&EPA
United States
Environmental Protection
Agency
Office of Water Regulations
and Standards (WH-552)
Washington, D.C. 20460
EPA 506/6-90/001b
December 1990
Water
BIOACCUMULATION
OF SELECTED POLLUTANTS
IN FISH
A National Study
Volume II
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EPA 506/6-90/001 b
December 1990
BIOACCUMULATION OF
SELECTED POLLUTANTS
IN FISH - A NATIONAL STUDY
Volume II
Prepared by:
Tetra Tech, Inc.
3746 Mt. Diablo Blvd.
Lafayette, California 94549
and
10306 Eaton Place
Fairfax, Virginia 22030
Prepared for:
Assessment and Watershed Protection Division
Office of Water Regulations and Standards
U.S. Environmental Protection Agency
401 M Street SW
Washington, D.C. 20460
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APPENDIX C
PROFILES OF BIOACCUMULATION STUDY
CHEMICALS
Dioxins/Furans
Dioxin: 2,3,7,8 Tetrachloro-
dibenzo-p-dioxin
1,2,3,7,8 Pentachlorodibenzo-
dioxin
Hexachlorodibenzodioxins
Furans
Other Xenobiotics
Biphenyl
Chlordane
Chlorpyrifos
p,p' -DDE
Dicofol
Dieldrin
Diphenyl Bisulfide
Endrin
Heptachlor
Heptachlor
Heptachlor Epoxide
Hexachlorobenzene
a -Hexachlorocyclohexane
Isopropalin
Other Xenobiotics fcont.")
Lindane
Mercury
Methoxychlor
Mirex
Nitrofen
Nonachlor
Octachlorostyrene
Oxychlordane
Pentachloroanisole
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Perthane
Polychlorinated Biphenyls (PCBs)
1,2,3,4 and 1,2,3,5 Tetrachlorobenzene
1,2,4,5 Tetrachlorobenzene
1,2,3 Trichlorobenzene
1,2,4 Trichlorobenzene
1,3,5 Trichlorobenzene
Trifluralin
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DIOXIN: 2,3,7,8 TCDD
CAS No.: 1746-01-6
CAS Preferred Nomenclature:
Dibenzo[b,e][l,4]dioxin,2,3,7,8-tetrachloro-
Empirical Formula: C12H4CUO2
Synonyms and Common Names:
- 2,3,7,8 Tetrachlorodibenzo-p-dioxin
- TCDD or TDD
C12H4CI402,TCDD
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish) for a 10
cancer risk (ATSDR, 1987):
0.000014 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Health Adviso-
ries (U.S. EPA, 1988)
£hild_(10kg):
1-day exposure = I ng/L
10-day exposure = 0.1 ng/L
longer-term exposure = 0.01 ng/L
adull(70kg):
longer-term exposure = 0.04 ng/L
Food and Drug Administration
Health Advisory for Fish* (U.S. EPA,
1987c):
< 25 parts per trillion (ppt), no seri-
ous health concerns
25-50 ppt, restrict consumption to
twice per month
> 50 ppt, consumption not recom-
mended
* Guidance developed for fish caught
in the Great Lakes for use in inter-
state commerce only
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EPA Drinking Water Standard Mari- Center for Disease Control Level of
mum Contaminant Level: Concern in Soil for residential areas
None established at present (U.S. EPA, 1987c):
Ippb
Use Restrictions and Bans:
EPA has required manufacturers to reduce concentrations of TCDD in chemical
products; most chemicals now have less than 0.02 p g/g (ATSDR, 1987). Some
compounds such as 2,4,5 T are no longer produced in the U.S.
SOURCES OF DIOXIN
Dioxin Formation;
TCDD is one of 75 types of dioxin formed as unwanted impurities during the
manufacture of other organic compounds including herbicides containing 2,4,5
trichlorophenoxy acids (2,4,5 T), 2,4,5 trichlorophenol used in the defoliant Agent
Orange, hexachlorophene formerly used as a germaride, pentachlorophenol and
PCBs. Other dioxms which have been studied include 1,2,3,7,8 PeCDD and two of
the HxCDDs (1,2,3,6,7,8 and 1,2,3,7,8,9 HxCDD). TCDD is the most toxic and most
studied of all the isomers.
Dioxin can be generated as a by-product of paper and pulp mill bleaching processes
which use chlorine. It can then be released to aquatic systems in various wastewater
streams and sludges generated by these industries (U.S. EPA, 1988; NCASI, 1987).
Uses of Dioxin;
No commercial production or importation of dioxin in the U.S., but small quantities
are produced for research purposes (NITS, 1980 and ATSDR, 1987).
Other Sources;
Examples of levels of dioxin found in other organic compounds are listed below
(ATSDR), 1987):
- Until 1960,2,4,5 T had up to 100 ft g/g g/g TCDD, now <0.1 p g/g
- Agent Orange had 0.02 to 54 p g/g
- Hexachlorophene had 0.2 to 0.5 ng/g
- Pentachlorophenol has <0.1/< g/g of other dioxin isomers but no TCDD
- Polychlorinated Biphenyls (PCBs) also contain TCDD. Oil containing PCBs
was formerly used in electrical transformers. Utilities are gradually replacing
these old transformers.
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Incineration of municipal and industrial wastes at too low a temperature (< 800°C)
can produce dioxin. (Verschueren, 1983; ATSDR, 1987; U.S. EPA, 1987b).
Derivatives of pentachlorophenol and other woodtreating wastes (NCASI, 1987;
U.S. EPA, 1987b).
Currently, EPA is investigating possible correlations between dioxin and nearby
petroleum refineries which use chlorine or chlorinated solvents in the catalytic
reforming process.
Other sources of dioxin include fires 'and/or spills involving chlorinated benzenes
and PCBs, particularly fires involving transformers or capacitors, burning of wood
in presence of chlorine, and automobile exhaust from leaded gasoline (ATSDR,
1987).
FATE OF DIOXIN IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, dioxin is only slightly soluble in water
(Aq. sol. = 0.000317) and strongly sorbs to soil (Kow = 10,500,000). It has a high
potential for bioaccumulation (BCF = 5,000), although experimental data have
shown much higher values (e.g., over 9,000).
Persistence;
Because dioxin strongly sorbs to sediment, it persists in soils and aquatic systems.
Photolysis can occur, aided by photosensitizers in surface water (half-life 1 to 1.5
years) or in the top few inches of soil (half-life 1 to 3 years) (U.S. EPA, 1985b and
Freeman, elaL, 1986). Hydrolysis is not thought to be important (Callahan, el al,
1979). Biotransformation of dioxin in soils is slow (ATSDR, 1987).
HEALTH EFFECTS
Carcinogenicity;
Oral exposure causes increased incidence of tumors in liver, tongue, hard palate
and lungs in rats (Kociba e_t al., 1978a,b) and in thyroid and adrenal glands in mice
(NTP, 1982a,b). EPA classification is B2, a probable human carcinogen (IRIS,
1989). IARC classification 2b (IARC, 1982).
In combination with herbicides such as trichlorophenols, dioxin is classified by the
EPA as Bl, limited evidence of human carcinogenicity (IRIS, 1989). -
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Mutagenic Activity;
Mutagenicity tests have produced inconclusive results. Bacterial tests were nega-
tive as were most tests using rats and mice except when bone marrow cells were
used (Green el aL, 1977; Meyne el aL, 1985). Early tests using yeast cells showed
positive results (IARC, 1982).
Reproductive Effects;
Adverse reproductive effects are caused in a variety of animals:
- fetotoxic in monkeys (U.S. EPA, 1985b)
- embryotoxic and teratogenic in mice, rabbits, ferrets and rats (IARC, 1977;
U.S.EPA,1985b)
- reduced fertility and spontaneous abortions in monkeys (ATSDR, 1987)
- birth defects in mice (e.g., cleft palates and kidney abnormalities) (U.S. EPA,
1985b)
Other lexicological Effects;
Major observed toxic effect on humans is chloracne (U.S. EPA, 1985b).
Human exposure through herbicides and other TCDD-contaminated chemicals can
also cause altered liver function, porphyria, neurotoxicity, and hyperpigmentation
(U.S. EPA, 1985b).
Toxic effects to acutely exposed animals include extreme weight loss, liver and
thymus damage, immunotoxicity and hepatotoxicity (IARC, 1977; U.S. EPA,
1985a).
Toricological Effects Indices:
Cancer potency factor (CPF): UfixlO5 (mg/kg/day)"1. (U.S. EPA, 1986a).
Reference Dose (RfD): IxlO"6 /i g/kg/day (ATSDR, 1987).
Oral LDso: 0.6 /* gflcg in guinea pigs ; 5,500^ g/kg in hamsters (U.S. EPA 1985b).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration
Factor, BCF:
3.17x10"* (25°C)
1.4xlO'9(25°C)
2.1X10"6
6.15-7.28
6.0-739
best estimate,
5000*
7900-9300,
fathead minnows
Reference
Molecular Weight (g/mole):
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Density (g/mL):
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
321.97
solid, colorless
needles with no
odor
305
4122
1.827 (est)
N/A
1.93xlO'5(22°C)
Windholz, 1983
Windholz, 1983
SchroyelaL, 1985
SchroyelaL, 1985
SchroyslaL, 1985
MarplefilaL, 1986
Schroyfiial., 1985
SchroyfilaL, 1985
SchroyelaL, 1985
U.S.EPA,1985a
U.S. EPA, 1985a
U.S. EPA, 1986a
U.S.EPA,1985b
Value used for estimating aquatic effects
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REFERENCES
ATSDR. 1987. Draft Toricological Profile for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. U.S.
Public Health Service, Oak Ridge National Lab, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants. Office of Water Planning and
Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Freeman, R.A., J.M. Schroy, F.D. Hileman, R.W. Noble. 1986. Environmental Mobility of
2,3,7,8-TCDD and Comparison Chemicals in a Roadway Soil Matrix. In: Chlorinated Dioxins
and Dihenzofarans in Perspective. (C. Rappe, G. Choudhary, LJL Keith, eds.) Lewis
Publishers, Inc., Chelsea.
Green, S., Moreland, Sheu, C 1977. Cytogenic Effect of 2,3,7,8-Tetrachlorodibenzo-p-dioxin
on Rat Bone Marrow Cells. Food and Drug Administration, Washington, D.C. FDA By-
Lines, fi:292. (Cited in U.S. EPA 1985a).
International Agency for Research on Cancer. 1982. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 29. IARC, Geneva, World Health
Organization.
Integrated Risk Information System (IRIS). 1989. 2,3,7,8,-TCDD. U.S. Environmental
Protection Agency, Washington, D.C.
Kociba, R J., D.G. Keyes, J.E. Beyer, and R.M. Carreon. 1978a. Results of a Two-year Chronic
Toxicity and Oncogenicity Study of 23,7,8-Tetrachlorodibenzo-p-dioxin in Rats. Toxicol.
Appl. Pharmacol.. 46f2V279-3Q3.
Kociba, R J., D.G. Keyes, J.E. Beyer, and R.M. Carreon. 1978b. Toxicologic Studies of
2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) in Rats. Toxicol. Occup. Med. (De Toxicol.
Environ. Sci.), 4:281-287. (Cited in U.S. EPA 1985a.)
Marple, L, R. Brunck and L. Throop. 1986. Water Solubility of 2,3,7,8-Tetrachlorodibenzo-
p-dioxin. Environ. Sci. Technol. 2Q: 180-182.
Meyne, J., D.C. Allison, K. Bose, S.W. Jordan, P.F. Ridolpho, and J. Smith. 1985. Hepatotoxic
Doses of Dioxin do not Damage Mouse Bone Marrow Chromosomes. Mutat. Res. 152:63-69.
NCASI. 1987. Dioxin: A Critical Review of its Distribution, Mechanism of Action, Impacts
on Human Health and the Setting of Acceptable Exposure Limits. National Council of the
Paper Industry of Air and Stream Improvement. Technical Bulletin No. 254. New York, NY.
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NTIS, 1980. Dioxins. Prepared for EPA Industrial Environmental Research Laboratory.
Contract Numbers: 68-03-2577,68-03-2659,68-03-2579.
NTP (National Toxicological Program). 1982a. Bioassay of 2,3,7,8-Tetrachloro-dibenzo-p-
dioxin for Possible Carcinogenicity (Gavage Study). DHHS Publ. No. (NIH) 82-1765.
Bethesda, MD: Carcinogenesis Testing Program, NCI, NIH; Research Triangle Park, NC:
National Toxicology Program.
NTP (National Toxicological Program). 1982b. Bioassay of 2,3,7,8-Tetrachloro-dibenzo-p-
dioxin for Possible Carcinogenicity (Dermal Study). DHHS Publ. No. (NIH) 82-1757.
Bethesda, MD: Carcinogenesis Testing Program, NCI, NIH; Research Triangle Park, NC:
National Toxicology Program.
Podoll, R J., H.M. Jaber andT. Mill. 1986. Tetrachlorodibenzodioxin: Rates of Volatilization
and Photolysis in the Environment. Environ. Sci. TechnoL 20:490-492.
Schroy, J.M., Hileman F.D., Cheng S.C. 1985. Physical/Chemical Properties of 2,3,7,8-
TCDD. Chemosphere; 11:877-880.
U.S. EPA. 1985a. Drinking Water Criteria Document for 2,3,7,8-Tetrachlorodibenzo-p-di-
oxin. EPA Report No. 600/X-84-194-I. Environmental Criteria and Assessment Office, U.S.
EPA, Cincinnati, OH.
U.S. EPA. 1985b. Health Assessment Document for Polychlorinated Dibenzo-p-dioxins.
Office of Health and Environmental Assessment, Washington, D.C. EPA/600/8-84/014F.
U.S. EPA. 1986a. Superfund Public Health Evaluation Manual. Office of Emergency and
Remedial Response, Washington, D.C. EPA/540/1-86/060.
U.S. EPA. 1986b. Health Assessment Document for Polychlorinated Dibenzofurans (Review
Draft). Environmental Criteria and Assessment Office, Cincinnati, OH. EPA/600/8-86/018-
A
U.S. EPA. 1987a. The National Dioxin Study. Tiers 3,5,6 and 7. Office of Water Regulations
and Standards, Washington, D.C. EPA 440/4-87-003.
U.S.EPA. 1987b. National Dioxin Study. Washington, D.C. EPA 530-SW-87-025.
U.S.EPA 1987c. 2,3,7,8-Tetrachlorodibenzo-p-dioxin. Health Advisory, Office of Drinking
Water. Washington, D.C.
U.S. EPA. 1988. U.S. EPA/Paper Industry Cooperative Dioxin Screening Study. Office of
Water, Washington, D.C. EPA-440/1-88-025.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
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Windholz, M. ed. 1983. The Merck Index: An Encyclopedia of Chemicals. Drugs, and
Biologicals. Merck and Co., Rahway, NJ.
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1,2,3,7,8 PeCDD
(PENTACHLORODIBENZODIOXIN)
CAS No.: 40321-76-4
CAS Preferred Nomenclature:
Dibenzo-[b,e]( l,4,)dioxin,
1,2,3,7,8-pentachloro-
Empirical formula: CiiHsQsCh
C H Cl O
Synonyms and Common Names: '
- 1,2,3,7,8 Pentachlorodibenzodioxin
- PeCDD
REGULATORY STATUS
None established at present.
SOURCES OF PeCDD
Formation of PeCDD:
PeCDD is not intentionally produced for any commercial purposes in the U.S. It
is an unwanted byproduct of the manufacture of other organic compounds, as is
2,3,7,8 TCDD. PeCDD can also be formed during the incineration of municipal
and industrial wastes at low temperatures (<800 C) (U.S. EPA, 1984; ATSDR,
1987).
See "Dioxin:2,3,7,8 TCDD" and "Hexachlorodibenzodioxins" for more information
on other dioxins.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, PeCDD is only slightly soluble in water
and strongly sorbs to soil (Kow= 7xl06). It also has a strong potential for
bioaccumulation, although experimental data on specific BCF values were not
found.
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Persistence;
Photolysis of PeCDD can occur. In hexane,the half-life of PeCDD exposed to
sunlight was reported to be 5.4 hours (U.S. EPA, 1984).
PeCDD OBSERVED IN THE ENVIRONMENT
PeCDD has been detected in fish tissues (at unspecified concentrations), but not
in drinking water (U.S. EPA, 1984).
HEALTH EFFECTS
Toxicological Effects;
No chronic exposure studies have been conducted with PeCDD. This includes a
lack of studies on the potential carrinogenicity, teratogenicity or mutagenicity of
the compound.
Other forms of dioxin are extremely toxic and carcinogenic hi animals. The acute
LD50 value of PeCDD suggests that it is biologically less active than TCDD (2,3,7,8
TCDD), but there are insufficient data to quantitatively estimate the health risk
from PeCDD exposure (U.S. EPA, 1984; ATSDR,-1987). See "Dioxin: 2,3,7,8
TCDD", for more information.
Toxicological Effects Indices;
Oral LDso values: guinea pigs, 0.009 /
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PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight: 356.5 U.S. EPA, 1984
Melting Point (°C): 240-241 U.S. EPA, 1984
Water Solubility, S (pg/L): 0.04 (est.) U.S. EPA, 1984
KOW (Octanol-Water Partition
Coefficient): 7xl06(est.) U.S. EPA, 1984
Soil Adsorption Coefficient, Koc (ml/g): 5xl06 U.S. EPA, 1984
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REFERENCES
ATSDR. Agency for Toxic Substances and Disease Registry. 1987. Draft lexicological
Profile for 2,3,7,8-TCDD (Dioxin). U.S. Public Health Service.
U.S. EPA. 1984. Health Assessment Document for Polychlorinated Dibenzo-pDioxins.
Office of Health and Environmental Assessment, Washington, D.C. EPA/600/8-84/014A.
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HEXACHLORODIBENZODIOXINS
U3,6,7,8-HxCDD:
CAS No.: 57653-85-7
CAS Preferred Nomenclature:
Dibenzo-[b,e](l,4,) dioxin,
1,2,3,6,7,8-hexachloro-
Empirical formula: Ci2H2Cl6O2
Synonyms and Common Names:
- 1,2^3,6,7,8 Hexachlorodibenzodioxin
- HxCDD
- HxDD
ci
1,2,3,7,8.9-HxCDD;
CAS No.: 19408-74-3
CAS Preferred Nomenclature:
Dibenzo-[b,e]( l,4,)dioxin,
1,2,3,7,8,9 hexachloro-
Empirical formula: Ci2H2Cl6O2
Synonyms and Common Names:
- -1,2,3,7,-8,9 Hexachlorodibenzodioxin
- HxCDD
- HxDD
1,2,3,4,7,8-HxCDD;
CAS No.: 39227-28-6
CAS Preferred Nomenclature:
Dibenzo-[b,e](l,4)dioxin,
1,2,3,4,7,8-hexachloro-
Empirical formula: Ci2H2Cl6O2
Synonyms and Common Names:
- 1,2,3,4,7,8 Hexachlorodibenzodioxin
- HxCDD
- HxDD
Cl C!
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REGULATORY STATUS
None established at present
SOURCES OF HxCDD
Total HxCDD Produced:
The HxCDDs are not intentionally produced for any commercial purposes in the
U.S.
The HxCDDs, as well as other forms of dioxin, are produced as un-
wantedcontaminants of organic compounds, particularly chlorophenols such as
pentachlorophenol (U.S. EPA, 1984; ATSDR, 1987).
See "Dioxin:2,3,7,8 TCDD" and "1,23,7,8 PeCDD" for more information on other
dioxins.
FATE IN ENVIRONMENT
Partitioning;
Based on their physical/chemical properties, the HxCDDs are only slightly soluble
in water and strongly sorb to soil (Kpw =4.2x10 ). They also have strong potential
for bioaccumulation(BCF for 1^3,7,8,9-HxCDD = 5,800).
Persistence:
Photolysis of the HxCDDs can occur. In n-hexadecane, the half-life of 1,2,3,6,7,8-
HxCDD exposed to a sunlamp was 6.8 hours. Two other HxCDDs, 1,2,3,6,7,9- and
1,2,4,6,7,9-HxCDD (m hexane) had half-lives, respec-tively, of 17 and 47 hours,
when exposed to sunlight (U.S. EPA, 1984).
HxCDDs OBSERVED IN THE ENVIRONMENT
HxCDDs (unspecified isomers) have been detected in fish, gelatin and human milk
but not in drinking water. Concentrations were not given (U.S. EPA, 1984).
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HEALTH EFFECTS
Carcinogenicity;
The HxCDDs are rated as probable (B2) human carcinogens by the U.S. EPA
because a 2:1 mixture of 1,2,3,7,8,9 and 1,2,3,6,7,8 HxCDD caused liver tumors in
rats and mice (U.S. EPA, 1984).
Other Toxicological Effects:
Potency of HxCDD estimated to be l/20th of TCDD, the most toxic form of dioxin
(U.S. EPA, 1984). See "Dioxin:2^,7,8 TCDD" for more health effects information.
No studies have been conducted on the teratogenicity or mutagenicity of the
HxCDDs.
r
Toxicological Effects Indices:
. Cancer Potency Factor: 6.2X103 (mg/kg/day)'1 (U.S. EPA, 1984; PHRED, 1988).
1,2^,6,7,8 HxCDD oral LDso values: guinea pigs, 0.178 to 0.255 ft mol/kg; mice,
3.19/*mol/kg.
1,2,3,7,8,9 HxCDD oral LDso values: guinea pigs, 0.153 to 0.255 p mol/kg; mice,
3.67 ^mol/kg.
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1,2,3,6,7,8 HxCDD PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight: 390.9 U.S. EPA, 1984
Melting Point (°C): 285-286 U.S. EPA, 1984
Water Solubility S(mg/L): SxlO"6 (est.) U.S. EPA, 1984
Log (Octanol-Water Partician
Coefficient), log Kow: 7.6 U.S. EPA, 1984
Soil Adsorption Coefficient, Koc (ml/g): 3xl07 (est.) U.S. EPA, 1984
1,2,3,7,8,9 HxCDD PHYSICAL/CHEMICAL PROPERTIES
\
t
Value Reference
Molecular Weight: 390.9 PHRED, 1988
Melting Point (°C): 243-244 U.S. EPA, 1984
Water Solubility, S (mg/L): 6x10"* PHRED, 1988
Log (Octanol-Water Partition Coefficient),
log Kow: 7.6 PHRED, 1988
Soil Adsorption Coefficient, Koc (ml/g):. 3xl07 . PHRED, 1988
Fish Bioconcentration Factor BCF: 5800 PHRED, 1988
i
1,2,3,4,7,8 HxCDD PHYSICAL/CHEMICAL PROPERTIES
v
Value Reference
\
Molecular Weight: 390.9 U.S. EPA, 1984
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REFERENCES
ATSDR. Agency for Toxic Substances and Disease Registry. 1987. Draft Toxico-logical
Profile for 2,3,7,8 TCDD (Dioxin). U.S. Public Health Service.
PHRED. Public Health Risk Evaluation Database. 1988. Office of Emergency and Remedial
Response, U.S. EPA, Washington. D.C.
U.S. EPA. 1984. Health Assessment Document for Polychlorinated Dibenzo-p-Dioxins.
Office of Health and Environmental Assessment, Washington, D.C. EPA/600/8-84/014A.
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FURANS
(POLYCHLORINATED DIBENZOFURANS, PCDFs)
CAS Preferred Nomenclature:
2,3,7,8-Tetrachloro-dibenzofuran,
2,3,7,8 TCDF
Empirical Formula: Ci2H4CUO
The polychlorinated dibenzofurans (PCDFs) are a group of 135 halogenated tricy-
clic aromatic hydrocarbons with many structural, distribution, and toxicity similar-
ities to the dioxins (polychlorinated dibenzodioxins, PCDDs). A partial list of the
furans is shown in Table 1. Very little is known about the individual furans because
they typically occur as mixtures of different forms. For this reason, the sources,
environmental fates and health effects of the PCDFs will be discussed as a group,
with mention of individual furans when appropriate.
REGULATORY STATUS
No criteria or standards established at present.
SOURCES OFPCDFs
PCDF Production and Use;
PCDFs are not intentionally produced for any commercial purposes.
PCDF-contamination of products or processes has not caused the banning or
restriction of use in the U.S.
Other Sources;
Just like the PCDDs, PCDFs are unwanted trace impurities of PCBs, chlorinated
phenols such as hexachlorobenzene or pentachlorophenol, and phenoxy herbicides
such as 2,4,5 T. The production of many of these compounds has been restricted
or banned (e.g., PCBs), but products containing them may still be in use (e.g.,
electrical transformers). Example concentrations are listed below:
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- Phenoxy herbicides had 0.008-0.15 mg/kg PCDFs (Rappe £l al., 1978,1979;
Ahlingfiiai, 1977).
- Pentachlorophenol has contained 59.8-790 mg/kg PCDFs (Rappe el aL, 1979).
- Hexachlorobenzene was found to contain 0.35 to 58.3 mg/kg PCDFs
(VillanuevaelaL, 1974).
- PCDF contaminants in polychlorinated biphenyls (PCBs) have been measured
at levels of 0.8 to 13.6 mg/kg (CNRC, 1978). 2,3,7,8 TCDF and 2,3,4,7,8
PeCDF are generally found at < 1 ppm in most PCBs (U.S. EPA, 1986).
Incineration of municipal and industrial wastes at too low a temperature (< 800 °C)
can produce PCDFs which can be released to the environment either in flue gas or
adsorbed to fly ash (U.S. EPA, 1986).
FATE OF PCDFs IN ENVIRONMENT
Partitioning
i
As shown in Table 1,2,3,7,8 TCDF is the only PCDF for which a number of physical
and chemical properties have been determined. Based on these properties, and its
structural similarity to the dioxin 2^,7,8, TCDD, 2,3,7,8 TCDF is likely to be only
slightly soluble in water and strongly sorb to soil (Kows 660,700). It also has a high
potential for bioaccumulation based on an estimated BCF of 602,600 (Hansch and
Leo, 1981).
Persistence;
Because 2,3,7,8 TCDF strongly sorbs to sediments, it persists in soils and aquatic
systems. Some photodegradation can occur with tetra- and penta-CDFs losing
chlorine atoms and forming tri-CDFs. For example, irradiation (254 nm) of 1/ug/L'
2^,7,8 TCDF in n-hexane for four hours yielded 2,3,8 and 2,3,7 TrCDF (Mazer and
Hileman, 1982).
- Very little is known about the biodegradation of PCDFs, but they are probably nice
the dioxins and relatively resistant to biodegradation (U.S. EPA, 1986).
HEALTH EFFECTS
PCDF Effects on Animals:
Toxicological studies of PCDFs demonstrate that the effects of this group of
compounds are remarkably similar to the PCDDs (U.S. EPA, 1986) (see "Dioxin:
2,3,7,8 TCDD", "1,2,3,7,8 PeCDD" or "HxCDDs" for more information on dioxins).
At present only short-term, high dose, acute exposure animal tests have been
conducted with PCDFs. The most studied form has been 2,3,7,8 TCDF which
C-20
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causes adverse health effects very similar to those caused by 2,3,7,8 TCDD. These
effects include weight loss, liver, thymus and immune system damage, and skin
changes (U.S. EPA, 1986).
Two of three monkeys died after six months of exposure to 5 g/kg 2,3,7,8 TCDF in
their food (U.S. EPA, 1986).
PCDF Effects on Humans:
Human exposure to PCDFs occurred in two major incidents when PCBs (containing
a mixture of PCDFs) accidently contaminated rice oil in Japan and China. The
resulting symptoms (attributed to 2,3,4,7,8 PeCDF exposure) consisted of liver
disturbances, skin lesions, excessive skin pigmentation, temporary blindness, numb-
ness of feet and hands, and weakness (Kuratsuneeial., 1972;Kuratsune, 1975,1980;
Urabe and Asahi, 1985; Lu and Wu, 1985; Hsu el al, 1985).
Studies of potential carcinogenesis in humans are still ongoing. No tests have been
conducted with animals (U.S. EPA, 1986).
Reproductive Effects;
2^,4,7,8 PeCDF, 1,2^,7,8 PeCDF and 1,2^,4,7,8 HxCDF can cause kidney damage
and cleft palate in mice fetuses (U.S. EPA, 1986).
Mutagenic Activity;
The four PCDFs (2,8 DCDF, 3,6 DCDF, 2,3,7,8 TCDF and OCDF) tested for
mutagenicity in bacteria had negative results (U.S. EPA, 1986).
Toxicological Effects Indices;
Reference Dose (RfD), 2^,7,8 TCDF: 2xlO~5/< g/kg/day (U.S. EPA, 1986).
Reference Dose (RfD), 2^,4,7,8 PeCDF: 3\10'6/i g/kg/day (U.S. EPA, 1986).
Oral LD50 values for 2,3,7,8 TCDF: guinea pigs, 5-10 n g/kg; mice and rats, > 6000
H g/kg; rhesus monkey, 1000 p. g/kg (U.S. EPA, 1986).
C-21
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REFERENCES
Ahling, B., A. Lindskog, B. Jansson and G. Sundstrom. 1977. Formation of Polychlorinated
Dibenzo-p-dioxins and Dibenzofurans during Combustion of a 2,4,5-T Formulation.
Chemospher. &461-468.
CNRC (Canadian National Research Council). 1978. Polychlorinated Biphenyls: Biological
Criteria for an Assessment of their Effects on Environment Quality. Publ. No. 16077.
NRCC/CNRC, Ottawa.
Hansch, C. and AJ. Leo. 1981. Log P Software Program for Med-Chem Project, Pomona
College, California.
Hsu, S.T., C.I. Ma, and S.K.H. Hsu. 1985. Discovery and Epidemiology of PCB Poisoning in
Taiwan. A Four-Year Follow-up. Environ. Health Perspect. 52:5.
Kuratsune, M.,T.Yoshimara,J.Matsuzaka and A. Yamaguchi. 1972. Epidemiological Study
on Yusho; a Poisoning Caused by Ingestion of Rice Oil Contaminated with a Commercial
Brand of Polychlorinated Biphenyls. Environ. Health Perspect. 1:119-128.
Kuratsune, M. 1975. National Conference Polychlorinated Biphenyls. Chicago. November
19-21,1975. EPA 560/6-75-004.
Kuratsune, M. 1980. Yusho. In: Halogenated Biphenyls, Terphenyls, Naphthalenes,
Dibenzodioxins and Related Products. (R.D. Kimbrough, ed.) Elsevier, Amsterdam.
Lu, Y.C. and Y.C Wu. 1985. Clinical Findings and Immunological Abnormalites in Yu-
Cheng Patients. Environ. Health Perspect. 52:17.
Mazer, T. and F.D. Hileman. 1982. The Ultraviolet Photolysis of Tetra-Chlorodibenzofurans.
Chemospher. 11:651-661.
Rappe, C., A. Gara and H.R. Buser. 1978. Identification of Polychlorinated Dibenzofurans
(PCDFs) in Commercial Chlorophenol Formulations. Chemospher. 2:981-991.
Rappe, C, H.R. Buser and H-P. Bosshardt. 1979. Dioxins, Dibenzofurans and Other Poly-
halogenatedAromatics: Production, Use, Formation, and Destruction. Ann. N.Y. Acad. Sci.
220:1-18.
Urabe, H. and M. Asahi, 1985. Past and Current Dermatological Status of Yusho Patients.
Environ. Health Perspect. 52:11.
U.S. EPA. 1986. Review Draft. Health Assessment Document for Polychlorinated
Dibenzofurans. Environmental Criteria and Assessment Office, Cincinnati, OH. EPA/600/8-
86/018 A.
C-22
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Villanueva, E.C., R.W. Jennings, V.W. Burse and R.D. Kimbrough. 1974. Evidence of
Chlorodibenzo-p-dioxin and Chlorodibenzofiuan in Hexachlorobenzene. J. Agric. Food
Chem. 22(5^:916-917.
C-23
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C-24
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BIPHENYL
CAS No.: 92-52-4
CAS Preferred Nomenclature:
1,1-Biphenyl
Empirical Formula: Ci2Hio
Synonyms and Common Names:
- Bibenzene - 1,1-Biphenyl
- Diphenyl - Phenylbenzene
C12H10
REGULATORY STATUS
Standards and Criteria:
o EPA Water Quality Criteria (for
human consumption offish):
None established at present
e EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Adviso-
ries:
None established at present
EPA Tolerance Level for Citrus Fruit
(40CFR180.141):
HOppm
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
None found.
Total Biphenyl Produced:
SOURCES OF BIPHENYL
Commercial production of biphenyl began in 1926 (Verschueren, 1983). In 1976,
approximately 88 million pounds of biphenyl were produced (Kirk-Othmer, 1982).
However, in 1984, production decreased to approximately 35 million pounds
(USITC, 1985). In 1986, four companies were producing biphenyl: Bethlehem
Steel Corporation, Dow Chemical, Monsanto Company, and Sybron Corporation.
C-25
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Uses of Biphenyl;
Biphenyl is used as a textile dye carrier, heat exchange medium, hydraulic fluid
component, and as a plasticizer (Kirk-Othmer, 1982). It is also used during pack-
aging, storage, and transport as a citrus wrapper fungicide to control mycelial growth
and spore formation of blue, green, and stem rot molds. Biphenyl is used primarily
on grapefruit, lemons, and oranges (Farm Chemicals Handbook, 1985; Thomson,
1985; Worthing, 1979).
Biphenyl is the basic structural unit for the production of polychlorinated biphenyls
(PCBs) (Waid, 1986) and is a breakdown product of PCBs.
Other Sources;
Biphenyl is also a by-product of benzene production. About 1 kg is generated for
every 100 kg of benzene (Verschueren, 1983).
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, biphenyl is soluble in water (Aq. Sol. =
7.5 mg/1), highly volatile (H estimated as 0.027 atm m3/mol), and strongly sorbed
to organic matter (Kow = 12,300). Biphenyl has a moderate potential for
bioaccumulation (BCF s500).
Persistence;
Biphenyl is biodegradable. Acclimation can significantly increase the biotransfor-
mation rate. For example, in fresh sewage no degradation occurred after 24 hours,
whereas, in acclimated sewage, 87 percent was degraded after 24 hours (Ver-
schueren, 1983). In river water at 20°C, 50 percent of initial biphenyl concentra-
tions from 1 to IQQfigfL were degraded after 1.5 to 3 days. This corresponds to a
degradation rate of 0.46/day to 0.92/day (Bailey, el aL, 1983).
The volatilization half-life in deep water was found to be 7.52 hours (Bailey el aL,
1983).
HEALTH EFFECTS
Carcinogenicity;
Papilloma and squamous cell tumors of the forestomach were observed in rats
(Clayton and Clayton, 1981-1982).
C-26
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The carcinogenic potential of this compound has not been evaluated by IARC or
theU.S.EPA.
Mutagenic Activity;
Biphenyl produced chromosome damage (sister chromatid exchange) in hamster
fibroblast cells (Sax, 1984).
Reproductive Effects;
No effect was observed in rats fed biphenyl during fetal development (Shepard,
1980).
Other Toncological Effects;,
Repeated exposure to dust may result in irritation of human skin and the respiratory
tract.
Chronic (long-term, low dose) exposure may affect the central nervous system
causing symptoms such as fatigue, headache, tremors, insomnia, sensory impair-
ment, and mood changes (Sittig, 1985).
Brain damage and nerve degeneration were reported in workers exposed to biphe-
nyl (Gosselin, 1984).
lexicological Effects Indices;
Reference Dose (RfD): 5 x 10~2 mg/kg/day (PHRED, 1988).
TWA-TLV (time-weighted average, threshold limit value) for occupational expo-
sure: 0.2 ppm (1.5 mg/m3) (ACGffl, 1986).
Oral LDso: rat, 328 g/kg; rabbit, 2.41 g/kg (Gosselin, 1984).
C-27
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C: t
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm«m3/mol):
154.2
solid, light tan flakes
69-71
254-255
1.18 @4°C
N/A
1(70°C)
0.027 (calc.)
Log (Octanol-Water Partition Coefficient),
logKow: 4.09
Soil Adsorption Coefficient,
Koc(ml/g):
Fish Bioconcentration Factor, BCF:
4.4xl03(calc.)
590 (calc.)
437 (exptl.)*
Verschueren, 1983
Hartley &Kidd, 1983
Hartley &Kidd, 1983
Verschueren, 1983
Verschueren, 1983
Hartley &Kidd, 1983
Lymanfilal., 1982
Leo, 1983
Lymanfilal., 1982
Lymanfilal., 1982
Verschueren, 1983
Value used for estimating aquatic effects
C-28
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REFERENCES
t
ACGIH (American Conference for Governmental Industrial Hygienist). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Bailey, R.E., S.J. Gonsior, and W.L. Rhinehart. 1983. Biodegradation of the
Monochlorobiphenyls and Biphenyl in River Water. Environ. Sci. Technol. 17_(10):621-624.
Clayton, G.D. and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed., Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, New York.
\
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
Kirk-Qthmer Encyclopedia of Chemical Technology. 1984. 3rd ed. John Wiley and Sons, Inc.
New York.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Poult's Toxicology. The
Basic Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Leo,AJ. 1983. Log P Parameter Database, Pomona College, Qaremont, California.
Lyman, W J. ed. 1982. Handbook of Chemical Property Estimation Methods. McGraw-Hill,
New York. 977 p.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. EPA, Office of Emergency
and Remedial Response, Washington, D.C.
Reynolds, J.E.F. and A.B. Prasad, eds. 1982. Martindale! The Extra Pharmacopeia. 28th ed.
The Pharmaceutical Press, London.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Shepard,T.H. 1980. Catalog of Teratogenic Agents. 3rded. The Johns Hopkins University
Press, Baltimore.
Sittig, M., ed. 1985. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nd ed.
Noyes Publications, Park Ridge, NJ.
C-29
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Thomson, W.T. 1985. Agricultural Chemicals Book IV - Fungicide. 1985 revision.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. Office of Solid Waste and
Emergency Response, Washington, D.C. EPA-540/1-86/060.
U.S. International Trade Commission (USTIC). 1985. Synthetic Organic Chemicals. United
States production and sales. 1984. U.S. Government Printing Office, Washington, D.C.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Waid, J.S., ed. 1986. PCBs and the Environment. CRC Press. Boca Raton, FL.
Worthing, C.R., ed. 1979. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-30
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CHLORDANE
CAS No.: 57-74-9 (combined form)
5103-74-2 (trans- form)
5103-71-9 (cis-form)
CAS Preferred Nomenclature:
4,7-Methano-lH-indene
1,2,4,5,6,7,8,8-octachloro-
2,3,3a,4,7,7a-hexahydro
Empirical Formula: CioHeClg, occurs in cis and trans forms
Synonyms and Common Names:
- ChlorKil - Chlorindan
- Corodan - Dowchlor
- Kypchlor - Niran
- Octa-Klor - Topiclor
- Oktaterr - Ortho-Klor
- Synklor - Octachlorodi-hydrodicyclopentadiene
- Torichlor - Velsicol 1068
REGULATORY STATUS
a
C,0H6CI8
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish) for a 10H
cancer risk (U.S. EPA, 1986b):
0.48 ng/L
EPA Ambient Water Quality Criteria «
(for protection of aquatic or-
ganisms)(IRIS, 1989):
Freshwater Saltwater
Chronic/* g/L 4.3xlO"3 4.0x10*
Acute,/* g/L 2.4 9.0xlO"2
EPA Drinking Water Health Ad-
visories (IRIS, 1989)
jMd_(10kg):
1-day exposure = 60 p g/L
10-day exposure = 60/* g/L
longer-term exposure = 0.5 A g/L
adiilL(70kg):
longer-term exposure = 2/* g/L
EPA Tolerance Levels for Raw
Agricultural Commodities (51FR
46668):
All tolerances revoked, 12/24/86
C-31
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EPA Drinking Water Standard Food and Drug Administration Ac-
(50FR 4696): tion Level for Fish (55 FR 14361):
Proposed Maximum Contaminant 0.3 ppm ,
Level = 0.002 mg/L Action Level for Other Food
Proposed Maximum Contaminant 0.1 to 0.1 to 0.3 ppm
Level Goal = 0 mg/L
FDA Action Levels are for use in
interstate commerce.
Use Restrictions and Bans;
All uses except subsurface ground insertion for termite control cancelled in 1987.
All other uses except the dipping of roots or tops of nonfood plants were cancelled
in 1978, although some uses were phased out gradually through 1983 (43 FR 12372).
Limited sales, distribution and use of existing stocks of chlordane products allowed,
with the requirement that all applications must be done by a licensed applicator
(1987,52 FR 42145).
SOURCES OF CHLORDANE
Total Chlordane Produced;
In 1971, 25 million Ibs. were produced by Velsicol Chemical Co. (Ouellette and
King, 1977). In 1974, production had decreased to 22 million Ibs. (U.S. EPA, 1980).
Most uses phased out between 1978 and 1980. Velsicol Corp. is still the only U.S.
producer (U.S. EPA, 1986b).
Oxychlordane, although not found in technical-grade chlordane, is a major meta-
bolic product of chlordane. It has comparable toxic effects (see Oxychlordane
profile) (Barnett and Dorough, 1974).
Uses of Chlordane;
» Chlordane is a chlorinated hydrocarbon originally registered as a pesticide in 1948.
Prior to cancellation in 1980, it was used for control of ants, cutworms, grasshoppers,
and other insects for corn, grapes, strawberries and other crops (Hartley and Kidd,
1987).
Until, 1987, chlordane was used as a dip for nonfood roots and tips of plants.
Currently, the only authorized use is for subsurface termite fumigation (52 FR
42145,11730/87).
* For a combination of cis- and trans-chlordane, cis- and trans-nonachlor, heptachlor, heptachlor eporide,
Oxychlordane, chlordene, and a -, ft and y chlordene.
C-32
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FATE IN ENVIRONMENT
Partitioning:
Based on its physical/chemical properties, chlordane is moderately volatile (H =
9.6x10 atm m /mole), sorbs moderately to soil (Kow = 2,100), and has a high
potential for bioaccumulation (BCF = 14,000).
Persistence:
The cis- form of chlordane can hydrolyze under alkaline conditions (Kb = 4.3x10
mol/hr). The trans- form did not hydrolyze at pH 3,7 or 11 during the 5-day duration
of the experiments (Ellington el aL, 1987). Chlordane can undergo photolysis in
the presence of photosensitizers. One degradation product is photo-cis-chlordane
(more toxic to some animals and can be bioaccumulated (IRIS, 1989)). Little
information is available on the biotransfonnation of chlordane in aquatic systems.
The half-life is estimated to be about 1 year (Hartley and Kidd, 1987).
HEALTH EFFECTS
Carcinogenicity;
Chlordane administered orally has been shown to cause liver carcinomas in mice
and rats of both sexes (IRIS, 1989; Williams ejtaL, 1984). The EPA classification is
B2, a probable human carcinogen (IARC Class 2-b) (IARC, 1979; IRIS, 1989).
Mutagenic Activity:
Tests with chlordane in cultured mammalian cells has shown it to be mutagenic.
Results have been negative, however, in mouse and bacterial tests. Chlordane has
induced gene conversions in yeast. (U.S. EPA, 1984; IRIS, 1989).
Reproductive Effects;
Orally-administered chlordane was not fetotoxic or teratogenic to rat offspring. It
did cause decreased fertility in both sexes for rats and in female mice. The viability
of mice and rat offspring was also decreased (U.S. EPA, 1984).
Other Toxicological Effects;
Acute (short-term, high dose) poisoning effects are due to chlordane neurotoxicity
and can result in hyperextitability, convulsions, depression, muscle tremors, coma
and possible death (U.S. EPA, 1984). Chronic (long-term, low-dose) exposure can
C-33
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result in liver tenacity and blood disorders such as anemia (U.S. EPA, 1984).
Chronic chlordane exposure causes liver disease in rats, mice, and dogs (IRIS, 1989;
TDB, 1985-1986).
lexicological Effects Indices;
Cancer potency factor (CPF) = 1.3 (mg/kg/day)"1 (IRIS, 1989)
Concentration
Cancer Risk Level in Drinking Water (IRIS. 1989)
lin 10,000 . 3^ g/L
1 in 100,000 0.3 ft g/L
lin 1,000,000 0.03ft g/L
Reference Dose (RfD) for non-carcinogenic effects: 6xlO's mg/kg/day
(IRIS, 1989)
TWA-TLV (Time-weighted average, threshold limit value for occupational expo-
sures): 0.5 mg/m3 for skin exposure (ACGffl, 1986).
C-34
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Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
PHYSICAL/CHEMICAL PROPERTIES
Value
409.8
pure-solid;
technical grade-
amber viscous liquid
Boiling Point (°C):
Specific Gravity:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Henry's Law Constant H @
25°C (atm m3/mol):
Hydrolysis Rates:
Octanol-Water Partition
Coefficient, log Kow:
Org. Carbon Adsorption
Coefficient, Koc (ml/g):
Fish Bioconcentration
Factor,.BCF:
103.0-105.0 (cis)
107.0-108.8 (trans-)
175
L56-LS7
0.056-1.85
lx!0'5(25°C)
9.dxlO'5
trans-: no
degradation in 5 days
cis-: Kb - 4.3xlO'3/
mol/hr
3.32
1.4X105
1.4xl04*
Reference
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
U.S. EPA, 1986b
CallahaneiaL, 1979
US. EPA, 1986b
Ellington eiaL,
1987
U.S. EPA, 1986b
U.S. EPA, 1986b
U.S. EPA, 1986b
U.S. EPA, 1980
Value used for estimating aquatic effects
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienlsts). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Barnett, J.R. and H.W. Borough. 1974. Metabolism of Chlordane in Rats. J. Agric. Food
Chem. 22:612-619
Hartley, D. and Kidd, eds. 1987. Agrochemicals Handbook. Royal Society of Chemistry:
Nottingham, England.
Callahan, M.A., M.W. Slimak, N.W. Gabel, LP. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C Whitmore,-B. Maestri, WJl. Mabey, B.R. Holt, and C Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. I. Office of Water Plan-
ning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Ellington, JJ., F.E. Stancil, Jr., W.D. Payne, and C. Trusty. 1987. Measurement of Hydrolysis
Rate Constants for Evaluation of Hazardous Waste Land Disposal: Volume 2: Data on 54
Chemicals. U.S. Environmental Protection Agency, Athens, Georgia.' EPA Report No.
EPA/600/3-87/019.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
Integrated Risk Information System (IRIS). 1989. Chlordane. U.S. Environmental Protec-
tion Agency. Last Updated 2/10/88. <.:.
Ouellette, R.P. and J A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill
Book Co., New York.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S.EPA. 1980. Ambient Water Quality Criteria for Chlordane. Office of Water Regulations
and Standards, Criteria and Standards Division. EPA-440/5-8-027.
U.S. EPA. 1984. Health Effects Assessment for Chlordane. Office of Research and Devel-
opment, Cincinnati, OH. EPA-540/1-86-023.
U.S. EPA. 1986a. Pesticide Fact Sheet #109, Chlordane.
U.S.EPA. 1986b. Superfund Public Health Evaluation Manual. U.S. EPA Office of Solid
Waste and Emergency Response, Washington, D.C. EPA-540/1-86/060.
C-36
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Williams, G.M. and S. Numoto. 1984. Promotion of Mouse liver Neoplasmas by the Organo-
chlorine Pesticides Chlordane and Heptachlor in Comparison to Dichlorodi-
phenyltrichloroethane. Carcinogenesis 1:1689-1696.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicalsr Drugs,, and
Biologicals. 10th ed. Merck and Co., Rahway, New Jersey.
C-37
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CHLORDANE, HEPTACHLOR, OXYCHLORDANE AND RELATED COMPOUNDS
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
There are several components in technical grade chlordane. Active ingredients include
chlordane, tis-chlordane, trans-chlordane, trans-nonachlor, and heptachlor (Stickel si al.
1979). The metabolic products of chlordane are oxychlordane, chlordane isomers, glucuron-
ides and heptachlor (Newell el at 1987).
Technical grade heptachlor contains heptachlor, trans-chlordane and cis-chlordane (Stickel
fit aL 1979). Heptachlor metabolizes to heptachlor epoxide (U.S. EPA 1980, as cited in
NeweU).
Stickel fital (1979) investigated the lethal levels of chlordane and the metabolites oxychlord-
ane and heptachlor epoxide in several bird species. The lethal level of heptachlor epoxide in
the brains of heptachlor fed birds was 8 ppm wet weight. In oxychlordane fed birds, the lethal
level of oxychlordane was 5 ppm wet weight. However, chlordane compounds exhibit an
additive effect. For birds that were fed chlordane, Stickel fit al. (1979) found that the lethal
levels of heptachlor epoxide and oxychlordane in the brain were only about 28 percent of the
concentrations listed above.
Chlordane components and metabolites have been detected in several fish-eating bird species.
Two hundred twenty eggs were randomly collected from black-crowned night-herons in the
intennountaln western United States between 1978 and 1980. Oxychlordane was detected in
35 percent of the eggs. Over 27 percent had heptachlor epoxide residues. Cis-chlordane was
detected in 16 percent. Trans-nonachlor was found in 25 percent, and cis-nonachlor was
present in 6 percent of the eggs (Henny £t al 1984).
Ohlendorf fit aL (1981) collected individuals of various species of herons nationwide and
analyzed them for organochlorines. Most of the birds were found either dead or moribund.
The highest concentration of heptachlor epoxide (1.9 ppm), oxychlordane (0.87 ppm), and
trans-nonachlor (1.1 ppm in the brain), were found in a great blue heron that apparently died
from dieldrin.
Residues of these contaminants were also detected in a high percentage of dead or dying
ospreys collected from the eastern United States from 1975 to 1985 (Wiemeyer ei at 1987).
Cis-chlordane was detected in 52 percent of the ospreys. Trans-nonachlor was detected in 45
percent. Concentrations of oxychlordane and cis-nonachlor were found in thirty-five percent
of the birds, while 13 percent had detectable levels of heptachlor epoxide.
The State of New York proposed piscivorous wildlife dietary criteria for chlordane (0.5 ppm),
and for heptachlor epoxide (0.2 ppm) (Newell fit al 1987). These general criteria were
established based on existing studies with factors of uncertainty taken into account.
The effects of chlordane, oxychlordane, and heptachlor epoxide on piscivorous wildlife are
summarized in the following table:
C-38
-------
Effects of Chlordane* Concentrations on Piscivorous Wildlife
Animal
Concentration
Effect
Source
Chlnrdane
Piscivorous
Wildlife 0.5 ppm (diet)
0.37 ppm (diet)
Heptachlnr Epnxide
Birds
Piscivorous
Wildlife
8 ppm (brain)
0.2 ppm (diet)
Estimated
NOEL
cancer risk
oflO'2
death
Estimated
NOEL
Newell eiaL, 1987
Newell el al., 1987
0.21 ppm (diet) cancer risk
of 10
,-2
StickelelaL, 1979
Newell el aL, 1987
Newell el al., 1987
Qxvchlordane
StickelelaL, 1979
Birds 5 ppm (brain) death
'Chlordane, heptachlor epoxide, and oxychlordane
REFERENCES
Henny, CJ., LJ. Blus, AJ. Krynitsky, and CM. Bunck. 1984. Current impact of DDE on
black-crowned night-herons in the intermountain west. J. Wildl. Manage. 48(1) 1-13.
Khasawinah, A.M. 1982. Metabolism of chlordane/heptachlor in animals. Prepared for the
Velsicol Chemical Corp., Chicago (unpubl.) (as cited in Newell el aL 1987).
Newell, AJ., D.W. Johnson and L.K. Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection..
Ohlendorf, H.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine residues and
mortality of herons. Pest. Monit. J. 14(4) 125-135.
C-39
-------
Stickel, L.F., W.H. Stickel,R.D. McArthur, and D.L. Hughes. 1979. Chlordane in birds: a
study of lethal residues and loss rates, in Toxicology and Occupational Medicine, organizer
W.B. Deichman, Elsevier/North Holland, New York, NY.
U.S. EPA (Environmental Protection Agency). 1980. Ambient water quality criteria for
heptachlor. EPA 440/5-80-052, USEPA, Wash., D.C
Wiemeyer, S. N., S.K. Schmeling and A Anderson. 1987. Environmental pollutant and
necropsy data for ospreys from the eastern United States, 1975-1982. J. Wildl. Diseases, 23(2)
279-291.
C-40
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CHLORPYRIFOS
CAS No.: 2921-88-2
CAS Preferred Nomenclature:
Phosphorothioic acid, 0,0-diethyl
o-(3,5,6-trichloro-2-pyridinyl) ester
Empirical Formula: C9HnCl3NO3PS
Synonyms and Common Names:
- Dursban - Eradex
- Lorsban - Pyrinex
- Brodan
ci
'
C9H11CI3N03PS
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption offish):
None established at present
EPA Drinking Water Health Adviso-
ries:
None established at present
EPA Ambient Water Quality Criteria EPA Tolerance Levels (40 CFR
(for protection of aquatic organisms)
(U.S. EPA, 1986):
Freshwater Saltwater
Acute, n g/L 0.083 0.041
Chronic, ,u g/L 0.041 0.0056
185.1000):
mint oil = 10 ppm
citrus oil = 25 ppm
other listed commodities = 0.05 to 5
ppm
EPA Drinking Water Standard Maxi- Food and Drug Administration Ac-
mum Contaminant Level: tion Level for Fish:
None established at present None established at present
Use Restrictions and Bans:
Current labelling states that it is not to be applied directly to water bodies (U.S.
EPA, 1986).
Meat or dairy animals are not allowed to graze in treated orchards.
Treated seeds are not to be used for human consumption, as a feed for livestock or
poultry, or for grains to be used in making oils.
C-41
-------
SOURCES OF CHLORPYR1FOS
Total Chlorpyrifos Produced;
In 1982 about 3,500 tons were used as an insecticide (Green £i al, 1987).
Developed during the 1960s by Dow Chemical (Midland, Michigan) to replace the
more persistent organochlorine pesticides (e.g. DDT)(SRI, 1986; U.S. EPA, 1986).
Uses of Chlorpyrifos;
Chlorpyrifos is an organophosphate insecticide developed in the 1960s to replace
the environmentally persistent organochlorine pesticides (e.g., DDT).
It has been used for a broad range of insecticidal applications, including mosquitoes,
flies, household pests and aquatic larvae.
Primarily, it is used to control soil and foliar insect pests on cotton, peanuts and
sorghum (Worthing, 1983; U.S. EPA, 1986).
Chlorpyrifos is also used to control root-infesting and boring insects on a variety of
fruits (e.g., citrus crops, apples, bananas, peaches, grapes, nectarines), nuts (e.g.,
almonds, walnuts), vegetables (e.g., beans, broccoli, brussel sprouts, cauliflower,
soybeans, cabbage, peas) and field crop (e.g., alfalfa and corn)(U.S. EPA, 1984).
As a household insecticide it has been used to control ants, cockroaches, fleas, and
mosquitos (Worthing, 1983).
Chlorpyrifos is registered for use in controlling subsurface termites in California
(U.S. EPA, 1983).
It is also used to control ticks on cattle and sheep (Thomson, 1985).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
Based upon its physical/chemical properties, Chlorpyrifos has a low volatility (H =
6.7x10 atm m /mol), and a moderate potential for bioaccumulation
(BCF=470). Chlorpyrifos is predicted to have an intermediate volatilization rate
from surface soil (P/SKoc = 6.9x10 mm Hg L/mg corresponding to an
estimated volatilization half-life of 23 days) (Lyman el al, 1982).
C-42
-------
Chlorpyrifos is hydrophobic (i.e., has an affinity for organic soils), rapidly sorbs to
suspended organics and sediments in aquatic systems (Kow = 128,800), and remains
stable for long periods of time (U.S. EPA, 1986).
McCall (1986) reported intermediate soil/water partition coefficients (Ks) of 50,
66, and 100 for chlorpyrifos adsorbed to a loam soil (organic carbon 0.68 percent),
a sandy loam soil (organic carbon 1.1 percent), and a silt loam soil (organic carbon
2.0 percent), respectively. In soil column studies, using 30 cm columns, approxi-
mately 5 percent of the chlorpyrifos applied leached below the top 5 cm of loam
soil, but less than 1 percent leached below the top 5 cm of sandy loam and silt loam
soils leached with 20 in. of water at a rate of 1 ml/hr.
Murphy and Lutenske (1986) reported a high steady state BCF of 1.4xl03 for
chlorpyrifos in rainbow trout.
Persistence:
The hydrolysis half-life for chlorpyrifos in buffered, distilled water at 25°C was
found to be 22.8,35.3 and 62.7 days at pH 8.1,6.9 and 4.7, respectively; the rate was
enhanced 16-fold in canal and pond water at 25°C (Verschueren, 1983). McCall
(1986) reported relatively long to intermediate hydrolysis half-lives (25°C) for
chlorpyrifos of 72.8 days at pH 5,72.1 days at pH 7, and 15.8 days at pH 9. Hydrolysis
products are 3,5,6-trichloro-2-pyridinol and O-ethyl O-(3,5,6-trichloro-2-pyridyl)
phosphorothioate. Macalady and Wolfe (1985) observed hydrolysis half-lives rang-
ing from 12-68 days in pond and river water.
Photolysis of chlorpyrifos can occur as evidenced by the following experimental
data. Fontaine and Teeter (1987) reported a relatively short half-life of 2.6 days for
chlorpyrifos in air exposed to artificial light with a comparable but less intense
irradiation spectrum to that of sunlight. Yackovich and Miller (1984) reported
relatively short 50 percent dissipation times of 3-to 6 days for chlorpyrifos on loam
soil irradiated with > 290 nm artificial light compared to a 50 percent dissipation
time of 12 days on loam soil incubated in the dark.
Bidlack (1979) reported intermediate to relatively long 50 percent dissipation times
of 11 to 141 days (averaging 63 days) for chlorpyrifos incubated in 7 different soils
under aerobic conditions. McCall (1985) reported a 50 percent dissipation time of
7 to 10 days for chlorpyrifos incubated in a sandy loam soil under aerobic conditions.
Bidlack (1979) reported 50 percent dissipation times of 15 and 58 days for
chlorpyrifos incubated under anaerobic conditions in a loam soil and in a clay soil,
respectively.
C-43
-------
HEALTH EFFECTS
Carcinogenicity;
Studies with rats, mice and dogs demonstrated no carcinogenicity (U.S. EPA, 1983).
Mutagenic Activity:
Bacterial mutagenicity tests were negative (U.S. EPA, 1983).
Reproductive Effects;
No teratogenic or fetotoxic effects in mice or rats (IRIS, 1989).
Other lexicological Effects;
Chlorpyrifos, in a manner similar to other organophosphate pesticides, interferes
with the nerve-muscle relationship by inhibiting the enzyme cholinesterase. With-
out cholinesterase, the neurotransmitter acetylcholine accumulates at nerve-mus-
. cle junctions andinterferes with muscle coordination (Green elal., 1986; U.S. EPA,
1986).
Acute (high-dose, short-term) poisoning can produce a variety of symptoms includ-
ing weakness, blurred vision, nausea, diarrhea, wheezing, tremors, psychosis, con-
vulsions, paralysis, coma, and death (Klaassen £l al., 1986; U.S. EPA, 1983,1986).
It is rapidly detoxified in rats and dogs (Worthing, 1983).
lexicological Effects Indices;
Reference Dose (RfD): 3 x 10"3 mg/kg/day (IRIS, 1989).
TWA-TLV (time-weighted average, threshold limit value) for occupational skin
exposure: 0.2 mg/m3 (ACGIH, 1986).
. Oral LDso: rats, 82-245 mg/kg (U.S. EPA, 1983).
C-44
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm m/mol):
351
solid, white
granules -
42-43.5
N/A
1.398 @ 43.5°C
(liquid)
N/A
2(25°C)
1.87xlO'5(25°C)
6.7xlO'6
Log (Octanol-Water Partition Coefficient),
logKow: 5.11
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration
Factor, BCF:
13,600
470
450 (exptl.)'
U.S. EPA, 1983
Farm Chemicals
Handbook, 1987
Hartley & Kidd, 1983
Verschueren, 1983
Hartley & Kidd, 1983
McCall, 1983
McCall, 1983
Leo, 1983
Kenaga, 1980
McCall, 1983;
Kenaga, 1980
* Value used for estimating aquatic effects
C-45
-------
REFERENCES
*
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Bidlack, H.D. 1979. Degradation of Chlorpyrifos in Soil Under Aerobic, Aerobic/Anaerobic,
and Anaerobic Conditions. Dow Chemical Co. Asc. #256041.
Farm Chemicals Handbook. 1987. Meister Publishing Co., Willoughby, OH.
Fontaine, D.D. and Teeter, D. 1987. Photodegradation of Chlorpyrifos in the Vapor Phase.
Report #GH-C-1911. Dow Chemical Co. and ABC Laboratories.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop
Improvement and Pest Management. 3rd ed. Pergamon Press, Oxford, England.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Kenaga, E.E. 1980. Correlation of bioconcentration factors of chemicals in aquatic and
terrestrial organisms with their physical and chemical properties. Environ. Sci. Technol.
14:553-556.
Klaassen C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology. The
Basic Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Leo, AJ. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
Medchem Project, Pomona College, Claremont, California.
Lyman, W.J., Reehl, W.F., and Rosenblatt, D.H. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co.
Macalady, D.L. and N.L. Wolfe. 1985. Effects of sediments sorption and abiotic hydrolysis.
1. organophosphorothionate esters. J. Agric. Food Chem. 22(2): 167-173.
McCall, P.R., el al., 1983. Estimation of Environmental Partitioning or Organic Chemicals in
Model Ecosystems. Residue Reviews. 82:231-244.
McCall, P.J. 1985. Column Leaching and Sorption Studies with Chlorpyrifos. Report GH-
C-1977. Dow Chemical Co. Ace. No. 260794.
McCall, P.J. 1985b. Chlorpyrifos Aged Column Leaching. Report GH-C-1778. Dow Chem-
ical Co.
C-46
-------
McCall, P.J. 1986. Hydrolysis of Chlorpyrifos in Dilute Aqueous Solution. Report GH-C-
1791.
Murphy, P.G. and Lutenske, N.E. 1986. Bioconcentration of Chlorpyrifos in Rainbow Trout.
Project #ES-928. Dow Chemical Co. Ace. No. 400564-01.
Stanford Research Institute (SRI) 1986. Directory of Chemical Producers. Standard Research
Institute, Menlo Park, California.
Thomson, W.T. 1985. Agricultural Chemicals Book I - Insecticide. 1985 revision.
U.S. EPA. 1983. Analysis of the Risks and Benefits of Seven Chemicals Used for Subterra-
nean Termite Control. EPA-540/9-83-005.
U.S. EPA. 1984. Registration Standard for Chlorpyrifos. Office of Pesticides.
U.S. EPA. 1986. Ambient Water Quality Criteria for Chlorpyrifos. EPA-440/5-86-005.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
Yackovich, P.R. and Miller, J.H. 1984. Photodegradation of Chlorpyrifos on Commerce Soil
Surface. Dow Chemical Co.
C-47
-------
C-48
-------
p,p'-DDE
CAS No.: 72-55-9
CAS Preferred Nomenclature:
Benzene,l,l'-(dichloroethenylidene)
This (4-chloro-
Empirical Formula: CwHgCU
Synonyms and Common Names:
- 4,4'-DDE
- p,p'-Dichlorodiphenyl dichloroethylene
- l,l-Dichloro-2,2-bis (p-chlorophenyl) - ethylene
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for EPA Drinking Water Health Adviso-
human consumption of fish) for a 10~6 ries:
combined (DDT and DDE) cancer None established at present
risk (U.S. EPA, 1980):
0.024 ng/L
EPA Ambient Water Quality Criteria Food and Drug Administration Ac-
(for protection of aquatic organisms) tion Level for Fish, combined (DDT,
DDT, TDE and DDE combined TDE and DDE) (55 FR 14361):"
(U.S. EPA, 1980): 5 ppm
Freshwater Saltwater
Acute,//g/L 1.1 LSxlO"1
Chronic, ^g/L l.OxlO"3 l.OxlO'3
EPA Drinking Water Standard Maxi- Food and Drug Administration Ac-
mum Contaminant Level: tion Levels for Other Foods:
None established at present 0.05 to 3 ppm
FDA Action Levels are for use in in-
terstate commerce
Use Restrictions and Bans: Not produced commercially.
C-49
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SOURCES OF DDE
Total DDE Produced:
DDE is a metabolic breakdown product of the insecticide DDT. DDT was first
synthesized in 1874 and was used as an insecticide starting in 1939. By 1961,1,200
formulations were available for use on 334 crops. Peak production was 180 million
pounds in 1963 (McEwen and Stephenson, 1979).
HEALTH EFFECTS
Carcinogenicity:
Liver tumors (hepatocellular carcinomas) observed in mice, but not in rats. IARC
Classification - 2b. (IARC, 1973; Sax, 1984; HSDB, 1988).
The U.S. EPA has classified DDE as a probable human carcinogen (B2) and is
presently reviewing experimental data in order to determine a cancer potency factor
(PHRED, 1988).
Mutagenic Activity;
Not mutagenic in bacterial assays, but weakly mutagenic in mouse lymphocytes and
cytogenetic analysis in rats (Sax, 1984; HSDB, 1988).
Reproductive Effects;
No data located on teratogenicity of DDE, but did not adversely affect lactation or
neonatal growth at maternal daily doses of 10 mg/kg (HSDB, 1988).
Other Toxicological Effects;
Causes liver damage in rats (Sax, 1984).
Toxicological Effects Indices;
. Cancer Potency Factor (CPF): 3.4X10"1 (mg/kg/day)'1 (IRIS, 1989).
Oral LDso: rat, 880-1240 mg/kg (Sax, 1984).
C-50
-------
PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant,
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm m3/mol):
Log (Octanol-Water Parti-
tion Coefficient), log Kow:
Value
318.0
solid
88-90
N/A
N/A
N/A
0.04 (20°C)
6.5X10"6 (20°C)
6.8x10
7.00
,-5
Soil Adsorption Coefficient, Koc(ml/g): 4.4xlOe
Fish Bioconcentration
Factor, BCF:
LSxlO5 (exptl.)
53,600 (calc)*
Reference
Callahaneial., 1979
Callahaneial, 1979
Callahaneial., 1979
PHRED, 1988
PHRED, 1983;
MabeyetaL, 1982
PHRED, 1988;
Mabeyfital, 1982
Verschueren, 1983;
PHRED; 1988;
Lymaneial, 1982
* Value used in estimating aquatic effects
C-51
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REFERENCES
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol I. Office of Water Planning
and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
HSDB. 1988. Hazardous Substances Data Base Computer Printout: p,p'-DDE. Retrieved
May 16,1988. Bethesda, MD: National Library of Medicine.
International Agency for Research on Cancer. 1973. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 5. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA. Washington, D.C.
Lyman, W.J., ed. 1982. Handbook of Chemical Property Estimation Methods. McGraw-Hill,
New York. 977 p.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W.
Partridge, HJaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, Inc., New York.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. EPA, Office of Emergency
and Remedial Response, Washington, D.C. *
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Singmaster, J.A., HI. 1975. Environmental Behavior of Hydrophobic Pollutants in Aqueous
Solutions. Ph.D. Thesis. Univ. California, Davis, Calif. 143pp. University of Microfilms, Ann
Arbor, Mich., Order No. 76-14,237. (Diss. Abstr. Int. B 1976,36(12, Pt. 1):6206-6207.
U.S. EPA. 1980. Office of Water Regulations and Standards. Ambient Water Quality
Criteria for DDT. Washington D.C.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 1 2nd ed.
Van Nostrand Reinhold, New York.
Zepp, R.G., N.L. Wolfe, J.A. Gordon, and R.C. Fincher. 1976. Light-Induced Transforma-
tions of Methoxychlor in Aquatic Systems. J. Agric. Food Chem. 24(4):727-733.
C-52
-------
Zepp, R.G. N.L. Wolfe, L.V. Azarraga, R.H. Coz, and C.W. Pape. 1977. Photochemical
Transformation of the DDT and Methoxychlor Degradation Products, DDE and DMDE, by
sunlight. Arch. Environ. Contain. Toxicol. &305-314.
C-53
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DDE
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
The use of the insecticide DDT was severely restricted in the United States in 1972. However,
the long-lived DDT and its metabolite, DDE, are still present in the tissue and eggs of many
fish eating birds.
The concentration of DDE residue in avian eggs is negatively correlated with reproductive
success. A study of black-crowned night-herons from 1978-80, determined that residues
greater than 1.0 ppm reduced eggshell thickness, and levels greater than 8.0 ppm reduce the
percentage of successful nests and clutch size, and increase the percentage of cracked eggs
(Henny el al. 1984). Almost 11 percent of eggs collected from nightherons in San Francisco
Bay in 1982 had concentrations of DDE above 8.0 pmm (Ohlendorf el al. 1988).
For the sensitive brown pelican, a concentration greater than 0.5 ppm in eggs was estimated
to cause eggshell thinning (Blus 1972, Blus el al. 1971). From this data, the EPA in 1976
estimated a NOEL for the eggs of the brown pelican at 2.0 ppm, with a corresponding dietary
NOEL of 0.2 ppm (Newell el al. 1987). More recently, the State of New York has also
proposed a fish flesh criterion of 0.2 ppm DDE to protect all piscivorous wildlife (Newell el
al. 1987).
DDE residues in eggs at concentrations high enough to affect reproductive success were
observed in herring gull eggs from the Great Lakes between 1974 and 1978 (mean of 21 ppm
for a Lake Ontario colony in 1974) (Weseloh £t al 1979). In Maine, differences in DDE
concentrations observed between the common eider, herring gull and black-backed gull were
attributed to differences in feeding habits (Szaro el al. 1979). The highest concentrations
(mean of 8.66 ppm) were detected in the eggs of black-backed gulls which are piscivorous and
have also been observed to eat carrion of marine mammals. The common eider, with the
lowest concentrations (mean of 0.23 ppm), feeds primarily on marine invertebrates.
DDE has also been detected in high concentrations (2.9 ppm) in eggs from the American
crocodile in the Florida Everglades (Hall el al 1979).
In birds, the lethal effect of DDE in the brain is estimated to be about 250 ppm (as cited in
Ohlendorf el aL 1981). Although DDE is often present in the brains of piscivorous birds, it is
seldom found at levels considered lethal.
Dead or moribund bald eagles were collected nationwide from 1971 to 1974 and analyzed for
organochlorine residues. Of the 101 specimens analyzed, DDE was detected in 97 percent of
the brains. However, only one death could possibly be attributed to DDE (230 ppm)
(Barbehenn and Reichel 1981).
In 1969 and 1973 in southern Ontario, ring-billed gulls found dead of no apparent disease were
analyzed for organochlorines. Most had DDE residues in the brain, although a lethal level
was detected in only one specimen (Stickel elal1984).
C-54
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Of twelve adult black-crowned night-herons found dead in 1980 and 1981 in Nevada, all had
DDE residues in the brain. Only one dead immature heron collected did not have a detectable
DDE residue in the brain (Henny el aL 1984).
The effects of DDE on piscivorous wildlife are summarized in the following table:
Effects of DDE Concentrations on Piscivorous Wildlife
Animal
Birds
Brown
Pelican
Brown
Pelican
Brown
Pelican
Black-crowned
Night-heron
Piscivorous
Wildlife
Concentration
250 ppm(brain)
> 0.5 ppm(egg)
>2.0ppm(egg)
>0.2ppm(diet)
l.Oppm(egg)
8.0 ppm (egg)
0.2 ppm (diet)
0.226 ppm
(diet)
Effect
death
eggshell
thinning
eggshell
eggshell
thinning
eggshell
thinning
reduced
clutch size
reduced percentage
of successful
nests
increased percentage
of cracked
eggs
estimated
NOEL
cancer risk
of 10'2
Source
Ohlendorf 1981
Blus 1972;
BlusfilaL 1971
U.S. EPA 1976
U.S. EPA 1976
Henny elal. 1984
Henny eial. 1984
Newell elal. 1987
Newell filal. 1987
C-55
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REFERENCES
Barbehenn, KR and W.L. Reichel. 1981. Organochlorine concentrations in bald eagles:
brain/body lipid relations and hazard evaluation. J. Toxicol. Environ. Health. 8:325-330.
Blus, L. 1972. Further analysis of the logarithmic relationship of DDE residues to nest success.
Nature 240: 164. (Cited in Newell)
Blus, L.J., R. Heath, C. Gish, A. Belisle, and R. Prouty. 1971. Eggshell thinning in the brown
pelican: implication of DDE. Bioscience 21: 1213-1215. (As cited in Newell 1987).
Hall, R. J., T. E. Kaiser, W. B. Robertson, Jr. and P.C. Patty. 1979. Organochlorine residues
in eggs of the endangered American crocodile (Crocodylus acutus). Bull. Environ. Contam.
Toxicol. 23:87-90.
Henny, C. J., L. J. Blus, A. J. Krynitsky, and C. M. Bunck. 1984. Current impact of DDE on
black-crowned night-herons in the intermountain west. J. Wildl. Manage. 48(1):1-13.
Newell, A. J., D.W. Johnson and L.K Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, H.M., T.in. Custer, R.W. Lowe, M. Rigney and E. Cromartie. 1988. Organochlo-
rines and mercury in eggs of coastal terns and herons in California, USA. Colon. Waterbirds.
Ohlendorf, K.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine residues and
mortality of herons. Pest. Monit. J. 14(4)125-135.
Stickel, U.K., L.F. Stickel, R.A. Dyrland and D.LHughes. 1984. Aroclor 1254 residues in
birds: lethal levels and loss rates, Arch. Environ, (ontam. Toxicol. 13:7-13.
Szaro, R. C., N. C. Coon, and E. Kolbe. 1979. Pesticide and PCB of common eider, herring
gull and great black-backed gull eggs. Bull. Environm. Contam. Toxicol. 22:394-399.
U.S. EPA (Environmental Protection Agency). 1976. Quality criteria for water. EPA 440/9-
76-023. USEPA, Wash., D.C. 256pp. (As cited in Newell 1987)
Weseloh, D. V., P. Mineau, and D.J. Hallett. 1979. Organochlorine contaminants and trends
in reproduction in great lakes herring gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour.
Conf. 44:543-557.
C-56
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DICOFOL
CAS No.: 115-32-2
CAS Preferred Nomenclature:
Benzenemethanol, 4-chloro-.alpha.
-(4-chlorophenyl)-.alpha.-
(trichloromethyl)-
Empirical Formula:
Synonyms and Common Names:
- Kelthane - Carbax
- Mitigan - CPCA
- Acarin - Decofol
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Ad-
visories:
None established at present
EPA Tolerance Levels for Food (21
CFR 193.80; 40 CFR 185.410):
dried tea = 45 ppm
hops = 30 ppm
cottonseed = 0.1 ppm
other foods = 5-10 ppm
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
Effective December 31, 1988, all uses to be cancelled unless registered formulas
contain less than 0.1% DDT and related contaminants (51 FR 19508).
C-57
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SOURCES OF DICOFOL
Total Dicofol Produced;
Dicofol is a pesticide structurally similar to DDT which was introduced in 1957.
Technical-grade dicofol is a brown viscous oil.
Recent use in the U.S. is 2 to 3 million pounds per year (Holder, 1986). Dicofol is
produced by Rohm and Haas, Inc. and Makhteshim-Agan, Inc. (51FR 19509).
Uses of Dicofol;
Used primarily (60%) to control mites on cotton and citrus. Other major uses
include the control of mites on apples (10%) and on ornamental plants and turf
(10%) (51 FR 19515).
Another 20% is used for the control of mites on a variety of other agricultural
products including:
- pears, apricots and cherries (51 FR 19515; Farm Chemicals Handbook, 1985)
- seed crop soil treatment
- vegetables (e.g., beans and corn)
- shade trees (U.S. EPA, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, dicofol is predicted to be essentially
non-volatile in water (H = 3.5x10 atm m/mol) and from soil surfaces (P/SKoc
= 4.8xlO"14 mm Hg L/mg). It is very strongly sorbed to soil and sediment (Kow
s 1,148,000), and has a high potential for bioaccumulation (BCF = 5.5xl04)
(LymanfilaL, 1982).
Fisher (1975) reported that dicofol and its aerobic soil breakdown products were
relatively immobile in a column experiment using sandy loam soil. Approximately
93 percent of radioactivity applied as C-dicofol and > 99 percent of the total
radioactivity accounted for remained in the upper 2 inches of a sandy loam soil
column after 30 days of aerobic aging followed by 44 days of leaching with 0.5 in/day.
C-58
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Tillman (1986) reported a maximum non-steady state, whole body BCF of 1.0 x 10
and an estimated steady-state whole body BCF > 2.5 x 10 for bluegill sunfish
exposed to 0.006 ppm dicofol for 28 days.
Persistence;
Dicofol can hydrolyze with the rate increasing as pH increases. For example,
Warren (1986) reported hydrolysis half-lives for dicofol at (25°C) of 85 days at pH
5,64 hours at pH 7, and 26 minutes at pH 9. The half-life for dicofol hydrolysis in
distilled water at pH 8.2 was found to be 1 hour; in filtered river water at pH 7.5,
roughly 90% conversion of dicofol to 4,4'-dichlorobenzophenone occurred in 24
hours, though dicofol recovery was poor (Walsh and Hites, 1979).
The photolysis half-life for dicofol was found to be 144 hours in one study using thin
films (TDB, 1985). However, studies using water and soil solutions reported longer
half-lives. For example, Carpenter (1986a) reported a relatively long pho-
todegradative half-life of >37 days for dicofol in water exposed to artificial light
with wavelengths > 290 nm. Carpenter (1986b) reported an intermediate pho-
todegradative half-life between 21 and 30 days for dicofol adsorbed to a silt loam
soil when exposed to these same conditions. Dicofol appears to be poorly metab-
olized by microbes in aerobic soil systems (Walsh and Hites, 1979). It has been
found to undergo degradation in anaerobic sewage sludge, however (Verschueren,
1983).
HEALTH EFFECTS
Carcinogenicity;
Technical-grade dicofol (containing an undetermined level of DDT) induced
hepatocellular (liver) carcinomas in male mice. Results were negative in female
mice as well as in rats (NCI, 1978).
Dicofol is classified by the U.S. EPA as a possible human carcinogen (Class C) with
only limited animal evidence supporting the classification (Holder, 1986).
Because it is structurally related to DDT and there is a large data base supporting
the carcinogenicity of DDT, it has been suggested that difocol be classified some-
where between C and B2 (as a probable human carcinogen). Further study is
necessary to determine the correct classification (Holder, 1986).
Mutagenic Activity;
Additional studies need to be done to determine whether dicofol causes mutagenic
effects (Holder, 1986).
C-59
-------
Negative results were reported for induction of chromosomal aberrations in Chi-
nese hamster lung cells and for bacterial tests (IARC, 1983).
Positive results were noted in a micronucleus test with rat bone marrow cells
(IARC, 1983).
Reproductive Effects;
In a multi-generation mouse study there were no effects on reproduction or fetal
development (IARC, 1983).
With rats, dicofol influenced only early (pre-implantation) embryo development
(IARC, 1983).
Other lexicological Effects;
Although no symptoms of toxicity were demonstrated in dogs fed 300 ppm for one
year, two of the four test animals died before completion of the experiment (Clayton
and Clayton, 1981).
Report of possible suppression of adrenal function (Clayton and Clayton, 1981).
Toxicological Effects Indices;
Estimated cancer potency factor (CPF): = 0.44 (mg/kg/day)"1 (Holder, 1986).
The U.S. EPA Carcinogen Assessment Group recommends the use of a CPF of 0.34
(mg/kg/day)"1 for any combination of dicofol, DDT, DDE and DDD (Holder, 1986).
Occupational exposure to DDT should be limited to 1 mg/m3 (ACGIH, 1986).
Oral LDsO: rats, between 575 and 1,000 mg/kg (McEwen and Stephenson, 1979;
Worthing, 1983; Matsumura, 1985).
C-60
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H
@25°C(atm- ma/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Bioconcentration Factor, BCF:
370.5
Colorless solid;
technical grade,
brown viscous oil
78.5-79.5
180 @ 0.098mm Hg
technical grade,
1.45@25*C
N/A
0.8 (20°C)
5.8xlO'9 (calc.)
3.5xlO'9 (calc.)
6.06 (calc.)
1.5x105 (calc.)
Sax, 1984
Kirk-Othmer, 1984;
Matsumura, 1985
Hartley & Kidd, 1983
Hartley & Kidd, 1983
Hartley & Kidd, 1983
Verschueren, 1983
Lymanfilal., 1982
Lymanfilal., 1982
Lymanejal., 1982
Lymaneial., 1982
5.5xl04 (calc.) Lyman si al., 1982
LOxlO4 to > 2.5xl04 (est.) Tillman (1986)
Value used for estimating aquatic effects
C-61
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Carpenter, M. 1986a. Aqueous Photolysis of C-p,p'-dicofol (Kelthane). Prepared by
Analytical Bio-Chemistry Laboratories for Rohm and Haas. TR No. 310-86-58.
Carpenter, M. 1986b. Photodegradation of C-p,p'-dicofol on the Surface of Soil. Prepared
by Analytical Bio-Chemistry Laboratories for Rohm and Haas. TR No. 310-86-58.
Clayton, G.D. and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed., Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, New York.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Fisher, J.D. 1975. Laboratory Leaching Study With Soil-aged Kelthane. Rohm and Haas Co.
Tech. Report No. 3423-75-50.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
Holder, J.W. 1986. The Assessment of the Carcinogenicity of Dicofol (Kelthane), DDT, DDE
and DDD (TDE). U.S. EPA Carcinogen Assessment Group. EPA/600/6-86/001.
International Agency for Research on Cancer. 1983. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 30. IARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1984. 3rd. ed. John Wiley and Sons,
Inc., New York.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book, Co., New York.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of
Pesticides in the Environment. John Wiley and Sons, Inc., New York.
Matsumura, F. 1985. Toxicology of Insecticides. Plenum Press: New York.
National Cancer Institute (NCI). 1978. Bioassay of Dicofol for Possible Carcinogenicity. NCI
Carcinogenesis Technical Report Series, No. 90.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
C-62
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Tillman, AM. 1986. The bioconcentration, elimination, and metabolism of C-dicofol by
bluegill sunfish (Lepomis machrocbirus). Rohm and Haas Co. Report No. 310-86-17.
%
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1983. Guidance for the Reregistration of Pesticide Products Containing Dicofol
as the Active Ingredient. 540-RS-83-003.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. EPA Office of
Pesticides and Toxic Substances, Washington, D.C.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number
of products registered.
Verschueren, K 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nbstrand Reinhold, New York.
Walsh, P.R. and R.A. Hites. 1979. Dicofol Solubility and Hydrolysis in Water. Bull. Environ.
Contam. Toxicol. 22:305-311.
Warren, J. 1986. Hydrolysis of 1 C-p,p'-dicofol (Kelthane). Prepared by Analytical Bio-
Chemistry Laboratories for Rohm and Haas. Report No. 310-86-41.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-63
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C-64
-------
DIELDRIN
CAS No.: 60-57-1
CAS Preferred Nomenclature:
2, 7:3,6-Dimethanonaphth(2,3b)oxirene,
3,4,5,6,9,9-hexachloro-la,2,2a,3,6,6a,7,7,7a-
octahydro-, (la , 2 /8 , 2 a, 30 , 6/3 , 6aa , 7/8 , la )-
Empirical Formula:
Synonyms and Common Names:
Dieldrex - Illoxol
HEOD - Octalox
REGULATORY STATUS
C12H8CI6°
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption offish) for a 10''
cancer risk (50 FR 79318):
0.076 mg/L
EPA Ambient Water Quality Criteria <
(for protection of aquatic organisms)
(U.S. EPA, 1980):
Freshwater Saltwater
Acute, figfL 2.5 0.71
Chronic,//g/L 0.0019 0.0019
EPA Drinking Water Standard Maxi- i
mum Contaminant Level:
None established at present
EPA Drinking Water Health Ad-
visories (U.S. EPA, 1988; ATSDR,
1987):
dlM(lOkg):
1-day, 10-day, longer-term
exposures = 0.5 pgfL
adult (7kg):
longer-term exposure = 2//g/L
Food and Drug Administration Ac-
tion Level for Fish, total aldrin and
dieldrin (55 FR 14361):
0.3 ppm
Food and Drug Administration Ac-
tion Levels for Other Foods (55 FR
14361):
0.02 - 0.3 ppm
FDA Action Levels are for use in in-
terstate commerce
C-65
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Use Restrictions and Bans;
Suspension of uses on food products in 1974 (ATSDR, 1987).
All uses banned in 1985 except for subsurface termite control, dipping of nonfood
roots and tops, and moth proofing in a closed system by manufacturing processes
(U.S. EPA, 1985). These useshave been voluntarily cancelled by industry (ATSDR,
1987).
SOURCES OF DIELDRIN
Total Dieldrin Produced;
In 1970 about 670,000 Ibs were used. Dieldrin is no longer produced in the U.S.
Until 1985, products containing dieldrin were imported from Europe. None have
been imported since then.
Uses of Dieldrin;
Dieldrin is an organochlorine pesticide that was widely-used from 1950 to 1974 for
controlling soil-dwelling insects, especially termites, on cotton, corn and citrus
crops.
Uses prior to 1974 included the following (Worthing, 1983):
- Control of locusts
- Control of tropical disease carriers (e.g., mosquitos)
- Wood preservative
- Termite control for electrical cables and buildings
- Moth proofing woolen clothes and carpets.
Other Sources:
Breakdown product (by oxidation) of the pesticide aldrin (Verschueren, 1983)
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, dieldrin has a low volatility (H = 2xlO"7
atm m3/mol), sorbs readily to soil organic matter (Kow = 20,890), and has a high
potential for bioaccumulation (BCF = 4,670).
C-66
-------
Persistence;
Dieldrin can undergo hydrolysis under neutral pH conditions (Kn = 7.5xlO~6/
mole/hr) but the half life is long (10.5 years) (Ellington1 el al, 1986). Direct
photolysis of dieldrin can also occur; the half life is about 2 months (Callahan, £i
al., 1979).
Dieldrin can be biotransformed very slowly by soil microbes to an epoxide which
is more toxic to some insects than the parent compound. Further degradation
results in the ketone-aldrin, an aldehyde and alcohols (Morrill el al., 1982). Under
aerobic conditions, dieldrin can be degraded to 6,7-trans-dihydroxydihydroaldrin
(Kirk-Othmer, 1978).
HEALTH EFFECTS
Carcinogenicity;
Dieldrin has caused liver carcinoma in feeding studies (oral administration) with
five strains of male and female mice (50 FR10080). The EPA has classified dieldrin
as a B2, probable human carcinogen, IARC classification 2b. (IARC, 1982;
PHRED, 1988):
Mutagenic Activity:
Mutagenic in human lung cells in culture. Interferes with metabolic cooperation
in cultured cells (i.e., it promotes mutagenic activity). Negative in mouse dominant
lethal test, Salmnnell^ yeast and Drosophila (fruit flies). Inconclusive data on
chromosome damage to mouse bone marrow cells (IARC, 1982).
Reproductive Effects;
In hamsters, high doses of dieldrin exposure resulted in fetal deaths, congenital
defects and retarded growth (Proctor and Hughes, 1978).
Decreased fertility in rats and mice; increased postnatal mortality in rats (ATSDR,
1987).
Other lexicological Effects;
Identified as a neurotoxin (Clayton and Clayton, 1981). The acute affects can
include: headache, dizziness, hyperexcitability, tremors, convulsions, depression
and death (ATSDR, 1987).
Chronic effects: damage to liver in rats, dogs, and hamsters, also evidence of
suppressed immune systems (Gosselin el al., 1984).
C-67
-------
Low levels decreased learning capabilities in monkeys (50 FR 10080).
Toxicological Effects Indices;
Cancer potency factor (CPF): 16 (mg/kg/day)"1 (U.S. EPA, 1987a).
. Reference Dose (RfD): 5xlO"5 mg/kg/day (U.S. EPA, 1987b).
TLV-TWA (time-weighted average, threshold limit value) for occupational skin
exposure: 0.25 mg/m3 (ACGffl, 1986).
LDso in humans, approximately 5 mg/kg (ATSDR, 1987).
Oral LDso: rats, 46 mg/kg (Sax, 1984).
Tolerance levels for agricultural commodities: 0 to 0.1 ppm (ATSDR, 1987).
C-68
-------
Molecular Weight:
Physical State @ 20°C:
PHYSICAL/CHEMICAL PROPERTIES
Value
380.9
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm m3/mol):
Hydrolysis, Ko, 1/mole/hr
solid; buff to light
tan flakes; mild odor
175-176
N/A
1.75
N/A
0.186 (20°C)
S.lxlO"6
2xlO'7 (20°C)
7.5X1Q-6
Log (Octanol-Water Partition Coefficient),
logKow: 4.32
Soil Adsorption Coefficient,
Koc(ml/g): 1700
Fish Bioconcentration Factor, BCF: 4670*
Reference
Windholz, 1983
Worthing, 1983
Callahanelal., 1979
Verschueren, 1983
Callahanfilal., 1979
Callahanfilal., 1979
U.S. EPA, 1986b
Ellington elal.,
1986
Leo, 1983
MabeyfiiaL, 1982
U.S. EPA, 1980
Value used for estimating aquatic effects
C-69
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
ATSDR. 1987. Draft lexicological Profile for Aldrin/Dieldrin. Agency for Toxic Substances
and Disease Registry, U.S. Public Health Service.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol I. Office of Water Planning
and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Clayton, G.D. and F.E. Clayton, eds. 1981-82. Patty's Industrial Hygiene and Toxicology. 3rd
rev. ed., Vol. 2A, 2B, 2C, Toxicology. John Wiley and Sons, New York.
Ellington, JJ., F.E. Stancil, Jr. and W.D. Payne. 1986. Measurement of Hydrolysis Rate
Constants for Evaluation of Hazardous Waste Land Disposal. Volume I. U.S. Environmental
Protection Agency, Athens, Georgia. EPA Report No. EPA/600/3-86/043.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
International Agency for Research on Cancer. 1982. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Suppl. 4. IARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1978. 3rd Ed. John Wiley and Sons,
Inc., New York.
Leo, A.J. 1983. Log P Parameter Database, Pomona College, Claremont, California.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
Morrill, L.G., B.C. Mahilum and S.H. Mohiuddin. 1982. Organic Compounds in Soils:
Sorption, Degradation and Persistence. Ann Arbor Science Publishers, Inc. Ann Arbor,
Michigan, p. 187-238.
Public Health Risk Evaluation Database (PHRED). 1988. Office of Emergency and Reme-
dial Response, U.S. Environmental Protection Agency. Washington, D.C.
Proctor, N.H. and J.P. Hughes. 1978. Chemical Hazards of the Workplace. Lippincott
Company, Philadelphia.
C-70
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Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Sittig, M., ed. 1980. Pesticide Manufacturing and Toxic Materials Control Encyclopedia.
Noyes Data Corp., Park Ridge, New Jersey.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1976. Quality Criteria for Water. Office of Water and Hazardous Materials,
Washington, D.C.
U.S. EPA. 1980. Ambient Water Quality Criteria for Aldrin/Dieldrin. U.S. EPA Office of
Water Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-019.
U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. EPA Office of
Pesticides and Toxic Substances, Washington, D.C.
U.S. EPA. 1986a. Computer retrieval from Office of Pesticides for registered sites and
number of products registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual. U.S. EPA Office of Solid
Waste and Emergency Response, Washington, D.C. EPA-540/1-86/060.
U.S. EPA. 1987a. Carcinogenicity Assessment of Aldrin and Dieldrin. GAG, Washington,
D.C. EPA/600/6-87/006.
U.S. EPA. 1987b. Draft RCRA Facility Investigation (RFI) Guidance Office of Solid Waste,
Washington, D.C. EPA-530/SW-87-001.
U.S. EPA. 1988. Dieldrin - Health Advisory. Office of Drinking Water, Washington, D.C.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M. ed. 1983. The Merck Index: An Encyclopedia of Chemicals. Drugs, and
Biologicals. Merck and Co., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-71
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DIELDRIN
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
The concentration of dieldrin in the brain determined to cause death in several bird species
appears to be quite low. The average level that put the animal at risk of death is between 5
and 9 ppm (Ohlendorf si aL 1981 and Stickel si aL 1972). A concentration of 6.8 ppm was
determined to be the average level lethal to birds from several laboratory studies (Heinz and
Johnson 1981). However, levels as low as 1 ppm in the brain may trigger irreversible starvation
in sensitive individuals (Heinz and Johnson 1981). During starvation, mobilization of low
concentrations of dieldrin from body fats to the brain may cause death, after concentrating to
a lethal level (Newell si aL 1987).
>
Dieldrin is commonly found in the brain, tissues, and eggs of fisheating birds that also have
residues of organochlorines such as DDE and PCBs. Dieldrin was the apparent cause of death
for several ring-billed gulls in southern Ontario in 1969 and 1973. Stickel filaL (1984) analyzed
54 gulls that had died of no apparent disease. Of these birds, eight specimens had dieldrin
levels in the brain greater than 5 ppm. The cause of death in many of the other gulls was most
likely PCB contamination (Stickel el al. 1984).
From 1971 to 1971,101 dead or dying bald eagles were collected and analyzed for organochlo-
rines. Based on the data provided, four eagles had died from lethal concentrations of dieldrin
(concentrations near 5 ppm in the brain) (Barbehenn and Reichel 1981).
In a nationwide survey of 72 species of heron found dead or moribund between 1966 and 1973,
10 specimens had greater than 5 ppm in the brain and had possibly died of dieldrin poisoning.
Eight others had concentrations of dieldrin greater than 2.0 ppm in the brain (Ohlendorf si
aL 1981).
Based on a number of studies in the literature, the State of New York proposed a dietary fish
flesh criterion of 0.12 ppm to protect piscivorous wildlife (Newell el al. 1987).
The effects of dieldrin on piscivorous wildlife are summarized in the following table:
C-72
-------
Concentration
5 ppm (brain)
Effect
death
Source
Stickel £ial.,
1972
Effects of Dieldrin Concentrations on Piscivorous Wildlife
Animal
Birds
Birds 6.8 ppm death Heinz and
Johnson, 1987
Birds (sensitive 1.0 ppm (brain) irreversible Heinz and
individuals) starvation Johnson, 1987
Piscivorous 0.12 ppm (diet) estimated NOEL Newell el aL
Wildlife 1987,
0.022 ppm (diet) cancer risk of Newell el al,
10'2 1987
REFERENCES
Barbehenn, K.R. and in.L. Reichel. 1981. Organochlorine concentrations in bald eagles:
brain/body lipid relations and hazard evaluation. J. Toxicol. Environ. Health. 8:325-330.
Heinz; G. and R. Johnson. 1981. Diagnostic brain residues of dieldrin: Some new insights.
Avian and Mammalian Wildlife Toxicology: Second Conference, ASTM STP 757, D. Lamb
and G. Kenaga (eds), American Society of Testing and Materials pp 72-92 (as cited in Newell
1987).
Newell, A.J., D.in. Johnson and L.K. Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish mildl., Bureau Environ. Protection.
Ohlendorf, K.M., O.tt. Swineford, and LN. Locke. 1981. Organochlorine residues and
mortah'ty of herons. Pest Monit. J. 14(4): 125-135.
Stickel, W.H., L.F. Stickel, R.A. Dyrland and D.L. Hughes. 1984. Aroclor 1254 residues in
birds: lethal levels and loss rates, Arch. Environ. Contain. Toxicol. 13:7-13.
Stickel, W.H., L.F. Stickel and J.in. Spann. 1972. Tissue residues of dieldrin in relation to
mortality in birds and mammals, in Chemical Fallout: current research on persistent pesticides.
(Eds.) Miller, M.W. and G.G. Berg. Charles-C. Thomas publisher, Springfield, USA.
C-73
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C-74
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DIPHENYL BISULFIDE
CHS
12 10 2
CAS No.: 882-33-7
CAS Preferred Nomenclature:
Disulfide, dlphenyl
Empirical Formula: Ci2HioS2
Synonyms and Common Names:
- Phenyl disulfide
REGULATORY STATUS
No use restrictions or regulatory standards.
SOURCES OF DIPHENYL DISULFIDE
Total Diphenyl Disulfide Produced;
Manufactured by Parish Chemical Co., less than 23,000 pounds of diphenyl disulfide
were produced in 1982 (Perwak elal., 1983; SRI, 1986).
Uses of Diphenyl Disulfide:
Diphenyl disulfide is used primarily as a flavoring agent in non-alcoholic beverages,
ice cream, candy, gelatin and pudding (Perwak elal., 1983).
Small amounts are used in the pharmaceutical industry and as a vulcanizing agent
in the manufacture of rubber (Perwak elal., 1983).
FATE IN ENVIRONMENT
Partitioning;
Based on measured properties and structure-activity relationships, diphenyl disul-
fide can volatilize at a low rate (H = 7.6xlO"6 atm» m3/mole) and has a moderately
strong tendency to sorb to soil (Kow^25,700).
C-75
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Persistence;
Little information is available on transformation processes in the environment.
Hydrolysis and biodegradation are not expected to occur at environmentally signif-
icant rates (Ferwak el ai, 1983).
HEALTH EFFECTS
Carcinogenicity;
The U.S. EPA has not evaluated the potential carcinogenicity of diphenyl disulfide.
Other Toxicological Effects;
There are no reports of adverse health effects caused by diphenyl disulfide in either
animals or humans.
Toxicological Effects Indices;
Intraperitoneal LDso: 'mice, 100 mg/kg (Tatken and Lewis, 1983).
C-76
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Presure, P (mm Hg):
Henry's Law Constant, H @ 25 °C
(atm«m /mol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Absorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
218.3
solid
61-62
310
1.353
N/A
5.1
1.4XKT4
7.6X10"6
4.41
7900
1200 (calc.)*
Weast, 1986
Weast, 1986
Weast, 1986
Weast, 1986
Lyman,filaL,1982
Lyman,£lal., 1982
Lyman,filal., 1982
Leo, 1983
Lyman,fiial., 1982
Lyman, filal., 1982
Value used for estimating aquatic effects
C-77
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REFERENCES
Leo, A.J. 1983. Log P Parameter Database. Medchem Project, Pomona College, Claremont,
CA.
Lyman, W J., Reehl, W.F., and Rosenblatt, D.H. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Co.
Perwak, J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong and
K. Scow. 1983. Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants.
U.S. EPA Draft Report. EPA Contract 68-01-5949.
Stanford Research Institute (SRI). 1986. Directory of Chemical Producers.
Stanford Research Institute, Menlo Park, CA.
Tatken, R.L. and R J. Lewis, eds. 1983. Registry of Toxic Effects of Chemical Substances
(RTECS). 1981-82 ed.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67th ed. CRC Press, Boca
Raton, FL.
C-78
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ENDRIN
CAS No.: 72-20-8
CAS Preferred Nomenclature:
2,7,3,6-Dimethanonaphth(2,3b)oxirene,
3,4,5,6,9,9-hexachloro- la,
2,2a,3,6,6a,7,7a-octahydro-
Empirical Formula: CiiHgQeO
Synonyms and Common Names:
- Endrex - Insecticide 269
- Endriocol - Mendrin
- Hexadrin - Oktanex
ci
ciaHecl6°
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of water and
fish) (PHRED, 1988):
EPA Ambient Water Quality Criteria «
(for protection of aquatic organisms)
(U.S. EPA, 1980):
Freshwater Saltwater
Acute, ^g/L 0.18 0.0023
Chronic, yug/L 0.037 0.0023
EPA Drinking Water Health Adviso-
ries (U.S. EPA, 1989):
child (in kg):
1-day exposure = 20/ug/L
10-day exposure = 20/ig/L
longer-term exposure = 3/
-------
Use Restrictions and Bans;
Endrin is an organochlorine compound originally registered as a pesticide in 1951.
It was used to control a wide variety of pests until its long-term persistence in soils
and high levels of mammalian toxicity were recognized.
In 1964, the high level of endrin persistence in soils led to cancellation of its use on
tobacco (Sittig, 1980; U.S. EPA, 1980).
By 1979, specified uses on cotton, small grains, apple orchards, sugarcane, and
ornamentals were also restricted (44 FR 43632).
In 1984, the sole remaining producer of endrin voluntarily requested cancellation
of registration of all endrin products. This action effectively ended its use in the
U.S. (U.S. EPA, 1984).
SOURCES OF ENDRIN
Total Endrin Produced;
Endrin was first used in the U.S. in 1951. By 1971, approximately 1 million pounds
of endrin were produced by Velsicol (Ouellette and King, 1977).
Endrin production had decreased to 400,000 pounds by 1978 (U.S. EPA, 1978).
Uses of Endrin;
Endrin is a broad spectrum pesticide and has been used to control many pests,
including termites, mice and army worms.
Prior to 1979, the main domestic use of endrin was for the control of cotton
bollworms (an insect larva) which attack cotton crops in the southeastern and
Mississippi delta states (U.S. EPA, 1980).
Registered uses of endrin included foliar treatment for citrus, potatoes, barley, oats,
rye, wheat, cotton, apple orchards, sugarcane, various flowers and bark treatment
for ash and hackbeny trees (U.S. EPA, 1986).
Endrin has also been used to control pest populations of birds and rodents (U.S.
EPA, 1980).
Other Sources;
Isodrin may be metabolically converted to endrin (Matsumura, 1985).
Endrin is also found in the pesticide dieldrin in small quantities (Verschueren,
1983).
C-80
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FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, endrin is strongly sorbed to organic
matter (Kow= 219,000) and volatilizes slowly from water (H = 4x10-7 atm m3/mol).
It volatilizes from soils even slower with an estimated half-life of 34 days (p/SKoc
= 4.7x10 mm Hg L/mg). Bioaccumulation is an important fate process;
bioconcentration factors are moderately high to very high, ranging from 6.8x10 to
1.3xl04 in microcosm experiments (Callahan si al, 1979 and Lyman el at, 1982).
Persistence;
Endrin is very resistant to hydrolysis (half-life over 4 years). Photolysis of endrin
in hexane has been documented. No data concerning the photolysis rate of endrin
in the aqueous environment was found. A half-life of about 7 days was observed
when endrin was applied to a sandy loam soil and exposed to sunlight (Shell
Chemical Co., 1975).
Endrin can undergo biotransformation. Guenzi (1974) reported a biodegradation
loss rate of 4-5% per year over 14 years.
HEALTH EFFECTS
Carcinogcnicity:
No evidence of endrin carcinogenicity has been reported (U.S. EPA, 1980). Treon
£l al. (1955) reported that the incidence of cancers in rats fed endrin for 2 years was
no greater than in control rats.
A National Cancer Institute bioassay determined no carcinogenic effects in rats or
mice (NCI, 1979).
The U.S. EPA has classified endrin as a Class D carcinogen (inadequate evidence
of carcinogenicity in animals).
Mutagenic Activity;
Conflicting results have been reported for endrin mutagenicity. Dikshith and Datta
(1972) reported chromosomal aberrations and cellular degeneration in rat testes.
However, negative results for endrin have been recorded with the mouse dominant
lethal test (TDB, 1984).
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Reproductive Effects;
Pregnant rats and mice fed endrin showed reduced fetal survival rates (Nodu el al,
1972). Endrin-exposed mouse fetuses had a higher incidence of club feet.
Endrin produced embryocidal and teratogenic effects in pregnant hamsters. Single
doses of endrin (5 mg/kg) resulted in increased fetal death, congenital abnormalities
(i.e., eye deformities, cleft palate and fused ribs) and growth retardation. Lower
doses (1.5 to 5 mg/kg) did not cause similar effects (OttolenghielaL, 1974; Chernoff
filaL, 1979).
Other Toxicological Effects:
Regardless of the method of exposure, endrin, like the related compounds aldrin
and dieldrin, is highly toxic to humans (Matsumura, 1985). In one animal study
endrin was shown to be five times as toxic as dieldrin (U.S. EPA, 1980).
Primarily, the central nervous system is affected with acute (short-term, high dose)
poisoning by endrin. A range of symptoms can be caused, including dizziness,
nausea, confusion, hyperexcitability, generalized tremors or twitching, and convul-
sions. Death from respiratory failure may also occur (U.S. EPA, 1980; Sax, 1984).
In rats and dogs chronic (long-term, low dose) exposure to endrin has led to poor
survival rates and degenerative changes in the liver, kidneys and brain (U.S. EPA,
1980).
Chronic human exposure to endrin (e.g., in the production of the pesticide) was not
shown to cause adverse health effects (Jager, 1970).
Toxicological Effects Indices;
. Reference Dose (RfD): SxlO"4 mg/kg/day (U.S. EPA, 1989).
TWA-TLV (time-weighted average, threshold limit value) for occupational skin
exposure: 0.1 mg/m3 (ACGffl, 1986).
Oral LDso: rats, 3-43 mg/kg; rabbits, 7-10 mg/kg; monkeys, 3 mg/kg (U.S. EPA,
1980; Sax, 1984; Matsumura, 1985).
C-82
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mole):
Log (Octanol-Water
Partition Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Biocoricentration
Factor, BCF:
380.9
white crystalline
solid; technical
grade, light tan
powder
Decomposition
above 200°C
N/A
1.7 @ 20°C
N/A
0.25 (25°C)
2xlO'7 (25°C)
4xlO'7
3.54
l.TxlO3
6.8xl02to
1.3xl04
(exptl.)
1480
3970'
Windholz, 1983
Matsumura, 1985
U.S. EPA, 1980
U.S. EPA, 1980
CallahanfilaL, 1979
CallahanfilaL, 1979
Mabeyeial., 1982
Leo, 1983
PHRED, 1988
Verschueren el al,
1983; Callahan ei al-,
1979
PHRED, 1988
U.S. EPA, 1980
'Value used in estimating aquatic effects
C-83
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienist). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Shimak, N.W. Gabel, I.P. May, C.F. Howler, J.R. Freed, P. Jennings,
R.L. Durice, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould, 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. 1. Office of Planning and
Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Chernoff, N. el al, 1979. Perinatal Toxicity of Endrin in Rodents. I. Fetotoxic Effects of
Prenatal Exposure in Hamsters. Submitted to Toxicol. Appl. Pharraacol. and the U.S. EPA
(Manuscript).
Emerson, T.E. el al, 1964. Cardiovascular Effects of the Insecticide Endrin Can. Jour.
Physiol. Pharmacol. 42:41.
FDA, 1986. NSSP Manual, Part 1, Appendix C. U.S. Food and Drug Administration,
Washington, D.C
Guenzi, W.D., ed. 1974. Pesticides in Soil and Water. Soil Science Society of America, Inc.
Madison, Wisconsin.
Jager, K.W., 1970. Aldrinr Dieldrin, Endrin and Telodrin: An Epidemiological and Toxico-
logical Study of Long-Term Occupational Exposure. Elsevier Publ. Co., Amsterdam, The
Netherlands.
Leo, AJ. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
Medchem Project, Pomona College; Claremont, California.
Lyman, W.J., W.F. Reehl and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw Hill Book Co.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
Matsumura,F. 1985. Toxicology of Insecticides. Plenum Press: New York.
National Cancer Institute (NCI). 1979. Bioassay of Endrin for Possible Carcinogenicity.
DHEW Pub. No. (NIH) 79-812. U.S. Dept. Health, Edu. Welfare, Bethesda, Maryland.
Nodu fit al, 1972. Influence of Pesticides on Embryos. On the Influence of Organochloric
Pesticides. Oyo Yakuri. fi:673. (Jap.)
C-84
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Ottolenghi, A.D. elal., 1974. Teratogenic Effects of Aldrin, Dieldrin, and Endrin in Hamsters
and Mice. Teratology. 2:11.
Ouellette,R.P.andJ.A.King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co,. New York.
PHRED. 1988. Public Health Risk Evaluation Database. Office of Emergency and Remedial
Response, U.S. EPA, Washington, D.C.
Reins, D.S. fit al» 1966. Effect of Endrin on Venous Return and Catecholamine Release in
the Dog. Can. Jour. Physiol. Phannacol. 44:59.
Sax, N.I., 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Shell Chemical Company. 1975. Photodegradation of Endrin on Soil. Experimental Data
Submitted to the U.S. Environmental Protection Agency.
Sittig, M. ed. 1980. Pesticide Manufacturing and Toxic Materials Control Encyclopedia.
Noyes Data Corp., Park Ridge, New Jersey.
Toxicology Data Bank (TDB) Database. 1985-86. Available through the National Laboratory
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Commit-
tee.
Treon, J.F. £l at 1955. Toxicity of Endrin for Laboratory Animals. Agric. Food Chem. 2:842.
U.S. EPA. 1978. Endrin-Position Document 2/3. Special Pesticide Review Division. Office
Pesticide Programs, Washington, D.C.
U.S. EPA. 1980. Ambient Water Quality Criteria for Endrin. Office of Water Regulations
and Standards. EPA-440/5-80-047.
U.S. EPA. 1984. Internal Office of Pesticide Programs memorandum from G. La Rocca to
B. BurnamfilaL, August 16,1984.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number
of products registered.
U.S. EPA. 1989. Health Effects Assessment Summary Tables (HEAST). Environmental
Criteria and Assessment Office, Cincinnati, OH.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
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-------
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs,, and
Biologicals. 10th ed. Merck Co., Inc., Rahway, NJ.
C-86
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ENDRIN
OBSERVATION AND EFFECTS ON PISCIVOROUS WILDLIFE
Endrin is lethal to birds at very low concentrations. In the brain, concentrations of only 0.8
ppm or more result in death. Levels between 0.6 ppm and 0.8 ppm are hazardous and result
in either survival or death (Stickel elal. 1979).
During 1975 and 1976, twelve of fifteen dead white pelicans collected from refuges in northern
California had lethal levels of endrin in the brain (0.74 to 2.7 ppm). Stickel elal. (1979) blamed
these deaths on the presence of endrin in the agricultural return flows entering the refuges.
White pelicans were also found dead with high levels of endrin near the Teton Dam disaster
of 1976. On the Gulf Coast of Louisiana, both white and brown pel icans were found dead
with endrin present in the brain (Stickel el al. 1979).
Ohlendorf je al. (1981) recorded lethal levels of endrin in the brain of one heron from
Minnesota in 1972, and one from Wisconsin in 1978. Bald eagles with lethal levels of endrin
were found in Iowa in 1977 and in Minnesota in 1976 (Stickel el al. 1979).
The endrin concentration in eggs appears to affect hatching success. For the brown pelican,
Blus £1 al (1979) estimated that concentrations of greater than 0.5 ppm in the eggs caused
reproductive impairment (as cited hi Newell elal. 1987). Pelican eggs from Louisiana during
1972 to 1974 commonly contained 0.5 ppm endrin (Stickel elal 1979).
Based on data from several laboratory studies, the State of New York proposed a dietary fish
flesh criterion of 0.025 ppm endrin to protect piscivorous wildlife (Newell el al. 1987).
The effects of endrin on piscivorous wildlife are summarized in the following table:
C-87
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Effects of Endrin Concentrations on Piscivorous Wildlife
Animal Concentration Effect Source
Bird 0.6-0.8ppm hazardous Stickel si al,
(brain) 1979
Bird 0.8 ppm (brain) death Stickel £i a].,
1979
Brown Pelican 0.5 ppm (egg) reproductive Blus el al., 1979
impairment
Piscivorous 0.025 ppm (diet) estimated NOEL Newell £laL,
Wildlife 1987
REFERENCES
Blus, LJ., R. Heath, C. Gish, A. Belisle, and R. Prouty. 1979. Eggshell thinning in the brown
pelican: implication of DDE. Bioscience 21:1213-1215. (as cited in Newell 1987).
Newell, A. J., D.W. Johnson and L.K. Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, K.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine residues and
mortality of herons. Pest. Monit. J. 14(4) .125-135.
Stickel, in.H., inJL Reichel, and D.L Hughes. 1979. Endrin in birds: lethal residues and
secondary poisoning, Toxicology and Occupational Medicine, organizer in. B. Deichman,
Elsvier/North-Holland, New York, NY.
C-l
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HEPTACHLOR
CAS No.: 76-44-8
CAS Preferred Nomenclature:
4,7-Methano- IH-indene
l,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-
Empirical Formula: CioHsCl?
Synonyms and Common Names:
- Velsicol 104 - Heptagran
- Rhodiachlor - Heptalube
- Heptox - DrinoxH-34
E3314 - Gold Crest H-60
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish) for a 10"6
cancer risk (IRIS, 1989):
0.00029 ns/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organ-
isms)(IRIS, 1988):
Freshwater Saltwater
Acute, pgfL 5.2X10'1 5.3xlO'z
Chronic, fig/L 3.8x10° 3.6xlO'3
EPA Drinking Water Standard (50
FR 46936; IRIS, 1989):
Proposed Maximum Contaminant
Level = 0.0004 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
EPA Drinking Water Health Adviso-
ries (IRIS, 1989):
child (10 kg):
1-day and 10-day exposures = 10/wg/L
longer-term exposure = 5/^g/L
adult (70 kg):
longer-term exposure = 17.5 figfL
Food and Drug Administration Ac-
tion Level for Fish (heptachlor + hep-
tachlor epoxide)(55 FR 14362):
0.03 ppm
FDA Action Levels for Other Foods
(55 FR 14362):
0.01 to 0.02 ppm
FDA Action Levels are for use in in-
terstate commerce
C-89
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Use Restrictions and Bans;
All uses except subsurface ground insertion for termite control and dipping of roots
or tops of nonfood plants banned by 1983 (43 FR 12372).
SOURCES OF HEPTACHLOR
Total Heptachlor Produced;
In 1971,6 million Ibs. were produced by Velsicol Chemical Co. (Ouellette and King,
1977).
By 1983, most uses had been cancelled (Rafats and MacLean, 1986).
Heptachlor is no longer sold in the U.S. as of 8/87, but remaining stock can be used
in some states by commercial exterminators for termite control (ATSDR, 1987).
Uses of Heptachlor;
Production of heptachlor as a registered insecticide began in 1952. It was widely
used to control fire ants in southern states (Rafats and MacLean, 1986) and to
control soil insects on corn and other crops (U.S. EPA, 1980).
Use of registered products (e.g., soil treatment for pineapples and sugarcane)
allowed only by certified applicators (U.S. EPA, 1986b). No uses are allowed in
Minnesota, Massachusetts, and New York (ATSDR, 1987).
Other Sources:
Contaminant of the pesticide chlordane (Callahan, si M-, 1979).
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, heptachlor is moderately volatile (H =
1.48x10 atm m /mol), strongly sorbed to sediment (Kow = 186,000), and has a
high potential for bioaccumulation (BCF = 1.57xl04).
Persistence:
Heptachlor can persist in aquatic systems once it sorbs onto sediment.
Heptachlor in the water column can undergo hydrolysis, photolysis and can be
oxidized to heptachlor epoxide. Heptachlor is hydrolyzed to 1-hydroxychlordene;
C-90
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C-91
-------
the half-life is one to three days (Callahan £lal, 1979). Specific near-surface rate
constants for photolysis were not found, although photoisomerization is thought to
occur (Verschueren, 1983).
Heptachlor can be biotransformed to heptachlor epoxide or chlordane, but at a
slower rate in aquatic systems than abiotic hydrolysis (Callahan si al-, 1979).
HEALTH EFFECTS
Carcinogenicity;
Exposure to heptachlor induced liver tumors in two strains of mice, but tests using
rats did not result in any tumors(IRIS, 1989). The EPA classification is B2, a
probable human carcinogen, based on tumors in mice and the fact that related
chemicals cause liver cancers (U.S. EPA, 1986b).
Mutagenic Activity;
Mutagenic effects were not observed in tests using bacteria, Drosophila or mam-
malian liver cells. Increased chromosomal aberrations were found in tests using
mouse bone marrow cells. (IARC, 1979; U.S. EPA, 1980; IRIS, 1987).
Reproductive Effects;
Exposure to heptachlor has been associated with stillbirths in humans.
In animals, observed effects include decreased fertility and decreased survival of
newborns in rats and liver damage in dogs (U.S. EPA, 1980).
Other Toxicoiogical Effects;
Acute (short-term, low dose) exposure of humans can cause blood disorders,
including anemia and leukemia, and central nervous system damage (e.g., hyperex-
citability, depression, and convulsions) (U.S. EPA, 1980,1986b; IARC, 1979).
Hepatotoxicity, renal and adrenotoxicity, and blood disorders have been reported
from chronic, (long-term, low dose) exposure to heptachlor in animals.
Toxicoiogical Effects Indices;
Cancer Potency Factor (CPF): 4.5 (mg/kg/day)"1 (IRIS, 1989).
Reference Dose (RfD):'5 x 10"4 mg/kg/day (U.S. EPA, 1987a; IRIS, 1989).
TWA-TLV (time-weighted average, threshold limit value), for occupational skin
exposure: 0.5 mg/m3 (ACGIH, 1986).
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Hydrolysis, KQ 1/hr:
Henry's Law Constant H @
25°C (atm m3/mol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Bioconcentration Factor, BCF:
Value
373.3
solid
95-96 (pure)
46-74 (technical grade)
135-145°Cat
1-1.5 mm Hg
1.57-1.59
at9°C
1.65-1.67
at25°C
N/A
0.056-0.18
at25°C
3xlO-4at25°C
0.03at30°C
1.48xlO"3
5.27
4.4
1.2X10"4
I.lxl03to
2.1xl04
11,200'
Reference
Windholz, 1983
Hartley and Kidd, 1987
U.S. EPA, 1986c
U.S. EPA, 1986c
U.S. EPA, 1986c
Callahansial., 1979
Verschueren, 1983
CallahanelaL, 1979
Mills ciaL, 1985
Leo, 1983
Mabeyelal., 1982
MabeyeiaL, 1982
Verschueren, 1983
U.S. EPA, 1980
'Value used for estimating aquatic effects
C-93
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienist). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
ATSDR. 1987. Draft lexicological Profile for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. U.S.
Public Health Service, Oak Ridge National Lab, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. I. Office of Water
Planning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Hartley, D. and H. Kidd, eds. 1987. Agrochemicals Handbook. Royal Society of Chemistry.
Nottingham, England.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS, 1989. Integrated Risk Information System Database. U.S. EPA, Washington, D.C.
Leo.AJ. 1983. Log P Parameter Database. Pomona College, Claremont, California.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic
Priority Pollutants. SRI International. EPA 440-4-81-014.
Mills, W.B., D.B. Porcella, MJ. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and D.A. Haith. 1985. Water Quality Assessment: A Screening Procedure for Toxic
and Conventional Pollutants in Surface and Groundwater. U.S. Environmental Protection
Agency: Athens, Georgia. EPA 600/6-85/002a. 444 pp.
Ouellette,R.P.andJ.A.King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Rafats, J. and J. MacLean. 1986. Heptachlor Contamination, Special Reference Brief.
National Agricultural Library, Beltsville, Maryland. NAL SRB 86-02.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Com-
mittee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Heptachlor. U.S. EPA Office of Water
Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-052.
C-94
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U.S. EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. EPA Office of
Pesticides and Toxic Substances, Washington, D.C.
U.S. EPA. 1986a. Computer Retrieval From Office of Pesticides for Registered Sites and
Number of Products Registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual. Office of Emergency and
Remedial Response, Washington, D.C. EPA-540/1-86/060.
U.S. EPA. 1986c. Pesticide Fact Sheet Number 107.1: Heptachlor. Office of Pesticide
Programs, Washington, D.C. EPA-540/FS-87-202. PB-87-233748.
U.S. EPA. 1987a. Draft. RCRA Facility Investigation (RFI) Guidance. Office of Solid
Waste. OSWER Directive 9502,00-6C.
U.S. EPA. 1987b. Health Advisory for Heptachlor and Heptachlor Epoxide. Office of
Drinking Water.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals,. Drugs, and
Binlngicals. 10th ed. Merck Co., Inc., Rahway, New Jersey.
