DRAFT
       REVISED DRAFT FINAL REPORT
       THEORETICAL EVALUATION OF
SITES LOCATED IN THE ZONE OF SATURATION
        Contract No.  68-01-6438
             Task No. 012
            Prepared  for:

           Mr. James  Bland
        Project-Officer  (5 AHWM)
  U.S.  Environmental  Protection Agency
               Region V
        Chicago, Illinois  60604
             Prepared  by:

             Versar  Inc.
          6850 Versar  Center
            P.O.  Box 1549
     Springfield, Virginia  22151

                 and

            JRB Associates
         8400 Westpark Drive
       McLean, Virginia  22102
            Date Prepared:

            April  6,  1983

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                            TABLE OF CONTENTS


1.0  INTRODUCTION 	      1

2.0  DRAIN THEORY 	      4

     2.1  Drain Spacing and Head Levels	      4

          2.1.1   Drains On Impervious Barriers 	      5
          2.1.2   Drains Above Impervious Barriers	      7
          2.1.3   Drains On Sloping Impervious Barriers 	     11

     2.2  Drain Pipe Sizing	     13

          2.2.1   Hydraulic Gradient (i) and Roughness Coefficient   14
          2.2.2   Discharge (Q)	     17
          2.2.3   Pipe Size	     21

     2.3  Filters and Envelopes	     23

          2.3.1   Function of Filters and Envelopes	     23
          2.3.2   Design of Sand and Gravel Filters	     24
          2.3.3   Design of Sand and Gravel Envelopes	     26
          2.3.4   Synthetic Filters 	     26

3.0  DESIGN AND CONSTRUCTION	     28

     3.1  Hypothetical Site	     28
     3.2  Sensitivity Analysis  	     31

          3.2.1   Drains On Impermeable Barriers	     31
          3.2.2   Drains On Sloping Impervious Barriers 	     34
          3.2.3   Drains Above An Impervious Barrier   	     40

     3.3  Application	     40

          3.3.1   Parameter Estimation   	     43
          3.3.2   Landfill Size	     44
          3.3.3   Example Problem	     44

     3.4  Application	     47

          3.4.1   Construction Inspection  	     47
          3.4.2   Drain System Maintenance	     48
          3.4.3   Future Operating  Conditions  	     49
                                     11

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                            TABLE OF CONTENTS
                               (Continued)
4.0  FLOW NET ANALYSIS	    50

     4.1  Introduction	    50
     4.2  Initial Conditions  	    52
     4.3  Parameter Analysis	    55

5.0  MODELS	    60

     5.1  Release Rate Models	    60

          5.1.1   Fundamentals	    60

                  5.1.1.1  Leachate Generation   	    60
                  5.1.1.2  Leachate Constituent  Concentrations.  .    66
                  5.1.1.3  Leachate Release  	    66

          5.1.2   Selected Release Rate Models   	    69

     5.2  Solute Transport Models  	    77

          5.2.1   Fundamentals	    77

                  5.2.1.1  Analytical Models  	    80
                  5.2.1.2  Numerical  Models  	    81

          5.2.2   Selected  Solute  Transport  Models  	    82

                   5.2.2.1   Analytical Models  	    86
                   5.2.2.2   Numerical  Models  	    90

      5.3  Model  Limitations	    94

 6.0  RECOMMENDATIONS	    95

 7.0  BIBLIOGRAPHY	     97
                                    iii

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                          LIST OF TABLES


2-1  Values for the Equivalent Depth d of Hooghoudt 	     10

2-2  Minimum Hydraulic Gradients for Closed Pipes  	      15

2-3  Drain Grades for Selected Critical Velocities 	      16

3-1  Range of Site Variables	      30

3-2  Drain Length Spacing (m)  for Drains on an Impermeable
     Barrier	      32

3-3  Values of h/L for Various C=q/k^ and Angles a	      36

3-4  Drain Spacing (m) for Head Maintenance Levels of 2 Meters   38

3-5  Drain Spacing (m) for Drains Above an Impermeable Barrier   41

3-6  Example Data Set	      45

5-1  Major Factors Affecting Leachate Generation 	      62

5-2  Factors Affecting Leachate Constituent Concentrations .      67

5-3  Factors Affecting Leachate Release  	      68

5-4  Release Rate Models	      70

5-5  Solute Transport Models 	      83
                                IV

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                         LIST OF FIGURES


1-1  Typical Stratigraphic Column of Zone of Saturation
     Sites in Wisconsin	       2

2-1  Drains Resting on an Impervious Barrier 	       6

2-2  Flow to Drains Above an Impervious Barrier	       8

2-3  Drains on Sloping Impermeable Barrier  	      12

2-4  Flow Components to  a Landfill	      18

2-5  Division of  a Symmetrical Drawdown Drain Problem Into
     Two Equivalent Fragments	      20

2-6  Capacity Chart  n = 0.013	      22

3-1  Hypothetical Zone of Saturation Landfill	     29

3-2  Drain  Length versus Flow Rates  for Head Levels  Equal to
     1  Meter	     33

3-3  Plot  of  h/L versus  h/I = tan o for Drain  and  Sloping
     Impervious  Layers  	     37

3-A  Drain Length (L)  versus c  - q/k^	      39

 3-5  Drain Spacing  (L)  versus Inflow rates (q)  	      42

 4-1  Cross Section  of Typical Zone of Saturation Landfill   .      51

 4-2   Inflow With Typical Landfill Cell	      54

 4-3   Flow Nets With Different Leachate Levels	      56

 4-4   Flow Nets With Different Vertical Gradients	      57

 4-5   Flow Nets With Different Numbers of Drains	      58

 5-1  Major Components of Groundwater Transport Equations . .      79

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                             ACKNOWLEDGMENTS
    This report was prepared by Dr. Edward Repa, Ms. Kathi Wagner, and
Mr. Rodger Wetzel of JRB Associates, and Mr. Michael Christopher of
Versar Inc., under the direction of Dr. G. Thomas Farmer, Task Manager.
This report was prepared for the Wisconsin Department of Natural
Resources under the U.S. EPA's Technical Assistance Project sponsored by
U.S. EPA, Region V.
                                    VI

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                            1.0  INTRODUCTION

    The State of Wisconsin and much of EPA Region V are located in a
portion of the United States characterized by thick surficial deposits of
saturated glacial till underlain by fractured sedimentary or crystalline
rock.  A typical stratigraphic column for Wisconsin is shown in Figure
1-1.  Landfill site design in this part of the country is complicated by
the hydrology of the zone of saturation.  At these sites, the glacial
clay deposits into which the landfills are built act as limited
unconfined aquifers.  Hydraulic conductivities of the clays range from
 10~  cm/sec, where the clays are fractured, to 10   cm/sec, where
the clays are unfractured (Newport, 1962).  Underlying the clays are
thick units of dolomite and sandstone which act as confined aquifers.
Confining pressures in these units can bring groundwater to the land
surface in drilled wells.  Recharge of these underlying units occurs at
or near outcrops.
    Siting landfills in this region, especially those which will accept
hazardous wastes, is a problem because the base grade of the facility is
typically below the water table (i.e., in the zone of saturation).  As a
result of having the base grade below the groundwater table, the
potential for accelerated leachate generation and contaminate release is
greatly enhanced.  To alleviate this problem, landfill operators are
required to manage groundwater and leachate  in  the landfills so that
inward hydraulic gradients  are constantly maintained, thereby limiting
the possibility of contaminant escape.  The method utilized  to maintain
inward hydraulic gradients  is  a drainage collection  system  installed on
the base of the landfill.   The drainage system  allows for the maintenance
of landfill head levels which  are lower than the natural groundwater
table  (i.e.,  inward hydraulic  gradients).
                                    -1-

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         Geologic
            Log
          \ \  \  \. \  \
             \ v \ \
          -\ \ \
            \ \ \ \ \
           \ \ \ \ V
           \  \  \ \ V
           \\x\\\
           \ \ \  \ \

                -'- V
Rock Unit
                       Glacial deposits
                         Red Clav
Galena Dolomite and
  Platteville Formation
St. Peter Sandstone



Trempealeau Formatior

Franconia Sandstone


Galesville Sandstone
       Aauifer
                             Limited Unconfined
                                 Aquifer
Confined Aquifer,
solution cavities
                                                    Confined Aquifer
   Vertical Scale 1"=200'
Figure 1-1.  Typical Stratigraphic Column of Zone of Saturation
             Sites in Wisconsin (City of Fond du Lac) (Newport, 1962)
                               -2-

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    The purpose of this study was to perform a theoretical evaluation of
the validity of the presently used landfill management schemes for
groundwater and leachate at sites located in the zone of saturation.
This evaluation included flow net and parameter sensitivity analyses.
The key parameters that were evaluated include:
    o  Drain spacing.
    o  Hydraulic conductivities of the landfill and natural soils
       surrounding the site.
    o  Inflow rates resulting from groundwater infringement and leachate
       generation.
    o  Head maintenance levels within the landfill.
    o  Pipe sizing.
    o  Drainage blanket use.
Other parameters addressed  include landfill dimensions, construction
inspections, and future operating conditions.  Drainage theory and
selected models for predicting release rates and solute transport are
also described.
    The results of this study should assist permit writers  in determining
engineering design modifications and site monitoring  requirements,  as
well as aid in establishing a basis for  future design protocols for zone
of saturation landfills.
                                   -3-

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                            2.0  DRAIN THEORY

    There are three major elements to consider  in the design of a
subsurface drainage system suitable for zone of saturation landfills:
    o  The drain  spacing required to achieve the desired head maintenance
       levels.
    o  The hydraulic design of the conduit, including the pipe diameter
       and gradient.
    o  The properties of the drain filter and envelope.
    This section  briefly describes the principles involved in determining
a desirable drain slope and spacing, and in selecting appropriate drain
materials.
2.1  Drain Spacing and Head Levels
    There are numerous analytical solutions and models that have been
developed for estimating the drain spacing required to maintain head
levels at a predetermined height in saturated media.  This section
presents the analytical solutions for determining drain spacing based on
maintenance head  levels, permeabilities, and flow rates for:
    o  Drains resting on an impermeable barrier
    o  Drains installed above an impermeable barrier
    o  Drains resting on an impermeable barrier that slopes symmetrically
       at an angle to the drains.
    The equations presented here assume that steady state conditions
exist, that recharge distribution and leachate generation over the area
between the drains is uniform, and that the soil is homogeneous.  Most
real world situations do not fully meet these criteria; therefore, the
results obtained  should be considered approximate.  In using the
equations for designing a landfill drain system, a conservative approach
                                    -4-

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should be taken to ensure that head maintenance levels are at or below
the desired height.
2.1.1  Drains on Impervious Barriers
    Groundwater flow to drains resting on a horizontal (flat) impervious
barrier can be represented (Van Schlifgaarde, 1974; Wesseling, 1973) by
the equation:

    L = [(8KDh + 4Kh2)/ql°'5
where:
    L = drain spacing  (m)
    K = hydraulic  conductivity of the drained material (m/day)
    D = distance between the water level  in the drain line and the
        impermeable barrier (m)
    h = water table height above the drain levels  at the midpoint between
        two drains (m)
    q = leachate generation rate (m/day)  [equal to total  inflow
          3                                 2
        (m /day) divided by landfill area (m )J
Figure 2-1 illustrates the relationship between these terms.  When  two
parallel drain lines are installed properly, each  line causes the
establishment of a drawdown curve that, in theory, will intersect midway
between the two drain  lines.  In solutions to gravity flow problems, the
distance from the  drain to a point where  the drawdown can be  considered
insignificant (Ah  = 0) is equal to half of the drain spacing  (L/2).
This distance, L,  is commonly referred to as the "zone of influence" of
the drain.
    For a pipe drain resting on an  impermeable barrier, the  parameter D
approximately equals the radius of  the pipe and hence can be  very small
in comparison to h (the water table height above the drain).  Then, since
the term 8KDh becomes  very small (=0), equation 1  can be  simplified to:
             2     05
    L =  KAKh )/q]
Equation 2 represents  horizontal flow to  the drains above the drain level.
                                     -5-

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Figure 2-1: Drains Resting On An Impervious Barrier
                            -6-

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    Drain spacing (L) and hydraulic head level (h) in the equations are
interdependent design variables which are a function of the leachate
generation rate (q) and hydraulic conductivity (K) of the drained
material.  Assuming a constant leachate generation rate and hydraulic
conductivity, the closer two drains are spaced the more their drawdown
curves will overlap and the lower the hydraulic head levels between the
drains will be.  Therefore, in order to space the drains at the required
distance to achieve the desired head maintenance levels, the hydraulic
conductivity of the landfill material and the quantity of leachate
generated must be determined to a reasonable degree of accuracy.
2.1.2  Drains Above Impervious Barriers
    Equations 1 and 2 are suitable for estimating drain spacing and head
levels if the drains are located on an impervious barrier, as is the case
with most landfill operations.  In using drainage system design
equations, a layer is generally considered  impervious if it has a
permeability at least 10 times less than the overlaying layer (i.e.,
K      /K       >10) .  The clay base of a landfill may not act as  an
  above   below
impermeable layer in the design equations if:
    o  Clays are not adequately compacted to produce  the desired
       permeability
    o  Clays are fractured (naturally or during placement)
    o  Clays are not uniform (e.g., contain sandy zones)
    o  Landfill material has a permeability comparable to the clay liner.
    Where drains are not installed on impermeable barriers, flow to  the
drains is radial (as illustrated in Figure  2-2).  In  this case the drains
are considered to be installed at the interface of  a  two-layered soil
with hydraulic conductivities of K  and K   (as shown  in Figure 2-2).
Substituting the hydraulic conductivity of  the material below the  drain
(K ) into the first  term of the right hand  side of  equation 1
  2
compensates for radial flow to the drain system,  and  gives:
                      2    0.5
L
                             .
      =  t(8X2Dh =  AiLjh  )/q]                                          <3>
                                     -7-

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     m
Figure 2-2  Radial Flow to Drains Above An Im-
                pervious  Barrier
                          -8-

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However, the drain spacing calculated by equation 3 does not take into
account the fact that flow velocity in the vicinity of the drain is
higher than elsewhere in the flow region.  If the flow velocity was
uniform, the reduction in hydraulic head caused by the drain would be
distributed evenly around the drain.  But, because of the non-uniform
velocity, a proportionally higher loss of head occurs close to the drain,
and the actual water table elevation (h) will stand higher than expected
with drains spaced according to equation 3.
    To account for the increase in h caused by radial flow, Hooghoudt
(1940) introduced a reduction of the parameter D to a smaller equivalent
depth, d.  The equation that was developed to take into account radial
flow can be rewritten as:
                      2    05
    L = [(8K2dh + A^h )/q]                                          (4)
where the new term d is the equivalent depth (m)
    Equation 4 shows the drain spacing L is dependent on the equivalent
depth d.  But the value of d is calculated from a specified value for L,
so equation 4 cannot be solved explicitly in terms of L.  The use of this
equation as a drain spacing formula involves either a trial and error
procedure of selecting d and L until both sides of the equation are  equal
or the use of nomographs which have been developed specifically for
equivalent depth and drain spacing.  Table 2-1 gives values of the
equivalent depth (d) as a function of drain spacing (L) and saturated
thickness below the drains (D).  This tables show values of d for a  drain
pipe with a radius (r ) of 0.1 meter.  Similar tables have been
prepared for other values of r  .  For saturated thicknesses (D) greater
than 10 meters, the equivalent depth can be calculated from drain spacing
using the following equation:
    d = 0.057 (L) + 0.845                                            (5)
This equation was developed by linear regression from the values given  in
Table 2-1.
                                     -9-

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                 7.5
                     10
                         15
                             20
                                      30
                                                      50
O
D
0 * ii 0 4 7 048 049 049 049 0 50 050
0.75 0.60 0.65 0.69 0.71 0.73 0.74 0.75 0.75 0.75 0.76 0.76
1.00 0.67 0.75 0.80 0.86 0.89 0.91 0.93 0.94 0.96 0.96 0.96
1.25 0.70 0.82 0.89 1.00 1.05
1.50
1.75
2.00
2.25
1.50
.1.75
3.00
3.25
3.50
3.75
4.00
4.50
5.00
5.50
6.00
7.00
6.00
i.OO
10.00
0.88 0.97 1.11 1.19
0.91 1.02 1.20 1.30

















1.08 1.28 1.41
1.13 1.34 1.50















1.38 1.57
1.42 1.63
1.45 1.67
1.48 1.71
1.50 1.75
1.52 1.78









1.81
1.09 1.12 1.13 1.14 1.14 1.15
1.25 1.28 1.31 1.34 1.35 1.36
.39 1.45 1.49 1.52 1.55 1.57
1.5 1.57 1.62 1.66 1.70 1.72
.69 1.69 1.76 1.B1 1.84 1.86
1.69 1.79 1.87 1.94 1.99 2.02
1.76 1.88 1.98 2.05 2.12 2.18
1.83 1.97 2.08 2.16 2.23 2.29
1.88 2.04 2.16 2.26 2.35 2.42
1.93 2.11 2.24 2.35 2.45 2.54
1.97 2.17 2.31 2.44 2.54 2.64
2.02 2.22 2.37 2.51 2.62 2.71
1.85 2.08 2.31 2.50 2.63 2.76 2.87
1.88 2.15 2.38 2.58 2.75 2.89 3.02






0.71 0.93 1.14 1.53 1.89
2.20 2.43 2.65 2.84 3.00 3.15
2.48 2.70 2.92 3.09 3.26
2.54 2.81 3.03 3.24 3.43
2.57 2.85 3.13 3.35 3.56
2.89 3.18 3.43 3.66
1 3.23 3.48 3.74
2.24 2.58 2.91 3.24 3.56 3.88
L — > 50 75
D
0.5 0. 50
1 0.96 0.
2 1.72 1.

3 2.29 2.

4 2.71 3.

5 3.02 3.

6 3.23 3.

7 3.43 4.

8 3.56 4.

9 3.66 4.

10 3.74 4.
12.5
15

17.5
20
25
30
35

40
45

50
60
80


97 0.
80 1.

49 2.

85 90


97 0.
82 1.

52 2.

04 3.08 3.

49 3.


55 3.

85 3.93 4.

14 4.


23 4.

38 4.49 4.

57 4.


70 4.

74 4.89 5.
5.02 5.20 5.
5.

5.










- 3.88 5.

20 5.40 5.


30 5.53 5.
5.62 5.
5.74 5.


















100 150 200 250 H
to
cr


97 0.98 0.
82 1.83 1.


54 2.56 2.

12 3.


16 3.

61 3.67 3.


00 4.08 4.


33 4.42 4.


61 4.72 4.


82 4.95 5.




98 0.
0 I-1
P O
	 O fS)
C 1
99 0.99 0.99 H1 H
85 1.00 1.92 1.94 3 rf

60 2.

&• (D
72 2.70 2.83 a <
W u
24 3.46 3.58 3.66 jtT ft> M

78 4.

rf O e
12 4.31 4.43 C n (0
n u
23 4.70 4.97 5.15 p O

i-f >-i« l-h
62 5.22 5.57 5.81 O r-t> 6'

a. i-t» M
95 5.68 6.13 6.43 ~~ fl>' "

t-t M rrl
23 6.09 6.63 7.00 gr (0 (H"

M* !"1 C^
04 5.18 5.47 6.45 7.09 7.53 O rr H-
38 5.56 5.
60 5.80 6.


