlor
Hexachtorobenzene
Hexachlorobutadiene
Hexachkxoethane ... .
Hexachlorocydopentadiene
LJndane
Maleic anhydride ...
Methanol ... .
Methomyl
Methyl bromide
Methyl ethyl ketone
Methyl isobutyl ketone
Napthalene
Napthopuinone
Nitrobenzene
4-Nitrophenol .
2-Nitropropdne .
Paraldehyde (trimer of acetaldehyde)
PentacMorophenol
Phenol .
Phorate •
Phosphorodithioic acid esters
2-Picoline
Pyridine
Tetrachlorobenzene(s)
Tetrachloroethane(s)
Tetrachloroethene
Tetrachlorophenol
Toluene diisocyanate(s)
2 4-Toluenediamine
2 5-Toluenediamine
3 4-Toluenediamine
Trichloroethene(s)
Trichlorofluoromethane
Trichlorophenol(s)
2 4 5-Trichlorophenoxy proptonic acid
Trichloropropane
Vinvl chloride
Method
Numbers
8040, 8250
8040 8250
6010 8120
8250
8010 8240
8010 8240
8150 8250
8120 8250
8250 8270
8250
8040 8250
8090 8250
8040 8250
8090 8250
8060 8250
8080 8250
8030 8240
8015, 8240
8010, 8240
8250, 8330
8015. 8240
8250
8080, 8250
8120, 8250
8120, 8250
8010. 8240
8120, 8250
8080, 8250
8250
8010, 8240
8250
8010, 8240,
8260
8015 8240
8015 8240
8100 8250
8090 6250
8090 8250
8040, 8240
8030, 8240
8015 8240
8040, 8250
8040, 8250
8140
8140
8090, 8250
8090, 8250
8090, 8250
8120, 8250
8010, 8240
8010, 8240
8040, 8250
8020, 8024
8250
8250
8250
8250
8250
8080, 8250
8010, 8240
8010, 8240
8010, 8240
8040, 8250
8150, 8250
8010, 8240
8010, 8240
83
-------
Pt. 261, App. HI
40 CFR Ch. I (7-1-92 Edition)
TABLE 1—ANALYSIS METHODS FOR ORGANIC
CHEMICALS CONTAINED IN SW-846—Contin-
ued
Compound
Wtyfidene chloride
Xvtone -
Method
Numbers
8010. 8240
8020,8240
'Analyne for phenanthrene and catbazote; if these are
present in a ratio between 1.4:1 and 5:1 creosote should be
considered present
TABLE 2—ANALYSIS METHODS FOR INORGANIC
CHEMICALS AND MISCELLANEOUS GROUPS
OF ANALYTES CONTAINED IN SW-846*
Compound
Antimony „,
Arsenic
Barium
Calcium
Chromium .
Chromium Hexavatent
Cobalt
•-"•fr"-*1 — - --- -"-
Iron
Lead
Magnesium
Mercury
(Molybdenum
Nickel
Third
Edition
Method(s)
6010
6010
6010
6010
6010, 7090,
7091
6010
6010
6010
6010
7198
6010
6010, 7210,
7211
6010. 7380,
7381
6010
6010
6010, 7460.
7461
6010
6010
Second
Edition
Method(s)
7040, 7041
7060.7061
7080.7081
7130. 7131
7190, 7191
7195. 7196,
7197
7420, 7421
7470. 7471
7520, 7521
TABLE 2—ANALYSIS METHODS FOR INORGANIC
CHEMICALS AND MISCELLANEOUS GROUPS
OF ANALYTES CONTAINED IN SW-846'—Con-
tinued
Compound
Osmium ...
Selenium
Silicon
Silver
Thallium
Vanadium
Zinc
Cyanides
Total Organic Halides
Sulfides
Sulfates
Total Organic Carbon
Phenolics
Oil and Grease , .
Total Coliform
Nitrate
Chlorides
Alpha-Emitting Radium Isotopes
Radkjm-226
Third
Edition
Methods)
7550
6010
6010
6010
6010
6010 7770
6010, 7840,
7841
6010, 7910,
7911
6010. 7950,
7951
9022
9035, 9036,
9038
9060
9065, 9066*.
9067
9070, 9071
9131, 9132
9200
9250, 9251,
9252
9310
9315
9320
Second
Edition
Method(s)
7740, 7741
7760, 7761
9010
9020
9030
•The Third Edition of SW-846 and its Revision I are
available from the Government Printing Office, Superintend-
ent of Documents. Washington, DC 20402, (202) 783-3238,
document number 955-001-00000-1.
* When Method 9066 is used it must be preceded by the
manual distillation specified in procedure 7.1 of Method
9065. Just prior 10 distillation in method 9065, adjust the
surfuric aod-presewed sample to pH 4 with 1+9 NaOH.
After the manual distillation is completed, the autoanalyzer
manifold is simplified by connecting the re-sample line direcl-
ly to the sampler.
TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846a
Title
Uathnrl HAtArtinn 1 imft
s^n-yinrl Water
RAfttrarwts ,
Saimle Praoarataon Methods
Third Edition
Section
No.
1.0
1.1
1.2
1.3
1.4
1.5
1.6
2.0
2.1
2.2
2.3
2.4
2.5
2.6
3.0
3.1
3.2
Method
No.
Second Edition
Section
No.
10.0
10.1
Method
No.
84
-------
Environmental Protection Agency Pt. 261, App. Ill
TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 •—Continued
Trtte
Add Digestion of Waters for Total Recoverable or
Dissolved Metals for Analysis by Flame AAS or ICP
Acid Digestion of Aqueous Samples and Extracts for
Total Metals for Analysis by Flame AAS or ICP
Acid Digestion of Aqueous Samples and Extracts for
Total Metals for Analysis by Furnace AAS
Dissolution Procedure for Oils Greases or Waxes
Acid Digestion of Sediments Sludges and Softs
Unttevifi fnr tha Dotarmiruitinn of Matalfi
Inductively Coupled Plasma Atomic Emissions Spec-
Atomic Absorption Methods
Antimony Flame AAS ..—•
Antimony Furnace AAS ,
Arsenic Furnace AAS
Arsenic Gaseous Hydride AAS
Barium Flame AAS
BerytNum Furnace AAS
CaoVrtium Flame AAS
Cadmium Furnace AAS
ftAlrattm Plama AAS
Chromium Flame AAS •
Chromium Hexavalent, Coprecipitation
Chromium, Hexavalent. Cotorimetric
Chromium Hexavalent, Chetotioci/Extractkwv
Chromium, Hexavalent Differential Pulse Polarography....
P-nhflH Flame AAfi
CVthihlt PiimAr*} AA£
Lead Flame AAS
Lead Furnace AAS
Mercury in Liquid Waste. Manual Cold Vapor Technique
Mercury in Solid or Semteolid Waste. Manual Cold
Vapor Technique
Nickel Flame AAS
Selenium Furnace AAS *—.
Selenium Gaseous Hydride AAS
Silver Flame AAS
CyuHiiim Plama AA^
Extractions and Preparations
Separatory funnel Liquid-Liquid Extraction
rnntinimis Urujd-Uouid Extraction
Third Edition
Section
No.
3.2
3.2
3.2
3.2
3.2
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
4.0
4.1
4.2
4.2.1
4.2.1
4.2.1
4.2.1
Method
No.
3005
3010
3020
3040
3050
•6010
7000
7020
7040
7041
7060
7061
7080
7081
•7090
•7091
7130
7131
7140
7190
7191
7195
7196
7197
•7198
7200
7201
•7210
•7211
•7380
•7381
7420
7421
7450
•7460
•7461
7470
7471
7480
7481
7520
•7550
7610
7740
7741
7760
7761
•7770
•7840
•7841
7870
•7910
•7911
•7950
•7951
3500
3510
3520
Second Edition
Section
No.
4.1
4.1
4.1
4.1
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
5.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
8.0
4.2
4.2
Method
No.
3010
3020
3040
3050
7040
7041
7060
7061
7080
7081
7130
7131
7190
7191
7195
7196
7197
7420
7421
7470
7471
7520
7740
7741
7760
7761
3510
3520
85
-------
Pt. 261, App. Ill 40 CFR Ch. I (7-1-92 Edition)
TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 •—Continued
Title
Soxhtet Extraction
Ultrasonic Extraction
Waste Dilution
Purge-antf-Trap ......
Protocol for Analysis of Sorbent Cartridges from VOST...
Cleanup
Alumina Column Cleanup
Alumina Column Cleanup and Separation of Petroleum
Waste*
Sttra Gol dMren
QJJ rtmmftnrfffl*f
fOB and D8CP
AHHMfcYOtrttl OliHH^f*
VoiaMa Organic Compounds in Water by
Purge-and-Trap CapMary Column GC with
PC and EHOrolyfc CondudNtty Detector to
SaMl^M
iriTa^fri ArnAwslMte JL a> Miihiin
Phenols.
|J^to»A*i^B!f^a>ft
dor*
f*fevMfsfw4»nM4win CajMttrktaM
Oiganophoaphorua Partcidai: CapVary
Column
GC/MS VoMVat
Analysis of Chlorinated Dioxins and Dfcenzo-
hjrans . -~
Hgh Partonnance Liquid Chromatographic Mathoda
(HPLC) . ~~
t^^M^M^MW
Itoadacans Exkactton and Screening of Purgoable Organics
aa- »• .. ^•^•A ^ateHwte
Total and AmanaMn CyanMa (Putaiinelilc Manual)
TnlBl «Mr1 AmM^t-te <^-— fWfc> fPlAMhlMfcfc- AieiMI^Mrft
Trtel (>««^r HaMas fTOXI
riaia^^afai rVntVM* 1 Mafto /POX>
Toltf Oryante Maidai (TOX) by NaiKvon Actuation Ana»y*t*
Acid-SotuMa and Adrt-lnaoluMo SuMWas
"iitfaim ifiiikMhiMifaf AiaivTMtwl rhtrvaniBlBl
Sialaia (TurtHdhiiatricl
Tom dnanir Carbon
flkBMr** TT^i Iniima^tair Aiiftnmr' — * ^ *ADk
Phenoics. tSueOrophotomelric. MBTH).
Third Edition
Section
No.
4.2.1
4.2.1
4.2.1
4.2.1
4.2.1
4.2.2
4.2.2
4,2.2
4.2.2
4.2.2
422
422
422
422
4.3
4.3.1
4.3.1
4.3.1
4.3.1
4.3,1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.2
432
4.32
432
4.32
4.32
4.3.3
4.3.3
4.4
4.4
4.4
S.O
S.O
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Method
No.
3540
3550
3580
5030
•5040
3600
3610
•3611
3620
3630
3640
3650
3660
8000
8010
8011
8015
8020
8021
8030
8040
8060
8070
8080
8090
8100
8110
8120
8140
8141
8150
8240
8250
8260
8270
8280
8310
3810
3820
9010
9012
9020
9021
•9022
9030
9031
•9035
•9036
•9038
•9060
•9065
•9066
•9067
Second Edition
Section
No.
4.2
4.2
5.0
4.2
6.1
8.1
8.1
8.1
„.„
8.1
8.1
8.1
8.1
8.1
8.1
8.1
........
8.2
6.2
8.2
8.2
8.3
8.3
5.0
9.0
9.0
9.0
9.0
Method
No.
3540
3550
5030
3530
8010
8015
8020
8030
8040
8060
8080
8090
8100
8120
8140
.„..„..
8240
8250
8270
8310
5020
9010
9020
9030
86
-------
Environmental Protection Agency Pt. 261, App. Ill
TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 "—Continued
Title
Total Recoverable Oil and Grease (Gravimetric, Separatory
Oil and Grease Extraction Method for Sludge Samples
Nitrate
Chloride (Titrimetric Mercuric Nitrate)
Extraction Procedure for Oily Wastes
pH Etectrometric Measurement ..
pH Paper Method •
Soil pH .
Specific Conductance -
Paint Filter Liquids Test
Saturated Hydraulic Conductivity, Saturated leachate Conductw-
Alpha-Emitting Radium Isotopes
Radium-228
Ignrtability -«
Test Method to Determine Hydrogen Cyanide Released
Test Method to Determine Hydrogen Sulfide Released
lanitflhitftv
Pensky-Martens Closed-Cup Method .
Setaftash Closed-Cup Method
Extraction Procedure (EP) Toxicity Test Method and
Structural Integrity Test
Waste nharactarization Strataov
Third Edition
Section
No.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
7.0
7.1
7.3
7.3
7.3
7.3
7.4
8.0
8.1
8.1
8.1
8.2
8.2
8.3
8.4
8.4
9.0
9.1
9.2
10.0
10.0
10.0
10.0
11.0
11.1
11.2
11.3
11.4
11.5
12.0
12.1
12.2
12.3
12.4
12.5
12.6
13.0
13.1
13.2
13.3
Method
No.
•9070
•9071
•9131
•9132
•9200
•9250
•9251
•9252
•1320
M330
9040
9041
9045
9050
•9080
•9081
9090
9095
•9100
•9310
•9315
•9320
1010
1020
1110
1310
•0010
•0020
•0030
Second Edition
Section
No.
9.0
9.0
2.0
2.1.1
2.1.2
2.1.3
2.1.4
2.0
2.1.1
2.1.1
2.1.1
2.1.2
2.1.2
2.1.3
2.1.4
2.1.4
1.0
1.0, 1.1
1.2. 1.3, 1.4
Method
No.
9040
9095
1010
1020
1110
1310
87
311-147 O—92-
-------
Pt. 261, App. VII 40 CFR Ch. I (7-1-92 Edition)
TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 "—Continued
Title
Third I
Section
No.
134
135
136
13.7
Edition
Method
No.
Second
Section
No.
Edition
Method
No.
•The Third Edition of SW-846 and its Revision I are available from the Government Printing Office, Superintendent of
Documents. Washington, DC 20402, (202) 738-3238, document number 955-001-00000-1.
"This method may be used in conjunction with or in addition to the methods found in the Second Edition of SW-846 as
When Method 9066 is used it must be preceded by the manual distillation specified in procedure 7.1 of Method 9065. Just
prior to distillation in Method 9065, adjust the sulfuric acid-preserved sample to pH 4 with 1 +9 NaOH. After the manual
distillation is completed, the autoanalyzer manifold is simplified by connecting the re-sample line directly to the sampler.
[48 PR 15257, Apr. 8, 1983, as amended at 50 PR 2000, Jan. 14, 1985; 50 FR 42942, Oct. 23,
1985; 51 FR 5330, Feb. 13, 1986; 51 FR 6541, Feb. 25, 1986; 51 FR 37729, Oct. 24, 1986; 54 FR
41407, Oct. 6, 1989; 54 FR 40267, Sept. 29. 1989; 55 FR 8950, Mar. 9. 1990; 55 FR 18505, May
2,1990; 55 FR 50483. Dec. 6, 1990]
APPENDIX IV TO PART 261—[RESERVED
FOR RADIOACTIVE WASTE TEST METH-
ODS]
APPENDIX V TO PART 261—[RESERVED
FOR INFECTIOUS WASTE TREATMENT
SPECIFICATIONS]
APPENDIX VI TO PART 261—[RESERVED
FOR ETIOLOGIC AGENTS]
APPENDIX VII TO PART 261—BASIS FOR
LISTING HAZARDOUS WASTE
EPA
hazard-
ous
waste
No.
EPA
hazard-
ous
waste
No.
F001
F002
F003..
F004..
F005..
F006..
F007..
F008..
F009..
F010..
F011..
F012..
F019..
F020..
F021..
F022..
F023.
F024.
Hazardous constituents for which listed
Tetrachtoroethylene, methytene chloride trichlor-
oethylene, 1,1,1-trichloroethane, carbon tetra-
chlofkle, chlorinated fluorocarbons.
Tetrachtoroethylene, methylene chloride, trichlor-
oethylene, 1,1,1-tnchloroethane, 1,1,2-trichlor-
oethane, chtorobenzene, 1,1,2-trichloro-1,2,2-
trichfluoroethane, ortho-dichlorobenzene, trich-
lorofluoromethane.
N.A.
Cresois and cresylic acid, nitrobenzene.
Toluene, methyl ethyl ketone, carbon disulfide,
isobutanol, pyridine, 2-ethoxyethanol, benzene,
2-nitropropane.
Cadmium, hexavalent chromium, nickel, cyanide
(comptexed).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (comptexed).
Hexavalent chromium, cyanide (complexed).
Hazardous constituents for which listed
Tetra- and pentachlorodibenzo-p^xins; tetra
and pentachlorodi-benzofurans; tri- and
tetrachlorophenols and their chlorophenoxy de-
rivative acids, esters, ethers, amirte and other
salts.
Penta- and hexachtorodibenzo-p-dioxins; penta-
and hexachlorodibenzofurans; pentachloro-
phenol and its derivatives.
Tetra-, penta-, and hexachlorodibenzo-p-dioxins;
tetra-, penta-, and hexachlorodibenzofurans.
Tetra-, and pentachtorodibenzo-p-dioxins; tetra-
and pentachlorodibenzofurans; tri- and tetra-
chlorophenols and their chlorophenoxy deriva-
tive acids, esters, ethers, amine and other salts.
Chloromethane, dichloromethane, trichlorometh-
ane, carbon tetrachloride, chloroethylene, 1,1-
dichloroethane, 1,2-dichloroethane, trans-1-2-
dichloroethytene, 1.1-dichloroethylene, 1,1,1-
trichloroethane, 1,1,2-trichloroethane, trichlor-
oethylene, 1,1,1.2-tetra-chloroethane, 1,1,2,2-te-
trachloroethane, tetrachloroethytene, pentach-
loroethane, hexachloroethane, allyl chloride (3-
chloropropene), dtohloropropane, dichloropro-
pene, 2-chloro-1,3-butadiene, hexachloro-1,3-
butadiene, hexachlorocyclopentadiene, hexach-
lorocyclohexane, benzene, chlorbenzene, dich-
lorobenzenes, 1,2,4-trichkxobenzene, tetrachlor-
obenzene, pentachtorobenzene, hexachloroben-
zene, toluene, naphthalene.
88
-------
Environmental Protection Agency
Pt. 261, App. VII
EPA
hazard-
ous
waste
No.
F025....
F026...
F027...
F028...
F032...
F034..
F035..
F037..
F038..
F039..
K001..
K002...
K003...
K004...
K005...
K006...
K007...
K008...
K009...
K010...
K011..
K013..
K014..
Hazardous constituents for which listed
EPA
hazard-
ous
waste
No.
Chloromethane; Dtctiloromethane; Trichlorometh-
ane; Carbon tetrachloride; Chkxoethylene; 1,1-
Dichloroefhane; 1,2-Dichloroethane; trans-1,2-
Dfchloroethytene; 1,1-Dichloroethylene; 1,1,1-
Trichloroethane; 1,1,2-Trichloroethane; Trichlor-
oethylene; 1,1.1,2-Tetrachioroethane; 1,1,2,2-
Tetrachloroethane; Tetrachloroethylene; Pen-
tachloroethane; Hexachloroethane; Ally! chlo-
ride (3-Chloropropene); Dichloropropane; Dich-
loropropene; 2-Chloro-1,3-butadiene; Hexach-
loro-1,3-butadiene; Hexachlorocyclopentadiene;
Benzene; Chlorobenzene; Dichlorobenzene;
1,2,4-Trichlorobenzene; Tetrachlorobenzene;
Pentachlorobenzene; Hexachlorobenzene; Tolu-
ene; Naphthalene.
Tetra-, penta-, and hexachiorodibenzo-p-dioxins;
tetra-, penta-, and hexachlorodibenzofurans.
Tetra-, penta-, and hexachlorodibenzo-p-dioxins;
tetra-, penta-, and hexachlorodibenzofurans; tri-,
tetra-, and pentachlorophenols and their chloro-
phenoxy derivative acids, esters, ethers, amine
and other salts.
Tetra-, penta-, and hexachlorodibenzo-p-dioxins;
tetra-, penta-, and hexachlorodibenzofurans; tri-,
tetra-, and pentachlorophenols and their chloro-
phenoxy derivative acids, esters, ethers, amine
and other salts.
Benz(a)anthracene, benzo(a)pyrene, dibenz(a.h)-
anthracene, indeno(1,2,3-cd)pyrene, pentachlor-
ophenol, arsenic, chromium, tetra-, penta-,
hexa-, heptachlorodibenzo-p-dioxins, tetra-,
penta-, hexa-, heptachlorodibenzofurans.
Benz(a)anthracene. benzo(k)fluoranthene,
benzo(a)pyrene, dibenz(a,h)anthracene,
indeno(1,2,3-cd)pyrene, naphthalene, arsenic,
chromium.
Arsenic, chromium, lead.
Benzene, benzo(a)pyrene, chrysene, lead, chromi-
um.
Benzene, benzo(a)pyrene chrysene, lead, chromi-
um.
All constituents for which treatment standards are
specified for multi-source leachate (wastewaters
and nonwastewaters) under 40 CFR 268.43(a),
Table CCW.
Pentachlorophenol. phenol, 2-chlorophenol, p-
chloro-m-cresol, 2,4-dimethylphenyl, 2,4-dinitro-
phenol, trichlorophenols, tetrachlorophenols,
2,4-dinitrophenol, cresosote, chrysene, naphtha-
lene, fluoranthene, benzo(b)fluoranthene,
benzo(a)pyrene, indeno(l,2,3-cd)pyrene,
benz(a)anthracene, dibenz(a)anthracene, acen-
aphthalene.
Hexavalent chromium, lead
Hexavalent chromium, lead.
Hexavalent chromium.
Hexavalent chromium, lead.
Hexavalent chromium.
Cyanide (complexed), nexavalent chromium.
Hexavalent chromium.
Chloroform, formaldehyde, methylene chloride.
methyl chloride, paraldehyde, formic acid.
Chloroform, formaldehyde, methylene chloride,
methyl chloride, paraldehyde, formic acid, chtor-
oacetakJehyde.
Acrykxutrite, acetonitrite, hydrocyanic acid.
Hydrocyanic acid, acrytonitrite. acetonitrile.
Acetonitrile, acrylamide.
K015....
K016....
K017....
K018....
K019....
K020....
K021..
K022..
K023..
K024..
K025..
K026..
K027..
K028..
K029..
K030..
K031..
K032..
K033..
K034..
K035..
K036...
K037...
K038...
K039...
K040...
K041...
K042...
K043...
K044...
K045...
K046...
K047...
K048..
K049..
K050..
K051..
K052.,
K060..
K061..
Hazardous constituents for which listed
3enzyl chloride, Chlorobenzene, toluene, benzo-
trichloride.
Hexachlorobenzene, hexachlorobutadiene, carbon
tetrachloride, hexachloroethane, perchloroethy-
lene.
Epichlorohydrin, chloroethers [bis(chloromethyl)
ether and bis (2-chloroethyl) ethers], trichloro-
propane, dichloropropanols.
1,2-dichloroethane, trichloroethylene, hexachloro-
butadiene, hexachlorobenzene.
Ethylene dichloride, 1,1,1-trichloroethane, 1,1,2-
trichloroethane, tetrachloroethanes (1,1,2,2-te-
trachloroethane and 1,1,1,2-tetrachloroethane),
trichloroethylene, tetrachloroethylene, carbon
tetrachloride, chloroform, vinyl chloride, vinyli-
dene chloride.
Ethylene dichloride, 1,1,1-trichloroethane, 1,1,2-
trichloroethane, tetrachloroethanes (1,1,2,2-te-
trachloroethane and 1,1,1,2-tetrachloroethane),
trichloroethylene, tetrachloroethylene, carbon
tetrachloride, chloroform, vinyl chloride, vinyli-
dene chloride.
Antimony, carbon tetrachloride, chloroform.
Phenol, tars (polycyclic aromatic hydrocarbons).
Phthalic anhydride, mateic anhydride.
Phthalic anhydride, 1,4-naphthoquinone.
Meta-dinitrobenzene, 2,4-dinitrotoluene.
Paraldehyde, pyndines, 2-picoline.
Toluene diisocyanate, toluene-2, 4-diamine.
1,1,1-trichloroethane, vinyl chloride.
1,2-dichloroethane, 1,1,1-trichloroethane, vinyl
chloride, vinylidene chloride, chloroform.
Hexachlorobenzene, hexachlorobutadiene, hexa-
chloroethane, 1,1,1,2-tetrachloroethane, 1,1,2,2-
tetrachloroethane, ethylene dichloride.
Arsenic.
Hexachlorocyclopentadiene.
Hexachlorocyclopentadiene.
Hexachlorocyclopentadiene.
Creosote, chrysene, naphthalene, fluoranthene
benzo(b) fluoranthene, benzo(a)pyrene,
indeno(1,2,3-cd) pyrene, benzo(a)anthracene,
dibenzo(a)anthracene, acenaphthalene.
Toluene, phosphorodithioic and phosphorothioic
acid esters.
Toluene, phosphorodithioic and phosphorothioic
acid esters.
Phorate, formaldehyde, phosphorodithioic and
phosphorothioic acid esters.
Phosphorodithioic and phosphorothioic acid
esters.
Phorate, formaldehyde, phosphorodithioic and
phosphorothioic acid esters.
Toxaphene.
Hexachlorobenzene, ortho-dichlorobenzene.
2,4-dichlorophenol, 2,6-dichlorophenol, 2,4,6-trich-
lorophenol.
N.A.
N.A.
Lead.
N.A.
Hexavalent chromium, lead.
Hexavalent chromium, lead.
Hexavalent chromium.
Hexavalent chromium, lead.
Lead.
Cyanide, napthalene, phenolic compounds, ar-
senic.
Hexavalent chromium, lead, cadmium.
89
-------
Pt. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
EPA
hazard-
ous
waste
No.
K062
K064
K065
K066
K069
K071
K073
K083..
K084..
K085..
K086..
K087..
K088..
K090.
K091..
K093.
K094..
K095..
K096.
K097..
K098..
K099.
K100..
K101..
K102..
K103..
K104..
K105..
K106..
Hazardous constituents for which listed
Hexavalent chromium, lead.
Lead, cadmium.
Do.
