EPA -660/2-74-033 April 1974 Environmental Protection Technology Series Nitrogen and Phosphorus Losses From Agronomy Plots In North Alabama Office of Research and Development U.S. Environmental Protection Agency Washington, D,C 20460 ------- PESEARCH KFPOKTING SERIES Research reports of the Office of Research and Monitoring*. Environmental Protection Aqency, have been grouped into five series. These five bread categories were established to facilitate further development and application of environmental technology. Elimination of traditional grouping was consciously planned to foster technology transfer and a maxizmni interface in related fields. The five series are: 1* Environmental Health Effects Research 2, Environmental Protection Technology 3. Ecological Research 4. Environmental Monitoring 5. Socioeconomic Environmental Studies This report has been assigned to the ENVIRONMENTAL PROTECTION TECHNOLOGY series. This series describes research performed to develop and demonstrate instrumentation, equipment and methodology to repair or prevent environmental degradation from point and non-point sources of pollution. This work provides the new or improved technology required for the control and treatment of pollution sources to meet environmental quality standards. EPA REVIEW NOTICE This report has been reviewed by the Office of Research and Development, EPA, and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Environmental Protection Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use* ------- EPA-660/2-74-033 April 1974 NITROGEN AND PHOSPHORUS LOSSES FROM AGRONOMY PLOTS IN NORTH ALABAMA By Robert R. Bradford Alabama A. & M. University Normal, Alabama 35762 Grant No. 800401 Project 13020 DWH Program Element 1BB039 Project Officer Dr. George W. Bailey Southeast Environmental Research Laboratory Athens, Georgia 30601 Prepared for OFFICE OF RESEARCH AND DEVELOPMENT U.S. ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C 20460 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20*02 - Price 90 cents ------- ABSTRACT A study of nitrogen and phosphorus losses from Decatur silt loam soil was conducted over three cropping periods from 1969-1972. Experimental agronomy plots at Alabama A. & M. University were seeded to cotton, corn, soybeans, and millet and compared with uncropped and unfertilized check plots. The effects of these crops on nitrogen losses total nitrogen, nitrate- nitrogen, and ammonium-nitrogen (for 1971-1972 only) and phosphorus losses were evaluated. Average total rainfall and losses of sediment and runoff were also determined. Losses of total nitrogen and nitrate-nitrogen were generally positively correlated with the amounts of rainfall, runoff, and sediment. Phos- phorus losses were positively correlated with sediment losses. More than 95% of phosphorus losses were associated with sediment loss. Corn was generally more effective in reducing total nitrogen and nitrate- nitrogen losses via surface runoff than cotton; whereas nitrate-nitrogen concentrations in subsurface water were lower in samples from cotton plots. The effect of crops on loss of all nutrients was considerably smaller than seasonal effects and sediment losses. The effect of two fertilizers, ammonium nitrate and sulfur-coated urea (a slow-release nitrogen fertilizer), upon nutrient losses showed no evidence of superiority for sulfur-coated urea in reducing the total nitrogen or nitrate-nitrogen losses. This report was submitted in fulfillment of Project Number 13020 DWH, Grant Number 800401, by the Department of Natural Resource and Environ- mental Studies, Alabama Agricultural and Mechanical University, under the (partial) sponsorship of the Environmental Protection Agency. Work was completed as of December 1972. ii ------- CONTENTS Page No. Abstract ii List of Figures iv List of Tables v Acknowledgments vii Sections I Conclusions 1 II Recommendations 2 III Introduction 3 IV Experimental Approach 4 V Results and Discussion 8 VI References 38 VII Glossary 40 ill. ------- FIGURES No, Page No. 1 Relationships between Rainfall, Runoff, and Sediment during the 1969-1970 Season 9 2 Nitrogen Losses from Plots through Surface Runoff during the 1969-1970 Season 15 3 Phosphorus Losses from Plots through Surface Runoff during the 1969-70 Season 18 A Relationships between Rainfall, Runoff, and Sediment during the 1970-1971 Season 21 5 Nitrogen Losses from Plots through Surface Runoff during the 1970-1971 Season 26 6 Phosphorus Losses from Plots through Surface Runoff during the 1970-1971 Season 28 7 Relationships between Rainfall, Runoff, and Sediment during the 1971-1972 Season 30 8 Nitrogen Losses from Plots through Surface Runoff during the 1971-1972 Season 34 9 Phosphorus Losses from Plots through Surface Runoff during the 1971-1972 Season 37 iv ------- TABLES No. Page No. 1 Average Loss of Total Nitrogen through Surface Runoff from Plots Seeded to Different Crops, 1969-1970 10 2 Average Concentration of Nitrate-Nitrogen in Surface Runoff from Plots Seeded to Different Crops, 1969-1970 11 3 Average Loss of Nitrate-Nitrogen through Surface Runoff from Plots Seeded to Different Crops, 1969-1970 12 4 Average Concentration of Nitrate-Nitrogen in Subsurface Water from Plots Seeded to Different Crops, 1969-1970 13 5 Average Loss of Phosphorus through Surface Runoff from Plots Seeded to Different Crops, 1969-1970 16 6 Average Loss of Total Phosphorus in Sediment Derived From Plots Seeded to Different Crops, 1969-1970 17 7 Average Loss of Total Nitrogen through Surface Runoff From Cotton and Corn Plots Treated with Sulfur- Coated Urea and Ammonium Nitrate, 1970-1971 22 8 Average Loss of Nitrate-Nitrogen through Surface Runoff From Cotton and Corn Plots Treated with Sulfur- Coated Urea and Ammonium Nitrate, 1970-1971 23 9 Average Loss of Nitrate-Nitrogen through Surface Runoff from Plots Seeded to Different Crops, 1970-1971 24 10 Average Loss of Total Nitrogen through Surface Runoff from Plots Seeded to Different