92 7.20 8.06 8.68 J3* 

M *- ••!
76 5.99 6.44 8.20 9.47 10.4 ™ JJ £
87 6.12 6.60 8.54 9.97 11. 1 
11.813.8 2- 5' x^
12.0 13.8 3 „ JJ
in CO O
12.1 14.3 ^*g ^
1 14.6 O 0 n
1 -^ t—O
38 5.76 6.00 6.26 6.82 9.55 12.2 14.7 O





09 II
          Source:  Wessellng, 1973.

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2.1.3  Drains on Sloping Impervious Barriers
    Typically, landfill cells are designed so that the compacted base of
the cell slopes symmetrically at an angle towards the drains.  A
cross-section of such a design is shown  in Figure 2-3.  By designing the
drain system on sloping barriers, the flow of water towards the
collection system is accelerated, thus decreasing the steady-state head
maintenance levels.  This allows the drains to be spaced further apart or
the heads to be lowered if the other parameters in the equation are held
constant.
    Drain spacing can be calculated for  landfills designed with an
impervious layer sloping towards the drains at an angle by the following
equation (Moore, 1980):

    L = (2h    /c°'5)/[tan2a/c) +1 - (tan a/c) (tan*a + c)°' ]         (6)
            max
where:
    c = q/R (dimensionless)
    a = slope angle (degrees)
    hmax = maximum allowable head level  above impervious layer (m)
Note that because the "peak" formed by the two slopes between the drains
intrudes on the saturated mound between  the drains, h    is not found
                                                     max
directly above this peak (midway between the drains) but at some distance
to either side of this point.
    For example, consider a landfill to  be constructed in glacial till
with bottom drains constructed of a material with a hydraulic
                          -4               -6
conductivity (K) of 2 x 10   cm/sec (2 x 10   m/sec).  The fill will
have slopes toward the drains of 2% (1.1°), has an estimated leachate
                                              -4
generation rate of 6 inches per year (4.2 x 10   m/day) based on water
calculations, and must maintain the leachate level at a maximum elevation
of 2 m above the drains.  The drain spacing is calculated using
equation 6:
                                     -11-

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                Infiltration  (q)
Figure 2-3' Drains  on Sloping  Impervious Barriers
                           -12-

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    L = (2h    /c°'5)/[tan2a/c) +1 -  (tan ot/c) (tan2a + c)°'5]         (6)
            max
         where C = q/K = - *.2 * 10        - = 2.43 x
                         2 x 10   m/sec x 86,400 sec/day

    T       (2 x 2 m)      /TO. 69 x 10~4)   ,   (1.92 x 10~2
    L _ -       / - — + 1 - - -
        (2.43 x 10  )    I [(2.43 x 10  )       (2.43 x 10  )

      + (3.69 x 10~4 + 2.43 x 10~3)°'5
            A «tt                  T                          O
      = - 2-S — — /[(1. 52 x 10  ) + 1 - (7.90) (5.29 x 10~ )]
        4.93 x 10
                        -1
      =81.1 m/7.34 x 10

      = 110.6 m
    These drainage system design equations assume that the drain pipe
will accept the drainage water when it arrives at the drainline and that
the drain pipe will carry away the water without a buildup in pressure.
To meet the second assumption, the pipe size and drain slope must be
adequate to carry away the water after it enters the drain pipe.  The
following sections describe the methods utilized to ensure that these
assumptions are valid.
2.2  Drain Pipe Sizing
    The design diameter of a drain pipe is dependent on the flow rate,
the hydraulic gradient, and the roughness coefficient of the pipe.  The
roughness coefficient, in turn, is a function of the hydraulic resistance
of the drain pipe.  The formula for the hydraulic design of a drain pipe
is based on the Manning formula for pipes which is:

    QT = (i°-5> A/n                                          (7)
                                    -13-

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where:
    QT = design discharge (nr/sec)
    R  = hydraulic radius of the pipe (m) , which is equal to the wetted
         cross-sectional area divided by the wetted perimeter, or is
         equal to 1/4 of the diameter of a full flowing pipe
    i  = hydraulic gradient (dimensionless)
    A  = cross-sectional area of flow (m?)
    n  = roughness coefficient  (dimensionless).
Each of the above factors is described  in further detail in the following
sections.
2.2.1  Hydraulic Gradient (i) and Roughness Coefficient  (n)
    Subsurface drains are generally  installed  on a gradient (i) that is
sufficient to result  in  a water velocity within the pipe that will
prevent silting, but  is  less than the velocity which will cause turbulent
flow.  Past experience has  shown  that non-silting velocities  occur  above
1.4 feet per second  (Soil Conservation  Service, 1973).   In  situations
where silting may be  a problem  and velocities  are less  than 1.4 ft/sec,
filters and traps can be utilized to prevent the drains  from  clogging.
The minimum hydraulic gradients required  to prevent siltation in  three
sizes of closed  pipe  are listed in Table  2-2.  However,  steeper gradients
are generally desirable  provided  they are  less than the  gradients which
would result in  turbulent flow.
    To prevent turbulent flow,  the hydraulic gradients  should result  in
velocities that  are  less than critical  velocities.  Table 2-3 gives
critical velocities  for  various drain sizes, gradients,  and roughness
coefficients.  For  smooth perforated concrete  or plastic pipes, roughness
coefficients can be  assumed to  be equal to 0.013  (Soil  Conservation
Service, 1973).  Knowing the velocity which results  in  siltation  and  that
which results  in turbulent  flow,  the design engineer  can select  a
gradient which results  in  a velocity somewhere between  the  two extremes.
                                     -14-

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TABLE 2-2.  MINIMUM HYDRAULIC GRADIENTS  FOR CLOSED PIPES
        Pipe Diameter                    Grade
        Inches       Cm                     %

          4         10.2                   0.10

          5         12.7                   0.07

          6         15.2                   0.05
          Source:   Soil Conservation Service, 1973
                             -15-

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          TABLE 2-3.  DRAIN GRADES FOR  SELECTED  CRITICAL VELOCITIES
Drain Size

laches
,. , VELOCITY

1.4 ips^1' 3.5 fps 5.0 fps 6.0 fps 7.0 fps 9.0 fps
                           Grade - feet per 100  feet
                        For drains with
Clay Tile, Concrete Tile,
4
5
6
8
10
12

Clay Tile,
4
5
6
3
10
12

.28
.21
.17
.11
.08
.07

1.8
1.3
1.0
0.7
0.5
0.4
For drains
Concrete Tile, and
.41
.31
.24
.17
.12
.09

2.5
1.9
1.5
1.0
.8
.6
For drains
and Concrete Pipe (with good alignment)
3.6
2.7
2.1
1.4
1.1
0.8
with "n"
Concrete
5.2
3.9
3.1
2.1
1.6
1.2
with "n"
Corrugated Plastic
4
5
6
8
10
12
.53
.40
.32
.21
.16
.13
3.3
2.5
2.0
1.3
1.0
.8
6.3
5.1
4.0
2.7
2.0
1.6
5.1
3.9
3.1
2.1
1.5
1:2
- 0.013
Pipe (with
7.5
5.6
4.4
3.0
2.2
1.8
- 0.015
Pipe
9.8
7.3
5.8
3.9
2.9
2.3
7.0
5.3
4.1
2.8
2.1
1.6

11.5
8.7
6.9
4.6
3.5
2.7

fair alignment)
10.2
7.7
6.0
4.1
3.0
2.4


13.3
9.9
7.9
5.3
4.0
3.1
16.8
12.7
10.0
6.8
5.0
3.9


21.9
16.6
13.2
8.8
6.6
5.1
(1)—Feet per second
(2)—"n"  is the roughness coefficient

Source:  Soil Conservation Service, 1973.
                                       -16-

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2.2.2  Discharge (0)
    The design discharge of a pipe, Q  is equal to the sum of the
individual discharges which impinge upon the drain.  Figure 2-4 shows the
various flow components that could contribute to a drain discharge within
a landfill.  These flow components can be broken into two major
categories—flow from within the site and flow from the surrounding
aquifer.
    In most instances the flow rates are estimated for design purposes so
that the drain spacing can be determined using the previously presented
equations.  Estimates of discharge can be obtained using two simplified
methods—the water balance method and the method of fragments.  The water
balance method is used to calculate the amount of the percolation that
can recharge the water table between the lines of drains.  This flow must
be removed to maintain steady state conditions.  A simple water balance
equation is as follows:
    qp = P-RO-ST-ET
    where:
    qp = percolation rate:  amount of water that must be removed by
         drainage system (m/day)
    P  = precipitation  (m/day)
    RO = surface water  runoff (m/day)
    ST = change in  soil  (refuse) moisture storage  (m/day)
    ET = evapotranspiration rate  (m/day)
Once the percolation rate has been calculated, discharge can  be  obtained
by multiplying the  percolation  rate by  the drainage  area  (i.e.,  Q
  o                          *)
(m/day) = q   (m/day) Area  (m )).
    When using the  water balance method to calculate  flow  rates  or
discharges for landfills, the following points should be considered:
                                     -17-

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I
                                          Lateral flow
                                             in waste
   Lateral
 flow in
rounding materi
                     Figure  2-4s Flow  Components to a Zone of Saturation  Landfill

-------
    o  Precipitation values for those  time periods with high intensity
       rainfalls should be used to ensure percolation values are
       maximized and drainage design is adequate to handle these
       discharges.
    o  Soil (refuse) moisture storage  changes can be significant as new
       refuse is placed into the landfill; once field capacity of the
       materials is attained the SI term can be considered zero.
    o  Variations in cover depths and  the absence of vegetation can have
       significant effects on percolation rates; these effects will
       probably be greatest during the active operational phase when
       shallow covers  are presented and drainage is inadequate.
    The method of fragments is used to calculate the flow rates that are
derived from the aquifer that borders  the outermost drains.  This flow
component is not considered in the drain spacing equations but could
significantly affect the pipe sizing of the border drain.  Discharge of
the border drains can  be derived exclusively from horizontal flow or
through a combination  of horizontal and radial flow.  Figure 2-5 shows
the division of the border drain flow  into two fragments that can be
calculated separately  and summed.
    The quantity of flow into fragment 1 (Figure 2-5) can be estimated
(Moulton, 1979) from the equation:

    Q_, = K(h2)x/2(R.-b)                                            (9)
     Gl             u
where:
               discharge (m3/day)
    K   = hydraulic conductivity (m/day)
    h   = height of the water table above the drain (m)
    x   = length of the drain (m)
    Rjj=   distance of  the drain's influence  (m)
    b   = half the width of the drain  and the trench  (m).
                                     -19-

-------
i
i
i
                     Impervious Boundary
                                                             Fragment  No.  i
          - — I
                                                                        Impervious
Fragment   No.  2
                                                         H
                                                            D i  q2
                                                                          Impervious
           Figure 2-5*  Division of Symmetrical Drawdown Drain Problem  into Two


                           Equivalent  Fragments  (Moulton, \379)
                                                                                         _Rd_/2_
                           ^-2b


-------
In order to solve the equation, the value of R. must be known or
                                              a
estimated.  Typically, the value of R, is estimated using an equation
                                     d
such as the Sichardt (1940) equation:

    R. = C(h)(K)°'5                                                 (10)
     a
    where h and K are as specified as above, and C is a constant that
Sichardt set equal to 3; however, most drainage engineering books now
recommend this constant be set at 1.5-2 for "realistic" results.
    The quantity of flow into fragment 2 can be estimated (Moulton, 1979)
from the equation:
    <>   = (K(H-D)x)/[R./D)-(l/ff)(log 0.5(sinh w/D)]                 (11)
     G2               d
where the new terms are:
    H = height of water table above impervious barrier (m)
    D = height of the drain above impervious barrier (m)
Once the individual discharges for the segments are calculated, the total
discharge is the sum of the individual discharges.  For sites on
impervious barriers, the total discharge is equal to Q  ; for sites
with drains above an impermeable barrier the total discharge is the sum
of QG1 plus QG2.
2.2.3  Pipe Size
    Once the total discharge (Q ) has been determined, an appropriate
grade selected, and the appropriate roughness coefficient determined, the
minimum drain diameter can be determined.  Nomographs such  as the one
shown in Figure 2-6 are typically utilized to obtain pipe diameters.
Because the nomographs are based on the Manning formula (Equation 7),
this formula can be used directly to obtain pipe size.  Rearranging
Equation 7, pipe diameter  (d) can be found from:
               0.5 1.5
    d = 4(Q n/i   )
                                    -21-

-------
                i;
                '  •
                (I
I
I   >
I
                ,•„


                '•!
                n
                c  I
                I'

                  •

                M
                 o
                   i
 H-
II'J
 s
 M
 n

 i  i
 i
  V.
                              '   .
 n
 H-
 • i
                              i i
                               I


                              H


                               II


                                 •


                              •   '
                              l   '
                              i  .,

-------
    A margin of safety is usually incorporated in the selected drain
diameter which will account for the reduction in drain capacity caused by
siltation over time and for any discharge in excess of the design
capacity.  Because the nomographs and Manning formula estimate drain
diameter without accounting for a margin of safety, the drain diameter is
typically chosen as the next larger size.
2.3  Filters and Envelopes
    Performance of a drainage system is based on the assumption that the
pipe will accept all inflow without a pressure build-up.  Filters and
envelopes are used to ensure that this requirement is met.
2.3.1  Function of Filters and Envelopes
    The primary function of a filter is to prevent soil particles from
entering and clogging the drain.  The function of an envelope is to
improve water flow into the drains by providing a material that has a
higher permeability than the surrounding soil.  Envelopes may also be
used to provide suitable bedding for a drain and to stabilize the soil
material on which the drain is being placed.  The filter's function and
the envelope's function are somewhat contradictory because filtering  is
best accomplished by fine materials, and coarse materials are more
appropriate for envelopes.
    As percolating water approaches a subsurface drain, the  flow velocity
increases as a result of convergence towards the perforations or joints
in the pipe.  This increase in velocity  is accompanied  by an increased
change in hydraulic gradient.  As a result, the potential for soil
particles to move towards the drain is  increased.  By using  a highly
permeable envelope material around the  pipe, the number of pore
connections at the boundary between the  soil and the envelope will
increase, thereby decreasing the hydraulic gradient.
    A filter should prevent the  entry of  soil  particles, which  could
result in sedimentation  and clogging of the drains,  blocking of
                                     -23-

-------
perforation or tile joints, or blocking of the envelope.  The filter
materials should not, however, be so fine that they prevent all soil
particles from passing through.  If silts and clays are not permitted to
pass through, they may clog the envelope resulting in increased entrance
resistance which can cause the water level to rise above the drain.
    Although filters and envelopes have different distinct functions, it
is possible to meet the requirements of both a filter and an envelope by
using well-graded sands and gravels.  The specifications for granular
filters, however, are more rigid that those for envelopes.  It is usually
necessary for filter materials to be screened and graded to develop the
desired gradation curves.  Envelope materials, on the other hand, may
have a wide range of allowable sizes and gradings (Soil Conservation
Service, 1973).
2.3.2  Design of Sand and Gravel Filters
    Detailed design procedures are available for both gravel and sand
envelopes.  The Soil Conservation Service (SCS) (1973) has distinct
design criteria for filters and envelopes, whereas the Bureau of
Reclamation (1979) has developed one set of standards for a well-graded
envelope which meets the requirements of both a filter and an envelope.
The separate SCS design criteria will be considered below for the
following reasons:
    o  Site specific conditions may warrant the use of only a filter or
       an envelope, but not both.
    o  Where both a filter and an envelope are needed, the SCS design
       criteria for a filter can generally be used.
    o  It may be desirable to use a fabric filter with a gravel envelope.
    The approach recommended by SCS is  to determine whether the drainage
system needs a filter and then determine the need for an envelope.
Generally, this sequence is performed because a well-graded filter  can
also function as an envelope.
                                     -24-

-------
    The general procedure for designing a gravel filter is to (1) make a
mechanical analysis of both the soil and the proposed filter material;
(2) compare the two particle distribution curves; and (3) decide by some
set of criteria whether the envelope is satisfactory.  The Corps of
Engineers and the Soil Conservation Service (1973) have adopted similar
criteria which set size limits for a filter material based on the size of
the base material.  These limits are:
    50 percent grain size of the filter
     _ ~       ,;:,. ..   r     = 12 to  58
     50 percent grain size of the base
    15 percent grain size of the filter
    —           	~	 = 12 to  «*0
     15 percent grain size of the base
Multiplying the 50 percent grain size of the base material by 12 and  58
gives the limits within which the 50 percent grain size of the filter
should fall.  Multiplying the 15 percent grain size  of the base material
by 12 and 40 gives the limits within which the 15 percent grain  size  of
the filter should fall.
    All of the filter material should pass the 1.5 inch  sieve, 90 percent
of the material should pass the 0.76-inch sieve, and not more than
10 percent of  the material should pass the No. 60 sieve.  The maximum
size limitation aids  in preventing damage to drains  during placement,  and
the minimum size limitation aids in  preventing an excess of  fines  in  the
filter which can clog the drain.  When the filter and base materials  are
more or less uniformly graded, a generally safe  filter stability ratio of
less than 5 is recommended.
    15 percent filter grain size _ 12 fcQ 5g
    85 percent filter grain size
    Consideration must also be given to  the  relationship between the
grain  size of  the  filter and  the diameter of  the perforations  in the
pipe.  In general,  the 85 percent grain  size  of  the  filter  should  be  no
smaller than one-half the diameter of  the perforations.   SCS recommends a
minimum filter thickness of 8 cm  (3  inches)  or more  for  sand and gravel
envelopes  (Soil Conservation  Service,  1973).
                                     -25-

-------
2.3.3  Design of Sand and Gravel Envelopes
    The first requirements of sand and gravel envelopes is that the
envelope have a permeability higher than that of the base material.  SCS
(1973) generally recommends that all of the envelope material should pass
the 1.5-inch sieve, 90 percent should pass the 0.75-inch sieve, and not
more than 10 percent should pass the No. 60 sieve  (0.25 millimeter).
This minimum limitation is the same for filter materials; however, the
gradation of the envelope is not important since it  is not designed to
act as a filter.
    The optimum thickness of envelope materials has  been a subject of
considerable debate.  Theoretically, by increasing the effective diameter
of a pipe, the amount of  inflow  is  increased.  If  the permeable envelope
is considered to be an extension of the pipe,  then the larger  the
envelope's thickness the  better.  There are, however, practical
limitations to increasing envelope  thickness.  The perimeter of the
envelope through which flow occurs  increases as  the  first power of  the
diameter of the envelope, while  the amount  of  the  envelope material
required increases as the square of the diameter.  Doubling  the diameter
of the envelope (and consequently decreasing the  inflow  velocity  at  the
soil-envelope interface by half) would  require four  times the  volume  of
envelope material with an attendant increase  in  costs.   Recommendations
for drain envelope thickness have been made by various  agencies.   The
Bureau of Reclamation (1978) recommends a minimum thickness  of
10 centimeters (4-inch) around  the  pipe.   SCS  (1973) recommends an
8 centimeter (3-inch) minimum thickness.
2.3.4  Synthetic Filters
    For synthetic materials, the suitability  of a filter can be
determined from the ratio of the particle size distribution  to the pore
size  of the fabric.  The  accepted  design  criterion for geotextile filters
 is:
                                     -26-

