v . - UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON. D.C. 20460 OFFICE OF - ADMINISTRATION AND RESOURCES;^ MANAGEMENT ;-- MEMORANDUM . ,*mf j i .. - !•• . rru SUBJECTS Guidelines for the Sele.ction. of Chemical Protective Clothing..- Third Edition FRQMs David Weitzman, Acting Director Occupational Health and Safety Staff TJQ/ Users of the Chemical Protective Clothing Guidelines I am pleased to provide you with a copy of the "-Guidelines 'for the Selection of Chemical Protective Clothing" - Third iEd it ion. The Guidelines meet an important need of the Super fund program.: to^prppide up-to-date recommendations for selecting chemical - protective clothing. All chapters and appendices have been' : updated- through December 1986. ..This edition of the Guidelines contains approximately 3500 ^recommendations' covering over. 500 chemicals and 36 clothing materials. Qualitative chemical resistance information and. qualitative test data were combined to generate these recommend- ations •• This represents an increase of 52% over the second 'edition. text remains essentially the same as the second edition except. L-fibr the inclusion of -a new chapter: Chapter 5 -"Full-Body" Protection", and three related appendices. Chapter 5 provides-: a detailed discussion of design features and physical- proper tie sv of fullyjjody encapsulating ensembles and product, descriptions 'for splash., suits. The new appendices, G through I, contain djata. sheets for encapsulating ensembles, product descriptions, for splash suits, and describes the EPA's Environmental Respqnse Team's levels of protection (A through D). The Guidelines is in loose-leaf format ,to permit easy update as additional information- on chemical protective clothing becomes available. My- staff is also having this information computerized so that you can access the latest information at any time and ^n '".' searches. We expect this system to be aval'lable year. ------- The Guidelines is the most comprehensive compilati’on 6! c1 emical protective clothing performance and use information cuLrrently available. We are continuing to update the performance .ard:*use information and are considering adding new chapters for future.editions. If you have any suggestions or comments pl a se contact Cherie Zieschang at (202) 382—3650. I hope you find the updated Guidelines a useful reference. ------- Volume I: Field Guide Guidelines for the Selection of Chemical Protective Clothing 3rd Edition A.D. Schwope, Arthur D. Little, Inc. P.P. Costas, Arthur D. Little, Inc. J.O. Jackson, Los Alamos National Laboratory J. O. Stull, U.S. Coast Guard D.J. Weitzman, U.S. Environmental Protection Agency February 1987 Office of Administration Occupational Health and Safety Staff ------- DISCLAIMER Arthur D. Little, Inc., prepared this document with what it believes is the best currently available information. The document is subject to revision as additional knowledge and experience are gained. Arthur D. Little cannot guarantee the accuracy of ‘information used to develop the chemical protective clothing recommendations contained herein, and the mention of company names or products does not constitute endorse- ment by Arthur D. Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind which may be claimed to result from the use of this document. 11 ------- ACKNOWLEDGEMENTS This Guidelines for the Selection of Chemical Protective Clothing was prepared by Arthur D. Little, Inc., (Cambridge, Massachusetts), under subcontract to Los Al mos National Laboratory (New Mexico) for the U.S. Environmental Protection Agency (EPA) and the’ •U.S. Coast Guard. Particularly helpful in the preparation of this, the third edition of the Guidelines were.J.F. Stampfer and H.J. Ettinger (Los Alamos National Laboratory)’, and Krister Forsberg. Mr. ‘Forsberg of the Royal Institute of Technology (Stockholm) reviewed each, line of data presented in Appendix A of Volume II for consistency with the original literature sources. We also thank Dr. Douglas Walters of the National Toxicology Program for contributing an extensive compilation ,of glove permeation data generated for the NTP by the Radian Corporation. The text, except for the addition of Chapter 5--Full-Body Protection to Volume I,’ ‘remains essentially the same (although updated) as the first EPA and ACGIH editions for which we note the support and review comments of W. Aaroe, B.E. Benson, S.P. Berandinelli, R. Ellis, E.R. .Hoyle, K. Hunninen, R.F. Kent, W.F. Keffer, R.C. Magor, A.P. ‘Nielson, M.D. Royer, A. Smith, R.S. Stricoff, F. Thompson, R.D. Turpin. L., Walz, and R.W. Weeks. In addition, we appre’ciate the assistance of encapsulat- ing ensemble manufacturers in the preparation of Appendix C of Volume I. The authors also acknowledge the contributions of the Arthur D. Little project team which included William Hawes, whose programming skills greatly facilitated the information ‘organization task, and T. Carroll, C. Luciano, M. Rourke, and D. Ryan, who assisted us in gathering, and inputting ‘the information. Finally, we thank the typists and r port production specialists who assembled the document. 111 ------- SPECIAL NOTE TO USERS This document contains comprehensive tables of recommendations to aid and facilitate the selection’ of chemical protective clothing (CPC). The recommendations are based on an extensive ‘compilation and analysis’ of CPC vendors’ literature and experimental test data published in technical journals ‘and reports. It is imperative that users of the recommendation tables familiarize themselves with the background information that precedes and accompanies the tables. The selection of CPC must take into account the potential hazard and the conditions of use- -neither is considered in this document. , The recommendations are riot nor do they imply a guarantee of safety. Although every effort has been made to prepare this document as ac- curately as possible, errors can and do occur. Users of this document are asked to no’tify Lt. Jeffrey 0. Stull, Commandant (G-DMT-3), U.S. Coast Guard, 2100 Second Street, S.W., Washington, D.C. 20593 (202-267-0853), or Mr. David Weitzman, U.S. Environmental Protection ‘Agency Office of Occupational Health and Safety, Room 3503, Waterside Mall, 401 M Street, S.W., Washington, D.C. 20460 (202-382-3647) of errors so that theycan be corrected. iv ------- TABLE OF CONTENTS VOLUME. I Page CHAPTER 1 - OVERVIEW 1 A. INTRODUCTION 1 B. CHEMICAL PROTECTIVE CLOTHING 1 C. OBJECTIVE OF THE GUIDELINES 2 D. AUDIENCE’ AND ORGANIZATION OF 2 GUIDELINES ‘ CHAPTER 2 - CHEMICAL PROTECTIVE CLOTHING 4 LIMITATIONS A. CHEMICAL RESISTANCE ‘ 4 B. DESIGN AND CONSTRUCTION 4 C. APPLICATION 5 D. REUSE ‘ 6 E. ‘‘SUBSTITUTION OF CPC 6’ F. COST 6 CHAPTER 3 - PERMEATION THEORY’ .7 A. INTRODUCTION ‘ 7 B. PERMEATION THEORY CONCEPTS 7 C. INFLUENCING FACTORS 8 CHAPTER 4 - CLASSIFICATION OF CHEMICAL 11 PROTECTIVE CLOTHING V ------- TABLE OF CONTENTS (CONTINUED) Page 19 19 20 31 39 39 40 47 4.7 47 48 48 48 49 51 51 51 52 54 54 61 64 66. 121 CHAPTER 5 - FULL-BODY PROTECTION A. INTRODUCTION B. ENSEMBLE DESIGN AND CONSTRUCTION C. ENSEMBLE EVALUATION D. QUALITY CONTROL E. SPLASH SUITS F. ENSEMBLE SELECTION CONSIDERATIONS CHAPTER 6 - CPC USE PROCEDURES A. PURCHASE B. PRE-USE INSPECTION C. DONNING D. IN-USE E. DOFFING F. REUSE AND STORAGE CHAPTER 7 - CPC. VENDORS’ LITERATURE A. INTRODUCTION B. COMMENTS ON VENDORS’ CPC RATINGS AND RECOMMENDATIONS C. VENDORS’ TEST METHODS CHAPTER 8 - CPC RECOMMENDATIONS A. SCOPE: AND LIMITATIONS B. RECOMMENDATIONS ? c ( SERI T C ONS MATRIX A - RECOMMENDATIONS BY CHEMICAL MATRIX B: - RECOMMENDATIONS BY CHEMICAL CLASS vi ------- • TABLE OF CONTENTS (CONTINUED) Page APPENDIX A - GLOSSARY • A-i APPENDIX B - CHEMICAL INDEX B-i APPENDIX C - PRODUCT INDEX C-i APPENDIX D - VENDOR DIRECTORY • D-i APPENDIX E - PRODUCT DESCRIPTION CODE ‘ • E-i APPENDIX F - CLOTHING CLASSIFICATION CODE F-i’ .APPENDIX G - DATA SHEETS FOR ENCAPSULATING G-i • ENSEMBLES • APPENDIX H - PRODUCT DESCRIPTIONS • FOR SPLASH H-i SUITS APPENDIX I - DEFINITION OF PROTECTION LEVELS I-i ‘APPENDIX J DOFFING PROCEDURES • J-1’ vii ------- CHAPTER. 1 OVERVIEW A. INTRODUCTION Skin Ls an organ of the human body and has a surface area of about 1.8 m . A principal function of skin is to protect our internal organs from exposure to potentially harmful components of the external environ- ment. Direct contact with chemicals can pose a significant challenge to the skin; possible reactions are: • The skin will act as an effective barrier, and there will be no detrimental effect due to the contact. • The skin will suffer a primary irritation such as a burn (corrosion), chafing due to extraction of essential oils, or dermatitis. • The skin will become sensitized to the chemical. ‘Once sensi- tized, the skin will react to quantities of chemicals much smaller than otherwise would have any effect. Some chemicals are both primary irritants and sensitizers,. • The skin will be penetrated by the chemical’, and the chemical and/or its metabolites will enter the blood stream. This may or may not have a health effect, depending on the chemical and the amount of exposure. The latter type of reaction, which would include, for example, irrepara- ble liver damage and cancer, receives a high level of attention from both the lay and the technical communities. And, of course, such debilities warrant serious consideration. However, it is also important to recog- nize that primary skin irritations and sensitizations account for signif- icantly greater numbers of lost time incidents. It is estimated that skin diseases account for two-thirds of all identified job-related diseases. Furthermore, seven’ out of ten industrial claims paid by insurance companies are for temporary disability resulting from derma- titis. B. CHEMICAL PROTECTIVE CLOTHING Along with engineering controls and carefully planned work procedures, chemical protective clothing ‘(CPC) is a key element in minimizing the potential for worker exposure to chemicals. In the context of this document, CPC includes all, items of clothing primarily intended to, prevent chemical contact with the skin. These include gloves, coveralls, pants, jackets, and boots. Respirators are not included. in this classification. 1 ------- C. OBJECTIVE OF THE GUIDELINES CPC in one form or another is commercially available from hundreds of vendors in the United States. Furthermore, the clothing is fabricated from a wide variety of plastic and rubber materials. In addition, the effectiveness of a particular item of clothing is highly dependent on the chemical with which it may be challenged. For example, a neoprene glove provides excellent protection from sulfuric acid, but it is rapidly permeated by toluene. Finally, the conditions under which the clothing is used can affect performance. These factors combine to create a perplexing situation for those who are involved in or responsible for the protection of workers who handle chemicals--for example, at a hazardous waste site. In recognition of this problem, the EPA’s Occupational Health and Safety Staff developed in 1983 the Guidelines for the Selection of Chemical Protective Clothing. To this third edition of the Guidelines, the Coast Guard’s Office of Research and Development has added a chapter and three appendices pertinent to full-body protection. The objective of the Guidelines is that it be a concise, up-to-date source of information pertinent to the selection of clothing for protection from chemicals. All chapters and appendices have been updated as of December 1986. D. AUDIENCE AND ORGANIZATION OF GUIDELINES The Guidelines is principally directed towards: • field safety personnel who are more typically faced with an immediate need, to provide the best clothing for workers .oi-i a day-to-day basis, and • planners and researchers who, for example, have the respcnsi- bility for developing the safety plan for a particular project. These personnel may have the time to investigate peculiarities in clothing performance or tb prescribe clothing testing in anticipation of particular needs. In order to satisfy such diverse requirements,, the Guidelines is divided into two volumes. Volume I is intended to be useful as a “field manual.” It contains a discussion of the basic concepts of permeation and chemical resistance, an overview of CPC vendors’ literature, detailed discussion of’full-body protection, an analysis of test methods for CPC, and, proba- bly most importantly, two matrices for the selection of protective clothing. The matrices’ present clothing recommendations for 12 major clothing materials and cover approximately 500 chemicals or aqueous solutions. In addition, permeation data are provided for approximately 25 multi-component organic solutions. The appendices include an exten- sive listing of CPC sources organized by product type and principal chemical barrier material. Detailed information is provided for full- body ensembles. The appendices also include a glossary of’ CPC terms and 2 ------- instructions for selecting clothing types and doffing potentially contam- inated clothing. Volume I brings virtually all CPC performance information to one loca- tion, and provides the basic information required to select, order and intelligently use CPC. The sources are identified in the Bibliography of Volume II. Volume II is more technical in content. It contains a more detailed discussion of permeation theory, CPC testing methods and CPC vendors’ literature. The appendix to Volume II contains all the data on which are based the recommendations in the matrices ‘of Volume I. In one sense, Volume II could be considered a supporting document for Volume I. In another, Volume II serves as the starting point for further investigation of CPC. Together the two volumes represent the most comprehensive compilation of chemical protective clothing performance and use information available to the public. We urge the use of the Guidelines as an important means for maintaining the well-being of workers who may be exposed to potentially harmful chemicals. We, furthermore, urge all users of the Guidelines to participate in its continued improvement by sending comments ,and criti- cism’s to: Lt. Jeffrey 0. Stull Commandant (G-DMT-3) U.S. Coast Guard 2100 Second Street, S.W. Washington, D.C. 20593 Mr. David Weitzman U.S. Environmental Protection Agency Office of Ocèupational Health and Safety (PM-273) Room 3503 Waterside Mall 401 M Street, S.W. Washington, D.C. 20460 3 ------- CHAPTER 2 CHEMICAL PROTECTIVE CLOTHING LIMITATIONS The use of chemical protective clothing is but one component of the overall program for maintaining the health and safety of workers. It complements (and is not a substitute for) good planning, work practices, engineering and administrative controls, or personal hygiene. Several factors which. should be considered in the specification and selection of CPC are discussed in the following paragraphs. A.. CHEMICAL RESISTANCE The performance of CPC as a barrier to chemicals is determined by the materials and quality of its construction. Chemical protective clothing is based on plastic and elastomeric materials. Typically each chemical interacts with a given plastic or elastomer in a relatively unique manner. That is, each chemical/material pair has peculiar interactions. The situation becomes even more complex when multi-component solutions are involved. Four important factors to bear in mind when considering CPC are: • In general, there is no such thing as “impermeable” plastic or rubber clothing. • No one clothing material will be a barrier to all chemicals. • For a given clothing material type, chemical resistance can - . vary significantly from product to product. For example, not all brands of nitrile gloves provide equivalent protection. • For certain chemicals or combinations of chemicals, there is no commercially available glove or clothing that will provide more than. an hour’s protection following contact. In these cases, it is recommended that clothing be changed as soon as it is safely possible after any contact with the chemical or chemical mixture. B. DESIGN AND CONSTRUCTION Design and construction factors that can influence performance are as follows: . • Stitched seams of clothing may be highly penetrable by chemi- cals if not overlayed with tape or sealed with a coating. 4 ------- • Lot-to-lot variations do occur and may have a significant effect on the barrier effectiveness of the CPC. They may go undetected due to quality control procedures insensitive to chemical resistance issues. • Pinholes may exist in elastomeric or plastic products due to deficiencies or poor quality control in the formulation or in the manufacturing processes. • Thickness may vary from point to point on the clothing item. Depending on the manufacturing process, the finger crotch area of the glove is particularly susceptible to thin coverage. • Garm nt closures differ significantly from manufacturer to manufacturer and within one manufacturer’s product line. Attention should be paid to button and zipper areas and the number of fabric overlaps in these areas. Gloves are typically produced by one of two ‘principal processes- -latex- dipping and solvent (cement) dipping. Latex gloves predominate the market. Researchers have speculated, however, that the chemical resis- tance of a solvent-dipped glove may be greater than that of a latex- dipped glove of the same generic material. The principal reason being that the solvent-dipped glove is produced by a multiple-dip process while the latex process is a single-dip operation. In a multiple-dip process, imperfections in any one layer are covered by subsequent layers. Since the solvent-dip process is more involved, these products are generally more expensive. Consequently, the manufacturers of such gloves typically highlight the fact the, gloves are solvent-dipped in justifying the cost. Factors that may affect the performance of encapsulating ensembles and splash suits are discussed in Chap’ter 5. C,. APPLICATION The degree of protection provided by an item of clothing is also a function of the application. For example, a less durable piece of clothing may be more than adequate for a moderate duration, mild activity (e.g., sampling) whereas it would not endure more than 5 minutes of a vigorous, emergency response activity. Factors such as abrasion, puncture and tear resistance, and reaction to perspiration and crumpling should be considered. Temperature and, to some extent, humidity have significant influenoes on the performance of elastomeric and plastic CPC. Also with regard to application, it is important to recognize that protective clothing can be cumbersome and restrictive and thereby hasten the onset of worker fatigue. A result is that the period of safe and effective worker activity maybe reduced. 