Crops, 1970-1971 25 11 Average Loss of Phosphorus through Surface Runoff from Plots Seeded to Different Crops, 1970-1971 27 12 Loss of Total Nitrogen through Surface Runoff from Corn and Millet Plots Treated with Sulfur-Coated Urea and Ammonium Nitrate, 1971-1972 31 13 Loss of Nitrate-Nitrogen through Surface Runoff from Corn and Millet Plots Treated with Sulfur-Coated Urea and Ammonium Nitrate, 1971-1972 32 ------- TABLES (continued) No. Page No. 14 Loss of Ammonium-Nitrogen through Surface Runoff from Corn and Millet Plots Treated with Sulfur-Coated Urea and Ammonium Nitrate, 1971-1972 33 15 Loss of Phosphorus through Surface Runoff from Corn and Millet Plots Treated with Sulfur-Coated Urea and Ammonium Nitrate, 1971-1972 35 vi ------- ACKNOWLEDGMENTS Dr. Robert R. Bradford was the principal investigator of this study. Dr. Luke Mugwira was the associate investigator during the last year. Mr. Leslie Glover, an undergraduate student in the Department of Natural Resource and Environmental Studies, provided assistance in field-related activities while Mr. V. J. Thakore and Mr. Donald Outland, Research Assistants, assisted in the chemical and physical analyses of samples. Support of the project by the Office of Research and Development, Envi- ronmental Protection Agency, and the cooperation of Dr. George W. Bailey, Grant Project Officer, are gratefully acknowledged. vii ------- SECTION I CONCLUSIONS 1. Average monthly losses of nitrate-nitrogen (N03-N) and soluble phos- phorus (P) from small cotton, corn, millet, and soybean plots which had been treated with fertilizers were approximately the same as losses from uncropped and unfertilized check plots. 2. The concentration of NOj-N in subsurface water was higher than the concentration observed in surface runoff; magnitudes of five-fold were observed in some cases. This suggested that, for this soil, more NOo-N may have been lost through infiltration and percolation than via surface runoff * 3. Loss of nitrogen (N) as ammonium-nitrogen (NH^-N) in surface runoff from the first two or three runoff producing rains following appli- cation of fertilizers may constitute a more serious problem than loss of NOo-N over the same interval. The surface losses of NO^-N accounted for only 25% of the total N lost from the plots. 4. Sediment borne N and F constituted the greater loss of these two nutrients. More than 95% of P was lost with the sediment. 5. The slow-release nitrogen used in this study showed no evidence of being superior to ammonium-nitrate in reducing loss of N03~N or total N. Losses of NH^-N from sulfur-coated urea (SCU) treated plots were higher during the first three runoff producing rains than from plots treated with ammonium-nitrate. This may have been accen- tuated by the actual runoff of SCU pellets from the plots along with surface water and sediment. 6. The type of crop grown may be a factor in loss of N. ------- SECTION II RECOMMENDATIONS 1. Growers should be encouraged to use management and tillage practices which minimize erosion of croplands since the most serious losses of N and P occurred as sediment contained in surface runoff. 2. Nitrogen and phosphorus requirements of major agronomic crops should be established for the different geographical regions. 3. The optimum time to apply fertilizers to agronomic crops should be determined. This is particularly needed where double cropping is practiced since plant cover greatly influences loss of nitrogen and phosphorus. 4. Growers should be encouraged to apply fertilizers at rates not in excess of those recommended on the basis of soil test results. 5. Slow-release nitrogen fertilizers should be developed which release N sufficient for adequate growth and nutrition of plants but which reduce the need to apply large quantities of nitrogen. If such fertilizers are in pellet form, care should be taken in the incorpo- ration of such fertilizers into the soil. ------- SECTION III INTRODUCTION There is considerable interest in the fate of nitrogen and phosphate fertilizers applied to croplands. Some environmentalists believe that nitrogen lost from fertilized fields through percolation and surface runoff and phosphorus losses through surface runoff signifi- cantly contribute to the eutrophication of waterways in the United States and also reduce the quality of drinking water. The North Alabama area of the Tennessee Valley has annual rainfall of about 140 cm which results in high amounts of runoff and erosion, and possible loss of fertilizers from fields to which they are applied into rivers and reservoirs. Previous research data from different regions suggest that the amount of nitrogen removed from croplands depends on the kind of nitrogen fertilizer, crop, rainfall, and associated cultural practices.1»2,3 It has been found that phosphorus is lost through erosion essentially as sediment-borne P, and very little is lost through leaching and runoff water.5,6,7 There is, however, no general agreement on how much nitrogen and phosphorus are contributed to water bodies by agri- culture. Thus it has been suggested that the prolification of Milfoil and algal blooms in several areas may be caused by changes in the nutri- ent budget which created conditions ideal for growth of aquatic plants. Some environmentalists believe that losses of nutrients from commer- cial fertilizers applied to agricultural land play a significant role in the increased instances of eutrophication.9 Others argue that many water bodies naturally have enough NOg-N to support algal blooms and that good plant cover reduces sediment loss from land through runoff and thus enhances water quality.10 The objectives of this study were to: 1. Determine amounts of nitrogen and phosphorus in surface runoff from Decatur silt clay loam soil under un-cropped and cropped (cotton, corn, soybeans, and millet) conditions* 2. Compare nitrogen and phosphorus losses through surface runoff from plots treated with a slow-release nitrogen source and a conventional nitrogen source. 