C-95
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C-96
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HEPTACHLOR EPOXIDE
CAS No.: 1024-57-3
CAS Preferred Nomenclature:
2,5-Methano-2H-indeno( l-2-b)oxirene,
2,3,4,5,6,7,8-heptachloro-la,lb,5,5a,6,6a-
hexahydro-
Empirical Formula: CioHsClvO
Synonyms and Common Names:
- l,4,5,6,7,8,8-Heptachloro-2,3-epoxy-
2,3,3a,4,7,7a-hexahydro-4,7-methanoindene,
- Epoxy heptachlor
- Velsicol53-CS-17
Cl H
C10H5C.70
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish) for a 10"
cancer risk (IRIS, 1989):
0.00029 ng/L
EPA Drinking Water Health Ad-
visories (IRIS, 1989):
cMjL(lOkg)
long-term exposure = 0.13/ug/L
adult (10kg)
long-term exposure = 0.5/*g/L
EPA Ambient Water Quality Criteria Food and Drug Administration Ac-
(for protection of aquatic or-
ganisms)(IRIS, 1989):
Freshwater
Acute, fig/L 52xlQ~l
Chroni
-------
Use Restrictions and Bans:
Restrictions onheptachlor, the parent compound, were instituted in 1978. Hepta-
chlor is no longer sold in the U.S. as of 8/87 but remaining stock can be used in some
states by commercial exterminators for termite control. No uses are allowed in
Minnesota, Massachusetts, and New York (ATSDR, 1987).
SOURCES OF HEPTACHLOR EPOXIDE
Not produced as a separate chemical.
Heptachlor epoxide is a metabolic breakdown product of heptachlor which can be
produced in microorganisms, plants and animals (including humans).
It is a contaminant of heptachlor and chlordane.
Most uses of heptachlor have been banned. However, heptachlor epoxide can still
be found in the environment.
FATE IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, heptachlor epoxide is somewhat volatile
(H = 4.4x10 atm m /mol), sorbs to organic matter to a moderate extent (K0w
= 500), and can be bioaccumulated (BCF values range from 850 to 4,500 based on
experimental data).
Persistence;
Heptachlor epoxide is resistant to biotransformation. Its estimated half-life in soils
is several years (U.S. EPA, 1987a).
Heptachlor epoxide is not susceptible to hydrolysis, oxidation or photolysis.
(Mabey elal., 1982 and Eichelberger and Lichtenberg, 1971).
HEALTH EFFECTS
Carcinogenicity;
Exposure to heptachlor epoxide caused an increased incidence of liver carcinomas
in rats and mice and hepatomas in female rats (IRIS, 1989). It is classified as a
probable human carcinogen (B2) by the U.S. EPA (1986).
C-98
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Some increased lung and bladder cancers occurred in pesticide manufacturing plant
workers, but it is difficult to associate occurrences with quantitative doses of a
specific chemical. (ATSDR, 1987).
Mutagenic Activity:
No evidence of mutagenic activity was observed using mouse dominant lethal test,
Ames test, or tests with fruit flies. (IRIS, 1989).
Reproductive Effects:
When animals were fed heptachlor epoxide there was decreased fertility and
decreased fetal survival noted in rat and mice studies extending for 2 to 3 genera-
tions. (Cerey and Ruttkay-Nedecka, 1971; Ruttkay-Nedecka, eial., 1972; Green,
1970).
Higher heptachlor epoxide levels were found in one group of women with prema-
ture delivery (Wassennan, elaL, 1982) and in stillborn infants (Curley, elal., 1969).
Data are not considered adequate to define a direct relationship between exposure
and reproductive effects. (ATSDR, 1987).
Other Toxicological Effects:
Acute (short-term, high dose) exposure in humans can cause central nervous system
effects (e.g., irritability, dizziness, muscle tremors, and convulsions) (U.S. EPA,
1986).
In animals, liver, kidney and blood disorders can occur. The oral LDso values for
heptachlor epoxide range from 46.5 to 60 mg/kg. (U.S. EPA, 1980; IARC, 1979;
IRIS, 1988).
Toxicological Effects Indices:
Cancer Potency Factor (CPF): 9.1 (mg/kg/day)"1 (IRIS, 1989)
Reference Dose (RfD): 1.3 x 10"5 mg/kg/day (IRIS, 1989)
C-99
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Density/Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Bioconcentration Factor,
BCF (for fish):
Value
389.3
solid
157-160
N/A
N/A
N/A
0.350 (25°C)
3xlO-4(25°C)
(value for
heptachlor)
4.4X10"4
2.70
2.2X102
1.44xl04 (calc.)
2900pinfish
4500 minnow
1700 mussel
850 oyster
11,280*
Reference
Windholz, 1983
CallahansiaL, 1979
Mabeyelal., 1982
Mabeyelal., 1982
Mabeyelal., 1982
Mabeyelal., 1982
Mabeyelal., 1982
LymaneiaL, 1982
Zaroogian el al,
1985
U.S. EPA, 1980
* Value used for estimating aquatic effects
C-100
-------
REFERENCES
ATSDR. 1987. Draft lexicological Profile for 2,3,7,8-Tetrachlorodibenzo-p-Dioxin. U.S.
Public Health Service, Oak Ridge National Lab, Oak Ridge, TN.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. I. Office of Water Plan-
ning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Cerey, K., and Ruttkay-Nedecka, J. 1971. The Influence of Heptachlor on Rat Fertility and
Growth. Z. Versuchstierkd. 12:243-244.
Curley, A., Copeland, M.F., Kimbrough, R.D. 1969. Chlorinated Hydrocarbon Insecticides
in Organs of Stillborn and Blood of Newborn Babies. Arch. Environ. Health. 12:628-632.
Eichelberger, J.W. and JJ. Lichtenberg. 1971. Persistence of Pesticides in River Water.
Environ. Sci.Technol. 5:541-544.
Green, V.A. 1970. Effects of Pesticides on Rat and Chick Embryo. In: Trace Subst. Environ.
Health 3, Proc. Univ. Mo. Annual. Conf., 3rd, Meeting Date 1969 (Hemphill, D., ed.).
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System Database. U.S. EPA, Washington, D.C.
Lyman, WJ., W.F. Reehe and D.H. Rosenblatt, 1982. Handbook of Chemical Property
Estimation Methods - Environment.' McGraw-Hill, New York, NY
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440- 4-81-014.
Ruttkay-Nedecka, J., Cerey, K, Rosival, L. 1972. Evaluation of the Chronic Toxic Effect of
Heptachlor. Kongr. Chem. Pol'nohospod. 2jC27.
U.S. EPA. 1980. Ambient Water Quality Criteria for Heptachlor. U.S. EPA Office of Water
Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-052.
U.S. EPA. 1985. Drinking Water Criteria Document for Heptachlor, Heptachlor Epoxide
and Chlordane. EPA Report No. 600/X-84-197-1.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. Office of Emergency and
Remedial Response, Washington, D.C. EPA-540/1-86/060.
C-101
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U.S. EPA. 1987. Draft. RCRA Facility Investigation (RFI) Guidance. Office of Solid Waste.
OSWER Directive 9502.00-6C.
U.S. EPA. 1987b. Heptachlor and Heptachlor Epoxide Health Advisory. Office of Drinking
Water.
Windholz, M., ed., 1983. The Merck Index! An Encyclopedia of Chemicals,
Drugs,and Biologicals. 10th ed. Rahway, N.J. Merck Co., Inc.
Zaroogian, G.E., J.F. Heltshe, and M. Johnson. 1985. Estimation of bioconcentration in
marine species using structure-activity models. Environ. Toxicol. Chem., 1:3-12.
C-102
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HEXACHLOROBENZENE
CAS No.: 118-74-1
CAS Preferred Nomenclature:
Benzene, hexachloro-
Empirical Formula:
Synonyms and Common Names:
- HCB - Amadin
- No Bunt - Co-op Hexa
- Perchlorobenzene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish) for a 10"6
cancer risk (U.S. EPA, 1987):
0.74 ng/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms)
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Ad-
visories (U.S. EPA, 1987):
fihild.(10 kg):
1-day, 10-day and long-term
exposure = 0.05 mg/L
adult (70 kg):
long-term exposure = 0.2 mg/L
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
Food and Drug Administration Ac-
tion Level for Meat and Poultry (Mor-
ris and Cabral, 1986):
0.5 ppm
FDA Action Levels are for use in in-
terstate commerce
Use Restrictions and Bans:
In 1984 registration of hexachlorobenzene as a pesticide was voluntarily cancelled
(Morris and Cabral, 1986).
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SOURCES OF HEXACHLOROBENZENE
i
Total Hexachlorobenzene Produced;
Production in the U.S. of HCB as a pesticide was about 3.2 million Ibs in 1975
(Blackwood and Sipes, 1979). Commerical production in the U.S. was discontinued
in 1976 (U.S. EPA, 1984). Since 1981 no HCB has been imported (Menzie, 1986).
HCB is formed, however, as a by-product of the production of other chlorinated
compounds. Major sources include carbon tetrachloride, tetrachloroethene, and
trichloroethene. HCB is also an impurity in some pesticides (e.g., pen-
tachloronitrobenzene, chlorothalonil, dacthal, picloran) and in pentachlorophenol.
Uses of Hexachlorobenzene:
Primary agricultural use prior to 1985 was as a fungicide to protect seeds of grain
crops, particularly wheat (Devine, 1982; Pelletier, 1985)
In the early 1970's, small amounts of HCB were used for a variety of industrial
purposes:
- fungicide in paper products (Verschueren, 1983)
- pyrotechnic materials (QuinlivanelaL, 1975)
- synthetic rubber production for tires (Mumma and Lawless, 1975)
- reported use as fluxing agent in aluminum production (Quinlivan el a]., 1975)
- reported use in graphite electrode production (Mumma and Lawless, 1975).
Other Sources;
HCB can be formed during incineration of municipal waste and chlorination
treatment of industrial process water and wastewater.
HCB is a breakdown product of the biotransformation of lindane (Morris and
Cabral, 1986).
Emissions to air and water from landfills containing pesticides and industrial wastes
(Brooks and Hunt, 1984).
FATE IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, hexachlorobenzene can volatilize but not
readily (H = 6.8X10"4 atm m3/mol). An experimentally-determined volatiliza-
C-104
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tion half-life was 41 hours in one meter deep water (Korte and Greim, 1981). HCB
sorbs strongly to soils or sediments containing organic matter (Kow 457,000). HCB
can bioaccumulate, although the potential differs substantially among aquatic
species (BCF = 7,800 to 22,000).
Persistence;
Hexachlorobenzene is widespread and persistent in aquatic systems. Recent ex-
periments by Mill and Haag (1986) confirmed that photolysis is slow with a half-life
of about 90 days. Earlier experiments had suggested that natural organics (e.g.
humic acids) might increase photolysis, but Mill and Haag found no such effect.
Because of its chemical structure, HCB does not undergo hydrolysis at tempera-
tures normally found in the environment. Experiments to determine biotransfor-
mation rates of HCB found negligible degradation (Tabak, ejtal., 1981 and
Callahan,fiiaL,1979).
HEALTH EFFECTS
Carcinogenicity;
Hexachlorobenzene causes liver tumors in rats, mice and hamsters (IARC, 1979;
U.S. EPA, 1984). Tumors have also been induced in kidneys of rats and in adrenal
and thyroid glands of hamsters (U.S. EPA, 1984). EPA classification B2: Probable
human carcinogen (IARC Class 2b) (PHRED, 1988).
Mutagenic Activity;
Hexachlorobenzene was not mutagenic in bacterial or mammalian cell assays, but
was mutagenic in yeast (U.S. EPA, 1984). The Ames test was also negative (Morris
and Cabral, 1986).
Reproductive Effects;
HCB is teratogenic in mice and rats (IARC, 1979) and fetotoxic in rats and quail.
An increase in mortality of breast-fed babies whose mothers have been chronically
exposed to HCB has also been reported (IARC, 1979).
Other Toxicological Effects:
Chronic (long-term, low dose) human exposure to HCB can cause porphyria with
the following symptoms: skin lesions, excessive pigmentation, excessive hair pro-
duction or hair loss, light sensitivity and neurologic damage (U.S. EPA, 1984 and
1987). Effects on animals include liver and kidney lesions in rats; immunosuppres-
sion in mice, rats and dogs; neurologic damage in mice; and changes in ovaries of
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female mice (U.S. EPA, 1987; Morris and Cabral, 1984). One test using rats showed
no effects on the first generation at dosages of 0.32-40 ppm, but the second
generation had liver and parathyroid gland problems. Oral LDso values range from
1,700 mg/kg in cats to 10,000 mg/kg in rats (U.S. EPA, 1987).
Toxicological Effects Indices;
Cancer potency factor (CPF): 1.7 (mg/kg/day)"1 (U.S. EPA, 1986; PHRED, 1988).
Reference Dose (RfD): 0.0008 mg/kg/day (IRIS, 1989).
C-106
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PHYSICAL/CHEMICAL PROPERTIES
Value Reference
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/P):
284.8
solid
231
323-326
2.044 (23°C)
N/A
6xlO'3(25°C)
0.11 (24°C)
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Callahaneial, 1979
Verschueren, 1983
Vapor Pressure, P (mm Hg):
Henry's Law Constant H @
25°C (atm m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,
Koc(ml/g):
Fish Bioconcentration
Factor, BCF:
1.089xlO'5 (20°C)
5.66
3900(calc)
7800 rainbow trout
22,000 fathead
minnow
8,690*
Callahaneial., 1979
Lymanfiial, 1982
Leo, 1983
LymanfilaL, 1982
U.S. EPA, 1987
U.S. EPA, 1987
U.S. EPA, 1980
Value used for estimating aquatic effects
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REFERENCES
Blackwood and Sipes. 1979. Status Assessment of Toxic Chemicals: Hexachlorobenzene.
U.S. Environmental Protection Agency, Office of Research and Development, Washington,
D.C. EPA-600/2-79-210g.
Brooks, G.W. and G.E. Hunt. 1984. Source Assessment for Hexachlorobenzene. EPA
Contract No. 68-02-3818. Research Triangle Park, N.C.
Callahan, M.A., M.W. Slimak, N.W. Gabel, IP. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol II. Office of Water
Planning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029b.
Devine, K. 1982. Preliminary Quantitative Usage Analysis of Hexachlorobenzene. U.S.
Environmental Protection Agency, Office of Pesticides Programs, Washington, D.C.
ICF Incorporated. 1985. Draft Superfund Public Health Evaluation Manual. U.S. EPA Office
of Solid Waste and Emergency Response, Washington, D.C. EPA Contract #68-01-7090.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1988. Integrated Risk Information Service. Office of Emergency and Remedial Re-
sponse, U.S. Environmental Protection Agency, Washington, D.C.
Korte, F. and H. Greim. 1981. Feasibility of Test Guidelines and Evidence of Base-set Testing
according to the Chemicals Legislation. Environmental Research Plan of the Ministry of the
Interior, Research Report No: 10704006/1. Federal Environmental Agency, West Berlin,
Germany.
Leo, AJ. 1983. Log P Parameter Database, Pomona College, Claremont, California.
Lyman, W J., ed. 1982. Handbook- of Chemical Property Estimation Methods. McGraw-Hill,
New York. 977pp.
Menrie, C.M. 1986. Hexachlorobenzene: Uses and Occurrence, pp. 13-22. In: Morris, C.R.
and J.R.P. Cabral, ed. Hexachlorobenzene: Proceedings of an International Symposium.
IARC. Scientific Publications No.77.
Mill, T. and W. Haag. 1986. The Environmental Fate of Hexachlorobenzene. p.61-66. In:
Morris, C.R. and J.R.P. Cabral, ed., Hexachlorobenzene: Proceedings of an International
Symposium. IARC Scientific Publications, No.77
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Morris, C.R. and J.R.P. Cabral, eds. 1986. Hexachlorohenzene: Proceedings of an Interna-
tional Symposium. IARC Scientific Publication No.77. Lyon, France.
Mumma, C.E. and E.W. Lawless. 1975. Survey of Industrial Processing Data, Task I -
hexachlorobenzene, pollution from chlorocarbon processes. U.S. Environmental Protection
Agency, Washington, D.C. EPA-560/3-75-003.
Pelletier, E.N. 1985. Fungicidal Uses of HCB and Other Fungicides Possibly Containing
HCB. Memo from E.N. Pelletier to P. Tobin, February 11, 1985. U.S. Environmental Protec-
tion Agency, Office of Pesticides Programs, Washington, D.C.
Public Health Risk Evaluation Database (PHRED). 1988. Office of Emergency and Reme-
dial Response. U.S. EPA, Washington, D.C.
Quinlivan, S.M., M. Ghasseni, and M. Shanty. 1975. Survey of Methods Used to Control
Water Containing Hexachlorobenzene. U.S. Environmental Protection Agency, Washington,
D.C. NTISPB 25305.
Tabak, H.H., S.A. Quave, C.I. Mashni, and E.F. Earth, 1981. Biodegradability Studies with
Organic Priority Pollutant Compounds. Jour. Water Pollution Control Federation
: 1503-15 18.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1984. Health Effects Assessment for Hexachlorobenzene. EPA Report No.
540/1/86-017. Washington, D.C.
U.S. EPA. 1986. Computer Retrieval from Office of Pesticides for Registered Sites and
Number of Products Registered.
U.S. EPA. 1987. Health Advisory for Hexachlorobenzene. U.S. Environmental Protection
Agency, Office of Drinking Water, Washington, D.C
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
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C-110
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a-HEXACHLOROCYCLOHEXANE
(alpha-BHC)
CAS No.: 319-84-6
CAS Preferred Nomenclature:
Cyclohexane, 1,2,3,4,5,6-hexachloro-
(l.alpha., 2.alpha., 3 .beta., 4.beta.,
S.beta., 6.beta.)-
Empirical Formula:
Synonyms and Common Names:
a-Hexachlorocyclohexane a-Benzenehexachloride
a-BHC a-Hexachloran
128Ma-HCH a-Lindane
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish) for a 10"*
cancer risk (IRIS, 1989):
3.1 x lQ~2i*g/L
EPA Ambient Water Quality Criteria <
(for protection of aquatic organ-
isms)(IRIS, 1989):
Freshwater Saltwater
Acute,/ig/L 100 0.34
Chronic, pg/L - -
Above are LECs (Lowest Effect Con-
centration)
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Adviso-
ries:
fihM(lOkg):
1-day, 10-day and long-term
exposures = 50/ig/L
adult (70 kg):
long-term exposure = 20/ig/L
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
C-lll
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Use Restrictions and Bans;
In 1977, EPA cancelled inclusion of a-hexachlorocyclohexane in technical grade
lindane (EPA, 1985).
Uses of all but y - hexachlorocyclohexane (lindane) were cancelled by 1978 (41FR
46031; 43 FR 31432).
SOURCES OFg-HEXACHLOROCYCLOHEXANE
Total Hexachlorocyclohexane Produced:
a-Hexachlorocyclohexane is no longer produced in the United States.
Uses of-Hexachlorocyclohexane;
Hexachlorocyclohexane occurs in eight forms. Technical grade lindane is an off-
white to brown powder that, prior to 1977, contained a-hexachlorocyclohexane.
Technical-grade lindane was used to control cockroaches, flies, aphids, grain wee-
vils, and beetles (Kirk-Othmer, 1982).
Other Sources;
May be selective degradation product of other hexachlorocyclohexane isomers.
(Matsumura, 1985).
FATE IN ENVIRONMENT
Partitioning;
Based on the physical/chemical properties of a-hexachlorocyclohexane, sorption to
sediment is moderate(Kow = 8,000), and the potential for bioaccumulation is low
(BCF = 130). Based on its similarity to the y isomer, volatilization is estimated to
be low.
Experiments by Tsukano (1973) reported Freundlich isotherms for the
hexachlorocyclohexane isomers on two soils with organic carbon contents of 1.9
percent and 5.2 percent. The values were 1/n = 0.71 to 0.83 and K = 30 to 120 for
the second soil.
Persistence;
Hydrolysis, photolysis and oxidation are not thought to be important fate determin-
ing processes in the environment. One experiment showed no change due to
C-112
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hydrolysis at a pH of 7.3 to 8 after 2 years (Callahan el al, 1979). No other studies
under acidic or more alkaline conditions were found.
Biotransfonnation has been observed in laboratory experiments conducted using
soil/water mixtures under anaerobic conditions. (Tsukano, 1973).
HEALTH EFFECTS
Carcinogcnicity;
Inadequate data exists to determine whether a-hexachlorocyclohexane is a human
carcinogen. Exposure to a-hexachlorocyclohexane caused increased incidences of
liver tumors in mice and rats. a-Hexachlorocyclohexane is classified by the EPA as
a probable (B-2) human carcinogen. IARC (1979) states that hexachlorocyclohex-
ane cannot be classified (class d) because of limited data.
Mutagenic Activity:
a-Hexachlorocyclohexane (tested individually and mixed with /3-hexachloro-
cyclohexane) was determined to be non-mutagenic in bacteria, yeast, and Drosoph-
ila (IARC, 1979).
Reproductive Effects: No data found.
Other Toxicological Effects: None found.
Toxicological Effects Indices;
Cancer potency factor (CPF): 6.3 (mg/kg/day)"1 (IRIS, 1989).
C-113
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm« m3/mol):
Value
291
solid
157-158
N/A
N/A
N/A
1.63
2.5xlO'5
N/A
Log (Octanol-Water Partition Coefficient),
logKow: 3.90
Soil Adsorption Coefficient, Koc(mVg):
Fish Bioconcentration Factor, BCF:
3800
130'
Reference
Callahanelal., 1979
Gunther, 1971
Brooks, 1974
CallahaneiaL, 1979
MabeyfiiaL, 1982
MabeyfilaL, 1982
OWRS, U.S. EPA, 1980
* Value used for estimating aquatic effects
C-114
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REFERENCES
Brooks, G.T. 1974. Chlorinated Insecticides: Volume I: Technology and Applications. CRC
Press: Cleveland, Ohio.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, and B. Maestri. 1979. Water Related Environmental Fate of
129 Priority Pollutants. U.S. Environmental Protection Agency, Washington, D.C. EPA-
440/4-79-029a.
Gunther, F.A. 1971. Halogen Derivatives of Aliphatic Hydrocarbons. Residue Review.
26:34-77.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information Service. Office of Emergency and Remedial Re-
sponse, U.S. Environmental Protection Agency, Washington, D.C.
Kirk-Othmer. 1982. Encyclopedia of Chemical Technology. 3rd. ed. John Wiley and Sons,
Inc., New York.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, T.W.
Partridge, H. Jaber, D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
Matsumura, F. 1985. Toxicology of Insecticides. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
OWRS, U.S. EPA. 1980. Ambient Water Quality Criteria Documents for -Hexa-
chlorocyclohexane.
Tsukano, Y. 1973. Factors Affecting Disappearance of BHC Isomers from Field Rice Soil.
JARQ. 2(2):93-97.
U.S. EPA. 1985. Guidance for the Registration of Pesticide Products Containing Lindane as
the Active Ingredient. U.S. EPA Office of Pesticide Programs. EPA 540/RS-86-121.
U.S. EPA. 1987. Draft RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency. Office of Solid Waste, Washington, D.C. EPA-530/SW-87-001.
C-115
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C-116
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ISOPROPALIN
CAS No.: 33820-53-0
CAS Preferred Nomenclature:
Benzenamine, 4-(l-methylethyl)-2,6-
dinitro-N,N-dipropyl-
Empirical Formula: Ci5H23NsO4
Synonyms and Common Names:
- Paarlan
- 2,6-Dinitro-N,N-dipropylcumidene
- El-179
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption offish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Ad-
visories:
None established at present
EPA Tolerance Levels for peppers
and tomatoes (40 CFR 180.313):
0.05 ppm
(Proposed to be revoked in May 1990)
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
Isopropalin may be used only as a pre-emergent herbicide on tobacco fields that
are not rotated with food or feed crops.
SOURCES OF ISOPROPALIN
Total Isopropalin Produced;
Isopropalin is produced by Eli Lilly and Co. No production data are available (SRI,
1986).
C-117
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One report states that other dinitroaniline herbicides are used more widely than
isopropalin. This would make isopropalin production in the U.S. less than 4,000
tons per year (Green £l aL, 1987).
Uses of Isopropalin
Isopropalin is a dinitroaniline compound used as an herbicide to control grasses
and broadleaf weeds in the vegetable crops of peppers and tomatoes (Ouellette and
King, 1977; Worthing, 1983; Farm Chemicals Handbook. 1985).
The only currently registered use for isopropalin is as a preemergent spray for
controlling weeds in tobacco crops (Worthing, 1983; IRIS, 1989).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based upon it's physical/chemical properties, isopropalin is predicted to volatilize
relatively rapidly from water (H = 1.5 x 10*4 atm m3/mol) and at a slower rate from
surface soil (P/SKoc = 4.4 x 10 mm Hg«L/mg corresponding to an estimated
volatilization half-life of 3.6 days).
It adsorbs relatively strongly to soils and sediments (estimated Koc = 8.5 x 104),
and has a high potential for bioaccumulation (estimated BCF = 2.5 x 10 ) (Lyman
, 1982).
IsopropaUn has a low potential for leaching from soils. Holzer and Sieck (1972)
reported that isopropalin and its associated breakdown products which formed
during 30 days of aerobic incubation were relatively immobile in a sandy loam soil.
Approximately 99% of the radio-labeled compound initially applied as 14C-
isopropalin remained in the top 2 inches of a 12 inch sandy loam column after 45
days of elution with 0.5 inches water/day.
Sleight ( 1972) reported maximum isopropalin concentrations of 25-40 mg/kg in the
edible tissues of bluegill sunfish during 42 days of exposure to 0.025 mg/L. The
tissue to water concentration ratios correspond to non-steady state BCF values of
Persistence:
Saunders and Smith (1983) reported that at 24°C, isopropalin did not undergo any
detectable hydrolysis over a 42 day period at pH values of 5,7, and 9.
C-118
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Saunders and Smith (1983) reported a short photodegradative half-life of 1.5 hours
for isopropalin in a pH 7 buffered aqueous solution exposed to artificial light with
a similar irradiation spectrum to that of sunlight.
Biodegradation of isopropalin in soil occurs. The specific processes include
dealkylation, reduction of nitro groups to amino groups. Twelve different break-
down products, representing at most 4% of the parent compound, were identified
(Golab and Althaus, 1975). Golab (1983) reported relatively long 50% dissipation
times of approximately 6 months for 2 ppm isopropalin incubated at 23°C in a sandy
loam, a loam, and a clay loam soil under aerobic conditions. Golab and Sassic
(1983) reported that the degradation of isopropalin in a loam soil was more rapid
under anaerobic conditions (45% dissipated within 60 days) than under aerobic
conditions.
ISOPROPALIN OBSERVED IN THE ENVIRONMENT
No data available.
HEALTH EFFECTS
Carcinogenicity;
The carcinogenic potential of isopropalin has not been evaluated by the U.S. EPA
(IRIS, 1989). No experimental data have been found for carcinogenicity tests with
isopropalin.
Mutagenic Activity: No data found.
Reproductive Effects:
The U.S. EPA states that better studies on the reproductive effects of ispropalin
need to be conducted. In one rat study with isopropalin the only effects noted were
reduced weights and reduced food consumption in exposed mothers (IRIS, 1989).
Other Toxicological Effects:
Acute human toxicity due to short-term high dose exposure to isopropalin is
considered to be insignificant (Sittig, 1985).
Isopropalin at high doses (> 2000 mg/kg) caused eye and skin irritation in rabbits
(Worthing, 1983).
No fatalities were observed in chickens, dogs, mallard ducks or rabbits fed
isopropalin at 2000 mg/kg or quail fed a dosage of 1000 mg/kg (Worthing, 1983).
C-119
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Subchronic (90-day feeding) exposure of rats caused a reduction in the number of
red blood cells and alterations in organ weights at the highest dose (288 mg/kg/day).
The U.S. EPA does not require that chronic (long-term, low dose) exposure tests
be conducted because of isopropalin's use on tobacco. The U.S. EPA recognizes
that the use of tobacco products is detrimental to the consumer and that the use of
tobacco is voluntary. It may be possible then to avoid exposure to isopropalin
residues (IRIS, 1989).
Toxicological Effects Indices:
. Reference Dose (RfD): 1.5 x 10'2 mg/kg/day (IRIS, 1989).
Oral LDso rats and mice: >5000 mg/kg (Dreisbach, 1980; Sittig, 1985; Worthing,
1983).
LCso (96 hour): fathead minnow, > 0.1 mg/L; goldfish, > 0.15 mg/L.
C-120
-------
Molecular Weight:
Physical State @ 20°C:
PHYSICAL/CHEMICAL PROPERTIES
Value
309.4
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mole)
red-orange
liquid
N/A
390 (calc.)
N/A
N/A
0.08 (25°C)
3xlO'5(25.6°C)
LSxlO^calc.)
Log (Octanol-Water
Partition Coefficient), log Kow: 5.74 (calc.)
Soil Adsorption Coefficient, Koc (ml/g): 8.5x10 (calc.)
Fish Bioconcentration Factor, BCF: 2.5xl04 (calc.)"
Reference
Worthing, 1893
Worthing, 1983
Lymanetal., 1982
Herbicide Handbook,
1983
Herbicide Handbook,
1983
Lymanfilal., 1982
Lymanelal., 1982
Lymanelal., 1982
LymanfilaL, 1982
* Value used for estimating aquatic effect
C-121
-------
REFERENCES
*
Dreisbach, R.H. 1980. Handbook of Poisoning: Prevention, Diagnosis and Treatment.
Lange Medical Publications, Los Altos, California.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Golab, T. and Althaus, W.A. 1975. Transformation of Isopropalin in Soil and Plants. Weed
Science 22:165.
Golab, T. 1983. 14C-Isopropalin Aerobic Soil Degradation Study. Eli Lilly and Co. ABC-
0154.
Golab, T. and Sassic, KA. 1983. (14C) Isopropalin Anaerobic Soil Degradation Study. Eli
Lilly and Co. ABC-0155.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Croplmprovement and Pest
Management. 3rd ed. Pergamon Press, Oxford, England.
Herbicide Handbook. 1983. Weed Science Society of America. 5th ed.Champaign, Illinois.
Holzer, F.J. and Sieck, R.F. 1972. EL-179 Leaching Study on Degradation Products. Eli Lilly
Co. and Purdue University. CDL: 126281-C; MRID #00002474.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Ouellette,R.P.andJ.A.King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co,. New York.
Saunders, D.G. and Smith, S.K. 1983. Photodegradation of Isopropalin in Aqueous Solution.
Eh' Lilly and Co. l-EWD-83-02.
Sittig, M., ed. 1985. Pesticide Manufacturing and Toxic Materials Control Encyclopedia.
Noyes Data Corp., Park Ridge, New Jersey.
Sleight, R.H. 1972. Research Report: Accumulation and Persistence of 14C-EL-179 Resi-
dues of Bluegill. (Lepomis macrochirus) continually exposed to the chemical in water. Eli
Lilly and Co. CDL: 126281-D; MRID #00002475.
Smith, S.K. and Saunders, D.G. 1983. Hydrolysis of the Herbicide Isopropalin in Aqueous
Buffer Solution. Eh' Lilly and Co. l-EWD-82-33.
C-122
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Stanford Research Institute (SRI). 1986. Directory of Chemical Producers. Stanford Research
Institute, Menlo Park, California.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-123
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C-124
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LINDANE
- HEXACHLOROCYCLOHEXANE)
CAS No.: 58-89-9
CAS Preferred Nomenclature:
Cyclohexane, 1,2,3,4,5,6-hexachloro-,
Empirical Formula: CgHeGe
Synonyms and Common Names:
- y-Benzene hexachloride -y-Hexachlorocyclohexane
-y-BHC -Gammexane
-y-HCH -Jacutin
- y-Hexachlorobenzene -Lindex
C6H6CI6
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish) (IRIS,
1989):
625\lQ~2ftgfL
EPA Ambient Water Quality Criteria
(for protection of aquatic organ-
isms)(IRIS, 1989):
Freshwater Saltwater
Acute,//g/L 2.0 1.6x10"
Chronic, ^g/L S.OxlO"2
EPA Drinking Water Health Adviso-
ries (PHRED, 1988)
child (10 kg):
1-day and 10-day exposure =
1200 fig/L
longer-term exposure = 33/fg/L
adulL(70 kg):
longer-term exposure = 0.12/ug/L
lifetime exposure = 0.2/jg/L
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
C-125
-------
EPA Drinking Water Standard Food and Drug Administration Ac-
(IRIS, 1989): tion Level for Other Foods (55 FR
Current Maximum Contaminant 14362)
Level = 0.004 mg/L 0.1 to 0.5 ppm
Proposed Maximum Contaminant
Level = 0.0002 mg/L
Proposed Maximum Contaminant
Level Goal = 0.0002 mg/L
FDA Action Levels are for use in in-
terstate commerce
Use Restrictions and Bans:
In 1977, EPA banned inclusion of a-and /J-hexachlorocyclohexane in technical
grade lindane.
Use in smoke fumigation devices for indoor domestic purposes banned in 1985 (48
FR 48512,50 FR 5424).
Use of lindane in dog dips for the control of pests (other than mites) permitted only
for veterinary use (U.S. EPA, 1985).
Application permitted only under direct supervision of a certified applicator.
Protective clothing required (U.S. EPA, 1985).
SOURCES OF LINDANE
Total Lindane Produced;
First synthesized in 1825, lindane's insecticidal properties were discovered in 1942
(Hayes, 1982).
In 1971,1 million Ibs. were produced by Occidental Petroleum Corporation (Ouell-
ette and King, 1977).
Technical lindane (a mixture of several isomers of hexachlorocyclohexane) is no
longer produced in the United States, but is imported from France, Germany,
Spain, Japan, and China (U.S. EPA, 1985). It is an off-white to brown powder with
a persistent, musty odor (Hayes, 1982).
Uses of Lindane;
Lindane is registered for use as an insecticide/acaracide on a variety of fruit and'
vegetable crops, ornamentals, tobacco, forestry, domestic outdoor and indoor uses
by homeowners, commercial warehouses or feed storage areas, farm animal prem-
ises, and wooden structures (U.S. EPA, 1985).
C-126
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Undane is primarily used on phytophagous and soil-inhabiting insects, public health
pests, and animal ectoparasites (Farm Chemicals Handbook, 1987).
In 1982, approximately 48%, 20%, and 19% of the Undane use in the U.S. was for
seed treatment, livestock and hardwood lumber, respectively.
Other Sources: Component of other hexachlorocyclohexanes.
FATE OF LINDANE IN THE ENVIRONMENT
Partitioning;
Based upon it's physical/chemical properties, lindane is predicted to volatilize
relatively slowly from water (H = 4.9 x 10~7 atm» m3/mol), volatilize at an inter-
mediate rate from soil surfaces (F/SKoc = 33 x 10 mm Hg L/mg, correspond-
ing to an estimated volatilization half-life of 18 days), and have intermediate
adsorption to soils and sediments (Koc = 3.8 x 103) (Lyman el al, 1982).
Kay and Elrick (1967) reported intermediate soil/water partition coefficients (Kp)
of 23,20, and 17 for Undane adsorbed to a sandy loam (organic carbon content (oc)
of 3.2%), loam (oc = 3.6%), and loamy sand (oc = 2.9%) soil, respectively. The
corresponding Koc values are 720,560, and 590, respectively. Foschi, si al., 1970
reported that Undane is moderately susceptible to leaching from a low organic soil.
After elution with 35 inches of water, 80%, 19%, and 1% of the total lindane
recovered from a 60 cm sandy clay loam (oc = 1.5%) column were recovered in
the 0 to 5 cm, 5 to 20 cm, and 20 to 40 cm segments, respectively. No lindane was
detected in the 40 to 60 cm segment or in the leachate.
Forbis (1986) reported maximum BCFs of 780 (edible tissue) and 1,400 (whole
body) for bluegill sunfish exposed to 0.54 ppb lindane over a 28 day period.
Persistence:
Based upon the hydrolysis rate constants measured by EUington £ial. (1986),
Undane has an intermediate hydrolysis half-life of 14 days at pH 9, and relatively
long hydrolysis half-lives of 210 days at pH 7 and 240 days at pH 5.
ADL (1986) reported a relatively long photodegradative half-life of 48 days for
Undane in water.
Biotransformation is favored in biologically rich, anaerobic environments. Half-
Uves range from several days to over a year (Callahan el al., 1979). Under some
conditions, Undane degrades to y-pentachlorocyclohexane (Kirk-Othmer, 1978).
C-127
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HEALTH EFFECTS
Carcinogenicity;
Evidence to determine whether y-hexachlorocyclohexane is a human carcinogen is
limited. The technical grade of lindane (containing approximately 65% a-
hexachlorocyclohexane) has been shown to cause liver cancer in four strains of mice.
Experiments performed on ratswere negative (Itofilal., 1975,Fitzhughelal., 1950).
The carcinogenicity data for lindane is presently under review by the U.S. EPA
(IRIS, 1989).
However, on the basis of mouse carcinogenicity the EPA has previously rated
lindane as a B-2 carcinogen (IRIS, 1989).
Mutagenic Activity:
Predominantly negative results have been obtained in mutagenicity testing of
lindane. Tsoneva-Maneva el at (1971) reported lindane induced alterations in
mitotic activity of Chinese hamster cells. Chromosomal breaks and gaps in Chinese
hamster cells have also been attributed to lindane exposure (Ishidata and
Odashima, 1971). Mutagenic effects were not observed in tests using bacteria
(Buselmaier elal, 1972; Schubert, 1969).
Reproductive Effects:
Lindane has been shown to cause disturbed estrous cycles, decreases in fetal
survival, and reduced numbers of live births in rats, delayed sexual maturation in
female rats (Shtenberg and Mametkulien, 1976), and increases in stillbirths in dogs
(Litterst and Miller, 1975).
Other lexicological Effects;
Acute lindane poisoning affects the nervous system causing restlessness, tremors,
unsteady gait, heavy breathing, and convulsions. Violent convulsions are rapid in
onset and generally followed by death or recovery within 24 hours. The probable
human oral lethal dose is 50-500 mg/kg (Klaassen fit at, 1986).
Rats fed diets containing lindane developed mild toxicity-related changes primarily
in the kidneys and also in the liver.
C-128
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lexicological Effects Indices;
Cancer Potency Factor (CPF): 1.33 (mg/kg/d)*1 (PHRED, 1988)
Technical Grade CPF: 1.8 (mg/kg/d)'1 (IRIS, 1989)
Reference Dose (RfD): SxlO"4 mg/kg/d (IRIS, 1989)
TWA-TLV (time-weighted average-threshold limit value) for occupational skin
exposure: 0.5 mg/m3 (ACGffl, 1986)
C-129
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PHYSICAL/CHEMICAL PROPERTIES FOR LINDANE
Molecular Weight (g/mole):
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Hydrolysis, kn (hr*1),
Kb (1/Mhr)
Value
290.85
colorless solid
112.9
323.4
1.87
N/A
7.52 0.4 @ 25°C
9.4xlO'6@200C
1.20.2xlO'4
198
4.9x10
,-7
Henry's Law Constant,
H @ 25°C (atm m3/mol):
Log (Octanol-Water Partition Coefficient),
logKow: 3.72
Soil Adsorption Coefficient, Koc(ml/g): 3.8 x 103
Fish Bioconcentration Factor, BCF:
780 edible tissue,
1400 whole body for
bluegill sunfish
130
Reference
Windholtz, 1983
IRIS, 1989
Callahanfiial, 1979
IRIS, 1989; Weast, 1979
Verschueren, 1983
Callahanfiial., 1979
IRIS, 1989; Windholz,
1983
Ellington £lal., 1987
Mills filaL, 1985
IRIS, 1989
LymanfilaL, 1982
Forbis, 1986
Value used for estimating aquatic effects
C-130
-------
REFERENCES
i
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Arthur D. Little (ADL), Inc. 1986. The Installation Restoration Program Toxicology Guide,
Vol. 2.
Buselmaier, W., G. Rohrborn, and P. Propping. 1972. Mutagenicity, Investigations with
Pesticides in the Host Predicted Assay and Dominant Lethal Test in Mice. Biol. Zbl.
21:311-325.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.P. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C Whitmore, and B. Margin. 1979. Water Related Environmental Fate of
129 Priority Pollutants. U.S. Environmental Protection Agency, Washington, D.C. EPA
440/4-79-029A..
Ellington, J J., F.E. Stancil, Jr., W.D. Payne, and C. Trusty. 1987. Measurement of Hydrolysis
Rate Constants for Evaluation of Hazardous Waste Land Disposal. Volume 2. Data on 54
Chemicals. U.S. Environmental Protection Agency, Athens, GA.
Farm Chemicals Handhnnlc. 1987. Meister Publishing Co. Willoughby, OH.
Fitzhugh, O.G., A.A. Nelson, and J.P. Frawley. 1950. The Chronic Toxicities of Technical
Benzene Hexachloride and its Alpha, Beta, and Gamma Isomers. J. Pharmacol. Exp Therap.
100:59-66.
Forbis, A.D. 1986. Uptake, Deouration, and Bioconcentration of C-Lindane by .Bluegill
Sunfish (Lepomis macrochiurus). Analytical Bio-Chemistry Laboratories. Ace. No. 400561-
02.
Foschi, S., Cesari, A, £1 al. 1970. Investigation into Degradation and Vertical Movement of
Agricultural Chemicals in Soil. Notiz. Mai. Pliante 82(37).
Hayes, W.J. Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc. Baltimore, MD.
Integrated Risk Information Service (IRIS). 1989. U.S. EPA, Washington, D.C.
Ito, N., H. Nagaski, H. Ade. 1975. Development of Hepatocellular Carcinomas in Rats
Treated with Benzene Hexachloride. J. Natl. Cancer Inst. 5^:801-805.
Kay, B.D. and Elrick, D.E. 1967. Adsorption and Movement of Lindane in Soils. Soil Sci.
104(5):314-322.
C-131
-------
Kirk-Othmer. 1978. Encyclopedia of Chemical Technology 1982. 3rd ed. John Wiley and
Sons, Inc., NY.
Klaassen, CD., MO. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology: The
Basic Science of Poisons. Srded. MacMillen Publishing Co., NY.
Litterst, C.L. and E. Miller. 1975. Distribution of Lindane in Basins of Control and
Phenobarbitol Pretreated Dogs at the Onset of Lindane Induced Convulsions. Bull. Environ.
Contain. Toxicol. 13:619.
Lyman, W J., Reehl, W.F., and Rosenblatt, D.H. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co.
Mills, W.B., D.B. Porcella, MJ. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and DA. Haith. 1985. Water Quality Assessment: A Screening Procedure for Toxic
and Conventional Pollutants in Surface and Ground Water. U.S. Environmental Protection
Agency, Athens, GA. EPA 600/6-85/002a.
Ouellette, R.P. and J.A. King. 1977. Chemical Week: Pesticides Register. McGraw-Hill Book
Co., NY.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. EPA, Office of Emergency
and Remedial Response, Washington, D.C.
Schubert, A. 1969. Investigations on the Induction of Respiration Deficient Yeast Mutants
by Chemical Herbicides. Z. AUg. Mikrobiol. (Gier.) 2:77.
Shtenberg, A.I. and C. Mametkulian. 1976. The Effect of Gamma-Isomer of
Hexachlorocydohexane (HCHH) on the State of Sexual Glands in Rats. Vap. Pitan (Rus).
1:62.
U.S. EPA. 1985. Guidance for the Registration of Pesticide Products Containing Lindane as
the Active Ingredient. United States Environmental Protection Agency Office of Pesticide
Programs. EPA540/RS-86-121.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. Office of Solid Waste and
Emergency Response, Washington, D.C. EPA-540/1-86/060.
U.S.EPA. 1987. Draft of RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency Office of Solid Waste. EPA 530/SW-87-001.
U.S.EPA. 1988. Treatabability Manual I. Treatability Data. EPA 600/2-82-001A.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. Van
Nostrand. Reinhold,NY.
C-132
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Windholz, M, ed. 1983. The Merck Index: An Encyclopedia of Chemicals. Drugs, and
Biologicals. Merck and Co., Rahway, NJ.
C-133
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C-134
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MERCURY
CAS No.: 7439-97-6
CAS Preferred Nomenclature: Mercury
Formula: Hg, can occur in elemental and
inorganic and organic (methyl) forms
Synonyms and Common Names: Quicksilver
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for EPA Drinking Water Health Adviso-
human consumption of fish) (45 FR ries (for inorganic mercury)
79318) (IRIS, 1989): (IRIS, 1989)
0.153 fig/L adult (70 kg):
long-term and lifetime exposure
EPA Ambient Water Quality Criteria Food and Drug Administration Ac-
(for protection of aquatic organ- tion Level for Fish (40 FR 45663):
isms)(IRIS, 1989): 1 ppm
Freshwater Saltwater
Acute,/
-------
Use Restrictions and Bans;
All uses as a bactericide or fungicide banned after 8/7&except the following (41FR
16497,41 FR 26743,41 FR 36068):
- treatment of textiles for outdoor use
- control of brown mold on new lumber
- in-can preservative in water-based paints
- for exterior use
SOURCES OF MERCURY
Natural Sources;
Mercury occurs in nature (about 3x10 % of earth's crust) mostly in combination
with sulfur to form more than 25 different minerals. Commercially, the most
important mineral is cinnabar (HgS), from which elemental mercury (Hg) is
extracted (USDI, 198S). Mercury can occur as elemental Hg, as well as inorganic
and organic (organomercurial) forms. It forms complexes with organic ligands,
chlorides and sulfur compounds.
Degassing contributes an estimated 25,000 to 150,000 tons per year to the atmo-
sphere, compared to about 5,000 tons per year from fossil fuel burning (Klaassen
filai, 1986).
Total Mercury Produced;
1.6 million pounds (USDI, 1986).
Industrial Uses of Mercury;
Electrical applications including the production of mercury cell batteries, mercury
vapor lamps, thermostats, cathode tubes and switches.
Catalyst in the production of urethane polymers for use in plastics.
Cathode in the electrolytic production of chlorine and caustic soda (U.S. EPA,
1987).
Uses of Mercury In Homes and Businesses;
Batteries for many small electronic devices such as calculators, hearing aids and
cameras
Thermometers and barometers
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Amalgamated with silver and tin to form tooth fillings.
Uses as Fungicide/Bactericide (Limited see Regulatory Status);
A fungicide in some exterior water-based paints
Formerly as a fungicide in paper products and for the protection of seed grain from
mildew
As preservative in laboratories.
FATE IN ENVIRONMENT
Partitioning
The fate of mercury depends on its speciation, pH, redox conditions and presence
of complexing ions including organic ligands, chloride and sulfhydryl groups (-SH).
Mercury exists in the 0 (metallic), 1 + (murcurous) and 2 + (mercine) forms. The
+1 species can hydrolyze to form Hg(OH)z. The 2 + species can hydrolyze to form
the species Hg(OH)+, Hg(OH)2, and Hg(OH)3 (Rubin, 1976). The relative
amounts of each species are dependent on pH.
Examples of Hg complexes include Hg(OH)2 under alkaline conditions and HgCh
under acidic conditions. In alkaline sediments under moderately reducing condi-
tions, dimethyl mercury can form which is insoluble and highly volatile. At neutral
and lower pH values, monomethyl mercury can form. Under strongly reducing
conditions (e.g., in the presence of hydrogen sulfide (H2S)), mercury can precipitate
as HgS which is insoluble (Nriagu, 1979).
Persistence:
Mercury is readily sorbed to soil organic matter, clays and hydrous metal oxides
with the exception of some organic chloride-Hg complexes, e.g. CHsHgCl .
Methylmercuric chloride has a Kow value of about 2.0 (Medeiros, 1980). Mercury
is also bioaccumulated. BCF values for inorganic mercury range from 1,800 to
5,000. BCF values for organic mercury are higher (10,000 to 82,000). Most of the
mercury in fish is present in the methyl form.
Mercury is biologically methylated and in limited amounts may be lost from soils
by volatilization (LymanfilaL, 1987).
HEALTH EFFECTS
Carcinogenicity;
Mercury has not been shown to cause cancer in humans.
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Rats have developed local tumors at the point of injection of metallic mercury (U.S.
EPA, 1984).
The EPA designates mercury as a Group D chemical, not classified (U.S. EPA,
1984).
Mutagenic Activity;
Methyl mercury was shown to be a weak mutagen in experiments with fruit flies
(U.S. EPA, 1981). Mercuric salts were not mutagenic in tests using nonmammalian
cells, but results using mammalian cells were inconclusive.
Reproductive Effects;
Both inorganic and organic forms of mercury are toxic to developing fetuses. The
fetal nervous system is particularly sensitive, with mercury disrupting and delaying
nerve cell development. Fetuses chronically exposed (low doses over long time
periods) to organic mercury are born mentally retarded and exhibit cerebral
palsy-like symptoms (Marsh, 1987).
Other lexicological Effects;
Mercury toxicity in humans produces a number of different symptoms depending
on whether the exposure is of a short-term, high dose (acute) type or long-term, low
dose (chronic) type. Elemental mercury vapor produces an acute pneumonitis.
Inorganic mercury salts can cause acute gastrointestinal distress and renal failure.
(The lethal dose of mercuric chloride in humans is 1 to 4 g.) Both of these forms,
as well as the organic mercurials, produce neurologic effects after chronic exposure
to mercury. Eye and skin irritation can also occur (Sittig, 1985).
Symptoms such as numbness of the extremities, tremors, spasms, personality and
behavior changes, difficulty in walking, deafness, blindness and death have been
associated with the long-term ingestion of mercurycontaminated fish. (U.S. EPA,
1981).
Toxicological Effects Indices;
RfD (Reference Dose): 0.002 mg/kg/day for inorganic mercury compounds and
0.0003 mg/kg/day for alkyl (organic forms) or mixed alkyl-inorganic mercury (U.S.
EPA, 1986).
TWA-TLV (Time-weighted average, threshold limit value for occupational expo-
sures): 0.01 mg/m alkyl mercury for skin exposure and 0.05 mg/m for vapor
exposure (ACGffl, 1986).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa
Water Solubility (mg/L):
Vapor Pressure, (mm Hg):
Henry's Law Constant @ 25°C
(atm m3/mol):
Hydrolysis Rates:
Log (Octanol-Water Partition
Coefficient), log Kow:
Partition Coefficient, Kp (ml/g):
(Inorganic Hg)
Fish Bioconcentration Factor,
BCF:
200.6
liquid
-38.87
356.72
13.534 (25°C)
N/A
0.056 (25°C)
2xlO'3 (25°C)
Hg° 6.97xlO'3
(CH3)2Hg - 7.45xl03
Hg(OH)2 = -8
1 + and 2 + forms
hydrolyze, specific rate
constants not found
CHsHgCl =0.3
= 0.4
1,000- IxlO6 I/kg
1800-4994
(inorganic)
10,000-81,670*
(organic)
5,500
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Wmdholz, 1983
Windholz, 1983
Lindquistfiial., 1984
Lindquistfiial., 1984
Rubin, 1976
Medeiroseial.,1980
Halbach, 1985
Gherini and
Rajashenkar, 1975
U.S. EPA, 1985
U.S. EPA, 1985
Olson eial., 1975
U.S. EPA, 1980
* Value used for estimating aquatic effect
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REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Bloom, N. 1988. Determination of Methylmercury in Water at the Femtomolar (pg/L) Level
Following Aqueous Phase Ethylation with Sodium Tetraethylborate, EPRI Project Report,
Palo Alto, California.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. II. Office of Water
Planning and Standards, U.S. Environmental Protection Agency. EPA-440/79-029b.
Gherini, S.A. and P. Rajashenkar, 1975. A Study of the Water Quality Impact of the Im-
plementation of Air Quality Standards. U.S. EPA Contract No. 68-01-2243.
Halbach S., The Octanol Water Distribution of Mercury Compounds, Short Communication,
Arch. Toxicol., 57: 139-141,1985
IRIS, 1989. Integrated Risk Information System Database. U.S. EPA, Washington, D.C.
Kirk-Qthmer Encyclopedia of Chemical Technology. 1982. 3rd Edition. John Wiley and
Sons, Inc., New York.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Poult's Toxicology, The
Basic Science of Poisons. 3rded. Macmillan Publishing Co., New York.
Lindquist, O., A. Jernelov, K. Johansson, and H. Rodhe. 1984. Mercury in the Swedish
Environment: Global and Local Sources. Report No. 91-7590-154-4. Prepared for the
National Swedish Environment Board.
Lyman, W.L., I. Bodek, W.F. Reehl, and D.H. Rosenblatt. 1987. Methods for Estimating
Physicochemical Properties of Inorganic Chemicals of Environmental Concern. U.S. Army
Medical Research and Development Command, Fort Detrick, MD. Contract No. DAMD
17-83-C-3274.
Marsh, D.O. 1987. Dose-Response Relationships in Humans: Methyl Mercury Epidemics
in Japan and Iraq. In: The Toxicitv of Methyl Mercury. (C.U. Eccles and Z. Annau, eds).
Johns Hopkins University Press. Baltimore, MD.
Medeiros D., Cadwell L., and Preston R., A Possible Physiological Uptake Mechanism of
Methylmercury by the Marine Bloodworm (Glycera dibranchiata), Bull. Environm. Contam.
Toxicol., 24:97-101,1980.
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Nriagu, J.O., ed. 1979. The Biogeochemistry of Mercury in the Environment. Elsevier/North-
Holland Biomedical Press, New York.
Olson, G.F., D.J. Mount, V.M. Snarski, and T.W. Thorslund. 1975. Mercury Residues in
Fathead Minnows, Pimpehales promelas Rafinesque, Chronically Exposed to Methyl Mercury
in Water. Bulletin of Environmental Contamination and Toxicology, v. 14, no. 2.
Rubin, A.J., ed. 1976. Aqueous-Environmental Chemistry of Metals. Ann Arbor Science
Publishers, Inc., Ann Arbor, Michigan.
Sittig, M. 1985. Handbook nf Toxic and Hazardous Chemicals and Carcinogens. 2nd ed.
Noyes Publications, Park Ridge, New Jersey.
U.S. Department of the Interior. (USDI). Bureau of Mines. 1986. Mineral Commodity
Summaries 1986. U.S. Government Printing Office, Washington, D.C. Publication No. 1986-
606-225.
U.S. EPA. 1980. Ambient Water Quality Document. EPA 440/5-80 Series.
U.S. EPA. 1981. An Exposure and Risk Assessment for Mercury. Office of Water Regula-
tions and Standards, Washington, D.C. EPA-440/4-85-011.
U.S. EPA. 1984. Health Effects Assessment for Mercury. Office of Emergency and Remedial
Response, Washington, D.C. EPA-540/1-86-042.
U.S. EPA. 1985. Ambient Aquatic Life Water Quality Criteria for Mercury. Office of
Research and Development, Duluth, Minn. PB85-22745.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. EPA Office of Solid
Waste and Emergency Response, Washington, D.C. EPA-540/1-86/060.
U.S. Department of the Interior (USDI). Bureau of Mines. 1985. Minerals Facts and
Problems. 1985 ed. Bulletin 675. U.S. Printing Office, Washington, D.C.
Windholz, M.-, ed. 1983. The Merck Index; An Encyclopedia nf Chemical.sr Drugs, and
Biolngicals. 10th ed. Merck & Co., Rahway, New Jersey.
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MERCURY
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
Mercury is toxic to mink at diet concentrations of 1 to 2 ppm (Wren 1989). This finding is
consistent with the lethal dose reported by the State of Wisconsin (WDHSS 1988).
The effects of mercury in piscivorous wildlife are summarized in the following table:
Effects of Mercury Concentrations on Piscivorous Wildlife
Animal Concentration Effect Source
Mink l.Omg/kg Death WDHSS, 1988
(diet)
Mink 1-2 ppm (diet) Death Wren, 1989
River Otter >2.0mg/kg Death WDHSS, 1988
(diet)
REFERENCES
Wisconsin Department of Health and Social Services (WDHSS). 1988. Technical Support
Document for Chapter MR 105 of the Wisconsin Administrative Code. Division of Health.
Madison, Wisconsin.
Wren, C.D. 1989. Personal Communication. BAR. Environmental. Nicholas Beaver Park,
RR3, Guelph, Ontario, Canada.
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METHOXYCHLOR
CAS No.: 72-43-5
CAS Preferred Nomenclature:
Benzene, 1, l'-(2,2,2-trichloroethyh'dene)
bis (4-methoxy)-
Empirical Formula: Ci6Hi5ClsO2
Synonyms and Common Names:
- Methoxy-DDT - Marlate
- DMDT - Dianisyl trichloroethane
- Maralate - Dimethoxy-DT
- p,p'-Dimethoxydiphenyl - Metox
- trichloroethane
CH,0
OCH,
C16H15CI3°2
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of water and
fish)(U.S. EPA, 1987):
EPA Drinking Water Health Adviso-
ries (U.S. EPA, 1987; PHRED, 1988):
Child (10 kg):
1 day exposure = 6.0 mg/L
10 day exposure = 2.0 mg/L
long-term exposure = 0.5 mg/L
adult (70 kg):
long-term exposure = 2.0 mg/L
lifetime exposure = 0.4 mg/L
EPA Ambient Water Quality Criteria EPA Tolerance Levels for Food (40
(for protection of aquatic organisms): CFR 180.120):
Freshwater Saltwater 1-14 ppm
Acute, ^g/L -
Chronic,/4g/L 0.03 0.03
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EPA Drinking Water Standards (50 Food and Drug Administration Ac-
FR 46936; IRIS, 1989): tion Level for Fish
Current Maximum Contaminant None established at present
Level = 0.1 mg/L
Proposed Maximum Contaminant
Level = 0.4 mg/L
Proposed Maximum Contaminant
Level Goal = 0.4 mg/L
Use Restrictions and Bans:
None found.
SOURCES OF METHQXYCHLQR
Total Methoxychlor Produced;
Methoxychlor is an organochlorine pesticide with a similar chemical structure to
DDT. It was first introduced in 1945.
In 1971, 9.9 million pounds were produced by the companies Chemical Formula-
tions, DuPont, and Prentiss (Ouellette and King, 1977).
By 1982, very little methoxychlor was being produced. Current data are unavail-
able, but the volume produced by the two listed producers, Drexel Chemical
Company and Kincaid Enterprises, is also likely to be small (SRI, 1986; Green £i
at, 1987).
Uses of Methoxychlor:
Like DDT, methoxychlor is effective against a wide range of insects that affect fruits,
vegetables, forage crops and livestock (Hayes, 1982; McEwen and Stephenson,
1979).
Hundreds of products containing methoxychlor are registered for insect control in
foliar treatment, dormant application, seed or soil treatment and post-harvest
application of many crops (U.S. EPA, 1986).
Methoxychlor is used primarily to control houseflies, blackflies and mosquitos in
areas of human habitation including hotels, bakeries, meat processing plants, flour
mills and dairy barns (Worthing, 1983; U.S. EPA, 1986; McEwen and Stephenson,
1979).
Mosquito control uses also include methoxychlor treatment of stagnant ponds,
streams and other aquatic recreation areas (U.S. EPA, 1986).
Methoxychlor is also used in mothproofing (U.S. EPA, 1986).
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Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based on its' physical/chemical properties, methoxychlor is estimated to be volatile
(H = 1.5xlO"5 atm m3/mole), strongly sorbed to soil (Kow- 47,900), and has a
high potential for bioaccumulation (BCF = 8,300), although some empirical data
show a more moderate potential for bioaccumulation.
Persistence;
Methoxychlor is considered to be moderately biodegradable (Wolfe el al, 1977).
Methoxychlor is estimated to have a half-life for direct photolysis in water (in the
central U.S.) of 4.5 months, and also undergoes indirect photolysis (Wolfe el al,
1977); photolysis half-lives of 2-5 hours have been observed in river water (TDB,
1985). The rate of hydrolysis has been found to be independent of pH under
environmental conditions, with a half-life of about 1 year at 27°C (Wolfe el al.,
1977).
HEALTH EFFECTS
Carcinogenicity;
The evidence for methoxychlor carcinogenicity is inconclusive, according to the
U.S. EPA Carcinogen Assessment Group's review of a National Cancer Institute
Bioassay (HSDB, 1988). The EPA has not yet classified its carcinogenic potential
(PHRED, 1988).
No cancers were observed in four experiments with rats fed 1,000 mg/kg or in one
mouse feeding experiment (LARC, 1979).
Mutagenic Activity;
Methoxychlor was found not to be mutagenic in bacterial and yeast cell assays as
well as in a mouse dominant lethal test (LARC, 1979).
It was weakly positive in a mammalian cell transformation assay (HSDB, 1988).
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Reproductive Effects;
Adverse reproductive effects have been reported. In studies with rats a dietary level
of 1% methoxychlor has produced testicular atrophy, inhibition of spermatogenesis
and arrested folliculogenesis (IARC, 1979; HSDB, 1988).
Methoxychlor is also reported to be fetotoxic in rats, causing wavy ribs, but only at
doses (100-400 mg/kg) causing maternal toxicity. There is no evidence of any
teratogenesis at lower doses (IARC, 1979; Hayes, 1982; HSDB, 1988).
Other Toxicological Effects;
In man, acute, short-term, high doses, up to 2 mg/kg/day, have not been shown to
cause any adverse effects.
Animals exposed to high doses of methoxychlor have exhibited a variety of symp-
toms. Dogs fed 2,000 or 4,000 mg/kg for two years developed nervousness, tremors
and convulsions. Rats had similar central nervous system effects as well as severely
retarded growth (Hayes, 1982; HSDB, 1988). Kidney injury and uterine and
mammary enlargement were observed in pigs, while monkeys had liver and intes-
tinal damage (IARC, 1979; HSDB, 1988).
Toxicological Effects Indices;
Adjusted Reference Dose for drinking water: 1.7 mg/L (50 FR 46936).
TWA-TLV (time-weighted average, threshold limit value) for occupational expo-
sure: 10 mg/m3 (ACGffl, 1986).
Oral LD50: rat, 5-7 mg/kg; mouse, 1.8 mg/kg (IARC, 1979; HSDB, 1988).
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm m3/mol):
345.7
colorless crys-
tals, solid
89
416 (calc.)
1.41 (25°C)
N/A
IxlO'1
1.3xlO'6(200C)
(calc.)
1.5xlO'5 (calc.)
Log (Octanol-Water Partition Coefficient),
log Kow: 4.68
Soil Adsorption Coefficient, KOC (ml/g): 8xl04
Fish Bioconcentration Factor, BCF: 1.9xl02-1.6xl03
(exptl.)
8300'
Windholz, 1983
Hayes, 1982
Worthing, 1983
LymanfiiaL, 1982
Hartley & Kidd, 1983
PHRED, 1988
LymaneJal, 1982
LymanfitaL, 1982
PHRED, 1988
PHRED, 1988
Kenaga, 1980
PHRED, 1988
* Value used for estimating aquatic effects
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Press
Management. 3rd ed. Pergamon Press, Oxford, England.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
Hayes, W J., Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc., Baltimore, MD.
HSDB. 1988. Hazardous Substances Data Base. Computer printout: Methoxychlor. Re-
trieved May 16,1988. Bethesda, MD. National Library of Medicine.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, B.C.
Kenaga, E.E. 1980. Correlation of bioconcentration factors of chemicals in aquatic and
terrestrial organisms with their physical and chemical properties. Environ. Sci. Technol.
14:553-556.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Matsamura, F. 1985. Toxicology of Insecticides. 2nd ed. Plenum Press, New York.
McEwen, F.L. and G.R. Stephenson, 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, New York.
Ouellette, R.P. and J.A King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. EPA, Office of Emergency
and Remedial Response, Washington, D.C.
Stanford Research Institute (SRI). 1986. Directory of Chemical Producers. Stanford Re-
search Institute, Menlo Park, California.
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Toxicology Data Bank (TDB) database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number
of products registered.
U.S. EPA 1987. Office of Drinking Water. Methoxychlor Health Advisory. Environmental
Protection Agency, Washington, D.C.
Windholz, M., ed. 1983. The Merck Index; an encyclopedia of chemicals, drugs and hinlog-
icals. 10th ed. Merck & Co., Rahway, New Jersey.
Wolfe, N.L., R.G. Zepp, D.F. Paris, G.L. Baughman, and R.C. Hollis. 1977. Methoxychlor
and DDT degradation in water: rates and products. Environ. Sci. Technol. 11:1077-1081.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
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C-150
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MIREX
CAS No.: 2385-85-5
CAS Preferred Nomenclature:
l,3,4-Metheno-lH-cyclobuta(cd)
pentalene, 1, la,2,2,3,3a,4,5,5,5a,5b,6-
dodecachloro-octahydro-
Empirical Formula: CioCli2
C10CI12
Synonyms and Common Names:
- Dechlorane - Perchloropentacyclodecane
- Hexachlorocyclo- - Ferchlorodi-homocubane
- pentadiene dime - Ferriamicide
- Paramex
- Dodecachlorooctahydro-l,3,4-metheno-2H-cyclobutal (cd) pentalene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Drinking Water Health Adviso-
ries:
None established at present
EPA Ambient Water Quality Criteria Food and Drug Administration Ac-
(for protection of aquatic organ- tion Level for Fish (43 FR 14736):
isms)(IRIS, 1989): O.lOppm
Freshwater Saltwater
Acute, ^ug/L - -
Chronic, ^g/L 0.001 0.001
FDA Action Levels are for use in in-
terstate commerce
EPA Drinking Water Standards Max-
ium Contaminant Level:
None established at present
Use Restrictions and Bans;
All registered uses were cancelled as of 1977 (41 FR 56703).
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All existing stock were not to be sold, distributed or used after June 30,1978 (N AS,
1978).
SOURCES OF M1REX
Total Mirex Produced:
3.3 million Ibs. was produced by Hooker Chemicals and Plastics Co. between 1959
and 1975 (Suta, 1977). Twenty-five percent was used as a pesticide and the
remainder as a fire retardant. Commercial production stopped in 1978.
Uses of Mirex;
Mirex was used primarily for the control of the imported fire ant in eight southeast-
ern states from 1962 to 1975. Approximately 250,000 kg were used to treat 14
million acres (NAS, 1978; Kutz el al, 1985). Mirex was also used in Hawaii to
control the pineapple mealy-bug (Suta, 1977).
Mirex was also used as a fire retardant in plastics, rubber, paint, paper and electrical
products (KutzfilaL, 1985; Windholz, 1983).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, mirex is predicted to have a relatively
low volatility from water (H = 2.2 x 10"5 atm m3/mol at 25°C), low volatility from
surface soil (P/S Koc = 1.3 x IQ'U mm Hg L/mg corresponding to an estimated
volatilization half-life of >30 years), a strong adsorption to soils and sediments
(Kow = 199,500 and Koc = 2.4 x 10 ) and a high potential for bioaccumulation
(BCF = 2.6 x 103 - 4.1 x 104) (Lyman filal., 1982).
Persistence:
Mirex is thermally and chemically very stable and resistant to biodegradation (Bell
el al, 1978). There is some evidence that mirex can be biotransformed into
chlordecane (Kepone) in soil (Klaassen elal., 1986). However, mirex applied at 1
Ib/acre to a Mississippi soil was reported to have a 50% dissipation time of > 2.5
years (State of Mississippi, 1982 as cited by U.S. EPA, 1982). Mirex appears to be
persistent in the aquatic environment as evidenced by no reported significant
decreases in the concentration of mirex in a water/sediment system over a 130 day
period (State of Mississippi, 1982 as cited by U.S. EPA, 1982).
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Photolysis of mirex in water can occur, but at a slow rate (Verschueren, 1983). The
rate determined experimentally using river water in sunlight was 0.0042/day (Smith
elai, 1978).
HEALTH EFFECTS
Carcinogenicity;
Hepatomas and liver-cell carcinomas were observed in mice and rats fed mirex in
their diet. Mirex has been classified as a probable human carcinogen, (2b) by IARC
(1979). The carcinogenic data for mirex are presently under review by the U.S.
EPA (IRIS, 1989).
The results of one animal cancer study (Ulland el aL, 1977) have been analyzed
using a dose-response model not typically used by the EPA. This one-hit model
was used to derive a possible carcinogenic potency factor of 0.354 (mg/kg/day)"1
(U.S. EPA, 1982).
Mutagenic Activity;
Negative in dominant lethal assay in mice (IARC, 1979). Not generally active in
short-term tests (WHO, 1984).
Reproductive Effects;
Some studies have reported that mirex is fetotoxic (25 mg/kg) and teratogenic
(causing cleft palate, heart defects, cataracts) to rats (6 mg/kg/day). Also, fewer and
less viable offspring were born to mice fed 1.8 mg/kg for 3 months (WHO, 1984;
.KlaassenfiiaL, 1986). Voles also had decreased pup survival when exposed to mirex
in the diet (IRIS, 1988). Further studies must be done to confirm these results
(IRIS, 1988).
Other lexicological Effects;
Acute hepatotoxicity (liver toxicity) was noted in rats after oral administration of
mirex (IARC, 1979). Liver hypertrophy observed in rats fed 1 mg/kg for 14 days
(WHO, 1984).
Chickens exposed to mirex had depressed levels of certain types of antibodies (IgG
and IgM) (Klaassen £i ai., 1986).
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Toxicologicai Effects Indices;
Cancer Potency Factor (CPF): 1.8 (mg/kg/day)"1 (HEAST, 1989).
Reference Dose (RfD): 2 x 10"6 mg/kg/day (IRIS, 1989).
Oral LDso: rat, 740 mg/kg (IARC, 1979).
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Molecular Weight:
Physical State @ 20°C:
PHYSICAL/CHEMICAL PROPERTIES
Value
545.6
solid, snow-
white crystals
485 (decomp.)
N/A
N/A
N/A
0.2 (24°C)
Melting Point (°C):
Boiling Point (°C):
Density/Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm m3/mol): 2.2xlO'5
Log (Octanol-Water Partition Coefficient),
log Kow: 5.3
Soil Adsorption Coefficient, Koc (ml/g): 2.4xl07
Fish Bioconcentration Factor, BCF: 2.6xlO*4.1xlQ4*
(exptl.)
18,100
6x10* (25°C)
Reference
Windholz, 1983
Verschueren, 1983
Windholz, 1983
PHRED, 1988;
Verschueren, 1983
TDB, 1985
1982
Lymaneial., 1982
PHRED, 1988
Verschueren, 1983
PHRE'D, 1988
* Value used for estimating aquatic effects
C-155
-------
REFERENCES
*
Bell, M.A., R.A. Ewing, G.A. Lutz, and E.G. Alley. 1978. Review of the Envi- ronmental
Effects of PoUutants: I. Mirex and Kepone. (NTIS Abstract). EPA Health Effects Research
Laboratory, Cincinnati, OH EPA/600/1-78-013. NTIS PB80-125958.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Pest
Management. Srded. Pergamon Press. Oxford, England.
HEAST. 1989. Health Effects Assessment Summary Tables. Office of Solid Waste and
Emergency Response. U.S. Environmental Protection Agency, Washington, D.C.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Klaassen, C.D., M.D. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology, The
Basic Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Kutz, F.W., S.C. Strassman, C.R. Stroup, J.C. Carra, C.C. Leininger, D.L. Watts and C.M.
Sparacino. 1985. The Human Body Burden of Mirex in the Southeastern United States. J.
Toxicol. and Environ. Health, 15:385-394.
Lyman, W.T., W.E. Reehl, D.E. Rosenblatt. 1982. Handbook of Chemical Estimation
Methods. McGraw-Hill Book Co.
National Academy of Sciences (NAS). 1978. Kepone/Mirex/Hexachlorocyclopentadiene:
An Environmental Assessment. National Academy of Sciences, National Research Council,
Washington, D.C. NTIS PB 280289.
Ouellette, R.P. and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
PHRED. 1988. Public Health Risk Evaluation Database. Office of Emergency and Remedial
Response, U.S. EPA, Washington, D.C.
State of Mississippi. 1982. Environmental Fate Studies in support of an emergency request
for use of mirex on fire ants.
Suta,B.E. 1977. Human Population Exposures to Mirex and Kepone. EPA-600/1-78-045.
Toxicology Data Bank (TDB) database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
C-156
-------
Ulland, B.M., N.P. Page, R.A. Squire, E.K. Weisburger, and R.L. Cyphor. 1977. A carcino-
genicity assay of mirex in Charles River CD rats. J. Natl. Cancer Inst. 58:133-140.
U.S. EPA. 1982. Office of Pesticides Programs Reviews of Environmental Fate Studies
submitted by the State of Mississippi in support of an emergency request for use of mirex on
fire ants.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: an encyclopedia of chemicals, drugs, and biolog-
icals. 10th ed. Merck & Co., Rahway, New Jersey.
World Health Organization. 1984. Mirex. Environmental Health Criteria 44:1-70.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-157
-------
MIREX
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
The U. S. Environmental Protection Agency banned the use of mirex in 1978, in part because
of its detrimental effects on fish and wildlife (Eisler 1985). Eisler's review provides a good
summary of mirex hazards to non-target species and concentrations found in wildlife.
High concentrations of mirex in eggs were blamed for the low reproductive success of Lake
Ontario herring gulls hi the early 1970s (Oilman elal 1978,1977). In 1975, the reproductive
success of herring hulls in Lake Ontario colonies was only one tenth that of colonies on the
other four Great Lakes (Oilman 1978,1977). The mean concentration of mirex in eggs from
one Lake Ontario colony was 7.4 ppm in 1974 (Weseloh eial. 1979).
Lake Ontario was the only Great Lake contaminated with mirex (Kaiser 1978, NAS1978), and
both Oilman el al (1977,1978) and Norstrom el al (1980) suggested that a high percentage
of the mirex in the eggs originated from Lake Ontario fish.
Differences in feeding habits have been related to differences in mirex concentrations in eggs
of three bird species in Maine: the common eider, herring gull and black-backed gull (Szaro
eial 1979). Eggs of the black-backed gull had levels of DOE and PCBs greater than those in
the eggs of the herring gull, which, in turn, were higher than in the eggs of the common eider.
Mirex was detected only in the eggs of the black-backed gull (up to 0.26 ppm) (Szaro el al.
1979). Szaro eial (1979) attributed the higher levels of contaminants in the blacked-back gull
to its predatory and scavenging feeding habits.
Based on a study of herring gulls and predation on alewives, Norstrom el al (1978) estimated
a bioaccumulation factor of 50 for mirex in gull eggs.
Mirex residues have been detected in the brains and tissues of various piscivorous birds
collected nationwide, such as bald eagles (Barbehenn and Reichel 1981) and herons
(Ohlendorf el al 1981). However, in both studies, mirex concentrations were recorded at
nonhazardous levels.
Mirex has also been detected in eggs of the American crocodile (up to 0.02 ppm) (Hall el al.
1979).
The State of New York proposed a fish flesh criterion for mirex at 0.33 ppm to protect
piscivorous wildlife. This criterion was based on studies of rats (Gaines andKimbrough 1969),
prairie voles and old field mice (Hyde 1972), and mallards (Newell el al 1987; Schafer el al.
1983).
The effects of mirex on piscivorous wildlife are summarized in the following table:
C-158
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Effects of Mirex Concentrations on Piscivorous Wildlife
Animal Concentration Effect Source
Piscivorous 0.33 ppm (diet) estimated Newell £ial.
Wildlife NOEL 1987
0.373 ppm (diet) cancer risk Newell fit al.
of 10'2 1987
REFERENCES
Barbehenn, KR. and in.L. Reichel. 1981. Organochlorine concentrations in bald eagles:
brain/body lipid relations and hazard evaluation. J. Toxicol. Environ. Health. 8:325-330.
Eisler, R. 1985. Mirex hazards to fish, wildlife and invertebrates: a synoptic review. U.S. Fish
Wildl. Serv. Biol. Rep. 85(1.1),42 pp.
Gaines, T. and R. Kimbrough. 1969. The oral toxicity of mirex in adult and suckling rats.
Toxicol. Appl. Pharmacol. 14:631-632. (as cited in Newell 1987).
Oilman, A.P., D. J. Hallett, G.A. Fox, LJ. Allan, W.J. Learning and D.B. Peakall. 1978.
Effects of injected organochlorines on naturally incubated herring gull eggs. J. Wildl. Manage.
42:484-493. (as cited in Eisler 1985).
Oilman, A.P., G.A. Fox, D.B. Peakall, S. M. Teeple, T.R. Carroll and G.T. Katmes. 1977.
Reproductive parameters and egg contaminant levels of Great Lakes herring gulls. J. Wildl.
Manage. 41:458-468. (as cited iaEisler 1985).
Kail, R. J., T. E. Kaiser, in. B. Robertson, Jr., and P.C. Patty. 1979. Organochlorine residues
in eggs of the endangered American crocodile (Crocodvlus acutus). Bull. Environ. Contain.
Toxicol. 23:87-90.
Hyde, K. 1972. Studies of the responses of selected wildlife species to mirex bait exposure.
Ph.D. thesis, Louisiana State University, Baton Rouge. 170pp.(as cited in Eisler 1985).
Kaiser, K.L.E. 1978. The rise and fall of mirex. Environ. Sci. Technol. 12:520-528. (as cited
in Eisler 1985).
NAS. 1978. Scientific and technical assessments of environmental pollutants.
Kepone/mirex/hexachlorocyclopentadiene: an environmental assessment.. Nat. Acad. Sci.,
Washington, DC. 73pp.(as cited in Eisler 1985).
C-159
-------
Newell, A.J., D.W. Johnson and L.K. Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Norstrom, R J., D J. Hallett, F.I. Onuska, and M.E. Comba. 1980. Mirex and its degradation
products in Great Lakes herring gulls. Environ. Sci. Technol. 14:860-866. (as cited in Eisler
1985).
Norstrom, RJ., DJ. Hallett, and R.A. Bonstegard. 1978. Coho salmon (Oncorhvnchus
kisutch) and herring gulls (Lams arsentatus) as indicators of organochlorine contamination in
Lake Ontario. J. Fish. Re. Board Canada. 35:1401-1400 (as cited in Eisler 1985).
Ohlendorf,H. M.,D. M. Swineford, and L. N. Locke. 1981. Organochlorine residues and
mortality of herons. Pest. Monit. J. 14(4): 125-135.
Schafer, E. Jr., W. Bowles, and J. Hulbert. 1983. The acute oral toxicity, repellency and hazard
potential of 998 chemicals to one or more species of wild and domestic birds. Arch. Environ.
Contain. Toxicol. 12:335-382. (as cited in Newell 1987).
Szaro, R. G, N. C. Coon, and E. Kolbe. 1979. Pesticide and PCB of common eider, herring
gull and great black-backed gull eggs. Bull. Environ. Contain. Toxicol. 22:394-399
Weseloh, D.V., P. Mineau,andDJ. Hallett. 1979. Organochlorine contaminants and trends
in reproduction in Great Lakes herring gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour.
Conf. 44:543-557.
C-160
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NITROFEN
CAS No.: 1836-75-5
CAS Preferred Nomenclature:
Benzene, 2,4-dichloro-2-(4-nitrophenoxy)-
Empirical Formula: Ci2H7Cl2NO2
Synonyms and Common Names:
- NIP
- Nitrophen
- F-W-925
- TOKE-25
- Nitrochlor
- 2,4-Dichlorophenyl-.para.-nitrophenyl ether
C12H7CI2N02
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Ad-
visories:
None established at present
EPA Tolerance Levels (50 FR 37850)
All tolerances revoked 9/18/85
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
All uses of nitrofen, a selective herbicide, were cancelled voluntarily by 1984 (40
FR2151).
C-161
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SOURCES OF NITROFEN
Total Nitrofen Produced;
Nitrofen is no longer produced or sold in the United States (Ouellette and King,
1977).
Uses of Nitrofen:
Prior to 1984, nitrofen was used as a selective herbicide to control weeds in various
crops, including vegetables, cereal, grains, sugar beets, rice and some ornamental
plants (Worthing, 1983).
Other Sources: None identified.
NITROFEN OBSERVED IN THE ENVIRONMENT
No data available.
FATE IN ENVIRONMENT
Partitioning;
Based on estimates of physical/chemical properties, nitrofen strongly sorbs to soil
(Kow ^339,00) and has a high potential for bioaccumulation (BCF estimated as
1.6x104). Nitrofen volatilizes at alow rate (H = 3.1x10-6 atm m3/mole).
Persistence;
Nitrofen can biodegrade under both aerobic and anaerobic conditions. In one
experiment, a 70% loss of nitrofen present in soil at a concentration of 10 ppm
(incubated at 30°C) occurred after 10 days which represents a decay rate of 0.12/day.
Nitrofen applied in a flooded paddy field (anaerobic conditions) had a half-life of
16 days (TDB, 1986). Under these conditions, the nitro group (NOz) is reduced to
NH2 (Grover, 1988).
Nitrofen solutions and aqueous suspensions can undergo rapid photolysis (TDB,
1986).
C-162
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HEALTH EFFECTS
Carcinogenicity:
The U.S. EPAhas not classified the potential carcinogenicity of nitrofen. However,
IARC (1983) considers that the available information is sufficient evidence to
identify nitrofen as carcinogenic in experimental animals.
Mice fed nitrofen displayed a significant increase in the incidence of liver carcino-
mas (IARC, 1983).
Nitrofen administered in high doses to rats also resulted in various types of tumors
at different anatomical sites (IARC, 1983).
Mutagenic Activity:
Nitrofen was found to be mutagenic in Salmonella typhimurium. Negative results
were obtained when nitrofen was tested in Bacillus subtilis and rat and mouse bone
cells (IARC, 1983).
Reproductive Effects;
In rats, nitrofen increased the incidence of stillbirths and reduced the survival rate
of newborns (IARC, 1983). Poor survival was due to heart, diaphragm and kidney
malformations, as well as lung immaturity (IARC, 1983; Klaassen el al., 1986).
Nitrofen produced similar birth defects in mouse fetuses (IARC, 1983).
Other Toxicological Effects;
Increased liver weight, neurological symptoms, and respiratory distress generally
occur after rats are exposed to nitrofen (IARC, 1983).
Toxicological Effects Indices:
Oral LD50: rats, 410-3580 mg/kg (IARC, 1983).
C-163
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L)
Vapor Pressure, P (mm Hg)
Henry's Law Constant, H @ 25°C
(atm m3/mole)
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,
Koc(ml/g):
Fish Bioconcentration Factor, BCF:
284.1
colorless
crystals
70-71
180-190 @
0.2S mm Hg
1.3 (liquid @
90°C)
N/A
0.7-1.2 (22$C)
8xlO'6(40$C)
S.lxlO"6 (calc.)
5.53 (calc.)
5.9xl04(calc.)
1.6xl04 (calc.)"
Windholz, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Hartley and Kidd, 1983
Worthing, 1983
Worthingt 1983
Lymanelal, 1982
Lymanelal., 1982
LymanelaL, 1982
Lymanelal., 1982
* Value used for estimating aquatic effects
C-164
-------
REFERENCES
Grover, R., ed. 1988. Environmental Chemistry of Herbicides. Vol. I, CRC Press, Inc. Boca
Raton, Florida.
Hartley and Kidd, eds. 1983. Herbicide Handbook. Weed Science Society of America. 5th
ed. Champaign, Illinois.
International Agency for Research on Cancer. 1983. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 30. IARC, Lyon, France.
Klaassen, C.D., M.O. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology: The
Basic Science of Poisons. 3rded. MacmiUen Publishing Co., New York.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Ouellette,R.P. and J.A. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Commit-
tee.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals. Drugs, and
Biologicals. 10th ed. Merck Co., Inc., Rahway, NJ.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-165
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C-166
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NONACHLOR
(cis- and trans- isomers)
CAS No.: cis-5103-73-1
trans - 39765-80-5
combined - 3734-49-4
CAS Preferred Nomenclature: (combined)
4,7-Methano- IH-indene,
l,2,3,4,5,6,7,8,8-nonachloro-2,3,3a,4,7,7a-
hexahydro-
Empirical Formula: CioHsCl9
Synonyms and Common Names: None
REGULATORY STATUS
cis-nonachlor
Cl
era
trans-nonachlor
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Ad-
visories:
None established at present
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
None for nonachlor. However, trans-nonachlor is a minor (7-10%) constituent of
technical grade chlordane, a chlorinated hydrocarbon pesticide (McEwen and
Stephenson, 1979; Takamiya, 1987). Chlordane has been banned for all uses except
for subsurface termites (see profile for Chlordane for additional information).
C-167
-------
SOURCES OF NONACHLOR
Total Nonachlor Produced;
Nonachlor is not intentionally produced for any commercial purposes.
Uses of Nonachlor:
As an impurity in technical chlordane, nonachlor is distributed in the environment
when chlordane is used to control soil-inhabiting insects (e.g., termites).
Other Sources:
An impurity in the technical grade of the pesticide heptachlor (Nash and Harris,
1973).
FATE IN ENVIRONMENT
Partitioning;
Based on its estimated physical/chemical properties, nonachlor is non-volatile (H
= 2xlO"7 atm m3/mole), strongly sorbed to soil (Kow = 457,000), and has a high
potential for bioaccumulation (BCF = 2.2X104).
Persistence:
Data on the persistence of cis- and trans-nonachlor are sparse, although their
structural similarity to cis- and trans-chlordane (one chlorine atom replaces one
hydrogen atom) suggests that they would behave similarly. Nonachlor present as
an impurity in heptachlor was found in soil test plots 16 years after the application
of 112 kg/ha and 224 kg/ha of technical heptachlor at concentrations of 2.3 and 5.2
ppm respectively. Plots of the same type soil treated with technical chlordane,
which contains roughly 7% nonachlor, also showed traces of nonachlor (< 0.03
ppm) after 16 years (Nash and Harris, 1973). Assuming nonachlor behaves like
chlordane, hydrolysis is not expected to be an important process although sensitized
photolysis may occur. Biodegradation is expected to be very slow, although it may
be important for ultimate degradation (Callahan el al, 1979).
The immediate metabolic product of trans-nonachlor is trans-chlordane (Tashiro
and Matsumura, 1978).
C-168
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HEALTH EFFECTS
i
Carcinogenicity;
No data found for nonachlor.
Chlordane is a probable human carcinogen because it causes liver rumors in mice
and rats (see Chlordane).
Mutagenic Activity;
No data found.
Reproductive Effects:
No data found.
Other Toxicological Effects;
Trans-nonachlor is reported to induce drug-metabolizing enzymes in the liver.
Whether this is potentially related to any adverse health effects is not known
(Campbell filaL, 1983).
Chlordane causes nerve, liver, kidney and lung damage (see profile for Chlordane).
Toxicological Effects Indices;
LCso: mosquito larvae = 3.5xlO~2ppm'(Tashiro and Matsumura, 1977).
No health effects indices are available for nonachlor. The indices for chlordane
are:
- Cancer Potency Factor (CPF): 1.3 (mg/kg/day)"1 (IRIS, 1989)
Concentration in
Cancer Risk Level Drinking Water (IRIS. 1988^
1 in 10,000 3fi g/L
1 in 100,000 0.3 n g/L
1 in 1,000,000 0.03 /*g/L
- Reference Dose (RfD): 6xlO"5 (mg/kg/day) (IRIS, 1989)
- TWA-TLV (time-weighted average, threshold limit value) for occupational
skin exposure: 0.5 mg/m3 (ACGIH, 1986; IRIS, 1988).
C-169
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Henry's Law Constant,
H@25°C(atm»m3/mol):
2xlO'7 (calc.)
Log (Octanol-Water Partition Coefficient),
log KOW: 5.66 (calc.)
Soil Adsorption Coefficient, Koc (ml/g): 7.3x104 (calc.)
Fish Bioconcentration Factor, BCF: 2.2xl04 (calc.)'
Reference
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
444.2
solid
148 (calc.)
471 (calc.)
N/A
N/A
0.06 (calc.)
2X10"8 (calc.)
Lyman ejtal., 1982
Lyman £laL, 1982
Lyman filal., 1982
Lyman £l al, 1982
Lyman filal., 1982
Lyman filal., 1982
Lyman filal., 1982
Lyman filal., 1982
* Value used for estimating aquatic effects
C-170
-------
REFERENCES
ACGIH (American Conference of Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Occupational Exposures to Chemicals. ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L, Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol I. Office of Water Planning
and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Campbell, M.A., J. Gyorkos, B. Lee, K. Homonko, and S. Safe. 1983. The Effects of 22
Organohalogen Pesticides as Inducers of the Hepatic Drug-Metabolizing Enzymes. (Ab-
stract). GenPharmacol. 14(4): 445-454.
IRIS, 1989. Integrated Risk Information System, U.S. Environmental Protection Agency.
Washington, D.C.
Lyman, W.L., W.F. Reehl and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons. New York.
Nash, R.G. and W.G. Harris. 1973. Chlorinated Hydrocarbon Insecticide Residues in Crops
and Soil. J. Environ. Quality. 2:269-273.
Taguchi, S. and T. Yakushiji. 1988. Influence of Termite Treatment in the Home on the
Chlordane Concentration in Human Milk. Arch. Environ. Contain. Toxicol., 11:65-71.
Takamiya, K 1987. Residual Levels of Plasma Oxychlordane and Trans- nonachlor in Pest
Control Operators and Some Characteristics of These Accumulations. Bull. Environ. Contam.
Toxicol., 22:750-755.
Tashiro, S. and F. Matsumura. 1977. Metabolic Routes of cis- and trans-Chlordane in Rats.
J. Agric. Food Chem., 2£(4):872-880.
Tashiro, S. and F. Matsumura. 1978. Metabolism of Trans-nonachlor and Related Chlordane
Components in Rat and Man. (Abstract). Arch. Environ. Contam. Toxicol. 1:113-127.
C-171
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C-172
-------
OCTACHLOROSTYRENE
CAS No.: 29082-74-4
CAS Preferred Nomenclature:
Benzene, pentachloro
(trichloroethenyl)-
Empirical Formula:
Molecular Weight: 379.7
REGULATORY STATUS
No use restrictions or regulatory standards.
SOURCES OF OCTACHLOROSTYRENE
Formation of Octachlorostyrene;
There is no intentional commercial production of octachlorostyrene. Oc-
tachlorostyrene is associated with wastes from the electrolytic production of chlo-
rine prior to 1970 when graphite anodes and coal tar pitch binder were used. It is
hypothesized that the chlorination of this binder material was a major source of
octachlorostyrene as well as other chlorinated styrenes (Kaminsky and Hites, 1984).
After 1970, metal anodes were used.
It is reported that octachlorostyrene is also formed when graphite anodes are used
during the electrolytic production of magnesium from magnesium chloride (Tar-
kpeaelal., 1985).
FATE IN ENVIRONMENT
Partitioning:
Based on estimated physical/chemical properties using structure-activity relation-
ships, (Lyman, elal 1982) octachlorostyrene is highly volatile (estimated H = 0.15
atm m3/mol) and strongly sorbs to organic matter (KoWs 87,100,000). It has a high
potential for bioaccumulation (BCF = 4.2xl06).
C-173
-------
Persistence;
Octachlorostyrene is persistent in sediments (Kaminsky and Kites, 1984). Pro-
cesses which can transform octachlorostyrene include hydrolysis, biodegradation,
and photolysis, but at low rates. The estimated half-lives cited were > 1,000 days
for hydrolysis and > 100 days for biodegradation (Wise and Wrich, 1984). Infor-
mation was found showing that octachlorostyrene can undergo photolysis in
water/solvent mixtures exposed to wavelengths between 230 and 290 mm. The rate
was slower at wavelengths greater than 290 mm. (Hustert &i al, 1984).
HEALTH EFFECTS
Carcinogenicity;
The potential carcinogenicity of octachlorostyrene has not been evaluated.
Mutagenic Activity;
Results were negative in bacterial mutagenicity tests (Tarkpea & al, 1985;
Kaminskyu and Kites, 1984).
Effects on Humans and Animals;
No reports of adverse health effects in humans or animals.
C-174
-------
PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Water Solubility, (mg/L):
Henry's Law Constant, H@25°C
(atm»m3/mole):
Log (Octanol - Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
Value
379.7
Solid
2xlO'4(calc)
O.lS(calc)
7.94 (calc)
4.4xl06(calc)
33,000(calc)'
Reference
Lyman, elal., 1982
Lyman, elal., 1982
Lyman, el al., 1982
Lyman, elal .,1982
Lyman, filaU 1982
* Value used for estimating aquatic effects
C-175
-------
REFERENCES
Hustert, K, D. Kotzias, and F. Korte. 1984. Beitrag Zum Verhalten von Octochlorostyrol bei
UV-Bestrahlung. Chemospher. 12:845-848.
Kaminsky, R. and R.A. Hites. 1984. Octachlorostyrene in Lake Ontario; Sources and Fates.
Environ. ScL Technol. 1&275-279.
Lyman, W.L., Reehl, W.F., Rosenblatt, D.H., 1982. Handbook of Chemical Property Estima-
tion Methods. McGraw-Hill Book Co., New York.
Tarkpea, M., I. Hagen, G.E. Carlberg, P. Kolsaker and H. Storflor. 1985. Mutagenicity, Acute
Toxicity, and Bioaccumulation Potential for Six Chlorinated Sytrenes. Bull. Environ. Contam.
Toxicol. 25:525-530.
Wise, P.L and M. Wrick. 1984. Memo, Candidates for the Emerging Chemical Identification
and Management Project: Polychlorinated Systems. September 4,1984.
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OXYCHLORDANE
CAS No.: 27304-13-8
CAS Preferred Nomenclature:
2,5-methano-2 H-indeno
(l,2b)oxirene, 2,3,4,5,6,6a,7,7-octachloro-
la,lb,5,5a,6,6 hexahydro-
Empirical Formula: CioHeClsO
Synonyms and Common Names:
- Octachlor epoxide
- Oxychlordan
- 1,2-dichlorochlordene epoxide
REGULATORY STATUS
No use restrictions or regulatory standards.
SOURCES OF OXYCHLORDANE
Uses of Oxychlordane;
Oxychlordane is not used in any commercial products and is not found in technical-
grade chlordane.
Other Sources
Oxychlordane is a major metabolic breakdown product of the pesticide chlordane
(Taguchi and Yakushuji, 1988). It is one of many compounds formed as a result of
a series of oxidative enzyme reactions with chlordane (Barnett and Dorough, 1974;
Tashiro and Matsumura, 1977).
FATE IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, Oxychlordane is estimated to have low
volatility (H = 3x10" atm m /mole), a moderate tendency to sorb to soil (Kow
=400), and a low potential for bioaccumulation (BCF = 19).
C-177
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Persistence:
Based on its structural similarity to the pesticides chlordane, dieldrin and aldrin,
oxychlordane is not expected to be susceptible to hydrolysis, but to be affected by
indirect photolysis. Biodegradation is also expected to be slow (Callahan el at,
1979). It is likely to be highly persistent (Kirk-Othmer, 1978).
Four months after application of high purity chlordane to alfalfa, oxychlordane
comprised 16% of the residues measured in the crop (WHO, 1984).
Oxychlordane is considered to be more persistent than its parent compound,
chlordane (WHO, 1984).
OXYCHLORDANE OBSERVED IN THE ENVIRONMENT
Sample Type Concentration Reference
Market Basket Foods l-5^g/kg WHO, 1984
(found in less than 1% of samples
taken in 1963-1969)
Human Breast Milk 75.4-116 pgfL WHO, 1984
(1976 study of 1463 women)
Human Fat 0.03-0.4 mg/kg WHO, 1984
Fat of dogs, rats, pigs, cattle (Concentrations WHO, 1984
not given)
Tokyo Bay gobyfish 3/*g/kg Worthing, 1983
Bats (Maryland and Virginia) 0.11-to6.33/*g WHO, 1984
HEALTH EFFECTS
Carcinogenicity;
It has been suggested that chlordane metabolites (e.g., oxychlordane) may be
carcinogenic in humans because chlordane causes liver cancer in mice (WHO,
1984). The EPA has not evaluated the carcinogenic potential of oxychlordane.
Other Toxicological Effects:
Oxychlordane is considered to be more toxic than its parent compound, chlordane
(see Chlordane profile) (WHO, 1984).
C-178
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No other information was found on the human health effects, mutagenicity or
reproductive effects of oxychlordane.
Toxicological Effects Indices;
. Acute oral LDso: rat, 19.1 mg/kg (Mastri el aL, 1969, in WHO, 1984).
Temporary reference dose proposed by the FAO/WHO for the sum of the alpha-
and gamma- forms of chlordane plus oxychlordane: 0.0 to 0.001 mg/kg (WHO,
1984).
A 1972 Joint Meeting on Pesticide Residues established food residue tolerance
levels of 0.02 to 0.5 mg/kg for a sum of alpha-, gamma-, and oxychlordane (WHO,
1984).
C-179
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PHYSICAL CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant H @
25°C(atm m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
Value
354.9
solid
134 (calc.)
317 (calc.)
N/A
N/A
200 (calc.)
IxlO^calc.)
3xlO'7(calc.)
2.60 (calc.)
300 (calc.)
19 (calc.)«
Reference
Lymanfilal., 1982
LymanfilaL, 1982
Lymanelal., 1982
LymanfilaL, 1982
LymanfilaL, 1982
LymanejtaL, 1982
Lyuman el al, 1982
Lymanelal., 1982
Value used for estimating aquatic effects
C-180
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REFERENCES
Barnett, J.R. and H.W. Dorough. 1974. Metabolism of Chlordane in Rats. J. Agric. Food
Chem., 22:612-619.
Kirk-Othmer Encyclnpedia of Chemical Technology. 1978. 3rd ed. John Wiley and Sons,
Inc., New York.
Lyman, W.L., W.F. Reehe, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods - Environment. McGraw-Hill, New York, NY.
Mastri, C., M.L. Keplinger and O.E. Fancher. Acute Oral Toxicity Study on Four Chlordenes
in Albino Rats. 1969. Illinois, Industrial Bio-Test Laboratories (Report for Velsicol Chemical
Corporation).
Taguchi, S. and T. Yakushiji. 1988. Influence of Termite Treatment in the Home on the
Chlordane Concentration in Human Milk. Arch. Environ. Contain. Toxicol., 11:65-71.
Tashiro, S. and F. Matsumura. 1977. Metabolic Routes of cis- and trans- chlordane in Rats.
J. Agric. Food Chem., 2i:872.-880.
World Health Organization (WHO). 1984. Chlordane. Environmental Health Criteria 34.
World Health Organization, Geneva.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. British Crop
Protection Council, Craydon, England.
C-181
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C-182
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PENTACHLOROANISOLE
CAS No.: 1825-21-4
CAS Preferred Nomenclature:
Benzene, Pentachloromethoxy-
Empirical Formula: CvHsClsO
Synonyms and Common Names:
- PCA
- 2,3,4,5,6 Pentachloroanisole
- Pentachlorophenyl methyl ether
- Methyl pentachlorophenate
REGULATORY STATUS
Standards and Criteria:
No standards or criteria for pentachloroanisole were found. See pentachlorophe-
nol profile for standards applicable to parent compound.
Use Restrictions and Bans;
Uses of pentachlorophenol were restricted in 1984 primarily to wood preservation,
excluding logs for homes and interiors of buildings. (See pentachlorophenol pro-
file).
SOURCES OF PENTACHLOROANISOLE
Production:
Not produced as a separate chemical.
Other Sources;
Pentachloroanisole is a metabolic product of pentachlorophenol. It can be formed
by microorganisms in the soil environment (Kaufman, 1978; Cserjesi and Johnson,
1972) and in aquatic sediments (Pierce and Victor, 1978).
C-183
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FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, pentachloroanisole is volatile (H =
8xlO"3 atm m/mol), strongly sorbs to organic matter (Kow = 457,000), and has
a high potential for bioaccumulation (BCF = 10,000). It is also retained longer by
fish than pentachlorophenol (ti/2 = 6 to 24 days for pentachloroanisole versus a
ti/z = 0.25 to 1 day for pentachlorophenol, Lech, ei al., 1978).
Persistence:
Environmental fate data for pentachloroanisole are scarce. Rate constants for
hydrolysis, photolysis, or acid-base dissociation were not found. Based on its
chemical structure, it would not be expected to hydrolyze (Lyman el a]., 1982) but
may undergo photolysis (Sadtler, 1979). Conversion back to pentachlorophenol in
soils can occur under both aerobic and anaerobic conditions, but is faster under
anaerobic conditions (42% in 24 days vs. 6% under aerobic conditions, Kaufman,
1978).
PENTACHLOROANISOLE OBSERVED IN THE ENVIRONMENT
In lake contaminated with fuel oil containing pentachlorophenol in Mississippi
(Pierce and Victor, 1978)
Water (mg/L) 0.03-1.94
Sediment (mg/g) 14-80
Fish Tissue (ng/g wet weight) 30-250
HEALTH EFFECTS
Carcinogenicity;
No data found. The EPA has not evaluated the carcinogenic potential for pen-
tachloroanisole. The data for pentachlorophenol carcinogenicity are currently
under review (IRIS, 1989).
Mutagenic Activity: No data found.
Reproductive Effects;
Female rats fed pentachloroanisole at a dose of 41 mg/kg/day gained less weight
during pregnancy. Male offspring had lower birth weights and were smaller in
length. Female offspring exhibited no such effects. (Welsh, ei al., 1987).
C-184
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Toxicological Effects Indices;
. Oral LDso: rats 500 mg/kg (Sax, 1984).
C-185
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKai
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C(atm m3/mol):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(mVg):
Fish Bioconcentration Factor, BCF:
Value
280.4
solid
104 (calc.)
258(calc.)
N/A
N/A
0.2 (calc.)
5xlO'3(calc.)
8xlO'3(calc.)
5.66 (calc.)
4.2xl04(calc.)
1.0xl04(calc.)«
Reference
Windholz, 1983
Lymanelal., 1982
Lymanelal., 1982
Lymanelal-, 1982
Lymanelal., 1982
Lymanelal., 1982
Callahan-elal.,
1982
LymanfilaL, 1982
Lymanelal., 1982
* Value used for estimating aquatic effects
C-186
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REFERENCES
i
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol I. Office of Water Planning
and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Cserjesi, AJ. and E.L. Johnson. 1972. Methylation of Pentachlorophenol by Trichoderma
virgatum. Can. Journal of Microbiology 18:45-49.
IRIS. 1989. Integrated Risk Information System (IRIS), U.S. EPA, Washington, D.C
Kaufman, D.D. 1978. Degradation of Pentachlorophenol in Soil, and by Soil Microorganisms,
in Pentachlorophenol Chemistry, Pharmacology, and Knvi'rnnmental Toxicology. (K.R. Rao,
ed.) Plenum Press, New York, p.27-39.
Lech, J.J., AH. Glickman and C.N. Statham. 1978. Studies on the Uptake, Disposition and
Metabolism of Pentachlorophenol and Pentachloroanisole in Rainbow Trout (Salmo
gairdneri) p. 107-113.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Pierce, R.H., Jr., and D.M. Victor. 1978. Fate of Pentachlorophenol in an Aquatic Ecosystem
in Pentachlorophenol Chemistry, Pharmacologyr and Environmental Toxicology. (K.R. Rao,
ed.) Plenum Press, New York, p.27-39.
Sadtler Research Labs. 1979. Sadtlers Handbook of Ultraviolet Spectra. Sadder Research
Labs, Division of Bio-Rad Labs, Inc., Philadelphia.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials, 6th ed. Van Nostrand Reinhold
Co., New York.
Welsh, JJ., T.F. Collins, T.N. Black, S.L. Graham, and M.W. O'Donnell, Jr. 1987. Teratogenic
Potential of Purified Pentachlorophenol and Pentachloroanisole in Subchronically Exposed
Sprague-DawleyRats. Food Chem. Toxicol. 25£2}:163-172.
Windholz, M., ed. 1983. The Merck Index; An Encyclopedia of Chemicals, Drugsf and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
C-187
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C-188
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o
a ^Y Cl
Cl
;6HCI5
PENTACHLOROBENZENE
CAS No.: 608-93-5
CAS Preferred Nomenclature:
Benzene, pentachloro-
Empirical Formula: CeHCls
Synonyms and Common Names:
- QCB
- 1,2,3,4,5 Pentachlorobenzene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for EPA Drinking Water Health Adviso-
human consumption of fish) (IRIS, ries:
1989): None established at present
85/
-------
Major Uses: No data found.
Other Sources;
Pentachlorobenzene is an impurity (approximately 0.17%) in the soil fungicide
pentachloronitrobenzene (Verschueren, 1983;KlaasseneiaL, 1986).
FATE IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, pentachlorobenezene is highly volatile
(H = 3.8x10 atm m3/mol), strongly sorbed to soil (Kow = 155,000), and has a
high potential for bioaccumulation. Experimentally determined values for BCF
ranged from LSxlG5 to 2X105 (Oliver and Niimi, 1983).
The steady-state bioconcentration factor found for bluegills was 3,400 (CIS
database).
Persistence:
Little information specific to pentachlorobenzene was found in the literature.
Much of its behavior is inferred from that of hexa- and tetrachlorobenzenes.
Neither hydrolysis nor chemical oxidation of pentachlorobenzene is expected to be
environmentally significant based on the behavior of these related compounds.
Although chlorobenzenes of 3 or fewer chlorines can be biodegraded, hexa- and
pentachlorobenzene are considered resistant to biodegradation (Bailey, 1983).
Pentachlorobenzene has been found to undergo photolytic degradation in acetoni-
trile/water mixtures at wavelengths >285 nm (Choudhry and Hutzinger, 1984).
After 24 hours, 41.2% of an initial pentachlorobenzene concentration of approxi-
mately ImM underwent non-sensitized degradation while 53.8% disappeared in
four hours when acetone at 0.55 M was present as a sensitizer. Roughly 3.4% of
the pentachlorobenzene that underwent sensitized photolysis was converted to
PCBs; lesser amounts were convened by direct photolysis.
PENTACHLOROBENZENE OBSERVED IN THE ENVIRONMENT
No data available.
C-190
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HEALTH EFFECTS
Carcinogenicity:
Not yet evaluated by U.S. EPA for carcinogenicity (IRIS, 1989).
U.S. EPA (1980) reports one study that alludes to carcinogenicity of pen-
tachlorobenzene in mice but not in rats and dogs. No details are available.
Mutagenic Activity: No data available.
Reproductive Effects:
Weanling rat pups of mothers receiving 18 mg/kg/day developed tremors (IRIS,
1989).
Pregnant rats given SO, 100 or 200 mg/kg orally during days 6-15 of gestation
produced sternal defects suggestive of retarded development (U.S. EPA, 1980).
Other Toxicologicai Effects;
Liver and kidney toxicity observed in rats fed pentachlorobenzene at doses as low
as 8.3 mg/kg/day (IRIS, 1989).
Toxicologicai Effects Indices;
Reference Dose (RfD): SxlO"4 mg/kg/day (IRIS, 1989).
C-191
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PHYSICAL/CHEMICAL PROPERTIES
Value
Reference
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H@ 25°C
(atm m3/mol):
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient,
Koc(ml/g):
Fish Bioconcentration
Factor, BCF:
250.3
solid
86
277
1.8342 (16.5°C)
N/A
0.24(22°C)
2.8xlO'3(25°C)
(calc.)
3.8xlO'3(calc.)
5.19
5.8xl04(calc.)
1.3xl05-2.0xl05
(exptl.)
2125*
Windholz, 1983
Weast, 1986
Weast, 1986
Weast, 1986
Verschueren, 1983
Lymaneial., 1982
Lymaneial., 1982
U.S. EPA, 1986
Lymaneial., 1982
Oliver & Niimi,
1983
U.S.EPA, 1986
* Value used for estimating aquatic effects
C-192
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REFERENCES
Bailey, R.E. 1983. Comment on Chlorobenzenes in Sediments, Water, and Selected Fish from
Lakes Superior, Huron, Erie, and Ontario. Environ. Sci. Technol. 12:504.
Choudhry, G.G. and O. Hutzinger, 1984. Acetone-sensitized and Non-sensitized Photolysis
of Tetra- Penta- and Hexachlorobenzenes in Acetonitrile-water Mixtures: Photoisomeriza-
tion and Formation of Several Products including Polychlorinated Biphenyls. Environ. Sci.
Technol. 18:235-241.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, B.C.
Klaassen, CD., M.D.Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology. The
Basic Science of Poisons. 3rd ed. Macmillan Publishing Co., New York.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Oliver, B.G. and AJ. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by
Rainbow Trout: Correlations with Partition Coefficients and Environmental Residues. En-
viron. Sci. Technol. IZ:287-291.
PHRED. 1988. Public Health Risk Evaluation Database. Office of Emergency and Remedial
Response, U.S. EPA, Washington, D.C.
U.S. EPA 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. Office of Water
Regulations and Standards, Criteria and Standards Division. EPA-440/5-80-028.
U.S. EPA. 1986. Superfund Public Health Evaluation Manual. Office of Emergency and
Remedial Response, Washington, D.C. EPA-540/1-86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Physics. 67th ed. CRC Press, Boca
Raton, Florida.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
Worthing, C.R., ed. 1983. The Pesticide Manual: A world compendium. 7th ed. British Crop
Protection Council, Croydon, England.
C-193
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C-194
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PENTACHLORONTTROBENZENE
CAS No.: 82-68-8
CAS Preferred Nomenclature:
Benzene, pentachloronitro-
Empirical Formula: CeClsNOi
Synonyms and Common Names:
- Brassicol - Terraclo
- Quintozene - PCNB
- TFungiclor - Folosan
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
No specific criteria or LELs have
been developed for PCNB (IRIS,
1989)
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Drinking Water Health Adviso-
ries:
None established at present
EPA Tolerance Levels (40 CFR
180.291):
0.1 ppm for cottonseed
0.2 ppm for collards, kale, and
mustard greens
Food and Drug Administration Ac-
tion Levels for Fish:
None established at present
Use Restrictions and Bans;
Use of pentachloronitrobenzene itself has not been restricted, however, the allow-
able level of the contaminant hexachlorobenzene has been set at 0.1 percent (U.S.
EPA, 1986b).
C-195
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SOURCES OF PENTACHLORONITROBENZENE
Total Pentachloronitrobenzene Produced;
In 1971, approximately 3 million Ibs. were produced by Olin Co. (Ouellette and
King, 1977).
Uses of Pentachloronitrobenzene:
Pentachloronitrobenzene has been used primarily as a soil fungicide and as a seed
dressing agent (e.g., peanuts). Other uses have been to control stem and root rot
for flowers and vegetables (e.g., cabbage), and molds on flowers, cotton and turf
(Farm Chemicals Handbook, 1985).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning
Based on its physical/chemical properties, Pentachloronitrobenzene is somewhat
volatile (H = IxlO^atm m/mol), is strongly sorbed to soil organic matter (Kow
= 282,000), and has a low potential for bioaccumulation (BCF values derived
experimentally range from 6.3 to 79) (Verschueren, 1983).
Persistence:
Pentachloronitrobenzene can undergo hydrolysis (Kn = 2.8 x 10' /hr) (Ellington,
fit al, 1986) and aqueous photoreduction (A.D. Little, 1974). The estimated
half-life is 2.8 years at a pH of 7, so hydrolysis is unlikely to be environmentally
significant in most cases. Biotransformation in soils can also occur, particularly
under anaerobic conditions (Verschueren, 1983).
PENTACHLORONITROBENZENE OBSERVED IN THE ENVIRONMENT
No data found.
C-196
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HEALTH EFFECTS
Carcinogenicity;
Dietary exposure of mice to pentachloronitrobenzene (1206 ppm for 18 months)
induced liver tumors (IARC, 1973). Similar studies in rats (2500 ppm for 25
months) showed no increased incidence of tumors (IARC, 1973). Pen-
tachloronitrobenzene is classified as category 3 by IARC and Class C by EPA,
indicating that there is limited evidence of carcinogenicity in animals, and that
additional studies are needed to characterize the effect of this chemical (IARC,
1973; PHRED, 1988).
Mutagenic Activity: No data found.
Reproductive Effects;
Cleft palates were observed in the offspring of mice exposed orally to 500 mg/kg of
pentachloronitrobenzene (Courtney, 1983; Klaassen, elal., 1986).
No effects were observed in rats given 1653 ppm pentachloronitrobenzene (Jordan
and Borzelleca, 1973).
Other Toxicological Effects;
Dogs fed pentachloronitrobenzene for 2 years at levels between 180 ppm and 1080
ppm developed various levels of liver damage, abnormal bile production and
secondary kidney degeneration (RTECS, 1984; IRIS, 1989).
Toxicological Effects Indices;
Reference Dose (RfD): 3 x 10"3 mg/kg/day (IRIS, 1989).
Oral LDso: rats, 1200-1650 mg/kg (Klassen el at, 1986).
C-197
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PHYSICAL/CHEMICAL PROPERTIES
Value
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C(atm» m3/mol):
Hydrolysis, KN 1/hr:
Log (Octanol-Water Partition
Coefficient), log KOW:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Bioconcentration
Factor, BCF:
U3xl(T(250C)
1.0 xl
-------
REFERENCES
Courtney, D. 1973. The Effect of Pentachloronitrobenzene on Fetal Kidneys. Toxicol. Appl.
Pharmacol. 25:455.
Ellington, J.J., F.E. Stantil, Jr., and W.D. Payne. 1986. Measurement of Hydrolysis Rate
Constants for Evaluation of Hazardous Waste Land Disposal. Volume I. U.S. Environmental
Protection Agency: Athens, Georgia. EPA/600/3-86/043.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Hartley, D. and H. Kidd, eds. 1983. The Agrochemicals Handbook. The Royal Society of
Chemistry, Nottingham, England.
International Agency for Research on Cancer. 1973. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 5. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Jager, K.W. 1970. Aldrin. Dieldrin. Endrin and Telndrin: An Epidemiological and Toxico-
logical Study of Long-Term Occupational Exposure. Elsevier Publ. Co., Amsterdam, The
Netherlands.
Jordon, R.J., and J.F. Borzelleca. 1973. Teratogenic Studies with Pentachloronitrobenzene
in Rats. Toxicol. Appl. Pharmacol. 21:454.
Klaassen, C.D., M.O. Amdur and J. Doull, eds. 1986. Casarett and DouU's Toxicology. He.
Basic Science of Poisons. Macmillan Publishing Co., New York.
PHRED (Public Health Risk Evaluation Database) (Draft 204). February 18, 1988. Phase
Linear Systems, Inc. for U.S. EPA, Office of Emergency and Remedial Response.
Ouellette,R.P.andJ.A.King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Registry of Toxic Effects of Chemical Substances (RTECS^ Database. 1984. Available
through the National Library of Medicine's MEDLARS system, National Institute of Occu-
pational Safety and Health (NIOSH).
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. Office of Water
Regulations and Standards, Washington, D.C. Report #PB81-117-392.
U.S.EPA. 1985. Suspended, Cancelled, and Restricted Pesticides. U.S. EPA
Office of Pesticides and Toxic Substances, Washington, D.C.
C-199
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U.S. EPA. 1986. Computer Retrieval from Office of Pesticides for Registered Sites and
Number of Products Registered.
U.S. EPA. 1986b. Superfund Public Health Evaluation Manual, U.S. EPA Office of Solid
Waste and Emergency Response, Washington, D.C. EPA-540/1-86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicalsr Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
C-200
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PENTACHLOROPHENOL
CAS No.: 87-86-5
CAS Preferred Nomenclature: Phenol, pentachloro-
Empirical Formula: CeHClsO
Synonyms and Common Names:
PCP
Permatox
Penchlorol
Fungilen
Preventol P
Permacide
Chem-Tol
Santobrite
Penwar
Termi-Trol
- Penta
- Chlorophen
- Permite
- Dowicide?
- Liroprem
- Priltox
- Durotox
- Lauxtol
- SantophenR
- Weedone
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (IRIS,
1989):
for human consumption of fish and
water = 1.01 mg/L to control undesir-
able taste and odor = 30/ig/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organ-
isms)(IRIS, 1989):
Freshwater Saltwater
Chronic, /tg/L 22 13
Acute,/ig/L 13 7.9
EPA Drinking Water Standards
(IRIS, 1989):
Proposed Maximum Contaminant
EPA Drinking Water Health Adviso-
ries (52 FR 175; IRIS, 1989):
cMd.(10kg):
1-day exposure = 1.0 mg/L
10-day and long-term exposure =
0.3 mg/L
adulL(70kg):
long-term exposure = 1.05 mg/L
lifetime exposure = 0.22 mg/L
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
C-201
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EPA Drinking Water Standards
(IRIS, 1989):
Proposed Maximum Contaminant
Level = 0.22 mg/L
Proposed Maximum Contaminant
Level Goal = 0.22 mg/L
Use Restrictions and Bans:
In 1984, most uses as an herbicide, antimicrobial agent (e.g., in cooling towers),
defoliant, disinfectant, and in marine anti-fouling paint were discontinued (49 FR
48367).
Continued uses allowed: wood preservative if not on logs for homes or interior of
buildings, in oil field flood waters and in pulp and paper mill solutions (49 FR
48367).
SOURCES OF PENTACHLOROPHENOL
Total Pentachlorophenol Produced;
Pentachlorophenol was developed as a wood preservative in 1936.
4 million pounds were produced in 1971 (Ouellette and King, 1977). By 1974
production had increased to 54 million pounds of which 44 million pounds were
used in wood preservation. In 1984, uses were curtailed. By 1986 only 1 company,
Vulcan Materials, was producing pentachlorophenol (SRI, 1986).
VI
In aquatic systems a major metabolic product of pentachlorophenol is pen-
tachloroanisole (C/HsClsO).
Uses of Pentachlorophenol;
Major use (90%) is as a wood preservative to control termites and fungal rot for
utility poles, fence posts, railroad ties and exterior lumber (Klaassen et al., 1986).
Other uses (9%) include production of sodium pentachlorophenate (Na-PCP).
This was used hi marine anti-fouling paint; in cooling tower water to control
microorganism growth; and to prevent fungal rot in carpets, canvas and other
textiles (Cirelli, 1978).
PCP has also been used as a microbial agent in oil field flooding waters and drilling
muds and in the paper and pulp industry (Cirelli, 1978).
PCP and Na-PCP together were formerly the second most used pesticide in the U.S.
(Cirelli, 1978), for example, as a pre-harvest defoliant for cotton and pre-emergence
herbicide (Agrochemicals Handbook, 1978).
C-202
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Other Sources;
PCP is a breakdown product of the biotransfonnation of hexachlorobenzene and
pentachlorobenzene (Koss and Koransky, 1978).
FATE IN ENVIRONMENT
Partitioning:
Based on its physical/chemical properties, pentachlorophenol can volatilize (H =
2.75x10 atm m /mol), although this is not a dominant fate process. For
example, Kv in a shallow stream is calculated to be 0.024/day, compared to the
photolysis rate of 1. I/day (Mills el aL, 1985). PCP sorbs strongly to soil organic
matter (Kow = 132,000) and can bioaccumulate (BCF & 1,000).
Persistence:
PCP exists predominantly (over 90%) as an anion in waters having a pH of 5.7 or
higher (pKa = 4.7). Hydrolysis and volatilization are thus not generally environ-
mentally significant. Photolysis is rapid (Kpo = 1.224/hr), with half-lives of 0.2 and
4.8 hours at depths of 10 cm and 300 cm, respectively, in a clear body of water at
the latitude of Cleveland on a midsummer day (Callahan £l al., 1979).
PCP can be degraded by a variety of microorganisms; one PCP-degrading strain
(Flavohacterium) was found to degrade PCP in natural waters at initial concentra-
tions of 10 ppb to 100 ppb, usually within 48 hours (Alexander and Aleem, 1961).
First-order biotransfonnation rate constants in water range from 0.05 to 0.5/day
(Mills filal., 1985). However, pentachlorophenol in soils degrades more slowly. In
four laboratory experiments, kb ranged from 4.2 x 10"4 to 5.2 x 10" /day (Tabak el
aL, 1981; Baker and Mayfield, 1980).