5 ------- D. REUSE Protective clothing decontamination and reuse are controversial and unresolved issues at this time. Often surface contamination can be removed by scrubbing with soap and water. In other cases, especially with highly viscous liquids, surface decontamination may be practically impossible, and the CPC should be discarded. A more subtle problem arises with regard to the detection and removal of a chemical that has been absorbed into the elastomer or plastic. Once absorbed, some of this chemical will continue to diffuse through the material towards the inside surface even after the surface has been decontaminated. For highly resistant clothing the amount of chemical reaching the inside may be insignificant. However, for moderately performing materials significant amounts of chemical may reach- the inside. This’m’ay not occur during the work shift but can take place’ while, for example, a glove is stored overnight. The next morning when the worker dons the glove, he may be putting his skin into direct contact with a hazardous chemical. In addition to chemical resistance, which is a function of temperature, both duration and, the surface area exposed affect the amount of chemical that may reach the inside surface. Reuse decisions must consider these factors as well as the toxicity of the involved chemical(s). In fact, unless extreme care is taken to ensure decontamination, the reuse of CPC which has been contacted with highly toxic chemicals is not advisable,. In summary, the decision to reuse CPC must take into account previous uses; unfortunately, there is little or no documented experience for guidance in this task. E. SUBSTITUTION OF ‘CPC Particular caution is required when substituting clothing from one manufacturer for that of another manufacturer. Clothing performance is determined by the type of plastic or elastomer, the specific formulation of that plastic or elastomer, and the clothing manufacturing process. For example, materials classified generically as nitrile rubber can differ significantly in composition and, therefore, chemical resistance. Testing is the only means for identifying the superior products for a particular application. F. COST Cost is an important consideration in the selection and utilization of clothing, especially where clothing is likely to be damaged (e.g., tear, puncture, etc.). In some cases it may be more cost-effective to adopt the practice of, using multiple changes of less expensive but relatively poorer performing clothing than to attempt to extend the use of better performing but more expensive clothing. 6 ------- CHAPTER 3 PERMEATION THEORY A. INTRODUCTION This manual addresses the problem of. selecting the most appropriate CPC for situations where human exposure to potentially hazardous chemicals is possible. An important concern in such situations is the effectiveness of the CPC as a barrier to the chemicals. Barrier properties may be estimated by simple immersion tests wherein the CPC or a portion thereof is exposed to the chemical(s) of concern, and the material examined for obvious signs of degradation, swelling, or weight changes. This has been the traditional method for generating the chemical resistance tables which are included in many CPC brochures. It is important to note, however, that permeation may occur with little or no visible or physical effect on clothing materials. The barrier effectiveness of CPC can be measured by permeation testing. The standard procedure for performing permeation tests is American Society for Testing and Materials (ASTM) Method F739-85 promulgated by ASTM Committee F-23. This same committee has developed a standard battery of chemicals for permeation testing in ASTM FlOOl-86. The 15 chemicals in the battery represent a wide range of chemicals (e.g., ketones, acids, bases, hydrocarbons, etc.) and are listed across the top of Table 5.4. Permeation testing with these chemicals will facilitate the comparison of clothing materials. An overview of permeation theory and associated concepts is presented in this chapter. For more detailed discussion, please refer to Chapter 2 of Volume II. B. PERMEATION THEORY CONCEPTS . Permeation of a liquid or vapor through a rubber or plastic material is a three-step process involving: • the sorption of the chemical at the outside surface of the CPC, • the diffusion of the chemical through the CPC material, and • the desorption of the chemical from the inside surface (i.e., towards the wearer) of the CPC. Of principal importance in selecting CPC for protection from chemicals is the rate at which chemicals permeate the clothing materials and the time elapsed between the contact with the chemical and the. appearance of the chemical on the inside of the CPC (i.e., breakthrough time). 7 ------- 1. Periueation Rate Classical permeation theory (Fick’s Law) states that the chemical permea- tion rate through a material is a function of the: • diffusion coefficient of the permeating chemical in the mate- rial (this is a property of the chemical/material pair)., • the difference in chemical concentrations between the inside and outside surfaces of the material, and • the thickness of the material. Permeation rate is often expressed in terms of the amount of a chemical • which passes through a given area of clothing per. unit time. (Common units are micrograms per square centimeter per minute.) Thus, obviously, the total amount of chemical permeating an article of clothing increases’ as the area exposed to the chemical is increased and also as the duration of exposure is lengthened. For a given chemical/material pair, the permeation rate decreases as the material thickness is increased. The concentration gradient mentioned above pertains to concentrations in the clothing material itself. Thus, there is generally a decrease in permea- tion rate as the amount of chemical absorbed by the material decizeases. This is discussed further in Paragraph C.3. below’. 2. BreakthroUgh Tune Breakthrough time is defined as the elapsed time from initial contact of the outside surface of the CPC with chemical to the first detection of chemical on the inside surface. In some cases (e.g., when handling • suspect carcinogens), breakthrough time may be the single most important criterion for CPC selection. Measured breakthrough times are readily determined by permeation testing and are dependent on the sensitivity of the analytical method used in the test and the test procedure. ‘ These factors should be considered when comparing breakthrough time data. C. INFLUENCING FACTORS 1. Temperature Most CPC permeation’data and other chemical resistance information are generated at 20°-25°C. Permeation rates increase and breakthrough times decrease with increasing temperatures. The extent of the reduction in barrier performance with increasing temperature is dependent on the chemical/material pair. • 8 ------- 2. CPC Thickness For a given chemical/clothing material pair: • Permeation is inversely proportional to thickness. Thus, doubling the thickness will theoretically halve the permeation rate. • Breakthrough time increases with thickness. However, there is no simple mathematical relationship for calculating the break- through time at one thickness from, that at another thiákness. 3. Solubility Effect Permeation rate is a direct function of the solubility of the chemical in the CPC material. Solubility is the amount of chemical that can be absorbed by a given amount of CPC material (i.e., grams liquid per gram material); absorption may be accompanied by swelling. In general, chemicals having high solubilities will rapidly permeate the CPC material in question. Thus, simple immersion testing to determine solubility is an expedient means for preliminary evaluation of candidate. CPC items. (See Volume II for further discussion of solubility and permeation.) Caution in interpreting solubility data is required, however, since low solubilities do not necessarily correspond to low permeation rates. It is important to remember that permeation rate is a function of both solubility and: diffusion coefficient. Gases, for example, have low solubilities but high diffusion coefficients and may permeate CPC materials at rates several times greater than a liquid with moderate to high solubility in the material. 4. Multi-component Liquids Multi-component liquids represent a difficult problem relative to the selection of the most appropriate CPC. Rarely is there any prior .CPC experience with the particular solution of concern, and often the compo- nents of the solution are not known. Furthermore, mixtures of chemicals can be significantly more aggressive towards plastics and rubbers than any one of the components alone. Finally, the presence of a small fraction of a rapidly permeating component may carry a chemical that would permeate at a slower rate if in pure form. At the present time, researchers are attempting to develop correlations for the prediction of multi-component permeation. Hovever, this work is in its early stages. In the meantime, immersion and permeation testing are recommended as the best means of selecting CPC for multi-component solutions. 9 ------- 5. Persistent Permeation Once a chemical has begun to diffuse into a plastic/rubber material, it will continue to diffuse even after.the chemical on the outside surface is removed. This is because a concentration gradient has been estab- lished with the material, and there is a natural tendency for the chemi- cal to move towards areas of lower concentration. This phenomenon has significant implicatIons relative to the reuse of CPC. For example, a possible field scenario is: • chemical contacts and absorbs into a glove, • breakthrough does not occur during the workday since the glove has low permeability to the chemical, • prior to removal, the glove is washed to remove surface chemi- cal, but • the next morning some fraction of the absorbed chemical has reached the inside surface of the glove due to continued diffusion. Of course, similar scenarios could occur over b.oth shorter and longer time frames, for example, morning to afternoon or over a weekend. The user must take this possibility into account when reuse is considered. Factors influencing persistent permeation were discussed in Chapter 2, Part D. 10 ------- CHAPTER 4 CLASSIFICATION OF CHEMICAL PROTECTIVE CLOTHING Personal protective clothing (PPC) is a broad category into which is placed virtually any wearable item designed to protect the well-being of a worker. Chemical protective clothing is a subcategory of PPC and is intended .to isolate the worker from contact with chemicals; it is. the subject of this manual. Items within the subcategory range from goggles to gloves to full-body encapsulating ensembles. Respirators are not considered chemical protective clothing within the context of the Guidelines. For the purposes of the Guidelines, the common items of CPC have been divided into ten types that represent specific parts of the body for which protection is designed. The objective is to facilitate the speci- fication and purchase of CPC. The classification is presented in Table 4.1 which is followed by sketches of several of the items. Appendix C. is a catalogue of presently available CPC and is organized according to CPC material, with subcategories for each clothing class. Appendix G addresses specifically full body protective clothing, and Appendix H addresses splash suits. The EPA also classifies protective clothing by the . level of protection that is required based on the severity of the hazard. The classification scheme and guidance for using it is represented as Appendix I. Other organizations may have different ways of classifying CPC based on either function, application, or level of protection. Full-body protection is discussed in more detail in Chapt r 5. 11 ------- TABLE 4.1 CLASSIFICATION OF CPC Coat, Jacket Coverall Apron Pants, Bib Overall Full-body Encapsulating Hood Shoe Cover Boot Face Shield Glove 12 ------- FACE SHIELD HOOD 13 ------- JACKET COAT 14 ------- PANTS BIB OVERALL 15 ------- APRON COVERALLS 16 ------- SPLASH SUIT 17 ------- FULL BODY ENCAPSULATING SUIT 18 ------- CHAPTER 5 FULL-BODY PROTECTION A. INTRODUCTION 1. Purpose and Scope The type of chemical protective clothing required for any given situa- tion depends on the amount, composition and toxicity of the chemical(s) involved, and the duration of exposure. In the most severe cases or in cases where the above factors are poorly defined, the highest degree of body and respiratory protection is required. The EPA has categorized such protection as Level A protection. (See Appendix I .) As defined, Level A protection includes a fully encapsulating, single-piece, chemi- cally resistant ensemble with gas-tight closures and interfaces between pants/boots and sleeves/gloves. It also includes a pressure-demand, self-contained breathing apparatus or, a pressure-demand, airline respirator (with escape bottle). Not all commercially available, fully encapsulating ensembles meet the EPA’s criteria for Level A protection. The principal point of variance is the means for air supply and respira- tory protection. (See Section 5.B.8.) In less severe situations Level B or Level C protection is, appropriate. Level B protection includes the same respiratory protection as, Level A ‘but’ two- as well as single-piece clothing is acceptable and gas-tight closures and interfaces are not required. Level C protection includes the same clothing as Level B, but an air-purifying respirator may be worn. The National Fire Protection Association (NFPA) Subcommittee on Hazard- ous Chemical Protective Clothing is developing a classification for chemical protective suits that distinguishes “vapor protective” garments from “liquid (or splash) protective” garments. Each class is further divided into “rugged” or “limited use” types of garments. The result is four different classes of full-body protection. The performance re- quirements for each class are being established and will be promulgated. as NFPA standards. Until the NFPA standard is finalized, there is no way of comparing the EPA and NFPA systems. The purpose of this chapter is to provide information that will help guide the selection and specification of full-body encapsulating ensem- bles as well as so-called “splash suits.” The chapter focuses on the design features and physical properties of both types. Test methods are also discussed. Tables and data sheets (Appendix C) are used to summa- rize the information and enable quick comparison of commercially avail- able full-body protective clothing. A summary of chemical’ resistance information pertinent to specific ensemble materials is provided in Table 5.4. For more comprehensive discussions of chemical resistance, 19 ------- please refer to other chapters of the Guidelines. Respiratory protec- tion is not addressed in the Guidelines. 