ENVIRONMENTAL PROTECTION AGENCY OFFICE OF ENFORCEMENT REMOTE SENSING STUDY GREEN WATER IN LAKE SUPERIOR OCTOBER 1972 NATIONAL FIELD INVESTIGATIONS CENTER-DENVER AND NATIONAL WATER QUALITY LABORATORY DULUTH. MINNESOTA JANUARY 1973 tXEAl ------- ENVIRONMENTAL PROTECTION AGENCY OFFICE OF ENFORCEMENT REMOTE SENSING STUDY GREEN WATER IN LAKE SUPERIOR OCTOBER 1972 National Field Investigations Center and EPA National Water Quality Laboratory Duluth, Minnesota January 1973 ------- THIS REPORT WAS PREPARED BY: 1) Arthur W. Dybdahl Physicist Remote Sensing Programs Process Control Branch National Field Investigations Center-Denver Environmental Protection Agency 2) Jim V. Rouse Geologist Process Control Branch National Field Investigations Center-Denver Environmental Protection Agency ------- TABLE OF CONTENTS Chapter Title Page I INTRODUCTION 1 II MISSION PURPOSE 1 III BACKGROUND 2 IV CHRONOLOGICAL DATA 3 V AIRCRAFT SENSOR DATA 3 VI CONTROLS ON AERIAL RECONNAISSANCE DATA 9 VII FLIGHT PARAMETER DATA 11 VIII WEATHER INFORMATION 11 IX MECHANICS OF AERIAL RECONNAISSANCE DATA INTERPRETATIONS 13 X RESULTS OF THE AERIAL RECONNAISSANCE DATA ANALYSIS AND INTERPRETATIONS 16 XI SUMMARY AND CONCLUSIONS 25 REFERENCES 26 APPENDIX A 27 ii ------- REMOTE SENSING STUDY GREEN WATER IN LAKE SUPERIOR October 1972 I. INTRODUCTION An aerial reconnaissance study of the green water phenomenon in Lake Superior was conducted on October 19, 1972. This effort was requested by the Director of the National Water Quality Laboratory, EPA, Duluth, Minnesota. The sections of Lake Superior covered during this study are shown in Figure 1. II. MISSION PURPOSE The aerial reconnaissance study of the northern shore reaches of Lake Superior was designed to fulfill the following objectives: (a) Document the presence of the green-water phenomenon. (b) Obtain the precise location and lake surface area of the green water recorded. (c) Compare, to the extent practicable, the color characteristics of the green water mass to those recorded in the immediate vicinity of the Reserve Mining Company's taconite tailing effluent. (d) Document the presence of any lake water up-welling along the Minnesota shore. ------- PAGE NOT AVAILABLE DIGITALLY ------- -2- III. BACKGROUND EPA1 has carried out extensive investigations regarding the cause or source of the green-water effect. A long term detailed field sampling program and subsequent laboratory analysis were initiated in September, 1968. The results, pertinent to this report, of the study are as follows: (a) The major cause of the "green-water phenomenon" along Lake Superior's northern shore (refer to Figure 1) was taconite tailings suspended in the water. (b) Taconite tailings were characterized by a mixture of cummingtonite, grunerite, and quartz. (c) The taconite tailings, comprising the suspended solids in the green-water, originated from a launder discharge within the Reserve Mining Company facility located at Silver Bay, Minnesota. (d) Throughout the period of study, the green water was not observed northeast of the Reserve Mining Company effluent regardless of the prevailing wind direction. (e) Water clarity in the green water, caused by the taconite tailings, was 4 to 10 times less than the clarity in the clear or background water in Lake Superior. Patterns2 for the surface currents in Lake Superior have been documented through detailed long term field studies initiated in 1966. These patterns indicate that the characteristic surface currents, along the U. S. section of the northern shore of Lake Superior, are in a counter-clockwise direction. ------- -3- It was concluded, from a drift-bottle study^ performed by Northern Michigan University, that the test bottles released in Lake Superior along the Michigan shore would not (except under unusual circumstances) gather or strand along the Minnesota's northern shore- line, because of prevailing off-shore winds causing an upwelling and off-shore drift. IV. CHRONOLOGICAL DATA The aerial reconnaissance mission was flown on October 19, 1972 between the hours of 0917 and 1108 CDT. V. AIRCRAFT SENSOR DATA Two high performance aircraft were used to carry out this remote sensing mission. The sensors, carried on-board each of these aircraft, were three cameras and an Infrared Line Scanner. Two of the three cameras were KS-87B Aerial Framing Cameras with 6-inch (152mm) focal length lens assemblies. They were mounted in the aircraft in their respective vertical positions. The framing cameras were uploaded with different film and optical filter combinations as follows: (a) Kodak 2403 with a Wratten HF3/HF5 gelatin optical filter combination which effectively eliminates the sunlight scattering by the lower atmosphere. The