United Slates National Air and EPA 520'5-91 -004 Environmental Protection Radiation Environmental Laboratory Agency Ollice ol Radiation Programs xvEPA Radiation Radiological Surveys of Naval Facilities in the New London Harbor and on the Thames River, Connecticut ------- EPA 520/5-91-004 Radiological Surveys of Naval Facilities in New London Harbor and on the Thames River, Connecticut Mark O. Semler and Richard L. Blanchard National Air and Radiation Environmental Laboratory 1504 Avenue A Montgomery, Alabama 36115—2601 December 1991 U.S. Environmental Protection Agency Office of Radiation Programs 401 M Street, S.W. Washington, D.C. 20460 ------- TABLE OF CONTENTS List of Figures v List of Tables v Preface ix Introduction 1 Characteristics of the Harbor, Thames River, and the Environs 3 Survey and Analytical Methods 5 Results and Discussion 14 Conclusions 29 References 31 Appendix A: Description of Samples Collected 34 Appendix B: Concentration of Cobalt-60 in Individual Sediment Samples 37 Appendix C: Concentration of Radionuclides in Sediment Core Samples 39 Appendix D: Local Gamma Exposure Rate Survey 42 ------- LIST OF FIGURES Figure 1. New London, Connecticut Harbor and Thames River .... 10 2. Electric Boat Sediment Sampling Sites 11 3. New London Submarine Base Sediment Sampling Sites. . . 12 4. State Pier and Sound Signature Facility Sediment Sampling Sites 13 5. Electric Boat Core, Water and Biota Sampling Sites . . 21 6. New London Submarine Base Core, Water, and Biota Sampling Sites 22 LIST OF TABLES Table 1. Summary of Samples Collected 9 2. Summary of Radionuclide Concentrations in Sediment Samples 16 3. Comparison of Co-60 Concentrations in Sediment Samples Collected in 1972 and 1989 18 4. Summary of the Co—60 Concentrations in Sediment Core Samples ..... 19 5. Description of Biota Samples 25 6. Summary of Gamma-Ray Exposure Rates 27 ------- PREFACE The Office of Radiation Programs identifies and evaluates environmental public health impacts of both natural and man-made radiation sources. The National Air and Radiation Environmental Laboratory (NAREL), formerly the Eastern Environmental Radiation Facility (EERF), is a fully integrated participant with other components of the Office in these efforts. The Laboratory provides comprehensive capability for evaluating radiation sources through planning and conducting environmental studies, nationwide surveillance, and laboratory analysis. The NAREL also provides special analytical support for Environmental Protection Agency Regional Offices and other federal government agencies, as requested, as well as technical assistance to the radiological health programs of state and local health departments. This report presents results of the surveys conducted by NAREL personnel to assess levels of environmental radioactivity resulting from maintenance and operation of nuclear-powered warships at the New London Submarine Base (NLSB), General Dynamics Electric Boat Division, Sound Signature Facility, and the State Pier, all located within New London, Connecticut, Harbor on the Thames River. The purpose of the survey was to determine if activities related to IX ------- nuclear-powered warships resulted in release of radionuclides which may contribute to significant population exposure or contamination of the environment. Readers of our reports are encouraged to bring comments, omissions, or errors to our attention. ^X/flxuw -J- ^yU"i^o/-v\CUvv—- Sam T. Windham, Director National Air and Radiation Environmental Laboratory ------- INTRODUCTION Since 1963, the National Air and Radiation Environmental Laboratory (NAREL), formerly the Eastern Environmental Radiation Facility (EERF), U.S. Environmental Protection Agency (USEPA), in cooperation with U.S. Naval Sea Systems Command (NAVSEA), has surveyed facilities serving nuclear-powered warships on the Atlantic and Pacific coasts and the Gulf of Mexico. These surveys assess whether construction, maintenance, overhaul, or refueling of nuclear-powered warships have created elevated levels of radioactivity. The surveys emphasize sampling those areas and pathways that could expose the public. In 1984, NAVSEA requested that the USEPA again survey all active facilities servicing nuclear-powered warships. In 1989, the USEPA conducted a radiological survey of New London, Connecticut, Harbor and the Thames River, focusing on the action facilities servicing nuclear—powered warships, in order to determine if nuclear ship activity has contributed to detectable quantities of radioactivity to the environment. Measurements and sampling were primarily conducted in the environs of the New London Submarine Base (NLSB), General Dynamics Electric Boat Division (Electric Boat), Sound