\ EPA-450/3-77-038/
   November 1977
                                   MOTOR VEHICLE
                              EMISSIONS CONTROL
                                       BOOK THREE

                               REACTION SYSTEMS
      ::'.;:* '.;:•'•; ;'•>:•.• ;--uv.•;•:•'                 •;/.;.<-'-'::-Jv!vV
          • . • - •»•>:•.•.,             . • i . .'.•••,-. • - A
               *
         U.S. ENVIRONMENTAL PROTECTION AGENCY
              Office of Air and Waste Management
           Office of Air Quality Planning and Standards
          Research Triangle Park, North Carolina 277 1 1

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                                            EPA-450/3-77-038
MOTOR VEHICLE EMISSIONS CONTROL
                    BOOK THREE
  AIR INJECTION  REACTION SYSTEMS
                       B.D. Hayes, Project Director
                    M.T. Maness, Associate Project Director
                     R.A. Ragazzi, Principal Investigator
                   R.A. Barrett, Graduate Research Assistant

                      Department of Industrial Sciences
                        Colorado State University
                       Fort Collins, Colorado 80523
                  EPA Grants No. T008135-01-0 and T900621-01-0

                EPA Region VIII Project Officer: Elmer M. Chenault

                     EPA Project Officer: Bruce Hogarth




                           Prepared for


                U.S. ENVIRONMENTAL PROTECTION AGENCY
                    Office of Air and Waste Management
                  Office of Air Quality Planning and Standards
                   Control Programs Development Division
                  Research Triangle Park, North Carolina 27711

                           November 1977

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Copies of this publication are available free of charge to Federal employees,
current contractors and grantees, and nonprofit organizations - as supplies
permit - from the Library Services Office (MD-35), Environmental Protection
Agency, Research Triangle Park, North Carolina 27711; or, for a fee, from
the National Technical Information Service, 5285 Port Royal Road, Springfield,
Virginia 22161.
This report was furnished to the Environmental Protection Agency by the
Department of Industrial Sciences, Colorado State University, Fort Collins,
Colorado, 80523, through Grants No. T008135-01-0 and No.  T900621- 01-0.
The contents of this report are reproduced herein as received from Colorado
State University. The opinions, findings, and conclusions expressed are
those of the authors and not necessarily those of the Environmental Protection
Agency. Mention of company or product names is not to be considered as
an endorsement by the Environmental Protection Agency.
                        Publication No. EPA-450/3-77-038
                                 11

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           MOTOR VEHICLE EMISSIONS CONTROL
             -- SERIES OF SEVEN BOOKS --
MOTOR VEHICLE EMISSIONS STAFF.,  COLORADO STATE UNIVERSITY
BOOK ONE   -  POSITIVE CRANKCASE VENTILATION SYSTEMS





BOOK TWO   -  THERMOSTATIC AIR CLEANER SYSTEMS





BOOK THREE -  AIR INJECTION REACTION SYSTEMS





BOOK FOUR  -  FUEL EVAPORATION CONTROL SYSTEMS





BOOK FIVE  -  EXHAUST GAS RECIRCULATION SYSTEMS





BOOK SIX   -  SPARK CONTROL SYSTEMS





BOOK SEVEN -  CATALYTIC CONVERTER SYSTEMS
                      ill

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                     ACKNOWLEDGMENTS








The Motor Vehicle Emissions Control Staff of the Department



of Industrial Sciences at Colorado State University would



like to acknowledge the efforts extended by the Environmental



Protection Agency, Research Triangle Park, and Region VIII



Environmental Protection Agency, Manpower Development



Division.








A special thanks must be extended to the automotive vehicle



equipment and parts manufacturers for their cooperation and



assistance in the development of this training material.
                               iv

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            INSTRUCTIONS  FOR THE USE  OF THIS BOOK


This book is one of a series designed specifically to  teach the concepts
of automobile emissions control systems.   Each  book is  designed to be
used as self-instructional material.  Therefore,  it is  important that
you follow the step-by-step procedure format so that you may realize the
full value of the emissions system which  is  being presented.  The topics
are taught in incremental steps and each  topic  treatment prepares the
student for the next topic.  Each book is  divided into  sections which
include the introduction, purpose, function, inspection and testing of
the emissions system presented.

As you proceed through this series, please begin  with  book one and read
the following books in sequence.   This is  important because there are
several instances where material  covered  in  a given book relies on
previously covered material in another book.

To receive the full benefits of the book,  please  answer the self-
evaluation statements related to the material.  These statements are
separated from the text by solid lines crossing the page.  The answers
to the statement can be found at the end of  the book as identified by
the table of contents.  You should check for the  correct answer after
you respond to each statement.   If you find  that  you have made a mistake,
go back through the material which relates to the statement or statements.

Fill-in-the-blank statements are utilized  for self-evaluation purposes
throughout the material.  An example statement  would appear like this:
The  American flag is  red,  white,  and
You would write "blue"  in  the  blank and immediately check your answer at
the end of the book.

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The material, statements and illustrations should be easy to follow and
understand.  In several illustrations a small ghost named "VEC" (Vehicle
Emissions Control) has been used to make the picture easier to understand.

Upon completion of this series, you should be able to better understand
the emissions control systems and devices which are an integral part of
automobiles today.  Your increased knowledge should help you keep these
"emissions controlled" vehicles operating as they were designed to
operate.  Respectable fuel economy, performance and driveability, as well
as cleaner air, can be obtained from the automobile engine that has all
of its emissions systems functioning properly.
                                vi

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                          CONTENTS