resultant photo- graphic data were 4.5"x4.5" black and white negatives. This sensor was used for depth penetration below the surface of the lake water. ------- -4- (b) Kodak Aerochrome Infrared Film 2443 with a Wratten 16 gelatin optical filter resulting in a 4.5"x4.5" color transparency. This filter transmits a portion of the visible optical spectrum, i.e., deep green, yellow, orange, red, along with the near infrared energy from 0.7 to 1.0 microns. This film presents a modified color or false color rendition in the processed transparency unlike the more familiar true-color films. It has an emulsion layer that is sensitive to the near infrared in addition to the red and green layers, whereas the true- color ektachrome films have red, green, and blue sensi- tive layers. (Every color in the visible optical spectrum is formed in the true color film by various combinations of red, green and blue dyes similar to the red, green and blue dots on the front of a color television picture tube.) The modified or false color rendition comes into play when the exposed image on the infrared film is processed. In the finished transparency, the scene objects (trees, plants) producing infrared exposure, appear red in color, while red and green objects produce green and blue images, respectively. The most important asset of this film is its capability of recording the presence of various levels of chlorophyll in plant growth. The leaves on a healthy tree will record as a bright red image rather than the usual green. The orange filter is used to keep all blue light from reaching the film which would cause an unbalance in the normal red, green, blue color balance. ------- -5- The viewing angle of the framing cameras was 41° centered about the aircraft's nadir as shown below: AIRCRAFT ALTITUDE I GROUND LEVEL Viewing Angle of a Framing Camera Configured with a 6-inch Focal Length. A diagram of a typical framing camera is provided below: Focal Plane Shutter Lens Film Advances Frame by Frame Framing Camera ------- -6- The remaining camera of the three mentioned above, was a high altitude panoramic camera, the KA-55. A typical panoramic camera is shown in the diagram below: Scanning Stovepipe" pivoted at rear nodal point Film Advances Frame by Frame Scanning Lens Panoramic This camera used a 32" lens assembly, provided twice the image magnification over that provided by the framing cameras. The lens assembly scans in a direction perpendicular to the aircraft's line of flight through an angle of 90° centered about the nadir of the aircraft as shown below: AIRCRAFT ALTITUDE GROUND LEVEL The viewing angle of the lens assembly in the direction parallel to the aircraft's line of flight was 21.1°. ------- -7- The panoramic camera carried a Kodak Aerographic Ektachrome S0-397 film producing a true color transparency 4.5"xl8.8" in size. No special optical filters were used with this film in order to preserve the true color or real world rendition of the area flown. This camera was used to photograph as much of the green water as possible in the aircraft's lateral direction while including the shoreline within each frame. This was required so that the precise location and surface area of the green water could be established. An infrared line scanner (IRLS), which records a thermal map of an imaged area, completed the array of airborne sensors used on this mission. The IRLS uses an infrared detector in an electro- optic system to record on film the amount of infrared energy detected in the imaged area. The effective focal length of the IRLS is 1.15 inches and the field of view is 120° perpendicular to the line of flight. The three basic units in an infrared reconnaissance set are scanner optics, a detector, and a recording unit. The scanner collects the infrared emissions from the ground and reflects them to a parabolic mirror. The parabolic mirror focuses the infrared emissions onto the detector. The detector converts the infrared energy collected by the scanner into an electrical signal. In the recording unit the electrical signal is converted to visible light through a cathode ray tube which is then recorded on ordinary black and white film. The diagrams below depict the optical ------- -8- collection system and the lateral field of view of the IRLS, respectively. Detector i m m 1 AIRCRAFT ALTITUDE i Basic Two-Sided Coaxial Rotating Mirror Optical System GROUND LEVEL Field-of-View of the IRLS The Appendix contains information pertinent to aerial sensors in respect to: - Focal length - Angle of view - Effects of focal length and altitude on scale and ground coverage. ------- -9- VI. CONTROLS ON AERIAL RECONNAISSANCE DATA This mission was flown with two high performance reconnaissance