EFV\
Untt«d
Environmental Protection
Agwicy
OH KM of
PwtictdM and
WMturxrtonDC 20460
March 1986
PMiekiM
Guidance for the
Reregistration of
Pesticide Products
Containing Copper sulfate
as the Active Ingredient
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GUIDANCE FOR THE
REREGISTRATION OF PESTICIDE PRODUCTS
CONTAINING
AS THE ACTIVE INGREDIENT
COPPER SULFATE
CASE NUMBER: 0636
CAS NUMBER; 1344-73-6
ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF PESTICIDE PROGRAMS
WASHINGTON, D.C. 20460
/
MARCH 1986
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TABLE OF CONTENTS
Introduction
I. Regulatory Position and Rationale
II. Requirement for Submission of Generic Data
III. Requirement for Submission of Product-Specific
Data ............ ............. 37
IV. Submission of Revised Labeling ............ 3&
A. Label Contents .................. 3?
B. Collateral Information Labeling .......... ^
V. Instructions for Submission .............. ^5
APPENDICES
1-1 EPA Index to Pesticide Chemicals .......... 50
II-l Guide to Bibliography ............... 196
II-2 Bibliography .................... 198
II-3 FIFRA §3(c)(2)(E) Summary Sheet - EPA Form 8580-1 .202
II-4 Certification of Attempt to Enter Into an Agreement
with Other Registrants for Development of Data
EPA Form 8580-2 ................. ' -203
III-l Product Specific Data Report (End-Use Products) .20^
IV-i 40 CFR 162.10 Labeling Requirements ....... 206
IV-2 Table of Labeling Requirements .......... 218
' IV-3 Physical/Chemical Hazards Labeling Statement. . .221
IV-4 Storage and Disposal Instructions ........ 222
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INTRODUCTION
The Federal Insecticide, Fungicide, and Rodenticide Act
(FIFRA sec. 3(g)) directs EPA to reregister all pesticides as
expeditiously as possible.
To carry out this task, EPA has established the Regis-
tration Standards program, which will review all pesticide
products containing active ingredients first registered before
January 1, 1977. Pesticides will be reviewed in use clusters
which have been ranked to give earliest review to pesticides
used on food ana feed crops.
The Registration Standards program involves a thorough
review of the scientific data base underlying pesticide
registrations and an identification of essential but missing
studies which may not have been required when the product
was initially registered or studies that are now considered
insufficient. EPA's reassessment results in the development
of a regulatory position, contained in a Registration Standard,
on each pesticide and its uses. The Agency may require the
registrant to modify product labels to provide additional
precautionary statements, restrict the use of the pesticide
to certified applicators, provide reentry intervals, modify
uses or formulation types, specify certain packaging limitations,
or other requirements to assure that proper use of the pesticide
will not result In unreasonable adverse effects on the environment
The scientific review, which is not contained in this
Guidance Package but is available upon request, concentrates
on the technical grade of the active ingredient and identifies
missing generic data. However, during the review of these
data we are also looking for potential hazards that may be
associated with the end use (formulated) products that contain
the active ingredient. If we have serious concerns, we will
address end use products as part of the Registration Standards
program and will propose regulatory actions to the extent neces-
sary to protect the public.
EPA has the authority under PIPRA sec. 3(c)(2)(B) to
require registrants to submit data that will answer our
questions regarding the hazard that may result from the
intended use of a pesticide. Although sec. 3(c)(2)(B) provides
that all registrants are responsible for these data, the
Agency generally imposes generic data requirements only on the
registrants of the manufacturing use products (basic suppliers
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of the active ingredient) and other producers who do not
qualify for the formulator's exemption.*
A producer who wishes to qualify for the forraulator's
exemption may change his source of supply to a registered
source, provided the source does not share ownership in
common with the registrant's firm. A registrant may do so
by submitting a new Confidential Statement of Formula, EPA
Form 8570-4, identifying the registered source of the active
ingredient, to the appropriate Product Manager within 90
days of receipt of this Guidance Document. The chart on the
following page shows what is generally required of those who
do and do not qualify for the formulator's exemption in the
Registration Standards program.
If you decide to request the Agency to cancel the regis-
tration of any of your products subject to the requirements
of this Guidance Document, please notify the Product Manager
named in the cover letter, within 90 days from the receipt
of this document. If you decide to maintain your product
registration(s), you must provide the information described in
the following pages within the timefraraes outlined. The Agency
may issue a notice of intent to cancel or suspend the registratio:
of any currently registered product which does not comply
with the requirements set forth in this Guidance Document.
You are reminded that FIFRA sec. 6(a)(2) requires you to
submit factual information raising concerns of possible
unreasonable adverse effects of a pesticide. You should
notify the Agency of interim results of studies in progress
if those results show possible adverse effects.
*The formulator's exemption applies to a registrant of an
product if the source of his active ingredient(s.): (1) is a
registered product and (2) is purchased from a source which
does not have ownership in common with the registrant's
firm.
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PRODUCTS SUBJECT TO THE
REGISTRATION STANDARDS PROGRAM
ACTION(S) REQUIRED TO
MAINTAIN REGISTRATION
I. Products That Do Not Qualify
For The Formulator's Exemption
A. Single Active Ingredient
Products*
These products must be reregis-
tered. To obtain rereglstration
labeling, packaging and data
requirements must be satisfied
in accordance with the Regis-
tration Standards Guidance
Document.
> I
E. Multiple Active
Products
Ingredient
These products will not be
reregistered at this time.
However, generic data required
to continue the registration of
the active ingredient under
review, as described in the
Registration Standards Guidance
Document, will be required and
some labeling precautions may
also be required.
II. Products That Do Qualify Foi
The Formulator's Exemption
Only when additional restric-
tions or labeling are needed to
protect man or the environment
will these products be subject
to the Registration Standard
requirements. Affected products
will be dealt with in a variety
of ways, including but not
limited to the Label Improvemerr
Program and special intent
to cancel notices.
* End use products of registrants who also produce a manufacturing
use product will not be required to be reregistered provided that
registrant 'fulfills the requirements specified in the Guidance
Document for manufacturing use product(s). Such end use products
will be subject to the labeling changes required for products in "II"
above. If there are no manufacturing use products registered by any
company end use products will be required to be reregistered.
NOTE: If all registrants in "I" above fail to meet the requirements i:
I-A and E above, then the registrants in "II" lose their right to
qualify for the formulator's exemption and become subject to the
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I. REGULATORY ASSESSMENT
A. INTRODUCTION
This Registration Standard describes the regulatory position and
rationale for all registered manufacturing-use products (MPs)
containing, copper sulfate as the sole active ingredient. This
Standard also will require significant changes on the labels of
some other EPs. The Agency bases its position and rationale on an
evaluation of all MPs, EPs, and Section 3, 24(c) and intrastate
uses registered for copper sulfate. After briefly describing the
chemical and its uses, this chapter presents the regulatory position
and rationale, the criteria for registration, acceptable ranges
and limits, labeling considerations and tolerance reassessment.
B. DESCRIPTION OF THE CHEMICAL
Copper sulfate is the common name developed through long usage and
the name used in this Standard to represent the active ingredient
in the pentahydrate, monohydrate and basic copper sulfate forms.
Other names for the pentahydrate are bluestone, blue vitriol,
Salzburg vitriol, Roman vitriol, and blue copperas. Basic copper
sulfate is marketed under various trade names, Including BSC Copper
Fungicide, CP Basic Sulfate, and Tri-Basic Copper Sulfate. The
Chemical Abstracts Service (CAS) number for .copper sulfate is
13M4-73-6 and the EPA Chemical Code number is 024401 for the
pentahydrate form, 024402 for the monohydrate form, and 008101 for
basic copper sulfate.
Copper sulfate is an odorless blue or green-white powder or crystalline
solid. The empirical formula is CuS04-5H20 (pentahydrate):
CuS04.H20 (monohydrate) and CuSOu (anhydrous). The molecular
weight is 249.69 (pentahydrate);'177.62 (monohydrate); and 159-61
(anhydrous). Upon heating, the pentahydrate form loses 4 mol H2C
at 110°C and all 5 mol ^0 at 250°C. The resulting anhydrous forr;
is stable up to 650°C.
Solubility of copper sulfate pentahydrate is 31-6 g/100 cc at 0°C
and 203-3 g/100 cc at 100°C in water and 15-6 g/100 cc at 18°C in
methanol. For the anhydrous form, solubility in water is
14.3 g/100 cc at 0°C and 75.4 g/100 cc at 100°C; in methanol solubility
is 1.04 g/100 cc at 18°C. Both forms are insoluble in ethanol.
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Formulations of basic copper sulfate include a 53 percent technical,
dusts ranging in concentration from 2.0 to 52.0 percent a.i.,
wettable powders ranging in concentration from 4.0 to 53 percent
a.i., and fluid concentrates ranging from 0.11 to 4.24 Ib a.i ../gallon.
Formulations of copper sulfate monohydrate include 10 to 20 percent
a.i. dusts, an 11 percent a.i. granular and a 27.7 percent a.i.
soluble concentrate. Formulations of copper sulfate pentahydrate
include 15, 99, and 99-5 percent a.i. technical products, a 50
percent a.i. formulation intermediate, 20 and 75 percent a.i.
granulars, crystalline formulations ranging from 93.75 to 100
percent a.i., soluble concentrate/solids ranging from 25.5 to 99
percent a.i., soluble concentrate/liquids ranging from 8.5 to
15.1 percent a.i., and ready to use products ranging from 0.76
•to 15.0 percent a.i..
Basic copper sulfate is registered as an herbicide and a fungicide.
Registered sites for herbicidal use include pecans, live oak,
ornamental woody shrubs, and ornamental and/or shade trees.
Registered sites for fungicidal use are too numerous to list here,
but are listed in the attached Index of Pesticidal Uses. Copper
sulfate monohydrate is registered (as a combination with hydrated
lime) as a fungicide for application to numerous agricultural crops.
Copper sulfate pentahydrate is registered as an algicide, a
mollusciciae an agricultural fungicide when used with lime, and
as an industrial fungicide when used alone. Registered sites
for the molluscicidal use include freshwater aquaria, artificially
impounded water and rice paddies. Registered agricultural sites
for the fungicidal use are too numerous to list here, but are
listed in the attached Index of Pesticidal Uses. Non-agricultural
sites for the pentahydrate used alone include wood,.sewer syste.-.s,
papermills, and cooling towers.
Copper sulfate is active against a range of foliar pathogens th=:
attack fruits and vegetables. It is generally less effective
than most widely available organic protectants and systemic
fungicides. Copper sulfate has some limited activity against
bacterial pathogens. One of the limiting factors in the use of
copper compounds is their serious potential for phytotoxicity.
The mode of action involves the inactivation of most fungal
enzyme systems and protein precipitation. An excess of copper
sulfate kills algae by causing an imbalance with other enzyme
metal cofactors resulting in enzyme blockage.
An estimated 8,295,000 pounds (a.i.) of copper sulfate and
hydrates are used annually in the United States. Of the total
amount of all types of copper sulfate applied in the United
States in 1982, approximately 36% and 2655 were applied to oranges
and tomatoes, respectively. Between 1 and 10 percent were applied
to walnuts, grapefruits, almonds, pears, lemons, potatoes,
tobacco, and grapes. Less than one percent was applied to peaches,
cherries, beans/peas, peanuts, applies, rice, sugarbeets, lettuc-.
pecans, olive, nectarines, plums, cauliflower, apricots, strawberr^ci,
onions, celery, and wheat. Approximately 18,000 Ibs a.i. are
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used annually for algae control and 15,000 Ibs a.i. for control
of vegetation on rights-of-ways.
The method of application of copper sulfate depends on the formulation
and use. For ground applications, equipment varies from dusters to
boom scrayers and airblast applicators. For homeowner use, hand
held equipment such as compressed air sprayers, and paint brushes
are used. For use in impounded waters, lakes, ponds, reservoirs
and irrigation and drainage conveyance systems, application may
be by spraying or dusting the water surface or towing a burlap
bag of large crystals behind a boat, by dumping large crystals,
by continuously metering finer crystals into flowing water by a
specially designed feeder, or by aerial application. Application
rates range from 0.0013 to 10.0 ppm for aquatic uses and from
0.24 to 21.2 Ib ai/A for terrestrial uses.
C. REGULATORY POSITION AND RATIONALE
Based on a review and evaluation of all available data and other
relevant information on copper sulfate, the Agency has determines the
following:
1. Manufacturing-use pesticide products containing copper sulfate
as the sole active ingredient may be registered for sale, distri-
bution, reformulation, and use, subject to the terms and conditions
of this Standard. Registrants must provide or agree to develop
additional data, as specified in Table A, in order to maintain
existing regulations or permit new copper sulfate registrations.
Rationale: The copper sulfate data base is incomplete, but the
Agency is not aware of any evidence of hazard to human health
or the environment that would warrant cancellation or suspension
of products at this time. Issuance of this Standard provides
a mechanism for identifying data needs. The required data
will be reviewed and evaluated and the Agency will determine
at that time if they will affect the registrations cf copper
sulfate.
2. The Agency does not possess laboratory toxicological data
meeting Agency standards for copper sulfate compounds. However,
there is a substantial volume of data on copper in the literature
which addresses all major biological actions. The Agency has
determined that sufficient information on toxicity of copper
sulfate is available from literature sources, and that toxicology
studies normally required for registration are not needed.
The acute toxicity of copper sulfate is adequately defined and
its metabolism in humans and animals well understood.
Rationale: Copper is ubiquitous in nature, and is a required
nutritional element for both plants and animals. It is one
cf 26 elements found essential to life. Copper is found in
the adult human body at levels of 80-150 ing. Oral ingestion
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of copper compounds is irritating to the gastric muccsa and
eraesis occurs promptly, thereby reducing the amounts of copper
available for absorption into the body. Moreover, man is
protected from excess body copper by an effective homeostatic
mechanism, which integrates absorption, retention and excretion
to stabilize the copper body burden. Only a small percentage
of copper ingested is absorbed, and most of the absorbed
copper is excreted.
3. Because of acute toxicity and sensitization characteristics,
the Agency will require registrants to place certain precautionary
statements on the labels of manufacturing-use and end-use
products containing copper sulfate. The specific language of
these statements is given in Section P of this Chapter.
Rationale: Copper sulfate is only moderately toxic upon acute
oral exposure (Toxicity Category II) and dermal exposure
(Toxicity Category II). Ocular exposure to the granular
material, however, can cause severe eye damage (Toxicity
Category I). Kypersensitivity or sensitization can result
from copper contact with the skin. Labels of certain products
should therefore contain statements that warn applicators of
copper sulfate's toxicity, give first aid instructions, and
require the use of precautionary measures such as protective
clothing and goggles.
4. The Agency will require registrants to submit additional data
on the effects of EFs containing copper sulfate on non-target
aquatic organisms. The Agency will require certain precautionary
statements to be placed on EP labels for the protection of
non-target aquatic organisms. The wording of these statements
is provided in Section F of this Chapter.
Rationale: Existing studies on technical copper sulfate shew that
it is toxic to aquatic organisms, and that indiscriminate use can
lead to reductions in populations of aquatic organisms, either
through direct tcxicity or through the oxygen depletion that
occurs when too much aquatic vegetation is killed at once.
However, the limited data before the Agency at this time does
not indicate that an unreasonable hazard to non-target aquatic
organisms exists. Data on the toxicity of EPs and their
effects en non-target aquatic organisms are needed to complete
an evaluation of the hazards posed to non-target aquatic life
by copper sulfate use. Precautionary label statements warning
of the danger to non-target aquatic organisms will mitigate
the hazard until the hazard evaluation can be completed.
5. The Agency will require that labels bear statements for the
protection of certain endangered species identified by the
Office of Endangered Species (OES), U.S. Department of the
Interior. The statements will require that applicators
consult E?A endangered species bulletins for their area before
applying copper sulfates. The wording of these label statements
7
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Rationale: The OES has determined that the use of copper sulfates
in certain areas would pose a risk to Solano Grass, the Slackwater
Darter, and several species of freshwater mussels. Requiring
applicators to consult EPA endangered species bulletins before
applying copper sulfates in those areas will minimize the
potential for exposure of those endangered species.
6. The Agency will request that the OES determine whether any
endangered species, or the habitat of any endangered species,
will be placed in jeopardy by the algicide uses of copper
sulfate. The Agency will review other uses of copper sulfate,
and, if appropriate, will refer them to OES for determinations
of Jeopardy to endangered species.
Rationale: The Agency has determined that certain use patterns,
particularly the algicide use, could pose problems for endangered
aquatic species, because of the toxicity of copper sulfate to
aquatic species. The limited data before the Agency at this
time does not indicate that any unreasonable hazard to endangered
species exists, but consultation with OES will allow the Agency
to identify any potential hazards associated with the algicide
use pattern. Agency review of the other use patterns is appropriate
in light of coppe,r sulfate fs toxicity to aquatic species.
D. CRITERIA FOR REGISTRATION UNDER THE STANDARD
To be covered under this Standard, products must contain copper
sulfate as the sole active ingredient, bear required labeling, arc
conform to the product composition, acute toxicity limits, and use
pattern requirements listed in Section £ of this document.
The applicant for registration or reregistration of manufacturing-use
products subject to this Standard must comply with all terms and
conditions described in it, including submission of an up-to-date
Confidential Statement of Formula, submission of revised labeling,
commitment to fill data gaps on the schedule specified by the Agency
and, when applicable, offer to pay compensation as required by
Sections 3(c)(l)(D) and 3(c)(2)(D) of the Federal Insecticide,
Sections 3(c)(l)(D) and 136 (c)(2)(D) of the Federal Insecticide,
Fungicide, and Rodenticide Act (FIFRA), as amended, 7 U.S.C. 136 (c; '.
and 136(c)(2)-(D). Registration applicants must contact the Agency for
specific instructions, including updated information on data
requirements and companies whose data have been used in support of
registration.
E. ACCEPTABLE RANGES AND LIMITS
1. Product Composition Standard
To be covered under this Standard, manufacturing use products
must contain copper sulfate as the sole active ingredient.
Each MP formulation proposed for registration must be fully
described with an appropriate certification of limits, stating
maximum ana minimum amounts of the active ingredient
may be present in products.
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2. Acute Tcxicity Limits
The Agency will consider registration of technical grade ana
manufacturing use products containing copper sulfate, provided
that the product labeling bears appropriate precautionary
statements for the acute toxicity category in which each
product is placed .
3. Use Patterns
To be registered under this Standard, manufacturing use
products containing copper sulfate may be labeled for formulaticr
into end use products only for the commodities listed below.
The attached index entry lists all registered uses, as well
as approved maximum application rates and frequencies.
- Terrestrial, non-domestic food uses on fruit and nut
crops, vegetable crops, and wheat seed treatment
- Terrestrial, non-domestic non-food uses on ornamentals
and tree wounds
- Aquatic, food uses on rice and cranberries
- Aquatic, non-food uses on water systems (sewer pumps and
force mains, pulp and paper mills, cooling towers, spray
ponds, pole soaking treatments, control of algae and
molluscs in lakes and ponds)
F. REQUIRED LABELING
All manufacturing-use copper sulfate products must bear appropriate
labeling as specified in 40 CFR 162.10. The guidance package
for this Standard contains information on label requirements.
All labeling changes must appear on all products released for
shipment by October 1, 1986. All labeling changes must appear or.
all products in channels of trade by October 1, 1987. In additicr.
to the above, the following information must appear on the labeling
1. Ingredient Statement
The ingredient statement for all crystalline formulations
and solutions containing copper sulfate must list the active
ingredient as one of the following:
"Copper sulfate pen tan yd rate* XXfr " :
"Copper sulfate monohydrate* XX*":
"Basic copper sulfate* XX
The ingredient statement r.ast have a footnote reading:
ccrrer ecuivalent
* 11
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2. nse Pattern Statements
All manufacturing-use copper sulfate products must state
that they are intended for formulation into end-use products
for the aforementioned use patterns. Labeling must specify
sites, which are listed in Section E.3. of this document
under Use Patterns. However, no use may be included on the
label if the registrant fails to agree to comply with the
data requirements for that use pattern, as listed in Table A.
3. Precautionary Statements
a. Labels for manufacturing-use copper sulfate products must
bear statements reflecting the compound's acute human
toxicity. Copper sulfate is in Toxicity Category I by
eye and dermal irritation routes of exposure.
The following human hazard statement, based on data reviewed
by the Agency, must appear on all MP labels, and on the
labels of all EPs in the 99% a.i. crystalline form:
"DANGER - Causes severe eye and skin irritation. Harmful if
labsorbed through the skin or inhaled. May cause skin
sensitization reactions in certain individuals. Avoid
contact with the skin, eyes, or clothing. Avoid breathing
dust. Protective clothing, including goggles, should
be worn. Wash thoroughly with soap and water after
handling. Remove contaminated clothing and wash before
reuse."
One of the following statements of practical treatment,
based on data reviewed by the Agency, must appear on all
MP labels, and on the labels of all EPs in the 99% a.i.
crystalline form, under a heading that reads either
"First Aid" or "Practical Treatment":
"IF IN EYES, flush with plenty of water. Call a physician.
IF ON SKIN, wash with plenty of soap and water. Get
medical attention. IF SWALLOWED, call a physician or
Poison Control Center. Drink 1 or 2 glasses of water and
induce vomiting by touching the back of throat with
finger. Do not induce vomiting or give anything by mouth
to an unconscious person."; or
"IF IN EYES, flush with plenty of water. Call a physician.
IF ON SKIN, wash with plenty of soap and water. Get
medical attention. IF SWALLOWED, call a physician or
Poison Control Center. Drink 1 or 2 glasses of water and
induce vomiting by touching back of throat with finger, cr,
if available, by administering syrup of ipecac. Do not
induce vc-itir.^ cr give anything by nouth to an ur.ccnscic
person."
10
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b. The following revised environmental hazard statement must
appear on all MP labels:
"This pesticide is toxic to fish and aquatic organisms.
Do not discharge effluent containing this product into
lakes, streams, ponds, estuaries, oceans, or public
water unless this product is specifically identified
and addressed in an NPDES permit. Do not discharge
effluent containing this product into sewer systems
without previously notifying the sewage treatment plant
authority. For guidance contact your State Water Board
or Regional Office of the EPA."
c. The following statements must appear on all EP labels:
i. "May cause skin sensitization in certain individuals"; and
ii . "ENDANGERED SPECIES RESTRICTIONS
It is a violation of Federal laws to use any pesticide in
a manner that results in the death of an endangered species
or adverse modification of their habitat.
The use of this product may pose a hazard to certain
Federally designated endangered species known to occur
in specific areas within the following counties:
STATE
Species
(Bulletin No.)
CALIFORNIA
Scianc Grass
(EPA/ES-85-13)
TENNESSEE
Slackwater Darter
(EPA/ES-85-04)
Freshwater Mussels
(EPA/ES -85-07)
ALABAMA
Slackwater Darter
(EPA/ES-85-05)
VIRGINIA
Freshwater Mussels
(EPA/ES-85-06)
I
COUNTY
Solano
Lawrence
Wayne
Hancock
Claiborne
Hawkins
Sullivan
Lauderdale
Limestone
Madison
Grayson
Smyth
Scott
Lee
Washington
11
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Before using this product in the above counties you must
obtain the EPA Bulletin specific to your area. This
Bulletin identifies areas within these counties where
the use of this pesticide is prohibited, unless specified
otherwise. The EPA Bulletin is available from either your
County Agricultural Extension Agent, the Endangered Species
Specialist in your State Wildlife Agency Headquarters, or
the appropriate Regional Office of the U.S. Pish and
Wildlife Service. THIS BULLETIN MUST BE REVIEWED PRIOR TO
PESTICIDE USE."
d. All copper sulfate products intended for direct application
to water must bear the following statements:
i. "This pesticide is toxic to fish. Direct application
of copper sulfate to water may cause a significant
reduction in populations of aquatic invertebrates,
plants and fish."
ii. "Do not treat more than one-half of lake or pond at or.e
time in order to avoid depletion of oxygen from decaying
vegetation. Allow 1 to 2 weeks between treatment fcr
oxygen levels to recover."
iii. "Trout and other species of fish may be killed at
application rates recommended on this label, especially
in soft or acid waters. However, fish toxicity generally
decreases when the hardness of water increases."
iv« "Do not contaminate water by cleaning of equipment cr
disposal of wastes."
v. "Consult your State Pish and Game Agency before applying
this product to public waters. Permits may be required
before treating such waters."
e. All copper s_ulfate products Intended for end use applications
to water where there is likelihood of effluent reaching
natural waters, i.e. cooling towers, paper or pulp mills,
spray ponds, sewer pumps, force mains, algicide and
molluscicide uses, must bear the following statement:
"This pesticide is toxic to fish and aquatic organisms.
Do not discharge effluent containing this product into
lakes, streams, ponds, estuaries, oceans, or public
waters unless this product is specifically identified
and addressed in an NPDES permit. Do not discharge
effluent containing this product to sewer systems without
previously notifying the sewage treatment plant authority.
For guidance contact your State Water Board or Regional
Office of the EPA."
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f. All copper sulfate products intended for end use on
terrestrial sites must bear the following statement:
"This pesticide is toxic to fish and aquatic organisms.
Do not apply directly to water. Drift and runoff from
treated areas may be hazardous to fish and aquatic
organisms in adjacent aquatic sites. Do not contaminate
water by cleaning of equipment or disposal of wastes."
G. TOLERANCE REASSESSMENT
Copper sulfate basic, monohydrate, and pentahydrate are exempt
from the requirements of a tolerance when applied to growing
crops in accordance with good agricultural practices (MO CFR
16C-'. ICCKb) (1)) . There is a specific exemption from the
requirement of a tolerance for copper in meat, milk, poultry,
eggs, fish, shellfish, and irrigated crops when copper sulfate
pentahydrate is used as an algicide or herbicide in irrigation
water systems, lakes, ponds, reservoirs or other bodies of water
(40 CFR I80.1021(a)). The Agency has reviewed these exemptions
and they appear well-founded. Copper is a required micronutrient
and is unlikely to exhibit toxic effects when individuals are
exposed to small amounts.
There are a number of factors which minimize the possibility of
exposure from dietary intake as a result of these uses of copper
sulfate. First, copper sulfate can be washed off plants by rain
and during food processing. Second, water soluble cupric ions are
rapidly adsorbed by organic matter in soils. This adsorption
immobilizes the ions before they become "fixed forms" in other
combinations, from which they would be slowly available. Most of
the copper in soil is unavailable for plant growth. Third, toxic
copper levels in plants induce an imbalance with iron, producing a
chlorosis similar to iron deficiency. This chlorosis causes plar.t
dwarfing, stunted roots and decreased growth and yield. These
effects occur before there are significant increases in plant
copper. Thus there is a "built-in" warning to applicators, which
would tend to limit excess copper application and, consequently,
residue levels. Fourth, plants resist copper accumulation and
translocation to stems, leaves or seeds. Most plants growing on
soils containing up to 1000 ppm copper showed only a slight elevatio:
in copper content compared to plants grown on normal soils. Fifth,
crop growth normally occurs at pH 6.0-6.5- At this level the soil
has a greater than normal capacity to absorb applications such as
copper. Therefore, the usual practice of liming soil to bring it
to the proper pH for crop production markedly increases its capacity
for sequestering copper ions, thus limiting acccessibility of
copper to plants.
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II. REQUIREMENT FOR SUBMISSION OF GENERIC DATA
A. This portion of the guidance document is a Notice
issued under the authority of FIPRA sec. 3(c)(2)(B). The
tables following this section list the data required for
maintaining the registrability of each product.
EPA has determined that additional generic data described
in Table A must be submitted to EPA for evaluation in order
to maintain in effect the registration(s) of your product (s)
identified as an attachment to the cover letter accompanying
this guidance document. As required by PIFRA sec. 3(c)(2)(B),
you are required to take appropriate steps to comply with
this Notice.
EPA may suspend the registration of each of those products
unless, within the specified time, you have informed EPA how
you will satisfy the requirements of this Notice. Any such
suspension will remain in effect until you have complied with
the terms of this Notice.
B. What Generic DatalZ Must be Submitted. You may deter-
mine which generic data you must submit by consulting Table A
at the end of this chapter. That table lists the generic
data needed to evaluate the continued registrability of all
products, and the dates by which the data must be submittea.
The required studies must be conducted in accordance with
EPA approved protocols (such as those contained In the Pesticide
Assessment Guidelines 2/ or data collected under the approved
protocols of the Organization for Economic Cooperation and
Development (OECD). If you do not wish to develop data
in support of certain uses appearing in your labeling, you
may delete those uses at the time you submit your revised
labeling.
For certain kinds of testing (generally ecological
effects), EPA requires the test substance to be a "typical
formulation," and in those cases EPA needs data of that type
i/ Generic data pertain to the properties or effects of a
particular ingredient, and thus are relevant to an evaluation of
the risks of all products containing that ingredient, regardless
of the product's unique composition or specific use. Product-
specific data relate only to the properties or effects of a
product with a particular composition (or a group of products
with closely similar composition).
2/ The Pesticide Assessment Guidelines are available in hard
copy or microfiche from the National Technical Information
Service, 5265 rort Royal Road, Springfield, Va. 221 cl.
-------
for each major formulation category (e.g., emulsifiable concen-
trates, wettable powders, granulars, etc.) These are classified
as generic data and when needed are specified in Table A.
EPA may possess data on certain "typical formulations" but
not others. Product-specific data are further explained in
Chapter III of this document.
C. Options Available for Complying With Requirements
to Submit Data
Within 90 days of your receipt of this Notice you must
submit to EPA a completed copy of the form entitled "FIFRA
Section 3(c)(2)(B) Summary Sheet" [EPA Form 8580-1, Appendix
II-3] for each of your products. On that form you must state
which of the following methods you will use to comply with
the requirements of this Notice:
1. (a) Notify EPA that you will submit the data, and
(b) either submit the existing data you believe will
satisfy the requirement, or state that you will generate
the data by conducting testing. If the test procedures
you will use deviate from (or are not specified in) the
Pesticide Assessment Guidelines or protocols contained in
the Reports of Expert Groups to the Chemicals Group,
Organization for Economic Cooperation and Development
(OECD) Chemicals Testing Programme, you must enclose the
protocols you will use.
OR
2. Notify EPA that you have entered Into an agreement
with one or more other registrants to jointly develop (or
share In the cost of developing) the data. If you elect
this option, you must notify EPA which registrant(s) are
parties to the agreement.
OR
3. File with EPA a completed "Certification of Attempt to
Enter Into an Agreement With Other Registrants for Develop-
ment of Data" (EPA Form 8580-6, Appendix II-4)V
V FIFRA sec. 3(c)(2)(E) authorizes joint development cf
data Fy two or more registrants, and provides a mechanism by
which parties can obtain an arbitrator's decision If they agree
to Jointly develop data but fail to agree on all the terms of
the agreement. The statute does not compel any registrant tc
agree to develop data jointly.
(Fcotr.cte continued on next page)
-------
OR
4. Request that EPA amend your registration by deleting
the uses for which the data are needed. (This option is
not available to applicants for new products.)
OR
5. Request voluntary cancellation of the registrations )
of your products for which the data are needed. (This option
is not available to applicants for new products.)
D. Procedures for Requesting Changes in Testing Methodology
and Extensions of Time
EPA recognizes that you may disagree with our conclusions
regarding the appropriate ways to develop the required data
or how quickly the data must be submitted . If the test
procedures you plan to use deviate from (or are not specified
in) the registration guidelines or protocols contained in
the reports of the Expert Groups to the Chemical Groups,
Organization for Economic Cooperation and Development (OECD)
Chemicals Testing Programme, you must submit the protocol
for Agency review prior to the initiation of the test.
If you think that you will need more time to generate the
required data than is allowed by EPA's schedule, you may
submit a request for an extension of time. The extension
request must be submitted in writing to the Product Manager.
(Footnote continued from previous page)
In EPA's opinion, joint data development by all regis-
trants subject to a data requirement or a cost-sharing agreement
among all such registrants is clearly in the public interest.
Duplication of testing could increase costs, tie up testing
facilities, and subject an unnecessarily large number of
animals to testing.
As noted earlier, EPA has discretion to suspend the
registration of a product when a registrant fails to submit data
required under PIPRA Section 3(c)(2)(B). EPA has concluded that
it should encourage Joint testing rather than duplicative
testing, and that suspension should be withheld in certain cases.
to further this goal. Accordingly, if (1) a registrant has
informed us of his intent to develop and submit data required
by this Notice; and (2) a second registrant informs EPA that
it has made a bona fide offer to the first registrant to share
in the expenses of the testing [on terms to be agreed upon
or determined by arbitration under FIFRA Section 3(c)(2)(B) (iii) ]
and (3) the first registrant has declined to agree to enter
into a cost-sharing agreement, E?A will r.ct suspend tr.e
second firm's registration.
-------
The extension request should state the reasons why you believe
that an extension is appropriate. While EPA considers your
request, you must strive to meet the deadline for submitting
the required data.
»7
-------
TABIE A
GENERIC DATA REQUIREMENTS FOR COPPER SULFATES
Guideline Citation and Test . Guidelines
Name of 'iv-st Substance Status
§158.120
Product Chemistry
Are Data Footnote
Required Number
Yes No
Data Must Be
Submitted Within
Time Frames Listed
Belowiy
Product Identity:
61-1 -
61-2 -
61-3 -
Ahalys
Ing red
62-1 -
62-2 -
62-3 -
Physic,-
Product Identity and TGAI R
Disclosure of Ingredients
Description of Beginning Materials TCAI R
and Manufacturing Process
Discussion of Formation of TCAI R
Impirities
is and Certification of Product
ents
Preliminary Analysis TCAI CR
Certification of Ingredient TCAI R
Limits
Analytical Methods and Data TCAI R
for Fnforcement of Limits
il and Chemical Characteristics
m n 2
n m
m n 3
m n n
m n 5
on n 6
6 months
6 months
12 months
12 months
12 months
63-2 - Color
TGAI
n
ra
-------
TABLE A
GENERIC DATA REQUIRFMENTS FOR COPPER SULFATES
Guidellri'
Name of '
§158.120
f\i i
Dj J
63-4 -
63-5 -
63-6 -
63-7
63-8
63-9
63-10
63-11
> Citation and
'\?st
Product Chemistry (Continued)
Physical State
Odor
Melting Point
Boiling Point
- Den.sity, Bulk Density, or
Specific Gravity
- Solubility
- Vapor Pressure
Dissociation constant
Octanol/water partition
Test Guidelines
Substance Status
TGAT
TGAI
T(1AI
TGAI
TGAI
TGAI
PAI
TGAI, PAI
PAI
R
R
R
R
R
R
R
R
R
Data must Be
Are Data Footnote Submitted Within
Required Number Time Frames Listed
Yes No Below!/
n
n
n
n
n
n
n
n
n
m
m
rin
m
m
[X]
[X]
[X]
m
co< Tficient
-------
TABLE A
GENERIC DATA RBQUD^RMENTS TOR COPPER SULPATES
Guideline Citation and Test Guidelines
Name >f Test Substance Status
§158.; 20 Product Chemistry (Continued)
63-1; - pH TCAI, PAT R
63-1° - Stability TfJAI R
Are Data Footnote
Requ 1 red Numbe r
Yes No
PI [X]
n m
Data Must Be
Submitted Within
Time Frames
Listed Below I/
TGAI - Technical Grade of the Active Ingredient; PAI = Pure Active Ingredient; R = Required; CR = Conditionally Required
I/ Dnta must be submitted within the Indicated time frame, based on the date of the Guidance Document.
' 6 Month Due Date Is April 1, 1986.
' 18 Month Die Date Is October 1, 1986.
?./ Registrants must submit data showing precisely what form of cooper sulfate Is being used In their products.
3/ Registrants must submit data on the nature and amount of Impurities present in the monohydrate and anhydrous forms
ol copper sulfate, If It Is being used.
V Registrants must each submit a preliminary analysis.
5/ EfKih registrant must submit certified limits for the pentahydrate and (If In fact used) the monohydrate and
anhydrous forms. Limits may also be required for Impurities 1f their presence Is of toxlcologlcal concern.
6_/ S) mid there be toxlcologlcal concern over certain Impurities requiring certified limits, analytical methods
w' I.I bi- needed to verify those limits.
-------
TKBIK A
GENERIC DATA REQUIREMENTS FOR COPPER SUIPATES
Data Req' Irenvnts Con position!/
§158.125 Residue Chemistry
171-4 - Nature of Residue (Metabolism)
Plants PA IRA
Does EPA Have Data
To Satisfy This
Requirement? (Yes, Bibliographic
No, or Partially) Citation
Yes 00062069 00099262
0007028? 00099263
00070288 00099269
00099255 00099281
00099256 00099282
00099257 0009928*4
00099258 00099288
00099259 00099537
00099260
Must Additional
Data Re Submit, ted
Under FIFRA Swtion
3(c)(2)(B)?
No
Livestock PAIRA
171-4 - Residue Analytical Method
- Plant residues TOAI
- Animal Residues TOAI
171-1 - Storage Stability Data PAT
Yes
Yes
Yes
N/Al/
00062068
00065678 00099522
00099551
00065678 00099551
00099522
No
No
No
No
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SUIFATES
Data Requirements
Composition]/
Does EPA Have Data
To Sati.sfy This
Requirement? (Yes,
No, or Partially)
Bibliographic
Citation
Must Additional
Data Be Submitted
Under FIFRA Section
3(c)(2)(B)?
§158.125 Residue Chemistry (continued)
171-4 Magnitude of the Residue-
Residue Studies for Each
Foixi Use
TCAI
N/Al/
No
Irrigated Crops, Fish and
ShHlflsh
Magnitude of the Residue in
Meat, Poultry, and Eggs
TGAI
TCAI
N/A!/
N/A5./
No
No
I/ Ccrni er Is exempted frcm the requirements of a tolerance In eggs, fish, meat, milk, Irrigated crops, and shellfish when
it 3 us'-d, as copper sulfate, as an alglolde or herbicide In Irrigation water systems, lakes, ponds, reservoirs, or
otti r bolles of water (40 cm l80.1021(n)).
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SULFATES
Data Requirement
Composition!/ Pattern?/
Does KPA Have Data
To Satisfy This
Requirement? (Yes,
No or Partially)
Must Additional
Data Be Submitted
Blhliographic Under FIFRA Section
Citation 3(c)(2)(B)?
§158.130 Knvironmental Fate
DEGRADATION STUDIES-LAB:
161-1 - Hydrolysis TCAI
Photod' I'radntion
161-2 - In writer TGAI
161-3 On soil TGAI
I6l-t - In Air TGAI
METABOLISM STUDIES-LAB;
162-1 - Aerobic Soil TGAI
162-2 - Anaerobic Soil TQAI
162-3 - Anaerobic Aquatic TGAI
162-4 Aerobic Aquatic TGAI
A,B,C,D,E,F,H No
A,B,C,D,E,F,H No
A,B No
A,B No
A,B,E,F,H No
A,B No
C,D No
C,D No
No!/
NoV
NoV
Yes - 27 months
Yes - 2? months!/
Yes - 27 months
Yes - 27 months
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SULPATES
Data Requirement
Conposltloni/ Pattern?/
Does EPA Have Data
To Satisfy This
Requirement? (Yes,
No or Partially)
Must Additional
Data Be Submitted
Bibliographic Under PIPRA Section
Citation 3(c)(2)(B)?
§158.130 F-nvironmental Pate
(continued)
MOBILITY STUDIES;
163-1 - Leaching and
163-2 -
163-3
DISSIP/
16M-1 -
16*4-2 -
!6'l-3 -
16'M -
161-5 -
Adsorption/Desorptlon
Volatility (Lab)
Volatility (Field)
1'ION STUDIES-FIELD:
Soil
Aquatic
Forestry
Combination and
Tank Mixes
Soil , Long-term
TGAI
TGAI
TGAI
TOAI
TGAI
N/Ai/
N/Al/
TOAI
A,B,C,D,E,P,H
A,B,E,P
A,B,E,P,
A,B,H
C,D
-
-
A,B,H
No
No
No
No
No
-
-
No
Yes - 12 months^./
No!/
No!/
Yes - 27 months
Yes - 27 months
Reservedl2/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SUIJPATES
Data Requirement
Use
Ccmposltionl/ Pattern^/
Does EPA Have Data
To Satisfy This
Requirement? (Yes,
No or Partially)
Bibliographic
Citation
Must Additional
Data Be Submitted
Under PIPRA Section
3(c)(2)(B)?
§158.130 Environmental Fate
( cont 1 nued )
ACCUMUl ATIOM STUDIES:
16S-1
165-2
165-3
165-1
165-5
§158.
- Rotational Crops
(Confined)
- Rotational Crops
(Field)
- Irrigated Crops
- In Pish
- In Aquatic Non-Target
Organisms
I'lO Reentry Protection
TCAI
TGAI
TCAI
TGAI
TGAI
TCAI
A,B,C
A,B,C
C,D
A,B,C,D
D
A,B,C,D
No
No
No
No
No
No
Noll/
Noli/
Noli/
Noli/
Noil/
Noli/
I/ Con >slt1on: TCAI = Technical grade of the active ingredient; PAIRA = Pure active ingredient, radiolabelled;
TEI = Typical end-use product.
2/ The use i^tterns are coded as follows: A = Terrestrial, Pood Crop; B = Terrestrial, Non-Pood; C = Aquatic, Pood
Croi ; D - Aquatic, Non-Food; E = Greenhouse, Food Crop; F = Greenhouse, Non-Pood; G = Forestry; H = Domestic
Out/ioor; I = Indoor
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SULFATES
§158.130 Environmental Pate
(continued)
3/ A hydrolysis study Is not required because these pesticides are inorganic compounds and probably will not hydrolyze,
V Dita are not required because these pesticides are inorganic compounds and are resistant to photolysis.
5/ P»ta ar« not required from registrants who must submit data from an anaerobic aquatic metabolism study.
6/ The dcm-'stlc outdoor, greenhouse, and aquatic uses require a basic equilibrium (adsorption/desorption) test.
7/ Dnta ar<: not required, because the compound lias a low vapor pressure and Is assumed not to volatilize.
8/ P'ta are not required because there are no forestry uses.
9/ I >ta are not required under this Standard, which deals only with products containing copper sulfates a:i the .single
'• tlve Ingredient.
_10/ T i la 'dn ha requirement may be waived, depending on results of the aerobic soil, field dissipation (soil), and field
d'salpntion (Aquatic sediment) studies required under 16?-1, 1M-1, and
•\\j P'ta not required because all food tolerances for copper sulfates have been exempted.
1_2/ P'ta are not required because copper sulfates are freely soluble in water and they presumably have octanol/ water
I'--rtltlon coefficients less than 1000.
13/ D-'ita are not required because copper sulfates are water soluble and therefore have a low potential for
b I oacci mutation.
V\_/ Dita are not required because the copper sulfates do not fall within Toxlcity Category I for inhalation toxlclty,
a' id because the non-volatile properties and methods of use should minimize exposure of workers re-entering treated
fields.
-------
TABIE A
GENERIC DATA REQUIREMENTS FOR COPPER SUfFATES
Does EPA Have Data Must Additional
To Satisfy This Data Be Submitted
Use Requirement? (Yes, Bibliographic Under PIFRA Section
Data Requirement Composition!/ Patterns^/ No or Partially) Citation 3(c)(2)(B)?
§138.133
ACUTE '
81-1 -
81-2 -
81-3 -
81 -it -
81-5 -
Toxicology
PI-STINT):
Acute Oral Toxicity - TGAI
Acute Dermal Toxicity TGAI
Acute Inhalation TGAI
Toxicity
Primary Eye Irritation TGAI
Primary Dermal Irritation TGAI
A,R,C,D, No
E.P.H.I
A,B,C,D, No
K,P,H,I
A,B,C,D, No
F P H T
E<» "»''»-'-
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
Nol/
Nol/
Nol/
Nol/
Nol/
-------
TABIE A
GENERIC DATA REQUIREMENTS FOR COPPER SUIFATES
Does EPA Have Data Must Additional
To Satisfy This Data Be Submitted
Use Requlranent? (Yes, Bibliographic Under FIPRA Section
Data Reqnrremnnt Composition!/ Patterns^/ No or Partially) Citation 3(c)(2)(B)?