HEALTH EFFECTS
Carcinogenicity;
There was no evidence of the carcinogenicity of pure PCP in mice and rats fed doses
of up to 30 mg/kg/day for two years (U.S. EPA, 1984). However, technical-grade
PCP may be carcinogenic because of its contamination with the highly carcinogenic
dioxins and furans (IRIS, 1989).
The EPA has assigned pentachlorophenol to Group D; not classified as to human
carcinogenicity. The research data are currently under review (IRIS, 1989).
C-203
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Mutagenic Activity;
Tests have yielded conflicting results. There were no observed mutagenic effects
in Drnsnphila melanogaster (fruit flies) (IARC, 1979) or Salmonella bacteria
(Ames test). Some mutations were observed in mice and Saccaromyces cerevisiae
(yeast) (Scow el aL, 1980).
Reproductive Effects;
PCP has caused fetal posioning in rats (Scow el a]., 1980). The basic response was
reproductive failure with those surviving having subcutaneous fluid retention and
swelling, kidney damage, and skeletal defects of the skull, ribs, and vertebrae. The
incidence increased at higher doses (IARC, 1979).
Other Toricological Effects;
Acute (short-term, high dose) and chronic (long-term, low dose) effects both can
include (U.S. EPA, 1984):
skin irritation - fever
profuse sweating - tachycardia (rapid heart beat)
kidney damage ' vision damage
labored breathing - weakness
heart failure - convulsions.
Chronic human exposure to PCP has been associated with aplastic anemia (Roberts,
1981). Exposure to PCP aggravates pre-existing kidney and liver diseases (Clayton
and Clayton, 1982).
Fatalities due to PCP exposure have occurred (Klaassen el al, 1986).
lexicological Effects Indices;
. Reference Dose (RfD): 0.03 mg/kg/day (IRIS, 1989).
TWA-TLV (Time-weighted average, threshold limit value) for occupational skin
exposure: 0.5 mg/m3 (ACGIH, 1986).
For a 70 kg (ISO Ibs) person, a lethal oral dose is 50-500 rag/kg (IRIS, 1989).
C-204
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @ 25°C
(atm m /mol):
Hydrolysis: Ka, L/mole/hr;
Kn, 1/hr; Kb, L/mole/hr:
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, Koc (ml/g):
Fish Bioconcentration Factor, BCF:
Value
266.3
solid
190-191
309-310
1.978 (22/4°C)
4.74
14 (20°C)
1.1 x W4
(20°C)
2.75 xlO"6
4.6x10^,
2.4 xlO"4,
0.138
5.12
5.3x10*
770(calc.)
900-1,000
Reference
Windholz, 1983
Windholz, 1983
Windholz, 1983
Windholz, 1983
Callahaneial., 1979
Callahaneial., 1979
Callahaneial., 1979
MabeysiaL, 1982
Park £1 aL, 1980
Leo, 1982
Mabeyslal., 1982
LymanelaL, 1982
Callahanfilal, 1979
C-205
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REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Environment. ACGIH, Cincinnati, OH.
Alexander, M., and M.H. Aleem. 1961. Effect of Chemical Structure on Microbial Decom-
position of Aromatic Herbicides. J. Agric. Food Chem. 9(1): 44-47.
Agrochemicals Handbook. 1982. Meister Publishing Co., Willoughby, OH.
Baker, M.D., and C.I. Mayfield. 1980. Microbial and Nonbiological Decomposition of
Chlorophenols and Phenols in Soil, Water, Air, Soil Pollution. 13:411.
Buhler, D.R., ME. Rasmusson and H.S. Nakave, 1973. Occurrence of Hexachlorophene and
Pentachlorophenql in Sewage and Water. Environ. Sci. Technol. 2:929-934.
Callahan, M.A., M.W. Slimak, N.W. Gabel, IP. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol H. Office of Water
Planning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029b.
Cirelli, D.P. 1978. Patterns of Pentachlorophenol Usage in the United States of America -
An Overview In: Pentachlorophenol: Chemistryr Pharamcology,. and Environmental Toxicol-
Ogy.. (K.R. Rao, ed.) Plenum Press, New York.
International Agency for Research on Cancer. 1979. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 20. IARC, Lyon, France.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd. ed. John Wiley and Sons,
Inc., New York.
Klaassen, C.D., M.O. Amdur and J. Doulh, ed. 1986. Casarett and Doull's Toxicology. The
Science of Poisons. Macmillan Publishing Co., New York.
Koss, G. and W. Kornasky. 1978. Pentachlorophenol in Different Species of Vertebrates after
Administration of Hexachlorobenzene and Pentachlorobenzene. In: Pentachlorophenol:
Chemistry, Pharamacologyr and Environmental Toxicology. (K.R. Rao, ed.) Plenum Press,
New York.
Leo,AJ. 1983. Log P Parameter Database. Medchem Project, Pomona College, Claremont,
CA.
C-206
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Lyman, WJ., W.F. Reehe, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods-Environment. McGraw-Hill: New York. 977pp.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L Johnson, T. Mill, T.W. Chou, J. Gates, I.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
Mills, W.B., D.B. Porcella, M J. Ungs, S.A. Gherini, K.V. Summers, L. Mok, G.L. Rupp, G.L.
Bowie, and D.A. Haith. 1985. Water Quality Assessment: A Screening Procedure for Toxic
and Conventional Pollutants in Surface and Ground Water. U.S. Environmental Protection
Agency, Athens, GA. EPA 600/6-85/002a.
Ouellette,R.P.andJ.A.King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Park, RA., C.I. Connolly, J.R. Albanese, L.S. Clesceri, S.W. Heitzman, H.H. Herbrandson,
B.H. Indyke, J.R. Loehe, S. Ross, D.D. Sharma, and W.W. Sinister. 1980. Modeling Transport
and Behavior of Pesticides and Other Toxic Organic Materials in Aquatic Environments
(PEST). Report No. 7. Center for Ecological Modeling, Renselaer Polytechnic Institute, Troy,
NY. 163 pp.
Roberts, HJ. 1981. Aplastic Anemia due to Pentachlorophenol. The New England Journal
of Medicine. 305(27); 1650-1651.
Scow, K, M. Goyer, J. Perwak, E. Payne, R. Thomas, D. Wallace, P. Walker, M. Wood, and
L Delpire. 1980. An Exposure and Risk Assessment for Pentachlorophenol. U.S. EPA,
Office of Water Regulations and Standards, Office of Water and Waste Management, Wash-
ington, D.C.
Stanford Research Institute (SRI). 1986.- Directory of Chemical Producers. Stanford Re-
search Institute, Menlo Park, California.
Tabak, H.H., S.A. Quave, C.I. Mashni, and E.F. Earth. 1981. Biodegradation Studies with
Organic Priority Pollutant Compounds. J. Water Pollution Control Fed. 51:1503-1518.
U.S. EPA. 1976. Summary of Reported Episodes involving Pentachlorophenol. Pesticide
Episode Review System. U.S. EPA, Office of Pesticide Programs, Pesticide Episode Response
Branch, Operations Division, Washington, D.C.
U.S. EPA. 1980. Ambient Water Quality Criteria for Pentachlorophenol. Office of Water
Regulations and Standards. PB81-117764.
U.S. EPA. 1980. An Exposure and Risk Assessment for Pentachlorophenol. Office of Water
Regulations and Standards. EPA-440/4-81-021.
U.S. EPA. 1984. Health Effects Assessment for Pentachlorophenol. EPA/540/1-86-043.
C-207
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U.S. EPA. 1986. Superfund Public Health Evaluation Manual. U.S. EPA Office of Solid
Waste and Emergency Response, Washington, D.C EPA 540/1- 86/060.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index! An Encyclopedia of Chemicals, Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
Wong, A.S. and D.E. Cosby. 1978. Photolysis of Pentachlorophenol in Water, pp. 19-25. In:
Pentachlorophennl! Chemistry, Pharmacology, and Environmental Toxicology. (K.R. Rao,
ed.) Plenum Press, New York.
Worthing, C.R., ed. 1979. The Pesticide Manual; A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
Zitko, V., O. Hutzinger and P.M.K. Chou. 1974. Determination of Pentachlorphenol and
Chlorobiphenylols in Biological Samples. Bull. Environ. Contain. Toxicol. 12(fi):649-653.
C-208
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PERTHANE
CAS No.: 72-56-0
CAS Preferred Nomenclature:
Benzene, 1, l-(2,2-dichloroethylidene)
bis (4-ethyl)-
Empirical Formula:
Synonyms and Common Names:
- Ethylan
- 1, l-Dichloro-2,2-bis(p-ethylphenyl)
- ethane
C2H5
C18H20CI2
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restriction and Bans:
EPA Drinking Water Health Adviso-
ries:
None established at present
EPA Tolerance Levels for raw agricul-
tural commodities (40 CFR 180.139):
in meat and milk = 0 ppm
in other commodities = IS ppm
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
In 1980, all registered uses were cancelled (45 FR 41694).
SOURCES OF PERTHANE
Total Perthane Produced:
Perthane was produced by Rohm and Haas, Inc. from 1950 until it was discontinued
in 1980 (Farm Chemicals Handbook).
C-209
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UsesofPerthane;
Prior to 1980, perthane was used in a minor capacity as an insecticide on a variety
of crops and in certain household settings. Its structural similarity to DDT made it
particularly effective in controlling pests on pears, and leafhoppers and larvae on
various vegetables (i.e., peppers, tomatoes, broccoli, brussel sprouts, cauliflower,
kohlrabi, lettuce, spinach and potatoes) (Ouellette and King, 1977; McEwen and
Stephenson, 1979; Hayes, 1982; U.S. EPA, 1986).
Perthane was registered as an insecticide for use on the foliage of grapes, apples
and cherries.
Inhomes and dog kennels, perthane was used in controlling animal pests (U.S. EPA,
1986).
Perthane has also been used in mothproofing blankets, upholstery and other textile
products (Hayes, 1982; U.S. EPA, 1986).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
Based on its estimated physical/chemical properties, perthane is moderately vola-
tile (H = 6.1x10 atm m3/mol, very strongly sorbed to soil (Kow = 13,800,000),
and has a high potential for bioaccumulation (BCF = 6.6x10 ).
Persistence;
Although perthane is structurally similar to DDT, it is not as persistent and can
undergo both biodegradation and photolysis (Ware, 1975; McEwen and Stephen-
son, 1979; TDB, 1985).
HEALTH EFFECTS
Carcinogenicity;
In one study with mice, females, but not males, developed liver tumors as a result
of two years of exposure to perthane in their diet (3000 ppm) (Reuber, 1980).
The U.S. EPA has not yet classified perthane as to its potential carcinogenicity.
Mutagenic Activity: No data found.
Reproductive Effects: No data found.
C-210
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Other Toxicological Effects;
There is no information available on any adverse human health effects caused by
acute (short-term, high dose) exposure to perthane. In a few experimental cases,
perthane was used as a therapeutic agent in the treatment of prostate and breast
cancers. Several of the exposed persons developed diarrhea, vomiting and nausea.
There was no evidence of liver, kidney or nerve damage. However, there were no
demonstrable benefits from the treatments (Hayes, 1982).
Rats fed perthane for two years at doses between 500 and 5,000 ppm demonstrated
no adverse health effects. There were some minor liver changes (Hayes, 1982).
Perthane was lethal to dogs that received doses of 5,000 ppm for 22 weeks. Lower
levels either had no effects (100 ppm) or caused some adrenal degeneration (1,000
ppm) (Hayes, 1982).
Toxicological Effects Indices;
Oral LDso: rats, 6600 to 8170 mg/kg; mice, 9340 rag/kg (McEwen and Stephenson,
1979; Hayes, 1982; RTECS, 1984).
C-211
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Value
307.3
Crystalline
solid; technical
grade, waxy solid
56-57
N/A
N/A
N/A
0.1
1.5xlO'5 (calc.)
Reference
Hayes, 1982
Hayes, 1982
Windholz, 1983
Hollifield, 1979
LymanfilaL, 1982
Henry's Law Constant
H@25°C(atm» m3/mol):
6.1xlO'5 (calc.)
LymanfilaL, 1982
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient,Koc (ml/g):
Fish Bioconcentration Factor,BCF:
7.14 (calc.)
I.lxl06(calc.)
6.6xlOs(calc.)*
Lymanfilal., 1982
LymanfiiaL, 1982
LymanelaL, 1982
* Value used for estimating aquatic effects
C-212
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REFERENCE
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Hayes, W J., Jr. 1982. Pesticides Studied in Man. Waverly Press, Inc., Baltimore, MD.
Hollifield, H.C. 1979. Rapid Nephelometric Estimate of Water Solubility of Highly Insoluble
Organic Chemicals of Environmental Interest. Bull. Environ. Contain. Toxicol. 22:57-586.
Lyman, W.L., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley and Sons, Inc., New York.
Ouellette, R.P. and JA. King. 1977. Chemical Week Pesticides Register. McGraw-Hill Book
Co., New York.
Reuber, M.D. 1980. Histopathology of Carcinomas of the Liver in Mice Fed Perthane.
Tumori. M:277-283.
Registry of Toxic Effects nf Chemical Substances (RTECS) Database. 1984. Available
through the National Library of Medicine's MEDLARS system, National Institute of Occu-
pational Safety and Health (NIOSH).
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1986. Computer retrieval from Office of Pesticides for registered sites and number
of products registered.
Ware, G.W. 1975. Pesticides: An Auto-tutorial Approach. W.H. Freeman and Co., San
Francisco.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals. Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
C-213
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C-214
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POLYCHLORINATED BIPHENYLS
CAS No.: 1336-36-3 (undifferentiated)
Specific CAS numbers have also been assigned to PCBs with various levels of chlorination
and for individual Aroclors. Some of the other CAS numbers include:
Total Monochlorobiphenyl 27323-18-8
Total Dichlorobiphenyl 25512-42-9
Total Trichlorobiphenyl 25323-68-6
Total Tetrachlorobiphenyl 26914-33-0
Total Pentachlorobiphenyl 25429-29-2
Total Hexachlorobiphenyl 26601-64-4
Total Octachlorobiphenyl 31472-83-0
Total Nonachlorobiphenyl 53742-07-7
Total Decachlorobiphenyl 2051-24-3
CAS Preferred Nomenclature:
l,l'-Biphenyl, chloro-derivatives
Empirical Formula: Ci2Hio-xClx, where x is 1 to 10
C12H4CI6' Hexachlorobiphenyl
Major Component of Aroclor 1260
Synonyms and Common Names:
- Chlorinated biphenyls
- Chlorinated diphenyls
-PCBs
- Aroclors*
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish) (IRIS,
1989):
0.045 ng/L
EPA Drinking Water Health Adviso-
ries for Aroclor 1016 (U.S. EPA,
1987):
child (10 Kg):
long-term exposure = Ig/L
adull(70Kg):
long-term exposure = 4 g/L
Aroclors are mixtures of PCBs which have been designated using a 4-digit numbering system. The first 2 digits
indicate the parent molecule (12 represents biphenyl). The next two digits indicate the percent chlorine. Up to
8 Cl atoms can be present.
C-215
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EPA Ambient Water Quality Criteria Food and Drug Administration Toler-
(for protection of aquatic organ- ance Level for Fish and Shellfish (21
isms)(U.S. EPA, 1976): CFR 109.30):
Freshwater Saltwater 2 ppm
Acute, ^g/L 2.0 10.0
Chronic, pgfL 0.014 0.03
EPA Drinking Water Standards (40
CFR Part 141):
Proposed Maximum Contaminant
Level = 0.0005 mg/L
Proposed Maximum Contaminant
Level Goal = 0 mg/L
Use Restrictions and Bans:
In May 1979, EPA banned the use of PCBs except in totally-enclosed systems (40
CFR 76). In August, 1982 these regulations were revised to restrict uses of PCBs
in electrical equipment. PCB transformers and electromagnets posing a risk to food
were banned after October 1,1985. In limited access areas, PCB transformers and
large capacitors could be used until the equipment is worn out. Small PCB
capacitors can continue to be used.
SOURCES OF PCBs
Total PCB Production;
PCB production in the U.S. began in 1929 and stopped in 1977 (Ghirelli eial., 1983).
Production peaked in-1970 at 85 million pounds (Matthews and Dedrick, 1984).
Annual production between 1971 and 1977 averaged about 40 million pounds
(ATSDR, 1987).
Uses of PCBs:
PCBs are a family of chemicals. Commerical products can be mixtures of up to 209
different compounds. After 1974, PCBs were used primarily as a dielectric fluid
in capacitors and transformers.
Prior to 1974, PCBs were used in other products as well:
- plasticizer in plastic and rubber products
- lubricant in hydraulic and vacuum fluids
- ink carrier and solvent in manufacturing process for carbonless paper
- sealer for gaskets and furnaces (Versar 1976 and 1980; Ghirelli et al, 1983;
ATSDR, 1987).
C-216
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Other Sources;
Trace quantities of PCBs can be produced during manufacture of chlorinated
hydrocarbon compounds in the presence of catalysts or at high temperatures (e.g.
1,1,1-trichloroethene, tetrachloroethene, carbon tetrachloride) (Versar, 1983).
FATE IN ENVIRONMENT
Partitioning:
PCBs differ in their behavior depending on the number of chlorine atoms present.
A higher number of chlorines (e.g., Aroclor 1260) makes the compound less soluble
in water, and more refractory (i.e., doesn't degrade). PCBs, in general, are relatively
insoluble, sorb strongly to organic matter (Kow = 750,000), and can volatilize
(half-lives are 10 to 12 hours) (Callahan £i aL, 1979). In lakes volatilization is
considered to be an important loss process (Swackhamer and Armstrong, 1986).
PCBs have a high potential for bioaccumulation (BCF values range from 26,000 to
660,000 (Leifer el aL 1983).
Persistence:
PCBs can undergo photolysis, although specific rate constants in water were not
found (Leifler el aL, 1983; Callahan, el aL, 1979). PCBs do not hydrolyze at a
significant rate (Mabey elaL, 1982). Biotransformation of PCBs with three or less
chlorines (e.g., Aroclor 1221 and 1232) can occur, while other PCBs are essentially
refractory (Brown el aL, 1987, Leifler el aL, 1983). Highly chlorinated PCBs can
degrade by dechlorination reactions under anaerobic conditions to less chlorinated
PCBs. These can then biodegrade (Brown el aL, 1987).
HEALTH EFFECTS
Carcinogenicity:
PCBs administered orally have been shown to cause liver tumors in rats and mice
(Norback and Weltman, 1985; U.S. EPA 1985 and 1987). They are classified as
probable human carcinogens: IARC class 2b; U.S. EPA class B2 (IARC, 1982; IRIS,
1988).
Because PCBs can be contaminated with other compounds (e.g.,chlorinated
dibenzofurans, dioxin), it is difficult to assess the cause of observed cancers in
human exposure incidents.
C-217
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Mutagenic Activity:
PCBs have not been shown to be mutagenic in either in-vitro or in-vivo experimen-
tal tests (ATSDR, 1987).
Negative results were obtained from the Ames bacterial test, the rat dominant lethal
tests and fruit fly chromosomal tests (U.S. EPA, 1984).
Reproductive Effects;
PCBs are fetotoxic in rats, monkeys, minks and rabbits (U.S. EPA, 1984).
PCBs have not been found to be teratogenic in rats, mice or monkeys (ATSDR,
1987).
Other lexicological Effects;
The major toxic effect in animals is liver damage (IARC, 1978).
Other effects in animals include stomach, thyroid, and kidney damage, porphyria
and immunosuppressive effects (ATSDR, 1987).
Accidental and occupational exposures of humans (to relatively high levels of
PCBs) have resulted in chloracne and liver damage (Matthews and Dedrick, 1984;
U.S. EPA, 1984; ATSDR, 1987).
Toxicological Effects Indices;
Cancer potency factor (CPF), total PCBs: 7.7 (mg/kg/day)"1 (ATSDR, 1987)
'. Reference Dose (RfD), Aroclor 1016:0.0001 mg/kg/day (ATSDR," 1987)
TWA-TLV (time-weighted average, threshold limit value), for occupational expo-
sures:
Aroclor 1254 = 0.5 mg/m3 (ACGIH, 1986)
Aroclor 1242 = 1 mg/m3 (ACGIH, 1986)
Oral LDso: mink, 750 mg/kg (Aroclor 1221); rats, 1010 mg/kg (Aroclor 1254).
C-218
-------
PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Density, (g/cm3 at 25°C)
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor pressure, P (mm Hg):
Hydrolysis:
Henry's Law Constant KH @
25°C (atm m3/mol):
Value
200.7-375.7
liquid
N/A
275-420
1.15-1.58 at 25°C
N/A
Reference
HutzingerelaL, 1974
MackayelaL, 1983
Callahanfilal., 1979
0.0027 (Aroclor 1260)
0.59 (Aroclor 1221
Monsanto, 1974
7.7xlOn° (Arochlor 1254) Callahanfilal., 1979
MabeyeiaL, 1982
v3
6.7x10° (Aroclor 1221)
not environmentally
significant
5.28X10"4 (Aroclor 1242) ATSDR, 1987
4.6xlO'3 (Aroclor 1260)
Log (Octanol-Water Partition Coefficient),
log Kow: 4.7 (Aroclor 1221)
6.8 (Aroclor 1260)
Soil Adsorption Coefficient, Koc (ml/g): S.SxlO5
Fish Bioconcentration Factor, BCF:
26,000-660,000
31,200'
Hansch and Leo, 1985
Mabeyfilal, 1982
LeiferalaL, 1983
U.S. EPA, 1980
* Value used for estimating aquatic effects
* Aroclors are mixtures of PCBs which have been designated using a 4-digit numbering system. The first 2 digits
indicate the parent molecule (12 represents biphenyl). The next two digits indicate the percent chlorine. Up to
8 Cl atoms can be present.
C-219
-------
REFERENCES
ACGIH. 1986. Threshold Limit Values for Occupational Exposures to Chemicals. ACGIH,
Cincinnati, OH.
ATSDR. 1987. Draft lexicological Profile for Selected PCBs. Agency for Toxic Substances
and Disease Registry, U.S. Public Health Service.
Brown, J.F., Jr., B.L. Bedard, MJ. Brennan, J.C Carnahan, H. Feng, R.E. Wagner. 1987.
Polychlorinated Biphenyl Dechlorination in Aquatic Sediments. Science 236:709-712.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, CF. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri, W.R. Mabey, B.R. Holt, and C. Gould. 1979.
Water-Related Environmental Fate of 129 Priority Pollutants, Vol. I. Office of Water Plan-
ning and Standards, U.S. Environmental Protection Agency. EPA-440/4-79-029a.
Ghirelli, R.P. F.H. Palmer. T.L. Spielman, M. Jung, R.L. Severeid, G.W. Bowes, D.B. Cohen.
1983. Polychlorinated Biphenyls. California State Water Resources Control Board. Special
Projects Report No. 83-lsp.
Hansch, C. and AJ. Leo. 1985. Log P Data Base. Pomona College, Claremont, CA.
Hutzinger, S., S. Safe, and V. Zitko. 1974. The Chemistry of PCBs. Chemical Rubber
Publishing Co., Cleveland, Ohio.
IRIS. 1989. Integrated Risk Information System. U.S. EPA. Washington, D.C.
International Agency for Research on Cancer. 1978. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 18. IARC, Lyon, France.
International Agency for Research on Cancer. 1982. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans, Vol. 29. IARC, Lyon, France.
Leifer, A., R.H. Brink, G.C. Thorn, K.G. Partymiller. 1983. Environmental Transport and
Transformation of Polychlorinated Biphenyls. EPA Report No. EPA-560/5-83-025. Wash-
ington, D.C.
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, I.W.
Partridge, H. Jaber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440- 4-81-014.
Mackay, D., W.Y. Shiu, J. Billington and G.L. Huang. 1983. Physical Chemical Properties of
Polychlorinated Biphenyls in Physical Behavior of PCBs in the Great Lakes. (D. Mackay, S.
Paterson, S. J. Eisenreich and M.S. Simmons, eds.). Ann Arbor Science, Ann Arbor, Michigan.
C-220
-------
Matthews, H.B. and R.L. Dedrick. 1984. Pharmacokinetics of FCBs. Ann. Rev. Pharmacol.
Toxicol. 24:85-103.
Monsanto. 1974. PCBs-Aroclors Technical Bulletin 0/PL 360A. St. Louis, MO.
Norback, D.H. and R.H. Weltman. 1985. Polychlorinated Biphenyl Induction of Hepatocellu-
lar Carcinoma in the Sprague-Hawley Rat. Envir. Health Perspective. 60:97-105.
Swackhamer, D.L and D.E. Armstrong. 1986. Estimation of the Atmospheric and Non-
atmospheric Contributions and Losses of Polychlorinated Biphenyls for Lake Michigan on the
Basis of Sediment Records of Remote Lakes. Environ. Science and Technol. 20(QV879-883
U.S. EPA. 1976. Quality Criteria for Water. Office of Water and Hazardous Materials,
Washington, D.C.
U.S.EPA. 1980. Ambient Water Quality Criteria Document. EPA 440/5-80 Series.
U.S. EPA. 1984. Health Effects Assessment for Polychlorinated Biphenyls. Office of Emer-
gency and Remedial Response, Washington, D.C. EPA-540/1-86-004.
U.S. EPA. 1985. Draft Drinking Water Criteria Document for Polychlorinated Biphenyls
(PCBs). Washington, D.C. NTIS #PB86-118312/AS.
U.S. EPA. 1987. Final Drinking Water Criteria Documents for Polychlorinated Biphenyls.
ECACO-CIN-414.
Versar. 1976. PCBs in the United States: Industrial Use and Environmental Distribution.
Prepared for EPA under contract 68-01-3259. Task 1.
Versar. 1980. Production and Use of PCB 1248 and 1254. Prepared for EPA- MDSD.
Contract 68-01-3852. Task 22. Subtask 1.
Versar. 1983. Exposure Assessment for Incidentally Produced Polychlorinated Biphenyls
(PCBs). Prepared for EPA-OTS. Contract 68-01-6251. Task 2.
Wilson, D.L. 1988. Project Summary Report on Decontamination of PCB-Gearing Sedi-
ments. Hazardous Waste Engineering Research Laboratory, Cincinnati, OH. EPA/600/52-
87/093.
C-221
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PCBs
OBSERVATIONS AND EFFECTS ON PISCIVOROUS WILDLIFE
During the last two decades, polychlorinated biphenyls (PCBs) were commonly detected in
the tissues and eggs of fish-eating birds. Szaro el aL (1979) found PCBs in all eggs that were
collected from successful colonies of the herring gull and great black-backed gull in Maine.
PCBs were also detected in 50 percent of black-crowned night heron eggs from the intermoun-
tain western states (Kenny el al. 1984). PCB residues were detected in 83 percent of the
ospreys found dead or moribund in the eastern states (iniemeyer eial. 1987), and in 90 percent
of various heron species collected nationwide (66 percent found dead or moribund)
(Ohlendorf elal. 1981).
PCB residues were apparently the cause of death of many ring-billed gulls in southern Ontario
hi 1969 and 1973. Of the specimens sampled that died of no apparent disease, 61 percent had
residues of PCBs in the brain exceeding the lethal level of 310 ppm, and 30 percent had PCBs
concentrations greater than 200 ppm in the brain (Stickel fit al. 1984). DDE and dieldrin were
also present in most specimens. DDE residues were at a lethal level (250 ppm) in one
specimen and dieldrin residues were at a lethal level (5 ppm) in more than 14 percent of the
dead birds.
High reproductive failure of Lake Ontario herring gulls in the early 1970s prompted an
investigation of the organochlorine concentration hi the gull eggs. PCB concentrations of up
to 180 ppm were detected. This level is one order of magnitude greater than the concentration
found in eggs from successful herring colonies on Lakes Erie, Huron and Superior. Repro-
ductive success of the Lake Ontario herring gull colonies unproved in latter years, parallelling
a decline in PCB and other organochlorines concentrations in gull eggs (Weseloh eial. 1979).
However, Oilman el al (1978,1977) suggest that high levels of mirex, not PCBs, in the eggs
were to blame for the reproductive failure.
In 1981 and 1982 duck hunters from New York and New Jersey were cautioned about eating
wild waterfowl. The waterfowl from the Hudson and Niagra River areas contained greater
than 5 ppm PCBs (fresh weight) which was in excess of FDA tolerances for poultry (Eisler
1986).
Fish-eating mammals are also affected by PCBs. Mink are very sensitive to PCBs, and are the
most sensitive of the wildlife species tested (Eisler 1986). A concentration as low as 0.64 ppm
wet weight in food can cause reproductive failure in mink (Plantonow and Karstud 1973).
Ringer (1983) determinedd that a concentration of 0.67 ppm hi the mink diet causes repro-
ductive failure. In the field, residues of PCBs indicative reproductive failure have been
observed in mink from western Maryland and northern Oregon (Henny si aL 1981,0'Shea el
aL 1981).
C-222
-------
River otters form the Columbia River in Oregon were found with high levels of PCBs. Henny
filaL (1981) suggest these elevated PCB levels may be contributing to the declining harvest of
the Columbia River otter.
Based on Plantonow and Karstud's 1973 mink study, the International Joint Commission (a
United States-Canada Treaty Organization), set an objective for PCB in fish at 0.1 ppm to
protect piscivorous wildlife (Newell el aL 1987). The State of New York propoosed a slightly
less conservative fish flesh criterion of 0.13 ppm from the sam data to protect piscivorous
wildlife (Newell filal 1987).
The effects of PCBs on piscivorous wildlife are summarized in the following table:
Effects of PCB Concentrations on Piscivorous Wildlife
Animal
Birds
Mink
Mink
Piscivorous
Wildlife
Concentration
310 ppm (brain)
0.64 mg/kg
(diet)
0.67 mg/kg
(diet)
or
0.225 ppm/day
(diet)
0.1 mg/kg/day
(diet)
0.13 ppm (diet)
0.11 ppm (diet)
Effect
death
reproduction
impaired
reproduction
impaired
NOEL
estimated
NOEL
cancer risk
oflO'2
Source
Stickel, 1984
Plantonow and
Karstud, 1973
Ringer, 1983
Ringer, 1983
Newell £ial,
1987
Newell fiial,
1987
C-223
-------
REFERENCES
Eisler, R. 1986. Polychlorinated biphenyl hazards to fish, wildlife and invertebrates: A
synoptic review. U.S. Fish Wildl. Serv. Biol. Rep. 85(1.7), 72 pp.
Oilman, A.P., D. J. Kallett, G.A. Fox, LJ. Allan, in J. Learning and D.B. Peakall. 1978. Effects
of injected organochlorines on naturally incubated herring gull eggs. J. Wildl. Manage.
42:484-493. (As cited in Eisler, 1985)
Oilman, A.P., G.A. Fox, D.B Peakall., S. M. Teeple, T.R. Carroll and G.T.Hatmes. 1977.
Reproductive parameters and egg contaminant levels of Great Lakes herring gulls. J. Wildl.
Manage. 41:458-468. (As cited in Eisler, 1985)
Kenny, CJ., LJ. Blus, AJ. Krynitsky, and CM. Bunck. 1984. Current impact of DDE on
black-crowned night-herons in the intennountain west. J. inildl. Manage. 48(1): 1-13
Kenny, C. J., L. J. Blus, S. V. Gregory, and C. J. Stafford. 1981. PCBs and organochlorine
pesticides in wild mink and river otters from Oregon, pp. 1763-1780 in J. A. Chapman and 0;
Pursley (eds.). Worldwide furbearer conference proceedings. Vol HI. Frostburh, MD. (As
cited in Eisler, 1986)
Newell, AJ., D.in. Johnson and L.K. Allen. 1987. Niagara River biota contamination project:
fish flesh criteria for piscivorous wildlife. Tech. Rep. 87-3. NY Dept. Environ. Conserv., Div.
Fish Wildl., Bureau Environ. Protection.
Ohlendorf, H.M., D.M. Swineford, and L.N. Locke. 1981. Organochlorine residues and
mortality or herons. Pest. Monit. J. 14(4):125-135
O'Shea, TJ., T.E. Kaiser, G.R. Askins and J.A. Chapman. 1981. Polychlorinated biphenyls
in a wild mink population, pp. 1746-1752 in J.A. Chapman and D. Pursley (eds.). Worldwide
furbearer conference proceedings. Vol ffl. Frostburgh, Md. (As cited in Eisler, 1986)
Palntonow, N. and C. Karstud. 1973. Dietary effects of polychlorinated biphenyls on mink.
Can. J. Comp. Med. 37:391-400. (as cited in Newell, 1987)
Ringer, R. 1983. Toxicology of PCBs in minks and ferrets. In F. D'ltri and M. Kamrin (eds.),
PCBs: Human and Environmental Hazards. Butterworth Pub., Woburn, MA. pp. 227-140.
(As cited in Newell, 1987)
Stickel, W.H., L.F. Stickel, R.A. Dyrland and D.L. Hughes, 1984. Aroclor 1254 residues in
birds: lethal levels and loss rates, Arch. Environ Contain, Toxicol. 13:7-13
Szaro, R.C., N.C. Coon, and E. Kolbe. 1979. Pesticides and PCB of common eider, herring
gull and great black-backed gull eggs. Bull. Environm. Contain. Toxicol, 22:394-399
C-224
-------
Weseloh, D.V., P. Mineau, D J. Hallet, 1979. Organochlorine contaminants and trends in
reproduction in great lakes herring gulls, 1974-1978. Trans. N. Am. Wildl. Nat. Resour. Conf.
44:543-557
Weimeyer, S.N., S.K. Schmeling and A. Anderson. 1987. Environmental pollutant and
necropsy data for ospreys from the eastern United States, 1975-1982, J. Wildl. Diseases,
23(2):279-291
C-225
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C-226
-------
1,2,3,4 AND 1,2,3,5 TETRACHLOROBENZENE
1,2,3,4-TETRACHLOROBENZENE:
CAS No.: 634-66-2
CAS Preferred Nomenclature:
Benzene, 1,2,3,4-tetrachloro-
Empirical Formula:
Synonyms and Common Names:
- 1,2,3,4 TCB
1,2,3,5-TETRACHLOROBENZENE;
CAS No.: 634-90-2
CAS Preferred Nomenclature:
Benzene, 1,2,3,5-tetrachloro-
Empirical Formula: GsH2CL4
Synonyms and Common Names:
- 1,2,3,5 TCB
ci
Cl
Cl
Cl
1.2.3,4-tetrachlorobenzene
Cl
CI
Cl
Cl
1,2.3.5-tetrachlOfObenzene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Health Adviso-
ries:
None established at present
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
C-227
-------
SOURCES OF 1,2,3,4 AND 1,2,3,5 TETRACHLOROBENZENE
Total 1,2,3,4 and 1,2,3,5 TCB Produced;
No current producers for either tetrachlorobenzene were identified (SRI, 1986).
Uses of 1,2,3,4 and 1,2,3,5 TCB;
1,2,3,4 TCB has been used as a component of dielectric fluids (Verschueren, 1983).
No information was found on the uses of 1,2,3,5 TCB.
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
Based on their properties, both 1,2,3,4 and 1,2,3,5 TCB are moderately volatile
(estimated H = 1,300 to 1,400 atm m3/mole), strongly sorb to soil (Kow = 43,000
to 83,000), and have a high potential for bioaccumulation. (BCF values from
experimental data ranged from 1,800 to 72,000.)
Persistence;
Little information is available on the photolysis and hydrolysis of either 1,2,3,4 or
1,2,3,5 TCB, but based on the similarity of their structure to 1,2,4,5 TCB, neither
process is expected to be environmentally significant.
Because of the high degree of chlorination of 1,2,3,4 and 1,2,3,5 TCB, biodegrada-
tion is not expected to occur readily (Perwak fit aL, 1983). However, in a solution
of 200 mg/L of 1,2,3,4 TCB, Pseudomonas bacteria were able to produce 33% ring
degradation after 120 hours at 30°C (Verschueren, 1983). It is likely that 1,2,3,5
TCB would behave similarly.
HEALTH EFFECTS
Carcinogenicity:
No data found. The U.S. EPA has not classified the potential carcinogenicity of
either 1,2,3,4 or 1,2,3,5 TCB.
C-228
-------
Mutagenic Activity;
No adequate data available (U.S. EPA, 1980).
Reproductive Effects;
In rats 1,2,3,4 TCB reduced embryonic growth at the level which also caused
maternal poisoning effects (1000 mg/kg) (TDB, 1985).
No data were found for 1,2,3,5 TCB.
Other Toxicological Effects;
^^^^^_^^v^_^_««^^^_^B«a^_^^_^v«9^B^»^^B«m ^
Liver damage was produced in rats fed high doses of 1,2,3,4 TCB (1,000 to 6,600
mg/kg/day) (TDB, 1985).
Rats fed 1,2,3,5 TCB (75 mg/kg) for 2 months developed enlarged adrenal glands.
No specific health effects were noted as a result of this condition (U.S. EPA, 1980).
Toxicological Effects Indices: None found.
C-229
-------
PHYSICAL/CHEMICAL PROPERTIES
1.2.3.4 TETRACHLOROBENZENE: Value
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mole):
Log (Octanol-Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, KOC (ml/g):
Fish Bioconcentration Factor, BCF:
215.9
solid needles
47.5
254
1.70
5.92
3.5 (22°C)
0.027 (25°C)
UxlO"3 (calc.)
4.64
1.2xl04 (calc.)
2100 (calc.)
1,125* to 12,000
(exptl.)
Verschueren, 1983
Verschueren, 1983
Weast, 1986
Weast, 1986
Kirk-Othmer, 1982
N/A
Banerjee, 1984
Verschueren, 1983
Kirk-Othmer, 1982
LymanelaU 1982
Leo, 1983
Lymaneial., 1982
Lymaneial., 1982;
U.S. EPA, 1980
* Value used for estimating aquatic values
C-230
-------
1,2,3,5 TETRACHLOROBENZENE:
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant, H @
25°C (atm m3/mole):
Log (Octanol- Water Partition
Coefficient), log Kow:
Soil Adsorption Coefficient, KOC (ml/g):
Fish Bioconcentration Factor, BCF:
Value
215.9
solid
54.5
246
N/A
5.10
2.4(22°C)
1 @ 58.2°C
1.4xlO'3 (calc.)
4.92
2.0xl04(calc.)
4,000 (calc.)
1,800 to 72,000
(exptl.) .
Reference
Verschueren, 1983
Weast, 1986
Weast, 1986
N/A
Banerjee, 1984
Verschueren, 1983
Weast, 1986
LymanelaL, 1982
Leo, 1983
LymanelaL, 1982
LymaneiaL, 1982
U.S. EPA, 1980;
Verschueren, 1983
C-231
-------
REFERENCES
»
Banerjee, S. 1984. Solubility of Organic Mixtures in Water. Environ. Sci. Technol. 1&587-
591.
Hawley, G.G. 1981. The Condensed Chemical Dictionary. 10th ed. Van Nostrand Reinhold,
Inc., New York.
International Agency for Research on Cancer. 1977. IARC Monographs on the Evaluation
of the Carcinogenic Risk of Chemicals to Humans. Vol. 15. IARC, Lyon, France.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons,
Inc., New York.
Leo, AJ. 1983. Log P Parameter Database, Pomona College, Claremont, California.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York
Oliver, B.G. and AJ. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by
Rainbow Trout: Correlations with Partition Coefficients and Environmental Residues. En-
viron. Sci. Technol. 12:287-291.
Perwak J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft
Report. EPA Contract 68-01-5949.
Stanford Research Institute (SRI). 1986. Directory of Chemical Producers. Stanford Re-
search Institute, Menlo Park, California.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. EPA Office
of Water Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed. Van
Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry and Phvsics. 67th ed. CRC Press, Boca
Raton, Florida.
C-232
-------
1,2,4,5 TETRACHLOROBENZENE
CAS No.: 95-94-3
CAS Preferred Nomenclature:
Benzene, 1,2,4,5-tetrachloro-
Empirical Formula:
Synonyms and Common Names:
- 1,2,4,5 TCB
- 5-Tetrachlorobenzene
- s-Tetrachlorobenzene
ci
o
ci
.ci
1,2.4,5-tetrachlorobenzene
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish)(45 FR
79318):
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
EPA Ambient Water Quality Criteria EPA Drinking Water Health Adviso-
(for protection of aquatic organ- ries:
isms)(IRIS, 1989): None established at present
Freshwater Saltwater
Acute, ^g/L 250 160
Chronic, ftgfL 50 129
Above are LECs (Lowest Effect Con-
centration).
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
Use Restrictions and Bans: None found.
C-233
-------
SOURCES OF 1,2,4,5 TETRACHLOROBENZENE
Total 1,2,4,5 Tetrachlorobenzene Produced;
In 1977, Dow Chemical produced between 10 million and 50 million pounds of
1,2,4,5 TCB (Perwak el aL, 1983).
Uses of 1,2,4,5 Tetrachlorobenzene;
1,2,4,5 TCB is a chlorophenoxy compound used as a precursor for the production
of the herbicide, 2,4,5 1(2,4,5 trichlorophenoxyacetic acid). 2,4,5 T was a major
component of Agent Orange, the defoliant used in Vietnam (Klaassen el al, 1986).
1,2,4,5 TCB has also been used as a precursor for the production of other organic
chemicals and in the dye industry (Perwak £i al., 1983).
- It has also been utilized in the moisture-proofing of electrical insulation (Perwak
el al, 1983).
Other Sources! None identified.
FATE IN ENVIRONMENT
Partitioning:
Based on its physical/chemical properties, 1,2,4,5 TCB is highly volatile (H = 0.027
atm m3/mole), strongly sorbs to soil (Kow s47,000), and has a high potential for
bioaccumulation. BCF values from experimental data ranged between 5,300 and
13,000.
Persistence;
Photolysis is not excepted to be significant for 1,2,4,5 TCB since little absorption
occurs in the solar region (> 290 mm) for the chemical (Perwak el al., 1983).
Biodegradation is not expected to occur readily because of the high degree of
chlorination, although Pseudomonas bacteria are able to produce 30% ring disrup-
tion of a 200 mg/L solution at 30°C after 120 hours (Perwak el al., 1983; Ver-
schueren, 1983). In one study under anaerobic conditions, chlorobenzenes
persisted for seven years (TDB, 1985).
Hydrolysis of 1,2,4,5 TCB is not expected to be environmentally significant (Perwak
elaU 1983).
C-234
-------
1,2,4,5 TETRACHLOROBENZENE OBSERVED IN THE ENVIRONMENT
No data available.
HEALTH EFFECTS
Carcinogenicity;
The U.S. EPA has not yet evaluated the potential carcinogenicity of 1,2,4,5 TCB
(IRIS, 1989).
Mutagenic Activity;
No adequate data available (U.S. EPA, 1980).
Reproductive Effects: No data found.
Other Toxicological Effects;
No reported effects on humans.
Rats fed 1,2,4,5 TCB for 13 weeks developed kidney damage at relatively moderate
doses (0.34 mg/kg/day). Liver damage was also reported to occur at higher doses
(3.4 to 32 mg/kg/day). A higher dose (200 mg/kg/day) caused a significant increase
in deaths (IRIS, 1989).
Dogs fed 1,2,4,5 TCB (5 mg/kg/day) for 2 years showed no adverse health effects
(IRIS, 1988). .
Toxicological Effects Indices;
Reference Dose (RfD): SxlO"4 mg/kg/day (IRIS, 1989).
Oral LDso: rats, 1500 mg/kg; mice, 1035 mg/kg (Tatken and Lewis, 1984).
C-235
-------
PHYSICAL/CHEMICAL PROPERTIES
Value
Henry's Law Constant, H @
25°C (atm m3/mole):
0.027 (calc.)
C (atm nr/mole)
Log (Octanol-Water Partition Coefficient),
logKow: 4.67
Soil Adsorption Coefficient,Koc (ml/g): 1.6xl03
Fish Bioconcentration Factor,
BCF:
5300 to 13000
(exptl.)
1125*
Reference
Molecular Weight:
Physical State @20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
215.9
solid
139.5
248
1.833
N/A
6.0
0.3 (22°C)
0.045 (25°C)
Windholz, 1983
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Kirk-Othmer, 1984
PHRED, 1988
Verschueren, 1983
Kirk-Othmer, 1984
Lymanelal., 1982
PHRED, 1988
PHRED, 1988
Oliver and Niimi,
1983
PHRED, 1988;
U.S. EPA, 1980
* Value used for estimating aquatic effects
C-236
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REFERENCES
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, B.C.
Kirk-Othmer Encyclopedia of Chemical Technology. 1984. 3rd ed. John Wiley and Sons,
Inc., New York.
Klaassen, C.D., M.O. Amdur, and J. Doull, eds. 1986. Casarett and Doull's Toxicology: The
Basic Science of Poisons. 3rd ed. Macmillen Publishing Co. NY.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York
Oliver, B.G. and AJ. Niimi. 1983 Bioconcentration of Chlorobenzene from Water by
Rainbow Trout: Correlations with Partition Coefficients and Environmental Residues. En-
viron. Sti. Technol. 12:287-291.
Perwak J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft
Report. EPA Contract 68-01-5949.
PHRED. 1988. Public Health Risk Evaluation Database. Office of Emergency and Remedial
Response, U.S. EPA, Washington, D.C.
Tatken, R.L. and R J. Lewis, Sr., eds. 1983. Registry of Toxic Effects of Chemical Substances.
(RTECS). 1981-82 ed.
Toxicology Data Bank (TDB^ Database. 1985-1986. Available through the National Library
of Medicine, TDB Peer Review Committee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. EPA Office
of Water Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Weast, R.C., ed. 1986. CRC Handbook of Chemistry And Physics. 67th ed. CRC Press, Boca
Raton, Florida,
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicalsr Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
C-237
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C-238
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1,2,3 TRICHLOROBENZENE
CAS No.: 87-61-6
CAS Preferred Nomenclature:
Benzene, 1,2,3-trichloro-
Empirical Formula:
Synonyms and Common Names:
- 1,2,6-trichlorobenzene
- vic-trichlorobenzene
1,2,3-trichlorobenzene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria
(for human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic
organisms):
None established at present
EPA Drinking Water Standard
Maximum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Health
Advisories:
None established at present
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
SOURCES OF 1,2,3 TRICHLOROBENZENE
Total 1,2,3 Trichlorobenzene Produced:
In 1977, Dow Chemical Company in Midland, Michigan produced between 1 and
10 million pounds of 1,2,3-trichlorobenzene (Perwak el aL, 1983). In 1986, Stan-
dard Chlorine Chemical (Delaware City, Delaware) was the only producer, but
production figures are not available (SRI, 1986).
C-239
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Uses of 1,23 Trichlorobenzene:
1,2,3 trichlorobenzene is not commonly used directly, but instead is used as an
intermediate in chemical synthesis (Sax, 1986).
1,2,3 trichlorobenzene is used as a solvent for high melting products, as a coolant
in electrical installations and glass tempering, for polyester dying, termite prepara-
tions, synthetic transformer oil, lubricants, heat transfer medium, and insecticides
(Sax, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, 1,2,3 trichlorobenzene sorbs moderately
strong to sediment (Kow = 12,900). Volatilization can occur from water at a
moderate rate (H = 9.3X10*4 atm m3/mol). The potential for bioaccumulation
is high based on experimental data. (BCF ranged between 1,200 and 2,600.)
Persistence;
Direct photolysis of 1,2,3 trichlorobenzene is not likely to occur in natural waters
(Perwak el al., 1983).
Hydrolysis is not an environmentally significant process (Ellington el al, 1986).
Biotransformation of 1,2,3 trichlorobenzene may occur but at an unknown rate. No
degradation occurred beneath the water table (anaerobic conditions) (TDB, 1986).
PerwakfilaL (1983) reported that 10% of 1,2,3 trichlorobenzene degraded after 12
weeks in a soil containing high organic matter and up to 8% volatilized while only
2% degraded in a soil with low organic material content (up to 40% volatilized).
Degradation by Psuedomona.s bacteria is more rapid; at 30 C, 87% ring disruption
occurred within 120 hours in a concentration of 200 mg/L 1,2,3 trichlorobenzene
(Verschueren, 1983).
HEALTH EFFECTS
Carcinogenicity:
No data found. The EPA has not classified the potential carcinogenicity of 1,2,3
trichlorobenzene.
Mutagenic Activity: No data found.
C-240
-------
Reproductive Effects: No data found.
Other Toxicologicai Effects:
Trichlorobenzenes can cause liver damage in humans and animals (Gosselin, 1984;
HSDB, 1988).
1,23 trichlorobenzene is irritating to human eyes and mucous membranes of the
respiratory tract (Sax, 1986; HSDB, 1988).
1,2,3 trichlorobenzene is considered moderately toxic to humans with acute or
chronic ingestion or inhalation (Sax, 1986).
At high doses technical grade trichlorobenzene (30% 1,2,3 TCB and 70% 1,2,4
TCB) is moderately irritating to rabbit skin (HSDB, 1988).
Toxicologicai Effects Indices:
None found for human exposure.
Chronic Hazard Level for rats: 0.01 mg/kg/day/5.5 month (loss of hair) (Sax, 1986).
C-241
-------
PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm m3/mol):
Value
181.45
solid, white
crystals
53.5
218.5
1.69
N/A
12 @ 22°C
0.07@25°C
9.3xlO'4(calc.)
Reference
Kirk-Othmer, 1982
Sax, 1986
Kirk-Othmer, 1982
Kirk-Othmer, 1982
Windholz, 1983
Verschueren, 1983
U.S. EPA, 1980
LymanelaU 1982
Log (Octanol- Water Partition Coefficient),
4.11
Soil Adsorption Coefficient, Koc(mVg): 4600 (calc.)
Fish Bioconcentration Factor, BCF: 1200-2600*
(exptl.)
Leo, 1983
Lymanelal., 1982
Oliver and Niimi,
1983
* Value used for estimating aquatic effects
C-242
-------
REFERENCES
Ellington, J.J., F.E. Stancil, Jr. and W.D. Payne. 1986. Measurement ofHydrolysis Rate
Constants for Evaluation of Hazardous Waste Land Disposal. Volume I. U.S. Environmental
Protection Agency, Athens, Georgia. EPAReport No. EPA/600/3-86/043.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. ClinicalToxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
HSDB (Hazardous Substances Data Base). 1988. National Library of Medicine, Bethesda,
MD.
Kirk-Qthmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons, Inc.,
New York.
Leo,AJ. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
MedChem Project, Pomona College, Claremont, California.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York
Oliver, B.G. and A.J. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by
Rainbow Trout: Correlations with Partition Coefficients and Environmental Residues. En-
viron. Sci. Technol. 12:287-291.
Perwak, J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft
Report. EPA Contract 68-01-5949.
Sax, N.I. 1986. Hazardous Chemicals, Information Annual, No. 1. Van Nostrand Reinhold
Co., New York.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. EPA Office
of Water Regulations and Standards. EPA 440/5-80-028.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M. ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and
Biologicals. 10th ed. Merck and Co., Rahway, New Jersey.
C-243
-------
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-244
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1,2,4 TRICHLOROBENZENE
CAS No.: 120-82-1
CAS Preferred Nomenclature:
Benzene, 1,2,4,-trichloro-
Empirical Formula:
Synonyms and Common Names:
- Hostetex L-PEC
- Unsym-Trichlorobenzene
- 1,2,4 Trichlorobenzol
1,2,4-trichlorobenzene
REGULATORY STATUS
Standards and Criteria;
EPA Water Quality Criteria (for
human consumption of fish) (U.S.
EPA, 1989):
15.4 mg/L
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
(U.S. EPA, 1989)
Propose MCLG 9ng/l
Use Restrictions and Bans; None found.
EPA Drinking Water Health Adviso-
ries:
None established at present
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
SOURCES OF 1,2,4 TRICHLOROBENZENE
Total 1,2,4 Trichlorobenzene Produced;
In 1979,16 million pounds of 1,2,4 trichlorobenzene were produced (Perwak el al.,
1983). -
C-245
-------
Uses of 1,2,4 Trichlorobenzene;
1,2,4 trichlorobenzene is used as a solvent in chemical manufacturing, in dyes and
intermediate production, and in transformer dielectric fluid. In addition, it is used
as a degreaser, lubricant, and tenniticide (Verschueren, 1983; Sax, 1986).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, 1,2,4 trichlorobenzene strongly sorbs to
organics (Kows 19,900) and can volatilize (H = 2.3xlO"3 atm m/mol). In
addition, the potential for bioaccumulation is high (BCF estimated as 2,800).
Persistence;
1,2,4 trichlorobenzene is not expected to undergo hydrolysis at an environmentally
significant rate (Mabey si al, 1982).
The biotransformation rate of 1,2,4 trichlorobenzene is reportedly very slow. After
135 hours, no degradation of 0.1 mg/L 1,2,4 trichlorobenzene exposed to normal
sewage occurred. However, 56% was degraded by adapted sewage (Verschueren,
1983). Psuedomonas bacteria transformed l,2,4trichlorobenzene at a faster rate,
with concentrations of 200 mg/L (at 30°C) undergoing 92% ring disruption after
120 hours (Verschueren, 1983).
HEALTH EFFECTS
Carcinogenicity;
McNamara el al. (1981) reported no increased incidence of tumors in a 6-month
feeding study. A 2-year skin painting study with 1,2,4 trichlorobenzene demon-
strated no increase in tumors in mice (Toxline, 194). These studies, however, are
not considered adequate for carcinogenicity assessment.
No tumor development was observed in mice inhaling 600 ppm 1,2,4
trichlorobenzene daily for 6 months (U.S. EPA, 1980).
The EPA has not classified the carcinogenic potential of 1,2,4 trichlorobenzene.
Mutagenic Activity: '
1,2,4 trichlorobenzene was found to be non-mutagenic in the bacteria Salmonella
typhimurium (McNamara el al, 1981).
C-246
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Reproductive Effects;
While no increases in teratogenicity or embryo lethality were observed in rats fed
360 mg/kg/day on days 9-13 of gestation, retarded embryonic development occurred
(Kitchin and Ebron, 1983).
Other Toxicological Effects;
Chronic (long-term, low dose) exposure to 1,2,4 trichlorobenzene has resulted in
liver, kidney, brain and lung damage in animals (Sittig, 1985; HSDB, 1988).
In humans, exposure to 1,2,4 trichlorobenzene has been reported as causing central
nervous system stimulation, headache, dermatitis and skin, eye, and throat irritation
(Sax, 1986; HSDB, 1988).
At high doses technical grade trichlorobenzene (30% 1,2,3 TCB and 70% 1,2,4 TCB
is moderately irritating to rabbit skin (HSDB, 1988).
Toxicological Effects Indices;
. Reference Dose (RfD): 2xlO"2 mg/kg/day (PHRED, 1988).
TLV-C (threshold limit value-ceiling - not to be exceeded during occupational
exposure): 40 mg/m3 (ACGffl, 1986).
. Oral LD50: rat, 756 mg/kg (U.S. EPA, 1980; HSDB, 1988).
C-247
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PHYSICAL/CHEMICAL PROPERTIES
Value
,-3
Henry's Law Constant,
H @ 25°C (atm m3/mol): 2.3x10
Log (Octanol-Water Parti-
tion Coefficient), log Kow: 4.3
Soil Adsorption Coefficient,
Koc(mVg): 9.2X103
Fish Bioconcentration Factor, BCF: 2800* (calc.)
Reference
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
181.45
clear liquid
17.15
213.8
1.45 (20/4°C)
N/A
30 @ 25°C
0.29 @ 25°C
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Kirk-Othmer, 1984
Weast, 1986
Sax, 1986
U.S. EPA, 1980
Mabeyelal.,1982
PHRED, 1988
PHRED, 1988
PHRED, 1988;
ICF, 1985
* Value used for estimating aquatic effects
C-248
-------
REFERENCES
ACGIH (American Conference for Governmental Industrial Hygienists). 1986. Threshold
Limit Values for Chemical Substances in the Work Place. ACGIH, Cincinnati, OH.
Callahan, M.A., M.W. Slimak, N.W. Gabel, I.P. May, C.F. Fowler, J.R. Freed, P. Jennings,
R.L. Durfee, F.C. Whitmore, B. Maestri. 1979. Water Related Environmental Fate of 129
Priority Pollutants. U.S. Environmental Protection Agency, Washington D.C. EPA-440/4-79-
029a.
HSDB (Hazardous Substances Data Base). 1988. National Library of Medicine, Bethesda,
MD.
ICF, Inc., 1985. Draft Superfund Public Health Evaluation Manual.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons,
Inc., New York.
Kitchin, K.T., and M.T. Ebron. 1983. Material Hepatic and Embryonic Effects of 1,2,4-
Trichlorobenzene in the Rat. Environ. Res. 21:362-373.
Lvman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982. Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York
Mabey, W.R., J.H. Smith, R.T. Podoll, H.L. Johnson, T. Mill, T.W. Chou, J. Gates, J.W.
Patridge, H. Saber, and D. Vandenberg. 1982. Aquatic Fate Process Data for Organic Priority
Pollutants. SRI International. EPA 440/4-81-014.
McNamara, P.W., M. Byrne, M. Goyer, P. Lucas, K Scow, and M. Wood. 1981. An Exposure
and Risk Assessment for 1,2,4,-Trichlorobenzene. U.S. EPA Office of Water Regulations and
Standards. EPA 440/4-85-017.
Perwak, J., E. Cole, S. Coons, N. Green, W. Lyman, M. Miller, J.H. Ong, and K. Scow. 1983.
Evaluation of Waterborne Exposure Pathways to Paragraph 4(c) Pollutants. U.S. EPA Draft
Report. EPA Contract 68-01-5949.
Public Health Risk Evaluation Database (PHRED). 1988. U.S. EPA Office of Emergency
and Remedial Response, Washington, D.C.
Sax, N.I. 1986. Ha7arHous Chemicals Information Annual. No. 1. Van Nostrand Reinhold
Co., New York.
Sittig, M. 1985. Handbook of Toxic and Hazardous Chemicals and Carcinogens. 2nd ed.
Noyes Publications: Park Ridge. New Jersey. Toxicology Data Bank (TDB) Database. 1985-
C-249
-------
1986. Available through the National Library of Medicine's MEDLARS System, National
Library of Medicine, TDB Peer Review Committee.
U.S.EPA 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. EPA Office
of Water Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-028.
U.S. EPA 1987. Draft of RCRA Facility Investigation (RFI) Guidance. U.S. Environmental
Protection Agency, Office of Solid Waste. EPA 530/SW-87-001.
U.S. EPA, 1989. Draft Summary of Drinking Water Regulations and Health Advisories,
Office of Drinking Water.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Weast, R.C. ed. 1986. CRC Handbook of Chemistry and Physics. 67 ed. CRC Press, Boca
Raton, Florida.
Worthing, C.R., ed. 1983. The Pesticide Manual: A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-250
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1,3,5 TRICHLOROBENZENE
CAS No.: 108-70-3
CAS Preferred Nomenclature:
Benzene, 1,3,5-trichloro-
Empirical Formula:
Synonyms and Common Names:
- sym-Trichlorobenzene
ci
1,3,5-trichlorobenzene
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans: None found.
EPA Drinking Water Health Adviso-
ries:
None established at present
Food and Drug Administration Ac-
tion Level for Fish:
None established at present
SOURCES OF 1,3,5 TRICHLOROBENZENE
Total 1,3»5 Trichlorobenzene Produced;
In 1986, 1,3,5 trichlorobenzene was produced by Southland Corporation. No
production data are available (SRI, 1986).
Uses of 13,5 Trichlorobenzene;
1,3,5 trichlorobenzene is commonly used as an intermediate in chemical synthesis
of other organic compounds (Sax, 1984).
C-251
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1,3,5 trichlorobenzene is also used as a solvent for dyes in textile manufacture
(Kirk-Othmer, 1982).
Other Sources: None found.
FATE IN ENVIRONMENT
Partitioning;
Based on its physical/chemical properties, 1,3,5 trichlorobenzene is moderately
volatile (H estimated to be 6.0 x 10 atm m /mole), moderately sorbed to soil
(Kows30,000), and has a high potential for bioaccumulation. (BCF from experi-
mental data range from 1,800 to 4,100.)
Persistence;
Hydrolysis and aqueous photolysis are expected to be unimportant under environ-
mental conditions based on the structural similarity with 1,2,3 and 1,2,4
trichlorobenzene.
Using fresh sewage, 1,3,5 trichlorobenzene at an initial concentration of 1.0 mg/L
was not degraded after 135 hours, compared with 47 percent degraded using
acclimated sewage. Biodegradation by Pseudomonas bacteria was found to be
more rapid, with 78 percent of an initial 200 mg/L sample degraded (ring disruption)
after 120 hours at 30°C (Verschueren, 1983).
1,3,5-TRICHLOROBENZENE OBSERVED IN THE ENVIRONMENT
No data available.
HEALTH EFFECTS
Carcinogenicity;
No data found. The U.S. EPA has not classified the potential carcinogenicity of
1,3,5 trichlorobenzene.
Mutagenic Activity: No data found.
Reproductive Effects;
No teratogenic effects were observed in rats when mothers were fed 1,3,5-
trichlorobenzene at doses between 75 and 600 mg/kg. There were some mild
changes in bone development (at unspecified doses) (U.S. EPA, 1985).
C-252
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Other Toxicologicai Effects:
1,3,5 trichlorobenzene has been found to be moderately irritating to human skin,
eyes and other mucous membranes (Sax, 1984).
Rats that inhaled 1,3,5 trichlorobenzene on a schedule simulating possible occu-
pational exposures (6 hours/day, 5 days/week, for 13 weeks) developed some
reversible changes to lung tissues (U.S. EPA, 1985).
It has been reported that trichlorobenzenes cause liver damage to humans and
animals, but it is not known which one (1,3,5-, 1,2,3- or 1,2,4-trichlorobenzene) is
the toxic component (Gosselin, 1984).
Toxicologicai Effects Indices: None found.
C-253
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PHYSICAL/CHEMICAL PROPERTIES
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H@25°C(atm m3/mol):
Log (Octanol-Water
Partition Coefficient), log Kow:
Soil Adsorption Coefficient, Koc(ml/g):
Fish Bioconcentration Factor, BCF:
Value
181.45
solid
63.4
208.5
N/A
N/A
5.88 @ 20°C
0.15 (25°C)
6.0xlO'3(calc.)
4.49
9100 (calc.)
1400 (calc.)
1800-4100*
(exptl.)
Reference
Kirk-Othmer, 1982
Windholz, 1983
Kirk-Othmer, 1982
Verschueren, 1983
U.S. EPA, 1980
Lymaneial., 1982
Leo, 1983
LymanelaL, 1982
LymanfilaL, 1982
Oliver & Niimi, 1983
* Value used for estimating aquatic effects
C-254
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REFERENCES
Gosselin, R.E., R.P. Smith, H.C. Hodge, and I.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Kirk-Othmer Encyclopedia of Chemical Technology. 1982. 3rd ed. John Wiley and Sons,
Inc., New York.
Leo, AJ. 1983. Log P Parameter Database, Pomona College, Claremont, California.
Lyman, W.G., W.F. Reehl, and D.H. Rosenblatt. 1982 Handbook of Chemical Property
Estimation Methods. McGraw-Hill Book Co., New York.
Oliver, B.G. and AJ. Niimi. 1983. Bioconcentration of Chlorobenzenes from Water by
Rainbow Trout: Correlations with Partition Coefficients and Environmental Residues. En-
viron. Sci. Technol. 12:287-291.
Sax, N.I. 1984. Dangerous Properties of Industrial Materials. 6th ed. Van Nostrand Reinhold
Co., New York.
Stanford Research Institute (SRI). 1986. Directory of Chemical Producers. Stanford Re-
search Institute, Menlo Park, California.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS System, National Library of Medicine, TDB Peer Review Commit-
tee.
U.S. EPA. 1980. Ambient Water Quality Criteria for Chlorinated Benzenes. U.S. EPA Office
of Water Regulations and Standards, Criteria and Standards Division. EPA 440/5-80-028.
U.S. EPA. 1985. Health Assessment Document for Chlorinated Benzenes. U.S. EPA, Office
of Health and Environmental Assessment. EPA 600/8-84-015F.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and
Biologicals. 10th ed. Merck & Co., Rahway, New Jersey.
C-255
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C-256
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TRIFLURALIN
CAS No.: 1582-09-8
CAS Preferred Nomenclature:
Benzenamine, 2,6-dinitro-N,N-
dipropyl-4-(trifluoromethyl)-
Empirical Formula:
Synonyms and Common Names:
- Treflan - Triflurex
- Trefanocide - Crisalin
- Elancolan - Trim
- Ipersan - Ipifluor
C,H7-N-C,H,
C,3H16F3N3°4
REGULATORY STATUS
Standards and Criteria:
EPA Water Quality Criteria (for
human consumption of fish):
None established at present
EPA Ambient Water Quality Criteria
(for protection of aquatic
organisms):
None established at present
EPA Drinking Water Standard Maxi-
mum Contaminant Level:
None established at present
Use Restrictions and Bans:
EPA Drinking Water Health Adviso-
ries (IRIS, 1989):
Child (10 kg):
1-day, 10-day, long-term
exposures = 30/
-------
SOURCES OF TRIFLURALIN
Total Trifluralin Produced;
The herbicidal properties of the dinitroanilines, particularly trifluralin, were first
reported in 1960 (Farm Chemicals Handhnnk. 1985). In 1982, 25,000 tons of
trifluralin were produced, of which 18,000 tons were used in the U.S. (Green el al,
1987). In 1986, only the Eli Lilly Co. produced trifluralin (SRI, 1986).
Uses of Trifluralin:
Trifluralin is used as an herbicide to control annual grasses and broadleaf weeds in
a wide variety of agricultural crops and in some domestic and industrial situations
(Worthing, 1983; U.S. EPA, 1987a).
The primary uses of trifluralin are on cotton and soybeans. In 1987 the uses were
divided as follows: 65% on soybeans, 19% on cotton, 8% on sunflowers, 4% on
wheat and 6% for all other purposes (U.S. EPA, 1987a).
Trifluralin is registered for use on forty broadleaf crops (McEwen and Stephenson,
1979). It is also used to control weeds in orchards and in vegetable crops (47 FR
33777).
Non-agricultural uses are the control of grasses (e.g., barnyard grass, duckweed,
crabgrass) in rights-of-way, for outdoor domestic sites and industrial sites (McEwen
and Stephenson, 1979; Thomson, 1983; Farm Chemicals Handbook. 1985; U.S.
EPA, 1987a).
Other Sources: None identified.
FATE IN ENVIRONMENT
Partitioning;
Based upon it's physical/chemical properties, trifluralin is predicted to volatilize
relatively slowly from both water (H = 1.9 x 10 atm m /mol) and soil surfaces
(P/SKoc = 3.3x10" mmHg L/mg corresponding to an estimated volatilization
half-life of 48 days), adsorb relatively strongly to soils and sediments (Koc =
218,800), and have a high potential for bioaccumulation (BCF = 1.8 x 103 to 6.0 x
1982).
Trifluralin appears to have a very low potential for leaching. Gray el al, 1982
reported that after elution with 60 cm of water, > 90% of the applied trifluralin and
> 99% of the trifluralin accounted for remained in the upper 5 cm of soil columns
packed with a sandy loam (oc = 0.8%), a silt loam (oc = 2.8%), or a clay loam (oc
C-258
-------
= 1.3%) soil. Helling and Turner (1968) reported that trifluralin was essentially
immobile (Rf = 0.0) on soil thin-layer chromatography plates using 14 different
soils.
Bionomics (1973) reported trifluralin tissue concentrations of 5.5 to 12 mg/kg in
bluegill sunfish exposed to an average of 7.9/*g/L over 35 days. The tissue to water
concentration ratios correspond to non-steady state bioconcentration factors of 7.0
Persistence;
Mosier and Saunders (1978) reported that trifluralin at 30°C did not undergo any
detectable hydrolysis at pH, 3, 6, or 9 over a 32 day period.
Trifluralin is susceptible tophotolytic degradation (McEwenand Stephenson, 1979;
TDB, 1985). A study by Zepp and Baughman reported a half-life of approximately
1 hour for trifluralin in water exposed to sunlight (TDB, 1985).
Trifluralin is also biodegradable; a Pseudomonas bacteria has been found that
decomposes it in aqueovs media (LymanfiiaL, 1982.) The rate of biodegradation
is uncertain. Parr and Smith (1973) reported that the rate of trifluralin degradation
in a silt loam soil was much greater under anaerobic conditions ( < 1% remaining
after 20 days incubation) than under aerobic conditions (approximately 85% re-
maining after 20 days incubation).
In soil half-lives of 3 to more than 27 weeks have been reported (Verschueren,
1983). The associated dissipation rates ranged from 0.033/day to 0.0037/day. Other
determinations of trifluralin half-lives are:
- 21 to 35 days in irrigated soils
- 126 to greater than 190 days in a sandy loam soil
- 50 days in sandy loam soil in a greenhouse (Worthing, 1983).
Research by Golab fiiaL, 1979 showed that trifluralin can undergo dealkylation and
cyclazation reactions to form 28 different breakdown products.
HEALTH EFFECTS
Carcinogenicity;
The U.S. EPA has classified trifluralin as a possible human carcinogen (group C)
on the basis that there is only limited evidence from animal experiments that it
causes cancer (U.S. EPA, 1987a, b).
In a feeding experiment with rats, trifluralin caused kidney tumors, but only at very
high doses (6500 ppm) and at a rate only slightly greater than that seen in control
animals (Tatken and Lewis, 1983; U.S. EPA, 1987a).
C-259
-------
Studies with mice and hamsters showed that technical-grade trifluralin caused liver
and lung tumors. However, it was not certain whether these were caused by the
trifluralin alone or by the nitrosamine contaminant (84-88 ppm dipropylnitrosam-
ine) (47 FR 33777; Gosselin eiaL, 1984; U.S. EPA, 1987a).
Similar chemicals (e.g., ethalfluralin) have been demonstrated to cause tumors in
rats (U.S. EPA, 1987a).
Mutagenic Activity;
Trifluralin is not considered to be mutagem'c. The dominant lethal test with mice
was negative as were tests with yeast cells and sister chromatid (chromosome)
exchange in hamster cells (U.S. EPA, 1987a).
Reproductive Effects;
Trifluralin has not been shown to impair the reproductive ability of rats, rabbits, or
dogs (U.S. EPA, 1987a, b). The only adverse effect demonstrated was reduced birth.
weights in rats exposed to high doses. (IRIS, 1989).
Other lexicological Effects:
Triflurahn is not acutely toxic to humans but may cause eye or skin irritation in
exposed humans (Dreisbach, 1980; U.S. EPA, 1987a).
Long-term, low dose (chronic) exposure to trifluralin caused kidney damage in rats
(at 200 ppm) (U.S. EPA, 1987a).
Toxicological Effects Indices;
Reference Dose (RfD): 7.5xlO"3 mg/kg/day (IRIS, 1989).
Cancer Potency Factor (CPF): 7.7xlO'3 (mg/kg/day)'1 (IRIS, 1989).
Oral LDso: mice, 500 mg/kg; rats, 10,000 mg/kg; dogs, chickens, rabbits, 2 mg/kg
(U.S. EPA, 1987b).
C-260
-------
Molecular Weight:
Physical State @ 20°C:
Melting Point (°C):
Boiling Point (°C):
Specific Gravity:
Acid Dissociation Constant, pKa:
Water Solubility, S (mg/L):
PHYSICAL/CHEMICAL PROPERTIES
Value
335.3
yellow-orange
crystalline solid
48.5-49
139-140 @
4.2 mm Hg
N/A
0.3
4.0 @ 27°C
l.lxlO'4(250C)
£
(calc.)
Vapor Pressure, P (mm Hg):
Henry's Law Constant,
H @ 25°C (atm m3/mol):
Log (Octanol-Water Partition
Coefficient), log Kow: 5.34
Soil Adsorption Coefficient, KOC (ml/g): 1.37xl04
Fish Bioconcentration Factor, BCF: 1800-6000*
Reference
Worthing, 1983
Worthing, 1983;
U.S. EPA, 1987b
Worthing, 1983
Windholz, 1983
N/A
U.S. EPA, 1987b;
Herbicide Handbook, 1983
Worthing, 1983;
Verschueren, 1983
U.S. EPA, 1987a
Lymanfilal., 1982
Leo, 1983
PHRED, 1988
Worthing, 1983
* Value used for estimating aquatic effects
C-261
-------
REFERENCES
»
Bionomics EG+G. 1973. Exposure of Fish to 14C-trifluralin: Accumulation, Distribution,
and Elimination of 14C Residues. Submitted to U.S. EPA by Elanco Proudcts Co.
Dreisbach, R.H. 1980. Handbook of Poisoning! Preventing Diagnosis and Treatment.
Lange Medical Publications, Los Altos, California.
Farm Chemicals Handbook. 1985. Meister Publishing Co., Willoughby, OH.
Golab, T., W.A. Althaus, and H.L. Wooten. 1979. Fate of 14C) Trifluralin in Soil, J. Agric.
FoodChem. 22:163.
Gosselin, R.E., R.P. Smith, H.C. Hodge, and J.E. Braddock. 1984. Clinical Toxicology of
Commercial Products. 5th ed. The Williams and Wilkins Co., Baltimore.
Gray,J.E.,A.Loh,R.F.Sieck,eiaL 1982. Laboratory Leaching of Ethalfluralin. Eli Lilly Co.
Green, M.B., G.S. Hartley, and T.F. West. 1987. Chemicals for Crop Improvement and Pest
Management. 3rded. Pergamon Press. Oxford, England.
Helling and Turner. 1968. Pesticide Mobility: Determination by Soil Thin-Layer Chroma-
tography. Sti 162:562-563.
Helling,'C.S. 1976. DinitroanUine Herbicides in Soils. J. Environ. Qual.SU): 1-15.
IRIS. 1989. Integrated Risk Information System. U.S. EPA, Washington, D.C.
Leo, AJ. 1983. Log P Parameter Database, Issue #24 (dated 12/16/83). Obtained from the
Medchem Project, Pomona College, Claremont, California.
Lyman, WJ., W.F. Reehl, and D.H. Rosenblatt, ed. 1982. Handbook nf Chemical Property
Estimation Methods. McGraw-Hill, New York. 977 p.
McEwen, F.L. and G.R. Stephenson. 1979. The Use and Significance of Pesticides in the
Environment. John Wiley & Sons. New York.
Mosier, J. and D. Saunders. 1978. A Hydrolysis Study on the Herbicide Trifluralin. Eli Lilly
Co. Submitted to U.S. EPA.
Parr, J.F. and S. Smith. 1973. Degradation of Trifluralin Under Laboratory Conditions and
Soil Anaerobiosis, Soil Sci. HS(l):55-63.
Public Health Risk Evaluation Database (PHRED). 1988. Office of Emergency and Reme-
dial Response, U.S. EPA, Washington, D.C.
C-262
-------
Stanford Research Institute (SRI). 1986. Directory of Chemical Producers. Stanford Re-
search Institute, Menlo Park, California.
Tatken, R.L. and R J. Lewis, Sr., eds. 1983. Registry of Toxic Effects of Chemicals Substances
(RTECS). 1981-82 ed.
Thomson, W.T. 1985. Agricultural Chemicals Bonk II - Herbicide. 1981-82 ed.
Toxicology Data Bank (TDB) Database. 1985-1986. Available through the National Library
of Medicine's MEDLARS system, National Library of Medicine. TDB Peer Review Commit-
tee.
U.S. EPA. 1987a. Guidance for the Reregistration of Pesticide Products Containing Triflu-
ralin as the Active Ingredient. Office of Pesticides and Toxic Substances, Washington, D.C.
EPA540RS-87195.
U.S. EPA 1987b. Draft Trifluralin Health Advisory. Office of Drinking Water, Washington,
D.C.
Verschueren, K. 1983. Handbook of Environmental Data on Organic Chemicals. 2nd ed.
Van Nostrand Reinhold, New York.
Windholz, M., ed. 1983. The Merck Index: An Encyclopedia of Chemicals, Drugs, and
Biolngicals. 10th ed. Merck & Co., Rahway, New Jersey.
Worthing, C.R., ed. 1983. The Pesticide Manual; A World Compendium. 7th ed. British
Crop Protection Council, Croydon, England.
C-263
-------
C-264
-------
APPENDIX D
-------
APPENDIX D-l
Key to Site Description Matrix
Site Description Matrix
Also included in Volume I, Appendix B-3
-------
Key to Table D-l
Matrix of Episodes and Site Descriptions
COLUMN HEADING
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
EPA REGION
EPISODE
LATITUDE
LONGITUDE
STATE
WATERBODY
LOCATION
NSQ
B
POINT SOURCES:
PPC
PPNC
REFINERY
NPLSITE X
DESCRIPTION
The U.S. Environmental Protection Agency Region which includes the
sample location.
The EPA Episode Number which is specific to each sampling location.
The latitude of the sample site in degrees, minutes and seconds.
The longitude of the sample site in degrees, minutes and seconds.
The state where the sample was collected.
Name of the water body where the sample was collected.
The nearest town, road or county to the sample location.
Sample site from the USGS NASQAN monitoring network.
Background site as selected for study.
Point sources include the following six categories:
Site near paper and pulp mill using chlorine for bleaching (includes mills
using the sulfite process).
Site near paper and pulp mill not using chlorine for bleaching.
Site near refinery using the catalytic reforming process.
Site near an EPA National Priority List Site (Superfund site).
14. OTHER INDUSTRY
Site near State Superfund site or known dump site.
Site near industrial facility other than a paper mill, refinery, or wood
preserver.
15. POTW Site near discharge of a Publicly Owned Treatment Works (POTW).
16. WP Site near wood preserver.
NONPOINT: Nonpoint sources include the following two categories:
17. URBAN Site near urban runoff.
18. AGRICULTURE Site near agricultural area.
D-l-1
-------
D-l-2
-------
TABLE D-l
Matrix or Episodes and Sile Descriptions
EPA
«K
1
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
FpK«cn/cnc, llg)
Five |ij|itr nulls (I'l'NC), Air Drake Co , hydro-power, dairy fields
Ind chemical, slccl, pclrochcmic.il, landfills
Allied Chemical (manufacturer of HCB), landfills
Ind: Harrison Radiator, chem (HCB), Ag- orchards and croplands
Sampled below Belmonl Dam. Superfund sue is approximately 10 miles
upstream (heavy metals, hydrocarbons)
Same as 2326
-------
TABLED-1 (Conl.)
EPA
tttg
II
II
II
II
II
II
II
II
II
11
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
III
III
III
III
111
III
111
III
Episode
*
3306
3319
3320
2709
3259
3409
3321
3322
3260
2328
2329
3323
3324
3325
3326
3300
3297
3299
3302
3303
3412
3305
2322
3308
3411
3307
3327
3432
3431
2210
3147
3099
3098
3097
3149
3100
3317
Ijillludt Longlludi
44.57-30N 074.49.00W
4040.00N 073.20.00W
404545N 073: 19.00 W
41 1630N 073.57 OOW
43 (BOON 073.36 30W
413000N 073.57 30W
403840N 073.50 40W
403745N 073.47.00W
43 51 30N 073 22.00W
43.20.25N 078.43 14W
431405N 077.32.03W
404800N 07345-OOW
404700N 073:45 OOW
40 49 DON 073.40 OOW
40 50 ION 073.40 15W
431530N 0790345W
430300N 078S855W
43 02 DON 07853.45W
430230N 079.11 OOW
44.1230N 075.00 OOW
432800N 076 31 OOW
445830N 074.44 OOW
44 59 DON 073 20 OOW
45 00 DON 07321 OOW
4311 18N 0773730W
444230N 0752830W
403820N 07402I5W
175940N 0664625W
182640N 0660630W
385220N 0770215W
385230N 07702.30W
38.35 OON 075 12 OOW
39.48 08N 0753444W
39.35 40N 075:37.50W
39.43 58N 07545.37W
391536N 07631:30W
39-28 OON 079-01KMW
Sim* Wabrbody Lanlbn
NY Grass River Massena
NY Great South Bay Babylon
NY Great South Bay Babylon
NY Hudson River Peekskill
NY Hudson River Fort Miller
NY Hudson River Peekskill
NY Jamaica Bay New York
NY Jamaica Bay New York
NY Lake Champlain Ticondcroga
NY Lake Ontario Olcotl
NY Lake Onlano Rochester
NY Little Neck Bay Long Is Sound
NY Little Neck Bay Long Is Sound
NY Manhassell Bay Long Is Sound
NY Manhassell Bay Long Is Sound
NY Niagara R Delta Porter
NY Niagara River Niagara Falls
NY Niagara River N. Tonawanda
NY Niagara River Lcwiston
NY Oswegaichie River Newton Falls
NY Oswego Harbor Oswcgo
NY Raquelle River Massena
NY Richelieu River Rouses Pi
NY Richelieu River Rouses Pi
NY Rochester Embay Rochester
NY Si Lawrence River Ogdcnsburg
NY Upper Bay New York
PR Guayanilla Bay
PR San Juan Harbor San Juan
DC E Potomac River DC
DC Polemic River Park N of Wilson Br
DE Indian River Roscddle Bead
DE Red Clay Creek Ashland
DE Red Lion Creek Tybouts Corner
DE White Clay Creek Thompson
MD Baltimore Harbor Baltimore
MD Potomac R N. Br. Weslernporl
NSQ B
X
X
X
X
POINT SOUKCtS
NPL Olbcr
PPC PPNC WP Hlnj SIU Ind POTW
X
X
X
XXX
X X
XXX
X X
X X
X
X
X
X X
X X
X X
X X
X X
X X
X X
X X
X
X
X XX
X
X
X
X
X X
X X
X XX
X X
X X
X X
X
X
X X
X X
NONPOINT
Ultra A*rl
X
X
X
X
X
X
X X
X X
X X
X X
X X
X
X
X X
X
X X
X X
X
X
X
Additional SIU Description
(FKllllks In Ihc Tkhilqr of Ihc umpllng site)
Sampled below ALCOA'S outfall (PCB concern), CM & Reynolds (2
miles below mouth of river)
Same as 3320
Same as 3319
Same as 3409, Ind . chem ; P&P mill 150 river miles upstream, Supcrfund
site (PCB)
Fort Miller Pulp and Paper (Finch, Pyruyn & Co.)
Same as 2709; Ind : chem.; P&P mill ISO river miles upstream, Supcrfund
site (PCB)
Same as 3322, ind chem ; airport, landfill
Same as 3321, Ind chem , airport; landfill
International Paper Co
Ag : apple orchards and croplands
Ind . chem (Kodak), Site at the mouth of Genesee River
Same as 3324
Same as 3323
Same as 3326
Same as 3325
Ind . chem , Olin, Duponl, Ondenlal (HCB); Ag.: orchards, landfill
Ind cbem ; Ohn, Duponl, Oxidenlal Chem (HCB), (companies
downstream of site)
Ind chemical
Ind . chem , Olin, Duponl, Oxidenlal (HCB), Ag.: orchards
Newton Falls Paper Mill (defunct since October 1984)
Ind Chemical
Potsdam Paper and Norfolk Paper (PPNC), ALCOA, GM, Reynolds
(upstream of mouth)
Ind chemical
Pondcrosa Fibers (out of business more than 4 years), Dow chemical in
Canada
Sampled al 69lh Street Pier
Carililiun Gulf Refining Corp , landfill
Estuary
Ind: metal plalmg, mining; illegal dump (landfill), Ag mushroom farming
Chemical spill (HCB concern); Superfund site (HCB)
Westvaco (indirect); rural
-------
TABLE D-l (Conl.)
EPA
"I
111
III
III
III
III
III
III
III
111
HI
III
111
111
III
111
III
III
III
III
III
III
III
III
III
III
III
111
111
III
III
III
III
III
III
III
IV
IV
spkodc
*
2231
3103
3316
3161
3420
3094
3095
3096
3318
3419
3310
3101
2215
2212
3104
3415
2211
3414
3315
2216
3422
3421
2225
2228
2227
2220
3423
3424
3193
3258
2500
3314
1311
3312
3313
2304
2309
Lolllude Longitude
39:39 31N 07610:28W
39.38.00N 0761000W
412520N 078.44:10W
3956.30N 074.14 35W
395342N 076.49.09W
4002.24N 074 59 20 W
39 53 DON 07S11.46W
39.50. 12N 075 20 00 W
40.23 20N 078 24 20 W
420925N 080.02.57W
4039.40N 0751435W
4003.40N 075 28 23 W
4017:30N 079-52 33W
39.58 DON 07511.20W
39-58 22N 075 11. 33 W
41 18 SON 0754800W
400300N 076 30 00 W
41 18.50N 07548.45W
4021.00N 076 23 00 W
4133-22N 07741.28W
36 33 ION 0765457W
374715N 080 00 06 W
3735-OON 07925.00W
374015N 0780510W
364613N 0770959W
374603N 0771957W
373155N 0764840W
373201N 076 50 38 W
370145N 078 55 40 W
364948N 0761730W
3827.WIN 081 49 OOW
383130N 0815437W
3940.00N 080:5 152W
40 09: ION 080.42 25W
3931 ION 077.S2.30W
3132.48N 0893045W
32.24:4 IN 086.24 30W
Suit Wiurbody Locollon
MD Susquchaima River Conowingo
MD Susquehanna River Conowingo
PA Clarion River Ridgcway
PA Cobb Creek Philadelphia
PA Codorus Creek Spring Grove
PA Delaware River Torresdale
PA Delaware River SchuylkiUJncI
PA Delaware River Eddyslone
PA Frankstown Branch Kladdcr Station
PA Lake Erie Erie
PA Lehigh River Easton
PA Little Valley Creek Paoli
PA Monongahela River Clairlon
PA SchuyUull River Philadelphia
PA Schuylkill River Philadelphia
PA Susquchanna N Br Ransom
PA Susquchanna River Columbia
PA Susquehanna River Pitlslon
PA Union Canal Lebanon
PA Young Womens Cr Renovo
VA Blackwater River Riverdale
VA Jackson River Covinglon
VA James River Glasgow
VA James River Carler&vtllc
VA Nolloway River Sebrell
VA Pamunkey River Hanover
VA Pamunkey River West Point
VA Pamunkey River West Point
VA Roanoke River Brookncal
VA S Br Ehiahclh R Norfolk
WV Kanawha Rivti Nilro
WV Kanawha River Wmfield
WV Ohio River Nw Marlmsvle
WV Ohio River Wheeling
WV Opequon Creek Bedington
AL Alabama River Clairbornc
AL Alabama River Montgomery
NSy B
X
X
X
X
X
X
POINT SOIIKDfcS
NPL Olhcr
PPC PPNC WP Rfny Silt lad POTW
X X
X X
X
X X
X
X X
X XX
X XX
X
X XX
X X
X
X X
X X X X
X X X X
X
X XX
X
X
X
X
X X
XX X
X X
X X
X
X
X
X X
X X
X X
X XX
X
X X
X X
NONPOINT
Uitan Agrt
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X X
X X
X
X
X X
X X
Additional Slle Description
(FoilllUci In the Ylclnllj of Ihc sampling tile)
Same as 3 103
Same as 2231
Penlech Papers in Johtuonburg, rural, acid mine drainage
Old PCP plant (defunct for more than 5 years), landfill
P.H Gladtfelder in Spring Grove
Coastal Eagle Point Oil Co in NJ, Inorganic chem
Mobil Oil in NJ, Ind chem; multiple sources; Ag . croplands (trucking of
vegetables)
Applelon Paper on the Jumata River (Holler Creek)
Hammermill Paper (indirect), railyard, food processing plant
Steel industry
Paoli Railyard (historic PCB problems)
Ind.. inorganic chem. and pest
Same as 3104, two refineries, Ind . org chem & pest ; P&P mill,
Superfund site (PCP)
Same as 2212, two refineries; Ind org chem & pest , P&P mill.
Superfund site (PCP)
Superfund site (heavy metals)
Gladtfelder (bleachkraft) 20 miles upstream an tributary
Superfund site (heavy metals), acid mine drainage
Pesticide concern
Union Camp Corporation in Franklin
Weslvjco Corporation
Light agriculture, rural
Westvaco (PPC), Virginia Fibers and Nckoosa Edwards (PPNC)
Union Camp is 20 miles downstream of sampling site
Upstream from the Cheasepedke Corporation
Chcdscpeakc Corporation (upstream of site)
Chcascpeakc Corporation (downstream of silo)
Rural
Ind |>eblicidcs, trtililiiropliLiiol, and organic chi.niii.jls (Dow .mil
Mumamo), rural
Ind pesticides (Monsanto), rural
Quaker State Oil Refining, steel industries, urban runoff
Ag orchards, rural
Alabama River Pulp Company
Ind. organic chem. & pest , Fence-post company, Ag croplands
-------
TABLED-1 (Conl.)
EPA
B*l
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
Eobodc
ri|pnww-
«
3360
3170
2302
3172
3328
3137
3169
3168
3331
3332
2151
3329
3334
3174
2148
3333
2142
3173
21S2
3330
3337
3177
3375
3376
3377
3378
3178
3179
2294
3176
3336
2290
3175
3338
3180
3335
Latitude Lonxlludc
32.07.55N 08SKB.43W
31-29 40N 085:22 06W
3I0401N 087A2.40W
34-12 07N 085:26 45W
33.17.24N 086:21 42W
310102N 085:13 24W
33.50 1SN 0863146W
3052.30N 087:S7.48W
30.50.00N 086:50 00 W
303852N 0812928W
30.23.04N 085.33 24W
30 01 DON 083:46 OOW
295031N 085.17.59W
27.1Z18N 0804728W
27.38 54N 0802410W
3007.38N 085.39.25W
293848N 081 37.32W
300000N 081 40 OOW
3021:30N 0820454W
302800N 083 15 OOW
31:39.10N 081.49.00W
342600N 083 40 30 W
333924N 08440.25W
332837N 084-54 04W
331645N 085 06 OOW
3108.00N 085 04 OOW
3455.00N 08310.00W
34.27.00N 0835730W
320120N 083S630W
305200N 084.36 OOW
3043-37N 081:32.00W
3322.25N 081.S6.35W
3210.30N 081:08:50W
3322.00N 081:56 OOW
31.18 OON 08445.00W
31-08 15N 081.31.35W
SUIc W.urbod} Location
AL Chattahoochee Collomon
AL Choctawhatchee R. Henry Co.
AL Conecuh River E. Brewton
AL Coosa River Slate line
AL Coosa River Coosa Pines
AL Cowarts Creek Houston Co
AL Inland Lake Blounl Co
AL Mobile River near Cold Cr
FL 11 Mile Creek PerdidoBay
FL Amelia River Fcrnandma Bet
FL Econfina Creek Panama Cily
FL Fcnholloway River Perry
FL Gulf Co Canal Si. Joe
FL Lake Okecchobec Okeechobee
FL Main Canal Vero Beach
FL St. Andrew Bay Panama City
FL Si. Johns River Palalka
FL Si. Johns River Green Cv Spr
FL Si. Mary's River Macelenny
FL Wilhlacooche River Blue Spring
GA Allamaha River Jesup
GA Challahoochee R Gainesville
GA Chdllaboochee R. Auslell
GA Chatlahoochce R Whilesburg
GA Chatlahoochee R Franklin
GA Challahoochee R DonaldsonviUe
GA Chaltooga River Clayton
GA Cheslatce River above L Lamer
GA Hint River L BUckshcar
GA Lake Seimnole
GA North River (mouth) Si. Marys
GA Savannah River Augusta
GA Savannah River Savannah
GA Savannah River Augusta
GA Spring Creek Early County
GA Turtle R. (mouth) S Brunswick R
NSQ B
X
X
X
X
X
X
X
POINT SOURCES
NFL Other
PPC PPNC WP Rlny She Ind POTW
X
X
X
X
X X
X
X
X
X X
X
X X
X X
X
X
X
X X
X X
X
X
X X
X
X
X X
X
X X
X XXX
X XX
X
NONPOINT
Urban Agrl
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Additional Site Description
(FacUlllcs In Ihc vicinity of Ihe campling ilk)
Alabama Kraft in AL (goes into GA water but on AL side)
Container Corporation
Kimberly Clark; wooded area, Ag croplands and grazing fields
Several chem & pest plants, Hydro-power
Champion International Corp. in Cantonment; rural; swampland; Ag
croplands
ITT Rayonicr, Inc.
Buckeye Cellulose; rural; swampland, Ag : grazing fields
St. Joe Paper (indirect)
Collected below salinity structure
Southwest Forest Ind., Inc (indued) (Stone Container Corp )
Georgia Pacific Corporation
Wood treatment plant
ITT Rayomer, Inc.: swampland, Ag.: croplands
TownofScboville: heavy melals, wood products, Ag: chicken farms and
orchards
Box Board on Hwy 92
Great Southern Pacific Paper Company
Mining: gold, sand, and gravel, Ag - orchards, dairy farms & chicken
houses
Procter & Gamble (Buckeye Cellulose)
Great Southern Pacific Paper Company
Oilman Paper Company
Federal Paperboard in Pond, Georgia Pacific, Ind pest
Fort Howard Paper (PPC), Union Camp and Stone Container Corp
(PPNC); Nuclear power
Ponderosa Fibers (indirect)
Brunswick Paper & Pulp on the Turtle R , marshland, wooded area, Ag
grazing fields
-------
TABLE D-l (Conl.)
EPA
m
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
IV
£pb«dc
3183
3339
3182
2056
2341
3181
3446
3185
2126
3445
3341
3340
3435
2133
3184
3344
2139
3165
3345
3164
3342
3167
3166
2138
3395
3343
3346
3385
3347
3186
3348
3187
3349
2301
3189
2298
3350
2297
latitude Unilludc
3824-22N 0823&32W
36.S5.41N 089:05 52W
365527N 086:52:47W
3800.30N 085:56-30W
384629N 084:57.52W
38.00.30N 085:56:30W
382422N 082.3S.S2W
302500N 089.04.00W
32.20 SIN 090:51.48W
30.19:32N 088.3 1:OOW
3025:20N 088:31:10W
31.13.28N 08902.50W
312500N 091:30.00W
3229.14N 090 49:02 W
32-28'OON 09049.00W
34.23:SON 078.10.30W
35.40 02N 093:04.23W
34.43 SON 0793924W
35.15 06N 08240-45W
35.56 45N 079.19.20W
34.36:30N 078.59.00W
3550.35N 078.50.20W
35 08 DON 083:38 15W
35.15.29N 077.35.09W
35I1:56N 0770645W
353205N 082.54 40W
3SS1.SSN 076.4S.40W
35.59 25N 081 31-32W
34-4130N 080:5 1:50 W
3245-SON 079 53 10W
332!:24N 079I834W
322946N 080 31 33 W
33.51:08N 080:37.32W
35.29-4SN 0874958W
35.55.37N 084-58- 18W
3S:16:31N 088.58.36W
3S:19:08N 084.48. 13 W
36:00:56N 0834954W
Stale Walcibody Location
KY Big Sandy Catllelsburg
KY Mississippi River Wickuffc
KY Mud River Russellville
KY Ohio River West Point
KY Ohio River MarUand
KY Ohio River Weslpoinl
KY Sandy River Callcllsburg
MS Bernard Bayou Gulfport
MS Big Black River Bovina
MS Chevron Effluent Pascagoula
MS Escatawpa River Moss Point
MS Leaf River New Augusta
MS Mississippi River Natchez
MS Yazoo River Redwood
MS Yazoo River Redwood
NC Cape Fear River Ricgclwood
NC Catlaloocbee Creek Caltaloochee
NC Deep River Ramscur Dam
NC French Broad River Pisgah Forest
NC Haw River Saxapahaw
NC Lumber River Lumberton
NC Medlins Pond Morrisville
NC Nanthalia River Macon Co.
NC Neuse River Kinslon
NC Neuse River New Bern
NC Pigeon River Clyde
NC Roanoke River Plymouth
NC Yadlun River Patterson
SC Catawba River Calawba
SC Charleston Harbor Charleston
SC Sampit River Georgetown
SC Si Helena Sound
SC Waleree River Eastover
TN Buffalo River Flalwoods
TN Ft LoudonRes
TN Hatchie River Bolivar
TN Hiwasee River Calhoun
TN Holston River Knoxville
NSO B
X
X
X
X
X
X
POINT SOURCES
NPL Olhn
PPC PPNC WP Rlor Slli lod POTW
X XX
X
X X
XXX
X X
XXX
XXX
X X
X
X XX
X
X
X
X X
X
X X
X
X X
X X
X
X X
X
X
X X
X
X X
X
XX X
X
X
X
X
X XX
NONPOINT
Urban Airt
X
X
X X
X X
X X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X
X
X
X
Addlttnul Site Description
(FoclUlla la Ihc rtclolli ol Ihc umplhw >ll<)
Ashland Oil Inc.; Ind.: chem,. iron and steel; coal mining, timber
Westvaco Corporation, Ag.: croplands
Ind: metal plating; rendering plant; Ag : croplands
Same as 3181. Ind.: chem. & pest , refinery, Ag.: crops; Superfund site
(PCB's; solvents; dionns & furans)
WilliamcUe Industries; multiple sources; rural
Same as 2056; Ind.: chem. & pest., refinery; Ag.: crops; Superfund sue
(PCB's; solvents; dioans & furans)
Ashland Oil refinery; coal mining
Ind.: chem ; woud treatment; (gas recovery) refinery, rural, Superfund site
(solvents)
Ag: soybeans and cotton
Chevron refinery, International Paper, shipyard; fertilizer company
International Paper Company
Leaf River Forest Products
International Paper Company
Same as 3184, Ind.: paper; fertilizer plant
Same as 2133, Ind: paper; fertilizer plant
Federal Paper Board; rural; swampland; wooded area, Ag . croplands
Champion Paper (PPC-indircct source); wooded area
Ecusla (sulfite mill using chlorine), rural, wooded area, Ag : croplands
Ind : textiles; rural, Ag.: croplands
Alpha Cellulose (sulfile null using chlorine)
Koppers Company (wood treat.), Superfund site wood treat (PCP)
Weyerhaeuser Company
Weyerhaeuser Company
Champion International in Canton, rural, wooded area, Ag : croplands
Weyerhaeuser Company on Welch Creek; rural; wooded area; Ag :
croplands
Scaled Air Corporation (makes absorbent paper for meat trays)
Bowaler Carolina; rural; wooded area, Ag : croplands
Westvdcu Paper and Pulp; Amoco chemical plant
International Paper Company, rural, wooded arcj, Ag . croplands
Union Camp Corporation; rural; wooded area, Ag : croplands
Ind.: aluminum
Bowaler South Paper Company, rural; wooded area; Ag ; croplands
Industry: metals
-------
TABLE D-l (Conl.)
EPA
RCR
IV
IV
IV
IV
IV
IV
IV
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
*
3403
3444
3188
3404
3351
3190
3401
2379
2383
3113
2380
3114
3115
3117
2059
3356
2060
2057
3119
3118
1994
3120
3122
1998
3148
2432
2410
2431
2430
2435
2387
3112
3125
2385
3001
2416
2394
2439
Ulllixte Lontflud*
36:33:02N 082.3SK»W
35.05:15N 090.05.30W
350354N 08520.28W
36.01.20N 08312-OOW
35:56 24N 083-10.52W
35.50.15N 08404-13W
35.03.S4N 086:16:39W
37.37.31N 089.2S:42W
413547N 088.04:07W
41.52 13N 088.18 31W
41:19 40N 088.45: 10 W
39.43.00N 091:31.04W
3832:30N 090-1S:OOW
42.21:10N 087 49 40 W
41:37.10N 087.29:15W
41-37.10N 087:29 15W
38 07 SON 087.S6.20W
38.30.45N 087.17.30W
42:33 OON 085.54:OOW
4S.SO.OON 087 05 00 W
43.03 OON 08348'45W
4239.00N 082:10.00W
45:47 OON 087.59.00W
43.15.O5N 086.14 55W
43.15.0SN 086.14.55W
43.1957N 086-08 42W
42.16.45N 083:07.20W
46:29 4SN 084.22.25W
46:34.30N 085.15.10W
47:55 23N 089.08.42W
44-16 08N 093.21 05W
45:5&17N 094-22.05W
44:33.34N 092.25.47W
48:36-29N 093-24 13W
48-35 29N 092.53:34W
41.29:50N 081.42 10W
39:33.44N 084:18.19W
3%15:S3N 084.40:30W
Suic WXclbodT Locilton
TN HoUtonR..S Fork Kingsport
TN Mississippi River Nonconnah Cr.
TN Nickajack Reservoir
TN Pigeon River Newport
TN Pigeon River Newport
TN Tennessee River Knoxville
TN Tennessee River Hardm Co.
IL Big Muddy River Grand Tower
IL Des Plaines River Lockport
IL Fox River Geneva
IL Illinois River Marseilles
IL Mississippi River Quincy
IL Monsanto Effluent East Si Louis
IL Lake Michigan Waukegan
IN Indiana Harbor Can East Chicago
IN Indiana Harbor Can East Chicago
IN Wabash River New Harmony
IN While River Petersburg
Ml Allegan Lake Allegan
Ml Escanaba River Escandba
Ml Flint River Flushing
Ml Kalamazoo River Saugaluck
Ml Menominee River Quinnesec
Ml Muskegon Lake Muskegon
MI Muskegon Lake Muskegon
Ml Muskegon River Bridglon
Ml Rouge River River Rouge
MI Si Marys River Saull Si Marie
Ml Tahquamenon R Paradise
Ml Washington Creek Isle Royale
MN Cannon Lake Fairbaull
MN Mississippi River Lilllc Falls
MN Mississippi River Red Wing
MN Rainy River Inlern'l Falls
MN Rainy River Inlern'l Falls
OH Cuyahoga River Cleveland
OH Great Miami River Frankbn
OH Great Miami River Nw. Baltimore
NSQ B
X
X
X
X
X
X
X
X
POINT SOURCES
NPL Olb.r
PPC PPNC WP Rftij Site Ind POTW
X
X XX
X X
X
X
X
X
X
X XX
X X
X XX
X X
X X
X X
X X X X
X X X X
X X
X X
X X
X
X X
X
X
X XXX
X XXX
X
X X
X XX
X
X
X XX
X X
X
X X
X XX
X XX
NONPOIN1
Ultun Aftrt
X
X
X
X
X
X
X
X X
X X
X
X
X
X
X
X X
X
X
X
X
X
X X
X
X
X
Additional Site Description
(FucUllto In the vicinity or Ibe umpllng lib)
Mead Corporation (Chlorine Dioxide process)
Mapco, Eraon, Union refineries; cement factory, soybean processing
Ind., chem., coke, rendering; railyards; landfill
Champion International in North Carolina
Champion International in North Carolina
Tcnnesce River Pulp and Paper in Counce, TN
Ind ; organic chem. &. pest.; Refineries (downstream); steel; incinerator
Ind.; chem. & pest.; Union oil, Texaco, Mobil; Ammunition plant
Celolex Corporation (deinking)
Six chemical/pharmaceutical plants (paradichlorobenzene)
Open lake sample; Supcrfund site (PCB) at Waukegan Harbor
Same as 2059; Amoco Oil; Ind : primarily steel; waslewater; Superfund site
(PCB)
Same as 3356; Amoco Oil; Ind.: primarily steel; waslewater; Superfund site
(PCB)
Ind : chem. & pest.; coal mining; (site at the mouth of the Wabash R )
Hydro-power; coal mining
Historical PCB conlaminalon from paper deinking; Superfund site (PCB)
Mead Corporation (historical PCB contamination)
Automobile manufacturing (heavy metals and oils)
Historical PCB contamination site is downstream of Kalamazoo
Champion International Corporation
Scott Paper (indirect); Power & chem plant, Ag orcb.; same as 3148,
Superfund site (PCB)
Scotl Paper (indirect); Power & chem. plant; Ag . orch ; same as 1998,
Superfund site (PCB)
Far upstream of bleachkraft (Scotl Paper Company)
Ind . heavy steel, chem.; automobile (PCB's in effluent)
Si Mary's Paper; Algoma Steel, dredging
Cdnadian Bleach Kraft P&P mill jboul 30 miles upwind in Thunder Bay,
Onl
Henncpm Paper
Ashland Oil/Koch Refining; urban runoff, historical PCB contamination
Boise Cascade on both sides of the nver
Site is above the dam. Boise Cascade outfall is below dam
Ind. chem; oil,
Applelon Papers and Miami Papers (deinking); Ind . metals and others
Sorg P&P null (deinking); Proctor and Gamble, Ag runoff, Superfund site
-------
TABLE D-l (Conl.)
EP/
**
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
V
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
tpbodc
2618
3132
3135
3136
3137
2429
3138
3140
3143
3144
2422
3134
3141
2427
3142
3110
2397
2608
3106
3107
3108
3109
3145
3146
2023
3060
3062
3061
3078
3443
2015
21)18
3073
2016
3452
3077
2017
3088
3083
Ijillluib Lonxlludt
39.24 40N 084:33:14W
39.1736N 083.55 48W
44.49 39N 091 30.38W
45240SN 091.13.18W
45:55.00N 090 26-41 W
4427.39N 088.03:30W
44 16.10N 088.22 18W
441324N 0882734W
44-00 43N 088-31 OOW
43.32-17N 089:27 36 W
46-30.21 N 090:52.30W
44.01 58N 088.08-45W
400326N 08753.54W
450316N 087.44 SOW
4343.51N 0874704W
4458.00N 09246.00W
453727N 0892514W
44-1600N 0895300W
44 16 (ION 089.53 OOW
45.01 20N 0893909W
45.10 31N 089.40 OOW
445657N 08937.45W
452617N 08843.56W
44S257N 089.38 17W
3520.56N 09417.54W
34.26 41N 09206.38W
34.lO.09N 091.43 56W
331118N 0924153W
34S0.39N 09207.20W
340900N 09131 «IW
333327N 091 14 15W
35 59 4 W (N2 1245W
355633N 09207.05W
333307N 09402.28W
341500N 094.06 OOW
33S7.17N 094.21:49W
33.14 32N 093.59:58W
30.53 DON 093.25-OOW
324000N 09143.00W
Suit Mfelcifcody Lnollon
OH Hamilton Canal Hamilton
OH Sciolo River Chillicothe
Wl Chippewa River Eau Claire
Wl Flambeau River E Ladysmilh
Wl Flambeau River Park Falls
Wl Fox River DePere Dam
Wl Fox River Applelon
Wl Fox River Lk ButleD Moris
Wl Fox River Oshkosh
Wl Fox River, upper Portage
Wl Lake Superior Ashland
Wl Manitowoc River Chillon
Wl Milwaukee River Milwaukee
Wl PcshtigoR Harbor Pcshtigo
Wl Shcboygan River Kohlcr
Wl SI Croix River Hudson
Wl Wise R/Boom Lake Rhmelander
Wl Wisconsin River U PenlcnweU Fl
Wl Wisconsin River U Pentcnwcll Fl
Wl Wisconsin River Brokaw
Wl Wisconsin River Merrill
Wl Wisconsin River Wausau
Wl Wisconsin River Mohawskin
Wl Wisconsin River Rothschild
AR Arkansas River Van Buren
AR Arkansas River Little Rock
AR Arkansas River Pine Bluff
AR Bayou DeLoulre El Dorado
AR Bayou Melo Jacksonville
AR Bayou Melo Reydcll
AR Mississippi River Arkansas ( ily
AR N Sylamnrc Creek Fifty Six
AR N Sylamore Creek Fifty Six
AR Red River Index
AR Red River Index
AR Rolling Fork River De Queen
AR Sulphur River Texarkana
LA Anacoco Bayou Dendder
LA Bayou Bonne Idee Oak Ridge
NSQ B
X
X
X
X
X
X
X
POINI SOUHCES
NFL Olhcr
PPC PPNC WP Rlnr Site Ind POTW
X X
X XX
X
X
X X
X XX
X X
X
X
X X
X
X X
X X
X X
X X
X
X XX
X XX
X
X
X X
X
X
X X
X X
X X
X X
X
X X
X
X X
X X
X
X
X
NONPOINT
Urban Agri
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Addlllanil Sllc Description
(FicUllla la Ihe >lclnlty of Ihc umpllng tilt)
Canal off G Miami R ; Appleton Paper; Aviation plant; steel;
hydro-power; Superfund site
Mead Corporation on Paint Creek; Ind . inorg chem & pest , Supcrfund
site
Pope and Talbot (demking)
Pope and Talbot (deinking)
Flambeau Paper, Ag croplands and grazing fields
Fort Howard, James River, Green Bay Pkg , Nicolel Paper, Champion
Kerwin Paper Company (deinking), Gladlfelder, Wl Tissue, Kimberly Clark
Gladtfelder, Wl Tissue Mills, Kerwin Paper (historical PCB contamination)
Ponderosa (deinking)
Historical PCB contamination
James River-Dune Northern (deinking), rural
Incinerator, H2O softener plant, Ag : croplands
Ind : melals (historical PCB contamination); 300-400 Industrial discharges
Badger Paper Mills, (indirect)
Supcrfund site (historical PCB contamination)
Anderson Windows; wood treatment plant
Upstream of paper mills
Nekoosa, Fort Edwards, Consolidated Kraft, Vulcan mat (rubber &
plastic), same as 3 106
Nekoosa, Fort Edwards, Consolidated Kraft, Vulcan mat (rubber &
plastic), same as 2608
Wausau Paper (sulfitc mill)
Ward Paper (deinking)
Wood treatment plant site is between paper mills
Rhmelander Paper Company
Weyerhaeuser, half dozen small mills, Ag croplands
International Paper Company, wooded area, Ag croplands
Lion Oil Company
Superfund site (dioxins), rural, wooded area
Downstream about 30 miles of the Jacksonville site (3078)
Pollalch Corporation, Ag croplands
bami. as 3071
Same as 2018
Nekoosa Edwards Paper Company
Nekoosa Paper; lime and gravel mines, Ag crop and grazing lands
Wood treatment plant on Bear Creek
International Paper Company in Texas
Boise Southern Co (Boise Cascade), rural, Ag . cropland
HCB use in agriculture
-------
TABLE D-l (Conl.)
ETA
fen
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VI
VII
VII
VII
VII
*
3086
3442
3353
3063
3092
33S2
3064
3082
2S32
3065
3066
3418
3416
3080
2S44
3087
3425
3074
3105
3090
3079
2027
3076
3091
2026
3089
3084
3085
3068
3069
3081
2280
3075
3093
3070
3072
3071
2283
3035
3037
3038
3034
Lolllude Longitude
3ftl2.00N 093:17:OOW
3ft02.36N 09ft22:27W
323100N 091.54:OOW
30 05 DON 093.20.00W
32:05.00N 092.47:OOW
32:33 DON 091-51:OOW
3002.00N 090.02.00W
32.49 DON 091.11:OOW
3045:30N 091:23'45W
302700N 091:13.00W
300600N 091K)1.00W
30.39 DON 091:17.00W
33.00 DON 092:04.00W
32:27 DON 092'07:OOW
30.30.23N 090.21:42W
32 35 DON 091:56 OOW
3233.00N 091:55.00W
35.46 38N 105.39.27W
351342N 09831.35W
36 04 DON 095.16.00W
36S200N 096.56:OOW
343818N 094.36 45W
33'5700N 094 35 OOW
3356-OON 095 07 OOW
341403N 096.58.32W
354100N 095-14 OOW
261142N 097.36.06W
285859N 095.23 41W
2940-48N 09458.50W
27.50 30N 097.30 20W
31:25.58N 0943356W
2857.3SN 09641.13W
28-09.00N 096-52 OOW
31 08 (KIN 0944839W
293V30N 093 54 OOW
31:05:OON 105.36 OOW
29:14.15N 098.21.43W
30.S4.41N 098.02.12W
42.03 54N 09147:48W
41.40 57N 093 40 08 W
4I33.02N 093.31 29W
41.34:53N 090.23.23W
Suit W.urtxxly Loullon
LA Bayou D'lnde Sulfur
LA Bayou Labarcbc Norco
LA Bayou LaFourche Bastrop
LA Calcasieu River Moss Lake
LA Dugdemona River Hodge
LA Lake Irwm Start
LA Lake Ponlcharlrian New Orleans
LA Lake Providence
LA Mississippi River St Francisville
LA Mississippi River Baton Rouge
LA Mississippi River Union
LA Mississippi River Zachary
LA Ouachila River Slcrhngton
LA Ouachila River Monroe
LA Tangipahoe River Robert
LA Whdm Brake Swarlz
LA Wham Brake Swarlz
NM Rio Mora Terrero
OK Fort Cobb Reservoir Fort Cobb
OK Fort Gibson Res Pyrer Creek
OK Haw Reservoir
OK Kiamichi River Big Cedar
OK Little River Goodwaler
OK Red River
OK Washita River Durwood
OK Webbers Falls Muskogce
TX Arroyo Colorado Harlingcn
TX Brazos River Freeport
TX Houston Ship Chnl Morgan Point
TX Inner Harbor Corpus Chrisli
TX Lake Sam Rayburn Lufkin
TX Lavaca River Edna
TX Mesquite Bay
TX Neches River Diboll
TX Ncchcs River (lidal) Port Arthur
TX Rio Grande River El Paso
TX San Antonio River San Antonio
TX So Fork Rocky Cr. Briggs
IA Cedar River Palo
IA DCS Moines River Des Momes
IA Des Moines River Des Moines
IA Mississippi River Le Claire
NSQ B
X
X
X
X
X
X
X
X
POINT SOURCES
NFL Olber
PPC PPNC WP Rfni Site lad POTW
X
X X
X X
X XX
X
X X
X
X XX
X
X
X
X X
X
X
X
X
X
X
X X
X X
X
X XXX
X XX
X X
X X
X XX
X X
X XX
X
X X
X X
X
NONPOINT
Ultra Agri
X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X X
X X
X
X
X X
AddlUoul SIU Dacrlplloa
(Facllllk* In Iht vicinity of Ihe umpllng die)
Cilgo Petroleum Corporation, Ind.: chem
Shell and Norco Refineries; Shell chemical plant
International Paper Company, rural
Conoco, Inc.; Ind : chem.
Above Bayou LaFourche This dammed water feeds Wham Brake.
HCB use in agriculture
Crown Zellerbach
Georgia Pacific Corporation, Crown Zellerbach; two refineries
Ind: multiple sources; Ag : cropland and grazing
Georgia Pacific and James Madison Paper; rural; wooded area
Georgia Pacific and International Paper; rural; wooded area
Georgia Pacific in Arkansas; Ag crop and grazing lands
Same as 3452, International Paper Co. (discharges to B. LaFourche)
Same as 3087, International Paper Co. (discharges to B. LaFourche)
Ag : croplands, golf course near Ihe site
Robell Tissue Mills
Vulcan Plant in Wichita, Kansas (chemical processing plant)
Heavily wooded area; Ag : cattle
Wood treatment: Thompson Lumber, Hoffman Preserver, Nixon Bros
Preserver
Weyerhaeuser Company
Kerr McGee Refining Corporation, Total Petroleum, Inc.
Fort Howard Paper Company
HCB use
At Dow Chemical outfall
Champion International and Simpson Paper; four refineries, Ag , croplands
Four refineries
Champion International Corporation on the Angelina River
Tcmple-Easlcx, Inc in Diboll jnd Borden Chemical (ruin)
Temple-Eastex, Inc in Silsbcc, TX, two refineries, Ind.: chem & pcsi
Chevron USA, Inc , El Paso Refining Company
Howell Hydrocarbons
Background sue
About SO miles downstream of Waterloo
Upstream about 10 miles from a POTW
Below POTW (prelreatment plant)
Upstream of lock and dam at Davenport (above dam)
-------
TABLE D-l (Conl.)
tPA
"»
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VII
VIII
VIII
VIM
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
VIII
IX
IX
IX
IX
£pkod.