Signature Facility, and the State Pier. ------- This survey was a follow—up of two previous surveys conducted in the same areas during July 1966 (Ca66) and July 1972 (Wi73). Cobalt-60 was the predominant non-naturally occurring radionuclide observed during both surveys. Concentrations in sediment samples collected by dredge (0-10 cm depth into the sediment) during the 1972 Groton Harbor survey ranged from 0.2 to 26 pCi/g dry weight, with an average of 2.9 pCi/g. The Cobalt—60 concentrations in sediment samples collected during the 1972 survey from locations that duplicated those of the 1966 survey had decreased by a factor of about 30. This decrease was attributed to a reduction in radioactivity discharged to the harbor, radioactive decay (half- life of Co-60 is 5.27 years) and natural sedimentation. Much of the Cobalt-60 remaining was found at a depth of 15 cm to 20 cm in the sediment (Wi73), indicating that it did not result from operations of the early 1970's. ------- CHARACTERISTICS OF THE HARBOR, THAMES RIVER, AND THE ENVIRONS The Thames River is a tidal estuary arising at the confluence of the Yantic and Shetucket Rivers, approximately 24 km (15 miles) north of the Groton—New London Harbor area. The river varies in width from 0.21 km (0.13 miles) to a maximum of 1.82 km (1.13 miles) where it empties into Long Island Sound. The mean tidal range of the river at New London is 76 cm (2.5 feet). The bottom sediment is characterized mainly by mud, gravel, and sand. Because of silting, maintenance dredging is required in the channel and in the areas adjacent to the piers. Between the 1966 and 1972 surveys, dredging had been done in an area adjacent to pier 17 and the marine railway at the NLSB and in the area north of the State Pier. Dredging continued in the Thames River during the 1980's, primarily to accommodate the greater draft of the Trident class submarine. However, according to General Dynamics personnel, no recent dredging has been performed around the piers, only in the Thames River Channel. Some changes have occurred since the 1972 survey that are noteworthy. The North Yard at Electric Boat has been expanded to include the Land Level Facility and Building 260, and finger pier B has been removed. At the NLSB, piers 18 through 24 have been replaced with piers 31, 32, and 33. A new facility, the Sound Signature Facility, has been added south 3 ------- of the State Pier at Fort Trumball. Personal communications with local authorities indicated no commercial fishing is done in the Groton—New London Harbor area, although sport fishing and power and sail boating are popular, and a ferry boat operates out of New London. There appeared to be no swimming in the harbor area. The two principal population centers in the vicinity are Groton, with about 9,000 people, and New London with about 250,000 people (1980 census). Both Groton and New London obtain their city water supplies from reservoirs fed by surface streams. The harbor area is industrialized with essentially no agriculture along the shore. The major industries in the harbor area are the New London Submarine Base, General Dynamics Electric Boat Division, the U.S. Coast Guard Academy, and Charles Pfizer and Sons. ------- SURVEY AND ANALYTICAL METHODS Personnel from the General Dynamics Radiological Control Group accompanied the NAREL team during surveys of the four facilities. They provided information on those sampling sites where radioactivity associated with Naval nuclear propulsion plants/ if it were present, would most likely be detected. Extensive sediment sampling was conducted in the pier and dock areas where nuclear warships were being or had been serviced. Sampling procedures and locations were also selected so that comparisons could be made with the data obtained in the 1972 survey. Locations of vessels and additions and changes in the piers and docks prevented resurveying some locations used in 1972. Public access or recreational areas and public drinking water supplies in the vicinity of the Naval facilities were also surveyed for radioactivity. Cobalt—60 is the predominant radioisotope one would find in environmental media if radioactivity were present as a result of Naval nuclear propulsion plant operations (Ca66, Wi73, Se88); therefore, environmental sampling focused on detecting this radioisotope. The Co-60 content in all samples was determined by gamma—ray spectroscopy. Water samples were also analyzed for tritium since this radionuclide is known to be produced in the coolant of light-water nuclear reactors. ------- As stated above, if radioactivity were released as a result of Naval nuclear propulsion plant operations, it would be detected as Co—60 in the sediment. Radionuclides