ENVIRONMENTAL PROTECTION AGENCY
             OFFICE OF ENFORCEMENT
             REMOTE SENSING  STUDY
         GREEN WATER IN LAKE SUPERIOR
                 OCTOBER 1972
NATIONAL FIELD INVESTIGATIONS CENTER-DENVER
                     AND
       NATIONAL WATER QUALITY LABORATORY
             DULUTH. MINNESOTA
                  JANUARY 1973
tXEAl

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    ENVIRONMENTAL PROTECTION AGENCY

        OFFICE OF ENFORCEMENT
        REMOTE SENSING STUDY

    GREEN WATER IN LAKE SUPERIOR

           OCTOBER 1972
National Field Investigations Center
                 and
EPA National Water Quality Laboratory
           Duluth, Minnesota

             January 1973

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          THIS REPORT WAS PREPARED BY:
1)  Arthur W.  Dybdahl
    Physicist
    Remote Sensing Programs
    Process Control Branch
    National Field Investigations Center-Denver
    Environmental Protection Agency
2)  Jim V. Rouse
    Geologist
    Process Control Branch
    National Field Investigations Center-Denver
    Environmental Protection Agency

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                             TABLE OF CONTENTS


Chapter                          Title                               Page

    I         INTRODUCTION 	    1

   II         MISSION PURPOSE	    1

  III         BACKGROUND	    2

   IV         CHRONOLOGICAL DATA	    3

    V         AIRCRAFT SENSOR DATA 	    3

   VI         CONTROLS ON AERIAL RECONNAISSANCE DATA 	    9

  VII         FLIGHT PARAMETER DATA	11

 VIII         WEATHER INFORMATION	11

   IX         MECHANICS OF AERIAL RECONNAISSANCE DATA
              INTERPRETATIONS	13

    X         RESULTS OF THE AERIAL RECONNAISSANCE DATA
              ANALYSIS AND INTERPRETATIONS 	   16

   XI         SUMMARY AND CONCLUSIONS	25

              REFERENCES	26

              APPENDIX A	27
                                 ii

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                       REMOTE SENSING STUDY




                   GREEN WATER IN LAKE SUPERIOR




                           October 1972







I.  INTRODUCTION




     An aerial reconnaissance study of the green water phenomenon




in Lake Superior was conducted on October 19, 1972.  This effort




was requested by the Director of the National Water Quality




Laboratory, EPA, Duluth, Minnesota.  The sections of Lake Superior




covered during this study are shown in Figure 1.






II.  MISSION PURPOSE




     The aerial reconnaissance study of the northern shore reaches




of Lake Superior was designed to fulfill the following objectives:




     (a)  Document the presence of the green-water phenomenon.




     (b)  Obtain the precise location and lake surface area of the




          green water recorded.




     (c)  Compare, to the extent practicable, the color characteristics




          of the green water mass to those recorded in the immediate




          vicinity of the Reserve Mining Company's taconite tailing




          effluent.




     (d)  Document the presence of any lake water up-welling along




          the Minnesota shore.

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III.  BACKGROUND




     EPA1 has carried out extensive investigations regarding the




cause or source of the green-water effect.  A long term detailed




field sampling program and subsequent laboratory analysis were




initiated in September, 1968.  The results, pertinent to this report,




of the study are as follows:




     (a)  The major cause of the "green-water phenomenon" along




          Lake Superior's northern shore  (refer to Figure 1) was




          taconite tailings suspended in  the water.




     (b)  Taconite tailings were characterized by a mixture of




          cummingtonite, grunerite, and quartz.




     (c)  The taconite tailings, comprising the suspended solids




          in the green-water, originated  from a launder discharge




          within the Reserve Mining Company facility located at




          Silver Bay, Minnesota.




     (d)  Throughout the period of study, the green water was




          not observed northeast of the Reserve Mining Company




          effluent regardless of the prevailing wind direction.




     (e)  Water clarity in the green water, caused by the taconite




          tailings, was 4 to 10 times less than the clarity in




          the clear or background water in Lake Superior.




     Patterns2 for the surface currents in Lake Superior have been




documented through detailed long term field studies initiated in 1966.




These patterns indicate that the characteristic surface currents,




along the U. S. section of the northern shore of Lake Superior, are




in a counter-clockwise direction.

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                                -3-






     It was concluded, from a drift-bottle study^ performed by




Northern Michigan University, that the test bottles released in




Lake Superior along the Michigan shore would not (except under unusual




circumstances) gather or strand along the Minnesota's northern shore-




line, because of prevailing off-shore winds causing an upwelling




and off-shore drift.