*
2191
2190
3036
2194
3039
2201
3040
3047
3048
3049
3045
2199
3044
3046
3050
3042
31)43
3041
2205
3197
3198
3200
3236
3237
3235
3234
2122
2105
2100
3111
2109
3199
2111)
3195
3196
2098
3266
3282
3288
3285
LBIHudc Longitude
41.15 32N 095S5.20W
403607N 095.38 44W
403607N 095.38 44W
3732.34N 097 1629W
373235N 0971629W
360230N 090 07 30 W
360230N 090.07 30W
3942.36N 091-21 06W
3852.33N 090 10.26W
37I746N 089 30 56 W
390752N 09427.58W
39-11.14N 093.53 45W
394432N 094.51.36W
3911:14N 093.53 45W
37.59.1SN 09348.45W
41 15.32N 09S 55:20W
410818N 0955240W
414542N 103.25 02W
405948N 09601 18W
383300N 1060100W
39 48- ION 104S730W
401030N 104.59 OOW
461000N 1 12.46 26W
470105N 1142120W
454535N 11I0504W
4756 I4N 1141104W
454748N 1082812W
473525N 1031505W
490030N 0971240W
490030N 097.12 40W
424942N 0963345W
424945N 0963315W
440049N UI34948W
40-45. ION 11155.15W
41.20.40N 1053545W
42.34-27N 106 41:31 W
3305.00N 113 02 OOW
331200N 115.37.00W
3641.00N 121 44 OOW
334600N 118 08 OOW
SUIt Wilcitody London
I A Missouri River Council Bluffs
IA Nishndbolna River Hamburg
IA Nishnabofna River Hamburg
KS Arkansas River Derby
KS Arkansas River Derby
MO Litlle River Ditch 81 Hornersnlle
MO Little River Ditch 81 Hornersville
MO Mississippi River Hannibal
MO Mississippi River Wesl Allon
MO Mississippi River Cape Giradcau
MO Missouri River Kansas City
MO Missouri River Lexington
MO Missouri River Si Joseph
MO Missouri River Lexington
MO Osage River Roscoc
NE Missouri River Omaha
NE Missouri River Bdlcvuc
NE North Plalle River Mcgrcw
NE Plalte River Louisville
CO Arkansas River Salida
CO South Plane River Denver
CO SI Vrian River Longmunl
MT Clark Fork River Warm Springs
MT Clark Fork River Huson
MT East Gdllalm River Bozcman
MT Goose Bay Lakeside
MT Yellowstone River Billings
ND Lilllc Missouri R Wai ford City
ND Red River Pimhina
ND Red River Pemhma
SD Big Sioux River Akron
SO Big Sioux River Akron
SD Castle Creek IlillCn,
UT Jordan River Salt Lake City
WY Laramie River Laramie
WY North Pldtte River Alcova
AZ GJa River Gila Bend
CA Alamo River Calipatna
CA Blanco Drain Salinas
CA Colorado Lagoon Long Beach
NMJ B
X
X
X
X
X
X
X
X
X
X
X
X
X
POINT SOURCES
NPL Olbcr
PPC PPNC WP Rfny SIU Ind POTW
X X
X
X
X X
X X
X X
X X
X X
X X
X X
X
X X
X
X X
X X
X
X
X
X
X X
X
X
X
X
X
X X
X X
X X
X X
X X
X
X X
X
X
NONPOINT
UlbMl Agrl
X
X
X
X
X
X
X
X X
X
X X
X
X X
X X
X
X
X
X
X
X
X
X
X X
X X
X X
X X
X
X
X
Additional Silts Description
(FMllllto In in. vklnlly otlhc sampling tilt)
Ind : chem and pesl ; metals, hydro-power, same as 3042-opposite sides of
river
Same as 3036
Same as 2190
Same as 3039. Below Wichita
Same as 2194. Below Wichita
Same as 3040. Rice growing region
Same as 2201 Rice growing region, heavy pesticide use
Fish collected near downtown area
Ind : chem. ; heavy melals; heavy shipping traffic
Collected at POTW outfall Proctor & Gamble paper products, Ag
croplands
Same as 3046
Same as 2199
Ag: croplands
Ind : chem and pest., metals, hydro power, same as 2191 - opposite sides
of river
Defunct wood treatment plant
Stone Container Corporation
Sugar bcel processing plant, croplands. Same as 3 1 1 1
Sugar bcel processing plant, croplands, Same as 2100
Same as 3199
Same as 2109
Ind pesticides, Superfund site (chlorobenzencs)
Railroad tic treating plant (defunct)
Cotton growing region (Near Phoenix)
HCB use in agriculture
Multiple sources
Multiple sources
-------
KJ
TABLE D-l (Conl.)
ffl
l
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
IX
X
X
X
X
X
X
X
X
X
X
X
X
X
X
LplMldc
0
3273
3286
3271
3272
3275
3276
3289
3451
3354
3283
3355
3290
3274
3357
3267
3270
3287
2748
3281
3264
3450
3269
3278
2037
3261
3262
2776
3238
3241
3246
2070
3244
3245
3212
3250
3249
3158
2478
3256
3248
3203
Latitude Longitude
41.45.00N 124-11KWW
3340.00N US' 18 OOW
4034.00N 123'1100W
37 55 DON 122'21:OOW
405400N 1240000W
40S2.00N 124.00 OOW
364800N 121 46 OOW
34 01 DON 11841.00W
37 57 DON 12118.00W
330600N 115 40 OOW
37.56 OON 121.19 OOW
39 58 DON 121 20 OOW
41S5.00N 124.07.00W
38 02 OON 121 44 OOW
40 27 OON 122 11 OOW
40 09 OON 122 11 OOW
33 46 OON 118 06 OOW
34 24 OON 119 30 OOW
3420.00N 119 04 OOW
335427N 118.31.28W
3355-OON 11828:OOW
37 43 OON 121 09 OOW
39 24 OON 123 06 OOW
19 46 15N 155 05 33W
21 18 OON 157 59 OOW
220430N 15922:30W
35 40 OON 114 40 OOW
605830N 14927.35W
61 1320N 14951.21W
57 03 OON 13314.00W
613242N I513045W
58 41 OON 134 03 OOW
552345N 13I4420W
434829N 1170015W
47.38.05N 1164315W
4733-07N 1I622.06W
423725N 11431.58W
430008N 1151206W
4625-15N 1 17.02 04W
4719.08N 11633.35W
4537.19N 1224520W
Stale Walcrbodj Location
CA Elk Creek Cresceni Cily
CA Harbor Park Uke Harbor Cily
CA Hayfork Creek Hayfork
CA Laurilzen Canal Richmond
CA Mad River Arcala
CA Mad River Slough Arcala
CA Moss Landing Dm Moss Landing
CA MoulhofMalibiiCr Mahbu
CA New Mormon Sigh Stockton
CA New River Westmoreland
CA Old Mormon Slough Stockton
CA Port of Stockton Stockton
CA Rowdy Creek Smith River
CA Sacramento Delta Antioch
CA Sacramento River Anderson
CA Sacramento River Red Bluff
CA San Gabriel River Long Beach
CA Santa Clara River Santa Paula
CA Santa Clara River Santa Pdula
CA Santa Monica Bay Los Angeles
CA Short Bank (Pac O ) Los Angeles
CA Stanislaus River Ripun
CA Upper Eel River Potter Valley
HI Honohi Stream Hilo
HI Pearl Harbor Middle Loch
HI Wailua Faelekaa Si Kauai
NV Colorado River Blw Hoover Dn
AK Bird Creek Bird
AK Ship Creek Anchorage
AK Silver Bay Silica
AK Susilna River Susilna
AK Vandcrbill Creek Juncau
AK Ward Cove Kclclukan
ID Boise River Pjrma
ID Coeui d'Alene Lake Coeurd'Alene
ID Coeur d'Alene River Coeur d'Alene
ID Rock Creek Twin Falls
ID Snake River Kings Hill
ID Snake River Lewiston
ID St Joe River Si Mane
OR Columbia River Portland
NSQ B
X
X
X
X
X
X
X
X
POINT SOURCES
NFL Giber
PPC PPNC WP Rfny Site lad POTW
X
X
X
X
X
X
X XX
X
* XX
X XX
X X
X
X
X
X XX
X
X
X
X X
X
X
X
X
X
X
X
X
NONPOINT
Uiba Ajtrl
X
X X
X X
X
X
X
X
X
X
X X
X
X
X
X
X
X
Additional SUe Description
(Faculties In Ihe riclnllj of the umpllng »lle)
McNamara & Peepe (historical PCP site)
Multiple sources
Sierra Pacific (historical PCP site)
United Heckathorn- pesticide packaging plant in 60's (PCB's, DDT, Pb)
Mollala-Arcala
Sierra Pacific
Multiple sources
POTW: Tapia Creek, grazing land (horses)
McCormick and Baxter (wood preservers); Superfund site (solvents)
Multiple sources (HCB use)
McCormick & Baxter (wood preservers), Ag.. croplands & orch ,
Superfund site (solvents)
McCormick &. Baxter (wood preservers), Superfund site (solvents)
Arcala Lumber Company (historical PCP site)
Gaylord Container Corp.; Ind . chem.; refinery, power plant, Ag
orchards and croplands
Simpson Paper Company, wooded area
Diamond International (recycled paper); Ag . croplands and grazing
Simpson Paper Company, Pacific Coast Paper
Same as 3281
Same as 2748
El Scgundo Refinery, Hyperion POTW outfall, multiple sources
POTW Hyperion outfall
Multiple sources
Louisiana Pacific (historical PCP sue)
Ag . sugar cane growing (pesticides)
Combustion sources, Superfund site (solvents)
Agent Orange test site (not a designated superfund site) -
Salvage yard with runoff of PCB, Superfund site, landfill
Alaska Pulp Company
Louisiana Pacific Corp (sulfilc null), Kclchikan Pulp and Paper
Ind silver mining
Mining
Potlatch Corporation
-------
TABLE D-l (Conl.)
ETA
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Episode
3216
3218
3219
3201
3208
3212
3205
3215
3206
3217
3213
3437
3226
3438
3220
3221
3222
3439
3440
3441
3163
3191
3192
3162
3227
3295
3294
2247
2246
3223
3224
3230
3231
45:S1.53N 122:47:39W
46:09 21N 123.24:OOW
45:39. ION 12056:OOW
45:36 06N 122.43.57W
44.03 30N 116.57.00W
43:46 59N 1 17.03 09W
452&33N 123.M.07W
45-23:40N 1224S.30W
45:34.S3N 12244.39W
44.23: 16N 123'14:03W
451717N 122.58.03W
45:17.38N 1224608W
472330N 122:37.38W
461536N 1235757W
225927N 046.07.SOW
46.06 OON 1185500W
453408N 122.24 42W
46.1506N 123-33.32W
460033N 12251:04W
45:58.05N 12249.19W
47.16 12N 122.25:50W
46-58 OON 123.53 OOW
46:57. 13N 123SM5W
47:17.05N 1 22:24:28 W
47:14 20N 123.02.40W
48.08.00N 1232445W
4806.30N 122.45.30W
47.12.52N 122:20 25W
47:49 52N 12202'50W
480152N 122.13 OOW
484501N 122.29 02W
47:11:10N 120.02:30W
46.22.42N 119:25.29W
OR Columbia River Si. Helens
OR Columbia River Wauna
OR Columbia River Dalles
OR Columbia Slough Portland
OR Malheur River Ontario
OR Owyhee River Owybee
OR Tualatin River Cherry Grove
OR Tualatin River Cook Park
OR Willamette River Portland
OR Willamette River Hallsey
OR Willamette River Newburgh Pool
OR Willamette River Wilsonvillc
WA Burley Lagoon Purdy
WA Columbia R (lower) Estuary
WA Columbia River Longview
WA Columbia River Tn Cities
WA Columbia River Camas
WA Columbia River Woody Island
WA Columbia River Kalama
WA Columbia River Deer Island
WA Commencement Bay Tacoma
WA Grays Harbor Hoquiam
WA Grays Harbor Cosmopolis
WA Hylebos Waterway Tacoma
WA Oakland Bay Shelton
WA Port Angeles Harbor Port Angeles
WA PortTownsend Port Townsend
WA Puyallup River Puyallup
WA Snohomish Monroe
WA Steamboat Slough Everett
WA Whaicom Waterway Bcllmgham
WA Yakima River Cle Blum
WA Yakima River Ricbland
NSQ B
X
X
X
X
POINT SOURCES
NPL Other
PPC PPNC WP Rfn? Silt Ind POTW
X XX
X
X X
X X
X X
X X
X
X X
X
X
X
X
X
X X
X X
X X
X X X X X
X
X
X XX
X
X X
X
X
X
X X
X
X
NONP01NT
Urban Atrl
X X
X
X
X
X
X
X
X X
X
X
X
X
X
X
X
X
X X
X
X
X
X
X X
Additional Sue Dacrlplioo
(FacUIUei la Ihe riclnll) ( be urapllnx ille)
Boise Cascade (indirect)
James River Corporation in Clatskanie
Hydro-power (PCB's generated); food processing plant; Ag . orcb &
croplands
Five paper mills using Cl bleach, two paper mills not using Cl bleach,
shipyard
Minor industries; Ag.: croplands
Ind :' chem.; smelters; shipyards; timber
Hallsey Pulp Company (Pope and Talbot); Ag.: croplands
Dcinking plant; other pulp mills upstream; Ag.. croplands
Below transformer and scrap metal salvage yard, below Superfund site
(PCB)
Weyerhaeuser and Longview Fiber Company, Ag croplands & gracing
fields
Boise Cascade; Ag.. croplands & grazing fields
Crown Zellerbach (James River Corporation)
Boise Cascade and Weyerhaueser, Longview Fiber downstream
Boise Cascade and Weyerhaueser, Longview Fiber downstream
Boise Cascade and Weyerhaueser, Longview Fiber downstream
Simpson Tacoma Kraft, US Oil and Refining, heavily industrialized.
Superfund site (Commencement Bay)
ITT Rayonier, Inc. (sulflte mill, nonchlorme)
Weyerhaeuser Company (suliile mill, chlorine)
Champion Paper Company, heavily industrialized; Superfund site
Simpson Pulp Mill (wood overlay products)
ITT Rayonier, Inc.
Simpson Paper Company (downstream)
Light agriculture, limber
Weyerhaeuser Company and Scoll Paper Company; Superfund site
(solvents)
Georgia Pacific (sulfite process)
-------
APPENDIX D-2
Dioxins/Furans: Episode Numbers Used in Statistical Tests
(By Category)
-------
TABLE D-2
Dioxins/Furans: Episode Numbers Used in Statistical Tests (By Category)
NASQAN (NSQ)
Episode
2015
2016
2017
2023
2026
**\J£*\J
2070
2098
2105
2122
2126
2148
2151
2152
2191
2205
2220
2228
2246
2247
2280
2298
2309
2322
2358
2430
2431
2432
2437
2439
2478
2544
2776
3036
3041
3042
State
AR
AR
AR
AR
OK
X^AX
AK
WY
ND
MT
MS
FL
FL
FL
IA
NE
VA
VA
WA
WA
TX
TN
AL
NY
ME
MI
MI
MI
MN
OH
ID
LA
NV
IA
NE
NE
3050
3104
3199
3281
3308
Total
MO
PA
SD
CA
NY
40
AGRICULTURE (AG)
Episode
2280
2358
2478
3050
3082
3083
3084
3099
3105
3158
3170
3171
3180
3193
3208
3212
3282
3352
3437
Total
SUPERFUND
Episode
3078
3097
3226
3261
3272
State
TX
ME
ID
MO
LA
LA
TX
DE
OK
ID
AL
AL
GA
VA
OR
OR
CA
LA
OR
19
(NPL)
State
AR
DE
WA
HI
CA
3414
3415
Total
POTW
Episode
2122
2152
2205
2322
2432
2544
3036
3041
3308
3450
3451
Total
BACKGROUND
Episode
2027
2037
2110
2139
2216
2283
2301
2379
2387
2397
2435
2651
3001
3022
3023
3027
PA
PA
7
State
MT
FL
NE
NY
MI
LA
LA
NE
NY
CA
CA
11
(B)
State
OK
HI
SD
NC
PA
TX
TN
IL
MN
WI
MI
NJ
MN
ME
ME
ME
D-2-1
-------
TABLE D-2 (Cont.)
3028
3037
3073
3074
3075
3166
3169
3178
3179
3187
3200
3205
3230
3238
3248
3309
3320
3430
Total
PULP & PAPER
(Chlorine) (PPQ
Episode
2015
2016
2017
2138
2142
2228
2294
2302
2304
2355
2385
2422
2427
2532
2721
ME
IA
AR
NM
TX
NC
AL
GA
GA
SC
CO
OR
WA
AK
ID
NY
NY
NJ
34
State
AR
AR
AR
NC
FL
VA
GA
AL
AL
ME
MN
WI
WI
LA
ME
2725
3062
3080
3081
3088
3107
3118
3122
3146
3150
3151
3152
3192
3217
3218
3220
3221
3222
3224
3237
3245
3246
3256
3260
3267
3303
3316
3317
3318
3328
3329
3331
3332
3333
3335
3336
3337
3339
ME
AR
LA
TX
LA
WI
MI
MI
WI
MA
MA
NH
WA
OR
OR
WA
WA
WA
WA
MT
AK
AK
ID
NY
CA
NY
PA
MD
PA
AL
FL
FL
FL
FL
GA
GA
GA
KY
3340
3341
3342
3343
3344
3345
3346
3347
3348
3349
3350
3351
3353
3395
3403
3404
3416
3418
3420
3421
3422
3423
3424
3425
3435
3452
Total
INDUSTRY/URBAN
(IND/URB)
MS
MS
NC
NC
NC
NC
NC
SC
SC
SC
TN
TN
LA
NC
TN
TN
LA
LA
PA
VA
VA
VA
VA
LA
MS
AR
79
Episode State
1994
2023
2026
2057
2060
2191
2210
MI
AR
OK
IN
IN
IA
DC
D-2-2
-------
TABLE D-2 (Cont.)
2215
2220
2225
2227
2309
2328
2329
2380
2383
2410
2416
2500
3024
3025
3026
3034
3035
3038
3039
3040
3042
3043
3044
3045
3046
3047
3048
3049
3060
3061
3063
3064
3066
3069
3071
3072
3079
3085
PA
VA
VA
VA
AL
NY
NY
IL
IL
MI
OH
WV
ME
ME
ME
IA
IA
IA
KS
MO
NE
NE
MO
MO
MO
MO
MO
MO
AR
AR
LA
LA
LA
TX
TX
TX
OK
TX
3086
3094
3095
3096
3100
3101
3103
3111
3113
3115
3120
3125
3134
3141
3144
3147
3149
3164
3165
3168
3172
3174
3182
3183
3186
3188
3189
3190
3198
3199
3203
3206
3219
3227
3231
3234
3235
3236
LA
PA
PA
PA
MD
PA
MD
ND
IL
IL
MI
MN
WI
WI
WI
DC
DE
NC
NC
AL
AL
FL
KY
KY
SC
TN
TN
TN
CO
SD
OR
OR
OR
WA
WA
MT
MT
MT
3244
3249
3250
3252
3258
3264
3269
3275
3276
3283
3285
3286
3289
3296
3297
3298
3299
3300
3301
3302
3306
3307
3310
3311
3312
3313
3314
3315
3321
3322
3324
3326
3327
3411
3412
3426
3428
3431
AK
ID
ID
ID
VA
CA
CA
CA
CA
CA
CA
CA
CA
NY
NY
NY
NY
NY
NY
NY
NY
NY
PA
WV
WV
WV
WV
PA
NY
NY
NY
NY
NY
NY
NY
NJ
NJ
PR
D-2-3
-------
TABLE D-2 (Cont.)
3432 PR
3434 NJ
3438 WA
3442 LA
3443 AR
3444 TN
3446 KY
Total 128
PULP & PAPER
(No Chlorine) (PPNC)
Episode State
3089 OK
3090 OK
3091 OK
3092 LA
3093 TX
3108 WI
3112 MN
3114 IL
3135 WI
3136 WI
3137 WI
3138 WI
3140 WI
3143 WI
3145 WI
3184 MS
3191 WA
3270 CA
3287 CA
3294 WA
3330 FL
3360 AL
3375 GA
3376 GA
3377 GA
3378 GA
3401 TN
Total 27
WOOD PRESERVERS
(WP)
Episode State
3076 OK
3077 AR
3110 WI
3167 NC
3173 FL
3196 WY
3197 CO
3271 CA
3273 CA
3274 CA
3278 CA
Total 11
REFINERY/OTHER
INDUSTRY (R/I)
Episode State
2026 OK
2380 IL
2383 IL
3061 AR
3063 LA
3069 TX
3071 TX
3072 TX
3086 LA
3095 PA
3096 PA
3125 MN
3183 KY
3264 CA
3312 WV
3431 PR
3434 NJ
3442 LA
3444 TN
3446 KY
Total 20
D-2-4
-------
APPENDIX D-3
Xenobiotics: Episode Numbers Used in Statistical Tests
(By Category)
-------
TABLE D-3
Other Xenobiotics: Episode Numbers Used in Statistical Tests (By Category)
NASQAN (NSQ)
Episode
2015
2016
2017
2023
2026
2070
2098
2105
2122
2126
2148
2151
2152
2191
2205
2220
2228
2246
2247
2280
2298
2309
2322
2358
2430
2431
2432
2437
2439
2478
2544
2776
3036
3041
3042
State
AR
AR
AR
AR
OK
X^Am
AK
WY
ND
MT
MS
FL
FL
FL
IA
NE
VA
VA
WA
WA
TX
TN
AL
NY
ME
MI
MI
MI
MN
OH
ID
LA
NV
IA
NE
NE
3050
3104
3199
3281
3308
Total
MO
PA
SD
CA
NY
40
AGRICULTURE (AG)
Episode
2280
2358
2478
3050
3082
3083
3084
3099
3105
3158
3170
3171
3180
3193
3208
3212
3352
3437
Total
SUPERFUND
Episode
3078
3097
3226
3261
3272
3414
State
TX
ME
ID
MO
LA
LA
TX
DE
OK
ID
AL
AL
GA
VA
OR
OR
LA
OR
18
(NPL)
State
AR
DE
WA
HI
CA
PA
3415
Total
POTW
Episode
2122
2152
2322
2432
2544
3308
3450
3451
Total
BACKGROUND
Episode
2110
2139
2216
2283
2397
2435
2651
3022
3023
3028
3073
3074
3075
3166
3169
3178
3200
3205
3230
3238
PA
7
State
MT
FL
NY
MI
LA
NY
CA
CA
8
(B)
State
SD
NC
PA
TX
WI
MI
NJ
ME
ME
ME
AR
NM
TX
NC
AL
GA
CO
OR
WA
AK
D-3-1
-------
TABLE D-3(Cont.)
3248
Total
PULP & PAPER
(Chlorine) (PPQ
Episode
2017
2138
2294
2302
2422
2532
2721
2725
3107
3118
3122
3151
3152
3192
3222
3224
3237
3245
3246
3260
3267
3303
3316
3318
3332
3335
3336
3340
3341
3342
3348
3395
ID
21
State
AR
NC
GA
AL
WI
LA
ME
ME
WI
MI
MI
MA
NH
WA
WA
WA
MT
AK
AK
NY
CA
NY
PA
PA
FL
GA
GA
MS
MS
NC
sc
NC
3403
3416
3418
3420
3421
3422
3423
3424
3425
3435
Total
INDUSTRY/URBAN
(IND/URB)
TN
LA
LA
PA
VA
VA
VA
VA
LA
MS
42
Episode State
3043
3044
3045
3079
3085
3101
3120
3149
3172
3174
3189
3190
3203
3234
3235
3236
3244
3258
3269
3275
3276
3283
3285
NE
MO
MO
OK
TX
PA
MI
DE
AL
FL
TN
TN
OR
MT
MT
MT
AK
VA
CA
CA
CA
CA
CA
3286
3289
3296
3298
3306
3307
3315
3411
3412
3426
3428
3438
Total
CA
CA
NY
NY
NY
NY
PA
NY
NY
NJ
NJ
WA
35
PULP & PAPER
(No Chlorine )
Episode
3090
3091
3108
3112
3135
3136
3140
3143
3145
3191
3287
3294
3330
3360
3376
3377
3401
Total
(PPNQ
State
OK
OK
WI
MN
WI
WI
WI
WI
WI
WA
CA
WA
FL
AL
GA
GA
TN
17
D-3-2
-------
TABLE D-3 (Cont.)
WOOD PRESERVERS
(WP)
Episode
3076
3077
3110
3167
3173
3196
3197
3271
3273
3274
3278
Total
State
OK
AR
WI
NC
FL
WY
CO
CA
CA
CA
CA
11
REFINERY/OTHER
INDUSTRY (R/I)
Episode
3061
3063
3072
3095
3446
Total
State
AR
LA
TX
PA
KY
5
D-3-3
-------
D-3-4
-------
APPENDIX D-4
Dioxin/Furan Data by Episode Number
-------
Key for Dioxin/Furan Data Table (Units = pg/g)
2,3,7,8 TCDD
1,2,3,7,8 PeCDD
1,2,3,4,7,8 HxCDD
1,2,3,6,7,8 HxCDD
1,2,3,7,8,9 HxCDD
1,2,3,4,6,7,8 HpCDD
2,3,7,8 TCDF
1,2,3,7,8 PeCDF
2,3,4,7,8 PeCDF
1,2,3,4,7,8 HxCDF
1,2,3,6,7,8 HxCDF
1,2,3,7,8,9 HxCDF
2,3,4,6,7,8 HxCDF
1,2,3,4,6,7,8 HpCDF
1,2,3,4,7,8,9 HpCDF
Compound Name
TetrachJorinated dibenzodioxins
Pentachlorinated dibenzodioxins
Hexachlorinated dibenzodioxins
Heplachlorinated dibenzodioxins
Tetrachlorinated dibenzofurans
Pentachlorinated dibenzofurans
Hexachlorinated dibenzofurans
Heptachlorinated dibenzofurans
CAS Number
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
37871-00-4
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57117-44-9
72918-21-9
60851-34-5
67562-39-4
55673-89-7
Concentration Information
ND = Not Detected
NA = Not Analyzed
QR = Below 40 percent recovery
DPE = Diphenyl Ether interference, a "Y" in the
column indicates that there was interference
with the analyses for 2,3,4,7,8 PeCDF; 1,2,3,4,6,7
HxCDF; 1,2,3,4,7,8 HxCDF; and 2,3,4,6,7,8
HxCDF
= Asterisk on 1,2,3,4,7,8 HxCDFindicates
coelulion with 1,2,3,4,6,7 HxCDF on GC column
(DBS 30M)x
Episode and SCC Information
Episode Number: Refer to Site Matrix Table
D-l for Walerbody Name and Location
SCC = Sample Control Center Numbers
First Letter Designation:
S = Confirmation Sample
D = Environmental Sample
Q = Duplicate Sample
Sample Information
Sample Type
F = Field Sample
L = Lab Duplicate
M = Molluscs/Crustaceans
O = Other
Fish Tissue Type
PF = Predator Fillet
BF = Bottom Fillet
WB = Whole Body
WP = Whole Predator
Second Letter Designation:
A = Region 1
B = Region 2
C = Region3
D = Region 4
E = Region5
F = Region 6
G = Region?
H = RegionS
Y = Region1;
J = Region 10
'The number of samples shown on the summary
tables in Volume I do not included the duplicate
and confirmation samples.
D-4-1
-------
D-4-2
-------
Dioxins/Furans
Concentration Ranges
D-4-3
-------
D-4-4
-------
Episode SCC Type Description
1994 DEO 17702 F WB Carp
1994 DEO 17703 F PF Walleye
1994 OD 11 0586 L UB Carp
1998 13285 F UB Carp
1998 13421 F PF Pike
2015 DF001001
2015 DF001002
2016 DF001101
2016 OF001102
2017 OF001201
2017 DF001202
2018 DF001301
2023 DF001402
2023 DF001403
2026 DF001702
2026 DF001703
2027 DF001802
2027 DF001803
2037 DY000501
2037 DY000502
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000901
2070 DJ000902
2070 QD072186
2098 DH001501
2098 DH001504
2100 DH001702
2100 DH001703
UB Carp
PU Crappie
UB Sucker
BF Sucker
UB Carp
BF Carp
UB Sucker
PF Spotted Bass
UB Carp
UB Carp
PF White Crappie
PF Lm Bass
UB Carp
UB not available
PU not available
UB Carp
UB Carp
UB Carp
UB Carp
UP Rainbow Trout
UB Longnose Sucker
UP Rainbow Trout
UB not available
PF not available
PF Sauger
UB Catfish
2100 GDI 11086 L UB Catfish
2105 DH002201 F PF Sauger
2105 DH002204 F UB Carp
2105 QD063086 L UB Carp
2109 DH002601 UB not available
2109 DH002602 BF not available
2110 DH002710 UP Broun Trout
2122 DH003901 PF Rainbow Trout
2122 DH003904 UB White Sucker
2126 DD000302 UB Carp
2378
TCDD
34.03
ND
29.26
ND
0.68
4.73
1.43
4.17
1.69
0.66
ND
ND
ND
ND
1.17
ND
ND
0.46
ND
ND
4.23
ND
6.63
1.76
ND
ND
ND
ND
ND
ND
1.65
1.98
ND
ND
ND
0.97
ND
ND
ND
ND
ND
12378
PECDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.09
OR 13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCDD
OR 5
OR ND
4.01
ND
ND
ND
ND
ND
NO
1.72
ND
OR ND
ND
0.76
ND
ND
ND
ND
ND
ND
QR ND
ND
OR 2
QR ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
123678
HXCDD
QR 61
OR ND
58.90
1.91
ND
4.48
ND
2.95
2.05
3.32
1.05
QR ND
ND
ND
1.35
ND
ND
3.57
ND
ND
QR 15
ND
OR 16
QR 2
ND
ND
QR ND
ND
ND
ND
7.34
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
5.48
DIOXIN
123789
HXCDD
QR 16
QR ND
13.47
ND
ND
ND
ND
ND
ND
0.74
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
OR ND
QR ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
1.61
/ FURAN CONCENTRATIONS.
1234678 2378 12378
HPCDD
QR 45
QR ND
OR ND
4.44
ND
QR 15
QR ND
4.04
5.10
QR 14
QR 6
QR ND
QR 2
3.08
OR 5
5.48
QR ND
QR ND
ND
OR 4
OR 45
8.16
OR 22
OR 8
ND
QR 3
QR ND
QR ND
1.01
ND
OR ND
OR ND
1.06
OR ND
OR ND
OR 14
QR 4
OR ND
1.89
4.32
OR 23
TCDF
14.09
0.80
12.63
ND
2.28
4.17
2.38
16.61
5.23
1.47
0.31
0.74
ND
0.30
0.55
ND
ND
0.81
0.29
ND
2.39
2.66
4.55
2.20
0.50
ND
ND
0.61
ND
ND
0.21
ND
ND
ND
ND
0.46
ND
ND
ND
1.09
0.37
PECDF
8.19
ND
7.74
0.76
ND
ND
ND
ND
ND
0.33
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.92
1.36
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
P9/9
23478
PECDF
29.32
ND
24.30
1.93
ND
2.11
ND
1.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.33
3.26
0.91
15.41
ND
ND
ND
ND
ND
ND
ND
ND
1.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCDF*
QR 19
QR ND
17.04
ND
ND
QR 2
ND
2.19
0.63
ND
NO
QR ND
ND
ND
ND
NO
ND
ND
ND
1.24
ND
ND
QR 3
0.84
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
OR ND
0.35
ND
ND
123678
HXCDF
QR 6
QR ND
ND
ND
ND
QR 1
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
1.35
1.51
ND
QR 1
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
123789
HXCDF
QR ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
234678
HXCDF
QR 8
QR ND
4.89
ND
ND
QR ND
ND
2.05
0.81
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR 1
0.48
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
1234678 1234789
HPCDF
OR 17
QR ND
QR 17
ND
ND
OR 2
OR ND
3.09
ND
QR ND
QR ND
QR ND
OR ND
OR ND
QR ND
ND
QR ND
QR ND
1.13
QR ND
QR 6
1.29
OR 4
OR 2
ND
QR ND
QR ND
QR ND
ND
ND
QR ND
QR ND
ND
OR ND
QR ND
QR 3
OR ND
OR ND
ND
ND
QR ND
HPCDF
QR ND
QR ND
QR ND
ND
ND
QR ND
QR ND
ND
ND
QR ND
QR ND
QR ND
QR ND
QR ND
QR ND
ND
QR ND
QR ND
ND
QR ND
QR ND
ND
QR ND
QR ND
ND
OR ND
QR ND
QR ND
ND
ND
QR ND
OR ND
ND
QR ND
QR ND
QR ND
QR ND
QR ND
ND
ND
OR ND
DPE
TEC
50.51
0.08
52.89
0.35
0.91
6.65
1.67
7.18
2.61
1.40
0.14
0.07
ND
0.14
1.36
0.05
ND
0.90
0.04
0.97
6.32
1.36
14.79
2.14
0.05
ND
ND
0.06
0.01
ND
2.40
2.72
0.01
ND
ND
1.02
ND
ND
0.05
0.15
0.75
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
2126 DD000303
2126 00062686
2133 DD001002
2138 DD001501
2138 DD001504
2139 DD001601
2139 00001604
2139 QD071486
2142 DD001902
2142 DD001903
2148 DD002501
2148 DD002504
2151 DD002801
2151 D0002803
2152 DD002902
2152 DD002903
2190 DG005101
2190 DG005104
2191 DG005205
2191 DG005206
2191 QD092486
2194 DG005501
2194 DG005504
2199 DG006001
2199 DG006004
2201 DG006201
2201 DG006204
2205 DG006601
2205 DG006602
2210 DC005401
2211 DC005503
2212 DC005602
2212 DC005605
2215 DCQ05902
2216 DC006002
2216 DC006003
2220 DC006401
2220 DC006405
2225 DC006902
2225 DC006903
2225 QD101387
F PF White Crappie
L UB Carp
BF Blue Catfish
UB Redhorse Sucker
PF Lm Bass
UB Carp
PF Rainbow Trout
PF Rainbow Trout
UB Catfish
PF Lm Bass
UB Saltwater Catfish
PF Saltwater Catfish
PF Lm Bass
UB Spotted Sucker
PF Lm Bass
UB Lake Chubsucker
UB Carp
PF Bluegill
UB Carp
BF Carp
BF Carp
UB Carp
BF Channel Catfish
UB Carp
PF Lm Bass
UB Carp
BF Bowfin
UB Carp
BF Carp
UB Catfish
UB Redhorse Sucker
PF Sm Bass
UB White Sucker
UB Carp
PF Brown Trout
UB White Sucker
PF Redbreast Sunfish
UB Catfish
PF Sm Bass
UB Shorthead Redhorse
UB Shorthead Redhorse
2378
TCDD
ND
2.16
ND
2.01
0.86
NO
2.26
1.87
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.44
ND
ND
ND
ND
ND
5.61
0.59
ND
2.01
ND
ND
ND
ND
ND
ND
6.76
5.86
12378
PECOD
ND
ND
ND
1.79
0.62
ND
ND
ND
0.66
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.93
2.58
123478
HXCDD
OR ND
1.84
ND
NO
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
QR ND
ND
ND
QR ND
QR ND
ND
NO
QR ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
1.70
1.10
123678
HXCDD
OR ND
4.77
1.97
4.61
4.13
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR 7
ND
1.59
4.48
OR ND
1.11
ND
OR 12
OR ND
ND
ND
OR ND
0.20
OR ND
ND
4.64
ND
ND
ND
2.22
ND
3.25
2.86
DIOXIN
123789
HXCDD
QR ND
1.41
ND
1.14
0.56
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
OR ND
ND
ND
OR ND
OR ND
ND
ND
QR ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.42
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
OR ND
QR 23
OR 6
15.91
6.72
QR ND
2.21
1.67
6.74
ND
QR 3
1.60
2.06
2.04
2.62
2.55
5.98
1.80
OR 23
QR 9
QR 8
QR ND
QR ND
4.02
ND
QR 56
QR ND
QR ND
ND
QR 5
1.29
QR ND
4.32
12.92
ND
OR ND
QR 6
6.12
0.36
6.67
6.92
TCDF
ND
ND
ND
13.45
0.82
ND
0.90
0.75
0.26
0.10
ND
ND
ND
ND
ND
ND
ND
ND
1.33
ND
ND
1.16
ND
ND
ND
ND
ND
0.38
0.41
0.85
7.77
ND
13.97
0.80
ND
0.29
ND
0.42
0.38
44.75
38.76
12378
PECDF
ND
ND
ND
1.33
0.27
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.61
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
0.88
0.37
ND
ND
ND
ND
ND
1.96
1.54
P9/9
23478
PECDF
ND
ND
ND
3.69
0.52
ND
0.70
0.70
0.86
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.74
ND
0.22
ND
ND
ND
ND
ND
QR ND
1.40
ND
2.86
1.73
ND
ND
ND
0.38
ND
3.88
3.16
123478
HXCDF*
QR ND
OR ND
ND
11.3
1.7
OR ND
ND
NO
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
QR ND
NO
ND
ND
QR ND
0.37
NO
NO
ND
ND
ND
1.25
1.90
QR ND
1.11
ND
ND
ND
0.82
ND
ND
5.6
3.80
123678
HXCDF
OR ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
123789
HXCDF
QR ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
QR ND
QR ND
ND
5.45
0.60
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
1.56
QR ND
ND
ND
NO
NO
ND
NO
NO
8.37
4.11
1234678 1234789
HPCDF
OR ND
QR ND
OR ND
4.77
1.00
OR ND
ND
0.48
1.13
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
OR 4
OR ND
OR ND
QR ND
OR ND
ND
ND
QR ND
QR ND
QR ND
0.96
QR ND
1.29
QR ND
ND
1.44
ND
QR ND
QR ND
ND
ND
6.03
4.49
HPCDF
OR ND
QR ND
QR ND
ND
ND
QR ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
OR ND
QR ND
QR ND
QR ND
QR ND
ND
ND
QR ND
QR ND
QR ND
ND
QR ND
ND
QR ND
ND
ND
ND
QR ND
OR ND
ND
ND
ND
ND
DPE
TEC
ND
2.96
0.20
8.62
2.30
ND
2.72
2.34
0.86
0.01
ND
0.02
0.02
0.02
0.03
0.03
0.06
0.02
0.16
ND
0.16
0.93
ND
2.74
ND
ND
ND
0.04
0.05
5.82
2.46
ND
5.04
1.57
ND
0.03
0.08
0.52
0.04
16.80
13.98
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
2227 DC007102
2227 DC007104
2228 DC007201
2228 DC007204
2228 OD070286
2231 DC007503
2246 DJ002301
2246 DJ002302
2247 DJ002403
2247 DJ002404
2280 DF005201
2280 DF005204
2280 QD062386
2283 DF005501
2283 DF005502
2290 DD003403
2294 DD003801
2294 DD003804
2297 DD004102
2297 DD004103
2298 DD004201
2298 DD004203
2301 DD004504
2301 OD071786
2302 DD004601
2304 DD004801
2304 DD004804
2309 DD005301
2309 DD005304
2322 DB001301
2322 DB001304
2322 00082686
2326 DB001701
2326 DB001704
2328 DB001904
2329 DB002004
2341 DD006002
2341 DD006003
2355 DA001603
2356 DA001702
2356 DA001703
PF Lm Bass
UB Channel Catfish
PF Longear Sunfish
UB Redhorse Sucker
UB Redhorse Sucker
UB Gizzard Shad
BF Bridgetip Sucker
UB Bridge!ip Sucker
PF Bridgetip Sucker
UP Mountain Whitefish
UB Carp
BF Channel Catfish
BF Channel Catfish
UB Gray Redhorse
UP Longear Sunfish
UB Spotted Sucker
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Channel Catfish
UP Lm Bass
UP Rock Bass
UP Rock Bass
UB Quillback Carpsucker
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB White Sucker
PF Lm Bass
PF not available
UB White Sucker
PF Rock Bass
PF Chinook Salmon
PF Broun Trout
PF Lm Bass
UB Carpsucker
UB White Sucker
PF Lm Bass
UB White Sucker
2378
TCDD
NO
ND
ND
ND
ND
ND
ND
ND
ND
0.37
ND
ND
ND
ND
ND
4.5
2.6
1.69
ND
ND
ND
ND
ND
ND
0.55
28.66
16.08
ND
ND
ND
ND
ND
ND
ND
12.89
12.49
2.14
4.42
7.97
3.57
23.38
12378
PECDD
ND
0.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
14.3
0.9
0.75
0.35
ND
QR ND
QR ND
ND
ND
0.47
9.40
1.26
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.16
ND
ND
123478
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.5
ND
0.55
ND
ND
QR ND
QR ND
ND
OR ND
ND
11.62
0.31
QR ND
ND
OR ND
QR ND
ND
ND
ND
ND
ND
NO
ND
0.55
ND
ND
123678
HXCDD
ND
2.77
ND
ND
1.36
ND
ND
ND
1.30
1.64
ND
0.44
NO
ND
ND
100.9
1.2
ND
0.47
ND
OR ND
QR ND
ND
OR ND
ND
25.98
1.77
QR 8
NO
QR ND
OR ND
ND
ND
ND
ND
ND
0.39
1.96
4.31
ND
4.76
D10XIN
123789
HXCDD
ND
0.87
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.7
0.2
0.29
ND
ND
OR ND
QR ND
ND
QR ND
0.21
5.38
0.32
OR ND
ND
QR ND
QR ND
ND
ND
ND
ND
ND
ND
ND
0.40
ND
ND
/ FURAN
CONCENTRATIONS.
1234678 2378
HPCDD
ND
8.05
QR 2
ND
QR 3
QR 4
OR ND
OR 5
QR 1
QR 2
QR ND
2.17
2.10
QR ND
QR ND
141.2
2.3
4.58
1.67
ND
QR ND
QR ND
QR ND
OR ND
2.60
90.77
2.20
QR 26
QR 2
QR ND
QR ND
QR ND
8.16
ND
ND
QR ND
0.72
3.72
7.38
QR ND
1.11
TCDF
0.39
0.24
ND
3.81
4.21
8.5
ND
ND
1.22
0.99
ND
ND
ND
ND
ND
22.0
2.1
5.29
1.51
0.45
ND
ND
0.86
ND
0.45
49.48
34.50
11.67
3.2
ND
0.41
ND
ND
ND
4.29
5.76
4.38
6.56
40.59
2.32
43.82
12378
PECDF
ND
ND
ND
ND
ND
ND
ND
0.20
ND
ND
ND
ND
ND
ND
ND
17.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.59
3.11
1.46
ND
ND
P9/9
23478
PECDF
ND
0.54
ND
ND
0.71
1.6
ND
ND
ND
0.50
ND
ND
ND
ND
ND
15.3
ND
0.52
ND
ND
ND
ND
ND
ND
ND
7.22
0.64
ND
ND
ND
ND
ND
0.56
ND
4.61
ND
0.91
5.21
1.13
ND
2.19
123478
HXCDF*
ND
ND
ND
0.83
1.67
2.6
ND
1.00
ND
ND
ND
ND
ND
ND
QR ND
11.6
0.7
0.70
ND
ND
QR ND
QR ND
ND
ND
0.50
4.20
0.20
QR ND
ND
QR ND
ND
ND
ND
ND
8.14
4.15
0.60
3.40
0.74
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
6.2
ND
ND
ND
ND
OR ND
OR ND
ND
ND
ND
2.52
ND
OR ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.82
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
QR ND
QR ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
0.51
ND
1.0
ND
0.52
0.58
0.57
ND
ND
ND
ND
QR ND
9.6
0.4
0.24
ND
ND
OR ND
QR ND
ND
ND
ND
1.82
ND
QR ND
ND
QR ND
ND
ND
ND
ND
1.36
ND
0.34
0.67
0.90
ND
ND
1234678 1234789
HPCDF
ND
0.61
QR ND
ND
QR ND
QR 2
OR ND
QR ND
QR 1
QR 1
QR ND
ND
ND
OR ND
QR ND
12.5
0.5
0.53
ND
0.30
QR ND
QR ND
QR ND
QR ND
0.73
5.54
0.37
OR ND
QR ND
QR ND
QR ND
QR ND
ND
ND
5.46
OR 2
0.63
1.55
2.29
OR ND
ND
HPCDF
ND
ND
QR ND
ND
QR ND
OR ND
OR ND
QR ND
QR ND
QR ND
QR ND
ND
ND
QR ND
QR ND
0.5
ND
ND
ND
ND
QR ND
QR ND
OR ND
OR ND
ND
ND
ND
QR ND
QR ND
OR ND
OR ND
OR ND
ND
ND
ND
QR ND
ND
ND
ND
QR ND
ND
DPE
TEC
0.04
1.12
ND
0.52
1.08
2.01
ND
0.16
0.31
0.94
ND
0.07
0.02
ND
ND
38.15
3.54
3.08
0.39
0.05
ND
ND
0.09
ND
0.93
48.03
20.81
1.17
0.32
ND
0.04
ND
0.36
NO
16.63
13.48
3.21
8.57
14.03
3.80
29.34
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
2358 DA001901 F UP ns
2369 DA003202 F PF Lm Bass
2369 DA003203 F WB White Sucker
2369 QD030387 L UB White Sucker
2375 DA003802 F PF Pickerel
2375 DA003B03 F WB White Sucker
2376 DA003903 F WB White Sucker
2376 QD111886 L WB White Sucker
2379 DE005404
2380 DE005S01
F PF Lm Bass
F WB Carp
2383 DE005B01 F WB Carp
2385 DE006002 F WB White Sucker
2385 OD101987 L WB White Sucker
2387 DE006201
2394 DE006901
2397 DE007201
2397 DE007204
2410 DE008S01
2410 DE008504
2416 DE009101
2422 DE009702
2427 DE010202
2427 DE010203
2427 QD102887
2429 DE010402
2429 DE010403
2429 OD0106B7
2430 DE010602
2430 DE010603
2431 DE010702
2431 DE010703
2432 DE010710
2432 DE010713
F WB Carp
F WB Carp
F WB Sucker
F PF Walleye
F WB Carp
F PF Sm Bass
F WB Carp
F WB Carp
F WB Carp
F PF Walleye
L PF Walleye
F WB Carp
F PF Walleye
L PF Walleye
F PF Northern Pike
F WB Redhorse Sucker
F PF Brown Trout
F WB Sucker
F WB Redhorse Sucker
F PF Walleye
2435 DE011001 F WB Longnose Sucker
2435 DE011004 F PF Brook Trout
2437 DE011202 F PF Walleye
2437 DE011203 F WB Carp
2439 DE011401 F WB Carp
2439 DE011402 F WP Sm Bass
2478 DJ003901 F FB Sucker
2478 DJ003902 F WB Sucker
2378
TCDO
NO
ND
1.01
ND
ND
1.26
ND
NO
ND
11.29
17.83
32.69
31.72
ND
4.2
ND
ND
23.72
0.44
3.74
3.92
8.54
0.33
0.42
S.S6
ND
0.48
ND
ND
ND
1.70
ND
0.8
ND
ND
ND
ND
2.23
1.75
ND
ND
12378
PECDD
ND
OR ND
OR ND
ND
NO
0.80
ND
ND
ND
ND
ND
0.87
0.83
ND
5.9
ND
ND
ND
OR ND
ND
1.19
12.13
ND
ND
ND
ND
ND
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCDD
ND
OR ND
OR ND
OR ND
ND
0.43
ND
OR ND
OR ND
1.85
3.26
ND
ND
ND
3.7
ND
ND
OR ND
OR ND
1.40
0.39
4.45
ND
ND
OR ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
1.66
ND
ND
ND
123678
HXCDD
4.57
OR ND
OR 1
OR 1
ND
1.77
ND
OR ND
OR ND
ND
27.84
0.62
0.83
ND
11.8
ND
ND
OR 25
OR ND
9.47
3.54
19.32
ND
ND
OR 14
NO
ND
ND
OR ND
ND
0.51
ND
ND
ND
ND
ND
ND
9.42
1.58
ND
ND
DIOXIN
123789
HXCDD
ND
OR ND
OR ND
OR ND
ND
0.24
ND
OR ND
OR ND
ND
ND
ND
ND
ND
2.8
ND
ND
OR ND
OR ND
ND
0.30
2.67
ND
ND
OR ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
2.83
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
OR 24
OR ND
OR ND
OR 3
1.77
3.87
ND
OR ND
OR ND
OR 29
OR 37
2.03
1.85
3.39
27.1
1.34
ND
OR ND
OR ND
OR 8
10.67
31.31
0.35
0.38
OR 25
ND
0.88
ND
OR ND
ND
1.42
ND
ND
ND
1.8
1.4
OR 4
OR 21
3.42
4.66
OR ND
TCDF
0.60
ND
9.50
8.51
0.64
12.70
9.12
8.16
ND
5.51
6.81
75.29
74.70
1.36
8.0
0.89
ND
14.15
1.00
4.07
8.80
34.95
5.76
5.93
5.66
2.49
2.59
ND
0.80
3.60
0.93
0.6
2.0
4.4
ND
0.4
ND
2.32
2.97
ND
ND
12378
PECOF
ND
ND
ND
ND
ND
0.67
ND
ND
ND
1.74
4.47
0.71
0.68
ND
1.6
ND
ND
9.13
ND
1.87
0.63
9.08
ND
0.18
ND
ND
ND
ND
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
P9/9
23478
PECDF
ND
ND
ND
ND
ND
1.19
2.03
1.67
ND
6.43
15.19
2.00
1.95
0.24
5.6
ND
ND
29.78
ND
10.11
1.47
20.14
ND
ND
0.51
ND
ND
ND
ND
0.56
ND
ND
ND
1.3
ND
ND
ND
3.27
1.36
ND
ND
123478
HXCDF*
3.01
OR ND
OR ND
OR 1
ND
0.88
3.61
ND
OR NO
9.07
ND
2.30
1.90
ND
1.3
ND
ND
34.26
QR ND
1.85
1.40
5.60
0.40
0.50
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.53
2.01
ND
OR ND
123678
HXCDF
ND
QR ND
OR ND
OR ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
2.7
NO
ND
5.68
OR ND
1.03
0.99
4.84
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.58
ND
ND
QR ND
123789
HXCDF
ND
QR ND
OR ND
QR ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
234678
HXCDF
NO
QR ND
QR ND
OR ND
ND
ND
ND
ND
QR ND
3.89
7.80
ND
NO
ND
0.9
ND
ND
6.42
QR ND
ND
1.01
2.59
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.82
ND
OR ND
1234678 1234789 OPE
HPCDF
QR ND
OR ND
QR ND
QR 2
ND
1.02
ND
QR ND
OR ND
QR 13
OR 16
1.10
0.86
0.30
1.7
ND
ND
OR ND
QR ND
QR ND
2.84
4.23
0.23
ND
QR 11
ND
ND
ND
QR ND
ND
0.40
ND
ND
ND
ND
ND
QR ND
QR 6
2.85
ND
QR ND
HPCDF
QR ND
QR ND
QR ND
QR ND
ND
ND
ND
QR ND
OR ND
QR ND
QR ND
ND
ND
ND
ND
ND
ND
QR ND
QR NO
QR ND
ND
ND
ND
ND
QR ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
OR ND
OR ND
ND
ND
OR ND
TEC
0.82
ND
1.96
0.85
0.08
3.94
2.29
1.65
ND
16.62
30.22
42.01
40.91
0.29
13.44
0.10
ND
45.12
0.54
10.67
7.06
32.93
0.95
1.08
6.38
0.25
0.75
ND
0.08
0.90
1.86
0.06
1.00
1.09
0.02
0.05
ND
6.00
3.33
0.05
ND
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
2500 DC010201 F PF Bass
2500 DC010203 F UB Black Buffalo
2532 DF019302 F PF Lm Bass
2532 DF019303 F UB Carp
2544 DF019202 F UB Blacktail Redhorse
2608 DE014501 F PF Walleye
2608 DE014504 F UB Carp
2618 DE015401 F UB Carp
2618 DE015402 f BF Carp
2618 DE015403 F UB Ouillback
2618 QD 102088 L UB Ouillback
2651 DB008401 F UB White Sucker
2653 DB008503 F UB Carp
2654 DB008601 F UB Carp
2709 DB005101 F UB Catfish
2721 DA006502 F UB Sucker
2722 DA006601 F UB Sucker
2725 DA006301 F UB Sucker
2748 DY006505 F UB Sucker
2748 DY006506 F BF not available
2776 DY007101 F UB Carp
2776 DY007103 F PF Trout
3001 DE019501 F PF Walleye
3001 DE019502 F UB White Sucker
3022 DA008401 F UB White Sucker
3022 DA008402 F PF Chain Pickerel
3023 DA008501 F PF Sm Bass
3024 DA008601 F PF Lm Bass
3025 DA008701 F UB White Sucker
3025 DA008702 F PF Chain Pickerel
3026 DA009001 F WB Catfish
3026 OA009002 F PF Lm Bass
3027 DA009301 F UB Sucker
3028 DA008801 f PF Chain Pickerel
3028 OD031787 L PF Chain Pickerel
3034 DG025701 F UB Carp
3034 DG025702 F PF Lm Bass
3035 DG025801 F UB Carp
3035 DG025802 F PF Sm Bass
3036 OG025901 F PF Freshwater Orun
3036 DG025902 F UB Carp
2378
TCOD
10.40
ND
0.82
6.00
ND
7.07
67.18
3.96
1.64
2.10
1.73
0.85
2.82
ND
ND
40.96
ND
16.08
ND
ND
ND
ND
ND
ND
0.37
ND
ND
ND
1.57
ND
23.11
2.88
ND
ND
ND
1.17
ND
1.76
ND
ND
ND
12378
PECDD
ND
ND
ND
2.64
ND
ND
2.37
3.87
1.44
1.82
1.72
ND
1.08
ND
ND
2.45
ND
2.02
ND
ND
ND
ND
ND
ND
0.54
ND
ND
ND
1.33
ND
2.27
0.21
ND
ND
ND
0.66
ND
2.29
ND
ND
0.39
123478
HXCDD
OR ND
OR ND
ND
2.95
ND
ND
1.80
2.73
ND
ND
0.54
ND
0.78
ND
OR ND
ND
OR ND
ND
ND
ND
ND
ND
OR ND
ND
0.21
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.65
ND
1.11
ND
ND
ND
123678
HXCDD
OR ND
OR ND
0.56
6.57
ND
ND
6.11
12.95
4.76
3.11
3.13
ND
2.04
ND
OR ND
8.43
OR ND
9.54
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
10.76
ND
8.96
ND
ND
ND
ND
1.69
ND
2.33
ND
ND
0.69
D10XIN
123789
HXCOD
OR ND
OR ND
ND
0.91
ND
ND
0.86
1.48
ND
ND
ND
ND
ND
ND
OR ND
0.71
OR ND
0.89
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.83
ND
ND
ND
ND
0.49
ND
ND
ND
ND
0.22
/ FURAN
CONCENTRATIONS.
1234678 2378
HPCDD
OR 1
OR ND
2.14
20.34
0.35
0.43
18.10
22.49
8.50
9.37
9.46
OR ND
7.17
ND
OR 5
4.49
OR ND
4.72
ND
OR 2
ND
ND
OR ND
OR ND
0.72
OR ND
0.23
OR ND
OR 20
0.98
2.39
0.28
OR ND
OR ND
ND
6.40
ND
4.41
OR ND
ND
2.66
TCDF
1.07
ND
ND
9.81
0.90
7.72
35.27
9.18
2.79
8.33
8.43
2.19
1.16
0.36
3.41
207.49
ND
106.82
ND
ND
ND
ND
ND
ND
6.21
ND
0.30
0.90
0.85
ND
8.25
6.05
1.93
ND
ND
10.60
0.30
1.94
ND
ND
0.38
12378
PECOF
ND
ND
ND
4.07
ND
ND
2.66
1.70
ND
0.84
0.86
ND
0.43
ND
ND
4.87
ND
5.11
ND
ND
ND
ND
ND
ND
0.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.08
ND
0.39
ND
ND
ND
P9/9
23478
PECDF
ND
ND
ND
6.41
ND
0.15
3.65
5.05
1.81
2.25
2.37
ND
2.36
ND
4.03
6.15
ND
6.19
ND
ND
ND
ND
ND
ND
1.36
ND
ND
ND
ND
ND
6.24
0.20
ND
ND
ND
1.28
ND
1.16
ND
ND
ND
123478
HXCOF*
ND
ND
0.40
4.91
NO
ND
2.98
1.14
0.33
ND
ND
ND
1.40
ND
OR ND
1.51
OR NO
1.58
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
0.76
ND
OR ND
ND
ND
0.42
ND
1.60
ND
ND
ND
123678
HXCDF
ND
ND
ND
3.18
ND
ND
ND
1.61
0.62
ND
ND
ND
ND
ND
OR ND
ND
OR ND
0.50
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
OR ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
1.45
ND
ND
1.18
ND
ND
ND
ND
ND
1.27
ND
OR ND
ND
OR ND
0.33
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
5.27
ND
0.29
ND
OR ND
ND
ND
0.73
ND
1.00
ND
ND
ND
1234678 1234789
HPCDF
OR ND
OR ND
ND
3.99
0.18
0.20
2.33
1.51
0.51
0.89
0.95
OR ND
1.70
ND
OR ND
2.05
OR ND
2.48
ND
OR ND
ND
ND
OR ND
OR ND
0.15
OR ND
ND
OR ND
OR 8
ND
0.94
ND
OR ND
OR ND
ND
3.11
ND
1.07
OR ND
ND
ND
HPCDF
OR ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
OR ND
ND
OR ND
ND
ND
OR ND
ND
ND
OR ND
OR ND
ND
OR ND
ND
OR ND
OR ND
ND
ND
ND
OR ND
OR ND
ND
ND
ND
ND
OR ND
ND
ND
DPE
TEC
10.51
ND
0.94
13.95
0.10
7.92
75.35
11.65
4.21
5.42
5.13
1.07
5.32
0.04
2.36
67.38
ND
32.48
ND
ND
ND
ND
ND
ND
2.00
ND
0.03
0.09
3.92
0.01
29.31
3.69
0.19
ND
ND
3.75
0.03
4.36
ND
ND
0.35
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3036 OD1202B7
3037 DG026001
3037 DG026002
3038 DG026101
3038 DG026102
3039 DG026201
3039 DG026202
3040 DG026301
3040 DG026302
3041 DG026401
3041 DG026402
3041 00031588
3042 DG026501
3042 DG026502
3043 DG026601
3043 DG026602
3043 QD111987
3044 DG026701
3044 DG026702
3045 DG026801
3045 DG026802
3046 DG026901
3047 DG027001
3047 DG027002
3048 DG027101
3048 DG027102
3049 DG027201
3049 OG027202
3049 QD111087
3050 DG027301
3060 DF009101
3060 DF009102
3061 DF019105
3061 DF019106
3062 DF024024
3062 DF024324
3062 QD024324
3062 OD071587
3062 SF024324
3063 DF023301
3063 DF023302
L PF Freshwater Drun
F WB Carp
F PF Black Crappie
F WB Carp
F BF Channel Catfish
F UB Carp
F BF Channel Catfish
F UB Carp
F PF White Crappie
F BF Channel Catfish
F WB Carp
L BF Channel Catfish
F WB Carp
F PF Northern Pike
F BF Flathead Catfish
F BF Flathead Catfish
L BF Flathead Catfish
F WB Carp
F BF Flathead Catfish
F WB Carp
F BF Flathead Catfish
F WB Bigmouth Buffalo
F WB Carp
F PF Sm Bass
F WB Carp
F PF White Bass
F WB Carp
F PF Crappie
L PF Crappie
F WB Bigmouth Buffalo
F WB Flathead Catfish
F WB Sm Buffalo
F PF Bass
F WB Sucker
F WB Blue Catfish
F BF Grass Carp
L BF Grass Carp
L WB Blue Catfish
F BF Grass Carp
F WB Sea Catfish
F PF Spotted Seatrout
2378
TCDD
NO
0.39
ND
2.90
0.63
1.54
ND
3.02
ND
ND
ND
0.44
ND
ND
0.47
0.31
0.27
0.82
0.23
2.40
ND
0.66
1.29
ND
2.69
ND
7.49
ND
ND
0.92
ND
1.21
0.62
ND
33.86
8.85
9.14
32.36
8.99
1.50
ND
12378
PECDD
ND
0.38
ND
1.68
ND
1.95
ND
4.67
ND
0.72
ND
0.62
1.62
ND
ND
0.21
ND
1.09
ND
ND
0.42
ND
1.46
ND
3.96
ND
2.80
ND
ND
ND
ND
ND
1.13
3.68
1.21
ND
ND
1.17
ND
1.57
ND
123478
NXCDD
ND
ND
ND
1.00
ND
0.84
ND
6.71
ND
ND
0.21
0.47
0.63
ND
ND
ND
ND
0.68
ND
QR ND
ND
ND
1.14
ND
2.26
ND
1.79
ND
ND
0.40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
ND
0.57
ND
3.21
1.22
3.86
0.88
8.78
ND
0.93
0.38
0.85
4.20
ND
1.32
0.39
0.24
ND
0.58
OR 4
1.26
0.39
2.92
ND
12.37
ND
5.55
ND
ND
0.54
ND
ND
1.98
7.94
1.28
ND
ND
1.50
ND
1.65
ND
DIOXIN
123789
HXCDD
ND
ND
ND
0.72
0.32
0.86
ND
3.13
ND
0.17
ND
0.18
0.95
ND
ND
ND
ND
0.34
ND
OR ND
ND
ND
ND
ND
ND
ND
1.09
ND
ND
ND
ND
ND
1.29
ND
ND
ND
ND
ND
ND
0.46
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
ND
1.25
ND
11.09
1.81
14.05
2.13
55.10
0.50
1.46
1.71
1.52
QR 10
0.20
QR 3
1.07
0.56
7.76
2.03
QR 15
2.73
2.44
10.76
0.32
QR 29
QR ND
25.93
ND
ND
2.69
QR ND
QR ND
5.22
QR 15
3.84
2.51
2.71
3.72
1.96
3.70
ND
TCDF
ND
1.10
ND
1.78
ND
1.46
ND
0.71
ND
ND
0.26
0.21
1.07
ND
0.45
0.15
ND
0.89
ND
ND
ND
0.85
3.10
ND
4.66
0.51
2.44
0.16
ND
3.15
ND
4.20
ND
ND
32.07
69.82
69.29
33.8
71.92
1.20
1.51
12378
PECDF
ND
ND
ND
0.50
ND
0.52
ND
ND
ND
ND
ND
ND
0.35
ND
ND
ND
ND
0.29
ND
0.27
ND
ND
0.64
ND
ND
ND
ND
ND
ND
0.29
ND
ND
ND
0.27
0.64
ND
0.30
0.61
ND
1.09
2.52
P9/9
23478
PECDF
ND
ND
ND
1.13
0.27
1.36
ND
0.66
ND
ND
ND
0.36
0.70
ND
ND
ND
ND
0.47
0.18
ND
ND
ND
0.92
ND
2.46
ND
2.20
ND
ND
ND
ND
0.48
ND
ND
3.57
0.78
0.57
ND
0.50
5.73
ND
123478
HXCDF*
ND
0.40
ND
1.30
ND
0.51
ND
0.91
ND
0.13
ND
0.29
0.45
ND
0.38
0.40
ND
1.30
ND
QR 1
ND
ND
0.85
ND
1.65
ND
2.65
ND
ND
ND
ND
ND
0.27
ND
1.06
ND
ND
1.14
ND
3.52
2.00
123678
HXCDF
ND
ND
ND
0.62
ND
0.76
ND
0.52
ND
ND
ND
ND
0.37
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.31
0.32
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
0.97
ND
0.29
ND
0.76
ND
ND
ND
0.26
ND
ND
0.25
ND
ND
ND
ND
QR 0
ND
ND
0.37
ND
ND
ND
1.86
ND
ND
1.44
ND
ND
ND
0.42
ND
ND
ND
ND
ND
ND
ND
1234678 1234789 DPE
HPCDF
ND
0.34
ND
1.70
0.39
1.25
ND
1.36
ND
0.31
0.18
0.33
QR 1
ND
QR ND
0.68
ND
1.18
0.34
QR ND
ND
ND
1.02
ND
QR ND
QR ND
3.34
ND
ND
1.71
QR ND
QR ND
0.23
QR 1
ND
ND
ND
0.40
ND
4.09
2.41
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
QR ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
QR ND
QR ND
ND
ND
ND
ND
QR ND
QR ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
TEC
ND
0.80
ND
5.42
0.94
4.23
0.11
8.40
ND
0.50
0.10
1.17
1.94
ND
0.71
0.53
0.30
2.02
0.40
2.41
0.36
0.81
3.47
ND
7.99
0.05
11.82
0.02
ND
1.53
ND
1.87
1.59
2.69
39.76
16.25
16.40
36.66
16.24
6.00
0.53
Y
Y
Y
Y
Y
Y
Y
Y
V
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
V
Y
-------
Episode SCC Type Description
3064 DF02330S M
3064 DF023306
3065 DF023419
3065 DF023420
3065 QD022588
3066 DF023503
3066 DF023504
3068 DF024001
3068 DF024002
3069 DF024007
3069 DF024008
3070 DF024009
3070 DF024010
3071 DF024014
3072 DF024017
3072 DF024018
3072 QD040788
3073 DF019221
3073 DF019222
3073 QD121587
3074 DF026017
3075 DF024102
3076 DF028502
3076 DF028503
3077 DF019113
3077 DF019114
3077 QD121087
3078 DF009118
3078 DF023B15
3078 DF023816
3078 SF009118
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3080 OD040987
3081 DF024105
3081 DF024106
3082 DF023401
3082 DF023402
3082 OD120787
Shellfish
PF Spotted Seatrout
BF Bigmouth Buffalo
UB Flathead Catfish
UB Flathead Catfish
UB Catfish
PF Freshwater Drum
Oysters
PF At I. Croaker
UB Sea Catfish
PF Trout
UB Croaker
PF Sheepshead
UB Carp
UB Carp
PF Uhite Bass
PF Uhite Bass
UB Uhite Sucker
PF Sm Bass
UB Uhite Sucker
PF Brown Trout
BF Sea Catfish
UB Channel Catfish
PF Spotted Bass
BF Flathead Catfish
UB Redhorse Sucker
BF Flathead Catfish
UB Carp
UB Sm Buffalo
PF Black Crappie
UB Carp
PF Uhite Bass
UB Carp
UB Carp
PF Ltn Bass
UB Carp
PF Uhite Bass
UB Catfish
UB Carp
PF Lm Bass
PF Lm Bass
2378
TCDD
ND
NO
1.83
1.78
1.79
4.62
ND
6.70
ND
0.72
ND
ND
0.69
1.07
ND
ND
ND
0.30
ND
0.30
ND
ND
0.39
ND
ND
ND
ND
17.91
203.64
23.10
15.41
ND
0.34
3.62
1.03
3.35
0.94
2.45
ND
ND
ND
12378
PECDD
ND
ND
0.53
0.68
0.67
ND
ND
ND
ND
0.81
ND
ND
ND
0.69
ND
ND
ND
ND
ND
0.25
OR ND
ND
0.63
ND
ND
ND
ND
3.35
12.62
ND
3.07
ND
ND
2.64
ND
3.31
ND
ND
1.02
ND
ND
123478
HXCDD
ND
ND
ND
0.29
0.44
0.71
ND
ND
ND
ND
ND
ND
0.19
ND
ND
ND
ND
ND
ND
0.24
QR ND
ND
0.63
ND
ND
ND
ND
2.43
1.50
ND
2.00
ND
ND
1.92
ND
2.18
ND
1.44
ND
ND
ND
123678
HXCDD
0.26
ND
0.86
0.57
0.50
2.43
ND
ND
0.49
0.82
ND
0.59
ND
2.09
ND
ND
ND
0.45
ND
0.46
QR ND
ND
1.47
ND
ND
ND
ND
5.13
2.46
ND
3.08
ND
0.52
4.88
0.25
6.58
0.47
2.20
2.52
ND
ND
DIOXIN
123789
HXCDD
ND
ND
0.30
ND
ND
0.77
ND
ND
ND
ND
ND
0.33
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
1.51
0.49
ND
0.73
ND
ND
1.87
ND
2.14
ND
0.88
0.40
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
3.45
1.46
2.50
2.03
1.97
11.11
0.85
0.89
ND
1.80
0.21
2.46
1.44
4.95
0.54
0.25
0.25
0.94
0.19
1.11
OR ND
0.51
2.01
0.35
0.47
0.75
0.89
27.86
6.07
2.14
25.96
0.37
1.46
23.95
ND
29.65
1.56
7.86
12.89
1.44
0.37
TCDF
0.47
ND
0.18
5.09
4.93
4.58
0.28
14.13
1.38
ND
ND
0.71
0.31
3.11
0.52
0.26
0.30
1.46
0.33
1.27
ND
ND
0.24
ND
ND
ND
ND
8.87
21.23
12.41
7.23
1.08
0.61
4.89
ND
6.95
0.80
ND
3.83
0.97
0.99
12378
PECDF
ND
ND
ND
0.69
0.72
1.31
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.51
ND
0.44
ND
0.14
ND
ND
0.32
ND
ND
0.88
ND
ND
pg/g
23478
PECDF
ND
ND
0.66
1.06
0.99
3.09
ND
ND
ND
1.07
ND
ND
ND
1.56
ND
ND
ND
0.14
ND
ND
ND
ND
0.44
ND
ND
ND
ND
1.05
0.70
ND
0.91
0.20
0.32
0.47
ND
0.75
ND
0.26
ND
ND
ND
123478
HXCOF*
ND
ND
ND
0.53
0.62
2.05
ND
ND
ND
ND
ND
ND
ND
0.42
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
0.41
ND
ND
ND
0.30
0.38
ND
0.54
ND
ND
0.40
ND
ND
123678
HXCOF
ND
ND
ND
ND
ND
0.73
ND
ND
ND
ND
ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
0.22
ND
0.74
ND
ND
ND
ND
ND
ND
ND
0.25
ND
ND
ND
ND
ND
ND
QR ND
ND
0.61
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.18
0.38
ND
0.49
ND
ND
ND
ND
ND
1234678 1234789 DPE
HPCDF
0.35
0.18
0.27
0.33
0.36
1.35
ND
ND
ND
0.21
ND
0.17
0.55
0.55
ND
ND
ND
0.20
ND
ND
QR ND
ND
0.58
0.18
ND
ND
ND
0.23
ND
ND
ND
ND
0.27
0.59
ND
1.22
ND
0.23
1.16
ND
0.18
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
0.11
0.02
2.59
3.38
3.33
7.56
0.04
8.12
0.19
1.76
ND
0.19
0.76
2.89
0.06
0.03
0.03
0.57
0.03
0.63
ND
0.01
1.25
0.01
ND
0.01
0.01
22.18
213.05
24.36
18.06
0.21
0.69
6.85
1.05
7.59
1.08
3.11
1.41
0.11
0.10
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
KJ
Episode SCC Type Description
3083 DF023405
3083 OF023406
3084 DF024109
3084 QD072188
3085 DF024113
3085 DF024114
3085 SF024113
3086 DF023409
3086 DF023411
3087 DF023413
3087 DF023414
3087 DF023415
3087 DF023416
3087 QD023414
3087 00072387
3087 SF023414
3087 SF023415
3088 DF023417
3088 OF023418
3089 DF019209
3089 DF019210
3090 DF019213
3090 DF019214
3091 DF019217
3091 DF019218
3092 DF023501
3092 DF023502
3093 DF024011
3093 DF024118
3093 QD080387
3094 DC017201
3094 QD092988
3095 DC038801
3095 DC038802
3096 DC035001
3096 DC03S002
3096 QD052488
3097 DC038701
3097 DC038702
3098 DC038601
3098 DC038602
F US Black Bullhead
F PF Lm Bass
F WB Channel Catfish
L WB Channel Catfish
F UB Sea Catfish
F PF Black Drum
F UB Sea Catfish
F UB Catfish
F PF Black Drum
F UB Carp
F PF White Crappie
F UP Bluegill
F UP Lm Bass
L PF White Crappie
L UB Carp
F PF White Crappie
F UP Bluegill
F UB Channel Catfish
F PF Bluegill
F PF White Crappie
F WB Carp
F PF White Crappie
F UB Channel Catfish
F UB River Carpsucker
F PF White Crappie
F WB Carp
F PF Warmouth
F PF Lm Bass
F WB Sm Buffalo
L WB Sm Buffalo
F BF Channel Catfish
L BF Channel Catfish
F BF Brown Bui Ihead
F UB Channel Catfish
F BF Brown Bullhead
F UB Channel Catfish
L UB Channel Catfish
F BF Brown Bullhead
F UB Carp
F UB White Sucker
F PF American Eel
2378
TCDD
ND
ND
1.28
1.07
2.58
0.66
2.73
ND
ND
117.89
13.11
66.70
20.22
16.79
114.34
14.30
73.98
13.69
1.4
ND
ND
ND
ND
ND
ND
2.11
ND
ND
0.41
ND
1.71
1.69
1.24
ND
0.53
4.62
4.53
0.8]
1.42
24.89
3.32
12378
PECDD
0.80
ND
0.96
0.86
6.82
ND
8.01
2.99
ND
7.24
0.79
1.93
ND
1.21
7.28
1.00
1.91
ND
ND
ND
ND
ND
0.36
ND
ND
6.99
ND
ND
0.70
0.68
2.16
2.08
1.23
ND
ND
5.33
4.84
NO
2.27
27.23
12.46
123478
HXCDD
0.49
ND
ND
ND
3.73
ND
4.38
0.82
ND
ND
ND
ND
ND
ND
1.94
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.94
ND
ND
0.49
0.63
' ND
ND
ND
ND
ND
ND
1.10
ND
ND
ND
ND
123678
HXCDD
0.91
ND
ND
0.94
10.50
1.77
11.85
2.47
ND
5.88
ND
1.92
ND
0.50
6.38
ND
1.24
1.25
ND
ND
0.4
ND
0.55
ND
ND
14.18
ND
ND
1.90
1.45
2.16
2.50
1.67
4.72
0.43
5.32
4.95
ND
3.23
7.00
8.43
DIOXIN
123789
HXCDD
0.40
ND
ND
0.31
2.18
ND
2.51
ND
ND
2.11
ND
ND
ND
ND
ND
ND
ND
0.57
ND
ND
ND
ND
ND
ND
ND
5.59
ND
ND
0.51
0.53
NO
0.33
ND
0.91
ND
ND
1.01
ND
0.88
6.80
3.21
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
10.74
ND
1.83
1.59
9.41
1.06
11.05
3.72
ND
12.33
ND
ND
2.82
0.94
12.33
0.46
1.24
4.92
0.5
ND
1.4
ND
2.04
0.49
ND
106.84
0.87
1.41
6.97
7.69
5.33
6.00
3.10
5.70
0.76
4.39
4.08
OR ND
ND
27.39
6.20
TCDF
0.32
ND
0.51
0.53
4.62
14.77
5.15
4.04
0.32
261.34
81.40
71.94
8.74
110.71
253.01
107.66
68.81
7.65
2.2
0.40
1.4
0.71
0.39
ND
ND
0.41
ND
ND
ND
0.55
0.60
0.51
2.31
0.86
0.97
0.71
0.77
1.42
4.62
5.03
ND
12378
PECDF
ND
ND
ND
0.33
7.59
20.30
8.75
2.60
0.25
8.80
1.65
2.09
ND
2.28
8.74
1.67
1.73
ND
ND
ND
ND
ND
0.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.35
0.77
ND
0.67
0.66
ND
2.96
ND
ND
P9/9
23478
PECDF
0.15
ND
1.01
0.92
45.51
11.25
56.85
33.25
ND
17.24
2.46
1.59
2.09
3.21
18.36
1.92
1.40
ND
ND
ND
0.3
ND
0.75
ND
ND
ND
ND
ND
ND
0.18
4.84
3.58
4.29
9.89
0.92
14.01
11.85
2.91
7.53
0.92
ND
123478
HXCDF*
ND
ND
ND
0.18
11.92
6.65
13.74
19.98
ND
0.40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.49
ND
0.24
0.24
0.49
2.26
ND
2.60
2.42
ND
2.92
ND
ND
123678
HXCDF
ND
ND
ND
ND
16.21
8.19
20.67
ND
ND
1.49
ND
ND
ND
ND
1.60
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.63
0.48
0.75
ND
ND
ND
1.51
ND
2.63
ND
ND
123789
HXCDF
ND
ND
ND
ND
0.96
ND
1.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
5.29
1.08
7.01
2.48
ND
0.54
ND
ND
ND
NO
0.53
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.23
0.30
ND
ND
1.49
1.24
ND
0.53
ND
0.88
1234678 1234789 OPE
HPCDF
ND
ND
ND
0.21
8.20
1.45
8.95
25.66
ND
ND
ND
ND
ND
NO
0.75
ND
ND
ND
ND
ND
0.2
ND
ND
0.72
ND
2.31
ND
ND
ND
ND
0.53
0.47
0.26
ND
ND
ND
ND
OR ND
1.71
2.66
1.45
HPCDF
ND
ND
ND
ND
1.26
0.19
1.49
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
TEC
0.79
ND
2.33
2.19
34.85
10.57
15.01
21.52
0.04
157.87
22.98
75.95
22.17
30.24
154.07
25.93
82.18
14.69
1.63
0.04
0.35
0.07
0.68
0.01
ND
9.71
0.01
0.01
1.27
0.82
5.63
5.01
4.65
5.92
1.14
15.38
14.25
2.41
7.97
41.15
10.88
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode see Type Description
3098 QD032587 L UB White Sucker
3100 DC019701
3100 DC019702
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
3105 DF025002
3106 DE026801
3106 DE026802
3107 DE026901
3108 DE027001
3108 OE027002
3109 DE025001
3109 DE025002
3110 DE022501
3110 DE022502
3111 DH015801
3111 DH015802
3112 DE022401
3112 DE022402
3113 DE021101
3113 DE021102
3114 DE021201
3115 DE021301
3115 DE021302
3117 DE021501
3117 DE021502
3118 DE021601
3118 OE021602
3118 DE021603
3118 SE021602
3119 DE021701
3119 DE021702
3120 DE021801
3120 DE021802
3122 DE022001
3122 DE022003
3122 DE022004
PF White Perch
WP Winter Flounder
PF Brown Trout
WB Channel Catfish
WB Carp
PF Lm Bass
WB Carp
WB Carp
PF Lm Bass
PF Walleye
PF White Bass
WB Carp
PF Walleye
WB Carp
WB Carp
PF Sm Bass
BF Flathead Catfish
BF Carp
PF Walleye
WB Silver Redhorse
WB Carp
PF Walleye
BF Channel Catfish
BF Carp
BF Carp
WB Carp
PF Catfish
PF Lake Trout
PF Brown Trout
PF Walleye
WB Carp
WB Carp
WB Carp
WB Carp
PF Lm Bass
WB Carp
PF Bass
WB Carp
WB Redhorse Sucker
PF Sm Bass
2378
TCDO
24.02
ND
NO
ND
ND
0.96
ND
1.68
0.73
ND
7.02
17.52
ND
ND
2.68
0.50
0.35
ND
2.72
ND
ND
2.98
ND
ND
1.49
0.72
7.00
6.24
3.74
ND
1.37
11.61
3.85
9.39
ND
2.30
3.07
0.73
21.01
1.36
1.37
12378
PECDD
25.09
0.50
ND
ND
OR 2
ND
ND
ND
0.30
ND
ND
0.54
0.99
ND
2.09
0.42
ND
0.38
5.68
ND
ND
1.38
ND
0.77
1.73
ND
1.84
0.91
8.76
2.35
ND
2.22
1.01
2.22
0.59
ND
ND
ND
6.22
ND
ND
123478
HXCDD
ND
ND
ND
ND
0.84
0.67
ND
1.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34
2.34
ND
ND
1.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.69
0.53
0.70
ND
ND
0.40
ND
0.96
ND
ND
123678
HXCDD
7.14
0.56
ND
ND
2.84
0.99
ND
2.19
ND
ND
0.25
ND
3.41
ND
14.39
0.74
ND
1.35
8.14
ND
1.48
2.79
ND
2.25
5.77
1.18
7.18
3.82
5.97
1.41
ND
2.87
1.30
2.37
1.63
ND
2.41
ND
10.13
ND
ND
DIOXIN
123789
HXCDD
5.90
ND
ND
ND
0.67
ND
ND
0.42
ND
ND
ND
ND
ND
ND
1.05
ND
ND
0.15
0.90
ND
ND
1.25
ND
ND
ND
ND
0.84
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
ND
ND
/ FURAN CONCENTRATIONS,
1234678 2378 12378
HPCDD
OR 26
1.31
1.26
ND
3.87
3.76
0.87
5.11
1.70
0.53
1.32
1.43
7.49
ND
42.22
1.21
ND
2.64
10.35
NO
ND
5.99
0.26
2.89
14.78
4.61
39.51
11.94
0.98
2.00
ND
4.42
3.51
3.32
3.64
ND
0.54
ND
14.86
OR ND
OR 0
TCDF
5.18
3.70
2.91
5.49
ND
5.72
0.39
2.66
1.23
ND
8.22
26.57
2.66
0.36
2.73
ND
1.01
8.84
16.96
ND
1.42
5.50
1.01
0.94
3.60
4.64
4.11
0.87
43.70
9.55
5.55
14.64
7.53
12.46
0.89
2.35
3.34
2.08
16.91
8.80
3.95
PECDF
ND
0.69
ND
1.85
0.29
0.76
ND
1.69
ND
ND
ND
0.96
0.35
ND
1.34
ND
ND
0.74
4.35
ND
ND
ND
ND
ND
2.03
0.55
0.66
ND
12.69
ND
ND
1.60
0.89
1.35
ND
ND
0.38
ND
ND
ND
ND
P9/9
23478
PECDF
0.99
2.43
1.12
5.92
3.06
1.90
ND
4.11
0.33
ND
ND
ND
1.55
ND
5.44
ND
ND
1.41
14.85
ND
ND
ND
ND
1.39
3.04
0.71
2.41
1.65
25.28
2.49
0.66
4.33
2.14
3.86
ND
ND
1.22
ND
14.30
0.20
ND
123478
HXCDF*
ND
0.19
ND
ND
1.46
0.50
ND
0.71
0.30
ND
ND
ND
ND
ND
7.32
1.01
ND
1.44
1.65
ND
ND
ND
ND
ND
2.30
ND
0.82
ND
2.44
ND
ND
ND
1.17
0.29
ND
ND
0.29
ND
4.06
NO
ND
123678
HXCDF
ND
ND
ND
ND
0.31
ND
ND
1.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.38
ND
ND
ND
ND
ND
2.52
ND
ND
ND
4.14
ND
ND
0.65
0.44
0.40
ND
ND
ND
ND
1.49
ND
ND
123789 234678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
0.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HXCDF
1.39
ND
ND
ND
1.09
0.31
ND
0.38
ND
ND
ND
ND
2.77
ND
5.61
0.60
ND
0.36
0.80
ND
ND
ND
ND
ND
0.29
ND
ND
ND
1.26
ND
0.38
ND
ND
ND
0.20
ND
0.24
ND
1.97
ND
ND
1234678 1234789
HPCDF
OR 3
ND
0.19
ND
0.92
0.42
ND
0.61
0.37
0.53
0.19
0.42
3.46
ND
13.16
0.94
ND
0.49
0.95
ND
ND
1.32
ND
ND
2.00
ND
3.12
ND
ND
ND
ND
0.50
0.77
0.35
ND
ND
0.41
ND
1.71
OR ND
OR ND
HPCDF
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
OR ND
DPE
TEC
39.02
1.96
0.87
3.60
2.31
2.81
0.05
4.71
1.22
0.01
7.88
20.51
2.32
0.04
10.18
0.97
0.45
2.21
16.63
ND
0.29
4.85
0.10
1.43
5.59
1.73
10.88
8.18
27.16
3.54
2.29
16.90
6.61
12.40
0.60
2.53
4.38
0.94
35.03
2.34
1.76
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y.
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3125 DE022301 F WB Carp
3125 DE022302 F PF White Bass
3125 OD 120888 L PF White Bass
3132 DE023201
3132 DE023202
3134 DE023401
3134 DE023403
3134 DE02340S
3134 DE023406
3135 DE023501
3136 DE023602
3137 DE023701
3137 DE023702
3138 DE023801
3138 OE023802
3140 DE024002
3141 DE024102
3141 DE024103
3141 SE024102
3143 DE024401
3143 DE024402
3143 DE024403
3144 DE024901
3 US DE026601
3145 00071988
3146 DE026701
3146 DE026702
3146 QD060288
3146 SE026701
3147 DC035201
3148 DE027101
3148 DE027103
3149 DC038501
3150 DA008901
3151 DA009101
3151 OA009102
3151 QD072887
3152 DA009201
3161 OC019801
3161 DC019802
3162 DJ022121
UB Carp
US Channel Catfish
PF Crappie
UB Carp
UB Carp
UB Sucker
UB Carp
PF Walleye
UB Redhorse Sucker
PF Walleye
UB Carp
PF Sm Bass
UB Carp
UB Carp
PF Northern Pike
UB Carp
Rotten (catf)
PF White Bass
UB Carp
UB Carp
UB N. Redhorse
UB N. Redhorse
UB Carp
PF Walleye
UB Carp
UB Carp
UB Carp
UB Carp
PF Walleye
UB White Sucker
UB White Sucker
UB Uhite Sucker
PF Sm Bass
UB Uhite Sucker
UB Uhite Sucker
BF Black Bullhead
WB Uhite Sucker
UB Big Skate
2378
TCDD
2.15
0.41
0.29
8.58
14.75
0.16
NO
1.99
0.59
1.22
ND
NO
NO
4.99
ND
1.50
20.31
1.70
16.79
ND
ND
0.91
1.25
0.86
0.78
4.56
0.24
5.02
4.31
2.49
3.46
NO
ND
13.51
7.87
0.89
8.20
7.82
ND
1.52
2.86
12378
PECDD
1.43
ND
ND
2.19
2.48
ND
0.53
1.14
ND
ND
ND
ND
ND
OR 2
ND
ND
22.39
OR 1
17.14
ND
ND
2.58
0.51
ND
0.33
2.78
ND
3.44
2.92
0.52
2.42
ND
ND
12.01
2.89
ND
2.95
0.40
0.73
2.68
4.61
123478
HXCDD
1.04
ND
ND
0.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
3.98
ND
ND
0.73
ND
ND
ND
1.87
ND
ND
2.53
ND
1.17
ND
OR ND
2.01
ND
ND
ND
ND
0.78
2.11
ND
123678
HXCOD
2.53
ND
ND
5.41
12.20
ND
0.48
1.16
ND
1.25
ND
ND
ND
QR ND
0.31
1.77
18.52
0.87
17.26
ND
ND
4.74
ND
0.96
0.70
13.68
ND
17.34
14.27
0.70
2.89
ND
QR ND
9.25
1.85
ND
2.15
3.20
1.50
3.13
6.59
DIOXIN
123789
HXCDD
ND
ND
ND
0.92
2.68
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
5.03
NO
3.54
ND
ND
0.96
ND
ND
ND
ND
ND
2.30
1.89
ND
0.62
ND
QR ND
3.92
1.19
ND
0.59
ND
0.25
0.38
ND
/ FURAN CONCENTRATIONS,
1234678 2378 12378
HPCOD
8.19
2.03
1.30
QR 7
4.91
ND
1.83
3.20
0.58
3.67
ND
0.78
ND
OR ND
1.25
4.87
43.71
2.12
37.99
3.11
0.62
20.56
2.43
1.22
1.48
47.38
0.88
49.70
47.34
2.96
5.59
0.57
ND
16.10
3.13
ND
3.25
0.50
2.14
8.54
5.41
TCDF
23.36
7.87
7.36
5.63
6.13
0.90
6.71
1.75
32.60
3.99
ND
10.63
ND
4.30
1.80
1.28
2.91
OR 9
2.48
1.82
2.66
12.10
2.05
15.11
14.76
10.22
0.93
11.10
9.02
8.73
8.54
3.54
1.40
21.84
43.19
1.67
43.55
81.2
0.81
11.05
59.62
PECDF
2.30
ND
ND
ND
ND
ND
1.61
0.76
1.29
ND
ND
ND
ND
QR 1
ND
ND
2.59
0.74
2.07
ND
0.45
2.74
0.38
0.22
ND
1.12
ND
1.44
1.10
1.34
2.46
ND
ND
3.51
0.90
ND
0.98
4.09
0.40
1.40
22.62
pg/g
23478
PECDF
3.61
ND
0.46
6.09
3.27
ND
7.16
10.68
4.37
ND
ND
ND
ND
OR ND
0.40
1.08
20.21
1.94
15.68
ND
0.26
2.54
1.90
0.47
0.35
2.76
ND
2.50
2.67
2.05
4.27
0.43
ND
ND
1.87
0.22
2.01
4.35
1.13
3.45
19.21
123478
HXCOF*
1.49
ND
ND
2.12
2.50
ND
0.76
0.40
ND
ND
ND
ND
ND
OR ND
ND
ND
3.16
ND
3.02
ND
ND
1.20
ND
ND
ND
1.17
ND
1.32
1.14
0.90
1.70
ND
QR ND
6.51
1.31
ND
1.09
1.30
ND
2.56
8.03
123678
HXCDF
1.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
5.79
ND
3.81
NO
ND
ND
ND
ND
ND
1.76
ND
2.65
2.25
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
0.91
4.90
123789
HXCDF
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
0.51
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
1.35
2.61
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
NO
1.69
ND
1.65
ND
ND
1.07
ND
ND
ND
0.62
ND
0.78
0.50
0.32
0.75
ND
QR NO
2.57
ND
ND
1.02
ND
ND
2.44
ND
1234678 1234789 DPE
HPCDF
0.82
NO
NO
1.01
2.52
ND
ND
ND
ND
0.64
ND
ND
ND
QR ND
ND
ND
5.26
0.16
4.31
ND
ND
4.19
ND
ND
ND
3.55
ND
3.79
3.11
ND
1.45
ND
ND
4.03
1.27
0.22
ND
ND
ND
3.55
ND
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
0.49
ND
ND
ND
ND
ND
ND
ND
TEC
7.84
1.22
1.27
14.34
20.31
0.25
4.74
8.30
6.11
1.79
ND
1.07
ND
5.42
0.42
2.39
45.94
2.82
28.50
0.21
0.42
5.93
2.70
2.73
2.68
10.83
0.34
12.15
7.89
4.94
8.57
0.57
0.14
24.56
15.09
1.17
15.60
18.97
1.31
7.03
23.87
Y
Y
V
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3162 DJ022122
3162 OJ022123
3162 DJ022403
3162 DJ024001
3162 DJ025103
3162 QD041889
3163 DJ022402
3163 DJ022404
3163 DJ024002
3163 DJ025102
3164 DD015701
3164 DD015702
3165 DD015703
3165 DD015704
3165 QD031788
3166 00015705
3166 DD015706
3167 DD015707
3167 OD015708
3167 QD040588
3167 SD015708
3168 DD015711
3168 DD015712
3168 SD015711
3169 DD015713
3170 DD015715
3171 DD015717
3172 DD015719
3172 DD015720
3173 DD015721
3173 DD015722
3173 OD070689
3174 DD015723
3174 DD015724
3175 DD015801
3175 DD015802
3176 DD015803
3176 DDO15804
3177 DD015805
3177 DD015806
3178 DD015807
F UB Ratfish
M Dungeness Crab
F PF Quillback Rockfish
F UP Starry Flounder
0 Hepatopancreas,Crab
L Hepatopancreas
N Dungeness Crab
M Dungeness Crab
F UP Starry Flounder
0 Hepatopancreas,Crab
PF Lm Bass
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Lm Bass
PF Walleye
UB White Sucker
PF Lm Bass
UP Bluegill
PF Lm Bass
UP Bluegill
UB Carp
PF Lm Bass
UB Carp
UB Black Redhorse
UB Spotted Sucker
UB Spotted Sucker
UB Carp
PF Lm Bass
PF Lm Bass
UB Channel Catfish
PF Lm Bass
PF Lm Bass
UB Channel Catfish
UB Channel Catfish
PF Lm Bass
F UB Spotted Sucker
F PF Lm Bass
F UB Carp
F PF Lm Bass
F UB North Hogsucker
2378
TCDD
5.04
NO
NO
2.43
6.61
10.79
5.44
ND
1.51
5.67
ND
5.66
NO
1.53
0.48
NO
NO
2.22
7.3
2.83
6.72
8.84
2.30
7.88
NO
ND
ND
1.40
0.15
ND
1.39
ND
ND
ND
3.31
ND
ND
ND
ND
ND
ND
12378
PECDD
ND
ND
ND
4.72
10.17
15.90
6.43
0.94
1.21
6.10
OR ND
9.94
NO
5.07
NO
NO
NO
3.59
11.5
4.44
11.01
2.60
ND
2.56
ND
ND
ND
OR 1
ND
ND
0.86
ND
ND
ND
3.82
ND
ND
ND
ND
ND
ND
123478
HXCDD
ND
ND
ND
ND
3.46
4.89
ND
ND
ND
ND
ND
ND
ND
3.52
NO
ND
ND
ND
14.3
1.88
11.80
3.64
ND
3.85
OR ND
0.39
ND
1.63
ND
ND
ND
ND
ND
ND
0.97
ND
NO
ND
0.70
ND
ND
123678
HXCDD
2.17
ND
ND
9.58
26.28
34.02
27.72
2.22
2.30
17.82
1.93
24.87
2.92
12.40
3.09
ND
0.40
6.40
37.3
7.28
44.20
10.96
ND
9.51
QR ND
0.89
ND
3.09
ND
ND
1.69
ND
ND
ND
5.50
0.31
2.03
ND
1.74
ND
ND
DIOXIN
123789
HXCDD
ND
ND
ND
0.66
5.10
6.67
ND
ND
ND
2.67
0.22
3.53
ND
ND
ND
ND
ND
ND
8.5
ND
7.87
1.35
ND
ND
QR ND
0.28
ND
0.86
ND
ND
0.32
ND
ND
ND
1.25
ND
ND
ND
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
ND
2.25
ND
3.48
37.12
48.32
15.99
1.79
1.11
15.31
1.69
50.79
4.41
14.19
4.47
0.86
1.24
10.52
111.9
14.49
110.12
QR 39
0.45
34.26
QR ND
4.55
0.59
11.64
0.70
ND
2.30
ND
ND
0.36
6.72
0.62
1.63
ND
7.14
0.75
0.74
TCDF
145.88
26.47
1.09
9.80
334.80
403.90
67.41
49.18
3.00
206.62
0.31
4.61
0.43
4.37
ND
ND
1.88
ND
ND
ND
0.34
14.62
4.90
13.94
2.30
0.84
0.49
9.69
1.37
ND
1.61
ND
ND
0.28
ND
ND
1.54
ND
1.24
ND
ND
12378
PECDF
9.81
10.81
ND
5.88
99.62
120.30
3.70
19.65
ND
68.35
QR NO
1.59
ND
0.84
ND
ND
ND
ND
1.3
NO
1.03
1.19
ND
0.85
ND
ND
ND
0.92
ND
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
pg/g
23478
PECDF
18.12
3.23
ND
13.58
45.72
56.37
4.11
6.40
1.09
34.48
QR ND
4.14
0.33
3.04
0.30
ND
0.23
ND
ND
ND
0.79
2.10
ND
1.92
ND
ND
ND
ND
ND
ND
1.43
ND
ND
ND
0.65
ND
ND
ND
0.34
ND
ND
123478
HXCOF*
1.64
3.09
ND
5.36
37.49
45.33
2.28
5.80
0.19
19.73
0.40
2.41
2.22
6.65
1.91
ND
ND
3.74
13.8
3.61
1.50
0.52
ND
0.33
QR NO
ND
ND
0.22
ND
ND
ND
ND
ND
ND
1.88
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
2.12
ND
2.22
27.93
30.86
2.16
ND
ND
13.12
ND
2.09
ND
ND
ND
ND
ND
1.21
7.0
ND
5.24
ND
ND
ND
QR ND
ND
ND
0.30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
3.35
3.71
ND
ND
ND
ND
0.33
ND
1.68
5.40
1.12
ND
ND
3.92
19.3
4.67
0.87
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.79
ND
ND
ND
0.92
ND
ND
1234678 1234789 DPE
HPCDF
ND
ND
ND
0.93
10.86
13.91
3.71
ND
0.35
4.52
0.31
3.99
1.66
6.36
1.45
ND
ND
10.12
58.3
10.68
9.43
QR NO
ND
ND
QR ND
0.36
ND
0.23
ND
ND
0.25
ND
ND
ND
2.73
ND
ND
ND
1.31
ND
0.27
HPCDF
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.5
ND
0.94
QR ND
ND
ND
QR ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
29.56
5.35
0.11
14.68
83.86
106.50
21.05
10.39
3.22
55.57
0.34
17.08
0.95
9.07
1.30
0.01
0.36
5.75
24.84
7.05
15.20
14.36
2.79
11.40
0.23
0.29
0.05
3.14
0.29
ND
2.94
ND
ND
0.03
6.68
0.04
0.37
ND
0.71
0.01
0.01
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3178 DD015803
3179 DD015809
3179 DD01S810
3180 DD015812
3181 DD015813
3181 DD015814
3182 OD015815
3182 OD015816
3183 DD015817
3183 OD015818
3184 OD015819
3184 DD01S820
3185 DD015821
3185 DD015822
3185 SD015821
3186 DD015823
3186 D0015824
3187 DD015902
3188 ODD 15903
3188 DDO 15904
3189 OD015905
3189 DD015906
3190 00015907
3190 DD015908
3191 DJ024003
3191 DJ024005
3192 OJ024007
3192 DJ024009
3192 Q0020789
3193 DC039001
3193 QD039001
3195 DH020104
3195 OH020105
3196 DH020108
3197 DH020110
3198 DH020111
3199 DH020101
3199 DH020103
3200 DH020112
3201 DJ024012
3203 DJ02401B
PF Redeye Bass
WB Golden Redhorse
PF Lm Bass
PF Lm Bass
PF Lm Bass
WB Carp
PF Rock Bass
UB Carp
UB Carp
PF Sauger
UB Carp
PF White Crappie
WB Channel Catfish
PF Lm Bass
WB Channel Catfish
PF Spot
WP Southern Flounder
WP Summer Flounder
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WP Starry Flounder
Soft Shell Clems
WP Starry Flounder
Soft Shell Clams
Soft Shell Clams
PF Sm Bass
PF Sm Bass
WB Carp
WB Chub
WB Sucker
WB Sucker
WB Sucker
WB Carp
WB Carp
WB Sucker
WB Carp
WB Carp
2378
TCDD
ND
0.31
ND
ND
ND
4.38
ND
ND
4.38
0.67
3.13
ND
4.14
1.50
3.97
ND
0.18
ND
ND
ND
ND
0.84
0.60
5.35
ND
ND
0.45
ND
ND
0.52
ND
ND
2.33
ND
ND
1.53
0.25
ND
0.56
7.66
2.86
12378
PECDD
ND
0.57
ND
ND
ND
2.69
ND
ND
0.93
ND
5.13
ND
12.27
1.81
12.09
ND
ND
ND
2.83
ND
0.76
ND
1.02
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.98
0.28
ND
0.74
0.46
ND
ND
7.83
3.33
123478
HXCDO
ND
ND
ND
ND
ND
2.84
ND
ND
ND
ND
5.98
ND
7.94
0.81
9.37
ND
ND
ND
2.08
ND
OR .6
ND
1.13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.16
ND
ND
ND
ND
ND
2.93
ND
123678
HXCDD
ND
1.36
ND
ND
ND
13.37
0.51
ND
ND
ND
11.09
ND
50.77
8.74
51.84
ND
0.50
0.67
5.48
ND
OR .9
ND
2.56
ND
ND
ND
ND
ND
ND
0.48
ND
ND
0.76
0.58
ND
0.63
0.58
ND
ND
24.79
8.68
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
2.15
ND
ND
ND
ND
2.98
ND
9.49
0.99
8.96
ND
ND
0.34
0.77
ND
QR ND
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.25
ND
ND
3.36
1.09
/ FURAN
1234678
HPCDD
ND
3.23
ND
ND
ND
54.47
0.92
3.23
7.76
0.59
53.19
ND
105.15
22.15
106.52
ND
1.47
3.06
11.49
ND
QR 4
ND
10.75
ND
0.5
1.70
0.69
2.35
2.10
2.28
2.82
1.79
2.24
2.26
0.44
1.69
2.21
0.74
0.74
91.72
13.27
CONCENTRATIONS,
2378 12378
TCDF
ND
1.77
ND
ND
ND
3.23
8.63
23.53
3.05
ND
ND
ND
0.32
0.26
0.28
ND
0.23
ND
4.13
ND
1.24
ND
3.58
0.73
ND
1.90
9.06
12.97
13.18
15.86
19.28
ND
7.71
0.18
0.75
9.36
0.43
ND
3.64
1.82
4.10
PECDF
ND
ND
ND
ND
ND
ND
ND
1.02
1.36
ND
ND
ND
ND
0.33
0.49
ND
ND
ND
1.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.38
ND
ND
ND
1.65
0.57
P9/9
23478
PECDF
ND
ND
ND
ND
ND
4.49
ND
7.02
3.83
ND
ND
ND
ND
0.29
4.76
ND
ND
ND
2.79
ND
0.54
ND
0.80
ND
ND
ND
0.23
ND
ND
0.80
1.02
ND
0.73
ND
ND
0.66
ND
ND
0.34
4.81
2.19
123478
HXCDF*
ND
1.18
ND
ND
ND
4.17
ND
ND
2.47
ND
1.79
ND
16.45
0.72
2.70
ND
ND
ND
1.50
ND
QR .8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.96
ND
ND
ND
ND
ND
2.23
2.88
123678
HXCDF
ND
ND
ND
ND
ND
1.94
ND
ND
0.95
ND
ND
ND
2.96
0.68
2.67
ND
ND
ND
1.12
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.62
0.91
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
1.25
ND
ND
ND
2.29
ND
ND
0.57
ND
0.81
ND
11.85
ND
1.14
ND
ND
ND
0.80
ND
QR .6
ND
0.90
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.67
ND
ND
ND
ND
NO
0.80
1.85
1234678 1234789 DPE
HPCDF
ND
1.25
ND
ND
ND
4.51
ND
ND
1.40
ND
1.53
ND
29.41
1.98
7.76
ND
ND
ND
1.27
ND
0.78
ND
1.66
ND
ND
0.29
0.56
0.49
0.38
ND
ND
0.25
0.24
0.95
ND
ND
0.32
ND
ND
8.88
2.88
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.69
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
ND
1.20
ND
ND
ND
11.56
0.92
5.95
7.62
0.68
8.51
ND
21.60
4.03
13.56
ND
0.27
0.13
4.58
ND
0.78
0.84
2.50
5.42
ND
0.21
1.48
1.33
1.34
2.58
2.47
0.02
4.06
0.43
0.08
3.26
0.63
0.01
1.10
19.02
7.76
Y
Y
V
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3205 DJ024024
3206 DJ022301
3206 DJ024102
3206 DJ024103
3208 OJ024109
3212 DJ024121
3212 OD050388
3216 OJ023707
3216 DJ023708
3216 OD091688
3217 DJ023709
3217 DJ023710
3218 DJ023711
3218 DJ023712
3219 DJ023713
3219 DJ023714
3220 DJ023902
3220 DJ023903
3220 OD012288
3221 DJ022405
3221 DJ023904
3221 DJ023905
3222 DJ023906
3222 DJ023907
3223 DJ023717
3224 DJ023715
3226 DJ023721
3227 DJ023723
3231 DJ023911
3234 DH020301
3235 DH020303
3236 DH020305
3236 OH020306
3237 OH020307
3237 DH020308
3238 DJ023918
3238 OD080888
3241 DJ023924
3244 DJ023622
3245 DJ023623
3245 DJ023624
M Crayfish (whole)
N Crayfish
F PF Ira Bass
F UB Sucker
F UB Sucker
F UB Carp
L UB Carp
F PF Squawfish
F UB Sucker
L UB Sucker
F PF Uhitefish
F UB Sucker
F PF Squawfish
F UB Sucker
F UB White Sturgeon
F PF White Sturgeon
F PF Squawfish
F UB Bridgelip Sucker
L PF Squawfish
F UB Carp
F BF Channel Catfish
F UB Sucker
F PF Squawfish
F UB Sucker
F UP Starry Flounder
N Soft Shell Clams
M Pacific Oysters
H Pacific Oysters
F UB Carp
F UP Squawfish
F UB Uhite Sucker
F UB Largescale Sucker
F PF Brown Trout
F PF Rainbow Trout
F UB Largescale Sucker
F UP Dolly Varden
L UP Dolly Varden
F UP Dolly Varden
F UB Coast Sculpin
F UP Spotted Ratfish
F UP Flathead Sole
2378
TCOD
ND
2.61
0.74
2.25
ND
0.70
0.87
1.28
2.57
2.01
4.58
0.76
1.73
2.78
2.14
0.36
1.48
5.23
1.75
56.02
7.92
5.12
1.14
2.28
1.57
ND
ND
ND
0.79
ND
0.33
0.53
ND
ND
ND
ND
ND
0.53
ND
ND
ND
12378
PECDD
ND
3.75
ND
3.31
ND
ND
ND
0.95
0.68
0.55
1.56
0.27
0.78
ND
ND
ND
0.49
0.68
ND
1.67
0.34
0.23
NO
0.32
ND
ND
ND
ND
1.20
ND
0.50
0.72
0.91
ND
ND
ND
ND
ND
ND
ND
0.24
123478
HXCDD
ND
ND
ND
1.10
ND
ND
NO
ND
ND
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.75
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
ND
10.05
0.82
4.06
ND
ND
ND
0.80
0.90
0.77
1.79
ND
0.77
0.66
ND
ND
0.56
ND
ND
1.34
0.37
ND
0.20
0.45
0.42
1.48
ND
ND
2.93
ND
0.94
1.00
ND
ND
ND
ND
ND
0.57
ND
ND
ND
D10XIN
123789
HXCDD
ND
1.42
ND
0.61
ND
ND
ND
ND
0.18
0.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
0.49
34.42
0.43
16.57
0.56
0.77
ND
0.90
5.86
4.66
2.47
0.54
2.00
ND
0.52
0.37
1.16
2.20
ND
ND
2.70
0.33
ND
1.65
2.37
34.14
ND
7.49
6.88
0.91
2.77
2.80
ND
ND
ND
0.79
0.77
0.58
1.62
0.44
1.59
TCDF
ND
48.14
1.09
3.35
1.69
ND
ND
9.03
11.38
10.27
16.12
2.43
21.63
16.39
61.58
8.02
20.12
28.34
20.73
320.69
4.97
41.78
11.95
15.95
11.58
0.49
.29
.74
9.14
D
.02
.73
.42
.67
2.98
0.37
0.37
3.13
0.45
0.22
ND
12378
PECDF
ND
54.32
ND
0.91
ND
ND
ND
0.51
0.28
ND
ND
ND
0.29
ND
0.64
ND
0.21
0.30
ND
3.52
ND
ND
ND
ND
ND
ND
ND
ND
0.65
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
P9/9
23478
PECDF
ND
19.02
0.34
2.27
ND
ND
ND
0.59
0.44
0.43
0.45
ND
0.36
ND
0.33
ND
ND
0.67
0.26
7.32
1.09
0.55
0.21
0.25
ND
ND
ND
ND
ND
ND
0.34
0.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCDF*
ND
18.85
ND
3.02
ND
ND
ND
ND
ND
ND
0.60
0.40
ND
0.60
ND
ND
ND
ND
ND
ND
ND
0.20
ND
ND
ND
0.25
ND
ND
0.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
10.15
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
0.87
ND
1.16
ND
ND
NO
ND
ND
ND
0.36
0.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234678 1234789
HPCDF
ND
6.44
0.24
2.66
ND
ND
ND
ND
0.76
0.65
0.40
ND
ND
0.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.24
0.26
3.06
ND
2.14
0.91
ND
0.20
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
HPCDF
ND
1.76
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
ND
26.11
1.11
6.61
0.17
0.71
0.87
3.07
4.46
3.68
7.54
1.21
4.57
4.55
8.50
1.17
3.82
8.78
3.95
92.89
9.20
9.71
2.46
4.22
2.80
0.59
0.13
0.31
2.80
0.01
0.98
1.59
0.60
0.17
0.30
0.04
0.04
0.91
0.06
0.03
0.14
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3246 DJ022108
3246 DJ022109
3248 DJ022502
3249 DJ022504
3250 DJ022506
3252 DJ022510
3252 OD082288
3256 DJ022517
3256 DJ02251B
3258 DC038901
3258 DC038902
3259 DB000466
3259 DB069101
3260 DB000493
3261 DY026002
3262 OY026004
3264 DY022602
3266 DY022702
3267 DY022101
3267 DY022102
3267 QD020288
3269 DY022106
3270 DY022107
3270 DY022108
3270 SY022108
3271 DY022110
3272 DY022111
3272 DY022112
3273 DY022113
3273 DY022114
3274 DY022116
3275 DY022118
3276 DY022119
3276 DY022120
3278 DY022124
3281 DY022205
3282 DY022207
3283 DY022209
3285 DY022212
3285 DY022213
3286 OY022215 F
PF Red Striped Rockfish
UP Flathead Sole
UB Composite Bottom
UB Sucker
UB Sucker
UB Sucker
UB Sucker
PF Sm Bass
UB Sucker
PF Spot
UB Croaker
UB Goldfish
UB Sucker
UB Carp
UB Striped Hullet
UB Tilapia Tilapia
UB Hornyhead Turbot
UB Channel Catfish
PF Rainbow Trout
UB Sacramento Sucker
PF Rainbow Trout
UB Channel Catfish
PF Squawfish
UB Sucker
UB Sucker
UB Sucker
PF Leopard Shark
UB White Surfperch
UB Sculpin
UB Surf Smelt
UB Sculpin
UB Sucker
UB Walleye
PF Broun Rockfish
UB Sacramento Sucker
UB Sucker
UB Carp
UB Carp
UP Stingray
UB Diamond Turbot
UB Carp
2378
TCDD
ND
ND
ND
ND
ND
0.58
0.48
0.74
0.46
1.52
ND
1.20
1.89
0.96
0.76
0.33
4.08
0.47
11.74
6.35
11.26
ND
6.84
6.45
5.60
0.21
ND
1.27
0.63
ND
ND
ND
0.68
ND
ND
ND
ND
0.93
1.91
ND
1.59
12378
PECDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR 1
ND
ND
ND
ND
3.99
ND
ND
ND
ND
0.91
0.83
ND
ND
ND
ND
2.98
ND
ND
ND
ND
0.43
ND
ND
ND
ND
0.78
1.65
2.40
1.48
123478
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.81
ND
0.90
123678
HXCDD
ND
ND
ND
ND
0.40
ND
0.44
ND
ND
ND
0.87
4.07
1.37
ND
1.15
0.81
4.93
ND
ND
ND
ND
1.33
0.63
ND
ND
0.42
0.47
2.46
0.71
ND
ND
ND
0.78
0.31
ND
ND
ND
0.48
3.15
2.34
3.26
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.46
ND
ND
0.31
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
0.16
ND
ND
ND
ND
ND
0.96
0.63
0.38
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
ND
0.34
2.18
0.86
2.25
0.96
0.97
0.28
0.73
ND
2.80
5.87
2.40
2.91
4.17
15.08
3.25
1.22
ND
0.64
1.69
4.08
ND
0.62
0.47
1.22
1.70
4.84
1.47
0.54
0.73
0.32
2.42
3.12
0.74
0.72
ND
1.32
8.69
5.05
5.33
TCDF
ND
0.35
0.86
0.75
1.95
2.31
2.19
2.75
2.62
5.05
ND
0.93
24.73
6.65
3.48
ND
3.49
0.61
106.94
61.40
99.67
0.36
35.81
55.75
44.52
0.27
0.52
17.98
0.64
1.06
0.39
ND
1.54
0.61
ND
ND
1.57
3.96
12.90
0.79
1.81
12378
PECDF
ND
ND
ND
ND
ND
NO
ND
ND
ND
1.76
0.64
ND
0.96
0.42
0.71
ND
ND
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
1.82
0.47
NO
ND
ND
ND
ND
ND
ND
ND
0.50
2.67
ND
0.53
pg/9
23478
PECDF
ND
ND
ND
ND
0.44
ND
0.23
ND
ND
3.96
ND
2.72
5.53
0.52
1.54
ND
2.36
0.76
0.54
ND
0.60
0.73
0.54
ND
0.30
ND
ND
3.90
0.49
ND
ND
ND
0.22
0.16
ND
ND
0.53
0.95
7.30
1.85
1.35
123478
HXCDF*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.25
0.59
ND
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
0.76
ND
ND
ND
ND
ND.
ND
ND
ND
0.22
0.66
NO
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.63
0.56
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
0.33
ND
ND
ND
0.94
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
ND
1234678 1234789 DPE
HPCDF
ND
ND
0.23
ND
0.30
ND
ND
ND
0.23
ND
0.40
0.42
0.23
ND
1.54
3.48
0.35
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.67
ND
ND
ND
0.28
0.17
ND
ND
ND
0.26
0.46
ND
0.53
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
TEC
ND
0.04
0.11
0.08
0.48
0.82
0.87
1.02
0.73
4.09
0.21
3.28
7.39
1.94
2.33
0.60
8.13
0.92
22.72
12.50
21.54
1.03
11.17
12.03
10.08
0.29
0.12
6.97
1.20
0.11
0.05
ND
1.28
0.20
0.01
0.01
0.42
2.30
8.50
2.61
3.78
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC Type Description
3287 DY022216
3288 DY022218
3288 QD060188
3289 DY022219
3289 DY022220
3290 DY022221
3290 DY022222
3294 DJ022111
3294 DJ022113
3295 DJ022114
3296 DB040101
3297 DB041501
3297 DB041504
3297 SB041S01
3298 DB041601
3298 DB041604
3298 QD 11 2988
3299 DB040601
3299 DB040604
3300 DB040201
3300 DB040204
3300 SB040201
3301 DB041101
3301 DB041104
3301 QD092088
3301 SB041101
3302 DB041901
3302 DB041904
3303 DB042301
3304 DB041001
3304 DB041004
3305 DB042001
3305 DB042004
3306 DB041801
3307 DB042101
3307 OD100588
3308 DB040001
3308 QD0306B9
3309 DB041301
3310 DC032701
3310 DC032702
UB Tilapia Zilli
UB Sucker
UB Sucker
UP Bocaccio
UB Sculpin
PF Redear Sunfish
UB Blackfish
UP True Cod
Mussel
UP Atlantic Salmon
UB White Sucker
UB Carp
PF Sin Bass
UB Carp
UB Carp
PF Lm Bass
PF Lm Bass
UB White Sucker
PF Lm Bass
UB White Sucker
PF Sm Bass
UB White Sucker
UB Carp
PF Northern Pike
UB Carp
UB Carp
UB White Sucker
PF Lm Bass
UB White Sucker
PF Northern Pike
UB White Sucker
UB Channel Catfish
PF Sm Bass
UB White Sucker
F UB White Sucker
L UB White Sucker
F PF Northern Pike
L PF Northern Pike
F UB White Sucker
F UB Bullhead
F PF Walleye
2378
TCDD
0.54
NO
ND
ND
ND
ND
2.39
ND
ND
ND
ND
6.40
ND
5.42
3.49
ND
ND
1.35
1.24
9.83
2.40
8.27
33.70
0.74
35.07
32.01
8.76
0.98
1.15
0.70
1.70
12.82
ND
1.01
1.38
1.30
ND
ND
0.24
1.20
ND
12378
PECOD
NO
ND
ND
ND
ND
ND
6.38
ND
ND
ND
ND
1.97
ND
1.86
4.34
ND
ND
1.61
0.49
1.13
ND
0.99
6.92
ND
6.91
6.17
0.96
ND
0.25
ND
0.93
3.22
ND
ND
ND
ND
ND
ND
ND
1.38
ND
123478
HXCDD
ND
ND
ND
ND
ND
ND
2.60
ND
ND
ND
ND
ND
ND
0.55
0.88
ND
ND
0.36
ND
ND
ND
ND
2.43
ND
ND
2.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.61
ND
123678
HXCDD
ND
ND
ND
ND
ND
ND
7.92
ND
ND
0.25
ND
1.63
ND
1.44
5.51
ND
ND
0.83
ND
ND
ND
ND
12.17
ND
13.07
11.83
ND
ND
0.63
ND
0.87
2.07
ND
ND
ND
ND
ND
ND
0.42
2.71
ND
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
1.29
NO
ND
ND
ND
0.24
ND
ND
1.21
ND
ND
ND
ND
ND
ND
ND
1.57
ND
1.89
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
/ FURAN CONCENTRATIONS.