tend to accumulate in the sediment over time, which enables detection of events that may have occurred in the past. A standard Peterson dredge was used to sample approximately the top 10 centimeters of sediment. Eighty- five sediment samples were collected from around the four locations surveyed. At the laboratory these samples were dried, ground to a fine powder, placed in 400 cm3 sample counting containers, and counted on intrinsic germanium detectors for 1000 minutes. The minimum detectable activity for Co-60 in this geometry is approximately 0.01 picocuries per gram (pCi/g). Sediment core samples are useful in determining the vertical distribution of radioactivity in harbor bottom sediment. If radioactive material were present from past operations and subsequently covered with sediment, the radioactivity might be detected in the core samples. Seven core samples were taken with 3.8 cm diameter plastic tubes housed in a mechanical coring tool. The cores were frozen and sectioned into 2.5 cm lengths. The individual sections were freeze—dried and counted on intrinsic germanium detectors for 1000 minutes to determine the gamma-ray emitting radioisotopes. The minimum detectable activity for Co-60 in this geometry is approximately 0.1 pCi/g. ------- Water samples were collected at ten sites. The surface water samples were grab samples. The drinking water samples, collected from taps, represent the water supplies for Groton and New London, Connecticut, and the New London Submarine Base. One liter water samples were analyzed for gamma-ray emitters, especially Co-60, on intrinsic germanium detectors. The minimum detectable level for Co—60 in this geometry is 5 picocuries per liter (pCi/L) . The water samples were also analyzed for tritium. The tritium found in reactor coolant systems is in oxide form and chemically indistinguishable from water; therefore, it does not accumulate in marine life or on the harbor floor (Ma88). The minimum detectable level for tritium is 200 pCi/L with the analytical procedure used. Aquatic biota samples were collected at six sites by divers. These samples were divided for analysis as follows: fish — muscle only; lobster — meat only; crab — whole animal; mussels, clams, conch, and oysters — meats; starfish, sea cucumber, and sea urchin — analyzed whole; and vegetation (kelp and sea lettuce). The biota samples were dried, ground to a fine powder, and counted on intrinsic germanium detectors for 1000 minutes. The counting geometry was determined by the amount of sample available; the minimum detectable level for Co-60 is 0.01 pCi/g for a 400 cm3 sample and 0.1 pCi/g for a 40 cm3 sample. ------- Gamma .radiation measurements were made with pressurized ionization chambers or portable scintillation survey instruments that were calibrated with the pressurized ionization chambers. Measurements were made at all sites in the pier and dock areas where the majority of the sediment samples were collected and along the security restricted area boundaries at Electric Boat and the NLSB. Public access and recreation areas in the vicinity of the NLSB were surveyed with portable scintillation survey instruments, as were the shores of the Thames River. Sampling sites are shown on maps of New London Harbor and the Thames River, New London Submarine Base, Electric Boat, Sound Signature Facility, and the State Pier in Figures 1 through 6. A summary of the samples collected from the four sites is presented in Table 1. Sample types collected at each sampling location are detailed in Appendix A. 8 ------- TABLE 1 Summary of Samples Collected Sampling Facility Sites Number of Samples Water Sediment Cores Biota River/Harbor 8 Sound Signature Facility New London Submarine Base 36 Electric Boat 33 State Pier 8 TOTAL 88 8 0 5 5 _0 10 34 32 _8 85 0 0 10 12 3 4 0. _P_ 7 22 NOTE: See Appendix A for a listing of all samples collected at each sampling location. ------- Figure 1 STATE PIER j NEW LONDON < SOUND SIGNATURE FACILITY 1-95 BRIDGE GROTON i 1 KM 1. New London, Connecticut Harbor and Thames River 10 ------- 0.05 0.1 KM h ri, !