Do.
Hexavalent chromium, lead, cadmium.
Mercury.
Chloroform, carbon tetrachloride, hexacholroeth-
ane, trichloroethane. tetrachloroethylene, dich-
loroethylene, 1,1,2,2-tetrachloroethane.
Aniline, diphenylamine, nitrobenzene, phenylene-
diamine.
Arsenic.
Benzene, dichlorobenzenes, trichlorobenzenes, te-
trachlorobenzenes, pentachlorobenzene, hex-
achlorobenzene, benzyl chloride.
Lead, hexavalent chromium.
Phenol, naphthalene.
Cyanide (complexes).
Chromium.
Do.
Phthalic anhydride, maleic anhydride.
Phthalic anhydride.
1,1,2-trichkxoethane. 1,1,1,2-tetrachloroethane,
1,1,2,2-tetrachloroethane.
1,2-dfchloroethane, 1,1,1-trichloroethane, 1,1.2-
tnchloroethane.
Chlordane, heptachkx.
Toxaphene.
2,4-dichlorophenol, 2,4,6-trichlorophenol.
Hexavalent chromium, lead, cadmium.
Arsenic.
Arsenic.
Aniline, nitrobenzene, phenylenediamine.
Aniline, benzene, diphenylamine, nitrobenzene,
phenylenediamine.
Benzene, monochlorobenzene, dichlorobenzenes.
2,4,6-trichlorophenol.
Mercury.
EPA
hazard-
ous
waste
No.
K107...
K108...
K109...
K110...
K111...
K112...
K113...
K114...
K115...
K116...
K117...
K118..
K123..
K124..
K125..
K126..
K131..
K132..
K136..
Hazardous constituents for which listed
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
2,4-Dinitrotoluene.
2,4-Toluenediamine, otoluidine, otoluidine, ani-
line.
2,4-Toluenediamirte, otoluidine, otoluidine, ani-
line.
2,4-Toluenediamine, otoluidine, p-toluidine.
2,4-Toluenediamine.
Carbon tetrachloride, tetrachloroethylene, chloro-
form, phosgene.
Ethylene dibromide.
Ethylene dibromide.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Dimethyl sulfate, methyl bromide.
Methyl bromide.
Ethylene dibromide.
N.A.—Waste is hazardous because it fails the test for the
characteristic of ignitability, corrosrvity, or reactivity.
[46 PR 4619, Jan. 16, 1981, as amended at 46
PR 27477, May 20, 1981; 49 FR 5312, Feb.
10, 1984; 50 FR 2000, Jan. 14, 1985; 50 FR
42942, Oct. 23, 1985; 51 FR 5330, Feb. 13,
1986; 51 FR 6541, Feb. 25, 1986; 51 FR
37729, Oct. 24, 1986; 54 FR 35421, Sept. 13,
1989; 54 FR 41407, Oct. 6, 1989; 54 FR 50978,
Dec. 11, 1989; 55 FR 18505, May 2, 1990; 55
FR 22684, June 1, 1990; 55 FR 46396, Nov. 2,
1990; 55 FR 50483, Dec. 6,1990]
APPENDIX VIII TO PART 261—HAZARDOUS CONSTITUENTS
Common name
Aceryl chloride
1 -Acetyl-2-thiourea
Akftcarb
Aldrin
AIM alcohol
AUul rhlfvute
4-Aminobiohenvl
Chemical abstracts name
Same
Ethanone, 1-phenyl-
Acetamide N-9H-fluoren-2-yl-
Same
Acetamide, N-(aminolhioxomethyl)-
2-Propenal
2-Propenamide
2-Propenenitrile
Same
Propanal, 2-methyl-2-(methylthio)-, O-
[(methylamino)carbonyl]oxime.
1,4,5,8-
Dimethanonaphthalene, 1,2.3.4.10,10-10-
hexachloro-1 ,4.4a,5,8.8a-hexahydro-.
(1 alpha,4alpha.4abeta,5alpha,8alpha.
Babeta)-.
2-Propen-1 -ol .
1 -Propane 3-chloro
Same
[1,1'-Biphenyl]-4-amine
Chemical
abstracts No.
75-05-8
98-66-2
53-96-3
75-36-5
591-08-2
107-02-8
79-06-1
107-13-1
1402-68-2
116-06-3
309-00-2
107-18-6
107-18-6
20859-73-6
92-67-1
Hazardous
waste No.
U003
U004
U005
U006
P002
POOS
U007
U009
P070
P004
POOS
P006
90
-------
Environmental Protection Agency
Pt. 261, App. VIII
Common name
Chemical abstracts name
Chemical
abstracts No.
Hazardous
waste No.
5-(Aminomethyl)-3-isoxazolol...
4-Aminopyridine
Amitrole
Ammonium vanadate
Aniline
Antimony
Antimony compounds, N.O.S.1
Aramrte
Arsenic
Arsenic compounds, N.O.S.1..
Arsenic acid
Arsenic pentoxide
Arsenic trioxide
Auramine
Azaserine
Barium
Barium compounds, N.O.S.1...
Barium cyanide
Benztclacridine
Benz[a]anthracene
Benzal chloride
Benzene
Benzenearsonic acid
Benzidine
Benzof.b]fluoranthene
Benzo[j]fluoranthene
Benzo(k)fluoranthene
Benzotalpyrene
p-Benzoquinone
Benzotrichloride
Benzyl chloride
Beryllium
Beryllium compounds, N.O.S.1
Bromoacetone
Bromoform
4-Bromophenyl phenyl ether..
Brucine
Butyl benzyl phthalate
Cacodylic acid
Cadmium
Cadmium compounds, N.O.S.1
Calcium chromate
Calcium cyanide
Carbon disulfide
Carbon oxyfluoride
Carbon tetrachloride
Chloral
Chlorambucil
Chlordane..
Chlordane (alpha and gamma isomers)..
Chlorinated benzenes, N.O.S.1
Chlorinated ethane, N.O.S.1
Chlorinated fiuorocarbons, N.O.S.1
Chlorinated naphthalene, N.O.S.1
Chlorinated phenol, N.O.S.1
Chlomaphazin
Chloroacetaldehyde
Chloroalkyl ethers, N.O.S.1
p-Chloroaniline
Chlorobenzene
Chlorobenzilate
p-Chtoro-m-cresol
2-Chloroethyl vinyl ether
Chloroform
Chloromethyl methyl ether..
3(2H)-lsoxazolone, 5-(aminomethyl)-..
-Pyridinamine
H-1,2,4-Triazol-3-amine
Vanadic acid, ammonium salt
tenzenamine
Same
Sulfurous acid, 2-chloroethyl 2-[4-(1,1-
dimethylethyl)phenoxy]-1-methylethyl
ester.
Same
Arsenic acid H3AsO«
Arsenic oxide AszO5
Arsenic oxide AszOj
Benzenamine, 4,4'-carbonimidoylbis[N,N-di-
methyl.
L-Serine, diazoacetate (ester)
Same
Same
Same
Same
Benzene, (dichloromethyl)-
Same
Arsonic acid, phenyl-
[1,1'-Biphenyl]-4,4 Miamine..
3enz[e]acephenanthrylene
Same
Same
Same
2,5-Cyclohexadiene-1,4-dione.
Benzene, (trichloromethyl)-
Benzene, (Chloromethyl)-
Same
2-Propanone, 1-bromo-
Methane, tribromo-
Benzene, 1-bromo-4-phenoxy-
Strychnidin-10-one, 2,3-dimethoxy-
1,2-Benzenedicarboxylic acid, butyl phenyl-
methyl ester.
Arsinic acid, dimethyl-
Same
Chromic acid H2CrOt, calcium salt.
Calcium cyanide Ca(CN)2
Same
Carbonic difluoride
Methane, tetrachloro-
Acetaldehyde, trichloro-.
acid,
4-[bis(2-
Benzenebutanoic
chloroethyl)amino]-.
4,7-Methano-1H-indene, 1,2,4,5,6.7,8,8-oc-
tachloro-2,3,3a,4,7,7a-hexahydro-.
Naphthalenamine, N,N'-bis(2-chloroethyl)-
Acetaldehyde, chloro-
Benzenamine, 4-chloro-
Benzene, chloro-
Benzeneacetic acid, 4-chloro-alpha-(4-chlor-
ophenyl)-alpha-hydroxy-, ethyl ester.
Phenol, 4-chloro-3-methyl-
Ethene, (2-chloroethoxy)-
Methane, trichloro-
Methane, chloromethoxy-
2763-96-4
504-24-5
61-82-5
7803-55-6
62-53-3
7440-36-0
140-57-8
7440-38-2
7778-39-4
1303-28-2
1327-53-3
492-80-8
115-02-6
7440-39-3
542-62-1
225-51-4
56-55-3
98-87-3
71-43-2
98-05-5
92-87-5
205-99-2
205-82-3
207-08-9
50-32-8
106-51-4
98-07-7
100-44-7
7440-41-7
598-31-2
75-25-2
101-55-3
357-57-3
85-68-7
75-60-5
7440-43-9
13765-19-0
592-01-8
75-15-0
353-50-4
56-23-5
75-87-6
305-03-3
57-74-9
494-03-1
107-20-0
106-47-8
108-90-
510-15-6
59-50-7
110-75-8
67-66-3
107-30-:
P007
POOS
U011
P119
U012
P010
P011
P012
U014
U015
P013
U016
U018
U017
U019
U021
U022
U197
U023
P028
P015
P017
U225
U030
P018
U136
U032
P021
P022
U033
U211
U034
U035
U036
U036
U026
P023
P024
U037
U038
U039
U042
U044
U046
91
-------
Pt. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
Common name
beta-Chloronaphthalene
o-Chlorophenol -
1 -(o-Chk>ropnenyl)thk>urea
Chtoroprene
3-Chloroproptonrtrite
Chrofniom
Chromium compounds N O S *
Chrysene
Citrus red No 2
Coat tar creosote
Copper cyanide
Creosote
Cresof (Cresylic acid)
Crotonaldehyde
Cyanides (soli&le salts and complexes)
N.O.S.'.
Cyanogen bromide
Cyanogen chloride
Cycasin
2-Cydohexyl-4 6-dinitrophenol
Cydophosphamide
24-O
2 4-D salts esters - .
Daunomycin
ODD
DDF
DDT...
DiaHate
Dibenz[a,fi]acndine .. .
Dtb6nz[a h]anthracene
7H-Dibenzo[c glcarbazote
Dtoenzof.a,0pyrene
1 ,2-Dibromo-3-chloropropane
Dtoutyl phthalate
o-Dichlorobenzene
p-Dichlorobenzene
Dichlorobenzene NOS '
3 3'-Dichlorobenzidine
1 4-Dichloro-2-butene
Dichlorodifkjoromethdne
Dichtoroethylene NOS1
1 1 -Dichtoroethylene
1 2-Dichloroethylene
Dichtoroetrryl ether
Dichtoromethoxy ethane
Diohloromethyl ether
2 4-Dicnkxophenol
2,6-Dtchtorophenol
DicNoropropane NOS '
Dichloropropanol NOS1
Dicnloropropene NOS1
1.3-Dichlorooraoene
Chemical abstracts name
Naphthalene 2-chk>ro-
Phenol, 2-chloro-
Thiourea (2-chlorophenyl)-
1 3-Butadiene 2-chloro-
Propanenitrile, 3-chloro-
Same
Same
2-Naphthalenol, 1-[(2,5-
dimethoxyphenyl)azo]-.
Same . .. .
Copper cyanide CuCN
Same
Phenol, methyl-
2-Butenal
Ethanedinitrile
Cyanogen bromide (CN)Br
Cyanogen chloride (CN)a
beta-D-Glucopyranoside (methyl-ONN-
azoxy)methyl.
Phenol 2-cyclohexyl-4 6-dinitro-
2H-1 ,3 2-Oxazaphosphorin-2-amine, N,N-
bis(2-chloroethyl)tetrahydro-, 2-oxide.
Acetic acid (2 4-dichlorophenoxy)-
5,12-Naphthacenedione, 8-acetyl-10-[(3-
amino-2,3,6-trideoxy-alpha-L-lyxo-
hexopyranosyl)oxy ] -7,8,9, 1 0-tetrahydro-
6,8,11-trihydroxy-1-methoxy-. (8S-cis)-.
Benzene, 1,1'-(2,2-dicfiloroethylidene)bis[4-
chloro-.
Benzene 1 r-(dichlOfoethenylidene)tHS[4-
chloro-.
Benzene. 1,1 '-(2,2,2-
tnchloroethylidene)bis[4-chloro-.
Carbamothioic acid, bis(1-methylethyl)-, S-
(2,3-dichloro-2-propenyl) ester.
Same
Same . ..
Same
Same
NaphthoM 2 3 4-def]chrysene
DibenzoCb def}chrysene
Benzo[rst]pentapnene
Propane 1 2-dibromo-3-chloro-
1 ,2-Benzenedicarboxylic acid, dibutyl ester
Benzene, 1,2-dichloro-
Benzene 1 3-dichtoro-
Benzene 1 4-dichloro-
Benzene dichloro-
[1 1'-Biphenyl]-44'-diamine, 3,3'-dichkxo-
2-Butene 1 4-dichtoro-
Methane, dtehtorodifluoro-
Dichkxoethylene
Etnene 1 1-dichkxo-
Ethene, 1,2-dichlrol-, (E)-
Ethane 1 Voxybis[2-chkxo-
Propane 2 2'-oxybisC2-chtoro-
Ethane, 1,1'-[metnytenebts(oxy)]bis[2-
chtoro-.
Methane, oxybisCchloro-
Phenol 2 4-dichloro-
Phenol, 2,6-dJchtoro-
Arsonous dichloride phenyl-
Propane dichloro-
Propano) dichloro-
1-Propene dichloro-
1-Prooene. 1.3-dichtorc-
Chemical
abstracts No.
91-58-7
95-57-8
5344-82-1
126-99-8
542-76-7
7440-47-3
218-01-9
6358-53-8
8007-45-2
544-92-3
1319-77-3
4170-30-3
460-19-5
506-68-3
506-77-4
14901-08-7
131-89-5
50-18-0
94-75-7
20830-81-3
72-54-8
72-55-9
50-29-3
2303-16-4
226-36-8
224-42-0
53-70-3
194-59-2
192-65-4
189-64-0
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
25321-22-6
91-94-1
764-41-0
75-71-8
25323-30-2
75-35-4
156-60-5
111-44-4
108-60-1
111-91-1
542-88-1
120-83-2
87-65-0
696-28-6
26638-19-7
26545-73-3
26952-23-8
542-75-6
Hazardous
waste No.
U047
U048
P026
P027
U050
P029
U051
U052
U053
P030
P031
U246
P033
P034
1)058
U240
U240
U059
U060
U061
U062
U063
U064
U066
U069
U070
U071
U072
U073
U074
U075
U078
U079
U025
U027
U024
P016
U081
U082
P036
U084
92
-------
Environmental Protection Agency
Pt. 261, App. VIII
Common name
Chemical abstracts name
Chemical
abstracts No.
Hazardous
waste No.
Dieldrin..
1,2:3,4-Diepoxybutane.
Diethylarsine
1,4-Diethyleneoxide
Dtethylhexyl phthalate.
N,N'-Diethylhydrazine
O,O-Diethyl S-methyl dithiophosphate.
Diethyl-p-nitrophenyl phosphate
Diethyl phthalate
O,O-Diethyl 0-pyrazinyl phosphoro-thioate.
Diethylstilbesterol.
Dihydrosafrole
Diisopropylfluorophosphate (DFP).
Dimethoate..
3,3'-Dimethoxybenzidine
p-Dimethylaminoazobenzene
7,12-Dimethylbenz[a]anthracene
3,3'-Dimethylbenzidine
Dimethylcarbamoyl chloride
1,1-Dimethylhydrazine
1,2-Dimethylhydrazine
alpha,alpha-Dimethylphenethylamine.
2,4-Dimethylphenol
Dimethyl phthalate
Dimethyl sulfate
Dinitrobenzene, N.O.S.1
4,6-Dinitro-o-cresol
4,6-Dinitro-o-cresol salts
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Dinoseb
Di-n-octyl phthalate
Diphenylamine
1,2-Dipheny)hydrazin9
Di-n-propylnitrosamine
Disulfoton
Dithiobiuret..
Endosulfan..
Endothall.
Endrin
Endrin metabolites.
Epichlorohydrin
Epinephrine
Ethyl carbamate (urethane)
Ethyl cyanide
Etnylenebisdithiocarbamic acid
Ethytenebisdithiocarbamic acid, salts and
esters.
Ethylene dibromide
Ethytene dichloride
Etnytene glycol monoethyl ether
2,7:3,6-Dtmethanonaphth[2,3-b]oxirene,
3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
octahydro-,
(laalpha,2beta,2aalpha,3beta,6beta,
6aalpha,7beta,7aalpha)-.
2,2'-Bioxirane
Arsine, diethyl-
1,4-Dioxane
1,2-8enzenedicarboxylic acid, bis(2-ethyl-
hexyl) ester.
Hydrazine, 1,2-diethyl-
Phosphorodithioic acid, O,O-diethyl S-methyl
ester.
Phosphoric acid, diethyl 4-nitrophenyl ester....
1,2-Benzenedicarboxylic acid, diethyl ester
Phosphorothioic acid, O,O-diethyl O-pyra-
zinyl ester.
Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis-,
(E)-.
1,3-Benzodioxole, 5-propyl-
Phosphorofluoridic acid, bis(l-methylethyl)
ester.
Phosphorodithioic acid, O.O-dimethyl S-t2-
(methylamino)-2-oxoethyl] ester.
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-..
Benzenamine, N,N-dimethyl-4-(phenylazo)-
BenzCalanthracene, 7,12-dimethyl-
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
Carbamic chloride, dimethyl-
Hydrazine, 1,1-dimethyl-
Hydrazine, 1,2-dimethyl-
Benzeneethanamine, alpha.alpha-dimethyl-....
Phenol, 2,4-dimethyl-
1,2-Benzenedicarboxylic acid, dimethyl ester.
Sulfuric acid, dimethyl ester
Benzene, dinitro-
Phenol, 2-methyl-4,6-dinitro-
Phenol, 2,4-dinitro-
Benzene, 1-methyl-2,4-dinitro-
Benzene, 2-methyl-1,3-dinitro-
Phenol, 2-(1 -methylpropyl)-4,6-dinitro-
1,2-Benzenedicarboxylic acid, dioctyl ester
Benzenamine, N-phenyl-
Hydrazine, 1,2-diphenyl-
1-Propanamine, N-nitroso-N-propyl-
Phosphorodithioic acid, O,O-diethyl S-C2-
(ethylthio)ethyl] ester.
Thioimidodicarbonic diamide [(H,N)C(S)]2N
H.
6,9-Methano-2,4,3-benzodioxathiepin,
6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-
hexahydro-, 3-oxide.
7-Oxabicycto[2.2.1]heptane-2,3-dicarboxylic
acid.
2,7:3,6-Dimethanonaphth[2,3-b]oxirene,
3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
octa-hydro-,
(1aalpha,2beta,2abeta,3alpha,6alpha,
6abeta.7beta,7aatpha)-.
Oxirane, (chloromethyl)-
1,2-Benzenediol, 4-[1-hydroxy-2-
(methylamino)ethyl]-, (R)-.
Carbamic acid, ethyl ester
Propanenrtrile
Carbamodithioic acid, 1,2-ethanediylbis-
Ethane, 1,2-dibromo-.
Ethane, 1,2-dichloro-.
Ethanol, 2-ethoxy-
60-57-1
1464-53-5
692-42-2
123-91-1
117-81-7
1615-80-1
3288-58-2
311-45-5
84-66-2
297-97-2
56-53-1
94-58-6
55-91-4
60-51-5
119-90-4
60-11-7
57-97-6
119-93-7
79-44-7
57-14-7
540-73-8
122-09-8
105-67-9
131-11-3
77-78-1
25154-54-5
534-52-1
51-28-5
121-14-2
606-20-2
88-85-7
117-84-0
122-39-4
122-66-7
621-64-7
298-04-4
541-53-7
115-29-7
145-73-3
72-20-8
106-89-8
51-43-4
51-79-6
107-12-0
111-54-6
106-93-4
107-06-2
110-80-5
P037
U085
P038
U108
U028
U086
U087
P041
U088
P040
U089
U090
P043
P044
U091
U093
U094
U095
U097
U098
U099
P046
U101
U102
U103
P047
P047
P048
U105
U106
P020
U017
U109
U111
P039
P049
P050
P088
P051
P051
U041
P042
U238
P101
U114
U114
U067
U077
U359
93
-------
Pi. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
Common name
Chemical abstracts name
Chemical
abstracts No.
Hazardous
waste No.
Ethyteneimine
Ethytene oxide
Ethytenethiourea
Ethylidene dicnloride
Ethyl methacrylate
Ethyl methanesulfonate..
Famphur
Fluoranthene
Fluorine
Fluoroacetamide
Fluoroacetic acid, sodium salt...
Formaldehyde
Formic acid
Grycidylaldehyde
Halomethanes, N.O.S.'
Heptachlor
Aziridine
Oxtrane
2-lmidazolidinethione
Ethane, 1,1-dichloro-
2-Propenoic acid. 2-methyl-, ethyl ester
Methanesulfonic acid, ethyl ester
Phosphorolhiote acid, O-[4-
t(dimethylamino)sulfonyl]phenyl] O,O-di-
methyl ester.
Same
Same
AcetamkJe, 2-fluoro-
Acetic acid, fluoro-, sodium salt
Same
Same
Oxiranecarboxyaldehyde
Heptachlor epoxide..
Heptachlor epoxide (alpha, beta, and
gamma isomers).
Heptachtorodibenzofurans
Heptachlorodibenzo-p-dioxins
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachkxodibenzo-p-dioxins
Hexachlorodibenzofurans
Hexachloroethane
Hexachlorophene
Hexachloropropene
Hexaethyi tetraphosphate
Hydrazine
Hydrogen cyanide
Hydrogen fluoride
Hydrogen suffide
lndenotl,2,3-cd]Dyrene
Isobutyl alcohol
Isodrin
4,7-Methano-1 H-indene, 1,4,5,6,7,8,8-hep-
tachloro-3a,4,7,7a-tetrahydro-.
2,5-Methano-2H-indenof 1,2-Woxirene,
2,3,4,5,6,7,7-heptachloro-1 a,1 b,5,5a,6.6a-
hexa- hydro-,
(1 aalpha, 1 bbeta,2alpha,5alpha,
5abeta,6beta,6aalpha)-.
Benzene, hexachkxo-
1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
Isosafrote..
Kepone
Lasiocarpine..
Lead
Lead compounds. N.O.S.'
Lead acetate
Lead phosphate
Lead subacetate
Lindane
Mateic anhydride.
Matechydrazide.
Malononrtrile
Melphalan
Mercury
Mercury compounds, N.O.S.'.
Mercury fulminate
Methacrytonrtrile
Ethane, hexachtoro-
Phenol. 2,2'-methytenebis[3,4,6-trichloro-...
1-Propene, 1,1,2,3,3,3-hexachloro-
Tetraphosphoric acid, hexaethyl ester
Same
Hydrocyanic acid
Hydrofluoric acid
Hydrogen sulfide H.S
Same
1-Propanol, 2-methyl-
1,4.5,8-
Dimethanonaphthalene, 1,2,3,4,10,10-
hexachloro-1,4,4a,5,8,8a-hexahydro-,
(lalpha,4alpha,4abeta,5beta,8beta,Babeta)-
1,3-Benzodioxole, 5-(1-propenyl)-
1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-
one, 1,1a,3.3a,4,5,5,5a,5b,6-
decachlorooctahydro-.
2-Butenoic acid, 2-methyl-,7-[t2,3-dihydroxy
2-(1 -methoxyethyl)-3-methyl-1 -
oxobutoxy]methyl]-2,3,5,7a-tetrahydro-lH-
pyrrolizin-1-yl ester,
[lS-tlalpha(Z),7(2S',3R*),7aalpha]]-
Sam«
Acetic acid, tead(2+) salt
Phosphoric acid, lead(2+) salt (2:3)
Lead, bis(acetato-O)tetrahydroxytri-
Cyclohexane, 1,2,3,4,5,6-hexachloro-.
(1 alpha,2alpha,3beta,4alpha,5alpha,6beta)-
2,5-Furandk>ne
3,6-Pyridazinedione, 1,2-dihydro-
Propanedinitrile
L-Phenylalanine, 4-tbis(2-
chloroethyl)aminol]-.
Same
151-56-4
75-21-8
96-45-7
75-34-3
97-63-2
62-50-0
52-85-7
206-44-0
7782-41-4
640-19-7
62-74-8
50-00-0
64-18-6
765-34-4
76-44-8
1024-57-3
118-74-1
87-68-3
77-47-4
67-72-1
70-30-4
1888-71-7
757-58-4
302-01-2
74-90-8
7664-39-3
7783-06-4
193-39-5
78-83-1
465-73-6
120-58-1
143-50-0
303-34-1
7439-92-1
301-04-2
7446-27-7
1335-32-6
58-89-9
108-31-6
123-33-1
109-77-3
148-82-3
7439-97-6
Fulminic acid, mercury(2-i-) salt..
2-Propenenitrite, 2-methyl-
628-86-4
126-98-7
P054
U115
U116
U076
U118
U119
P097
U120
P056
P057
P058
U122
U123
U126
P059
U127
U128
U130
U131
U132
U243
P062
U133
P063
U134
U135
U137
U140
P060
U141
U142
4143
U144
U145
U146
U129
U147
U148
U149
U150
U151
P065
U152
94
-------
Environmental Protection Agency
Pt. 261, App. VIII
Common name
Methapyrilene
Methomyl .. ....
Methoxychlor
Methyl bromide .