Introduction to Emissions Control 	 3-1
     Hydrocarbons 	 3-1
     Carbon Monoxide  	 3-1
     Oxides of Nitrogen	3-2
     Formation of Hydrocarbons  	 3-2
     Formation of Carbon Monoxide 	 .3-3
     Formation of Oxides of Nitrogen  	 3-3
     Ignition Timing  	 3-3
     Carburetion	3-5
System Introduction 	 3-7
System/Component Purpose  	 3-11
     Air Pump	3-12
     Inlet Filters	3-13
     Pressure Relief Valve  	 3-15
     Diverter Valve 	 3-16
     Gulp Valve	3-18
     Check Valve	3-18
     Air Injection Manifold 	 3-20
System/Component Function 	 3-23
     Air Pump	3-23
     Pressure Relief Valve  	 3-24
     Diverter Valve 	 3-24
     Gulp Valve	3-29
     Check Valve	3-30
     Air Injection Manifold 	 3-32
System Inspection 	 3-35
System Testing  . ,	3-37
     Air Pump Test	3-37
     Gulp Valve Test	3-37
     Diverter Valve Test	3-38
     Check Valve Test	3-40
Summary	3-43
Answers	3-45
                            vii

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                 INTRODUCTION TO  EMISSIONS CONTROL
As we all know emissions systems  and devices  have  been  installed on the
automobile engine because of the  air pollution  problem.   In order for
you to understand these emissions systems  and devices you should have a
background of the problem.  All of the  emissions control  systems were
installed on the engine to reduce just  three  specific exhaust products.
These are known as products of combustion.   The  three products which the
emissions systems are designed to reduce are  hydrocarbons, carbon monoxide
and oxides of nitrogen.
                             HYDROCARBONS
Gasoline, like all petroleum products,  is  made  up  of hundreds of hydro-
carbon compounds.  The name "hydrocarbon"  has been given  to these com-
pounds because they are made up of hydrogen and carbon  atoms.  This is
also the reason hydrocarbons have the abbreviation (HC).

Hydrocarbons are gasoline vapors  or raw gasoline itself.  One reason
hydrocarbon emissions must be controlled is because it  is one of the
major components of photochemical smog.  Photochemical  or "Los Angeles"
smog forms when hydrocarbons and  oxides of nitrogen combine in the
presence of sunlight.  In order to avoid this smog condition the hydro-
carbon emissions from automobiles must  be  controlled.   Hydrocarbons
also act as an irritant to our eyes and some  are suspected of causing
cancer and other health problems.
                            CARBON  MONOXIDE
Another product of combustion that must be controlled is carbon monoxide.
Carbon monoxide has the abbreviation (CO). CO  is  also  hazardous to our
health when it is mixed with the  air we breathe.   It can cause headaches,
reduce mental alertness and even  cause  death  if enough  of it is in the
air.  Carbon monoxide is also a problem in that it speeds the formation
of photochemical smog.  For these reasons  CO  emissions  must be controlled.
                                  3-1

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3-2
                              OXIDES OF NITROGEN
     Oxides of nitrogen are the last harmful  products of combustion  we will
     discuss.  Nitrogen oxides have been given the abbreviation  (NO  ).   As
                                                                  /\
     you already know, oxides of nitrogen and hydrocarbons  combine to  form
     photochemical  smog.   The sunlight which  triggers the formation  of photo-
     chemical smog  has another effect on oxides of nitrogen.   Some of  the
     oxides of nitrogen are broken down and a gas  called ozone is  formed.
     Ozone is a lung and eye irritant and it  also  deteriorates rubber  and
     affects the growth of vegetation.  Since the  nitrogen  oxides  have these
     effects they must also be controlled.
     Now that you are familiar with the emissions  which  must  be  controlled
     let's find out where they originate.
                          FORMATION OF  HYDROCARBONS
     Hydrocarbons, you will  recall, are fuel  vapors  or raw  fuel.   For  this
     reason hydrocarbon emissions  will  result from any uncontained supply
     of gasoline.  Hydrocarbon emissions also come from  the tailpipe.   If
     the automobile engine could achieve "complete combustion,"  all  of the
     unburned fuel or hydrocarbons would be  used up.  However, it  is impos-
     sible for today's automobile engines to  achieve  "complete combustion."
     Any time the fuel  mixture in  the combustion chamber is not  completely
     burned,  some hydrocarbons will be  emitted from  the  tailpipe.   The two
     main'reasons why hydrocarbons are  not completely burned  are because of
     engine misfire and "quench areas."  When an engine  misfire  occurs, none
     of the raw fuel  or hydrocarbons  are burned.   When this happens  they are
     simply exhausted directly to  the atmosphere.  Quench areas  are  places in
     the combustion chamber  where  the flame  goes out before the  fuel is com-
     pletely burned.   Small  cavities  such  as  where the head gasket seals the
     cylinder head to the block is a  quench  area.  Another  quench  area is
     located  between  the top of the piston and the first compression ring.
     These areas are  sources of hydrocarbon  emissions.

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                                                                    3-3
                   FORMATION OF  CARBON  MONOXIDE
Carbon monoxide fs partially burned fuel.   Carbon  monoxide  is  formed in
the combustion chamber whenever there is  not enough  air  to  burn all the
fuel.  This means that whenever a "rich"  air/fuel  mixture is pulled into
the combustion chamber carbon monoxide will  be  formed.   After  the flame
goes out the carbon monoxide is exhausted  through the tailpipe  and into
the air.

                  FORMATION OF OXIDES OF NITROGEN
Oxides of nitrogen are also formed  in the combustion chamber.  These
oxides result from the nitrogen which Is  contained in our air.  In some
cases combustion temperatures in the automobile engine can  exceed 4500°F.
At temperatures above approximately 2500°F,  nitrogen oxides will start
forming.  Therefore,  if combustion  chamber  temperatures  exceed 2500°F,
oxides of nitrogen will be produced and then exhausted to our  atmosphere.

Now that you understand how these emissions  are formed in the  automobile
engine, we will see how changes in  ignition  timing and carburetor adjust-
ment affect the amount of these pollutants.

As you know,  changes  in timing and  carburetion  can have  a large effect
on how an engine performs.  These changes in timing  and  carburetion also
can have drastic effects on the amount of pollutants which  are present
in the automobile's exhaust.   The amount  of  hydrocarbons, carbon monoxide
and oxides of nitrogen which are present  in  the exhaust  gases will vary
as timing and carburetion adjustments are changed.
                            IGNITION TIMING
Prior to emissions controlled automobiles, advancing the spark timing
was a common  practice.  Setting the spark timing this way caused the
spark plug to fire before the piston reached top dead center.  This
advanced spark timing allowed the maximum amount of  heat energy to be

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3-4
     exerted on the piston.  As a result the best performance and fuel econ-
     omy could be obtained.  Unfortunately, this also produced high hydro-
     carbon and nitrogen oxide emissions levels.