1234678
HPCDD
7.30
0.56
0.43
2.74
0.68
1.44
15.80
ND
ND
1.81
0.42
2.13
0.59
1.62
17.01
ND
ND
0.88
0.66
0.58
ND
0.42
17.82
ND
18.99
16.97
0.68
0.39
4.11
ND
1.67
1.57
ND
0.84
0.81
ND
ND
ND
4.78
3.60
0.42
2378
TCDF
3.61
1.95
2.01
0.76
0.84
ND
22.07
0.94
ND
1.44
2.90
8.82
ND
7.14
2.62
ND
ND
4.65
1.32
7.33
0.70
7.18
7.30
1.67
7.92
7.37
6.53
ND
9.10
0.91
22.64
3.00
2.43
12.34
8.67
9.73
0.63
0.68
1.41
2.16
0.69
12378
PECDF
ND
ND
ND
ND
ND
ND
1.97
ND
ND
ND
ND
6.39
ND
5.83
1.04
ND
ND
5.50
0.85
1.20
ND
1.02
6.38
ND
6.16
5.60
0.92
ND
ND
ND
0.93
0.57
ND
0.65
ND
0.31
ND
ND
ND
1.39
ND
pa/a
23478
PECDF
ND
0.30
0.35
ND
ND
ND
4.75
ND
ND
ND
0.58
22.67
1.85
20.80
3.89
ND
ND
42.58
5.48
4.94
ND
4.80
27.29
ND
26.30
26.09
4.36
ND
0.48
ND
1.88
8.86
ND
2.20
0.71
0.75
ND
ND
ND
4.21
ND
123478
HXCDF*
ND
ND
ND
ND
ND
ND
3.90
ND
ND
ND
ND
37.92
1.34
36.53
1.07
ND
ND
30.77
3.08
1.46
ND
1.32
15.44
ND
15.98
16.73
0.78
ND
ND
ND
ND
1.15
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
1.29
ND
ND
ND
ND
13.84
0.35
10.77
1.83
ND
ND
8.31
ND
ND
ND
ND
12.72
ND
13.95
10.07
ND
ND
ND
ND
ND
0.65
ND
ND
ND
ND
ND
ND
ND
1.00
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
ND
ND
1.81
ND
ND
ND
ND
ND
ND
0.85
0.83
ND
ND
1.42
ND
ND
ND
ND
1.37
ND
1.54
1.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234678
HPCDF
1.35
ND
ND
ND
ND
ND
3.29
ND
ND
ND
ND
11.76
ND
10.22
3.02
ND
ND
6.38
0.58
0.32
ND
ND
9.26
ND
9.56
8.46
0.56
ND
0.99
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.88
ND
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.47
ND
ND
ND
ND
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
0.99
0.35
0.38
0.10
0.09
0.01
12.33
0.09
ND
0.19
0.58
25.43
1.10
10.30
9.25
ND
ND
28.43
4.72
13.81
2.47
10.08
56.69
0.91
57.70
39.87
12.21
0.98
2.54
0.79
5.52
19.59
0.24
3.38
2.61
2.66
0.06
0.07
0.49
4.79
0.07
Y
V
Y
-------
Episode SCC Type Description
3311 DC032801
3311 DC032802
3312 DC033101
3312 DC033102
3313 DC033201
3313 DC033202
3314 DC033301
3314 OC033302
3314 SC033301
3314 SC033302
3315 DC033401
3316 DC033501
3316 DC033502
3317 DC033601
3317 DC033602
3317 SC033601
3317 SC033602
3318 DC033701
3318 DC033702
3319 DB041401
3319 OD063088
3320 DB041412
3321 DB040401
3322 DB040412
3323 DB041206
3324 DB041252
3325 DB041218
3325 OD082988
3326 DB041208
3327 DB040301
3327 DB040315
3328 DD029111
3328 DD029112
3328 SD029111
3328 SD029112
3329 DD016003
3329 SD016003
3330 DD029109
3330 DD029110
3330 DD029423
3331 DD016001
F WB Redhorse Sucker
F PF Sm Bass
F WB Redhorse Sucker
F PF Sm Bass
F WB Redhorse Sucker
F PF Sm Bass
F WB Channel Catfish
F PF White Bass
F WB Channel Catfish
F PF White Bass
F WB Carp
F WB White Sucker
F PF Brown Trout
F WB White Sucker
F WP Pumpkinseed
F WB White Sucker
F WP Punpkinseed
F WB White Sucker
F PF Rock Bass
F WP Winter Flounder
L WP Winter Flounder
F WP Bluefish
F WP Winter Flounder
F WP Bluefish
F WP Winter Flounder
F WP Bluefish
F WP Bluefish
L WP Bluefish
F WP Bluefish
F WP Bluefish
F WP Bluefish
F WB Carp
F PF Lm Bass
F WB Carp
F PF Lm Bass
F WB Bowfin
F WB Bowfin
F PF Suwannee Bass
F WB Spotted Sucker
F PF Black Crappie
F WB Brown Bullhead
2378
TCDO
ND
NO
ND
ND
3.65
0.55
56.34
7.20
47.10
6.22
ND
5.79
3.55
58.21
35.50
46.57
29.85
1.71
0.41
ND
1.2
0.75
2.39
1.16
0.69
1.74
0.71
0.52
1.07
2.92
30.04
8.78
23.83
7.24
13.19
11.46
ND
1.21
ND
5.96
12378
PECDD
ND
ND
0.36
ND
0.41
ND
1.02
ND
0.91
ND
0.59
0.57
ND
0.32
ND
ND
ND
ND
ND
ND
ND
ND
0.37
ND
ND
NO
ND
ND
ND
ND
0.88
ND
0.72
ND
0.65
0.54
ND
1.79
ND
ND
123478
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
0.34
ND
0.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
0.54
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
ND
ND
0.41
ND
0.37
ND
1.95
ND
1.16
ND
0.62
0.37
ND
0.25
ND
ND
ND
0.18
ND
ND
0.4
OR ND
0.34
ND
ND
ND
ND
ND
ND
ND
0.40
1.11
ND
0.75
ND
0.71
0.50
ND
1.12
ND
0.27
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
0.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.22
ND
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
0.53
ND
1.72
0.42
1.45
0.48
4.37
0.37
3.48
ND
4.87
1.52
0.45
0.37
0.43
ND
0.23
0.69
0.38
0.61
0.8
OR ND
0.65
ND
ND
0.72
1.31
0.60
0.60
0.53
0.48
3.64
0.82
2.96
0.47
ND
0.61
1.72
1.35
0.43
1.37
2378
TCDF
6.42
1.05
8.30
2.18
13.51
0.52
8.20
5.84
6.97
5.24
1.52
30.48
3.89
171.06
88.06
144.02
73.02
30.70
4.52
13.73
13.3
1.93
9.09
0.67
4.18
1.65
1.27
1.40
1.47
2.72
13.24
22.04
10.89
21.59
40.76
39.89
ND
1.41
ND
1.18
12378
PECDF
0.64
ND
0.51
ND
0.23
ND
1.76
0.40
1.35
0.33
0.38
1.48
ND
0.39
ND
0.35
0.20
0.31
ND
1.74
1.9
1.06
0.87
0.42
ND
0.48
0.42
0.42
0.46
0.72
0.84
0.82
ND
ND
ND
1.32
1.20
ND
ND
ND
ND
P9/9
23478
PECDF
0.61
ND
0.83
NO
0.71
ND
5.70
0.89
5.14
0.58
0.63
2.13
0.78
0.63
0.28
0.56
0.18
0.46
ND
0.64
0.7
0.93
1.15
0.75
ND
0.88
0.72
0.66
0.70
2.46
4.45
0.30
4.05
0.32
2.21
2.04
ND
0.30
ND
ND
123478
HXCOF*
ND
ND
ND
ND
ND
ND
1.00
0.22
0.93
ND
ND
0.48
0.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.36
ND
0.87
1.02
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
0.59
ND
ND
ND
ND
0.35
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.55
1.39
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.32
ND
ND
ND
ND
ND
1234678
HPCDF
ND
ND
ND
ND
ND
ND
0.79
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.20
1.08
ND
ND
ND
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
0.98
0.10
1.51
0.22
5.62
0.61
61.07
8.27
48.97
6.84
0.96
10.40
4.36
75.84
44.45
61.07
37.19
5.05
0.87
1.79
3.02
1.46
4.14
.62
.11
.38
.23
.02
.60
4.46
5.31
34.27
11.14
25.72
9.43
19.12
16.09
0.02
2.54
ND
6.12
-------
Episode SCC Type Description
3331 DD016002
3331 DD016007
3331 OD016008
3331 SD016008
3332 DD016009
3332 DD016010
3333 DD016011
3333 DD016012
3333 DD029108
3333 QD121588
3334 DD016013
3334 DD016014
3335 DD016015
3335 DD016016
3335 DD029101
3335 DD029102
3335 DD029103
3335 QD081588
3335 SD016015
3336 DD016004
3336 DD016005
3336 DD016006
3336 DD016017
3336 DD016018
3336 OD092288
3337 DD016019
3337 DD016020
3337 QD051388
3338 DD016021
3338 DD016022
3338 DD029107
3339 DD016023
3339 DD016024
3339 OD016023
3340 DD029113
3340 DD029114
3340 SD029114
3341 DD016103
3341 DD016104
3341 OD092788 L
3341 SD016103 F
PF Lin Bass
UB Carp
BF White Catfish
BF White Catfish
WP Spotted Drum
PF Caranx Hippos
PF Bluefish
WB Sea Catfish
PF Weakfish
PF Bluefish
UB Sea Catfish
BF Striped Mullet
WP Spot
PF Spotted Bass
WP Red Drum
WB Southern Flounder
WP Sheepshead
WP Southern Flounder
WP Spot
WP Black Drum
PF Striped Mullet
WP Sheepshead
WP Red Drum
PF Spotted Seatrout
PF Spotted Seatrout
WB Spotted Sucker
PF Lm Bass
WB Spotted Sucker
PF Lm Bass
WB Spotted Sucker
PF Chain Pickerel
WB Carp
PF White Bass
WB Carp
PF Lm Bass
WB Channel Catfish
WB Channel Catfish
PF Lm Bass
WB Catfish
PF Lm Bass
PF Lm Bass
2378
TCDO
4.37
24.04
8.94
8.10
0.63
ND
0.77
3.13
ND
0.98
3.50
ND
24.01
ND
0.82
0.71
40.25
0.70
20.11
ND
2.70
3.53
ND
ND
ND
4.62
0.88
4.88
ND
1.72
0.83
4.75
1.42
4.48
3.77
98.88
82.72
7.75
34.40
6.10
6.68
12378
PECOO
UD
1.17
0.55
0.61
1.12
ND
0.70
0.54
ND
0.78
4.04
ND
2.41
ND
ND
0.39
2.57
0.36
2.08
ND
ND
1.32
ND
ND
ND
1.93
ND
2.23
ND
1.85
ND
1.84
0.28
1.74
ND
3.52
3.33
ND
4.00
ND
ND
123478
HXCDD
ND
ND
ND
ND
0.23
ND
ND
0.24
ND
ND
1.24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.18
ND
1.61
ND
ND
ND
1.40
ND
1.60
ND
1.42
ND
ND
2.28
ND
ND
123678
HXCDD
ND
ND
0.76
0.68
0.90
ND
ND
1.06
ND
0.81
8.02
ND
2.53
ND
ND
ND
1.52
0.75
1.66
0.43
ND
ND
ND
ND
ND
2.53
ND
3.36
ND
7.08
ND
3.15
0.25
3.04
ND
3.70
3.12
ND
9.54
ND
ND
DIOX1N
123789
HXCDD
ND
0.37
0.18
ND
0.29
ND
ND
0.25
ND
ND
1.55
ND
0.71
ND
0.29
ND
ND
0.32
0.59
0.23
ND
0.24
ND
ND
ND
0.86
ND
0.99
ND
0.40
ND
0.68
ND
ND
ND
0.98
0.67
ND
3.75
ND
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
1.09
13.42
1.68
0.96
1.40
ND
0.69
1.06
ND
0.72
5.05
ND
2.72
0.45
1.12
2.42
3.76
2.47
2.25
1.66
1.07
1.00
0.29
0.72
0.58
5.34
0.90
5.41
ND
11.03
ND
20.03
1.79
17.57
ND
5.38
4.94
ND
23.44
ND
ND
2378
TCDF
0.58
7.84
1.48
1.57
2.95
ND
2.50
1.62
ND
2.50
0.71
ND
40.03
1.00
4.99
0.84
9.21
0.92
39.06
0.90
11.62
4.88
0.75
ND
ND
8.09
0.34
8.89
ND
5.87
ND
6.46
2.91
6.79
0.31
10.19
10.28
14.90
18.06
10.92
12.81
12378
PECDF
ND
0.40
ND
ND
0.30
ND
ND
ND
ND
ND
ND
ND
4.52
0.65
3.20
ND
1.40
ND
3.61
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
0.86
ND
0.21
ND
0.23
ND
ND
ND
pg/9
23478
PECDF
ND
ND
0.27
0.21
0.50
ND
0.34
0.43
ND
0.40
ND
ND
5.15
ND
ND
ND
6.06
ND
4.90
ND
ND
ND
ND
ND
ND
0.50
ND
0.75
ND
1.04
ND
2.18
0.74
2.15
ND
1.93
1.83
0.31
3.25
0.26
ND
123478
HXCDF*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.41
ND
0.26
ND
0.71
ND
1.43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.28
ND
1.13
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.09
ND
ND
ND
0.49
ND
0.77
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.86
ND
0.75
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
1.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.97
ND
0.23
ND
0.71
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.23
ND
ND
ND
0.19
ND
ND
ND
ND
ND
1234678
HPCDF
ND
2.75
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
ND
OR ND
ND
ND
0.30
0.21
ND
ND
ND
ND
ND
0.36
ND
0.27
ND
0.89
ND
0.74
ND
0.78
ND
0.39
ND
ND
ND
ND
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OR ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
4.44
25.74
9.61
8.61
1.91
ND
1.55
3.94
ND
1.91
6.72
ND
32.72
0.14
1.57
1.01
45.94
1.10
26.02
0.17
3.87
4.71
0.08
0.01
0.01
7.16
0.92
7.91
ND
4.62
0.83
8.37
2.28
7.98
3.80
103.32
85.75
9.41
41.62
7.32
7.96
Y
T
Y
-------
Episode SCC Type Description
3341 SD016104
3342 DD016105
3342 00016106
3343 DD016107
3343 OD016108
3344 DD016109
3344 DD016110
3344 SD016109
3345 DD016111
3345 DD016112
3345 SD016111
3346 DD016113
3346 DD016114
3346 OD042088
3346 SD016113
3346 SD016114
3347 00016115
3347 00016116
3347 SD01611S
3348 00016117
3348 00016118
3348 00072888
3348 SD016117
3348 SD016118
3349 00016119
3349 00016120
3350 00016121
3350 00016122
3350 QD052688
3351 00016123
3351 00016124
3351 QD021888
3352 DF023723
3352 DF023724
3352 CD091388
3353 DF024121
3353 DF024122
3353 QD024121
3354 DY022301
3354 DY022302
3355 DY022303
UB Catfish
UB Spotted Sucker
PF Bluegill
WB White Sucker
PF Redbreast Sunfish
UB Carp
PF Lm Bass
UB Carp
UB Redhorse Sucker
PF Lm Bass
UB Redhorse Sucker
UB Creek Chubsucker
PF Lm Bass
UB Creek Chubsucker
UB Creek Chubsucker
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
PF White Perch
UB Blue Catfish
UB Blue Catfish
PF White Perch
UB Blue Catfish
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
PF Rock Bass
UB Carp
UB Carp
PF Crappie
UB Carp
UB Carp
BF Blue Catfish
UB Sm Buffalo
BF Blue Catfish
UB Carp
PF Lm Bass
UB Carp
2378
TCOD
31.20
2.70
ND
75.70
12.01
22.30
0.93
20.94
5.50
1.44
5.78
143.32
18.24
157.50
156.34
20.88
15.31
3.17
12.58
18.20
104.13
107.02
15.73
87.26
9.10
1.17
3.97
0.48
3.83
0.17
22.07
21.04
ND
1.31
1.23
5.53
5.17
4.83
1.07
ND
13.38
12378
PECDD
3.44
0.94
ND
2.64
ND
2.32
ND
2.60
6.71
1.00
7.69
1.34
ND
1.53
1.44
0.20
2.29
0.32
1.80
1.65
12.48
12.19
1.33
10.81
1.51
ND
4.58
ND
4.40
ND
2.49
1.95
ND
2.55
2.41
0.92
1.68
0.75
3.08
0.49
53.95
123478
HXCDD
1.83
0.91
ND
ND
ND
1.76
ND
1.68
ND
ND
2.44
ND
ND
ND
0.25
ND
2.39
ND
1.80
ND
1.11
1.16
ND
0.93
0.97
ND
1.35
ND
1.47
ND
1.91
2.48
ND
5.39
4.45
ND
1.06
ND
2.62
ND
37.56
123678
HXCDD
9.51
3.13
ND
ND
0.33
6.80
ND
7.26
7.08
1.14
8.34
ND
ND
ND
0.67
ND
ND
0.34
4.82
0.22
2.25
2.25
ND
1.59
3.02
ND
6.82
ND
6.13
ND
5.33
4.44
ND
6.52
5.77
1.82
1.62
1.47
7.54
0.43
89.08
DIOXIN
123789
HXCDD
3.07
0.37
ND
0.51
ND
1.51
ND
1.23
2.69
ND
3.44
ND
ND
ND
0.17
ND
0.95
ND
0.65
ND
0.71
0.81
ND
ND
0.95
ND
1.08
ND
0.91
ND
0.52
ND
ND
1.88
1.68
0.54
0.53
0.47
1.68
ND
24.76
/ FURAN
CONCENTRATIONS,
1234678 2378
HPCDD
18.72
5. OS
0.44
4.43
1.01
33.06
ND
35.39
17.20
2.45
22.01
1.74
0.28
1.18
2.00
0.37
32.23
0.95
27.62
1.85
4.59
4.57
1.18
3.81
16.84
0.81
14.12
ND
13.42
ND
13.53
13.36
1.10
37.95
32.45
5.21
5.08
4.74
25.82
1.47
249.06
TCDF
15.82
24.54
ND
143.88
5.94
3.34
ND
2.84
93.71
1.39
105.13
194.74
20.10
207.38
194.16
23.20
4.11
2.12
3.42
48.49
26.15
27.48
48.32
21.03
10.43
0.56
4.32
ND
3.65
ND
16.09
16.89
ND
0.96
0.86
2.87
19.91
2.74
3.44
ND
1.03
12378
PECOF
ND
0.72
ND
7.20
ND
0.49
ND
0.59
ND
ND
ND
1.25
ND
1.31
1.48
0.21
0.33
ND
0.28
1.97
4.17
4.47
1.43
3.53
0.53
ND
0.93
ND
0.97
ND
1.66
1.64
ND
ND
ND
ND
0.33
ND
1.24
ND
3.08
pg/g
23478
PECDF
2.80
1.16
ND
8.23
NO
ND
ND
2.28
0.68
ND
1.00
9.18
0.48
10.32
12.08
0.64
ND
ND
1.51
1.99
16.58
16.76
1.60
13.10
2.03
ND
2.05
ND
1.93
ND
3.47
3.65
ND
ND
ND
0.33
0.49
ND
2.37
ND
17.07
123478
HXCDF*
ND
0.30
ND
1.40
ND
2.07
ND
0.63
0.36
ND
ND
ND
NO
ND
ND
ND
0.39
ND
0.37
ND
ND
0.42
ND
ND
ND
ND
2.09
ND
1.85
ND
1.73
1.10
ND
ND
ND
ND
ND
ND
1.85
ND
19.67
123678
HXCDF
ND
ND
ND
1.34
ND
ND
ND
0.83
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
0.60
ND
ND
ND
ND
ND
ND
ND
0.84
ND
0.60
ND
1.15
0.94
ND
ND
ND
ND
ND
ND
1.85
ND
13.14
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
ND
ND
0.61
ND
1.89
ND
0.27
ND
ND
ND
ND
ND
ND
ND
ND
0.29
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.39
ND
1.41
ND
3.03
3.48
ND
ND
ND
ND
ND
ND
ND
ND
6.78
1234678 1234789 DPE
HPCDF
ND
0.48
ND
0.85
ND
2.92
ND
1.35
0.48
ND
ND
ND
ND
ND
NO
ND
1.48
0.13
1.31
ND
ND
ND
ND
ND
ND
ND
1.79
ND
1.55
ND
2.83
3.53
ND
ND
ND
ND
ND
ND
3.46
ND
25.42
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.57
TEC
35.38
6.77
ND
96.32
12.65
25.58
0.93
23.27
19.76
2.22
20.83
168.13
20.49
184.24
177.88
23.39
17.62
3.59
14.33
25.01
121.94
124.98
21.53
96.54
12.60
1.23
9.28
0.48
8.80
0.17
28.27
27.02
0.01
4.44
4.04
6.73
8.63
5.72
6.05
0.30
71.02
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-------
Episode SCC
3355 DY022304
3355 SY022303
3356 DE030201
3356 SE030201
3357 DY022223
3357 DY022224
3360 DD029117
3360 DD029118
3360 OD022389
3375 DD016305
3375 DD016306
3375 QD101188
3376 DD016307
3376 DD016308
3376 QD050389
3377 DD016309
3377 DD016310
3377 SD016309
3378 DD016311
3378 DD016312
3378 DD029115
3378 D0029116
3385 DD016401
3395 DD016421
3395 DD016422
3395 SD016421
3401 DD016509
3401 DD016510
3403 DD016513
3403 DD016514
3404 00016515
3404 00016516
3404 SD01651S
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907
3412 SB040907
3414 OC036203
3414 DC036204
Type Description
PF Lm Bass
UB Carp
UB Carp
UB Carp
PF Squawfish
UB Sacramento Sucker
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
UB Spotted Sucker
PF Lm Bass
UB Greyfin Sucker
BF Channel Catfish
UB Redhorse Sucker
UB Redhorse Sucker
PF Lm Bass
UB Redhorse Sucker
UB Carp
PF Lm Bass
UB River Carpsucker
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
UB Carp
PF Sm Bass
BF Channel Catfish
2378
TCDD
NO
15.0
6.55
5.50
0.80
3.47
1.09
ND
NO
5.18
0.83
5.34
7.15
ND
ND
7.15
ND
7.64
0.43
ND
0.36
ND
1.38
49.19
5.48
45.04
3.35
ND
6.59
1.00
12.20
0.67
9.70
2.32
ND
1.10
1.30
28.30
24.40
ND
0.65
12378
PECDD
ND
58.9
9.35
8.95
0.34
0.90
0.52
ND
0.68
5.43
ND
5.78
10.55
ND
ND
12.38
ND
12.28
ND
ND
0.49
ND
ND
3.04
ND
2.56
1.09
ND
6.61
ND
4.78
ND
4.06
4.75
ND
0.70
ND
6.94
5.52
ND
ND
123478
HXCDD
ND
40.0
3.00
2.28
ND
ND
ND
ND
ND
2.88
ND
3.21
7.53
ND
ND
8.29
ND
9.93
ND
ND
0.30
ND
ND
ND
ND
ND
0.74
ND
1.38
ND
1.11
ND
1.14
3.55
ND
ND
ND
1.25
1.21
ND
ND
123678
HXCDD
0.89
113.5
7.77
6.69
0.44
1.40
1.37
ND
2.28
20.42
0.59
22.47
41.95
ND
ND
47.29
ND
50.11
ND
ND
0.78
ND
0.55
2.11
ND
1.56
2.06
10.67
3.07
ND
5.60
ND
4.89
13.63
ND
1.12
ND
6.50
4.54
ND
1.10
DIOXIN
123789
HXCDD
ND
24.9
1.73
1.20
ND
ND
ND
ND
ND
2.68
ND
2.73
5.84
ND
ND
7.77
ND
10.50
ND
ND
ND
ND
ND
0.43
ND
ND
0.43
ND
0.70
ND
1.05
ND
0.85
2.54
ND
ND
ND
0.86
0.65
ND
ND
/ FURAN (
1234678
HPCDD
1.24
283.1
12.44
11.91
ND
2.68
4.73
ND
6.74
93.06
0.85
102.97
138.06
1.22
ND
171.02
ND
161.29
1.91
ND
2.31
ND
1.60
4.81
0.71
4.13
11.70
ND
7.59
ND
9.51
0.87
7.70
34.76
0.34
1.38
ND
8.76
7.67
ND
2.48
:ONCENTR
2378
TCDF
ND
1.2
5.33
5.27
3.71
35.79
2.49
ND
2.91
6.97
1.69
7.59
5.56
ND
ND
8.01
0.43
6.99
9.05
ND
7.13
ND
3.92
273.81
10.96
245.75
12.00
1.00
19.71
2.51
6.29
1.10
6.66
9.19
1.01
4.83
1.16
2.83
2.57
ND
0.56
AT IONS,
12378
PECDF
ND
3.5
3.35
2.63
ND
0.24
ND
ND
ND
2.08
ND
2.35
2.46
ND
ND
3.09
ND
2.77
ND
ND
ND
ND
ND
4.21
ND
3.38
1.05
ND
1.82
ND
0.76
ND
0.58
1.95
ND
ND
ND
1.89
1.70
ND
ND
pg/g
23478
PECDF
ND
19.6
24.81
21.67
0.23
1.25
0.50
ND
0.59
5.93
0.42
6.68
7.16
ND
ND
10.21
ND
8.64
0.46
ND
0.56
ND
0.19
5.15
ND
4.65
2.04
ND
4.47
ND
1.97
ND
1.76
11.86
ND
0.98
ND
20.91
16.80
0.26
2.73
123478
HXCDF*
ND
16.5
2.37
2.31
ND
ND
ND
ND
ND
1.97
ND
2.24
4.59
ND
ND
4.20
ND
4.52
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.59
ND
ND
ND
ND
1.65
ND
0.24
ND
8.50
8.82
ND
ND
123678
HXCDF
ND
14.3
3.30
2.33
ND
ND
ND
ND
ND
3.37
ND
4.18
5.51
ND
ND
6.17
ND
5.73
ND
ND
ND
ND
ND
0.31
ND
ND
ND
ND
0.37
ND
ND
ND
ND
3.19
ND
ND
ND
5.88
4.35
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
2.8
1.29
0.99
ND
ND
ND
ND
ND
1.01
ND
1.23
2.03
ND
ND
2.48
ND
3.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
ND
ND
ND
0.99
ND
ND
ND
0.85
ND
ND
ND
1234678
HPCOF
ND
23.7
2.43
2.01
ND
ND
ND
ND
ND
7.58
ND
7.96
15.53
ND
ND
16.35
ND
26.74
ND
ND
ND
ND
ND
ND
ND
0.32
0.34
ND
1.84
ND
0.57
ND
0.34
3.15
NO
0.31
ND
3.36
2.62
ND
ND
1234789
HPCDF
ND
5.7
ND
ND
ND
ND
ND
ND
ND
0.65
ND
0.83
0.91
ND
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
0.10 Y
54.7
26.43
13.41
1.50
8.30
2.03
ND
1.22
15.91
1.28
17.17
24.97
0.01
ND
28.90
0.04
18.77
1.58
ND
1.73
ND
1.94
81.21
6.58
71.77
6.61
1.17
14.95
1.25
17.12
0.79
12.91
14.58
0.10
2.58
1.42
45.11
29.67
0.13
2.21
-------
Episode SCC Type Description
3415 DC036205 F PF Sm Bass
3415 DC036206 F BF Channel Catfish
3416 DF025210 F PF Channel Catfish
3416 OF025211 F BF Carp
3416 OF025212 F PF Lm Bass
3418 DF025007 F PF Blue Catfish
3419 DC036207 F UB White Sucker
3419 OC036208 F PF Freshwater Drum
3420 DC036209 F PF Greenfish
3420 DC036210 F UB Carp
3421 DC036211 F PF White Perch
3421 DC036212
3421 SC036212
3422 DC036213
3422 DC036214
3423 DC036215
3423 DC036216
3424 DC036217
3424 DC036218
3425 DF025005
3425 DF025012
3425 0003 1389
3426 DB069102
3427 DB069103
3428 OB069104
3429 DB06910S
3430 OB069106
3431 DB069109
3432 OB069111
3433 DB069112
WB Carp
WB Carp
PF Lm Bass
WB Yellow Bullhead
PF White Perch
WB White Catfish
PF Shortnose Gar
WB White Catfish
WB Carp
BF Channel Catfish
BF Channel Catfish
PF Bluefish
PF Bluefish
PF Bluefish
PF Weakfish
WB White Catfish
WB Red Snapper
BF Red Snapper
WP Flounder
3433 OD021689 L WP Flounder
3434 DB040801 F WP Flounder
3435 DD016601 F PF White Bass
3435 DD016602 F WB Bigmouth Buffalo
3437 OJ022302 H Crayfish
3438 DJ022303 N Dungeness Crab
3439 DJ022304 F WB White Sturgeon
3439 00062289 L WB White Sturgeon
3440 DJ022305 F WB White Sturgeon
3441 DJ022306 F WB White Sturgeon
3442 DF024301 F PF Channel Catfish
2378
TCDD
NO
1.85
3.14
6.46
ND
1.40
ND
ND
23.86
40.32
5.95
54.09
43.96
1.45
1.84
0.83
2.46
1.07
1.94
160.36
52.90
43.41
0.85
1.26
ND
ND
0.75
ND
ND
4.45
4.37
6.29
NO
3.08
ND
0.97
ND
0.88
1.06
ND
ND
12378
PECDD
ND
1.00
ND
ND
ND
ND
ND
ND
0.79
1.64
ND
1.77
1.78
ND
ND
ND
2.71
ND
1.05
9.43
3.08
2.43
ND
ND
ND
ND
ND
1.19
ND
0.94
ND
0.97
ND
2.52
ND
ND
NO
ND
ND
ND
ND
123478
HXCDO
ND
0.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
ND
ND
ND
ND
ND
ND
2.08
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
ND
1.28
ND
ND
ND
ND
ND
NO
1.07
2.67
ND
4.43
3.43
ND
ND
ND
2.91
0.99
ND
6.98
1.29
ND
ND
ND
NO
ND
0.68
ND
ND
0.92
1.19
1.70
ND
3.22
ND
1.22
ND
ND
ND
ND
ND
DIOXIN
123789
HXCDD
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
0.76
0.45
ND
ND
ND
0.89
ND
0.52
2.89
0.58
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.64
ND
ND
ND
ND
ND
ND
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
ND
2.71
2.19
2.61
ND
ND
ND
ND
4.11
5.86
ND
2.40
2.10
ND
1.62
1.84
5.75
1.36
3.60
21.60
4.05
3.14
NO
ND
ND
ND
0.89
ND
ND
0.79
0.63
0.69
ND
8.68
3.33
ND
0.72
0.84
ND
0.62
ND
2378
TCDF
ND
1.43
1.68
2.97
2.16
0.65
6.85
ND
19.22
12.57
10.86
60.25
50.75
0.67
0.68
4.68
3.32
2.33
3.60
82.46
4.92
4.23
1.90
2.23
1.80
ND
1.14
1.43
ND
1.37
1.47
1.26
2.2
8.29
1.77
16.45
22.05
20.94
17.75
22.15
ND
12378
PECDF
ND
0.47
ND
ND
ND
ND
ND
ND
0.68
0.69
ND
3.05
2.48
ND
ND
ND
0.67
ND
ND
4.15
ND
ND
ND
0.41
ND
ND
0.73
0.71
ND
ND
ND
ND
ND
1.66
ND
ND
ND
0.52
ND
ND
ND
pg/g
23478
PECDF
ND
3.30
ND
ND
ND
ND
ND
ND
0.34
3.03
ND
ND
5.34
ND
ND
ND
2.09
ND
0.74
10.45
2.34
1.72
0.42
0.63
0.98
ND
1.39
1.71
ND
1.90
2.21
3.12
ND
1.70
ND
0.43
ND
ND
ND
ND
ND
123478
HXCOF*
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.40
0.46
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.73
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.54
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
NXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234678
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
0.24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.89
ND
ND
ND
ND
ND
ND
ND
1234789
HPCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
ND
4.36
3.33
6.78
0.22
1.47
0.69
ND
26.53
44.32
7.04
61.74
50.88
1.52
1.92
1.32
5.66
1.42
3.28
180.32
56.33
45.99
1.25
1.82
0.67
ND
1.67
1.63
ND
6.11
5.75
8.64
0.23
6.66
0.21
2.95
2.21
3.01
2.84
2.22
ND
-------
Episode SCC Type Description
3442 QD081089
3444 DD016603
3444 DD016604
3444 DD029512
L PF Channel Catfish
F WB Carp
F PF Channel Catfish
F PF Lm Bass
3444 00091289 L UB Carp
3445 DD029513
3445 DD029514
3446 DD016605
F UB Flounder
F UB Hardhead Catfish
F PF Striped Bass
3446 DD016606 F UB Carpsucker
3446 DD029511 F UB Carp
3446 QD092089 L UB Carp
3450 DY022308 F PF Uhite Croaker
3450 DY022309 F PF Uhite Croaker
F PF Uhite Croaker
F PF Uhite Croaker
F UB Sm Buffalo
PF Blue Catfish
PF Flathead Catfish
3451 DY022310
3451 DY022314
3452 DF025218
3452 DF02S219 F
3452 DF025220 F
3452 QD103189 L UB Sm Buffalo
2378
TCDD
NO
3.51
3.77
ND
4.01
ND
0.91
21.55
1.90
3.22
2.26
1.02
2.24
1.93
1.22
9.01
40.73
2.26
9.03
12378
PECDD
ND
9.00
3.54
ND
9.80
ND
2.40
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.06
ND
ND
123478
HXCOD
ND
8.29
1.16
ND
8.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDD
ND
22.88
7.68
ND
25.53
ND
5.57
NO
ND
1.03
1.45
ND
ND
ND
ND
ND
ND
ND
ND
D10XIN
123789
HXCDD
ND
4.00
1.45
ND
5.04
ND
2.02
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/ FURAN CONCENTRATIONS,
1234678
HPCDD
ND
131.65
10.03
OR ND
150.84
2.63
5.90
ND
ND
3.84
4.61
ND
ND
ND
ND
ND
ND
ND
ND
2378
TCDF
ND
1.51
ND
ND
1.45
ND
ND
3.62
0.68
1.42
1.38
ND
ND
ND
ND
17.37
10.98
ND
16.85
12378
PECDF
ND
1.14
ND
ND
1.26
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
pg/g
23478
PECDF
ND
2.28
1.02
ND
2.67
ND
ND
1.78
ND
1.76
1.92
ND
ND
ND
ND
ND
ND
ND
ND
123478
HXCDF*
ND
2.55
ND
ND
2.76
ND
ND
ND
ND
0.86
0.92
ND
ND
ND
ND
ND
ND
ND
ND
123678
HXCDF
ND
5.63
ND
ND
5.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
123789
HXCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
234678
HXCDF
ND
1.26
0.36
ND
1.91
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234678
HPCDF
ND
13.76
1.20
OR ND
13.43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234789
HPCDF
ND
ND
ND
QR ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DPE
TEC
ND
15.27
7.23
ND
17.08
0.03
2.93
22.80
1.97
4.47
3.64
1.02
2.24
1.93
1.22
10.75
42.36
2.26
10.72
-------
D-4-26
-------
Dioxins/Furans
Detection Limits
D-4-27
-------
D-4-28
-------
Episode SCC Type Description
1994 DE017702
1994 DE017703
1994 OD1 10586 I
1998 13285
1998 13421
2015 DF001001
2015 DF001002
2016 DF001101
2016 DF001102
2017 DF001201
2017 DF001202
2018 DF001301
2023 DF001402
2023 DF001403
2026 DF001702
2026 DF001703
2027 DF001802
2027 DF001803
2037 DY000501
2037 DY000502
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000901
2070 DJ000902
2070 QD072186
2098 DH001501
2098 DH001504
2100 DH001702
2100 DH001703
2100 OD111086
2105 DH002201
2105 DH002204
2105 QD063086
2109 DH002601
2109 DH002602
2110 OH002710
2122 DH003901
2122 OH003904
2126 DD000302
2126 OD000303
2126 OD062686
2133 DD001002
F UB Carp
F PF Walleye
. UB Carp
UB Carp
PF Pike
UB Carp
PU Crappie
UB Sucker
BF Sucker
UB Carp
BF Carp
UB Sucker
PF Spotted Bass
UB Carp
UB Carp
PF White Crappie
PF Lm Bass
UB Carp
UB not available
PU not available
UB Carp
UB Carp
UB Carp
UB Carp
UP Rainbow Trout
UB Longnose Sucker
UP Rainbow Trout
UB not available
PF not available
PF Sauger
UB Catfish
UB Catfish
PF Sauger
UB Carp
UB Carp
UB not available
BF not available
UP Broun Trout
PF Rainbow Trout
UB Uhite Sucker
UB Carp
PF Uhite Crappie
= UB Carp
: BF Blue Catfish
010XIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
NA
2.16
NA
3.94
NA
NA
NA
NA
NA
NA
1.13
1.99
0.60
0.67
NA
1.94
0.74
NA
1.15
2.35
NA
3.28
NA
NA
2.15
0.50
0.50
0.88
0.36
1.69
NA
NA
0.44
0.58
0.40
NA
0.42
0.27
0.39
0.81
6.49
0.93
NA
1.45
12378
PECDD
30.99
2.15
112.58
5.18
1.43
6.04
1.70
2.75
2.37
4.90
1.24
3.09
0.52
0.72
1.52
2.52
0.75
2.07
1.94
5.33
6.33
NA
NA
3.50
6.64
1.33
1.16
1.17
0.65
1.35
8.80
8.12
1.14
1.75
1.29
7.28
1.23
0.97
0.92
1.74
9.79
0.77
7.44
5.42
123478
HXCDD
NA
3.02
NA
1.00
1.65
4.70
1.28
0.97
1.70
NA
2.20
3.37
1.17
NA
1.35
3.37
0.90
1.73
1.50
3.31
1.69
0.78
NA
2.09
13.32
3.61
2.23
1.50
1.47
1.72
2.29
2.94
0.73
1.45
0.79
2.00
1.02
1.96
0.84
0.78
6.14
1.30
NA
1.57
123678
HXCDD
NA
3.02
NA
NA
2.89
NA
1.28
NA
NA
NA
NA
3.37
0.78
1.62
NA
3.37
0.90
NA
2.25
5.80
NA
7.10
NA
NA
13.32
3.61
2.23
1.50
0.73
2.58
NA
23.55
0.73
1.45
0.79
12.01
1.02
1.96
0.84
0.78
NA
1.30
NA
NA
123789 1234678
HXCOD
NA
3.02
NA
1.00
1.65
3.13
1.28
2.93
1.27
NA
1.10
3.37
0.78
1.08
1.35
3.37
0.90
1.15
1.50
2.48
3.95
0.78
1.25
2.09
13.32
3.61
2.23
1.50
0.73
1.72
2.29
2.94
0.73
1.45
0.79
2.00
1.02
1.96
0.84
0.78
NA
1.30
NA
1.57
HPCDD
NA
4.19
99.13
NA
3.06
NA
2.24
NA
NA
NA
NA
6.04
NA
NA
NA
NA
5.31
41.78
6.96
NA
NA
NA
NA
NA
19.59
NA
6.12
4.00
NA
5.68
8.87
6.35
NA
5.16
3.58
NA
NA
4.91
NA
NA
NA
3.66
NA
NA
2378
TCDF
NA
NA
NA
6.02
NA
NA
NA
NA
NA
NA
NA
NA
1.34
NA
NA
0.60
0.23
NA
NA
0.89
NA
NA
NA
NA
NA
0.30
1.75
NA
0.41
0.74
NA
0.50
0.40
0.48
0.20
NA
0.91
0.20
1.18
NA
NA
0.20
0.85
0.35
12378
PECDF
NA
0.98
NA
NA
1.23
2.45
0.61
1.29
0.70
NA
0.37
0.93
0.25
0.31
0.48
1.21
0.33
0.56
0.93
NA
NA
0.77
7.27
NA
2.58
0.58
0.87
0.51
0.30
0.42
0.50
1.02
0.63
0.90
0.37
0.58
0.49
0.36
0.47
0.88
0.44
0.32
0.64
0.59
23478
PECDF
NA
0.98
NA
NA
1.05
NA
1.23
NA
1.64
1.82
0.37
0.93
0.25
0.77
0.48
1.21
0.33
0.74
0.62
NA
NA
NA
NA
3.40
2.58
0.58
0.87
0.51
0.30
0.42
2.83
NA
0.63
0.90
0.37
0.58
0.49
0.36
0.47
1.17
0.73
0.32
0.81
0.59
123478
HXCDF*
NA
1.50
NA
2.91
0.90
NA
0.60
NA
NA
1.23
0.51
1.65
0.36
0.46
0.69
1.63
0.41
1.05
0.78
NA
10.11
0.28
NA
NA
4.51
1.41
0.94
0.66
0.34
0.69
1.60
1.18
0.79
1.46
0.67
0.85
0.86
0.96
NA
1.19
0.39
0.54
0.47
0.80
123678
HXCDF
NA
1.50
10.18
0.38
0.90
NA
0.60
1.11
0.47
0.61
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
NA
NA
0.28
NA
1.82
4.51
1.41
0.94
0.66
0.34
0.69
0.96
1.18
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.59
0.54
0.47
0.80
123789
HXCDF
3.07
1.50
1.78
0.38
0.90
0.74
0.60
0.24
0.47
0.41
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
0.77
0.79
0.28
0.58
1.04
4.51
1.41
0.94
0.66
0.34
0.69
0.96
0.89
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.39
0.54
0.47
0.80
234678 1234678 1234789
HXCDF
NA
1.50
NA
1.55
0.90
1.87
0.90
NA
NA
0.41
0.51
1.65
0.36
0.46
0.69
1.63
0.41
0.52
0.78
2.72
3.72
0.28
NA
NA
4.51
1.41
0.94
0.66
0.34
0.69
0.96
0.89
0.79
1.46
0.67
0.85
0.43
0.96
0.59
1.19
0.39
0.54
0.47
0.80
HPCDF
NA
2.94
NA
3.48
1.82
NA
1.26
NA
3.44
1.21
1.25
4.23
NA
NA
1.34
4.74
NA
NA
NA
6.57
NA
NA
NA
NA
6.82
2.13
4.00
NA
NA
1.66
2.79
2.79
1.27
4.13
2.87
NA
1.20
NA
2.40
1.51
NA
NA
NA
1.52
HPCDF
8.18
2.94
5.14
0.77
1.82
1.57
1.26
0.39
0.87
0.80
1.25
4.23
NA
NA
1.34
3.16
NA
NA
1.12
1.64
2.91
0.80
2.22
3.35
6.82
2.13
4.00
NA
NA
1.66
2.79
2.79
1.27
4.13
2.87
2.52
1.20
NA
1.20
3.77
NA
NA
NA
1.52
-------
Episode SCC Type Description
2138 DD001501
2138 DD001504
2139 DD001601
2139 OD001604
2139 QD071486
2142 DD001902
2142 DD001903
2148 DD002501
2148 DD002504
2151 DD002801
2151 DD002803
2152 DD002902
2152 DD002903
2190 DG005101
2190 DG005104
2191 DG00520S
2191 DG005206
2191 QD092486
2194 DG005501
2194 DG005504
2199 DG006001
2199 DG006004
2201 DG006201
2201 DG006204
2205 OG006601
2205 DG006602
2210 DC005401
2211 OC005503
2212 DC005602
2212 DC005605
2215 DC005902
2216 DC006002
2216 DC006003
2220 DC006401
2220 DC006405
2225 DC006902
2225 DC006903
2225 OD101387
2227 DC007102
2227 DC007104
2228 DC007201
2228 DC007204
2228 QD070286
2231 OC007503
WB Redhorse Sucker
PF Lm Bass
WB Carp
PF Rainbow Trout
PF Rainbow Trout
WB Catfish
PF Lai Bass
WB Saltwater Catfish
PF Saltwater Catfish
PF Lm Bass
WB Spotted Sucker
PF Lm Bass
WB Lake Chubsucker
WB Carp
PF Bluegill
WB Carp
BF Carp
BF Carp
WB Carp
BF Channel Catfish
WB Carp
PF Lm Bass
WB Carp
BF Bowfin
WB Carp
BF Carp
WB Catfish
WB Redhorse Sucker
PF Sm Bass
WB White Sucker
WB Carp
PF Brown Trout
WB White Sucker
PF Redbreast Sunfish
WB Catfish
PF Sm Bass
WB Shorthead Redhorse
WB Shorthead Redhorse
PF Lm Bass
WB Channel Catfish
PF Longear Sunfish
WB Redhorse Sucker
. WB Redhorse Sucker
: WB Gizzard Shad
OIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
NA
NA
1.02
NA
NA
1.60
1.02
1.85
0.36
0.29
0.33
0.70
0.51
1.12
0.82
1.59
1.06
1.00
2.46
0.40
NA
1.U
6.01
1.28
1.12
0.66
NA
NA
1.80
NA
2.75
0.34
0.37
0.70
1.10
1.31
NA
NA
0.97
1.65
0.62
2.81
3.40
2.70
12378
PECDD
NA
NA
2.75
1.50
1.11
NA
0.92
1.61
0.99
1.13
1.03
1.17
1.53
1.87
0.67
4.28
2.37
0.84
0.56
1.65
3.11
1.13
13.63
1.53
1.74
1.12
10.44
1.21
2.74
1.62
4.19
0.70
0.63
1.51
2.62
0.96
NA
NA
0.90
NA
0.97
2.62
3.11
5.30
123478
HXCDD
3.52
2.44
2.69
1.04
0.89
2.47
2.46
1.27
0.77
0.54
0.73
1.55
0.75
1.83
1.20
2.20
1.68
1.12
0.33
1.04
0.88
0.78
18.77
2.38
1.94
0.78
4.78
2.47
2.26
0.20
3.93
0.72
0.71
1.35
1.46
2.47
NA
NA
2.42
2.46
1.51
1.23
1.47
1.20
123678
HXCDD
NA
NA
2.69
1.74
1.78
2.85
1.84
1.27
0.77
0.54
0.73
3.10
0.75
3.20
1.20
NA
5.06
NA
NA
3.14
NA
1.17
NA
2.38
1.94
0.78
7.97
NA
2.26
1.66
NA
0.72
1.06
3.39
NA
1.85
NA
NA
1.81
NA
1.51
4.30
NA
6.20
123789 1234678
HXCDD
NA
NA
2.69
1.04
0.89
1.38
1.37
1.27
0.77
0.54
0.73
1.55
0.75
1.83
1.20
2.20
1.68
1.12
0.33
0.69
0.88
1.17
11.55
2.38
1.94
0.78
4.78
1.38
2.26
0.20
3.93
0.72
0.71
1.35
0.97
1.38
NA
.44
.35
NA
.51
.23
.47
.90
HPCDD
NA
NA
6.49
NA
NA
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.60
4.62
NA
4.70
NA
9.92
7.29
5.54
NA
NA
3.82
NA
NA
4.45
2.72
NA
NA
NA
NA
NA
1.96
NA
NA
11.91
NA
NA
2378
TCDF
NA
NA
0.59
NA
NA
NA
NA
0.90
0.26
0.25
0.55
0.47
0.58
0.90
0.20
NA
1.23
1.20
NA
0.20
1.20
0.45
1.44
0.29
NA
NA
NA
NA
0.86
NA
NA
0.20
NA
0.48
NA
NA
NA
NA
NA
NA
0.47
NA
NA
NA
12378
PECOF
NA
NA
0.77
1.11
NA
0.99
0.77
0.81
0.43
0.41
0.48
0.75
0.51
0.79
0.46
NA
0.56
0.49
0.20
0.27
0.20
0.25
1.08
0.67
0.61
0.31
1.50
0.96
1.21
NA
NA
0.35
0.30
0.87
0.52
0.78
NA
NA
0.76
0.77
0.75
1.51
1.41
3.00
23478
PECDF
NA
NA
0.77
NA
NA
NA
0.85
0.81
0.43
0.41
0.48
0.75
0.51
0.53
0.46
2.65
0.56
0.74
NA
0.27
NA
0.25
1.08
0.67
0.61
0.31
2.26
NA
1.51
NA
NA
0.35
0.30
0.87
NA
0.85
NA
NA
0.83
NA
0.75
2.65
NA
NA
123478
HXCDF*
NA
NA
1.31
0.58
0.45
2.84
2.83
1.20
0.65
0.82
0.68
1.78
0.74
0.66
1.32
1.13
0.65
0.44
0.20
0.41
NA
0.37
1.83
0.79
1.21
0.50
1.38
NA
1.00
NA
2.37
0.42
0.39
NA
1.75
2.84
NA
NA
2.78
2.82
1.17
NA
NA
NA
123678
HXCDF
3.06
2.82
1.31
0.58
0.45
2.85
2.84
1.20
0.65
0.82
0.68
0.71
0.74
0.88
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
2.85
1.00
NA
0.79
0.42
0.39
0.67
0.50
2.85
2.83
2.84
2.79
2.83
0.78
0.68
0.68
0.60
123789
HXCDF
2.77
2.75
1.31
0.39
0.45
2.78
2.77
1.20
0.65
0.82
0.68
0.71
0.74
0.44
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
2.78
1.00
0.20
0.79
0.42
0.39
0.67
0.50
2.78
2.76
2.77
2.72
2.76
0.78
0.68
0.68
0.60
234678 1234678 1234789
HXCDF
NA
NA
1.31
0.58
0.45
1.96
1.96
1.20
0.65
0.82
0.68
0.71
0.74
0.44
0.53
1.13
0.65
0.44
0.20
0.41
0.39
0.37
1.83
0.79
1.21
0.50
1.38
NA
1.00
0.22
1.58
0.42
0.39
0.67
0.50
1.96
NA
NA
1.92
1.95
0.78
NA
0.68
NA
HPCDF
NA
NA
3.24
1.26
NA
NA
1.44
3.48
1.31
0.99
1.23
NA
2.05
NA
NA
NA
2.37
1.35
0.43
1.30
0.75
0.76
5.33
2.52
2.11
NA
4.40
NA
2.81
0.52
NA
0.80
0.98
NA
NA
1.45
NA
NA
1.42
NA
NA
NA
NA
NA
HPCDF
2.62
2.59
3.24
0.63
0.91
2.62
2.61
3.48
1.31
0.99
1.23
NA
1.36
NA
NA
2.89
2.37
1.35
0.43
1.30
0.50
0.76
5.33
2.52
?.11
0.87
4.40
2.62
2.81
0.19
2.70
0.80
0.98
NA
NA
2.62
2.60
2.61
2.56
2.60
NA
NA
NA
1.30
-------
Episode SCC Type Description
2246 DJ002301
2246 DJ002302
2247 OJ002403
2247 DJ002404
2280 DF005201
2280 DF005204
2280 QD062386
2283 DF005501
2283 DF005502
2290 DD003403
2294 DD003801
2294 DD003804
2297 DD004102
2297 DD004103
2298 DD004201
2298 DD004203
2301 DD004504
2301 QD071786
2302 DD004601
2304 DD004801
2304 DD004804
2309 DD005301
2309 DD005304
2322 DB001301
2322 DB001304
2322 QD082686
2326 DB001701
2326 DB001704
2328 DB001904
2329 DB002004
2341 DD006002
2341 DD006003
2355 DA001603
2356 DA001702
2356 DA001703
2358 DA001901
2369 DA003202
2369 DA003203
2369 OD030387
2375 DA003802
2375 DA003803
2376 DA003903
2376 QD111886
2379 DE005404
BF Bridgetip Sucker
UB Bridgelip Sucker
PF Bridgelip Sucker
UP Mountain Uhitefish
UB Carp
BF Channel Catfish
Dup Of DF005204
UB Gray Redhorse
UP Longear Sunfish
UB Spotted Sucker
PF Lro Bass
UB Carp
UB Carp
PF Lin Bass
UB Channel Catfish
UP Lm Bass
UP Rock Bass
UP Rock Bass
UB QuiIIback Carpsucker
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB White Sucker
PF Lm Bass
PF not available
UB White Sucker
PF Rock Bass
PF Chinook Salmon
PF Broun Trout
PF Lin Bass
UB Carpsucker
UB White Sucker
PF Lm Bass
UB White Sucker
UP ns
PF Lm Bass
UB White Sucker
UB White Sucker
PF Pickerel
UB White Sucker
UB White Sucker
UB White Sucker
PF Lm Bass
D10X1N / FURAN DETECTION LIMITS, pg/g
2378
TCOO
0.41
2.20
0.98
NA
0.49
0.93
0.40
0.20
0.30
NA
NA
NA
1.25
1.08
0.41
0.07
0.96
1.49
NA
NA
NA
2.39
1.20
0.20
0.36
0.68
0.42
1.17
NA
NA
NA
NA
NA
NA
NA
3.57
1.84
NA
1.73
0.51
NA
3.02
2.85
1.39
12378
PECDD
0.92
5.07
0.94
3.59
1.88
1.08
0.96
0.62
1.40
NA
NA
NA
NA
0.92
2.29
0.26
2.74
2.99
NA
NA
NA
4.74
0.30
0.75
1.75
1.23
4.05
1.85
5.65
3.87
1.12
2.02
NA
0.86
6.24
7.07
2.35
2.01
0.94
0.60
NA
4.44
5.40
2.18
123478
HXCDD
1.00
1.35
0.86
.18
.25
0.67
.32
.10
.13
NA
2.46
NA
2.45
2.47
1.60
0.20
2.47
2.87
2.45
NA
NA
5.82
1.00
0.83
.39
.96
.46
.25
.36
.89
2.47
2.46
NA
0.86
1.62
6.62
4.02
1.46
0.70
0.69
NA
1.70
2.41
2.40
123678
HXCDD
1.00
8.78
HA
NA
1.25
NA
0.53
1.10
1.13
NA
NA
3.17
NA
1.84
5.60
0.20
3.71
2.87
2.09
NA
NA
NA
2.10
0.83
1.39
1.30
5.36
3.49
1.36
1.89
NA
NA
NA
1.30
NA
NA
4.02
NA
NA
1.38
NA
2.84
2.41
2.40
123789 1234678
HXCDD
1.00
1.35
0.86
1.18
1.25
0.67
0.53
1.10
1.13
NA
NA
NA
1.37
1.38
1.60
0.20
2.47
2.87
NA
NA
NA
1.94
1.00
0.83
.39
.30
.46
.25
.36
.89
.38
.37
NA
0.86
1.62
6.62
4.02
1.09
0.70
0.69
NA
1.70
2.41
2.40
HPCDD
9.77
NA
NA
NA
5.70
NA
NA
3.10
7.36
NA
NA
NA
NA
1.28
15.47
1.28
19.27
12.94
NA
NA
NA
NA
NA
1.54
2.66
4.86
NA
10.70
3.60
3.09
NA
NA
NA
2.23
NA
NA
3.93
3.69
NA
NA
NA
8.44
6.05
4.28
2378
TCDF
0.36
5.06
NA
NA
0.38
NA
NA
0.42
0.41
NA
NA
NA
NA
NA
0.42
0.20
NA
3.23
NA
NA
NA
NA
NA
3.99
NA
0.73
2.81
1.95
NA
NA
NA
NA
NA
NA
NA
NA
0.52
NA
NA
NA
NA
NA
NA
0.57
12378
PECDF
0.40
NA
0.32
0.30
0.34
0.39
0.29
0.25
0.52
NA
0.77
1.16
0.77
0.78
1.03
0.20
0.82
0.76
0.77
4.27
NA
0.44
0.30
0.30
0.32
0.36
1.13
0.59
0.87
1.02
NA
NA
NA
0.21
3.73
1.78
1.04
0.47
0.36
0.30
NA
0.58
1.04
0.69
23478
PECDF
0.40
2.03
1.62
NA
0.34
0.58
0.44
0.25
0.52
NA
0.93
NA
1.16
0.85
1.03
0.20
0.82
0.76
0.84
NA
NA
1.79
0.30
0.30
0.32
0.36
NA
0.59
NA
0.61
NA
NA
NA
0.21
NA
1.78
1.04
0.62
0.36
0.30
NA
NA
NA
0.69
123478
HXCDF*
0.46
NA
2.59
0.44
0.76
0.37
0.28
0.52
0.78
NA
NA
NA
2.82
2.83
0.96
0.20
1.30
1.13
NA
NA
NA
0.92
0.50
0.45
0.56
0.61
0.53
0.72
NA
NA
NA
NA
NA
0.35
0.54
NA
1.98
0.93
NA
0.35
NA
NA
8.62
1.17
123678
HXCOF
0.46
0.50
0.47
0.44
0.51
0.37
0.28
0.52
0.52
NA
2.83
2.85
2.83
2.85
0.96
0.20
1.30
1.13
2.83
NA
2.84
0.92
0.50
0.45
0.56
0.61
0.53
0.72
0.67
1.01
2.85
NA
2.85
0.35
0.54
2.64
1.98
0.93
0.61
0.35
2.83
0.90
1.72
1.17
123789
HXCDF
0.46
0.50
0.47
0.44
0.51
0.37
0.28
0.52
0.52
2.73
2.76
2.78
2.76
2.77
0.96
0.20
1.30
1.13
2.76
2.79
2.77
0.92
0.50
0.45
0.56
0.61
0.53
0.72
0.67
1.01
2.78
2.76
2.76
0.35
0.54
2.64
1.98
0.93
0.61
0.35
2.76
0.90
1.72
1.17
234678 1234678 1234789
HXCDF
0.46
NA
NA
NA
0.51
0.37
0.28
0.52
0.52
NA
NA
NA
1.95
1.96
0.96
0.20
1.30
1.13
1.95
NA
1.96
0.92
0.50
0.45
0.56
0.61
0.53
0.72
NA
3.03
NA
NA
NA
0.35
0.54
2.64
1.98
1.86
0.61
0.35
1.95
2.40
1.72
1.17
HPCDF
1.11
4.57
NA
NA
NA
0.87
0.46
2.75
3.11
NA
NA
NA
1.44
NA
3.81
0.36
6.61
8.89
NA
NA
NA
6.06
1.40
1.52
2.10
2.30
2.05
1.40
NA
NA
NA
NA
NA
1.13
1.82
36.36
2.75
3.64
NA
0.72
NA
2.74
3.59
3.00
HPCDF
1.11
1.82
0.93
0.93
NA
0.58
0.46
2.75
3.11
NA
2.61
2.62
2.60
2.62
3.81
0.36
2.64
5.92
2.60
2.63
2.61
2.42
.40
.52
2.10
.53
.02
.40
.37
2.75
2.62
2.61
2.60
1.13
1.82
9.09
2.75
3.64
1.57
0.72
2.61
1.37
3.59
3.00
-------
DIOX1N / FURAN DETECTION LIMITS, pg/g
Episode SCC
2380 DE005501
2383 DE005801
2385 DE006002
2385 QD 101987
2387 DE006201
2394 DE006901
2397 DE007201
2397 DE007204
2410 DE008S01
2410 DE008S04
2416 DE009101
2422 DE009702
2427 DE010202
2427 DE010203
2427 QD 102887
2429 DE010402
2429 DE010403
2429 QD010687
2430 DE010602
2430 DE010603
2431 DE010702
2431 DE010703
2432 DE010710
2432 DE010713
2435 DE011001
2435 DE011004
2437 DE011202
2437 DE011203
2439 DE011401
2439 DE011402
2478 DJ003901
2478 DJ003902
2500 DCO 10201
2500 DC010203
2532 DF019302
2532 DF019303
2544 DF019202
2608 DE014501
2608 DE014504
2618 DE015401
2618 DE015402
2618 DE015403
2618 QD102088
2651 DB008401
Type Description
F WB Carp
F WB Carp
F WB White Sucker
F WB White Sucker
F WB Carp
F WB Carp
F WB Sucker
F PF Walleye
F WB Carp
F PF Sm Bass
F WB Carp
F WB Carp
F WB Carp
F PF Walleye
L PF Walleye
F WB Carp
F PF Walleye
L PF Walleye
F PF Northern Pike
F WB Redhorse Sucker
F PF Brown Trout
F WB Sucker
F WB Redhorse Sucker
F PF Walleye
F WB Longnose Sucker
F PF Brook Trout
F PF Walleye
F WB Carp
F WB Carp
F WP Sm Bass
F FB Sucker
F WB Sucker
F PF Bass
F WB Black Buffalo
F PF Lm Bass
F WB Carp
F WB Blacktail Redhorse
F PF Walleye
F WB Carp
F WB Carp
F BF Carp
F WB Quill back
F WB Quill back
F WB White Sucker
2378
TCOD
NA
NA
NA
NA
1.04
NA
1.09
0.33
NA
NA
NA
NA
NA
NA
NA
NA
1.19
NA
0.99
0.49
1.70
NA
0.58
NA
0.58
0.58
0.58
0.58
NA
NA
0.39
0.37
NA
1.62
NA
NA
1.40
NA
NA
NA
NA
NA
NA
NA
12378
PECDD
19.70
33.59
NA
NA
0.92
NA
0.87
0.69
55.12
0.95
17.66
NA
NA
0.97
0.92
13.65
.16
.25
.92
.19
NA
.79
.75
.75
.75
.75
.75
.75
10.82
4.54
1.48
1.06
1.38
1.71
1.11
NA
0.93
0.95
NA
NA
NA
NA
NA
1.35
123478
HXCDD
NA
NA
2.49
2.46
2.47
NA
0.73
0.80
17.50
0.64
NA
NA
NA
2.40
2.46
17.25
0.63
0.68
2.46
1.88
2.46
2.46
1.45
1.45
1.45
1.45
1.45
1.45
NA
0.81
1.40
1.51
2.70
2.92
2.45
NA
2.10
2.46
NA
NA
2.47
2.62
NA
1.00
123678
HXCDD
38.31
NA
NA
NA
1.85
NA
1.46
0.80
NA
0.64
NA
NA
NA
1.79
1.84
NA
0.63
1.03
1.84
1.88
1.84
NA
1.45
1.45
1.45
1.45
1.45
1.45
NA
NA
1.40
1.51
2.70
2.92
NA
NA
1.57
1.84
NA
NA
NA
NA
NA
1.33
123789
HXCDD
10.10
13.12
1.38
1.38
1.38
NA
1.10
0.80
9.10
0.64
6.65
NA
NA
1.34
1.37
5.07
0.63
0.68
1.37
1.88
1.37
1.37
1.45
1.45
1.45
1.45
1.45
1.45
NA
0.81
1.40
1.51
2.70
2.92
1.37
NA
1.13
1.37
NA
NA
1.45
1.68
1.57
0.66
1234678
HPCDD
NA
NA
NA
NA
NA
NA
NA
0.73
106.38
4.15
NA
NA
NA
NA
NA
NA
2.84
NA
1.34
3.28
1.49
NA
5.16
5.16
5.16
NA
NA
NA
NA
NA
NA
5.25
NA
4.00
NA
NA
NA
NA
NA
NA
NA
NA
NA
8.55
2378
TCDF
NA
NA
NA
NA
NA
NA
NA
0.20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.53
NA
NA
NA
NA
NA
NA
0.48
NA
0.48
NA
NA
0.29
0.97
NA
0.45
1.34
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDF
NA
NA
NA
NA
0.78
NA
0.22
0.25
NA
0.31
NA
NA
NA
0.75
NA
4.54
0.31
0.55
0.77
0.39
NA
0.77
0.90
0.90
0.90
0.90
0.90
0.90
1.91
0.99
0.41
0.46
1.03
0.56
0.80
NA
0.63
0.77
NA
NA
1.13
NA
NA
0.69
23478
PECDF
NA
NA
NA
NA
NA
NA
0.22
0.25
HA
0.42
NA
NA
NA
1.06
1.09
NA
0.74
0.78
0.85
0.39
NA
1.06
0.90
0.90
NA
0.90
0.90
0.90
NA
NA
0.41
0.46
1.03
0.56
1.07
NA
0.74
NA
NA
NA
NA
NA
NA
0.34
123478
HXCDF*
NA
29.79
NA
NA
2.84
NA
0.47
0.32
NA
0.29
NA
NA
NA
NA
NA
35.95
0.66
0.30
2.83
0.74
2.83
2.83
1.46
1.46
1.46
1.46
1.46
1.46
NA
NA
0.58
2.08
0.64
1.07
NA
NA
2.74
2.88
NA
NA
NA
2.84
2.83
0.33
123678
HXCDF
5.17
11.67
2.85
2.84
2.85
NA
0.31
0.32
NA
0.29
NA
NA
NA
2.77
2.84
1.84
0.39
0.30
2.84
0.74
2.84
2.84
.46
.46
.46
.46
.46
.46
NA
0.37
0.58
0.69
0.64
1.07
2.82
NA
2.29
2.84
4.42
NA
NA
2.85
2.84
0.33
123789
HXCDF
0.79
0.99
2.78
2.77
2.78
2.77
0.31
0.32
1.33
0.29
2.18
2.77
2.76
2.70
2.77
1.84
0.26
0.30
2.77
0.74
2.77
2.77
1.46
1.46
1.46
1.46
1.46
1.46
0.46
0.37
0.58
0.69
0.64
1.07
2.75
2.73
2.44
2.77
2.76
2.76
2.78
2.78
2.77
0.33
234678 1234678 1234789
HXCDF
NA
NA
2.11
1.96
1.96
NA
0.31
0.32
NA
0.29
2.45
NA
NA
1.90
1.96
1.84
0.26
0.30
1.96
0.74
1.95
1.96
1.46
1.46
1.46
1.46
1.46
1.46
10.41
NA
0.58
0.69
0.64
1.07
1.94
NA
1.70
1.95
NA
2.10
1.96
1.96
1.96
0.33
HPCOF
NA
NA
NA
NA
NA
NA
0.71
0.74
42.82
1.13
4.61
NA
NA
NA
1.46
NA
0.64
0.61
1.44
2.37
1.44
NA
4.13
4.13
4.13
4.13
4.13
4.13
NA
NA
1.28
1.80
3.36
4.06
1.45
NA
NA
NA
NA
NA
NA
NA
NA
1.33
HPCDF
2.67
2.74
2.62
2.61
2.62
2.61
0.71
0.74
4.50
1.13
2.30
2.61
2.60
2.54
2.61
6.69
0.64
0.61
2.61
2.37
2.61
2.61
4.13
4.13
4.13
4.13
4.13
4.13
1.06
0.70
1.28
1.80
2.24
4.06
2.59
2.57
2.18
2.61
2.61
2.60
2.62
2.62
2.61
1.33
-------
Episode SCC Type Description
2653 DB008503
2654 DB008601
2709 DB005101
2721 DA006502
2722 DA006601
2725 DA006301
2748 DY006505
2748 DY006506
2776 DY007101
2776 DY007103
3001 DE019501
3001 DE019502
3022 DA008401
3022 DA008402
3023 DA008501
3024 DA008601
3025 DA008701
3025 DA008702
3026 DA009001
3026 DA009002
3027 DA009301
3028 DA008801
3028 QD031787
3034 DG025701
3034 DG025702
3035 DG025801
3035 DG025802
3036 DG025901
3036 DG025902
3036 QD120287
3037 DG026001
3037 DG026002
3038 DG026101
3038 DG026102
3039 DG026201
3039 DG026202
3040 DG026301
3040 DG026302
3041 DG026401
3041 DG026402
3041 00031588
3042 DG026501
3042 DG026502
3043 DG026601
UB Carp
UB Carp
UB Catfish
WB Sucker
UB Sucker
UB Sucker
UB Sucker
BF not available
UB Carp
PF Trout
PF Walleye
UB White Sucker
UB White Sucker
PF Chain Pickerel
PF Sm Bass
PF Lm Bass
WB White Sucker
PF Chain Pickerel
UB Catfish
PF Lm Bass
UB Sucker
PF Chain Pickerel
PF Chain Pickerel
UB Carp
PF Lm Bass
UB Carp
PF Sm Bass
PF Freshwater Drum
UB Carp
PF Freshwater Drum
UB Carp
PF Black Crappie
UB Carp
BF Channel Catfish
UB Carp
BF Channel Catfish
UB Carp
PF White Crappie
BF Channel Catfish
UB Carp
BF Channel Catfish
UB Carp
PF Northern Pike
BF Flathead Catfish
D10XIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
NA
1.88
7.87
NA
1.39
NA
0.55
0.81
0.72
1.19
0.10
0.28
NA
0.10
0.99
0.20
NA
0.12
NA
NA
1.19
0.11
0.11
NA
1.01
NA
0.16
0.99
1.26
0.99
NA
0.16
NA
NA
NA
1.16
NA
1.01
1.31
1.03
NA
1.30
0.99
NA
12378
PECDD
NA
1.53
4.80
NA
2.73
NA
1.01
1.11
1.69
0.98
0.37
0.93
NA
0.49
0.95
0.40
NA
0.32
NA
NA
0.50
0.29
0.19
NA
0.92
NA
0.25
0.92
NA
0.92
NA
0.20
NA
1.50
MA
0.95
MA
0.98
MA
1.23
NA
NA
0.92
2.39
123478
HXCDD
NA
1.13
2.79
2.43
3.12
2.46
1.28
1.55
1.97
0.71
0.60
0.90
NA
1.04
2.47
3.42
0.76
0.68
2.47
2.47
0.60
0.87
0.22
NA
2.46
NA
0.38
2.46
2.49
2.47
2.46
0.22
NA
2.47
NA
2.46
NA
2.47
2.46
NA
NA
NA
2.46
0.30
123678
HXCOD
NA
2.26
5.59
NA
3.12
NA
.28
.55
.97
0.71
0.60
.21
.82
.04
.84
.14
NA
0.68
NA
1.85
3.61
0.87
0.91
NA
1.84
NA
0.38
1.84
NA
1.84
NA
0.22
NA
NA
NA
NA
NA
1.85
NA
NA
NA
NA
1.84
NA
123789 1234678
HXCDD
1.35
1.13
2.79
NA
3.12
NA
1.28
1.55
1.97
0.71
0.60
0.60
1.36
1.04
1.38
1.14
0.50
0.68
NA
1.38
0.80
0.87
0.22
NA
1.37
1.55
0.38
1.37
NA
1.38
1.37
0.22
NA
NA
NA
1.38
NA
1.38
NA
1.38
NA
NA
1.37
0.73
HPCDD
NA
3.62
NA
NA
8.07
NA
4.60
NA
5.89
2.99
1.21
4.22
NA
3.08
NA
5.03
NA
NA
NA
NA
4.92
5.09
3.95
NA
1.26
NA
0.69
1.31
NA
1.26
NA
2.29
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2378
TCDF
NA
NA
NA
NA
1.11
NA
0.26
0.32
1.59
1.62
0.51
2.25
NA
0.20
NA
NA
NA
0.20
NA
NA
NA
0.24
0.20
NA
NA
NA
0.97
0.49
NA
0.49
NA
0.20
NA
0.49
NA
0.49
NA
0.49
0.51
NA
NA
NA
0.48
NA
12378
PECDF
NA
0.24
1.86
NA
0.76
NA
0.50
0.43
0.72
0.32
0.20
0.41
NA
0.28
0.77
0.37
0.26
0.21
1.85
0.78
0.20
0.19
0.20
NA
0.77
NA
0.20
0.77
0.78
0.77
0.77
0.20
NA
0.78
NA
0.77
0.87
0.78
0.77
0.78
0.77
NA
0.77
NA
23478
PECDF
NA
0.59
NA
NA
0.76
NA
0.50
0.43
0.72
0.64
0.20
0.31
NA
0.28
0.85
0.37
0.26
0.32
NA
NA
1.30
0.19
0.20
NA
0.85
NA
0.20
0.85
0.85
0.85
0.85
0.20
NA
NA
NA
0.85
NA
0.85
1.17
0.89
NA
NA
0.84
0.90
123478
HXCDF*
NA
0.30
4.43
NA
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.39
2.80
0.42
2.83
0.51
0.26
0.37
NA
2.84
0.34
0.30
0.20
NA
2.83
NA
0.19
2.83
2.86
2.83
NA
0.20
NA
2.84
NA
2.83
NA
2.84
NA
2.84
NA
NA
2.82
NA
123678
HXCDF
2.78
0.30
1.32
2.81
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.26
2.81
0.42
2.84
0.34
0.39
0.37
2.85
2.85
0.34
0.30
0.20
3.42
2.84
2.83
0.19
2.84
2.87
2.84
2.84
0.20
NA
2.85
NA
2.84
NA
2.85
2.83
2.85
2.83
NA
2.83
NA
123789
HXCDF
2.71
0.30
1.32
2.74
1.39
2.77
0.63
0.65
1.04
0.38
0.21
0.26
2.74
0.42
2.77
0.34
0.26
0.37
2.78
2.78
0.34
0.30
0.20
2.77
2.77
2.76
0.19
2.77
2.80
2.77
2.77
0.20
2.77
2.78
2.76
2.77
2.75
2.78
2.76
2.78
2.76
0.20
2.76
0.20
234678 1234678 1234789
HXCDF
NA
0.30
1.32
2.51
1.39
NA
0.63
0.65
1.04
0.38
0.21
0.26
1.94
0.42
1.96
0.34
NA
0.37
NA
1.96
0.34
0.30
0.20
NA
1.96
NA
0.19
1.95
1.98
1.96
1.96
0.20
NA
1.96
NA
1.96
NA
1.96
1.95
1.96
NA
0.97
1.95
NA
HPCDF
NA
0.73
NA
NA
3.77
NA
1.37
1.99
NA
NA
0.71
1.38
NA
1.28
1.45
0.79
NA
3.48
NA
1.45
1.53
0.70
0.27
NA
1.44
NA
0.44
1.44
1.46
1.45
NA
0.35
NA
NA
NA
1.44
NA
1.45
NA
NA
NA
NA
1.44
1.20
HPCDF
2.56
0.73
NA
2.58
3.77
2.61
1.37
1.99
NA
NA
0.71
0.92
2.59
1.28
2.61
0.79
0.85
0.71
2.62
2.62
1.02
0.70
0.27
2.62
2.61
2.60
0.44
2.61
2.64
2.61
2.61
0.23
2.61
2.62
2.60
2.61
2.59
2.62
2.61
2.62
2.60
0.22
2.60
0.20
-------
DIOXIN / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3043 DG026602 F BF Flathead Catfish
3043 00111987 L BF Flathead Catfish
3044 DG026701
3044 DG026702
3045 DG026801
3045 OG026802
3046 DG026901
3047 DG027001
3047 DG027002
3048 DG027101
3048 DG027102
3049 DG027201
3049 OG027202
3049 OD1 11087
3050 DG027301
3060 DF009101
3060 DF009102
3061 DF019105
3061 DF019106
3062 DF024024
3062 DF024324
3062 QD024324
3062 QD071587
3062 SF024324
3063 DF023301
3063 DF023302
3064 DF023305
3064 DF023306
3065 DF023419
3065 DF023420
3065 OD022588
3066 DF023503
3066 DF023504
3068 DF024001
3068 DF024002
3069 DF024007
3069 DF024008
3070 DF024009
3070 DF024010
3071 DF024014
3072 DF024017
3072 OF024018
UB Carp
BF Flathead Catfish
WB Carp
BF Flathead Catfish
UB Bigmouth Buffalo
WB Carp
PF Sm Bass
WB Carp
PF White Bass
WB Carp
PF Crappie
PF Crappie
WB Bigmouth Buffalo
WB Flathead Catfish
WB Sm Buffalo
PF Bass
WB Sucker
WB Blue Catfish
BF Grass Carp
BF Grass Carp
WB Blue Catfish
BF Grass Carp
WB Sea Catfish
PF Spotted Seatrout
Shellfish
PF Spotted Seatrout
BF Bigmouth Buffalo
WB Flathead Catfish
WB Flathead Catfish
WB Catfish
PF Freshwater Drum
Oysters
PF At I. Croaker
WB Sea Catfish
PF Trout
WB Croaker
PF Sheepshead
WB Carp
WB Carp
PF White Bass
3072 OD040788 L PF White Bass
3073 DF019221 F UB White Sucker
2378
TCDD
NA
NA
NA
NA
NA
0.73
NA
NA
1.00
NA
0.09
NA
1.01
1.13
NA
0.40
NA
NA
2.18
NA
NA
NA
NA
NA
NA
1.02
1.15
0.99
NA
NA
NA
NA
0.99
NA
1.30
NA
1.00
1.07
NA
NA
1.06
1.06
1.19
NA
12378
PECDD
NA
0.91
NA
1.04
6.27
NA
0.94
NA
0.92
NA
0.32
NA
0.92
0.92
1.22
0.30
2.19
NA
NA
NA
1.03
0.93
NA
0.35
NA
0.92
0.92
0.96
NA
NA
NA
1.83
0.92
1.06
0.91
NA
0.92
0.92
1.16
NA
2.11
0.92
0.92
1.05
123478
HXCDD
2.46
2.45
NA
2.47
1.04
0.22
2.45
NA
2.48
NA
0.44
NA
2.46
2.47
NA
0.38
0.43
3.18
0.27
2.46
2.47
2.46
2.46
1.37
2.59
2.45
2.46
2.45
2.46
NA
NA
NA
2.46
2.45
2.46
2.69
2.47
2.46
NA
2.46
2.47
2.47
2.47
2.47
123678
HXCDO
NA
NA
2.33
NA
NA
NA
NA
NA
1.85
NA
0.44
NA
1.84
1.84
NA
0.38
3.92
NA
NA
NA
1.84
1.84
NA
0.67
NA
1.83
NA
1.83
NA
NA
NA
NA
1.84
1.97
NA
NA
1.85
NA
1.83
NA
1.85
1.85
1.85
NA
123789 1234678
HXCDD
1.37
1.37
NA
1.38
2.79
0.22
1.37
1.38
1.38
5.18
0.44
NA
1.38
1.38
1.38
0.38
0.43
NA
0.27
.44
.38
.37
.37
.98
NA
.37
.37
.37
NA
1.38
1.36
NA
1.38
1.37
1.37
1.38
1.38
NA
.37
.37
.38
.38
.38
.38
HPCDD
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.07
NA
1.26
1.26
NA
0.89
8.35
NA
NA
NA
NA
NA
NA
NA
NA
1.58
NA
NA
NA
NA
NA
NA
NA
NA
1.80
NA
NA
NA
NA
NA
NA
NA
NA
NA
2378
TCDF
NA
0.48
NA
0.49
1.97
NA
NA
NA
0.51
NA
NA
NA
NA
0.55
NA
0.41
NA
0.60
1.17
NA
NA
NA
NA
NA
NA
NA
NA
0.52
NA
NA
NA
NA
NA
NA
NA
0.50
0.49
NA
NA
NA
NA
NA
NA
NA
12378
PECDF
0.77
0.77
NA
0.78
NA
0.20
0.77
NA
0.78
2.78
0.20
1.32
0.77
0.78
NA
0.20
0.72
0.77
NA
NA
0.77
NA
NA
0.45
NA
NA
0.77
0.77
0.77
NA
NA
NA
0.77
0.77
0.99
0.77
0.78
0.77
0.77
0.95
0.78
0.78
0.78
0.78
23478
PECDF
0.85
0.84
NA
NA
1.51
0.93
0.84
NA
0.85
NA
0.20
NA
0.85
0.85
1.10
0.20
NA
0.99
1.27
NA
NA
NA
0.84
NA
NA
0.84
0.84
0.84
NA
NA
NA
NA
0.85
1.08
0.84
NA
0.85
0.84
0.84
NA
0.95
0.85
0.85
NA
123478
HXCDF*
NA
2.82
NA
2.84
NA
0.46
2.82
NA
2.85
NA
0.22
NA
2.83
2.83
2.83
0.20
1.27
NA
2.73
NA
2.83
2.82
NA
0.97
NA
NA
2.82
2.81
2.82
NA
NA
NA
2.83
2.82
2.83
2.83
2.84
2.82
2.81
NA
2.84
2.84
2.84
2.84
123678
HXCDF
2.84
2.83
2.85
2.85
0.70
0.20
2.83
2.85
2.86
2.81
0.22
3.06
2.84
2.85
2.85
0.20
0.20
2.84
1.10
2.84
2.84
2.83
2.84
1.21
NA
NA
2.84
2.82
2.83
2.84
2.82
NA
2.84
2.83
2.84
2.84
2.85
2.83
2.83
NA
2.85
2.85
2.85
2.85
123789
HXCDF
2.77
2.76
2.78
2.78
0.28
0.20
2.76
2.78
2.79
0.20
0.22
2.77
2.77
2.77
2.77
0.20
0.20
2.77
0.22
2.77
2.77
2.76
2.77
1.40
2.77
2.76
2.76
2.75
2.76
2.77
2.75
2.77
2.77
2.76
2.77
2.77
2.78
2.76
2.76
2.77
2.78
2.78
2.78
2.78
234678 1234678 1234789
HXCDF
1.95
1.95
2.47
1.96
NA
0.20
1.95
NA
1.97
2.81
0.22
NA
1.96
1.96
NA
0.20
0.20
1.96
NA
2.07
1.96
.95
.99
.57
2.14
.95
.95
.95
.95
NA
1.94
NA
1.96
1.95
1.95
1.96
1.97
1.95
1.95
NA
1.96
1.96
1.96
1.96
HPCDF
NA
1.44
NA
NA
6.04
0.81
1.44
NA
1.45
8.87
0.59
NA
1.45
1.45
NA
0.49
0.47
NA
NA
1.48
1.45
1.44
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
1.45
1.44
1.44
NA
1.45
NA
NA
NA
1.45
1.45
1.45
NA
HPCDF
2.61
2.60
2.62
2.62
1.09
0.20
2.60
2.62
2.63
0.42
0.59
2.61
2.61
2.62
2.62
0.49
0.47
2.61
0.34
2.61
2.61
2.60
2.61
1.66
2.61
2.60
2.61
2.60
2.60
2.61
2.59
2.62
2.61
2.60
2.61
2.61
2.62
2.61
2.60
2.61
2.62
2.62
2.62
2.62
-------
Episode SCC Type Description
3073 DF019222 1
3073 QD121587 1
3074 DF026017
3075 OF024102
3076 DF028502
3076 DF028S03
3077 DF019113
3077 DF019114
3077 QD121087
3078 DF009118
3078 DF023815
3078 DF023816
3078 SF009118
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3080 00040987
3081 DF024105
3081 DF024106
3082 DF023401
3082 DF023402
3082 00 120787
3083 DF023405
3083 DF023406
3084 DF024109
3084 QD072188
3085 DF024114
3086 DF023409
3086 DF023411
3087 DF023413
3087 DF023414
3087 DF023415
3087 DF023416
3087 QD023414
3087 OD072387
3087 SF023414
3087 SF023415
3088 DF023417
3088 OF023418
3089 DF019209
3089 DF019210
3090 DF019213
3090 DF019214
: PF Sm Bass
. UB Uhite Sucker
PF Brown Trout
BF Sea Catfish
UB Channel Catfish
PF Spotted Bass
BF Flathead Catfish
UB Redhorse Sucker
BF Flathead Catfish
UB Carp
UB Sm Buffalo
PF Black Crappie
UB Carp
PF Uhite Bass
UB Carp
UB Carp
PF Lm Bass
UB Carp
PF Uhite Bass
UB Catfish
UB Carp
PF Lm Bass
PF Lm Bass
UB Black Bullhead
PF Lm Bass
UB Channel Catfish
UB Channel Catfish
PF Black Drum
UB Catfish
PF Black Drum
UB Carp
PF Uhite Crappie
UP Bluegill
UP Lm Bass
PF Uhite Crappie
UB Carp
PF Uhite Crappie
UP Bluegill
UB Channel Catfish
PF Bluegill
PF Uhite Crappie
UB Carp
PF Uhite Crappie
UB Channel Catfish
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCOO
1.10
NA
0.75
1.00
NA
0.99
0.99
1.09
0.99
NA
NA
NA
NA
1.23
NA
NA
NA
NA
NA
NA
1.43
1.04
1.12
1.08
0.11
NA
NA
NA
4.32
0.99
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.99
1.05
0.98
1.27
12378
PECOD
0.92
NA
0.48
0.92
NA
0.93
0.92
0.99
0.92
NA
NA
1.47
NA
0.91
1.08
NA
0.92
NA
5.39
2.89
NA
0.93
1.01
NA
0.20
NA
NA
1.46
NA
0.92
NA
NA
NA
1.97
NA
NA
NA
NA
0.92
0.94
0.98
1.04
0.91
NA
123478
HXCDD
2.47
NA
0.65
2.47
NA
2.46
2.44
2.45
2.45
NA
NA
2.46
NA
2.45
2.46
NA
0.20
NA
0.76
NA
3.57
2.43
2.43
NA
0.20
2.47
2.47
2.46
NA
2.46
4.93
2.45
2.46
2.46
2.46
NA
1.11
1.36
2.46
2.46
2.45
2.46
2.44
2.46
123678
HXCDD
1.85
NA
0.65
1.85
NA
1.84
1.83
1.83
1.83
NA
NA
1.85
NA
1.83
NA
NA
NA
NA
NA
NA
NA
1.82
1.81
NA
0.55
2.51
NA
NA
NA
1.84
NA
1.83
NA
1.97
NA
NA
0.72
NA
NA
1.84
1.83
NA
1.82
NA
123789 1234678
HXCDD
1.38
1.38
0.65
1.38
1.37
1.38
1.37
1.37
1.37
NA
NA
1.37
NA
1.37
1.37
NA
0.20
NA
0.68
NA
NA
1.36
1.35
NA
0.20
1.38
NA
1.41
1.55
1.37
NA
1.37
1.37
.38
.37
2.94
.32
.98
NA
.37
.37
.38
1.36
NA
HPCOD
NA
NA
1.31
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.49
NA
NA
NA
NA
NA
NA
NA
2.56
NA
NA
NA
NA
1.32
NA
1.25
2.37
NA
NA
NA
NA
NA
NA
NA
1.29
NA
1.37
NA
2378
TCOF
NA
NA
0.20
0.49
NA
0.49
0.48
0.86
0.48
NA
NA
NA
NA
NA
NA
NA
1.09
NA
NA
0.50
NA
NA
NA
NA
0.20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDF
0.78
0.77
0.20
0.78
0.77
0.77
0.77
0.77
0.77
0.77
NA
1.03
NA
0.77
NA
NA
0.28
NA
0.20
0.77
NA
0.77
0.76
0.77
0.20
0.87
NA
NA
NA
NA
NA
NA
NA
0.96
NA
NA
NA
NA
0.77
0.77
0.77
0.77
0.76
NA
23478
PECDF
0.85
0.87
0.20
0.85
NA
0.85
0.84
0.84
0.84
NA
NA
0.85
NA
NA
NA
NA
0.20
NA
0.44
NA
1.76
0.84
0.83
NA
0.20
NA
NA
NA
NA
0.84
NA
NA
NA
NA
NA
NA
NA
NA
0.85
0.84
0.84
NA
0.84
NA
123478
HXCOF*
2.84
2.83
0.23
2.84
2.83
2.83
2.81
2.81
2.81
2.83
NA
2.83
0.87
2.81
NA
NA
0.20
NA
0.20
2.82
NA
2.80
2.79
2.83
0.20
2.84
NA
NA
NA
2.82
NA
2.81
2.83
2.83
2.82
2.94
0.94
0.96
2.83
2.82
2.82
2.83
2.81
2.82
123678
HXCDF
2.85
2.84
0.23
2.85
2.84
2.84
2.82
2.82
2.82
2.84
2.81
2.84
1.04
2.82
2.84
0.42
0.20
0.68
0.20
2.83
3.19
2.81
2.80
2.84
0.20
2.85
2.85
NA
3.93
2.83
NA
2.82
2.84
2.84
2.84
NA
1.18
1.20
2.84
2.83
2.83
2.84
2.82
2.83
123789
HXCDF
2.78
2.77
0.23
2.78
2.77
2.77
2.75
2.75
2.75
2.77
2.74
2.77
0.89
2.75
2.77
0.20
0.20
0.20
0.20
2.76
2.76
2.74
2.73
2.77
0.20
2.78
2.77
2.77
2.77
2.76
2.76
2.75
2.77
2.77
2.76
2.78
1.07
1.40
2.77
2.76
2.76
2.77
2.75
2.76
234678 1234678 1234789
HXCOF
1.96
1.96
0.23
1.96
NA
.96
.94
.94
.95
.96
.95
.95
0.86
1.95
NA
NA
0.20
NA
0.20
1.95
2.16
1.93
1.93
1.95
0.20
1.96
1.96
NA
NA
1.95
NA
1.95
1.96
1.96
1.95
NA
1.03
1.57
1.96
1.95
1.95
1.96
1.94
1.95
HPCDF
1.45
1.45
0.77
1.45
NA
NA
.43
.44
.44
NA
.43
.44
0.66
1.44
NA
NA
0.40
NA
0.32
NA
NA
1.46
NA
1.44
0.27
1.45
NA
NA
NA
.44
.76
.44
.44
.44
.44
NA
0.66
0.70
1.44
1.44
1.44
NA
1.43
1.76
HPCDF
2.62
2.61
0.77
2.62
2.61
2.61
2.59
2.59
2.60
2.61
2.59
2.61
1.66
2.60
2.61
0.24
0.20
0.26
0.20
2.60
2.61
2.58
2.57
2.61
0.20
2.62
2.62
NA
2.61
2.60
2.60
2.60
2.61
2.61
2.61
2.61
1.65
2.07
2.61
2.60
2.60
2.61
2.59
2.60
fc
-------
Episode SCC Type Description
3091 DF019217
3091 DF019218
3092 DF023501
3092 DF023502
3093 DF024011
3093 DF024118
3093 OD080387 L
3094 DC017201
3094 QD092988
3095 DC038801 F
3095 DC038802
3096 DC03S001
3096 DC035002
3096 QD052488
3097 DC038701
3097 DC038702
3098 DC038601
3098 DC038602 F
3098 QD032587 L
3100 DC019701
3100 DC019702
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF025001
3105 DF025002
3106 DE026801
3106 DE026802
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3109 DE025002
3110 DE022501
3110 DE022502
3111 DH015801
3111 DH015802
3112 DE022401
3112 DE022402
3113 DE021101
3113 DE021102
3114 DE021201
F WB River Cerpsucker
F PF White Crappie
F UB Carp
F PF Wai-mouth
F PF Lm Bass
F UB Sm Buffalo
UB Sm Buffalo
F BF Channel Catfish
L BF Channel Catfish
BF Brown Bullhead
UB Channel Catfish
BF Broun Bullhead
UB Channel Catfish
UB Channel Catfish
BF Broun Bullhead
UB Carp
UB White Sucker
PF American Eel
UB White Sucker
PF White Perch
UP Winter Flounder
PF Broun Trout
UB Channel Catfish
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
PF Walleye
PF White Bass
UB Carp
PF Walleye
UB Carp
UB Carp
PF Sm Bass
BF Flathead Catfish
BF Carp
PF Walleye
UB Silver Redhorse
UB Carp
PF Walleye
BF Channel Catfish
BF Carp
BF Carp
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378
TCDD
0.99
0.98
NA
0.98
1.01
NA
1.07
NA
NA
NA
5.16
NA
NA
NA
NA
NA
NA
NA
NA
1.60
1.25
1.88
3.67
NA
1.24
NA
NA
0.99
NA
NA
2.38
0.98
NA
NA
NA
1.67
NA
0.09
1.16
NA
1.26
1.60
NA
NA
12378
PECOD
0.92
0.91
NA
0.94
0.92
NA
NA
NA
NA
NA
4.92
1.07
NA
NA
4.78
NA
NA
NA
NA
NA
1.07
1.00
NA
1.42
0.95
2.99
NA
0.91
0.98
NA
NA
1.03
NA
NA
0.97
NA
NA
0.23
2.64
NA
1.06
NA
NA
1.35
123478
HXCDD
2.46
2.44
NA
2.45
2.46
NA
NA
2.46
2.46
2.46
3.37
2.46
3.69
NA
18.44
2.47
4.01
2.73
0.29
2.47
2.56
2.46
NA
NA
2.44
NA
2.45
2.45
2.46
2.46
2.45
2.45
2.47
2.43
2.44
NA
NA
0.29
0.20
NA
2.46
2.45
2.46
2.68
123678
HXCDD
1.84
1.82
NA
1.83
1.84
NA
NA
NA
NA
NA
NA
NA
NA
NA
6.27
NA
NA
NA
NA
NA
1.91
1.84
NA
NA
1.83
NA
2.05
1.83
NA
2.53
NA
1.83
NA
NA
1.83
NA
NA
0.29
NA
NA
1.84
NA
NA
NA
123789 1234678
HXCDD
1.38
1.36
NA
1.37
1.37
NA
NA
1.37
NA
1.38
NA
1.37
2.12
NA
3.13
NA
0.44
NA
NA
1.38
1.43
1.37
NA
.37
.36
NA
.37
.37
.37
1.37
1.36
1.36
NA
1.36
1.36
NA
NA
0.29
0.20
NA
1.37
1.37
1.72
1.38
HPCDD
NA
1.25
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
24.85
15.14
NA
NA
NA
NA
NA
1.27
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.25
NA
NA
1.25
NA
NA
2.26
2.57
NA
NA
NA
NA
NA
2378
TCDF
0.52
0.48
NA
0.48
0.48
0.86
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20
NA
NA
NA
NA
0.70
NA
NA
NA
NA
0.48
NA
NA
NA
NA
NA
0.49
NA
NA
NA
0.28
NA
NA
NA
NA
NA
NA
12378
PECOF
0.77
0.76
0.77
0.77
0.77
0.77
0.77
0.88
0.77
NA
NA
0.85
NA
NA
1.87
NA
0.51
0.20
0.43
NA
1.14
NA
NA
NA
0.77
NA
0.77
0.77
0.77
NA
NA
0.77
NA
0.76
0.78
NA
NA
0.20
0.31
1.20
0.77
1.08
NA
NA
23478
PECDF
0.85
0.84
1.53
0.84
0.84
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20
NA
NA
NA
NA
NA
NA
0.84
NA
NA
0.84
0.89
1.94
NA
0.84
NA
1.01
1.03
NA
NA
0.20
0.63
1.80
0.84
NA
NA
NA
123478
HXCDF*
2.83
2.80
2.89
2.82
2.83
NA
2.83
NA
NA
NA
NA
2.83
NA
NA
1.71
NA
0.21
0.20
1.21
NA
2.94
2.82
NA
NA
2.80
NA
NA
2.82
2.83
3.01
3.72
2.81
NA
NA
2.81
NA
NA
0.20
0.20
3.39
2.83
2.81
NA
2.83
123678
HXCDF
2.84
2.82
2.84
2.83
2.84
3.70
2.84
HA
NA
NA
3.85
2.84
3.82
NA
0.85
NA
0.20
0.20
0.30
2.85
2.95
2.83
NA
2.84
2.82
NA
2.83
2.83
2.84
2.84
2.81
2.82
3.29
2.80
2.82
2.81
NA
0.20
0.20
2.85
2.84
2.82
NA
2.84
123789
HXCDF
2.77
2.74
2.77
2.76
2.77
3.29
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.78
0.51
2.78
0.20
0.20
0.21
2.78
2.88
2.76
2.77
2.77
2.75
2.74
2.76
2.76
2.77
2.77
NA
2.75
2.78
2.73
2.75
2.74
2.76
0.20
0.20
NA
2.77
2.75
2.77
2.77
234678 1234678 1234789
HXCDF
2.14
.94
.96
.95
.96
3.23
.95
.96
NA
NA
3.06
1.96
NA
NA
0.85
NA
2.83
NA
NA
1.96
2.03
1.95
NA
NA
1.94
NA
1.95
1.95
1.96
1.99
NA
1.94
NA
NA
1.94
NA
NA
0.20
0.20
2.32
1.96
1.95
NA
1.96
HPCDF
NA
1.43
NA
1.44
1.44
1.45
1.57
NA
NA
NA
2.45
1.44
3.25
2.81
1.37
NA
NA
NA
NA
1.45
NA
1.44
NA
NA
1.43
NA
NA
NA
NA
NA
NA
1.43
NA
NA
1.43
NA
NA
0.28
0.26
NA
1.44
1.44
NA
1.45
HPCDF
2.61
2.59
2.61
2.60
2.61
2.62
2.61
2.61
2.61
2.60
2.61
2.61
2.61
2.62
0.91
2.62
0.35
0.20
0.40
2.62
2.71
2.60
2.61
2.61
2.59
2.59
2.60
2.60
2.61
2.61
2.59
2.60
NA
2.57
2.59
2.59
2.60
0.28
0.26
2.61
2.61
2.60
2.61
2.61
-------
DIOXIN / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3115 DE021301
3115 DE021302
3117 DE021501
3117 DE021502
3118 DE021601
3118 DE021602
3118 DE021603
3118 SE021602
3119 DE021701
3119 DE021702
3120 DE021801
3120 DE021802
3122 DE022001
3122 DE022003
3122 DE022004
3125 DE022301
3125 DE022302
3125 OD1 20888
3132 DE023201
3132 DE023202
3134 DE023401
3134 DE023403
3134 DE023405
3134 DE023406
3135 DE023501
3136 DE023602
3137 DE023701
3137 DE023702
3138 DE023801
3138 DE023802
3140 DE024002
3141 DE024102
3141 DE024103
3141 SE024102
3143 DE024401
3143 DE024402
3143 DE024403
3144 DE024901
3145 DE026601
3145 OD071988
3146 DE026701
3146 DE026702
WB Carp
PF Catfish
PF Lake Trout
PF Brown Trout
PF Walleye
WB Carp
WB Carp
WB Carp
WB Carp
PF Lm Bass
WB Carp
PF Bass
WB Carp
WB Redhorse Sucker
PF Sm Bass
WB Carp
PF White Bass
PF White Bass
WB Carp
WB Channel Catfish
PF Crappie
WB Carp
WB Carp
WB Sucker
WB Carp
PF Walleye
WB Redhorse Sucker
PF Walleye
WB Carp
PF Sm Bass
WB Carp
WB Carp
PF Northern Pike
WB Carp
Rotten (catf)
PF White Bass
WB Carp
WB Carp
WB N. Redhorse
WB N. Redhorse
WB Carp
PF Walleye
3146 00060288 L WB Carp
3146 SE026701 F WB Carp
2378
TCDD
NA
NA
NA
2.44
NA
NA
NA
NA
4.64
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.71
NA
NA
NA
0.97
1.35
1.00
NA
1.11
NA
NA
NA
NA
1.33
1.00
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDD
NA
NA
NA
NA
1.73
NA
NA
NA
NA
1.06
5.20
1.53
NA
0.22
0.24
NA
1.02
0.92
NA
NA
0.93
NA
NA
1.26
1.49
0.90
1.29
0.92
NA
1.22
1.35
NA
NA
NA
1.49
0.99
NA
NA
1.09
NA
NA
0.97
NA
NA
123478
HXCDD
3.45
2.46
2.45
2.52
2.47
NA
NA
NA
0.59
0.24
NA
0.89
NA
0.32
0.32
NA
2.47
2.46
NA
2.63
2.49
2.43
2.45
2.46
2.47
2.41
2.45
2.47
3.21
2.46
2.95
6.72
2.47
NA
2.45
2.47
NA
2.46
2.46
2.47
NA
2.47
2.46
NA
123678
HXCDD
NA
NA
NA
NA
1.84
NA
NA
NA
NA
2.60
NA
0.89
NA
1.51
0.32
NA
1.85
1.84
NA
NA
1.86
NA
NA
1.84
NA
1.80
1.83
1.85
2.41
NA
NA
NA
NA
NA
3.93
1.85
NA
2.32
NA
NA
NA
1.84
NA
NA
123789
HXCDD
NA
NA
.60
.41
.38
.37
.37
.22
1.31
0.24
0.20
0.89
NA
0.32
0.32
.38
.38
.38
NA
NA
.39
.36
.37
.38
.38
.34
.37
1.38
1.88
1.37
1.38
NA
1.38
NA
.37
.38
NA
.37
.37
.38
3.58
1.38
NA
NA
1234678
HPCDD
NA
NA
NA
NA
1.34
NA
NA
NA
NA
111.71
NA
3.92
NA
2.21
NA
NA
NA
NA
NA
NA
1.27
NA
NA
NA
NA
1.23
NA
1.34
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2378
TCDF
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.50
NA
0.55
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDF
NA
0.95
NA
1.65
0.98
NA
NA
NA
0.38
0.37
NA
0.48
1.98
0.31
0.30
NA
0.88
0.83
1.62
1.45
0.78
NA
NA
NA
0.78
0.76
0.89
0.78
NA
0.83
0.87
NA
NA
NA
1.34
NA
NA
NA
NA
0.78
NA
0.78
NA
NA
23478
PECDF
NA
NA
NA
NA
NA
NA
NA
NA
1.31
1.17
NA
0.60
NA
NA
0.40
NA
1.26
NA
NA
NA
0.86
NA
NA
NA
1.47
0.83
1.29
0.85
7.13
NA
NA
NA
NA
NA
1.38
NA
NA
NA
NA
NA
NA
0.85
NA
NA
123478
HXCDF*
NA
3.04
NA
2.83
2.83
2.82
NA
NA
1.25
0.20
NA
0.57
NA
0.20
0.20
NA
2.84
2.83
NA
NA
2.86
NA
NA
2.83
2.84
2.77
2.82
2.84
2.83
2.82
2.83
NA
2.84
NA
2.81
2.84
NA
2.83
2.83
2.83
NA
2.83
NA
NA
123678
HXCDF
2.89
2.84
NA
2.84
2.85
NA
NA
NA
0.57
0.20
0.58
0.20
NA
0.20
0.20
NA
2.85
2.84
2.91
2.82
2.87
2.80
2.82
2.84
2.85
2.78
2.83
2.85
2.84
2.84
2.84
NA
2.85
NA
2.83
2.85
3.82
2.84
2.84
2.85
NA
2.85
NA
NA
123789
HXCDF
2.76
2.77
2.76
2.77
2.78
2.76
2.77
0.88
0.20
0.20
0.20
0.20
2.76
0.20
0.20
2.78
2.78
2.77
2.76
2.75
2.80
2.73
2.75
2.77
2.78
2.71
2.76
2.78
2.77
2.76
2.77
2.77
2.78
0.89
2.76
2.78
2.75
2.77
2.77
2.77
2.77
2.77
2.77
0.88
234678 1234678 1234789
HXCDF
1.95
1.96
NA
1.96
NA
1.95
1.96
0.86
NA
0.28
NA
0.20
NA
0.40
0.20
2.13
1.96
1.96
NA
NA
1.98
2.06
1.95
1.96
2.18
1.91
1.95
1.96
1.96
1.95
1.96
NA
1.96
NA
1.95
1.96
NA
1.96
1.96
1.96
NA
1.96
NA
NA
HPCDF
NA
2.13
1.44
1.44
1.48
NA
NA
NA
1.36
0.72
NA
0.73
NA
0.25
0.25
NA
1.45
1.47
NA
NA
1.46
1.59
1.46
1.45
NA
1.41
.44
.45
.44
.44
.45
NA
NA
NA
.45
.45
NA
.44
.44
.45
NA
1.45
NA
NA
HPCDF
2.60
2.61
2.60
2.61
2.62
2.60
2.61
1.65
0.27
0.36
0.21
0.48
2.61
0.25
0.25
2.62
2.62
2.65
2.60
2.59
2.64
2.57
2.60
2.61
2.62
2.55
2.60
2.62
2.61
2.61
2.61
2.61
2.62
1.81
2.60
2.62
2.59
2.61
2.61
2.62
2.62
2.62
2.61
1.84
-------
Episode SCC Type Description
3147 DC035201
3148 DE027101
3148 DE027103
3149 DC038501
3150 DA008901
3151 DA009101
3151 DA009102
3151 00072887
3152 DA009201
3161 DC019801
3161 DC019802
3162 DJ022121
3162 DJ022122
3162 DJ022123
3162 DJ022403
3162 OJ024001
3162 DJ025103 0
3162 QD041889 0
3163 DJ022402 H
3163 DJ022404 H
3163 OJ024002 F
3163 OJ025102 0
3164 OD015701
3164 DD015702
3165 DD015703
3165 DD015704
3165 00031788
3166 DD015705
3166 DD015706
3167 DD015707
3167 DD015708
3167 OD040588
3167 SD015708
3168 DD015711
3168 DD015712
3168 SD015711
3169 00015713
3170 00015715
3171 OD015717
3172 DD015719
3172 DD015720
3173 DD015721
3173 DD015722
3173 OD070689
WB Carp
WB Carp
PF Walleye
WB White Sucker
WB White Sucker
WB White Sucker
PF Sm Bass
WB White Sucker
WB White Sucker
BF Black Bullhead
WB White Sucker
WB Big Skate
WB Ratfish
Dungeness Crab
PF Quillback Rockfish
WP Starry Flounder
Hepa t opanc reas,C rab
Hepatopancreas
Dungeness Crab
Dungeness Crab
WP Starry Flounder
Hepatopancreas,Crab
PF Lm Bass
WB Carp
PF Lm Bass
UB Redhorse Sucker
PF Lm Bass
PF Walleye
WB White Sucker
PF Lm Bass
WP Bluegill
PF Lm Bass
WP Bluegill
WB Carp
PF Lm Bass
WB Carp
WB Black Redhorse
WB Spotted Sucker
WB Spotted Sucker
WB Carp
PF Lm Bass
PF Lm Bass
WB Channel Catfish
PF Lm Bass
DIOX1N / FURAN DETECTION LIMITS, pg/g
2378
TCOD
NA
NA
1.30
0.51
NA
NA
NA
NA
NA
1.34
NA
NA
NA
1.61
1.12
NA
NA
NA
NA
2.24
NA
NA
1.64
NA
1.46
NA
NA
1.00
1.01
NA
NA
NA
NA
NA
NA
NA
0.99
1.16
1.07
HA
NA
0.99
NA
0.99
12378
PECOD
NA
NA
0.91
0.52
NA
NA
1.05
NA
NA
NA
NA
NA
1.03
1.81
1.04
NA
NA
NA
NA
NA
NA
NA
64.57
NA
1.89
NA
1.86
0.92
1.00
NA
NA
NA
NA
NA
1.00
NA
1.10
0.92
0.92
NA
0.92
0.93
NA
0.92
123478
HXCDD
2.52
NA
2.45
0.81
NA
2.47
2.45
2.73
2.45
NA
NA
2.46
2.45
2.74
2.45
2.47
NA
NA
2.46
2.45
2.47
2.47
2.46
2.46
2.46
NA
2.47
2.47
2.47
3.40
NA
NA
NA
NA
2.47
NA
2.46
NA
2.47
NA
2.47
2.46
2.46
2.46
123678
HXCDD
NA
NA
1.84
2.43
NA
NA
1.83
NA
NA
NA
NA
NA
NA
3.56
1.83
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.85
NA
NA
NA
NA
NA
NA
1.85
NA
1.84
NA
1.84
NA
1.85
1.84
NA
1.84
123789 1234678
HXCDD
1.38
NA
1.37
0.81
NA
NA
1.37
NA
1.37
NA
NA
1.65
1.37
1.56
1.37
NA
NA
NA
5.94
1.40
1.38
NA
NA
NA
1.43
2.13
1.38
1.38
1.38
2.53
NA
2.30
NA
NA
1.38
2.44
1.37
NA
1.38
NA
1.38
1.37
NA
1.37
HPCDD
NA
NA
NA
0.93
NA
NA
1.25
NA
NA
NA
NA
NA
2.01
NA
1.41
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4.43
NA
NA
NA
NA
1.26
NA
1.26
2378
TCOF
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.73
0.49
NA
0.49
0.67
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.50
NA
0.49
12378
PECDF
NA
NA
0.77
0.25
NA
NA
0.77
NA
NA
NA
NA
NA
NA
NA
1.01
NA
NA
NA
NA
NA
0.78
NA
4.24
NA
0.77
NA
0.78
0.78
0.78
0.77
NA
0.77
NA
NA
0.78
NA
0.77
0.77
0.77
NA
0.78
0.77
NA
0.77
23478
PECDF
NA
NA
NA
0.25
2.23
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.87
NA
NA
NA
NA
NA
NA
NA
193.32
NA
NA
NA
NA
0.85
NA
0.94
1.33
1.03
NA
NA
0.85
NA
0.95
0.86
0.85
NA
0.85
0.85
NA
0.85
123478
HXCDF*
NA
NA
2.82
3.33
NA
NA
2.81
NA
NA
2.80
NA
NA
NA
NA
2.81
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.84
2.84
NA
NA
NA
NA
NA
2.84
NA
2.82
2.83
2.83
NA
2.84
2.83
2.83
2.83
123678
HXCDF
2.85
3.48
2.83
0.33
4.61
2.85
2.82
2.84
2.83
2.81
NA
NA
3.37
NA
2.82
NA
NA
NA
NA
7.19
2.85
NA
2.84
NA
2.84
3.31
2.85
2.85
2.85
NA
NA
3.69
NA
3.12
2.85
1.28
2.83
2.84
2.84
NA
2.85
2.84
2.84
2.84
123789
HXCDF
2.78
2.74
2.76
0.33
NA
2.78
2.75
2.77
2.76
2.74
2.78
2.77
2.76
2.77
2.75
2.77
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.77
2.77
2.77
2.78
2.78
2.78
2.77
2.77
2.76
0.86
2.77
2.78
1.40
2.76
2.77
2.77
2.76
2.78
2.77
2.77
2.77
234678 1234678 1234789
HXCDF
NA
NA
1.95
0.33
NA
2.71
1.95
NA
.95
.98
NA
.96
.95
.96
.94
2.19
NA
NA
1.98
1.95
1.96
2.54
NA
3.08
NA
NA
NA
1.96
1.96
NA
NA
NA
NA
1.96
1.96
1.57
.95
.95
.96
.95
.96
.95
.96
.96
HPCDF
1.54
NA
1.44
0.51
NA
NA
NA
2.26
1.59
1.83
NA
2.23
1.44
1.79
1.43
NA
NA
NA
NA
1.79
NA
NA
NA
NA
NA
NA
NA
1.45
1.45
NA
NA
NA
NA
1.44
1.45
0.67
2.25
NA
1.45
NA
1.45
1.44
NA
1.44
HPCDF
2.62
2.59
2.60
0.51
NA
2.62
2.60
2.61
2.60
2.59
2.62
2.61
2.61
2.61
2.59
2.61
2.62
2.61
2.61
2.60
2.62
2.61
2.61
2.61
2.61
2.61
2.62
2.62
2.62
2.61
NA
2.61
NA
2.61
2.62
1.87
3.82
2.61
2.61
2.60
2.62
2.61
2.61
2.61
-------
Episode SCC Type Description
3174 DD015723
3174 DD015724
3175 DD01S801
3175 DD015802
3176 DD015803
3176 DD015804
3177 DD015805
3177 DD015806
3178 DD015807
3178 D0015808
3179 DD015809
3179 DD015810
3180 DD015812
3181 DD015813
3181 DD015814
3182 DD015815
3182 DD015816
3183 DD015817
3183 DD015818
3184 DD015819
3184 DD015820
3185 DD015821
3185 DD015822
3185 SD015821
3186 DD015823
3186 DD015824
3187 DD015902
3188 DD015903
3188 DD015904
3189 DD015905
3189 DD015906
3190 DD015907
3190 DD015908
3191 DJ024003
3191 DJ024005 M
3192 DJ024007 F
3192 DJ024009 H
3192 OD020789
3193 DC039001
3193 QD039001
3195 DH020104
3195 DH020105
3196 DH020108
3197 DH020110
PF Ln Bass
UB Channel Catfish
UB Channel Catfish
PF Lm Bass
UB Spotted Sucker
PF Lm Bass
UB Carp
PF Lm Bass
UB North Hogsucker
PF Redeye Bass
UB Golden Redhorse
PF Lm Bass
PF Lm Bass
PF Lm Bass
UB Carp
PF Rock Bass
UB Carp
UB Carp
PF Sauger
UB Carp
PF Uhite Crappie
UB Channel Catfish
PF Lm Bass
UB Channel Catfish
PF Spot
UP Southern Flounder
UP Sunnier Flounder
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UP Starry Flounder
Soft Shell Clams
UP Starry Flounder
Soft Shell Clams
Soft Shell Clams
PF Sm Bass
PF Sm Bass
UB Carp
UB Chub
UB Sucker
UB Sucker
2378
TCOD
0.99
1.10
NA
.02
.23
.11
.06
.04
.00
1.00
NA
0.99
0.99
1.12
NA
1.18
2.29
NA
NA
NA
1.04
NA
NA
NA
1.22
NA
1.02
2.70
1.39
2.36
NA
NA
NA
1.01
1.07
NA
1.19
1.23
NA
1.26
1.68
NA
1.08
1.12
12378
PECDD
0.92
0.92
NA
0.94
1.68
1.14
1.52
0.92
0.97
0.92
NA
1.13
0.93
0.92
NA
0.92
1.64
NA
0.92
NA
0.92
NA
NA
NA
0.92
1.04
1.21
NA
1.00
NA
0.93
NA
0.95
0.98
0.91
1.09
0.92
0.92
1.28
1.31
1.42
NA
NA
1.04
DIOXIN / FURAN DETECTION LIMITS, pg/g
123478 123678 123789 1234678 2378 12378
HXCDD
2.46
2.46
NA
2.46
2.47
2.46
NA
2.47
2.47
2.47
2.56
2.46
2.46
2.47
NA
2.46
2.48
2.46
2.46
NA
2.47
NA
NA
NA
2.46
2.46
2.47
NA
2.46
NA
2.45
NA
2.46
2.47
2.45
2.45
2.46
2.46
2.47
2.46
2.46
2.46
NA
2.46
HXCDD HXCDD
1.84
1.84
NA
NA
NA
1.84
NA
.85
.85
.85
NA
.84
.84
.84
NA
NA
3.04
3.23
.37
.37
NA
.37
.38
.37
.38
.38
.38
.38
.38
.37
.37
.38
NA
.37
.38
.37
1.84 1.38
NA NA
1.84 1.38
NA NA
NA NA
NA NA
1.84
NA
NA
NA
1.84
NA
1.83
NA
.84
.85
.84
.83
.84
.84
NA
1.86
2.06
NA
NA
1.84
.37
.38
NA
NA
.37
.36
.37
NA
.37
.38
.37
.37
.37
.37
.38
.38
.37
.37
.36
.37
HPCDD
1.26
NA
NA
NA
NA
1.34
NA
NA
NA
1.26
NA
1.26
1.62
1.32
NA
NA
NA
NA
NA
NA
1.44
NA
NA
NA
1.32
NA
NA
NA
1.83
NA
1.25
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
TCDF
0.49
NA
0.49
0.53
NA
0.56
NA
0.49
0.84
0.49
NA
0.59
0.60
0.49
NA
NA
NA
NA
0.93
1.24
0.52
NA
NA
NA
1.00
NA
0.71
NA
0.57
NA
0.72
NA
NA
0.49
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
PECDF
0.77
0.77
0.78
0.77
0.78
0.77
0.80
0.78
0.78
0.78
0.78
0.77
0.77
0.78
2.18
0.77
NA
NA
0.77
0.80
0.78
1.18
NA
NA
0.79
0.77
0.77
NA
0.77
0.77
0.77
0.88
0.77
0.78
0.77
0.77
0.77
0.77
0.77
1.03
0.79
0.87
0.77
0.77
23478
PECDF
0.84
0.93
NA
0.85
0.96
0.85
NA
0.85
0.85
0.85
0.92
0.85
0.85
0.85
NA
0.86
NA
NA
0.85
1.04
0.85
1.57
NA
NA
0.86
0.85
0.85
NA
0.84
NA
0.84
NA
0.84
0.85
0.84
NA
0.85
0.84
NA
NA
1.27
NA
0.84
0.85
123478
HXCDF*
2.82
2.82
NA
2.83
2.84
2.83
3.79
2.84
2.84
2.84
NA
2.83
2.82
2.83
NA
2.82
2.88
NA
2.83
NA
2.83
NA
NA
NA
2.83
2.83
2.83
NA
2.82
NA
2.82
3.57
2.82
2.84
2.82
2.81
2.83
2.82
2.83
2.83
2.83
2.82
NA
2.83
123678
HXCDF
2.83
2.83
2.85
2.84
2.85
2.84
2.85
2.85
2.85
2.85
2.85
2.84
2.84
2.85
NA
2.84
2.84
NA
2.84
2.85
2.85
NA
NA
NA
2.84
2.84
2.84
NA
2.83
2.81
2.83
2.76
2.83
2.85
2.83
2.83
2.84
2.83
2.84
2.84
2.84
2.83
2.82
2.84
123789
HXCDF
2.76
2.76
2.77
2.77
2.78
2.77
2.78
2.78
2.78
2.78
2.78
2.77
2.76
2.77
2.77
2.76
2.77
2.77
2.77
2.77
2.77
2.77
2.75
0.87
2.77
2.77
2.77
2.78
2.76
2.74
2.76
2.69
2.76
2.78
2.76
2.76
2.77
2.76
2.77
2.77
2.77
2.76
2.75
2.77
234678 1234678 1234789
HXCDF
1.95
1.95
NA
1.96
1.96
1.95
NA
1.96
1.97
1.96
NA
1.96
1.95
1.96
NA
1.95
1.96
NA
1.96
NA
1.96
NA
1.94
NA
1.95
1.96
1.96
NA
1.95
NA
1.95
NA
1.95
1.96
1.95
1.95
1.96
1.95
1.96
1.96
1.96
1.95
NA
1.96
HPCDF
1.44
1.44
NA
1.44
1.45
1.44
NA
1.45
NA
1.45
NA
1.44
1.44
1.45
NA
1.44
1.45
NA
1.44
NA
1.45
NA
NA
NA
1.44
1.45
1.45
NA
1.44
NA
1.44
NA
1.44
1.45
NA
NA
NA
NA
1.45
1.44
NA
NA
NA
1.44
HPCDF
2.61
2.60
2.62
2.61
2.62
2.61
2.62
2.62
2.62
2.62
2.62
2.61
2.61
2.62
2.61
2.61
2.61
2.61
2.61
2.62
2.62
2.75
2.59
NA
2.61
2.61
2.61
2.62
2.60
2.59
2.60
2.53
2.60
2.62
2.60
2.60
2.61
2.61
2.61
2.61
2.61
2.61
2.59
2.61
-------
Episode SCC Type Description
3198 OH020111
3199 DH020101
3199 DH020103
3200 DH020112
3201 DJ024012
3203 DJ024018
3205 DJ024024
3206 DJ022301
3206 OJ024102
3206 DJ024103
3208 DJ024109
3212 DJ024121
3212 QD050388
3216 DJ023707
3216 DJ023708
3216 Q0091688
3217 OJ023709
3217 OJ023710
3218 DJ023711
3218 DJ023712
3219 DJ023713
3219 OJ023714
3220 DJ023902
3220 DJ023903
3220 ODD12288
3221 DJ022405
3221 DJ023904
3221 DJ023905
3222 OJ023906
3222 DJ023907
3223 DJ023717
3224 DJ023715
3226 DJ023721
3227 OJ023723
3231 DJ023911
3234 DH020301
3235 DH020303
3236 DH020305
3236 DH020306
3237 DH020307
3237 DH020308
3238 DJ023918
3238 00080888
3241 DJ023924
F UB Sucker
F UB Carp
F UB Carp
F UB Sucker
F UB Carp
F UB Carp
H Crayfish (whole)
H UB Crayfish
F PF Lm Bass
F UB Sucker
F UB Sucker
F UB Carp
L UB Carp
F PF Squawfish
F UB Sucker
F UB Sucker
F PF Uhitefish
F UB Sucker
F PF Squaufish
F UB Sucker
F UB White Sturgeon
F PF White Sturgeon
F PF Squaufish
F UB Bridgelip Sucker
F PF Squaufish
F UB Carp
F BF Channel Catfish
F UB Sucker
F PF Squaufish
F UB Sucker
F UP Starry Flounder
H Soft Shell Clams
H Pacific Oysters
H Pacific Oysters
F UB Carp
F UP Squaufish
F UB White Sucker
F UB Largescale Sucker
F PF Brown Trout
F PF Rainbow Trout
F UB Largescale Sucker
F UP Dolly Varden
F UP Dolly Varden
F UP Dolly Varden
D10XIN / FURAN DETECTION LIMITS, pg/g
2378
TCOD
NA
NA
1.09
NA
NA
NA
0.99
NA
NA
NA
1.12
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.11
1.23
1.01
NA
1.15
NA
NA
1.08
1.25
1.37
1.11
1.04
NA
12378
PECDD
NA
NA
0.97
1.17
NA
NA
0.92
NA
1.41
NA
0.97
0.93
0.91
NA
NA
NA
NA
NA
NA
t.48
0.92
0.92
NA
NA
1.18
NA
NA
NA
1.14
NA
0.97
0.91
0.92
1.52
NA
0.94
NA
NA
NA
0.98
1.15
0.95
0.92
1.21
123478
HXCOO
2.46
2.47
2.47
2.46
NA
3.47
2.47
2.64
2.46
NA
2.48
2.47
2. 45
2.47
2.48
2.46
NA
2.46
2.46
2.46
2.46
2.47
2.46
2.98
2.45
2.46
2.47
2.44
2.47
2.46
2.46
2.45
2.47
2.47
2.67
2.53
2.51
NA
2.47
2.46
2.47
2.46
2.46
2.46
123678 123789 1234678 2378 12378 23478 123478 123678 123789 234678 1234678 1234789
HXCDD HXCOD HPCOD TCDF PECDF PECDF HXCDF* HXCDF HXCOF HXCDF HPCDF HPCDF
NA 1.38 NA NA NA NA 2.83 2.84 2.77 .96 1.47 2.61
NA NA NA NA 0.78 0.91 2.84 2.85 2.78 .96 NA 2.62
1.85 1.38 NA 1.05 0.90 0.93 2.84 2.85 2.78 .96 1.45 2.62
1.84 1.37 NA NA 0.77 NA 2.82 2.83 2.76 .95 1.44 2.60
NA NA NA NA NA NA NA NA 2.77 NA NA 2.61
NA NA NA NA NA NA NA NA 2.79 NA NA 2.63
1.85 1.38 NA 0.57 0.78 0.85 2.84 2.85 2.78 .96 1.45 2.62
NA NA NA NA NA NA NA NA NA NA NA NA
NA 1.38 NA NA 0.84 NA 2.83 2.84 2.77 .96 NA 2.61
NA NA NA NA NA NA NA 2.79 2.72 NA NA 2.56
1.85 1.38 NA NA 0.78 0.85 2.85 2.86 2.79 .97 1.45 2.63
1.85 1.38 NA 0.61 0.78 0.85 2.84 2.85 2.78 .96 1.45 2.62
1.83 1.37 1.65 0.77 0.77 0.84 2.81 2.82 2.75 .94 1.44 2.59
NA 1.38 NA NA NA NA 2.84 2.85 2.78 .96 1.45 2.62
NA NA NA NA NA NA 2.84 2.86 2.78 .97 NA 2.62
NA NA NA NA 0.87 NA 2.83 2.84 2.77 .96 NA 2.61
NA 1.35 NA NA 0.82 NA NA 2.79 2.72 NA NA 2.56
1.84 1.37 NA NA 0.77 0.85 NA 2.84 2.77 NA .44 2.61
NA 1.37 NA NA NA NA 2.82 2.83 2.76 .95 .44 2.61
NA 1.38 2.27 NA 0.83 1.18 NA 2.84 2.77 .96 NA 2.61
1.84 1.37 NA NA NA NA 2.82 2.83 2.76 .95 .44 2.60
1.84 1.38 NA NA 0.77 0.85 2.83 2.84 2.77 .96 .45 2.61
NA 1.37 NA NA NA 1.03 2.82 2.83 2.76 .95 .44 2.60
1.84 1.37 NA NA NA NA 2.82 2.83 2.76 .95 .46 2.60
1.96 1.37 1.91 NA 0.77 NA 2.82 2.83 2.76 .95 .44 2.60
NA 1.37 3.20 NA NA NA 2.83 2.84 2.77 .96 .44 2.61
NA .38 NA NA 0.77 NA 2.83 2.84 2.77 .96 .45 2.61
1.83 .36 NA NA 0.77 NA NA 2.82 2.75 .94 .43 2.59
NA .38 1.93 NA 0.78 NA 2.84 2.85 2.78 .96 .45 2.62
NA .37 NA NA 0.77 NA 2.83 2.84 2.77 .95 NA 2.61
NA .37 NA NA 0.77 1.24 2.82 2.83 2.76 .95 NA 2.60
NA .82 NA NA 0.77 0.87 NA 2.83 2.76 .95 NA 2.60
1.84 .38 1.47 NA 0.78 0.95 2.83 2.85 2.77 .96 1.45 2.62
2.81 NA NA NA 0.77 1.22 2.83 2.84 2.77 .96 NA 2.61
NA .37 NA NA NA 2.34 NA 2.84 2.76 NA NA 2.61
1.90 .42 NA 0.91 0.80 0.87 2.91 2.92 2.85 2.01 1.49 2.69
NA .39 NA NA 0.83 NA 2.86 2.87 2.80 1.97 NA 2.64
NA .39 NA NA 0.82 NA 2.86 2.87 2.80 1.98 NA 2.64
2.72 .38 2.09 NA 0.99 1.08 2.84 2.85 2.78 1.96 .45 2.62
1.84 .37 1.26 NA 0.77 1.06 2.82 2.83 2.76 .95 .44 2.61
1.85 .38 1.59 NA 0.81 1.40 2.84 2.85 2.78 .96 .45 2.62
1.84 .38 NA NA 0.77 0.85 2.83 2.84 2.77 .96 .45 2.61
1.84 .37 NA NA 0.77 0.85 2.83 2.84 2.77 .95 .44 2.61
NA .38 NA NA 0.81 1.02 2.83 2.84 2.77 .96 .44 2.61
-------
Episode SCC Type Description
DIOXIN / FURAN DETECTION LIMITS, pg/g
3244 DJ023622
3245 DJ023623
3245 DJ023624
3246 DJ022108
3246 DJ022109
3248 DJ022502
3249 DJ022504
3250 DJ022506
3252 DJ022510
3252 QD082288
3256 DJ022517
3256 DJ022518
3258 DC038901
3258 DC038902
3259 DB000466
3259 DB069101
3260 DB000493
3261 DY026002
3262 DY026004
3264 DY022602
3266 DY022702
3267 DY022101
3267 DY022102
3267 QD020288
3269 DY022106
3270 OY022107
3270 DY022108
3270 SY022108
3271 DY022110
3272 DY022111
3272 DY022112
3273 DY022113
3273 DY022114
3274 DY022116
3275 DY022118
3276 DY022119
3276 DY022120
3278 DY022124
3281 DY022205
3282 DY022207
3283 DY022209
3285 DY022212
3285 DY022213
3286 DY022215
F UB Coast Sculpin
F UP Spotted Ratfish
F UP Flathead Sole
F PF Red Striped Rockfish
F UP Flathead Sole
F UB Composite Bottom
F UB Sucker
F UB Sucker
F UB Sucker
L UB Sucker
F PF Sm Bass
F UB Sucker
F PF Spot
F UB Croaker
F UB Goldfish
F UB Sucker
F UB Carp
F UB Striped Mullet
F UB Tilapia Tilapia
F UB Hornyhead Turbot
F UB Channel Catfish
F PF Rainbow Trout
F UB Sacramento Sucker
L PF Rainbow Trout
F UB Channel Catfish
F PF Squaufish
F UB Sucker
F UB Sucker
F UB Sucker
F PF Leopard Shark
F UB White Surfperch
F UB Sculpin
F UB Surf Smelt
F UB Sculpin
F UB Sucker
F UB Walleye
F PF Brown Rockfish
F UB Sacramento Sucker
F UB Sucker
F UB Carp
F UB Carp
F UP Stingray
F UB Diamond Turbot
F UB Carp
2378
TCDD
.11
.02
.11
.14
0.95
.01
.00
.10
NA
NA
NA
NA
NA
1.01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.74
NA
NA
NA
NA
0.99
NA
NA
1.23
1.11
0.99
NA
1.13
0.99
0.99
1.70
NA
NA
1.76
NA
12378
PECDD
0.94
0.91
NA
0.92
0.88
0.95
0.92
1.30
1.16
1.05
0.92
0.93
2.89
0.92
NA
1.68
1.25
1.98
0.96
NA
1.57
1.14
0.97
1.28
NA
NA
1.03
0.33
1.00
0.92
NA
1.35
1.07
0.93
1.00
NA
0.98
0.92
1.15
1.23
NA
NA
NA
NA
123478
HXCDD
2.46
2.43
2.46
2.46
2.36
2.47
2.47
2.45
2.47
2.47
2.46
2.40
2.61
2.47
3.12
NA
2.47
NA
2.46
2.47
2.46
2.46
2.47
2.47
2.47
2.47
2.46
1.04
2.44
2.46
2.70
2.47
2.47
2.49
2.46
2.45
2.42
2.46
2.46
2.56
2.50
NA
2.46
NA
123678 123789
HXCDD HXCDD
1.84 .37
1.82 .36
2.01 .38
1.84 .38
1.76 .32
1 .85 .38
1.85 .38
NA .37
1.87 .38
NA .38
1.84 .37
1.79 .34
3.20 .47
NA .39
NA NA
NA .37
2.06 .38
NA NA
NA .37
NA .53
1.84 .38
1.84 .37
1.85 .38
1.84 .38
NA .38
NA .38
1.84 .38
0.65 .22
NA .36
NA .37
NA NA
NA .38
.84 .38
.86 .39
.84 .38
NA NA
NA .35
.84 .38
.84 .37
.91 .44
NA .40
NA NA
NA NA
NA NA
1234678
HPCDD
NA
NA
NA
3.00
NA
NA
NA
NA
NA
NA
NA
NA
5.25
NA
NA
NA
NA
NA
NA
NA
NA
2.60
NA
NA
NA
2.27
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.27
NA
NA
NA
NA
2378
TCDF
NA
NA
1.25
0.52
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.81
NA
NA
NA
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.49
NA
NA
0.49
0.71
NA
NA
NA
NA
NA
12378
PECDF
0.88
0.77
0.77
0.77
0.74
0.78
0.78
0.77
0.78
0.78
0.77
0.75
NA
NA
0.77
NA
NA
NA
0.84
0.92
0.77
NA
0.78
0.90
0.81
0.78
0.77
0.43
0.77
0.77
NA
NA
0.77
0.78
0.77
0.77
0.76
0.77
0.77
0.98
NA
NA
1.05
NA
23478
PECDF
0.92
0.84
1.08
0.85
0.81
0.85
0.85
NA
0.97
NA
0.84
0.82
NA
0.85
NA
NA
NA
NA
0.89
NA
NA
NA
0.99
NA
NA
NA
0.96
NA
0.84
1.01
NA
NA
0.85
0.85
0.85
NA
NA
0.85
0.84
NA
NA
NA
NA
NA
123478
HXCDF*
2.83
2.80
2.83
2.83
2.71
2.84
2.84
2.82
2.83
2.84
2.82
2.76
2.87
NA
NA
2.83
2.84
NA
2.82
2.86
2.83
2.83
2.84
2.83
2.84
2.84
2.83
0.93
2.80
2.82
2.83
NA
2.83
2.86
2.83
2.81
2.78
2.83
2.82
2.83
NA
NA
2.91
2.93
123678
HXCDF
2.84
2.81
2.84
2.84
2.72
2.85
2.85
2.83
2.85
2.85
2.83
2.77
2.90
2.85
NA
2.84
2.85
2.83
2.84
2.85
2.84
2.84
2.85
2.85
2.85
2.85
2.84
1.23
2.81
2.84
NA
2.85
2.84
2.87
2.84
2.82
2.79
2.84
2.84
2.84
2.89
3.36
NA
NA
123789 234678 1234678
HXCOF HXCDF HPCDF
2.77 1.96 .44
2.74 1.93 .43
2.77 1.96 .45
2.77 1.96 .44
2.65 1.87 .38
2.78 1.96 NA
2.78 1.96 1.45
2.76 1.95 NA
2.77 1.96 1.45
2.78 1.96 1.45
2.76 1.95 1.44
2.70 1.91 NA
2.81 1.99 1.45
2.78 NA NA
2.77 1.96 NA
2.77 1.96 NA
2.78 1.96 1.76
2.76 NA NA
2.76 1.95 NA
2.78 1.96 NA
2.77 1.96 .45
2.77 1.96 .44
2.78 1.96 .45
2.77 .96 .45
2.78 .96 .45
2.78 .96 .45
2.77 .96 .45
0.96 0.95 0.70
2.74 .94 .43
2.76 .95 .44
2.77 .96 .63
2.77 NA NA
2.77 .96 .45
2.80 .97 .46
2.77 .96 .45
2.75 .94 NA
2.72 .92 NA
2.77 .96 .44
2.76 .95 .44
2.77 .96 .45
2.82 .99 NA
2.78 NA NA
2.73 .93 1.59
2.81 .99 NA
1234789
HPCDF
2.61
2.58
2.61
2.61
2.50
2.62
2.62
2.60
2.62
2.62
2.61
2.54
2.62
2.62
2.61
2.61
2.62
2.60
2.61
2.62
2.61
2.61
2.62
2.62
2.62
2.62
2.61
2.07
2.58
2.61
2.61
2.62
2.61
2.64
2.61
2.59
2.57
2.61
2.61
2.61
2.66
2.62
2.57
2.65
-------
Episode SCC Type Description
OIOXIN / FURAN DETECTION LIMITS, pg/g
3287 DY022216 F UB
3288 DY022218 F UB
3288 Q0060188 F UB
3289 DY022219 F UP
3289 DY022220 F UB
3290 DY022221 F PF
3290 DY022222 F UB
3294 DJ022111 F UP
3294 DJ022113 H
3295 DJ022114 F UP
3296 DB040101 F UB
3297 08041501 F UB
3297 DB041504 F PF
3297 SB041501 F UB
3298 DB041601 F UB
3298 OB041604 F PF
3298 QD112988 L PF
3299 DB040601 F UB
3299 DB040604 F PF
3300 DB040201 F UB
3300 DB040204 F PF
3300 SB040201 F UB
3301 08041101 F UB
3301 08041104 F PF
3301 QD092088 L UB
3301 SB041101 F UB
3302 DB041901 F UB
3302 DB041904 F PF
3303 DB042301 f UB
3304 DB041001 F PF
3304 DB041004 F UB
3305 DB042001 F UB
3305 DB042004 F PF
3306 DB041801 F UB
3307 DB042101 F UB
3307 OD100588 L UB
3308 DB040001 F PF
3308 QD030689 L PF
3309 DB041301 F UB
3310 DC032701 F UB
3310 DC032702 F PF
3311 DC032801 F UB
