r/EPA
United StttM
Environmental Protection
Agency
OHio* of
P««icid«» «nd Toxic
Washington OC 2O460
April 1987
PwticidM
Guidance for the
Reregistration of
Pesticide Products
Containing
Group II Copper Compounds
as the Active Ingredient
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GUIDANCE FOR THE
REREGISTRATION OF PESTICIDE PRODUCTS
CONTAINING
GROUP II COPPER COMPOUNDS
AS THE ACTIVE INGREDIENT
CASE NUMBER 0649
April 1987
ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF PESTICIDE PROGRAMS
WASHINGTON, D.C. 20460
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TABLE OF CONTENTS
I. Introduction 1
II. Chemical(s) Covered by this Standard 4
A. Description of Chemical
B. Use Profile
III. Agency Assessment 9
A. Summary 9
B. Preliminary Risk Assessment .9
C. Other Science Findings 11
D. Tolerance Reassessment 12
E. Summary of Label Changes and Data Gaps 14
IV. Regulatory Position and Rationale 15
A. Regulatory Positions 15
B. Criteria for Registration 19
C. Acceptable Ranges and Limits 19
D. Required Labeling 20
V. Products Subject to this Standard 23
VI. Requirement for Submission of Generic Data 24
A. What are generic data? 24
B. Who must submit generic data? . . . 24
C. What generic data must be submitted? 25
D. How to comply with DCI requirements ..... .25
E. Procedures for requesting change in protocol . .27
F. Procedures for requesting extensions of time . .27
G. Existing stocks provisions upon suspension or
cancellation , .28
VII. Requirement for Submission of Revised Labeling ... .29
VIII. Instructions for Submission 30
A. Manufacturing use products ........... 30
B. End use products 31
C. Intrastate products 31
D. Addresses. 31
Glossary/Acronyms iii
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APPENDICES
I. DATA APPENDICES
Guide to Tables
Table A
II. LABELING APPENDICES
Summary of label requirements and table
40 CFR 162.10 Labeling Requirements
Physical/Chemical Hazards Labeling Statements
Storage Instructions
Pesticide Disposal Instructions
Container Disposal Instructions
III. USE INDEX APPENDIX
IV. BIBLIOGRAPHY APPENDICES
Guide to Bibliography
Bibliography
V. FORMS APPENDICES
EPA Form 8580-1 FIFRA §3(c)(2)(B) Summary Sheet
EPA Form 8580-6 Certification of Attempt to Enter Into an
Agreement with Other Registrants for Development
of Data
EPA Form Formulator's Exemption Statement
EPA Form Certification with Respect to Citation of Data
ii
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GLOSSARY/ACRONYMS
1. The Agency: U.S Environmental Protection Agency/EPA
2. A.I.: Active ingredient
3. DCI: Data Call-in Notice
4. EPs: End-Use pesticide products
5. EUP: Experimental Use Permit
6. FIFRA: Federal Insecticide, Fungicide, Rodenticide Act (As amended)
7. MPs: Manufacturing-Use pesticide products
8. NPDES Permit: National Pollutant Discharge Elimination System
permit
9. OES: Office of Endangered Species, U.S. Dept. of the Interior
10. RAC's: Raw agricultural commodities
11. 40 CFR: Title 40, Code of Federal Regulations
12. Ion: An atom/group of atoms that carries a positive or negative
electrical charge as a result of having gained or lost one
or more electrons.
iii
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I. INTRODUCTION
The Registration Standards Program
EPA has established the Registration Standards program
in order to provide an orderly mechanism by which pesticide
products containing the same active ingredient can be reviewed
and standards set for compliance with FIFRA. The standards
are applicable to reregistration and future applications for
registration of products containing the same active ingredient.
Each registrant of a product containing an active ingredient
subject to this Standard who wishes to continue to sell or
distribute that product must bring his product and labeling
into compliance with FIFRA, as instructed by this Standard.
Pesticides have been grouped into use clusters and will be
reviewed on the basis of a ranking scheme giving higher
priority to (1) pesticides in clusters used on food and feed
crops; and (2) pesticides produced in large volumes.
The Registration Standards program involves a thorough
review of the scientific data base underlying a pesticide's
registration. The purpose of the Agency's review is to
reassess the potential hazards arising from the currently
registered uses of the pesticide; to determine the need for
additional data on health and environmental effects; and to
determine whether the pesticide meets the "no unreasonable
adverse effects" criteria of FIFRA. In its review EPA identifies
1. Studies that are acceptable to support the data
requirements for the currently registered uses of the
pesticide.
2. Additional studies necessary to support continued
registration. The additional studies may not have been
required when the product was initially registered or may be
needed to replace studies that are now considered inadequate.
3. Labeling revisions needed to ensure that the product
is not misbranded and that the labeling is adequate to protect
man and the environment.
The detailed scientific review, which is not contained
in this document, but is available upon request1, focuses on
l-The scientific reviews may be requested from: Information Services
Section (TS-768C), Office of Pesticide Programs, U.S. Environmental
Protection Agency, Room 236, Crystal Mall #2, 1921 Jefferson Davis
Highway, Arlington, Virginia 22202 (telephone (703) 557-4453).
In addition, reviews may be purchased from the National Technical
Information Service, 5285 Port Royal Road, Springfield, Virginia
22161, approximately 90 days after issuance of a Standard.
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the pesticide active ingredient. The scientific review
primarily discusses the Agency's evaluation of and conclusions
from available data in its files pertaining to the pesticide
active ingredient. However, during the review of these data
the Agency is also looking for potential hazards that may be
associated with the end use products that contain the active
ingredient. The Agency will apply the provisions of this
Registration Standard to end use products if necessary to
protect man and the environment.
EPA's reassessment results in the development of a
regulatory position, contained in this Registration Standard,
on the pesticide and each of its registered uses. See
Section IV - Regulatory Position and Rationale. Based on its
regulatory position, the Agency may prescribe a variety of
steps to be taken by registrants to maintain their registrations
in compliance with FIFRA. These steps may include:
1. Submission of data in support of product registration;
2. Modification of product labels;
3. Modifications to the manufacturing process of the
pesticide to reduce the levels of impurities or contaminants;
4. Restriction of the use of the pesticide to certified
applicators or other specially trained individuals;
5. Modification of uses or formulation types; or
6. Specification of packaging limitations.
Failure to comply with these requirements may result in
the issuance of a Notice of Intent to Cancel or a Notice of
Intent to Suspend (in the case of failure to submit data).
In addition, in cases in which hazards to man or the
environment are identified, the Agency may initiate a special
review of the pesticide in accordance with 40 CFR Part 154
to examine in depth the risks and benefits of use of the
pesticide. If the Agency determines that the risks of the
pesticide's use outweigh the benefits of use, the Agency
may propose additional regulatory actions, such as cancellation
of uses of the pesticide which have been determined to cause
unreasonable adverse effects on the environment.
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EPA has authority under the Data Call-in (DCI) provisions
of FIFRA sec. 3(c)(2)(B) to require that registrants submit
data to answer our questions regarding the chemical, toxicological,
and environmental characteristics and fate of a pesticide.
This Registration Standard lists the data EPA believes are
necessary to resolve our concerns about this pesticide. These
data are listed in Table A in Appendix I. Failure to comply
with the DCI requirements enumerated in this Registration Standard
may result in issuance by EPA of a Notice of Intent to Suspend the
affected product registrations.
Registrants are reminded that FIFRA sec. 6(a) (2) requires
them to submit factual information concerning possible unreason-
able adverse effects of a pesticide at any time that they
become aware of such information. You should notify the
Agency of any information, including interim or preliminary
results of studies, if those results suggest possible adverse
effects on man or the environment. This requirement continues
as long as your products are registered by the Agency.
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II. CHEMICALS COVERED BY THIS STANDARD
Description of chemicals
The following compounds are covered by this Registration Standard.
They are designated the Group II copper compounds since a previous
Standard covered copper sulfate compounds.
Table 1. Identifying information for the Group II copper compounds
Compound ~~a
Copper ammonium
carbonate
Copper ammonium
complex
Copper carbonate
Basic copper
(CAC)
(CC)
(CCB)
(BCC)
Empirical
Formula
_.b
c
CuCO3.Cu(OH)
— a
Molecular
Weight
b
__c
2 221.11
— d
CAS Registry
No.
33113-08-5
16828-95-8
12069-69-1
— d
Shaughne^i
No.
022703
022702
022901
008001
Copper carbonate (CCB) CuCOs-Cu (OH) 2
Basic copper (BCC) — d
chloride
Copper chloride (CCD) CuCl2.2H2O
dihydrate
Copper citrate (CCT) CeH4Cu207
Copper hydroxide (CH) Cu(OH)2
Copper nitrate (CN) Cu(NO3)2
Copper oxalate (CO) CuC2O4
Copper oxychloride (COG ) ClCu2H3O3
— e
Copper oxychloride (COGS) — f
sulfate
221.11
— d
170.48
315.18
97.56
187.56
151.56
213.56
C
12069-69-1
— d
10125-13-0
10402-15-0
20427-59-2
3251-23-8
814-91-5
1332-40-7
8012-69-9
022901
008001
023701
044005
023401
076102
023305
023501
023503
aCopper compounds which are registered as pesticides and covered
by this Standard.
Unavailable.
clndefinite.
dCould not be determined from available information. While Quali-
tative Use Assessment (19 November 1985) defines BCC as identical
to COG, desk references indicate the two compounds are distinct,
and give a formula of CuCl2.Cu(OH)2 and a molecular weight of
232.00 for BCC.
eFormula approximate (from desk references only). Exact formula of
registered technical grade product was unavailable.
fcould not be determined from available information. Alternative
formulae found include: (i) [3Cu(OH)2.CuCl2 + 3Cu(OH)2.CuS04]
(from desk references); (ii) [CuSO4.Cu(OH)2] + 8[CuCl2.4Cu(OH)2]
(from MRID 00058009); and (iii) [CuCl2.2CuO.4H2O] +
[CuCl2.3Cu0.3.5H20] + [CuS04.2Cu(OH)2J(29:59.5:11.5;(Agency files).
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Copper ammonium carbonate (CAC) is the common name for a bacterio-
cide and fungicide produced in the U.S. by Mineral Research and
Development Corp. It is also known as Copper-Count-N.
Copper ammonium complex (CC) of indefinite composition is a
fungicide produced in the U.S. by Kocide Chemical Corp. Other
names for this substance include ammoniacal copper complex and
K-Cop.
Copper carbonate (CCB) is the common name of a fungicide produced
in Italy by Caffaro S.p.A., and in the U.S. by Tennessee Chemical
Co., and the Leffingwell Division of Uniroyal Chemical. The
chemical name for CCB is basic cupric carbonate; other names
include copper carbonate hydroxide, cupric subcarbonate, Bremen
blue, Bremen green, malachite, [carbonate (2)-dihydroxy]dicopper,
and Nutra-Spray Basic Copper Carbonate.
The nature of the compound basic copper chloride (BCC) is unclear
from available information. BCC is considered synonymous with
copper oxychloride (see below) by some sources, but is considered
a distinct compound by others (see Table 1). No alternate names
or manufacturer data were available for BCC as of this writing.
Copper chloride dihydrate (CCD) is the common name for a fungicidal
compound for which no manufacturer data or alternate names were
available as of this writing.
Copper citrate (CCT) is the common name of an algicide and bacterio-
cide. The chemical name for CCT is 2-hydroxyl-2,3-propanetri-
carboxylic acid copper salt (1:2). Alternate names are cupric
citrate and Cuprocitrol. As of this writing, no manufacturer
data were available for this material.
Copper hydroxide (CH) is the common name for a fungicide produced
in Italy by Caffaro S.p.A, in France by La Cornuloia S.A., in
Great Britian by McKechnie Chemicals, Ltd., and in the U.S. by
Kocide Chemical Corp., and by Crystal Chemical Inter-America.
The chemical name for CH is cupric hydroxide; other names include
Comae Parasol, Criscobre, Cudrox, Cuidrox, and Kocide.
Copper nitrate (CN) is the common name for a fungicide. The chemi-
cal name for CN is cupric nitrate; alternate names and manufacturer
information were not available as of this writing.
Copper oxalate (CO), chemical name cupric oxalate, is a crow repel-
lent. Another name for CO is Crow-Chex. No manufacturer
information was available as of this writing.
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Copper oxychloride (COG) is the common name for a fungicide manu-
factured in West Germany by BASF AG, in Italy by Caffaro S.p.A.,
in France by Rhone-Poulenc Agrochimie, and in Switzerland by
Sandoz, Ltd. The chemical name for this compound is reported
(Farm Chemicals Handbook, 1986, p. C. 28) to be basic cupric
chloride; however, the empirical formula for COC differs from
that available for BCC (see Table 1). Other names for COC include
atacamite, BASF-Grunkupfer, basic copper chloride (but see above),
Blitox Chempar, Cobox, Colloidox, Coprantol, CopTox, Coxysan,
Cu56, Cuidrox, Cudrox, Cupramar, Cupravit, Cuprocaffaro, Cuprokylt,
Cuprosana, Cuprovinol, Cuprox, Devicopper, Fytolan, Kauritil,
Kilex, Pasta Caffaro, Recop, Rhodiacuivre, Viricuivre, and Vitigran.
Copper oxychloride sulfate (COCS) is the common name for a fungicide
manufactured in the U.S. by C.P. Chemicals, Inc., and by Los Angeles
Chemical Co. Other names for COCS include Copro 53, Capro 57,
CS-56, and Coxysul.
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B. Use Profile
Copper ammonium carbonate (CAC) is a fungicide federally regis-
tered for use on field, bush, vine, and vegetable crops, and
deciduous fruit and nut trees. CAC formulations registered
for use on food/feed crops include 8% and 10% soluble concen-
trates/liquids (SC/Ls) and 8% flowable concentrates (FICs).
These formulations are applied as dormant, delayed dormant,
and/or foliar treatments by aerial or ground equipment.
Copper ammonium complex (CC) is a fungicide federally registered
for use on field, bush, vine, and vegetable crops, deciduous nut
trees, ornamental plants and forest trees, and for treatment of
wood products. CC formulations registered for use on food/feed
crops include 0.8% and 8% soluble concentrate/liquids (SC/Ls).
These formulations are applied as foliar treatment by ground or
aerial equipment.
Copper carbonate (CCB) is a fungicide federally registered for
use on field, bush, vine and vegetable crops, citrus, and
deciduous fruit and nut trees. CCB formulations registered for
use on food/feed products include: 20% and 55% dust (D), used
for seed treatment of sorghum and wheat; a 1.3% impregnated
paper for wrapping pear fruits after harvest; and a 51% wettable
powder (WP) applied to various crops as a dormant, delayed
dormant, soil, and foliar treatment by ground equipment.
Basic copper chloride (BCC) is a fungicide for which no end-use
products have been identified.
Copper chloride dihydrate (CCD) is a fungicide which is not pre-
sently registered for food uses. Use is limited to treatment
of soil for ornamental bulbs and the planting medium for orchids.
It is formulated as a one percent emulsifible or 2.7% liquid
concentrate.
Copper citrate (CCT) is an algicide and antimicrobial compound
for cooling water systems, applied as an 11.24% liquid. There
are no federal product registrations at present. There is an
intrastate registration for use in California.
Copper hydroxide (CH) is a fungicide, herbicide, and marine
antifoulant federally registered for use on field, bush, vine
and vegetable crops, cereal grains, citrus fruits, deciduous
fruit and nut trees, bananas, cocoa, coffee, mangoes, as well
as ornamental plants and forest trees, and boat bottoms and
hulls (as an antifoulant). CH formulations registered for use
on food/feed crops include: D, WP, FIG and ready-to-use (RTU)
liquids. CH formulations are applied to barley, rice and
wheat seed, and as dormant, delayed dormant, and foliar treatments
by ground or aerial equipment (ground only for grapes and
hops). The Agency estimates that CH accounts for approximately
85% of the total Group II copper usage. The antifoulant use
pattern is not being considered under this Standard.
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Copper nitrate (CN) is a fungicide and antimicrobial used only
in aquatic nonfood sites, such as cooling towers, paper mill
systems and heat exchangers, applied as .04% and .6% RTU liquids.
Copper oxalate (CO) is a bird repellent federally registered for
use on corn seed as a 4% dust.
Copper oxychloride (COG) is a fungicide federally registered for
use on field, bush, vine, and vegetable crops, citrus fruits, and
deciduous fruit trees. Additional COC uses include ornamental
plants and greenhouse-grown peppers and tomatoes. COC formu-
lations registered for use on food/feed crops include WPs, and
a FIG. These are applied as delayed dormant, dormant, soil, or
foliar treatments by aerial or ground equipment.
Copper oxychloride sulfate (COGS) is a fungicide federally regis-
tered for use on field, bush, vine and vegetable crops, citrus
fruits, deciduous fruit and nut trees. Other COGS sites include
tobacco, ornamental plants, white oak, and greenhouse-grown
vegetable seedlings. COGS formulations registered for
food/feed crop use include Ds, WPs, and a wettable powder/dust.
These formulations are applied as dormant, delayed dormant,
and foliar treatments by ground or aerial equipment (ground only
for hops and vegetable seedlings in greenhouses and coldframes).
8
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III. AGENCY ASSESSMENT
A. SUMMARY
The Group II copper compounds are used primarily as fungicides
on a wide variety of food crops. However, four of the compounds
are fungicides/algicides with no food uses ( basic copper chloride,
copper chloride dihydrate, copper citrate, and copper nitrate).
Note that the copper ion is the entity responsible for fungicidal/
pesticidal actions in these copper compounds, both for food and
non-food uses. (Copper oxalate is the only exception: it is used
as a bird repellent for seed corn, acting through taste aversion).
Application techniques vary widely from aerial application to
various types of ground applications to impregnated paper which
is wrapped around pears.
The Agency has reviewed all of the data submitted to support the
registration of the Group II copper compounds, as well as open
literature information relevant to these compounds. Based on
the review of these data, the Agency has reached the following
conclusions: 1) The only significant concern for potential risks
posed by uses of Group II copper compounds is for toxicity to
aquatic organisms, which may include endangered species; 2) the
toxicity of copper ion is well understood, and additional data
on chronic health effects is not required; 3) no significant
risks to human health are likely to be posed by any of the
registered uses of Group II pesticide compounds; 4) the existing
exemptions from tolerance requirements for some of the Group II
compounds are appropriate, and exemptions are also appropriate
for the rest of the Group II compounds which have not been
specifically exempted or have been subject to a tolerance re-
quirement in the past.
B. PRELIMINARY RISK ASSESSMENT
1. Ecological Effects
The primary issue associated with the registration of these
chemicals involves their toxicity to aquatic organisms. The
Agency has relevant data on some Group II compounds, and
also considered data on the aquatic toxicity of copper sulfates,
since these data also indicate the aquatic effects of copper ion.
According to the available data, some copper compounds are highly
toxic to some species of fish and aquatic invertebrates. For
example, the lethal concentrations (LCsos) for fish range from 22
parts per billion (ppb) of copper sulfates for (fathead minnow)
to greater than 180 parts per million (ppm) of copper oxychlorides
for (bluegill).
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Chronically, copper compounds are expected to affect some fish
species (brook trout) at levels between 3 and 5 ppb. Acute
toxicity to aquatic invertebrates is also very high with LC5QS
ranging from 6.5 ppb to 200 ppb for (Daphnia ma_gnia). Chronic
effects on aquatic invertebrates are expected at levels ranging
from 6 ppb for (Gamma r_u_s_ p s eu do1i mnaeu s ) to 58 ppb for (mysid
shrimp).
Using theoretical calculations and models, the Agency estimates
that terrestrial applications may result in aquatic concentrations
in excess of aquatic LCsg's and thus produce hazardous conditions
for some aquatic organisms. Additional data are required in order
to determine whether terrestrial applications are likely to raise
aquatic concentrations to hazardous levels. Through this
Registration Standard, the Agency is requiring that registrants
produce information regarding the availability of dissolved
copper ions in aquatic systems. Once this information is avail-
able, the hazards to aquatic organisms can be adequately
evaluated.
2. Endangered^ jSp_ec_iej5_
Copper compounds are not expected to have acute toxic effects on
terrestrial organisms. For example, data on acute toxicity to
avian species shows that copper compounds are practically non-
toxic in the diet (LC5Q >10,000 ppm copper sulfate for mallard
ducks and bobwhite quail), and moderately toxic in a single dose
(LDso 340 to 420 mg/kg copper sulfate for bobwhite quail).
However, there may be some potential for chronic effects on en-
dangered birds, since the use patterns for some of the Group II
copper compounds involve frequent application to certain fruit
and field crops which could result in chronic exposure of avian
species. Thus, avian reproduction studies will be needed to
evaluate the potential for chronic effects. In addition, the
use of these compounds may result in potentially hazardous
exposure to endangered aquatic species. The Agency has developed
labeling precautions for endangered species that will be required
if the U.S. Fish and Wildlife Service (USFWS) concurs. If data
on ecological effects, required by this Standard, indicates
additional hazards to endangered species, the Agency will initiate
consultation with the USFWS on appropriate measures to mitigate
these hazards.
10
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C. OTHER SCIENCE FINDINGS
The role of copper as an essential nutrient for plant and animal
life has been known for decades. Consequently, explanations of
the metabolism and biological role of copper in living organisms
are readily available in the basic literature of biochemistry as
well as plant, animal and human physiology, and specific litera-
ture citations are not given in this Standard for information
derived from such sources. The points summarized under items 1,
2, 3, and 4 below are drawn primarily from open sources including
textbooks on these subjects.
1. Available information, primarily from open literature sources,
indicates that these compounds do not present risks of chronic
or subchronic adverse health effects.
a. The copper ion in the Group II copper compounds is not only
a recognized pesticide, but it is also a trace element
essential for growth and well-being of higher plants and
animals, including man. Copper is ubiquitous in nature,
and occurs in virtually all soils, as well as plant and
animal tissues.
b. Man has a natural, efficient homeostatic mechanism for
regulating the body levels of copper ions over a wide
range of dietary intake. This mechanism integrates the
absorption, retention and excretion of copper to stabilize
the body burden. Only a small percentage of ingested
copper is absorbed, and most of the absorbed copper is
excreted. The adult human body burden of copper is
typically 80 - 150 mg.
c. There is no known evidence of chronic adverse human health
effects from dietary exposure, and none would be expected
except in case of massive intake disrupting the natural
homeostatic mechanism controlling body levels of copper.
Industrial hygiene literature indicates that long term
occupational exposure, such as copper mining, is not
associated with adverse chronic effects.
2. Several natural factors also limit the availabilty of copper
in growing plants, and consequently in raw agricultural
commodities treated with Group II copper compounds.
a. Physio-chemical properties of soils naturally modify copper
ion availability and when soils are adjusted/limed to the
pH required for normal crop production, the effect is to
reduce copper ion availability to the crop.
11
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b. Toxic copper levels in plants induce an imbalance with
iron which causes plant dwarfing, stunted roots and
decreased growth and yields. These effects appear before
significant copper build-up occurs, and consequently
act as a warning which prevents excess application of
copper compounds to food/feed crops.
3. Available data do not indicate that these compounds leach
into ground water supplies.
4. Available data indicate that most Group II compounds fall
into Toxicity Category III for oral and dermal toxicity
(except copper chloride dihydrate which is Category II for
oral toxicity), and Category IV for dermal irritation.
Based on data described in the bibliography, copper carbonate
was found to be a Category III eye irritant; copper oxychloride
sulfate was found to be a Category II eye irritant;and copper
oxychloride and copper hydroxide were found to be Category I
eye irritants. Copper is also considered to be a dermal
sensitizer. Additional data are required to assess the acute
toxicological characteristics of certain of the Group II
copper compounds. Refer to Table A (Appendix I) for a
description of data required.
D. TOLERANCE REASSESSMENT
1. A tolerance of 3 parts per million (ppm) on pears has been
established for residues of combined copper resulting
from post-harvest application of basic copper carbonate
(in impregnated paper wrappers)(40 CFR 180.136). This
is the only tolerance for a Group II copper compound.
0 The current 3 ppm tolerance does not appear to be
necessary in terms of health protection; many untreated
food commodities have higher levels of naturally occurring
copper.
0 The toxicological and physio-chemical factors cited
in Section C above support the view that any residues
likely to result in pears from use of basic copper car-
bonate impregnated paper wrappers would not pose any
significant risks to human health.
0 The Agency will revoke this tolerance and establish
an exemption from tolerance requirements for use of
copper compounds impregnated into wrapping paper for
pears (see Part IV).
12
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2. Several Group II copper compounds are exempt from tolerance
requirements when applied to growing crops in accordance
with good agricultural practices. These are copper
carbonate, copper hydroxide and copper oxychloride (40 CFR
180.1001(b)(1)). Copper carbonate is also exempt from
tolerance requirements for residues in meat, milk, poultry,
eggs, fish, shellfish and irrigated crops resulting from
use as an algicide (40 CFR 180.1021(b)). The Agency
believes these exemptions are appropriate, given the lack
of toxicological concern about low level dietary exposure
to copper. In addition, exemptions are supported by several
factors which limit the likelihood of exposure to excessive
copper residues resulting from application of Group II
copper compounds to growing plants.
0 Copper salts are expected to be washed off plants by
rain and during processing;
0 Water soluble cupric ions are rapidly adsorbed and
immobilized by organic matter in soil;
8 As noted above (C.2), high levels of copper visibly
damage plants before toxicologically significant levels
are reached, and most copper in soils is unavailable
for uptake by growing plants.
3. There are several Group II copper compounds used on
food/feed commodities for which tolerances or exemptions
have not been established. These are copper ammonium
carbonate, copper ammonium complex, copper oxalate,
and copper oxychloride sulfate. The Agency will
revise 40 CFR 180.1001(b)(1) to include these specific
copper compounds along with the other copper compounds
already exempted from tolerance requirements when applied
to growing agricultural crops (see Part IV). Basic copper
chloride, copper chloride dihydrate, copper citrate and
copper nitrate have no food uses, and will not be exempted
as part of this Agency action.
4. There are no Mexican tolerances, Codex Maximum Residue
Levels, or exemptions for copper on food/feed commodities.
Canada has established a tolerance of 50 ppm calculated as
metallic copper to cover residues on all fresh fruits
and vegetables resulting from application of copper
compounds, including copper oxychloride, copper oxy-
chloride sulfate and other copper sulfate compounds.
13
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E- SUMMARY OF LABEL CHANGES AND DATA GAPS
The Agency has determined that label revisions must be made
in the following areas (See Section D, Part IV).
0 Environmental Hazards
0 Protective Clothing
The Agency has identified data necessary to evaluate the
environmental and human risks associated with the use of
Group II copper compounds. These data must be developed in
order to maintain registrations of products or register new
products containing Group II copper compounds. The following
table summarizes the data gaps, including product chemistry
information. Please note that this is only a summary and
details can be obtained by referring to Table A.
Summary ofL Data. Gajps; - Group II Copper Compounds
158.120 Product Chemistry:
61-2 Description of Beginning Materials
and Manufacturing Process
61-3 Discussion of Formation of Impurities
62-1 Preliminary Analysis
62-2 Certification of Limits
62-3 Anal. Method of Enforcement
63-2 Color, Physical State, Odor, Boiling Point,
to Specific Gravity, Solubility, Vapor Pressure
Dissociation Constant, Octanol/water partition coef.,
63-13 pH, and Stability
158.135 Toxicology:
81-1 Acute Oral Toxicity (Rat)
81-2 Acute Dermal Toxicity (Rabbit)
81-4 Eye Irritation Toxicity (Rabbit)
81-5 Dermal Irritation (Rabbit)
158.130 Environmental Fate
163-1 Mobility Studies
164-1,2 Dissipation Studies
158.145 Wildlife and Aquatic Organisms
70-1 Special Testing
71-4 Avian Reproduction Studies
(Copper Hydroxide; Copper Oxychloride Sulfate)
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IV. REGULATORY POSITION AND RATIONALE
A. Regulatory Positions
Based on a review and evaluation of all available data and other
relevant information on the Group II copper compounds, the Agency
has reached the determinations listed below.
1. The Agency has determined that most chronic toxicological
studies normally required to support pesticide registrations
need not be submitted in support of Group II copper compounds.
Rationale: The Agency does not have submitted data on Group II
compounds which meet Agency guidelines for most health
effects testing usually required to support pesticide
registrations. However, the Agency has determined that the
copper ion is the entity responsible for the biological
actions of Group II compounds, and that adequate information
to characterize the toxicity of the copper ion is available
from literature sources. The available information shows
that copper is ubiquitous in nature and is a necessary
nutritional element for both animals and plants. It is one
of 26 elements found essential to life. Copper (ion) is
present in the adult human body at levels of 80-150 mg.
Oral ingestion of excessive amounts of copper (ion) from
pesticidal uses is unlikely; copper compounds are irritating
to the gastric mucosa and emesis usually occurs promptly,
thereby reducing the amounts of copper (ion) available for
absorption into the human body. Moreover, man is protected
from excess copper (ion) in the body by an effective homeostatic
mechanism which integrates absorption, retention and excretion
to stabilize copper (ion) burden in the body. Only a small
percentage of copper (ion) ingested is absorbed, and most of
the absorbed copper is excreted.
In view of the fact that copper (ion) occurs naturally in
most foods, and the metabolism of copper is well understood,
as summarized above, there is no reason to expect that
long term exposure to copper (ion) in the diet is likely
to pose risks of chronic or sub-chronic adverse effects.
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2. The Agency has determined that data must Re submitted to
characterize the acute oral toxicity of copper ammonium
carbonate, copper ammonium complex and copper oxalate.
Data must also be submitted to characterize the acute dermal
toxicity and primary eye and sfcin irritation effects for all
the Group II copper compounds except copper carbonate,
copper hydroxide, copper oxychloride and copper oxychloride
sulfate.
Rationale: The Agency does not have this acute toxicity
data for the Group II compounds cited above. The Group II
copper compounds for which the Agency does have data are only
moderately toxic upon acute oral or dermal exposure (Toxicity
Category III). Copper chloride dihydrate, however, is in
Category II for acute oral toxicity. Ocular exposure to Group
II compounds may cause moderate to severe eye irritation
(Toxicity Category I, II, or III). Data for these types of
acute effects are needed to ensure the proper labeling of the
Group II compounds for which these data are not currently
available.
3. The Agency has determined that certain precautionary statements
for persons handling or applying Group II copper compounds are
required on the labels of manufacturing-use and end-use products
in order to minimize acute toxicity and skin sensitization.
Labels of these products must contain statements that warn
persons applying or handling the Group II copper compounds of
potential effects, give first aid instructions, and require
the use of precautionary measures such as protective clothing
and goggles. The specific language of these statements is
given in Section D of this Part.
Rationale: The Group II copper compounds can pose risks of
acute effects, such as eye irritation. In addition, it is
known that hypersensitivity or sensitization can result from
the copper compounds' contact with the skin.
4. The Agency is not imposing a re-entry interval for workers
after sprays have dried, for any of the Group II copper
compounds.
Rationale: The toxicity of the Group II compounds does not
warrant significant concern about exposure of workers reentering
treated areas after sprays have dried, according to criteria in
40 CFR Part 158.140. Group II copper compounds have not been
determined to be toxic via oral, dermal or inhalation exposure,
and no chronic health concerns have been identified.
16
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5. The Agency will require registrants to submit additional data
needed to assess the effects of Group II copper compounds on
nontarget species, particularly aquatic organisms. These
requirements are specified in Table A of the Data Appendices
of this guidance document.
Rationale: Existing studies on the Group II copper compounds
indicate that they are toxic to certain fish species and
other non-target aquatic organisms (invertebrates). Toxicity
to terrestrial organisms is low; however, the potential for
chronic effects on avian species resulting from certain
use patterns for Group II copper compounds cannot be assessed
without further data.
The limited data currently before the Agency are not adequate
to determine whether these copper compounds, applied at
recommended rates, actually present unreasonable hazards to
fish and other non-target organisms. Thus, the Agency will
require field dissipation studies, and monitoring for residues
in the environment and adverse effects on wildlife to determine
whether the use of specific Group II compounds results in
unreasonable adverse effects.
6. The Agency has determined that additional label precautions
for hazards to fish and other aquatic organisms are required
to prevent unreasonable adverse effects on the environment.
These label requirements are specified in Section D of this
Part.
Rationale: Since the Group II compounds are toxic to aquatic
organisms in laboratory studies, label precautions will
mitigate the potential for adverse effects until a complete
hazard evaluation based on adequate data is available.
7. The Agency has determined that labeling to mitigate potential
hazards to endangered species will not be required through
this Registration Standard.
Rationale: Labeling precautions for endangered species are
being deferred until concurrence is obtained from the U.S.
Fish and Wildlife Service. The Agency will notify registrants
through a Pesticide Registration (PR) Notice, of the final
labeling requirements for endangered species.
17
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8. The Agency will revise 40 CFR 180.1001(b)(1) to add copper
ammonium carbonate, copper ammonium complex, copper oxalate,
and oxychloride sulfate to the list of copper compounds
exempted by that regulation from tolerance requirements when
applied to growing crops.
Rationale: The metabolism of copper in growing plants is
well understood and documented in the available literature.
The use of those Group II compounds not currently exempt
from tolerance requirements would have essentially the same
result in terms of contribution of copper (ion) to growing
crops as the use of the Group II compounds already exempt
under this section (copper carbonate, copper hydroxide and
and copper oxychloride). The Agency believes there is
adequate information to show that there is no toxicological
concern raised by the contribution of copper (ion) to
growing crops likely to result from application of Group II
pesticide compounds, and consequently no tolerances are required
for such uses.
9. The Agency will revoke the existing tolerance of 3 ppm combined
copper on pears resulting from post-harvest use of copper
carbonate (40 CFR 180.136). The Agency will establish an
exemption from tolerance requirements for use of copper
compounds in impregnated wrapper paper for post-harvest
use on pears.
Rationale: Available information on both toxicity and the
potential for dietary exposure to copper ion likely to
result from pesticidal use of copper compounds on food
commodities indicate that there is no need for the current
tolerance in terms of health protection. No toxicologically
significant exposure is likely to result from paper wrappers
impregnated with any Group II copper compound; consequently
this use should be exempt from tolerance requirements.
10. While the data gaps are being filled, currently registered MPs
and EPs containing Group II copper compounds may be sold,
distributed, formulated and used in the United States, subject
to the terms and conditions specified in this Standard.
Registrants must provide and agree to develop additional
data, as specified in the Data Appendices of this guidance
document, in order to maintain existing registrations.
Rationale: Under FIFRA, the Agency does not normally cancel
or withhold registration simply because data are missing
or inadequate (see FIFRA sec. 3(c)(2)(B) and 3(c)(7)).
Issuance of this Standard provides a mechanism for identifying
data needs. These data will be evaluated, after which the
Agency will determine if additional regulatory changes are
necessary.
18
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B. Criteria for Registration
To be covered under this Standard, manufacturing-use products must
contain a Group II copper compound (copper ammonium carbonate,
copper ammonium complex, copper carbonate, basic copper chloride,
copper chloride dihydrate, copper citrate, copper hydroxide,
copper nitrate, copper oxalate, copper oxychloride, or copper oxy-
chloride sulfate) as the sole active ingredient, bear required
labeling, and conform to the product composition, acute toxicity
limits, and use pattern requirements listed in Section C below.
C. Acceptable Ranges and Limits
1. Product Compos^iliion Standard
To be covered under this Standard, manufacturing-use products (MPs)
must contain Group II copper compounds as the sole active in-
gredient. Each MP formulation proposed for registration must
be fully described with an appropriate certification of limits,
stating maximum and minimum amounts of the active ingredient
which may be present in products.
2. Acute Toxicity Limits
The Agency will consider registration of technical grade and MP
products containing the Group II copper compounds, provided that
the product labeling bears appropriate precautionary statements for
the acute toxicity category in which each product is placed.
3. Use Patterns
To be registered under this Standard, manufacturing use products con-
taining the Group II copper compounds may be labeled for formulation
into end-use products only for the commodities listed below. The
attached index entry lists all registered uses, as well as approved
maximum application rates and frequencies.
- Terrestrial food uses on fruit, grain, nut and vegetable crops, and
for grain seed treatment (including crow repellent treatment);
- Terrestrial, nonfood uses on forest trees, ornamentals, and
tobacco;
- Greenhouse food use on vegetable seedlings;
- Aquatic impact food uses on rice and cranberries;
- Aquatic, nonfood uses on water systems (pulp and paper mill
systems, cooling towers, spray ponds, and pole soaking treatments);
- Indoor use on wood products
19
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D. Required Labeling
All manufacturing-use and end-use Group II copper compound
products must bear appropriate labeling as specified in 40 CFR
162.10, PR Notice 83-3, and below. Appendix II contains
information on label requirements.
No pesticide product containing Group II copper compounds
may be released for shipment by a registrant or producer of
that product after April 30, 1988, unless the product bears
an Agency approved amended label which complies with the require-
ments of this Standard.
No pesticide product containing Group II copper compounds
may be distributed, sold, offered for sale, held for sale, shipped,
delivered for shipment, or received and (having been so received)
delivered or offered to be delivered by any person after
April 30, 1989, unless the product bears an Agency approved
amended label which complies with the requirements of this Standard.
The following information must appear on the labeling
within the time limits specified above:
1. Ing re d i e n t S taterne nt
The ingredient statement for all manufacturing-use products con-
taining Group II copper compounds must list the active ingredient
in the following manner (examples):
"Copper oxychloride XX%" ;
"Copper chloride dihydrate XX%" ;
"Copper hydroxide XX%" ;
The ingredient statement must have a footnote reading;
"Metallic copper equivalent XX%"
2. Use Pattern Statements^
All manufacturing-use products containing Group II copper com-
pounds must state that they are intended for formulation into
end-use products for the aforementioned use patterns. Labeling
must specify sites which are listed in Section C.3. above under
Use Patterns. However, no use may be included on the label if
the registrant fails to comply with the data requirements for
that use pattern, as listed in Table A of the Data Appendices of
this document.
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3. Precauti on a r y S t a t erne n t s
a. Hazards to Humans and Domestic Animals (Manufacturing-Use)
Labels for manufacturing-use products (MPs) containing
Group II copper compounds must bear statements reflecting
the compound's acute human toxicity. These compounds are
in Toxicity Category III for oral and dermal toxicity
(except copper chloride dihydrate which is Toxicity Category
II for oral effects)*; Category IV for dermal irritation; and
Category I, II, or III for eye irritation.
The following human hazard statements must appear on all
MP labels:
- Copper hydroxide and copper oxychloride -
"DANGER. Corrosive. Causes irreversible eye damage."
(and text below)
- Copper oxychloride sulfate -
"WARNING. Causes substantial but temporary eye injury."
(and text below)
- Copper carbonate -
"CAUTION. Causes eye irritation." (and text below)
- Other Group II compounds -
(Use existing signal word and eye precautions until test
results are available [see Table Af footnotes J./&2/] ,
and text below)
- All MPs -
"Harmful if swallowed, absorbed through the skin or
inhaled. May cause skin sensitization reactions in
certain individuals. Avoid contact with skin, eyes,
or clothing. Avoid breathing dust. Protective
clothing, including goggles, should be worn. Wash
thoroughly with soap and water after handling.
Remove contaminated clothing and wash before reuse."
b. Hazards to Humans and Domestic Animals (End-Use)
- All EPs -
"May cause skin sensitization reactions in certain
individuals."
*There are no single-active manufacturing- or end-use products
registered for pesticidal use as of March 1987.
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- All EPs - (Cont.)
NOTE: The remainder of text from 40 CFR Section 162.10
should reflect toxicity characteristics of the particular
Group II copper end-use formulation. Acute toxicity
information on end-use formulations was not assessed in
developing this Standard unless the end-use product was
substantially similar to a manufacturing-use formulation.
c. Environmental Hazards (Manufacturing-Use)
"This pesticide is toxic to fish and aquatic organisms. Do
not discharge effluent containing this product into lakes,
streams, ponds, estuaries, oceans, or public water unless
this product is specifically identified and addressed in an
NPDES permit. Do not discharge effluent containing this
product into sewer systems without previously notifying the
sewage treatment plant authority. For guidance contact
your State Water Board or Regional Office of the EPA."
d. Environmental Hazards (End-Use)
The following statements may be combined as appropriate
where more than one site category applies:
- Aquatic non-crop uses -(pulp/paper mill systems, cooling
towers, spray ponds, pole soaking)
"This pesticide is toxic to fish and aquatic organisms. Do
not discharge effluent containing this product into lakes,
streams, ponds, estuaries, oceans, or public waters unless
this product is specifically identified and addressed in an
NPDES permit. Do not discharge effluent containing this
product to sewer systems without previously notifying the
sewage treatment plant authority. For guidance contact
your State Water Board or Regional Office of the EPA."
- Terrestrial uses -
"This pesticide is toxic to fish and aquatic organisms. Do
not apply directly to water. Drift and runoff from treated
areas may be hazardous to fish and aquatic organisms in
adjacent aquatic sites. Do not allow rinsate from cleaning
of equipment or disposed material to enter surface or ground
water." (NOTE: Drift and runoff statement may be deleted
where it does not apply, e.g. grain seed treatment)
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V. PRODUCTS SUBJECT TO THIS STANDARD
All products containing the pesticide identified in
Section II.A. are subject to certain requirements for data
submission or changes in composition, labeling or packaging
of the product. The applicable requirements depend on whether
the product is a manufacturing or end-use product.
Products are subject to this Registration Standard as
follows:
A. Manufacturing-use products containing this pesticide are
subject to:T5The restrictions upon use, composition, or
packaging listed in Section IV; 2) The data requirements
listed in Table A; 3) The labeling requirements specified
for manufacturing-use products in Section IV; 4) Administrative
requirements (application forms, Confidential Statement of
Formula, data compensation provisions) associated with
reregistration.*
B. End-use products containing this pesticide are subject to:
1) The labeling requirements specified for end-use products
in Section IV; 2) If not eligible for the formulator's
exemption, the data requirements listed in Table A.
1 Data requirements are listed in the Tables in Appendix I
of this Registration Standard. The Guide to Tables in that
Appendix explains how to read the Tables. Table A lists
generic data requirements applicable to all products containing
the pesticide subject to this Registration Standard. The
data in Table A need not be submitted by a producer who is
eligible for the formulator's exemption.
2 If you purchase from another producer and use as the source
of your active ingredient, only EPA-registered products, you
are eligible for the formulator's exemption for generic data
concerning that active ingredient (Table A). Two circumstances
nullify this exemption: 1) If you change sources of active
ingredient to an unregistered product, formulate your own
active ingredient, or acquire your active ingredient from a
firm with ownership in common with yours, you individually
lose the exemption and become subject to the data requirements
in Table A; 2) If no producer subject to the generic data
requirements in Table A agrees to submit the required data,
all end-use producers lose the exemption, and become subject
to those data requirements.
