United States              Office of Solid Waste
              Environmental Protection       (5301)
              Agency                  Washington, DC 20460        November 1993

              Solid Waste	__


&EPA   Notification of Regulated Waste Activity
              EPA Form 8700-12 (Rev. 11/30/93) Previous editions are obsolete.

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         United States Environmental Protection Agency
                                    Washington, D.C. 20460

                  Notification off Regulated Waste Activity
                                     Forms and Instructions
TJhis package is designed to help you determine if you are subject to the
regulations under the Resource Conservation and Recovery Act (RCRA)
and, if so% to help you notify EPA or your authorized State of your
regulated waste activities and get a U.S. EPA Identification Number.
RCRA is a Federal law. If yqu are regulated but do not comply with the
RCRA notification requirements, you may be subject to civil penalties.
The following materials are contained in the indicated sections of this
booklet

I.    Guidance on how to determine if you handle a hazardous waste
     that is regulated under RCRA;

II.   Guidance on how to determine if your waste activities are regulated
     under U.S. EPA's Waste-As-Fuel provisions;

III.  Guidance on how to determine if you must notify EPA of your used
     t)il recycling activities;

IV.  Guidance on how to file the Notification Form and a list of
     contacts, alphabetized by State, where you can get information,
     obtain more forms, and send your completed form;

V.   Two copies of EPA Form 8700-12: "Notification of Regulated Waste
     Activity" and complete line by line instructions for filling out the
      Notification form;

VI.  A list of definitions to help in understanding and completing the
      Notification Form;
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Notification of Regulated Waste Activity
VII.  Guidance on EPA hazardous waste numbers for waste streams
     commonly generated by small quantity generators, Appendix 1:
     "Typical Waste Streams Produced by Small Quantity Generators"
     and Appendix 2: "Typical Waste Streams and EPA Hazardous
     Waste Numbers;" and

VIII. A reprint of Part 261 (July 1, 1993) from Title 40 of the Code of
     Federal Regulations (CFR). This document contains the regulations
     that U.S. EPA has developed, identifying and listing hazardous
     waste.

To obtain a copy of 40 CFR Part 266 which discusses the waste-as-fuel
administrative standards, contact your EPA Regional Office listed later in
this package, or call the RCRA/Superfund Industry Assistance Hotline
at 1-800-424-9346 (or in the Washington, D.C. area at (703) 412-9810).
After your completed notification is received, you will be sent a written
acknowledgment that will include your U.S. EPA Identification Number.
You must use this number on all communications with U.S. EPA
regarding your activities.

It is important for you to understand that this package only addresses
the requirements of the Federal hazardous waste and  used oil programs.
Many States may have requirements that are different from the Federal
requirements; those States may use this form or a similar form which
may require additional information not required on this form.  It is up to
you, as the waste handler, to learn about all the requirements that affect
you.

Finally, we know that understanding these regulations and how they
affect your business is not an easy job. In Section IV of the instructions,
we have listed the addresses and phone numbers of the contacts for
each State who can answer your questions and help you understand the
Federal and State regulations that apply to you. In addition to those
contacts, the following contacts are also available to help with your
questions:

A.   RCRA/Superfund Industry Assistance Hotline -- 1-800-424-9346
     (If you are located in the Washington, D.C. area call (703)
     412-9810)

B.   EPA Small Business Ombudsman Hotline - 1-800-368-5888

C.   Your Trade Association
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                                         Notification of Regulated Waste Activity
I.    How to Determine if You Handle a

     Regulated  Hazardous Waste

Persons who generate, transport, treat, store, or dispose of solid wastes
are responsible for determining if their solid waste is a hazardous waste
regulated under the Resource Conservation and Recovery Act (hereafter
referred to as RCRA).  In addition, persons who recycle secondary
materials must also determine  whether those materials are solid and
hazardous wastes under the provisions of RCRA. If you need help
making this determination after reading these instructions, contact the
addressee listed for your State  in Section IV. C. of these instructions.

You will need to refer to Title 40, Part 261 of the Code of Federal
Regulations (hereafter referred  to as CFR) to help you decide if the waste
you handle is regulated under  RCRA.1 Section VIII is a reprint of 40
CFR Part 261. To determine if you are regulated under RCRA, ask
yourself the following questions:

A.    Do I Handle A Solid Waste?

40 CFR 261.2 defines "solid waste" as any discarded material that is not
excluded under Section 261.4(a) or that is not excluded by variance
granted under Sections 260.30 and 260.31. A discarded material is any
material which is:

 1.    abandoned, as explained in §261.2(b); or
2.    recycled, as explained in  §261.2(c); or
3.    considered inherently waste-like as explained in §261.(c).

B.    Has My Solid Waste Been Excluded From The Regulations  Under
      Section 261.4?

The list of general exclusions can be found in 40 CFR 261.4.  If the solid
waste that you handle has been excluded, either by rule or special
variance, then you do not need to notify U.S. EPA for that waste.
    1 Many States have requirements that vary from the Federal regulations.  These
 State regulations may be more strict than the Federal requirements by identifying
 additional wastes as hazardous, or may not yet include all wastes currently regulated
 under RCRA. It is your responsibility to comply with all regulations that apply to you.
 For more information on State requirements, you are strongly urged to contact the
 appropriate addressee listed for your State in Section IV of these instructions.
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Notification of Regulated Waste Activity
If your solid waste was not excluded from regulation, you need to
determine if it is a hazardous waste that U.S. EPA regulates. The U.S.
EPA regulates hazardous waste two ways:

1.   by specifically listing the waste and assigning it a unique EPA
     Waste Code Number; or

2.   by regulating it because it possesses any of four hazardous
     characteristics and assigning it a generic EPA Waste Code Number.

C.   Is My Solid Waste Specifically Listed as a Hazardous Waste?

Sections 261.31 -- 261.33 of 40 CFR identify certain solid wastes that
U.S. EPA has specifically listed as hazardous. Persons who handle listed
hazardous waste are subject to regulation and must notify U.S. EPA of
their activities unless they are exempted as discussed below. Refer to
this section of the CFR (enclosed as Section VIII) to see if your waste is
included as a "listed waste."

D.   Does My Solid Waste  Possess a Hazardous Characteristic?

Even if your waste is not specifically listed as a hazardous waste, it may
still be hazardous because it exhibits certain hazardous characteristics.
These  characteristics are:

1.   Ignitability;

2.   Corrosivity;

3.   Reactivity; and

4.   Toxicity.

Sections 261.20 through 261.24 of 40 CFR explain what each of the
characteristics is and outlines the testing procedures you should use to
determine if your waste meets these characteristics. Persons who handle
characteristic waste that is regulated must notify U.S. EPA of their
activities unless they are exempted, as discussed below. If you are
handling a newly regulated waste and have already notified EPA prior to
that activity and already have an EPA Identification Number, no
re-notification is required.
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                                        Notification of Regulated Waste Activity
E.   Has My Hazardous Waste Been Exempted From The Regulations

The list of exemptions can be found in 261.5 and 261.6(a)(3) of 40 CFR.
If the hazardous waste that you handle has been exempted, then you do
not need to notify U.S. EPA for that waste.

II.   How To Determine if You Must Notify U.S.  EPA of

     Your Waste-as-Fuel Activities

Persons who market or burn hazardous waste (and any material
produced from or otherwise containing hazardous waste) for energy
recovery are required to notify U.S. EPA (or their State agency if the
State is authorized to operate its own hazardous waste program) and
obtain a U.S. EPA Identification Number unless they are exempt as
outlined below (see Subpart H of 40 CFR Part 266).  Hazardous waste is
considered to be burned for energy recovery if it is burned in a boiler or
industrial furnace that is not regulated as a hazardous waste incinerator
under Subpart O of 40 CFR Parts 264 or 265.

Even if you have previously notified U.S. EPA of hazardous waste
activities and have a U.S. EPA Identification Number, you must renotify
to identify your waste-as-fuel activities. (You do not have to renotify for
those activities you previously notified for, only for any newly regulated
activities.)  If you have previously notified, be sure to complete Item I
"First or Subsequent Notification," by marking an "X" in the box for
subsequent notification.  Fill in your U.S. EPA Identification Number in
the spaces provided. (Your U.S. EPA Identification Number will not
change.)

Who is exempt from hazardous waste-as-fuel notification
requirements?

 1.    Ordinary generators (and initial transporters): Generators (and
      initial transporters who pick up hazardous waste from generators)
      are not marketers  subject to the notification requirement if they
      do not market hazardous waste fuel directly to a burner. In
      such situations, it is the recipient of that fuel who makes the
      decision to market the materials as a fuel, (typically after
      processing or blending), and it is the recipient who must notify.

 2.    Specific exemptions provided by 4O CFR 261.6:  The rules
      provide conditional exemptions for several specific waste-derived
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Notification of Regulated Waste Activity
     fuels under 261.6(a)(3), including fuels produced by petroleum
     refineries that recycle refinery hazardous waste, and coke and coal
     tar derived from coal coking wastes by the iron and steel industry.
     Marketers and burners of these exempted fuels are not subject to
     the notification requirement.

111.  How to  Determine if You Must Notify  U.S. EPA of

     Your Used Oil Recycling Activities

Persons who transport, process, re-refine, market or burn off-
specification used oil for energy recovery are required to notify U.S. EPA
(or their State agency if the State is authorized to operate its own
hazardous waste program) and obtain a U.S. EPA Identification Number
unless they are exempt as outlined below (see 40 CFR Part 279).  Used
oil is considered to be burned for energy recovery if it is burned in an
industrial furnace, boiler, or hazardous waste incinerator subject to
regulation under Subpart O  of 40 CFR Parts 264 or 265.

Used oil transporters, off-specification burners, processors, re-refiners
and marketers who have not previously notified EPA of their hazardous
waste activities or notified under 40 CFR Part 266, Subpart E must
notify to identify their used oil recycling activities.

Who is exempt from used oil notification requirements?

 1.    Persons who burn on-specification used oil fuel: Used oil that is
      to be burned for energy recovery and that meets the specification
      provided under 40 CFR 279.11 is essentially exempt from the
      regulations.  However, the person who first claims that the used
      oil meets the specification is subject to notification as a used
      oil fuel marketer and certain other requirements (see 4O CFR
      Part 279, Subpart H). The burner of on-specification fuel is not
      required to notify.

 2.    Used oil generators are not subject to the notification
      requirements.

 3.    Used oil generators operating used-oil-fired space heaters:
      Persons who only burn used oil that they generate (or used oil
      received from household do-it-yourselfer used oil changers) in
      used-oil-fired space heaters are exempt from the notification
      requirement provided that the device is vented to the outdoors and
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                                        Notification of Regulated Waste Activity
     the device is not designed to have a capacity greater than 0.5
     million Btu/hour.

IV.  How to File  EPA Form 8700-12, "Notification of

     Regulated Waste Activity"

If your waste activity is regulated under RCRA, you must notify the U.S.
EPA of your regulated waste activities and obtain a U.S. EPA
Identification Number. You can satisfy both of these requirements by
completing and signing the enclosed notification form and mailing it to
the appropriate address listed in Part C of this section.

Per the Hazardous Waste Import Regulations, 40 CFR 262.60, foreign
generators should not apply for a Federal I.D. number. These regulations
state that when filling out a U.S. manifest, you must include the name
and address of the foreign generator, and the name and address and
EPA I.D. number of the importer. Please contact the U.S. firms involved
with your shipments and determine which firm will serve as the
importer.

If this is a subsequent notification, you need to complete Items I, II, IV,
VI, VII, VIV and X and any other sections that are being added to (i.e.,
newly regulated activities) or altered (i.e., installation contact). All other
sections may be left blank.

A.   How Many Forms Should I File?

A person who is subject to the hazardous waste regulations, used oil
regulations, and/or the waste-as-fuel regulations under RCRA should
submit one notification form per site or location. If you conduct
hazardous waste or used oil activities at more than one location, you
must submit a separate form for each location.  (If you previously notified
for hazardous waste activities and are now notifying for waste-as-fuel
activities at the same location, you must submit a second form, but your
U.S. EPA Identification Number will remain the same).

If you only transport hazardous waste and do not generate, market,
burn, treat, store, or dispose of these wastes, you may submit one form
which covers all transportation activities your company conducts. This
form should be sent to the appropriate address (listed in Part C) that
serves the State where your company has its headquarters or principal
place of business. However, if you are a transporter who also generates,
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Notification of Regulated Waste Activity
treats, stores, or disposes of hazardous wastes, you must complete and
submit separate notification forms to cover each location.

B.   Can I Request That This Information Be Kept Confidential?

All information you submit in a notification can be released to the
public, according to the Freedom of Information Act, unless it is
determined to be confidential by U.S. EPA pursuant to 40 CFR Part 2.
Since notification information is very general, the U.S. EPA believes it is
unlikely that any information in your notification could qualify to be
protected from release. However, you may make a claim of confidentiality
by printing the word "CONFIDENTIAL" on both sides of the Notification
Form and on any attachments.

EPA will  take action on the confidentiality claims in accordance with 40
CFR Part 2.

C.   Where Should I Send My Completed Form?

Listed alphabetically in Table 1 are the addresses and phone numbers of
the proper contacts in each State where you can get additional
information and more forms, and where you should mail your completed
forms. As shown in Table  1, U.S. EPA and many States have arranged
for the States to answer your questions and receive completed forms. In
a few instances, the workload is shared between U.S. EPA and  the State,
or handled by U.S. EPA alone. To avoid delay and confusion, follow the
directions for your State very carejully.
  Estimated Burden:   Public reporting burden for this collection of
  information is estimated to be 4.35 hours, including time for reviewing
  instructions, searching  existing data sources, gathering  and main-
  taining the data needed, and completing and reviewing the collection
  of information. Send comments regarding the burden estimate or any
  other aspect of this collection of information, including suggestions for
  reducing this burden, to Chief, Information Policy Branch,  2136, U.S.
  Environmental Protection Agency, 401 M St., S.W., Washington, D.C.
  20460; and to the Paperwork Reduction Project (2050-0028), Office of
  Management and Budget, Washington, D.C. 20503.
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                                               Notification of Regulated Waste Activity
                                    Table 1
                     Alphabetized State Listing of Contacts for
                   Obtaining and Submitting the Notification Form
Alabama
Obtain information or forms from, and mail
completed forms to:
Land Division
Alabama Department of
 Environmental Management
1751 Cong. Wm. L. Dickinson Drive
Montgomery, Alabama  36130
(205) 271-7730

Alaska
Obtain information or forms from:
Department of Environmental Conservation
41 OWilloughby Avenue, Suite 105
Juneau, Alaska 99801-1795
(9O7) 465-5ISO
Mail completed forms to:
U.S. EPA Region 10
Waste Management Branch, HW-105
1200 Sixth Avenue
Seattle,  Washington 98101
(206) 553-0151

American Samoa
Obtain information from:
Environmental Quality Commission
Government of American Samoa
Pago Pago, American Samoa 96799
Overseas Operator Commercial  call  (684)
Country Code 663-2304
Obtain  forms  from  and   mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074

Arizona
Obtain information or forms from:
Office of Waste Programs
Arizona Department of
 Environmental Quality
3033 N. Central Avenue
Phoenix, Arizona 85012
(602) 207-4108
MaiZ completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074

Arkansas
Obtain information or forms from, and mail
completed forms to:
Arkansas Department of Pollution
 Control and Ecology
8001 National Drive
P.O. Box 8913
Little Rock, Arkansas  72219-8913
(501) 570-2872

California
Obtain in/brmation or forms from, and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074

Colorado
Obtain information or forms from, and mail
completed forms to:
Colorado Department of Health
4300 Cherry Creek Drive, South
HMWMD-HWC-B2
Denver, Colorado 80222-1530
(303) 692-3300

Connecticut
Obtain information or forms from, and mail
completed forms to:
Hazardous Material Management Unit
Department of Environmental Protection
State Office Building
165 Capitol Avenue
Hartford, Connecticut 06106
(203) 566-4869
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Notification of Regulated Waste Activity
                               Table 1 (continued)
Delaware
Obtain in/brmatton orjbrms from, and mail
completed forms to:
Delaware Department of Natural Resources
  & Environmental Control
Division of Air and Waste Management
Hazardous Waste Management Branch
P.O. Box 1401, 89 Kings Highway
Dover, Delaware 19903
(302) 739-3689
(302) 739-3672

District  of Columbia
Obtain in/brmatton or forms from, and mail
completed forms to:
Department of Consumer and
  Regulatory Affairs
Environmental Regulation Administration
Hazardous Waste Branch
2100 Martin Luther King Jr. Ave., S.E.
Washington, D.C. 2002O
(202)404-1167

Florida
Obtain information orjbrms from, and mail
completed forms to:
Hazardous Waste Regulation Section
Department of Environmental Regulation
Twin Towers Office Building
2600 Blair Stone Road
Tallahassee, Florida 32399-2400
(904) 488-0300

Georgia
Obtain in/brmatton or forms from, and mail
completed forms to:
Land Protection Branch
Industrial and Hazardous
Waste Management Program
1154 East Tower
205 Butler Street, S.E.
Atlanta,  Georgia 30334
(404) 656-7802

Guam
Obtain in/ormationjrom:
Guam Environmental Protection Agency
Harmon Plaza
Complex Unit B-107
103 Orjas Street
Harmon, Guam 96911
Obtain  forms  from   and  mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415) 744-2074

Hawaii
Obtain in/ormationjTOm;
Hawaii Department of Health
Solid and Hazardous Waste Branch
Five Waterfront Plaza, Suite 250
500 Ala Moana Boulevard
Honolulu, Hawaii 96813
Obtain/orms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street H-3-4
San Francisco, California 94105
(415) 744-2074

Idaho
Obtain in/brmatton or forms from, and mail
completed forms to:
Department of Environmental Quality
 1410 N. Hilton, Third Floor
Boise, Idaho  83706
(208) 334-5879

Illinois
Obtain in/brmatfon or forms from, and mail
completed forms to:
Illinois Environmental Protection Agency
Division of Land Pollution Control
2200 Churchill Road
Springfield, Illinois 62706
(217) 785-8452
 Obtain in/brmation or forms from:
 Indiana Department of
  Environmental Management
 1O5 S. Meridian Street
 P.O. Box 60 15
 Indianapolis, Indiana  46225
 (317)232-8925
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                                               Notification of Regulated Waste Activity
                               Table 1 (continued)
MaH completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. Box A3587
Chicago, IL 60690
(312) 886-4001

Iowa
Obtain information or forms from, and mail
completed forms to:
U.S. EPA Region 7
RCRA Branch
Attn: WSTM/RCRA/IOWA
726 Minnesota Avenue
Kansas City, Kansas 66101
(913) 551-7646

Kansas
Obtain information or forms from, and mail
completed forms to:
Department of Health and Environment
Attn:  Hazardous Waste Section
Forbes Field, Building 740
Topeka, Kansas 66620
(913)296-1600

Kentucky
Obtain information or forms from, and mail
completed forms to:
Division of Waste Management
Department of Environmental Protection
Cabinet for Natural Resources
& Environmental Protection
Fort Boone Plaza, Bldg. #2
14 Reilly Road
Frankfort, Kentucky 40601
(502) 564-6716
Louisiana
Obtain information or forms from, and mail
completed forms to:
Louisiana Department of
 Environmental Quality
Department of Solid and Hazardous Waste
P.O. Box82178
Baton Rouge, Louisiana 70884-2178
(504) 765-0332

Maine
Obtain information or forms from, and mail
completed forms to;
Bureau of Oil and
 Hazardous Materials Control
Department of Environmental Protection
State House Station #17
Augusta, Maine 04333
(207) 289-2651

Maryland
Obtain information or forms from, and mail
completed forms to:
Maryland Department of the Environment
Waste Management Administration
Hazardous Waste Program
2500  Broening Highway
Baltimore, Maryland  21224
(410)631-3343
(410)  631-3344

Massachusetts
Obtain information or forms from, and mail
completed forms to:
Division of Solid and Hazardous Waste
Massachusetts Department of
 Environmental Protection
One Winter Street, 5th Floor
Boston,  Massachusetts  02108
(617) 292-5851

Michigan
Obtain information or forms from:
Waste Management Division
Michigan Department of Natural Resources
Box30241
Lansing, Michigan 48909
(517) 373-2730
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Notification of Regulated Waste Activity
                               Table 1 (continued)
Mail completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, IL 60604
(312) 886-4001

Minnesota
Obtain information or forms from:
Solid and Hazardous Waste Division
Minnesota Pollution Control Agency
520 Lafayette Road, North
St. Paul, Minnesota 55155
(612) 297-8330
Mail completed forms to:
U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, IL 60604
(312) 886-4001

Mississippi
Obtain information or forms from, and mail
completed forms to:
Department of Environmental Quality
Attn: Jerry Banks
P.O. Box 10385
Jackson, Mississippi  39289-0385
(601) 961-5171

Missouri
Obtain information or forms from, and mail
completed forms to:
Waste Management Program
Department of Natural Resources
Jefferson Building
205 Jefferson Street (13/14 floor)
P.O. Box 176
Jefferson City, Missouri 65102
(314) 751-3176

Montana
Obtain information or forms from, and mail
completed forms to:
Solid and Hazardous Waste Bureau
Department of Health and
 Environmental Sciences
Cogswell Building
Helena,  Montana 59620
(406) 444-1430
Nebraska
Obtain information or forms from, and mail
completed forms to:
Hazardous Waste Management Section
Department of Environmental Quality
State House Station
P.O. Box 98922
Lincoln, Nebraska 68509-8922
(402) 471-2186

Nevada
Obtain information or forms from:
Waste Management Program
Division of Environmental Protection
The Bureau of Waste
 Management Permits Branch
333 West Nye Lane
Carson City, NV  89710
(702) 687-5872
Mafl completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H-3-4
San Francisco, CA 94105
(415)  744-2074

New Hampshire
Obtain information or forms from, and mail
completed forms to:
Division of Public Health Services
Office of Waste Management
Bureau of Hazardous Waste
 Classification & Manifests
Department of Health and Welfare
Health and Welfare Building
6 Hazen Drive
Concord, New Hampshire 03301
(603)  271-2900

New Jersey
Obtain information from:
New Jersey Department of Environmental
 Protection and Energy
Bureau of Manifests and
 Information Systems
Hazardous Waste and Regulation Program
401 East State Street, CN-421
Trenton, New Jersey 08625-0421
(609) 292-8341
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                                               Notification of Regulated Waste Activity
                              Table 1 (continued)
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn:  RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212)264-9883

New Mexico
Obtain information and forms from:
Hazardous Waste Bureau
525 Camino De Loss Marquez
Sante Fe, New Mexico 87501
(505) 827-4358
Mail completed forms to:
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445  Ross Avenue, Suite 1200
Dallas, Texas  75202-2733
(214)  655-6750

New York
Obtain information from:
New York Department of
  Environmental Conservation
Solid  and Hazardous Waste
  Manifest Section
50 Wolfe Road
Albany, New York  12212
(518)457-6858
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn:  RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212)  264-9883

North Carolina
Obtain information or forms from, and mail
completed forms to:
Solid  and Hazardous Waste
  Management Branch
Division of Health Services
Department of Human Resources
P.O. Box 27687
Raleigh, North Carolina 27611-7687
(919)  733-2178
North Dakota
Obtain information or forms from, and mail
completed forms to:
Division of Waste Management
Department of Health and
 Consolidated Laboratories
1200 Missouri Avenue
P.O. Box 5520
Bismarck, North Dakota  58502-5520
(701) 221-5166

Northern Mariana Islands
Obtain information from:
Department of Public Health and
 Environmental Services
Division of Environmental Quality
Saipan, Mariana Islands  96950
Overseas Operator: (676) 234-6984
Cable Address: Gov. NMI Saipan
Obtain forms from and mail
completed forms to:
U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street, H:3-4
San Francisco, California 94105
(415)  744-2074

Ohio
Obtain information or forms from, and mail
completed forms to:
Ohio Environmental Protection Agency
1800  WaterMark Drive
Columbus, Ohio 43215
(614)  644-2977

Oklahoma
Obtain information or forms from:
Department of Environmental Quality
Hazardous Waste Quality
  Management Service
1000  Northeast 10th Street
Oklahoma City, Oklahoma 73117-1212
(405)  271-5338
Mail completed forms to:
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445  Ross Avenue, Suite 1200
Dallas, Texas 75202-2733
(214)  655-6750
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Notification of Regulated Waste Activity
                               Table 1 (continued)
Oregon
Obtain information or forms front, and mail
completed forms to:
Oregon Department of
 Environmental Quality
Hazardous Waste Operations
811 Southwest 6th Avenue
Portland, Oregon 972O4
(503) 229-5356

Pennsylvania
Obtain information from:
Pennsylvania Department of
 Environmental Resources
Bureau of Waste Management
Market Street State Office Building
400 Market Street, 14th Floor
Harrisburg, Pennsylvania 17105-8471
(717) 787-6239
Obtain forms from and mail
completed forms to:
U.S. EPA Region 3
RCRA Programs Branch
Pennsylvania Section (3 HW51)
841 Chestnut Street
Philadelphia, PA 19107
(215) 597-1230

Puerto Rico
Obtain information from:
Puerto Rico Environmental Quality Board
Land Pollution Control Area
Inspection, Monitoring and Surveillance
P.O. Box 11488
Santurce, Puerto Rico 00910-1488
(809) 722-0439
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Divison
Attn: RCRA Notifications
26 Federal Plaza. Room 505
New York, New York 1O278
(212) 264-9883
Rhode Island
Obtain information or forms from, and mail
completed forms to:
Solid Waste Management Program
Department of Environmental Management
204 Canon Building 75 Davis Street
Providence, Rhode Island  02908
(401) 277-2797

South Carolina
Obtain information or forms from, and mail
completed forms to:
Bureau of Solid and Hazardous
 Waste Management
Department of Health and
 Environmental Control
2600 Bull Street
Columbia, South Carolina 29201
(803) 734-5214

South Dakota
Obtain information or forms from, and mail
completed forms to:
Department of Environment and
  Natural Resources
Office of Waste Management
319Coteau
c/o 500  E. Capital Avenue
Pierre, South Dakota  57501-5070
(605) 773-3153

Tennessee
Obtain information or forms from, and mail
completed forms to:
Division of Solid Waste Management
Tennessee Department of Public Health
401 Church Street
LNC Tower, 5th Floor
Nashville, Tennessee 37243"-153 5
(615) 532-0780

Texas
Obtain information or forms Jrom:
Industrial and Hazardous Waste Division
Waste Evaluation Section
P.O. Box 13087, Capitol Station
Austin, Texas  78711-3087
(512) 908-6832
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                                               Notification of Regulated Waste Activity
                               Table 1 (continued)
Mai! completed forms to;
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, Texas  75202-2733
(214) 655-6750

Utah
Obtain information or forms from, and mail
completed forms to:
Division of Solid and Hazardous Waste
Department of Environmental Quality
P.O. Box 144880
Salt Lake City, Utah 84114-4880
(801) 538-6170

Vermont
Obtain information or forms from, and mail
completed forms to:
Waste Management Division
Agency of Environmental Conservation
103 South Main Street
Waterbury, Vermont 05676
(802)241-3888

Virgin Islands
Obtain information from:
Virgin Islands Department of Planning &
Natural Resources
Division of Environmental Protection
179 Altona and Welgunst
St. Thomas, Virgin Islands 00801
(809) 774-3320
Obtain forms from and mail
completed forms to:
U.S. EPA Region 2
Air and Waste Management Division
Attn:  RCRA Notifications
26 Federal Plaza, Room 505
New York, New York  10278
(212)264-9883

Virginia
Obtain information or forms from, and mail
completed forms to:
Virginia Department of Waste Management
Monroe Building, 1 Hh Floor
101 North 14th Street
Richmond, Virginia  23219
(804) 225-3863
Washington
Obtain information or forms from, and mail
completed forms to:
Department of Ecology
P.O. Box 47658
Olympia, Washington 98504-7658
(206) 459-6316

West Virginia
Obtain information or forms from, and mail
completed forms to:
Department  of  Commerce,  Labor  and
Environmental Protection
Division of Environmental Protection
Office of Waste Management
1356 Hansford Street
Charleston, West Virginia 25301
(304) 558-5393

Wisconsin
Obtain information or forms from:
Bureau of Solid Waste
Department of Natural Resources
P.O. Box 7921
Madison, Wisconsin 53707
(608)266-1327
Mail completed farms to:
U.S. EPA Region 5
RCRA Activities
P.OBoxA3587
Chicago, IL 60690
(312)  886-4001

Wyoming
Obtain information or forms from, and mail
completed forms to:
U.S. EPA Region 8
Hazardous Waste  Management  Division
(8HWM-ON)
999 18th Street Suite 500
Denver, Colorado 80202-2405
(303)  294-1361
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Notification of Regulated Waste Activity
                                    Table 2
                U.S. EPA Regional Contacts for the Notification Form
U.S. EPA Region 1
RCRA Support Section
JFK Federal Building
Boston, MA 02203-2211
(617) 573-5750
        Connecticut, Maine,
        Massachusetts, New Hampshire,
        Rhode Island, Vermont

U.S. EPA Region 2
Air and Waste Management Division
Attn: RCRA Notifications
26 Federal Plaza, Room 505
New York, NY 10278
(212)264-9883
        New Jersey, New York, Puerto
        Rico, Virgin Islands

U.S. EPA Region 3
RCRA Programs Branch (3 HW50)
841 Chestnut Street
Philadelphia, PA 19107
(215) 597-1230 (PA, DC)
(215) 597-3884 (VA, WV, DE, MD)
        Delaware, District of Columbia,
        Maryland, Pennsylvania, Virginia,
        West Virginia

U.S. EPA Region 4
Hazardous Waste Management Division
RCRA Permitting Section
345 Courtland Street, NE
Atlanta, GA 30365
(404) 347-3433
        Alabama. Florida, Georgia,
        Kentucky, Mississippi, North
        Carolina, South Carolina,
        Tennessee

U.S. EPA Region 5
RCRA Activities
P.O. BoxA3587
Chicago, 1L 60690
(312) 886-4001
        Illinois, Indiana, Michigan,
        Minnesota, Ohio, Wisconsin
U.S. EPA Region 6
Hazardous Waste Management Division
First Interstate Bank Tower
1445 Ross Avenue, Suite 1200
Dallas, TX 75202-2733
(214) 655-6750
       Arkansas, Louisiana, New Mexico,
       Oklahoma, Texas

U.S. EPA Region 7
RCRA Branch, Permitting Section
726 Minnesota Avenue
Attn:  WSTIN/RCRA/PRMT
Kansas City, KS 66101
(913) 551-7654
       Iowa, Kansas, Missouri, Nebraska

U.S. EPA Region 8
Hazardous Waste Management Division
999 18th Street, Suite 500
Denver, CO 80202-2405
(303) 294-1361
        Colorado, Montana, North Dakota,
        South Dakota, Utah, Wyoming

U.S. EPA Region 9
Hazardous Waste Management Division
75 Hawthorne Street H-3-4
San Francisco, CA 94105
(415) 744-2074
        Arizona, California, Hawaii,
        Nevada, American Samoa, Guam,
        Northern Mariana Islands

U.S. EPA Region 10
Waste Management Branch, HW-105
1200 Sixth Avenue
Seattle, WA 98101
(206) 553-0151
        Alaska, Idaho, Oregon,
        Washington
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                                        Notification of Regulated Waste Activity
V.   Line-by-Line Instructions for Completing EPA Form

     8700-12

Type or print in black ink all items except Item X, "Signature,"  leaving a
blank box between words. The boxes are spaced at 1/4" intervals which
accommodate elite type (12 characters per inch). When typing, hit the
space bar twice between characters. If you print, place each character in
a box. Abbreviate if necessary to stay within the number of boxes
allowed for each Item. If you must use additional sheets, indicate clearly
the number of the Item on the form to which the information on the
separate sheet applies.

Note: When submitting a subsequent notification form, notifiers must
complete in their entirety Items I, II, IV, VI, VII, VTV and X. Other
sections that are being added to (i.e., newly regulated activities) or
altered (i.e.,  installation contact) must also be completed. All other
sections may be left blank.

Item I - Installations EPA ID Number:

Place an "X" in the appropriate box to indicate whether this is your first
or a subsequent notification for this site. If you have filed a previous
notification, enter the EPA Identification Number assigned to this site in
the boxes provided. Leave EPA ID Number blank if this is your first
notification for this site.

Note: When the owner of an installation changes, the new owner must
notify U.S. EPA of the change, even if the previous owner already
received a U.S. EPA Identification Number. Because the  U.S. EPA ID
Number is site-specific, the new owner will keep the existing ID number.
If the installation moves to another location, the owner/operator must
notify EPA of this change. In this instance a new U.S. EPA Identification
Number will be assigned, since the installation has changed locations.

Items II and IV -- Name and Location of Installation:

Complete Items II and IV. Please note that the address you give for Item
IV, Location of Installation, must be  a physical address, not a post office
box or route number.
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Notification of Regulated Waste Activity
County Code and Name: Give the county code, if known.  If you do not
know the county code, enter the county name, from which EPA can
automatically generate the county code.  If the county name is unknown
contact the local Post Office. To obtain a list of county codes, contact
the National Technical Information Service U.S. Department of
Commerce, Springfield, Virginia, 22161 or at (703) 487-4650. The list of.
codes is contained in the Federal Information Processing Standards
Publication (FIPS PUB) number 6-3.

Item IV - Installation Mailing Address:

Please enter the Installation Mailing Address. If the Mailing Address and
the Location of Installation (Item IV) are the same, you can print "Same"
in the box for Item IV.

Item V - Installation Contact:

Enter the name, title, and business telephone number of the person who
should be contacted regarding information submitted on this form.

Item VI - Installation Contact Address:

A.   Code: If the contact address is the same as the location of
     installation address listed in Item IV or the installation mailing
     address listed in Item IV, place an "X"  in the appropriate box to
     indicate where the contact may be reached.  If the location of
     installation address, the installation mailing address, and the
     installation contact address are all the same, mark the "Location"
     box. If the contact address is not the same as those addresses in
     either Item III or IV, place an "X" in the "Other" box and complete
     Item VLB. If an "X" is entered in either the location or mailing box,
     Item VLB. should be left blank.

B.   Address:  Enter the contact address only if the contact address is
     different from either the location of installation address (Item IV) or
     the installation mailing address (Item IV), and if Item VI.A. was
     marked "Other."
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                                         Notification of Regulated Waste Activity
Item VII - Ownership:

A.   Name: Enter the name of the legal owner(s) of the installation,
     including the property owner. Also enter the address and phone
     number where this individual can be reached. Use the comment
     section in XI or additional sheets if necessary to list more than one
     owner.

B.   Land Type: Using the codes listed below, indicate in VII.B. the
     code which best describes the current legal status of the land on
     which the installation is located:
     F   =   Federal
     S   =   State
     1   =   Indian
     P   =   Private
     C   =   County
     M  =   Municipal*
     D   =   District
     O   =   Other
     *Note: If the Owner Type is best described as Indian, County or
     District, please use those codes. Otherwise, use Municipal

C.   Owner Type: Using the codes listed below, indicate in VII. C. the
     code which best describes the legal status of the current owner of
     the installation:
     F   =   Federal
     S   =   State
     I   =   Indian
     P   =   Private
     C  =   County
     M  =   Municipal*
     D  =   District
     O  =   Other
     *Note: If the Owner Type is best described as Indian, County or
     District, please use those codes. Otherwise, use Municipal

D.   Change of Owner Indicator: (If this is your installations jirst
     notification, leave Item VII. D. blank and skip to Item VIII. If this  is a
     subsequent notification,  complete Item VII.D. as directed below.)

     If the owner of this installation  has changed since the installation's
     original notification, place an "X" in the box marked "Yes" and enter
     the date the owner changed.
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Notification of Regulated Waste Activity
     If the owner of this installation has not changed since the
     installation's original notification, place an "X" in the box marked
     "No"  and skip to Item VIII.

     If an additional owner(s) has been added or replaced since the
     installation's original notification, place an "X" in the box marked
     "Yes." Use the comment section in XI to list any additional owners,
     the dates they became owners, and which owner(s) (if any) they
     replaced. If necessary attach a separate sheet of paper.

Item VIII -  Type of Regulated Waste Activity:

A.   Hazardous Waste Activity: Mark an "X" in the appropriate box(es)
     to show which hazardous waste activities are going on at this
     installation.

     1.  Generator: If you generate a hazardous waste that is identified
         by characteristic or listed in 40 CFR Part 261, mark an "X" in
         the appropriate box for the quantity of non-acutely hazardous
         waste that is generated per calendar month. If you generate
         acutely hazardous waste please refer to 40 CFR Part 262 for
         further information.

     2.  Transporter: If you transport hazardous waste, indicate if it is
         your own waste, for commercial purposes, or mark both boxes
         if both classifications apply. Mark an "X" in each appropriate
         box  to indicate the method(s) of transportation you use.
         Transporters do not have to complete Item IX of this form, but
         must sign the certification in Item X. The Federal regulations
         for hazardous waste transporters are found in 40 CFR
         Part 263.

     3.  Treater/Storer/Disposer:  If you treat, store or dispose of
         regulated hazardous waste, then mark an "X" in this box. You
         are reminded to  contact the appropriate addressee listed for
         your State in Section III.C. of this package to request Part A of
         the RCRA Permit Application. The Federal regulations for
         hazardous waste installation owners/operators  are found in 40
         CFR Parts 264 and 265.

     4.  Hazardous Waste Fuel: If you market hazardous waste fuel,
         place an "X" in the appropriate box(es). If you burn hazardous
         waste fuel on-site, place an "X" in the appropriate box and
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                                         Notification of Regulated Waste Activity
         indicate the type(s) of combustion devices in which hazardous
         waste fuel is burned. (Refer to the definition section for
         complete descriptions of each device).

         Note: Generators are required to notify for waste-as-fuel
         activities only if they market directly to the burner.

         "Other Marketer" is defined as any person,  other than a
         generator marketing hazardous waste, who markets hazardous
         waste fuel.

     5.   Underground Injection Control:  If you generate and/or treat,
         store or dispose of hazardous waste, place an "X" in the box if
         an injection well is located at your installation. "Underground
         Injection" means the subsurface emplacement of fluids
         through a bored, drilled or driven well; or through a dug well,
         where the depth of the dug well is  greater than the largest
         surface dimension.

B.   Used Oil Recycling Activities: Mark an "X" in the appropriate
     boxfes) to indicate which used oil recycling activities are taking
     place at this installation.

     1.   Used Oil Fuel Marketer:  If you market off-specification used
         oil, mark an "X" in box la. If you are the first to claim the
         used oil meets the used oil specification established in 40 CFR
         Part 279.11,  mark an "X" in box Ib. If either of these boxes
         are marked, you must also notify (or have previously notified}
         as a used oil transporter, off-specification used oil fuel burner,
         or used oil processor/re-refiner, unless  you are a used oil
         generator. (Used oil generators are not  required to notify.)

     2.   Used Oil Burner:  If you burn off-specification used oil fuel,
         place an "X" in the box(es) to indicate the type(s) of combustion
         device(s) in which off-specification used oil fuel is burned.
         (Refer to the definition section for complete descriptions of
         each device.)

     3.   Used Oil Transporter:  If you transport used oil and/or
         own/operate a  used oil transfer facility, place an "X" in the
         appropriate boxfes) to indicate this used oil recycling activity.
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Notification of Regulated Waste Activity
     4.  Used Oil Processor/Re-refiner: If you process and/or re-
         refine used oil, place an "X" in the appropriate box(es) to
         indicate this used oil activity.

Item IX - Description of Hazardous Wastes:

Note: Only persons involved in hazardous waste activity (Item VIII.A.)
need to complete this item. Transporters requesting a U.S. EPA
Identification Number do not need to complete this item, but must sign
the "Certification" in Item X.

You will  need to refer to 40 CFR Part 261 (enclosed as Section VII) in
order to  complete this section. Part 261 identifies those wastes that  EPA
defines as hazardous. If you need help completing this section, please
contact the appropriate addressee for your State as listed in Section IV.
C. of this package.

A.   Characteristics of Nonlisted Hazardous Wastes: If you handle
     hazardous wastes which are not listed in 40 CFR Part 261,
     Subpart D, but do exhibit a characteristic of hazardous waste  as
     defined in 40 CFR Part 261, Subpart C, you should describe these
     wastes by the EPA hazardous waste number for the characteristic.
     Place an "X" in the box next to the characteristic of the wastes that
     you handle. If you mark "4. Toxicity Characteristic," please list the
     specific EPA hazardous waste number(s) for the specific
     contaminant(s) in the box(es) provided. Refer to Section VTV to
     determine the appropriate hazardous waste number(s).

B.   Listed Hazardous Wastes: If you handle hazardous wastes that
     are listed in 40 CFR Part 261,  Subpart D, enter the appropriate
     4-digit numbers in the boxes provided.

     Note: If you handle more than 12 listed hazardous wastes, please
     continue listing the waste codes on the extra sheet provided at the
     end of this booklet. If it is used, attach the additional page to the
     rest of the form before mailing it to the appropriate EPA Regional or
     State Office.

C.   Other Wastes: If you handle other wastes or State regulated wastes
     that have a waste code, enter the appropriate code number in  the
     boxes provided.
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                                        Notification of Regulated Waste Activity
Item X - Certification:

This certification must be signed by the owner, operator, or an
authorized representative of your installation. An "authorized
representative" is a person responsible for the overall operation of the
installation (i.e.,  a plant manger or superintendent, or a person of equal
responsibility). All notifications must include this certification to be
complete.

Item XI -- Comments:

Use this space for any additional comments.

VI.  Definitions

The following definitions are included to help you to understand and
complete the Notification Form:

Act or RCRA means the Solid Waste Disposal Act, as amended by the
     Resource Conservation and Recovery Act of 1976, as amended by
     the Hazardous and Solid Waste Amendments of 1984, 42 U.S.C.
     Section 6901 et seq.

Authorized Representative means the person responsible for the
     overall operation of the installation or an operational unit (i.e., part
     of a installation), e.g., superintendent or plant manager, or person
     of equivalent responsibility.

Boiler means an enclosed device using controlled flame combustion and
     having the following characteristics:

      1.   The unit has physical provisions for recovering and exporting
          energy in the form of steam, heated fluids, or heated gases;

     2.   The units combustion chamber and primary energy recovery
          section(s) are of integral design (i.e., they are physically formed
          into one manufactured or assembled unit);

     3.   The unit continuously maintains an energy recovery efficiency
          of at least 60 percent, calculated in terms of the recovered
          energy compared with the thermal value of the fuel;
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Notification of Regulated Waste Activity
     4.  The unit exports and utilizes at least 75 percent of the
         recovered energy, calculated on an annual basis (excluding
         recovered heat used internally in the same unit, for example,
         to preheat fuel or combustion air or drive fans or feedwater
         pumps); and

     5.  The unit is one which the Regional Administrator has
         determined on a case-by-case basis, to be a boiler after
         considering the standards in 40 CFR 260.32.

Burner means the owner or operator of any boiler or industrial furnace
     that bums hazardous waste fuel for energy recovery and that is not
     regulated as a RCRA hazardous waste incinerator.

Disposal means the discharge, deposit, injection, dumping, spilling,
     leaking, or placing of any solid waste or hazardous waste into or on
     any land or water so that such solid waste or hazardous waste or
     any constituent thereof may enter the environment or be emitted
     into the air or discharged into any waters, including ground
     waters.

Disposal Installation means a installation or part of a installation at
     which hazardous waste is intentionally placed into or on any land
     or water, and at which waste will remain after closure.

EPA Identification (I.D.) Number means the number assigned by EPA
     to each generator, transporter, and treatment, storage, or disposal
     installation.

Generator means any person, by site, whose act or process produces
     hazardous waste identified or listed in 40 CFR Part 261.

Hazardous Waste means a hazardous waste as defined in 40 CFR 261.3.

Hazardous Waste Fuel means hazardous waste and any fuel that
     contains hazardous waste that is burned for energy recovery in a
     boiler or industrial furnace that is not subject to regulation as a
     RCRA hazardous waste incinerator. However, the following
     hazardous waste fuels are subject to regulation as used oil fuels:

     1.  Used oil fuel burned for energy recovery that is also a
         hazardous waste solely because it exhibits a characteristic of
         hazardous waste identified in Subpart C of 40 CFR Part 261;
         and
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                                        Notification of Regulated Waste Activity
     2.   Used oil fuel mixed with hazardous wastes generated by a
         small quantity generator subject to 40 CFR 261.5.

Hazardous Waste Fuel Marketer is a person who markets hazardous
     waste fuel.  However, generators and initial transporters (i.e.,
     transporters who receive hazardous waste directly from generators
     including initial transporters who operate transfer stations) who do
     not market directly to persons who burn  the fuels are not subject
     to waste-as-fuel requirements (including  notification) under
     Subpart D of 40 CFR Part 266.

Industrial Boiler means a boiler located on the site of a installation
     engaged in a manufacturing process where substances are
     transformed into new products, including the component parts of
     products, by mechanical or chemical processes.

Industrial Furnace means any of the following enclosed devices that are
     integral components of manufacturing processes and that use
     controlled flame combustion to accomplish recovery of materials or
     energy: cement kilns, lime kilns, aggregate  kilns (including asphalt
     kilns),  phosphate kilns, coke ovens, blast furnaces, smelting
     furnaces, refining furnaces, titanium dioxide chloride process
     oxidation reactors, methane reforming furnaces, pulping liquor
     recovery furnaces, combustion devices used in  the recovery of
     sulfur values from spent  sulfuric acid, and other devices as the
     Administrator may add to this list.

Installation means all contiguous land, structures, other
     appurtenances, and improvements on the land, used for treating,
     storing, or disposing of hazardous waste. A installation may consist
     of several treatment, storage, or disposal operational units (e.g.,
     one or more landfills, surface impoundments, or combinations of
     them).

Municipality means a city, village, town, borough, county, parish,
     district, association, Indian tribe or authorized Indian tribal
     organization, designated  and approved management agency under
     Section 208 of the Clean  Water Act, or any other public body
     created by or under State law and having jurisdiction over disposal
     of sewage, industrial wastes, or other wastes.

Off-Specification Used Oil Fuel means used  oil fuel that does not meet
     the specification provided under 40 CFR 279.11.
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Notification of Regulated Waste Activity
On-Specification Used Oil Fuel means used oil fuel that meets the
     specification provided under 40 CFR 279.11.

Operator means the person responsible for the overall operation of a
     installation.

Owner means a person who owns a installation or part of a installation,
     including landowner.

Processing means chemical or physical operations designed to produce
     from used oil, or to make used oil more amenable for production of
     fuel oils, lubricants, or other used oil-derived product.  Processing
     includes, but is not limited to: blending used oil with virgin
     petroleum products, blending used oils to meet the fuel
     specification, filtration, simple distillation, and chemical or physical
     separation.

Small Quantity Exemption means small quantities of hazardous waste
     that are exempt from the requirements of 40 CFR 266.108.

Smelter Deferral means that the mandate in section 3000(g) to regulate
     facilities burning hazardous waste for energy recovery as may be
     necessary to protect human health and the environment does not
     apply to devices burning for the purpose of material recovery.

Storage means the holding of hazardous waste for a temporary period,
     at the end of which the hazardous waste is treated, disposed of, or
     stored elsewhere.

Transportation means  the movement of hazardous waste by air, rail,
     highway, or water.

Transporter means a person engaged in the off-site transportation of
     hazardous waste by air, rail, highway, or water.

Treatment means any method, technique, or process, including
     neutralization, designed to change the physical, chemical, or
     biological character or composition of any hazardous waste so as to
     neutralize such waste, or so as to recover energy or material
     resources from the waste, or so as to render such waste
     nonhazardous, or  less hazardous; safer to transport, store or
     dispose of; or amenable for recovery, amenable for storage, or
     reduced in volume. Such term includes any activity or processing
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                                        Notification of Regulated Waste Activity
     designed to change the physical form or composition of hazardous
     waste so as to render it nonhazardous.

Underground Injection Control means the subsurface emplacement of
     fluids through a bored, drilled or driven well; or through a dug
     well, where the  depth of the dug well is greater than the largest
     surface dimension.

Used Oil means any oil that has been refined from crude oil, or any
     synthetic oil, that has been used, and as a result of such use, is
     contaminated by physical or chemical impurities.

Used Oil Burner means a facility where used oil not meeting the
     specification requirements in 40 CFR 279.11 is burned for energy
     recovery in devices identified in Section 279.61 (a).

Used Oil Processor means a facility that processes on- or off-
     specification used oil.

Used Oil Recycling Activities,  for the purposes of this form, include
     used oil transportation, processing,  and re-refining; burning off-
     specification used oil fuel;  and used oil fuel marketing.

Used Oil Re-refiner is a person who produces lubricating oils and
     greases, industrial fuel, asphalt extender, gasoline, and other
     products from on- or off-specification used oil.

Used Oil Transfer Facility means any transportation related facility
     including loading docks, parking areas, storage areas, and other
     areas where shipments of used oil are held for more than 24 hours
     during the normal course  of transportation and not longer than 35
     days.  Transfer facilities that store used oil for more than 35 days
     are subject to regulation under 40 CFR Part 279, Subpart F.

Used Oil Transporter means any person who transports used oil, any
     person who collects used oil from more than one generator and
     transports the collected oil, and owners and operators of used oil
     transfer facilities. Used oil transporters may consolidate or
     aggregate loads of used oil for purposes of transportation but, with
     the following exception, may not process used oil. Transporters
     may conduct incidental processing operations that occur in the
     normal course of used oil  transportation (e.g., settling and water
     separation), but that are not designed to produce (or make more
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Notification of Regulated Waste Activity
     amenable for production of) used oil-derived products or used oil
     fuel.

Used Oil Fuel Marketer means any person who conducts either of the
     following activities:

     1.  Directs a shipment of off-specification used oil from their
         facility to a used oil burner; or

     2.  First claims that used oil that is to be burned for energy
         recovery meets the used oil fuel specifications set forth in 40
         CFR279.11.

Utility Boiler means a boiler that is used to produce electricity, steam or
     heated or cooled air or other gases or fluids for sale.

VII. EPA Hazardous Waste Numbers for Waste Streams

     Commonly Generated by  Small Quantity

     Generators

The Environmental Protection Agency recognizes that generators of small
quantities  of hazardous waste, many of which are small businesses, may
not be familiar with the manner in which hazardous waste materials are
identified in the  Code of Federal Regulations. This insert has been
assembled in order to aid small quantity generators in determining for
their wastes the EPA Hazardous Waste Numbers that are needed to
complete the "Notification of Regulated Waste Activity," Form 8700-12.

This insert is composed of two appendices. Appendix 1 lists eighteen
general industry categories that contain small quantity generators. For
each of these categories, commonly generated hazardous waste streams
are identified. Appendix 2 lists EPA Hazardous Waste Numbers for each
waste stream identified in Appendix 1.

To use this insert:

 1.   Locate your industry in Appendix 1 to identify the waste streams
     common to your activities.

2.   Find  each of your waste streams  in Appendix 2, and review the
     more detailed descriptions of typical wastes to determine which
     waste streams actually result from your activities.
 Page 28

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                                        Notification of Regulated Waste Activity
3.   If you determine that a waste stream does apply to you, report the
     4-digit EPA Hazardous Waste Number in Item IX, B. of Form
     8700-12, "Notification of Regulated Waste Activity."

The industries and waste streams described here do not provide a
comprehensive list but rather serve as a guide to potential small quantity
generators in determining which of their wastes, if any, are hazardous.
Except for the pesticide category, this insert does not include EPA
Hazardous Waste Numbers for commercial chemical products that are
hazardous when discarded unused. These chemicals and their EPA
Hazardous Waste Numbers are listed in 40 CFR 261.33.

If the specific Hazardous Waste Number that should be applied to your
waste stream is unclear, please refer to 40 CFR Part 261,  reprinted in
Section VIII of this notification package. In those cases where more than
one Hazardous Waste Number is applicable, all should be used. If you
have any questions,  or if you are unable to determine the proper EPA
Hazardous Waste Numbers for your wastes, contact your state
hazardous waste management agency as listed in Section IV of these
notification instructions, or the RCRA/Superfund Hotline at
1-800-44-9346 (or in the Washington, D.C. area at (703) 412-9810).
                                                             Page 29

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Notification of Regulated Waste Activity
VIII.    Reprint of Part 261 from Title 40 of the Code of
        Federal Regulations (July 1,1992).
Page 30

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Environmental Protection Agency
                               §261.1
  PART 261—IDENTIFICATION AND
  LISTING OF HAZARDOUS WASTE

           Subparl A—General

Sec.
261.1  Purpose and scope.
261.2  Definition of solid waste.
261.3  Definition of hazardous waste.
261.4  Exclusions.
261.5  Special  requirements  for hazardous
   waste   generated   by   conditionally
   exempt small quantity generators.
261.6  Requirements for recyclable materi-
   als.
261.7  Residues of  hazardous  waste  in
   empty containers.
261.8  PCB wastes  regulated under Toxic
   Substance Control Act.

Subparl B—Criteria for Identifying the Charac-
    teristics of Hazardous Waste and for List-
    ing Hazardous Wastes

261.10  Criteria for identifying the charac-
   teristics of hazardous waste.
261.11  Criteria for listing hazardous waste.

   Subpart C—Characteristics of Hazardous
                 Waste

261,20  General.
261.21  Characteristic of ignitability.
261.22  Characteristic of corrosivity.
261.23  Characteristic of reactivity.
261.24  Toxicity characteristic.

    Subpart D—Lists of Hazardous Wastes

261.30  General.
261.31  Hazardous wastes  from non-specific
   sources.
261.32  Hazardous  wastes  from   specific
   sources.
261.33  Discarded  commercial   chemical
    products,  off-specification  species, con-
    tainer residues, and spill residues there-
    of.
261.35 Deletion of certain hazardous waste
    codes following equipment cleaning and
    replacement.

          APPENDICES TO PART 261
APPENDIX   I—REPRESENTATIVE  SAMPLING
    METHODS
APPENDIX II—METHOD 1311 TOXICITY CHAR-
    ACTERISTIC LEACHING PROCEDURE (TCLP)
APPENDIX  III—CHEMICAL  ANALYSIS  TEST
    METHODS
APPENDIX IV—[RESERVED  FOR RADIOACTIVE
    WASTE TEST METHODS]
APPENDIX  V—[RESERVED  FOR  INFECTIOUS
    WASTE TREATMENT SPECIFICATIONS]
APPENDIX  VI—[RESERVED  FOR  ETIOLOGIC
    AGENTS]
Sec.
APPENDIX VII—BASIS  FOR LISTING HAZARD-
   OUS WASTE
APPENDIX VIII—HAZARDOUS CONSTITUENTS
APPENDIX  IX—WASTES   EXCLUDED  UNDER
   §§260.20 AND 260.22
APPENDIX  X—METHOD  OF ANALYSIS  FOR
   CHORINATED DIBENZO-P-DIOXINS AND -Di-
   BENZOFURANS

  AUTHORITY: 42 U.S.C.  6905,  6912(a), 6921,
6922, and 6938.
  SOURCE: 45 FR 33119, May 19, 1980, unless
otherwise noted.
         Subpart A—General

§ 261.1  Purpose and scope.
  (a) This  part identifies those solid
wastes which are subject to regulation
as hazardous  wastes under  parts 262
through 265,  268, and parts 270, 271,
and 124 of  this chapter and which are
subject  to  the notification  require-
ments  of  section  3010 of RCBA. In
this part:
  (1) Subpart A  defines  the  terms
"solid waste"  and "hazardous waste",
identifies those wastes which are ex-
cluded  from  regulation under  parts
262  through 266, 268  and 270 and es-
tablishes special management require-
ments  for  hazardous  waste  produced
by conditionally exempt small quanti-
ty  generators and hazardous  waste
which is recycled.
  (2) Subpart B sets forth the criteria
used by EPA to identify characteris-
tics of hazardous waste and to list par-
ticular hazardous wastes.
  (3) Subpart C identifies characteris-
tics of hazardous waste.
  (4) Subpart D lists  particular haz-
ardous wastes.
  (b)(l) The definition of solid  waste
contained in this part applies only  to
wastes  that also are hazardous for pur-
poses of the regulations implementing
subtitle C  of RCRA.  For example, it
does not apply to materials (such  as
non-hazardous scrap,  paper,  textiles,
or rubber)  that are not otherwise haz-
ardous wastes and that are recycled.
  (2) This part identifies only some of
the materials which  are  solid  wastes
and  hazardous  wastes under sections
3007, 3013, and 7003 of RCRA. A mate-
rial  which  is not  defined as  a  solid
waste in this  part, or is not  a hazard-
ous waste  identified or listed in this
                                       27

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§261.2

part, is still a solid waste and a hazard-
ous waste for purposes of these  sec-
tions if:
  (i) In the case of sections 3007  and
3013,  EPA has reason to believe that
the material  may be  a  solid  waste
within the meaning of section 1004(27)
of  RCRA  and  a  hazardous  waste
within the meaning of  section 1004(5)
of RCRA; or
  (ii)  In the case of section 7003, the
statutory elements are established.
  (c) For the purposes  of  §§ 261.2 and
261.6:
  (DA "spent material" is any materi-
al that has been used and as a result
of contamination can no longer serve
the purpose for which it was produced
without processing;
  (2)  "Sludge" has the same meaning
used in § 260.10 of this chapter;
  (3) A "by-product" is a material that
is not one of the primary products of a
production process and is not solely or
separately produced by the production
process. Examples are process residues
such  as slags  or  distillation  column
bottoms. The term does not include a
co-product  that is produced for the
 general public's use and  is ordinarily
used in the form it is produced by the
process.
   (4) A material is "reclaimed" if it is
 processed to recover a usable product,
 or if  it is regenerated. Examples are
recovery of lead values from spent bat-
 teries and  regeneration of spent sol-
vents.
   (5) A material is "used or reused" if
 it is either:
   (i)  Employed  as  an ingredient (in-
 cluding use as  an intermediate) in an
 industrial process to  make a product
 (for   example,  distillation  bottoms
 from one process used as feedstock in
 another process). However, a material
 will not satisfy this condition if dis-
 tinct components of the  material are
 recovered as separate end products (as
 when  metals   are  recovered   from
 metal-containing secondary materials);
 or
   (ii)  Employed in a particular  func-
 tion or application as an effective sub-
 stitute for a commercial  product (for
 example, spent pickle liquor used as
 phosphorous precipitant   and  sludge
 conditioner in wastewater treatment).
         40 CFR Ch. I (7-1-92 Edition)

  (6) "Scrap metal" is bits and pieces
of metal  parts  (e.g.,} bars,  turnings,
rods, sheets, wire) or metal pieces that
may be combined together with bolts
or soldering (e.g., radiators, scrap auto-
mobiles,  railroad  box  cars), which
when worn or superfluous can be recy-
cled.
  (7) A material is "recycled" if it is
used, reused, or reclaimed.
  (8) A material is "accumulated spec-
ulatively" if it is accumulated before
being recycled. A material is not accu-
mulated speculatively, however, if the
person accumulating it can show that
the material is potentially recyclable
and has a feasible means of being recy-
cled;  and  that—during the  calendar
year (commencing on January 1)—the
amount of material that is recycled, or
transferred to a different site for recy-
cling,  equals  at least  75  percent by
weight or volume  of the amount of
that material accumulated at the be-
ginning of  the period. In calculating
the percentage of turnover, the 75 per-
cent  requirement is to be  applied to
each material of the same  type (e.g.,
slags  from a single  smelting process)
that is recycled in the same way  (i.e.,
from which the same material is recov-
ered or that is used in the same way).
Materials accumulating in units  that
would \js  exempt  from   regulation
under § 261.4(c) are not be included in
making  the  calculation.   (Materials
that  are  already  defined  as  solid
wastes also are not to be included in
making the calculation.) Materials are
no longer  in this  category  once they
 are removed from accumulation for re-
 cycling, however.
 [45 FR 33119, May 19, 1980, as  amended at
 48 FR 14293, Apr. 1, 1983; 50 FR 663, Jan. 4,
 1985; 51 FR 10174,  Mar. 24, 1986; 51 FR
 40636, Nov. 7, 1986]

 § 261.2 Definition of solid waste.
   (aXI) A solid waste is any discarded
 material  that  is  not  excluded  by
 § 261.4(a) or that  is not excluded by
 variance granted under §§ 260.30  and
 260.31.
   (2) A discarded material is any mate-
 rial which is:
   (i) Abandoned, as explained in para-
 graph (b) of this section; or
                                     28

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Environmental Protection Agency
                              §261.2
  (ii)  Recycled, as explained  in para-
graph (c) of this section; or
  (iii)  Considered  inherently waste-
like, as explained in paragraph (d) of
this section.
  (b)  Materials are solid waste if they
are abandoned by being:
  (1) Disposed of; or
  (2) Burned or incinerated; or
  (3)  Accumulated, stored, or treated
(but not recycled) before or in lieu of
being abandoned by being disposed of,
burned, or incinerated.
  (c) Materials are solid wastes if they
are recycled—or accumulated, stored,
or treated before recycling—as speci-
fied in paragraphs (c)(l) through (4)
of this section.
  (1)  Used in a manner constituting
disposal, (i) Materials noted with a "*"
in Column 1 of Table I are solid wastes
when they are:
  (A) Applied to or placed on the land
in a manner that constitutes disposal;
or
  (B) Used to produce products  that
are applied to or placed on the land or
are otherwise  contained in products
that are applied to or placed on the
land (in which  cases the product itself
remains a solid waste).
  (ii)  However, commercial chemical
products listed  in § 261.33 are not solid
wastes if they  are applied to the land
and that  is their  ordinary  manner  of
use.
  (2) Burning for energy recovery,  (i)
Materials noted with a "*" in column 2
of Table 1 are  solid wastes when they
are:
  (A) Burned to recover energy;
  (B) Used to  produce  a  fuel  or are
otherwise contained in fuels (in which
cases the  fuel  itself remains a solid
waste).
  (ii)  However, commercial chemical
products listed in  § 261.33 are not solid
wastes if they are  themselves fuels.
  (3) Reclaimed. Materials  noted with
a "*" in column 3 of Table 1 are solid
wastes when reclaimed.
  (4) Accumulated speculatively. Mate-
rials noted with a "*" in column 4 of
Table  1 are solid wastes when accumu-
lated speculatively.
                                   TABLE 1


Sludges (listed in 40 CFR part 261 31 or 261 32) 	

By-products (listed in 40 CFR part 261 31 or 261 32)
By-products exhibiting a characteristic of hazardous waste 	


Use
constituting
disposal
(§261.2(c)(1))
0)
(")
C)
C)
(*)
(*)
C)
n
Energy
recovery/fuel
(|261.2
-------
§261.3
         40 CFR Ch. I (7-1-92 Edition)
  (3) The Administrator will  use the
following criteria to add wastes to that
list:
  (i)(A) The materials  are ordinarily
disposed of, burned, or incinerated; or
  (B) The materials contain toxic con-
stituents listed  in appendix  VIII of
part 261 and these  constituents are
not ordinarily found in raw materials
or products  for which the materials
substitute (or are found in raw materi-
als or  products  in smaller concentra-
tions)  and  are  not  used or reused
during the recycling process; and
  (ii) The  material  may  pose a sub-
stantial hazard to human health and
the environment when recycled.
  (e) Materials that are not solid waste
when recycled. (1) Materials  are not
solid wastes when they can be shown
to be recycled by being:
  (i) Used or reused  as ingredients in
an industrial process to make a prod-
uct,  provided the materials  are not
being reclaimed; or
  (ii) Used or reused as effective sub-
stitutes for commercial products; or
  (iii) Returned to the original process
from which they are generated, with-
out first being reclaimed. The  material
must be returned as a substitute for
raw  material feedstock, and the  proc-
ess must use raw materials as principal
feedstocks.
  (2) The following materials  are solid
wastes, even if the recycling  involves
use,  reuse,  or return to  the original
process (described in paragraphs (e)(l)
(i) through (iii) of this section):
  (i) Materials used in  a  manner con-
stituting disposal, or used to  produce
products that are  applied to the  land;
or
  (ii) Materials burned for energy re-
covery, used to produce a fuel, or con-
tained in fuels; or
  (iii) Materials accumulated  specula-
tively; or
  (iv)  Materials  listed  in paragraph
(d)(l) of this section.
  (f) Documentation of  claims  that
materials are not solid wastes or are
conditionally exempt from regulation.
Respondents in actions  to enforce reg-
ulations implementing  subtitle  C of
RCRA who raise a claim that a certain
material is not a solid waste, or is con-
ditionally  exempt  from  regulation,
must demonstrate  that   there  is  a
known market or disposition for the
material,  and  that  they  meet  the
terms of the exclusion or exemption.
In doing so, they must provide appro-
priate  documentation  (such  as con-
tracts showing that a second person
uses the material as an ingredient in a
production  process)  to  demonstrate
that the material is not a waste, or is
exempt from  regulation. In addition,
owners or operators of facilities claim-
ing that they actually are recycling
materials must show  that they have
the necessary equipment to do so.