3311 DC032802 F PF
3312 DC033101 F UB
Titapia Zilli
Sucker
Sucker
Bocaccio
Sculpin
Redear Sunfish
Blackfish
True Cod
Mussel
Atlantic Salmon
White Sucker
Carp
Sm Bass
Carp
Carp
Lm Bass
Lm Bass
White Sucker
Lm Bass
White Sucker
Sm Bass
White Sucker
Carp
Northern Pike
Carp
Carp
White Sucker
Lm Bass
White Sucker
Northern Pike
White Sucker
Channel Catfish
Sm Bass
White Sucker
White Sucker
White Sucker
Northern Pike
Northern Pike
White Sucker
Bullhead
Walleye
Redhorse Sucker
Sm Bass
Redhorse Sucker
2378
TCDD
NA
1.09
1.20
0.99
1.20
1.07
NA
1.02
0.99
1.11
1.34
NA
1.14
NA
NA
0.99
0.99
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.48
NA
NA
NA
1.11
1.01
NA
NA
1.21
1.29
1.37
2.12
12378
PECDD
0.99
0.99
1.14
0.93
0.97
0.96
NA
0.94
0.92
0.96
1.04
NA
0.93
NA
NA
0.92
0.92
NA
NA
NA
1.02
NA
NA
0.95
NA
NA
NA
0.92
NA
0.94
NA
NA
0.94
1.11
1.41
1.12
0.93
0.94
0.97
NA
0.94
1.00
0.94
NA
123478
HXCDD
2.46
2.47
2.45
2.45
2.46
2.47
NA
2.47
2.46
2.47
2.44
2.78
2.46
NA
NA
2.46
2.47
NA
2.46
2.46
2.46
1.10
NA
2.46
5.04
NA
2.46
2.47
2.46
2.45
2.45
2.63
2.45
2.46
2.43
2.46
2.47
2.47
2.47
NA
2.47
2.46
2.47
2.47
123678
HXCDD
.84
.85
.83
.83
.84
.85
NA
1.85
1.84
NA
1.83
NA
1.84
NA
NA
1.84
1.84
NA
1.84
2.06
1.84
0.67
NA
1.84
NA
NA
2.05
1.85
NA
1.84
NA
NA
1.83
1.84
.82
.84
.84
.84
NA
NA
.84
.84
.85
NA
123789 1
HXCDD
1.37
1.38
1.37
1.37
1.37
1.38
NA
1.38
1.38
1.38
1.36
NA
1.37
1.24
NA
1.38
1.38
1.37
1.37
1.37
1.38
1.31
NA
1.38
NA
1.70
1.38
1.38
1.37
1.37
1.37
1.38
1.37
1.37
1.36
1.37
1.38
1.38
1.38
NA
1.38
1.37
1.38
1.38
234678
HPCOO
NA
NA
NA
NA
NA
NA
NA
1.41
1.50
NA
NA
NA
NA
NA
NA
1.34
1.36
NA
NA
NA
1.26
NA
NA
1.35
NA
NA
NA
NA
NA
1.25
NA
NA
1.25
NA
NA
1.58
1.30
1.26
NA
NA
NA
NA
1.26
NA
2378
TCDF
NA
NA
NA
NA
NA
0.60
NA
NA
0.55
NA
NA
NA
0.51
NA
NA
0.51
0.49
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.65
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECDF
0.77
0.78
0.77
0.85
0.77
0.78
NA
0.78
0.77
0.78
0.77
NA
0.77
NA
NA
0.77
0.77
NA
NA
NA
0.80
NA
NA
0.79
NA
NA
NA
0.78
0.77
0.77
NA
NA
0.77
NA
1.04
NA
0.77
0.77
0.78
NA
0.78
NA
0.80
NA
23478
PECDF
0.85
NA
NA
0.90
0.84
0.85
NA
0.85
0.85
0.85
NA
NA
NA
NA
NA
0.85
0.85
NA
NA
NA
1.59
NA
NA
1.08
NA
NA
NA
0.88
NA
0.91
NA
NA
1.00
NA
NA
NA
0.85
0.85
0.86
NA
0.85
NA
0.86
NA
123478
HXCDF*
2.83
2.84
2.81
2.82
2.82
2.84
NA
2.84
2.83
2.84
2.81
NA
NA
NA
NA
2.83
2.83
NA
NA
NA
2.83
NA
NA
2.83
NA
NA
NA
2.84
2.83
2.82
2.82
NA
2.81
2.83
2.79
2.83
2.83
2.83
2.84
2.95
2.83
2.82
2.84
2.83
123678
HXCDF
2.84
2.85
2.83
2.83
2.83
2.85
NA
2.85
2.84
2.85
2.82
NA
NA
NA
NA
2.84
2.84
NA
3.48
2.84
2.84
1.17
NA
2.84
NA
NA
2.84
2.85
2.84
2.83
2.83
NA
2.82
2.84
2.81
2.84
2.84
2.84
2.85
NA
2.85
2.83
2.85
2.85
123789
HXCOF
2.77
2.78
2.76
2.76
2.76
2.78
2.73
2.78
2.77
2.78
2.75
2.77
2.76
0.87
2.77
2.77
2.77
2.77
2.76
2.77
2.77
1.06
2.78
2.77
2.77
1.07
2.77
2.78
2.77
2.76
2.76
2.77
2.75
2.77
2.74
2.77
2.77
2.77
2.78
2.76
2.77
2.76
2.78
2.77
234678 1
HXCDF
1.95
1.96
1.95
1.95
1.95
1.96
NA
1.96
1.96
1.96
1.94
2.37
1.95
NA
NA
.96
.96
NA
.95
.96
.96
.03
NA
1.96
NA
NA
1.96
1.96
1.96
1.95
1.95
1.97
1.94
1.95
1.93
1.96
1.96
1.96
1.96
2.02
1.96
1.95
1.96
1.96
234678 1
HPCDF
NA
1.45
1.44
1.44
1.44
1.45
NA
1.45
1.45
1.45
1.43
NA
1.44
NA
NA
1.44
1.45
NA
NA
NA
1.44
0.65
NA
1.45
NA
NA
NA
1.45
NA
1.44
1.44
1.59
1.43
1.44
1.43
1.44
1.45
1.45
NA
2.31
1.45
1.44
1.45
1.45
234789
HPCDF
2.61
2.62
2.60
2.60
2.60
2.62
2.57
2.62
2.61
2.62
2.59
NA
2.61
1.81
2.78
2.61
2.61
NA
2.60
2.61
2.61
1.64
2.62
2.61
2.67
2.07
2.61
2.62
2.61
2.60
2.60
2.62
2.59
2.61
2.58
2.61
2.61
2.61
2.62
2.61
2.62
2.60
2.62
2.62
-------
Episode SCC Type Description
3312 DC033102
3313 DC033201
3313 DC033202
3314 DC033301
33U DC033302
33U SC033301
3314 SC033302
3315 DC033401
3316 DC033501
3316 DC033502
3317 OC033601
3317 DC033602
3317 SC033601
3317 SC033602
3318 DC033701
3318 DC033702
3319 DB041401
3319 QD063088
3320 DB041412
3321 DB040401
3322 DB040412
3323 DB041206
3324 DB041252
3325 DB041218
3325 QD082988
3326 DB041208
3327 DB040301
3327 DB040315
3328 DD029111
3328 00029112
3328 SD029111
3328 SD029112
3329 DD016003
3329 S0016003
3330 DD029109
3330 00029110
3330 DD029423
3331 00016001
3331 DD016002
3331 DD016007
3331 00016008
3331 S0016008
3332 00016009
3332 00016010
F PF Sin Bass
F WB Redhorse Sucker
F PF Soi Bass
F UB Channel Catfish
F PF White Bass
F UB Channel Catfish
F PF White Bass
F WB Carp
F WB White Sucker
F PF Brown Trout
F WB White Sucker
F WP Pumpkinseed
F WB White Sucker
F WP Pumpkinseed
F WB White Sucker
F PF Rock Bass
F UP Uinter Flounder
F UP Uinter Flounder
F UP Bluefish
F UP Uinter Flounder
F UP Bluefish
F UP Uinter Flounder
F UP Bluefish
F UP Bluefish
L UP Bluefish
F UP Bluefish
F UP Bluefish
F UP Bluefish
F UB Carp
F PF Lm Bass
F UB Carp
F PF Lm Bass
F UB Boutin
F UB Bowfin
F PF Suuannee Bass
F UB Spotted Sucker
F PF Black Crappie
F UB Broun Bullhead
F PF Lm Bass
F UB Carp
F BF White Catfish
F BF White Catfish
F WP Spotted Drum
F PF Caranx Hippos
DIOXIN / FURAN DETECTION
2378 12378
TCDD PECDD
1.01 0.92
NA NA
NA 0.99
NA NA
NA 0.96
NA NA
NA 0.22
1.33 NA
NA NA
NA 1.05
NA NA
NA 0.92
NA 0.38
NA 0.27
NA 1.00
NA 0.92
1.66 1.24
NA 1.20
NA 1.61
NA NA
NA 0.91
NA 0.92
NA .06
NA .05
NA .03
NA .03
NA .36
NA NA
NA NA
NA 0.94
NA NA
NA 0.25
NA NA
NA NA
1.20 1.30
NA NA
0.99 0.92
NA 0.92
NA 0.99
NA NA
NA NA
NA NA
NA NA
1.16 0.99
123478
HXCDD
2.47
2.46
2.47
2.46
2.47
NA
1.15
NA
2.46
2.46
2.46
2.46
1.07
1.15
2.46
2.45
2.47
2.47
2.47
2.44
2.44
2.47
2.45
2.46
2.46
2.46
2.46
NA
NA
2.46
1.36
1.11
2.47
1.04
2.47
2.45
2.47
2.46
2.46
2.47
2.47
1.12
NA
2.45
123678 123789
HXCDD HXCDD
1.84 .38
NA .38
1.85 .38
NA NA
1.85 .38
NA .33
0.64 .34
NA NA
NA .37
1.84 .37
NA .37
1.84 .37
0.64 .22
0.64 .33
NA .37
.83 .37
.86 .38
NA .38
.84 .38
NA .37
.82 .36
.84 .38
.83 .37
.84 .37
.84 .37
.84 .37
.84 .38
NA NA
NA .37
1.84 .37
NA .21
0.65 .31
NA .38
NA .22
1.84 .38
NA NA
1.85 .38
NA .37
1.84 .37
4.91 NA
NA NA
NA 1.32
NA NA
1.83 1.37
1234678
HPCDD
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
NA
NA
1.08
NA
NA
NA
NA
NA
4.10
NA
1.29
2.23
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.63
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.25
LIMITS,
2378
TCOF
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.49
NA
0.49
NA
NA
NA
NA
NA
NA
0.50
P9/9
12378
PECOF
0.77
NA
0.78
NA
NA
NA
NA
NA
NA
0.77
NA
1.15
NA
NA
NA
0.77
NA
NA
NA
NA
NA
0.88
NA
NA
NA
NA
NA
NA
NA
0.77
1.04
0.43
NA
NA
0.77
0.77
0.78
0.77
0.77
NA
0.78
0.43
NA
0.77
23478
PECDF
0.91
NA
0.85
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.84
NA
NA
NA
NA
NA
0.92
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.85
NA
0.85
0.84
0.84
1.41
NA
NA
NA
0.84
123478
HXCDF*
2.83
2.83
2.84
NA
NA
NA
0.89
2.82
NA
NA
2.83
2.82
0.87
0.88
2.82
2.81
2.84
2.83
2.83
2.81
2.80
2.83
2.81
2.83
2.83
2.83
2.83
2.83
2.82
2.82
NA
0.94
NA
NA
2.83
2.82
2.84
2.82
2.82
3.33
2.84
0.94
2.81
2.81
123678
HXCDF
2.84
2.84
2.85
NA
2.85
1.10
1.11
2.83
NA
2.84
2.84
2.84
1.03
1.10
2.84
2.83
2.85
2.85
2.84
2.82
2.81
2.84
2.82
2.84
2.84
2.84
2.84
2.84
2.83
2.83
1.22
1.18
NA
NA
2.84
2.83
2.85
2.84
2.83
2.84
2.85
1.19
2.83
2.82
123789 234678
HXCDF HXCDF
2.77 1.96
2.77 1.96
2.78 1.96
2.77 NA
2.78 1.96
0.99 0.91
0.99 0.91
2.76 .95
2.77 .96
2.77 .95
2.77 .95
2.76 .95
0.89 .86
0.99 .91
2.76 .95
2.76 .95
2.78 .96
2.77 .96
2.77 .96
2.75 .94
2.74 .94
2.77 .96
2.75 .95
2.77 .96
2.77 .96
2.77 .95
2.77 .96
2.77 .96
2.76 .95
2.76 .95
0.96 .95
1.07 .03
2.77 NA
0.96 .95
2.77 .96
2.76 .95
2.78 .96
2.76 .95
2.76 .95
2.77 NA
2.78 .96
1.07 .04
2.76 .95
2.75 .94
1234678
HPCDF
1.45
1.50
1.45
NA
1.45
0.71
0.67
1.44
1.44
1.44
1.44
1.44
0.67
0.67
1.44
1.44
1.45
1.45
1.78
1.43
1.43
1.45
1.44
1.44
1.44
1.44
1.44
NA
1.44
1.44
0.66
0.66
NA
NA
1.45
1.44
1.45
1.44
1.44
NA
1.45
0.71
1.44
1.43
1234789
HPCDF
2.61
2.61
2.62
NA
2.62
1.87
1.88
2.60
2.61
2.61
2.61
2.61
1.87
1.87
2.61
2.60
2.62
2.62
3.12
2.59
2.59
2.61
2.60
2.61
2.61
2.61
2.61
2.61
2.60
2.60
1.80
1.65
2.62
1.81
2.61
2.60
2.62
2.61
2.61
2.61
2.62
2.07
2.60
2.59
-------
Episode SCC Type Description
3333 DDO16011
3333 DD016012
3333 DD029108
3333 QD1215B8
3334 DD016013
3334 DD016014
3335 DD016015
3335 DD016016
3335 DD029101
3335 DD029102
3335 DD029103
3335 QD081588
3335 SD016015
3336 DD016004
3336 DD016005
3336 DD016006
3336 DD016017
3336 DD016018
3336 QD0922B8
3337 DD016019
3337 DD016020
3337 QD0513B8
3338 DD016021
3338 DD016022
3338 DD029107
3339 DD016023
3339 DD016024
3339 QD016023
3340 DD029113
3340 DD029114
3340 SD029114
3341 OD016103
3341 DDO16104
3341 00092788
3341 SD016103
3341 SD016104
3342 DDO16105
3342 DD016106
3343 DD016107
3343 DDO16108
3344 DDO16109
3344 DDO16110
3344 SD016109
3345 DDO16111
F PF Bluefish
F WB Sea Catfish
F PF Ueakfish
L PF Bluefish
F UB Sea Catfish
F BF Striped Mullet
UP Spot
PF Spotted Bass
UP Red Drum
UB Southern Flounder
UP Sheepshead
UP Southern Flounder
UP Spot
UP Black Drum
PF Striped Mullet
UP Sheepshead
UP Red Drum
PF Spotted Seatrout
PF Spotted Seatrout
UB Spotted Sucker
PF Lm Bass
UB Spotted Sucker
PF Lm Bass
UB Spotted Sucker
PF Chain Pickerel
UB Carp
PF White Bass
UB Carp
PF Lm Bass
UB Channel Catfish
UB Channel Catfish
PF Lm Bass
UB Catfish
PF Lm Bass
PF Lm Bass
UB Catfish
UB Spotted Sucker
PF Bluegill
UB White Sucker
PF Redbreast Sunfish
UB Carp
PF Lm Bass
UB Carp
UB Redhorse Sucker
2378
TCDD
NA
NA
1.05
NA
NA
1.00
NA
1.05
NA
NA
NA
NA
NA
0.99
NA
NA
1.17
0.99
0.99
NA
NA
NA
1.07
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.10
NA
NA
NA
NA
NA
NA
12378
PECOD
NA
NA
0.93
NA
NA
0.91
NA
0.92
0.92
NA
NA
NA
NA
0.94
1.22
NA
0.92
0.92
0.92
NA
0.97
NA
0.95
NA
0.97
NA
NA
NA
0.93
NA
NA
0.98
NA
0.97
0.22
NA
NA
0.92
NA
1.84
NA
0.97
NA
NA
DIOXIN / FURAN DETECTION LIMITS, pg/g
123478 123678 123789 1234678 2378 12378
HXCDO
2.46
NA
2.47
2.45
NA
2.45
2.47
2.46
2.46
2.46
2.45
2.44
1.09
2.47
2.47
2.46
2.46
2.46
2.46
NA
2.45
NA
2.46
2.47
2.47
NA
2.47
NA
2.47
NA
1.87
2.46
NA
2.47
1.15
NA
NA
2.47
2.47
4.93
NA
2.46
NA
3.85
HXCDD
2.13
NA
1.84
NA
NA
1.84
NA
1.84
2.12
2.35
NA
NA
NA
NA
1.84
2.50
1.84
1.84
1.84
NA
1.83
NA
1.84
NA
1.85
NA
NA
NA
1.85
NA
NA
1.84
NA
1.85
0.64
NA
NA
1.85
5.95
NA
NA
1.84
NA
NA
HXCDD
1.37
NA
1.38
1.37
NA
1.37
NA
1.37
NA
1.37
1.37
NA
NA
NA
1.38
NA
1.37
1.38
1.37
NA
1.37
NA
1.37
NA
1.38
NA
1.38
1.53
1.38
NA
NA
1.38
NA
1.38
1.33
NA
NA
1.38
NA
2.75
NA
1.38
NA
NA
HPCDD
NA
NA
1.26
NA
NA
1.45
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.28
NA
1.40
NA
NA
NA
1.40
NA
NA
1.49
NA
1.48
1.30
NA
NA
NA
NA
NA
NA
1.48
NA
NA
TCDF
NA
NA
0.57
NA
NA
0.52
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.62
0.58
NA
NA
NA
0.53
NA
0.66
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.92
NA
NA
NA
0.53
NA
NA
PECDF
0.77
0.77
0.78
0.77
0.77
0.77
NA
NA
NA
0.77
NA
0.77
NA
0.77
0.78
0.87
0.77
0.77
0.77
0.80
0.77
0.77
0.77
1.33
0.78
1.47
NA
NA
0.78
NA
0.44
NA
0.81
0.78
0.42
0.41
NA
0.78
NA
1.55
NA
0.77
NA
1.17
23478
PECDF
NA
NA
0.85
NA
2.40
0.84
NA
0.84
0.85
0.90
NA
0.88
NA
0.85
0.95
1.42
0.84
0.85
0.85
NA
0.84
NA
0.84
NA
0.85
NA
NA
NA
0.85
NA
NA
NA
NA
NA
0.36
NA
NA
0.85
NA
1.69
2.79
0.85
NA
NA
123478
HXCDF*
2.82
2.82
2.83
2.82
2.82
2.82
NA
2.82
NA
2.83
NA
2.80
NA
2.83
2.83
2.82
2.82
2.83
2.83
2.86
2.81
2.82
2.82
2.91
2.84
NA
2.83
NA
2.84
2.84
0.94
2.83
2.81
2.84
0.88
0.84
NA
2.84
NA
5.66
NA
2.83
NA
NA
123678
HXCDF
2.83
2.83
2.85
2.83
2.83
2.83
NA
2.84
2.84
2.84
NA
2.81
NA
2.84
2.85
2.83
2.83
2.84
2.84
2.85
2.82
2.84
2.83
2.85
2.85
NA
2.85
NA
2.85
2.86
1.19
2.84
2.83
2.85
1.10
1.10
2.84
2.85
NA
5.69
3.48
2.84
NA
2.85
123789 234678 1234678 1234789
HXCOF HXCDF
2.76 1.95
2.76 1.95
2.77 1.96
2.76 1.95
2.76 1.95
2.76 1.95
2.78 NA
2.76 1.95
2.77 NA
2.77 1.95
2.76 NA
2.74
0.97
2.77
2.77
2.76
2.76
2.77
2.77
2.78
2.75
2.76
2.76
2.78
2.78
2.76
2.77
2.76
2.78
2.78
1.07
2.77
2.76
2.78
0.99
O.B7
2.77
2.78
.94
.65
.96
.96
.95
.95
.96
.96
.97
.95
.95
.95
.96
.96
NA
.96
.95
.96
NA
.04
.96
.95
.96
1.91
1.86
.96
.96
2.77 NA
5.55 3.92
2.78 NA
2.77 1.96
0.87 NA
2.78 1.96
HPCDF
1.44
1.44
1.45
1.44
1.44
1.44
NA
1.44
1.44
1.44
1.59
1.43
NA
NA
1.45
1.44
1.44
1.44
1.44
NA
1.44
NA
1.44
NA
1.45
NA
1.45
NA
1.45
NA
0.66
1.44
1.44
1.45
0.67
0.65
NA
1.45
NA
2.89
NA
1.44
NA
NA
HPCDF
2.61
2.60
2.62
2.60
2.60
2.60
2.62
2.61
2.61
2.61
2.60
2.59
1.88
2.61
2.62
2.61
2.61
2.61
2.61
2.62
2.60
2.61
2.61
2.62
2.62
2.60
2.62
2.60
2.62
2.62
1.66
2.61
2.60
2.62
1.87
1.80
2.61
2.62
2.62
5.23
2.62
2.61
3.01
2.62
-------
OIOXIN / FURAN DETECTION LIMITS, pg/g
Episode SCC Type Description
3345 DD016112 F PF Lm Bass
3345 SD016111 F UB Redhorse Sucker
3346 DD016113 F UB Creek Chubsucker
3346 DD016114 F PF Lm Bass
3346 ODOA2088 L UB Creek Chubsucker
3346 SD016113 F UB Creek Chubsucker
3346 SD016114 F PF Lm Bass
3347 DD01611S F UB Carp
3347 DD016116 F PF Lm Bass
3347 SD016115 F UB Carp
3348 DD016117 F PF White Perch
3348 DD016118 F UB Blue Catfish
3348 QD072888 F UB Blue Catfish
3348 SD016117 F PF White Perch
3348 SD016118 F UB Blue Catfish
3349 00016119 F UB Carp
3349 00016120 F PF Lm Bass
3350 OD016121 F UB Carp
3350 DD016122 F PF Lm Bass
3350 GD052688 F UB Carp
3351 00016123 F PF Rock Bass
3351 DD016124 F WB Carp
3351 OD021888 L UB Carp
3352 DF023723 F PF Crappie
3352 DF023724 F UB Carp
3352 QD091388 F UB Carp
3353 DF024121 F BF Blue Catfish
3353 DF024122 F UB Sm Buffalo
3353 QD024121 L BF Blue Catfish
3354 DY022301 UB Carp
3354 DY022302 PF Lm Bass
3355 DY022303 UB Carp
3355 DY022304 PF Lm Bass
3355 SY022303 UB Carp
3356 DE030201 UB Carp
3356 SE030201 UB Carp
3357 DY022223 PF Squaufish
3357 DY022224 UB Sacramento Sucker
3360 00029117 UB Carp
3360 DD029118 PF Lm Bass
3360 QD022389 UB Carp
3375 DDO 16305 UB Carp
3375 DD016306 PF Lm Bass
3375 00101188 L UB Carp
2378
TCDD
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.00
NA
NA
NA
NA
NA
NA
1.11
NA
1.49
NA
NA
NA
NA
NA
NA
1.13
2.36
NA
NA
NA
12378
PECDD
NA
NA
NA
0.98
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.95
NA
0.91
NA
0.92
NA
NA
0.91
NA
NA
NA
NA
NA
NA
NA
NA
1.80
NA
NA
NA
NA
NA
NA
1.14
NA
NA
1.19
NA
123478
HXCDD
2.46
NA
2.47
2.46
2.46
NA
0.90
NA
2.46
NA
2.47
NA
NA
1.12
NA
NA
2.47
NA
2.45
NA
2.46
NA
NA
2.45
NA
NA
2.46
NA
2.47
NA
2.47
NA
2.46
NA
NA
NA
2.46
2.45
2.47
2.46
2.46
NA
2.46
NA
123678
HXCDD
NA
NA
1.85
1.84
1.84
NA
0.69
8.97
NA
NA
NA
NA
NA
0.66
NA
NA
1.84
NA
1.83
NA
1.84
NA
NA
1.83
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.84
NA
NA
NA
NA
123789 1234678
HXCDD
1.37
NA
1.38
1.37
1.37
NA
1.15
NA
1.37
NA
1.38
NA
NA
1.32
1.51
NA
1.38
NA
1.37
NA
1.38
NA
1.36
1.37
NA
NA
NA
NA
NA
NA
1.38
NA
1.37
NA
NA
NA
.37
.37
.38
.38
.38
NA
1.37
NA
HPCDD
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.68
NA
1.26
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.46
NA
NA
1.26
NA
NA
NA
NA
2378
TCDF
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.77
NA
0.63
NA
NA
0.58
NA
NA
NA
NA
NA
NA
0.57
NA
0.62
NA
NA
NA
NA
NA
NA
1.10
NA
NA
NA
NA
12378
PECDF
0.77
0.92
NA
0.77
NA
NA
NA
NA
0.77
NA
NA
NA
NA
NA
NA
NA
0.77
NA
0.77
NA
0.77
NA
NA
0.77
0.78
0.77
0.77
NA
0.78
NA
0.77
NA
0.77
NA
NA
NA
0.77
NA
0.78
0.81
0.77
NA
0.81
NA
23478
PECDF
0.85
NA
NA
NA
NA
NA
NA
2.68
0.85
NA
NA
NA
NA
NA
NA
NA
0.85
NA
0.84
NA
0.85
NA
NA
0.84
0.85
0.91
NA
NA
1.09
NA
0.85
NA
1.20
NA
NA
NA
NA
NA
NA
0.87
NA
NA
NA
NA
123478
HXCDF*
2.83
0.76
2.84
2.83
2.83
0.77
0.76
NA
2.83
NA
2.84
2.84
NA
0.94
1.05
2.84
2.83
NA
2.82
NA
2.83
NA
NA
2.81
2.84
2.82
2.82
2.83
2.84
NA
2.83
NA
2.83
NA
NA
NA
2.83
2.82
2.83
2.83
2.83
NA
2.82
NA
123678
HXCDF
2.84
1.25
2.85
2.84
2.84
1.28
1.25
3.08
2.84
NA
2.85
2.84
2.85
1.19
1.11
2.85
2.84
NA
2.83
NA
2.84
NA
NA
2.82
2.85
2.83
2.83
2.84
2.85
NA
2.84
NA
2.84
NA
NA
NA
2.84
2.83
2.85
2.84
2.84
NA
2.84
NA
123789
HXCDF
2.77
0.88
2.78
2.77
2.77
0.94
0.87
2.77
2.77
0.99
2.78
2.77
2.78
1.07
0.99
2.78
2.77
2.77
2.76
2.78
2.77
2.76
2.74
2.75
2.78
2.76
2.76
2.77
2.78
2.77
2.77
2.77
2.77
0.20
2.77
0.96
2.77
2.76
2.77
2.77
2.77
2.77
2.76
2.76
234678 1234678 1234789
HXCDF
1.96
0.83
1.96
1.96
1.96
0.88
0.83
NA
1.96
0.91
1.96
1.96
1.96
1.04
0.91
1.96
1.96
NA
1.95
NA
1.96
NA
NA
1.94
.96
.95
.95
.96
.96
2.17
1.96
NA
1.96
NA
NA
NA
1.96
1.95
1.96
1.96
1.96
NA
1.95
NA
HPCDF
1.44
0.81
1.45
1.44
1.44
0.81
0.81
NA
NA
NA
1.45
1.45
1.45
0.66
0.68
1.45
1.45
NA
1.44
NA
1.45
NA
NA
.43
.45
.44
.44
.44
.45
NA
1.45
NA
1.44
NA
NA
NA
1.44
1.44
1.45
1.44
1.45
NA
1.44
NA
HPCDF
2.61
3.01
2.62
2.61
2.61
3.01
3.01
2.61
2.61
1.81
2.62
2.61
2.62
1.66
1.81
2.62
2.61
2.61
2.60
2.62
2.61
2.60
2.59
2.59
2.62
2.61
2.60
2.61
2.62
2.62
2.61
NA
2.61
NA
2.61
1.87
2.61
2.60
2.62
2.61
2.61
NA
2.61
NA
-------
Episode SCC Type Description
D10XIN / FURAN DETECTION LIMITS, pg/g
3376 DD016307
3376 DD016308
3376 00050389
3377 DDO16309
3377 DD016310
3377 SD016309
3378 DD016311
3378 DD016312
3378 DD029115
3378 00029116
3385 DD016401
3395 DD016421
3395 DD016422
3395 SD016421
3401 DD016S09
3401 DD016510
3403 00016513
3403 00016514
3404 OD016515
3404 00016516
3404 SD016515
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907
3412 SB040907
3414 DC036203
3414 DC036204
3415 DC036205
3415 DC036206
3416 DF025210
3416 DF025211
3416 DF025212
3418 DF025007
3419 DC036207
3419 DC036208
3420 DC036209
3420 DC036210
3421 DC036211
3421 DC036212
3421 SC036212
3422 DC036213
3422 DC036214
UB Carp
PF Lm Bass
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
UB Spotted Sucker
PF Lm Bass
UB Greyfin Sucker
BF Channel Catfish
UB Redhorse Sucker
UB Redhorse Sucker
PF Lin Bass
UB Redhorse Sucker
UB Carp
PF Lm Bass
UB River Carpsucker
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
UB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
PF Channel Catfish
BF Carp
PF Lm Bass
PF Blue Catfish
UB White Sucker
PF Freshwater Drum
PF Greenfish
UB Carp
PF White Perch
UB Carp
UB Carp
PF Lm Bass
UB Yellow Bullhead
2378
TCDD
NA
1.21
1.19
NA
1.24
NA
NA
1.00
NA
1.02
NA
NA
NA
NA
NA
1.12
NA
NA
NA
NA
NA
NA
1.09
NA
NA
NA
NA
1.11
NA
1.04
NA
NA
NA
1.54
NA
1.16
0.99
NA
NA
NA
NA
NA
NA
NA
12378
PECDD
NA
1.13
1.29
NA
0.95
NA
1.24
1.06
NA
1.18
1.26
NA
1.25
NA
NA
0.94
NA
1.10
NA
1.17
NA
NA
0.97
NA
1.00
NA
NA
0.92
1.22
0.92
NA
1.17
1.37
1.09
1.01
1.19
0.91
NA
NA
0.92
NA
NA
0.94
0.91
123478
HXCOD
NA
2.76
2.83
NA
2.46
NA
2.62
2.47
NA
2.47
2.46
3.33
2.46
1.59
NA
2.46
NA
2.45
NA
2.46
NA
NA
2.46
2.46
2.45
NA
NA
2.46
2.47
2.46
NA
2.46
2.47
2.46
2.46
2.47
2.45
2.46
2.95
2.46
2.47
NA
2.47
2.45
123678
HXCDO
NA
2.07
2.12
NA
1.88
NA
2.02
1.85
NA
1.84
NA
NA
1.84
NA
NA
NA
NA
1.83
NA
1.85
NA
NA
1.84
NA
1.83
NA
NA
1.84
NA
1.84
NA
1.84
1.84
1.84
1.84
1.84
1.83
NA
NA
1.84
NA
NA
1.85
1.83
123789 1234678
HXCDD
NA
1.58
1.62
NA
1.38
NA
1.37
1.38
1.38
1.38
1.37
NA
1.38
1.39
NA
1.37
NA
1.37
NA
1.37
NA
NA
1.38
1.38
1.37
NA
NA
1.37
1.38
1.38
1.37
1.37
1.38
1.37
1.38
1.38
1.37
1.37
NA
1.37
NA
NA
1.38
1.37
HPCDD
NA
NA
1.49
NA
2.27
NA
NA
1.32
NA
1.65
NA
NA
NA
NA
NA
1.35
NA
1.42
NA
NA
NA
NA
NA
NA
1.31
NA
NA
1.26
NA
1.39
NA
NA
NA
1.32
1.52
1.55
1.25
NA
NA
1.56
NA
NA
1.71
NA
2378
TCDF
NA
0.64
0.64
NA
NA
NA
NA
0.53
NA
0.56
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.54
NA
0.49
NA
NA
NA
NA
NA
NA
0.48
NA
NA
NA
NA
NA
NA
NA
12378
PECOF
NA
0.78
0.78
NA
0.77
NA
0.91
0.78
0.94
0.80
0.77
NA
0.78
NA
NA
0.77
NA
0.77
NA
0.77
NA
NA
0.77
0.94
0.77
NA
NA
0.77
0.78
0.77
NA
0.82
0.77
0.77
0.77
0.91
0.77
NA
NA
0.77
NA
NA
0.78
0.77
23478
PECOF
NA
0.85
0.85
NA
0.85
NA
NA
0.85
NA
0.86
NA
NA
1.16
NA
NA
0.85
NA
1.04
NA
0.85
NA
NA
0.85
NA
1.18
NA
NA
NA
NA
0.85
NA
0.94
1.24
0.85
1.12
1.61
0.84
NA
NA
0.86
7.11
NA
0.85
0.87
123478
HXCDF*
NA
2.84
2.84
NA
2.83
NA
2.83
2.84
2.84
2.83
2.82
2.84
2.83
0.94
2.81
2.83
NA
2.82
2.82
2.83
0.94
NA
2.83
NA
2.82
NA
NA
2.82
2.83
2.83
2.83
2.82
2.83
2.83
2.83
2.83
2.82
2.83
2.83
2.83
NA
NA
2.84
2.82
123678
HXCDF
NA
2.85
2.85
NA
2.84
NA
2.84
2.85
2.85
2.85
2.83
NA
2.84
1.19
2.83
2.84
NA
2.83
2.91
2.84
1.18
NA
2.84
2.84
2.83
NA
NA
2.83
2.85
2.84
2.84
2.83
2.84
2.84
2.84
2.85
2.83
2.84
2.85
2.84
2.85
1.04
2.85
2.83
123789
HXCDF
2.76
2.78
2.78
2.77
2.77
1.40
2.77
2.78
2.78
2.77
2.76
2.78
2.77
1.07
2.76
2.77
2.76
2.76
2.76
2.77
1.06
2.77
2.77
2.77
2.76
2.77
1.07
2.76
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.77
2.76
2.77
2.77
2.77
2.78
0.89
2.78
2.76
234678 1234678 1234789
HXCDF HPCDF
NA NA
1.96 1.45
1.96 1.45
NA NA
1.96 1.44
NA NA
.95 1.44
.96 1 .45
.96 1 .45
.96 1 .45
.95 1.44
.96 1.54
.96 1 .45
.04 NA
1 .95 NA
1 .95 1 .44
NA NA
1 .95 1 .44
1.95 NA
1 .96 1 .44
1.03 NA
NA NA
1.96 1.45
1.96 NA
1.95 1.44
NA NA
1.40 NA
1.95
1.96
1.96
1.95
1.95
1.96
1.96
1.96
1.96
1.95
1.95
1.96
1.96
1.96
0.87 <
1.96
1.95
.44
.45
.44
.44
.44
.45
.44
.45
.45
.44
NA
.45
.44
.45
).66
.45
.44
HPCDF
NA
2.62
2.62
NA
2.61
0.93
2.61
2.62
2.62
2.62
2.60
2.62
2.61
1.66
2.60
2.61
NA
2.60
2.60
2.61
1.65
2.61
2.61
2.61
2.60
2.61
1.66
2.61
2.62
2.61
2.61
2.61
2.61
2.61
2.61
2.62
2.60
2.61
2.62
2.61
2.62
1.66
2.62
2.60
-------
Episode SCC Type Description
3423 DC036215 F
3423 DC036216 F
3424 DC036217 F
3424 DC036218 F
3425 DF025005 F
3425 DF025012 F
3425 0)031389 L
3426 DB069102 F
3427 DB069103
3428 DB069104
3429 DB069105
3430 DB069106
3431 DB069109
3432 DB069111
3433 DB069112
3433 00021689
3434 DB040801
3435 DD016601
3435 DD016602
3437 DJ022302 M
3438 DJ022303 M
3439 DJ022304 F
3439 QD062289 L
3440 DJ022305 F
3441 DJ022306
3442 DF024301
3442 QD081089
3444 DD016603
3444 DD016604
3444 DD029512
3444 QD091289
3445 DD029513
3445 DD029514
3446 DD016605
3446 DD016606
3446 DD029511
3446 00092089
3450 DY022308
3450 DY022309
3451 DY022310
3451 DY022314
3452 DF025218
3452 DF025219
3452 DF025220
PF White Perch
UB White Catfish
PF Shortnose Gar
WB White Catfish
WB Carp
BF Channel Catfish
BF Channel Catfish
PF Bluefish
PF Bluefish
PF Bluefish
PF Weakfish
UB White Catfish
WB Red Snapper
BF Red Snapper
WP Flounder
WP Flounder
WP Flounder
PF White Bass
WB Bigmouth Buffalo
WB Crayfish
Dungeness Crab
WB White Sturgeon
WB White Sturgeon
WB White Sturgeon
WB White Sturgeon
PF Channel Catfish
PF Channel Catfish
WB Carp
PF Channel Catfish
PF Lm Bass
WB Carp
WB Flounder
WB Hardhead Catfish
PF Striped Bass
UB Carpsucker
UB Carp
UB Carp
PF White Croaker
PF White Croaker
PF White Croaker
PF White Croaker
UB Sm Buffalo
PF Blue Catfish
PF Flathead Catfish
DIOXIN /
2378
TCDD
NA
HA
NA
NA
NA
NA
NA
NA
NA
1.06
0.99
NA
1.22
0.99
NA
NA
NA
1.72
NA
1.11
NA
2.07
NA
NA
1.75
0.99
0.99
NA
NA
1.44
NA
1.05
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12378
PECOD
1.07
NA
0.92
NA
NA
NA
NA
0.95
0.94
1.01
1.00
1.01
NA
1.01
NA
1.62
NA
1.08
NA
0.99
1.22
0.94
1.06
1.12
0.92
0.96
0.92
NA
NA
1.20
NA
1.16
NA
1.07
0.92
1.20
1.28
1.28
1.64
1.74
1.48
1.10
NA
1.16
123478
HXCDD
2.47
2.45
2.46
2.56
NA
2.46
2.46
2.47
2.47
2.46
2.46
2.47
2.57
2.46
2.46
2.46
2.46
2.47
3.04
2.45
2.45
2.47
2.47
2.46
2.48
2.47
2.45
NA
NA
2.73
NA
2.46
3.18
2.45
2.46
2.46
2.46
2.47
2.46
2.47
2.47
2.46
2.71
2.47
123678
HXCDD
1.84
NA
NA
1.83
NA
NA
2.41
.85
.84
.84
.84
NA
.85
.84
NA
NA
NA
1.85
NA
1.84
NA
1.84
1.85
1.84
1.85
1.85
1.84
NA
NA
2.05
NA
1.95
NA
1.83
1.84
NA
NA
1.84
1.84
1.85
1.85
1.84
2.03
1.84
FURAN DETECTION LIMITS, pg/g
123789
HXCDD
1.38
NA
1.37
NA
NA
NA
NA
1.38
1.38
1.37
1.37
1.38
1.38
1.37
1.37
1.37
1.37
1.38
NA
1.37
1.37
1.38
1.38
1.37
1.38
1.38
1.37
NA
NA
1.56
NA
1.37
NA
1.37
1.37
1.38
1.37
1.38
1.37
1.38
1.38
1.38
1.54
1.38
1234678 2378 12378 23478 123478 123678 123789 234678 1234678 1234789
HPCDD TCDF PECDF PECDF HXCDF* HXCDF HXCDF HXCDF HPCDF HPCDF
NA NA 0.77 0.87 2.83 2.84 2.77 .96 1.45 2.61
NA NA NA NA 2.82 2.83 2.76 .95 1.44 2.60
NA NA 0.77 1.19 2.82 2.84 2.76 .95 1.44 2.61
NA NA 0.85 NA 2.82 2.83 2.76 .95 1.44 2.60
NA NA NA NA 2.89 NA 2.77 .97 NA 2.62
NA NA 0.87 NA 2.82 2.83 2.76 .95 .44 2.61
NA NA 0.85 NA 2.83 2.84 2.77 .96 .45 2.61
.26 NA 0.78 NA 2.84 2.85 2.78 .96 .45 2.62
.26 NA NA NA 2.83 2.85 2.77 .96 .45 2.62
.26 NA 0.87 NA 2.83 2.84 2.77 .95 .44 2.61
.26 0.49 0.77 0.85 2.83 2.84 2.77 .96 .44 2.61
NA NA NA NA 2.84 2.85 2.78 .96 .45 2.62
.26 NA NA NA 2.84 2.85 2.78 .96 .45 2.62
.26 0.49 0.77 0.85 2.83 2.84 2.77 .95 .44 2.61
NA NA 0.97 NA 2.83 2.84 2.77 .96 .44 2.61
NA NA 1.03 NA 2.83 2.84 2.77 .96 .44 2.61
NA NA 1.14 NA 2.83 2.84 2.77 .96 .44 2.61
1.34 NA 0.80 0.87 2.84 2.85 2.77 .96 .45 2.62
NA NA NA NA NA 2.84 2.77 .96 NA 2.61
NA NA 0.77 0.84 2.82 2.83 2.76 .95 .44 2.60
3.95 NA 0.91 NA 2.81 2.83 2.76 1.95 .54 2.60
NA NA 1.03 0.91 2.83 2.85 2.77 1.96 .45 2.62
NA NA NA 0.94 2.84 2.85 2.78 1.96 .45 2.62
1.51 NA 1.07 0.93 2.83 2.84 2.77 1.96 .44 2.61
NA NA 1.09 0.91 2.83 2.85 2.77 1.96 .45 2.62
1.33 0.49 0.78 0.85 2.84 2.85 2.78 1.96 .45 2.62
1.25 0.48 0.77 0.84 2.82 2.83 2.76 1.95 .44 2.60
NA NA NA NA NA NA 2.77 NA NA 3.02
NA 0.59 0.82 NA 2.84 2.85 2.78 NA NA 2.62
1.64 0.75 0.87 0.91 2.84 2.85 2.78 1.96 .56 2.78
NA NA NA NA NA NA 2.76 NA NA 2.97
NA 0.58 0.78 0.87 2.83 2.84 2.77 1.96 .44 2.61
NA 0.64 0.78 1.19 2.84 2.85 2.78 1.96 .45 2.62
1.65 NA 1.28 NA 2.96 2.83 2.76 1.95 .44 2.60
1.59 NA 1.05 1.65 2.82 2.84 2.76 1.95 .44 2.61
NA NA 1.32 NA NA 2.94 2.77 1.96 .70 2.61
NA NA 1.39 NA NA 2.84 2.77 1.95 .67 2.61
1.35 0.49 0.77 0.93 2.83 2.84 2.77 1.96 .45 2.61
1.26 0.49 0.77 0.97 2.82 2.83 2.76 1.95 .44 2.61
1.26 0.57 0.93 0.96 2.84 2.85 2.78 1.96 .45 2.62
1.26 0.55 1.02 1.02 2.84 2.85 2.78 1.96 .45 2.62
1.39 NA 0.93 0.96 2.83 2.84 2.77 1.96 .44 2.61
1.99 NA 0.80 1.78 2.82 2.83 2.76 1.95 .49 2.68
1.26 0.54 0.80 0.86 2.83 2.84 2.77 1.96 .45 2.61
-------
Episode SCC Type Description
DIOXIN / FURAN DETECTION LIMITS, pg/g
2378 12378 123478 123678 123789 1234678 2378 12378 23478 123478 123678 123789
TCDD PECDD HXCDD HXCDD HXCDD HPCDD TCDF PECDF PECDF HXCDF* HXCDF HXCDF
234678 1234678 1234789
HXCDF HPCDF HPCDF
3452 QD103189 F UB Sra Buffalo
NA
1.10 2.47 1.84 1.38
1.29
NA 0.80
0.87
2.83 2.84
2.77
1.96
1.45 2.61
-------
APPENDIX D-5
Xenobiotic Data by Episode Number
-------
Key for Xenobiotic Data Table (Units = ng/g)
Setl
Merc
123 TCB
124 TCB
135 TCB
1234 TCB
1235 TCB
1245 TCB
ocs
PC
PCNB
HCB
aBHC
gBHC
cis CHLOR
trans CHLOR
Mercury, g
1,2,3 Trichlorobenzene
1,2,4 Trichlorobenzene
1,3,5 Trichlorobenzene
1,2,3,4 Tetrachlorobenzene
1,2,3,5 Tetrachlorobenzene
1,2,4,5 Tetrachlorobenzene
Octachlorostyrene
Pentachlorobenzene
Pentachloronitrobenzene
Hexachlorobenzene
alpha BHC
gamma BHC (lindane)
cis Chlordane
trans Chlordane
CAS Number
7439/97/6
87/61/6
120/82/1
108/70/3
634/66/2
634/90/2
95/94/3
29082/74/4
608/93/5
82/68/8
118/74/1
319/84/6
58/89/9
51
5103/74/2
DATA FLAGS
D = Value below limit of quantitation
For all Xenobiotics except Mercury and PCBs,
D = 2.5 ng/g
For Polychlorinated Biphenyls
Number of Chlorines D, na/g
1-3 1.25
4-6 2.50
7-8 3.75
9-1 6.25
Detection limit for Mercury was 0.05 g/g, except for 1990 samples which had a detection
limit of 0.0013 g/g.
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate
samples (those starting with a Q) and confirmation samples (those starting with an S). The
number of samples shown on the summary tables in Volume I do not included the duplicate
and confirmation samples.
D-5-1
-------
D-5-2
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
1994 DEO 17703
1994 OE017702
1998 13421
1998 13285
2015 DF001002
2015 DF001001
2016 DF001102
2016 DF001101
2017 DF001202
2017 DF001201
2018 DF001301
2023 DF001402
2023 DF001403
2026 DF001706
2026 DF001702
2027 DF001802
2027 DF001803
2037 DY000502
2037 DV000501
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000901
2070 DJ000902
2098 DH001504
2098 DH001501
2100 DH001702
2100 DH001703
2105 DH002201
2105 DH002204
2109 DH002602
2109 DH002601
2110 DH002710
2122 DH003901
2122 DH003904
2126 DD000303
2126 DD000302
2133 DD001002
2138 DD001504
2138 DD001501
2139 OD001604
2139 DD001601
2142 DD001903
2142 DD001902
V-
U)
PF Walleye
UB Carp
PF Northern Pike
UB Carp
UP Crappie
UB Carp
BF Sucker
UB Sucker
BF Carp
UB Carp
UB Sucker
PF Spotted Bass
UB Carp
UB Flathead Catfish
UB Carp
PF Lm Bass
UB Carp
UP not available
UB not available
UB Carp
UB Carp
UB Carp
UB Carp
UP Rainbow Trout
UB Longnose Sucker
PF not available
UB not available
PF Sauger
UB Catfish
PF Sauger
UB Carp
BF not available
UB not available
UP Brown Trout
PF Rainbow Trout
UB White Sucker
PF White Crappie
UB Carp
BF Blue Catfish
PF Lm Bass
UB Redhorse Sucker
PF Rainbow Trout
UB Carp
PF Lm Bass
UB Catfish
Merc
P9/9
0.12
0.11
0.28
0.08
0.17
0.14
0.31
0.18
0.15
0.11
0.07
0.24
0.16
0.14
0.16
1.63
0.21
0.09
0.10
0.06
0.12
O.U
0.09
ND
ND
ND
ND
0.3S
0.32
0.45
ND
0.12
ND
ND
0.11
0.12
0.71
0.14
0.37
0.88
0.437
ND
0.08
0.348
0.10
123
TCB
1.40
ND
ND
0.19
ND
ND
NO
ND
69.0
ND
ND
ND
ND
0.45
ND
ND
ND
0.60
1.02
0.15
0.28
ND
ND
124
TCB
D 1.35
ND
ND
D 0.29
ND
ND
ND
ND
191
ND
ND
ND
ND
D 0.64
ND
ND
ND
D 0.35
D 0.60
D 0.35
D ND
ND
ND
135
TCB
D ND
ND
ND
D ND
ND
ND
ND
ND
E 2.77
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
D ND
D ND
ND
ND
ND
1234
TCB
ND
ND
ND
0.09
ND
ND
ND
ND
11.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
D ND
ND
ND
ND
ND
15.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
15.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OCS
ND
ND
ND
ND
ND
ND
ND
ND
3.72
ND
20.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
4.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
aBHC
gBHC CIS
CHLOR
TRANS
CNLOR
4.07
ND
2.52
ND
ND
0.66
ND
ND
19.7
ND
4.56
2.18
ND
ND
2.52
ND
ND
ND
ND
ND
ND
ND
ND
3.58
ND
4.10
ND
ND
D ND
1.26
ND
18.6
7.84
9.80
D 3.63
ND
6.42
6.58
1.55
ND
ND
3.98
ND
1.39
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
15.3
ND
5.26
ND
ND
ND
D ND
ND
ND
ND
ND
D 1.64
ND
ND
46.4
7.67
5.17
3.30
ND
13.2
3.04
ND
148
60.2
68.2
74.9
ND
ND
26.0
ND
14.3
ND
ND
D 4.06
43.6
ND
3.50
ND
5.20
8.23
1.96 D
ND
E 111
38.9
38.0
55.5
ND
ND
22.7
ND
16.5
ND
2.43 D ND
2.73
3.46
ND ND
45.5 22.2
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
2148
2148
2151
2151
2152
2152
2190
2190
2191
2191
2194
2194
2199
2199
2201
2201
2205
2205
2210
2211
2212
2212
2215
2216
2216
2220
2220
2225
2225
2227
2227
2228
2228
2231
2246
2246
2247
2247
2280
2280
2280
2283
2283
2290
2290
D0002504
D0002501
00002801
DD002803
DD002902
DD002903
OGOOS101
DGOOS104
DG005206
OGOOS205
DG005504
DG005501
DG006001
DG006004
DG006204
DG006201
DG006602
DG006601
DC005401
DC005503
DC005602
DC005605
DC005902
DC006002
DC006003
DC006401
DC006405
DC006903
DC006902
DC007102
DC007104
DC007204
DC007201
DC007503
DJ002301
DJ002302
DJ002403
DJ002404
OF005204
DFOOS201
QD121688
DFOOS502
DF005501
DD003402
PF
UB
PF
UB
PF
UB
UB
PF
BF
UB
PF
UB
UB
PF
PF
UB
BF
UB
UB
UB
PF
UB
UB
PF
UB
PF
UB
UB
PF
PF
UB
PF
PF
UB
BF
UB
PF
UP
PF
UB
UB
UP
UB
PF
D0003403 f UB
Saltwater Catfish
Saltwater Catfish
Lra Bass
Spotted Sucker
Ln Bass
Lake Chubsucker
Carp
Bluegill
Carp
Carp
Channel Catfish
Carp
Carp
Ln Bass
Bowf in
Carp
Carp
Carp
Catfish
Redhorse Sucker
Sm Bass
Uhite Sucker
Carp
Brown Trout
Uhite Sucker
Redbreast Sunfish
Catfish
Shorthead Redhorse
Sm Bass
Lra Bass
Channel Catfish
Redhorse Sucker
Longear Sunfish
Gizzard Shad
Bridgelip Sucker
Bridgelip Sucker
Bridgelip Sucker
Mountain Uhitefish
Channel Catfish
Carp
Carp
Longear Sunfish
Gray Redhorse
Lm Bass
Spotted Sucker
Merc
P9/9
0.28
0.12
0.81
0.07
0.98
0.13
NO
0.85
0.05
ND
0.24
0.10
ND
0.27
0.58
0.12
0.16
0.07
0.08
0.151
0.24
0.06
ND
0.14
0.08
0.07
ND
0.125
0.23
0.614
0.138
0.08
0.16
ND
0.52
0.20
0.19
0.10
0.29
0.17
0.13
0.15
1.13
0.21
123
TCB
ND
1.35
2.60
ND
0.92
ND
ND
ND
0.35
ND
0.28
ND
0.33
0.71
ND
ND
ND
ND
ND
ND
ND
ND
0.38
ND
ND
ND
17.7
124
TCB
ND
0 1.01
1.97
ND
D 0.67
ND
0.76
ND
D 0.26
0.35
D 0.45
4.60
D 0.64
D 0.59
ND
ND
0.15
0.46
0.82
ND
ND
ND
D ND
ND
ND
ND
104
135
TCB
ND
D ND
D ND
ND
D ND
ND
D ND
ND
0 ND
D ND
D ND
ND
D ND
D ND
ND
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
9.20
1234
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
12.0
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
12.0
OC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCNB
ND
ND
ND ND
ND ND
ND ND
ND
2.43 D ND
ND ND
ND ND
ND
ND ND
1.88 D ND
ND ND
ND ND
0.32 D ND
1.93 D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
ND
ND
0.51
ND
2.15
11.6
ND
ND
ND
ND
5.07
ND
ND
2.72
ND
ND
ND
aBHC
ND
ND
ND
D 1.09
ND
D 10.2
1.89
ND
NO
ND
0.93
6.55
2.33
ND
ND
ND
ND
0.78
gBHC
ND
ND
ND
D 1.68
ND
ND
D 11.9
ND
ND
ND
D ND
ND
D 2.70
1.36
7.18
13.6
ND
D ND
CIS
CHLOR
4.90
ND
ND
D 69.7
ND
76.2
77.5
34.5
19.9
3.99
ND
166
7.14
D 6.05
112
378
ND
4.57
TRANS
CHLOR
3.97
ND
ND
E 182
ND
107
72.9
34.6
11.0
ND
ND
E 126
3.94
2.27
E 64.3
E 310
ND
2.40
E
D
E
D
ND
ND
3.12
ND
ND
ND
ND
ND
ND
0.83 D ND
ND
15.7
ND
7.75
ND
ND
ND
ND
ND
8.78
ND
ND
ND
ND
ND
128
3.07
3.51
ND
ND
87.7
ND
9.70
2.46 D 1.17 D
1.28 D 2.41 D 1.20 D
ND ND ND
ND 41.8 39.8
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
2294 00003801 F PF Lm Bass
2294 00003804
2297 DD004103
2297 00004102
2298 DD004201
2298 DD004203
2301 00004502
2301 00004503
2301 00004501
2301 DD004504
2302 DD004601
2304 DD004804
2304 00004801
2309 DD005304
2309 00005301
2322 DB001304
2322 DB001301
2326 DB001704
2326 DB001701
2328 DB001904
2329 DB002004
2341 DD006002
2341 DD006003
2355 DA001603
2356 DA001703
2356 DA001702
2369 DA003202
2375 DA003802
2375 DA003803
2376 DA003903
2379 DE005401
2379 DE005404
2380 DE005501
2383 DE005801
2385 DE006002
2387 DE006201
2387 DE006204
2394 DE006901
2394 OD006901
2394 00022189
2397 DE007204
2397 DE007201
2410 OE008501
2410 OE008504
2416 OE009101
UB Carp
PF Lm Bass
UB Carp
UB Channel Catfish
UP Lm Bass
UB Stn Bass
UB Bluegill
UP Black Crappie
UP Rock Bass
UB Quillback Carpsucker
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB White Sucker
PF Rock Bass
UB White Sucker
PF Chinook Salmon
PF Broun Trout
PF Lm Bass
UB Carpsucker
UB White Sucker
UB White Sucker
PF Lm Bass
PF Lm Bass
PF Pickeral
UB White Sucker
UB White Sucker
UB Carp
PF Lm Bass
UB Carp
UB Carp
UB Uhite Sucker
UB Carp
PF Walleye
UB Carp
UB Carp
UB Carp
PF Walleye
UB Sucker
UB Carp
PF Sm Bass
UB Carp
Here
M9/9
0.592
0.068
0.522
0.076
0.11
0.23
0.18
0.2
0.11
0.14
0.366
0.356
0.230
0.32
0.16
0.74
0.20
0.21
ND
0.32
0.24
0.296
0.06
0.100
0.2
1.07
0.47
0.64
0.17
ND
0.14
0.45
0.11
0.16
0.167
0.06
0.15
0.03
1.77
0.13
0.08
0.16
ND
123
TCB
3.53
0.77
0.51
ND
ND
ND
0.35
ND
ND
0.46
2.11
24.8
ND
0.60
ND
ND
1.10
3.23
ND
0.57
NO
ND
ND
ND
ND
ND
ND
124
TCB
2.25
D 0.47
0 0.37
ND
0.29
0.65
D 0.29
0.47
0.78
D 0.54
D 1.73
49.0
0.59
D 0.32
0.84
0.78
D 0.71
5.66
1.28
D 0.57
0.69
1.25
ND
ND
3.33
ND
10.2
135
TCB
D 0.44
D ND
D ND
ND
D ND
D ND
D ND
D ND
D ND
0 0.15
0 ND
ND
D ND
D ND
D HA
D ND
D ND
0.29
D ND
D ND .
D ND
D ND
ND
ND
ND
ND
ND
1234
TCB
D ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.35
ND
11.3
ND
ND
ND
ND
ND
0 0.93
NO
ND
ND
ND
ND
ND
2.45
ND
4.76
1235
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.33
ND
12.9
ND
ND
ND
ND
ND
0 NO
NO
ND
ND
ND
ND
ND
D ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.33
ND
12.9
NO
NO
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
OCS
ND
ND
ND
ND
ND
ND
ND
ND
ND
0 16.8
14.8
14.3
ND
NO
NO
ND
ND
ND
ND
ND
NO
ND
NO
NO
50.7
5.61
ND
PCB
ND
ND
ND
ND
ND
ND
NO
NO
ND
0.82
1.46
8.56
ND
ND
ND
0.82
ND
2.77
3.40
ND
NO
2.24
1.63
ND
3.64
NO
5.21
PC
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
HCB
aBHC
ND 2.67
ND ND
ND ND
ND
ND
30.3
1.95
ND
ND
ND
gBHC
3.98
ND
ND
ND
ND
CIS
CHLOR
NO
4.35
ND
ND
ND
TRANS
CHLOR
3.87
2.49 D
ND
ND
ND
ND 2.94 ND ND 14.9
ND ND ND ND 4.74
ND 1.12 D 0.58 D 1.26 D ND
1.16 D 0.27 D 1.96 D 1.08 D ND
8.19 2.27 D 1.33 D 18.1 5.58
8.87 4.76 ND 17.0 1.91 D
ND
7.22
ND
15.2
ND
ND
125 E 84.7
3.69 ND
1.42 D 1.09 D ND
85.5 ND 5.43
ND
5.06
55.3
ND
3.08
30.6
ND ND
ND 17.4
6.94 19.3
ND ND
6.10 9.16
ND ND
NO ND
ND
18.1
18.9
ND
15.8
25.1
18.2
1.28 D ND
100 78.5
179 125
NO ND
83.2 71.5
129 107
118 96.0
0.85 D 2.22 D ND 2.70 ND
25.3 20.8 ND 95.3 53.8
2.38 D 1.45 D 0.86 D 1.86 D ND
NO 15.9 44.5 164 112
-------
3
Episode SCC Type Description
Merc
P9/9
123
TCB
124
TCB
135
TCB
XENOB10TICS CONCENTRATIONS, ng/g
1234
TCB
1235
TCB
1245
TCB
DCS
PCB
PCNB
2422 DE009702
2427 DE010203
2427 DE010202
2429 DE010403
2429 OE010402
2430 OE010602
2430 DE010603
2430 00121488
2431 OE010702
2431 OE010703
2432 OE010713
2432 OE010710
2435 DE011004
2435 DE011001
2437 DE011202
2437 DE011203
2439 DE011401
2439 DE011402
2478 DJ003901
2478 OJ003903
2478 OJ003902
2500 DC010201
2500 DC010203
2532 DF019302
2532 DF019303
2544 DF019203
2544 DF019202
2608 OE014501
2608 OE014504
2618 OE015401
2618 DE015402
2618 OE015403
2651 DB008401
2653 DB008503
2654 OB008601
2709 DB005101
2721 OA006S02
2721 OD011089
2722 DA006601
2725 OA006301
2748 DY006506
2748 OY006505
2776 DY007103
2776 DY007101
UB Carp
PF Walleye
UB Carp
PF Walleye
UB Carp
PF Northern Pike
UB Redhorse Sucker
UB Redhorse Sucker
PF Brown Trout
UB Sucker
PF Walleye
UB Redhorse Sucker
PF Brook Trout
UB Longnose Sucker
PF Walleye
UB Carp
UB Carp
UP Sra Bass
BF Sucker
UB Chisel mouth
UB Sucker
PF Bass
UB Black Buffalo
PF Lin Bass
UB Carp
PF Lm Bass
UB Blacktail Redhorse
PF Walleye
UB Carp
UB Carp
BF Carp
UB Quillback
UB White Sucker
UB Carp
UB Carp
UB Catfish
UB Sucker
UB Sucker
UB Sucker
UB Sucker
BF Sucker
UB Sucker
PF Trout
UB Carp
2776 Q0010489 L UB Carp
0.206
0.23
0.10
0.33
0.27
0.2
0.10
0.27
0.09
0.49
0.25
0.13
0.08
0.29
0.12
0.05
0.05
0.16
NO
0.14
0.26
0.12
0.11
ND
0.73
0.58
0.69
0.18
0.02
0.06
0.04
0.28
0.14
0.68
0.10
0.11
0.34
0.06
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.32 D
0.65 0
ND
2.11 D
ND
0.33 D
1.86 D
ND
0.47 D
10.59
1.59 D
ND
ND
ND
ND
0.51 0
ND
ND
ND
1.24 D
ND
ND
ND
ND
ND
ND
ND
1.81 D
ND
ND
0.47 D
ND
ND
ND
ND
0.34 D
1.49 D
0.45 D
0.93 D
264. 81E
3.01
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.93
0.52
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0 0.93
D 0.52
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.27
ND
ND
11.3
1.92
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.61
ND
ND
ND
D ND
2.92
ND
0.59
1.98
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
2.72
7.51
ND
ND
0.51
ND
1.76
2.36
ND
6.49
3.08
ND
ND
93.7
ND
4.03
22.5
5.41
ND
NO
2.56
0.84
3.48
ND
ND
ND
ND
ND
ND
ND
11.3
29.0
9.09
ND
D 1.56
2.32
D 3.37
D 9.08
ND
5.56
2.61
1.04
0.52
ND
ND
15.9
6.00
2.07
ND
0.80
1.45
D 2.37
3.58
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.65
ND
D ND
D ND
ND
2.97
ND
27.4
9.95
D ND
D 2.18
2.24
ND
ND
17.2
D 6.58
24.4
D ND
D 5.25
D ND
3.97
ND
ND
ND
19.0
ND
ND
ND
ND
92.1
31.0
ND
ND
ND
ND
26.5
12.2
96.0
41.0
1.97
D 6.51
D 41.0
ND
ND
147
39.4
131
9.90
NO
37.25
41.1
ND
ND
ND
ND
ND
1.11
1.31
ND
45.8
14.5
NO
ND
ND
ND
11.8
ND
69.4
20.3
D NO
5.53
48.0
4.86
6.73
118
31.4
97.1
3.92
ND
64.66
20.9
ND
ND
ND
ND
ND
D ND
D ND
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3001 DE019S01
3001 DE01950Z
3022 DA008402
3022 DA008401
3023 DA008501
3024 DA008601
3025 OA008702
3025 OA008701
3026 OA009001
3026 DA009002
3027 DA009301
3028 DA008801
3034 DG025702
3034 DG025701
3035 DG025802
3035 DG025801
3036 DG025901
3036 DG025902
3037 OG026002
3037 OG026001
3038 OG026102
3038 DG026101
3039 DG026202
3039 DG026201
3040 DG026302
3040 DG026301
3041 DG026401
3041 DG026402
3042 OG026501
3042 DG026502
3042 00026501
3043 DG026602
3043 DG026601
3044 DG026702
3044 DG026701
3045 DG026801
3045 DG026802
3046 OG026901
3047 OG027002
3047 DG027001
3048 DG027101
3048 OG027102
3048 00012689
3048 00027101
3049 DG027202
F PF ualleye
F UB White Sucker
F PF Chain Pickerel
F UB White Sucker
F PF Sm Bass
F PF Lm Bass
F PF Chain Pickerel
F UB White Sucker
F WB Catfish
F PF Lm Bass
F UB Sucker
F PF Chain Pickerel
F PF Lm Bass
F UB Carp
F PF Sm Bass
F UB Carp
F PF Freshwater Drum
F UB Carp
F PF Black Crappie
F UB Carp
F PF Channel Catfish
F UB Carp
F PF Channel Catfish
F UB Carp
F PF White Crappie
F UB Carp
F PF Channel Catfish
F UB Carp
F UB Carp
F PF Northern Pike
L UB Carp
F PF Flathead Catfish
F BF Flathead Catfish
F PF Flathead Catfish
F UB Carp
F UB Carp
F BF Flathead Catfish
F UB Bigmouth Buffalo
F PF Sm Bass
F UB Carp
F UB Carp
F PF White Bass
L PF White Bass
L UB Carp
F PF Crappie
Merc
P9/9
0.82
NA
0.31
0.05
0.54
0.37
0.99
0.28
0.08
0.8
0.21
0.73
0.13
0.08
0.17
0.08
0.19
NO
0.09
0.12
0.077
NO
0.08
0.05
0.39
0.11
NO
NO
NO
0.64
0.16
NO
0.19
NO
0.13
0.24
0.14
0.21
0.09
NO
0.13
123
TCB
ND
0.28
0.37
0.34
ND
ND
ND
ND
0.39
ND
ND
ND
0.29
ND
ND
0.19
ND
ND
ND
ND
ND
ND
NO
NO
0.14
ND
ND
124
TCB
ND
D 0.47
0 0.22
D 0.67
.28
ND
0.17
ND
D 0.57
ND
ND
ND
D ND
ND
ND
D ND
ND
0.46
ND
ND
ND
ND
ND
1.16
D 0.09
ND
ND
135
TCB
ND
D 0.18
D ND
D ND
D ND
ND
D ND
ND
D ND
ND
NND
ND
0.15
ND
ND
ND
NO
D ND
ND
ND
ND
ND
ND
D 0.66
D ND
ND
ND
1234
TCB
ND
0 0.25
ND
0.28
.09
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
1235
TCB
ND
D ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
DCS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
N
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
PCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.88
ND
0.77
ND
ND
ND
ND
ND
0.84
0.82
ND
ND
PCNB
ND
ND
ND
NO
.12 D ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D 15.5
D ND
ND
ND
HCB
NO
NO
ND
NO
0.60
ND
ND
ND
3.37
3.06
ND
0.59
aBHC
ND
ND
ND
ND
gBHC
ND
ND
ND
ND
CIS
CHLOR
ND
ND
ND
ND
TRANS
CHLOR
ND
ND
ND
ND
0.17
0.59 D 2.40 D 0.67 D 5.05 3.50
ND
8.00
26.3
ND
13.0
77.4
86.8
E 7.03 E
0 1.25 D
57.1
D 0.72 D
90.8
ND
ND
E 188 E
21.2
21.8
NO
E 135
NO
ND
E 169
ND
0.73
1.41
0.93
0.86
NO
16.8
1.73
D
D
D
D
0
ND
2.73
1.83
2.83
2.27
ND
1.84
0.21
D
D
D
D
ND
10.3
NO
2.53
ND
ND
8.25
0.51
ND
8.65
22.6
ND
12.4
73.9
102
0 8.95
D 0.99
12.3
ND
5.03
D 0.76
83.3
ND
70.9
D 1.50
51.8
1.34
89.9
1.37 D 2.59 2.31 D ND
2.93
ND
NO
D 1.16
10.1
10.5
ND
D ND
ND
196
19.9
23.6
ND
2.32
ND
ND
ND
ND
D 2.01
ND
NO
NO
ND
D 3.
ND
ND
2.
ND
50
23
4
0
0
D 1
.74
.76
.66
.68
D
0
D
ND
4
0
0
5
.99
.80
.77
.02
D
D
ND
147
ND
ND
200
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3049 DG027201
3050 DG027301
3060 DF009101
3060 DF009102
3060 QD073189
3061 DF01910S
3061 DF019106
3062 DF024024
3063 OF023301
3063 DF023302
3064 DF023306
3064 DF02330S
3065 DF023419
306S DF023420
3065 QD0107B8
3066 DF023503
3066 DF023504
3068 DF024001
3068 DF024002
3069 DF024007
3069 DF024008
3069 OD051788
3070 DF024009
3070 DF024010
3071 DF024014
3071 DF024015
3072 DF024018
3072 DF024017
3072 00070688
3073 DF019222
3073 DF019221
3074 DF026017
3075 OF024102
3076 DF028503
3076 OF028S02
3077 DF019113
3077 DF019114
3078 OF009118
3078 DF023815
3078 DF023816
3079 DF019205
3079 DFO19206
3080 DF023317
3080 DF023318
3081 OF024105
US Carp
WB Bigmouth Buffalo
WB Flathead Catfish
UB Sm Buffalo
WB Flathead Catfish
PF Bass
UB Sucker
UB Blue Catfish
UB Sea Catfish
PF Spotted Seatrout
PF Spotted Seatrout
Shellfish
BF Bigmouth Buffalo
UB Flathead Catfish
BF Bigmouth Buffalo
UB Catfish
PF Freshwater Drum
Oysters
PF At I. Croaker
UB Sea Catfish
PF Trout
UB Sea Catfish
UB Croaker
PF Sheepshead
UB Carp
PF Longnose Gar
PF White Bass
UB Carp
UB Carp
PF Sm Bass
UB White Sucker
PF Brown Trout
PF Hardhead Catfish
PF Spotted Bass
UB Channel Catfish
PF Flathead Catfish
UB Redhorse Sucker
UB Carp
UB Sm Buffalo
PF Black Crappie
PF White Bass
UB Carp
UB Carp
PF Lm Bass
PF White Bass
Merc
«*9/9
0.09
0.09
0.12
ND
0.24
0.20
ND
0.23
0.15
0.07
0.00
0.06
ND
NA
ND
0.08
ND
ND
0.11
0.20
NA
0.05
0.06
0.08
0.66
0.49
0.11
NA
0.204
0.06
0.07
0.38
0.58
0.09
0.882
0.42
NA
0.26
0.07
0.18
0.06
0.23
0.83
0.68
123
TCB
ND
ND
ND
ND
ND
NO
1.73
ND
ND
ND
ND
0.37
ND
0.51
0.52
0.62
ND
ND
1.04
ND
5.84
1.48
ND
ND
ND
ND
0.27
0.69
ND
ND
ND
ND
ND
ND
ND
NO
0.64
0.16
124
TCB
0.40
ND
ND
ND
ND
0.06
D 1.05
1.36
0.45
ND
0.15
D 0.63
0.15
D 1.11
D 0.71
D 0.34
0.66
ND
D 0.60
ND
3.39
D 0.87
ND
0.97
ND
ND
D 0.25
D 0.43
ND
ND
ND
ND
ND
ND
ND
4.81
D 0.36
D ND
D
D
D
D
D
D
D
0
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
ND
ND
0.54
0.18
ND
ND
ND
ND
ND
ND
ND
0.45
ND
ND
ND
0.56
0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
1234
TCB
ND
ND
ND
ND
ND
ND
ND
D 3.47
D 5.21
ND
0.60
0.19
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.38
ND
ND
ND
ND
ND
0.06
1235
TCB
ND
ND
ND
ND
ND
ND
ND
8.74
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
0.53
ND
D ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
8.74
9.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
3 0.53
ND
ND
CCS
ND
ND
ND
ND
ND
ND
ND
43.1
4.53
ND
ND
ND
ND
ND
ND
ND
ND
0.56
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
10.4
51.40
ND
ND
0.24
ND
0.81
ND
ND
1.99
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34
ND
ND
ND
ND
ND
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
*ND
ND
D ND
ND
ND
ND
ND
ND
ND
HCB
1.27
1.37
ND
ND
ND
0.13
ND
75.0
43.69
ND
0.30
3.26
0.31
6.19
2.41
ND
7.66
ND
ND
ND
ND
ND
ND
ND
0.73
0.48
ND
ND
ND
ND
ND
ND
ND
2.10
2.24
ND
ND
aBHC
D 2.51
D 4.51
ND
ND
ND
D 0.42
NO
2.69
3.23
0.80
D ND
1.94
D ND
6.63
D ND
ND
10.1
3.10
ND
ND
4.71
ND
ND
ND
D 0.96
D 0.54
ND
ND
0.99
ND
ND
4.04
0.31
D ND
D 2.19
3.33
ND
gBHC
2.68
3.19
ND
ND
ND
D ND
ND
3.15
ND
D 1.98
ND
D 0.81
ND
ND
ND
5.34
6.68
ND
ND
5.11
ND
ND
9.53
ND
D 0.66
D 0.78
ND
ND
D ND
ND
ND
1.07
D ND
1.59
D 2.58
14.4
ND
CIS
CHLOR
ND
21.0
ND
9.19
ND
ND
11.5
6.16
8.07
D ND
2.70
D 8.46
2.88
19.8
1.75
ND
8.78
3.51
ND
1.89
2.59
ND
82.09
66.04
D 2.00
D 2.30
ND
ND
ND
ND
ND
D ND
ND
D 5.19
13.2
ND
ND
TRANS
CHLOR
30.2
18.2
ND
15.64
ND
ND
9.30
ND
3.13
3.12
3.08
6.86
3.30
19.3
D 2.64
ND
4.00
ND
ND
D ND
ND
ND
91.94
101.90
D 1.35 D
D 1.43 D
ND
ND
1.83 D
ND
ND
23.2
1.62 D
19.67
9.74
31.0
ND
0.12 D 0.58 D ND
1.70 D 0.26 D
-------
XEN08IOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3081 DF024106
3082 DF023402
3082 DF023401
3083 DF023405
3083 DF023406
3084 DF024109
308S DF024113
3085 DF024114
3086 DF023411
3086 DF023409
3086 DF023410
3087 DF023416
3087 DF023413
3087 DF023414
3087 OF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 DF019210
3090 OF019213
3090 DF019214
3091 DF019218
3091 DF019217
3092 DF023S01
3092 DF023502
3093 DF024011
3093 DF024118
3094 DC017201
309S DC038801
3095 DC038802
3096 DC035001
3096 DC035002
3097 DC038701
3097 DC038702
3097 00071989
3098 OC038601
3098 DC038602
3098 OD051288
3100 OC019701
3101 OC019901
3103 DC036201
3103 DC036202
3104 OC020001
3104 DC020002
3105 DF025001
US Catfish
PF Lm Bess
UB Carp
WB Black Bullhead
PF Lm Bass
UB Channel Catfish
UB Sea Catfish
PF Black Orun
PF Black Drun
UB Catfish
PF Red Drun
UP Lm Bass
UB Carp
PF White Crappie
UP Bluegill
UB Channel Catfish
PF Bluegill
PF White Crappie
UB Carp
PF White Crappie
UB Channel Catfish
PF Uhite Crappie
UB River Carpsucker
UB Carp
PF Wai-mouth
PF Lm Bass
UB Sm Buffalo
BF Channel Catfish
BF Brown Bullhead
UB Channel Catfish
BF Broun Bullhead
UB Channel Catfish
BF Brown Bullhead
UB Carp
PF Brown Bullhead
UB Uhite Sucker
PF American Eel
UB Uhite Sucker
PF Uhite Perch
PF Brown Trout
UB Channel Catfish
UB Carp
PF Lm Bass
UB Carp
UB Carp
Here
M9/9
0.10
ND
ND
ND
0.313
0.10
0.12
0.05
0.08
0.31
0.32
0.09
ND
0.07
0.03
0.05
0.18
ND
ND
ND
ND
0.06
ND
0.26
0.28
0.816
0.207
0.15
0.06
0.08
0.06
0.11
0.16
0.07
0.08
0.19
NA
ND
ND
0.05
ND
0.15
ND
0.08
123
TCB
0.23
ND
0.32
ND
ND
ND
ND
ND
0.57
ND
0.55
ND
0.26
ND
0.43
0.33
0.35
ND
0.31
0.53
0.18
ND
3.36
0.51
ND
1.35
1.47
ND
ND
54.89
ND
3.13
ND
0.99
0.51
ND
ND
0.89
1.31
ND
D
D
D
D
D
D
D
D
D
0
D
D
D
D
124
TCB
0.22
ND
0.30
ND
ND
0.91
ND
ND
0.49
ND
0.46
ND
ND
0.11
0.30
0.21
0.21
ND
0.78
0.29
0.14
0.08
3.30
0.44
0.55
1.11
1.43
ND
ND
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
103.82
D
D
D
D
ND
5.15
ND
0.78
0.79
ND
ND
0.98
1.23
ND
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.08
ND
ND
ND
0.48
ND
0.12
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
0.07
ND
ND
ND
ND
ND
2.18
6.35
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.05
ND
ND
ND
0.09
10.4
1.82
3.50
D 1.16
10.6
20.92
6.34
D 76.65
ND
D 2.22
ND
ND
0.28
ND
ND
ND
ND
ND
1235
TCB
D ND
ND
ND
ND
3.46
1.08
D 3.17
10.7
ND
ND
ND
ND
ND
ND
0.16
ND
0.27
D ND
ND
ND
ND
D ND
4.25
D 1.44
1.64
D 1.29
6.18
4.21
0.79
28.30
ND
D 1.23
ND
ND
D ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
3.46
0 1.08
3.17
10.7
ND
ND
ND
ND
ND
ND
D 0.16
ND
D 0.27
ND
ND
ND
ND
ND
4.25
D 1.44
D 1.64
D 1.29
6.18
4.21
D 0.79
28.30
ND
D 1.23
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
ND
ND
ND
65.3
D ND
138
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D 0.74
ND
ND
ND
ND
ND
ND
D ND
D ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
0.06
NO
ND
ND
42.6
11.02
E 125
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.57
ND
0.32
ND
ND
ND
7.76
1.71
5.41
1.19
9.47
30.49
46.3
36.17
ND
1.30
ND
0.53
0.35
ND
ND
ND
1.26
ND
PCI
D ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
D ND
D ND
ND
ND
ND
D ND
ND
HCB
ND
1.54
ND
ND
913
50.74
202
18.1
ND
ND
ND
ND
ND
ND
0.34
ND
1.35
ND
ND
ND
NO
0.25
5.38
ND
ND
ND
ND
2.57
12.5
1.97
ND
0.77
ND
2.74
0.31
2.11
ND
ND
ND
ND
D
E
E
D
D
D
D
D
D
D
aBHC
0.83
7.56
0.43
2.27
ND
ND
4.23
0.74
2.83
0.93
2.98
17.8
ND
ND
0.90
ND
2.17
0.63
1.65
ND
ND
0.65
2.78
ND
ND
0.64
15.3
1.10
ND
0.41
ND
ND
44.4
4.27
ND
ND
ND
1.58
ND
ND
D
D
D
D
D
D
D
D
D
D
D
D
D
D
gBHC
ND
ND
ND
9.57
ND
ND
1.64
0.29
ND
ND
1.54
ND
ND
ND
0.49
ND
1.40
0.42
ND
NO
ND
ND
1.68
2.09
ND
ND
4.86
ND
ND
ND
ND
38.8
ND
2.85
ND
ND
22.6
ND
5.04
ND
CIS
CHLOR
ND
ND
ND
80.6
ND
ND
D 6.62
D ND
ND
ND
D ND
ND
ND
ND
D 4.02
0.90
D 19.3
D 0.62
ND
ND
ND
1.68
D 92.8
D 23.1
78.4
5.80
97.7
3.76
7.80
2.44
ND
1.95
ND
4.52
0.22
26.25
ND
1.80
56.9
6.22
TRANS
CHLOR
ND
7.85
ND
39.8
ND
ND
ND
ND
4.38
ND
ND
ND
ND
ND
2.73
D 0.44
11.2
D ND
ND
ND
ND
D 0.93
E 58.1
17.2
53.1
7.61
62.2
5.81
ND
D 3.81
ND
D 7.12
ND
13.08
D 2.63
51.05
15.9
D 4.75
45.4
E 3.33
-------
XENOB10TICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3105 DF025002
3106 DE026801
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3110 DE022501
3110 DE022502
3111 DH015801
3111 DH015802
3112 DE022401
3112 DE022402
3113 DE021101
3113 DE021102
3113 QD030789
3114 DE021201
3115 DE021301
3115 DE021302
3115 QD101689
3117 DE021501
3118 DE021601
3118 DE021602
3118 DE021603
3118 OD010689
3118 QD020488
3119 DE021702
3119 DE021701
3120 DE021801
3120 DE021802
3122 DE022004
3122 DE022001
3122 DE022003
3125 DE022301
3125 DE022302
3132 DE023201
3132 OD010588
3134 DE023403
3134 DE023405
3134 DE023406
3135 DE023501
3136 DE023601
3137 DE023701
3138 DE023801
3140 DE024001
3140 DE024002
F PF Lm Bass
F PF Walleye
F UB Carp
F PF Walleye
F UB Carp
F UB Carp
F BF Flathead Catfish
F BF Carp
F PF Walleye
F WB Silver Redhorse
F UB Carp
F PF Walleye
F BF Channel Catfish
F BF Carp
F BF Channel Catfish
F BF Carp
F WB Carp
F PF Catfish
L WB Carp
F PF Lake Trout
F PF Walleye
F WB Carp
F WB Carp
L WB Carp
L PF Walleye
F PF Lm Bass
F UB Carp
F UB Carp
F PF Bass
F PF Sm Bass
F UB Carp
F UB Redhorse Sucker
F UB Carp
F PF White Bass
F UB Carp
L UB Carp
F UB Carp
F UB Carp
F UB Sucker
F UB Carp
F PF Northern Pike
F UB Redhorse Sucker
F UB Carp
F PF Walleye
F UB Carp
Merc
fig/9
0.134
0.57
0.16
0.25
0.30
0.23
0.11
0.04
0.91
0.14
0.179
0.47
0.08
0.08
0.07
0.05
0.09
0.22
0.56
0.15
0.24
NA
0.28
0.33
0.17
0.30
0.56
1.40
0.61
0.11
0.48
0.22
NA
0.09
0.03
0.05
0.09
0.24
0.13
0.21
0.09
0.04
123
TCB
ND
0.57
NO
0.18
ND
0.44
ND
7.46
ND
0.70
ND
ND
ND
ND
ND
ND
2.48
ND
6.94
ND
1.77
ND
ND
ND
ND
0.22
ND
0.16
ND
0.51
1.47
2.05
ND
ND
ND
ND
ND
ND
ND
ND
ND
D
0
D
D
D
D
D
D
D
D
0
124
TCB
ND
0.42
0.07
0.13
ND
ND
ND
4.71
0.50
0.63
ND
ND
ND
0.50
0.24
2.43
4.98
1.06
4.51
ND
ND
ND
ND
ND
0.20
0.13
ND
0.19
ND
0.26
8.41
11.94
ND
ND
ND
ND
ND
NO
ND
ND
ND
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
ND
ND
0.10
ND
0.11
ND
ND
ND
ND
ND
0.03
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
0.06
ND
ND
ND
ND
0.74
0.78
ND
ND
ND
ND
0.04
ND
ND
ND
ND
1235
TCB
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
0.28
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
OC!
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.87
0.91
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCNB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D 13.85
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
ND
0.77
ND
ND
ND
ND
ND
ND
1.63
ND
1.57
1.88
1.21
0.75
3.82
ND
ND
5.22
0.10
ND
0.74
ND
0.24
ND
0.15
ND
ND
2.64
ND
ND
ND
0.73
ND
ND
0.92
ND
ND
1.44
ND
0.49
D
D
D
D
D
D
D
D
D
D
D
D
D
D
aBHC
ND
ND
1.81
ND
1.77
ND
1.08
5.87
10.6
2.77
ND
0.79
ND
0.50
1.45
ND
ND
0.76
5.48
ND
ND
0.39
ND
0.18
ND
0.42
8.31
1.55
6.56
0.34
ND
ND
1.15
1.20
ND
1.46
ND
2.22
ND
ND
ND
D
0
D
D
D
D
D
D
D
D
D
D
D
D
D
D
gBHC
ND
ND
ND
ND
ND
ND
ND
ND
7.59
ND
ND
1.39
2.17
1.35
1.71
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0.48
ND
0.69
5.68
0.61
12.40
ND
1.17
ND
ND
1.58
ND
ND
ND
ND
ND
CIS
CHLOR
ND
ND
ND
ND
2.03 D
5.81
4.42
67.8
7.53
3.35
ND
D 12.1
D 23.7
D 12.8
D 31.3
31.0
29.1
28.5
154
6.74
18.8
3.88
19.6
7.73
10.40
D 2.99
35.2
D ND
ND
D 2.21 D
53.84
67.69
D 3.15
5.86
ND
D 4.73
ND
ND
12.5
1.93 D
3.63
TRANS
CHLOR
ND
ND
ND
ND
ND
3.87
2.09
38.7
5.24
1.17
ND
7.44
14.4
7.86
33.5
36.4
39.4
34.1
51.8
1.71
5.80
1.41
6.29
1.87
6.06
0.86
18.4
ND
ND
0.50
41.20
46.00
2.55
7.30
ND
2.74
ND
ND
7.59
0.72
2.32
D
D
D
D
D
D
D
D
D
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3141 DE024101
3141 DE024102
3141 DE024103
3H3 OE024401
3H3 DE024403
3144 DE024901
3145 DE026601
3U6 OE026701
3U6 DE026702
3U7 DC035201
3148 DE027101
3148 DE027103
3149 DC038501
3150 DA008901
3150 QD120187
3151 DA009101
3152 DA009201
3161 DC019801
3161 DC019802
3162 OJ024001
3163 DJ024002
3164 00015701
3164 DD015702
3165 DD015703
3165 D0015704
3166 00015705
3166 00015706
3167 DD015707
3167 D0015708
3167 OD062388
3168 DDO15711
3168 DD015712
3169 DD015714
3169 DD015713
3169 OD022789
3170 DD015716
3170 DD015715
3171 DD015718
3171 D0015717
3172 DD015719
3172 DD015720
3173 DD015721
3173 DD015722
3174 DD015723
3174 DD015724
PF Northern Pike
WB Carp
PF Northern Pike
Rotten (catf)
UB Carp
UB Carp
UB N. Redhorse
UB Carp
PF Walleye
UB Carp
UB Carp
PF Walleye
UB White Sucker
UB White Sucker
UB White Sucker
UB White Sucker
UB White Sucker
BF Black Bullhead
UB White Sucker
UP Starry Flounder
UP Starry Flounder
PF Lm Bass
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Walleye
UB White Sucker
PF Lm Bass
F UP Bluegill
L UP Bluegill
F UB Carp
PF Lm Bass
PF Lm Bass
UB Black Redhorse
UB Black Redhorse
PF Lm Bass
UB Spotted Sucker
PF Lm Bass
UB Spotted Sucker
UB Carp
PF Lm Bass
PF Lm Bass
UB Channel Catfish
PF Lm Bass
UB Channel Catfish
Merc
P9/9
0.17
0.02
0.14
0.01
0.05
0.20
0.22
0.16
0.28
0.05
0.08
0.82
0.14
0.158
NA
0.22
0.06
0.12
0.05
0.05
NO
0.665
0.18
0.43
0.25
0.87
0.29
0.33
0.08
NA
0.19
0.37
0.4
0.16
0.82
0.15
0.72
0.15
NO
0.11
0.31
0.06
0.29
0.05
123
TCB
ND
NO
ND
3.78
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
0.20
ND
0.53
NO
ND
ND
30.2
4.90
0.24
ND
ND
ND
0.22
ND
ND
ND
ND
NO
ND
ND
ND
124
TCB
0.59
ND
ND
2.32
ND
ND
NO
ND
ND
0.55
ND
ND
ND
ND
ND
D ND
ND
D 0.55
NO
ND
NO
23.3
8.52
D 0.25
NO
NO
ND
D ND
ND
ND
0.12
0.09
0.69
ND
0.42
ND
135
TCB
D ND
ND
ND
0 ND
NO
0.26
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
NO
ND
0.14
D ND
NO
NO
ND
ND
ND
ND
0 NO
0 ND
D NO
ND
D ND
NO
1234
TCB
ND
NO
ND
ND
ND
D ND
ND
ND
ND
ND
0.37
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
6.29
D 1.10
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
0.39
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
3.12
D ND
D 0.13
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
1.26
ND
1245
TCB
ND
ND
ND
ND
NO
D 0.39
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.12
ND
D 0.13
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
D 1.26
ND
OCi
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
33
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
PCS
0.54
0.78
ND
NO
0.28
ND
ND
ND
ND
0.81
ND
ND
ND
ND
ND
ND
ND
0.52
1.45
ND
ND
2.77
ND
ND
ND
ND
0.56
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCNB
D ND
0 ND
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
NO
NO
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
4.69
ND
ND
0.81
NO
0.57
1.21
ND
3.64
3.19
ND
0.23
ND
ND
ND
ND
0.64
ND
29.2
ND
ND
ND
ND
ND
ND
4.84
0.89
ND
ND
0.09
0.09
ND
ND
ND
ND
aBHC
3.31
ND
1.90
ND
0 1.33
ND
D 1.95
D 0.85
ND
3.98
3.29
ND
D 0.26
ND
1.84
1.47
ND
D 0.59
4.64
0.45
0.25
ND
ND
ND
ND
ND
1.86
D ND
ND
ND
D ND
D ND
ND
ND
ND
ND
gBHC
ND
6.28
D ND
ND
D ND
ND
D 1.82
D ND
ND
6.40
1.71
ND
D 6.40
6.34
D 6.50
D 1.56
3.98
D NO
1.40
D ND
D 0.66
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
1.15
ND
3.27
ND
CIS
CHLOR
22.2
56.5
10.3
ND
6.92
6.88
D ND
ND
ND
42.6
D ND
7.37
10.0
13.0
14.3
D 7.19
ND
23.03
D 155
1.96
D 0.58
ND
ND
ND
ND
ND
ND
ND
4.83
4.40
ND
ND
D 6.18
ND
9.70
3.38
TRANS
CHLOR
6.93
30.9
2.79
ND
3.52
4.23
ND
ND
ND
28.9
ND
2.12 D
3.64
6.12
6.62
2.92
ND
36.15
82.7
D 0.76 0
D NO
ND
ND
ND
ND
ND
1.43 D
ND
ND
2.01 D
0.63 D
0.49 D
5.11
ND
4.53
1.29 D
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3175 DDO15802
3175 DDO15801
3176 DD015804
3176 DDO15803
3177 DD01580S
3177 QD100488
3178 DDO15808
3178 DD015807
3179 DD015810
3179 DD015809
3180 DD015812
3181 DD015813
3181 DD0158H
3182 DD015815
3182 DD015816
3183 DD015817
3183 DD015818
3184 DD015819
3184 DD015820
3185 DD015822
3185 DD015821
3186 OD015824
3187 DD015902
3188 DD015903
3188 DD015904
3189 DD015906
3189 DD01590S
3189 OD092188
3190 DD015908
3190 OD015907
3191 DJ024003
3191 OJ024005
3192 DJ024007
3192 DJ024009
3193 DC039002
3193 DC039001
3195 OH020104
3195 DH020105
3196 DH020107
3196 DH020108
3197 DH020110
3197 DH020109
3198 OH020111
3199 DH020102
3199 DH020101
PF Lm Bass
UB Channel Catfish
PF Lm Bass
UB Spotted Sucker
UB Carp
UB Carp
PF Redeye Bass
UB North Hogsucker
PF Lm Bass
UB Golden Redhorse
PF Lm Bass
PF Lm Bass
UB Carp
PF Rock Bass
UB Carp
UB Carp
PF Sauger
UB Carp
PF White Crappie
PF Lm Bass
UB Channel Catfish
UP Southern Flounder
UP Sunnier Flounder
UB Carp
PF Lm Bass
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
UB Carp
UP Starry Flounder
Soft Shell Clams
UP Starry Flounder
Soft Shell Clams
PF Sm Bass
PF Sm Bass
UB Carp
UB Chub
PF Brown Trout
UB Sucker
UB Sucker
PF Rainbow Trout
UB Sucker
PF Walleye
UB Carp
Merc
M9/9
0.4
0.18
0.13
NO
0.03
NA
0.55
0.23
0.44
0.24
0.43
0.28
0.06
0.13
0.04
ND
0.30
0.14
0.31
0.67
0.12
0.05
ND
0.03
0.14
0.26
0.06
NA
0.05
0.05
0.01
0.01
0.01
0.01
0.4
0.35
0.08
0.14
0.182
0.182
0.06
ND
0.12
0.37
0.09
123
TCB
ND
ND
ND
ND
ND
ND
0.39
1.03
ND
ND
ND
ND
ND
ND
ND
ND
1.67
0.16
ND
ND
ND
0.09
ND
0.05
ND
1.71
ND
ND
ND
ND
ND
124
TCB
ND
ND
ND
ND
ND
ND
D 0.27
D 2.25
ND
ND
ND
ND
ND
ND
ND
ND
J 1.43
D ND
ND
ND
ND
D 0.07
ND
D 0.08
ND
D 2.46
0.83
NO
ND
2.00
0.17
135
TCB
ND
ND
ND
ND
ND
NO
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
J 0.486 J
0.09 D
1.20 D
0.20 D
0.92 D
D ND
ND
D ND
ND
D ND
D ND
ND
ND
D ND
D 0.06 D
1234
TCB
ND
ND
ND
ND
ND
ND
ND
0.58
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.06
ND
0.06
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
D 0.65
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
D 0.65
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
ND
ND
ND
ND
ND
ND
D 1.90
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCS
ND
ND
ND
ND
ND
ND
ND
D 1.02 D
ND
ND
0.73 D
ND
ND
5.73
ND
ND
0.629 J
ND
ND
ND
D ND
ND
ND
ND
ND
ND
0.54 D
ND
ND
1.21 D
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
ND
ND
ND
ND
aBHC
ND
ND
ND
ND
ND
gBHC
CIS
CHLOR
0.32 D ND
ND ND
3.25 3.69
ND ND
0.891 D ND
7.83
D ND
9.30
0.28
ND
6.57
ND
ND
ND
ND
ND
ND
0.33
ND
ND
ND
ND
0.32
ND
ND
ND
ND
ND
ND
ND
5.68
ND
3.58
4.11
D 0.51
0.25
ND
ND
ND
D ND
2.29
ND
ND
1.48 D ND
ND
ND
ND
ND
ND
ND
ND
0.33
14.6
ND
ND
ND
8.02
ND
ND
ND
ND
3.88
4.67
ND
ND
ND
1.46
ND
ND
D ND
ND
ND
5.32
5.25
ND
8.13
ND
59.8
D ND
41.5
52.3
1.75
ND
38.8
ND
ND
60.1
ND
25.9
31.8
25.2
ND
ND
D ND
ND
19.8
14.0
30.1
TRANS
CHLOR
ND
1.06
4.18
4.12
ND
6.73
ND
38.5
ND
35.0
40.3
D 0.47
ND
30.6
ND
ND
58.4
ND
18.6
23.7
14.4
ND
ND
ND
ND
4.23
11.1
18.2
1.56 D 1.25 D ND
16.3 12.0 ND 28.8 20.4
0.52 D 0.93 D 0.45 D ND ND
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3199 DH020103
3200 DH020112
3203 DJ024018
3205 DJ024023
3205 DJ024024
3206 DJ024103
3208 DJ024109
3212 DJ024120
3212 DJ024121
3213 DJ024123
3215 DJ023705
3216 DJ023707
3216 DJ023708
3216 OD022388
3217 DJ023709
3217 DJ023710
3218 DJ023712
3218 DJ023711
3219 DJ023713
3219 DJ023714
3220 DJ023902
3220 DJ023903
3221 DJ023904
3221 DJ023905
3222 DJ023906
3222 DJ023907
3223 DJ023717
3224 DJ023715 t
3226 DJ023721 1
3227 DJ023723 1
3231 OJ023910
3231 DJ023911
3234 DH020302
3234 DH020301
3235 DH020304
3235 DH020303
3236 DH020306
3236 DH020305
3237 DH020307
3237 DH020308
3237 QD080988
3238 DJ023918
3241 DJ023923
3241 DJ023924
3244 DJ023622
V1
t
UB Carp
UB Sucker
UB Carp
PF Cutthroat Trout
Crayfish (whole)
UB Sucker
UB Sucker
BF Catfish
UB Carp
UB Squaufish
UB Sucker
PF Squaufish
UB Sucker
UB Sucker
PF Uhitefish
UB Sucker
UB Sucker
PF Squaufish
UB Uhite Sturgeon
PF Uhite Sturgeon
PF Squaufish
UB Bridgelip Sucker
PF Channel Catfish
UB Sucker
PF Squaufish
UB Sucker
UP Starry Flounder
1 Soft Shell Clams
1 Pacific Oysters
1 Pacific Oysters
PF Sm Bass
UB Carp
PF Lake Uhitefish
UP Squaufish
PF Broun Trout
UB Uhite Sucker
PF Broun Trout
UB Largescale Sucker
PF Rainbou Trout
UB Largescale Sucker
UB Largescale Sucker
UP Dolly Varden
PF Rainbou Trout
UP Dolly Varden
UB Coast Sculpin
Merc
M9/9
0.06
0.11
0.10
0.07
ND
ND
0.13
0.21
0.22
0.11
0.18
0.33
0.05
NA
0.06
0.07
0.09
0.36
0.10
0.09
0.23
0.05
0.34
0.08
0.74
ND
0.058
0.06
ND
ND
0.24
0.20
0.08
0.14
0.1
0.06
0.1
0.08
0.08
0.14
NA
0.05
0.06
0.05
ND
123
TCB
2.40
0.34
ND
ND
ND
ND
ND
ND
4.78
7.05
ND
0.24
ND
0.12
ND
ND
ND
ND
0.43
ND
ND
ND
0.32
ND
0.20
0.31
ND
ND
ND
ND
ND
ND
ND
124
TCB
D 1.39
D 0.32
0.72
ND
ND
0.38
ND
ND
2.16
6.26
ND
D ND
0.48
D 0.17
ND
0.12
ND
ND
D ND
ND
ND
ND
D 0.23
ND
D 0.14
D 0.55
ND
ND
ND
ND
ND
ND
ND
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
0.24
ND
ND
ND
ND
ND
ND
0.43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
NO
D ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.61
ND
ND
ND
ND
ND
ND
1.02
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
D 1.61
ND
ND
ND
NO
ND
ND
D 1.02
ND
ND
ND
ND
ND
ND
ND
OC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
ND
ND
ND
ND
ND
PCB
PCNB
ND
0.60 D
0.54 D
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
6.88
2.12
ND
ND
4.98
2.24
15.6
ND
ND
ND
ND
ND
ND
ND
3.32
ND
ND
10.6
1.49
ND
ND
ND
ND
ND
4.55
0.40
0.77
0.67
0.65
1.07
1.47
aBHC
ND
ND
D 1.11
ND
7.17
ND
D ND
ND
ND
ND
ND
2.74
5.48
4.03
ND
ND
ND
ND
4.89
D ND
ND
ND
0.35
ND
ND
1.89
D 0.91
D 2.78
D ND
ND
D ND
D ND
D ND
gBHC
ND
ND
D ND
ND
18.6
ND
ND
ND
ND
9.34
ND
ND
ND
ND
ND
ND
ND
ND
6.05
ND
ND
ND
D ND
ND
ND
D ND
D ND
2.88
2.57
3.35
3.88
ND
ND
CIS
CHLOR
9.33
13.7
9.68
ND
ND
7.03
3.59
13.7
ND
18.1
0.17
ND
ND
ND
0.73
10.8
0.80
ND
10.4
ND
ND
ND
ND
ND
ND
12.3
0.67
0.58
ND
ND
ND
ND
1.81
TRANS
CHLOR
8.64
ND
6.70
ND
ND
2.45 D
2.48 D
7.36
ND
6.53
D ND
ND
ND
ND
D ND
9.18
D 0.72 D
ND
4.68
ND
ND
ND
ND
ND
ND
7.27
D ND
D ND
ND
ND
ND
ND
D ND
-------
XENOBIOT1CS CONCENTRATIONS, ng/g
Episode SCC Type Description
3245 DJ023624
3246 OJ022109
3248 DJ022S02
3248 ODOSOS88
3249 OJ02250J
3249 DJ022504
3250 DJ022505
3250 DJ022506
3252 DJ022509
3252 OJ022510
3252 00020989
3252 00052588
3256 DJ022518
3258 DC038901
3258 DC038902
3259 DB000466
3259 DB000473
3259 DB069101
3260 DB000493
3261 DY026001
3261 DY026002
3262 DY026004
3266 DY022701
3266 DY022702
3266 OD012389
3267 DY022101
3267 OY022102
3270 DY022107
3270 DY022108
3271 DY022110
3272 DY022111
3272 DY022112
3273 DY022113
3273 DY022114
3274 DY022115
3274 DY022116
3275 DY022118
3276 DY022119
3278 DY022123
3278 DY022124
3281 DY022205
3282 DY022206
3282 DY022207
3283 DY022209
3285 DY022212
UP Flathead Sole
UP Flathead Sole
UB Composite Bottom
UB not available
PF Brook Trout
UB Sucker
PF Pink Salmon
UB Sucker
PF Lm Bass
UB Sucker
PF Lm Bass
UB Sucker
UB Sucker
PF Spot
UB Croaker
UB Goldfish
PF Lm Bass
UB Sucker
UB Carp
PF Caranx Ignobliis
UB Striped Mullet
UB Tilapia Tilapia
PF Black Crappie
UB Channel Catfish
PF Black Crappie
PF Rainbow Trout
UB Sacramento Sucker
PF Squawfish
UB Sucker
UB Sucker
PF Leopard Shark
UB White Surfperch
UB Sculpin
UB Surf Smelt
PF Rainbow Trout
UB Sculpin
UB Sucker
UB Walleye
PF Green Sunfish
UB Sacramento Sucker
UB Sucker
BF Flathead Catfish
UB Carp
UB Carp
UP Stingray
Merc
C9/9
ND
0.04
0.16
NA
0.08
0.21
0.11
0.09
0.29
0.10
NA
0.21
NO
0.05
0.21
1.66
0.29
0.05
0.05
ND
0.07
0.33
0.21
ND
ND
0.81
0.06
0.18
0.89
0.13
0.10
0.03
ND
0.21
ND
0.06
0.42
0.24
ND
0.03
ND
0.09
0.08
123
TCB
0.27
MO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MD
ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
3.19
0.67
ND
ND
ND
ND
0.29
1.02
ND
ND
0.38
ND
ND
4.77
124
TCB
D ND
ND
0.40
0.15
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.62
ND
ND
ND
ND
ND
ND
ND
ND
D ND
0.09
ND
0.16
ND
D ND
D 0.72
ND
ND
D 0.26
ND
ND
2.99
135
TCB
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
D 0.08
ND
ND
D ND
ND
ND
0.46
1234
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.01
D ND
ND
ND
ND
ND
ND
D ND
1235
TCB
ND
ND
ND
0.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
D 0.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.60
ND
0.56
0.93
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
D 0.75
5.01
ND
PO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
HCB
ND
ND
ND
ND
ND
ND
2.24
ND
4.82
ND
3.36
3.28
ND
ND
1.80
ND
ND
1.03
NO
ND
ND
8.70
ND
ND
ND
ND
ND
4.82
1.89
NO
ND
0.15
0.55
0.23
2.02
6.83
23.8
ND
aBHC
7.48
ND
ND
ND
ND
ND
D ND
ND
J ND
ND
ND
0.70
17.48
7.88
D ND
ND
ND
D 2.54
ND
ND
ND
ND
ND
ND
2.48
ND
ND
8.43
D ND
ND
ND
D 1.33
D ND
D ND
D ND
2.91
ND
2.82
gBHC
ND
ND
ND
ND
ND
0.74
ND
ND
3.54
ND
ND
D 0.75
2.67
5.66
ND
ND
ND
1.88
ND
ND
ND
ND
ND
ND
D 3.98
4.06
ND
7.78
0.84
ND
ND
D 0.39
ND
ND
ND
2.01
ND
ND
CIS
CHLOR
ND
ND
ND
ND
ND
D ND
2.61
ND
J 9.42
ND
7.24
D 2.43
10.76
5.19
13.9
ND
ND
D ND
44.5
1.08
ND
11.1
ND
0.23
ND
ND
ND
21.9
D ND
ND
ND
D ND
4.97
6.06
10.1
D 10.3
7.99
97.2
TRANS
CHLOR
ND
ND
ND
ND
NO
ND
1.98
ND
J ND
ND
2.77
D 0.87
20.85
2.45
8.82
ND
ND
ND
32.1
D ND
ND
ND
ND
D ND
ND
ND
ND
4.62
ND
ND
ND
ND
1.25
3.73
6.56
7.00
7.63
E 67.6
D
D
D
D
-------
XEN08IOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3285 DY022213 F
3286 DY02221S F
3287 DY022216 F
3288 DY022217 F
3288 DY022218
3289 DY022219
3289 DY022220
3290 OY022221
3290 OY022222
3294 DJ022112
3294 DJ022111
3294 DJ022113 H
3295 DJ022114 F
3296 DB040101
3297 DB041501
3298 DB041601
3298 08041604
3299 DB040601
3299 DB040604
3299 OD040601
3300 OB040201
3300 OB040204
3300 QD021389
3301 DB041101
3301 DB041104
3301 00030989
3302 DB041901
3302 DB041904
3303 DB042301
3303 DB042304
3303 00102588
3304 DB041001
3304 DB041004
3304 00041004
3305 DB042001
3305 DB042004
3305 OD110388
3306 DB041801
3306 DB041804
3306 QD041801
3307 DB042101
3308 OB040001
3309 OB041301
3310 OC032701
3310 DC032702
s
WB Diamond Turbot
UB Carp
UB Tilapia Zilli
PF Squaufish
UB Sucker
WP Bocaccio
UB Sculpin
PF Redear Sunflsh
UB Blackfish
PF Atlantic Salmon
UP True Cod
Mussel
UP Atlantic Salmon
UB White Sucker
UB Carp
UB Carp
PF Lm Bass
UB Uhite Sucker
PF Lm Bass
UB Sucker
UB Uhite Sucker
PF Sm Bass
UB Channel Catfish
UB Carp
PF Northern Pike
PF Northern Pike
UB Uhite Sucker
PF Lm Bass
UB White Sucker
PF Sm Bass
UB Uhite Sucker
PF Northern Pike
UB Uhite Sucker
UB Uhite Sucker
UB Channel Catfish
PF Sm Bass
UB Channel Catfish
UB Uhite Sucker
PF Sm Bass
UB Uhite Sucker
UB Uhite Sucker
PF Northern Pike
UB Uhite Sucker
UB Bullhead
PF Walleye
Here
M9/9
0.11
ND
ND
0.11
ND
0.02
NA
0.11
0.06
0.05
ND
0.00
0.05
0.05
0.03
0.00
0.32
0.08
0.11
0.10
0.14
0.08
0.17
0.12
0.25
0.17
1.19
0.48
0.20
0.14
0.32
0.11
0.72
0.17
0.48
0.13
ND
0.24
123
TCB
ND
ND
ND
0.17
ND
3.89
ND
ND
ND
0.19
0.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.40
0.25
ND
ND
ND
0.27
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.35
ND
1.95
1.58
124
TCB
ND
0.354
0.26
D ND
ND
2.26
0.12
ND
ND
D 0.17
D 0.24
ND
ND
1.06
2.16
ND
0.37
0.28
ND
ND
ND
ND
1.10
ND
ND
D 3.09
D 0.22
ND
ND
ND
D ND
ND
ND
1.58
ND
ND
0.19
ND
0.42
0.14
D 0.79
ND
D 11.0
D 2.46
J
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.32
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
1.78
0.76
ND
ND
ND
ND
0.17
0.13
ND
0.68
ND
ND
D 4.63
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1235
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.56
ND
ND
ND
D 0.97
D 0.75
ND
ND
ND
ND
D ND
D ND
ND
D 0.66
ND
ND
1.56
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.56
ND
ND
ND
D 0.97
D 0.75
ND
ND
ND
ND
ND
ND
ND
D 0.66
ND
ND
D 1.56
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
ND
NO
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
D ND
ND
0.94
N
ND
26.6
1.35
1.53
D 49.6
1.01
1.42
D 28.2
ND
ND
ND
ND
ND
3.23
5.38
32.8
ND
37.1
ND
ND
0.84
1.20
ND
ND
ND
ND
PCB
ND
1.08
ND
ND
ND
ND
ND
ND
0.80
ND
ND
ND
ND
6.11
5.82
ND
D 0.45
0.66
ND
2.05
D ND
D ND
5.99
D ND
D ND
8.37
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
PCI
ND
J ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HCB
ND
ND
ND
0.51
2.12
ND
0.33
ND
2.14
0.79
ND
ND
ND
9.43
8.54
ND
5.23
3.03
1.65
9.80
0.54
0.78
43.2
1.20
1.13
11.5
0.30
ND
ND
ND
ND
0.58
1.25
11.1
ND
12.7
0.86
ND
1.22
0.84
ND
0.91
ND
0.80
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
aBHC
ND
ND
ND
ND
ND
2.63
1.17
ND
2.54
2.64
0.65
ND
4.57
4.05
16.0
ND
0.84
0.90
0.39
3.42
ND
ND
7.85
ND
ND
3.42
ND
1.70
ND
2.67
ND
0.42
2.36
3.94
ND
6.63
1.77
0.72
2.87
0.97
ND
ND
NO
ND
D
D
D
D
D
D
D
0
D
D
D
gBHC
ND
5.59
6.94
ND
ND
ND
ND
ND
4.85
ND
0.63
ND
4.13
ND
ND
ND
ND
ND
ND
4.16
ND
ND
5.28
ND
ND
1.90
ND
ND
ND
1.83
ND
ND
ND
1.39
ND
ND
ND
ND
1.82
ND
ND
1.83
6.43
ND
CIS
CHLOR
37.4
J 43.4
3.83
ND
14.9
ND
1.48
ND
33.2
ND
D ND
ND
3.13
8.64
28.5
ND
2.99
1.64
3.57
14.6
1.08
0.93
32.9
1.53
1.86
D 10.3
0.60
ND
ND
D ND
ND
4.43
6.19
D 34.8
ND
38.5
1.94
ND
D 3.01
2.06
ND
D ND
12.2
3.20
TRANS
CHLOR
17.5
31.6
ND
2.48
8.90
ND
D 0.80
ND
17.3
ND
ND
ND
ND
4.55
18.1
ND
ND
D 0.32
ND
2.62
D ND
D ND
14.6
D ND
D ND
1.54
D ND
ND
ND
ND
ND
ND
ND
7.40
ND
8.23
D ND
ND
ND
D ND
ND
ND
8.07
5.16
-------
£
ex
Episode SCC
3311 DC032801
3311 DC032802
3312 DC033101
3312 DC033102
3313 DC033201
3313 DC033202
3314 DC033301
3314 DC033302
3315 DC033401
3315 DC033402
3316 DC033501
3317 DC033601
3318 DC033701
3319 DB041401
3320 DB041412
3321 DB040401
3321 QD 100688
3323 DB041206
3324 DB041252
3325 DB041218
3326 DB041208
3327 DB040301
3327 DB040315
3328 DD029111
3329 DDO 16003
3330 DD029110
3331 DD016007
3332 DDO 16009
3333 DD016012
3334 DD016013
3335 DD016015
3335 DD029101
3335 DD029102
3335 DD029103
3335 OD091588
3336 DD016004
3336 DDO 16006
3336 DD016017
3336 DD016018
3337 DD016019
3338 D0016022
3339 DD016023
3340 DD029114
3341 DD016104
3341 QD081788 1
Type Description
UB Redhorse Sucker
PF Sm Bass
UB Redhorse Sucker
PF Sm Bass
UB Redhorse Sucker
PF Sm Bass
F UB Channel Catfish
F PF White Bass
F UB Carp
PF Lm Bass
UB White Sucker
UB White Sucker
UB White Sucker
UP Winter Flounder
UP Bluefish
UP Winter Flounder
UP Winter Flounder
UP Winter Flounder
UP Bluefish
UP Bluefish
UP Bluefish
UP Bluefish
UP Bluefish
UB Carp
UB Boufin
UB Spotted Sucker
UB Carp
UP Spotted Drum
UB Sea Catfish
UB Sea Catfish
UP Spot
UP Red Drum
UB Southern Flounder
UP Sheepshead
UP Red Drum
UP Black Drum
UP Sheepshead
UP Red Drum
PF Spotted Seatrout
UB Spotted Sucker
UB Spotted Sucker
UB Carp
UB Channel Catfish
UB Catfish
. UB Catfish
XENOBIOTICS CONCENTRATIONS, ng/g
Merc
C9/9
0.10
0.08
ND
0.09
0.23
0.63
0.07
0.15
ND
0.18
0.07
ND
ND
0.01
0.11
0.02
NA
0.03
0.06
0.03
0.03
0.08
0.10
0.05
0.02
0.18
0.05
0.02
0.18
0.53
0.53
0.63
0.04
0.60
0.04
0.31
0.06
0.08
0.11
0.08
0.10
0.05
0.12
NA
123
TCB
0.22
0.47
ND
1.10
0.13
0.48
ND
0.26
ND
ND
0.15
ND
ND
ND
ND
0.48
0.95
0.10
4.56
0.26
0.80
2.27
2.69
ND
0.17
0.16
ND
ND
ND
ND
ND
ND
0.30
ND
ND
ND
ND
ND
0.10
1.44
0.70
3.16
0.42
ND
ND
0
D
D
D
F
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
124
TCB
0.68
0.80
ND
1.05
0.22
0.43
0.96
0.17
ND
ND
0.12
ND
ND
ND
ND
0.85
0.85
0.07
2.93
0.17
0.50
10.6
ND
0.52
0.35
0.29
ND
ND
ND
ND
0.49
0.12
0.28
ND
ND
ND
ND
ND
ND
2.09
ND
6.57
ND
ND
0.10
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
ND
ND
ND
0.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1234
TCB
0.14
0.16
ND
0.37
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.99
ND
ND
ND
1235
TCB
D 0.14
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.92
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.04
ND
ND
ND
1245
TCB
D 0.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.92
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.04
ND
ND
ND
DCS
D ND
ND
ND
ND
ND
ND
ND
0.73
ND
ND
0.67
ND
ND
ND
ND
ND
D 3.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.60
ND
ND
ND
PCS
0.34
ND
ND
0.33
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
1.56
ND
0.21
ND
0.09
ND
ND
ND
ND
0.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.57
ND
ND
ND
PCI
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
NO
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
HCB
1.99
1.18
ND
ND
ND
ND
6.39
1.94
ND
ND
0.46
ND
ND
ND
0.48
ND
2.58
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.72
ND
ND
ND
ND
ND
ND
ND
2.61
ND
ND
ND
aBHC
D 0.50
D ND
ND
2.57
ND
ND
ND
D ND
ND
ND
D ND
8.11
ND
1.69
D 0.76
2.50
5.01
D 0.60
2.33
ND
1.51
1.98
ND
ND
0.85
ND
2.09
ND
ND
5.84
0.61
ND
D ND
ND
ND
ND
ND
ND
ND
10.6
0.85
ND
6.13
1.25
gBHC
D ND
ND
ND
ND
ND
ND
ND
0.97
ND
ND
0.91
ND
ND
0 0.84
D ND
ND
1.70
D 1.41
D 1.53
0.81
D ND
D 0.39
ND
ND
D 0.64
ND
D ND
ND
ND
2.59
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
20.8
ND
D ND
CIS
CHLOR
15.3
1.40
48.9
4.88
8.42
0.73
112
D 17.1
16.1
ND
D 2.61
ND
ND
D 14.5
4.12
24.0
D 27.0
D 19.4
D 12.3
D 7.01
11.4
D 8.40
ND
8.16
ND
D ND
ND
ND
1.35
10.5
ND
0.46
ND
ON
ND
ND
ND
ND
0.69
ND
ND
27.7
ND
6.43
6.07
TRANS
CHLOR
8.77
D 3.46
30.5
10.65
4.33
D 2.03
90.7
6.70
9.59
ND
1.16
ND
ND
5.16
1.42
11.3
10.8
5.49
8.15
4.20
6.10
4.84
5.36
ND
2.10
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
D ND
ND
4.63
17.2
ND
1.30
ND
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC Type Description
3342 DD016105
3343 DD016107
3344 DD016110
3344 DD016109
3345 DD016111
3346 DD016113
3346 DD016114
3347 DD016115
3348 DD016117
3348 DD016118
3349 DD016119
3350 DD016121
3350 DD016122
3351 DD016124
3352 DF023723
3352 DF023724
3352 00022089
3353 DF024121
3353 DF024122
3354 DY022301
3354 DY022302
3355 DY022303
3355 OY022304
3356 DE030201
3357 DY022223
3357 DY022224
3360 DD029117
3375 D0016305
3375 DD016306
3375 QD071189
3376 DD016307
3376 DD016308
3377 DD016309
3377 DD016310
3378 00016311
3378 DD029115
3385 DD016401
3385 00101888
3395 DD016421
3401 DD016509
3401 00016510
3403 00016513
3403 DD016514
3404 00016515
3404 00016515
WB Spotted Sucker
WB White Sucker
PF Lm Bass
WB Carp
WB Redhorse Sucker
WB Creek Chubsucker
PF Lm Bass
WB Carp
PF White Perch
WB Blue Catfish
WB Carp
WB Carp
PF Lm Bass
WB Carp
PF Crappie
WB Carp
PF Crappie
BF Blue Catfish
WB Sm Buffalo
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Squawfish
WB Sacramento Sucker
WB Carp
WB Carp
PF Lm Bass
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
WB Spotted Sucker
WB Greyfin Sucker
WB Redhorse Sucker
WB Redhorse Sucker
WB Redhorse Sucker
WB Carp
PF Lm Bass
WB River Carpsucker
PF Lm Bass
WB Carp
WB Carp
Here
P9/9
0.18
NO
0.26
0.23
0.87
0.03
0.32
0.07
0.25
0.12
0.12
0.08
0.65
0.07
0.17
0.09
0.32
O.H
0.07
0.11
0.03
0.28
0.04
0.95
0.10
0.07
0.08
0.31
0.09
0.34
0.07
0.20
0.07
0.07
0.17
NA
0.24
0.13
0.42
0.10
0.21
0.07
123
TCB
3.92
0.52
0.37
ND
0.26
ND
5.20
0.08
ND
ND
ND
ND
ND
0.17
ND
0.41
ND
ND
ND
ND
ND
ND
ND
ND
1.83
19.4
0.38
0.55
26.8
0.24
4.03
0.54
8.16
4.38
NO
ND
ND
ND
0.07
1.14
0.29
ND
0.97
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
124
TCB
7.58
ND
0.50
ND
0.16
ND
9.01
ND
ND
ND
ND
ND
ND
ND
ND
0.28
ND
ND
ND
ND
0.34
ND
1.30
ND
1.20
17.0
0.38
0.61
16.1
0.24
2.58
0.40
4.77
2.80
ND
ND
ND
0.51
0.08
1.05
0.17
ND
0.62
D
D
D
D
D
D
D
D
D
D
D
D
D
D
D
135
TCB
ND
ND
ND
ND
ND
ND
0.06
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.35
ND
ND
0.04
0.79
ND
ND
ND
ND
0.25
ND
14.9
0.78
ND
ND
1234
TCB
0.88
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
D ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
1235
TCB
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
0.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
DCS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.30
4.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PCB
ND
ND
ND
ND
ND
ND
ND
ND
0.12
ND
ND
NO
ND
ND
0.25
ND
ND
ND
ND
ND
1.02
ND
D 0.83
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
PCI
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
HCB
ND
ND
2.08
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.59
ND
0.30
ND
ND
ND
1.38
ND
2.92
ND
ND
11.5
ND
ND
0.90
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.70
0.14
2.31
ND
ND
ND
aBHC
ND
9.58
D 4.01
ND
ND
ND
ND
ND
ND
2.79
ND
ND
D ND
ND
D 1.13
ND
1.10
2.33
D ND
ND
1.66
ND
6.34
ND
ND
ND
D ND
ND
ND
ND
ND
1.02
3.05
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
gBHC
25.7
4.66
6.75
0.98
3.35
0.16
ND
ND
4.62
ND
ND
ND
ND
ND
D 1.14
ND
D 0.58
D 2.04
8.42
ND
D ND
ND
ND
21.3
2.37
21.9
ND
0.71
18.5
ND
21.9
D 1.56
ND
4.98
1.35
1.11
ND
ND
0.39
3.24
ND
ND
0.50
CIS
CHLOR
ND
ND
ND
D 2.18
ND
D ND
25.3
ND
ND
ND
ND
1.29
ND
ND
D ND
ND
D 6.14
D ND
ND
ND
57.9
ND
43.8
27.0
D 16.2
145
2.01
D 4.53
185
1.57
177
D 2.58
ND
ND
D 13.2
D 10.5
46.5
13.4
D 0.43
64.4
3.86
13.1
D 12.9
TRANS
CHLOR
32.8
2.55
11.9
D 1.42
ND
ND
20.1
ND
ND
7.98
ND
D ND
9.72
ND
2.40
ND
3.37
3.25
6.46
ND
32.0
ND
25.8
16.8
10.9
155
D 6.40
13.26
E 191
D 2.92
159
5.03
ND
ND
8.06
6.17
32.0
8.38
D ND
30.0
1.55
8.75
8.77
-------
XENOBIOT1CS CONCENTRATIONS, ng/g
Episode see Type Description
3409 DB005101
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907
3414 DC036203
3414 DC036204
3415 DC036205
3415 DC036206
3419 DC036207
3419 DC036208
3420 DC036209
3420 DC036210
3421 DC036211
3421 DC036212
3422 DC036213
3422 DC036214
3423 DC036216
3424 DC036218
3425 DF02500S
3426 DB069102
3427 DB069103
3428 DB069104
3429 DB069105
3430 DB069106
3431 DB069109
3433 DB069112
3434 DB040801
3434 QD011889 1
3435 DD016602
3443 DF009118
3444 DD016603
3444 DD016604
3444 DD029512
3445 DD029513
3446 DD01660S
3446 DD016606
3446 QD091889
UB Catfish
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
UB Uhite Sucker
PF Freshwater Drum
PF Greenfish
UB Carp
PF Uhite Perch
UB Carp
PF Lin Bass
UB Yellow Bullhead
UB Uhite Catfish
UB Uhite Catfish
UB Carp
PF Bluefish
PF Bluefish
PF Bluefish
PF Ueakfish
UB Uhite Catfish
UB Red Snapper
UP Flounder
UP Flounder
. UP Flounder
: UB Bigmouth Buffalo
: UB Carp
: UB Carp
: PF Channel Catfish
; PF Lm Bass
: UB Flounder
: PF Striped Bass
: UB Carpsucker
: UB Carpsucker
Here
C9/9
0.1
0.06
0.26
0.04
0.22
0.21
0.31
0.09
0.22
0.29
0.02
0.20
0.07
0.03
0.05
0.01
0.73
0.46
0.07
0.03
0.03
0.20
0.28
0.19
0.11
0.08
0.15
0.05
0.04
0.05
0.422
0.05
0.08
0.28
0.04
0.39
0.02
123
TCB
0.35
ND
1.93
ND
ND
5.34
2.19
0.14
1.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.41
17.7
0.64
0.18
NO
ND
0.47
0.27
0.68
ND
ND
ND
ND
ND
ND
ND
0.11
124
TCB
D 0.62
ND
D 80.4
ND
5.11
3.12
D 1.06
D ND
D 0.83
ND
ND
ND
ND
ND
ND
0.22
ND
ND
ND
ND
D 1.35
11.9
D 0.72
D 0.15
ND
ND
D 1.42
D 1.00
D 2.31
ND
ND
ND
ND
0.30
0.13
0.22
D 0.19
135
TCB
D ND
ND
0.95
ND
ND
0.55
D ND
ND
D ND
ND
ND
ND
NO
ND
ND
D ND
ND
ND
ND
ND
D ND
1.70
D ND
D ND
ND
ND
D ND
D ND
D ND
ND
ND
0.35
ND
0 ND
D ND
D ND
D ND
1234
TCB
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
1235
TCB
0.22
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1245
TCB
D 0.22
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DCS
D ND
ND
ND
1.51
29.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.95
ND
ND
1.09
2.93
3.30
PCS
0.47
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.90
1.87
1.90
ND
ND
D ND
ND
ND
PCNB
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HD
ND
0.86
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
HCB
2.53
ND
3.91
0.58
11.5
ND
ND
ND
ND
2.14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
44.1
7.24
10.7
0.85
ND
1.09
0.94
6.44
aBHC
2.47
ND
ND
D 0.73
ND
ND
3.63
ND
1.43
D 4.65
ND
0.39
ND
ND
3.80
ND
ND
0.85
ND
3.37
1.13
ND
ND
ND
ND
ND
1.15
ND
4.04
ND
ND
ND
D 0.73
ND
D ND
4.97
ND
gBHC
D 8.00
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
D 0.37
ND
ND
ND
ND
ND
D 1.11
1.25
2.67
ND
ND
ND
D ND
0.31
ND
1.41
1.35
CIS
CHLOR
37.3
ND
ND
1.72
42.6
ND
6.34
ND
9.54
1.63
ND
ND
ND
ND
ND
ND
ND
6.17
ND
ND
D 2.81
5.18
8.36
ND
3.97
ND
D 11.5
D 13.0
10.6
173
86.8
113
7.66
D ND
5.77
D 10.3
D 11.3
TRANS
CHLOR
22.8
ND
ND
D ND
17.8
ND
4.56
ND
6.39
D 5.75
1.92
ND
ND
ND
ND
ND
ND
1.89
ND
ND
1.35
1.91
3.61
ND
2.13
ND
4.84
6.72
5.77
206
85.0
E 126
12.9
ND
23.9
20.5
22.1
D
D
D
D
D
E
-------
Key for Xenobiotic Data Table (Units = ng/g) (continued)
Set 2 CAS Number
OXYCHLOR = Oxychlordane 26880/48/8
cisNON = cisNonachlor 3732/49/4
trans NON = trans Nonachlor 39765/80/5
HEFT = Heptachlor 76/44/8
HEPTEP = Heptachlor epoxide 1024/57/3
DDE = p.p'DDE 72/55/9
DIELDRIN 60/57/1
ENDRIN 72/20/8
DICOFOL = Dicofol (Kelthane) 115/32/2
MECHL = Methoxychlor 72/43/5
PERTHANE 72/56/0
MIREX 2385/85/5
NITROFEN 1836/75/5
CHLORPYRIFOST 2921/88/2
ISOPROP = Isopropalin 33820/53/0
DATA FLAGS
D = Value below limit of quantitation for all Xenobiotics except Mercury and PCBs,
D = 2.5 ng/g
For Polychlorinated Biphenyls
Number of Chlorines D( ng/g
1-3 1.25
4-6 2.50
7-8 3.75
9-10 6.25R
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate
samples (those starting with a Q) and confirmation samples (those starting with an S). The
number of samples shown on the summary tables in Volume I do not included the duplicate
and confirmation samples.