2. Sources of Information The information presented in this chapter was obtained principally from the vendors of ensembles and ensemble components and from review of the literature pertinent to materials testing. In many cases the information is incomplete. ‘Information gaps may be generally accounted for by one of ‘three reasons: the test has not been performed, the information is proprietary, or the information was not known to the vendor. The latter situation is typical of cases in whtch the vendor was assembling an ensemble from components selected on the basis of overall performance rather than fundamental properties and composition. B. ENSEMBLE DESIGN AND CONSTRUCTION Individual data sheets that characterize thirty-nine commercially available fully encapsulating ensembles are presented as Appendix C. The data sheets are in a standard format to facilitate comparison of the various ensembles. In the following paragraphs, the fundamental ele- ments of the ensembles and alternative approaches to their design are discussed under the headings: - primary materials, - seams, - closures, - gloves, - boots, - - exhaust valves, - visors, - air supply systems, - communication systems, - cooling systems, and - fittings. Typically there are several designs available for each component. A summary of the advantages and disadvantages of various types is pre- sented in Section 5.F. 1. Primary Materials The primary, material is the flexible plastic or rubber film, sheet, coated fabric, or. laminate that composes the major portion of the external surface area of an encapsulating ensemble. In many cases the primary material includes a supporting fabric for increased resistance to tear and puncture. The primary materials of presently available 20 ------- encapsulating ensembles are listed alphabetically in Table 5.1, along with their respective ensemble vendors. In the table, each primary material is described from left to right in the sequence of its composi- tion from external to internal surface. For example, for a material listed as butyl/polyester/chloroprene, butyl rubber is the outside surface of the ensemble and the chloroprene is the surface facing the wearer. Between these surface materials is a polyester fabric. Nylon®, Dacron (polyester), and Nomex® fabrics are the principal sup- porting fabrics of encapsulating ensembles. The fabrics may be of woven or nonwoven type. The fabrics are either laminated to the plastic or rubber film/sheet under heat and pressure or coated with a solution of the plastic/rubber material. In addition to supplying strength, the fabric layer serves as a wear indicator. Its appearance warns of excessive abrasion and loss of thickness of the chemical barrier layer. In some cases, a wear indicator layer is incorporated into the outer plastic/rubber material. Upon abrasion, the wear layer, which is a different color, becomes visible alerting the user to take appropriate action (i.e., repair or discard the suit). As discussed in Chapter 3, the breakthrough time and permeation rate of a chemical through a primary material is strongly influenced by the material thickness. The primary materials listed in Table 5.1 range in thickness from 8 mils to 28 mils. (One mil is equivalent to 0.001 inches or 0.025 mm.) The strength and durability of a primary material is partially determined by its weight (i.e., weight per unit area). The materials listed in Table 5.1 range in weight from 2.5 oz/sq yd to 29 oz/sq yd. The supporting materials (fabrics) range in weight from about 1 oz/sq yd to 10 oz/sq yd. 2. Seams The seams discussed in this section are those formed when two pieces of the primary material are joined. Other seams, such as those around closures and fittings, are discussed later. A seam should, at a mini- mum, equal the physical strength and chemical resistance of the primary material. Basic seaming techniques and components are described here: Stitching - Stitching, typically with nylon thread, holds sections of the primary material together. In some cases the stitching is essential to the strength of the seam. Double stitching is usually used in these cases. For additional strength, the primary material is sometimes lapped (folded over) before stitching. In other cases, the stitching is not intended to provide physical strength, but rather to hold the sections in place while they are cemented or welded together. Needle holes produced by stitching are potential routes for chemical entry. The holes must be covered or sealed. 21 ------- TABLE 5.1 ENCAPSULATING SUITS - PRIMARY MATERIALS Primary Material 1 Ensemble Vendor 2 Butyl/Nylon/Butyl ‘Andover Industries Fyrepel Products Trelleborg Buty l/Polyester/Ch loroprene Mine Safety Appliances Chlorinated Polyethylene ILC Dover Chlorobutyl/Nomex®/Chlorobutyl Arrowhead Products ILC Dover Chloroprene/Nylon National Draeger Polyvinyl Chloride/Nylon Andover Industries Polyvinyl Chloride/Polyester Standard Safety Equipment Polyvinyl Chloride/Nylon/ Fyrepel Products Polyvinyl Chloride National Draeger Trelleborg Wheeler Protective Apparel Teflon®/Fiberglass/Teflon Chemical Fabrics Corporation Teflon/Nomex/Teflon Chemical Fabrics Corporation Viton/Nomex/Chlorobutyl Andover Industries Viton/Nylon/Chloroprene Mine Safety Appliances National Draeger Viton/Butyl/Nylon/Butyl Trelleborg Viton/Polyester/Viton Fyrepel Products 1 The primary materials are described with the external surface first and surface facing the wearer last. See Appendix D for the address and telephone number of each vendor. 22 ------- Strapping - Strapping is a narrow strip of plastic/rubber material that is cemented or welded over the seam. Strapping covers the needle holes of the stitching and provides additional strength to the seam. Cement - Cements (adhesives) are solutions of plastics or rubbers in a solvent. Cements are used to attach strapping or to, form the seam directly. When the solvent evaporates, the previously dis- solved plastic/rubber remains. This residue must be equal in chemical resistance to the primary material. Welding - Welding is the joining of materials on a molecular level and is contrasted with the mechanical approaches of stitching and adhesives. There are two types of welding: thermal and solvent. Thermal welding is achieved either by applying heat directly to the plastic or by passing an electric current through the material to generate heat (dielectric welding). Solvent welding is achieved by partially dissolving the surfaces of the plastic material and joining the surfaces under pressure. As the solvent dries, the molecules of the two surfaces become entangled and bonding occurs. A welded seam has the inherent chemical, resistance of the primary material since no other material composes the seam. ‘ Not all primary materials are susceptible to welding; rubbers cannot be welded. Sealant - Sealants (top coatings) are plastics/rubbers that are dissolved in a solvent. Sealants’ are used to fill the holes created by’stitching. The chemical resistance of the sealant must equal that of the primary material. 3. Closures Closures are used to seal the opening through which the ensemble is donned and doffed. There are three types of closures currently being used. The pressure sealing zipper is the most common. These zippers are designed such that the teeth of the zipper protrude only slightly through a plastic/rubber coated fabric. When the zipper is closed, the teeth lock, tightly pressing the plastic/rubber on the two sides of the zipper together forming a gas-tight seal. Current pressure sealing zippers are manufactured using either chioro- prene or polyvinyl chloride coated nylon or polyester fabric. Chioro- prene is more commonly used because of the poor aging characteristics of polyvinyl chloride. The zippers are typically equipped with nickel- silver teeth and a brass slider. Zippers can be ordered with stainless steel components for additional chemical resistance. The second type of ‘closure found on encapsulating ensembles is based on extruded sealing lips. This closure is similar in principal to the “Ziploc®” closure of plastiá bags. Sealing lips are often used in 23 ------- conjunction with a restraint zipper. The zipper provides closure strength and the sealing lips provide the gas-tight seal. The third type of closure utilizes flaps of material (along both sides of the opening) which are thermally welded together after the suit is donned. Unsealing the suit is accomplished by cutting off the welded portion of the flaps. The flaps are initially sufficiently large to permit the closure to be sealed, cut, and resealed several times. Closures may be located along one side or diagonally across the front of the garment, or along the center of the back. Frontal closures allow the user to seal or unseal his own suit. •Rear closures provide easier donning and doffing but require two people to seal the suit. Rear closures are also less susceptible to liquid splashes. The lengths of current closure designs vary. The greater the closure length, the easier the donning and doffing; however, cost increases with length. Some garments also have a protective flap which covers the closure. The flap provides protection to the closure from physical. abuse and chemical splashes. Finally, the closure is typically attached to the primary material by one of the methods described above for seaming. Again, this interface must be of equal strength and chemical resistance as that of the primary material. 4. Glove/Sleeve Interface Gloves used with Level A encapsulating ensembles must be attached to the garment in a gas-tight manner. Several physical configurations of the glove/sleeve interface are discussed here. Chemical resistance of glove materials is discussed elsewhere in the Guidelines. Gas-tight glove/sleeve assemblies are of two types: integral and detachable. An integral glove is directly and permanently attached to the garment sleeve by seaming at the interface. Some manufacturers use a rigid ring at the interface to aid this attachment. Most often the seaming technique of the primary material seams (including stitching, strapping, etc.) is used. The glove can only be removed by cutting or debonding at the interface. The glove replacement procedure is not simple, and it is sometimes required that the suit be returned to the vendor. As with all seams, the glove/sleeve interface should be as strong and as chemically resistant as the primary material. Detachable gloves are secured to the sleeve by mechanical means and can readily be replaced by the user. Alternative gloves can be used depend- ing on the situation. There are three basic types of detachable glove/ sleeve interfaces: Concentric Rings - This interface is based on two, tapered rings about two inches wide and four inches fri diameter. One ring is 24 ------- slightly smaller in diameter than the other and fits snugly into the larger one. The, larger ring is positioned at the end of and inside the garment sleeve. The smaller ring is placed inside the glove at the glove cuff The glove is then pushed down the garment sleeve from the shoulder. As, the glove passes through the sleeve opening, the smaller insert is pressed inside the larger one, and a compression seal is formed. Ring/Clamp - This interface uses a support ring i the sleeve and a clamp around the glove. The ring, about four inches in diameter and one inch wide, is placed in the garment sleeve near the cuff. The glove is then pulled over the ring on the outside of the garment. A glove clamp, similar to a hose clamp, is placed around the glove over the ring. The clamp is tightened to form the seal. Some ensembles include an additional piece of primary material at the end of the sleeve which folds over the clamp. Connect Rings - In this type of interface, rings installed by the manufacturer at the glove and the slaeve cuffs are mechanically joined. In general, the gloves should have equivalent or better chemical resis- tance than the primary material. However, this is not essential since the gloves can be replaced more readily than the ensemble. Overgloves are sometimes used with encapsulating suits to provide an additional layer of chemical permeation protection and to help minimize phyèical abuse to attached gloves. Overgloves are typically large and bulky and are not usually attached to the suit in a gas-tight manner. Some encapsulating suits provide’ “splash guards”’ to prevent entrapment of liquid chemicals between the inner arid outer gloves. A splash guard is a flap of primary material attached to the garment sleeve which can be pulled over the end of an overglove. 5. Boot/Pant Interface There are three types of boots used with encapsulating ensembles: booties, standard boots (i.e., a boot having sole, heel and closure), and overboots. Booties are integral, sock-like terminations to the garment legs. These are typically fabricated of the primary material and are attached to the garment with a seam (usually of the same con- struction as the primary material seam). Booties are designed to be worn inside standard boots. Since the booties are attached to the garment with a gas-tight seait, the standard boots worn over them do not need a gas-tight interface. Typically, encapsulating suits with bootie leg terminations have “splash guards.” A splash guard is a flap of primary material attached to the garment leg which can be pulled over the top of the boot in order to minimize the entry of liquids into the standard boot. 25 ------- Standard boots may be integral or detachable. Gas-tight boot/pant interfaces are achieved by means similar to those described above for the glove/sleeve interfaces. Overboots are designed to be worn over standard boots. Overboots are similar to booties (in that they have no firm sole or heel), but are much larger. Overboots can be made integral to the garment by seaming, in which case they are used in conjunction with standard boots which do not have a gas-tight interface. Alternatively, overboots can be of the pullover type with an elastic cuff, in which case they are used with standard boots which have gas-tight interfaces. ‘6. Exhaust Valves Encapsulating suits are usually designed such that air from the respira- tor flows into the suit creating a positive pressure in the suit. The philosophy behind this design is that a positive pressure in the suit counters inward leakage of gases and liquids through any openings or pinholes in the suit. To prevent the build-up of excessive pressures which can restrict movement and stress the suit seams, encapsulating suits are equipped with exhaust valves. These valves are one-way valves designed to open at “cracking pressures” low enough to prevent excess pressures in and “ballooning” of the suits. Cracking pressures range from less than a tenth of an inch of water to approximately 2.5 inches of water. Higher cracking pressures may restrict movement, while lower cracking pressures may allow an internal suit pressure to become negative relative to the outside atmosphere for a short period of time. Studies are on-going to determine the relation- ship between cracking pressure and suit performance. There are no current guidelines for the selection of appropriate suit exhaust valves. There are two types of exhaust valves used in encapsulating ensembles. One type, the flapper valve, consists of a rubber diaphragm or disk supported under tension in a housing such that when there- is equal pressure on both sides or less pressure on the inside of the ensemble, the valve is closed. When over pressure exists inside the suit, the diaphragm is pushed outward opening the valve. Flapper valves have a cracking pressure that is quite low, only several tenths of an inch of water, and cannot be adjusted. The second type of exhaust valve employs a spring to hold the diaphragm pressed against the housing and the valve closed. When the pressure in the suit is greater than the force of the spring, the valve opens. The advantage of this type of exhaust valve is that the cracking pressure can be closely controlled. In certain situations, such as when squatting, pressure can rapidly build inside the ensemble because of the sudden loss of free volume. This pressure must be relieved to prevent res tricting the movement of 26 ------- the wearer and to prevent overstressing the seams. The valve must have sufficient air flow capacity to allow rapid pressure relief. The design of the valve must provide a tight seal to prevent backflow or back diffusion of outside air which may be contaminated. Both spring controlled valves and .flapper valves, typically have diaphragms of natural or silicone rubber. The housings are either metal or plastic. These materials, as well as the metallic spring, are susceptible to chemical attack. The valves should routinely be inspected for material degradation and performance. . Both flapper and spring controlled valves are typically installed with covers designed to prevent direct exposure of the valve to liquid chemicals. Some valve covers are designed to seal themselves unless air is flowing out. 7. Visors Visors are either permanently attached to the suit or are removable. Replacement of a permanently attached visor usually requires returning the suit to the vendor. Removable visors employ a mechanical clamping device ‘and a rubber gasket to attach the vIsor in a gas-tight manner seal. Visors must allow clear vision with a wide field of view. The field of view should not be reduced significantly when the wearer turns his head. The materials must resist scratches and be chemically resis- tant. The thickness of the visor is another consideration; thin flexi- ble visors may be subject to damage from creasing, whereas thick rigid visors are generally heavier, but can provide better physical integrity. Visors are made from polycarbonate, acrylics, fluorinated ethylene propylene (FEP), and flexible polyvinyl chloride. All these materials have good clarity and strength. However, acrylic and polycarbonate visors are susceptible to crazing (i.e., surface cracking) upon exposure to certain chemicals. Crazing severely degrades vision clarity and can cause catastrophic failure of the visor. For these reasons, splash visors are sometimes worn over the primary visors. Splash visors are clear, flexible, disposable films of highly chemically resistant materi- als, such as FEP. They are intended to prevent liquid chemicals from coming into direct contact with the visor and thereby increase the useful life of the visor. However splash visors do not prevent visor exposure to vapors which, in certain situations, can also cause crazing. 