[50 FR 664, Jan. 4, 1985, as amended at 50
FR 33542, Aug. 20, 1985; 56 FR 7206, Feb.
21, 1991; 56 FR  32688, July 17, 1991; 56  FR
42512, Aug. 27, 1991]

§ 261.3  Definition of hazardous waste.
  (a)  A  solid  waste,   as  defined  in
§ 261.2, is a hazardous waste if:
  (1) It is  not excluded from  regula-
tion as  a  hazardous  waste  under
§ 261.4(b); and
  (2) It meets  any of the following cri-
teria:
  (i) It exhibits any of the characteris-
tics  of hazardous waste  identified in
subpart C except that any mixture of
a waste from the extraction, beneficia-
tion, and processing of ores and miner-
als excluded  under § 261.4(b)(7) and
any other  solid waste  exhibiting a
characteristic  of  hazardous  waste
under subpart C of this part only if it
exhibits a  characteristic  that  would
not  have been  exhibited by the  ex-
cluded  waste alone if  such  mixture
had not occurred or if it continues to
exhibit any of the characteristics  ex-
hibited by the  non-excluded wastes
prior to mixture. Further, for the pur-
poses of applying the Toxicity Charac-
teristic  to such mixtures, the mixture
is also a hazardous waste if it exceeds
the  maximum concentration for any
contaminant  listed   in  table   I  to
§ 261.24 that would not have been  ex-
ceeded by the excluded waste alone if
the mixture had not occurred or if it
continues  to  exceed   the maximum
concentration for any  contaminant  ex-
ceeded by  the nonexempt waste prior
to mixture.
  (ii) It is listed  in subpart D of this
part and has  not been excluded from
the  lists  in subpart  D  of  this part
                                    30

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Environmental Protection Agency
                             §261.3
under  §§ 260.20 and 260.22  of  this
chapter.
  (iii) It is  a mixture of a solid waste
and a hazardous waste that is listed in
subpart D of this part solely because it
exhibits one or more of the character-
istics of hazardous waste identified in
subpart C of this part, unless the re-
sultant mixture no longer exhibits any
characteristic of hazardous waste iden-
tified  in subpart  C  of this  part  or
unless the solid waste is excluded from
regulation under § 261.4(b)(7)  and the
resultant mixture  no longer  exhibits
any  characteristic  of hazardous waste
identified in subpart C of this  part for
which the  hazardous waste listed in
subpart D of this part was listed.
  (iv) It is a mixture of solid waste and
one or more hazardous wastes  listed in
subpart D of this part  and  has not
been excluded from paragraph (a)(2)
of this section under  §§260.20  and
260.22 of this chapter; however, the
following mixtures of solid wastes and
hazardous  wastes  listed in  subpart D
of this part are not hazardous wastes
(except by application of  paragraph
(a)(2)  (i) or (ii) of this section) if the
generator  can demonstrate that the
mixture consists of wastewater the dis-
charge of which is  subject to regula-
tion under either section 402 or sec-
tion 307(b) of the Clean Water Act (in-
cluding wastewater  at facilities which
have  eliminated  the  discharge  of
wastewater) and:
  (A) One or more of the following sol-
vents  listed in § 261.31—carbon tetra-
chloride, tetrachloroethylene, trichlor-
oethylene—Provided, That the maxi-
mum  total weekly usage  of these sol-
vents (other  than the amounts  that
can be  demonstrated not  to be dis-
charged to wastewater) divided by the
 average  weekly flow of  wastewater
 into the headworks of the  facility's
 wastewater treatment or pretreatment
 system does not exceed 1  part per mil-
 lion; or
  (B)  One  or more of the following
spent solvents listed in § 261.31—meth-
 ylene chloride, 1,1,1-trichloroethane,
 chlorobenzene, o-dichlorobenzene, cre-
 sols, cresylic  acid, nitrobenzene, tolu-
 ene, methyl ethyl ketone, carbon di-
 sulfide,  isobutanol, pyridine,  spent
 chlorofluorocarbon  solvents—provided
 that the maximum  total weekly  usage
of  these  solvents  (other  than  the
amounts that can be demonstrated not
to be discharged to wastewater) divid-
ed  by the  average weekly flow  of
wastewater into the headworks of the
facility's wastewater treatment  or pre-
treatment system does not exceed 25
parts per million;  or
  (C) One  of  the following  wastes
listed  in  § 261.32—heat   exchanger
bundle cleaning sludge from the petro-
leum refining industry (EPA Hazard-
ous Waste No. K050); or
  (D) A discarded commercial  chemi-
cal product, or chemical intermediate
listed in § 261.33,  arising from de mini-
mis losses  of  these  materials from
manufacturing operations  in   which
these materials are used as raw mate-
rials or are produced in the manufac-
turing process. For purposes  of  this
paragraph (a)(2)(iv)(D), "de minimis"
losses include those from normal ma-
terial handling operations  (e.g., spills
from the unloading or transfer of ma-
terials from bins or other containers,
leaks from pipes, valves or other de-
vices  used  to  transfer   materials);
minor  leaks  of process  equipment,
storage tanks or containers; leaks from
well  maintained pump packings  and
seals; sample  purgings; relief  device
discharges;  discharges  from   safety
showers and rinsing and  cleaning of
personal  safety  equipment; and rin-
state from empty  containers or from
containers that are rendered empty by
that rinsing; or
   (E) Wastewater resulting from labo-
ratory operations containing toxic (T)
wastes listed in subpart D of this part,
Provided, That the annualized  average
flow of laboratory wastewater does not
exceed one percent of total wastewater
flow into the headworks of the facili-
ty's wastewater treatment or pre-treat-
ment system, or provided the wastes,
combined  annualized average  concen-
 tration does not exceed one part per
 million in the  headworks of the facili-
 ty's wastewater treatment or pre-treat-
 ment facility. Toxic (T) wastes used in
 laboratories that  are  demonstrated
 not to be discharged to wastewater are
 not to be  included in this calculation.
   (b) A solid waste which is  not ex-
 cluded from regulation under para-
 graph (a)(l) of this section becomes a
                                     31

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§261.3
         40 CFR Ch. I (7-1-92 Edition)
hazardous waste when any of the fol-
lowing events occur:
  (1) In the case of a waste listed in
subpart D of this part, when the waste
first meets the listing description set
forth in subpart D of this part.
  (2) In the case of a mixture of solid
waste and one or  more listed hazard-
ous wastes,  when a hazardous waste
listed in subpart D is first added to the
solid waste.
  (3) In the case  of any other waste
(including a waste mixture), when the
waste exhibits any of  the characteris-
tics  identified in  subpart C of  this
part.
  (c) Unless and until it meets the cri-
teria of paragraph (d) of this section:
  (DA hazardous waste will remain a
hazardous waste.
  (2)(i) Except as otherwise provided
in paragraph  (c)(2Xii) of this section,
any  solid waste  generated from the
treatment, storage, or disposal of a
hazardous waste, including any sludge,
spill  residue,  ash,  emission  control
dust, or leachate (but not  including
precipitation  run-off) is  a hazardous
waste. (However, materials that are re-
claimed from solid wastes and that are
used beneficially are not solid  wastes
and  hence  are not hazardous  wastes
under  this  provision unless the  re-
claimed material is burned for energy
recovery or used in a manner  consti-
tuting disposal.)
  (ii) The  following  solid wastes are
not hazardous even though they are
generated  from the treatment, stor-
age, or disposal of a hazardous waste,
unless they exhibit one or more of the
characteristics of hazardous waste:
  (A) Waste pickle liquor sludge gener-
ated  by lime stabilization  of spent
pickle  liquor  from the iron  and steel
industry (SIC Codes 331 and 332).
  (B) Waste from burning any  of the
materials exempted  from  regulation
by § 261.6(a)(3)(v) through (viii).
  (C) Nonwastewater residues, such as
slag, resulting from high temperature
metals recovery (HTMR) processing of
K061  waste,  in  units  identified as
rotary  kilns,  flame reactors, electric
furnaces, plasma arc furnaces, slag re-
actors,  rotary hearth  furnace/electric
furnace combinations or  industrial
furnaces  (as  defined  in  40  CFR
260.10(6), (7), and (12), that are dis-
posed  in  subtitle D units,  provided
that these residues  meet the generic
exclusion levels identified below for all
constituents, and exhibit no character-
istics of hazardous waste. Testing re-
quirements must be incorporated  in a
facility's waste analysis plan  or a  gen-
erator's self-implementing waste anal-
ysis  plan; at  a minimum, composite
samples of residues  must be collected
and  analyzed  quarterly and/or when
the  process or operation  generating
the waste changes. The generic exclu-
sion levels are:
Constituent
Antimony 	
Arsenic 	
Barium 	
Beryllium
Cadmium 	
Chromium (total) 	
Lead 	

Nickel
Selenium
Silver 	
Thallium
Vanadium 	

Maximum
for any
single
compos-
ite
sample
(mg/1)
0.063
0.055
6.3
0.0063
0032
0.33
0.095
0009
063
0.16
0.30
0013
1.26

  For each shipment of K061  HTMR
 residues sent to subtitle D unit that
 meets the generic exclusion levels for
 all constituents, and does not  exhibit
 any characteristic, a notification and
 certification must be sent to the ap-
 propriate  Regional  Administrator (or
 delegated  representative) or State au-
 thorized  to implement part  268  re-
 quirements. The notification must in-
 clude the  following information:  (1)
 The name and address of the subtitle
 D unit receiving the waste shipment;
 (2) the EPA hazardous waste number
 and treatability group  at the initial
 point of  generation;  (3) treatment
 standards  applicable to the waste at
 the intital point of generation. The
 certification must be signed by an au-
 thorized representative and must state
 as follows: "I certify under penalty of
 law that the generic exclusion levels
 for  all  constituents have been met
 without  impermissible  dilution  and
 that  no  characteristic  of hazardous
 waste is exhibited.  I am aware that
                                    32

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Environmental Protection Agency
                              §261.4
there are significant penalties for sub-
mitting a false certification, including
the possibility of fine and  imprison-
ment."
  (d)  Any  solid waste  described in
paragraph  (c) of this  section is not a
hazardous waste if it meets the follow-
ing criteria:
  (1) In the case of any solid waste, it
does not exhibit any of the character-
istics of  hazardous waste identified in
subpart  C  of  this  part.  (However,
wastes that exhibit a characteristic at
the point of  generation  may still be
subject to  the  requirements of part
268,  even if they no longer exhibit a
characteristic at the point of land dis-
posal.)
  (2) In the case of a waste which is a
listed waste  under subpart  D of this
part, contains a waste listed under sub-
part D of this part or is derived from a
waste listed in subpart D of this part,
it also has been excluded from para-
graph  (c)   of   this  section  under
§§ 260.20 and 260.22 of this chapter.
  (e)  Sunset provision.  Paragraphs
(a)(2)(iv) and (c)(2)(i) of  this section
shall remain in effect only until April
28, 1993.
[57 FR 7632,  Mar. 3, 1992; 57 FR 23063,
June 1, 1992]
  EFFECTIVE DATE NOTE: At 57 FR 7632, Mar.
3, 1992 § 261.3 was revised, effective Febru-
ary  18,  1992.  Paragraphs  (a)(2)(iv)  and
(c)(2)(i) will  expire on April 28, 1993.

§ 261.4 Exclusions.
  (a) Materials  which  are  not solid
wastes.  The  following  materials  are
not solid wastes for the purpose of this
part:
  (l)(i) Domestic sewage; and
  (ii) Any mixture of  domestic sewage
and other  wastes that passes through
a sewer system to a publicly-owned
treatment  works for  treatment.  "Do-
mestic sewage" means untreated sani-
tary wastes that pass  through a sewer
system.
  (2) Industrial wastewater discharges
that  are point source discharges sub-
ject to regulation under section 402 of
the Clean Water Act, as amended.
[Comment:  This exclusion applies  only to
the actual point  source  discharge. It does
not exclude industrial  wastewaters  while
they are  being collected, stored or treated
before discharge, nor does it exclude sludges
that are generated by industrial wastewater
treatment.]

  (3) Irrigation return flows.
  (4)  Source,  special nuclear or  by-
product  material  as defined  by the
Atomic Energy Act of 1954, as amend-
ed, 42 U.S.C. 2011 et seg.
  (5)  Materials subjected  to in-situ
mining techniques which  are not re-
moved from the ground as part of the
extraction process.
  (6) Pulping liquors (i.e., black liquor)
that are  reclaimed in a pulping liquor
recovery furnace  and then reused in
the pulping process,  unless it is  accu-
mulated  speculatively  as  defined  in
§ 261.l(c) of this chapter.
  (7)   Spent  sulfuric  acid   used  to
produce  virgin sulfuric acid,  unless it
is accumulated speculatively as  de-
fined in § 261.l(c) of this chapter.
  (8) Secondary materials  that are re-
claimed  and returned to the  original
process  or  processes in which  they
were generated where they are reused
in the production process provided:
  (i) Only tank storage is involved, and
the entire process through completion
of reclamation is  closed by  being en-
tirely  connected with pipes  or  other
comparable enclosed means of convey-
ance;
  (ii)  Reclamation  does  not involve
controlled flame combustion (such as
occurs in boilers, industrial furnaces,
or incinerators);
  (iii)  The secondary materials  are
never accumulated in such  tanks for
over twelve months  without  being re-
claimed; and
  (iv)  The  reclaimed material is not
used  to produce  a  fuel,  or  used to
produce products that are used in a
manner constituting disposal.
  (9)(i) Spent wood preserving  solu-
tions that have been reclaimed and are
reused for their original intended pur-
pose; and
  (ii) Wastewaters from the wood pre-
serving  process  that have  been re-
claimed  and are reused to treat  wood.
  (10)  EPA  Hazardous  Waste  No.
K087, and  any wastes from  the coke
by-products processes that are hazard-
ous only because they exhibit the Tox-
icity  Characteristic  specified in Sec-
tion 261.24 of this part, when,  subse-
quent to generation, these materials
                                     33

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§261.4
         40 CFR Ch. I (7-1-92 Edition)
are recycled to coke ovens, to the tar
recovery process  as a  feedstock  to
produce  coal  tar  or are mixed  with
coal tar prior to the tar's sale or refin-
ing. This exclusion  is conditioned  on
there being no land disposal  of the
wastes from the point they are gener-
ated to the point they are recycled to
coke ovens or  the  tar refining process.
  (11) Nonwastewater splash condens-
er dross residue from the treatment of
K061 in high temperature metals  re-
covery units, provided it is shipped in
drums (if shipped)  and  not  land dis-
posed before recovery.
  (b) Solid wastes which are not haz-
ardous  wastes. The  following  solid
wastes are not hazardous wastes:
  (1)   Household   waste,   including
household waste that has been collect-
ed, transported, stored,  treated, dis-
posed, recovered  (e.g., refuse-derived
fuel)  or reused.  "Household  waste"
means any material  (including  gar-
bage, trash  and  sanitary  wastes in
septic tanks) derived from households
(including  single  and  multiple resi-
dences,  hotels  and  motels,  bunk-
houses, ranger stations, crew quarters,
campgrounds, picnic grounds and day-
use recreation areas). A resource re-
covery  facility managing  municipal
solid waste shall not be  deemed to be
treating, storing, disposing of, or oth-
erwise managing hazardous wastes for
the purposes of regulation under this
subtitle, if such facility:
  (i) Receives and burns only
  (A) Household  waste   (from single
and multiple dwellings, hotels, motels,
and other residential sources) and
  (B) Solid waste from commercial or
industrial sources that  does not con-
tain hazardous waste; and
  (ii) Such facility does not accept haz-
ardous wastes and the owner or opera-
tor  of  such  facility  has established
contractual requirements or other ap-
propriate  notification  or  inspection
procedures  to assure that  hazardous
wastes are not received at or burned in
such facility.
  (2) Solid wastes generated by any of
the following and which are returned
to the soils as fertilizers:
  (i) The growing and  harvesting of
agricultural crops.
  (ii) The raising of animals, including
animal manures.
  (3) Mining overburden  returned to
the mine site.
  (4) Fly ash waste, bottom ash waste,
slag waste, and flue gas emission con-
trol waste, generated primarily from
the combusion of coal or other fossil
fuels, except as provided  by  § 268.112
of this chapter for facilities that burn
or process hazardous waste.
  (5) Drilling fluids, produced waters,
and other wastes associated  with  the
exploration, development, or produc-
tion of crude  oil, natural gas or geo-
thermal energy.
  (6)(i) Wastes which fail the test for
the Toxicity  Characteristic  because
chromium  is present or are listed in
subpart D due to the presence of chro-
mium, which  do not fail  the test for
the Toxicity  Characteristic  for  any
other constituent or are not listed due
to the presence of any other constitu-
ent, and which do not fail the test for
any other characteristic, if it is shown
by a waste generator or by waste gen-
erators that:
  (A) The  chromium in the waste is
exclusively (or nearly exclusively) tri-
valent chromium; and
  (B) The waste is generated from an
industrial process which uses trivalent
chromium exlcusively (or nearly exclu-
sively) and the process does not  gener-
ate hexavalent chromium; and
  (C) The  waste is typically and  fre-
quently managed in non-oxidizing en-
vironments.
  (ii) Specific wastes which  meet the
standard in  paragraphs  (b)(6)(i)(A),
(B) and (C) (so long as they do not fail
the test for  the charactristic  of EP
toxicity, and  do not fail  the test for
any other characteristic) are:
  (A) Chrome (blue) trimmings gener-
ated by the following subcategories of
the leather tanning and  finishing in-
dustry: hair pulp/chrome tan/retan/
wet finish;  hair  save/chrome tan/
retan/wet  finish; retan/wet finish; no
beamhouse;   through-the-blue;   and
shearling.
  (B) Chrome (blue) shavings generat-
ed by  the following subcategories of
the leather tanning and  finishing in-
dustry: Hair pulp/chrome tan/retan/
wet finish;  hair  save/chrome tan/
retan/wet  finish; retan/wet  finish; no
beamhouse;   through-the-blue;   ana
shearling.
                                    34

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Environmental Protection Agency
                             §261.4
   Buffing dust generated by the
following subcategories of the leather
tanning and finishing industry;  hair
pulp/chrome  tan/retan/wet   finish;
hair   save/chrome   tan/retan/wet
finish; retan/wet  finish;  no  beam-
house; through-the-blue.
  (D) Sewer screenings generated by
the  following  subcategories  of  the
leather tanning and  finishing indus-
try:  Hair pulp/crome tan/retan/wet
finish; hair  save/chrome  tan/retan/
wet finish; retan/wet  finish; no beam-
house; through-the-blue;  and  shear-
ling.
  (E) Wastewater  treatment  sludges
generated by the following subcategor-
ies of the leather tanning  and finish-
ing industry: Hair pulp/chrome  tan/
retan/wet  finish;  hair  save/chrome
tan/retan/wet    finish;   retan/wet
finish; no  beamhouse;  through-the-
blue; and shearling.
  (F) Wastewater  treatment  sludes
generated by the following subcategor-
ies of the leather tanning  and finish-
ing industry: Hair pulp/chrome  tan/
retan/wet  finish; hair save/chrome-
tan/retan/wet  finish;  and  through-
the-blue.
  (G) Waste scrap leather from the
leather  tanning  industry,  the  shoe
manufacturing industry,  and  other
leather product manufacturing indus-
tries,
  (H) Wastewater  treatment sludges
from the production  of TiO2 pigment
using chromium-bearing ores by the
chloride process.
  (7) Solid waste  from the extraction,
beneficiation, and  processing of ores
and  minerals  (including coal,  phos-
phate rock  and overburden from the
mining of uranium ore), except as pro-
vided by § 266.112 of this chapter for
facilities that burn or process hazard-
ous   waste.   For    purposes    of
§ 261.4(b)(7), beneficiation  of ores and
minerals is  restricted to the following
activities: Crushing; grinding; washing;
dissolution;  crystallization; filtration;
sorting; sizing; drying; sintering; pelle-
tizing; briquetting; calcining to remove
water and/or carbon dioxide; roasting,
autoclaving, and/or  chlorination  in
preparation   for  leaching   (except
where the roasting (and/or  autoclav-
ing  and/or  chlorination)/leaching se-
quence produces  a final or intermedi-
ate product that does not undergo fur-
ther beneficiation or processing); grav-
ity  concentration;  magnetic  separa-
tion;  electrostatic  separation;  flota-
tion; ion exchange;  solvent extraction;
electrowinning; precipitation;  amalga-
mation; and  heap, dump, vat, tank,
and in situ leaching. For  the  purpose
of § 261.4(b)(7),  solid waste from the
processing  of ores and minerals in-
cludes only the following wastes:
  (i) Slag  from  primary copper proc-
essing;
  (ii) Slag from  primary lead  process-
ing;
  (iii) Red and brown muds from baux-
ite refining;
  (iv) Phosphogypsum from phosphor-
ic acid production;
  (v) Slag from elemental phosphorus
production;
  (vi) Gasifier ash  from coal  gasifica-
tion;
  (vii) Process wastewater from coal
gasification;
  (viii)  Calcium sulfate   wastewater
treatment plant sludge from  primary
copper processing;
  (ix)  Slag  tailings  from   primary
copper processing;
  (x) Fluorogypsum from  hydrofluoric
acid production;
  (xi) Process wastewater  from hydro-
fluoric acid production;
  (xii)  Air   pollution   control  dust/
sludge from iron blast furnaces;
  (xiii) Iron blast furnace slag;
  (xiv) Treated residue from roasting/
leaching of chrome ore;
  (xv) Process wastewater from  pri-
mary magnesium processing by the an-
hydrous process;
  (xvi) Process wastewater from phos-
phoric acid production;
  (xvii) Basic oxygen furnace and open
hearth  furnace air pollution  control
dust/sludge from carbon steel produc-
tion;
  (xviii) Basic  oxygen  furnace  and
open hearth furnace slag  from carbon
steel production;
  (xix)  Chloride process  waste solids
from titanium  tetrachloride  produc-
tion;
  (xx) Slag from primary  zinc process-
ing.
  (8) Cement kiln  dust waste, except
as provided by § 266.112 of this chap-
                                    35

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§261.4
         40 CFR Ch. I (7-1-92 Edition)
ter for facilities that burn or process
hazardous waste.
  (9) Solid waste which consists of dis-
carded wood or wood  products which
fails the test for the Toxicity Charac-
teristic solely for arsenic and which is
not a hazardous  waste for any other
reason or reasons, if the waste is gen-
erated by persons who utilize the ar-
senical-treated  wood  and wood prod-
ucts for these materials' intended end
use.
  (10) Petroleum-contaminated media
and debris that fail the  test for the
Toxicity  Characteristic  of  § 261.24
(Hazardous    Waste    Codes   D018
through D043 only) and are subject to
the corrective action regulations under
part 280 of this chapter.
  (11)  Injected groundwater that is
hazardous only because it exhibits the
Toxicity  Characteristic  (Hazardous
Waste Codes D018 through D043 only)
in § 261.24 of this part that is reinject-
ed through  an underground injection
well pursuant to  free phase hydrocar-
bon recovery operations undertaken at
petroleum refineries,  petroleum  mar-
keting  terminals,  petroleum   bulk
plants, petroleum pipelines, and petro-
leum transportation  spill sites  until
January 25,  1993. This extension ap-
plies to recovery  operations in exist-
ence, or for which contracts have been
issued, on or before  March 25,  1991.
For groundwater returned through in-
filtration  galleries from such oper-
ations at petroleum refineries, market-
ing terminals,  and bulk plants,  until
[insert date six months after publica-
tion]. New operations involving injec-
tion wells (beginning after March 25,
1991) will qualify for  this compliance
date  extension  (until  January   25,
1993) only if:
  (i) Operations are performed pursu-
ant to a written state agreement  that
includes a  provision to  assess  the
groundwater and the need for further
remediation once the free phase recov-
ery is completed; and
  (ii) A copy of the written agreement
has been submitted to: Characteristics
Section (OS-333), U.S. Environmental
Protection Agency, 401 M Street, SW.,
Washington, DC 20460.
  (12) Used  chlorofluorocarbon refrig-
erants  from  totally  enclosed  heat
transfer equipment, including mobile
air  conditioning  systems,  mobile re-
frigeration, and commercial and indus-
trial air conditioning and refrigeration
systems that use chlorofluorocarbons
as the heat transfer fluid in a refriger-
ation cycle, provided the refrigerant is
reclaimed for further use.
  (13)—(14) [Reserved]
  (15) Non-terne plated used  oil filters
that are not mixed with wastes listed
in subpart D of this part  if  these oil
filters have been gravity hot-drained
using one of the following methods:
  (i)  Puncturing  the filter anti-drain
back valve or the filter dome end and
hot-draining;
  (ii) Hot-draining and crushing;
  (iii) Dismantling and hot-draining;
or
  (iv) Any other equivalent hot-drain-
ing method that  will remove used oil.
  (c) Hazardous wastes which  are ex-
empted  from certain regulations. A
hazardous waste which is generated in
a  product  or  raw  material  storage
tank, a product or raw material trans-
port vehicle or vessel, a product or raw
material pipeline, or in a manufactur-
ing process  unit or an associated non-
waste-treatment-manufacturing  unit,
is not  subject  to  regulation under
parts 262 through  265, 268,  270, 271
and 124 of this chapter or to the noti-
fication requirements  of section 3010
of RCRA until it  exits the unit in
which  it was  generated,  unless the
unit is  a surface  impoundment, or
unless the hazardous waste remains in
the  unit more than 90 days  after the
unit ceases to be operated for manu-
facturing, or for storage or transporta-
tion of product or raw materials.
  (d) Samples. (1) Except as provided
in paragraph (d)(2)  of this  section, a
sample of solid waste or a sample of
water, soil,  or  air,  which  is  collected
for the sole purpose of testing to de-
termine its characteristics or composi-
tion, is  not subject to any require-
ments  of  this  part  or  parts  262
through 268 or part 270 or part 124 of
this chapter or to the notification re-
quirements  of section 3010 of  RCRA,
when:
  (i) The sample is  being transported
to a laboratory for the purpose of test-
ing;  or
                                    36

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Environmental Protection Agency
                             §261.4
  (ii) The sample is being transported
back to the sample collector after test-
ing; or
  (iii) The  sample is being stored by
the sample collector before transport
to a laboratory for testing; or
  (iv) The sample is being stored  in a
laboratory before testing; or
  (v) The sample is being stored  in a
laboratory after testing but before it is
returned to the sample collector; or
  (vi) The sample is being stored tem-
porarily in the laboratory after testing
for a specific purpose  (for example,
until conclusion  of a court case or en-
forcement action where further  test-
ing of the sample may be necessary).
  (2) In  order to qualify for the ex-
emption  in paragraphs (d)(l) (i) and
(ii) of this section, a sample  collector
shipping samples to a laboratory and a
laboratory  returning  samples  to a
sample collector must:
  (i) Comply  with U.S. Department of
Transportation  (DOT), U.S.  Postal
Service (USPS), or any other applica-
ble shipping requirements; or
  (ii)  Comply with the following re-
quirements if the sample collector de-
termines that DOT, USPS,  or other
shipping requirements  do not apply to
the shipment of the sample:
  (A) Assure  that the following infor-
mation accompanies the sample:
  (1)  The sample collector's  name,
mailing   address,   and  telephone
number;
  (2)  The laboratory's  name, mailing
address, and telephone number;
  (.3) The quantity of the sample;
  (4) The date of shipment; and
  (5) A description of the sample.
  (B) Package  the sample so that it
does  not leak, spill, or vaporize  from
its packaging.
  (3) This exemption does not apply if
the laboratory  determines  that the
waste is hazardous but the laboratory
is no longer meeting any of the condi-
tions stated in paragraph (d)(l) of this
section.
   (e) Treatability Study Samples.  (1)
Except as provided in paragraph (e)(2)
of this section,  persons who generate
or collect samples  for  the purpose of
conducting treatability studies as de-
fined in section 260.10, are not subject
to any  requirement  of  parts  261
through 263 of this chapter  or to the
notification  requirements of Section
3010 of RCRA, nor are such samples
included in  the quantity determina-
tions of § 261.5 and § 262.34(d) when:
  (i) The sample is being collected and
prepared  for  transportation by the
generator or sample collector; or
  (ii) The sample is being accumulated
or stored by the generator or sample
collector prior to transportation to a
laboratory or testing facility; or
  (iii) The sample is being transported
to the laboratory or testing facility for
the purpose of conducting a treatabil-
ity study.
  (2)  The exemption  in  paragraph
(e)(l) of this  section is applicable to
samples of hazardous waste  being col-
lected and shipped for the purpose of
conducting treatability studies provid-
ed that:
  (i) The generator or sample collector
uses (in "treatability studies") no more
than  1000 kg of  any non-acute hazard-
ous waste, 1  kg of acute hazardous
waste, or 250 kg  of soils,  water, or
debris contaminated  with acute haz-
ardous waste  for  each process  being
evaluated for each generated  waste
stream; and
   (ii)  The mass of each sample ship-
ment does not exceed 1000 kg of non-
acute hazardous waste, 1 kg of acute
hazardous waste,  or  250 kg of soils,
water,  or debris  contaminated with
acute hazardous waste; and
   (iii) The sample must be packaged so
that  it will not  leak,  spill, or vaporize
from  its packaging during shipment
and the requirements of paragraph A
or B of this subparagraph are met.
   (A)  The  transportation   of  each
sample shipment  complies  with U.S.
Department of Transportation (DOT),
U.S.  Postal Service  (USPS), or  any
other  applicable  shipping require-
ments; or
   (B)  If the  DOT,  USPS, or  other
shipping requirements do not apply to
the shipment of the sample, the fol-
lowing information must accompany
the sample:
   (1) The name, mailing address,  and
telephone number of the originator of
 the sample;
   (2)  The name,  address,  and tele-
 phone number of  the facility that will
 perform the treatability study;
   (3) The quantity of the sample;
                                    37

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§261.4

  (4) The date of shipment; and
  (5) A description of the sample, in-
cluding  its   EPA  Hazardous  Waste
Number.
  (iv) The sample is shipped to a labo-
ratory  or  testing  facility  which  is
exempt  under § 261.4(f) or has an ap-
propriate  RCRA permit or  interim
status.
  (v) The generator or  sample collec-
tor maintains the following records for
a period ending 3 years after comple-
tion of the treatability study:
  (A) Copies of the shipping  docu-
ments;
  (B) A copy of the contract with the
facility  conducting  the treatability
study;
  (C) Documentation showing:
  (1) The amount  of  waste  shipped
under this exemption;
  (2) The name, address,  and  EPA
identification number of the laborato-
ry  or testing facility that received the
waste;
  (3) The date the shipment was made;
and
  (4) Whether or not unused samples
and residues were returned to the gen-
erator.
  (vi) The generator reports the infor-
mation  required   under  paragraph
(eXvXC) of this section in its biennial
report.
  (3) The Regional  Administrator, or
State Director (if located in an author-
ized State), may grant  requests,  on a
case-by-case  basis, for quantity limits
in  excess of those  specified  in para-
graph (e)(2)(i) of this section, for up to
an  additional 500 kg of  non-acute haz-
ardous waste, 1 kg of acute hazardous
waste, and  250 kg  of soils, water, or
debris contaminated with acute haz-
ardous waste, to conduct further treat-
ability study evaluation when: There
has been an equipment or mechanical
failure during the conduct of a treat-
ability study; there is a need to verify
the results  of a previously  conducted
treatability  study; there is  a need to
study  and  analyze  alternative tech-
niques within  a previously evaluated
treatment process;  or there is a  need
to do further evaluation of an ongoing
treatability  study to determine  final
specifications for treatment. The addi-
tional quantities allowed are subject to
all  the provisions in paragraphs (e)(l)
         40 CFR Ch. I (7-1-92 Edition)

and (e)(2Xii)(vi) of  this section. The
generator  or  sample  collector must
apply to the Regional Administrator
in the Region where the sample is col-
lected and provide in writing the fol-
lowing information:
  (i) The reason why the generator or
sample  collector requires  additional
quantity of sample for the treatability
study evaluation and the  additional
quantity needed;
  (ii)  Documentation  accounting for
all samples of hazardous waste from
the  waste  stream  which  have  been
sent  for  or  undergone  treatability
studies  including the data each previ-
ous sample from the waste stream was
shipped, the quantity of each previous
shipment, the laboratory or testing fa-
cility to which  it was shipped, what
treatability study processes were con-
ducted  on each sample shipped,  and
the available results of each treatabil-
ity study;
  (iii) A description of the technical
modifications  or change in specifica-
tions  which will be evaluated and the
expected results;
  (iv) If such further study is being re-
quired due  to equipment  or mechani-
cal failure, the applicant must include
information regarding the  reason for
the failure  or breakdown and also in-
clude what procedures or  equipment
improvements have been made to pro-
tect against further breakdowns; and
  (v)  Such other information that the
Regional Administrator considers nec-
essary.
  (f)  Samples  Undergoing Treatability
Studies  at  Laboratories  and Testing
Facilities.  Samples  undergoing treat-
ability  studies and  the laboratory or
testing  facility conducting such treat-
ability  studies (to the extent such fa-
cilities  are not otherwise  subject to
RCRA  requirements)  are not subject
to any  requirement of this part, part
124, parts  262-266, 268, and 270, or to
the notification requirements of  Sec-
tion 3010 of RCRA provided that the
conditions  of  paragraphs  (f)   (1)
through (11) of this section are met. A
mobile  treatment  unit (MTU) may
qualify as a testing facility subject to
paragraphs (f) (1) through (11) of this
section. Where a group of  MTUs  are
located at  the same site, the limita-
tions specified in  (f) (1) through (11)
                                    38

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Environmental Protection Agency
                             §261.4
of this section  apply to  the entire
group of MTUs  collectively as if the
group were one MTU.
  (1) No less than 45 days before con-
ducting treatability studies, the facili-
ty notifies the Regional  Administra-
tor, or State Director (if located in an
authorized State), in writing that it in-
tends to conduct treatability studies
under this paragraph.
  (2) The laboratory or testing facility
conducting the treatability study has
an EPA identification number.
  (3) No more than a total of 250 kg of
"as received" hazardous waste is sub-
jected to initiation of treatment in all
treatability studies  in any single day.
"As received" waste refers to the waste
as received in the shipment from the
generator or sample collector.
  (4) The  quantity  of  "as received"
hazardous  waste stored at the facility
for the purpose of evaluation in treat-
ability studies does not exceed 1000 kg,
the total of which can include 500 kg
of soils, water, or debris contaminated
with acute hazardous waste or 1 kg of
acute hazardous waste. This quantity
limitation does not include:
  (i) Treatability study residues; and
  (ii) Treatment  materials (including
nonhazardous solid  waste) added  to
"as received" hazardous waste.
  (5)  No  more  than 90  days  have
elapsed since the treatability study for
the sample was completed, or no more
than one  year has elapsed since the
generator or sample collector shipped
the sample to the laboratory or testing
facility, whichever date first occurs.
  (6) The treatability study  does not
involve  the placement  of hazardous
waste on the land or open burning of
hazardous waste.
  (7) The  facility  maintains records
for 3 years following completion  of
each study that show compliance with
the treatment rate limits and the stor-
age time and quantity limits. The fol-
lowing specific information must be in-
cluded for  each treatability study con-
ducted:
  (i) The  name,  address,  and  EPA
identification number of the generator
or  sample  collector of  each  waste
sample;
  (ii) The  date the  shipment was re-
ceived;
  (iii) The  quantity of waste accepted;
  (iv) The quantity of "as received"
waste in storage each day;
  (v)  The  date the treatment  study
was  initiated and  the amount of "as
received"  waste introduced to  treat-
ment each day;
  (vi) The date the treatability study
was concluded;
  (vii) The date any unused sample or
residues generated from the treatabil-
ity study were returned to the genera-
tor or sample collector or, if sent to a
designated facility, the name of the fa-
cility  and  the  EPA  identification
number.
  (8) The  facility keeps, on-site, a copy
of the treatability study contract and
all shipping papers associated with the
transport  of treatability study samples
to and from the facility for a period
ending 3  years from the  completion
date of each treatability study.
  (9) The  facility prepares and submits
a report to the Regional Administra-
tor, or State Director (if located in an
authorized State), by  March  15 of
each year that estimates the number
of studies and the  amount of waste ex-
pected to  be used  in treatability stud-
ies during the current year, and in-
cludes the following information for
the previous calendar year:
  (i)  The name,  address,  and  EPA
identification  number of the  facility
conducting the treatability studies;
  (ii) The types (by process) of treat-
ability studies conducted;
  (iii) The names and addresses of per-
sons for whom studies have been con-
ducted (including their EPA identifica-
tion numbers);
  (iv) The total quantity of waste in
storage each day;
  (v) The quantity and types of waste
subjected to treatability studies;
  (vi)  When each treatability study
was conducted;
  (vii) The final disposition of residues
and  unused sample from  each treat-
ability study.
  (10) The facility determines whether
any  unused sample or residues gener-
ated by the treatability study are haz-
ardous waste under § 261.3 and, if so,
are subject to  parts 261 through 268,
and  part  270  of this chapter, unless
the  residues and  unused samples are
returned   to  the  sample  originator
under the § 261.4(e) exemption.
                                    39

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§261.5
         40 CFR Ch. I (7-1-92 Edition)
  (11) The facility notifies the Region-
al Administrator, or State Director (if
located in an  authorized State),  by
letter when the  facility is  no longer
planning  to conduct any treatability
studies at the site.
(Approved  by  the  Office of Management
and Budget under  control number 2050-
0088)
[45 PR 33119, May 19, 1980]
  EDITORIAL NOTE: For FEDERAL REGISTER ci-
tations affecting § 261.4, see the List of CFR
Sections Affected in the Finding Aids  sec-
tion of this volume.

§261.5 Special requirements for hazard-
   ous  waste generated  by conditionally
   exempt small quantity generators.
  (a)  A  generator is a conditionally
exempt small quantity generator in a
calendar  month   if he generates  no
more than 100 kilograms of hazardous
waste in that month.
  (b)  Except for  those wastes identi-
fied in paragraphs (e), (f), (g), and (j)
of this section, a conditionally exempt
small quantity generator's hazardous
wastes  are not subject to  regulation
under parts 262 through 266, 268, and
parts 270 and 124 of this chapter, and
the notification  requirements of sec-
tion 3010 of RCRA, provided the gen-
erator complies with the requirements
of paragraphs (f), (g), and (j) of this
section.
  (c)  Hazardous waste that is not sub-
ject  to regulation or  that is subject
only  to §262.11,  §262.12,  §262.40(0,
and   § 262.41  is  not included in  the
quantity  determinations  of this part
and  parts 262 through 266,  268, and
270 and is not subject to any of the re-
quirements of those parts.  Hazardous
waste that is subject  to the  require-
ments of § 261.6 (b) and (c)  and sub-
parts C, D, and F of part 266 is includ-
ed in, the quantity  determination of
this part  and is subject to the require-
ments of parts 262  through 266 and
270.
  (d)  In determining the quantity of
hazardous waste generated, a genera-
tor need not include:
  (1)  Hazardous  waste when it is re-
moved from on-site storage; or
  (2)  Hazardous waste produced by on-
site treatment (including reclamation)
of his hazardous waste, so long as  the
hazardous  waste that is treated was
counted once; or
  (3) Spent materials that are generat-
ed, reclaimed, and subsequently reused
on-site, so long as such spent materials
have been counted once.
  (e)  If  a  generator generates acute
hazardous waste in a calendar month
in quantities greater  than  set  forth
below, all quantities of that acute haz-
ardous waste are subject to full regula-
tion under parts 262 through 266, 268,
and parts 270 and 124 of this chapter,
and the notification requirements of
section 3010 of RCRA:
  (DA total of one kilogram of  acute
hazardous  wastes listed in  §§261.31,
261.32, or 261.33(e).
  (2)  A total of 100 kilograms of any
residue or contaminated soil, waste, or
other debris resulting from the clean-
up of a spill, into or on any land or
water, of any acute hazardous wastes
listed in §§ 261.31, 261.32, or 261.33(e).
  [Comment: "Full regulation" means those
regulations  applicable  to  generators  of
greater than 1,000 kg of non-acutely hazard-
ous waste in a calendar month.]
  (f)  In order for acute  hazardous
wastes generated by  a generator of
acute hazardous wastes in quantities
equal to or less than those set forth in
paragraph (e)(l) or (2) of this section
to be excluded from full  regulation
under this section, the generator must
comply  with  the  following require-
ments:
  (1)  Section 262.11 of this chapter;
  (2)  The  generator may accumulate
acute hazardous waste  on-site. If he
accumulates at any time acute hazard-
ous wastes in  quantities greater than
those set forth in paragraph (eXl) or
(e)(2) of this section, all of those accu-
mulated wastes are subject  to regula-
tion under parts 262 through 266, 268,
and parts 270 and 124 of this chapter,
and  the applicable  notification  re-
quirements of section 3010 of RCRA.
The time period of § 262.34(a) of this
chapter, for accumulation  of wastes
on-site, begins when the accumulated
wastes exceed the applicable exclusion
limit;
  (3)   A conditionally  exempt  small
quantity generator may  either treat or
dispose of his acute hazardous  waste
in an on-site facility or ensure delivery
to an of f-site treatment, storage or dis-
                                     40

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Environmental Protection Agency
                             §261.6
posal facility, either of which, if locat-
ed in the U.S., is:
  (i) Permitted under part 270 of this
chapter;
  (ii) In interim status under parts 270
and 265 of this chapter;
  (iii) Authorized  to  manage hazard-
ous waste by a State with a hazardous
waste management program approved
under part 271 of this chapter;
  (iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
  (v) A facility which:
  (A) Beneficially uses or reuses, or le-
gitimately  recycles  or  reclaims its
waste: or
  (B) Treats its waste prior to benefi-
cial  use  or reuse, or legitimate recy-
cling or reclamation.
  (g) In order for hazardous waste gen-
erated by a conditionally exempt small
quantity  generator in quantities of less
than 100 kilograms of hazardous waste
during a calendar month  to be ex-
cluded from full regulation under this
section,  the  generator must  comply
with the  following requirements:
  (1) Section 262.11 of this chapter;
  (2) The conditionally exempt small
quantity  generator may  accumulate
hazardous waste on-site. If he accumu-
lates at any time more than a total of
1000  kilograms   of  his  hazardous
wastes,   all  of  those   accumulated
wastes are subject to  regulation under
the special provisions of  part 262 ap-
plicable to  generators of  between 100
kg and 1000 kg  of hazardous waste in a
calendar  month as well as the require-
ments of parts 263 through 266,  268,
and parts 270 and 124 of this chapter,
and the  applicable  notification re-
quirements of section 3010 of RCRA.
The time period of § 262.34(d) for ac-
cumulation of wastes on-site begins for
a conditionally exempt small  quantity
generator  when   the   accumulated
wastes exceed 1000 kilograms;
  (3)  A  conditionally exempt small
quantity  generator may either treat or
dispose of his  hazardous waste in an
on-site facility or ensure delivery to an
off-site treatment, storage or disposal
facility, either  of  which,  if located in
the U.S., is:
  (i) Permitted under part 270 of this
chapter;
  (ii) In interim status under parts 270
and 265 of this chapter;
  (iii) Authorized  to  manage  hazard-
ous waste by a State with a hazardous
waste management program approved
under part 271 of this chapter;
  (iv) Permitted, licensed, or registered
by a State to manage municipal or in-
dustrial solid waste; or
  (v) A facility which:
  (A) Beneficially uses or reuses, or le-
gitimately  recycles  or  reclaims  its
waste; or
  (B) Treats  its waste prior to benefi-
cial use  or reuse, or legitimate  recy-
cling or reclamation.
  (h) Hazardous waste subject to the
reduced  requirements of this  section
may be mixed  with non-hazardous
waste and remain subject to these re-
duced  requirements even though the
resultant mixture exceeds the  quanti-
ty limitations identified in this section,
unless  the  mixture meets any of the
characteristics   of hazardous  waste
identified in subpart C.
  (i) If any person mixes a solid waste
with a hazardous waste that exceeds a
quantity exclusion level of this sec-
tion, the mixture is subject to full reg-
ulation.
  (j) If a conditionally  exempt small
quantity generator's wastes are mixed
with used oil, the mixture is subject to
subpart E of part 266 of this chapter if
it is destined to be burned for energy
recovery. Any material produced from
such a mixture by processing, blend-
ing, or other treatment is also so regu-
lated if it is destined to  be burned for
energy recovery.

[51 PR 10174,  Mar. 24, 1986, as amended at
51 FR 28682, Aug. 8, 1986; 51 FR 40637, Nov.
7, 1986; 53 PR 27163, July 19, 1988]

§261.6   Requirements for recyclable mate-
    rials.
  (aXI) Hazardous wastes  that are re-
cycled are subject to  the requirements
for generators, transporters, and stor-
age facilities of paragraphs (b) and (c)
of this section, except for the materi-
als listed  in paragraphs  (a)(2)  and
(a)(3)   of   this   section.   Hazardous
wastes that are recycled  will be known
as "recyclable materials."
  (2) The following recyclable materi-
als are not subject to  the requirements
                                    41

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§261.6
         40 CFR Ch. I (7-1-92 Edition)
of this section but are regulated under
subparts C through H of part 266 of
this chapter and all applicable provi-
sions in parts 270 and  124 of this chap-
ter:
  (i) Recyclable  materials used in a
manner constituting disposal (subpart
C);
  (ii)  Hazardous wastes  burned  for
energy  recovery in boilers and indus-
trial furnaces that are not regulated
under subpart O of part 264 or 265 of
this chapter (subpart H);
  (iii) Used oil  that  exhibits one or
more of the characteristics of hazard-
ous waste and is burned for energy re-
covery  in  boilers and industrial fur-
naces  that are not  regulated under
subpart O of  part 264 or 265 of this
chapter (subpart E);
  (iv) Recyclable materials from which
precious metals are reclaimed (subpart
P);
  (v) Spent lead-acid batteries that are
being reclaimed (subpart G).
  (3)  The following recyclable materi-
als are not subject to  regulation under
parts 262 through parts  266 or parts
268, 270 or 124 of this chapter, and are
not subject to the notification require-
ments of section 3010  of RCRA:
  (i) Industrial ethyl alcohol that is re-
claimed except that,  unless provided
otherwise  in  an international agree-
ment as specified in §  262.58:
  (A) A person initiating a shipment
for reclamation in a  foreign country.
and any  intermediary arranging for
the shipment, must comply with the
requirements  applicable to  a  primary
exporter in §§ 262.53. 262.56 (a)(l)-(4),
(6), and (b), and 262.57, export  such
materials only upon consent of the re-
ceiving country  and   in  conformance
with  the  EPA  Acknowledgment  of
Consent as defined in subpart E of
part  262, and  provide a copy of the
EPA  Acknowledgment of Consent to
the shipment to the transporter  trans-
porting the shipment  for export;
  (B)   Transporters   transporting  a
shipment for export may not accept a
shipment if he  knows the shipment
does not conform to the EPA Acknowl-
edgment of Consent, must ensure that
a copy of the EPA Acknowledgment of
Consent  accompanies  the shipment
and must ensure that it is delivered to
the facility designated by the person
initiating the shipment.
  (ii) Used batteries (or used battery
cells) returned to  a battery manufac-
turer for regeneration;
  (iii) Used oil that  exhibits one  or
more of the characteristics of hazard-
ous waste  but is recycled in some other
manner than being burned for energy
recovery;
  (iv) Scrap metal;
  (v) Fuels produced from the refining
of oil-bearing hazardous wastes  along
with normal  process streams at a pe-
troleum refining facility if such wastes
result  from  normal petroleum  refin-
ing,  production,   and transportation
practices;
  (vi) Oil reclaimed  from hazardous
waste resulting from normal petrole-
um refining, production, and transpor-
tation practices, which oil is  to  be re-
fined  along  with  normal   process
streams at a  petroleum refining  facili-
ty;
  (viiXA)  Hazardous  waste fuel pro-
duced   from  oil-bearing  hazardous
wastes from  petroleum refining, pro-
duction, or transportation practices, or
produced  from oil  reclaimed from such
hazardous wastes, where such hazard-
ous  wastes are reintroduced into  a
process that does not use distillation
or does not  produce products  from
crude oil  so long as the resulting fuel
meets the used oil specification  under
§ 266.40(e) of this chapter and so long
as no other hazardous wastes are used
to produce the hazardous waste fuel;
   (B) Hazardous waste fuel  produced
from oil-bearing hazardous waste from
petroleum refining  production, and
transportation practices, where such
hazardous wastes are  reintroduced
into a refining process after a point at
which contaminants  are  removed,  so
long as the fuel meets the used oil fuel
specification under § 266.40(e) of this
chapter; and
   (C) Oil reclaimed  from oil-bearing
hazardous wastes  from petroleum re-
fining, production, and transportation
practices,  which  reclaimed  oil   is
burned as a fuel  without reintroduc-
tion to a refining process, so long as
the  reclaimed  oil meets the  used  oil
fuel specification  under § 266.40(e) of
this chapter; and
                                    42

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Environmental Protection Agency
                             §261.7
  (viii) Petroleum coke produced from
petroleum  refinery hazardous  wastes
containing oil at the same facility at
which such  wastes were generated,
unless the resulting coke product ex-
ceeds one or more of the characteris-
tics of hazardous waste in part 261,
subpart C.
  (b)  Generators and transporters of
recyclable materials are subject to the
applicable  requirements of  parts  262
and 263 of this chapter and the notifi-
cation requirements  under   section
3010 of RCRA, except as provided in
paragraph (a) of this section.
  (c)(l) Owners or operators of facili-
ties  that  store  recyclable  materials
before they are recycled are regulated
under all applicable provisions  of sub-
parts A  through L,  AA, and  BB of
parts 264  and 265,  and  under parts
124,  266, 268, and 270 of this chapter
and   the  notification   requirements
under section 3010 of RCRA, except as
provided in paragraph (a) of this  sec-
tion.  (The recycling  process  itself  is
exempt from regulation except as pro-
vided in § 261.6(d).)
  (2) Owners or operators of facilities
that recycle recyclable materials with-
out storing them before they are  rcy-
cled  are  subject  to  the following re-
quirements,  except  as  provided  in
paragraph (a) of this section:
  (i)  Notification requirements under
section 3010 of RCRA;
  (ii) Sections 265.71 and 265.72 (deal-
ing with  the use of the manifest  and
manifest discrepancies)  of this chap-
ter.
  (iii) Section 261.6(d) of this chapter.
  (d) Owners or operators of facilities
subject to RCRA permitting  require-
ments with hazardous waste manage-
ment  units  that recycle hazardous
wastes are subject to the requirements
of subparts AA and BB of part 264 or
265 of this chapter.
[50 PR 49203, Nov. 29, 1985, as amended at
51 FR 28682, Aug. 8, 1986; 51 PR 40637, Nov.
7,  1986; 52 FR 11821, Apr. 13, 1987; 55 FR
25493, June 21, 1990; 56 FR 7207, Feb. 21,
1991; 56 FR 32692, July 17,  1991]

§261.7  Residues  of  hazardous waste  in
   empty containers.
  (a)(l) Any hazardous waste remain-
ing in either (i) an empty container or
(ii) an inner liner removed from an
empty container, as defined in para-
graph (b) of this section, is not subject
to regulation under parts 261 through
265,  or part 268,  270  or 124 of this
chapter or to the notification require-
ments of section 3010 of RCRA.
  (2) Any hazardous waste in either (i)
a container that is not empty or (ii) an
inner liner removed from a container
that is not empty, as defined in para-
graph (b)  of this section, is subject to
regulation  under  parts  261 through
265, and parts 268, 270 and 124 of this
chapter and to  the notification  re-
quirements of section 3010 of RCRA.
  (b)(l) A container or an inner  liner
removed from  a container  that  has
held any  hazardous waste,  except a
waste that is a  compressed gas or that
is identified as  an acute  hazardous
waste  listed in  §§261.31,  261.32,  or
261.33(e) of this chapter is empty if:
  (i) All wastes  have been removed
that can be removed using the prac-
tices commonly employed to remove
materials  from that type of container,
e.g., pouring, pumping, and aspirating,
and
  (ii) No  more than  2.5  centimeters
(one inch)  of  residue remain  on the
bottom of the container  or inner liner,
or
  (iiiXA) No more than 3 percent by
weight of the total capacity  of the
container remains in the container or
inner liner if the container is less than
or equal to 110 gallons in size, or
  (B) No   more than  0.3 percent  by
weight of the total capacity  of the
container remains in the container or
inner liner if the container is  greater
than 110 gallons in size.
  (2) A container that has held a haz-
ardous waste that is a compressed gas
is empty when  the pressure in the con-
tainer approaches atmospheric.
  (3) A container or an inner liner re-
moved from a container that has held
an acute  hazardous waste listed in
§§ 261.31, 261.32, or 261.33(e) is empty
if:
  (i) The  container or inner liner has
been triple rinsed using a solvent capa-
ble of removing the commercial chemi-
cal product or manufacturing chemi-
cal intermediate;
  (ii) The  container or inner liner has
been cleaned by another method that
has been shown in the scientific litera-
                                    43

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§ 261.8
         40 CFR Ch. I (7-1-92 Edition)
ture, or by tests conducted by the gen-
erator, to achieve equivalent removal;
or
  (iii) In the case of a container, the
inner liner that prevented contact  of
the commercial chemical product  or
manufacturing  chemical  intermediate
with the container, has been removed.

[45 PR 78529, Nov. 25, 1980, as amended at
47 PR 36097, Aug. 18,  1982; 48 FR 14294,
Apr. 1, 1983; 50 FR 1999, Jan. 14, 1985; 51
FR 40637, Nov. 7, 1986]

§ 261.8  PCB wastes regulated under Toxic
    Substance Control Act
  The disposal  of PCB-containing di-
electric fluid and  electric  equipment
containing such fluid authorized  for
use  and regulated under part  761  of
this chapter and that are hazardous
only because they fail the test for the
Toxicity   Characteristic  (Hazardous
Waste Codes D018 through D043 only)
are  exempt  from  regulation  under
parts 261  through 265, and parts 268,
270, and  124 of this chapter, and the
notification  requirements  of section
3010 of RCRA.

[55 FR 11862, Mar. 29, 1990]

Subport  B—Criteria  for  Identifying
     the Characteristics of Hazardous
     Waste and for Listing Hazardous
     Waste

§ 261.10 Criteria for identifying the char-
    acteristics of hazardous waste.
   (a) The Administrator  shall identify
and define a characteristic of hazard-
ous waste in subpart C only upon de-
termining that:
   (DA solid waste that exhibits  the
characteristic may:
   (i) Cause, or significantly contribute
to, an increase in mortality  or an  in-
crease  in  serious irreversible, or inca-
pacitating reversible, illness; or
   (ii) Pose a substantial present or po-
tential hazard to human health or the
environment  when  it  is  improperly
treated, stored, transported, disposed
of or otherwise managed; and
   (2) The characteristic can be:
   (i) Measured by an available stand-
ardized test method which is reason-
ably  within the capability of genera-
tors of solid waste  or private sector
laboratories that are available to serve
generators of solid waste; or
  (ii)  Reasonably detected by genera-
tors  of  solid  waste  through  their
knowledge of their waste.

§261.11  Criteria  for  listing  hazardous
    waste.
  (a)  The Administrator shall list a
solid  waste as a hazardous waste only
upon determining that the solid waste
meets one of the following criteria:
  (1)  It exhibits any of the character-
istics of hazardous waste identified in
subpart C.
  (2)  It has been found to be fatal to
humans in low doses or, in the absence
of data on human toxicity, it has been
shown in studies to have an oral LD 50
toxicity (rat) of less than 50  milli-
grams per kilogram, an inhalation LC
50  toxicity (rat) of less than 2  milli-
grams per liter, or a dermal LD 50 tox-
icity  (rabbit)  of less  than 200  milli-
grams per kilogram or is otherwise ca-
pable of causing or significantly con-
tributing to an increase in serious irre-
versible, or incapacitating reversible,
illness. (Waste listed  in accordance
with  these criteria will be designated
Acute Hazardous Waste.)
  (3)  It contains any of the toxic con-
stituents listed  in appendix VIII and,
after considering the following factors,
the Administrator concludes that  the
waste is capable of posing a substan-
tial  present  or potential  hazard  to
human health or the  environment
when  improperly   treated,  stored,
transported or  disposed  of, or other-
wise managed:
  (i)  The nature of the  toxicity pre-
sented by the constituent.
  (ii) The concentration of the constit-
uent in the waste.
  (iii) The potential of the constituent
or  any toxic degradation product of
the constituent to migrate from  the
waste into the environment under  the
types of improper management consid-
ered  in paragraph (a)(3)(vii)  of this
section.
  (iv) The persistence of  the constitu-
ent or any  toxic degradation product
of the constituent.
  (v) The potential for the constituent
or  any toxic degradation product of
the constituent to degrade into non-
                                     44

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Environmental Protection Agency
                            §261.21
harmful constituents and  the  rate of
degradation.
  (vi) The degree to which the constit-
uent  or any degradation  product of
the constituent bioaccumulates in eco-
systems.
  (vii) The plausible types of improper
management to which the waste could
be subjected.
  (viii)  The  quantities of  the waste
generated  at  individual   generation
sites or on a regional or national basis.
  (ix) The nature and severity of the
human  health  and   environmental
damage that has occurred as a result
of  the   improper  management  of
wastes containing the constituent.
  (x)  Action taken by other govern-
mental agencies  or  regulatory  pro-
grams based  on the health or environ-
mental hazard posed by the waste or
waste constituent.
  (xi) Such other factors as may be ap-
propriate.
Substances will be listed on appendix
VIII only if they have been shown in
scientific  studies to have  toxic, carci-
nogenic, mutagenic or teratogenic ef-
fects on humans or other life forms.
  (Wastes listed  in accordance with
these criteria will be designated Toxic
wastes.)
  (b) The Administrator may list class-
es or  types of solid waste as hazardous
waste if he has reason to  believe  that
individual wastes, within the class or
type of waste, typically or frequently
are hazardous under the definition of
hazardous waste  found   in  section
1004(5) of the Act.
  (c)  The Administrator  will use the
criteria for listing specified in this sec-
tion to establish the  exclusion limits
referred to in § 261.5(c).
[45 PR 33119,  May 19, 1980, as amended at
55 FR 18726, May 4, 1990; 57 FR 14, Jan. 2,
1992]

    Subpart  C—Characteristics of
          Hazardous Waste

§ 261.20 General.
  (a)  A solid  waste,  as   defined  in
§ 261.2, which  is not  excluded from
regulation as a hazardous waste under
§ 261.4(b), is a hazardous waste if it ex-
hibits any of the  characteristics identi-
fied in this subpart.
[Comment: § 262.11 of this  chapter sets
forth the generator's responsibility to deter-
mine whether his waste  exhibits  one  or
more of the characteristics identified in this
subpart]

  (b) A hazardous waste which is iden-
tified by  a characteristic in this sub-
part is assigned every EPA Hazardous
Waste Number that is applicable as sot
forth in  this  subpart. This number
must be used  in complying with the
notification   requirements  of  section
3010 of the Act and all applicable rec-
ordkeeping   and  reporting  require-
ments under parts  262 through 265,
268, and 270 of this chapter.
  (c) For purposes of this subpart, the
Administrator  will consider a sample
obtained  using any of the applicable
sampling  methods specified in appen-
dix I to  be a  representative sample
within the meaning of part 260  of this
chapter.

[Comment. Since the appendix I sampling
methods are not being formally adopted by
the Administrator, a person who desires to
employ an alternative sampling method is
not required to demonstrate the equivalency
of his method  under the procedures set
forth in §§ 260.20 and 260.21.]
[45 FR 33119, May 19, 1980, as amended at
51 FR 40636, Nov. 7, 1986; 55 FR 22684,
June 1, 1990; 56 FR 3876, Jan. 31, 1991]

§ 261.21  Characteristic of ignitability.
  (a) A solid waste exhibits the charac-
teristic of ignitability if a representa-
tive sample  of the  waste has  any of
the following properties:
  (1) It is a liquid, other than an aque-
ous solution containing less than  24
percent  alcohol by volume  and  has
flash point  less than  60°C (140"F), as
determined   by  a   Pensky-Martens
Closed  Cup  Tester,  using  the test
method  specified in ASTM Standard
D-93-79 or  D-93-80  (incorporated by
reference, see  § 260.11), or a Setaflash
Closed  Cup  Tester,  using  the test
method  specified in ASTM Standard
D-3278-78 (incorporated by reference,
see §260.11), or as  determined by an
equivalent test method approved by
the Administrator  under  procedures
set forth  in §§  260.20 and 260.21.
  (2) It is not  a liquid and is capable,
under standard temperature and pres-
sure, of causing fire through friction,
absorption of moisture or spontaneous
                                     45

-------
§261.22
         40 CFR Ch. I (7-1-92 Edition)
chemical changes and. when ignited,
burns so  vigorously and persistently
that it creates a hazard.
  (3) It  is an ignitable compressed gas
as defined in 49  CFR 173.300 and as
determined by the test methods de-
scribed  in  that regulation or  equiva-
lent test methods approved by the Ad-
ministrator under §§ 260.20 and 260.21.
  (4) It  is an oxidizer as defined in 49
CFR 173.151.
  (b) A solid  waste that exhibits the
characteristic of  ignitability  has the
EPA  Hazardous  Waste  Number of
D001.
[45 PR 33119, May  19, 1980, as amended at
46 PR 35247. July 7. 1981; 55 PR 22684. June
1,19903

§ 261.22  Characteristic of corrosivity.
  (a) A solid waste exhibits the charac-
teristic  of  corrosivity  if a representa-
tive sample of the waste has either of
the following properties:
  (1) It is  aqueous and has a pH less
than or equal to 2 or greater than or
equal to 12.5, as determined by a pH
meter   using  either  an  EPA   test
method or an equivalent test method
approved by the Administrator under
the procedures set forth in §§260.20
and 260.21. The  EPA  test method for
pH is specified as Method 5.2 in "Test
Methods for  the Evaluation  of Solid
Waste,  Physical/Chemical  Methods"
(incorporated   by    reference,   see
§ 260.11).
  (2) It is  a liquid and corrodes steel
(SAE 1020) at a rate greater than 6.35
mm (0.250 Inch) per year at a test tem-
perature of 55°C (130'F) as determined
by the test method specified in NACE
(National Association of Corrosion En-
gineers) Standard TM-01-69 as stand-
ardized in "Test Methods for the Eval-
uation  of  Solid  Waste,  Physical/
Chemical Methods" (incorporated by
reference,  see § 260.11)  or an equiva-
lent test method approved by the Ad-
ministrator under the procedures set
forth in §§ 260.20 and 260.21.
  (b) A solid waste that exhibits the
characteristic  of corrosivity  has the
EPA Hazardous  Waste Number of
D002.

[45 PR 33119, May 19, 1980, as amended at
46 PR 35247. July 7.1981; 55 PR 22684, June
1.1990]
§ 261.23  Characteristic of reactivity.
  (a) A solid waste exhibits the charac-
teristic of reactivity if a representative
sample of the waste has any of the fol-
lowing properties:
  (1) It is normally unstable and read-
ily  undergoes violent change without
detonating.
  (2) It reacts violently with water.
  (3)  It  forms  potentially  explosive
mixtures with water.
  (4) When mixed with water, it gener-
ates toxic gases, vapors or fumes in a
quantity sufficient to present a danger
to human health or the environment.
  (5) It is a cyanide or sulfide bearing
waste which, when exposed to pH con-
ditions between 2 and  12.5, can gener-
ate toxic gases, vapors or fumes in a
quantity sufficient to present a danger
to human health or the environment.
  (6) It is capable of detonation or ex-
plosive reaction if it is subjected to a
strong initiating source or if heated
under confinement.
  (7) It is readily capable of detona-
tion or explosive decomposition or re-
action at standard  temperature and
pressure.
  (8) It is a forbidden  explosive as de-
fined in  49  CFR 173.51, or a Class  A
explosive as defined in 49 CFR 173.53
or a Class B explosive  as defined in 49
CFR 173.88.
  (b) A solid waste  that  exhibits the
characteristic of  reactivity  has  the
EPA  Hazardous  Waste  Number  of
D003.