aircraft. The exposure, processing and subsequent interpretation of the photographic films were under the control of the National Field Investigations Center - Denver, EPA. The precise flight lines, shown in Figure 1, the respective altitudes of each aircraft and the approximate time of flight were specified to the flight crews. The film and optical filters were provided by NFIC-Denver. The respective exposure levels for the film were specified to the personnel installing the film in the aerial cameras. They were as follows: (a) Camera Station 1 - Infrared film 2443 has an aerial exposure index (AEI) of 10 with a Wratten 12 yellow optical filter. Camera was set on AEI of 12 with a Wratten 16 orange filter (1/3 stop underexposed). (b) Camera Station 2 - Tri-X black and white film 2403 has an AEI of 250. Camera was set on AEI of 150 with HF-3/HF-5 haze cutting optical filters (2/3 stop overexposed). (c) Camera Station 3 - S0-397 true color film has an AEI of 12. Camera was set on AEI of 12 with no external optical filters. The film was processed in processors manufactured by Eastman Kodak Company. The infrared and true-color Ektachrome films were ------- -10- processed in the Ektachrome RT Processor, Model 1811, Type M, Federal Stock Number 6740-109-2987PK, Part Number 460250. This machine uses Kodak EA-5 chemicals. The temperature of the respective chemicals in the processor and the film process rate, in feet per minute, are the important parameters. Their values were specified as follows: 1) Prehardner 115°F 2) Neutralizer 115°F 3) First Developer 115°F 4) First Stop Bath 115°F 5) Color Developer 120°F 6) Second Stop Bath 120°F 7) Bleach 125°F 8) Fixer 120°F 9) Stabilizer 120°F The film process rate was 9 feet per minute. The nine chemical baths, mentioned above, comprise the EA-5 process used for the color films. The temperature and pressure of the fresh water supplied to the processor was 120°F and 45 pounds per square inch minimum respectively. The fresh water is used to wash the film immediately before entering the dryers. The black and white film 2403 was processed in a Kodak Versamat Model 11-CM processor using Kodak 641 chemicals. This process contains only two chemical baths which are the developer and fixer. During processing, these were maintained at 85°F with a film process rate of 12 feet per minute. Fresh water temperature was maintained at 85°F with a pressure greater than 45 pounds per square inch. ------- -11- With complete control over the patterns of flight, film type and exposure, film processing and photographic interpretation, the true color film S0-397 is a true and exact representation of the actual scene recorded by the reconnaissance aircraft on October 19, 1972, VII. FLIGHT PARAMETER DATA The flight parameter data consists of the following entities: (a) direction-of-flight of the aircraft (line-of-flight) (b) air speed of aircraft (c) aircraft altitude above ground level (AGL) (d) time of flight. The values of these parameters are as follows: Flight Line 1 Flight Line 2 Flight Lines 3-7 Air Speed 360 Knots 360 Knots 360 Knots Altitude 16,000 feet AGL 7,500 feet AGL 7,500 feet AGL The above mentioned flight lines are depicted in Figure 1. The time of flight for this study was 19 October 1972 at 0917 to 1108 hours CDT. VIII. WEATHER INFORMATION* The direction and speed of the wind at Duluth, Minnesota on October 17 - 19, 1972 were the following: (The wind direction is measured at a particular angle clockwise from true north.) *This information was provided by EPA National Water Quality Laboratory, 6201 Congdon Boulevard, Duluth, Minnesota 55804. ------- -12- Day Oct. 17 Oct. 18 Oct. 19 Time 1100 1200 (Noon) 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 (Mdnt) 0100 0200 0300 0400 0500 0600 0700 0800 0900 1000 1100 1200 (Noon) 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 (Mdnt) 0100 0200 0300 0400 0500 0600 0700 0800 0900 1000 1100 1200 (Noon) TABLE VII-1 Wind Direction 290° 290 280 320 280 280 280 320 300 310 320 320 320 300 300° 310 270 280 290 310 300 310 310 330 330 340 340 310 300 280 330 320 300 270 280 290 270 240 250° 250 260 260 260 260 250 220 230 260 210 260 Wind Speed (Knots) 14 14 15 12 11 14 13 11 9 10 13 9 8 6 5 6 6 8 5 6 8 9 11 10 11 11 13 12 11 10 (gusts to 19) 14 (gusts to 21) 11 (gusts to 17) 9 6 7 8 8 6 6 6 5 7 7 8 7 4 6 7 10 13 ------- -13- The daily amounts of rainfall in the Duluth vicinity, recorded for the 20 days preceding the flight, are provided below: TABLE VII-2 Rainfall (inches) October 1972 Day Amount Day Amount Oct. 1 trace Oct. 11 trace 2 trace 12 0.0 3 0.04 13 0.0 4 0.0 14 trace 5 0.04 15 0.0 6 0.0 16 trace 9 0.0 17 0.0 8 0.01 18 trace 9 trace 19 0.0 10 0.29 The last measurable