     In order to reduce emissions levels, ignition spark timing was retarded.
     By firing the spark plug after the piston reaches top dead center, not
     as much of the heat energy is converted to work on the piston.  The
     extra heat energy which is not used on the piston now passes through
     the exhaust valve and into the exhaust manifold.  This keeps the exhaust
     gas temperatures higher.  These higher exhaust temperatures allow burning
     of the air/fuel  mixture to continue in the exhaust manifold.  This further
     oxidation or burning in the exhaust manifold helps to reduce HC and CO
     emissions.

     Another advantage of retarded timing from an emissions standpoint is
     that combustion  temperatures are not as high.  This is due to the fact
     that the maximum combustion pressure will be lower.  Since the combustion
     temperatures will be lower and the formation of oxides of nitrogen de-
     pends on temperature, a smaller amount of these pollutants will be ex-
     hausted to the atmosphere.

     There is one more advantage to using retarded spark timing.  As you know,
     when ignition timing is retarded the engine's idle speed will drop.  This
     decrease in idle speed occurs because less heat energy is applied to the
     combustion chamber and more heat energy is being supplied to continue the
     burning process  in the exhaust manifold.   In order to regain an acceptable
     idle speed, the  throttle plates must be opened wider.  This wider throttle
     plate opening allows more air to pass through the carburetor.  This increase
     in air flow will  reduce the amount of residual exhaust gases in the cylinder,
     This in turn will allow a more burnable mixture which can be made leaner.
     Since the mixture can be leaner there will be more air in the combustion
     chamber.  As you know, the more air that is made available during com-
     bustion the lower will be the HC and CO emissions.

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                                                                    3-5
                              CARBURET I ON
Adjustments made to the carburetor air/fuel ratio can also have a large
effect on the amount of pollutants which come from the automobile engine.
When idle mixture settings become richer there is less air present for
the combustion process.  This lack of air results in an increase in hydro-
carbon and carbon monoxide emissions.

When idle mixture screws are turned in, the amount of fuel is reduced
and the mixture becomes leaner.   This leaner mixture contains more air
and therefore more oxygen is available for more complete burning of the
fuel.  This results in lower HC  and CO emissions levels.

As the idle mixture screws are turned in, the idle air/fuel mixture be-
comes leaner.  If this mixture becomes too lean a "lean misfire" will
occur.  A "lean misfire" will occur because the fuel is so diluted or
thinned out by the air that the  mixture will not ignite.  This leads to
a very large increase in hydrocarbon emissions.  This happens because
the failure of the mixture to ignite results in that amount of raw fuel
being emitted to the atmosphere.

The carbon monoxide emissions decrease when a lean misfire condition is
present.  Carbon monoxide is partially burned fuel.  Since no combustion
takes place during a lean misfire condition no CO is formed and the total
amount of CO produced by the engine will be less.

A lean misfire usually occurs in one or more cylinders.  This condition
may also move from cylinder to cylinder while the engine is running.
This is caused by the uneven distribution of the air/fuel mixture
delivered to each cylinder.  This condition occurs mainly because of
problems with intake manifold design.

Now you should understand how changes in timing and carburetion adjust-
ment can affect emissions levels.  With this knowledge you will be able
to understand how each emissions control system we will discuss helps to
reduce the air pollution caused  by the automobile.

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                                                                    AIR
                                                                    3-7
                       SYSTEM INTRODUCTION
The next system we are going to discuss  is  the AIR  system.  As you  remem-
ber from the introduction of this book,  hydrocarbons  and  carbon  monoxide
emissions must be controlled.  The AIR system greatly helps reduce  these
two emissions.  Before we go any further with this  system let's  briefly
review what happens after the exhaust gases leave the combustion chamber.

As you recall when ignition spark timing is retarded  the  exhaust gas
temperatures will be hotter.  Using retarded timing helped to continue the
burning or "oxidizing" of the unburned hydrocarbons and carbon monoxide.
This takes place because there is a small amount of air in the exhaust
manifold and when the hot exhaust gases  come in contact with this air
they can continue to burn.  The amount of burning which takes place in
the exhaust manifold depends on just how much air is  availalbe.   Unfortu-
nately, there is not enough air in the manifold to  burn all the  hydrocar-
bons and carbon monoxide which are present  in the exhaust gases.

The AIR system is designed to supply more air to the  exhaust manifold and
actually burn the unburned portion of the exhaust gases.   This reduces
the harmful hydrocarbon, HC, and carbon  monoxide, CO, emissions.  These
exhaust gases should be further oxidized before they  go out the  tailpipe.
Because of the incomplete combustion taking place in  the  cylinders,
carbon monoxide and hydrocarbons are pushed out of  the cylinders  during
the exhaust stroke.  If the hydrocarbons and carbon monoxide in  the
exhaust manifold continued to burn, the  harmful gas, carbon monoxide,would
change to the harmless gas, carbon dioxide  which has  a symbol CCL.  The
HC that is burned in the exhaust manifold because of  the  AIR system, is
reduced to water vapors which have a symbol ^0.

The AIR system injects air into the exhaust manifold. This is how  this
system got its name.  AIR stands for air injection  reaction.  However,
different manufacturers have their own name for this  system.  Figure 3-1
shows the different names which are used for this system.  Even  though

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3-8
n

VEHICLE
MANUFACT.
AMERICAN
MOTORS^tORP
CHRYSLER
CORPORATION
fi)RD MOTOR
COMPANY
GENERAL
MOTORS CORR
AIR INJECTION
SYSTEM
A, G.
(AIR GUARD)
AIR
INJECTION
THERMACTOR
A.I.R.
(AIR INJECTOR
REACTOR)

^^
                                 FIGURE  3-1

     each  manufacturer uses a different name for this system they  all have the
     same  purpose and all function in  the same way.