§158.133
81-6 -
81-7 -
Toxicology
Derma! Sensitizatlon TGAI
Acute Delayed TGAI
Neurotoxicity - Hen
A,B,C,n, No
E.P.H.I
A,B,C,D, N/A
E,F,H,I
Nol/
N/A
SUBCHRONIC TESTING:
82-1 -
82-2 -
82-3 -
82-1 -
82-5 -
90-Day Feeding - TGAI
Rodent
Non-rodent (dog)
Non- rodent (guinea pig)
21-Day Dermal TOAI
90-Day Dermal TGAI
90-Day Inhalation TGAI
90-Driy Neurotoxlclty- TGAI
Hen
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E.P.H.I
A,B,C,D, N/A
K,F,H,I
Nol/
Nol/
Nol/
Nol/
N/A
-------
TABLE A
(1ENERIC DATA REQUIRI'MENDS FOR COPPER SULFATES
Data Ren ilremmt
Use
Composition!/ Patterns^/
Does EPA Have Data
To Satisfy This
Requirement? (Yes,
No or Partially)
Bibliographic
Citation
Must Additional
Data Be Submitted
Under FIPRA Section
3(c)(2)(B)?
L3f' Toxicology (continued)
CHRONIC TESTING;
83-1 - Chronic Toxicity - TGAI
Rodont (rat)
Non-rodent (dog)
83-2 - Oncogeniolty - TGAI
Rat
Mouse
83-3 - Teratogenlcity - TGAI
Rat
Hamnter
83-4 - Reproduction - TGAI
2-g'-Herat Ion
A,B,C,D,
E.P.H.I
A,B,C,D,
E.F.H.I
A,B,C,D,
E,F,H,I
A.B.C.D,
E,F,H,I
No
No
No
No
Nol/
Nol/
Nol/
Nol/
-------
TABIE A
GENERIC DATA REQUIREMENTS FOR COPPER SULFATES
Data Requirement
Use
Conpositloni7 Patterns^/
Does EPA Have Data
To Satisfy This
Requirement? (Yes,
No or Partially)
Bibliographic
Citation
Must Additional
Data Be Submitted
Under PIPRA Section
3(c)(2)(B)7
MUTAGEf
81-2 -
8H-2 -
84-2 -
SPECIAI
85-1 -
'I CITY TESTING
'iene Mutation TOAI
'.hromosomal Aberration TGAI
ither Geno toxic TGAI
Effects
. TESTING:
'lenernl Metabolism TGAI
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,P,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
No!/
No!/
No!/
No!/
\/ ConporItlon: Material to be tested is technical grade unless otherwise specified in footnotes. PAI= Pure Active
Ingredient. PAIRA- Pure Active Ingredient, Radio-Labeled.
2/ The ure patterns are coded as follows: A = Terrestrial, Pood Crop; B = Terrestrial, Non-Pood; C « Aquatic, Pood Crop;
D * Aci'iatlc, Non-Pood; E = Greenhouse, Pood Crop; F * Greenhouse, Non-Food; G = Forestry; H = Domestic Outdoor;
I * Inioor; IP * Industrial Preservative.
V Although the Agency does not have "guideline" quality studies for this data requirement per se, there Is adequate
InfonH'itlon In the extensive open literature on copper sulfate to characterize its toxicity.
-------
GENERIC
TABUS A
REQUIREMENTS FOR COPPER SULFATES
Data R< quimnent
Use
Composltlonl/ Pattern?/
Doer, EPA Have Data
To SatisTy This
Requirement? (Yea,
No or Partially)
§JS8_.l'i'5 W1.1 dllfe and Aquatic Organisms
AVIAN AND MAMMALIAN TESTING
71-1 - Avian Acute Oral Toxlclty TGAI A,B,C,D,H,l3/ Yes
71-? - Avian Dietary Toxlclty
a) Waterfowl TGAI
b) Upland Gameblrd TGAI
71-3 - Wild Mammal Toxlclty TGAI
71-'< - Avian Reproduction TGAI
71-5 - Simulated and Actual TEP
Field Testing - Mammals and Birds
AQUATIC ORGANISM TESTING
72-] - Freshwater Fish Acute
Toxlcity
a) Warmwater Fish
TGAI
TEP
b Coldwator F1 h
TKP
A,B,C,D,H, Yea
A,B,C,D,H,ll/ Yes
A,B,G,D No
A,B,C,D No
A,B,C,D Nb
A,B,C,D,H
Yes
No
n>
31
Bibliographic
Citation
00067*155
O0067'» 56
00067 '151
00106119
OOOH7160
00099374
ono'47'i60
no05678l
('0099168
Must Additional
Data Be Submitted
Under FIFRA Section
3(c)(2)(B)?
No
No
No
No
No!1/
No
Yes - 9 months
No
Yo.s - 9 months
-------
TABIJ5 A
GBNERIC DATA REQUIREMENTS POR COPPER SUL.PATES
Data R(
§158.1'!
12-2
72-3
72-1
72-5
noes EPA Have Data Must Additional
To Satisfy This Data Be Submitted
Use Requirement? (Yes, Bibliographic Under PIFRA oectlon
lulrement Composition!/ Pattern?/ No or Partially) Citation 3(c)(2)(B)?
5 Wlltlllfe and Aquatic Organisms (continued)
- Acute Toxiclty to TGAI
Freshwater Invertebrates
TEP
- Acute Toxiclty to
Estuarlne and Marine
Organisms
a) Shrimp TGAI
TEP
b) Marine Pish TGAI
TEP
c) Oyster TGAI
TEP
- Pish Early Life
Stage and Aquatic
Invertebrate life-Cycle
fO Pish TOAI
I l Aquatic Invertebrate TOAI
- Pl.-'i - T.ife-Cyr-.le THAI
A,B,C,D,H,l3/ Yes
C.D5/ No
A,G,D Partially
C,D!/ NO
A,C,D No
C.D5/ No
A.C.D Partially
C.Dl/ No
C,D No
C,D No
G , 0 No
00009558 No
Yes - 9 months
00099559 No
Yes - 12 months
Yes - 12 months
Yes - 12 months
00085289 No
00099561
Yes - 12 months
Yes - 15 months^/
Yes -1.5 months
Reserved!/
32
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SUIFATES
Data requirement
Does EPA Have Data
To Satisfy This
Use Requirement? (Yes,
Composition.1/ Pattern?/ No or Partially)
Blbllographlo
Citation
Must Additional
Data Be Submitted
Under PIPRA Section
3(c)(2)(B)
§158.1'1') Wildlife And Aquatic Organisms (continued)
72-6 - Aquatic Organism
Accunulation
72-7 - Simulated or Actual
Field Testing -
Aquatic Organisns
TCAI, PAI or C,D
Degradation
Product
TEP A,C,D
Yes
No
00099168
Yes - 2-'4
I/ C< nposltion: TGAI = Technical grade of the active ingredient; PAI = Pure active Ingredient; TEP = Typical end-use
pi xJuct.
2/ The use patterns are coded as follows: A = Terrestrial, Food Crop; B = Terrestrial, Non-Food; C = Aquatic, Food
Crop; P> = Aquatic, Non-Food; E = Greenhouse, Food Crop; F = Greenhouse, Non-Food; G = Forestry; H = Domestic
Cvtdoor; I = Indoor
3/ Study nxjulred for MPs that are to be used to create products with only indoor uses.
V Dnta from acute toxicology tests Indicate that reproductive and/or field tests will not be necessary.
5/ In addition to testing of technical, formulation testing is required when pesticide is applied directly to water.
-------
TABLE A
GENERIC DATA REQUIREMENTS TOR COPPER SULFATES
§158.1^ Wildlife and Aquatic Organisms (Continued)
6/ Pish anbryolarvae testing on coldwater (trout) and wamiwater (blueglll) socles to support rice use, aquatic
herbicide and molluscicide use.
!/ Reserved pending results of fish early life stage study.
§/ Dat?« are not required because copper sul fates are freely soluble In water and therefore have a low potential for
bioMficumulatlon
9/ To f-onduct a risk assessment and develop a Fish Caution for snail and leech control. Present fish caution Is based
on nlgiclde and herbicide use (2 ppm copper" sulfate). Precaution recommends treating only 1/3 to 1/2 of the pond or
lake in heavy algae situations and retreating the remaining area 7-21 days later in order to reduce fish kills.
However, copper sulfate use as molluscicide Is at much higher levels (10 ppm). This application accounts for about
20 times the toxlcity level for trout and up to 30 times for other fish species . Since diffusion rates, decomposition
absorption, and precipitation of copper sulfatie in a large body of water la unknown, field testing to determine
the appropriate treatment zone will be required to protect nontarget aquatic organisms.
Note: After completion of the data-gathering phase of the Registration Standard process, the Agency discovered
additional data concerning the effects of copper sulfate on non-target organisms. These data were discovered
too late to be reviewed for this Registration Standard. Registrants and applicants may wish to contact the
Agency to determine whether any of these additional data will fulfill data requirements under §158. 145-
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SIJIFATES
Data Requirement
Use
Ccmposltionl/ Pattern?/
Does EPA Have Data
To Satisfy This
Requj reroent? (Yes,
No, or Partially)
Bibliographic
Citation
Must Additional
Data Be Submitted
Under PIFRA Section
3(c)(2)(B)7
§158.155 Nontarget Insect
NONTARGFT INJECT TESTING -
Polllmtorn:
lll-l - Honey bee acute TGAI A,B,H Yen
contact toxic Ity
111-2 - Honey bee - toxlcity of TEP A.R.H No
00001999 No
Nol/
residues on foliage
I'll-** - Honey bee subacute
feeding study
111-5 - field testing for
pollinators
[Reserved]!/
TEP
A,B,H
No
Nol/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER SULFATES
Does EPA Have Data Must Additional
To Satisfy This Data Be Submitted
Use Requirement? (Yes, Bibliographic Under PIPRA Section
Data Requirement Ccmpositionl/ Pattern!/ No or Partially) Citation 3(c)(2)(B)7
§158.155 Nontarget Insect (continued)
NONTARQET INSKCT TESTING -
AQUATIC INSECT^
1*12-1 - Acute toxlclty to [Reserved]V
aquatic insects
lte-2 - Aquatic Insect [Reserved]V
life-cycle study
142-3 - -Sljnulated or actual [Reserved ]5/
field testing for
aquatic Insects
113-1- NOHTARQET INSECT TESTING [Reserved]5/
thru T iEbATORS AND PARASITES
143-3 ~~
I/ Conposition: TQAI - Technical grade of the active ingredient; TEP = Typical end-use product.
j2/ The use pattern codes are as follows: A - Terrestrial, Food Crop; B = Terrestrial, Non-Food; C - Aquatic, Food Crop;
D « Aquatic, Non-Food; E - Greenhouse, Pood Crop; F = Greenhouse, Non-Pood; G = Forestry; H « Domestic Outdoor;
I - Indoor.
J3_/ Data are not required because the acute study data indicate low toxicity to bees.
V Reserved, pending Agency development of test methodology.
5/ Reserved, pending Agency decision as to whether the data requirement .should be established.
.16
-------
III. REQUIREMENT FOR SUBMISSION OF PRODUCT-SPECIFIC DATA
Note: Unless stated otherwise in Section I, Regulatory
Position and Rationale, this Section applies only to manufac-
turing use products, not to end use products.
A necessary first step in determining which statements
must appear on your product's label is the completion and
submission to EPA of product-specific data* listed on the
form entitled "Product Specific Data Report" (EPA Form
8580-4, Appendix III-l) to fill gaps identified by EPA
concerning your product. Under the authority of PIPRA sec.
3(c)(2)(B), EPA has determined that you must submit these
data to EPA in order to reregister your product(s).
Table A—Generic Data Requirements for Manufacturing-Use
Products—lists the data you must submit. Data that are
required to be submitted are identified in the column of
those tables entitled "Must Data Be Submitted Under §3(c)(2)(E
»/ Product specific data pertain to data that support the
formulation which is marketed; it usually includes product
chemistry data and acute toxicity data.
-------
IV. SUBMISSION OF REVISED LABELING
Note: This section applies to end-use products only to the
extent described In Section I (Regulatory Position and
Rationale). Otherwise, the following information pertains
exclusively to manufacturing-use products.
FIPRA requires each product to be labeled with accurate,
complete and sufficient instructions and precautions, reflecting
the results of data concerning the product and its ingredients.
Labeling requirements are set out in 10 CPR 162.10 (see
Appendix IV-1) and are summarized for products containing
this active ingredient as part of this Guidance Document
(See Appendix IV-2). Applications submitted in response to
this notice must include draft labeling for Agency review.
If you fail to submit revised labeling information
complying with this section (supplemented by requirements
described in Section I, Regulatory Position and Rationale),
EPA may issue a notice of intent to cancel the registration
under FIFRA sec."6(b)(1) .
A. Label Contents
40 CFR 162.10 requires that certain specific labeling
statements appear at certain locations on the label. This
is referred to as format labeling. Specific label items
listed below are keyed to Appendix IV-2.
Item 1. PRODUCT NAKE - The name, brand or trademark is
required to be located on the front panel, preferably centere:
in the upper part of the panel. The name of a product will
not be accepted if it is false or misleading.
Item 2. COMPANY NAME AND ADDRESS - The name and address
of the registrant or distributor is required on the label.
The name and address should preferably be located at the
bottom of the front panel or at the end of the label text.
Item 3. NET CONTENTS - A net contents statement is
required on all labels or on the container of the pesticide.
The preferred location is the bottom of the front panel
Immediately above the company name and address, or at the end
of the label text. The net contents must be expressed in the
largest suitable unit, e.g., "1 pound 10 ounces" rather than
"26 ounces." In addition to English units, net contents may
be expressed in metric units. See Appendix IV-1. [40 CFR
I62.10(d)j
-------
Item 4. EPA REGISTRATION NUMBER - The registration
number assigned to the pesticide product must appear on the
label, preceded by the phrase "EPA Registration No.," or "EFA
Reg. No." The registration number must be set in type of a
size and style similar to other print on that part of the
label on which it appears and must run parallel to it. The
registration number and the required identifying phrase must
not appear in such a manner as to suggest or imply recommends tier.
or endorsement of the product by the Agency. See Appendix IV-1.
[40 CFR I62.10(e)]
Item 5. EPA ESTABLISHMENT NUMBER - The EPA establishment
number, preceded by the phrase "EPA Est." is the final estab-
lishment at which the product was produced, and may appear
in any suitable location on the label or immediate container.
It must also appear on the wrapper or outside container of
the package if the EPA establishment number on the immediate
container cannot be clearly read through such wrapper or contalr.e
See Appendix IV-1. [40 CPR I62.10(f)]
Item 6A. INGREDIENTS STATEMENT - An ingredients statement
is required on the front panel. The ingredients statement must
contain the name and -percentage by weight of each active ingredie
and the total percentage by weight of all inert ingredients.
The preferred location is immediately below the product name.
The ingredients statement must run parallel with, ana be clearlj
distinguished from, other text on the panel. It must not be
placed in the body of other text. See Appendix IV-1. [40 CFR
I62.10(g)]
Item 6B. POUNDS PER GALLON STATEMENT - For liquid agricul-
tural formulations, the pounds per gallon of active ingredient
must be indicated on the label.
Item 7. FRONT LABEL PRECAUTIONARY STATEMENTS - Front panel
precautionary statements must.be grouped together, preferably
within a block outline. The table below shows the minimum type
size requirements for various size labels.
Size of Label Signal Word "Keep Out of Reach
on Front Panel Minimum Type Size of Children"
in Square Inches All Capitals Minimum Type Size
5 and under 6 point 6 point
above 5 to 10 10 point 6 point
above 10 to 15 12 point 8 point
above 15 to 30 14 point 10 point
over 30 18 point - 12 point
39
-------
Item 7A. CHILD HAZARD WARNING STATEMENT - The statement
"Keep Out of Reach of Children" must be located on the front
panel above the signal word except where contact with children
during distribution or use is unlikely. See Appendix IV-1 .
[40 CPR I62.10(h)(l)(il)3
Item 7B. SIGNAL WORD - The signal word (DANGER, WARNING,
or CAUTION) is required on the front panel immediately below
the child hazard warning statement. See Appendix IV-1.
[40 CFR 162.10 (h)(l)(i)]
v
Item ?C. SKULL & CROSSBONES AND WORD "POISON" - On products
assigned a toxicity Category I on the basis of oral, dermal,
or inhalation toxicity, the word "Poison" shall appear on the
label in red on a background of distinctly contrasting color ar.c
the skull and crossbones shall appear in immediate proximity to
the word POISON. See Appendix IV-1. [40 CFR l62.10(h) ( 1) ( i) ]
Item 7D. STATEMENT OF PRACTICAL TREATMENT - A statement
of practical treatment (first aid or other) shall appear on
the label of pesticide products in toxicity Categories I,
II, and III. See Appendix IV-1. [40 CFR I62.10(h) (1) (ill) ]
Item 7E. REFERRAL STATEMENT - The statement "See Side
(or Back) Panel for Additional Precautionary Statements" is
required on the front panel for all products, unless all
required precautionary statements appear on the front panel .
See Appendix IV-1. [40 CFR I62.10(h) (1) (lii)]
Item 8. SIDE/BACK PANEL PRECAUTIONARY LABELING - The
precautionary statements listed below must appear together
on the label under the heading "PRECAUTIONARY STATEMENTS."
The preferred location is at the top of the side cr back
panel preceding the directions for use, and it Is preferred
that these statements be surrounded by a block outline. Each
of the three hazard warning statements must be headed by the
appropriate hazard title. See Appendix IV-1. [40 CFR 162.10
Item 8A. HAZARD TO HUMANS AND DOMESTIC ANIMALS - Where a
hazard exists to humans or domestic animals, precautionary
statements are required indicating the particular hazard, the
route(s) of exposure and the precautions to be taken to avoid
accident, Injury or damage. See Appendix IV-1. [40 CFR 162. 1C
40
-------
Item 83. ENVIRONMENTAL HAZARD - Where a hazard exists to
non- target organisms excluding humans and domestic animals,
precautionary statements are required stating the nature of
the hazard and the appropriate precautions to avoid potential
accident, injury, or damage. See Appendix IV-1 . [40 CFR
Item 8C. PHYSICAL OR CHEMICAL HAZARD
1. Flammability statement. Precautionary statements relating
to flammability of a product are required to appear on the
label if it meets the criteria in Appendix IV- 3. The require-
ment is based on the results of the flashpoint determinations
and flame extension tests required to be submitted for all
products. These statements are to be located in the side/back
panel precautionary statements section, preceded by the
heading "Physical/Chemical Hazards." Note that no signal
word is used in conjunction with the flammability statements.
2 . Criteria for declaration of non-f lammability . The
following criteria will be used to determine if a product
is non-flammable:
a. A "non-flammable gas" is a gas (or mixture of gases;.
that will not ignite when a lighted match is placed
against the open cylinder valve.
b. A "non-flammable liquid" is one having a flashpoint
greater than 350°F (177°C).
c. A " no n- flammable aerosol" is one which meets the
following criteria:
i. The fla^ie extension is zero inches;
ii. -There is no flashback; and
ill. The flashpoint of the non-volatile liquid
component is greater than 350°P (177°C).
3. Declaration of non-f lammability . Products which
meet the criteria for non- flammability specified
above may bear the notation "non-flammable" or "non-
flammable (gas, liquid, etc.)" on the label. It may
appear as a substatement to the ingredients statement,
or on a back or side panel, but shall not be highlighted
or emphasized (as with an inordinately large type
size) in any way that may detract from precaution.
41
-------
4. Other physical/chemical hazard statements. When
chemistry data demonstrate hazards of a physical or
chemical nature other than flammability, appropriate
statements of hazard will be prescribed. Such statements
may address hazards of explosivity, oxidizing or reducing
capability, or mixing with other substances to produce
toxic fumes.
Item 9A. RESTRICTED USE CLASSIFICATION - FIFRA sec. 3(d)
requires that all pesticide formulations/uses be either unclassified
or classified for restricted use. Products classified for
restricted use may be limited to use by certified applicators
or persons under their direct supervision (or may be subject
to other restrictions that may be imposed by regulation).
In the Registration Standard, the Agency has (1) indicated
certain formulations/uses are to be restricted (Section I
indicates why the product has been classified for restricted
use); or (2) reserved any classification decision until
appropriate data are submitted.
The Regulatory Position and Rationale states whether
products containing this active ingredient are classified
for restricted use. If they are restricted the draft label(s)
submitted to the Agency as part of your application must
reflect this determination (see below).
If you do not believe that your product should be classified
for restricted use, you must submit any information and
rationale with your application for reregistration. During
the Agency's review of your application, your proposed classi-
fication determination will be evaluated in accordance with
the provisions of iJO CFR 162.IK c). You will be notified of
the Agency's classification decision,
A. Classification Labeling Requirements
If Section I of this Guidance Document indicates that
your product has been classified for restricted use, the
following label requirements apply:
1. Front panel statement of restricted use classification.
a. The statement "Restricted Use Pesticide" must
appear at the top of the front panel of the label.
The statement must be set in type of the same
minimum size as required for human hazard signal
word (see table in 40 CFR 162.10(h)(1)(iv).
4?
-------
b. Directly below this statement on the front panel,
a summary statement of the terms of restriction must
appear (including the reasons for restriction if
specified in Section I). If use is restricted to
certified applicators, the following statement is
required: "For retail sale to and use only by
Certified Applicators or persons under their direct
supervision and only for those uses covered by the
Certified Applicator's Certification."
2. Some but not all uses restricted. If the Regulatory
Position and Rationale states that some uses are classified
for restricted use, and some are unclassified, several courses
of action are available:
a. You may label the product for Restricted use.
If you do so, you may include on the label uses that
are unrestricted, but you may not distinguish them
on the label as being unrestricted.
b. You may delete all restricted uses from your
label and submit draft labeling bearing only unrestricted
uses .
c. You may "split" your registration, i.e., register-
two separate products with identical formulations, one
bearing only unrestricted uses, and the other bearing
restricted uses. To do so, submit two applications for
reregistration, each containing all forms and necessary
labels. Both applications should be submitted simul-
taneously. Note that the products will be assigned
separate registration numbers.
E. Compliance Schedules
No product with a use classified for restricted use
under this Standard may be released for shipment by the
registrant or producer after one year from the date of
issuance of this Standard, unless such product bears the
restricted use classification. All products still in
channels of trade after two years from the date of issuance
of this Standard must be labeled for restricted use.
Item 9B [There is no Item 9B].
Item 9C. MISUSE STATEMENT - All products must bear the
misuse statement, "It is a violation of Federal law to use
this product in a manner inconsistent with its labeling."
This statement appears at the beginning of the directions
for use, directly beneath the heading of that section.
45
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Item 10A. REENTRY STATEMENT - If a reentry Interval
has been established by the Agency, it must be Included on
the label. Additional worker protection statements may be
required in accordance with PR Notice 83-2, March 29, 1983-
Item 10B [There is no Item 10B].
Item IOC. STORAGE AND DISPOSAL BLOCK - All labels are
required to bear storage and disposal statements. These
statements are developed for specific containers, sizes, and
chemical content. These instructions must be grouped and
appear under the heading "Storage and Disposal" In the directions
for use. This heading must be set in the same type sizes as
required for the child hazard warning. Refer to Appendix
IV-4 to determine the disposal instructions appropriate for
your products.
Item 10D. DIRECTIONS FOR USE - Directions for use must
be stated in terms which can be easily read and understood by
the average person likely to use or to supervise the use of
the pesticide. When followed, directions must be adequate to
protect the public from fraud and from personal injury and to
•prevent unreasonable adverse effects on the environment. See
Appendix IV-1. [40 CPR 162.10]
B. Collateral Labeling
Bulletins, leaflets, circulars, brochures, data sheets,
flyers, or other written or graphic printed matter which is
referred to on the label or which is to accompany the product
are termed collateral labeling. Such labeling may not bear
claims or representations that differ in substance from
those accepted in connection with registration of the product.
It should be made part of the response to this notice and
submitted for review.
-------
3. Within the times set forth In Table A, you must submit
to the Registration Division all generic data, unless you are
eligible for the formulator's exemption. If for any reason any
test is delayed or aborted so that the agreed schedule cannot be
met, notify the Product Manager and the Office of Compliance
Monitoring .
B. For Manufacturing Use Products containing Copper Sulfate
in combination with other active ingredients
1. Within 90 days from receipt of this document, you must
submit the "PIFRA Section 3(c)(2)(B) Summary Sheet," EPA Fora
8580-1. Refer to Appendix II-3 with appropriate attachments.
If on the Summary Sheet, you commit to develop the data,
request a minor chemical exemption, present arguments that a data
requirement is not applicable, or submit protocols or modified
protocols for Agency review, you must also submit a copy of the
Summary Sheet (and any supporting information) to the Office of
Compliance Monitoring, which will be monitoring the data generated
in response to this notice. This information should be submitted
to the Office of Compliance Monitoring at the address giver, at
the end of this section. (Actual studies are not to be submitted,
2. Within the times set forth in Table A, you must submit
to the Registration Division all generic data, unless you are
eligible for the formulator's exemption. If for any reason any
test is delayed or aborted so that the agreed schedule cannot be
met, notify the Product Manager and the Office of Compliance
Monitoring.
C. For End Use Products containing Copper Sulfate alone
or in combination with other active ingredients:
1. Within 90 days from receipt of this document, you must
submit the "FIFRA Section 3(c)(2)(B) Summary Sheet," EPA Form
8580-1. Refer to Appendix II-3 with appropriate attachments.
If on the Summary Sheet, you commit to develop the data,
request a minor chemical exemption, present arguments that a
data requirement is not applicable, or submit protocols or modified
protocols for Agency review, you must also submit a copy of the
Summary Sheet (and any supporting information) to the Office of
Compliance Monitoring, which will be monitoring the data generated
in response to this notice. This information should be submitted
to the Office of Compliance Monitoring at the address given at
the end of this section. (Actual studies are not to be submitted.)
46
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2. Within 6 months from receipt of this document you must
submit:
a. Confidential Statement of Formula, EPA Form 8570-4.
b. Product-Specific Data Report, EPA Form 8580-4
(Appendix III-l).
c. Two copies of any required product-specific data.
(Refer to Table C).
d. Two copies of draft labeling, including the label and
associated brochures. If current labeling conforms to the
requirements of this guidance document and the results of
the short-term data, you may submit such labeling. End use
product labeling must comply specifically with the instructions
in Section I (Regulatory Position and Rationale) of this
guidance document. Labeling should be either typewritten
text on 8 1/2 x 11 inch paper or a mockup of the labeling
suitable for storage in 8 1/2 inch files. The draft label
must indicate the intended colors of the final label, clear
indication of the front panel label, and the intended type
sizes of the text.
e. Evidence of compliance with data support requirements
of FIFRA sec. 3(c)(l)(D). Refer to 40 CFR 152.80-152.99
(enclosed) for latest requirements.
3. Within the time frames set forth in Table A, submit all
generic data,unless you are eligible for the formulator's
exemption.
D. For intrastate products containing Copper Sulfate
either as the sole active ingredient or in combination
with other active ingredients
These products are being called in for full Federal
registration. Producers of these products are being sent
a letter instructing them how to submit an application for
registration.
E. Applications and other required Information should be
submitted to the following address:
Richard Mountfort
Product Manager
Registration Division (TS-767C)
Office of Pesticide Programs
Environmental Protection Agency
401 M St., S.W.
Washington, D.C. 20460
Phone No. (703) 557-1650
47
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The address for submission to the Office of Compliance Monitoring
is:
Laboratory Data Integrity Program
Office of Compliance Monitoring (EN-342)
Environmental Protection Agency
401 M St., S.W.
Washington, D.C. 20460
48
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Pages 50 through 195 consist of three entries to the EPA
Index to Pesticide Chemicals: Basic copper sulfate, copper
sulfate monchydrate , and copper sulfate pentahydrate.
49
-------
APPENDIX 1-1
EPA Index Co Pesticide Chemicals
BASIC COPPER SBLFATE*
PESTIC1DS: Herbicide
FORMDLATIONS;
Tech (53Z)
WP (12.5Z, 12.75Z, 46.25Z, 52Z)
CENEBAL WARMINGS AND LIMITATIONS; A selective herbicide for the control
of ball BOSS, lichens and Spanish moss. The active ingredient is express-
ed as percentage of metallic copper.
TIME REQUIRED FOR CONTROL; Not located.
PHTTOTOXICITY TO TARGET «EDS: Not located.
PHTTOTOXICITY TO CROPS: Not located.
MODE OF ACTION: Not located:
TOABBB
TOABBA
GRASSES AND OTHER MONOCOTS CONTROLLED;
ball moss
Spanish BOSS
*LAAAAA
NONFIDWERING PLANTS CONTROLLED:
lichens
50
*tribasic copper sulfate
Issued: 1-27-83
1-008101-1
-------
Site, Dosage
and Formulation
AGRICULTURAL CROPS
D008AA Pecan
535 3AA Pecan (ornamental)
•»
12 tbsp product/
gal water
(12.51 WP)
(12.75Z WP)
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Tolerance, Use. Limitations
--
Exempt.
Directed spray. Spanish BOSS control. Apply dur-
ing winter.
35191AA
ORNAMENTALS
Live Oak
3.12 Ib a~i./
IflO gal water
(52Z WP)
%004AA
1500QAA
Ornamental Woodv
Shrubs-
Ornamental and /or
Shade Trees
3 tbsp product/
gal water
(46.25X WP)
0,c limited to TX. Directed spray. Ball moss
control. Apply in the spring after a heavy rain,
using, 1.5 gallons of spray per foot of tree
height. Applications may be needed once a year.
Directed spray. Lichen control. Thoroughly wet
lichens, and repeat as needed.
Pecan (ornamental) See AGSI CULTURAL CROPS, Pecan cluster.
51
Issued: 1-27-83
1-008101-2
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation
531 technical chemical
basic copper sulfate (008101)
035896-00004
12.51 wettable powder
^basic copper sulfate (008101)
005481-00135
12.751 vettable powder
basic copper sulfate (008101)
002217-00613 033955-00097 048391-00013
46.251 wettable powder
basic copper sulfate (008101)
000557-01933
52Z wettable powder
basic copper sulfate (008101)
001278-00001
Issued: 1-27-83 1-008101-3
-------
EPA Index Co Pesticide Chemicals
BASIC COPPER SDLFATE
Appendix B
Listing of Registration Numbers By Site
AgUCDLTURAL CROPS
Pecan
002217-00613 005481-00135 033955-00097 048391-00013
ORNAMENTALS
Live Oak
001278-00001
Ornamental Woodv
Shrubs
000557-01933
Ornamental and/or
Shade Trees
000557-01933
Pecan (ornamental)
002217-006L300548L-00135 033955-00097 048391-00013
53
Issued: 1-27-83
1-008101-4
-------
EPA Index to Pesticide Chemical*
cOOSiOl BASIC COPPER SDLFATE*
TYPE PESTICIDE: Fungicide
yOKMULATIONS:
Tech (532)
D (22, 32, 3.42, 3.3Z, 3.82. 42, 4.5Z. 5Z, 62, 6.252, 6.32. 6.7Z, 7Z,
8Z)
TO (4Z, 5.22. 6.32, 7.1Z, 7.3Z, 7.42, 12.52, 12.75Z, 13.852, 14.32,
14.92, 15.22, 15.62, 17.052, 18.12, 192, 20.12, 222, 30.252, 30.62,
332, 46.252, 502, 522, 532)
WP/D (3.72, 52, 72)
F1C (0.11 Ib/gal, 0.39 Ib/gal or 4.152, 0.48 Ib/gal or 4.42, 0.53 Ib/gal,
1 lb/g«l, 3 Ib/gal, 4.24 Ib/gal)
GENERAL WAKINGS ASP LIMITATIONS; Do not use vith or ianediately before
or after lime sulfur or ferbaa. Dosage rates are given in pounds of
metallic copper. May be applied by dilute ground equipment, concentrate
equipment, aircraft, or sprinkler irrigation systems. For concentrate
sprayers, consult manufacturer's recommendations for spray volumes. Dusts
may be applied by aircraft. Dosages may be adjusted proportionately for
•mailer areas [note, however, that the relationship of tablespoons per
gallon to pounds per 100 gallons varies among labeling]. Wettable powder
formulations (53 percent) may be applied as a dust when prepared with^a
suitable diluent. Though recommendations for the addition of hydrated
lime and/or spreader-sticker are given within, a State Agricultural Co-
operative Extension Service should be consulted for specific information.
NOTE - Agricultural seed treatment uses are placed as a group after the
agricultural crop uses.
Definition of Terns:
MAJ - Multiple active ingredient(s)
a.i. - active ingredient
Tablespoons (tbls) actual: A hypothetical quantity computed by multiply-
ing the number (or equivalent number) of tablespoons or product by the
concentrations of metallic copper (from basic copper sulfate) in the
formulation.
54
*tribssic copper sulfa.e
Issued: 9-16-82 II-008101-1
-------
Site and Pest
AGRICULTURAL CROPS
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Formulations)
general Warnings and Limitations: Ibe restrictions on the timing of
application in certain sites may be attributed to phytotoxicity. Over-
spraying may cause injury to tender foliage of almonds, apricot, peaches,
and come Japanese plums.
/23001AA Alfalfa
BKCBM Leaf spot
(Cercospora)
jHBCLAT Leptosphaerulina
leaf spot
I03001AA Almond
jUDMCS Brown rot blossom
and twig blight
j (Bonilinia)
IIJAZCEL Sho thole
1 (Coryneum blight)
Exempt
Ho preharvest interval through 1.04
pounds per 100_gallons. -
1.04 lb/ Foliar application. Apply 10 to 14
100 gal days before each harvest. Consult
(522 WP) a State Extension Service for sen-
sitive local species that might be
injured.
Exempt
Apply through 21.2 pounds per acre.
Do not apply when trees are in full
leaf.
Dormant, delayed dormant, and foliar
application. Add a suitable sprea-
der-sticker. Apply in dormant (for
•hothole), and at pink bud through
popcorn stage.
OR M&I
Formulated with sulfur; or zinc
sulfate, basic.
1.59-2.65 lb/
100 gal
{350-400
gal/A]
[max. 21.2
Ib/A]
(19-53Z WP)
<7S WP/D)
(4.24 lb/
gal F1C)
or
1.0-1.5 lb/
100 gal
1350-400
gal/A]
(3 Ib/gal
F1C)
or
2.85-3.23
Ib/A
(3.8Z D)
(7Z HP/D)
or
55
Issued: 9-16-82
II-008101-2
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use. Limitations
Formulation(s)
Almonds (continued)
/04001AA
FAAANAX
Apple
Anthracnose
(Heofabraea)
concentrate:
4.24-7.42
Ib/A
125-50
gal/A]
(531 WP)
(4.24 Ib/gal
F1C)
or
2.5-3.0 Ib/A
(3 Ib/gal
F1C)
or
aerial,
dormant:
8.48-10.6 lb/
20 gal/A
(53J WP)
(4.24 Ib/gal
F1C)
or
4.0-7.42 lb/
20 gal/A
(3-4.24 lb/
gal F1C)
OR MAI
1.14-1.52 lb/
100 gal
(191 WP)
or
0.24-0.48 lb/
100 gal
(0.48 Ib/gal
or 4.4Z F1C)
Exempt
No preharvest interval through 16.96
pounds per acre.
1.59-2.12 lb/ Foliar or postharvest application.
100 gal For red varieties, apply to foliage
[max. 16.96 before or after harvest. For yellow
Ib/A] varieties, apply to foliage after
(12.5-532 WP) harvest once every 2 to 3 years as
needed. A suitable oil spreader n^y
be added for postharvest applica-
tions.
Issued: 9-16-82
II-008101-3
56
-------
Site and Pest
IIUJVAG
Apple (continued)
Apple scab
(Venturia)
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use, Limitations
Formulation(s)
0.53-0.66 lb/ DelaveH
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATS
Dosages and Tolerance, Use, Limitations
Formulation(s)
FBANEBI
Apple (continued)
Fire blight
(Ervinia)
FCAFGAL
Sooty blotch
(Gloeodes)
0.11-0.285
lb/100 gal
(19-532 WP)
or
1.06 Ib/A
[concen-
trate]
(532 WP)
or
0.8-1.14 Ib/A
(3.8-6.72 D)
or
1.8-2.76 Ib/A
(62 D)
OR MAI
0.19-0.285
lb/100 gal
(max. 1.14
Ib/A]
(192 WP)
0.66 lb/
100 gal
(532 WP)
Foliar application. Apply at 10
percent bloom. Repeat at 5 day
intervals until late bloom is over.
OR MAI
Formulated with zinc sulfate, basic
Foliar application. Add hydrated
lime. Apply in late cover sprays.
Under conditions where copper ir.-u:
is likely to occur, add additional
limp.
/05001AA Apricot
FBADMCB Brovn rot blossom
and twig blight
(Monilinia)
1.97-4.24 lb/
100 gal
[max. 21.2
Ib/A]
(12.5-532 WP)
(72 WP/D)
(4.24 lb/
gal F1C)
or
1.0-1.5 lb/
100 gal
(3 Ib/gal
F1C)
or
Exempt
Apply through 21.2 pounds per acre.
Do not apply when trees are in fui*
leaf.
Delayed dormant and foliar appli-
cation. Add a suitable spreader-
sticker. For shothole, apply as a
fall or winter spray (after most
leaves have fallen, but before first
rains). Repeat in red bud to pop-
corn. For brown rot, apply red bud
through prejacket.
OR MAI
Formulated with sulfur; or zinc
sulfate, basic.
58
Issued: 9-16-32
II-008101-5
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Uset Limitations
Fommlation(s)
Apricot (continued)
/2800QAA
FiAAGAP
IHAUCBM
SAJSCB
2.85-3.23
Ib/A
(3.82 D)
(71 WP/D)
or
concentrate:
4.24-6.36
Ib/A
(4.24 Ib/gal
F1C)
or
3.0-3.5 Ib/A
(3 Ib/gal
F1C)
OR MAI
-1.52-1.71 lb/
100 gal
(192 W?)
or
0.48-0.72 lb/
100 gal
(0.48 Ib/gal
or 4.42 F1C)
Exempt
Do not apply later than 140 days
after bloom through 21.2 pounds pe:
acre.
Anthracnose 0.15-2.12 lb/ Foliar application. Apply when
(Glomerella) 100 gal blossom buds open. Repeat at 4 week
C*rcospora fruit [max.. 21.2 intervals for a total of 5 appl i-
«pot (blotch) Ib/A] cations. A suitable spreader may
Scab (spot anthrac- (50-532 WP) be added.
nose) (Sphaceloma) (4.24 Ib/gal
F1C)
or
1.0 lb/
100 gal
(3 Ib/gal
F1C)
Avocado
59
Issued: 9-16-82
II-008101-6
-------
/06002AA
FMAWPCR
FMBOCBM
/28063AA
FCAGHAM
FCADSBL
/28001AA
FMABIAH
FAAACDP
FBAAXAA
FBARPDZ
FFABPCN
FFACQBB
Site and Pest
Banana
Black pitting
(Piricularia)
Sigatoka disease
(Cercospora leaf
•pot)
Barley
Belminthosporium
•pot blotch
Septoria leaf
blotch
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use, Limitations
Pormulation(s)
Exempt
Bo praharvest interval through 1.3
pounds per sere.
2.6 lb/
100 gal
(521 WP)
1.3
3 gal/A
(522 WP)
1.04 lb/
100 gal
(522 WP)
Beans (dry, green, and lima)
Angular leaf spot
(Isariopsis)
Anthracnose
(Colletotrichum)
Bacterial (comaon)
blight (Xantho-
•onas)
Bacterial halo
blight (Pseudo-
monas)
Downy mildew
(Phytophthora)
Powdery mildew
0.53-2.12
Ib/A
or
1.04-2.12
lb/100 gal
[max. 3.975
Ib/A]
(12.75-532
WP)
(3-4.24 lb/
gal F1C)
or
2.0-2.8 Ib/A
(7-82 D)
OR MM
0.7-1.4 lb/
100 gal
(5-72 WP/D)
or
Poliar application. Apply the first
and second week after emergence.
Apply directly to the fruit stems
and include the basal portion of
the leaf crown.
Foliar application. Add a suitable
spreader. Apply on a 14 day sche-
dule during the wet season and a 21
day schedule during dry season.
Exempt
No preharvest interval through 1.04
pounds per 100 gallons.
Foliar application. Apply at early
heading and again 10 days later.
Exempt
Ho preharvest interval through 3.975
pounds per acre.
Foliar application. Apply when
plants are 5 inches high or when
disease first appears. Repeat at 5
to 10 day intervals.
OR MAI
Formulated with one or a combination
of: maneb; methylated napthalenes;
carbaryl; malathion; 0,0-diethyl 0-
(2-i«opropyl-6-aethyl-4-pyrimidinyl)
phosphorothioate; piperonyl butox-
Ide, technical; pyrethrins; rotenone
(and other cube resins); or sulfur.
60
Issued: 9-16-82
H-O08101-7
-------
Site and Pest
Beans (continued)
UA&UAH
Bus t ( TJrornyce s )
12800 2AA
IFABPAU
3AAQBB
Beets
Downy mildew
(Peronospora)
Leaf blights
Leaf spots
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Formulations)
0.68-2.8 Ib/A
(3.4-7Z D)
(5-7Z OT/D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
0.6-1.36 Ib/A Foliar application.
(2-3.4Z D) Formulated with carbaryl; sulfur;
or or maneb and sulfur.
3.25-3.9 Ib/A
(6.5Z D)
Exempt
Ho preharvest Interval through 3.71
pounds per acre.
1.0-2.12 Ib/A Foliar application. Apply when
or disease first appears. Repeat at /
1.56-1.59 IV to 10 day intervals.
100 gal ' OR MAI
[max. 3.71 Formulated with methoxychlor, tech-
Ib/A] nical; malathion; or sulfur.
(52-53Z WP)
(3-4 Ib/gal
F1C)
or
2.1-3.6 Ib/A
(7-8Z D)
OR MAI
2.45-3.5 Ib/A
(5-7Z D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
Issued: 9-16-82
£1
II-008101-8
-------
EPA Index to Pesticide Chemicals
/01002AA
/01003AA
/01004AA
/01005AA
/01006AA
FAAAEAH
FMAMSBL
FJAPKAH
Site and Pest
Blackberry
Boysenberry
Dewberry
Loganberry
Raspberry
Anthracnose
(El since)
Leaf and cane
(Septoria)
Yellow rust
(Kuehneola)
spot
/13005AA
/13006AA
/13007AA
/13008AA
FFABPAU
FMBCQBB
Boysenberry
Broccoli
Brussels Sprouts
Cabbage
Cauliflower
Downy mildew
(Peronospora)
Leaf spots
BASIC COTPER SULFATE
Dosages and Tolerance. Pse, Limitations
Formulation(s)
Exempt
Ho preharvest interval through 3.18
pounds per acre per application.
1.0-3.18 lb/
100 gal
[max. 3.18
Ib/A/appli-
eation]
(12.75-5 3X
WP)
(3-4.24 lb/
gal F1C)
Delayed dormant, foliar, and post-
harvest application. For anthrac-
nose, apply low rate when leaf buds
begin to open. Repeat when flower
buds show white and continue at 10
to 14 day intervals. For leaf and
cane spot, apply 1.0 to 3.18 pounds
when leaf buds begin to open. Re-
peat when flowers begin to open.
For yellow rust, apply 3.18 pounds
when leaf buds swell and when flow-
ers open. For leaf and cane spot,
and yellow rust, apply 3.18 pounds
as a postharvest spray after pruning
and before fall rains.
See Blackberry cluster.
0.53-2.12
Ib/A
or
1.14-1.52 lb/
100 gal
[max. 3.18
Ib/A]
(19-53Z WP)
(71 HP/D)
(3-4.24 lb/
gal F1C)
or
1.575-3.2
Ib/A
(6.3-81 D)
(7Z WP/D)
or
Exempt
Ho preharvest interval through 3.2
pounds per cere.
Foliar application. Apply when
plants are above ground in plar.'.
bed or before disease normally ap-
pears. Repeat at 7 to 10 day inter-
vals in plant bed and field.
OR MAI
Formulated with methoxychlor, tech-
nical; carbaryl; malathion; rotenone
(and other cube resins); sulfur;
maneb and 0,0-diethyl 0-(2-iso-
pr opy 1-6-me thy 1-4-p yrimid i ny 1)
pbosphorothioate; or carbaryl.
62
Issued: 9-16-82
II-008101-9
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages.and Tolerance. Use. Limitations
Fonnulation(s)
Broccoli cluster (continued)
/28073AA
Brussels Sprouts
Cabbage
Carrots
ffABPCV
FBttOM
BASAAX
Downy mildew
(Plasmopara)
Early blight
(Cercospora)
Late blight
(Alteraaria)
OR MAI
0.7 lb/
100 gal
(7Z HP/D)
or
1.0-3.15 Ib/A
(3.4-7Z D)
(7Z WP/D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
See Broccoli cluster.