8. Air Supply Systenis A detailed discussion of respirators is excluded from the Guidelines; however, the general respiratory protection requirements of the EPA for Levels A and B ensembles are reviewed here. EPA guidelines on Levels A and B suits specify the use of ‘a pressure- demand, supplied-air respirator approved by the Mine Safety and Health 27 ------- Administration (MSHA) and National Institute for Occupational Safety and Health (NIOSH). Supplied-air respirators are of two general types: - pressure-demand, self-contaIned breathing apparatu (SCBA), or - pressure-demand, airline respirator (with escape bottle). As discussed earlier in this chapter, not all encapsulating ensembles are of the Level A or B type. Several encapsulating ensembles are gas-tight but do not have a supplied-air respirator. The air supply for these suits is umbilically fed to an air distribution system in the ensemble, not to a respirator. In other ensembles the respirator or the self-contained breathing apparatus is not fully isolated from the external environment. The EPA designation for each of the thirty-nine commercially available encapsulating ensembles is shown in the upper right corner of the data sheets in Appendix G. Egress bottles (or escape bottles) ’ supply air to the wearer in the event that the airline is severed. Most vendors supply egress bottles as an option. In order to meet the criteria of Level A or B protection, egress bottles, are required for an ensemble that is supplied air by umbilical hose. A major consideration for selecting an air supply system is how well the garment accommodates the space requirements of the air supply system. The garment should provide sufficient space in its interior to allow a comfortable’ fit to the user wearing a breathing apparatus. Components of the air supply system should not chafe or cause internal wear of the garment. 9. Coiiuuunications Sets Voice communication when using full-body encapsulating ensemble can be achieved by three principal means: voice amplification, hard-wire systems, and wireless devices. Voice amplification systems, as the name implies, consist of a microphone attached through an amplifier to a belt mounted speaker. This system is useful when all persons are working within talking distance of one another. Hard-wired systems consist of a microphone and speaker headset which are connected by wire directly to ‘other workers or to a central, base unit and then to other workers. This system is most conveniently used when the air supply to the ensemble is by umbilical hose. Wireless systems are based on radio transmitters/receivers and allow the greatest range of operations. Whichever the system, it must be located and must operate in a manner that minimizes its impact on worker performance and safety. The total weight of the unit and the weight distribution of the unit, especially if it is worn on the head, must be considered. Also the system must not abrade the inside of the ensemble. 28 ------- Microphones may be held in place against the neck (i.e., throat micro- phones), mounted on or in the respirator face piece, suspended in front of the mouth on a boom or, in the case of bone conduction microphones, mounted somewhere on the head. Neck microphones are well accepted and function well in high noise areas; however, some users report problems due to slippage of the microphone. Readjustment is difficult when wearing an encapsulating ensemble. Three modes of operation are common: continuous, push-to-transmit, and voice-activated. Continuous systems are convenient to use and require virtually no training. However, they are continuously consuming power requiring frequent replacement of batteries. Push-to-transmit systems reduce battery consumption but require a free hand to operate. Voice- activated systems combine the advantages of both, they are low energy consumption and hand free operation. A slight drawback of voice- activated systems is that some training is required in their use since the first syllable of the first word is “lost” in activating the system. Wireless systems operate on the basic principles of radio communication. So-called simplex systems transmit and receive on the same frequency. Thus, only one person can talk at a time and a fixed interval of time must elapse before the next person can begin talking. In a duplex system, two frequencies are utilized so that there can be rapid give- and-take conversation, e.g., the telephone is a duplex system. Through the use of a base station, duplex capability can be extended to large groups of people. Half-duplex systems allow one person (e.g., the foreman) to have full duplex capability but all others to have only simplex capability. Thus, the foreman can talk to and hear all members of his group but the group members can only talk to and hear the fore- man. Obviously, each system has advantages and disadvantages in any given situation. 10. Cooling Systems In isolating the worker from the environment, fully encapsulating- ensembles can produce a significant thermal burden on the wearer. Cooling due to natural convection and evaporation is prevented. Thermal burden can be reduced by a variety of methods as follow: Passive systems such as vests containing ice, dry ice, frozen gels, or other heat sinks. These systems require equipment for pre-freezing the heat sink contents prior to use. Typi- cally such systems have a service life of one to four hours, depending on the workload and the external temperatures. There is no control over the cooling rate or cooling distribu- tion. Powered systems in which a chilled fluid is pumped in tubes in contact with the head, neck, chest and other body regions. The fluid may be air, water or some other heat transfer 29 ------- medium. Similar to the passive systems, ice, dry ice, and frozen gels are the principal heat sinks. These systems are battery powered and typically have operating periods of one to four hours. Some systems can be controlled by the wearer. - Umbilical air cooling systems which distribute air to the head, neck, and other body regions through a tubular manifold system. The air is exhausted through the pressure relief valves. Air flow rate can be controlled by the wearer. - Umbilical air cooling systems in which pressurized air enters the ensemble through an expansion valve (i.e., vortex tube). • The ensemble may contain one or more vortex tubes so that the cooling air is evenly distributed. However, the noise of the expansion restricts proximity to the head.. With this system the wearer can control the rate of cooling. . - Powered cooling systems based on swing, Stirling cycle, and conventional compressors. Fuel- and battery-powered systems are available. To date these systems have not proven practi- cal •because of their weight. However, new developments in high efficiency, high storage capacity batteries may change this situation. In addition to the above systems, cooling can alsobe achieved from the evaporation of water that is sprayed over the surface of the ensemble. As with air supply systems, the selected cooling system (if any) should not chafe the inside of the garment. 11. Fittings Certain ensemble äonfigurations include umbilical or other external air supply, cooling and communication systems. Fittings are required where the lines for these systems enter the ensemble, usually through the primary material. The fittings should have standard threads or quick disconnects for attaching the lines. These fittings and the means with which they are attached to the ensemble must be selected with full consideration to chemical resistance. Furthermore their attachment to the ensemble must be sufficiently strong to prevent their being pulled out. 12. Disposable Suits Disposable encapsulating suits are designed for limited use. Their low cost allows the user to discard the suit rather than decontaminate it after use. These suits are typically large and loose fitting and do not necessarily have gas-tight interfaces for glove and boot attachment and pressure sealing zippers. Because of their low cost, disposable suits are often used over standard encapsulating suits. This arrangement 30 ------- provides the user with the full, gas-tight protection offered by the standard suits and protects the (more expensive) standard suit from gross contamination. Disposable encapsulating suits are fabricated using polyethylene-coated or Saranex®-laminated Tyvek®, or polyvinyl chloride film. C. ENSEMBLE EVALUATION 1. Introduction •The performance of an encapsulating ensemble depends on its chemical resistance, physical properties, fit, design features, ‘and. sizing. Chemical resistance is discussed elsewhere in the Guidelines. The physical characteristics of encapsulating ensembles are for the most part determined on the component level and are described below. Methods for testing the overall ensemble are described in Section 5.C.4. Limited information is. also provided for sizing and fit considerations. 2. Physical Properties Standard tests exist for measuring many of the physical properties of ensemble materials and in many cases these tests are specific to an ensemble component. More than one test method exists for measuring some physical properties. Selected standard tests are listed in Tables 5.2 and 5.3. ASTM standard test methods were selected because they are readily available, regularly updated to reflect changes in the state of the art, and actively supported by. an identifiable group of persons that are available for consultation. The importance of material physical properties is often underestimated. Physical properties provide a means for estimating and comparing the strength and durability of various ensemble components. Information on certain of these properties is considered essential to the evaluation of ensembles. These key properties are identified in Tables 5.2 and 5;3 and discussed further in Section 5.C.3. Although no vendor provides data .on all of the properties, it is useful for. the user to be familiar with the terms: . Abrasion Resistance - The amount .of material removed from a surface during relative motion against another surface. . Antifog - Measurement of the effect of water vapor condensation on the read-through characteristics of clear materials. Blocking - The adherence of materials to one another or themselves. 31 ------- TABLE 5.2 PHYSICAL PROPERTY TEST METHODS (Not Including Visors) Property Test Method Abrasion Resistance 1 ASTM D3389 Blocking ASTM D1893 Brittleness ASTM D2137 Bursting Strength ASTM 03786 Coating Adhesion ASTM D751 Cut Resistance 1 ASTM F23.20.01 2 Durometer ASTM D2240 Flammability 1 ASTM D568 Flex Fatigue 1 ASTM D671 (Plastics) ASTM D430 (Elastomers) Hydrostatic Resistance ASTM D751 Low Temperature Bending ASTM D2136’ Ozone Resistance ASTM D304l Penetration Resistance ASTM F903 Pressure (Inflation) Testing ASTM F23.50.01 2 Puncture Propagation Tear ASTM D2582 Puncture Resistance 1 ASTM F23.20.02 2 Qualitative Leak Testing ASTM F23.50.02 2 Seam Strength 1 ‘ASTM D75l Stiffness 1 ASTM Dl043 (Plastics) ASTM Dl053 (Elastomers) Tear Strength 1 ASTM D751 Tensile Strength 1 ASTM D751 (Supported Materials) ASTMD4l2 (Unsupported Materials) Thickness ASTM D751 UV Light Resistance ASTM G26. Weight ASTM D751 Zipper Strength 1 . ASTM 2061 Key physical property . See Section 5.C.3. Test method is currently being developed. 32 ------- TABLE 5.3 VISOR PHYSICAL PROPERTY TEST METHODS Property Test Method Abrasion Resistance ASTM D1O44 Antifog MIL-A-1542B Distortion 1 ASTM D881 Impact Strength 1 ASTM D3029 Light Transmission and Haze 1 ASTM D1003 Scratch Resistance ASTM F548 Stiffness’ ASTM D1O43 (Plastics) ASTM D1053 (Elastomers) Tear Resistance ASTM D1004 Tensile Strength ASTM D638 Thickness ASTM D638 TJV Light Resistance ASTM G26 1 Key property. See Section 5.C.3. 33 ------- Brittleness - Evaluation of the lowest temperature at which flexi- ble materials will not exhibit fractures or cracks when subjected to specified impact conditions. Bursting Strength - The multidirectional force required to break a material. Coating Adhesion - The force required to peel a coating from a substrate. Compression Set - The residual deformation of a material when subjected to a compressive force then released. Corrosion Resistance - The amount of mass or thickness loss from materials upon exposure to chemical environments. Cut Resistance - The force required to cause a sharp-edged blade to cut the surface of a material. Distortion - The deviation of the line of sight through flat or curved sections of transparent materials. Durometer - The degree to which materials res.ist indentation bya specified probe under a specified load. Flammability - The ignition, propagation, and self-extinguishing characteristics of a material. Flex Fatigue - The number of repeated bends required to cause cracking in a flexible material. Hydrostatic Resistance - The force. required to cause the penetra- tion of water through a coated fabric. Impact Resistance - The force required to cause materials to exhibit fractures or cracks when subjected to impact. Light Transmission and Haze - The light-scattering properties of transparent materials. Low Temperature Bending - The degree of cracking that occurs at a specified temperature in a flexible material when the material is bent around a cylindrical rod. Ozone Resistance - The degradation effects on a material as the result of ozone exposure. Penetration - The flow of a liquid on a non-molecular level through closures, porous materials, seams, pinholes or imperfections in a protective clothing material. 34 ------- Puncture Propagation Tear - The force required for a sharp object to snag and subsequently tear a material. Puncture Resistance - The force required to penetrateS a material with a cylindrical probe in a direction normal to the surface of the material. Scratch Resistance - •The degree to which clear materials are scratched or marred as a result of motion against another surface. Seam Strength - The force required in tension to break a seam with the force applied perpendicular to the direction of the seam. This type of testing is similar to tensile testing of the primary material. Static - The resistance to an accumulation of electrical charge. Stiffness - The force required to twist or bend a material a specified amount or the amount of bending occurring as a result of a specific applied force. Tear Strength - The force required to initiate or propagate a nick or cut in a direction normal to the direction of the applied force. Tear strength results are usually reported for both the warp and fill (woof) directions of coated fabrics. Warp refers to threads in a fabric running in the lengthwise direction (machine direc- tion), and fill to the fibers in the crosswise direction (cross machine direction). Tensile Strength - The force in tension required to break a materi- al. Tensile strength results are usually reported for both the warp and fill directions of coated fabrics. IJV Light Resistance - The degradation effects on a material as the result of exposure to UV light. Weight - There are two kinds of weight associated with encapsulat- ing ensembles: the material weight and the ensemble weight. Material weight is the weight per unit area (e.g., oz/sq yd) of the primary material. The ensemble weight is the total weight of the fabricated garment. In some cases, the ensemble weight reported by vendors includes only the garment and detachable gloves and boots, while in other cases ensemble weight includes breathing apparatus and cooling. The ensemble weight reported on the data sheets in Appendix C includes only garment, gloves, and boots and not cooling and breathing apparatus. Zipper Strength - The force required to pull a zipper apart in a direction perpendicular to the zipper direction. This is also 35 ------- known as zipper crosswise strength and can be applied to other types of garment closures. 3. Key Physical Properties ASTM Committee F-23 and the NFPA are developing standards. which describe a minimum battery of physical property tests to be preformed on an encapsulating ensemble. These tests will complement chemical resistance testing such as for permeation, degradation, and penetration resistance. The battery of physical tests will also standardize the methods used for measuring each physical property so that results can be compared from one product to another. Until the ASTM and NFPA standards are final- ized, the tests marked with an asterisk in Tables .5.2 and 5.3 should be considered essential to the evaluation of the components of a fully encapsulating ensemble. 4. Chemical Resistance Other chapters of the Guidelines address the issue of chemical resis- tance from the perspective of generic clothing materials categories. For example, all butyl rubber materials regardless of thickness, source, and formulation have been classified together in order to form the chemical resistance recommendations, in Matrix A. Generic classifica- tions provide general guidance as to chemical resistance but,’ as noted elsewhere, ,chemical. resistance can vary significantly within a generic class. In Table 5.4, ensemble-specific chemical resistance information, for the fifteen chemicals composing the standard battery of test chemi- cals in ASTM FlOOl-86, is presented. Breakthrough time and permeation rate data are presented when available. In some other cases, qualita- tive ratings of chemical resistance are listed as supplied by the ensemble vendor. The qualitative ratings should be used with extreme caution because, in several instances, it would appear that they. are generic rather than specific to the clothing material. 5. Complete Ensemble Testing Only a few methods exist for evaluating the complete ensemble. These methods can be classified in the categories of garment,pressure (infla- tion) testing, leak testing, and manned ensemble functionality testing. A variety of methods exists tor each category and the quantitativeness of the results varies with the method. Draft ASTM standards have been proposed for both garment pressure testing and qualitative leak testing. These tests are described below. Pressure testing measures the integrity of the suit and visor material, suit seams, and suit closures for gas tightness. The test involves the inflation of the garment to a specified pressure and either measuring a pressure drop over time or applying a soap solution to the outside of the garment to detect leaks (by the appearance of bubbles). The suit exhaust valves must be closed to perform the test and a provision must 36 ------- Material Vendor Thickness (mils) - . 