IV.  CHRONOLOGICAL DATA




     The aerial reconnaissance mission was flown on October 19,




1972 between the hours of 0917 and 1108 CDT.






V.  AIRCRAFT SENSOR DATA




     Two high performance aircraft were used to carry out this




remote sensing mission.  The sensors, carried on-board each of these




aircraft, were three cameras and an Infrared Line Scanner.




     Two of the three cameras were KS-87B Aerial Framing Cameras




with 6-inch (152mm) focal length lens assemblies.  They were mounted




in the aircraft in their respective vertical positions.  The




framing cameras were uploaded with different film and optical




filter combinations as follows:




     (a)  Kodak 2403 with a Wratten HF3/HF5 gelatin optical filter




          combination which effectively eliminates the sunlight




          scattering by the lower atmosphere.  The resultant photo-




          graphic data were 4.5"x4.5" black and white negatives.




          This sensor was used for depth penetration below the surface




          of the lake water.

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                           -4-






(b)   Kodak Aerochrome Infrared Film 2443  with  a  Wratten 16




     gelatin optical filter resulting in  a  4.5"x4.5"  color




     transparency.   This filter transmits a portion of  the




     visible optical spectrum, i.e.,  deep green, yellow,




     orange, red, along with the near infrared energy from




     0.7  to 1.0 microns.  This film presents a modified color




     or false color rendition in the  processed transparency




     unlike the more familiar true-color  films.   It has an




     emulsion layer that is sensitive to  the near infrared in




     addition to the red and green layers,  whereas the  true-




     color ektachrome films have red, green, and blue sensi-




     tive layers.   (Every color in the visible optical  spectrum




     is formed in the true color film by  various combinations




     of red, green  and blue dyes similar  to the  red,  green and




     blue dots on the front of a color television picture tube.)




     The  modified or false color rendition  comes into play




     when the exposed image on the infrared film is processed.




     In the finished transparency,  the scene objects  (trees,




     plants) producing infrared exposure, appear red  in color,




     while red and  green objects produce  green and blue images,




     respectively.   The most important asset of  this  film is




     its  capability of recording the  presence  of various levels




     of chlorophyll in plant growth.   The leaves on a healthy




     tree will record as a bright  red image rather than the




     usual green.   The orange filter  is used to  keep  all blue




     light from reaching the film  which would  cause an  unbalance




     in the normal  red,  green,  blue color balance.

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                                   -5-


       The viewing angle of  the  framing cameras was 41° centered about

  the aircraft's nadir as shown  below:
                                                    AIRCRAFT
                                                    ALTITUDE
                                                        I
                          GROUND  LEVEL
Viewing Angle of a  Framing Camera Configured with a 6-inch  Focal Length.
     A diagram  of  a  typical framing camera is provided below:
                  Focal Plane
                           Shutter
                                          Lens
                          Film Advances Frame by Frame
                               Framing Camera

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                                -6-


      The remaining  camera of the three mentioned above, was a

 high altitude panoramic  camera,  the KA-55.  A typical panoramic

 camera is shown in  the diagram below:
                                   Scanning
                                   Stovepipe"
                                 pivoted at rear
                                  nodal point
                        Film Advances Frame by Frame
                         Scanning Lens Panoramic

     This camera used  a 32" lens  assembly, provided twice the image

magnification over  that  provided by the  framing cameras.  The lens

assembly scans in a direction perpendicular to the aircraft's line

of flight through an angle of 90°  centered about the nadir of the

aircraft as shown below:
 AIRCRAFT
 ALTITUDE
                           GROUND  LEVEL

        The viewing angle  of  the lens assembly in the direction

   parallel to the aircraft's line  of flight was 21.1°.

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                                -7-






     The panoramic camera carried a Kodak Aerographic Ektachrome S0-397




film producing a true color transparency 4.5"xl8.8" in size.  No




special optical filters were used with this film in order to preserve




the true color or real world rendition of the area flown.




     This camera was used to photograph as much of the green water as




possible in the aircraft's lateral direction while including the




shoreline within each frame.  This was required so that the precise




location and surface area of the green water could be established.




     An infrared line scanner (IRLS), which records a thermal map




of an imaged area, completed the array of airborne sensors used




on this mission.  The IRLS uses an infrared detector in an electro-




optic system to record on film the amount of infrared energy




detected in the imaged area.  The effective focal length of the IRLS




is 1.15 inches and the field of view is 120° perpendicular to the




line of flight.