See Broccoli cluster.
Exempt
Ho preharvest interval through 3.975
pounds per acre.
The addition of hydrated lime to
•prays is recommended.
1.0-2.12 Ib/A Foliar application.
Caul iflove"
or
0.93-2.12
lb/100 gal
[max. 3.975
Ib/A]
(52-532 WP)
(71 WP/D)
(3-4.24 lb/
gal F1C)
or
2.1-3.6 Ib/A
(7-8Z D)
(7Z HP/D)
OR MAI
0.75-3.15
Ib/A
(3.5-7Z D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
See Broccoli cluste".
Apply when dis-
Repeat at 7 to
ease first appears.
10 dl?V •? it^ai-tral c .
OR MAI
Formulated with one or a combination
of: maneb; nethoxychlor, technical;
parathion; malathion; or sulfur.
Issued: 9-16-82
11-008101-10
-------
Site and Pest
/28003AA
FBAAPDZ
FBAMCBM
FBASSBL
FMBCQBB
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Formulatiop(s)
Exempt
Ho preharvest interval through 5.3
pounds per acre.
Bacterial blight
(Pseudomonas)
Early blight
(Cercospora)
Late blight
(Septoria)
Leaf spots
/05002AA
FDAAPDZ
Cherry (sour)
Bacterial canker
(gunmosis)
(Pseudomonas)
Foliar application. Apply in plant
bed or field when plants are 6 inch-
es high or disease first appears.
Repeat at 5 to 14 day intervals as
needed. May be tank mixed with
mancozeb, maneb, or chlorothalonil.
OR MAI
Formulated with one or a combination
of: calcium arsenate; maneb; meth-
ylated napthalenes; carbaryl; para-
thion; malathion; piperonyl butox-
ide, technical; pyrethrins; rotenone
(and other cube resins); sulfur; or
zinc sulfate, basic.
1.0-2.12 Ib/A
or
1.0-2.65 lb/
100 gal
{max. 5.3
Ib/A]
(12.5-532 WP)
(71 WP/D)
(1-4.24 lb/
gal F1C)
or
1.4-3.5 Ib/A
(3.8-82 D)
(72 WP/D)
OR MM
0.7-1.71 lb/
100 gal
(192 WP)
(72 WP/D)
or
0.75-3.5 Ib/A
(3.5-72 D)
(72 WP/D)
Exempt
Do not apply to sveet cherries or
the English Morelo variety as
severe injury will occur.
0.44-1.1 lb/ Postharvest application. To aid in
100 gal the control of bacterial canker,
(222 WP) «pply low rates at beginning of leaf
or fall and high rates at end of leaf
3.9-6.24 Ib/A fall.
(0.39 Ib/gal
or 4.152
F1C)
64
Issued: 9-16-82
II-008101-11
-------
£PA Index to Pesticide Chemicals
BASIC COPPER SULFAIE
Site and Pest
Dosages and Tolerance, Use, Limitations
Poraulation(s)
Cherry (sour) (continued)
fJADHCB
Brown rot blossom
and twig blight
(Wbnilinia)
Brown rot of fruit
(Monilinia)
1.54-2.65 lb/
100 gal
[max. 26.5
Ib/A]
(22-532 WP)
(7Z WP/D)
(3-4.24 lb/
gal F1C)
or
0.51-1.06 lb/
100 gal
or
1.325 Ib/A
(12.5-532 WP)
(4.24 Ib/gal
F1C)
or
Delayed dormant and foliar appli-
cation. Apply at popcorn and late
bloom (add hydrated lime in late
bloom spray) . Add a suitable
spreader-sticker.
OR MAI
Formulated with zinc sulfate, basic
MCCDJ
Cherry leaf spot
(Coccomyces)
;FJAZCEL
Coryneum blight
(shothole)
[dust]
(72 WP/D)
OR M&I
1.52-1.71 lb/
100 gal
(192 WP)
1.06-2.65 lb/ Foliar and postharvest application
100 gal Apply at petal fall (with hydrated
(522 WP) lime). Apply once or twice post-
(3-4.2A lb/ harvest.'
gal F1C)
or
0.51-1.0 lb/
100 gal
or
1.325 Ib/A
(12.5-532 WP)
2.0-3.18 lb/
100 gal
(532 WP)
(3-4.24 lb/
gal F1C)
or
3.9-6.24 Ib/A
(0.39 Ib/gal
cr -.is:
F1C)
Dormant application. Apply as a
dormant spray. Add a suitable
•preader-sti cker.
65
Issued: 9-16-82
11-008101-12
-------
EPA Index to Pesticide Chemicals
/0200QAA
Site and Pest
Citrus Fruits
FMAHPDZ
Bacterial blast
(Pseudomonas)
(in northern CA)
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Liaitatloas
Fonnulation(s)
Exempt
Do not apply later than 3 weeks
after petal fall through 33.92
pounds per acre; or through 0.795
pound per 100 gallons 4 weeks after
that.
Basic copper culfate should not be
applied where copper injury is known
to occur. The use of copper and oil
combinations should be avoided after
the fruit has attained a size of
0.75 inch in diameter and during hot
weather. Application rates and tim-
ing, disease occurrence, and cau-
tions for specific varieties will
vary with locality. A suitable
spreader-sticker may be added.
1.1-2.2 lb/ Foliar application. Apply in Octo-
100 gal ber-November before the first rain.
[max. 30.8 Spray entire tree. Do not apply to
Ib/A] Mandarins until after fruit has been
(222 W?) picked.
FCAJPCN
FMATMCQ
FMCBSBL
FIBLDAD
FIBLDAP
FAABEAH
Brown rot
(gunmosis')
(Phytophthora)
Greasy spot
(Mycosphaerella)
Leaf and fruit spot
(Septoria)
Melanose
(Diaporthe)
Pink pitting of
grapefruit
(Mycosphaerella)
Scab (spot
anthracnose)
(Zlsinoe)
0.25-1.59 lb/
100 gal
[max. 33.92
Ib/A]
(12.5-532
WP)
(1-4.24 lb/
gal F1C)
or
aerial or
concentrate:
5.0-13.25
Ib/A
(50-532 WP)
(3-4.24 lb/
gal F1C)
OR MAI
0.24-1.26 lb/
100 gal
(6.3-192 WP)
(72 WP/D)
(0.48 Ib/gal
or 4.42 F1C)
ox
Foliar and postharvest application.
For brown rot, apply by ground
equipment. Hy^*f»>' H"i< and zinc
sulfate may be added. For brovn
rot and Septoria spot, apply before
rains or at first sign of disease.
Use lowest rate in CA where copper
injury may be a problem or groves
are fumigated with hydrogen cyanide.
Use up to 0.795 pound elsewhere.
For brown rot gumaosis, spray ground
and skirts of trees to a height of
3 to 4 feet, or use a paint-like
mixture on trunk and crown. For
melanose and scab, apply at higher
half of dose range. May be tank
mixed with sulfur. For melanose,
apply up to 0.795 pound, 1 to 3
weeks after petal fall and repeat 4
weeks later if needed. For scab,
apply just before trees begin to
flush and repeat at two-thirds petal
fall. For greasy spot or pink pit-
ting , apply ai lower hail dcsc ra:.^
laaued: 9-16-82
II-008101-13
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Site and Pest
Citrus Fruits (continued)
Dosages and Tolerance. Use. Limitations
Formulation(s)
~~ anytime during the 2 months after
(71 WP/D) expansion of early spring flush and
within 1 month after expansion of
late spring or other flushes; or,
apply 1 summer spray.
OR MAI
Formulated with sulfur; or zinc
sulfate, basic.
MBLCGA
Bed alga
(Cephaleuros)
(in FL)
0.75-0.795
lb/100 gal
(501 UP)
(4.24 lb/
gal F1C)
/0101GAA
FIBFQBB
Cranberrv
Fruit rots
Foliar application. A suitable
spreader-sticker may be added.
Apply in the early summer (June) as
a preventative spray. Repeat in
late summer (early August) to con-
trol new colonies.
Exempt
No preharvest interval through 5.2
pounds per acre.
5.2 Ib/A Use limited to WI.
(522 WP) Foliar application. Apply beginning
in late bloom. Additional applica-
tions may be required. Consult a
State Agricultural Cooperative Ex-
tension Service Agent.
Issued: 9-16-82
11-008101-14
-------
EPA Index to Pesticide Chemicals
Site and Pest
BASIC COPPER SULFATE
Dosages and Tolerance, Use. Limitations
Formulation(s)
'100CQAA
Cucurbits (cucumbers, melons,
pumpkin, squash)
?BATAAX
FMABPDZ
TAAACOP
.'GATEBI
•TABPEA
FBAQMCO
FMBCQBB
FFACEBJ
FEAJCCV
Alternarla leaf
blight
Angular lesf spot
(Pseudomonas)
Anthracnose
(Colletotrichum)
Bacterial wilt
(ETwinia)
Downy mildew
(Pseudopero-
nospera)
Gummy stem blight
(Mycosphaerella)
Leaf spots
Powdery mildew
(Erysiphe)
Scab (Cladosporium)
0.75-2.12
Ib/A
or
0.75-2.65 lb/
100 gal
[max. 6.36
Ib/A]
(12.5-53Z
WP)
(71 WP/D)
(3-4.24 lb/
gal F1C)
or
0.75-3.85
Ib/A
(5-8Z D)
(7Z WP/D)
OR MAI
0.7-1.4 lb/
100 gal
(5-7Z UP/D)
or
0.7-3.5 Ib/A
(3.5-7Z D)
(7Z WP/D)
or
0.06-0.12
Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
No preharvest interval through 6.36
pounds per acre.
Consult a State Agricultural Cooper-
ative Extension Service regarding
the addition of hydrated lime.
Soil or foliar application. A soil
application after planting but be-
fore emergence may help decrease in-
fections of angular leaf spot, an-
thracnose, and Alternaria leaf spot.
Otherwise, apply at lower rates when
plants emerge or begin to vine, or
before diseases appear. Repeat ac
7 to 10 day intervals (or more fre-
quently if needed), increasing to
higher rates for maturing high plant
populations (40,000 plants per
acre). A 7 percent dust may be
mixed with zineb.
OR MAI
Formulated with one or a combination
of: lindane (gamma isomer of ben-
zene hexachloride); calcium arsen-
ate; maneb; methoxychlor, technical;
methylated naptualcues; carbaryl;
parathion; malathion; 0,0-diethyl
0-(2-isopropyl-6-methyl-4-pyriEi-
dinyl) phosphorothioate; piperonyl
butoxide, technical; pyrethrins;
rotenone (and other cube resins);
endosulfan; or sulfur.
Issued: 9-16-82
11-008101-15
-------
/010L2AA
/Q013AA
fttAPEB
Site and Pest
Currant
Gooseberry
Anthracnose
(Pseudopeziza)
Leaf spots
EPA Index to Pesticide Chemicals
BASIC COPPER SCLFATE
Dosages and Tolerance, Use. Limitations
Formulatioa(s)
Exempt
UP pr . ...... .,..,.,._~, i through 0.7
pound per 100 gallons; or through
'11001 AA
FUACff
ffttPAD
MCQBB
BiAPBU
Devberry
Eggplant
Anthracnose
(Colletotrichum)
Downy mildew
(Peronospora)
Early blight
(Alternaria)
Leaf spots
Phomopsis blight
7.42 *w
bloom.
2 seeks after
0.66-0.7 lb/
100 gal
(12.7 5-5 3Z
WP)
OR
3.125-3.18
lb/100 gal
[max. 7.42
Ib/A]
(50-532 WP)
See Blackberry cluster.
Foliar application. Apply at leaf
opening."Repeat at 10 to 14 day
intervals.
OR
Foliar and postharvest application.
Apply at full bloom, 2 weeks later,
and after harvest.
1.0-2.12 Ib/A
or
0.93-2.12
lb/100 gal
[aax. 3.445
Ib/A]
(52-532 WP)
(3-4.24 lb/
gal F1C)
or
2.1-3.6 Ib/A
(7-82 D)
OR MAI
0.7-1.* lb/
100 gal
(72 WP/D)
or
0.875-3.5
Ib/A
(3.4-7Z D)
(7Z WP/D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.42)
Exempt
No preharvest interval through 3.5
pounds per acre.
Foliar application. Apply in plant
bed or in field before disease
appears. Repeat at 7 to 10 day
intervals.
OR MAI
Fonn'jT**'0'* «H*K ««» or a combination
of: maneb; methoxychlor, technical;
methylated napthalenes; carbaryl;
malathion; piperonyl butoxide, tech-
nical; pyrethrins; rotenone (and
other cube resins); or sulfur.
69
Issued: 9-16-82
11-008101-16
-------
/03005AA
PBAAXAA
Site and Pest
Pilbert
Bacterial blight
(Xanth omona s)
EPA Index to Pesticide Chemicals
BASIC COPPER SOLFATE
Dosages and Tolerance, Use. Limitations
Pormulaticm(s)
Exempt
Postharvest application through 3.18
pounds per 100 gallons.
3.12-3.18 lb/ Postharvest application. Apply by
/01014AA
FAAAEAH
PIADMAV
FIHFGBG
PFA35PCV
Gooseberrv
Grapes
Anthracnose
(Elsinoe)
Bitter rot
(Melaneonivm)
Black rot
(Guignardia)
Downy mildew
(Plasmopara)
100 gal
(50-52Z WP)
(4.24 Ib/gal
nc)
ground equipment. Add a suitable
spreader-sticker. Apply in late
August - early September before
first heavy rain. If heavy fall
rains occur, repeat spray after
three-quarters of leaves have drop-
ped.
See Currant cluster.
1.0-1.59 lb/
100 gal
[max. .4.24
Ib/A]
(12.5-53Z WP)
(4.24 Ib/gal
F1C)
or
0.5 lb/
100 gal
(3 Ib/gal
PIC)
or
1.4-3.5 Ib/A
(6-71 D)
or
concentrate:
2.12-2.65
Ib/A
(53Z WP)
(4.24 Ib/gal
PIC)
or
1.0-1.59 Ib/A
(3-4.24 lb/
gal PIC)
OR MM
0.7-1.4 lb/
ICC gal
(7Z WP/D)
or
Exempt
Ho preharvest interval through 4.24
pounds per acre.
Delayed dormant and foliar appli-
cation. Apply when nev growth is
0.5 inch long. Repeat at 10 to 14
day intervals. The addition of
hydrated lime may be recommended.
OR M&I
Formulated with maneb; methoxychlor,
technical; carbaryl; parathion;
rotenone (and other cube resins);
or sulfur.
70
Issued: 9-16-82
II-008101-17
-------
Site and Pest
Crapes (continued)
FliRBAW
Bunch rot
(Botrytis)
FDAKEY
"ACUAS
/0802QAA
Dead arm
(Cryptosporella)
Powdery mildew
(Uncinula)
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use, Limitations
Formulation(s)
1.75-3.5 Ib/A
(3.5-72 D)
(72 WP/D)
1.06 Ib/A Foliar application. Mix with aul-
[dust] fur. Add zinc sulfate. Apply at
(532 WP) buckshot stage. Repeat monthly
until harvest.
1.99 lb/ Delayed dormant application. Add
100 gal hydrated lime. Apply as soon as
(532 WP) green tips show.
MPEA
Dovny mildew
(Pseudoperono-
•pora)
2.65-3.18 lb/ Foliar application. Prepare dust
A [dust] with a suitable diluent. Apply when
(532 WP) disease appears.
Exempt
Two week preharvest interval through
1.04 pounds per 100 gallons as a
spray or 4.0 pounds per acre as a
dust.
1.04 lb/
100 gal
(522 WP)
or
1.0 Ib/A
(3 Ib/gal
F1C)
3.2-4.0 Ib/A
(82 D)
Foliar application. Apply as a
crown treatment (after pruning but
before training). Additional treat-
ments at 10 day intervals may be
needed.
71
Issued: 9-16-82
11-008101-18
-------
/13020AA
FAAA3AB
FFABBBA
FMBCCBM
Site and Pest
Lettuce
Anthracnose
(Marsonnina)
Downy mildew
(Bremia)
Leaf spot
(Cercospora)
/06007AA
FAAAGAP
FEAJEAB
Anthracnose
(Glomerella)
EPA Index to Pesticide Chemicals
BASIC COPPER SDLFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 2.65
pounds per acre.
0.93-1.59 IV Foliar application. Apply before
100 gal
(max. 2.65
Ib/A]
(19-53Z WP)
or
0.26 lb/
100 gal
(521 HP)
or
1.52-2.27
Ib/A
(3.8-6.3Z D)
OR MM
0.0525-0.0875
lb/1,000
• q.ft
(7Z D)
See Blackberry cluster.
diaease appears. Repeat at 7 to 10
day intervals.
OR MAI
Formulated with carbaryl.
1.5-2.12 IV
100 gal
Scab (spot anthrac- (50-53Z WP)
nose) (Elsinoe) (4.24 Ib/gal
nc>
/05003AA nectarine
/05004AA Peach
FGAYQAA Bacterial diseases
(on peach)
1.5-2.12 IV
100 gal
(50-53Z WP)
(4.24 Ib/gal
ric>
or
Exempt
Ho preharvest interval through 2.12
pounds per 100 gallons.
Foliar application. Apply when
first bloom clusters have appeared.
Repeat weekly until fruit sets and
then spray monthly for a total of 5
to 12 applications depending upon
area.
Exempt
Do not apply after pink bud or
after trees are in leaf through
15.84 pounds per acre.
Dormant application. Add a suitable
spreader-sticker. Apply during
dormant season.
72
Issued: 9-16-82
II-008101-19
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATZ
Dosages and Tolerance, Use. Limitations
Formulation(s)
Nectarine cluster (continued)
1.0 lb/
100 gal
(3 Ib/gal
PIC)
iPIADMCB
EAGTAB
fJAZCEL
Brovn rot blossom
and twig blight
(Monilinia)
Leaf curl
(Taphrina)
Shothole
(Coryneum blight)
1.54-3.18 lb/
100 gal
[max. 15.84
Ib/A]
(12.5-532 WP)
(4.24 lb/
gal F1C)
or
1.0-1.5 lb/
100 gal
(0.39 Ib/gal
or 4.42 PIC)
(3 Ib/gal
F1C)
or
concentrate:
4.24-8.48
Ib/A
(50-532 WP)
(4.24 Ib/gal
PIC)
or
3.0-4.0 Ib/A
(3 Ib/gal
PIC)
or
CA, aerial,
dormant:
8.0-10.6 lb/
20 gal/A
(50-532 WP)
or
4.75-9.5 Ib/A
(192 WP)
OR MAI
1.52-1.71 lb/
100 gal
(191 WP)
or
1.02-1.36
Ib/A
(3.42 D)
Dormant and delayed dormant appli-
cation. Add a suitable spreader-
sticker. For leaf curl and shot-
hole, during the dormant season
(before fall rains). For brown rot
and shothole, apply before bud swell
and in full pink bud stage.
OR MAI
Formulated with zinc sulfate, basic;
or carbaryl and sulfur.
Issued: 9-16-82
II-008101-20
-------
/28014AA
Site and Pest
Olive
EPA Index to Pesticide Chemical*
BASIC COPPER SULFATZ
Dosages and Tolerance, Use, Limitations
Formulations)
Exempt
Ho preharvest interval through 6.36
pounds per acre.
In areas with 10 inches or less
rainfall per year, use up to 1.06
pounds per 100 gallons.
FMBHCFK
Peacock, spot
(Cyclocloniua)
/14011AA
FFABPAO
FMBCQBB
FCAEAAX
Onion
Downy mildew
(Peronospora)
Leaf spots
Purple blotch
(Alternaria)
/06010AA
PAAACEP
Papaya
Anthracnose
(Colletotri chu=}
Peach
Issued: 9-16-82
2.12-4.24
Ib/A
or
0.44-3.18 lb/
100 gal
[max. 6.36
Ib/A]
(22-532 WP)
(3-4.24 Ib/gal
F1C)
Foliar application.
October.
Apply in late
Exempt
Ho preharvest interval through 3.5
pounds per acre.
Foliar application. Apply when
plants are 4 to 6 inches high.
Repeat at 7 to 10 day intervals.
Mix the 7 percent dust formulation
with sulfur, cr sszcb, zineb, or
thiram.
OR MAI
Formulated with one or a combination
of: maneb; parathion; nalathion;
0,0-diethyl 0-(2-isopropyl-6-methyl-
4-pyrimidinyl) phosphorothioate; or
sulfur.
1.0-2.12 Ib/A
or
0.93-1.59
lb/100 gal
[max. 3.445
Ib/A]
(19-53Z WP)
(3-4.24 lb/
gal F1C)
or
1.14-3.5 Ib/A
(3.8-72 D)
OR MAI
0.0875-3.5
Ib/A
(3.5-72 D)
Exempt
Ho preharvest interval through 0.795
pounds per 100 gallons.
0.795 lb/ Foliar application. Apply before
100 gal disease is expected to appear. Re-
(532 WP) peat at 10 to 14 day intervals or
•t 5 to 7 day Intervals during
periods of heavy rainfall.
See Nectarine cluster.
11-008101-21
74
-------
EPA Index to Pesticide Chemicals
I28015AA
SKCBM
Site and Pest
Peanuts
Cercospora leaf
spot
/04003AA
FAAANAK
FMPNAX
(HAHPDZ
Pear
Anthracnose
(Neofabraea)
Perennial canker
(Meofabraea)
Bacterial blight
(Pseudomonas)
BASIC COPPER SULFATE
Dosages and Tolerance, Use. Limitations
Formulation(s)
Exempt-
No preharvest interval through 2.12
pounds per acre.
0.75-2.12
Ib/A
(52-53* WP)
(1-4.24 lb/
gal F1C)
or
0.73-1.24
Ib/A [dust]
(52-532 WP)
OR MAI
0.24-0.4 Ib/A
(41 WP)
(0.11-0.53
Ib/gal F1C)
(0.48 Ib/gal
or 4.42 F1C)
or
0.51-1.02
Ib/A
(3-42 D)
or
1.2-1.6 Ib/A
(42 D)
Foliar application. Sprays may be
tank nixed with sulfur. When dust-
ing is preferred, mix with sulfur.
Apply when disease appears. Repeat
at 10 to 14 day intervals.
OR MAI
Formulated with sulfur; or carbaryl
and sulfur.
Exempt
No preharvest interval through 1.99
pounds per 100 axres.
2.0 lb/
100 gal
(502 WP)
Postharvest application.
•uitable oil spreader.
Add a
1.5-2.625 lb/ Postharvest and dormant application.
100 gal Apply before fall rains and again
(3 Ib/gal at dormant before spring growth
F1C) starts.
HAQNAK
Bullseye rot
(Neofabraea)
1.99 lb/ Foliar application. Apply before
100 gs1 harvest. Add a suitable oil
(532 WP) spreader.
7'J
Issued: 9-16-82
11-008101-21
-------
FBANEBI
Site and Pest
Pear (continued)
Fire blight
(Ervinia)
FBATFAA
FEAJVAG
Leaf blight
(Fabraea)
Pear scab
(Venturia)
/28016AA
FFABPAU
FMBCQBB
Peas
Downy mildew
(Peronospora)
Leaf spots
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use. Limitations
Fonnulation(s)
0.125-0.27
lb/100 gal
[400 gal/A]
(12.75-532
WP)
(3-4.24 lb/
gal F1C)
or
0.75-1.89
Ib/A
(3-6.71 D)
OR MAI
0.19-0.285
lb/100 gal
[max. 1.14
Ib/A]
(19Z WP)
(0.48 Ib/gal
or 4.42 F1C)
0.66-1.0 lb/
100 gal
(12.52 WP)
(72 »/D)
or
(72 HP/D)
1.89 Ib/A
(6.32 D)
Foliar application. May be applied
in concentrate sprayers. Apply at
10 percent bloom. Repeat at 5 to 7
day intervals during bloom.
OR MAI
Formulated with sulfur; or zinc
sulfate, basic.
Foliar application. Add hydrated
lime. Apply in first 3 cover
sprays.
Delayed dennant and foliar applica-
tion. For scab, apply in cluster
bud, bloom and petal fall or at
other times prior to rain.
Exempt
No preharvest interval through 3.18
pounds per acre.
0,93-1.59 lb/ Foliar application. Apply before
100 gal diseases appear. Repeat at 7 to 10
[up to 200 day intervals.
gal/A} OR MAI
(532 WP) Formulated with carbaryl and roten-
OR MAI one (and other cube resins).
(72 D)
76
Issued: 9-16-82
11-008101-23
-------
FFACEBJ
/03008AA
BAJCCV
/28017AA
FAAACDP
FMAAXAA
FFABPAU
FBAMAAX
MBCCBM
RiAVCBM
FBAAPCH
Site and Pest
Peas (continued)
(Blackeyed)
Powdery mildew
(Erysiphe)
Pecan
Pecan scab
(Cladosporium)
Peppers
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use, Limitations
Fonnulation(s)
1.04-1.56 Foliar application. Apply at first
lb/100 gal sign of disease. Repeat at 7 day
(521 WP) intervals.
Exempt
Ho preharvest interval through 1.06
pounds per 100 gallons.
1.06 lb/ Foliar application. Apply as a
100 gal foliar spray according to current
(53Z WP) state schedule for timing and
limits.
0.75-0.765 Foliar application. Apply when
tbls catkins show. Repeat 3 to 4 times
«ctual*/gal at 3 week intervals.
(12.5-12.752
WP)
Exempt
No preharvest interval through 5.0
pounds per acre.
Antnracnose
(Colletotrichum)
Bacterial spot
(Xanthomonas)
Downy mildew
(Peronospora)
Early blight
(Alternaria)
Leaf spot (frogeye
leaf spot)
(Cercospora)
Phytophthora blight
1.0-2.12 Ib/A
or
1.0-2.5
lb/100 gal
[max. 5.0
'
(33-532 WP)
(1-4.24 lb/
gal F1C)
or
2.1-3.6 lb/A
(7-82 D)
OR MAI
2.12 lb/
100 gal
(30.252 WP)
or
0.875-3.5
lb/A
(3.4-72 D)
or
0.24 lb/A
Foliar application. Apply in seed
bed before disease appears and con-
tinue in the field at 7 day inter-
vals.
OR MAI
Formulated with one or a combination
of: maneb; methoxychlor, technical;
carbaryl; malathion; rotenone (and
other cube resins); sulfur; endo-
•ulfan; or cap tan.
or 4.47 F1O
77
Issued: 9-16-82
11-008101-24
-------
Site and Pest
'05005AA
'05006AA
?EAADAS
Black knot
(Dibotryon)
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Pse. Limitations
Fotmulation(s)
Exempt
Do not apply later than second cover
through 6.36 pounds per acre.
1.06-1.59 lb/ Delayed dormant and foliar applica-
100 gal tion. Add hydrated line. Apply at
[sax. 6.36 green tip stage. Repeat at shuck-
Ib/A] shed and in 2 cover sprays if dis-
(532 WP) ease is serious.
FBADMCB
FMBCCjBB
FBADMCB
FBAZCEL
Brown rot blossom 0.795-1.325 Delayed dormant and foliar applica-
blight (Monilinia) lb/100 gal tion. Add hydrated line. Apply
Leaf spot (12.5-53Z WP) Apply just before blossoms open.
Repeat at shuck split and again in
2 to 3 weeks.
Brovn rot
(Monilinia)
Shothole
(Coryneum blight)
2.08-3.18 lb/
100 gal
[max. 13.25
Ib/A]
(52-532 WP)
(4.24 Ib/gal
F1C)
or
1.0-1.5 lb/
100 gal
(3 Ib/gal
F1C)
or
concentrate:
6.36 Ib/A
(532 WP)
(4.24 Ib/gal
F1C)
or
3.0 Ib/A
(3 Ib/gal
F1C)
or
Dormant, delayed dormant, and folia:
application. Add a suitable sprea-
der-sticker. Apply in dormant sea-
son." For brown rot, also apply at
greenbud to full bloom.
OR MAI
Formulated with zinc sulfate, basic.
78
Issued: 9-16-82
II-008101-25
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Pormulation(s)
Plum cluster (continued)
/14013AA Potato
FBAMAAX Early blight
(Alternaria)
FBASPCN Late blight
(Phytophthora)
CA, aerial,
dormant:
8.48-10.6
Ib/A
(532 WP)
(4.24 Ib/gal
F1C)
or
4.0-5.0 Ib/A
(3 Ib/gal
PIC)
OR MM
1.52-1.71 lb/
100 gal
(192 WP)
1.5-3.18 Ib/A
or
1.0-2.65
lb/100 gal
[nax. 6.36
Ib/A]
(12.5-532 WP)
(72 WP/D)
(3-4.24 lb/
gal F1C)
or
1.05-4.2 Ib/A
(6.3-82 D)
(72 WP/D)
OR MAI
0.7-1.4 lb/
100 gal
(72 WP/D)
or
0.7-3.9 Ib/A
(3.4-72 D)
(72 WP/D)
or
0.24-0.36
Ib/A
(0.48 Ib/gal
or A.£! F1C)
Exempt
No preharvest interval through 6.36
pounds per acre.
Foliar application. Apply when
plants emerge. Repeat at 7 to 10
day intervals or more often for
severe late blight.
OR Mil
Formulated with one or a combination
of: calcium arsenate; maneb; met'n-
ozychlor, technical; methylated
napthalenes; carbaryl; parathion;
malathion; 0,0-diethyl 0-(2-iso-
propyl-6-methyl-4-pyrimidinyl)
phosphorothioate; piperonyl butox-
ide, technical; pyrethrins; rotenone
(and other cube resins); sulfur; or
•ndosulfan.
Issued: 9-16-82
11-008101-26
-------
EPA Index to Pe*ticide Chemicals
Site and Pest
Prune
BASIC COPPER SULFATZ
Dosages and Tolerance. Use, Limitations
Fonnulation(s)
See Plum cluster.
/28072AA
FMAHPCR
FMBCHAM
FMIHRAM
FLAKE AZ
FMBCCBM
FBBMRAM
FICHSAS
/28023AA
FAAAGAP
FICHCBF
FBAYDA?
FMAVCBM
See Blackberry cluster.
Exempt
Ho preharvest Interval
pound per acre.
through 0.24
Blast (Pirlcularia)
Brown leaf spot
(Bftlmintho sporium)
Brown bordered leaf
and sheath spot
(Bhizoctonia)
Leaf smut
(Entyloma)
Harrow brown leaf
spot (Cercospora)
Sheath blight
(Bhizoctonia)
Stem rot
(Sclerotium)
Soybeans
Anthracnose
(Glomerella)
Brown stem rot
(Cephalosporiua)
Diaporthe pod and
stem blight
Leaf spot
(Cercospora)
0.24 Ib/A Foliar application. As an aid in
(0.48 Ib/gal disease control, apply at panicle
or 4.42 F1C) initiation. Repeat at 14 day inter-
rals.
Formulated with sulfur.
Exempt
Ro preharvest interval through 0.24
pound per acre.
0.24 Ib/A Foliar application. As an aid in
(0.48 Ib/gal disease control, apply at pcci are
or 4.42 F1C) one-eighth to one-half inch long
(early pod set). Repeat at 10 to
14 day intervals throughout the
growing season.
Formulated with sulfur.
Issued: 9-16-82
11-008101-27
-------
EPA Index to Pesticide Chemicals
/13024AA
ffABPAO
BBCCBM
FGASAAV
Site and Pest
Spinach
Anthracnose
(Colletotrichum)
Downy mildew
(blue mold)
(Peronospora)
Leaf spot
(Cercospora)
White rust
(Albugo)
/01016AA
HAAOT
FTABPAD
FMTDAH
FGAKDBS
WBCMCO
S trawberry
Anthracnose
(Colletotrichun)
Downy mildew
(Peronospora)
Leaf blight
(Dendrophoma)
leaf scorch
(DLplocarpon)
leaf spot
(Mycosphaerella)
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 3.2
pounds per acre.
1.0-2.12 Ib/A Foliar application. Apply before
or when disease first appears.
Bepeat at 7 to 10 day intervals.
OR MAI
Formulated with one or a combination
of: carbaryl; sulfur; or maneb and
sulfur.
[max. 150
gal/A]
(52-53Z WP)
(3-4.24 lb/
gal F1C)
or
2.4-3.2 Ib/A
(6.3-8Z D)
OR MAI
1.25-3.5 Ib/A
(5-72 D)
or
0.24 Ib/A
(0.48 Ib/gal
or 4.42 F1C)
Exempt
No preharvest interval through 3.975
pounds per acre.
1.06-2.12 lb Delayed dormant and postharvest
100 gal applicawiwu. auu uj-i.ai.ed lime.
(532 WP) Apply 1.06 to 1.59 pounds pre-
blossom, and 1.59 to 2.12 pounds
postharvest.
1.0-2.12 lb/
100 gal
[max. 3.975
Ib/A]
(12.5-532 WP)
(3-4.24 lb/
gal F1C)
(72 WP/D)
or
2.205-3.15
Ib/A
(6.32 D)
(72 WP/D)
OR MM
0.7 lb/
100 gal
(?: '^.^
or
Delayed dormant and foliar appli-
cation. Apply after leaves form at
10 to 14 days intervals.
OR MAI
Formulated with, carbaryl; rotenone
(and other cube resins); or carbaryl
and sulfur.
81
Issued: 9-16-82
II-008101-2c
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use. Limitations
Fonnulation(s)
Strawberry (continued)
/2802QAA
FFABPAU
FMBCCBM
Sugar Beets
Downy mildew
(Peronospora)
Leaf spot
(Cercospora)
/26003DA
FMABPDZ
FGASPD2
FGASPDZ
Tobacco
Angular leaf spot
(Ps eud omoaa s)
Wildfire
(Pseudomonas)
Wildfire
(Pseudomonas)
1.02-3.04
Ib/A
(3.4-71 D)
(7Z WP/D)
Btempt
Ho preharvest interval through 3.18
pounds per 100 gallons.
1.0-3.18 Ib/A Foliar application. Apply when
or
2.04-3.18
lb/100 gal
(50-5 3Z WP)
(3-4.24 lb/
gal F1C)
OR MM
0.24-0.48
Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
plants are 4 to 6 inches high or
when disease first appears. Repeat
at 7 to 10 day intervals.
OR MAI
Formulated with sulfur.
0.4 lb/25
ga1/100
sq.yd
(532 WP)
N.F.
No preharvest interval through 2.12
pounds per 100 gallons.
Use limited to IN, KY, OH, and TN.
Foliar application to plant beds.
Using a sprinkler can, apply when
plants are in 2-leaf stage and again
in 7 to 10 days.
0.53 lb/10 Soil and foliar application to plant
gal/100 beds. Apply after sowing seed or
• q.ft when plants emerge. Repeat at 5 to
or 10 day intervals until transplanted.
1.59-2.12 lb/
100 gal
(53Z WP)
Issued: 9-16-82
11-008101-29
-------
/11005AA
fiAAGAP
IMACEI
JHBPPDZ
Site and Pest
Tomato
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
Mo preharvest interval through 6.36
pounds per acre.
ffliGCCV
F1AMAAI
BASPCN
BBCSBL
FHBCSDG
JHEAAX
Anthracnose
(Glomerella)
Bacterial canker
(Corynebacterium)
Bacterial speck
(Pseudomonas)
Bacterial spot
(Xanthomonas)
dadosporlum leaf
mold
Early blight
(Alternaria)
Late blight
(Phytophthora)
Leaf spot
(Septoria)
Leaf spot
(Stemphylium)
Railhead spot
(Altemaria)
1.0-3.18 Ib/A
or
1.0-2.625
lb/100 gal
[max. 6.36
Ib/A]
(12.5-53Z WP)
(7Z WP/D)
(1-4.24 IV
gal F1C)
or
1.05-4.2 Ib/A
(6.3-8Z D)
(7Z WP/D)
OR HM
0.7-2.12 lb/
100 gal
(30.25Z WP)
(5-7Z WP/D)
or
0.875-3.9
Ib/A
(3.4-7Z D)
(5-7Z WP/D)
or
0.24-0.36
Ib/A
(0.48 Ib/gal
or 4.4Z F1C)
Foliar application. Apply in plant
bed or field before disease appears.
Repeat at 4 to 14 day intervals.
May be tank mixed mancozeb, maneb,
2,4-dichloro-6-(o-chloroanilino)-s-
triazlne, or chlorothalonil.
OR MAI
Formulated with one or a combination
of: calcium arsenate; maneb;
methoxychlor, technical; methylated
napthalenes; carbaryl; parathion;
malathion; 0,0-diethyl 0-(2-iso-
propyl-6-methyl-4-pyrimidiny 1)
phosphorothioate; piperonyl butox-
ide, technical; pyrethrins; rotenone
(and other cube resins); sulfur;
endosulfan; or captan.
/28024DA
FKAAQBB
Vegetables (seedlings)
Damping—off
4.24 Ib/A
or
2.12 lb/
100 gal
(53Z WP)
Exempt
Plant bed application through 2.12
pounds per 100 gallons.
Soil and foliar application to plant
beds. Apply to soil surface in
plant beds after emergence. Repeat
at 4 to 7 day intervals as needed.
Issued: 9-16-82
faj
11-008101-30
-------
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance. Use. Limitations
Formulation(s)
03009AA Walnut
'BAAXAA Bacterial blight
(Xanthomonas)
'28065AA
•CADHAM
•MBCSBL
FJACPEJ
Wheat
Helminthosporium
leaf spot
Septoria leaf spot
Leaf rust
(Puccinia)
1.0-2.65 lb/
100 gal
[max. 23.85
Ib/A]
(50-532 WP)
(4.24 Ib/gal
F1C)
or
2.0-3.15
Ib/A
(5-6.31 D)
1.04 lb/
100 gal
(522 WP)
Exempt
Ho preharv
-------
/28072AA
FKAAQBB
FKABQBB
/28065AA
PLAITAQ
Site and Pest
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Rice (water planted rice seed)
Exempt
Seed treatment through 1.06 ounces
per 100 pounds seed.
Damping-off
Seed rot
Soybeans (seed)
Wheat (seed)
1.0-1.06 oz/ Seed treatment. Apply as a slurry
100 Ib seed using tumblers or mixing devices
(50Z WP) generally used.
(4.24 Ib/gal
F1C)
See Cotton (seed) cluster.
Exempt
Seed treatment through 2.12 ounces
per bushel.
Common bunt/stink- Spring wheat: Seed treatment. Apply as a dry mix
ing smut 1.06 oz/bu to seed..
(Tilletia) or
Winter wheat:
1.59 oz/bu
or
Infested win-
ter wheat:
2.12 oz/bu
(532 WP)
/3502IAA
/350aDA
/31026AA
/31026DA
FBAAQBB
FB4ECEL
WBCQBB
ORNAMENTALS
(Ornamental Plants (herbaceous plants and bulbs; woody shrubs, trees an:
vines) )
Arbor vitae
Aster
Blight
Coryneum twig
blight
Leaf spots
1.0-2.915 Ib/ Foliar application. Apply in early
100 gal/A fall. Repeat in late fall.
(12.5-53Z WP)
or
2.12 Ib/A
[dust]
(53Z WP)
Issued: 9-16-82
II-008101-32
-------
EPA Index to Pesticide Chemicals
Site and Pest
BASIC COPPER SULFATE
Dosages and Tolerance, Use. Limitations
Pormulation(s)
/3500QAA
/35000DA
/31003AA
/31003DA
/34000AA
/34000DA
Ornamental and/or Shade Trees
(including Arborvitae, Cedar,
Cypress, Dogwood, Elm, Juniper,
Linden, Maple, Oak, Pine, Spruce,
Sycamore, Tuliptree, Willow, and
Tew)
Ornamental Flowering Plants
(including Aster, Begonia,
Carnation, Chrysanthemums,
Dalhias, Delphinium, Geranium,
Gladiolus, Hollyhock, Iris,
Lilies, Marigolds, Nasturtium,
Pansies, Peonies, Phlox, Snap-
dragon, Stocks, Sweet Pea, Tulips,
Violets, and Zinnia)
Ornamental Woody Shrubs and Vines
(including Azalea, Barberry, Box-
wood, Camellia, Gardenia, Haw-
thorn, Ivy, Laurel, Lilac,
Rhododendron hybrids/cultivars,
Rose, and Virginia Creeper)
FAAAOjBB
FBZAPDZ
FMCZPDZ
FDAEPCB
FMAEDBS
FBAABAW
PJAFGBI
FBAACEL
FDACPCN
FFABQBB
FBATQBB
FEAFTAB
FCADQBB
FEAHEBP
FGAKSBL
Anthracnose
Bacterial blight
(Pseud omonas)
Bacterial leaf spot
( Pseudomooas)
Black canker
(Physalospora)
Black spot
(DLplocarpon)
Botrytis blight
Cedar-apple rust
(Gymnosporangium)
Coryneum blight
Dleback
(Phytophthora)
Downy mildew
Leaf blights
Leaf blister
(Taphrina)
Leaf blotch
Leaf gall
(Exobasidiua)
Leaf scorch
(Septoria)
1.0-2.12 lb/
100 gal
(12.5-532 HP)
(72 WP/D)
or
2.0-2.12
Ib/A
(7-82 D)
(72 WP/D)
OR MAI
0.31-1.4 lb/
100 gal
(3.7-72 WP/D)
or '
0.51-2.0 Ib/A
(3.4-52 D)
(3.7-72 WP/D)
Foliar application. Apply before
diseases appear. Repeat at 7 to 10
day intervals and after rains. For
anthraenose on sycamore, apply at
first budding. Repeat as full
coverage spray 10 to 14 days later.
For bacterial blight of lilac, apply
in September and again before fa-1
rains. For bacterial leaf spot on
barberry, apply when leaves appear.
Repeat 2 to 3 times 10 days apart.
For black canker of willow, apply
when new leaves are one-quarter inch
long. Repeat in 2 weeks. For
botrytis blight of peonies, Apply
before shoots are 1 foot tall.
Repeat in 2 weeks, and again if any
signs of bud blast appear. For
cedar-apple rust of cedar and jun-
iper, apply in July-August. For
leaf blister of elm and oak, apply
before growth begins or as leaves
uncurl. For leaf gall of azales,
apply to entire plant before buds
Issued: 9-16-82
86
11-008101-33
-------
EPA Index to Pesticide Chemicals
SfBCqBB
FDAAVAL
FIAVQBB
FFACQBB
FMQLAS
F1AEQBB
FICUQBB
BASIC COPPER SULFATE
Site and Pest Dosages and Tolerance. Use, Limitations
Formulation(s)
Ornamental and/or Shade Trees cluster (continued)
Pest list continued from the previous page.
Leaf spots
Nectria canker
(Volutella)
Needle cast
Powdery mildew
Stem canker
(Leptosphaeria)
Twig blight
Wound rot and decay 2.121 metal-
lic copper
paste
(53Z WP)
break in spring. Ke^eat 2 to 3
veeks later.
OR MAI
Formulated with one or a combination
of: llndane (gamma isomer of ben-
zene hexachloride); zineb; methyla-
ted napthalenes; carbaryl; piperonyl
butoxide, technical; pyrethrins;
rotenone (and other cube resins);
or sulfur.
Tree wound application. Mix with
phenol. Apply paste with a spatula
to previously cleaned wound area.
/35097AA
/35097DA
Palm
FAUCI?
FUEGAT
FMBCQBB
/3115SAA
/31155DA
FHBCXAA
Anthracncse
(Colic to trichina)
False smut
(Graphiola)
Leaf spots
Scab
Philodendron
2.12 lb/ Foliar application. Apply to wet
100 gal above ground parts at first sign of
(12.5-531 OP) disease. Repeat as needed.
Bacterial leaf
(Xanthomonas)
spot
1.04 lb/ Foliar application. Tank mix with
100 gal mancozeb. Apply when diseases ap-
(522 WP) pear. Repeat at 7 to 10 day inter-
vals.
(Lawns and Turf (including ground cover))
/33010AA Ornamental Lawns
FMAXPCR Gray leaf spot
(Piricularia)
(in FL)
1.06 lb/
100 gal/A
(46.25-53J
WP)
or
2.12 lo/
100 gal
(532 WP)
Foliar application. Apply before
or at first sign of disease. Repeat
at 10 to 14 day intervals as needed.