2 2 8 ’ , —5 . , z . - •C ’ 0 2 ‘& . 0 ) 2 C 2 2 0 ) C 0 ‘ 2 ’ o. . 0— ., I > . - ô. 2 0 B ‘0 .2 ‘.E .C ’ 0 Eo ã 4 . 0 2 ‘00 i • . 8 8 ’ CO 0)0) 0 z @1 0 . 0 E .2°• • •2 -os (O o ° —S U c - 4. • ‘ 0 o ‘0— C ‘0’ .2 o’ •C U.C ‘ 0 I.- C E . ‘ ‘ ‘ ‘ • C — C 0 e 2 > . 0 I U ‘ O C Butyl/Nylon/Butyl ‘ Andover 2 Fyrepel 4 Trelleborg 3 14-15 14 15-18 A A U U X U X B B B B B U •X A A - U C A A B X ‘ U X B B U X Butyl/Polyester/ChloroPrefle ’ MSA 19 8 ( ‘ 8 ( ) 8 ( ) 0.2 Chlorinated Polyethylene lLC 14 20 0.25 (1020) 1.3 ( ) 0.1 ( ) 0.3 ( ) B’ C 1 C ) >3 ( >3) ) 1 I ) >3 C ) >3 C ) C 0.5 ( ) 1.2 C ) Chlorobutyl/Nome;cfChlOrObUtYl Arrowhead 19 . ‘ ILC 20 ‘ Chloroprene/Nylon Draeger ND 5 . ‘ PVC/Nylon Andover 15 PVC/Polyester PVC/Nylon/PVC Standard Safety Fyrepel 14 1 Draeger Trelleborg 13 Wheeler 28-30 ND ND 18 20 X 3 3 X 3 X 3 B ‘ 3 X ‘ ‘ ; ‘ 3 B 2 A 3 X 3 ‘ B 1 A 4 X 3 X 4 X 3 Teflon/Fibeu’ylass/TeflOn ChernFab 10 Teflon/Nomex/TeflOn ChemFab 18 >8 ( ) >8 ( ) 0.3 (0.05 0.8 (0.02) >8 C I >8) ) >8 ( ) >8 ( C >8 ( I >8 ( ) >8 ( ) >8 ) ) >8 I C >8 ( ) ‘ U’ >8 Viton/Nomex/Chlorobutyl Andoser 2 20 U U A B U U U A C B B A A A Viton/Butyl/Nylon/Butyl Trelleborg 3 ND ‘ 3 3 1 2 3 ‘ 3 2 2 2 , 2 2 2 3 2 Viton/Nylor s/Ch loroprene MSA Draeger , 23 Np 0.7 ( ) ‘ ‘ ‘ 8 ( C 8 ( I ‘ 0.1) Viton/Polyester/Viton Fyrepel 4 8 X A ‘B X X X A C B. B A A X A TABLE 5.4 PRODUCT-SPECIFIC CHEMICAL RESISTANCE IN FORMATION FOR FULL BODY ENCAPSULATING ENSEMBLES L ) - 5 5 (1) Number piecedirig parentheses is breakthrough time in hours; number in parentheses is permeation rate in pg/cm 2 /min. II no parenthese follows number, see footnote (3). (2) A =recoinmerded; B minor effect;C = moderate effect; U not recommended (3) 1 not effected; 2 slightly effected; 3. 4. 5 material can be destroyed (4) A recommended; B minor-to-moderate effect; C moderate to severe; X not recommended (5) No data ‘ ------- be made.for attaching a pressure gauge. Some manufacturers specify the pressure to which the suit should be inflated. The proposed ASTM method specifies a maximum inflation pressure (3 inches water gau ge pressure), a test pressure (2 inches water), and an allowable pressure drop (20%) over a three-minute peripd. It also requires using the soap solution to locate leaks if the suitdoes not meet the pass/fail criteria. Leak testing measures the integrity of the entire ensemble to a gas challenge agent in a manner simulating actual use. This testing involves exposing a test subject wearing the ensemble in a closed chamber to a challenge agent and measuring the agent concentration both inside and outside the suit. The proposed ASTM method employs ammonia gas at a concentration of 1000 to 2000 ppm and length of stain detection tubes. Other methods may use different gases or aerosols (at non-toxic concentrations) and appropriate detection methods. Dependent on the means used to measure the presence of gas, the test can be qualitative, semi-quantitative or quantitative. When concentration measurements are precise, the results can be used in a semi-quantitative manner by ratioing the external to internal gas challenge agent concentrations for calculating a . rotection factor. Large protection factors are indica- tive of high ensemble integrity. Manned ensemble testing is often performed to determine the range of activities that a user can do while wearing the ensemble. These’may include different types of exercises or tasks which simulate the end application of the suit. Results from these tests are generally subjec- tive regarding the design, comfort, and fit of the garment. Measurement of the wearers physiological condition (e.g., core temperature, skin temperature, heart rate, and blood pressure) during this testing can help quantify the results when compared to tests with the subject not wearing the ensemble. 6. Ensemble Sizing and Fit Manufacturers may offer one size or several sizes of their respective garments. (See Appendix C.) There are no standards for sizing these garments; consequently, one manufacturer’s “large” may not fit the same group of people as another manufacturer’s “large.” Generally, the more sizes offered by a manufacturer, the greater the range of people who will comfortably (and functionally) be fit by a given garment design. The only way to gauge the fit of a garment is to actually try on each of the available sizes offered by the manufacturer. 38 ------- D. QUALITY CONTROL There is no industry standard test series by which the quality of fully encapsulating ensembles is controlled. The level of manufacturer quality assurance ranges from simple visual inspections to a large battery of tests on the ensemble and its components. Some manufacturers perform lot-by-lot tests to verify chemical resistance and physical properties of the primary materials. All the vendors listed in Table 5.1 subject completed ensembles to pressure (inflation) testing; as previously described. While closure, interface or seam imperfections are thereby located and corrected prior to shipping, this does not test exhaust values. None of the vendors provided any insight into minimum’physical property values or performance levels acceptable for any of the individual components of an encapsulating ensemble. Indeed, while limits would be most useful in evaluating suit components, it would be difficult to set such limits since they are highly dependent on the application condi- tions. Both the ASTM F-23 Committee and the NFPA Subcommittee on Hazardous Chemical Protective Clothing are developing standards which would increase the information provided by manufacturers on the performance of these garments. The proposed ASTM standard would specify documentation requirements for chemical protective suits and suit components. The NFPA is writing performance standards for each type of chemical protec- tive suit in its proposed suit classification system. E. SPLASH SUITS Level B (and Level C) protective clo..hing, as defined by the EPA, is used in situations where the atmospheric concentration of toxic sub- stances requires a high level of respirator protection, but less skin •protection than Level A. (See Appendix I for further explanation.) The garment should cover most of the body, but is not completely sealed. This type of clothing is commonly referred to as a “splash suit.” Several of the major manufacturers of splash suits and their products are listed in Appendix H. The styles and primary materials ar’ given along with the major construction features. In many cases, chemical splash suits are almost identical to commercial rain gear. Splash suit components include jacket, pants (usually overalls), coveralls, and hood. Splash suits minimize exposure to liquids. However, the closures and interfaces are not gas- or liquid- tight. The primary material in splash suits is typically a fabric-supported plastic or rubber film/sheet. The most commonly used plastic is poly- vinyl chloride. Other polymers used include: polyethylene, 39 ------- chloroprene, styrene/butadiene rubber, polyurethane, a blend of nitrile rubber and polyvinyl chloride, and butyl rubber. The seams of the primary’material are usually stitched and cemented or welded. The closures on splash suit’s need not be liquid proof. ‘ fhey typically are either simple zippers or snaps. The snaps can be metal or plastic. Closures often have a ‘storm fly front, which is an extra flap of materi- al in front of the closure’ to prevent direct li’quid.contact with the closure. Other construction features of splash suits include batwing sleeves (extra material under the arm for a greater degree of movement) and take-up snaps on the sleeves and pant cuffs (to reduce but not seal arm and leg openings). Splash suits do not include integral gloves, boots, or air supply systems; these are separate components. Disposable splash suits are fabricated using polyethylene-coated or Saranex®-laminated Tyvek® as ‘the primary materiaL Jackets, pants, coveralls, and hoods, are available as disposables. F. ENSEMBLE SELECTION CONSIDERATIONS The selection of fully encapsulating ensembles and splash suits depends on: - the,nature and severity of the hazard, - the type and duration of the tasks to be performed, - the performance features and limitations of the available clothing, and - cost. The information provided in Appendix I provides considerable guidance to assist in matching the level of protection to the hazard. The selection of an ensemble for a specific application typically involves trade-offs among physical and chemical properties, design features, and human factors considerations. There are no current ensembles which provide both flame and chemical protection. Nearly all CPC materials will ignite and burn when con- tacted by flame. These ensembles should not be used for situations where the probability of contact with flame or flashover conditions is high. Combined thermal and chemical protective suit systems should be considered carefully. Thermal protection may be worn either inside or outside the chemical protective suits. When externally worn, thermal protective clothing is subject to contamination and must be disposed of after use. When worn inside (e.g., aramid fiber jumpsuit), the integ- rity of the chemical protective’ clothing will be lost in a flame situa- tion, resulting in a potentially life-threatening situation. Alterna- tively, thermal protection can be worn both inside and outside the suit. 40 ------- In any of these cases, the additional burden (weight/heat stress) to the wearer must be considered. In Table 5.5 are listed the advantages and disadvantages of many of alternatives discussed earlier. Chemical resistance issues are not included in the table as they are discussed elsewhere in the Guidelines. Neither is cost addressed. Ensemble design and component alternatives are characterized in a qualitative manner since there are no generally accepted quantitative criteria by which they can be assessed. The state of the art is not sufficiently advanced for setting minimum physical property or performance values for ensemble materials and components. However, the NFPA Subcommittee on Hazardous ChemIcal Protective Clothing is engaged in several studies to define performance levels for chemical protective suits used in emergency response. 41 ------- TABLE 5.5 ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS COMPONENT ADVANTAGES DISADVANTAGES COMMENTS PRIMARY MATERIAL COMPOSITION WIDE VARIETY AVAILABLE CHEMICAL RESISTANCE VARIES FROM MATERIAL TO MATERIAL AND FROM VENDOR TO VENDOR. FLAME RESISTANCE SHOULD BE CONSIDERED SUPPORTING FABRIC ADDS STRENGTH INCREASES WEIGHT REDUCES FLEXIBILITY EDGES MUST BE SEALED WEAR INDICATOR INDICATES REDUCED PROTECTION PREFERRED THICKNESS! INCREASES STRENGTH INCREASES WEIGHT WEIGHT INCREASES PROTECTION REDUCES FLEXIBILITY SEAMS WELDED CHEMICAL RESISTANCE EQUIVALENT TO RUBBER MATERIALS CANNOT BE WELDED THAT OF PRIMARY MATERIAL LESS BULKY LESS SUSCEPTIBLE TO SNAGGING STITCHED APPLICABLE TO ALL MATERIALS REQUIRES STRAPPING OR SEALANTS LAPPED AND DOUBLE-STITCHED CONSTRUCTIONS MUST BE TESTED FOR CHEMICAL RESISTANCE PREFERRED PENETRATION THROUGH PINHOLES ------- TABLE 5.5 (CONTINUED) ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS COMPONENT ADVANTAGES DISADVANTAGES COMMENTS CLOSURES PRESSURE SEALING SIMPLE AVAILABLE MATERIALS HAVE LIMITED STAINLESS STEEL TEETH AND SLIDER AVAILABLE ZIPPER CHEMICAL RESISTANCE FLAP MAY BE ADDED TO PROTECT ZIPPER SEALING LIP PROTECTS ZIPPER FROM ENVIRONMENT TWO-STEP PROCESS: ZIPPER AND SEAL ZIPPER REQUIRES DEXTERITY SOME SEALING LIP MATERIALS MAY BECOME STIFF/UNOPERABLE IN COLD WEATHER WELDED CHEMICAL RESISTANCE EQUIVALENT TO HEAT SEALING EQUIPMENT REQUIRED THAT OF PRIMARY MATERIAL DON/DOFF REQUIRES HELPER LIMITS NUMBER OF REUSES FRONT MAY BE USER OPERATED, IF ZIPPER MORE DIFFICULT TO DON AND DOFF SUIT EMERGENCY DOFFING, IF ZIPPER MORE SUSCEPTIBLE TO CHEMICAL EXPOSURE BACK LESS SUSCEPTIBLE TO CHEMICAL EXPOSURE TWO-MAN OPERATION EASIER TO DON/DOFF SUIT GLOVE/SLEEVE & BOOT/PANT INTERFACE OVERGLOVES/BOOTS INCREASE PROTECTION AND SERVICE LIFE BUT REDUCE MOBILITY, TACTILITY AND DEXTERITY INTEGRAL FACTORY SEALED AND TESTED DIFFICULT TO REPLACE, MAY REQUIRE. • RETURN TO FACTORY NOT INTERCHANGEABLE FOR FIT OR CHEMICAL RESISTANCE ------- TABLE 5.5 (CONTINUED) ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS COMPONENT ADVANTAGES DISADVANTAGES COMMENTS DETACHABLE EASY TO REPLACE SEAL IS MADE IN FIELD AND IS CAN BE OPTIMIZED FOR FIT AND NOT READILY TESTED CHEMICAL RESISTANCE • -CONCENTRIC RINGS NO MECHANICAL PARTS RELIES ON COMPRESSION SEAL; NO CLAMP OR LOCK DIFFICULT TO INSPECT --RING/CLAMP SIMPLE MAY REQUIRE TWO PERSONS EASILY INSPECTED CORROSION OF CLAMP MECHANICAL SEAL - -CONNECT RINGS EASE OF USE COMPLEXITY MECHANICAL SEAL REPAIR MAY REQUIRE RETURN TO FACTORY EXHAUST VALVES VALVES SHOULD BE COVERED TO PREVENT DIRECT EXPOSURE TO LIQUIDS. COVERS SHOULD BE OF A DESIGN WHICH MINIMIZES BACK DIFFUSION FLAPPER SIMPLE CANNOT ADJUST CRACKING PRESSURE CHEMICAL RESISTANCE OF DIAPHRAGM SPRING-OPERATED CAN ADJUST CRACKING PRESSURE CORROSION RESISTANCE OF SPRING CHEMICAL RESISTANCE OF DIAPHRAGM ------- TABLE 5.5 (CONTINUED) ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS COMPONENT ADVANTAGES DISADVANTAGES COMMENTS VISORS SPLASH VISORS INCREASE PROTECTION AND VISOR SERVICE LIFE. SPLASH VISORS MAY RESTRICT HEAD ROTATION AND INTERFERE WITH VISION INTEGRAL FACTORY SEALED AND TESTED REPLACEMENT REQUIRES RETURN TO FACTORY DETACHABLE VISORS EASILY REPLACED SEALING IS USER DEPENDENT CHEMICAL RESISTANCE OF GASKET FLEXIBLE LIGHTWEIGHT MAY CREASE RESULTING IN DECREASE IN CHEMICAL RESISTANCE U ’ RIGID STURDY, DURABLE HEAVY, MAY SHATTER (IF GLASS) AIR SUPPLY SYSTEMS SCBA WIDE RANGE OF OPERATION DURATION OF ACTIVITY LIMITED BY AIR SUPPLY ENSEMBLE MUST BE DESIGNED TO ACCOMODATE SCBA WEIGHT AIRLINE LONG WORK PERIODS LIMITS RANGE OF OPERATIONS CHEMICAL RESISTANCE OF AIRLINE SHOULD COOLING AIR CAN ALSO BE SUPPLIED BE CONSIDERED ------- TABLE 5.5 (CONTINUED) ADVANTAGES AND DISADVANTAGES OF ALTERNATIVE ENSEMBLE COMPONENTS COMPONENT ADVANTAGES DISADVANTAGES COMMENTS COMMUNICATION SETS VOICE COMMUNICATION IS ESSENTIAL FOR SAFE, EFFICIENT WORK VOICE-AMPLICATION INEXPENSIVE FUNCTIONAL OVER SHORT DISTANCES HARD-WIRED SYSTEM EXTENDS RANGE OF OPERATION REQUIRES ALL PERSONS BE CONNECTED BY WIRE WIRELESS VOICE/HEARING QUALITY HIGH BATTERY LIFE LIMITS OPERATION PERIOD USER MUST DECIDE AMONG CONTINUOUSLY ON, ALLOWS WIDE RANGE OF OPERATION SOME TRAINING REQUIRED PUSH TO ACTIVATE, OR VOICE ACTIVIATION. ALSO, AMONG SIMPLEX, DUPLEX OR HALF-DUPLEX COOLING SYSTEMS ALLOWS EXTENDED WORK PERIODS ADDED WEIGHT/BULK REDUCES LIKELIHOOD OF HEAT STRESS UMBILICAL SYSTEMS RESTRICT RANGE OF OPERATION PASSIVE SYSTEMS ALLOW NO CONTROL OF COOLING RATE ------- CHAPTER 6 CPC USE PROCEDURES A. PURCHASE Protective clothing is purchased either directly from the manufacturer or through a CPC distributor. Listings of these organizations may be found in, for example, the Thomas Register or Best’s Safety Directory. A fairly extensive listing is provided as Appendices C and D. The larger distributors carry several manufacturers’ products and a wide variety of products. Virtually every manufacturer has a catalogue of its products which describes each product as to the sizes available, thickness of the rubber or plastic barrier, and the materials of construction. For convenience, detailed summaries of this information for full-body ensem- bles is provided as Appendices C and H. Many of the catalogues also contain chemical resistance ratings charts for the products. The reliability of the ratings varies from vendor to vendor. Some ratings are based on extensive testing, while others would appear to have minimal supporting evidence. Further comments on CPC vendors’ literature are presented in Chapter 7. In making CPC purchase decisions, important considerations are: • the application to which the clothing will be put, • the recommendations presented in Chapter 8, • past experience with the particular item of clothing, and • cost and availability. B. PRE-USE INSPECTION Each item of clothing should be inspected immediately upon removing it from the package. First determine that the material of construction is that which was ordered or specified for the task at hand. This will involve comparing the item number with the catalogue number. Items of different materials should be kept separated. (See Storage below.) Visually inspect the items for defects such as imperfect seams, non- uniform coatings, pinholes, malfunctioning closures, and tears. Some flexible niaterials.may stiffen during extended storage periods; flex the product and observe for surface cracks or other signs of shelf life deterioration. Pinholes may be detectable by holding the garment up to a light in a dark room. Cloves with holes can be identified by pressuriz- ing the glove. This can be accomplished by blowing into the glove and 47 ------- then tightly rolling the gauntlet towards the fingers (thereby reducing volume and increasing pressure) while observing that the glove holds pressure. Alternatively, the glove could be inflated and then held under water and examined for the presence of air bubbles. Full-body encapsu- lating ensembles should be checked for the operation of pressure relief valves and the fittings at the wrists, ankles, and neck. Standard methods for, leak testing full-body ensembles are discussed in Chap- ter 5.C.5. C. DONNING Each worker should thoroughly inspect the clothing he is to wear inunedi- ately before donning. Of principal concern are cuts, tears, punctures’, and discoloration or stiffness which may be indicative of chemical attack resultant from previous use or non-uniformities in the rubber or plastic. The ‘wearer should understand all aspects of the clothing operation and its limitations; this is especially important for full-body encapsulating ensembles where misuse could potentially result in suffocation. Note, ‘some materials may have temperature limitations; for example, some CPC become stiff and may be unusable at low temperatures. Once the clothing is on, all closures should be secured and checked. Use the “buddy system.” Finally, the fit of the clothing should beevalu- ated., Improperly fitting protective clothing represents a severe poten- tial hazard. Where clothing is too small, worker movement is,restricted, likelihood, for tear is increased, and the potential for’ accelerated worker fatigue. is increased. Where the clothing is too large, the possibility of snag is increased, and the dexterity and coordination of the worker may be compromised. D. IN-USE During the course of the work task, each worker should periodically inspect his protective clothing. Of principal concern ‘are tears, punc- tures, seam discontinuities, or closure failure that may have developed while’ working. Evidence of chemical attack such as discoloration, swelling, stiffening, or softening should also be noted., (Note: Perniea-. tion can occur without any visible effects on the clothing material.) Any item of clothing that has been physically damaged or chemically degraded should be doffed and replaced as soon as safely possible. E.. DOFFING A principal objective of the doffing process is to restrict the transfer of chemical from the work area. A second objective is to avoid contact of the person doffing the garment as well as others with chemical on the outside of the garment. 