     The three basic units in an infrared reconnaissance set are




scanner optics, a detector, and a recording unit.  The scanner




collects the infrared emissions from the ground and reflects them




to a parabolic mirror.  The parabolic mirror focuses the infrared




emissions onto the detector.  The detector converts the infrared




energy collected by the scanner into an electrical signal.  In




the recording unit the electrical signal is converted to visible




light through a cathode ray tube which is then recorded on ordinary




black and white film.  The diagrams below depict the optical

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                                -8-


   collection system  and  the  lateral field of view of the IRLS,

   respectively.
                                      Detector
     i m m
     1
  AIRCRAFT
 ALTITUDE
     i
                        Basic Two-Sided Coaxial Rotating
                           Mirror Optical System
                          GROUND  LEVEL
                     Field-of-View of the IRLS

     The Appendix contains  information pertinent to aerial sensors

in respect to:

          - Focal length

          - Angle of view

          - Effects of focal  length and altitude on scale

            and ground coverage.

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                                 -9-





VI.  CONTROLS ON AERIAL RECONNAISSANCE DATA




     This mission was flown with two high performance reconnaissance




aircraft.  The exposure, processing and subsequent interpretation




of the photographic films were under the control of the National




Field Investigations Center - Denver, EPA.




     The precise flight lines, shown in Figure 1, the respective




altitudes of each aircraft and the approximate time of flight




were specified to the flight crews.  The film and optical filters




were provided by NFIC-Denver.  The respective exposure levels for




the film were specified to the personnel installing the film in the




aerial cameras.  They were as follows:




     (a)  Camera Station 1 - Infrared film 2443 has an aerial




          exposure index (AEI) of 10 with a Wratten 12 yellow




          optical filter.  Camera was set on AEI of 12 with a




          Wratten 16 orange filter (1/3 stop underexposed).




     (b)  Camera Station 2 - Tri-X black and white film 2403 has an




          AEI of 250.  Camera was set on AEI of 150 with HF-3/HF-5




          haze cutting optical filters (2/3 stop overexposed).




     (c)  Camera Station 3 - S0-397 true color film has an AEI of 12.




          Camera was set on AEI of 12 with no external optical




          filters.




     The film was processed in processors manufactured by Eastman




Kodak Company.  The infrared and true-color Ektachrome films were

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                                -10-






processed in the Ektachrome RT Processor, Model 1811, Type M,




Federal Stock Number 6740-109-2987PK, Part Number 460250.  This machine




uses Kodak EA-5 chemicals.  The temperature of the respective




chemicals in the processor and the film process rate, in feet per




minute, are the important parameters.  Their values were specified




as follows:




     1)  Prehardner       115°F




     2)  Neutralizer      115°F




     3)  First Developer  115°F




     4)  First Stop Bath  115°F




     5)  Color Developer  120°F




     6)  Second Stop Bath 120°F




     7)  Bleach           125°F




     8)  Fixer            120°F




     9)  Stabilizer       120°F




     The film process rate was 9 feet per minute.  The nine chemical




baths, mentioned above, comprise the EA-5 process used for the




color films.  The temperature and pressure of the fresh water supplied




to the processor was 120°F and 45 pounds per square inch minimum




respectively.  The fresh water is used to wash the film immediately




before entering the dryers.




     The black and white film 2403 was processed in a Kodak Versamat




Model 11-CM processor using Kodak 641 chemicals.  This process contains




only two chemical baths which are the developer and fixer.   During




processing, these were maintained at 85°F with a film process rate




of 12 feet per minute.   Fresh water temperature was maintained at




85°F with a pressure greater than 45 pounds per square inch.

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                                -11-


     With complete control over the patterns of flight, film type

and exposure, film processing and photographic interpretation, the

true color film S0-397 is a true and exact representation of the

actual scene recorded by the reconnaissance aircraft on October 19, 1972,


VII.  FLIGHT PARAMETER DATA

     The flight parameter data consists of the following entities:

     (a)  direction-of-flight of the aircraft (line-of-flight)

     (b)  air speed of aircraft

     (c)  aircraft altitude above ground level (AGL)

     (d)  time of flight.

     The values of these parameters are as follows:

          Flight Line 1    Flight Line 2    Flight Lines 3-7

Air Speed    360 Knots        360 Knots        360 Knots

Altitude  16,000 feet AGL  7,500 feet AGL   7,500 feet AGL

     The above mentioned flight lines are depicted in Figure 1.

     The time of flight for this study was 19 October 1972 at 0917

to 1108 hours CDT.


VIII.  WEATHER INFORMATION*

     The direction and speed of the wind at Duluth, Minnesota on

October 17 - 19, 1972 were the following:  (The wind direction

is measured at a particular angle clockwise from true north.)
*This information was provided by EPA National Water Quality Laboratory,
6201 Congdon Boulevard, Duluth, Minnesota   55804.