-------
      P85 (85% pore size of the filter fabric)
    D85 (85% grain size of the subgrade material)  ~

    or P85 < D85

Using this equation, the P85 of the filter fabric can be determined from
the D85 of the subgrade soil.  Manufacturers  of  geotextile fabrics can
then be consulted to select the proper filter type  (DuPont Co., 1981).
                                      -27-

-------
                       3.0  DESIGN AND CONSTRUCTION

    This chapter presents an analysis of a hypothetical zone of
saturation landfill site that is based on data provided by the State of
Wisconsin.  A sensitivity analysis was performed for the site (based on
the equations presented in Chapter 2) using the following parameters:
    o  Groundwater/leachate generation rates, q
    o  Hydraulic conductivity of waste materials, K^ and native soils,
       K2
    o  Head maintenance levels within the site, h
    o  Drain spacing, L
Also included in this chapter are design and construction considerations
which may be incorporated into a zone of saturation landfill.
3.1  Hypothetical Site
    A hypothetical zone of saturation landfill site was developed using
available data from similar sites located in Wisconsin.  A cross-section
of this site is presented in Figure 3-1.  Table 3-1 presents some of the
typical ranges of values that may be encountered at similar sites.  The
hypothetical site and the accompanying site data are used in the next
section as the basis for the sensitivity analysis.  Assumptions made to
simplify the site conditions include:
    o  Landfill materials and soils are homogeneous and isotropic.
    o  Water tables within and outside the site are drawn down to drain
       level.
    o  Groundwater system is at equilibrium (steady state) conditions.
    o  Groundwater pressures in the underlying (dolomite) aquifer do not
       affect groundwater movement into the bottom of the pit.
                                    -28-

-------
lo
-r>
i
                *-
                                                 Final Clay Cover
                                            Landfill Material  (K,=IO"3to id"5)
                                             Base grades = 1 %
 4^
^IV^pvc^pjpe^1^
                                                    „
                                              Original-^
                                           #   water table
f
                             in pea gravel
     -25ft
                                                                 •Recompacted Clay
                                         Clay  (K?=ICr5tolO~7)
          125   250ft
                                                                                    Dolomite
                                 X  X
X  X X  X X  XXX  X  X
            X X  X  X  X  X XX XXXXXXXXXXXX  X  XXX  X
          Figure 3-1= Cross  Section of Hypothetical  Zone  of  Saturation Landfill

-------
                   TABLE 3-1.  RANGE OF SITE VARIABLES
         Parameter
           Range of Values
Cell Dimensions

   o  Depth of cell


   o  Thickness of compacted clay
      beneath drains

   o  Thickness of compacted clay
      sidewalls

   o  Thickness of clay till below
      base grade

   o  Drain spacing

Hydraulic Data

   o  Depth to water table

   o  Permeability of:

        Clay till

        Refuse

        Compacted clay

   o  Drain diameters

   o  Slope of base
20 to 30 feet (average)  up to
60 feet

3 to 5 feet
5 feet (average)
20 to 30 feet (minimum) usually
greater than 50 feet

200 to 400 feet
10 feet (average)



10~5 to 10~7 cm/sec

10~2 to 10~5 cm/sec
< 10~7 cm/sec
   to 6  inches

    (average)
                                     -30-

-------
If these assumptions are invalid, the drain equations will predict drain
spacings that are too large.  The degree to which these equations
over-predict will be directly related to the degree the assumptions are
invalid.
3.2  Sensitivity Analyses
    Sensitivity analyses were performed on the drain equations for:
    o  Drains on impervious barriers
    o  Drains on sloping impervious barriers
    o  Drains above impervious barriers.
The variables in the sensitivity analyses include head maintenance
levels, hydraulic conductivities, flow rates, drain spacing and barrier
slope.
3.2.1  Drains on Impervious Barriers
    The equation for drains placed on an impervious barrier is
(Equation 2, Chapter 2):

    L = (AK^/q)0'5                                                (2)
When using this equation, a barrier is usually considered  impervious if
the barrier material has a permeability (K ) at least 10 times less
than the overlying material (K ).  This situation typically occurs in
landfills that have recompacted clay bases.
    Table 3-2 presents the results obtained when equation  2 is solved for
drain spacing (L) using various values of flow rates  (q),  head
maintenance levels (h), and hydraulic conductivities  (K )  of the
landfill material.  A log-log plot of drain length versus  flow rate for
four hydraulic conductivities (holding the head level constant at  one
meter)  is shown in Figure 3-2.  Table 3-2 and Figure  3-2 show how  the
proper drain spacing (L) is directly related to head maintenance levels
(h), inversely related to the square root of the leachate  generation rate
(q), and directly related to the square root of the landfill permeability
                                    -31-

-------
TABLE 3-2.   DRAIN LENGTH SPACING  (m) FOR DRAINS ON AN IMPERMEABLE BARRIER





1
U)
N)
1







~
4
(•/day)

0.5

0.01
0.005

0.001
0.0005

0.0001

0.00005



io2
157

353


1115
1577

35?7

4989



,o3
50

III
157

353
499

1115

1577



ID'*
•6

35
1 50
1
:>»
i 	
157
*
353

499



io5
1
5 1
L
II
16

35
50

III
1 	
157



,o-'
105
	
235
333

744
105?

235?

3326

h

,o-3
33


1
| 105
1 	
235
333

744

1052

-4(.J

• o-»
II

23
33
	 (
i "
|
1 105
I 	
235

333



h.!
1.)


h-l(')


h-0.5(l)

Mc./itc)
,o-5
3

7
II

23
33
.
1 "
1
1 105
1 	
io-2 ,
1
1 52
1
j_ "8
166 |
1
371 *
525

1174

1661


17

37
52

118
166

371

525

io-*
5

1?
1?

37
t
1 5?
1
1 118
1 	
166

io"5 io 2 io"3 io* io 5 io 2 io~3 io*
2

li
5

12
17

37
-1
1 52
1 	
26

59
83
L___,
186 |
1
263 I
1
588 1
L
831
—
8

19
26

59
83

186
	 1
263 1
l_
3

6
8

19
26

59

83
_ 	 _
1

2
3

6
13

29
42

93
8 131
1 	 ,
19 Z94 1

26 416 .
. . 	 - "~
4 1

9 3
13 4

29 9
42 13

93 29

31 42
— _
,o5
> 1

I
1

3
*

9

13
-.-. -
      Isobar equal to 122 liters (400 ft.): »a
-------
   10001
                  3  4 367891
                                     2   3  4567891
                                                            2   3  4S67891
t.

. i
    1001


       (I

       7

       6
 I .-:


  I
       I i
         I'M
           I
                                                                                                          2    3  4567891
                     0.00005  0.0001      0.0005     .001            0.005   0.01



                                                            (q(m/day)




                          Figure  3-2.   Drain Length versus Flow Rates for Head Levels Equal to 1-meter

-------
    Leachate generation rate  (q) and landfill permeability  (1^) are the
most important parameters to  determine accurately when designing a
landfill, not because they are the most sensitive, but because they are
the most difficult to determine accurately.  Head maintenance levels are
usually predetermined in the  landfill design and therefore  are not
sensitive even though they potentially can have the greatest effect on
drain spacing.
    One aspect of the equation for drains on impervious barriers that is
not readily apparent is that  this equation can also be used for
determining the depth of drainage blankets.  When the equation is
utilized for this purpose, the height of the water table  is designed to
remain within the blanket.  Permeabilities of the drainage  blanket
materials are also generally  known with some accuracy, which is not the
case with most landfill materials.  Table 3-2 also shows  the combination
of flow rates, hydraulic conductivities, and head maintenance  levels that
yield drain spacings that are equal to or less than the maximum spacing
used in the hypothetical site (i.e., 400 ft).  Generally, when flow rates
are large and hydraulic conductivities are low,  the theoretical upper
limit of 400  feet on drain spacing  is  too large  to accomplish  the
intended design.  It  is, therefore, important to quantify the  values
associated with  leachate generation rates  and landfill  permeabilities to
determine drain  spacing; drain  spacing should not be  specified
arbitrarily.
3.2.2  Drains on Sloping  Impervious Barriers
    Drains  that  are  placed on sloping  impervious barriers are  governed  by:

    L  =  (2h/c°'5)/[(tan2a/c)  +  1 - (tan  a/cMtan a+c)  '  ]           (6)
As  discussed  in  the  previous  section,  the  underlying  drain material  is
typically  considered impermeable if its  permeability  is at least  ten
times  less  than  the  permeability of the  overlying material.  This
situation  is  typical of landfills that have  compacted clay bases.
                                     -34-

-------
    Table 3-3 gives solved values of h/L for selected values of c = q/K
and barrier slope angles, a.  Figure 3-3 presents a plot of h/L versus
I = tan ex for selected values of c = q/K .   This graph shows how h/L
is indirectly related to the barrier slope angle and directly related to
c = q/K .  Generally, the greatest decrease in h/L occurs when the
barrier angle increases from zero to five degrees (i.e., up to
approximately 10% slope).  Angles greater than five degrees cause
decreasingly smaller changes in h/L.  For design purposes, this means
that increasing the angle above five degrees has little effect on head
maintenance levels (h) and drain spacing (L).
    Using the values of h/L presented in Table 3-3, drain spacing was
solved while holding head maintenance levels (h) constant at two meters.
Table 3-4 presents the results of this analysis, and Figure 3-4 shows a
plot of drain length versus c = q/K  for barrier angles of 0°, 1° and
5°.  These data show that if h is held constant, the barrier angle has
the greatest effect on increasing drain spacing length at lower values of
c = q/K  (i.e., low leachate generation rates divided by high
permeabilities).
    The equation for drains on an impermeable sloping barrier can also be
utilized for determining the thickness of a drain blanket by substituting
h for the thickness of the drain blanket (i.e., so that the maintenance
head level is designed to be within the blanket) and K  for the
permeability of the drain blanket.  For example, consider a landfill
without a drainage blanket with the following parameters:  q =
0.0005 m/day, K  = 0.00864 m/day (i.e., 10~  cm/sec), a = 1", and
h = 2 meters.  Based on these figures, drains would have to be spaced at
intervals of L = 18 meters to maintain a 2-meter head level.  If a
drainage blanket that has a permeability of K  = 0.864 m/day
   _3
(10   cm/sec) is installed at the site and the values of q and L remain
unchanged, the thickness of the blanket and hence the corresponding
height of the head levels would be 0.14 meters.  This is a substantial
reduction in head levels for a relatively thin drain layer.  The
advantage to lowering the head level within the site is that less
leachate is likely to be released from the site.

                                    -35-

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TABLE 3-3  VALUES OF h/L FOR VARIOUS C=q/Kj AND ANGLES a
c=q/Kj
5.787
0.5787
0.05787
0.005787
0.0005787
0
1.203
0.380
0.120
0.038
0.012
a (degrees)
0.5 1
1.198
0.376
0.116
0.034
0.009
1.194
0.372
0.112
0.031
0.008
2
1.186
0.364
0.105
0.027
0.007
3
1.177
0.356
0.101
0.024
0.006
5
1.161
0.341
0.092
0.022
0.006

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     0.10
    0.06
    0.06
    0.04
    0.02
                                              .0001
                    0.1
0.2
 to n
0.3
0.4
Figure 3-3.  Plot  of  h/L versus I=tar. a for
             drain and  sloping in^ervious labors
             (Moore,  1980)'
                           -37-

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TABLE 3-4  DKAIN SPACING (m) FOR HEAD MAINTENANCE LEVELS OF 2-METERS
c-q/I^
5.787
0.5787
0.05787
0.005787
0.0005787

0
1.66
5.26
16.67
52.63
166.67

1
1.68
5.38
17.86
64.52
250.00
a (degrees)
3
1.70
5.62
19.80
83.33
317.40

5
1.72
5.87
21.74
90.91
326.60
                                 -38-

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                                                                                                  3  4  5  6 7 B 9 I
5. 787(10  A)
5.787
                                            c=c|/K
                                                  I
                                                                         o   - o
      l'"i|Min- T-/I .   Drnin  T.onpitli  (I,)  vorsua  c=q/K^  for u P(|iinl  to 0  ,  1  ,  and  5  .

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3.2.3  Drains Above an Impervious Barrier
    The governing equation for a drain system above an impervious barrier
is:
                        .0.5                                        0)
    L =
    where the parameters are as defined previously in Chapter 2.
    This equation takes into account radial flow to the drains through
the material underlying the drain.
    Solutions to the equation are shown in Table 3-5 for a head
maintenance level (h> of two meters, a permeability (K > of the
                                            _5        •"•
landfill material of 0.00864 m/day (i.e., 10   cm/sec), and a depth to
the impermeable layer (D) of 30.4 meters.  Figure 3-5 shows a plot of
drain spacing (L) versus inflow rates (q) for various permeabilities of
underlying material (K  ).  These presentations show that when the
permeabilities of the overlying (K ) and the underlying (K2> material
are the same, the drain spacing (L) increases.  This phenomenon is caused
by the introduction of  radial flow to the drains rather than straight
lateral flow.
    When the permeability of the underlying material (K2>  is an order
of magnitude (0.1) less than the overlying material (KI>,  the
calculated drain spacing does not differ significantly from a drain on an
impermeable barrier.  If the underlying material has a permeability that
is two orders of magnitude  (0.01) less than the overlying  material, the
drain spacing is identical  to a drain on an impermeable barrier.  This
occurs because the term 8K  dh does not significantly affect the results
of the drain spacing equation.  Consequently, the "rule of thumb" for
designing drains is that if the underlying layer has a permeability at
least 10 times less than the overlying material, the underlying material
can be considered  impermeable.
3.3  Application
    The basic premise behind the  use  of  a  landfill  located in  the zone of
saturation  is that  if  the  head maintenance levels within  the  site are
                                     -40-

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TABLE 3-5  DRAIN SPACING (m) FOR DRAINS ABOVE AN IMPERMEABLE
           BARRIER (h-2m, K =0.00864 m/day  (10-5cm/sec), D=30.4m)
q
(m/day)
0.05
0.01
0.005
0.001
0.0005
0.0001
0.00005

io-5
2
5
7
19
31
114
212

io-6
2
4
5
12
18
43
64
K9 (cm/sec)
ID'7
2
4
5
12
17
37
52

Impermeable
2
4
5
12
17
37
52
                               -41-

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         2    3   4  5 fi 7 8 <» 1
                                7    .1  4
                                                                               2    3   4367891
                                                                                                       Z   3  456789
1,1
                                                                                                          t'1'1
               0.0005 0.0001
0.0005  0.001
0.005    0.01
0.05
                            FlRiire 3-5.   Drain SpnrfnK  ('•) versus  inflow races  (q) where
                                          li=2  mi-1 ITS and Kj=10~5  cm/sec.

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less than the groundwater levels outside  the  site, then hydraulic
gradients should be into the  site, thus minimizing the likelihood of
contaminant release.  Basic hydraulic principles  show this to be the case
as long as (1) the landfill materials and soils are homogeneous and
isotropic, (2) water tables are drawn down to drain levels, and (3) the
groundwater system is at equilibrium.  In reality, these conditions
rarely exist at a landfill site.  For these real-world situations, the
Wong (1977) model can be used to predict  releases.
3.3.1  Parameter Estimation
    In order to utilize the drain spacing equations, the input parameters
must be known with some accuracy.  The two parameters which are the most
difficult to estimate accurately are leachate generation rate (q) and
hydraulic conductivity  (K).   Head maintenance level  (h) and barrier slope
angle (a) are typically chosen by the designer and are not estimated.
    Total inflow rates  to the drains can  be estimated through the use of
water balance equations (equation 8) and  the method of fragments
(equations 9 and 10).  These  equations, however,  do not take into account
the volume of liquid that is  added to the site as landfill material
(e.g., paper waste sludges).   Estimating  this volume is very specific to
a landfill.  Once the total volume is estimated,  the value should
probably be increased to take into account variations that were not
anticipated (e.g., acceptance of more liquids, unseasonably high
precipitation) and to add a margin of safety to the design.
    Determining the hydraulic conductivity of the landfill material with
any accuracy is very difficult because, typically, the material is a
mixture of wastes and daily covers which  tends to create discrete cells.
Waste mixtures tend to cause  the landfill to be very heterogeneous and
anisotropic, making estimations of permeabilities difficult.  Here, as
before, the hydraulic conductivity selected should probably be the
highest value found for the waste materials.  The problems associated
with daily cover can be minimized if the  cover is removed each day,
allowing old and new fill materials to be hydraulically connected.
                                    -43-

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    The use of drainage blankets in a landfill effectively eliminates the
problem associated with determining conductivities.  Hydraulic
conductivities for the drainage blanket can be determined easily in the
lab and most blanket materials are relatively homogeneous and isotropic.
A blanket layer covering the bottom of the cell and the sidewalls
provides a hydraulic connection between the leachate generated and the
drains.  A drainage blanket also aids in the prevention of leachate
pooling, accelerates leachate removal times, and allows for lower head
maintenance levels with the same drain spacing.
3.3.2  Landfill Size
    Technically a landfill is depth-limited in a zone of saturation
setting only by the propensity of the sidewalls for slumping or failure.
Theory shows that lower base grades in the fill result in higher
hydraulic gradients into the site.  These higher gradients will result in
larger quantities of groundwater that must be removed from the site.
Problems can arise, however, if the base grades are extended deep enough
to cause quick conditions in the base or if the base intercepts an
aquifer that has a lower head level than the overlying aquifer.  If quick
conditions occur, extensive dewatering may be necessary to maintain a
stable base.  If the base extends into an underlying aquifer with a lower
head level, contamination of the aquifer is likely when the pit is
filled.  The areal extent of the landfill is generally not considered
limiting if the drainage system is functioning properly.
3.3.3  Example Problem
    An example of the use of the drain equations for the hypothetical
site developed in Section 3.2 is presented here for illustrative
purposes.  Table 3-6 presents the data utilized in the example.  For the
example, the recompacted clay base and sidewalls were assumed to have the
same permeabilities as the saturated clay aquifer.
    To calculate the drain spacing needed at the site, the equation for
drains on sloping barriers (equation 6) can be used because the
                                    -44-

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               TABLE 3-6.  EXAMPLE DATA SET
 Parameter
          Value
Cell Dimensions

 o Width
 o Length
 o Depth
1000 ft (304m)
1000 ft (304m)
  30 ft (9.1m)
Clay Thickness Below Base
  50 ft (15.2m)
Hydraulic Conductivities
 o Fill (K1)

 o Clay (F^)
   - compacted or natural
10 5 cm/sec (0.00864 m/day)

10~7 cm/sec (0.0000864 in/day)
Base Grade
1% (0.6 degrees)
Water Table  (b.l.s.)
10 ft (3.0m)
Head Maintenance Levels
10 ft (3.0m)
Inflow (q) From Percolation    10  in/yr  (0.0007  m/day)
                             -45-

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underlying clay material has a permeability of 10 times less than the
fill material.  Solving equation 6 for drain spacing (L):

    L = (2h/c°'5)/[(tan2a/c) + 1 - (tan a/c)(tan o+c) ' ]
        c =
        = 0. 0007 (m/day)/0. 00864 (m/day)
        = 0.08102

    L = <2(3.0)/0.08102°'5/[tanZ0.6/0.08102)+l-(tan 0.6/0.08102)