D-5-19
-------
D-5-20
-------
Episode SCC Type Description
XEN08IOTICS CONCENTRATIONS, ng/g
2015 DF001001
2016 DF001101
2017 DF001201
2018 DF001301
2023 DF001403
2026 DF001702
2027 DF001803
2037 DY000501
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 DJ000902
2098 DH001501
2100 DH001703
2105 DH002204
2109 DH002601
2110 DH002710 1
2122 DH003904 1
2126 DD000302 f
2133 DD001002 1
2139 DD001601 1
2142 DD001902 1
2148 DD002501 1
2151 DD002803 1
2152 DD002903 1
2190 DG005101
2190 DG005104
2191 DG005205
2194 DG005501
2199 DG006001
2199 DG006004
2201 DG006201
2205 DG006601
2210 DC005401
2211 DC005503
2212 DC005602
2212 DC005605
2215 DC005902 1
2216 DC006003 1
2220 DC006405 f
V-
to
F WB
F WB
F WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
WB
: WP
' WB
: WB
: BF
: WB
: WB
: WB
: WB
' WB
WB
PF
WB
WB
WB
PF
WB
WB
WB
WB
PF
WB
WB
' WB
' WB
Carp
Sucker
Carp
Sucker
Carp
Carp
Carp
not available
Carp
Carp
Carp
Carp
Longnose Sucker
N/A
Catfish
Carp
N/A
Brown Trout
White Sucker
Carp
Blue Catfish
Carp
Catfish
Saltwater Catfish
Spotted Sucker
Lake Chubsucker
Carp
Bluegill
Carp
Carp
Carp
Lm Bass
Carp
Carp
Catfish
Redhorse Sucker
Sm Bass
White Sucker
Carp
White Sucker
Catfish
OXY
NO
ND
NO
ND
ND
ND
ND
ND
ND
28.5
ND
19.1
NO
NO
ND
ND
12.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
36.0
NO
ND
28.8
ND
9.94
ND
ND
5.62
4.26
4.09
25.3
91.4
NO
NO
CIS
CHLOR
22.6
ND
ND
ND
ND
6.14
ND
ND
30.4
31.2
25.5
27.7
ND
ND
8.56
ND
ND
ND
ND
ND
ND
ND
20.5
ND
ND
ND
14.6
ND
17.8
23.3
9.67
12.6
NO
NO
52.0
5.57
6.57
42.5
124
ND
ND
TRANS KEPT
NON
61.7
18.1
2.49
8.66
4.96
16.1
3.85
3.18
82.9
89.1
74.6
77.4
ND
ND
25.2
ND
17.6
ND
3.31
9.23
6.17
ND
36.8
11.1
ND
ND
39.7
ND
56.2
73.6
26.3
36.4
2.38
ND
158
15.6
22.9
142
477
ND
7.07
NON
ND
ND
D NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.79
ND
ND
0 ND
ND
ND
ND
ND
E ND
E 19.6
ND
ND
HEPT
EP
6.34
ND
ND
ND
ND
ND
ND
ND
ND
15.0
16.0
23.2
ND
ND
ND
ND
24.4
ND
ND
3.77
ND
ND
ND
ND
ND
ND
63.2
ND
ND
32.7
19.1
7.91
ND
ND
15.7
NO
1.07
NO
21.9
ND
ND
DDE
471
1223
66.7
ND
30.5
252
64.4
0.51
38.7
64.6
769
46.5
2.89
5.04
187
2.57
62.8
5.61
18.9
474
659
4.95
75.1
34.4
8.97
10.4
56.2
4.61
52.3
41.8
70.0
48.8
19.2
22.3
381
88.8
52.1
186
122
2.04
19.6
DIELDRIN ENDRIN D1COFOL ME PER
E
E
E
D
E
E
E
E
E
E
E
E
E
D
73.7
ND
ND
ND
1.70
ND
ND
NO
58.5
110
81.2
153
ND
NO
18.1
NO
108
ND
7.64
18.2
15.4
NO
21.9
7.36
ND
ND
224
14.7
258
60.8
312
70.4
8.79
7.94
73.1
8.45
4.92
112
128
NO
NO
ND
ND
ND
ND
D 3.73
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
7.50
ND
E ND
E ND
ND
ND
9.02
ND
ND
E 2.25
ND
ND
ND
ND
0.61
ND
ND
ND
0.26
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
0.79
ND
ND
5.37
ND
4.09
ND
ND
4.56
2.32
1.23
0.66
ND
NO
ND
ND
ND
D 0.64
6.02
ND
ND
CHL
ND
D ND
ND
ND
ND
D ND
ND
ND
8.22
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.81
D ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.04
D ND
D ND
ND
ND
4.82
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
PERTHANE MIREX
NITROFEN CHLOR ISOPROP
PYRIFOS
ND
4.24
21.6
ND
ND
ND
ND
ND
2.07
ND
6.22
0.76
ND
ND
1.30
ND
ND
ND
ND
23.1
3.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.24
2.31
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
0 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.4
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
3.21
1.82
ND
ND
ND
5.61
ND
10.4
ND
ND
19.4
ND
ND
ND
ND
23.9
ND
ND
7.66
26.3
ND
ND
ND
ND
ND
ND
ND
8.65
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIH ENDRIN DICOFOL HE
EP CHL
PERTHANE H1REX
NITROFEN CHLOR ISOPROP
PYRIFOS
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.3
10.6
18.5
ND
ND
ND
18.3
ND
55.4
68.0
ND
36.9
63.2
57.6
ND
ND
ND
ND
ND
243
ND
ND
ND
ND
ND
ND
33.7
ND
ND
ND
ND
ND
16.5
ND
ND
ND
ND
ND
12.7
ND
ND
ND
42.3
24.6
47.2
ND
ND
ND
12.2
ND
35.1
65.7
ND
61.9
59.9
50.0
ND
ND
ND
ND
ND
ND
14.9
ND
ND
ND
3.61
ND
96.7
10.5
8.20
4.12
4.34
ND
53.3
ND
11.0
ND
2.06
3.40
37.2
14.9
2.12
ND
129
60.3
151
2.81
ND
8.27
38.5
2.18
96.9
172
ND
279
197
167
2.46
63.4
3.63
83.9
8.21
58.3
37.8
ND
1.38
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
E ND
ND
e ND
ND
ND
ND
ND
D ND
ND
ND
ND
E ND
E ND
E ND
D ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
8.84
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.92
5.06
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.3
26.1
ND
ND
ND
ND
ND
ND
52.8
ND
ND
ND
ND
29.8
1.09
151
41.9
21.6
45.9
46.9
5.79
94.0
371
18.8
186
14.2
53.9
337
217
15.9
9.63
682
415
56.1
14.9
3.02
63.0
39.0
6.62
497
997
10.9
114
86.6
73.4
19.6
579
15.3
115
108
1521
640
12.6
11.7
7.73
4.34
D ND
49.6
ND
ND
ND
ND
ND
21.1
E 14.5
ND
E ND
ND
E ND
E 38.0
E ND
1.29
3.76
E 53.5
E 47.3
83.7
9.73
ND
16.3
25.6
ND
E 105
114
ND
90.0
73.0
68.3
6.17
E 99.0
4.30
64.2
21.5
E 168
E 4.60
ND
ND
2.48
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
4.19
ND
ND
ND
ND
ND
ND
ND
ND
5.91
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
NO
ND
ND
0.47
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.88
2.82
ND
ND
ND
ND
1.78
ND
ND
3.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
N
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.03
0.85
ND
ND
7.89
ND
ND
ND
0.89
7.13
6.39
ND
ND
225
131
ND
ND
ND
ND
ND
ND
2.81
8.63
ND
ND
ND
ND
0.45
3.98
ND
ND
ND
2.46
3.21
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
E 3.39
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
6.49
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.95
ND
ND
ND
ND
ND
4.66
ND
26.4
33.0
ND
18.2
21.5
11.2
ND
9.44
ND
46.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
XENOBIOTICS CONCENTRATIONS, ng/g
Episode SCC
2432 DE010710
2435 DE011001
2437 DEO 11 203
2439 DE011401
2439 DE011402
2478 DJ003902
2500 DCO 10203
2532 DF019303
2544 DF019202
2608 DE014504
2618 DE015401
2618 DE015402
2618 DE015403
2651 DB008401
2653 DB008503
2654 DB008601
2709 DB005101
2721 DA006502
2721 0001 1089
2722 DA006601
2725 DA006301
2748 DY006505
2776 DY007101
2776 ODD 10489
3001 DE019502
3022 DA008401
3023 DA008501
3024 DA008601
3025 DA008701
3028 OAOOS801
3034 DG025701
3035 DG025801
3036 DG025902
3037 DG026001
3038 OG026101
3039 DG026201
3040 DG026301
3041 DG026402
3042 DG026501
3042 DG026502
3042 OD026501
3043 DG026601
Type Description
UB Redhorse Sucker
UB Longnose Sucker
UB Carp
UB Carp
UP Sm Bass
UB Sucker
UB Black Buffalo
UB Carp
UB Blacktail Redhorse
UB Carp
UB Carp
BF Carp
UB Ouillback
UB White Sucker
UB Carp
UB Carp
UB Catfish
UB Sucker
UB Sucker
UB Sucker
UB Sucker
UB Sucker
UB Carp
UB Carp
UB White Sucker
UB White Sucker
PF Sm Bass
PF Lm Bass
UB White Sucker
PF Chain Pickerel
UB Carp
UB Carp
UB Carp
UB Carp
UB Carp
UB Carp
UB Carp
UB Carp
UB Carp
PF Northern Pike
UB Carp
BF Flathead Catfish
OXY
17.9
4.64
ND
77.0
37.7
ND
ND
ND
ND
ND
96.2
24.3
68.9
1.45
16.4
9.34
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
13.5
ND
3.91
ND
28.0
1.17
ND
4.08
ND
ND
ND
CIS
CHLOR
19.6
10.0
ND
54.8
48.3
ND
ND
12.5
ND
ND
57.7
19.3
51.2
D 7.04
38.4
37.25
20.8
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
5.29
12.3
9.88
6.69
ND
44.1
D 8.37 E
ND
ND
ND
18.8
11.3
TRANS
NON
58.6
20.4
10.9
147
173 E
4.53
7.15
30.7
15.3
ND
197
66.1
164
17.2
138 E
65.61
57.2
ND
ND
ND
ND
NO
3.14
5.42
ND
ND
ND
ND
11.1 E
ND
ND
47.9
ND
20.1
ND
133 E
23.4 E
2.07 0
84.6
2.33 0
50.7
ND
HEPT
NON
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.84
ND
ND
ND
HEPT
EP
ND
11.4
ND
20.8
16.8
NO
NO
12.4
ND
ND
28.6
8.16
ND
ND
6.57
8.07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.64
22.4
ND
19.9
ND
14.5
ND
1.03
ND
ND
ND
ND
DDE
516
114
128
109
80.9
197
6.98
73.8
25.3
64.4
77.6
23.2
65.2
89.0
177
59.92
223
20.6
13.8
3.01
10.6
31.1
58.7
101
27.6
14.0
2.18
118
18.6
ND
39.2
258
72.0
103
70.3
185
555
374
165
12.0
108
85.8
DIELDRIN
E ND
E 55.8
58.6
99.8
103 E
E ND
3.99
99.5
38.2
35.0
128
47.3
88.5
E 6.90
E 23.8
19.25
E 14.9
ND
ND
ND
ND
ND
E ND
E ND
ND
ND
0 ND
E 46.0
E 3.68 E
ND
35.5
E 160 E
323 E
E 136 E
ND
E 36.0
E 24.6 E
E 74.3 E
E 61.3
1.58 D
55.8
79.3
ENDRIN
ND
13.4
ND
ND
ND
ND
ND
7.45
ND
ND
35.1
12.9
6.30
ND
ND
ND
ND
8.55
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
4.52 E
ND
ND
ND
ND
ND
ND
ND
ND
4.97
ND
ND
ND
NO
DICOFOL
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
2.17 0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.57
ND
ND
ND
ND
ND
ND
ME
CHL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.50
ND
ND
ND
ND
ND
ND
ND
ND
NO
PER
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERTHANE MIREX NITROFEN CHLOR ISOPROP
PYRIFOS
1.03
0.44
ND
ND
ND
ND
1.73
1.16
2.63
ND
ND
NO
ND
0.97
5.90
ND
2.21
4.77
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
ND
ND
ND
1.03
ND
ND
ND
ND
0.39
NO
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
D ND
ND
10.40
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.3
ND
1.50
ND
ND
ND
17.8
5.55
ND
2.91
4.59
ND
3.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.46
4.53
5.13
ND
12.4
0.81
ND
30.1
1.62
40.8
5.44
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
2.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
0 ND
15.0
ND
ND
ND
D 2.82
ND
13.4
D ND
25.9
37.5
-------
Episode SCC Type Description
3044 DG026701
3045 DG026801
3045 DG026802
3046 OG026901
3047 DG027001
3048 OG027101
3048 DG027102
3048 ODD12689 L
3048 OD027101
3049 DG027201
3050 DG027301
3060 DF009101
3060 DF009102
3060 OD073189
3061 OF019106
3062 DF024024
3063 DF023301
3063 OF023302
3064 DF023305 N
3065 DF023419
3065 DF023420
3065 00010788
3066 DF023503
3066 DF023504
3068 DF024001 N
3068 DF024002
3069 DF024007
3069 OF024008
3069 QD051788
3070 DF024009
3070 DF024010
3071 DF0240U
3071 DF024015
3072 DF024017
3072 OD070688
3073 DF019221
3074 DF026017
3076 DF028502
3077 DF0191U
3078 DF009118
3078 DF023815
3078 DF023816
F UB Carp
F UB Carp
F BF Flathead Catfish
F WB Bigmouth Buffalo
F WB Carp
F UB Carp
F PF White Bass
PF White Bass
L UB Carp
F UB Carp
F UB Bigmouth Buffalo
F UB Flathead Catfish
F UB Sin Buffalo
L UB Flathead Catfish
F UB Sucker
F UB Blue Catfish
F UB Sea Catfish
F PF Spotted Seatrout
Shellfish
F BF Bigmouth Buffalo
F UB Flathead Catfish
F BF Bigmouth Buffalo
F UB Catfish
F PF Freshwater Drum
Oysters
F PF At I. Croaker
F UB Sea Catfish
F PF Trout
F UB Sea Catfish
F UB Croaker
F PF Sheepshead
F UB Carp
F PF Longnose Gar
F UB Carp
L UB Carp
F UB White Sucker
F PF Broun Trout
F UB Channel Catfish
F UB Redhorse Sucker
F UB Carp
F UB Sm Buffalo
F PF Black Crappie
XEN08IOTICS CONCENTRATIONS, ng/g
OICOFOL ME
CHL
ND
HO
HO
m
m
NO
0.30
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
OXY
8.44
42.3
2.53
6.95
NO
19.6
2.27
1.94
18.6
10.1
6.75
ND
NO
ND
2.23
ND
2.79
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
61.5
NO
ND
ND
ND
NO
ND
ND
1.85
ND
CIS
CHLOR
20.4
59.6
7.31
8.02
ND
64.6
D 5.42
D 4.98
38.1
37.6
8.92
ND
9.19
ND
D ND
ND
8.66
3.60
ND
ND
4.97
ND
7.74
1.75
ND
5.18
5.56
ND
ND
ND
ND
82.09
66.04
ND
ND
ND
ND
ND
ND
ND
D 11.3
ND
TRANS
NON
NO
186 E
22.3
20.7
NO
225 E
12.9
11.8
97.5
ND
23.9
ND
21.47
ND
ND
20.3
20.1
7.55
3.77
4.24
10.6
7.28
16.3
ND
ND
10.4
9.98
ND
15.8
4.44
ND
104.14
172.05E
6.55
4.47
ND
ND
7.10
ND
6.72
45.9
2.89
HEPT
NON
4.43
9.74
2.09
ND
ND
3.63
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HEPT
EP
10.9
24.1
D 2.26
10.6
ND
17.6
4.15
3.88
17.0
16.6
9.34
ND
ND
ND
2.26
ND
ND
ND
ND
ND
ND
ND
9.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.21
ND
DDE
133 E
166 E
23.4
36.4
ND
67.1
13.1
11.6
32.0
206 E
30.6
21.99
447. 57E
14.87
5.93
271 E
41.5
8.54
3.17
18.8
29.1
31.3
39.6
9.49
16.8
12.2
51.2
3.33
69.7
6.80
0.56 D
154. 75E
302. 29E
545 E
416 E
7.79
43.0
55.1
6.39
2425 E
152 E
51.1 E
DIELDRIN
116 E
107 E
18.5
216 E
ND
190 E
26.2
25.3
92.8
201 E
125
ND
ND
ND
4.18
8.33
12.4
5.91
ND
3.61
6.44
4.95
61.5
8.28
ND
13.4
5.38
ND
5.71
ND
ND
53.11
89.36
ND
ND
2.20 D
ND
ND
ND
ND
30.6
4.78
ENDRIN
ND
7.37
ND
ND
ND
18.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.52
ND
ND
ND
ND
ND
0.64 D
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Oil
ND
ND
ND
N
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
PERTHANE HI REX NITROFEN CHLOR 1SOPROP
PYRIFOS
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.17
ND
2.03
0.88
ND
0.33
0.51
0.42
ND
ND
ND
ND
0.35
ND
ND
ND
ND
ND
4.19
ND
ND
ND
0.94
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
D ND
ND
D ND
D ND
ND
D ND
D ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
9.04
17.8
6.12
ND
ND
12.1
ND
ND
12.3
4.37
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.81 D
ND
3.11
ND
ND
ND
ND
ND
ND
ND
ND
63.68
11.78
1.83 D
2.10 D
ND
ND
ND
ND
ND
5.68
0.82 D
10.5
6.53
ND
ND
16.5
5.92
ND
ND
ND
13.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
KEPT DOE DIELDRIN ENDRIN DICOFOL ME
EP CHL
PERTHANE MIREX NITROFEN CHLOR ISOPROP
PYR1FOS
3079 DF019205
3079 DF019206
3080 DF023317
3080 DF023318
3081 DF024105
3081 DF024106
3082 DF023401
3083 DF023406
3084 DF024109
3085 DF024113
308S OF024114
3086 DF023409
3086 DF023410
3087 OF023413
3087 DF023414
3087 OF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 OF019210
3090 DF019213
3090 DF019214
3091 DF019217
3092 DF023501
3092 DF023502
3093 DF024011
3093 DF024118
3094 DC017201
3095 DC038801
3095 DC038802
3096 DC035001
3096 DC035002
3097 DC038701
3097 DC038702
3097 OD071989
3098 OC038601
3098 DC038602
3098 OD051288
3100 DC019701
3101 DC019901
3103 DC036201
3103 DC036202
I
PF White Bass
UB Carp
UB Carp
PF Lm Bass
PF White Bass
UB Catfish
UB Carp
PF Lm Bass
UB Channel Catfish
UB Sea Catfish
PF Black Drum
UB Catfish
PF Red Drum
UB Carp
PF White Crappie
UP Bluegill
UB Channel Catfish
PF Bluegill
PF White Crappie
UB Carp
PF White Crappie
UB Channel Catfish
UB River Carpsucker
UB Carp
PF Yarmouth
PF Lm Bass
UB Sm Buffalo
BF Channel Catfish
BF Brown Bui Ihead
UB Channel Catfish
BF Broun Bui Ihead
UB Channel Catfish
BF Brown BuiIhead
UB Carp
PF Brown Bullhead
UB White Sucker
PF American Eel
UB White Sucker
PF White Perch
PF Brown Trout
UB Channel Catfish
UB Carp
NO
NO
2.27
NO
ND
ND
ND
ND
6.59
ND
ND
3.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.48
ND
ND
ND
ND
ND
ND
ND
11.7
ND
21.5
ND
ND
ND
ND
7.29
ND
ND
5.53
ND
ND
5.19
7.44
D 13.2
ND
NO
ND
ND
ND
34.6
ND
ND
18.8
ND
ND
ND
ND
ND
ND
ND
1.58
ND
13.8
ND
ND
ND
ND
ND
34.5
8.64
40.6
5.80
65.6
3.76
ND
2.44
ND
1.95
ND
4.52
0.22
26.25
ND
24.86
18.3
31.9
ND
2.54
ND
7.87
ND
70.4
ND
ND
53.8
ND
ND
ND
2.29 0
ND
ND
ND
D 3.17
1.12 D
28.9
0.98 D
ND
ND
ND
1.29 D
106
30.8
126
3.70
162 I
5.42
7.65
5.45
ND
19.0
ND
11.88
12.9
40.69
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.87
3.40
4.29
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.80
ND
2.87
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.10
ND
ND
1.18
ND
ND
23.21 9.96
32.4 8.44
298 E ND
10.66 ND
10.3 0.62
4.40 ND
2199 E ND
93.2 ND
3221 E 66.4
86.8 ND
14.97 ND
48.6 25.1
ND ND
38.4 ND
8.92 ND
35.8 ND
6.89 ND
2.09 D ND
2.46 D ND
20.8 3.97
1.48 D ND
52.7 9.89
33.1 0.51
40.93 8.34
0.81 D ND
0.76 D ND
5.51 ND
984 E 83.5
322 20.3
2329 E 64.9
34.38 6.89
1189 E ND
77.72 ND
114 ND
70.09 ND
224 E ND
D 551 E 11.7
284 E ND
18.81 7.47
D 18.8 13.1
164.92 7.69
152 ND
ND
2.51
ND
ND
D ND
ND
ND
ND
18.0
ND
ND
1.65
ND
4.0
ND
ND
ND
ND
ND
ND
ND
ND
D ND
12.25
ND
ND
ND
ND
NO
ND
ND
ND
ND
5.63
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.70
ND
ND
ND
0.76
4.05
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.4
ND
3.69
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.13
ND
ND
ND
1.81
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
3.40
ND
ND
5.21
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.12
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
42.4
ND
0.34
0.71
10.4
ND
ND
ND
ND
2.45
ND
0.99
ND
0.68
3.68
ND
ND
0.52
ND
0.57
ND
0.71
ND
ND
0.29
ND
ND
ND
3.01
1.88
0.21
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
D ND
ND
ND
ND
D ND
ND
D ND
ND
0 ND
ND
ND
D ND
ND
ND
ND
ND
D NO
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.57
1.61
17.5
ND
ND
ND
ND
ND
20.6
ND
ND
ND
NO
ND
NO
NO
NO
ND
ND
ND
ND
1.82
ND
ND
ND
ND
ND
19.8
8.95
19.4
2.50
23.0
ND
ND
ND
MD
2.09
ND
ND
ND
1.96
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
-------
I
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
KEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE M1REX
NITROFEN CHLOR
PYRIFOS
ISOPROP
3104 DC020001
3104 DC020002
310S DF025001
3105 DF025002
3106 DE026801
3107 DE026901
3108 DE027001
3108 DE027002
3109 DE025001
3110 DE022501
3110 DE022S02
3111 DH015802
3112 DE022401
3112 DE022402
3113 DE021101
3113 DE021102
3113 OD030789
3114 DE021201
3115 DE021301
3115 OE021302
3115 00101689
3117 DE021501
3118 DE021601
3118 DE021602
3118 DE021603
3118 QD010689
3118 QD020488
3120 DE021801
3120 DE021802
3122 DE022001
3122 OE022003
3125 DE022301
3125 DE022302
3132 OE023201
3132 00010588
3134 DE023403
3134 OE023405
3134 DE023406
3135 DE023501
3136 DE023601
PF Lm Bass
UB Carp
UB Carp
PF Lm Bass
PF Walleye
UB Carp
PF ualleye
UB Carp
UB Carp
BF Flat head Catfish
BF Carp
UB Silver Redhorse
UB Carp
PF Ualleye
BF Channel Catfish
BF Carp
BF Channel Catfish
BF Carp
UB Carp
PF Catfish
UB Carp
PF Lake Trout
PF Ualleye
UB Carp
UB Carp
UB Carp
PF Ualleye
UB Carp
PF Bass
UB Carp
UB Redhorse Sucker
UB Carp
PF White Bass
UB Carp
UB Carp
UB Carp
UB Carp
UB Sucker
UB Carp
PF Northern Pike
3137 DE023701 F UB Redhorse Sucker
3138 OE023801 F UB Carp
NO
7.98
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.83
9.75
5.24
11.9
5.6
9.74
ND
87.2
3.90
ND
ND
ND
5.00
ND
6.65
ND
ND
ND
ND
24.82
25.93
ND
14.5
ND
ND
ND
ND
ND
1.8
16.0
ND
ND
ND
ND
ND
ND
ND
ND
25.8
ND
ND
ND
5.73
25.3
5.95
23.7
31.0
29.1
28.5
127
9.25
14.6
3.51
16.2
10.4
ND
ND
10.5
ND
ND
ND
37.37
48.02
ND
3.88
ND
ND
ND
ND
4.02
7.66
50.7
8.32 E
ND
ND
2.08
ND
2.40 D
10.2
4.36
81.5
10.8
3.47
ND
13.9
78.0
15.0
60.1
48.1
47.7
47.4
350 E
22.3
36.6
9.62
40.1
28.7
7.22
5.30
28.7
1.73 D
ND
2.66
106.17
133.24
3.14
12.1
ND
7.41
ND
ND
11.6
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
29.5
ND
ND
ND
ND
ND
ND
25.8
ND
10.2
9.95
40.7
0.84
ND
ND
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.61 6.37
81.6 E 29.4
1448 E ND
75.9 E ND
5.57 ND
22.99 1.73 D
2.06 D ND
22.81 ND
136 E ND
91.5 E 7.73
658 E 228
60.6 8.60
53.5 5.15
4.69 ND
130 E 11.1
1003 E ND
133 E 10.3
46.6 187 E
76.6 50.8
104 E 55.3
73.3 52.1
1891 E 405 E
145 12.2
814 E 17.7
181 ND
895 E 19.5
180 16.0
48.71 11.09
35.60 4.36
450 E ND
10.70 ND
136 54.0
30.6 5.17
50.71 83.39
63.70 69.62
22.2 2.80
74.4 E ND
33.8 ND
59.1 8.62
0.94 D ND
6.86 D ND
85.6 4.15
ND
4.45
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.60
3.07
ND
ND
ND
ND
ND
ND
ND
ND
4.66
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.44
ND
ND
ND
ND
ND
ND
ND
ND
14.9
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.93
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.63
ND
ND
ND
ND
ND
ND
ND
5.95
ND
ND
0.47
D 2.98
ND
ND
1.71
ND
ND
ND
34.3
ND
7.06
0.32
1.88
0.64
2.24
0.27
ND
ND
3.32
ND
ND
0.70
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
D ND
D ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
14.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.19
ND
ND
6.92
7.23
7.40
ND
7.44
12.8
7.22
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.61
ND
ND
ND
ND
ND
0.80
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
KEPT DDE DIELDRIN ENDR1N DICOFOL HE
EP CHL
PERTHANE HIREX
NITROFEN CHLOR
PYRIFOS
ISOPROP
3140 DE024001
3UO DE024002
3141 DE024101
3141 DE024102
3141 DE024103
3143 DE024401
3143 DE024403
3144 DE024901
3145 DE026601
3146 DE026701
3146 DE026702
3147 DC035201
3148 DE027101
3148 DE027103
3149 DC038S01
3150 DA008901
3150 QD120187
3151 DA009101
3152 DA009201
3161 DC019801
3161 DC019802
3162 DJ024001
3163 DJ024002
3164 DD015702
3165 DD015704
3166 DD015706
3167 DD015708
3167 00062388
3168 00015711
3168 00015712
3169 00015713
3169 QD022789
3170 DD015715
3171 DD015717
3172 DD015719
3172 DD015720
3173 DD015722
3174 DD015724
3175 00015801
3176 DDO15803
3177 DD015805
3177 00100488
PF Walleye
WB Carp
PF Northern Pike
UB Carp
PF Northern Pike
Rotten (catf)
WB Carp
UB Carp
UB N. Redhorse
UB Carp
PF Ualleye
UB Carp
UB Carp
PF Ualleye
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
BF Black Bullhead
UB Uhite Sucker
UP Starry Flounder
UP Starry Flounder
UB Carp
UB Redhorse Sucker
UB Uhite Sucker
UP Bluegill
UP Bluegill
UB Carp
PF Lm Bass
UB Black Redhorse
L UB Black Redhorse
F UB Spotted Sucker
F UB Spotted Sucker
F UB Carp
F PF Lm Bass
F UB Channel Catfish
F UB Channel Catfish
F UB Channel Catfish
F UB Spotted Sucker
F UB Carp
L UB Carp
NO
NO
24.0
NO
13.8
NO
NO
NO
NO
NO
NO
NO
NO
3.86
3.56
8.64
9.45
NO
NO
6.33
29.8
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
18.6
21.8
9.40
ND
ND
NO
NO
NO
NO
NO
17.1
7.70
NO
ND
ND
ND
ND
23.03
47.2
NO
NO
29.1
16.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.12
ND
ND
ND
ND
NO
1.82 0
5.11
57.3 E
63.2
27.9
ND
7.64
9.34
3.80
15.1
ND
32.3
58.0
15.7
26.5
7.32
7.63
7.93
ND
23.72
161
4.39
1.57 D
104
52.3
ND
1.75 0
2.64
2.80
ND
6.93
5.71
3.51
3.53
9.08
ND
13.4
3.15
8.60
3.54
7.82
7.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.86
ND
ND
ND
ND
ND
0.67
ND
ND
ND
ND
NO
8.60
36.8
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
14.8
42.5
291
564
137
29.5
34.49
137
17.5
100
1.78
79.2
282
85.7
289
19.1
18.4
26.2
5.83
26.38
114
21.0
4.84
111
35.5
79.9
15.2
21.9
590
65.4
384
335
104
48.6
638
32.1
55.0
78.5
55.9
82.2
33.0
30.8
ND
ND
E 50.0
E 63.8
E 29.9
ND
4.04
23.9
4.22
16.5
0 ND
15.8
E 4.51
9.37
15.6
3.36
3.43
2.36
1.75
63.26
450
ND
0.28
32.2
4.76
ND
NO
ND
E ND
E ND
E ND
E NO
E ND
ND
E ND
ND
ND
2.07
E 3.74
E ND
1.95
1.89
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 1.63
ND
ND
ND
D ND
ND
4.73
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D NO
D ND
NO
NO
1.51
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.92
D ND
ND
8.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.73
0.69
ND
ND
ND
NO
NO
0.50
ND
ND
ND
ND
ND
NO
D NO
ND
1.72
ND
ND
7.71
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
2.66
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
D NO
D ND
ND
ND
8.15
NO
ND
D NO
ND
ND
ND
ND
ND
NO
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
1.16
2.90
0.34
ND
ND
ND
0.48
1.52
ND
ND
NO
0.29
NO
ND
0.69
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
4.96
ND
11.3
10.8
0.21
0.28
3.26
0.36
ND
ND
73.2
1.47
0.30
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
D ND
D ND
ND
ND
ND
D ND
ND
ND
0 ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
2.04
ND
ND
ND
D ND
D ND
ND
D ND
ND
ND
E ND
D ND
0 ND
ND
ND
ND
62.7
ND
5.23
ND
ND
ND
ND
ND
ND
7.90
NO
NO
3.99
6.09
4.22
ND
NO
4.35
13.6
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
1.90
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.2
0 ND
ND
ND
ND
ND
-------
§
Episode SCC Type Description
3178 OD015807 F UB North Hogsucker
3179 DD015809 F UB Golden Redhorse
3180 D001S812 PF Lm Bass
3181 0001S8U UB Carp
3182 D0015815 PF Rock Bass
3182 DD015816 UB Carp
3183 DD015817 UB Carp
3183 DD015818 PF Sauger
3184 DDO15820 PF White Crappie
3185 DD015821 UB Channel Catfish
3186 DD015824 UP Southern Flounder
3187 DDO15902 UP Summer Flounder
3188 DD015903 UB Carp
3188 DD015904 PF Lm Bass
3189 DD015905 UB Carp
3189 00092188 UB Carp
3190 DD01S907 UB Carp
3191 DJ024003 UP Starry Flounder
3191 DJ024005 Soft Shell Clams
3192 DJ024007 UP Starry Flounder
3192 DJ024009 Soft Shell Clams
3193 DC039001 PF Sm Bass
3195 DH020104 UB Carp
3195 OH020105 UB Chub
3196 DH020108 UB Sucker
3198 DH020111 UB Sucker
3199 DH020101 UB Carp
3199 DH020103 UB Carp
3200 DH020112 UB Sucker
3203 DJ024018 UB Carp
3205 OJ024024 Crayfish (whole)
3206 DJ024103 UB Sucker
3208 DJ024109 UB Sucker
3212 DJ024120 BF Catfish
3212 OJ024121 UB Carp
3213 OJ024123 UB Squaufish
3215 DJ023705 UB Sucker
3216 OJ023707 PF Squawfish
3216 OJ023708 UB Sucker
3216 00022388 UB Sucker
3217 OJ023710 UB Sucker
3218 DJ023711 PF Squaufish
XENOBIOTICS CONCENTRATIONS, ng/g
OXY
NO
2.37
NO
S.35
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
4.51
NO
2.60
NO
NO
NO
NO
NO
NO
NO
NO
2.93
NO
3.75
NO
NO
NO
NO
5.56
NO
NO
NO
NO
NO
NO
NO
NO
NO
CIS
CHLOR
NO
D 3.82
NO
57.0
NO
24.9
27.7
NO
NO
19.2
NO
ND
35.5
NO
14.0
18.3
11.1
NO
ND
ND
ND
15.4
5.16
10.6
ND
4.36
6.26
6.77
ND
5.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
TRANS
NON
1.95
15.4
ND
242
1.38
94.2
94.9
2.39
ND
60.7
1.01
ND
130
1.83
42.6
55.5
29.1
ND
ND
ND
ND
31.8
16.4
33.4
1.38
14.7
21.3
20.2
10.9
14.4
ND
ND
13.4
4.54
24.7
ND
33.3
1.58
ND
ND
ND
2.67
D
E
D
E
0
D
E
D
D
D
KEPT
NON
ND
ND
ND
ND
ND
ND
76.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
HEPT
EP
ND
ND
ND
3.55
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.83
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DDE
9.37
38.6
13.1
121
3.16
87.7
38.8
2.00
27.3
41.9
4.70
3.75
162
2.85
148
203
31.6
0.89
1.04
1.44
ND
201
84.4
225
11.8
35.4
78.8
39.9
200
333
0.58
37.1
1142
517
3214
43.5
463
34.3
80.9
89.8
35.8
52.0
D1ELDRIN ENDRIN
ND
6.99
ND
E 57.3
ND
E 46.1
13.5
D ND
ND
17.6
ND
ND
E 100
ND
E 29.6
E 47.6
8.39
D ND
D ND
D ND
ND
E 9.76
E 18.5
E 27.6
1.97
24.7
33.5
11.5
79.2
E 12.4
D ND
ND
E 88.0
E 74.3
E 182
ND
E 37.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
26.5
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
NO
ND
NO
DICOFOL ME PER
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
21.1
ND
ND
2.29
NO
ND
ND
18.4
11.6
ND
ND
9.91
ND
NO
ND
ND
ND
CHL
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
ND
46.5
393
ND
2.55
ND
ND
D ND
ND
ND
ND
3.42
ND
NO
NO
ND
0.39
ND
ND
0.56
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
PERTHANE HIREX
NITROFEN CHLOR
PYRIFOS
ISOPROP
ND
ND
1.39
5.89
ND
ND
1.89
ND
ND
6.88
ND
ND
3.68
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.39
ND
ND
0.94
ND
ND
ND
ND
ND
ND
ND
0.26
ND
ND
ND
ND
ND
ND
D ND
ND
0.65
ND
D ND
ND
ND
ND
ND
ND
J ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
1.39
ND
ND
19.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.08
15.4
2.51
26.5
ND
ND
ND
ND
ND
ND
ND
2.36
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
2.32
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
XENOB10TICS CONCENTRATIONS, ng/g
KEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE MIREX N1TROFEN CHLOR ISOPROP
PYR1FOS
3219 DJ023713
3219 DJ023714
3220 DJ023903
3221 DJ023905
3222 DJ023907
3223 DJ023717
3224 DJ023715 N
3226 DJ023721 N
3227 DJ023723 N
3231 DJ023910
3231 DJ023911
3234 DH020301
3235 DH020303
3236 DH020305
3237 DH020308
3237 QD080988
3238 DJ023918
3241 DJ023924
3245 DJ023624
3246 DJ022109
3248 DJ022502
3248 Q0050588
3249 DJ022503
3249 DJ022504
3250 DJ022506
3252 DJ022509
3252 DJ022510
3252 OD020989
3252 00052588
3256 DJ022518
3258 OC038901
3258 DC038902
3259 DB000466
3259 DB000473
3259 DB069101
3260 08000493
3261 DY026002
3262 DY026004
3266 DY022701
3266 OY022702
3266 ODO12389
3267 DY022101
I
WB White Sturgeon
PF White Sturgeon
WB Bridgetip Sucker
WB Sucker
WB Sucker
WP Starry Flounder
Soft Shell Clams
Pacific Oysters
Pacific Oysters
PF Sm Bass
WB Carp
WP Squaufish
WB White Sucker
WB Largescale Sucker
WB Largescale Sucker
WB Largescale Sucker
WP Dolly Varden
WP Dolly Varden
WP Flathead Sole
WP Flathead Sole
WB Composite Bottom
WB not available
PF Brook Trout
WB Sucker
WB Sucker
PF Lm Bass
WB Sucker
PF Lm Bass
WB Sucker
WB Sucker
PF Spot
WB Croaker
WB Goldfish
PF Lm Bass
WB Sucker
WB Carp
WB Striped Mullet
WB Tilapia Tilapia
PF Black Crappie
WB Channel Catfish
PF Black Crappie
PF Rainbow Trout
NO
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.39
ND
ND
ND
ND
5.33
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
J ND
ND
ND
ND
10.76
5.26
ND
ND
ND
ND
44.7
5.66
ND
ND
ND
ND
20.1
1.88 D
ND
15.8
4.45
ND
ND
ND
ND
ND
23.9
7.32
1.81 D
ND
ND
ND
1.17 D
4.57
ND
ND
ND
ND
ND
ND
6.36
ND
23.7 J
ND
20.3
3.69
19.66
13.9
11.6
ND
14.1
ND
88.2
10.9
ND
10.9
ND
1.71 D
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.62
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
797
136
107
590
89.2
1.46
1.00
1.50
7.21
63.6
2493
44.3
16.9
15.7
13.0
12.7
7.94
50.5
5.29
1.80
32.9
31.7
1.99
7.37
60.6
84.0
848
62.1
1061
117
58.31
45.8
94.2
5.37
202
54.0
144
48.8
54.8
2090
77.1
3.90
E ND
E ND
ND
E ND
E ND
D ND
ND
D ND
ND
E 5.32
E 103
ND
ND
ND
ND
1.40 D
ND
ND
ND
D ND
ND
NO
D ND
ND
E 4.00
E 5.50
E 56.8 J
E 3.77
E 56.1
10.8
14.99
16.8
ND
ND
ND
6.51
E 41.2
ND
E ND
E ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.58
24.3
1.49
36.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
J ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.87
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
J ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
u>
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE MIREX
N1TROFEN CHLOR
PYRIFOS
ISOPROP
3267 OY022102
3270 OY022108
3271 DY022110
3272 OY022112
3273 DY022113
3273 DY0221U
3274 DY022116
3276 DY022119
3278 DY022124
3281 OY022205
3282 DY022206
3282 DY022207
3283 DY022209
3285 OY022212
3285 OY022213
3286 DY022215
3287 DY022216
3288 OY022217
3288 DY022218
3289 OY022219
3289 DY022220
3290 DY022221
3290 DY022222
3294 DJ022111
3294 DJ022113
3295 OJ022114
3296 DB040101
3297 DB041501
3298 DB041601
3298 DB041604
3299 DB040601
3299 DB040604
3299 OD040601
3300 DB040201
3300 DB040204
3300 OD021389
3301 DB041101
3301 DB041104
3301 00030989
3302 08041901
3302 DB041904
3303 DB042301
F UB Sacramento Sucker
F UB sucker
F UB Sucker
F UB White Surfperch
F UB Sculpin
F UB Surf Smelt
F UB Sculpin
F UB Ualleye
F UB Sacramento Sucker
F UB Sucker
F BF Flathead Catfish
F UB Carp
F UB Carp
F UP Stingray
F UB Diamond Turbot
F UB Carp
F UB Tilapia Zilli
F PF Squaufish
F UB Sucker
F UP Bocaccio
F UB Sculpin
F PF Redear Sunfish
F UB Blackfish
F UP True Cod
H Hussel
F UP Atlantic Salmon
F UB White Sucker
F UB Carp
F UB Carp
F PF Lm Bass
F UB White Sucker
F PF Lm Bass
L UB Sucker
F UB White Sucker
F PF Sm Bass
L UB Channel Catfish
F UB Carp
F PF Northern Pike
L PF Northern Pike
F UB White Sucker
F PF Lm Bass
F UB Uhite Sucker
NO
HO
HD
14.3
ND
NO
ND
ND
ND
2.14
ND
ND
ND
19.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.83
ND
ND
ND
ND
ND
7.89
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
83.2
22.2
25.7
8.94
ND
ND
ND
ND
ND
15.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.9
ND
ND
23.3
ND
ND
18.7
ND
NO
2.78
4.57
ND
16.0
1.11
ND
ND
ND
11.6
7.21
10.9
36.8
9.27
140
43.5
60.6
25.5
3.63
16.6
ND
5.16
ND
37.8
ND
ND
1.22
6.99
9.59
29.2
0.83
27.1
3.63
17.6
26.7
4.97
3.80
68.7
3.03
3.69
39.4
2.16
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
N
ND
ND
ND
ND
ND
ND
ND
1.51
ND
ND
10.4
53.8
3.10
805
11.7
4.34
1.65
7.23
73.2
80.4
2820
8708
772
10.9
101
149
45.7
1433
1484
95.3
172
13.3
997
9.46
0.38
31.0
43.6
58.2
202
11.5
141
21.7
106
267
41.4
30.9
1005
29.9
35.5
509
19.8
31.0
ND
ND
ND
E 260
ND
ND
D ND
ND
E ND
E 1.21
E 44.0
E 188
E ND
21.9
ND
E ND
4.12
E 174
E 161
5.07
E 6.78
ND
E ND
ND
0 NO
ND
13.7
19.8
E 22.4
ND
E 19.3
3.69
E 14.6
E 18.1
2.53
1.65
E 85.4
2.64
3.86
E 25.8
ND
ND
ND
ND
ND
16.2
ND
ND
ND
ND
ND
D ND
13.8
E 45.4
ND
ND
ND
ND
ND
E 7.39
16.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.93
5.13
ND
ND
ND
ND
ND
ND
11.8
ND
ND
ND
ND
1.37
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.95
ND
ND
6.71
0.36
0.57
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
NO
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 0.29
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.48
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
0.88
ND
ND
ND
0.57
2.78
ND
ND
0.75
0.28
1.29
37.9
7.91
6.03
73.7
5.92
6.87
65.6
3.63
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
3.95
3.17
ND
ND
NO
D ND
ND
ND
ND
D ND
D ND
ND
ND
D ND
D ND
0 ND
12.8
ND
ND
ND
ND
ND
10.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
78.7
344
61.7
ND
ND
5.12
3.40
ND
ND
ND
ND
ND
2.22
ND
ND
ND
ND
ND
12.0
ND
ND
ND
ND
ND
ND
ND
14.0
4.29
5.29
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
E ND
ND
ND
ND
J ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
XEN08IOTICS CONCENTRATIONS, ng/g
3303 DB042304
3303 00102588
3304 DB041001
3304 DB041004
3304 OD041004
3305 DB042001
3305 DB042004
3305 OD110388
3306 DB041801
3306 DB041804
3306 QD041801
3307 DB042101
3308 DB040001
3309 DB041301
3310 DC032701
3310 DC032702
3311 OC032801
3311 OC032802 F
3312 DC033101
3312 DC033102
3313 DC033201
3313 DC033202
3314 DC033301
3314 DC033302
3315 DC033401
3315 DC033402
3316 DC033501
3317 DC033601
3318 DC033701
3319 DB041401
3320 DB041412
3321 DB040401
3321 OD100688
3323 DB041206
3324 DB041252
3325 DB041218
3326 DB041208
3327 DB040301
3327 08040315
3328 DD029111
3329 DD016003
3330 DD029110
F PF Sffl Bass
L UB White Sucker
F PF Northern Pike
F UB White Sucker
L UB White Sucker
F UB Channel Catfish
F PF Sm Bass
L UB Channel Catfish
F UB White Sucker
F PF Sm Bass
L UB White Sucker
F UB White Sucker
F PF Northern Pike
F UB White Sucker
F UB Bullhead
F PF Walleye
F UB Redhorse Sucker
PF Sm Bass
UB Redhorse Sucker
PF Sm Bass
UB Redhorse Sucker
PF Sm Bass
UB Channel Catfish
PF White Bass
UB Carp
PF Lm Bass
UB White Sucker
UB White Sucker
UB White Sucker
UP Winter Flounder
WP Bluefish
UP Winter Flounder
UP Winter Flounder
UP Winter Flounder
UP Bluefish
UP Bluefish
UP Bluefish
UP Bluefish
UP Bluefish
UB Carp
UB Boufin
UB Spotted Sucker
OXY
NO
NO
ND
ND
ND
36.1
ND
43.3
NO
ND
ND
3.02
ND
ND
ND
ND
2.96
ND
ND
1.99
3.33
2.03
9.51
1.93
2.41
ND
NO
NO
NO
ND
ND
2.20
2.13
2.75
4.56
ND
3.05
ND
ND
ND
ND
0.46
CIS
CHLOR
ND
ND
ND
ND
6.29
29.0
ND
28.9
ND
ND
ND
3.75
ND
ND
ND
3.20
4.54
1.40
20.3
4.88
6.35
0.73
50.9
D 7.53
D ND
ND
ND
ND
ND
ND
ND
D 6.21
0 5.47
11.9
4.14
2.59
6.11
3.34
6.82
6.72
ND
D ND
TRANS
NON
ND
ND
2.04 D
8.03
16.1
77.1
ND
77.2
3.93
1.53 D
5.90
5.98
ND
ND
30.8
ND
13.2
3.95
53.9
12.83
26.4
4.16
185 E
24.1
22.1
2.08 D
1.84 0
ND
5.56
13.5
12.3
20.6
20.9
39.4
8.77
7.12
14.6
8.90
17.1
18.2
ND
6.59
HEPT
NON
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
HEPT
EP
ND
ND
ND
ND
ND
ND
ND
5.17
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
DDE
1.81
10.7
20.7
115
207
602
9.75
607
42.1
13.5
63.4
78.8
2.49
15.2
100
12.4
6.28
1.51
22.6
5.33
200
19.48
51.7
10.0
14028
915
3.92
ND
22.2
25.8
42.9
26.2
26.4
29.5
27.3
15.9
29.0
46.2
43.8
247
2.07
15.1
OIELDRIN
D
E
E
E
E
E
D
E
D
E
E
E
D
ND
ND
ND
ND
12.5
43.0
ND
42.9
12.9
ND
12.6
5.55
ND
4.05
12.4
4.50
3.74
1.18 D
5.69
4. 55
7.75
ND
19.6
4.79
ND
ND
ND
ND
5.93
14.1
4.52
12.1
9.85
8.18
9.74
2.78
8.90
4.82
8.41
ND
4.25
1.84 D
ENDRIN
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
118
4.54
ND
ND
ND
ND
ND
ND
ND
ND
4.24
ND
ND
ND
ND
ND
ND
ND
ND
ND
DICOFOL
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.39 D
ND
ND
ND
ND
ND
ND
ND
ND
0.53 D
ME
CHI
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PERTHANE HI REX NITROFEN CHLOR ISOPROP
PYRIFOS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.25
12.7
18.1
135
2.25
137
5.53
4.10
8.84
18.8
ND
ND
ND
ND
0.57
0.18
1.36
1.14
0.83
ND
ND
0.22
ND
ND
ND
ND
ND
ND
ND
ND
3.30
0.63
ND
ND
ND
ND
0.32
5.84
ND
7.00
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
D ND
D ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34
0.93
ND
2.86
1.23
1.12
ND
17.2
2.40
ND
ND
ND
ND
22.3
ND
ND
1.45
1.61
0.63
3.38
1.11
0.84
2.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
D ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
D ND
ND
D ND
D ND
ND
ND
ND
ND
ND
-------
I
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DOE OIELDR1N ENDRIN DICOFOL ME
EP CHL
PERTHANE HIREX NITROFEN CHLOR 1SOPROP
PYRIFOS
3331 OD016007
3332 DD016009
3333 DD016012
3334 D0016013
3335 DD016015
3335 D0029101
3335 DD029102
3335 D0029103
3335 00091588
3336 DD016004
3336 D0016006
3336 DD016017
3336 DD016018
3337 OD016019
3338 DD016022
3339 DD016023
3340 OD029114
3341 DD016104
3341 00081788
3342 00016105
3343 00016107
3344 00016109
3345 00016111
3346 00016113
3346 D0016114
3347 00016115
3348 DD016117
3348 D0016118
3349 00016119
3350 DD016121
3350 00016122
3351 00016124
WB Carp
WP Spotted Drum
WB Sea Catfish
WB Sea Catfish
WP Spot
WP Red Drum
WB Southern Flounder
WP Sheepshead
WP Red Drum
WP Black Drum
WP Sheepshead
WP Red Drum
PF Spotted Seatrout
WB Spotted Sucker
WB Spotted Sucker
WB Carp
WB Channel Catfish
WB Catfish
WB Catfish
WB Spotted Sucker
WB White Sucker
WB Carp
WB Redhorse Sucker
WB Creek Chubsucker
PF Lm Bass
WB Carp
PF White Perch
WB Blue Catfish
WB Carp
WB Carp
PF Lm Bass
WB Carp
3352 DF023723 F PF Crappie
3352 DF023724 F WB Carp
3352 00022089 L PF Crappie
3353 DF024121 F BF Blue Catfish
3353 DF024122 F WB Sm Buffalo
3354 DY022301 F WB Carp
3354 DY022302 F PF Lm Bass
3355 DY022303 F WB Carp
3355 DY022304 F PF Lm Bass
3356 DE030201 F WB Carp
NO
NO
1.70
5.94
NO
NO
ND
ND
ND
ND
ND
ND
NO
NO
NO
5.52
ND
4.46
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.13
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
4.65
ND
ND
ND
ND
0 NO
29.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.81
19.6
ND
18.0
16.2
ND
ND
ND
ND
ND
ND
21.2
ND
ND
D 7.86
29.6
ND
16.5
ND
ND
ND
NO
NO
14.1
ND
24.4
ND
ND
ND
ND
5.03
65.0
ND
1.45
1.12
2.19
ND
NO
NO
ND
ND
ND
ND
53.9
ND
41.8
38.7
41.0
5.42
42.0
14.4
3.62
ND
76.4
ND
2.50
17.0
89.3
4.21
ND
ND
6.17
ND
7.49
11.3
ND
0.98
53.9
2.02
37.1
ND
ND
ND
ND
ND
D NO
D ND
0 ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.46
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
NO
8.31
11.9
51.2
254
6.32
3.37
6.03
5.83
2.20
1.13
3.49
1.71
NO
18.2
ND
95.5
15.9
288
265
207
9.57
229
106
17.7
4.45
178
3.85
13.8
242
146
6.27
559
144
2237
118
1082
1980
835
14.1
477
22.1
382
ND
ND
ND
E ND
ND
D 1.76
ND
ND
D ND
D ND
ND
D ND
ND
3.46
ND
E 30.7
7.75
E 16.7
E 14.3
E 22.0
ND
E 36.4
E 3.50
ND
NO
E NO
0.96
6.06
E 7.18
E 47.0
NO
E 3.30
D ND
E ND
E ND
ND
E ND
2.29
ND
E 22.3
ND
E 25.6
ND
ND
ND
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.45
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.54
ND
1.73
NO
74.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D NO
NO
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.52
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.39
ND
0.27
8.17
NO
ND
ND
ND
ND
ND
ND
ND
D 0.42
7.22
ND
1.41
10.2
3.67
3.25
ND
ND
4.55
ND
ND
ND
1.50
ND
0.27
1.47
NO
ND
ND
ND
6.00
ND
4.96
12.0
ND
ND
1.00
ND
1.45
D NO
ND
0 ND
ND
ND
0.51
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
D NO
ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
17.9
ND
D ND
ND
D NO
ND
ND
ND
ND
ND
D NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.67
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.88
ND
ND
0.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.37
ND
ND
ND
ND
ND
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
D ND
ND
NO
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDRIN DICOFOL HE
EP CHL
PERTHANE HIREX NITROFEN CHLOR ISOPROP
PYRIFOS
3357 DY022224
3360 DD029117
3375 00016305
3375 DD016306
3375 OD071189
3376 DD016307
3376 DD016308
3377 DD016309
3377 DD016310
3378 DD016311
3378 DD029115
3385 DD016401
3385 QD101888
3395 DD016421
3401 DD016509
3401 00016510
3403 00016513
3403 00016514
3404 00016515
3404 QD016515
3409 DB040701
3409 DB040706
3411 DB040501
3412 DB040901
3412 DB040907
3414 DC036203
3414 DC036204
3415 DC036205
3415 DC036206
3419 DC036207
3419 DC036208
3420 DC036209
3420 DC036210
3421 DC036211
3421 DC036212
3422 DC036213
3422 DC036214
3423 DC036216
3424 DC036218
3425 DF025005
3426 DB069102
3427 DB069103
UB Sacramento Sucker
UB Carp
UB Carp
PF Lm Bass
PF Lm Bass
WB Carp
PF Lm Bass
WB Carp
PF Lm Bass
UB Spotted Sucker
UB Greyfin Sucker
UB Redhorse Sucker
B not available
UB Redhorse Sucker
UB Carp
PF Lm Bass
UB River Carpsucker
PF Lm Bass
UB Carp
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
UB White Sucker
PF Freshwater Drum
PF Greenfish
UB Carp
PF Uhite Perch
UB Carp
PF Lm Bass
UB Yellow Bullhead
UB Uhite Catfish
UB Uhite Catfish
UB Carp
PF Btuefish
PF Btuefish
ND
NO
ND
0.88
ND
ND
ND
ND
1.78
ND
ND
ND
2.77
4.78
ND
ND
14.4
ND
ND
1.84
26.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.9
ND
2.21
4.53
48.5
1.57
123
2.58
5.11
ND
6.76
5.70
23.7
ND
ND
28.0
ND
6.60
D 8.52
25.2
ND
ND
3.01
19.2
ND
ND
ND
3.45
1.63
ND
ND
ND
ND
ND
ND
ND
5.42
ND
ND
ND
ND
30.3
33.8
188
6.08
21.65
157
4.39
398 E
13.70
7.18
ND
19.8
25.3
65.6
27.2
1.72 D
99.8
8.36
19.2
22.0
78.0
3.17
ND
6.58
47.2
ND
13.4
ND
20.7
9.20
A. 88
4.12
11.4
3.38
ND
ND
ND
10.3
1.75 D
ND
5.98
5.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
207
409
447
2.57
8.22
167
4.38
632
11.42
175
194
17.5
18.6
174
1157
68.0
32.5
3.40
136
185
374
14.3
17.2
55.6
671
13.4
54.6
8.56
81.9
29.58
9.47
10.31
36.9
2.76
22.2
4.35
5.91
57.7
14.1
55.1
27.2
ND
20.5
E ND
E 94.1
1.82
7.06
E 41.5
ND
E ND
3.37
E 6.77
E ND
ND
ND
E 28.7
ND
E ND
66.7
3.97
E ND
E NO
E 16.9
ND
12.3
E 2.59
E 29.3
ND
14.7
NO
11.4
20.02
4.78
7.59
ND
ND
13.4
ND
ND
ND
ND
ND
4.13
ND
ND
ND
ND
D NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
8.80
ND
ND
2.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.77
ND
ND
ND
0.78
ND
0.46
ND
1.25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
17.9
ND
D ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
NO
ND
10.2
14.4
ND
ND
20.9
ND
35.5
ND
1.73
10.6
ND
ND
1.89
4.83
0.21
ND
ND
ND
ND
ND
ND
ND
14.2
85.4
ND
ND
ND
0.77
ND
ND
1.03
ND
ND
ND
ND
ND
ND
ND
ND
0.38
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
1.57
4.78
64.5
1.15
2.72
45.6
0.90
23.6
3.42
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
D ND
ND
ND
D ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
XENOBIOTICS CONCENTRATIONS, ng/g
HEPT DDE DIELDRIN ENDR1N DICOFOL ME
EP CHL
PERTHANE HI REX NITROFEN CHLOR ISOPROP
PYRIFOS
3428 DB069104
3429 OB069105
3430 DB069106
3431 DB069109
3433 DB069112
3434 DB040801
3434 OD011889
3435 00016602
3444 00016603
3444 DD016604
3444 00029512
3445 DD029513
3446 DD016605
3446 DD016606
3446 00091889
F PF Bluefish
F PF Ueakfish
F WB White Catfish
F UB Red Snapper
F UP Flounder
F UP Flounder
L UP Flounder
F UB Bigmouth Buffalo
F UB Carp
F PF Channel Catfish
F PF Lm Bass
F UB Flounder
F PF Striped Bass
F UB Carpsucker
F UB Carpsucker
ND
ND
ND
ND
7.09
8.39
6.61
ND
ND
10.
1.87
ND
2.62
2.52
NO
ND
ND
ND
ND
3.94
5.95
7.09
44.3
86.8
113.0
7.66
ND
5.77
10.3
11.3
11.6
ND
7.51
5.01
8.48
14.2
20.1
115
76.4
109
16.1
ND
30.5
26.9
27.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
28.7
15.4
10.5
1.36
ND
ND
ND
ND
60.2
10.2
28.7
8.33
36.8
65.3
88.1
141
2448
2459
28.7
8.08
11.1
12.9
13.2
E 4.47
ND
ND
ND
5.05
E 14.8
E 16.5
236
E 115
E 58.9
14.3
1.36
1.22
1.70
ND
ND
ND
ND
ND
ND
ND
ND
162
ND
3.22
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
4.53
ND
2.83
ND
ND
1.40
0.43
0.57
ND
ND
ND
ND
ND
ND
ND
ND
4.55
0.88
ND
ND
D ND
D ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.24
ND
ND
1.73
2.01
3.49
ND
ND
0.65
ND
ND
ND
ND
ND
ND
D ND
0.24
ND
D ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
0.96
D ND
ND
22.6
21.7
22.3
1.53
ND
0.48
ND
0.45
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
D ND
-------
Key for Xenobiotic Data Table (Units = ng/g) (continued)
Sfili
TRIFLUR
PCA
BIPHENYL
TOTPCBs
1C1
2C1
3C1
4C1
5C1
6C1
7C1
8C1
9C1
10 Cl
DIPHENDIS
HCBUT
Trifluralin
PentachloroanisoleT1825/21/4
Total Polychlorinated Biphenyls
Total Monochlorobiphenyls
Total Dichlorobiphenyls
Total Trichlorobiphenyls
Total Tetrachlorobiphenyls
Total Pentachlorobiphenyls
Total Hexachlorobiphenyls
Total Hectachlorobiphenyls
Total Octachlorobiphenyls
Total Nonachlorobiphenyls
Total Decachlorobiphenyls
Diphenyl Disulfide
Hexachlorobutadiene
CAS Number
1582/09/8
92/52/4
1336/36/3
27323/18/8
2551/42/9
25323/68/6
26914/33/0
25429/29/2
26601/64/4
28655/71/2
31472/83/0
53742/07/7
2051/24/3
882/33/7
87/68/3
DATA FLAGS
D = Value below limit of quantitation for all Xenobiotics except Mercury and PCBs,
D = 2.5 ng/g
For Polychlorinated Biphenyls
Number of Chlorines Df ng/g
1-3 1.25
4-6 2.50
7-8 3.75
9-10 6.25
E = Value exceeds highest calibration standard
See Dioxin/Furan Data Table Key for explanation of other codes. The tables include
environmental samples (those starting with a sample number of D) and the duplicate
samples (those starting with a Q) and confirmation samples (those starting with an S). The
number of samples shown on the summary tables in Volume I do not included the duplicate
and confirmation samples.
D-5-3S
-------
D-5-36
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3d 4C1 SCI
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
2015 DF001001
2016 DF001101
2017 DF001201
2018 DF001301
2023 DF001403
2026 DF001702
2027 DF001803
2037 DY000501
2056 DE000501
2057 DE000601
2059 DE000801
2060 DE000901
2070 OJ000902
2098 DH001501
2100 DH001703
2105 DH002204
2109 DH002601
2110 DH002710
2122 DH003904
2126 DD000302
2133 DD001002
2139 DD001601
2142 00001902
2148 DD002501
2151 DD002803
2152 DD002903
2190 DG005101
2190 DG005104
2191 DG005205
2194 DG005501
2199 DG006001
2199 DG006004
2201 DG006201
2205 DG006601
2210 DC005401
2211 DC005503
2212 DC005602
2212 DC005605
2215 DC005902
2216 DC006003
UB Carp
UB Sucker
UB Carp
UB Sucker
UB Carp
UB Carp
UB Carp
UB not available
UB Carp
UB Carp
UB Carp
UB Carp
UB Longnose Sucker
UB N/A
UB Catfish
UB Carp
UB N/A
UP Broun Trout
UB White Sucker
UB Carp
BF Blue Catfish
UB Carp
UB Catfish
UB Saltwater Catfish
UB Spotted Sucker
UB Lake Chubsucker
UB Carp
PF Bluegill
UB Carp
UB Carp
UB Carp
PF Lm Bass
UB Carp
UB Carp
UB Catfish
UB Redhorse Sucker
PF Sm Bass
UB White Sucker
UB Carp
UB White Sucker
2220 DC006405 F UB Catfish
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.4
ND
ND
ND
ND
120
ND
ND
4.62
ND
ND
ND
ND
ND
ND
85.5
ND
458
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.41
1.82
2.85
0.15
0.33
2.31
0.82
ND
13.6
4.47
3.59
3.06
ND
ND
14.1
ND
ND
ND
ND
4.02
1.70
ND
ND
ND
ND
2.01
E 1.23
ND
E 5.66
15.0
6.28
ND
ND
0.57
19.9
0.87
0.59
12.1
23.8
ND
1.69
0.57
D 0.34
ND
D 0.45
D 0.13
D 0.59
D 0.29
ND
33.4
1.05
22.5
0.56
0.22
0.85
1.08
ND
0.46
0.17
0.45
0.36
D 0.13
0.61
0.54
ND
0.64
D 0.66
0 0.15
0.49
2.07
2.47
2.63
0.57
0.86
D 0.40
25.9
D 0.89
D 0.41
0.24
10.2
0.29
0 0.82
D 924.75
D 142
6.12
D ND
D 101.67
D 106.85
D 7.64
ND
1295.2
D 1051
15897.
D 461.7
D ND
D 2.94
D 685.64
ND
D ND
D ND
D 19.62
D ND
D 30.74
D ND
D 273.95
24.66
D ND
D ND
D 5.04
D ND
D 146.37
D 297
26.64
D 42.63
D ND
D 19.06
2313.4
D 1322.6
D 856.34
D 3804.1
9437
D ND
D 31.2
ND
ND
ND
ND
ND
ND
ND
ND
22.4
ND
ND
ND
ND
ND
4.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.00
ND
46.3
ND
ND
ND
1.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
7.58
ND
ND
10.4
112
ND
ND
4.75
ND
ND
ND
1.17
1.11
ND
ND
24.4
95.6
1196
32.5
ND
ND
12.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9.37
16.1
ND
3.18
ND
ND
28.7
3.71
3.14
206
E 1689
ND
ND
129
20.3
ND
ND
D 13.9
0 4.61
ND
ND
102
517
E 7183
147
ND
ND
131
ND
ND
ND
ND
ND
2.44
ND
2.85
ND
ND
ND
ND
ND
41.0
54.0
ND
19.3
ND
ND
229
81.0
86.9
E 1032
E 4112
ND
ND
E 300
50.3
2.27
ND
24.6
33.0
ND
ND
209
E 305
E 4523
147
ND
ND
265
ND
ND
ND
11.1
ND
D 11.6
ND
63.3
6.06
ND
ND
2.06
ND
56.3
106
6.80
7.88
ND
6.74
E 578
E 242
E 258
E 1203
E 2230
ND
7.50
E 367
54.7
D 3.85
ND
41.0
48.1
7.64
ND
E 552
E 108
E 2169
109
ND
2.94
E 213
ND
ND
ND
8.52
ND
16.7
ND
139
18.6
ND
ND
D 1.81
ND
28.9
94.3
16.0
10.2
ND
10.8
E 1017
E 525
E 340
E 1005
E 1063
ND
23.7
E 124
16.7
ND
ND
21.0
16.9
ND
ND
E 328
25.4
E 663
26.2
ND
ND
E 54.2
ND
ND
ND
ND
ND
ND
ND
E 58.3
ND
ND
ND
D 1.17
ND
10.8
26.1
3.84
2.07
ND
1.52
E 389
E 346
E 148
E 309
E 231
ND
ND
ND
ND
ND
ND
ND
3.13
ND
ND
E 53.4
ND
E 117
ND
ND
ND
3.82
ND
ND
ND
ND
ND
ND
ND
10.5
ND
ND
ND
D ND
ND
ND
ND
NO
D ND
ND
D ND
E 64.2
E 88.8
E 20.3
E 38.7
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 27.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 8.99
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XEHOBIOT1CS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
OIPHEN HCBUT
DIS
2227 DC007104 F UB Channel Catfish
2228 DC007201
2231 DC007503
2246 DJ002302
2247 DJ002404
2280 DF005201
2280 00121688
2283 DF005501
2290 DD003403
2294 DD003804
2297 DD004102
2298 DD004203
2301 DD004504
2302 DD004601
2304 DD004801
2309 DD005301
2322 DB001301
2326 DB001701
2328 DB001904
2329 DB002004
2341 DD006003
2355 DA001603
2356 DA001702
2375 OA003803
2376 DA003903
2379 DE005404
2380 DE005501
2383 DE005801
2385 DE006002
2394 DE006901
2394 OD006901
2394 00022189
2397 DE007201
2410 DE008501
2410 DE008504
2416 DE009101
2422 DE009702
2427 DE010202
2429 DE010402
2430 DE010603
PF Longear Sunfish
WB Gizzard Shad
UB Bridgelip Sucker
UP Mountain Uhitefish
UB Carp
UB Carp
UB Gray Redhorse
UB Spotted Sucker
UB Carp
UB Carp
UP Lm Bass
UP Rock Bass
UB Ouillback Carpsucker
UB Carp
UB Carp
UB White Sucker
UB Uhite Sucker
PF Chinook Salmon
PF Brown Trout
UB Carpsucker
UB Uhite Sucker
PF Lm Bass
UB Uhite Sucker
UB Uhite Sucker
PF Lm Bass
UB Carp
UB Carp
UB Uhite Sucker
UB Carp
UB Carp
UB Carp
UB Sucker
UB Carp
PF Sm Bass
UB Carp
UB Carp
UB Carp
UB Carp
UB Redhorse Sucker
2430 OD121488 L F not available
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.27
ND
ND
ND
ND
ND
37.9
3.08
ND
ND
ND
ND
31.5
6.02
0.33
10.3
0.70
ND
15.4
4.14
ND
3.65
11.6
ND
62.3
42.7
0.87
25.8
30.0
25.8
ND
ND
ND
60.4
ND
ND
1.70
ND
0.56
0.87
0.10
1.84
0.56
0.49
ND
0.14
0.51
12.5
0.82
0.14
0.22
0.15
0.22
0.72
0.16
D 0.79
1.12
D 1.04
1.17
ND
0.86
0.32
0.58
3.59
0.16
1.71
0.99
D 0.92
2.05
2.38
1.13
0.24
12.4
0.19
7.54
0.36
1.42
D 1.35
0.32
D 0.40
D ND
D ND
D 1228.9
D 205.5
D 82.24
5.48
D 2.68
D ND
472.7
D ND
D 132.5
D 4.52
D 28.24
0 26.21
D 1058.6
D 828.56
D 93.28
D 18.87
D 3937.2
D 2109.3
1776.9
D 84.6
D 39.62
0 796.74
1110.2
D ND
D 8471.2
D 8783.0
D 343.1
D 7319.9
D 5332.9
D 4609.8
D 45.37
11119.
D 422.66
3680.9
D 938.69
D 18490.
D 29129.
D 10.15
D 9.27
ND
ND
MD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
7.74
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
9.82
ND
6.07
ND
ND
2.04
2.23
ND
9.31
8.79
ND
21.5
36.7
30.9
ND
17.2
ND
32.0
ND
7.23
81.7
ND
ND
ND
ND
11.4
ND
ND
ND
ND
ND
11.8
ND
NO
ND
ND
ND
5.26
2.26
2.11
ND
63.7
8.76
34.5
ND
ND
D 19.8
D 59.5
NO
184
323
ND
1105
577
477
1.31
194
3.46
260
2.69
1108
2458
ND
NO
ND
ND
161
21.5
4.38
ND
ND
ND
88.7
ND
NO
ND
3.74
ND
109
69.3
0 19.9
ND
E 557
250
313
18.1
ND
270
E 309
ND
E 2072
E 1921
32.4
E 2740
E 1576
E 1262
4.56
E 2789
45.7
E 1030
81.7
E 12055
E 17379
ND
ND
ND
ND
337
94.4
37.0
ND
ND
NO
171
ND
33.1
ND
11.7
4.08
390
E 262
41.3
9.16
E 1343
E 679
E 507
44.5
6.83
E 323
E 348
ND
E 3142
E 2803
79.2
E 2348
E 1713
E 1524
20.2
E 3743
91.4
E 1044
264
E 3699
E 6251
2.15
1.71
ND
ND
E 445
E 77.7
36.1
5.48
2.68
ND
170
ND
83.3
4.52
12.8
16.5
E 435
f. 392
25.8
9.71
E 1455
E 818
E 625
22.0
23.3
E 162
E 274
ND
E 2254
E 2636
E 141
E 1048
E 1198
E 1100
19.3
E 2872
E 188
E 955
E 378
E 1226
E 2147
0 8.00
D 7.56
ND
ND
E 171
11.9
4.76
ND
ND
ND
31.2
ND
E 16.1
ND
ND
5.63
E 105
E 95.2
4.17
ND
E 442
E 307
E 245
ND
9.49
E 19.9
E 101
ND
E 672
E 924
E 78.4
E 57.4
E 202
E 190
NO
E 1306
E 82.3
E 327
E 174
E 328
E 619
ND
ND
ND
ND
45.1
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
14.4
E 7.80
ND
ND
E 66.7
E 46.6
E 38.6
NO
ND
ND
E 16.5
ND
E 124
E 159
E 12.1
ND
30.2
25.9
ND
E 198
E 11.8
32.9
38.3
67.3
E 169
ND
ND
ND
ND
42.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
13.9
8.28
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
25.0
ND
ND
ND
ND
16.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
2431 DE010703
2432 DE010710
2435 DE011001
2437 DE011203
2439 OE011401
2439 DE011402
2478 DJ003902
2500 DC010203
2532 DF019303
2544 OF019202
2608 DE014504
2618 DE015401
2618 DE015402
2618 DE015403
2651 DB008401
2653 DB008503
2654 OB008601
2709 OB005101
2721 OA006502
2721 OD011089
2722 DA006601
2725 DA006301
2748 DY006505
2776 DY007101
2776 OD010489
3001 DE019502
3022 DA008401
3023 DA008501
3024 DA008601
3025 DA008701
3028 DA008B01
3034 DG025701
3035 DG025801
3036 DG025902
3037 DG026001
3038 DG026101
3039 DG026201
3040 DG026301
3041 DG026402
3042 DG026501
3042 DG026502
F UB Sucker
F UB Redhorse Sucker
F UB Longnose Sucker
F UB Carp
F UB Carp
F UP Sm Bass
F UB Sucker
F UB Black Buffalo
F UB Carp
F UB Blacktail Redhorse
F UB Carp
F UB Carp
F BF Carp
F UB Quill back
F UB White Sucker
F UB Carp
F UB Carp
F UB Catfish
F UB Sucker
L UB Sucker
F UB Sucker
F UB Sucker
F UB Sucker
F UB Carp
L UB Carp
F UB Uhite Sucker
F UB Uhite Sucker
F PF Sm Bass
F PF Lm Bass
F UB Uhite Sucker .
F PF Chain Pickerel
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F UB Carp
F PF Northern Pike
ND
ND
ND
54.8
ND
ND
ND
ND
23.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.79
23.1
117
53.0
222
ND
28.6
6.15
27.7
ND
ND
ND
ND
9.40
44.5
46.8
ND
0.76
3.19
24.2
6.02
122
33.1
240 E
2.91
1.50 D
10.88
4.06
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.1 E
ND
0 2.97
3.20
E 6.21
3.33
6.49
3.87
E 1.01 D
0.30 D
3.43
ND
0.21
0.64
0.27
0.82
0.55
0.18
0.53
3.50
0.54
0.62
1.91
ND
0.20
1.37
0.71
0.76
D 29.3
D 1676.9
D 115.18
D 789.5
D 7977.2
D 5444
D 40.77
687.2
D 677
D 24.79
D 3955.9
8706.3
D 2909.5
0 7091.4
0 480.04
D 1833.1
131 .69E ND
1.19
ND
ND
0.08
2.16
0.24
ND
ND
ND
0.75
0.11
0.53
.25
0.09
0.72
0.65
0.64
0.48
70.2
0.36
0.29
0.52
75.6
0.52
D 8444.0
460.31
384.89
D ND
D 321.71
D ND
21.2
32.69
10.2
D ND
D ND
D 30.78
D 33.6
D ND
D 872.12
D 731.85
D ND
D 38.55
148. 7
0 635.4
D 58.26
D 8.9
E 285.12
0 3.96
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
14.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.32
ND
ND
ND
ND
ND
24.2
45.0
ND
ND
ND
ND
6.28
72.2
27.4
45.9
ND
3.29
ND
5.49
4.41
12.6
ND
15.6
ND
ND
ND
10.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
20.7
ND
ND
ND
20.9
ND
ND
6.69
NO
ND
647
E 616
ND
ND
16.8
ND
432
1280
455
E 1022
1.34
82.5
ND
303
14.9
4.29
ND
1.74
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.02
6.75
ND
ND
0.80
16.0
ND
1.54
28.6
ND
ND
242
6.65
40.1
E 2843
E 1970
ND
ND
91.9
ND
E 2341
E 3140
E 1162
E 2514
D 27.0
E 461
8.83
E 2918
21.6
10.4
ND
D 28.0
ND
ND
ND
ND
ND
ND
4.72
ND
ND
85.5
87.2
ND
5.85
D ND
103
3.16
4.72
34.3
ND
13.0
E 601
35.4
303
E 2745
E 1718
11.1
42.4
201
7.99
E 895
E 2594
E 800
E 2014
114
E 649
11.67
E 2502
86.1
84.9
ND
64.4
ND
5.32
9.01
ND
ND
ND
16.9
18.2
ND
E 235
244
ND
17.2
17.3
264
E 23.7
2.64
111
ND
16.3
E 638
55.1
E 379
E 1526
E 982
22.8
206
E 254
16.8
E 258
E 1418
E 419
E 1276
E 220
E 482
ND
E 1963
E 209
E 180
ND
124
ND
12.4
19.1
ND
ND
ND
9.16
E 15.4
ND
E 372
E 330
ND
15.5
94.8
E 199
E 31.4
ND
83
3.96
ND
E 167
16.5
E 67.4
E 192
E 113
6.87
E 303
E 96.5
ND
23.7
E 186
E 46.1
E 197
E 99.6
E 118
ND
E 620
E 110
E 92.7
ND
E 64.4
ND
3.48
4.58
ND
ND
ND
ND
E ND
ND
E 144
E 63.9
ND
ND
15.1
E 53.4
E ND
ND
ND
ND
ND
22.3
1.53
ND
ND
ND
ND
E 124
16.8
ND
ND
16.1
ND
22.5
E 18.1
E 32.0
ND
E 121
14.3
ND
ND
8.77
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 30.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 11.8
ND
ND
ND
ND
ND
ND
ND
5.37
ND
11.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
20.50
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3042 OD026S01
3043 OG026601
3044 DG026701
3045 DG026801
3045 OG026802
3046 OG026901
3047 DG027001
3048 DG027101
3048 DG027102
3048 OD012689
3048 OD027101
3049 DG027201
3050 DG027301
3060 DF009101
3060 OF009102
3060 OD073189
3061 DF019106
3062 DF024024
3063 DF023301
3063 OF023302
3064 DF023305
3065 DF023419
3065 OF023420
3065 OD010788
3066 DF023503
3066 DF023504
3068 DF024001
3068 DF024002
3069 DF024007
3069 DF024008
3069 OD051788
3070 OF024009
3070 DF024010
3071 DF024014
3071 DF024015
3072 DF024017
3072 00070688
3073 DF019221
3074 DF026017
3076 DF028502
3077 DF019114
L WB Carp
F BF Flathead Catfish
F WB Carp
F WB Carp
F BF Flathead Catfish
F WB Bigmouth Buffalo
F WB Carp
F WB Carp
F PF White Bass
L PF White Bass
L WB Carp
F WB Carp
F WB Bigmouth Buffalo
F WB Flathead Catfish
F WB Sm Buffalo
L WB Flathead Catfish
F WB Sucker
F WB Blue Catfish
F WB Sea Catfish
F PF Spotted Seatrout
H Shellfish
F BF Bigmouth Buffalo
F WB Flathead Catfish
F BF Bigmouth Buffalo
F WB Catfish
F PF Freshwater Drum
H Oysters
F PF At I. Croaker
F WB Sea Catfish
F PF Trout
F WB Sea Catfish
F WB Croaker
F PF Sheepshead
F WB Carp
PF Longnose Gar
WB Carp
WB Carp
WB White Sucker
PF Brown Trout
WB Channel Catfish
WB Redhorse Sucker
25.9
55.9
82.8
39.1
5.58
ND
ND
ND
1.64
1.43
ND
46.5
27.8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.90
2.20
ND
ND
ND
ND
ND
0.65
E 4.03
3.98
0.60
8.01
ND
15.4
D 0.96
D 0.96
9.14
10.5
7.31
ND
2.51
ND
7.52
J.75
ND
ND
ND
0.48
1.47
0.50
8.12
0.87
3.25
0.73
ND
ND
ND
ND
ND
3.09
8.03
0.32
D 0.21
0.28
ND
4.47
ND
28.9
D 0.75
3.37
32.8
D 13.2
1.89
1.17
4.82
D 0.37
D 0.35
4.69
1.10
0.58
0.15
0.53
0.06
0.43
0.54
0.65
0.69
0.38
D 0.38
D 0.59
D 0.53
0.77
D 0.43
ND
0 1.25
0.19
0.25
0.24
0.56
0.21
3.06
2.25
D 0.12
D 0.11
D 0.79
0.20
0.39
0.13
245.69
D 153.19
100.23
2220.9
121.03
D 31.28
D 192.3
2472.5
D 80.31
D 75.81
1125.6
0 1661.6
D 15.55
0 ND
D ND
D
D ND
D 282.4
D 349.34
D 163.17
D 9.04
D 92.73
D 180.95
D 133.2
D 190.55
D ND
ND
D 136.39
D 216.37
D ND
D 324
D 84
D ND
ND
D ND
D 102.65
D 87.24
D ND
D 44.76
D 46
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.96
ND
ND
ND
ND
2.90
ND
ND
0.45
ND
1.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.65
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.1
NO
ND
8.10
12.9
ND
ND
1.96 D
ND
ND
ND
D 13.52
ND
ND
ND
ND
ND
ND
ND
D ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
14.34
D 17.47
ND
ND
ND
ND
ND
0.10 D
8.29
5.29
ND
310 E
8.98
1.43
ND
263 E
1.70 D
1.69 D
66.4
26.7
ND
ND
1128. IE
ND
ND
ND
2.54
4.97
ND
ND
1.70 D
ND
9.33
ND
ND
7.29
ND
ND
ND
ND
1.70 D
22.96
78.44
ND
ND
ND
ND
ND
ND
60.8 95.1
40.1 68.6
12.2 46.5
1104 E 458 E
38.0 31.2
9.26 9.17
50.5 26.5
1247 E 687 E
23.7 32.0
23.2 29.7
503 E 347 E
231 E 499 E
ND 5.58
0.87 D 4.09
1782.7E 937. 37E
0.79 D 2.75
ND ND
45.0 92.6
35.9 84.7
22.4 66.5
ND 4.80
2.63 22.8
33.0 62.5
4.60 37.8
31.5 45.1
2.61 D 14.3
24.1 16.7
46.2 48.7
3.17 48.7
3.88 6.48
11.7 85.7 E
10.3 19.3
50.72 75.12
76.06 137.27
219. 80E 372. 82E
3.05 31.5
6.44 23.6
ND ND
7.56 18.9
ND 18.4
0.24 D 1.09 D
65.5
39.2
31.9
239 E
33.1
9.87
88.1
219 E
18.4
17.2
167
652 E
9.97
ND
96.30
0.42 D
ND
124
177
55.9
4.24
49.0
69.1
71.5
78.5
4.25
ND
34.2
119 E
1.12 D
178 E
39.0
13.54
28.26
144.40
55.8 E
47.2
ND
18.3
27.6
ND
16.0
ND
9.63
86.5
9.75
1.55 D
19.1
43.6
4.51
4.02
40.3
238 E
ND
ND
ND
ND
ND
20.8
42.6
10.5
ND
18.3
14.2
19.3
25.0
ND
ND
ND
45.5
ND
48.6
15.4
ND
ND
20.79
12.3
10.0
ND
ND
ND
ND
ND
ND
ND
6.39
ND
ND
ND
ND
ND
ND
ND
14.9
ND
ND
ND
ND
ND
ND
6.60
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.96
3960.0
3.96
ND
ND
ND
ND
ND
ND
ND
ND
ND
21.2
40.8
ND
ND
11.48
ND
ND
141.08
278.89
859.56
ND
ND
ND
ND
ND
1.43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
164
88.31
ND
ND
2.54
ND
1.96
ND
ND
0.81
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1 10C1
DIPHEN HCBUT
DIS
3078 DF009118
3078 DF023815
3078 DF023816
3079 DF019205
3079 DF019206
3080 OF023317
3080 DF023318
3081 DF024105
3081 DF024106
3082 DF023401
3083 DF023406
3084 DF024109
3085 DF024113
3085 DF024114
3086 OF023409
3086 DF023410
3087 DF023413
3087 DF023414
3087 DF023415
3088 DF023417
3088 DF023418
3089 DF019209
3089 DF019210
3090 DF019213
3090 DF019214
3091 DF019217
3092 DF023501
3092 DF023502
3093 OF024011
3093 DF024118
3094 DC017201
3095 DC038801
3095 OC038802
3096 OC035001
3096 DC035002
3097 OC038701
3097 OC038702
3097 OD071989
3098 OC038601
3098 DC038602
3098 ODOS1288
UB Carp
UB Sm Buffalo
PF Black Crappie
PF White Bass
UB Carp
UB Carp
PF Lin Bass
PF White Bass
UB Catfish
UB Carp
PF Lm Bass
UB Channel Catfish
UB Sea Catfish
PF Black Drum
UB Catfish
PF Red Drum
UB Carp
PF White Crappie
UP Bluegill
UB Channel Catfish
PF Bluegill
PF White Crappie
UB Carp
PF White Crappie
UB Channel Catfish
UB River Carpsucker
UB Carp
PF Uarmouth
PF Lm Bass
UB Sm Buffalo
BF Channel Catfish
BF Broun Bullhead
UB Channel Catfish
BF Broun Bullhead
UB Channel Catfish
BF Broun Bullhead
UB Carp
PF Broun Bullhead
UB Uhite Sucker
PF American Eel
UB Uhite Sucker
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.05
ND
16.0
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.8
0.31
1.27
2.77
8.30
ND
0.38
3.39
3.44
ND
5.61
ND
ND
ND
ND
1.05
ND
1.60
ND
ND
ND
1.80
1.33
4.92
0.11
2.69
ND
ND
0.63
8.95
3.92
13.2
2.15
13.8
0.45
0.39
0.44
35.0
17.4
39.9
0.65
0.98
D 0.17
D 0.25
0.20
3.52
0.16
D 0.34
0.51
1.11
0.33
0.75
8.74
13.79
0.61
2.76
D 1.68
0.08
D 0.70
0.45
0.23
0.21
D 0.62
D 0.25
0.96
D 0.16
1.30
0.14
0.17
D 0.50
4.70
ND
0.98
D 0.74
1.64
D 0.17
D ND
D 0.61
ND
0.98
ND
D ND
D 114.89
D 10.53
D ND
D 97.67
337.71
D ND
D 10.45
D 12.3
D 7
D ND
D 239.7
82.2
ND
D 1116.9
14.63
D 142.6
D 8.95
D 86.56
D 8.86
D ND
D 6.93
D 67.65
D 74.7
D 1887.5
D ND
D 67.6
D ND
D ND
D 4.3
1961.5
838.8
D 2974.6
D ND
D 4412.9
D ND
463.54
D
809.24
D ND
1042.6
ND
ND
ND
ND
ND
6.00
ND
ND
ND
ND
ND
ND
ND
ND
1.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.07
ND
ND
ND
ND
ND
2.77
ND
1.07
ND
1.42
ND
ND
9.71
ND
ND
ND
0.75
ND
18.0
ND
ND
ND
ND
ND
ND
ND
2.25
ND
ND
9.30
ND
ND
ND
ND
ND
ND
ND
0.51
ND
3.70
D ND
ND
ND
8.26
9.09
ND
D 5.04
18.0
D 4.35
3.94
D 4.94
6.87
6.26
4.46
ND
7.98
ND
D 2.94
ND
8.81
ND
ND
ND
ND
ND
8.10
ND
D 13.89
8.94
0.86
ND
ND
0.86
ND
ND
ND
ND
ND
D 7.64
ND
ND
ND
ND
ND
38.2
30.0
72.1
24.78
91.6
30.78
40.1
30.30
45.8
310
62.1
ND ND ND
31.8 38.4 29.9
ND 3.47 5.77
22.98 24.98 3.56
5.27 33.0 45.9
71 .8 103 103
2.44 D 6.00 1.90
0.81 D 3.61 6.03
NO 2.50 9.80
ND 7.00 ND
0.75 D 0.74 D ND
43.0 86.7 78.6
ND 45.7 36.5
37.96 21.69 1.61
98.7 E 399 E 455
D ND 6.67 7.10
ND 109 ND
1.59 D 1.81 D 5.55
D 12.8 20.7 36.6
ND 3.68 5.18
ND ND ND
ND 1.68 D 5.25
5.15 21.9 29.2
12.5 42.1 20.1
135 E 704 E 891
ND ND ND
ND 29.7 30.4
ND ND ND
ND ND ND
ND 1.10 D 3.20
321 E 616 E 710
E 171 E 282 E 244
E 551 E 877 E 1006
54.76 43.19 11.71
E 807 E 1556 E 1432
68.03 84.38 41.58
E 120 E 151 E 119
63.02 65.27 28.40
379 E 298 E 74.0
370 123 ND
473 400 87.4
ND
6.81
1.29 D
ND
13.5
27.1
D ND
ND
ND
ND
ND
23.3
ND
D ND
E 98.8 E
ND
24.3
ND
15.6
ND
ND
ND
11.4
ND
E 134
ND
3.80 D
ND
ND
ND
E 223 E
E 86.4 E
E 333 E
2.62
E 419 E
14.29
E 29.5
8.48
5.57
ND
6.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
24.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.4
ND
ND
ND
ND
ND
36.6
10.9
67.3
3.28
66.6
17.30
ND
11.10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.52
5.41
52.1
1.93
22.7
8.29
ND
3.74
ND
ND
ND
ND
ND
ND
55.21
ND
ND
10.34
ND
ND
ND
1.49
ND
ND
77.40
E 15.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.07
ND
ND
ND
ND
E 16.1
150.08
ND
270.28
ND
216.67
ND
809
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.27
ND
ND
ND
ND
23.0
3.53
2.37
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOB10TICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3100 DC019701
3101 DC019901
3103 DC036201
3103 DC036202
3104 DC020001
3104 DC020002
3105 DF02S001
3105 DF025002
3106 OE026801
3107 DE026901
3108 DE027001
3108 OE027002
3109 DE025001
3110 OE022501
3110 DE022502
3111 DH015802
3112 DE022401
3112 OE022402
3113 OE021101
3113 DE021102
3113 OD030789
3114 DE021201
PF White Perch
PF Broun Trout
WB Channel Catfish
WB Carp
PF Lm Bass
WB Carp
WB Carp
PF Lm Bass
PF Walleye
WB Carp
PF Walleye
WB Carp
WB Carp
BF Flat head Catfish
BF Carp
WB Silver Redhorse
WB Carp
PF Walleye
BF Channel Catfish
BF Carp
BF Channel Catfish
BF Carp
3115 DE021301 F WB Carp
3115 DE021302 F PF Catfish
3115 00101689 L WB Carp
3117 OE021501
3118 OE021601
3118 OE021602
3118 OE021603
3118 OD010689
3118 OD020488
3120 DE021801
3120 OE021802
3122 OE022001
3122 OE022003
3125 OE022301
3125 OE022302
3132 OE023201
3132 OD010588
3134 DE023403
3134 DE023405
PF Lake Trout
PF Walleye
WB Carp
WB Carp
WB Carp
PF Walleye
WB Carp
PF Bass
WB Carp
WB Redhorse Sucker
WB Carp
PF White Bass
WB Carp
WB Carp
WB Carp
WB Carp
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
23.7
ND
ND
ND
ND
ND
20.0
58.5
33.1
52.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.20
6.03
ND
ND
0.80
0.27
0.64
ND
ND
4.76
ND
ND
0.90
3.38
0.33
4.49
13.4
ND
ND
1.92
0.77
ND
6.05
4.68
5.26
1.27
3.10
5.68
2.79
ND
ND
ND
ND
ND
0.19
2.32
ND
1.37
0.69
11.5
1.26
5.21
7.30
ND
ND
0 1.71
0 1.06
0 0.35
0.34
1.19
5.07
0.68
0.14
0 0.19
0.32
0 0.20
0.61
0.50
0.20
1.22
0.60
D 1.79
0.15
0.55
1.25
1.30
D 0.52
5.63
53.8
3.16
ND
0.13
0.68
0.18
0.62
0 0.11
D 0.90
0.26
D 1.23
D 0.22
1.80
0 1.37
1.89
2.13
0.38
0.33
D ND
D ND
D ND
D 778.7
D ND
1783.4
D 8.62
0 ND
D 231.79
D 761.4
D 37.85
D 483.7
D 5863.4
D 1804.4
D 23809
D 271.46
D 176.1
D 12.2
D 537.6
D 2658.9
D 570.79
D 74
ND
5108.2
D 515.1
D 2516.5
D 832.6
D 2744.8
D 666.3
D 1938.2
D 854.05
D 17723.
D 473.66
D 3938.2
D 792.96
D 2804.3
D 3145.8
D 9223.9
D 13587.
NO
NO
NO
ND
1.11
ND
ND
ND
ND
ND
ND
ND
0.90
ND
ND
ND
ND
ND
ND
ND
ND
ND
17.1
27.5
19.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
12.71
ND
2.79
ND
D 23.64
17.5
ND
ND
ND
ND
ND
ND
D 1.35
ND
102
ND
ND
ND
ND
ND
ND
ND
104
34.9
101
ND
ND
ND
ND
ND
ND
3.86
1.07
ND
D 2.66
ND
0.52
4.40
8.60
3.46
ND
66.64
129
80.75
NO
106.43
184 E
ND
ND
18.5
46.4
1.01 D
25.1
D 115 E
6.03
1114 E
7.76
ND
ND
3.50
37.5
3.49
ND
E 259 E
126 E
E 250 E
47.2
5.10
11.9
24.6
11.9
8.10
196
D 63.7
6.26
ND
100
D 10.6
127
126
298 E
56.9 E
105.01
1076
123.28 43.51
E 2634
290.82 542.44
77.0
95.67
655
ND
ND
124
298
18.7
164
2833
159
9812
66.3
20.7
ND
52.9
418
54.8
ND
231
203
217
951
138
543
280
569
186
829
313
1102
20.5
863
127
684
792
2744
2234
234
70.04
E 522
ND
ND
E 62.7
274
12.2
185
E 2047
E 807
E 8766
115
71.8
5.30
132
E 928
141
36.4
E 220
E 227
E 204
E 1744
203
E 969
302
E 1058
245
622
293
E 7377
131
E 1896
E 354
787
815
E 3656
E 6093
E 1248
11.16
61.1
271.36 81.24
384
21.18
E 298
8.62
ND
E 22.3
110
5.94
86.5
E 630
E 710
E 3502
E 69.8
66.3
6.90
E 234
E 980
E 249
37.6
E 86.1
E 89.7
E 91.1
E 1848
142
E 753
184
E 839
161
251
151
E 7159
231
E 1005
E 263
700
859
E 2128
E 4363
83.7
2.96
E 96.5
E ND
ND
4.29
28.9
ND
23.1
E 182
E 110
E 453
12.6
17.3
ND
E 97.8
E 268
E 104
ND
5.36
15.1
18.9
E 446
27.0
E 197
42.0
E 221
66.2
36.4
28.2
E 1850
78.4
E 74.2
E 34.5
404
469
E 348
E 771
5.24
ND
85.10
ND
ND
10.4
ND
ND
ND
4.10
ND
ND
E 47.9
12.4
E 60.0
ND
ND
ND
17.4
E 27.4
18.5
ND
ND
ND
ND
E 72.0
ND
42.6
ND
45.9
ND
ND
4.08
E 229
9.60
ND
3.34
97.9
76.2
E 46.5
E 65.5
2.62
ND
37.51
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.31
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.01
370.17
5148
1392.0
ND
322.27
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
923
758
902
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
MD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.53
10.5
2.99
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOB10TICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3134 DE023406
3135 DE023S01
3136 DE023601
3137 DE023701
3138 DE023801
3140 OE024001
3140 DE024002
3141 DE024101
3141 DE024102
3141 DE024103
3143 DE024401
3143 DE024403
3144 OE024901
3145 DE026601
3146 DE026701
3146 DE026702
3147 DC035201
3148 DE027101
3148 DE027103
3149 OC038501
3150 OA008901
3150 00120187
3151 DA009101
3152 DA009201
3161 OC019801
3161 DC019802
3162 OJ024001
3163 DJ024002
3164 D0015702
3165 DD015704
3166 DD015706
3167 DD015708
3167 OD062388
3168 DD015711
3168 DD015712
3169 DD015713
3169 OD022789
3170 DD015715
3171 D0015717
3172 DD015719
3172 DD015720
WB Sucker
UB Carp
PF Northern Pike
UB Redhorse Sucker
UB Carp
PF Walleye
UB Carp
PF Northern Pike
UB Carp
PF Northern Pike
Rotten (catf)
UB Carp
UB Carp
UB N. Redhorse
UB Carp
PF Walleye
UB Carp
UB Carp
PF Walleye
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
UB Uhite Sucker
BF Black Bullhead
UB Uhite Sucker
UP Starry Flounder
UP Starry Flounder
UB Carp
UB Redhorse Sucker
UB Uhite Sucker
UP Bluegill
UP Bluegill
UB Carp
PF Lra Bass
UB Black Redhorse
UB Black Redhorse
UB Spotted Sucker
UB Spotted Sucker
UB Carp
PF Lm Bass
NO
NO
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
0.92
ND
NO
0.59
0.66
0.95
7.79
0.86
1.90
ND
4.05
ND
0.76
23.0
2.93
6.59
ND
ND
12.2
88.8
87.4
16.0
0.58
23.19
72.8
ND
0.17
47.4
7.74
1.41
1.75
1.19
2.02
NO
ND
ND
ND
0.07
1.95
ND
0.69
0 0.72
0.23
1.01
D 0.50
0 0.22
0 0.15
8.43
0 2.14
D 1.47
3.35
2.29
0.93
D 0.37
3.58
0.32
1.91
0.72
0.10
0.03
0.31
0.32
0.31
D 0.72
4.29
18.3
ND
D 0.35
2.08
0.65
0 0.56
D 0.14
D 0.10
D 0.36
0.10
0.47
0.43
0.48
D 0.36
D 0.50
0.23
D 25240
D 1521.4
D 8
D ND
0 13362
0 1467.4
0 4390.3
4117
0 22695.
D 3678.1
206.97
D 435.6
D 22283.
D 643.2
4137.6
D 68.72
D 786.1
D 1824.1
D 363.9
D 51
D 669.98
D 646.07
D 5365.9
D 479.7
ND
1697.5
525.54
D 82.01
1033.4
0 548.2
0 11.8
D 3.13
D 14.43
D 354.59
D 1.36
D 10.1
D 9.55
D 5.14
D 2.03
0 2803.4
0 293.6
ND
ND
ND
0.62
ND
1.41
0.95
ND
ND
ND
ND
ND
12.6
ND
ND
ND
ND
ND
ND
ND
3.30
2.86
ND
ND
1.31
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
1.13
ND
D ND
79.1
53.3
D 83.9
50.5
283
93
ND
2.10
267
ND
ND
ND
5.00
ND
ND
ND
1.08
0.61
4.43
ND
D 20.30
49.5
ND
ND
ND
ND
4.50
ND
1.10
ND
ND
ND
NO
ND
ND
ND
ND
253
D 36.2
NO
8.82
E 1194
E 388
E 788
E 609
E 3334
E 598
4.87
20.6
E 3123
26.1
224
6.71
53.7
13.7
3.40
3.00
D 61.8
D 58.9
403
ND
52.72
E 339
ND
ND
NO
25.5
ND
MD
D ND
1.97
ND
ND
NO
ND
ND
20.9
ND
4664
273
6.00
19.0
E 7801
E 660
E 2093
E 1675
E 9981
E 1639
64.2
125
E 13038
244
E 2149
39.2
E 131
267
82.7
12.5
256
243
E 3153
19.2
44.07
E 690
47.1
5.71
299
237
ND
ND
ND
D 27.0
ND
ND
NO
ND
ND
298
21.6
E 11880
E 667
2.00
8.67
E 2343
E 256
E 1008
E 962
E 5180
E 824
87.0
167
E 5317
E 248
E 1261
17.2
E 227
E 792
139
18.3
172
169
E 1388
80.6
50.87
E 311
178
26.6
E 366
E 180
7.30
NO
5.81
98.6
ND
ND
ND
NO
ND
E 1140
110
E 7582
E 478
D ND
1.08
E 1228
E 98.5
E 330
E 622
E 2816
E 414
50.9
108
E 508
E 99.8
E 397
5.61
E 312
E 613
115
17.2
96.5
95.9
E 332
218
24.72
E 227
E 208
38.6
E 289
E 87.1
NO
3.13
7.52
E 151
1.36
10.1
9.55
4.22
2.03
E 1021
E 119
E 861
E 66.1
ND
D ND
E 570
E 10.2
E 69.8
E 174
E 946
E 102
ND
12.9
E 18.3
25.3
E 92.2
ND
E 57.4
E 125
23.8
ND
47.4
47.7
E 68.1
139
4.11
E 72.3
E 63.8
11.1
E 74.9
E 18.6
ND
ND
ND
E 58.1
D ND
ND
ND
0.92
D NO
E 280
E 36.7
ND
ND
NO
ND
E 133
ND
14.6
E 24.5
E 150
E 8.1
ND
ND
ND
ND
14.4
ND
ND
13.4
ND
ND
27.6
23.5
17.4
22.9
ND
8.73
22.1
ND
4.53
ND
ND
ND
ND
15.1
ND
NO
ND
D ND
ND
E 43.5
6.30
ND
ND
ND
ND
13.9
ND
2.06
ND
5.85
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.30
4.60
ND
ND
ND
ND
6.54
ND
ND
ND
ND
ND
NO
2.82
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
38.2
ND
ND
0 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
D ND
ND
ND
198.10
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XEN08IOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 SCI
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3173 DD01S722
3174 DD015724
3175 DD015801
3176 DD01S803
3177 DD01580S
3177 OD100488
3178 ODD15807
3179 DD015809
3180 00015812
3181 DD015814
3182 DD015815
3182 DD015816
3183 DD015817
3183 DD015818
3184 OD015820
3185 00015821
3186 00015824
3187 00015902
3188 DDO15903
3188 DD015904
3189 00015905
3189 00092188
3190 00015907
3191 OJ024003
3191 DJ02400S
3192 DJ024007
3192 DJ024009
3193 DC039001
3195 DH020104
3195 OH020105
3196 DH020108
3198 DH020111
3199 DH020101
3199 DH020103
3200 DH020112
3203 DJ024018
3205 DJ024024
3206 DJ024103
3208 DJ024109
3212 OJ02&120
3212 DJ024121
F UB Channel Catfish
F UB Channel Catfish
F UB Channel Catfish
F UB Spotted Sucker
F UB Carp
L UB Carp
F UB North Hogsucker
F UB Golden Redhorse
F PF Lm Bass
F UB Carp
F PF Rock Bass
F UB Carp
F UB Carp
F PF Sauger
F PF Uhite Crappie
F UB Channel Catfish
F UP Southern Flounder
F UP Simmer Flounder
F UB Carp
F PF Lm Bass
F UB Carp
L UB Carp
F US Carp
F UP Starry Flounder
H Soft Shell Clams
F UP Starry Flounder
H Soft Shell Clams
F PF Sm Bass
F UB Carp
F UB Chub
F UB Sucker
F UB Sucker
F UB Carp
F UB Carp
F UB Sucker
F UB Carp
0 Crayfish (whole)
F UB Sucker
F UB Sucker
F BF Catfish
F UB Carp
NO
NO
NO
NO
ND
ND
ND
NO
ND
ND
ND
16.7
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
20.0
ND
163
ND
ND
ND
20.5
64.8
153
1.83
ND
2.45
NO
1.73
1.30
0.74
0.96
ND
14.1
ND
1.70
2.13
ND
ND
570
ND
ND
4.64
ND
2.76
4.48
1.07
ND
ND
ND
ND
0.91
0.58
1.48
ND
29.7
1.11
NO
3.11
2.13
ND
5.24
ND
E ND
ND
0 1.50
0.40
0 0.53
0.10
0 ND
0 0.21
D ND
D 0.19
ND
0.32
0.31
0 0.279
0 1.19
0.52
0.31
4.43
0.24
0.12
J 2.61
0.57
0.99
1.44
D 0.16
0.25
ND
0.21
0.11
D 0.35
D 3.64
D 4.59
0.51
8.85
D 0.27
0.21
1.04
0 3.41
0.09
7.33
0.59
0.33
0.79
D 485.52
D 2.54
D 170.6
D 21.72
67.37
D 63.79
ND
D 79.63
ND
D 1367.4
D 780.42
D 24118.