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VI. REQUIREMENT FOR SUBMISSION OF GENERIC DATA
This portion of the Registration Standard is a notice
issued under the authority of FIFRA sec. 3(c)(2)(B). It
refers to the data listed in Table A, which are required to
be submitted by registrants to maintain in effect the regis-
tration of products containing this active ingredient.3
A. What are generic data?
Generic data pertain to the properties or effects of a
particular active ingredient. Such data are relevant to an
evaluation of all products containing that active ingredient
regardless of whether the product contains other ingredients.
(unless the product bears labeling that would make the data
requirement inapplicable).
Generic data may also be data on a "typical formulation"
of a product. "Typical formulation" testing is often required
for ecological effects studies and applies to all products
having that formulation type. These are classed as generic
data, and are contained in Table A.
B. Who must submit generic data?
All current registrants are responsible for submitting
generic data in response to a data request under FIFRA sec.
3(c)(2)(B) (DCI Notice). EPA has decided, however, not to
require a registrant who qualifies for the formulator's
exemption (FIFRA sec. 3(c)(2)(D) and § 152.85) to submit
generic data in response to a DCI notice if the registrant
who supplies the active ingredient in his product is complying
with the data request.
If you are not now eligible for a formulator's exemption,
you may qualify for one if you change your source of supply
to a registered source that does not share ownership in
common with your firm. If you choose to change sources of
supply, the Confidential Statement of Formula must identify
the new source(s) and you must submit a Formulator's Exemption
Statement form.
If you apply for a new registration for products containing
this active ingredient after the issuance of this Registration
Standard, you will be required to submit or cite generic
data relevant to the uses of your product if, at the time
3 Registrations granted after issuance of this Standard
will be conditioned upon submission or citation of the data
listed in this Registration Standard.
24
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the application is submitted, the data have been submitted
to the Agency by current registrants. If the required data
have not yet been submitted, any new registration will be
conditioned upon the new registrant's submission or citation
of the required data not later than the date upon which
current registrants of similar products are required to provide
such data. See FIFRA sec. 3(c)(7)(A). If you thereafter fail
to comply with the condition of that registration to provide
data, the registration may be cancelled (FIFRA sec. 6(e)).
C. What generic data must be submitted?
You may determine which generic data you must submit by
consulting Table A. That table lists the generic data needed
to evaluate current uses of all products containing this
active ingredient, the uses for which such data are required,
and the dates by which the data must be submitted to the
Agency.
D. How to comply with PCI requirements.
Within 90 days of your receipt of this Registration
Standard, you must submit to EPA a completed copy of the form
entitled "FIFRA Section 3(c)(2)(B) Summary Sheet" (EPA Form
8580-1, enclosed) for each of your products. On that form
you must state which of the following six methods you will
use to comply with the DCI requirements:
1. You will submit the data, and either—
(a) Submit the existing data that you believe will
satisfy the data requirements, or
(b) State that you will secure the data or have made
a contract to have any necessary studies completed
within the applicable time period.
2. You have entered into an agreement with one or more
registrants to jointly develop (or share in the cost of
developing) the data, but will not be submitting the data
yourself. If you use this method, you must state who will
submit the data on which you will rely. You must also provide
EPA with documentary evidence that an agreement has been
formed which allows you to rely upon the data to be submitted.
Such evidence may be: (1) your letter offering to join in
an agreement and the other registrant's acceptance of your
offer, (2) a written statement by the parties that an agreement
exists, or (3) a written statement by the person who will be
submitting the data that you may rely upon its submission.
The Agency will also require adequate assurance that the
person whom you state will provide the data is taking appropriate
steps to secure it. The agreement to produce the data need
not specify all of the terms of the final arrangement between
the parties or a mechanism to resolve the terms.
25
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3. You have attempted to enter into an agreement to
jointly develop data, but no other registrant has accepted
your offer. You request that EPA not suspend your registration
for non-compliance with the PCI. EPA has determined that,
as a general policy, it will not suspend the registration of
a product when the registrant has in good faith sought and
continues to seek to enter into a data development/cost
sharing program, but the other registrants developing the
data have refused to accept its offer. [If your offer is
accepted, you may qualify for Option 2 above by entering
into an agreement to supply the data.3
In order to qualify for this method, you must:
1. File with EPA a completed "Certification of Attempt
to Enter into an Agreement with other Registrants for Develop-
ment of Data" (EPA Form 8580-6, enclosed).
2. Provide us with a copy of your offer to the other
registrant and proof of the other registrant's receipt of your
offer (such as a certified mail receipt). Your offer must,
at a minimum, contain the following language or its equivalent:
[Your company name] offers to share in the burden of
producing the data required pursuant to FIFRA sec.
3(c)(2)(B) in the [name of active ingredient] Registration
Standard upon terms to be agreed or failing agreement
to be Ixsund by binding arbitration as provided by FIFRA
section 3(c) (2) (B)(iii).
The remainder of your offer may not in any way attempt to
limit this commitment. If the other registrant to whom your
offer is made does not accept your offer, and if the other
registrant informs us on a DCI Summary Sheet that he will
develop and submit the data required under the DCI, then you
may qualify for this option. In order for you to avoid
suspension under this method, you may not later withdraw or
limit your offer to share in the burden of developing the
data. In addition, the other registrant must fulfill its
commitment to develop and submit the data.
4. You request a waiver of the data requirement. If
you believe that a data requirement does not (or should not)
apply to your product or its uses, you must provide EPA with
a statement of the reasons why you believe this is so. Your
statement must address the specific composition or use factors
that lead you to believe that a requirement does not apply.
Since the Agency has carefully considered the composition and
uses of pesticide products in determining that a data require-
ment applies, EPA does not anticipate that many waivers will
be granted. A request for waiver does not automatically
extend the timeframes for developing required data, and if
your waiver request is denied, your registration may be
suspended if you fail to submit the data.
26
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5. You request that EPA amend your registration by deleting
the uses for which the data are needed. You are not required
to submit data for uses which are no longer on your label.
6. You request voluntary cancellation of the registration
of your product(s) for which the data are needed.
E. Procedures for requesting a change in testing protocol.
If you will generate the required data and plan to use
test procedures which deviate from (or are not specified in)
either EPA's Pesticide Assessment Guidelines or the Reports
of Expert Groups to the Chemicals Group, Organization for
Economic Cooperation and Development (OECD) Chemicals Testing
Programme, you must submit for EPA approval the protocols
you propose to use.
You should submit your protocols before beginning testing
and await EPA approval, because the Agency will not ordinarily
accept as sufficient studies using unapproved protocols.
A request for protocol approval will not automatically extend
the timeframe for submission of the data, nor will extensions
generally be given to conduct studies due to submittal of
inappropriate protocols.
F. Procedures for requesting extensions of time.
If you think that you will need more time to generate
the data than is allowed by EPA's schedule, you may submit a
request for an extension of time. Any request for a time
extension which is made as an initial response to a section
3(c)(2)(B) request notice must be submitted in writing to
the Product Manager listed at the end of this section and
must be made before the deadline for response. Once dates
have been committed to and EPA has accepted these commitments,
any subsequent requests for a time extension must be submitted
in writing to the Office of Compliance Monitoring.
EPA will view failure to request an extension before
the response deadline as a waiver of any future claim that
there was insufficient time to submit the data. While EPA
considers your request, you must strive to meet the deadline
for submitting the data.
The extension request should state the reasons why you
believe that an extension is necessary and the steps you
have taken to meet the testing deadline. Time extensions
normally will not be granted due to problems with laboratory
capacity or adequacy of funding, since the Agency believes
that with proper planning these can be overcome. Time extensions
may be considered when joint data development is planned,
27
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or when the Agency must approve a new or modified protocol
before the study can be begun.
A request for an extension does not automatically extend
the timeframe for submission of the data. If EPA denies your
request for a time extension and you do not submit the data
as requested, EPA may begin proceedings to suspend the regis-
trations of your products.
G. Existing stocks provision upon suspension or cancellation.
the Agency has determined that if a registration is
suspended for failure to respond to a DCI request under
FIFRA sec. 3(c)(2)(B), an existing stocks provision is not
consistent with the Act. Accordingly, the Agency does not
anticipate granting permission to sell or distribute existing
stocks of suspended product except in rare circumstances.
If you believe that your product will be suspended or cancelled
and that an existing stocks provision should be granted, you
have the burden of clearly demonstrating to EPA that granting
such permission would be consistent with the Act. The following
information must be included in any request for an existing
stocks provision:
1. Explanation of why an existing stocks provision is
necessary, including a statement of the quantity of
existing stocks and your estimate of the time required
for their sale or distribution; and
2. Demonstration that such a provision would be consis-
tent with the provisions of FIFRA.
28
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VII. REQUIREMENT FOR SUBMISSION OF REVISED LABELING
FIFRA requires each product to be labeled with accurate,
complete and sufficient instructions and precautions, reflecting
the Agency's assessment of the data supporting the product
and its uses. General labeling requirements are set out in
40 CFR 162.10 (see Appendix II - LABELING and SUMMARY). In
addition, labeling requirements specific to products containing
this pesticide are specified in Section IV.D of this Registra-
tion Standard. Applications submitted in response to this
notice must include draft labeling for Agency review.
If you fail to submit revised labeling as required,
which complies with 40 CFR 162.10 and the specific instructions
in Section IV.D., EPA may issue a Notice of Intent to Cancel
the registration of your product under FIFRA sec. 6(b)(l).
29
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VIII. INSTRUCTIONS FOR SUBMISSION
A. Manufacturing Products (MUPs) containing Copper Compounds
as the sole active ingredient.
1. Within 90 days from receipt of this document, you
must submit to the Product Manager in the Registration Division
for each product subject to this Registration Standard:
a. The "FIFRA Section 3(c)(2)(B) Summary Sheet" (EPA
Form 8580-1), with appropriate attachments, or Formulator's
Exemption Statement. *
b. Confidential Statement of Formula (EPA Form 8570-4).
c. Evidence of compliance with data compensation
requirements of FIFRA sec. 3(c)(l)(D). Refer to 40 CFR
152.80-152.99.
d. Protocol for residue/incidence monitoring program.
2. Within 9 months from receipt of this document you
must submit to the Product Manager:
Five copies of draft labeling. Labeling should be
either typewritten text on 8-1/2 x 11 inch paper or a
mockup of the labeling suitable for storage in 8-1/2 x
11 files. The draft label must indicate the intended
colors of the final label, clear indication of the front
panel of the label, and the intended type sizes of the
text.
3. Within the times set forth in Table A, you must
submit to the Registration Division all generic data, unless
you are eligible for the formulator's exemption. If for any
reason any test is delayed or aborted so that the agreed
schedule cannot be met, immediately notify the Product Manager
and the Office of Compliance Monitoring of the problem, the
reasons for the problem, and your proposed course of action.
4 if on the Summary Sheet, you commit to develop the data,
present arguments that a data requirement is not applicable
or should be waived, or submit protocols or modified protocols
for Agency review, you must submit a copy of the Summary
Sheet (and any supporting information) to the Office of
Compliance Monitoring, which will be monitoring the data
generated in response to this notice. This submission is in
addition to responding to the Product Manager, and should be
submitted to the Office of Compliance Monitoring at the
address given at the end of this section. (Actual studies
are not to be submitted to the Office of Compliance Monitoring,
30
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B. End Use Products containing Copper Compounds alone or in
combination with other active ingredients
1. Within 90 days from receipt of this document, you
must submit to the Product Manager in the Registration Division:
a. FIFRA Section 3(c)(2)(B) Summary Sheet/ with
appropriate attachments4 (EPA Form 8580-1),or Formulators
Exemption Statement (EPA Form ).
b. Confidential Statement of Formula (EPA Form 8570-4)
2.
must
*-» » WWiAJ.-l.V^id&l.-fc.C.&J- WUUW CUIC 11U Wi. J. \^rj. 11IU -L« \ .LJ E n, .L W^ 1U \S *
2. Within 9 months from receipt of this document you
: submit to the Product Manager:
a. Five copies of draft labeling, including the
container label and any associated supplemental labeling.
Labeling should be either typewritten text on 8-1/2 x 11
inch paper or a mockup of the labeling suitable for
storage in 8-1/2 x 11 files. The draft labeling must
indicate the intended colors of the final label, clear
indication of the front panel of the label, and the
intended type sizes of the text. End-use product labeling
must comply specifically with the instructions in Section
IV (Regulatory Position and Rationale).
C. Intrastate Products containing Copper Compounds as
sole active ingredient or in combination with other
active ingredients.
These products are being called in for full Federal regis-
tration. Producers of these products are being sent a letter
instructing them how to submit an application for registration.
D. Addresses
The required information must be submitted to the following
address:
Richard F. Mountfort, PM-23
Registration Division (TS-767C)
Office of Pesticide Programs
Environmental Protection Agency
401 M St., SW
Washington, D.C. 20460
The address for submissions to the Office of Compliance
Monitoring is:
Laboratory Data Integrity Program
Office of Compliance Monitoring (EN-342)
Environmental Protection Agency
401 M St., SW
Washington, DC 20460
31
-------
APPENDIX I
DATA APPENDICES
32
-------
TGUIDE-1
GUIDE TO TABLES
Tables A, B, and C contain listings of data requirements
for the pesticides covered by this Registration Standard.
Table A contains generic data requirements that apply to
the pesticide in all products, including data requirements
for which a "typical formulation" is the test substance.
Table B contains product-specific data requirements that
apply only to a manufacturing use product.
Table C contains product-specific data requirements that
apply only to an end use product.
The data tables are generally organized according to the
following format:
1. Data Requirement (Column 1). The data requirements are
listed ih the order in which they appear in 40 CPR Part 158.
The reference numbers accompanying each test refer to the
test protocols set out in the Pesticide Assessment Guidelines,
which are available from the National Technical Information
Service, 5285 Port Royal Road, Springfield, VA 22161.
2. Test Substance (Column 2). This column lists the composition
of the test substance required to be used for the test, as
follows:
TGAI = Technical grade of the active ingredient
PAI = Pure active ingredient
PAIRA = Pure active ingredient, radio labeled
TEP = Typical end use formulation
MP = Manufacturing use product
EP = End use product
Any other test substances, such as metabolites, will be
specifically named in Column 2 or in footnotes to the table.
3. Use pattern (Column 3). This column indicates the use
patterns to which the data requirement applies. Use patterns
are the same as those given in 40 CPR Part 158. The following
letter designations are used for the given use patterns:
A » Terrestrial, food
B - Terrestrial, non-food
C = Aquatic, food
D = Aquatic, non-food
E = Greenhouse, food
P = Greenhouse, non-food
G = Forestry
H = Domestic outdoor
I = Indoor
Any other designations will be defined in a footnote to the table,
33
-------
TGUIDE-2
4. Does EPA have data? (Column 4). This column indicates one
of three answers:
YES - EPA has data in its files that completely satisfy
this data requirement. These data may he cited by
other registrants in accordance with data compensation
requirements of Part 152, Subpart E.
PARTIALLY - EPA has some data in its files, but such data
do not fully satisfy the data requirement. In some oases,
the Agency may possess data on one of two required species,
or ;nay port .-jess data on one test substance but not all.
The term may also indicate that the data available to
EPA are incomplete. In this case, when the data are
clarified, or additional details of the testing submitted
by the original data submitter, the data may be determined
to be acceptable. If this is the case, a footnote to
the table will usually say so.
NO - EPA either possesses no data which are sufficient
to fulfill the data requirement, or the data which EPA
does possess are flawed scientifically in a manner that
cannot be remedied by clarification or additional infor-
mation.
5. Bibliographic citation (Column 5). If the Agency has
acceptable data in its files, this column lists the identifying
number of each study. This normally is the Master Record
Identification (MRID) number, but may be a GS number if no
MRID number has been assigned. Refer to the Bibliography
Appendices for a complete c 1. batlon of the study.
6. Must additional data be submitted? (Column 6). This
column indicates whether the data .'mat be submitted to the
Aii^ncy. If column 3 Indicates that the Agency already has
data, this column will usually indicate NO. If column 3
indicates that the Agency has only partial data or no data,
this column will usually indicate YTD". In some cases, even
though the Agency does not have the data, EPA will not require
its submission because of the unique characteristics of the
chemical; because data on another chemical can be used to
fulfill the data requirement; or because the data requirement
has been waived or reserved. Any such unusual situations
will be explained in a footnote to the table.
7. Timeframe for submission (Column 7). If column 5 requires
that data be submitted, this column indicates when the data
are to be submitted, based on the issuance date of the Regis-
tration Standard. The timeframes are those established either
as a result of a previous Data Call-in letter, or standardized
time framea established by PR Notice 85-5 (August 22, 1985).
8. Footnotes (at the end of each table). Self-explanatory.
34
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER AMMONIUM CARBONATE 8% FORMULATION INTERMEDIATE3 (EPA REG. NO. 10143-2)
CJJ
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Conposition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Marufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
Certified Limits
Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63-4 - Odor
63-5 - Melting Point
63-6 - Boiling Point
63-7 - Density, Bulk Density, or
Specific Gravity
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
Use Does EPA Bibliographic Must Addtl Time Frame
Patterns Have Data? Citation1 Data be for
Submitted? Submission
All
All
All
All
All
All
All
All
All
All
All
All
No
No
No
No
No
No
No
No
No
No
No
No
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER AMMONIUM CARBONATE 8% FORMULATION INTERMEDIATE3 (EPA REG. NO. 10143-2)
Data Requirement
Test Use Does EPA Bibliographic
Substance Patterns Have Data? Citation-'-
Must Addtl Tine Frame
Data be for
Submitted? Submission
§158.120 Product Chemistry (Continued)
63-8
63-9
63-10
63-11
63-12
63-13
Other
64-1
- Solubility
- Vapor Pressure
- Dissociation Constant
- Octanol/Water Partition
Coefficient
-pH
- Stability
Requirement:
- Sutmittal of samples
TGAI or PAI
PAI
PAI
PAI
TGAI
TGAI
N/A
No
No
No
No
No
No
No
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Wo 2/
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
a The 8% formulation intermediate serves as a manufacturing-use product.
I/ Not applicable. Although product chemistry data may been submitted in the past, the Agency has determined that
~~ these data nust be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The corpound does not require samples at this time.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER HYDROXIDE 90% TECHNICAL3 (EPA REG. NOS. 1812-297, 48957-16, and 45002-2)
GENERIC DATA REQUIREMENTS FOR COPPER HYDROXIDE 88% FORMULATION INTERMEDIATE1* (EPA REG. NO. 1812-292)
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Composition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Manufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
Certified Limits
Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63^1 - Odor
63-5 - Melting Point
63-6 - Boiling Point
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
Use Does EPA
Patterns Have Data?
All
All
All
All
All
All
All
All
All
All
All
Partially
No
No
No
No
No
No
No
No
No
No
Bibliographic Must Addtl Time Franre
Citation1 Data be for
Submitted? Submission
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
6 Months
6 Months
6 Months
6 Months
6 Months
63-7 - Density, Bulk Density, or
Specific Gravity
TGAI
All
No
N/A
Yes
6 Months
-------
TABLŁ A
00
GENERIC DATA REQUIREMENTS FOR COPPER HmiOXIDE 90% TECHNICAL/1 (EPA REG. NOS. 1812-297, 48957-16, and 45002-2)
GENERIC DATA REQUIREMENTS FOR COPPER HYDROXIDE 88% FORMULATION IOTERT4EDIATEb (EPA REG. NO. 1812-292)
Data Requirement
Test Use Does EPA Bibliographic
Substance Patterns Have Data? Citation1
§158.120 Product Chemistry (Continued)
63-8 - Solubility
63-9 - Vapor Pressure
63-10 - Dissociation Constant
63-11 - Octanol/Water Partition
Coefficient
63-12 - pH
63-13 - Stability
Other Requirement:
64-1 - Submittal of samples
T3AI or PAI
PAI
PAI
PAI
TGAI
TGAI
N/A
No
No
No
No
No
No
N/A
N/A
N/A
N/A
N/A
N/A
No
Must Addtl Time Frame
Data be for
Submitted? Submission
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
No 2/
a The 90% Technical serves as a manufacturing-use product.
b The 88% Formulation Intermediate serves as a manufacturing product.
I/ Not applicable. Although product chemistry data may have been submitted in the past, the Agency has determined that
~~ these data must be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The compound does not require submittal of samples at this time.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER OXYCHLORIDE 98.75% TECHNICAL3 (EPA REG. NO. 279-2811)
GENERIC DATA REQUIREMENTS FOR BASIC COPPER CHLORIDE 99.76% TECHNICAL13 (EPA REG. NO. 8732-2)
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Conposition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Manufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
Certified Limits
Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63-4 - Odor
63-5 - Melting Point
63-6 - Boiling Point
63-7 - Density, Bulk Density, or
Specific Gravity
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
Use
Patterns
All
All
All
All
All
All
All
All
All
All
All
All
Does EPA
Have Data?
Partially
No
No
No
No
No
No
No
No
No
No
No
Bibliographic Must Addtl Time Frame
Citation1 Data be for
Submitted? Submission
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
-------
TABLJ3 A
GENERIC DATA REQUIREMENTS FOR COPPER OKfCHLORIDE 98.75% TECHNICALA (EPA REG. NO. 279-2811)
GENERIC DATA REQUIREMENTS FOR BASIC COPPER CHLORIDE 99.76% TECHNICAL13 (EPA REG. NO. 8732-2)
Data Requirement
Test Use Does EPA Bibliographic Must Addtl Tine Frame
Substance Patterns Have Data? Citation1 Data be for
Submitted? Submission
§158. 120 Product Chemistry (Continued)
63-8
63-9
63-10
63-11
63-12
63-13
Other
64-1
- Solubility
- Vapor Pressure
- Dissociation Constant
- Octanol/Water Partition
Coefficient
- pH
- Stability
Requirement:
- Submittal of samples
TGAI or PAI
PAI
PAI
PAI
TGAI
TGAI
N/A
No N/A
No N/A
No N/A
No N/A
No N/A
No N/A
No N/A
Yes
Yes
Yes
Yes
Yes
Yes
No 2/
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
The 98.75% Technical serves as a manufacturing-use product.
The 99.76% Technical serves as a manufacturing-use product.
_!/ Not applicable. Although product chemistry data nay been submitted in the past, the Agency has determined that
these data must be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The compound does not require submittal of samples at this time.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER OXYCKLORIDE SULFATE 99.9% TECHNICAL3 (EPA REG. NO. 55146-31)
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Composition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Manufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
Certified Limits
_^ Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63-4 - Odor
63-5 - Melting Point
63-6 - Boiling Point
63-7 - Density, Bulk Density, or
Specific Gravity
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
Use Does EPA
Patterns Have Data?
All
All
All
All
All
All
All
All
All
All
All
All
Partially
No
No
No
No
No
No
No
No
No
No
Partially
Bibliographic Must Addtl Time Frame
Citation1 Data be for
Submitted? Submission
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER OXYCHDDRIDE SULFATE 99.9% TECHNICAL3 (EPA REG. NO. 55146-31)
Data Requirement
Test Use Does EPA Bibliographic
Substance Patterns Have Data? Citation3-
J158. 120 Product Chemistry (Continued)
63-8
63-9
63-10
63-11
63-12
63-13
Other
64-1
- Solubility
- Vapor Pressure
- Dissociation Constant
- Octanol/Water Partition
Coefficient
-pH
- Stability
Requirement:
- Submittal of samples
TGAI or PAI
PAI
PAI
PAI
TGAI
TGAI
N/A
No
No
No
No
No
No
No
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Must Addtl Time Frame
Data be for
Submitted? Submission
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
No 2/
a The 99.9/100% Technical serves as a manufacturing-use product.
_!/ Not applicable. Although product chemistry data may have been submitted in the past, the Agency has determined that
~~ these data must be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The compound does not require samples at this time.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR COPPER OXYCHLORIDE SULFATE, 56% TECHNICAL3 (EPA REG. NO. 55146-5)
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Conposition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Manufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
4b> Certified Limits
Ovl
Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63-4 - Odor
63-5 - Melting Point
63-6 - Boiling Point
63-7 - Density, Bulk Density, or
Specific Gravity
TGAI
1GAI
TGAI
1GAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
TGAI
Use Does EPA
Patterns Have Data?
All
All
All
All
All
All
All
All
All
All
All
All
Partially
Partially
No
No
No
No
No
No
No
No
No
Partially
Bibliographic Must Addtl Time Frame
Citation1 Data be for
Submitted? Submission
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
6 Months
6 Months
6 Months
6 Months
6 Months
6 Months
-------
TABTF. A
GENERIC DATA REQUIREMENTS FOR COPPER OXYCHDORIDE SULFATE, 56% TECHNICAL^ (EPA REG. NO. 55146-5)
Data Requirement
Test Use Does EPA
Substance Patterns Have Data?
Bibliographic Must Addtl Time Frame
Citation1 Data be for
Submitted? Submission
§158.120 Product Chemistry (Continued)
63-8
63-9
63-10
63-11
63-12
63-13
Other
64-1
- Solubility
- Vapor Pressure
- Dissociation Constant
- Octanol/Water Partition
Coefficient
-pH
- Stability
Requirement:
— Submittal of samples
TGAI or PAI
PAI
PAI
PAI
TGAI
TGAI
N/A
Partially
No
No
No
No
No
No
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
No 2/
a The 56% Technical serves as a manufacturing-use product.
_!/ Not applicable. Although product chemistry data nay been submitted in the past, the Agency has determined that
these data must be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The compound does not require samples at this time.
-------
TABLE A
3/11 GENERIC DATA RETIREMENTS FOR UNREGISTERED GROUP II COPPER COMPOUNDS, TECHNICAL PRODUCTS a/
Data Requirement Test
Substance
§158.120 Product Chemistry
Product Identity and Composition:
61-1 - Product Identity and Disclosure
of Ingredients
61-2 - Description of Beginning Mate-
rials and Manufacturing Process
61-3 - Discussion of Formation of
Impurities
Analysis and Certification of Product
Ingredients
62-1 - Preliminary Analysis of Product
Samples
62-2 - Certification of Ingredient
Limits
62-3 - Analytical Methods to Verify
Certified Limits
^
•^ Physical and Chemical Characteristics
63-2 - Color
63-3 - Physical State
63-4 - Odor
63-5 - Melting Point
63-6 - Boilinq Point
TCAI
TGAI
TCAI
TCAI
TCAI
TCAI
TCAI
TGAI
TCAI
TCAI
TCAI
Use Does EPA
Patterns Have Data?
All
All
All
All
All
All
All
All
All
All
All
Partially
No
No
No
No
No
No
No
No
No
No
Bibliographic Must Addtl Time Frame
Citation1 Data be for
Submitted? Submission
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
6 Months
6 Months
6 Months
12 Months
12 Months
12 Months
G Months
6 Months
6 Months
6 Months
6 Months
63-7 - Density, Bulk Density, or
Specific Gravity
TCAI
All
No
N/A
Yes
6 Months
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR UNREGISTERED GROUP II COPPER (COMPOUNDS, TECHNICAL PRODUCTS a/
Data Requirenent Test Use Does EPA Bibliographic Must Addtl Time Frame
Substance Patterns Have Data? Citation1 Data be for
Submitted? Submission
§158.120 Product Chemistry (Continued)
63-8
63-9
63-10
63-11
63-12
63-13
Other
64-1
- Solubility TGAI or PAI
- Vapor Pressure PAI
- Dissociation Constant PAI
- Octanol/Water Partition
Coefficient PAI
- pH TGAI
- Stability TGAI
Requirement:
- Submittal of samples N/A
No N/A
No N/A
No N/A
No N/A
No N/A
No N/A
No N/A
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
Yes 6 Months
No 2/
a/ Unregistered products, analogous to technicals, are likely to serve as manufacturing-use products for copper amnonium
~ conplex, copper carbonate, copper chloride dihydrate, copper nitrate and copper oxalate. Note that unregistered
technicals may be used to formulate other Group II Copper Compounds.
I/ Not applicable. Although product chemistry data may been submitted in the past, the Agency has determined that
~~ these data must be resubmitted for each pesticide. New requirements have been introduced and previously submitted
data must be updated. Therefore bibliographic citations for the old data are not applicable.
2/ The compound does not require samples at this time.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Test1 Does EPA Bibliographic Must Addtl Tine Frame
Data Requirement Substance Have Data? Citation Data be for
Submitted? Submission
§158.125 Residue Chemistry
171-4 - Nature of Residue
(Metabolism)
- Plants PAIRA Yes 00062069
00070287
00070288
00099255
00099256
00099257
00099258
00099259
00099260
00099262 No
00099263
00099269
00099281
00099282
00099284
00099288
00099537
- Livestock
4s* 171-4 - Residue Analytical
-*J Method
- Plant residues
- Animal Residues
PAIRA & Plant
Meatbolites
Yes
00062068
No
TGAI &
Metabolites
TGAI
Yes
Yes
00002200 00088167
00065678 00099522
00099551
00065678 00099551
00099522
No
No
171-4 - Storage Stability Data PAI
No
No I/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
CO
Data Requirement
Test
Substance
Does EPA Bibliographic
Have Data? Citation
Must Addtl Time Frame
Data be for
Submitted? Submission
§158.125 Residue Chemistry - Continued
171-4 - Magnitude of the Residue
Residue Studies
o Crop
— Crop Field Trials
Pears
— Processed Food/Feed
— Meat/Milk/
Poultry /Eggs
- Potable Water
- Fish
- Irrigated Crops
- Food Handling
171-5 - Reduction of Residue
171-6 - Proposed Tolerance
-
TEP
EP
TGAI or Plant
Metabolites
EP
EP
EP
EP
Residue of
Concern
Residue of
Concern
GS0649-001
Yes 00002200,
00088167
No
No
No
No
No
No
No
No
No 2/
No 3/
No 3/
No 4/
No 4/
No 3/4/
No 4/
No 4/
No 4/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
§158.125 Residue Chemistry - Continued
I/ There are no data aval table on storage stability on plants. In light of the exemptions from the requirements of
a tolerance established for copper, and since it occurs naturally in plants and aninals, no storage stability
studies are necessary.
2/ The Agency intends to revoke the existing tolerance of 3 ppm combined copper on pears as being unnecessary to
protect human health. Thus additional data to support the tolerance on pears are not required.
3/ When applied to growing crops in accordance with good agricultural practices, copper carbonate, copper hydroxide,
and copper oxychloride are exenpt from the requirements of a tolerance (40 CFR 180.1001 (a) (1).
4/ Copper is exempted from the requirements of a tolerance in neat, milk, poultry/eggs, potable water, fish, irrigated
crops when it is used, as an algicide or herbicide in irrigation water systems, lakes, ponds, reservoirs, or
other bodies of water (40 CFR 180.1021 (a)).
-------
GENERIC DATA
TABLE A
FOR GROUP II COPPER COMPOUNDS
Data Requirement Test
Substance
§158.130 Environmental Fate
DEGRADATION STUDIES-LAB:
161-1 - Hydrolysis TGAI or PAIRA
Photodegradation
161-2 - In water TGAI or PAIRA
161-3 - On soil TGAI or PAIRA
161-4 - In Air TGAI or PAIRA
METABOLISM STUDIES-LAB:
162-1 - Aerobic Soil TGAI or PAIRA
162-2 - Anaerobic Soil TGAI or PAIRA
162-3 - Anaerobic Aquatic TGAI or PAIRA
162-4 - Aerobic Aquatic TGAI or PAIRA
MOBILITY STUDIES:
163-1 - Adsorption/ TGAI or PAIRA
Desorption
163-2 - Volatility (Lab) TEP
163-3 - Volatility (Field) TEP
Use Does EPA Bibliographic Must Addtl Time Frame
Patterns Have Data? Citation Data be for
Submitted? Submission
A,B,C,D,
F,H,
A,B,C,D,
F,H,
A,B
A,B
A,B,C,D
A,B
C,D
C,D
A,B,C,D,
E,F,H
A,B,E,F
A,B,E,F
No
No
No
No
No
NO
No
No
No
No
No
No I/
No 2/
No 2/
No 2/
Ho 3/
No 3_/
No 3_/
No 3_/
Yes 4/ 12 Months
No 5/
No5/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test
Substance
Use
Patterns
Does EPA Bibliographic
Have Data? Citation
Must Addtl
Data be
Submitted?
Time Frame
for
Sutnassion
§158.130 Environmental Fate - Continued
DISSIPATION STUDIES-FIELD:
164-1 - Soil
164-2 - Aquatic (Sediment)
164-3 - Forestry
164-4 - Combination and
Tank Mixes
164-5 - Soil, Long-term
ACCUMULATION STUDIES:
165-1 - Rotational Crops
(Confined)
165-2 - Rotational Crops
(Field)
165-3 - Irrigated Crops
165-4 - In Fish
165-5 - In Aquatic Non-Target
TEP
TEP
TEP
TEP
PAIRA
TEP
TEP
TGAI or PAIRA
TEP
A,B,C
C,D
N/A 7/
N/A 8/
A,B,H
A,B,C
A,B,C
A,C.D
A,B,C,D
D
No
No
No
No
No
No
No
No
Yes 6/
Yes 6_/
No 3/
No 3_/
No 3/
No 3/
No 3_/
No 3/
27 Months
27 Months
Organisms
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
§158.130 Environmental Fate - Continued
I/ A hydrolysis study is not required because these pesticides are inorganic compounds and will not hydrolyze.
2/ Data are not required because these pesticides are inorganic compounds and are resistant to photolysis.
3/ The Guidelines and use patterns indicate that these data are not required.
4_/ The domestic outdoor, greenhouse, and aquatic uses will require a basic equilibrium (adsorption/desorption) test,
but not a leaching study as described in the guidelines 163-1.
5/ Data are not required, because the conpounds have a low vapor pressure and do not volatilize readily.
6_/ Data are required to clarify the following: (a) Will copper ion leave treated fields via runoff or other
mechanisms and enter aquatic systems; (b) Once in the aquatic system, will the copper ion remain in solution or
will it becone unavailable for impact on aquatic organisms (e.g. via adsorption to sediment or precipitation)?
The guideline testing protocols for soil and aquatic sediment dissipation studies (164-1,2) will need to be
modified for these copper compounds. Registrants nust consult with the Agency to agree on acceptable protocols
for meeting these data requireermts, prior to initiating testing.
Data are not required because there are no forestry uses.
The data requirements for combination and tank mixes are not addressed in this Standard.
en
-------
TABU: A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
on
Data Requirement
§158.140 Reentry Protection
132-1 - Foliar Dissipation
132-1 - Soil Dissipation
133-3 - Dermal Exposure
133-4 - Inhalation Exposure
§158. 142 Spray Drift
201-1 - Droplet Size Spectrum
201-1 - Drift Field Evaluation
Special Tests
Test
Substance
TEP
TEP
TEP
TEP
TEP
TEP
Use
Pattern
A,B,C,D
A,B,C,D
A,B,C,D
A,B,C,D
Reserved
Reserved
N/A I/
Does EPA Bibliographic
Have Data? Citation
No
No
No
No
V
II
Must Addtl Time Frame
Data be for
Submitted? Submission
No I/
No I/
No I/
No I/
I/ Available data indicate that there are no toxicological concerns with regards to reentry exposure of the Group II
~ Copper Compounds by workers.
2/ Reserved: Data may be required to clarify the following: (a) Will copper ion leave treated fields via runoff or
other mechanisms and enter aquatic systems; (b) Once in the aquatic system, will the copper ion remain in solution
or will it become unavailable for impact on aquatic organisms (e.g. via adsorption to sediment or precipitation)?
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Date Requirement
Test Use Does EPA Bibliographic
Substance Patterns Have Data? Citation
§158.135 Toxicology
ACUTE TESTING;
81-1 - Acute Oral Toxicity TGAI I/
81-2 - Acute Dermal Toxicity TGAI 2/
81-3 - Acute Inhalation TGAI
Toxicity
81-4 - Primary Eye Irritation MP 2/
81-5 - Primary Dermal MP 2/
Irritation
81-6 - Dermal Sensitization TGAI
SUBCHRONIC TESTING;
82-1 - 90-Day Feeding - TGAI
Rodent
Nonrodent (dog)
82-2 - 21-Day Dermal TGAI
A,B,C,D Partially
E,F,H,I
A,B,C,D Partially
E,F,H,I
A,B,C,D Partially
E,F,HrI
A,B,C,D, Partially
E,F,H,I
A,B,C,D, Partially
E,F,H,I
A,B,C,D Partially
E,F,H,I
A,B,C,D,
E,F,H,I
A,BfC,Df
E,F,H,I
No
00053980,00133277, Yes I/
00152506,00155931, ~~
00159371
00053980,00126194, Yes 2/
00152505,00159371
00155932,00159371, No 3/
00160580
00053980,00126194, Yes 2/
00152503,00155934
00053980,00126194, Yes 2/
00152502,00155935,
00159371
00152504,00155936 No 4/
No 5/
No 5/
Must Addtl Time Frame
Data be for
Submitted Submission
9 Months
9 Months
9 Months
9 Months
-------
TABLE A
GENERIC DftIA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test Use Does EPA Bibliographic
Substance Patterns Have Data? Citation
Must Addtl Time Frame
Data be for
Submitted? Submission
§158.135 Toxicology - Continued
SUBCHRONIC TESTING:
82-3 - 90-Day Dermal TGAI
82-4 - 90-Day Inhalation TGAI
CHRONIC TESTING:
83-1 - Chronic Toxicity - TGAI
Rodent (rat)
Nonrodent (dog)
JJJ 83-2 - Oncogenicity - TGAI
Rat
Mouse
83-3 - Teratogenicity - TGAI
Rat
Rabbit
83-4 - Reproduction - TGAI
2-generation
A,B,C,D, No
E,F,H,I
AfB,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
A,B,C,D, No
E,F,H,I
No 5/
No 5/
No 5/
No 5/
No 5/
No 5/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test Use Does EPA Bibliographic
Substance Pattern Have Data? Citation
Must Addtl Time Frame
Data be for
Submitted? Submission
§158.135 Toxicology - Continued
MUTAGENICITY TESTING
84-2 - Gene Mutation
(Ames Test)
TGAI
84-2 - Structural Chromosomal TGAI
Aberration
84-2 - Other Genotoxic
Effects
TGAI
A,B,C,D
E,F,H,I
No
A,B,C,D, No
E,F,H,I
AfB,C,D, No
E,FrH,I
No 5/
No 5/
No 5/
\J Data are required for: copper ammonium complex, copper ammonium carbonate, and copper oxalate.
NOTE: If there are no registered technical/manufacturing-use products for these compounds, a
representative end-use fornulation should be tested.
2/ Data are required for: copper ammonium conplex, copper ammonium carbonate, basic copper chloride,
copper citrate, copper chloride dihydrate, copper oxalate and copper nitrate. NOTE: If registered
technical/manufacturing-use products do not exist, a representative end-use fornulation should be tested.
3/ Toxicological concerns for acute inhalation exposure is usually only in the industrial setting such as metal
works, and is not considered a significant concern for pesticide application. There is a threshhold limit
value (TLV) of 1 mg/m^ for all copper dusts or mists (on a "time weighted average" [TWA] basis) established by
the American Conference of Governmental Industrial Hygientists: Documentation of Threshhold Limit Values for
Substances in the Vtorkplace, 3rd Edition, 1971.
4/ Copper is a recognized dermal sensitizer, therefore data will not be required on any of the chemicals in the
Group II Copper Compounds. Data may be submitted or cited, however, to rebut this conclusion for specific products.
5/ The element of toxicological concern in these Group II Copper Compounds is the copper ion, and although the Agency
does not have Guideline-quality studies for this data requirement per se, there is adequate information in the
extensive open literature on copper (ion) to characterize its toxicity.
-------
Ul
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test Use
Substance Pattern
Does EPA
Have Data?
Bibliographic
Citation
Must Addtl
Data be
Submitted?
Time Frame
for
Submission
§158.145 Wildlife and
Aquatic Organisms
AVIAN AND MAMMALIAN TESTING
71-1
71-2
71-3
71-4
- Avian Oral 11)50
- Avian Dietary LCso
a. Waterfowl
b. Upland game bird
- Wild Manual
Toxicity
- Avian Reproduction
a. Waterfowl
b. Upland game bird
TGAI
TCAI
TGAI
TEP
TGAI
TGAI
TGAI
A1/,B2/,D3/
A1/,B2/,D3/
A1/,B2/,D3/
Al/
A1/,B2/,D3/
Al/
A1/,B2/
Yes4/
Yes
Yes
Partially
No
No
No
00067455 5/
00067456 5/
00067454 5_/
00106119 5/
GS0649-002 7/**
No 4/6/
No 4/
No 4/
No
No 8/
Yes 9/
Yes 9/
24 Months
24 Months
71-5 - Simulated and Actual
Field Testing -
- Manuals, and TEP
- Birds
Actual Field Testing
- Mammals, and TEP
- Birds
K3UATIC ORGANISM TESTING
72-1 - Acute Toxicity
Freshwater Fish
a. warnwater TGAI
A1/»B2/,D3/ No
A1/,B2/,D3/ No
Reserved 10/
Reserved 10/
Yes
GS0649-003 ll/
GS0649-004 TT/
00099374 5/
No
-------
Ui
CD
TABLŁ A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test
Substance
Use
Pattern
Does EPA
Have Data?
Bibliographic
Citation
Must Addtl
Data be
Submitted?
Tine Frame
for
Submission
§158.145 Wildlife and
Aquatic Organisms
MUATIC ORGANISM TESTIN3
72-1 - Acute Toxicity
Freshwater Fish
a. warnwater (cont'd) TGAI
b. coldwater
TEP
TCAI
Yes
M/,B2/,D3/ Yes
72-2 - Acute ICso Freshwater
Invertebrates
72-3 - Acute LCso Estuarine
and Marine Organisms
TEP
TGAI
TGAI
A1/,B2/,D3/ Yes
A1/.D3/17/ Yes
72-4 - Fish Early Life
Stage and Aquatic
Invertebrate Life-
Cycle
T3AI
M/,B2/,D3/ Yes
00047460 5/
GS0649-003" 13/ No 14/
GS0649-O04 ll/ No
00099371 l^T"
00099370 12/
00047460 5/
00099168 5/
00056781 5/
00099355 15/
GS0649-006 13/
00099558 5/ No 16/
00085289 5/18/ No
00099559 5/18/
00099561 5/I9/
00028002 5/207**
00086564 5/2T/**
GS0649-007 No 22/
-------
TABU: A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
Data Requirement
Test Use Does EPA Bibliographic
Substance Pattern Have Data? Citation
Must Addtl Time Frame
Data be for
Submitted? Submission
Ul
§158.145 Wildlife and
Aquatic Organisms
AQUATIC ORGANISM TESTIN3
72-5 - Fish full life-cyle
72-6 - Aquatic Organism
Accumulation
- Crustacean
- Fish
- Insect Nymph
- Mollusk
72-7 - Simulated Field
Testing
- Aquatic Organisms
- Actual Field Testing
- Aquatic Organisms
70-1 - Special Testing
T3AI
TGAI, PAI OR
Degradation
Product
A1/,B2/,D3/ Yes
No
GS0649-007
TEP
A1/,B2/,D3/ No
TEP
Al/
No
No 22/
No 22/
Reserved 23/
Yes 24/
3 Months 24/
(ProtocolT"
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
§158.145 Wildlife and Aquatic Organisms - Continued
I/ The following compounds are registered for Terrestrial, Food Crops:
Chemical Name Type Shaughnessy No.