     The AIR system was first used on  automobile engines in 1966.   During 1966
     and 1967 most of the automobiles  which were equipped with an AIR system
     were  sold  in California.  Starting in 1968 AIR systems were installed on
     many  engines throughout the country.  Many of the foreign automobiles
     which are  imported into this country also have air injection  systems.

     Since the  AIR system does its job after the combustion takes  place in the
     cylinder,  the system is very beneficial.  It does an effective job of
     reducing HC and CO from the exhaust.  It also allows the manufacturers to
     change carburetion and ignition timing to give better driveability.
     1.    The amount of  secondary burning or  oxidizing which takes
          place in  the exhaust  manifold depends on  how much 	
          is  available.

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2.   The AIR system injects fresh air into the
                                                          AIR
                                                          3-9
3.   AIR is the abbreviation for
4.    The AIR system does its job after
     takes place in the cylinders.
5.                             and
     are effectively reduced by the AIR system.
6.    By using the AIR system manufacturers could change
     	 and ignition timing to give us
     better driveability.

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                                                                    AIR
                                                                    3-11
                   SYSTEM/COMPONENT  PURPOSE


Now that you are  familiar with how the AIR system helps control  the
emissions of hydrocarbons and carbon monoxide it is time to take a
closer look at the  components of this system.  First you will  look at
each component separately to find out what part it plays in the  AIR
system.

The components of the  AIR system are shown in figure 3-2.  As  you can
see this system is  composed of an air pump, a diverter valve,  a  check
                                   MANIFOLD  VACUUM
                                   SIGNAL LINE
                  DIVERTER
                  VALVE
                            MANIFOLD
                             FIGURE  3-2

valve, an air injection or distribution manifold and the connecting hoses
and vacuum lines.   V8 engines use  two check valves and two injection
manifolds.

Figure 3-3 shows where these  components are usually located on a V8
engine.

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3-12
                 CONNECTING
                 HOSE
                CHECK
                VALVE
CONNECTING
    CHECK
    VALVE
                                  FIGURE 3-3

                                  AIR PUMP
     Since the AIR system supplies the exhaust manifold(s)  with additional
     air to oxidize or burn the hydrocarbons and carbon monoxide, a means of
     "pumping" outside air into the exhaust manifold must be used.   This is
     the job of the air pump.  The air pump is a belt driven pump and as you
     can see in figure 3-4, it is located much like other belt driven engine
     components.
                                  FIGURE 3-4

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                                                                    AIR
                                                                    3-13
The air pump drav/s fresh air from the engine  compartment  through an
inlet, usually located in the pump itself.   Part  of this air  inlet serves
as a filter to remove any foreign matter from the air.   If dirt or dust
is allowed into the air pump it could possibly damage  the  pump and render
the system useless.

                          INLET  FILTERS
The most popular air pump inlet and filter  arrangement is  shown in
figure 3-5.
                                           AIR  INLET
                             FIGURE 3-5

The air enters the pump and is  filtered by  a  centrifugal fan filter.
This filter is actually part of the pump itself.

The second method which can be  used is  the  external filter shown in
figure 3-6.

As you can see the filter and air  inlet are separated from the pump
itself.  A hose is used to connect the  filter to the pump.
Figure 3-7 shows the location  of  the  pump discharge or outlet.

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3-14
                    AIR  INLET
                                 FIGURE 3-6
                PULLEY
                                                   PUMP
                                                   DISCHARGE
                  AIR IN
TO DIVERTER VALVE
                                 FIGURE  3-7
    A hose is connected to the pump  outlet  so  the supply air can move on to
    the diverter valve and injection manifolds.

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                                                                AIR
                                                                3-15
     An
supplies the air for the air injection
      system.
8.   Before air  enters  the pump  it passes through an
     	 to remove any  dust particles.
9.   The AIR  system uses a
             driven pump.
                    PRESSURE RELIEF VALVE
The air  pump is usually equipped with a pressure relief valve.   This
valve is shown in figure 3-8.  This  pressure relief  valve limits the
maximum  pressure from the pump.  This is done to prevent exhaust system
                            PRESSURE RELIEF VALVE
                           FIGURE  3-8
overheating at high engine speeds.   Limiting the maximum pump pressure
can also be done at the diverter valve.  For this reason, not all  air
pumps will have a built-in pressure  relief valve.

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3-16
                              DIVERIER VALVE
     A diverter or anti-backfire valve  and  its  various  connections  is shown
     in figure 3-9.
                TO AIR
                MANIFOLD 8
                CHECK VALVE
                           /
                DIVERTED  AIR
                TO ATMOSPHERE
                                                  INTAKE
                                                  MANIFOLD
                                                  VACUUM
                                                       ?> AIR
                                                       ANIFOLD
                                                       CHECK
                                                     vALVE
FROM
AIR
PUMP
                                  FIGURE  3-9
     This valve has been called several  different  names.  The purpose of the
     valve,  regardless  of its  name,  is  the  same.   The  valve's job is to prevent
     backfire by momentarily diverting  the  air  pump's  output.  This is done so
     that air does not  reach the exhaust valve  area during the initial stages
     of engine deceleration.  Engine deceleration  takes place when you take your
     foot off the gas pedal.  When  this  occurs  the throttle  plates in the
     carburetor close creating a high vacuum  condition just  beneath the throttle
     plates.   Because of this  vacuum condition  rich air/fuel mixture is drawn
     into the cylinders.  This rich  mixture cannot burn completely during the
     power stroke so much of the mixture is pushed out past  the exhaust valves
     and into the exhaust manifold.   If  the AIR system was allowed to inject
     fresh air into the exhaust ports under this condition,  an undesirable
     backfire would occur.  This backfire would take place as soon as the fresh
     air mixed with the overly rich  exhaust gases.  This  valve is called a
     diverter valve because it diverts  the  air  from the air  pump away from the
     exhaust manifold and out  to the atmosphere.   It's called an anti-backfire
     valve because it prevents backfiring during deceleration.