48 ------- Detailed doffing procedures have been developed by the EPA and are contained in the Interim Standard Operating Safety Procedures of the Office of Emergency and Remedial Response, Hazardous Response Suppoi t Division. Part 7 and pertinent Annexes of the Interim Standard are included herein as Appendix J. They address: • doffing site location, • decontamination, and • disposal of contaminated garments. F. REUSE AND STORAGE Several considerations relative to the storage and reuse of protective clothing were discussed in Chapter 2. They primarily focus on hazards that could potentially develop upon the storage of contaminated clothing. Briefly, in cases where a chemical is absorbed by the clothing, the chemical begins to permeate into the clothing. Short duration washing of the clothing with• soap and water removes surface contamination but not absorbed chemical. After surface decontamination, some of the absorbed chemical will continue to permeate the clothing material and may ulti- mately appear on the inside surface. This can happen during periods of overnight or weekend storage. Where such potential hazards may develop, clothing can be checked inside and out for discoloration or, if possible, by wipe testing for suspect chemicals prior to reuse. This is particu- larly important for full-body encapsulating ensembles which are generally subject to extensive reuse due to their cost. Note, however, that negative (i.e., no chemical found) test results do not necessarily preclude the possibility that some absorbed chemical will be released to the inside of the CPC during reuse. It should be noted that, at the present time, there is very little docu- mentation regarding clothing reuse. The use of disposable clothing, of course, obviates the problem. Where reusable CPC is required, however, the type of problem discussed above can best be minimized by selecting the most resistant clothing for the chemical at hand; such clothing will absorb little or no chemical. Furthermore, used clothing should be stored in well-ventilated areas. Ideally, there should be good air flow around each item of clothing. Reuse of face shields and lens is a particularly important issue. Good vision is required for both safety and efficiency on the work site. All such items should be inspected for crazing, cracks, and fogginess prior to use. See Chapter 3, Part D, in Volume II. 49 ------- Finally, in storing protective clothing, different types of materials of clothing should not be mixed. For example, glàves which are black in color and virtually indistinguishable from one another may be made from nitrile, neoprene, Viton, polyvinyl chloride, butyl, etc., materials.• Each material has unique chemical barrier properties. Mixing the gloves significantly’ increases the chance that a worker will be wearing the wrong clothing for the chemical of concern. It may be possible to separate mixed gloves by using the manufacturer’s product’number that is often found in the gauntlet area. ‘ 50 ------- CHAPTER 7 CPC VENDORS’ LITERATURE A. INTRODUCTION The most widely available sources of information on CPC are the product catalogues of the CPC manufacturers and vendors. These booklets contain descriptions of the types, sizes, and varieties of CPC produced by each manufacturer. In most cases the basic materials of construction of the CPC are also included in the product descriptions. Many manufacturers also include information pertinent to the chemical resistance of their products or of the materials from which the products are fabricated. This information is often in the form of tables of qualitative chemical resistance ratings or use recommendations for the products/materials and particular chemicals. However, the leading manufacturers are increas- ingly providing information from permeation testing. A few vendors also provide information pertinent to abrasion, tear, etc., resistance but in general most catalogues do not address such application-related issues. Since the focus of these Guidelines is the selection of clothing for protection from exposure to chemicals, the vendors’ chemical ratings and recommendations tables are the focus in this chapter; they are discussed in more detail in Chapter 4 of Volume II. B. COMMENTS ON VENDORS’ CPC RATINGS AND RECOMMENDATIONS Of the 150 CPC èatalogues which were obtained and reviewed in the prepa- ration of the Guidelines, 26 contained some form of chemical resistance information for the products described therein. The information was both qualitative and quantitative. The qualitative ratings/recommendations typically were on a four-grade scale of “excellent,” “good,” “fair,” and either “poor” or “not recommended.” In a small number of cases, five- or six-grade scales were used. With the exception of those tables based on permeation testing, these tables do not include information as to the basis for the recommendations. From the results of interviews with several of the vendors who do not supply permeation test results, it would appear that, at present, most do not have (or at least are unwill- ing to share) performance specifications or quantitative test data for their products. The ratings/recommendations for a particular type of product (for example, nitrile gloves) for a particular chemical may vary from vendor to vendor. Both of these factors- -little or no test data and inconsistencies among recommendation tables- -make the selection, from qualitative information, of the best CPC for a given application a difficult and uncertain task. An increasing number of vendors have available or are providing permea- tion test data, i.e., breakthrough times and permeation rates. These data allow the comparison of CPC products. However, such comparisons 51 ------- must be performed with caution since test results can be influenced by the testing method. For example, analytical sensitivity can strongly influence the detection of breakthrough. Also, some vendors report the earliest breakthrough time found in replicate tests while others report an average value. Given the above facts, the most important consiaeration to keep in mind when using vendor recommendation tables, including those based on permea- tion tests, is that the tables are intended to provide guidance, in the selection of CPC. That is, the tables are meant as a place to start the CPC selection process. The tables are meant for identifying candidate CPC for further evaluation and are particularly useful for identifying CPC from which poor performance would be expected and, therefore, which can be dropped from consideration. In no way do the recommendations address the wide variety of uses, challenges, and care to which the CPC may be subjected. Most vendors strongly emphasize this point in’ the ‘descriptive text which accompanies the tables. Secondly, the vendors’ recommendations were not developed by, nor are they sanctioned by, industrial hygienists or other safety professionals. CPC manufacturers are in business to sell clothing and not to set the standards for safety at any given work site. In conclusion, the principal purpose of the catalogues is to provide information about products in terms of the sizes, styles, and materials of construction. The ratings.charts should’ only be used as a starting point for further evaluation if chemical resistance is an issue. C. VENDORS’ ‘TEST METHODS The quality of the test methods used by vendors to generate data to support their recommendations range from state of the art to rudimentary. Since the promulgation of ASTM Method F739, several CPC vendors, have generated tabulations of permeation data for their products. As addi- tional standards are developed, an increase in testing can be expected. It would appear, however, that many purveyors of recommendation tables continue to rely on information provided by the supplier of the raw materials from which the clothing is fabricated. In general, the suppli- ers’ ratings are based on some form of immersion testing, but little or no permeation testing. Two drawbacks of this approach are (1) the raw material supplier may be unaware of the special needs of CPC, and (2) the CPC vendor has no firsthand knowledge of the chemical resistance of his products. Potential problems associated with the first drawback are: • Chemical permeation of a rubber or plastic material can occur with little or no physical effect on the rubber or plastic. This may or may not be detected by an immersion test. • The information provided by the materials supplier is typically developed for a general elastomer/plastic formulation or type. 52 ------- A result i-s that the recomnendation may not take into account formulation modifications that are required to put the material into a form appropriate for CPC. A further comment on recommendation tables based on immersion testing is that most are quite old, and based on subjective observation of immersion test specimens rather than quantification of swelling, weight, or strength changes. In many cases the details of the testing and the qualitative descriptions -for defining “excellent,” “good,” etc., were- not documented. Thus, it becomes impossible to compare results. Another consideration associated with the age of the recommendations is -that as time passes and 1. raw materials suppliers change formulations, - 2. CPC manufacturers change raw materials suppliers, and 3. CPC manufacturers change production methods, the performance of the same “nominal” product may also change. There is no indication that recommendations are routinely updated to reflect these changes, except in a few exceptional cases. These considerations may also apply to permeation data and the recommendations based on them. Again, the CPC recommendation tables should oniy be used for guidance. This includes those presented in the next chapter. 53 ------- CHAPTER 8 CPC RECOMMENDATIONS In this chapter, CPC recommendations for approximately 500 chemicals or aqueous solutions are presented. In addition, the chemicals. have been grouped into generic families (e.g., acids, amines, etc.) and general recommendations are made for each family which is represented by more than one chemical having CPC performance information for a given mate- rial. The recommendations are contained in Matrices A and B, and the data on which the recommendations are based are tabulated in Appendices A through E in Volume II. Appendix F in Volume II contains permeation data for several non-aqueous, multi-component solutions. The matrices are complemented by Appendices B through H which contain information perti- nent to the acquisition of CPC such as a directory of vendors’ addresses and telephone numbers. A. SCOPE AND LIMITATIONS 1. Chemicals Two matrices have.been developed. Matrix A (pp. 66-120) ‘contains CPC recommendations for approximately 500 chemicals or aqueous solutions and 33 clothing materials. The chemicals are the liquids inclu4ed in the Clean Water Act (CWA) Sections 311 and 307a, the Clean Air Act (CM) Section 112, and the Resource Conservation and Recovery Act (RCRA) Sections P, U, F, and K. Also included are any other chemicals (princi- pally liquids but including some gases) for which there were CPC vendors’ recommendations cr technical reports of permeation test results.’ No recommendations are presented for non-aqueous, multi-component solutions. Vendors’ recommendations or permeation data were not available for all the liquids addressed in the aforementioned acts. Approximately 40% of the chemicals are included in OSHA Directive Subpart 2- -Toxic and Hazard’- ous Substances, 29 CFR 1910.1000, Tables Z-1 and Z-2. 2. Chemical Classes An alphabetical list of the chemicals is presented in Appendix B. Note where a percentage follows the name of the chemical, it is indicative of the concentration of the chemical in water. All other liquids are single-component. Multi-component organic solutions are not addressed although permeation data for some are presented in Appendix F in Volume II. The right-hand column of Appendix B contains two pieces of information for each chemical: the chemical abstract number (CAS number) and a numeric “chemical class” code. The code is the “key” to Matrix A since the matrix is organized numerically by chemical class, with the code shown in parentheses following the generic class name. The chemical classification scheme is summarized in Table 8.1 and is based on the 54 ------- TABLE 8.1 LISTING OF CHEMICAL CLASSES Class Code ACIDS, CARBOXYLIC, ALIPHATIC Unsubstjtuted 102 Substituted 103 Polybasic 104 Others 106 ACID HALIDES, CARBOXYLIC Aliphatic 111 Aromatic and Heterocyclic 112 ALDEHYDES Aliphatic and Alicyclic 121 Aromatic and Heterocyclic 122 AMIDES Amides 132 AMINES, ALIPHATIC & ALICYCLIC Primary 141 Secondary 142 Tertiary 143 Polyamine 144 AMINES, AROMATIC Primary 145 Secondary, Tertiary 146 Polyamine 147 ANHYDRIDES, CARBOXYLIC Aliphatic 161 CYANIDES Cyanides 215 ESTERS, CARBOXYLIC Formates 221 Acetates 222 Higher Monobasic 223 Polybasic 224 Aromatic Phthalates 226 55 ------- TABLE 8.1 (Continued) LISTING OF CHEMICAL CLASSES Class Name Class Code ESTERS, OTHER THAN CARBOXYLIC Sulfonates 232 Others 233 ETHERS Aliphatic 241 Aromatic 242 Alkyl-Aryl 243 HALOGEN COMPOUNDS Aliphatic, Unsubstituted 261 Aliphatic, Substituted 262 Aromatic, Unsubstituted 263 Aromatic, Substituted 264 Polynuclear 265 Vinyl Halides 267 HETEROCYCLIC COMPOUNDS Nitrogen, Pyridines 271 Nitrogen, Quinolines 272 Nitrogen, Others 274 Oxygen, Epoxy Compounds 275 Oxygen, Furan Derivatives 277. Oxygen, Others 278 Sulfur 279 HYDRAZINES Hydrazines 280 HYDROCARBONS Aliphatic and Alicyclic 291 Aromatic 292 Polynuclear 293 HYDROXYL COMPOUNDS Aliphatic & Alicyclic, Primary 311 Aliphatic & Alicyclic, Secondary 312 Aliphatic & Alicyclic, Tertiary 313 Aliphatic& Alicyclic, Polyols 314 Aromatic 316 56 ------- TABLE 8.1 (Continued) LISTING OF CHEMICAL CLASSES Class Name Class Code INORGANIC ACIDS Inorganic Acids 370 INORGANIC BASES Inorganic Bases 380 INORGANIC GASES• Inorganic Gases 350 INORGANIC SALTS Inorganic Salts 340 I SOCYANATES Is.ocyanates 210 KETONES Aliphatic & Alicyclic 391 Alkyl-Aryl 393 LACTONES Lactones 400 MIS CELLANEOUS Miscellaneous 560 NITRILES Aliphatic & Alicyclic 431 Aromatic 432 NITRO COMPOUNDS Unsubstituted 441 Substituted 442 Nitroso 443 ORGANIC SALTS Organic Salts 550 ORGANO -METALLIC COMPOUNDS Organo-Metallic Compounds 461 57 ------- TABLE 8.1 (Continued) LISTING OF CHEMICAL CLASSES Class Name Class Code ORCANO-PHOSPHOROUS COMPOUNDS Organo-Phosphorous Compounds 460 ORGANO- SILICON COMPOUNDS Organo Silicon Compounds 480 PEROXIDES Peroxides 300 QUINONES Quinones 490 SULFUR COMPOUNDS Thiols 501 Sulfides & Disulfides 502 Sulfoxides 503 Sulfonic Acids 504 Sulfonyl Chlorides 505 Others 507 58 ------- system used by the Eastman Kodak Company. This system was selected because it addresses a large fraction of the chemicals of concern herein. Other classes have been added as needed. - In Matrix B (pp. 121-124), CPC recommendations are provided for the same 33 materials but in this case for generic families of chemicals. The chemicals in each family and on which the Matrix B recommendations are based are readily determined from Matrix A. Note that not all classes in Matrix A are presented in Matrix B; furthermore, recommendations are not given for all materials for all classes. The criterion for being given a recommendation in Matrix B is that the class must contain more than one chemical with CPC recommendation for the material of concern. In many cases there was considerable variability among the recommendations for chemicals within a class; these are indicated by double asterisks(**). In these cases, please refer to Matrix A for specific information. 