87
Issued: 9-16-82
II -00 8101-3'*
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Site and Pest Dosages and Tolerance, Use, Limitations
Pormulation(s)
AERIAL AND TANK MIX APPLICATIONS
9001500 Aerial Application
AAAAAAA
— Refer to
AGRICULTURAL CROPS
All sites except Filbert, Walnut
9900300 Tank Mix
AAAAAAA
— Refer to
AGRICULTURAL CROPS
Celery, Curcurbits, Grapes, Onion,
Peanuts, Tomato
ORNAMENTAL PLANTS
(Ornamental Plants (herbaceous plants and bulbs;
voody shrubs, trees and vines)
Ornamental and/or Shade Trees,
Philodendron
Issued: 9-16-82 11-008101-35
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation
531 technical chemical
basic copper sulfat* (008101)
035896-00004
21 dust
basic copper sulfate (008101), maneb (014505) plus sulfur (077501)
003743-00189
31 dust
basic copper sulfate (008101)
000802-00364
basic copper sulfate (008101) plus sulfur (077501)
009859-00094 009859-00095
basic copper sulfate (008101), earbaryl (056801) plus sulfur (077501)
009859-00096
3.41 dust
basic copper sulfate (008101) plus sulfur (077501)
005905-00322 006735-00163 009779-00023 009779-00106
009779-00121
basic copper sulfate (008101), earbaryl (056801) plus sulfur (077501)
001842-00199 001842-00207 001990-00463 006735-00164
006735-00166 009779-00060 009779-00062 009779-00112
3.5Z dust
basic copper sulfate (008101) plus maneb (014505)
000595-00286
basic copper sulfate (008101), maneb (014505) plus parathlon (057501)
000595-00257 000595-00291
basic copper sulfate (008101) , maneb (014505) plus nalathion (057701)
000595-00234
basic copper sulfate (008101), maneb (014505) plus 0,0-diethyl
0-(2-isopropyl-6-methyl-4-pyrimidinyl) phosphorothioate (057801)
000595-00277
3.8Z dust
basic copper sulfate (008101)
005967-00107
89
Issued: 9-16-82 11-008101-36
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
AI dust
basic copper sulfate (008101)
000802-00492
basic copper sulfate (008101) plus sulfur (077501)
001191-00278 002124-00054 002460-00002 003342-00028
003743-00201 004139-00005 009859-00080
4.51 dust
basic copper sulfate (008101), maneb (014505) plus parathion (057501)
034704-00172
5Z dust
basic copper sulfate (008101)
002124-00473 005967-00129
basic copper sulfate (008101) plus lindane (gamma isomer of benzene
hexachloride) (009001)
002917-00054
basic copper sulfate (008101) plus methoxychlor, technical (034001)
000595-00317 002393-00243 034704-00137
basic copper sulfate (008101) plus rotenone (and other, cube resins)
(071003)
001159-00039 002393-00218
basic copper sulfate (008101), maneb (014505) plus r-lfur ("77501)
046946-00020
basic copper sulfate (008101), piperonyl butoxide, technical (067501),
pyrethrins (069001), rotenone (and other cube resins) (071003) plus
sulfur (077501)
000419-00092 000419-00103
62 dust
basic copper sulfate (008101)
000279-02722
basic copper sulfate (008101) plus carbaryl (056801)
000327-00127
basic copper sulfate (008101), carbaryl (056801) plus parathion (057501)
002124-00634
6.25Z dust
basic copper gulfate (008101) plus carbaryl (056801)
003743-00333
90
Issued: 9-16-82 11-008101-37
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
;
6.31 dust
basic copper sulfate (008101)
000239-00129 000279-01266
6.71 dust
basic copper sulfate (008101)
005967-00120
71 dust
basic copper sulfate (008101)
000226-00032 000477-00054 000595-00221 000829-00006
001386-00492 002124-00580 002342-00856 003743-00188
003743-00334 008590-00051 034704-00133
basic copper sulfate (008101) plus calcium arsenate (013501)
000279-00825 000477-00073 000769-00149
basic copper sulfate (008101) plus methoxychlor, technical (034001)
008590-00166
basic copper sulfate (008101) plus carbaryl (056801)
000016-00127 000226-00243 002124-00572 034704-00192
basic copper sulfate (008101) plus parathion (057501)
000595-00241 000595-00294 008590-00172 008590-00187
basic copper sulfate (008101) plus malathion (057701)
000595-00229
basic copper sulfate (008101) plus rotenone (and other cube resins)
(071003)
000904-00174 002342-00842 008590-00064
basic copper sulfate (008101) plus sulfur (077501)
000595-00204
basic copper sulfate (008101) plus endosulfan (079401)
002342-00849 002393-00249 034704-00144
basic copper sulfate (008101), naneb (014505) plus malathion (057701)
000595-00283
basic copper sulfate (008101), carbaryl (056801) plus rotenone (and
other cube resins)' (071003)
000869-00137
basic copper sulfate (008101), malathion (057701) plus sulfur (077501)
000595-00242
Si
Issued: 9-16-82 II-O 08101-38
-------
EPA Index to Pesticide Chemicals
BASIC COPPER StJLFATE
Listing of Registered Pesticide Products by Formulation (continued)
8Z dus t
basic copper sulfate (OOS101)
002935-00332
AZ vettable powder
basic copper sulfate (008101) plus sulfur (077501)
001842-00226
5.2Z vettable powder
basic copper sulfate (008101), lead arsenate (013502) plus sulfur
000635-00528
6.31 wettable powder
basic copper sulfate (008101) plus sulfur (077501)
009859-00129 009859-00130
7.11 wettable powder
basic copper sulfate (008101) plus sulfur (077501)
002124-00793
7.32 wettable powder
basic copper sulfate (008101) plus sulfur (077501)
002124-00790 002124-00795
7.42 wettable powder
basic copper sulfate (008101) plus sulfur (077501)
002124-00791
12.5Z wettable powder
basic copper sulfate (008101)
002169-00047 005481-00135
12.752 wettable powder
basic copper sulfate (008101)
000904-00166 004931-00135 005887-00041 023486-00045
033955-00097
13.85Z vettable powder
basic copper sulfate (008101)
000557-01874
14.3Z vettable powder
basic copper sulfate (008101)
002124-00794
14.92 wettable powder
basic copper sulfate (008101)
000557-01877 002124-00788 002124-00789
92
Issued: 9-16-82 11-008101-39
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
15.21 vettable powder
basic copper sulfate (008101)
009859-00253
15.6Z vettable powder
basic copper sulfate (008101)
000557-01871 002124-00792
17.05Z wettable powder
basic copper sulfate (008101)
000557-01899
18.11 wettable powder
basic copper sulfate (008101)
000557-01900
191 wettable powder
basic copper sulfate (008101)
005967-00111
basic copper sulfate (008101) plus zinc sulfate, basic (089101)
001202-00307
20.11 wettable powder
basic copper sulfate (008101)
009859-00261
221 wettable powder
basic copper sulfate (008101)
001148-00006 009859-00155
30.251 vettable powder
basic copper sulfate (008101) plus captan (081301)
002124-00779
30.61 wettable powder
basic copper sulfate (008101)
009859-00156
331 wettable powder
basic copper sulfate (008101)
009859-00142
46.251 wettable powder
basic copper sulfate (008101)
000557-01933 009859-00125
507 wettable powder
basic copper sullate (008101)
000802-00012 001109-00035 009859-00084 020004-00001
Issued: 9-16-82
93
H-0 08101-4 u
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
521 vettable powder
basic copper sulfate (008101)
001278-00001
53Z vettable powder
basic copper sulfate (008101)
000226-00033 000239-00005
000456-00004
000557-01896
004833-00002
007001-00066
010103-00008
035896-00009
000476-00102
001109-00013
005905-00296
008901-00016
014775-00032
045115-00024
000279-00423
000477-00069
001109-00036
005967-00106
009782-00012
019713-00072
000279-00698
000557-01882
002124-00297
006720-00226
00985 9-00115
035896-00007
3.7Z wettable powder/dust
basic copper sulfate (008101), lindane (gamma isomer of benzene hexa-
chlorlde) (009001), zineb (014506), carbaryl (056801) plus sulfur
(077501)
000728-00086
51 wettable powder/dust
basic copper sulfate (008101), piperonyl butoxide, technical (067501),
pyrethrins (069001), rotenone (and other cube resins) (071003) plus
•ulfur (077501)
000004-00107
7Z wettable powder/dust
basic copper sulfate (008101)
000004-00058 001772-00067
basic copper sulfate (008101) plus carbaryl (056801)
001767-00075 002006-00057
basic copper sulfate (008101) plus rotenone (and other cube resins)
(071003)
000004-00053 000572-00058
basic copper sulfate (008101) plus sulfur (077501)
000557-01940
basic copper sulfate (008101), methylated napthalenes (054002) plus
rotenone (and other cube resins) (071003)
000004-00030
basic copper sulfate (008101), methylated napthalenes (054002), carbaryl
(056801) plus rotenone (and other cube resins) (0710C3)
000004-00029
b.li. Ib/gal flovable concentrate
basic copper su'fate (008101) plus sulfur (077501)
009859-00097
Issued: 9-16-82
11-008101-41
-------
EPA Index to Pesticide Chemical*
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
0.39 Ib/gal or A.15Z flovable concentrate
basic copper sulfat^. (008101)
000682-00067
0.48 Ib/gal or 4.4Z flovable concentrate
basic copper sulfate (008101)
022555-00003
0.53 Ib/gal flowable concentrate
basic copper sulfate (008101) plus sulfur (077501)
009859-00085
1 Ib/gal flowable concentrate
basic copper snlfate (006101)
035896-00014
3 Ib/gal flovable concentrate
basic copper sulfate (008101)
001812-00241 044283-00001
4.24 Ib/gal flowable concentrate
basic copper sulfate (OOS101)
001109-00034 003238-00080 009859-00119 022555-00004
9b
Issued: 9-16-82 11-008101-42
-------
ZPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
State Label Registrations
AL Reg. No.
022555-06356
AZ Reg. No.
022555-06375
CA Reg. No.
000239-04231 000239-04234 005967-05184 007001-07752
010972-07149 022555-06299
CO Reg. No.
022555-06365
FL Reg. No.
002342-06958 022555-06364 033914-08109
GA Reg. No.
022555-06363
ID Reg. No.
022555-06301
IL Reg. No.
022555-06367
KS Reg. No.
022555-06362 022555-06387
LA Reg. No.
022555-06361
HI Reg. No.
022555-06354
MN Reg. No.
022555-06360 022555-06386
MT Reg. No.
022555-06300
RB Reg. No.
022555-06359 022555-06388
NV Reg . No.
022555-06377
OK. Reg. No.
022555-06358
Issued: 9-16-82 11-008101-43
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
State Label Registrations (continued)
OR Reg. No.
022555-06376
SC Reg. Mo.
022555-06355
TX Reg. No.
022555-06357 022555-06373
DT Reg. No.
022555-06370
WA Reg. No.
022555-06369
VI Reg. No.
022555-06366
Issued: 9-16-82 11-008101-44
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Appendix A
Listing of Common Chemical Names Used on the Entry
Chemical Common Name EPA Acceptable
Code(source) Common/Chemical Same
014504 mancozeb xinc ion and manganese ethylene bis-
dithiocarbamate 802, a coordination
product of manganese 162, sine 22,
ethylene bisdithiocarbamate 622
Issued: 9-16-82 U-008101-4 5
-------
/23001AA
/03001AA
ZPA Index to Pesticide Chemicals
BASIC COPPER ST7LFATZ
Appendix B
Listing of Registration Bombers By Site
AGRICOLTUSAL CROPS
Alfalfa
/0400UA
/05001AA
/28000AA
/0600ZAA
001278-00001
Alaonds
000004-00058
000557-01896
001148-00006
004833-00002
006720-00226
010103-00008
035896-00007
Apple
000004-00058
000456-00004
001148-00006
004833-00002
005967-00107
023486-00045
Apricot
000004-00058
000557-01896
001109-00034
001278-00001
005481-00135
006720-00226
010103-00008
033955-00097
Avocado
000557-01882
001109-00035
006720-00226
022555-00004
Banana
001278-00001
000239-00005
001109-00013
001202-00307
005967-00106
007001-00066
019713-00072
044283-00001
000239-00005
000635-00528
001202-00307
004931-00135
005967-00111
033955-00097
000239-00005
000682-00067
001109-00036
001812-00241
005967-00106
007001-00066
019713-00072
035896-00007
000557-01896
001109-00036
008901-00016
035896-00007
000279-00698
001109-00034
001278-00001
005967-00107
008901-00016
022555-00003
045115-00024
000279-00698
000802-00012
001278-00001
005481-00135
005967-00120
035896-OQ007
000279-00698
000802-00'V
001148-00006
002124-00297
005967-00107
008901-00016
022555-00003
044283-00001
001109-00013
001278-00001
009782-00012
044283-00001
000476-00102
001109-00036
001812-00241
005967-00111
009859-00119
022555-00004
000279-02722
000904-00166
002169-00047
005887-00041
008901-00016
000476-00102
001202-00307
004833-00002
005967-00111
009859-00119
022555-00004
045115-00024
001109-00034
001812-00241
019713-00072
045115-00024
Issued: 9-16-82
99
11-008101-46
-------
S063AA
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Sit* (continued)
Barley
001278-00001
Beans
500004-00029
000226-00033
000476-00102
000595-00277
001109-00013
001159-00039
002124-00297
003743-00333
006735-00166
010103-00008
035896-00007
000004-00030
000226-00243
000557-01896
000595-00283
001109-00034
001278-00001
002393-00218
004931-00135
008590-00064
019713-00072
044283-00001
000004-00107
000419-00092
000572-00058
000869-00137
001109-00035
001812-00241
002935-00332
006720-00226
008901-00016
022555-00003
045115-00024
000226-00032
000419-00103
000595-00229
000904-00174
001109-00036
001990-00463
003743-00189
006735-00163
009782-00012
022555-00004
046946-00020
D02AA Beets
—000476-00102
000595-00229
001278-00001
006720-00226
022555-00003
045115-00024
D02AA Blackberry
000279-00698
001109-00036
008901-00016
035896-00007
1002AA Boysenberry
000279-00698
001278-00001
019713-00072
044283-00001
H3005AA Broccoli
000239-00129
000572-00058
001109-00013
001812-00241
006720-00226
010103-0OOOS
035896-00007
000557-01896
000595-00317
001386-00492
008901-00016
022555-00004
000802-00012
001278-00001
019713-00072
044283-00001
001109-00013
001812-00241
022555-00004
045115-00024
000016-00127
000279-01266
000595-00229
001109-00036
001990-00463
006735-00166
019713-00072
044283-00001
000595-00204
001109-00013
001812-00241
010103-00008
035896-00007
001109-00013
001812-00241
022555-00004
045115-00024
001109-00034
004833-00002
023486-00045
000226-00033
000476-00102
000595-00277
001159-00039
002935-00332
008590-00064
022555-00003
045115-00024
000595-00221
001109-00036
002935-00332
019713-00072
044283-00001
001109-00034
004833-00002
023486-00045
001109-00036
008901-00016
035896-00007
000226-00243
000557-01896
000595-00317
001278^00001
005967-00111
008901-00016
022555-00004
Issued: 9-16-82
too
11-008101-47
-------
EPA Index to Pesticide Chemicals
/13006AA
/13007AA
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Site (continued)
Brussels Sprouts
—000604-06658OC-J016-00127 000239-00129 000279-01266
000557-01896 005967-00111 006720-00226 006735-O0166
008590-00064 008901-00016 010103-00008 035896-00007
Cabbage
000004-00058
000239-00129
000572-00058
001109-00013
001812-00241
005967-00111
008901-00016
022555-00004
000016-00127
000279-01266
000595-00229
001109-00036
001990-00463
006720-00226
010103-00008
035896-00007
000226-00033
000476-00102
000595-00277
001159-00039
002393-00218
006735-00166
019713-00072
044283-0X01
000226-00243
000557-01896
000595-00317
001278-00001
002935-00332
008590-00064
022555-00003
045115-00024
/28073AA
/13008AA
/28003AA
Carrots
000004-00058
000477-00069
000595-00229
000595-00283
000595-00317
001278-00001
008901-00016
022555-00003
045115-00024
Cauliflower
000004-00058
000239-00129
000572-00058
001109-00013
001812-00241
006720-00226
010103-00008
035896-00007
Celery
000004-00030
000279-00423
000477-00054
000572-00058
000595-00241
000595-00286
000904-00166
001109-00035
ccis::-::: ~
002935-00332
005905-00296
006720-00226
Issued: 9-16-82
000239-00005
000557-01896
000595-00234
000595-00286
001109-00013
001812-00241
009782-00012
022555-00004
046946-00020
000016-00127
000279-01266
000595-00229
001109-00036
001990-00463
006735-00166
019713-00072
044283-00001
000016-00127
000279-01266
000477-00069
000595-00204
000595-00242
000595-00291
000904-00174
001109-00036
CCll£?-OOC-~
003238-00080
005967-00107
008590-00051
000476-00102
000595-00204
000595-00242
000595-00291
001109-00034
002935-00332
010103-00008
035896-00007
000226-00033
000476-00102
000595-00277
001159-00039
002935-00332
008590-00064
022555-00003
045115-00024
000239-00005
000419-00092
000477-00073
000595-00221
000595-00257
000595-00294
001109-00013
001202-00307
OC""5^ "-C-CC3'
005481-00135
005967-00111
008590-00064
II-OOBlOlUi
000477-00054
000595-00221
000595-00257
000595-00294
001109-00036
005905-00296
019713-00072
044283-00001
000226-00243
000557-01896
000595-00317
001278-00001
005967-00111
008901-00016
022555-00004
000239-00129
000476-00102
000557-01896
000595-00234
000595-00283
000802-00012
001109-00034
001278-00001
n*"*^C3_2£<"1 "
005887-00041
005967-00120
008901-00016
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SDLFATE
Appendix B
Listing of Registration Numbers By Site (continued)
Celery (continued)
009782-00012 009859-00084 009859-00115 009859-00119
009859-00125 009859-00142 010103-00008 014775-00032
019713-OOC72 020004-00001 022555-00004 023486-00045
034704-00133 034704-00172 035896-00007 035896-00009
035896-00014 044283-00001 045115-00024 046946-00020
HB002AA Cherry (sour)
000004-00058
000477-00069
001109-00034
001278-00001
004833-00002
006720-00226
010103-00008
033955-00097
12000AA Citrus Fruits
000239-00005
000557-01874
000557-01899
001109-00013
001148-00006
002124-00297
002124-00791
002124-00795
005967-00106
009782-00012
009859-00125
009859-00156
014775-00032
022555-00004
035896-00014
iOlOlOAA Cranberry
001278-00001
iflOOOQAA Cucurbits (cucumbers, aelons,
~"pumpkin7 squash)
000004-00030 000004-00053
000226-00032
000239-00129
000477-00054
000572-00058
000595-00234
000595-Cw2co
000595-00317
000239-00005
000557-01896
001109-00036
001812-00241
004931-00135
007001-00066
019713-00072
035896-00007
000476-00102
000557-01877
000557-01900
001109-00034
001202-00307
002124-00788
002124-00792
003238-00080
005967-00111
009859-00084
009859-00129
009859-00253
019713-00072
033955-00097
044283-00001
000016-00127
000239-00005
000476-00102
000557-01896
000595-00229
000279-00698
000682-00067
001148-00006
002124-00297
005481-00135
008901-00016
022555-00004
044283-00001
000477-00069
000557-01882
000557-01933
001109-00035
001278-00001
002124-00789
002124-00793
004833-00002
006720-00226
009859-00115
009859-00130
009859-00261
020004-00001
035896-00007
045115-00024
000595-00294
000904-00174
Issued: 9-16-82
001109-00013
000004-00058
000226-00033
000279-00423
000477-00069
000595-00204
000595-00241
000595-00286
000829-00006
001109-00034
000476-00102
001109-00013
001202-00307
002169-00047
005887-00041
009859-00119
023486-00045
045115-00024
000557-01871
000557-01896
000557-01940
001109-00036
001812-00241
002124-00790
002124-007y4
005481-00135
008901-00016
009859-00119
009859-00155
010103-00008
022555-00003
035896-00009
000004-00107
000226-00243
000456-00004
000477-00073
000595-00221
OOG535-00257
000595-00291
000869-00137
001109-00035
11-008101-49
-------
EPA Index to Pesticide Chemicals
/0101IAA
/01004AA
/11001AA
/03005AA
/01013AA
BASIC COFFEE SULFATE
Appendix B
Lifting of Begistration Numbers By Site (continued)
Cucurbits (cucumbers, melons,
pumpkin, squash) (continued)
001109-00036
002124-00473
002342-00856
003238-00080
005887-00041
008590-00051
009859-00084
010103-00008
022555-00003
034704-00192
045115-00024
Currant
000802-00012
008901-00016
Dewberry
001109-00013
001812-00241
023486-00045
Eggplant
000004-00030
000572-00058
000595-00234
000869-00137
001159-00039
001990-00463
009782-00012
022555-00004
046946-00020
Filbert
001159-00039
002169-00047
002393-00218
003743-00188
005905-00296
008590-00064
009859-00115
014775-00032
022555-00004
035896-00007
001278-00001
023486-00045
001109-00034
008901-00016
035896-00007
000419-00092
000595-00204
000595-00242
000904-00174
001278-00001
002935-00332
010103-00008
035896-00007
001278-00001
002342-00842
002917-00054
003743-00334
006720-00226
008901-00016
009859-00119
019713-00072
023486-00045
035896-00009
001812-00241
002342-00849
002935-00332
004931-00135
007001-00066
009782-00012
009859-00125
020004-00001
034704-00137
044283-00001
004931-00135 005887-00041
035896-00007
001109-00036
019713-00072
044283-00001
000476-00102
000595-00221
000595-00286
001109-00013
001386-00492
006720-00226
019713-00072
044283-00001
001109-00034 001109-00035 001278-00001
Gooseberry
000802-00012
008901-00016
001278-00001
022555-00004
045115-00024
000557-01896
000595-00229
000595-00317
001109-00036
001812-00241
008901-00016
022555-00003
045115-00024
001278-00001
023486-00045
004931-00135
035896-00007
005887-00041
Issued: 9-16-82
103
11-008101-50
-------
EPA Index to Pascicide Chemicals
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Site (continued)
J014AA Grapes
000016-00127
000279-02722
000557-01896
000595-00286
001109-00034
001812-00241
005887-00041
008901-00016
023486-00045
044283-00001
000226-00033
000456-00004
000572-00058
000904-00166
001109-00036
002169-00047
006720-00226
010103-00008
033955-00097
045115-00024
000239-00005
000477-00054
000595-00204
000904-00174
001278-00001
004931-00135
008590-00166
019713-00072
035896-00007
000279-00423
000477-00069
000595-00221
001109-00013
001767-00075
005481-00135
008590-00172
022555-00004
035896-00014
I02QAA
B020AA
I005AA
S007AA
&Q03AA
1014AA
Hops
001278-00001
Lettuce
000016-00127
005967-00111
Loganberry
000279-00698
001278-00001
019713-00072
044283-00001
Mango
000557-01882
001278-00001
Nectarine
001812-00241 002935-00332 022555-00003
000239-00005
000682-00067
001148-00006
002124-00297
005967-00106
009859-00119
035896-00007
Olive
000279-00698
001148-00006
008901-00016
044283-00001
000239-00129
008901-00016
001109-00013
001812-00241
022555-00004
045115-00024
001278-00001
035896-00007
001109-00034
004833-00002
023486-00045
005967-00107
001109-00036
008901-00016
035896-00007
000557-01896 001109-00034 001109-00035
000279-00698
001109-00013
001278-00001
003238-00080
005967-00111
010103-00008
044283-00001
001109-00013
001278-00001
019713-00072
045115-00024
000476-00102
001109-00034
001812-00241
004833-00002
006720-00226
019713-00072
045115-00024
001109-00034
001812-00241
022555-00004
000557-01896
001109-00036
001990-00463
005887-00041
008901-00016
022555-00004
001109-00036
004833-00002
035896-00007
I»sued: 9-16-82
104
H-008101-51
-------
EPA Index to Pesticide Chemicals
JKUIAA
K31QAA
JB004AA
(ZB015AA
N003AA
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Site (continued)
Onion
0X239-00129
000595-00229
000595-00283
001109-00013
001812-00241
019713-00072
044283-00001
Papaya
006720-00226
Peach
000239-00005
000682-00067
001109-00034
001202-00307
002124-00297
005481-00135
006720-00226
019713-00072
044283-00001
Peanuts
000557-01896
001191-00278
001842-00199
002460-00002
005905-00322
006735-00166
009779-00062
009782-00012
009859-00095
015713-00072
035896-00009
Pear
000004-00058
000279-02722
000802-00364
001109-00035
001278-00001
003342-00028
005967-00107
006720-00226
019713-00072
035896-00007
lasued: 9-16-82
000279-01266
000595-00234
000595-00286
001109-00034
005967-00107
022555-00004
045115-00024
008901-00016
000279-00698
000802-00012
001109-00035
001278-00001
002169-000^7
005887-00041
008901-00016
022555-00004
045115-00024
001109-00013
001278-00001
001842-00207
003342-00028
006720-00226
008901-00016
009779-00106
009859-00080
009859-00096
022555-00003
035896-00014
000239-00005
000476-00102
000802-00492
001109-00036
001812-00241
004833-00002
005967-00111
008901-00016
022555-00003
044283-00001
000595-00204
000595-00257
000595-00291
001109-00036
005967-00111
034704-00172
046946-00020
000476-00102
000904-00166
001109-00036
001812-00241
003238-00080
005967-00106
009859-00119
033955-00097
001109-00034
001772-00067
001842-00226
003743-00201
006735-00163
009779-00023
009779-00112
009859-00085
009859-00097
022535-00004
044283-00001
000239-00129
000557-01896
001109-00013
001148-00006
002124-00297
005481-00135
005967-00120
009859-00119
022555-00004
045115-00024
000595-00221
000595-00277
OOU:> y 3-00/9 4
001278-00001
007001-00066
035896-00007
000557-01896
001109-00013
001148-00006
001990-00463
004833-00002
005967-00111
010103-00008
035896-00007
001109-00036
001812-00241
002124-00054
004139-00005
006735-00164
009779-00060
009779-00121
009859-00094
010103-00008
035896-00007
045115-00024
000279-00698
000802-00012
001109-00034
001202-00307
002169-00047
005967-00106
005967-00129
010103-00008
105
11-008101-52
-------
'2S016AA
'03008AA
'28017AA
/05005AA
/14013AA
EPA Index to Pesticide Chemicals
BASIC COPPER STJLFATE
Appendix B
Listing of Registration Numbers By Site (continued)
Peas
000869-00137 001278-00001 035896-00007
Pecan
005481-00135
Peppers
000016-00127
000595-00204
000595-00242
000829-00006
001109-00035
001812-00241
002935-00332
006735-00166
009859-00115
014775-00032
022555-00004
035896-00014
Pluo
000239-00005
001109-00013
001278-00001
005481-00135
009859-00119
033955-00097
Potato
000004-00029
000226-00033
000279-00423
000476-00102
000557-01933
000595-00229
000595-00277
000595-00317
000904-00174
001386-00492
002006-00057
002342-O0842
002393-00243
003743-00188
005887-00041
008590-00051
009782-00012
009859-00125
020CC-- ::c:i
008901-00016 033955-00097 035896-00007
000226-00243
000595-00221
000595-00283
000869-00137
001109-00036
001990-00463
003238-00080
008901-00016
009859-00119
019713-00072
034704-00192
044283-00001
000279-00698
001109-00034
001812-00241
006720-00226
010103-00008
035896-00007
000004-00030
000226-00243
000279-01266
000477-00054
000572-00058
000595-00234
000595-00283
000769-00149
001109-00013
001767-00075
002124-00297
002342-00849
002393-00249
003743-00333
005905-00296
OCS59C-CC1?: -'
009859-00084
009859-00142
000476-00102
000595-00229
000595-00286
001109-00013
001278-00001
002124-00779
003743-00334
009782-00012
009859-00142
020004-0X01
035896-00007
045115-00024
000476-00102
001109-00036
002169-00047
007001-00066
019713-00072
044283-00001
000016-00127
000239-00005
000419-00092
000477-00069
000595-00204
000595-00241
000595-00286
000802-00012
001109-00034
001812-00241
002124-00580
002342-00856
002935-00332
003743-00334
005967-00111
CC8590-OC187
009859-00115
014775-00032
000557-01896
000595-00234
000595-00317
001109-00034
001386-00492
002342-00849
006720-00226
009859-00084
010103-00008
022555-00003
035896-00009
046946-00020
000557-01896
001202-00307
004833-00002
008901-00016
022555-00004
045115-00024
000226-00032
000239-00129
000456-00004
000557-01896
000595-00221
000595-00257
000595-00294
000829-00006
001278-00001
001990-00463
002169-00047
002393-00218
003238-00080
004931-00135
006720-00226
OOSPCI-OCOlf
009859-00119
019713-00072
*1/ O c ^ f\nni. e
Issued: 9-16-82
106
11-008101-53
-------
::oo6AA
M06AA
!!072AA
D23AA
1302 4AA
Q016AA
1802 QAA
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Site (continued)
"i
Potato (continued)
033955-00097
034704-00192
045115-00024
Prune
500239-00005
001109-00013
001812-00241
008901-00016
022555-00004
Raspberry
000279-00698
001278-00001
019713-00072
044283-00001
Rice
022555-00003
Soybeans
022555-00003
Spinach
000016-00127
000595-00204
001278-00001
008901-00016
022555-OOC04
04694 6X50020
Strawberry
000004-00058
000476-00102
000904-00174
001812-00241
005967-00111
010103-00008
033955-00097
Sugar Beets
00023S-U0005
001109-00013
001278-00001
022555-00004
044283-00001
Issued: 9-16-82
034704-00133
035896-00007
046946-00020
000279-00698
001109-00034
004833-00002
009859-00119
035896-00007
001109-00013
001812-00241
022555-00004
045115-00024
000239-00129
001109-00013
001812-00241
010103-00008
035896-0000-'
000016-00127
000557-01896
001109-00013
001990-00463
006720-00226
014775-00032
035896-00007
000235-001:9
001109-00034
001812-00241
034704-00133
045115-00024
034704-00144
035896-00009
000476-00102
001109-00036
006720-00226
010103-00008
044283-00001
001109-00034
004833-00002
023486-00045
000476-00102
001109-00034
002935-00332
019713-00072
04A2S3-00001
000239-00005
000572-00058
001109-00036
002124-00297
008901-00016
019713-00072
044283-00001
000477-00069
001109-00035
002124-00297
035896-00007
107
11-008101-54
034704-00172
044283-00001
000557-01896
001278-00001
007001-00066
019713-00072
045115-00024
001109-00036
008901-00016
035896-00007
000557-01896
001109-00036
006720-00226
022555-00003
045115-00024
000239-00129
000904-00166
001278-00001
005481-00135
009782-00012
022555-00004
045115-00024
000557-01896
001109-00036
006720-00226
022555-00003
035896-00009
-------
/26003DA
/11005AA
/28024DA
/03009AA
/28065AA
/28007AA
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Appendix B
Listing of Registration Numbers By Site (continued)
Tobacc o
000226-00033 006720-00226 010103-00008 035896-00007
Tomato
0"0"0004-00029
000016-00127
000239-00005
000279-01266
000456-00004
000477-00073
000595-00204
000595-00277
000769-00149
000904-00166
001109-00035
001767-00075
002006-00057
002124-00634
002342-00856
003238-00080
004931-00135
005967-00111
008590-00051
009859-00084
009859-00142
022555-00003
034704-00133
035896-00009
046946-00020
000004-00030
000226-00032
000239-00129
000327-00127
000476-00102
000557-01896
000595-00221
000595-00283
000802-00012
000904-00174
001109-00036
001772-00067
002124-00297
002124-00779
002393-00218
003743-00188
005481-00135
005967-00120
008590-00064
009859-00115
014775-00032
022555-00004
034704-00144
035896-00014
Vegetables (seedlings)
)35896-00007
Walnut
500239-00005
000802-00012
001109-00036
005967-00106
009859-00115
035896-00007
Wheat
001278-00001
000239-00129
001109-00013
001148-00006
005967-00129
010103-00008
044283-00001
022555-00003
(Agricultural Seed Treatment)
Cottor. (seed)
022555-00003
Issued: 9-16-82
000004-00058
000226-00033
000279-00423
000419-00092
000477-00054
000557-01933
000595-00229
000595-00286
000829-00006
001109-00013
001278-00001
001812-00241
002124-00572
002169-00047
002393-00249
003743-00333
005887-00041
006720-00226
008901-00016
009859-00119
019713-00072
023486-00045
034704-00192
044283-00001
000476-00102
001109-00034
001278-00001
006720-00226
019713-00072
045115-00024
108
11-008101-55
000004-00107
000226-00243
000279-00825
000419-00103
000477-00069
000572-00058
000595-00242
000595-00317
000869-00137
001109-00034
001386-00492
001990-00463
002124-00580
002342-00842
002935-00332
003743-00334
005905-00296
006735-00166
009782-00012
009859-00125
020004-00001
033955-00097
035896-00007
045115-00024
000557-01896
001109-00035
001812-00241
008901-00016
022555-00004
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATZ
Appendix B
Listing of Registration Numbers By Site (continued)
J8072AA Rice (water planted rice seed)
~ 001109-00034 001109-00035
P23AA Soybeans (seed)
022555-00003
|!065AA Wheat (seed)
000239-00005 00476-00102 035896-00007
P502UA
P5021DA
P26AA
1I026DA
ORNAMENTALS
(Ornamental Plants (herbaceous plants and bulbs; woody shrubs, trees and
vines)) ——-——-—^—————^—_____
Arborvitae
000004-00058
006720-00226
Aster
000004-00058
000602-00012
033955-00097
000904-00166
035896-00007
005481-00135
006720-00226 035896-00007
300QAA
aSOOODA
31003AA
31003DA
Ornamental and/or Shade Trees
(inciudi-g Arborvitae, Cedar,
Cypress, Dogwood, Elm, Juniper,
Linden, Maple, Oak4 Pine, Spruce,
Sycamore, Tuliptree, Willow, and
Yew)
000004-00058 00090^-00166 001278-0.0001
005481-00135 005887-00041 006720-00226
035896-00007
004931-00135
033955-00097
Ornamental Flowering Plants
(including Aster, Begonia,
Carnation, Chrysanthemums,
Dalhias, Delphinium, Geranium,
Gladiolus, Hollyhock, Iris,
Lilies, Marigolds, Nasturtium,
Pansies, Peonies, Phlox, Snap-
dragon, Stocks, Sweet Pea, Tulips,
Violets, and Zinnia)
000004-00058 000004-00107 000802-00012 000904-00166
002169-00047 002935-00332 005481-00135 006720-00226
010102-?^!"" 022955-00097 035896-00007
Issued: 9-16-82
109
11-008101-56
-------
/34000AA
/3400ODA
/35097AA
/35097DA
/31155AA
/31155DA
/3301QAA
EPA Index to Pesticide Chemicals
BASIC COPPER SULFATE
Appendix B
Listing of Registration. Numbers By Site (continued)
Ornamental Woody Shrubs and Vines
(including Azalea, Barberry, Box
wood, Camellia, Gardenia, Haw-
thorn, Ivy, Laurel, Lilac,
Rhododendron hybrids/cultivars,
Rose, and Virginia Creeper)
000004-00030 000004-00058
000419-00103
000904-00166
006720-00226
000557-01882
002169-00047
006735-00163
000016-00127
000728-00086
002935-00332
010103-00008
000419-00092
000802-00012
005481-00135
033955-00097
035896-00007
Palm
005481-00135
Philodendron
006720-00226 033955-00097 035896-00007
001278-00001
(Lawns and Turf (including ground cover))
Ornamental Lawns
000557-01882000557-01923 006720-00226 035896-000007
Issued: 9-16-82
11?
11-008101-57
-------
EPA Index to Pesticide Chemicals
BASIC COPPER SITUATE
000004-00029
000004-00107
000226-00243
000279-00698
000327-00127
000476-00102
000557-01871
000557-01896
000557-01940
000595-00229
000595-00257
000595-00291
000635-00528
000802-00012
000869-00137
001109-00013
001148-00006
001278-00001
001812-00241
001990-00463
002124-00473
002124-00779
002124-00791
002124-00795
002342-O0856
002460-00002
003342-00028
003743-00333
004185-00271
005887-00041
005967-00107
006720-00226
007001-00066
008590-00172
009779-OCC6G
009779-00121
009859-00085
009859-00097
009859-00129
009859-00156
014775-00032
022555-00004
034704-00137
035896-00004
044283-00001
000004-00030
000016-00127
000239-00005
000279-00825
000419-00092
000477-00054
000557-01874
000557-01899
000572-00058
000595-00234
000595-00277
000595-00294
000682-00067
000802-00364
000904-00166
001109-00034
001159-00039
001386-00492
001842-00199
002006-00057
002124-00572
002124-00788
002124-00792
002169-00047
002393-00218
002917-00054
003743-00188
003743-00334
004833-00002
005905-00296
005967-00111
006735-00163
008590-00051
008590-00187
OOS779-00052
009782-00012
009859-00094
009859-00115
009859-00130
009859-00253
019713-00072
023486-00045
034704-00144
035896-00007
045115-00024
000004-00053
000226-00032
000239-00129
000279-01266
000419-00103
000477-00069
000557-01877
000557-01900
000595-00204
000595-00241
000595-00283
000595-00317
000728-00086
000802-00492
000904-00174
001109-00035
001191-00278
001767-00075
001842-00207
002124-00054
002124-00580
002124-00789
002124-00793
002342-00842
002393-00243
002935-00332
003743-00189
004139-00005
004931-00135
005905-00322
005967-00120
006735-00164
008590-00064
008901-00016
009779-00105
009859-00080
009859-00095
009859-00119
009859-00142
009859-00261
020004-00001
033955-00097
034704-00172
035896-00009
046946-00020
000004-00058
000226-00033
* «*» **^ ^ _^rt / *> O
, ^ "V W* ta. ^
000279-02722
000477-00073
000557-01882
000557-01933
000595-00221
000595-00242
000595-00286
000604-00024
000769-00149
000829-00006
000962-00342
001109-00036
001202-00307
001772-00067
001842-00226
002124-00297
002124-00634
002124-00790
002124-00794
002342-00849
002393-00249
003238-00080
003743-00201
004185-00090
005481-00135
00 59 67-0 CIO 6
005967-00129
006735-00166
008590-00166
009779-00023
009779-00112
009859-00084
009859-00096
009859-00125
009859-00155
010103-00008
022555-00003
034704-00133
034704-00192
035896-00014
Issued: 9-16-82
1 11
11-008101-58
-------
EPA Index to Pesticide Chemicals
W324402 COPPER SULFATE MONOHYDRATE
TYPE PESTICIDE: Algaecide
FORMULATIONS:
G
SC/S (27.72)
CEKEBAL WARNINGS AND LIMITATIONS: An algaecide registered for use in
f.»»»f.g poQi a and cooling cowers. This product i« toxic to fish; treatec
effluent should not be discharged where it will drain into lakes, streams,
ponds, or public waters. Concentrations and dosages have been calculatec
for metallic copper (Cu) , with the associated formulations indicated in
percent copper sulfate monohydrate. A metallic content of 35.8 percent
of the active ingredient was inferred for the purpose of calculating the
dosages. Refer to the formulations page for percentages of metallic cop-
per and copper sulfate monohydrate.
TIME REQUIRES FOR CONTROL: Not located.
PHYTOTOXICITf TO TARGZT WEEDS: Not located.
PHYTOTOXICITY TC CROPS: Not located.
MODE OF ACTION: The absorbed copper causes an imbalance with other mecal
cofactors resulting in enzyme blockage and eventual death of the a.gae.
AQUATIC WEEDS CONTROLLED:
PKAAAAA algae
112
Issued: 1-31-83 1-024402-1
-------
EPA Index co Pesticide Chemicals
COPPEE SULFATZ MONOHYDRATE
Site. Dosage Tolerance, Use, Limitations
and Formulation
AQOATIC AREAS
(Industrial)
/65019MA Commercial and Indns-
trial Water Cooling
Tower Sysraas
3.94-4.93 ppm Cu Water treatment for algae control. Repeat as
(lU c) needed.
(Ornamental and Recreational)
/5501 IMA Swimming ?ool 'Water
O.Z* lb Cu/ Water treatment fcr algae control. Initial ao-
10.0CC gal plication. One application will last an entire
[3 ppm Cii] season.
c-.-% sc.s:
113
Issued: 1-31-83
-------
EPA Index to Pesticide Chemicals
COPPES SULrATS MONOtTZDSATS
Listing of Registered Pesticide Products by Formulation
IIS (metallic Cu: 3.9&2) granular
copper suiiate aionohydrate (.024-02)
005427-00005*
*taetallic copper inferred
27.7* (metallic Cu: 9.921) soluble concentrate/solid
copper sulfate monohydrate (024402)
005605-00077*
*metallic copper inferred
Issued: 1-31-63
114
1-024402-3
-------
EPA lacex to Pesticide' Chemicals
COPPER 3ULFA7S MONOHYDRATE
Appendix B
Listing of Regiscracion Numbers By Site
AQUATIC AREAS
(Industrial)
/65019MA Commercial and Indus-
""trial Water Cooling
Tocer Systems
005427-00005
(Ornamental and Recreational)
/6501 IMA Swiaming Pool Water
005605-00077
115
i.ssuec.
-------
EPA Index co Pesticide Chemicals
C2<*402
COPPER SULFATE MONOHYDRATE
Fungicide
TYPE PESTICIDE:
FORMULATIONS :
15 U OX, # OS)
SC/S (29. 4Z)
GENERAL WARNINGS AND LIMITATIONS: Dusts contain 10 to 20 percent copper
sulfate mono hydrate with 3.5 to 7.16 percent metallic copper, respective-
ly. Dosage rates are given in pounds metallic copper with the associated
formulations in percent copper sulfate mono hydrate. Refer to the fonnu-
lation pages for the percent metallic copper and percent copper sulfate
mono hydrate for each registration. Dusts may be applied by ground equip-
ment or aircraft. Dust throughly, keeping plants covered during periods
of infection, and only when foliage is moist.
Definition of teras;
M.A.I. - Multiple active ingredient
Site and Pest
04001AA AD ole
BANEBI Fire blight
(Ervinia)
13005AA Broccoli
13007AA~ Cabbage
13008AA Cauliflower
FABPAU Downy mildew
(Percr^spora)
M3CQBB Leaf spot
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 1.75
pounds per acre.
1.4-1.75 Ib/A Foliar application. Apply ahead of
(102 D) *ny periods of high humidity. The
number of applications is determined
by length of bloom period.
Exempt
No preharvest interval through 2.S6
pounds per acre.
0.72-2.86 Foliar application. Apply before
Ib/A disease appears. Repeat at 7 to 10
(10-20Z D) day intervals.
Cabbage'
See Broccoli cluster.
Issued: 2-10-83
II-O24402-1
-------
JS073AA
tACBM
K03AA
IIHCBM
tess.
tJSBL
Sice and Pest
Carrots
EPA Index to Pesticide Chemicals
COPPER SULFATZ MONOHYDRATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 2.86
pounds per acre.
Early blight
(Cercospora)
Late blight
(Alternaria)
Cauliflower
Celerv
Bacterial blight
(Pseudomonas)
Early blight
(Cercospora)
Late blight
(Septoria)
Citrus Fruits
Brown ro t
(Phytophthora)
Leaf and fruit
spot^( Septoria)
0.72-2.86
Ib/A
(10-20* D)
OR MAI
1.79-2.15
Ib/A
(20Z D)
Foliar application. Apply at first
sign of disease. Repeat at 7 to 10
day intervals as needed.
OR MAI
Formulated with sulfur.
See Broccoli cluster.
Exempt
No preharvest interval through 2.86
pounds per acre.
0.72-2.86
Ib/A
(10-202 D)
OR MAI
Foliar application. Apply at weekly
intervals in the plant bed and re-
peat at 7 to 10 day intervals ir.
the field beginning when plants are
2.1-2.45 Ib/A established.
(20Z D) " OR MAI
Formulated with sulfur.
Exempt
Apply through 3.3 pounds per acre
in central CA, or 0.26 to 0.47
pounds -per 100 gallons in southern
CA in accordance with directions
below.
0.47 lb/ Use limited to central CA.
100 gal Foliar application. Add 6 pounds
[500-700 of hydrated lime. Apply in fall
gal/A] prior to wet season.