• ' NORTH YARD PRIVATE SOUTH YARD NUCLEAR REPAIR FACILITY GUARD TOWER BUOY#13 THAMES RIVER RED MARKER 2. Electric Boat Sediment Sampling Sites ------- "I H- uq 2 n CD 0 0.1 0.2 KM USS NAUTILUS MEMORIAL DEPENDENTS MARINA NR-1 COMPOUND • "3 3. New London Submarine Base Sediment Sampling Sites ------- Figure 4 t i 0 0.1 0.2 KM SOUND SIGNATURE FACILITY 4. State Pier and Sound Signature Facility Sediment Sampling Sites 13 ------- RESULTS AND DISCUSSION Sediment Samples Eighty—five sediment samples were Collected from around the four locations surveyed and from the harbor and river. The sampling locations are shown in: Figure I, The Thames River and New London Harbor; Figure 2, Electric Boat; Figure 3, the NLSB; and Figure 4, the State Pier and the Sound Signature Facility. A summary of the radionuclide concentrations measured in the sediment samples is presented in Table 2. Traces of Co—60 were observed in all samples collected. The Co-60 concentrations in individual samples are provided in Appendix B. The presence of the Co—60 in the sediment of these locations is the result of past Co-60 releases from nuclear-powered warships. The Cs-137 observed in the sediments can be attributed to fallout from previous atmospheric nuclear tests, and the other radionuclides detected are naturally occurring. The Co—60 concentrations vary widely between samples; however, the average concentrations at the four sites are similar, ranging from 0.14 pCi/g at the NLSB to 0.26 pCi/g at the State Pier. The average Co-60 concentration of all samples collected is 0.18 pCi/g. 14 ------- Background sediment samples were collected from three locations upriver (North) of the Navy facilities (see sites 39, 40, and 41 in Figure 1) . Low concentrations of Co—60 were observed in sediment samples from upriver locations during the 1972 survey, indicating that small quantities of Co-60 have moved upriver. Considering that the background samples were collected only from about 1.2 km to 4.5 km north of the NLSB, the radioactivity observed upriver probably resulted from tidal movements generating currents that had swept sediments short distances upriver. Also, the lower concentrations measured in sediments out of the facility confines in the harbor and river were probably the result of faster currents and dredging activities. The average upriver background concentration observed during this survey, 0.02 pCi/g, is significantly less than for the 1972 survey, consistent with the expected decrease due to radioactive decay and sedimentation. It also indicates that no Co-60 has been released since the 1972 survey. 15 ------- TABLE 2 Summary of Radionuclide Concentrations in Sediment Samplesa'b/c Radionuclide Electric Boat Submarine Base State Pier No. of Samples K-40 Cs-137 Co-60 Ra-226 Th-232 32 19(13-20) 0.13(0.02-0.69) 0.20(0.06-0.65) 1.6 (1.2-2.1) 0.84(0.71-1.00) 34 17(10-20) 0.17(0.03-0.35) 0.14(0.01-0.23) 1.5(0.86-1.8) 0.77(0.52-1.19) 8 17(16-18) 0.13(0.10-0.16) 0.26(0.16-0.60) 1.5(1.2-1.8) 0.77(0.68-0.89) Radionuclide Sound Signature Facility Harbor/ River Background*3 No. of Samples K-40 Cs-137 Co-60 Ra-226 Th-232 16(14-19) 0.10(0.09-0.11) 0.16(0.08-0.20) 1.3(1.0-1.5) 0.69(0.57-0.77) 5 3 17(13-19) 14(11-15) 0.13(0.03-0.29) 0.10(0.02-0.24) 0.06(0.02-0.11) 0.02(<.01-0.03) 1.6(0.9-1.9) 1.3(1.0-1.7) 0.96(0.85-1.03) 0.80(0.63-0.90) Concentrations are pCi/g dry weight. ''Mean concentrations are given with the range shown in parentheses. "Approximate 2-sigma counting errors are: K-40 (3%); Cs-137 (20%); Co-60 (30% for concentrations less than 0.1 pCi/g); Ra-226 (20%); and Th-232 (10%). dSampling sites 39, 40, and 41 are considered background sites (see Figure 1). 16 ------- Cobalt-60 was observed in sediment samples collected during previous surveys of these facilities in 1966 and 1972. An attempt was made during this recent survey to collect some sediment samples from the same sites used in 1972. Although changes in piers and docks since the last survey, as well as conditions that existed during this survey, made this task difficult, twelve sampling sites were duplicated. The results obtained in 1989 are compared in Table 3 with measurements made in 1972. Significant decreases in the Co-60 concentration have occurred at all sites. A seven to eight fold decrease in the Co-60 concentration has occurred in sediments at the NLSB, which is about the decrease that would result from radioactive decay in the 17-year period since the last survey with no subsequent Co-60 added. A greater decrease is observed to have occurred in sediments at the Electric Boat area and the State Pier (25 to 30 fold), which may be the result of sedimentation in addition to radioactive decay. 