3 ------- SECTION IV EXPERIMENTAL APPROACH A field containing Decatur site play loam, which had not been cropped for several years, was selected for use in this investigation. Two adjacent sites with 1% and 6% slope, respectively, were graded to uniform slope. Each site contained seven hydrocollection units (plots) 2.4 m x 4.6 m and were spaced 2.1 m apart in order to minimize fertili- zer contamination. Each hydrocollection unit was marked by metal frames 2.4-m wide, 4.6-m long, 0.5-m high, and imbedded into the soil to a depth of 15 cm. Surface runoff from the plots was directed into 190-liter holding tanks through 15-cm diameter metal conduits installed at ground level. The holding tanks were fitted with covers to prevent unwanted precipitation from entering. Suction lysimeters consisting of a plastic pipe, 5 cm in diameter, capped on the lower end by a porous ceramic cup, and designed to per- mit intake and removal of subsurface water were installed to a depth of 1.2 m in the center of each plot. The.lysimeters were maintained in an evacuated condition between sampling periods by means of a porta- ble vacuum pump. Two rain gauges were located in the test area for collecting data on natural rainfall. No supplementary irrigation was used during the investigation. After each runoff producing rain repre- sentative runoff samples were taken in duplicate from each holding tank. These samples were stored at 0°C prior to chemical analysis. 1969-1970 CROPPING AND RUNOFF SEASON Initial soil analyses were: Total N In top 15 cm 9.1 kg/ha Total P in top 15 cm 414 g/ha Soluble P in subsurface water (1.2 m) 0.44 mg/1 During the first year of the study, losses of N and P in runoff and percolating water were monitored from the plots cropped with 'Stone- ville1 cotton, 'Pioneer 309B1 corn, and 'Hood1 soybeans. Each crop ------- was planted in two plots. A check plot was left at each site and crops were randomized within each site. Fertilizers for the following crops were applied as NH,N03 and 0-20-20 broadcast and disked under at the following (kg/ha) rates: N P205 K20 Cotton ----------- 22 67 67 Corn --------------- 22 62 62 Soybeans ---------- 0 45 45 Because of the delayed funding of this proposal, the crops were planted on August 12 which was late in the season for these crops in North Alabama; therefore, no sidedressing with additional 67 kg/ha of N was made as originally planned. The plants were harvested on October 15 and barley was planted on all plots to provide a winter cover crop. Total nitrogen, which includes organic-nitrogen plus ammonium-nitrogen, was determined in surface runoff by Kjeldahl method. Nitrate-nitrogen and soluble phosphorus were determined in surface runoff and subsurface samples by methods recommended by FWPCA.H Surface runoff and subsurface water were filtered to remove sediment prior to analysis for nitrate- nitrogen and soluble phosphorus. Sediment content in surface runoff samples was determined by thoroughly mixing one liter of surface runoff, then quickly decanting the homo- geneous sample into a tared 100-ml beaker. The sample was then brought to dryness on a steam plate and the beaker reweighed.12 Total phosphorus and organic phosphorus in sediments removed from sur- face runoff were determined by procedures described in Methods of Soil Analysis . Total nitrogen in sediments removed from surface runoff was determined by the Kjeldahl method. Rainfall data were obtained via two rain gauges located in the plot area. Statistical tests employed to compare data collected were analysis of variance, least significant difference (LSD), and simple correlation. A preliminary analysis of variance of the data indicated that there were no significant differences between the two sites for the para- meters studied. Consequently, the two sites were treated as blocks for the three cropping seasons (1969-1972). 1970-1971 CROPPING AND RUNOFF SEASON The practices employed during the first year of the investigation were repeated in 1970 and 1971 with some modifications. In the second year, nitrogen losses were evaluated as a function of N fertilizer. Conven- tional ammonium nitrate (AN) was compared with slow-release fertilizer, sulfur-coated urea (SCU-D), supplied by the Tennessee Valley Authority. ------- This experiment was intended to evaluate relative losses of N in run- off as influenced by these two N fertilizers. Fertilizers for the crops shown were applied at the following (kg/ha) rates: N Cotton 90 67 67 y u o i \* 2 0 45 45 The following chemical composition and dissolution rates were calcu lated from weighted average values for this SCU blend: Composition Dissolution rate, % N Daily Z N % S _ 7 days 7-14 days 29.6 30.8 9.0 0.3 The dissolution rates were measured in water at 38°C. Sulfur-coated urea contained 3% sealant (wax) and 0.25% microbiocide (coal tar) over- laid on a layer of sulfur. The same cotton, corn, and soybean varie- ties used in the first year were planted on May 11. Barley was grown on all plots as a winter cover crop. Because of the very low concentrations found in 1969-1970 samples, subsurface water was not analyzed for NO^-N and soluble P. Analytical techniques for measuring N and P losses, statistical methods, and meteorological procedures were the same as those used in 1969-1970 season* 1971-1972 CROPPING AND RUNOFF SEASON Data for 1970-1971 showed no significant difference in N loss between the three row-crops grown; therefore, in 1971-1972 cotton and soybeans were replaced by a forage crop, namely millet. It was thought that because of the tillered growth characteristics of millet, it might sub- stantially differ from corn which is a typical representative of row crops. Plots were rototilled and fertilized on April 3rd. Millet and corn were planted on May 16. Efforts were made to quantify N and F losses during ten runoff producing rain periods from April 1971 through March 1972. Surface runoff samples from the plots were analyzed for NIfy-N in addition to the analyses indi- cated for the 1969-1970 season. Collection of rainfall data and statis- tical tests used were the same as described for the first year of the study. 