precipitation occurred on October 10, 1972. There was virtually no rain for eight days preceding the mission, thus precluding the possibility of land run-off in the Silver Bay vicinity at the time of flight. The wind direction as observed by the direction of travel of a smoke plume, from within the Reserve Mining Company facility, was measured from the photographic film to be 263°. This area was photographed at approximately 1000 hours. The wind direction at Duluth, at this particular time, was 260° as given in the table above. IX. MECHANICS OF AERIAL RECONNAISSANCE DATA INTERPRETATIONS In order to document the magnitude of the surface area of Lake Superior covered by the large green-water mass, the precise location of the latter was plotted on a series of.USGS 15 Minute (Scale 1:62,500) maps. Thus, the surface area affected by the green water mass was ------- -14- measured and calculated from these maps. The location of the green water is shown in Figure 2. There was no ground truth, in the form of water samples, obtained on October 19, 1972 to correlate the constituency of the green-water mass in Lake Superior with that of the Reserve Mining Company's taconite effluent. Consequentially, a detailed color analysis was conducted on the color films to show that the green- water mass and the taconite effluent have identical color character- istics. The mechanics of this analysis is outlined in the following paragraphs. The original photographic transparencies were subjected to optical tests whereby the light transmittance* through the film was precisely measured. Each preselected physical point on a given transparency (in most cases five points per transparency) was measured for optical transmittance with the use of a Macbeth Corporation TD-203AM transmission densitometer. This system measures film transmittance on a scale from 100% to 0.01%. It also provides transmittance in terms of film density on a scale from 0.00 to 4.00, where- 100% transmittance is equivalent to 0 density units, 10% to 1.0 density units, 1% to 2.0 density units, 0.1% to 3.0 density units, and 0.01% to 4.0 density units. The transmittance measure- ments were made through red, green, blue and yellow (visual) optical *Light transmittance is defined as Amount of light transmitted through an object Light Transmittance = Amount of light incident upon the object. ------- PAGE NOT AVAILABLE DIGITALLY ------- -15- fliters* contained within the densitometer. These filters provide the optical transmittance or density values only in their respective colors of the optical spectrum. For example, the blue filter transmits light colored from violet through the common blue. It is opaque or does not transmit the deep greens, yellow, orange, and red. This type and degree of color isolation is required to analyze the respective color densities in the photographic films. The term "color analysis" refers to the measurement of the various film densities, through a particular color filter in the densitometer, and the subsequent technical interpretation of this data. The color analysis was, for the most part, performed on the false color infrared imagery rather than the true color film for the following reasons: (a) The green and background waters are differentiated only by various shades of green in the true color film. Through the previously discussed modified color rendition, the false color infrared film shows the green water as being bright blue in color and the background waters as a very dark grayish-green. The latter provides a significantly wider color separation between the two types of water for a precise color analysis than does the true color data. (b) The affects of high altitude atmospheric haze is not present in the false color infrared film where as there is a definite influence upon rendition of the true color film. The former film eliminates this interference factor in the color analysis. *These filters were manufactured and calibrated to established specifications by Eastman Kodak Company, Rochester, New York 14650. ------- -16- X. RESULTS OF THE AERIAL RECONNAISSANCE DATA ANALYSIS AND INTERPRETATIONS The surface area of Lake Superior affected by the green water is shown in Figure 2. Two generations or densities of the green water have been plotted. The first generation is the heaviest concentra- tion appearing heavy green and the second is comprised of lesser concentrations appearing lighter green in color. The magnitude of the total surface area of green water was calculated to be approximately 66 square miles. No trace of the green water was recorded from a point immediately north of the Reserve Mining Company launder effluent along shore to a point near Tofte, Minnesota. The true-color