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                                  -12-
  Day
Oct. 17
Oct. 18
Oct. 19
Time

1100
1200  (Noon)
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400  (Mdnt)

0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200  (Noon)
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400  (Mdnt)

0100
0200
0300
0400
0500
0600
0700
0800
0900
1000
1100
1200  (Noon)
   TABLE VII-1

Wind Direction

     290°
     290
     280
     320
     280
     280
     280
     320
     300
     310
     320
     320
     320
     300

     300°
     310
     270
     280
     290
     310
     300
     310
     310
     330
     330
     340
     340
     310
     300
     280
     330
     320
     300
     270
     280
     290
     270
     240

     250°
     250
     260
     260
     260
     260
     250
     220
     230
     260
     210
     260
Wind Speed (Knots)

        14
        14
        15
        12
        11
        14
        13
        11
         9
        10
        13
         9
         8
         6
         5
         6
         6
         8
         5
         6
         8
         9
        11
        10
        11
        11
        13
        12
        11
        10 (gusts to 19)
        14 (gusts to 21)
        11 (gusts to 17)
         9
         6
         7
         8
         8
         6

         6
         6
         5
         7
         7
         8
         7
         4
         6
         7
        10
        13

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                                -13-


     The daily amounts of rainfall in the Duluth vicinity, recorded

for the 20 days  preceding the flight, are provided below:


                            TABLE VII-2
                         Rainfall (inches)
                           October 1972

  Day         Amount                         Day        Amount

Oct. 1        trace                       Oct. 11       trace
     2        trace                            12        0.0
     3         0.04                            13        0.0
     4         0.0                             14       trace
     5         0.04                            15        0.0
     6         0.0                             16       trace
     9         0.0                             17        0.0
     8         0.01                            18       trace
     9        trace                            19        0.0
    10         0.29
     The last measurable precipitation occurred on October 10, 1972.

There was virtually no rain for eight days preceding the mission,

thus precluding the possibility of land run-off in the Silver Bay

vicinity at the time of flight.

     The wind direction as observed by the direction of travel of a

smoke plume, from within the Reserve Mining Company facility, was

measured from the photographic film to be 263°.  This area was

photographed at approximately 1000 hours.  The wind direction at

Duluth, at this particular time, was 260° as given in the table above.


IX.  MECHANICS OF AERIAL RECONNAISSANCE DATA INTERPRETATIONS

     In order to document the magnitude of the surface area of Lake

Superior covered by the large green-water mass, the precise location

of the latter was plotted on a series of.USGS 15 Minute (Scale 1:62,500)

maps.  Thus, the surface area affected by the green water mass was

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                                -14-



measured and calculated from these maps.  The location of the green

water is shown in Figure 2.

     There was no ground truth, in the form of water samples,

obtained on October 19, 1972 to correlate the constituency of the

green-water mass in Lake Superior with that of the Reserve Mining

Company's taconite effluent.  Consequentially, a detailed color

analysis was conducted on the color films to show that the green-

water mass and the taconite effluent have identical color character-

istics.  The mechanics of this analysis is outlined in the following

paragraphs.

     The original photographic transparencies were subjected to

optical tests whereby the light transmittance* through the film

was precisely measured.  Each preselected physical point on a

given transparency (in most cases five points per transparency)

was measured for optical transmittance with the use of a Macbeth

Corporation TD-203AM transmission densitometer.  This system measures

film transmittance on a scale from 100% to 0.01%.  It also provides

transmittance in terms of film density on a scale from 0.00 to 4.00,

where- 100% transmittance is equivalent to 0 density units, 10%

to 1.0 density units, 1% to 2.0 density units, 0.1% to 3.0 density

units, and 0.01% to 4.0 density units.  The transmittance measure-

ments were made through red, green, blue and yellow (visual) optical
*Light transmittance is defined as
                              Amount of light transmitted through an object
  Light Transmittance    =    Amount of light incident upon the object.

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fliters* contained within the densitometer.  These filters provide

the optical transmittance or density values only in their respective

colors of the optical spectrum.  For example, the blue filter

transmits light colored from violet through the common blue.

It is opaque or does not transmit the deep greens, yellow, orange,

and red.  This type and degree of color isolation is required to

analyze the respective color densities in the photographic films.

The term "color analysis" refers to the measurement of the various

film densities, through a particular color filter in the densitometer,

and the subsequent technical interpretation of this data.

     The color analysis was, for the most part, performed on the

false color infrared imagery rather than the true color film for

the following reasons:

     (a)  The green and background waters are differentiated only

          by various shades of green in the true color film.