6 ------- Crops grown, replications, fertilizers (application methods were the same as for the 1969-1970 season) and their rates for the 1971-1972 season are shown below: Crop Corn Corn Millet Millet Fallow Replications 3 3 3 3 2 N Source N NH4N03 100 SCU 100 NH4N03 100 SCU 100 00 Kg/ha P205 35 35 35 35 00 K20 35 35 35 35 00 ------- SECTION V RESULTS AND DISCUSSION 1969-1970 CROPPING AND RUNOFF SEASON Results Rainfall data (cm/mo) on plot area during the 1969-1970 season are given below: Sept. 11.15 Oct. 6.32 Nov. 6.30 Dec. 22.71 Jan. 6.02 Feb. 7.34 Mar. 14.96 Apr. 23.06 The average total monthly rainfall, surface runoff, and sediment losses for the 1969-1970 cropping and runoff season are shown in Figure 1. Rainfall was high in September, December, March, and April and was uniformly lower during the rest of the season. The average monthly runoff and sediment losses followed distribution patterns similar to those observed for rainfall (Fig. 1). Nitrogen Losses The average monthly total nitrogen loss, the concentration and total loss of NOq-N in surface runoff, and the concentration of NOq-N in subsurface water are shown in Tables 1, 2, 3, and 4, respectively. All of these forms of nitrogen were significantly affected by the type of crop and the time (month) of the season. The total N loss in the sea- son increased only where cotton was planted (Table 1). The average N03-N concentration in surface runoff was significantly higher in plots planted to cotton, corn, and soybeans than in runoff from check plots (Table 2). When averaged over the 8-month sampling period, total N03-N losses through surface runoff from plots planted to cotton were lower than losses from corn and soybean plots (Table 3). However, the concentration of N03~N in the subsurface water was higher only on corn plots (Table 4). 8 ------- 60 i 50 o LU CO 40 o n 30 o to 20 10 0 RAINFALL (cm) RUNOFF (liters/ha) XlO'l SEDIMENT (kg/ha) X2X1Q-2 * A * \\ » m * * I \ * * * I \ > / \ * « / \ / \ I * ' * I \ * * : / \ : : : ' \ ' * * : / \ ' 'V // \\ /// V V\.>7 A--« -* .»'**-**,. A ' -A. A- I I I 1 x/ / * I SEPT. OCT. NOV. DEC. JAN. FEB. MAR. APR. Figure 1. Relationships between rainfall, runoff, and sediment during the 1969-1970 season. ------- Table 1. AVERAGE LOSS OF TOTAL NITROGEN THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (kg/ha) 1969-1970 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means Cotton 10.8 9.5 9.0 24.6 9.0 8.4 15.8 24.6 14.0 Corn 8.4 6.3 6.2 18.5 7.3 6.7 14.0 19.7 10.9 Crops Soybeans 10.1 6.7 6.7 21.3 6.7 6.2 15.7 16.9 11.3 Check 9.1 6.2 5.6 20.7 5.6 5.6 13.4 17.9 10.5 Means 9.6 7.2 6.9 21.3 7.2 6.7 14.8 19.8 LSD at 0.05 for comparing means: F ratio Crops 1.2 8'9S2 Months 1.7 68.1 *, ** Significant at the 5% and 1% level of probability, respectively, 10 ------- Table 2. AVERAGE CONCENTRATION OF NITRATE-NITROGEN IN SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (fflg/1) 1969-70 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means LSD at 0.05 Crops Months Crops Cotton 0.17 0.11 0.10 0.23 0.17 0.20 0.23 0.19 0.17 for comparing Corn 0.22 0.10 0.09 0.24 0.18 0.22 0.25 0.20 0.19 means : Soybeans 0.20 0.15 0.13 0.33 0.12 0.16 0.25 0.17 0.19 0.03 0.04 Check 0.17 0.07 0.12 0.18 0.11 0.14 0.18 0.16 0.14 F ratio A *| 7^* Means 0.19 0.11 0.11 0.24 0.14 0.18 0.22 0.18 * Significant at the 5% level of probability, 11 ------- Table 3. AVERAGE LOSS OF NITRATE-NITROGEN THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (g/ha) 1969-1970 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means LSD at 0.05 Crops »* .«_*_ Crops Cotton 4.48 4.48 3.47 11.76 5.71 2.80 26.32 33.15 11.52 for comparing Corn 7.28 4.03 3.92 15.23 7.39 4.03 31.92 34.83 13.58 means: Soybeans 5.71 7.84 6.27 17.47 6.16 3.47 32.48 31.36 13.85 F 1.86 n £.* 1 1 Check 5.15 3.36 5.60 11.31 4.48 2.80 24.08 28.56 10.67 ratio 7.U* to o ** Means 5.65 4.93 4.82 13.94 5.94 3.28 28.70 31.98 *, ** Significant at the 5% and 1% level of probability, respectively. 12 ------- Table 4. AVERAGE CONCENTRATION OF NITRATE-NITROGEN IN SUBSURFACE WATER FROM PLOTS SEEDED TO DIFFERENT CROPS (mg/D 1969-1970 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means Crops Cotton 0.92 0.25 0.23 0.90 1.03 1.08 1.17 1.07 0.83 LSD at 0.05 for comparing Crops Months *, ** Significant at the Corn 1.16 0.24 0.22 1.15 1.15 1.10 1.11 1.17 0.91 means: 5% and 1% Soybeans Check 0.92 0.22 0.21 0.91 0.98 0.97 1.05 0.93 0.77 0.06 0.09 level of 0.96 0.20 0.17 0.95 0.91 1.05 1.07 1.00 0.79 F ratio 4 -4 78.3 probability, Means 0.99 0.23 0.20 0.98 1.02 1.05 1.10 1.04 respectively. 13 ------- Losses of total N and NO^-N and the Nt^-N concentrations were generally positively correlated with the amounts of rainfall, runoff, and sedi- ment loss. The highest levels of each of the six parameters occurred during the months of December, March, and April and also in Septem- ber in the case of N03-N concentration (Figs. 1 and 2). The following data also indicate that the N and P losses were significantly corre- lated with the amount of runoff and sediment losses. Correlation coefficient (r) relating surface runoff and sediment loss to nitrogen and phosphorus (P) levels is given below: Surface runoff Sediment Sediment loss .707** Total N03-N .948** .733** Total N .619** .913** Soluble P .724** .437* The concentration of N03~N in subsurface water was five times higher than in surface runoff and remained approximately 1 ppm during the growing season except for the low values in October and November (Table 4). Phosphorus Losses The data in Table 5 indicate that the losses of soluble P through run- off and percolation were not Influenced by the type of crop grown. Although the level of soluble P in surface runoff did not change during the sampling period, total