3. Materials The 12 materials for which the most information is available are listed across the top of the matrices. Where information on other materials was available, recommendations for these materials are in the right-most column of the matrices. There were 21 such materials. A general charac- terization of several of the physical properties of 13 of the materials is presented in Table 8.2. The 33 material categories were reduced from the approximately 145 types and forms of clothing materials listed in Appendix E, and represent the materials of construction for well over 90% of the CPC considered in the Guidelines. Multi-component materials are identified in two ways. Blends are indi- cated by a “+.“ For example, a blend of nitrile rubber and PVC is designated nitrile + PVC. Coated or laminated structures are indicated by a “/.“ For example, nitrile rubber coated polyester fabric is desig- nated nitrile/polyester. By grouping several types and forms of clothing into one category, it is likely that in some cases particularly good or particularly poor items have gone unnoted since there can be significant differences in product quality between vendors. This is a compromise that must be accepted and recognized in summary compilations such as Matrices A and B. In general, however, a given material will exhibit the same performance relative to another material independent of-whether the materials are free films or coatings and independent of source. For example, if a butyl rubber glove is more resistant than a nitrile rubber glove to a given chemical, then it is highly likely that butyl rubber gloves and clothing in both supported and unsupported form will be better barriers to that chemical than their nitrile counterparts. In other words, differences in performances betw.een products of a given material will probably be small compared to performance differences between. categories of materials. In using the matrices, it must be remembered that their purpose is to provide a starting point for CPC selections. 59 ------- TABLE 8.2 * PHYSICAL CHARACTERISTICS OF CPC MATERIALS Material (Designation Abrasion Cut, Heat Ozone Puncture Tear ReLative in Matrices) Resistance Resistance FLexibility Resistance Resistance Resistance Resistance Cost ButyL Rubber (Butyt) F G G E E G G High Chlorinated PoLyethylene E G G 0 E 0 G Low (CPE) Natural Rubber E E E F P E E Medium Nitrile-Butadiene E E E G F E 0 Medium Rubber (NBR) Neoprene E E 0 G E G G Medium Nitrite Rubber (Nitrite) E E E 0 F E 0 Medium Nitrite Rubber + PolyvinyL G G G F E G G Medium ChLoride (Nitrite + PVC) PolyethyLene F F 0 F F P F Low Polyurethane E E 0 0 0 0 High Polyvinyl Alcohol (PVA) F F P 0 E F 0 Very High PoLyvinyL ChLoride (PVC) G P F P E G 0 Low Styrene-Butadi ne E G G 0 F F F Low Rubber (SBR) Viton G - 0 0 0 E G G Very High * Ratings are subject to variation depending on formulation, thickness, and whether the material is supported by fabric. E-excettent; 0-good; F-fair; P-poor ------- Selections based on the matrices’ recommendations do not guarantee protection since in no way do the matrices take into account such key issues as the application of the CPC or quality differences between CPC products. 4. Perfor nance Information The information on which the matrices are based is from three sources: • Vendors’ qualitative chemical resistance charts that are often included in CPC catalogues. The ratings in the charts of approximately 26 vendors (including the five largest manufac- turers of CPC) were tabulated and reviewed by chemical and material classes. In total, over 7,500 individual ratings composed the tabulation. • Qualitative chemical resistance charts from the suppliers of CPC raw materials. • The technical and product literature which addresses chemical resistance and permeation testing of CPC materials and prod- ucts. In all, over 5,200 individual test results (such as breakthrough time, permeation rate, tensile property, and percent weight change) were tabulated. The vendors use a variety of rating scales; some have three grades, most have four grades, and a few have five or six grades. In order to compare ratings, anormalized four-grade system (i.e., A, B, C, D) was developed. Briefly, products with the highest rating. in a four- or three-grade system or the highest two ratings in the case of a six-grade system were given a normalized rating of “A.” A normalized rating of “B” was given to the next highest vendor’s ranking, which was generally call “good,” but in some three-grade systems was. called “fair.” A normalized rating of “C” was given to the third highest vendor ranking except for the. three-grade systems. Typically, vendOrs called this ranking “fair.” Finally, all vendors’ rankings of “poor” and “not recommended” were given a normalized rating of “D.” B. RECOMMENDATIONS The recommendations in Matrices A and B resulted from a comprehensive analysis of all the information described above. Briefly, two separate computer data bases were developed: one for qualitative resistance information, •and one for quantitative data from CPC testing. (The test data are presented. in Appendices A through D of Volume II.) No attempt was made to validate any of the data prior to their input. The method of analysis served as an internal validation process. The information for each chemical/material pair in each data base was analyzed separately using computer algorithms .which took into account the amount and 61 ------- consistency of the information for each pair. (The rationale is de- scribed in detail in Appendix H of Volume II.) For each data base, the result was a classification of each chemical/material pair into one of the four following groups: Group 1 - - significant amount of information indicating excellent chemical resistance.• - Group 2 - - lesser amount of information indicating excellent chemical resistance. or - - significant amount of information indicating good chemical resistance. Group 3 - - significant amount of information indicating fair chemical resistance. or - - lesser amount of information indicating poor chemical resistance. Group 4 - - significant amount of information indicating poor chemical resistance. In all cases the algorithms were designed to produce a conservative classification; that is, inconsistencies were resolved in favor of the lower group. The results of the quantitative and qualitative analyses were, ‘then combined to produce the recommendations shown in Matrix A. Again,’ this was performed by means of a computer. The rationale was that shown in Table 8.3. In all cases of inconsistencies between the •ata and qualita- tive ratings, the test data were more influential in forming the recomL mendation. In, some cases (indicated by ** in the table), technical judgment rather than a computer algorithm was used because the informa- tion was not readily susceptible to simple computer analysis. Rather, it required careful consideration’ as to source, methods, and past experi- ence. Single and double, upper and lower’ case “r’s” and “n’s” are used to convey the recommendations. Briefly, RR, R, rr, and r indicate various degrees of good resistance and NN, N, nn, and n indicate various degrees of poor chemical resistance; Double characters indicate that there are test data to support the recommendations, and single characters indicate that only qualitative information was available. Upper case characters indicate consensus and a relatively large amount of information, whereas 62 ------- Test Data TABLE 8.3 QUALITAT!VE DESCRIPTION OF RECOMMENDATIONS IN MATRIX A* Qualitative Ratings *Recommendations obtained by computer algorithm. See Appendix H of Volume II for rationale. **Reomt.nendations for these combinations were determined on basis of technical judgement rather than computer alçjorithm. (-h) Quantity/ Resistance . Many/Excellent Few/Excellent or . Many/Good Many/Fair or Few/Poor Many/Poor . None Many/Excellent R R R R * * R A Few/Excellent or Many/Good rr rr ** : ** rr Many/Fair or Few/Poor flfl nfl . flfl . flfl S flfl Many/Poor N N N N N N N N N N None A r fl N No Recommenda- t ion ------- lower case indicates a relatively small amount of information or incon- sistencies. The recommendations in Matrix B are based on the technical judgment of the authors upon review of Matrix A. As stated in Point 6 of Section C which follows, Matrix .B is designed to provide general guidance to the initial steps of clothing selection. C. USER INSTRUCTIONS To make the most effective use of the Guidelines, references must be made to the matrices and the appendices. Assuming that the chemical(s) for •which protection is required is known, the procedure would beas follows: 1. Go to Appendix B, an alphabetical listing of chemicals listed in Matrix A. Find the chemical and referring to the right-most column, its class code. If the chemical is not listed, go to Step 6. 2. Return to Matrix A, a numerical listing of the chemicals by class. Locate the class which contains the subject chemical by means of the numbers in the parentheses’ next to the class names. Table 8.1 is a listing of the chemical, classes and their codes. 3’. Locate the subject chemical and read across to determine which is (are) the preferred clothing material(s) for the chemical. 4. Go to Appendix C, an alphabetical listing of CPC by material type and by product type. The vendors for the CPC are listed in the right column. Additional information on the products can be found by referring to Appendix E and using the first two digits of the product code from Appendix C. Also additional information on encapsulating ensembles and splash suits can be found in Appendices C and H, respectively. 5. Co to Appendix D, an alphabetical listing of the vendors and their addresses and telephone numbers. Contact the vendor(s) and initiate procurement procedures. 6. When the specific chemical of interest is not listed in Appen- dix B, it may be possible to narrow the CPC alternatives through the use of Matrix B. With the help of Table 8.1, attempt to classify the chemical; then follow the general recommendations provided in Matrix B. At this point, two options are open: (a) follow Steps 4 and’ 5’ above, or (b) return to Matrix A. In Matrix A, review all the chemicals in the class of interest and identify the one or two that are most similar to the specific chemical in question. Select CPC 64 ------- on the basis of the recommendations for the similar chemicals. Note. that in Matrix B, asterisks are indicative that the particular material exhibited considerable variability in its resistance to the chemicals of the given class. In these cases reference to Matrix A and caution in CPC selection is highly advised. During the selection and eventual use of the CPC recommended in Matrices A and B, it is important to remember that: 1. The recommendations are based on the best information avail- able. In some cases, however, this information is very limited 2. The recommendations are a guide, not a guarantee. 3. The recommendations probably do not hold for extreme use conditions (e.g., high and low temperatures, long-term contact, high abrasion, etc.) nor do they consider the problems associ- ated with reuse described in Chapter 6, Part F. 4. There may be certain products in each category that are better or poorer than the norm. Also, the quality of construction of even the “better” products can vary from batch to batch. In their present form, the matrices do not address quality issues. The assessment of quality and uniformity o.f quality can best be gained through field experience and, therefore, left as a task for the field personnel. It is possible that future Guidelines will be modified to include recommendations for specific products that are based on quality and field performance. 5. The “double” letter recommendations are based primarily on breakthrough time data; permeation rate data were given only secondary consideration. A final comment pertains to the completeness of CPC product and vendor listings presented in the appendices. The objective was to include at least one source for any given item of CPC. The listings, therefore, are extensive but are probably not all-inclusive; it is unlikely that all distributors or all brands/lines of CPC are mentioned. The listings are designed such that they can be readily expanded to cover additional manufacturers or distributors as they become known to the EPA or U.S. Coast Guard. Furthermore, the recommendations can also be modified as additional performance information becomes available to the EPA or U.S. Coast Guard. 65 ------- MATRIX A RECOMMENDATIONS BY CHEMICAL 66 ------- Acids, Carboxylic, Aliphatic Llnsubstituted (102) Acetic Acid Acetic Acid, <30% Acetic Acid, 30-70% AceticAcid, >70% Acrylic Acid Butyric Acid Diacetin 2-Ethylhexanoic Acid Formic Acid Formic Acid, 30-70% Formic Acid, >70% -J ft rr R r r r r r -4 -J ¼ ’ . 4. 4. -.1’ 0 — 4. . ¼’ -4 I : nn RR nfl RR nfl n NN rr r rr n rr rr nfl n rr R ft R r NN ft n r rr rr nfl rr nfl n nfl rr rr rr rr n r rr rr r -I 0 TEFLON( rr) NEOP+NAT R(JB(RR) NEOPRENE+SBR( r) NAT+NEOP+NBR( r) POLYtJRETHANE( r) SARANEX( rr) SBR( r) VIT/CLORBUTL( rr) NEOP/NAT RtJB(RR) SBR/NEOPRENE( r) POLYIJRETHANE( r) SBR( r) TEFLON( rr) NEOP+NAT RUB( r) NEOPRENE+SBR( r) POLYURETHANE( R) SBR( R) SBR/NEOPRENE( r) NEOP+NAT RUB(rr) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. 4. .4 S ------- Acids, Carboxylic, Aliphatic (cont.) Unsubst/tuted (cont.) (102) Glycerin Triacetate Laurie Acid Lauric Acid, 30-70% Linoleic Acid Methylacrylic Acid Oleic Acid Palmitic Acid Propionic Acid Stearic Acid I ‘I / (5 , -I ‘I ‘ q q• r n r rr rr rr r n r n n r r nfl rr rr rr rr rr NN rr n f l NN r R R r R e 1/ - .1 Ii r r nfl r r r rr r r NEOP+NAT RtJB( r) NEOPRENE+SBR( n) POLYtJRETHANE( r) SBR( n) SBR/NEOPRENE( r) rr r TEFLON( rr) R POLYURETHANE( R) SBR( R) SBR/NEOPRENE( r) Note: Numbers in parentheses are chemical class codes —- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- Lactic Acid Acids, Carboxylic, Aliphatic (cont.) Substituted (703) Chloroacetic Acid Lactic Acid, <30% Lactic Acid, >70% Malic Acid Polybasic (101/) Maleic Acid Maleic Acid, >70% Malic Acid Oxalic Acid .4- ‘4I 4 ) . 4. ‘4.4 - -J .- — ‘3 , -d ‘4! . 4. 4. 0 -J 4. — NN SARANEX(rr) R r r R R R R R r r NEOP+NAT RUB( n) NEOPRENE+SBR( r) POLYURETHANE( R) SBR( R) SBR/NEOPRENC( r) r r rr rr rr rr rr rr rr r r r n n R R n rr RR RR rr rr r ,r rr r RR RR Others (106) BenzenesulfOnic Acid rr n R r rr rr rr r rr n RR rr rr POLYURETHANE( n) SBR( r) SBR/NEOPRENE( r) SBR( r) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.. Source: Arthur 0. Little, Inc. ------- Acid Halides, Carboxylic Aliphatic (111) •1 . a. ..- -. # — , ‘.. * * ‘I a. -I 0 -J ’ 0 . : • a. a. ‘ l a 0 I S• Acetyl Chloride n r n TEFLON(rr) SARANEX( nfl) Ethyl Chiorocarbonate Aromatic and lleterocyclic (712) Benzoyl Chloride Al dehydes Aliphatic and A//cyclic (121) Aceta Idehyde -J 9 Acrolein Butyra Idehyde Crotona I dehyde Decanal (all isomers) r rr n r RR NN rr NN no rr on rr rr nfl n rr NN nfl 0 HYPALON(nn) TEFLON(rr) NEOPRENE+SBR( r) POLYURETHANE( r) SBR( n) V IT/CLORB IJTL(nn) S ILVERSHIELD(rr) SBR/NEOPRENE( n). VIT/CLORBUTL( rr) r TEFLON( rr) POLYURETHANE( n) SBR( r) SBR/NEOPRENE( r) TEFLON( rr) NN rr rr SARANEX(rr) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. •NN NN NN NN NN no NH NN on NN nfl ft nfl NN n R no r r nfl NH rr rr NN C, •.1 .5 ‘I ------- Aldehydes (cont.) Aliphatic and Al/cyclic (cont.) (121) Formaldehyde, <37% G I uta ra I dehyde Hexana I I sobutyra Idehyde rr Propionaldehyde rr Trichloroacetaldehyde . nfl Aromatic and iletrocyclic (122) Benza Idehyde Furfura I , a. -.. ¼• a. sI c - a. ‘ a. . 0 , ! > -. . . A. q . C, RR rr r NN NN nfl NN RR rr rr r rr n n nn nn n nfl NN RR RR r n NN NN nfl NN NN rr nfl fin n NN RR rr rr NN NN NN nfl NN NN rr ‘I r TEFLON(rr) NEOP+NAT RUB( n) NEOPRENE+SBR( r) POLYIJRETHANE( r) SBR( R) SILVERSHIELD( rr) SBR/NEOPRENE( r) r N n r NEOP+NAT RIJB( n) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( r) SBR/NEOPRENE( n) N rr r TEFLON( rr) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SILVERSHIELD( rr) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes -— see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g..RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. —4 I.- . ------- f in nn nfl nfl Am/des (132) N, N-Dimethylacetamide Dimethylformamide RR ‘ nfl NN , fl NN, nn NN N NN Formamide, 30% Hexamethy lphosphoamide rr nfl nfl nn nn ‘Urea r •r r r Asnines, Aliphatic&Alicycl ic Pr/mary (1I 1) Allylamine Butylarnine nn nfl NN n NN NN nfl iso—Butylarnine nfl rr fi NN Cyclohexylathine Ethanolamine nfl rr r n NN RR fin RR RR nn RR rr -4 NEOP+NAT RUB( n) SARANEX( rr) TEFLON( rr) NEOP+NAT RUB(nn) SBR( r) VIT/CLORBUTL( rr) SILVERSHIELD(rr) NEOP+NAT RUB( r) POLYURETHANE( nfl) r nfl NN NN n TEFLON(rr) VI T/CLORBUTL( nn) fin NN n VIT/CLORBUTL(rr) rr rr fl fl NE0P ENE+SBR( n) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: ArthurD. Little, Inc. n ides’ 1 I ‘4, I C., ‘I ------- -1 -.1 w a. ‘4 , ‘5 , 0 a. . Amines, Aliphatic &Alicyclic (cont.) Primary (liii) (cant.) Ethylamine, 30-10% I sopropylamine Methy lam me Methylarnine, 30-70% Mono I sop ropano lami ne n- P ropy lam me Secondary (11/2) sec-Butyl amine Diallyamine 01-n-amy lam i ne Dibuty lam me Diethylamine nn nn r nn rr rr rr rr nfl NN n rr NN rr rr rr TEFLON( rr) SI LVERSH I ELD( nn) . MN NN TEFL ON(rr) . PV ACETATE(rr) rr SBR( r) nfl rr NM rr SILVERSHIELD(rr) rr . TEFLON( rr) PV ACETATE(rr) nn nn nn NN nn rr NN rr n f l rr NM rr n nn rr NM rr n nn n NN NN n NM NN n MN fin n SARAN [ X(nn) SBR( r) VIT/CL ORBUTL(nn) IILVERSIIIELD(rr) Diisobuty lamine nn rr rr rr Note: Numbers in parentheses are chemical class codes —- see Table 81 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. -I / a. -d S. • 44g. -I / -J ‘I ------- Aznines, Aliphatic &Alicyclic (cont.) Secondary (11i2) (cont.) Di isopropylamine Dime thy lam me Di methylethano lam I ne Dip ropy lam me Ethyi-n-butylami ne Ethylenimine n-Me thy le tha no lamine Morphol me Pyrrole -.1 4. -.. - -. . * 4. sd c .