[45 PR 33119. May 19. 1980,  as amended  at
55 PR 22684, June 1.19901

§ 261.24  Toxicity characteristic.
  (a) A solid waste exhibits the charac-
teristic  of toxicity if, using the test
methods described in  appendix II or
equivalent methods approved by the
Administrator  under  the procedures
set forth in §§ 260.20  and 260.21, the
extract from a representative sample
of the waste contains  any of the con-
taminants listed in table  1 at the con-
centration equal to or greater than the
respective value  given in that  table.
Where the waste contains less than 0.5
percent  filterable  solids, the  waste
itself, after filtering using the method-
ology outlined in appendix II, is con-
                                    46

-------
Environmental Protection Agency

sidered to be the extract  for  the pur-
pose of this section.
  (b)  A solid waste that  exhibits the
characteristic of toxicity has  the EPA
Hazardous Waste Number specified in
Table I which corresponds to  the toxic
contaminant  causing it to be hazard-
ous.

TABLE 1—MAXIMUM CONCENTRATION OF CON-
  TAMINANTS FOR THE TOXICITY CHARACTERIS-
  TIC
EPA HW
No.1
••
	 1
D004
D005
D018
D006
D019
D020
D021
D022
D007
D023
D024
D025
D026
D016
D027
D028
D029
D030
D012
D031
0032
D033
D034
D008
D013
D009
D014
D035
D036
D037
0038
D010
D011
nnoo
D015
D040
D041
D042
D017
D043

Contaminant
Arsenic
Barium
Benzene
Cadmium 	
Carbon tetrachloride 	
Chlordane
Chlorobenzene
Chloroform 	
Chromium 	
o-Cresol 	
m-Cresol 	

Cresol
24-D 	
1,4-Dichlorobenzene 	
1,2-Dichloroethane 	
1 , 1 -Dichloroethylene 	
2,4-Dinitrotoluene 	
Heptachlor (and its
epoxide).
Hexachlor obenzene 	
Hexachlorobutadiene 	
Lead 	


Methoxychlor 	
Methyl ethyl ketone 	
Pentrachlorophenol 	

Silver 	


Trichloroethylene 	
2,4,5-Trichtorophenol 	
2,4,6-Trichlorophenol 	
2 4 5-TP (Silvex)


CAS No *
7440-38-2
7440-39-3
71-43-2
7440-43-9
56-23-5
57-74-9
108-90-7
67-66-3
7440-47-3
95-48-7
108-39-4
106-44-5

94-75-7
106-46-7
107-06-2
75-35-4
121-14-2
72-20-8
76-44-8
118-74-1
87-68-3
67-72-1
7439-92-1
58-89-9
7439-97-6
72-43-5
78-93-3
98-95-3
87-86-5
110-86-1
7782-49-2
7440-22-4
127-18-4
• 8001-35-2
79-01-6
95-95-4
88-06-2
93-72-1
75-01-4
L_ .._„.
Regula-
tory
Level
(mg/L)
5.0
100.0
0.5
1.0
0.5
0.03
100.0
6.0
5.0.
4 200.0
4 200.0
4 200.0
4 200.0
10.0
7.5
0.5
0.7
30.13
0.02
0.008
30.13
0.5
3.0
5.0
0.4
0.2
10.0
200.0
2.0
100.0
3 5.0
1.0
5.0
0.7
0.5
0.5
400.0
2.0
1.0
0.2

  1 Hazardous waste number.
  2 Chemical abstracts service number.
  3 Quantitation limit is greater than the calculated regulatory
 level. The quantitation limit therefore becomes the regulatory
 level.
                              §261.30

 4 If o-, m-, and p-Cresol concentrations cannot be differen-
tiated, the total cresol (D026) concentration  is used. The
regulatory level of total cresol is 200 mg/l.

[55  FR 11862, Mar. 29, 1990, as amended at
55 FR 22684, June 1,  1990; 55 FR  26987,
June 29, 1990]

    Subpart D—Lists of Hazardous
               Wastes

§ 261.30  General.
  (a)  A  solid  waste  is a  hazardous
waste if  it  is listed  in this  subpart,
unless it  has been excluded from this
list under §§ 260.20 and 260.22.
  (b)  The Administrator will indicate
his basis for listing the classes or types
of wastes listed in this subpart by em-
ploying one or more of the following
Hazard Codes:

Ignitable Waste	  (I)
Corrosive Waste	  (C)
Reactive  Waste	  (R)
Toxicity Characteristic Waste	  (E)
Acute Hazardous Waste	  (H)
Toxic Waste	  (T)
 Appendix VII  identifies  the constitu-
 ent which caused the Administrator to
 list the waste as a Toxicity Character-
 istic Waste  (E) or Toxic Waste (T) in
 §§261.31 and 261.32.
   (c) Each  hazardous  waste listed in
 this subpart is assigned  an EPA Haz-
 ardous Waste Number which precedes
 the name of the waste.  This number
 must be used  in complying with  the
 notification  requirements  of  Section
 3010 of the Act and  certain  record-
 keeping and  reporting  requirements
 under parts  262 through 265, 268, and
 part 270 of this chapter.
   (d) The following hazardous wastes
 listed in § 261.31 or § 261.32 are subject
 to the exclusion limits for acutely haz-
 ardous  wastes established  in  § 261.5:
 EPA Hazardous Wastes Nos. FO20,
 PO21, FO22, PO23, FO26, and FO27.
 [45 FR 33119, May 19, 1980, as amended at
 48 FR 14294, Apr. 1, 1983; 50 FR 2000, Jan.
 14, 1985; 51 FR 40636, Nov. 7,  1986; 55 FR
 11863, Mar. 29, 1990]
                                       47

-------
§261.31
                                            40 CFR Ch. I (7-1-92 Edition)
§ 261.31   Hazardous wastes from non-specific sources.
   (a)  The  following solid  wastes are listed hazardous  wastes  from  non-specific
sources unless they are  excluded under
dix IX.
                                 260.20 and 260.22 and listed  in appen-
Industry and EPA hazardous
        waste No.
Generic:
  F001...
  F002..
  F003..
  F004..
  F005..
  F006..
  FOOT..
  F008..

  F009..

  F010..

  F011..

  F012..

  F019..


  F020..
  F021,
                              Hazardous waste
The following spent halogenated solvents used in degreasmg: Tetrachloroethylene,
  tnchloroethylene, methylene  chloride,  1,1,1-trichloroethane. carbon tetrachloride,
  and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreas-
  ing containing, before  use, a total of ten percent or more (by volume) of one or
  more  of the above halogenateo solvents or those solvents listed  in F002, F004,
  and F005; and still bottoms from the recovery of these spent solvents and spent
  solvent mixtures.
The following spent halogenated solvents: Tetrachloroethylene, methylene chloride,
  trichloroethylene. 1,1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro-1.2,2-trifluor-
  oethane, ortho-dichlorobenzene. trichlorofluoromethane, and 1,1.2-trichloroethane;
  all spent solvent mixtures/blends containing, before use, a total  of ten percent or
  more  (by volume) of one  or more of the  above halogenated  solvents or those
  listed  in F001, F004, or F005, and still bottoms from the recovery  of these spent
  solvents and spent solvent mixtures.
The following spent non-halogenated solvents: Xylene, acetone, ethyl acetate, ethyl
  benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, and
  methanol; all spent solvent mixtures/blends containing, before use,  only the above
  spent non-halogenated solvents; and all spent solvent mixtures/blends containing,
  before use, one or more of the above  non-halogenated solvents,  and, a total of
  ten percent or more (by volume) of one or  more of those solvents listed in F001,
  F002, F004, and F005; and still bottoms from the recovery of these spent solvents
  and spent solvent mixtures.
The following spent  non-halogenated solvents:  Cresols  and cresylic  acid, and
  nitrobenzene; all spent solvent mixtures/blends containing, before  use, a total of
  ten percent or more (by volume) of one or more of the above non-halogenated
  solvents or those solvents  listed in F001, F002, and F005; and still bottoms from
  the recovery of these spent solvents  and spent solvent mixtures.
The following spent non-halogenated solvents: Toluene, methyl ethyl ketone,  carbon
  disulfide, isobutanol, pyridine, benzene, 2-ethoxyethanol.  and 2-nitropropane;  all
  spent solvent  mixtures/blends  containing, before use, a total of ten percent  or
  more  (by volume) of one or more of the above non-halogenated solvents or those
  solvents  listed in F001, F002, or F004; and still bottoms from the recovery  of
  these spent solvents and spent solvent mixtures.
Wastewater treatment  sludges  from  electroplating  operations  except from the
  following processes: (1) Sulfuric acid anodizing of aluminum;  (2) tin plating on
  carbon steel;  (3) zinc plating (segregated basis) on carbon steel; (4) aluminum or
  zinc-aluminum  plating on carbon steel;  (5)  cleaning/stripping associated with tin,
  zinc and aluminum plating on carbon steel; and (6) chemical etching and milling of
  aluminum.
Spent cyanide plating bath solutions from electroplating operations	
Plating bath residues from the bottom of plating baths from electroplating operations
  where cyanides are used in the process.
Spent stripping  and cleaning bath solutions  from electroplating operations where
  cyanides are used in the process.
Quenching  bath residues from oil baths from metal heat treating operations where
  cyanides are used in the process.
Spent cyanide  solutions from salt bath pot  cleaning  from metal  heat  treating
  operations.
Quenching waste water treatment sludges from metal heat treating  operations where
  cyanides are used in the process.
Wastewater treatment sludges  from the chemical conversion coating of aluminum
  except from zirconium phosphating in aluminum can washing when such phosphat-
  ing is  an exclusive conversion coating process.
Wastes  (except wastewater and  spent carbon  from  hydrogen chloride  purification)
  from the production or  manufacturing use (as a reactant, chemical intermediate, or
  component  in a formulating process) of tri- or tetrachlorophenol,  or  of interme-
  diates used to produce their pesticide derivatives. (This listing does  not  include
  wastes from  the production   of Hexachlorophene from  highly  purified  245-
  trichlorophenol.).
Wastes  (except  wastewater and  spent  carbon from  hydrogen chloride  purification)
  from the production or  manufacturing use (as a reactant chemical intermediate, or
  component  in a formulating process) of pentachtorophenol, or of intermediates
  used to produce its derivatives.
 Hazard
  code
                                                                                                          (T)
(T)
(I)'
                                                                                                         (T)
                                                                                                         (T)
(R.T)
(R, T)

(R.T)

(R, T)

(R.T)

(T)

(T)


(H)
                                                      48

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Environmental Protection  Agency
                                                                            §261.31
Industry and EPA hazardous
        waste No.
  F022..
                               Hazardous waste
Hazard
 code
  F023..
  F024..
  F025





  F026..




  F027..




  F028..

  F032 '
  F034
  F035 '
  F037..
Wastes (except wastewater  and spent carbon Irom hydrogen chloride purification)
  from the manufacturing use (as a reaclant, chemical intermediate, or component in
  a formulating process) of  tetia-,  penta-, or hexachlorobenzenes under alkaline
  conditions.
Wastes (except wastewater  and spent carbon from hydrogen chloride purification)
  from the production of materials on equipment previously used for the production
  or manufacturing  use (as  a reactant, chemical intermediate,  or component  in a
  formulating process) of tri- and tetractilorophenols. (This listing does not include
  wastes  from equipment used only  for the production or use of Hexachlorophene
  from highly purified 2,4,5-trichlorophenol.).
Process wastes, including but not limited to,  distillation residues,  heavy ends,  tars,
  and  reactor clean-out wastes, from the production of certain chlorinated aliphatic
  hydrocarbons  by  free radical catalyzed  processes.  These chlorinated aliphatic
  hydrocarbons  are those having carbon chain  lengths  ranging  from one to and
  including five,  with  varying amounts and positions of chlorine  substitution. (This
  listing does not include wastewaters, wastewater treatment sludges, spent cata-
  lysts, and wastes  listed in §261.31  or §261.32).
Condensed light ends, spent fillers and filter aids, and spent desiccant wastes  from
  the  production of  certain chlorinated  aliphatic  hydrocarbons, by  free  radical
  catalyzed processes.  These chlorinated aliphatic hydrocarbons are  those  having
  carbon  chain lengths ranging from  one to and including five, with varying amounts
  and  positions of chlorine substitution.
Wastes (except  wastewater  and  spent carbon from hydrogen chloride purification)
  from the production of materials on equipment  previously used for the manufactur-
  ing use (as a reactant.  chemical  intermediate, or component in  a formulating
  process) ol tetra-, penta-. or hexachlorobenzene under alkaline conditions.
Discarded unused formulations containing  tri-. tetra-,  or  pentachlorophenol  or dis-
  carded  unused formulations containing compounds derived from these chlorophen-
  ols. (This listing does not  include formulations  containing Hexachlorophene sythe-
  sized from  prepurified 2,4,5-tnchlorophenol as the sole component.)
Residues  resulting from the  incineration or thermal treatment ol soil  contaminated
  with  EPA Hazardous Waste Nos F020, F021, F022. F023. F026, and F027.
Wastewaters. process residuals, preservative  drippage, and spent formulations from
  wood preserving processes generated  at plants  that currently  use or  have
  previously used chlorophenolic formulations (except potentially cross-contaminated
  wastes  that have had the  F032 waste code deleted in accordance with §261.35
  of this  chapter and  where  the  generator  does not  resume  or initiate  use  of
  chlorophenolic  formulations).  This  listing  does  not include K001 bottom sediment
  sludge from the treatment of wastewater from wood  preserving processes that use
  creosote and/or pentachlorophenol. (NOTE: The listing  of wastewaters that  have
  not come into  contact with process contaminants is stayed administratively. The
  listing for plants that have previously used  chlorophenoltc formulations is adminis-
  tratively stayed whenever  these wastes are covered by the F034 or F035 listings.
  These stays will remain in  effect until further administrative action is taken.).
Wastewaters, process residuals, preservative  drippage, and spent formulations from
  wood preserving process generated at plants that use creosote formulations. This
  listing does not  include  K001 bottom sediment sludge from the  treatment of
  wastewater from wood preserving processes that use creosote and/or pentachlor-
  ophenol. (NOTE: The  listing of wastewaters that have not come into contact with
  process contaminants is stayed administratively. The stay will remain in effect until
  further administrative action is taken.).
Wastewaters, process residuals, preservative  drippage, and spent formulations from
  wood preserving  process  generated at  plants  that use  inorganic preservatives
  containing  arsenic  or chromium.  This  listing does  not  include  K001  bottom
  sediment sludge from the  treatment of wastewater from wood preserving process-
  es that  use creosote and/or pentachlorophenol. (NOTE: The listing of wastewaters
  that  have not  come into contact  with process contaminants is stayed administra-
  tively. The stay will  remain in effect until further administrative action is taken.).
Petroleum refinery primary oil/water/solids separation sludge—Any sludge generated
  from the gravitational  separation of oil/water/solids during the storage or  treat-
  ment of  process  wastewaters and oily  cooling  wastewaters from petroleum
  refineries. Such sludges  include,  but are not  limited to, those generated in: oil/
  water/solids separators; tanks and impoundments, ditches and other conveyances;
  sumps;  and stormwater  units  receiving  dry weather  flow. Sludge generated  in
  stormwater units  that do  not receive  dry  weather  flow, sludges generated from
  non-contact once-through cooling  waters  segregated  for treatment from  other
  process or oily cooling waters, sludges  generated  in  aggressive biological  treat-
  ment units as defined in  § 261.31(b)(2) (including  sludges generated in  one or
  more additional units  after wastewaters have been treated in aggressive biological
  treatment units) and K051 wastes are not included in this listing.
                                                                                                            (H)
                                                                                                            (H)
                                                                                                            (T)
                                                                                                            (T)
(H)
(H)
(T)

(T)
                                                                                                             (T)
                                                                                                             (T)
                                                                                                             (T)
                                                         49

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§261.31
                                 40 CFR Ch. I (7-1-92 Edition)
Industry and EPA hazardous
      waste No.
                       Hazardous waste
Hazard
 code
  F038..
  F039..
Petroleum refinery secondary (emulsified) oil/water/solids separation sludge—Any
  sludge and/or float generated from the physical and/or chemical separation of oil/
  water/solids in process wastewaters and oily cooling wastewaters from petroleum
  refineries. Such wastes include, but are not limited to. all sludges and floats
  generated in: induced air flotation (IAF) units, tanks and impoundments, and all
  sludges generated in OAF units. Sludges generated in stormwater units that do not
  receive dry weather flow, sludges  generated from non-contact  once-through
  cooling waters segregated for treatment from other process or oily cooling waters,
  sludges and floats generated in aggressive biological treatment units as defined in
  §261.31(b)(2) (including sludges and floats generated in one or more additional
  units after wastewaters have been treated in aggressive biological treatment units)
  and F037, K048, and K051 wastes are not included in this listing.
Leachate (liquids that have percolated through land disposed wastes) resulting from
  the disposal of more than one restricted waste classified as hazardous under
  subpart D of this part. (Leachate resulting from the disposal of one or more of the
  following EPA Hazardous Wastes and no other Hazardous Wastes retains its EPA
  Hazardous Waste Number(s): F020. F021, F022. F026, F027, and/or F028.).
                                                                                (T)
                                                                                (T)
  1 The F032, F034, and F305 listings are administratively stayed with respect to the process area receiving drippage of these
wastes provided persons desiring to continue operating notify EPA by August 6, 1991 of their intent to upgrade or install drip
pads, and by November 6, 1991 provide evidence to EPA that they have adequate financing to pay for drip pad upgrades or
installation, as provided in the administrative stay. The stay of the listings will remain in effect until February 6,  1992 for
existing drip pads and until May 6, 1992 for new drip pads.
  *(I,T) should be used to specify mixtures containing ignitable and toxic constituents.

  (b) Listing Specific Definitions: (1) For the purposes of the P037 and P038 list-
ings, oil/water/solids is defined  as oil and/or water and/or solids.
  (2) (i) For  the purposes of the F037  and F038 listings, aggressive biological
treatment units  are defined as units  which employ one of the  following four
treatment methods: activated sludge; trickling filter; rotating biological contac-
tor for the continuous accelerated biological oxidation of wastewaters; or  high-
rate aeration. High-rate aeration is a system of surface impoundments or tanks,
in  which intense mechanical aeration  is  used to completely mix the wastes, en-
hance biological  activity, and (A) the units employs a  minimum of 6 hp per mil-
lion gallons of treatment volume; and either (B) the hydraulic retention time of
the unit is no longer than 5 days; or (C) the  hydraulic retention time  is  no
longer than 30 days and the unit does not generate a sludge that is a hazardous
waste by the  Toxicity Characteristic.
  (ii) Generators and treatment, storage  and disposal  facilities have the burden
of  proving  that their sludges  are exempt from listing as F037 and F038 wastes
under  this  definition.  Generators and treatment, storage and disposal facilities
must maintain, in  their operating or other onsite records, documents and data
sufficient to prove that: (A) the unit is an aggressive biological treatment unit as
defined in this subsection; and (B) the sludges sought to be exempted from  the
definitions  of F037 and/or F038 were actually generated in the  aggressive bio-
logical treatment unit.
  (3) (i) For the purposes of the F037 listing, sludges are considered to be gener-
ated at the moment of deposition in the unit, where deposition is defined as at
least a temporary cessation of lateral particle movement.
  (ii) For the purposes of the F038 listing,
  (A) sludges are considered to be generated at the moment of deposition in  the
unit, where deposition is defined as at least a temporary cessation of lateral par-
ticle movement and
  (B) floats are considered to be generated at the moment they are  formed in
the top of the unit.

[46 PR 4617.  Jan. 16,  1981]
  EDITORIAL NOTE:  For FEDERAL REGISTER citations affecting  § 261.31, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
                                          50

-------
Environmental Protection  Agency
                                                                         §261.32
§ 261.32   Hazardous wastes from specific sources.
   The  following  solid wastes  are listed hazardous  wastes  from  specific sources
unless they are excluded under  §§ 260.20  and 260.22 and listed in appendix IX.
Industry and EPA hazardous
        waste No.
                              Hazardous waste
Wood preservation: K001	1 Bottom sediment sludge from the treatment of wastewaters from wood preserving
                             processes that use creosote and/or pentachlorophenol.
Inorganic pigments:
  K002	
  K003.
  K004.
  K005.
  K006.
  K007	
  K008	
Organic chemicals:
  K009	
  K010	
  K011	
  K013	
  K014	
  K015	
  K016	
  K017	
 Wastewater treatment sludge from the production of chrome yellow and orange
  pigments.
 Wastewater treatment sludge from the production of molybdate orange pigments	
 Wastewater trealment sludge from the production of zinc yellow pigments	
 Wastewater treatment sludge from the production of chrome green pigments	
 Wastewater treatment sludge from the production  of chrome oxide green pigments
  (anhydrous and hydrated).
 Wastewater treatment sludge from the production of iron blue pigments	
 Oven residue from the production of chrome oxide  green pigments	
  K018.
  K019.

  K020.
  K021 ....
  K022....
  K023....
  K024....
  K025....
  K026....
  K027....
  K028 ....
  K029.
  K030.
  K083	
  K085	
  K093	
  K094	
  K095	
  K096	
  K103.
  K104.
  K105.

  K107.

  K108.
  K109.

  K110.

  K111 .
  K112.

  K113.

  K114.
Distillation bottoms from the production of acetaldehyde from ethylene	
Distillation side cuts from the production of acetaldehyde from ethylene	
Bottom stream from the wastewater stripper in the production of acrylonitrile	
Bottom stream from the acetonitnle column in the production of acrylonitrile	
Bottoms from the acetonitnle purification column in the production of acrylonitrile	
Still bottoms from the distillation of benzyl chloride	
Heavy ends or distillation residues from the production of carbon tetracnloride	
Heavy ends  (still bottoms) from  the purification  column in the production  of
  epichlorohydrin.
Heavy ends from the fractionation column in ethyl chloride production	
Heavy ends  from  the distillation of ethylene dichloride  in  ethylene dichloride
  production.
Heavy ends  from  the distillation of vinyl  chloride  in  vinyl chloride  monomer
  production.
Aqueous spent antimony catalyst waste from fluoromethanes production	
Distillation bottom tars from the production of phenol/acetone from cumene	
Distillation light ends from the production of phthatic anhydride from naphthalene	
Distillation bottoms from the production of phthalic anhydride from naphthalene	
Distillation bottoms from the production of nitrobenzene by the nitration of benzene....
Stripping still tails from the production of methy ethyl pyridines	
Centrifuge and distillation residues trom toluene dusocyanate production	
Spent  catalyst from the hydrochlorinator reactor in  the production of  1,1,1-trichlor-
  oethane.
Waste from the product steam stripper in the production of 1,1,1-trichloroethane	
Column bottoms or heavy ends from the combined production of trichloroethylene
  and perchloroethylene.
Distillation bottoms from aniline production	
Distillation or fractionation column bottoms from the production of chlorobenzenes	
Distillation light ends from the production of phthalic anhydride from ortho-xylene	
Distillation bottoms from the production of phthalic anhydride from ortho-xylene	
Distillation bottoms from the production of 1,1,1-trlchloroethane	
Heavy ends from the heavy  ends column from the  production of 1,1,1-trichloroeth-
  ane.
Process residues from aniline extraction from the production of aniline	
Combined wastewater streams generated from nitrobenzene/aniline production	
Separated aqueous stream from the reactor product washing step in the production
  of chlorobenzenes.
Column bottoms from product separation from the  production  of  1,1-dimethyl-
  hydrazine (IJDMH) from carboxylic acid hydrazine?
Condensed column overheads from product separation and condensed reactor vent
  gases from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid
  hydrazides.
Spent filter cartridges from product purification from the production of 1,1-dimethylhy-
  drazine (UDMH) from carboxylic acid hydrazides.
Condensed column overheads  from intermediate separation from  the production of
  1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides.
Product wash waters from the production of dinitrotoluene via nitration of toluene	
Reaction by-product water from the drying column in the  production of toluenedia-
  mine via hydrogenation of dinitrotoluene.
Condensed liquid light ends from the purification of toluenediamine in the production
  of toluenediamine via hydrogenation of dinitrotoluene.
Vicinals from the purification  of toluenediamine  in the production of toluenediamine
  via hydrogenation of dinitrotoluene.
 Hazard
  code
                                                                             (T)
(T)

(T)
(T)
(T)
(T)

CD
(T)

(T)
(T)
(R, T)
(R, T)
(T)
(T)
(T)
(T)
(T)

(T)

m
(T)
(T)
(T)
(T)
(T)
(R, T)
(T)

(T)
(T)

(T)
(T)
m
(T)
(T)
(T)

(T)
(T)
(T)

(C,T)

d.T)
(T)

(T)

(C,T)
(T)

(T)

(T)
                                                      51

-------
§ 261.32
40 CFR Ch. I (7-1-92 Edition)
Industry and EPA hazardous
waste No.
K115 	
K116 	
K117 	
K118 	

K136 	
Inorganic chemicals:
K071 	
K073
K106 	
Pesticides:
K031
K032
K033 	
K034 	
K035
K036
K037
K038
K039 	
K040
K041
K042 	
K04S
K097 	
K098
K099
K123 	
K124
K125
K126
K131 	
K132 	
Explosives:
K044 	
K045 .. .
K046 	
K047
Petroleum refining:
K048
K049 	
K050
K051 	
K052
Iron and steel:
K061 	
K062 	
Primary copper:
K064 	

Hazardous waste
Heavy ends from the purification of tofcjenediamine m the production of toluenedia-
mme via hydrogenation of dinitrotoluene.
Organic condensate from the solvent recovery column in the production of toluene
dfeocyanate via phosgenation of toluenediamine.
Wastewater from the reactor vent gas scrubber in the production of ethytene
dibromide via brommatton of ethene.
Spent adsorbent solids from purification of ethytene dibromide in the production of

Still bottoms from the purification of ethytene dibromide in the production of ethytene
dibromide via brominatkxi of ethene.
Brine purification muds from the mercury cell process in chlorine production, where
separately prepurified brine is not used.
Chlorinated hydrocarbon waste from the purification step of the diaphragm cell
process using graphite anodes in chlorine production.
Wastewater treatment sludge from the mercury cell process in chlorine production 	
By-product salts generated in the production of MSMA and cacodyltc acid 	
Wastewater treatment sludge from the production of chlordane 	
Wastewater and scrub water from the chlorinatkxi of cyclopentadiene in the
production of chlordane.
Filter solids from the filtration of hexachlorocyclopentadiene in the production of
chlordane.
Wastewater treatment sludges generated in the production of creosote 	
Still bottoms from toluene reclamation distillation in the production of disulfoton 	
Wastewater treatment sludges from the production of disulfoton 	
Wastewater from the washing and stripping of phorate production 	
Filter cake from the filtration of diethylphosphorodithioic acid in the production of
phorate.
Wastewater treatment sludge from the production of phorate 	
Wastewater treatment sludge from the production of toxaphene 	
Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the
production of 2.4.5-T.
2 6-Dtchtorophenol waste from the production of 2.4-D 	
Vacuum stripper discharge from the chlordane chlorinator in the production of
chlordane.
Untreated process wastewater from the production of toxaphene 	
Untreated wastewater from the production of 2,4-D 	
Process wastewater (including supemates. filtrates, and washwaters) from the
production of ethytenebisdithiocarbamic acid and its salt.
Reactor vent scrubber water from the production of ethylenebisdithiocarbamic acid
and its salts.
Filtration evaporation, and centrifugation solids from the production of ethylenebis-
dithiocarbamic acid and its salts
Baghouse dust and floor sweepings in milling and packaging operations from the
production or formulation of ethytenebisdithiocarbamic acid and its salts.
Wastewater from the reactor and spent sulfuric acid from the acid dryer from the
production of methyl bromide.
Spent absorbent and wastewater separator solids from the production of methyl
bromide.
Wastewater treatment sludges from the manufacturing and processing of explosives ..
Spent carbon from the treatment of wastewater containing explosives 	
Wastewater treatment sludges from the manufacturing formulation and loading of
lead-based initiating compounds.
Pink/red water from TNT operations
Dissolved air flotation (DAF) float from the petroleum refining industry
Slop oil emulsion solids from the petroleum refining industry 	
Heat exchanger bundle cleaning sludge from the petroleum refining industry
API separator sludge from the petroleum refining industry 	
Tank bottoms (leaded) from the petroleum refining industry
Emission control dust/sludge from the primary production of steel in electric
furnaces.
Spent pickle liquor generated by steel finishing operations of facilities within the iron
and steel industry (SIC Codes 331 and 332).
Acid plant btowdown slurry/sludge resulting from the thickening of blowdown slurry
from primary copper production.
Hazard
code
(T)
(T)
(T)
(T)

(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
0")
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(T)
(C, T)
(T)
(T)
(C, T)
m
(R)
(R)
(T)
(R)
(T)
(T)
(T)
(T)
(T)
(T)
(C.T)
(T)

                                   52

-------
Environmental Protection Agency
                            §261.33
Industry and EPA hazardous
waste No.
Primary lead:
K065 	
Primary zinc:
K066.. .
Primary aluminum:
K088..
Ferroalloys:
K090 	
K091
Secondary lead.
K069 	
K100
Veterinary Pharmaceuticals:
K084
K101
K102 	
Ink formulation:
K086 	
Coking:
K060
K087

Hazardous waste
Surface impoundment solids contained in and dredged from surface impoundments
at primary lead smelting facilities
Sludge from treatment of process wastewater and/or acid plant blowdown from
primary zinc production.
Spent potliners from primary aluniinunr reduction
Emission control dust or sludge from ferrochromiumsiiicon production
Emission control dust or sludge from ferrochromium production
Emission control dust/sludge from secondary lead smelting. (NOTE: This listing is
stayed administratively for sludge generated from secondary acid scrubber sys-
tems. The stay will remain in effect until further administrative action is taken. If
EPA takes further action effecting this stay, EPA will publish a notice of the action
in the Federal Register.
Waste leaching solution from acid leaching of emission control dust/sludge from
secondary lead smelting.
Wastewater treatment sludges generated during the production of veterinary Pharma-
ceuticals from arsenic or organo-arsenic compounds.
Distillation tar residues from the distillation of aniline-based compounds in the
production of veterinary Pharmaceuticals from arsenic or organo-arsenic com-
pounds.
Residue from the use of activated carbon for decolorization in the production of
veterinary Pharmaceuticals from arsenic or organo-arsenic compounds.
Solvent washes and sludges, caustic washes and sludges, or water washes and
sludges from cleaning tubs and equipment used in the formulation of ink from
pigments, driers, soaps, and stabilizers containing chromium and lead.
Ammonia still lime sludge from coking operations 	
Decanter tank tar sludge from coking operations 	

Hazard
code
(T)
(T)
(T)
(T)
(T)
ft)
(T)
(T)
(T)
(T)
(T)
(T)
(T)

[46 FR 4618, Jan. 16, 1981]
  EDITORIAL NOTE: For FEDERAL REGISTER citations affecting § 261.32, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
§261.33  Discarded  commercial chemical
   products, off-specification species, con-
   tainer  residues,  and  spill  residues
   thereof.
  The following materials or items are
hazardous wastes if and when they are
discarded  or intended to be discarded
as described in § 261.2(a)(2)(i),  when
they are mixed with waste  oil or used
oil or  other material and  applied to
the land for dust  suppression or road
treatment, when  they are  otherwise
applied to the land in lieu of their
original intended use or when they are
contained in products that are applied
to the  land in lieu of their original in-
tended use, or when, in lieu of their
original intended  use, they  are pro-
duced  for use  as  (or as a component
of) a fuel, distributed for use as a fuel,
or burned as a fuel.
  (a) Any commercial  chemical prod-
uct, or manufacturing  chemical inter-
mediate  having  the  generic  name
listed in paragraph (e) or (f) of this
section.
  (b) Any off-specification commercial
chemical  product  or  manufacturing
chemical intermediate which, if it met
specifications, would have the generic
name listed in paragraph (e) or (f) of
this section.
  (c) Any residue remaining in a con-
tainer  or in an inner liner  removed
from  a container that has  held any
commercial chemical product or man-
ufacturing   chemical    intermediate
having  the  generic name  listed  in
paragraphs (e)  or  (f) of  this section,
unless the container is empty as de-
fined in § 261.7(b) of this chapter.

[Comment. Unless the residue is being bene-
ficially used or reused, or legitimately recy-
cled or reclaimed; or being accumulated,
stored, transported or treated prior to such
use, re-use,  recycling or reclamation, EPA
                                     53

-------
§261.33

considers the residue to be intended for dis-
card, and thus, a hazardous waste. An exam-
ple of a legitimate  re-use of the residue
would be where the residue remains in the
container and the container is used to hold
the same commercial chemical product or
manufacturing chemical intermediate it pre-
viously held. An example of the discard of
the residue would be where the drum is sent
to a drum reconditioner who reconditions
the drum but discards the residue.]

  (d) Any residue or contaminated soil,
water or  other debris  resulting from
the cleanup of a spill into or on any
land  or  water of  any  commercial
chemical  product  or  manufacturing
chemical  intermediate  having the ge-
neric name listed in paragraph (e) or
(f) of this section, or  any residue or
contaminated   soil,  water or  other
debris resulting from the cleanup of a
spill, into or on any land  or water, of
any off-specification chemical product
and manufacturing chemical  interme-
diate which, if it met specifications,
would have the generic name listed in
paragraph (e) or (f) of this section.

[Comment The phrase "commercial chemi-
cal product or manufacturing chemical in-
termediate having the generic name listed
in ..."  refers to a chemical  substance
which  is manufactured or formulated for
commercial or  manufacturing use which
consists of the commercially  pure grade of
         40 CFR Ch. I (7-1-92 Edition)

the chemical,  any technical grades of the
chemical  that are produced or marketed,
and all formulations in which the chemical
is  the  sole active ingredient. It does not
refer to a material, such as a manufacturing
process waste, that contains any of the sub-
stances listed in paragraph (e) or (f). Where
a manufacturing process waste is deemed to
be a hazardous waste  because it contains a
substance listed in paragraph (e) or (f), such
waste will be listed in either §261.31 or
§ 261.32 or will be identified as a hazardous
waste by the characteristics set forth in sub-
part C of this part.]

  (e) The commercial chemical  prod-
ucts, manufacturing chemical interme-
diates  or off-specification commercial
chemical products  or  manufacturing
chemical intermediates referred to in
paragraphs (a) through (d) of this sec-
tion, are identified as acute hazardous
wastes (H) and are  subject to be the
small  quantity  exclusion defined  in
§ 261.5(e).

[Comment For the convenience of the regu-
lated community  the primary  hazardous
properties of these materials have been indi-
cated by the letters T (Toxicity). and R (Re-
activity). Absence of a letter indicates that
the compound only is listed for acute toxici-
ty.]

  These wastes and their correspond-
ing  EPA Hazardous Waste  Numbers
are:
Haz-
ardous
waste
No.
P023
P002
P067
P058
P002
P003
P070
P004
POOS
P006
P007
P006
P009
P1 19
P099
P010
P012
P011
P011
P012
P038
P036
P054
P067
P013
am*
Chemical
abstracts No.
107-20-0
591-08-2
640-19-7
62-74-8
591-08-2
107-02-8
116-06-3
309-00-2
107-18-6
20859-73-8
2763-46-4
K/14 44 C
SO4-24-S
131-74-8
7803-55-6
506-61-6
7778-39-4
1327-53-3
1303-28-2
1303-28-2
1327-53-3
692-42-2
696-28-6
151-56-4
75-55-8
542-62-1
ino_47_a
Substance
Acetaldenyde, chtoro-
A in uli.i.ifflu ftl •*ik..k.M»iM«im]jLjui-aJliLjl\
Acetarrade, N-(anwK>tnioxometnyi)-
Acetamkfe, 2-fluoro-
Acetic add, fluoro-, sodium salt
l-Acety<-2-thiourea
Acrotan
AKScarb
AkJrin
ASy! alcohol
Aluminum phosphide (R.T)
5-{Arnirx>methyQ-3-isoxazolol
A AjmliuullHlllilll'l
4-Amnopyrane
Ammonium pfcrate (H)
Ammonium vanadate
ArgentateU-). bis(cyano-C)-, potassium
Arsenic add H>AsO4
Arsenic oxide AStOi
Aisenic oxide As>Oi
Arsenic pentoxide
Arsenic trioxide
Arsine, dtalhyl-
Arsonous dKNoride, phenyt-
Azmtne
Aariome, 2-methyl-
Barium cyanide
                                      54

-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
P077
P028
P042
P046
POM
P001
P028
P015
P017
P018
P045
P021
P021
P022
P095
P023
P024
P026
P027
P029
P029
P030
P031
P033
P033
P034
P016
P036
P037
P038
P041
P040
P043
P004
P060
P037
P051
POM
P046
P047
P048
P020
P065
P111
P039
P049
P050
P088
P051
P051
P042
P031
P066
P101
P054
P097
P056
P057
P058
P085
P059
P082
Chemical
abstracts No.
100-01-6
100-44-7
51-43-4
122-09-8
108-98-5
1 81-81-2
100-44-7
7440-41-7
598-31-2
357-57-3
39196-18-4
592-01-8
592-01-8
75-15-0
75-44-5
107-20-0
106-47-8
5344-82-1
542-76-7
544-92-3
544-92-3
460-19-5
506-77-4
506-77-4
131-89-5
542-88-1
696-26-6
60-57-1
692-42-2
311-45-5
297-97-2
55-91-4
309-00-2
465-73-6
60-57-1
'72-20-8
60-51-5
122-09-8
•534-52-1
51-28-5
88-85-7
152-16-9
107-49-3
296-04-4
541-53-7
115-29-7
145-73-3
72-20-8
72-20-8
51-43-4
460-19-5
16752-77-5
107-12-0
151-56-4
52-85-7
7782-41-4
640-19-7
62-74-8
626-86-4
76-44-8
757-58-4
Substance
Benzenamine, 4-nitro-
Benzene, (chtorometfiyl)-
1,2-Benzenediol. 4-t1-hydroxy-2-(methylamino)ethyl]-, (R)-
Benzeneethanamine. alpha.alpha-dimethyl-
Benzenethiol
2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present at concentrations
greater than 0.3%
Benzyl chloride
Beryllium
Bromoacetone
Brutine
2-Butanone. 3.3-o*netfiyM-(rnethyNhioh
O-Cmethylamino)carbonyli oxime
Cakaum cyanide
CaWum cyanide Ca(CN)»
Carbon disuffide
Carbonic dwhtoride
p-CMoroanifine
HoOptorophenyQthiourea
3-unloropropionrirHe
Copper cyanide

Cyanogen

2-CyctohexyM.6-dinrtrophenol
DicNonxnelhyl ether
DMdrin
Dtethyiaraine
O.O-Oietriyi O-pyrazinyl phosphorothioate
1,4.5.8«rnetrianonaprithalene. 1^.3,4,10,10-hexa- chtofo-l.4.4a,5.8.8a.-hexahydro-,
1,4.5.^Oimethanonaphthatene. lA3,4,l0.10-h*xa- chtoro-1,4.4a,5.8,e»nexariydro-.
(1 alpha,4alpha,4abeta,5beta,8beta3abeta)-

2.7:3,6-Dimethanonaphth C2,3-blox»ene. 3.4,5.6,9.»-hexachtoro-1a^^a,3,6,6a.7,7a-octanydro-.
OMnetnoate
4.6-Oinrtro-o-cre«o(, A salts
2,4-Oinitrophenol
Oinoseb
UapfKMpnoranwie, ocwnemyt-
nkilvMUahnrir Arkl t Atf*Attnil mmtat
Dfeurfoton
Drthiobiuret
Endosultan
EndothaN
Endrin
Endnn, & metaboWes
Epviephnne

r^[C(methyamino)carbonyl}oxy3-, methyl ester
Ethyl cyanide
cthyfooeifnne
Famphur
Fluorine
Fluoroacetamide
Fluoroacetic acid, sodum salt
Fuhninic acid, mercury(2-t-) aalt (R,T)
Heptachtor
                                    55
  311-147 O—92-

-------
§ 261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
P116
P068
P063
P063
P096
P060
P007
P092
P065
P082
P064
P016
P112
P118
P050

P059

P066
P068
P064
P069
P071
P072
P073
P073
P074
P074
P075
P076
^&\w
P077
P078
P076
P078
P081
P082
•mfc«« *
P084
P065
P067
P087
P068
P069
P034
P048
P047
P020
P009
P092
P093
P094
P09S
P096
P041
P039
P094
P044
P043
P089
P040
P097

P071
P110
P098
P098
P099
P070

Chemical
abstracts No.
79-19-6
60-34-4
74-90-8
74-90-8
7803-51-2
465-73-6
2763-96-4
62-38-4
628-86-4
62-75-9
624-83-9
542-88-1
509-14-8
75-70-7
115-29-7

76-44-8

16752-77-5
60-34-4
624-83-9
75-86-5
298-00-0
m»po_4
OO"OO~^
13463-39-3
13463-39-3
557-19-7
557-19-7
'54-11-5
10102-43-9
< A/\rt4 *»
1UU-U1-O
10102-44-0
10102-43-9
10102-44-0
55-63-0
62-75-9
jlCjtQ Af\_f\
454»— 4O-O
152-16-9
20816-12-0
20816-12-C
145-73-3
56-38-2
131-89-5
51-28-5
'534-52-1
88-85-7
131-74-8
62-38-4
103-85-5
298-02-2
75-44-5
7803-51-2
311-45-5
296-O4-4
298-02-2
60-51-5
55-91-4
56-38-2
297-97-2
52-85-7

298-00-0
78-00-2
151-50-8
151-50-8
506-61-6
116-06-3

Substance
Hydrazinecarbothioamide
Hydrazine, methyl-
Hydrocyanic acid
Hydrogen cyanide
Hydrogen phosphide
sodrin
3(2H)-lsoxazotone, 5-(aminomethyl)-
Mercury, (acetato-O)phenyl-
Mercury fulminate (R,T)
Methanamine. N-methyl-N-nitroso-
Methane, isocyanato-
Methane, oxybistchkxo-
Methane, tetranitro- (R)
Methanethiol, trichtoro-
6,9-Methano-2,4.3-benzodioxathiepin. 6,7.8,9.10,10-
hexachkxo-1l5.5a.6,9.9a-hexahydro-, 3-oxide
4,7-Methanc-1H-indene, 1.4,5,6,7.8,8-heptachloro-
3a,4.7.7a-tetrahydro-
Methomyl
Methyl hydrazine
Methyl isocyanate
2-Methyllactonitrile
Methyl paratnion
alpha-Naphthytthiourea
Nickel carbonyl
Nickel carbonyl NKCO),, (T-4)-
Nickel cyanide
Nickel cynakte NKCN),
Nicotine, & salts
Nitric oxide
p-Nitroanihne
Nrtrogen dwxide
Nitrogen oxide NO
Nitrogen oxide NOi
Nrtroglycenne (R)
N-Nitrosodimethytamine
N*NilmsomethylvinylarrHoe
C)ctarnethylpyrophospnoramide
Osmium oxide OsO4, (T-4)-
Osmium tetroxide
7-C)xatiicy<^[22.11twptane-2.3-dKart>oxylic acid
Paratnion
Phenol. 2-cyctohexyM,6K»nrtro-
Phenol. 2,4-dinitro-
Phenol. 2-methyl-4.6-dinitrc-. & salts
Phenol, 2-(1-rr«thylpropyl)-4.6-o1nitro-
Phenol, 2,4,6-trinitro-, ammonium salt (R)
Phenyhnercury acetate
Phenytthiourea
Phorate
Phosgene
PhospNne
Phosphoric acid, dtethyl 4-nrtropnenyl ester
Pnosphorodrthioic acid. O.O-diethyl
S-C2-(ethylthio)ethyl] ester
nil ml, ilumtjlilltijiij'i tt/*fH C\ fl llillllllll
pnospnoroonreoic acxi. (j.ixaeinyi
S-C(ethytthio)methyl) ester
Pnosphorodrthioic acid. O.O-dimethyl S-[2-(methylarnino)-2-oxoetfiylJ ester
Phosphorofluoridic acid. bis(1-methylethyl) ester
Phospnorothioic acid, O.O-diethyl O-<4-nrtrophenyl) ester
Phosphorothioic acid. O.O-diethyl Opyrazinyl ester
Phospnorothioic acid,
O-[4-[(dimethylamino)sulfonyl]phenyl] O.O-dwnethyl ester
Phosphorothioic acid, O.O,-dimethyl O-(4-nrtrophenyt) ester
Ptumbane, tetraettiyl-
Potassium cyanide
Potassium cyanide K(CN)
Potassium silver cyanide
Propanal. 2-methyl-2-(methytthio)-,
O-t(methylamino)carbonyl]oxime
                                    56

-------
Environmental Protection Agency
                             §261.33
Haz-
ardous
waste
No.
P101
P027
P069
P081
P017
P102
P003
POOS
P067
P102
P008
P075
P114
P103
P104
P104
P105
P106
P106
P108
P018
P108
P116
P109
P110
P111
P112
P062
P113
P113
P114
P115
P109
P045
P049
P014
P116
P026
P072
P093
P123
P118
P119
P120
P120
P084
P001
P121
P121
P122
Chemical
abstracts No.
107-12-0
542-76-7
75-86-5
55-63-0
598-31-2
107-19-7
107-02-8
107-18-6
75-55-8
107-19-7
504-24-5
'54-11-5
12039-52-0
630-10-4
506-64-9
506-64-9
26628-22-8
143-33-9
143-33-9
1 57-24-9
357-57-3
1 57-24-9
7446-18-6
3689-24-5
78-00-2
107-49-3
509-14-8
757-58-4
1314-32-5
1314-32-5
12039-52-0
7446-18-6
3689-24-5
39196-18-4
541-53-7
108-98-5
79-19-6
5344-82-1
86-88-4
103-85-5
8001-35-2
75-70-7
7803-55-6
1314-62-1
1314-62-1
4549-40-0
'81-81-2
557-21-1
557-21-1
1314-84-7
Substance

Propaneratnle
Propanenitrite, 3-chkxo-
Propaneortrite, 2-hydroxy-2-methyl-
1,2,3-Propanetriol. trinitrate (R)
2-Propanone, 1-bromc-
Propargyl alcohol
2-Propenal
2-Propen-1-ol
1 ,2-Propylenimine
2-Propyn-1-ol
4-Pyrtdinamine
Pyridine. 3-(1-mettiyl-2-pyrroltdinyl)-, (S)-, & salts
Selenkxis acid, dithallium(l +) salt
Selenourea
Silver cyanide
Silver cyanide Ag(CN)
Sodium azkte
Sodium cyanide
Sodium cyanide Na(CN)
Strychnidin-10-one, & salts
Strychnidin-10-one, 2.3-dimethoxy-
Strychnine, & salts
Sulfuric acid. ditnallium(1 +) salt
Tetraethyldithiopyrophosphate
Tetraethyl lead
Tetraethyl pyrophosphate
Tetranitromethane (R)
Tetraphosphoric acid, hexaethyl ester
Thallic oxide
Thallium oxide TUO,
Thallium(l) selenite
Thallium(l) sulfate
Thiodiphosphoric acid, tetraethyl ester
Thiofanox
Thioimidodicarbonic diamide [(H2N)C(S)LNH
Thiophenol
Thiosemicarbazide
Thiourea, (2-chlorophenyl)-
Thkxirea, 1-naphthalenyl-
Thiourea, phenyt-
Toxaphene
Trichloromethanethiol
Vanadic acid, ammonium salt
Vanadium oxide ViOs
Vanadium pentoxide
Vinylamine, N-methyl-N-nitroso-
Warfarin, & salts, when present at concentrations greater than 0.3%
Zinc cyanide
Zinc cyanide Zn(CN)2
Zinc phosphide ZnjP2, when present at concentrations greater than 10% (R,T)
  1 CAS Number given for parent compound only.

  (f)  The commercial chemical prod-
 ucts, manfacturing chemical interme-
 diates, or off-specification commercial
 chemical products referred to in para-
 graphs (a) through (d) of this section,
 are identified  as  toxic wastes (T),
 unless otherwise designated and are
 subject to the  small quantity genera-
 tor exclusion defined in § 261.5 (a) and
 (g).
[Comment.1 For the convenience of the regu-
lated community,  the primary  hazardous
properties of these materials have been indi-
cated by the letters T (Toxicity), R (Reac-
tivity),  I (Ignitability) and C (Corrosivity).
Absence of a letter indicates that the com-
pound is only listed for toxicity.]

  These wastes and their correspond-
ing EPA  Hazardous  Waste  Numbers
are:
                                      57

-------
§ 261.33
                                                               40 CFR Ch. I (7-1-92  Edition)
 Haz-
ardous
waste
  No.
  Chemical
abstracts No.
                                        Substance
U001
U034
U187
U005
U240
U112
U144
U214
see
  F027
U002
U003
U004
U005
U006
U007
U008
U009
U011
U012
U136
U014
U015
U010

U157
U016
U017
U192
U018
U094
U012
U014
U049
U093
U328
U353
U1S8
U222
U181
D019
U038
U030
U035
U037
U221
U028
U069
U088
U102
U107
U070
U071
U072
U060
U017
U223
U239
U201
U127
U056
U220
U105
U106
U05S
U169
U183
 U185
 U020
 U020
    75-07-0
    75-87-6
    62-44-2
    53-96-3
   1 94-75-7
    141-78-6
   301-04-2
   563-68-8
    93-76-5

    67-64-1
    75-05-8
    98-86-2
    53-96-3
    75-36-5
    79-O6-1
    79-10-7
    107-13-1
    61-82-5
    62-53-3
    75-60-5
    492-80-8
    115-02-6
    50-07-7

    56-49-5
    225-51-4
    98-87-3
 23950-58-5
    56-55-3
    57-97-6
    62-53-3
    492-80-8
   3165-93-3
    60-11-7
    95-53-4
    106-49-0
    101-14-4
    636-21-5
    99-55-8
    71-43-2
    510-15-6
    101-55-3
    305-03-3
    108-90-7
 25376-45-8
    117-81-7
     84-74-2
     84-66-2
    131-11-3
    117-84-0
     95-50-1
    541-73-1
    106-46-7
     72-54-8
     98-87-3
  26471-62-5
   1330-20-7
    108-46-3
    118-74-1
    110-82-7
    108-88-3
    121-14-2
    606-20-2
     98-82-8
     98-95-3
    608-93-5
     82-68-8
     98-09-9
     98-09-9
Acetaktehyde (I)
Acetaldehycte, trichkxo-
Acetamkte, N-(4-ethoxyphenyl)-
Acetamide, N-9H-fluoren-2-yl-
Acetic acid, (2,4-dichlorophenoxy)-, salts & esters
Acetic acid ethyl ester (I)
Acetic acid, lead(2+) salt
Acetic acid, thallium(1 +) salt
Acetic acid. (2,4,5-trichlorophenoxy)-

Acetone (I)
Acetonitrite (I,T)
Acetophenone
2-Acetylaminofluorene
Acetyl chloride (C.R.T)
Acrylamkte
Acrylic acid (I)
Acrytonitrile
Amrtrote
Aniline (I,T)
Arsinic acid, dimethyl-
Aurarrune
Azaserine
Azirino[2<,3':3.4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-t[(aminocarbonyl)oxy]methyl]-
  1,la,2,8,8a,8b-hexahydro-8a-metnoxy-5-methyl-, [1aS-(laalpha, 8beta,8aalpha,8balpha)]-
Benztjlaceanthrylene, 1,2-dihydro-3-methyl-
Benz[c]acridine
Benzal chloride
Benzamide, 3.5-dichloro-N-(1.1 -dimethyl-2-propynyl)-
BenzCalanthracene
BenzCalanthracene, 7,12-dimethyl-
Benzenamine (I.T)
Benzenamine, 4,4'-carbonimidoylbis[N,N-dimethyl-
Benzenamine, 4-chloro-2-methyl-, hydrochtoride
Benzenamine, N.N-dimethyl-4-(phenylazo)-
Benzenamine, 2-methyl-
Benzenamine, 4-melhyl-
Benzenamine, 4,4'-methytenebis[2-chloro-
Benzenamine, 2-methyl-, hydrochloride
Benzenamine, 2-methyl-5-nitro-
Benzene (I.T)
Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-t ethyl ester
Benzene,  1-bromo-4-phenoxy-
Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-
Benzene,  chtoro-
Benzenediamine, ar-methyl-
1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
1,2-Benzenedicarboxylic acid, dibutyl ester
1,2-Benzenedicarboxylic acid, diethyl ester
1,2-Benzenedicarboxylic acid, dimethyl ester
1,2-Benzenedicarboxylic acid, dioctyl ester
Benzene, 1,2-dichloro-
Benzene. 1,3-dichloro-
Benzene, 1,4-dichkxo-
Benzene, 1,1 '-(2,2-dichloroethylidene)bis[4-chloro-
Benzene. (dichloromethyl)-
Benzene, 1,3-diisocyanatomethyl- (R.T)
Benzene, dimethyl- (I.T)
 1,3-Benzenediol
Benzene, hexachloro-
Benzene, hexahydro- (I)
Benzene, methyl-
Benzene. 1-methyl-2.4-dinitro-
 Benzene, 2-methyl-1,3-dinitro-
 Benzene, (1-methylethyl)- (I)
 Benzene, nitro-
 Benzene, pentachloro-
 Benzene, pentachkxonitro-
 BenzenesuWonic acid chloride (C.R)
 Benzenesulfonyl chloride (C.R)
                                                       58

-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.

Chemical
abstracts No.


Substance

Haz-
ardous
waste
No.
U207
1)061
U247
U023
U234
U021
U202
U203
U141
U090
U064
U248
U022
U197
U023
U085
U021
U073
U091
U095
U225
U030
U128
U172
U031
U159
U160
U053
U074
U143
U031
U136
U032
U236
U178
U097
U114
U062
U215
U033
U1S6
U033
U211
U034
U035
U036
U026
U037
U038
U039
U042
U044
U046
U047
U04B
U049
U032
U050
U051
U052
U053
U055
U246
U197
UOS6
Chemical
abstracts No.
95-94-3
50-29-3
72-43-5
98-07-7
99-35-4
92-87-5
1 81-07-2
94-59-7
120-58-1
94-58-6
189-55-9
'81-81-2
50-32-8
106-51-4
98-07-7
1464-53-5
92-87-5
91-94-1
119-90-4
119-93-7
75-25-2
101-55-3
87-68-3
924-16-3
71-36-3
78-93-3
1338-23-4
4170-30-3
764-41-0
303-34-4
71-36-3
75-60-5
13765-19-0
51-79-6
615-53-2
79-44-7
1 111-54-6
2303-16-4
6533-73-9
353-50-4
79-22-1
353-50-4
56-23-5
75-87-6
305-03-3
57-74-9
494-03-1
108-90-7
510-15-6
59-50-7
110-75-8
67-66-3
107-30-2
91-58-7
95-57-8
3165-93-3
13765-19-0
218-01-9

1319-77-3
4170-30-3
98-82-8
506-68-3
106-51-4
1 10-82-7
                        Benzene, 1,2,4,5-tetrachloro-
                        Benzene, 1,1 '-(2,2,2-trichloroethy1idene)bis[4-chloro-
                        tenzene, 1,1'-(2,2,2-trichloroethylidene)bis[4- methoxy-
                         lenzene, (trichloromethyl)-
                        tenzene, 1,3,5-trinitro-
                         lenzidine
                         ,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, & salts
                         ,3-Benzodioxole, 5-(2-propenyl)-
                         ,3-Benzodioxole, 5-(1 -propenyl)-
                         ,3-Benzodioxole, 5-propyl-
                        Benzo[rst]pentaphene
                        2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present at concentrations
                          of 0.3% or toss
                        3enzo[a]pyrene
                          Benzoquinone
                        Benzotrichloride (C,R,T)
                        2,2'-Bioxirane
                         1,1 '-Biphenyl]-4,4'-diamine
                         1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dichloro-
                         1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-
                         1,1 '-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
                         Jromoform
                        4-Bromophenyl phenyl ether
                        1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
                        1-Butanamine, N-butyl-N-nitroso-
                        1-Butanol  (I)
                        2-Butanone (I.T)
                        2-Butanone, peroxide (R,T)
                        2-Butenal
                        2-Butene,  1,4-dichloro- (I.T)
                        2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-
                          2-(1 -methoxyethyl)-3-methyl-1 -oxobutoxy] methyl ]-
                          2,3,5,7a-tetrahydro-1 H-pyrrolizin-1 -yl ester,
                          [ 1 S-[ 1 alpha(Z),7(2S* ,3R*),7aalpha] 1-
                        n-Butyl alcohol (I)
                        Cacodylic acid
                        Calcium chromate
                        Carbamic acid, ethyl ester
                        Carbamic acid, methylnitroso-, ethyl ester
                        Carbamic chloride, dimethyl-
                        Carbamodithioic acid, 1,2-ethanediylbis-,
                          salts &  esters
                        Carbamothioic acid,  bis(l-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester
                        Carbonic  acid, dithallium(1 +) salt
                        Carbonic  difluoride
                        Carbonochloridic acid, methyl ester (I.T)
                         Carbon oxyfluoride (R,T)
                         Carbon tetrachloride
                         Chloral
                         Chlorambucil
                         Chlordane, alpha &  gamma isomers
                         Chlornaphazin
                         Chlorobenzene
                         Chlorobenzilate
                         p-Chloro-m-cresol
                         2-Chloroethyl vinyl ether
                         Chloroform
                         Chloromethyl methyl ether
                         beta-Chloronaphthalene
                         o-Chlorophenol
                         4-Chloro-c-toluidine, hydrochloride
                         Chromic  acid H2CrO4,  calcium salt
                         Chrysene
                         Creosote
                         Cresol (Cresylic acid)
                         Crotonaldehyde
                         Cumene  (I)
                         Cyanogen bromide  (CN)Br
                         2,5-Cyclohexadiene-1,4-dione
                         Cyclohexane (I)
                                                           59

-------
§ 261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
U129

U057
U130
U058
U240
U059
U060
U061
U062
U063
U064
U066
U069
U070
U071
U072
U073
U074
U075
U078
U079
U025
U027
U024
U081
UOB2
U084
U085
U10B
U028
U086
U067
U088
U089
U090
U091
U092
U093
U094
U095
U096
U097
U098
U099
U101
U102
U103
U105
U106
U107
uioe
U109
U110
VM1
U041
U001
U174
U155
U067
U076
U077
U131
U024
U117
U02S
U184
U206
U209
i iA«a
Chemical
abstracts No.
58-89-9

108-94-1
77-47-4
50-18-0
'94-75-7
20830-81-3
72-54-8
50-29-3
2303-16-4
53-70-3
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
91-94-1
764-41-0
75-71-8
75-35-4
156-60-5
111-44-4
108-60-1
111-91-1
120-83-2
87-65-0
542-75-6
1464-53-5
123-91-1
117-81-7
1615-60-1
3288-58-2
84-66-2
56-53-1
94-58-6
119-90-4
124-40-3
60-11-7
57-97-6
119-93-7
80-15-9
79-44-7
57-14-7
540-73-8
105-67-9
131-11-3
77-78-1
121-14-2
606-20-2
117-84-0
123-91-1
122-66-7
142-84-7
621-64-7
106-89-8
75-07-0
55-18-5
91-80-5
106-93-4
75-34-3
107-06-2
67-72-1
111-91-1
60-29-7
111-44-4
76-01-7
630-20-6
79-34-5
CO CC C
Substance
Cyclohexane, 1,2,3,4,5,6-hexachloro-,
(1alpha,2alpha,3beta,4alpha,5alpha,6beta)-
Cyctohexaoone (I)
,3-Cydopentadiene, 1,2,3,4,5,5-hexachloro-
Cyclophosphamtde
2.4-0, salts & esters
Daunomycin
ODD
DOT
Diallate
Dibenz[a,h]anthracene
Dibenzo[a,i]pyrene
1 ,2-Dibrorno-3-chloropropane
Dibutyl phthalate
o-Dichtorobenzene
m-Dichlorobenzene
p-Oichlorobenzene
3,3'-Dichlorobenzidine
1,4-Oicrikxo-2-butene (I.T)
Dichkxodifluorometriane
1.1-Dichkxoetriytene
1,2-Dichloroethylene
Dichloroethyl ether
Dtehtoroisopropyl ether
Ochkxomethoxy ethane
2,4-Dichlorophenol
2,6-Dichlorophenol
1 ,3-Dichkxopropene
1.2:3.4-Oiepoxyt>utane (I,T)
1,4-DiethyleneoxKJe
Diethylhexyl phthalate
N,N'-Diethylhydrazine
O.O-Dtethyt S-methyl dithiophosphate
Diethy) phthalate
OiethylstHbesterol
Oinydrosafrole
3.3'-Oimethoxybenzidine
Dimethyiamine (I)
p-Oimethylaminoazobenzene
7.1 2-Dimethytt)en2[a]anthracene
3.3--Dimethylbenzidine
alpha,alpha-Dirnetnylbenzylhydroperoxide (R)
Dimetnytcafbamoyl cnkxide
1 ,1-Oimethylnydrazine
1 ,2-Oimethylhydrazine
2,4-Dimetriytphenol
Dimethyl phthalate
Dimethyl sutfate
2.4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,4-Dioxane
1 ^-Diphenylnydrazine
Dioropylamine (I)
DMvpropytaitrosanvne
Epicnkxohydrin
Ethanal(l)
Ethanamine, N-ethyl-N-nitroso-
1,2-Ethanediamine, N,N-«fimethyl-N^2-pyrklinyl-N'-(2-thienylmethyl)-
Etharte, 1.2-dtofomo-
Ethane. 1.1-dichkxo-
Ethane, 1,2-<*chkxo-
Etnane. hexachtoro-
Ethane, l.1'-[metnylenebis(oxy)]bis[2-chloro-
Ethane. l,1'-oxybis-(l)
Ethane, 1.1'-oxybisl2-chtoro-
Ethane, pentachloro-
Ethane, 1.1.1^-tetrachloro-
Ethane, 1.1^^-tetrachtoro-
l~tln»«il>llli
-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
U226
U&7
U359
U173
U004
U043
U042
U078
U079
U210
U228
U112
U113
U238
U117
U114
U067
U077
U359
U115
U116
U076
UJ18
U119
U120
U122
U123
U124
U125
U147
U213
U125
U124
U206
U206

U126
U163
U127
U128
U130
U131
U132
U243
U133
UOB6
U098
U099
U109
U134
U134
U135
U135
U096
U116
U137
U190
U140
U141
U142
U143
U144
U146
U145
U146
U129
U163
U147
U148
U149
Chemical
abstracts No.
71-55-6
79-00-5
110-80-5
1116-54-7
90-86-2
75-01-4
110-75-8
75-35-4
156-60-5
127-18-4
79-01-6
141-78-6
140-88-5
51-79-6
60-29-7
1 111-54-6
106-93-4
107-06-2
110-80-5
75-21-8
96-45-7
75-34-3
97-63-2
62-50-0
206-44-0
50-00-0
64-18-6
110-00-9
98-01-1
108-31-6
109-99-9
98-01-1
110-00-9
18883-66-4
18883-66-4