loss of soluble P by runoff and the con- centration of the P in subsurface water changed between different months (Table 5). Total soluble P in surface runoff was higher in March than in other months. Total soluble P in surface runoff, sedi- ment P, and organic P in sediment loss were generally correlated with rainfall and runoff (Figs. 1 and 3). Comparison of data in Tables 5 and 6 indicate that nearly all P losses from the plots were due to sediment loss. Organic P losses accounted for approximately 30 to 40% of the total P lost from the plots. Concentration of P in subsurface water was quite variable and was not significantly affected by the crop. These P levels were higher from September to December than from January to April. The concentrations of P in surface runoff and in subsurface water are within the range reported by Duley1^ who found P contents of 0.12 to 1.50 ppm in surface runoff water collected from a set of unfertilized erosion plots receiv- ing natural rainfall. 14 ------- 40 Ul UJ 30 20 10 60 h - "TOTAL N (kg/ha) ^Nof-N (g/ha) 50 X10'z ..._... \\ *- * * I I 1 I I I I _ _ I SEPT. OCT. NOV. DEC. JAN. FEB. MAR. APR. Figure 2. Nitrogen losses from plots through surface runoff during the 1969-1970 season. 15 ------- Table 5. AVERAGE LOSS OF PHOSPHORUS THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (g/ha) 1969-1970 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means LSD at 0.05 Crops Months Crops Cotton 5.4 6.0 5.4 10.5 8.0 2.4 18.1 8.4 8.0 for comparing Corn 5.6 10.2 9.0 11,3 9.1 3.9 18.8 14.0 10.2 means: Soybeans 4.3 4.1 9.5 11.3 8.5 2.8 15.8 18.0 9.3 3.6 Check 4.4 9.6 8.3 4.5 6.9 1.3 9.9 11.0 6.9 F ratio NS 11.1* Means 4.9 7.5 8.1 9.4 8.1 2.6 15.7 12.7 * Significant at 5% level of probability NS Non-significant 16 ------- Table 6. AVERAGE LOSS OF TOTAL PHOSPHORUS IN SEDIMENT DERIVED FROM PLOTS SEEDED TO DIFFERENT CROPS (kg/ha) 1969-1970 Month Sept. Oct. Nov. Dec. Jan. Feb. Mar. Apr. Means LSD at 0.05 Crops Months Crops Cotton 12.3 11.2 11.2 61.6 11.2 6.7 29.1 90.7 29.3 for comparing Corn 11.2 6.7 6.7 39.7 6.7 6.7 22.4 50.4 18.8 means : Soybeans 12.3 6.7 11.2 45.9 11.2 6.7 29.1 50.4 21.7 11.87 Check 16.8 11.2 11.2 45.9 11.2 5.6 28.0 40.3 21.3 F ratio NS 24.62** Means 13.2 8.9 10.0 48.2 10.0 6.4 27.1 57.9 NS Non-significant ** Significant at the 1% level of probability 17 ------- 60 50 40 to LU £ \l 20 10 SOLUBLE P (g/ha) ^RUNOFF P (kg/ha) XIO3 SEDIMENT P (kg/ha) I ;* 'i ^ i!\ :: * :\ J I \ I i SEPT. OCT. NOV. DEC. JAN. FEB. MAR. APR. Figure 3. Phosphorus losses from plots through surface runoff during 1969-1970 season. 18 ------- Discussion To determine nitrogen losses from surface runoff in 1969-1970, data were collected for total N and N03-N. Of these, N03~N losses were only a small percent (generally less than 1%) of the total. Total N losses were invariably associated with high rainfall months as exemplified by the high values in December, March, and April. Rain- fall was the single most important factor affecting N losses through surface runoffs and its impact can be seen on cropped and fertilized as well as on check plots (Table 1). Contribution of nitrate from farmland to the ground water is of inter- est in terms of causing contamination of drinking water. For the 1969-1970 season, N03-N losses in subsurface water were not correlated with rainfall (Table 4). The data for this period indicated that cotton because of its growth habit, elaborate root structure, and long- er growing season was more efficient than corn in reducing loss of N03-N in subsurface water. In general, these losses were approximately at the level of 1 ppm (Table 4). Although this concentration of nitrate in the subsurface water exceeded 0.03 ppm N03~N level that would cause eutrophication,-^ it is doubtful that these losses signifi- cantly affect water quality. Additional dilution of such concentra- tion in ground water should also be considered when interpreting such data. Phosphorus Losses Our data confirms earlier findings that a very large amount of P is lost with the sediment; only 1% or less P leaves the cropland in soluble formr The concentration of P lost can generally be estimated by multiplying the total sediment lost by the total P content of sediment which, in this study, was found to be 0.5%. The type of crop did not affect soluble P loss. Since soluble P is in equilibrium with sediment P and it is in greater magnitude, practices which would reduce erosion would contribute considerably toward reducing loss of total P from cropland. 1970-1971 CROPPING AND RUNOFF SEASON Results Rainfall data (cm/mo) on plot area during the 1970-1971 season are given below: May 7.34 June 6.60 July 6.02 Aug. 7.29 Sept. 5.08 Oct. 10 .74 Nov. 6 .60 Dec. 5 .26 Jan. 8.38 19 ------- The average total monthly rainfall, runoff, and sediment losses from the experimental plots during the 1970-1971 season are shown in Figure 4. The highest monthly rainfall occurred in October, followed by May and January, with monthly precipitation varying between 5.08 cm and 6.60 cm during the rest of the season. Monthly runoff and sediment generally followed a similar pattern as rainfall. The data were analyzed initially to compare N loss for the two differ- ent fertilizer materials, sulfur-coated urea and ammonium nitrate. A second analysis was done to compare N and P losses among corn, cotton, soybeans, and check plots. Nitrogen Losses The results for total N losses and losses of N03-N through surface run- off from plots that received AN and SCU are given in Tables 7 and 8. Neither fertilizer source showed evidence of being superior to the other in reducing losses of N03-N or total N via surface runoff during the 1970-1971 season. The fluctuation of average monthly concentrations of N03-N in surface runoff generally followed those of average monthly rainfall and runoff. Data for comparing the effects of cotton, corn, and soybeans on N losses are shown in Tables 9 and 10. The total N loss and total losses