(29.42 SC/S)
Issued: 2-10-83
117
II-024402-2
-------
Site and Pesc
EPA Index to Pesticide Chemicals
COPPER SULFATE HONOR-TO RATE
Dosages and Tolerance', Use. Limitations
Formulaeion(s)
Citrus Fruits (continued)
•GAJPCH
1
Brown rot
(Phytophthora)
'05004AA
Peach
-BADMCB
TAGTAB
?BAZCEL
'04003AA
Brown rot blossom
and tvig blight
(Monilinia)
Leaf curl
(Taphrina)
Sho thole
(Coryneum blight)
Pear
•EAJVAG
Fire blir-*
(Erwinia)
Scab
(Ven.turia)
0.26-0.47 lb/ Use limited to southern CA.
100 gal
(29.4Z SC/S)
Foliar and soil application. Apply
0.26 pound (add 4 pounds of hydrated
line) as a skirt spray on soil,
trunk, and lover 3 to 4 feet of fol-
iage. Apply in fall just prior to
wee season. In coastal areas or
other areas where no copper injury
has been found, apply 0.47 pound
(add 6 pounds of hydrated lime) as
a full coverage spray. Apply in
fall just prior to wet season.
Exempt
Ho preharvest interval through 3.5
pounds per acre.
Formulated with sulfur.
2.8-3.5 Ib/A Dormant, delayed dormant, and foliar
(20S D) application. For brown rot, apply
during prabloom and petal fall per-
iod. For leaf curl, apply in late
"fall and in the spring prior to bud
swell. For shothole, apply in late
fall and pink bud stage.
Exempt
No preharvest interval through j.i
pounds per acre.
Do not apply to Anjou or Cornice
varieties.
0.465-2.51
Ib/A
(10-201 D)
OR MM
2.8-3.5 Ib/A
(202 D)
Foliar application. Apply at 10
percent bloom and repeat at 5 to 1
day intervals or before any rainy
or wet weather. The number of ap-
plications is determined by length
of the bloom period.
OR MAI
Formulated with sulfur.
Issued: 2-10-83
118
11-02440 2-3
-------
{S017AA
i'.004AA
IIACDP
UCCBM
J.012AA
WftAX
ISPCN
M&AA
face
::oo5AA
IH&AX
1SPCN
B3BL
Site and Pest
Pepper ^
Pimento
EPA Index to Pesticide Chemicals
COPPER SULFATE MONCHID RATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exes??
No preharvest interval through 2.86
pourHe «•••• »/••!•• f/w rapper, or 1.79
pounds per acre for pimento.
Anthracnose
(Colletotrichum)
Leaf spot
(Cercospora)
Piaento
Potato
Early blight
(Altemaria)
Late blight
(Phytophthora)
Strawberry
Leaf spot
(Mycosp'naerella)
Early blight
(Altemaria)
Late blight
(Phytophthora)
Leaf spot
(Septoria)
0.72-2.86 Foliar application. Apply at first
Ib/A sign of disease. Repeat at 7 to 10
(10-202 D) day intervals as needed.
See Pepper cluster.
Exempt
No preharvest interval through 2.45
pounds per acre
1.07-2.15 Foliar application. Apply when
Ib/A plants are 4 to 6 inches high. Re-
(10-20Z) peat at a 10 day interval as r.eec-
OR MAI ed.
2.1-2.45 Ib/A OR MAI
(102 D) Formulated with sulfur.
Exempt
No preharvest interval through 2.86
pounds per acre.
0.72-2.86 Folisr —r1----- 7- . Apply before
Ib/A or after first sign of disease.
(10-202 D) Repeat at 7 to 10 day intervals as
needed.
Exempt
No preharvest interval throug'r 2.c-
pounds per acre.
0.72-2.86 Foliar application. Apply weekly
Ib/A if disease appears in plant beds.
(10-202 D) Dust plants 5 days before or after
OR MAI transplanting. Repeat applications
2.1-2.45 Ib/A at 7 to 10 day intervals.
(202 D) * OR MAI
Formulated with sulfur.
Issued: 2-10-83
II-024402-4
-------
Site and Pest
'03009AA Walnut
T3AAXAA Walnut blight
(Xanthomonas)
EPA Index to Pesticide Chemicals
COPPER SULFATE MONCHYDSATE
Dosages and Tolerance. Use, Limitations
Formulacion(s)
Exempt
No preharvest interval through 3.58
pounds per acs«*
1.07-3.58
Ib/A
(20* D)
OR MA.I
2.8-3.5 Ib/A
(202 D)
Delayed dormant and foliar applica-
tion. Apply at early prebloon (1
percent pistillate blooms), late
prebloom (10 to 20 percent pistil-
late blooms), and early postbloom.
Additional applications are required
immediately before or after rain.
OR MAI
Formulated with sulfur.
'001500
.AAAAAA
AERIAL AND TANK MIX APPLICATIONS
Aerial Application
Refer to
AGRICULTURAL CROPS
All sites except Citrus Fruits
Issued: 2-10-63
I £v
II-024402-5
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE MONOHYDRATE
Listing of Registered Pesticide Products by Formulation
102 (3.5% metallic copper) dust
copper sulfate monohydrate (024402)
000279-01054 ,-
101 (3.582 metallic i^pper) dust
copper sulfate monohydrate (024402)
000239-01060 000476-02035
201 (72 metallic copper) dust
copper suifate monohydrate (024402) plus sulfur (077501)
000279-00373
202 (7.16% metallic copper) dust
copper sulfate monohydrate (024402)
000239-01153 000476-00107
29.42 (10.52 metallic copper) soluble concentrate/solid
copper sulfate monohydrate (02^402)
004833-00005 017545-00001
1999 State Label Registrations
CA Reg. No.
000239-04194 000229-04195 000279-04001
121
Issued: 2-10-83 IIHD24402-6
-------
EPA Index to Pesticide Chemicals
COPPER SUUATE MONOHYDRATE
Appendix B
Listing of Registration Numbers By Site
^
/C4001AA Apple
000279-01054
/13005AA Broccoli
000476-00107 000476-02035
/13007AA Cabbage
000476-00107 000476-02035
/28073AA ^0^1239-01060 000279-00373 000476-00107 000476-02035
/13008AA Cauliflower
000476-00107 000476-02035
—000239-01060 000239-01153 000279-00373 000476-00107
000476-02035
/02000AA Citrus Fruits
004833-00005 017545-00001
/05004AA Peach
000279-00373
.0400 ~~io"0239-01060 000239-01153 000279-00373 000279-01054
000476-00107 000476-02035
.28017AA " 000i39-01060 000239-01153 000476-00107 000476-02035
/11004AA Pimento
000239-01060 000239-01153
/14013AA Potato
—000239-c;:-:: ccc::9-c::53 00:2:9-00373
'01016AA "St 000239!% 10 60 000239-01153 000476-00107 000476-02035
/11005AA Tomato
' 000239-01060 000239-01153 000275-00373 000476-00107
000476-02035
/03009AA —0^1:39-01153 000279-00373 000476-00107 000476-02035
Issued: 2-10-83
122
11-024402-7
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)* **
TYPE PESTICIDE: Algaecide; Herbicide
FORMULATIONS:
Tech (98.52, 992, 99.52)
G (0.32, 19.922, 202, 242, 752, 802)
P/T (42, 8.32, 8.72, 19.912, 86.22)
Cr (93.752, 952, 96.52, 96.92, 98.82, 992, 99.412, 99.52, 99.572, 1002)
SC/S (22, 42, 4.952, 172, 24.752, 54.72, 672)
SC/L (52, 5.6252, 6.332, 6.392, 152, 15.12, 18.92, 22.22, 482)
RTU (1.072, 1.142, 22, 2.182, 3.462, 5.62, 6.32, 6.332, 6.52, 6.932, 72,
9.62, -102, 11.5%, 12.642, 12.72, 132, 252)
GENERAL WARNINGS AND LIMITATIONS: Copper sulfate is a nonselective al-
gaecide registered for control of filamentous and planktonic algae in^
commercial, municipal, and irrigation water systems. It is also an herb-
icide used mainly for the destruction of tree roots that have obstructed
sections of sewer systems. Dosages and concentrations have been calcula-
ted for copper as elemental. Concentrations and dosages are given for
metallic copper (Cu) with the associated formulations listed as percent
copper sulfate (pentahydrate or anhydrous). For copper sulfate pentahy-
drate labels that did not give the percentage of metallic copper, a me-
tallic content of 25 percent of the active ingredient was inferred for
the purpose of calculating dosages. For similar copper sulfate anhydrous
labels, a metallic content of 39.81 percent of the active ingredient was
inferred. Refer to the formulation pages for the percent or pounds per
gallon of metallic copper and the perc-ent of copper sulfate or anhydrous
copper sulfate for each registration.
The tolerance of fish to the level of copper in water varies with species
as well as water hardness. The following maximum levels of metallic cop-
per are considered safe for these fish in waters of average hardness and
slight alkalinity when the chemical is evenly distributed:
Species of fish Pounds of metallic copper/acre foot of water
Trouts * 0.01
Carp 0.22
Suckers 0.22
Catfish 0.27
Pickerel 0.27
Goldfish 0.33
Perches 0.45
Sunfishes 0.90
Black Bass 1.33
Definitions of Terms:
**Copper Sulfate (.Pentahydrate and Anhydrous) is the name chosen to pres-
ent the active ingredient in this report. This name does not appear in
either Acceptable Common Names and Chemical Names for the Ingredient
Statements of Pesticide Labels ci Active Chemical Code List (Shaughnessy) .
It was chosen to best represent the approved labeling and chemical con-
stitution. The use of this name will be confined to this report unless
otherwise noted ir. future r«.:.--—
*copper sulphate
Bluestone ^ ^
Issued: 1-31-83 1-024401-1
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
TIME REQUIRED FOR CONTROL: Few hours to 2 days for removal of root
blockage. Algae will absorb the chemical within hours after treatment,
and control should be evident within 3 to 5 days.
PHYTOTOXICITY TO TARGET WEEDS: Not located
PHYTOTOXICITY TO CROPS: Not located
MODE OF ACTION; For algaecidal action, the absorbed copper causes an im-
balance with other metal cofactors resulting in enzyme blockage and even-
tual death of the algae.
ulAACF
WOODY PLANTS CONTROLLED:
roots
"QABAA
lAAAAA
"AA3AA
IYABAA
IPABAA
rAACAA
ICABAA
AAAAG
rLASAA
CADAA
.ZADAA
GABAA
1HABAA
PACAA
: LAB A A
LABAA
ICABAA
SADAA
AADAA
OABAA
LADAA
CACAA
AAAAE
AAAAN
FABAA
AQUATIC WEEDS CONTROLLED:
acnanthes
algae
anabaena
anacystis
ankistrodesmus
aphanizomenon
asterionella
blue-green algae
botryococcus
calothrix
cerastium
chara
chlamydomonas
chlorella
cladophora
closterium
coelastrum
crucigenia
cylindrospermum
cymbella
desmidium
diatoma
diatoms
dinoflagellates
draparnaldia
(c)
(a)
(a)
(d)
(a)
(a)
(b)
(d)
(b)
(d)
(c)
(c)
Cb)
(a)
(b)
(c)
(b)
(c)
(c)
(b)
WABAA
eudorina
Issued: 1-31-63
1-024401-2
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAKYDRATE AND ANHYDROUS)
AQPATIC WEEDS CONTROLLED: (continued)
5AA euglena
JAC filamentous algae
>UK filamentous green algae
BAA fragilaria (a)
JAA glenodinium (b)
UA gloeocystis (b)
JAA gloeotrichia (a)
UAA golenkinia (c)
SAA gomphonema (b)
J£AA gomphosphaeria (a)
|iAF green algae
$SAA hydrodictyon (a)(e)
JB5F leafy pondweed (f)
melosira (a)
microcystis
$3AA microspora (b)
|UV mustard yellow algae
|IBA navicula (a)
|iGZ neidium (c)
|CAA . nitella (d)
Ji2AA nitzschia (b)
lEAA nostoc (c)
1IAA oedogonium
|£AA oocystis --(c)
kAA oscillatoria (b)
I^A palmella (c)
ICAA pandorina (d)
JliAP pigmented flagellates
ICAA pithophora (c)
IDAA phormidium (c)
IUB planktonic algae
IIBA plectonerna boryanum (b)
iaAA polycystis '(a)
«BN pondweed (f)
'iSCAA rivularia (a)
IIBJ sago pondweed (f)
scenedesmus (d)
spirogyra (a)
staurastrum (c)
iBAA s tephanodiscus
symploca
synedra
synura
tabellaria
tetraedon
tribonema
ulothrix
125
Issued: 1-31-83 1-024401-3
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
AQUATIC WEEDS CONTROLLED: (continued)
JHABAA uroglena (a)
IWADAA volvox (*)
IXADAA rygnema (b)
(a) Concentration of 0.06 to 0.13 ppm metallic copper will provide
control.
(b) Concentration of 0.13 to 0.24 ppm metallic copper will provide
control.
(c) Concentration of 0.24 to 0.36 ppm metallic copper will provide
control.
(d) Concentration of 0.36 to 0.5 ?pn metallic copper will provide
control.
(e) Daily treatments for 5 days are needed for control.
(f) Removal of heavy infestations by mechanical means or with the use
of another herbicide may be necessary.
I 4- S.
Issued: 1-31-63
1-024401-4
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site, Dosage Tolerance, Use. Limitations
and Formulation
AGRICULTURAL CROPS '
General Warnings and Limitations;
Agricultural and Livestock Tolerances:
Copper is exempt from the requirements of a tolerance in eggs, fish,
meat, milk, irrigated crops, and shellfish when it results from the use
of copper sulfate as an algaecide or herbicide in irrigation conveyance
systems and lakes, ponds, reservoirs, or bodies of water in which fish or
shellfish are cultivated.
J4AA- Rice Exempt
0.71-1.51 Ib Cu/ Water treatment for algae control. Apply to a
A-ft flooded field, twice a year or as needed to main-
[0.26-0.56 ppm Cu] tain control. Apply the higher dosage in deeper
(992 Cr) water.
(15. IS SC/L,
anhydrous)
2.49-3.74 Ib Cu/A
(992 Cr)
DOMESTIC DWELLINGS, MEDICAL FACILITIES AND SCHOOLS
WOA Nonerop Areas
Stump treatment. To decompose old stumps, here
(96.52 Cr) several 1 inch holes as deeply as is possible into
stump, fill with chemical and cover with soil.
Sprinkle entire stump occasionally over a 4 to o
week period.
Issued: 1-31-83 1-024401-5
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Sice, Dosage Tolerance, Use, Limitations
and Formulation
AQUATIC AREAS
General Warnings and Limitations; For algae control, Apply in l*te spring
or early summer when algae first appear, the dosages are variable, and
depend upon algae species, water hardness, water temperature, amount of
algae present, as well as whether water is clear, turbid, flowing or sta-
tic. Preferably, the water should be clear with temperatures above 60 F
(15.6 C). Higher dosages are required at lower water temperatures, higher
algae concentrations, and for hard waters. If filamentous algae are
abundant, spray mats of floating algae in early afternoon on a sunny day.
Static water requires less chemical for algae control than does flowing
water. Use the higher dosages for chara, nitella, and filamentous algae
(pond scums), and the lower dosages for planktonic algae. If there is
uncertainty about the dosage, begin with a lower dose and increase until
control is achieved, or until the maximum allowable level has been rea-
ched .
Copper sulfate becomes less effective as the biocarbonate alkalinity of
water increases. Its effectiveness is significantly reduced when the
biocarbonate alkalinity exceeds 150 ppm as calcium carbonate. To control
algae in hard waters, such as those commonly found in the midwestern
states, a higher dosage is required. Treatment of algae can result in
oxygen loss from the decomposition of dead algae. This loss can cause
fish suffocation. If the algae cover more than one-third of the total
water area, treat in sections. Treat one-third to one-half of the water
area in a single operation and wait for 10 to 14 days between treatments.
Begin treatment along the shore and proceed outward in bands to allow fish
to move into untreated areas. In regions where ponds freeze in winter,
treatment should be done 6 to 8 weeks before expected freeze time to pre-
vent masses of decaying algae under an ice cover.
Trout and certain other species of fish may be killed at recommended ap-
plication rates, especially in soft or acidic waters. Before treating
bodies of water, consult proper state authorities, s-uch as the fisheries
cassissior. or conservation departisent to obtain any necessary permits.
Agricultural and Livestock Tolerances;
Copper is exempt from the requirements of a tolerance in eggs, fish,
meat, milk, irrigated crops, and shellfish when it results from the use
of copper sulfate as an algaecide or herbicide in irrigation conveyance
systems and lakes, ponds, reservoirs, or bodies of water in which fish or
shellfish are cultivated.
Definition of Terms:
CFS * cubic.feet per second.
i 28
Issued: 1-31-63 1-024401-6
-------
Site, Dosage
and Formulation
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance, Use, Limitations
(Potable Water)
Potable Reservoir
' Water
1 ppm Cu (potable water)
General Information; Spray uniformly over the
surface of the vater, particularly above the in-
fested areas. Applications may be made by any of
the following methods: 1. Spray algal growth with
algaecide dissolved in water. 2. Place crystals
in a burlap bag and drag through the water by
boat. 3. Use plastic sprinkling cans to distri-
bute algaecide dissolved in water. 4. Broadcast
crystals on water surface. Dissolve copper sul-
fate in a glass or plastic container. If a meta.
container must be used, it should be painted,
copper lined, or enameled.
0.05-1.37 Ib Cu/ water treatment for algae control. Use the higher
A-ft dosage when methyl orange alkalinity in water ex-
[0.02-0.5 ppta Cu; ceeds 50 ppm, anc for control of resistant biue-
(992 Cr) green algae.
(152 SC/L,
anhy drou s )
(15.12 SC/L,
anhydrous)
(18.9% SC/L)
(11.52 RTTJ,
anhydrous)
2.71 Ib Cu/A-ft
[1 ppm Cu]
(802 G)
1 gal product/A-fc
,',• Q* cr/T
\— - -1- / " >
anhydrous)
2.51-3.78 Ib Cu/A
cr)
water treatment for algae control. Use the lower
dosage early in the season when algae are your.,
and actively growing, and use the higher dosage
later when algae become more resistant. Do not
exceed the higher dosage in water that is less
than 2 feet deep.
" c ,
r .i
(11. 5Z RTU,
anhydrous)
weighted tape to remove a large porewn
algae before treating the pond.
or
Issued: 1-31-83
1-024401-7
-------
EPA Index Co Pesticide Chemicals
COPPER SULFATE (PSNIAHYD8ATE AND ANHYDROUS)
Tolerance, Use, Limitations
Site, Dosage
and Formulation
Potable Reservoir Water (continued)
0.68-1.02 Ib Cu/
A-ft
[0.25-0.38 ppm Cu]
(99X Cr)
0.5? Ib Cu/A-ft
[0.21 ppm Cu]
(251 RTO)
Water treatment for algae control. Double the
dosage for water with at least 100 ppm methyl
orange alkalinity, or for the control of chara and
nitella. Repeat treatment after 1 to 2 weeks if
algae are still present.
5015MA Potable Water Convey- 1 ppm Cu (potable water)
ance Svstems
0.057 Ib Cu/CFS/hr
[0.25 ppm Cu]
(99Z Cr)
0.22 Ib Cu/CFS/hr
[0.98 ppm Cu]
(15Z SC/L,
anhydrous)
0.063-0.13 Ib Cu/
CFS/hr
[0.2S-0.56 ppc
Cu]
(99.52 Cr)
0.0013-0.002 Ib Cu
CFS/hr
[0.006-0.009 ppm
Cu]
(152 SC/L,
anhydrous)
Water treatment for algae control. Continuous
feed method. Maintain application for 45 minutes.
Start treatment as soon as the algae start to
interfere with the flow of water, and make ap-
plication at a point of turbulence in the systen.
Water treatment for algae control. Continuous
feed method. Start treatment when water is first
turned into the system and continue throughout the
irrigation season.
0.015-0.021 Ib Cu/ Water treatment for control of leafy and sago
CFS/hr pondweed. Continuous feed method. Start crest-
[0.067-0.095 ppm ment when water is first turned into the system
Cu] and continue throughout the irrigation season.
(152 SC/L,
anhydrous)
Issued: 1-31-83
130
1-024401-8
-------
I20MA
JH19MA
Sice, Dosage
and Formulation
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance, Use, Limitations
Potable Water Conveyance Systems (continued)
Water treatment for algae control. Slug feed
method. Repeat application every 2 weeks. An
application is required every 5 to 30 miles de-
pending upon alkalinity and algae concentration
in the water.
0.063-0.76 Ib Cu/
CFS flow
(991 Cr)
(99.5Z Cr)
0.07-0.51 Ib Cu/
CTS flow
(152 SC/L,
anhydrous)
(Industrial)
General Warnings and Limitations; Badly fouled systems must be cleaned
before treatment is begun. Applications may be made in the tower su~~ ,
tower basin, or on distribution decks.
General Information: Air washer waters subject
Air Washer Water
Systems _„_...... ^ _____________
Evaporative Condenser to acidification rroa tobacco dust or other
Water Systems acidifying materials require adjustment of pK
with alkaline additives.
2-3 qt produc ti
1,000 gal
(6.931 ETJ,
anhydrous)
1-1.5 qt product/
1,000 gal
(6.93% RTU,
anhydrous)
Water treatment for algae control. Initial slug
application. Repeat until control is evident.
Water treatment for algae control. Maintenance
application. Repeat weekly or as needed to main-
tain control.
Commercial and Indus-
trial Water Cooling General Information: Some products may be fed
Tower Systems Into the system unciluted using a stoker-type
-- "" feeder, or as a 5 percent water solution, using
plastic or ceramic proportioning equipment.
0.96 oz Cu/
1,000 gal
[7 ppm Cu]
(242 G)
0.14 oz Cu/
1,000 g£-
[I ppm Cu}
(80Z G)
or
Water treatment for algae control. Initial ap-
plication. Repeat until control is evident.
Issued: 1-31-83
1-024401-9
-------
EPA Index Co Pesticide Chemicals
COPPER SULFATE (PENIAHYDBATE AND ANHYDROUS)
Tolerance, Use, Liaitations
Site. Dosage
and Formulation
Gomercial and Industrial Water Cooling Tower Systems (continued)
1.25 gal product/
1,000 gal
(1.142 RTU,
anhydrous)
2-3 qt product/
1,000 gal
(6.932 RTU,
anhydrous)
0.81 oz Cu/
1,000 gal
[6 ppm Cu]
(202 G)
0.46 oz Cu/
1,000 gal
[3.4 p pm Cu]
(802 G)
Water treatment for algae control. Initial ap-
plication. Repeat until control is evident.
Formulated with sodium pentachlorophenate and
other chlorophenols.
Water treatment for algae control. Initial ap-
plication. Repeat until control is evident.
Formulated with citric acid.
7.7-15.4 fl.oz Water treatment for algae control. Initial ap-
product/1,000 gal plication. Repeat until control is evident.
(9.62 RTU, Formulated with alkyl*dimethyl benzyl ammonium
anhydrous) chloride *alkyl (502 C14, 402 C12, 102 C16).
0.48 oz Cu/
1,000 gal
[3.3 ppo Cu j
(242 G)
0.0.3-0.14 oz Cu/
1,000 gal
[0.2-1 ppm Cu]
(802 G)
0.63 gal product/
1,000 gal
(1.142 RTU,
anhydrous)
1-1.5 qt product/
1,000 gal
(6.932 RTU,
anhydrous)
Water treatment for algae control. Maintenance
application. Apply after control is evident and
repeat weekly or as needed to maintain control.
Issued: 1-31-83
132
1-024401-10
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDSATE AND ANHYDROUS)
Site, Dosage Tolerance, Use, Limitations
and Formulation
Comercial and Industrial Water Cooling Tower Systems (continued)
0.41 oz Cu/ Water treatment for algae control. Maintenance
1,000 gal application. Apply after control is evident and
[3 ppm Cu] repeat weekly or a« needed to maintain control.
(20Z G) Formulated with sodium peatachlorophenate and
other chlorophenols.
1-5-15.4 fl.oz Water treatment for algae control. Maintenance
product/1,000 gal application. Apply after control is evident and
(9.6Z KIU, repeat weekly or as needed to maintain control.
anhydrous) Formulated with alkyl*dimethy1 benzyl ammonium
chloride *alkyl C50Z C14, 402 C12, 10S C16).
0.17-0.5 oz Cu/ Water treatment for algae control. Intermittent
1,000 gal application. Frequency and amount of treatment
[1.2-3.7 ppm Cu] will depend upon the kind and density of algal
(8.31 P/T) infestation.
Formulated with sodium pentachlorophenate and
other chlorophenols.
Evaporative Condenser
Water SystemsSee Air Washer Water Systems cluster.
(Impounded Water)
General Warnings and Limitations: Spray uniformly over the surface of
the water, particularly above the infested area*. Applications may be
made by any 1 of the following methods: 1. Spray algal growth with
algaecide dissolved in water. 2. Place crystala in a burlap bag and
drag through the water by boat. 3. Use plastic .sprinkling cans to dis-
tribute algaecide dissolved in water. 4. Broadcast crystals on water
surface. Dissolve copper sulfate in a glass or plastic container. If
a metal container must be used, it should be painted, copper lined, or
enameled.
133
Issued: 1-31-83 I-O24401-11
-------
EPA Index Co Pesticide Chemicals
COPPER SULFA7E (PENTAHYDRATE AND ANHYDROUS)
Site, Dosage Tolerance, Use, Limitations
and Formulation
65031MA Impounded Waters
General Information: Impounded waters include
lakes, ponds, reservoirs, farm ponds, and fire
ponds. Apply only in areas where algae are well
established and growing vigorously. Since still
waters allow for lower dosages, try to shut off
or divert the flow before beginning to treat each
section. Water supply may be resumed 3 to 4 days
after treatment. Do not apply in deep water areas
where potential for algal growth is limited.
0.05-1.51 Ib Cu/ Water treatment for algae control. Use the higher
A-ft dosage when methyl orange alkalinity in water ex-
[0.02-0.56 ppin Cu] ceeds 50 ppm, and for control of resistant blue-
(992 Cr) green algae.
(99.52 Cr)
(152 SC/L,
anhydrous)
(15.12 SC/L,
anhydrous)
(18.92 SC/L)
(11.52 HTU,
anhydrous)
2.71 Ib Cu/A-ft
[1 ppm Cu]
(802 G)
1 gal product/A-ft
(482 SC/L,
anhydrous)
2.52-3.78 Ib Cu/A Water treatment for algae control. Use the .ower
(992 Cr) dosage early in the season when algae are young
and actively growing, and use the higher dosage
later when algae become more resistant. Do not
exceed the higher dosage in water that is less
than 2 feet deep.
1-2 Ib Cu/A Water treatment for control of chara and nitella.
(19.91* P/I) .Use the lower dosage when vegetation is young and
actively growing, and the higher dosage as the
season progresses.
134
Issued: 1-31-83 1-024401-12
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site, Dosage Tolerance, Use, Limitations
and Formulation
Impounded Waters (continued)
0.67-1 Ib Cu/A-ft Water treatment for control of char*. When ia-
[0.25-0.37 ppm Cu] festation is heavy, drag the bottom with a wire
(11.52 RTU, or weighted tape to remove a large portion of the
anhydrous) al8» before treating the pond.
0.68-1.02 Ib Cu/
A-ft
[0.25-0.38 ppm Cu]
(992 Cr)
0.57 Ib Cu/A-ft
[0.21 ppm Cu]
(252 RTU)
Industrial Ponds and
Spray Ponds
3.26-25.3 Ib Cu/
million gal
[0.4-3 ppm Cu]
(802 G)
(Moving Water)
Irrigation Convey-
ance Systems
0.11 Ib Cu/CFS/hr
[0.5 ppm Cu]
(252 RTU)
Water treatment for algae control. Double the
dosage for water with at least 100 ppm methyl
orange alkalinity, or for the control of chara and
nicella. Repeat treatment after 1 to 2 weeks if
algae are scill present.
Water treatment for algae control. Broadcast.
Water treatment for algae control. Continuous
feed method. Maintain application for 3 hours.
0.057 Ib Cu/CFS/hr Water treatment for algae control. Continuous
[0.2 ppm Cu]
(992 Cr)
0.22 Ib Cu/CFS/hr
[0.98 ppm Cu]
(152 SC/L,
anhydrous)
0.063-0.13 Ib Cu/
CTS/hr
[0.28-0.56 ppra Cu]
(99.52 Cr)
Li W ^ W» "• O __-- —
*Ad method. Maintain application for 45 minutes.
Start treatment as soon as the algae start inter-
fering with the flow of water, and make applica-
tion at a point of turbulence in the system.
135
Issued: 1-31-83
1-024401-13
-------
EPA Index to Pesticide Chemicals
COPPER ST7LFATE (PENTAHYDRATE AMD ANHYDROUS)
Tolerance, Use, Limitations
Site, Dosage
and Formulation
Irrigation Conveyance Systems (continued)
0.025-0.05 Ib Cu/
CFS/hr
[0.11-4.2 ppm Cu]
(99Z Cr)
Water treatment for Algae control. Continuous
feed method. Maintain application for 12 hours
daily. Start treatment when water is first turned
into the system and continue throughout the irri-
gation season.
0.0013-0.002 Ib Cu/ Water treatment for algae control. Continuous
feed method. Start treatment when water is first
turned into the system and continue throughout
the irrigation season.
CFS/hr
(992 Cr)
(152 SC/L,
anhydrous)
(11.52 KTU,
anhydrous)
0.063-0.126 Ib Cu/ Water treatment for control of leafy and sago
CFS/hr pondweed. Continuous feed method. Maintain ap-
[0.28-0.56 ppm Cu] -plication for 12 hours daily. Start treatment
(992 Cr) when water is first turned into the system and
continue throughout the irrigation season.
0.017-0.025 Ib Cu/ Water treatment for control of leafy and sage
CFS/hr pondweed. Continuous feed method. Start treat-
[0.08-0.11 ppm Cu] ment when water is first turned into the system
(992 Cr) and continue throughout the irrigation season.
0.015-0.021 Ib Cu/
CFS/hr
[0.067-0.09 ppm Cuj
(152 SC/L,
anhydrous"
0.018-0.026 Ib Cu/
CFS/hr
[0.09-0.11 ppm Cu]
(11.52 KTU,
anhydrous)
0.25 Ib Cu/
CFS flow
(99% Cr)
Water treatment for algae control. Slug feed
method. Place chemical in a burlap bag in an area
of turblent flow and repeat every 10 to 14 days
in warm weather.
Issued: 1-31-83
136
1-024401-14
-------
Site, Dosage
«nd Formulation
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance, Use. Limitations
Irrigation Conveyance Systems (continued)
0.063-0.76 Ib Cu/ Water treatment for algae control. Slug feed
CFS flow
(991 Cr)
(99. 5Z Cr)
0.07-0.51 Ib Cu/
CFS flow
(152 SC/L,
anhydrous)
(Ornamental and Recreational)
method. Repeat application every 2 weeks. An
application is required every 5 to 30 miles de-
pending upon alkalinity and algae concentration
in the water.
Swimming Pool Water
0.34 Ib Cu/
10,000 gal
[4 ppm Cu]
(54.72 SC/S)
0.038 Ib Cu/
10,000 gal
[0.5 ppm Cu]
(672. SC/S)
0.23 Ib Cu/
10,000 gal
[3 ppm Cu]
(6.52 KTU.
anhydrous;
or
Treated pool effluent should not be discharged
where it will drain into lakes, streams, ponds or
public water.
General Information: Application should be made
to a pool free of visible algae. For heavy algal
infestations, more drastic treatments, such as
superchlorination, may be required to eradicate
the algae before treatment. Allow the chlorine
level to return to normal before resumption of
swimming. Not recommended for pools with marble
dust or marcite finish. The chemical is generally
effective for 1 month, but effectiveness varies
depending on pool conditions, daily chlorination
and use. The chemical can also be used to help
control swimming pool odors and algae during the
winter months. Before application remove all de-
bris from pool. Dissolve soluble concentrates in
water and apply to skimmers or along the edge of
the pool.
Water treatment for algae control. Initial ap-
plication. Apply when first filling the pool, or
when pool has visible algae and repeat until con-
trol is evident. Follow with maintenance appli-
cation.
i J/
Issued: 1-31-83
1-024401-15
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site, Dosage Tolerance, Use, Limitations
and Formulation
Swimming Pool Water (continued)
0.6 Ib Cu/
10,000 gal
[7 ppo Cu]
(7Z BTD,
anhydrous)
1.25 qt product/ Water treatment for algae control. Initial ap-
10,000 gal plication. Apply when first filling the pool.
(52 SC/L, Follow with maintenance application.
anhydrous)
5 fl.oz produce/
10,000 gal
(6.332 SC/L,
anhydrous)
(6.332 RTU,
anhydrous)
1 qt product/
10,000 gal
(6.392 SC/L,
anhydrous)
10 fl.oz product/
10,000 gal
(22.22 SC/L)
18 fl.oz product/
10,000 gal
(5.62 RTU,
anhydrous)
3.7 qt product/
10,000 gal
(6.52 HTU,
anhydrous)
8-16 fl.oz product/ Water treatment for algae control. Initial ap-
10,000 gal plication. Apply the higher dosage for pools with
(5.6252 SC/L, visible algae, and repeat if necessary.
anhydrous)
12.8-25.6 fl.oz Water treatment for algae control. Initial ap-
product/lC.OOC gal plication. Apply the higher dosage for peels vit-
(2.182 KTU, visible algae, and repeat if necessary.
anhydrous) Formulated with alkyl*dimethyl benzyl ononium
- v «_„•_•_ + . 1 l_. * ft iy*> n* l l no f " i />• *••* .' •»
Issued: 1-31-83 1-0244
i .3 a
-------
Site, Dosage
and Formulation
EPA Index to Pesticide Chemicals
COPPER SULFATE (FENTAHYDRATE AND ANHYDROUS)
Tolerance, Use, Limitations
Swimming Pool Water (continued)
0.033 Ib Cu/
10,000 gal
[0.4 ppm Cu]
(8.72 P/T)
0.25 cup product/
10,000 gal
(175 SC/S)
Water treatment for algae control. Initial ap-
plication. Repeat until control is evident.
Formulated with sodium dichloroisocyanurate.
Wa5er treatment for algae control. Initial ap-
plication. If resistant algae should appear,
double the dosage and repeat until control is
achieved.
Formulated with dichlone.
12.8 fl.oz
product/10,000
(1.072 RTU,
anhydrous)
25.6 fl.oz
product/10,000
(10Z KTU,
anhydrous)
Water treatment for algae control. Initial ap-
gal plication.
Formulated with tetrasodium ethylenediaminetetra-
acetate; alkyl*dimethy 1 benzyl ammonium chloride
*alkyl (602 C14, 30% C16, 52 C12, 52 CIS); and
alkyl*dimethyl ethylbenzyl ammonium chloride
gal *alkyl (682 C12, 322 C14); or alkyl*dimethy 1
benzyl ammonium chloride *alkyl (502 C14 402 Cl7
102 C16).
2.5 fl.oz product/
10,000 gal
(6.332 SC/L,
anhydrous)
(6.332 RTU,
anhydrous)
8 fl.oz product/
10,000 gal
(5.6252 SC.'L,
anhydrous)
(6.392 SC/L,
anhydrous)
9 fl.oz product/
10,000 gal
(5.62 RTU,
anhydrous)
Water treatment_for algae control. Maintenance
application. Apply every 7 to 14 days, or as
needed to maintain control.
139
Issued: 1-31-83
1-024401-17
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PEOTAHYDRATE AND ANKDROUS)
Tolerance, Use, Limitations
Site, Dosage
and Formulation
Swimming Pool Water (continued)
3.2 fl.oz product/
10,000 gal
(1.07Z BTU,
anhydrous)
(2.18Z KTU,
anhydrous)
0.34 lb Cu/
10,000 gal
make up water
[4 ppn Cu]
(54.72 SC/S)
1 pt product/
10,000 gal
(1.071 RTU,
anhydrous)
0.019 lb Cu/
10,000 gal
[0.2 ppn Cu]
(42 P/T)
Water treatment for algae control. Maintenance
application. Apply every 7 to 14 days, or as
needed to maintain control.
Formulated vith tetrasodium ethylenediaminetetra-
acetate; alky l*di«e thy1 benzyl ammonium chloride
*alkyl (602 C14, 302 C16, 52 C12, 52 CIS); and
alkyl*dimethyl ethylbenzyl ammonium chloride
*alkyl (682 C12, 322 Cli'); or alky l*dimethy 1
benzyl ammonium chloride *alkyl (502 C14, 40% C12,
102 CIS).
Water treatment for algae control.
application.
Make up water
Water treatment for algae control. Make up water
application. Apply if weekly make up rate is more
than 10 percent of total pool capacity.
Formulated with tetrasodium ethylenediaminetetra-
acetate; alkyl*dimethyl benzyl ammonium chloride
*alkyl (602 C14, 302 C16, 52 C12, 52 CIS); and
alkyl*dimethyl ethylbenzyl ammonium chloride
*alkyl (632 C12, 322 C14).
Water treatment for algae control.
application.
Winterizing
10,000 gal
[0.7 ppm Cu]
(24.752 SC/S)
20 fl.oz product/
10,000 gal
(22.22 SC/L)
3.7 qt product/
10,000 gal
(6.52 RTU,
anhydrous)
0.74 gal product/
10,000 gal
140
Issued: 1-31-83
1-024401-18
-------
Index Co Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND
Tolerance, Use, Limitations
Site, Dosage
and Formulation
Swimming Pool Water (continued)
0.05 lb Cu/
10 000 gal
[0.6 ppm Cu]
(2X BTTJ,
anhydrous)
21.3 fl.oz
produc t/
10,000 gal
(3.462 BTU,
anhydrous)
0.5 gal product/
10,000 gal
(13% KTU,
anhydrous)
12.8 fl.oz
product/
10,000 gal
(1.07Z KTU,
anhydrous)
2.6 qt product/
10,000 gal
(102 KTU,
anhydrous)
(Other Commercial)
7ish Hatcheries, Fish Ponds
Water treatment for algae control. Winterizing
application.
Formulated with one or a combination of: tetra-
•odium e thylenediaminete traacetate; alky l*fine thy 1
benzyl aamonium chloride *alkyl (602 C14, 302 C16,
5Z C12 52 C18); alky l*dime thy 1 benzyl ammonium
chloride *alkyl (502 C14, 402 C12, 102 C16); di-
alkyl (602 C14, 302 C16, 52 C12, 52 CIS) methyl
benzyl ammonium chloride; or alkyl*diaethy1 ethy.-
benzyl ammonium chloride *alkyl (682 C12, 32Z
C14)'.
0.57 lb Cu/A-ft
[0.21 ppm Cu]
(252
Water treatment for algae control. Double the
Sosage for water with at least 100 ?pm methyl
orange alkalinity, or for the control of chara
anTnitella.Bepeat treatment after 1 to 2 wee*s
if algae are still present.
sprayers.
(18.92 SC/L)
141
Issued: 1-31-S3
-------
>5026MA
Site, Dosage
and Formulation
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance. Use, Limitations
(Sevage Systems (Industrial/Home))
General Warnings and Limitations: Copper sulfate is registered for
clearing sewer systems of root blockage. Pour one-fourth Co one-half
of the dosage into toilet nearest sewer line blockage. Flush toilet and
repeat until entire dosage has been used. May also be applied through
the junction box, stack base, trap or drain openings, laterals or dis-
tribution box.
Sevage Systems
0.4 oz Cu
(19.922 G)
0.48 Ib Cu
(96.52 Cr)
1.32 oz Cu
(992 Cr)
2.75-5.5 oz Cu
(100Z Cr)
0.13 Ib Cu
(98.82 Cr)
(992 Cr)
General Information; Sewage systems include
cesspools, catch basins, storm sewers, storm
drains, septic tank drainfields, sewer pumps,
force mains, sewers and sewerlines. The chemical
is most effective when used during the growing
season of trees and shrubs. Badly neglected or
completely stopped sewers require mechanical
cleaning prior to application. The chemical muse
come into contact with obstructive roots to be
effective; therefore, some flow must be present
to carry it to the roots. Do not use in metal
vessels, sinks, tub drains or fixture traps, as
the chemical may corrode metal trim. Apply in the
late evening when the sewer flow will be at a
minimum. Repeat as needed to maintain control.
Do not. apply during extreme storm water tlcv.
Dissolve the soluble concentrates in water before
application.
Water treatment for root blockage control.
ventive application.
Pre-
Issued: 1-31-83
14?
1-024401-20
-------
EPA Index Co Pesticide Chemicals
Site, Dosage
and Formulation
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance, Use, Limitations
Sewage Systems (continued)
0.25-1.5 Ib Cu
(751 G)
(93.75-100Z Cr)
(15.12 SC/L,
anhydrous)
0.38-0.76 Ib Cu/
4-6 in. diameter
of sewerline
(98.82 Cr)
1-2 gal product/
4 in. diameter
of sewerline
(6.3: KTU,
anhydrous)
1 gal product/
300-400 ft length
of sewerline
(12.72 BTU,
anhydrous)
1 tablet
(86.22 P/T)
2 tablets/4 in.
sewerlir.e
(86.22 P/T)
8 cups produc t
(952 Cr)
0.5 Ib Cu
(992 Cr)
0.25 Ib Cu
(992 Cr)
0.016-0.031 Ib Cu/
4 in. sewerline
(992 Cr)
Issued: 1-31-83
Water treatment for root blockage control. Use
the lover dosage as a preventive measure or for
partial stoppage and the higher dosage for com-
plete stoppage. Repeat in 7 to 10 days for com-
plete stoppage.
Water treatment for root blockage control. Apply
to toilet once a week for 4 weeks. Repeat once a
month using 1 to 2 tablets per application.
Water treatment for root blockage control. For
serious stoppage, repeat treatment 2 to 3 times
over a 10 day .period.
Water treatment for root blockage centre.. I.ac=.
in cloth bag at the storage well inlet.
Water treatment for root blockage control. Re-
place the clean-out plug in sewerline with the
dispenser cartridge. Attach a garden hose to the
cartridge and turn the water on moderate flow.
When all crystals have been dissolved, disconnect
hose and remove dispenser. Repeat every 3 months.
Water treatment for root blockage control. Apply
the higher dosaee once a week for 4 weeks, and
the lower dosage weeniy lor H weeks thereafter.
143
1-024401-21
-------
Site, Dosage
and Formulation
Sewage Systems (continued)
EPA Index to Pesticide Chemicals
COPPER SDLFATE (PENTAHYDRATE AND ANHYDROUS)
Tolerance, Use, Limitations
0.12 Ib Cu
(99Z Cr)
0.25-0.5 oz Cu/
4 in. sewerline
(992 Cr)
1.5-3 tbls product
(992 Cr)
0.17-0.34 Ib Cu
(1002 Cr)
0.38-0.75 oz Cu
(1002 Cr)
1.75 oz Cu
(1002 Cr)
2-3 Ib product/
application
(0.32 G)
2.5 Ib product/
application
(0.32 G)
2-2.17 Ib product/
application
(0.32 G)
Hater treatment for root blockage control.
peat 3 or 4 tiaes over a few day period.
Re-
Water treatment for root blockage control. Place
2 bags into toilet or clean-out weekly for 4
weeks, and 1 bag weekly for 4 weeks thereafter.
Water treatment for root blockage control. Apply
the higher dosage initially, and the lower dosage
once a week for 4 weeks thereafter.
Water treatment for root blockage control. Apply
the higher dosage initially and the lower dosage
twice a year to prevent further growth.
Water treatment for root blockage control. Apply
the higher dosage weekly for 4 weeks, and the
lower dosage monthly thereafter.
Water treatment for root blockage control. Apply
every 3 weeks during the spring and fall, and
every 2 months.-at other times. Make initial ap-
plication at 2 week intervals for slow drainage.
Water treatment for root blockage control. Apply
to stack base, trap or drain. Slowly add 1 pail
of cold water. Make 3 applications at 15 minutes
intervals.
Formulated with sodium hydroxide.
Water treatment for root blockage control. Appl>
to clean-out. Slowly add one pail of cold water.
Make 10 applications at 10 minute intervals.
Formulated with sodium hydroxide.
Water treatment for root blockage cor.ir-1. Apply
to stack base or toilet. Make 3 applications ac
10 minute intervals. For sluggish sewers, repeat
for 4 days and flush with garden hose 1 day after
last application.
Formulated with sodium hydroxide.
Issued: 1-31-63
1-024401-22
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site, Dosaee Tolerance. Use. Limitations
and Formulation '
Sewage Systems (continued)
??S3Jvc?U W*ter *PPlicati°° for root blockage control. Ap-
1>Z5 SC/s; ply_to trap or drain openings. For slow flowing
drains, repeat in 24 hours. Repeat until control
0.038 Ib Cu is evident.
(4.95Z SC/S) Formulated with sodium hydroxide.