765-34-4
70-25-7
116-74-1
87-68-3
77-47-4
67-72-1
70-30-4
1888-71-7
302-01-2
1615-80-1
57-14-7
540-73-8
122-66-7
7664-39-3
7664-39-3
7783-06-4
7783-06-4
80-15-9
96-45-7
193-39-5
85-44-9
78-83-1
120-58-1
143-50-0
303-34-4
301-04-2
1335-32-6
7446-27-7
1335-32-6
58-89-9
70-25-7
108-31-6
123-33-1
109-77-3
Substance
Ethane, 1,1,1-trichloro-
Etfwne, 1,1,2-trichtoro-
Ettianol, 2-etrtoxy-
Ethanol, 2,2'-(nitrosoimino)bis-
Ethanone, 1-phenyl-
Ethene, chloro-
Ethene, (2-chloroethoxy)-
Ethene, 1,1-dicti(oro-
Ethene, 1 ,2-dichloro-, (E)-
Ethene, tetracriloro-
Ethene, trictiloro-
Ethyl acetate (1)
Ethyl acrylate (1)
Ethyl carbamate (urethane)
Ethyl ether (1)
Ethylenebisdithiocarbamic acid, sails & esters
Ethylene dibromide
Elhylene dichtoride
Ethytene glycol monoethyl ether
Ethylene oxide (I,T)
Ethytenethiourea
Ethylidene dichloride
Ethyl methacryjate
Ethyl methartesulfonate
-luoranthene
Formaldehyde
Formic acid (C,T)
Furan (1)
2-Furancarboxaldehyde (!)
2.5-Furandione
Furan. tetrafiy*o-(l)
Furfural (1)
Furfuran (1)
Glucopyranose, 2-deoxy-2-(3-methy1-3-nitrosoureido)-, D-
D-Glucose. 2-
-------
§261.33
                                                              40 CFR Ch.  I  (7-1-92 Edition)
 Haz-
ardous
 waste
  No.
  Chemical
abstracts No.
                                         Substance
U1SO
U151
U152
U092
U029
U045
U046
U068
U080
U075
U138
U119
U211
U153
U225
U044
U121
U036
U154
U155
U142
U247
U154
U029
U186
U045
U156
U226
U157
U158
U068
U080
U159
U160
U138
U161
U162
U161
U164
U010
U059

U167
U168
U026
U165
U047
U166
U236

U166
U167
U168
U217
U169
U170
U171
U172
U173
U174
U176
U177
U17B
U179
U180
U181
U193
U058

U115
   148-82-3
  7439-97-6
   126-98-7
   124-40-3
    74-83-9
    74-87-3
   107-30-2
    74-95-3
    75-09-2
    75-71-8
    74-88-4
    62-50-0
    56-23-5
    74-93-1
    75-25-2
    67-66-3
    75-69-4
    57-74-9
    67-56-1
    91-80-5
   143-50-0
    72-43-5
    67-56-1
    74-83-9
   504-60-9
    74-87-3
    79-22-1
    71-55-6
    56-49-5
   101-14-4
    74-95-3
    75-09-2
    78-93-3
  1338-23-4
    74-88-4
   108-10-1
    80-62-6
   106-10-1
    56-04-2
    50-07-7
 20830-81-3

   134-32-7
    91-59-8
   494-03-1
    91-20-3
    91-58-7
   130-15-4
    72-57-1

   130-15-4
   134-32-7
    91-59-8
 10102-45-1
    98-95-3
   100-02-7
    79-46-9
   924-16-3
  1116-54-7
    55-18-5
   759-73-9
   684-93-5
   615-53-2
   100-75-4
   930-55-2
    99-55-8
  1120-71-4
    50-18-0

    75-21-8
 Melphalan
 Mercury
 Methacrylonitrile (I, T)
 Methanamine, N-methyl- (I)
 Methane, bromo-
 Methane, chloro- (I. T)
 Methane, chkxomethoxy-
 Methane, dibromo-
 Methane, dichtoro-
 Methane, dichlorodifluoro-
 Methane, todo-
 Methanesulfonic acid, ethyl ester
 Methane, tetrachloro-
 Methanethiol (I, T)
 Methane, tribromo-
 Methane, trichloro-
 Methane, trichlorofluoro-
 4.7-Methano-1H-indene. 1,2.4,5.6.7,8,8-octachloro-2,3.3a.4,7.7a-hexahydro-
 Methanol (I)
 Methapyrilene
 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1 a,3.3a,4,5.5.5a,5b.6-decachtorooctahydro-
 Methoxychtor
 Methyl alcohol (I)
 Methyl bromide
 1-Methylbutadiene (I)
 Methyl chloride (I,T)
 Methyl chtorocarbonate (I.T)
 Methyl chloroform
 3-Methyteholanthrene
 4,4--Methytenebis(2-chloroaniline)
 Methytene bromide
 Methytene chloride
 Methyl ethyl ketone (MEK) (I,T)
 Methyl ethyl ketone peroxide (R.T)
 Methyl iodide
 Methyl isobutyl ketone (I)
 Methyl methacrylate (I.T)
 4-Methyl-2-pentanone (I)
 Methytthiouracil
-Mrtomycin C
 5.12-Naphthacenedione, 8-acetyl-10-[(3-amirK>-2,3,6-trideoxy)-alpha-L-lyxo-hexopyranosyl)oxy]-
   7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
 1-Naphthalenamine
 2-Naphthalenamine
 Naphthatenamine, N.N'-bis(2-chkxoettiyl)-
 Naphthalerie
 Naphthalene, 2-crtloro-
 1,4-Naphthalenedk>ne
 2.7-Naphthalenedisulfonic acid, 3.3'-[(3,3'-
   dimethylll.l'-biDhenyll-4,4'-diyt)bis(azo)btsC5-arnino-4-nydroxy]-, tetrasodium salt
 1.4-Naphthoquinone
 alpha-Naphthylamine
 beta-Naphthylamme
 Nitric acid, tnallium(l +) salt
 Nitrobenzene (I,T)
 p-Nitrophenol
 2-Nitropropane (I.T)
 N-Nrtrosodi-n-butylamine
 N-Nrtrosodietrianolamine
 N-Nrtrosodtetrtylamine
 N-Nitroso-N-ettiylurea
 N-Nitroso-N-methylurea
 N-Nitroso-N-methylurethane
 N-Nitrosopiperidine
 N-Nitrosopyrrolidine
 5-Nitro-o-toluidine
 1,2-Oxathk>lane, 2,2-dioxide
 2H-1,3,2-Oxazaphosphorin-2-amine,
   N.N-bis(2-chloroethyl)tetrahydro-, 2-oxide
 Oxirane (I.T)
                                                       62

-------
Environmental Protection Agency
§261.33
Haz-
ardous
waste
No.
U126
U041
U182
U183
U184
U185
See
F027
U161
U186
U187
U188
U048
U039
UOB1
U082
U089
U101
U052
U132
U170
SM
F027
SM
F027
SM
F027
SM
F027
U1SO
U145
UOB7
U189
U190
U191
U179
U192
U194
U111
U110
U066
U063
U149
U171
U027
U193
SM
F027
U235
U140
U002
U007
U064
U243
U009
U152
UOOB
U113
U118
U162
U194
U063
U146
U198
U191
U237
U164
U180
U200
Chemical
abstracts No.
765-34-4
106-69-8
123-63-7
608-93-5
76-01-7
82-68-8
87-86-5
108-10-1
504-60-9
62-44-2
108-95-2
95-57-8
59-50-7
120-83-2
87-65-0
56-53-1
105-67-9
1319-77-3
70-30-4
100-02-7
87-66-5
58-90-2
95-95-4
86-06-2
146-62-3
7446-27-7
3286-56-2
1314-80-3
65-44-9
109-06-8
100-75-4
23950-58-5
107-10-8
621-64-7
142-84-7
96-12-6
78-87-5
109-77-3
79-46-9
106-60-1
1120-71-4
93-72-1
126-72-7
76-63-1
67-64-1
79-06-1
542-75-6
1888-71-7
107-13-1
126-96-7
79-10-7
140-66-5
97-63-2
80-62-6
107-10-6
78-87-5
123-33-1
110-86-1
109-06-6
66-75-1
56-04-2
930-55-2
50-55-5
Substance
Oxiranecarboxyaldehyde
Oxirane, (chtoromethyl)-
Paraldehyde
'entachlorobenzene
Pentachloroethane
Pentachloronitrooenzene (PCNB)
Pentachlorophenol
Pentanol, 4-methyl-
1,3-Pentadiene (I)
Phenacetin
Phenol
Phenol, 2-chkxo-
Phenol. 4-cMoro-3-methyl-
Phenol. 2.4-dfchtoro-
ttenol, 2,6-dtehloro-
Phenol. 4^4X1 .2-<»etrryM,2-ethenedryl)bis-. (E)-
Phenol. 2,4-oTmethyf-
TMnoi, iiNtlnyl
Phenol. 2,2--methytenebi»[3,4,6-trichloro-
Phanol. 4-nNro-
Phenol. pantachtoro-
Phenoi. 2,3.4.6-teWchtorc-
Phenol, 2,4.5-Wehloro-
Phenol. 2,4.6-trichtorc-
L-Phenytaiartna, 4-tbis(2-chloroethyl)arnirK>J-
Phosphoric acid. «ead(2+) salt (2:3)
Phosphorus suffide (R)
Phthafir AnhwrkirlA
2-Picoline
pjperidne. 1-nilroso-
Pronamide
-ptopanarnioe |i, ij

Propane, l^-dkromo-3-chloro-
Propane. 1^-dkWoro-
ropanaonvM
Propane, 2-nitro- (I.T)
Propane. 2^-oxybist2-chlofo-
PrrvyHVhir arirl ?.l? 4 S IrifihlQfOOhllfKmvW
1-Propanol. 2^-dferomo-. phosphate (3:1)
1-Prapmol. 2-methyt- (I.T)

1 -Propsna, 1 . * ,2l3«9.9"ne)(vcfiioio*
^-rropui MM *u in
2-fnUpWMIMfM, Z-rnaOTyi- |l, 1 )
2-Propanoic acid (0
2-Propenoic add. ethyl ester (1)
2-Propanoic acid. 2-mamyl-. ethyl aster
2 Proponoic acid 2-m*1hy4- m^hyi «fi^ (I T)
n-Piopylamina (t.T)

Pyntfcw
Pyricfine, 2-fiwlhyl-


PyrroAcSno, 1-fli1fo>o-
                                   63

-------
§261.33
40 CFR Ch. I (7-1-92 Edition)
Haz-
ardous
waste
No.
U201
U202
U203
U204
U204
U205
U205
U015
See
F027
U206
U103
U189
See
F027
U207
U206
U209
U210
See
F027
U213
U214
U215
U216
U216
U217
U218
U153
U244
U219
U244
U220
U221
U223
U328
U353
U222
U011
U227
U228
U121
See
F027
See
F027
U234
U182
U235
U236
U237
U176
U177
U043
U248
U239
U200

U249
Chemical
abstracts No.
108-46-3
1 81-07-2
94-59-7
7783-00-8
7783-00-8
7488-56-4
7488-56-4
115-02-6
93-72-1

18883-66-4
77-78-1
1314-80-3
93-76-5

95-94-3
630-20-6
79-34-5
127-18-4
58-90-2

109-99-9
563-68-8
6533-73-9
7791-12-0
7791-12-0
10102-45-1
62-55-5
74-93-1
137-26-8
62-56-6
137-26-6
108-88-3
25376-45-8
26471-62-5
95-53-4
106-49-0
636-21-5
61-82-5
79-00-5
79-01-6
75-69-4
95-95-4

88-06-2

99-35-4
123-63-7
126-72-7
72-57-1
66-75-1
759-73-9
684-93-5
75-01-4
'81-81-2
1330-20-7
50-55-5

1314-84-7
Substance
Resofctnol
Saccharin. & salts
Safrote
Setenious acid
Selenium dioxide
Selenium sulfide
Selenium sulfide SeSj (R,T)
L-Serine, diazoacetate (ester)
Silvex (2,4,5-TP)

Streptozotocin
Sulfuric acid, dimethyl ester
Sulfur phosphide (R)
2,4,5-T

1 ,2,4.5-TetracMorobenzene
1 ,1 ,1 ,2-Tetrachkxoethane
1,1 ,2.2-Tetrachloroethane
Tetrachkxoetnytene
2.3.4.6-Tetrachlorophenol

Tetrahydrofuran (1)
ThalKurrKI) acetate
ThaltiumO) carbonate
ThaHium(l) chloride
Thallium chloride Tld
ThalNum(l) nitrate
Tnioacetamide
TNomethand (I.T)
Thioperoxydicarbonic diamide t(H,N)C(S)]»S,. tetramethyl-
Thiourea
Thiram
Toluene
Tohjenediamine
Toluene diisocyanate (R,T)
o-Toluidine
p-Toluidine
o-Toluidine hydrochloride
1 H-1 ,2,4-Triazol-3-amine
1,1 ,2-Trichloroethane
Trichloroethytene
Trichkxornonofluoromethane
2,4,5-Trichkxophenol

2,4,6-Trichlorophenol

1,3,5-Trinitrobenzene (R.T)
1,3,5-Trioxane, 2,4,6-trimethyl-
Tris(2,3-dioromopfOpyl) phosphate
Trypan blue
Uracil mustard
Urea, N-ethyl-N-rntroso-
Urea, N-methyl-N-nitroso-
Vinyt chloride
Warfarin, & salts, when present at concentrations of 0.3% or less
Xytene(l)
Yohimban-16-carboxylic acid, H,l7-dimethoxy-l8-[(3,4,5-trimethoxybenzoyl)oxy]-, methyl ester.
(3beta,l6beta,17alpha,18beta,20alpha)-
Zinc phosphide Zn,Pi, when present at concentrations of 10% or less
  1 CAS Number given for parent compound only.

(Approved by the Office of Management and Budget under control number 2050-0047)
[45 FR 78529, 78541, Nov. 25, 1980]
  EDITORIAL NOTE: For FEDERAL REGISTER citations affecting i 261.33, see the List of CFR
Sections Affected in the Finding Aids section of this volume.
                                        64

-------
Environmental Protection Agency
                           § 261.35
§261.35  Deletion  of  certain  hazardous
   waste codes following equipment clean-
   ing and replacement.
  (a)  Wastes from  wood  preserving
processes at plants that do not resume
or initiate use of chlorophenolic  pre-
servatives will not meet the listing def-
inition of F032 once the generator has
met all  of  the requirements of para-
graphs  (b) and (c) of  this  section.
These wastes may, however, continue
to meet another hazardous waste list-
ing description or may exhibit one or
more  of the  hazardous  waste charac-
teristics.
  (b) Generators must either clean or
replace  all  process  equipment  that
may  have  come  into  contact with
chlorophenolic  formulations  or  con-
stituents thereof,  including, but not
limited to, treatment cylinders, sumps,
tanks, piping systems, drip pads,  fork
lifts,  and trams, in  a  manner  that
minimizes or eliminates the escape of
hazardous   waste   or   constituents,
leachate, contaminated  drippage, or
hazardous waste decomposition prod-
ucts  to  the ground water,  surface
water, or atmosphere.
  (1)  Generators shall do one of the
following:
  (i) Prepare  and follow an equipment
cleaning plan and  clean equipment in
accordance with this section;
  (ii) Prepare and follow an equipment
replacement  plan  and replace equip-
ment in accordance  with this section;
or
  (iii) Document cleaning and replace-
ment in accordance  with this section,
carried out after termination of use of
chlorophenolic preservations.
  (2) Cleaning Requirements.
  (i) Prepare and sign a written equip-
ment cleaning plan that describes:
  (A) The equipment to be cleaned;
  (B) How  the  equipment  will be
cleaned;
  (C) The solvent to be used in clean-
ing;
  (D) How solvent rinses will be tested;
and
  (E) How cleaning residues will be dis-
posed.
  (ii) Equipment must  be cleaned  as
follows:
  (A) Remove all visible residues from
process equipment;
  (B) Rinse process equipment with an
appropriate solvent until dioxins and
dibenzof urans are not detected in the
final solvent rinse.
  (iii) Analytical requirements.
  (A) Rinses must be tested in accord-
ance with SW-846, Method 8290.
  (B)  "Not  detected" means  at or
below the  lower method calibration
limit (MCL) in  Method 8290, Table 1.
  (iv) The generator must manage all
residues from the cleaning process as
P032 waste.
  (3) Replacement requirements.
  (i) Prepare and sign a written equip-
ment replacement plan that describes:
  (A) The equipment to be replaced;
  (B) How  the  equipment will  be re-
placed; and
  (C) How the  equipment will be dis-
posed.
  (ii) The generator must manage the
discarded equipment as P032 waste.
  (4) Documentation requirements.
  (i) Document that previous  equip-
ment cleaning and/or replacement was
performed in accordance with this sec-
tion and occurred  after cessation of
use of chlorophenolic preservatives.
  (c) The generator must maintain the
following records  documenting the
cleaning  and replacement  as part of
the facility's operating record:
  (1) The name and address of the fa-
cility;
  (2)  Formulations previously   used
and the date on which their use ceased
in each process  at the plant;
  (3) Formulations currently used in
each process at  the plant;
  (4) The equipment cleaning or re-
placement plan;
  (5) The name and address of any
persons  who conducted  the cleaning
and replacement;
  (6) The dates on which cleaning and
replacement were accomplished;
  (7) The dates of  sampling and test-
ing;
  (8) A description of the sample han-
dling  and preparation techniques, in-
cluding  techniques  used for extrac-
tion,  containerization,   preservation,
and chain-of-custody of the samples;
  (9) A  description of the  tests per-
formed,  the  date the tests were per-
formed, and the results of the tests;
                                    65

-------
Pt. 261, App. I
          40 CFR Ch. I (7-1-92 Edition)
  (10) The name  and model numbers
of the instrument(s) used in perform-
ing the tests;
  (11) QA/QC documentation; and
  (12) The following statement signed
by the generator or his authorized rep-
resentative:

  I  certify  under penalty of law that all
process equipment required to be cleaned or
replaced under 40 CFR 261.35 was cleaned
or replaced as represented in the equipment
cleaning and replacement  plan and accom-
panying documentation. I am aware that
there are significant penalties for providing
false information, including  the possibility
of fine or imprisonment.

[55 FR 50482, Dec. 6, 1990,  as amended at 56
PR 30195, July 1, 1991]

  EFFECTIVE DATE NOTE: At  55 FR 50482,
Dec. 6, 1990, § 261.35 was added. Paragraph
(c) contains information collection and rec-
ordkeeping  requirements  and  will not
become effective until approval has been
given by the  Office of Management and
Budget. A  notice will be published in the
FEDERAL REGISTER once approval has been
obtained.

        APPENDICES TO PART 261

       APPENDIX I TO PART 261—
  REPRESENTATIVE SAMPLING METHODS
  The  methods  and  equipment  used  for
sampling waste materials will vary with the
form and consistency of the waste materials
to be sampled. Samples collected using the
sampling protocols  listed below,  for sam-
pling waste with properties similar to the in-
dicated materials, will be considered by the
Agency to be representative of the waste.

Extremely  viscous liquid—ASTM  Standard
  D140-70 Crushed or powdered material—
  ASTM Standard D346-75 Soil or rock-like
  material—ASTM Standard D420-69  Soil-
  like material—ASTM Standard D1452-65
Fly  Ash-like  material—ASTM  Standard
  D2234-76 [ASTM Standards are available
  from ASTM, 1916 Race St., Philadelphia,
  PA 19103]
Containerized  liquid  wastes—"COLIWASA"
  described in  "Test  Methods for the Eval-
  uation of Solid Waste, Physical/Chemical
  Methods," *  U.S.  Environmental Protec-
  * These methods are  also described in
"Samplers and  Sampling  Procedures for
Hazardous Waste Streams," EPA 600/2-80-
018, January 1980.
  tion Agency, Office of Solid Waste, Wash-
  ington, D.C. 20460. [Copies  may  be  ob-
  tained from Solid Waste Information, U.S.
  Environmental Protection Agency, 26 W.
  St. Clair St., Cincinnati, Ohio 45268]
Liquid waste in pits, ponds, lagoons, and
  similar reservoirs.—"Pond  Sampler"  de-
  scribed in  "Test Methods for the Evalua-
  tion  of  Solid Waste,  Physical/Chemical
  Methods." "
  This manual also contains additional in-
formation on application of these protocols.

APPENDIX  II TO  PART  261—METHOD
  1311   TOXICITY    CHARACTERISTIC
  LEACHING PROCEDURE (TCLP)
        1.0  Scope and Application

  1.1  The TCLP is designed to determine
the mobility of both organic and inorganic
analytes present in liquid, solid, and multi-
phasic wastes.
  1.2  If a total analysis of the waste dem-
onstrates that individual analytes  are not
present in the  waste,  or that  they are
present but at such low concentrations that
the appropriate regulatory levels could not
possibly be exceeded, the TCLP need not be
run.
  1.3  If an analysis of any one of the liquid
fractions of the TCLP extract indicates that
a regulated  compound is  present  at such
high  concentrations that, even  after ac-
counting for dilution from the other frac-
tions  of  the  extract,  the concentration
would be equal to or above the regulatory
level for that compound, then the  waste is
hazardous and it is not necessary to analyze
the remaining fractions of the extract.
  1.4  If an analysis of extract  obtained
using a bottle extractor shows that  the con-
centration of any regulated volatile analyte
equals or exceeds the  regulatory level for
that compound, then the waste is hazardous
and extraction using the ZHE  is  not neces-
sary. However, extract from a bottle extrac-
tor cannot be used to demonstrate that the
concentration  of  volatile compounds  is
below the regulatory level.

         2.0  Summary of Method

  2.1  For liquid wastes (i.e., those  contain-
ing less than 0.5% dry solid material), the
waste, after filtration through a 0.6 to 0.8
ftm glass fiber filter, is defined as the TCLP
extract.
  2.2  For wastes containing greater than or
equal to 0.5% solids, the  liquid, if any, is
separated from the solid phase and stored
for later analysis; the particle size of the
solid  phase  is  reduced, if necessary. The
solid  phase is extracted with an amount of
extraction fluid equal to 20 times the weight
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Environmental Protection Agency
                         Pt. 261, App. II
of the solid phase. The extraction fluid em-
ployed is a function of the alkalinity of the
solid phase of the waste. A special extractor
vessel is used when testing for volatile ana-
lytes (see Table 1 for a list of volatile com-
pounds).  Following extraction, the liquid ex-
tract  is separated from the solid phase by
filtration through a 0.6 to 0.8 jim glass fiber
filter.
  2.3  If  compatible (i.e.,  multiple phases
will not  form on combination),  the initial
liquid phase  of the waste is  added to the
liquid extract,  and these are  analyzed to-
gether. If incompatible, the liquids are ana-
lyzed separately and the results are mathe-
matically combined  to  yield  a  volume-
weighted average concentration.

             3.0  Interferences
  3.1  Potential interferences that may be
encountered during analysis are discussed in
the individual analytical methods.

       4.0  Apparatus and Materials
  4.1  Agitation apparatus: The agitation
apparatus must be capable of rotating the
extraction vessel in an end-over-end fashion
(see Figure 1) at 30  ±2 rpm. Suitable devices
known to EPA are identified in Table 2.
  4.2  Extraction Vessels.
  4.2.1 Zero-Headspace  Extraction  Vessel
(ZHE). This device  is for use only when the
waste is being  tested for the mobility  of
volatile analytes (i.e.,  those listed in Table
1). The ZHE (depicted in Figure 2) allows
for  liquid/solid  separation  within  the
device, and effectively precludes  headspace.
This type of vessel allows for initial liquid/
solid  separation, extraction,  and final ex-
tract filtration  without opening the vessel
(see section 4.3.1). The vessels shall have an
internal  volume of  500-600  mL,  and  be
equipped to accommodate  a 90-110  mm
filter. The devices contain VITON* l O-rings
which should be replaced frequently. Suita-
ble ZHE devices known to EPA are identi-
fied in Table 3.
  For the ZHE to be acceptable for use, the
piston within the ZHE should be able to be
moved with  approximately 15 pounds  per
square inch  (psi)  or less. If  it takes more
pressure to move the  piston,  the O-rings in
the device should be  replaced. If this does
not solve the problem, the ZHE is unaccept-
able  for TCLP analyses and the manufac-
turer should be contacted.
   The ZHE  should be checked for leaks
after every extraction. If the device contains
a built-in pressure gauge,  pressurize  the
device to 50 psi, allow it to stand  unattended
for 1 hour, and recheck the pressure. If the
device does  not have  a  built-in pressure
gauge, pressurize the  device  to 50 psi, sub-
   'VITON*  is  a registered trademark of
 DuPont.
merge it in water, and check for the pres-
ence of air bubbles escaping from any of the
fittings. If pressure is lost, check all fittings
and  inspect and replace  O-rings, if neces-
sary. Retest the device. If leakage problems
cannot be solved, the  manufacturer should
be contacted.
  Some ZHEs use gas pressure  to  actuate
the ZHE  piston, while others use mechani-
cal pressure (see Table 3). Whereas the vola-
tiles procedures (see section  7.3) refers to
pounds per square inch (psi), for the me-
chanically actuated piston, the pressure ap-
plied is  measured  in torque-inch-pounds.
Refer to the manufacturer's instructions as
to the proper conversion.
  4.2.2  Bottle Extraction Vessel. When the
waste is being evaluated using the nonvola-
tile extraction, a jar with sufficient capacity
to hold the sample and the extraction fluid
is needed.  Headspace is  allowed  in this
vessel.
  The extraction bottles may be constructed
from various  materials, depending on the
analytes to be analyzed and  the nature of
the  waste (see  section 4.3.3). It is recom-
mended  that borosilicate glass  bottles be
used  instead of other types of glass, espe-
cially when inorganics are of concern. Plas-
tic bottles, other than polytetrafluoroethy-
lene, shall not be used if organics are to be
investigated. Bottles  are  available  from  a
number of laboratory suppliers. When this
type of extraction vessel  is used, the filtra-
tion device discussed in section 4.3.2 is used
for initial liquid/solid separation and final
extract filtration.
  4.3  Filtration Devices: It is recommended
that all nitrations be  performed in a hood.
  4.3.1  Zero-Headspace  Extractor  Vessel
(ZHE): When the waste is evaluated for vo-
latiles, the zero-headspace extraction vessel
described in section 4.2.1 is  used for filtra-
tion. The device shall  be capable of support-
ing  and  keeping in  place the  glass fiber
filter and be able to withstand the pressure
needed to accomplish separation (50 psi).
  NOTE: When it is suspected that the glass
fiber  filter has  been ruptured,  an in-line
glass fiber filter may be used to filter the
material within the ZHE.
  4.3.2 Filter Holder: When the waste  is
evaluated for other than volatile analytes,
any filter holder capable of supporting  a
glass fiber filter and  able to withstand the
pressure  needed to accomplish separation
may be used. Suitable filter holders range
from simple vacuum units to relatively com-
plex systems capable  of  exerting pressures
of up to  50 psi or more. The type  of filter
holder used depends  on the properties  of
the material to be filtered (see section 4.3.3).
These devices shall have a minimum inter-
nal volume of 300 mL  and be equipped to ac-
commodate a minimum filter size of 47 mm
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Pt. 261, App. II
          40 CFR Ch. I (7-1-92 Edition)
(filter holders having an internal capacity
of 1.5 L or greater, and equipped to accom-
modate a 142 mm diameter filter, are recom-
mended).  Vacuum  filtration  can only  be
used  for  wastes with  low solids  content
(<10%) and for highly granular, liquid-con-
taining wastes. All other types of wastes
should be filtered using positive pressure fil-
tration. Suitable filter  holders  known  to
EPA are shown in Table 4.
  4.3.3 Materials of  Construction: Extrac-
tion vessels and filtration devices shall  be
made of inert materials which will not leach
or absorb waste components. Glass, polyte-
trafluoroethylene (PTFE), or type 316 stain-
less steel equipment may be used when eval-
uating the mobility of both organic and  in-
organic components. Devices made of high
density polyethylene (HDPE), polypropyl-
ene (PP), or polyvinyl chloride  (PVC) may
be used only when evaluating the mobility
of metals. Borosilicate glass bottles are rec-
ommended for use over other types of glass
bottles, especially when inorganics are ana-
lytes of concern.
  4.4  Filters: Filters shall be made of boro-
silicate glass fiber,  shall contain no binder
materials, and shall have an effective pore
size of 0.6  to 0.8 jon, or equivalent. Filters
known to EPA which meet these specifica-
tions  are identified in  Table 5. Pre-filters
must not be used. When evaluating the mo-
bility of metals, filters shall be acid-washed
prior  to use  by rinsing with IN nitric acid
followed by  three  consecutive rinses with
deionized distilled water (a minimum of 1 L
per rinse is recommended). Glass fiber filter
are fragile and should be handled with care.
  4.5  pH Meters: The meter should be  ac-
curate to ± 0.05 units at 25°C.
  4.6  ZHE   Extract   Collection   Devices:
TEDLAR® * bags or glass, stainless steel or
PTFE gag-tight syringes are used to collect
the initial liquid phase and the final extract
of the waste when using the ZHE device.
The devices listed are recommended for use
under the following conditions:
  4.6.1  If  a waste  contains  an  aqueous
liquid phase or if a waste does not contain a
significant amount  of  nonaqueous liquid
(i.e., <1%  of total waste),  the  TEDLAR®
bag or a 600 mL syringe should be used to
collect and combine  the initial liquid and
solid extract.
  4.6.2  If  a waste  contains a  significant
amount of nonaqueous liquid in the initial
liquid phase (Le.. >1% of total waste), the
syringe or the TEDLAR® bag may be used
for both the intitial solid/liquid separation
and the final extract  filtration.  However,
analysts should use one or  the other, not
both.
  * TEDLAR® is a registered trademark of
Dupont.
  4.6.3  If  the waste contains no initial
liquid phase (is 100% solid) or has no signifi-
cant solid phase (is 100% liquid), either the
TEDLAR® bag or the syringe may be used.
If the syringe is used, discard the first 5 mL
of liquid expressed from the device. The re-
maining aliquots are used for analysis.
  4.7  ZHE Extraction  Fluid  Transfer  De-
vices: Any device capable of transferring the
extraction  fluid   into  the  ZHE  without
changing the nature of the extraction fluid
is acceptable (e.g, a positive displacement or
peristaltic  pump, a gas tight  syringe, pres-
sure filtration unit (see  section  4.3.2), or
other ZHE device).
  4.8  Laboratory  Balance: Any laboratory
balance  accurate  to  within  ±  0.01 grams
may be used (all weight measurements are
to be within ± 0.1 grams).
  4.9  Beaker or  Erlenmeyer  flask, glass,
500 mL.
  4.10  Watchglass, appropriate diameter to
cover beaker or erlenmeyer flask.
  4.11  Magnetic stirrer.

               5.0  Reagents

  5.1  Reagent grade chemicals  shall  be
used in all tests. Unless otherwise indicated,
it is intended  that all reagents shall con-
form to the specifications of the Committee
on  Analytical  Reagents  of  the American
Chemical Society, where such specifications
are available.  Other grades may  be used,
provided it is first ascertained that the rea-
gent is of sufficiently high purity to permit
its use without lessening the accuracy of the
determination.
  5.2  Reagent water. Reagent water is de-
fined as water in which an interferant is not
observed at or above the methods  detection
limit of the analyte(s) of  interest. For non-
volatile extractions, ASTM Type II water or
equivalent meets the definition of reagent
water. For volatile extractions, it  is recom-
mended that reagent water be generated by
any of  the  following methods.  Reagent
water should be monitored periodically for
impurities.
  5.2.1  Reagent water for volatile  extrac-
tions may be generated by passing tap water
through  a carbon  filter bed containing
about   500  grams   of  activated  carbon
(Calgon Corp., Filtrasorb-300 or equivalent).
  5.2.2  A  water purification system (Milli-
pore Super-Q  or  equivalent) may also be
used to generate reagent water for volatile
extractions.
  5.2.3  Reagent water for volatile  extrac-
tions may also be prepared by boiling water
for 15 minutes. Subsequently, while main-
taining the water temperature at 90 +  5 de-
grees C, bubble a contaminant-free inert gas
(e.g., nitrogen) through  the  water for 1
hour. While still hot. transfer the water to a
narrow mouth screw-cap bottle under zero-
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Environmental Protection Agency
                         Pt. 261, App. II
headspace  and  seal with  a  Teflon-lined
septum and cap.
  5.3  Hydrochloric  acid (IN), HC1, made
from ACS reagent grade.
  5.4  Nitric  acid (IN), HNO3, made  from
ACS reagent grade.
  5.5  Sodium hydroxide (IN), NaOH, made
from ACS reagent grade.
  5.6  Glacial acetic acid, CH3CH2OOH, ACS
reagent grade.
  5.7  Extraction fluid.
  5.7.1 Extraction fluid #1: Add 5.7 mL gla-
cial CH3CH2OOH to  500  mL  of reagent
water (See section 5.2), add 64.3 mL of IN
NaOH, and dilute to  a volume  of 1  liter.
When correctly prepared,  the pH of  this
fluid will be 4.93 ±0.05.
  5.7.2 Extraction fluid #2: Dilute 5.7 mL
glacial CHsCH2OOH  with reagent  water
(See  section 5.2) to a volume  of 1  liter.
When correctly prepared,  the pH of this
fluid will be 2.88±0.05.
  NOTE: These extraction  fluids  should be
monitored frequently for  impurities.  The
pH should be checked prior to use to ensure
that these fluids are made up accurately. If
impurities are found or the pH is not within
the above specifications, the fluid shall be
discarded  and fresh extraction  fluid  pre-
pared.
  5.8  Analytical standards shall be  pre-
pared according to the appropriate analyti-
cal method.

  6.0  Sample Collection, Preservation, and
                 Handling
  6.1  All  samples shall be collected  using
an appropriate sampling plan.
  6.2  The TCLP may place reQuirements
on the minimal size of the field sample, de-
pending upon the physical state or states of
the waste and the analytes of concern. An
aliquot is needed for preliminary evaluation
of which extraction fluid is to be used for
the nonvolatile  analyte extraction proce-
dure. Another aliquot may be needed to ac-
tually conduct the  nonvolatile extraction
(see section  1.4 concerning the  use of this
extract for volatile  organics). If  volatile or-
ganics are of concern,  another aliquot may
be needed. Quality control measures may re-
quire additional aliquots.  Further,  it is
always wise  to collect more samples just in
case  something goes wrong with the initial
attempt to conduct the test.
  6.3  Preservatives shall not be  added to
samples before extraction.
  6.4  Samples may be refrigerated unless
refrigeration results in irreversible physical
 change to the waste. If precipitation occurs,
 the  entire  sample  (including precipitate)
 should be extracted.
   6.5  When the waste is to be evaluated for
 volatile analytes, care shall be taken to min-
 imize the loss of volatiles.  Samples shall be
 collected and stored in a manner intended
to prevent the loss of volatile analytes (e.g.,
samples should be collected in Teflon-lined
septum capped  vials and stored at 4  °C.
Samples should be opened only immediately
prior to extraction).
  6.6  TCLP  extracts  should  be prepared
for analysis and analyzed as soon as possible
following  extraction. Extracts or portions of
extracts for metallic analyte determinations
must be  acidified with nitric acid to a  pH
<2, unless precipitation occurs (see section
7.2.14  if   precipitation  occurs). Extracts
should be preserved for other analytes  ac-
cording to the guidance given in the individ-
ual analysis  methods. Extracts or portions
of extracts for organic analyte  determina-
tions shall not be allowed to come into con-
tact  with the atmosphere (i.e.,  no head-
space) to  prevent losses. See section  8.0 (QA
requirements) for acceptable sample and ex-
tract holding times.

              7.0 Procedure

  7.1 Preliminary   Evaluations.   Perform
preliminary  TCLP evaluations on  a  mini-
mum 100 gram aliquot of waste. This  ali-
quot may not actually undergo  TCLP  ex-
traction.  These  preliminary  evaluations in-
clude: (1) Determination of  the  percent
solids  (section 7.1.1);  (2)  determination of
whether  the waste  contains  insignificant
solids and is, therefore, its own extract after
filtration (section 7.1.2);  (3) determination
of whether the solid portion of the waste re-
quires particle size reduction (section 7.1.3);
and  (4) determination  of which of  the  two
extraction fluids are to be used for the non-
volatile TCLP extraction of the waste (sec-
tion 7.1.4.).
   7.1.1  Preliminary determination  of per-
cent solids: Percent solids is defined as that
fraction of a waste sample (as a percentage
of the total sample) from which no liquid
may be forced out by an applied pressure, as
described below.
   7.1.1.1  If  the  waste will obviously yield
no liquid when subjected to pressure filtra-
tion (i.e., is  100% solids)  proceed to section
7.1.3.
   7.1.1.2  If  the  sample  is liquid or multi-
phasic, liquid/solid separation  to  make  a
preliminary  determination of percent solids
is required.  This  involves  the filtration
device described in section 4.3.2 and is out-
lined in sections 7.1.1.3 through 7.1.1.9.
   7.1.1.3  Pre-weigh the filter and the con-
tainer that will receive the filtrate.
   7.1.1.4  Assemble  the  filter holder  and
filter following the manufacturer's instruc-
tions. Place  the filter on  the support screen
 and secure.
   7.1.1.5  Weigh out  a  subsample of  the
 waste (100 gram minimum) and  record the
 weight.
   7.1.1.6  Allow slurries to stand to permit
 the solid phase to settle. Wastes that settle
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Pt. 261, App. II
                               40 CFR Ch. I (7-1-92 Edition)
slowly may be centrifuged prior to filtra-
tion. Centrifugation is to be used only as an
aid to filtration.  If used, the liquid should
be decanted and  filtered followed by filtra-
tion  of  the solid portion  of  the waste
through the same filtration system.
  7.1.1.7  Quantitatively transfer the waste
sample to the filter holder (liquid and solid
phases).  Spread  the  waste sample evenly
over the surface of the filter. If filtration of
the waste at 4 °C reduces the amount of ex-
pressed liquid over what would be expressed
at room temperature then allow the sample
to warm  up to  room temperature in the
device before filtering.
  NOTE: If waste  material (>1%  of original
sample weight) has  obviously adhered to
the container used to transfer the sample to
the  filtration  apparatus,  determine  the
weight of this residue and subtract it from
the  sample weight determined  in  section
7.1.1.5 to determine he weight of the waste
sample that will be filtered.
  Gradually apply vacuum or gentle pres-
sure of 1-10 psi, until air or pressurizing gas
moves through the filter. If this point is not
reached under  10 psi, and if  no additional
liquid has passed  through the filter in any 2
minute interval,  slowly  increase the pres-
sure in 10 psi increments to a maximum of
50 psi. After each incremental increase of 10
psi, if the pressurizing gas has not moved
through the filter, and if  no  additional
liquid has passed  through the filter in any 2
minute interval, proceed to the next 10 psi
                     increment.   When  the   pressurizing  gas
                     begins to move through the filter, or when
                     liquid flow  has ceased at  50 psi (i.e.,  filtra-
                     tion  does not result  in any  additional fil-
                     trate within any 2 minute period), stop the
                     filtration.
                      NOTE:  Instantaneous application  of high
                     pressure can degrade the glass fiber filter
                     and may cause premature plugging.
                      7.1.1.8 The material in the filter holder is
                     defined  as the solid phase of the waste, and
                     the filtrate  is defined as the liquid phase.
                      NOTE:  Some wastes, such as oily wastes
                     and some paint wastes, will obviously con-
                     tain  some  material that  appears to  be  a
                     liquid. Even after applying vacuum or pres-
                     sure  filtration, as outlined in section 7.1.1.7,
                     this material may not filter. If this  is the
                     case,  the   material  within  the filtration
                     device is defined as a solid. Do not replace
                     the original filter with a  fresh filter  under
                     any circumstances. Use only one filter.
                      7.1.1.9 Determine  the   weight  of  the
                     liquid phase by subtracting  the weight of
                     the filtrate container (see  section 7.1.1.3)
                     from the total weight of the filtrate-filled
                     container. Determine the weight of the solid
                     phase of the waste sample by subtracting
                     the weight of  the liquid phase from the
                     weight of the total waste sample, as  deter-
                     mined in section 7.1.1.5 or 7.1.1.7.
                      Record the weight of the liquid and solid
                     phases.  Calculate the percent solids as fol-
                     lows:
      Percent solids  =
                                  Weight of solid (section 7.1.1.9)
                           Total weight of waste (section 7.1.1.5 or 7.1.1.7)
                                                    xlOO
  7.1.2  If the percent solids determined in
section 7.1.1.9 is equal to or greater than
0.5%, then proceed either to section 7.1.3 to
determine  whether the solid  material re-
quires particle size reduction or to section
7.1.2.1 if it is noticed that a small amount of
the filtrate is entrained  in wetting of the
filter.  If the percent solids determined  in
section 7.1.1.9 is less than 0.5%, then pro-
ceed to section 7.2.9 if the nonvolatile TCLP
is to be performed and to section 7.3 with a
fresh portion of the  waste if the volatile
TCLP is to be performed.
                      7.1.2.1  Remove the solid phase and filter
                     from the filtration apparatus.
                      7.1.2.2  Dry the  filter and solid phase at
                     100 ±  20°C until two successive weighings
                     yield the same value within ±  1%. Record
                     the final weight.
                      NOTE: Caution should be taken to ensure
                     that  the subject solid will  not  flash upon
                     heating. It is recommended  that the drying
                     oven be vented to a hood or other appropri-
                     ate device.
                      7.1.2.3  Calculate the percent dry solids as
                     follows:
        i dry solids =
(Weight of dry waste+filter)—tared weight of filter

  Initial weight of waste (section 7.1.1.5 or 7.1.1.7)
xlOO
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                         Pt. 261, App. II
  7.1.2.4  If the percent dry solids is less
than 0.5%, then proceed to  section 7.2.9 if
the nonvolatile TCLP is to be performed,
and to section 7.3 if the volatile TCLP is to
be performed. If the percent  dry  solids is
greater than or equal to 0.5%, and if the
nonvolatile TCLP is to be performed, return
to the beginning of this section (7.1) and,
with a fresh  portion  of  waste, determine
whether particle size reduction is necessary
(section 7.1.3) and determine the appropri-
ate extraction fluid (section 7.1.4). If only
the volatile TCLP  is to be performed,  see
the note in section 7.1.4.
  7.1.3  Determination  of   whether  the
waste requires particle size reduction (parti-
cle size is reduced  during this step): Using
the solid portion of the waste, evaluate the
solid for particle size. Particle size reduction
is required, unless  the solid has a surface
area per gram of material equal to  or great-
er than 3.1 cm1, or is smaller than 1 cm in
its narrowest  dimension (i.e., is capable of
passing  through  a 9.5 mm  (0.375  inch)
standard sieve). If the surface area is small-
er or the particle size larger than described
above,  prepare  the  solid  portion of  the
waste for extraction by crushing, cutting, or
grinding the waste to a surface area or par-
ticle size as described above. If the solids are
prepared for  organic volatiles  extraction.
special precautions must be taken (see sec-
tion 7.3.6).
  NOTE: Surface area criteria are meant for
filamentous (e.g., paper, cloth, and similar)
waste materials. Actual measurement of sur-
face area is not required, nor is it recom-
mended. For materials that do not obviously
meet the criteria,  sample-specific  methods
would need to be developed and employed
to measure the surface area. Such method-
ology is currently not available.
   7.1.4  Determination  of  appropriate  ex-
traction fluid: If  the solid  content of  the
waste is greater than or equal to 0.5% and if
the sample will be  extracted for nonvolatile
constituents (section 7.2), determine the ap-
propriate fluid (section 5.7) for the nonvola-
tiles extraction as follows:
   NOTE:  TCLP extraction for volatile con-
stituents uses only extraction fluid #1 (sec-
tion 5.7.1). Therefore, if TCLP extraction
for nonvolatiles is not required, proceed to
section 7.3.
   7.1.4.1  Weigh  out a small  subsample of
 the solid phase of the waste,  reduce  the
solid (if necessary) to a particle size of ap-
proximately 1 mm in diameter or less,  and
 transfer 5.0 grams of the solid phase of the
 waste to a 500 mL  beaker or Erlenmeyer
 flask.
   7.1.4.2  Add 96.5 mL of reagent water to.
 the beaker, cover with a watchglass, and stir
 vigorously for 5 minutes using a  magnetic
 stirrer. Measure and record the pH. If the
pH is <5.0, use extraction fluid #1. Proceed
to section 7.2.
  7.1.4.3  If the pH from section 7.1.4.2 is
>5.0. add  3.5 mL  IN NCI,  slurry  briefly,
cover with a watchglass, heat to 50°C, and
hold at 50°C for 10 minutes.
  7.1.4.4  Let the solution cool to room tem-
perature and  record  the  pH. If the pH is
<5.0, use extraction  fluid #1. If the pH is
>5.0, use extraction fluid #2. Proceed to sec-
tion 7.2.
  7.1.5 If the aliquot of the waste used for
the preliminary  evaluation (sections 7.1.1-
7.1.4) was  determined to be  100% solid at
section 7.1.1.1, then it can be used for  the
section 7.2 extraction (assuming at least 100
grams remain), and the section 7.3 extrac-
tion (assuming at least 25 grams remain). If
the aliquot was subjected to the procedure
in section 7.1.1.7, then another aliquot shall
be used  for the volatile extraction proce-
dure in section 7.3. The aliquot of the waste
subjected to the procedure in section 7.1.1.7
might be appropriate for use for the section
7.2 extraction if an adequate amount of
solid (as determined  by section 7.1.1.9) was
obtained. The amount of solid necessary is
dependent  upon  whether   a   sufficient
amount of extract will be produced to sup-
port the analyses. If an adequate amount of
solid remains, proceed  to section  7.2.10 of
the nonvolatile TCLP extraction.
  7.2  Procedure When Volatiles are not In-
volved. A minimum sample size of 100 grams
(solid and liquid phases) is recommended. In
some cases, a larger sample size may be ap-
propriate,  depending on the solids content
of the waste sample (percent solids, See sec-
tion 7.1.1), whether the initial liquid phase
of the waste win be miscible with the aque-
ous  extract of the solid, and whether inor-
ganics, semivolatile organics, pesticides,  and
herbicides  are   all  analytes of  concern.
Enough  solids should be generated for ex-
traction such that the volume of TCLP ex-
tract will be sufficient to support all of the
analyses required.  If the amount of extract
generated by a single TCLP extraction will
not be sufficient to perform all of the analy-
ses,  more  than one extraction may be  per-
formed and the  extracts from each com-
bined and aliquoted for analysis.
   7.2.1 If the waste will obviously yield no
liquid when subjected to pressure filtration
(i.e., is 100%  solid, see section 7.1.1), weigh
out  a subsample  of the waste (100 gram
minimum) and proceed to section 7.2.9.
   7.2.2 If the sample is liquid or multipha-
sic,  liquid/solid separation is required. This
Involves the  filtration device described in
section 4.3.2 and is outlined in sections 7.2.3
to 7.2.8.
   7.2.3 Pre-weigh the container  that  will
receive the filtrate.
   7.2.4 Assemble the filter holder and filter
 following  the manufacturer's instructions.
                                          71

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Pt. 261, App. II
          40 CFR Ch. I (7-1-92 Edition)
Place the filter on the support screen and
secure. Acid-wash the filter if evaluating the
mobility of metals (see section 4.4).
  NOTE: Acid-washed filters may be used for
all nonvolatile extractions even when metals
are not of concern.
  7.2.5  Weigh out a subsample of the waste
(100 gram minimum) and record the weight.
If the waste contains <0.5% dry solids (sec-
tion 7.1.2), the liquid portion of the waste,
after filtration, is defined as the TCLP ex-
tract.  Therefore,  enough of the  sample
should be filtered so that the amount of fil-
tered liquid will support all of the  analyses
required of the TCLP extract. For wastes
containing >0.5% dry solids (sections 7.1.1
or 7.1.2), use the percent solids information
obtained in section  7.1.1 to  determine the
optimum sample size (100 gram minimum)
for filtration. Enough solids should be  gen-
erated by filtration to support the  analyses
to be performed on the TCLP extract.
  7.2.6  Allow slurries  to stand to permit
the solid phase to settle. Wastes that settle
slowly may be centrifuged prior to filtra-
tion. Use centrifugation only as an aid to fil-
tration. If the waste  is centrifuged, the
liquid should be decanted and filtered fol-
lowed by  filtration of the solid portion of
the  waste  through  the  same  filtration
system.
  7.2.7  Quantitatively  transfer  the waste
sample (liquid and solid phases) to the filter
holder (see section 4.3.2). Spread the waste
sample evenly over the surface of the filter.
If filtration of the waste at 4 °C reduces the
amount of expressed liquid over what would
be  expressed at room  temperature,  then
allow the sample to warm up to room tem-
perature in the device before filtering.
  NOTE If waste material (> 1% of the origi-
nal sample weight) has obviously adhered to
the container used to transfer the sample to
the  filtration  apparatus,  determine  the
weight of this residue and subtract it from
the  sample weight  determined  in section
7.2.5, to determine the weight of the waste
sample that will be filtered.
  Gradually  apply vacuum  or gentle  pres-
sure of 1-10 psi. until air or pressurizing gas
moves through the filter. If this point is
reached under 10 psi, and if no additional
liquid has passed through the filter in any 2
minute interval,  slowly increase the  pres-
sure in 10 psi increments to a maximum of
SO psi. After each incremental increase of 10
psi,  if the pressurizing gas has not moved
through the filter,  and if no additional
liquid has passed through the filter in any 2
minute interval, proceed to the next 10 psi
increment.  When   the  pressurizing  gas
begins to move through the filter, or when
the liquid flow has ceased at 50 psi (i.e., fil-
tration does not result in any additional fil-
trate within a 2 minute period), stop the fil-
tration.
  NOTE: Instantaneous  application of high
pressure can degrade the glass fiber filter
and may cause premature plugging.
  7.2.8  The material in the filter holder is
defined as the solid phase of the waste, and
the filtrate is defined as the liquid  phase.
Weigh the filtrate.  The liquid phase may
now be either analyzed  (See section  7.2.12)
or stored at 4°C until time of analysis.
  NOTE: Some wastes, such as  oily  wastes
and  some paint wastes, will obviously con-
tain some material that appears  to be a
liquid. Even after applying  vacuum or pres-
sure filtration, as outlined  in section 7.2.7,
this  material may not  filter. If this is the
case, the  material within the  filtration
device is  defined  as a  solid and is carried
through the extraction as a solid. Do  not re-
place the original filter with a fresh filter
under any circumstances.  Use only one
filter.
  7.2.9  If  the waste  contains  <0.5% dry
solids (see section 7.1.2), proceed to section
7.2.13. If  the  waste contains  >0.5% dry
solids (see section 7.1.1 or 7.1.2), and if parti-
cle size reduction of the solid was needed in
section 7.1.3, proceed to section 7.2.10. If the
waste  as received passes a 9.5 mm sieve,
quantitatively transfer  the solid  material
into the  extractor  bottle  along  with the
filter used to separate the initial liquid from
the  solid  phase,  and  proceed to  section
7.2.11.
  7.2.10  Prepare  the solid portion  of the
waste for extraction by crushing, cutting, or
grinding the waste to a surface area or par-
ticle size as described in section 7.1.3. When
the surface area or particle size has been ap-
propriately altered, quantitatively transfer
the solid material into an extractor  bottle.
Include the filter used to separate the ini-
tial liquid from the solid phase.
  NOTE: Sieving of the waste is not normally
required.  Surface  area  requirements  are
meant for filamentous  (e.g., paper,  cloth)
and  similar waste materials. Actual meas-
urement of surface area is  not recommend-
ed. If sieving is necessary,  a Teflon-coated
sieve should be used to avoid contamination
of the sample.
  7.2.11  Determine the amount of extrac-
tion fluid to add to the extractor vessel as
follows:
 Weight of
 extraction
   fluid
 20 x percent solids (section
   7.1.1 )x weight of waste
  filtered (section 7.2.5 or
	7.2.7)	

            100
  Slowly add this amount of appropriate ex-
traction fluid (see section 7.1.4) to the ex-
tractor vessel. Close  the extractor bottle
                                         72

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Environmental Protection Agency
                         Pt. 261, App. II
tightly (it is recommended that Teflon tape
be used to ensure a  tight seal), secure in
rotary agitation device, and rotate at 30 ± 2
rpm for 18 ± 2 hours. Ambient temperature
(i.e., temperature of room in which  extrac-
tion takes place) shall be maintained at 23
± 2°C during the extraction period.
 NOTE: As   agitation continues,  pressure
may build within  the extractor bottle for
some types of wastes (e.g., limed or calcium
carbonate  containing waste  may  evolve
gases  such as carbon dioxide). To  relieve
excess pressure, the extractor bottle may be
periodically  opened (e.g., after 15 minutes,
30 minutes,  and 1 hour) and vented into a
hood.
  7.2.12 Following the 18 ± 2 hour extrac-
tion, separate the material in  the extractor
vessel into its component  liquid and  solid
phases  by filtering  through  a new  glass
fiber filter, as outlined in section 7.2.7. For
final  filtration of the  TCLP extract, the
glass fiber filter may be changed, if neces-
sary,  to facilitate  filtration.  Filter(s)  shall
be acid-washed (see section 4.4) if evaluating
the mobility of metals.
  7.2.13 Prepare the TCLP extract as fol-
lows:
  7.2.13.1  If the waste contained no initial
liquid phase, the filtered liquid material ob-
tained from section 7.2.12 is defined as the
TCLP extract. Proceed to section 7.2.14.
  7.2.13.2  If  compatible  (e.g.,  multiple
phases will not result on combination), com-
bine the filtered liquid resulting from sec-
tion 7.2.12 with the initial liquid phase of
the waste obtained in section 7.2.7.  This
combined liquid is defined as the TCLP ex-
tract. Proceed to section 7.2.14.
  7.2.13.3  If the initial liquid phase of the
waste, as obtained from section 7.2.7, is not
or may not be compatible with the  filtered
liquid resulting from section  7.2.12, do not
combine these liquids. Analyze these liquids,
collectively  defined  as  the TCLP extract,
and combine the results mathematically, as
described in section 7.2.14.
  7.2.14  Following collection  of the TCLP
extract, the pH of the extract should be re-
corded. Immediately aliquot  and preserve
the extract  for  analysis. Metals  aliquots
must be acidified with nitric acid to pH <2.
If precipitation is observed upon addition of
nitric acid to a small aliquot of the extract,
then  the remaining portion of the extract
for metals  analyses  shall not be acidified
and the extract shall be analyzed as soon as
possible. All other aliquots must be stored
under refrigeration (4 °C> until  analyzed.
The TCLP extract  shall be  prepared and
analyzed according to appropriate analytical
methods. TCLP extracts to be analyzed for
metals shall be acid digested except in those
instances where digestion causes loss of me-
tallic analytes. If an analysis of the undi-
gested extract shows that the concentration
of any regulated metallic  analyte  exceeds
the regulatory level, then the waste is haz-
ardous and digestion of  the  extract is not
necessary. However, data on undigested ex-
tracts alone cannot be used to demonstrate
that the waste is not hazardous. If the indi-
vidual phases are to be analyzed separately,
determine  the volume  of the  individual
phases (to ± 0.5%), conduct the appropriate
analyses, and combine the results mathe-
matically by using a simple volume-weight-
ed average:
 Final Analyte
 Concentration
                           Vi+V,
where:
Vi=The volume of the first phase (L).
Ci=The  concentration  of the  analyte of
    concern in the first phase (mg/L).
V2=The volume of the second phase (L).
C2=The  concentration  of the  analyte of
    concern in the second phase (mg/L).
  7.2.15  Compare  the  analyte  concentra-
tions in  the  TCLP extract with the levels
identified  in  the appropriate regulations.
Refer to section 8.0 for quality assurance re-
quirements.
  7.3 Procedure  When Volatiles  are  In-
volved. Use the ZHE device to obtain TCLP
extract for analysis of volatile compounds
only. Extract resulting  from the use of the
ZHE shall not be used  to evaluate the mo-
bility of nonvolatile  analytes (e.g.,  metals,
pesticides, etc.).
  The ZHE device has approximately a 500
mL internal capacity. The ZHE can thus ac-
commodate a maximum of 25 grams of solid
(defined as that  fraction of  a sample from
which no  additional  liquid may be forced
out by an applied pressure of 50 psi), due to
the need to  add an  amount of extraction
fluid equal to 20 times the weight  of the
solid phase.
  Charge the ZHE with sample only once
and do not open the device until the final
extract (of the solid) has been collected. Re-
peated filling of the ZHE to obtain 25 grams
of solid is not permitted.
  Do not allow the waste, the initial liquid
phase, or  the extract to be exposed to the
atmosphere for any more time than is abso-
lutely necessary. Any manipulation of these
materials should be done when cold  (4°C) to
minimize loss of volatiles.
  7.3.1  Pre-weigh  the  (evacuated)  filtrate
collection container (See section 4.6) and set
aside. If using a TEDLAR* bag, express all
liquid from  the  ZHE device into the  bag,
whether for the initial or final liquid/solid
separation, and  take an aliquot from  the
liquid in the bag for analysis. The contain-
ers listed in section 4.6 are recommended for
                                          73

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PI. 261, App. II
          40 CFR Ch. I (7-1-92 Edition)
use under the conditions stated in sections
4.6.1-4.6.3.
  7.3.2  Place  the ZHE  piston  within the
body of the ZHE (it may be helpful first to
moisten the piston O-rings slightly with ex-
traction fluid). Adjust the piston within the
ZHE body to a height that will minimize the
distance the piston will have to move once
the ZHE is charged  with sample (based
upon  sample size requirements  determined
from section 7.3, section 7.1.1 and/or 7.1.2).
Secure the  gas inlet/outlet flange (bottom
flange)  onto the ZHE body in  accordance
with   the   manufacturer's  instructions.
Secure  the  glass fiber filter between the
support screens and set aside. Set liquid
inlet/outlet flange (top flange) aside.
  7.3.3  If the waste is 100% solid (see sec-
tion 7.1.1). weigh out a subsample (25 gram
maximum) of the waste, record weight, and
proceed to section 7.3.5.
  7.3.4  If  the  waste  contains  <5%  dry
solids (section 7.1.2), the liquid portion of
waste, after  filtration,  is  defined  as the
TCLP extract. Filter enough of the sample
so that the  amount of filtered liquid will
support all of the volatile analyses required.
For wastes containing >5% dry solids (sec-
tions  7.1.1 and/or  7.1.2),  use  the percent
solids information obtained in section 7.1.1
to determine the optimum sample  size to
charge  into  the  ZHE.  The recommended
sample size is as follows:
  7.3.4.1  For wastes containing <5% solids
(see  Section 7.1.1), weigh out a 500 gram
subsample of waste and record the weight.
  7.3.4.2 For wastes containing >5% solids
(see Section 7.1.1), determine the amount of
waste to charge into the ZHE as follows:
         Weight of waste to charge ZHE  =
                                                         25
                                            percent solids (section 7.1.1)
                             xlOO
  Weigh out a subsample of the waste of the
appropriate size and record the weight.
  7.3.5  If particle size reduction of the solid
portion of the waste was required in section
7.1.3, proceed to section 7.3.6. If particle size
reduction was not required in section 7.1.3,
proceed to section 7.3.7.
  7.3.6  Prepare the waste for extraction by
crushing, cutting, or grinding the solid  por-
tion of the waste to a surface area or parti-
cle  size as  described  in  section  7.1.3.1.
Wastes  and  appropriate reduction  equip-
ment should be refrigerated, if  possible, to
4°C  prior to  particle size  reduction.  The
means used to effect particle size reduction
must not generate  heat in and  of itself. If
reduction of the solid phase of the waste is
necessary, exposure of the waste to the at-
mosphere should be  avoided to the  extent
possible.
  NOTE: Sieving of  the  waste is not recom-
mended due to the possibility that volatiles
may be lost. The use of an appropriately
graduated ruler is  recommended as  an ac-
ceptable alternative.  Surface area require-
ments  are  meant  for filamentous  (e.g.,
paper, cloth)  and similar waste materials.
Actual  measurement of surface area is not
recommended.
  When the surface area or particle size has
been appropriately altered, proceed to sec-
tion 7.3.7.
  7.3.7  Waste slurries need not be allowed
to stand to permit the solid phase to settle.
Do not centrifuge wastes prior to filtration.
  7.3.8  Quantitatively  transfer  the  entire
sample (liquid and solid phases) quickly to
the  ZHE.  Secure  the filter and support
screens onto  the top flange of the device
and secure the top flange to the ZHE body
in accordance with the manufacturer's  in-
structions. Tighten  all ZHE  fittings and
place the device in the vertical  position (gas
inlet/outlet flange on the bottom). Do not
attach the extract collection device to the
top plate.
  NOTE: If waste material (>1% of original
sample weight)  has obviously adhered to
the container used to transfer the sample to
the ZHE, determine the weight of this resi-
due and subtract it from the sample weight
determined in section 7.3.4 to determine the
weight of the waste sample that will be  fil-
tered.
  Attach  a gas line to the gas inlet/outlet
valve (bottom flange) and, with the liquid
inlet/outlet valve (top flange) open, begin
applying  gentle pressure of  1-10 psi  (or
more if necessary) to force all headspace
slowly out of the ZHE device into a hood. At
the  first appearance of  liquid from the
liquid inlet/outlet valve, quickly  close the
valve and discontinue pressure. If  filtration
of the waste at 4 °C reduces the amount of
expressed liquid  over  what would  be  ex-
pressed  at  room temperature, then allow
the sample to warm up to room temperature
in the device  before filtering. If the waste is
100%  solid (see  section 7.1.1), slowly  in-
crease the pressure to a maximum of 50 psi
to force most of the headspace out of the
device and proceed to section 7.3.12.
  7.3.9  Attach the evacuated  pre-weighed
filtrate  collection container to the liquid
inlet/outlet valve and open the valve. Begin
                                          74

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Environmental Protection Agency
                          Pt. 261, App. II
applying gentle pressure of 1-10 psi to force
the liquid phase of the sample into the fil-
trate collection container. If no additional
liquid has passed through the filter in any 2
minute interval, slowly increase  the pres-
sure in 10 psi increments to  a maximum of
50 psi. After each incremental increase of 10
psi,  if no  additional  liquid has   passed
through the filter in any 2 minute interval,
proceed to the next 10 psi increment. When
liquid  flow has ceased such  that continued
pressure filtration at 50 psi  does not result
in any additional filtrate within a 2 minute
period, stop the filtration. Close the liquid
inlet/outlet valve, discontinue pressure to
the piston, and disconnect and weigh the fil-
trate collection container.
  NOTE: Instantaneous  application of high
pressure can degrade the glass fiber filter
and may cause premature plugging.
  7.3.10  The material in the ZHE is defined
as the solid phase of the waste and the fil-
trate is defined as the liquid phase.
   NOTE: Some  wastes, such  as oily wastes
 and some paint wastes,  will obviously con-
 tain some material that  appears to  be a
 liquid. Even after applying pressure filtra-
 tion, this material will not filter. If this is
 the case,  the material within the filtration
 device is  defined  as a solid and  is carried
 through the TCLP extraction as a solid.
   If the original waste contained <0.5% dry
 solids  (see section 7.1.2), this filtrate  is de-
 fined as the TCLP extract and is analyzed
 directly. Proceed to section 7.3.15.
   7.3.11  The  liquid phase may now be
 either analyzed immediately (See sections
 7.3.13 through 7.3.15) or stored at 4°C under
 minimal headspace conditions  until time of
 analysis.
   Determine the weight of extraction  fluid
 #1 to add to the ZHE as follows:
              Weight of extraction
                      fluid
  20 x percent solids (section
7.1.1) xweight of waste filtered
    (section 7.3.4 or 7.3.8)

             100
  7.3.12  The following sections detail how
to add the appropriate amount of extraction
fluid to  the  solid material within the ZHE
and agitation of the ZHE vessel. Extraction
fluid #1  is used in all cases (See section 5.7).
  7.3.12.1 With the ZHE in the vertical po-
sition, attach a line from the extraction
fluid reservoir to the  liquid inlet/outlet
valve. The line used shall contain fresh ex-
traction fluid and should be preflushed with
fluid to eliminate any  air  pockets  in the
line. Release  gas pressure  on the  ZHE
piston  (from  the gas  inlet/outlet  valve),
open the liquid inlet/outlet valve, and begin
transferring extraction fluid (by pumping or
similar  means)  into the  ZHE. Continue
pumping extraction fluid into the ZHE until
the appropriate amount of fluid has been
introduced into the device.
  7.3.12.2  After  the  extraction fluid has
been added, immediately  close the  liquid
 inlet/outlet  valve and disconnect the extrac-
 tion fluid line. Check the  ZHE to ensure
 that all valves are in their closed positions.
 Manually rotate the device in an end-over-
 end  fashion 2 or 3 times. Reposition the
 ZHE in the  vertical position with the liquid
 inlet/outlet  valve on  top. Pressurize the
 ZHE to 5-10  psi (if necessary) and  slowly
 open the liquid inlet/outlet valve to  bleed
 out any headspace (into a hood) that may
 have been introduced due to the addition of
 extraction fluid. This bleeding shall be done
  quickly and shall be stopped at the first ap-
  pearance of liquid from the valve.  Re-pres-
  surize the ZHE with 5-10 psi and check all
  ZHE fittings to ensure that they are closed.
    7.3.12.3  Place the ZHE in the rotary agi-
  tation apparatus (if it is not already there)
  and rotate at 30 ±  2 rpm for 18 ± 2 hours.
  Ambient temperature  (i.e., temperature of
  room in  which extraction occurs)  shall be
  maintained at 22  ±  3°C during agitation.
    7.3.13   Following  the 18 ± 2 hour agita-
  tion period, check the pressure behind the
  ZHE piston by quickly opening and closing
  the gas  inlet/outlet valve and noting the
  escape of gas. If the pressure has not been
  maintained (i.e.,  no gas release observed),
  the device is leaking. Check the ZHE  for
  leaking as specified in section 4.2.1, and per-
  form the  extraction  again  with  a  new
  sample of waste. If the pressure within the
  device has been maintained, the material in
  the extractor vessel is once again separated
  into its component liquid and  solid phases.
  If  the  waste  contained an  initial  liquid
  phase, the liquid may be filtered directly
  into the same filtrate collection  container
  (i.e.,  TEDLAR*  bag)  holding the  initial
  liquid phase of the  waste. A separate filtrate
  collection container must be used if combin-
  ing would create multiple phases, or there is
  not enough volume left within the filtrate
  collection  container.  Filter  through  the
  glass fiber filter, using  the ZHE device as
                                           75

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ft. 261, App. II
                              40 CFR Ch. I (7-1-92 Edition)
discussed in section 7.3.9. All extract shall
be filtered and collected if the TEDLAR*
bag is used, if the extract is multiphasic, or
if the waste contained an initial liquid phase
(see sections 4.6 and 7.3.1).
  NOTE: An in-line glass fiber filter may be
used to filter the material within the ZHE if
it is suspected that the glass fiber filter has
been ruptured.
  7.3.14 If the original waste contained no
initial liquid phase, the filtered liquid mate-
rial obtained from section  7.3.13 is defined
as the TCLP extract. If the waste contained
an initial liquid phase, the filtered liquid
material obtained from section 7.3.13 and
the initial liquid phase  (section 7.3.9) are
collectively defined as the TCLP extract.
  7.3.15 Following collection of the TCLP
extract, immediately prepare the extract for
analysis and store with minimal headspace
at 4°C until analyzed.  Analyze the TCLP ex-
tract according to the appropriate analytical
methods. If the individual  phases are to be
analyzed separately (i.e., are not miscible),
determine  the volume  of the  individual
phases (to 0.5%), conduct the appropriate
analyses,  and combine  the results mathe-
matically  by using a simple volume-weight-
ed average:
  Final Analtye
  Concentration
(ViKC.WViXCs)

     V,+V2
where:
V,=The volume of the first phases (L).
Ci=The concentration of the  analyte of
    concern in the first phase (mg/L).
Vj=The volume of the second phase (L).
C»=The concentration of the  analyte of
    concern in the second phase (mg/L).
  7.3.16  Compare  the analyte concentra-
tions in the TCLP extract with the levels
identified  in  the appropriate regulations.
Refer to section 8.0 for quality assurance re-
quirements.