Copper Ammonium Carbonate F 022703
Copper Ammonium Complex F 022702
Copper Carbonate F 022901
Copper Hydroxide F,H 023401
Copper Oxalate B 023305
Copper Oxychloride F 023501
Copper Oxychloride Sulfate F 022702
F-Fungicide; H-Herbicide; B-Bird Repellent
2/ The following compounds are registered for Terrestrial, Nonfood Crops:
Copper Ammonium Complex (ornamental plants, forest trees, wood treatment)
Copper Chloride Dihydrate (orchid and flower bulb medium)
Copper Hydroxide (ornamental plants, forest trees)
Copper Oxychloride (ornamental plants, forest trees)
Copper Oxychloride Sulfate (ornamental plants, tobacco, forest trees)
3y The following compounds are registered for Aquatic Nonfood Crops:
Copper citrate and copper nitrate.
4_/ The studies which satisfy this requirement for group II copper compounds were conducted with copper sulfate which is
not one of the copper compounds included in this standard.
5_/ Conducted with copper sulfate, taken from copper sulfate registration standard dated March 21, 1985.
6/ The avian acute oral LDso would only be required for cooling tower and industrial water treatment (copper citrate a
copper nitrate). However, these studies will not be required for this Registration Standard since the results from
the copper sulfate tests are being used to indicate acute oral toxicity for all group II copper compounds.
T/ Conducted with 51% MCE formulation of copper carbonate called Nutra-spray. This test may be upgraded if additional
description of procedure is provided.
8/ Copper compounds are considered to be low in toxicity to mammals/ therefore the study is not required.
-------
TABLE A
GENERIC DMA REQUIREMENTS TOR. GROUP II COPPER COMPOUNDS
§158.145 Wildlife and Aquatic Organisms - Continued
9/ Avian reproduction tests are required for oopper hydroxide and copper oxychloride sulfate. If these rampounds
exhibit unusually hicfi chronic toxicity, tests with other conpounds may be required.
10/ Reserved pending receipt of avian reproduction studies.
ll/ Conducted with copper oxychloride.
12/ Conducted with copper hydroxide.
13/ Conducted with 50 ICE formulation of copper oxychloride sulfate.
14/ Fornulated testing is not a requirement for copper oxychloride sulfate.
15/ Conducted with 8% MCE formulation of copper ammonium carbonate.
16 Data from tests with copper sulfate and the EPA Ambient Water Quality Criteria for Copper - 1984 document
(GS0649-007) fulfill this requirement.
IT/ Not required for copper chloride, copper oxalate, or copper chloride dihydrate.
18/ Pink shrinp IC$Q.
19/ Oyster LCso-
20/ Striped bass LCso
21/ Ponpano UCso-
22/ Data frcm EPA Water Quality Document for Copper - 1984 is sufficient to characterize the chronic toxicity of
copper conpounds to fish and aquatic invertebrates.
23/ Reserved pending receipt of information from residue and incidence monitoring.
24/ Residue and incidence monitoring: See Table 3 for copper compounds requiring monitoring and specific use sites
which trigger residue monitoring or residue and incidence monitoring.
OS Residue monitoring would include taking samples of water and sediment from several locations for each use trig-
— gering residue monitoring. These samples must be analyzed for total recoverable copper and acid-soluble copper
as defined in the EPA Water Quality Criteria for Copper - 1984.
Incidence monitoring means structured searches for evidence of acute response of aquatic organisms to the
presence of copper. This nust be conducted at several locations throughout the use areas triggering this type
of monitoring. Incidence monitoring would be primarily fish kills but could also include other observeable
evidence of acute toxicity including that demonstrated by invertebrates. It would be acceptable to conduct
incidence and residue monitoring concurrently at the same locations for those sites that require both types of
monitoring. In any case, residue monitoring nust accompany incidence monitoring to include analysis of any dead
or moribund fish found.
Within three months of issuance, registrants nust submit a proposed monitoring program protocol incorporating the
types of monitoring described above which are required for their chemicals/use patterns indicated in the table
below. Once the Agency accepts a monitoring program plan, both types of monitoring must be conducted until the
results provide data adequate to determine whether these copper compounds pose risk to aquatic organisms, and if
so, to quantify those risks. The Agency will review annual reports of monitoring results until a final
determination on this issue is made.
-------
O\
K)
TABIZ A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
§158.145 Wildlife and Aquatic Organisms - Continued
Table 3; Copper compounds and the specific sites that require monitoring:
USE SITE SHAUGHNESSY NUMBERS FOR COPPER COMPOUNDS
Alfalfa
Apples
Barley
Beans
Peanuts
Soybeans
Sugar beets
Citrus
022703
-
-
-
R I
R
R
R
R I
023501
-
-
R
-
R I
R I
023503
-
R
-
R I
—
—
R I
. R I
023401
R I
—
R I
R I
R I
—
R I
R I
R- Residue Monitoring
I- Incidence Monitoring for Acute Effects to Aquatic Organisms
* Fulfills requirement on its own.
** Could fulfill requirement in conjunction with other test data.
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS:
(Copper armonium carbonate, ocpper amiDtiiuin conplex,
copper carbonate, copper hyroxide, and copper oxychloride)
Data Requirenent
Test Use Does EPA Bibliographic
Substance Pattern Have Data? Citation
Must Addtl Time Frame
Data be for
Submitted? Submission
§158.155 Nontarget Insect
NONTABGET INSECT TESTING -
POLLINATORS!
141-1 - Honey bee acute
contact toxicity
141-2 - Honey bee - toxicity
of residues on
foliage
141-4 - Honey bee subacute
feeding study
141-5 - Field testing for
pollinators
NONTARGET INSECT TESTING -
K3UATIC INSECTS;
142-1 - Acute toxicity to
aquatic insects
142-1 - Aquatic insect
life-cycle study
142-3 - Simulated or actual
field testing for
aquatic insects
143-1 - NONTARGET INSECT
thru TESTING - PREDATORS
143-3 AND PARASITES
TCAI
TEP
A,B
A,B
(Reserved) 2/
TEP
A,B
(Reserved) 3_/
(Reserved) 3_/
(Reserved) 3/
(Reserved) 3_/
No
No
Yes
No I/
9 Months
No
No I/
-------
TABLŁ A
GENERIC DATA REQUIREMENTS TOR GROUP II COPPER COMPOUNDS
I/ Data requirement is reserved pending receipt of data from the acute contact study.
2/ Data requirement is reserved pending development of test methodology.
3/ Data requirement is reserved pending an Agency decision as to whether the data requirement should be
established.
-------
TABLE A
GENERIC DATA RETIREMENTS FOR GROUP II COPPER COMPOUNDS (Copper Oxychloride Sulfate)
Data Requirement
Test Use Does EPA Bibliographic
Substance Pattern Have Data? Citation
Must Addtl Tine Frame
Data be for
Submitted? Submission
ON
cn
§158.155 Nontarget Insect
NONTARGET INSECT TESTIN3 -
POLLINATORS;
141-1 - Honey bee acute
contact toxicity
141-2 - Honey bee - toxicity
of residues on
foliage
141-4 - Honey bee subacute
feeding study
141-5 - Field testing for
pollinators
NONTARGET INSECT TESTING -
142-1 - Acute toxicity to
aquatic insects
142-1 - Aquatic insect
life-cycle study
142-3 - Simulated or actual
field testing for
aquatic insects
143-1 - NONTARGET INSECT
thru TESTING - PREDATC
143-3 AND PARASITES
TGAI
TEP
A,B
A,B
(Reserved) 2/
TEP A,B
(Reserved) 3_/
(Reserved) 3_/
(Reserved) 3_/
(Reserved) 3/
Yes
No
00036935
No
No I/
No I/
-------
TABLE A
GENERIC DATA REQUIREMENTS FOR GROUP II COPPER COMPOUNDS
(Copper Oxychloride Sulfate)
I/ Data from the acute contact study indicate low toxicity to honey bees, therefore further testing is not required.
2/ Data requirement is reserved pending development of test methodology.
3/ Data requirement is reserved pending an Agency decision as to whether the data requirement should be
established.
-------
APPENDIX II
LABELING APPENDICES
67
-------
SUMMARY-1
LABEL CONTENTS
40 CPR 162.10 requires that certain specific labeling
statements appear at certain locations on the label. This
is referred to as format labeling. Specific label items listed
below are keyed to the table at the end of this Appendix.
Item 1. PRODUCT NAME - The name, brand or trademark is
required to be located on the front panel, preferably centered
in the upper part of the panel. The name of a product will
not be accepted if it is false or misleading.
Item 2. COMPANY NAME AND ADDRESS - The name and address
of the registrant or distributor is required on the label.
The name and address should preferably be located at the
bottom of the front panel or at the end of the label text.
Item 3. NET CONTENTS - A net contents statement is
required on all labels or on the container of the pesticide.
The preferred location is the bottom of the front panel
immediately above the company name and address, or at the end
of the label text. The net contents must be expressed in the
largest suitable unit, e.g., "1 pound 10 ounces" rather than
"26 ounces." In addition to English units, net contents may
be expressed in metric units. [40 CFR I62.10(d)]
Item 4. EPA REGISTRATION NUMBER - The registration
number assigned to the pesticide product must appear on the
label, preceded by the phrase "EPA Registration No.," or "EPA
Reg. No." The registration number must be set in type of a
size and style similar to other print on that part of the
label on which it appears and must run parallel to it. The
registration number and the required identifying phrase must
not Appear in such a manner as to suggest or imply recommendation
or endorsement of the product by the Agency.
[40 CPR I62.10(e)]
Item 5. EPA ESTABLISHMENT NUMBER - The EPA establishment
number, preceded by the phrase "EPA Est." is the final estab-
lishment at which the product was produced, and may appear
in any suitable location on the label or immediate container.
It must also appear on the wrapper or outside container of
the package if the EPA establishment number on the immediate
container cannot be clearly read through such wrapper or container.
[40 CFR I62.10(f)]
Item 6A. INGREDIENTS STATEMENT - An ingredients statement
is required on the front panel. The ingredients statement must
contain the name and percentage by weight of each active ingredient
and the total percentage by weight of all inert ingredients.
The preferred location is immediately below the product name.
The ingredients statement must run parallel with, and be clearly
distinguished from, other text on the panel. It must not be
placed in the body of other text. [40 CFR I62.10(g)]
-------
SUMMARY-2
Item 6B. POUNDS PER GALLON STATEMENT - For liquid agricul-
tural formulations, the pounds per gallon of active ingredient
must be Indicated on the label.
Item 7. FRONT LABEL PRECAUTIONARY STATEMENTS - Front panel
precautionary statements must be grouped together, preferably
within a block outline. The table below shows the minimum type
size requirements for various size labels.
Size of Label Signal Word "Keep Out of Reach
on Front Panel Minimum Type Size of Children"
in Square Inches All Capitals Minimum Type Size
5 and under 6 point 6 point
above 5 to 10 10 point 6 point
above 10 to 15 12 point 8 point
above 15 to 30 14 point 10 point
over 30 18 point 12 point
Item 7A. CHILD HAZARD WARNING STATEMENT - The statement
"Keep Out of Reach of Children" must be located on the front
panel above the signal word except where contact with children
during distribution or use is unlikely. [40 CFR 162 ,10(h) (1) (11) ]
Item 7B. .SIGNAL WORD - The signal word (DANGER, WARNING,
or CAUTION) is required on the front panel immediately below
the child hazard warning statement. [10 CFR 162.10 (h)(l)(i)]
Item 70. SKULL & CROSSBONES AND WORD "POISON" - On products
assigned a toxicity Category I on the basis of oral, dermal,
or inhalation toxicity, the word "Poison" shall appear on the
label in red on a. background of distinctly contrasting color and
the skull and crossbones shall appear in immediate proximity to
the word POISON. [10 CFR 162 .10 (h) ( 1 ) ( i) ]
Item 7D. STATEMENT OF PRACTICAL TREATMENT - A statement
of practical treatment (first aid or other) shall appear on
the label of pesticide products in toxicity Categories I,
II, and TIT. [10 CFR 162 ,10(h) (1) (ill) ]
Item 7E. REFERRAL STATEMENT - The statement "See Side
(or Back) Panel for Additional Precautionary Statements" is
required on the front panel for all products, unless all
required precautionary statements appear on the front panel.
CFR I62.10(h)(l)(lil)]
Item 8. SIDE/BACK PANEL PRECAUTIONARY LABELING - The
precautionary statements listed below must appear together
on the label under the heading "PRECAUTIONARY STATEMENTS."
The preferred location is at the top of the side or back
panel preceding the directions for usy, and it is preferred
that these statements be surrounded by a block outline. Each
of the three hazard warning statements must be headed by the
appropriate hazard title. [10 CFR 162. L0(h) (2) ].
69
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SUMMARY-3
Item 8A. HAZARD TO HUMANS AND DOMESTIC ANIMALS - Where a
hazard exists to humans or domestic animals, precautionary
statements are required Indicating the particular hazard, the
route(s) of exposure and the precautions to be taken to avoid
accident, injury or damage. [MO CFR I62.10(h)(2)(1)]
Item 8B. ENVIRONMENTAL HAZARD - Where a hazard exists to
non-target organisms excluding humans and domestic animals,
precautionary state-meats are required stating the nature of
the hazard and the appropriate precautions to avoid potential
accident, injury, or damage. [10 CPR 162.10(h)(2)(11)]
Item 80. PHYSICAL OR rJHRMICAL HAZARD - FLAMMABILITY
Precautionary statements relating to flammabillty of a product
are required to appear on the label if It meets the criteria
l-i the PHYS/CHEM Labeling Appendix, The requirement is
based on the results of the flashpoint determinations and
flame extension tests required to be submitted for all products.
These st-ttoments are to be located In the side/back panel
precautionary statements section, preceded by the heading
"Physical/Chemical Hazards." Note that no signal word is
used in conjunction with the flammabllity statements.
Item 9A. RESTRICTED USE CLASSIFICATION - FIPRA sec. 3(d)
requires that all pesticide formulations/uses be classified
for either general or restricted use. Products classified
for restricted use may be limited to use by certified applicators
or- persons under their direct supervision (or may be subject
to other restrictions that may be imposed by regulation).
In the Registration Standard, the Agency has (1) indicated
certain formulations/uses are to be restricted (Section IV
Indicates *hy the product has been classified for restricted
use); or (2) reserved any classification decision until
appropriate data are submitted.
The Regulatory Position and Rationale states whether
products containing this active ingredient are classified
for restricted use. If they are restricted the draft label(s)
submitted to the Agency as part of your application must
reflect this determination (see below).
If you do not believe that your product should be classified
for restricted use,- you must submit any information and
rationale with your application for reregistration. During
the Agency's review of your application, your proposed classi-
fication determination will be evaluated in accordance with
the provisions of 10 CFR I62.11(c). You will be notified of
the Agency's classification decision.
70
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SUMMARY- 4
Classification Labeling Requirements
If your product has been classified for restricted use,
the following label requirements apply:
1. All uses restricted.
a. The statement "Restricted Use Pesticide" must
appear at the top of the front panel of the label. The
statement must be set in type of the sane minimum size
as required for human hazard signal word (see table in
CPR
b. Directly below this statement on the front panel,
a summary statement of the terms of restriction must
appear (including the reasons for restriction if specified
in Section I). If use is restricted to certified applicators,
the following statement is required: "For retail sale
to and use only by Certified Applicators or persons
under their direct supervision and only for those uses
covered by the Certified Applicator's Certification."
2. Some but not all uses restricted. If the Regulatory
Position and Rationale states that some uses are classified
for restricted use, and some are unclassified, several courses
of action are available:
a. You may label the product for Restricted use.
If you do so, you may include on the label uses that
are unrestricted, but you may not distinguish them
on the label as being unrestricted.
b. You may delete all restricted uses from your
label and submit draft labeling bearing only unrestricted
uses .
c. You may "split" your registration, i.e., register
two separate products with identical formulations, one
bearing only unrestricted uses, and the other bearing
restricted uses. To do so, submit two applications for
rereglstration, each containing all forms and necessary
labels. Both applications should be submitted simul-
taneously. Note that the products will be assigned
separate registration numbers.
Item 9B. MISUSE STATEMENT - All products must bear the
misuse statement, "It is a violation of Federal law to use
this product in a manner inconsistent with its labeling."
This statement appears at the beginning of the directions
for use, directly beneath the heading of that section.
71
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SUMMARY-5
Item 10A. REENTRY STATEMENT - If a reentry interval
has been established by the Agency, it must be included on
the label. Additional worker protection statements may be
required in accordance with PR Notice 83-2, March 29, 1983-
Item 10B. STORAGE AND DISPOSAL BLOCK - All labels are
required to bear storage and disposal statements. These
statements are developed for specific containers, sizes, and
<*hem.i.!:y.l content. These instructions must be grouped and
appear under the heading "Storage and Disposal" in the directions
for use. This heading must be set In the same type sizes as
required for the child hazard warning. Refer to Appendix II,
STOR, PEST/DIS, and CONT/DIS to determine the storage and
disposal instructions appropriate for your products.
Item IOC. DIRECTIONS FOR USE - Directions for use must
be stated in terms which can be easily read and understood by
the average person likely to use or to supervise the use of
the pesticide. When followed, directions must be adequate to
protect the public from fraud and from personal injury and to
prevent unreasonable adverse effects on the environment.
[MO CFR 162.in]
COLLATERAL LABELING
Bulletins, leaflets, circulars, brochures, data sheets,
flyers, or other written or graphic printed matter which is
referred to on the label or which is to accompany the product
are termed collateral labeling. Such labeling may not bear
claims or representations that differ in substance from those
accepted in eona^ .-t-.l.oa with registration of the product. It
should be made part of the response to this notice and submitted
for review.
72
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SUMMARY-6
LABELING REQUIREMENTS OP THE PIFRA, AS AMENDED
ITEM
1
2
*
3
H
5 •
6A
6B
7
7A
7B
LABEL ELEMENT
Product name
Company name
and address
Net contents
EPA Reg. No.
EPA Est. No.
Ingredients
statement
Pounds/gallon
statement
Front panel
precautionary
statements
Keep Out of Reach
of Children
(Child. hazard
warning)
Signal word
APPLICABILITY
OP REQUIREMENT
All products
All products
All products
All products
All products
All products
Liquid products
where dosage
given as Ibs.
al/unit area
All products
All products
All products
PLACEMENT
REQUIRED
Front panel
None
None
None
None
Front panel
Front panel
Front panel
Front panel
Front panel
ON LABEL
PREFERRED
Center front
panel
Bottom front
panel or end
of label text
Bottom front
panel or end
of label text
Front panel
Front panel,
Immediately
before or
following
Reg. No.
Immediately
following
product name
Directly below
the main
ingredients
statement
Above signal
word
Immediately
below child
hazard
warning
COMMENTS
If registrant is not the producer, must
be qualified by "Packed for . . .,"
"Distributed by. . .," etc.
May be in metric units in addition to
U.S. units
Mist be In similar type size and run
jparallel to other type.
May appear on the container instead of
the label.
Text must run parallel with other text
on the panel.
All front panel precautionary statements
must be grouped together, preferably
blocked.
Note type size requirements.
Note type size requirements.
PO
-------
SUMMARY-7
ITEM
7C
7D
7E
8
8A
8B
LABEL ELEMENT
Skull & cross-
bones and word
POISON (in red)
Statement of
Practical
Treatment or
First Aid
Referral
statement
Side/back panel
precautionary
statements
Hazards to
humans and
domestic
animals
Envirormental
hazards
APPLICABILITY
OP REQUIREMENT
All products
which are Cat-
egory I based
on oral, der-
mal, or inhala-
tion toxicity
All products
in Categories
I, II, and III
All products
where pre-
cautionary
labeling
appears on
other than
front panel.
All products
All products
in Categories
I, II, and III
All products
PLACEMENT
REQUIRED
Front panel
Category I:
Front panel
unless refer-
ral statement
is used.
Others:
Grouped with
side panel
precautionary
statements .
Front panel
None
None
None
ON LABEL
PREFERRED
Both in close
proximity to
signal word
Front panel
for all.
Top or side
of back panel
preceding
directions
for use
Same as above
Same as above
COMMENTS
«
1
Must be grouped under the headings in
8A, 8B, and 8C; preferably blocked.
Must be preceded by appropriate signal
word.
Envirormental hazards Include bee
caution where applicable.
-------
SUMMARY-8
ITEM
9A
9B
10A
10B
IOC
LABEL ELEMENT
Physical OP
chemical
hazards
Restricted
block
Misuse
statement
Reentry
statement
Storage and
disposal block
Directions
for use
APPLICABILITY
OF REQUIREMENT
All pressurized
products, others
with flash
points under
150°P
All restricted
products
All products
PR Notice 33-2
or as determined
by^the Agency
All precincts
All products
PLACEMEN!
REQUIRED
None
Top center
of front
panel
Immediately
following
heading of
directions
for use
In the
directions
for use
In the
directions
for use
None
1 ON LABEL
PRhM-lKKEL)
Same as above
Preferably
blocked
Immediately
after misuse
statement
Immediately
before
specific
directions
for use or
at the end of
directions
for use
None
COMMENTS
Refer to Appendix II guide
FHYS/CHEM
Includes a statement of the terms of
restriction. The words "RESTRICTED USE
PESTICIDE" must be same type size as
signal word.
Required statement is:
"It is a violation of Federal law
to use this product in a manner ]
inconsistent with its labeling."
Must be sob apart and clearly distin-
guishable from from other directions
for use.
Refer to Appendix II guides STOR,
CONT/DIS, and PEST/DIS for further
information and required statements.
May be in metric as well as U.S. units
LT>
-------
0 162.10 Labeling requirements.
(a) General—
-------
Environmental Prelection Agency
§ 162.10
(v) The producing establishment
number as prescribed in paragraph (f)
of this section:
(vi) An ingredient statement as pre-
scribed in paragraph (g) cf this sec-
tion;
(vii) Warning or precautionary state-
ments as prescribed in paragraph (h)
of this section;
(viii) The directions for use as pre-
scribed in paragraph (i) of this section:
and
(ix) The use classification^) as pre-
scribed in paragraph (j) of this section.
(2) Prominence and legibility, (i) All
words, statements, graphic representa-
tions, designs or other information re-
quired on the libeling by the Act or
the regulations In this part must be
clearly legible to a person with normal
vision, and must be placed with such
conspicuousness (as compared with
other words, statements, designs, or
graphic matter on the labeling) and
expressed in such terms as to render it
likely to be read and understood by
the ordinary individual under custom-
ary conditions of purchase and use.
(ii) All required label text must:
(A) Be set in 6-polnt or larger type;
(B) Appear on a clear contrasting
background; and
(C) Not be obscured or crowded.
(3) Language to be -used. All required
label or labeling text shall appear in
the English language. However, the
Agency may require or the applicant
may propose additional text in other
languages as is considered necessary to
protect the public. When additional
text in another language is necessary.
all labeling requirements will be ap-
plied equally to both the English and
other-language versions of the label-
ing.
(4) Placement of Label—(1) General.
The label shall appear on or be secure-
ly attached to the Immediate contain-
er of the pesticide product. For pur-
poses of this Section, and the mis-
branding provisions of the Act. "se-
curely attached" shall mean that a
label can reasonably be expected to
remain affixed during the foreseeable
conditions and period of use. If the im-
mediate container is enclosed within a
wrapper or outside container through
which the label cannot be clearly read.
the label must also be securely at-
tached to such outside wrapper or con-
tainer, if it is a part -of the package as
customarily distributed or sold.
(ii) Tank cars and other bulk con-
tainers— < A) Transportation. While a
pesticide product is in transit, the ap-
propriate provisions of 49 CPR Parts
170-189, concerning the transportation
of hazardous materials, and specifical-
ly those provisions concerning the la-
beling. marking and placarding of haz-
ardous materials and the vehicles car-
rying them, define the basic Federal
requirements. In addition, when any
registered pesticide product is trans-
ported in a tank car. tank truck or
other mobile or portable bulk contain-
er, a copy of the accepted label must -
be attached to the shipping papers.
and left with the consignee at the time
of delivery.
(B) Storage. When pesticide prod-
ucts are stored in bulk containers,
whether mobile or stationary, which
remain In the custody of the user, a
copy of the label of labeling, including
all appropriate directions for use. shall
be securely attached to the container
in the immediate vicinity of the dis-
charge control valve.
(5) False or misleading statements.
Pursuant to section 2(q)(lXA) of the
Act, a pesticide or a device declared
subject to the Act pursuant to
J 162.15. is mlsbranded if its labeling is
false or misleading in any particular
including both pesticidal and non-pes-
ticidal claims. Examples of statements
or representations in the labeling
which constitute misbranding include:
(1) A false or misleading statement
concerning the composition of the
(ii) A false or tntelea^ing statement
concerning the effectiveness of the
product as a pesticide or device;
(ill) A false or misleading statement
about the value of the product for
purposes other than as a pesticide or
device;
(iv) A false or ™tei»«^ing comparison
with other pesticides or devices;
(v) Any statement directly or indi-
rectly implying that the pesticide or
device Is recommended or endorsed by
any agency of the Federal Govern-
ment;
(vi) The name of a pesticide which
contains two or more principal active
77
-------
§ 162.10
ingredients if the name suggests one
or more but not all such principal
active ingredients even though the
names of the other ingredients are
stated elsewhere in the labeling;
(vii) A true statement used in such a
way as to give a false or misleading im-
pression to the purchaser;
(viii) Label disclaimers which negate
or detract from labeling statements re-
quired under the Act and these regula-
tions;
(ix) Claims as to the safety of the
pesticide or its ingredients, including
statements such as "safe," "nonpoison-
ous," "noninjurious," "harmless" or
"nontoxic to humans and pets" with
or without such a qualifying phrase as
"when used as directed"; and
(x) Non-numerical and/or compara-
tive statements on the safety of the
product, including but not limited to:
(A) "Contains all natural Ingredi-
ents";
(B) "Among the least toxic chemi-
cals known"
(C) "Pollution approved"
(6) Final printed labeling. (1) Except
as provided in paragraph (a)(6)(ii) of
this section, final printed labeling
must be submitted and accepted prior
to registration. However, final printed
labeling need not be submitted until
draft label texts have been provision-
ally accepted by the Agency.
(ii) Clearly legible reproductions or
photo reductions will be accepted for
unusual labels such as those silk-
screened directly onto glass or metal
containers or large bag or drum labels.
Such reproductions must be of micro-
film reproduction quality.
-------
Environment^ Protection Agency
or endorsement of the product by the
Agency.
(f) Producing establishment regis-
tration number. The producing estab-
lishment registration number preced-
ed by the phrase "EPA Est.". of the
final establishment at which the prod-
uct was produced may appear in any
suitable location on the label or imme-
diate container. It must appear on the
wrapper or outside container of the
package if the EPA establishment reg-
istration number on the immediate
container cannot be clearly read
through such wrapper or container.
(g) Ingredient statement—<1> Gener-
al The label of each pesticide product
must bear a statement which contains
the name and percentage by weight of
each active ingredient, the total per-
centage by weight of all inert ingredi-
ents; and if the pesticide contains ar-
senic in any form, a statement of the
percentages of total and water-soluble
arsenic calculated as elemental ar-
senic. The active ingredients must be
designated by the term "active ingredi-
ents" and the inert Ingredients by the
term "inert ingredients," or the singu-
lar forms of these terms when appro-
priate. Both terms shall be in the
same type size, be aligned to the same
margin and be equally prominent. The
statement "Inert Ingredients, none" is
not required for pesticides which con-
tain 100 percent active ingredients.
Unless the ingredient statement Is a
complete analysis of the pesticide, the
term "analysis" shall not be used as a
heading for the Ingredient statement.
(2) Position of ingredient statement.
(I) The Ingredient statement Is nor-
mally required on the front panel of
the label. If there is an outside con-
tainer or wrapper through which the
Ingredient statement cannot be clearly
read, the ingredient statement must
also appear on such outside container
or wrapper. If the size or form of the
package makes it impracticable to
place the ingredient statement on the
front panel of the label, permission
may be granted for the ingredient
statement to appear elsewhere.
(ii) The text of the ingredient state-
ment must run parallel with other
text on the panel oh which it appears.
and must be clearly distinguishable
§ 162.10
from and must not be placed in the
body of other text.
(3) Names to be used in ingredient
statement. The name used for each in-
gredient shall be the accepted
common name, if there is one, fol-
lowed by the chemical name. The
common name may be used alone only
if it is well known. If no common name
has been established, the chemical
name alone shall be used. In no case
will the use of a trademark or proprie-
tary name be permitted unless such
name has been accepted as a common
name by the Administrator under the
authority of Section 25(c)(6).
(4) Statements of percentages. The
percentages of ingredients shall be
stated in terms of weight-to-weight.
The sum of percentages of the active
and the inert ingredients shall be 100.
Percentages shall not be expressed by
a range of values such as "22-25%." If
the uses of the pesticide product are
expressed as weight of active Ingredi-
ent per unit area, a statement of the
weight of active ingredient per unit
volume of the pesticide formulation
shall also appear in the ingredient
statement.
(5) .Accuracy of stated percentages.
The percentages given shall be as pre-
cise as possible reflecting good manu-
facturing practice. If there may be un-
avoidable variation between manufac-
turing batches, the value stated for
each active ingredient shall be the
lowest percentage which may be
present.
(6) Dstcricrzticr- Pesticides which
change in chemical composition sig-
nificantly must meet the following la-
ding requirements: _
(1) In cases where It is determined
that a pesticide formulation changes
chemical composition significantly.
the product must bear the following
statement in a prominent position on
the label: "Not for sale or use after
[date]."
(11) The product must meet all label
oia
-------
§ 162.10
(h) Warnings and precautionary
statements. Required warnings and
precautionary statements concerning
the general areas of lexicological
hazard including hazard to children,
environmental hazard, and physical or
chemical hazard fall into two groups:
those required on the front panel of
the labeling and those which may
appear elsewhere. Specific require-
ments concerning content, placement.
40 CFR Ch. I (7-1-45 Edition)
type size, and prominence are given
below.
(1) Required front panel statements.
With the exception of the child
hazard warning statement, the text re- /
quired on the front panel of the label'«
Is determined by the Toxicity Categc- ;
ry of the pesticide. The category is as-
signed on the basis of the highest
hazard shown by any of the indicators
in the table below:
^«^
Oral ID*
InhsMton LC_
DsrmalLO..
Eysaftoc*
Skfcl *tort*
ToxfcHy etMQOrtes
1
Up to and induing SO
U|no and (ndutfng 2
mg/Msr.
Up to and toducfrq 200
wttNn7dsys.
II
From 50 ttvu 500 mg/kfl-
From .2 twu 2 mg/IMr —
From 200 thru 2000
Comsat opactty
psrsMfriQ for 7 days.
hours.
HI
From 500 thru 6000 mo/
"0-
Fram 2. thru 20 me/star.
From 2400 fvu 20.000_
No oornaat opacity;
«HMn7days.
Modarala hitaHon at 72
hours.
tv
GmttM tttan 20.000.
NoMlaton.
Md or sight IrrKatton at
72 hours.
(i) Human hazard signal tconi—
-------
Environmental Protection Agency
§162.10
front panel near the word "Poison"
and the skull and crossbones.
(B) Other toxicity categories. The
statement of practical treatment is not
required on the front panel except as
described in paragraph (hXIXiiiXA) of
this section. The applicant may. how-
ever, include such a front panel state-
ment at his option. Statements of
practical treatment are. however, re-
quired elsewhere on the label in
accord with paragraph (h)(2) of this
section if they do not appear on the
front panel.
(iv) Placement and prominence. All
the require front panel warning state-
ments shall ES grouped together on
the label, and shall appear with suffi-
cient prominence relative to other
front panel text and graphic material
to make them unlikely to be over-
looked under customary conditions of
purchase and use. The following table
shows the minimum type size require-
ments for the front panel warning
statements on various sizes of labels:
Size o< Ubel front panel in tquare
incto
5 and undar
Above 5 to 10
Above 10 lo 15 _
Above IS to 30
Over 30
Pa
Requved
«gn4
won). •!
capUH
$
10
12
14
18
nt»
-Keep reacfrof
c**dreo-
6
6
e
10
12
(2) Other required warnings and pre-
cautionary statements. The warnings
and precautionary statements as re-
quired below shall appear together on
the label under the general heading
"Precautionary Statements" and
under appropriate subheadings of
"Hazard to Humans and Domestic Ani-
mals." "Environmental Hazard" and
"Physical or Chemical Hazard."
(1) Hazard to humans and domestic
animals. (A) Where a hazard exists to
humans or domestic animals, precau-
tionary statements are required indi-
cating the particular hazard, the
route(s) of exposure and the precau-
tions to be taken to avoid accident.
injury or damage. The precautionary
paragraph shall be immediately pre-
ceded by the appropriate hazard signal
word.
(B) The following table depicts typi-
cal precautionary statements. These
statements must be modified or ex-
panded to reflect specific hazards.
ToxteHy
category
Precautionary rtatemeott by toadty category
Oral. Inhalation, or dermal toricNy
Skin and eye local effects
Fatal (pofeonoM) V meowed (Muled or absorbed
•vough tun]. Da not broafw vapor (duel or epray
mOU. Do not 0*^ STK. ST. tf-Jn, or on dotting
(front panel aiiiement of
4ay be latal « e*aeo«ed (Inhaled or
ttrough tte eUnl. Oo not breathe vapora (duet or
epray mMl. Oo not get In eyee. art akin, or on
Corroafve. cauaei eye and ttin damage (or tUn
kitaMon]. Oo not get in eyee, on aUn. or on
dotting. Wear gogghM jx !acc cnieid and rubber
tfove»wj»»nhandfcig.HaT^orta«alllevM
-------
§ 162.10
40 CFR Ch. I (7-1-85 Edition)
stances under which they are required
follow:
(A) If a pesticide intended for out-
door use contains an active ingredient
with a mammalian acute oral LD« of
100 or less, the statement "This Pesti-
cide is Toxic to Wildlife" is required.
(B) If a pesticide intended for out-
door use contains an active ingredient
with a fish acute LC« of 1 ppm or less.
the statement "This Pesticide is Toxic
to Pish" is required.
(C) If a pesticide Intended for out-
door use contains an active ingredient
with an avlan acute oral LDM of 100
mg/kg or less, or a subacute dietary
LCM of 500 ppm or less, the statement
"This Pesticide is Toxic to Wildlife" is
required.
(D) If either accident history or field
studies demonstrate that use of the
pesticide may result in fatality to
birds, fish or mammals, the statement
"This pesticide is extremely toxic to
wildlife (fish)" is required.
(E) For uses involving foliar applica-
tion to agricultural crops, forests, or
shade trees, or for mosquito abate-
ment treatments, pesticides toxic to
pollinating insects must bear appropri-
ate label cautions.
(P) For all outdoor uses other than
aquatic applications the label must
bear the caution "Keep out of lakes,
ponds or streams. Do not contaminate
water by cleaning of equipment or dis-
posal of wastes."
(iii) Physical or chemical hazards.
Warning statements on the flammabil-
ity or explosive characteristics of the
pesticide are required as follows:
Flash point
Required text
(A) PRESSURIZED CONTAINERS
Flash point at or below 20* F; t there • a flashback at
any valve opening.
Flash point above 20* F and not over 80' F or if the
(tame extension « more than 18 in long at a distance
of 6 in from the flame.
All other pressurized containers
Extremely flammable. Contents under pressure. Keep away from
fire, sparks, and heated surfaces. Do not puncture or Incinerate
container. Exposure to temperatures above 130* F may cause
bursting.
Flammable. Contents under pressure. Keep away from heat.
sparks, and open flame. Do not puncture or Incinerate container.
Exposure to temperatures above 130* F may cause bunting.
Contents under pressure. Do not use or store near heat or open
flame. Do not puncture or incinerite container. Exposure to
temperatures above 130* F may cause bunting
(B)
CONTAINERS
At or betow 20* F..
Above 20* F and not over 80' F—
Above 80' F and not over 150' F.
Extremely flammable. Keep away from fire, sparks, and heated
surfaces.
Flammable. Keep tway from heat and open flame.
Do not use or store near heat or open flame.
(i) Directions for U*e—{l) General
re
-------
Environmental Protection Agency
§ 162.10
for use only by manufacturers of prod-
ucts other than pesticide products In
their regular manufacturing processes,
provided that:
(1) The label clearly shows that the
product Is intended for use only In
manufacturing processes and specifies
the typeis) of products involved.
(2) Adequate information such as
technical data sheets or bulletins, is
available to the trade specifying the
type of product involved and its
proper use in manufacturing process-
es;
(J) The product will not come into
the hands of the general public except
after incorporationJnto finished prod-
ucts; and
«) The Administrator •determines
that such directions are not necessary
to prevent unreasonable adverse ef-
fects on man or the environment.
(B) Detailed directions for use may
be omitted from the labeling of pesti-
cide products for which sale is limited
to physicians, veterinarians, or drug-
gists, provided that:
(1) The label clearly states that the
product is for use only by physicians
or veterinarians;
(2) The Administrator determines
that such directions are not necessary
to prevent unreasonable adverse ef-
fects on man or the environment; and
(3) The product is.also a drug and
regulated under the provisions of the
Federal Pood, Drug and Cosmetic Act.
(C) Detailed directions for use may
be omitted from the labeling of pesti-
cide products which are Intended for
use only by formiilators In preparing
pesticides for sale to the public, pro
vided that
(1) There Is information readily
available to the formulators on the
composition, toxlcity, methods of use.
applicable restrictions or limitations,
and effectiveness of the product for
pesticide purposes;
(2) The label clearly states that the
product Is Intended for use only in
manufacturing, formulating, mixing,
or repacking for use as a pesticide and
specifies the type<8) of pesticide prod-
ucts involved;
(J) The product as finally manufac-
tured, formulated, mixed, or repack-
aged is registered; and
(4) The Administrator determines
that such directions are not necessary
to prevent unreasonable adverse ef-
fects on man or the environment.
(2) Contents of Directions for Use.
The directions for use shall include
the following, under the headings "Di-
rections for Use":
(i) The statement of use classifica-
tion as prescribed in 162.10(j) immedi-
ately under the heading "Directions
for Use."
(ii) Immediately below the state-
ment of use classification, the state-
ment "It is a violation of Federal law
to use this product in a manner incon-
sistent with its labeling."
(lii) The site(s) of application, as for
example the crops, animals, areas, or
objects to be treated.
(iv) The target pestts) associated
with each site.
(v) The dosage rate associated with
each site and pest.
(vl) The method of application, in-
cluding instructions for dilution. If re-
quired, and type
-------
§ 162.11
40 CFR Ch. I (7-l-«5 Edition)
(E) For restricted use pesticides, a
statement that the pesticide may be
applied under the direct supervision of
a certified applicator who is not phys-
ically present at the site of application
but nonetheless available to the
person applying the pesticide, unless
the Agency has determined that the
pesticide may only be applied under
the direct supervision of a certified ap-
plicator who is physically present.
(P) Other pertinent information
which the Administrator determines
to be necessary for the protection of
man and the environment.
(j) Statement of Use Classification.
By October 22. 1976. all pesticide prod-
ucts must bear on their labels a state-
ment of use classification as described
in paragraphs (j) (1) and (2) of this
section. Any pesticide product for
which some uses axe classified for gen-
eral use and others for restricted use
shall be separately labeled according
to the labeling standards set forth in
this subsection, and shall be marketed
as separate products with differen-
registration numbers, one bearing di-
rections only for general use(s) and
the other bearing directions for re-
stricted use(s) except that, if a product
has both restricted use(s) and general
use(s), both of these uses may appear
on a product labeled for restricted use.
Such products shall be subject to the
provisions of 5 162.10(j)(2).
(1) General Use Classification. Pesti-
cide products bearing directions for
use(s) classified general shall be la-
beled with the exact words "General
Classification" immediately below the
heading "Directions for Use." And ref-
erence to the general classification
that suggests or implies that the gen-
eral utility of the pesticide extends
beyond those purposes and uses con-
tained in the Directions for Use will be
considered a false or misleading state-
ment under the statutory definitions
of misbranding.
(2) Restricted Use Classification.
Pesticide products bearing direction
for useXs) classified restricted shall
bear statements of restricted use clas-
sification on the front panel as de-
scribed below:
(1) Front panel statement of restrict-
ed use classification. (A) At the top of
the front panel of the label, set in type
of the same minimum sizes as required
for human hazard signal words (see
table in ( 162.10(h)(l)(iv)). and appear-
ing with sufficient prominence relative
to other text and graphic material on
the front panel to make it unlikely to
be overlooked under customary condi-
tions of purchase and use, the state-
ment "Restricted Use Pesticide" shall
appear.
(B) Directly below this statement on
the front panel, a summary statement
of the terms of restriction imposed as
a precondition to registration shall
appear. If use is restricted to certified
applicatorc. the following statement is
required: "For retail sale to and use
only by Certified Applicators or per-
sons under their direct supervision arid
only for those uses covered by the Cer-
tified Applicator's certification." If,
however, other regulatory restrictions
are imposed, the Administrator will
define the appropriate wording for the
terms of restriction by regulation.
(k) Advertising. [Reserved]
[40 PR 28268. July 3, 1975: 40 PR 32329.
Aug. 1. 1975: 40 PR 36571. Aug. 21. 1975, as
amended at 43 PR 5786, Feb. 9,1978]
84
-------
Criteria
PHYS/CHEM-1
PHYSICAL/CHEMICAL HAZARDS
Required Label Statement
I. Pressurized Containers
A. Flashpoint at or below
20°F; or if there is a
flashback at any valve
opening.
B. Flashpoint above 20°F
and not over 80°F; or
if the flame extension
is more than 18 inches
long at a distance of
6 inches from the
valve opening.
C. All Other Pressurized
Containers
II. Non-Pressurized Containers
A. Flashpoint at or below
20°F.
B. Flashpoint above 20°P
and not over 80°F.
C. Flashpoint over 80°F
and not over 150°F.
D. Flashpoint above
150°F.
Extremely flammable.
Contents under pressure.