Methyl chloride
Methyl chlorocarbonate ,
Methyl chloroform
3-Methylcholanthrene
4 4'-Methylenebis(2-chloroaniline)
Methyl ethyl ketone (MEK)
Methyl hydrazine
Methyl iodide
Methyl isocyanate
2-Methytlactonitrile
Methyl methacrylate
Methyl parathton
Methylthiouracil •
Mrtomycin C
MNNG
Naphthalene
Nickel
Nickel compounds N O S '
Nickel carbonyl
Nickel cyanide
Nicotine
Nicotine salts
Nitric oxide
salt.
n-Mitrnnhannl
N-Nitrosodietnyiamine
N-Nrtroso-N-ethylurea
N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane
N-Nitrosonomicotine
j
Chemical abstracts name
1 2-Ethanediamine, N,N-dimethyl-N'-2-pyri-
dinyl-N'-(2-thienylmethyl)-.
Ethanimidothioic acid, N-
[ [ (methylamino)carbonyl ] oxy ] - , methyl
ester.
Benzene, 1, 1 '-(2.2,2-
trichloroethylidene)bis[4-methoxy-.
Methane, bromo-
Methane, chloro-
Carbonochloridic acid, methyl ester
Ethane 1 1 1-trichloro-
Benz[j]aceanthrylene, 1 ,2-dihydro-3-methyl- ...
Benzenamine, 4,4'-methylenebis[2-chloro-
Methane dibromo-..
Methane dichloro-..
2-Butanone ... ....
2-Butanone peroxide
Hydrazine, methyl-
Methane, iodo-
Methane, isocyanato-
Propanenitrile, 2-hydroxy-2-methyl-
2-Propenoic acid, 2-methyl-, methyl ester
Methanesulfonic acid methyl ester
Phosphorothioic acid, O,O-dimethyl O-(4-ni-
trophenyl) ester.
4(1 H)-Pyrimidinone, 2,3-dihydrc-6-methyl-2-
thioxo-.
Azirino[2',3':3,4]pyrrolo[1,2-a]indole-4,7-
dione,
6-amino-8- [ [ (aminocarbonyl)oxy ] methyl ] -
1 , 1 a,2,8,8a,8b-hexahydro-Ba-methoxy-5-
methyl-, [laS-
(1 aalpha,8beta,8aalpha,8balpha)]-.
Guanidine, N-methyl-N'-nitro-N-nitroso-
Ethane 1 1 '-thk>bist2-chlor o-
Same
1 4-Naphthalenedione
1-Naphthatenamine
2-Naphthalenamine
Thiourea 1-naphthalenyl-
Same
Nickel carbonyl Ni(CO)«, (T-4)-
Nickel cyanide Ni(CN),
Pyridine, 3-(1-methy1-2-pyrrolkJinyl)-, (S)-
Nitrogen oxide NO
Benzenamine, 4-nitro-
Benzene, nitre-
Nitrogen oxide NOi
Ethanamine, 2-chloro-N-(2-chloroethyl)-N-
methyl-.
Ethanamine 2-chloro-N-(2-chloroethyl)-N-
methyl-, N-oxide.
1 2,3-Propanetriol, trinitrate
Phenol 4-nitro-
Propane 2-nitro*
1-Butanamine, N-butyl-N-nitroso-
Ethanol 2 2'-(nitrosoimino)bis-
Ethanamine, N-ethyl-N-nitroso-
Methanamine, N-methyl-N-nitroso-
Urea N-ethyl-N-nitroso-
Ethanamine N-methyl-N-nitroso-
Urea N-methyl-N-nitroso-
Carbamic acid, methylnitroso-. ethyl ester
Vinylamine, N-methyl-N-nitroso-
Morpholine 4-nrtroso-
Pyridine, 3-(1-nitroso-2-pyrrolidiny1)-, (S)-
Chemical
abstracts No.
91-80-5
16752-77-5
72-43-5
74-83-9
74-87-3
79-22-1
71-55-6
56-49-5
101-14-4
74-95-3
75-09-2
78-93-3
1338-23-4
60-34-4
74-88-4
624-83-9
75-86-5
80-62-6
66-27-3
298-00-0
56-04-2
50-07-7
70-25-7
505-60-2
91-20-3
130-15-4
134-32-7
91-59-8
86-88-4
7440-02-0
13463-39-3
557-19-7
54-11-5
10102-43-9
100-01-6
98-95-3
10102-44-0
51-75-2
126-85-2
55-63-0
100-02-7
79-46-9
35576-91-1D
924-16-3
1116-54-7
55-18-5
62-75-9
759-73-9
10595-95-6
684-93-5
615-53-2
4549-40-0
59-89-2
16543-55-8
Hazardous
waste No.
U155
P066
U247
U029
U045
U156
U226
U157
U158
U068
U080
U159
U160
P068
U138
P064
P069
U162
P071
U164
U010
U163
U165
U166
U167
U168
P072
P073
P074
P075
P075
P076
P077
U169
P078
P081
U170
U171
U172
U173
U174
P082
U176
U177
U178
P084
95
-------
PI. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
Common name
N-Nitrosopiperidine .. ..
N-Nitrosopyrrolidine .
5-Nitro-o-toluidine . .
Octamethylpyrophosphoramide
Osmium tetrowde . .
Paraldehyde
Pentachtorobenzene
Pentachlorodibenzofurans
Pentachtoroethane
Pentachtoronttrooenzene (PCNB)
Pentachtorophenol
Phenol
Phenytmercury acetate ..
Phosphine
Phorate
Phthalic acid esters N O S *
PhthaNc anhydride
2-PicoHne
Potychkxinaled biphenyts N O S '
Potassium silver cyanide
Pronamide
1 3-propane sultone
Pyridine
Reserpine
Satrote
Silver
Silver compounds N O S '
Sirvex (2 4 5-TP) .
TCDD
Tetrachloroethane N O S l
111 2-Tetrachloroethane
1 1 2,2-Tetrachtoroethane
234 6-Tetrachtorophenoi
Chemical abstracts name
Piperidine, 1-nitroso-
Pyrrolidine, 1-nitroso-
Qlycine N-methyl-N-nitroso-
Benzenamine, 2-methyl-5-nitro-
Diphosphoramide octamethyl-
Osmium oxide OsO., (T-4)-
1 3 5-Trioxane, 2 4,6-trimethyl-
Phosphorothioic acid, O O-diethyl O-(4-nitro-
phenyl) ester.
Benzene, pentachloro-
Ethane pentachloro-
Benzene pentachloronitro-
Phenol, pentachloro-
Acetamide N-(4-ethoxyphenyl)-
Same .
Benzenediamtne
Mercury, (acetatc-O)phenyt-
Thiourea phenyt-
Carbonic dichtonde
Same
Phosphorodithioic acid, O,O-diethyl S-
[(ethylthio)methylj ester.
1 ,3-lsobenzofurandione
Pyridine, 2-methyl-
Potassium cyanide K(CN)
Argentate(1 -), bis(cyano-C)-, potassium
Benzamkle, 3,5-dtehloro-N-(1,1-dimethyl-2-
propynyl)-.
1 ,2-Oxathiolane, 2,2-dk>xide
1-Propanamine
2-Propyn-1-ol
Propane 1 2-dichtoro-
Aziridine 2-methyl-
4( 1 H)-Pyrimidinone 2 3-dihydro-6-propyl-2-
thioxo-.
Same
Yohimban-16-carboxylic acid, 11,17-dimeth-
oxy-18-t(3,4,5-trimethoxybenzoyl)oxyj-
smethyf ester,
(3beta, 1 6beta, 1 7alpha, 1 8beta,20alpha)-.
1 3-Benzenediol
1 2-Benzisothiazol-3(2H)-one, 1,1 -dioxide
1 ,3-Benzodioxote, 5-(2-propenyl)-
Same
Selenious acid
Selenium sulfide SeSi
Same .
Same . .
Silver cyanide Ag(CN)
Propanoic acid, 2-(2,4,5-trichlorophenoxy)-
Sodium cyanide Na(CN)
D-Glucose, 2-deoxy-2-
t f(metriylnitrosoamino)carbonyl)amino] -.
Strychnidin-10-one
Dibenzotb e] 1 1 ,4]dioxin, 2,3,7,8-tetrachloro- .
Benzene 124 5-tetrachtoro-
Ethane tetrachtoro- N O S
Ethane 111 2-tetrachtoro-
Ethane 1 1 2 2-tetrachtoro-
Ethene tetrachkxo-
Phenol 2 3 4.6-tetrachtoro-
ThKxtohosphoric acid, tetraethyl ester
Chemical
abstracts No.
100-75-4
930-55-2
1 3256-22-9
99-55-8
152-16-9
20816-12-0
123-63-7
56-38-2
608-93-5
76-01-7
82-68-8
87-86-5
62-44-2
108-95-2
25265-76-3
62-38-4
103-85-5
75_44_5
7803-51-2
298-02-2
85-44-9
109-06-8
151-50-6
506-61-6
23950-58-5
1120-71-4
107-10-8
107-19-7
78-87-5
75-55-8
51-52-5
110-86-1
50-55-5
108-46-3
81-07-2
94-59-7
7782-49-2
7783-00-8
7488-56-4
630-10-4
7440-22-4
506-64-9
93-72-1
143-33-9
18883-66-4
57-24-9
1746-01-6
95-94-3
25322-20-7
630-20-6
79-34-5
127-18-4
58-90-2
3689-24-5
Hazardous
waste No.
U179
U180
U181
P085
P087
U182
P089
U183
U184
U185
See F027
U187
U188
P092
P093
P095
P096
P094
U190
U191
P098
P099
U192
U193
U194
P102
U083
P067
U196
U200
U201
U202
U202
U203
U204
U205
P103
P104
See F027
P106
U206
P106
P108
U207
U208
U209
U210
SeeF027
P109
96
-------
Environmental Protection Agency
Pt. 261, App. VIII
Common name
Tetraethyl lead ...
Tetraethyl pyrophosphate ....
Tetranitromethane
Thallium
Thallium compounds N.O S '
Thallic oxide
Thallium(l) acetate .
Thallium(l) carbonate
Thallium(l) chloride
Thatlium(l) nitrate
Thallium selenite
Thallium(l) sulfate
Thioacetamide
Thiofanox
Thiomethanol
Thiophenol
Thiosern'carbaz'dfi
Thiourea . ..
Thiram
Toluene .. ... . .
Toluenediamine
Toluene-2 4-diamine
Toluene-2 6-diamine
Toluene-3 4-diamine
Toluene diisocyanate
p-Toluidine
1 2 4-Trichlorobenzene
1 1 2-Trichloroethane
Trichloroethylene
Trichloromethanethiol ...
2 4 5-Trichlorophenol
2 4 6-Trichlorophenol
245-T
1 3 5-Trinitrobenzene
Tris(2 3-dibromopropyl) phosphate
Trypan blue ... ....
Uracil mustard ...
Vanadium pentoxide .. ...
Vinyl chloride
Warfarin
Warfarin
tons less than 0.3%.
Warfarin salts when present at concentra-
tions greater than 0.3%.
Zinc phosphide
Zinc phosphide
Chemical abstracts name
Plumbane tetraethyl-
Diphosphoric acid tetraethyl ester
Methane tetranitro-
Same
Thallium oxide TI2Oj
Acetic acid thailium(1 +) salt
Carbonic acid dithallium(1 + ) salt
Thallium chloride TICI
Nitric acid thallium(1 + ) salt
Selenious acid dithallium(l+) salt
Sulfuric acid dithallium(1 +) salt
Ethanethioamide
2-Butanone 3 3-dtmethyl- 1 -(methylthio)- 0-
[(methylamino)carbonyl] oxime.
Methanethiol
Benzenethiol
Hydrazinecarbothioamide
Same
Thioperoxydicarbonic diamide [(H2N)C(S)]jS
2, tetramethyl-.
Benzene, methyl-
Benzenediamine, ar-methyl-
1 3-Benzenediamine 4-methyl-
1 ,3-Benzenediamine, 2-methyl-
1 2-Benzenediamine 4-methyl-
Benzene, 1 ,3-diisocyanatomethyl-
Benzenamine 2-methyl-
Benzenamine 2-methy(- hydrochtoride
Benzenamine 4-methyl-
Same
Benzene, 1,2,4-trichloro-
Ethane, 1,1,2-trichloro-
Ethene trichloro-
Methanethiol, trichloro-
Methane trichforofluoro-
Phenol 2 4,5-trichloro-
Phenol, 2,4,6-trichloro-
Acetic acid, (2,4,5-trichlorophenoxy)-
Propane 1 2,3-trichloro-
Phosphorothioic acid O O O-triethyl ester
Benzene 1 ,3,5-trinitro-
Aziridine 1 1' 1 "-phosphinothioylidynetris-
1-Propanol, 23-dibromo-, phosphate (3:1)
2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-di-
methyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]-
bis[5-amino-4-hydroxy-, tetrasodium salt.
2,4-(1 H,3H)-Pyrimidinedione, 5-[bis(2-
chloroethyl)amino]-.
Vanadium oxide VjOs
Ethene, chloro-
2H-1 -Benzopyran-2-one, 4-hydroxy-3-(3-oxo-
1-phenylbutyl)-, when present at concen-
trations less than 0.3%.
2H-1 -Benzopyran-2-one, 4-hydroxy-3-(3-oxo-
1-phenylbutyl)-, when present at concen-
trations greater than 0.3%.
Zinc cyanide Zn(CN)2
Zinc phosphide ZnjPi, when present at con-
centrations greater than 10%.
Zinc phosphide Zn3Ps, when present at con-
centrations of 10% or less.
Chemical
abstracts No.
78-00-2
107-49-3
509-14-8
7440-28-0
1314-32-5
563-68-8
6533-73-9
7791-12-0
10102-45-1
12039-52-0
7446-18-6
62-55-5
39196-18-4
74-93-1
108-98-5
79-19-6
62-56-6
137-26-8
108-88-3
25376-45-8
95-80-7
823-40-5
496-72-0
26471-62-5
95-53-4
636-21-5
106-49-0
8001-35-2
120-82-1
79-00-5
79-01-6
75-70-7
75-69-4
95-95-4
88-06-2
93-76-5
25735-29-9
96-18-4
126-68-1
99-35-4
52-24-4
126-72-7
72-57-1
66-75-1
1314-62-1
75-01-4
81-81-2
81-81-2
557-21-1
1314-84-7
1314-84-7
Hazardous
waste No.
Pi 10
P111
P112
P113
U214
U215
U216
U217
P114
P115
U218
P045
U153
P014
P116
U219
U244
U220
U221
U223
U328
U222
U353
P123
U227
U228
P118
U121
See F027
SeeF027
See F027
U234
U235
U236
U237
P120
U043
U248
P001
U248
P001
P121
P122
U249
1 The abbreviation N.O.S. (not otherwise specified) signifies those members of the general class not specifically listed by
name in this appendix.
97
-------
Pt. 261, App. IX
40 CFR Ch. I (7-1-92 Edition)
[53 PR 13388, Apr. 22, 1988, as amended at 53 FR 43881, Oct. 31, 1988; 54 FR 50978, Dec. 11,
1989; 55 FR 50483. Dec. 6, 1990; 56 FR 7568, Feb. 25, 1991]
APPENDIX IX TO PART 261—WASTES EXCLUDED UNDER §§ 260.20 AND 260.22
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES
Facility
Address
Waste description
Aptus. Inc
Coffeyville,
Kansas.
Kiln residue and spray dryer/baghouse residue (EPA Hazardous Waste No. F027) generated
during the treatment of cancelled pesticides containing 2,4,5-T and Silvex and related
materials by Aptus1 incinerator at Coffeyville, Kansas after December 27, 1991, so long as:
(1) The incinerator is monitored continuously and is in compliance with operating permit
conditions. Should the incinerator fail to comply with the permit conditions relevant to the
mechanical operation of the incinerator, Aptus must test the residues generated during the
run when the failure occurred according to the requirements of Conditions (2) through (4),
regardless of whether or not the demonstration in Condition (5) has been made.
(2) A minimum of four grab samples must be taken from each hopper (or other container) of
kiln residue generated during each 24 hour run; all grabs collected during a given 24 hour
run must then be composited to form one composite sample. A minimum of four grab
samples must also be taken from each hopper (or other container) of spray dryer/
baghouse residue generated during each 24 hour run; all grabs collected during a given 24
hour run must then be composited to form one composite sample. Prior to the disposal of
the residues from each 24 hour run, a TCLP leachate test must be performed on these
composite samples and the leachate analyzed for the TC toxic metals, nickel, and
cyanide. If arsenic, chromium, lead or silver TC leachate test results exceed 1.6 ppm,
barium levels exceed 32 ppm, cadmium or selenium levels exceed 0.3 ppm, mercury
levels exceed 0.07 ppm, nickel levels exceed 10 ppm, or cyanide levels exceed 6.5 ppm,
the wastes must be retreated to achieve these levels or must be disposed in accordance
with subtitle C of RCRA. Analyses must be performed according to SW-846 methodolo-
gies.
(3) Aptus must generate, prior to the disposal of the residues, verification data from each 24
hour run for each treatment residue (i.e., kiln residue, spray dryer/baghouse residue) to
demonstrate that the maximum allowable treatment residue concentrations listed below
are not exceeded. Samples must be collected as specified in Condition (2). Analyses must
be performed according to SW-846 methodologies. Any residues which exceed any of the
levels listed below must be retreated or must be disposed of as hazardous.
Kiln residue and spray dryer/baghouse residue must not exceed the following levels:
Aldrin—0.015 ppm
Benzene—9.7 ppm
Benzo(a)pyrene—0.43 ppm
Benzo(b)fluoranthene—1.8 ppm
Chlordane—0.37 ppm
Chloroform—5.4 ppm
Chrysene—170 ppm
Dibenz(a,h)anthracene—0.083 ppm
1,2-Dichloroethane—4.1 ppm
Dichloromethane— 2.4 ppm
2,4-Dichlorophenol—480 ppm
Dichlorvos—260 ppm
Disulfaton—23 ppm
Endosullan 1—310 ppm
Fluorene—120 ppm
lndeno(1,2.3,cd)-pyrene—330 ppm
Methyl parathion—210 ppm
Nitrosodiphenylamine—130 ppm
Phenanthrene—150 ppm
Polychlorinated biphenyls—0.31 ppm
Tetrachloroethylene—59 ppm
2,4,5-TP (silvex)—110 ppm
2,4.6-Trichloropnenol—3.9 ppm
98
-------
Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Arco Building
Products.
Arco Chemical
Co.
Arkansas
Department
of Pollution
Control and
Ecology.
Sugarcreek.
Ohio.
Miami, FL
Vertac
Superfund
site,
Jackson-
ville,
Arkansas.
(4) Aptus must generate, prior to disposal of residues, verification data from each 24 hour
run for each treatment residue (i.e., kiln residue, spray dryer/baghouse residue) to
demonstrate that the residues do not contain tetra-, penta-, or hexachlorodibenzo-p-dioxins
or furans at levels of regulatory concern. Samples must be collected as specified in
Condition (2). The TCDD equivalent levels for the solid residues must be less than 5 ppt.
Any residues with detected dioxins or furans in excess of this level must be retreated or
must be disposed of as acutely hazardous. SW-846 Method 8290, a high resolution gas
chromatography and high resolution mass spectroscopy (HRGC/HRMS) analytical method
must be used. For tetra- and penta-chlorinated dioxin and furan homoiogs, the maximum
practical quantitation limit must not exceed 15 ppt for the solid residues. For hexachiorin-
ated dioxin and furan homologs, the maximum practical quantitation limit must not exceed
37 ppt for the solid residues.
(5) The test data from Conditions (1), (2), (3), and (4) must be kept on file by Aptus for
inspection purposes and must be compiled, summarized, and submitted to the Director for
the Characterization and Assessment Division. Office of Solid Waste, by certified mail on a
monthly basis and when the treatment of the cancelled pesticides and related materials is
concluded. The testing requirements for Conditions (2), (3), and (4) will continue until
Aptus provides the Director with the results of four consecutive batch analyses for the
petitioned wastes, none of which exceed the maximum allowable levels listed in these
conditions and the director notifies Aptus that the conditions have been lifted. All data
submitted will be placed in the RCRA public docket.
(6) Aptus must provide a signed copy of the following certification statement when submitting
data in response to the conditions listed above: "Under civil and criminal penalty of law for
the making or submission of false or fraudulent statements or representations, I certify that
the information contained in or accompanying this document is true, accurate, and
complete. As to the (those) identified section(s) of this document for which I cannot
personally verify its (their) truth and accuracy,! certify as the company official having
supervisory responsibility for the persons who, acting under my direct instructions, made
the verification that this information is true, accurate, and complete."
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after August 15, 1986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO19) generated from
the chemical conversion coating of aluminum after April 29, 1986.
Kiln ash, cyclone ash, and calcium chloride salts from incineration of residues (EPA
Hazardous Waste No. F020 and F023) generated from the primary production of 2,4,5-T
and 2,4-D after August 24, 1990. This one-time exclusion applies only to the incineration
of the waste materials described in the petition, and it is conditional upon the data
obtained from ADPC&E's full-scale incineration facility. To ensure that hazardous constitu-
ents are not present in the waste at levels of regulatory concern once the full-scale
treatment facility is in operation, ADPC&E must implement a testing program for the
petitioned waste. This testing program must meet the following conditions for the exclusion
to be valid:
(1) Testing: Sample collection and analyses (including quality control (OC) proce-
dures) must be performed according to SW-846 methodologies.
(A) Initial testing: Representative grab samples must be taken from each
drum and kiln ash and cyclone ash generated from each 24 hours of
operation, and the grab samples composited to form one composite
sample of ash for each 24-hour period. Representative grab samples
must also be taken from each drum of calcium chloride salts generated
from each 24 hours of operation and composited to form one composite
sample of calcium chtoride salts for each 24-hour period. The initial
testing requirements must be fullfilled for the following wastes: (i)
Incineration by-products generated prior to and during the incinerator's
trial burn; (ii) incineration by-products from the treatment of 2,4-D wastes
lor one week (or 7 days if incineration is not on consecutive days) after
completion of the trial burn; (iii) incineration by-products from the
treatment of blended 2,4-D and 2,4, 5-T wastes for two weeks (or 14
days if incineration is not on consecutive days) after completion of the
trial burn; and (iv) incineration by-products from the treatment of blended
2,4-D and 2,4,5-T wastes for one week (or 7 days if incineration is not
on consecutive days) when the percentage of 2, 4, 5-T wastes exceeds
the maximum percentage treated under Condition (1}(A)(iu). Prior to
disposal of the residues from each 24-hour sampling period, the daily
composite must be analyzed for all the constituents listed in Condition
(3). ADPC&E must report the analytical test data, including quality control
information, obtained during this initial period no later than 90 days after
the start of the operation.
99
-------
Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
(B) Subsequent testing: Representative grab samples of each drum of kiln
and cyclone ash generated from each week of operation must be
composited to form one composite sample of ash for each weekly
period. Representative grab samples of each drum of calcium chloride
salts generated from each week of operation must also be composited
to form one composite sample of calcium chloride salts for each weekly
period.
Prior to disposal of the residues from each weekly sampling period, the
weekly composites must be analyzed for all of the constituents listed in
Condition (3). The analytical data, including quality control information,
must be compiled and maintained on site for a minimum of three years.
These data must be furnished upon request and made available for
inspection by any employee or representative of EPA.
(2) Waste holding: The incineration residues that are generated must be stored as
hazardous until the initial verification analyses or subsequent analyses are
completed.
If the composite incineration residue samples (from either Condition (1)(A) or
Condition (1)(B)) do not exceed any of the delisting levels set in Condition (3), the
incineration residues corresponding to these samples may be managed and
disposed of in accordance with all applicable solid waste regulations.
If any composite incineration residue sample exceeds any of the delisting levels set
in Condition (3), the incineration residues generated during the time period
corresponding to this sample must be retreated until they meet these levels
(analyses must be repeated) or managed and disposed of in accordance with
subtitle C of RCRA. Incineration residues which are generated but for which
analysis is not complete or valid must be managed and disposed of in
accordance with subtitle C of RCRA, until valid analyses demonstrate that the
wastes meet the delisting levels.
(3) Delisting levels: If concentrations in one or more of the incineration residues for
any of the hazardous constituents listed below exceed their respective maximum
allowable concentrations also listed below, the batch of failing waste must either
be re-treated untH it meets these levels or managed and disposed of in
accordance with subtitle C of RCRA.
(A) Inorganics (teachable): Arsenic, 0.32 ppm; Barium, 6.3 ppm; Cadmium,
0.06 ppm; Chromium, 0.32 ppm; Cyanide, 4.4 ppm; Lead. 0.32 ppm;
Mercury, 0.01 ppm; Nickel, 4.4 ppm; Selenium, 0.06 ppm; Silver, 0.32
ppm. Metal concentrations must be measured in the waste teachate as
per 40 CFR 261.24. Cyanide extractions must be conducted using
distilled water.
(B) Organics: Benzene, 0.87 ppm; Benzo(a)anthracene, 0.10 ppm;
Benzo(a)pyrene, 0.04 ppm; Benzo (b)fluoranthene, 0.16 ppm; Chloroben-
zene, 152 ppm; o-Chkxophenol, 44 ppm; Chrysene, 15 ppm; 2, 4-D. 107
ppm; DDE, 1.0 ppm; Dibenz(a,h)anthracene, 0.007 ppm; 1, 4-Dtehtoro-
benzene, 265 ppm; 1, 1-Dichloroethylene, 1.3 ppm; trans-1,2-Dichloroeth-
ytene. 37 ppm; Dtchtoromethane, 0.23 ppm; 2,4-Dichlorophenol, 43 ppm;
Hexachkxobenzene, 0.26 ppm; Indeno (1,2,3-cd) pyrene, 30 ppm; Poly-
chlorinated biphenyls. 12 ppm; 2,4.5-T. 1 x 10 • ppm; 1,2,4,5-Tetrach-
lorobenzene, 56 ppm; Tetrachloroethylene, 3.4 ppm; Trichtoroethylene.
1.1 ppm; 2.4,5-Trichtorophenol. 21,000 ppm; 2,4,6-Trichlorophenol, 0.35
ppm.