           8.0  Quality Assurance

  8.1 A minimum  of  one blank (using the
same extraction fluid  as used for the sam-
ples) must be analyzed for every 20 extrac-
tions that have been conducted in an extrac-
tion vessel.
  8.2 A matrix spike shall be performed for
each waste type (e.g., wastewater treatment
sludge, contaminated  soil, etc.) unless the
result exceeds the  regulatory level and the
data is being used solely  to  demonstrate
 that the waste property exceeds the regula-
 tory level. A minimum of one matrix spike
 must be analyzed for each analytical batch.
 The bias determined from the matrix spike
 determination shall be used to correct the
 measured values.  (See  sections  8.2.4 and
 8.2.5.)  As a minimum,  follow  the matrix
spike addition guidance provided in each an-
alytical method.
  8.2.1  Matrix spikes are to be added after
filtration of the TCLP extract and before
preservation. Matrix  spikes should not be
added  prior  to TCLP extraction of the
sample.
  8.2.2 In most cases, matrix spikes should
be added at a concentration equivalent to
the corresponding regulatory level. If the
analyte concentration is less than one half
the regulatory level, the spike concentration
may be as low as one half of the analyte
concentration, but may not be not less than
five  times  the method detection  limit. In
order to avoid differences in matrix effects,
the  matrix spikes must be  added to the
same nominal  volume of TCLP extract as
that which was analyzed for  the  unspiked
sample.
  8.2.3 The purpose  of the matrix spike is
to monitor the performance of the analyti-
cal methods used, and to determine whether
matrix interferences exist.  Use of other in-
ternal calibration methods, modification of
the analytical methods, or use of alternate
analytical methods may be needed to accu-
rately measure the analyte concentration of
the TCLP extract when the recovery of the
matrix spike is below the expected analyti-
cal method performance.
  8.2.4  Matrix spike recoveries are calculat-
ed by the following formula:
    %R (% Recovery)=100 (X.-XU)/K
where:
X,=measured value for the spiked sample,
Xu=measured  value   for  the   unspiked
    sample, and
K=  known value of the spike in the sample.
  8.2.5  Measured  values are  corrected for
analytical bias using the following formula:
X€=100(XU/%R)
where:
Xj=corrected value, and
Xu=measured value of the  unspiked sample.
  8.3  All  quality  control  measures  de-
scribed in  the appropriate analytical meth-
ods shall be followed.
  8.4  Samples must  undergo TCLP extrac-
tion within the following time periods:

   SAMPLE MAXIMUM HOLDING TIMES (DAYS)



Vdatites 	
Semivola-
tites .
Mercury 	
From:
Field
collection
to: TCLP
extraction
14

14
28
From:
TCLP
extraction
to:
Prepara-
tive
extraction
NA

7
NA
From:
prepara-
extraction
determi-
native
analysis
14

40
28

Total
elapsed
time
28

61
56
                                         76

-------
Environmental Protection Agency
                         Pt. 261, App. II
  SAMPLE MAXIMUM HOLDING TIMES (DAYS)-
                 Continued
   TABLE 2—SUITABLE ROTARY AGITATION
               APPARATUS l



Metals,
except
mercury 	

From:
Field
collection
to: TCLP
extraction


180
From:
TCLP
extraction
to:
Prepara-
tive
extraction


NA
From:
prepara-
extraction
to:
determi-
native
analysis


180


Total
elapsed
time


360
  NA=Not applicable.

  If sample  holding times are exceed-
ed, the values obtained will be consid-
ered minimal concentrations. Exceed-
ing the holding time is not acceptable
in establishing that a  waste  does not
exceed the regulatory level. Exceeding
the  holding  time will  not invalidate
characterization  if the waste exceeds
the regulatory level.

      TABLE 1—VOLATILE ANALYTES 1
-------
PI. 261, App. II
                                                         40 CFR Ch. I (7-1-92 Edition)
   TABLE 4—SUITABLE FILTER HOLDERS 1—
                  Continued
Company
Micro
Filtration
Systems.




Mtfpore
Corpora-
lion.


Location
Dublin, CA.
(800)
334-
7132,
(415)
828-
6010.
Bedford.
MA,
(800)
225-
3384.
Model/catalogue
No.
302400
311400





YT30142HW
XX1004700



Size
142 mm.
47 mm.





142 mm.
47 mm.



                                              lyzed. Plastic devices (not listed above) may be used when
                                              only inorganic anatytes are of concern. The 142 mm size
                                              filter holder is recommended.


                                                   TABLE 5—SUITABLE FILTER MEDIA l
Any device capable of
    th9 mst0 is
      writli ttw
                            the iquid from me toM
                               ttMt it is ch0fnicaty
                        the cmnlitusnlt to bs ana-
Company
Millipore
Corporation.
Nucteopore
Corporation.
Whatman
Laboratory
Products, Inc..
Micro FittrBbon
Systofns.

Location
Bedford, MA,
(800) 225-3384.
Pteasanton, CA.
(415) 463-2530.
Clifton. NJ. (201)
773-5800.

Dublin. CA, (800)
334-7132. (415)
828-«010.
Model
AP40

211625

GFF


GF76


Pore
Size
(ftm)
0.7

0.7

0.7


0.7



4.4 of
                                             78

-------
Environmental Protection Agency
Pt. 261, App. II
        Motor
     (30 ± 2 rpm)
1 Extraction VMM! Holder
f








              Figure 1.   Rotary Agitation Apparatus
                                  79

-------
Pt. 261, App. II
   Top Range—»

     Support Screen/
               Filter
     Support Seme
       Vfton o-rings-
Bottom Range
 Pressurized Gas
 Inlet/Outlet Valve
         40 CFR Ch. I (7-1-92 Edition)

Liquid Inlet/Outlet Valve
                                   t
 "• ••
  :/
                         ••;•'•:•.
                         #••'
       Sample
                - «•*?••:•
       Piston
                                  Gas
       Figure  2.   Zero-Headspace Extractor (ZHE)
                           80

-------
Environmental Protection Agency


                              METHOD 1311

                TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
      Pt. 261, App. II
                              f START J

( ;
t

* )

Separate
liquids from
solids with
0.6 - 0.8 urn
glass fiber
filter
i
i
<0.5%

Discard
solids

Use a
sub-sample of
waste
1
t
What is
the %
solids in the
waste?
1
100%
f

CD
i
Liquid
Separate
. liquids from
>0.5% solids with
0.6 - 0.8 urn
glass fiber
filter

Examine
solids


Solid
                                Must the
                                solid be
                                milled?
Yes
                              Extract with
                           appropriate fluid
                           1) Bottle extractor
                           for non-volatiles
                           2) ZHE  device for
                                volatile*
                                                               Reduce
                                                            particle size
                                                            fo <9.5 mm
                                    81

-------
Pt. 261, App. II
                  40 CFR Ch. I (7-1-92 Edition)
                         METHOD 1311  (CONTINUED)

                TOXICITY CHARACTERISTIC LEACHATE PROCEDURE
                               Store liquid
                                 at 4C
     Separate
   extract from
    solids with
  0.6 -  0.8  urn
    glass fiber
       filter
         Solid
      Discard
      solids
  Combine
extract with
liquid phase
  of  waste
                           Measure amount of
                           liguid and analyze
                             (mathematically
                           combine result with
                             result of  extract
                                analysis)
                                  Analyze
                                   liquid
 [
                                  STOP
 [55 FR 26987, June 29, 1990]
                                       82

-------
Environmental Protection Agency
                       Pt. 261, App. Ill
 APPENDIX III TO PART 261—CHEMICAL
       ANALYSIS TEST METHODS
  Tables 1, 2. and 3 specify the appropriate
analytical  procedures, described  in  "Test
Methods for Evaluating Solid Waste, Physi-
cal/Chemical Methods,"  (incorporated  by
reference, see § 260.11) which shall be used
to determine whether a  sample contains a
given appendix VII or VIII toxic constitu-
ent.
  Table 1 identifies each appendix VII or
VIII organic constituent  along with the ap-
proved measurement method. Table 2 iden-
tifies the corresponding  methods for inor-
ganic species. Table 3 summarizes the con-
tents of SW-846 and supplies specific sec-
tion and method numbers for sampling and
analysis methods.
  Prior  to   final sampling  and  analysis
method selection the analyst should consult
the specific section or method described in
SW-846 for additional guidance on which of
the approved methods should be  employed
for a specific sample analysis situation.
 TABLE 1—ANALYSIS METHODS FOR ORGANIC
     CHEMICALS CONTAINED IN SW-846
TABLE 1—ANALYSIS METHODS FOR ORGANIC
  CHEMICALS CONTAINED IN SW-846—Contin-
  ued
Compound
AoetonttrHe 	
Acrotein 	
AcryiamkJe 	
Acrylonrtrite 	
2.Amino-l-methylbenz6n6 (o-Toluidine) 	
4-Amino-l-metnylbenzene (p-Toluidine)
Aniline 	

Benz(a)anthracene 	
Benzo(a)pyrene 	
Benzotrichloride 	
Benzyl chloride 	
Benzo(b)fluoanthene 	 	 	

Bis(2-chloroethoxymethane) 	
Bis(2-cnloroethyt)etner 	
Bis(2-chloroisopropyl)ether 	
Carbon bisulfide 	
Carbon tetracntoride 	
Chlordane 	

Chlorinated dibenzo-p-dioxins 	
Chlorinated dibenzofurans 	 ••••-


Chloroform 	

2-Chkxopnenol 	

Creosote ' 	
Method
Numbers
8030, 8240
8030, 8240
8015. 8240
8030, 8240
8250
8250
8250
8020, 8024
8100, 8250,
8310
8100, 8250,
8310
8120. 8250
8120, 8250
8100, 8250,
8310
8100, 8250,
8270, 8310
8010, 8240
8010, 8240
8010, 8240
8015, 8240
8010, 8240
8080, 8250
8080, 8250
8280
8280
8010, 8240
8020, 8240
8010, 8240
8010, 8240
8040, 8250
8100, 8250,
8310
8100, 8250
Compound
Cresol(s) 	
Cresylic Acid(s)
Dichlorobonzene(s)
Dichlofoethane(s) 	
Dichloromethane 	
Dichloropnenoxyacetic acid 	
Dichtoropropanol 	
Dimethyl sulfate 	 	
1 l-Dimethylhydrazine (UDMH) 	
2 4-Dimethytpnenol ... . 	
Dinitrobenzene ... . 	
4 6-Dinrtro-o-cresol ... • 	
2 4-Dinttrotoluene .. . 	
2 6-Dinitrotoluene
Endrin . .. 	
2-Ethoxyethanol ... . 	
Ethyl ether 	
Ethylene dibromide 	
Ethylene truourea 	
Formaldehyde 	
Formic add 	
Heptachlor 	 	 	
Hexachtorobenzene 	
Hexachlorobutadiene 	
Hexachkxoethane ... . 	
Hexachlorocydopentadiene 	
LJndane 	
Maleic anhydride ... 	
Methanol ... . 	
Methomyl 	
Methyl bromide 	
Methyl ethyl ketone 	
Methyl isobutyl ketone 	
Napthalene
Napthopuinone
Nitrobenzene 	
4-Nitrophenol . 	
2-Nitropropdne . 	
Paraldehyde (trimer of acetaldehyde)
PentacMorophenol 	
Phenol . 	
Phorate 	 • 	
Phosphorodithioic acid esters 	

2-Picoline 	
Pyridine 	
Tetrachlorobenzene(s) 	
Tetrachloroethane(s) 	 	
Tetrachloroethene 	
Tetrachlorophenol

Toluene diisocyanate(s) 	

2 4-Toluenediamine 	
2 5-Toluenediamine 	
3 4-Toluenediamine


Trichloroethene(s) 	
Trichlorofluoromethane 	
Trichlorophenol(s) 	
2 4 5-Trichlorophenoxy proptonic acid 	
Trichloropropane 	
Vinvl chloride 	
Method
Numbers
8040, 8250
8040 8250
6010 8120
8250
8010 8240
8010 8240
8150 8250
8120 8250
8250 8270
8250
8040 8250
8090 8250
8040 8250
8090 8250
8060 8250
8080 8250
8030 8240
8015, 8240
8010, 8240
8250, 8330
8015. 8240
8250
8080, 8250
8120, 8250
8120, 8250
8010. 8240
8120, 8250
8080, 8250
8250
8010, 8240
8250
8010, 8240,
8260
8015 8240
8015 8240
8100 8250
8090 6250
8090 8250
8040, 8240
8030, 8240
8015 8240
8040, 8250
8040, 8250
8140
8140
8090, 8250
8090, 8250
8090, 8250
8120, 8250
8010, 8240
8010, 8240
8040, 8250
8020, 8024
8250
8250
8250
8250
8250
8080, 8250
8010, 8240
8010, 8240
8010, 8240
8040, 8250
8150, 8250
8010, 8240
8010, 8240
                                        83

-------
Pt. 261, App. HI
           40 CFR Ch. I (7-1-92 Edition)
TABLE 1—ANALYSIS  METHODS FOR ORGANIC
  CHEMICALS CONTAINED IN SW-846—Contin-
  ued
Compound
Wtyfidene chloride 	
Xvtone 	 - 	

Method
Numbers
8010. 8240
8020,8240

  'Analyne for phenanthrene and catbazote; if these are
present in a ratio between 1.4:1 and 5:1 creosote should be
considered present


TABLE 2—ANALYSIS METHODS FOR INORGANIC
  CHEMICALS AND  MISCELLANEOUS  GROUPS
  OF ANALYTES CONTAINED IN SW-846*
Compound

Antimony „, 	
Arsenic 	
Barium 	




Calcium
Chromium . 	
Chromium Hexavatent 	
Cobalt

•-"•fr"-*1 — - --- -"-
Iron 	

Lead 	
Magnesium


Mercury
(Molybdenum
Nickel 	
Third
Edition
Method(s)
6010
6010
6010
6010
6010, 7090,
7091
6010
6010
6010
6010
7198
6010
6010, 7210,
7211
6010. 7380,
7381
6010
6010
6010, 7460.
7461

6010
6010
Second
Edition
Method(s)

7040, 7041
7060.7061
7080.7081



7130. 7131

7190, 7191
7195. 7196,
7197




7420, 7421



7470. 7471

7520, 7521
TABLE 2—ANALYSIS METHODS FOR INORGANIC
  CHEMICALS AND  MISCELLANEOUS GROUPS
  OF ANALYTES CONTAINED IN SW-846'—Con-
  tinued
Compound
Osmium 	 ...

Selenium 	
Silicon 	
Silver 	

Thallium 	

Vanadium 	

Zinc 	

Cyanides
Total Organic Halides
Sulfides
Sulfates 	

Total Organic Carbon
Phenolics 	

Oil and Grease , . 	
Total Coliform 	 	
Nitrate 	
Chlorides 	


Alpha-Emitting Radium Isotopes
Radkjm-226

Third
Edition
Methods)
7550
6010
6010
6010
6010
6010 7770
6010, 7840,
7841
6010, 7910,
7911
6010. 7950,
7951

9022

9035, 9036,
9038
9060
9065, 9066*.
9067
9070, 9071
9131, 9132
9200
9250, 9251,
9252
9310
9315
9320

Second
Edition
Method(s)


7740, 7741

7760, 7761







9010
9020
9030














                                                  •The Third Edition of  SW-846  and its Revision I are
                                                available from the Government Printing Office, Superintend-
                                                ent of Documents. Washington, DC 20402, (202) 783-3238,
                                                document number 955-001-00000-1.
                                                  * When  Method 9066 is used it must be preceded by the
                                                manual distillation specified in  procedure 7.1 of Method
                                                9065. Just prior 10 distillation in method 9065, adjust the
                                                surfuric aod-presewed sample to pH 4 with 1+9 NaOH.
                                                After the  manual distillation is completed, the autoanalyzer
                                                manifold is simplified by connecting the re-sample line direcl-
                                                ly to the sampler.
             TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846a
Title



Uathnrl HAtArtinn 1 imft 	








s^n-yinrl Water
RAfttrarwts , 	


Saimle Praoarataon Methods 	
Third Edition
Section
No.
1.0
1.1
1.2
1.3
1.4
1.5
1.6
2.0
2.1
2.2
2.3
2.4
2.5
2.6
3.0
3.1
3.2
Method
No.

















Second Edition
Section
No.
10.0
10.1














Method
No.

















                                             84

-------
Environmental Protection Agency                            Pt. 261, App. Ill
      TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 •—Continued

Trtte
Add Digestion of Waters for Total Recoverable or
Dissolved Metals for Analysis by Flame AAS or ICP 	
Acid Digestion of Aqueous Samples and Extracts for
Total Metals for Analysis by Flame AAS or ICP
Acid Digestion of Aqueous Samples and Extracts for
Total Metals for Analysis by Furnace AAS
Dissolution Procedure for Oils Greases or Waxes
Acid Digestion of Sediments Sludges and Softs
Unttevifi fnr tha Dotarmiruitinn of Matalfi
Inductively Coupled Plasma Atomic Emissions Spec-
Atomic Absorption Methods

Antimony Flame AAS 	 ..—•
Antimony Furnace AAS , 	 	 	
Arsenic Furnace AAS 	 	 	 	 	
Arsenic Gaseous Hydride AAS 	
Barium Flame AAS 	


BerytNum Furnace AAS
CaoVrtium Flame AAS 	
Cadmium Furnace AAS 	
ftAlrattm Plama AAS
Chromium Flame AAS 	 • 	

Chromium Hexavalent, Coprecipitation 	
Chromium, Hexavalent. Cotorimetric 	
Chromium Hexavalent, Chetotioci/Extractkwv 	 	 	
Chromium, Hexavalent Differential Pulse Polarography....
P-nhflH Flame AAfi
CVthihlt PiimAr*} AA£




Lead Flame AAS 	
Lead Furnace AAS 	



Mercury in Liquid Waste. Manual Cold Vapor Technique
Mercury in Solid or Semteolid Waste. Manual Cold
Vapor Technique 	


Nickel Flame AAS 	


Selenium Furnace AAS *—. 	
Selenium Gaseous Hydride AAS 	
Silver Flame AAS 	

CyuHiiim Plama AA^











Extractions and Preparations 	
Separatory funnel Liquid-Liquid Extraction 	 	 	
rnntinimis Urujd-Uouid Extraction 	
Third Edition
Section
No.
3.2
3.2
3.2
3.2
3.2
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
3.3
4.0
4.1
4.2
4.2.1
4.2.1
4.2.1
4.2.1
Method
No.
3005
3010
3020
3040
3050
•6010
7000
7020
7040
7041
7060
7061
7080
7081
•7090
•7091
7130
7131
7140
7190
7191
7195
7196
7197
•7198
7200
7201
•7210
•7211
•7380
•7381
7420
7421
7450
•7460
•7461
7470
7471
7480
7481
7520
•7550
7610
7740
7741
7760
7761
•7770
•7840
•7841
7870
•7910
•7911
•7950
•7951



3500
3510
3520
Second Edition
Section
No.

4.1
4.1
4.1
4.1



7.0
7.0
7.0
7.0
7.0
7.0

7.0
7.0
7.0
7.0
7.0
7.0
7.0






7.0
5.0


7.0
7.0

7.0

7.0
7.0
7.0
7.0







8.0



4.2
4.2
Method
No.

3010
3020
3040
3050



7040
7041
7060
7061
7080
7081

7130
7131
7190
7191
7195
7196
7197






7420
7421


7470
7471

7520

7740
7741
7760
7761












3510
3520
                                     85

-------
Pt. 261, App. Ill                                40 CFR Ch. I (7-1-92 Edition)
      TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 •—Continued

Title
Soxhtet Extraction 	
Ultrasonic Extraction 	
Waste Dilution 	
Purge-antf-Trap ...... 	
Protocol for Analysis of Sorbent Cartridges from VOST...
Cleanup
Alumina Column Cleanup
Alumina Column Cleanup and Separation of Petroleum
Waste* 	

Sttra Gol dMren





QJJ rtmmftnrfffl*f
fOB and D8CP

AHHMfcYOtrttl OliHH^f*
VoiaMa Organic Compounds in Water by
Purge-and-Trap CapMary Column GC with
PC and EHOrolyfc CondudNtty Detector to
SaMl^M
iriTa^fri ArnAwslMte JL a> Miihiin
Phenols. 	 	 	
|J^to»A*i^B!f^a>ft

dor* 	 	 	


f*fevMfsfw4»nM4win CajMttrktaM
Oiganophoaphorua Partcidai: CapVary
Column 	

GC/MS VoMVat 	



Analysis of Chlorinated Dioxins and Dfcenzo-
hjrans . -~ 	 	
Hgh Partonnance Liquid Chromatographic Mathoda
(HPLC) . ~~ 	


t^^M^M^MW
Itoadacans Exkactton and Screening of Purgoable Organics 	
aa- 	 »• 	 .. 	 ^•^•A ^ateHwte
Total and AmanaMn CyanMa (Putaiinelilc Manual) 	
TnlBl «Mr1 AmM^t-te <^-— fWfc> fPlAMhlMfcfc- AieiMI^Mrft
Trtel (>««^r HaMas fTOXI 	
riaia^^afai rVntVM* 1 Mafto /POX>
Toltf Oryante Maidai (TOX) by NaiKvon Actuation Ana»y*t* 	 	
Acid-SotuMa and Adrt-lnaoluMo SuMWas 	

"iitfaim ifiiikMhiMifaf AiaivTMtwl rhtrvaniBlBl 	

Sialaia (TurtHdhiiatricl
Tom dnanir Carbon 	

flkBMr** TT^i Iniima^tair Aiiftnmr' — * ^ *ADk
Phenoics. tSueOrophotomelric. MBTH). 	
Third Edition
Section
No.
4.2.1
4.2.1
4.2.1
4.2.1
4.2.1
4.2.2
4.2.2
4,2.2
4.2.2
4.2.2
422
422
422
422
4.3
4.3.1
4.3.1
4.3.1
4.3.1
4.3,1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.1
4.3.2
432
4.32
432
4.32
4.32
4.3.3
4.3.3
4.4
4.4
4.4
S.O
S.O
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
Method
No.
3540
3550
3580
5030
•5040
3600
3610
•3611
3620
3630
3640
3650
3660

8000
8010
8011
8015
8020
8021
8030
8040
8060
8070
8080
8090
8100
8110
8120
8140
8141
8150
8240
8250
8260
8270
8280
8310
3810
3820
9010
9012
9020
9021
•9022
9030
9031
•9035
•9036
•9038
•9060
•9065
•9066
•9067
Second Edition
Section
No.
4.2
4.2
5.0







4.2

6.1
8.1
8.1
8.1
„.„
8.1
8.1
8.1
8.1
8.1
8.1
8.1
........
8.2
6.2
8.2
8.2
8.3
8.3
5.0
9.0
9.0
9.0

9.0







Method
No.
3540
3550
5030







3530



8010
8015
8020
8030
8040
8060
8080
8090
8100
8120
8140
.„..„..
8240
8250
8270

8310
5020

9010
9020

9030



	

                                    86

-------
Environmental Protection Agency                             Pt. 261, App. Ill
      TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 "—Continued

Title
Total Recoverable Oil and Grease (Gravimetric, Separatory
Oil and Grease Extraction Method for Sludge Samples


Nitrate


Chloride (Titrimetric Mercuric Nitrate)


Extraction Procedure for Oily Wastes
pH Etectrometric Measurement .. 	
pH Paper Method • 	
Soil pH . 	
Specific Conductance - 	



Paint Filter Liquids Test 	
Saturated Hydraulic Conductivity, Saturated leachate Conductw-

Alpha-Emitting Radium Isotopes 	
Radium-228

Ignrtability 	 -«


Test Method to Determine Hydrogen Cyanide Released
Test Method to Determine Hydrogen Sulfide Released


lanitflhitftv 	
Pensky-Martens Closed-Cup Method . 	
Setaftash Closed-Cup Method 	




Extraction Procedure (EP) Toxicity Test Method and
Structural Integrity Test 	























Waste nharactarization Strataov 	
Third Edition
Section
No.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
6.0
7.0
7.1
7.3
7.3
7.3
7.3
7.4
8.0
8.1
8.1
8.1
8.2
8.2
8.3
8.4
8.4
9.0
9.1
9.2
10.0
10.0
10.0
10.0
11.0
11.1
11.2
11.3
11.4
11.5
12.0
12.1
12.2
12.3
12.4
12.5
12.6
13.0
13.1
13.2
13.3
Method
No.
•9070
•9071
•9131
•9132
•9200
•9250
•9251
•9252
•1320
M330
9040
9041
9045
9050
•9080
•9081
9090
9095
•9100
•9310
•9315
•9320








1010
1020
1110

1310



•0010
•0020
•0030
















Second Edition
Section
No.











9.0





9.0



2.0
2.1.1
2.1.2
2.1.3

2.1.4
2.0
2.1.1
2.1.1
2.1.1
2.1.2
2.1.2
2.1.3
2.1.4
2.1.4
1.0
1.0, 1.1
1.2. 1.3, 1.4





















Method
No.











9040





9095












1010
1020
1110

1310























                                     87
    311-147  O—92-

-------
Pt. 261, App. VII                                            40 CFR Ch. I (7-1-92 Edition)

        TABLE 3—SAMPLING AND ANALYSIS METHODS CONTAINED IN SW-846 "—Continued

Title





Third I
Section
No.
134
135
136
13.7

Edition
Method
No.





Second
Section
No.





Edition
Method
No.





  •The Third Edition of SW-846 and  its Revision I  are available from the Government Printing Office, Superintendent of
Documents. Washington, DC 20402, (202) 738-3238, document number 955-001-00000-1.
  "This method may be used in conjunction with or  in addition to the methods found in the Second Edition of SW-846 as

  When Method 9066 is used it must be preceded by the manual distillation specified in  procedure 7.1  of Method 9065. Just
prior to distillation in Method 9065, adjust the  sulfuric acid-preserved sample to pH 4  with 1 +9 NaOH. After the manual
distillation is completed, the autoanalyzer manifold is simplified by connecting the re-sample line directly to the sampler.

[48 PR 15257, Apr.  8,  1983, as amended at 50 PR 2000, Jan. 14, 1985; 50 FR 42942, Oct. 23,
1985; 51 FR 5330, Feb. 13, 1986; 51 FR 6541,  Feb.  25, 1986; 51 FR 37729, Oct. 24, 1986; 54 FR
41407, Oct. 6, 1989;  54 FR 40267, Sept.  29. 1989; 55 FR 8950, Mar. 9. 1990; 55 FR 18505, May
2,1990; 55 FR 50483. Dec. 6,  1990]
APPENDIX  IV TO  PART  261—[RESERVED
   FOR RADIOACTIVE WASTE TEST  METH-
   ODS]

APPENDIX  V  TO  PART  261—[RESERVED
     FOR  INFECTIOUS  WASTE TREATMENT
     SPECIFICATIONS]

  APPENDIX VI TO  PART 261—[RESERVED
           FOR ETIOLOGIC AGENTS]

  APPENDIX VII  TO PART 261—BASIS FOR
         LISTING HAZARDOUS WASTE
                                              EPA
                                             hazard-
                                              ous
                                              waste
                                              No.
  EPA
 hazard-
  ous
  waste
  No.
 F001	
 F002	
 F003..
 F004..
 F005..
 F006..

 F007..
 F008..
 F009..
 F010..
 F011..
 F012..
 F019..
                                             F020..




                                             F021..


                                             F022..

                                             F023.



                                             F024.
     Hazardous constituents for which listed
Tetrachtoroethylene,  methytene  chloride trichlor-
  oethylene,  1,1,1-trichloroethane, carbon  tetra-
  chlofkle, chlorinated fluorocarbons.
Tetrachtoroethylene,  methylene  chloride, trichlor-
  oethylene,  1,1,1-tnchloroethane,  1,1,2-trichlor-
  oethane,  chtorobenzene,  1,1,2-trichloro-1,2,2-
  trichfluoroethane, ortho-dichlorobenzene,  trich-
  lorofluoromethane.
N.A.
Cresois and cresylic acid, nitrobenzene.
Toluene,  methyl ethyl ketone,  carbon disulfide,
  isobutanol, pyridine,  2-ethoxyethanol, benzene,
  2-nitropropane.
Cadmium, hexavalent  chromium, nickel, cyanide
  (comptexed).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (salts).
Cyanide (comptexed).
Hexavalent chromium, cyanide (complexed).
    Hazardous constituents for which listed
Tetra-  and pentachlorodibenzo-p^xins;  tetra
  and   pentachlorodi-benzofurans;   tri-    and
  tetrachlorophenols and their chlorophenoxy de-
  rivative acids, esters, ethers, amirte and other
  salts.
Penta-  and hexachtorodibenzo-p-dioxins; penta-
  and  hexachlorodibenzofurans;   pentachloro-
  phenol and its derivatives.
Tetra-,  penta-, and hexachlorodibenzo-p-dioxins;
  tetra-, penta-, and hexachlorodibenzofurans.
Tetra-,  and pentachtorodibenzo-p-dioxins; tetra-
  and  pentachlorodibenzofurans;  tri- and tetra-
  chlorophenols and their  chlorophenoxy deriva-
  tive acids, esters, ethers, amine and other salts.
Chloromethane, dichloromethane, trichlorometh-
  ane,  carbon tetrachloride,  chloroethylene,  1,1-
  dichloroethane,  1,2-dichloroethane,  trans-1-2-
  dichloroethytene,   1.1-dichloroethylene,  1,1,1-
  trichloroethane,  1,1,2-trichloroethane,  trichlor-
  oethylene, 1,1,1.2-tetra-chloroethane, 1,1,2,2-te-
  trachloroethane,  tetrachloroethytene,  pentach-
  loroethane, hexachloroethane, allyl chloride (3-
  chloropropene),  dtohloropropane,  dichloropro-
  pene, 2-chloro-1,3-butadiene,  hexachloro-1,3-
  butadiene, hexachlorocyclopentadiene, hexach-
  lorocyclohexane,  benzene, chlorbenzene,  dich-
  lorobenzenes, 1,2,4-trichkxobenzene, tetrachlor-
  obenzene, pentachtorobenzene, hexachloroben-
  zene, toluene, naphthalene.
                                                   88

-------
Environmental Protection Agency
                                                                                  Pt. 261, App.  VII
  EPA
 hazard-
  ous
 waste
  No.
F025....
F026...

F027...




F028...




F032...




F034..



F035..
F037..

F038..

F039..



K001..
 K002...
 K003...
 K004...
 K005...
 K006...
 K007...
 K008...
 K009...

 K010...
 K011..
 K013..
 K014..
     Hazardous constituents for which listed
  EPA
hazard-
  ous
 waste
  No.
Chloromethane;  Dtctiloromethane; Trichlorometh-
  ane; Carbon tetrachloride; Chkxoethylene; 1,1-
  Dichloroefhane;  1,2-Dichloroethane;  trans-1,2-
  Dfchloroethytene;  1,1-Dichloroethylene;   1,1,1-
  Trichloroethane; 1,1,2-Trichloroethane; Trichlor-
  oethylene;   1,1.1,2-Tetrachioroethane;  1,1,2,2-
  Tetrachloroethane;   Tetrachloroethylene;  Pen-
  tachloroethane;  Hexachloroethane;  Ally!  chlo-
  ride  (3-Chloropropene); Dichloropropane;  Dich-
  loropropene;  2-Chloro-1,3-butadiene;  Hexach-
  loro-1,3-butadiene;  Hexachlorocyclopentadiene;
  Benzene;   Chlorobenzene;   Dichlorobenzene;
  1,2,4-Trichlorobenzene;    Tetrachlorobenzene;
  Pentachlorobenzene; Hexachlorobenzene; Tolu-
  ene; Naphthalene.
Tetra-, penta-,  and hexachiorodibenzo-p-dioxins;
  tetra-, penta-,  and hexachlorodibenzofurans.
Tetra-, penta-,  and hexachlorodibenzo-p-dioxins;
  tetra-, penta-,  and hexachlorodibenzofurans; tri-,
  tetra-, and  pentachlorophenols and their chloro-
  phenoxy derivative acids, esters, ethers,  amine
  and other salts.
Tetra-, penta-,  and hexachlorodibenzo-p-dioxins;
  tetra-, penta-,  and hexachlorodibenzofurans; tri-,
  tetra-, and  pentachlorophenols and their chloro-
  phenoxy derivative acids, esters, ethers,  amine
  and other salts.
Benz(a)anthracene, benzo(a)pyrene,  dibenz(a.h)-
  anthracene, indeno(1,2,3-cd)pyrene, pentachlor-
  ophenol,  arsenic,   chromium,  tetra-,  penta-,
  hexa-,    heptachlorodibenzo-p-dioxins,    tetra-,
  penta-,  hexa-, heptachlorodibenzofurans.
Benz(a)anthracene.         benzo(k)fluoranthene,
  benzo(a)pyrene,         dibenz(a,h)anthracene,
  indeno(1,2,3-cd)pyrene,  naphthalene,  arsenic,
  chromium.
Arsenic, chromium, lead.
Benzene, benzo(a)pyrene, chrysene, lead, chromi-
  um.
Benzene, benzo(a)pyrene chrysene, lead, chromi-
  um.
All constituents  for which treatment standards are
  specified for multi-source leachate (wastewaters
  and nonwastewaters) under 40 CFR 268.43(a),
  Table CCW.
Pentachlorophenol.  phenol,  2-chlorophenol,  p-
  chloro-m-cresol,  2,4-dimethylphenyl,  2,4-dinitro-
  phenol, trichlorophenols,   tetrachlorophenols,
  2,4-dinitrophenol, cresosote, chrysene, naphtha-
  lene,    fluoranthene,    benzo(b)fluoranthene,
  benzo(a)pyrene,         indeno(l,2,3-cd)pyrene,
  benz(a)anthracene,  dibenz(a)anthracene,  acen-
  aphthalene.
Hexavalent chromium, lead
Hexavalent chromium, lead.
Hexavalent chromium.
Hexavalent chromium, lead.
 Hexavalent chromium.
Cyanide (complexed),  nexavalent chromium.
 Hexavalent chromium.
 Chloroform,   formaldehyde,   methylene  chloride.
   methyl chloride, paraldehyde, formic acid.
 Chloroform,   formaldehyde,   methylene  chloride,
   methyl chloride, paraldehyde, formic  acid, chtor-
   oacetakJehyde.
 Acrykxutrite, acetonitrite, hydrocyanic acid.
 Hydrocyanic acid, acrytonitrite. acetonitrile.
 Acetonitrile,  acrylamide.
K015....

K016....


K017....


K018....

K019....
K020....
K021..
K022..
K023..
K024..
K025..
K026..
K027..
K028..
K029..

K030..
 K031..
 K032..
 K033..
 K034..
 K035..
 K036...

 K037...

 K038...

 K039...

 K040...

 K041...
 K042...
 K043...

 K044...
 K045...
 K046...
 K047...
 K048..
 K049..
 K050..
 K051..
 K052.,
 K060..

 K061..
                                                                  Hazardous constituents for which listed
3enzyl chloride, Chlorobenzene, toluene,  benzo-
  trichloride.
Hexachlorobenzene,  hexachlorobutadiene,  carbon
  tetrachloride, hexachloroethane,  perchloroethy-
  lene.
Epichlorohydrin,  chloroethers  [bis(chloromethyl)
  ether and bis (2-chloroethyl) ethers], trichloro-
  propane, dichloropropanols.
1,2-dichloroethane,  trichloroethylene,  hexachloro-
  butadiene, hexachlorobenzene.
Ethylene  dichloride,  1,1,1-trichloroethane,  1,1,2-
  trichloroethane,  tetrachloroethanes  (1,1,2,2-te-
  trachloroethane  and  1,1,1,2-tetrachloroethane),
  trichloroethylene,  tetrachloroethylene,  carbon
  tetrachloride, chloroform,  vinyl chloride, vinyli-
  dene chloride.
Ethylene  dichloride,  1,1,1-trichloroethane,  1,1,2-
  trichloroethane,  tetrachloroethanes  (1,1,2,2-te-
  trachloroethane  and  1,1,1,2-tetrachloroethane),
  trichloroethylene,  tetrachloroethylene,  carbon
  tetrachloride, chloroform,  vinyl chloride, vinyli-
  dene chloride.
Antimony, carbon tetrachloride, chloroform.
Phenol,  tars  (polycyclic aromatic  hydrocarbons).
Phthalic  anhydride, mateic anhydride.
Phthalic  anhydride, 1,4-naphthoquinone.
Meta-dinitrobenzene, 2,4-dinitrotoluene.
Paraldehyde, pyndines, 2-picoline.
Toluene diisocyanate, toluene-2, 4-diamine.
1,1,1-trichloroethane, vinyl chloride.
1,2-dichloroethane,   1,1,1-trichloroethane,   vinyl
  chloride, vinylidene chloride, chloroform.
Hexachlorobenzene,  hexachlorobutadiene, hexa-
  chloroethane, 1,1,1,2-tetrachloroethane, 1,1,2,2-
  tetrachloroethane, ethylene dichloride.
Arsenic.
Hexachlorocyclopentadiene.
Hexachlorocyclopentadiene.
Hexachlorocyclopentadiene.
Creosote,  chrysene,  naphthalene,   fluoranthene
  benzo(b)    fluoranthene,     benzo(a)pyrene,
  indeno(1,2,3-cd)   pyrene,  benzo(a)anthracene,
  dibenzo(a)anthracene, acenaphthalene.
Toluene, phosphorodithioic  and phosphorothioic
  acid esters.
Toluene, phosphorodithioic  and phosphorothioic
  acid esters.
Phorate,  formaldehyde,  phosphorodithioic   and
  phosphorothioic acid  esters.
Phosphorodithioic   and   phosphorothioic   acid
  esters.
Phorate,  formaldehyde,  phosphorodithioic   and
  phosphorothioic acid  esters.
Toxaphene.
 Hexachlorobenzene, ortho-dichlorobenzene.
2,4-dichlorophenol, 2,6-dichlorophenol, 2,4,6-trich-
   lorophenol.
 N.A.
 N.A.
 Lead.
 N.A.
 Hexavalent chromium, lead.
 Hexavalent chromium, lead.
 Hexavalent chromium.
 Hexavalent chromium, lead.
 Lead.
 Cyanide,  napthalene,  phenolic  compounds,  ar-
   senic.
 Hexavalent chromium, lead, cadmium.
                                                          89

-------
Pt. 261, App.  VIII
                                                          40 CFR Ch. I (7-1-92 Edition)
  EPA
 hazard-
  ous
 waste
  No.
K062	
K064	
K065	
K066	
K069	
K071	
K073	
K083..

K084..
K085..
K086..
K087..
K088..
K090.
K091..
K093.
K094..
K095..

K096.

K097..
K098..
K099.
K100..
K101..
K102..
K103..
K104..

K105..

K106..
     Hazardous constituents for which listed
Hexavalent chromium, lead.
Lead, cadmium.
    Do.
    Do.
Hexavalent chromium, lead, cadmium.
Mercury.
Chloroform, carbon  tetrachloride, hexacholroeth-
  ane, trichloroethane.  tetrachloroethylene, dich-
  loroethylene, 1,1,2,2-tetrachloroethane.
Aniline, diphenylamine,  nitrobenzene, phenylene-
  diamine.
Arsenic.
Benzene, dichlorobenzenes, trichlorobenzenes, te-
  trachlorobenzenes, pentachlorobenzene,  hex-
  achlorobenzene, benzyl chloride.
Lead, hexavalent chromium.
Phenol, naphthalene.
Cyanide (complexes).
Chromium.
    Do.
Phthalic anhydride, maleic anhydride.
Phthalic anhydride.
1,1,2-trichkxoethane.   1,1,1,2-tetrachloroethane,
  1,1,2,2-tetrachloroethane.
1,2-dfchloroethane,   1,1,1-trichloroethane,   1,1.2-
  tnchloroethane.
Chlordane,  heptachkx.
Toxaphene.
2,4-dichlorophenol, 2,4,6-trichlorophenol.
Hexavalent chromium, lead, cadmium.
Arsenic.
Arsenic.
Aniline, nitrobenzene, phenylenediamine.
Aniline, benzene,  diphenylamine,  nitrobenzene,
  phenylenediamine.
Benzene, monochlorobenzene, dichlorobenzenes.
  2,4,6-trichlorophenol.
Mercury.
  EPA
hazard-
  ous
 waste
  No.
K107...
K108...
K109...
K110...
K111...
K112...

K113...

K114...
K115...
K116...

K117...
K118..
K123..
K124..
K125..
K126..
K131..
K132..
K136..
                                                            Hazardous constituents for which listed
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
1,1-Dimethylhydrazine (UDMH).
2,4-Dinitrotoluene.
2,4-Toluenediamine, otoluidine,  otoluidine,  ani-
  line.
2,4-Toluenediamirte, otoluidine,  otoluidine,  ani-
  line.
2,4-Toluenediamine, otoluidine, p-toluidine.
2,4-Toluenediamine.
Carbon tetrachloride, tetrachloroethylene, chloro-
  form, phosgene.
Ethylene dibromide.
Ethylene dibromide.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Ethylene thiourea.
Dimethyl sulfate, methyl bromide.
Methyl bromide.
Ethylene dibromide.
  N.A.—Waste is hazardous because it fails the test for the
characteristic of ignitability, corrosrvity, or reactivity.

[46 PR 4619, Jan. 16, 1981, as amended at 46
PR 27477,  May 20, 1981; 49 FR 5312,  Feb.
10,  1984;  50 FR  2000, Jan. 14,  1985; 50 FR
42942,  Oct. 23,  1985; 51 FR 5330, Feb. 13,
1986;  51  FR  6541,  Feb.  25, 1986;  51  FR
37729, Oct. 24, 1986; 54 FR 35421, Sept. 13,
1989; 54 FR 41407, Oct. 6, 1989; 54 FR 50978,
Dec.  11,  1989;  55 FR 18505, May 2,  1990; 55
FR 22684, June  1, 1990; 55 FR 46396, Nov. 2,
1990; 55 FR 50483, Dec. 6,1990]
                  APPENDIX VIII TO PART 261—HAZARDOUS CONSTITUENTS
Common name



Aceryl chloride
1 -Acetyl-2-thiourea




Akftcarb 	
Aldrin 	
AIM alcohol
AUul rhlfvute

4-Aminobiohenvl 	
Chemical abstracts name
Same 	
Ethanone, 1-phenyl- 	
Acetamide N-9H-fluoren-2-yl- 	
Same 	
Acetamide, N-(aminolhioxomethyl)- 	
2-Propenal 	
2-Propenamide 	
2-Propenenitrile 	
Same 	
Propanal, 2-methyl-2-(methylthio)-, O-
[(methylamino)carbonyl]oxime.
1,4,5,8-
Dimethanonaphthalene, 1,2.3.4.10,10-10-
hexachloro-1 ,4.4a,5,8.8a-hexahydro-.
(1 alpha,4alpha.4abeta,5alpha,8alpha.
Babeta)-.
2-Propen-1 -ol . 	
1 -Propane 3-chloro 	
Same 	
[1,1'-Biphenyl]-4-amine 	
Chemical
abstracts No.
75-05-8
98-66-2
53-96-3
75-36-5
591-08-2
107-02-8
79-06-1
107-13-1
1402-68-2
116-06-3
309-00-2
107-18-6
107-18-6
20859-73-6
92-67-1
Hazardous
waste No.
U003
U004
U005
U006
P002
POOS
U007
U009

P070
P004
POOS

P006

                                                    90

-------
Environmental Protection Agency
                                              Pt. 261, App. VIII
             Common name
                                                  Chemical abstracts name
                                             Chemical
                                           abstracts No.
                           Hazardous
                           waste No.
5-(Aminomethyl)-3-isoxazolol...
4-Aminopyridine	
Amitrole	
Ammonium vanadate	
Aniline	
Antimony	
Antimony compounds, N.O.S.1
Aramrte	
Arsenic	
Arsenic compounds, N.O.S.1..
Arsenic acid	
Arsenic pentoxide	
Arsenic trioxide	
Auramine	
Azaserine	
Barium	
Barium compounds, N.O.S.1...
Barium cyanide	
Benztclacridine	
Benz[a]anthracene	
Benzal chloride	
Benzene	
Benzenearsonic acid	
Benzidine	
Benzof.b]fluoranthene	
Benzo[j]fluoranthene	
Benzo(k)fluoranthene	
Benzotalpyrene	
p-Benzoquinone	
Benzotrichloride	
Benzyl chloride	
Beryllium	
Beryllium compounds, N.O.S.1
Bromoacetone	
Bromoform	
4-Bromophenyl phenyl ether..
Brucine	
Butyl benzyl phthalate	
 Cacodylic acid	
 Cadmium	
 Cadmium compounds, N.O.S.1
 Calcium chromate	
 Calcium cyanide	
 Carbon disulfide	
 Carbon oxyfluoride	
 Carbon tetrachloride	
 Chloral	
 Chlorambucil	
 Chlordane..
 Chlordane (alpha and gamma isomers)..
 Chlorinated benzenes, N.O.S.1	
 Chlorinated ethane, N.O.S.1	
 Chlorinated fiuorocarbons, N.O.S.1	
 Chlorinated naphthalene, N.O.S.1	
 Chlorinated phenol, N.O.S.1	
 Chlomaphazin	
 Chloroacetaldehyde	
 Chloroalkyl ethers, N.O.S.1	
 p-Chloroaniline	
 Chlorobenzene	
 Chlorobenzilate	
  p-Chtoro-m-cresol	
  2-Chloroethyl vinyl ether	
  Chloroform	
  Chloromethyl methyl ether..
3(2H)-lsoxazolone, 5-(aminomethyl)-..
 -Pyridinamine	
 H-1,2,4-Triazol-3-amine	
Vanadic acid, ammonium salt	
tenzenamine	
Same	
Sulfurous   acid,  2-chloroethyl   2-[4-(1,1-
  dimethylethyl)phenoxy]-1-methylethyl
  ester.
Same	
Arsenic acid H3AsO«	
Arsenic oxide AszO5	
Arsenic oxide AszOj	
Benzenamine,  4,4'-carbonimidoylbis[N,N-di-
  methyl.
L-Serine, diazoacetate (ester)	
Same	
Same	
Same	
Same	
 Benzene, (dichloromethyl)-	
Same	
Arsonic acid, phenyl-	
 [1,1'-Biphenyl]-4,4 Miamine..
 3enz[e]acephenanthrylene	
Same	
Same	
Same	
2,5-Cyclohexadiene-1,4-dione.
Benzene, (trichloromethyl)-	
Benzene, (Chloromethyl)-	
Same	
 2-Propanone, 1-bromo-	
 Methane, tribromo-	
 Benzene, 1-bromo-4-phenoxy-	
 Strychnidin-10-one, 2,3-dimethoxy-	
 1,2-Benzenedicarboxylic  acid, butyl phenyl-
   methyl ester.
 Arsinic acid, dimethyl-	
 Same	
 Chromic acid H2CrOt, calcium salt.
 Calcium cyanide Ca(CN)2	
 Same	
 Carbonic difluoride	
 Methane, tetrachloro-	
 Acetaldehyde, trichloro-.
                      acid,
4-[bis(2-
 Benzenebutanoic
   chloroethyl)amino]-.
 4,7-Methano-1H-indene,   1,2,4,5,6.7,8,8-oc-
   tachloro-2,3,3a,4,7,7a-hexahydro-.
 Naphthalenamine, N,N'-bis(2-chloroethyl)-	
 Acetaldehyde, chloro-	
 Benzenamine, 4-chloro-	
 Benzene, chloro-	
 Benzeneacetic acid, 4-chloro-alpha-(4-chlor-
   ophenyl)-alpha-hydroxy-, ethyl ester.
 Phenol, 4-chloro-3-methyl-	
 Ethene, (2-chloroethoxy)-	
 Methane, trichloro-	
 Methane, chloromethoxy-	
               2763-96-4
                504-24-5
                 61-82-5
               7803-55-6
                 62-53-3
               7440-36-0
                                                 140-57-8
                                                                                         7440-38-2
               7778-39-4
               1303-28-2
               1327-53-3
                492-80-8

                115-02-6
               7440-39-3
                 542-62-1
                 225-51-4
                  56-55-3
                  98-87-3
                  71-43-2
                  98-05-5
                  92-87-5
                 205-99-2
                 205-82-3
                 207-08-9
                  50-32-8
                 106-51-4
                  98-07-7
                 100-44-7
                7440-41-7
                 598-31-2
                  75-25-2
                 101-55-3
                 357-57-3
                  85-68-7

                  75-60-5
                7440-43-9
13765-19-0
  592-01-8
   75-15-0
  353-50-4
   56-23-5
   75-87-6
  305-03-3

   57-74-9
                 494-03-1
                 107-20-0
                  106-47-8
                  108-90-
                  510-15-6

                   59-50-7
                  110-75-8
                   67-66-3
                  107-30-:
                  P007
                  POOS
                  U011
                  P119
                  U012
                  P010
                  P011
                  P012
                  U014

                  U015
                  P013
                  U016
                  U018
                  U017
                  U019
                  U021
                  U022
                  U197
                  U023
                  P028
                  P015
                   P017
                   U225
                   U030
                   P018
                                                                                                            U136
U032
P021
P022
U033
U211
U034
U035

U036

U036
                   U026
                   P023
                   P024
                   U037
                   U038

                   U039
                   U042
                   U044
                   U046
                                                        91

-------
Pt. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
Common name
beta-Chloronaphthalene
o-Chlorophenol 	 - 	
1 -(o-Chk>ropnenyl)thk>urea
Chtoroprene 	
3-Chloroproptonrtrite 	
Chrofniom 	
Chromium compounds N O S *
Chrysene 	
Citrus red No 2 	
Coat tar creosote
Copper cyanide
Creosote
Cresof (Cresylic acid) 	
Crotonaldehyde
Cyanides (soli&le salts and complexes)
N.O.S.'.
Cyanogen bromide
Cyanogen chloride 	
Cycasin
2-Cydohexyl-4 6-dinitrophenol
Cydophosphamide 	
24-O
2 4-D salts esters - .
Daunomycin 	
ODD 	 	
DDF
DDT... 	
DiaHate 	
Dibenz[a,fi]acndine .. .

Dtb6nz[a h]anthracene
7H-Dibenzo[c glcarbazote


Dtoenzof.a,0pyrene
1 ,2-Dibromo-3-chloropropane
Dtoutyl phthalate 	
o-Dichlorobenzene 	

p-Dichlorobenzene
Dichlorobenzene NOS '
3 3'-Dichlorobenzidine
1 4-Dichloro-2-butene
Dichlorodifkjoromethdne 	
Dichtoroethylene NOS1
1 1 -Dichtoroethylene
1 2-Dichloroethylene 	
Dichtoroetrryl ether

Dichtoromethoxy ethane 	
Diohloromethyl ether 	
2 4-Dicnkxophenol
2,6-Dtchtorophenol

DicNoropropane NOS '
Dichloropropanol NOS1
Dicnloropropene NOS1
1.3-Dichlorooraoene 	
Chemical abstracts name
Naphthalene 2-chk>ro- 	
Phenol, 2-chloro- 	
Thiourea (2-chlorophenyl)-
1 3-Butadiene 2-chloro- 	
Propanenitrile, 3-chloro- 	
Same 	

Same 	 	
2-Naphthalenol, 1-[(2,5-
dimethoxyphenyl)azo]-.
Same . .. . 	
Copper cyanide CuCN
Same
Phenol, methyl- 	
2-Butenal

Ethanedinitrile
Cyanogen bromide (CN)Br 	
Cyanogen chloride (CN)a 	
beta-D-Glucopyranoside (methyl-ONN-
azoxy)methyl.
Phenol 2-cyclohexyl-4 6-dinitro- 	
2H-1 ,3 2-Oxazaphosphorin-2-amine, N,N-
bis(2-chloroethyl)tetrahydro-, 2-oxide.
Acetic acid (2 4-dichlorophenoxy)- 	

5,12-Naphthacenedione, 8-acetyl-10-[(3-
amino-2,3,6-trideoxy-alpha-L-lyxo-
hexopyranosyl)oxy ] -7,8,9, 1 0-tetrahydro-
6,8,11-trihydroxy-1-methoxy-. (8S-cis)-.
Benzene, 1,1'-(2,2-dicfiloroethylidene)bis[4-
chloro-.
Benzene 1 r-(dichlOfoethenylidene)tHS[4-
chloro-.
Benzene. 1,1 '-(2,2,2-
tnchloroethylidene)bis[4-chloro-.
Carbamothioic acid, bis(1-methylethyl)-, S-
(2,3-dichloro-2-propenyl) ester.
Same 	
Same . ..
Same 	
Same
NaphthoM 2 3 4-def]chrysene 	
DibenzoCb def}chrysene
Benzo[rst]pentapnene 	
Propane 1 2-dibromo-3-chloro- 	
1 ,2-Benzenedicarboxylic acid, dibutyl ester 	
Benzene, 1,2-dichloro- 	
Benzene 1 3-dichtoro- 	
Benzene 1 4-dichloro- 	
Benzene dichloro- 	
[1 1'-Biphenyl]-44'-diamine, 3,3'-dichkxo- 	
2-Butene 1 4-dichtoro- 	
Methane, dtehtorodifluoro- 	
Dichkxoethylene 	
Etnene 1 1-dichkxo- 	
Ethene, 1,2-dichlrol-, (E)- 	
Ethane 1 Voxybis[2-chkxo- 	
Propane 2 2'-oxybisC2-chtoro-
Ethane, 1,1'-[metnytenebts(oxy)]bis[2-
chtoro-.
Methane, oxybisCchloro- 	
Phenol 2 4-dichloro- 	
Phenol, 2,6-dJchtoro- 	
Arsonous dichloride phenyl- 	
Propane dichloro- 	
Propano) dichloro- 	
1-Propene dichloro- 	
1-Prooene. 1.3-dichtorc- 	
Chemical
abstracts No.
91-58-7
95-57-8
5344-82-1
126-99-8
542-76-7
7440-47-3

218-01-9
6358-53-8
8007-45-2
544-92-3

1319-77-3
4170-30-3

460-19-5
506-68-3
506-77-4
14901-08-7
131-89-5
50-18-0
94-75-7

20830-81-3
72-54-8
72-55-9
50-29-3
2303-16-4
226-36-8
224-42-0
53-70-3
194-59-2
192-65-4
189-64-0
189-55-9
96-12-8
84-74-2
95-50-1
541-73-1
106-46-7
25321-22-6
91-94-1
764-41-0
75-71-8
25323-30-2
75-35-4
156-60-5
111-44-4
108-60-1
111-91-1
542-88-1
120-83-2
87-65-0
696-28-6
26638-19-7
26545-73-3
26952-23-8
542-75-6
Hazardous
waste No.
U047
U048
P026

P027


U050


P029
U051
U052
U053
P030
P031
U246
P033

P034
1)058
U240
U240
U059
U060

U061
U062


U063



U064
U066
U069
U070
U071
U072

U073
U074
U075

U078
U079
U025
U027
U024
P016
U081
U082
P036



U084
                                    92

-------
Environmental Protection Agency
                                                Pt.  261, App. VIII
             Common name
                                                    Chemical abstracts name
                                               Chemical
                                             abstracts No.
              Hazardous
              waste No.
Dieldrin..
1,2:3,4-Diepoxybutane.
Diethylarsine	
1,4-Diethyleneoxide	
Dtethylhexyl phthalate.
N,N'-Diethylhydrazine	
O,O-Diethyl S-methyl dithiophosphate.
Diethyl-p-nitrophenyl phosphate	
Diethyl phthalate	
O,O-Diethyl  0-pyrazinyl  phosphoro-thioate.
Diethylstilbesterol.
Dihydrosafrole	
Diisopropylfluorophosphate (DFP).
Dimethoate..
3,3'-Dimethoxybenzidine	
p-Dimethylaminoazobenzene	
7,12-Dimethylbenz[a]anthracene	
3,3'-Dimethylbenzidine	
Dimethylcarbamoyl chloride	
1,1-Dimethylhydrazine	
1,2-Dimethylhydrazine	
alpha,alpha-Dimethylphenethylamine.
2,4-Dimethylphenol	
Dimethyl phthalate	
Dimethyl sulfate	
Dinitrobenzene, N.O.S.1	
4,6-Dinitro-o-cresol	
4,6-Dinitro-o-cresol salts	
2,4-Dinitrophenol	
2,4-Dinitrotoluene	
2,6-Dinitrotoluene	
Dinoseb	
Di-n-octyl phthalate	
Diphenylamine	
1,2-Dipheny)hydrazin9	
Di-n-propylnitrosamine	
Disulfoton	
 Dithiobiuret..

 Endosulfan..
 Endothall.