Keep away from fire, sparks,
and heated surfaces. Do not
puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Flammable. Contents under
pressure. Keep away from
heat, sparks, and flame. Do
not puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Contents under pressure.
Do not use or store near
heat or open flame. Do not
puncture or incinerate
container. Exposure to
temperatures above 130°F
may cause bursting.
Extremely flammable. Keep
away from fire, sparks, and
heated surfaces.
Flammable. Keep away from
heat and open flame.
Do not use or store near
heat and open flame.
None required.
85
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STOR-1
STORAGE INSTRUCTIONS FOR PESTICIDES
Heading;
All products are required to bear specific label instructions
about storage and disposal. Storage and disposal instructions
must be grouped together in the directions for use portion of
the label under the heading STORAGE AND DISPOSAL. Products
intended solely for domestic use need not include the heading
"STORAGE AND DISPOSAL."
Storage Instructions;
All product labels are required to have appropriate storage
instructions. Specific storage instructions are not prescribed.
Each registrant must develop his own storage instructions,
considering, when applicable, the following factors:
1. Conditions of storage that might alter the composition or
usefulness of the pesticide. Examples could be temperature
extremes, excessive moisture or humidity, heat, sunlight,
friction, or contaminating substances or media.
2. Physical requirements of storage which might adversely
affect the container of the product and its ability to
continue to function properly. Requirements might include
positioning of the container in storage, storage or damage
due to stacking, penetration of moisture, and ability to
withstand shock or friction.
3. Specifications for handling the pesticide container,
including movement of container within the storage area,
proper opening and closing procedures (particularly for
opened containers), and measures to minimize exposure
while opening or closing container.
4. Instructions on what to do if the container is damaged in
any way, or if the pesticide is leaking or has been
spilled, and precautions to minimize exposure if damage occurs
5. General precautions concerning locked storage, storage in
original container only, and separation of pesticides
during storage to prevent cross-contamination of other
pesticides, fertilizer, food, and feed.
6. General storage instructions for household products should
emphasize storage in original container and placement in
locked storage areas.
86
-------
CONT/DIS-1
CONTAINER DISPOSAL INSTRUCTIONS
The label of each product must bear container disposal
instructions appropriate to the type of container.
1. Domestic use products must bear one of the following
container disposal statements:
Container Type
Statement
Non-aerosol products
(bottles, cans, jars)
Non-aerosol products
(bags)
Aerosol products
Do not reuse container (bottle, can, jar).
Rinse thoroughly before discarding in trash.
Do not reuse bag. Discard bag in trash.
Replace cap and discard containers in
trash. Do not incinerate or puncture.
2. All other products must bear container disposal instructions,
based on container type,listed below:
Container Type
Statement
Metal
containers
( non-aerosol)
Plastic containers
Glass containers
Fiber drums
with liners
Paper and
plastic bags
Compressed gas
cylinders
Triple rinse (or equivalent). Then offer
for recycling or reconditioning, or puncture
and dispose of in a sanitary landfill, or by
other procedures approved by state and local
authorities.
Triple rinse (or equivalent). Then offer
for recycling or reconditioning, or puncture
and dispose of in a sanitary landfill, or
incineration, or, if allowed by state and
local authorities, by burning. If burned,
stay out of smoke.
Triple rinse (or equivalent). Then dispose
of in a sanitary landfill or by other
approved state and local procedures.
Completely empty liner by shaking and
tapping sides and bottom to loosen clinging
particles. Empty residue into application
equipment. Then dispose of liner in a
sanitary landfill or by incineration if
allowed by state and local authorities.
If drum is contaminated and cannot be
reused^, dispose of in the same manner.
Completely empty bag into application
equipment. Then dispose of empty bag in
a sanitary landfill or by incineration,
or, if allowed by State and local
authorities, by burning. If burned, stay
out of smoke.
Return empty cylinder for reuse (or
similar wording)
I/ Manufacturer may replace this phrase with one indicating
whether and how fiber drum may be reused.
87
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APPENDIX III
USE INDEX APPENDIX
-------
:02270
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
TYPE PESTICIDE! Fungicide
FORMULATIONS;
F1C (0.77 Ib/gal or 8X)
SC/L (0.77 Ib/gal or 8Z, 0.784 Ib/gal or 8X, 0.934 Ib/gal or 10%)
GENERAL WARNINGS AND LIMITATIONS; Apply immediately after preparation.
May be corrosive to aluminum, brass, bronze and copper after long periods
of contact. Dosage rates and formulations are given in metallic copper
equivalent.
Definition of Terast
MAI - Multiple active ingredient.
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s>
TERRESTRIAL FOOD CROP
(Agricultural Crops)
General Warnings and Limitations! With dilute ground equipment, apply
specified rate in 10 to 60 gallons of water per acre for vegetable or
field crops, or 100 to 800 gallons per acre for orchards (use 500 to
2,000 gallons for citrus). For concentrate spraying, apply In not less
than 5 gallons per acre or 20 to 100 gallons per acre for orchards.
Apply 3 to 20 gallons per acre by aircraft.
/03001AA Almond
FBADMCB Brown rot blossom
and twig blight
(Monilinia)
1.54-2.31
Ib/A
or
1.54-2.31 lb/
100 gal
(0.77 Ib/gal
or 8% SC/L)
Exempt
Do not apply later than bud swell
through 2.31 pounds per 100 gallons.
Delayed dormant application. Apply
at bud swell stage. Dormant oil may
be used*
Issued: 7-22-85
II-022703-1
89
-------
/05001AA
FBADMCB
/28001AA
FBAAXAA
FBARPDZ
/28073AA
FBAMCBM
FBASAAX
Site and Pest
Apricot
Brown rot blossom
and twig blight
(Monilinia)
Beans
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
Do not apply later than jacket fall
through 2.31 pounds per 100 gallons,
1.54-2.31 Delayed dormant and foliar applica-
Ib/A tion. Apply at red bud to jacket
or fall stage.
1.54-2.31 lb/
100 gal
(0.77 Ib/gal
or 82 9C/L)
Exempt
No preharvest interval through 0.5Q
pound per acre.
Bacterial (common)
blight
(Xanthomonas)
Bacterial halo
blight
(Pseudomonas)
Carrots
Early blight
(Cercospora)
Late blight
(Alternaria)
0.26-0.58 Foliar application. Apply when
lb/A plants are 3 to 5 inches high and
(0.77 Ib/gal before disease appears. Repeat at
or 82 SC/L) 7 to 10 day intervals or 5 to 7 days
(0.934 Ib/gal under severe conditions.
or 10% SC/L) OR MAI
Formulated with sulfur.
—OR MAI—
0.26-0.58
lb/A
(0.77 Ib/gal
or 82 F1C)
Exempt
No preharvest interval through 0.5Q
pound per acre.
0.26-0.58 Foliar application. Apply when
lb/A plants are 6 inches high. Apjly 3
(0.77 Ib/gal to 10 tinea at 7 to 10 day Inter-
or 82 SC/L) vals.
(0.934 Ib/gal OR MAI
or. 102 SC/L) Formulated with sulfur.
—OR MAI--
0.26-0.58
lb/A
(0.77 Ib/gal
or 82 F1C)
Issued: 7-22-85
II-022703-2
90
-------
EPA Index to Pesticide Chemicals
/28003AA
FBAMCBM
FBASSBL
Site and Pest
Celery
Early blight
(Cercospora)
Late blight
(Septoria)
/02000AA
FMAYMCA
Citrus Fruits
Greasy spot
(Mycosphaerella)
FIBLDAP
Melanoae
(Diaporthe)
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply 4 to 7
Ib/A times at weekly intervals.
(0.77 Ib/gal OR MAI
or 3Z SC/L) Formulated with sulfur.
(0.934 Ib/gal
or 10Z SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z F1C)
Exempt
Apply through 3.85 pounds per acre
in accordance with directions below,
1.28-2.31
Ib/A
or
0.58-0.776
lb/500 gal
(0.77 Ib/gal
or 8Z SC/L)
or
0.098 lb/15
gal
(0.784 Ib/gal
or 8Z SC/L)
or
1.925-3.85
Ib/A
(0.77 Ib/gal
or 8Z SC/L)
1.925-3.85
Ib/A
or
0.58-0.776
lb/500 gal
(0.77 Ib/gal
or 8% SC/L)
or
Use limited to FL.
Foliar application. Apply at post-
bloom and within 1 month after any
leaf expansion of any growth flush,
Do not apply with oil.
Foliar application. Apply 1 to 3
weeks after bloom. Dosage rate
depends upon disease severity*
Issued: 7-22-85
11-022703-3
-------
Site and Pest
FAABEAH
/10000AA
FBATAAX
FMABPDZ
FFABPEA
FFACEBJ
FEAJCCV
/01014AA
FEAAEAH
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Citrus Fruits (continued)
Scab (spot anthrac-
nose) (Elsinoe)
0.47 Ib/A
(0.934 Ib/gal
or 10Z SC/L)
0.58-0.77 lb/
500 gal
or
2.31-3.08
Ib/A -
[aircraft]
(0.77 Ib/gal
or 8X SC/L)
Foliar application. Make 2 applica-
tions. Apply just before the trees
begin to flush and again when two-
thirds of the petals have fallen.
Cucurbits (Cantaloupe, Cucumber,
Melons, Squash)
Alternaria leaf
blight
Angular leaf spot
(Pseudomonas)
Downy mildew
(Pseudoperon-
ospora)
Powdery mildew
(Erysiphe)
Scab
(Cladosporium)
Grapes
Anthracnose
(Elsinoe)
Exempt
No preharvest interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply beginning
Ib/A after vining (or after emergence for
(0.77 Ib/gal melons) and repeat until midharvest.
or 8Z SC/L) Be certain to spray underside of
(0.934 Ib/gal leaves.
or 10Z SC/L) OR MAI
or Formulated with sulfur.
0.098 lb/15
gal
(0.784 Ib/gal
or 82 SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z F1C)
Exempt
2 week preharvest Interval through
0.58 pound per acre. Add 4 pounds
of hydrated lime to all sprays.
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z SC/L)
or
Foliar application. Apply when
leaves first appear, Just after
blooming, and then at 2 week inter-
vals.
OR MAI
Formulated with sulfur.
Issued: 7-22-85
II-022703-4
92
-------
Site and Pest
Grapes (continued)
FIBPGBG
FFABPCV
/05003AA
/05004AA
Black rot
(Guignardia)
Downy mildew
(Plasmopara)
Nectarine
Peach
FBADMCB Brown rot blossom
and twig blight
(Monilinia)
FEAGTAB Leaf curl
(Taphrina)
Peach
'28015AA Peanuts
rMBCCBM Cercospora leaf
spot
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z F1C)
0.47 Ib/A Foliar application. Apply when
(0.934 Ib/gal leaves first appear, before blossoms
or 10X SC/L) open, after petal fall, and at 2
week intervals.
Exempt
Do not apply at or after full bloom
through 2.31 pounds per acre.
1.54-2.31 Dormant or delayed dormant applica-
Ib/A tlon. May be applied with dormant
(0.77 Ib/gal oil.
or 81 SC/L)
1.54-2.31 Dormant application. Apply at leaf
Ib/A fall or before bud swell.
(0.77 Ib/gal
or 8Z SC/L)
See Nectarine cluster.
Exempt
No preharvest Interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply when dis-
Ib/A ease appears. Apply 4 to 8 times
(0.77 Ib/gal at 10 to 14 day Intervals.
or 8% SC/L) OR MAI
(0.934 Ib/gal Formulated with sulfur.
or 10% SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8* F1C)
Issued: 7-22-85
II-022703-5
93
-------
/28017AA
FMAAXAA
FMBCCBM
Site and Pest
Peppers
Bacterial spot
(Xanthomonas)
Leaf spot
(Cercospora)
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 0.58
pound per acre.
/14013AA
FBAMAAX
FBASPCN
Potato
Early blight
(Alternaria)
Late blight
(Phytophthora)
/28023AA
FBAAPDZ
Soybeans
Bacterial blight
(Pseudomonas)
Foliar application. Apply at emer-
gence in plant beds or before the
disease appears* Apply in the field
after transplanting or emergence.
Repeat at 7 to 10 day intervals or
at 4 to 5 days if disease is severe.
OR MAI
Formulated with sulfur.
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8X SC/L)
(0.934 Ib/gal
or 10X SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z F1C)
Exempt
No preharvest Interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply when or
Ib/A before disease appears. Apply 4 to
(0.77 Ib/gal 6 times at 7 to 10 day intervals.
or 8Z SC/L) OR MAI
(0.934 Ib/gal Formulated with sulfur.
or 10* SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8% F1C)
Exempt
No preharvest interval through 0.51
pound per acre.
0.34-0.51 Foliar application. Apply when
Ib/A plants are 3 to 5 inches high and
(0.77 Ib/gal before disease appears. Repeat at
or 81 SC/L) 7 to 10 day intervals or 5 to 7 days
(0.934 Ib/gal when- severe conditions are present.
or 10% SC/L)
Issued: 7-22-85
II-022703-6
94
-------
/01016AA
FMBCMCO
FGAKDBS
Site and Pest
Strawberry
Leaf spot
(Mycosphaerella)
Leaf scorch
(Diplocarpon)
/28020AA
FMBCCBM
Sugar Beets
Leaf spot
(Cercospora)
!/11005AA
FMAAXAA
FBAMAAX
FBASPCN
Tomato
Bacterial spot
(Xanthomonas)
Early blight
(Alternaria)
Late blight
(Phytophthora)
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 0.58
pound per acre.
0.26-0.58 Delayed dormant and foliar applica-
Ib/A tion. Apply as soon as new growth
(0.77 Ib/gal starts and repeat at 7 to 10 day
or 8Z SC/L) intervals.
(0.934 Ib/gal OR MAI
or 10Z SC/L) Formulated with sulfur.
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8Z F1C)
Exempt
No preharvest interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply when dis-
Ib/A ease appears. Apply 3 to 6 times
(0.77 Ib/gal at 10 to 14 day intervals.
or 8X SC/L) OR MAI
(0.934 Ib/gal Formulated with sulfur.
or 10Z SC/L)
—OR MAI—
0.26-0.58
Ib/A
(0.77 Ib/gal
or 8% F1C)
Exempt
No preharvest interval through 0.58
pound per acre.
0.26-0.58 Foliar application. Apply in plant
Ib/A beds at emergence at 4 to 5 day
(0.77 Ib/gal intervals. In field begin immedi-
or 8X SC/L) ately after transplanting or emer-
(0.934 Ib/gal gence. In areas where the disease
or 10% SC/L) is less severe, the interval can be
or 5 to 7 days.
OR MAI
Formulated with sulfur.
Issued: 7-22-85
II-022703-7
95
-------
Site and Pest
Tomato (continued)
/03009AA
FBAAXAA
Walnut
Walnut blight
(Xanthomonas)
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
0.098 lb/15
gal
(0.784 Ib/gal
or 8Z SC/L)
—OR MAI—
0.26-0.58
Ib/A -
(0.77 Ib/gal
or 81 F1C)
Exempt
No preharvest interval through 2.31
pound per acre.
1.925-2.31 Delayed dormant and foliar applica-
Ib/A tion. Apply at early preblooa and
(0.77 Ib/gal again at late prebloom. Additional
or 8Z SC/L) applications can be made if the dis-
ease persists.
AERIAL AND TANK MIX APPLICATION
9001500
AAAAAAA
Aerial Application
Refer to
TERRESTRIAL FOOD CROP
(Agricultural Crops)
All Sites
Issued: 7-22-85
II-022703-8
96
-------
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Listing of Registered Pesticide Products by Formulation
&208.0002 8% formulation intermediate
copper ammonium carbonate (022703)
010143-00002
&208.0014 8* (0.77 Ib/gal) flovable concentrate
copper ammonium carbonate (022703) plus sulfur (077501))
007001-00334 010465-00002 010465-00004 010659-00013
&208.0015 8% (0.77 Ib/gal) soluble concentrate/liquid
copper ammonium carbonate (022703)
007001-00251 009159-00088 010465-00001 010465-00003
&208.0015 8Z (0.784 Ib/gal) soluble concentrate/liquid
copper ammonium carbonate (022703)
000557-01883
4210.0015 IPS (0.934 Ib/gal) soluble concentrate/liquid
copper ammonium carbonate (022703)
011503-00001
Issued: 7-22-85 II-022703-9
97
-------
/0300LAA
FBADMCB
/0500LAA
FBADMCB
/2800LAA
FBAAXAA
FBARPDZ
/28073AA
FBAMCBM
FBASAAX
/28003AA
FBAMCBM
FBASSBL
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Almond
Brown rot blossom and twig blight (Monilinia)
(0.77 Ib/gal or 8% SC/L)
007001-00251 010465-00003
Apricot
Brown rot blossom and twig blight (Monilinia)
(0.77 Ib/gal or 8X SC/L)
007001-00251 010465-00003
Beans
Bacterial (common) blight (Xanthomonas)
Bacterial halo blight (Pseudomonas)
(0.77 Ib/gal or 8X F1C)
007001-00334 010465-00002 010465-00004
(0.77 Ib/gal or 8X SC/L)
• 007001-00251 009159-00088
(0.934 Ib/gal or 10% SC/L)
011503-00001
Carrots
Early blight (Cercospora)
Late blight (Alternaria)
(0.77 Ib/gal or 8* F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8Z SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10Z SC/L)
011503-00001
Celery
Early blight (Cercospora)
Late blight (Septoria)
(0.77 Ib/gal or 82 F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8Z SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10Z SC/L)
011503-00001
Issued: 7-2..-S5
010465-00001 010465-00003
010465-00004
010465-00001 010465-00003
010465-00004
010465-00001
010465-00003
11-022703-10
-------
/02000AA
FMAYMCA
FIBLDAP
FAABEAH
/10000AA
FBATAAX
FMABPDZ
FFABPEA
FFACEBJ
FEAJCCV
/01014AA
FEAAEAH
FIBFGBG
FFABPCV
/05003AA
FBADMCB
FEAGTAB
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Citrus Fruits
Greasy spot (Mycosphaerella)
Melanose (Diaporthe)
Scab (spot anthracnose) (Elsinoe)
(0.77 Ib/gal or 8% SC/L)
007001-00251 010465-00001 010465-00003
(0.784 Ib/gal or 8% SC/L)
000557-01883
(0.934 Ib/gal or 10% SC/L)
011503-00001
Cucurbits (Cantaloupe, Cucumber, Melons, Squash)
Alternaria leaf blight
Angular leaf spot (Pseudomonas)
Downy mildew (Pseudoperonospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
(0.77 Ib/gal or 8% F1C)
007001-00334 010465-00002 010465-00004
010465-00001 010465-00003
(0.77 Ib/gal or 8% SC/L)
007001-00251 009159-00088
(0.784 Ib/gal or 8% SC/L)
000557-01883
(0.934 Ib/gal or 10% SC/L)
011503-00001
Grapes
Anthracnose (Elsinoe)
Black rot (Guignardia)
Downy mildew (Plasmopara)
(0.77 Ib/gal or 8Z F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8% SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10% SC/L)
011503-00001
Nectarine
Brown rot blossom and twig blight (Monilinia)
Leaf curl (Taphrina)
(0.77 Ib/gal or 8% SC/L)
007001-00251 010465-00003
010465-00004
010465-00001 010465-00003
Issued: 7-22-85
11-022703-11
-------
/05004AA
FBADMCB
FEAGTAB
/28015AA
FMBCCBM
/28017AA
FMAAXAA
FMBCCBM
/14013AA
FBAMAAX
FBASPCN
/28023AA
FBAAPDZ
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Peach
Brown rot blossom and twig blight (Monilinia)
Leaf curl (Taphrina)
(0.77 Ib/gal or 8Z SC/L)
007001-00251 010465-00003
Peanuts
Cercospora leaf spot
(0.77 Ib/gal or 8Z F1C)
007001-00334 010465-00002 - 010465-00004
010659-00013
(0.77 Ib/gal or 8Z SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10Z SC/L)
011503-00001
Peppers
Bacterial spot (Xanthomonas)
Leaf spot (Cercospora)
(0.77 Ib/gal or 8Z F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8Z SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10Z SC/L)
011503-00001
Potato
Early blight (Alternaria)
Late blight (Phytophthora)
(0.77 Ib/gal or 8Z F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8Z SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10Z SC/L)
011503-00001
Soybeans
Bacterial blight (Pseudomonas)
(0.77 Ib/gal or 8Z SC/L)
007001-00251 010465-00003
(0.934 Ib/gal or 10Z SC/L)
011503-00001
010465-00001 010465-00003
010465-00004
010465-00001 010465-00003
010465-00004
010465-00001 010465-00003
Issued: 7-22-85
II-02270J-12
100
-------
/01016AA
FMBCMCO
FGAKDBS
/28020AA
FMBCCBM
/11005AA
FMAAXAA
FBAMAAX
FBASPCN
/03009AA
FBAAXAA
EPA Index to Pesticide Chemicals
COPPER AMMONIUM CARBONATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Strawberry
Leaf spot (Mycosphaerella)
Leaf scorch (Diplocarpon)
(0.77 Ib/gal or 8% F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8% SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10* SC/L)
011503-00001
Sugar Beets
Leaf spot (Cercospora)
(0.77 Ib/gal or 8Z F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 8* SC/L)
007001-00251 009159-00088
(0.934 Ib/gal or 10% SC/L)
011503-00001
Tomato
Bacterial spot (Xanthomonas)
Early blight (Alternaria)
Late blight (Phytophthora)
(0.77 Ib/gal or 8% F1C)
007001-00334 010465-00002
(0.77 Ib/gal or 82 SC/L)
007001-00251 009159-00088
(0.784 Ib/gal or 8X SC/L)
000557-01883
(0.934 Ib/gal or 10% SC/L)
011503-00001
Walnut
Walnut blight (Xanthomonas)
(0.77 Ib/gal or 8% SC/L)
007001-00251 010465-00003
010465-00004
010465-00001 010465-00003
010465-00004
010465-00001 010465-00003
010465-00004
010465-00001 010465-00003
Issued: 7-22-85
11-022703-13
101
-------
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AM AMMONIA COMPLEX)
TYPE PESTICIDE; Fungicide
FORMULATIONS;
SC/L (0.8Z, 0.8 Ib/gal or 8Z)
RTU (4.3Z)
GENERAL WARNINGS AND LIMITATIONS; Avoid contact with skin and eyes. In
case of skin contact, remove with washing; for eyes, wash with copious
amounts of water and get immediate medical attention.
Dosages and formulations are given in metallic copper equivalent.
Agricultural Crop Tolerances; Exempt
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s)
TERRESTRIAL FOOD CROP
(Agricultural Crops)
General Warnings and Limitations; For dilute, high volume sprays, use
from 25 to 100 gallons per acre. For concentrate ground sprays, apply
20 to SO gallons per acre. For aerial spraying, use 3 to 15 gallons
per acre.
/28001AA Beans
FBAFXAV Bacterial blight
(common)
(Xanthomonas)
FBZRPGG Halo blight
(Pseudomonas)
0.264-0.6
Ib/A
(0.8 Ib/gal
or 8Z SC/L)
/10002AA . Cantaloupe
/10005AA Honeydew Melons
/10006AA Muskmelons
/10008AA Watermelons
FBAAAAX Alternaria blight
FMABPDZ Angular leaf spot
(Pseudomonas)
FFABPEA Downy mildew
(Pseudoperono-
spora)
FFACSCO Powdery mildew
(Sphaerotheca)
FEAJCCV Scab (Cladosporium)
Issued: 7-22-85
0.264-0.6
Ib/A
(0.8 Ib/gal
or 82 SC/L)
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
Foliar application. Make first ap-
plication when plants are 3 to 5
inches high before disease symptoms
appear. Continue applications on a
7 to 10 day schedule, depending on
local conditions.
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
Foliar application. Apply when
plants begin to vine. Continue ap-
plications on a weekly basis. In
areas where angular leaf »pot is a
problem, applications should be
made on a 5 to 7 day schedule.
II-022702-1
102
-------
/28003AA
FBZAPDZ
FBAMCBM
FBASSBL
/10010AA
/10013AA
/10014AA
FBAAAAX
FMABPDZ
FFACSCO
/28015AA
FMBCCBM
/28017AA
FMZAXAA
FMBCCBM
Site and Pest
Celery
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Dosages and Tolerance. Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
Bacterial blight
(Pseudomonas)
Early blight
(Cercospora)
Late blight
(Septoria)
Cucumber
Squash ^Summer)
Squash (Winter)
Alternaria blight
Angular leaf spot
(Pseudononas)
Powdery mildew
(Sphaerotheca)
Honeydew Melons
Muskmelons
Peanuts
Cercospora leaf
spot
Peppers
Bacterial spot
(Xanthomonas)
Cercospora leaf
spot
0.264-0.6
Ib/A
(0.8 Ib/gal
or 81 SC/L)
0.264-0.6 Foliar application. Begin applica-
Ib/A tion when plants are first estab-
(0.8 Ib/gal lished, then every 7 days depending
or 82 SC/L) on disease conditions.
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
Foliar application. Apply when
plants begin to vine. Continue ap-
plications on a weekly basis. In
areas where angular leaf spot is a
problem, applications should be
made on a 5 to 7 day schedule.
See Cantaloupe cluster.
See Cantaloupe cluster.
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
0.264-0.6 Foliar application. Apply at the
lb/A first sign of disease and every 10
(0.8 Ib/gal to 14 days thereafter.
or 81 SC/L)
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
0.264-0.6 Foliar application. Apply before
lb/A disease appears and continue at 7
(0.8 Ib/gal to 10 day intervals.
or 8X SC/L)
Issued: 7-22-85
II-022702-2
103
-------
/14013AA
Site and Peat
Potato
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
FBAMAAX
FBASPCN
/28023AA
FBZAPDZ
Early blight
(Alternaria)
Late blight
(Phytophthora)
Soybeans
Bacterial blight
(Pseudomonas)
/28020AA
FMBCCBM
Squash (Summer)
Squash (Winter)
Sugar Beets
Cercospora leaf
spot
/11005AA
FMZAXBA
FBAMAEP
Tomato
Bacterial spot
(Xanthomonas)
Early blight
(Alternaria)
0.376-0.48
Ib/A
(0.8 Ib/gal
or 8Z SC/L)
0.264-0.6 Foliar application. Begin applica-
Ib/A tion when plants are 3 to 4 inches
(0.8 Ib/gal high and continue at 7 to 10 day
or 8Z SC/L) intervals.
Exempt
No preharvest interval through 0.48
pound copper (metallic equivalent)
per acre.
Foliar application. Make first ap-
plication when plants are 3 to 5
inches high before disease symptoms
appear. Continue applications on a
7 to 10 day schedule, depending on
local conditions.
See Cucumber cluster.
See Cucumber cluster.
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
0.264-0.6 Foliar application. Apply when
Ib/A plants are 3 to 4 inches high and
(0.8 Ib/gal continue on a 10 to 14 day interval
or 8Z SC/L) or more frequent if disease condi-
tions are severe.
Exempt
No preharvest interval through 0.6
pound copper (metallic equivalent)
per acre.
0.264-0.6
Ib/A
(0.8 Ib/gal
or 8Z SC/L)
Foliar application. In seed beds,
begin applications when seedlings
emerge and repeat at 4 to 5 day in-
tervals. In field, begin applica-
tions immediately after transplant-
ing and continue on 7 day intervals
or more frequently if disease con-
ditions are severe.
Issued: 7-22-85
II-022702-3
104
-------
EPA Index to Pesticide Chemicals
/03009AA
Site and Pest
Walnut
FBZAXAA
Walnut blight
(Xanthomonaa)
Watermelons
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Dosages and Tolerance, Use, Limitations
Formulation( s)
Exempt
No preharvest interval through 2.4
pounds copper (metallic equivalent)
per acre.
Delayed dormant and foliar applica-
tion. Make first and second appli-
cations at early and late prebloom
respectively. If disease conditions
persist, make additional applica-
tions .
See Cantaloupe cluster.
2.0-2.4 Ib/A
(0.8 Ib/gal
or 8Z SC/L)
/31065AA
/3U29AA
/3LL21AA
/31156AA
/34120AA
/31197AA
FFACQBB
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Chrysanthemum
Delphinium
Hollyhock
Phlox
Rose
Sweet Pea
Powdery mildew
2.0 tbls 0.8% Foliar application. Apply spray to
SC/L/gal upper and lower surfaces of the
(0.8Z SC/L) foliage every 3 to 5 days depending
on the severity of infection. Re-
peat after rains. Apply every 10
days as a preventive treatment. For
phlox, apply from early growth until
bloom.
/64002NA
F7AEQBB
INDOOR
(Wood or Wood Structure Protection Treatments)
Wood Protection Treatment (Seasoned
Forest Products)
Wood rot/decay —
(4.3Z RTU)
Wood protection treatment. Apply
several coats with brush or rag mop
to all surfaces of previously pres-
sure treated lumber exposed by cut-
ting, notching, and dapping.
Formulated with ammonium arsenate.
Issued: 7-22-85
II-022702-4
105
-------
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Site and Pest Dosages and Tolerance. Use, Limitations
FormulationC s)
AERIAL AND TANK MIX APPLICATIONS
9001500 Aerial Application
AAAAAAA
— Refer to
TERRESTRIAL FOOD CROP
""{Agricultural Crops)
All Sites
Issued: 7-22-85 II-022702-5
106
-------
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OP AN AMMONIA COMPLEX)
Listing of Registered Pesticide Products by Formulation
4200.8015 0.8Z soluble concentrate/liquid
copper (In the fora of an ammonia complex) (022702)
000358-00121
4208.0015 81 (0.8 Ib/gal) soluble concentrate/liquid
copper (in the form of an ammonia complex) (022702)
008901-00014
4204.3016 4.31 liquid-ready to use
—copper (in the form of an ammonia complex) (022702) plus ammonium arse-
nate (013601)
003098-00003 011351-00001
Issued: 7-22-85 II-022702-6
107
-------
EPA Index to Pesticide Cheaicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
/28001AA Beans
FBZFXAV Bacterial blight (common) (Xanthomonas)
FBZRPGG Halo blight (Pseudomonas)
(0.8 Ib/gal or 82 SC/L)
(0.8 Ib/gal or 82 SC/L)
008901-00014
/10002AA Cantaloupe
FBAAAAX Alternaria blight
FMABPDZ Angular leaf spot (Pseudomonas)
FFABPEA Downy mildew (Pseudoperonospora)
FFACSCO Powdery mildew (Sphaerotheca)
FEAJCCV Scab (Cladosporium)
(0.8 Ib/gal or 82 SC/L)
008901-00014
/28003AA Celery
FBZAPDZ Bacterial blight (Pseudomonas)
FBAMCBM Early blight (Cercospora)
FBASSBL Late blight (Septoria)
(0.8 Ib/gal or 82 SC/L)
008901-00014
/10010AA Cucumber
FBAAAAX Alternaria blight
FMABPDZ Angular leaf spot (Pseudomonas)
FFACSCO Powdery mildew (Sphaerotheca)
(0.8 Ib/gal or 82 SC/L)
008901-00014
/10005AA Honeydew Melons
FBAAAAX Alternaria blight
FMABPDZ Angular leaf spot (Pseudomonas)
FFABPEA Downy mildew (Pseudoperonospora)
FFACSCO Powdery mildew (Sphaerotheca)
FEAJCCV Scab (Cladosporium)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Issued: 7-22-85
II-022702-7
108
-------
/10006AA
FBAAAAX
FMABPDZ
FFABPEA
FFACSCO
FEAJCCV
/28015AA
FMBCCBM
/28017AA
FMZAXAA
FMBCCBM
/14013AA
FBAMAAX
FBASPCN
/28023AA
FBZAPDZ
/10013AA
FBAAAAX
FMABPDZ
FFACSCO
/10014AA
FBAAAAX
FMABPDZ
FFACSCO
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Muskmelons
Alternaria blight
Angular leaf spot (Pseudomonas)
Downy mildew (Pseudoperonospora)
Powdery mildew (Sphaerotheca)
Scab (Cladosporium)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Peanuts
Cercospora leaf spot
(0.8 Ib/gal or 8% SC/L)
008901-00014
Peppers
Bacterial spot (Xanthomonas)
Cercospora leaf spot
(0.8 Ib/gal or 82 SC/L)
008901-00014
Potato
Early blight (Alternaria)
Late blight (Phytophthora)
(0.8 Ib/gal or 8% SC/L)
008901-00014
Soybeans
Bacterial blight (Pseudomonas)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Squash (Summer)
Alternaria blight
Angular leaf spot (Pseudomonas)
Powdery mildew (Sphaerotheca)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Squash (Winter)
Alternaria blight
Angular leaf spot (Pseudomonas)
Powdery mildew (Sphaerotheca)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Issued: 7-22-85
II-022702-8
109
-------
/28020AA
FMBCCBM
/11005AA
FMZAXBA
FBAMAEP
/03009AA
FBZAXAA
/10008AA
FBAAAAX
FMABPDZ
FFABPEA
FFACSCO
FEAJCCV
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AM AMMONIA COMPLEX)
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Sugar Beets
Cercospora leaf spot
(0.8 Ib/gal or 82 SC/L)
008901-00014
Tomato
Bacterial spot (Xanthomonas)
Early blight (Alternaria)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Walnut
Walnut blight (Xanthomonas)
(0.8 Ib/gal or 82 SC/L)
008901-00014
Watermelons
Alternaria blight
Angular leaf spot (Pseudomonas)
Downy mildew (Pseudoperonospora)
Powdery mildew (Sphaerotheca)
Scab (Cladosporium)
(0.8 Ib/gal or 82 SC/L)
008901-00014
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
/31065AA Chrysanthemum
FFACQBB Powdery mildew
(0.82 SC/L)
000358-00121
/31129AA Delphinium
FFACQBB Powdery mildew
(0.82 SC/L)
000358-00121
/31121AA Hollyhock
FFACQBB Powdery mildew
(0.82 SC/L)
000358-00121
/31156AA Phlox
FFACQBB Powdery mildew
(0.82 SC/L)
000358-00121
Issued: 7-22-85
II-022702-9
110
-------
/34120AA
FFACQBB
/31197AA
FFACQBB
EPA Index to Pesticide Chemicals
COPPER (IN THE FORM OF AN AMMONIA COMPLEX)
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Rose
Powdery mildew
(0.8* SC/L)
000358-00121
Sweet Pea
Powdery mildew
(0.8X SC/L)
000358-00121
/64002NA
FYAEQBB
INDOOR
(Wood or Wood Structure Protection Treatments)
Wood Protection Treatment (Seasoned Forest Products)
Wood rot/decay
(4.3X RTU)
003098-00003 011351-00001
Issued: 7-22-85
11-022702-10
1 1 1
-------
=022901
EPA Index to Pesticide Chemicals
COPPER CARBONATE*
TYPE PESTICIDE; Fungicide
FORMULATIONS;
DC20Z, 55Z)
WP (51Z)
Impr (1.3Z)
GENERAL WARNINGS AND LIMITATIONS; Copper carbonate Is compatible with
aost organophosphate and carbamate pesticides* Do not use with 6-methyl-
2,3-quinoxalinedithiol cyclic S,S-dlthlocarhamate, lime sulfur, or strong-
ly acidly spray materials.
Dosage rates and formualtlons are given In metallic copper equivalent.
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s)
704001AA
FBANEBI
/05001AA
FDZAPDZ
FBADMCB
FBAZCEL
FBADMCB
TERRESTRIAL FOOD CROP
(Agricultural Crops)
General Warnings and Limitations; The use of a spreader-sticker is
recommended for sprays.
Apple
Fire blight
(Ervlnia)
Apricot
Bacterial canker
(gummosis)
(Pseudomona8)
Brown rot blossom
and twig blight
(Monilinia)
Shothole
(Coryneum)
Exempt
Full bloom application through 2.04
pounds per acre.
0.255 lb/100 Foliar application. Apply at full
gal bloom, or at petal fall, calyx or
[250-800 late bloom stage.
gal/A]
(51Z WP)
Exempt
Full bloom application through 12.75
pounds per acre.
2.04-2.55 lb/ Dormant, delayed dormant, and foliar
100 gal application. For bacterial canker,
(SIX WP) apply In October and November. For
shothole in the Sacramento Valley,
apply between November 15 and Decem-
ber 15. For brown rot, apply at red
bud, early and late bloom stages.
Brown rot twig 1.275 lb/100 Dormant application. Apply with a
blight (Monilinia) gal dormant oil spray.
(51Z WP)
*basic copper carbonate
Issued: 7-22-85
II-022901-1
1 12
-------
EPA Index to Pesticide Chemicals
05002AA
BADMCB
HBCCDJ
02000AA
•GAJPCN
•"MBCSBL
'GAJPCN
KBCSBL
RAFAAA
'05003AA
/05004AA
FBADMCB
FEAGTAfl
•BAAQAB
Site and Pest
Cherry
Brown rot blossom
and twig blight
(Monilinia)
Cherry leaf spot
(Coccomyces)
Citrus Fruits
Brown rot gummosis
(Phytophthora)
Leaf spot
(Septoria)
Brown rot gummosis
(Phytophthora)
Leaf spot
(Septoria)
Leafhopper
(repellancy)
Nectarine
Peach
Brown rot blossom
and twig blight
(Monilinia)
Leaf curl
(Taphrlna)
Peach blight
Issued: 7-22-85
COPPER CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
Petal fall application through 20.4
pounds per acre.
2.04-2.55 lb/ Delayed dormant and foliar applica-
100 gal
[250-800
gal/A]
(51Z WP)
0.255-0.64
lb/100 gal
or
1.53-7.65
Ib/A
(51Z WP)
0.38-0.765
lb/100 gal
(51Z WP)
0.51-0.765
lb/100 gal
or
1.53-12.75
Ib/A
(51Z WP)
0.255-0.51
lb/100 gal
(51Z WP)
tion. For brown rot, apply at pop-
corn or full bloom, and at petal
fall. For leaf spot, apply at petal
fall.
Exempt
Apply through 12.75 pounds per acre.
Soil, basal bark, and foliar appli-
cation. Apply in late fall at time
of first rains. Spray skirts of
trees from the ground up to 3 to 4
feet high with up to 6 gallons of
spray per tree. Also apply 2 to 4
gallons of spray on the trunk and
ground under the tree. Repeat in
extremely wet years.
Foliar application. Apply to entire
tree in late fall. In copper sensi-
tive or smog areas add 1 pound of
lime as a protective agent.
Use limited to the San Joaquin Val-
ley.
Foliar application. Add 15 to 30
pounds of lime per 100 gallons. Ap-
ply October through November.
Foliar application. Add to gibber-
relic acid sprays as an aid in the
control of brown rot and leaf spot.
Exempt
Pink bud application through 12.75
pounds per acre.
1.53-2.55 lb/ Dormant and delayed dormant appli-
100 gal
(51Z WP)
cation. For leaf curl and peach
blight, apply 2.04 to 2.55 pounds
per 100 gallons between November 15
and December 15. For leaf curl, ap-
ply 1.53 pounds per 100 gallons in
a dormant spray, if the late fall
II-022901-2
1 13
-------
EPA Index to Pesticide Chemicals
Site and Pest
PPMAAAC
/28014AA
FMBHCFK
/OA003EA
FIBFBAW
/28019AA
/28065AA
FIATTAQ
FLAMSCC
COPPER CARBONATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Nectarine cluster (continued)
Copper deficiency
Olive
0.51-0.765
lb/100 gal
(51Z WP)
spray has been omitted. For brown
rot and peach blight, apply 2.04 to
2.55 pounds per 100 gallons at pink
bud.
Copper deficiency spray. Apply
alone or with an oil emulsion.
Peacock spot
(Cycloclonium)
Exempt .
Preharvest (late fall) application
through 16.32 pounds per acre.
Wash olives after picking.
1.53-2.55 lb/ Foliar application. Apply to whole
100 gal tree in late fall.
(51Z WP)
See Nectarine cluster.
3 ppm of combined copper
Impregnated fruit wrap with 1.3 per-
cent metallic copper equivalent.
Fruit wrap. Apply 1 wrap per fruit
within 1 week after harvesting and
before storage.
Formulated with ethoxyquin.
Exempt
Seed treatment (dry) through 0.825
ounce per bushel of seed.
Do not use treated seed for food,
feed, or oil.
Avoid inhaling dust by wearing a
respirator.
Common bunt/stink- 0.4-0.6 oz/bu Seed treatment. Seeds may be treat-
Nest rot
(Botrytis)
Sorghum
Wheat
(1.3Z Impr)
ing smut
(Tilletia)
(on wheat)
Kernel smut
(Sphacelotheca)
(on sorghum)
(20Z D)
or
0.825 oz/bu
(55Z D)
ed in a small tightly closed con-
tainer or in a rotating drum treat-
er. Treated seed should be poured
out on a screen to remove excess
formulation. The excess dust can
be used again.
Issued: 7-22-85
H-022901-3
1 14
-------
Site and Pest
/03009AA Walnut
FBAAXAA Bacterial blight
(Xanthomonas)
Wheat
EPA Index to Pesticide Chemicals
COPPER CARBONATE
Dosages and Tolerance,JUse, Limitations
Formulatlon(s)
Exempt
1.02-1.53 lb/ Delayed dormant and foliar applica-
100 gal tion. Two sprays are recommended.
(51* WP) Apply first in early prebloom with
1 percent of flowers showing and
again when 10 percent of flowers are
showing. In severe disease areas,
make a third application in the post
bloom period.
See Sorghum cluster.