(C) Chlorinated dtoxins and furans: 2,3,7,8-Tetrachlorodibenzo-p
-------
Environmental Protection Agency Pt. 261, App. IX
TABLE 1 —WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
BBC Brown
Boveri, Inc.
Boeing
Commercial
Airplane Co.
Bommer
Industries
Inc.
Capitol
Products
Corp.
Caprtol
Products
Corporation.
Chamberiian-
Feathertite,
Inc.
Cincinnati
Metropolitan
Sewer
District.
day
Equipment
Corporation.
Continental
Can Co.
Dover Corp.,
Norn's Drv.
Eli Lilly and
Company.
Sanford, FL
Auburn,
Washington.
Landrum, SC...
Harrisburg, PA.
KenUand, IN....
Hot Springs,
AR.
Cincinnati, OH
Cedar Falls,
Iowa.
CHympia, WA.
Tulsa, OK
Clinton,
Indiana.
(5) Data submittals: Within one week of system start-up, ADPC&E must notify the
Section Chief, Variances Section (see address below) when the lull-scale inciner-
ation system is on-line and waste treatment has begun. The data obtained
through Condition (1)(A) must be submitted to the Section Chief, Variances
Section, PSPD/OSW (OS-343), U.S. EPA, 401 M Street SW., Washington, DC
20460, within the time period specified. At the Section Chief's request, ADPC&E
must submit analytical data obtained through Condition (1)(B) within the time
period specified by the Section Chief. Failure to submit the required data obtained
from Condition (1)(A) within the specified time period or to maintain the required
records for the time specified in Condition (t)(B) (or to submit data within the lime
specified by the Section Chief) will be considered by the Agency, at its discretion,
sufficient basis to revoke ADPCSE's exclusion to the extent directed by EPA. All
data must be accompanied by the following certification statement:
"Under civil and criminal penalty of law for the making or submission of false or
fraudulent statements or representations (pursuant to the applicable provisions of
the Federal Code, which include, but may not be limited to. 18 U.S.C. 1001 and
42 U.S.C. 6928), I certify that the information contained in or accompanying this
document is true, accurate and complete. As to the (those) identified section(s) of
this document for which I cannot personally verify its (their) truth and accuracy, I
certify as the company official having supervisory responsibility for the persons
who, acting under my direct instructions, made the verification that this informa-
tion is true, accurate and complete. In the event that any of this information is
determined by EPA in its sole discretion to be false, inaccurate or incomplete,
and upon conveyance of this fact to the company, I recognize and agree that this
exclusion of wastes will be void as if it never had effect or to the extent directed
by EPA and that the company will be liable for any actions taken in contravention
of the company's RCRA and CERCLA obligations premised upon the company's
reliance on the void exclusion."
Dewatered Waslewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after October 17. 19S6.
Residually contaminated soils in an inactive sludge pile containment area on March 27,
1990, previously used to store wastewater treatment sludges generated from electroplating
operations (EPA Hazardous Waste No. F006).
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from their
electroplating operations and contained in evaporation ponds #1 and #2 on August 12,
1987.
Dewatered wastewater treatment slugdges (EPA Hazardous Waste No. FO19) generated
from the chemical conversion coating of aluminum after September 12, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after November 17, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after July 16, 1986.
Sluiced bottom ash (approximately 25,000 cubic yards) contained in the South Lagoon, on
September 13, 1985 which contains EPA Hazardous Waste Nos. F001, F002, F003, F004,
and F005.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) and spent
cyanide bath solutions (EPA Hazardous Waste No. F009) generated from electroplating
operations and disposed of in an on-site surface impoundment. This is a onetime
exclusion. This exclusion was published on August 1, 1989.
Dewatered wastewater treatment sludges (DPA Hazardous Waste No. FO19) generated from
the chemical conversion coating of aluminum after September 12, 1986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO06) generated from
their electroplating operations after April 29, 1986.
Incinerator scrubber liquids, entering and contained in their onsite surface impoundment, and
solids settling from these liquids originating from the burning of spent solvents (EPA
Hazardous Waste Nos. F002. F003, and F005) contained in their onsite surface impound-
ment and solids retention area on August 18, 1988 and any new incinerator scubber
liquids and settled solids generated in the surface impoundment and and disposed of in
the retention are after August 12, 1988.
101
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Pf. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
EPA's Mobile
Incineration
System.
Denney Farm
Site;
McDowell,
MO.
Envirite
Corporation.
Canton, Ohio;
Harvey,
Illinois;
Thomaston,
Connecticut;
and York,
PA.
Falconer
Glass
IndusL. Inc.
Florida
Production
Engineering
Company.
General Cable
Co.
Falconer, NY.
Daytona
Beach,
Florida.
Muncie, IN
Process wastewater, rotary kiln ash, CHEAF media, and other solids (except spent activated
carbon) (EPA Hazardous Waste Nos. F020, F022, F023, F026, F027, and F028) generated
during the field demonstration of EPA's Mobile Incinerator at the Denney Farm Site in
McDowell, Missouri, after July 25, 1985, so long as: (1) The incinerator is functioning
properly; (2) a grab sample is taken from each tank of wastewater generated and the EP
leachate values do not exceed 0.03 ppm for mercury. 0.14 ppm for selenium, and 0.68
ppm for chromium; and (3) a grab sample is taken from each drum of soil or ash
generated and a core sample is collected from each CHEAF roll generated and the EP
leachate values of daily composites do not exceed 0.044 ppm in ash or CHEAF media for
mercury or 0.22 ppm in ash or CHEAF media for selenium.
Dewatered wastewater sludges (EPA Hazardous Waste No. F006) generated from electro-
plating operations; spent cyanide plating solutions (EPA Hazardous Waste No. F007)
generated from electroplating operations; plating bath residues from the bottom of plating
baths (EPA Hazardous Waste No. F008) generated from electroplating operations where
cyanides are used in the process; spent stripping and cleaning bath solutions (EPA
Hazardous Waste No. F009) generated from electro-plating operations where cyanides are
used in the process; spent cyanide solutions from salt bath pot cleaning (EPA Hazardous
Waste No. F011) generated from Metal heat treating operations; quenching wastewater
treatment sludges (EPA Hazardous Waste No. F012) generated from metal heat treating
where cyanides are used in the process; wastewater treatment sludges (EPA Hazardous
Waste No. F019) generated from the chemical conversion coating of aluminum after
November 14, 1986. To ensure that hazardous constituents are not present in the waste
at levels of regulatory concern, the facility must implement a contingency testing program
for the petitioned wastes. This testing program must meet the following conditions for the
exclusions to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
EP Toxicity test for arsenic, barium, cadmium, chromium, lead, selenium, silver, mercury,
and nickel. If the extract concentrations for chromium, lead, arsenic, and silver exceed
0.315 ppm; barium levels exceed 6.3 ppm; cadmium and selenium exceed 0.063 ppm;
mercury exceeds 0.0126 ppm; or nickel levels exceed 2.205 ppm, the waste must be re-
treated or managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive and leachable cyanide. If the
reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
test without acetic acid adjustment) exceed 1.26 ppm, the waste must be re-treated or
managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the
permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of specific organic toxicants. If
the total content of anthracene exceeds 76.8 ppm, 1,2-diphenyl hydrazine exceeds 0.001
ppm, methylene chloride exceeds 8.18 ppm, methyl ethyl ketone exceeds 326 ppm, n-
nitrosodiphenylamine exceeds 11.9 ppm, phenol exceeds 1,566 ppm, tetrachloroethylene
exceeds 0.188 ppm, or trichloroethylene exceeds 0.592 ppm, the waste must be managed
and disposed as a hazardous waste under 40 CFR Parts 262 and 265 and the permitting
standards of 40 CFR Part 270.
(4) A grab sample must be collected from each batch to form one monthly composite
sample which must be tested using GC/MS analysis for the compounds listed in #3 above
as well as the remaining organics on the priority pollutant list. (See 47 FH 52309
November 19, 1982, for a list of the priority pollutants.)
(5) The data from conditions 1-4 must be kept on file at the facility for inspection purposes
and must be compiled, summarized, and submitted to the Administrator by certified mail
semi-annually. The Agency will review this information and if needed will propose to
modify or withdraw the exclusion.
The organics testing described in conditions 3 and 4 above are not required until six months
from the date of promulgation. The Agency's decision to conditionally exclude the
treatment residue generated from the wastewater treatment systems at these facilities
applies only to the wastewater and solids treatment systems as they presently exist as
described in the delisting petition. The exclusion does not apply to the proposed process
additions described in the petition as recovery including crystalization, electrolytic metals
recovery, evaporative recovery, and ion exchange.
Wastewater treatment sludges from the filter press and magnetic drum separator (EPA
Hazardous Waste No. F006) generated from electroplating operations after July 16, 1986.
This is a one-time exclusion. Wastewater treatment sludges (EPA Hazardous Waste No.
F006) generated from electroplating operations and contained in four on-site trenches on
January 23. 1987.
Dewatered wastewater treatment sludges (EPA Hazardous Waste Nos. F006 and K062)
generated from electroplating operations and steel finishing operations after October 24,
I 1986. This exclusion does not apply to sludges in any on-site impoundments as of this
I date.
102
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Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
General
Electric
Company.
General
Motors
Corp.,
Fisher Body
Division.
Shreveport
Louisiana.
Elyria, OH....
Geological
Reclamation
Operations
and
Systems,
Inc.
Morrisville, PA.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and contained in four on-site treatment ponds on August 12, 1987.
The residue generated from the use of the Chemfix* treatment process on sludge (EPA
Hazardous Waste No. F006) generated from electroplating operations and contained in
three on-site surface impoundments on November 14, 1986. To assure that stabilization
occurs, the following conditions apply to this exclusion:
(1) Mixing ratios shall be monitored continuously to assure consistent treatment.
(2) One grab sample of the treated waste shall be taken each hour as it is pumped to the
holding area (cell) from each trailer unit. At the end of each production day, the grab
samples from the individual trailer units will be composited and the EP toxicity test will be
run on each composite sample. If lead or total chromium concentrations exceed 0.315
ppm or if nickel exceeds 2.17 ppm, in the EP extract, the waste ill be removed and
retreated or disposed of as a hazardous waste.
(3) The treated waste shall be pumped into bermed cells which are constructed to assure
that the treated waste is identifiable and retrievable (i.e., the material can be removed and
either disposed of as a hazardous waste or retreated if conditions 1 or 2 are not met).
Failure to satisfy any of these conditions would render the exclusion void. This is a one-time
exclusion, applicable only to the residue generated from the use of the Chemfix* treatment
process on the sludge currently contained in the three on-site surface impoundments.
Wastewater treatment sludge filter cake from the treatment of EPA Hazardous Waste No.
F039, generated at a maximum annual rate of 1,000 cubic yards. This exclusion was
published on August 20, 1991. This exclusion covers the filter cake resulting from the
treatment of hazardous leachate derived from only "old" GROWS and non-hazardous
leachate derived from only non-hazardous sources. This exclusion does not address the
wastes disposed of in the "old" GROWS Landfill or the grit generated during the removal
of heavy solids from the landfill leachate. To ensure that hazardous constituents are not
present in the filter cake at levels of regulatory concern, GROWS must implement a
testing program for the petitioned waste. This testing program must meet the conditions
listed below in order for the exclusion to be valid:
(1) Testing: Sample collection and analyses, including quality control (QC) procedures, must
be performed according to SW-846 methodologies.
(A) Sample Collection: Each batch of waste generated over a four-week period must be
collected in containers with a maximum capacity of 20-cubic yards. At the end of the four-
week period, each container must be divided into four quadrants and a single, full-depth
core sample shall be collected from each quadrant. All of the full-depth core samples then
must be composited under laboratory conditions to produce one representative composite
sample for the four-week period.
(B) Sample Analysis: Each four-week composite sample must be analyzed for all of the
constituents listed in Condition (3). The analytical data, including quality control informa-
tion, must be compiled and maintained on site for a minimum of three years. These data
must be furnished upon request by any employee or representative of EPA or state of
Pennsylvania.
(2) Waste Holding: The dewatered filter cake waste must be stored as hazardous until the
verification analyses are completed.
If the four-week composite sample does not exceed any of the delisting levels set in
Condition (3), the filter cake waste corresponding to this sample may be managed and
disposed of in accordance with all applicable solid waste regulations. If the four-week
composite sample exceeds any of the delisting levels set in Condition (3), the filter cake
waste generated during the time period corresponding to the four-week composite sample
must be retreated until it meets these levels (analyses must be repeated) or managed and
disposed of in accordance with subtitle C of RCRA.
Filter cake waste which is generated but for which analyses are not complete or valid must
be managed and disposed of in accordance with subtitle C of RCRA, until valid analyses
demonstrate that the waste meets the delisting levels.
(3) Delisting Levels: If the concentrations in the four-week composite sample of the filter
cake waste for any of the hazardous constituents listed below exceed their respective
maximum allowable concentrations (ppm) also listed below, the four-week batch of failing
filter cake waste must either be retreated until it meets these levels or managed and
disposed of in accordance with subtitle C of RCRA.
(A) Inorganics (Leachable):
Arsenic—0.79
Barium—15.9
Cadmium—0.16
Chromium—0.79
Cyanide—11.1
Lead—0.79
Mercury—0.032
Selenium—0.16
103
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Silver— 0.79
Nickel— 11.1
Leachable metal concentrations must be measured in the filter cake leachate as per 40 CFR
§261.24. Cyanide extractions must be conducted using distilled water in place of the
leaching media per 40 CFR § 261 .24.
(B) Organics:
Acetone— 2.02E+ 03
Acetophenone — 3.53E + 04
Acetonitrile; Methyl cyanide— 2.43E+ 01
Acrolein— 1.38E+02
Acrylonitrile— 6.26E - 04
Aldrin— 5.27E-03
Aniline— 8.72E- 01
Anthracene— 3.01 E + 02
Benzene— 3.47E + 00
Benzo[a]anthracene — 5.78E— 01
Benzo(b)f luoranthene — 6.4 1 E - 0 1
Benzo(k)fluoranthene— 3.04E + 03
BenzoCalpyrene — 1 .51 E —01
gamma-BHC; Lindane— 5.90E-01
Bis(2-chloroethyl) ether— 6.94E- 04
Bis(2-ethylhexyl) phthalate— 1.64E + 02
Bromodichloromethane — 2.94E + 03
Bromoform; Tribromomethane — 3.76E + 03
Butyl benzyl phthalate— 2.49E + 05
Carbon disulfide— 4.98E + 04
Carbon tetrachloride— 5.49E+00
Chlordane— 7.51E + 01
p-Chloroaniline— 1 .85E+02
Chlorobenzene— 5.95E + 02
Chlorobenzilate— 1 .68E + 03
p-Chloro-m-cresol— 5. 1 BE + 02
Chloroform— 1 .94E + 00
2-Chlorophenol— 1 .72E+02
Chrysene— 5.92E + 01
Cresol— 4.91E + 03
2,4-D; 2.4-Dichlorophenoxyacetic acid — 4.17E+02
4,4'-DDD; ODD— 2.33E+00
4,4'-DDE; DDE— 3.86E + 00
4,4'-DDT; DDT— 1.21 E + 01
Dibenzta,h]anthracene— 2.86E-02
Dibromochloromethane; Chlorodibromomethane— 3.05E + 03
1 ,2-Dibromo-3-chloropropane — 4.09E - 02
1,2-Dibromoethane; Ethylene dibromide— 2.37E-03
Di-n-butyl phthalate— 9.84E+ 05
o-Dichlorobenzene; 1 ,2-Dichlorobenzene— 1 .95E + 04
m-Dichlorobenzene; 1 ,3-Dichlorobenzene— 1.87E+05
p-Dichlorobenzene; 1 ,4-Dichlorobenzene— 1.03E+03
3,3'-Dichlorobenzidine— 2.21 E - 01
Dichlorodif luoromethane — 4. 1 5E + 05
1 , 1 -Dichloroethane— 4.45E - 02
1 ,2-Dichloroethane; Ethylene dichloride— 1.45E + 00
1 ,1 -Dichloroethylene— 4.96E + 00
trans-1 ,2-Dichloroethylene— 1 .42E + 02
2,4-Dichlorophenol— 1 .69E+02
1 ,2-Dichloropropane— 2.73E + 00
1 ,3-Dichloropropene (total cis and trans isomers)— 2.32E-02
Dieldrin— 5.04E-03
Diethyl phthalate— 1.00E + 06
Dimethoate— 1 .32E + 00
7,1 2-Dimethylbenz[a]anthracene— 1 .46E - 02
2,4-Dimethylphenol— 4.87E + 01
Dimethyl phthalate— 1.00E + 06
m-Dinitrobenzene— 5. 1 4E + 00
4,6-Otnitro-o-cresol— 2.00E + 02
2,4-Dinitrophenol— 8.96E+01
Dinitrotoluene (total of-2,4- and 2,6- isomers)— 4.54E-03
Dinoseb; DNBP— 5.26E + 02
Di-n-octyl phthalate— 1.34E+05
1 ,4-Dioxane— 7.89E - 02
104
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Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Goodyear Tire
and Rubber
Co.
Gould, Inc
Randleman,
NC.
McConnels-
ville, OM.
Diphenylamine—4.81 E+04
Disulfoton—3.34E+00
Endosulfan I and Endosulfan II (total)—7.74E+01
Endrin—3.92E + 00
Ethylbenzene— 1.94E + 04
Fluoranthene— 1.16E + 05
Fluorene—4.09E + 01
Heptachlor—1.31E + 01
Heptachlor epoxide—3.26E+00
Hexachlorobenzene—1.02E + 00
Hexachlorobutadiene—2.01 E+01
Hexachlorocyclopentadiene—3.23E+04
Hexachloroethane— 1.15E + 01
Hexachlorophene;— 1.22E+04
Indeno (1,2,3-cd) pyrene—1.16E+02
Isobutyl alcohol; Isobutanol—3.22E+04
Isophorone—2.86E+00
Methacrylonitrile; 2-methyl-2-Propenenitrile—5.77E—01
Methoxychlor—1.03E + 05
Methylbromide; Bromomethane—1.41E+02
Methyl chloride; Chloromethane—3.22E + 04
Methylene chloride; Dichloromethane—9.07E-01
Methyl ethyl ketone; 2-Butanone—1.50E+03
Methyl methacrylate—5.08E + 05
Methyl parathion; Phosphorothioic acid—5.27E+01
4-Methyl-2-pentanone; Methyl isobutyl ketone—6.40E +03
Naphthalene—1 .OOE + 06
Nitrobenzene—2.56E + 01
N-Nitroso-di-n-butylamine—8.15E - 05
N-Nitrosodiethylamine—2.00E - 07
N-Nitrosodimethylamine—2.19E - 05
N-Nitrosodiphenylamine—4.55E + 01
N-Nitrosodipropylamine; Di-n-propylnitrosamine; N-Nitrosodi-n-propylamine—5.02E - 05
Nitrosopyrrolidine; N-Nitrosopyrrolidine; l-nitroso-Pyrrolidine—3.06E - 05
Polychlorinated biphenyls;—4.77E + 01
Pentachlorobenzene—8.91 E + 03
Pentachloronitrobenzene—2.82E+00
Pentachlorophenol—1.14E+04
Phenanthrene—5.46E + 01
Phenol—8.00E+04
Pronamide—2.13E+05
Pyrene—1.OOE+ 06
Pyridine—1.31E+01
Silvex; 2,4,5-TP; 2-(2,4,5-trichlorophenoxy)-Propanoic acid—3.87E+01
Styrene—9.14E + 00
2,4,5-T; 2,4,5-Trichloropnenoxyacetic acid—6.63E+03
1,2,4,5-Tetrachlorobenzene—2.19E+02
1,1,2,2-Tetrachloroethane—2.28E - 02
Tetrachloroethene; Tetrachloroethylene—1.34E+01
2,3,4,6-Tetrachlorophenol—1.17E + 04
Tetraethyl dithiopyrophosphate—2.51 E + 02
Toluene—4.58E +04
Toxaphene—3.09E + 02
1,2,4-Trichlorobenzene—4.75E+04
1,1,1-Trichloroethane—8.70E+02
1,1,2-Trichloroethane—9.03E - 02
Trichloroethylene; Trichloroethene—4.47E + 00
Trichlorof luoromethane—3.31E+05
2,4,5-Trichlorophenol—8.20E+04
2,4,6-Trichlorophenol—1.38E+00
1,2,3-Trichloropropane—5.46E + 02
sym-Trinitrobenzene—2.17E + 00
Vinyl chloride—7.11E-01
Xylene (total)—8.49E+05
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.
105
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Hoechst
Celanese
Corporation.
Hoechst
Celanese
Corporation.
Hanover Wire
Cloth
Division
Holston Army
Ammunition
Plant.
Imperial
Clevite.
International
Minerals
and
Chemical
Corporation.
Kawneer
Company,
Incorporat-
ed.
Kay-Fries, Inc...
Keymark Corp ..
Keymark Corp ..
Lederie
Laboratories.
Lincoln Plating
Company.
Loxcreen
Company,
Inc.
Marque tie
Electronics
Incorporat-
ed.
Martin
Marietta
Aerospace.
Mason
Chamber-
lain,
Incorporat-
ed.
Merck &
Company,
Incorporat-
ed.
Maytag
Company.
Metropolitan
Sewer
District of
Greater
Cincinnati.
Mtcbelin Tire
Corp.
Address
Bucks,
Alabama.
Leeds, South
Carolina.
Hanover,
Pennsylva-
nia.
Kingsport,
Tennessee.
Salem IN
Terre Haute,
Indiana.
Sphngdale,
Arkansas.
Stoney Point,
NY.
Fonda, NY
Fonda, New
York.
Pearl River,
NY.
Lincoln, NE
Hayti MO
Milwaukee,
Wisconsin.
Ocala, Florida..
Bay St. Louis.
Mississippi.
Elkton,
Virginia.
Newton, IA
Cincinnati, OH.
Sandy
Springs,
South
Carolina.
Waste description
Distillation bottoms generated (at a maximum annual rate of 31,500 cubic yards) from the
production of sodium hydrosuifite (EPA Hazardous Waste No. F003). This exclusion was
published on July 17, 1990. This exclusion does not include the waste contained in
Hoechst Celanese's on-site surface impoundment.
Distillation bottoms generated (at a maximum annual rate of 38,500 cubic yards) from the
production of sodium hydrosuifite (EPA Hazardous Waste No. F003). This exclusion was
published on July 17, 1990.
Dewatered filter cake (EPA Hazardous Waste No. F006) generated from electroplating
operations after August 15, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste Nos. F003, F005, and
K044) generated from the manufacturing and processing of explosives and containing
spent non-halogenated solvents after November 14, 1986.
Solid resin cakes containing EPA Hazardous Waste No. F002 generated after August 27,
1985. from solvent recovery operations.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of n-butyl alchohol after August 15, 1986.
Wastewater treatment filter press sludge (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 26 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on November 13, T990.
Biological aeration lagoon sludge and filter press sludge generated after September 21,
1984, which contain EPA Hazardous Waste Nos. F003 and F005 as well as that disposed
of in a holding lagoon as of September 21, 1984.
Wastewater treatment sludge (EPA Hazardous Waste No. F019) generated from chemical
conversion coating of aluminum after November 27, 1985.
Wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from the
chemical conversion coating of aluminum and contained in an on-site impoundment on
August 1 2, 1 987. This is a one-time exclusion.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste Nos. F003 and
F005) generated from the recovery of the following solvents: Xylene, acetone, ethyl
acetate, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, methanol,
toluene, and pyridine after August 2, 1988. Excusion applies to primary and secondary
filter press sludges and compost soils generated from these sludges.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 17, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after July 16, 1986.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations. This exclusion was published on April 20, 1989.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after January 23, 1987.
Wastewater treatment sludge filter cake (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 1.262 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on October 27, 1989.
One-time exclusion for fly ash (EPA Hazardous Waste No. F002) from the incineration of
wastewater treatment sludge generated from pharmaceutical production processes and
stored in an on-site fly ash lagoon. This exclusion was published on May 12, 1989.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and wastewater treatment sludges (EPA Hazardous Waste No. F019)
generated from the chemical conversion coating of aluminum November 17, 1986.
Sluiced bottom ash sludge (approximately 25.000 cubic yards), contained in the North
Lagoon, on September 21, 1984. which contains EPA Hazardous Wastes Nos. F001,
F002. F003, F004. and F005.
Dewatered wastewater treatment sludge (EPA Hazardous Wastes No. F006) generated from
electroplating operations after November 14, 1986.
106
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Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Monroe Auto
Equipment.
North
American
Philips
Consumer
Electronics
Corporation.
Pamcor C, Inc ..
Address
Paragould, AR..
Greenville,
Tennessee.
Las Piedras,
! PR.
Philway
Products,
Incorporat-
ed.
Plastene
Supply
Company.
Reynolds
Metals
Company.
Reynolds
Metals
Company.
Siegel-Robert,
Inc.
Square D
Company.
Syntex
Agribusi-
ness.
Ashland, Ohio ..
Portageville,
Missouri.
Sheffield, AL
Sheffield, AL
St. Louis, MO...
Oxford, Ohio
Springfield,
MO.
Waste description
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after vacuum filtration after November 27, 1985. This exclusion does not
apply to the sludge contained in the on-site impoundment.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations. This exclusion was published on April 20, 1989.
Dewatered Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after October 17, 1986.
Filter press sludge generated (at a maximum annual rate of 96 cubic yards) during the
treatment of electroplating wastewaters using lime (EPA Hazardous Waste No. F006). This
exclusion was published on October 26, 1990.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after August 15, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after August 15, 1986.
Wastewater treatment filter press sludge (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 3,840 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on July 17, 1990.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.
Dewatered filter press sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after August 15, 1986.
Kiln ash, cyclone ash, separator sludge, and filtered wastewater (except spent activiated
carbori) (EPA Hazardous Waste No. F020 generated during the treatment of wastewater
treatment sludge by the EPA's Mobile Incineration System at the Denney Farm Site in
McDowell, Missouri after June 2, 1988, so long as:
(1) The incinerator is monitored continuously and is in compliance with operating permit
conditions. Should the incinerator fail to comply with the permit conditions relevant to the
mechanical operation of the incinerator, Syntex must test the residues generated during
the run when the failure occurred according to the requirements of Conditions (2) through
(6), regardless of whether or not the demonstration in Condition (7) has been made.