 Endrin	
 Endrin metabolites.
 Epichlorohydrin	
 Epinephrine	
 Ethyl carbamate (urethane)	
 Ethyl cyanide	
 Etnylenebisdithiocarbamic acid	
 Ethytenebisdithiocarbamic  acid,   salts  and
   esters.
 Ethylene dibromide	
 Ethytene dichloride	
 Etnytene glycol monoethyl ether	
2,7:3,6-Dtmethanonaphth[2,3-b]oxirene,
  3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
  octahydro-,
  (laalpha,2beta,2aalpha,3beta,6beta,
  6aalpha,7beta,7aalpha)-.
2,2'-Bioxirane	
Arsine, diethyl-	
1,4-Dioxane	
1,2-8enzenedicarboxylic  acid,   bis(2-ethyl-
  hexyl) ester.
Hydrazine,  1,2-diethyl-	
Phosphorodithioic acid, O,O-diethyl S-methyl
  ester.
Phosphoric acid, diethyl 4-nitrophenyl ester....
1,2-Benzenedicarboxylic acid, diethyl ester	
Phosphorothioic acid,  O,O-diethyl  O-pyra-
  zinyl ester.
Phenol,  4,4'-(1,2-diethyl-1,2-ethenediyl)bis-,
  (E)-.
1,3-Benzodioxole, 5-propyl-	
Phosphorofluoridic  acid,  bis(l-methylethyl)
  ester.
Phosphorodithioic  acid, O.O-dimethyl S-t2-
  (methylamino)-2-oxoethyl]  ester.
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-..
Benzenamine, N,N-dimethyl-4-(phenylazo)-	
BenzCalanthracene, 7,12-dimethyl-	
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-	
Carbamic chloride, dimethyl-	
Hydrazine,  1,1-dimethyl-	
Hydrazine,  1,2-dimethyl-	
Benzeneethanamine, alpha.alpha-dimethyl-....
Phenol, 2,4-dimethyl-	
1,2-Benzenedicarboxylic acid, dimethyl ester.
Sulfuric acid, dimethyl ester	
Benzene, dinitro-	
Phenol, 2-methyl-4,6-dinitro-	
 Phenol, 2,4-dinitro-	
 Benzene, 1-methyl-2,4-dinitro-	
 Benzene, 2-methyl-1,3-dinitro-	
 Phenol, 2-(1 -methylpropyl)-4,6-dinitro-	
 1,2-Benzenedicarboxylic acid, dioctyl ester	
 Benzenamine, N-phenyl-	
 Hydrazine, 1,2-diphenyl-	
 1-Propanamine, N-nitroso-N-propyl-	
 Phosphorodithioic  acid,   O,O-diethyl   S-C2-
   (ethylthio)ethyl] ester.
 Thioimidodicarbonic diamide  [(H,N)C(S)]2N
   H.
 6,9-Methano-2,4,3-benzodioxathiepin,
   6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-
   hexahydro-, 3-oxide.
 7-Oxabicycto[2.2.1]heptane-2,3-dicarboxylic
   acid.
 2,7:3,6-Dimethanonaphth[2,3-b]oxirene,
   3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-
   octa-hydro-,
   (1aalpha,2beta,2abeta,3alpha,6alpha,
   6abeta.7beta,7aatpha)-.
 Oxirane, (chloromethyl)-	
 1,2-Benzenediol,            4-[1-hydroxy-2-
   (methylamino)ethyl]-, (R)-.
 Carbamic acid, ethyl ester	
 Propanenrtrile	
 Carbamodithioic acid, 1,2-ethanediylbis-	
 Ethane, 1,2-dibromo-.
 Ethane, 1,2-dichloro-.
 Ethanol, 2-ethoxy-	
                                                                                               60-57-1
 1464-53-5
  692-42-2
  123-91-1
  117-81-7

 1615-80-1
 3288-58-2

  311-45-5
   84-66-2
  297-97-2

   56-53-1

   94-58-6
   55-91-4

   60-51-5

  119-90-4
   60-11-7
   57-97-6
  119-93-7
   79-44-7
   57-14-7
  540-73-8
  122-09-8
  105-67-9
  131-11-3
   77-78-1
25154-54-5
  534-52-1
   51-28-5
  121-14-2
  606-20-2
   88-85-7
  117-84-0
  122-39-4
  122-66-7
  621-64-7
  298-04-4

  541-53-7

  115-29-7


  145-73-3

    72-20-8
   106-89-8
    51-43-4

    51-79-6
   107-12-0
   111-54-6
   106-93-4
   107-06-2
   110-80-5
                                                                                                                P037
U085
P038
U108
U028

U086
U087

P041
U088
P040

U089

U090
P043

P044

U091
U093
U094
U095
U097
U098
U099
P046
U101
U102
U103
 P047
 P047
 P048
 U105
 U106
 P020
 U017
 U109
 U111
 P039

 P049

 P050


 P088

 P051
 P051
 U041
 P042

 U238
 P101
 U114
 U114

 U067
 U077
 U359
                                                          93

-------
Pi. 261, App. VIII
                              40 CFR Ch. I (7-1-92  Edition)
             Common name
                                                   Chemical abstracts name
                                              Chemical
                                            abstracts No.
            Hazardous
            waste No.
Ethyteneimine	
Ethytene oxide	
Ethytenethiourea	
Ethylidene dicnloride	
Ethyl methacrylate	
Ethyl methanesulfonate..
Famphur	
Fluoranthene	
Fluorine	
Fluoroacetamide	
Fluoroacetic acid, sodium salt...
Formaldehyde	
Formic acid	
Grycidylaldehyde	
Halomethanes, N.O.S.'	
Heptachlor	
Aziridine	
Oxtrane	
2-lmidazolidinethione	
Ethane, 1,1-dichloro-	
2-Propenoic acid. 2-methyl-, ethyl ester	
Methanesulfonic acid, ethyl ester	
Phosphorolhiote         acid,         O-[4-
  t(dimethylamino)sulfonyl]phenyl]   O,O-di-
  methyl  ester.
Same	
Same	
AcetamkJe, 2-fluoro-	
Acetic  acid, fluoro-, sodium salt	
Same	
Same	
Oxiranecarboxyaldehyde	
Heptachlor epoxide..
Heptachlor  epoxide   (alpha,   beta,   and
  gamma isomers).
Heptachtorodibenzofurans	
Heptachlorodibenzo-p-dioxins	
Hexachlorobenzene	
Hexachlorobutadiene	
Hexachlorocyclopentadiene	
Hexachkxodibenzo-p-dioxins	
Hexachlorodibenzofurans	
Hexachloroethane	
Hexachlorophene	
Hexachloropropene	
Hexaethyi tetraphosphate	
Hydrazine	
Hydrogen cyanide	
Hydrogen fluoride	
Hydrogen suffide	
lndenotl,2,3-cd]Dyrene	
Isobutyl alcohol	
Isodrin	
4,7-Methano-1 H-indene,   1,4,5,6,7,8,8-hep-
  tachloro-3a,4,7,7a-tetrahydro-.
2,5-Methano-2H-indenof 1,2-Woxirene,
  2,3,4,5,6,7,7-heptachloro-1 a,1 b,5,5a,6.6a-
  hexa-                           hydro-,
  (1 aalpha, 1 bbeta,2alpha,5alpha,
  5abeta,6beta,6aalpha)-.
Benzene, hexachkxo-	
1,3-Butadiene, 1,1,2,3,4,4-hexachloro-	
1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
 Isosafrote..
 Kepone	
 Lasiocarpine..
 Lead	
 Lead compounds. N.O.S.'
 Lead acetate	
 Lead phosphate	
 Lead subacetate	
 Lindane	
 Mateic anhydride.
 Matechydrazide.
 Malononrtrile	
 Melphalan	
 Mercury	
 Mercury compounds, N.O.S.'.
 Mercury fulminate	
 Methacrytonrtrile	
Ethane, hexachtoro-	
Phenol. 2,2'-methytenebis[3,4,6-trichloro-...
1-Propene, 1,1,2,3,3,3-hexachloro-	
Tetraphosphoric acid, hexaethyl ester	
Same	
Hydrocyanic acid	
Hydrofluoric acid	
Hydrogen sulfide H.S	
Same	
1-Propanol, 2-methyl-	
1,4.5,8-
   Dimethanonaphthalene,  1,2,3,4,10,10-
   hexachloro-1,4,4a,5,8,8a-hexahydro-,
   (lalpha,4alpha,4abeta,5beta,8beta,Babeta)-
1,3-Benzodioxole, 5-(1-propenyl)-	
1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-
   one,  1,1a,3.3a,4,5,5,5a,5b,6-
   decachlorooctahydro-.
2-Butenoic acid, 2-methyl-,7-[t2,3-dihydroxy
   2-(1 -methoxyethyl)-3-methyl-1 -
   oxobutoxy]methyl]-2,3,5,7a-tetrahydro-lH-
   pyrrolizin-1-yl ester,
   [lS-tlalpha(Z),7(2S',3R*),7aalpha]]-
Sam«	
 Acetic acid, tead(2+) salt	
 Phosphoric acid, lead(2+) salt (2:3)	
 Lead, bis(acetato-O)tetrahydroxytri-	
 Cyclohexane,        1,2,3,4,5,6-hexachloro-.
   (1 alpha,2alpha,3beta,4alpha,5alpha,6beta)-
 2,5-Furandk>ne	
 3,6-Pyridazinedione,  1,2-dihydro-	
 Propanedinitrile	
 L-Phenylalanine,                  4-tbis(2-
   chloroethyl)aminol]-.
 Same	
 151-56-4
  75-21-8
  96-45-7
  75-34-3
   97-63-2
  62-50-0
  52-85-7
 206-44-0
7782-41-4
 640-19-7
  62-74-8
  50-00-0
  64-18-6
 765-34-4
  76-44-8

1024-57-3
 118-74-1
  87-68-3
  77-47-4
  67-72-1
  70-30-4
1888-71-7
 757-58-4
 302-01-2
  74-90-8
7664-39-3
7783-06-4
 193-39-5
  78-83-1
 465-73-6
  120-58-1
  143-50-0
                                                                                             303-34-1
                                                                                            7439-92-1
  301-04-2
 7446-27-7
 1335-32-6
   58-89-9

  108-31-6
  123-33-1
  109-77-3
  148-82-3

 7439-97-6
 Fulminic acid, mercury(2-i-) salt..
 2-Propenenitrite, 2-methyl-	
  628-86-4
  126-98-7
P054
U115
U116
U076
U118
U119
P097
U120
P056
P057
P058
U122
U123
U126
                                                                   P059
U127
U128
U130
U131
U132
U243
P062
U133
P063
U134
U135
U137
U140
P060
U141
U142
                                                                                                              4143
 U144
 U145
 U146
 U129

 U147
 U148
 U149
 U150

 U151
 P065
 U152
                                                        94

-------
Environmental Protection Agency
Pt. 261, App. VIII
Common name
Methapyrilene
Methomyl .. ....
Methoxychlor
Methyl bromide . 	
Methyl chloride 	
Methyl chlorocarbonate 	 , 	
Methyl chloroform
3-Methylcholanthrene 	
4 4'-Methylenebis(2-chloroaniline) 	 	


Methyl ethyl ketone (MEK)

Methyl hydrazine
Methyl iodide
Methyl isocyanate
2-Methytlactonitrile
Methyl methacrylate

Methyl parathton
Methylthiouracil 	 • 	
Mrtomycin C
MNNG

Naphthalene




Nickel
Nickel compounds N O S '
Nickel carbonyl
Nickel cyanide
Nicotine 	
Nicotine salts
Nitric oxide







salt.
n-Mitrnnhannl




N-Nitrosodietnyiamine

N-Nrtroso-N-ethylurea

N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane 	


N-Nitrosonomicotine 	
j
Chemical abstracts name
1 2-Ethanediamine, N,N-dimethyl-N'-2-pyri-
dinyl-N'-(2-thienylmethyl)-.
Ethanimidothioic acid, N-
[ [ (methylamino)carbonyl ] oxy ] - , methyl
ester.
Benzene, 1, 1 '-(2.2,2-
trichloroethylidene)bis[4-methoxy-.
Methane, bromo- 	
Methane, chloro- 	
Carbonochloridic acid, methyl ester 	
Ethane 1 1 1-trichloro- 	
Benz[j]aceanthrylene, 1 ,2-dihydro-3-methyl- ...
Benzenamine, 4,4'-methylenebis[2-chloro- 	
Methane dibromo-.. 	
Methane dichloro-.. 	
2-Butanone ... .... 	
2-Butanone peroxide
Hydrazine, methyl- 	
Methane, iodo- 	
Methane, isocyanato- 	
Propanenitrile, 2-hydroxy-2-methyl- 	
2-Propenoic acid, 2-methyl-, methyl ester 	
Methanesulfonic acid methyl ester 	
Phosphorothioic acid, O,O-dimethyl O-(4-ni-
trophenyl) ester.
4(1 H)-Pyrimidinone, 2,3-dihydrc-6-methyl-2-
thioxo-.
Azirino[2',3':3,4]pyrrolo[1,2-a]indole-4,7-
dione,
6-amino-8- [ [ (aminocarbonyl)oxy ] methyl ] -
1 , 1 a,2,8,8a,8b-hexahydro-Ba-methoxy-5-
methyl-, [laS-
(1 aalpha,8beta,8aalpha,8balpha)]-.
Guanidine, N-methyl-N'-nitro-N-nitroso- 	
Ethane 1 1 '-thk>bist2-chlor o- 	
Same 	
1 4-Naphthalenedione 	
1-Naphthatenamine 	
2-Naphthalenamine 	
Thiourea 1-naphthalenyl- 	
Same 	

Nickel carbonyl Ni(CO)«, (T-4)- 	
Nickel cyanide Ni(CN), 	
Pyridine, 3-(1-methy1-2-pyrrolkJinyl)-, (S)- 	

Nitrogen oxide NO 	
Benzenamine, 4-nitro- 	
Benzene, nitre- 	
Nitrogen oxide NOi 	
Ethanamine, 2-chloro-N-(2-chloroethyl)-N-
methyl-.
Ethanamine 2-chloro-N-(2-chloroethyl)-N-
methyl-, N-oxide.
1 2,3-Propanetriol, trinitrate 	
Phenol 4-nitro- 	
Propane 2-nitro* 	

1-Butanamine, N-butyl-N-nitroso- 	
Ethanol 2 2'-(nitrosoimino)bis- 	
Ethanamine, N-ethyl-N-nitroso- 	
Methanamine, N-methyl-N-nitroso- 	
Urea N-ethyl-N-nitroso- 	
Ethanamine N-methyl-N-nitroso- 	
Urea N-methyl-N-nitroso- 	
Carbamic acid, methylnitroso-. ethyl ester 	
Vinylamine, N-methyl-N-nitroso- 	
Morpholine 4-nrtroso- 	
Pyridine, 3-(1-nitroso-2-pyrrolidiny1)-, (S)- 	
Chemical
abstracts No.
91-80-5
16752-77-5
72-43-5
74-83-9
74-87-3
79-22-1
71-55-6
56-49-5
101-14-4
74-95-3
75-09-2
78-93-3
1338-23-4
60-34-4
74-88-4
624-83-9
75-86-5
80-62-6
66-27-3
298-00-0
56-04-2
50-07-7
70-25-7
505-60-2
91-20-3
130-15-4
134-32-7
91-59-8
86-88-4
7440-02-0

13463-39-3
557-19-7
54-11-5

10102-43-9
100-01-6
98-95-3
10102-44-0
51-75-2

126-85-2

55-63-0
100-02-7
79-46-9
35576-91-1D
924-16-3
1116-54-7
55-18-5
62-75-9
759-73-9
10595-95-6
684-93-5
615-53-2
4549-40-0
59-89-2
16543-55-8
Hazardous
waste No.
U155
P066
U247
U029
U045
U156
U226
U157
U158
U068
U080
U159
U160
P068
U138
P064
P069
U162

P071
U164
U010
U163

U165
U166
U167
U168
P072


P073
P074
P075
P075
P076
P077
U169
P078




P081
U170
U171

U172
U173
U174
P082
U176

U177
U178
P084


                                   95

-------
PI. 261, App. VIII
40 CFR Ch. I (7-1-92 Edition)
Common name
N-Nitrosopiperidine .. .. 	
N-Nitrosopyrrolidine . 	

5-Nitro-o-toluidine . .
Octamethylpyrophosphoramide
Osmium tetrowde . . 	
Paraldehyde

Pentachtorobenzene

Pentachlorodibenzofurans
Pentachtoroethane
Pentachtoronttrooenzene (PCNB)
Pentachtorophenol 	 	

Phenol

Phenytmercury acetate .. 	


Phosphine
Phorate 	 	
Phthalic acid esters N O S *
PhthaNc anhydride
2-PicoHne 	
Potychkxinaled biphenyts N O S '

Potassium silver cyanide
Pronamide
1 3-propane sultone 	





Pyridine
Reserpine 	



Satrote





Silver
Silver compounds N O S '

Sirvex (2 4 5-TP) . 	




TCDD



Tetrachloroethane N O S l
111 2-Tetrachloroethane
1 1 2,2-Tetrachtoroethane

234 6-Tetrachtorophenoi

Chemical abstracts name
Piperidine, 1-nitroso- 	
Pyrrolidine, 1-nitroso- 	
Qlycine N-methyl-N-nitroso-
Benzenamine, 2-methyl-5-nitro- 	
Diphosphoramide octamethyl- 	
Osmium oxide OsO., (T-4)- 	
1 3 5-Trioxane, 2 4,6-trimethyl- 	
Phosphorothioic acid, O O-diethyl O-(4-nitro-
phenyl) ester.
Benzene, pentachloro- 	


Ethane pentachloro- 	
Benzene pentachloronitro- 	 	
Phenol, pentachloro- 	
Acetamide N-(4-ethoxyphenyl)- 	
Same . 	
Benzenediamtne 	
Mercury, (acetatc-O)phenyt- 	
Thiourea phenyt- 	
Carbonic dichtonde 	
Same 	
Phosphorodithioic acid, O,O-diethyl S-
[(ethylthio)methylj ester.
1 ,3-lsobenzofurandione 	
Pyridine, 2-methyl- 	

Potassium cyanide K(CN) 	
Argentate(1 -), bis(cyano-C)-, potassium 	
Benzamkle, 3,5-dtehloro-N-(1,1-dimethyl-2-
propynyl)-.
1 ,2-Oxathiolane, 2,2-dk>xide 	
1-Propanamine 	
2-Propyn-1-ol 	 	
Propane 1 2-dichtoro- 	
Aziridine 2-methyl- 	
4( 1 H)-Pyrimidinone 2 3-dihydro-6-propyl-2-
thioxo-.
Same 	
Yohimban-16-carboxylic acid, 11,17-dimeth-
oxy-18-t(3,4,5-trimethoxybenzoyl)oxyj-
smethyf ester,
(3beta, 1 6beta, 1 7alpha, 1 8beta,20alpha)-.
1 3-Benzenediol 	
1 2-Benzisothiazol-3(2H)-one, 1,1 -dioxide 	

1 ,3-Benzodioxote, 5-(2-propenyl)- 	
Same 	

Selenious acid
Selenium sulfide SeSi 	
Same . 	
Same . . 	

Silver cyanide Ag(CN) 	
Propanoic acid, 2-(2,4,5-trichlorophenoxy)- 	
Sodium cyanide Na(CN) 	
D-Glucose, 2-deoxy-2-
t f(metriylnitrosoamino)carbonyl)amino] -.
Strychnidin-10-one 	

Dibenzotb e] 1 1 ,4]dioxin, 2,3,7,8-tetrachloro- .
Benzene 124 5-tetrachtoro- 	


Ethane tetrachtoro- N O S 	
Ethane 111 2-tetrachtoro- 	
Ethane 1 1 2 2-tetrachtoro- 	
Ethene tetrachkxo- 	
Phenol 2 3 4.6-tetrachtoro- 	
ThKxtohosphoric acid, tetraethyl ester 	
Chemical
abstracts No.
100-75-4
930-55-2
1 3256-22-9
99-55-8
152-16-9
20816-12-0
123-63-7
56-38-2
608-93-5


76-01-7
82-68-8
87-86-5
62-44-2
108-95-2
25265-76-3
62-38-4
103-85-5
75_44_5
7803-51-2
298-02-2

85-44-9
109-06-8

151-50-6
506-61-6
23950-58-5
1120-71-4
107-10-8
107-19-7
78-87-5
75-55-8
51-52-5
110-86-1
50-55-5
108-46-3
81-07-2

94-59-7
7782-49-2

7783-00-8
7488-56-4
630-10-4
7440-22-4

506-64-9
93-72-1
143-33-9
18883-66-4
57-24-9

1746-01-6
95-94-3


25322-20-7
630-20-6
79-34-5
127-18-4
58-90-2
3689-24-5
Hazardous
waste No.
U179
U180

U181
P085
P087
U182
P089
U183


U184
U185
See F027
U187
U188

P092
P093
P095
P096
P094

U190
U191

P098
P099
U192
U193
U194
P102
U083
P067

U196
U200
U201
U202
U202
U203


U204
U205
P103


P104
See F027
P106
U206
P106
P108

U207



U208
U209
U210
SeeF027
P109
                                    96

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Environmental Protection Agency
Pt. 261, App. VIII
Common name
Tetraethyl lead ...
Tetraethyl pyrophosphate ....
Tetranitromethane
Thallium
Thallium compounds N.O S '
Thallic oxide
Thallium(l) acetate .
Thallium(l) carbonate 	
Thallium(l) chloride
Thatlium(l) nitrate
Thallium selenite 	
Thallium(l) sulfate
Thioacetamide 	
Thiofanox
Thiomethanol 	
Thiophenol
Thiosern'carbaz'dfi
Thiourea . .. 	
Thiram 	
Toluene .. ... . .
Toluenediamine
Toluene-2 4-diamine
Toluene-2 6-diamine
Toluene-3 4-diamine
Toluene diisocyanate


p-Toluidine

1 2 4-Trichlorobenzene
1 1 2-Trichloroethane 	 	 	
Trichloroethylene
Trichloromethanethiol ... 	

2 4 5-Trichlorophenol
2 4 6-Trichlorophenol
245-T 	



1 3 5-Trinitrobenzene

Tris(2 3-dibromopropyl) phosphate
Trypan blue ... .... 	
Uracil mustard ... 	
Vanadium pentoxide .. ... 	
Vinyl chloride
Warfarin 	
Warfarin 	

tons less than 0.3%.
Warfarin salts when present at concentra-
tions greater than 0.3%.
Zinc phosphide
Zinc phosphide 	

Chemical abstracts name
Plumbane tetraethyl-
Diphosphoric acid tetraethyl ester
Methane tetranitro-
Same

Thallium oxide TI2Oj
Acetic acid thailium(1 +) salt
Carbonic acid dithallium(1 + ) salt 	
Thallium chloride TICI
Nitric acid thallium(1 + ) salt
Selenious acid dithallium(l+) salt 	
Sulfuric acid dithallium(1 +) salt
Ethanethioamide 	 	
2-Butanone 3 3-dtmethyl- 1 -(methylthio)- 0-
[(methylamino)carbonyl] oxime.
Methanethiol 	
Benzenethiol 	
Hydrazinecarbothioamide
Same 	
Thioperoxydicarbonic diamide [(H2N)C(S)]jS
2, tetramethyl-.
Benzene, methyl- 	
Benzenediamine, ar-methyl- 	
1 3-Benzenediamine 4-methyl-
1 ,3-Benzenediamine, 2-methyl- 	
1 2-Benzenediamine 4-methyl-
Benzene, 1 ,3-diisocyanatomethyl- 	
Benzenamine 2-methyl-
Benzenamine 2-methy(- hydrochtoride
Benzenamine 4-methyl- 	
Same
Benzene, 1,2,4-trichloro- 	
Ethane, 1,1,2-trichloro- 	
Ethene trichloro- 	 	
Methanethiol, trichloro- 	
Methane trichforofluoro-
Phenol 2 4,5-trichloro- 	
Phenol, 2,4,6-trichloro- 	
Acetic acid, (2,4,5-trichlorophenoxy)- 	

Propane 1 2,3-trichloro- 	
Phosphorothioic acid O O O-triethyl ester 	
Benzene 1 ,3,5-trinitro- 	
Aziridine 1 1' 1 "-phosphinothioylidynetris- 	
1-Propanol, 23-dibromo-, phosphate (3:1) 	
2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-di-
methyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]-
bis[5-amino-4-hydroxy-, tetrasodium salt.
2,4-(1 H,3H)-Pyrimidinedione, 5-[bis(2-
chloroethyl)amino]-.
Vanadium oxide VjOs 	
Ethene, chloro- 	
2H-1 -Benzopyran-2-one, 4-hydroxy-3-(3-oxo-
1-phenylbutyl)-, when present at concen-
trations less than 0.3%.
2H-1 -Benzopyran-2-one, 4-hydroxy-3-(3-oxo-
1-phenylbutyl)-, when present at concen-
trations greater than 0.3%.

Zinc cyanide Zn(CN)2 	
Zinc phosphide ZnjPi, when present at con-
centrations greater than 10%.
Zinc phosphide Zn3Ps, when present at con-
centrations of 10% or less.
Chemical
abstracts No.
78-00-2
107-49-3
509-14-8
7440-28-0

1314-32-5
563-68-8
6533-73-9
7791-12-0
10102-45-1
12039-52-0
7446-18-6
62-55-5
39196-18-4
74-93-1
108-98-5
79-19-6
62-56-6
137-26-8
108-88-3
25376-45-8
95-80-7
823-40-5
496-72-0
26471-62-5
95-53-4
636-21-5
106-49-0
8001-35-2
120-82-1
79-00-5
79-01-6
75-70-7
75-69-4
95-95-4
88-06-2
93-76-5
25735-29-9
96-18-4
126-68-1
99-35-4
52-24-4
126-72-7
72-57-1
66-75-1
1314-62-1
75-01-4
81-81-2
81-81-2


557-21-1
1314-84-7
1314-84-7

Hazardous
waste No.
Pi 10
P111
P112


P113
U214
U215
U216
U217
P114
P115
U218
P045
U153
P014
P116
U219
U244
U220
U221



U223
U328
U222
U353
P123

U227
U228
P118
U121
See F027
SeeF027
See F027



U234

U235
U236
U237
P120
U043
U248
P001
U248
P001
P121
P122
U249

  1 The abbreviation N.O.S. (not otherwise specified) signifies those members of the general class not specifically listed by
name in this appendix.
                                              97

-------
Pt. 261, App.  IX
                                                      40 CFR Ch.  I  (7-1-92  Edition)
[53 PR 13388, Apr. 22, 1988, as amended at 53 FR 43881, Oct. 31, 1988; 54 FR 50978, Dec. 11,
1989; 55 FR 50483. Dec. 6, 1990; 56 FR 7568, Feb. 25, 1991]
      APPENDIX IX TO PART 261—WASTES  EXCLUDED UNDER §§ 260.20 AND 260.22
                    TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES
   Facility
                 Address
                                                             Waste description
Aptus. Inc	
Coffeyville,
  Kansas.
Kiln residue and spray dryer/baghouse residue (EPA Hazardous Waste No. F027) generated
  during the treatment of cancelled pesticides containing  2,4,5-T and Silvex and related
  materials by Aptus1 incinerator at Coffeyville, Kansas after December 27, 1991, so long as:
(1) The incinerator  is monitored continuously and is in compliance with operating permit
  conditions. Should the incinerator  fail to comply with the permit conditions relevant to the
  mechanical operation of the incinerator, Aptus must test the residues generated during the
  run when the failure occurred according to the requirements of Conditions (2) through (4),
  regardless of whether or not the  demonstration  in  Condition (5)  has  been made.
(2) A minimum of  four grab samples must be taken from each hopper (or other container) of
  kiln residue generated during each 24 hour run; all grabs collected during a given 24 hour
  run must then be composited to form one composite sample.  A minimum of four grab
  samples must also be taken from  each  hopper (or other  container) of  spray dryer/
  baghouse residue generated during each 24 hour run; all grabs collected during a given 24
  hour  run must then be composited to form one composite sample. Prior to the disposal of
  the residues  from each 24 hour run, a TCLP leachate test must be performed on these
  composite samples and  the  leachate analyzed for the TC  toxic  metals, nickel,  and
  cyanide. If arsenic, chromium, lead or silver TC leachate  test  results exceed 1.6  ppm,
  barium levels exceed 32 ppm, cadmium or selenium levels exceed  0.3 ppm, mercury
  levels exceed 0.07 ppm, nickel levels exceed 10 ppm, or cyanide levels exceed 6.5 ppm,
  the wastes must be retreated to achieve these  levels or  must be disposed in accordance
  with  subtitle C of RCRA.  Analyses must be performed according to SW-846 methodolo-
  gies.
(3) Aptus must generate, prior to the disposal of the residues, verification data from each 24
  hour run for each treatment  residue (i.e., kiln residue, spray dryer/baghouse residue) to
  demonstrate  that the maximum  allowable  treatment  residue concentrations listed below
  are not exceeded. Samples must  be collected as specified in Condition  (2). Analyses must
  be performed according to SW-846 methodologies. Any residues which exceed any of the
  levels listed below must be retreated or must be disposed of as hazardous.
Kiln  residue and  spray dryer/baghouse residue must not  exceed the following  levels:
Aldrin—0.015 ppm
Benzene—9.7 ppm
Benzo(a)pyrene—0.43 ppm
Benzo(b)fluoranthene—1.8 ppm
Chlordane—0.37 ppm
Chloroform—5.4 ppm
Chrysene—170 ppm
Dibenz(a,h)anthracene—0.083 ppm
1,2-Dichloroethane—4.1 ppm
Dichloromethane— 2.4 ppm
2,4-Dichlorophenol—480 ppm
Dichlorvos—260 ppm
Disulfaton—23 ppm
Endosullan 1—310 ppm
Fluorene—120 ppm
lndeno(1,2.3,cd)-pyrene—330 ppm
Methyl parathion—210 ppm
Nitrosodiphenylamine—130  ppm
Phenanthrene—150 ppm
Polychlorinated biphenyls—0.31 ppm
Tetrachloroethylene—59 ppm
2,4,5-TP (silvex)—110 ppm
2,4.6-Trichloropnenol—3.9 ppm
                                                     98

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Environmental  Protection Agency                                            Pt. 261, App. IX

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
    Facility
   Address
                                                 Waste description
Arco Building
  Products.
Arco Chemical
  Co.
Arkansas
  Department
  of Pollution
  Control and
  Ecology.
Sugarcreek.
  Ohio.
Miami, FL	

Vertac
  Superfund
  site,
  Jackson-
  ville,
  Arkansas.
(4) Aptus must generate, prior to disposal  of residues, verification data from each  24 hour
  run for  each treatment  residue  (i.e.,  kiln residue,  spray  dryer/baghouse residue)  to
  demonstrate that the residues do not contain tetra-, penta-, or hexachlorodibenzo-p-dioxins
  or furans  at levels of regulatory concern. Samples  must be collected  as specified in
  Condition (2). The TCDD equivalent levels for the solid residues must be less than  5 ppt.
  Any residues with detected dioxins or furans in excess of this  level must be retreated or
  must be disposed of as acutely hazardous. SW-846 Method 8290, a high resolution gas
  chromatography and high resolution mass spectroscopy (HRGC/HRMS) analytical method
  must be used. For tetra- and penta-chlorinated dioxin and furan homoiogs,  the maximum
  practical quantitation limit must not exceed 15 ppt for the solid residues. For hexachiorin-
  ated dioxin and furan homologs, the maximum practical quantitation limit must not exceed
  37 ppt for the solid residues.
(5) The test data from Conditions  (1), (2), (3), and (4) must be kept on file by Aptus for
  inspection purposes and must be compiled, summarized, and submitted  to the Director for
  the Characterization and Assessment Division. Office of Solid Waste, by certified mail on a
  monthly basis and when the treatment of the cancelled pesticides and related materials is
  concluded. The testing requirements for Conditions  (2), (3), and  (4)  will  continue until
  Aptus provides the Director with the results of four  consecutive batch analyses for the
  petitioned wastes,  none of which exceed  the  maximum allowable levels listed in  these
  conditions and the  director  notifies  Aptus  that the conditions have been lifted.  All data
  submitted  will be placed in the RCRA public docket.
(6) Aptus must provide a signed copy of the following certification statement when submitting
  data in response to the conditions listed above: "Under civil and criminal penalty of law for
  the making or submission of false or fraudulent statements or representations, I certify that
  the information contained  in  or accompanying this  document is  true,  accurate, and
  complete.  As to the (those) identified  section(s) of this document for  which  I cannot
  personally verify its (their) truth and accuracy,! certify  as the  company official having
  supervisory  responsibility for the  persons who, acting under my direct  instructions,  made
  the verification that this information is true, accurate, and complete."
Dewatered wastewater treatment sludge (EPA Hazardous Waste No.  F019) generated from
  the chemical conversion coating of aluminum after August 15, 1986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste  No.  FO19) generated from
  the chemical conversion coating of aluminum after April 29,  1986.
Kiln  ash,  cyclone ash,  and  calcium chloride  salts from  incineration  of residues  (EPA
  Hazardous Waste No. F020 and F023)  generated from the primary production of 2,4,5-T
  and 2,4-D after August 24, 1990. This one-time exclusion applies only  to the incineration
  of the waste materials described in the  petition,  and  it  is conditional upon  the data
  obtained from ADPC&E's full-scale incineration  facility. To ensure that hazardous  constitu-
  ents are  not present in  the waste at  levels  of regulatory concern once the full-scale
  treatment  facility  is  in operation, ADPC&E must implement a testing program for the
  petitioned waste. This testing program must meet the following conditions for the exclusion
  to be valid:
        (1)  Testing:  Sample  collection and analyses (including quality control (OC)  proce-
          dures) must be performed according to SW-846 methodologies.
                (A)  Initial testing:  Representative grab samples must be taken from each
                  drum and kiln ash and cyclone ash generated from  each 24  hours of
                  operation, and  the grab samples  composited  to form one  composite
                  sample  of ash  for each  24-hour  period. Representative  grab  samples
                  must also be taken from  each drum of calcium chloride salts generated
                  from each 24 hours of operation and composited to form one composite
                  sample  of calcium chtoride  salts for each 24-hour  period.  The initial
                  testing requirements  must be fullfilled  for  the  following wastes:  (i)
                  Incineration by-products generated prior to and during the incinerator's
                  trial burn;  (ii) incineration by-products from the treatment  of 2,4-D wastes
                  lor one week (or 7 days if incineration is not on consecutive days) after
                  completion of  the trial  burn;  (iii)  incineration  by-products  from the
                  treatment of blended 2,4-D and 2,4, 5-T wastes for  two weeks  (or 14
                  days if incineration is  not on consecutive days) after completion  of the
                  trial burn;  and (iv) incineration by-products from the treatment of blended
                  2,4-D and 2,4,5-T wastes for one week (or 7 days if incineration is not
                  on consecutive days) when the percentage of 2, 4, 5-T wastes exceeds
                  the  maximum  percentage treated  under  Condition  (1}(A)(iu).  Prior to
                  disposal  of the  residues from each 24-hour sampling period, the daily
                  composite must be analyzed  for all the constituents  listed in  Condition
                  (3). ADPC&E must report the analytical test data, including quality control
                  information, obtained during this initial period  no later  than 90 days after
                  the start of the  operation.
                                                        99

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Pt. 261, App. IX                                                 40 CFR Ch. I (7-1-92  Edition)

              TABLE  1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
Waste description
                                              (B) Subsequent testing: Representative grab samples of each drum of kiln
                                                and  cyclone ash  generated from each week of operation  must be
                                                composited  to  form one composite sample of ash for each  weekly
                                                period. Representative grab samples of each drum of calcium chloride
                                                salts generated from each  week of operation must also  be composited
                                                to form one composite sample of calcium chloride salts for each weekly
                                                period.
                                              Prior to disposal  of  the residues from  each weekly sampling period, the
                                                weekly composites must  be analyzed for all of the constituents listed in
                                                Condition (3). The analytical data, including quality control  information,
                                                must be  compiled  and maintained on site for a minimum of three years.
                                                These data must  be furnished  upon request and made  available for
                                                inspection by any employee or representative of EPA.
                                       (2) Waste holding: The incineration  residues that are generated must be stored as
                                         hazardous until  the  initial  verification  analyses or subsequent analyses  are
                                         completed.
                                       If the composite  incineration  residue samples  (from  either Condition  (1)(A) or
                                         Condition (1)(B)) do not  exceed any  of the delisting levels set in Condition (3), the
                                         incineration residues corresponding to these  samples  may  be managed  and
                                         disposed of in accordance with all applicable solid waste regulations.
                                       If any composite incineration  residue sample exceeds any of the  delisting levels set
                                         in  Condition (3),  the incineration  residues generated during the time period
                                         corresponding to this sample must be  retreated until they meet  these levels
                                         (analyses must be repeated) or  managed  and disposed of in accordance with
                                         subtitle C of  RCRA. Incineration residues which are generated but for which
                                         analysis  is not  complete  or  valid  must be  managed  and  disposed  of in
                                         accordance with  subtitle C of RCRA,  until valid analyses demonstrate  that the
                                         wastes meet the  delisting levels.
                                       (3) Delisting levels: If concentrations in one or more of the incineration residues for
                                         any of the hazardous constituents listed below exceed their respective maximum
                                         allowable concentrations also listed below, the batch of failing waste must either
                                         be re-treated  untH  it  meets these  levels or  managed and  disposed of in
                                         accordance with subtitle C  of RCRA.
                                               (A) Inorganics (teachable): Arsenic, 0.32 ppm; Barium, 6.3 ppm; Cadmium,
                                                 0.06 ppm; Chromium, 0.32 ppm;  Cyanide, 4.4 ppm; Lead. 0.32 ppm;
                                                 Mercury, 0.01  ppm; Nickel, 4.4  ppm; Selenium,  0.06 ppm; Silver, 0.32
                                                 ppm. Metal concentrations must be measured in the  waste teachate as
                                                 per  40  CFR  261.24. Cyanide  extractions  must be conducted using
                                                 distilled water.
                                               (B)  Organics: Benzene,  0.87  ppm;   Benzo(a)anthracene,  0.10 ppm;
                                                 Benzo(a)pyrene, 0.04 ppm; Benzo (b)fluoranthene, 0.16 ppm; Chloroben-
                                                 zene, 152 ppm; o-Chkxophenol,  44 ppm; Chrysene, 15 ppm; 2, 4-D. 107
                                                 ppm; DDE, 1.0 ppm; Dibenz(a,h)anthracene, 0.007 ppm; 1, 4-Dtehtoro-
                                                 benzene, 265 ppm; 1, 1-Dichloroethylene, 1.3 ppm; trans-1,2-Dichloroeth-
                                                 ytene. 37 ppm; Dtchtoromethane, 0.23 ppm; 2,4-Dichlorophenol, 43 ppm;
                                                 Hexachkxobenzene, 0.26 ppm; Indeno (1,2,3-cd) pyrene, 30 ppm; Poly-
                                                 chlorinated  biphenyls. 12 ppm; 2,4.5-T. 1  x  10 • ppm;  1,2,4,5-Tetrach-
                                                 lorobenzene, 56 ppm; Tetrachloroethylene, 3.4 ppm; Trichtoroethylene.
                                                 1.1 ppm; 2.4,5-Trichtorophenol. 21,000 ppm; 2,4,6-Trichlorophenol, 0.35
                                                 ppm.
                                               (C)  Chlorinated  dtoxins  and  furans:  2,3,7,8-Tetrachlorodibenzo-p
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Environmental Protection  Agency                                           Pt. 261, App. IX

              TABLE 1 —WASTES  EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                Waste description
BBC Brown
  Boveri, Inc.
Boeing
  Commercial
  Airplane Co.
Bommer
  Industries
  Inc.
Capitol
  Products
  Corp.
Caprtol
  Products
  Corporation.
Chamberiian-
  Feathertite,
  Inc.
Cincinnati
  Metropolitan
  Sewer
  District.
day
  Equipment
  Corporation.

Continental
  Can Co.
Dover Corp.,
  Norn's  Drv.
Eli Lilly and
  Company.
Sanford, FL	

Auburn,
  Washington.

Landrum, SC...


Harrisburg, PA.


KenUand, IN....
Hot Springs,
  AR.

Cincinnati, OH
Cedar Falls,
  Iowa.
CHympia, WA.

Tulsa, OK	

Clinton,
  Indiana.
        (5) Data submittals: Within one week of  system start-up,  ADPC&E must notify the
          Section Chief, Variances Section (see address below) when the lull-scale inciner-
          ation system  is on-line and  waste treatment has begun. The data obtained
          through Condition (1)(A) must  be submitted to the  Section  Chief, Variances
          Section, PSPD/OSW (OS-343), U.S.  EPA, 401  M Street SW., Washington, DC
          20460,  within the time period specified. At the Section Chief's request, ADPC&E
          must submit analytical data obtained  through Condition (1)(B) within the time
          period specified by the Section Chief. Failure to submit the required data obtained
          from Condition (1)(A) within the  specified time period or to maintain the required
          records for the time specified in Condition  (t)(B) (or to submit data within the lime
          specified by the Section Chief) will be considered by the Agency, at its discretion,
          sufficient basis to revoke ADPCSE's exclusion to the extent directed by EPA. All
          data must be accompanied by the following certification statement:
        "Under civil and criminal penalty of law for the making  or submission of false or
          fraudulent statements or representations (pursuant to the applicable provisions of
          the  Federal Code, which include, but may not be limited to. 18 U.S.C. 1001  and
          42 U.S.C. 6928),  I certify that the information contained in or accompanying this
          document is true, accurate and complete. As to the (those) identified section(s) of
          this document for which I cannot personally  verify its (their) truth and accuracy,  I
          certify as the company official having supervisory responsibility for the persons
          who, acting under my direct instructions, made the  verification  that this informa-
          tion is true, accurate and  complete. In the event that any of this information is
          determined by EPA in its  sole discretion  to  be false, inaccurate or incomplete,
          and upon conveyance of this fact to the company, I  recognize and agree that this
          exclusion  of wastes will be void as if it never had effect or to the extent directed
          by EPA and that the company will be liable for any actions taken in contravention
          of the company's RCRA and CERCLA obligations premised upon the company's
          reliance on the void exclusion."
Dewatered Waslewater treatment sludges (EPA Hazardous Waste No. F006) generated from
  electroplating operations after October 17. 19S6.
Residually contaminated soils in  an inactive sludge pile containment area on  March 27,
  1990, previously used to store wastewater treatment sludges  generated from electroplating
  operations (EPA Hazardous Waste No. F006).
Wastewater  treatment sludges (EPA Hazardous Waste  No.  F006) generated  from their
  electroplating operations  and contained in evaporation ponds #1 and #2 on August 12,
  1987.
Dewatered  wastewater treatment slugdges (EPA Hazardous Waste No.  FO19) generated
  from the chemical  conversion coating of aluminum after September 12, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
  the chemical conversion coating of aluminum after  November 17, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
  the chemical conversion coating of aluminum after July 16, 1986.

Sluiced bottom ash  (approximately 25,000 cubic  yards) contained in the South Lagoon, on
  September 13, 1985 which contains EPA Hazardous Waste Nos. F001, F002, F003, F004,
  and F005.

Dewatered wastewater treatment  sludges (EPA Hazardous Waste No.  F006)  and spent
  cyanide bath solutions (EPA Hazardous Waste No.  F009) generated from  electroplating
  operations and disposed  of  in  an on-site surface  impoundment.  This  is  a onetime
  exclusion. This exclusion  was published on August  1,  1989.
Dewatered wastewater treatment sludges (DPA Hazardous Waste No. FO19) generated from
  the chemical conversion coating of aluminum after  September 12, 1986.
Dewatered wastewater treatment sludge (EPA Hazardous Waste No. FO06) generated from
  their electroplating operations after April 29, 1986.
Incinerator scrubber  liquids, entering and contained in their onsite surface impoundment, and
  solids  settling from these liquids  originating  from the burning  of spent solvents (EPA
  Hazardous Waste  Nos. F002. F003, and F005) contained in  their onsite surface impound-
  ment and solids retention area on August  18, 1988 and  any  new incinerator scubber
  liquids and settled solids generated in  the surface impoundment  and and disposed of in
  the retention are after August 12, 1988.
                                                      101

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Pf.  261,  App.  IX                                                  40 CFR  Ch. I (7-1-92 Edition)

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                 Waste description
EPA's Mobile
  Incineration
  System.
Denney Farm
  Site;
  McDowell,
  MO.
Envirite
  Corporation.
Canton, Ohio;
  Harvey,
  Illinois;
  Thomaston,
  Connecticut;
  and York,
  PA.
 Falconer
   Glass
   IndusL. Inc.
 Florida
   Production
   Engineering
   Company.
 General Cable
   Co.
                Falconer, NY.
 Daytona
   Beach,
   Florida.

 Muncie,  IN	
Process wastewater, rotary kiln ash, CHEAF media, and other solids (except spent activated
  carbon) (EPA Hazardous Waste Nos. F020, F022, F023, F026, F027, and  F028) generated
  during  the  field demonstration of  EPA's Mobile Incinerator at the  Denney Farm Site in
  McDowell,  Missouri, after July 25, 1985, so long as:  (1) The  incinerator  is functioning
  properly; (2) a grab sample  is taken from each  tank of  wastewater generated and the EP
  leachate values do not exceed  0.03 ppm for mercury. 0.14  ppm for selenium, and 0.68
  ppm for chromium; and  (3)  a  grab  sample is taken from  each  drum of  soil  or ash
  generated and a core sample is collected from each CHEAF roll generated  and the EP
  leachate values of daily composites do not exceed 0.044 ppm in ash or CHEAF media for
  mercury or 0.22 ppm in ash  or CHEAF media for selenium.
Dewatered wastewater sludges  (EPA Hazardous Waste No. F006) generated from electro-
  plating operations; spent cyanide  plating  solutions  (EPA Hazardous Waste  No.  F007)
  generated from electroplating  operations; plating bath residues from the bottom of plating
  baths (EPA Hazardous Waste No.  F008) generated from electroplating operations where
  cyanides are used  in  the  process; spent  stripping and  cleaning bath solutions (EPA
  Hazardous Waste No. F009) generated from electro-plating operations where cyanides are
  used in the process; spent  cyanide solutions from salt bath pot cleaning  (EPA Hazardous
  Waste No. F011) generated from Metal heat treating  operations; quenching wastewater
  treatment sludges (EPA Hazardous Waste No.  F012) generated from metal  heat treating
  where  cyanides are used in the process; wastewater treatment sludges  (EPA Hazardous
  Waste No.  F019)  generated  from the  chemical conversion coating  of aluminum after
  November  14, 1986. To ensure that hazardous constituents are not present in the waste
  at levels of regulatory concern, the facility must implement a contingency testing program
  for the petitioned wastes. This testing program  must meet the following conditions for the
  exclusions to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
  EP Toxicity test for arsenic, barium, cadmium,  chromium, lead,  selenium, silver, mercury,
  and nickel.  If the extract concentrations for chromium, lead, arsenic, and silver exceed
  0.315 ppm; barium  levels exceed  6.3 ppm; cadmium  and selenium  exceed 0.063 ppm;
  mercury  exceeds 0.0126 ppm; or nickel  levels exceed 2.205 ppm, the waste must be re-
  treated or managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265
  and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive  and leachable cyanide. If the
  reactive cyanide levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
  test without acetic acid adjustment) exceed 1.26 ppm, the waste must  be  re-treated or
  managed and disposed as  a hazardous waste under 40 CFR Parts 262 to 265 and the
  permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of specific organic toxicants. If
  the total content of anthracene exceeds 76.8 ppm, 1,2-diphenyl hydrazine exceeds 0.001
  ppm, methylene chloride exceeds  8.18  ppm, methyl ethyl ketone exceeds  326 ppm, n-
  nitrosodiphenylamine exceeds 11.9 ppm, phenol exceeds 1,566 ppm, tetrachloroethylene
  exceeds 0.188 ppm, or trichloroethylene  exceeds 0.592 ppm, the waste must be managed
  and disposed as a hazardous waste under 40 CFR Parts 262 and 265 and the permitting
  standards of 40 CFR Part 270.
(4) A grab sample must  be  collected from  each  batch to form one monthly composite
  sample which must be tested  using GC/MS analysis for the compounds listed in #3 above
   as well  as  the remaining  organics  on the  priority pollutant  list.  (See 47 FH  52309
   November 19, 1982, for a list of the priority pollutants.)
(5) The data from conditions  1-4 must be  kept on file at the facility for inspection purposes
   and must be compiled,  summarized, and submitted to the Administrator by certified mail
   semi-annually. The  Agency will  review  this information  and if  needed will propose to
   modify or withdraw the exclusion.
The organics testing described in conditions 3 and 4 above are not required until six months
   from the  date  of  promulgation.  The  Agency's decision  to conditionally  exclude the
   treatment  residue generated  from the  wastewater treatment systems at these facilities
   applies only to the wastewater and solids treatment systems as they presently exist as
   described in the delisting petition. The exclusion does  not apply to the proposed process
   additions described in the  petition as recovery including crystalization, electrolytic metals
   recovery, evaporative recovery, and ion exchange.
 Wastewater  treatment  sludges from the  filter press and  magnetic  drum separator (EPA
   Hazardous Waste No. F006) generated from electroplating operations after July 16, 1986.

 This is a  one-time exclusion. Wastewater treatment sludges  (EPA Hazardous Waste No.
   F006) generated from electroplating operations and contained in four on-site trenches on
   January 23. 1987.

 Dewatered wastewater  treatment sludges (EPA  Hazardous Waste Nos.  F006 and K062)
   generated from electroplating operations and steel finishing  operations after October  24,
I   1986. This exclusion  does  not  apply to sludges  in any on-site impoundments as of this
I   date.
                                                       102

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Environmental  Protection Agency                                           Pt. 261, App. IX

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                 Waste description
General
  Electric
  Company.
General
  Motors
  Corp.,
  Fisher Body
  Division.
Shreveport
  Louisiana.

Elyria, OH....
Geological
  Reclamation
  Operations
  and
  Systems,
  Inc.
Morrisville, PA.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
  ing  operations  and contained in four  on-site treatment  ponds  on August  12,  1987.

The residue generated from the use of the  Chemfix*  treatment process on sludge (EPA
  Hazardous Waste No. F006)  generated from electroplating operations and contained in
  three on-site surface impoundments  on  November 14,  1986. To assure that  stabilization
  occurs, the following conditions apply to this exclusion:

(1) Mixing ratios shall be monitored continuously to assure consistent treatment.
(2) One grab sample of  the treated waste shall be taken each hour  as it is  pumped to the
  holding area (cell) from each trailer unit.  At the  end of each production day, the  grab
  samples from the individual  trailer units will  be composited and the EP toxicity test will be
  run  on each composite  sample.  If lead or total chromium  concentrations exceed  0.315
  ppm or if nickel  exceeds 2.17 ppm, in the  EP extract, the waste ill be removed  and
  retreated or disposed of as a hazardous waste.
(3) The  treated waste shall be pumped into bermed cells which are constructed to assure
  that the treated waste is identifiable and retrievable (i.e., the material  can be removed  and
  either disposed of as  a  hazardous waste or  retreated if conditions 1 or 2 are not met).
Failure to satisfy any of these conditions would render the exclusion void.  This is a one-time
  exclusion, applicable only to the residue generated from the use of the Chemfix* treatment
  process on  the  sludge currently contained  in the three on-site  surface  impoundments.
Wastewater treatment sludge  filter cake from the treatment of EPA Hazardous Waste  No.
  F039,  generated  at a maximum annual rate of 1,000 cubic yards. This  exclusion  was
  published on August 20, 1991. This exclusion  covers  the  filter cake  resulting from the
  treatment  of hazardous  leachate derived  from only  "old"  GROWS and  non-hazardous
  leachate  derived from only  non-hazardous sources. This exclusion does not address the
  wastes disposed of in the "old" GROWS Landfill or the grit generated during the removal
  of heavy solids from the  landfill leachate. To ensure  that hazardous constituents are not
  present in the  filter  cake at levels  of  regulatory concern,  GROWS must implement a
  testing program for the petitioned waste. This testing program must meet the conditions
  listed below in order for the  exclusion to be  valid:
(1) Testing: Sample collection and analyses,  including quality  control  (QC) procedures, must
  be performed according to SW-846 methodologies.
(A)  Sample Collection: Each  batch of  waste generated over a four-week period must be
  collected in containers with  a maximum capacity of 20-cubic yards.  At the end of the four-
  week  period, each container must be divided into four  quadrants and a single, full-depth
  core sample shall be collected from each quadrant. All of the full-depth core samples then
  must be composited under laboratory conditions to produce one representative composite
  sample for the four-week period.
(B)  Sample Analysis:  Each four-week  composite sample must be  analyzed for all of the
  constituents  listed in Condition (3). The analytical data, including quality control  informa-
  tion, must be compiled and maintained on site for a minimum of three  years.  These data
  must be  furnished upon request by  any employee or representative of EPA or  state of
  Pennsylvania.
(2) Waste Holding: The  dewatered filter cake waste must be  stored  as hazardous  until the
  verification analyses are completed.
If the four-week  composite sample does  not exceed any  of the  delisting levels set in
  Condition (3), the filter cake waste corresponding to this sample  may be managed  and
  disposed of  in  accordance with  all  applicable  solid  waste regulations. If the four-week
  composite sample exceeds  any of the delisting levels set in Condition  (3), the filter  cake
  waste generated during the  time period corresponding to the four-week composite sample
  must be retreated until it meets these levels (analyses must  be repeated) or managed and
  disposed of in accordance with subtitle C of RCRA.
Filter cake waste which  is generated but for which analyses are not  complete or valid  must
  be managed and disposed of in accordance with subtitle C of RCRA, until valid analyses
  demonstrate that the waste  meets the delisting levels.
(3) Delisting Levels: If the  concentrations in  the  four-week composite sample  of the filter
  cake waste  for any of the hazardous constituents  listed below exceed their respective
  maximum allowable  concentrations (ppm) also listed below,  the four-week  batch of failing
  filter cake waste must either be retreated until it meets  these levels or managed  and
  disposed of in accordance with subtitle C of RCRA.
(A) Inorganics (Leachable):
Arsenic—0.79
Barium—15.9
Cadmium—0.16
Chromium—0.79
Cyanide—11.1
Lead—0.79
Mercury—0.032
Selenium—0.16
                                                       103

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Pt. 261, App. IX                                 40 CFR Ch. I (7-1-92 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility




























Address















































































































Waste description
Silver— 0.79
Nickel— 11.1
Leachable metal concentrations must be measured in the filter cake leachate as per 40 CFR
§261.24. Cyanide extractions must be conducted using distilled water in place of the
leaching media per 40 CFR § 261 .24.
(B) Organics:
Acetone— 2.02E+ 03
Acetophenone — 3.53E + 04
Acetonitrile; Methyl cyanide— 2.43E+ 01
Acrolein— 1.38E+02
Acrylonitrile— 6.26E - 04
Aldrin— 5.27E-03
Aniline— 8.72E- 01
Anthracene— 3.01 E + 02
Benzene— 3.47E + 00
Benzo[a]anthracene — 5.78E— 01
Benzo(b)f luoranthene — 6.4 1 E - 0 1
Benzo(k)fluoranthene— 3.04E + 03
BenzoCalpyrene — 1 .51 E —01
gamma-BHC; Lindane— 5.90E-01
Bis(2-chloroethyl) ether— 6.94E- 04
Bis(2-ethylhexyl) phthalate— 1.64E + 02
Bromodichloromethane — 2.94E + 03
Bromoform; Tribromomethane — 3.76E + 03
Butyl benzyl phthalate— 2.49E + 05
Carbon disulfide— 4.98E + 04
Carbon tetrachloride— 5.49E+00
Chlordane— 7.51E + 01
p-Chloroaniline— 1 .85E+02
Chlorobenzene— 5.95E + 02
Chlorobenzilate— 1 .68E + 03
p-Chloro-m-cresol— 5. 1 BE + 02
Chloroform— 1 .94E + 00
2-Chlorophenol— 1 .72E+02
Chrysene— 5.92E + 01
Cresol— 4.91E + 03
2,4-D; 2.4-Dichlorophenoxyacetic acid — 4.17E+02
4,4'-DDD; ODD— 2.33E+00
4,4'-DDE; DDE— 3.86E + 00
4,4'-DDT; DDT— 1.21 E + 01
Dibenzta,h]anthracene— 2.86E-02
Dibromochloromethane; Chlorodibromomethane— 3.05E + 03
1 ,2-Dibromo-3-chloropropane — 4.09E - 02
1,2-Dibromoethane; Ethylene dibromide— 2.37E-03
Di-n-butyl phthalate— 9.84E+ 05
o-Dichlorobenzene; 1 ,2-Dichlorobenzene— 1 .95E + 04
m-Dichlorobenzene; 1 ,3-Dichlorobenzene— 1.87E+05
p-Dichlorobenzene; 1 ,4-Dichlorobenzene— 1.03E+03
3,3'-Dichlorobenzidine— 2.21 E - 01
Dichlorodif luoromethane — 4. 1 5E + 05
1 , 1 -Dichloroethane— 4.45E - 02
1 ,2-Dichloroethane; Ethylene dichloride— 1.45E + 00
1 ,1 -Dichloroethylene— 4.96E + 00
trans-1 ,2-Dichloroethylene— 1 .42E + 02
2,4-Dichlorophenol— 1 .69E+02
1 ,2-Dichloropropane— 2.73E + 00
1 ,3-Dichloropropene (total cis and trans isomers)— 2.32E-02
Dieldrin— 5.04E-03
Diethyl phthalate— 1.00E + 06
Dimethoate— 1 .32E + 00
7,1 2-Dimethylbenz[a]anthracene— 1 .46E - 02
2,4-Dimethylphenol— 4.87E + 01
Dimethyl phthalate— 1.00E + 06
m-Dinitrobenzene— 5. 1 4E + 00
4,6-Otnitro-o-cresol— 2.00E + 02
2,4-Dinitrophenol— 8.96E+01
Dinitrotoluene (total of-2,4- and 2,6- isomers)— 4.54E-03
Dinoseb; DNBP— 5.26E + 02
Di-n-octyl phthalate— 1.34E+05
1 ,4-Dioxane— 7.89E - 02
                                    104

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Environmental  Protection Agency                                         Pt. 261, App.  IX

             TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                 Address
                                              Waste description
Goodyear Tire
  and Rubber
  Co.
Gould, Inc	
Randleman,
  NC.

McConnels-
  ville, OM.
Diphenylamine—4.81 E+04
Disulfoton—3.34E+00
Endosulfan I and Endosulfan II (total)—7.74E+01
Endrin—3.92E + 00
Ethylbenzene— 1.94E + 04
Fluoranthene— 1.16E + 05
Fluorene—4.09E + 01
Heptachlor—1.31E + 01
Heptachlor epoxide—3.26E+00
Hexachlorobenzene—1.02E + 00
Hexachlorobutadiene—2.01 E+01
Hexachlorocyclopentadiene—3.23E+04
Hexachloroethane— 1.15E + 01
Hexachlorophene;— 1.22E+04
Indeno (1,2,3-cd) pyrene—1.16E+02
Isobutyl alcohol; Isobutanol—3.22E+04
Isophorone—2.86E+00
Methacrylonitrile; 2-methyl-2-Propenenitrile—5.77E—01
Methoxychlor—1.03E + 05
Methylbromide; Bromomethane—1.41E+02
Methyl chloride; Chloromethane—3.22E + 04
Methylene chloride; Dichloromethane—9.07E-01
Methyl ethyl ketone; 2-Butanone—1.50E+03
Methyl methacrylate—5.08E + 05
Methyl parathion; Phosphorothioic acid—5.27E+01
4-Methyl-2-pentanone; Methyl isobutyl ketone—6.40E +03
Naphthalene—1 .OOE + 06
Nitrobenzene—2.56E + 01
N-Nitroso-di-n-butylamine—8.15E - 05
N-Nitrosodiethylamine—2.00E - 07
N-Nitrosodimethylamine—2.19E - 05
N-Nitrosodiphenylamine—4.55E + 01
N-Nitrosodipropylamine; Di-n-propylnitrosamine; N-Nitrosodi-n-propylamine—5.02E - 05
Nitrosopyrrolidine; N-Nitrosopyrrolidine; l-nitroso-Pyrrolidine—3.06E - 05
Polychlorinated biphenyls;—4.77E + 01
Pentachlorobenzene—8.91 E + 03
Pentachloronitrobenzene—2.82E+00
Pentachlorophenol—1.14E+04
Phenanthrene—5.46E + 01
Phenol—8.00E+04
Pronamide—2.13E+05
Pyrene—1.OOE+ 06
Pyridine—1.31E+01
Silvex; 2,4,5-TP; 2-(2,4,5-trichlorophenoxy)-Propanoic acid—3.87E+01
Styrene—9.14E + 00
2,4,5-T; 2,4,5-Trichloropnenoxyacetic acid—6.63E+03
1,2,4,5-Tetrachlorobenzene—2.19E+02
1,1,2,2-Tetrachloroethane—2.28E - 02
Tetrachloroethene; Tetrachloroethylene—1.34E+01
2,3,4,6-Tetrachlorophenol—1.17E + 04
Tetraethyl dithiopyrophosphate—2.51 E + 02
Toluene—4.58E +04
Toxaphene—3.09E + 02
1,2,4-Trichlorobenzene—4.75E+04
1,1,1-Trichloroethane—8.70E+02
1,1,2-Trichloroethane—9.03E - 02
Trichloroethylene; Trichloroethene—4.47E + 00
Trichlorof luoromethane—3.31E+05
2,4,5-Trichlorophenol—8.20E+04
2,4,6-Trichlorophenol—1.38E+00
1,2,3-Trichloropropane—5.46E + 02
sym-Trinitrobenzene—2.17E + 00
Vinyl chloride—7.11E-01
Xylene (total)—8.49E+05
Dewatered wastewater treatment sludges (EPA  Hazardous Waste No. F006) generated from
  electroplating operations.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
  ing operations after November 27, 1985.
                                                    105

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Pt. 261, App. IX                               40 CFR Ch. I (7-1-92 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Hoechst
Celanese
Corporation.

Hoechst
Celanese
Corporation.
Hanover Wire
Cloth
Division
Holston Army
Ammunition
Plant.
Imperial
Clevite.
International
Minerals
and
Chemical
Corporation.
Kawneer
Company,
Incorporat-
ed.
Kay-Fries, Inc...


Keymark Corp ..

Keymark Corp ..


Lederie
Laboratories.



Lincoln Plating
Company.
Loxcreen
Company,
Inc.
Marque tie
Electronics
Incorporat-
ed.
Martin
Marietta
Aerospace.
Mason
Chamber-
lain,
Incorporat-
ed.
Merck &
Company,
Incorporat-
ed.
Maytag
Company.

Metropolitan
Sewer
District of
Greater
Cincinnati.
Mtcbelin Tire
Corp.


Address
Bucks,
Alabama.


Leeds, South
Carolina.

Hanover,
Pennsylva-
nia.
Kingsport,
Tennessee.

Salem IN 	

Terre Haute,
Indiana.



Sphngdale,
Arkansas.


Stoney Point,
NY.

Fonda, NY 	

Fonda, New
York.

Pearl River,
NY.



Lincoln, NE 	

Hayti MO


Milwaukee,
Wisconsin.


Ocala, Florida..


Bay St. Louis.
Mississippi.



Elkton,
Virginia.


Newton, IA 	


Cincinnati, OH.




Sandy
Springs,
South
Carolina.
Waste description
Distillation bottoms generated (at a maximum annual rate of 31,500 cubic yards) from the
production of sodium hydrosuifite (EPA Hazardous Waste No. F003). This exclusion was
published on July 17, 1990. This exclusion does not include the waste contained in
Hoechst Celanese's on-site surface impoundment.
Distillation bottoms generated (at a maximum annual rate of 38,500 cubic yards) from the
production of sodium hydrosuifite (EPA Hazardous Waste No. F003). This exclusion was
published on July 17, 1990.
Dewatered filter cake (EPA Hazardous Waste No. F006) generated from electroplating
operations after August 15, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste Nos. F003, F005, and
K044) generated from the manufacturing and processing of explosives and containing
spent non-halogenated solvents after November 14, 1986.
Solid resin cakes containing EPA Hazardous Waste No. F002 generated after August 27,
1985. from solvent recovery operations.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of n-butyl alchohol after August 15, 1986.



Wastewater treatment filter press sludge (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 26 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on November 13, T990.

Biological aeration lagoon sludge and filter press sludge generated after September 21,
1984, which contain EPA Hazardous Waste Nos. F003 and F005 as well as that disposed
of in a holding lagoon as of September 21, 1984.
Wastewater treatment sludge (EPA Hazardous Waste No. F019) generated from chemical
conversion coating of aluminum after November 27, 1985.
Wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from the
chemical conversion coating of aluminum and contained in an on-site impoundment on
August 1 2, 1 987. This is a one-time exclusion.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste Nos. F003 and
F005) generated from the recovery of the following solvents: Xylene, acetone, ethyl
acetate, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, methanol,
toluene, and pyridine after August 2, 1988. Excusion applies to primary and secondary
filter press sludges and compost soils generated from these sludges.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 17, 1986.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after July 16, 1986.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations. This exclusion was published on April 20, 1989.


Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after January 23, 1987.

Wastewater treatment sludge filter cake (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 1.262 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on October 27, 1989.


One-time exclusion for fly ash (EPA Hazardous Waste No. F002) from the incineration of
wastewater treatment sludge generated from pharmaceutical production processes and
stored in an on-site fly ash lagoon. This exclusion was published on May 12, 1989.

Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations and wastewater treatment sludges (EPA Hazardous Waste No. F019)
generated from the chemical conversion coating of aluminum November 17, 1986.
Sluiced bottom ash sludge (approximately 25.000 cubic yards), contained in the North
Lagoon, on September 21, 1984. which contains EPA Hazardous Wastes Nos. F001,
F002. F003, F004. and F005.


Dewatered wastewater treatment sludge (EPA Hazardous Wastes No. F006) generated from
electroplating operations after November 14, 1986.


                                   106

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Environmental Protection Agency                           Pt. 261, App. IX
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Monroe Auto
Equipment.

North
American
Philips
Consumer
Electronics
Corporation.
Pamcor C, Inc ..
Address
Paragould, AR..


Greenville,
Tennessee.




Las Piedras,
! PR.
Philway
Products,
Incorporat-
ed.
Plastene
Supply
Company.
Reynolds
Metals
Company.
Reynolds
Metals
Company.
Siegel-Robert,
Inc.
Square D
Company.
Syntex
Agribusi-
ness.





































Ashland, Ohio ..



Portageville,
Missouri.

Sheffield, AL 	


Sheffield, AL 	


St. Louis, MO...

Oxford, Ohio 	

Springfield,
MO.






































Waste description
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after vacuum filtration after November 27, 1985. This exclusion does not
apply to the sludge contained in the on-site impoundment.
Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations. This exclusion was published on April 20, 1989.




Dewatered Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after October 17, 1986.
Filter press sludge generated (at a maximum annual rate of 96 cubic yards) during the
treatment of electroplating wastewaters using lime (EPA Hazardous Waste No. F006). This
exclusion was published on October 26, 1990.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
electroplating operations after August 15, 1986.

Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after August 15, 1986.