Issued; 7-22-85
H-022901-4
1 15
-------
EPA Index to Pesticide Chemicals
COPPER CARBONATE
Listing of Registered Pesticide Products by Formulation
i020.0003 201 dust
copper carbonate (022901)
001990-00027 001990-00403 002124-00530
&050.0003 55Z dust
copper carbonate (022901)
001109-00024
4051.0006 51Z vettable powder
copper carbonate (022901)
000400-00382
&001.3010 1.3Z impregnated materials
copper carbonate (022901) plus 6-ethoxy-l,2-dihydro-2,2,4-trimethyl-
quinoline (055501)
003222-00006
Issued: 7-22-85 II-022901-5
116
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EPA Index to Pesticide Chemicals
COPPER CARBONATE
Appendix A
Listing of Common Chemical Names Used on the Entry
Chemical Common Name EPA Acceptable
Code (source) Common/Chemical Name
055501 ethoxyquin (ISO) 6-ethoxy-l,2-dihydro-2,2,4-trimethyl-
quinoline
Issued: 7-22-85 II-022901-6
1 17
-------
EPA Index to Pesticide Chemicals
COPPER CARBONATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
/04001AA Apple
FBANEBI Fire blight (Erwinia)
(51% WP)
000400-00382
/05001AA Apricot
FDZAPDZ Bacterial canker (gummosis) (Pseudomonas)
FBADMCB Brown rot blossom and twig blight (Monllinia)
FBADMCB Brown rot twig blight (Monilinia)
FBAZCEL Shothole (Coryneum)
(51Z WP)
000400-00382
/05002AA Cherry
FBADMCB Brown rot blossom and twig blight (Monilinia)
FMBCCDJ Cherry leaf spot (Coccomyces)
(51Z WP)
000400-00382
/02000AA Citrus Fruits
FGAJPCN Brown rot gummosis (Phytophthora)
FMBCSBL Leaf spot (Septoria)
IRAFAAA Leafhopper (repellancy)
(51Z WP)
000400-00382
/05003AA Nectarine
FBADMCB Brown rot blossom and twig blight (Monilinia)
PPMAAAC Copper deficiency
FEAGTAB Leaf curl (Taphrina)
FBAAQAB Peach blight
(51Z WP)
000400-00382
/28014AA Olive
FMBHCFK Peacock spot (Cycloclonium)
(51* WP)
000400-00382
Issued: 7-22-85
II-022901-7
118
-------
/05004AA
FBADMCB
PPMAAAC
FEAGTAB
FBAAQAB
/04003EA
FIBFBAW
/28019AA
FLAMSCC
/03009AA
FBAAXAA
/2806SAA
FLATTAQ
EPA Index to Pesticide Chemicals
COPPER CARBONATE
Appendiz B
Listing by Site/Pest and Site/Formulatlon/Reglstration Number (continued)
Peach
Brown rot blossom and twig blight (Monilinia)
Copper deficiency
Leaf curl (Taphrina)
Peach blight
(SIX WP)
000400-00382
Pear
Nest rot (Botrytis)
(1.3Z Impr)
003222-00006
Sorghum
Kernel smut (Sphacelotheca)
(20Z D)
001990-00027 001990-00403
002124-00530
(551 D)
001109-00024
Walnut
Bacterial blight (Xanthomonas)
(51Z WP)
000400-00382
Wheat
Common bunt/stinking smut (Tilletia)
(20% D)
001990-00027 001990-00403 002124-00530
(551 D)
001109-00024
Issued: 7-22-85
II-022901-8
1 19
-------
EPA Index to Pesticide Chemicals
cOOSOOl BASIC COPPER CHLORIDE
TYPE PESTICIDE; Fungicide
FORMULATIONS; Tech (57Z)
GENERAL WARNINGS AND LIMITATIONS; For use in formulations to be applied
to potatoes and tomatoes. The formulation is given in percent metallic
copper equivalent.
Issued; 7-22-85 II-008001-1
120
-------
EPA Index to Pesticide Chemicals
B&SIC COPPER CHLORIDE
Listing of Registered Pesticide Products by Formulation
&057.0001 57Z (metallic copper equivalent) technical chemical
basic copper chloride (008001)
008732-00002
&000.0090 Formulation not identified
basic copper chloride (008001)
000495-00005*
•jacket currently unavailable for review
Issued: 7-22-85 II-008001-2
121
-------
EPA Index to Pesticide Chemicals
BASIC COPPER CHLORIDE
Auxiliary Documentation
1. For Reg. No. 8732-2, the percent of basic copper chloride is 99.7687Z.
The product name is the ultimate formulation: copper oxychloride.
2. Reg. No. 495-5 was not available for review. A formulation could not
be determined from other data sources.
Issued: 7-22-85 II-008001-1
122
-------
C023701
EPA Index to Pesticide Chemicals
COPPER CHLORIDE (DIHYDRATE)
TYPE PESTICIDE: Fungicide
FORMULATIONS: EC (IX)
GENERAL WARNINGS AND LIMITATIONS: The dosage and formulation are given
in metallic copper equivalent.
Observe warnings and limitations for the other active ingredient.
/31081AA
/31005AA
FIAAGAN
/31005AA
FIAAFAK
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s)
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Cymbidium Orchids
Gloeosporium rot
[MAI] Soil application. Water soil 12
1 this 1% EC/ hours prior to application. Do not
gal water/12 water for 24 hours following appli-
sq.ft of
soil
(12 EC)
cation.
Formulated with dichloroethyl ether.
Ornamental Bulb Plants
Fusarium rot
Refer to Cymbidium Orchids for use and limitation
information.
Issued: 7-22-85
II-023701-1
123
-------
EPA Index Co Pesticide Chemicals
COPPER CHLORIDE (DIHYDRATE)
Listing of Registered Pesticide Products by Formulation
&201.0012 2.682 (12 metallic copper equivalent) emulsifiable concentrate
copper chloride (dihydrate) (023701) plus dichloroethyl ether (029502)
000190-00020
Issued: 7-22-85 II-023701-2
124
-------
/31081AA
/31005AA
FIAAGAN
/31005AA
FIAAFAK
EPA Index to PesticiGe Chemicala
COPPER CHLORIDE (DIHYDRATE)
Appendix L
Listing by Site/Pest and Site/Fonnulation/Registration Number
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Cymbidium Orchids
Gloeosporium rot
(1Z EC)
000190-00020
Ornamental Bulb Plants
Fusarium rot
UZ EC)
000190-00020
Issued: 7-22-85
II-023701-3
125
-------
EPA Index to Pesticide Chemicals
C044005 COPPER CITRATE
TYPE PESTICIDE: Antimicrobial, Algaecide
FORMULATIONS: RTU (11.242)
GENERAL WARNINGS AND LIMITATIONS: None.
Site and Pest Dosages and Tolerance, Use, Limitations
FormulationCs)
Currently there are no federally registered products containing this chem-
ical.
Issued: 7-22-85 II-044005-1
126
-------
EPA Index Co Pesticide Chemicals
COPPER CITRATE
Listing of Registered Pesticide Products by Formulation
9999999 State Label Registration
CA Reg. No.
009743-05241
Issued: 7-22-85 II-044005-2
127
-------
EPA Indcx to P««ticide Chemicals
cC23401 COPPER HYDROXIDE
TYPE PESTICIDE: Fungicide, Antifoulant, Herbicide
FORMULATIONS:
Tech (57.3Z, 59Z)
FI (57.3Z)
D (1.61, 2.6Z, 2.7Z, 4.39Z)
WP (4.4Z, 4.5Z, 4.6Z, 9.5Z, 9.9Z, 10.41, 202, 32Z, 50Z)
FIG (0.53 Ib/gal, 1 Ib/gal, 13.4Z, 2 Ib/gal, 2.12 Ib/gal, 17.5Z, 3.04 lb/
gal)
RTU (1.95Z, 3.91Z, 4.56Z, 5.21Z, 5.73Z, 5.86Z, 13.7Z, 14.26Z, 15.3Z)
GENERAL WARNINGS AND LIMITATIONS: Compatible with moat commonly used in-
secticides and adjuvants.
Dosages and formulations are given in metallic copper equivalents. The
percent of copper hydroxide for each label is given in the Listing of
Registered Pesticide Products by Formulation (page 29).
Observe all warnings and limitations for other active ingredients in mul-
tiple active ingredient labels or in tank mixes.
Do not enter treated area without protective clothing until spray has
dried.
Registration Number 008901-00001 (50 percent wettable powder) contains the
following information: Application of the product to crops listed on the
label at the rates indicated, just prior to anticipated frost conditions,
will afford control of ice nucleating bacteria (Pseudomonas syringae,
Pseudomonas fluorescens, and Erwinia herbicola) and may therefore provide
protection against light frost. These applications are not recommended
for those geographical areas where weather conditions favor severe frost.
NOTE: Seed treatment uses are placed as a group after the agricultural
crop uses.
Definition of Terms;
MAI - multiple active ingredient(s)
Issued: 7-22-85 II-023401-1
128
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Site and Pest
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use,' Liaications
Formulacion(s)
/2300IAA
FMBCCBM
FMBCLAT
/03001AA
FBAZPDZ
TERRESTRIAL FOOD CROP
(Agricultural Crops)
General Warnings and Limitations: For homeowner uses, 1 level table-
spoon of the SO percent wettable powder per gallon of water is equiva-
lent to 1 pound of the product per 100 gallons. Similarly, 1 teaspoon
of the 3.04 pounds per gallon flowable concentrate per gallon of water
is equivalent to 1 pint of the product per 100 gallons^
Unless noted otherwise, application can be made from moat types of spray
equipmment at the following gallonages. For dilute, high volume sprays
apply from 25 to 100 gallons of water per acre for most vegetable crops,
400 to 800 gallons per acre for fruit orchards and up to 1,500 gallons
per acre as may be required for large citrus groves. For concentrate
ground sprays, apply from 5 to 20 gallons per acre for most vegetable
crops and 25 to 100 gallons per acre for fruit and nut crops. For air-
craft application, use 3 to 15 gallons per acre. No additional surfac-
tants are required.
Alfalfa
Cercospora leaf
spot
Leptoephaerulina
leaf spot
Almond
Exempt
No preharvest interval through 1.01
pounds per acre.
Spray injury may occur with sensi-
tive varieties such as Lahontan.
1.0-1.01 Ib/A Foliar application. Apply 10 to 14
(50% WP) days before each harvest or earlier
(2 Ib/gal, if disease threatens. Apply with
3.04 Ib/gal ground equipment or by aircraft.
FIG)
Exempt
Apply to full bloom stage through
6.0 pounds per acre; or, apply up
to 8 weeks postbloom through 0.13
pound per 100 gallons. Slight leaf
injury may occur fron postblooa
spray.
Bacterial shoot
blight
(Pseudomonas)
1.0-2.03 lb/
100 gal
or
concentrate
or aircraft:
3.0-6.0 Ib/A
(20Z, 50* WP)
(3.04 Ib/gal
F1C)
or
Dormant or delayed dormant applica-
tion. Apply at dormant to early
pink bud. Apply concentrate sprays
in 25 to 100 gallons per acre and
in 15 to 25 gallons per acre by
aircraft.
Issued: 7-22-85
II-023401-2
129
-------
Sice and Pest
Almond (continued)
EPA Index Co Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitacions
Formulation(s)
0.25-0.34 oz/
gal
(1 Ib/gal
F1C)
FBADMCB
FBAZCEL
Brown rot blossom
blight (Monilinia)
Shothole
(Coryneua blight)
0.125-0.13
lb/100 gal
(50Z WP)
(3.04 Ib/gal
F1C)
1.0-1.52 lb/
100 gal
[300-400
gal/A]
(20Z, 50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
concentrate
or aircraft:
3.0-4.0 Ib/A
(50Z WP)
or
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
Foliar application. In sprinkler
irrigated orchards-or where disease
is severe, apply 2 to 4 sprays at 2
week postbloom intervals or just
before sprinkling.
Dormant, delayed dormant, and foliar
applications. Apply in late dormant
before foliage buds swell if fre-
quent rainfall occurs. Apply again
in popcorn. To avoid plant injury,
do not apply after full bloom. Ap-
ply in 7.5 to 25 gallons per acre
by aircraft.
Issued: 7-22-85
II-023401-3
130
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EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
/OAOOLAA
Site and Pest
Apple
FMAGPDZ
FDAANAF
FAAANAK
Blister spot
(Pseudomonas)
European canker
(Nectria)
Northwestern an-
thracnose
(Neofabraea)
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 8.0
pounds per acre.
Use on yellow varieties may cause
discoloration. To avoid, pick be-
fore spraying.
Discontinue full coverage spray when
green-tip reaches 0.5 inch as phyto-
toxity may occur from later applica-
tions.
Do not use drench treatment if soil
pH is below 5.5 or copper toxicity
may result.
1.5-2.03 lb/
100 gal
[300-400
gal/A]
(50Z WP)
(3.04 Ib/gal
F1C)
or
0.25-0.34 oz/
gal
(1 Ib/gal
F1C)
Foliar or postharvest application.
Apply before fall rains.
FBAHEBI
Fire blight
(Ervinia)
1.0-2.03 lb/ Delayed dormant application. Apply
100 gal as a full cover spray between sil-
(50Z WP) ver-tip and green-tip.
(3.04 Ib/gal
F1C)
or
0.16-0.31 oz/
gal
(1 Ib/gal
F1C)
FDAGPCN
Phytophthora collar 2.0-2.03 lb/
rot 100 gal
(50Z WP)
(3.04 Ib/gal
F1C)
or
0.31 oz/gal
(1 Ib/gal
F1C)
Use limited to areas other than CA.
Trunk drench. Apply 4 gallons of
suspension as a drench on the lower
trunk area of each tree. Apply
either in early spring or in fall
after harvest each year.
Issued: 7-22-85
II-023401-4
131
-------
/0500LAA
Sice and Pest
Apricot
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
Apply up to full bloom through 6.08
pounds per acre.
Do not apply after bloom to avoid
spray injury.
FBADMCB
FBAZCEL
Brown rot blossom 1.0-1.52 lb/
blight (Monilinia) 100 gal
Shothole [300-400
(Coryneum blight) gal/A]
(20Z, 50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
concentrate
or aircraft:
4.0 Ib/A
(50Z WP)
or
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
Delayed dormant and foliar applica-
tion. Apply at popcorn to full
bloom.
/28000AA
FEAJSCB
Avocado
Scab (spot anthrac- 1.0-1.01 lb/
nose) (Sphaceloma) 100 gal
or
Exempt
Apply up to 6 months after bloom
buds swell through 5.07 pounds per
acre.
Foliar application. Apply when
bloom buds begin to swell. Repeat
at monthly intervals for 5 to 6 ap-
4.0-5.07 Ib/A plications. Consult a State Agri-
(50Z WP) cultural Extension Service for
(2 Ib/gal, recommendations.
3.04 Ib/gal
FIG)
or
0.16 oz/gal
(1 Ib/gal
F1C)
Issued: 7-22-85
II-023401-5
132
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EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
/06002AA
Site and Pest
Banana
FIEQPOZ
FMBOCBM
Black pitting
(Piricularia
grisea)
Sigatoka disease
(Cercospora leaf
spot)
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 1.01
pounds per acre by aircraft; or,
apply up to 2 weeks after fruit
emergence through 2.03 pounds per
100 gallons.
2.0-2.03 lb/ Fruit and leaf crown application.
100 gal Apply directly to the fruit stem
(50% WP) and include the basal portion of
(2 Ib/gal, the leaf crown. Apply during the
3.04 Ib/gal first and second week after
F1C) emergence.
aircraft: Foliar application. Apply at 14 day
1.0-1.01 Ib/A intervals throughout the wet season
[3 gal/A in- or at 21 day intervals during dry
eluding 0.5 periods.
gal agricul-
tural oil]
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
/28063AA Barley
/28065AA Wheat
FCADHAM Helminthosporium
leaf blotch
FMBCSBL Septoria leaf
blotch
0.75-1.01
Ib/A
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
Exempt
Apply 10 days after early heading
through 1.01 pounds per acre.
Foliar application. Apply at early
heading and repeat 10 days later.
Issued: 7-22-85
II-023401-6
133
-------
/28001AA
FBZFXAV
FBZRPGG
Site and Pest
Beans
Bacterial blight
(common)
(Xanthomonas)
Halo blight
(Pseudomonas)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 1.52
pounds per acre.
0.5-1.52 Ib/A Foliar application. As a protective
/01002AA
Blackberry
FMAMMCO
FMAMSBL
Leaf and cane spot
(Mycosphaerella)
(Septoria)
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.094-0.25
oz/gal
(1 Ib/gal
F1C)
[MAI]
1-3 qt 17.5Z
FIG/A
(17.5Z F1C)
- — ---*» •
spray, apply when plants are 6 inch-
es high. Repeat at 7 to 14 day in-
tervals depending on local condi-
tions.
—OR MAI--
Formulated with sulfur.
1.0-2.03 lb/
100 gal
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.15-0.31 oz/
gal
(1 Ib/gal
F1C)
Exempt
Delayed dormant and postharvest ap-
plications through 2.03 pounds per
100 gallons.
Apply in late spring through 1.01
pounds per 100 gallons.
Delayed dormant, foliar, and post-
harvest applications. Add 1 quart
superior-type oil per 100 gallons
for all sprays. Apply delayed dor-
mant spray after training in spring
at high rate. Apply in late spring
at low rate. Apply in fall after
harvest at high rate.
Issued: 7-22-85
II-023401-7
134
-------
/13005AA
/13006AA
/13007AA
/13008AA
FFABPAU
/13007AA
FIAFXAA
FMBCAAX
/10002AA
/10005AA
/10006AA
FFABPEA
Sice and Pest
Broccoli
Brussels Sprouts
Cabbage
Cauliflower
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
ExempC
No preharvest interval through 0.51
pound per acre for broccoli, brus-
sels sprouts, and cauliflower or
1.01 pounds per acre for cabbage.
A slight reddening of older leaves
may occur on broccoli and a slight
flecking of wrapper leaves may occur
on cabbage at the high rate.
Downy mildew
(Peronospora)
(cabbage)
Black rot
(Xanthomonas)
Leaf spot
(Alternaria)
Brussels Sprouts
Cabbage
Cantaloupe
Honeydgw Melons
Musknelons
Downy mildew
(Pseudoperono-
spora)
Foliar application. Apply after
transplants are set in the field,
or shortly after emergence of field-
seeded crops or when conditions
favor disease development. Repeat
at 7 day intervals.
0.25-0.51
Ib/A
tmin. 25
gal/A]
(502 WP)
(3.04 Ib/gal
F1C)
or
0.062-0.094
oz/gal
(1 Ib/gal
F1C)
1.0-1.01 Ib/A
[min. 25
gal/A]
(50* WP)
(3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
See Broccoli cluster.
See Broccoli cluster.
Exempt
No preharvest interval through 1.01
pounds per acre.
1.0-1.01 Ib/A Foliar application. Apply before
(50% WP) disease appears at weekly intervals.
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
Foliar application. Apply after
transplants are set in the field,
or shortly after emergence of field-
seeded crops or when conditions
favor disease development. Repeat
at 7 to 10 day intervals.
Issued: 7-22-85
II-023401-8
135
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Sice and Pest
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
/28073AA
FBAMCBM
Cantaloupe cluster (continued)
0.16 oz/gal
(1 Ib/gal
F1C)
Carrots
Early blight
(Cercospora)
/28003AA
FBAAPDZ
FBAMCBM
FBASSBL
/05002AA
Cauliflower
Celery
Bacterial blight
(Pseudomonas)
Early blight
(Cercospora)
Late blight
(Septoria)
Cherry
FBADMCB
Brown rot blossom
rot (Monilinia)
Exempt
No preharvest interval through 1.01
pounds per acre.
1.0-1.01 Ib/A Foliar application. Apply when
(501 WP) disease threatens. Repeat at 7 to
(2 Ib/gal, 14 day intervals depending upon
3.04 Ib/gal disease severity.
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
See Broccoli cluster.
Exempt
No preharvest interval through 1.01
pounds per acre.
Ib/A
1.0-1.01
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
1.0-1.52 lb/
100 gal
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
Foliar application. Apply as soon
as plants are first established in
the field. Repeat at 5 to 7 day
intervals depending upon disease
severity and weather. One or 2
quarts of a suitable agricultural
spray oil per acre may be used as a
spreader-sticker.
Exempt
Apply in October, January, or August
through 3.04 pounds per 100 gallons,
or 1.52 pounds per 100 gallons up
to full bloom.
Delayed dormant and foliar applica-
tion. Apply as a full cover spray
at popcorn and full bloom.
Issued: 7-22-85
II-023401-9
136
-------
Sice and Pest
Cherry (continued)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
0.16-0.25 oz/
(1 Ib/gal
F1C)
FBAAFDZ
PBAZCEL
Dead bud
(Pseudomonas)
Shothole
(Coryneum blight)
/02000AA
Citrus Fruits
FGAJPCN
Brown rot guramosis
(Phytophthora)
FMAYMCO
FIBLDAP
FMBIMCO
FAABEAH
3.0-3.04 lb/
100 gal
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.5 oz/gal
(1 Ib/gal
F1C)
Greasy spot
(Mycosphaerella)
Melanose
(Diaporthe)
Pink pitting
(Mycosphaerella)
Scab (spot anthrac-
nose) (Elsinoe)
Apply in October (before heavy rain
falls) and again in January adding
1 pint of superior-type oil per 100
gallons. In orchards where disease
is severe, a spray should also be
applied in August.
0.25-0.51 lb/
100 gal
(20%, 50Z WP)
(3.04 Ib/gal
F1C)
or
0.062-0.094
oz/gal
(1 Ib/gal
F1C)
0.375-0.76
lb/100 gal
or
aircraft:
3.0-3.04 lb/
10 gal/A
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.062-0.125
oz/gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 3.04
pounds per acre.
Concentrate sprays may be applied
at equivalent rates.
Foliar and soil applications. Apply
in fall just before or after first
heavy rains. Apply to skirts of
trees to height of at least 4 feet.
Apply also to bare ground 1 foot
beyond skirt. For CA, in areas sub-
ject to copper injury, add 0.333 to
1 pound of high quality lime per 0.5
pound metallic copper.
Foliar application. Apply
bloom and postbloom sprays,
as pre-
Issued: 7-22-85
11-023401-10
137
-------
Sice and Peat
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Citrus Fruits (continued)
FIBLDAP
FAAAEAH
Melanose
(Diaporthe) 500 gal
Scab (spot anthrac- (9.SZ, 9.9Z
nose) (Elsinoe) 10.42 WP)
2.08-2.09 lb/ Use limited to FL.
/07001AA
FIFAPLG
Cocoa
Black pod
(Phytophthora
palmivora)
/07002AA
Coffee
FJAGHAO
Coffee leaf rust
(Hemileia)
(in Brazil)
(MAI]
2.07 lb/500
gal
(4.4Z, 4.51,
4.6Z WP)
(All formulations include nutrition-
al materials.)
Dormant and foliar application. For
scab, apply just before flush ap-
pears, usually late January or early
February. For melanose and scab,
apply 1 to 2 weeks after petal fall.
—OR MA1--
Formulated with sulfur.
wet areas:
1.0-2.28 Ib/A
or
drier areas:
3.25-4.31
Ib/A
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
average den-
sity plant-
ings:
1.75-2.79
Ib/A
(50Z WP}
(2 Ib/gal,
3.04 Ib/gal
F1C)
Exempt
No preharvest interval through 4.31
pounds per acre.
Foliar application. Apply at the
start of the rainy season and repeat
while infection conditions persist.
In high rainfall areas, apply at 14
to 21 day intervals at a rate de-
pending upon disease severity. For
drier areas, where 2 to 4 applica-
tions are recommended during criti-
cal infection periods and at long
application intervals, apply at a
rate according to disease incidence
and planting density.
Exempt
No preharvest interval through 4.05
pounds per acre as a spray or 4.29
pounds per acre as a dust.
Foliar application. Apply from Sep-
tember to March depending upon alti-
tude and local recommendations. Ap-
ply at 3 to 4 week intervals depend-
ing upon disease severity and rain-
fall conditions. Apply dust using
ground equipment.
or
Issued: 7-22-85
11-023401-11
138
-------
Site and Pest
Coffee (continued)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation^ s)
high density
plantings:
3.5-4.05 Ib/A
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
1.24-4.29
Ib/A
(2.7% D)
FMBACBM
FGAOCEF
/01010AA
FIBFQBB
Iron spot
(Cercospora)
Pink disease
(Corticium)
Cranberry
Fruit rot
1.0-1.01 Ib/A Foliar application. Apply as a di-
(50% WP) lute or concentrate spray. Apply
(2 Ib/gal, at the start of the wet season and
3.04 Ib/gal continue at monthly intervals for 3
F1C) applications.
Exempt
No preharvest interval through 4.05
pounds per acre.
4.0-4.05 Ib/A Foliar application. Apply beginning
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
in late bloom. One or 2 additional
applications made at 10 to 14 day
intervals may be needed, depending
upon disease pressure. Consult a
State Agricultural Extension Service
for recommendations.
/10010AA Cucumber
PMABPDZ Angular leaf spot
(Pseudomonas)
FFABPEA Downy mildew
(Ps eudoperono-
spora)
0.75-1.01
Ib/A
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.125-0.16
oz/gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 1.01
pounds per acre.
Foliar application. Apply weekly
once the plants begin to vine.
Issued: 7-22-85
11-023401-12
139
-------
/0101LAA
/01013AA
FHBCQBB
Site and Pest
Currant
Gooseberry
Leaf spot
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Exempt
Apply after petal fall through 5.07
pounds per acre.
5.0-5.07 Ib/A Postharvest, delayed dormant, and
/11001AA
FAAACDP
PBAMAAX
FBAAPBU
/03005AA
FBAAXAA
Eggplant
Anthracnose
(Colletotrichum)
Early blight
(Alternaria)
Phomopsis blight
Filbert
Bacterial blight
(Xanthomonas)
foliar application. Apply 3 times,
first after harvest, then before
bloom, and after petal fall.
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.81 oz/gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 1.01
pounds per acre.
Use limited to areas other than CA.
1.0-1.01 Ib/A Foliar application. Apply before
(502 WP) disease appears. Repeat at 7 to 10
(3.04 Ib/gal day intervals.
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 3.04
pounds per 100 gallons.
2.0-3.04 lb/
100 gal
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.31-0.5 oz/
gal
(1 Ib/gal
F1C)
Foliar and postharvest application.
Add 1 pint superior-type oil per 100
gallons. Apply in late August or
early September. In seasons of
heavy rainfall, apply another spray
when three-fourths of the leaves
have dropped.
Issued: 7-22-85
11-023401-13
140
-------
EPA Index to Pesticide Chemicals
/01014AA
Sice and Pest
Grapes
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulat100(3)
Exempt
No preharvest interval through 1.01
pounds per acre.
Slight to severe foliage injury may
occur on copper-sensitive varieties
such as Concord, Delaware, Niagara,
and Rosette.
FIBFGBG
FFABPCV
FFACUAB
/08020AA
Black rot
(Guignardia)
Downy mildew
(Plasmopara)
Powdery mildew
(Uncinula)
1.0-1.01 Ib/A
(50Z WP)
(3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
FiC)
Foliar application. Add 2 to 6
pounds of hydrated lime per acre and
apply as a dilute or concentrate
spray. Apply as the last 1 or 2
late summer sprays following an
early season application of another
fungicide. Consult a State Agricul-
tural Extension Service for timing
recommendat ions.
See Currant cluster.
See Cantaloupe cluster.
Exempt
Apply through 1.01 pounds per 100
gallons. Do not apply within 2
weeks of harvest.
FFABPEA
/13020AA
FFABBBA
Downy mildew
(Pseudoperono-
spora)
Lettuce
Downy mildew
(Bremia)
1.01 lb/100 Crown treatment and foliar applica-
gal tion. Apply to crown (after prun-
(50% WP) ing, but before training) as needed.
(3.04 Ib/gal After training, apply at approxi-
F1C) mately 10 day intervals.
Exempt
No preharvest interval through 1.01
pounds per acre.
0.5-1.01 Ib/A Foliar application. Apply when
(50Z WP)
(3.04 Ib/gal
FIC)
or
C.094-0.16
oz/gal
(1 Ib/gal
FIC)
disease first appears and repeat at
7 to 10 day intervals as needed to
suppress disease.
Issued: 7-22-85
11-023401-14
141
-------
EPA Index Co Pesticide Chemicals
COPPER HYDROXIDE
Site and Pest
Dosages and Tolerance, Use, Limitacions
Formulaeion(s)
/06007AA
Exempt
No preharvesC interval through 5.07
pounds per acre.
Use limited Co FL.
FAAAGAP
Anthracnose
(Glomerella)
/05003AA
/05004AA
Muskmelons
Nectarines
Peaches
FMCBXAA
Bacterial fruit
and leaf spot
(Xanthomonas)
1.0-1.01 lb/
100 gal
or
4.0-5.07 Ib/A
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
0.125-1.01
lb/100 gal
Foliar application. Apply monthly
after fruit sec until harvest.
See Cantaloupe cluster.
Exempt
Apply through 0.17 pound per 100
gallons. Do not apply within 3
weeks of harvest.
Dormant application through 8.11
pounds per acre.
Slight defoliation and spotting of
leaves may occur from use in cover
sprays.
Dormant and foliar applications.
Apply in dormant stage at high rate.
FBADMCB
(20Z, 50Z WP) Apply at first and second cover
(2 Ib/gal, sprays at low rate.
3.04 Ib/gal
F1C)
or
0.016-0.16
oz/gal
(1 Ib/gal
F1C)
Brown rot blossom 1.0-1.5 lb/ Delayed dormant application. Apply
blight (Monilinia) 100 gal at pink bud as a full cover spray.
(20Z, 50Z WP) (This application also aids in the
(3.04 Ib/gal control of leaf curl and shothole.)
F1C)
or
Issued: 7-22-85
11-023401-15
142
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
FormulationCs)
Nectarines (continued)
FEAGTAB
FBA2CEL
Leaf curl
(Taphrina)
Shothole
(Coryneura blight)
/28014AA
FMBHCFK
Olive
Peacock spot
(Cycloconium)
/14011AA
FFABPAU
FCAEAAX
Onion
Downy mildew
(Peronospora)
Purple blotch
(Alternaria)
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
1.0-2.03 lb/ Dormant application. Apply at leaf
100 gal fall. Apply at high per acre rate
or when rainfall is very heavy and dis-
4.0-8.11 Ib/A ease pressure is high. Apply again
(20%, 50% WP) in late dormant if rain is frequent.
(2 Ib/gal, May be applied with agricultural
3.04 Ib/gal spray oil. For concentrate sprays,
F1C) apply at equivalent rates in 100
or gallons water.
0.16-0.34 oz/
gal
(1 Ib/gal
F1C)
Exempt
Apply through 6.08 pounds per acre.
Use limited to CA.
1.0-1.5 lb/ Postharvest and foliar applications.
100 gal Apply before winter rains. Repeat
or in early spring if disease is se-
4.0-6.08 Ib/A vere.
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 1.01
pounds per acre.
1.0-1.01 Ib/A Foliar application. Apply when
(50% WP) plants are 4 to 6 inches high and
(3.04 Ib/gal repeat at 7 to 10 day intervals.
F1C)
or
Issued: 7-22-85
11-023401-16
143
-------
Site and Pest
Onion (continued)
/28015AA
FMBCCBM
Peaches
Peanuts
Cercospora leaf
spot
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
0.16 oz/gal
(1 Ib/gal
F1C)
See Nectarines cluster.
Exempt
No preharvest interval through 1.52
pounds per acre.
0.75-1.52
Ib/A
(502 WP)
(2 ib/gal,
3.04 Ib/gal
FIG)
or
1 gal 13.72
RTU/A
[aircraft]
(13.72 RTU)
or
0.39-0.65
Ib/A
(2.62 D)
fMAIJ
0.265-0.96
Ib/A
(322 WP)
(0.53 Ib/gal
F1C)
or
3-4 qt 13.42
F1C/A
(13.42 F1C)
or
1-2 qt 17.52
FIG/A
(17.52 F1C)
or
0.24-0.4 Ib/A
(1.62 0)
Foliar application. Apply 40 to 45
days after planting or when disease
symptoms appear. Repeat at 10 to
14 day intervals. Apply by ground
equipment or aircraft using 3 to 10
gallons per acre by aircraft. May
be tank mixed with sulfur (1 to 2
quarts of a 6 pound per gallon flow-
able concentrate).
—OR MAI--
Formulated with sulfur.
Issued: 7-22-85
11-023401-17
144
-------
/04003AA
FMAHPDZ
Site and Pest
Pear
Bacterial blast
(Pseudomonas)
EPA Index co Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance. Use. Limitations
Formulation(s)
Exempt
Apply throughout bloom period
through 0.51 pound per acre. Exces-
sive dosages may cause fruit russet.
FBAMEBI
Fire blight
(Ervinia)
/28016AA
FFACEBJ
Peas
Powdery mildew
(Erysiphe)
Postharvest and dormant applica-
tions. Apply before fall rains and
again at dormant before spring
growth starts.
1.5-2.03 lb/
100 gal
[300-400
gal/Al
(202, 502 WP)
(3.04 Ib/gal
F1C)
or
0.25-0.31 oz/
gal
(1 Ib/gal
FIG)
0.12-0.13 lb/ Foliar application. Apply at 5 day
100 gal intervals throughout the bloom peri-
or od.
0.5-0.51 Ib/A
(20*, 502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.016 oz/gal
(1 Ib/gal
F1C)
or
0.52-0.54
Ib/A
(2.62, 2.72
D)
Exempt
No preharvest interval through 1.52
pounds per acre.
0.75-1.52 Foliar application. Apply when dis-
Ib/A ease symptoms first appear. Repeat
(502 WP) at weekly intervals.
(2 Ib/gal, —0*
3.04 Ib/gal
F1C)
or
Issued: 7-22-85
11-023401-18
145
-------
Sice and Pest
Peas (continued)
/28017AA
FMAAXAA
Peppers
Bacterial spot
(Xanthomonas)
/14013AA
FBAMAAX
FBASPCN
Potato
Early blight
(Alternaria)
Late blight
(Phytophthora)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
0.125-0.25
oz/gal
(1 Ib/gal
F1C)
Formulated with sulfur.
[MAI]
1.5-3 qt
17.52 F1C/A
(17.51 FIG)
Exempt
No preharvest interval through 1.67
pounds per acre.
1.0-1.52 Ib/A Foliar application. Apply when dis-
(50Z WP) ease threatens at 7 to 14 day inter-
(2 Ib/gal, vals depending upon disease severi-
3.04 Ib/gal ty.
F1C) —OR MAI—
or
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
or
1.13-1.67
Ib/A
(2.7Z D)
[MAI] Formulated with sulfur.
2-3 qt 17.5Z
F1C/A
(17.5Z F1C)
Exempt
Apply through 2.03 pounds per acre.
Do not apply within 2 weeks of
harvest.
Foliar application. Apply at 7 to
10 day intervals beginning when
plants are 6 inches high. Apply 0.5
to 0.76 pound per acre where disease
is light and up to 1.5 to 2.03
pounds per acre where disease is
more severe.
0.5-2.03 Ib/A
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.094-0.125
oz/gal
(1 Ib/gal
F1C)
Issued: 7-22-85
11-023401-19
146
-------
/10011AA
/10012AA
FEAJCCV
Site and Pest
Pumpkin
Squash
Powdery mildew
(Erysiphe)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Exempt
No preharvest interval through 1.52
pounds per acre.
/01016AA
Squash
Strawberry
FBATDAH
FMBCMCO
Leaf blight
(Dendrophoma)
Leaf spot
(Mycosphae.rella)
/28020AA
FMBCCBM
Sugar Beets
Leaf spot
(Cercospora)
0.75-1.52
Ib/A
(50Z UP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.125-0.25
oz/gal
(1 Ib/gal
F1C)
Foliar application. Apply when
plants are 3 weeks old or when dis-
ease symptoms first appear. Repeat
at weekly intervals.
1.0-1.5 lb/
100 gal/A
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16-0.25 oz/
gal
(1 Ib/gal
F1C)
See Pumpkin cluster.
Exempt
No preharvest interval through 1.52
pounds per acre.
Discontinue applications if signs
of phytotoxicity appear.
Delayed dormant and foliar applica-
tions. Apply when plants are estab-
lished and repeat at 7 day intervals
throughout the season.
1.0-2.53 Ib/A
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
1 gal 13.7Z
RTU/A
(13.7Z RTU)
Exempt
No preharvest interval through 2.53
pounds per acre.
Foliar application. Add a suitable
agricultural spray oil at 2 quarts
per acre. Apply when disease
threatens and continue for 4 to 5
applications at 10 to 14 day inter-
vals depending upon weather condi-
tions. Apply the liquid-ready to
use formulation using low volume
aircraft or mist sprayers.
—OR MAI—
Issued: 7-22-85
11-023401-20
147
-------
EPA Index Co Pesticide Chemicals
COPPER HYDROXIDE
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s)
Sugar Beets (continued)
/11005AA
FMBPPDZ
Tomato
Bacterial speck
(Pseudomonas)
FMAAXAA
Bacterial spot
(Xanthomonas)
FBAHAAX
Early blight
(Alternaria)
[MAI] Formulated with sulfur.
2-5 qt 17.5Z
F1C/A
(17.5Z FIG)
Exempt
No preharvest interval through 2.03
pounds per acre.
1.0-1.01 Ib/A Foliar application. Apply at 10 to
(50Z WP) 30 day intervals beginning when dia-
(3.04 Ib/gal ease threatens. Use more frequent
F1C) applications when disease pressure
or is high.
0.16 oz/gal
(1 Ib/gal
F1C)
1.0-2.03 Ib/A
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16-0.31 oz/
gal
(1 Ib/gal
F1C)
Foliar application. Apply when dis-
ease threatens at 7 to 10 day inter-
vals. Apply more frequently when
disease is severe. May be tank mix-
ed with 1.2 to 1.6 pounds active
ingredient per acre of mancozeb or
maneb.
—OR MAI—
[MAI] Formulated with sulfur.
2-4 qt 17.5Z
F1C/A
(17.5Z F1C)
1.0-1.52 Ib/A Foliar application. Apply when dis-
(50Z WP) ease threatens at 7 to 10 day inter-
(2 Ib/gal, vals.
3.04 Ib/gal —OR MAI—
F1C)
or
0.16-0.25 oz/
gal
(1 Ib/gal
FIG)
Issued: 7-22-85
11-023401-21
148
-------
Site and Pest
Tomato (continued)
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
/03009AA
FBZAXAA
Walnut
Walnut blight
(Xanthomonas)
/10008AA
FAAACDP
FFABPEA
Watermelons
Anthracnose
(Colletotrichum)
Downy mildew
(Pseudoperono-
spora)
[MAI]
2-3 qt 17.5Z
F1C/A
(17.5Z F1C)
Formulated with sulfur.
1.0-1.01 lb/
100 gal
[min. 4.0
Ib/A]
(202, 502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.16 oz/gal
(1 Ib/gal
F1C)
0.75-1.52
Ib/A
(502 WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.125-0.25
oz/gal
(1 Ib/gal
F1C)
Exempt
No preharvest interval through 6.3
pounds per acre per application.
Delayed dormant and foliar applica-
tions. One pint of summer oil emul-
sion may be added per 100 gallons
of spray. Apply at early prebloom
when catkins are partially expanded.
Repeat 3 times during bloom and
early nutlet stage at 7 to 10 day
intervals. Additional applications
may be required when frequent rain-
fall occurs. May be applied in con-
centrate sprays at equivalent rates
in 50 to 100 gallons per acre.
Exempt
No preharvest interval through 1.52
pounds per acre.
Foliar application. Apply as soon
as plants become established. Re-
peat at weekly intervals. For an-
thracnose, apply 1.0 pound per acre.
For downy mildew, apply 0.75 to 1.52
pounds per acre.
Wheat
See Barley cluster.
Issued: 7-22-85
11-023401-22
149
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Site and Pest
/28063AA
/2806SAA
FLATTAQ
/28072AA
FKABADD
FKABPES
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
(Agricultural Seed Treatment)
General Warnings and Limitations; Do not use treated seed for food,
feed, or oil purposes. Consult a State Agricultural Experiment Station
for specific recommendations.
Barley
Wheat
Bacterial leaf
blight (Pseudo-
monas syringae)
Bacterial leaf
streak (Xantho-
nonas translucens)
Common bunt
(Tilletia caries)
Rice
1.06 oz/100
Ib seed
(2.12 Ib/gal
or 19.5Z
F1C)
Exempt
Seed treatment through 1.06 ounces
per 100 pounds of seed.
Seed treatment. Dilute product with
equal parts of water before apply-
ing.
Seed rot
(Achlya) (Pythium)
Wheat
Exempt
Seed treatment through 2.12 ounces
per 100 pounds of seed.
Phytotoxicity may occur in drill-
seeded rice.
1.06-2.12 oz/ Seed treatment. For ease of hand-
100 Ib seed ling and when using a seed treating
(2.12 Ib/gal machine, dilute product with an
or 19.52 equal volume of water.
F1C)
See Barley cluster.
Issued: 7-22-85
11-023401-23
150
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Site and Pest
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
TERRESTRIAL NON-FOOD CROP
/34147AA
FMBCCBM
FMBCSBL
/34018AA
FMBCAAX
FMBCCBM
FMBCXAA
/34022AA
FBADBAW
FBBJBAW
FMBCCBM
FDACPCN
FFACQBB
(Ornamental Plants and Forest Treea)
Adam's Needle
Leaf spot
(Cercospora)
Leaf spot
(Septoria)
Aralia
Leaf spot
(Alternaria)
Leaf spot
(Cercospora)
Leaf spot
(Xanthomonas)
0.094 oz/gal
(1 Ib/gal
F1C)
Discoloration of foliage and/or
blooms has been noted on some vari-
eties of azalea, carnation, chrysan-
themum, English ivy, and rose.
Spray deposits may be removed by
washing.
Phytotoxicity may depend upon vari-
etal differences of the ornamentals
listed. As a test, apply the recom-
mended rate to a few plants and ob-
serve after 7 to 10 days for symp-
toms of phytotoxicity.
Foliar application. Apply for thor-
ough coverage beginning at the first
sign of disease. Repeat as needed.
Apply at shorter intervals during
periods of frequent rains or when
severe disease conditions persist.
Refer to Adam's Needle for dose and use informa-
tion.
Azalea
Botrytis blossom
blight
Botrytis leaf and
stem blight
Leaf spot
(Cercospora)
Phytophthora die-
back
Powdery mildew
Issued: 7-22-85
11-023401-24
151
-------
/31034AA
FAAAGAN
FMZCXAA
/31057AA
FBATAAX
FMZCPDZ
FBAABAW
FEAABAW
FMBCSBL
/34045AA
FBAABAW
/31093AA
FBAABAW
EPA Index Co Pesticide Chemicals
COPPER HYDROXIDE
Site and Pest Dosages and Tolerance, Use, Limitations
Foraulation(s)
Azalea (continued)
Refer to Adam's Needle for dose and use informa-
tion.
Begonia
Anthracnose
(leaf spot)
(Gloeosporium)
Bacterial leaf spot
(Xanthomonas)
Refer to Adam's Needle for dose and use informa-
tion.
Carnation
Alternaria blight
(leaf spot)
Bacterial leaf spot
(Pseudomonas)
Botrytis blight
Refer to Adam's Needle for dose and use informa-
tion.
/31065AA Chrysanthemum
Botrytis blight
Leaf spot
(Septoria)
Cotoneaster
Botrytis blight
Easter Lily
Botrytis blight
Refer to Adam's Needle for dose and use informa-
tion.
Refer to Adam's Needle for dose and use informa-
tion.
Refer to Adam's Needle for dose and use informa-
tion.