          Through the previously discussed modified color rendition,

          the false color infrared film shows the green water as being

          bright blue in color and the background waters as a very

          dark grayish-green.  The latter provides a significantly

          wider color separation between the two types of water for

          a precise color analysis than does the true color data.

     (b)  The affects of high altitude atmospheric haze is not

          present in the false color infrared film where as there is a

          definite influence upon rendition of the true color film.

          The former film eliminates this interference factor in the

          color analysis.
*These filters were manufactured and calibrated to established specifications
 by Eastman Kodak Company, Rochester, New York 14650.

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                                -16-
X.  RESULTS OF THE AERIAL RECONNAISSANCE DATA ANALYSIS AND INTERPRETATIONS




     The surface area of Lake Superior affected by the green water is




shown in Figure 2.  Two generations or densities of the green water




have been plotted.  The first generation is the heaviest concentra-




tion appearing heavy green and the second is comprised of lesser




concentrations appearing lighter green in color.  The magnitude of




the total surface area of green water was calculated to be approximately




66 square miles.




     No trace of the green water was recorded from a point immediately




north of the Reserve Mining Company launder effluent along shore to




a point near Tofte, Minnesota.




     The true-color photographic data, recorded by a high altitude




panoramic camera, is presented in this report as Figure 3 through




Figure 46.  The green water is clearly shown in the prints in




a light milky-green rendition, while the background waters appear




in a darker greenish-blue color.  The above mentioned figures are




located in a packet near the back of this report.  They can be




trimmed and, beginning with Figure 3, put together in sequence to




form a mosaic of the area from a point near Two Harbors, Minnesota




to that near Silver Bay.




     It is seen from the above mentioned prints that the green water




did not form a continuum from the Reserve Mining Company effluent




to the location of the mass near Split Rock, which is approximately




8.9 statute miles southwest of Silver Bay along shore.  For this




reason, the detailed color analysis, discussed in Section IX, was




performed on the film for following areas:

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                                -17-







     (a)   Characteristic color of the blue on background water




          northeast of Silver Bay where there was  no detectable




          levels of green water.




     (b)   Characteristic color of the green-water  along the effluent




          delta at Silver Bay.  This is depicted by the bright,




          prominent blue areas of Figures 47, 48 and 49.




     (c)   Characteristic color of the green-water  in the large




          mass from Beaver Bay to Encampment Island, a distance of




          approximately 16.8 miles along shore.  This area is shown




          in the false color infrared prints labeled Figures 50




          through 87.




     (d)   Characteristic color of the blue or background water in




          the areas where sharp or distinctive boundaries exist




          between the green and background waters.  One such loca-




          tion was in the vicinity of Split Rock.




     A total of 83 different frames or transparencies were tested




for optical film densities with the densitometer.   Each of these




values was graphically plotted to  form characteristic curves for




the green water at the Reserve Mining Company effluent delta, the




background or blue water northeast of Silver Bay,  the green water




in the 66 square mile mass, the background/green water near Split




Rock, and the typical outflowing river waters.  The river water is




called commonly a "tea" due to the high natural organic waste




content giving rise to a grayish brown characteristic color.  The




typical graphic plots for the above are presented in Figures 88 through




93 where the optical film density is along the ordinate or vertical




axis.

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                                -18-






     It was discussed in Section VIII that the green and blue are




the dominant colors, in the modified rendition, of the two types of




water  (background and green) in the false color infrared film.  The




smaller the blue optical density value, the more blue there is




present in the transparency, i.e., the blue transmittance is greater.




The graphic plots depicted in Figures 89 and 91 are derived from




the imagery recorded over the Lake Superior background on blue water.




The two respective plots have the same general shapes with the blue




optical density in each being greater than the green optical density.




This is a result of the blue transmittance in the original trans-




parencies being less than that of the green.  This curve shape is




characteristic of all those generated from the background water




imagery, during the color analysis.  The plots depicted in Figures 90




and 92 are obtained from the imagery recorded over two different




locations in the sixty six square mile green-water mass whose posi-




tion is shown in Figure 2.  These curves also have the same general




shape.  The blue optical density is seen to be significantly less,




in these two figures, than that of the green.  This results from the




blue transmittance in the original transparencies being greater




than that of the green.   The dominant color in this case, is




the bright blue recalling that the green-water mass records as




blue in the false color infrared film.   Likewise, this curve shape is




characteristic of all those generated from the imagery obtained




over the green-water mass.  This shape is unique, based on spectral




characteristics,  for the taconite tailings present in water.

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                                -19-






Areas in the water of high turbidity caused by land run-off, for




example, would display a different characteristic curve than that




for the green water mass.  The former would be yellow-gray or




yellow brown rather than green.