photographic data, recorded by a high altitude panoramic camera, is presented in this report as Figure 3 through Figure 46. The green water is clearly shown in the prints in a light milky-green rendition, while the background waters appear in a darker greenish-blue color. The above mentioned figures are located in a packet near the back of this report. They can be trimmed and, beginning with Figure 3, put together in sequence to form a mosaic of the area from a point near Two Harbors, Minnesota to that near Silver Bay. It is seen from the above mentioned prints that the green water did not form a continuum from the Reserve Mining Company effluent to the location of the mass near Split Rock, which is approximately 8.9 statute miles southwest of Silver Bay along shore. For this reason, the detailed color analysis, discussed in Section IX, was performed on the film for following areas: ------- -17- (a) Characteristic color of the blue on background water northeast of Silver Bay where there was no detectable levels of green water. (b) Characteristic color of the green-water along the effluent delta at Silver Bay. This is depicted by the bright, prominent blue areas of Figures 47, 48 and 49. (c) Characteristic color of the green-water in the large mass from Beaver Bay to Encampment Island, a distance of approximately 16.8 miles along shore. This area is shown in the false color infrared prints labeled Figures 50 through 87. (d) Characteristic color of the blue or background water in the areas where sharp or distinctive boundaries exist between the green and background waters. One such loca- tion was in the vicinity of Split Rock. A total of 83 different frames or transparencies were tested for optical film densities with the densitometer. Each of these values was graphically plotted to form characteristic curves for the green water at the Reserve Mining Company effluent delta, the background or blue water northeast of Silver Bay, the green water in the 66 square mile mass, the background/green water near Split Rock, and the typical outflowing river waters. The river water is called commonly a "tea" due to the high natural organic waste content giving rise to a grayish brown characteristic color. The typical graphic plots for the above are presented in Figures 88 through 93 where the optical film density is along the ordinate or vertical axis. ------- 0.0 ------- n ' *• .._.... ...... ,,,-,,„,, lfiast:fit; Swtr;fi 0.8 o.ot ------- So: Sauace Mile Gn en Water ------- 2. 2 0.8 0.0 ------- 0.8 o.ou ------- 2. . , : , ' 0.8 0.0 ------- -18- It was discussed in Section VIII that the green and blue are the dominant colors, in the modified rendition, of the two types of water (background and green) in the false color infrared film. The smaller the blue optical density value, the more blue there is present in the transparency, i.e., the blue transmittance is greater. The graphic plots depicted in Figures 89 and 91 are derived from the imagery recorded over the Lake Superior background on blue water. The two respective plots have the same general shapes with the blue optical density in each being greater than the green optical density. This is a result of the blue transmittance in the original trans- parencies being less than that of the green. This curve shape is characteristic of all those generated from the background water imagery, during the color analysis. The plots depicted in Figures 90 and 92 are obtained from the imagery recorded over two different locations in the sixty six square mile green-water mass whose posi- tion is shown in Figure 2. These curves also have the same general shape. The blue optical density is seen to be significantly less, in these two figures, than that of the green. This results from the blue transmittance in the original transparencies being greater than that of the green. The dominant color in this case, is the bright blue recalling that the green-water mass records as blue in the false color infrared film. Likewise, this curve shape is characteristic of all those generated from the imagery obtained over the green-water mass. This shape is unique, based on spectral characteristics, for the taconite tailings present in water. ------- -19- Areas in the water of high turbidity caused by land run-off, for example, would display a different characteristic curve than that for the green water mass. The former would be yellow-gray or yellow brown rather than green. An optical density characteristic curve was plotted from the original transparencies recorded over the Reserve Mining Company effluent delta at Silver Bay. It is depicted in Figure 88. Its shape is nearly identical to those of Figures 90 and 92, characteristic of the green-water