Issued: 7-22-85
11-023401-25
152
-------
/34052AA
FHZCXAA
/34053AA
FAAACDP
FBAABAW
/31111AA
FBAABAW
/34106AA
FBBJVAL
/34109AA
FDABPBU
/34058AA
FBANEBI
FEAJFAM
Site and PesC
English Ivy
ŁPA Index Co Pesci.ci.de Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limications
Fonmilacion(s)
Bacterial leaf spoC
(XanChomonas)
Refer Co Adam's Needle for dose and use informa-
tion.
Euonymus
Anthracnose
(Colletotrichum)
Botrytis blight
Gladiolus
Botrytis blight
Refer to Adam's Needle for dose and use informa-
tion.
Refer to Adam's Needle for dose and use informa-
tion.
Pachysandra
Volutella leaf and
stem blight
Refer to Adam's Needle for dose and use informa-
tion.
Periwinkle
Canker and dieback
(Phomopsio)
Refer to Adam's Needle for dose and use informa-
tion.
Pyracantha
Fire blight
(Ervinia)
Scab
(Fusicladium)
Refer to Adam's Needle for dose and use informa-
tion.
Issued: 7-22-85
11-023401-26
153
-------
/34120AA
FMAEDBS
FFACQBB
/35191AA
PFOABBB
Site and Pest
Rose
Black spot
(Diplocarpon)
Powdery mildew
Live Oak
Ball moss
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Refer to Adam's Needle for dose and use informa-
tion.
3.0-3.04 lb/
100 gal
(50% WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.5 oz/gal
(1 Ib/gal
F1C)
Use limited to TX.
Foliar application. Apply in spring
after heavy rain using 1.5 gallons
of spray per foot of tree height.
Make sure to wet tufts thoroughly.
A second application may be required
after 12 months.
/31155AA
FMBCXAA
Philodendron
Bacterial leaf spot 0.75-0.76 lb/ Foliar application. Tank mix with
(Xanthomonas)
1.2 pounds active ingredient manco-
zeb per 100 gallons water. Apply
weekly before disease appears.
/35119AA
FAAAGAT
Sycamore
Anthracnose
(Gnooonia)
100 gal
(50Z WP)
(2 Ib/gal,
3.04 Ib/gal
F1C)
or
0.125 oz/gal
(1 Ib/gal
F1C)
1.0-1.52 lb/ Foliar application. Apply as a full
100 gal cover spray first at bud crack and
(50Z WP) again 7 to 14 days later at 10 per-
(3.04 Ib/gal cent leaf expansion.
F1C)
or
0.16-0.25 or/
(1 Ib/gal
F1C)
Issued: 7-22-85
11-023401-27
154
-------
Sice and Pest
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
AERIAL AND TANK MIX APPLICATIONS
9001500
AAAAAAA
Aerial Application
9900300
AAAAAAA
Tank Mix
Refer to
TERRESTRIAL FOOD CROP
(Agricultural Crops)
All sites except Grapes and Hops
Refer to
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Peanuts, Tomato
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Philodendron
Issued: 7-22-85
11-023401-29
55
-------
&057.3001
&059.0001
&057.3002
&001.6003
&002.6003
&002.7003
&004.3903
&004.4006
&004.5006
&004.6006
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Listing of Registered Pesticide Products by Formulation
57.32 metallic copper equivalent (902 copper hydroxide) technical chemicaj.
copper hydroxide (023401)
008901-00012
592 metallic copper equivalent (882 copper hydroxide) technical chemical
copper hydroxide (023401)
045002-00002 048957-00016
57.3Z metallic copper equivalent (882 copper hydroxide) formulation inter-
mediate
copper hydroxide (023401)
008901-00005
1.61 metallic copper equivalent (2.51 copper hydroxide) dust
jpper hydroxic
008901-00004
copper hydroxide (023401) plus sulfur (077501)
2.6Z metallic copper equivalent (4.3Z copper hydroxide) dust
copper hydroxide (023401)
008901-00003
2.7Z metallic copper equivalent (4.151 copper hydroxide) dust
jpper hydroxic
007001-00224
copper hydroxide (023401)
Ł$
I3Z
4.392* metallic copper equivalent (6.74Z copper hydroxide) dust
copper hydroxide (023401) plus endosulfan (079401)
000264-00365*
fjacket currently unavailable for review
Calculated value based on the ratio of metallic copper to copper
hydroxide
4.4Z metallic copper equivalent (6.76Z* copper hydroxide) vettable powder
copper hydroxide (023401) plus sulfur (077501)
002124-00799
^calculated value based on the ratio of metallic copper to copper
hydroxide
4.5Z metallic copper equivalent (6.91Z* copper hydroxide) wettable powder
copper hydroxide (023401) plus sulfur (077501)
002124-00797 002124-00801
Calculated value based on the ratio of metallic copper to copper
hydroxide
4.62 metallic copper equivalent (7.06Z* copper hydroxide) wettable powder
copper hydroxide (023401) plus sulfur (077501)
002124-00803
^calculated value based on the ratio of metallic copper to copper
hydroxide
Issued: 7-22-85
11-023401-30
156
-------
E;?A Index to Pesticide Chemicals
COPPER HYDROXIDE
Listing of Registered Pesticide Products by Formulation (continued)
4009.5006 9.52 metallic copper equivalent (14.59%* copper hydroxide) vettable powder
copper hydroxide (023401)
002124-00798
Calculated value based on the ratio of metallic copper to copper
hydroxide
4009.9006 9.92 metallic copper equivalent (15.22* copper hydroxide) vettable powder
copper hydroxide (023401)
002124-00796 002124-00800
Calculated value based on the ratio of metallic copper to copper
hydroxide
&010.4006 10.4Z metallic copper equivalent (15.97%* copper hydroxide) wettable pow-
der
copper hydroxide (023401)
002124-00802
^calculated value based on the ratio of metallic copper to copper
hydroxide
&020.0006 202 metallic copper equivalent (30.7% copper hydroxide) wettable powder
copper hydroxide (023401)
008901-00022
&032.0006 32Z metallic copper equivalent (502 copper hydroxide) wettable powder
copper hydroxide (023401) plus sulfur (077501)
008901-00010
4050.0006 502 metallic copper equivalent (77% copper hydroxide) wettable powder
copper hydroxide (023401)
iqu
J23"
007001-00065 008901-00001 045002-00001 048957-00014
&204.4014 0.53 Ib/gal or 4.42 metallic copper equivalent (6.752 copper hydroxide)
flowable concentrate
copper hydroxide (023401) plus sulfur (077501)
001812-00215
4209.5014 1 Ib/gal or 9.5Z metallic copper equivalent (14.61 copper hydroxide) flow-
able concentrate
copper hydroxide (023401)
008901-00028
4213.4014 13.41 metallic copper equivalent (20.51 copper hydroxide) flowable concen-
trate
copper hydroxide (023401)
001812-00195
4219.5014 2 Ib/gal or 19.51 metallic copper equivalent (30Z copper hydroxide) flow-
able concentrate
copper hydroxide (023401)
008901-00007
Issued: 7-22-85 11-023401-31
157
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EPA Index co Pesticide Chemicals
COPPER HYDROXIDE
Listing of Registered Pesticide Products by Formulation (continued)
&219.5014 2.12 Ib/gal or 19.52 metallic copper equivalent (302 copper hydroxide)
flovable concentrate
copper hydroxide (023401)
008901-00017
&217.5014 17.5% metallic copper equivalent (272 copper hydroxide) flovable concen-
trate
copper hydroxide (023401)
008901-00008
&224.4014 3.04 Ib/gal or 24.42 metallic copper equivalent (37.52 copper hydroxide)
flovable concentrate
copper hydroxide (023401)
008901-00020 047916-00047
&201.9516 1.951* metallic copper equivalent (32 copper hydroxide) liquid-ready to
use
copper hydroxide (023401), cuprous oxide (025601) plus tributyltin flu-
oride (083112)
003073-00040
^calculated value based on the ratio of metallic copper to copper
hydroxide
&203.9116 3.912* metallic copper equivalent (61 copper hydroxide) liquid-ready to
use
copper hydroxide (023401), cuprous oxide (025601) plus tributyltin flu-
oride (083112)
003073-00048 003073-00049
Calculated value based on the ratio of metallic copper to copper
hydroxide
&204.5616 4.561* metallic copper equivalent (72 copper hydroxide) liquid-ready to
use
copper hydroxide (023401), cuprous oxide (025601) plus bis(tributyltin)
oxide (083001)
003073-00050
^calculated value based on the ratio of metallic copper to copper
hydroxide
&205.2116 5.211* metallic copper equivalent (82 copper hydroxide) liquid-ready to
use
copper hydroxide (023401) plus copper as metallic from cuprous and
cupric oxide (042403)
003073-00034 003073-00035
Issued: 7-22-85
11-023401-32
158
-------
&205.7316
&205.8616
&213.7016
&214.2616
4215.3016
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Listing of Registered Pesticide Products by Formulation (continued)
5.731* metallic copper equivalent (8.82 copper hydroxide) liquid-ready to
- - *• -
copper hydroxide (023401) plus copper as metallic from cuprous and
cupric oxide (042403)
003073-00016
^calculated value based on the ratio of metallic copper to copper
hydroxide
5.862* metallic copper equivalent (9% copper hydroxide) liquid-ready to
use - - a - * -
copper hydroxide (023401) plus copper as metallic from cuprous and
cupric oxide (042403)
003073-00002
Calculated value based on the ratio of metallic copper to copper
hydroxide
13. 72 metallic copper equivalent (21% copper hydroxide) liquid-ready to
use -
copper hydroxide (023401)
008901-00002
14.262* metallic copper equivalent (21.9% copper hydroxide) liquid-ready
to use ~ -
copper hydroxide (023401), cuprous oxide (025601) plus bis(tributyltin)
oxide (083001)
001609-00011
•^calculated value based on the ratio of metallic copper to copper
hydroxide
15. 3Z* metallic copper equivalent (23.5% copper hydroxide) liquid-ready
to use
copper hydroxide (023401), cuprous oxide (025601) plus bis( tributyltin)
oxide (083001)
001609-00010
^calculated value based on the ratio of metallic copper to copper
hydroxide
9999999 State Label Registrations
CA Reg. No.
007001-07765
FL Reg. No.
005095-03083 005095-07872 014775-08730
014775-08763
NY Reg. No.
038655-10434
Issued: 7-22-85
11-023401-33
014775-08762
159
-------
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Listing of Registered Pesticide Products by Formulation (continued)
OR Reg. No.
001871-08961 002935-06563
IX Reg. No.
006735-04808
Issued: 7-22-85 11-023401-34
160
-------
Listing of
Chemical
Code
014504
Index to Pesticide Chemicals
COPPER HYDROXIDE:
Appendix A
Common Chemical Names Used on the Entry
023401
025601
042403
077501
079401
083001
083112
Common Name
(source)
mancozeb (ISO)
EPA Acceptable
Common/Chemical Name
zinc ion and manganese ethylene
bisdithiocarbamate 802, a coordination
product of manganese 16X, zinc 2%,
ethylene bisdithiocarbamate 622
copper hydroxide
cuprous .oxide
copper as metallic from cuprous and
cupric oxide
sulfur
endosulfan
bis(tributyltin) oxide
tributyltin fluoride
Issued: 7-22-85
11-023401-35
161
-------
/23001AA
FMBCCBM
FMBCLAT
/03001AA
FBAZPDZ
FBADMCB
FBAZCEL
/04001AA
FMAGPDZ
FDAANAF
FBANEBI
FAAANAK
FDAGPCN
SPA Index Co Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Sice/Formulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Alfalfa
Cercospora leaf spot
Leptosphaerulina leaf spot
(50Z WP)
007001-00065 008901-00001 045002-00001 048957-00014
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Almond
Bacterial shoot blight (Pseudomonas)
Brown rot blossom blight (Monilinia)
Shothole (Coryneum blight)
(201 WP)
008901-00022
008901-00001 045002-00001 048957-00014
(502 WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Apple
Blicter spot (Pseudomonas)
European canker (Nectria)
Fire blight (Ervinia)
Northwestern anthracnose (Neofabraea)
Phytophthora collar rot
(50Z WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Issued: 7-22-85
11-023401-36
162
-------
/0500IAA
FBADHCB
FBAZCEL
/28000AA
FEAJSCB
/06002AA
FIEQPOZ
FMBOCBM
/28063AA
FCADHAM
FMBCSBL
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Forraulation/Registration Number (continued)
Apricot
Brown rot blossom blight (Monilinia)
Shothole (Coryneum blight)
(20Z WP)
008901-00001 045002-00001 048957-00014
008901-00022
(50Z WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Avocado
Scab (spot anthracnose) (Sphaceloma)
(50% WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Banana
Black pitting (Piricularia grisea)
Sigatoka disease (Cercospora leaf spot)
(50Z WP)
007001-00065 008901-00001 045002-00001
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Barley
Helminthosporium leaf blotch
Septoria leaf blotch
(502 WP)
007001-00065 008901-00001 045002-00001
048957-00014
048957-00014
048957-00014
Issued: 7-22-85
11-023401-37
163
-------
/2800LAA
FBZFXAV
FBZRPGG
/01002AA
FMAMMCO
FMAMSBL
/13005AA
FFABPAU
I?A Index co Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Barley (continued)
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Beans
Bacterial blight (comon) (Xanthomonas)
Halo blight (Pseudomonas)
(50Z WP)
007001-00065 008901-00001 04S002-00001
048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(17.51 F1C)
008901-00008
Blackberry
Leaf and cane spot
(Mycosphaerella) (Septoria)
(502 WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Broccoli
Downy mildew (Peronospora)
(50Z WP)
007001-00065 008901-00001
048957-00014
045002-00001 048957-00014
Issued: 7-22-85
11-023401-38
164
-------
/13006AA
FFABPAU
/13007AA
FIAFXAA
FFABPAU
FMBCAAX
/10002AA
FFABPEA
EPA Index Co Pesticide Chemicals
CG??iR HYDROXIDE
Appendix B
Listing by Sice/Pest and Site/Formulation/Registration Number (continued)
Broccoli (continued)
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Brussels Sprouts
Downy mildew (Peronospora)
(50% WP)
007001-00065 008901-00001
045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal FIG)
008901-00020 047916-00047
Cabbage
Black rot (Xanthomonas)
Downy mildew (Peronospora)
Leaf spot (Alternaria)
(50% WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Cantaloupe
Downy mildew (Pseudoperonospora)
(50Z WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
045002-00001 048957-00014
048957-00014
Issued: 7-22-85
11-023401-39
165
-------
045002-00001 048957-00014
045002-00001 048957-00014
Ł?A Index Co Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
/28073AA Carrots
FBAMCBM Early blight (Cercospora)
(50J WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/13008AA Cauliflower
FFABPAU Downy mildew (Peronospora)
(50* WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/28003AA Celery
FBAAPDZ Bacterial.blight (Pseudomonas)
FBAMCBM Early blight (Cercospora)
FBASSBL Late blight (Septoria)
(50Z WP)
007001-00065 008901-00001 045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/05002AA Cherry
FBAOMCB Brown rot blossom rot (Monilinia)
FBAAPDZ Dead bud (Pseudomonas)
FBAZCEL Shothole (Coryneum blight)
(501 WP)
007001-00065 008901-00001 045002-00001 048957-00014
Issued: 7-22-85
11-023401-40
166
-------
/02000AA
FGAJPCN
FMAYMCO
FIELDAP
FMBIMCO
FAABEAH
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix &
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Cherry (continued)
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-OOOA7
Citrus Fruits
Brown rot gutmnosis (Phytophthora)
Greasy spot (Mycosphaerella)
Melanose (Diaporthe)
Pink pitting (Mycosphaerella)
Scab (spot anthracnose) (Elsinoe)
(4.4Z WP)
002124-00799
002124-00801
002124-00800
(4.52 WP)
002124-00797
(4.6Z WP)
002124-00803
(9.5Z WP)
002124-00798
(9.9Z WP)
002124-00796
(10.42 WP)
002124-00802
(20Z WP)
008901-00022
(502 WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Issued: 7-22-85
008901-00001 045002-00001 048957-00014
11-023401-41
-------
707001AA
FIFAPLG
/07002AA
FJAGHAO
FMBACBH
FGAOCEF
/01010AA
FIBFQBB
/10010AA
FMABPDZ
FFABPEA
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Cocoa
Black pod (Phytophthora palmivora)
(50Z WP)
007001-00065 008901-00001 045002-00001
048957-00014
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Coffee
Coffee leaf rust (Hemileia) (in Brazil)
Iron spot (Cercospora)
Pink disease (Corticium)
(2.7Z D)
007001-00224
(50Z WP)
007001-00065
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Cranberry
Fruit rot
(50Z WP)
007001-00065
008901-00001 045002-00001 048957-00014
008901-00001 045002-00001 048957-00014
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Cucumber
Angular leaf spot (Pseudomonas)
Downy mildew (Pseudoperonospora)
(50Z WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
048957-00014
Issued: 7-22-85
11-023401-42
163
-------
/01011AA
FMBCQBB
/11001AA
FAAACDP
FBAMAAX
FBAAPBU
/03005AA
FBAAXAA
/01013AA
FMBCQBB
EPA Index co Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Foraulation/Registration Number (continued)
Cucumber (continued)
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Currant
008901-00001 045002-00001 048957-00014
Leaf spot
(50% WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Eggplant
Anthracnose (Colletotrichum)
Early blight (Alternaria)
Phomopsis blight
(502 WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal FIG)
008901-00020 047916-00047
Filbert
Bacterial blight (Xanthomonas)
(50Z WP)
007001-00065 008901-00001 045002-00001
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
045002-00001 048957-00014
048957-00014
Gooseberry
Leaf spot
(50Z WP)
007001-00065
008901-00001 045002-00001 048957-00014
Issued: 7-22-85
11-023401-43
169
-------
/01014AA
FIBFGBG
FFABPCV
FFACUAfi
/10005AA
FFABPEA
/08020AA
FFABPEA
E?A Index to Pe.3Ci.cide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Fonnulation/RegisCration Number (continued)
Gooseberry (continued)
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Grapes
Black rot (Guignardia)
Downy mildew (Plasmopara)
Powdery mildew (Uncinula)
(50* WP)
007001-00065 008901-00001
045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Honeydew Melons
Downy mildew (Pseudoperonospora)
(50Z WP)
007001-00065 008901-00001 045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Hops
Downy mildew (Pseudoperonospora)
(50Z WP)
007001-00065 008901-00001 045002-00001
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Issued: 7-22-85
11-023401-44
170
-------
/13020AA
FFABBBA
/06007AA
FAAAGAP
/10006AA
FFABPEA
/OS003AA
FMCBXAA
FBADMCB
FEAGTAB
FBAZCEL
iFA Ind^x r0 Pesticide Chenicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Lettuce
Downy mildew (Bremia)
(50% WP)
008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Mango
Anthracnose (Glomerella)
(50% WP)
007001-00065 008901-00001
045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Muskmelons
Downy mildew (Pseudoperonospora)
(50% WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Nectarines
Bacterial fruit and leaf spot (Xanthomonas)
Brown rot blossom blight (Monilinia)
Leaf curl (Taphrina)
Shothole (Coryneum blight)
(20Z WP)
008901-00022
048957-00014
(50% WP)
007001-00065
Issued: 7-22-85
008901-00001 045002-00001 048957-00014
11-023401-45
171
-------
/28014AA
FMBHCFK
/14011AA
FFABPAU
FCAEAAX
/05004AA
FMCBXAA
FBADMCB
FEAGTAB
FBAZCEL
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Nectarines (continued)
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Olive
Peacock spot (Cycloconium)
(50Z WP)
007001-00065 008901-00001
045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Onion
Downy mildew (Peronospora)
Purple blotch (Alternaria)
(50Z WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Peaches
Bacterial fruit and leaf spot (Xanthomonas)
Brown rot blossom blight (Monilinia)
Leaf curl (Taphrina)
Shothole (Coryneum blight)
(20Z WP)
008901-00022
045002-00001
(50Z WP)
007001-00065
008901-00001 045002-00001 048957-00014
Issued: 7-22-85
11-023401-46
172
-------
"EPA Incex Co Pescixide Chemicals
CO??EX HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Peaches (continued)
(1 Ib/gal FIG)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/28015AA Peanuts
FMBCCBM Cercospora leaf spot
(1.6Z D)
008901-00004
(2.6Z D)
008901-00003
(321 WP)
008901-00010
(50Z WP)
007001-00065 008901-00001 045002-00001 048957-00014
(0.53 Ib/gal F1C)
001812-00215
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(13.4Z F1C)
001812-00195
(17.5Z F1C)
008901-00008
(13.7Z RTU)
008901-00002
/040C3AA Pear
FHAHPDZ Bacterial blast (Pseudomonas)
FBANEBI Fire blight (Erwinia)
(2.6Z D)
008901-00003
Issued: 7-22-85
11-023401-47
173
-------
ŁPA Index Co Pesticide Chemicals
CC-??ŁR HiJRCXIDt
Appendix 5
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Pear (continued)
(2.72 D)
007001-00224
(202 WP)
008901-00022
(502 WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/28016AA Peas
FFACEBJ Powdery mildew (Erysiphe)
(502 WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(17.5Z F1C)
008901-00008
/28017AA Peppers
FMAAXAA Bacterial spot (Xanthomooas)
(2.72 D)
007001-00224
008901-00001 045002-00001 048957-00014
045002-00001 048957-00014
(502 WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
008901-00001 045002-00001
Issued: 7-22-85
11-023401-48
174
-------
/14013AA
FBANAAX
FBASPCN
/10011AA
FEAJCCV
/10012AA
FEAJCCV
045002-00001 048957-00014
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Peat and Site/Forraulation/Registration Number (continued)
Peppers (continued)
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(17.51 F1C)
008901-000.08
Potato
Early blight (Alternaria)
Late blight (Phytophthora)
(50% WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Pumpkin
Powdery mildew (Erysiphe)
(502 WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Squash
Powdery mildew (Erysiphe)
(50% WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
045002-00001 048957-00014
045002-00001 048957-00014
Issued: 7-22-85
11-023401-49
175
-------
/01016AA
FBATDAH
FMBCMCO
/28020AA
FHfiCCBM
/1100SAA
FMBPPDZ
FMAAXAA
FBAMAAX
EPA Inoex to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Squash (continued)
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Strawberry
Leaf blight (Dendrophoma)
Leaf spot (Mycosphaerella)
(502 WP)
007001-00065 008901-00001 045002-00001 048957-00014
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Sugar Beets
Leaf spot (Cercospora)
(50Z WP)
007001-OOQ65 008901-00001
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(17.52 F1C)
008901-00008
(13.72 RTU)
008901-00002
Tomato
Bacterial speck (Pseudomonas)
Bacterial spot (Xanthomonas)
Early blight (Alternaria)
(502 WP)
007001-00065 008901-00001
(1 Ib/gal F1C)
008901-00028
045002-00001 048957-00014
045002-00001 048957-00014
Issued: 7-22-85
II-O23401-50
176
-------
/03009AA
FBZAXAA
/10008AA
FAAACDP
FFABPEA
/28065AA
FCADHAM
FMBCSBL
-.-A Index Co Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
Tomato (continued)
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(17.5Z F1C)
008901-00008
Walnut
Walnut blight (Xanthomonas)
(202 WP)
008901-00022
008901-00001 045002-00001 048957-00014
(50Z WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Watermelons
Anthracnose (Colletotrichum)
Downy mildew (Pseudoperonospora)
(502 WP)
007001-00065 008901-00001 045002-00001 048957-00014
(1 Ib/gal F1C)
. 008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
Wheat
Helminthosporium leaf blotch
Septoria leaf blotch
(50Z WP)
007001-00065 008901-00001 045002-00001 048957-00014
Issued: 7-22-85
11-023401-51
177
-------
/28063AA
FLATTAQ
/28072AA
FKABADD
FKABPES
/28065AA
FLATTAQ
EPA Iniex to Pesticide Cne.nicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Wheat (continued)
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal F1C)
008901-00020 047916-00047
(Agricultural Seed Treatment)
Barley
Bacterial leaf blight (Pseudomonas syringae)
Bacterial leaf streak (Xanthomonas translucens)
Common bunt (Tilletia caries)
(2.12 Ib/gal or 19.5Z F1C)
008901-00017
Rice
Seed rot
(Achlya) (Pythium)
(2.12 Ib/gal or 19.5Z F1C)
008901-00017
Wheat
Bacterial leaf blight (Pseudomonas syringae)
Bacterial leaf streak (Xanthomonas translucens)
Common bunt (Tilletia caries)
(2.12 Ib/gal or 19.5Z F1C)
008901-00017
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
/34147AA Adam's Needle
FMBCCBM Leaf spot (Cercospora)
FMBCSBL Leaf spot (Septoria)
(1 Ib/gal F1C)
008901-00028
Issued: 7-22-85
11-023401-52
178
-------
EPA Index to Pesticide Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
/34018AA Aralia
FMBCAAX Leaf spot (Alternaria)
FMBCCBM Leaf spot (Cercospora)
FMBCXAA Leaf spot {Xanthomonas)
(1 Ib/gal F1C)
008901-00028
/34022AA Azalea
FBADBAW Botrytis blossom blight
FBBJBAW Botrytis leaf and stem blight
FMBCCBM Leaf spot (Cercospora)
FDACPCN Phytophthora dieback
FFACQBB Powdery mildew
(1 Ib/gal F1C)
008901-00028
/31034AA Begonia
FAAAGAN Anthracnose (leaf spot) (Gloeosporium)
FMZCXAA Bacterial leaf spot (Xanthomonas)
(1 Ib/gal F1C)
008901-00028
/31057AA Carnation
FBATAAX Alternaria blight (leaf spot)
FMZCPDZ Bacterial leaf spot (Pseudomonas)
FBAABAW Botrytis blight
(1 Ib/gal F1C)
008901-00028
/3106SAA Chrysanthemum
FBAABAW Botrytis blight
FMBCSBL Leaf spot (Septoria)
(1 Ib/gal F1C)
008901-00028
/34045AA Cotoneaster
FBAABAW Botrytis blight
(1 Ib/gal F1C)
008901-00028
/31093AA Easter Lily
FBAABAW Botrytis blight
(1 Ib/gal F1C)
008901-00028
/34052AA English Ivy
FMZCXAA Bacterial leaf spot (Xanthomonas)
(1 Ib/gal F1C)
008901-00028
Issued: 7-22-85
11-023401-53
179
-------
/34053AA
FAAACDP
FBAABAW
/31111AA
FBAABAW
/35191AA
PFOABBB
/34106AA
FBBJVAL
/34109AA
FDAfiPBU
/3115SAA
FMBCXAA
EPA Index to Pesticide Chenicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Euonyrnus
Anthracnose (Colletotrichum)
Botrytis blight
(1 Ib/gal F1C)
008901-00028
Gladiolus
Botrytis blight
(1 Ib/gal F1C)
008901-00028
Live Oak
008901-00001 045002-00001 048957-00014
Ball moss
(50Z WP)
007001-00065
(1 Ib/gal F1C)
008901-00028
(2 Ib/gal F1C)
008901-00007
(3.04 Ib/gal FIG)
008901-00020 047916-00047
Pachysandra
Volutella leaf and stem blight
(1 Ib/gal FIG)
008901-00028
Periwinkle
Canker and dieback (Phomopsis)
(1 Ib/gal FIG)
008901-00028
Philodendron
Bacterial leaf spot (Xanthomonaa)
(50Z WP)
007001-00065 008901-00001 045002-00001
(1 Ib/gal FIG)
008901-00028
(2 Ib/gal FIG)
008901-00007
(3.04 Ib/gal FIG)
008901-00020 047916-00047
048957-00014
Issued: 7-22-85
11-023401-54
180
-------
/34058AA
FBANEBI
FEAJFAM
/34120AA
FMAEDBS
FFACQBB
/35119AA
FAAAGAT
tPA Index to Pestici.ce Chemicals
COPPER HYDROXIDE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
Pyracantha
Fire blight (Erwioia)
Scab (Fusicladium)
(1 Ib/gal F1C)
008901-00028
Rose
Black spot (Diplocarpon)
Powdery mildew
(1 Ib/gal F1C)
008901-00028
Sycamore
Anthracnose (Gnomonia)
(50X WP)
007001-00065 008901-00001
045002-00001 048957-00014
(1 Ib/gal FIG)
008901-00028
(3.04 Ib/gal F1C)
008901-00020 047916-00047
/690020A
IAFAAAA
AQUATIC NON-FOOD
(Antifouling Treatments)
Boat Bottoms/Hulls (fiberglass) (primed/unprimed)
Fouling organisms
(1.95Z RTU)
003073-00040
(3.91Z RTU)
003073-00048
(4.56Z RTU)
003073-00050
(5.211 RTU)
003073-00034
(5.73Z RTU)
003073-00016
(5.86Z RTU)
003073-00002
003073-00049
003073-00035
Issued: 7-22-85
11-023401-55
181
-------
C.PA Index to Pesticide Cnemicals
CJPPtR HYDROXIDE
CFR 40 Section 180.1001 - exemption from tolerance.
The ratio of metallic copper to copper hydroxide used to calculate formu-
lations and dosages was primarily based on information from Reg. No. 8901-
12 and 8901-5.
Currently dated (6/23/71) labeling for Reg. No. 3073-16 gives the percent
of Kocide on the label (10%), not the percent of copper hydroxide (8.8Z).
The Agency has requested the necessary change by the registrant.
NOTE: For all labels with Philodendron, a tank mix with mancozeb is rec-
ommended. There do not seem to be any current mancozeb labels that claim
control of Bacterial leaf spot on Philodendron. Perhaps other data
exists.
Issued: 7-22-85 II-023401-i
182
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C076102
EPA Index to Pesticide Chemicals
COPPER NITRATE*
TYPE PESTICIDE; Fungicide, Antimicrobial
FORMULATIONS; RTU (0.042, 0.62)
GENERAL WARNINGS AND LIMITATIONS; Formulations may cause irritation of
skin. In case of contact, wash with water. Undiluted formulations will
become unstable and less active if allowed to contact iron, copper,
bronze, tin, brass, aluminum, lead, zinc or chrome.
Dosage rates and formulations are given in metallic copper equivalent.
Definition of Terms;
MAI - multiple active ingredients
ppm - parts per million
/65028MA
/65034MA
/65029MA
DBABAM
FYAFQBB
Site and Pest
AQUATIC NON-FOOD
(Aquatic Sites)
Heat Exchanger Water Systems
Industrial Ponds and Reservoirs
Industrial Processing Water
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Slime-forming bac-
teria
Slime-forming fungi
[MAI]
0.008-0.032
oz/10,000
gal water
or
0.006-0.024
ppm
(0.6% RTU)
Clean heavily contaminated systems
prior to treatment.
Water treatment. Slug feed initial-
ly. For systems that are not highly
contaminated, treatment should be
made at a location just after a pump
where turbulence or high velocity
flow takes place. Repeat slug
treatment after 1 week. The makeup
water should be treated at the low
rate.
Formulated with silver nitrate.
/65019MA
DBABAAA
FYAFQBB
Industrial Water Cooling Tower
Systems
Slime-forming bac-
teria
Slime-forming fungi
[MAI]
0.008-0.032
oz/10,000
gal water
or
0.006-0.024
ppm
(0.62 RTU)
Clean heavily contaminated systems
prior to treatment.
Water treatment. Slug feed initial-
ly. Repeat after 1 week. The make-
up water should be treated at the
low rate.
Formulated with silver nitrate.
*cupric nitrate
Issued: 7-22-85
II-076102-1
193
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Site and Pest
EPA Index to Pesticide Chemicals
COPPER NITRATE
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
/65008MA
Pulp and Paper Mill Systems
DBABAAA
FYAFQBB
Slime-forming bac-
teria
Slime-forming fungi
[MAI]
General
machine
treatment:
0.0015-0.03
ppm by
weight of
furnish
or
Broke:
0.006-0.06
ppm by
weight of
broke
(0.6Z RTU)
[MAI]
(0.04Z RTU)
May be used as a slimicide in the
manufacture of paper and paperboard
that contact food in accordance
with prescribed conditions (CFR 21,
Indirect Food Additives, Section
176.300).
Water treatment. General machine
treatment. Continuous feed by pump.
Add at 1 or more places, such as the
beater, hydropulper, before or after
the refiners, storage chests, ma-
chine chest, head box wire pit and
fan pump. As an alternative, slug
feed using equivalent amounts added
at intervals.
OR
Broke. In some mills, treatment is
based on the highly contaminated
broke system. The amount added de-
pends upon the microbiological con-
tamination. For highly contaminated
systems start at the higher dose
level then reduce toward the lower
end of the range as control is
achieved.
Formulated with silver nitrate.
Water treatment.
Formulated with silver nitrate.
Issued: 7-22-85
II-076102-2
1 O A
~
-------
EPA Index to Pesticide Chemicals
COPPER NITRATE
Listing of Registered Pesticide Products by Formulation
&200.0416 0.04% liquid-ready to use
copper nitrate (076102) plus silver nitrate (072503)
004855-00006
&200.6016 0.6% liquid-ready to use
copper nitrate (076102) plus silver nitrate (072503)
004855-00004
Issued: 7-22-85 II-076102-3
185
-------
/65028MA
DBABAAA
FYAFQBB
/65034MA
DBABAAA
FYAFQBB
/65029MA
DBABAAA
FYAFQBB
/65019MA
DBABAAA
FYAFQBB
/65008MA
DBABAAA
FYAFQBB
EPA Index to Pesticide Chemicals
COPPER NITRATE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number
AQUATIC NON-FOOD
(Aquatic Sites)
Heat Exchanger Water Systems
Slime-forming bacteria
Slime-forming fungi
(0.62 RTU)
004855-00004
Industrial Ponds and Reservoirs
Slime-forming bacteria
Slime-forming fungi
(0.62 RTU)
004855-00004
Industrial Processing Water
Slime-forming bacteria
Slime-forming fungi
(0.62 RTU)
004855-00004
Industrial Water Cooling Tower Systems
Slxme-forming bacteria
Slime-forming fungi
(0.62 RTU)
004855-00004
Pulp and Paper Mill Systems
Slime-forming bacteria
Slime-forming fungi
(0.042 RTU)
004855-00006
(0.62 RTU)
004855-00004
Issued: 7-22-85
II-076102-4
186
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EPA Index to Pesticide Chemicals
COPPER NITRATE
Auxiliary Documentation
Please note that the Shaughnessy number 076102 includes cupric nitrate as
a synonym for copper nitrate. The Acceptable Chemical Names book ('Bla-
lock'), however, gives a separate accession number for each name. Osten-
sibly, this means both names should appear on the label.
Concerning Reg. No. 4855-4:
Density is 8.75 Ib/gal, or 0.84 oz/gal of metallic copper.
The Pulp and Paper Mill entry is derived from the last correspondence
(on 9/28/72) by the Agency to the registrant (see attachment to label).
Please also note the slightly different caution statements of the labels:
4855-4 - May cause temporary discoloration and/or mild irritation of
skin. In case of contact, wash with water.
4855-6 - May cause irritation of skin and eyes. In case of contact,
wash with water.
Issued: 7-22-85 II-076102-i
187
-------
EPA Index to Pesticide Chemicals
COPPER OXALATE*
TYPE PESTICIDE: Repellent
FORMULATIONS; D (4Z)
GENERAL WARNINGS AND LIMITATIONS; The dosage and formulation are given
in active ingredient (copper oxalate).
/28005AA
VIVFABA
Site and Pest
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Corn
Dosages and Tolerance. Use, Limitations
Formulation(s)
Crows
0.32 oz/bu
seed
<4Z D)
(See Auxiliary Documentation for
tolerance information).
Seed treatment through 0.32 ounce
per bushel.
Do not use treated seed for food or
feed purposes.
Seed treatment. Mix in a suitable
container with seed until all *eed
is colored. Seed may be planted
immediately or stored.
*cupric oxalate
Issued: 7-22-85
II-023305-1
-------
EPA Index to Pesticide Chemicals
COPPER OXALATE
Listing of Registered Pesticide Products by Formulation
&004.0003 42 dust
copper oxalate (023305)
007832-00002
9999999 State Label Registration
CA Reg. No.
011117-06024
Issued: 7-22-85 II-023305-2
189
-------
EPA Index to Pesticide Chemicals
COPPER OXALATE
AUXILIARY DOCUMENTATION
No tolerance can be located in CFF 40.
Please note that the formulation is colored.
Issued: 7-22-85 II-023305-i
190
-------
C023501
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
TYPE PESTICIDE; Fungicide
FORMULATIONS:
Tech (58.IX)
WP (472, 502, 53%)
F1C (20.582)
GENERAL WARNINGS AND LIMITATIONS: Dosages and formulations are given in
metallic copper equivalents. The percent of copper oxychloride for each
label is given in the Listing of Registered Pesticide Products by Formu-
lation (page 6).
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulation(s)
/28073AA
FBAMCBM
FBASAAX
728003AA
TERRESTRIAL FOOD CROP
(Agricultural Crops)
General Warnings and Limitations: Apply for thorough coverage using
dilute or concentrate ground equipment or by aircraft.
Carrots
Early blight
(Cercospora)
Late blight
(Alternaria)
Celery
FBAMCBM
FBASSBL
Early blight
(Cercospora)
Late blight
(Septoria)
Exempt
No preharvest interval through
21.25 pounds per acre.
1.41-2.125 Foliar application. Apply when dis-
lb/A ease is first reported in area. Re-
(472, 502, peat at 7 to 10 day intervals as
53% WP) needed.
Exempt
No preharvest interval through 3.29
pounds per acre.
Remove residues by washing and
stripping.
1.41-3.29 Foliar application. Apply when
lb/A plants are 2 to 3 inches tall or
(472, 50%, before disease appears. Repeat at
532 WP) 5 to 14 day intervals.
Issued: 7-22-85
II-023501-1
191
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
/02000AA
FMAYMCO
FIBLDAP
FAABEAH
Site and Pest
Citrus Fruits
Greasy spot
(Mycosphaerella)
Melanose
(Diaporthe)
Scab (spot anthrac-
nose) (Elsinoe)
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Exempt
No preharvest interval through 3.18
pounds per acre.
Do not use in areas where copper
injury is known to occur or where
fumigation with hydrogen cyanide is
practiced.
3.125 Ib/A Dormant and foliar application. Ap-
(50% WP) ply beginning in dormant season.
Repeat at two-thirds petal fall,
when fruit is 0.5 inch in diameter
and as needed thereafter.
2.35-3.055 Use limited to FL.
lb/500 gal/A Dormant and foliar application. Ap-
(47% WP) ply in dormant season before spring
flush. Repeat within 2 weeks after
petal fall. For melanose and scab,
repeat in 4 weeks at low rate.
3.18 lb/500
gal
(53% WP)
Dormant and foliar application. Ap-
ply in dormant season before spring
growth. Repeat 1 to 3 weeks after
petal fall. For melanose and scab,
repeat in 4 weeks.
/10010AA Cucumber
/10001AA Melons
FMABPDZ Angular leaf spot
(Pseudomonas)
FAAACDP Anthracnose
(Colletotrichum)
FFABPEA Downy mildew
(Pseudoperono-
spora)
FEAJCCV Scab (Cladosporium)
/10008AA (watermelons)
FFABPEA Downy mildew
(Pseudoperono-
spora)
FBAQMCO Gummy stem blight
(Mycosphaerella)
2.12 Ib/A
(53% WP)
0.72 lb/100
gal/A
(20.58% F1C)
Exempt
No preharvest interval through 2.12
pounds per acre.
Foliar application. Apply when dis-
ease is first reported in area. Re-
peat at 7 to 10 day intervals as
needed.
Use limited to FL.
Foliar application. Apply before
disease appears. Repeat at 6 to 10
day intervals as needed.
Issued: 7-22-85
II-023501-2
192
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
/05004AA
FEAGTAB
/28015AA
FMBCCBM
/28017DA
/28017CA
FKAAQBB
/14013AA
FBAMAAX
FBASPCN
Site ana Pest
Peach
Leaf curl
(Taphrina)
Peanuts
Cercospora leaf
spot
Dosages and Tolerance, Us"e, Limitations
Fonnulation(s)
Exempt
Do not apply after petal fall
through 2.125 pounds per 100 gal-
lons.
2.125 lb/100 Foliar application. Apply in bloom
gal and petal fall.
(50% WP)
2.12 lb/100 Delayed dormant and foliar applica-
gal tion. Apply at prebloom to petal
(53% WP) fall.
Exempt
No preharvest interval through 0.72
pound per acre.
0.72 lb/5-20 Foliar application. Apply as soon
gal/A as first leaf spots are observed.
(20.58% F1C) Repeat at 10 to 14 day intervals as
needed.
Peppers (transplants in cold
frames, greenhouses, etc.)
Damping-off
2.125 lb/100
(50% WP)
2.12 lb/100
gal
or
1.06 oz/3 gal
(53% WP)
Potato
Early blight
(Alternaria)
Late blight
(Phytophthora)
1.41-3.71
Ib/A
(47%, 50%,
53% WP)
Exempt
Soil application to transplants.
Apply as a light spray to soil
around plants. Apply when plants
emerge and repeat at 4 to 7 day in-
tervals until transplanting.
Apply as above except also spray
plants lightly but thoroughly.
Exempt
No preharvest interval through 3.71
pounds per acre.
Foliar application. Apply before
disease appears. Repeat at 7 to 10
day intervals as needed. Apply high
rate at 7 day intervals if late
blight infection is severe on large
plants.
Issued: 7-22-85
II-023501-3
193
-------
/28020AA
FMBCCBM
Site and Pest
Sugar Beets
Leaf spot
(Cercospora)
/11005AA
FMAAXAA
Tomato
Bacterial spot
(Xanthomonas)
FBAMAAX
FBA5PCN
FMBCSBL
/11005DA
/11005CA
FKAAQBB
Early blight
(Alternaria)
Late blight
(Phytophthora)
Leaf spot
(Septoria)
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 3.18
pounds per acre.
3.0-3.18 Ib/A Foliar application. Apply before
(50%, 532 disease appears. Repeat at 7 to 10
WP) day intervals.
1.88 Ib/A
(47% WP)
2.65-3.18
Ib/A
(53% WP)
1.41-3.71
Ib/A
(47%, 50%,
53% WP)
Foliar application. Apply when dis-
ease symptoms first appear. Repeat
at 7 to 10 day intervals for as long
as disease threatens.
Exempt
No preharvest interval through 3.71
pounds per acre.
Foliar application. In seed beds,
apply after the first leaves appear
at 5 to 6 day intervals. In the
field, apply if disease is expected
at 5 to 7 day intervals. Use the
shorter interval during periods of
rainy weather.
Foliar application. Apply before
disease appears. Repeat at 7 to 14
day intervals. If late blight is
severe, apply at high rate on large
plants.
(tomato (transplants in cold
frames, greenhouses, etc.))
Damping-off 2.125 lb/100
gal
(50% WP)
2.12 lb/100
gal
or
1.06 oz/3 gal
(53% WP)
Soil application to transplants.