of N03-N are not significantly affected by the type of crop. Differ- ences in concentrations and total losses of NOg-N during the season were apparently a result of fluctuations in surface runoff. Compari- son of the data in Tables 7 and 8 indicate that N03~N accounted for only 4% of the total N loss from the plots. The nitrogen losses from plots via surface runoff during 1970-1971 season are shown in Figure 5. Phosphorus Losses It was assumed that SCU and AN would probably not influence P losses from plots and no statistical tests were made to compare the effects of the two fertilizers on P losses. Table 11 shows P losses as func- tions of the type of crop and month during the 1970-1971 season. The average total P content in sediment was approximately 0.5%. Consider- ing the amounts of sediment in the runoff from plots (Fig. 4), it is evident that most of the P losses were due to sediment losses. The data in Figures 4 and 6 show that total P in surface runoff was closely associated with sediment loss throughout the 1970-1971 season. Discussion Nitrogen and phosphorus losses from plots were not affected by growing cotton, corn, or soybeans nor by SCU and AN applications equivalent to 90 kg/ha of N on cotton and corn plots. These losses were generally increased by high rainfall and were correlated with runoff and sediment 20 ------- £ Ul 1-4 a UJ in a 3~ U- u. 0 C£ m _J j£ i ll- CS to L_ J~ 0 ^ 100 90 80 70 60 50 40 30 20 10 n mm - "RAINFALL (cm) / ARUNOFF (liters/ha) / .......... SEDIMENT fka/ha} / * - / : / s A.-/--A \ - t . : / / M *f * / / . t \ \ // \\ * / / / > A \\ ' / \\ ' A / / » / » / * * \\ * : \: / *. \ ^ / »: / \ \ S ! V: \ X .x / V: / * v / 5 - *. » / ^ A * * » " ^ * ** * - i / «* ^.,.--""ii^-.-'- ^ .__j(/l-- i " ii i.* i , JUNE JULY AUG. OCT. NOV. DEC. JAN. Figure 4. Relationships between rainfall, runoff, and sediment during the 1970-1971 season. 21 ------- Table 7. AVERAGE LOSS OF TOTAL NITROGEN THROUGH SURFACE RUNOFF FROM COTTON AND CORN PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1970-1971 Month June July Aug. Oct. Nov. Dec. Jan. Means LSD at 0.05 Crops Fertilizer Months Corn SCU 172 199 228 146 142 22 216 161 for comparing Sources AN 61 189 197 130 243 24 177 146 means: Cotton SCU 202 187 23 292 292 19 239 179 AN 116 260 47 249 682 25 209 227 F ratio NS NS NS Means 138 209 124 204 340 22 210 NS Non-significant 22 ------- Table 8. AVERAGE LOSS OF NITRATE-NITROGEN THROUGH SURFACE RUNOFF FROM COTTON AND CORN PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1970-1971 Month June July Aug. Oct. Nov. Dec. Jan. Means Grand Means LSD at 0.05 for Crops Fertilizer Months Corn SCU 8.1 1.0 8.8 3.0 8.1 0.4 3.0 4.6 5. comparing sources Cotton AN 6.0 4.2 7.6 2.9 21.3 0.4 1.9 6.3 5 means: SCU 16.4 2.4 3.2 24.5 8.9 0.3 4.5 8.6 5.5 AN 6.8 2.4 2.0 4.6 25.3 1.8 9.0 7.4 8.0 F ratio NS NS 6.7* Means 9.3 2.5 5.4 8.7 15.9 0.7 4.6 NS Non-significant * Significant at the 5% level of probability. 23 ------- Table 9. AVERAGE LOSS OF NITRATE-NITROGEN THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (g/ha) 1970-1971 Month June July Aug. Oct. Nov. Dec. Jan. Means LSD at 0 Crops Months Crops Cotton Corn 11.6 2.4 2.6 14.5 17.1 1.0 6.8 8.0 .05 for 7.1 2.6 8.2 3.0 15.7 0.4 2.4 5.5 comparing means: Soybeans 17.9 5.1 9.6 5.6 10.0 2.3 5.8 8.1 F 5.5 5. Check 12.2 4.4 6.5 1.6 4.8 0.6 3.0 4.7 ratio NS 6** Means 12.2 3.7 6.7 6.2 11.7 1.1 4.5 NS Non-significant ** Significant at the 1% level of probability 24 ------- Table 10. AVERAGE LOSS OF TOTAL NITROGEN THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (g/ha) 1970-1971 Month June July Aug. Oct. Nov. Dec. Jan. Means LSD at 0.05 Crops Crops Cotton 158 224 35 270 487 22 224 203 for comparing Corn 116 194 213 137 193 23 196 153 means : Soybeans 114 373 138 121 161 46 203 165 F i -i c e Check 193 202 96 170 345 40 159 172 ratio NS ..** Means 146 248 120 175 296 33 196 Months NS Non-significant ** Significant at the 1% level of probability 25 ------- UJ 100 90 80 70 60 50 40 30 20 10 I 0 TOTAL N (kg/ha) X10'1 FERTILIZERS AND CROPS N03-N (mg/1) X10? FERTILIZERS^ CROPS* N03-N (g/ha) FERTILIZERS? AND CROPS6 :\ r^\ \\ \\ JUNE JULY AUG. OCT. NOV. DEC. JAN. Figure 5. Nitrogen losses from plots through surface runoff during the 1970-1971 season. 26 ------- Table 11. AVERAGE LOSS OF PHOSPHORUS THROUGH SURFACE RUNOFF FROM PLOTS SEEDED TO DIFFERENT CROPS (g/ha) 1970-1971 Month June July Aug. Oct. Nov. Dec. Jan. Means LSD at 0.05 Crops Months Crops Cotton 4.5 1.2 0.4 5.4 18.9 0.5 2.5 4.8 for comparing Corn 5.6 1.8 3.8 4.3 7.8 0.4 2.4 3.7 means: Soybeans 4.3 1.0 1.0 1.2 4.0 0.8 1.3 1.9 3.9 Check 1.0 0.3 0.5 0.8 6.0 0.3 0.8 1.4 F ratio NS 4.4** Means 3.8 1.0 1.4 2.9 9.2 0.5 1.8 NS Non-significant ** Significant at the 1% level of probability 27 ------- Ul cc SOLUBLE P (mg/1) XI0 IN RUNOFF ATOTAL P (g/ha) IN RUNOFF SEDIMENT P (g/ha) X10-2 A ; \ I I \ JUNE JULY Figure 6. Phosphorus losses from plots through surface runoff during the 1970-1971 season. 28 ------- loss suggesting that the seasonal conditions were more important con- siderations in controlling N and P losses from fields than were crop type and fertilizer forms. Phosphorus data supported findings of the first cropping year which indicated that practically all P losses from the plots were associated with sediment. 