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                                                              AIR
                                                              3-17
A muffler was installed on the diverter valve to prevent the loud noise
when the valve diverts the air to the  atmosphere.  On newer engines, the
muffler is internal and you cannot see it.  The older type diverter
valves had an external muffler.  Figure 3-10 shows both types of diverter
valves.
                       DIVERTER VALVES
           EXTERNAL MUFFLER
INTERNAL MUFFLER
                          FIGURE 3-10
10.  Most air pumps  are equipped  with a
                   valve.
11.  Maximum pump pressure is limited by the  pressure relief
     valve.   This is  done to prevent exhaust  system
     	 at high speeds.
12.  In order to prevent a
              in  the exhaust
     system during deceleration,  the AIR system uses a diver-
     ter  valve.

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3-18
     13.  The diverter valve  is usually very noisy when  it diverts
          air to the  atmosphere.  To prevent this  noise  a
                           was  installed.
                               GULP VALVE
     Some manufacturers  use another type of  anti-backfire valve which 1s called
     a gulp valve.   This valve allows air from the air pump to be sent to the
     intake manifold when the engine decelerates.  This air will dilute the
     rich fuel mixture before it goes into the cylinder, thus preventing a
     backfire.  Figure 3-11 shows a gulp valve.
                               GULP  VALVE
                                FIGURE 3-11
                              CHECK VALVE
    The next component of the AIR system we shall  discuss  is the check
    valve.  A check, valve is used to  prevent exhaust gases from reaching the
    hoses, pump or  anti-backfire  valve.

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                                                                  AIR
                                                                  3-19
The air pump has  enough pressure to keep  the air flowing toward  the air
pipe assemblies.   But what would happen if the pump stopped pumping air
for some reason or if an air hose would break?  Exhaust gases  would go
into the air pipe assembly instead of the tailpipe.  It is  the check
valve's job to prevent this from occuring.  The check valve prevents hot
exhaust gases from backing up into the hoses and pump.   A check  valve is
shown in figure 3-12.  The check valve is a one-way valve.   This means
                           CHECK  VALVE
                            FIGURE  3-12

that it will  permit air to flow 1n only one direction or one way.  On an
in-line engine  there is only one check valve, because there is only one
air injection manifold.  There are two air injection manifolds on V8
engines and therefore two check valves.  Check valves are usually mounted
on the air injection manifold and connect to the diverter valve with a
rubber hose.
14.   The gulp valve used  by some  manufacturers  diverts air
      from the air  pump to the 	  _______________
      during  the first few  seconds of deceleration.

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3-20
     15.   During the  first few seconds of deceleration the  gulp
          valve will  dilute the rich fuel mixture before  it goes
          into the cylinder, thus  preventing a	.
    16.   When exhaust  pressure is  higher than  the system air
          pressure, the 	  valve prevents  the back  flow of
          exhaust gas into the air  supply hoses.
                      AIR  INJECTION  MANIFOLD
    The last component of the AIR system  we shall  discuss is  the air injection
    manifold.  Some manufacturers call  their injection manifold an air
    distribution manifold.  The purpose of the air injection  manifold is to
    distribute the pump air to the exhaust ports of each cylinder.  As you
    can see in figure 3-13, only one manifold is used for an  in-line engine.
                     AIR  INJECTION MANIFOLDS
               6 CYLINDER
                                      8  CYLINDER
                              FIGURE 3-13

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                                                                  AIR
                                                                  3-21
A V8 engine will use two injection manifolds.   These manifolds usually
have one outlet or nozzle for  each cylinder.   In  some applications,  how-
ever, this may not be the case.  Because of design  limitations some  V8
engines have only seven nozzles.  These nozzles are usually located  very
near the exhaust valves.  Figure 3-14 shows the exhaust valve and air
injection nozzle location usually found on an  AIR equipped automobile.
                            FIGURE 3-14
17.   The air  injection manifold distributes the pump air  to
      the 	 ports of  each cylinder.
18.   Some V8  engines  have only
      design  limitations.
nozzles because of
Now that you are familiar with all of the AIR  system components  it  is time
to take a closer look at how they function.

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                                                                   AIR
                                                                   3-23
                   SYSTEM/COMPONENT FUNCTION


You will recall  from  the last section of this  chapter that an AIR system
has four basic components.  These are the air  pump, anti-backfire valve,
check valve and  the air injection manifold.  Now we shall look more
closely at each  of these components so you can understand how they do
their job.
                            AIR  PUMP
As you remember  the belt driven air pump supplies the system with air to
be injected into the  exhaust manifold.  This pump is a rotary vane type
pump.  The air pump is made up of a pump housing, a rotor, and vanes.
Most air pumps have between 2 and 5 vanes. Figure 3-15 shows a simplified
view of the inside of the air pump.  After the air is filtered to remove
               CROSS  SECTION OF AIR  PUMP
                 VANE
             ROTOR
             PUMP
             HOUSING
             VANE  SEALS
                                           OUTLET
                                              INLET
                            FIGURE 3-15
any dirt or dust  it enters the inlet of the pump.  As the vanes  move
around the pump housing they pull  air through the inlet and push it out
through the outlet.  The arrows in figure  3-15 show the flow direction of
air through the pump.

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3-24
                         PRESSURE  RELIEF  VALVE
     A spring loaded valve is  used as a pressure relief  valve on those air
     pumps which have a built-in  relief valve.  As  you recall, maximum pump
     pressure must be limited  to  prevent exhaust system  overheating at high
     engine speeds.  When pressure in the pump exceeds a maximum pressure
     level the relief valve spring will be compressed, opening the valve.
     With this condition the excess air will pass through the valve to the
     atmosphere.  When the pump pressure drops back to a safe level the
     relief valve will close and  the pump will operate normally again.
     19.  Maximum  pump pressure  is limited by  the pressure  relief
          valve to prevent exhaust system overheating at 	
          engine speeds.
     20.  When pump pressure exceeds  its preset maximum pressure
          level,  the relief valve will  vent the excess pressure to
          the
                             DIVERTER VALVE
     The purpose of the diverter or  anti-backfire valve is  to divert pump air
     to the atmosphere during the first few seconds of engine deceleration.
     Now let's  see how this valve accomplishes this.  A combination diverter
     and pressure regulator valve is shown in figure 3-16.  This diverter
     valve is made up of two valve plates, a spring loaded  stem, a diaphragm
     and a diaphragm spring.  The diverter valve has an inlet connection for
     the air supply from the pump, an outlet for air to reach the injection
     manifold,  and a signal line from the intake manifold.  This manifold
     vacuum line provides the signal which tells the diverter valve when to
     "dump" its air to the atmosphere.