        [ ( tan20 . 6+0 . 008102 ) ° ' 5 ]
      = (21. 079) /[ (0.00135 )+l-(0. 12926) (0.28483)]
      = 21.85m(71.89 ft)
The value obtained for drain spacing using these parameters is
significantly less than the currently specified allowable upper limit
(about 400 ft).  However, this solution would not be considered
conservative for an actual site where (1) conductivities of the fill may
not be a uniform 10~  cm/sec,  (2) inflow rates may be higher than
expected; for example, when the site  is not capped, and  (3) materials
with high water content may be landfilled.
    An appropriate pipe size can be selected by calculating the system's
expected discharge and considering the factors described in Section 2.
Total flow along any single collector pipe can be calculated by:

    Q1 = qA
where q, inflow, is 0.0007 m/day and  A, area, is the area drained by each
drain line-22m  x 304m (drain spacing  times length)
    Q  = (0.0007 m/day) (22m) (304m)

       = 4.7 m3/day (0.002 ft3/sec)
Using Figure 2-6 for plastic pipes with a roughness coefficient of
n = 0.013 and a design velocity of 1.4 ft/sec, a 4-inch  drain  pipe  should
be sufficient to handle the discharge.  Total discharge  from the main
header pipe  is:
                                    -46-

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    QT = qA
       = (0.0007 m/day)(304m) (304m)

       = 64.7 m /day (0.026 ft /sec or 17,094 gal/day)
Using Figure 2-6 again, a 4-inch pipe should be sufficient to handle the
flows.  A larger size pipe may be selected as a margin of safety.
3.4  Construction Aspects
    Previous discussions related the application of the design criteria
for zone-of-saturation  landfill leachate collection systems to a
hypothetical site.  Some aspects of construction of these sites are
important but do not fall within the focus of the other sections.  These
considerations  are described  in the following sections and include:
    o  Construction inspection
    o  Collector drain  maintenance
    o  Future operating conditions
3.4.1  Construction Inspection
    Construction  inspections  are important  to ensure  the  specified design
criteria are  implemented  in  the field.   Some criteria which  are  important
for zone of  saturation  landfills are:
    o  Moisture of clays when compacted  on  bases  and  sidewalls
    o  Placement  of drain  pipe  and filter envelopes,  and  their protection
       while  exposed
    o  Compliance with  specified design  criteria  for  slopes,  and drain
       blanket  thickness  and gradation
    The  clay tills associated with the  zone of  saturation landfills  can
easily exceed the moisture content at which maximum density can  be
achieved.   Trying to  compact these excessively  wet clays  on the  base and
sidewalls  of the  landfill is a wasted effort,  and in many instances,
causes the soil to  shear.   Shearing of  the  clays  may result in  planes of
weakness  and cracks  throughout the layer which  can easily transmit
                                     -47-

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leachate out of the cell.  Construction inspections can identify when the
soils exceed the optimum moisture content for compaction and prevent
their placement until the clays have dried to within an acceptable
moisture content range.
    Construction inspections should be performed during drain pipe and
filter envelope placement.  Inspections can ensure that these operations
are performed as specified in the designs and that:
    o  Drain pipes are not damaged during placement
    o  Filter materials are kept free of fines and are graded and
       installed properly
    o  Drains are protected after placement so that fines do not clog
       drains before wastes are placed
    Slopes specified within a cell are generally just enough to prevent
pooling of leachate on the compacted clay base (i.e., 1% slope).  With
these gentle slopes, there is a very small margin for error that would
still ensure that leachate moves freely towards the drain.  Inspections
performed during the grading of the base can verify proper construction.
Inspections should also be performed during the placement of a drain
blanket to ensure adequate blanket thickness and proper gradation of the
blanket material.
3.4.2  Drain System Maintenance
    Proper maintenance of a drain system is a critical element in
ensuring its continued performance.  The initial design of the system
must allow for  adequate  access to the drain system  components both  for
inspections and cleanings.  Regular maintenance inspections should  be
performed to assess the  system's performance and to plan cleaning and
repairing activities.  Additionally, maintenance inspections should be
performed when  an unexplained reduction  in flow occurs to  sumps or
increased head  levels  are observed within  the cell.
                                     -48-

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3.4.3  Future Operating Conditions
    Landfill designs should anticipate and account for the type of waste
disposal operations planned.  As mentioned previously, hydraulic
conductivities of the wastes placed in a cell are critical to the design
of the leachate collection system.  Conductivities used for design
purposes are frequently estimates based on the experience of the designer
or are averages that represent the range of conductivities that could be
found throughout the cell.  If the landfill will be accepting balings,
shreddings, large solid objects, or separations of particular wastes
during its operational life, the conductivities used in the drain designs
should be adjusted to reflect the hydraulic conductivity of these
materials and their volume in relation to the remainder of the fill
material.
    The total quantity of water that must be extracted from zone of
saturation landfills can vary widely.  Water can be derived from
percolating rainfall, groundwater infiltration, and from sludges or
liquids brought into the site.  Underestimating the amount of water that
must be removed will result in rising internal head levels and the
eventual release of generated leachate.  Therefore, care must be
exercised to ensure that water removal capabilities specified in the
landfill design realistically represent the eventual landfill operations.
                                    -49-

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                          4.0  FLOW NET ANALYSIS

4.1 Introduction
    Water flow through porous media is governed by several physical
relationships (e.g., Darcy's Law) that can also be represented
mathematically.  The equations used to represent this flow can be
arranged so that they apply to certain physical conditions.  The
solutions to the equations can then be obtained through numerical or
graphical means; the graphical solutions are called flow nets.  In this
case, the flow nets are graphical representations of two-dimensional
equations of continuity for water flow.
    The generation and application of a flow net requires certain
assumptions and simplifications.  Most of these are common to any
representation (model) of a natural physical system and include the
assumptions of aquifer homogeneity, water incompressibility and laminar
Darcian flow.  Consideration of site conditions at each of three
Wisconsin landfills reveals several features which are common to all, so
that the flow nets can be constructed for a generic site that
incorporates these common features (Figure 4-1) and also includes some
simplifications.  These include:
    a) elimination of small heterogeneities in the clay around the site,
       since they are discontinuous and not well-mapped.
    b) treatment of the underlying dolomite as an impermeable boundary.
       It is recognized that recharge to the clay probably does occur
       from the dolomite; however, the vertical permeability of the clay
       is low enough that this recharge can be considered negligible for
       the purposes of constructing a flow net.
    c) treatment of all landfill surfaces as orthogonal to ground surface.
    d) assuming that the landfill excavation can be treated as a circular
       well so that water flows radially to it.
                                    -50-

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                      LEACHATE MAINTENANCE LEVEL
                                                                       WATER TABLE
                                         REFUSE
                                              x10~3cmsec~1
CLAY TILL
K  *1 x 10  cm sec
   DOLOMITE
                        DRAINS
                                                            O
                                                                          * 70-80 FEET
                                                      h ^50-75 FEET
                                                      0  20 40  60 FEET
0
10 FEET
     FIGURE 4-1. CROSS SECTION OF TYPICAL ZONE-OF-SATURATION LANDFILL
                                       51

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    e) assuming that the water table aquifer can be treated as a line
       source of seepage beyond 250 feet from the landfill.
The flow nets are composed of two families of lines that intersect at
right angles.  Flow lines show paths along which water can flow;
equipotential lines represent lines of equal hydraulic head.   The flow
nets constructed for the generic site indicate the approximate
arrangement of flow lines and equipotential lines around the landfill for
different physical conditions, as explained below.
4.2 Initial Conditions
    Three points need to be made about the flow nets before examination.
First, by treating the excavation as a circular well, some idea of the
radius of influence (R ) and equivalent well radius (R ) can be
obtained.  These are defined by:
         r	
          LW
         	  where L = length of landfill
          *          W = width of landfill
    Values of L and W were chosen equal to 300 ft. so that R  = 169 ft.
             rr~
   R  = C&h-»  /      where C = a constant ranging from 1.5 to 3
                        Ah = drawdown expected in "well"
                         K = hydraulic conductivity in cm/sec
    Values chosen for Ah (30 feet) and K (1 x 10   cm/sec  )
represent typical values for these parameters at each site.  Several
references used suggested setting C = 2.0 for typical results.  This
gives R  = 19 feet.
       o
    Second, there is a difference between the horizontal and vertical
hydraulic conductivities at these sites because of the layered nature of
the till deposits.  Average values for horizontal K and vertical K used
here were 1 x 10   cm/sec   and 2 x 10   cm/sec   , respectively.
Construction of flow nets for anisotropic media requires that the
horizontal and/or vertical dimensions be transformed to offset the effect
of different horizontal and vertical hydraulic conductivities.
                                    -52-

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                                                y
                                LANDFILL CELL
                       300 FEET
                                                                   ~l
                                             AQUIFER ACTS AS LINE SOURCE
                                             OF SEEPAGE BEYOND THESE LINES
FIGURE 4-2.  INFLOW TO TYPICAL LANDFILL CELL (PLAN VIEW)

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A .3 Parameter Analysis
    Examination of the effect of leachate maintenance levels
(Figures 4-3A, B, C) indicate that the most favorable situation in terms
of collecting lower amounts of leachate is when the maintenance level is
relatively high.  This causes redistribution of the equipotential lines
in the aquifer around the drains such that the contribution of inflow
from the aquifer is small compared to that from the leachate.  However,
this does not leave much of a safety margin and also enhances the
susceptibility for outward leakage along permeable sandy lenses in the
sides of the landfill.
    Analysis of the effect of vertical gradients (Figures 4-4A, B)
indicates that, in comparison to sidewall inflow and leachate from the
refuse, the amount of inflow at the base will be small regardless of the
direction of gradient.  This is predominantly due to the low vertical
hydraulic conductivity of the clay till in contrast to the more permeable
sidewalls.
    Analysis of the effect of drain spacing (Figure 4-5) shows that the
drains tend to depress equipotential lines between their centers,
bringing higher head levels closer to the bottom of the excavation.  In
the presence of a local downward gradient, this might enhance the
possibility of diffusion of contaminants through the base of the fill,
although most movement would be horizontal because of aquifer
anisotropy.  As the number of drains increases, this effect becomes less
noticeable, and at some point would be offset by inflow through the base
of the excavation.
    The effect of the depth of excavation below the water table can also
be examined by using some of the assumptions and site dimensions given
earlier and treating the excavation as a well.  If the leachate
maintenance level is set at the base of the fill, the amount of inflow in
relation to excavation depth varies as follows:
                                    -55-

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     (7)  LEACHATE LEVEL AT (H-h)





                           t
       B) LEACHATE LEVEL AT (H-1)
      C )  LEACHATE LEVEL AT (H-.5h)
                                                 SCALE:
                                                             0



                                                             10 FT.
                                                 VERTICAL EXAGGERATION = 7x
FIGURE 4-3. FLOW NETS WITH DIFFERENT LEACHATE LEVELS

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         B  UPWARD GRADIENT
FIGURE 4-4. FLOW NETS WITH DIFFERENT VERTICAL GRADIENTS

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      A)  TWO CORNER DRAINS
      B )  THREE DRAINS
        r
       C] SIX DRAINS
FIGURE 4-5.  FLOW NETS WITH DIFFERENT NUMBERS OF DRAINS
                        58

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          Depth Below Water                Approximate
          Table Excavated. Ft.             Inflow. GPM
                   10                           8.8
                   20                          16.7
                   30                          23.8
                   40                          29.8

These inflows need to be considered  in comparison to the capacity of the

drain system and the possible  inducement of heaving or buckling because

of the artesian head in the underlying dolomite.  Rough calculations

indicate that 40 feet  is about the maximum depth  that should be
excavated, less if the remaining  depth to  the  dolomite  is  below about 50

feet.
                                      -59-

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                               5.0  MODELS

    This chapter characterizes some commonly accepted models that can be
utilized in the design and performance evaluation of waste disposal
sites, and in the tracking of pollutants released from these sites.
These models are divided into two major groups:  (1) release rate models
and (2) solute transport models.  Typically, estimates of leachate
quantity and quality released from a site are obtained from a release
rate model and are used as input to a solute transport model.  The theory
behind some of the models is very complex and readers should refer to
other sources such as Bachmat et.  al. (1980), Mercer and Faust (1981),
Anderson (1979), and Weston (1978) for in-depth discussions of modeling.
5.1  Release Rate Models
    The first and probably the most crucial step in waste site modeling
is to obtain accurate estimates of the quantity and quality of leachate
that will be released into the subsurface environment.  Only after
adequate determination of leachate release can a solute transport model
be performed.  This section briefly describes the theory behind  release
rate models and presents those models that can potentially be utilized  in
obtaining release rates from landfills.
5.1.1  Fundamentals
    Most release rate models are based on dividing  the problem of
prediction into three separate components—leachate generation,
constituent concentrations, and leachate release rates from the  site.
Combining the three separate components allows for  prediction of the
quantity and quality of leachate that can be expected to be released  from
the site.
                                     -60-

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5.1.1.1  Leachate Generation
    Leachate generation refers to the quantity of fluid within the site
available to leach and transport waste constituents.  The major factors
that directly influence leachate generation are listed in Table 5-1.
Probably the most important factors for zone-of-saturation landfills are
infiltrating precipitation and groundwater intrusion.  There are
currently two main approaches for predicting leachate generation—the
water balance approach and the use of bounding assumptions.
    Fenn, Hanley, and DeGeare (1975) pioneered the  use of water balances
to predict leachate generation from solid waste disposal facilities based
on the earlier work of Thornthwaite (1955).  Several authors have since
updated and modified Fenn, et al.'s., work for application to other types
of waste disposal sites.  Basically, water balances numerically partition
the amount of fluid moving into, around, and through the cap of a land
disposal facility by utilizing the equation:
                          Perc = P - RO - ST - ET
where:
Perc   = percolation rate; the portion of precipitation which  infiltrates
         the surface and  is not taken up by plants  or  evaporated
     P = precipitation  rate
    RO = surface water  runoff; the portion of  the precipitation which
         does not  infiltrate  into  the ground but  instead moves overland
         away from  the  site
    ST = change  in  soil moisture  storage
    ET = Actual  evapotranspiration;  the  combined amount of water  returned
         to  the  atmosphere  through direct  evaporation  from surfaces and
         vegetative transpiration.
                                     -61-

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     TABLE 5-1   MAJOR FACTORS AFFECTING LEACHATE GENERATION
      Primary Factors
      Secondary Factors
Precipitation


Liquid Content of Wastes



Liquids from Waste Decomposition


Groundwater Intrusion



Soil Moisture Storage


Evapotransp iration



Runon/Runoff Control



Operation Mode

Surface/Cap Conditions
quantity, intensity, duration,
frequency, seasonal distribution

type, quantity, moisture content,
and moisture storage capacity
(field capacity)

waste composition, waste environ-
ment, and micro-organism populations

flow rates into pit, seasonal
distribution of water table, head
levels, liner materials

field capacity of materials,
seasonal fluctuations

temperature, wind velocity,
humidity, vegetation type, solar
radiation, soil characteristics

diversions, crowning of surface
cap, permeability and integrity
of cap, depression storage

open versus closed, coverage

permeability, integrity, surface
contour, runoff underdrain
systems, subsidence
                                  -62-

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    Values for the parameters needed for such an analysis can be found in
a variety of sources or estimated using a variety of techniques.
Precipitation values for a given location are available from a number of
sources including the National Weather Service.  Runoff is very site
specific and difficult to measure.  Most release rate models use one of
the following methods to estimate runoff:
    •  Rational Formula—utilizes empirical runoff coefficients based on
       vegetative type, soil type, and slope.
    •  SCS Curve Numbers—utilizes empirical coefficients which relate
       runoff to soil type, land use, management practices, and daily
       rainfall.
    •  Green-Ampt Equation—approximates runoff based on soil properties,
       initial water content and distribution, surface conditions, and
       accumulative infiltration.
Both evapotranspiration and soil moisture storage can be estimated using
empirical soil moisture retention relationships such as those developed
by Thornthwaite (1955).  Some models require that evapotranspiration be a
measured site specific input, while others  do  not specify a method to
obtain values.  Some models relate evapotranspiration to physical
parameters such as temperature, solar  radiation, and the leaf area index
(LAI), while others store evapotranspiration and soil moisture
information for various locations on a national data base that  can be
accessed by the model.  One model also makes simplifying assumptions to
estimate soil moisture storage  either  by  apportioning soil moisture  into
a "wet" zone and a "dry" zone or by using the  method of  depth-weighted
fractional water content within the soil  profile.
    Release rate models also  allow the user to set  surface  conditions  and
cover  liner characteristics  for the site  with  varying degrees of
flexibility.  Some methods  allow multiple clay-synthetic liners,  others
only clay liners, while  still  another  can only be  applied  to open sites
                                     -63-

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without covers.  Cover vegetation, slope, contour, and soil properties

can also be specified in all but the most simplistic models.

    When cover liners are used to  impede percolation to waste cells,

excess water moves away from the site  through  subsurface lateral drainage

above the liner.  Models estimate  this  lateral drainage by:

    •  Approximate methods  (utilizing  correction  factors) derived from
       the Boussinesq equation for lateral  saturated flow.

    •  Empirical methods development by Moore  (1980) which  calculate the
       maximum hydraulic head above the liner  and then the  upper bound of
       the quantity  of liquid flowing  into  tile drains.  The liner  is
       assumed to be impermeable for these  calculations.

    •  Empirical methods which calculate  percolation through the liner
       and soil moisture storage;  then extrapolate lateral  drainage as
       the remaining excess water.

    The next  step  is to  predict  the  flow  rate  through  the  top  liner.

This  is ultimately the major  contributing factor  in leachate generation.

Numerous methods are used  to  predict  this percolation  rate and they can

be  divided into methods  for clay liners and those for  synthetics.

Methods used  for clay liners  include:

    •  Darcy's Law for  saturated conditions, which relates flow velocity
       to hydraulic  conductivity,  effective porosity,  hydraulic head,  and
       travel distance  using  the following general equation:

                                 V =  Kh/nx

       where:   V  is flow velocity,  K is  hydraulic conductivity,  n is
                effective  porosity,  h is  hydraulic head difference, and
                x  is travel distance

    •  Approximations of saturated Darcy flow as  proposed by Wong (1977).

    •  Soil  storage  routing techniques through multiple soil layers which
       relate liner  permeability to inflow rate,  time interval, hydraulic
       conductivity, soil water storage,  and  evapotranspiration.