Wastewater treatment filter press sludge (EPA Hazardous Waste No. F019) generated (at a
maximum annual rate of 3,840 cubic yards) from the chemical conversion coating of
aluminum. This exclusion was published on July 17, 1990.
Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.
Dewatered filter press sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after August 15, 1986.
Kiln ash, cyclone ash, separator sludge, and filtered wastewater (except spent activiated
carbori) (EPA Hazardous Waste No. F020 generated during the treatment of wastewater
treatment sludge by the EPA's Mobile Incineration System at the Denney Farm Site in
McDowell, Missouri after June 2, 1988, so long as:
(1) The incinerator is monitored continuously and is in compliance with operating permit
conditions. Should the incinerator fail to comply with the permit conditions relevant to the
mechanical operation of the incinerator, Syntex must test the residues generated during
the run when the failure occurred according to the requirements of Conditions (2) through
(6), regardless of whether or not the demonstration in Condition (7) has been made.
(2) Four grab samples of wastewater must be composited from the volume of filtered
wastewater collected after each eight hour run and, prior to disposal the composite
samples must be analyzed for the EP toxic metals, nickel, and cyanide. If arsenic,
chromium, lead, and silver EP leachate test results exceed 0.61 ppm; barium levels
exceed 12 ppm; cadmium and selenium levels exceed 0.12 ppm; mercury levels exceed
0.02 ppm; nickel levels exceed 6.1 ppm; or cyanide levels exceed 2.4 ppm, the
wastewater must be retreated to achieve these levels or must be disposed in accordance
with all applicable hazardous waste regulations. Analyses must be performed according to
SW-846 methodologies.
(3) One grab sample must be taken from each drum of kiln and cyclone ash generated
during each eight hour run; all grabs collected during a giver eight hour run must then be
composited to form one composite sample. A composite sample of four grab samples of
the separator sludge must be collected at the end of each eight hour run. Prior to the
disposal of the residues from each eight hour run, an EP leachate test must be performed
on these composite samples and the leachate analyzed for the EP toxic metals, nickel,
and cyanide (using a distilled water extraction for the cyanide extraction) to demonstrate
that the following maximum allowable treatment residue concentrations listed below are
not exceeded. Analyses must be performed according to SW-846 methodologies. Any
residues which exceed any of the levels listed below must be retreated to achieve these
levels or must be disposed in accordance with all applicable hazardous waste regulations.
Maximum Allowable Solids Treatment Residue EP Leachate Concentrations (mg/L)
Arsenic — 1 .6
Barium — 32
Cadmium— 0.32
Chromium — 1.6
Lead— 1.6
Mercury— 0.065
Nickel— 16
Selenium— 0.32
Silver— 1 .6
Cyanide— 6.5
                                    107

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Pt. 261, App.  IX                                                  40 CFR  Ch. I (7-1-92  Edition)

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
Waste description
                              (4)—If Syntex stabilizes any of the kiln and cyclone ash or separator sludge, a Portland
                                cement-type stabilization  process must be  used and Syntex must collect a  composite
                                sample of four grab samples from each batch of stabilized waste. An MEP leachate test
                                must be performed on these composite samples and the leachate analyzed for the EP
                                toxic metals, nickel, and cyanide (using a distilled water extraction for the cyanide leachate
                                analysis) to demonstrate that  the maximum allowable treatment residue concentrations
                                listed in Condition (3) are not  exceeded during any run of the MEP extraction. Analyses
                                must be performed according to  SW-846  methodologies. Any residues which exceed any
                                of the levels listed in Condition (3) must be retreated to achieve these levels or must be
                                disposed in accordance with all  applicable hazardous waste regulations. (If the residues
                                are  stabilized,  the analyses required in this  condition supercede the analyses required in
                                Condition (3).)
                              (5) Syntex must generate, prior to disposal of residues, verification data from each eight hour
                                run  from each treatment residue  (i.e., kiln and cyclone ash, separator sludge,  and filtered
                                wastewater) to demonstrate that  the maximum allowable treatment residue concentrations
                                listed below are not exceeded. Samples must be collected as specified in Conditions (2)
                                and (3). Analyses must be performed according to SW-846 methodologies. Any solid or
                                liquid residues which exceed any of the levels listed below must be retreated to achieve
                                these levels or must be disposed in accordance with Subtitle C of RCRA.
                              Maximum Allowable Wastewater Concentrations (ppm):
                                Benz(a)anthracene— 1 x 10'4
                                Benzo(a)pyrene—4 x 10~5
                                Benzo(b)fluoranthene—2 x 10'4
                                Chloroform—0.07
                                Chrysene—0.002
                                Dibenz(a,h)anthracene—9 x 10"6
                                 1,2-Dichloroethane—0.06
                                Dichloromethane—0.06
                                 IndenoO ,2,3-cd)pyrene—0.002
                                Porychlorinated biphenyls—1 x 10~4
                                 1,2,4,5-Tetrachlorobenzene—0.13
                                2.3,4,6-Tetrachloropnenol—12
                                Toluene—120
                                 Tnchloroethylene—0.04
                                2,4,5-Trichlorophenol—49
                                2,4,6-Trichkxophenol—0.02
                               Maximum Allowable Solid Treatment Residue Concentrations (ppm):
                                 Benz(a)anthracene—1.1
                                 Benzo(a)pyrene—0.43
                                 Benzo(b)fluoranthene—1.8
                                 Chloroform—5.4
                                 Chrysene—170
                                 Dibenz(a,h)anthracene—0.083
                                 Dichloromethane—2.4
                                 1,2-Dichloroethane—4.1
                                 IndenoO ,2,3-cd)pyrene—330
                                 Porychlorinated biphenyls—0.31
                                 1,2.4.5-Tetrachlorobenzene—720
                                 Trichkxoethytene—6.6
                                 2.4.6-Trichlorophenol—3.9
                               (6) Syntex must  generate, prior to disposal of residues, verification data from each eight hour
                                 run for each treatment residue (i.e..  kiln  and cyclone ash, separator sludge, and filtered
                                 wastewater) to demonstrate  that the residues do not contain tetra-. penta-, or hexachloro-
                                 dibenzo-p-dioxins or furans at  levels of regulatory concern. Samples must be collected as
                                 specified in Conditions (2) and (3). The TCDD equivalent levels for wastewaters must be
                                 less than 2 ppq and less than 5 opt for the solid treatment residues. Any residues with
                                 detected  dtoxins or furans  in excess of these levels  must be  retreated or must  be
                                 disposed as acutely hazardous.  Method 8290, a high resolution gas chromatography and
                                 high resolution mass spectroscopy (HRGC/HRMS) analytical method,  must be used. For
                                 tetra- and pentachkxonated dtoxin and furan nomotogs, the maximum practical quantitaton
                                 limit must not exceed 15 ppt for solids and  120 ppq for wastewaters. For hexachlorinated
                                 homotogs, the maximum practical quantitation limit must not exceed 37 ppt for solids and
                                 300 ppq for wastewaters.
                               (7MA) The test  data from Conditions (1), (2), (3). (4). (5) and (6) must be kept on file by
                                 Syntex for inspection purposes and  must be compiled, summarized, and submitted to the
                                 Section Chief. Variances Section. PSPD/OSW (WH-563), US EPA, 401 M Street S.W.,
                                 Washington, D.C. 20460 by certified  mail on a monthly basis and  when the treatment of
                                 the lagoon sludge is concluded. All  data submitted will  be placed in the RCRA docket
                                                       108

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Environmental Protection Agency                                          Pt. 261, App. IX

              TABLE 1—WASTES EXCLUDED  FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                 Waste description
SRof
  Tennessee.
Tennessee
  Electroplat-
  ing.
Ripley. TN	

Ripley,
  Tennessee.
Tennessee
  Electroplat-
  ing.

Texas
  Instruments,
  Inc.
Tricil
  Environmen-
  tal Systems,
  Inc.
Ripley, TN.
Dallas, TX.
               Milliard, Ohio..
(B) The testing requirements for Conditions (2), (3), (4), (5), and (6) will continue until Syntex
  provides the Section Chief, Variances Section, with the results  of four consecutive batch
  analyses  for  the petitioned  wastes, none  of which  exceed  the maximum allowable
  treatment  residue  concentrations listed in these  conditions  and  the Section  Chief,
  Variances Section, notifies Syntex that the conditions have been  lifted.
(8)  Syntex  must  provide  a signed copy  of  the following certification  statement  when
  submitting data  in response to the conditions listed above:   "Under  civil and  criminal
  penalty of  law  for the  making or submission of  false or   fraudulent  statements  or
  representations, I certify  that the information  contained in or accompanying this document
  is true, accurate, and complete. As to the (those) identified section(s) of this document for
  which I cannot personally verify its (their) accuracy, I  certify as the company official having
  supervisory responsibility for the persons who, acting under my direct instructions, made
  the verification that this information is true, accurate and complete."
Dewatered wastewater treatment sludges (EPA Hazardous Waste  No. F006) generated from
  the copper, nickel, and chromium electroplating of plastic parts  after November 17, 1986.
Dewatered  wastewater treatment  sludges (EPA Hazardous Waste Nos.  F006)  generated
  from electroplating operations after November 17,  1986.  To ensure  chromium levels do
  not exceed the regulatory standards there must be  continuous batch testing of the filter
  press sludge for chromium for  45 days after the exclusion is granted. Each batch  of
  treatment residue must be representatively sampled  and tested using the EP toxicity test
  for chromium. This data  must be kept on file at the  facility for inspection purposes. If the
  extract levels exceed 0.922 ppm of chromium the waste must be managed and disposed
  of as hazardous. If these conditions are not met, the exclusion does not  apply. This
  exclusion does  not apply to  sludges  in any on-site impoundments  as  of  this date.
Wastewater treatment sludge (EPA Hazardous  Waste No. F006) generated from electroplat-
  ing operations and  contained in an on-site surface impoundment (maximum  volume  of
  6,300 cubic yards). This  is a one-time exclusion. This exclusion was published on April 8,
  1991.
Wastewater treatment sludges (EPA Hazardous Waste  Nos. F006  and F019) generated after
  August 27, 1985, from  their electroplating  operations  that have been batch  tested for
  cadmium using the EP toxicity procedure and have been found to contain less than 0.30
  ppm  cadmium in the EP extract. Wastewater treatment sludges that exceed this level will
  be considered a  hazardous waste.
Dewatered wastewater treatment sludges (EPA Hazardous Waste  No. F006) generated from
  electroplating operations after November 17, 1986. To ensure that hazardous constituents
  are not present in the  waste at levels of regulatory concern, the facility must implement a
  contingency testing program for the petitioned wastes. This testing program must meet the
  following conditions for the exclusion to be valid:
(1) Each batch  of treatment residue must be representatively sampled and tested using the
  total  oil and grease test  and the EP  Toxicity test (or the Oily Waste EP test, if the oil and
  grease content  of the  waste  exceeds  one  percent)  for  arsenic,  barium,  cadmium,
  chromium, lead,  selenium, silver, mercury,  and  nickel. If the  extract  concentrations for
  chromium, lead,  arsenic, and  silver  exceed 0.315 ppm; barium levels  exceed 6.3 ppm;
  cadmium and selenium  levels exceed  0.063 ppm;  mercury levels exceed 0.013 ppm;  or
  nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and disposed as a
  hazardous waste under 40 CFR  Parts 262 to 265 and the permitting standards of 40 CFR
  Part  270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
  reactive cyanide  levels exceed 250 ppm or leachable cyanide levels (using the EP Toxicity
  test  without acetic acid  adjustment) exceed 1.26 ppm, the waste must be re-treated or
  managed and disposed  as a hazardous waste under 40  CFR  Parts 262 to 265 and the
  permitting standards of 40 CFR Part 270.
(3)  Each batch of  the waste must be tested  for the total content  of the following organic
  toxicants.  If the total  content  of any of the  constituents exceeds the  maximum levels
  shown, the waste must  be managed and disposed as a hazardous waste under 40 CFR
  Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
                   Compound and Maximum Acceptable Levels  (ppm)
Acrolein—56.8
Anthracene—76.8
Benzene—0.106
p-Chloro-m-cresol— 133
1,1 -Dichloroethane—0.01
Fluorene—10.4
Methylene chloride—8.2
Methyl ethyl ketone—326
n-Nitrosodiphenylamine—11.9
Phenanthrene—14
Tetrachloroethylene—0.188
Trichloroethylene—0.59
Chloroform—0.013
                                                       109

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Pt.  261, App.  IX                                                  40 CFR  Ch. I (7-1-92  Edition)

              TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
Address
Waste description
Tricil
  Environmen-
  tal Systems,
  Inc.
Nashville,
  Tennessee
1,2-Dichloroethane—0.0083
1,2-trans-Dichloroethylene—231
2,4-Dimethylphenol—12.5
Vinyl chloride—0.18
(4)  A grab sample must be  collected  from  each batch to form one  monthly composite
  sample, which must be tested using GC/MS analysis for the compounds shown above as
  well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
  19, 1982, for a list of the priority pollutants.)
(5)  The test  data from conditions 1-4  must be kept on file at the facility for inspection
  purposes and  must be  compiled, summarized,  and  submitted to the  Administrator by
  certified mail on a  semiannual basis. The Agency  will  review  this  information  and if
  needed, will propose to modify or withdraw the exclusion. The  organics testing described
  in conditions 3 and 4 above is not required until May  18,  1987. The Agency's decision to
  conditionally exclude  the treatment  residue  generated from  the wastewater treatment
  system at this facility applies only to the wastewater treatment residue as described in this
  petition.
Dewatered wastewater treatment sludges (EPA Hazardous Waste  No. F019) generated from
  chemical conversion  coating  of aluminum  after  November 17, 1986. To  ensure  that
  hazardous constituents are not present in the waste at levels  of regulatory concern,  the
  facility  must implement a  contingency testing program for the petitioned wastes. This
  testing  program  must  meet  the  following conditions for the  exclusion to be valid:
(1)  Each batch of treatment residue must be representatively sampled and tested using  the
  total  oil and grease test and the EP Toxicity test  (or the Oily Waste EP test, if the oil and
  grease  content of the  waste  exceeds  one percent) for  arsenic,  barium,  cadmium,
  chromium,  lead, selenium, silver, mercury, and nickel. If  the  extract concentrations  for
  chromium,  lead, arsenic,  and silver  exceed  1.1  ppm;  barium  levels  exceed 22.2 ppm;
  cadmium and selenium levels exceed 0.22 ppm; mercury levels exceed  0.044 ppm; or
  nickel levels exceed 7.8 ppm, the waste will be re-treated  or managed and disposed as a
  hazardous waste under 40 CFR Parts 262 to 265 and the  permitting standards of 40 CFR
  Part 270.
(2)  Each batch of treatment residue must be tested for reactive and teachable cyanide. If  the
  reactive cyanide levels exceed 250 ppm or teachable cyanide levels (using the EP Toxicity
  test without acetic acid  adjustment) exceed  4.4 ppm,  the waste must be re-treated or
  managed and disposed as a hazardous waste under 40 CFR  Parts 262 to 265 and  the
  permitting standards of 40 CFR Part 270.
(3)  Each batch of the waste must be tested for the total content of the following organic
  toxicants.  If the total content of any  of the constituents exceeds the maximum levels
  shown, the waste must be managed and disposed as a hazardous waste  under 40 CFR
  Parts 262 to 265 and the permitting standards of 40 CFR Part 270.
                   Compound and Maximum Acceptable Levels (ppm)
Acrotein—363
Anthracene—492
Benzene—0.68
p-Chtoro-m-cresol—848
1,1 -Dichloroethane—0.068
Fluorene—66.7
Methylene chloride—52.4
n-Nitrosodiphenylamine—76.1
Phenantnrene—89
Tetrachtoroethytene—1.2
Trichloroethytene—3.78
Chkxolorm—0.081
1,2-Dichloroethane—0.053
2,4-Dirnethylphenol—79.7
Vinyl chloride—1.16
1.2-Diphenyt hydrazine—0.005
(4)  A grab sample must be  collected  from each batch to form one  monthly composite
  sample, which must be tested using GC/MS analysis for the compounds shown above as
  well  as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
  19, 1982, for a list of the priority pollutants.)
(5)  The test  data from conditions 1-4 must be kept on file at the  facility for inspection
  purposes and  must be  compiled, summarized,  and submitted to  the Administrator by
  certified mail on a semiannual basis. The Agency  will  review  this information  and if
  needed, will propose to modify or withdraw the exclusion. The  organics testing described
  in conditions 3 and 4 above is not required until May 18,  1987. The Agency's decision to
  conditionally exclude the  treatment residue generated from   the wastewater treatment
  system at this facility applies only to the wastewater treatment residue  as described in  this
  petition.
                                                      110

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Environmental Protection  Agency                                           Pt. 261, App. IX

              TABLE 1—WASTES  EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                Waste description
Tricil
  Environmen-
  tal Systems,
  Inc.
Muskegon,
  Michigan.
 United
   Technol-
   ogies
   Automotive,
   Inc.
 Universal Oil
   Products.

 U.S. EPA
   Combustion
   Research
   Facility.
 U.S.
   Nameplate
   Company,
   Inc.
Jeffersonville,
   IN.
 Decatur,
   Alabama.

 Jefferson,
   Arkansas.
 Mount Vernon,
   Iowa.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from
  electroplating operations after November 17, 1986. To ensure that hazardous constituents
  are not present in the waste at levels of regulatory concern, the facility must implement a
  contingency testing program for the petitioned wastes. This testing program must meet the
  following conditions for the exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
  total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if  the oil and
  grease content  of  the  waste  exceeds one  percent)  for  arsenic,  barium,  cadmium,
  chromium, lead,  selenium, silver, mercury, and nickel.  If the extract  concentrations  for
  chromium, lead,  arsenic,  and  silver exceed 0.315 ppm; barium levels  exceed 6.3  ppm;
  cadmium  and selenium levels exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or
  nickel levels exceed 2.2 ppm, the waste will be re-treated or managed and  disposed as a
  hazardous waste  under 40 CFR Parts 262 to 265 and the permitting standards of 40 CFR
  Part 270.
(2) Each batch of treatment  residue must be tested for reactive and teachable  cyanide.  If the
  reactive cyanide levels exceed 250 ppm or teachable cyanide levels (using the  EP Toxicity
  test without acetic acid adjustment) exceed 1.26 ppm, the waste  must be re-treated or
  managed and  disposed as a hazardous waste under 40 CFR parts 262 to 265 and the
  permitting standards of 40 CFR part 270.
(3) Each batch of  the waste must be tested for the total content of the following organic
  toxicants.  If  the  total  content of any of the  constituents exceeds the maximum  levels
  shown, the waste must be managed and disposed as  a hazardous waste under 40 CFR
  parts 262 to 265  and the permitting standards of 40 CFR part 270.
                   Compound and Maximum Acceptable Levels (ppm)
Acrolein—56.8
Anthracene—76.8
Benzene—0.106
p-Chloro-m-cresol—133
1,1-Dichloroethane—0.01
Fluorene—10.4
Methylene chloride—8.2
Methyl ethyl ketone—326
n-Nitrosodiphenylamine—11.9
Phenanthrene—14
Tetrachloroethylene—0.188
Trichloroethylene—0.59
Chloroform—0.013
1,2-Dichloroethane—0.0083
1,2-trans-Dichloroethylene—231
2,4-Dimethylphenol—12.5
Vinyl chloride—0.18
(4)  A grab sample must be collected from each batch to form one monthly composite
  sample, which  must be tested using GC/MS analysis for the compounds shown above as
  well as the remaining organics on the priority pollutant list. (See 47 FR 52309, November
  19, 1982, for a list of the priority pollutants.)
(5)  The test  data  from  conditions 1-4  must be kept on file at the facility for inspection
  purposes  and  must be compiled,  summarized,  and submitted  to the Administrator by
  certified mail  on a semiannual basis.  The  Agency will review  this  information  and if
  needed, will propose to modify or withdraw the exclusion. The organics testing described
  in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
  conditionally exclude  the treatment residue generated from the wastewater treatment
  system at this  facility applies only to the wastewater treatment residue as described in this
  petition.
Dewatered  wastewater treatment sludge (EPA Hazardous Waste No. FO19) generated from
  the chemical conversion of aluminum after April 29, 1986.
 Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
   ing operations and contained in two on-site lagoons  on August  15, 1986. This is a one-
   time exclusion.
 One-time exclusion for scrubber water (EPA Hazardous  Waste No.  F020) generated in  1985
   from  the  incineration of Vertac still bottoms. This exclusion was published  on June 28,
   1989.

 Retreated  wastewater treatment  sludges (EPA  Hazardous Waste  No. F006)  previously
   generated from electroplating operations and currently  contained in  an  on-site surface
   impoundment after  September 28, 1988. This  is a one-time exclusion for  the  reteated
   wastes only. This exclution  does  not relieve the waste unit from regulatory compliance
   under Subtitle C.
                                                       Ill

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Pt. 261, App. IX                                40 CFR Ch. I (7-1-92 Edition)
         TABLE 1—WASTES EXCLUDED FROM NON-SPECIFIC SOURCES—Continued
Facility
VAWof
America
Incorporat-
ed.
Vermont
American,
Corp.
Waterloo
Industries.

Watervliet
Arsenal.
William L.
Bonnell Co.

William L.
Bonnell Co.

Windsor
Plastics, Inc.
Address
St. Augustine,
Florida.


Newark, OH 	


Pocahontas,
AR.

Watervliet, NY..

Carthage, TN....


Newnan,
Georgia.

Evansville, IN ...

Waste description
Wastewater treatment sludge filter cake (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum. This exclusion was published on February 1 ,
1989.

Wastewater treatment sludge (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after November 27, 1985.

Wastewater treatment sludges (EPA Hazardous Waste No. F006) generated from electroplat-
ing operations after dewatering and held on-site on July 17, 1986 and any such sludge
generated (after dewatering) after July 17, 1986.
Wastewater treatment sludges (EPA Hazardous Waste No F006) generated from electroplat-
ing operations after January 10, 1986.
Dewatered Wastewater treatment sludges (Vacuum filter sludge) (EPA Hazardous Waste No.
F019) currently generated from the chemical conversion coating of aluminum after October
17, 1986. This exclusion does not apply to sludges in the on-site surface impoundments.
Dewatered wastewater treatment sludges (EPA Hazardous Waste No. F019) generated from
the chemical conversion coating of aluminum after November 14, 1986. This exclusion
does not include sludges contained in Bonnell's on-site surface impoundments.
Spent non-halogenated solvents and still bottoms (EPA Hazardous Waste No. F003)
generated from the recovery of acetone after November 17, 1986.
                TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES
Facility
American
Cyanamid.
Amoco Oil Co...
Akzo
Chemicals
Inc.
(formerly
Stauffer
Chemical
Company).
Bethlehem
Steel Corp.
Address
Hannibal,
Missouri.
Wood River,
IL
Axis, AL 	
Steelton, PA 	
Waste description
Wastewater and sludge (EPA Hazardous Waste No. K038) generated from the washing and
stripping of phorate production and contained in on-site lagoons on May 8, 1987, and such
wastewater and sludge generated after May 8, 1987.
150 million gallons of DAF from petroleum refining contained in in four surge ponds after
treatment with the Chemifix' stabilization process. This waste contains EPA Hazardous
Waste No. K048. This exclusion applies to the 150 million gallons of waste after chemical
stabilization as long as the mixing ratios of the reagent with the waste are monitored
continuously and do not vary outside of the limits presented in the demonstration samples;
one grab sample is taken each hour from each treatment unit, composited, and EP toxicity
tests performed on each sample. If the levels of lead or total chromium exceed 0.5 ppm in
the EP extract, then the waste that was processed during the compositing period is
considered hazardous; the treatment residue shall be pumped into termed cells to ensure
that the waste is identifiable in the event that removal is necessary.
Brine purification muds generated from their chlor-alkali manufacturing operations (EPA
Hazardous Waste No. K071) and disposed of in brine mud pond HWTF: 5 EP-201.
Uncured and cured chemically stabilized electric arc furnace dust/sludge (CSEAFD) treat-
ment residue (K061) generated from the primary production of steel after May 22, 1989.
This exclusion is conditioned upon the data obtained from Bethlehem's full-scale CSEAFD
treatment facility because Bethlehem's original data were obtained from a laboratory-scale
CSEAFD treatment process. To ensure that hazardous constituents are not present in the
waste at levels of regulatory concern once the full-scale treatment facility is in operation,
Bethlehem must implement a testing program for the petitioned waste. This testing
program must meet the following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation of the full-scale treatment system,
Bethlehem must collect representative grab samples of each treated batch of the CSEAFD
and composite the grab samples daily. The daily composites, prior to disposal, must be
analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
(using distilled water in the cyanide extractions), and the total constituent concentrations
of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
846 methodologies. Bethlehem must report the analytical test data obtained during this
initial period no later than 90 days after the treatment of the first full-scale batch.
                                    112

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Environmental  Protection Agency                                           Pt. 261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
Bethlehem
  Steel Corp.
Johnstown,
  PA.
                                                 Waste description
(B)  Subsequent  Testing:  Bethlehem must collect representative grab samples  from  every
  treated batch  of  CSEAFD  generated  daily and composite  all of the grab samples  to
  produce a weekly composite sample. Bethlehem then must analyze each weekly compos-
  ite sample for the  EP leachate concentrations  of all the EP toxic metals and  nickel.
  Analyses must be performed according to SW-646 methodologies. The  analytical data,
  including  all quality  control  information, must be compiled and maintained  on site for a
  minimum of three years. These data must be furnised upon request and made available
  for inspection  by  any employee or representative  of EPA or the State of  Pennsylvania.
(2) Oelisting Levels: If the EP extract concentrations resulting  from  the testing in condition
  (1)(A) or (1){B) for chromium, lead,  arsenic,  or  silver  exceed 0.315 mg/L,  for  barium
  exceeds  6.3 mg/l;  lor cadmium or selenium  exceed 0.063  mg/l; lor mercury exceeds
  0.0126 mg/l; for nickel exceeds 3.15  mg/l: or for  cyanide exceeds 4.42 mg/L, or total
  reactive  cyanide  or total  reactive sulfide levels  exceed 250 mg/kg and 500 mg/kg,
  respectively, the waste must either be re-treated or managed and disposed in accordance
  with subtitle C  of RCHA.
(3) Data submittals: Within one week of system start-up, Bethlehem must notify the Section
  Chief, Variances  Section (see address below)  when their full-scale stabilization system is
  on-line and waste  treatment  has begun. All data obtained through  the  initial  testing
  condition (1)(A), must be submitted to the Section Chief, Variances Section, PSPD/OSW,
  (OS-343), U.S. EPA, 401 M Street, S.W., Washington,  DC 20460 within  the time period
  specified in condition  (1){A).  At  the  Section Chief's request,  Bethlehem must  submit
  analytical data obtained through condition (1)(B) to the above address,  within the time
  period  specified by  the Section Chief. Failure to submit the required data obtained from
  either condition (1)(A) or (1)(B) within the specified time periods will  be considered by the
  Agency sufficient basis to revoke Bethlehem's exclusion to the extent directed  by EPA.  All
  data must be accompanied  by the following certification statement:
"Under civil and criminal penalty of  law for the making or submission of false or fraudulent
  statements or  representations  (pursuant to the applicable provisions of the  Federal Code
  which include, but may not be limited to,  18  U.S.C. 6926), I certify that the information
  contained in or accompanying this document is true, accurate and complete.
"As to the  (those)  identified section(s) of this document for which I  cannot  personally verify
  its  (their)  truth  and  accuracy,  I  certify  as the  company  official  having  supervisory
  responsibility for  the  persons who,  acting  under  my  direct  instructions,   made  the
  verification that this information is true, accurate and complete.
"In the event that any of this information is determined by EPA in its sole  discretion to  be
  lalse, inaccurate  or incomplete, and  upon conveyance of  this fact  to  the  company, I
  recognize and agree that this exclusion of wastes  will be void as if  it never had effect or
  to the extent directed by EPA and that the company will be liable for any actions taken in
  contravention  of  the  company's  RCRA  and CERCLA obligations premised  upon the
  company's reliance  on  the void exclusion."
Uncured  and cured chemically stabilized electric arc furnace  dust/sludge  (CSEAFD) treat-
  ment residue (K061) generated from the primary production of steel after May 22, 1989.
  This exclusion is conditioned upon the data obtained from Bethlehem's full-scale CSEAFD
  treatment facility because  Bethlehem's original data were obtained from a labortory-scale
  CSEAFD treatment  process. To ensure that hazardous constituents are not  present in the
  waste at levels of regulatory concern once the full-scale treatment facility is in operation,
  Bethlehem must  implement a testing program  for  the petitioned waste. This testing
  program  must  meet the following conditions for the exclusion to be valid:
(1) Testing:
(A) Initial Testing: During the  first four weeks of operation of the full-scale treatment system,
  Bethlehem must  collect representative grab samples of each treated batch of the CSEAFD
  and composite the grab samples daily. The daily  composites, prior to disposal, must  be
  analyzed for the EP leachate concentrations of all  the EP toxic metals, nickel and cyanide
  (using  distilled water in the cyanide extractions), and the total constituent concentrations
  of reactive sulfide and reactive cyanide. Analyses must be  performed according to SW-
  846  methodologies. Bethlehem must report the analyticai test data obtained  during this
  initial period no  later than 90  days after the  treatment  of the  first  full-scale  batch.
(B) Subsequent Testing: Bethlehem must collect representative grab samples  from every
  treated batch of CSEAFD  generated daily and composite  all  of  the grab  samples to
  produce  a weekly composite sample. Bethlehem then must analyze each weekly compos-
  ite  sample  for the EP leachate  concentrations  of all the  EP  toxic metals  and  nickel.
  Analyses must be  performed  according to SW-846 methodologies. The analytical data,
  including all quality control information, must be compiled and  maintained on site for a
   minimum of three years. These data must be furnished upon request and made available
   for inspection by any  employeee  or representative of EPA or the State  of Pennsylvania.
                                                       113

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Pt. 261, App. IX                                                   40 CFR Ch.  I  (7-1-92  Edition)

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                   Address
                                                  Waste description
BF Goodrich
  Interme-
  diates
  Company,
  Inc.
Calvert City,
  Kentucky.
(2) Delisting Levels: If the EP extract concentrations resulting from the testing in  condition
  (1)(A) or (1)(B) for chromium,  lead, arsenic,  or  silver exceed 0.315 mg/L, for  barium
  exceeds  6.3  mg/l; for cadmium or selenium  exceed 0.063  mg/l; for mercury exceeds
  0.0126 mg/l; for nickel exceeds 3.15 mg/l; or for cyanide exceeds  4.42  mg/L, or total
  reactive  cyanide or  total  reactive  sulfide  levels exceed 250  mg/kg and  500 mg/kg,
  respectively, the waste must either be re-treated or managed and disposed in accordance
  with subtitle C of RCRA.
(3) Data submittals: Within one week of system start-up, Bethlehem must notify the Section
  Chief, Variances Section (see address below)  when their full-scale  stabilization system is
  on-line and waste treatment has begun.  All  data  obtained  through  the initial  testing
  condition (1)(A), must be submitted to the Section Chief,  Variances Section,  PSPD/OSW,
  (OS-343), U.S. EPA, 401  M Street, SW., Washington, DC 20406 within the time period
  specified in condition (1)(A). At the Section  Chief's  request. Bethlehem must  submit
  analytical data obtained through condition  (1)(B)  to  the  above address,  within  the time
  period specified by the Section Chief. Failure  to submit the required data obtained from
  either condition (1)(A) or (1)(B) within the specified time periods will be considered by the
  Agency sufficient basis to revoke Bethlehem's exclusion to the extent  directed by EPA. All
  data must be accompanied by the following certification statement:
"Under  civil and criminal penalty of law for the making or submission of false or fraudulent
  statements or representations (pursuant to  the applicable provisions of the Federal Code
  which include, but may  not be limited to,  18  U.S.C. 6928), I certify  that the information
  contained in or accompanying this document is true, accurate and complete.
"As to the  (those) identified section(s) of this document for which I cannot personally verify
  its  (their)  truth  and accuracy. I  certify  as  the  company  official  having supevisory
  responsibility  for  the  persons  who, acting  under  my   direct  instructions, made  the
  verification that this information is true, accurate and complete.
"In the  event that any of this information  is determined by  EPA in its sole discretion to be
  false, inaccurate or  incomplete, and  upon conveyance  of this fact to the company, I
  recognize and agree that this exclusion  of wastes will be  void as if it never had effect or
  to the extent directed by EPA and that the  company will be liable for any actions taken in
  contravention  of  the company's RCRA and  CERCLA  obligations premised  upon the
  company's reliance on the void exclusion."
Brine purification muds and  saturator insolubles (EPA Hazardous Waste  No. K071) after
  August 18. 1989. This exclusion is conditional upon the collection and submission of data
  obtained from BFG's full-scale treatment system because BFG's original data was  based
  on  data  presented by another petitioner using an identical treatment process. To  ensure
  that hazardous constituents are not present in the waste at levels of regulatory concern
  once  the full-scale  treatment facility is in operation, BFG  must implement  a  testing
  program.  All  sampling  and analyses  (including quality  control procedures)  must be
  performed according  to SW-846 procedures. This testing program must meet  the following
  conditions for the exclusion to be valid:
(1)  Initial Testing:  During  the first four weeks  of full-scale operation,  BFG must do the
  following:
(A) Collect representative grab samples  from every batch of the treated mercury  brine
  purification muds and treated saturator insolubles on a daily basis and composite the grab
  samples  to produce  two separate  daily composite samples (one of the treated mercury
  brine  purification muds and one of the treated saturator insolubles). Prior to disposal of the
  treated  batches,  two  daily  composite  samples  must  be  analyzed  for EP  leachate
  concentration  of mercury. BFG must  report the analytical test  data, including all quality
  control data, within 90 days after the treatment of the first full-scale batch.
(B) Collect representative grab  samples  from every batch of the treated mercury  brine
  purification muds and treated saturator insolubles on a daily basis and composite the grab
  samples  to produce two separate weekly composite samples  (one of the  treated mercury
  brine  muds and one of  the treated saturator insolubles). Prior to disposal of the  treated
  batches,  two weekly  composite  samples must be analyzed for the EP leachate concentra-
  tions  of all the EP toxic metals (except mercury), nickel, and cyanide (using distilled water
  in the cyanide extractions), and the total constituent concentrations of reactive sulfide and
  reactive  cyanide.  BFG must report the analytical test data,  including all quality  control
  data,  obtained during this initial period no later than 90 days after the treatment of the first
  full-scale batch.
(2) Subsequent Testing: After the first four weeks of full-scale operation, BFG  must do the
  following:
(A) Continue to sample and test as described in condition (1)(A). BFG must  compile and
  store on-site for a  minimum of three years all analytical data and  quality  control data.
  These data must be furnished upon  request  and made available for inspection  by any
  employee or representative of EPA or the State of Kentucky.
                                                        114

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Environmental  Protection Agency                                            Pt. 261, App.  IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                 Waste description
CF&I Steel
  Corporation.
Pueblo,
  Colorado.
(B)  Continue to sample and test as described in  condition  (1)(B). BFG must compile and
  store  on-site  for a minimum of three years  all  analytical data and quality control data.
  These data must be furnished upon request and made available for inspection by any
  employee or representative of EPA or the State of Kentucky. These testing requirements
  shall  be terminated  by EPA when the results  of  four  consecutive weekly  composite
  samples of both the treated mercury brine muds  and  treated saturator insolubles, obtained
  from either the initial  testing or subsequent testing, show the maximum allowable levels in
  condition (3) are not exceeded and the Section Chief, Variances Section, notifies BFG that
  the requirements of this condition have been lifted.
(3) If, under condition (1) or (2), the EP leachate concentrations for chromium, lead,  arsenic,
  or silver exceed 0.316 mg/l; for  barium exceeds 6.31 mg/l; for cadmium  or selenium
  exceed 0.063 mg/l; for mercury exceeds 0.0126 mg/l,  for nickel exceeds 3.16 mg/l; for
  cyanide exceeds 4.42 mg/l; or for total reactive cyanide or total reactive sulfide  levels
  exceed 250 mg/kg and 500 mg/kg, respectively,  the waste must either be retreated  until it
  meets these levels or managed and disposed of in accordance with  subtitle C of RCRA.
(4)  Within one  week  of system start-up.  BFG must  notify the Section  Chief,  Variances
  Section (see  address below) when the full-scale system  is  on-line and waste treatment
  has begun. All data obtained through condition (1) must be submitted to the Section  Chief,
  Variances  Section, PSPD/OSW (OS-343), U.S. EPA, 401 M Street, SW., Washington, DC
  20460 within the time period specified in condition (1). At the Section Chief's request, BFG
  must submit any  other analytical data obtained through condition (2) to the above address,
  within the  time period specified by the Section Chief. Failure to  submit the required data
  will be considered by the Agency sufficient basis to revoke BFG's exclusion to  the  extent
  directed by EPA.  All  data must be accompanied by the following certification  statement:
"Under  civil  and criminal penalty of law  for the making or submission of false or fraudulent
  statements or representations (pursuant to the applicable  provisions of the Federal Code
  which include, but may not be limited to, 18 U.S.C.  §6928),  I certify that the information
  contained  in or accompanying this document is true, accurate and complete.
As to the (those) identified section(s) of this document for which I cannot personally verify its
  (their) truth and accuracy, I certify as the company official  having supervisory responsibility
  for the persons who, acting under my direct instructions, made the  verification that this
  information is true, accurate and complete.
In the event that any of this information is determined by EPA in its sole  discretion  to  be
  false, inaccurate  or  incomplete,  and  upon conveyance of  this fact  to  the company, I
  recognize  and agree  that this exclusion of  wastes will be  void as if it never had effect or
  to the extent  directed by  EPA and that the company will be liable for  any actions  taken in
  contravention  of  the company's  RCRA  and CERCLA obligations  premised  upon the
  company's reliance on the void exclusion."
Fully-cured  chemically  stabilized  electric  arc  furnace  dust/sludge (CSEAFD)  treatment
  residue (EPA Hazardous Waste No.  K061)  generated from the primary production of steel
  after May  9, 1989. This exclusion  is conditioned upon the data obtained from CF&l's full-
  scale  CSEAFD  treatment  facility because CF&l's  original   data  was obtained  from  a
  laboratory-scale CSEAFD treatment process.  To ensure that  hazardous  constituents are
  not present  in the waste at levels of regulatory concern once the  full-scale treatment
  facility is in operation. CF&I must implement  a  testing  program  for the  petitioned waste.
  This testing program must meet  the  following  conditions for the exclusion to be vaild:
(1) Testing:
(A) Initial Testing: During the first four weeks of operation  of the full-scale treatment system,
  CF&I  must collect representative grab samples of each  treated batch of the CSEAFD and
  composite the  grab  samples  daily.  The  daily  composites,  prior to disposal, must  be
  analyzed for the  EP leachate concentrations of all the EP toxic metals, nickel, and cyanide
  (using distilled water in the cyanide extractions), and the  total constituent concentrations
  of reactive sulfide and reactive cyanide. Analyses must be performed according to SW-
  846 methodologies.  CF&I must report the analytical test  data obtained during this initial
  period no  later than 90 days after the treatment of the first full-scale batch.
(B) Subsequent Testing: CF&I must collect representative grab samples from every treated
  batch  of CSEAFD generated daily and composite all of the grab samples to  produce a
  weekly composite sample. CF&I then must analyze each weekly composite sample for the
  EP leachate  concentrations of all of the EP toxic metals and nickel. Analyses  must  be
  performed according to SW-846 methodologies. The analytical  data,  including all  quality
  control information,  must be compiled and  maintained on site for a  minimum  of three
  years. These data must be furnished  upon request and made available for inspection by
  any employee or representative of EPA or the State of Colorado.
(2) Delisting levels: If the EP extract concentrations determined in conditions (1)(A)  or (1)(B)
  for chromium, lead, arsenic, or silver exceed 0.315  mg/1; for barium exceeds 6.3  mg/1;
  for cadmium or selenium exceed 0.063 mg/1;  for mercury  exceeds 0.0126 mg/1;  for
  nickel exceeds 3.15  mg/1; or for cyanide exceeds 4.42 mg/1, or total reactive cyanide or
  total  reactive sulfide levels exceed 250 mg/kg and 500  mg/kg, respectively, the  waste
   must either be  re-treated or managed  and disposed  in accordance with Subtitle C of
   RCRA.
                                                       115

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Pt. 261, App. IX                                                  40 CFR  Ch. I (7-1-92 Edition)

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
   Address
                                                 Waste description
Envtnte
  Corporation.
Canton. Ohio;
  Harvey,
  Illinois;
  Thomaston,
  Connecticut;
  and York
  PA.
(3) Data submittals: Within one week of system start-up. CF&l must notify the Section Chief,
  Variances Section (see address below) when their full-scale stabilization system is on-Nne
  and  waste treatment  has begun. All data obtained through the initial testing condition
  (1)(A), must be submitted to the Section Chief, Variances Section, PSPD/OSW, (OS-343),
  U.S. EPA, 401 M Street. SW., Washington. DC 20460 within the time period specified in
  condition (1}(A|. At the Section Chiefs request, CF&l must submit analytical data obtained
  through condition (1)(B) to the above address, within the time period specified by the
  Section Chief. Failure  to submit the required data obtained from either condition (1)(A) or
  (1)(B) within the specified time periods will be considered by the Agency sufficient basis to
  revoke CF&l's exclusion to the extent directed by EPA. All data must be accompanied by
  the following certification  statement "Under civil  and  criminal penalty  of  law for the
  making of submission of false or fraudulent statements or representations (pursuant to the
  applicable provisions of the Federal Code which include, but  may not be limited  to,  18
  U.S.C. 6928), I certify  that the information contained in or accompanying this document is
  true, accurate and complete.  As to the {those} identified section(s)  of this document  tor
  which I  cannot personalty verify its (their) truth  and accuracy, I certify as the company
  official having supervisory  responsibility for  the persons who,  acting under my  direct
  instructions, made the verification that this information is true,  accurate and complete. In
  the event that any of this information is determined by EPA in  its sole discretion to  be
  false, inaccurate or incomplete, and upon conveyance  of this  fact to the  company,  I
  recognize and agree that this  exclusion of wastes will be void as if it never had effect or
  to the extent  directed by EPA and that the company will  be liable for any actions taken in
  contravention of the  company's  RCRA  and CERCLA  obligations premised upon trie
  company's reliance on the void exclusion."
Spent  pickle liquor  (EPA  Hazardous Waste  No.  K062)  generated  from  steel finishing
  operations of facilities within  the iron  and  steel  industry  (SIC  Codes  331  and  332);
  wastewater treatment  sludge  (EPA  Hazardous  Waste  No. K002)  generated  from the
  production of chrome yellow  and orange pigments; wastewater treatment sludge  (EPA
  Hazardous Waste  No.  K003)  generated from  the production of molybdate orange
  pigments; wastewater treatment sludge (EPA Hazardous Waste No. K004)  generated from
  the production of zinc yellow pigments; wastewater  treatment sludge (EPA Hazardous
  Waste No. KOOS) generated from the production of chrome green pigments; wastewater
  treatment sludge (EPA Hazardous Waste No. K006) generated from the production of
  chrome  oxide green  pigments  (anhydrous and  hydrated); wastewater treatment  sludge
  (EPA Hazardous Waste No. K007) generated from the production of iron blue pigments;
  oven  residues (EPA   Hazardous Waste  No. K008) generated from  the production  of
  chrome  oxide green  pigments after November  14,  1986. To  ensure that hazardous
  constituents are not present in the waste at levels of regulatory concern, the facility must
  implement a contingency testing program for the petitioned wastes. This testing program
  must meet the following conditions for the exclusions to be valid:
(1) Each batch  of treatment residue must be representatively sampled and tested using the
  EP Toxicity test for arsenic, barium, cadmium, chromium, lead, selenium,  silver, mercury,
  and nickel. If the extract concentrations for  chromium,  lead, arsenic, and silver exceed
  0.315 ppm, barium levels exceed 6.3 ppm; cadmium and selenium exceed  0.063  ppm;
  mercury exceeds 0.0126 ppm; or nickel  levels exceed 2.205 ppm, the waste must be re-
  treated or managed and disposed as a hazardous waste under 40 CFR Parts 262 to 265
  and the permitting standards of 40 CFR Part 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
  reactive cyanide levels exceed 250  ppm; or teachable cyanide levels  (using the EP
  Toxicity  test without acetic acid adjustment)  exceed  1.26 ppm,  the waste  must be re-
  treated or managed and disposed as hazardous waste under 40 CFR Parts  262 to 265
  and the permitting standards of 40 CFR 270.
(3) Each batch of waste must be tested for the  total content of specific organic toxicants. If
  the total content of anthracene exceeds 76.8 ppm.  1,2-diphenyl hydrazine exceeds 0.001
  ppm,  methytene chloride exceeds 6.18  ppm, methyl ethyl ketone exceeds 326 ppm. n-
  nitrosodiphenylamine exceeds 11.9 ppm, phenol  exceeds 1.566 ppm, tetrachtoroethytene
  exceeds 0.168 ppm, or trichloroethylene exceeds 0.592 ppm,  the waste must be managed
  and disposed as a hazardous waste under 40 CFR Parts 262 to 265 and the permitting
  standards of 40 CFR Part 270.
(4) A grab sample must be  collected  from  each batch to form  one monthly composite
  sample  which must be tested using  GC/MS analysis for the compounds listed  in #3
  above as well as the remaining organics on the priority  poltutan  list (See 47 FR 52309,
  November 19, 1982, for a list of the priority pollutants.)
                                                      116

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Environmental Protection  Agency                                           Pt.  261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
   Address
                                                  Waste description
LCP Chemical.
Mearl Corp	

Monsanto
  Industrial
  Chemicals
  Company.
Occidental
  Chemical
  Corp.
  Muscle
  Shoals
  Plant
               Orrington, ME..
Peekskill, NY....

Sauget, Illinois..
Sheffield,
  Alabama.
(5) The data from conditions 1-4 must be kept on file at the facility for inspection purposes
  and  must be compiled, summarized, and submitted to the Administrator by certified mail
  semi-annually. The  Agency  will  review  this information and if  needed will  propose to
  modify or withdraw  the exclusion. The organics testing described in conditions 3 and  4
  above is not required until  six  months  from  the  date of  promulgation.  The Agency's
  decision  to  conditionally  exclude the  treatment residue generated from  the  wastewater
  treatment systems at these facilities applies only to the wastewater and solids treatment
  systems as they presently exist as described in the detisting petition. The exclusion does
  not  apply to the  proposed  process  additions described  in the  petition as recovery,
  including crystalizafon. electrolytic metals  recovery,  evaporative  recovery, and ion  ex-
  change.
Brine purification muds and wastewater treatment sludges generated after August 27. 1985
  from their chlor-alkali manufacturing operations (EPA  Hazardous Waste Nos. K071  and
  K106) that have been batch  tested for mercury using the EP toxicity procedures and have
  been found  to  contain less  than 0.05 ppm mercury in the  EP extract. Brine  purification
  muds and  wastewater treatment sludges that exceed  this  level  will be  considered  a
  hazardous waste.
Wastewater treatment sludge (EPA Hazardous Waste  Nos. K006 and K007) generated from
  the production of chrome oxide green and  iron blue pigments after November 27, 1985.
Brine purification muds (EPA Hazardous Waste No. K071) generated from the mercury cell
  process in chlorine production, where separately prepurified brine is not used after August
  15, 1986.

Retorted wastewater treatment sludge from the mercury cell process in chlorine production
  (EPA Hazardous Waste No. K106) after September  19, 1989. This exclusion is conditional
  upon the submission of data obtained  from  Occidental's full-scale retort treatment system
  because Occidental's original data were based on a  pilot-scale retort system. To ensure
  that  hazardous constituents  are  not present in the  waste at  levels of regulatory concern
  once the full-scale treatment facility is in operation, Occidental must implement a testing
  program. All sampling  and  analyses (including  quality control  procedures) must  be
  performed according to SW-846  procedures. This testing program must meet the following
  conditions for the exclusion to be valid:
(1) Initial Testing—During the first four weeks of full-scale retort operation, Occidental  must
  do the following:
(A) Collect representative grab samples from every batch of retorted  material and composite
  the grab samples to produce a weekly composite sample. The weekly composite samples,
  prior to disposal or recycling, must be analyzed for the EP leachate concentrations of all
  the EP toxic metals (except mercury),  nickel, and cyanide  (using distilled water in the
  cyanide extractions),  and the total constitutent concentrations  of  reactive  sulfide  and
  reactive  cyanide. Occidental must report the  analytical test data, including all quality
  control data,  obtained during this initial period no later than 90 days after the treatment  of
  the first full-scale batch.
(B)  Collect representative  grab  samples  of  every batch  of retorted material   prior to its
  disposal  or recycling and analyze the sample  for EP  leachate concentration of mercury.
  Occidental must report the analytical test data, including all quality control data, within 90
  days after the treatment of the first full-scale batch.
(2) Subsequent Testing—After the first four weeks of full-scale retort operation, Occidental
  must do the following:
(A) Continue to sample and test as described in condition (1)(A).  Occidental must  compile
  and  store on-site for a minimum  of three years all analytical data and quality control data.
  These data  must be  furnished upon  request  and  made available for inspection by any
  employee or representative of EPA or the State of Alabama. These testing requirements
  shall  be terminated by  EPA  when  the results of four consecutive  weekly composite
  samples of  the  petitioned waste, obtained from either  the initial testing or  subsequent
  testing show the maximum  allowable levels in condition (3) are  not  exceeded and the
  Section  Chief,   Variances Section,  notifies Occidental that the  requirements  of  this
  condition have been lifted.
(B) Continue to sample and test for mercury as described in condition (1)(B).
Occidental must compile and store on-site for a minimum of three years all analytical  data
  and  quality control data.  These data must be furnished upon request and made available
  for inspection by any employee or representative of EPA or the  State ot Alabama. These
  testing requirements shall remain in  effect  until Occidental provides EPA with analytical
  and  quality  control  data  for thirty consecutive batches of retorted material, collected as
  described in  condition (1)(B), demonstrating that the  EP teachable levels of  mercury are
  below the  maximum  allowable level  in condition (3) and the Section Chief, Variances
  Section, notifies Occidental that the testing in condition (2)(B) may be replaced with (2)(C).
                                                        117

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Pt. 261, App. IX                                                  40 CFR  Ch. I (7-1-92 Edition)

                  TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                   Address
                                                  Waste description
Occidental
  Chemical
  Corporation.
Delaware City,
  Delaware.
(C) [If the conditions in (2)(B) are satisfied, the testing requirements lor mercury in (2)(B)
  shall be replaced with the following condition].  Collect representative grab samples from
  every batch of retorted material on a daily  basis and composite the grab samples to
  produce a weekly composite sample.  Occidental must analyze  each weekly composite
  sample  prior to  its disposal or recycling for  the  EP leachate concentration of mercury.
  Occidental must compile and store  on-site for a  minimum of three years all analytical data
  and quality control data. These data must be furnished upon request  and made available
  for inspection by  any employee or representative cf  EPA  or  the  State  of  Alabama.
(3) If, under condition (1) or (2), the EP leachate concentrations for chromium,  lead, arsenic,
  or silver exceed  1.616  mg/l; for barium exceeds 32.3 mg/l; for cadmium or selenium
  exceed  0.323  mg/l; for mercury exceeds 0.065 mg/l,  for nickel exceeds 16.15 mg/l;  for
  cyanide exceeds 22.61 mg/l; or for total reactive cyanide or  total reactive  sulfide levels
  exceed  250 mg/kg and 500 mg/kg, respectively, the waste must either be retreated until it
  meets these levels or managed and disposed of in accordance with subtitle C  of RCRA.
(4) Within one week  of system start-up. Occidental must notify the Section Chief,  Variances
  Section (see  address below)  when the full-scale retort  system is  on-line and  waste
  treatment  has begun. All data obtained through condition (1)  must be submitted  to the
  Section Chief, Variances Section, PSPD/OSW (OS-343),  U.S. EPA,  401  M Street SW.,
  Washington, DC 20460 within  the  time period specified in condition  (1). At the Section
  Chief's  request Occidental must  submit any  other  analytical  data obtained through
  condition (2) to the above address,  within the time period  specified by the Section Chief.
  Failure  to submit the  required  data will be considered by the  Agency sufficient basis to
  revoke Occidental's exclusion to the extent directed by EPA. All data must  be  accompa-
  nied by  the following certification statement:
"Under civil  and criminal penalty of law for the  making or submission of false  or fraudulent
  statements or representations (pursuant to the applicable provisions of the Federal Code
  which include, but may not be  limited  to, 18 U.S.C. €928), I  certify that the information
  contained  in or accompanying this document is true, accurate and complete.
As to the  (those) identified section(s) of this document for which I cannot personnel verify its
  (their) truth and accuracy, I certify as the company official having supervisory  responsibility
  for the  persons who,  acting under my direct  instructions,  made the verification that this
  information is true, accurate and complete.
In the event that any of this  information  is determined by EPA  in its sole discretion to  be
  false,  inaccurate or incomplete, and upon conveyance of this fact  to the company, I
  recognize  and agree that this exclusion of wastes  will be void as if it  never had effect or
  to the extent directed by EPA and that the company will be liable for any actions taken in
  contravention  of  the  company's RCRA and CERCLA obligations  premised  upon the
  company's reliance on the void exclusion."
Sodium chloride  treatment  muds (NaQ-TM), sodium  chloride saturates cleanings (NaCI-SC),
  and potassium chloride treatment muds (KCI-TM) (ail classified as EPA Hazardous Waste
  No. K071) generated at a maximum combined rate (for all three wastes) of 1,018 tons per
  year. This exclusion  was published on April 29, 1991  and is  conditioned  upon the
  collection of data from Occidental's full-scale brine treatment system because Occidental's
  request  for exclusion was based on data  from a laboratory-scale brine treatment process.
  To ensure that hazardous constituents are not present in the waste at levels  of regulatory
  concern once  the full-scale treatment system is in operation, Occidental must implement a
  testing   program  for the petitioned  waste All sampling and  analyses (including quality
  control procedures) must be performed according to SW-846 methodologies. This testing
  program must  meet the following conditions for the exclusion to be valid:
<1)  Initial  Testing: During  the first four  weeks of  full-scale treatment system operation.
  Occidental must do the following:
(A) Collect representative grab samples from each batch of the three treated wastestreams
  (sodium chloride saturate* cleanings (NaCI-SC), sodium chloride  treatment  muds (NaQ-
  TM) and potassium chloride treatment muds  (KCI-TM)) on an as generated basis, and
  composite the samples to produce three separate weekly composite samples (of each
  type of  K071  waste).  The three weekly  composite samples,  prior to disposal, must  be
  analyzed for the EP leachate concentrations of all the EP toxic metals (except  mercury),
  nickel and cyanide (using  deionized  water  in  the cyanide extractions), and  the total
  constituent concentrations of reactive sulfide and reactive cyanide. Occidental must report
  the waste volumes produced and the analytical test data, including all  quality  control data,
  obtained during this initial period, no later than 90 days after the treatment of me first full-
  scale batch.
(B)  Collect representative grab samples of each batch of the three treated wastestreams
  (NaCI-SC,  NAO-TM and KCI-TM)  and composite the  grab  samples to produce three
  separate daily  composite samples (of each type of  K071 waste) on an  as generated basis.
  The  three daily composite samples,  prior to disposal, must be analyzed for the  EP
  leachate concentration of mercury. Occidental must report the waste volumes  produced
  and the analytical  test data, including all quality control data,  obtained during  this initial
  period, no later than 90 days after the treatment of the  first full-scale batch.
                                                       118

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Environmental  Protection Agency                                            Pt. 261, App.  IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                Waste description
 Perox,
   Incorporat-
   ed.
Sharon,
  Pennsylva-
  nia.
(2)  Subsequent Testing:  After the  first four weeks of  full-scale  treatment  operations,
  Occidental  must do  the following  (all  sampling  and analyses (including  quality  control
  procedures) must be  performed according to SW-846 procedures):
(A)  Continue  to sample and test as described in condition (1)(A) Occidental must compile
  and store on-site for a  minimum of three years the records of waste volumes  produced
  and all  analytical  data  and quality control data. These data must be furnished upon
  request  and made available for inspection  by  any employee or representative of EPA or
  the State of Delaware. These testing requirements shall be terminated by  EPA  when the
  results of four consecutive weekly composite  samples of the  petitioned waste, obtained
  from either the initial  testing or subsequent testing, show the maximum allowable levels in
  condition  (3) are  not  exceeded  and the Section  Chief, Variances  Section,  notifies
  Occidental  that the requirements of this condition have been lifted.
(B)  Continue to sample and test for mercury as described in condition  (1)(B). Occidental
  must  compile and store  on-site  for a minimum  of  three years  the  records  of  waste
  volumes produced and  all  analytical data and quality control  data. These data must be
  furnished upon request and made available for inspection by any employee or representa-
  tive of EPA or the State of Delaware. These testing requirements shall be  terminated and
  replaced with the requirements  of  condition (2)(C)  if Occidental provides EPA with
  analytical  and quality  control  data for thirty consecutive batches of  treated material,
  collected as  described  in condition (1)(B), demonstrating that the EP leachable level of
  mercury in condition (3) is not exceeded  (in  all  three  treated wastes), and  the Section
  Chief, Variances Section,  notifies Occidental that the testing  in condition (2)(B) may be
  replaced with (2)(C).
(C)  [If the conditions in  (2)(B) are satisfied, the testing requirements for  mercury in (2)(B)
  shall be replaced with the  following condition.] Collect  representative grab samples from
  each batch of the three treated wastestreams  (NaCI-SC, NaCI-TM  and KCI-TM) on an as
  generated  basis  and composite  the  grab samples to  produce three  separate  weekly
  composite  samples (of  each type of K071 waste). The three weekly composite samples,
  prior  to disposal, must be analyzed  for  the  EP  leachate  concentration  of mercury.
  Occidental must compile and store on-site for a minimum of  three years the records of
  waste volumes produced and all analytical  data and quality control  data. These data must
  be furnished upon  request and  made  available  for  inspection   by any employee  or
  representative of EPA or the State of Delaware.
(3)  If under conditions  (1) or  (2), the EP leachate concentration for chromium, lead, arsenic,
  or silver exceeds  0.77  mg/L;  for barium exceeds  15.5 mg/L; for  cadmium  or selenium
  exceeds 0.16 mg/L;  for mercury exceeds 0.031 mg/L; for nickel or total cyanide exceeds
  10.9 mg/L; or the total reactive cyanide or  total reactive sulfide levels exceeds 250 mg/kg
  and 500 mg/kg, the waste must either be  retreated  or  managed and  disposed of in
  accordance with all applicable hazardous waste regulations.
(4)  Within one  week of system start-up, Occidental  must notify the Section Chief,  Variances
  Section (see address below) when the full-scale system is on-line and waste  treatment
  has begun. All data obtained through condition (1) must  be submitted to the Section Chief,
  Variances  Section, PSPD/OSW, (OS-333), U.S. EPA, 401 M Street, SW., Washington, DC
  20460 within the  time  period required in  condition (1). At the Section Chief's request,
  Occidental must submit any other  analytical data obtained through conditions (1)  and (2)
  to the  above address  within the time period specified  by the  Section Chief.  Failure to
  submit  the required  data  will be  considered by  the  Agency  sufficient basis  to  revoke
  Occidental's  exclusion to the extent directed by EPA. All data  (either submitted  to EPA or
  maintained at the site) must be accompanied by the following statement:
"Under civil  and criminal  penalty of law  for the  making or submission of  false or  fraudulent
  statements or representations  (pursuant to  the applicable provisions of the Federal Code,
  which include, but may  not be limited to 18 U.S.C. 1001 and 42 U.S.C. 6926), I certify that
  the  information contained  in  or  accompanying  this  document  is true, accurate  and
  complete.
As to the (those)  identified section(s) of this document for  which I cannot personally verify its
  (their) truth and  accuracy, I certify as the company official having supervisory responsibility
  for the persons who, acting under my direct instructions,  made the verification that this
  information is true, accurate and complete.
 In  the event that  any  of  this information is determined by EPA in its sole discretion to be
  false,  inaccurate or incomplete,  and  upon conveyance of this fact to  the company, I
  recognize  and agree that this  exclusion of wastes will be void as if it never had effect or
  to the extent directed by EPA and that the company will be liable for any actions taken in
  contravention of  the  company's  RCRA  and CERCLA obligations premised  upon the
  company's reliance on the void exclusion."
 Iron oxide (EPA Hazardous Waste No. K062) generated (at a maximum annual  rate  of 4800
   cubic yards)  from a spent hydrochloric acid pickle liquor regeneration plant for spent pickle
   liquor  generated  from  steel  finishing operations. This  exclusion was  published  on,
   November 13, 1990.
                                                        119
     311-147  O—92-

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Pt. 261, App. IX                                                   40  CFR Ch. I (7-1-92 Edition)

                  TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility
Pioneer Chlor
Alkai
Company,
Inc.
(formerly
Address
St. Gabriel, LA .
Waste description
Brine purification muds, which have been washed and vacuum filtered, generated after
August 27, 1985 from their chlor-alkali manufacturing operations (EPA Hazardous Waste
No. K071) that have been batch tested for mercury using the EP toxicity procedure and
have been found to contain less than 0.05 ppm in mercury in the EP extract. Brine
purification muds that exceed this level will be considered a hazardous waste.
  Stauffer
  Chemical
  Company).
Reynolds
  Metals
  Company.
Gum Springs,    Kiln residue (generated at a maximum annual volume of 300,000 cubic yards per year) from
  Arkansas.   I    rotary kiln treatment of spent potliners (EPA Hazardous Waste No. K088). This exclusion
              j    was  published on December  30,  1991.  This  exclusion does not apply to electrostatic
              i    precipitator dust  generated by the rotary kiln.  This exclusion initially applies  only to the
                  treatment  by one rotary kiln  of  potliners  generated by Reynolds Metals' four primary
                  aluminum facilities (Massena, New York; Longview, Washington; Troutdale, Oregon; and
                  Baie Comeau.  Quebec) described in the  petition.  Reynolds may only accept  spent
                  potliners from other sources, or modify its treatment
                  process, or add an additional rotary kiln in accordance with Condition (5). This  exclusion is
                  conditional  upon  the  submission of  data  obtained  trom  each rotary  kiln after  it is
                  established  at the  R.P. Patterson  facility  in  Gum  Springs, Arkansas. To  ensure that
                  hazardous constituents are not present in the waste at levels of regulatory concern while
                  the treatment facility is in  operation,  Reynolds must  implement a testing program. This
                  testing program  must  meet  the following conditions for  the exclusion  to be  valid:
                (1) Operating Conditions:
                (A)  Initial Verification Testing: During the first 20 days of full-scale operation of the  rotary
                  kiln,  at typical operating conditions, Reynolds must monitor and submit to EPA the  rotary
                  kiln operating conditions (including, but not limited to: Temperature range of the kiln (hot
                  and  cold end),  kiln residue exit  temperature, spent potliner feed rate, brown sand feed
                  rate, limestone  feed rate,  natural gas feed rate, oxygen/air  feed rate, and rotary  kiln
                  residence time  of the raw  materials). The  ratio  of the spent  potliner feed  rate to the
                  combined feed rates of the spent potliner,  brown sand, and limestone must be no more
                  than 0.35. Information on all
                  other operating conditions  should encompass all conditions used  for preliminary testing
                  runs and  those  anticipated for  subsequent waste processing.  During  initial verification
                  testing,  the petitioner  must also demonstrate  to  EPA  how the  range of operating
                  conditions could affect the  process (i.e., submit analyses of  representative grab samples,
                  as specified under Condition (2), of the kiln residue generated under the expected range
                  of operating conditions). The source of the brown sand must be from Reynolds'  dry lake
                  beds at the Bauxite, Arkansas facility. Reynolds must submit the information  specified in
                  this  condition  and obtained during this initial  period no later  than  90 days after the
                  treatment of the first full-scale batch of spent potliner.
                (B)  Subsequent Verification  Testing: During subsequent verification testing, Reynolds  must
                  monitor the performance of the  rotary kiln at  all times to  ensure that it falls within the
                  range  of  operating  conditions  demonstrated  during initial verification testing, to be
                  adequate  to maintain  the  levels of  hazardous constituents below the delistmg  levels
                  specified in Condition (4). The feed rates of spent potliner, lime and brown sand are to be
                  as that described in Condition
                  (1)(A). Records of the operating conditions  of the rotary kiln (including, but not limited to:
                  Temperature range of the kiln,  kiln  residue exit temperature,  spent potliner feed rate,
                  brown sand feed rate, limestone feed rate, natural gas feed rate, oxygen/air feed rate, and
                  rotary kiln  residence  time of the raw materials) should be maintained on site for  a
                  minimum of five years. This  information  must be furnished  upon request and  made
                  available for inspection by any  employee or representative of  EPA  or  the  State of
                  Arkansas.
                (2)  Testing: Sample collection and analyses (including quality control (QC) procedures) must
                  be  performed according  to SW-846 methodologies.  For fluoride,  samples  must be
                  analyzed using Method 340.2 from "Methods for Chemical Analysis of Water and Waste".
                  If the EPA judges the treatment  process to be effective under the operating conditions
                  used during the initial verification testing, Reynolds may replace the testing required in
                  Condition (2)(A)  with the testing required in Condition (2)(B). Reynolds  must  continue to
                  test daily composites of  kiln residue generated beyond  the time period  specified in
                  Condition (2)(A) until and unless notified  by EPA in writing that testing in Condition (2)(A)
                  may be replaced by Condition (2)(B) (to the extent directed by EPA).
                (A)  Initial Verification Testing: During the first 20 operating days of full-scale operation of the
                  new on-line rotary kiln. Reynolds must collect and analyze daily composites of  kiln residue.
                  Daily composites must be composed of representative grab samples collected every 6
                  hours  during each 24-hour kiln operating cycle.  The  kiln residue samples  must  be
                  analyzed, prior to the disposal of the kiln residue,  for all constituents listed  in Condition
                  (4).  Reynolds  must report the analytical test  data, including  quality  control  information,
                  obtained during this initial period no later than  90 days after the treatment of  the first full-
                  scale batch of untreated spent potliner.
                                                        120