1971-1972 CROPPING AND RUNOFF SEASON Results Rainfall data (cm/runoff producing rain) on plot area during the 1971-1972 season are given below: Apr. 4/6 July 7/16 Aug. 8/6 Dec. 12/3 Dec. 12/11 Dec. 12/27 Jan. 1/3 Jan. 1/18 Feb. 2/1 Mar. 3/17 8.36 11.94 7.54 5.72 11.44 6.55 8.46 8.28 6.55 12.55 For 1971-1972 the data (surface and sediment runoffs, rainfall, total N, P, etc.) were prescribed for each runoff producing rain period rather than averaged over a month as was done in 1969-1970 and in 1970-1971. The average total rainfall, runoff, and sediment losses from the plots during 10 runoff producing periods for the 1971-1972 season are given in Figure 7. Runoff did not follow a similar distribution pattern to that of rainfall during most of the runoff producing rains. The lack of correlation between rainfall and runoff may have been due to varia- ble rainfall intensity during the intervals between runoff periods. Nitrogen Losses When compared with check plots, growing corn and millet did not reduce nitrogen losses from the plots (Tables 12, 13, and 14). However, total N and nitrate-nitrogen losses were significantly affected by AN, SCU, and by time of sampling during the season. The losses of N over the 1971-1972 cropping and runoff season were higher for SCU and AN treated plots than for check plots. Total N losses occurring in the first four runoff producing periods accounted for 50 to 70% of all N losses moni- tored- (Fig. 8). Losses of N during the remaining 1971-1972 season were relatively uniform. However, Nfy-N losses were approximately five times those observed for NOo-N. Computations from data in Tables 12 and 14 indicate that Nfy-N loss accounted for about 20% of total N losses through runoff. Phosphorus Losses Total loss of P in 1971-1972 season are shown in Table 15. Corn and millet did not affect P losses from plots when compared with check plots. 29 ------- 100 90 .... |80 O UJ "» 70 o «£ u! 60 u_ o S 50 m _l _l i 40 »t g fe 30 H- I 20 "* 10 n "RAINFALL (cm) _= A RUNOFF ( 1 i ters/ha ) .......... SEDIMENT fka/ha) X1Q~2 A /\ / \ \A ^ A. A / % V / \ » \ ^ * ^ \ 'A \ *A V \ / - x\ \/ ^ ^ \ \ * ^^'"*>.^ \ ^^^ -8-«.r-« X'7^1 1 I I T 1 1 1 I" 1 1 23456 RUNOFF PERIOD 8 10 Figure 7. Relationships between rainfall, runoff, and sediment during the 1971-1972 season. 30 ------- Table 12. LOSS OF TOTAL NITROGEN THROUGH SURFACE RUNOFF FROM CORN AND MILLET PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1971-1972 Runoff date Apr. 6 July 16 Aug. 6 Dec. 3 Dec. 11 Dec. 27 Jan. 3 Jan. 18 Feb. 1 Mar. 17 Means SCU 963 471 394 233 152 125 107 239 234 180 310 Grand Means Corn AN 883 536 646 416 441 260 142 171 312 325 413 329 Millet SCU 1045 653 660 335 138 132 80 276 299 284 390 304 AN 542 475 264 170 143 128 89 242 273 262 259 LSD at 0.05 for comparing means: Crops Fertilizers 52 Runoffs 94 Crop x fertilizer x runoff interaction 208 NS Non-significant ** Significant at the 1% level of probability Check 418 405 461 359 158 165 142 153 166 204 263 F ratio NS 7.2** 34.9** NS Means 770-2 508.0 485.0 302.6 206.4 162.0 112.0 216.2 256.8 251.0 31 ------- Table 13. LOSS OF NITRATE-NITROGEN THROUGH SURFACE RUNOFF FROM CORN AND MILLET PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1971-1972 Runoff date Apr. 6 July 16 Aug. 6 Dec. 3 Dec. 11 Dec. 27 Jan. 3 Jan. 18 Feb. 1 Mar. 17 Means Corn SCU 36.0 6.4 15.7 37.5 6.6 5.5 1.7 3.0 2.3 8.3 12.3 AN 43.0 5.2 5.9 6.9 4.5 9.6 2.6 2.1 1.9 5.2 8.7 Grand means 7.8 LSD at 0.05 for comparing means Crops Fertilizers Runoffs Crox x fertilizer x runoff Millet SCU 47.5 18.3 19.9 46.6 17.3 13.8 7.7 13.7 2.0 14.7 20.1 10. interaction AN 19.8 3.6 3.9 24.5 10.3 6.1 2.0 2.0 1.5 4.5 7.8 1 3.2 5.9 14.1 Check 2.6 1.4 2.6 2.7 2.0 2.7 1.8 1.8 1.3 5.5 2.4 F ratio NS 40.2** 14.7** NS Means 29.78 6.98 9.60 23.64 8.14 7.54 3.16 4.52 1.80 7.64 NS Non-significant ** Significant at the 1% level of probability 32 ------- Table 14. LOSS OF AMMONIUM-NITROGEN THROUGH SURFACE RUNOFF FROM CORN AND MILLET PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1971-1972 Runoff date Apr. 6 July 16 Aug. 6 Dec. 3 Dec. 11 Dec. 27 Jan. 3 Jan. 18 Feb.l Mar. 17 Means Corn SCU 184 98 108 39 21 28 30 22 22 28 58 AN 224 96 95 90 55 84 57 25 35 27 79 Grand means 55 Millet SCU 233 110 122 65 25 42 27 27 30 31 71 50 LSD at 0.05 for comparing means: Crops Fertilizers Crops x fertilizer interaction Crop x fertilizer x runoff interaction AN 61 52 53 73 30 56 40 17 22 27 43 14.9 21.0 31.0 Check 31 24 28 25 11 48 40 22 28 35 29 F ratio NS 15.0** 6.3* 4.4* Means 146.6 76.0 81.2 58.4 28.4 51.6 38.8 22.6 27.4 29.6 NS Non-significant ** Significant at the 1% level of probability 33 ------- CO I LU LU "J LU l_^ LU oe 100 90 80 70 60 50 40 30 20 10 n * -TOTAL N (g/ha) X 0.1 tv _ *N03-N (mg/1) X 0.01 /\ »N03-N (g/ha) X 0.1 / \ iNH4-N (g/ha) X 2 | \ I I I \ ! \ ! \ * i \ / ' \ / N / * / V t^ 1 * \ X Xx / \ / * \ ^ ^, / \ / / A .1 1 * ! >t \ / 1 / / X^v ^ / V / >w \ / \^ / y... ' \ \ 1 0 * \ ^»* *»,! \ ,* *% ; \ X* \*^** ****«. '**** \* """^ * * "^« - ^^^C.'* * t*^ + t--t t f f---i^-^--x> 456 RUNOFF PERIOD 8 10 Figure 8. Nitrogen losses from plots through surface runoff during the 1971-1972 season. 34 ------- Table 15. LOSS OF PHOSPHORUS THROUGH SURFACE RUNOFF FROM CORN AND MILLET PLOTS TREATED WITH SULFUR-COATED UREA AND AMMONIUM NITRATE (g/ha) 1971-1972 Runoff date Apr. 6 July 16 Aug. 6 Dec. 3 Dec. 11 Dec. 27 Jan. 3 Jan. 18 Feb. 1 Mar. 17 Means scu 53.5 46.8 52.2 18.1 15.1 12.2 18.3 41.3 36.3 37.3 33.1 Grand means Corn AN 120.7 98.1 109.7 12.7 15.5 26.9 17.0 27.4 43.6 46.9 51.9 40.0 Millet SCU 98.3 66.8 44.2 11.5 14.3 63.8 14.0 47.7 49.7 59.0 46.9 LSD at 0.05 for comparing means: Crops Fertilizers TJiinnff « AN 68.3 62.5 41.1 15.9 12.0 17.9 15.4 47.1 33.5 45.8 36.0 43.9 9.7 17.8 Check 2.1 7.2 9.5 7.2 3.9 7.5 11.6 5.7 9.2 9.8 7.4 F ratio NS 37.5** 7.1** Means 68.58 56.28 51.34 13.08 12.16 25.66 15.26 33.84 34.46 39.76 NS Non-significant ** Significant at the 1% level of probability 35 ------- The P levels in runoff were highest in the first three runoff periods and lover during the fourth, fifth, sixth, and seventh periods (Fig. 9). The P losses in runoff in 1971-1972 were not as closely related to sediment loss as in the 1969-1971 period. Discussion The application of 100 kg/ha N as SCU and AN increased N losses from plots cropped with corn and millet during April to December 1971, especially where SCU was applied. Data from samples taken April 6th reflect high values for nutrient loss since the plots had been rototilled and fertilized on April 3rd Just prior to a runoff producing rain. In the first four runoff producing periods, the lighter weight and larger pelleted SCU may have washed with the runoff resulting in an inflated value of total N loss from such plots when compared with AN. The results obtained in this study suggest that for annual corps, SCU is not superior to AN in controlling N and P losses through surface runoff. Cropping practices employed for growing millet and corn appar- ently had no effect on N and P losses. 