17 ------- TABLE 3 Comparison of Co—60 Concentrations in Sediment Samples Collected in 1972 and 1989. Co-60 Concentration, Sampling Location pCi/g dry weight 1989 1972 1989 1972 49 48 50 55 59 46 48 43 52 51 New London Submarine Base 0.18 0.18 0.19 0.18 0.21 1.5 1.9 1.3 1.4 1.0 Average Concentrations 0.19 1.4 Electric Boat 13 21 22 23 25 85 87 25 31 30 33 32 Average 8 12 Average Concentrations State Concentrations 0 0 0 0 0 0 .23 .20 .39 .34 .16 .26 1 2 2 9 26 8 .1 .5 .5 .3 .1 .3 Pier 0 0 0 .16 .22 .19 4 5 4 .0 .5 .8 Although Co-60 was observed in sediment at the Navy facilities/ the concentrations present are very small, and have continued to decrease with time at a rate equal to or greater than the decay rate of Co—60. The small and decreasing quantities of 18 ------- Co-60 in the harbor sediments pose no radiological impact to the area. Sediment Core Samples Sediment core samples were collected at seven sites: four samples from the aquatic environs of Electric Boat (Figure 5) and three samples from the NLSB (Figure 6) . Traces of Co-60 were detected throughout the cores in all samples. A summary of the Co- 60 concentrations measured in the core samples is presented in Table 4, and the results for each depth increment (2.5 cm) are reported in Appendix C. TABLE 4 Summary of the Co-60 Concentrations in Sediment Core Samples3 Sample Location1* Total Depth, cm Co-60 Concentration, pCi/g dry weight0 Range Average Electric Boat 8 15 21 26 28 43 15 13 0 0 0 0 .07-0 .10-0 .05-0 .07-0 .18 .19 .12 .07 0. 0. 0. 0. 13 15 09 07 New London Submarine Base 48 52 65 25 18 13 0 0 0 .14-0 .21-0 .23-0 .37 .31 .36 0. 0. 0. 23 25 28 aSee Appendix C for detailed analytical results. bSee Figures 5 and 6 for sampling locations. 19 ------- °Analytical uncertainties in the results are about 75% for concentrations between 0.1 and 0.2 pCi/g, and 35% for concentrations greater than 0.2 pCi/g. 20 ------- PRIVATE PIER 0 0.05 0.1 KM NORTH YARD SOUTH YARD NUCLEAR REPAIR FACILITY GUARD TOWER d h (D BUOY#13 THAMES RIVER AREA SAMPLED BY DIVERS FOR AQUATIC BIOTA CORE SAMPLE WATER SAMPLE RED MARKER 5. Electric Boat Core, Water and Biota Sampling Sites ------- "I 1' •Q d n (D o 0.1 KM 0.2 USS NAUTILUS MEMORIAL ISJ rv. DEPENDENTS MARINA 6. New London Submarine Base Core, Water and Biota Sampling Sites ------- Cobalt-60 concentrations in the core samples from the NLSB were about twice those measured in samples from Electric Boat (0.2 versus 0.1 pCi/g); however, the difference is probably not significant considering the variability of Co-60 concentrations in the sediment and the few samples obtained. No significant variation in concentration with depth was observed in cores from Electric Boat. The maximum concentration of 0.37 pCi/g at a depth of about 18 cm was observed in the core from the NLSB at sampling location 48 (see Appendix C), however, this concentration cannot be related to any particular occurence and indicates the Co—60 is not the result of current operations. The other radionuclides observed in the core samples are Cs-137, which is attributed to fallout from previous atmospheric nuclear tests, and K—40, Ra-226, and Th—232, which are naturally occurring radionuclides. Water Samples Surface water samples were collected at seven sites: sites 2, 16, 21, and 31 at Electric Boat and sites 46, 51, and 72 at the NLSB. No radioactivity associated with nuclear-powered warships was detected in any of the water samples by the gamma-ray analysis. Tritium concentrations were below the limit of detection, 200 pCi/L. Drinking water samples were collected from Groton (site 28), New London (site 29), and the NLSB (site 88). No detectable 23 ------- gamma-ray activity was observed in any of the drinking water samples, and the tritium concentrations were below the detectable level. Biota Samples Twenty-two biota samples were analyzed from six locations (see Figures 5 and 6). A list of the samples from each site that were analyzed for gamma-ray emitting radionuclides is provided in Table 5. The small concentrations of Co-60, less than 0.1 pCi/g dry weight, measured in samples of kelp, sea lettuce, and starfish from Electric Boat and kelp, sea lettuce, and sea cucumber from the NLSB may be due to sediment adhering to the surface of these biota samples. Cobalt-60 was not detected in any edible seafoods. Some samples contained small traces of Cs-137 and Th-232. 24 ------- TABLE 5 Description of Biota Samples Site Location3 Samples Analyzed Electric Boat North Area, Site 1 Clams & Mussels Starfish Lobster & Conch Kelp Middle Area, Site 2 Lobster Starfish & Sea Urchin Kelp South Area, Site 3 Lobster & Crab Starfish Mussels Sea Lettuce Kelp Submarine Base North Area, Site 1 Flounder Lobster & Mussels Kelp & Sea Lettuce Starfish Middle Area, Site 2 Starfish & Mussels Lobster Mussels & Conch South Area, Site 3 Lobster Starfish, Mussels, Conch Kelp & Sea Cucumber aSee Figures 5 and 6 for these sampling locations. 