(2) Four grab samples of wastewater must be composited from the volume of filtered
wastewater collected after each eight hour run and, prior to disposal the composite
samples must be analyzed for the EP toxic metals, nickel, and cyanide. If arsenic,
chromium, lead, and silver EP leachate test results exceed 0.61 ppm; barium levels
exceed 12 ppm; cadmium and selenium levels exceed 0.12 ppm; mercury levels exceed
0.02 ppm; nickel levels exceed 6.1 ppm; or cyanide levels exceed 2.4 ppm, the
wastewater must be retreated to achieve these levels or must be disposed in accordance
with all applicable hazardous waste regulations. Analyses must be performed according to
SW-846 methodologies.
(3) One grab sample must be taken from each drum of kiln and cyclone ash generated
during each eight hour run; all grabs collected during a giver eight hour run must then be
composited to form one composite sample. A composite sample of four grab samples of
the separator sludge must be collected at the end of each eight hour run. Prior to the
disposal of the residues from each eight hour run, an EP leachate test must be performed
on these composite samples and the leachate analyzed for the EP toxic metals, nickel,
and cyanide (using a distilled water extraction for the cyanide extraction) to demonstrate
that the following maximum allowable treatment residue concentrations listed below are
not exceeded. Analyses must be performed according to SW-846 methodologies. Any
residues which exceed any of the levels listed below must be retreated to achieve these
levels or must be disposed in accordance with all applicable hazardous waste regulations.
Maximum Allowable Solids Treatment Residue EP Leachate Concentrations (mg/L)
Arsenic — 1 .6
Barium — 32
Cadmium— 0.32
Chromium — 1.6
Lead— 1.6
Mercury— 0.065
Nickel— 16
Selenium— 0.32
Silver— 1 .6
Cyanide— 6.5
107
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
(4)—If Syntex stabilizes any of the kiln and cyclone ash or separator sludge, a Portland
cement-type stabilization process must be used and Syntex must collect a composite
sample of four grab samples from each batch of stabilized waste. An MEP leachate test
must be performed on these composite samples and the leachate analyzed for the EP
toxic metals, nickel, and cyanide (using a distilled water extraction for the cyanide leachate
analysis) to demonstrate that the maximum allowable treatment residue concentrations
listed in Condition (3) are not exceeded during any run of the MEP extraction. Analyses
must be performed according to SW-846 methodologies. Any residues which exceed any
of the levels listed in Condition (3) must be retreated to achieve these levels or must be
disposed in accordance with all applicable hazardous waste regulations. (If the residues
are stabilized, the analyses required in this condition supercede the analyses required in
Condition (3).)
(5) Syntex must generate, prior to disposal of residues, verification data from each eight hour
run from each treatment residue (i.e., kiln and cyclone ash, separator sludge, and filtered
wastewater) to demonstrate that the maximum allowable treatment residue concentrations
listed below are not exceeded. Samples must be collected as specified in Conditions (2)
and (3). Analyses must be performed according to SW-846 methodologies. Any solid or
liquid residues which exceed any of the levels listed below must be retreated to achieve
these levels or must be disposed in accordance with Subtitle C of RCRA.
Maximum Allowable Wastewater Concentrations (ppm):
Benz(a)anthracene— 1 x 10'4
Benzo(a)pyrene—4 x 10~5
Benzo(b)fluoranthene—2 x 10'4
Chloroform—0.07
Chrysene—0.002
Dibenz(a,h)anthracene—9 x 10"6
1,2-Dichloroethane—0.06
Dichloromethane—0.06
IndenoO ,2,3-cd)pyrene—0.002
Porychlorinated biphenyls—1 x 10~4
1,2,4,5-Tetrachlorobenzene—0.13
2.3,4,6-Tetrachloropnenol—12
Toluene—120
Tnchloroethylene—0.04
2,4,5-Trichlorophenol—49
2,4,6-Trichkxophenol—0.02
Maximum Allowable Solid Treatment Residue Concentrations (ppm):
Benz(a)anthracene—1.1
Benzo(a)pyrene—0.43
Benzo(b)fluoranthene—1.8
Chloroform—5.4
Chrysene—170
Dibenz(a,h)anthracene—0.083
Dichloromethane—2.4
1,2-Dichloroethane—4.1
IndenoO ,2,3-cd)pyrene—330
Porychlorinated biphenyls—0.31
1,2.4.5-Tetrachlorobenzene—720
Trichkxoethytene—6.6
2.4.6-Trichlorophenol—3.9
(6) Syntex must generate, prior to disposal of residues, verification data from each eight hour
run for each treatment residue (i.e.. kiln and cyclone ash, separator sludge, and filtered
wastewater) to demonstrate that the residues do not contain tetra-. penta-, or hexachloro-
dibenzo-p-dioxins or furans at levels of regulatory concern. Samples must be collected as
specified in Conditions (2) and (3). The TCDD equivalent levels for wastewaters must be
less than 2 ppq and less than 5 opt for the solid treatment residues. Any residues with
detected dtoxins or furans in excess of these levels must be retreated or must be
disposed as acutely hazardous. Method 8290, a high resolution gas chromatography and
high resolution mass spectroscopy (HRGC/HRMS) analytical method, must be used. For
tetra- and pentachkxonated dtoxin and furan nomotogs, the maximum practical quantitaton
limit must not exceed 15 ppt for solids and 120 ppq for wastewaters. For hexachlorinated
homotogs, the maximum practical quantitation limit must not exceed 37 ppt for solids and
300 ppq for wastewaters.
(7MA) The test data from Conditions (1), (2), (3). (4). (5) and (6) must be kept on file by
Syntex for inspection purposes and must be compiled, summarized, and submitted to the
Section Chief. Variances Section. PSPD/OSW (WH-563), US EPA, 401 M Street S.W.,
Washington, D.C. 20460 by certified mail on a monthly basis and when the treatment of
the lagoon sludge is concluded. All data submitted will be placed in the RCRA docket
108
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Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
SRof
Tennessee.
Tennessee
Electroplat-
ing.
Ripley. TN
Ripley,
Tennessee.
Tennessee
Electroplat-
ing.
Texas
Instruments,
Inc.
Tricil
Environmen-
tal Systems,
Inc.
Ripley, TN.
Dallas, TX.
Milliard, Ohio..
(B) The testing requirements for Conditions (2), (3), (4), (5), and (6) will continue until Syntex
provides the Section Chief, Variances Section, with the results of four consecutive batch
analyses for the petitioned wastes, none of which exceed the maximum allowable
treatment residue concentrations listed in these conditions and the Section Chief,
Variances Section, notifies Syntex that the conditions have been lifted.
(8) Syntex must provide a signed copy of the following certification statement when
submitting data in response to the conditions listed above: "Under civil and criminal
penalty of law for the making or submission of false or fraudulent statements or
representations, I certify that the information contained in or accompanying this document
is true, accurate, and complete. As to the (those) identified section(s) of this document for
which I cannot personally verify its (their) accuracy, I certify as the company official having
supervisory responsibility for the persons who, acting under my direct instructions, made
the verification that this information is true, accurate and complete."
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
the copper, nickel, and chromium electroplating of plastic parts after November 17, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste Nos. F006) generated
from electroplating operations after November 17, 1986. To ensure chromium levels do
not exceed the regulatory standards there must be continuous batch testing of the filter
press sludge for chromium for 45 days after the exclusion is granted. Each batch of
treatment residue must be representatively sampled and tested using the EP toxicity test
for chromium. This data must be kept on file at the facility for inspection purposes. If the
extract levels exceed 0.922 ppm of chromium the waste must be managed and disposed
of as hazardous. If these conditions are not met, the exclusion does not apply. This
exclusion does not apply to sludges in any on-site impoundments as of this date.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and contained in an on-site surface impoundment (maximum volume of
6,300 cubic yards). This is a one-time exclusion. This exclusion was published on April 8,
1991.
Wastewater treatment sludges (EPA Hazardous Waste Nos. F006 and F019) generated after
August 27, 1985, from their electroplating operations that have been batch tested for
cadmium using the EP toxicity procedure and have been found to contain less than 0.30
ppm cadmium in the EP extract. Wastewater treatment sludges that exceed this level will
be considered a hazardous waste.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after November 17, 1986. To ensure that hazardous constituents
are not present in the waste at levels of regulatory concern, the facility must implement a
contingency testing program for the petitioned wastes. This testing program must meet the
following conditions for the exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, barium, cadmium,
chromium, lead, selenium, silver, mercury, and nickel. If the extract concentrations for
chromium, lead, arsenic, and silver exceed 0.315 ppm; barium levels exceed 6.3 ppm;
cadmium and selenium levels exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or
nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and disposed as a
hazardous waste under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
test without acetic acid adjustment) exceed 1.26 ppm, the waste must be re-treated or
managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the
permitting standards of 40 CFR Part 270.
(3) Each batch of the waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrolein—56.8
Anthracene—76.8
Benzene—0.106
p-Chloro-m-cresol— 133
1,1 -Dichloroethane—0.01
Fluorene—10.4
Methylene chloride—8.2
Methyl ethyl ketone—326
n-Nitrosodiphenylamine—11.9
Phenanthrene—14
Tetrachloroethylene—0.188
Trichloroethylene—0.59
Chloroform—0.013
109
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Tricil
Environmen-
tal Systems,
Inc.
Nashville,
Tennessee
1,2-Dichloroethane—0.0083
1,2-trans-Dichloroethylene—231
2,4-Dimethylphenol—12.5
Vinyl chloride—0.18
(4) A grab sample must be collected from each batch to form one monthly composite
sample, which must be tested using GC/MS analysis for the compounds shown above as
well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
19, 1982, for a list of the priority pollutants.)
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue as described in this
petition.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
chemical conversion coating of aluminum after November 17, 1986. To ensure that
hazardous constituents are not present in the waste at levels of regulatory concern, the
facility must implement a contingency testing program for the petitioned wastes. This
testing program must meet the following conditions for the exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, barium, cadmium,
chromium, lead, selenium, silver, mercury, and nickel. If the extract concentrations for
chromium, lead, arsenic, and silver exceed 1.1 ppm; barium levels exceed 22.2 ppm;
cadmium and selenium levels exceed 0.22 ppm; mercury levels exceed 0.044 ppm; or
nickel levels exceed 7.8 ppm, the waste will be re-treated or managed and disposed as a
hazardous waste under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm or teachable cyanide levels (using the EP Toxicity
test without acetic acid adjustment) exceed 4.4 ppm, the waste must be re-treated or
managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the
permitting standards of 40 CFR Part 270.
(3) Each batch of the waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrotein—363
Anthracene—492
Benzene—0.68
p-Chtoro-m-cresol—848
1,1 -Dichloroethane—0.068
Fluorene—66.7
Methylene chloride—52.4
n-Nitrosodiphenylamine—76.1
Phenantnrene—89
Tetrachtoroethytene—1.2
Trichloroethytene—3.78
Chkxolorm—0.081
1,2-Dichloroethane—0.053
2,4-Dirnethylphenol—79.7
Vinyl chloride—1.16
1.2-Diphenyt hydrazine—0.005
(4) A grab sample must be collected from each batch to form one monthly composite
sample, which must be tested using GC/MS analysis for the compounds shown above as
well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
19, 1982, for a list of the priority pollutants.)
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue as described in this
petition.
110
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Environmental Protection Agency Pt. 261, App. IX
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Tricil
Environmen-
tal Systems,
Inc.
Muskegon,
Michigan.
United
Technol-
ogies
Automotive,
Inc.
Universal Oil
Products.
U.S. EPA
Combustion
Research
Facility.
U.S.
Nameplate
Company,
Inc.
Jeffersonville,
IN.
Decatur,
Alabama.
Jefferson,
Arkansas.
Mount Vernon,
Iowa.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after November 17, 1986. To ensure that hazardous constituents
are not present in the waste at levels of regulatory concern, the facility must implement a
contingency testing program for the petitioned wastes. This testing program must meet the
following conditions for the exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, barium, cadmium,
chromium, lead, selenium, silver, mercury, and nickel. If the extract concentrations for
chromium, lead, arsenic, and silver exceed 0.315 ppm; barium levels exceed 6.3 ppm;
cadmium and selenium levels exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or
nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and disposed as a
hazardous waste under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm or teachable cyanide levels (using the EP Toxicity
test without acetic acid adjustment) exceed 1.26 ppm, the waste must be re-treated or
managed and disposed as a hazardous waste under 40 CFR parts 262 to 265 and the
permitting standards of 40 CFR part 270.
(3) Each batch of the waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
parts 262 to 265 and the permitting standards of 40 CFR part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrolein—56.8
Anthracene—76.8
Benzene—0.106
p-Chloro-m-cresol—133
1,1-Dichloroethane—0.01
Fluorene—10.4
Methylene chloride—8.2
Methyl ethyl ketone—326
n-Nitrosodiphenylamine—11.9
Phenanthrene—14
Tetrachloroethylene—0.188
Trichloroethylene—0.59
Chloroform—0.013
1,2-Dichloroethane—0.0083
1,2-trans-Dichloroethylene—231
2,4-Dimethylphenol—12.5
Vinyl chloride—0.18
(4) A grab sample must be collected from each batch to form one monthly composite
sample, which must be tested using GC/MS analysis for the compounds shown above as
well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
19, 1982, for a list of the priority pollutants.)
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue as described in this
petition.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO19) generated from
the chemical conversion of aluminum after April 29, 1986.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and contained in two on-site lagoons on August 15, 1986. This is a one-
time exclusion.
One-time exclusion for scrubber water (EPA Hazardous Waste No. F020) generated in 1985
from the incineration of Vertac still bottoms. This exclusion was published on June 28,
1989.
Retreated wastewater treatment sludges (EPA Hazardous Waste No. F006) previously
generated from electroplating operations and currently contained in an on-site surface
impoundment after September 28, 1988. This is a one-time exclusion for the reteated
wastes only. This exclution does not relieve the waste unit from regulatory compliance
under Subtitle C.
Ill
-------
Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
VAWof
America
Incorporat-
ed.
Vermont
American,
Corp.
Waterloo
Industries.
Watervliet
Arsenal.
William L.
Bonnell Co.
William L.
Bonnell Co.
Windsor
Plastics, Inc.
Address
St. Augustine,
Florida.
Newark, OH
Pocahontas,
AR.
Watervliet, NY..
Carthage, TN....
Newnan,
Georgia.
Evansville, IN ...
Waste description
Wastewater treatment sludge filter cake (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum. This exclusion was published on February 1 ,
1989.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after dewatering and held on-site on July 17, 1986 and any such sludge
generated (after dewatering) after July 17, 1986.
Wastewater treatment sludges (EPA Hazardous Waste No F006) generated from electroplat-
ing operations after January 10, 1986.
Dewatered Wastewater treatment sludges (Vacuum filter sludge) (EPA Hazardous Waste No.
F019) currently generated from the chemical conversion coating of aluminum after October
17, 1986. This exclusion does not apply to sludges in the on-site surface impoundments.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after November 14, 1986. This exclusion
does not include sludges contained in Bonnell's on-site surface impoundments.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of acetone after November 17, 1986.
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES
Facility
American
Cyanamid.
Amoco Oil Co...
Akzo
Chemicals
Inc.
(formerly
Stauffer
Chemical
Company).
Bethlehem
Steel Corp.
Address
Hannibal,
Missouri.
Wood River,
IL
Axis, AL
Steelton, PA
Waste description
Wastewater and sludge (EPA Hazardous Waste No. K038) generated from the washing and
stripping of phorate production and contained in on-site lagoons on May 8, 1987, and such
wastewater and sludge generated after May 8, 1987.
150 million gallons of DAF from petroleum refining contained in in four surge ponds after
treatment with the Chemifix' stabilization process. This waste contains EPA Hazardous
Waste No. K048. This exclusion applies to the 150 million gallons of waste after chemical
stabilization as long as the mixing ratios of the reagent with the waste are monitored
continuously and do not vary outside of the limits presented in the demonstration samples;
one grab sample is taken each hour from each treatment unit, composited, and EP toxicity
tests performed on each sample. If the levels of lead or total chromium exceed 0.5 ppm in
the EP extract, then the waste that was processed during the compositing period is
considered hazardous; the treatment residue shall be pumped into termed cells to ensure
that the waste is identifiable in the event that removal is necessary.
Brine purification muds generated from their chlor-alkali manufacturing operations (EPA
Hazardous Waste No. K071) and disposed of in brine mud pond HWTF: 5 EP-201.
Uncured and cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treat-
ment residue (K061) generated from the primary production of steel after May 22, 1989.
This exclusion is conditioned upon the data obtained from Bethlehem's full-scale CSEAFD
treatment facility because Bethlehem's original data were obtained from a laboratory-scale
CSEAFD treatment process. To ensure that hazardous constituents are not present in the
waste at levels of regulatory concern once the full-scale treatment facility is in operation,
Bethlehem must implement a testing program for the petitioned waste. This testing
program must meet the following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
Bethlehem must collect representative grab samples of each treated batch of the CSEAFD
and composite the grab samples daily. The daily composites, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
(using distilled water in the cyanide extractions), and the total constituent concentrations
of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
846 methodologies. Bethlehem must report the analytical test data obtained during this
initial period no later than 90 days after the treatment of the first full-scale batch.
112
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Bethlehem
Steel Corp.
Johnstown,
PA.
Waste description
(B) Subsequent Testing: Bethlehem must collect representative grab samples from every
treated batch of CSEAFD generated daily and composite all of the grab samples to
produce a weekly composite sample. Bethlehem then must analyze each weekly compos-
ite sample for the EP leachate concentrations of all the EP toxic metals and nickel.
Analyses must be performed according to SW-646 methodologies. The analytical data,
including all quality control information, must be compiled and maintained on site for a
minimum of three years. These data must be furnised upon request and made available
for inspection by any employee or representative of EPA or the State of Pennsylvania.
(2) Oelisting Levels: If the EP extract concentrations resulting from the testing in condition
(1)(A) or (1){B) for chromium, lead, arsenic, or silver exceed 0.315 mg/L, for barium
exceeds 6.3 mg/l; lor cadmium or selenium exceed 0.063 mg/l; lor mercury exceeds
0.0126 mg/l; for nickel exceeds 3.15 mg/l: or for cyanide exceeds 4.42 mg/L, or total
reactive cyanide or total reactive sulfide levels exceed 250 mg/kg and 500 mg/kg,
respectively, the waste must either be re-treated or managed and disposed in accordance
with subtitle C of RCHA.
(3) Data submittals: Within one week of system start-up, Bethlehem must notify the Section
Chief, Variances Section (see address below) when their full-scale stabilization system is
on-line and waste treatment has begun. All data obtained through the initial testing
condition (1)(A), must be submitted to the Section Chief, Variances Section, PSPD/OSW,
(OS-343), U.S. EPA, 401 M Street, S.W., Washington, DC 20460 within the time period
specified in condition (1){A). At the Section Chief's request, Bethlehem must submit
analytical data obtained through condition (1)(B) to the above address, within the time
period specified by the Section Chief. Failure to submit the required data obtained from
either condition (1)(A) or (1)(B) within the specified time periods will be considered by the
Agency sufficient basis to revoke Bethlehem's exclusion to the extent directed by EPA. All
data must be accompanied by the following certification statement:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code
which include, but may not be limited to, 18 U.S.C. 6926), I certify that the information
contained in or accompanying this document is true, accurate and complete.
"As to the (those) identified section(s) of this document for which I cannot personally verify
its (their) truth and accuracy, I certify as the company official having supervisory
responsibility for the persons who, acting under my direct instructions, made the
verification that this information is true, accurate and complete.
"In the event that any of this information is determined by EPA in its sole discretion to be
lalse, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
Uncured and cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treat-
ment residue (K061) generated from the primary production of steel after May 22, 1989.
This exclusion is conditioned upon the data obtained from Bethlehem's full-scale CSEAFD
treatment facility because Bethlehem's original data were obtained from a labortory-scale
CSEAFD treatment process. To ensure that hazardous constituents are not present in the
waste at levels of regulatory concern once the full-scale treatment facility is in operation,
Bethlehem must implement a testing program for the petitioned waste. This testing
program must meet the following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
Bethlehem must collect representative grab samples of each treated batch of the CSEAFD
and composite the grab samples daily. The daily composites, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
(using distilled water in the cyanide extractions), and the total constituent concentrations
of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
846 methodologies. Bethlehem must report the analyticai test data obtained during this
initial period no later than 90 days after the treatment of the first full-scale batch.
(B) Subsequent Testing: Bethlehem must collect representative grab samples from every
treated batch of CSEAFD generated daily and composite all of the grab samples to
produce a weekly composite sample. Bethlehem then must analyze each weekly compos-
ite sample for the EP leachate concentrations of all the EP toxic metals and nickel.
Analyses must be performed according to SW-846 methodologies. The analytical data,
including all quality control information, must be compiled and maintained on site for a
minimum of three years. These data must be furnished upon request and made available
for inspection by any employeee or representative of EPA or the State of Pennsylvania.
113
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
BF Goodrich
Interme-
diates
Company,
Inc.
Calvert City,
Kentucky.
(2) Delisting Levels: If the EP extract concentrations resulting from the testing in condition
(1)(A) or (1)(B) for chromium, lead, arsenic, or silver exceed 0.315 mg/L, for barium
exceeds 6.3 mg/l; for cadmium or selenium exceed 0.063 mg/l; for mercury exceeds
0.0126 mg/l; for nickel exceeds 3.15 mg/l; or for cyanide exceeds 4.42 mg/L, or total
reactive cyanide or total reactive sulfide levels exceed 250 mg/kg and 500 mg/kg,
respectively, the waste must either be re-treated or managed and disposed in accordance
with subtitle C of RCRA.
(3) Data submittals: Within one week of system start-up, Bethlehem must notify the Section
Chief, Variances Section (see address below) when their full-scale stabilization system is
on-line and waste treatment has begun. All data obtained through the initial testing
condition (1)(A), must be submitted to the Section Chief, Variances Section, PSPD/OSW,
(OS-343), U.S. EPA, 401 M Street, SW., Washington, DC 20406 within the time period
specified in condition (1)(A). At the Section Chief's request. Bethlehem must submit
analytical data obtained through condition (1)(B) to the above address, within the time
period specified by the Section Chief. Failure to submit the required data obtained from
either condition (1)(A) or (1)(B) within the specified time periods will be considered by the
Agency sufficient basis to revoke Bethlehem's exclusion to the extent directed by EPA. All
data must be accompanied by the following certification statement:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code
which include, but may not be limited to, 18 U.S.C. 6928), I certify that the information
contained in or accompanying this document is true, accurate and complete.
"As to the (those) identified section(s) of this document for which I cannot personally verify
its (their) truth and accuracy. I certify as the company official having supevisory
responsibility for the persons who, acting under my direct instructions, made the
verification that this information is true, accurate and complete.
"In the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
Brine purification muds and saturator insolubles (EPA Hazardous Waste No. K071) after
August 18. 1989. This exclusion is conditional upon the collection and submission of data
obtained from BFG's full-scale treatment system because BFG's original data was based
on data presented by another petitioner using an identical treatment process. To ensure
that hazardous constituents are not present in the waste at levels of regulatory concern
once the full-scale treatment facility is in operation, BFG must implement a testing
program. All sampling and analyses (including quality control procedures) must be
performed according to SW-846 procedures. This testing program must meet the following
conditions for the exclusion to be valid:
(1) Initial Testing: During the first four weeks of full-scale operation, BFG must do the
following:
(A) Collect representative grab samples from every batch of the treated mercury brine
purification muds and treated saturator insolubles on a daily basis and composite the grab
samples to produce two separate daily composite samples (one of the treated mercury
brine purification muds and one of the treated saturator insolubles). Prior to disposal of the
treated batches, two daily composite samples must be analyzed for EP leachate
concentration of mercury. BFG must report the analytical test data, including all quality
control data, within 90 days after the treatment of the first full-scale batch.
(B) Collect representative grab samples from every batch of the treated mercury brine
purification muds and treated saturator insolubles on a daily basis and composite the grab
samples to produce two separate weekly composite samples (one of the treated mercury
brine muds and one of the treated saturator insolubles). Prior to disposal of the treated
batches, two weekly composite samples must be analyzed for the EP leachate concentra-
tions of all the EP toxic metals (except mercury), nickel, and cyanide (using distilled water
in the cyanide extractions), and the total constituent concentrations of reactive sulfide and
reactive cyanide. BFG must report the analytical test data, including all quality control
data, obtained during this initial period no later than 90 days after the treatment of the first
full-scale batch.
(2) Subsequent Testing: After the first four weeks of full-scale operation, BFG must do the
following:
(A) Continue to sample and test as described in condition (1)(A). BFG must compile and
store on-site for a minimum of three years all analytical data and quality control data.
These data must be furnished upon request and made available for inspection by any
employee or representative of EPA or the State of Kentucky.
114
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
CF&I Steel
Corporation.
Pueblo,
Colorado.
(B) Continue to sample and test as described in condition (1)(B). BFG must compile and
store on-site for a minimum of three years all analytical data and quality control data.
These data must be furnished upon request and made available for inspection by any
employee or representative of EPA or the State of Kentucky. These testing requirements
shall be terminated by EPA when the results of four consecutive weekly composite
samples of both the treated mercury brine muds and treated saturator insolubles, obtained
from either the initial testing or subsequent testing, show the maximum allowable levels in
condition (3) are not exceeded and the Section Chief, Variances Section, notifies BFG that
the requirements of this condition have been lifted.
(3) If, under condition (1) or (2), the EP leachate concentrations for chromium, lead, arsenic,
or silver exceed 0.316 mg/l; for barium exceeds 6.31 mg/l; for cadmium or selenium
exceed 0.063 mg/l; for mercury exceeds 0.0126 mg/l, for nickel exceeds 3.16 mg/l; for
cyanide exceeds 4.42 mg/l; or for total reactive cyanide or total reactive sulfide levels
exceed 250 mg/kg and 500 mg/kg, respectively, the waste must either be retreated until it
meets these levels or managed and disposed of in accordance with subtitle C of RCRA.