    •  Darcy's Law with provisions to arbitrarily increase liner
       permeability  assuming that certain events occur (e.g.,  burrowing
        animals or  equipment breach of the liner).
                                     -64-

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    o  Prediction of unsaturated flow driven by capillary forces
       utilizing the Green-Ampt approximation of the wetting front
       assuming a constant capillary head.
Methods to predict flow through synthetic liners include:
    o  Darcy's Law as described above and based on hydraulic head and
       liner thickness.
    o  Power Law relationships for estimating the aging of a liner based
       on the life expectancy of the liner.
    o  Arbitrary methods such as assuming that the liner will be
       impermeable for 20 years and then will fail completely (i.e.,
       after 20 years the model treats  the  facility  as if it were
       unlined).
    o  Stochastic (Monte Carlo) simulation  for liner failure due to aging
       and installation problems.
    The amount of water percolating through the cover liners and into the
waste cells is either adjusted according  to the moisture  content of the
wastes and fill materials  in the facility,  or the wastes  and fill
materials are assumed to be at field capacity and,  therefore, the amount
of water percolating into  the waste cells  is also the total quantity of
leachate generated.
    Water balances for waste disposal  sites produce  only  relative
solutions to leachate generation for comparing  different  designs or
sites.  The high degree of uncertainty that exists  in these solutions has
led to the use of bounding assumptions.  Bounding assumptions are based
on the knowledge that the  quantity of  leachate  generated  at a given
facility falls between 0%  and  100% of  the maximum potential amount  (based
on total possible leachate),  such  that upper and  lower  bounds for
leachate generation  volume can be  established.  Using  assumptions  and
empirical data,  the  bounds can be  narrowed to  produce  best- and worst-
case  scenarios which can,  in  turn, be  used to  design the landfill  based
upon  performance goals.
                                     -65-

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5.1.1.2  Leachate Constituent Concentrations
    For a release rate model to be useful, it must not only estimate the
quantity of leachate produced, but it also must estimate the quality
(i.e., leachate constituent concentrations).  The quantitative simulation
of the processes and interactions occurring within a landfill to produce
leachate are very complex, and therefore most available models do not
attempt to simulate all these processes.  Table 5-2 lists some of the
factors affecting leachate constituent  concentrations that would have to
be considered.
    Because of the complexity of the  interdependent interactions
occurring within a disposal site and  our  inability to accurately
characterize these interactions, simulations  of the processes are
extremely difficult, if not impossible.   Consequently,  release rate
models do not address  the  factors which govern constituent
concentrations.  Rather, the models make  assumptions  to greatly simplify
the complexities of the real world.   These  assumptions  are:
    •  Constituents are at the  saturation solubility  concentration  levels
       in leachate.
    •  Constituents exist  at  equilibrium concentrations between the
       aqueous and sorbed  phases.
    •  Bounding  assumptions are used  in a similar manner as described for
       leachate  generation.
5.1.1.3  Leachate Release
    Leachate  release  is  defined as  the escape of any contaminants  beyond
the containment  boundary  of a land disposal facility.  The type and
magnitude  of  release  depends  upon  the presence of a liner system,  the
type  of  liner employed,  the presence  and efficiency of a leachate
collection  system,  and the occurrence and magnitude of any system
failures.   Table 5-3  lists some of the factors affecting leachate  release
from  a land disposal  site.
                                     -66-

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TABLE 5-2    FACTORS AFFECTING  LEACHATE  CONSTITUENT  CONCENTRATIONS
       Major Conponents
                                 Primarv  Factors
                                                              Secondarv Factors
    Waste Composition
    Physicochemical
    Properties
    Contact Time
    Chemical Reactions
    and Interactions
    Chemical Reactions
    and Interactions
    (continued)
Volume

Constituents
Constituent
Concentrations

Solubility


Mobility


Persistence
                              Volatilization
Phase/State

Conditions of Waste
Environment
     Facility Age
Hvdrolysis
                              Oxidation
                              Reduction
                              photolysis
                              Microbial Degradation
 Microbial Acclimation

 Changes  in Waste
 Environment
pH; temperature;  composition of
liquid phase

Viscosity;  temperature; density;
sorption;  complexation

?H; temperature;  presence of catalysts;
chemical degradation (e.g. oxidation,
reduction,  hydrolysis, photolysis);
biological  degradation

tugacity;  constituent vapor pressure;
temperature

Temperature; pressure

Flow rates through wastes, fill
materials and drain layers; waste
permeability; waste porosity;
particle size: site heterogeneities:
capillary action; piping through
wastes: ponding in waste cells:
plugging of pore spaces

pH; temperature; soil pH,  catalysts
                         Presence and  type  of  oxidants:
                         catalysts:  oxygen  concentration; pH:
                         temperature

                         Oxygen concentration;  conpiexation
                         state; concentration  and type of
                         reducing agents: pH;  temperature

                         Solar radiation; transmissivity 01
                         water: presence of sensitizens and
                         quenchers

                         Microbial population;  soil aoisture
                         content; temperature;  pH, oxygen
                         concentration,  redox  potential
                                                       oh: temperature;  removal  of nost
                                                       soluble constituents
                                            -67-

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      TABLE  5-3     FACTORS  AFFECTING LEACHATE  RELEASE
  Major Components
                             Primary Factors
                                , Secondarv  Factors
Synthetic Liners
Physical Factors
                          Chemical Factors
Clav Liners
                          Leachate Collection
                          Phvsicochemical Factors
                          Chemical Factors
                          Phvsical Factors
                          Biological Factors
                          Leachate Collection
                         Aging:  human  activities; internal
                         loading stresses:  hydrogeology;
                         bathtub effect;  weather resistence;
                         deep root growth,  burrowing animals;
                         installation  and design problems
                         (e.g., subsidence from  improper
                         siting, improperly prepared seams);
                         uplifting by  gasses or liquids
                         under pressure;  impingment rate;
                         temperature

                         Chemical disintegration; weather,
                         ultraviolet radiation, chemical
                         and microbial attack from the soil
                         atmosphere; waste-linear compata-
                         bility: nature soil chemistry; pH,
                         temperature

                         Efficiency, maintenance; design

                         Chemical dehydration,  flocculation/
                         dispersion, alteration of shrink/
                         swell properties;  soil piping;
                         leachate characteristics; pore size
                         distribution

                         Dissolution of c.hemicai species,
                         adsorpsion properties; chemical
                         disintegration, native  soil chemistry-

                         Internal loading stresses; dehydration;
                         hydrogeology; weathering; erosion:
                         bathtub effect;  aging; iapingner-t
                         rate; hydraulic head:  structural and
                         design considerations  (e.g., proper
                         siting and design to handle
                         differential  subsidence

                         Microbial population;  burrowing
                         animals; deep root growth, human
                         activities

                         Efficiency; maintenance; design
                                     -68-

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    Prediction of leachate releases involves the estimation of leachate
quantity escaping from the site over time, which is combined with
constitutent concentration.  The major drawbacks in predicting releases
are obtaining realistic estimates of liner lifetime, estimating the
probability of liner failure, and establishing cause and magnitude of
failure if it occurs.  The methods employed to predict releases parallel
those used to estimate flow rates through cover liners (described
previously as part of the water balance approach).
5.1.2  Selected Release Rate Models
    Five release rate models and one series of simple calculations chosen
for their potential applicability to Wisconsin zone of saturation
landfills are discussed below and summarized  in Table 5-4.
    DRAINMOD  (1980) is a computer model developed  to predict  the response
of water in both the unsaturated and the  saturated zones  to rainfall,
evapotranspiration, specified levels of surface and subsurface drainage,
and the use of water table control or  subirrigation practices.  DRAINFIL
(1982) is an  adaptation of DRAINMOD for landfills  which  considers
drainage from a  sloping layer underlain by  a  tight clay  liner and  seepage
through the cap.  DRAINFIL can  also quantify  drainage to the  leachate
collection system and through the underlying  clay  liner  during the time
the landfill  is  open.  A water  balance for  the  soil water profile  is used
to calculate  the infiltration rate, vertical  and  lateral drainage,
evapotranspiration,  and distribution of  soil  water in the soil profile
using  approximate solutions  to  nonlinear  differential equations.   The
prohibitive cost of  using  numerical methods to  finding  solutions  to
equations of  this sort  requires that  approximate  methods be used.   Checks
of solutions  obtained  through  these methods suggest,  however, that
satisfactory  results  can  be  consistently obtained.
    The minimum data required  for  these models  include  precipitation
 (amount,  distribution,  intensity,  and duration),  water  table elevation,
daily  potential evapotranspiration (PET), net solar radiation,
temperature,  humidity,  wind velocity,  soil moisture content,  soil profile
                                     -69-

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                                 TABLE 5-4
                            RELEASE RATE MODELS
MODEL

DRAINMOD/
DRAlNKiL
HELP/
HSSWDS
LSIPE
PCLTF
LTTM
 Release
 Rate
 Computa-
 tions
ADVANTAGES

Predicts response
of water in un-
saturated zones
to rainfall

Requires minimum
amount of data.
Estimates vertical
and lateral
percolation.

Evaluation
efficiency of
liner design in
controlling
leachate release.
Addresses  all
necessary  to predict
a mass load release.

Accounts for
moisture content
of wastes  and  fill
material.  Includes
both  gravitational
and capillary  forces,
Simple and easy to
use.

A  series of simple
calculations
DISADVANTAGES

High cost
Ignores rainfall
intensity, duration,
and distribution.
Accuracy is
questionable

Estimates release
in a single
modular waste cell.
Based on assump-
tions of good
engineering design
(rare in older
landfills)

Unsaturated zone
Currently being
developed.  All
elements have not
been  tested.
REFERENCE

Skaggs (1982)
Perrier and
Gibson (1980)
                                                             Moore (1980)
 Some  assumptions
 are questionable.
                                                             U.S. EPA (1982)
Pope-Reid Assoc.
(1982) (Unpub.)
 SCS  Engineers
 (1982)
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depth, surface compaction, vegetation, depth of root zone, hydraulic
conductivity (saturated and unsaturated), and pressure head.  Host of the
data are readily available, though some difficulty may exist in obtaining
reliable unsaturated hydraulic conductivity and pressure head data.  In
addition, to simplify calculations, the models assume:
    •  One-dimensional, saturated flow in the bottom liner.
    •  Infiltration rates for uniform deep soils with constant initial
       water content expressed in terms of cumulative infiltration alone,
       regardless of the rate of application.
    •  Drainage is limited by the rate of soil water movement to the
       lateral drains and not by the hydraulic capacity of the drain
       tubes or outlet.
    DRAINMOD is currently being used  in assessing agricultural drainage
systems and has been field-verified in a variety of locations.  DRAINFIL,
however, has not yet undergone the final changes needed for its use in
assessing infiltration at waste disposal sites, and therefore remains
untested.
    These models are similar to other release rate models  in that  they
use a water balance approach, do not consider leachate constituent
concentrations, and do not consider any processes occurring within the
waste cell that may affect leachate quantity or quality.   Some unique
features of DRAINMOD/DRAINFIL are their ability to predict the upward
movement of water, and the precision of their hydraulic head estimates.
Hydrologic Evaluation of Landfill Performance (HELP/HSSWDS)
(Perrier and Gibson. 1980)
    The hydrologic evaluation of landfill performance  (HELP, formerly
HSSWDS) is a one-dimensional, deterministic water balance  model modified
and adapted from the CREAMS  (Chemical Runoff and Erosion  from
Agricultural Management Systems) soil percolation model for use in
estimating the amount of water that will move through various landfill
covers.  This model can simulate daily, monthly, and  annual values  for
runoff, percolation, temperature, soil-water characteristics, and
                                     -71-

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evapotranspiration with a minimum of data (e.g., percipitation, mean
temperature, solar radiation, leaf area index, and characteristics of the
cover material).  Should data be unavailable, the model provides default
values for such parameters as soil-water characteristics, precipitation,
mean monthly temperature, solar radiation, vegetative characteristics and
climate based on the location of the site.  The model is portrayed by its
developers as "no more complex than a manual tabulation of moisture
balance."
    The HELP model ignores rainfall intensity, duration, and distribution
and considers only mean rainfall rates, which could  somewhat limit the
accuracy of the estimates.   It also does not evaluate leachate quality.
However, it can estimate percolation through up to eight drainage layers
including through the waste  cell itself, and estimate lateral  drainage
through any or all of these  layers.  Some other features of the HELP
model  include the ability to provide estimates  of the impingement rate  of
leachate entering the bottom liner collection system, predict  the seepage
rate through a saturated clay liner, and estimate evapotranspiration and
runoff using a minimum of data.
    The HSSWDS model has been successfully  field verified  by Gibson and
Malone (1982) and many others.  Those  HSSWDS  users  contacted for  comments
and opinions believed that HSSWDS was  very  useful  in comparing sites or
cover  designs, but that  the  accuracy or validity of  the outputs could  not
be determined.  HELP  is  currently undergoing  refinement and has not  yet
been tested.
Landfill and Surface  Impoundment Performance  Evaluation (Moore. 1980)
    The Landfill  and  Surface Impoundment  Performance Evaluation (LSIPE)
model  attempts  to determine  the  adequacy  of designs  of  hazardous  waste
surface impoundments  and landfills  in  controlling  the amount of fluid
released to the environment. LSIPE utilizes  a  series of linearized
equations  and  simplified boundary  conditions  to evaluate the efficiency
of a proposed  liner design  in  terms of:
                                     -72-

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    •  Horizontal flow through sand and gravel drain layers.
    •  Vertical flow through low permeability clay liners.
    •  Efficiencies of liner-drain layer systems.
    •  Seepage through the bottom liner.
    LSIPE has the advantage of allowing for nonlinear equations and more
complex boundary conditions to be employed if needed.  Only transport of
liquids through a single modular waste cell can be estimated; however,
modules can then be arranged in the proposed configuration for analysis.
The LSIPE approach also possesses the unique capability of allowing for
leachate releases to be measured indirectly through the efficiency of the
leachate collection system.
    In order to provide estimates of the above mentioned  parameters, this
approach requires:
    •  Liquid routing diagram for the site.
    •  Water balance for the site.
    •  Slopes in the routing system.
    •  Hydraulic conductivities.
    •  Service life of any synthetic liners.
    The LSIPE model also makes the general assumption that  the operating
conditions for a waste landfill or surface impoundment meet  the basic
requirements of good engineering design,  including:
    •  Surface water runon has been  intercepted  and  directed away  from
       the site so that only the rainfall  impinging  directly on the
       landfill needs  to be accounted  for.
    •  Proper precautions have been  taken  to  prevent erosion of the  cover
       soils which would degrade cover  performance.
    •  Synthetic  liners have been  installed properly to  ensure their
       integrity  for design life.
                                     -73-

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Post-Closure Liability Trust Fund Model (PCLTF) (U.S. EPA 1982)

    This model is being developed to assess the adequacy of the

Post-Closure Liability Trust Fund established as the result of the

passage of CERCLA in 1980.  The fund will provide for liability claims

resulting from failure of RCRA permitted sites after proper closure.  The

analytical approach involves:

    •  Assessing failure probabilities of facilities.

    •  Determining environmental exposure.

    •  Assessing damage potential.

    •  Quantifying damages, and assessing costs for  clean-up, remedial
       action, damage to natural resources, personal injury and economic
       loss.

    PCLTF is the only model reviewed which  addresses all three components

necessary to predict a mass load release from a land disposal site.  The

model can be applied to open or closed facilities with  both clay and/or

synthetic liners.  The user can specify one of seven generic site types

from a variety of cover and bottom  liner and leachate collection

configurations.  The components of  the model  consists  of:

    •  User-supplied inputs which characterize the site design and
       operation, and identify the  wastes placed within the fill.

    •  A data base of physical and  chemical characteristics of waste
       constituents which relate to their solubility, toxicity,
       persistance, and mobility as well as their effect on synthetic
       liner performance.

    •  A data base of climate, soils, and the geology of various regions
       of the U.S.

    •  A baseline analysis with which to set  initial site  conditions.

    •  Water movement simulation which uses Monte Carlo simulation
       techniques to generate values for seepage velocity, effective
       porosity, dispersion, and liner failure to route leachates through
       the layers of the landfill,  including  liners  and drain  layers.
       Adjustments to leachate quantity are made based  on  moisture
       content of wastes and fill materials.
                                     -74-

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This model's output is a two-dimensional, uniformly distributed, leachate
discharge estimate (concentration and flux)  to the unsaturated soil
column beneath the site.  The output provides the source term for a mass
transport module for the unsaturated zone.
Leachate Travel Time Model  (LTTM) (Pope-Reid Associates. 1982)
    The Leachate Travel Time Model  (currently under development by
Pope-Reid Associates) combines  several  analytical techniques and
previously developed models to  evaluate the  performance of landfills of
various designs in a variety of climatic settings.  The model consists of
a monthly, quarterly, or annual hydrologic and waste  budget which is used
to calculate leachate volume in the active fill  area,  leachate head in
drain layers, containment time  and  seepage rate  through the bottom liner,
and travel time and seepage rate in the unsaturated zone below the
landfill.  The model possesses  the  unique feature of  accounting for the
moisture content of wastes  and  fill materials.   Actual measured values or
estimations of moisture content can be  input.  Also,  the model  includes
both gravitational and capillary forces to calculate  seepage  rates
through liners.
    The Leachate Travel Time Model  does not  include  a specific  cover
liner option, although the  user can incorporate  a cover  liner by  altering
the hydrologic budget.  Like other  models, the  current program  does not
address constitutent concentrations of  contaminant mass  transport, but
the authors do intend  to  incorporate constituent transport in the
future.  The model does,  however, address both  leachate  generation and
release in  a relatively  simple  and  easy-to-use  program which  incorporates
many  interesting features.
Release Rate Computations  for  Land  Disposal  Facilities (SCS Engineers.
1982)
    This approach  consists  of  a series  of simple calculations to  predict
the quantity of leachate  generated  and released from landfills  and
surface  impoundments which  will be  incorporated into EPA's RCRA Risk/Cost
                                     -75-

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Policy Model Project (ICF Incorporated, Clement Associates, Inc., and SCS

Engineers, Inc., 1982).  The approach assumes that:

    •  Synthetic liners last for 20 years, after which liquid moves
       freely through them.

    •  Clay liners retain their integrity for longer than 100 years.

    •  The only sources of liquids are infiltration from the surface and
       free liquids in waste.  Only saturated flow takes place through
       the liner in the absence of free liquids.

    •  Infiltration through the cover system after closure is less than
       or equal to leachate movement through the liner system.

    •  Synergistic effects do not occur.

    The time required for leakage to appear beneath the bottom of a clay

liner is given by:


    t = T*d2/4D

where:

    t = time to first appearance of leakage (sec)

    d = thickness of clay liner (cm)
                                            2
    D = linearized diffusivity constant,  (cm /sec) assumed to be
          5   2
        10  cm /sec.