25 ------- GAMMA RADIATION MEASUREMENTS Gamma radiation measurements were taken at the sediment sampling sites/ north of the State Docks (to represent background), along the Electric Boat and NLSB restricted area boundaries, and along each shoreline of the Thames River. The shoreline surveys extended from Jupiter Point on Long Island Sound to Hurlbut Road in Gales Ferry, Connecticut, on the east shore and from Ocean Beach Park on Long Island Sound to Powerhouse Road near Uncasville, Connecticut, on the west shore. In addition, a few radiation measurements were made in areas accessible to the public on the NLSB. Radiation measurements at the sediment sampling sites were performed with pressurized ionization chambers, while land surveys were conducted with portable scintillation survey instruments that had been calibrated with the pressurized ionization chambers. A summary of the gamma ray exposure measurements is presented in Table 6. Individual exposure rates measured during the land surveys are presented in Appendix D. 26 ------- TABLE 6 Summary of Gamma-Ray Exposure Rates Gamma—Ray Exposure Rates, i/R/hr Location of Survey Average Range Harbor Sampling Sites Electric Boat 4.3 3.4-5.2 New London Submarine Base 6.9 3.2-8.5 Background 4.1 3.8-4.6 Restricted Area Boundary at Electric Boat 4.0 3.5-4.8 Restricted Area Boundary at Submarine Base 3.9 3.2-4.6 Shoreline Survey* East Shoreline 8.2 3-12 West Shoreline 8.1 3-11 New London Submarine Base - Land Marine shoreline near Bldg 181 & 387 11 10-12 Lower base shoreline 8.2 6-10 Golf Course, greens 1-3 16 15-19 aSee Appendix D for individual exposure measurements. All gamma—ray exposure measurements made in accessible locations over water in the harbor reflect background exposure rates. The exposure rate measurements made in the harbor are lower than those taken on land because of the shielding afforded by the water. The exposure rates along the two shorelines of the Thames River are very similar and within the expected background range for that area, 3 //R/hr to 12 //R/hr (EPA 89) . A description of the 27 ------- areas surveyed is given in Appendix D. Measurements taken on the NLSB in areas accessible to the public ranged from 6 fJR/tir to 19 A*R/hr. The slightly elevated measurements over those taken along the shoreline are attributed to natural terrestrial radiation or areas where rock high in granite content was used as fill (Se88, Sm87, Wi87). 28 ------- CONCLUSIONS The radiological surveys of the Naval Facilities on the Thames River at Groton and New London, Connecticut, provide the basis for the following conclusions: 1. Trace quantities of Co-60 remain in the sediment at all locations investigated; however, the concentrations have significantly decreased since the earlier two surveys and represent no radiological impact to the environment or individuals living or working in the area. 2. Sediment samples that duplicated samples obtained in 1972 contained 8—30 times less Co—60 than the earlier samples, indicating that radioactive decay and sedimentation is naturally reducing the Co—60 levels in surface sediments and that no significant releases of Co-60 have occurred in recent years. 3. No Co-60 was detected in any edible aquatic species. 4. All seven sediment core samples contained low levels of Co-60. The maximum concentration observed was 0.37 pCi/g at a depth of about 18 cm, but this cannot be related to any particular occurrence and indicates the Co—60 is not the result of current operations. 29 ------- CONCLUSIONS — Continued 5. Water samples contained no detectable levels of radioactivity other than those occurring naturally. 6. Gamma-ray measurements did not detect any increased radiation exposure to the public above natural background levels. 7. Based on these surveys, current practices regarding nuclear- powered warship operations have resulted in no increase in radioactivity that would result in significant population exposure or contamination of the environment. 30 ------- REFERENCES B176 Blanchard, R.L., et. al. 1976. Radiological Surveillance Studies at the Oyster Creek BtfR Nuclear Generating Station. EPA-520/5-76-003. Washington, D.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. Ca66 Cahill, D.F., Breakfield, W.D., and McCurry, D.C., 1966. Radiological Survey of the Thames River, Connecticut, and Environs. Southeastern Radiological Health Laboratory Technical Report, July/August, 1966. Ca87 Callis, R.S., 1987. Radiological Survey of the Pearl Harbor Naval Shipyard and ^Environs, Honolulu, Hawaii. EPA 520/5-87-010. Washington, D.'C. : U.S. Environmental Protection Agency, Office of Radiation Programs. EPA89 U.S. Environmental Protection Agency, 1989. Environmental Radiation Data, Report 58, April - June 1989. EPA 520/5-89-034. Washington, D.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. 31 ------- REFERENCES — Continued EPA90a U.S. Environmental Protection Agency, 1990. Environmental Radiation Data: Report 59 (July - September 1989). EPA 520/5-90-003. Washington D.