mass. In Figure 92, the green optical density minus the blue optical density is 0.22 and in Figure 88, it is 0.24. The difference between these two numbers is quite small, approximately 8%. This further supports the similarity of the two curves. Also, a characteristic curve was plotted for the river water, in this area, flowing into Lake Superior called a freshwater tea as mentioned pre- viously in this section. The curve is shown in Figure 93. Its shape is completely different from those for the background water, the green-water mass, and the green water at the Reserve Mining Company effluent delta. It is concluded that this water source made no contribution to the observed green water effect. It is important to mention that there was only one small area, where plant growth, containing chlorophyl, was detected on the rocks at water level northeast of Silver Bay. This area was 7.7 miles northeast of the Reserve Mining Company effluent delta. But, from a point along shore, approximately 4,000 feet northeast of the delta to Two Harbors, Minnesota, there were many areas of plant growth on the rocks at water level. ------- -20- Optical studies were conducted on the properties of taconite tailings to further explain the green water phenomenon recorded in the aerial reconnaissance imagery. A wet sample of taconite tailings was taken, by the EPA National Water Quality Laboratory in Duluth, from the Reserve Mining Company east launder on October 2, 1972 at 2230 hours CDT. A partial of this sample was subjected to the optical tests at NFIC-Denver. The wet sample was put through 250 mesh and 325 mesh U.S.A. Standard Testing Sieves. The sieve set collected particle sizes of "45 to 63 microns" and "less than 45 microns" respectively (1 micron = one millionth meter) These particular particle sizes were chosen for testing over the larger sizes, because they will remain in suspension in water for much longer periods of time. The instrument used for these tests was a Beckman DK-2A spectrophotometer with an integrating sphere or reflectance head attached. This instrument measures the amount of light reflected from a sample based upon a known amount of incident light, as a function of wavelength or respective color of the inci- dent light. The reflective curves, for the above-mentioned taconite particle sizes, are presented in Figure 94. This curve begins at 0.4 microns which is in the violet region of the optical spectrum, passes through the visible region (deep blue through deep red to the human eye) into the near infrared and finally into the inter- mediate infrared region ending at 3.5 microns for Curve 1 and 2.5 microns for Curve 2. The green water effect, seen by average human observers, is caused only by the light in the 0.45 to 0.68 micron region in the visible spectrum. (The average human eye cannot see ------- PAGE NOT AVAILABLE DIGITALLY ------- -21- the deep blue and deep red colors as easily as the green, yellow and orange colors). In the region from 0.5 to 0.7 microns (deep blue green to red respectively) the curves are reasonably flat and nearly horizontal. In this area of the visible spectrum the taconite is called neutral density substance, i.e. it reflects all colors from blue green through red equally. In the area from 0.4 to 0.49 microns (violet to deep blue green) the reflectance tends quickly toward zero. This is referred to as a substance exhibiting minus-blue spectral characteristics. This is the reason for the smaller taconite fines appearing yellow-gray in color. If the reflectance in the blue were equal to that in the yellow, green and red, the fines would be gray rather than the observed yellow-gray. With this in mind, the reflectance or scattering of light by a spherical taconite particle is considered, as shown in Figure 95. The incident sunlight strikes the particle and is reflected or scattered off at various angles depicted by the green lines. This physical interaction is governed by the Law of Reflection in Geometrical Optics. A particle that is not spherical, such as having projections and indentations, will produce a scattering effect far more diffuse than the spherical one selected for simplicity of explanation. Now, place the taconite particle in water, as shown in Figure 96. The incident sunlight strikes the water surface, is bent or refracted and subsequently strikes the spherical particle as shown by the green lines. The light is scattered from the particle and portions of the light again emerge from the water. This is the light viewed by a human observer or camera. The characteristic of clear, background ------- INCIDENT SUNLIGHT SCATTERED LIGHT SCATTERED LIGHT PARTICLE IS ASSUMED AS SPHERICAL FOR SIMPLICITY OF EXPLANATION OF