    The volume of leachate release over time is given by:
    q = Ks(dh/d )A(At)
               z
where:
    q  = volume of leachate released over time

    Ka = saturated permeability coefficient

    dh = hydraulic gradient

    dz
    A  = Area at base of facility
    At = length of time over which leachate  releases.
                                    -76-

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5.2  Solute Transport Models
    Once the quantity and quality of a release from a land disposal site
has been determined, this estimate can be used as the input for a solute
transport model.  Solute transport models predict the migration of
chemical constituents away from a source over time in one, two, or three
dimensions.  A brief discussion of the principles used in transport
modeling and descriptions of several transport models are contained in
the following sections.
5.2.1  Fundamentals
    The transport models presented in this  section are all mathematical
models, rather than rating or  ranking type  models  (e.g.,  the MITRE
Model).  The mathematical approach to modeling  involves  applying a set of
equations, based on explicit assumptions, to describe the physical
processes affecting pollutant  transport  from a  site.  These models can be
divided into two types—deterministic and stochastic.  Deterministic
models attempt to define the shape and concentration of  waste migration
using the physical processes (e.g., groundwater  flow) involved, while
stochastic models attempt to define causes  and  effects using probablistic
methods.  Models presented in  this report are generally  deterministic.
    Deterministic mathematical models can be further divided into
analytical models and numerical models.  Analytical models  simplify
mathematical equations, allowing  solutions  to be obtained by analytical
methods (i.e., function of real variables). Numerical models,  on  the
other hand, approximate equations  numerically and result in a  matrix
equation that  is usually solved by computer analysis.  Both types  of
deterministic models  address a wide  range of physical  and chemical
characteristics but  the analytical models usually simplify  the
characteristics by  assuming  steady state conditions.   The physical and
chemical characteristics considered  by  these models  include:
    •  Boundary Conditions—hydraulic head  distribution, recharge and
       discharge points, locations and  types  of boundaries.
                                     -77-

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    •  Material Constants — hydraulic conductivity, porosity,
       transmissivity, extent of hydrogeologic units.
    •  Attenuation Mechanisms — adsorption-desorption, ion exchange,
       complexing, nuclear decay, ion filtration, gas generation,
       precipitation-dissolution, biodegradation, chemical degradation.
    •  Hydrodynamic Dispersion — diffusion and dispersion (transverse and
       longitudinal) .
    •  Waste Constituent Concentration — initial and background
       concentrations, boundary conditions.
    Both mathematical model types incorporate two sets of equations to
define transport; a groundwater flow equation and a mass transport
equation.  Figure 5-1 illustrates the relationship between these
equations.
    A general form of the water momentum balance equation for
nonhomogeneous anisotropic aquifers (Pope-Reid Associates (1982)) is:
        a   ,„   ah  .    0 ah
        IT (Kij 1x7 > - s IT + w
where:
    h = hydraulic head
    K = hydraulic conductivity
    S = storage coefficient
    W = volume flux per unit area (e.g., pumping or injection wells,
        infiltration, leakage)
    z = distance
    t = time
The Darcy equation is generally represented as:
         V. =
          i
where:
    V = groundwater velocity
    n = porosity
    K = hydraulic conductivity
                                    -78-

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             Mass Transport
               Eauations
Groundwater Flow
   Equations
              Mass Balance
              for Chemical
                Species
     Water
   Momentum
    Balance
                                                     Darcv's
                                                    Equation
                                 Transport
                                 Eauation
Figure 5-1.   Major Components  of Groundwater Transport Equation
             (after Mercer and Faust,  1981)
                                 -79-

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    The mass transport side of the model, which describes the
concentrations of a chemical species in a flow pattern in general form is:
    ac    a         ac      a          cfw
    tt - ^7 (Dij •  ^ - aT7 (CV - V + R
where:
    C' = concentration of solute in the source or sink fluid
    C  = chemical species concentration
    D  = dispersion tensor (i.e., hydrodynamic dispersion)
    V  = groundwater velocity (i.e., convection transport)
    R  = rate of chemical species attenuation/transformation
    These equations are coupled to provide predictions of solute
transport in the groundwater system with chemical reactions considered.
For analytical models, these equations are simplified to explicit
expression.  For either type of model, a sensitivity analysis of model
results can be performed by varying the input characteristics singularly
or in combination.  One type of sensitivity analysis that could be
performed involves changing single parameters (within known values of
occurrence) to demonstrate the effects that variations in individual
parameters have on model output.  This analysis helps identify those
parameters which have the greatest influence on model results.  A second
type of sensitivity analysis involves a series of trial runs of the model
using an array of input parameters which vary in accordance with the
expected errors associated with each parameter (i.e., Monte Carlo
simulation techniques).  This method provides a general assessment of the
overall model sensitivity and intrinsic precision by providing a range of
variations of the model outputs as a function of the error bars
associated with the input parameters (e.g., mean values, maximum values,
minimum values).
5.2.1.1  Analytical Models
    Analytical models provide estimates of waste constituent
concentrations and distributions using simplified,  explicit expressions
                                     -80-

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generated from partial differential equations.  The mathematical
expressions are usually simplified by assuming steady state conditions
relative to fluid velocity, dispersion dynamics, and other physical
parameters.  For example, groundwater flow equations can be simplified if
the aquifer is assumed to have infinite extent.  Governing equations
characterize both groundwater flow and mass transport, and may also
address dilution, dispersion, and attenuation.  These models can simulate
plume migration from the source to a utilized groundwater system allowing
for attenuation and dispersion.  The method provides a quick and
inexpensive solution with minimal amounts of data as long as the
simplifying assumptions do not render results invalid.
5.2.1.2  Numerical Models
    Numerical models characterize groundwater contamination processes
without the simplification of complex physical and chemical
characteristics required by analytical models.  The numerical models
reduce the partial differential equations to a set of algebraic equations
that define hydraulic head at specific points (i.e., grid points).  These
equations are solved through linear algebra using matrix techniques.
    The numerical methods most commonly used to simulate groundwater
transport problems can be divided into four groups:  finite difference

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form a matrix equation which is solved numerically.  The FE method is
better suited for solving complex two- and three-dimensional boundary
conditions than the FD method.  When using FD or FE methods for solving
contaminant transport problems, results are subject to numerical
dispersion or numerical oscillation.  Numerical dispersion causes answers
to be obscured because of accumulated round-off error at alternating time
steps.  Numerical oscillation causes answers to overshoot and undershoot
the actual solution at alternating  time steps.  Numerical oscillation is
generally associated with FE methods, while numerical dispersion is
generally associated with FD methods.
    The method of characteristics and discrete parcel random-walk models
were developed to minimize  the  numerical  difficulties associated with the
FE and FD methods.  Both the method of  characteristics  (MOO and discrete
parcel random walk method analyze temporal  changes in concentrations by
tracking a set of reference points  that flow with  the groundwater past a
fixed grid point.  In the HOC method, points  are placed in  each  finite
difference block and allowed  to move in proportion to the groundwater
velocity at  the point and the time  increment.  Concentrations  are
recalculated using summed particle  concentrations  at the new locations.
The random-walk method varies  from  the  HOC method  because,  instead  of
solving the  transport equation, a random process  defines dispersion.
Reference points move as  a  function of  groundwater flow, consistent with
a probability  function related  to groundwater velocity  and  dispersion
(longitudinal  and  transverse).   The methods provide comparable results
but the HOC  method  is time  consuming,  expensive,  and requires
considerable computer  storage.
5.2.2   Selected  Solute Transport Models
    Eight  analytical models and nine numerical models are  presented in
the following  sections.   Each has characteristics that make it unique;
therefore,  selection of  a model should be based on making the  best use of
available  data given the desired output.  These models are summarized in
Table 5-5.
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                       TABLE 5-5  SOLUTE TRANSPORT MODELS
  MODEL

(Analytical)

SESOIL
PESTAN
PLUME
Leachate
Plume
Migration
Model
Cleary
Model
ADVANTAGES
"User-friendly",
addresses numerous
processes.
Calculates pollutant
velocity, length of
pollutant slug,
contamainant concentra-
tions.  Easy to use,
inexpensive, can be
used as a screening
model.  Can be coupled
with PLUME.

A  saturated zone model.
Provides 2-dimension-
al plume traces.
DISADVANTAGES
Field and analytical
verifications not
yet performed.
Designed for un-
saturated zone
simulations.

One dimensional
through un-
saturated zone.
                                                               REFERENCE
Bonazountas and
Wagner (1981)
Enfield, et
al., (1982)
Effects of adsorp-
tion  and degreda-
tion  ignored  in
testing.
Predicts  plume  migra-
tion  and  mixing in
saturated zone.
Methods of use  are
simplified.

10 different models using a variety
of boundary conditions.   Little
 information available.
                                                               Wagner (1982)
                       Kent, et al.,
                       (1982)
                       Cleary
                       (1982)
                                     -83-

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                 TABLE 5-5  SOLUTE TRANSPORT MODELS (Continued)
  MODEL

(Analytical)

AT123D
Screening
Procedure
PATHS
ADVANTAGES
Estimates waste trans-
port in saturated and
unsaturated zones.
Computer coded,
available, valuable
for preliminary
assessments.

Assesses transport
and degradation
in saturated  zone
of specific chemicals.
Provides quantitative
and qualitative
screening based on
estimates of  exposure.

Used for saturated
flow.   Estimates
single  contaminant
transport.  Fast,
inexpensive.
DISADVANTAGES
Appears to have
not been field
verified.
                                                               REFERENCE
Yeh (1981)
Does not address
synergistic effects.
Unpublished and not
available to public.
Falco, et.
al. (1980)
 Ignores  dispersion
 effects.  Has not
 been  field verified
 Nelson  and
 Sheen  (1980)
 (Numerical Models)

 MMT/VTT/       Used  for  saturated or
 UNSAT  I D      unsaturated  zone.
               Computer  package
               available for
               graphic displays.
                          As with all
                          numerical models,
                          costs are high as
                          are requirements
                          for accurate
                          geohydrologic data.
                       Battelle
                       (1982)
                                     -84-

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                 TABLE 5-5  SOLUTE TRANSPORT MODELS (Continued)
  MODEL
ADVANTAGES
DISADVANTAGES
                                                               REFERENCE
(Numerical Models)
CFEST/
UNSAT ID
Pollutant
Movement
Simulator
FEMWASTE
Random Walk
Solute
Transport
Model
SWIFP
 Solute
 Transport/
 Groundwater
 Flow Model

 Leachate
 Organic
 Migration
 and Attenua-
 tion Model
CFEST predicts fluid
pressure, temperature,
and contaminant con-
centrations in
saturated zone.

Three-dimens ional
model for coupled
saturated-unsaturated
zone.

Two-dimensional model
for coupled saturated-
unsaturated zones.
Utilizes FEMWATER.

Saturated zone model.
Concentrations can be
specified in  any segment
of model.  Documented,
available to  public,
and verified.
Saturated  zone models
three-dimensional.  Field
and  analytically  verified,
well documented.
Presently being field  Battelle
verified.  Model       (1982)
documentation in
preparation.
Has not been
tested for
landfills.
Khaleel and
Reddell,
                                                               Yeh (1981)
                       Prickett,  et
                       al., (1981)
                                                               USGS (1982)
 Saturated zone.
 Analytically and
 field verified.
 Coupled saturated-
 unsaturated zones.
 Specifically designed
 for landfills.
                                         Ignores  dispersion.
 Currently  being
 revised.
                       Colder
                       Associates
                       (1982)
 Sykes, et
 al.  (1982)
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5.2.2.1  Analytical Models
    The eight analytical models characterized in this section do not
address cases involving secondary porosity, immiscible liquids, or more
than one contaminant.  Only one model, AT123D developed by G.T. Yeh
(1981), considers both the saturated and unsaturated hydrologic zones;
the other models are restricted to modeling only one hydrologic zone.
SESOIL (Bonazountas and Wagner. 1981)
    SESOIL, a seasonal soil compartment model, was developed by A.D.
Little Inc. for the U.S. EPA Office of Toxic Substances.  The model is
described as a "user-friendly" statistical/analytical mathematical model
designed for long term environmental pollutant fate  simulates.
Simulations are performed for the unsaturated zone and  are based on a
three-cycle rationale—the water cycle, the  sediment cycle, and the
pollutant cycle.  SESOIL addresses  numerous  processes  including
diffusion, sorption, chemical degradation, biological  degradation,  and
the complexation of metals.  The model  is  presently  being updated  and  is
available for limited use although  field or  analytical  verifications have
not yet been performed.
PESTAN  (Enfield. et  al.. 1982)
    PESTAN was developed at  the EPA Robert S.  Kerr Environmental Research
Laboratory.  The model calculates  the movement  of organic  substances  in
one dimension through the unsaturated  zone based on  linear  sorption and
first  order degradation  (i.e., hydrolysis  and biodegradation).
Calculated outputs  include  pollutant  velocity,  length  of the  pollutant
slug,  and contaminant concentrations.    Pollutant application rates to
the soil surface can be  changed  to determine the effect of the number of
applications, application  period,  and number of days before
reapplication.  This model  is  best classified as a screening  model
because it provides  for  a  rapid  evaluation of chemicals without the
sophistication  of  numerical models.  The model is also easy to use and
inexpensive.  PESTAN can be coupled with PLUME,  a saturated zone
analytical model.   PESTAN  has  been field verified for the chemicals DDT
and Aldicarb, and  the model is being used by EPA-Athens.
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PLUME (Wagner. 1982)
    PLUME is a steady state analytical model developed at Oklahoma State
University to model contaminant transport  in the saturated zone.
Themodel provides two-dimensional plume traces from a continuous source
and allows for first order degradation and linear sorption (i.e., organic
pollutants) with dispersion.  The model was verified using a case history
of groundwater contaminated with hexavalent chromium, although the
effects of adsorption and degradation were ignored.
Leachate Plume Migration Model  (Kent, et.  al. 1982)
    The Leachate Plume Migration Model was developed as  an analytical
technique for the hazard evaluation  of existing  and potential, continuous
source waste disposal sites by  predicting  plume  migration and mixing in
the saturated zone.  Predictions can be made  from nomographs, hand-held
calculators, or a large scale computer.  The  model allows for degradation
(i.e., radioactive  and biological) of constituents and  for the effects of
dispersion and diffusion.  The  predictive  methods presented  are
simplified so that  a strong background  in  mathematics  and computer
programming are not required  for their  use.   The model  has been  verified
using data from a chromium plume at  Long  Island  and  is  presently being
tested against other case studies.
Clearv Model  (Clearv. 1982)
    The Cleary Model consists  of ten different  analytical models that
describe mass transport  and  groundwater flow, with  dispersion,  under  a
variety of boundary conditions. The model addresses  conservative
constituents  (i.e., without  degradation).   The  ten  available models are:
    •  1-dimensional, mass  transport;  1st type  boundary conditions.
    •  1-dimensional, mass  transport;  3rd type boundary conditions.
    •   2-dimensional, mass  transport;  strip boundary, finite width.
     .   2-dimensional, mass  transport;  strip boundary, infinite width.
     •   2-dimensional,  mass  transport;  Gaussian source,  infinite width.
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    •  3-dimensional, mass transport; patch source, finite dimensions.

    •  3-dimensional, mass transport; 5 area Gaussian source.

    •  2-dimensional, groundwater flow; infinite dimensions, recharge
       boundary.

    •  2-dimensional, groundwater flow; finite dimensions, recharge
       boundary.

    •  2-dimensional, groundwater flow; infinite dimensions, no recharge.

These models were not available for review and R. Cleary  (developer)

could not be contacted; information concerning these models was,

therefore, very limited.

AT123D (Yeh. 1981)

    AT123D, developed by G. T. Yeh at Oak Ridge National  Laboratory, is a

generalized transient, one-, two-, or three-dimensional analytical

computer model for estimating waste transport in both the unsaturated and

saturated zones.  The model is flexible, providing 450 options: 288 for

the 3-dimensional case; 72 for the 2-dimensional case in  the x-z plane;

72 for the 2-dimensional case in the x-y plane; and 18 for  the

1-dimensional case in the longitudinal direction.  AT123D models all of

the following options:

    •  Eight sets of source configurations  (i.e., point source; line
       source parallel to x-, y-, or z-axis; area source  perpendicular to
       the x-, y-, or z-axis; and a volume  source).

    •  Three kinds of source releases  (instantaneous, continuous,  and
       finite duration releases).

    •  Four variations of the aquifer dimensions (finite  depth  and width,
       finite depth  and infinite width, infinite depth and  finite  width,
       infinite depth and infinite width).