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. EPA90b U.S. Environmental Protection Agency, 1990. U.S. Environmental Radiation Data: Report 60 (October - December 1989). EPA 520/5-90-018. Washington, D.C. : U.S. Environmental Protection Agency, Office of Radiation Programs. Ma88 Mangeno, J.J., Steele, J.M., and Poletti, L.F., 1988. Environmental Monitoring and Disposal of Radioactive Wastes from U.S. Naval Nuclear Powered Ships and Their Support Facilities. Naval Sea Systems Command Report, NT-88-1. Se88 Semler, M.O. and Blanchard, R.L., 1988. Radiological Survey of San Diego Bay". EPA 520/5-88-019. Washington, D.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. Sen88 Sensintaffar, E.L. and Blanchard, R.L., 1988. Radiological Survey of the Norfolk Naval Station, the Norfolk Naval Shipyard, and Newport News Shipbuilding. EPA 520/5-88-017. Washington, D.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. 32 ------- REFERENCES — Continued Sm87 Smith, J.M., 1987. Radiological Survey of Charleston Naval Base and Shipyard and the Charleston Naval Weapons Station. EPA 520/5-87-009. Washington, D.C. : U.S. Environmental Protection Agency, Office of Radiation Programs. Wi73 Windhan, S.T. and Phillips, C.R., 1973. Radiological Survey of New London Harbor, Thames River, Connecticut, and Environs. Radiation Data Report 14, No. 11, 659-666, November, 1973. Wi87 Windham, S.T., 1987. Radiological Survey of Kings Bay Submarine Support Facility. EPA 520/5-87-008. Washington, B.C.: U.S. Environmental Protection Agency, Office of Radiation Programs. 33 ------- APPENDIX A Description of Samples Collected Facility/Site No. Samples Collected Electric Boat 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 30 31 32 33 34 Sediment Sediment, Sediment Sediment Sediment Sediment Sediment Sediment, Sediment Sediment Sediment Sediment Sediment Sediment Sediment, Core, Sediment, Sediment Sediment Sediment Sediment Sediment, Core, Surface Water Sediment Sediment Sediment Sediment Sediment, Sediment Drinking Water Sediment Sediment, Sediment Sediment Sediment Surface Water Core, Biota3 Biota8 Surface Water Core, Biota8 Surface Water 34 ------- APPENDIX A — Continued Description of Samples Collected Facility/Site No. Samples Collected Thames River 35 36 37 38 39 40 41 75 Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment New London Submarine Base 29 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 Drinking water Sediment Sediment Sediment Sediment Sediment, Surface Water Sediment Sediment, Core Sediment Sediment Sediment, Surface Water Sediment, Core, Biota3 Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment, Core Sediment, Biota3 35 ------- APPENDIX A — Continued Description of Samples Collected Facility/Site No. Samples Collected New London Submarine Base 67 68 69 70 71 72 73 74 76 88 State Pier 77 78 79 83 84 85 86 87 Sound Signature Facility 80 81 82 Sediment Sediment Sediment Sediment Sediment Sediment, Surface Water, Biota8 Sediment Sediment Sediment Drinking Water Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment Sediment 'The nearest site to the biota collection area. 36 ------- APPENDIX B Concentration of Cobalt-60 in Individual Sediment Samples Site No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 35 36 37 38 Co-60, pCi/g Site No. Co-60, pCi/g 0.23±0.02a 0.07±0.02 0.09±0.01 0.09±0.01 0.07±0.01 0.30±0.03 0.13±0.03 0.2010.04 0.21±0.02 0.18±0.03 0.21±0.02 0.15±0.03 0.23±0.02 0.23±0.02 0.22±0.02 0.16±0.02 New London 0.02±0.01 0.07±0.02 NAC 0.02±0.01 Electric Boat 17 18 19 20 21 22 23 24 25 26 27 30 31 32 33 34 Harbor and Thames River 39 40 41 < 75 0.22±0.02 0.21±0.01 0.21±0.02 0.20±0.02 0.20±0.04 0.39±0.03 0.34±0.02 0.65±0.05 0.16±0.02 0.06±0.01 0.34±0.03 0.07±0.03 0.18±0.02 0.12±0.02 0.17±0.02 0.24±0.04 0.03±0.01b 0.01±0.01b 0.01b 0.11±0.02 New London Submarine Base 42 43 44 45 46 47 48 49 0.05±0.01 0.18±0.02 NA 0.01±0.01 0.15±0.02 0.18±0.02 0.18±0.02 0.18±0.02 59 60 61 62 63 64 65 66 0.21±0.02 0.09±0.02 0.20±0.04 0.05±0.01 0.07±0.01 0.15±0.02 0.19±0.03 0.13±0.02 37 ------- APPENDIX B — Continued Concentration of Cobalt-60 in Individual Sediment Samples Site No. 50 51 52 53 54 55 56 57 58 Co-60, pCi/g 0.19±0.02 0.12±0.03 NA 0.14±0.02 NA 0.18±0.02 0.23±0.04 0.16±0.02 0.21±0.03 Site No. 67 68 69 70 71 72 73 74 76 Co-60, pCi/g 0.17±0.02 0.15±0.02 0.16±0.02 0.06±0.01 0.15±0.02 0.07±0.01 0.16±0.02 0.15±0.02 0.16±0.02 State Pier 77 78 79 83 80 81 0.60±0.05 0.2110.02 0.23±0.03 0.26±0.02 Sound Signature 0.08±0.02 0.20±0.02 84 85 86 87 Facility 82 0.21±0.02 0.16±0.02 0.19±0.03 0.22±0.02 0.20±0.03 "Error term is given as 2—Sigma counting error, Concentration measured in background sample. "NA-Not Analyzed. 