     An optical density characteristic curve was plotted from the




original transparencies recorded over the Reserve Mining Company




effluent delta at Silver Bay.  It is depicted in Figure 88.  Its




shape is nearly identical to those of Figures 90 and 92, characteristic




of the green-water mass.  In Figure 92, the green optical density




minus the blue optical density is 0.22 and in Figure 88, it is 0.24.




The difference between these two numbers is quite small, approximately




8%.  This further supports the similarity of the two curves.  Also,




a characteristic curve was plotted for the river water, in this area,




flowing into Lake Superior called a freshwater tea as mentioned pre-




viously in this section.  The curve is shown in Figure 93.  Its




shape is completely different from those for the background water,




the green-water mass, and the green water at the Reserve Mining




Company effluent delta.  It is concluded that this water source made




no contribution to the observed green water effect.




     It is important to mention that there was only one small area,




where plant growth, containing chlorophyl, was detected on the rocks




at water level northeast of Silver Bay.  This area was 7.7 miles




northeast of the Reserve Mining Company effluent delta.  But, from a




point along shore, approximately 4,000 feet northeast of the delta




to Two Harbors, Minnesota, there were many areas of plant growth on




the rocks at water level.

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                                -20-






     Optical studies were conducted on the properties of taconite




tailings to further explain the green water phenomenon recorded in




the aerial reconnaissance imagery.  A wet sample of taconite tailings




was taken, by the EPA National Water Quality Laboratory in Duluth,




from the Reserve Mining Company east launder on October 2, 1972




at 2230 hours CDT.  A partial of this sample was subjected to the




optical tests at NFIC-Denver.  The wet sample was put through 250




mesh and 325 mesh U.S.A. Standard Testing Sieves.  The sieve set




collected particle sizes of "45 to 63 microns" and "less than 45




microns" respectively (1 micron = one millionth meter)  These




particular particle sizes were chosen for testing over the larger




sizes, because they will remain in suspension in water for much




longer periods of time.  The instrument used for these tests was a




Beckman DK-2A spectrophotometer with an integrating sphere or




reflectance head attached.  This instrument measures the amount of




light reflected from a sample based upon a known amount of incident




light, as a function of wavelength or respective color of the inci-




dent light.  The reflective curves, for the above-mentioned taconite




particle sizes, are presented in Figure 94.  This curve begins at




0.4 microns which is in the violet region of the optical spectrum,




passes through the visible region (deep blue through deep red to




the human eye) into the near infrared and finally into the inter-




mediate infrared region ending at 3.5 microns for Curve 1 and 2.5




microns for Curve 2.  The green water effect, seen by average




human observers, is caused only by the light in the 0.45 to 0.68 micron




region in the visible spectrum.  (The average human eye cannot see

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the deep blue and deep red colors as easily as the green, yellow




and orange colors).  In the region from 0.5 to 0.7 microns (deep




blue green to red respectively) the curves are reasonably flat and




nearly horizontal.  In this area of the visible spectrum the taconite




is called neutral density substance, i.e. it reflects all colors




from blue green through red equally.  In the area from 0.4 to 0.49 microns




(violet to deep blue green) the reflectance tends quickly toward zero.




This is referred to as a substance exhibiting minus-blue spectral




characteristics.  This is the reason for the smaller taconite




fines appearing yellow-gray in color.  If the reflectance in the




blue were equal to that in the yellow, green and red, the fines




would be gray rather than the observed yellow-gray.




     With this in mind, the reflectance or scattering of light by




a spherical  taconite particle is considered, as shown in Figure 95.




The incident sunlight strikes the particle and is reflected or




scattered off at various angles depicted by the green lines.  This




physical interaction is governed by  the Law of Reflection in




Geometrical  Optics.  A particle that is not spherical, such as




having projections and indentations, will produce a scattering effect




far more diffuse than the spherical  one selected for simplicity of




explanation.




     Now, place the taconite particle in water, as shown in Figure 96.




The incident sunlight strikes the water surface, is bent or




refracted and subsequently strikes the spherical particle as shown by




the green lines.  The light is scattered from the particle and portions




of the light again emerge from the water.  This is the light viewed




by a human observer or camera.  The  characteristic of clear, background

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                          INCIDENT SUNLIGHT
SCATTERED LIGHT
SCATTERED LIGHT
           PARTICLE IS  ASSUMED AS SPHERICAL  FOR SIMPLICITY
           OF EXPLANATION OF LIGHT SCATTERING.
   Figure 95. Scattering  of Sunlight By A Spherical Particle

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      INCIDENT
     SUNLIGHT
                                             SCATTERED
                                               LIGHT
SCATTERED
  LIGHT
                                                  WATER  LEVEL)
                                   SPHERICAL
                                   PARTICLE
     Figure  96. Scattering of Sunlight by Spherical
              Taconite Particle  in Water

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                                -22-






water in Lake Superior is a dark greenish-blue.  The bluish color is




caused by the reflection of the light incident upon the lake's sur-




face from the blue sky.)  With the presence of large numbers of




taconite particles in the water, this background color is lightened




significantly by the scattering process shown in Figure 96.  The




dark-green color is brightened and becomes a lighter green.  The




water containing taconite does not show as yellow or some other




color because taconite reflects all colors from blue green through




red equally, thus the characteristic green color of the water is




retained, but, appears much lighter.