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                                                                    AIR
                                                                    3-25
            DIAPHRAGM
            SPRING
            TO CHECK
            VALVE
            VALVE
            PLATES
                                             MANIFOLD
                                             VACUUM
TO CHECK
VALVE
                                                 TO AIR
                                                 PUMP
                                              STEM
                             FIGURE  3-16


When the engine is  operating  vacuum  will  be applied to both the upper and

lower sides of the  diaphragm.   This  is  accomplished by the use of a

timing orifice located in the diaphragm itself.  Figure 3-17  shows the

location of this orifice.   In this position the diaphragm spring will

raise the stem and  unseat the upper  valve plate.  When the diverter valve
            TIMING
            ORIFICE
            DIAPHRAGM
            SPRING
            VALVE
            PLATES
                                              MANIFOLD
                                              VACUUM
                                               STEM
                             FIGURE  3-17

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3-26
     is operating in this manner, air will  flow from the valve inlet past the
     upper valve plate and out through the valve outlet.  This flow of air
     through the diverter valve is shown in figure 3-18.
                 TO AIR
                 INJECTION
                 MANIFOLD
 TO  AIR
INJECTION
MANIFOLD
FROM AIR
PUMP
                                  FIGURE 3-18
     A high intake manifold vacuum will result when the carburetor throttle
     plates close during deceleration.  This high vacuum condition will act
     on the diaphragm in the diverter valve pulling it downward.  The
     diaphragm spring will compress, thus moving the stem downward.  When this
     happens the lower valve plate will be unseated and the air will be
     diverted through a muffler to the atmosphere.  Figure 3-19 shows how
     the air will flow through the diverter valve when it is in the dump
     position.

     Since the diaphragm has a timing orifice built into it which connects
     the upper and lower sides of the diaphragm the unequal vacuum conditions
     will stabilize.  When the vacuum on both sides of the diaphragm becomes
     equal the diaphragm spring will push the stem up again and unseat the
     upper valve plate.  When this happens the air will again flow to the
     injection manifold(s).  This equalizing of the two vacuum chambers
     will usually take approximately 2 to 3 seconds.  Thus the air will only
     be diverted to the atmosphere for the first few seconds of deceleration
     when the excessively rich mixture is liable to cause a backfire.

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             VENT
                                                                    AIR
                                                                    3-27
SEATED
                             FIGURE  3-19
When the engine is  turning  at  a  high RPM excessive pump pressure will be
produced.  It is the  diverter  pressure regulator valve's job to limit
this pressure.   As  you  can  see in  figure 3-20, when the excessive pump
pressure acts upon  the  diverter  pressure regulator valve, the lower valve
             5PSI
             VENT
      5PSI
                            FIGURE 3-20

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3-28
    plate will  unseat.  This will vent pump air to the atmosphere to hold
    the pressure to a pre-determined maximum.
    21.  The purpose  of  the anti-backfire valve is to divert pump
         air to the atmosphere during  the first few seconds of
         engine 	.
    22.  The vacuum  signal  which tells the diverter valve when  to
         "dump"  its  air  to  the 	 is provided
         by the  intake manifold.
    23.  The unequal  vacuum conditions created in the diverter
         valve diaphragm chambers will equalize through the  built-
         in	  	 during deceleration.
    24.  When  the  vacuum on both sides of the diverter valve
         diaphragm becomes equal the air will again flow  to the
    25.   It  usually takes approximately two to three
          for  the  two vacuum chambers in the diverter valve  to
          equalize.

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                                                                    AIR
                                                                    3-29
                           GULP VALVE

This second type of anti-backfire  valve  is  known as a gulp valve.  As you

can see in figure 3-21,  this  valve is  teed  into the supply line between

the air pump and the injection  manifold.   In order to prevent backfire on

deceleration the gulp valve diverts  pump  air to the intake manifold.
•0
*
V,
DISTRIBUTION
.MANIFOLD
rTt\
AIR

Q ' f- — '
Y
CHECK
VALVE
JLi

J V
r

ii ii .. ..
q
r . f
SIGNAL LINE
TO
INTAKE
J MANIFOLD^

^ J
^ i ^ i^~~^^
D f A,
J> ' K
GULP VALVE IN
R DISCHARGE
)
FAKE MANIFOLD^
                            FIGURE  3-21


Figure 3-22 shows an inside  view  of the  gulp  valve.  You will notice that

the upper diaphragm chamber  and valve  stem are much the same as the
          INTAKE
          MANIFOLD
          VACUUM
          SIGNAL
                                            AIR FROM
                                            AIR PUMP
           AIR DISCHARGE
           TO INTAKE
           MANIFOLD
                                    'AIR VALVE
                            FIGURE 3-22

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3-30
     diverter valve.   An intake manifold vacuum signal  is  used  to  dump  the
     gulp valve in the same manner as  the diverter valve.   When a  high  intake
     manifold vacuum occurs the diaphragm will  be  pulled down against spring
     force.   This will open the valve  and pump  air will pass through the  gulp
     valve to the intake manifold.  A  small  timing orifice in the  diaphragm
     will slowly equalize the vacuum on  both sides of  the  diaphragm returning
     the valve to a closed position.   This will  take only  a few seconds as
     does a  diverter valve.  After the gulp  valve  closes the air will again
     flow to the injection manifold.
                                CHECK  VALVE
     The check valve which is usually  mounted on the air injection manifold
     is a one-way valve.  This valve will allow air to pass from the pump
     side to the injection manifold side.  It will not allow air flow from the
     injection manifold side to the air  pump side.