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Environmental  Protection Agency                                            Pt. 261,  App.  IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
Waste description
                               (B) Subsequent Verification Testing: Following notification by EPA, Reynolds may substitute
                                 the testing conditions in (2)(B) for (2)(A). Reynolds must collect and analyze both daily and
                                 weekly composites of kiln residue. Daily composites must be  composed of representative
                                 grab samples collected  every 6  hours during a 24-hour kiln operating cycle and these
                                 samples  must be analyzed,  prior  to the  disposal of the  kiln  residue, for leachable
                                 concentrations of  cyanide  and  fluoride.  Weekly  composites must be composed  of
                                 representative grab samples collected every 6 hours during a  24-hour kiln operating cycle
                                 for each day in the week that the kiln is operating.
                                 The weekly samples must be analyzed,  prior to the disposal of the kiln  residue,  for the
                                 leachable concentrations of the inorganics listed in Condition (4)(A) and leachable levels
                                 of  the  semi-volatile  organic compounds listed in Condition (4)(B). Analyses of both daily
                                 and weekly samples must be completed prior to the disposal of waste generated during
                                 that  week as  set forth in  Condition (3).  The analytical data,  including quality  control
                                 information, must be compiled, summarized, and maintained on site for a  minimum of five
                                 years. These data must be furnished upon request and made available for inspection  by
                                 any employee or representative of EPA or the State of Arkansas.
                               (3)  Waste  Holding and Handling: Reynolds must  store,  as  hazardous,  all  kiln  residue
                                 generated until verification testing (as specified in Condition (2)(A) and (2)(B)) is completed
                                 and compared, by the petitioner, with the delisting levels set  forth in Condition (4). If the
                                 levels of hazardous constituents measured in the samples of kiln residue generated do not
                                 exceed any of the levels set forth in Condition (4), then the kiln residue is non-hazardous
                                 and may be managed and
                                 disposed of in  accordance  with all  applicable solid  waste regulations. If  hazardous
                                 constituent levels in  any daily or weekly sample exceed any  of the  delisting levels set in
                                 Condition  (4),  the kiln residue  generated during the time period corresponding  to this
                                 sample  must be retreated  until  it  meets  these levels (analyses must  be repeated)  or
                                 managed and disposed  of in  accordance with Subtitle C of RCRA.  Kiln residue which is
                                 generated but for which the required analysis is not complete or  valid must be managed
                                 and disposed of  in accordance with  Subtitle C of RCRA, until valid analysis demonstrates
                                 that Condition (4) is satisfied.
                               (4) Delisting Levels: All concentrations must be measured in  the waste  leachate  by the
                                 method specified in  40 CFR 261.24.
                               (A) The  leachable concentrations  for  metals may  not  exceed the following levels (ppm):
                                 arsenic, selenium, or silver—0.60; barium—12.0; antimony—0.12; lead—0.18; cadmium—
                                 0.06,  chromium  or  nickel—1.2; mercury—0.024;  beryllium—0.012; fluoride—48.0;  and
                                 cyanide—2.4 (cyanide extraction must be conducted using deionized  water).
                               (B) The leachable  constituent concentrations for organics may  not  exceed  the  levels listed
                                 below (ppm):
                                 Acenapthene—24
                                 Benz(a)anthracene—1.2x10"*
                                 Benzo(b)f luoranthene—2.4x10"4
                                 Benzo(a)pyrene—2.4x10~3
                                 Chrysene—2.4x10~3
                                 Fluoranthene—12
                                 Indeno (1,2,3-cd)pyrene—2.4x10~3
                                 Pyrene—12
                               (5)  Changes in  Operating Conditions and  Waste Sources: If after  completing  the initial
                                 verification test  period in Conditions (1)(A)  and (2)(A), Reynolds decides to treat  spent
                                 potliner from any other primary aluminum reduction  facility; or use a  new source for brown
                                 sand; or otherwise significantly change the operating conditions developed under Condition
                                 (1); then Reynolds must notify EPA in writing prior to instituting the change. Reynolds must
                                 also reinstitute  the testing  and  reporting  required in Conditions (1)(A) and  (2)(A) for a
                                 minimum period  of  four operating days and  fulfill all other requirements  in Conditions (1)
                                 and (2), as appropriate.
                                 Reynolds  may also add one  additional kiln at its  R.P. Patterson facility  in Gum  Springs,
                                 Arkansas  if  it  can demonstrate that the new kiln  can successfully treat spent potliners.
                                 Reynolds  must fulfill all requirements contained in  Conditions (1) and (2) for the second
                                 kiln. Reynolds must continue to test any kiln residue generated  beyond  the time period
                                 specified  in Condition  (2)(A)  until  and unless notified in writing  by EPA  that testing
                                 Condition (2)(A)  may be replaced by (2)(B) to the extent directed by  EPA.
                               (6) Data Submittals: Reynolds must notify in writing the Section Chief, Delisting Section (see
                                 address  below)  when the rotary kiln  is  on-line  and two  weeks  prior  to when waste
                                 treatment will begin. The  data  obtained through  Conditions (1)(A) and (2)(A) must be
                                 submitted to the Section Chief, Delisting Section, OSW (OS-333),  U.S. EPA, 401 M Street,
                                 SW, Washington,  DC 20460 within the time period specified.  At the  Section Chief's
                                 request, Reynolds must submit any other
                                                        121

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Pt.  261,  App. IX                                                 40 CFR Ch. I (7-1-92 Edition)

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
Waste description
                                analytical data obtained through Conditions  (1){B)  and (2)(B)  within the time period
                                specified by the Section Chief. Failure to submit the required data within the specified time
                                period or maintain the required records on site for the specified time will be considered by
                                the Agency, at its discretion, sufficient basis to revoke the exclusion to the extent directed
                                by EPA. All data must  be  accompanied by a signed copy of the following certification
                                statement to attest to the truth and accuracy of the data submitted:
                              "Under civil and criminal  penalty of law for the making or submission of false or fraudulent
                                statements or representations (pursuant to the applicable  provisions of the Federal Code,
                                which include, but may not be limited to, 18 USC § 1001 and 42 USC §6928), I certify that
                                the  information  contained  in or accompanying this document is true,  accurate and
                                complete.
                              "As to the (those)  identified section(s) of this document for  which I  cannot personally verify
                                its (their)  truth  and  accuracy,  I certify as  the company  official having supervisory
                                responsibility  for the  persons  who,  acting  under  my  direct instructions,  made the
                                verification that this information is true, accurate and complete.
                              "In the event that  any of this information is determined by  EPA in its sole  discretion  to be
                                false, inaccurate or incomplete,  and upon conveyance of  this fact to  the company,  I
                                recognize and agree that this  exclusion of wastes will be  void  as if  it never had effect or
                                to the extent directed by EPA  and that the company will be liable  for any  actions taken in
                                contravention  of the  company's RCRA and CERCLA  obligations  premised  upon the
                                company's reliance on the void exclusion."
                                                     122

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Environmental  Protection Agency                                            Pt. 261, App.  IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                  Address
                                                 Waste description
Roanoke
  Electric
  Steel Corp.
Roanoke, VA.
 Tricil
   Environmen-
   tal Systems,
   Inc.
                Milliard, Ohio..
Fully-cured chemically stabilized  electric  arc furnace dust/sludge  (CSEAFD) treatment
  residue  (EPA Hazardous Waste No. K061) generated from the primary production of steel
  after  March  22,  1989. This exclusion is  conditioned  upon  the  data  obtained from
  Roanoke's  full-scale CSEAFD treatment facility because Roanoke's  original data were
  obtained from a laboratory-scale CSEAFD treatment process. To ensure that hazardous
  constituents are not present in  the waste at levels  of regulatory concern once  the full-
  scale treatment facility is in operation, Roanoke must implement a testing program for the
  petitioned waste.
This testing program must  meet the following conditions  for the exclusion  to be valid:
(1)  Testing:
(A)  Initial testing: During the  first four weeks of operation of  the full-scale treatment system,
  Roanoke must collect representative grab samples of each treated batch of the CSEAFD
  and  composite the  grab samples  daily. The daily composites, prior to disposal,  must be
  analyzed for the EP leachate concentrations of all the EP toxic metals, nickel and cyanide
  (using distilled water in the cyanide extractions), and the  total constituent concentrations
  of reactive  sulfide  and reactive  cyanide. Analyses must be performed according to SW-
  846  methodologies.  Roanoke must  report  the analytical  test data obtained during this
  initial period  no later  than 90 days  after the treatment of the  first full-scale  batch.
(.8)  Subsequent  testing: Roanoke  must collect representative grab samples  from every
  treated  batch of CSEAFD generated daily and composite all  of  the grab  samples to
  produce a weekly composite sample. Roanoke then must  analyze each weekly composite
  sample  for a/I of the EP toxic metals and nickel. Analyses must be performed according to
  SW-846 methodologies. The analytical data, including all quality control information, must
  be compiled and maintained on site for a minimum of three years. These data  must be
  furnished upon request and made available  for inspection by any employee or representa-
  tive of EPA or the State of Virginia.
(2)  Delisting levels: If  the EP extract concentrations  for chromium, lead, arsenic,  or silver
  exceed  0.315 mg/l; for barium exceeds 6.3  mg/l; for cadmium or selenium exceed 0.063
  mg/l; for mercury  exceeds  0.0126 mg/l; for nickel exceeds  3.15  mg/l;  or  for cyanide
  exceeds 1.26 mg/l,  or total reactive cyanide or total reactive sulfide levels exceed 250
  mg/kg and 500 mg/kg,  respectively, the waste must either be re-treated or managed and
  disposed in accordance with Subtitle C of RCRA.
<3) Data  submittals:  Within one week of system start-up, Roanoke must notify the Sect/on
  Chief, Variances Section (see address below) when their full-scale stabilization system in
  on-line  and  waste treatment has begun.   All data obtained through the initial testing
  condition (1KA), must be  submitted to the Section Chief,  Variances Section, PSPD/OSW,
  (OS-343),  U.S.  EPA, 401 M Street, SW.,  Washington,  DC 20460 within the time  period
  specified in condition (?)
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Pt. 261, App. IX                                40 CFR Ch. I (7-1-92 Edition)
           TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
Facility








































Trial
Environmen-
tal System,
Inc.

























Address








































Muskegon,
Michigan.



























Waste description
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm; or teachable cyanide levels (using ther EP
Toxicity test without acetic acid adjustment) exceed 1.26 ppm, the waste must be
retreated or managed and disposed as hazardous waste under 40 CFR parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and disposed as a hazardous waste under 40 CFR
parts 262 and 265 and the permitting standards of 40 CFR Part 270.
Compound and Maximum Acceptable Levels (ppm)
Acrdein, 56.8
Anthracene, 76.8
Benzene, 0.106
p-Chtoro-m-cresol, 133
1,1-Dichloroethane, 0.01
Fluorene, 10.4
Methylenechloride, 8.2
Methyl ethyl ketone, 326
n-Nitrosodiphenylamine, 11.9
Phenanthrene, 14
Tetrachloroethylene, 0.188
Trichloroethytene, 0.59
Chloroform, 0.013
1,2-Dichloroethane, 0.0083
1 ,2-trans-Dichloroethylene, 231
2.4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
1 ,2-Diphenyl hydrazine, 0.001
(4) A grab sample must be collected from each batch to form one monthy composite
sample, which must be tested using GC/MS analysis for the organic compounds shown
above, as well as the remaining organics on the priority pollutant list (see 47 FR 52309,
November 19, 1982, Appendix A-126 Priority Pollutants).
(5) The test data from conditions 1-4 must be kept on file at the facility for inspection
purposes and must be compiled, summarized, and submitted to the Administrator by
certified mail on a semiannual basis. The Agency will review this information and if
needed, will propose to modify or withdraw the exclusion. The organics testing described
in conditions 3 and 4 above is not required until May 18, 1987. The Agency's decision to
conditionally exclude the treatment residue generated from the wastewater treatment
system at this facility applies only to the wastewater treatment residue described in this
petition.
Spent pickle liquor (EPA Hazardous Waste No. K062) generated by steel finishing operations
Of facilities within the iron and steel industry (SIC Codes 331 and 332); after November 17,
1986. To ensure that hazardous constituents are not present in the waste at levels of
regulatory concern, the facility must implement a contingency testing program for the
petitioned wastes. This testing program must meet the following conditions for the
exclusion to be valid:
(1) Each batch of treatment residue must be representatively sampled and tested using the
total oil and grease test and the EP Toxicity test (or the Oily Waste EP test, if the oil and
grease content of the waste exceeds one percent) for arsenic, barium, cadmium.
chromium, lead, mercury, selenium, silver and nickel. If the extract concentrations for
chromium, lead, arsenic, barium, and silver exceed 6.3 ppm, cadmium and selenium
exceed 0.063 ppm; mercury levels exceed 0.013 ppm; or nickel levels exceed 2.2 ppm,
the waste will be retreated or managed and disposed as a hazardous waste under 40 CFR
parts 262 to 265 and the permitting standards of 40 CFR 270.
(2) Each batch of treatment residue must be tested for reactive and teachable cyanide. If the
reactive cyanide levels exceed 250 ppm; or teachable cyanide levels (using the EP
Toxicity test without acetic acid adjustment) exceed 1.26 ppm, the waste must be
retreated or managed and disposed as hazardous waste under 40 CFR parts 262 to 265
and the permitting standards of 40 CFR Part 270.
(3) Each batch of waste must be tested for the total content of the following organic
toxicants. If the total content of any of the constituents exceeds the maximum levels
shown, the waste must be managed and dipnosed as a hazardous waste under 40 CFR
parts 262 and 265 and the permitting standards of 40 CFR Part 270:
Compound and Maximum Acceptable Levels (ppm)
Acrotetn, 56.8
Anthracene, 76.8
Benzene. 0.106
p-Chkxc-m-cresol, 133
1,1-Dichloroethane, 0.01
                                   124

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Environmental  Protection Agency                                           Pt. 261, App. IX

                 TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
   Facility
                  Address
                                                 Waste description
USX Steel
  Corporation,
  uss
  Division,
  Southworks
  Plant, Gary
  Works.
Chicago,
  Illinois.
Fluorene, 10.4
Methylenechloride, 8.2
Methyl ethyl ketone, 326
n-Nitrosodiphenylamine,  11.9
Phenanthrene, 14
Tetrachtoroettiylene, 0.188
Trichloroethyiene. 0.59
Chloroform, 0.013
1,2-Dtchloroethane. 0.0083
1,2-trans-Dtchloroethylene, 231
2,4-Dimethylphenol, 12.5
Vinyl chloride, 0.18
1,2-Diphenyl hydrazine, 0.001
(4)  A grab  sample  must  be  collected  from each batch to form one monthly composite
  sample, which must be  tested using GC/MS analysis for the organic compounds shown
  above, as well as the remaining organics on the priority pollutant list (see 47 FR 52309,
  November 19, 1982, Appendix A-126 Priority Pollutants).
(5)  The test data from  conditions  1-4  must be  kept  on  file  at the facility for inspection
  purposes  and must be compiled,  summarized, and submitted to the Administrator by
  certified mail on  a semiannual basis.  The  Agency will review this information and if
  needed, will propose to  modify or withdraw the exclusion. The organics testing described
  in conditions  3 and 4  above is not required until May 18, 1987. The Agency's decision to
  conditionally  exclude  the treatment residue  generated  from the  wasterwater treatment
  system at this facility  applies only to  the wastewater treatment residue described in this
  petition.
Fully-cured  chemically   stabilized  electric  arc  furnace dust/sludge  (CSEAFD) treatment
  residue 
-------
 Pt. 261, App. X                                            40 CFR Ch. I (7-1-92 Edition)

                TABLE 2—WASTES EXCLUDED FROM SPECIFIC SOURCES—Continued
    Facility
                Address
                                           Waste description
Vulcan
  Materials
  Company.
Port Edwards,
  Wl.
(3) Data submittals: Within one week of system start-up USX must notify the Section Chief,
  Oelisting Section (see address below) when their full-scale stabilization system is on-line
  and waste treatment has begun. The data  obtained through condition (1)(A) must be
  submitted to the Section Chief, Delisting Section, CAD/OSW (OS-333), U.S. EPA, 401 M
  Street, S.W., Washington, DC 20460 within the time  period  specified. At the Section
  Chief's request, USX must submit any other analytical  data obtained  through conditions
  (1)(A) or (1)(B) within the time period specified by the Section Chief. Failure to submit the
  required data obtained from conditions (1)(A) or (1)(B) within the specified time period or
  maintain the required records for the specified time will be considered by the  Agency, at
  its discretion, sufficient basis to revoke USX's exclusion  to the extent directed by EPA. All
  data  must be accompanied by  the  following certification statement: "Under civil  and
  criminal penalty of law for the making or submission of false or fraudulent statements or
  representations (pursuant to the applicable provisions of the Federal Code which include,
  but may not be limited to, 18 U.S.C. §6928), I certify that the information contained in or
  accompanying this document is true, accurate and complete. As to the (those) identified
  section(s) of this document for which  I  cannot  personally verify its (their) truth  and
  accuracy, I certify as the company official having supervisory responsibility for the persons
  who, acting under my direct instructions,  made the verification that this  information  is true,
  accurate and complete. In the event that any of this information is determined by  EPA in
  its sole discretion to be false, inaccurate or incomplete,  and upon  conveyance of this fact
  to the company,  I recognize and agree that this exclusion of wastes will be void  as if it
  never had effect or to the extent directed by EPA and that the company will be liable for
  any  actions taken  in contravention of the company's  RCRA  and CERCLA  obligations
  premised upon the company's reliance on the void exclusion."
Brine purification muds (EPA Hazardous Waste No. K071) generated from the mercury cell
  process  in chlorine production,  where  separately prepurified brine is  not used after
  November 17, 1986. To assure that mercury levels  in  this  waste are maintained at
  acceptable levels, the following conditions  apply to this exclusion:  Each batch of treated
  brine clanfier muds  and saturator insolubles must be tested (by the extraction procedure)
  prior to disposal and the leachate concentration of mercury must be less than or equal to
  0.0129 ppm. If the  waste does not meet this requirement, then it must be re-treated or
  disposed of as hazardous. This exclusion  does not  apply to wastes for which either of
  these conditions is not satisfied.
TABLE 3—WASTES EXCLUDED FROM COMMER-
  CIAL  CHEMICAL  PRODUCTS,  OFF-SPECIFICA-
  TION  SPECIES,  CONTAINER  RESIDUES, AND
  SOIL RESIDUES THEREOF
Facility
Union Carbide
Corp.
Address
Tafl LA

Waste description
Contaminated soil (approxi-
mately 1 1 ,000 cubic
yards), which contains
acrolem in concentra-
tions of less than 9 ppm.
[49 PR 37070, Sept. 21, 1984]
  EDITORIAL NOTE: For FEDERAL REGISTER ci-
tations  affecting  appendix IX of part 261,
see the List of CFR Sections Affected in the
Finding Aids section of this volume.
                                      APPENDIX X  TO  PART 261—METHOD OF
                                           ANALYSIS   FOR   CHLORINATED   DI-
                                           BENZO-P-DIOXINS    AND     -DIBENZO-
                                           FTJRANS »• * a- 4

                                                       Method 8280
                                        1. Scope and Application
                                        'This method is appropriate for the anal-
                                      ysis of tetra-,  penta-, and hexachlorinated
                                      dibenzo-p-dioxins and -dibenzofurans.
                                        2 Analytical protocol for determination  of
                                      TCDDs in phenolic chemical wastes and soil
                                      samples obtained from   the proximity  of
                                      chemical  dumps.  T.O.   Tiernan  and  M.
                                      Taylor.  Brehm  Laboratory,  Wright  State
                                      University, Dayton, OH 45435.
                                        'Analytical protocol for determination  of
                                      chlorinated dibenzo-p-dioxins and chlorinat-
                                      ed  dibenzofurans in river water. T.O. Tier-
                                      nan  and  M.   Taylor.  Brehm  Laboratory,
                                      Wright State University, Dayton, OH  45435.
                                        4 In general, the techniques that should be
                                      used to handle  these  materials are  those
                                      which  are followed for radioactive  or infec-
                                      tious  laboratory  materials.  Assistance  in
                                      evaluating  laboratory practices may be ob-
                                                                            Continued
                                                126

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Environmental Protection Agency
                         Pt. 261, App. X
  1.1  This method measures the concentra-
tion of chlorinated dibenzo-p-dioxins  and
chlorinated  dibenzofurans   in  chemical
wastes including still  bottoms, filter aids,
sludges, spent carbon,  and reactor residues,
and in soils.
  1.2  The sensitivity of this method is de-
pendent upon the level of interferences.
  1.3  This method is recommended for use
only by analysts experienced with  residue
analysis and skilled in mass spectral analyti-
cal techniques.
  1.4  Because  of  the extreme toxicity of
these compounds,  the analyst must  take
necessary precautions  to prevent  exposure
to himself, or to others, of materials known
or believed to contain CDDs or CDPs.
  2. Summary of the Method
  2.1  This method is  an analytical extrac-
tion  cleanup  procedure,   and  capillary
column gas  chromatograph-low resolution
mass spectrometry method, using capillary
column GC/MS  conditions  and   internal
standard  techniques, which allow for the
measurement of PCDDs and PCDPs in the
extract.
  2.2  If interferences  are  encountered, the
method provides selected  general purpose
cleanup procedures to aid the analyst in
their elimination.
  3. Interferences
  3.1  Solvents,  reagents,   glassware,  and
other sample processing hardware may yield
discrete artifacts and/or elevated  baselines
causing misinterpretation of gas chromato-
grams. All of these materials must be dem-
onstrated to  be  free  from interferences
under the conditions of the analysis by run-
ning method blanks. Specific selection of
reagents and purification of solvents by dis-
tillation  in all-glass  systems  may be re-
quired.
  3.2  Interferences co-extracted from the
samples will  vary considerably from source
to source, depending upon the  diversity of
the industry  being sampled. PCDD is often
associated with other interfering chlorinat-
tained from industrial  hygienists and per-
sons specializing in safe laboratory prac-
tices. Typical  infectious waste incinerators
are probably not satisfactory devices for dis-
posal of materials highly contaminated with
CDDs or CDFs. Safety instructions are out-
lined in EPA Test Method 613(4.0)
  See also: (1) "Program for monitoring po-
tential contamination in the laboratory fol-
lowing the handling and analyses of chlorin-
ated dibenzo-p-dioxins  and dibenzofurans"
by F. D. Hileman et al.. In:  Human and En-
vironmental Risks  of  Chlorinated Dioxins
and Related Compounds, R.E. Tucker, et al,
eds.,  Plenum  Publishing  Corp., 1983.  2)
Safety procedures outlined  in EPA Method
613, Federal Register  volume 44, No. 233,
December 3, 1979.
ed compounds such as PCB's which may be
at concentrations several orders  of  magni-
tude higher than that of PCDD. While gen-
eral cleanup techniques are provided  as part
of this method, unique samples may require
additional  cleanup  approaches to achieve
the sensitivity stated in Table 1.

 TABLE 1—GAS CHROMATOGRAPHY  OF  TCDD

Column

Glass capillary 	

Reten-
tion time
(min.)
9 5

Detec-
tion limit
(M/kg)1
0003

  1 Detection limit fo' liquid samples is 0.003 fig/I. This is
calculated from the minimum detectable GC response being
equal to five times the GC background noise assuming a 1
ml effective final volume of the 1 liter sample extract, and a
GC injection of 5 microliters. Detection levels apply to both
electron capture and GC/MS detection. For further details
see 44 FR 69526 (December 3, 1979).

  3.3  The other  isomers of tetrachlorodi-
benzo-p-dioxin may interfere with the meas-
urement of 2,3,7,8-TCDD. Capillary column
gas chromatography is required to resolve
those isomers that yield virtually identical
mass fragmentation patterns.
  4. Apparatus and Materials
  4.1. Sampling equipment for discrete or
composite sampling.
  4.1.1   Grab sample bottle—amber glass, 1-
liter or 1-quart volume. French or Boston
Round design is recommended. The contain-
er must be washed and solvent rinsed before
use to minimize interferences.
  4.1.2.  Bottle caps—threaded  to  screw on
to the sample bottles. Caps must be lined
with Teflon. Solvent washed foil, used with
the shiny side towards the sample, may be
substituted for the Teflon if sample  is  not
corrosive.
  4.1.3.  Compositing equipment—automatic
or manual composing  system. No  tygon or
rubber tubing may be used,  and the system
must  incorporate  glass  sample containers
for the  collection of a minimum of 250 ml.
Sample containers must be  kept refrigerat-
ed after sampling.
  4.2  Water bath—heated, with concentric
ring cover, capable of temperature control
(±2 °C). The bath should be used in a hood.
  4.3  Gas chromatograph/mass spectrome-
ter data system.
  4.3.1   Gas chromatograph: An  analytical
system  with a temperature-programmable
gas chromatograph and all required accesso-
ries including syringes, analytical  columns,
and gases.
  4.3.2   Column: SP-2250 coated on a 30 m
long x 0.25 mm I.D. glass column (Supelco
No. 2-3714  or  equivalent).  Glass  capillary
column conditions: Helium carrier gas at 30
cm/sec linear velocity run splitless. Column
temperature is 210 °C.
                                         127

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Pt. 261, App. X

  4.3.3  Mass spectrometer: Capable of scan-
ning from 35 to 450 amu every 1 sec or less,
utilizing 70 volts (nominal) electron energy
in the electron impact ionization mode and
producing a mass spectrum which meets all
the criteria in Table 2 when 50 ng of deca-
fluorotriphenyl-phosphine (DFTPP) is  in-
jected through  the  GC inlet. The  system
must also be capable of selected ion moni-
toring (SIM)  for  at least  4 ions  simulta-
neously, with a cycle time of 1 sec  or less.
Minimum integration time for SIM is 100
ms. Selected ion monitoring is verified by in-
jecting .015 ng of TCDD Cl37 to give a mini-
mum signal to noise ratio of 5 to 1 at mass
328.

     TABLE 2—DFTPP KEY IONS AND ION
           ABUNDANCE CRITERIA *
   Mass
       51
       68
       70
      127
      197
      196
      199
      275
      365
      441
      442
      443
                  Ion abundance criteria
30-60% of mass 198.
Less than 2% of mass 69.
Less than 2% of mass 69.
40-60% of mass 198.
Less than 1% of mass 198.
Base peak. 100% relative abundance.
5-9% of mass 196.
10-30% of mass 198.
Greater than 1% of mass 198.
Present but less than mass 443.
Greater than 40% of mass 198.
17-23% of mass 442.
  »J. W. Eichelberger, l_E. Hams, and W.L. Budde. 1975.
Reference compound to calibrate ion abundance measure-
ment in gas chromatography-mass spectrometry. Analytical
Chemistiy 47:995.

  4.3.4  GC/MS  interface:  Any  GC-to-MS
interface that gives acceptable calibration
points at 50 ng per injection for each com-
pound of interest and achieves  acceptable
tuning  performance criteria (see Sections
6.1 through  6.3) may  be used.  GC-to-MS
interfaces constructed of all glass or glass-
lined materials are recommended. Glass can
be deactivated by silanizing with dichlorodi-
methylsilane. The interface must be capable
of transporting at least 10 ng of the compo-
nents of interest from the GC to the MS.
  4.3.5  Data  system:  A  computer  system
must be interfaced to the mass spectrome-
ter. The system must  allow the continuous
acquisition and storage on machine-readable
media of all mass spectra obtained through-
out the duration of the chromatographic
program. The computer must have software
that  can search any GC/MS data file for
ions of a specific mass and that can plot
such ion abundances  versus time or scan
number. This type of  plot  is defined as an
Extracted Ion Current Profile (EICP). Soft-
ware must  also be able to integrate  the
abundance, in any EICP, between specified
time or scan number limits.
          40 CFR Ch. I (7-1-92 Edition)

  4.4  Pipettes-Disposable, Pasteur, 150 mm
long x 5 mm ID (Fisher Scientific Co., No.
13-678-6A or equivalent).
  4.5  Flint glass bottle (Teflon-lined screw
cap).
  4.6  Reacti-vial (silanized) (Pierce Chemi-
cal Co.).
  5. Reagents
  5.1  Potassium hydroxide-(ACS),  2% in
distilled water.
  5.2  Sulfuric acid-(ACS), concentrated.
  5.3  Methylene chloride, hexane, benzene,
petroleum ether, methanol, tetradecane-pes-
ticide quality or equivalent.
  5.4  Prepare  stock standard solutions of
TCDD and "Cl-TCDD (molecular weight
328) in a glove  box. The stock solutions are
stored in a glovebox, and checked frequent-
ly for signs of  degradation or evaporation,
especially just  prior to the preparation of
working standards.
  5.5  Alumina-basic, Woelm;  80/200 mesh.
Before use activate overnight  at 600°C, cool
to room temperature in a dessicator.
  5.6  Prepurified nitrogen gas
  6.0  Calibration
  6.1  Before using any cleanup procedure,
the analyst must process a series of calibra-
tion standards  through  the  procedure to
validate elution patterns and the absence of
interferences from reagents.
  6.2  Prepare  GC/MS  calibration  stand-
ards for the internal standard technique
that will allow  for measurement of relative
response factors of at least three CDD/
37CDD ratios.  Thus,  for  TCDDs,  at least
three TCDD/J1C1-TCDD  and TCDF/'O-
TCDF  must  be  determined.5 The   31C1-
TCDD/F  concentration  in  the  standard
should be fixed and selected  to yield a re-
producible response at the most  sensitive
setting of the mass spectrometer. Response
factors for PCDD and HxCDD may be de-
termined by measuring the response of the
tetrachloro-labelled compounds relative to
that of the unlabelled  1.2,3,4- or 2,3,7,8-
TCDD,    1,2,3,4,7-PCDD    or   1,2,3,4,7,8-
HxCDD, which are commercially available.8
                                    * JX21-labelled 2,3,7,8-TCDD  and  2.3,7,8-
                                  TCDF are  available from K.O.R. Isotopes,
                                  and Cambridge Isotopes, Inc.,  Cambridge,
                                  MA. Proper standardization requires the use
                                  of a specific labelled isomer for each conge-
                                  ner to be determined. However, the only la-
                                  belled isomers readily  available  are  31Cl-
                                  2,3,7,8-TCDD  and  J1Cl-2,3,7,8-TCDF.  This
                                  method therefore uses these isomers as sur-
                                  rogates for the  CDDs  and  CDFs. When
                                  other labelled CDDs and CDFs are avail-
                                  able, their use will be required.
                                    6 This procedure is adopted because stand-
                                  ards are not available for most of the CDDs
                                  and CDFs, and  assumes that all the con-
                                                                   Continued
                                         128

-------
Environmental Protection Agency
                        Pt. 261, App. X
  6.3  Assemble  the necessary  GC/MS ap-
paratus and establish operating parameters
equivalent to those indicated in Section 11.1
of  this  method.  Calibrate the GC/MS
system  according  to  Eichelberger,  et al.
(1975) by the  use of decafluorotriphenyl
phosphine (DPTPP). By  injecting calibra-
tion standards, establish the response fac-
tors for CDDs vs. 31C1-TCDD, and for CDFs
vs.  3K21-TCDF. The detection limit provided
in Table I should be  verified  by injecting
.015 ng of 31C1-TCDD  which should give  a
minimum signal to noise ratio  of 5 to 1 at
mass 328.
  7. Quality Control
  7.1  Before processing any samples, the
analyst should  demonstrate through the
analysis of a distilled water method blank,
that all glassware and reagents  are interfer-
ence-free. Each time a set of samples is ex-
tracted, or there is a change in reagents,  a
method blank should be processed as a safe-
guard against laboratory contamination.
  7.2  Standard  quality assurance practices
must be used with this method. Field repli-
cates must be collected to measure the pre-
cision of the sampling technique. Laborato-
ry replicates must be analyzed to establish
the precision of the analysis. Fortified sam-
ples must be analyzed to establish the  accu-
racy of the analysis.
  8.  Sample  Collection,  Preservation, and
Handling
  8.1  Grab and composite samples must be
collected in glass containers. Conventional
sampling  practices  should be   followed,
except  that  the  bottle  must not be
prewashed with sample before  collection.
Composite samples should  be  collected in
glass containers in accordance  with the re-
quirements  of  the RCRA  program.  Sam-
pling equipment must  be free of  tygon and
other potential sources of contamination.
  8.2  The samples must be  iced or refriger-
ated from the  time of collection until ex-
traction. Chemical preservatives should not
be  used  in  the  field unless more than 24
hours will elapse before delivery to the labo-
ratory. If an aqueous  sample is  taken and
the sample will not be extracted within 48
hours  of collection, the sample  should be
adjusted  to  a  pH  range  of  6.0-8.0  with
sodium hydroxide or sulfuric acid.
  8.3  All samples must be extracted within
7 days and completely analyzed within 30
days of collection.
  9. Extraction and Cleanup Procedures
  9.1  Use an aliquot of 1-10 g sample of the
chemical waste or soil to be analyzed. Soils
should be dried using a stream of prepuri-
fied nitrogen and pulverized in  a ball-mill or
 geners will show the same response as the
 unlabelled congener used as a standard. Al-
 though this assumption may not be true in
 all cases, the error will be small.
similar device. Perform this operation in a
clear area with proper hood space. Transfer
the sample to a tared 125 ml flint glass
bottle (Teflon-lined  screw cap) and deter-
mine the weight of the sample. Add an ap-
propriate  quantity  of 3*Cl-labelled 2,3,7,8-
TCDD (adjust the quantity according to the
required  minimum  detectable concentra-
tion), which is  employed as  an internal
standard.
  9.2  Extraction
  9.2.1 Extract chemical waste samples by
adding 10  ml methanol,  40 ml petroleum
ether, 50 ml doubly distilled water, and then
shaking the mixture for 2 minutes. Tars
should be completely dissolved in any of the
recommended  neat   solvents.  Activated
carbon samples must be extracted with ben-
zene using  method  3540  in SW-846  (Test
Methods for Evaluating Solid Waste—Physi-
cal/Chemical  Methods,   available  from
G.P.O. Stock  #055-022-81001-2).  Quantita-
tively transfer the  organic extract or  dis-
solved sample to a clean 250 ml flint glass
bottle (Teflon lined  screw cap), add 50 ml
doubly distilled water and shake for 2 min-
utes. Discard the aqueous layer and proceed
with Step 9.3.
  9.2.2 Extract  soil  samples by adding 40
ml  of petroleum ether to  the  sample,  and
then shaking for 20 minutes. Quantitatively
transfer the organic extract to a clean 250
ml  flint  glass bottle (Teflon-lined  screw
cap),  add  50 ml doubly distilled water  and
shake for  2 minutes. Discard  the aqueous
layer and proceed with Step 9.3.
  9.3  Wash the organic layer with 50 ml of
20% aqueous potassium hydroxide by shak-
ing for 10 minutes and then remove and dis-
card the aqueous layer.
  9.4  Wash the organic layer with 50 ml of
doubly distilled water by shaking for 2 min-
utes, and discard the aqueous layer.
  9.5  Cautiously add 50 ml  concentrated
sulfuric acid  and shake  for  10  minutes.
Allow the mixture to stand until layers  sep-
arate  (approximately  10  minutes),   and
remove  and discard  the acid layer. Repeat
acid washing until no color is visible in the
acid layer.
  9.6  Add 50 ml of doubly distilled water to
the organic extract and shake for 2 minutes.
Remove and discard the aqueous layer  and
dry the organic layer by adding lOg of anhy-
drous sodium sulfate.
  9.7  Concentrate the extract to incipient
dryness by heating  in a  55° C water bath
and simultaneously flowing a stream of  pre-
purified nitrogen over the extract. Quanti-
tatively transfer the residue to an alumina
microcolumn fabricated as follows:
  9.7.1  Cut off the  top section of a 10 ml
disposable Pyrex pipette at the 4.0 ml mark
and insert a plug of silanized glass wool into
the tip of  the lower portion of the pipette.
                                         129

-------
 Pt. 261, App. X
          40 CFR Ch. I (7-1-92 Edition)
  9.7.2  Add  2.8g of Woelm  basic alumina
 (previously  activated at 600° C  overnight
 and then cooled to room temperature in a
 desiccator just prior to use).
  9.7.3  Transfer  sample extract with  a
 small volume of methylene chloride.
  9.8 Elute the microcolumn with 10 ml of
 3% methylene chloride-in-hexane followed
 by 15 ml of 20% methylene chloride-in-
 hexane and  discard these  effluents.  Elute
 the  column with 15 ml  of 50% methylene
 chloride-in-hexane and concentrate this ef-
 fluent (55° C water bath, stream of prepuri-
 fied nitrogen) to about 0.3-0.5 ml.
  9.9 Quantitatively  transfer the residue
 (using methylene chloride to rinse the con-
 tainer)  to a silanized Reacti-Vial (Pierce
 Chemical Co.). Evaporate, using a stream of
 prepurified  nitrogen,  almost to  dryness,
 rinse the walls of the vessel with approxi-
 mately 0.5 ml methylene chloride, evaporate
 just to dryness, and tightly cap the  vial.
 Store the vial at 5° C  until analysis, at
 which time  the sample is reconstituted by
 the addition of tridecane.
  9.10 Approximately 1  hour before  GC-
 MS (HRGC-LRMS) analysis, dilute the resi-
 due in the micro-reaction vessel with an ap-
 propriate quantity  of   tridecane. Gently
 swirl the tridecane on the lower portion of
 the vessel to ensure dissolution of the CDDs
 and  CDFs. Analyze a sample by GC/EC to
 provide insight into  the  complexity of the
 problem, and to determine the manner in
 which the  mass spectrometer should be
 used. Inject an appropriate aliquot of the
 sample into the GC-MS instrument, using a
 syringe.
  9.11  If, upon preliminary GC-MS analy-
 sis, the sample appears to contain interfer-
 ing substances which obscure the analyses
 for  CDDs and  CDFs,  high performance
 liquid chromatographic (HPLC) cleanup of
 the extract is accomplished, prior to further
 GC-MS analysis.
  10. HPLC Cleanup Procedure'
  10.1   Place approximately 2 ml of hexane
 in  a 50 ml flint glass sample bottle  fitted
 with a Teflon-lined cap.
  10.2   At the  appropriate  retention time,
 position sample  bottle to  collect  the re-
 quired fraction.
  10.3   Add 2 ml of 5% (w/v) sodium car-
 bonate to the sample fraction collected and
 shake for one minute.
  10.4   Quantitatively  remove the  hexane
 layer (top layer) and transfer to  a micro-re-
 action vessel.
  10.5   Concentrate the fraction to  dryness
 and retain for further analysis.
  11. GC/MS Analysis
  11.1  The following column conditions are
 recommended: Glass capillary column condi-
 tions: SP-2250 coated on a 30 m  long x 0.25
 mm I.D. glass column (Supelco No. 2-3714,
 or equivalent) with helium carrier gas at 30
 cm/sec linear velocity, run splitless. Column
 temperature  is 210*C. Under these condi-
 tions the retention time for TCDDs is about
 9.5 minutes. Calibrate the system  daily
 with, a minimum, three injections of stand-
 ard mixtures.
  11.2  Calculate response factors for stand-
 ards relative  to 3Kfl-TCDD/F (see  Section
 12).
  11.3  Analyze samples with selected ion
 monitoring of at least  two ions from Table
 3. Proof of the presence of CDD or CDF
 exists if the following conditions are met:
  11.3.1 The retention time of the peak in
 the sample must match that in  the stand-
 ard, within the performance specifications
 of the analytical system.
  11.3.2 The  ratio  of  ions  must agree
 within  10% with that of the standard.
  11.3.3 The retention time  of  the  peak
maximum for the ions of interest must ex-
 actly match that of the peak.
TABLE 3—LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING, Low
  RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
  AND HEXACHLORINATED DIBENZO-P-DIOXINS AND DIBENZOFURANS


Class ol chlorinated dtoenzodioxin or dbenzofuran

Tetra 	 	





Number
of
chlorine
substit-
uents(x)

4





Monitored m/z
for
dibenzodioxjns
CUH.-.OII,

i 4iQ fio?
321.894
'327.885
'256.933
* 258.930

Monitored m/z
for
dibenzofurans
CijH»-»OdB

1 WV9OH9
305.903
'311.894


Approxi-
mate
theoretical
ratio
expected
on basis of
tsotopic
abundance

1.00

0.21
0.20
  1 For cleanup see also method #8320 or
#8330. SW-846, Test Methods for Evaluat-
ing Solid Waste, Physical/Chemical Meth-
ods (1982).
                                       130

-------
Environmental Protection Agency
                        Pt. 261, App. X
TABLE 3—LIST OF ACCURATE MASSES MONITORED USING GC SELECTED-ION MONITORING, Low
  RESOLUTION, MASS SPECTROMETRY FOR SIMULTANEOUS DETERMINATION OF TETRA-, PENTA-,
  AND HEXACHLORINATED DIBENZO-/P-DIOXINS AND DIBENZOFURANS—Continued


Class of chlorinated dibenzodioxin or dibenzofuran

Penta

Hexa


Number
nf
chlorine
substit-
uents (x)

5

6


Monitored m/z
for
dibenzodioxins
C,2H8-,021,

1 353 858
355.855
389 816
391.813

Monitored m/z
for
dibenzofurans
C12H8-XOC1,

1 337 863
339.860
373 821
375.318
Approxi-
mate
theoretical
ratio
expected
on basis of
isotopic
abundance
057
1.00
1 00
0.87
  1 Molecular ion peak.
  2 Cl,—labelled standard peaks.
  3 Ions which can be monitored in TCDD analyses for confirmation purposes.
  11.4  Quantitate the CDD and CDF peaks
from  the response relative  to  the   "C1-
TCDD/P  internal standards. Recovery  of
the internal standard  should  be  greater
than 50 percent.
  11.5  If a response is obtained for the ap-
propriate set of ions,  but is outside the ex-
pected ratio, a co-eluting impurity  may  be
suspected. In this case,  another set of ions
characteristic  of  the  CDD/CDP molecules
should be analyzed.  For TCDD  a good
choice of ions is m/e  257 and m/e 259. For
TCDF a good choice of  ions is m/e  241 and
243. These ions are useful in characterizing
the molecular structure to TCDD or TCDF.
For analysis of TCDD good analytical tech-
nique would require using all four ions, m/e
257, 320, 322, and 328, to verify detection
and signal to noise ratio of 5 to 1. Suspected
impurities such as DDE, DDD, or PCB resi-
dues can be confirmed by checking for their
major fragments. These materials can be  re-
moved by the cleanup columns. Failure to
meet  criteria  should be  explained  in the
report, or the sample reanalyzed.
  11.6  If broad background interference  re-
stricts the sensitivity  of the GC/MS analy-
sis, the analyst should employ cleanup pro-
cedures and reanalyze by GC/MS. See sec-
tion 10.0.
  11.7  In those circumstances where these
procedures do not yield a definitive conclu-
sion, the use of high resolution mass spec-
trometry is suggested.
  12. Calculations
  12.1  Determine the concentration of indi-
vidual compounds according to the formula:
   Concentration,
                                AxAs
                              GxAlsxRf
A = >ig of  internal standard added to the
   sample 8
G = gm of sample extracted
As=area of characteristic ion of the com-
   pound  being quantified.
Ais=area of characteristic ion  of the inter-
   nal standard
R,=response factor 9
 Response factors are calculated using data
obtained from the analysis of standards ac-
cording to the formula:
                    AsxCis
              Rf
where:
Cis=concentration of the internal standard
Cc = concentration  of  the standard  com-
   pound
  12.2  Report  results in micrograms  per
gram without correction  for recovery data.
When duplicate and spiked samples are ana-
lyzed, all data obtained should be reported.
  12.3  Accuracy and Precision. No data are
available at this time.

[50 FR 2001, Jan. 14,1985]
where:
  8 The  proper amount of standard to be
used  is  determined from the  calibration
curve (See Section 6.0).
  9 If   standards   for   PCDDs/Fs   and
HxCDDs/Fs are not available, response fac-
tors for ions derived from these congeners
are calculated relative to 3'C1-TCDD/F. The
analyst may use response factors for 1,2,3,4-
or   2.3.7.8-TCDD,    1,2,3,4,7-PeCDD,   or
1,2,3,4,7,8-HxCDD  for   quantitation  of
TCDDs/Fs,  PeCDDs/Fs and  HxCDDs/Fs,
respectively. Implicit in this requirement is
the assumption that  the same  response is
obtained from PCDDs/Fs ccontaining the
same numbers of chlorine atoms.
                                        131

-------
Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                                       Form Approved, OMB No. ZO50-0028 Expires 9-30-96
                                                                                         QSA No. 0248-EPA-OT
 Please referto the//tttruofftms
 tor Flttlttg Notification before
 completing this torn, 'the
 information requested hera is
 required by law (Section 30W
 of t ha Resource Conservatfon
 and Recovery Act), ",-/%K
"    '     ' * •"""''
   Notification  of  Regulated

   ;         Waste Activity
•^  " ', ''->- -•   ' .>,:..,r • f, •,    *    '•',',,•',  * ,-    '  "',
^UnlfetfStaie* irtvtorjiriental Protection Agency
                                                                                     Date Received
                                                                                 (For Official Use Only)
 I. Installation's EPA ID Number (Mark 'X'In the appropriate box)
 H. Name of Installation (Include company and specific site 01000)
 Ml. location of tnataOa&m (Physical address not P.O. Box or Route Number)
                                                                         C. Installation's EPA ID Number
                                                                               23pCode
 County Code
A' ''t-
County Name .
 IV. (nsialteaon Mafllng Atfciress (See Instructions)
                                                                              J<—»  •"--  i •"' ^x <, ^ ----^ ' y^/ '-- ^ •• <*&.£, *tf -S> ' }fi-Sj> \ V /y J Xi" ^-4v •*% V^' '''*•'
                                                                               2lD Cocte *', *i^* - ''^v '**$ v/-">-- r-, -; >-^^-^ ^ "r».
                                                                              ^"V«rX-^^^^T^"- '•>• ftX''™.. '% vj A"* *' '^--.^ i V "^X?"/'^^-'-:-*^-"'^ -; *• *
                             to be c^tacted regarding waste actfvlttes at site)
                                                           Ptwne Number (Area C^
4 Name of ln«taitatk)n'g tajpa Owner
Street P-O. Box, of Route Number
                                                                      Slate
rt»or^|Kin^l(^^^ffi
                                                8. Land Type
                                               C. Owner Type
                                 D.

                                 Yes
(Date Changed)
                                                                                                        tr
EPA Form 8700-12 (Rev. 11-30-93) Previous edition is obsolete.
                                                                                    Continued on Reverse

-------
 Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                                                       Form Approved, OMB Ho. 2050-0028 Expires 9-30-96
                                                                                                         QSA No. 0246-EPA-OT
  VIII. Type of Regulated Waste Activity (Mark 'X'ltt O» appropriate boxes; Refer to Instructions)
                                                                                    ID • For Off icial Use Only
                           A. Hazardous Waste Activity
                                                                                    B. Used CHI Recyc ling Activities
 1.  Generator (See Instructions)      ,     D &
Q  a. Greater than f OOOko/mo (2^200 IDS.)
    Bb. 100 to 1000 kg/mo (200-2,200 Ibs.)
    c.iess than 100 kg/mo (220 H»)   .-
 2,  Transporter(fndlcateModetnboxes1-5  >   4*
    below)      '   >,     >   -<
    a. For own waste only     !   •   '
    b. For commercial purposes
   |y!o& of Transportation
       If.AIr     '
                                                Treater, Storer, Disposer {at
                                                Installation} Note: A permit is
                                                required for 81(9 activity; see
                                                instructions.    *       >
                                                Hazardous Waste Fuel  ' ' ,'
                                                a. Generator Marketing to Burner
                                                b. Other Marketers
                                                c. BolteranoYorlrKlustrfelFumace
                                                    1. Smelter Deferral
                                                    2. Small Quantity Exemption
                                                Indicate Type of Combination
                                                   .
B
       3-Hlgnway
       4, Water
       S. Other ~apeclfy
                                                    §1, Utility Bofler
                                                    2. mdustrtat Bolter
                                                    3, industrial Furnace
                                         U 5.  Underground Injection Control
                                        1, Used Oil Fuel Marketer
                                        Qa. Marketer Directs Shipment of Used
                                           •  Oil to Off-Specification Burner
                                        D*». Marketer Who First Claims the Used
                                             Oil Meets the Specifications
                                        2, Used Oil Burner - Indicate Type(s} of
                                           Combustion Devtee(s)
                                           a. Utility Bolter          ;
                                           b. Industrial Boiler
                                        	c. Industrial Furnace
                                        3. Used 0« Transporter - Indicate Type(s)
                                           otAc«vfty(ies)    :,
                                           Ba. Transporter            '  .
                                           b, Transfer Factttty
                                        4 Used OB Processor/Re-refiner«indicate
                                           Type(s)ofActivlty(tea)
                                           Ba. Process          :   '
                                           b, Re-refine
  IX. Description of Hazardous Wastes (Use additional afieata If necessary)
 A. Characteristics of Nonlisted Hazardous Wastes. (Mark 'X' In the boxes corresponding to the characteristics of
    nonllsted hazardous wastes your Installation handles; See 40 CFR Parts 26130 • i

l.lgnltabte     ICwroulwj
            V  ***S0
                              (DM3}
ChafadwteUc  (U« specific EPA hazartww wart*
  B. Listed Hazardous Wastes. (See 40 CFR 281.31 - 33; See Instructions If you need to list more than 12 waste codes.)
  C. Other Wastes.  (State or other wastes requiring a handler to have an I.D. number; See Instructions.)
  X. Certification
  I certify under penalty of law that this document and all attachments were prepared under my direction or supervision In accordance with a
  system designed to assure that qualified personnel proper lygatherandevaluatethe Information submitted. Based on my Inquiry of the person
  or persons who manage the system, or those persons directly responsible for gathering the Information, the Information submitted Is, to the
  best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information,
  Including the possibility of fine and Imprisonment for knowing violations.
  Signature
                                            Name and Official Title (Type or print)
                                                        Dale Signed
 XI. Comments
  Note: Mail completed form to the appropriate EPA Regional or State Office. (See Section III of the booklet for addresses.)
EPA Form 8700-12 (Rev. 11-30-93) Previous edition Is obsolete.

-------
 Please print or type with ELITE type (12 characters per inch) in the unshaded areas only
                                                          Foim Approved, OMB No. 2050-0028 Explms 9-30-96
                                                                            GSA No. 0246-EPA-OT
                  .                          , ,      ,    ,,   „,„,„   ,„ ,   , ,                        ,
 \ B. Listed Hazardous Wastes. (See 40 CFR 261.31 • 33; Use this page only If you need to list more than 12 waste codes.)'
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EPA Form 8700-12 (Rev. 11-30-93) Previous edition Is obsolete.

-------
                                                Notification of Regulated Waste Activity
                                   Appendix 1
            Typical Waste Streams Produced by Small Quantity Generators
LABORATORIES
Acids/Bases, Heavy Metals/Inorganics,
Ignltable Wastes, Reactives, Solvents

PRINTING AND ALLIED INDUSTRIES
Acids/Bases, Heavy Metals/Inorganics,
Ink Sludges, Spent Plating Wastes,
Solvents

PESTICIDE END USERS AND
APPLICATION
Heavy Metals/Inorganics, Services,
Pesticides, Solvents

CONSTRUCTION
Acids/Bases, Ignitable Wastes, Solvents

EQUIMENT REPAIR
Acids/Bases, Ignitable Wastes, Lead Acid
Batteries,  Solvents

FURNITURE/WOOD MANUFACTURING
& REFINISHING
Ignitable Wastes, Solvents

OTHER MANUFACTURING (textiles.
plastics, leather)
Heavy Metals/Inorganics, Solvents

LAUNDRIES AND DRY CLEANERS
Dry Cleaning Filtration, Residues,
Solvents

EDUCATIONAL AND VOCATIONAL
SHOPS
Acids/Bases, Ignitable Wastes, Pesticides,
Reactives,  Solvents
VEHICLE MAINTENANCE
Acids/Bases, Heavy Metals/Inorganics,
Ignitable Wastes, Lead Acid Batteries,
Solvents

WOOD PRESERVING
Preserving Agents

MOTOR FREIGHT TERMINALS AND
RAILROAD
Acids/Bases, Transportation, Heavy
Metals/Inorganics, Ignitable Wastes, Lead
Acid Batteries, Solvents

FUNERAL SERVICES
Solvents (formaldehyde)

METAL MANUFACTURING
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Reactives, Solvents, Spent Plating Wastes

CHEMICAL MANUFACTURERS
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Reactives, Solvents

CLEANING AGENTS AND COSMETICS
Acids/Bases, Heavy Metals/Inorganics,
Ignitable Wastes, Pesticides, Solvents

FORMULATORS
Acids/Bases, Cyanide Wastes, Heavy
Metals/Inorganics, Ignitable Wastes,
Pesticides, Reactives, Solvents
BUILDING CLEANING AND
MAINTENANCE
Acid/Bases, Solvents
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                                                 Notification of Regulated Waste Activity
                                    Appendix 2
              Typical Waste Streams and EPA Hazardous Waste Numbers
ACIDS/BASES:

Acids, bases or mixtures having a pH less than or equal to 2 or greater than or equal to
12.5, or liquids that corrode steel at a rate greater than 0.25 inches per year, are
considered to be corrosive (for a complete description of corrosive wastes, see 40 CFR
261.22, Characteristic of Corrosivity). All corrosive materials and solutions have the EPA
Hazardous Waste Number of D002. The following are some examples of the more
commonly used corrosives:
                       Examples of Corrosive Waste Streams
             Acetic Acid
             Ammonium Hydroxide
             Chromic Acid
             Hydrobromic Acid
             Hydrochloric Acid
             Hydrofluoric Acid
             Nitric Acid
Oleum
Perchloric Acid
Phosphoric Acid
Potassium Hydroxide
Sodium Hydroxide
Sulfuric Acid
DRY CLEANING FILTRATION RESIDUES:

Cooked powder residue (perchloroethylene plants only), still residues and spent cartridge
filters containing perchloroethylene or valclene are hazardous and have an EPA
Hazardous Waste Number of F002.

Still residues containing petroleum solvents with a flash point less than 140F are also
considered hazardous, and have an EPA Hazardous Waste Number of D001.

HEAVY METALS/INORGANICS:

Heavy Metals and other inorganic waste materials exhibit the characteristic of TCLP
Toxicity and are considered hazardous if the extract from a representative sample of the
waste has any of the specific constituent concentrations as shown in 40 CFR 261.24,
Table 1. This may include dusts, solutions, wastewater treatment sludges, paint wastes,
waste inks and other such materials which contain heavy metals/inorganics (note that
wastewater treatment sludges from electroplating operations containing nickel and
cyanide, are identified as F006). The following are TCLP Toxic:
Waste Stream
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
EPA Hazardous Waste
Number
D004
D005
D006
D007
D008
D009
D010
D011
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Notification of Regulated Waste Activity
                              Appendix 2 (continued)
IGNITABLE WASTES:

Ignitable wastes include any flammable liquids, nonliquids, and contained gases that
have a flashpoint less than 140F (for a complete description of ignitable wastes, see 40
CFR 261.21, Characteristic of Ignitability). Examples are spent solvents (see also
solvents), solvent still bottoms, ignitable paint wastes (paint removers, brush cleaners
and stripping agents), epoxy resins and adhesives (epoxies, rubber cements and marine
glues), and waste inks containing flammable solvents. Unless otherwise specified, all
ignitable wastes have an EPA Hazardous Waste Number of D001.

Some commonly used ignitable compounds are:
                   Waste Stream
                       Acetone
                       Benzene
                   n-Butyl Alcohol
                   Chlorobenzene
                   Cychlohexanone
                    Ethyl Acetate
                    Ethylbenzene
                     Ethyl Ether
                 Ethylene Bichloride
                      Methanol
                Methyl Isobutyl Ketone
                 Petroleum Distillates
                       Xylene
EPA Hazardous Waste
      Number
        F003
        D001
        F003
        F002
        F003
        F003
        F003
        F003
        D001
        F003
        F003
        D001
        F003
INK SLUDGES CONTAINING CHROMIUM AND LEAD:

This includes solvent washes and sludges, caustic washes and sludges, or waster washes
and sludges from cleaning tubs and equipment used in the formulation of ink from
pigments, driers, soaps, and stabilizers containing chromium and lead. All ink sludges
have an EPA Hazardous Waste Number of K086.

LEAD ACID BATTERIES:

Used lead acid batteries should be reported on the notification form only if they are not
recycled. Used lead acid batteries that are recycled do not need to be counted in
determining the quantity of waste that you generate per month, nor do they require a
hazardous waste manifest when shipped off your premises. (Note: Special requirements
do apply if you recycle your batteries on your own premises - see 40 CFR Part 266.)
Waste Stream
Lead Dross
Spent Acids
Lead Acid Batteries
EPA Hazardous Waste
Number
D008
D002
D008, D002
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                                                 Notification of Regulated Waste Activity
                              Appendix 2 (continued)
ORGANIC WASTES:

See Section VTV, Table 1 - Maximum Concentration of Contaminants for the Toxicity
Characteristic for a list of constituents and regulatory levels.

PESTICIDES:

Pesticides, pesticide residues, washing and rinsing solutions and dips which contain
constituent concentrations at or above Toxicity Characteristic regulatory levels (see
Section VTV) are hazardous wste. Pesticides that have an oral LD50 toxicity (rat) < 50
mg/kg, inhalation LC50 toxicity (rat) < 2 mg/L or a dermal LD 50 toxicity (rabbit)
< 200 mg/kg, are hazardous materials. The following pesticides would be hazardous
waste if they are technical grade, unused and disposed. For a more complete listing, see
40 CFR 261.32-33 for specific listed pesticides, discarded commercial chemical products,
and other wastes, wastewaters, sludges, and by products from pesticide production.

(Note that while many of these pesticides are no longer in common use, they are Included
here for those cases where they may be found in  storage.)
                    Waste Stream
                       Aldicarb
                       Aldrin
                       Amitrole
                  Arsenic Pentoxlde
                   Arsenic Trioxide
                    Cacodylic Acid
            Carbamic Acid, Methylnitroso-
                     Ethyl Ester
                      Chlordane
                   Copper Cyanides
             1,2-Dibromo-3-Chloropropane
                 1,2-Dichloropropane
                 1,3-Dichloropropene
            2,4-Dichlorophenoxy Acetic Acid
                        DDT
                       Dieldrin
                     Dimethoate
             Dimethylcarbamoyl Chloride
                     Dinitrocresol
                       Dinoseb
          Disodium Monmomethane arsonate
                      Disulfoton
                     Endosulfan
                       Endrin
                Ethylmercuric Chloride
                      Famphur
                     Nepthachlor
                  Hexachlorobenzene
EPA Hazardous Waste
       Number
        P070
        P004
        U011
        P011
        P012
        U136

        U178
        U036
        P029
        U066
        U083
        U084
        U240
        U061
        P037
        P044
        U097
        P047
        P020
        D004
        P039
        P050
        P051
        D009
        P097
        P059
        U127
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Notification of Regulated Waste Activity
                              Appendix 2 (continued)
                   Waste Stream
                       Kepone
                       Lindane
             2-Methoxy Mercuric Chloride
                    Methoxychlor
                  Methyl Parathion
            Monosodium Methanearsonate
                       Nicotine
                      Parathion
               Pentachloronitrobenzene
                  Pentachlorophenol
                Phenylmercuir Acetate
                       Phorate
                     Strychnine
           2,4,5-Trichlorophenoxy Acetic Acid
        2-(2,4,5-Trichlorophenoxy)-Propionic Acid
                   Thallium Sulfate
                       Thiram
                     Toxaphene
                       Warfarin
                                                   EPA Hazardous Waste
                                                          Number
U142
U129
D009
D014
P071
D004
P075
P089
U185
U242
D009
P094
PI 08
U232
U233
P115
U244
P123
U248
 SOLVENTS:

 Spent solvents, solvent still bottoms or mixtures containing solvents are often hazardous.
 This includes solvents used in decreasing and paint brush cleaning, and distillation
 residues from reclamation. The following are some commonly used hazardous solvents
 (see also ignitable wastes for other hazardous solvents, and 40 CFR 261.31 for most
 listed hazardous waste solvents):
Waste Stream
Benzene
Carbon Disulflde
Carbon Tetrachloride
Chlorobenzene
Cresols
Cresylic Acid
O-Dichlorobenzene
Ethanol
Ethylene Dichloride
Isobutanol
Isopropanol
Kerosene
Methyl Ethyl Ketone
EPA Hazardous Waste
Number
D001
F005
F001
F002
F004
F004
F002
D001
D001
F005
D001
D001
F005
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                                                 Notification of Regulated Waste Activity
                              Appendix 2 (continued)
                    Waste Stream
                 Methylene Chloride

                      Naphtha
                    Nitrobenzene
              Petroleum Solvents (Flash-
                 point less than 14OF)
                      Pyridine
                1,1, 1-Trichloroethane

                 Tetrachloroethylene

                      Toluene
                  Trichloroethylene

                Trie hlorofluoromethane
                Trichlorotrifluoroethane
                    White Spirits
EPA Hazardous Waste
       Number
    F001 (Sludges)
  F002(Still Bottoms!
        D001
        FO04

        D001
        F005
    F001 (Sludges)
  F002(Still Bottoms)
    F001 (Sludges)
  F002 (Still Bottoms)
        F005
    F001 (Sludges)
  F002(Stlll Bottoms)
        F002
        F002
        DO01
REACTIVES:

Reactive wastes include reactive materials or mixtures which are unstabe, react violently
with or form explosive mixtures with water, generate toxic gases or vapors when mixed
with water (or when exposed to pH conditions between 2 and 12.5 in the case of cyanide
or sulflde bearing wastes), or are capable of detonation or explosive reaction when
irritated or heated (for a complete description of reactive wastes, see 40 CFR 261.23,
Characteristic of reactivity). Unless otherwise specified, all reactive wastes have an EPA
Hazardous Waste Number of D003. The following materials are commonly considered to
be reactive:
Waste Stream
Acetyl Chloride
Chromic Acid
Cyanides
Organic Peroxides
Perchlorates
Permanganates
Hypochlorites
Sulfldes
EPA Hazardous Waste
Number
D003
D003
D003
D003
D003
D003
D003
D003
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 Notification of Regulated Waste Activity
                              Appendix 2 (continued)
 SPENT PLATING AND CYANIDE WASTES:

 Spent plating wastes contain cleaning solutions and plating solutions with caustics,
 solvents, heavy metals and cyanides. Cyanide wastes may also be generated from heat
 treatment operations, pigment production and manufacturing of anti-caking agents.
 Plating wastes are generally Hazardous Waste Numbers F006-F009. Heat treatment
 wastes are generally Hazardous Waste Numbers F010-F012. See 40 CFR 261.31 for a
 more complete description of plating wastes.

 WOOD PRESERVING AGENTS:

 Compounds or mixtures used in wood preserving, including the wastewater treatment
 sludge from wastewater treatment operations, are considered hazardous. Bottom
 sediment sludges from the treatment of wastewater processes that use creosote or
 pentachlorophenol are hazardous, and have an EPA Hazardous Waste Number of K001.
 Unless otherwise indicated, specific wood preserving components are:
Waste Stream
Chromated Copper Arsenate
Creosote
Pentachlorophenol
EPA Hazardous Waste
Number
D004
K001
K001
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