     The origin of the green water effect is explained with the




use of the Infrared Line Scanner data or the so-called "thermal




maps."




     Figure 97 is a high altitude (16,000 feet AGL) thermal map




of the shore line from fro Harbors, Minnesota to a point near




Tofte, Minnesota, from left to right for the reader.  The Reserve




Mining Company effluent delta is in the center of this map.  Figure




98 is the thermal map, at an altitude of 7,500 feet AGL, of the




shore line from Two Harbors to the above mentioned effluent delta.




Figure 99 is the thermal map, at 7,500 feet AGL, of the shore line




from the delta to a point near Tofte, Minnesota.




     In these maps, the white areas are warm white, while the dark




areas are colder.  In Figure 97, notice the dark gray area along




shore, in the Lake, through the full length of the thermal map.  The




temperature of the water in this area is cooler than the water temp-




erature in the white areas near the bottom of the map.  These rela-




tive temperature indications are for the surface of the water only.

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Water is opaque or does not transmit infrared energy in the thermal




band from 8 to 14 microns.  The maximum penetration beneath the




water's surface is 0.01 cm.  With this IRLS imagery and known




facts about Lake Superior circulation, it is possible to explain




the observed areas of green water.




     At the time of flight, Lake Superior was in a near-isothermal




condition.  The entire lake mass was near the temperature of maximum




density for water.  Under this isothermal condition, wind-generated




currents have a significant influence on circulation of the entire lake




depth, as graphically portrayed by Hough.5




     It is generally accepted (Beeton and Chandler)6 that Lake Superior




currents are quickly responsive to wind changes.  As illustrated by




the wind data [Table VII-1], there had been strong offshore winds




for two days prior to the time of flight.  Shear along the wind-water




interface resulted in a surface current toward the southeast.  The




bearing of this current is to the right of the wind vector caused by




the Ekman effect 6»7 resulting from the Coriolis force.  The surface




current moved the surface layer of water toward the Apostle Islands.




This layer was slightly warmer than the underlying water, as a




result of solar heating.  This is depicted by the red arrows in Figure 100.




     The development of an offshore surface current required the




counter-development of a bottom current in opposition to the surface




current.  The bottom current moved to the northwest and surfaced




as an "upwelling" along the northern shore, as indicated by the cooler




water along the shore, in the thermal imagery [Figure 97, 98, 99].




The site of the upwelling was influenced by bottom topography and the




relative calm in the lee of the northern shore.  The vertical

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                               -24-







circulation pattern is depicted in Figure 100.




     EPA divers have previously testified to the presence of billowy




"clouds" of fine taconite tailings (brown arrows on Figure 100)




being detached from the main density current.  The bottom current




(blue arrows in Figure 100) would move opposite to the density current,




and would override the density layer.  This is indicated by the tri-




angular shape of the gray area of surface water in the center of




Figure 97.  This results from the bottom current being forced upward




over the density layer.




     The bottom current upwells along the entire northern shoreline




covered by the flights.  "Green water" conditions were present only




from Beaver Bay to the vicinity of Encampment Island.  This is




because the net movement of suspended tailings solids was a combina-




tion of returning bottom current and the prevalent counter-clockwise




lake circulation.  A predominant longshore current from Silver Bay




toward Duluth is clearly indicated by a geomorphic study of shoreline




features on the imagery and is consistent with published current




studies.3




     The thermal imagery indicates a sharp boundary between the




green  and blue water masses, especially along the northeastern




boundary of the green-water mass (east of Split Rock) as seen in




Figures 99 and 101.  This is further evidence of a superimposition




of a counter-clockwise circulation and an upwelling bottom current.




Stereoscopic examination of the boundary area on the film reveals




that the green-water mass underlies blue water for a short distance




northeast of this boundary.