    •  Modeling of radioactive wastes, chemicals, and head  levels.
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The transport mechanisms addressed are advection, hydrodynamic
dispersion, adsorption, decay/degradation, and waste losses to the
atmosphere from the unsaturated zone.  The model is computer coded and
publicly available, making it a potentially valuable tool for preliminary
assessment of waste disposal sites.  Fifty sample problems (simulations)
have been performed but actual field verification appears to be lacking.
Screening Procedure (Falco et al.. 1980)
    A screening procedure for assessing the transport and degradation of
solid waste constituents in the saturated zone as well as surface waters
was developed by Falco et al., (1980).  The procedure estimates the
movement and degradation of chemicals released from landfills and lagoons
based on the physical and chemical properties of the compound and a
defined range of environmental conditions that the compound would be
expected to encounter in groundwater.  The procedure developed involves
two parts, a mathematical model to obtain quantitative estimates of
exposure and a logic sequence that assigns qualitative descriptors of
behavior (e.g., low, significant, high) based on the quantitative
estimates of exposure.  Quantitative estimates are based on hydrolysis,
biological degradation, oxidation, and sorption.  The results of using
this procedure indicate that it provides a means of qualitatively
screening organic chemicals when specific process rates are available.
PATHS (Nelson and Schur. 1980)
    The PATHS groundwater model is a hybrid analytical/numerical model
for two-dimensional, saturated groundwater flow that estimates single
contaminant transport under homogeneous geologic conditions.  The model
also considers the effect of equilibrium ion exchange reactions for a
single contaminant at trace ion concentrations.  Dispersion effects are
not considered by the model.  The model provides a fast, inexpensive,
first-cut evaluation consistent with the amount of field data usually
available for a site.  Analytical verifications have been performed but
field verifications have not.
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5.2.2.2  Numerical Models
    The nine numerical models characterized in this section generally
address the following characteristics:
    •  Coupled saturated/unsaturated zones.
    •  Primary porosity.
    •  Heterogeneous, anisotropic aquifers.
    •  Miscible constituents.
    •  Dispersion.
    •  Attenuation/degradation.
    This group of models represents the most  flexible  approach to
modeling a wide range of hydrogeologic conditions  and  contaminant types
because the governing equations  are not simplified as  they are for the
analytical models.  These models  generally involve greater costs and
require accurate geohydrologic data for a  given  site.
MMT/VTT/UNSAT1D (Battelle.  1982)
    MMT (Multicomponent Mass  Transport) is a  one-  or  two-dimensional mass
transport code for  predicting the movement of contaminants  in the
saturated or  unsaturated zone.   The MMT model utilizes the discrete
parcel random-walk  method and was originally  developed to simulate the
migration of  radioactive contaminants.  The model  accounts  for
equilibrium sorption,  first-order decay and n-members  radioactive decay
chains.  A velocity field  (i.e.,  groundwater  flow equations) must be
input  to the  model  and this is generally  accomplished by coupling with
the VTT  (Variable Thickness Transient) model  for the  saturated  zone  and
UNSAT1D  (One-Dimensional Unsaturated  Flow) model for  the unsaturated
zone.  A computer package  facilitates interpretation  of results  by
providing  graphic data displays. The model has  been  used at the Hanford,
Washington,  site  to predict tritium concentrations.
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CFEST/UNSAT1D (Battelle. 1982)
    CFEST (Coupled Fluid Energy and Solute Transport) predicts fluid
pressure, temperature, and contaminant concentrations in saturated
groundwater systems.  Coupling the model with UNSAT1D allows for modeling
the unsaturated zone.  The model applies finite element techniques to
solve equations.  The flow system may be complex, multi-layered,
heterogeneous and anisotropic with time-varying boundary conditions and
time-varying areal sources and sinks.  Sorption and  contaminant
degradation are presently being incorporated  into the model.  The model
is presently being field verified for EPA  at  the Charles City, Iowa, site
for arsenic and pharmaceutical chemical waste (organics).  Model
documentation is in  preparation.
Pollutant Movement Simulator  (Khaleel and  Reddell.  1977)
    The Pollutant Movement Simulator  is a  three dimensional model
describing the two-phase  (air-water)  fluid flow equations  in  a coupled
saturated-unsaturated porous  medium.  Flow equations are  solved by  finite
difference methods.  A  three  dimensional  convective-dispersive equation
was also developed to describe the movement of a  conservative,
noninteracting tracer  in  nonhomogeneous,  anisotropic porous medium.
Convective-dispersive equations  are  solved by the  method  of
characteristics.  Attenuation processes have been  incorporated  into the
model  since  its original  release.  The model has  been tested  for  salt
(NaCL) movement in  sample  plots  and  is  presently  being used  in  coal mine
contamination studies.
FEMWASTE  (Yen. 1981)
    FEMWASTE, developed by G. T.  Yeh at  Oak Ridge National Laboratory,  is
a two  dimensional,  finite element, mass  transport model for the  coupled
saturated-unsaturated hydrologic zones.   This model utilizes  FEMWATER,
also developed by Yeh,  to provide the groundwater flow field allowing  for
a variety  of  boundary conditions and initial moisture conditions.
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Additionally, FEMWASTE incorporates the effects of convection,
dispersion, chemical sorption and first order decay in the mass transport
equations.  FEMWASTE/FEMWATER is computer coded and available to the
public.  This model has been field verified and is presently being used
by the Carson City office of the USGS.
Random Walk Solute Transport Model (Prickett et al.. 1981)
    The Random Walk Solute Transport Model, developed by Prickett,
Naymik, and Lonnquist  (1981), predicts  the transport of chemical species
(e.g., organics, metals,  inorganics) in the saturated zone by the random
walk or particle-in-a-cell method.  Mass  transport equations  include
provisions for dispersion and chemical  reactions  (attenuation).  The
model  also accounts for time varying pumpage,  injection by wells, natural
or artificial recharge, water exchange  between  surface water  and
groundwater, and flow  from springs.  Chemical  constituent concentrations
in any segment of  the  model can be specified.   Flow  equations  are solved
by finite  difference methods.   The model  has been documented  and made
available  to the public.  Analytical  and  field (i.e.,  fertilizer plant,
Meredosia, Illinois) verifications have been  performed.
Solute Transport j.nd Dispersion Model  (Konikow and Bredehoeft.  1974)
    The Solute Transport  and  Dispersion Model  simulates  the movement of
conservative chemical  species  in a two dimensional,  coupled
unsaturated-saturated  hydrologic zone.   Flow equations are  solved using
the finite difference  method  while mass transport equations  are solved by
the method of  characteristics.   The  model allows  for the incorporation of
pumping or recharging  wells,  diffuse infiltration, and for  varying  the
transmissivity,  boundary  conditions,  contaminant  concentrations,  and
saturated thickness.   Analytical and numerous field verifications have
been  performed for the model  (e.g.,  Hanford Reservation, Washington for
radioactives;  Rocky Mountain  Arsenal,  Colorado for pond leachate).
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SWIFF (USGS. 1978)
    The SWIFP model simulates the movement of nonconservative
constituents through the saturated zone in three dimensions.  The model
incorporates dispersion processes and also allows for deep well injection
predictions.  Flow and transport equations are  solved by the finite
difference method.  This model  is well documented and maintained, and has
been field and analytically verified.  Presently field verifications are
being performed in New Jersey for sea-water  intrusion, in Carson City for
geothermal transport, and  in Minnesota for coal tar  residues.  A version
of SWIFP has also been developed for  the  Nuclear Regulatory Commission to
handle radioactive materials.
Solute Transport/Groundwater Flow Model  (Colder Associates. 1982)
    This model simulates the movement of  multiple  conservative
constituents without dispersion in  the saturated zone.   Flow  and mass
transport equations are solved  using  finite  element  techniques.  The
model has been analytically  and field verified.
Leachate Organic Migration and  Attenuation Model  (Svk.es  et  al..  1982)
    The Leachate Organic Migration  and Attenuation Model simulates  the
movement of  nonconservative  organic solutes  through  the
saturated-unsaturated  zone.   The model  is generally  run  in  one  or  two
dimensions  but can  be  modified  for  three dimensional analysis.   Flow and
mass  transport equations  are solved by  finite element techniques.   This
model is  specific  to  sanitary landfills  because it measures organics as
chemical  oxidation  demand, and  addresses biodegradation, adsorption,
convection,  and  dispersion processes.  The model is currently being
revised.   Field  verification has been performed for the model at the
Borden Landfill,  Ontario,  Canada for chloride  and potassium,  at granite
sites for nuclear wastes,  and for aldicarb.
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5.3  Model Limitations

    The following issues provide a context for considering the

limitations inherent in the application of models to evaluate or predict

groundwater problems.

    •  Modeling results represent approximations of the actual movement
       of contaminants and groundwater; results should be used to
       estimate the comparative magnitude of a problem and to assign
       priorities.

    •  Models should be verified against actual field observations to
       determine how closely they simulate real world situations;
       verification should be performed in the actual hydrogeologic
       system to which the model is  to be applied.

    •  Model accuracy may vary dramatically when models are applied to
       situations for which they have not been verified.

    •  Models presently do not simulate all the processes that control
       contaminant movement; the equations that describe attenuation and
       dispersion are especially weak in most models.

    •  Generally, the capacity of a  model to  simulate field situations  is
       a function of its complexity; the more complex the model, the more
       data are required.  Model reliability  becomes a function of data
       accuracy,  i.e., "garbage in,  garbage out".

    •  Models for which sensitivity  analyses  have  not been conducted may
       generated mathematical errors when parameters are changed and
       assumptions modified.

    Because of the complexity and limitations of models, assertions

determined through the use of models should not be interpreted as actual

values but only as estimates.

    For Wisconsin zone of saturation landfills, those models  which

address leachate  production, such as DRAINMOD/DRAINFIL and LSIPE, are

applicable.  LTTM may be useful when fully documented and verified.

Solute transport  models, such as SWIFP  and the Random Walk. Solute

Transport Model, may be applicable  if leachate migration from existing

landfills is detected or suspected.
                                     -94-

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                           6.0  RECOMMENDATIONS


    Zone of saturation landfills are by nature very susceptible to

contaminant releases because of the large amounts of water, both

groundwater inflows and leachate, that must be removed by the drainage

system.  If the only sites available for construction of the landfills

are in the saturated zone, the following recommendations may help limit

the probabilities of leachate release:

    •  Determine as accurately as possible the values of inflow rates (q)
       and hydraulic conductivities (K) of both landfill material and
       soils because these values have a major impact on drain system
       design, especially drain spacing.

    •  Determine the hydrogeology of the site accurately so that
       groundwater level variations throughout the year are known and
       conservative head maintenance levels can be specified (i.e.,
       always maintaining inward hydraulic gradients).

    •  Design the landfill base so that it slopes toward the drains, thus
       allowing for lower head maintenance levels and more rapid leachate
       removal.

    •  Specify low head maintenance levels within the fill, thus reducing
       the hydraulic head capable of discharging leachate  (i.e., for
       hazardous waste sites, EPA regulations require heads less than
       1-foot).

    •  Select the proper drain equation for system design  and  allow for a
       margin of error in the results obtained (i.e., design
       conservatively).

    •  Design filters  and envelopes for drain pipes  that prevent silting
       and allow for free flow of liquids.

    •  Remove daily fill covers from cells or ensure by some other means
       that the cells  are hydraulically connected to the drainage  system
       thus allowing free flow of water between  cells and  drains.
                                     -95-

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    •  Incorporate drain blankets into landfill designs to reduce head
       maintenance levels without decreasing drain spacing and improve
       the overall efficiency of leachate collection.

    •  Compact clay base and sidewall layers at optimum working moisture
       conditions so that high density, low permeability barriers are
       created without shearing or fracturing the clay.

    •  Provide construction inspections to ensure that critical
       operations such as placement of leachate collection drain and
       filter envelopes, base gradings, and clay recompaction are
       performed as specified.

    •  Design leachate collection system so that routine maintenance and
       inspections can be performed to adequately maintain flows.

    •  Provide for continuous monitoring of leachate collection volumes
       and head levels so that problems can be  identified quickly.

    •  Design landfill drainage  systems to  incorporate anticipated future
       operations such as the acceptance of large quantities of liquids.

Understanding the drain equations and  the theory behind them and

incorporating the above recommendations into  the original landfill design

can substantially reduce the chances of leachate release.  However,

unless the designs are  incorporated properly  during  construction, the

system will fail to meet its  intended  purpose.
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                            7.0  BIBLIOGRAPHY
7.1  Background

Fenn, D.G., K.J. Hanley, and T.V. Degeare.  1975.  Use of the water
balance method for predicting leachate generation from solid waste
disposal sites.  U.S.EPA-530/SW-168, Cincinnati, Ohio.  40 pp..

Fungaroli, A.A.  1971.  Pollution of subsurface water by sanitary
landfills.  U.S.E.P.A. Solid Waste Management Series, SW-12rg.  Vol. 1.
132 pp.

Fungaroli, A.A. and R.L. Steiner.  1979.  Investigation of sanitary
landfill behavior.  Volume 1.  U.S.E.P.A. 600/2-79-053a.

Gerhart, R.A.  1977.  Leachate attenuation  in the unsaturated zone
beneath three  sanitary landfills  in Wisconsin.  University of Wisconsin.
Wisconsin Geological  and Natural  History  Survey.  Info. Circular No. 3.
93 pp.

Green, J.H. et al.  1965.  Groundwater pumpage  and water level changes in
Milwaukee-Waukesha area, 1950-61.  USGS Water Supply  Paper 1809-1.

Harr, C.A., L.C. Trotta, and R.G. Borman.   1978.  Ground-water resources
and  geology of Columbia County, Wisconsin.  University  of Wisconsin -
Extension.  Geological  and Natural History  Survey.  Info.  Circular
No.  37.  30 pp.

Holt, C.L.R.,  Jr.  1965.  Geology and water resources of Portage County,
Wisconsin.  USGS Water  Supply  Paper  1796.   77 pp.

Hughes, G.M. et al.   1971.  Hydrogeology  of solid waste disposal  sites  in
Northeastern Illinois.  U.S.E.P.A.  Publication  No.  SW-12d.   154 pp.

LeRoux, E.F.   1957.   Geology  and ground water resources of Outagamie
County.  USGS  Water  Supply Paper 1604.

Newport, T.G.   1962.  Geology  and ground  water  resources  of  Fond  du Lac
County, Wisconsin, USGS Water  Supply Paper  1604.

Olcott, P.G.   1966.   Geology  and water  resources of Winnebago County,
Wisconsin.   Geological  Survey  Water Supply  Paper 1814.

Roudkivi,  A.J. and R.A.  Callander.   Analysis  of groundwater  flow.   John
Wiley and  Sons, N.Y.   214  pp.
                                       -97-

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Sherrill, M.G.  1978.  Geology and ground water in Door County,
Wisconsin, with emphasis on contamination potential in the Silurian
Dolomite.  Geological Survey Water Supply Paper 2047.

Soil Conservation Service.  1980.  Ground water resources and geology of
Washington and Ozaukee Counties, Wisconsin.  University of Wisconsin -
Extension.  Geological and Natural History Survey.  Inform Circular
No. 38, 37 pp.

Young, H.L. and Batten, W.G.  1980.  Soil Survey of Winnebago County,
Wisconsin.  U.S. Department of Agriculture.

7.2  Drains

Bureau of Reclamation.  1978.  Drainage Manual.  Water Resource Technical
Publication.  United States Government Printing Office, Washington, D.C.
286 pp.

DuPont Company.  1981.  Designing  and Constructing Subsurface Drains.
DuPont Company, TYPAR Sales, Wilmington, Delaware.

Hooghoudt, S.B.  1940.  Bijdragen  tot de kennis van  enige natuurkundige
grootheden van de grond.  No. 7.   Versl. Landbouwk.   46:515-707.

Konet, P., K.J. Quinn and C. Slavik.  1981.  Analysis of design
parameters affecting the collection  efficiency of clay lined landfills.
In:  Proceedings of Fourth Annual  Madison Conference  of Applied Research
and Practice  on Municipal and Industrial Waste.   September 28-30,
University of Wisconsin Extension, Madison,  WI.

Moore, C.A.   1980.  Landfill and Surface Impoundment Performance
Evaluation.   U.S. Environmental  Protection Agency, SW-869, Office  of
Water  and Waste Management, Washington, D.C.

Moulton, L.K.  1979.  Design of  subsurface drainage  systems  for the
control  of groundwater.  Presented at:   58th Annual  Presentation of  the
Transportation Research Board, Washington, D.C.

Powers,  J.P.  1981.  Construction Dewatering.   John  Wiley  and  Sons.   New
York.  484 pp.

Sichardt, W.  and W.  Kyrieleis.   1940.   Grundwasserabenkungen bei
Fundierunesarbeiten.  Berlin,  Germany.

Soil Conservation  Service.   1973.   Drainage  of Agricultural  Land.  Water
Information  Center,  Inc.   Syosset, New York.  430 pp.

Van Schlifgaarde,  J.   1974.   Drainage for  Agriculture.   American Society
of Agronomy  17, Madison, Wisconsin.
                                       -98-

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Wesseling, J.  1973.  Theories of Field Drainage and Watershed Runoff:
Subsurface Flow into Drains.  In:  Drainage Principles and Applications.
International Institute for Land Reclamation and Improvement.  P.O.
Box 45, Wageningen, The Netherlands.

Winger, R.J. and W.F. Ryan.  1970.  Gravel Envelopes for Pipe
Drain-Design.  American Society of Agricultural Engineers.  Chicago,
Illinois, December 8-11.

7.3  Flow Nets

Bennett, R.R.  1962.  Flow Net Analysis.  In:  Ferris, J.G., D.B.
Knowles, R.M. Brown, and R.W. Stallman.  1962.  Theory of Aquifer Tests:
U.S. Geological Survey Water Supply Paper 1536-E,  pp. 139-144.

Bennett, R.R. , and R.R. Meyer.  1952.  Geology and Groundwater Resources
of the Baltimore Area.  Maryland Department of Geology, Mines, and Water
Resources.   Bulletin 4, 573 p.

Cedergren, H.E.  1977.  Seepage, Drainage,  and Flow Nets  (2nd Edition).
John Wiley and Sons, New York.   534 p.

Freeze, R.A.  and J.A. Cherry.   1979.   Ground Water.  Prentice-Hall,
Englewood Cliffs, New Jersey,   pp.  168-191.

Lohman, S.W.  1979.  Ground Water  Hydraulics.  U.S. Geological Survey
Professional Paper  708.   70 p.

Mansur, C.I.  and R.I. Kaufman.   1962.   Dewatering.  In:   Leonards,  G.A.
 (Ed.).  1962.  Foundation  Engineering.   McGraw-Hill, New York.
pp.  241-350.

Powers, J.P.  1981.  Construction  Dewatering  - A Guide  to Theory and
Practice.   John Wiley and  Sons,  New York.   484 pp.

 7.4  Models

 7.4.1   Release Rate Models

All, E.M.,  C.A. Moore,  and I.L.  Lee.   1982.  Statistical Analysis of
Uncertainties of  Flow of  Liquids Through Landfills.  Proceedings of the
 Eighth Annual Research  Symposium:   Land Disposal of Hazardous Wastes.
 EPA-600/ 9-82-002;  U.S.  Environmental  Protection Agency, Cincinnati, OH.
 pp.  26-52.
 Anderson, D. ,  K.W. Brown and T. Green.  1982.  Effect of
 on the Permeability of Clay Soil Liners.  Proceedings of the Eighth
 Annual Research Symposium:  Land Disposal of Hazardous Wastes.
 EPA-600/9-82-002; U.S. Environmental Protection Agency, Cincinnati, OH.
 pp. 174-178.
                                      -99-

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Bailey, G.  November 1982.  Personal communication.

Barrier, R.M.  1978.  Zeolites and Clay Minerals as Sorbents and
Molecular Sieves.  Academic Press, New York.  497 pp.  As cited in Haxo
et al., 1980.

Brady, N.C.  1974.  The Nature and Property of Soils.  Macmillan
Publishing Co., Inc.  New York, N.Y.

Brenner, Walter and Barry Rugg.  1982.  Exploratory Studies on the
Encapsulation of Selected Hazardous Wastes with Sulfur Asphalt Blends.
Proceedings of the Eighth Annual Research Symposium:  Land Disposal of
Hazardous Waste.  EPA-600/9-82-002; U.S. Environmental Protection Agency,
Cincinnati, OH.  pp. 315-326.

Burns, J., and G. Karpinski.  August 1980.  Water  Balance Method
Estimates How Much Leachate Site Will Produce.  Solid Wastes Management.
pp. 54-86.

Chou,  Sheng-Fu J., Robert A. Griffin, and Mei-In M. Chou.  1982.  Effect
of Soluble Salts and Caustic Soda on Solubility and Adsorption of
Hexachlorocyclopentadiene.  Proceedings of  the Eighth Annual Symposium:
Land  Disposal of Hazardous Waste.  EPA-600/9-82-002; U.S. Environmental
Protection Agency, Cincinnati, OH.  pp. 137-149.

D'Appolonia, D.J. and C.R. Ryan.  1979.  Soil-Bentonite  Slurry Trench
Cutoff Walls.  In:  Geotechnical Exhibition  and Technical Conference
Proceedings, Engineered  Construction International,  Inc., Chicago,  IL.

Dragun, James and Charles S. Helling.   1982.   Soil and Clay Catalyzed
Reaction:  I.  Physicochemical  and  Structural Relationships of Organic
Chemicals Undergoing Free - Radical Oxidation.   Proceedings of  the  Eighth
Annual Research  Symposium:  Land Disposal  of Hazardous Waste.
EPA-600/9-82-002; U.S.  Environmental Protection  Agency,  Cincinnati, OH.
pp. 106-121.

Falco, J.W., L.A. Mulkey, R.R.  Swank,  Jr.,  R.E.  Lipcsei, and  S.M.  Brown.
A Screening  Procedure  for Assessing the Transport and Degradation  of
Solid Waste  Constituents in  Subsurface  and Surface Waters.   (Unpublished
paper)

Fenn, D.G.,  K.J.  Hanley, and  T.V.  Degeare.   1975.   Use of the Water
Balance Method  for  Predicting  Leachate Generation from Solid  Waste
Disposal  Sites.   EPA/530/SW-168,  Solid Waste Information,  U.S.
Environmental  Protection Agency.   Cincinnati, OH.   40 pp.

Freeze, R.A.  and J.A.  Cherry.   1979.   Groundwater.  Prentice-Hall,  Inc.,
Englewood Cliffs,  N.J.   604  pp.
                                      -100-

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Fuller, W.H.  1982.  Methods for Conducting Soil Column Tests to Predict
Pollution Migration.  Proceedings of the Eighth Annual Research
Symposium:  Land Disposal of Hazardous Wastes.  EPA-600/9-002; U.S.
Environmental Protection Agency, Cincinnati, OH.  pp. 87-105.

Garrett, B.C., J.S. Warner, M.P. Miller, and L.G. Taft.  1982.
Laboratory and Field Studies of Factors  in Predicting Site Specific
Composition of Hazardous Waste Leachate.  Proceedings of the Eighth
Annual Research Symposium:  Land Disposal of Hazardous Wastes.
EPA-600/9-82-002; U.S. Environmental Protection Agency, Cincinnati, OH.
pp. 67-86.