0.07 Ib Cu/50 ft
length of sewer-
line
/ t mt f,f* /c \
( <*» SC / S /
145
Issued: 1-31-83 1-024401-23
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
I
Listing of Registered Pesticide Products by Formulation
98.5Z (metallic Cu: 252) technical chemical
copper sulfate pentahydrate (024401)
000140-00041*
Metallic copper inferred
991 (metallic Cu: 25Z) technical chemical
copper sulfate pentahydrate (024401)
039295-00003*
*metallic copper inferred
992 (metallic Cu: 25.2Z) technical chemical
copper sulfate pentahydrate (024401)
001109-00001 001109-00019 001109-00021 001109-00027
001109-00032 001278-00005 008901-00006 009905-00001
035896-00003
99.52 (metallic Cu: 25.2S) technical chemical
copper sulfate pentahydrate (024401;
011435-00001 046218-00001
0.31 granular
copper sulfate pentahydrate (024401) plus sodium hydroxide (075603)
000399-00009 008132-00002 008132-00003 010700-00002
19.922 (metallic Cu: 4.98%) granular
copper sulfate pentahydrate (024401)
010564-00001*
*metallic copper inferred
20Z (metallic Cu: 5.09%) granular
copper sulfate pentahydrate (024401) plus sodium pentachlorophenate and
other chlorophenols (063003)
003682-00029
24S (metallic Cu: 6^ granular
copper sulfate pentahydrate (024401)
003682-00023*
*metalii£ copper inferred
751 (metallic Cu: 18.752) granular
copper sulfate pentahydrate (024401)
005605-00173*
*metallic copper inferred
80Z (metallic Cu: 202) granular
copper sulfate pentahydrate (024401) plus citric acid (021801)
010932-00002
802 (metallic Cu: 20.4Z) granular
copper sulfate pentahydrate (024401)
001706-00055 OOi"06-OGC:1
146
Issued: 1-31-83 1-024401-24
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
4Z (metallic Cu: 1Z) pelleted/tableted
copper sulfate pent*hydrate (024401)
004829-00048*
Metallic copper inferred
8.31 (metallic• Cu: 2.08Z) pelleted/tableted
copper aulfate pentahydrate (024401) plus sodium pentachlorophenate and
other chlorophenols (063003)
003876-00005*
^metallic copper inferred
8.71 (metallic Cu; 2.181) pelleted/tableted
copper sulfate pentahydrate (024401) plus sodium dichloroisocyanurate
(081404)
009087-00006*
*metallic copper inferred
19.912 (metallic Cu: 52) pelleted/tableted
copper sulfate pentahydrate (024401)
007364-00026
86.21 (metallic Cu; 21.6%) pe^Ieted/tableted
copper sulfate pentahydrate (024401)
006209-00001*
*tnetallic copper inferred
93.752 (metallic Cu; 23.442) crystalline
copper sulfate pentahydrate (024401)
009283-OOOC1*
*metallic copper inferred
95Z (metallic Cu: 24.132) crystalline
copper sulfate pentahydrate ^02-»^Gi)
011332-00001*
*met£llic copper inferred
96.52 (metallic Cu: 24.131) crystalline
copper su^i-wc. pentanydrate (.uz^uu
000192-00077*
*metallic copper inferred
96.9Z (metallic Cu; 24.6Z) crystalline
copper sulfate pentahydrate (.02^4Ul)
007687-00001
98.81 (metallic Cu: 25.32) crystalline
copper sulfate pentahydrate C0244U1)
013892-00001
147
bmd: 1-31-83 1-024401-25
-------
EPA Index Co Pesticide Chemical*
COPPER SOLFATE (PENTAHYDBATE AMD ANHYDROUS)
Listing of fttgistered Pesticide Products by Formulation (continued)
991 (metallic Cu; 252) crystalline
copper sulfate pentahydrate (024401)
000779-00098* 001109-00020 003640-00077*
005576-00048* 006646-00004*
017106-00001* 034797-00019
039271-00001* 039295-00008
Metallic copper inferred
010174-00001*
036416-00001*
004990-00020*
010779-00001*
037952-00001
992 (metallic Cu: 25.21) crystalline
copper sulfate
000430-00039
001109-00020
001109-00032
003286-00030
008460-00001
008959-00021
009768-00037
010103-00006
011333-00006
038539-00001
pentahydrate (024401)
000829-00210 001109-00001
001109-00021 001109-00026
001278-00008
004931-00134
008590-00405
009669-00001
010103-00002
010103-00009
011450-00002
045450H>0001
001386-00304
007401-00326
008901-00012
009698-00001
010103-00004
010267-00001
015015-00001
045450-00002
001109-00019
001109-00027
002800-00058
007792-00001
008901-00021
009768-00036
010103-00005
010827-00061
037952-00001
99.412 (metallic Cu: 252) crystalline
copper sulfate pentahydrate (02440D
033855-00001*
*metallic copper inferred
99.51 (aetallic Cu: 25.22) crystalline
copper sulfate pentahydrate (024401)
011435-00002 046218-00002
99.572 (metallic Cu: 252) crystalline
copper sulfate pentahydrate (024AOD
002169-00187*
*tnetallic copper inferred
1001 (metallic Cu: 251) crystalline
copper sulfate pentahydrate (024401)
000427-00048* 005094-00001* 006741-00003*
010906-00001*
*metallic copper inferred
2Z (metallic Cu; 0.5Z) soluble concentrate/solid
copper sulfate pentahydrate (024401) plus sodium hydroxide (075603)
009902-00001*
*metallic copper inferred
4Z (metallic Cu: II) soluble concentrate/solid
copper sulfate pentahydrate (024401) plus sodium hydroxide (075603)
010694-00001*
•metallic copper inferred
010266-00001*
Issued: 1-31-83
148
1-024401-26
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
4.93Z (metallic Cu; 1.24Z) soluble concentrate/solid
copper sulfate pentahydrate (62446l) plus sodium hydroxide (075603)
018632-00001*
Metallic copper inferred
171 (metallic Cu: 4.251) soluble concentrate/solid
copper sulfate pentahydrate (024401) plus dichlone (029601)
008729-00003*
*metallic copper inferred
24.75Z (metallic Cu: 6.191) soluble concentrate/solid
copper sulfate pentahydrate (024401)
007124-00051*
*metallic copper inferred
54.71 (metallic Cu; 13.682) soluble concentrate/solid
copper sulfate pentahydrate (024401)
004829-00028*
•metallic copper inferred
671 (metallic Cu: 16.752) soluble concentrate/solid
copper sulfate pencahydrate (024401)
007151-00003*
*metallic copper inferred
52 (metallic Cu: 2S) soluble concentrate/liquid
copper sulfate anhydrous (024401)
007124-00057*
•metallic copper inferred
5.6252 (metallic Cu: 2.25*) soluble concentrate/liquid
copper sulface anhydrous (024401)
027588-00002
6.33Z (metallic Cu: 2.522) soluble concentrate/liquid
copper sulface anhydrous (024401)
007152-00078*
^netallic copper inferred
6.39Z (metallic Cu; 2.54Z) soluble concentrate/liquid
copper sulface anhydrous(024401;
007124-00049* 007124-00052* 009556-00020*
Metallic copper inferred
151 (metallic Cu: 0.58 Ib/gal or 62) soluble concentrate/liquid
copper sulfate anhydrous (02440U
010103-00010
15.11 (metallic Cu; 0.59 Ib/gal or-6Z) soluble concentrate/liquid
038539^00002 045450-00004
149
Issued: 1-31-83 1-024401-27
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
18.91 (metallic Cu: 0.5 Ib/gal or 4.732) soluble concentrate/liquid
copper aulfate pentahydrate (024401;~~~
041041-00001*
^metallic copper inferred
22.21 (metallic Cu: 5.651) soluble concentrate/liquid
copper sulfate pentahydrate (024401)
033230-00001
48Z (metallic Cu:'19.12) soluble concentrate/liquid
copper sulfate anhydrous (024401)
001439-00193
1.071 (metallic Cu: 0.43D liquid-ready to use
copper sulfate anhydrous (024401), tetrasodium ethylenediamineteera-
acetate (039107), alkyl*dimethyl benzyl amnoniun chloride *alkyl (602
C14, 302 C16, 52 C12, 51 CIS) (069104) plus alkyl*dimethyl ethylbenzyl
aomonium chloride * allcyl (68Z €12, 322 C14) (069154)
042321-00001**
**tnetallic copper inferred
1.14Z (metallic Cu: 0.45Z) liquid-ready to use
copper sulfate anhydrous (024401)
LOJJ
)2^
003682-00022
22 (metallic Cu; 0.07 Ib/gal or 0.82) liquid-ready to use
copper sulface anhydrous (024401), alky l*dime thy 1 benzyl aanonium
chloride *alkyl (602 CU, 30Z C16, 52 C12, 52 CIS) (069104) plus
dialkyl (602 C14, 302 C16, 52 >C12, 52 CIS) methyl benzyl ansnonium
chloride (069119)
007124-00028**
**metallic copper inferred
2.182 (metallic Cu; 0.872) liquid-ready to use
copper sulfate anhydrous (024401) plus alkyl*dimethyl benzyl ammonium
chloride *alkyl (502 C14, 402 C12, 102 C16) (069105)
044723-00001**
**metallic copper inferred
3.462 (metallic Cu; 1.382) liquid-ready to use
copper sulfate anhydrous (024401), alkyl*dimethyl benzyl amnonium
chloride *alkyl (602 C14, 302 C16, 52 C12, 52 CIS) (069104) plus
dialkyl (602 C14, 302 C16, 52 C12, 52 CIS) methyl benzyl aa&onium
chloride (069119)
007152-00020**
**metallic copper inferred
5.62 (metallic Cu; 2.232) liquid-ready to use
copper sulfate anhydrous (024401)
OOOZTS-OCCT" " '
^metallic copper inferred
150
Issued: 1-31-83 1-024401-28
-------
EPA Index to Pesticide Chemical*
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pe»ticide Products by Formulation (continued)
6.31 (metallic Cu: 2.512) liquid-ready to use
copper sulfate anhydrous (024401)
010155-00022*
*metallic copper inferred
6.332 (metallic Co: 2;522) liquid-ready to use
copper sulfate anhydrous (024401)
007152-00077*
*metallic copper inferred
6.52 (metallic Cu: 2.59Z) liquid-ready to use
copper sulface anhydrous (024401)
003524-00034* 005605-00098*
*metalLic copper inferred
6.51 (metallic Cu: 0.25 Ib/gal or 2.59Z) liquid-ready to use
copper sulface anhydrous (024401)
$
004829-00030*
*metallic copper inferred
6.932 (metallic Cu; 2.762) liquid-ready to use
copper sulfate anhydrous (024401)
010867-00006*
*metallic copper inferred
71 (metallic Cu: 0.658 Ib/gal or 2.79%T liquid-ready to use
copper sulfate anhydrous (.024401)
007124-00023*
*metallic copper inferred
9.62 (metallic Cu: 3.822) liquid-ready to use
copper sulfateanhydrous (024401) plus alkyl*dimethyl benzyl ammonium
chloride *alkyl (502 C14, 40? C12, 102 C16) (069105)
0345 71-0000 8~*
**metallic copper inferred
102 (metallic Cu; 3.982) liquid-ready to use
copper sulfate anhydrous (024401) plus alkyl*dimethyl benzyl ammonium
chloride *alkyl (502 C14, 40Z C12, 102 C16) (069105)
040916-00003**
**metallic copper inferred
11.52 (metallic Cu: 0.42 Ib/gal or 4.62) liquid-ready to use
copper sulfate anhydrous (024401;
009768-00035
12.641 (metallic Cu; 31162) liquid-ready to use
copper sulfate peatahydrate (024401;
007124-00058*
Metallic copper inferred
151
Is.ued: 1-31-83 1-024401-29
-------
EPA Index to Pesticide Chemical•
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
12,71 (metallic Cu: 5.06Z) liquid-ready to use
copper sulfate anhydrous (024401)
012204-00001*
Metallic copper inferred
131 (metallic Cu: 5.181) liquid-ready to use
copper sulfate anhydrous (024401), alky l*dime thy 1 benzyl ammonium
chloride *alkyl (60Z C14, 30Z C16, 5Z C12, 51 CIS) (069104) plus di-
alkyl (602 C14, 30Z C16, 5Z C12, 52 CIS) methyl benzyl ammonium chlor-
ide (069119)
007124-00039**
**metallic copper inferred
25Z (metallic Cu: 0.63 Ib/gal or 6.252) liquid-ready to use
copper sulfate pentahydrate (024401)
046923-00001
999 State Label Registrations
AZ Reg. No.
035051-03736
CA Reg. No.
002935-09848
005719-04897
FL Reg. No.
037347-03117
MI Reg. No.
000595-04553
OR Reg. No.
002935-09851
IX Reg. No.
003286-08041
035994-06090
Issued: 1-31-83
152
1-024401-30
-------
*PA Index to Pesticide Chemicals
COPPER SULFATE ( PENTAHTORATE AND ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site
AGRICULTURAL CROPS
Bice
001109-00032 008901-00021 039295-00008 045450-00001
045450-00002 045450-00004
DOMESTIC DWELLINGS. MEDICAL FACILITIES AND SCHOOLS
ft Noncrop Areas
000192-00077
AQUATIC AREAS
(Potable Water)
Potable Reservoir
Water
000430-00039
001109-00020
001109-00032
001706-00056
009768-00035
010103-00004
010103-00010
039295-00008
000829-00210
001109-00021
001278-00008
008901-00012
009768-00036
010103-00005
037952-00001
041041-00001
001109-00001
001109-00026
001439-00193
008901-00021
009768-00037
010103-00006
038539-00001
046923-00001
001109-00019
001109-00027
001706-00055
009669-00001
010103-00002
010103-00009
038539-00002
Potable Water Convey-
ance Systems
010103-00010
046218-00002
(Indus trial)
Air Washer Water
Sys terns
010867-00006
Commere ial and Indus-
trial Water Cooling
Tower Systems
001706-00055 001706-00056
003682-00029 003876-00005
011435-00002 038539-00001 038539-00002
003682-00022 003682-00023
010867-00006 034571-00008
Evaporative Condense:
Water Systems
r\ o e "7 _A r\ n n c
Issued: ' 31-83
1-024401-
-------
031MA
D34MA
D21MA
31 IMA
EPA Index to Pesticide Chemical*
COPPER SULFATE (PENTAHYDRATE AND ANHTOROUS)
Appendix B
Listing of Registration Numbers By Site (continued)
(Impounded Water)
Impounded" Waters
000430-00039
001109-00020
001109-00032
001706-00055
008901-00012
009768-00036
010103-00005
010827-00061
039295-00008
045450-00004
General Information: Impounded waters include
lakes, ponds, reservoirs, farm ponds, and fire
ponds.
000829-00210 001109-00001 001109-00019
001109-00021
001278-00008
001706-00056
008901-00021
009768-00037
010103-00006
011435-00002
041041-00001
046218-00002
Industrial Ponds and
Spray Ponds
001706-00055
001706-00056
(Moving Water)
Irrigation Convey-
ance Systems
001109-00001
008901-00021
010103-00010
038539-00002
001109-00027
009768-00035
011435-00002
039295-00008
(Ornamental and Recreational)
Swimming Pool Water
000278-00045
004829-00048
007124-00039
007124-00057
007152-00077
027588-00002
044723-00001
003524-00034
005605-00098
007124-00049
007124-00058
007152-00078
033230-00001
(Other Commercial)
>02MA Fish Hatcheries, Fish Ponds
041041-00001 046923-00001
001109-00026
001386-00304
007364-00026
009669-00001
010103-00002
010103-00009
037952-00001
045450-00001
046923-00001
001278-00008
009768-00036
037952-00001
046218-00002
004829-00028
007124-00023
007124-00051
007151-00003
008729-00003
040916-00003
154
001109-00027
001439-00193
008590-00405
009768-00035
010103-00004
010103-00010
038539-00001
045450-00002
008901-00012
009768-00037
038539-00001
046923-00001
004829-00030
007124-00028
007124-00052
007152-00020
009087-00006
042321-00001
Issued: 1-31-83
1-024401-32
-------
SPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site (continued)
(Sewage Systems (Indus trial/ Home) )
Sewage -Systems
000192-00077
000829-00210
001109-00027
003286-00030
005094-00001
006646-00004
007792-00001
008959-00021
010155-00022
010564-00001
010906-00001
012204-00001
018632-00001
038539-00001
045450-00002
General Information; Sewage systems include
cesspools, catch basins, storm sewers, storm
drains, septic tank drainfields, sewer pumps,
force mains, sewers and sewerlines,
000399-00009
001109-00001
001278-00008
003640-00077
005576-00048
006741-00003
008132-00002
009283-00001
010174-00001
010694-00001
011332-00001
013892-00001
033855-00001
039271-00001
045450-00004
000427-00048
001109-00020
002169-00187
004931-00134
005605-00173
007401-00326
008132-00003
009698-00001
010266-00001
010700-00002
011333-00006
015015-00001
034797-00019
039295-00008
000779-00098
001109-00021
002800-00058
004990-00020
006209-00001
007687-00001
008460-00001
009902-00001
010267-00001
010779-00001
011450-00002
017106-00001
036416-00001
045450-00001
155
Issued: 1-31-83
1-024401-33
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registration Numbers
046923-00001
045450-00002
041041-00001
039271-00001
036416-00001
033855-00001
017106-00001
011450-00002
011332-00001
010827-00061
010564-00001
010155-00022
010103-00005
009902-00001
009698-00001
009087-00006
008901-00006
008132-00003
007401-00326
007152-00020
007124-00052
007124-00028
006209-00001
005094-00001
004829-00030
003682-00023
003286-00030
001706-00055
001278-00005
001109-00021*
000829-00210
000399-00009
046218-00002
045450-00001
040916-00003
038539-00002
035896-00003
033230-00001
015015-00001
011435-00002
010932-00002
010779-00001
010267-00001
010103-00010
010103-00004
009768-00037
009669-00001
008959-00021
008729-00003
008132-00002
007364-00026
007151-00003
007124-00051
007124-00023
005605-00173
004990-00020
004829-00028
003682-00022
002800-00058
001439-00193
001109-00032*
001109-00020
000779-00098
000278-00045
046218-00001
044723-00001
039295-00008
038539-00001
034797-00019
027588-00002
013892-00001
011435-00001
010906-00001
010700-00002
010266-00001
010103-00009
010103-00002
009768-00036
009556-00020
008901-00021
008590-00405
007792-00001
007152-00078
007124-00058
007124-00049
006741-00003
005605-00098
004931-00134
00387.6-00005
003640-00077
002169-00187
001386-00304
001109-00027*
001109-00019*
000430-00039
000192-00077
045450-00004
042321-00001
039295-00003
037952-00001
034571-00008
018632-00001
012204-00001
011333H)0006
010867-00006
010694-00001
010174-00001
010103-00006
009905-00001
009768-00035
009283-00001
008901-00012
008460-00001
007687-00001
007152-00077
007124-00057
007124-00039
006646-00004
005576-00048
004829-00048
003682-00029
003524-00034
001706-00056
001278-00008
001109-00026
001109-00001*
000427-00048
000140-00041
*crystallines that were double coded a, technicals
156
Issued: 1-31-83
1-024401-34
-------
EPA Index to Pesticide Chemical*
COPPER SULFAIE ( PENT AHTO RATE AND ANHYDROUS)
Auxiliary Documentation
(1) The four 0.32 granular products (formulated with sodium hydroxide)
for root control were included in the report. The dosages were given
in product because of the small percentage of copper sulfate.
(2) Reg. * 192-77: for decomposing stumps, the code used was 67000,
noncrop areas, and was placed under DOMESTIC DUELLINGS.
(3) Labels that just said copper sulfate were assumed to be pentahydrate,
unless the 2 metallic indicated anhydrous.
(4) Crystalline products with algaecidal uses that were also for
reformulating purposes were double-coded as technical chemicals.
(5) Reservoirs were coded under 65031 and 65015.
(6) These labels have flowing and impounded water dosage discrepancies:
Reg. No.
Concentration
given on label
Concentration we
calculated
Flowing water sites
46218-2 1 PP» Cu
46923-1 1 01 Cu
0.28-0.56 ppm Cu
0.4 ppm Cu (Considering
the dose/min, not per
hour. The per minute
and per hour doses do
not give same
concentration.
38539-1 ! PPm Cu
Impounded water sites
0.22
Cu
11435-2
46?1 a-2
46923-1
41041-1
0.5 ppm Cu
0.5 ppm
0.13 ppm
0.17 ppm
-------
EPA Index Co Pesticide Chemicals
COPPER SULFATE (PENTAHYDSATE AND ANHYDROUS)
Auxiliary Documentation
(continued)
(8) Rice labels: Some doses vere given per A-Ft and others (2) for
surface acre, which were higher. Both of these were used.
(9) Label * 39295-8: No specific dose for impounded waters was given.
We inferred 5.44 Ib per acre foot from the example.
(10) Tolerance for potable water was taken from CFR 21, section 193.90.
(11) Label 1278-8: Algae control in impounded waters gives a general dose
and also refers to a booklet 10 for alga species doses. We did not
use the booklet because (A) it is not stamped accepted, (B) some
doses go as high as 10 ppm which is very toxic to fish.
(12) The Mountain Brand label brochure has a livestock restriction for
farm ponds; but the more recent registrations like 38539-2 and
41041-1 do not have any restriction and in fact allow use of the
treated water for swimming, drinking, fishing etc. immediately after
treatment. We followed the recent trend and did not include any
restrictions in this report.
(13)Label # 27588-2: (5.6252 SC/L) was determined to be anhydrous,
because 2 metallic was 2.252.
(14) Label * 010932-2 (802 Dust): Product Bulletin A-102 was ignored
because intent was unclear.
(15) Label * 38539-2 reads (62 metallic or 0.59 Ib/gal) anhydrous;
Label # 45450-4 reads (62 metallic or 10.59 ib/gal) anhydrous; we
assumed 10.59 Ib/gal was an error and used 0.59 Ib/gal.
(16) For slug application in irrigation systems, Label # 1278-8, 11435-2,
and # 46218-2 read "A pile is necessary every 50 to 30 miles." We
assumed this to be an error and wrote 5 to 30 miles, (from 10103-10)
in this report
(17) Label # 5427-5: 112 granular (monohydrate), was included in the
024402 report.
158
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Auxiliary Documentation
(continued)
(18) Labels with inferred metallic copper;
000140-00041*
000779-00098*
003682-00023*
004829-00048*
005605-00098*
006741-00003*
007124-00049*
007124-00058*
007152-00078*
009556-00020*
010266-00001*
010867-00006*
017106-00001*
036416-00001*
041041-00001*
000192-00077*
002169-00187*
003876-00005*
004990-00020*
005605-00173*
007124-00023*
007124-00051*
007151-00003*
008729-00003*
009902-00001*
010564-00001*
010906-00001*
018632-00001*
039271-00001*
042321-00001*
000278-00045*
003524-00034*
004829-00028*
005094-00001*
006209-00001*
007124-00028*
007124-00052*
007152-00020*
009087-00006*
010155-00022*
010694-00001*
011332-00001*
033855-00001*
039295-00003*
044723-00001*
(19) Anhydrous Copper Sulfate Labels:
000278-00045* 001439-00193
004829-00030* 005605-00098*
007124-00039* 007124-00049*
007152-00020* 007152-00077*
009768-00035 010103-00010
012204-00001* 027588-00002
040916-00003* 042321-00001*
* » inferred metallic copper
003524-00034*
007124-00023*
007124-00052*
007152-00078*
010155-00022*
034571-00008*
044723-00001*
000427-0004**
003640-00077*
004829-00030*
005576-00048*
006646-00004*
007124-00039*
007124-00057*
007152-00077*
009283-00001*
010174-00001*
010779-00001*
012204-00001*
034571-00008*
040916-00003*
003682-00022
007124-00028*
007124-00057*
009556-00020*
010867-00006*
038539-00002
045450-00004
-------
J?
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance, Use. Limitations
Formulae ion( s )
AGRICULTURAL CROPS
General Warnings and Limitations: Copper sulfate is exempt from require-
ment for tolerances when used on raw agricultural commodities (up to har-
vest) according to good agricultural practice. Dosage rates are given in
terms of the ratio of pounds of copper sulfate pentahydrate, pounds of
hydrated lime, and gallons of water (e.g. 10-10-100 Bordeaux mixture).
To prepare a Bordeaux mixture, fill the tank 1 quarter full with water.
•Then, with agitator running, wash the formulation into the tank through a
copper, bronze, plastic, or stainless steel screen. Add water so the tank
is three-quarters full and wash the hydrated lime through the screen.
Then add the balance of the water. Do not allow mixture to stand before
use. Spray mixtures and liquid formulations are corrosive to certain
metals. A Bordeaux paste is prepared by dissolving 1 pound of copper
sulfate pentahydrate in 3 quarts of water and mixing with 1.5 pounds of
slaked lime in 3 quarts of water.
Almond
Brown rot blossom
and twig blight
(Monilinia)
Sho thole
(Coryneum blight)
10-10-100
(992 Cr)
(94.3-992
SC/S)
(15-15.12
SC/L, anhy-
drous)
or
12-12-100
(94.3-982
SC/S)
Exempt
Apply up to a 12-12-100 mixture.
Dormant, delayed dormant, and foliar
application. For brown rot, apply
when buds begin to swell and at
'petal fall in certain areas. For
shothole, apply as dormant spray in
late or in early spring just before
buds swell.
Apple
Copper deficiency
(exanthema)
Crown gall
( Agr o bac t e r i urn)
Western white root
rot
10-10-100
(992 Cr)
(992 SC/S)
Bordeaux
paste
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
Exempt
Apply up to a 10-10-100 mixture
Foliar application. Apply tc c
iage in early summer.
Wound treatment. After infection
has been cut away, disiofect wounds
and allow to dry for several days.
Then cover the wounds with Bordeaux
paste.
Soil and base of tree application.
Apply when infection is detected to
base ana soi^. around trees.
Issued: 2-01-83
161
II-024401-2
-------
D01AA
3MCB
ZCEL
Site and Pest
Apricot
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance. Use, Limitations
Fonnulation(s)
Exempt
Apply up to a 12-12-100 mixture.
Brown rot blossom 10-10-100
and tvig blight
(Monilinia)
Sho thole
(Coryneum blight)
)02AA
)05AA
306AA
)07AA
VEAH
1SBL
;PBV
CQBB
)73AA
Blackberry
Loganberry
Raspberry
Youngberry
Anthracnose
(Elsinoe)
Cane blight
Leaf and cane spot
(Septoria)
Leaf rust
(Phragmidium)
(on raspberry)
Orange rust
Carrots
Late blight
(Altemaria)
>03AA
;SBL
Late blight
(Septoria)
(992 Cr)
(94.3-992
SC/S)
(15-15.12
SC/L, anhy-
drous)
or
12-12-100
(94.3-982
SC/S)
10-10-100
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
(992 SC/S)
or
4-6-100
(98.52 SC/S)
Dormant, delayed dormant, and foliar
application. For brown rot, apply
when buds begin to swell or in red
bud to popcorn, and at petal fall
depending upon area. For shothole,
apply in late fall and/or early
spring.
Exempt
Apply up to a
10-10-100 mixture,
Dormant, delayed dormant applica-
tion. Apply in late winter (Febru-
ary and March) just before leaves
open.
Exempt
Apply up to a 10-10-100 mixture.
Foliar application. Apply 4 weeks
after seeding and then at 7 to 9 day
intervals for at least 4 to 5 ap-
plications.
Exempt
Foliar application. Apply 4 weeks
after seeding and then at 7 to 9 day
intervals for at least 4 to 5 ap-
plications.
Issued: 2-01-63
162
II-024401-3
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHTORATE AND ANHYDROUS)
Dosages and Tolerance. Use, Limitations
Formulation(s)
Bacterial canker
(guano*is)
(Ps g
Brown rot blossom
and twig blight
(Honilinia)
(sour cherry)
Cherry leaf spot
(Coccomyces)
Citrus Fruits
Brown rot
(Phytophthora)
Leaf and fruit spot
(Septoria)
Brown rot
(Phytophthora)
Exempt
Apply up to a 10-10-100 mixture.
Wound treatment. After infection
has been cut away, disinfect wounds
«nd Allow to dry for several days.
Then cover the wounds with Bordeaux
paste.
Delayed dormant application.
Apply when buds begin to swell.
Bordeaux
paste
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
(94.3-992
SC/S)
(15-15.12
SC/L, anhy-
drous)
10-10-100 Foliar application. Apply as a full
(992 Cr) coverage spray after petal fall or
(992 SC/S) as recommended by a State Coopera-
(15-15.12 tive Agricultural Extension Agent.
SC/L, anhy-
drous)
Exempt
Apply up to a 3-4.5-100 mixture.
5-6-100
[1.885 Ib
a.i. ]
[500-700
gal/A]
(37.72 SC/S)
3-4-100
[1.13 Ib
a. i. ]
or
5-6-100
[1.885 Ib
&. i. ]
(37.72 SC/S)
2-2-100
(94.32 SC/S)
Use limited to central CA.
Foliar application. Apply as a full
coverage spray to mature trees in
fall prior to wet season.
Use limited to central CA.
Foliar application. Apply low rate
as a skirt spray on soil, trunk and
lower 3 to 4 feet of foliage. Ap-
ply in fall just prior to wet sea-
son. Apply high rate as a full
coverage spray in coastal areas or
other areas where no copper injury
has been found.
Foliar application. Apply during
the fall or winter periods when
disease may be a proolem.
Issued: 2-01-83
163
II-024401-4
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Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AMD ANHYDROUS)
Dosages and Tolerance, Use, Limitations
Formulaeion(s)
JPCN
JPCN
BSBL
JPCN
LDAD
BEAR
OOOAA
TEBI
3PEA
Citrus Fruits (continued)
(lemon, orange, grapefruit)
Brown roc 3-4.5-100
(Phytophthora) or
2-6-100
(992 Cr)
(992 SC/S)
(15-15.12
SC/L, anhy-
drous)
Brown rot 2-6-100
(Phytophthora) (992 Cr)
Leaf and fruit spot (992 SC/S)
(Septoria) (15-15.12
(in central CA) SC/L, anhy-
drous)
Foliar and soil application. Apply
3-4.5-100 where there is no history
of copper injury. Apply 2*6-100
with 3 pounds cine sul£ate where
injury has occured. Apply 6 gallons
of spray on skirt of tree 3 to 4
feet high, and 2 to 4 gallons on
trunk and ground under tree. If
Phytophthora hibernalis is present,
use 10 to 25 gallons to completely
cover each tree. Apply in November
or December just before or after
first rain. In a severe brown rot
season, apply again in January or
February.
Foliar application. Add 3 pounds
zinc sulfate. Apply 10 to 25 gal-
lons to completely cover each tree.
Apply in October, November or De-
cember just before or just alter
first rain. This application is
also used for copper and zinc de-
ficiencies.
Brown rot
(Phytophthora)
Melanose
(Diaporthe)
Scab (spot anthrac-
nose)
(Elsinoe)
Curcurbits
Bacterial wilt
(Erwinia)
Downy mildew
(Pseudoperono-
spora)
2-2-100 Foliar application. Use for brown
(98.52 SC/S) rot of lemons, melanose of grape-
fruit, and scab of grapefruit and
orange s.
Exempt
Apply up to a 10-10-100 mixture.
10-10-100 Foliar application. Apply when
(992 Cr) plants are young for bacterial wilt
(992 SC/S) or at first sign of disease for
downy mildew. Repeat at 7 to 10
day intervals.
Issued: 2-01-83
II-024401-5
-------
Site and Pest
Eggplant
I
JA
ii
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYD8ATE AND ANHTORQUS)
Dosages and Tolerance, Use, Limitations
Forfflulation(s)
Leaf spot and fruit 10-10-100
spot (992 Cr)
(99Z SC/S)
Exempt
Apply up to a 10-10-100 mixture.
Foliar application. Apply before
disease appear*. Repeat at 7 to 10
day intervals as needed.
Loganberry
Nectarine
Peach
Bacterial canker
(gummosis)
(Pseudomonas)
Crown gall
(Agrobacterium)
Phytophthora canker
(crown rot)
See Blackberry cluster.
Exempt
Apply up to a 12-12-100 mixture.
Bordeaux Wound treatment. After infection
paste has been cut away, disinfect wounds
(99Z Cr) and allow to dry for several days.
(992 SC/S) Then cover the wounds with Bordeaux
paste.
Brown rot blossom
and twig blight
(Monilinia)
Leaf curl
(Xaphrina)
Sho thole
(Coryneum blight)
Copper deficiency
(exanthema)
Pear scab
(Venturia)
10-10-100
(992 Cr)
(94.3-9 92
SC/S)
(15-15,12
SC/L, anhy-
drous)
or
12-12-100
(94.3-982
SC/S)
See Nectarine cluster.
Dormant, delayed dormant, and foliar
application. For brown rot, apply
when buds begin to swell or at petal
-fall in certain areas. -For leaf
curl, apply in late fall or in red
bud to popcorn. For shothole, apply
in late fall and/or early spring.
10-10-100
(992 Cr)
(992 SC/S)
10-10-100
or
5-5-100
(992 SC/S)
Exempt
Apply up to a 10-10-100 mixture.
Foliar application. Apply to fol-
iage in early summer.
Delayed dormant and foliar applica-
tion. Apply 10-10-100 in red bud
to popcorn and repeat 10 days later
or just after petal fall. If leaves
are out before second application,
apply at 5-5-100.
Issued: 2-01-83
1 fl
II-024401-6
-------
308AA
DAAD
)05AA
306AA
Site and Pest
Pecan
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
~>
Dosages and Tolerance, Use, Limitations
Fozmulation(s)
Crown gall
(Agrobacterium)
Exempt
Bordeaux Hound treatment. After infection
paste has been cut away, disinfect wounds
(992 Cr) and allow to dry for several days.
(99Z SC/S) Then cover the wounds with Bordeaux
paste.
Exempt
Apply up to a 12-12-100 mixture.
VPDZ
:PDZ
)AAU
Bacterial canker
(gummosis)
(Pseudomonas)
Crown gall
(Agrobac terium)
>MCB
:CEL
Brown roc blossom
and twig blight
(Monilinia)
Shothole
(Coryneum blight)
AAC
Copper deficiency
(exanthema)
Bordeaux
paste
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
(992 SC/S)
10-10-100
(992 Cr)
(992 SC/S)
(15-15.12
SC/L, anhy-
drous)
or
12-12-100
(94.3-982
SC/S)
10-10-100
(992 Cr)
(992 SC/S)
Wound treatment. After infection
has been cut away, disinfect wounds
and allow to dry for several days.
Then cover the wounds with Bordeaux
paste.
Dormant application. For bacterial
canker and guanosis, apply in lace
fall (November and December).
Dormant, delayed dormant, and foliar
-application. For brown roc, apply
when buds begin Co swell or in red
bud to popcorn, and at petal fall
in certain areas. For s ho thole,
apply as dormant spray in late fall
and at bud swell.
Foliar application. Apply to fol-
iage in early summer.
V66
Issued: 2-01-83
II-02A401-7
-------
COPPER
Site and Pest
Potato
Early blight
(Alternaria)
Late blight
(Phytophthora)
Prune
Raspberry
I Strawberry
< Leaf spot
(Mycosphaerella)
It Tobacco
index to Pesticide Chemicals
SULFATE (PENTAHYDRATE AHD AHHYDROUS)
Dosages and ' Tolerance. Use, Limitations
Fonnulation(s)
6-8-100
(99Z SC/S)
10-10-100
(992 Cr)
(992 SC/S)
Exempt
Apply up to a 10-10-100 mixture.
Foliar application. Apply when
plants are 4 to 6 inches high.
Repeat at 10 Co 14 day intervals.
Foliar application. Apply at first
sign of disease or just before dis-
ease usually appears. Repeat at 7
to 9 day intervals for at least 4
to 5 applications'.
See Plum cluster.
See Blackberry cluster.
4-4-100
(991 SC/S)
Exempt
Apply up to a 4-4-100 mixture.
Foliar application.
TT.F.
Wildfire
(Pseudomonas)
Tomato
Early blight:
(Alternaria)
Late blight
(Phytophthora)
Leaf spot
6-8-100 Foliar application to plant beds.
[25 gal/100 Appply immediately after emergence.
sq.yd bed] Apply again 7 to 10 days later.
(992 SC/S) Usually, a third application is made
7 days later.
Exempt
Apply up to a 6-8-100 mixture.
6-8-100 Foliar application. Apply when
(992 SC/S) plants are first set out. Repeat
at 10 to 14 day intervals.
4-4-100 Foliar application.
(98.52 SC/S)
Issued: 2-01-83
II-024401-8
-------
3009AA
vAPDZ
UDAAU
iCDCM
\APCN
:TRBA
Site and Pest
Walnut
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDBATE AMD ANHYDROUS)
Dosages and Tolerance, Use. Limitations
Formulation(s)
Exempt
Apply up to a 15-10-100 mixture and
only where Bordeaux mixture has been
shown to be non-phytotoxic.
Bacterial blight
(Zanthomonas)
Bacterial canker
(gunmosis)
(Pseudomonas)
Crown gall
(Agrobacterium)
Dothiorella die-
back
(melaxuma)
Phytophthora canker
(crown rot)
Root rot
(Rosellinia)
15-10-100
(99Z Cr)
(992 SC/S)
(15-15.12
SC/S, anhy-
drous)
Bordeaux
paste
(992 Cr)
(99t SC/S)
Delayed dormant application. Apply
with 0.5 gallon summer oil emulsion.
Apply in early prebloom 10 to 20
percent pistillate (not when catkin
blooms are showing) before or after
rain.
Wound treatment. After infection
has been cut away, disinfect wounds
and allow to dry for several days.
Then cover the wounds with Bordeaux
paste.
10-10-100
(992 Cr)
(992 SC/S)
"Soil and base of tree application.
Apply when infection is detected to
base and soil around trees.
Youngberry
See Blackberry cluster.
065AA
065DA
•057AA
057DA
126AA
126DA
COJBB
ORNAMENTALS
(Ornamental Plants (herbaceous plants and bulbs; woody shrubs, trees
and vines))
General Warnings and Limitations: Dosage rates and mixing instructions
are as given in AGRICULTURAL CROPS.
Chrysanthemum
Flowering Dogwood
Iris
Leaf spots
Issued: 2-01-83
8-8-100 Foliar application. Apply in spring
(98.52 SC/S) as growth starts. Repeat as needed.
H8
II-024401-9
-------
I
P
li
iA
ii
Sice and Pest
Hollyhock
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance, Use. Limitations
Fprmulation(s)
Anthracnose
(Co lie to tri chum)
Leaf spots
Ivy
Leaf spots
Li gu s tram
Oa K.
Root rot
(Rosellinia)
Palm
4-4-100
(98.52 SC/S)
Foliar application. Apply in spring
as growth starts. Repeat as needed.
4-4-100 Foliar application. Apply in spring
(98.52 SC/S) as growth starts. Repeat as needed.
10-10-100 Soil and base of tree application.
(992 Cr) Apply when infection is detected to
(992 SC/S) base and soil around trees.
I
B
!!
Ji
S
Anthracnose
(Co lletotrichum)
Leaf spots
Scab
Peonie s
Leaf blotch
(Cladosporium)
4-4-100
(98.52 SC/S)
Foliar application. Apply in spring
as growth starts. Repeat as needed.
4-4-100 Foliar application. Apply in spring
(98.52 SC/S) as growth starts. Repeat as needed.
Issued: 2-01-83
169
11-024401-10
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance, Use, Limitations
Fotmulation(s)
NONCROP AQUATIC AREAS, INDUSTRIAL; COOLING TOWERS, PULP AND PAPER MILLS.
ETC.
018MA
02 DMA
019MA
FQBB
Air Washer Water Systems
Evaporative Condenser Water Systern
Air washers should b* pre-cleaned,
if needed, and the pH adjusted when
subject to acidifying materials.
Slime-forming fungi 0.062-0.19 Ib Water treatment. Initial dose:
Cu/1,000 gal Apply a slug dose of 0.12 to 0.19
system water pound (15 to 22 ppm) depending on
or che condition of the
7.4-22 ppm Cu sequent dose: Apply
(6.93Z KTU,
anhydrous)
D19MA
Commercial and Industrial Water
Cooline Tower Svstems
•QBE
Slime-forming fungi 0.025-0.051
Ib Cu/1,000
gal system
water
or
3.0—6.1 ppm
Cu
(20Z G)
system. Sub-
a slug dose of
0.062 Co 0.093 pound (7.4 to 11 ppm)
weekly or as needed. If microbial
growth is noticed, apply initial
slug dose and repeat until control
is evident. Upon control, apply
subsequent slug dose.
Addition may be made in the tower
sump, tower basin, or on distri-
-bntion decks unless specified.
Heavy contamination must be removed
manually.
Water treatment. Initial dose:
Apply 0.051 pound C6.1 ppm) to the
sump of the cooling tower. Repeat
until microbial control is evident.
Subsequent dose: Apply 0.025 pounc
(3.0 ppm) periodically as needed to
maintain microbial control.
Formulated with sodium pentachloro-
phenate (and sodium salts of other
chlorophenols).
Issued: 2-01-63
0.00375- Water treatment. Add directly to
0.0375 Ib cooling water.
Cu/1,000 gal Formulated with alkyl*dimethy 1
system water benzyl ammonium chloride *alkyl
or (50Z C14, 40Z C12, 102 C16).
0.45-4.5 ppm
Cu
(15Z cu)
Refer to Aii Washer W«;.er Systems cluster for
additional dose and use pattern information.
17C
11-024401-11
-------
Site and Pesc
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYJJRATE AND ANHYDROUS)
Dosages and Tolerance. Use, Limitations
Formulation(s)
Pulp and Paper Mill Systems
forming fungi 0.45-1.8
ppm Cu
(152 RTU)
Sewage Systems
Fungus growth
Water treatment. Add directly to
the mill system or to the fresh
water added to the mill system.
Formulated with alkyl*dimethyl
benzyl ammonium chloride *alkyl
(502 C14, 40Z C12, 102 C16).
0.25-0.5 Ib Water treatment. For sewer pumps
Cu/cloth bag and force mains, place bag in inlet
(75Z G) or storage well.
(96.9-1002
Cr)
0.375-1.0 Ib
Cu/drain
(752 G)
(96.9-1002
Cr)
0.25-0.49 Ib
Cu/applica-
tion
(752 G)
(96.9-1002
Cr)
0.126 Ib Cu/
application
(992 Cr)
(15.12 SC/L,
anhydrous)
Water treatment. For storm drains,
apply 0.375 to 0.5 pound and use
water hose in dry weather to carry
formulation to obstruction. If
blockage still exists after several
hours, apply 0.5 to 1.0 pound. Do
-not apply during excessive storm
flow.
Water treatment. For sewers, add
0.25 pound into each junction or
terminal manhole. Repeat every 3
months until flow is free. Add
0.375 to 0.49 pound once a year.
Water treatment. For sewers and
storm drains with partial stoppage,
flush toward blockage with 5 gallons
of water. Repeat at 6 month inter-
vals to prevent blockage. For com-
plete stopage, remove obstruction
and apply as above.
See DOMESTIC DWELLINGS, JEDICAL FACILITIES, Abu
SCHOOLS, Sewage Systems for additional dose and
use pattern information.
Issued: 2-01-83
171
11-024401-12
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRAIE AND ANHYDROUS)
Dosages and Tolerance. Use. Limitations
Fozmulation(s)
03OA
02QA
QBE
DOMESTIC DWELLINGS. MEDICAL FACILITIES. AND SCHOOLS
Grout Seams of Ceramic Tile Stall
and Tub Showers
Mold/mildew
(6*.762 RTU,
anhydrous)
26MA
QBE
Sewage Systems
Fungus growth
May temporarily cause grout to turn
light aqua color.
Surface treatment. Clean tile but
not grout seams. Do not use a w&x
or a wax cleaner. Rinse with water.
Pump spray on grout seams. Wipe
with a damp cloth before spray dries
and rinse with water. Repeat when
new growth appears.
Do not pour into sink or tub drains.
Water treatment. Use for house and
building connections to street
sewers, cesspools, or septic tanks.
As a preventative, apply 0.25 to 0.5
pound every 3 to 6 months. For
partial stoppage, apply 0.48 to 1.0
pound once. For complete stoppage,
apply 1.5 pounds, and, if needed,
again in 7 to 10 days; or, apply
1.0 pound weekly for 2 to 3 weeks.