36 ------- CO LU LU a. LU > LU ce 100 on j\j 80 70 60 50 40 30 20 10 _ - "SOLUBLE P (mg/1) X102 ARUNOFF P (g/ha) ?m T MCMT D ^ L- n / 1\ -% \ g/ ; - - T ^ / - / *» . / / * r m * . ^r ^*J ff_ * * T*« ^^ * .-^A *AV.-C«-^*A , * A ****... . f i i T ' v -r T ?- i i 123456 7 89 10 RUNOFF PERIOD Figure 9. Phosphorus losses from plots through surface runoff during 1971-1972 season. 37 ------- SECTION VI REFERENCES 1. Moe, P. G., J. V. Mannering, and C. B. Johnson. Loss of Fertili- zer in Surface Runoff Water. Soil Science. 104(6):205:211, 1967. 2. Moe, P. G., J. V. Mannering, and C. B. Johnson. A Comparison of Nitrogen Losses from Urea and Ammonium Nitrate in Surface Runoff Water. Soil Science. 105(6):168-174, 1968. 3. Timmons, D. R., R. E. Burnell, and R. F. Bolt. Loss of Crop Nutrients through Runoff. Minn. Plant Sci. 24:16-18. 4. Viets, F. G., Jr. Fertilizer Use in Relation to Surface and Ground Water Pollution. In: Fertilizer Technology and Use, Olsen, R. A., et. al. (ed.) Madison, Wis. Amer. Soc. Agron. 1971. 5. Barrows, H. L., and V. J. Kilmer. Plant Nutrient Losses from Soils by Water Erosion. Advances in Agronomy. 15:303-316. Academic Press, Inc., New York. 1963. 6. Wadleigh, C. H. Agriculture and the Quality of Our Environment. U.S. Dept. Agri. Misc. Publ. 1065. 1968. 7. Biggar, J. W. and R. B. Corey. Nitrate and Phosphate in Lakes and Streams. Unpublished Mimeo. Madison, Wis. Univ. of Wisconsin. 8. Martin, J. B., Jr., B. N. Bradford, and H. G. Kennedy. Factors Affecting the Growth of Najas in Pickwick Reservoir. TVA Rpt. No. F70-74C02. 1969. 9. Edmondson, W. T. Fresh Water Pollution. In: Environment Re- sources, Pollution and Society, Murdock, W. W. (ed.) 1972. p 213-229. 10. Martin, W, P., W. E. Fenster, and L. D. Hanson. Fertilizer Manage- ment for Pollution Control. Iowa State Univ. (Symposium: Role of Agriculture in Clean Water. Ames. November 18-20, 1969.) 11. FWPCA Methods for Chemical Analysis of Water and Wastes. U.S. Dept. of the Interior, Division of Water Quality Research. Cincinnati, Ohio. 1969. 38 ------- 12. Jackson, M. L. Soil Chemical Analysis. Prentice Hall, Inc. 1958, 13. Black, C. A., D. D. Evans, L. E. Ensminger, J. L. White, F. E. Clark, and R. C. Dinauer. Methods of Soil Analysis. Amer. Soc. Agron., Amer. Soc. for Testing and Materials. 1965. 14. Duley, F. L. The Loss of Soluble Salts in Runoff Water. Soil Science. 21:401-409. 1926. 39 ------- SECTION VII GLOSSARY AN ATinnoTiiuTn-nitrate N Nitrogen NH/-N Ammonium-nitrogen NOj-N Nitrate-nitrogen P Phosphorus SCU Sulfur-coated urea (slow-release nitrogen fertilizer) Total Nitrogen Organic nitrogen plus ammonium nitrogen Average monthly losses Sum of concentrations, volumes, or quantities, measured for each runoff producing rain during a given month divided by the total number of runoff producing rains for the month. Check Plots Those plots which were uncropped and unfertilized. Infiltration Movement of water from the surface into the soil. Non-treated Plots Plots to which no fertilizers were applied. Percolation - Movement of water through the soil. Surface Runoff The water fraction of surface runoff after sediment has been removed from water. 40 4US. GOVERNMENT PRINTING OFFICE: 1974 546-J18/382 1-3 ------- SELECTED WATER RESOURCES ABSTRACTS INPUT TRANSACTION FORM . 1. Report No. 3, Accession No. w 4. Title NITROGEN AND PHOSPHORUS LOSSES FROM AGRONOMY PLOTS IN NORTH ALABAMA Authorfs) Robert R. Bradford 3/15/74 8. f. * Tforath^ Organization Report No. 9, Organization Alabama A. & M. University Normal, Alabama 35762 10. Project No. 13020DWH 11. Contract/Grant No. 800401 n. s; " *foa ProtectloB. 1.3 Type.. £ Repo * * #af - Period Coveted 1969-1972 IS. Supplementary Notes Environmental Protection Agency report number, EPA-660/2-74-033, April 1974. 16. Abstract . .':.."., A study of nitrogen and phosphorus losses from Decatur silt loam soil was conducted over three cropping periods from 1969-1972. Experimental agronomy plots at Alabama A. & M. University were seeded to cotton, corn, soybeans, and millet and compared with uncropped and unfertilized check plots. . The effects of these crops on nitrogen losses total nitrogen, nitrate-nitrogen, and ammonium^nitrogen (for 1971-1972 only) and phosphorus losses were evaluated. Average total rainfall and losses of sediment and runoff were also determined. Losses of total nitrogen and nitrate-nitrogen were generally positively correlated with the amounts of rainfall, runoff, and sediment. Phosphorus losses were positively corre- lated with sediment losses. More than 95% of phosphorus losses were associated with sediment loss. The effect of crops on loss of all nutrients was considerably smaller than seasonal effects and sediment losses. The effect of two fertilizers, ammonium nitrate and sulfur-coated urea,upon nutrient losses showed no evidence of superiority for sulfur-coated urea in reducing the total nitrogen or nitrate-nitrogen losses. I7a. Descriptors Rater qualtly, Water pollution agricultural sources, Nitrogen - Phosphorus losses. Cropping effects, Seasonal effects, Fertilizer effects, Sediment losses, Cultural practices. 17b. Identifiers Nutrient loss reduction, North Alabama Decatur silt loam, Seasonal-Cropplng-Fertilizer Effects, Water quality Sediment loss Interaction. 17c. COWRR Field & Group 18. Availability Abstractor Robert R. ! 19. Securitv C/gis. ;"'.. (Repoi.) 'JO. Se> 'rity Cf, ss. (Page) M. No. of Pages :2. Privet ' Send To: WATER RESOURCES SCIENTIFIC INFORMATION CENTER US DEPARTMENT OF THE INTERIOR WASHINGTON. D. C. 2O24O JJra/Jfjpr4 1 institution Alabama A. & M. University VV R S! C i O a ------- |