Gibson, A.C.  and P.G. Malone.  1982.  Verification  of the U.S. EPA HSSWDS
Hydrologic Simulation Model.  Proceedings of  the  Eighth Annual Research
Symposium:  Land Disposal of Hazardous Wastes.  EPA-600/9-82-
002; U.S. Environmental  Protection  Agency, Cincinnati, OH.   pp. 13-25.

Giroud, J.P.  and J.S. Goldstein.   1982.  Geomembrane Liner Design.  Waste
Age, September  1982.

Glaubbinger,  R.S.,  P.M.  Kohn,  and  R.  Ramirez.   1979.  Love Canal
Aftermath:  Learning  from a Tragedy.   Chemical Engineering.   October  22.

Guerero,  P.,  November 1982.  Personal Communication.

Hardcastle, J.H.  and  J.K.  Mitchell.  1974.   Electrolyte  Concentration
Permeability  Relations  in Sodium Illite-Silt Mixtures.   Clays and Clay
Minerals.   22(2) -.143-154.   As  cited in. Haxo,  et al. , 1980.

Haxo   H E.  et al.   September 1980.   Lining of Waste Impoundment and
Disposal  Facilities.   EPA/530/SW-870c, U.S.  Environmental Protection
Agency,  Cincinnati, OH.   385 pp.

Haxo   HE   Jr.  1981.   Testing Materials for Use  in the Lining of Waste
Disposal  Facilities,  Hazardous Solid Waste Testing:  First Conference
ASTM  STP 760, American Society for Testing and Materials,  pp. 269-292.

Haxo   H E   1982.   Effects on Liner Materials of Long-Term Exposure in
Waste Environments.  Proceedings of the Eight Annual Research Symposium:
Land  Disposal of Hazardous Waste.   EPA-600/9-82-002; U.S. Environmental
Protection Agency, Cincinnati, OH.  pp. 191-211.

Huck  PJ   1982.   Assessment of Time Domain Reflectrometry and Acoustic
 Emission Monitoring; Leak  Detection Systems for Landf"1 jj»««-
 Proceedings of the Eighth  Annual Research Symposium:  Land Disposal of
 Hazardous Waste.  EPA-600/9-82-002; U.S. Environmental Protection Agency,
 Cincinnati, OH.  pp. 261-273.
                                       -101-

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Hughes, J.  1975.  Use of Bentonite as a Soil Sealant for Leachate
Control in Sanitary Landfills.  Soil Lab. Eng. Report Data 280-E.
American Colloid Co., Skokie, IL.  As cited i.n Haro et al., 1980.

Hung, Cheng Y.  1980.  A Model to Simulate Infiltration of Rainwater
Through the Cover of a Radioactive Waste Trench Under Saturated and
Unsaturated Conditions.  Draft submitted to AGU for "Role of the
Unsaturated Zone in Radioactive and Hazardous Waste Disposal," to be
published by the Ann Arbor Science Publishers in 1983.

ICF Incorporated, Clement Associates, Inc., and SCS Engineers, Inc.,
1982.  RCRA Risk/Cost Policy Model Project, Phase 2 Report.  Submitted
to:  Office of Solid Waste, U.S. Environmental Protection Agency,
June IS, 1982.  Draft internal agency document.

JRB Associates, Inc.  1982.  Techniques for Evaluating Environmental
Processes Associated with the Land Disposal of Specific Hazardous
Materials, EPA Contract No. 68-01-5052, DOW No. 36, Task 1.

Kinman, Riley N., Janet I. Rickabaugh, James J. Walsh, and W. Gregory
Vogt.  1982.  Leachate from Co-Disposal of Municipal and Hazardous Waste
in Landfill Simulators.  Proceedings of the Eighth Annual Research
Symposium:  Land Disposal of Hazardous Waste.  EPA-600/9-82-002; U.S.
Environmental Protection Agency, Cincinnati, OH.  pp. 274-293.

Krisel, W.J., Jr., Editor.  1980.  CREAMS, a Field Scale Model for
Chemical Runoff and Erosion from Agricultural Management Systems.  Vols.
I, II, and III.  Draft copy.  USDA-SEA, AR, Cons. Res. Report 24.

Kumar, J. and J.A. Jedlicka.  1973.  Selecting and Installing Synthetic
Pond Linings.  Chemical Engineering. February 5, 1973.

Lee, J.  1974.  Selecting Membrane Pond Liners.  Pollution Engineering.
6(1):33-40.

Lentz, J.J.  1981.  Apportionment of Net Recharge in Landfill Covering
Layer  into Separate Components of Vertical Leakage and Horizontal
Seepage.  Vol. 17, No. 4, Water Resources Research, American Geophysical
Union,  pp. 1231-1234.

Lu, J.C.S., R.D. Morrison, and R.J. Stearns.  Leachate Production and
Management from Municipal Landfills:  Summary and Assessment.  Calscience
Research, Inc.  (Unpublished paper)

Lyman, W.J., W.F. Reehl, and D.H. Rosenblatt.  1982.  Handbook of
Chemical Property Estimation Methods:  Environmental Behavior of Organic
Compounds.  Prepared by Arthur D. Little, Inc. for the U.S. Army
Bioengineering Research and Development Laboratory, Fort Detrick, MD.  As
ciied  in JRB Associates, 1982.
                                     -102-

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Mabey, W. and T. Mill.  1978.  Critical Review of Hydrolysis of Organic
Compounds in Water Under Environmental Conditions.  J. Phys. and Chem.
1(2):383, 1978.  As cited in. JRB Associates, 1982.

Mielenz, R.C. and M.E. King.  1955.  Physical-Chemical Properties and
Engineering Performance of Clays.  Bulletin 169.  California Division of
Mines,  pp. 196-254.  As cited  in Haxo, et al., 1980.

Mingelgren, U.  et al.  1977.  A Possible Model for  the Surface-Induced
Hydrolysis of Organophosphorus  Pesticides on Kaolinite Clays, Soil
Science Society of America J. 41..  As  cited  in JRB  Associates, 1982.

Mill, X.  1980.  Data Needed  to Predict  the Environmental Fate of Organic
Chemicals.  In:  Dynamics, Exposure  and  Hazard Assessment of Toxic
Chemicals.  Rizwanul  and Hague, Eds.   As  cited  ill JRB Associates, 1982.

Montague, P.   1982.   Hazardous  Waste Landfills:   Some Lessons from New
Jersey.  Civil  Engineering.   ASCE.   September 1982.

Moore,  C.A.   September  1980.  Landfill and  Surface  Impoundment
Performance Evaluation.   SW-869,  U.S.  Environmental Protection Agency,
Cincinnati, OH. 63  pp.

Moore,  C.A.  and M.  Roulier.   1982.   Evaluating  Landfill  Containment
Capability.   Proceedings  of  the Eighth Annual Research  Symposium:  Land
Disposal of  Hazardous Wastes.  EPA-600/9-82-002;  U.S. Environmental
Protection Agency,  Cincinnati,  OH.   pp.  174-178.

Moore,  C.A.  and E.M.  Ali.   1982.   Permeability of Cracked Clay Liners.
Proceedings  of the Eighth Annual Research Symposium:  Land Disposal  of
Hazardous Wastes.   EPA-600/9-82-002; U.S. Environmental Protection
Agency, Cincinnati,  OH.  pp. 174-178.

Perrier, E.R.. and A.C. Gibson.  September 1980.  Hydrologic Simulation
of Solid Waste Disposal Sites.   EPA/530/SW-868c, U.S. Environmental
Protection Agency, Cincinnati,  OH.  Ill PP-

 Peters  WR   DW  Shultz, and B.M. Duff.  1982.  Electrical Resistivity
 £ch"ques for Locating L^ner Leaks.  Proceedings of the Eight Annual
 Research Symposium:  Land Disposal of Hazardous Wastes.
 EPA-600/9-82-002;  U.S.  Environmental Protection Agency, Cincinnati, OH.
 pp. 250-260.

 Pohi«nrf  Frederick G   Joseph P. Gould, R. Elizabeth Ramsey, and Daniel!
 C  Waters   1982   The Behavior of Heavy Metals During Landfill Disposal
 of Hazardous Wastes.  Proceedings of  the Eight A™
 Symposium:  Land Disposal of Hazardous Wastes^  EP
 Environmental  Protection Agency, Cincinnati, OH.   pp
                                       -103-

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Pope-Reid Associates, Inc.  1982.  Hazardous Waste Landfill Design,  Cost
and Performance Modelling.  Unpublished draft report.

Prickett, T.A.  July 1982.  Personal Communication.

Rosenbaum, M.S.  1976.  Effect of Compaction on the Pore Fluid Chemistry
of Montmorillonite.  Clays and Clay Minerals.  24:118-121.  As cited ill
Haxo, et al., 1980.

SCS Engineers, Inc.  1982.  Release Rate Computations for Land Disposal
Facilities.  Currently under development for EPA.

Shuckrow, Alan J. and Andrew P.  Pajak.  1982.  Studies on Leachate and
Groundwater Treatment at  Three Problem Sites.  Proceedings of the Eighth
Annual Research Symposium:  Land Disposal  of Hazardous Waste.
EPA-600/9-82-002; U.S. Environmental Protection Agency, Cincinnati, OH.
pp. 346-359.

Shultz, David W. and Michael Miklas.  1982.  Procedures for Installing
Liner Systems.  Proceedings of the Eighth  Annual  Research Symposium:
Land Disposal of Hazardous Waste.  EPA-600/9-82-002; U.S. Environmental
Protection Agency, Cincinnati, OH.  pp. 224-238.

Silka, L.R., and R.L. Swearingen.  1978.   A Manual  for Evaluating
Contamination Potential of Surface Impoundments.  EPA-570/9-78-003; U.S.
Environmental Protection  Agency, Cincinnati, OH.  73 pp.

Skaggs, R.W.  1980.  Combination Surface-Subsurface Drainage System for
Humid Regions.  Journal of the Irrigation  and Drainage Division, ASCE,
Vol. 106, No. 1R4, Proc.  Paper 15883, pp.  265-283.

Skaggs, R.W.  1980.  A Water Management Model for Artificially Drained
Soils.  Tech. Bui. No. 267, North Carolina Agricultural Research
Service.  54 pp.

Skaggs, R.W.  1982.  Modification to DRAINMOD to  Consider Drainage  from
and Seepage Through  a Landfill.   I.  Documentation. Unpublished EPA
Document, August 26, 1982.

Skaggs, R.W., A. Nassehzadeh-Tabrinzi,  and G.R.  Foster.   1982.
Subsurface Drainage  Effects on Erosion.   Paper  No.  8212,  Journal Series,
North Carolina Agricultural Research Service, Raleigh,  pp.  167-172.

Skaggs, R.W., N.R.  Fausey,  and B.H. Nolte.  1981.  Water  Management Model
Evaluation for North Central  Ohio.  0001-2351/81-2404-0929,  American
Society of Agricultural  Engineers,  pp.  922-928.

Skaggs  R.W.,  and  J.W. Gillian.   1981.   Effect  of Drainage System Design
and Operation  on Nitrate Transport.   0001-2351/81-2404-0929,  American
Society  of Agricultural  Engineers,  pp.  929-940.
                                      -104-

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Skaggs, R.W.  1982.  Field Evaluation of a Water Management Simulation
Model.  0001-2351/82/2503-0666, American Society of Agricultural
Engineers,  pp. 666-674.

Spooner, P.S., et al.  1982.  Draft Technical Handbook on Slurry Trench
Construction for Pollution Migration Control.  EPA Contract
No. 68-01-3113.

Thornthwaite, C.W. and J.R. Mather.  1955.  The Water Balance.
Centerton, N.J.  104 p.   (Drexel Institute of Technology.  Laboratory of
Climatology.  Publications in Climatology, V. 8, No. 1.)  As cited in
Fenn, Hanley, and DeGeare, 1975.

Thornthwaite, C.W. and J.R. Mather.  1957.  Instructions and Tables for
Computing Potential Evapotranspiration and the Water Balance.  Centerton,
NJ.  pp. 185-311.  (Drexel Institute of Technology.  Laboratory of
Climatology.  Publications in Climatology, V. 10, No. 3.)  As cited in
Fenn, Hanley, and DeGeare, 1975.

Tolman, A.L., A.P. Ballestero, Jr., W.H. Beck, Jr., and G.H. Emrich.
1978.  Guidance Manual for Minimizing Pollution from Waste Disposal
Sites, EPA-600/2-78-142.  U.S. Environmental Protection Agency,
Cincinnati, OH.  83 pp.

U.S. Environmental Protection Agency.  1981.  Land Disposal of Hazardous
Waste:  Summary of Panel  Discussions,  (SW-947).  U.S. EPA, Washington,
D.C., May 18-22, 1981.  Contract No. 68-01-6092.

U.S. Environmental Protection Agency.  June 1982.  Post-Closure Liability
Trust Fund Model Development.  Unpublished internal report.

U.S. Environmental Protection Agency.  1982.  Hazardous Waste Management
System:  Permitting Requirements for Land Disposal Facilities,  (40 CFR
Parts 122, 260, 264, and  265).  Federal Register, Vol. 47, No. 143,
July 26, 1982.

Waller, Muriel Jennings and J.L. Davis.  1982.  Assessment of Techniques
to Detect Liner Failings.  Proceedings of the Eighth Annual Research
Symposium:  Land Disposal of Hazardous Waste.  EPA-600/9-82-002; U.S.
Environmental Protection  Agency, Cincinnati, OH.  pp. 239-249.

Weber, W.J.  1972.  Physiochemical Processes for Water Quality Control.
As cited in JRB Associates, 1982.

Wong, J.  1977.  The Design of a System for Collecting Leachate from  a
Lined Landfill Site.  Water Resources Research, V. 13, No. 2,
pp. 404-410.  As cited  in. Moore, 1980.
                                      -105-

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7.4.2  Transport Models

Anderson, M.P.  1981.  Groundwater Quality Models - State of the Art.   In
Proceedings and Recommendations of the Workshop on Groundwater Problems
in the Ohio River Basin.  Cincinnati, OH.  ppp. 90-96.

Anderson, M.P.  1979.  Using Models to Simulate the Movement of
Contaminants through Groundwater Flow Systems.  CRC Critical Reviews in
Environmental Control 9(2):97-156.

Bachmat, Y., J. Bredehoeft, B. Andrews, D. Holtz, and S. Sebastian.
1980.  Groundwater Management:  The Use of Numerical Models.  Water
Resources Monograph 5.  American Geophysical Union, Washington, D.C.
127 p.

Bachmat, Y., B. Andrews, D. Holt,  and S.  Sebastian.  1978.  Utilization
of Numerical Groundwater Models for Water Resources Management.
Robert S. Kerr Environmental Research Laboratory, U.S. EPA, EPA-600/8-78-
012.

Battelle Pacific Northwest Laboratories.  1982.  Personal communication.

Bibby, R.   1981.  Mass Transport of Solutes  in Dual-Porosity Media.
Water Resources Research 17(4) -.1075-1081.

Bonazountas, M. and J. Wagner.  1981.  "SESOIL":  A Seasonal Soil
Compartment Model.  Arthur D.  Little, Inc.,  Cambridge, MA.

Chang, S.,  K. Barrett,  S. Haus, and A. Platt.  1981.  Site  Ranking Model
for Determining Remedial Action Priorities Among Uncontrolled  Hazardous
Substances  Facilities.  The MITRE  Corporation, Working Paper to EPA,
Contract No.  68-01-6278.

Charbeneau, R.J.  1981.  Groundwater  Contamination Transport with
Adsorption  and Ion Exchange Chemistry:   Method of Characteristics  for
Case Without  Dispersion.  Water Resources Research 17(3) -.705-713.

Chou, S.J., B.W.  Fischer,  and  R.A. Griffin.   1981.  Aqueous Chemistry  and
Adsorbtion  of Hexachlorocyclopentadiene  by Earth materials.  In:
Proceedings of the Seventh Annual  Research Symposium  on  Land  Disposal  of
Hazardous Waste.  EPA-600/9-81-0026,  p.  29-A2.

Chu, S.  and G. Sposito.   1980. A Derivation of  the Macroscopic  Solute
Transport Equation for Homogeneous,  Saturated, Porous Media.   Water
Resources Research 16(3) -.542-546.

Cleary,  R.  1982.  Personal  communication.
                                      -106-

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Dettinger, M.D. and J.L. Wilson.  1981.  First Order Analysis of
Uncertainty and Numerical Models of Groundwater Flow.  Part 1.
Mathematical Development.  Water Resources Research 17(1):149-161.

Dragun, J. and C.S. Helling.  1981.  Evaluation of Molecular Modeling
Techniques to Estimate the Mobility of Organic Soils:  II.   Water
Solubility and the Molecular Fragment Mobility Coefficient.  In:
Proceedings of the Seventh Annual Research Symposium on Land Disposal of
Hazardous Waste.  EPA-600/9-81-0026, p. 58-70.

Duffy, J.J., E. Peake, and M.F. Mohtadi.  1980.  Oil Spills on Land as
Potential Sources of Groundwater Contamination.  Environment
International 3(2):107-120.

Enfield, C.G., R.F. Carsel, S.Z. Cohen, T. Phan, and D.M. Walters.
1982.  Approximating Pollutant Transport to Ground Water.  U.S. EPA.
RSKERL.  Ada, OK.  (Unpublished paper)

Falco, J.W., L.A. Mulkey, R.R. Swank, R.E. Lipcsei, and S.W. Brown.  A
Screening Procedure for Assessing the Transport and Degradation of Solid
Waste Constituents in Subsurface and Surface Waters.   (Unpublished paper)

Faust, C.R.  The Use of Modeling in Monitoring Network Design.
Unpublished

Fenn, D.G., K.J. Hanley, and T.V. Degeare.  1975.  Use of the Water
Balance Method for Predicting Leachate Generation from Solid Waste
Disposal Sites.  EPA/530/SW-168.  U.S. EPA, Office of  Solid Waste,
Cincinnati, OH.

Fuller, W.H.  1982.  Methods for Conducting Soil Column Tests to  Predict
Pollutant Migration.  In:  Proceedings of the the Eighth Annual Research
Symposium on Land Disposal of Hazardous Waste.  EPA/600/9-82-002,
p. 87-103.

Fuller, W.H.  1977.  Movement of Selected Metals, Asbestos, and Cyanide
in Soil:  Applications to Waste Disposal Problems.  MERL, ORD, U.S. EPA,
EPA/600/2-77-020.  243 p.

Fuller, W.H., A. Amoozegar-Fard, E. Niebla, and M. Boyle.  1981.
Behavior of Cd, Ni, and Zn  in Single and Mixed Combinations in Landfill
Leachates.  In:  Proceedings of the Seventh Annual Research Symposium on
Land Disposal of Hazardous Waste.  EPA/600/9-81-0026,  p. 18-28.

Gorelick, S.M. and I. Rerason.  1982.  Optimal Dynamic  Management  of
Groundwater Pollutant Sources.  Water Resources Research 18(1):71-76.

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Grisak, G.E., J.F. Pickens, and J.A. Cherry.  1980.  Solute Transport
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Kuczera, G.  1982.  On the Relationship Between the Reliability of
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Pope-Reid Associates, Inc.  1982.  Technical Review of Groundwater
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Smith, L. and F.W. Schwartz.  1981.  Mass Transport.  3.  Role of
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Yeh, G.T. and D.S. Ward.  1980.  FEMWATER:  A Finite-Element Model of
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