D 1218.0
D 93.79
D ND
315.1
D 19.08
D ND
J 3309.2
D 32.02
D 1029.3
D 1389.3
D 541.5
D 8
ND
D 7.27
D 5.79
D 1064.3
382
516.9
D 31.29
256.6
D 64.24
D 23.47
D 80.09
2043.1
D ND
1536.9
D 31.12
D ND
D ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.792
5.02
ND
ND
ND
ND
ND
10.4
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.93
ND
ND
ND
ND
1.32
ND
ND
ND
ND
ND
ND
ND
1.98
NO
NO
ND
ND
ND
ND
ND
1.83
D 100
4.20
ND
ND
ND
ND
ND
J 26.5
ND
ND
ND
ND
ND
ND
ND
5.79
ND
ND
ND
D 3.62
8.00
ND
ND
6.50
D ND
ND
ND
ND
ND
ND
ND
ND
2.67
ND
NO
ND
ND
ND
ND
25.4
26.5
E 1754
13.8
ND
ND
37.2
ND
ND
28.3
ND
19.4
29.4
3.30
ND
ND
ND
ND
20.7
15.8
20.6
2.52
23.9
ND
ND
9.79
14.5
ND
ND
ND
ND
ND
10.3
ND
18.7
1.67
1.17
1.09
ND
3.13
ND
265
E 322
E 9934
167
3.29
ND
138
ND
ND
443
ND
154
206
75.4
ND
ND
ND
ND
456
40.4
73.1
3.35
59.6
ND
ND
7.60
208
ND
236
ND
ND
ND
97.9
ND
42.0
D 6.65
D 18.3
D 15.5
ND
22.5
ND
E 450
E 356
E 9872
E 393
25.1
ND
83.6
10.1
ND
E 1297
11.6
E 344
E 484
E 166
3.30
ND
1.60
ND
E 420
111
152
6.72
81.2
24.1
8.36
31.5
E 890
ND
E 702
7.62
ND
ND
265
2.54
68.9
13.4
33.4
32.5
ND
38.9
ND
E 521
E 65.2
E 2061
E 456
47.9
NO
56.1
8.98
ND
E 1270
16.9
E 396
E 519
E 212
4.70
ND
D 5.67
ND
E 140
E 164
E 205
10.8
66.9
30.9
12.5
24.7
E 713
ND
E 502
23.5
ND
ND
E 103
ND
E 23.9
ND
14.5
14.7
ND
15.1
ND
E 106
E 8.89
E 346
E 160
17.5
ND
ND
ND
ND
E 234
3.52
E 103
E 132
E 74.0
ND
ND
ND
ND
E 27.6
E 50.8
E 66.2
3.35
17.0
9.24
2.61
ND
E 186
ND
E 84.3
ND
ND
ND
9.32
ND
9.71
ND
ND
NO
ND
ND
ND
E ND
ND
E 50.4
E 19
ND
ND
ND
NO
NO
E ND
ND
E 12.9
E 18.9
10.8
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
E 30.3
ND
12.6
ND
ND
ND
NO
ND
2.74
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
IRIFLUR PCA
BIPHENYL TOT
PCBS
XEN08IOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 SCI
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3213 DJ024123
3215 DJ023705
3216 DJ023707
3216 DJ023708
3216 QD022388
3217 DJ023710
3218 DJ023711
3219 DJ023713
3219 DJ0237U
3220 OJ023903
3221 OJ023905
3222 OJ023907
3223 OJ023717
3224 OJ023715 M
3226 DJ023721 H
3227 DJ023723 H
3231 DJ023910
3231 DJ023911
3234 DH020301
3235 DH020303
3236 DH020305
3237 DH020308
3237 OD080988
3238 DJ023918
3241 DJ023924
3245 DJ023624
3246 DJ022109
3248 DJ022502
3248 00050588
3249 DJ022503
3249 DJ022504
3250 DJ022506
3252 DJ022509
3252 DJ022510
3252 OD020989
3252 00052588
3256 DJ022518
3258 DC038901
3258 DC038902
3259 DB000466
3259 DB000473
UB Squawfish
UB Sucker
PF Squawfish
UB Sucker
UB Sucker
UB Sucker
PF Squawfish
UB Uhite Sturgeon
PF Uhite Sturgeon
UB Bridgelip Sucker
UB Sucker
UB Sucker
UP Starry Flounder
Soft Shell Clams
Pacific Oysters
Pacific Oysters
PF Sm Bass
UB Carp
UP Squawfish
UB Uhite Sucker
UB Largescale Sucker
UB Largescale Sucker
UB Largescale Sucker
UP Dotly Varden
UP Dolly Varden
UP Flathead Sole
UP Flathead Sole
UB Composite Bottom
UB not available
PF Brook Trout
UB Sucker
UB Sucker
PF Lm Bass
UB Sucker
PF Lm Bass
UB Sucker
UB Sucker
PF Spot
UB Croaker
UB Goldfish
PF Lm Bass
NO
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.4
ND
ND
ND
ND
ND
ND
NO
1.16
16.9
ND
0.92
1.32
2.49
ND
0.18
ND
6.74
ND
0.68
ND
ND
ND
ND
ND
ND
ND
12.5
8.55
0.35
0.33
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
J ND
ND
ND
0.22
2.20
1.15
ND
ND
D NO
0.79
0.06
D 0.73
0 1.09
D 0.70
0.06
0 0.31
NO
ND
1.47
D 0.20
ND
1.20
0.24
0.14
0.15
0.89
0.17
0.68
0.42
D 0.45
0 0.31
0.19
0.53
ND
0.18
0.83
ND
0.09
0.25
0.14
0.14
0.28
0.07
0.90
0 1.03
0 1.15
D 0.55
2.55
0.15
102.74
D 722.01
D 37.1
D 127.9
D 173
D 8.2
D 55.6
D 190.84
23.91
174.72
D 265
0 92.36
10.48
D ND
D 2.51
D ND
D 2.89
D 330.9
D 33.3
0 22.01
D 202.12
0 741.17
D 683.21
D ND
D 142.92
131.56
D 17.4
0 56.3
112.32
0 1.27
D 563.8
D 313.6
0 1.38
D 182.29
D 3.18
D ND
D 53.9
D ND
0 486.4
82276.
D 4539.4
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.34
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
5.63
ND
235
4.41
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
1.99
ND
ND
1.10
ND
ND
ND
ND
3.90
ND
ND
ND
8.85
ND
E 1132
32.0
0.98
4.91
ND
ND
ND
ND
ND
ND
ND
0.72
ND
0.63
ND
ND
MD
ND
ND
ND
ND
ND
ND
21.2
15.9
ND
ND
D 5.02
ND
ND
ND
ND
ND
ND
ND
J 4.59
ND
ND
ND
69.26
10.6
E 4748
241
D 9.86
149
ND
15.0
21.7
ND
ND
7.01
ND
0 41.3
11.7
D 24.9
ND
ND
ND
ND
ND
13.3
ND
ND
18.1
205 E
174 E
ND
2.72
10.1
ND
ND
1.62 D
ND
11.4
10.9
ND
J 61.4
ND
ND
ND
215.80
94.6 E
E 42685 E
1929 E
32.9
381
12.4
55.1
71.0
NO
20.8
57.9
4.97
67.1
129
37.5
2.50
NO
NO
NO
NO
73.5
14.0
14.9
105
311
291
ND
38.1
47.3
NO
20.4
22.1
ND
60.6
92.4
ND
71.2
0.80
NO
30.5
251.35
192
23843
1495
45.5
E 160
19.8
57.8
68.6
8.20
29.7
E 95.4
15.4
55.1
107
25.3
7.98
ND
2.51
ND
2.89
163
19.3
4.77
E 72.5
E 197
E 195
ND
81.5
51.3
13.0
21.3
70.1
1.27
E 265
E 157
1.38
41.2
D 2.38
ND
23.4
73.36
E 155
E 7513
E 660
13.5
27.1
4.90
ND
11.7
ND
5.10
E 29.3
3.54
10.5
17.3
4.03
ND
ND
ND
ND
ND
81.1
ND
ND
6.52
E 6.97
E 7.31
ND
20.6
15.0
4.40
14.6
17.4
D ND
E 187
E 53.3
D ND
J ND
0 ND
ND
ND
3.64
E 34.2
E 1663
E 137
ND
ND
ND
ND
NO
ND
ND
1.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
0.85
ND
ND
NO
ND
E 39.8
ND
ND
ND
NO
ND
ND
ND
ND
E 369
41.0
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0 ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 81.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
629.76
ND
E 7.18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 SCI
6C1
7C1
8C1
9C1
10C1
OIPHEN HCBUT
DIS
3259 DB069101
3260 OB000493
3261 DY026002
3262 DY026004
3266 DY022701
3266 DY022702
3266 ODD12389
3267 DY022101
3267 DY022102
3270 OY022108
3271 DY022110
3272 DY022112
3273 DY022113
3273 DY022114
3274 OY022116
3276 OY022119
3278 DY022124
3281 DY022205
3282 DY022206
3282 DY022207
3283 DY022209
3285 DY022212
3285 DY022213
3286 OY022215
3287 DY022216
3288 DY022217
3288 DY022218
3289 DY022219
3289 DY022220
3290 DY022221
3290 DY022222
3294 DJ022111
3294 DJ022113
3295 DJ0221U
3296 DB040101
3297 DB041501
3298 DB041601
3298 DB041604
3299 DB040601
3299 DB040604
3299 00040601
F WB Sucker
F WB Carp
F WB Striped Mullet
F WB Tilapia Tilapia
F PF Black Crappie
F WB Channel Catfish
L PF Black Crappie
F PF Rainbow Trout
F WB Sacramento Sucker
F WB Sucker
F WB Sucker
F WB White Surfperch
F WB Sculpin
F WB Surf Smelt
F WB Sculpin
F WB Walleye
F WB Sacramento Sucker
F WB Sucker
F BF Flathead Catfish
F WB Carp
F WB Carp
F WP Stingray
F WB Diamond Turbot
F WB Carp
F WB Tilapia Zilli
F PF Squaufish
F WB Sucker
F WP Bocaccio
F WB Sculpin
F PF Redear Sunfish
F WB Blackfish
F WP True Cod
H Mussel
F WP Atlantic Salmon
F WB White Sucker
F WB Carp
F WB Carp
F PF Lm Bass
F WB White Sucker
F PF Lm Bass
L WB Sucker
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
116
43.8
19.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.05
ND
ND
ND
ND
ND
ND
ND
0.56
0.62
ND
ND
0.54
ND
ND
ND
ND
ND
E ND
ND
ND
NO
ND
0.425
4.35
ND
ND
ND
ND
0.31
64.2
ND
ND
ND
ND
ND
2.79
ND
ND
ND
ND
D 3.15
0.31
ND
ND
0.10
0.69
0.12
0.11
D ND
D ND
1.47
1.27
D 0.56
0.16
0.10
0.88
ND
0.45
0.25
0.57
0.95
0.33
ND
J 0.700
ND
0.15
1.09
0.45
1.14
D 0.19
1.55
0.51
0.30
0.07
0.17
0.73
1.68
0.14
0.60
0.42
0.24
124192
D 293.2
690.9
6.3
D ND
D 13.6
D ND
D ND
3.75
34.9
D ND
D 126.72
D 25.21
D ND
D 76.21
D ND
121.8
D 4.47
D 6.1
D 16.79
D 41.42
D 725
60.3
J 199.63
61
D 59.37
D 70.4
D 35.5
D 90.57
D 6.62
D 1217.4
D 16.31
D ND
D 23.84
D 579.63
D 754.3
D 3029.4
D 126.25
D 6345.7
D 610.32
D 4057
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.69
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.26
ND
ND
5072
ND
35.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.06
ND
ND
ND
45.6
ND
109
3.62
24.0
E 18344
20.3
29.9
ND
ND
ND
ND
ND
0.94
ND
ND
ND
ND
ND
ND
0.21
1.05
ND
ND
ND
ND
3.70
ND
8.00
2.30
ND
ND
ND
2.08
ND
12.1
ND
D 0.32
ND
14.4
42.3
243
1.75
E 437
43.7
E 160
E 60764
141
97.3
ND
ND
ND
ND
ND
D ND
ND
ND
8.35
ND
ND
ND
D 1.64
D 23.2
ND
ND
ND
ND
78.5
ND
J 64.0
D 11.4
ND
ND
2.76
D 17.6
ND
199
ND
D 0.88
ND
109
300
E 1006
D 24.5
E 2478
E 247
E 1246
E 29578
97.9
E 159
1.78
ND
ND
ND
ND
ND
17.9
ND
49.9
12.1
ND
8.31
D 2.62
50.1
2.02
1.51
5.88
ND
223
30.4
E 78.7
25.1
26.3
30.8
13.8
39.5
2.41
E 505
6.86
D 0.86
8.87
E 182
E 260
E 791
40.7
E 1901
E 193
E 1401
E 8862
34.0
E 266
D 4.52
ND
13.6
ND
ND
2.81
17.0
ND
59.1
11.7
ND
47.7
0.51
42.4
D 2.45
D 4.59
7.22
32.6
E 325
29.9
E 40.1
22.2
30.3
39.6
15.8
29.3
0 4.21
E 412
9.45
D ND
13.4
E 208
E 125
E 668
43.0
E 1083
E 97.5
E 887
E 1332
ND
E 92
ND
ND
ND
ND
ND
ND
ND
ND
9.37
1.41
ND
20.2
D ND
5.05
D ND
ND
ND
8.82
E 76.9
ND
8.83
ND
2.77
ND
3.14
2.09
ND
E 84.7
ND
ND
1.57
E 60.9
27.0
E 246
16.3
E 311
E 25.5
E 300
177
ND
E 11.6
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
17.9
ND
J ND
ND
ND
ND
ND
D ND
ND
4.60
ND
ND
D ND
5.33
ND
E 29.8
ND
E 22.5
ND
E 39.0
63.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
J ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3300 DB040201 F UB White Sucker
3300 DB040204 F PF Sm Bass
3300 QD021389 L WB Channel Catfish
3301 DB041101 F UB Carp
3301 D8041104 F PF Northern Pike
3301 00030989 L PF Northern Pike
3302 DB041901 F UB White Sucker
3302 DB041904 F PF Lm Bass
3303 DB042301 F UB White Sucker
3303 DB042304 F PF Sm Bass
3303 OD102588 L UB White Sucker
3304 DB041001 F PF Northern Pike
3304 DB041004 F UB White Sucker
3304 OD041004 L UB White Sucker
3305 DB042001 F UB Channel Catfish
3305 DB042004 F PF Sm Bass
3305 OD 11 0388 L UB Channel Catfish
3306 DB041801 F UB White Sucker
3306 DB041804 F PF Sm Bass
3306 OD041801 L UB White Sucker
3307 DB042101 F UB White Sucker
3308 DB040001 F PF Northern Pike
3309 DB041301 F UB White Sucker
3310 DC032701 F UB Bullhead
3310 DC032702 F PF Walleye
3311 DC032801 F UB Redhorse Sucker
3311 DC032802 F PF Sm Bass
3312 DC033101 F UB Redhorse Sucker
3312 DC033102 F PF Sm Bass
3313 DC033201 F UB Redhorse Sucker
3313 DC033202 F PF Sm Bass
3314 DC033301 F UB Channel Catfish
3314 OC033302 F PF White Bass
3315 DC033401 F UB Carp
3315 DC033402 F PF Lm Bass
3316 DC033501 F UB White Sucker
3317 DC033601 F UB White Sucker
3318 DC033701 F UB White Sucker
3319 DB041401 F UP Winter Flounder
3320 DB041412 F UP Bluefish
3321 DB040401 F UP Winter Flounder
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.28
ND
ND
4.21
1.28
1.25
0.39
ND
ND
ND
ND
ND
1.31
2.89
ND
ND
ND
ND
ND
ND
ND
ND
1.93
1.23
1.08
1.37
0.37
3.08
1.59
0.62
ND
7.77
0.78
ND
ND
0.46
1.78
1.50
NO
ND
1.29
D 0.13
0.21
0.25
12.1
D 0.18
D 0.13
D 1.41
0.11
0.30
0.20
0.81
0.09
D 0.46
0.64
1.48
0.13
1.56
0.43
0.20
0.50
0.47
0.12
D 0.37
D 1.70
D 1.63
D 0.15
D 0.24
0.33
D 1.24
D 0.21
0.42
1.95
D 0.76
0.18
0.19
D 0.32
D 4.93
D 1.53
0.14
0.70
D 0.35
0 1896.2
D 205.47
D 160.97
9305.9
D 399.86
D 474.21
D 2561.8
D 93.6
D 6055.6
D 755.66
D 8371
D 127.2
D 4770.9
D 8811.7
D 5579.1
D 85.83
D 5562.8
D 7435.9
D 3172.0
D 12027
D 488.7
D ND
D 62.47
D 372.6
D ND
D 285.95
D ND
D 741.47
D ND
D 326.61
D ND
D 3201.5
D 502.84
D 65.9
D 4.58
D 1783.5
6.38
D 51.5
D 129.77
D 279.73
D 312
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.00
1.27
5.55
ND
ND
ND
ND
ND
ND
0.63
ND
1.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
46.7
5.16
4.81
ND
ND
17.1
0.86
31.2
ND
5.98
16.1
10.5
ND
6.26
D 146
52.3
249
ND
ND
ND
ND
2.40
ND
D 2.75
ND
D 5.94
ND
0.23
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16.1
ND
1.62
1163
60.5
68.6
30.8
ND
879
D 65.0
1302
ND
162
364
116
1.81
105
E 698
E 279
E 1122
3.20
ND
ND
19.5
D 16.9
6.55
14.89
6.77
42.23
0.61
D 1.46
37.3
4.39
ND
ND
0.59
ND
ND
3.92
2.73
12.0
331
32.6
D 27.6
E 4133
E 175
E 207
407
14.3
E 3813
E 460
E 5619
29.0
E 1526
E 3170
1154
22.9
1034
E 2477
E 1127
E 4490
77.6
ND
2.97
62.8
29.6
35.6
25.30
95.6
84.98
D 20.8
D 10.01
403
62.2
11.6
ND
D 187
ND
3.68
28.0
43.2
64.8
E 619
69.6
53.9
E 2256
E 98.8
E 119
E 926
36.0
E 1076
E 183
E 1106
50.8
E 1823
E 3316
E 1989
32.9
E 1925
E 2064
E 835
E 3174
E 169
ND
29.3
153
40.9
81.4
29.97
E 254
86.64
116
11.49
E 1261
E 188
27.1
1.11
E 1019
6.38
27.3
53.2
111
E 113
E 622
E 75.1
E 56.9
E 1313
E 50.2
E 62.5
E 910
35.5
E 206
E 35.9
E 243
E 39.2
E 1013
E 1634
E 1635
22.5
E 1735
E 1280
E 546
E 1890
E 172
ND
27.0
E 107
6.27
E 110
9.07
E 279
25.04
E 141
1.79
E 1229
E 192
22.2
D 3.47
E 517
ND
16.9
E 38.9
E 108
E 100
E 258
E 26.3
E 19.8
E 357
10.2
E 12.3
E 262
7.80
E 52.0
10.9
E 56.2
8.20
E 211
E 286
E 580
5.72
E 621
E 586
E 261
E 880
E 55.4
ND
3.20
E 30.3
4.94
E 44.3
0.43
E 93.7
2.52
E 37.8
D ND
E 260
E 51.9
5.00
ND
E 52.7
ND
3.62
5.75
E 14.8
E 22.2
E 47.4
1.87
1.15
E 37.2
ND
ND
E 26.0
ND
12.5
ND
13.6
ND
E 30.0
E 25.6
E 94.6
ND
E 126
E 168
E 65.7
E 203
11.5
ND
ND
ND
ND
8.10
D ND
E 12.4
ND
10.4
ND
E 11.2
4.35
ND
ND
7.25
ND
ND
ND
ND
ND
2.72
D ND
D ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
10.6
E 14.9
4.76
E 13.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
101
ND
83.22
ND
250.37
ND
24.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.84
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND .
ND
ND
ND
ND
ND
0.36
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
£
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PC8S
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
D1PHEN HCBUT
D1S
3321 QD100688
3323 DB041206
3324 DB041252
3325 DB041218
3326 DB041208
3327 DB040301
3327 OB040315
3328 OD029111
3329 DDO16003
3330 D0029110
3331 DDO16007
3332 DDO16009
3333 DD016012
3334 DD016013
3335 DD016015
3335 DD029101
3335 DD029102
3335 DD029103
3335 QD091588
3336 DDO16004
3336 DDO16006
3336 DD016017
3336 DD016018
3337 DD016019
3338 DD016022
3339 DD016023
3340 DD029114
3341 DD016104
3341 OD081788
3342 DD016105
3343 DD016107
3344 DD016109
3345 DD016111
3346 DD016113
3346 DD016114
3347 OD016115
3348 00016117
3348 DDO16118
3349 00016119
3350 DD016121
3350 00016122
L UP Winter Flounder
F UP Winter Flounder
F UP Bluefish
F UP Bluefish
F UP Bluefish
F UP Bluefish
F UP Bluefish
F UB Carp
F UB Bowfin
F UB Spotted Sucker
F UB Carp
F UP Spotted Drun
F UB Sea Catfish
F UB Sea Catfish
F UP Spot
F UP Red Drum
F UB Southern Flounder
F UP Sheepshead
L UP Red Drum
F UP Black Drum
F UP Sheepshead
F UP Red Drum
F PF Spotted Seatrout
F UB Spotted Sucker
F UB Spotted Sucker
F UB Carp
F UB Channel Catfish
F UB Catfish
L UB Catfish
F UB Spotted Sucker
F UB White Sucker
F UB Carp
F UB Redhorse Sucker
F UB Creek Chubsucker
F PF Lm Bass
F UB Carp
F PF White Perch
F UB Blue Catfish
F UB Carp
F UB Carp
F PF Lm Bass
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
1.23
0.45
1.67
ND
0.35
ND
0.67
8.11
2.32
0.85
ND
ND
1.34
11.7
1.99
1.17
1.79
0.82
ND
ND
ND
ND
1.45
121
0.65
8.90
0.75
0.56
12.5
8.28
4.67
1.49
1.44
ND
14.7
0.28
2.82
6.17
ND
ND
D 1.28
D 0.07
D 0.48
0.08
D 0.19
2.37
0.65
D 0.67
1.05
D 1.47
D 0.28
0.85
0.39
D 2.95
1.83
D 0.67
D 0.43
D 0.74
D 0.31
3.34
0.42
0.06
0.23
D 1.33
E 2.30
D 0.87
2.38
D 5.30
D 5.89
13.8
0.93
1.01
D 0.80
D NO
0.10
2.16
D 0.26
0.18
0.10
0.51
0.24
D 303.09
D 227.46
D 411.27
D 184.81
0 394.07
D 628.2
D 1319.2
D 3305.7
D 26.3
D 144.85
D 144.3
D 12.3
D 89.57
1066.2
D 344
D 522.57
D ND
D 1327.8
D 611.44
37.48
D 210.12
D 15.67
D 15.25
D 41.47
D 429.25
D 757.1
D 78.66
456.67
439.4
132.8
D 16.27
D 1444.2
D 86.21
74.65
D ND
D 1935.0
D 6.04
D 38.22
D 550.06
D 569.5
D 34.07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.35
ND
ND
ND
ND
NO
ND
ND
ND
1.44
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.01
ND
ND
0.91
ND
ND
ND
ND
ND
ND
0.24
ND
ND
ND
ND
ND
ND
19.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
D 20.2
ND
2.38
ND
0.81
ND
ND
ND
7.79
3.96
9.77
2.74
6.77
17.6
27.0
1.50
D 5.37
ND
ND
ND
17.6
ND
1.88
D 0.83
ND
ND
2.12
ND
ND
ND
ND
20.8
13.9
11.6
ND
ND
ND
ND
7.19
ND
17.8
ND
32.2
ND
D 2.63
2.56
ND
ND
62.8
45.4
95.5
38.8
87.2
164
368
6.41
22.9
ND
ND
1.77
14.7
ND
D 14.4
D 4.62
8.60
2.31
D ND
3.22
ND
ND
2.98
90.7
173
9.07
51.2
47.3
21.2
ND
71.6
3.11
10.6
ND
E 335
ND
7.41
53.3
67.0
ND
113
88.3
E 157
84.0
E 161
E 221
395
E 987
8.73
54.1
30.5
ND
D 25.9
138
22.0
22.2
6.91
27.4
D 7.73
ND
28.6
4.49
2.55
5.27
E 142
E 218
24.6
114
104
64.2
12.0
E 249
23.2
16.3
NO
E 503
2.56
8.07
162
226
10.8
98.5
E 77.6
E 122
E 51.9
E 121
E 186
E
E 1371
9.66
E 52.3
90.0
12.3
51.1
E 539
45.8
39.9
5.46
70.3
28.5
3.88
82.5
9.29
8.81
12.6
E 146
E 251
25.9
E 227
E 219
47.4
4.27
E 322
44.4
8.31
ND
E 720
3.48
14.2
E 229
E 240
18.3
21.0
E 12.2
E 27.0
E 7.37
E 18.1
E 39.6
E 439
ND
E 8.71
23.8
ND
10.8
E 259
64.8
97.7
17.14
186
98.7
4.28
E 51.1
1.89
3.89
1.62
E 26.4
E 88.8
7.49
E 57.8
E 58.5
ND
ND
E 192
15.5
ND
ND
E 289
ND
5.10
E 86.0
E 36.5
4.97
ND
ND
ND
ND
ND
ND
E 96.3
ND
0.56
ND
ND
ND
E 79.1
150
E 239
13.78
E 593
E 327
14.4
30.0
D ND
ND
D ND
ND
12.4
ND
6.67
10.6
ND
ND
E 379
ND
ND
ND
E 53.5
ND
ND
E 17.2
ND
ND
ND
ND
ND
ND
ND
ND
17.4
ND
D ND
ND
ND
ND
18.8
61.4
E 102
ND
E 413
E 135
12.8
14.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 207
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E ND
ND
ND
ND
ND
ND
ND
E ND
E 5.49
48.98
E 29.5
E 12.2
E ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
E 16.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.50
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
OIPHEN HCBUT
OIS
3351 DD016124
3352 OF023723
3352 OF023724
3352 00022089
3353 DF024121
3353 OF02A122
3354 DY022301
3354 DY022302
3355 OY022303
3355 DY022304
3356 OE030201
3357 DY022224
3360 DD029117
3375 DD016305
3375 DDO16306
3375 OD071189
3376 DD016307
3376 DDO16308
3377 DD016309
3377 DD016310
3378 DDO16311
3378 00029115
3385 DD016401
3385 00101888
3395 DD016421
3401 DD016509
3401 00016510
3403 00016513
3403 00016514
3404 00016515
3404 ODD16515
3409 OB040701
3409 DB040706
3411 DB040501
3412 OB040901
3412 OB040907
3414 DC036203
3414 OC036204
3415 DC036205
3415 DC036206
3419 DC036207
UB Carp
PF Crappie
WB Carp
PF Crappie
BF Blue Catfish
UB Sm Buffalo
UB Carp
PF Lin Bass
UB Carp
PF Lm Bass
UB Carp
UB Sacramento Sucker
UB Carp
UB Carp
PF Lm Bass
PF Lm Bass
UB Carp
PF Lm Bass
UB Carp
PF Lm Bass
UB Spotted Sucker
UB Greyfin Sucker
UB Redhorse Sucker
B not available
UB Redhorse Sucker
UB Carp
PF Lm Bass
UB River Carpsucker
PF Lm Bass
UB Carp
UB Carp
UB Carp
PF Lm Bass
UB Redhorse Sucker
PF Sm Bass
UB Carp
PF Sm Bass
BF Channel Catfish
PF Sm Bass
BF Channel Catfish
UB White Sucker
NO
NO
10.9
NO
40.3
3.21
NO
NO
26.8
NO
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.18
ND
0.29
ND
0.57
5.95
18.4
ND
21.9
ND
2.00
1.43
16.4
647
9.70
14.45
334
3.09
187
1.82
1.56
4.14
1.21
1.09
9.59
1.67
ND
27.7
0.36
ND
0.59
1.92
ND
13.0
ND
ND
ND
2.99
ND
2.53
ND
0.68
0.14
D 0.19
0.18
D 0.34
0.29
0.96
0.14
2.37
0.13
D 26.4
D 0.35
0.51
E 15.3
0.52
0.80
E 1.92
0.15
0.90
D 0.30
D 0.52
4.20
D 0.60
D 0.44
0.73
D 1.07
0.17
70.6
.D 3.66
ND
D 0.29
D 0.60
0.73
12.0
0.22
0.69
0.23
2.70
0.60
1.62
0.15
D 1085.9
D ND
D 22.79
D ND
D 20.31
D 213
D 311.95
D 25.58
D 1950.8
D 113.45
6819.1
D 270.38
D 843.09
2847
D ND
D
D 3030.2
D ND
0 6061.5
D ND
D 89
4.51
D 182.43
D 191.77
D 926.8
D 1116.6
D 29.66
E 2528.3
80.05
332.4
D 414.96
D 14323.
D 256.9
207.43
D 274.7
D 3784.9
0 142.6
D 586.95
D 102.21
D 1075.2
D
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.55
ND
ND
ND
1.14
3.06
ND
0.15
7.56
0.87
ND
ND
ND
ND
ND
ND
ND
0.86
ND
ND
ND
NO
ND
NO
ND
NO
ND
ND
ND
NO
0.41
ND
ND
1.17
ND
ND
ND
ND
ND
0.60
ND
24.9
ND
ND
45.0
D 6.53
16.43
5.77
0 1.44
ND
D 3.32
ND
ND
ND
ND
ND
ND
NO
D NO
NO
NO
NO
8.00
ND
NO
ND
ND
NO
ND
ND
ND
D 3.12
2.35
ND
D 9.26
ND
ND
10.8
6.15
ND
D 11.2
ND
786
2.48
4.09
258
22.10
63.15
73.1
D 9.73
104
31.83
5.70
4.51
0.63
ND
ND
2.63
ND
2.76
1.71
ND
1.16
1007
20.3
14.0
ND
3.90
ND
3.85
ND
17.8
41.50
D 92.0 353 E 456
ND ND NO
2.42 D 2.45 D 7.49
ND ND ND
1.08 D 6.22 10.1
49.7 61.5 74.2
65.3 148 E 79.5
2.22 D 11.2 10.8
184 600 E 811
2.35 D 20.9 59.7
E 3517 E 1649 E 618
D 41.6 98.1 105
99.0 E 253 E 364
E 799 E 756 E 747
14.28 12.24 4.09
44.09 37.55 11.64
508 E 820 E 1042
13.19 19.64 8.14
E 1171 E 1960 E 2102
36.23 45.39 17.18
16.3 30.1 36.9
ND ND NO
D 16.2 77.3 E 76.5
21.2 91.8 E 72.2
29.8 206 E 457
66.9 293 E 643
ND 8.10 19.4
156 E 436 E 1515
6.27 21.7 44.3
26.4 81.0 E 142
D 28.9 100 E 188
E 6345 E 4164 E 2225
118 E 83.4 E 35.2
62.5 75.3 46.0
35.2 92.3 E 109
440 E 1397 E 1340
11.8 43.2 64.4
79.5 158 E 257
2.20 D 22.1 51.4
99.3 230 E 480
116.65E 117.16E 26.24
E 158
ND
ND
ND
2.91
16.8
13.0
1.36
E 296
E 29.2
E 190
23.2
E 123
E 242
NO
0.68
E 490
1.48
E 717
3.13
ND
ND
E 11.8
E 6.57
E 194
E 106
2.16
E 335
6.07
E 68.2
E 80.8
E 475
ND
9.63
E 38.2
E 495
E 23.2
E 88.6
E 25.1
E 219
ND
24.6
ND
ND
ND
D ND
ND
ND
D ND
E 48.0
1.30
E 30.7
ND
ND
ND
ND
D ND
E 91.4
D ND
E ND
ND
ND
ND
ND
ND
E 40.0
5.10
0 ND
E 76.3
ND
14.8
16.1
E 87.3
ND
ND
ND
E 84.3
ND
ND
1.41
E 29.1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.38
ND
ND
ND
12.0
ND
ND
ND
9.19
ND
ND
D ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
60.38
176.60
ND
53.77
ND
137.95
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
15.6
ND
ND
ND
ND
305.08
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
I
Episode SCC Type Description
TRIFLUR PCA
BIPHENYL TOT
PCBS
XENOBIOTICS CONCENTRATIONS, ng/g
1C1 2C1 3C1 4C1 5C1
6C1
7C1
8C1
9C1
10C1
DIPHEN HCBUT
DIS
3419 DC036208
3420 DC036209
3420 DC036210
3421 DC036211
3421 DC036212
3422 DC036213
3422 DC036214
3423 DC036216
3424 DC036218
3425 DF02S005
3426 DB069102
3427 DB069103
3428 DB069104
3429 DB06910S
3430 DB069106
3431 DB069109
3433 DB069112
3434 DB040801
3434 QD011889
3435 DD016602
3444 DOO 16603
3444 DD016604
3444 DD029512
3445 DD029513
3446 DDO 16605
3446 DDO 16606
3446 OD091889
PF Freshwater Drum
PF Greenfish
UB Carp
PF White Perch
WB Carp
PF Lm Bass
UB Yellow Bullhead
WB White Catfish
WB White Catfish
WB Carp
PF Bluefish
PF Bluefish
PF Bluefish
PF Weakfish
WB White Catfish
WB Red Snapper
WP Flounder
WP Flounder
WP Flounder
WB Bigmouth Buffalo
WB Carp
PF Channel Catfish
PF Lm Bass
WB Flounder
PF Striped Bass
WB Carpsucker
WB Carpsucker
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
21.8
13.4
NO
ND
ND
ND
ND
ND
10.54
12.3
0.33
2.92
0.77
ND
1.10
0.86
ND
0.16
ND
ND
ND
ND
ND
0.57
0.56
0.77
85.1
57.3
48.6
1.82
ND
ND
ND
1.19
ND
0.13
0.95
D 0.21
2.22
0 0.23
0.09
0 0.14
0 0.13
0.44
D 0.28
0.31
ND
0.12
0.17
0.34
D 0.60
0 0.41
D 0.98
7.11
2.77
1.44
D 0.22
0.44
0.28
0.62
D 0.47
D ND
D 324.5
D ND
D 33.99
D ND
D 13.25
D 693.9
D 76.4
0 187.07
D 213.34
D 193.05
697.8
D 16.98
0 107.04
D 231.18
D 485.37
D 759.78
D 1082.5
593.6
0 ND
D
D
D
D
D
D
ND
2.98
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.51
3.89
ND
ND
0.90
ND
ND
ND
3.22
5.51
ND
6.92
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.93
10.1
22.6
15.5
5.74
0.37
D 3.16
4.36
18.5
5.59
13.60
7.99
ND
2.47
ND
ND
ND
ND
1.37
5.64
6.93
24.4
ND
ND
2.05
20.9
39.3
D 83.5
73.0
112
107
39.1
D 1.33
54.9
68.8
70.1
29.62
22.73
65.0
ND
D ND
ND
ND
17.0
ND
D 17.4
49.6
47.4
246
ND
5.74
D 18.6
122
E 240
E 410
172
127
E 152
50.2
D 5.53
E 219
E 146
E 150
57.09
28.39
132
ND
24.6
ND
1.97
111
15.4
33.8
81.2
73.0
E 260
5.08
28.7
48.8
E 154
E 264
E 357
189
102
E 130
39.7
8.60
E 306
E 192
E 195
22.05
9.91
E 93.3
ND
ND
ND
D 8.99
E 334
43.8
77.2
E 66.5
E 57.2
E 151
11.9
54.8
118
E 139
E 175
E 203
129
36.2
E 49.5
10.4
2.74
E 124
E 74.5
E 74.9
3.57
0.49
E 20.7
ND
ND
ND
2.29
E 196
17.2
44.9
E 10.4
8.52
E 16.4
ND
E 17.8
E 40.8
E 42.3
E 39.6
E 28.1
20.5
ND
8.78
0.82
D ND
E 27.6
E 15.5
E 17.1
ND
D ND
ND
ND
ND
ND
0 ND
E 35.9
ND
12.4
ND
ND
ND
ND
ND
2.93
7.17
1.88
ND
ND
ND
ND
D ND
ND
3.79
2.51
2.72
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
D ND
ND
ND
ND
ND
ND
ND
D 0.97
D 0.80
E 0.90
117.92
82.35
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
406
470
146
18.6
D 741
D 504
D 529
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
APPENDIX D-6
Information on Fish Samples
-------
Key to Table D-6
FISH AND SHELLFISH SAMPLE INFORMATION
Episode Number
SCC Number
Dioxin/Furan Analyses
Percent Lipid Content
Wet Weight of Sample Analyzed
Xenobiotic Analyses
Percent Lipid Content
Wet Weight of Sample Analyzed
Number of fish use to make Composite Sample
Date Sample Collected
Key
NA = Not Available
NM = Not Measured
D-6-1
-------
D-6-2
-------
Episode SCC
No No
Dioxin/Furans
Xlipid wet weight
(g)
Xenobiotics
%lipid wet weight
(g)
1994
1994
1994
1998
1998
2015
2015
2016
2016
2017
2017
2018
2023
2023
2026
2026
2026
2027
2027
2037
2037
2056
2057
2059
2060
2070
2070
2070
2098
2098
2100
2100
2100
2105
2105
2105
2109
2109
2110
2122
2122
2126
2126
2126
2133
2138
2138
2139
2139
2139
2142
2142
2148
2148
2151
2151
2152
2152
2190
2190
2191
2191
2191
2194
2194
2199
2199
DE017702
DE017703
QD1 10586
13285
13421
DF001001
DF001002
DF001101
DF001102
DF001201
DF001202
DF001301
OF001402
DF001403
OF001702
OF001703
DF001706
OF001802
OF001803
Dr 000501
DY000502
DE000501
DE000601
DE000801
DE000901
DJ000901
DJ000902
QD072186
OH001501
DH001504
DH001702
OH001703
00111086
DH002201
OH002204
QD063086
OH002601
OH002602
OH002710
OH003901
OH003904
DD000302
00000303
00062686
00001002
00001501
00001504
DD001601
D0001604
QD071486
DD001902
00001903
00002501
00002504
00002801
OD002803
DD002902
DD002903
D6005101
OG005104
OG005205
OG005206
QD092486
OG005501
DG005504
OG006001
DG006004
NM
NM
NM
NM
NM
5.8
3.5
3.5
1.8
NM
NM
NM
NM
NM
5
NM
NM
NM
NM
NM
NM
NM
13
13 3
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
4 4
NM
NM
NM
NM
NM
NM
3.2
NM
3.2
NM
NM
NM
0 9
NM
NM
3.8
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2.6
NM
NM
19 98
20
20 01
20 02
19 92
20.09
20 07
19 98
20.06
19 95
20.12
20 01
20
20
20
5 67
NM
20 02
20 1
19 98
20 09
20 06
20 06
20.02
20 07
20.05
20.01
20 04
19 99
20
20 04
19 97
20 04
20 09
20
20 12
20 06
20
20 06
19 88
20 03
20 04
20 04
20 01
20
20 01
20 22
20
20 02
20 02
20
20 06
19 91
19 99
19 93
19 98
20
20 3
19 98
20 02
20.07
20
19 96
19 93
20 07
19 95
20 03
NM
NM
NM
NH
NM
9.2
NM
7
NM
10.5
NM
3
NM
1.1
7.6
NM
NM
NM
9.7
7
NM
11.2
15.2
17.4
12.9
NM
4.8
NM
6.8
NM
NM
12 7
NM
NM
3 1
NM
12 5
NM
2 4
NM
7.7
4.9
NM
NM
2 1
NM
NM
8 2
NM
NM
4 9
NM
4 8
NM
NM
6.2
NM
10.2
4.8
1
21 1
NM
NM
9.1
NM
10 2
2 1
NM
NM
NM
NM
NM
20 01
NM
19 98
NM
20.09
NM
20 09
NM
19 98
20
NM
NM
NM
20 01
20 04
NM
20.04
20 03
20 01
20.21
NM
20 18
NM
20 IS
NM
NM
19 98
NM
NM
20 09
NM
20
NM
17 33
NM
20 07
20 12
NM
NM
20 05
NM
NM
20 04
NM
NM
20
NM
20 07
NM
NM
20 04
NM
20 13
20 06
20 16
20 11
NM
NM
20 14
NM
20 06
19 99
NA
NA
NA
NA
NA
03
03
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
04
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
NA
NA
NA
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
No. of
Samples in
Compos i te
NA
NA
NA
NA
NA
03
03
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
04
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
NA
NA
NA
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Sampling
Date
850617
850617
850617
830527
830527
841117
841117
850522
850522
850531
850531
850309
840722
840722
840905
840905
840905
840816
840816
840801
840801
840808
841017
841009
841016
840820
840820
840820
641004
841004
840920
840920
840920
841004
841004
841004
840906
840906
840913
841017
841017
841002
841002
841002
841114
841023
841023
841017
841017
841017
840918
840918
840725
840725
841030
841030
840918
840918
840807
840807
841009
841009
841009
840906
840906
340911
840911
D-6-3
-------
Episode SCC
No. No.
Oioxm/Furans
%lipid wet weight
(9)
Xenobiotics
Xlipid wet weight
(9)
2201
2201
2205
2205
2210
2211
2212
2212
2215
2216
2216
2220
2220
2225
2225
2225
2227
2227
2228
2228
2228
2231
2246
2246
2247
2247
2280
2280
2280
2280
2283
2283
2290
2290
2294
2294
2297
2297
2298
2298
2301
2301
2301
2301
2301
2302
2304
2304
2309
2309
2322
2322
2322
2326
2326
2328
2329
2341
2341
2355
2356
2356
2358
2369
2369
2369
2375
DG006201
DG006204
DG006601
DG006602
DC005401
OC005503
DC005602
DC005605
OC005902
OC006002
DC006003
DC006401
DC006405
DC006902
DC006903
QD101387
DC007102
DC007104
OC007201
OC007204
QD070286
DC007503
DJ002301
OJ002302
DJ002403
DJ002404
DF005201
OF005204
QD062386
Q0121688
DF005501
DF005502
00003402
DD003403
00003801
00003804
D0004102
DD004103
00004201
00004203
00004501
D0004502
00004503
00004504
00071786
D0004601
DD004801
DD004804
00005301
DD005304
DB001301
DB001304
00082686
DB001701
DB001704
DB001904
DB002004
DD006002
00006003
DA001603
DA001702
DA001703
DA001901
DA003202
OA003203
QD030387
OA003802
NH
NM
NH
NH
10.9
4 8
NM
NH
NH
NH
NH
NH
NH
1.2
31.9
25.7
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
NH
10.4
NH
4 1
3 2
9 5
3 7
1
16 6
2 8
NH
NH
NH
NH
NH
2.2
15 5
3 8
NH
NH
4
NH
NH
NH
NH
NH
NH
2 8
8 8
10 9
NH
NH
NH
NH
16
12 6
NH
20
20
20.03
20.01
20 06
19.98
20
20.04
20
20.08
20.04
20.06
19 99
19.96
20 15
20 05
20 43
20 1
20 03
19 98
20.01
20 01
20 02
20 05
20.01
20 07
20 1
18 98
19 97
NH
20 02
20 18
NM
20 3
20 09
19 95
20 14
20 01
18 83
20 1
NM
NH
NM
20 02
20 02
20 11
19 89
20 03
20 13
20 21
20 06
20 16
20 11
20 05
20 05
20 08
20 01
20
20 08
20 1
20 05
19 96
4 75
20 01
20 1
20 02
20 02
9.7
NH
5.1
NH
13 5
3.9
1.8
7.7
10.5
NH
4.8
NH
8 9
NH
NH
NH
NH
8.6
0 4
NH
NH
18.6
NH
7.2
NH
5.5
2.6
NH
NH
3 1
6 3
NH
NH
15
NH
9 9
2 1
NH
NH
1 5
NH
NH
NH
2 1
NH
3.3
15 5
NH
3 6
NH
2 9
NH
NH
7 1
NH
4 2
11 9
NH
10.3
10 2
0 6
NH
NH
NH
NH
NH
NM
19.98
NH
20
NM
20 04
20.17
20 04
20 1
20.03
NM
19 99
NM
19 99
NH
NM
NM
NM
19 94
20.13
NM
NM
20 11
NH
19 97
NH
20 06
20 04
NH
NN
20 06
20 03
NH
NH
20
NH
19 97
20 11
NM
NM
20 08
NH
NH
NH
20
NH
20 06
20 04
NH
19 99
NH
19 94
NH
NH
20 04
NH
20 01
20 05
NH
20 11
20 14
20 09
NM
NM
NM
NM
NM
NM
NA
NA
NA
NA
NA
01
NA
NA
NA
NA
NA
06
03
05
03
03
03
02
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
02
01
03
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
NA
NA
NA
NA
NA
NA
NA
No. of
Samples in
Composite
NA
NA
NA
NA
NA
01
NA
NA
NA
NA
NA
06
03
05
03
03
03
02
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
01
01
01
NA
NA
NA
NA
NA
NA
NA
02
01
03
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
01
NA
NA
NA
NA
NA
NA
NA
Sampling
Date
840919
840919
841027
841027
840829
1984
1984
1984
1984
1984
1984
840920
840920
840906
840906
840906
840817
840817
840809
840809
840809
850918
840918
840918
840919
840919
850507
850507
850507
350507
841120
841120
841127
841127
850422
850422
841128
841128
850410
850410
850116
850116
850116
850116
850116
841101
841102
841102
841026
841026
840919
840919
840919
840926
840926
840918
8409 19
850423
840726
840814
840805
840805
840723
840917
840917
840917
840828
-------
Episode SCC
No No.
Oioxin/Furans
Xlipid wet weight
(g)
Xenobiotics
%lipid wet weight
(g)
2375
2376
2376
2379
2379
2380
2383
2385
2385
2387
2387
2394
2394
2394
2397
2397
2410
2410
2416
2422
2427
2427
2427
2429
2429
2429
2430
2430
2430
2431
2431
2432
2432
2435
2435
2437
2437
2439
2439
2478
2478
2478
2500
2500
2532
2532
2544
2544
2608
2608
2618
2618
2618
2618
2651
2653
2654
2709
2721
2721
2722
2725
2748
2748
2776
2776
2776
DA003803
DA003903
Q0111886
DEOOS401
OE005404
DE005501
DE005801
DE006002
QD101987
DE006201
DE006204
DE006901
QD006901
QD022189
OE007201
DE007204
DE008501
DE008504
OE009101
DE009702
OE010202
DE010203
QD102887
OE010402
OE010403
QD010687
OE010602
OE010603
QD121488
OE010702
OE010703
OE010710
DE010713
DE011001
DE011004
DE011202
OE011203
DE011401
DE011402
OJ003901
OJ003902
DJ003903
DC010201
OC010203
DF019302
DF019303
DF019202
DF019203
DE014501
DE014504
DE015401
DE015402
OE015403
QD 102088
OB008401
08008503
DB008601
DB005101
OA006502
QD011089
DA006601
DA006301
DY006505
OY006506
OY007101
OY007103
QOO 10489
7.4
NM
NH
NM
NM
NM
NM
4
4.1
8.5
NM
10 8
NM
NM
NM
NM
NM
3.1
NM
11 2
24 4
1.9
1.7
NM
NM
NM
1.4
NM
NM
5 6
3 2
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
2 3
10 8
NM
NM
1 7
21 5
14 7
5.9
8 9
8 8
7 6
3 9
NM
NM
6 2
NM
NM
6 3
NM
NM
2 6
NM
NM
20 09
19 95
20 03
NM
20 02
20 03
20.02
20
20.03
19 98
NM
20 02
NM
NM
20 05
20
20 07
20 08
20 09
20 04
20 12
20 59
20.06
19 98
20 06
20 05
20 06
19.92
NM
20 07
20 05
20 75
20 11
20
20 93
20 47
20 16
20
20 03
20 01
20 07
NM
20 11
20
20 18
20 37
20 02
NM
20 07
20 09
20 1
19 99
20
20 04
20 02
20 48
20 01
20
20 27
NM
20 04
20 05
20 02
20 04
20 02
20 01
NM
6 8
5 3
NM
NM
0.6
15 8
16.9
3.7
NM
NM
NM
14
12 9
11 4
5 7
NM
23.8
1 5
21.1
13.7
29 1
NM
NM
17.1
NM
NM
NM
5.1
4 7
NM
3 4
8 9
NM
5 9
NM
NM
17 9
16 2
7 1
NM
3 3
NM
NH
3 2
NH
11 4
10 5
NM
NM
22 5
20 4
6 3
12
NM
3 1
3 4
7.3
9 3
6 3
6 2
2 2
7 2
6.3
NM
2 6
NM
2.6
20 01
20 06
NM
NM
20 07
20 12
20 03
20 09
NM
NM
NM
20 15
20 05
20.09
20 11
NM
19 99
20 09
19 99
20.03
20 11
NM
NM
20.1
NM
NM
NM
20 17
20 04
NM
20.05
20 12
NM
19 96
NM
NM
19 98
20 15
20 15
NM
20 18
NM
NM
20 04
NM
20 02
20 03
NM
NM
19 96
20 03
20 06
20
NM
19 97
20 02
0 8
20 04
20 02
20 01
20 11
19 93
20 05
NM
20
NM
20 11
01
NA
NA
05
NA
NA
NA
04
04
01
NA
03
03
03
NA
NA
NA
NA
NA
05
03
05
05
05
05
05
01
NA
NA
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
NA
01
04
03
01
01
01
01
NA
02
NA
NA
03
03
NA
02
NA
NA
NA
NA
NA
No. Of
Samples in
Compos i te
01
NA
NA
05
NA
NA
NA
04
04
01
NA
03
03
03
NA
NA
NA
NA
NA
05
03
05
05
05
05
05
01
NA
NA
01
01
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
01
01
NA
01
04
03
01
01
01
01
NA
02
NA
NA
03
03
NA
02
NA
NA
NA
NA
NA
Sampling
Date
840828
840828
840828
840921
840921
840828
840717
840813
840813
840821
840821
841025
841025
841025
1984
1984
850619
850619
841016
1984
841010
841010
841010
840910
840910
840910
841017
841017
841017
841016
841016
850603
850603
850626
850626
841002
841002
841025
841025
841120
841120
841120
841114
841114
850809
850809
850725
850725
840801
840801
841025
841025
841025
841025
840809
841004
840919
850618
850613
850613
850613
850613
850630
850630
850914
850914
350914
D-6-5
-------
Episode SCC
No No
Oioxin/Furans
Xlipid wet weight
(9)
Xenotnotics
%lipid wet weight
(9)
3001
3001
3022
3022
3023
3024
3025
3025
3026
3026
3027
3028
3028
3034
3034
3035
3035
3036
3036
3036
3037
3037
3038
3038
3039
3039
3040
3040
3041
3041
3041
3042
3042
3042
3043
3043
3043
3044
3044
3045
3045
3046
3047
3047
3048
3048
3048
3048
3049
3049
3049
3050
3060
3060
3060
3061
3061
3062
3062
3062
3062
3062
3063
3063
3064
3064
3065
DE019501
OE019502
OA008401
DA008402
OA008501
OA008601
DA008701
DA008702
OA009001
DA009002
OA009301
DA008801
00031787
DG025701
OG025702
OG025801
DG025802
OG025901
DG025902
QD120287
OG026001
OG026002
DG026101
DG026102
DG026201
DG026202
OG026301
OG026302
OG026401
OG026402
QD031588
OG026501
DG026502
QD026501
DG026601
DG026602
QD111987
DG026701
DG026702
DGOZ6801
DG026802
OG026901
OG027001
OG027002
OG027101
OG027102
Q0012689
00027101
OG027201
OG027202
OD1 11087
DG027301
DF009101
OF009102
Q0073189
DF019105
OF019106
OF024024
OF024324
QD024324
00071587
SF024324
OF023301
DF023302
OF023305
DF023306
DF023419
1.6
8.2
21 8
1.4
1.6
0.9
5.2
2
2.1
0 9
9 8
1.3
1 3
7.9
0.7
NH
1.1
2 5
3.1
2 2
9.5
1.5
NH
NH
8.6
1 7
5 7
NH
9
5 1
9 2
15 2
NH
NH
9 7
NH
NH
NH
NH
4 5
2 8
5 7
10 3
1 4
13 1
1 8
NH
NH
10 3
0 6
0 5
17
1 6
11 9
NH
1 2
2 4
10 4
5 2
5 2
9 7
5 2
9 8
6.7
1 8
6 4
2 3
20 01
20 01
20 23
20.1
20 02
20.16
20.19
20 04
19 99
19 98
20 13
20 04
20.6
20 01
20 06
20 15
20.1
20 07
19 85
20 02
20 05
20 08
20.02
19 99
20 1
20 04
20 18
19 98
20 09
19 96
20 11
20 25
20 1
NH
20 18
20 07
20.11
19 99
20
20 02
20 06
20 13
19 95
19 93
20 01
20
NM
NH
20 07
20 03
20.01
20 01
20 06
20 04
NH
20 02
20
20 03
20 02
20 1
20
20 02
20 02
20.14
20 08
20 16
20 1
NH
3.6
17.9
NH
1.2
1.3
4.3
NH
2
NH
NH
0 2
NH
8.6
NH
13 5
NH
NH
9.3
NH
10
NH
17 7
NH
9
NH
5 1
NH
NH
5.2
NH
14 1
0 8
15.5
9 5
NH
NH
8 4
NH
6 2
2 5
5 4
10 3
NM
13 7
2 3
2 5
14 5
9
NH
NH
16 4
2 1
19.9
2
NH
2 2
15 1
NH
NM
NH
NH
10 3
5.8
3
NH
0 9
NM
20 07
20 06
NM
20 08
20 03
20.18
NM
20 11
NM
NM
0 04
NM
20.11
NM
20 07
NM
NM
20
NM
20 06
NM
20
NM
19 77
NM
20 04
NM
NM
20 06
NM
20 07
20 08
20 14
20 12
NM
NM
19 99
NM
19 97
20 02
20 12
20 12
NM
20 01
20
20 12
20 03
20
NM
NM
20 08
0 42
0.82
0 4
NM
20 04
20 04
NM
NM
NM
NM
20 04
19 96
20 14
NM
20 02
NA
NA
01
02
01
01
02
01
02
01
02
01
01
03
05
04
04
05
05
05
05
05
04
05
05
05
05
05
03
05
03
05
01
05
05
07
07
05
03
05
02
03
05
05
05
05
05
05
05
05
05
05
02
02
02
01
01
07
01
01
07
01
05
03
30
08
03
No. Of
Samples in
Composite
NA
NA
01
02
01
01
02
01
02
01
02
01
01
03
05
04
04
05
05
05
05
05
04
05
05
05
05
05
03
05
03
05
01
05
05
07
07
05
03
05
02
03
05
05
05
05
05
05
05
05
05
05
02
02
02
01
01
07
01
01
07
01
05
03
30
08
03
Sampling
Date
851023
851023
860818
860818
860818
860820
860820
860805
860805
860805
860805
860814
860814
860908
860908
860827
860827
860904
860904
860904
860827
860827
860827
860827
871014
871014
860820
860820
860820
860908
860820
860909
860909
860909
860910
860910
860910
860911
860911
860916
860916
871203
860819
860819
860819
860819
860819
860819
860820
860820
860820
871229
861117
861117
861117
861231
861231
861106
871119
871119
861106
871119
870507
870507
870405
870404
870326
D-6-6
-------
Episode
No.
3065
3065
3065
3066
3066
3068
3068
3069
3069
3069
3070
3070
3071
3071
3072
3072
3072
3072
3073
3073
3073
3074
3075
3076
3076
3077
3077
3077
3076
3076
3078
3078
3079
3079
3080
3080
3080
3081
3081
3082
3082
3082
3083
3083
3084
3084
3085
3085
3085
3086
3086
3086
308/
3087
3087
3087
3087
3087
3087
3087
3088
3088
3089
3089
3090
3090
3091
sec
No
DF023420
QD010788
QD022588
DF023503
DF023504
DF024001
OF024002
DF024007
DF024008
QD051788
DF024009
DF024010
DF024014
DF024015
DF024017
DF024018
QD040788
QD070688
DF019221
OF019222
QD121587
OF026017
DF024102
DF028502
DF028503
OF019113
OF019114
QD121087
OF009118
OF023815
DF023816
SF009118
DF019205
DF019206
DF023317
DF023318
QD040987
OF024105
DF024106
OF023401
DF023402
QD120787
DF023405
DF023406
DF024109
Q0072188
OF024113
DF024114
SF024113
DF023409
DF023410
DF023411
DF023413
DF023414
OF023415
DF023416
QD023414
QD072387
SF023414
SF023415
OF023417
OF023418
OF019209
DF019210
DF019213
DF019214
DF019217
Diox
Xlip
8 7
NM
7.6
14.2
1.3
1.7
7 1
4 8
1.5
NM
6 3
1
9.9
NM
3 2
0 7
0 7
NM
7 2
2 1
6.7
2
1.9
6.3
0 9
3.1
4 6
0 6
8 2
3 6
1 4
8 2
4 8
8 2
12 3
1
12 8
3.1
5 8
8 3
1 5
1 3
4 8
1 3
8 1
NM
4 5
1 6
4 5
9 1
NM
1
9.6
1
4.6
1 4
2
9 6
1
4 6
8 2
1 4
1 1
4 1
0 5
7 2
1 9
wet weight
(9)
20 04
NM
20.2
20.01
20 03
20.08
20 01
20.04
19 95
NM
20 09
20 15
20 07
NM
20
20
19 99
NM
19 97
19 98
20 02
20 01
20
20 07
20 04
20 19
20 17
20 06
20 03
20 24
20 07
20 03
20 16
20 07
19 98
20 02
20 06
20 17
20 1
20 09
20 28
20 35
20 07
20 11
19 99
20 01
20 02
20 07
20 02
20 03
NM
20 1
20 1
20 16
20 06
20 04
20 08
19 99
20 08
20 06
20 04
20 1
20 08
20 03
20 17
20 06
20 03
Xenobiotics
Xlipid wet weight
(9)
6 8
0 6
NM
8 6
1.1
2.4
7.2
4.9
1 1
4 9
5 7
0.7
12.1
10
2 6
NM
NM
2.4
8.3
NM
NM
1.7
NM
8.2
NM
NM
2.3
NM
6 1
3 1
0 8
NM
4 9
9 6
11 9
0 3
NM
5.1
5 4
8 3
NM
NM
NM
0 6
8 1
NM
4 6
1 3
NM
8 9
2
NM
9 5
0 7
3 9
NM
NM
NM
NM
NM
8 4
0 9
0 5
4 3
0 8
7 8
2
20 04
20.09
NM
20.04
0.23
0.49
20 01
20.13
0 22
20 04
20 03
0.13
0.86
0 8
20.16
NM
NM
19 95
19 98
NM
NM
20 12
NM
19.98
NM
NM
0 46
NM
19 93
20 11
20 01
NM
0 81
19 99
19.96
0.06
NM
20 02
20 03
19 92
NM
NM
NM
0.12
19 73
NM
19 95
0.27
NM
20 02
19 99
NM
20 08
20 05
20 12
NM
NM
NM
NM
NM
20 06
19 94
20 11
19 97
19 96
19 97
19 98
No. of
Samples in
Compos i te
03
NA
03
07
07
25
04
05
05
05
04
04
03
02
04
09
09
04
03
02
03
09
04
05
05
01
03
01
02
03
01
02
06
05
03
05
NA
04
04
03
05
05
03
05
OS
OS
08
06
08
04
02
03
05
02
01
01
02
05
02
01
08
06
06
05
05
05
05
Sampling
Date
870326
870320
870326
870409
870409
870320
870320
870225
870225
870225
870303
870303
870721
870721
870623
870610
870610
870623
870423
870423
870423
861112
870218
861203
870127
870409
870409
870409
870306
870306
870306
870306
861125
861125
870211
870211
870211
861209
861209
870212
870212
870212
870305
870212
871208
871208
870625
870625
870625
870507
870507
870507
870213
870213
870213
870213
870213
870213
870213
870213
870508
870508
870113
870113
871203
861201
870128
D-6-7
-------
Episode SCC
No No
Dioxin/Furans
Xlipid wet weight
(9)
Xenobiotics
%lipid wet weight
(9)
3091
3092
3092
3093
3093
3093
3094
3094
3095
3095
3096
3096
3096
3097
3097
3097
3098
3098
3098
3098
3100
3100
3101
3103
3103
3104
3104
3105
3105
3106
3106
3107
3108
3108
3109
3109
3110
3110
3111
3111
3112
3112
3113
3113
3113
3114
3115
3115
3115
3117
3117
3118
3118
3118
3118
3118
3118
3119
3119
3120
3120
3122
3122
3122
3125
3125
3125
OF019218
DF023501
DF023502
DF024011
DF024118
QD080387
DC017201
QD092988
DC038801
DC038802
DC035001
DC035002
QD052488
OC038701
OC038702
QD071989
DC038601
DC038602
QD032587
QD051288
OC019701
OC019702
DC019901
OC036201
DC036202
DC020001
DC020002
DF025001
DF025002
DE026801
DE026802
DE026901
DE027001
DE027002
DE025001
DE025002
DE022501
DE022S02
DHO 15801
DH015802
DE022401
DE022402
DE021101
DE021102
Q0030789
DE021201
DE021301
DE021302
QD101689
DE021501
DE021502
DE021601
OE021602
DE021603
QD010689
Q0020488
SE021602
OE021701
DE021702
DE021801
DE021802
DE022001
OE022003
OE022004
OE022301
OE022302
QD120888
0 7
9 7
1.7
0 4
8
NM
7 3
7.2
3 4
11.5
1 7
11 2
11 2
4 4
7 5
NM
1 9
3
2
NM
4.4
3.9
3 5
4.6
10.7
1 2
8 6
4 9
2 5
NM
NM
7 8
1.9
9.1
1.5
2 2
7.3
19 6
1 2
9.7
11 8
NM
5 6
7 9
NM
11 3
9 1
7 2
NM
16 3
8 1
2 6
14 6
7 6
NM
NM
14 6
2 1
5 4
6 3
1 9
NM
1 6
1 4
21 3
3.7
3 7
20 19
20 04
20 09
19 99
19 96
20 02
20.06
20 04
20 1
20 03
20 06
20 05
20
20 07
20
NM
20 02
20 34
20
NM
19 97
19 3
20 01
20.05
20.06
20 22
20 24
20 14
20 13
19 99
20 04
20 14
20 13
19 94
20 34
20 2
20.24
20 1
20
20
20
19 99
20 16
20 05
NM
20 02
20 12
20 05
NM
20 13
20 04
19 97
20 13
20 05
NM
NM
20 13
20 26
19 99
19 96
20 02
20 08
20 02
20 03
20
20
20 03
NM
9 7
1.5
0 6
8
NM
7.9
NM
2.9
13 3
1.3
12 2
NM
1 6
7
1
2 1
2.9
NM
2
2 3
NM
1.6
4.3
12 5
0 6
8 3
4 7
0 9
2
NM
7 7
0 6
10
2 5
NM
7 3
25 5
NM
9 9
10 9
0 3
5 9
6 3
5 7
11 8
10
7 8
8 4
17 5
NM
0 4
15 8
1 5
18.7
0 4
NM
NM
NM
5 9
0 9
17 4
1 7
NM
22 6
3 2
NM
NM
20.08
0.3
19.9
19.97
NM
20.02
NM
20 05
20 02
0.26
20 23
NM
0.32
19 96
0.2
20
0.59
NM
20.03
0 46
NM
0.33
0.87
20
0.12
20 06
20 08
19 98
20 11
NM
20 13
20 01
19 94
20 1
NM
19 99
20 09
NM
20 05
19 95
20 06
20 03
20 02
20 12
20 1
0 8
0 87
0 37
20
NM
20 05
19 97
20 04
20 02
20 06
NM
NM
NM
20 11
19 97
20 06
20 01
NM
19 99
20 08
NM
07
OS
08
04
04
04
OS
05
02
05
03
OS
05
05
03
05
03
01
NA
03
04
01
04
05
01
OS
03
05
05
03
07
OS
04
04
02
03
04
02
04
04
OS
05
07
OS
07
OS
04
08
04
OS
05
OS
05
05
OS
05
OS
OS
OS
05
05
01
05
05
05
05
05
No of
Samples in
Composite
07
05
08
04
04
04
OS
05
02
OS
03
OS
05
05
03
05
03
01
NA
03
04
01
04
05
01
OS
03
05
05
03
07
05
04
04
02
03
04
02
04
04
OS
05
07
OS
07
OS
04
08
04
OS
05
OS
05
05
OS
05
OS
OS
OS
05
05
01
05
05
05
05
05
Samp 1 1 ng
Date
870128
870430
870430
870603
870603
870603
871001
871001
871001
871001
870930
870930
870930
861118
861118
861118
861024
861024
861024
861024
861120
861120
861118
861105
861105
861217
861217
870210
870210
860617
851014
860811
860811
860811
860729
860729
860426
860920
861030
861030
860815
860815
870731
870731
870731
860904
890629
890629
890629
870929
870929
860730
860730
860730
860730
860730
860730
850708
850708
850709
850709
861009
861009
861009
870819
870819
870819
D-6-S
-------
Episode SCC
No. No
Dioxm/Furans
%lipid wet weight
(9)
Xenobiotics
%lipid wet weight
(9)
3132
3132
3132
3134
3134
3134
3134
3135
3136
3136
3137
3137
3138
3138
3140
3140
3141
3141
3141
3141
3143
3143
3143
3144
3145
3145
3146
3146
3146
3146
3147
3148
3148
3149
3150
3150
3151
3151
3151
3152
3161
3161
3162
3162
3162
3162
3162
3162
3162
3163
3163
3163
3163
3164
3164
3165
3165
3165
3166
3166
3167
3167
3167
3167
3167
3168
3168
DE023201
OE023202
QD010588
DE023401
DE023403
DE023405
DE023406
DE023501
OE023601
OE023602
DE023701
DE023702
OE023801
OE023802
OE 024001
OE024002
OE024101
DE024102
DE024103
SE024102
DE024401
OE024402
OE024403
DE024901
OE026601
Q0071988
OE026701
DE026702
QD060288
SE026701
DC03S201
DE027101
DE 027 103
DC038501
DA008901
QD120187
DA009101
DA009102
QD072887
DA009201
DC019801
DC019802
DJ022121
DJ022122
DJ022123
DJ022403
DJ024001
OJ025103
QD041889
OJ022402
OJ022404
OJ024002
DJ025102
OD015701
00015702
00015703
00015704
Q0031788
00015705
DD015706
DD015707
00015708
00040588
Q0062388
SD01570S
OD015711
00015712
8 4
9 1
NM
1 9
5
4.3
5.2
11 1
NM
0.9
9 7
1.3
7 9
2 5
NM
3 3
NM
15 8
2.6
15.8
10.4
3
10.8
11 1
10 8
10.9
16 3
1 3
16 3
16 3
9 6
NM
1 7
2 8
4
NM
1 4
1
1 4
3 7
3.5
8 2
3 4
10 6
0 8
0 5
1 9
4
5
4 1
0 7
1 5
2 6
2
14 7
2 1
4 6
1 9
1 8
7 2
1
2 4
0 8
NM
2 4
5 3
0 8
20 11
20 18
NM
19 82
20 33
20 16
20 03
20
NM
20 5
20 14
20
20 06
20 08
NM
20 02
NM
20 03
19 97
20 03
20.15
19 99
20 18
20 05
20.06
20.01
20 01
20 01
20 05
20 01
19 96
20 2
20 11
20
20 08
NM
20
20 16
20 05
20 1
20 23
19 99
20 04
20 13
20 04
20 18
20 02
20 01
20 03
20 04
20 13
20 01
20.02
20 06
20 04
20 06
20 02
20
19 98
19 99
20 04
20 02
20 09
NM
20 02
20 06
20
8 5
NM
8 5
NM
4 4
NM
5 5
11.4
1.1
NM
7.4
NM
8.1
NM
1 9
2 8
3 9
15
2.5
NM
13
NM
10
12 5
11
NM
17 8
1 9
NM
NM
9 1
12 7
0 3
2 9
4 5
5 2
4 5
NM
NM
3.9
2.6
7 4
NM
NM
NM
NM
1 4
NM
NM
NM
NM
1 9
NM
NM
12 8
NM
3.2
NM
NM
7 9
NM
2 1
NM
2 9
NM
4 7
0 5
20 07
NM
19 97
NM
20.27
20.13
20 06
20 04
20 03
NM
0 84
NM
20 16
NM
20 07
20 07
20 02
20 08
19 98
NM
20.09
NM
20
20 21
20 01
NM
20 02
19 99
NM
NM
19 97
20 02
20 06
20 05
20
20 08
20 1
NM
NM
20 02
0.52
20 02
NM
NM
NM
NM
20 14
NM
NM
NM
NM
20 03
NM
NH
20 09
NM
19 98
NM
NM
19 96
NM
19 95
NM
20 02
NM
20 19
20 06
OS
01
OS
01
02
02
02
01
02
01
05
NA
04
01
01
04
01
03
05
03
01
02
03
03
04
04
03
05
03
03
05
OS
OS
01
03
03
01
01
01
03
02
05
01
04
05
01
09
05
05
05
05
09
05
05
04
05
02
05
02
02
04
06
04
06
06
02
05
No of
Samples in
Compos i te
05
01
OS
01
02
02
02
01
02
01
05
NA
04
01
01
04
01
03
05
03
01
02
03
03
04
04
03
05
03
03
05
OS
OS
01
03
03
01
01
01
03
02
05
01
04
05
01
09
05
05
05
05
09
OS
05
04
05
02
05
02
02
04
06
04
06
06
02
05
Sampling
Date
850917
850916
850917
870513
860513
860513
860513
1986
870520
870520
890508
890508
870903
870903
870902
870902
870729
870326
870326
870326
870616
870616
870615
870521
870910
870910
870904
870904
870904
870904
861217
860806
870806
861118
861028
861028
861017
861017
861017
861017
861218
861218
890222
890222
890222
890222
870513
890222
890222
890222
890223
870513
890223
870518
870518
870519
870519
870519
870527
870527
870529
370529
870529
870529
870529
871014
871015
D-6-9
-------
Episode SCC
No. No
Dioxin/Furans
Xlipid wet weight
(9)
Xenobiotics
Xlipid wet weight
(9)
3168
3169
3169
3169
3170
3170
3171
3171
3172
3172
3173
3173
3173
3174
3174
3175
3175
3176
3176
3177
3177
3177
3178
3178
3179
3179
3180
3181
3181
3182
3182
3183
3183
3184
3184
3185
3185
3185
3186
3186
3187
3188
3188
3189
3189
3189
3190
3190
3191
3191
3192
3192
3192
3193
3193
3195
3195
3196
3196
3197
3197
3198
3199
3199
3199
3200
3201
SD015711
OD015713
00015714
QD022789
D0015715
DD015716
DD015717
D0015718
DD015719
D0015720
DD015721
D0015722
00070689
00015723
OD015724
OD015801
DD015802
DOO 15803
00015804
00015805
00015806
00100488
DD015807
DOO 15808
D0015809
DD015810
D0015812
00015813
00015814
00015815
00015816
00015817
00015818
00015819
00015820
00015821
00015822
S0015821
00015823
00015824
00015902
00015903
00015904
00015905
00015906
QD092188
00015907
D0015908
DJ024003
DJ024005
DJ024007
DJ024009
Q0020789
DC039001
00039001
DH020104
DH020105
DH020107
DH020108
OH020109
DH020110
OH020111
OH020101
DH020102
DH020103
DH020112
DJ024012
5 3
10 2
NM
NM
5 5
NM
3.9
NM
8.4
0.6
0 5
20.3
0 6
0 7
10 8
3 4
1 4
4 6
1 2
9
1.8
NM
3 3
0 7
7.9
2
1
2.5
7 2
1 1
7 4
7
0 6
5 5
0 5
6 5
2.2
6 3
2 9
1 7
2 7
4 5
0 4
4 8
0 5
NM
6 3
0 7
1 4
1 4
1
1 2
1
3 5
4 5
3 9
8 7
NM
1 4
NM
3 8
11 5
8 4
NM
4 9
6 1
10 3
20 06
20.09
NM
NM
20 07
NM
20.02
NM
20 11
19 99
20 07
20 05
20.06
20 09
20 1
20 01
20 05
19 99
20 07
19 99
20
NM
19.95
19 96
19 98
20 06
20 08
20 01
20 03
20 08
20 02
20 07
20 04
20 01
20 01
20 04
20 21
20 04
20 07
20 03
20 02
19 98
20 1
20 23
20 13
NM
20 65
20 1
20 16
20 11
20 15
20 06
20 09
20 02
20 04
20 05
20 09
NM
20 21
NM
20 06
20 04
20
NM
20
20 1
20 04
NM
11 3
NM
10.7
6
NM
3.7
NM
6.6
0.7
NM
19 7
NM
NM
8 9
2.9
NM
3 2
NM
7
NM
6.7
3.3
NM
8.2
NM
0 8
NM
6.8
0 4
8 6
6 9
0 3
NM
0 9
6 9
NM
NM
NM
1 4
2 8
10 8
1 9
6 2
NM
6.8
5 9
NM
2.7
1 8
2
1 5
NM
4 6
NM
4 1
8 5
NM
2 1
NM
NM
10 2
10 1
NM
4 8
6 5
NM
NM
20 1
NM
20 1
19 97
NM
20 04
NM
19.9
19 92
NM
20
NM
NM
20 08
20 37
NM
19 98
NM
20 08
NM
20.16
20 32
NM
20 08
NM
20 11
NM
20 07
19 97
19 97
20 29
20
NM
19 94
20 12
NM
NM
NM
20 05
20 05
20 04
20 03
20
NM
19 99
19 97
NM
20 02
20 1
20
20 14
NM
20 09
NM
20 14
20 12
NM
20 23
NM
NM
20
20 01
NM
20 12
20 04
NM
02
05
04
05
04
03
05
05
04
03
04
02
04
05
05
03
03
05
05
04
04
04
20
13
04
03
06
05
03
05
03
05
04
05
05
05
01
05
04
04
03
03
04
03
03
03
04
04
05
NA
01
NA
NA
05
05
05
04
05
05
05
05
05
02
03
02
05
NA
No. Of
Samples in
Composite
02
05
04
05
04
03
05
05
04
03
04
02
04
05
05
03
03
05
05
04
04
04
20
13
04
03
06
05
03
05
03
05
04
05
05
OS
01
05
04
04
03
03
04
03
03
03
04
04
05
NA
01
NA
NA
05
05
05
04
05
05
05
05
05
02
03
02
05
NA
Sampling
Date
871014
871112
871112
871112
871027
871027
871028
871028
871111
871111
870713
870721
870713
870623
870623
870915
870915
870626
870626
870914
870914
870914
870911
870911
870915
870915
870923
871006
871006
870813
870813
871008
871008
870903
870903
870915
870915
870915
871124
871124
870819
870707
870819
870708
870708
870708
870709
870709
870625
870625
870625
870625
870625
870526
870526
870819
870819
870823
870823
870826
870826
870822
870817
870817
870817
870824
870714
D-6-10
-------
Episode SCC
No No.
Dioxin/Furans
%lipid wet weight
(9)
Xenobiotics
Xlipid wet weight
(9)
3203
3205
3205
3206
3206
3206
3208
3212
3212
3212
3213
3215
3216
3216
3216
3216
3217
3217
3218
3218
3219
3219
3220
3220
3220
3221
3221
3221
3222
3222
3223
3224
3226
3227
3231
3231
3234
3234
3235
3235
3236
3236
3237
3237
3237
3238
3238
3241
3241
3244
3245
3245
3246
3246
3248
3248
3249
3249
3250
3250
3252
325?
3252
3252
325?
3256
3256
DJ024018
DJ024023
OJ024024
OJ022301
OJ024102
DJ024103
DJ024109
DJ024120
DJ024121
QD050388
DJ024123
DJ023705
DJ023707
DJ023708
QD022388
QD09168B
DJ023709
OJ023710
DJ023711
DJ023712
OJ023713
OJ023714
OJ023902
OJ023903
Q0012288
OJ022405
OJ023904
DJ023905
DJ023905
DJ023907
DJ023717
DJ023715
DJ023721
OJ023723
DJ023910
OJ023911
OH020301
OH020302
OH020303
DH020304
DH020305
DH020306
DH020307
DH020308
QD080988
OJ023918
00080888
OJ023923
OJ023924
DJ023622
DJ023623
DJ023624
DJ022108
OJ022109
OJ022502
QD050588
OJ022503
OJ022504
OJ022505
OJ022506
OJ022509
DJ022510
QD020989
QD052588
QD082288
DJ022517
OJ022518
4 3
NM
1 1
3 9
2
4.2
14.1
NM
4.5
NM
NM
NM
2
9 6
NM
8 2
8 8
9 6
2 9
7
3 9
0 7
3
11 4
3
25 1
3.6
10 9
1 3
3 2
2 5
0 7
2 8
2 1
NM
12 1
3 2
NM
7 4
NM
9 5
3
4 1
7 6
NM
9 9
2 1
NM
9 2
1 9
1 1
4 2
1 3
1 6
6 2
NM
NM
3 7
NM
6 3
NM
20 5
NM
NM
19 3
4 4
6 4
19 88
NM
20
20 1
20 03
20 44
19 91
NM
19 98
20.17
NM
NM
20
19 94
NM
20 03
20 42
20 06
20 09
20 03
20 1
20 02
20.1
20 08
20.11
20 05
20 02
20 21
20
20 07
20 1
20 13
20 01
20 02
NM
20 08
19.47
NM
19 86
NM
19 84
19 98
20 09
20
NM
20 03
20 07
NM
20 04
20 05
20 27
20 03
20 04
20 92
20
NM
NM
19 98
NM
20 12
NM
20 01
NM
NM
19 98
20 09
20 57
8 9
NM
0 7
NM
NM
6
18 3
3.4
6 3
NM
5 8
15 9
1 4
7 8
7 7
NM
NM
8.3
2 8
NM
3 3
0.5
NM
15 9
NM
NM
NM
23.7
NM
8
2 4
1 9
2 8
1 3
0 7
15 3
2 8
NM
6.8
NM
8.5
NM
NM
7 2
7 1
10
NM
NM
9 9
NM
NM
3 9
NM
2 2
6
6 3
0 7
3 4
NM
5 8
0 8
25
0 7
26 6
NM
NM
6 1
20 11
NM
19 9
NM
NM
20 09
20 14
20.02
20
NM
19 99
20 11
20.07
20 06
20 15
NM
NM
19.98
20.11
NM
20
20 1
NM
20 09
NM
NM
NM
20 13
NM
20 06
19 94
20 18
20 09
20 03
20
20 05
20 01
NM
20 08
NM
20 09
NM
NM
20 11
20 12
19 98
NM
NM
20 04
NM
NM
20 07
NM
20 01
20
20.15
20 03
19 97
NM
19 98
20 13
20 1
20 13
20 12
NM
NM
20
03
04
01
NA
04
04
OS
07
05
NA
NA
NA
04
04
04
04
05
04
05
05
NA
NA
05
04
05
03
01
01
03
05
11
NA
30
20
04
03
04
05
02
04
02
04
04
02
02
11
11
06
05
10
04
10
10
10
04
04
06
02
10
06
04
04
04
04
04
12
06
No Of
Samples in
Composite
03
04
01
NA
04
04
OS
07
05
NA
NA
NA
04
04
04
04
05
04
05
05
NA
NA
05
04
05
03
01
01
03
05
11
NA
30
20
04
03
04
05
02
04
02
04
04
02
02
11
11
06
05
10
04
10
10
10
04
04
05
02
10
06
04
04
04
04
04
12
06
Sampling
Date
870714
870813
870813
870722
870722
870722
870804
870804
870804
870804
870723
870811
870819
870819
870819
870819
870729
870729
870819
870819
870630
870630
870818
870818
870818
890328
870804
870804
870903
870903
870724
870613
870904
870904
870825
870825
870924
870924
870915
870915
870928
870928
870902
870902
870902
870613
870813
870612
870612
871016
870618
870618
870404
870404
870804
870804
870804
870804
870804
870804
870916
870916
870916
870916
870916
871124
871124
D-6-11
-------
Episode SCC
No No
Oioxin/Furans
%lipid wet weight
(9)
Xenobiotics
%lipid wet weight
(9)
3258
3258
3259
3259
3259
3260
3261
3261
3262
3264
3266
3266
3266
3267
3267
3267
3269
3270
3270
3270
3271
3272
3272
3273
3273
3274
3274
3275
3276
3276
3278
3278
3281
3282
3282
3283
3285
3285
3286
3287
3288
3288
3288
3289
3289
3290
3290
3294
3294
3294
3295
3296
3297
3297
3297
3298
3298
3298
3299
3299
3299
3300
3300
3300
3300
3301
3301
DC038901
DC038902
DB000466
08000473
DB069101
DB000493
DY026001
DY026002
OY026004
OY022602
OY022701
OY022702
QD012389
OY022101
DY02210Z
QD020288
OY022106
OY022107
OY022108
SY022108
DY022110
DY022111
OY022112
DY022113
DY022114
OY022115
OY022116
OY022118
DY022119
DY022120
DY022123
DY022124
OY022205
OY022206
DY022207
OY022209
OY022212
DY022213
OY022215
DY022216
DY022217
DY022218
QD060188
DY022219
DY022220
DY022221
DY022222
DJ022L11
DJ022112
OJ022113
DJ022114
OB040101
0804 1501
OB041504
SB041501
08041601
08041604
00112988
08040601
08040604
Q0040601
DB040201
OB040204
Q0021389
SB040201
08041101
08041104
17
8 4
10
NM
NM
8.9
NM
8
3 1
8 4
NM
6.9
NM
5 4
9.1
5 6
5.2
2 4
7 2
7.2
9 7
1 1
7.6
6 7
2
NM
3.7
11 2
4 4
3 3
NM
1 7
10 9
NM
7 6
5 1
6 3
4 3
5 3
2 4
NM
4 5
4 5
4 9
3 6
0 9
18 4
4 4
NM
1.5
1 8
6
14 6
1 1
14 6
16 8
0 7
1
3 4
1 7
NM
3 8
1 1
NM
3 8
19 7
0 8
19 99
19 98
20.02
NM
20 06
19 99
NM
20 14
20.08
20
NM
20 03
NM
20 06
20
20.01
20
19 99
20 03
20 03
20 26
20 08
20 05
20 01
20 02
NM
19 85
20 03
20 17
20 38
NM
20 04
20 08
NM
20 03
19 71
19 99
20 34
19 73
20 07
NM
19 98
20.15
20 13
20 1
20
20 33
19 99
NM
20 03
20
20 2
20 04
20 09
20 04
20 06
20 04
20 02
20 05
20 1
NM
20 05
20 04
NM
20 23
19 98
20 03
18 6
8 3
13 2
0 2
8.3
17 8
NM
7 6
2
NM
0.5
6 7
0.7
1 2
9
NM
NM
NM
6 9
NM
6 7
NM
6.3
4.7
0.1
NM
2.9
NM
4 4
NH
NM
3 5
8.1
1 8
7 8
3 5
7 4
3
4 6
2 3
3 2
4 5
NH
5
2 6
1 6
17 7
6 9
NM
0 9
1 1
6 1
14 7
NM
NM
15 8
1 7
NM
2.8
1 6
2 7
5 8
2.1
2 1
NM
19 4
0 6
3.73
20 04
20 01
20.07
20.1
20 02
NM
20.02
20 34
NM
20 04
20 3
20 04
20.13
20 09
NM
NM
NM
20 29
NM
20 04
NM
20 01
19 94
20 08
NM
20 11
NM
0 89
NM
NM
20 02
20 13
20 04
20 2
20 08
20 02
19 91
19 96
20 07
20 02
20 03
NM
20 05
20 11
20 03
19 98
19 97
NM
0.17
20 03
20 06
20 02
NM
NM
20 02
20 09
NM
20 08
20 05
19 9
20 02
19 98
20
NM
20 07
20 21
03
03
04
03
03
03
02
01
10
06
OS
OS
OS
04
04
04
01
04
04
04
09
01
04
22
20
10
09
10
03
07
06
06
10
03
03
03
06
03
04
04
07
08
08
10
07
08
03
20
07
20
10
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
No. of
Samples in
Composite
03
03
04
03
03
03
02
01
10
06
OS
OS
OS
04
04
04
01
04
04
04
09
01
04
22
20
10
09
10
03
07
06
06
10
03
03
03
06
03
04
04
07
08
08
10
07
08
03
20
07
20
10
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
03
Sampling
Date
870812
870812
870609
870609
870721
870610
870729
870729
870716
871119
871020
871020
871020
871009
871009
871009
871217
871006
871006
871006
870916
871210
871210
870914
870914
870914
870914
870913
870915
870915
871014
871014
870728
870903
870903
870903
870616
870616
870617
870616
870812
870812
870812
870813
870813
871119
871119
871121
870921
870921
871021
870714
870731
870731
870731
870724
870724
870724
870723
870723
870723
870713
870713
870713
870713
870713
870713
D-6-12
-------
Episode SCC
No No
Dioxin/Furans
%lipid wet weight
(g)
Xenobiotics
%lipid wet weight
(g)
3301
3301
3301
3302
3302
3303
3303
3303
3304
3304
3304
3305
3305
3305
3306
3306
3306
3307
3307
3308
3308
3309
3310
3310
3311
3311
3312
3312
3313
3313
3314
3314
3314
3314
3315
3315
3316
3316
3317
3317
3317
3317
3318
3318
3319
3319
3320
3321
3321
3322
3323
3324
3325
3325
3326
3327
3327
3328
3328
3328
3328
3329
3329
3330
3330
3330
3331
QD030989
QD092088
SB041101
DB041901
OB041904
OB042301
DB042304
QD102588
DB041001
DB041004
QD041004
DB042001
DB042004
QD1 10388
DB041801
DB041804
QD041801
DB042101
QD 100588
DB040001
Q0030689
OB041301
OC032701
DC032702
OC032801
OC032802
DC033101
OC033102
DC033201
DC033202
OC033301
OC033302
SC033301
SC033302
DC033401
OC033402
OC033501
OC033502
OC033601
OC033602
SC033601
SC033602
DC033701
OC033702
DB041401
QD063088
DB041412
OB040401
QD100688
DB040412
OB041206
OB041252
DB041218
QD082988
OB041208
DB040301
DB04031S
DD029111
OD02S112
SD029111
S0029112
00016003
S0016003
D0029109
DD029110
DD029423
DD016001
NM
20.4
19 7
6 7
0 6
5 2
NM
NM
NM
5.5
NM
23
NM
NM
4 5
NM
NM
3.7
4.6
0 6
1 5
6 3
6 1
0 7
3
1 5
3 9
1.4
1 9
0 8
10 9
2 7
10 9
2 8
3 9
NM
2 5
1 6
4 9
4 7
4 9
4 7
3 9
0 8
3 6
3 8
3
3 2
NM
2 7
2 7
3.4
2 6
2 5
3 2
NM
3 6
5 8
1 4
5.8
1 4
8 4
8.4
1.5
3.5
0 5
3 2
NM
20.07
19 98
20 04
20
20 06
NM
NM
20 11
20.11
NM
20 01
20 18
NM
20 07
NM
NM
20 29
20 06
20 02
20 02
20
20 08
20 01
20 1
19 99
20 01
20.02
20 04
20
20 05
19 97
20 05
19 97
20 11
NM
20 05
20 07
20 07
20 08
20 07
20 08
20 08
20 15
19 98
20 01
20 02
20 19
NM
20 24
20 02
20 16
20 06
20 06
20 07
20 04
20 03
20 1
20 1
20 1
20 1
20 01
20 01
20.02
20 12
19 99
20 08
0 7
NM
NM
7 1
0 4
6 1
0 7
6
0 4
6.1
8.2
21.2
1 2
23.2
5 2
2 2
6 1
3 7
NM
0 7
NM
5 9
5 6
0 7
2 9
0.6
3 8
1 7
1
0.5
10 7
2 1
NM
NM
4 5
1
2 2
NM
3 7
NM
NM
NM
3 5
NM
3 6
NM
3
4
4
NM
2 9
4 7
2 3
NM
4 2
3.8
3 1
6 1
NM
NM
NM
8 1
NM
NM
3 5
NM
NM
20 02
NM
NM
20 08
20 14
20 1
20 1
20.1
20 05
19.96
20.06
20 03
20 14
20 12
19 95
20 03
20 07
20 02
NM
20 03
NM
20 06
20 15
0.14
19 93
0 13
19 83
0.34
20
0 1
19 84
20 02
NM
NM
19 81
20 06
20 24
NM
19 96
NM
NM
NM
19 83
NM
20
NM
20 01
19 99
19 99
NM
20 14
20 03
19 94
NM
20 15
20 11
20 03
19 93
NM
NM
NM
20 1
NM
NM
20 1
NM
NM
03
NA
03
03
03
03
03
03
03
03
03
03
04
03
04
OS
04
03
03
03
03
03
OS
04
05
OS
OS
OS
OS
05
04
05
04
OS
02
02
05
03
05
10
05
10
05
05
11
11
28
11
11
29
02
10
34
34
10
14
08
03
04
03
04
02
02
02
04
04
01
No. Of
Samples in
Composite
03
NA
03
03
03
03
03
03
03
03
03
03
04
03
04
OS
04
03
03
03
03
03
OS
04
05
OS
OS
OS
OS
05
04
05
04
OS
02
02
05
03
05
10
05
10
05
05
11
11
28
11
11
29
02
10
34
34
10
14
08
03
04
03
04
02
02
02
04
04
01
Sampling
Date
870713
870713
870713
870723
870723
870630
870630
870630
870827
870827
870827
870909
870909
870909
880828
880828
880828
870917
870917
870813
870813
870724
871027
871027
870928
870928
870929
870929
671014
871014
871007
871007
871007
871007
870922
870922
870924
870924
871015
871015
871015
871015
870923
870923
870616
870616
870915
870630
870630
870908
870826
871002
870921
880921
870921
870929
871002
880512
880512
880512
880512
880513
880513
880419
880419
880419
880108
D-6-13
-------
Episode SCC
No No
Dioxin/Furans
%lipid wet weight
(9)
Xenobiotics
Xlipid wet weight
(9)
3331
3331
3331
3331
3332
3332
3333
3333
3333
3333
3334
3334
3335
3335
3335
3335
3335
3335
3335
3335
3336
3336
3336
3336
3336
3336
3337
3337
3337
3338
3338
3338
3339
3339
3339
3340
3340
3340
3341
3341
3341
3341
3341
3341
3342
3342
3343
3343
3344
3344
3344
3345
3345
3345
3346
3346
3346
3346
3346
3347
3347
3347
3348
3348
3348
3348
3348
DD016002
DD016007
DD016008
SD016008
DDO 16009
DD016010
DD016011
00016012
D0029108
QD121588
DDO 160 13
DD016014
00016015
D0016016
DD029101
00029102
00029103
QD081588
QD091588
SD016015
DD01B004
00016005
OD016006
DD01B017
00016018
QD092288
00016019
00016020
Q0051388
00016021
000 16022
00029107
00016023
00016024
QD016023
00029113
00029114
SD029114
DD015103
00016104
QD081788
QD092788
SD016103
SD016104
00015105
00016106
00016107
00015108
00016109
00016110
SD016109
00016111
00016112
SD01S111
00016113
00016114
QD042088
SD016113
SD016114
00016115
00016116
SD016115
00016117
00016118
QD072888
SD016117
SD016118
1 1
5
2 7
2.7
13.4
1 2
7 6
6 3
0 8
NM
12 2
1.5
13 2
2 3
4 8
1 4
8 1
2.1
NM
13 2
2 7
7 6
5.1
2
1 2
8 2
5 9
2
NM
0 8
4 9
0 6
7 4
1 9
7 3
0 9
8 8
8 8
0 7
7 7
NM
0 7
0 7
7 7
0 9
1 4
6 9
3 4
8 2
0 9
8.2
1 1
0 5
2 4
3 9
0 9
4
3 9
0 9
6 1
1 4
6 1
2 1
5 3
5 7
2 1
5 3
20.09
20 02
19 99
19 99
20.15
20.18
20.09
20 13
20 01
20.11
20 14
20 11
19.96
20 08
20 04
20.07
20 11
20 23
NM
19 96
20 02
20 01
20.09
20 09
20 04
20 06
19 95
20 16
20 08
20 09
19 98
19 98
20 12
20 01
20 1
20
19 94
19 94
20 04
20 15
NM
19 98
20 04
20 15
20.04
20
20 01
10 01
20
20 04
20
20
20 05
20
20
20 05
20 06
20
20 05
20 03
20 06
20 03
19.98
20 02
20
19 98
20 02
NM
1.1
NM
NM
14 2
-0-
NM
6 2
NM
NM
9 4
NM
11 3
NM
3.3
1.1
9 5
NM
3.6
NM
1.6
NM
4 8
3
1 1
NM
6 1
NM
NM
NM
5
NM
7 3
NM
NM
NM
8 2
NM
NM
7 8
8 2
NM
NM
NM
13 9
NM
1 4
NM
8 4
NM
NM
2 1
NM
NM
3 9
2 6
NM
NM
NM
4 5
NM
NM
2 1
5 1
NM
NM
NM
NM
20
NM
NM
20 07
-0-
NM
19.99
NM
NM
20 06
NM
20 04
NM
20.02
0.23
20
NM
19 81
NM
19.93
NM
20 02
19 98
20 04
NM
20 01
NM
NM
NM
20 04
NM
20
NM
NM
NM
20 13
NM
NM
20 01
20 02
NM
NM
NM
20 03
NM
20 12
NM
20 04
NM
NM
20 07
NM
NM
19 88
20 12
NM
NM
NM
20 05
NM
NM
20 06
20 03
NM
NM
NM
01
02
02
02
22
09
03
05
02
03
05
05
04
05
02
01
01
01
02
04
02
02
01
02
06
06
08
03
08
08
10
09
04
07
04
03
04
04
05
05
05
05
05
05
03
04
02
06
01
05
01
06
01
06
01
05
01
01
05
05
04
05
06
06
06
06
06
No. Of
Samples in
Composite
01
02
02
02
22
09
03
05
02
03
OS
05
04
05
02
01
01
01
02
04
02
02
01
02
06
06
08
03
08
08
10
09
04
07
04
03
04
04
05
05
05
05
05
05
03
04
02
06
01
05
01
06
01
06
01
05
01
01
05
05
04
05
06
06
06
06
06
Sampling
Date
880108
880108
880108
880108
880621
880621
880609
880609
880609
880609
880606
880606
880425
880425
880425
880425
880425
880425
880425
880425
880519
880519
880519
880519
880519
880519
880407
880407
880407
880129
880129
880129
880524
880524
880524
880428
880428
880428
870929
870929
870929
870929
870929
870929
871202
871202
871102
871102
871028
871028
871028
871103
871103
871103
871214
871214
871214
871214
871214
880307
880307
880307
880318
880318
880318
880318
880318
D-6-14
-------
Episode SCC
No No
Dioxin/Furans
%lipid wet weight
(g)
Xenobiotics
%lipid wet weight
(g)
3349
3349
3350
3350
3350
3351
3351
3351
3352
3352
3352
3352
3353
3353
3353
3354
3354
3355
3355
3355
3356
3356
3357
3357
3360
3360
3360
3375
3375
3375
3375
3376
3376
3376
3377
3377
3377
3378
3378
3378
3378
3385
3385
3395
3395
3395
3401
3401
3403
3403
3404
3404
3404
3404
3409
3409
3411
3412
3412
3412
3414
3414
3415
3415
3416
3416
3416
DD016119
DD016120
D0016121
00016122
QD052688
DD016123
DD016124
QD021888
DF023723
DF023724
Q0022089
Q0091388
OF024121
OF024122
QD024121
OY022301
DY022302
DY022303
DY022304
SY022303
DE030201
SE030201
DY022223
DY022224
DD029117
00029118
Q0022389
DD016305
DD016306
QD071189
QD101188
D0016307
DD016308
Q0050389
DD016309
DD016310
SD016309
OD016311
OD016312
D0029115
00029116
DD016401
QD101888
DD016421
DD016422
SD016421
00016509
00016510
00016513
00016514
00016515
OD016516
QD016515
S0016515
DB040701
DB040706
DB040501
DB040901
DB040907
SB040907
OC036203
OC036204
OC036205
OC036206
OF025210
OF025211
OF025212
8 5
1.5
10 6
0.5
NH
1 2
10 3
7 7
1 3
5 5
NM
NM
3
6 2
2 9
8 4
1 1
7 5
1
7.5
10.4
10.4
0.5
18 5
5 9
1 9
6 7
16 9
1 4
NM
18
12 6
2 4
1 7
12 7
1 3
12 7
7.4
1 6
10.8
2 7
4 8
NM
8 I
0.8
8 2
11 1
1 3
10.7
6 4
6 2
0 8
NM
6 2
12 2
1 1
8 3
1 8
14 7
14 7
0 8
9 6
0 8
11 5
3 1
2
1 6
20
20 02
20 07
20.13
20
20 03
20 12
20 23
20 18
19 99
NM
20 09
20 1
20 04
19 98
20 01
20 02
20 02
20 06
20 02
20 05
20 05
20 06
20 11
20.01
20 05
20 03
20 01
20 08
NM
20 12
20 09
19 99
19 99
20 05
20 04
20 05
20 07
19 98
20
20 01
20 1
NM
19 97
20 03
19 97
20 15
20 07
20 12
20 13
20 14
20 05
NM
20 14
20 07
20 03
20 03
20 13
20 03
20 03
20 09
20 01
20 04
20 07
20 09
20 02
20 06
5 8
NM
10 4
0.9
NM
NM
9 7
NM
1
5 6
0 7
NM
2 6
6 3
NM
9 2
0 8
6 5
0 6
NM
10 1
NM
NM
22 7
6 9
NM
NM
19 3
0 8
1 4
NM
13
0 5
NM
14 7
1
NM
1 5
NM
12
NM
4 7
6 7
8 1
NM
NM
12 3
0 6
11 7
1 4
6 1
NM
6 2
NM
11 7
0 6
10 3
2 1
16 9
NM
2 3
10 4
1 1
8.1
NM
NM
NM
20 05
NM
20
19 99
NM
NM
19 99
NM
20 09
19 74
20 05
NM
19 96
19 74
NM
20 01
19 99
19 97
19 98
NM
19 66
NM
NM
20 02
20 06
NM
NM
19 97
0 16
0 29
NM
20.03
0 09
NM
20 12
0 2
NM
19 98
NM
19 96
NM
20 08
20 11
20
NM
NM
19 98
20 1
19 98
20 01
20 03
NM
20 12
NM
20
20 08
20
20 02
20 06
NM
20 06
20 12
20 02
20 04
NM
NM
NM
03
02
06
04
06
01
02
02
01
03
01
03
02
03
02
03
03
03
03
03
04
04
01
01
04
04
04
03
05
05
03
05
05
05
05
05
05
02
05
03
01
05
NA
06
03
06
03
04
05
04
05
03
05
05
05
NA
03
06
03
03
NA
NA
05
NA
03
03
03
No. of
Samples in
Composite
03
02
06
04
06
01
02
02
01
03
01
03
02
03
02
03
03
03
03
03
04
04
01
01
04
04
04
03
05
05
03
05
05
05
05
05
05
02
05
03
01
05
NA
06
03
06
03
04
05
04
05
03
05
05
05
NA
03
06
03
03
NA
NA
05
NA
03
03
03
Samp 1 1 ng
Date
880218
880218
880406
880406
880406
880202
880202
880202
871211
871211
871211
871211
871210
871210
871210
871114
871114
871119
871119
871119
871118
871118
871202
871202
880901
880901
880901
880914
880914
880914
880914
880906
880906
880906
880906
880906
880906
880912
880912
880912
880912
880901
880901
880901
880901
880901
8804 Zl
880421
880810
880810
880810
880810
880810
880810
870915
870915
870909
870917
870917
870917
871007
871007
870922
870922
890906
890906
890906
D-6-15
-------
Episode SCC
No No
Dioxin/Furans
Xlipid wet weignt
(g)
Xenobiotics
%lipid wet weight
(g)
3418
3419
3419
3420
3420
3421
3421
3421
3422
3422
3423
3423
3424
3424
3425
3425
3425
34^6
3427
3428
3429
3430
3431
3432
3433
3433
3434
3434
3435
3435
3437
3438
3439
3439
3440
3441
3442
3442
3443
3444
3444
3444
3444
3445
3445
3446
3446
3445
3445
3446
3450
3450
3451
3451
3452
3452
3452
3452
DF025007
DC036207
OC036208
DC036209
DC036210
DC036211
DC036212
SC036212
DC036213
DC036214
DC036215
OC036216
OC036217
DC036218
DF025005
DF025012
QD031389
DB069102
DB069103
OB069104
OB069105
DB069106
OB069109
08069111
03069112
QD021689
DB040801
QD01 1889
D0016601
D0016602
DJ022302
DJ022303
OJ022304
QD062289
DJ022305
OJ022306
DF024301
QD081089
DF009118
00016603
DD016604
D0029512
QD091289
DD029513
00029514
00016605
DD016606
DD029511
QD091889
QD092089
DY022308
OY022309
OY022310
DY022314
OF025218
OF025219
OF025220
Q0103189
2
7 3
1 8
2 9
6 2
1 2
9 7
9 7
7 6
1 9
2 1
6 2
2 1
4 1
5.6
2 3
2 1
NM
NH
NH
NM
NM
NM
NM
3 6
3 6
NM
NM
2 8
22.6
3 5
3 6
2 9
2 6
3 2
4
1 2
1 1
8 2
12 1
7 1
1 2
11 4
2 7
6 5
1 2
2 8
7 5
NM
7 8
1.3
1 8
2 1
1 9
2 2
3
1 2
2 4
20 03
20 01
20 13
20.07
20.01
20.05
19 99
19 99
19 97
20 13
20 02
20 13
20 08
20 12
20 01
20 09
20.03
20
20 01
20.07
20 05
20
19 99
20.07
20 05
20 05
20 05
NM
20
20 02
20 11
20 15
20 01
19 99
20 06
20 01
20
20 11
20 03
20 03
19 98
20
20 12
20 06
19 99
20 13
20 08
20 03
NH
20.07
20 02
20 09
20
19 97
20 04
20 11
20 02
20 02
NM
7.3
1.4
2.8
5.4
0.9
10
NM
0.3
0.8
NM
6
NM
4 2
5 7
NM
NM
3 8
1
4.6
1.7
2.9
2.9
NM
4
NM
4 2
4 1
NM
23 6
NM
NM
NM
NM
NM
NM
NM
NM
6 1
10 9
6 4
0 8
NM
2 2
NM
0 5
2 9
NM
2 9
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
0.86
0.27
0.57
20 OB
20.09
20
NM
0.05
20 15
NM
20 12
NM
20
20 04
NM
NM
19 98
20.01
20 05
20.1
20 14
20 11
NM
19 99
NM
19 95
20 11
NM
20
NM
NM
NM
NM
NM
NM
NM
NM
19 93
0 82
0 8
0 16
NM
0 45
NM
0 1
0 57
NM
0.58
NM
NM
NM
NM
NM
NM
NM
NM
NM
08
03
05
03
03
05
05
05
05
03
05
05
03
05
03
03
03
03
03
03
05
05
02
02
05
05
05
05
02
01
NA
30
05
05
04
05
07
07
02
05
05
03
05
03
05
02
03
03
03
03
04
04
04
04
06
06
02
06
No. of
Samples in
Composite
08
03
05
03
03
05
05
05
05
03
05
05
03
05
03
03
03
03
03
03
05
05
02
02
05
05
05
05
02
01
NA
30
05
05
04
05
07
07
02
05
05
03
05
03
05
02
03
03
03
03
04
04
04
04
06
06
02
06
Sampling
Date
890516
890606
890606
881115
881115
880907
880907
880907
880920
881006
880913
880929
880914
880914
890131
890131
890131
880908
880908
880908
880829
880927
870927
870926
870820
870820
870820
870820
890105
890105
870822
890321
890327
890327
890328
890328
890426
890426
870306
890829
890829
890829
890829
890524
890524
890718
890718
890718
890718
890718
1988
1988
880518
880518
890912
890912
890912
890912
D-6-16
-------
APPENDIX D-7
List of Confirmation Samples
-------
TABLE D-7
List of Confirmation Samples
Episode
Number
3062
3085
3087
3087
3118
3141
3146
3167
3168
3185
3297
3300
3301
3314
3314
3317
3317
3328
3328
3329
3331
3335
3340
3341
3341
3345
3346
3347
3348
3348
3355
3356
3377
3395
3404
3412
3421
3443
SCC No. for
Environmental Sample
DF024324
DF024113
DF023414
DF023415
DE021602
DE024102
DE026701
DD015708
DD015711
DD015821
DB041501
DB040201
DB041101
DC033301
DC033302
DC033601
DC033602
DD029111
DD029112
DD016003
DD016008
DD016015
DD029114
DD016103
DD016104
DD016111
DD016113
DD016115
DD016117
DD016118
DY022303
DE030201
DD016309
DD016421
DD016515
DB040907
DC036212
DP009118
SCC No. for
Confirmation Samole
SF024324
SF024113
SF023414
SF023415
SE021602
SE024102
SE026701
SD015708
SD015711
SD015821
SB041501
SB040201
SB041101
SC033301
SC033302
SC033601
SC033602
SD029111
SD029112
SD016003
SD016008
SD016015
SD029114
SD016103
SD016104
SD016111
SD016113
SD016115
SD016117
SD016118
SY022303
SE030201
SD016309
SO016421
SD016515
SB040907
SC036212
SF009118
D-7-1
-------
D-7-2
-------
APPENDIX D-8
List of Duplicate Samples
-------
TABLE D-8
List of Duplicate Samples
Episode
Number
1994
2070
2100
2105
2126
2139
2191
2225
2228
2280
2280
2301
2322
2369
2376
2385
2394
2427
2427
2429
2430
2618
2721
2776
3028
3036
3041
3042
3043
3048
3048
3049
3060
3062
3062
3065
3065
3069
3072
3072
3073
3077
3080
SCC No. for
Environmental Sample
DE017702
DJ000901
DH001703
DH002204
DD000302
DD001604
DG005206
DC006903
DC007204
DF005201
DF005204
DD004504
DB001304
DA003203
DA003903
DE006002
DE006901
DE010203
DE010403
DE010403
DE010603
DE015403
DA006502
DY007101
DA008801
DG025901
DG026401
DG026501
DG026602
DG027101
DG027102
DG027202
DF009101
DF024024
DF024324
DF023419
DF023420
DF024008
DF024017
DF024018
DF019221
DF019113
DF023317
SCC No. for
Duplicate Sample
QD110586
QD072186
QD111086
QD063036
QD062686
QD071486
QD092486
QD101387
QD070286
QD121688
QD062386
QD071786
QD082686
QD030387
QD111886
QD101987
QD006901 and QD022189
QD 102887
QD010687
QD010687
QD121486
QD102088
QD011089
QD010489
QD031787
QD120287
QD031588
QD026501
QD111987
QD027101
QD012689
QD111087
QD073189
QD071587
QD024324
QD010788
QD022588
QD051788
QD070688
QD040788
QD 121587
QD 121087
QD040987
D-8-1
-------
TABLE D-S(Continued)
Episode
Number
3082
3084
3087
3087
3088
3093
3093
3094
3096
3097
3098
3113
3115
3118
3118
3125
3132
3145
3146 '
3150
3151
3162
3165
3167
3167
3169
3177
3189
3192
3193
3212
3216
3220
3237
3238
3248
3252
3252
3266
3267
3288
3298
3299
3300
SCC No. for
Environmental Sample
DP023402
DP024109
DF023413
DF023414
DF023418
DF024118
DF024118
DC017201
DC035002
DC038701
DC038601
DE021101
DE021301
DE021601
DE021602
DE022302
DE023201
DE026601
DE026701
DA008901
DA009101
DJ025103
DD015703
DD015707
DD015708
DD015713
DD015805
DD015905
DJ024009
DC039001
DJ024121
DJ023708
DJ023902
DJ020308
DJ023918
DJ022502
DJ022509
DJ022510
DY022701
DY022101
DY022218
DB041604
DB041601
DB040204
SCC No. for
Duplicate Sample
QD120787
QD072188
QD072387
QD023414
QD091587
QD080387
QD080387
QD092988
QD052488
QD071989
QD032587
QD030789
QD101689
QD020488
QD010689
QD120888
QD010588
QD071988
QD060288
QD120187
QD072887
QD041889
QD031788
QD040588
QD062388
QD022789
QD 100488
QD092188
QD020789
QD039001
QD050388
QD022388 and QD091688
QD012288
QD080988
QD080888
QD050588
QD020989
QD082288 and QD0525S8
QD012389
QD020288
QD060188
QD112988
QD040601
QD021398
D-8-2
-------
TABLE D-8 (Continued)
Episode
Number
3301
3303
3304
3305
3306
3307
3308
3319
3321
3325
3333
3335
3335
3336
3337
3339
3341
3341
3346
3348
3350
3351
3352
3352
3353
3360
3375
3375
3376
3385
3404
3425
3433
3434
3439
3442
3444
3446
3446
3452
SCC No. for
Environmental Samnle
DB041101
DB042301
DB041004
DB042001
DB041801
DB042101
DB040001
DB041401
DB040401
DB041218
DD016011
DD029101
DD029102
DD016018
DD016019
DD016023
DD016103
DD016104
DD016113
DD016118
DD016121
DD016124
DF023723
DF023724
DF024121
DD029117
DD016305
DD016306
DD016308
DD016401
DD016515
DF025012
DB069112
DB040801
DJ022304
DF024301
DF016603
DD016606
DD029511
DF025218
SCC No. for
Duplicate Samnle
QD092088
QD102588
QD041004
QD110388
QD041801
QD 100588
QD030689
QD063088
QD100688
QD082988
QD121588
QD091588
QD081588
QD092288
QD051388
QD016023
QD092788
QD081788
QD042088
QD072888
QD052688
QD012888
QD022089
QD091388
QD024121
QD022398
QD101188
QD071189
QD050389
QD 101888
QD016515
QD031389
QD021689
QD011889
QD062289
QD081089
QD091289
QD091889
QD092089
QD103189
D-8-3
-------
D-8-4
-------
APPENDIX D-9
Comments Regarding Sample Analyses from EPA Duluth
Laboratory
-------
TABLE D-9
Comments Regarding Sample Analyses From EPA-Duluth Laboratory
Episode SCC Ho. Comments
2016
2017
2057
2110
2122
2133
2190
2194
2212
2283
2298
2309
2309
2322
2328
2358
2383
2427
2429
2432
3022
3039
3041
3042
3048
3048
DF001101
DF001201
DE000601
DH002710
DH003904
DD001002
DG005104
DG005504
DC005602
DF005502
DD004201
DD005301
DD005304
DB001304
DB001904
DA001901
DE005801
DE010202
DE010402
DE010710
DA008401
DG026202
QD031588
DG026501
DG027101
QD027101
XC:
XC:
SC:
SC:
SC:
XC:
SC:
SC:
XC:
SC:
SC:
SC:
XC:
SC:
SC:
SC:
XC:
XC:
XC:
XC:
XC:
XC:
DC:
SC:
DC:
DC:
DC:
DC:
DC:
XC:
XC:
XC:
CONC OF DDE TAKEN FROM DILUTION
CONCENTRATION FOR DDE TAKEN FROM DILUTION
RERUN OF C102086LH
SAMPLE NUMBER ASSIGNED AT LAB AND DSR FILLED OUT AT LAB
DH003905 WAS COMBINED WITH DH003904 TO MAKE THIS SAMPLE
DDE QUANT. ION SATURATED, DDE CONCENTRATION IS A MINIMUM
VAL
NS = NO MORE SAMPLE
SAMPLE CONTAINER BROKEN POSSIBLE CONTAMINATION
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
RERUN OF D070286SN
RERUN FROM C082686CS,C070786KJ
RERUN FROM D082686CS.D070786KJ
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE.
ORIGINAL WAS F070786KJ
ORIGINAL WAS G070786KJ
ORIGINAL WAS I070786KJ
DDE VALUE HIGHER THAN REPORTED, DUE TO TIME CONSTRAINTS
UNABLE TO DILUTE SAMPLE
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
CONC FOR DDE TAKEN FROM DILUTION
CONC FOR DDE AND 4CL-PCB TAKEN FROM DILUTION
CONC FOR 4CL-PCB TAKEN FROM DILUTION
CONC FOR DDE TAKEN FROM DILUTION
1234678 HPCDD HAS LEVEL OF CONTAMINATION BELOW 1.5 PPT
LEVEL OF CONTAMINATION IN BLANK IS AT 0.6 PPT,
(QA: 25 X BLANK LEVEL)
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123567 HXCDD
AND S PPT OF 1234678 HPCDD
234678 HXCDF CONTAIMINATION BELOW 0.5 PPT
BLANK LEVEL AT 0.2 PPT (QA: 2.5 X BLANK LEVEL)
LOW CHRYSENE D12 INTERNAL STD. AREA WILL AFFECT VALUES
LOW CHRYSENE D12 INTERNAL STD. AREA WILL AFFECT VALUES
HIGH CHRYSENE D12 RESPONSE MAY PRODUCE LOWER TA VALUE
FOR THESE ANALYTES RELATED
D-9-1
-------
TABLE D-9(Continued)
Episode SCC No. Comments
3066 DP023504
DC: PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
DC: AND 0.5 PPT OF 1234678 HPCDD
3069 DF024008 DC:
3082
3084
3085
3087
3092
3094
3095
3095
3098
3100
3101
3105
3109
3115
3115
3115
3117
3134
3134
3134
3138
3151
3167
3168
3172
3175
DF023401
DF024109
DF024113
DF023416
DF023502
DC017201
DC038801
DC038802
DC038602
DC019702
DC019901
DF025001
DE025001
DE021301
DE021302
QD01689
DE021501
DE023401
DE023402
DE023406
DE023801
DA009101
DD015708
DD015711
DD015719
DD015802
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
SC:
XC:
XC:
XC:
SC:
XC:
DC:
XC:
DC:
DC:
1234678 HPCDD CONTAMINATION BELOW 1.5 PPT, BLANK
CONTAMINATION AT 0.6 PPT
DC: (GA: 2.5 X BLANK LEVEL)
XENO SAMPLE DILUTED 10:1
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
SAMPLE DILUTED 10:1
NS = NO MORE SAMPLE, XENO ANALYSIS WAS DONE BUT DID NOT
MEET XENO QA
HYDROCARBON PATTERN PRESENT
DDE QUANT ION SATURATED DDE CONCENTRATION IS A MINIMUM
VALUE
CONC FOR DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PCB AND DDE-P.P' VALUES TAKEN FROM DILUTIONS
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
PCB VALUES ARE TAKEN FROM DILUTIONS
SAMPLE DILUTED 10:1
4CL-PCB SATURATED SO VALUE REPORTED IS A MINIMUM VALUE
RECEIVED GROUND SAMPLE ID NUMBER IS 89-578-147
RECEIVED GROUND SAMPLE ID NUMBER IS 89-567-150
SAMPLE ID NUMBER IS 89-576-147
DDE QUANT ION SATURATED DDE CONCENTRATION IS A MINIMUM
VALUE
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
NS = RECEIVED GROUND. NOT ENOUGH SAMPLE FOR ANALYSIS
ALL PCB CONCENTRATIONS TAKEN FROM DILUTION
CONC OF 4CL-PCB TAKEN FROM DILUTION
4CL-PCB SATURATED VALUE REPORTED IS A MINIMUM
CONCENTRATION
ACTUAL OMNIVORE ANALYZED AS BOTTOM FEEDER
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PENTA WINDOW HAD CHROMATOGRAPHY PROBLEMS
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 1234678 HPCDD
D-9-2
-------
Episode SCC No.
3310
3315
3315
3317
3331
3333
3343
3333
3335
3335
3345
3352
3533
3353
3354
3355
3401
3401
3404
3416
3433
3443
3450
3450
3451
3451
DC032701
DC033401
DC033402
DC033602
DD016002
DD016011
DD016108
QD121588
DD029101
QD091588
DD016112
DF023724
DF024121
DF024122
DY022301
DY022303
DD016509
DD016510
DD016516
DF025212
DB069112
DF009118
DY022308
DY022309
DY022310
DY022314
TABLE D-9 (Continued)
Comments3
XC:
XC:
XC:
SC:
XC:
XC:
DC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
XC:
DC:
DC:
DC:
XC:
XC:
DC:
DC:
DC:
DC:
INTERNAL STD. AREA FOR CHRYSENE WAS LOW
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
CONC FOR DDE TAKEN FROM DILUTION
SAMPLE TO SMALL TO FILLET, GROUND WHOLE
FAILED QA XENOBIOTICS, NO MORE SAMPLE FOR REANALYSIS
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
PCDD/F: DUPLICATE IS 00121588 PCDD/F BLANK SAMPLE INDICATED
03 PPT OF 123678 HXCDD AND 0.5 PPT OF 1234678 HPCDD
NS = NO MORE SAMPLE XENOBIOTIC ANALYSIS WAS NOT DONE
PCDD/F: DUPLICATE OF QD016011 PCDD/F: BLANK SAMPLE INDICATED
0.5 PPT OF 123678 HXCDD AND 0 J PPT OF 1234678 HPCDD
XENO: DUPLICATE OF DD091588, DUPLICATE NOT RUN WITH SET WAS
MISTAKENLY REASSIGNED BUT DATA USED FOR PRECISION
XENO: DUPLICATE OF QD029101 NOT RUN WITH SET WAS MISTAKENLY
REASSIGNED BUT USED FOR PRECISION
NS = NO MORE SAMPLE, XENOBIOTIC ANALYSIS WAS NOT DONE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
CONC OF DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
DDE CONC. CALCULATED FROM DILUTION RUN OF ORIGINAL SAMPLE
DDE NUMBER TAKEN FROM DILUTION
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD AND 0.5
PPTOF 1234678 HPCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF HXCDD AND 0.5 PPT OF
1234678 HPCDD
NO WEIGHTS GIVEN
CHRYSENE-D12 HIGH RESPONSE MAY GIVE LOWER VALUES FOR
RELATED
SAMPLE DILUTED 10:1
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 948,949,950,951
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 952,953,954,955
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 396,397,398,399
SAMPLE CONTAINS THE FOLLOWING ID NUMBERS: AA 412,413,414,415
D-9-4
-------
TABLE D-9(Continued)
Episode SCCNo. Comments
3182
3185
3206
3206
3212
3212
3213
3219
3231
3245
3252
3259
3259
3259
3266
3272
3272
3282
3282
3283
3288
3288
3289
3290
3299
3300
3303
3306
DD015815
DD015821
DJ024102
DJ024103
DJ024120
DJ024121
DJ024123
DJ0237D
DJ023911
DJ023623
QD020989
DB000466
DB000473
DB069101
DY022702
DY022111
DY022112
DY022206
DY022207
DY022209
DY022217
DY022218
DY022220
DY022222
QD040601
DB040201
QD102588
QD041801
DC:
DC:
XC:
DC:
XC:
XC:
XC:
SC:
XC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
DC:
XC:
XC:
XC:
XC:
XC:
XC:
SC:
XC:
XC:
XC:
XC:
XC:
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 1234678 HPCDD
SAMPLE DILUTED 10:1
PCDD/F BLANK SAMPLE INDICATED 0.5 PPT OF 123678 HXCDD AND 0.5
PPTOF 1234678 HPCDD
TO MUCH NOISE IN TRICHLOROBIPHENYL WINDOW (M/Z 256) TO
QUANT
CONCENTRATION FOR DDE TAKEN FROM DILUTION
SAMPLE DILUTED 10:1
WERE RECIEVED GROUND
DDE CONCENTRATIONS CALCULATED FROM DILUTED SAMPLE
DDE CONCENTRATIONS CALCULATED FROM DILUTED SAMPLE
1234678 HPCDD CONTAMINATION BELOW 1.5 PPT, BLANK CONTAMINATION
AT 0.6 PPT, (GA:2.5 X BLANK LEVEL)
DOES NOT PASS GA FOR IODONAPHTHALENE BUT CORRELATES WELL
WITH
CONC FOR DDE, 4CL-PCB & 5CL-PCB ARE TAKEN FROM DILUTION
CONC FOR ALL PCBS TAKEN FROM DILUTION
CONC FOR DDE AND PCBS TAKEN FROM DILUTION
DILUTED SAMPLE BY A FACTOR OF 10:1
PCDD/F BLANK SAMPLE INDICATED 0 5 PPT OF 123678 HXCDD AND 0.5
PPT OF 1234678 HPCDD
SAMPLE DILUTED 10:1
CONC FOR DDE TAKEN FROM DILUTION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL SAMPLE
SAMPLE DILUTED 10:1
CONC FOR DDE TAKEN FROM DILUTION
SAMPLE DILUTED 10:1
NS = NO MORE SAMPLE
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL
SAMPLE
LOW CHRYSENE MAY PRODUCE ELEVATED VALUES FOR TA'S
RELATED TO QUANTIFICATION
DDE CONC. CALCULATED FROM DILUTED RUN OF ORIGINAL
SAMPLE
CONC FOR 4CL-PCB TAKEN FROM DILUTION
CONC FOR 4CL-PCB AND 5CL-PCB TAKEN FROM DILUTION
D-9-3
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