Completely stopped lines must be
partially opened by use of a sewer
rod.
To apply, add to toilet bowl nearest
sewerline 0.125 pound at a time and
flush each time. Addition may also
be made through the nearest clean-
out plug in basement. Apply in
evening before retiring when wasce
facilities are not being used.
See NONCROP AQUATIC AREAS, INDUSTRIAL: COOLING
TOWERS, PULP AND PAPER MILLS, ETC., Sewage Systems
for additional dose and use pattern information.
0.-25-1.5 lb
Cu/applica-
tion
(75Z G)
(93.75-1002
Cr)
. or
1.5-»3 tbls
992 Cr/
application
(992 Cr)
Tm.,.mA- 3-O1-83
172
II-024401-13
-------
Site and Pest
ft
11
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance. Use, Limitations
Formulation(s)
STRUCTURES r WOOD PRODUCTS AND WOOD COMMODITY PRESERVATION
(Terrestial Structure Wood Protection)
Wood Protection Treatments of
Existing Buildings or Parts of
Buildings (including bamboo,
greenhouses, porch flooring, roof
cornices, wood buildings, and
wood fences)
Apply to clean, unpainted wood,
of oxl
free
ot oil or stains. Use on all wood
to be in contact with masonry or
destined for prolonged exposure to
moisture.
a
f
i
Mildew
Wood decay/rot
0.137 Ib Cu/
200-400
sq.ft rough
or dressed
lumber
(3.842 BTU,
anhydrous)
Wood protection treatment. May be
applied by brush, spray, or dip.
For indoor wood subject to frequent
wetting such as occurs from conden-
sation or rain seepage, or comes in
direct contact with soil, apply 1
drenching coat. ' Wood already in-
stalled indoors may be treated using
adequate ventilation. For outdoor
-wood, 2 to 3 applications are re-
commended if the wood is to be ex-
posed to weather or severe moisture.
Thoroughly treat all cracks, knot
holes, wooden joints, and bolt hole
surfaces. One coat may follow an-
other within a few minutes. Dipping
for outdoor use should be for a.
minimum of 12 hours. Where ground
or water contact is planned, incier-
sion should be from 24 to 48 hours.
Formulated with chromic acid and
sodium dichromate.
Issued: 2-01-83
173
11-024401-14
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site and Pest Dosages and Tolerance. Use. Limitations
Formulaeion(s)
Wood Protection Treatments of Existing Buildings or Parts of Buildings
(continued)
0.126 Ib Cu/ 'wood protection treatment. Best
200 sq.ft results are obtained by immersion
rough lumber for at leaat 3 to 5 minutes. Wood
or 300 sq.ft intended for uae in contact with
dressed lum- soil should be dipped for a minimum
ber, 1 coat- of 3 minutes. If applied by brush
(3.5Z HTU, or spray, lumber should receive 2
anhydrous) flowing coats. Second or succeeding
coats should be applied before pre-
vious coat is completely dry. Allow
treated surfaces to dry for at least
48 hours before painting, varnish-
ing, or glazing.
Formulated with acetic acid and
sodium dichrornate.
(Wood Products and Wood Commodities Protection)
030A Finished Wood Products (including
03NA garage doors, mi11work, outdoor
110A furniture, playground equipment,
shingles, steps, truck bodies,
wood joists, and wood sashes and
frames)
020A Seasoned Forest Products (including
02NA lumber and porch columns)
Refer to (Terrestial Structure Wood Protection),
Wood Protection Treatments of Existing Buildings
or Parts of Buildings for dose and use informa-
tion.
174
Issued: 2-01-83 11-024401-15
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SDLFATE (PENTAHYDRATE AND ANHYDROUS)
Dosages and Tolerance. Use. Limitations
Foimulation(s)
Unseasoned Forest Products (green,
peeled posts)
Hood rot/decay 4.27-4.455 Ib soil contact wood protection treat-
4k / M « _ « . _ ^ ^ _ i_ _
Cu/24 gal
water
(992 Cr)
(15.12 SC/L,
anhydrous)
•ent. Prepare the copper sulfate
solution then prepare a aecond so-
lution with sodium chromate (18.0
pounds in 26 gallons of water).
Soak the green, peeled posts butt
end down in the copper sulfate so-
lution for 3 days, then butt end
down in the sodium chromate solution
for 2 days. Finally, turn the posts
upside down in the sodium chromate
for 1 additional day. Remove and
rinse posts with clear water.
Wood Containers or Items Used for
Growing Plants (flower boxes,
trellises)
Refer to (Terrestial Structure Wood Protection),
Wood Protection Treatments of Existing Buildings
or Parts of Buildings for dose and use informa-
tion.
Wood Protection Treatment By Pres-
sure (forest products)
Wood rot/decay
0.064-0.41
Cu water
solutions
(25.5-321
sc/s)
Cu water
solutions
(8.52 SC/L)
Wood protection treatment by pres-
sure.
Formulated with one or a. combination
of: arsenic pentoxide, sodium
pyroarsenate, potassium dichrornate
and sodium dichromate.
Wood protection treatment by pres-
sure. Apply only using vaccum-
pressure impregnation. Dilute with
water to concentration needed for
final retention desired. Either
kiln dry after treatment or allow 1
week between impregnation and in-
stallation of treated wood for fix-
ation of preservative. Impregnation
procedures must rigidly adhere to
current AWPA Standards.
Formulated with arsenic acid and
* CbCLum dichromate.
Issued: 2-01-63
11-024401-16
-------
EPA Index to Pesticide Chemicals
COFFER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site and Pest Dosages and Tolerance. Use, Limitations
Formulation(s)
(Aquatic and Marine Structure Protection)
0060A Wood Boats
Refer to (Terrestial Structure Wood Protection),
Wood Protection Treatments of Existing Buildings
or Parts of Buildings for dose and use informa-
tion.
17C
Issued: 2-01-53 II-024401-17
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation
15Z (metallic Cu: 0.58 Ib/gal or 6Z)* technical chemical
copper sulfate anhydrous (024401)
010103-00010**
*copper sulfate pentahydrate equivalent: 2.3 Ib/gal
**also listed as soluble concentrate/liquid
99Z (metallic Cu; 25.21) technical chemical
copper sulfate pentahydrate (024401)
000226-00004 000550-00066 001109-00001 001109-00007
001109-00019 001109-00021 001109-00027 001109-00032
001278-00005 008901-00006 009905-00001 035896-00003
039295-00003
99.51 (metallic Cu; 25.2?) technical chemical
copper sulfate pentahydrate (024401)
011435-00001 046218-00001
501 formulation intermediate
copper sulfate pentahydrate (024401), chromic acetate (021102) plus po-
tassium dichromate (068302)
003992-00006
201 (metallic Cu; 5.092) granular
copper sulfate pentahydrate (024401) plus sodium pentachlorophenate (and
sodium salts of other chlorophenols-)- (063003)
003682-00029
75Z (metallic Cu: 18.752) granular
copper sulfate pentahydrate (024401)
005605-00173*
*aetallic copper inferred
93.752 (metallic Cu: 23.44Z) crystalline .
copper sulfate pentahydrate (024401)
009283-00001*
Metallic copper inferred
96.51 (metallic Cu; 24.1251) crystalline
copper sulfate pentahydrate (024401)
000192-00077*
*metallic copper inferred
96.9Z (metallic Cu: 24.6Z) crystalline
copper sulfate pentahydrate (024401;
007687-00001
991 (metallic Cu: 25Z) crystalline
copper sulfate pantabydrate (024401)
*»etallic copper inferred 177
Issued: 2-01-83 11-024401-18
-------
EPA Index Co Pesticide Chemicals
COPPER SULFATE (PENTAHYDBATE AMD ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
991 (metallic Cu: 25.22) crystalline
copper sulfate pentahydrate (024401)
002105-00008 003286-00030 007401-00326 007792-00001
010267-00001 045450-00001
99.412 (metallic Cu; 25Z) crystalline
copper sulfate pentahydrate (024401;
033855-00001*
^metallic copper inferred
1002 (metallic Cu; 25Z) crystalline
copper sulfate pentahydrate (024401)
000427-00048* 010906-00001
*metallic copper inferred
25.51 (metallic Cu; 6.3752) soluble concentrate/solid
copper sulfate pentahydrate (024401), arsenic pentoxide (006802) plus
sodium dichromate (068304)**
000061-00140*
*metallic copper inferred
**AWPA Standard P5: CCA, Type C
26.82 (metallic Cu: 6.7Z) soluble concentrate/solid /M.an^
copper sulfate pentahydrate (U2UOI). arsenic pentoxide (006802), soaiuo
pyroarsenate (013401) plus sodium dichromate (068304)**
000061-00139*
*metallic copper inferred
**AWPA Standard P5: CCA, Type B
322 (metallic Cu; 82) soluble concentrate/solid
copper sulfate pentahydrate (024401), arsenic pentoxide (006802) plus
potassium dichromate (066302)**
000061-00127*
*metallic copper inferred
**AWPA Standard P5: CCA, Type A
37.72 (metallic Cu; 9.51) soluble concentrate/solid
copper sulfate pentahydrate (024401;
004833-00006 020004-00004
94.31 (metallic Cu; 24Z) soluble concentrate/solid
copper sulfate pentahydrate (024401)
000279-00505 010103-00001
9S (metallic Cu; 24.962) soluble concentrate/sol id
copper sulfate pentahydrate (024401)
000279-00108
178
Issued: 2-01-83 11-024401-19
-------
EPA Index Co Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AMD ANHYDROUS)
Listing of Registered Pesticide Products by Formulation (continued)
98.51 (metallic Cu: 25Z) soluble concentrate/solid
copper sulfate pentahydrate (024401)
000140-00041*
**etallic copper inferred
99L (metallic Cat 25.21) soluble concentrate/solid
copper sulfate pentahydrate (024401)
000239-00057 001386-00304 001388-00023 001772-00086
002105-00007 002105-00009 045450-00002
8.51 (metallic Cu: 0.208 Ib/gal or 2.11) soluble concentrate/liquid
copper sulfate pentahydrate (024401), arsenic acid (006801) plus sodium
dichromate (068304)*
045968-00004
*AWPA Standard P5: CCA» Type A
15Z (metallic Cu; 0.58 Ib/gal or 6Z)* soluble concentrate/liquid
copper sulfate anhydrous (024401)
010103-00010**
*copper sulfate pentahydrate equivalent: 2.3 Ib/gal
**also listed as technical chemical
*
15.12 (metallic Cut 0.59 Ib/gal or 62)* soluble concentrate'/liquid
copper sulfate anhydrous (024401) "
038539-00002 —
*copper sulfate pentahydrate equivalent: 2.31 Ib/gal
15.1Z (metallic Cu: 0.636 Ifa/gal or 6Z)* soluble concentrate/liquid
copper sulfate anhydrous (024401)
045450-00004**
*copper sulfate pentahydrate equivalent: 2.5 Ib/gal
**metallic copper inferred
0.76Z liquid-ready to use
copper sulfate anhydrous (024401)
019214-00002
3.841 (metallic Cu; 0.137 Ib/gal or 1.5271) liquid-ready to use
copper sulfate anhydrous (024401), chromic acid (021101) plus sodium
dichromate (068304)*
003992-00001 007754-00022
*AWPA Standard P5: ACC
3.51 (aetallic Cu; 0.126 Ib/gal or 1.4Z) liquid-ready to use
eot^r sulfate anhydrous (024401), acetic acid (044001J plus sodium
dichromate (068304)*
008300-00007
*AWPA Standard P5r ACC
179
Issued: 2-01-63 II-O24401-20
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATZ AMD AHHTDROOS)
Listing of Registered Pesticide Products by Formulation (continued)
6.932 (metallic Cu; 0.248 lb/gal or 2.762) liquid-ready to use
copper sulfate anhydrous (024401)
010867-00006*
Metallic copper inferred
151 (metallic Co; 3.751) liquid-ready to use
copper sulfate pentahydrate (024401) plus alkyl*di»ethyl benzyl a
chloride *alkyl (50Z C14, 40Z C12, 10Z C16) (069105)
003876-00051* 003876-00059*
Metallic copper inferred
999 State Label Registrations
CA Beg. No.
000239-04192 0012 02-0 SOU
TX Beg. No.
003286-08093
180
Issued: 2-O1-83 11-024401-21
-------
EPA Index to Pesticide Chemical*
COPPER SULFATE (PENIAHXDRATE AND ANHYDROUS)
AGRICULTURAL CROPS
Almond
500279-00108
010103-00010
045450-00002
Apple
002105-0000 7
Apricot
000239-00057
001388-00023
039295-00008
Blackberry
002105-00007
Carrots
002105-00007
Celery
000140-00041
Cherry
001386-00304
002105-00009
039295-00008
Citrus Fruits
000279-00505
038539-00002
045450-00004
001388-00023
039295-00008
002105-00008 002105-00009
000279-00108
010103-00001
045450-00001
002105-00008
002105-00008
002105-00007
001388-00023
010103-00001
045450-00001
000279-00505
010103-00010
045450-00002
002105-00009
002105-00009
002105-00008
002105-00007
oionn-oooio
045450-00002
000279-00505 004833-00006 020004-00004
(lemon, orange, grapefruit)
' 000140-00041
045450-00001
Cutcurbits
002105-00007
Eggplant
002105-00007
Loganberry
002105-00007
Nectarine
000239-00057
002105-00008
045450-00001
010103-00010
045450-00002
002105-00008
002105-00008
002105-00008
001386-00304
002105-00009
045450-00002
038539-00002
045450-00004
002105-00009
002105-00009
002105-00009
001388-00023
010103-00001
181
010103-00001
045450-00001
001386-00304
038539-00002
045450-00004
002105-00009
002105-00008
038539-00002
045450-00004
039295-00008
002105-00007
039295-00008
Issued: 2-01-63
II-O24401-22
-------
OOOAA
OOOAA
001AA
005AA
003AA
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAffZDRATE AND ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site
AGRICULTURAL CROPS
1001AA Almond
000279-00108
010103-00010
045450-00002
000279-00505
038539-00002
045450-00004
001388-00023
039295-00008
•001AA
001AA
.002AA
073AA
003AA
002AA
Apple
562105-00007
Apricot
000239-00057
001388-00023
039295-00008
Blackberry
002105-00007
Carrots
002105-00007
Celery
500140-00041
Cherry
002105-00008
000279-00108
010103-00001
045450-00001
002105-00008
002105-00008
002105-00007
002105-00009
000279-00505
010103-00010
045450-00002
002105-00009
002105-00009
002105-^00008
001388-00023
010103-00001
045450-00001
002105-00007
010103-00010
045450-00002
001386-00304
002105-00009
039295-00008
Citrus Fruits
000279-00505 004833-00006 020004-00004
(lemon, orange, grapefruit)
000140-00041 010103-00010 038539-00002
045450-00001 045450-00002 045450-00004
Curcurbits
002105-00007 002105-00008 002105-00009
lant
05-00007
Loganberry
002105-00007
nectarine
00023°-0nne"
002105-00008
045450-00001
Issued: 2-01-83
002105-00008 002105-00009
002105-00008 002105-00009
001386-0030*
002105-00009
045450-00002
001388-00023
010103-00001
182
11-024401-22
010103-00001
045450-00001
001386-00304
038539-00002
045450-00004
002105-00009
002105-00008
038539-00002
045450-00004
039295-00008
002105-00007
039295-00008
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRAIE AMD ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site (cdntinued)
000279-00108
002105-00007
039295-00008
002105-00007
002105-00008
000279-00108
002105-00007
038539-00002
045450-00004
Peach
355239-00057
001388-00023
010103-00001
Pear
000239-00057
Pecan
002105-00007
Plum
000239-00057
001388-00023
010103-00010
045450-00002
Potato
001772-00086
Prune
000279-00108
010103-00010
045450-00002
Raspberry
002105-00007
Strawberry
000140-00041
Tobacco
001386-00304
Tomato
000140-00041 001772-00086
000279-00505
002105-00008
045450-00001
002105-00008
002105-00009
000279-00505
002105-00008
039295-00008
001386-00304
002105-00009
045450-00002
002105-00009
001386-00304
002105-00009
045450-00001
002105-00007 002105-00008 002105-00009
000279-00505
038539-00002
045450-00004
001386-00304
03929-5-00008
001388-00023
045450-00001
002105-00008 002105-00009
Walnut
552105-00007
038539-00002
045450-00004
Youngberry
0021C5-00007
002105-00008
039295-00008
002105-00009
045450-00001
010103-00010
045450-00002
002105-00006 002105-00005
Issued: 2-01-83
183
11-024401-23
-------
)65AA
D65DA
557AA
D57DA
.21AA
L21DA
.26AA
.260 A
7€AA
>76DA
88AA
88DA
93AA
93DA
97AA
97DA
51AA
51DA
EPA Index to Pesticide Chemicals
COFFER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site (continued)
ORHAtCNTALS
(OmiSMTital Plants (herbaceous plants end bulbs; *oody shrubs, trees
and vines))
Chrysanthemum
000140-00041
Flowering Dogwood
000140-00041
Hollyhock
000140-00041
Iris
000140-00041
002105-00008 002105-00009
002105-00008 002103-00009
•OHCROP AQUATIC AREAS. INDUSTRIAL; COOLCTG TOMERS. PULP AND PAPER MILLS.
ETC.
18MA Air Washer Water Syst
Ui-Obw , —JWWWU
Issued: 2-01-83
184
11-024401-24
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Appendix B
Listing of Registration Numbers By Site (continued)
4 Commercial and Industrial Water
Cooling Tower Systems
003682-00029 003876-00059 010867-00006
4 Evaporative Condenser Water System
010867-00006
4 Palp and Paper Mill Systems
003876-00051
I Sewage Systems
000427-00048 005605-00173 007687-00001 010906-00001
033855-00001 045450-00001 045450-00002 045450-00004
DOMSTIC DWELLINGS, MEDICAL FACILITIES. AND SCHOOLS
I Grout Seams of Ceramic Tile Stall
I and Tub Showers
019214-00002
t Sewage Systems
000192-00077 000427-00048 003286-00030 005605-00173
007401-00326 007687-00001 007792-00001 009283-00001
010267-00001 010906-00001 017106-00001 033855-00001
STRICTURES, WOOD PRODUCTS AND WOOD COMMODITY PRESERVATION
(Terrestial Structure Wood Protection)
I Wood Protection Treatments of
I Existing Buildings or Parts of
Buildings
003992-00001 007754-00022 008300-00007
(Wood Products and Wood Commodities Protection)
1 Finished Wood Products
I
003992-00001 007754-00022 008300-00007
1 Seasoned Forest Products
003992-00001 n«-^e./._nn««-
185
lined: 2-01-33 11-024401-25
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND'ANHYDROUS )
Appendix B
Listing of Registration Numbers By Site (continued)
•001NA Unseasoned Forest Products (green,
peeled posts)
038539-00002 039295-00008 045450-00001 045450-00002
045450-00004
004NA Wood Containers or Items Used for
Growing Plants
003992-00001 007754-00022
0100A Wood Protection Treatment By Pres-
sure (forest products)
000061-00127 000061-00139 000061-00140 045968-00004
(Aquatic and Marine Structure Protection)
0060A Wood Boats
003992-00001 007754-00022
186
T..,,*d: 2-01-83 11-024401-26
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYJ)RATE AND ANHYDROUS)
Ancillary Documentation
CFR 180.1001 Exemptions from requirement for tolerances
ls!g. Ho. 10867-6 came from the copper sulfate mooohydrate (024402) Product
^Search Listing.
•
*
Ore following labels would appear to be more appropriately coded as basic
copper sulfate (008101):
001258-01034 001386-00099 002217-00613 019713-00081
035896-00004 048391-00013 006973-03596 009859-09138
009859-09140.
These labels have not been entered in this report, but will be added to
an existing basic copper sulfate report.
Bag. Mo. 46946-166 would appear to be more appropriately coded as copper
(as metallic from cuprous and cupric oxide) (042403)._
Reg. No. 10965-9875 is CA variance and has not been entered.
leg. No's 5870-14 and 5870-15 (for use in soft drink dispensers) were
left out of the report as directd by D. Hansen due to questions about
the pest claim, Z a.i, and dosage.
A listing of those products with copper sulfate anhydrous, and those with
metallic copper inferred (reluctantly'calculated at only 25Z) can be
found on the following ancillary page.
tote also that 3876-51 and 38786-59 are liquid products with the Z copper
sulfate as pentahydrate.
187
-------
EPA Index to P««ticid« Chemicals
COPIER SULPATE (PESIAHYDIATE AMD AWTDROO8)
AncillAxy DocuMntAtion
Lilting of Begiatared Pesticide Products
000061-00127
000192-00077
000279-00505
001109-00007
001109-00032
001772-00086
003286-00030
003992-00001
005870-00014
007754-00022
009283-00001
010267-00001
017106-00001
035896-00003
045450-00001
046218-00001
000061-00139
000226-00004
000427-00048
001109-00019
001278-00005
002105-00007
003682-00029
003992-00006
005870-00015
007792-00001
009905-00001
010867-00006
019214-00002
038539-00002
045450-00002
000061-00140
000239-00057
000550-00066
001109-00021
001386-00304
002105-00008
003876-00051
004833-00006
007401-00326
008300-00007
010103-00001
010906-00001
020004-00004
039295-00003
045450-00004
000140-00041
000279-00108
001109-00001
001109-00027
001388-00023
002105-00009
003876-00059
005605-00173
007687-00001
008901-00006
010103-00010
011435-00001
033855-00001
03965-00008
045968-00004
Listing of Registered Pesticide Products
copper inferred
000061-00127*
000192-00077*
005605-00173*
033855-00001*
000061-00139?
000427-00048*
009283-00001*
045450-00004*
000061-0 QUO*
003876-00051*
010867-00006*
000140-00041*
003876-00059*
017106-00001*
Lilting of Registered Pesticide Products
copper sulfate «nhydrpus
003992-00001
010103-00010
045450-00004
007754-00022
010867-00006
008300-00007
019214-00002
010103-00010
038539-00002
188
-------
EPA Index to Pesticide Chemical*
COPPER SULFATE (PENTAffXDRATE AND AKHTDROUS)
Ancillary Documentation
Lit ting of Hegi«tered Pesticide Product*
AWPA Standard P5's
25.5Z Owtallic Cu: 6.375Z) soluble concentrate/aolid
fcopper aulfate pentahydrate (024401), arsenic peatoxide (006802) plus
> sodium dichromate (068304)
000061-00140
AWPA Standard P5: CCA, Type C
26.8Z (aetallic Cu; 6.71) soluble concentrate/aolid
copper aulfate pentahydrate-(024401), arsenic, pentoxide (006802), sodium
pyroarsenate (013401) plus sodium dichromate (068304)
000061-00139
AWPA Standard P5: CCA, Type B
321 (metallic Cut 8Z) soluble concentrate/solid
copper sulfate pentahydrate (024401), arsenic pentoxide (006802) plus
potassium dichromate (068302)
000061-00127
AWPA Standard P5: CCA, Type A
8.51 (metallic Cu; 0.208 Ib/gal or 2.12) soluble concentrate/liquid
copper sulfate pentahydrate CO24401), arsenic acid (006801) plus sodium
dichromete (068304)
045968-00004
AWPA Standard P5: CCA, Type A
3.841 (metallic Cut 0.137 Ib/gal or 1.3271) liquid-ready to use
copper sulfate anhydrous (024401), chromic acid 1021101) plus sodium
dichromate (068304)
003992-00001 007754-00022
AWPA Standard P5: ACC
3.51 (metallic Cu; 0.126 Ib/gal or 1.4Z) liquid-ready to use
copper sulfate anhydrous (024401), acetic acid 1044001) plus sodium
dichromate (068304)
008300-00007
AWPA Standard P5: ACC
189
-------
EPA Index Co Pesticide Chemicals
401 COPPER SULFATE (PENTAHYDRATE AMD ANHYDROUS)* **
TYPE PESTICIDE: Molluscicide (Also refer to Fungicide and Herbicide
entries)
FORMJLATIONS;
Tech (99.SZ)
Cr (99X, 99.5Z)
9C/L (15.11)
BTU (3.SZ)
GENERAL WARNINGS AND LIMITATIONS:
Agricultural end Livestock Tolerances^
Copper is exempted froa the requirements of a tolerance in eggs, fish,
•eat, milk, irrigated crops, and shellfish when it results from the use
of copper sulfate as an algaecide or herbicide in irrigation conveyance
systems and lakes, ponds, reservoirs, or bodies of water in which fish or
shellfish are cultivated.
Dosages and concentrations have been calculated for copper as elemental.
Concentrations and dosages are given for metallic copper (Cu) vich the
associated formulations in percent copper eulfate Cpentahydrate *r anhy-
drous). For copper sulfate pentahydrate label* that do not give the per-
centage of metallic copper, a metallic content of 25 percent of the active
ingredient was inferred for the purpose of'calculating dosages. For sim-
ilar copper sulface anhydrous labels, a* metallic concent of 39.81 percent
of the active ingredient was inferred. Refer to the formulation pages
for the percent or pounds p«r gallon of metallic o>pp«r and the percent
of copper sulfate or anhydrous copper^-sulfate for each registration. .
Definitions of Terms:
**Copper Sulfate (Pentahydrate And Anhydrous) is the name chosen to pres-
ent the active ingredient in this report. This name does not appear in
either Acceptable Common Names and Chemical Names for Che Ingredient
Statements of Pesticide Labels or Active Chemical Code List (Shaughnessy).
It was chosen to best represent the approved labeling and chemical con-
stitution. The use of this name will be confined to this report unless
otherwise noted in future reports.
•topper sulphate 190
copper sulfate pentahydrate
Bluestone
Issued: 10-20-82 III-O24401-1
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site and Pest Dosages and Tolerance. Use. Limitations
Fonnulation(s)
HOHCROP AQOATIC AREAS
(fresh water)
Remove fuzzy (fin* leaf) plants such
as foxtail (Myriophyllum verticil-
1 a turn) and clean with liae water.
Sn«il» — Water treatment. Add 1 drop«of
(3.8Z RTU) solution per gallon of aquarium
or water and repeat the following day.
0.0545 oz Cu/ Thereafter, add 1 drop in each cor-
4 oz water ner after changing water, or 1 drop
[1 drop/gal where a snail appears.
aquarium
water]
(99X Cr)
0.0545 oz Cu/ Net bath. Bathe net 2 minutes fol-
4 oz water lowed by rinse.
[10 drops/
gal dipping
solution]
(99Z Cr)
191
Issued: 10-20-82 UI-024401-2
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AHD ANHYDROUS) _
Dosages and Tolerance. Pse^.-Limitations
Formulation(«)
ilMA
Artificially Impounded Waters
(including farm ponds)
1 ppm (potable water)
Exempt (••« Agricultural and Live-
stock Tolerance statement)
Fish Caution; feould treatment oc-
cur under conditions of a heavy al-
gae infestation, in order to avoid
suffocation of fish due to lack of
oxygen caused by the decaying- vege-
tation, never treat more than one-
third to one-half of the lake or
pond at a time.. Allow sufficient
time between treatments for oxygen
levels to recover (approximately 7
to 21 days). If fish are present
and the alkalinity of the water is
less than 50 parts per million as
calcium carbonate, treat one-third
to one-faalf of the lake or pond at
a time. Allow 7 to 14 days between
treatments. Trout and other species
of fish may be killed, especially
in soft and acid water. Consult lo-
cal department of fish and game be-
fore applying copper sulfate (penta-
"hydrate) in public waters.
-ZA
Host snails of
swinners itch
AA
Leeches
0.5-1.25 ppm
Cu
[moderately
hard water]
or
1.25-2.5 ppm
Cu
(very hard
water with
alkalinity
greater than
200 ppm]
(99.5Z Cr)
1.25 ppm Cu
[moderately
hard water]
(99.5Z Cr)
Water application. Apply on calm,
sunny afternoons when water tempera-
ture is above 60 F (15.6 C). Dis-
solve and distribute over entire
pond, pools, and tributaries. Ap-
ply as a uniform surface spray.
Keep swimmers and livestock away
from the water for 5 days following
treatment; doubling this period in
very soft waters.
Issued: 10-20-82
192
III-024401-3
-------
index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANHYDROUS)
Site and Pest Dosages and Tolerance. Use, Limitations
~ FotBBilation(s)
AERIAL. MOTHPROOFIHC AND TANK MIX APPLICATIONS
Aerial Application
Refer to
ACKIOJLTPBAL CROPS
Rice
193
l,.».d: 10-20-82 HI-02MOI-*
-------
EPA Index to Pesticide Chemicals
COPPER SULPATE (PENTAHTDRATE AND ANHYDROUS)
Listing of Registered Pesticide Products by Formulation
99.5Z (metallic Cu; 25.22) technical chemical
copper sulfate pentahydrate (024401)
011435-00001
991 (metallic Cu; 25.21) crystalline
copper sulfate pentahydrate (024401)
001109-00032 001278-00008 008901-00021 010103-00005
041988-00001 045450-00001 045450-00002
99.51 (metallic Cu: 25.21) crystalline
copper sulfate pentahydrate (024401)
011435-00002 046218-00002
15.1% (metallic Cu; 0.59 Ib/gal or 61) soluble concentrate/liquid
copper sulfate anhydrous (024401)
045450-00004
3.81 (metallic Cu; 0.951) liquid ready-to-use
copper sulfate pentahydrate (024401)
008999-00003
9999 State Label Registrations
CA Reg. No.
010965-09875
MI Reg. No.
000595-04553 000635-08183 010183-08855
MN Reg. No.
001109-04655
VI Reg. No..
001109-04656
Issued: 10-20-82 III-024401-5
-------
EPA Index to Pesticide Chemicals
COPPER SULFATE (PENTAHYDRATE AND ANBYDROUS)
Appendix B
Listing of Registration Numbers By Site
AGRICULTURAL CROPS
ft Rice
001109-00032 001278-00008 008901-00021 010103-00005
045450-00001 045450-00002 045450-00004
NOBCROP AQUATIC AREAS
I Aquaria (fresh water)
008999-00003 041988-00001
I Artificially Impounded Waters
(including farm pondsT
011435-00002 046218-00002
Issued: 10-20-82 HI-024401-6
-------
Appendix II-l
Guide to Use of This Bibliography
1. CONTENT OP BIBLIOGRAPHY. This bibliography contains
citations of all studies considered relevant by EPA in
arriving at the positions and conclusions stated elsewhere
in the Standard. Primary sources for studies in this
bibliography have been the body of data submitted to EPA
and its predecessor agencies in support of past regulatory
decisions. Selections from other sources including the
published literature, In those instances where they have
been considered, will be Included.
2. UNITS OF ENTRY. The unit of entry in this bibliography
is called a "study." In the case of published materials,
this corresponds closely to an article. In the case of
unpublished materials submitted to the Agency, the Agency
has sought to identify documents at a level parallel to
the published article from within the typically larger
volumes In which they were submitted. The resulting
"studies" generally have a distinct title (or at least a
single subject), can stand alone for purposes of review,
and can be described with a conventional bibliographic
citation. The Agency has attempted also to unite basic
documents and commentaries upon them, treating them as a
single study.
3. IDENTIFICATION OF ENTRIES. The entries in this bibliography
are sorted numerically by "Master Record Identifier," or
MRID, number. This number is unique to the citation, and
should be used at any time specific reference is required.
It is not related to the six-digit "Accession Number"
which has been used to identify volumes of submitted
studies; see paragraph Md)(*l) below for a further explana-
tion. In a few cases, entries added to the bibliography
late in the review may be preceded by a nine-character
temporary identifier. These entries are listed after
all MRID entries. This temporary identifier number is
also to be used whenever specific reference is needed.
4. FORM OF ENTRY. In addition to the Master Record Identifier
(MRID) , each entry consists of a citation containing
standard elements followed, in the case of material
submitted to EPA, by a description of the earliest known
submission. Bibliographic conventions used reflect the
standards of the American National Standards Institute
(ANSI), expanded tc provide for certain special needs.
196
-------
Appendix II-l (continued)
a. Author. Whenever the Agency could confidently identify
one, the Agency has chosen to show a personal author.
When no individual was identified, the Agency has
shown an identifiable laboratory or testing facility
as author. As a last resort, the Agency has shown
the first submitter as author.
b. Document Date. When the date appears as four digits
with no question marks, the Agency took It directly
from the document. When a four-digit date is followed
by a question mark, the bibliographer deduced the
date from evidence in the document. When the date
appears as (19??), the Agency was unable to determine
or estimate the date of the document.
c. Title. In some cases, it has been necessary for
Agency bibliographers to create or enhance a document
title. Any such editorial insertions are contained
between square brackets.
d. Trailing Parentheses. For studies submitted to the
Agency in the past, the trailing parentheses include
(in addition to any self-explanatory text) the fol-
lowing elements describing the earliest known submission:
(1) Submission Date. The date of the earliest known
submission appears immediately following the word
"received."
(2) Administrative Number. The next element,
immediately following the word "under," is the
registration number, experimental use permit
number, petition number, or other administrative
number associated with the earliest known submission
(3) Submitter. The third element is the submitter,
following the phrase "submitted by." When
authorship is defaulted to the submitter, this
element is omitted .
(4) Volume Identification (Accession Numbers). The
f-^al element in the trailing parentheses
Identifies the EPA accession number of the volume
in wh
-------
APPENDIX II-2
CPPICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Copper Sulfate Standard
MRID CITATION
00001999 Atkins, L., Jr.; Anderson, L.D. (1967) Toxlcity of Pesticides and
Other Agricultural Chemicals to Honey Bees: Laboratory Studies.
(Unpublished study received Jan 30, 1969 under 900802; prepared
by Univ. of California—Riverside, Dept. of Entonolcgy, sub-
mitted by Hercules, Inc., Agricultural Chemicals, Wilmington,
Del.; CDL:0931H-D)
00047460 WARP Institute, Incorporated (1973) Report: WARP No. 2040242,
2040243, 2040244. (Compilation; unpublished study received Mar
30, 1973 under unknown admin, no.; submitted by Koclde Chemical
Corp., Houston, Tex.; CDL:132472-A)
00056781 Vedder, D.L. (1970) Pish Toxicity. (Unpublished study received Sep
16, 1970 under 8959-1; prepared by Marine Biochemists, Inc.,
submitted by Applied Biochemists, Inc., Mequon, Wis.; CEL:
100318-C)
00062069 Schroeder, H.A.; Nason, A.P.; Tipton, I.H.; et al. (1966) Essential
trace metals In man: Copper. Journal of Chronic Diseases 19:
1007-1034. (Also In unpublished submission received Aug 25,
1976 under 37952-1; submitted by Canadian Metaflna Chemicals,
New Westminster, British Columbia; CDL:228l75-D)
00065678 Cities Service Company (1965?) General Chemistry: Copper Sulfate
Monohydrate. (Unpublished study received Jun 20, 1977 under
1109-33; CDL:230760-A)
00067454 Piccirillo, V.J. (1977) Final Report: Subacute Dietary LC50 Study
In Mallard Ducks: Project No. 811-106. (Unpublished study re-
ceived Jul 11, 1977 under 1109-7; prepared by Hazleton Labora-
tories America, Inc., submitted by Cities Service Co., Atlanta,
Ga.; CEL:230839-A)
00067455 Bodden, R. (1978) Report: WARP Institute No. 7020979. (Unpublished
study received Jun 12, 1978 under 1109-7; prepared by WARF
Institute, Inc., submitted by Cities Service Co., Atlanta, Ga.;
CDL:230839-B)
0006/456 WARF Institute, Incorporated (1977) Report: WARF Institute
No. 7020979. (Unpublished study received Jul 11, 1977 under
1109-7; submitted by Cities Service Co., Atlanta, Ga.; CEL:
230839-C)
198
-------
OFFICE OF FESTICIEE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Eata Base Supporting
Registrations Under the Copper Sulfate Standard
MR3D CITATION
00070287 Richelsen Chemical Conpany (1976) Copper Sulfate Pentahydrate:
Bate of Copper in the Environment. Sunnary of studies 231553-B,
and 231553-D through 231553-P. (Unpublished study received
Sep 13, 1977 under 41071-1; CDL.-231553-A)
00070288 U.S. Bureau of Sport Fisheries and Wildlife (1974) A Review of
the Literature on the Use of Copper Sulfate in Fisheries.
N.P. (PB-235 445; pp. 20, 41, 58, 59 only; available from:
National Technical Information Service, Springfield, VA; pub-
lished study; CEL:231553-B)
00099168 Vedder, D.L. (1970) Fish toxicity: [Cutrine]. (Unpublished study
received Sep 16, 1970 under 8959-1; prepared by Marine Bio-
chemists, Inc., submitted by Applied Biochemists, Inc., Mequon,
Wis.; CEL:00566l-F)
00099255 Phelps Dodge Refining Company (1962?) Full Reports of Investiga-
tions Made with Safety of the Pesticide Chemical: [Copper Sul-
fate as an Alglclde]. (Unpublished study received Nov 17, 1970
under 1F1093; CDL:090853-A)
00099256 Claypole, G. (19??) Careful Use of Chemicals Controls Lake Weeds
and Algae. N.P. (Also in unpublished submission received Nov
17, 1970 under 1F1093; submitted by Phelps Dodge Refining Co.,
New York, N.Y.; CDL:090853-B)
00099557 Sodden, R. (1978) [Toxicity Study of Cltgo Tri-Basic Copper Sul-
fate to Bobwhite Quail]. (Unpublished study received Jul 31,
1978 under 1109-13; prepared by Ralston Purina Co., submitted
by Cities Service Co., Atlanta, GA; CDL:234567-A)
00099258 Anon. (1965) New ways to apply aquatic herbicides. Weeds, Trees
and Turf ?(Feb/Apr):? (Also in unpublished submission re-
ceived Nov 17, 1970 under 1F1093; submitted by Phelps Dodge
Refining Co., New York, N.Y.; CDL:090853-D)
00099259 Bennett, D.G. (1967) Aquatic weed control becomes technical Opera-
tion. Weeds, Trees and Turf ?(May):? (Also in unpublished
submission received Nov 17, 1970 under 1F1093; submitted by
Phelps Dodge Refining Co., New York, N.Y.; CDL:090853-E)
00099260 Toth, S.J.; Riemer, D.N. (19??) Algae control in farm ponds: Are
present dosage rates of copper sulphate always adequate. [With-
out title]?:? (Also in unpublished submission received Nov
17 19^0 under 1F1093; submitted by Phelps Dodge Refining Co.,
New York, N.Y.; CEL:090853-F)
199
-------
OFFICE OF FESTICIEE PROGRAMS
REGISTRATION STANDARD BTRT.TOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Copper Sulfate Standard
MR3D CITATION
00099262 Riemer, D.N.; Toth, S.J. (1970) Adsorption of copper by clay
minerals, hunic acid and bottom muds. Journal of American Water
Works Association 62(3):195-197. (Also In unpublished sub-
mission received Nov 17, 1970 under 1P1093; submitted by Phelps
Dodge Refining Co., New York, N.Y.; CEL:090853-H)
00099263 Toth, S.J.; Riemer, D.N. (1968) Precise chemical control of algae
In ponds. Journal of Anerlcan Water Works Association 60(3):
367-371. (Also in unpublished submission received Nov 17, 1970
under 1P1093; submitted by Phelps Dodge Refining Co., New York,
N.Y.; CDL:090853-D
00099269 Agway, Incorporated (1971) [Efficacy of Various Compounds for Dry-
ing Cnion Foliage and Regulating Harvest Time]. (Compilation;
unpublished study received Jul 20, 1972 under 2F1226; CDL:
091056-A)
00099281 Markey, J.W. (1970) Letter sent to Lee Terbush dated Dec 14, 1970:
Petition on copper sulfate In water—additional information on
inerts. (Unpublished study received Nov 24, 1970 under 1F1073;
submitted by Cities Service Co., Atlanta, Ga.; CDL:093383-A)
00099282 Hale, F.E. (1942) The Use of Copper Sulfate In Control of Micro-
scopic Organisms. New York, N.Y.: Phelps Dodge Refining Corp.
(Also In unpublished submission received Nov 24, 1970 under
1F1073; submitted by Cities Service Co., Atlanta, Ga.; CDL:
093383-B)
00099284 Armstrong, E.L. (19??) Undated letter sent to Joseph G. Cunnings
[Copper sulfate pentahydrate to control algae and aquatic
weeds]. (U.S. Dept. of the Interior, Bureau of Reclamation;
unpublished study; CDL:093383-E)
00099288 Stauffer Chemical Company (1970?) Sutan(R): Bwlronmental Stud-
ies. Suomary of studies 097089-B through 097089-G. (Unpub-
lished study received on unknown date under 1F1042; GEL:
097089-A)
00099374 McCarm, J.A. (1971) [Humco Copper Sulfate: Bluegill (Lepctnis
macrochirus)]: Test No. 366. (U.S. Agricultural Research
Service, Pesticides Regulation Div., Animal Biology Laboratory;
unpublished study; CDL:130336-A)
00099522 Tlmuss, D. (1975) Laboratory Analysis: [Copper Sulfate]: File
No. 9206A. (Unpublished study received Apr 23, 1976 under
37952-1; prepared by Can Test Ltd., Canada, submitted by Cana-
dian Metaflna Chemicals, New Westminster, BC; CDL:228l72-B)
200
-------
CPPICE CP FESTICIEE PROGRAMS
REGISTRATION STANEARD BIBLIOGRAPHI
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Copper Sulfate Standard
MRID CTHKn.CH
00099537 Merenluk, G.; Medrfiibovskala, Z. (1970) The contamination of son
and fruit by copper-containing peticides. Glgiena 1 Sanlt. 35
(1):108-10. Taken from: Health Aspects of Pesticides Abstract
Bulletin 3:^5. (U.S. Dept. of Health, Education and Welfare
generated; abstract 70-1590; published study; CEL:228l73-Q)
00099551 Wilbur Ellis Co. (19??) [Ingredients, Composition and Manufacturing
Process of Copper Sulphate Paitahydrate]. (Unpublished study
received May 31, 1978 under 2935-412; CDL:234177-A)
00099556 WARP Institute, Inc. (1978) Report: WARP Institute No. 8031062-
1065. (Unpublished study received Jul 12, 1978 under 7368-28;
submitted by Georgia-Pacific Corp., Newport Beach, CA; CEL:
00099558 LeBlanc, G. ; Surprenant, D. (1978) Acute Tbxicity of Copper Sulfate
Granular Crystals to the Water Flea (Daphnia magna): Report
No. BW-78-7-211. (Unpublished study received Aug 22, 1978 under
1109-20; prepared by EG 4 G, Bionomics, submitted by Cities
Service Co., Atlanta, GA; CEL:23^664-A)
00099559 Heltznuller, T. (1978) Toxicity of Cities Service Company's Copper
Sulfate (pentahydrate) to Pink Shrimp (Penaeus duorarum): Re-
port No. BP-78-8-109. (Unpublished study received Aug 22, 1978
under 1109-20; prepared by EG & G, Bionomics, submitted by
Cities Service Co., Atlanta, GA; CDL:234664-B)
00099561 Hollister, T. (1978) Toxicity of Copper Sulfate (pentahydrate) to
Embryos of Eastern Oysters (Crassostrea vlrglnlca): Report
No. BP-78-8-108. (Unpublished study received Aug 22, 1978 under
1109-20; prepared by EG & G, Bionomics, submitted by Cities
Service Co., Atlanta, GA; CEL:234664-D)
00106119 Picclrillo, V. (1977) Final Report: Subacute Dietary I£50 Study
In Bobviiite Quail: Project No. 811-105. (Unpublished study re-
ceived Ffay 23, 1977 under 1109-7; prepared by'Bazleton Labora-
tories America, iu.., submitted by Cities Service Co., Atlanta,
GA; CDL:2302W-A)
201
-------
OMB Approval 2070-0057 (expires 5/31/56)
CERTIFICATION OF ATTEMPT TO ENTER
INTO AN AGREEMENT WITH OTHER REGISTRANTS
Itqalify, certify ^LL four items) FOR DEVELOPMENT OF DATA
Uam duly authorized to represent the following firm(s) who are subject to the require-
ments of a Notice under FIFRA Section 3(c)(2)(B) contained in a Guidance Document
to submit data concerning the active ingredient:
NAME OF FIRM
GUIDANCE DOCUMENT DATE
ACTIVE INGREDIENT
EPA COMPANY NUMBER
ffefirm or group of firms is referred to below as "my firm".)