Apply as a light spray to soil
around plants. Apply when plants
emerge and repeat at 4 to 7 day in-
tervals until transplanting.
Apply as above except also spray
plants lightly but thoroughly.
Issued: 7-22-85
II-023501-4
194
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER OXYCHLOR1DE
Dosages and Tolerance, Use, Limitations
Formulation(s)
/34022AA
FBAIBBC
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Azalea
Bud and twig blight 2.12 lb/100 Foliar application. Apply when dis-
(Briosia)
gal ease is first reported in area. Re-
(52% WP) peat at 7 to 10 day intervals or as
needed.
/34109AA Periwinkle
FDABPBU Canker (dieback)
(Phomopsis)
2.12 lb/100 Foliar application. Apply when dis-
gal ease is first reported in area. Re-
(53% WP) peat at 7 to 10 day intervals or as
needed.
/28017CA
/11005CA
GREENHOUSE FOOD CROP
(Agricultural Crops)
Peppers
Tomato
Refer to TERRESTRIAL FOOD CROP. (Agricultural
Crops), Peppers (transplants in cold frames,
greenhouses, etc.) for use and limitation infor-
mation.
Refer to TERRESTRIAL FOOD CROP, (Agricultural
Crops), Tomato (transplants in cold frames, green-
houses, etc.) for use ana limitation information.
9001500
AAAAAAA
AERIAL AND TANK MIX APPLICATIONS
Aerial Application
Refer to
TERRESTRIAL FOOD CROP
(Agricultural Crops)
All sites except Cucumber, Melons,
Peppers (transplants), Tomato, and
Tomato (transplants)
Issued: 7-22-85
II-023501-5
195
-------
&058.1001
&047.0006
&050.0006
4053.0006
&220.5814
EPA Index to Pesticide Chemicals
COPPER OXXCHLORIDE
Listing of Registered Pesticide Products by Formulation
58.1Z metallic copper equivalent (98.752 copper oxychloride) technical
chemical
copper oxychloride (023501)
000279-02811
47% metallic copper equivalent (80% copper oxychloride) wettable powder
copper oxychloride (023501)
007969-00027
50% metallic copper equivalent (85.03%* copper oxychloride) wettable pow-
der
copper oxychloride (023501)
007001-00256
*calculated value based on the ratio of metallic copper to copper
oxychloride
53t metallic copper equivalent (90.14%* copper oxychloride) wettable pow-
der
copper oxychloride (023501)
000279-02797
^calculated value based on the ratio of metallic copper to copper
oxychloride
20.582* metallic copper equivalent (35% copper oxychloride) flovable con-
centrate
copper oxychloride (023501)
048273-00002
^calculated value based on the ratio of metallic copper to copper
oxychloride
9999999 State Label Registration
OR Reg. No.
001871-08960
Issued: 7-22-85
II-023501-6
196
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EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
/28073AA Carrots
FBAMCBM Early blight CCercospora)
FBASAAX Late blight (Alternaria)
(47% WP)
007969-00027
(50% WP)
007001-00256
(53% WP)
000279-02797
/28003AA Celery
FBAMCBM Early blight (Cercospora)
FBASSBL Late blight (Septoria)
(472 WP)
007969-00027
(50% WP)
007001-00256
(53% WP)
000279-02797
/02000AA Citrus Fruits
FMAYMCO Greasy spot (Mycosphaerella)
FIBLDAP Melanose (Diaporthe)
FAABEAH Scab (spot anthracnose) (Elsinoe)
(47% WP)
007969-00027
(50% WP)
007001-00256
(53% WP)
000279-02797
/10010AA Cucumber
FMABPDZ Angular leaf spot (Pseudomonas)
FAAACDP Anthracnose (Colletotrichum)
FFABPEA Downy mildew (Pseudoperonospora)
FEAJCCV Scab (Cladosporium)
(53% WP)
000279-02797
Issued: 7-22-85
II-023501-7
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
/10001AA Melons
FMABPDZ Angular leaf spot (Pseudomonas)
FAAACDP Anthracnose (Colletotrichum)
FFA5PEA Downy mildew (Pseudoperonospora)
FEAJCCV Scab (Cladosporium)
(532 WP)
000279-02797
/10008AA (watermelons)
FFABPEA Downy mildew (Pseudoperonospora)
FBAQMCO Gummy stem blight (Mycosphaerella)
(20.58% F1C)
048273-00002
/05004AA Peach
FEAGTAB Leaf curl (Taphrina)
(502 WP)
007001-00256
(532 WP)
000279-02797
/28015AA Peanuts
FMBCCBM Cercospora leaf spot
(20.58% F1C)
048273-00002
/28017DA Peppers (transplants in cold frames, greenhouses, etc.)
FKAAQBB Damping-off
(50% WP)
007001-00256
(53% WP)
000279-02797
/14013AA Potato
FBAMAAX Early blight (Alternaria)
FBASPCN Late blight (Phytophthora)
(472 WP)
007969-00027
(50% WP)
007001-00256
(532 WP)
000279-02797
Issued: 7-22-85
II-023501-8
198
-------
/28020AA
FMBCCBM
/11005AA
FMAAXAA
FBAMAAX
FBASPCN
FMBCSBL
/11005DA
FKAAQBB
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Sugar Beets
Leaf spot (Cercospora)
(47% WP)
007969-00027
(50% WP)
007001-00256
(53% WP)
000279-02797
Tomato
Bacterial spot (Xanthomonas)
Early blight (Alternaria)
Late blight (Phytophthora)
Leaf spot (Septoria)
(472 WP)
007969-00027
(502 WP)
007001-00256
(53% WP)
000279-02797
(tomato (transplants in cold frames, greenhouses, etc.))
Damping-off
(50% WP)
007001-00256
(53% WP)
000279-02797
/34022AA
FBAIBBC
/34109AA
IDABPBU
TERRESTRIAL NON-FOOD CROP
(Ornamental Plants and Forest Trees)
Azalea
Bud and twig blight (Briosia)
(53% WP)
000279-02797
Periwinkle
Canker (dieback) (Phomopsis)
(53% WP)
000279-02797
Issued: 7-22-85
11-023501-9
199
-------
/28017CA
FKAAQBB
/11005CA
FKAAQBB
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
GREENHOUSE FOOD CROP
(Agricultural Crops)
Peppers
Damping-off
(50% WP)
007001-00256
(53% WP)
000279-02797
Tomato
Damping-off
(50% WP)
007001-00256
(53% WP)
000279-02797
Issued: 7-22-85
11-023501-10
200
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE
CFR 40 Section 180.1001 - exemption from tolerance.
The percentage of metallic copper in copper oxychloride (58.8%) was calcu-
lated based on information from Reg. Nos. 279-2811 and 7969-27.
Dosages from Reg. No. 48273-2 for peanuts and watermelons were based on
label information that indicated 2.5 pints of product are about equal to
3.5 pounds.
No reference in the literature for the use of copper oxychloride for Bac-
terial spot (Xanthomonas) could be located.
Issued: 7-22-85 II-023501-i
201
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EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
TABLE OF CONTENTS
Site Name Page
TERRESTRIAL FOOD CROP 1
(Agricultural Crops) 1
Almond 1
Apple 2
Apricot 3
Beans 3
Beets 4
Blackberry 4
Boysenberry 4
Broccoli 4
Brussels Sprouts 4
Cabbage 4
Cantaloupe 5
Carrots 5
Cauliflower 4
Celery 6
Cherry 6
Citrus Fruits 7
Cucumber 5
Cucurbits 5
Eggplant 8
Filbert 8
Grapes 9
Hops 9
Lettuce 9
Loganberry 4
Melons 5
Nectarine 10
Onion 11
Peach 10
Pear 11
Peppers 12
Plum 12
Potato 13
Prune 12
Pumpkins 5
Raspberry 4
Spinach 13
Squash 5
Strawberry 14
Sugar Beets 14
Tomato 14
Vegetables (seedlings in coldframes, greenhouses, hot beds,
etc.) 15
Walnut 15
Watermelons 5
Issued: 7-22-85 II-023503-i
202
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EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
TABLE OF CONTENTS
Site Name Page
TERRESTRIAL DON-FOOD CROP
(Agricultural Crops)
Tobacco
(Ornamental Plants and Forest Trees)
Azalea
Dahlias
Maple
Nasturtium
Pachysandra
Peonies
Periwinkle
Rose
White Oak
GREENHOUSE FOOD CROP
(Agricultural Crops)
Vegetables (seedlings)
16
16
16
16
16
16
16
16
16
17
17
17
17
17
17
17
AERIAL AND TANK MIX APPLICATIONS 38
Aerial Application 18
Issued: 7-22-85 II-023503-ii
203
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EPA Index to Pesticide Chemical*
C023503 COPPER OXYCHLORIDE SULFATE
TYPE PESTICIDE: Fungicide
FORMULATIONS;
Tech (56Z, 57Z)
D (31, 61, 15Z)
WP (15.23Z, 20Z, 24Z, 33.3Z, 50Z, 53Z, 55Z)
WP/D (6Z)
GENERAL WARMINGS AND LIMITATIONS; Compatible with most other fungicides
and/or insecticides except lime sulfur and dithiocarbamates.
Dosages and formulations are given in metallic copper equivalents.
May be applied by ground equipment or aircraft.
Observe all warnings and limitations for other active ingredients in mul-
tiple active ingredient labels and when oil is added to the spray.
Do not enter treated areas until sprays or dusts have dried or settled.
Definition of Terms;
MAI - multiple active ingredient(s)
max. - maximum
Site and Pest
Dosages and Tolerance, Use, Limitations
Formulat ion(s)
/03001AA
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Almond
FBADMCB
FBAZCEL
Brown rot blossom 1.0-2.12 lb/
blight (Monilinia) 100 gal
Shothole (Coryneum (50Z, 53Z WP)
blight) or
2.4-3.0 Ib/A
(62 D)
[MAI]
2.4-3.0 Ib/A
(61 D)
Exempt
Apply through 2.12 pounds per 100
gallons; or 8.48 pounds per acre in
CA.
Do not apply after petal fall.
Dormant, delayed dormant, and foliar
applications. For brown rot, apply
2.0 to 2.12 pounds per 100 gallons
in prebloom and petal fall stages.
For shothole, apply 1.0 to 2.12
pounds per 100 gallons with 1.5 to
2 gallons of a suitable emulsion as
a fall spray, in bud swell, and at
petal fall.
—OR MAI--
Formulated with sulfur.
Issued: 7-22-85
II-023503-1
204
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EPA Index to Pesticide Chemicals
/0400IAA
Site and Pest
Apple
FCAAPCE
FBANEBI
Blotch
(Phyllosticta)
Fire blight
(Erwinia)
FMAIMCO
FBANEBI
Brook's fruit spot
(Mycosphaerella)
Fire blight
(Erwinia)
IEAJVAG
Scab (Venturia)
Issued: 7-22-85
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Uae, Limitations
Formulation(s)
Exempt
Apply once through 2.0 pounds per
100 gallons no later than 0.5 inch
green tip.
No preharvest interval through 0.333
pound per 100 gallons with hydrated
lime.
Apply through 3.445 pounds per acre
no later than late secondary bloom.
0.125 lb/100
gal
(50% WP)
or
0.6-1.8 Ib/A
(32, 62 D)
[MAI]
0.9-1.8 Ib/A
(32, 6% D)
0.25-0.333
lb/100 gal
(502 WP)
Foliar application. Apply when 20
percent of the blossoms are open.
Repeat when 75 percent of blossoms
are open. For dust formulations,
the number of applications will be
determined by the length of the
bloom period.
—OR MAI —
Formulated with sulfur.
Foliar application. Add 1 to 1.5
pounds of hydrated lime. Apply in
cover sprays.
0.125-0.13 Foliar application. Apply in full
lb/100 gal bloom, petal fall, and late secon-
[max. 3.445 dary bloom.
Ib/A]
(502, 532 WP)
1.0-2.0 lb/
100 gal
(50% WP)
0.9-1.8 Ib/A
(62 D)
Delayed dormant application. Apply
once as a full cover spray between
silver tip and green tip. Do not
apply at this rate when green tip
exceeds 0.5 inch, as phytotoxicity
may occur.
Delayed dormant and foliar applica-
tions. Apply in prebloom and bloom.
The number of applications will be
determined by the length of the
bloom period.
—OR MAI--
[MAI] Formulated with sulfur.
0.9-1.8 Ib/A
(32, 62 D)
II-023503-2
205
-------
705001AA
FBADMCB
Site and Pest
Apricot
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
See dosage limits below.
Brown rot blossom 2.0-2.385 lb/ Delayed dormant and foliar applica-
blight (Monilinia) 100 gal tion. Apply in prebloom, bloom,
(502, 532 UP) and at petal fall.
or
2.4-3.0 Ib/A
(6% D)
FEAGTAB
FBAZCEL
Leaf curl
(Taphrina)
Shothole (Coryneum
blight)
/28001AA
FFABPCN
FMBJQBB
Beans
Downy mildew
(Phytophthora)
Pod spot
Dormant application. Apply just
before fall rain. Repeat in spring
while trees are still dormant.
Dormant and delayed dormant applica-
tion. Apply as a fall dormant spray
and in the spring at red bud.
2.0 lb/100
gal
(502 WP)
2.0-2.5 lb/
100 gal
(max. 15.9
lb/A]
(502, 532 WP)
or
2.4-3.0 lb/A
(62 D)
1.375-2.4 lb/ Dormant and delayed dormant applica-
100 gal tion. Add a suitable dormant flow-
(202, 242, able oil emulsion. Apply as a fall
502 WP) dormant spray and in the spring at
red bud.
6.0-6.36 lb/A Use limited to CA.
(242, 502 WP) Dormant application. Add 6 gallons
of a suitable dormant oil emulsion.
Apply as a dormant spray up to bud
swell.
5.75-5.76 lb/ Delayed dormant and foliar applica-
60-90 gal/A tion. Apply with concentrate ground
(242, 502 WP) equipment from prebloom to petal
fall.
Exempt
No preharvest interval through 2.12
pounds per acre.
0.5-2.12 lb/A Foliar application. Apply when dis-
(502, 53Z WP) ease threatens. Repeat as needed.
or
1.5-2.1 lb/A
(62 D)
Issued: 7-22-85
II-023503-3
206
-------
/28002AA
FBAAQBB
FMBCQBB
/01002AA
/01003AA
/01005AA
/01006AA
FAAAEAH
FHBCSBL
FJACKAH
FMALSBL
/13005AA
/13006AA
713007AA
/13008AA
.FFABPAU
Site and Pest
Beets
Blight
Leaf spot
Blackberry
Boysenberry
Loganberry
Raspberry
Anthracnose
(Elsinoe)
Leaf spot
(Septoria)
Cane rust (yellow
rust) (Kuehneola)
Cane spot
(Septoria)
EPA Index to Pesticide Chemicals
COPPER OXYCHLORXDE SULFATE
Dosages and Tolerance, Use, Limitations
Fo rmu1a tion(s)
Exempt
No preharvest interval through 1.325
pounds per acre.
1.25-1.325 Foliar application. Apply before
Ib/A disease appears. Repeat at 7 to 14
(502, 532 WP) day intervals during growing season.
Exempt
See dosage limits below.
Boysenberry
Broccoli
Brussels Sprouts
Cabbage
Cauliflower
Downy mildew
(Peronospora)
1.25 lb/100
gal
(502 WP)
Delayed dormant and foliar applica-
tions. Apply when buds begin to
open,
when flower buds show white,
and then at
as needed.
10 to 14 day intervals
0.875-3.18 Delayed dormant, foliar, and post-
lb/100 gal harvest applications. Apply when
[max. 3.18 new laterals are leafing out. Re-
Ib/A] peat when flowers begin to open and
(502, 532 WP) again as a postharvest spray after
or pruning but prior to fall rains.
3.0 Ib/A
(62 D)
See Blackberry cluster.
Exempt
No preharvest interval through 1.99
pounds per 100 gallons.
1.5-1.99 lb/ Foliar application. Apply at 7 to
100 gal 10 day intervals to protect new
(50%, 532 WP) growth throughout the growing sea-
son.
Brussels Sprouts
Cabbage
See Broccoli cluster.
See Broccoli cluster.
Issued: 7-22-85
II-023503-4
207
-------
Site and Pest
/10002AA Cantaloupe
/10010AA Cucumber
/10000AA Cucurbits
/1000IAA Melons
/10011AA Pumpkins
/10012AA Squash
/10008AA Watermelons
FMABPDZ Angular leaf spot
(Pseudomonas)
FAAACDP Anthracnose
(Colletotrichum)
FGZTEBI Bacterial wilt
(Erwinia)
FFABPEA Downy mildew
(Pseudoperono-
spora)
FBAQMCO Gummy stem blight
(Mycosphaerella)
FBATAAX Leaf blight
(Alternaria)
FMBCCBM Leaf spot
(Cercospora)
FFACEBJ Powdery mildew
(Erysiphe)
FEAJCCV Scab
(Cladosporium)
FGZTEBI Bacterial wilt
(Erwinia)
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Uae. Limitations
Formulation(a)
Exempt
No preharvest interval through 3.0
pounds per acre.
1.0-2.2 Ib/A
(50Z, 53Z,
55Z WP)
or
1.5-2.0 lb/
100 gal
(33.3Z, 50Z
WP)
or
1.5-2.1 Ib/A
(6Z D)
[MAI]
1.2-3.0 Ib/A
[dust]
or
1.2-3.0 lb/
100 gal/A
(6Z WP/D)
or
1.5-1.98 Ib/A
(6Z D)
1.0-2.0 Ib/A
(50Z WP)
Foliar application. Apply when
plants emerge or are established,
or when disease is first reported
in the area. Repeat at 5 to 10 day
intervals throughout the growing
season.
—OR MAI—
Formulated with rotenone; or endo-
sulfan.
Foliar application. Apply as above
to aid in the control of bacterial
wilt.
/28073AA
FBATQBB
FMBCQBB
Carrots
Leaf blights
Leaf spots
Exempt
No preharvest interval through 3.25
pounds per acre.
1.5-3.25 Ib/A Foliar application. Apply before
(50Z, 53Z, disease appears. Repeat at 7 to 10
55Z WP) day intervals.
or —OR MAI—
1.5-2.1 Ib/A
(6Z D)
[MAI]
1.5-2.1
(6Z D)
Formulated with sulfur.
Ib/A
Issued: 7-22-85
II-023503-5
-------
EPA Index to Pesticide Chemicals
/28003AA
FBAAPDZ
FBAMCBM
FBASSBL
Site and Pest
Cauliflower
Celery
Bacterial blight
(Pseudomonas)
Early blight
(Cercospora)
Late blight
(Septoria)
/05002AA
FBADMCB
FMBCCDJ
Cherry
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use; Limitations
Ponmilation(a)
See Broccoli cluster.
Exempt
No preharvest interval through 3.25
pounds per acre.
1.0-3.25 Ib/A Foliar application. Apply when
(33.3%, 50Z, plants are set in field or disease
532, 55% WP) is first reported in area. Repeat
or at 7 to 10 day intervals.
1.5-2.1 Ib/A —OR MAI—
(62 D)
[MAI]
1.2 Ib/A
[dust]
or
1.2 lb/100
gal/A
(6Z WP/D)
or
1.5-2.1 Ib/A
(6Z D)
2.52 lb/100
gal
(532 WP)
Formulated with rotenone; or sulfur.
Plant bed and foliar applications.
Apply in plant bed when plants are
3 inches high. Repeat 1 week before
transplanting, 1 week after trans-
planting, and at 2 week intervals
up to within 2 weeks of harvest.
Exempt
See dosage limits below.
Brown rot blossom 2.0-3.0 lb/ Delayed dormant and foliar applica-
blight (Monilinia) 100 gal tions. Apply at popcorn, full
[max. 12.5
Ib/A]
(502, 532 WP)
or
2.4-3.0 Ib/A
Cherry leaf spot
(Coccomyces)
bloom, and petal fall stages.
—OR MAI—
(62 D)
[MAI]
2.4-3.0 Ib/A
(62 D)
Formulated with sulfur.
Issued: 7-22-85
II-023503-6
209
-------
EPA Index to Pesticide Chemicals
Site and Pest
FMBCCDJ
FBAAPDZ
/02000AA
Cherry (continued)
Cherry leaf spot
(Coccomyces)
Dead bud
(Pseudomonas)
Citrus Fruits
FCAJPCN
Brown rot gunmosis
(Phytophthora)
COPPER OXYCULORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
0.625-0.825 Foliar and postharvest applications.
lb/100 gal Add 3 pounds of hydrated lime. Ap-
(50Z, 55Z WP) ply in cover sprays at 7 to 10 day
intervals and make 1 to 2 posthar-
vest foliage applications.
3.0 lb/100 Apply in October (before heavy rain
gal falls) and again before bud swell
(50Z WP) in the spring. Add 1 pint of supe-
rior type oil.
Exempt
See dosage limits below.
Do not apply in areas where copper
injury is known to occur or where
fumigation with hydrogen cyanide gas
is practiced.
Application may be made at low rates
in areas where severe copper injury
is known to occur, but spray skirts
no more than 2 feet high.
0.25-1.375 Foliar and soil application. Add
lb/100 gal 0.5 to 1.5 pounds hydrated lime to
(20Z, 24Z, sprays. Apply during the winter
50Z, 53Z WP) months. Spray the ground around the
or
3.0 Ib/A
(6Z D)
tree and the skirts of the trees to
a height of 3 to 4 feet, covering
the fruit. Treat inside as well as
outside spraying trunks and skirts
thoroughly using 4 to 6 gallons per
tree. The number of applications
depends upon the amount of rain.
—OR MAI—
FMAYMCO
Greasy spot
(Mycosphaerella)
[MAI]
3.0 Ib/A
(6Z D)
1.0 lb/100
gal
(50Z WP)
Formulated with sulfur.
Foliar application. Apply anytime
within 2 months after expansion of
early spring flushes or within 1
month after expansion in late spring
and other flushes of growth.
Issued: 7-22-85
II-023503-7
210
-------
Site and Peat
FMAYMCO
FIBLDAP
FAABEAH
/11001AA
FAAACDP
FBASPCN
IMBCQBB
FBAAPBU
/03005AA
FBAAXAA
EPA Index to Pesticide Chemiccl*
COPPER OXYCKLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Fomnilation(s)
Citrus Fruits (continued)
Greasy spot
(Mycosphaerella)
Melanose
(Diaporthe)
Scab (spot anthrac-
nose) (Elsinoe)
Cucumber
Cucurbits
Eggplant
Anthracnose
(Colletotrichum)
Late blight
(Phytophthora)
Leaf spots
Phomopsis blight
Filbert
Bacterial blight
(Xanthomonas)
3.0-3.35 lb/
500 gal
(15.232, 50Z,
552 WP)
Dormant and foliar applications.
Apply in dormant season before
spring growth appears. Repeat 1 to
3 weeks after petal fall. For mela-
nose and scab, repeat 4 weeks later.
Do not apply after fruit is 0.75
inch in diameter.
See Cantaloupe cluster.
See Cantaloupe cluster.
Exempt
No preharvest interval through 2.12
pounds per acre.
1.0-2.12 Ib/A Foliar application. Apply before
(502, 53Z WP) disease is expected to appear. Re-
or peat at 7 to 10 day intervals.
1.5-2.1 Ib/A —OR MAI—
(61 D)
[MAI]
1.5-2.1 Ib/A
(6% D)
3.0 Ib/A
(62 D)
[MAI]
3.0 Ib/A
(62 D)
Formulated with sulfur.
Exempt
Apply through 3.0 pounds per acre.
Foliar and postharvest applications.
Apply twice, once in August and the
second when half of the leaves have
dropped. If the fall is unusually
wet, make a third application when
most of the leaves have dropped.
—OR MAI—
Formulated with sulfur.
Issued: 7-22-85
II-023503-8
21 1
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
/01014AA
FIBFGBG
FFABPCV
FFACUAB
/08020AA
FFABPEA
Site and Pest
Grapes
Black rot
(Guignardia)
Downy mildew
(Plasmopara)
Powdery mildew
(Uncinula)
Downy mildew
(Pseudoperono-
spora)
Dosages and Tolerance. Use. Limitations
Fonnulation(s)
Exempt
No preharvest interval through 1.66
pounds per acre as a spray or 3.0
pounds per acre as a dust.
1.0-1.25 lb/ Delayed dormant and foliar applica-
100 gal tions. For black rot, apply when
(502, 55Z WP) buds break. Repeat when new shoots
or are 10 inches long, when blossoms
1.56-1.66 lb/ fall, and when berries reach the
125 gal/A size of BB shots. For downy mildew
(502, 532 WP) and powdery mildew, apply when dis-
ease is first reported in the area.
Repeat at 7 to 10 day intervals or
as needed for control.
—OR MAI—
IMAI]
1.2-3.0 Ib/A
(62, 152 D)
Formulated with sulfur; or endo-
eulfan.
Exempt
Apply through 2.12 pounds per acre
as a crown treatment.
1.5-2.12 Ib/A Crown treatment. Apply in early
(502, 532 WP) spring as a crown treatment.
1.5-2.1 Ib/A
or
(62 D)
[MAI]
1.5-2.1 Ib/A
(62 D)
—OR MAI—
Formulated with sulfur.
/13020AA
FFABBBA
Lettuce
Downy mildew
(Bremia)
Loganberry
Issued: 7-22-85
Exempt
No preharvest interval through 2.12
pounds per acre.
0.5-2.12 Ib/A Foliar application. Apply before
(502, 532 WP) disease is expected to appear. Re-
ar peat at 7 to 10 day intervals as
1.5-2.1 Ib/A needed.
(62 D) —OR MAI—
IMAI] Formulated with sulfur.
1.5-2.1 Ib/A
(62 D)
See Blackberry cluster.
II-023503-9
212
-------
/05003AA
/05004AA
FMZAXAA
Site and Pest
Melons
Nectarine
Peach
Bacterial spot
(Xanthomonas)
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(a)
See Cantaloupe cluster.
Exempt
See dosage limits below.
2.0 lb/100 Dormant and delayed dormant applica-
gal tions. Add 2 gallons of dormant
(502 WP) flovable oil emulsion. Apply as a
fall spray and in the spring at bud
swe11.
FBADMCB
Brown rot blossom 1.5-2.5 lb/
blight (Honilinia) 100 gal
FEAGTAB
FBAZCEL
Leaf curl
(Taphrina)
Shothole (Coryneum
blight)
Delayed dormant and foliar applica-
tions. Apply in prebloom, bloom,
(502, 532 WP) and petal fall.
or —OR MAI--
2.4-3.0 Ib/A
(62 D)
[MAI]
2.4-3.0 Ib/A
(62 D)
2.0-2.5 lb/
100 gal/A
(502 WP)
1.44-2.0 lb/
100 gal
(202, 242,
502 WP)
Formulated with sulfur.
Delayed dormant and foliar applica-
tions. Registration Number 005967-
00037: Apply in preblooia, petal
fall, and postbloom as needed. Do
not apply after petal fall to young
tender foliage of peach.
Dormant and delayed dormant applica-
tions. Add the recommended amount
of dormant flowable oil emulsion.
Apply as a dormant spray and at bud
swell.
2.0-2.385 lb/ Dormant and delayed dormant applica-
100 gal tions. Apply as a fall dormant
[peach max.: spray or just before bud swell or
9.54 Ib/A] at pink bud.
[nectarine
max.: 13.25
Ib/A]
(502, 532 WP)
2.0 lb/100
gal
(502 WP)
or
2.4-3.0 Ib/A
(62 D)
Dormant, delayed dormant and foliar
applications. Apply in fall dormant
period. Repeat in spring at bud
swell and again at petal fall.
—OR MAI—
Issued: 7-22-85
11-023503-10
213
-------
Site and Pest
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Nectarine cluster (continued)
/1401IAA
FFABPAU
Onion
Downy mildew
(Peronospora)
/04003AA
FBANEBI
FEAJVAG
Fire blight
(Erwinia)
Scab (Venturia)
[MAI]
2.4-3.0 Ib/A
(6Z D)
5.76 lb/60-
90 gal/A
(24Z WP)
Formulated with sulfur.
Delayed dormant and foliar applica-
tions. Apply using ground concen-
trate equipment. Apply from pre-
bloom to petal fall.
6.0-8.48 Ib/A Use limited to CA.
(502, 531 WP) Dormant application. Apply in dor-
mant up to bud swell.
Exempt
See dosage limits below.
ground:
Use limited to CA.
1.5-2.12 lb/ Foliar application. Apply when dis-
50-100 gal/A ease first appears and repeat at 7
or to 10 day intervals throughout the
aircraft: season.
3.5-3.71 lb/
5 gal/A
(50Z, 531 WP)
1.5-2.0 Ib/A
(502 WP)
Foliar application. Apply as needed
and repeat at 7 to 10 day intervals
throughout the season.
See Nectarine cluster.
Exempt
Apply through 2.98 pounds per acre.
Do not apply after petal fall. Do
not apply to d'Anjou, Commice, or
Seckel varieties.
0.125-0.13 Foliar application. Apply at 10
lb/100 gal percent bloom. Repeat at 3 to 5
[max. 2.98 day intervals until late bloom is
Ib/A] over.
(50Z, 53Z WP) —OR MAI—
or
0.6-1.2 Ib/A
(3Z D)
Issued: 7-22-85
11-023503-11
214
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
FBANEBI
/28017AA
FAAACDP
FMAAXAA
FMBCCBM
FBASPCN
FKAAQBB
/05005AA
/05006AA
FBADMCB
Site and Peat
Pear (continued)
Fire blight
(Erwinia)
Peppers
Anthracnose
(Colletotrichum)
Bacterial spot
(Xanthomonas)
Leaf spot
(Cercospora)
Late blight
(Phytophthora)
Damping-off
Plum
Prune
Dosages and Tolerance, Use, Limitations
Fonnulation(a)
[MAI]
0.9-1.8 Ib/A
(31, 6X D)
1.0-2.0 lb/
100 gal
(50Z WP)
Formulated with sulfur.
Dormant application. Apply as a
full cover spray between dormant
and bud swell.
1.0-1.59 Ib/A use limited to CA.
(50Z, 53% WP) Foliar application. Apply during
bloom and periods favorable to dis-
ease development.
Exempt
No preharvest interval through 2.12
pounds per acre.
1.0-2.12 Ib/A Foliar application. Apply before
(33.31, 50Z, diseases appear. Repeat at 7 to 14
53Z WP) day intervals.
or —OR MAI--
1.5-2.1 Ib/A
(6Z D)
[MAI]
1.5-2.1 Ib/A
(61 D)
Formulated with sulfur; or endo-
sulfan.
2.0-2.125 lb/ Foliar application. Apply at time
100 gal of emergence until plants reach a
(502 WP) height of 4 to 6 inches. Repeat at
4 to 7 dey intervals. Apply to
plants and surrounding soil.
Exempt
See dosage limits below.
Do not apply after petal fall.
Brown rot blossom 1.25-2.0 lb/ Delayed dormant and foliar applica-
blight (Monilinia) 100 gal tions. Apply at popcorn and full
[max. 3.0 bloom.
Ib/A]
(50Z WP)
or
0.31-0.46 lb/
100 gal
(50Z, 53Z WP)
—OR MAI--
Issued: 7-22-85
11-023503-12
215
-------
/14013AA
FBAMAAX
FBASPCN
/13024AA
FFABPAU
Site and Pest
EPA Index to Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Fonnulation(s)
Plain cluster (continued)
Potato
Early blight
(Alternaria)
Late blight
(Phytophthora)
Prune
Pumpkins
Raspberry
Spinach
Downy mildew
(blue mold)
(Peronospora)
Squash
[MAI] Formulated with sulfur.
2.4-3.0 Ib/A
(6Z D)
3.0-3.16 Ib/A Use limited to CA.
(50Z, 53Z WP) Delayed dormant and foliar applica-
tions. Apply in prebloom, bloom,
and petal fall.
Exempt
No preharvest interval through 2.2
pounds per acre.
0.75-2.2 Ib/A Foliar application. Apply when
(33.3Z, 50Z, plants are 4 to 6 inches high or
53Z, 55Z WP) when disease first appears in area.
or Repeat at 4 to 10 day intervals.
1.5-2.1 Ib/A —OR MAI—
(61 D)
[MAI] Formulated with rotenone; sulfur;
1.2-3.0 Ib/A or endosulfan.
(62 D)
(61 WP/D)
or
1.2-3.0 lb/
100 gal/A
(6Z WP/D)
See Plum cluster.
See Cantaloupe cluster.
See Blackberry cluster.
Exempt
No preharvest interval through 2.915
pounds per acre.
2.25-2.915 Foliar application. Apply uniformly
lb/100 gal/A when conditions favor disease.
(50Z, 53Z WP)
See Cantaloupe cluster.
Issued: 7-22-85
11-023503-13
216
-------
/01016AA
FMBCMCO
FFACSCO
/2B020AA
FMBCCBM
Site and Pest
Strawberry
Leaf spot
(Mycosphaerella)
Powdery mildew
(Sphaerotheca)
Sugar Beets
Leaf spot
(Cercospora)
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
Exempt
No preharvest interval through 1.325
pounds per 100 gallons.
1.25-1.325 Delayed dormant and foliar applica-
lb/100 gal tions. Apply thoroughly at 7 to 10
(502, 53! WP) day intervals during growing season.
/11005AA
FAAAGAP
FBAMAAX
FBASPCN
FMBCSBL
Tomato
Anthracnose
(Glomerella)
Early blight
(Alternaria)
Late blight
(Phytophthora)
Leaf spot
(Septoria)
Exempt
No preharvest interval through 3.3
pounds per acre.
1.0-3.3 Ib/A Foliar application. Apply when dis-
(502, 532, ease appears. Repeat as needed.
552 WP) —OR MAI--
or
1.5-2.1 Ib/A
(62 D)
[MAI]
1.5-2.1
(62 D)
Formulated with sulfur.
Ib/A
Exempt
No preharvest interval through 3.85
pounds per acre.
1.0-3.85 Ib/A Foliar application. Apply when
(33.31, 502, plants are 5 to 6 inches high and
532, 552 WP) again when fruit is set; or apply
or when disease first appears. Repeat
1.5-2.1 Ib/A at 4 to 10 day intervals. In areas
(62 D) where blight is severe, begin when
plants are set in field.
—OR MAI—
[MAll
1.2-3.0 Ib/A
(62 D)
(62 WP/D)
or
1.2-3.0 lb/
100 gal/A
(62 WP/D)
Formulated with rotenone; sulfur;
or endosulfan.
Issued: 7-22-85
11-023503-14
217
-------
FMAAXAA
Site and Pest
Tomato (continued)
Bacterial spot
(Xanthomonas)
SPA Index to Pesticide Chemicals
COPPER OXYCHLOR1DE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
1.0-3.3 Ib/A
(50Z, 53Z,
55Z WP)
/28024AA
/28024CA
FKAAQBB
Vegetables (seedlings in cold-
frames, greenhouses, hot beds,
etc.)
Damping-off
/03009AA
FBZAXAA
Walnut
Walnut blight
(Xanthomonas)
Plant bed and foliar application.
Apply beginning in plant bed after
first leaves appear. Repeat at 5
to 7 day intervals if disease is
known to occur in the area.
Exempt
See dosage limits below.
Do not apply to cabbage and related
seedlings.
2.0 Ib/A Foliar and soil application to seed-
(502 WP) lings. Apply when plants emerge.
or Repeat at 4 to 7 day intervals.
2.0-2.25 lb/ Spray plants and surrounding soil.
100 gal
or
1.0-1.1 oz/
3 gal
(50Z, 53Z.
55Z WP)
Exempt
No preharvest interval through 23.85
pounds per acre.
1.5-2.5 lb/
100 gal
(50% WP)
or
1.2-3.0 Ib/A
(6Z D)
Delayed dormant and foliar applica-
tions. Apply in prebloom stages.
Repeat at 1 percent and 10 to 20
percent pistillate bloom and post-
bloom as needed. If rains are fore-
cast during bloom, apply immediate-
Watermelons
1.19-2.52 lb/ Foliar application. Apply at 1 per-
100 gal cent pistillate bloom and again at
[max. 23.85 10 percent pistillate bloom.
Ib/Aj
(50Z, 53Z WP)
6.0-8.48 Ib/A Use limited to CA.
(50Z, 53Z WP) Delayed dormant and foliar applica-
tions. Apply in prebloom, bloom,
and postbloom.
See Cantaloupe cluster.
Issued: 7-22-85
11-023503-15
218
-------
/26003AA
FGASPDZ
/3A022AA
FBAIBBC
/31084AA
/31143AA
/31151AA
FBAABAW
FMBCQBB
/35083AA
/35230AA
FMBTRAW
Site and Pest
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance. Use. Limitations
Formulation(s)
TERRESTRIAL NON-FOOD CROP
(Agricultural Crops)
Tobacco
Wildfire 1.25-1.325 Plant bed application. Apply when
(Pseudomonas) lb/100 gal plants are in two-leaf stage. Re-
(50Z, 532 WP) peat at weekly intervals. Apply to
foliage and soil.
(Ornamental Plants and Forest Trees)
Azalea
Bud and twig blight 2.0-2.2 lb/
(Brioeia) 100 gal
(502, 532,
552 WP)
Bahlias
Botrytis blight
Leaf spots
Tar spot
(Rhytisma)
Foliar application. Apply when dis-
ease is first reported in area. Re-
peat at 7 to 10 day intervals or as
needed for control.
1.25-1.325 Foliar application. Apply before
lb/100 gal disease appears. Repeat at 7 to 10
(502, 532 WP) day intervals and after rains.
2.0-2.2 lb/
100 gal
(502, 532,
552 WP)
Foliar application. Add 2 pounds
of hydrated lime. Apply when dis-
ease is first reported in area. Re-
peat at 7 to 10 day intervals as
needed.
/31143AA
FMBCQBB
Nasturtium
Leaf spots
Refer to Dahlias for dose and use information.
/34106AA Pachysandra
FBBJVAL Volutella leaf and
stem blight
Issued: 7-22-85
1.65-1.855
lb/100 gal
(502, 532,
552 WP)
Foliar application. Add 3 pounds
of hydrated lime. Apply when dis-
ease is first reported in area. Re-
peat at 7 to 10 day intervals or as
needed for control.
11-023503-16
219
-------
Site and Peat
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Dosages and Tolerance, Use, Limitations
Formulation(s)
/31151AA Peonies
FAAAGAN Anthracnose
(Gloeosporium)
FBAABAW Botrytis blight
/34109AA Periwinkle
FDABPBU Canker (dieback)
(Phomopsis)
/34120AA Rose
FMAEDBS Black spot
(Diplocarpon)
FMBCQBB Leaf spots
FJAAPBW Rust
(Phragmidium)
/35230AA White Oak
FAAAGAT Anthracnose
(Gnomonia)
Refer to Dahlias for dose and use information.
2.0-2.2 lb/
100 gal
(50Z, 532,
552 WP)
Foliar application. Apply when dis-
ease is reported in area. Repeat
at 7 to 10 day intervals or as need-
ed for control.
1.25-1.325 Foliar application. Apply before
lb/100 gal disease appears. For black spot,
(50Z, 532 WP) apply when leaf buds swell in early
spring. Repeat at 7 to 10 day in-
tervals and after rains.
Refer to Maple for dosage and use information.
GREENHOUSE FOOD CROP
(Agricultural Crops)
/28024CA Vegetables (seedlings)
Refer to TERRESTRIAL FOOD CROP, (Agricultural
Crops), Vegetables (seedlings in coldframes,
greenhouses, hot beds, etc.) for pest, use and
limitation information.
Issued: 7-22-85
11-023503-17
220
-------
EPA Index to Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Site and Pest Dosages and Tolerance,.Use, Limitations
Formulaeion(»)
AERIAL AND TAKK MIX APPLICATIONS
9001500 Aerial Application
AAAAAAA
Refer to
TERRESTRIAL FOOD CROP
(Agricultural Crops)
All sites except Hops and Vegetables
(seedlings in coldframes, green-
houses, hot beds etc.)
Issued: 7-22-85 11-023503-18
221
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Listing of Registered Pesticide Products by Formulation
&056.0001 561 («etallic copper equivalent) technical chemical
copper oxychlori.de sulfate (023503)
035896-00001
4057.0001 57Z (metallic copper equivalent) technical chemical
copper oxychloride sulfate (023503)
000962-00388
4003.0003 3X (metallic copper equivalent) dust
copper oxychloride sulfate (023503)
000279-00934
copper oxychloride sulfate (023503) plus sulfur or sulphur (077501)
000279-00935
&006.0003 6Z (metallic copper equivalent) dust
copper oxychloride sulfate (023503)
000279-00080
copper oxychloride sulfate (023503) plus sulfur or sulphur (077501)
000279-00458
copper oxychloride sulfate (023503) plus endosulfan (079401)
000279-01322 000279-01589
tO 15.0003 15Z (metallic copper equivalent) dust
copper oxychloride sulfate (023503) plus sulfur or sulphur (077501)
000279-02297
&015.2306 15.232 (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-02402
&020.0006 20Z (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-02200
&204.0006 24Z (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-02445
&033.3006 33.3Z (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-00485
&050.0006 50Z (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-00614 000279-01077 000962-00342 005967-00037
007001-00254 035986-00013
Issued: 7-22-85
11-023503-19
222
-------
EPA Index Co Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Listing of Registered Pesticide Products by Formulation (continued)
4053.0006 531 (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000962-00291 001439-00160
6055.0006 552 (metallic copper equivalent) wettable powder
copper oxychloride sulfate (023503)
000279-00069
6006.0007 6Z (metallic copper equivalent) wettable powder/dust
copper oxychloride sulfate (023503) plus rotenone (and other cube
resins) (073001)
000607-00039
9999999 State Label Registration
CA Reg. No.