(4) Within one week of system start-up. BFG must notify the Section Chief, Variances
Section (see address below) when the full-scale system is on-line and waste treatment
has begun. All data obtained through condition (1) must be submitted to the Section Chief,
Variances Section, PSPD/OSW (OS-343), U.S. EPA, 401 M Street, SW., Washington, DC
20460 within the time period specified in condition (1). At the Section Chief's request, BFG
must submit any other analytical data obtained through condition (2) to the above address,
within the time period specified by the Section Chief. Failure to submit the required data
will be considered by the Agency sufficient basis to revoke BFG's exclusion to the extent
directed by EPA. All data must be accompanied by the following certification statement:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code
which include, but may not be limited to, 18 U.S.C. §6928), I certify that the information
contained in or accompanying this document is true, accurate and complete.
As to the (those) identified section(s) of this document for which I cannot personally verify its
(their) truth and accuracy, I certify as the company official having supervisory responsibility
for the persons who, acting under my direct instructions, made the verification that this
information is true, accurate and complete.
In the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
Fully-cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treatment
residue (EPA Hazardous Waste No. K061) generated from the primary production of steel
after May 9, 1989. This exclusion is conditioned upon the data obtained from CF&l's full-
scale CSEAFD treatment facility because CF&l's original data was obtained from a
laboratory-scale CSEAFD treatment process. To ensure that hazardous constituents are
not present in the waste at levels of regulatory concern once the full-scale treatment
facility is in operation. CF&I must implement a testing program for the petitioned waste.
This testing program must meet the following conditions for the exclusion to be vaild:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
CF&I must collect representative grab samples of each treated batch of the CSEAFD and
composite the grab samples daily. The daily composites, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals, nickel, and cyanide
(using distilled water in the cyanide extractions), and the total constituent concentrations
of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
846 methodologies. CF&I must report the analytical test data obtained during this initial
period no later than 90 days after the treatment of the first full-scale batch.
(B) Subsequent Testing: CF&I must collect representative grab samples from every treated
batch of CSEAFD generated daily and composite all of the grab samples to produce a
weekly composite sample. CF&I then must analyze each weekly composite sample for the
EP leachate concentrations of all of the EP toxic metals and nickel. Analyses must be
performed according to SW-846 methodologies. The analytical data, including all quality
control information, must be compiled and maintained on site for a minimum of three
years. These data must be furnished upon request and made available for inspection by
any employee or representative of EPA or the State of Colorado.
(2) Delisting levels: If the EP extract concentrations determined in conditions (1)(A) or (1)(B)
for chromium, lead, arsenic, or silver exceed 0.315 mg/1; for barium exceeds 6.3 mg/1;
for cadmium or selenium exceed 0.063 mg/1; for mercury exceeds 0.0126 mg/1; for
nickel exceeds 3.15 mg/1; or for cyanide exceeds 4.42 mg/1, or total reactive cyanide or
total reactive sulfide levels exceed 250 mg/kg and 500 mg/kg, respectively, the waste
must either be re-treated or managed and disposed in accordance with Subtitle C of
RCRA.
115
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Envtnte
Corporation.
Canton. Ohio;
Harvey,
Illinois;
Thomaston,
Connecticut;
and York
PA.
(3) Data submittals: Within one week of system start-up. CF&l must notify the Section Chief,
Variances Section (see address below) when their full-scale stabilization system is on-Nne
and waste treatment has begun. All data obtained through the initial testing condition
(1)(A), must be submitted to the Section Chief, Variances Section, PSPD/OSW, (OS-343),
U.S. EPA, 401 M Street. SW., Washington. DC 20460 within the time period specified in
condition (1}(A|. At the Section Chiefs request, CF&l must submit analytical data obtained
through condition (1)(B) to the above address, within the time period specified by the
Section Chief. Failure to submit the required data obtained from either condition (1)(A) or
(1)(B) within the specified time periods will be considered by the Agency sufficient basis to
revoke CF&l's exclusion to the extent directed by EPA. All data must be accompanied by
the following certification statement "Under civil and criminal penalty of law for the
making of submission of false or fraudulent statements or representations (pursuant to the
applicable provisions of the Federal Code which include, but may not be limited to, 18
U.S.C. 6928), I certify that the information contained in or accompanying this document is
true, accurate and complete. As to the {those} identified section(s) of this document tor
which I cannot personalty verify its (their) truth and accuracy, I certify as the company
official having supervisory responsibility for the persons who, acting under my direct
instructions, made the verification that this information is true, accurate and complete. In
the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon trie
company's reliance on the void exclusion."
Spent pickle liquor (EPA Hazardous Waste No. K062) generated from steel finishing
operations of facilities within the iron and steel industry (SIC Codes 331 and 332);
wastewater treatment sludge (EPA Hazardous Waste No. K002) generated from the
production of chrome yellow and orange pigments; wastewater treatment sludge (EPA
Hazardous Waste No. K003) generated from the production of molybdate orange
pigments; wastewater treatment sludge (EPA Hazardous Waste No. K004) generated from
the production of zinc yellow pigments; wastewater treatment sludge (EPA Hazardous
Waste No. KOOS) generated from the production of chrome green pigments; wastewater
treatment sludge (EPA Hazardous Waste No. K006) generated from the production of
chrome oxide green pigments (anhydrous and hydrated); wastewater treatment sludge
(EPA Hazardous Waste No. K007) generated from the production of iron blue pigments;
oven residues (EPA Hazardous Waste No. K008) generated from the production of
chrome oxide green pigments after November 14, 1986. To ensure that hazardous
constituents are not present in the waste at levels of regulatory concern, the facility must
implement a contingency testing program for the petitioned wastes. This testing program
must meet the following conditions for the exclusions to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
EP Toxicity test for arsenic, barium, cadmium, chromium, lead, selenium, silver, mercury,
and nickel. If the extract concentrations for chromium, lead, arsenic, and silver exceed
0.315 ppm, barium levels exceed 6.3 ppm; cadmium and selenium exceed 0.063 ppm;
mercury exceeds 0.0126 ppm; or nickel levels exceed 2.205 ppm, the waste must be re-
treated or managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm; or teachable cyanide levels (using the EP
Toxicity test without acetic acid adjustment) exceed 1.26 ppm, the waste must be re-
treated or managed and disposed as hazardous waste under 40 CFR Parts 262 to 265
and the permitting standards of 40 CFR 270.
(3) Each batch of waste must be tested for the total content of specific organic toxicants. If
the total content of anthracene exceeds 76.8 ppm. 1,2-diphenyl hydrazine exceeds 0.001
ppm, methytene chloride exceeds 6.18 ppm, methyl ethyl ketone exceeds 326 ppm. n-
nitrosodiphenylamine exceeds 11.9 ppm, phenol exceeds 1.566 ppm, tetrachtoroethytene
exceeds 0.168 ppm, or trichloroethylene exceeds 0.592 ppm, the waste must be managed
and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the permitting
standards of 40 CFR Part 270.
(4) A grab sample must be collected from each batch to form one monthly composite
sample which must be tested using GC/MS analysis for the compounds listed in #3
above as well as the remaining organics on the priority poltutan list (See 47 FR 52309,
November 19, 1982, for a list of the priority pollutants.)
116
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
LCP Chemical.
Mearl Corp
Monsanto
Industrial
Chemicals
Company.
Occidental
Chemical
Corp.
Muscle
Shoals
Plant
Orrington, ME..
Peekskill, NY....
Sauget, Illinois..
Sheffield,
Alabama.
(5) The data from conditions 1-4 must be kept on file at the facility for inspection purposes
and must be compiled, summarized, and submitted to the Administrator by certified mail
semi-annually. The Agency will review this information and if needed will propose to
modify or withdraw the exclusion. The organics testing described in conditions 3 and 4
above is not required until six months from the date of promulgation. The Agency's
decision to conditionally exclude the treatment residue generated from the wastewater
treatment systems at these facilities applies only to the wastewater and solids treatment
systems as they presently exist as described in the detisting petition. The exclusion does
not apply to the proposed process additions described in the petition as recovery,
including crystalizafon. electrolytic metals recovery, evaporative recovery, and ion ex-
change.
Brine purification muds and wastewater treatment sludges generated after August 27. 1985
from their chlor-alkali manufacturing operations (EPA Hazardous Waste Nos. K071 and
K106) that have been batch tested for mercury using the EP toxicity procedures and have
been found to contain less than 0.05 ppm mercury in the EP extract. Brine purification
muds and wastewater treatment sludges that exceed this level will be considered a
hazardous waste.
Wastewater treatment sludge (EPA Hazardous Waste Nos. K006 and K007) generated from
the production of chrome oxide green and iron blue pigments after November 27, 1985.
Brine purification muds (EPA Hazardous Waste No. K071) generated from the mercury cell
process in chlorine production, where separately prepurified brine is not used after August
15, 1986.
Retorted wastewater treatment sludge from the mercury cell process in chlorine production
(EPA Hazardous Waste No. K106) after September 19, 1989. This exclusion is conditional
upon the submission of data obtained from Occidental's full-scale retort treatment system
because Occidental's original data were based on a pilot-scale retort system. To ensure
that hazardous constituents are not present in the waste at levels of regulatory concern
once the full-scale treatment facility is in operation, Occidental must implement a testing
program. All sampling and analyses (including quality control procedures) must be
performed according to SW-846 procedures. This testing program must meet the following
conditions for the exclusion to be valid:
(1) Initial Testing—During the first four weeks of full-scale retort operation, Occidental must
do the following:
(A) Collect representative grab samples from every batch of retorted material and composite
the grab samples to produce a weekly composite sample. The weekly composite samples,
prior to disposal or recycling, must be analyzed for the EP leachate concentrations of all
the EP toxic metals (except mercury), nickel, and cyanide (using distilled water in the
cyanide extractions), and the total constitutent concentrations of reactive sulfide and
reactive cyanide. Occidental must report the analytical test data, including all quality
control data, obtained during this initial period no later than 90 days after the treatment of
the first full-scale batch.
(B) Collect representative grab samples of every batch of retorted material prior to its
disposal or recycling and analyze the sample for EP leachate concentration of mercury.
Occidental must report the analytical test data, including all quality control data, within 90
days after the treatment of the first full-scale batch.
(2) Subsequent Testing—After the first four weeks of full-scale retort operation, Occidental
must do the following:
(A) Continue to sample and test as described in condition (1)(A). Occidental must compile
and store on-site for a minimum of three years all analytical data and quality control data.
These data must be furnished upon request and made available for inspection by any
employee or representative of EPA or the State of Alabama. These testing requirements
shall be terminated by EPA when the results of four consecutive weekly composite
samples of the petitioned waste, obtained from either the initial testing or subsequent
testing show the maximum allowable levels in condition (3) are not exceeded and the
Section Chief, Variances Section, notifies Occidental that the requirements of this
condition have been lifted.
(B) Continue to sample and test for mercury as described in condition (1)(B).
Occidental must compile and store on-site for a minimum of three years all analytical data
and quality control data. These data must be furnished upon request and made available
for inspection by any employee or representative of EPA or the State ot Alabama. These
testing requirements shall remain in effect until Occidental provides EPA with analytical
and quality control data for thirty consecutive batches of retorted material, collected as
described in condition (1)(B), demonstrating that the EP teachable levels of mercury are
below the maximum allowable level in condition (3) and the Section Chief, Variances
Section, notifies Occidental that the testing in condition (2)(B) may be replaced with (2)(C).
117
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Occidental
Chemical
Corporation.
Delaware City,
Delaware.
(C) [If the conditions in (2)(B) are satisfied, the testing requirements lor mercury in (2)(B)
shall be replaced with the following condition]. Collect representative grab samples from
every batch of retorted material on a daily basis and composite the grab samples to
produce a weekly composite sample. Occidental must analyze each weekly composite
sample prior to its disposal or recycling for the EP leachate concentration of mercury.
Occidental must compile and store on-site for a minimum of three years all analytical data
and quality control data. These data must be furnished upon request and made available
for inspection by any employee or representative cf EPA or the State of Alabama.
(3) If, under condition (1) or (2), the EP leachate concentrations for chromium, lead, arsenic,
or silver exceed 1.616 mg/l; for barium exceeds 32.3 mg/l; for cadmium or selenium
exceed 0.323 mg/l; for mercury exceeds 0.065 mg/l, for nickel exceeds 16.15 mg/l; for
cyanide exceeds 22.61 mg/l; or for total reactive cyanide or total reactive sulfide levels
exceed 250 mg/kg and 500 mg/kg, respectively, the waste must either be retreated until it
meets these levels or managed and disposed of in accordance with subtitle C of RCRA.
(4) Within one week of system start-up. Occidental must notify the Section Chief, Variances
Section (see address below) when the full-scale retort system is on-line and waste
treatment has begun. All data obtained through condition (1) must be submitted to the
Section Chief, Variances Section, PSPD/OSW (OS-343), U.S. EPA, 401 M Street SW.,
Washington, DC 20460 within the time period specified in condition (1). At the Section
Chief's request Occidental must submit any other analytical data obtained through
condition (2) to the above address, within the time period specified by the Section Chief.
Failure to submit the required data will be considered by the Agency sufficient basis to
revoke Occidental's exclusion to the extent directed by EPA. All data must be accompa-
nied by the following certification statement:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code
which include, but may not be limited to, 18 U.S.C. €928), I certify that the information
contained in or accompanying this document is true, accurate and complete.
As to the (those) identified section(s) of this document for which I cannot personnel verify its
(their) truth and accuracy, I certify as the company official having supervisory responsibility
for the persons who, acting under my direct instructions, made the verification that this
information is true, accurate and complete.
In the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
Sodium chloride treatment muds (NaQ-TM), sodium chloride saturates cleanings (NaCI-SC),
and potassium chloride treatment muds (KCI-TM) (ail classified as EPA Hazardous Waste
No. K071) generated at a maximum combined rate (for all three wastes) of 1,018 tons per
year. This exclusion was published on April 29, 1991 and is conditioned upon the
collection of data from Occidental's full-scale brine treatment system because Occidental's
request for exclusion was based on data from a laboratory-scale brine treatment process.
To ensure that hazardous constituents are not present in the waste at levels of regulatory
concern once the full-scale treatment system is in operation, Occidental must implement a
testing program for the petitioned waste All sampling and analyses (including quality
control procedures) must be performed according to SW-846 methodologies. This testing
program must meet the following conditions for the exclusion to be valid:
<1) Initial Testing: During the first four weeks of full-scale treatment system operation.
Occidental must do the following:
(A) Collect representative grab samples from each batch of the three treated wastestreams
(sodium chloride saturate* cleanings (NaCI-SC), sodium chloride treatment muds (NaQ-
TM) and potassium chloride treatment muds (KCI-TM)) on an as generated basis, and
composite the samples to produce three separate weekly composite samples (of each
type of K071 waste). The three weekly composite samples, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals (except mercury),
nickel and cyanide (using deionized water in the cyanide extractions), and the total
constituent concentrations of reactive sulfide and reactive cyanide. Occidental must report
the waste volumes produced and the analytical test data, including all quality control data,
obtained during this initial period, no later than 90 days after the treatment of me first full-
scale batch.
(B) Collect representative grab samples of each batch of the three treated wastestreams
(NaCI-SC, NAO-TM and KCI-TM) and composite the grab samples to produce three
separate daily composite samples (of each type of K071 waste) on an as generated basis.
The three daily composite samples, prior to disposal, must be analyzed for the EP
leachate concentration of mercury. Occidental must report the waste volumes produced
and the analytical test data, including all quality control data, obtained during this initial
period, no later than 90 days after the treatment of the first full-scale batch.
118
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Perox,
Incorporat-
ed.
Sharon,
Pennsylva-
nia.
(2) Subsequent Testing: After the first four weeks of full-scale treatment operations,
Occidental must do the following (all sampling and analyses (including quality control
procedures) must be performed according to SW-846 procedures):
(A) Continue to sample and test as described in condition (1)(A) Occidental must compile
and store on-site for a minimum of three years the records of waste volumes produced
and all analytical data and quality control data. These data must be furnished upon
request and made available for inspection by any employee or representative of EPA or
the State of Delaware. These testing requirements shall be terminated by EPA when the
results of four consecutive weekly composite samples of the petitioned waste, obtained
from either the initial testing or subsequent testing, show the maximum allowable levels in
condition (3) are not exceeded and the Section Chief, Variances Section, notifies
Occidental that the requirements of this condition have been lifted.
(B) Continue to sample and test for mercury as described in condition (1)(B). Occidental
must compile and store on-site for a minimum of three years the records of waste
volumes produced and all analytical data and quality control data. These data must be
furnished upon request and made available for inspection by any employee or representa-
tive of EPA or the State of Delaware. These testing requirements shall be terminated and
replaced with the requirements of condition (2)(C) if Occidental provides EPA with
analytical and quality control data for thirty consecutive batches of treated material,
collected as described in condition (1)(B), demonstrating that the EP leachable level of
mercury in condition (3) is not exceeded (in all three treated wastes), and the Section
Chief, Variances Section, notifies Occidental that the testing in condition (2)(B) may be
replaced with (2)(C).
(C) [If the conditions in (2)(B) are satisfied, the testing requirements for mercury in (2)(B)
shall be replaced with the following condition.] Collect representative grab samples from
each batch of the three treated wastestreams (NaCI-SC, NaCI-TM and KCI-TM) on an as
generated basis and composite the grab samples to produce three separate weekly
composite samples (of each type of K071 waste). The three weekly composite samples,
prior to disposal, must be analyzed for the EP leachate concentration of mercury.
Occidental must compile and store on-site for a minimum of three years the records of
waste volumes produced and all analytical data and quality control data. These data must
be furnished upon request and made available for inspection by any employee or
representative of EPA or the State of Delaware.
(3) If under conditions (1) or (2), the EP leachate concentration for chromium, lead, arsenic,
or silver exceeds 0.77 mg/L; for barium exceeds 15.5 mg/L; for cadmium or selenium
exceeds 0.16 mg/L; for mercury exceeds 0.031 mg/L; for nickel or total cyanide exceeds
10.9 mg/L; or the total reactive cyanide or total reactive sulfide levels exceeds 250 mg/kg
and 500 mg/kg, the waste must either be retreated or managed and disposed of in
accordance with all applicable hazardous waste regulations.
(4) Within one week of system start-up, Occidental must notify the Section Chief, Variances
Section (see address below) when the full-scale system is on-line and waste treatment
has begun. All data obtained through condition (1) must be submitted to the Section Chief,
Variances Section, PSPD/OSW, (OS-333), U.S. EPA, 401 M Street, SW., Washington, DC
20460 within the time period required in condition (1). At the Section Chief's request,
Occidental must submit any other analytical data obtained through conditions (1) and (2)
to the above address within the time period specified by the Section Chief. Failure to
submit the required data will be considered by the Agency sufficient basis to revoke
Occidental's exclusion to the extent directed by EPA. All data (either submitted to EPA or
maintained at the site) must be accompanied by the following statement:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code,
which include, but may not be limited to 18 U.S.C. 1001 and 42 U.S.C. 6926), I certify that
the information contained in or accompanying this document is true, accurate and
complete.
As to the (those) identified section(s) of this document for which I cannot personally verify its
(their) truth and accuracy, I certify as the company official having supervisory responsibility
for the persons who, acting under my direct instructions, made the verification that this
information is true, accurate and complete.
In the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
Iron oxide (EPA Hazardous Waste No. K062) generated (at a maximum annual rate of 4800
cubic yards) from a spent hydrochloric acid pickle liquor regeneration plant for spent pickle
liquor generated from steel finishing operations. This exclusion was published on,
November 13, 1990.
119
311-147 O—92-
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Pioneer Chlor
Alkai
Company,
Inc.
(formerly
Address
St. Gabriel, LA .
Waste description
Brine purification muds, which have been washed and vacuum filtered, generated after
August 27, 1985 from their chlor-alkali manufacturing operations (EPA Hazardous Waste
No. K071) that have been batch tested for mercury using the EP toxicity procedure and
have been found to contain less than 0.05 ppm in mercury in the EP extract. Brine
purification muds that exceed this level will be considered a hazardous waste.
Stauffer
Chemical
Company).
Reynolds
Metals
Company.
Gum Springs, Kiln residue (generated at a maximum annual volume of 300,000 cubic yards per year) from
Arkansas. I rotary kiln treatment of spent potliners (EPA Hazardous Waste No. K088). This exclusion
j was published on December 30, 1991. This exclusion does not apply to electrostatic
i precipitator dust generated by the rotary kiln. This exclusion initially applies only to the
treatment by one rotary kiln of potliners generated by Reynolds Metals' four primary
aluminum facilities (Massena, New York; Longview, Washington; Troutdale, Oregon; and
Baie Comeau. Quebec) described in the petition. Reynolds may only accept spent
potliners from other sources, or modify its treatment
process, or add an additional rotary kiln in accordance with Condition (5). This exclusion is
conditional upon the submission of data obtained trom each rotary kiln after it is
established at the R.P. Patterson facility in Gum Springs, Arkansas. To ensure that
hazardous constituents are not present in the waste at levels of regulatory concern while
the treatment facility is in operation, Reynolds must implement a testing program. This
testing program must meet the following conditions for the exclusion to be valid:
(1) Operating Conditions:
(A) Initial Verification Testing: During the first 20 days of full-scale operation of the rotary
kiln, at typical operating conditions, Reynolds must monitor and submit to EPA the rotary
kiln operating conditions (including, but not limited to: Temperature range of the kiln (hot
and cold end), kiln residue exit temperature, spent potliner feed rate, brown sand feed
rate, limestone feed rate, natural gas feed rate, oxygen/air feed rate, and rotary kiln
residence time of the raw materials). The ratio of the spent potliner feed rate to the
combined feed rates of the spent potliner, brown sand, and limestone must be no more
than 0.35. Information on all
other operating conditions should encompass all conditions used for preliminary testing
runs and those anticipated for subsequent waste processing. During initial verification
testing, the petitioner must also demonstrate to EPA how the range of operating
conditions could affect the process (i.e., submit analyses of representative grab samples,
as specified under Condition (2), of the kiln residue generated under the expected range
of operating conditions). The source of the brown sand must be from Reynolds' dry lake
beds at the Bauxite, Arkansas facility. Reynolds must submit the information specified in
this condition and obtained during this initial period no later than 90 days after the
treatment of the first full-scale batch of spent potliner.
(B) Subsequent Verification Testing: During subsequent verification testing, Reynolds must
monitor the performance of the rotary kiln at all times to ensure that it falls within the
range of operating conditions demonstrated during initial verification testing, to be
adequate to maintain the levels of hazardous constituents below the delistmg levels
specified in Condition (4). The feed rates of spent potliner, lime and brown sand are to be
as that described in Condition
(1)(A). Records of the operating conditions of the rotary kiln (including, but not limited to:
Temperature range of the kiln, kiln residue exit temperature, spent potliner feed rate,
brown sand feed rate, limestone feed rate, natural gas feed rate, oxygen/air feed rate, and
rotary kiln residence time of the raw materials) should be maintained on site for a
minimum of five years. This information must be furnished upon request and made
available for inspection by any employee or representative of EPA or the State of
Arkansas.
(2) Testing: Sample collection and analyses (including quality control (QC) procedures) must
be performed according to SW-846 methodologies. For fluoride, samples must be
analyzed using Method 340.2 from "Methods for Chemical Analysis of Water and Waste".
If the EPA judges the treatment process to be effective under the operating conditions
used during the initial verification testing, Reynolds may replace the testing required in
Condition (2)(A) with the testing required in Condition (2)(B). Reynolds must continue to
test daily composites of kiln residue generated beyond the time period specified in
Condition (2)(A) until and unless notified by EPA in writing that testing in Condition (2)(A)
may be replaced by Condition (2)(B) (to the extent directed by EPA).
(A) Initial Verification Testing: During the first 20 operating days of full-scale operation of the
new on-line rotary kiln. Reynolds must collect and analyze daily composites of kiln residue.
Daily composites must be composed of representative grab samples collected every 6
hours during each 24-hour kiln operating cycle. The kiln residue samples must be
analyzed, prior to the disposal of the kiln residue, for all constituents listed in Condition
(4). Reynolds must report the analytical test data, including quality control information,
obtained during this initial period no later than 90 days after the treatment of the first full-
scale batch of untreated spent potliner.
120
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
(B) Subsequent Verification Testing: Following notification by EPA, Reynolds may substitute
the testing conditions in (2)(B) for (2)(A). Reynolds must collect and analyze both daily and
weekly composites of kiln residue. Daily composites must be composed of representative
grab samples collected every 6 hours during a 24-hour kiln operating cycle and these
samples must be analyzed, prior to the disposal of the kiln residue, for leachable
concentrations of cyanide and fluoride. Weekly composites must be composed of
representative grab samples collected every 6 hours during a 24-hour kiln operating cycle
for each day in the week that the kiln is operating.
The weekly samples must be analyzed, prior to the disposal of the kiln residue, for the
leachable concentrations of the inorganics listed in Condition (4)(A) and leachable levels
of the semi-volatile organic compounds listed in Condition (4)(B). Analyses of both daily
and weekly samples must be completed prior to the disposal of waste generated during
that week as set forth in Condition (3). The analytical data, including quality control
information, must be compiled, summarized, and maintained on site for a minimum of five
years. These data must be furnished upon request and made available for inspection by
any employee or representative of EPA or the State of Arkansas.