     This valve, as you can see in figure 3-23,  is a simple spring loaded
     device.  When the air pump pressure exceeds the exhaust system pressure
                                  CHECK
                                  VALVE^
              rrrm
                         AIR INJECTION MANIFOLD
                                 FIGURE 3-23
     the air will flow through the check valve as  shown in  figure  3-24.   The
     check valve spring will  be compressed and the air will  flow around  the

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                                                                   AIR
                                                                   3-31
                        CHECK VALVE
                           FIGURE 3-24

valve plate and  through the valve to the air injection manifold.  If for
any reason the exhaust system pressure is greater than the air pump
pressure the valve plate will seat preventing flow through the valve.
This condition is shown in figure 3-25.
                           FIGURE 3-25

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3-32
     26.   Another type of anti-backfire valve  is known as  a
                   valve.
    27.   Gulp valves  are teed  into the supply line between the
                                    	 and  the air pump.
    28.   The gulp valve diverts  pump air to  the
                            to prevent backfire on deceleration,
     29.   Usually mounted on the  injection manifold is a  check
          valve.  A  check valve will allow flow in 	
          direction.
     30.   The check  valve used  in the AIR system will allow air to
          pass through it from  the 	  side to the  injection
          manifold side.
                       AIR INJECTION MANIFOLD
     As you recall the purpose of the air injection or distribution manifold
     is to distribute the pump air to each cylinder.   This manifold is made of
     tubing with the cylinder nozzles all connected to a common line.  With
     this arrangement all the cylinders will  receive air.  Some engines may
     have passageways cut in the cylinder head instead of using an injection
     manifold.  These passageways distribute  and inject air in the same manner
     as an injection manifold.

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                                                              AIR
                                                              3-33
                 AIR  INJECTION  MANIFOLDS
           6 CYLINDER
                                  8  CYLINDER
                          FIGURE 3-26
31.  To  complete the AIR system  the air pump,  diverter valve,
     check valve, and  	 manifold are connected
     with hoses and pipes.
Now you should  understand  the AIR system.  It  is now time to look at the
maintenance procedures required to keep this system operating properly.

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                                                                    A1K
                                                                    3-35
                        SYSTEM INSPECTION


An Inspection of the AIR system should be made periodically  and  previous
to any testing of the system.   This inspection will  require  only simple
tools and takes only a few minutes.  Many problems may  be  avoided or
corrected by these steps.

      1.  Check to see that all  components are properly installed on
          the engine and no modifications have been  made.  Air pump,
          drive belt, anti-backfire valve, check valve, manifold and
          all connecting hoses should be in place.

          In order for the AIR system to function as it was  designed
          all components must  be installed correctly.

      2.  Inspect the air inlet filter if the system is so equipped.
          If the filter is excessively dirty it should  be  replaced.

          If the air inlet filter is dirty the air supply  for  the
          pump may be restricted.   This will  result  in  reduced effec-
          tiveness of the entire system.

      3.  The air pump drive belt  should be inspected for  excessive
          wear.  If the belt condition is unacceptable  it  should be
          replaced.  In addition,  this belt must be  tightened  according
          to manufacturer's specifications.

          If the drive belt is worn or too loose, the pump efficiency
          will  be reduced and  the  effectiveness  of the  entire  system
          will  suffer.

      4.  Check the system connecting hoses  for  cracks,  deterioration
          and loose connections.

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3-36
              Any air leaks in the  system will reduce the AIR system's
              effectiveness.  In addition, if air leaks  into the anti-
              backfire valve's signal line, a backfire condition on
              deceleration may occur.
     32.   The AIR  system should be inspected periodically and
          before                  the system.
     33.   All 	 of the  AIR system  must be
          installed correctly  in order for the system to function
          as it  was designed.

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                                                                    AIR
                                                                    3-37
                         SYSTEM TESTING
The AIR system should be tested periodically  or  anytime  it is suspected
to be working improperly.  The components  of  the AIR  system which require
testing are the air pump, anti-backfire valve and  the check valve(s).
                          AIR PUMP  TEST
Manufacturer's specifications should  be consulted  when testing the air
pump as with all other test procedures.  Figure  3-27  shows the procedure
recommended by one manufacturer.   They recommended the pump be tested
                            FIGURE  3-27

using a special  test tee  and pressure  gauge connected into the outlet hose
of the pump. •  The pump air  pressure is then measured at a specified
engine speed.

                         GULP  VALVE  TEST
The anti-backfire valve must also be tested to see that it is operating
correctly.   The  gulp valve,  if  used,can be tested as shown in figure 3-28.
With the engine  idling the  by-pass  hose should be pinched shut somewhere
between the valve and the intake manifold.  If the valve is operating
properly the  idle RPM should not change.  Now the vacuum signal  line should

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3-38
                           AIR TO
                           INTAKE MANIFOLD
                                 FIGURE 3-28

     be removed  for about 5 seconds, then replaced.  If the gulp valve  is  oper-
     ating  correctly, the engine will run rough for about 1-3 seconds.  Always
     check  the manufacturer's specifications before conducting this  test.   On
     certain  foreign models youwill damage the air pump by pinching  the  hose shut.
                           DIVERTER VALVE  TEST
     Figure 3-29 shows the first step to testing the diverter type  anti-backfire
                                FIGURE 3-29

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                                                                     AIR
                                                                     3-39
valve.  With the engine idling, hold your fingers by the vent port.  No
air should be felt escaping from the vent.  The engine should then be
sped up to produce excessive pump pressure.  As shown in figure 3-30,
some air should be felt escaping from the combination pressure regulator
                            FIGURE 3-30

diverter valve or the pump relief valve.  When the engine is decelerated
from the high engine speed hold your fingers by the diverter valve vent.
As you can see in figure 3-31, you should feel all the air from the pump
                            FIGURE  3-31

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3-40
     being vented for  1  to  3  seconds.  If the valve fails to operate properly,
     you should check  the vacuum signal line before replacing the valve.  Figure
     3-32 shows that manifold vacuum should be present in this line.
                                 FIGURE  3-32

                             CHECK  VALVE  TEST
     The last component to  be tested in  the AIR system is the check valve.
     To test the check  valve  you  must first remove the air supply hose from
                                 FIGURE  3-33

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                                                                 AIR
                                                                 3-41
the check  valve.  With the  engine running,  carefully hold your hand over
the check  valve and feel  for any leakage.   There should be no  exhaust
escaping from the check valve.  The engine  should now be shut  off and a
simple test made to assure  that the check valve is not stuck closed.  As
you can see in figure 3-34, when you push down on the check valve with a
screwdriver or solid rod  the valve plate should move freely.
                           FIGURE 3-34

Lastly to  test for leaks  with the engine operating, use soap and water
on a brush while watching for bubbles at the  connections.