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                                                                                     EAST
MINNESOTA
SHORE
     Taconite
     Tailings
     Deposited
     on Bottom
                                   Zone  of  Downflow
                                    of the  Warmer
                                    Surface Water
                        is Approximately
                           900 Feet
        Taconite Density Layer
        in Motion Toward Trench
 Eddy Currents  Remove  Fine
  Tailings  from  the Density
  Layer and Form Suspension
   in the  Upwelling  Water.
This  is Due to the Interactions
     of Opposing Currents
             Figure 100. Schematic  Diagram of Wind/Water Interactions Forming Green  Water

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XI.  SUMMARY AND CONCLUSIONS




     The presence of a large mass of green water was recorded along




the Minnesota shore of Lake Superior, between Beaver Bay and Encampment




Island, on 19 October 1972 between the hours of 0917 and 1108 hours




CDT.  The mass covered approximately sixty-six square miles of lake




surface area.




     The color characteristics of the green-water mass and of the




green water in the immediate area of the Reserve Mining Company




taconite effluent were essentially identical indicating that the




mass was made up of taconite tailings.




     The infrared data shows that the green water effect was caused




by wind-induced upwelling along shore, bringing fine suspended




tailings to the surface.  The tailings solids cause the green color




due to reflecting and scattering incident sunlight.  For two days




prior to flight, the upwelling resulted from strong offshore winds,




together with near-isothermal conditions in the lake.




     Numerous small areas of plant growth containing chlorophyl, were




detected on the aerial reconnaissance data from a point near the




Reserve Mining Company effluent delta to Two Harbors, Minnesota




while only one similar spot was found from a point near the delta




to Tofte, Minnesota.




     The data and conclusions given in this report, apply only to




the conditions recorded on October 19, 1972.

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                               -26-
                           REFERENCES
1.  Proceedings from the Lake Superior Enforcement Conference,
    Second Session, April 29-30, 1970, Volume 1, page 223,
    Effects of Taconite on Lake Superior.

2.  Proceedings from Lake Superior Enforcement Conference,
    Executive Session, May 13-15, 1969, September 30-October 1, 1969,
    Volume 1, page 67, An Appraisal of Water Pollution in the
    Lake Superior Basin.

3.  Drift - Bottle Study of the Surface Currents of Lake Superior,
    J. D. Hughes, J. P. Farrell and E. C.  Monahan, Department of
    Geography, Northern Michigan University, Marquette, Michigan.

4.  Geology of the Great Lakes, Jack L. Hough, University of Illinois
    Press, 1958.  Figure 22 on page 51.

5.  The St.  Lawrence Great Lakes:  Limnology in North America,
    A. M. Beeton and D. C. Chandler, D. G. Frey, editor, University
    of Wisconsin Press 1966, page 539.

6.  General Oceanography,  Gunter Dietrich, John Wiley and Sons,
    Copyright 1963, page 340ff.

7.  Elements of Physical Oceanography, Hugh J. McLellan, Pergamon
    Press, 1965.

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                                 -27-
                                 APPENDIX




Focal Length, Angle of View, and the Effects of Focal Length and Altitude

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                                    28
     The  focal  length of the aerial  sensors affects  the  size (or scale)


of the resulting imagery.  At any  given altitude, the  image size


chariges in  direct proportion to  changes in focal length.  Also for a


given focal length, the image size is inversely proportional to the


altitude.


     The  angle  of view of a sensor is a function of  the  focal length


and the image format size.  The  importance of the angle  of view is

its relationship to the amount of  target area recorded in the imagery.


Refer to  the following diagrams:   A. Focal length of a simple lens.


B. Effect of focal length on scale and ground coverage.   C. effect


of altitude on  scale and ground  coverage.
                  Point at
                  Infinity
                                             Reproduction of
                                             point at mfimty-
                                        [— Focal Length*
                                        I
                              -Parallel light rays from infinite
                              distance and a single point source.
                   Diagram A. Focal Length  of a Simple Lens


     Focal length  is  the distance from  the  lens (A) to the film (B)

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                                         29
3-Inch Focal Length  //   \   \
                 //               20,
                                    Ft
                                                                     20,000
                                                                      Ft
                                                                     6-Inch Focal Length
                 30.000 Ft
12-Inch Focal Length
                                   20,000
                                    Ft
                                  500 Ft
                         7,500 Ft
                                                  —/  /— 5,000 Ft
                                                                     18-Inch Focal Length
     DIAGRAM  B   Effect  of Focal Length  on Scale  and Ground  Coverage
                30,000 Ft
                                                  .22,500 Ft
                                10,000 Ft
                                                                       5,000 Ft
                                                                  ,500 Ft
                                                       /— 7,500 Ft
                                   3-Inch Focal Length
       DIAGRAM C    Effect  of Altitude on  Scale and  Ground Coverage

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