(3) Waste Holding and Handling: Reynolds must store, as hazardous, all kiln residue
generated until verification testing (as specified in Condition (2)(A) and (2)(B)) is completed
and compared, by the petitioner, with the delisting levels set forth in Condition (4). If the
levels of hazardous constituents measured in the samples of kiln residue generated do not
exceed any of the levels set forth in Condition (4), then the kiln residue is non-hazardous
and may be managed and
disposed of in accordance with all applicable solid waste regulations. If hazardous
constituent levels in any daily or weekly sample exceed any of the delisting levels set in
Condition (4), the kiln residue generated during the time period corresponding to this
sample must be retreated until it meets these levels (analyses must be repeated) or
managed and disposed of in accordance with Subtitle C of RCRA. Kiln residue which is
generated but for which the required analysis is not complete or valid must be managed
and disposed of in accordance with Subtitle C of RCRA, until valid analysis demonstrates
that Condition (4) is satisfied.
(4) Delisting Levels: All concentrations must be measured in the waste leachate by the
method specified in 40 CFR 261.24.
(A) The leachable concentrations for metals may not exceed the following levels (ppm):
arsenic, selenium, or silver—0.60; barium—12.0; antimony—0.12; lead—0.18; cadmium—
0.06, chromium or nickel—1.2; mercury—0.024; beryllium—0.012; fluoride—48.0; and
cyanide—2.4 (cyanide extraction must be conducted using deionized water).
(B) The leachable constituent concentrations for organics may not exceed the levels listed
below (ppm):
Acenapthene—24
Benz(a)anthracene—1.2x10"*
Benzo(b)f luoranthene—2.4x10"4
Benzo(a)pyrene—2.4x10~3
Chrysene—2.4x10~3
Fluoranthene—12
Indeno (1,2,3-cd)pyrene—2.4x10~3
Pyrene—12
(5) Changes in Operating Conditions and Waste Sources: If after completing the initial
verification test period in Conditions (1)(A) and (2)(A), Reynolds decides to treat spent
potliner from any other primary aluminum reduction facility; or use a new source for brown
sand; or otherwise significantly change the operating conditions developed under Condition
(1); then Reynolds must notify EPA in writing prior to instituting the change. Reynolds must
also reinstitute the testing and reporting required in Conditions (1)(A) and (2)(A) for a
minimum period of four operating days and fulfill all other requirements in Conditions (1)
and (2), as appropriate.
Reynolds may also add one additional kiln at its R.P. Patterson facility in Gum Springs,
Arkansas if it can demonstrate that the new kiln can successfully treat spent potliners.
Reynolds must fulfill all requirements contained in Conditions (1) and (2) for the second
kiln. Reynolds must continue to test any kiln residue generated beyond the time period
specified in Condition (2)(A) until and unless notified in writing by EPA that testing
Condition (2)(A) may be replaced by (2)(B) to the extent directed by EPA.
(6) Data Submittals: Reynolds must notify in writing the Section Chief, Delisting Section (see
address below) when the rotary kiln is on-line and two weeks prior to when waste
treatment will begin. The data obtained through Conditions (1)(A) and (2)(A) must be
submitted to the Section Chief, Delisting Section, OSW (OS-333), U.S. EPA, 401 M Street,
SW, Washington, DC 20460 within the time period specified. At the Section Chief's
request, Reynolds must submit any other
121
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Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
analytical data obtained through Conditions (1){B) and (2)(B) within the time period
specified by the Section Chief. Failure to submit the required data within the specified time
period or maintain the required records on site for the specified time will be considered by
the Agency, at its discretion, sufficient basis to revoke the exclusion to the extent directed
by EPA. All data must be accompanied by a signed copy of the following certification
statement to attest to the truth and accuracy of the data submitted:
"Under civil and criminal penalty of law for the making or submission of false or fraudulent
statements or representations (pursuant to the applicable provisions of the Federal Code,
which include, but may not be limited to, 18 USC § 1001 and 42 USC §6928), I certify that
the information contained in or accompanying this document is true, accurate and
complete.
"As to the (those) identified section(s) of this document for which I cannot personally verify
its (their) truth and accuracy, I certify as the company official having supervisory
responsibility for the persons who, acting under my direct instructions, made the
verification that this information is true, accurate and complete.
"In the event that any of this information is determined by EPA in its sole discretion to be
false, inaccurate or incomplete, and upon conveyance of this fact to the company, I
recognize and agree that this exclusion of wastes will be void as if it never had effect or
to the extent directed by EPA and that the company will be liable for any actions taken in
contravention of the company's RCRA and CERCLA obligations premised upon the
company's reliance on the void exclusion."
122
-------
Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Roanoke
Electric
Steel Corp.
Roanoke, VA.
Tricil
Environmen-
tal Systems,
Inc.
Milliard, Ohio..
Fully-cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treatment
residue (EPA Hazardous Waste No. K061) generated from the primary production of steel
after March 22, 1989. This exclusion is conditioned upon the data obtained from
Roanoke's full-scale CSEAFD treatment facility because Roanoke's original data were
obtained from a laboratory-scale CSEAFD treatment process. To ensure that hazardous
constituents are not present in the waste at levels of regulatory concern once the full-
scale treatment facility is in operation, Roanoke must implement a testing program for the
petitioned waste.
This testing program must meet the following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial testing: During the first four weeks of operation of the full-scale treatment system,
Roanoke must collect representative grab samples of each treated batch of the CSEAFD
and composite the grab samples daily. The daily composites, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
(using distilled water in the cyanide extractions), and the total constituent concentrations
of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
846 methodologies. Roanoke must report the analytical test data obtained during this
initial period no later than 90 days after the treatment of the first full-scale batch.
(.8) Subsequent testing: Roanoke must collect representative grab samples from every
treated batch of CSEAFD generated daily and composite all of the grab samples to
produce a weekly composite sample. Roanoke then must analyze each weekly composite
sample for a/I of the EP toxic metals and nickel. Analyses must be performed according to
SW-846 methodologies. The analytical data, including all quality control information, must
be compiled and maintained on site for a minimum of three years. These data must be
furnished upon request and made available for inspection by any employee or representa-
tive of EPA or the State of Virginia.
(2) Delisting levels: If the EP extract concentrations for chromium, lead, arsenic, or silver
exceed 0.315 mg/l; for barium exceeds 6.3 mg/l; for cadmium or selenium exceed 0.063
mg/l; for mercury exceeds 0.0126 mg/l; for nickel exceeds 3.15 mg/l; or for cyanide
exceeds 1.26 mg/l, or total reactive cyanide or total reactive sulfide levels exceed 250
mg/kg and 500 mg/kg, respectively, the waste must either be re-treated or managed and
disposed in accordance with Subtitle C of RCRA.
<3) Data submittals: Within one week of system start-up, Roanoke must notify the Sect/on
Chief, Variances Section (see address below) when their full-scale stabilization system in
on-line and waste treatment has begun. All data obtained through the initial testing
condition (1KA), must be submitted to the Section Chief, Variances Section, PSPD/OSW,
(OS-343), U.S. EPA, 401 M Street, SW., Washington, DC 20460 within the time period
specified in condition (?)
-------
Pt. 261, App. IX 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Trial
Environmen-
tal System,
Inc.
Address
Muskegon,
Michigan.
Waste description
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm; or teachable cyanide levels (using ther EP
Toxicity test without acetic acid adjustment) exceed 1.26 ppm, the waste must be
retreated or managed and disposed as hazardous waste under 40 CFR parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
parts 262 and 265 and the permitting standards of 40 CFR Part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrdein, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chtoro-m-cresol, 133
1,1-Dichloroethane, 0.01
Fluorene, 10.4
Methylenechloride, 8.2
Methyl ethyl ketone, 326
n-Nitrosodiphenylamine, 11.9
Phenanthrene, 14
Tetrachloroethylene, 0.188
Trichloroethytene, 0.59
Chloroform, 0.013
1,2-Dichloroethane, 0.0083
1 ,2-trans-Dichloroethylene, 231
2.4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
1 ,2-Diphenyl hydrazine, 0.001
(4) A grab sample must be collected from each batch to form one monthy composite
sample, which must be tested using GC/MS analysis for the organic compounds shown
above, as well as the remaining organics on the priority pollutant list (see 47 FR 52309,
November 19, 1982, Appendix A-126 Priority Pollutants).
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue described in this
petition.
Spent pickle liquor (EPA Hazardous Waste No. K062) generated by steel finishing operations
Of facilities within the iron and steel industry (SIC Codes 331 and 332); after November 17,
1986. To ensure that hazardous constituents are not present in the waste at levels of
regulatory concern, the facility must implement a contingency testing program for the
petitioned wastes. This testing program must meet the following conditions for the
exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, barium, cadmium.
chromium, lead, mercury, selenium, silver and nickel. If the extract concentrations for
chromium, lead, arsenic, barium, and silver exceed 6.3 ppm, cadmium and selenium
exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or nickel levels exceed 2.2 ppm,
the waste will be retreated or managed and disposed as a hazardous waste under 40 CFR
parts 262 to 265 and the permitting standards of 40 CFR 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm; or teachable cyanide levels (using the EP
Toxicity test without acetic acid adjustment) exceed 1.26 ppm, the waste must be
retreated or managed and disposed as hazardous waste under 40 CFR parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and dipnosed as a hazardous waste under 40 CFR
parts 262 and 265 and the permitting standards of 40 CFR Part 270:
Compound and Maximum Acceptable Levels (ppm)
Acrotetn, 56.8
Anthracene, 76.8
Benzene. 0.106
p-Chkxc-m-cresol, 133
1,1-Dichloroethane, 0.01
124
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Environmental Protection Agency Pt. 261, App. IX
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
USX Steel
Corporation,
uss
Division,
Southworks
Plant, Gary
Works.
Chicago,
Illinois.
Fluorene, 10.4
Methylenechloride, 8.2
Methyl ethyl ketone, 326
n-Nitrosodiphenylamine, 11.9
Phenanthrene, 14
Tetrachtoroettiylene, 0.188
Trichloroethyiene. 0.59
Chloroform, 0.013
1,2-Dtchloroethane. 0.0083
1,2-trans-Dtchloroethylene, 231
2,4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
1,2-Diphenyl hydrazine, 0.001
(4) A grab sample must be collected from each batch to form one monthly composite
sample, which must be tested using GC/MS analysis for the organic compounds shown
above, as well as the remaining organics on the priority pollutant list (see 47 FR 52309,
November 19, 1982, Appendix A-126 Priority Pollutants).
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wasterwater treatment
system at this facility applies only to the wastewater treatment residue described in this
petition.
Fully-cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treatment
residue
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Pt. 261, App. X 40 CFR Ch. I (7-1-92 Edition)
TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Vulcan
Materials
Company.
Port Edwards,
Wl.
(3) Data submittals: Within one week of system start-up USX must notify the Section Chief,
Oelisting Section (see address below) when their full-scale stabilization system is on-line
and waste treatment has begun. The data obtained through condition (1)(A) must be
submitted to the Section Chief, Delisting Section, CAD/OSW (OS-333), U.S. EPA, 401 M
Street, S.W., Washington, DC 20460 within the time period specified. At the Section
Chief's request, USX must submit any other analytical data obtained through conditions
(1)(A) or (1)(B) within the time period specified by the Section Chief. Failure to submit the
required data obtained from conditions (1)(A) or (1)(B) within the specified time period or
maintain the required records for the specified time will be considered by the Agency, at
its discretion, sufficient basis to revoke USX's exclusion to the extent directed by EPA. All
data must be accompanied by the following certification statement: "Under civil and
criminal penalty of law for the making or submission of false or fraudulent statements or
representations (pursuant to the applicable provisions of the Federal Code which include,
but may not be limited to, 18 U.S.C. §6928), I certify that the information contained in or
accompanying this document is true, accurate and complete. As to the (those) identified
section(s) of this document for which I cannot personally verify its (their) truth and
accuracy, I certify as the company official having supervisory responsibility for the persons
who, acting under my direct instructions, made the verification that this information is true,
accurate and complete. In the event that any of this information is determined by EPA in
its sole discretion to be false, inaccurate or incomplete, and upon conveyance of this fact
to the company, I recognize and agree that this exclusion of wastes will be void as if it
never had effect or to the extent directed by EPA and that the company will be liable for
any actions taken in contravention of the company's RCRA and CERCLA obligations
premised upon the company's reliance on the void exclusion."
Brine purification muds (EPA Hazardous Waste No. K071) generated from the mercury cell
process in chlorine production, where separately prepurified brine is not used after
November 17, 1986. To assure that mercury levels in this waste are maintained at
acceptable levels, the following conditions apply to this exclusion: Each batch of treated
brine clanfier muds and saturator insolubles must be tested (by the extraction procedure)
prior to disposal and the leachate concentration of mercury must be less than or equal to
0.0129 ppm. If the waste does not meet this requirement, then it must be re-treated or
disposed of as hazardous. This exclusion does not apply to wastes for which either of
these conditions is not satisfied.
TABLE 3—WASTES EXCLUDED FROM COMMER-
CIAL CHEMICAL PRODUCTS, OFF-SPECIFICA-
TION SPECIES, CONTAINER RESIDUES, AND
SOIL RESIDUES THEREOF
Facility
Union Carbide
Corp.
Address
Tafl LA
Waste description
Contaminated soil (approxi-
mately 1 1 ,000 cubic
yards), which contains
acrolem in concentra-
tions of less than 9 ppm.
[49 PR 37070, Sept. 21, 1984]
EDITORIAL NOTE: For FEDERAL REGISTER ci-
tations affecting appendix IX of part 261,
see the List of CFR Sections Affected in the
Finding Aids section of this volume.
APPENDIX X TO PART 261—METHOD OF
ANALYSIS FOR CHLORINATED DI-
BENZO-P-DIOXINS AND -DIBENZO-
FTJRANS »• * a- 4
Method 8280
1. Scope and Application
'This method is appropriate for the anal-
ysis of tetra-, penta-, and hexachlorinated
dibenzo-p-dioxins and -dibenzofurans.
2 Analytical protocol for determination of
TCDDs in phenolic chemical wastes and soil
samples obtained from the proximity of
chemical dumps. T.O. Tiernan and M.
Taylor. Brehm Laboratory, Wright State
University, Dayton, OH 45435.
'Analytical protocol for determination of
chlorinated dibenzo-p-dioxins and chlorinat-
ed dibenzofurans in river water. T.O. Tier-
nan and M. Taylor. Brehm Laboratory,
Wright State University, Dayton, OH 45435.
4 In general, the techniques that should be
used to handle these materials are those
which are followed for radioactive or infec-
tious laboratory materials. Assistance in
evaluating laboratory practices may be ob-
Continued
126
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Environmental Protection Agency
Pt. 261, App. X
1.1 This method measures the concentra-
tion of chlorinated dibenzo-p-dioxins and
chlorinated dibenzofurans in chemical
wastes including still bottoms, filter aids,
sludges, spent carbon, and reactor residues,
and in soils.
1.2 The sensitivity of this method is de-
pendent upon the level of interferences.
1.3 This method is recommended for use
only by analysts experienced with residue
analysis and skilled in mass spectral analyti-
cal techniques.
1.4 Because of the extreme toxicity of
these compounds, the analyst must take
necessary precautions to prevent exposure
to himself, or to others, of materials known
or believed to contain CDDs or CDPs.
2. Summary of the Method
2.1 This method is an analytical extrac-
tion cleanup procedure, and capillary
column gas chromatograph-low resolution
mass spectrometry method, using capillary
column GC/MS conditions and internal
standard techniques, which allow for the
measurement of PCDDs and PCDPs in the
extract.
2.2 If interferences are encountered, the
method provides selected general purpose
cleanup procedures to aid the analyst in
their elimination.
3. Interferences
3.1 Solvents, reagents, glassware, and
other sample processing hardware may yield
discrete artifacts and/or elevated baselines
causing misinterpretation of gas chromato-
grams. All of these materials must be dem-
onstrated to be free from interferences
under the conditions of the analysis by run-
ning method blanks. Specific selection of
reagents and purification of solvents by dis-
tillation in all-glass systems may be re-
quired.
3.2 Interferences co-extracted from the
samples will vary considerably from source
to source, depending upon the diversity of
the industry being sampled. PCDD is often
associated with other interfering chlorinat-
tained from industrial hygienists and per-
sons specializing in safe laboratory prac-
tices. Typical infectious waste incinerators
are probably not satisfactory devices for dis-
posal of materials highly contaminated with
CDDs or CDFs. Safety instructions are out-
lined in EPA Test Method 613(4.0)
See also: (1) "Program for monitoring po-
tential contamination in the laboratory fol-
lowing the handling and analyses of chlorin-
ated dibenzo-p-dioxins and dibenzofurans"
by F. D. Hileman et al.. In: Human and En-
vironmental Risks of Chlorinated Dioxins
and Related Compounds, R.E. Tucker, et al,
eds., Plenum Publishing Corp., 1983. 2)
Safety procedures outlined in EPA Method
613, Federal Register volume 44, No. 233,
December 3, 1979.
ed compounds such as PCB's which may be
at concentrations several orders of magni-
tude higher than that of PCDD. While gen-
eral cleanup techniques are provided as part
of this method, unique samples may require
additional cleanup approaches to achieve
the sensitivity stated in Table 1.
TABLE 1—GAS CHROMATOGRAPHY OF TCDD
Column
Glass capillary
Reten-
tion time
(min.)
9 5
Detec-
tion limit
(M/kg)1
0003
1 Detection limit fo' liquid samples is 0.003 fig/I. This is
calculated from the minimum detectable GC response being
equal to five times the GC background noise assuming a 1
ml effective final volume of the 1 liter sample extract, and a
GC injection of 5 microliters. Detection levels apply to both
electron capture and GC/MS detection. For further details
see 44 FR 69526 (December 3, 1979).
3.3 The other isomers of tetrachlorodi-
benzo-p-dioxin may interfere with the meas-
urement of 2,3,7,8-TCDD. Capillary column
gas chromatography is required to resolve
those isomers that yield virtually identical
mass fragmentation patterns.
4. Apparatus and Materials
4.1. Sampling equipment for discrete or
composite sampling.
4.1.1 Grab sample bottle—amber glass, 1-
liter or 1-quart volume. French or Boston
Round design is recommended. The contain-
er must be washed and solvent rinsed before
use to minimize interferences.
4.1.2. Bottle caps—threaded to screw on
to the sample bottles. Caps must be lined
with Teflon. Solvent washed foil, used with
the shiny side towards the sample, may be
substituted for the Teflon if sample is not
corrosive.
4.1.3. Compositing equipment—automatic
or manual composing system. No tygon or
rubber tubing may be used, and the system
must incorporate glass sample containers
for the collection of a minimum of 250 ml.
Sample containers must be kept refrigerat-
ed after sampling.
4.2 Water bath—heated, with concentric
ring cover, capable of temperature control
(±2 °C). The bath should be used in a hood.
4.3 Gas chromatograph/mass spectrome-
ter data system.
4.3.1 Gas chromatograph: An analytical
system with a temperature-programmable
gas chromatograph and all required accesso-
ries including syringes, analytical columns,
and gases.
4.3.2 Column: SP-2250 coated on a 30 m
long x 0.25 mm I.D. glass column (Supelco
No. 2-3714 or equivalent). Glass capillary
column conditions: Helium carrier gas at 30
cm/sec linear velocity run splitless. Column
temperature is 210 °C.
127
-------
Pt. 261, App. X
4.3.3 Mass spectrometer: Capable of scan-
ning from 35 to 450 amu every 1 sec or less,
utilizing 70 volts (nominal) electron energy
in the electron impact ionization mode and
producing a mass spectrum which meets all
the criteria in Table 2 when 50 ng of deca-
fluorotriphenyl-phosphine (DFTPP) is in-
jected through the GC inlet. The system
must also be capable of selected ion moni-
toring (SIM) for at least 4 ions simulta-
neously, with a cycle time of 1 sec or less.
Minimum integration time for SIM is 100
ms. Selected ion monitoring is verified by in-
jecting .015 ng of TCDD Cl37 to give a mini-
mum signal to noise ratio of 5 to 1 at mass
328.
TABLE 2—DFTPP KEY IONS AND ION
ABUNDANCE CRITERIA *
Mass
51
68
70
127
197
196
199
275
365
441
442
443
Ion abundance criteria
30-60% of mass 198.
Less than 2% of mass 69.
Less than 2% of mass 69.
40-60% of mass 198.
Less than 1% of mass 198.
Base peak. 100% relative abundance.
5-9% of mass 196.
10-30% of mass 198.
Greater than 1% of mass 198.
Present but less than mass 443.
Greater than 40% of mass 198.
17-23% of mass 442.
»J. W. Eichelberger, l_E. Hams, and W.L. Budde. 1975.
Reference compound to calibrate ion abundance measure-
ment in gas chromatography-mass spectrometry. Analytical
Chemistiy 47:995.
4.3.4 GC/MS interface: Any GC-to-MS
interface that gives acceptable calibration
points at 50 ng per injection for each com-
pound of interest and achieves acceptable
tuning performance criteria (see Sections
6.1 through 6.3) may be used. GC-to-MS
interfaces constructed of all glass or glass-
lined materials are recommended. Glass can
be deactivated by silanizing with dichlorodi-
methylsilane. The interface must be capable
of transporting at least 10 ng of the compo-
nents of interest from the GC to the MS.
4.3.5 Data system: A computer system
must be interfaced to the mass spectrome-
ter. The system must allow the continuous
acquisition and storage on machine-readable
media of all mass spectra obtained through-
out the duration of the chromatographic
program. The computer must have software
that can search any GC/MS data file for
ions of a specific mass and that can plot
such ion abundances versus time or scan
number. This type of plot is defined as an
Extracted Ion Current Profile (EICP). Soft-
ware must also be able to integrate the
abundance, in any EICP, between specified
time or scan number limits.
40 CFR Ch. I (7-1-92 Edition)
4.4 Pipettes-Disposable, Pasteur, 150 mm
long x 5 mm ID (Fisher Scientific Co., No.
13-678-6A or equivalent).
4.5 Flint glass bottle (Teflon-lined screw
cap).
4.6 Reacti-vial (silanized) (Pierce Chemi-
cal Co.).
5. Reagents
5.1 Potassium hydroxide-(ACS), 2% in
distilled water.
5.2 Sulfuric acid-(ACS), concentrated.
5.3 Methylene chloride, hexane, benzene,
petroleum ether, methanol, tetradecane-pes-
ticide quality or equivalent.
5.4 Prepare stock standard solutions of
TCDD and "Cl-TCDD (molecular weight
328) in a glove box. The stock solutions are
stored in a glovebox, and checked frequent-
ly for signs of degradation or evaporation,
especially just prior to the preparation of
working standards.
5.5 Alumina-basic, Woelm; 80/200 mesh.
Before use activate overnight at 600°C, cool
to room temperature in a dessicator.
5.6 Prepurified nitrogen gas
6.0 Calibration
6.1 Before using any cleanup procedure,
the analyst must process a series of calibra-
tion standards through the procedure to
validate elution patterns and the absence of
interferences from reagents.
6.2 Prepare GC/MS calibration stand-
ards for the internal standard technique
that will allow for measurement of relative
response factors of at least three CDD/
37CDD ratios. Thus, for TCDDs, at least
three TCDD/J1C1-TCDD and TCDF/'O-
TCDF must be determined.5 The 31C1-
TCDD/F concentration in the standard
should be fixed and selected to yield a re-
producible response at the most sensitive
setting of the mass spectrometer. Response
factors for PCDD and HxCDD may be de-
termined by measuring the response of the
tetrachloro-labelled compounds relative to
that of the unlabelled 1.2,3,4- or 2,3,7,8-
TCDD, 1,2,3,4,7-PCDD or 1,2,3,4,7,8-
HxCDD, which are commercially available.8
* JX21-labelled 2,3,7,8-TCDD and 2.3,7,8-
TCDF are available from K.O.R. Isotopes,
and Cambridge Isotopes, Inc., Cambridge,
MA. Proper standardization requires the use
of a specific labelled isomer for each conge-
ner to be determined. However, the only la-
belled isomers readily available are 31Cl-
2,3,7,8-TCDD and J1Cl-2,3,7,8-TCDF. This
method therefore uses these isomers as sur-
rogates for the CDDs and CDFs. When
other labelled CDDs and CDFs are avail-
able, their use will be required.
6 This procedure is adopted because stand-
ards are not available for most of the CDDs
and CDFs, and assumes that all the con-
Continued
128
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Environmental Protection Agency
Pt. 261, App. X
6.3 Assemble the necessary GC/MS ap-
paratus and establish operating parameters
equivalent to those indicated in Section 11.1
of this method. Calibrate the GC/MS
system according to Eichelberger, et al.
(1975) by the use of decafluorotriphenyl
phosphine (DPTPP). By injecting calibra-
tion standards, establish the response fac-
tors for CDDs vs. 31C1-TCDD, and for CDFs
vs. 3K21-TCDF. The detection limit provided
in Table I should be verified by injecting
.015 ng of 31C1-TCDD which should give a
minimum signal to noise ratio of 5 to 1 at
mass 328.
7. Quality Control
7.1 Before processing any samples, the
analyst should demonstrate through the
analysis of a distilled water method blank,
that all glassware and reagents are interfer-
ence-free. Each time a set of samples is ex-
tracted, or there is a change in reagents, a
method blank should be processed as a safe-
guard against laboratory contamination.
7.2 Standard quality assurance practices
must be used with this method. Field repli-
cates must be collected to measure the pre-
cision of the sampling technique. Laborato-
ry replicates must be analyzed to establish
the precision of the analysis. Fortified sam-
ples must be analyzed to establish the accu-
racy of the analysis.
8. Sample Collection, Preservation, and
Handling
8.1 Grab and composite samples must be
collected in glass containers. Conventional
sampling practices should be followed,
except that the bottle must not be
prewashed with sample before collection.
Composite samples should be collected in
glass containers in accordance with the re-
quirements of the RCRA program. Sam-
pling equipment must be free of tygon and
other potential sources of contamination.
8.2 The samples must be iced or refriger-
ated from the time of collection until ex-
traction. Chemical preservatives should not
be used in the field unless more than 24
hours will elapse before delivery to the labo-
ratory. If an aqueous sample is taken and
the sample will not be extracted within 48
hours of collection, the sample should be
adjusted to a pH range of 6.0-8.0 with
sodium hydroxide or sulfuric acid.
8.3 All samples must be extracted within
7 days and completely analyzed within 30
days of collection.