LIGHT SCATTERING. Figure 95. Scattering of Sunlight By A Spherical Particle ------- INCIDENT SUNLIGHT SCATTERED LIGHT SCATTERED LIGHT WATER LEVEL) SPHERICAL PARTICLE Figure 96. Scattering of Sunlight by Spherical Taconite Particle in Water ------- -22- water in Lake Superior is a dark greenish-blue. The bluish color is caused by the reflection of the light incident upon the lake's sur- face from the blue sky.) With the presence of large numbers of taconite particles in the water, this background color is lightened significantly by the scattering process shown in Figure 96. The dark-green color is brightened and becomes a lighter green. The water containing taconite does not show as yellow or some other color because taconite reflects all colors from blue green through red equally, thus the characteristic green color of the water is retained, but, appears much lighter. The origin of the green water effect is explained with the use of the Infrared Line Scanner data or the so-called "thermal maps." Figure 97 is a high altitude (16,000 feet AGL) thermal map of the shore line from fro Harbors, Minnesota to a point near Tofte, Minnesota, from left to right for the reader. The Reserve Mining Company effluent delta is in the center of this map. Figure 98 is the thermal map, at an altitude of 7,500 feet AGL, of the shore line from Two Harbors to the above mentioned effluent delta. Figure 99 is the thermal map, at 7,500 feet AGL, of the shore line from the delta to a point near Tofte, Minnesota. In these maps, the white areas are warm white, while the dark areas are colder. In Figure 97, notice the dark gray area along shore, in the Lake, through the full length of the thermal map. The temperature of the water in this area is cooler than the water temp- erature in the white areas near the bottom of the map. These rela- tive temperature indications are for the surface of the water only. ------- PAGE NOT AVAILABLE DIGITALLY ------- -23- Water is opaque or does not transmit infrared energy in the thermal band from 8 to 14 microns. The maximum penetration beneath the water's surface is 0.01 cm. With this IRLS imagery and known facts about Lake Superior circulation, it is possible to explain the observed areas of green water. At the time of flight, Lake Superior was in a near-isothermal condition. The entire lake mass was near the temperature of maximum density for water. Under this isothermal condition, wind-generated currents have a significant influence on circulation of the entire lake depth, as graphically portrayed by Hough.5 It is generally accepted (Beeton and Chandler)6 that Lake Superior currents are quickly responsive to wind changes. As illustrated by the wind data [Table VII-1], there had been strong offshore winds for two days prior to the time of flight. Shear along the wind-water interface resulted in a surface current toward the southeast. The bearing of this current is to the right of the wind vector caused by the Ekman effect 6»7 resulting from the Coriolis force. The surface current moved the surface layer of water toward the Apostle Islands. This layer was slightly warmer than the underlying water, as a result of solar heating. This is depicted by the red arrows in Figure 100. The development of an offshore surface current required the counter-development of a bottom current in opposition to the surface current. The bottom current moved to the northwest and surfaced as an "upwelling" along the northern shore, as indicated by the cooler water along the shore, in the thermal imagery [Figure 97, 98, 99]. The site of the upwelling was influenced by bottom topography and the relative calm in the lee of the northern shore. The vertical ------- PAGE NOT AVAILABLE DIGITALLY ------- -24- circulation pattern is depicted in Figure 100. EPA divers have previously testified to the presence of billowy "clouds" of fine taconite tailings (brown arrows on Figure 100) being detached from the main density current. The bottom current (blue arrows in Figure 100) would move opposite to the density current, and would override the density layer. This is indicated by the tri- angular shape of the gray area of surface water in the center of Figure 97. This results from the bottom current being forced upward over the density layer. The bottom current upwells along the entire northern shoreline covered by the flights. "Green water" conditions were present only from Beaver Bay to the vicinity of Encampment Island. This is because the net movement of suspended tailings solids was a combina- tion of returning bottom current and the prevalent counter-clockwise lake circulation. A predominant longshore current from Silver Bay toward Duluth is clearly indicated by a geomorphic