000239-10296 000239-10409 005719-04903
Issued: 7-22-85
11-023503-20
223
-------
EPA Index to Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Appendix A
Listing of Multiple Active Ingredient Chemical Names Used in the Entry
Chemical Common Name EPA Acceptable
Code (source) Common/Chemical Name
079401 — endosulfan
073001 rotenone rotenone (and other cube resins)
077501 sulfur sulfur or sulphur
— Use EPA Acceptable Common/Chemical Name
Issued: 7-22-85 11-023503-21
224
-------
/0300IAA
FBADMCB
FBAZCEL
/04001AA
FCAAPCE
FMAIMCO
FBANEBI
FEAJVAG
/05001AA
FBADMCB
FEAGTAB
FBAZCEL
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Foraulation/Registration Number
TERRESTRIAL FOOD CROP
(Agricultural Crops)
Almond
Brown rot blossom blight (Monilinia)
Shothole (Coryneum blight)
(6Z D)
000279-00080 000279-00458
000962-00342 005967-00037 007001-00254
(SOX WP)
000279-00614
035986-00013
(53Z WP)
000962-00291
Apple
Blotch (Phyllosticta)
Brook's fruit spot (Mycosphaerella)
Fire blight (Erwinia)
Scab (Venturis)
(3Z D)
000279-00934 000279-00935
(6Z D)
000279-00080
(50Z WP)
000279-00614
(53Z WP)
000962-00291
000279-00458
000962-00342
007001-00254 035986-00013
Apricot
Brown rot blossom blight (Monilinia)
Leaf curl (Taphrina)
Shothole (Coryneum blight)
(6Z D)
000279-00080
(20Z WP)
000279-02200
(24Z WP)
000279-02445
(50Z WP)
000279-00614
Issued: 7-22-85
000962-00342 007001-00254 035986-00013
11-023503-22
225
-------
/28001AA
FFABPCN
FMBJQBB
/28002AA
FBAAQBB
FMBCQBB
/01002AA
FAAAEAH
FJACKAH
FMALSBL
FMBCSBL
/01003AA
FAAAEAH
FJACKAH
FMALSBL
FMBCSBL
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Apricot (continued)
(531 WP)
000962-00291
001439-00160
Beans
Downy mildew (Phytophthora)
Pod spot
(61 D)
000279-00080
000279-01077
035986-00013
(50Z WP)
000279-00614
007001-00254
(53* WP)
000962-00291
Beets
Blight
Leaf spot
(50Z WP)
000962-00342
(531 WP)
000962-00291
Blackberry
Anthracnose (Elsinoe)
Cane rust (yellow rust) (Kuehneola)
Cane spot (Septoria)
Leaf spot (Septoria)
(6Z D)
000279-00080
000962-00342 005967-00037
005967-00037 007001-00254
(50Z WP)
000279-00614
(53Z WP)
000962-00291
000962-00342 007001-00254 035986-00013
Boysenberry
Anthracnose (Elsinoe)
Cane rust (yellow rust) (Kuehneola)
Cane spot (Septoria)
Leaf spot (Septoria)
(6Z D)
000279-00080
Issued: 7-22-85
11-023503-23
226
-------
/13005AA
FFABPAU
/13006AA
FFABPAU
/13007AA
FFABPAU
/10002AA
FMABPDZ
FAAACDP
FGZTEBI
FFABPEA
FBAQMCO
FBATAAX
FMBCCBM
FFACEBJ
FEAJCCV
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fornulation/Begistration Number (continued)
Boysenberry (continued)
(502 WP)
000279-00614 000962-00342 007001-00254
(532 WP)
000962-00291
Broccoli
Downy mildew (Peronospora)
(502 WP)
000962-00342
(532 WP)
000962-00291
Brussels Sprouts
Downy mildew (Peronospora)
(502 WP)
000962-00342
(532 WP)
000962-00291
Cabbage
Downy mildew (Peronospora)
(502 WP)
000962-00342
(532 WP)
000962-00291
Cantaloupe
Angular leaf spot (Pseudomonas)
Anthracnose (Colletotrichum)
Bacterial wilt (Erwinia)
Downy mildew (Pseudoperonospora)
Gummy stem blight (Mycosphaerella)
Leaf blight (Alternaria)
Leaf spot (Cercospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
(502 WP)
007001-00254
Issued: 7-22-85
11-023503-24
227
-------
/28073AA
FBATQBB
FMBCQBB
/13008AA
FFABPAU
/28003AA
FBAAPDZ
FBAMCBM
FBASSBL
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Carrots
Leaf blights
Leaf spots
(6Z D)
000279-00080 000279-00458
(50Z WP)
000279-01077
035986-00013
(53Z WP)
000962-00291
(55Z WP)
000279-00069
Cauliflower
Downy mildew (Peroaospora)
(50Z WP)
000962-00342 035986-00013
(53Z WP)
000962-00291
Celery
Bacterial blight (Pseudomonas)
Early blight (Cercospora)
Lace blight (Septoria)
(6Z D)
000279-00080 000279-00458
(33.3Z WP)
000279-00485
000962-00342 005967-00037 007001-00254
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
(6Z WP/D)
000607-00039
000279-01077
035986-00013
001439-00160
000962-00342 005967-00037
Issued: 7-22-85
11-023503-25
-------
/05002AA
FBADMCB
FMBCCDJ
FBAAPDZ
/02000AA
FGAJPCN
FMAYMCO
FIBLDAP
FAABEAH
/10010AA
FMABPDZ
FAAACDP
FGZTEBI
FFABPEA
FBAQMCO
FBATAAX
FMBCCBM
FFACEBJ
FEAJCCV
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Cherry
Brown rot blossom blight (Monilinia)
Cherry leaf spot (Coccomyces)
Dead bud (Pseudomonas)
(62 D)
000279-00080 000279-00458
(502 WP)
000279-00614 000962-00342
(532 WP)
000962-00291
(55% WP)
000279-00069
Citrus Fruits
Brown rot gummosis (Phytophthora)
Greasy spot (Mycosphaerella)
Melanose (Diaporthe)
Scab (spot anthracnose) (Elsinoe)
(62 D)
000279-00080 000279-00458
(15.23Z WP)
000279-02402
(202 WP)
000279-02200
(242 WP)
000279-02445
007001-00254 035986-00013
(502 WP)
000279-01077
(532 WP)
000962-00291
Cucumber
000962-00342 007001-00254 035986-00013
001439-00160
a U> u u» v ^ *•
Angular leaf spot (Pseudomonas)
Anthracnose (Colletotrichum)
Bacterial wilt (Erwinia)
Downy mildew (Pseudoperonospora)
Gummy stem blight (Mycosphaerella)
Leaf blight (Alternaria)
Leaf spot (Cercospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
Issued: 7-22-85
11-023503-26
229
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
Cucumber (continued)
000279-01589
000279-01077
035986-00013
001439-00160
(6Z D)
000279-00080
(33.32 WP)
000279-00485
(502 WP)
000279-00614
007001-00254
(532 WP)
000962-00291
(552 WP)
000279-00069
(62 WP/D)
000607-00039
/10000AA Cucurbits
FMABPDZ Angular leaf spot (Pseudomonas)
FAAACDP Anthracnose (Colletotrichum)
FGZTEBI Bacterial wilt (Ervinia)
FFABPEA Downy mildew (Pseudoperonospora)
FBAQMCO Gummy stem blight (Mycosphaerella)
FBATAAX Leaf blight (Alternaria)
FMBCCBM Leaf spot (Cercospora)
FFACEBJ Powdery mildew (Erysiphe)
FEAJCCV Scab (Cladosporium)
(502 WP)
007001-00254
/11001AA Eggplant
FAAACDP Anthracnose (Colletotrichum)
FBASPCN Late blight (Phytophthora)
FMBCQBB Leaf spots
FBAAPBU Phomopsis blight
(62 D)
000279-00080 000279-00458
000962-00342 005967-00037
(502 WP)
000279-00614
007001-00254
(532 WP)
000962-00291
000279-01077
035986-00013
000962-00342 005967-00037
Issued: 7-22-85
11-023503-27
230
-------
/03005AA
FBAAXAA
/01014AA
FIBFGBG
FFABPCV
FFACUAB
/08020AA
FFABPEA
/13020AA
FFABBBA
EPA Index to Pesticide Chemicals
COPPER OXYCHLO&IDE SULFATE
Appendix B
Listing by Site/Pest and Site/Foraulation/Regifltration Number (continued)
Filbert
Bacterial blight (Xanthomoaas)
(6Z D)
000279-00080 000279-00458
Grapes
Black rot (Guignardia)
Downy mildew (Plasmopara)
Powdery mildew (Uncinula)
(6Z D)
000279-00458
000279-01589
000962-00342 007001-00254
(15* D)
000279-02297
(50* WP)
000279-00614
(53* WP)
000962-00291
(55* WP)
000279-00069
Hops
Downy mildew (Pseudoperonospora)
(6* D)
000279-00080 000279-00458
(502 WP)
000279-00614
035986-00013
(532 WP)
000962-00291
Lettuce
Downy mildew (Bremia)
(6* D)
000279-00080
000279-01077 000962-00342 007001-00254
(50* WP)
000279-00614
007001-00254
(532 WP)
000962-00291
000279-00458
000279-01077
000962-00342 005967-00037
Issued: 7-22-85
11-023503-28
231
-------
/01005AA
FAAAEAH
FJACKAH
FMALSBL
PMBCSBL
/10001AA
FMABPDZ
FAAACDP
FG2TEBI
FFABPEA
FBAQMCO
FBATAAX
FMBCCBM
FFACEBJ
FEAJCCV
/05003AA
FMZAXAA
FBADMCB
FEAGTAB
FBAZCEL
EPA Index to Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fomilation/Regiatration Number (continued)
Loganberry
Anthracnose (Elsinoe)
Cane rust (yellow rust) (Kuehneola)
Cane spot (Septoria)
Leaf spot (Septoria)
(61 D)
000279-00080
(502 WP)
000279-00614 000962-00342 007001-00254
(53Z WP)
000962-00291
Melons
Angular leaf spot (Pseudomonas)
Anthracnose (Colletotrichum)
Bacterial wilt (Ervinia)
Downy mildew (Pseudoperonospora)
Gunny stem blight (Mycosphaerella)
Leaf blight (Alternaria)
Leaf spot (Cercospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
(61 D)
000279-00080 000279-01589
(33.31 WP)
000279-00485
000279-01077 000962-00342 005967-00037
001439-00160
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
(6Z WP/D)
000607-00039
Nectarine
Bacterial spot (Xanthomonas)
Brown rot blossom blight (Monilinia)
Leaf curl (Taphrina)
Shothole (Coryneum blight)
(6Z D)
000279-00080 000279-00458
Issued: 7-22-85
11-023503-29
232
-------
/14011AA
FFABPAU
/OS004AA
FMZAXAA
FBADMCB
FEAGTAB
FBAZCEL
/04003AA
FBANEBI
FEAJVAG
EPA Index to Pesticide Checiccls
COPPER OXYCKLORIDE SULFATE
Appendix B
Lilting by Site/Pest and Site/Forvulation/Registration Number (continued)
Nectarine (continued)
(201 WP)
000279-02200
(24Z WP)
000279-02445
(50% WP)
000962-00342
(53Z W?)
000962-00291
005967-00037 007001-00254 035986-00013
001439-00160
Onion
Downy mildew (Peronospora)
(SOX WP)
000279-01077 000962-00342
(53Z WP)
000962-00291
Peach
Bacterial spot (Xanthomonas)
Brown rot blossom blight (Monilinia)
Leaf curl (Taphrina)
Shothole (Coryneum blight)
(6Z D)
000279-00080 000279-00458
(202 WP)
000279-02200
(24Z WP)
000279-02445
(50Z WP)
000962-00342
(53Z WP)
000962-00291
005967-00037 007001-00254 035986-00013
001439-00160
Pear
Fire blight (Erwinia)
Scab (Venturia)
(3Z D)
000279-00934 000279-00935
Issued: 7-22-85
11-023503-30
233
-------
/28017AA
FAAACDP
FMAAXAA
FKAAQBB
FBASPCN
FMBCCBM
/05005AA
FBADMCB
/14013AA
FBAMAAX
FBASPCN
EPA Index to Pesticide Chemical*
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Formulation/Registration Number (continued)
Pear (continued)
(6Z D)
000279-00458
000962-00342 005967-00037 007001-00254
(50Z WP)'
000279-00614
035986-00013
(532 WP)
000962-00291
Peppers
Anthracnose (Colletotrichum)
Bacterial spot (Xanthomonas)
Damping-off
Late blight (Phytophthora)
Leaf spot (Cercospora)
(61 D)
000279-00080 000279-00458 000279-01589
(33.3Z WP)
000279-00485
000279-01077
035986-00013
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
Plom
Brown rot blossom blight (Monilinia)
(61 D)
000279-00458
000962-00342 005967-00037
(50Z WP)
000962-00342 005967-00037
(53Z WP)
000962-00291
Potato
Early blight (Alternaria)
Late blight (Phytophthora)
(61 D)
000279-00080 000279-00458
007001-00254 035986-00013
000279-01322 000279-01589
Issued: 7-22-85
11-023503-31
234
-------
/05006AA
FBADMCB
/10011AA
FMABPDZ
FAAACDP
FGZTEBI
FFABPEA
FBAQMCO
FBATAAX
FMBCCBM
FFACEBJ
FEAJCCV
EPA Index to Pesticide Ch*aic«le
COPPER OXYCHLORIDE SULFATE
Appendix B
Lieting by Site/Pest and Site/Foraulation/Registration Muaber (continued)
Potato (continued)
(33.3Z WP)
000279-00485
000279-01077
035986-00013
(501 HP)
000279-00614
007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
(62 WP/D)
000607-00039
Prune
Brown rot blossom blight (Monilinia)
(6Z D)
000279-00458
000962-00342 005967-00037
007001-00254
(50Z WP)
000962-00342
(53Z WP)
000962-00291
Pumpkins
Angular leaf spot (Pseudomonas)
Anthracnose (Colletotrichum)
Bacterial vilt (Ervinia)
Downy mildew (Pseudoperonospora)
Gummy stem blight (Mycosphaerella)
Leaf blight (Alternaria)
Leaf spot (Cercospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
(6Z D)
000279-01589
(50Z WP)
OQ7001-00254
Issued: 7-22-85
11-023503-32
235
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULPATE
Appendix B
Listing by Site/Pest and Site/Foroulation/Registration Number (continued)
/01006AA Raspberry
PAAAEAH Anthracnose (Elsinoe)
PJACKAH Cane rust (yellow rust) (Kuehneola)
FMALSBL Cane spot (Septoria)
FMBCSBL Leaf spot (Septoria)
(61 D)
000279-00080
(50Z WP)
000279-00614 000962-00342 007001-00254 035986-00013
(53Z WP)
000962-00291
/13024AA Spinach
PFABPAU Downy mildew (blue mold) (Peronospora)
(50Z WP)
000962-00342
(531 WP)
000962-00291
/10012AA Squash
PMABPDZ Angular leaf spot (Pseudomonas)
FAAACDP Anthracnose (Colletotrichum)
PGZTEBI Bacterial wilt (Erwinia)
FFABPEA Downy mildew (Pseudoperonospora)
FBAQMCO Gunny stem blight (Mycosphaerella)
FBATAAX Leaf blight (Alternaria)
FMBCCBM Leaf spot (Cercospora)
FFACEBJ Powdery mildew (Erysiphe)
FEAJCCV Scab (Cladosporium)
(6Z D)
000279-00080 000279-01589
(33.3Z WP)
000279-00485
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
(551 WP)
000279-00069
000279-01077
035986-00013
001439-00160
000962-00342 005967-00037
Issued: 7-22-85
11-023503-33
236
-------
/01016AA
FMBCMCO
FFACSCO
/28020AA
FHBCCBM
/11005AA
FAAAGAP
FMAAXAA
FBAMAAX
FBASPCN
FMBCSBL
SPA Index to Pesticide Chemicals
COPPER OZYCHLOEIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Forsulation/Registration Number (continued)
Squash (continued)
(6Z WP/D)
000607-00039
Strawberry
Leaf spot (Mycosphaerella)
Powdery mildew (Sphaerotheca)
(50Z WP)
000962-00342 007001-00254
(53Z WP)
000962-00291
Sugar Beets
Leaf spot (Cercospora)
(6Z D)
000279-00080 000279-00458
000279-01077
035986-00013
000962-00342 005967-00037
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
Tomato
Anthracnose (Glomerella)
Bacterial spot (Xanthomonas)
Early blight (Alternaria)
Late blight (Phytophthora)
Leaf spot (Septoria)
(6Z D)
000279-00080 000279-00458 000279-01322 000279-01589
(33.3Z WP)
000279-00485
(50Z WP)
000279-00614
007001-00254
(53Z WP)
000962-00291
000279-01077
035986-00013
000962-00342 005967-00037
Issued: 7-22-85
11-023503-34
23?
-------
/28024AA
FKAAQBB
/03009AA
FBZAXAA
/10008AA
FMABPDZ
FAAACDP
FGZTEBI
FFABPEA
FBAQMCO
FBATAAX
FMBCCBM
FFACEBJ
FEAJCCV
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fonmilation/Registration Number (continued)
Tomato (continued)
(551 WP)
000279-00069
(61 WP/D)
000607-00039
Vegetables (seedlings in coldframes, greenhouses, hot beds, etc.)
Damping-off
(502 WP)
000279-00614 000279-01077 000962-00342 005967-00037
007001-00254
(532 WP)
000962-00291
(55Z WP)
000279-00069
Walnut
Walnut blight (Xanthomonas)
(61 D)
000279-00080
000962-00342 005967-00037 007001-00254
(502 WP)
000279-00614
035986-00913
(532 WP)
000962-00291
Watermelons
Angular leaf spot (Pseudomonas)
Anthracnose (Colletotrichum)
Bacterial wilt (Ervinia)
Downy mildew (Pseudoperonospora)
Gummy stem blight (Mycosphaerella)
Leaf blight (Alternaria)
Leaf spot (Cercospora)
Powdery mildew (Erysiphe)
Scab (Cladosporium)
(502 WP)
007001-00254
Issued: 7-22-85
11-023503-35
238
-------
/26003AA
FGASPDZ
/34022AA
FBAIBBC
/31084AA
FBAABAW
FMBCQBB
/35083AA
FMBTRAU
/31143AA
FMBCQBB
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fonnulation/Registration Number (continued)
TERRESTRIAL NON-FOOD CROP
(Agricultoral Crops)
Tobacco
Wildfire (Pseudomonas)
(502 WP)
000962-00342 007001-00254
(532 WP)
000962-00291
(Ornamental Plants and Forest Trees)
Azalea
Bud and twig blight (Briosia)
(50Z WP)
000279-00614 000962-00342 007001-00254
(53Z WP)
000962-00291
(552 WP)
000279-00069
Bahlias
Botrytis blight
Leaf spots
(502 WP)
000962-00342 007001-00254
(532 WP)
000962-00291
Maple
Tar spot (Rhytisma)
(502 WP)
000279-00614 000962-00342
(532 WP)
000962-00291
(552 WP)
000279-00069
Nasturtium
Leaf spots
(502 WP)
000962-00342 007001-00254
Issued: 7-22-85
007001-00254
11-023503-36
239
-------
/34106AA
FBBJVAL
/31151AA
FAAAGAN
7EAABAW
/34109AA
FDABPBU
/34120AA
FMAEDBS
FMBCQBB
FJAAPBW
EPA Index to Pesticide Cheaicals
COPPER OXYCHLORIDE SULFATE
Appendix B
Listing by Site/Pest and Site/Forvulation/Registration Number (continued)
Nasturtium (continued)
(53Z WP)
000962-00291
Pachysandra
Volutella leaf and stem blight
(50Z WP)
000279-00614 000962-00342 007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
Peonies
Anthracnose (Gloeosporium)
Botrytis blight
(50Z WP)
000962-00342 007001-00254
(53Z WP)
000962-00291
Periwinkle
Canker (dieback) (Phomopsis)
(50* WP)
000279-00614 000962-00342 007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
Rose
Black spot (Diplocarpon)
Leaf spots
Rust (Phragmidium)
(50Z WP)
000962-00342 007001-00254
(53Z WP)
000962-00291
Issued: 7-22-85
11-023503-37
240
-------
/35230AA
FAAAGAT
/28024CA
FKAAQBB
SPA Index to Pesticide Chemical*
COPPER OXYCHLO&IDE SULFATE
Appendix B
Listing by Site/Pest and Site/Fonulation/Registration Number (continued)
White Oak
Anthracnose (Gnomonia)
(50Z WP)
000279-00614 000962-00342 007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
GREENHOUSE FOOD CROP
(Agricultural Crops)
Vegetables (seedlings)
Damping-off
(50Z WP)
000279-00614 000279-01077
007001-00254
(53Z WP)
000962-00291
(55Z WP)
000279-00069
000962-00342 005967-00037
Issued: 7-22-85
11-023503-38
241
-------
EPA Index to Pesticide Chemicals
COPPER OXYCHLORIDE SULFATE
Auxiliary Documentation
CFR 40 Sec. 180.1001 - exemption fro* tolerance
Reg. Mo. 279-614 (50Z WP):
This label was improperly coded under 023501, copper oxychloride.
Reg. No. 1439-160 (53Z WP, approved 10/18/67):
Dosages are presented as equivalents to some Bordeaux mixes, and (except
for celery) are not tied directly to a site. The implied dose range of
1.52-3.45 Ib metallic copper equivalent/100 gallons was not entered for
those sites.
Reg. No. 607-39 (6Z WP/D, with rotenone):
The following sites with insecticide claims appear on the label and are
not on any other copper oxychloride sulfate claims: asparagus, kale,
kohlrabi, turnips, radish, parsnips, swiss chard, gooseberry, and cur-
rants.
Issued: 7-22-85 II-023503-i
242
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APPENDIX IV
BIBLIOGRAPHY APPENDICES
243
-------
BIBGUIDE-1
GUIDE TO USE OP THIS BIBLIOGRAPHY
GROUP II COPPER COMPOUNDS
1. CONTENT OP BIBLIOGRAPHY. This bibliography contains
citations of all studies considered relevant by EPA in
arriving at the positions and conclusions stated elsewhere
in the Standard. Primary sources for studies in this
bibliography have been the body of data submitted to EPA
and its predecessor agencies in support of past regulatory
decisions. Selections from other sources including the
published literature, in those instances where they have
been considered, will be included.
2. UNITS OP ENTRY. The unit of entry in this bibliography
is called a "study." In the case of published materials,
this corresponds closely to an article. In the case of
unpublished materials submitted to the Agency, the Agency
has sought fco identify documents at a level parallel to
the published article from within the typically larger
volumes in which they were submitted. The resulting
"studies" generally have a distinct title (or at least a
single subject), can stand alone for purposes of review,
and can be described with a conventional bibliographic
citation. The Agency has attempted also to unite basic
documents and commentaries upon them, treating them as a
single study.
3. IDENTIFICATION OP ENTRIES. The entries in this bibliography
are sorted numerically by "Master Record Identifier," or
MRID, number. This number is unique to the citation, and
should be used at any time specific reference is required.
It is not related to the six-digit "Accession Number"
which has been used to identify volumes of submitted
studies; see paragraph 4(d)(4) below for a further explana-
tion. In a few cases, entries added to the bibliography
late in the review may be preceded by a nine-character
temporary identifier. These entries are listed after
all MRID entries. This temporary identifier number is
also to be used whenever specific reference is needed.
J». PORM OP ENTRY. In addition to the Master Record Identifier
(MRID), each entry consists of a citation containing
standard elements followed, in the case of material
submitted to EPA, by a description of the earliest known
submission. Bibliographic conventions used reflect the
standards of the American National Standards Institute
(ANSI), expanded to provide for certain special needs.
244
-------
BIBGUIDE-2
a. Author. Whenever the Agency could confidently Identify
one, the Agency has chosen to show a personal author.
When no individual was identified, the Agency has
shown an identifiable laboratory or testing facility
as author. As a last resort, the Agency has shown
the first submitter as author.
b. Document Date. When the date appears as four digits
with no question marks, the Agency took it directly
from the document. When a four-digit date is followed
by a question mark, the bibliographer deduced the
date from evidence in the document. When the date
appears as (19??), the Agency was unable to determine
or estimate the date of the document.
c. Title. In some cases, it has been necessary for
Agency bibliographers to create or enhance a document
title. Any such editorial insertions are contained
between' square brackets.
d. Trailing Parentheses. For studies submitted to the
Agency in the past, the trailing parentheses include
(in addition to any self-explanatory text) the fol-
lowing elements describing the earliest known submission:
(1) Submission Date. The date of the earliest known
submission appears immediately following the word
"received."
(2) Administrative Number. The next element,
immediately following the word "under," is the
registration number, experimental use permit
number, petition number, or other administrative
number associated with the earliest known submission,
(3) Submitter. The third element is the submitter,
following the phrase "submitted by." When
authorship is defaulted to the submitter, this
element is omitted.
(4) Volume Identification (Accession Numbers). The
final element In the trailing parentheses
identifies the EPA accession number of the volume
in which the original submission of the study
appears. The six-digit accession number follows
the symbol "CDL," standing for "Company Data
Library." This accession number is in turn
followed by an alphabetic suffix which shows the
relative position of the study within the volume.
For example, within accession number 123456, the
first study would be 123^56-A; the second, 123W-
B; the 26th, 123^56-Z; and the 27th, 123^56-AA.
245
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Conpounds Standard
MRID CITATION
00002200 Crown Zellerbach Corporation (19??) Analytical Procedures and
Equipment. Two undated methods. (Unpublished study received
Aug 2, 1965 under 3222-6; CDL:010748-2-F)
00028002 Wellborn, T.L.; Jr. (1969) The toxicity of nine therapeutic and
herbicidal compounds to striped bass. Progessive Fish-Cultur-
ist 31(? ):27-32. (Also in unpublished submission received Aug
20, 1976 under 39445-1; submitted by American Carbonyl, Inc.,
Tenafly, N.J.; CDL:228232-C)
00036935 Atkins, E.L.; Greywood, E.A.; Macdonald, R.L. (1975) Toxicity of
Pesticides and Other Agricultural Chemicals to Honey Bees: Labo-
ratory Studies. By University of California, Dept. of Entomolo-
gy. ?: UC, Cooperative Extension. (Leaflet 2287; published
study.)
00047460 WARF Institute, Incorporated (1973) Report: WARF No. 2040242,
2040243, 2040244. (Compilation; unpublished study received Mar
30, 1973 under unknown admin, no.; submitted by Kocide Chemical
Corp., Houston, Tex.; CDL:132472-A)
00053980 WARF Institute, Incorporated (1977) Report: WARF No. 7011554.
(Unpublished study received Jun 2, 1977 under 1109-24; submitted
by Cities Service Co., Atlanta, Ga.; CDL:230351-A)
00056781 Vedder, D.L. (1970) Fish Toxicity. (Unpublished study received Sep
16, 1970 under 8959-1; prepared by Marine Biochemists, Inc.,
subnatted by Applied Biochemists, Inc., Mequon, Wis.; CDL:
100318-C)
00058009 CP Chemicals, Incorporated (1969?) COGS Manufacturing Data. (Un-
published study received Nov 12, 1975 under 35896-5; CDL:
226402-A)
00062068 Scheinberg, I.H.; Sternlieb, I. (1960) Copper metabolism. Pharma-
cological Reviews 12:355-381. (Also in unpublished submission
received Aug 25, 1976 under 39752-1; submitted by Canadian Meta-
fina Chemicals, New Westminster, British Columbia; CDL:228175-C)
00062069 Schroeder, H.A.; Nason, A.P.; Tipton, I.H.; et al. (1966) Essential
trace metals in man: Copper. Journal of Chronic Diseases 19:
1007-1034. (Also in unpublished submission received Aug 25,
1976 under 37952-1; submitted by Canadian Metafina Chemicals,
New Westminster, British Columbia; CDL: 228175-D)
00065678 Cities Service Company (1965?) General Chemistry: Copper Sulfate
Monchydrate. (Unpublished study received Jun 20, 1977 under
1109-33; CDL:230760-A)
246
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Conpounds Standard
MRID CITATION
00067454 Piccirillo, V.J. (1977) Final Report: Subacute Dietary LT50 Study
in Mallard Ducks: Project No. 811-106. (Unpublished study re-
ceived Jul 11, 1977 under 1109-7; prepared by Hazleton Labora-
tories America, Inc., submitted by Cities Service Co., Atlanta,
Ga.; CDL:230839-A)
00067455 Sodden, R. (1978) Report: WARF Institute No. 7020979. (Unpublished
study received Jun 12, 1978 under 1109-7; prepared by WARF
Institute, Inc., submitted by Cities Service Co., Atlanta, Ga.;
CDL:230839-B)
00067456 WARF Institute, Incorporated (1977) Report: WARF Institute
No. 7020979. (Unpublished study received Jul 11, 1977 under
1109-7; submitted by Cities Service Co., Atlanta, Ga.; CDL:
230839-C)
00070287 Richelsen Chemical Company (1976) Copper Sulfate Pentahydrate:
Fate of Copper in the Environment. Summary of studies 231553-B,
and 231553-D through 231553-F. (Unpublished study received
Sep 13, 1977 under 41071-1; CDL:231553-A)
00070288 U.S. Bureau of Sport Fisheries and Wildlife (1974) A Review of
the Literature on the Use of Copper Sulfate in Fisheries.
N.P. (PB-235 445; pp. 20, 41, 58, 59 only; available from:
National Technical Information Service, Springfield, VA; pub-
lished study; CDL:231553-B)
00085289 Marshall, B.L. (1975) Final Report: Acute Bicassay on Shrinp
(Palaemonetes vulgaris). (Unpublished study received Mar 6,
1975 under 1109-19; prepared by Marine Research Institute, sub-
mitted by Cities Service Co., Atlanta, Ga.; CDL:110616-A)
00086564 Schneider, C.L.; Potter, H.S. (1969) Tests of Fungicides To Control
Sugarbeet Diseases. (Unpublished study received Dec 19, 1969
under 9F0841; submitted by Thompson-Hayward Chemical Co.,
Kansas City, Kans.; CDL:093544-D)
00088167 Crown Zellerbach Corporation (1949?) Analytical Methods. (Unpub-
lished study received Jan 28, 1956 under PP0059; CDL:090057^})
00099168 Vedder, D.L. (1970) Fish toxicity: Cutrine. (Unpublished study
received Sep 16, 1970 under 8959-1; prepared by Marine Bio-
chemists, Inc., submitted by Applied Biochemists, Inc., Mequon,
Wis.; CDL:005661-F)
247
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Conpounds Standard
MRID CITATION
00099255 Phelps Dodge Refining Company (1962?) Full Reports of Investiga-
tions Made with Safety of the Pesticide Chemical: Copper Sul-
fate as an Algicide. (Unpublished study received Nov 17, 1970
under 1F1093; CDL:090853-A)
00099256 Claypole, G. (19??) Careful Use of Chemicals Controls Lake Weeds
and Algae. N.P. (Also in unpublished submission received Nov
17, 1970 under 1F1093; submitted by Phelps Dodge Refining Co.,
New York, N.Y.; CDL:090853-B)
00099257 Anthony, S.S. (1969) Algae handled efficiently by Augusta Water
District. Water & Sewage Works ?(May):? (Also in unpub-
lished submission received Nov 17, 1970 under 1F1093; submitted
by Phelps Dodge Refining Co., New York, N.Y.; CDL:090853-C)
00099258 Anon. (1965) New ways to apply aquatic herbicides. Weeds, Trees
and Turf ?(Feb/Apr):? (Also in unpublished submission re-
ceived Nov 17, 1970 under 1F1093; submitted by Phelps Dodge
Refining Co., New York, N.Y.; CDL:090853-D)
00099259 Bennett, D.G. (1967) Aquatic weed control becomes technical Opera-
tion. Weeds, Trees and Turf ?(May):? (Also in unpublished
submission received Nov 17, 1970 under 1F1093; submitted by
Phelps Dodge Refining Co., New York, N.Y.; CDL:090853-E)
00099260 Toth, S.J.; Riemer, D.N. (19??) Algae control in farm ponds: Are
present dosage rates of copper sulphate always adequate. With-
out title?:? (Also in unpublished submission received Nov
17, 1970 under 1F1093; submitted by Phelps Dodge Refining Co.,
New York, N.Y.; CDL:090853-F)
00099262 Riemer, D.N.; Toth, S.J. (1970) Adsorption of copper by clay
minerals, humic acid and bottom muds. Journal of American Water
Works Association 62(3): 195-197. (Also in unpublished sub-
mission received Nov 17, 1970 under 1F1093; submitted by Phelps
Dodge Refining Co., New York, N.Y.; CDL:090853-H)
00099263 Toth, S.J.; Riemer, D.N. (1968) Precise chemical control of algae
in ponds. Journal of American Water Works Association 60(3):
367-371. (Also in unpublished submission received Nov 17, 1970
under 1F1093; submitted by Phelps Dodge Refining Co., New York,
N.Y.; CDL:090853-1)
00099269 Agway, Incorporated (1971) Efficacy of Various Compounds for Dry-
ing Onion Foliage and Regulating Harvest Time. (Compilation;
unpublished study received Jul 20, 1972 under 2F1226; CDL:
091056-A)
248
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Conpounds Standard
MRID CITATION
00099281 Markey, J.W. (1970) Letter sent to Lee Terbush dated Dec 14, 1970:
Petition on copper sulfate in water—additional information on
inerts. (Unpublished study received Nov 24, 1970 under 1F1073;
submitted by Cities Service Co., Atlanta, Ga.; CDL:093383-A)
00099282 Hale, F.E. (1942) The Use of Copper Sulfate in Control of Micro-
scopic Organisms. New York, N.Y.: Phelps Dodge Refining Corp.
(Also in unpublished submission received Nov 24, 1970 under
1F1073; submitted by Cities Service Co., Atlanta, Ga.; CDL:
093383-B)
00099284 Armstrong, E.L. (19??) Undated letter sent to Joseph G. Cummings
Copper sulfate pentahydrate to control algae and aquatic
weeds. (U.S. Dept. of the Interior, Bureau of Reclamation;
unpublished study; CDL:093383-E)
00099288 Stauffer Chemical Company (1970?) Sutan(R): Environmental Stud-
ies. Summary of studies 097089-B through 097089-G. (Unpub-
lished study received on unknown date under 1F1042; CDL:
097089-A)
00099355 McCann, J. (1973) Copper-Count-N: Rainbow Trout: Test No. 564.
(U.S. Environmental Protection Agency, Pesticides Regulation
Div., Animal Biology Laboratory; unpublished study; CDL:
128375-A)
00099370 MoCann, J.A. (1971) Kocide 101 Wettable Powder: Rainbow Trout
(Salmo gairdneri): Test No. 411. (U.S. Agricultural Re-
search Service, Pesticides Regulation Div., Animal Biology Lab-
oratory; unpublished study; CDL:129665-A)
00099371 MoCann, J.A. (1972) Kocide 101 WP: Bluegill (Lepomis macro-
chirus): Test No. 451. (U.S. Agricultural Research Serv-
ice, Pesticides Regulation Div., Animal Biology Laboratory; un-
published study; CDL:129665-B)
00099374 McCann, J.A. (1971) Hunco Copper Sulfate: Bluegill (Lepomis
macrochirus): Test No. 366. (U.S. Agricultural Research
Service, Pesticides Regulation Div., Animal Biology Laboratory;
unpublished study; CDL: 130336-A)
00099522 Timuss, D. (1975) Laboratory Analysis: Copper Sulfate: File
No. 9206A. (Unpublished study received Apr 23, 1976 under
37952-1; prepared by Can Test Ltd., Canada, submitted by Cana-
dian Metafina Chemicals, New Westminster, BC; CDL:228172-B)
249
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Conpounds Standard
MRID CITATION
00099537 Mereniuk, G.; Medzhibovskaia, Z. (1970) The contamination of soil
and fruit by copper-cxxitaijiing peticides. Gigiena i Sanit. 35
(1):108-10. Taken from: Health Aspects of Pesticides Abstract
Bulletin 3:445. (U.S. Dept. of Health, Education and Welfare
generated; abstract 70-1590; published study; CDL:228173-Q)
00099551 Wilbur Ellis Co. (19??) Ingredients, Composition and Manufacturing
Process of Copper Sulphate Pentahydrate. (Unpublished study
received May 31, 1978 under 2k5-412; CDL:234177-A)
00099552 Wilbur Ellis Co. (1969) Effectiveness of Copper Sulfate to Control
Aquatic Weeds and Algae. (Compilation; unpublished study re-
ceived May 31, 1978 under 2935-412; CDL:234179-A)
00099558 LeBlanc, 3.; Surprenant, D. (1978) Acute Toxicity of Copper Sulfate
Granular Crystals to the Water Flea (Daphnia magna): Report
No. BW-78-7-211. (Unpublished study received Aug 22, 1978 under
1109-20; prepared by EG & G, Bionomics, submitted by Cities
Service Co., Atlanta, GA; CDL:234664-A)
00099559 Heitnuller, T. (1978) Toxicity of Cities Service Company's Copper
Sulfate (pentahydrate) to Pink Shrimp (Penaeus duorarum): Re-
port No. 3P-78-8-109. (Unpublished study received Aug 22, 1978
under 1109-20; prepared by EG & G, Bionomics, submitted by
Cities Service Co., Atlanta, GA; CDL:234664-B)
00099561 Hollister, T. (1978) Toxicity of Copper Sulfate (pentahydrate) to
Embryos of Eastern Oysters (Crassostrea virginica): Report
No. BP-78-8-108. (Unpublished study received Aug 22, 1978 under
1109-20; prepared by EG & G, Bionomics, submitted by Cities
Service Co., Atlanta, GA; CDL:234664-D)
00106119 Piccirillo, V. (1977) Final Report: Subacute Dietary LC50 Study
in Bobwhite Quail: Project No. 811-105. (Unpublished study re-
ceived May 23, 1977 under 1109-7; prepared by Hazleton Labora-
tories America, Inc., submitted by Cities Service Co., Atlanta,
GA; CDL:230244-A)
00126194 Phillips, A.; Spalding, T. (1982) Toxicity Study: Lacco Copper
Oxychloride Sulfate 50% Sprayable Fungicide: NVP No. X2J016.
(Unpublished study received Feb 8, 1983 under 962-342; prepared
by Northview Pacific Laboratories, Inc., submitted by Los
Angeles Chemical Co., South Gate, CA; CDL:249611^A)
00133277 Northview Pacific Laboratories, Inc. (1983) Acute Oral Toxicity
Test/LD50: Lacco Copper Oxy Chloride Sulfate 50% Sprayable
Fungicide: NVP No. X2J016-1. (Unpublished study received
Nov 8, 1983 under 962-342; submitted by Los Angeles Chemical
Co., South Gate, CA; CDL.-251795-A)
250
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supportino
Registrations Under the Group II Copper Conpounds Standard
MRIP CITATION
00152502 Galloway, C. (1984) Rabbit Skin Irritation: Cupric Hydroxide:
Project No. 3482-84. Unpublished study prepared by Stillrreadow,
Inc. 10 p.
00152503 Galloway, C. (1984) Rabbit Eve Irritation: Cupric Hydroxide:
Project No. 3481-84. Unpublishd study prepared by Stillmeadow,
Inc. 17 p.
00152504 Sabol, E. (1985) Guinea Pig Skin Sensitization: Cupric Hydroxide:
Project No. 3483-84. Unpublished study prepared by Stillmeadcw,
Inc. 14 p.
00152505 Galloway, C. (1984) Rabbit Acute Dermal Toxicity: Cupric Hydroxide:
Project No. 3480-84. Unpublished study prepared by Stillmeadcw,
Inc. 9 p.
00152506 Galloway, C. (1985) Rat Acute Oral Toxicity: Cupric Hydroxide:
Project No. 3479-84. Unpublished study prepared by Stillmaadow,
Inc. 21 p.
00155931 Rosenfeld, G. (1984) Acute Oral Toxicity Study in Rats: Copper Oxy-
chloride Technical: C.S.E. #88687-4: Study #1144A. Unpublished
study prepared by Cosmopolitan Safety Evaluation, Inc. 29 p.
00155932 Rosenfeld, G. (1984) Acute Inhalation Toxicity Study in Rats: Copper
Oxychloride Technical: C.S.E. *S8687-4: Study #1144C. Unpublished
study prepared by Cosmopolitan Safety Evaluation, Inc. 31 p.
00155934 Rosenfeld, G. (1984) Primary Eye Irritation Study in Rabbits: Copper
Oxychloride Technical: C.S.E. #S8687-4: Study #1144D. Unpublished
study prepared by Cosmopolitan Safety Evaluation, Inc. 23 p.
00155935 Rosenfeld, G. (1984) Primary Dermal Irritation Study in Rabbits: Copper
Oxychloride Technical: C.S.E. #58687-4: Study #1144E. Unpublished
study prepared by Cosmopolitan Safety Evaluation, Inc. 13 p.
00155936 Rosenfeld, G. (1984) Guinea Pig Sensitization Study (Buehler); Copper
Oxychloride Technical: C.S.E. #S8687-4 Study #1144F. Unpublished
study prepared by Cosmopolitan Safety Evaluation, Inc. 15 p.
00159371 Deenihan, M. (1985) Acute Oral Toxicity (LD50); Acute Dermal Toxicity;
Primary Skin Irritation; Primary Eye Irritation: NVP Report No.
X5J0303. Unpublished study prepared by Northview Pacific Laboratories,
Inc. 33 p.
00160580 Newton, P. (1986) Four Hour Acute Dust Aerosol Inhalation Toxicity Study
in Rats of Copper Hydroxide Formulated 50% Cu: Study No. 420-2611.
Unpublished study prepared by American Biogenics Corp. 47 p.
251
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OFFICE OF PESTICIDE PROGRAMS
REGISTRATION STANDARD BIBLIOGRAPHY
Citations Considered to be Part of the Data Base Supporting
Registrations Under the Group II Copper Compounds Standard
GS0649-001
GS0649-002
GS0649-O03
GS0649-004
GS0649-005
GS0649-006
GS0649-007
Crown Zellerbach Corp.
Feb 27, 1956. 12 p.
(1956) Addendum to Petition PP0059 dated
Gibson, R.D. (1975) LCso Study with Nutra-Spray on Pheasants.
(Unpublished study received Aug 8, 1975; prepared by Harris
Laboratories, Inc, submitted by Leffingwell ChemLcal Ccnpany,
Brea, CA)
McCann, J.A. (1975) Copper Oxychloride: Bluegill (Lepomis
macrochirus): Static Jar Test. (U.S. Environmental Protection
Agency, Technical Services Div., Chemical & Biological Investi-
gations Branch; unpublished study).
McCann, J.A. (1975) Copper Oxychloride: Rainbow Trout (Salmo
gairdneri): Static Jar Test. (U.S. Environmental Protection
Agency, Technical Services Div., Chemical & Biological Investi-
gations Branch; unpublished study).
McCann, J.A. (1975) Oxycop: Bluegill (Lepomis macrochirus):
Static Jar Test. (U.S. Environmental Protection Agency,
Technical Services Div., Chemical & Biological Investigations
Branch; unpublished study).
McCann, J.A. (1975) Oxycop: Rainbow Trout (Salmo gairdneri):
Static Jar Test. (U.S. Environmental Protection Agency,
Technical Services Div., Chemical & Biological Investigations
Branch; unpublished study).
U.S. Environmental Protection Agency (1984) Ambient Water
Quality Criteria for Copper. (PB 85-227023; pp. 1-84;
available fron National Technical Information Service,
Springfield, VA ; published study;)
252
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