After you  have performed  these tests you will be sure that the AIR system
is operating properly and helping to keep our air clean.
34.   One test which  should  be done  to the  diverter  valve  is to
      decelerate the  engine  from a high speed while holding  your
      fingers by the	 vent.   As  the
      engine slows down you  should feel all  the air  from the
      pump being vented for  only 1 to 3 seconds.

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3-42
    35.  When testing a check valve you should push down on  the
         check valve with a screwdriver or solid rod.  The
         	^^   	   should move freely.

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                                                                    AIR
                                                                    3-43
                          SYSTEM SUMMARY


                               PURPOSE
The purpose of the air injection  system  is to supply additional oxygen
(air) at the exhaust ports  near the  exhaust valves to extend the combus-
tion process into the exhaust  system.  This reduces the unburned hydro-
carbon and carbon monoxide  emissions.

                          MAIN COMPONENTS
Air Pump - Supplies filtered low  pressure air to the system.

Diverter Valve - Diverts  air pump output to atmosphere during decelera-
tion to prevent backfire  and has  a built-in pressure relief valve to
protect the system.

Check Valve - Prevents hot  exhaust gases from backing up into the hoses
and pump.

Air Manifold - Distributes  air to each cylinder.

Air Nozzles - Injects air to each exhaust passage near the exhaust valves.

Manifold Vacuum Signal Line -  Senses manifold vacuum to actuate the
diverter valve.
                          SYSTEM FUNCTION
During normal operating conditions the air pump supplies air to the diver-
ter valve which then passes the air  on to the air nozzles for injection
into the exhaust manifold.   There the hot exhausted gases receive the
fresh oxygen charge and undergo further  combustion.  During deceleration
there is high intake manifold  vacuum and an excessively rich fuel mixture.
If fresh oxygen were supplied  to  these exhaust gases, reignition and
engine backfire could result.   The diverted valve senses the high intake
manifold vacuum and vents air  from the pump to the atmosphere.

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                                                        AIR
                                                        3-45
                        ANSWERS

 1.   air
 2.   exhaust manifold
 3.   air injection reaction
 4.   combustion
 5.   hydrocarbons, carbon monoxide
 6.   carburetion
 7.   air pump
 8.   air filter
 9.   belt
10.   pressure relief
11.   overheating
12.   backfire
13.   muffler
14.   intake manifold
15.   backfire
16.   check
17.   exhaust
18.   seven
19.   high
20.   atmosphere
21.   deceleration
22.   atmosphere
23.   timing orifice
24.   injection manifold or exhaust ports
25.   seconds
26.   gulp
27.   injection or distribution manifold
28.   intake manifold
2 9.   one
30.   pump
31.   injection or distribution
32.   testing
33.   components
34.   diverter valve
35.   valve plate

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
 1. REPORT NO.
    EPA-450/3-77-038
                                                           3. RECIPIENT'S ACCESSION-NO.
4. TITLE AND SUBTITLE
   Motor Vehicle Emissions Control - Book  Three
   Air Injection Reaction Systems
                                                           5. REPORT DATE
                                                                 November 1977
                                                   6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
                                                           8. PERFORMING ORGANIZATION REPORT NO.
   B.D.

   M.T.
Hayes
Maness
R.A. Ragazzi
R.A. Barrett
9. PERFORMING ORGANIZATION NAME AND ADDRESS
   Department of  Industrial Sciences
   Colorado State University
   Fort Collins,  Colorado  80523
                                                            10. PROGRAM ELEMENT NO.
                                                    11. CONTRACT/GRANT NO.
                                                     T008135-01-0
                                                     T900621-01-0
 12. SPONSORING AGENCY NAME AND ADDRESS
   Control Programs  Development Division
   Office of Air Quality Planning and Standards
   Office of Air and Waste Management
   U.S.  Environmental Protection Agency
                                                    13. TYPE OF REPORT AND PERIOD COVERED

                                                     Final  RennrE	
                                                    14.
                                 Final  Rep<
                                 SPONSORING
                                                               AGENCY CODE

                                                          EPA    200/04
15. SUPPLEMENTARY NOTES   Research Triangle Park,  North Carolina   27711
16. ABSTRACT
   This book is one  of  a series designed specifically to teach  the concepts of auto-
   mobile emissions  control systems.  It is  intended to assist  the practicing mechanic
   or the home mechanic to better understand the Air Injection  Reaction Systems  which
   are an integral part of automobiles today.   The mechanic's increased knowledge
   should help him keep "emissions controlled" vehicles operating  as designed.   Re-
   spectable fuel economy, performance and driveability, as well as cleaner air, can
   be obtained from  the automobile engine that has all of its emissions systems
   functioning properly.
 7.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                              b.lDENTIFIERS/OPEN ENDED TERMS
                                                                 c. COSATI Field/Group
Air Pollution
Air Injection
  Reaction Systems
Photochemical
Intake Manifold
Exhaust Manifold
System Inspector
             Carbon Monoxide
             Oxides of Nitrogen
             Carburetion
             Combustion
             Backfire
             Muffler
             Exhaust
 ? DfSTRfBTfiTO'N'STATEMENI

Release Unlimited
                                      19. SECURITY CLASS (ThisReport)
                                        Unclassified
                                            21. NO. OF PAGES
                                              20. SECURITY CLASS (Thispage)
                                                Unclassified
                                                                 22. PRICE
EPA Form 2220-1 (9-73)
                     fcU.S. GOVERNMENT PRINTING OFFICE: 1978 .7k 5 - 22"y

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