study of shoreline features on the imagery and is consistent with published current studies.3 The thermal imagery indicates a sharp boundary between the green and blue water masses, especially along the northeastern boundary of the green-water mass (east of Split Rock) as seen in Figures 99 and 101. This is further evidence of a superimposition of a counter-clockwise circulation and an upwelling bottom current. Stereoscopic examination of the boundary area on the film reveals that the green-water mass underlies blue water for a short distance northeast of this boundary. ------- EAST MINNESOTA SHORE Taconite Tailings Deposited on Bottom Zone of Downflow of the Warmer Surface Water is Approximately 900 Feet Taconite Density Layer in Motion Toward Trench Eddy Currents Remove Fine Tailings from the Density Layer and Form Suspension in the Upwelling Water. This is Due to the Interactions of Opposing Currents Figure 100. Schematic Diagram of Wind/Water Interactions Forming Green Water ------- PAGE NOT AVAILABLE DIGITALLY ------- -25- XI. SUMMARY AND CONCLUSIONS The presence of a large mass of green water was recorded along the Minnesota shore of Lake Superior, between Beaver Bay and Encampment Island, on 19 October 1972 between the hours of 0917 and 1108 hours CDT. The mass covered approximately sixty-six square miles of lake surface area. The color characteristics of the green-water mass and of the green water in the immediate area of the Reserve Mining Company taconite effluent were essentially identical indicating that the mass was made up of taconite tailings. The infrared data shows that the green water effect was caused by wind-induced upwelling along shore, bringing fine suspended tailings to the surface. The tailings solids cause the green color due to reflecting and scattering incident sunlight. For two days prior to flight, the upwelling resulted from strong offshore winds, together with near-isothermal conditions in the lake. Numerous small areas of plant growth containing chlorophyl, were detected on the aerial reconnaissance data from a point near the Reserve Mining Company effluent delta to Two Harbors, Minnesota while only one similar spot was found from a point near the delta to Tofte, Minnesota. The data and conclusions given in this report, apply only to the conditions recorded on October 19, 1972. ------- -26- REFERENCES 1. Proceedings from the Lake Superior Enforcement Conference, Second Session, April 29-30, 1970, Volume 1, page 223, Effects of Taconite on Lake Superior. 2. Proceedings from Lake Superior Enforcement Conference, Executive Session, May 13-15, 1969, September 30-October 1, 1969, Volume 1, page 67, An Appraisal of Water Pollution in the Lake Superior Basin. 3. Drift - Bottle Study of the Surface Currents of Lake Superior, J. D. Hughes, J. P. Farrell and E. C. Monahan, Department of Geography, Northern Michigan University, Marquette, Michigan. 4. Geology of the Great Lakes, Jack L. Hough, University of Illinois Press, 1958. Figure 22 on page 51. 5. The St. Lawrence Great Lakes: Limnology in North America, A. M. Beeton and D. C. Chandler, D. G. Frey, editor, University of Wisconsin Press 1966, page 539. 6. General Oceanography, Gunter Dietrich, John Wiley and Sons, Copyright 1963, page 340ff. 7. Elements of Physical Oceanography, Hugh J. McLellan, Pergamon Press, 1965. ------- -27- APPENDIX Focal Length, Angle of View, and the Effects of Focal Length and Altitude ------- 28 The focal length of the aerial sensors affects the size (or scale) of the resulting imagery. At any given altitude, the image size chariges in direct proportion to changes in focal length. Also for a given focal length, the image size is inversely proportional to the altitude. The angle of view of a sensor is a function of the focal length and the image format size. The importance of the angle of view is its relationship to the amount of target area recorded in the imagery. Refer to the following diagrams: A. Focal length of a simple lens. B. Effect of focal length on scale and ground coverage. C. effect of altitude on scale and ground coverage. Point at Infinity Reproduction of point at mfimty- [— Focal Length* I -Parallel light rays from infinite distance and a single point source. Diagram A. Focal Length of a Simple Lens Focal length is the distance from the lens (A) to the film (B) ------- 29 3-Inch Focal Length // \ \ // 20, Ft 20,000 Ft 6-Inch Focal Length 30.000 Ft 12-Inch Focal Length 20,000 Ft 500 Ft 7,500 Ft —/ /— 5,000 Ft 18-Inch Focal Length DIAGRAM B Effect of Focal Length on Scale and Ground Coverage 30,000 Ft .22,500 Ft 10,000 Ft 5,000 Ft ,500 Ft /— 7,500 Ft 3-Inch Focal Length DIAGRAM C Effect of Altitude on Scale and Ground Coverage ------- |