;lMy firm is willing to develop and submit the data as required by that Notice, if necessary. However, my firm would prefer to enter
' into an agreement with one or more other registrants to develop jointly, or to share in the cost of developing, the following required
'. items or data:
I My firm has offered in writing to enter into Rich an agreement. Copies of the offers are attached. That offer was irrevocable and included an otter to DC
bound by an arbitration decision under FIFRA Section 3(c)(2)(B)(iii» if final agreement on all terms could not be reached otherwise. This offer was made
to the following firm(s) on the following dateisi :
NAME OF FIRM
DATE OF OFFER
Ulv firm reauestc that EPA not suspend the registration (s) of my firm's product(s), if any of the firms named in paragraph (3) above
.my iirm requests in
-------
u."^ A, rroval 21,0-0057
(Empires 5/31/86'>
FIFHA SECTION 3(C)(2)(B) SUMMARY SHEET
WDUCT NAME
EPA REGISTRATION NO.
IPPLIC. ..„.,,,_ , GU|DANCE DOCUMENT
m respect to the requirement to submit "generic" data imposed by the FIFRA section 3(CK2)(B) notice contained in the referenced
Guidance Document, I am responding in the following manner:
D1. I will submit data in a timely manner to satisfy the following requirements. If the test procedures I will use deviate from (or ere no:
specified in) the Registration Guidelines or the Protocols contained in the Reports of Expert Groups to the Chemicals Group, OECC
Chemicals Testing Programme, I enclose the protocols that I will use:
D2. I have entered into an agreement with one or more other registrants under FIFRA section 3(C)(2)(B)(iil to satisfy the following dau
requirements. The tests, and any required protocols, will be submitted to EPA by:
NAME OF OTHER REGISTRANT
D3. I enclose e completed "Certification of Attempt to Enter Into an Agreement with Other Registrants for Development of Data" wit!-
respect to the following aata requirements:
A. I request that you amend my registration by deleting the following uses (this option is not available to applicants for new products):
D 5. I reouest voluntary cancellation of the registration of this product. (This option is not available to applicants for new products.'
"EGISTRANT'S AUTHORIZED REPRESENTATIVE
SIGNATURE
DATE
»A Form 8580-1 (10-82)
-------
Appendix HI-1
PRODUCT SPECIFIC DATA REPORT
EPA Registration No. Guidance Docunent for
Date
Registration
Guideline No.
§158.20
PRODUCT
CHEMISTRY
61-1
61-2
61-3
62-1
62-2
62-3
63-2
6>3
63-^
63-c
63-6
63-7
6<-e
63-9
63-10
63-H
63-12 i
Name of Test
Identity of
ingredients
Statement of
composition
Discussion of
formation of
ingredients
Preliminary
analysis
Certification of
limits
Analytical methods
for enforcement
limits
Color
Physical state
Odor
Melting point
Boiling point
Density, bulk-
density, or
specific gravity
Solubility
Vapor pressure
Dissociation
constant
Octanol/water
partition
coefficient
J^ — 1
Test not
required
for my
product
listed
above
(check
below)
I am complying with
data requirements by
Citing WOE*
Submit-
ting
Data
(At-
tached)
(Ftor H>A Use Only)
Accession Numbers
Assigned
204
-------
Appendix III-l (continued)
Registration
Guideline No.
63-13
63-14
63-15
63-16
63-17
63-18
63-19
63-20
63-21
§158.135
TOXICOLOGY
81-1
81-2
81-3
8i-ii
81-5
81-6
Name of Test
Stability
OxixJ izlng/ reduc ing
reaction
Flaninabllit£
Explodability
Storage stability
Viscosity
Miscibility
Corrosion
characteristics
Dielectric break-
down voltage
Acute oral LD-50,
rat
Acute dermal
ID-50
Acute inhalation,
LC-50 rat
Primary eye
irritation, rabbit
Primary dermal
Irritation
Dermal sensitiza-
tion
Test not
required
for my
product
listed
above
(check
below)
I am complying with
data requirements by
Citing MRID#
Submit-
ting
Data
(At-
tached)
(For EPA Use Only)
Accession Numbers
Assigned
205
-------
Appendix IV-1
Chapter I—Environmental Protection Agency
§162.10 Labeling requirements.
(a) General—(1) Contents of the label. Every pesticide
product shall bear a label containing the information specified by
the Act and the regulations in this Part. The contents of a
label must show clearly and prominently the following:
(1) The name, brand, or trademark under which the product is
sold as prescribed in paragraph (b) of this section;
(11) The name and address of the producer, registrant, or
person- for whom produced as prescribed in paragraph (c) of this
section;
(Hi) The net contents as prescribed in paragraph (d) of this
section;
(iv) The product registration number as prescribed In paragraph
(e) of this section;
(v) The producing establishment number as prescribed in para-
graph (f) of this section;
(vi) An ingredient statement as prescribed in paragraph (g) of
this section;
(vii) Warning or precautionary statements as prescribed in
paragraph (h) of this section;
(vill) The directions for use as prescribed in paragraph (1)
of this section; and
(lx^ The use classification(s) as prescribed In paragraph (j)
of this section.
(2) Prominence and legibility. (i) All words, statements,
graphic representations, designs or other information required or,
the labeling by the Act or the regulations in this part must be
clearly legible to a person with normal vision, and must be placed
with such conspicuousness (as compared with other words, state-
ments, designs, or graphic matter on the labeling) and expressed
in such terns a.s to ^enl^r It Mk^ly -. •; '•; * "e^I an? understood
by the ordinary Individual under customary conditions of purchic-
and use.
(11) All required label text must:
(A) Be set In 6-point or larger type;
(3) Appear on = clear contrasting background; and
(C) Not be obscured or crowded.
(?) Language to be used. All required label or labeling text
shall appear in the English language. However, the Agency may
require or the applicant may propose additional text In other
languages as is considered necessary to protect the public. When
additional text in another language is necessary, all labeling
requirements will be applied equally to both the English and
other-language versions of the labeling.
(h ) Placement of Latdl- - : i ] General. The 1 it; 1 shal 1 ^;_; : -. -
on or be securely attached to the immediate container of the
206
-------
Appendix IV-1 (continued)
pesticide product. For purposes of this Section, and the mis-
branding provisions of the Act, "securely attached" shall mean
that a label can reasonably be expected to remain affixed during
the foreseeable conditions and period of use. If the Immediate
container is enclosed within a wrapper or outside container
through which the label cannot be clearly read, the label must
also be securely attached to such outside wrapper or container,
if it is a part of the package as customarily distributed or
sold.
(ii) Tank cars and other bulk containers — (A) Transportation.
While a pesticide product is in transit, the appropriate
provisions of *»9 CPR Parts 170-189, concerning the transportation
of hazardous materials, and specifically those provisions con-
cerning the labeling, marking and placarding of hazardous materials
and the vehicles carrying them, define the basic Federal require-
ments. In addition, when any registered pesticide product is
transported in a tank car, tank truck or other mobile or portable
bulk container, a copy of the accepted label must be attached to
the shipping papers, and left with the consignee at the time of
delivery .
(B) Storage . When pesticide products are stored in bulk
containers, whether mobile or stationary, which remain in the
custody of the user, a copy of the label of labeling, including
all appropriate directions for use, shall be securely attached to
the container in the immediate vicinity of the discharge control
valve.
(5) False or misleading statements. Pursuant to section
2(q)(l)(A) of the Act, a pesticide or a device declared subject
to the Act pursuant to § 162.15, is mlsbranded if its labeling is
false or misleading in any particular including both pestlcidal
and non-pesticidal claims. Examples of statements or representations
in the labeling which constitute misbranding Include:
(1) A false or misleading statement concerning the composition
°f (ii! PA°false or misleading statement concerning the 'effectiveness
of the product as a pesticide or device;
(ill) A false or misleading statement about the value of the
product for purposes other than as a pesticide or device;
(iv) A false or misleading comparison with other pesticides or
vny statement directly or indirectly implying that the
pesticide or device is recommended or endorsed by any agency of
°rfviii)""li'ielTSi!iclaimer8 whlcfTnegate" or detract from labeling
statements r-equlrid under the Act and these regulations;
207
-------
Appendix IV-1 (continued)
(ix) Claims as to the safety of the pesticide or its ingredients,
including statements such as "safe," "nonpoisonous," "noninjurious,"
"harmless" or "nontoxic to humans and pets" with or without such
a qualifying phrase as "when used as directed"; and
(x) Non-numerical and/or comparative statements on the safety
of the product, Including but not limited to:
(A) "Contains all natural ingredients";
(B) "Among the least toxic chemicals known"
(C) "Pollution approved"
(6) Final printed labeling. (1) Except as provided in
paragraph (a)(6)(11) of this section, final printed labeling must
be submitted and accepted prior to registration. However, final
printed labeling need not be submitted until draft label texts
have been provisionally accepted by the Agency.
(il) Clearly legible reproductions or photo reductions will be
accepted for unusual labels such as those silk-screened directly
onto glass or metal containers or large bag or drum labels. Such
reproductions must be of microfilm reproduction quality.
(b) Name, brand, or trademark. (1) The name, brand, or
trademark under which the pesticide product is sold shall appear
on the front panel of the label.
(2) No name, brand, or trademark may appear on the label which:
(1) Is false or misleading, or
(11) Has not been approved by the Administrator through
registration or supplemental registration as an additional name
pursuant to § l62.6(b)(4).
(c) Name and address of producer, registrant, or person for
whom produced. An unqualified name and address given on the
label shall be considered as the name and address of the producer.
If the registrant's name appears on the label and the registrant
is not the producer, or if the name of the person for whom the
pesticide was produced appears on the label, it must be qualifier
by appropriate wording such as "Packed for «**,» "Distributed by
«»»," or "Sold by »*«" to show that the name is not that of the
producer.
(d) Net weight or measure of contents. (1) The net weight or
measure of content shall be exclusive of wrappers or other
materials and shall be the average content unless explicitly
stated as a minimum quantity.
(2) If the pesticide is a liquid, the net content statement
shall be in terms of liquid measure at 68°F (20°C) and shall be
expressed in conventional American units of fluid ounces, pints,
quarts, and gallons.
(3) If the pesticide is solid or semisolld, viscous or
pressurized, or is a mixture of liquid and solid, the net content
statement shall be in terms of weight expressed as avoirdupois
pounds and ounces.
(4) In all cases, net content shall be stated In terms of tne
largest suitable units, i.e., "1 pound 10 ounces" rather than
"26 ounces."
208
-------
Appendix IV-1 (continued)
(5) In addition to the required units specified, net content
may be expressed in metric units.
(6) Variation above minimum content or around an average is
permissible only to the extent that it represents deviation
unavoidable in good manufacturing practice. Variation below a
stated minimum is not permitted. In no case shall the average
content of the packages in a shipment fall below the stated
average content.
(e) Product registration number. The registration number
assigned to the pesticide product at the time of registration
shall appear on the label, preceded by the phrase "EPA Registration
No.," or the phrase "EPA Reg. No." The registration number shall
be set in type of a size and style similar to other print on that
part of the label on which it appears and shall run parallel to
it. The registration number and the required identifying phrase
shall not appear in such a manner as to suggest or imply
recommendation or endorsement of the product by the Agency.
(f) Producing establishments registration number. The producing
establishment registration number preceded by the phrase "EPA
Est.", of the final establishment at which the product was produced
may appear in any suitable location on the label or immediate
container. It must appear on the wrapper or outside container of
the package if the EPA establishment registration number on the
immediate container cannot be clearly read through such wrapper
or container.
(g) Ingredient statement—(1) General. The label of each
pesticide product must bear a statement which contains the name
and percentage by weight of each active Ingredient, the total
percentage by weight of all inert ingredients; and if the pesticide
contains arsenic in any form, a statement of the percentages of
total and water-soluble arsenic calculated as elemental arsenic.
The active ingredients must be designated by the term "active
ingredients" and the inert ingredients by the term "inert
ingredients," or the singular forms of these terms when appropriate
Both terms shall be in the same type size, be aligned to the same
margin and be equally prominent. The statement "Inert Ingredients,
none" is not required for pesticides which contain 100 percent
active ingredients. Unless the Ingredient statement is a complete
analysis of the pesticide, the term "analysis" shall not be used
as a heading for the ingredient statement.
(2) Position of Ingredient statement. (1) The ingredient
statement is normally required on the front panel of the label.
If there is an outside container or wrapper through which the
ingredient statement cannot be clearly read, the Ingredient
statement must also appear on such outside container or wrapper.
If the size or form of the package makes it Impracticable to place
the Ingredient statement on the front panel of the label, perir-sr.-
may be granted for the ingredient statement to appear elsewhere.
(i«) ^he text of the ingredient statement must run parallel
witlf other text on the panel on which it appears, and must be
clearly distinguishable from and must not be placed in the body
of other text.
209
-------
Appendix IV-1 (continued)
(3) Names to be used in ingredient statement. The name used
for each ingredient shall be the accepted common name, if there
is one, followed by the chemical name. The common name may be
used alone only if it is well known. If no common name has been
established, the chemical name alone shall be used. In no case
will the use of a trademark or proprietary name be permitted unless
such name has been accepted as a common name by the Administrator
under the authority of Section 25(c)(6).
(H) Statements of percentages. The percentages of ingredients
shall be stated in terms of weight-to-weight. The sum of per-
centages of the active and the inert ingredients shall be 100.
Percentages shall not be expressed by a range of values such as
"22-25%." If the uses of the pesticide product are expressed as
weight of active ingredient per unit area, a statement of the
weight of active ingredient per unit volume of the pesticide
formulation shall also appear in the ingredient statement.
(5) Accuracy of stated percentages. The percentages given
shall be as precise as possible reflecting good manufacturing
practice. If there may be unavoidable variation between manu-
facturing batches, the value stated for each active ingredient
shall be the lowest percentage which may be present.
(6) Deterioration. Pesticides which change in chemical
composition significantly must meet the following labeling re-
quirements :
(1) In cases where it is determined that a pesticide formulation
changes chemical composition significantly, the product must bear
the following statement in a prominent position on the label: "Not
for sale or use after [date]."
(ii) The product must meet all label claims up to the expiration
time indicated on the label.
(7) Inert ingredients. The Administrator may require the name
of any inert Ingredient(s) to be listed in the ingredient statement
if he determines that such ingredient(s) may pose a hazard to man
or the environment.
(h) Warnings ana precautionary statements. Required warnings
and precautionary statements concerning the general areas of
toxicologlcal hazard including hazard to children, environmental
hazard, and physical or chemical hazard fall into two groups; those
required on the front panel of the labeling and those which may
appear elsewhere. Specific requirements concerning content,
placement, type size, and prominence are given below.
(1) Required front panel statements. With the exception of the
child hazard warning statement, the text required on the front
panel of the label is determined by the Toxicity Category of the
pesticide. The category is assigned on the basis of the highest
hazard shown by any of the indicators in the table below:
210
-------
A;penc'x IV-1 ( cor -, i --. j« a ':
Hazard Indicators
Oraf LD^
Inhalation LC
1
Derma! LD
50
Eye effects
Skin effects
1
Up to and
Including
50 ag/kg
Up to and
Including
.2 no/ liter
Up to and
Including
200 tig/kg
Corrosive;
corneal opacity
not reversible
within 7 days
Corrosive
Toxlclty <
II
Fran 50 thru
500 ng/kg
From .2 thru
2 «g/l Iter
From 200
thru 2000
Corneal opacity
reversible
within 7 days;
Irritation
persisting for
7 days
Severe Irritation
at 72 hours
:ategor1es
III
Fro* 500 thru
5000 «g/kg
Froai 2 thru
20 -g/l Iter
From 2,000 thru
20,000
No cornea 1 opacity;
Irritation
reversible
•Ithln 7 days
Moderate Irritation
at 72 hours
IV
Greater than
5000 «g/kg
Greater than
20 wg/l Her
Greater than
20,000
No Irritation
Mild or sl'ght
Irritation at
72 hou's
(1) Human hazard signal word.—(A) Toxiclty Category I. All
pesticide products meeting the criteria of Toxicity Category 1
shall bear on the front panel the signal word "Danger." In
addition if the product was assigned to Toxlcity Category 1 on
the basis of Its oral, Inhalation or dermal toxlcity (as distinct
from skin and eye local effects) the word "Poison" shall appear
in red on a background of distinctly contrasting color and the
skull and crossbones shall appear in immediate proximity to the
word "poison."
All pesticide products meeting the
II shall bear on the front panel
(B) Toxicity Category II
criteria of Toxlcity Category
the signal word "Warning."
(C) Toxicity Category III.
criteria of Toxicity Category
the signal word "Caution."
(D) Toxicity Category IV.
criteria of Toxicity Category
the slenal word "Caution."
All pesticide products meeting the
III shall bear on the front panel
All pesticide
IV shall bear
products njcciir^ i:
on the front panel
211
-------
Appendix IV-1 (continued)
(E) Use of signal words. Use of any signal word(s) associated
with a higher Toxlcity Category is not permitted except when the
Agency determines that such labeling is necessary to prevent
unreasonable adverse effects on man or the environment. In no
case shall more than one human hazard signal word appear on the
front panel of a label.
(ii) Child hazard warning. Every pesticide product label shall
bear on the front panel the statement "keep out of reach of
children." Only in cases where the likelihood of contact with
children during distribution, marketing, storage or use is
demonstrated by the applicant to be extremely remote, or if the
nature of the pesticide is such that it is approved for use on
infants or small children, may the Administrator waive this
requirement.
(ill) Statement of practical treatment—(A) Toxicity
Category T7A statement of practical treatment (first aid or
other) shall appear on the front panel of the label of all
pesticides falling into Toxicity Category I on the basis of oral,
inhalation or dermal toxicity. The Agency may, however, permit
reasonable variations in the placement of the statement of
practical treatment is some reference such as "See statement of
practical treatment on back panel" appears on the front panel
near the word "Poison" and the skull and crossbones.
(B) Other toxicity categories. The statement of practical
treatment is not required on the front panel except as described
in paragraph (h)(1)(ill)(A) of this section. The applicant may,
however, include such a front panel statement at his option.
Statements of practical treatment are, however, required elsewhere
on the label in accord with paragraph (h)(2) of this section if
they do not appear on the front panel.
(iv) Placement and prominence. All the required front panel
warning statements shall be grouped together on the label, and
shall appear with sufficient prominence relative to other front
panel text and graphic material to make them unlikely to be over-
looked under customary conditions of purchase and use. The
following table shows the minimum type size requirements for the
front panel warning statements on various sizes of labels:
Si?p of label front panel
in square inches
CTTer '0
Points
Required
signal word,
all capitals
6
10
12
U
i P
"Keep out
of reach of
Children"
6
6
6
i **
i *•*
212
-------
Aj.pe;,5ix IV-1 (continued)
(2) Other required warnings and precautionary statements. The
warnings and precautionary statements as required below shall appear
together on the label under the general heading "Precautionary
Statements" and under appropriate subheadings of "Hazard to Humans
and Domestic Animals," "Environmental Hazard" and "Physical or
Chemical Hazard.11
(1) Hazard to humans and domestic animals. (A) Where a hazard
exists to humans or domestic animals, precautionary statements
are required indicating the particular hazard, the route (s) of
exposure and the precautions to be taken to avoid accident, injury
or damage. The precautionary paragraph shall be Immediately
preceded by the appropriate hazard signal word.
(B) The following table depicts typical precautionary statements.
These statements must be modified or expanded to reflect specific
hazards .
Toxlclty
category
Precautionary statements by toxldty category
Ore!. Inhalation, or dermal toxicIty
Skin and eye local effects
II
IV
Fatal (poisonous) If swallowed [Inhaled o-
absorbed through sk'n]. Do not breathe
vapor [dust] or spray mist]. Do not get
In eyes, on skin, or on clothing IFront
panel statement of practical treatment
required.].
May be fatal If swallowed [Inhaled o-
absorbed through the skin]. Do not breathe
vapors [dust or sprav rr's*l. Do not get In
•yes, on skin, or on clothing. [Appropriate
first eld statements required.!.
HeTrfii' 'f swan owe:? Pnhafed or absorbed
through the sklnl. Avoid breathing vapors
[dust or spray mist]. Avoid contact with
skin [eyes or clothing], [Appropriate
first aid statement required.].
\Ho p'ecautlona~y statements required.].
Corrosive, causes eye and skin damage [or [
skin Irritation], Do not get In eyes, on j
skin, or on cloth'ng. Wear goggles or face |
shield and rubber gloves when handling. |
Harmful or fatal If swallowed. |
[Appropriate first atd statement required.) |
I
Causes eye [and skin] Irritation. Do not |
get In eyes, on skin, or on clothing. |
Harmful If swallowed. (Appropriate first |
aid statement required.). I
I
Avoid contact with skin, eyes or clothing. |
In case of contact Immec! lately flus:- j
eyes or skin with plenty .of water. Get |
medical attention If Irritation pe-s'sts. ;
INo precautionary statements re<;u''ec.
(ii) Environmental hazards. Where a hazard exists to non-
target organisms excluding humans and domestic animals, precautionary
statements are required stating the nature of the hazard and the
appropriate precautions to avoid potential accident, in^i, -^
213
-------
Appendix IV-1 (continued)
damage. Examples of the hazard statements and the circumstances
under which they are required follow:
(A) If a pesticide intended for outdoor use contains an active
ingredient with a mammalian acute oral LDcQ of 100 or less, the
statement "This Pesticide is Toxic to Wildlife" is required.
(B) If a pesticide Intended for outdoor use contains an active
ingredient with a fish acute LCc0 of 1 ppm or less, the statement
"This Pesticide is Toxic to Pish" is required.
(C) If a pesticide intended for outdoor use contains an active
ingredient with an avian acute oral LDc0 of 100 rag/kg or less, or
a subacute dietary 1*050 °f 5°° PP01 or less, the statement "This
Pesticide is Toxic to Wildlife" is required.
(D) If either accident history or field studies demonstrate
that use of the pesticide may result in fatality to birds, fish
or mammals, the statement "This pesticide is extremely toxic to
wildlife (fish)" is required.
(E) For uses involving foliar application to agricultural
crops, forests, or shade trees, or for mosquito abatement
treatments, pesticides toxic to pollinating insects must bear
appropriate label cautions.
(F) For all outdoor uses other than aquatic applications the
label must bear the caution "Keep out of lakes, ponds or streams.
Do not contaminate water by cleaning of equipment or disposal of
W3. S t C S *'
(ill) Physical or chemical hazards. Warning statements on the
flammability or explosive characteristics of the pesticide are
required as follows:
Flasn point
Requires te*t
(A) PRESSURIZED CONTAINERS
Flash point at or belo* 20*F; If there Is a
flashback at any valve opening.
Flash point above 20*F and not over 80*F or If
the Hame extension Is wore than 18 In. long
at a distance of 6 In. from the flame.
All other pressurized containers
L-
Extremely flammable. Contents under pressure.
Keep e«ay from fire, sparks, end heeted
surfaces. Do not puncture or Incinerate
container. Exposure to temperatures above
!30*F may cause bursting.
FlawMble. Contents under pressure. Keep e«sy
fro* heat, sparks, and open flame. Do not
puncture or Incinerate container. Exposure to
temperatures above 150*F «ay cause bursting.
Contents under pressure. Do not use or store
near heat or open flame. Do not puncture o-
Incinerate container. Exposure to tempera-
tures above 13C*f may cause bursting.
_
(B) NONPRESSURIZED CONTAINERS
T
At or be low 20*F
j Extremely flammable. Keep away from fire, !
| sparks, and heated surfaces. i
Above 20'F and not over 80«F | Placable. Keep a.ay fro. heat and open flame. |
| Above 80V anc not over ISC'F | Do not use c- s*o-e nee- heat o- ore-
214
-------
Appendix IV-1 (continued)
(1) Directions for Use—(1) General requirements—(1) Adequacy
and clarity of directions. Directions for use must be stated in
terms which can be easily read and understood by the average
person likely to use or to supervise the use of the pesticide.
When followed, directions must be adequate to protect the public
from fraud and from personal injury and to prevent unreasonable
adverse effects on the environment.
(11) Placement of directions for use. Directions may appear
on any portion of the label provided that they are conspicuous
enough to be easily read by the user of the pesticide product.
Directions for use may appear on printed or graphic matter which
accompanies the pesticide provided that:
(A) If required by the Agency, such printed or graphic matter
Is securely attached to each package of the pesticide, or placed
within the outside wrapper or bag;
(B) The label bears a reference to the directions for use In
accompanying leaflets or circulars, such as "See directions in
the enclosed circular." and
(C) The Administrator determines that it is not necessary for
such directions to appear on the label.
(ill) Exceptions to requirement for direction for use—(A)
Detailed directions for use may be omitted from labeling of
pesticides which are intended for use only by manufacturers of
products other than pesticide products in their regular manu-
facturing processes, provided that:
(!_) The label clearly shows that the product is intended for
use only in manufacturing processes and specifies the type(s) of
products Involved.
(2) Adequate information such as technical data sheets or
bulletins, is available to the trade specifying the type of
product involved and its proper use in manufacturing processes;
(3) The product will not come into the hands of the general
pubTic except after incorporation into finished products; and
(^) The Administrator determines that such directions are not
necessary to prevent unreasonable adverse effects on man or the
environment.
(B) Detailed directions for use may be omitted from the labe-i^ng
of pesticide products for which sale is limited to physicians,
veterinarians, or druggists, provided that:
U) The label clearly states that the product is for use only
by physicians or veterinarians;
(2) Th" *drin*strator determines that such directions are not
necessary to^prevent unreasonable adverse effects on man or the
environment; and „,*<,*„•„*
(3) The product is also a drug and regulated under the provisions
of the Federal Food, Drug and Cosmetic Act. lahonno.
(C) Detailed directions for use may be omitted from the labeling
of pesticide products which are intended for use only by foraulators
in preparing pesticides for sale to the public, providea that:
(1) There is information readily available to the formulators
or The c^slllon ™xlMtv. methods of use. aoplleable restrictions
or limitations, and effectiveness of the product for
purposes;
215
-------
Appendix IV-1 (continued)
The label clearly states that the product is intended for
use only in manufacturing, formulating, mixing, or repacking for
use as a pesticide and specifies the type(s) of pesticide products
involved;
(3.) The product as finally manufactured, formulated, mixed, or
repackaged is registered; and
(^) The Administrator determines that such directions are not
necessary to prevent unreasonable adverse effects on man or the
environment.
(2) Contents of Directions for Use. The directions for use
shall include the following, under the headings "Directions for
Use" :
(i) The statement of use classification as prescribed in
162.10(J) immediately under the heading "Directions for Use."
(11) Immediately below the statement of use classification,
the statement "It Is a violation of Federal law to use this
product in a manner inconsistent with its labeling."
(ill) The site(s) of application, as for example the crops,
animals, areas, or objects to be treated.
(iv) The target pest(s) associated with each site.
(v) The dosage rate associated with each site and pest.
(vi) The method of application, including instructions for
dilution, If required, and type(s) of application apparatus or
equipment requried.
(vii) The frequency and timing of applications necessary to
obtain effective results without causing unreasonable adverse
effects on the environment.
(vili) Specific limitations on reentry to areas where the
pesticide has been applied, meeting the requirements concerning
reentry provided by MO CFR Part 170.
(ix) Specific directions concerning the storage and disposal
of the pesticide and its container, meeting the requirements of
40 CFR Part 165. These instructions shall be grouped and appear
under the heading "Storage and Disposal." This heading must be
set in type of the same minimum sizes as required for the child
hazard warning (See Table in § l62.10(h)(l)(lv).)
(x) Any limitations or restrictions on use required to prever.-.
unreasonable adverse effects, such as:
(A) Required intervals between application and harvest of f?o~
or feed crops.
(B) Rotational crop restrictions.
(C) Warnings as required against use on certain crops, animals,
objects, or in or adjacent to certain areas.
(D) [Reserved]
(E) For restricted use pesticides, a statement that the
pesticide may be applied under the direct supervision of a
certified applicator who is not physically present at the site of
application but nonetheless available to the person applying the
pesticide, unless the Agency has determined that the pesticide
may only be applied under the direct supervision of a certified
applicator who Is physically present.
216
-------
Appendix IV-1 (continued)
(P) Other pertinent information which the Administrator
determines to be necessary for the protection of man and the
environment .
U) Statement of Use Classification. By October 22, 1976, all
pesticide products must bear on their labels a statement of use
classification as described in paragraphs (J)(l) and (2) of this
section. Any pesticide product for which some uses are classified
for general use and others for restricted use shall be separately
labeled according to the labeling standards set forth in this
subsection, and shall be marketed as separate products with
different registration numbers, one bearing directions only for
general use(s) and the other bearing directions for restricted
use(s) except that, if a product has both restricted use(s) and
general use(s), both of these uses may appear on a product labeled
for restricted use. Such products shall be subject to the
provisions of § 162 . 10( J ) (2) .
(1) General Use Classification. Pesticide products bearing
directions for use(s) classified general shall be labeled with
the exact words "General Classification" immediately below the
heading "Directions for Use." And reference to the general
classification that suggests or implies that the general utility
of the pesticide extends beyond those purposes and uses contained
in the Directions for Use will be considered a false or misleading
statement under the statutory definitions of mlsbranding.
(2) Restricted Use Classification. Pesticide products bearing
direction for use(s) classified restricted shall bear statements
of restricted use classification on the front panel as described
below:
(1) Front panel statement of restricted use classification.
(A) At the top of the front panel of the label, set in type of
the same minimum sizes as required for human hazard signal worde
(see table in § l62.10(h) (1) ( iv) ) , and appearing with sufficient
prominence relative to other text and graphic material on the
front panel to make it unlikely to be overlooked under customary
conditions of purchase and use, the statement "Restricted Use
Pesticide" shall appear.
(B) Directly below this statement on the front panel, a summary
statement of the terms of restriction imposed as a precondition
to registration shall appear. If use is restricted to certified
applicators, the following statement is required: "For retail
sale to and use only by Certified Applicators or persons under
their direct supervision and only for those uses covered by the
Certified Applicator's certification." If, however, other
regulatory restrictions are imposed, the Administrator will define
the appropriate wording for the terms of restriction by regulation,
(k) Advertising. [Reserved]
ri.« FR pP?*53. J-j:1. y 3, 1975; HO PR 32329, Aug. 1, 1Q7?: 40^FR_
36571, Aug. 21, 1975, as amended at 43 PR 5786, Feb. 9, 197bj
217
-------
APPENDIX IV-2
LABFLING REQUIREMENTS OP THE FIFRA, AS AMENDED
ITEM
1
2
3
U
5
6A
6B
7
7A
7B
LABEL ELEMENT
Product name
Company name
and address
Net contents
EPA fteg. No.
EPA Eat. No.
Ingredients
statement
Pounds/gallon
statement
Front panel
precautionary
statements
Keep Out of Reach
of Children
(Child hazard
warning)
Signal word
APPLICABILITY
OP REQUIREMENT
All products
All products
All products
All products
All products
All products
Liquid products
where dosage
given as Ibs.
al/unlt area
All products
All products
All products
PLACEMENT ON LABEL
REQUIRED
Front panel
None
None
None
None
Front panel
Front panel
Front panel
Front panel
Front panel
PREFERRED
Center front
panel
Bottom front
panel or end
of label text
Bottom front
panel or end
of label text
Front panel
Front panel,
Immediately
before or
following
Reg. No.
Immediately
following
product name
Directly below
the main
ingredients
statement
Above signal
word
Immediately
below child
hazard
warning
COMMENTS
If registrant Is not the producer, must
be qualified by "Packed for . . .,"
"Distributed by. . .," etc.
May be in metric units in addition to
U.S. units
Must be in similar type size and run
parallel to other tyj>e.
May appear on the container instead of
the label.
Text must run parallel with other text
on the panel.
All front panel precautionary statements
must be grouped together, preferably
blocked .
Note type size requirements.
Note type size requirements.
218
-------
APPENDIX IV-2 (continued)
ITl'lM
7(1
7H
7R
H
PA
tfB
LABEL ELEMENT
Skull & cross-
boner; and word
POISON (In red)
Statement of
practical
treatment
Referral
statonent
i
i
Side/back panel
precautionary
statements
Hazards to
humans and
dane.-tic
animals
i Environmental
haz?ifds
APPLICABILITY
OP REQUIREMEM1
All products
which are Cat-
egory I based
on oral, der-
mal, or Inhala-
tion toxic ity
All products
in Categories
I, II, and III
All products
where pre-
cautionary
labeling
appears on
other than
front panel.
All products
All products
in Categories
I, II, and III
All products
PLACEMENT
REQUIRED
Front panel
Category I:
Front panel
unless refer-
ral statement
is used.
Others :
Grouped with
side panel
precautionary
statements .
Front panel
None
None
None
ON LABEL
PREFERRED
Both in close
proximity to
r.lgnal word
Front panel
for all.
Top or side
of back panel
preceding
directions
for use
Same as above
.Same as above
COMMENTS
Must be grouped under the headings in
8A, 8B, and 8C; preferably blocked.
Must be preceded by appropriate signal
word.
Environmental hazards include bee
caution where applicable.
219
-------
APPENDIX IV-2 (continued)
ITEM
8C
9A
90
10A
IOC
1PD
LABEL ELEMENT
Physical or
chemical
hazards
Restricted
block
Misuse
statement
Reentry
statement
Storage and
disposal block
Directions
for use
APPLICABILITY
OP REQUIREMENT
All pressurized
products, others
with flash
points under
150°F
All restricted
products
All products
All
cholinesterase
inhibitors
All products
All products
PLACEMENT ON LABEL
REQUIRED
None
Top center
of front
panel
Immediately
following
heading of
directions
for use
In the
directions
for use
In the
directions
for use
None
PREFERRED
Same as above
Preferably
blocked
Immediately
after misuse
statement
Immediately
before
specific
directions
for use or
at the end of
directions
for use
None
COMMENTS
Includes a statement of the terms of
restriction. The words "RESTRICTED USE
PESTICIDE" must be same type size as
signal word.
Must be set apart and clearly distin-
guishable from from other directions
for use.
May be in metric as well as U.S. units
220
-------
Appendix IV-3
Criteria
PHYSICAL-CHEMICAL HAZARDS
Required Label Statement
I. Pressurized Containers
A. Flashpoint at or below
20°P; or if there is a
flashback at any valve
opening.
B. Flashpoint above 20°F
and not over 80°F; or
If the flame extension
is more than 18 inches
long at a distance of
6 inches from the
valve opening.
C. ALL OTHER PRESSURIZED
CONTAINERS
II. Non-Pressurized Containers
A. Flashpoint at or below
20°F.
B. Flashpoint above 20°F
E.-r.:? not ever 80°F.
C. Flashpoint over 80°F
and not over 150°F.
D. Flashpoint above
150°F.
Extremely flammable.
Contents under pressure.
Keep away from fire, sparks,
and heated surfaces. Do not
puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Flammable. Contents under
pressure. Keep away from
heat, sparks, and flame. Do
not puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Contents under pressure.
Do not use or store near
heat or open flame. Do not
puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Extremely flammable. Keep
away from fire, sparks, and
heated surfaces.
Flammable. Keep away from
heat and open flame.
Do not use or store near
heat and open flame.
None required.
22\
-------
Appendix IV-4
STORAGE AND DISPOSAL INSTRUCTIONS FOR PESTICIDES
All products are required to bear specific label instructions
about storage and disposal. Storage and disposal instructions
must be grouped together in the directions for use portion of
the label under the heading STORAGE AND DISPOSAL. Products
intended solely for domestic use need not include the heading
"STORAGE AND DISPOSAL." The STORAGE AND DISPOSAL heading
must appear in the minimum type size listed below:
Size of label
front panel In
square inches
Required type size
for the heading
STORAGE AND DISPOSAL
(all capitals)
10 and under 6 point
Above 10 to 15 8 point
Above 15 to 30 10 point
Over 30. 12 point
Storage and disposal instructions must be set apart and
clearly distinguishable from other directions for use.
Blocking storage and disposal statements with a solid line is
suggested as a means of increasing their prominence.
A. Storage Instructions:
All product labels are required to have appropriate storage
instructions. Specific storage instructions are not prescribed
Each registrant must develop his own storage Instructions,
considering, when applicable, the following factors:
1. Conditions of storage that might alter the composition or
usefulness of the pesticide. Examples could be temperature
extremes, excessive moisture or humidity, heat, sunlight,
friction, or contaminating substances or media.
2. Physical requirements of storage which might adversely
affect the container of the product and its ability to
continue to function properly. Requirements might include
positioning of the container in storage, storage or damage
due to stacking, penetration of moisture, and ability to
withstand shock or friction.
3. Specifications for handling the pesticide container,
including movement of container within the storage area,
proper opening and closing procedures (particularly for
open*"' ror^?? Iners'' . and measures to minimize exposure
while opening or closing container.
222
-------
Appendix IV-4
(continued)
4. Instructions on whatr to do if the container is damaged in
any way, or if the pesticide is leaking or has been
spilled, and precautions to minimize exposure If damage occurs
5. General precautions concerning locked storage, storage in
original container only, and separation of pesticides
during storage to prevent cross-contamination of other
pesticides, fertilizer, food, and feed.
6. General storage instructions for household products should
emphasize storage in original container and placement in
locked storage areas.
B. Pesticide Disposal Instructions:
The label of all products, except those intended solely for
domestic use, must bear explicit instructions about pesticide
disposal. The statements listed below contain the exact wording
that must appear on the label of these products:
1. The labels of all products, except domestic use, must
contain the statement, "Do not contaminate water, food,
or feed by storage or disposal."
2. Except those products intended solely for domestic use,
the labels of all products that contain active ingredients
appearing on the "Acutely Hazardous" Commercial Pesticide
Products List (RCRA "E" List) at the end of this appendix
or are assigned to Toxicity Category I on the basis of
oral or dermal toxicity, skin or eye irritation potential,
or Toxicity Category I or II on the basis of acute inhala-
tion toxicity must bear the following pesticide disposal
statement:
"Pesticide wastes are acutely hazardous. Improper dis-
posal of excess pesticide, spray mixture, or rinsate is
a violation of Federal Law. If these wastes cannot be
disposed of by use according to label instructions,
contact your State Pesticide or Environmental Control
Agency, or the Hazardous Waste representative at the
nearest EPA Regional Office for guidance."
The labels of all products, except those intended for
domestic use, containing active or inert ingredients
that appear on the "Toxic" Commercial Pesticide Products
List (RCRA "F" List) at the end of this appendix or
Drese-^ y meet any of the criteria in Subpart C, 40 CFR
261 for'a hazardous waste must bear the following pesticide
disposal statement:
223
-------
Appendix IV-4
(continued)
"Pesticide wastes are toxic. Improper disposal of excess
pesticide, spray mixture, or rinsate is a violation of
Federal Law. If these wastes cannot be disposed of by
use according to label Instructions, contact your State
Pesticide or Environmental Control Agency, or the Hazardous
Waste representative at the nearest EPA Regional Office
for guidance."
Labels for all other products, except those intended for
domestic use, must bear the following pesticide disposal
statement:
"Wastes resulting from the use of this product may be
disposed of on site or at an approved waste disposal
facility."
3. Products intended for domestic use only must bear the
following disposal statement: "Securely wrap original
container in several layers of newspaper and discard in
trash."
C. Container Disposal Instructions
The label of each product must bear container disposal
instructions appropriate to the type of container.
1. All products intended for domestic use must bear one
of the following container disposal statements:
Container Type Statement
Non-aerosol products
(bottles, cans, Jars)
Non-aerosol products
(bags)
Aerosol products
Do not reuse container (bottle, can, jar ; .
Rinse thoroughly before discarding in trash.
Do not reuse bag . Discard bag in trash .
Replace cap and discard containers in
trash. Do not incinerate or puncture.
224
-------
Appendix IV-4
(continued)
Pesticides that are hazardous wastes under 40 CPR 26l.33(e) and (f)
when discarded.
"Acutely Hazardous" Commercial Pesticides (RCRA "E" List)
Active Ingredients, (no inerts);
Acrolein
Aldicarb
Aldrin
Allyl alcohol
Aluminum phosphide
4-Aminopyridine
Arsenic acid
Arsenic pentoxide
Arsenic trioxide
Calcium cyanide
Carbon disulflde
p-Chloroaniline
Cyanides (soluble cyanide salts, not specified elsewere)
Cyanogen chloride
2-Cyclohexyl-4,6-dinltrophenol
Dieldrin
0,0-Diethyl S-[2-ethylthio)ethyl] phosphorodithioate
(disulfoton, Dl-Syston)
0,0-Diethyl 0-pyrazinyl phosphorothioate (Zinophos)
Dlmethoate
0,0-Dimethyl 0-p-nitrophenyl phosphorothioate (methyl parathion)
4,6-Dinltro-o-cresol and salts
4,6-Dinitro-o-cyclohexylphenol
2,4 Dinitrophenol
Dinoseb
Endosulfan
Endothall
Endrin
Pamphur
Pluoroacetamide
Heptachlor
Hexanethyl tetraphosphate
Hydrocyanic acid
Hydrogen cyanide
Me thorny1
alpha-Naphthylthiourea (ANTU)
Nicotine and salts
Octamethylpyrophosphoramide (OMPA, schradan)
Parathion
225
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Appendix IV-M
(continued)
"Acutely Hazardous" Commercial Pesticides (RCRA "E" List)
Active Ingredients continued:
Phenylmercurlc acetate (PMA)
Phorate
Potassium cyanide
Propargyl alcohol
Sodium azide
Sodium cyanide
Sodium fluoroacetate
Strychnine and salts
0,0,0,0-Tetraethyl dithiopyrophosphate (sulfotepp)
Tetraethyl pyrophosphate
Thallium sulfate
Thiofanox
Toxaphene
Warfarin
Zinc phosphide
226
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Appendix IV-4
(continued)
"Toxic" Commercial Pesticide Products (RGRA "F" List)
Active Ingredients:
Acetone
Acrylonitrile
Amitrole
Benzene
Bis(2-ethylhexyl)pthalate
Cacodylic acid
Carbon tetrachlorlde
Chloral (hydrate)
Chlordane (technical)
Chlorobenzene
A-Chloro-m-cresol
Chloroform
o-Chlorophenol
4-Chloro-o-toluidine hydrochloride
Creosote
Cresylic acid
Cyclohexane
Decaehlorooctahydro-l,3,4-metheno-2H-cyclobuta[c,dJ-pentalen-2-one
(kepone, chlordecone)
1,2-Dibromo-3-chloropropane (DBCP)
Dibutyl phthalate .
S-3,3-(Dichloroallyl diisopropylthiocarbamate (dlallate, Avaaex;
o-Dichlorobenzene
p-Dichlorobenzene e
Dichlorodifluoromethane (Preon 12 ) vor,>,>>
3,5-Dichloro-N-d,l-dimethyl-2-propynyl) benzamlde (pronamide.Kerb)
Dichloro diphenyl dichloroethane (DDD)
Dichloro diphenyl trichloroethane (DDT)
Dichlorethyl ether
2,4-Dichlorophenoxyacetic, esters and salts U,*»-D;
1,2-Dichloropropane
1,3-Dichloropropane (Telone)
Dimethyl phthalate
Ethyl acetate .
Ethyl 4,i»'-dichlorobenzilate (chlorobenzilate;
Ethylene dibromide (EDB)
Ethylene dichloride
Ethylene oxide
Formaldehyde
Furfural
Hexachlorobenzene
Hexachlorocyclopentadlene
Hexachloroethane
Hydrofluoric acid
227
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Appendix IV-4
(continued)
"Toxic" Commercial Pesticide Products (RCRA "F" List)
Active Ingredients:
Isobutyl alcohol
Lead acetate
Lindane
Maleic hydrazlde
Mercury
Methyl alcohol
Methyl bromide
Methyl chloride
2,2'-Methylenebis (3,4,6-trichloropftenol) (hexachlorophene)
Methylene chloride
Methyl ethyl ketone
4-Methyl-2-pentanone (methyl isobutyl ketone)
Naphthalene
Nitrobenzene
p-Nitrophenol
Pentachloroethane
Pentachioronitrobenzene (PCNB)
Pentaclorophenol
Phenol
Phosphorodlthioic acid, 0,0-diethyl, methyl ester
Propylene dichloride
Pyridine
Resorcinol
Safrole
Selenium disulfide
Sllvex
1,2,^,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
2,3,4,6-Tetrachlorophenol
Thiraro
Toluene
1,1,1-Trichloroethane
Trlchloroethylene e
Trichloromonofluoromethane (Freon 11 )
2, *», 5-Trlchlorophenol
2,^,6-Trichlorophenol
2,^,5-Trichloripr.enoxyacetic acid (2,^1,5-T)
Xylene
228
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