9. Extraction and Cleanup Procedures
9.1 Use an aliquot of 1-10 g sample of the
chemical waste or soil to be analyzed. Soils
should be dried using a stream of prepuri-
fied nitrogen and pulverized in a ball-mill or
geners will show the same response as the
unlabelled congener used as a standard. Al-
though this assumption may not be true in
all cases, the error will be small.
similar device. Perform this operation in a
clear area with proper hood space. Transfer
the sample to a tared 125 ml flint glass
bottle (Teflon-lined screw cap) and deter-
mine the weight of the sample. Add an ap-
propriate quantity of 3*Cl-labelled 2,3,7,8-
TCDD (adjust the quantity according to the
required minimum detectable concentra-
tion), which is employed as an internal
standard.
9.2 Extraction
9.2.1 Extract chemical waste samples by
adding 10 ml methanol, 40 ml petroleum
ether, 50 ml doubly distilled water, and then
shaking the mixture for 2 minutes. Tars
should be completely dissolved in any of the
recommended neat solvents. Activated
carbon samples must be extracted with ben-
zene using method 3540 in SW-846 (Test
Methods for Evaluating Solid Waste—Physi-
cal/Chemical Methods, available from
G.P.O. Stock #055-022-81001-2). Quantita-
tively transfer the organic extract or dis-
solved sample to a clean 250 ml flint glass
bottle (Teflon lined screw cap), add 50 ml
doubly distilled water and shake for 2 min-
utes. Discard the aqueous layer and proceed
with Step 9.3.
9.2.2 Extract soil samples by adding 40
ml of petroleum ether to the sample, and
then shaking for 20 minutes. Quantitatively
transfer the organic extract to a clean 250
ml flint glass bottle (Teflon-lined screw
cap), add 50 ml doubly distilled water and
shake for 2 minutes. Discard the aqueous
layer and proceed with Step 9.3.
9.3 Wash the organic layer with 50 ml of
20% aqueous potassium hydroxide by shak-
ing for 10 minutes and then remove and dis-
card the aqueous layer.
9.4 Wash the organic layer with 50 ml of
doubly distilled water by shaking for 2 min-
utes, and discard the aqueous layer.
9.5 Cautiously add 50 ml concentrated
sulfuric acid and shake for 10 minutes.
Allow the mixture to stand until layers sep-
arate (approximately 10 minutes), and
remove and discard the acid layer. Repeat
acid washing until no color is visible in the
acid layer.
9.6 Add 50 ml of doubly distilled water to
the organic extract and shake for 2 minutes.
Remove and discard the aqueous layer and
dry the organic layer by adding lOg of anhy-
drous sodium sulfate.
9.7 Concentrate the extract to incipient
dryness by heating in a 55° C water bath
and simultaneously flowing a stream of pre-
purified nitrogen over the extract. Quanti-
tatively transfer the residue to an alumina
microcolumn fabricated as follows:
9.7.1 Cut off the top section of a 10 ml
disposable Pyrex pipette at the 4.0 ml mark
and insert a plug of silanized glass wool into
the tip of the lower portion of the pipette.
129
-------
Pt. 261, App. X
40 CFR Ch. I (7-1-92 Edition)
9.7.2 Add 2.8g of Woelm basic alumina
(previously activated at 600° C overnight
and then cooled to room temperature in a
desiccator just prior to use).
9.7.3 Transfer sample extract with a
small volume of methylene chloride.
9.8 Elute the microcolumn with 10 ml of
3% methylene chloride-in-hexane followed
by 15 ml of 20% methylene chloride-in-
hexane and discard these effluents. Elute
the column with 15 ml of 50% methylene
chloride-in-hexane and concentrate this ef-
fluent (55° C water bath, stream of prepuri-
fied nitrogen) to about 0.3-0.5 ml.
9.9 Quantitatively transfer the residue
(using methylene chloride to rinse the con-
tainer) to a silanized Reacti-Vial (Pierce
Chemical Co.). Evaporate, using a stream of
prepurified nitrogen, almost to dryness,
rinse the walls of the vessel with approxi-
mately 0.5 ml methylene chloride, evaporate
just to dryness, and tightly cap the vial.
Store the vial at 5° C until analysis, at
which time the sample is reconstituted by
the addition of tridecane.
9.10 Approximately 1 hour before GC-
MS (HRGC-LRMS) analysis, dilute the resi-
due in the micro-reaction vessel with an ap-
propriate quantity of tridecane. Gently
swirl the tridecane on the lower portion of
the vessel to ensure dissolution of the CDDs
and CDFs. Analyze a sample by GC/EC to
provide insight into the complexity of the
problem, and to determine the manner in
which the mass spectrometer should be
used. Inject an appropriate aliquot of the
sample into the GC-MS instrument, using a
syringe.
9.11 If, upon preliminary GC-MS analy-
sis, the sample appears to contain interfer-
ing substances which obscure the analyses
for CDDs and CDFs, high performance
liquid chromatographic (HPLC) cleanup of
the extract is accomplished, prior to further
GC-MS analysis.
10. HPLC Cleanup Procedure'
10.1 Place approximately 2 ml of hexane
in a 50 ml flint glass sample bottle fitted
with a Teflon-lined cap.
10.2 At the appropriate retention time,
position sample bottle to collect the re-
quired fraction.
10.3 Add 2 ml of 5% (w/v) sodium car-
bonate to the sample fraction collected and
shake for one minute.
10.4 Quantitatively remove the hexane
layer (top layer) and transfer to a micro-re-
action vessel.
10.5 Concentrate the fraction to dryness
and retain for further analysis.
11. GC/MS Analysis
11.1 The following column conditions are
recommended: Glass capillary column condi-
tions: SP-2250 coated on a 30 m long x 0.25
mm I.D. glass column (Supelco No. 2-3714,
or equivalent) with helium carrier gas at 30
cm/sec linear velocity, run splitless. Column
temperature is 210*C. Under these condi-
tions the retention time for TCDDs is about
9.5 minutes. Calibrate the system daily
with, a minimum, three injections of stand-
ard mixtures.
11.2 Calculate response factors for stand-
ards relative to 3Kfl-TCDD/F (see Section
12).
11.3 Analyze samples with selected ion
monitoring of at least two ions from Table
3. Proof of the presence of CDD or CDF
exists if the following conditions are met:
11.3.1 The retention time of the peak in
the sample must match that in the stand-
ard, within the performance specifications
of the analytical system.
11.3.2 The ratio of ions must agree
within 10% with that of the standard.
11.3.3 The retention time of the peak
maximum for the ions of interest must ex-
actly match that of the peak.
TABLE 3—LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING, Low
RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
AND HEXACHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS
Class ol chlorinated dtoenzodioxin or dbenzofuran
Tetra
Number
of
chlorine
substit-
uents(x)
4
Monitored m/z
for
dibenzodioxjns
CUH.-.OII,
i 4iQ fio?
321.894
'327.885
'256.933
* 258.930
Monitored m/z
for
dibenzofurans
CijH»-»OdB
1 WV9OH9
305.903
'311.894
Approxi-
mate
theoretical
ratio
expected
on basis of
tsotopic
abundance
1.00
0.21
0.20
1 For cleanup see also method #8320 or
#8330. SW-846, Test Methods for Evaluat-
ing Solid Waste, Physical/Chemical Meth-
ods (1982).
130
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Environmental Protection Agency
Pt. 261, App. X
TABLE 3—LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING, Low
RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
AND HEXACHLORINATED DIBENZO-/P-DIOXINS AND DIBENZOFURANS—Continued
Class of chlorinated dibenzodioxin or dibenzofuran
Penta
Hexa
Number
nf
chlorine
substit-
uents (x)
5
6
Monitored m/z
for
dibenzodioxins
C,2H8-,021,
1 353 858
355.855
389 816
391.813
Monitored m/z
for
dibenzofurans
C12H8-XOC1,
1 337 863
339.860
373 821
375.318
Approxi-
mate
theoretical
ratio
expected
on basis of
isotopic
abundance
057
1.00
1 00
0.87
1 Molecular ion peak.
2 Cl,—labelled standard peaks.
3 Ions which can be monitored in TCDD analyses for confirmation purposes.
11.4 Quantitate the CDD and CDF peaks
from the response relative to the "C1-
TCDD/P internal standards. Recovery of
the internal standard should be greater
than 50 percent.
11.5 If a response is obtained for the ap-
propriate set of ions, but is outside the ex-
pected ratio, a co-eluting impurity may be
suspected. In this case, another set of ions
characteristic of the CDD/CDP molecules
should be analyzed. For TCDD a good
choice of ions is m/e 257 and m/e 259. For
TCDF a good choice of ions is m/e 241 and
243. These ions are useful in characterizing
the molecular structure to TCDD or TCDF.
For analysis of TCDD good analytical tech-
nique would require using all four ions, m/e
257, 320, 322, and 328, to verify detection
and signal to noise ratio of 5 to 1. Suspected
impurities such as DDE, DDD, or PCB resi-
dues can be confirmed by checking for their
major fragments. These materials can be re-
moved by the cleanup columns. Failure to
meet criteria should be explained in the
report, or the sample reanalyzed.
11.6 If broad background interference re-
stricts the sensitivity of the GC/MS analy-
sis, the analyst should employ cleanup pro-
cedures and reanalyze by GC/MS. See sec-
tion 10.0.
11.7 In those circumstances where these
procedures do not yield a definitive conclu-
sion, the use of high resolution mass spec-
trometry is suggested.
12. Calculations
12.1 Determine the concentration of indi-
vidual compounds according to the formula:
Concentration,
AxAs
GxAlsxRf
A = >ig of internal standard added to the
sample 8
G = gm of sample extracted
As=area of characteristic ion of the com-
pound being quantified.
Ais=area of characteristic ion of the inter-
nal standard
R,=response factor 9
Response factors are calculated using data
obtained from the analysis of standards ac-
cording to the formula:
AsxCis
Rf
where:
Cis=concentration of the internal standard
Cc = concentration of the standard com-
pound
12.2 Report results in micrograms per
gram without correction for recovery data.
When duplicate and spiked samples are ana-
lyzed, all data obtained should be reported.
12.3 Accuracy and Precision. No data are
available at this time.
[50 FR 2001, Jan. 14,1985]
where:
8 The proper amount of standard to be
used is determined from the calibration
curve (See Section 6.0).
9 If standards for PCDDs/Fs and
HxCDDs/Fs are not available, response fac-
tors for ions derived from these congeners
are calculated relative to 3'C1-TCDD/F. The
analyst may use response factors for 1,2,3,4-
or 2.3.7.8-TCDD, 1,2,3,4,7-PeCDD, or
1,2,3,4,7,8-HxCDD for quantitation of
TCDDs/Fs, PeCDDs/Fs and HxCDDs/Fs,
respectively. Implicit in this requirement is
the assumption that the same response is
obtained from PCDDs/Fs ccontaining the
same numbers of chlorine atoms.
131
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ID • For Off icial Use Only
A. Hazardous Waste Activity
B. Used CHI Recyc ling Activities
1. Generator (See Instructions) , D &
Q a. Greater than f OOOko/mo (2^200 IDS.)
Bb. 100 to 1000 kg/mo (200-2,200 Ibs.)
c.iess than 100 kg/mo (220 H») .-
2, Transporter(fndlcateModetnboxes1-5 > 4*
below) ' >, > -<
a. For own waste only ! • '
b. For commercial purposes
|y!o& of Transportation
If.AIr '
Treater, Storer, Disposer {at
Installation} Note: A permit is
required for 81(9 activity; see
instructions. * >
Hazardous Waste Fuel ' ' ,'
a. Generator Marketing to Burner
b. Other Marketers
c. BolteranoYorlrKlustrfelFumace
1. Smelter Deferral
2. Small Quantity Exemption
Indicate Type of Combination
.
B
3-Hlgnway
4, Water
S. Other ~apeclfy
§1, Utility Bofler
2. mdustrtat Bolter
3, industrial Furnace
U 5. Underground Injection Control
1, Used Oil Fuel Marketer
Qa. Marketer Directs Shipment of Used
• Oil to Off-Specification Burner
D*». Marketer Who First Claims the Used
Oil Meets the Specifications
2, Used Oil Burner - Indicate Type(s} of
Combustion Devtee(s)
a. Utility Bolter ;
b. Industrial Boiler
c. Industrial Furnace
3. Used 0« Transporter - Indicate Type(s)
otAc«vfty(ies) :,
Ba. Transporter ' .
b, Transfer Factttty
4 Used OB Processor/Re-refiner«indicate
Type(s)ofActivlty(tea)
Ba. Process : '
b, Re-refine
IX. Description of Hazardous Wastes (Use additional afieata If necessary)
A. Characteristics of Nonlisted Hazardous Wastes. (Mark 'X' In the boxes corresponding to the characteristics of
nonllsted hazardous wastes your Installation handles; See 40 CFR Parts 26130 • i
l.lgnltabte ICwroulwj
V ***S0
(DM3}
ChafadwteUc (U« specific EPA hazartww wart*
B. Listed Hazardous Wastes. (See 40 CFR 281.31 - 33; See Instructions If you need to list more than 12 waste codes.)
C. Other Wastes. (State or other wastes requiring a handler to have an I.D. number; See Instructions.)
X. Certification
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision In accordance with a
system designed to assure that qualified personnel proper lygatherandevaluatethe Information submitted. Based on my Inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the Information, the Information submitted Is, to the
best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information,
Including the possibility of fine and Imprisonment for knowing violations.
Signature
Name and Official Title (Type or print)
Dale Signed
XI. Comments
Note: Mail completed form to the appropriate EPA Regional or State Office. (See Section III of the booklet for addresses.)
EPA Form 8700-12 (Rev. 11-30-93) Previous edition Is obsolete.
-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
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. , , , ,, „,„,„ ,„ , , , ,
\ B. Listed Hazardous Wastes. (See 40 CFR 261.31 • 33; Use this page only If you need to list more than 12 waste codes.)'
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EPA Form 8700-12 (Rev. 11-30-93) Previous edition Is obsolete.
-------
Notification of Regulated Waste Activity
Appendix 1
Typical Waste Streams Produced by Small Quantity Generators
LABORATORIES
Acids/Bases, Heavy Metals/Inorganics,
Ignltable Wastes, Reactives, Solvents
PRINTING AND ALLIED INDUSTRIES
Acids/Bases, Heavy Metals/Inorganics,
Ink Sludges, Spent Plating Wastes,
Solvents
PESTICIDE END USERS AND
APPLICATION
Heavy Metals/Inorganics, Services,
Pesticides, Solvents
CONSTRUCTION
Acids/Bases, Ignitable Wastes, Solvents
EQUIMENT REPAIR
Acids/Bases, Ignitable Wastes, Lead Acid
Batteries, Solvents
FURNITURE/WOOD MANUFACTURING
& REFINISHING
Ignitable Wastes, Solvents
OTHER MANUFACTURING (textiles.
plastics, leather)
Heavy Metals/Inorganics, Solvents
LAUNDRIES AND DRY CLEANERS
Dry Cleaning Filtration, Residues,
Solvents
EDUCATIONAL AND VOCATIONAL
SHOPS
Acids/Bases, Ignitable Wastes, Pesticides,
Reactives, Solvents
VEHICLE MAINTENANCE
Acids/Bases, Heavy Metals/Inorganics,
Ignitable Wastes, Lead Acid Batteries,
Solvents
WOOD PRESERVING
Preserving Agents
MOTOR FREIGHT TERMINALS AND
RAILROAD
Acids/Bases, Transportation, Heavy
Metals/Inorganics, Ignitable Wastes, Lead
Acid Batteries, Solvents
FUNERAL SERVICES
Solvents (formaldehyde)
METAL MANUFACTURING
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Reactives, Solvents, Spent Plating Wastes
CHEMICAL MANUFACTURERS
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Reactives, Solvents
CLEANING AGENTS AND COSMETICS
Acids/Bases, Heavy Metals/Inorganics,
Ignitable Wastes, Pesticides, Solvents
FORMULATORS
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Pesticides, Reactives, Solvents
BUILDING CLEANING AND
MAINTENANCE
Acid/Bases, Solvents
Page 1-i
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Notification of Regulated Waste Activity
Appendix 2
Typical Waste Streams and EPA Hazardous Waste Numbers
ACIDS/BASES:
Acids, bases or mixtures having a pH less than or equal to 2 or greater than or equal to
12.5, or liquids that corrode steel at a rate greater than 0.25 inches per year, are
considered to be corrosive (for a complete description of corrosive wastes, see 40 CFR
261.22, Characteristic of Corrosivity). All corrosive materials and solutions have the EPA
Hazardous Waste Number of D002. The following are some examples of the more
commonly used corrosives:
Examples of Corrosive Waste Streams
Acetic Acid
Ammonium Hydroxide
Chromic Acid
Hydrobromic Acid
Hydrochloric Acid
Hydrofluoric Acid
Nitric Acid
Oleum
Perchloric Acid
Phosphoric Acid
Potassium Hydroxide
Sodium Hydroxide
Sulfuric Acid
DRY CLEANING FILTRATION RESIDUES:
Cooked powder residue (perchloroethylene plants only), still residues and spent cartridge
filters containing perchloroethylene or valclene are hazardous and have an EPA
Hazardous Waste Number of F002.
Still residues containing petroleum solvents with a flash point less than 140F are also
considered hazardous, and have an EPA Hazardous Waste Number of D001.
HEAVY METALS/INORGANICS:
Heavy Metals and other inorganic waste materials exhibit the characteristic of TCLP
Toxicity and are considered hazardous if the extract from a representative sample of the
waste has any of the specific constituent concentrations as shown in 40 CFR 261.24,
Table 1. This may include dusts, solutions, wastewater treatment sludges, paint wastes,
waste inks and other such materials which contain heavy metals/inorganics (note that
wastewater treatment sludges from electroplating operations containing nickel and
cyanide, are identified as F006). The following are TCLP Toxic:
Waste Stream
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
EPA Hazardous Waste
Number
D004
D005
D006
D007
D008
D009
D010
D011
Page 2-i
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Notification of Regulated Waste Activity
Appendix 2 (continued)
IGNITABLE WASTES:
Ignitable wastes include any flammable liquids, nonliquids, and contained gases that
have a flashpoint less than 140F (for a complete description of ignitable wastes, see 40
CFR 261.21, Characteristic of Ignitability). Examples are spent solvents (see also
solvents), solvent still bottoms, ignitable paint wastes (paint removers, brush cleaners
and stripping agents), epoxy resins and adhesives (epoxies, rubber cements and marine
glues), and waste inks containing flammable solvents. Unless otherwise specified, all
ignitable wastes have an EPA Hazardous Waste Number of D001.
Some commonly used ignitable compounds are:
Waste Stream
Acetone
Benzene
n-Butyl Alcohol
Chlorobenzene
Cychlohexanone
Ethyl Acetate
Ethylbenzene
Ethyl Ether
Ethylene Bichloride
Methanol
Methyl Isobutyl Ketone
Petroleum Distillates
Xylene
EPA Hazardous Waste
Number
F003
D001
F003
F002
F003
F003
F003
F003
D001
F003
F003
D001
F003
INK SLUDGES CONTAINING CHROMIUM AND LEAD:
This includes solvent washes and sludges, caustic washes and sludges, or waster washes
and sludges from cleaning tubs and equipment used in the formulation of ink from
pigments, driers, soaps, and stabilizers containing chromium and lead. All ink sludges
have an EPA Hazardous Waste Number of K086.
LEAD ACID BATTERIES:
Used lead acid batteries should be reported on the notification form only if they are not
recycled. Used lead acid batteries that are recycled do not need to be counted in
determining the quantity of waste that you generate per month, nor do they require a
hazardous waste manifest when shipped off your premises. (Note: Special requirements
do apply if you recycle your batteries on your own premises - see 40 CFR Part 266.)
Waste Stream
Lead Dross
Spent Acids
Lead Acid Batteries
EPA Hazardous Waste
Number
D008
D002
D008, D002
Page 2-ii
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Notification of Regulated Waste Activity
Appendix 2 (continued)
ORGANIC WASTES:
See Section VTV, Table 1 - Maximum Concentration of Contaminants for the Toxicity
Characteristic for a list of constituents and regulatory levels.
PESTICIDES:
Pesticides, pesticide residues, washing and rinsing solutions and dips which contain
constituent concentrations at or above Toxicity Characteristic regulatory levels (see
Section VTV) are hazardous wste. Pesticides that have an oral LD50 toxicity (rat) < 50
mg/kg, inhalation LC50 toxicity (rat) < 2 mg/L or a dermal LD 50 toxicity (rabbit)
< 200 mg/kg, are hazardous materials. The following pesticides would be hazardous
waste if they are technical grade, unused and disposed. For a more complete listing, see
40 CFR 261.32-33 for specific listed pesticides, discarded commercial chemical products,
and other wastes, wastewaters, sludges, and by products from pesticide production.
(Note that while many of these pesticides are no longer in common use, they are Included
here for those cases where they may be found in storage.)
Waste Stream
Aldicarb
Aldrin
Amitrole
Arsenic Pentoxlde
Arsenic Trioxide
Cacodylic Acid
Carbamic Acid, Methylnitroso-
Ethyl Ester
Chlordane
Copper Cyanides
1,2-Dibromo-3-Chloropropane
1,2-Dichloropropane
1,3-Dichloropropene
2,4-Dichlorophenoxy Acetic Acid
DDT
Dieldrin
Dimethoate
Dimethylcarbamoyl Chloride
Dinitrocresol
Dinoseb
Disodium Monmomethane arsonate
Disulfoton
Endosulfan
Endrin
Ethylmercuric Chloride
Famphur
Nepthachlor
Hexachlorobenzene
EPA Hazardous Waste
Number
P070
P004
U011
P011
P012
U136
U178
U036
P029
U066
U083
U084
U240
U061
P037
P044
U097
P047
P020
D004
P039
P050
P051
D009
P097
P059
U127
Page 2-iii
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Notification of Regulated Waste Activity
Appendix 2 (continued)
Waste Stream
Kepone
Lindane
2-Methoxy Mercuric Chloride
Methoxychlor
Methyl Parathion
Monosodium Methanearsonate
Nicotine
Parathion
Pentachloronitrobenzene
Pentachlorophenol
Phenylmercuir Acetate
Phorate
Strychnine
2,4,5-Trichlorophenoxy Acetic Acid
2-(2,4,5-Trichlorophenoxy)-Propionic Acid
Thallium Sulfate
Thiram
Toxaphene
Warfarin
EPA Hazardous Waste
Number
U142
U129
D009
D014
P071
D004
P075
P089
U185
U242
D009
P094
PI 08
U232
U233
P115
U244
P123
U248
SOLVENTS:
Spent solvents, solvent still bottoms or mixtures containing solvents are often hazardous.
This includes solvents used in decreasing and paint brush cleaning, and distillation
residues from reclamation. The following are some commonly used hazardous solvents
(see also ignitable wastes for other hazardous solvents, and 40 CFR 261.31 for most
listed hazardous waste solvents):
Waste Stream
Benzene
Carbon Disulflde
Carbon Tetrachloride
Chlorobenzene
Cresols
Cresylic Acid
O-Dichlorobenzene
Ethanol
Ethylene Dichloride
Isobutanol
Isopropanol
Kerosene
Methyl Ethyl Ketone
EPA Hazardous Waste
Number
D001
F005
F001
F002
F004
F004
F002
D001
D001
F005
D001
D001
F005
Page2-iv
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Notification of Regulated Waste Activity
Appendix 2 (continued)
Waste Stream
Methylene Chloride
Naphtha
Nitrobenzene
Petroleum Solvents (Flash-
point less than 14OF)
Pyridine
1,1, 1-Trichloroethane
Tetrachloroethylene
Toluene
Trichloroethylene
Trie hlorofluoromethane
Trichlorotrifluoroethane
White Spirits
EPA Hazardous Waste
Number
F001 (Sludges)
F002(Still Bottoms!
D001
FO04
D001
F005
F001 (Sludges)
F002(Still Bottoms)
F001 (Sludges)
F002 (Still Bottoms)
F005
F001 (Sludges)
F002(Stlll Bottoms)
F002
F002
DO01
REACTIVES:
Reactive wastes include reactive materials or mixtures which are unstabe, react violently
with or form explosive mixtures with water, generate toxic gases or vapors when mixed
with water (or when exposed to pH conditions between 2 and 12.5 in the case of cyanide
or sulflde bearing wastes), or are capable of detonation or explosive reaction when
irritated or heated (for a complete description of reactive wastes, see 40 CFR 261.23,
Characteristic of reactivity). Unless otherwise specified, all reactive wastes have an EPA
Hazardous Waste Number of D003. The following materials are commonly considered to
be reactive:
Waste Stream
Acetyl Chloride
Chromic Acid
Cyanides
Organic Peroxides
Perchlorates
Permanganates
Hypochlorites
Sulfldes
EPA Hazardous Waste
Number
D003
D003
D003
D003
D003
D003
D003
D003
Page 2-v
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Notification of Regulated Waste Activity
Appendix 2 (continued)
SPENT PLATING AND CYANIDE WASTES:
Spent plating wastes contain cleaning solutions and plating solutions with caustics,
solvents, heavy metals and cyanides. Cyanide wastes may also be generated from heat
treatment operations, pigment production and manufacturing of anti-caking agents.
Plating wastes are generally Hazardous Waste Numbers F006-F009. Heat treatment
wastes are generally Hazardous Waste Numbers F010-F012. See 40 CFR 261.31 for a
more complete description of plating wastes.
WOOD PRESERVING AGENTS:
Compounds or mixtures used in wood preserving, including the wastewater treatment
sludge from wastewater treatment operations, are considered hazardous. Bottom
sediment sludges from the treatment of wastewater processes that use creosote or
pentachlorophenol are hazardous, and have an EPA Hazardous Waste Number of K001.
Unless otherwise indicated, specific wood preserving components are:
Waste Stream
Chromated Copper Arsenate
Creosote
Pentachlorophenol
EPA Hazardous Waste
Number
D004
K001
K001
Page 2-vi
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