38 ------- APPENDIX C Concentration of Radionuclides in Sediment Core Samples Concentration, pCi/a dry weight Depth, cm 2.5 5.1 7.6 10.2 12.7 15.2 17.8 20.3 22.9 25.4 27.9 2.5 5.1 7.6 10.2 12.7 15.2 2.5 5.1 7.6 10.2 12.7 2.5 5.1 7.6 K-40 Cs-137 Electric Boat, 18 0.3 18 0.2 25 0.1 22 0.1 20 0.1 17 0.4 18 0.1 17 0.04 21 24 16 Electric Boat, 18 0.2 18 0.2 19 0.1 19 0.1 22 0.1 20 0.2 Electric Boat, 18 14 0.1 17 0.1 20 0.1 20 0.1 Electric Boat, 25 0.2 20 0.2 20 0.2 Co-60 Ra-226 Site 8 0.18 1.7 0.12 1.8 0.16 0.15 0.15 0.10 0.11 1.6 0.07 2.3 Site 21 0.10 0.11 0.9 0.06 1.7 0.05 2.0 0.12 Site 26 0.07 1.9 0.07 2.0 2.6 Site 15 0.12 0.19 1.5 0.16 1.5 Th-232 0.6 0.7 1.6 0.7 0.8 0.9 0.9 1.1 0.8 2.3 1.0 0.9 1.0 1.6 1.0 0.8 0.7 0.8 1.0 0.8 2.2 1.0 0.9 39 ------- APPENDIX C — Continued Concentration of Radionuclides in Sediment Core Samples Concentration, pCi/q Depth, cm 10.2 12.7 15.2 17.8 20.3 22.9 25.4 27.9 30.5 33.0 35.6 38.1 40.6 43.2 2.5 5.1 7.6 10.2 12.7 15.2 17.8 20.3 22.9 25.4 2.5 5.1 7.6 10.2 K-40 Cs-137 22 22 22 22 19 20 19 24 18 22 20 21 18 18 18 23 16 21 20 20 21 21 17 20 22 16 20 18 Electric Boat, 0.5 0.2 0.2 0.3 0.2 0.2 0.2 0.2 0.2 0.1 0.4 0.2 0.1 Submarine Base, 0.1 0.2 0.1 0.3 0.2 0.2 0.2 0.2 Submarine Base/ 0.2 Co-60 Site 15 0.11 0.17 0.19 0.17 0.15 0.15 0.14 0.12 0.15 0.10 0.15 Site 48 0.16 0.24 0.14 0.16 0.26 0.28 0.37 0.26 0.17 Site 52 0.21 0.31 0.29 dry weight Ra-226 1.6 1.7 1.9 2.0 1.2 2.4 2.4 2.1 Th-232 1.6 0.8 1.0 1.7 0.9 0.9 1.0 1.1 1.7 1.0 1.2 0.9 0.3 0.8 0.8 0.8 0.8 1.3 1.0 1.1 0.9 0.8 1.3 1.8 0.7 1.1 0.8 40 ------- APPENDIX C — Continued Concentration of Radionuclides in Sediment Core Samples Concentration, pCi/q dry weight Depth, cm K-40 Cs-137 Co-60 Ra-226 Th-232 Submarine Base, Site 52 12.7 20 0.2 0.23 1.0 15.2 18 0.2 0.23 1.0 17.8 23 0.1 0.25 2.4 Submarine Base, Site 65 2.5 22 0.1 0.27 0.9 5.1 21 0.36 1.5 7.6 22 0.3 0.29 0.9 10.2 21 0.2 0.23 1.0 12.7 16 0.26 1.2 NOTE: The approximate uncertainties are: K-40 <10%); Cs—137 (60%); Ra-226 (80%); Th-232 (30%); Co-60 (75% for concentrations less than 0.1 pCi/L) ; Co-60 (50% for concentrations between 0.1 and 0.2 pCi/L); Co-60 (35% for concentrations greater than 0.2 pCi/L). 41 ------- APPENDIX D Local Gamma Exposure Rate Survey Location Average Exposure Rate Groton & Eastern Side of Thames River South of Electric Boat 1) Jupiter Point 2) Avery Point 3) Tyler Place on Eastern Point Shoreline, NE of Hobbs Island Shoreline, Point Juck 4) 5) 6) North of Electric Boat 7) Shoreline, North of Electric Boat off Thomas Street 8) Shoreline, Thomas Street at Creaker Memorial 9) Shoreline, Thomas Street at School Street 10) Shoreline, Thomas Street between Board and Bridge Street 11) Shoreline, under 1-95 bridge South of New London Submarine Base 12) Shoreline, South of USS Nautilus Memorial 13) Shoreline, between USS Nautilus and the Submarine Base North of New London Submarine Base 14) North Gate of Submarine Base on Military Highway 15) Military Highway at Mill Cave 16) Shoreline, Bluff Road at Brown's Crossing 17) Shoreline, Riverside Place at Hurlbut Road 10 9 10 6 5 Corner of Shore & Avery St. Mouth of River 8 10 7 3 8 7 11 7 12 7 12 7 42 ------- APPENDIX D — Continued Local Gamma Exposure Rate Survey Average Exposure Rate Location //R/hr New London & Western Side of Thames River Uncasville Area 18) Shoreline, end of Powerhouse Road 6 19) Shoreline, off Lanthrop Road 10 20) Shoreline, end of Lower Bartlett Road 11 Quaker Hill Area 21) Shoreline, end of Cap Road 9 22) Shoreline, end of Richard's Grove Road 10 23) Shoreline, end of Benham Avenue 8 New London, North of 1-95 Bridge 24) Shoreline, end of Saltonstall Street 10 25) Shoreline, end of Farnsworth Street 9 26) U.S. Coast Guard Academy, end of pier for USS Eagle 3 27) Shoreline, end of Lewis Street 7 28) Shoreline, under 1-95 bridge 8 New London, South of 1—95 Bridge 29) Shoreline, off 16th Street, North of State Pier 11 30) Shoreline, Bank Street, between Pearl Street and Captain WK 10 New London, South of Fort Trumbull 31) Shoreline, Pequot Avenue, south of Fort Turmbull 7 32) Shoreline, Pequot Avenue, between Plant and Thames Streets 6 33) Shoreline, Pequot Avenue at Chapel Street 7 34) Shoreline, Pequot Avenue, north of New London Lighthouse 7 35) Shoreline, Pequot Avenue at Lower Boulevard 7 43 ------- APPENDIX D — Continued Local Gamma Exposure Rate Survey Average Exposure Rate Location //R/hr Long Island Sound 36) Shoreline, Pequot Avenue at Neptune Avenue 7 37) Shoreline, Ocean Beach Park 9 New London Submarine Base Base Marina 38) Shoreline, near Bldg. 181 12 39) Shoreline, near Bldg. 387 10 Lower Base Survey 40) Shoreline, near Bldg. 176 6 41) Shoreline, near Bldg. 175 7 42) Shoreline, near Bldg. 174 9 43) Shoreline, near Bldg. 178 9 44) Near RADCON ship berthed between piers 12 & 13 10 Base Golf Course 45) Course Green at first hole 19 46) Course green at second hole 15 47) Course Green at third hole 15 44 ------- |