-j :w . 4. . 4. . -S . d 4 I 0 I > 4) nfl rr rr NN nfl nfl NN rr • NN nfl nn nn nn rr NN nfl nn nn NN rr NN rr RR nn N r NN RR n RR NN rr TEFLON( rr) TEFLON( rr) POLYCARBONAT( rr) CELLUL ACRYL(rr) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SILVERSHIELD( rr) SBR/NEOPRENE( n) n Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. C, -J ‘5 ‘I n ------- : ‘ 1 . -J -J — — , ; .-. * .* . 1 Q. , , , -.1 V. . . 4. 4. , . — . . Ainines, Aliphatic & Alicyclic (cont. ) Tertiary (7113) . tert-Butylarnine Diethanolamine Diethylami noethanol Dimethylbutylamine n-Ni trosod i methylam I ne Trial lylamine Triethanolamine Triethanolamine, >70% rr rr r •rr rr rr - .. Triethylamine Tri—n—propylamine rr n nn nn RR rr • rr rr rr n rr n nfl r rr rr rr rr rr nn nn nfl NN nfl nn rr r r r N R rr R rr NN rr SBR( n) TEFLON( rr) NEOP+NAT RUB( r) POLYURETHAN [ ( n) SBR( ii) SBR/NEOPRENE( n) rr n r POLYURETIIANE( n) SBR( n) SBR/NEOPRENE(. n) NN rr n Note: Numbers in parenthesesare chemical class cOdes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Li’ttle, Inc. I ‘4’ -I I, ------- Amines, Aliphatic &Alicyclic (cont.) P0/yam/ne ( /i4) 1, 3-Diaminopropane. Di ethylenetriam i ne Dime thy lam mop ropy lamine Ethylenediamine Iminobi spropylamine 3-Methylami flop ropy lam I ne Propylenediamine Tetraethylenepentam i ne N, N, N’ , ‘ —Tetramethylened i amine -J ° ‘ Triethylenetetrarnine -.1 nfl NN rr rr nfl nfl MN nfl . q. i -.1 — — * ‘1 - .- , -. * Q . ‘ 3 / O C., . . Q. , . -. . . . , , ‘ . . G, .-J . . . ;, , ._ . o . • rr nfl n NN rr fin rr NM nfl rr NM fin rr rr rr nfl nn nfl nfl rr nn rr NN nfl rr MN NN Il TEFLON(rr) SARANEX(rr) NN rr nn rr rr NN nfl rr Amines, Aromatic Pr/mary (145) Aniline RR r rr NM TEFLON( rr) NEOP+NAT RUB(rr) NEOPRENE+SBR( n) POLYURETHANE( r) SARANEX( rr) SBR( n) NEOP/NAT RUB(NN) SILVERSHIELD(rr) SBR/NEOPRENE( n) MN NN nfl NN RR NM NN rr Dimethylanaline fi Note: Numbers inparentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. n ------- -I rr Q . d C) n fl n r rr rr NN nfl C ) 4. - . -S -S — . / 4. 3d c • .J ‘. C, - 4. 4. ‘ 4 ’ 0 * . . 4 Amines, Aromatic (cont.) Secondary, Tertiary (Ui6) Dicyclohexylamine 1—Piperazineethaneamine o-Toluidine Polyaminè (71i7) Methyl Aniline Phenylenediamine Anhydrides, Carboxyl ic Aliphatic (161) Acetic Anhydride Prop ionic Anhydride Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.)see Table 8.3. Source: Arthur D. Little, Inc. n NN n fi fi NN ‘4’ 0 S .. . 4/ * -.4 C., - .1 ‘ S . 0 TEFLON( rr.) TEFLON( rr) ------- Hylene Cyan Ides Cyan ides (215) Hydrocyanic Acid Potassium Cyanide Sodium Cyanide, <30% Sodium Cyanide, 30-70% Esters, Carboxyl ic Formates (221) Ethylene Acetate Ethyl Formate -.4 03 Methyl Chloroformate Methyl Formate rr r r n n r n r R nn n * 1 • .1 - i I! n n R POLYURETHANE( r) SRR( n) SBR/NEOPRENE( n) n POLYLJRETHANE( n) SBR( R) SBR/NEOPRENE( r) n Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. C) -d Q c - I . ..- 4. . C.,. -J ‘I rr nn r r r rr NN n N ------- Esters, Carboxylic (cont.) Acetates (222) Amyl Acetate Butyl Acetate Butyl Cellosolve Acetate 2-Ethoxyethyl Acetate Ethyl Acetate Ethyl Acetoacetate Glycerin .Triacetate C) . Q . 4 -‘I .‘,, •.J . .-. 0 a C.) ... ., -. , . . ,I ‘. . . .- . ‘I • q q• Note: Numbers in pa rentheses are chemical class codes -— see Table 81 and Appendix B. For explanation of recommendation codes (e.g.. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. Cj . A. S. . g . C., A. £q Q. ‘ .C_, R n n nn , nn nfl NN rr nfl n n NEOP+NAT RUB( r) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( N) SBR/NEOPRENE( n) rr r NN NW nfl NN NW rr NW nfl TEFLON(rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) NAT+NEOP+NBR( r) POLYIJRETHANE( r) SBR( r) NEOP/NAT RUB(NN) .SILVERSHIELD( rr) SBR/NEOPRENE( n) NAT+NEOP+NBR( r) n nn nn . . ,r NAT+NEOP+NBR( . r) rr nn n NN NW nfl NW NW n nfl n n TE.FLON(rr) NEOP+NAT RUB( r) NEOPRENE+SBR( n) POLVURETHANE( r) SARANEX( nn) SBR( N) VIT/CLORBUTL(nn) SI LVERSH I ELD( rr) SBR/NEOPRENE( n) r r r ------- Esters, Carboxyl ic (cont. ) Acetates (222) (coAt.) Isoamyl Acetate Isopropyl Acetate Methyl Acetate Methyl Cel losolve Acetate Methyl Chloroacetate Propyl Acetate Vinyl Acetate Higher Monobasic (223) Butyl Acrylate Butyl Oleate Butyl Stearate I a. -J / ‘ ,$ - 4I . a. .1 w . . a. . — . . NEOP+NAT RUB(NN) HVPALON(nn) NEOP/NAT RUB nn) n n POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) NAT+NEOP+NBR( r) SARANEX( rr) fl NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SILVERSHIELD( rr) SBR/NEOPRENE( n) TEFLON( rr) n TEFLON(rr) ’ r r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: ArthurD. Little, Inc. ‘C, -J ‘I NN MN NN ‘nfl MN NN n rr n NN r n n NN nn NN rr ‘ n NM n ‘ n MN MN rr N n n r fl n r r ------- Esters, Carboxylic (cont.) Higher MoriobasIc (223) (corit.) Ethyl Acrylate Ethyl Methacrylate Isobutyl Acrylate Isopropylmethacrylate Methyl Acrylate Methyl Methacrylate Methyl Oleate Propylmethacryla te Polybasic (221,) Oibenzyl Sebacate Dibutyl Sebacate Di-(2-Ethylhexyl )-Sebacate Diethyl Oxalate Diethyl Sebacate Di isooctyl Sebacate Tannic Acid Tannic Acid, 30-70% Tannic Acid, >70% I (4 nfl NN nfl NN nfl nfl nfl nfl nfl rr n NN nfl n n NN r () 4. 4 1 ..., -.1• - . .- , 1 U—. — . . . 4. ‘ 3 1 ( 0 • .1 .. 4. 0 . 4. • / — . , 0 C., ‘I NW rr NN NN rr TEFLON(rr) SARANEX(rr) VIT/CLORBUTL(nn) rr NW nfl rr •nn rr nfl rr n n n NW RR nfl nfl r r r r r r R r R R rr R rr rr rr rr rr rr nfl NN NN n TEFLON(rr) NW n TEFLON(rr) r rr NW r n r r r r rr r NEOPRENE+SBR( r) POLVIJRETHANE( r) SBR( R) SBR/NEOPRENE( r) rr Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,.R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- Esters, Carboxyl Ic (cont. Aromatic Phtha/ates (226) Bis(2—Ethylhexyl ) Phtha late n—Butyl Phtha late 03 Q. it •.1 / .4, -I S. -d C., .1 41 rr r rr rr RR nn NN rr r RR n r NN rr NN rr RR N rr -J ii .. r NEOPRENE+SBR( n) POLYURETHANE.( n) SBR( r) SILVERSHIELD( rr) SI3R/NEOPRENE( r) n r flfl NN nfl NEOP+NAT RUB( r) Diisoctyl Phthalate r r Dimethyl Phthalate r r Di—n-octyl Phthalate Di—Sec—Octyl Phthalate r r Methyl Salicylate fl r Esters, other than Carboxylic Others (233) Ethyl Silicate Isobutyl Nitrite Tetrabutyl Orthotitanate In isooctyl Phosphate r r r nfl NN nfl Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. r r r ------- Ethers Aliphatic (2’ I1) • Butyl Cel losolve r UN Butyl Cellosolve Acetate Dibenzyl Ether n N R r r Dibutylether 2,2’—Dichloroethyl Ether nn rr 2—Ethoxyethyl Acetate n n rr n Ethyl Cel losolve Ethyl Ether • RR NN r r n NW NN NN NW nfl NN UN Isopropyl Ether rr n UN nn rr Methyl Cellosolve rr . n R r nfl Methyl Cellosolve Acetate . . Methyl Cellulose n r r 4. ‘ .‘ ‘ -I - • .. -. £ , ** 4. 3I a (J -I : 0 4. / , , . , I . , ,, . ‘ $:. rr rr R n UN NN NN RR nfl NN rr nfl rr R r n NAT+NEOP+NBR( r) NAT+NEOP+NBR( r) r POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) fl TEFLON(rr) r NAT+NEOP+NBR( r.) n NAT+NEOP+NBR( r) n TEFLON(rr) NEOP+NAT RUB( n) NEOPRENE+SBR(. r) POLYURETHANE( n) SBR( R) VIT/CLORBUTL(NN) SILVERSHIELD(rr) SBR/NEOPRENE( r) n NEOP/NAT RUB(NN) NEOP+NAT RUB(nn) NAT+NEOP+NBR( r) POLYURETI-$ANE( n) SBR( n) SBR/NEOPRENE( n) POLYURETHANE( r) Note: Numbers in parentheses are chemical class codes -- see Table 8. 1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. ‘4 ’ -d ‘4- r n I ) ------- Ethers (cont. Aromatic (242) 1, 3-D ioxo lane AIky/-Aryl (243) Phenyl Ethyl Ether Halogen Compounds Aliphatic, Unsubsti’tuted (261) Allyl Chloride n-Butyl Chloride Ca rbontet rab ron ide Carbon Tetrachloride 03 I -J / ‘4 , -I I -J -.1 ‘4J . q. q• n n r rr nn r-. N nfl r NN NN NN N NN RR n n n -J ‘I n TEFLON(rr) PV ACETATE(rr) NN rr n TEFLON(rr) .NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( N) NEOP/NAT RUB(NN) PV ACETATE( rr) SILVERSHIELD( rr) SBR/NEOPRENE( n) 2-Chloro—1,3-butadiene r NN NN rr NN Chlorodibrornornethane nn nn NN rr Chlorododecane r n Note: Numbers in parentheses are chemical class codes-- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. rr nn rr ------- Halogen Compounds (cont.) Aliphatic, Unsubstituted (261) (cont.) Ch 10 ro form Di ch I orobromomethane 1 ,4-Dichloro-2-butene Dichloroethane cis-D ich 10 roe thy lene 1,2-Dichioroethylene Ln ti, 2-D I chlo roethylene Dichioroethylene (all isomers) Dichloropropane (all isomers) Dichioropropane-Dich loropropene 2, 3-Dichloro-1-propene 1, 3—Dichloropropene Ethyl Bromide Q. S. ‘4, -I # -. . ‘4, a. ‘3 ’ c (.1 iQ . . a. , 0 ! > -. . . NN NH r n n n -4 // N NN r NN NH ii NN NN RR NN rr n TEFLON(rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( r) SARAN EX(NN) SBR( N) VIT/CLORBIJTL( rr) NEOP/NAT RUB(NN) SI LVERSH I ELD( NN) SBR/NEOPRENE( n) nn NH rr V ITON/BUTVL(rr) nfl NH NN rr NN RR SARANEX(rr) n n TEFLON(rr) fin NN NN rr nfl NN nfl NN rr NN rr n fi fin nfl fin NN NN rr NN rr rr NN rr rr NH nfl TEFLON(RR) TEFLON( rr) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix 8. For explanation of recommendation codes (e.g. RR,R.,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. ------- Halogen Compounds (cont.) Aliphatic, Unsubstituted (261) (cont,) Ethylene Dibromide Ethylene Dichioride Ethyl idene Dichloride Freon 11 Freon 12 Freon 21 Freon 22 0, 0 ’ Freon 112 Freon 1114B2 Freon IF Freon TMC I-la lothane Hexach 10 rocyc lopentad I ene Isopropyl Chloride no nn rr NN NN nn nfl r NH NN nn n r n R r n R n n r r r r n r NH RR no RR rr rr NN NN nn nn r : ‘ . ‘t. , -J 0 -1 -.1 ..- — --1 w - S. , • -S • a. . - -J NH NN RR NN no NH TEFLON(RR) SARANEX(NN) n NH NN nn NH rr n TEFLON(nn) NEOP+NAT RUB(NN) POLYURETHANE( no) NEOP/NAT RUB(NN) SILVERSHIELD( rr) rr NN nn fl n r n SBR(n) r n r SBR(n) o n SBR( n) o n SBR( n) n n NN nn NN r NEOP+NAT RUB(NN) NEOP/NAT RUB(nn) NH rr rr CHLOROBUTYL(rr) TEFLON(nn) rr NN on nn rr rr r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. c 4I ------- Halogen Compounds (cont.) Aliphatic, llnsubstituted (261) (cront.) Methyl Bromide n Methyl Chloride n N r 4. -I I. ‘3’ 4I’ -J C., -.1 ‘I’ . 4. 4. r nfl N I•) n ‘•n n N 4.4 ; 0?/ N r Methyl Chloroform NN n r NN NN NN NN NN RR MN rr n Methylene Bromide n n n n NN rr n Methylene Chloride . NN on r MN NM nn NN NN on NM no n Methyl ‘Iodide nn NM NM MN MN rr Propyl Chloride Propylene Dichloride on ‘ rr MN rr Tetrachiorodifluoroethane r n 1,1,1,2-Tetrachioroethane nn rr NN rr 1,1,2,2-Tetrachioroethane on n MN MN no NN rr NN rr Note: Numbers in parentheses are chemical class codes -- see Table’8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. -1 ‘I’ SARANEX( rn SBR( r) NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) TEFLON( rr) NEOP+NAT RUB(NN) POLYURETHANE( NN) NEOP/NAT RUB(NN) SILVERSH IEL O(rr) TEFLON( nfl) NEOP+NAT RIJB(NN) VI T/CLORBUTL( NN) NEOP/NAT RUB(NN) SILVERSFIIELD( rr) NEOP+NAT RIJB(NN) NEOP/NAT RUB(NN) PVACETATE( rr) TEFLON( rr) NEOP+NAT RUB(NN) ------- Halogen Compounds (cont.) Aliphatic, Unsubstituted (261) (cont.) let ra ch 10 roe thy lene Tetrafluoroethylene rr 1,1,2-Trichioroethane nn Trichio roe thy lene OD 1,2,3-Trichioropropane nn -J / ‘ ‘ —.1 — — . i ‘3 ’ 0 0 (. . -J . ‘I • . — q g NN rr r NN NN NN nfl NN nfl NN RR rr rr rr NN NN NN NN nfl NN rr NN nn NN NN NN NN NN NN NN nfl nfl rr rr Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and.Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. C ,, -5 ‘S n TEFLON(nn) NEOP+NAT RIJI3(NN) NEOPRENE+SBR( n) POLYURETHANE( n) SARANEX( NN) SBR( N) SI LVERSIl I ELD(rr) SBR/NEOPRENE( n) TEFLON( rr). POLYURETIIANE( NN) CHLOROBUTVL( r) TEFLON RR) N [ OP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURET1-IANE( nn) SARANEX( NN) SBR( N) NEOP/NAT RIJB(NN) SILVERSHIELD( rr) SBR/NEOPRENE( n) ------- £q -I .- .- * ‘I a. s’ , C.) ‘.1 0 •. . a. a. , ‘ 0 * - - Halogen Compounds (cont.) Aliphatic, Substituted (262) 2-Bromoethano I 1 -Brorno-2-propanol 3-Bromo-1 -propanol Ch I oroacetone Chloráacetonitri le 3-Gb Ioro-2-methylpropene 1-Ch Jo ro-2-p ropa no I 3-Ch loro-1-propanol 1,2—Dibromo-3-chloropropane Dichloroacetyl Chloride 2,2’-Dichloroethyl Ether Epichiorohydrin Ethylene Chiorohydrin Trichioroaceta Idehyde 2,2, 2-Trichloroethanol In? luo roe tha no I rr UN rr UN rr rr r n n R n rr NN nn rr NN rr nn n nfl RR nn n NN nfl NN rr rr rr rr rr N rr NN r r UN rr NU rr nfl NN rr n rr UN rr nn UN UN nfl nfl rr r rr rr rr n rr rr NN rr rr rr NN RR MN r POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) TEFLON( rr) TEFLON(RR) POLYURETHANE( nfl) SARANEX( nfl) SARANEX(nn) NEOP+NAT RUB(rr) NEOP/NAT RUB( rr) Note: Numbers in parentheses are chemical class codes.-- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. p C.) 0 a. I. C, -J ‘I ------- -J Halogen Compounds (cont.) Aromatic, Urisubstituted (263) Benzyl Chloride Bromobenzene Bromoch loromethane Ch 10 robe nzene o-Chlorotoluene p-Ch loroto I uene .o Dichlorobenzer e 1 ,2-D,i ch 10 robenzene 1, 3-D i ch lorobenzene F Iuo robenzene 1 ,2,t4-Tri hIorobenzene Aromatic, Substituted ( 26’i) Pentachlorophenol d !.& 1 — -. . . * .* 1 4. ‘3 ’ c ? . 4. £4, 4 ‘5 , * • ? C -, 4. . -J ‘I N n TEFLON(rr) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) rr rr n r NN RR n TEFLON(rr) NEOP+NAT RUB( n) SBR( n) rr rr n nfl rr n nfl rr n nfl nfl NN rr NN rr NN rr TEFLON(rr) SARANEX( nfl) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. n nn r N N n r r nn r fin n r N NN n nfl NN nn n n f l r r NN NN rr NN ------- (1 0 Halogen Compounds (cont.) Polynuclear (265) Chloronaphthalenes (all isomers) Polychlorinated Biphenyls (PCB’s) Vinyl I/a/ides (267) Dimethylvinyich loride Vinyl Chloride Vinyl idene Fluoride r N n nn n NN rr n rr rr NN NN n rr n rr r NN rr n rr NN rr NN rr NN n rr NN rr SILVERSHIELD(RR) TEFLON( rr) SARANEX( RR) SILVERSHIELD( rr) Note: Numbers in parentheses are chemical class codes -— see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.. Source: Arthur D. Little, Inc. I 0 -J ‘4’ I -J c5 -1 Q. C, -J ‘I ------- Heterocycl ic Compounds Nitrogen, pyridines (271) Pyrid me Nitrogen, Others (274) Ethylen i mine P i per i d i ne Oxygen, Epoxy Compounds (275) Allyl Glycidyl Ether Epichlorohydrin 1 ,2—Epoxybutane Ethylene Oxide Phenyl Glycidyl Ether Propylene Oxide 1,3-Propylene Oxide Oxygen, Fura, Derivatives (277) Fu ran Tetrahydrot’uran Oxygen, Others (278) 1,4-Dioxane rr rr rr nfl NN NN nfl nn n NN nfl nn n n n NN rr NN rr NN nn n n NN NN . n NN NN NN NEOP/NAT RIJB(nn) n TEFLON(rr) Note: Numbers in parentheses are chemical class codes - - see Table 8.1 and Appendix B. For explanation of ’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3.’ Source: Arthur D. Little, Inc. ,& , ‘ . 0 k 0 41 .. - ,•i! :$ — — ‘4. — ‘. 1 Cj . . * 41 4. .3’ . -.1 . 0 . 4. . . p1 ’. 0 , .> ,: . r NN NN NN rr n nn nfl NN n rr rr nn RR n’ NN nfl nn NN - ‘I ‘I NEOP+NAT RUB(NN) NEOP/NAT RUB(nn) NEOP/NAT RUB(rr) TEFLON( RR) POLYURETHANE(nn) SARNEX( nn) r r rr rr rr n NN nfl NN nn fl rr NN NN n n nn n NN NN RR r NN NN n NN NN n NN NN TEFLON( rn NEOP+NAT RUB(NN) SARANEX( NN) VI T/CLORBIJTL( NN) NEOP/NAT RUB(NN) TEFLON( rr) NEOP+NAT RUB(nn) SARANEX(nn) , ------- Hyd raz i nes Hydrazines (280) 1, 1—Dimethylhydrazine 1 • 2-Dimethylhyd raz me RR nfl n NH NH NH NH NH nfl Hydrazine rr n r rr rr rr n Hydrazine, 30—70% rr rr rr rr RR rr n rr Methylhydrazine NN nfl nfl rr n n CHLOROBUTYL(rr) TEFLON(nn) NEOP/NAT RUB(NN) n CHLOROBUTYL( rr) TEFLON(nn) SILVERSHIELD( rr) CHLOROBUTYL( rr) CR 39(rr) TEFLON(NN) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation cf recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ‘I -4 ‘.1 — — ‘ 1 * * Q. -.1 0 —1 q. 1 0 A. — . Q . . C, -4 ‘I ------- Hyd roca rbons Aliphatic and Alicyclic (291) Butad i ene Butane Butene Butylene Cyc I ohexa ne Decahydronaphtha lene Deca ne .4 - Diiscibutylene Di pen tene Ethane Ethyl Silicate Ga so I i ne rr NN. nn n q. -I / 1 -J / -J -J ¼ . a. a. 1 o — . a.: . NN rr N R r n N r n r r r r n r N r r NN NN n RR NN nn NN n r r r r r r nn r rr N rr NN rr r RR n n n n n r rr NN rr NN r nn -.1 .5 Ii NEOPRENE+SBR( r) POLVLJRETHANE( R) SBR( ii) SBR/NEOPRENE( n) SBR( r) TEFLON( rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLVURETHANE( n) SBR( n) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( R) SBR( n) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes-- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN; etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- . -.1 - . -.. Q ¼. o , âb C.) -., . Q . C., q . . . -S , 0 . > C, -1 -w c $ Hydrocarbons (cont.) Aliphatic and Al/cyclic (cont.) (291) Heptane Hexane NN 1-Hexene b-lonone rr I sobutylene I sooctane Isoprene JP-4, Jet Fuel Kerosene Methane Methyl Cyclopentane UN nfl rr RR rr NN rr UN NN NN NN UN RR NN r rr rr n r r NN UN nfl n nfl NN nfl nfl rr RR fl nfl UN r n rr rr n r NEOP/NAT RUB(NN) TEFLON(rr) NEOPRENE+SBR( n) POLYURETHANE( R) SBR( N) VIT/CLORBUTL( rr) SILVERSHIELD(rr) SBR/NEOPRENE( n) r nfl N rr .rr. nfl rr fin r n NEOP+NAT RUB(nn) NEOPRENE+SBR( n) POLYURETHANE( r) SBR( n) SBR/NEOPRENE( n) rr n Mineral Spirits N rr NN rr NN rr NN NEOP+NAT RUB(nn) SARAN EX(NN) SBR( r) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table8.3. Source: Arthur 0. Little, Inc. (I S., ------- , g’ ‘I a. o ‘ a. -J a. £4 , £4 1 0 -.1 . -1 £4i (v £4 ’ -J -J - .‘ -‘ .4- .“ .4_ .4- 0 .4- 0 . . Hydrocarbons (cont. Aliphatic and Al/cyclic (cant.) (291) Naphtha, V.M.& P N rr r N. nfl NN rr NN rr UN r n NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( R) SBR( n) SBR/NEOPRENE( n) Octadecane r n n-Octane r nfl rr rr rr nn n NEOP+NAT RUB( n) Pentane n UN NN NN NN UN nn NN RR NEOP+NAT RUB(NN) NEOP/NAT RUB(NN) SILVERSH IELD(rr) Pentene r n SBR( r) Pinene Call isomers) r fl Propane N N R R n rr r r NEOPRENE+SBR( n) POLYLJRETHANE( R) SBR( n) SBR/NEOPRENE( n) 2,2,t4 —Trimethylpentane r n 2,4,14—Trimethyl-1-pefltefle r fl Turpentine N r r N N N nfl nn rr N r n TEFLON(rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( r) SBR( n) SBR/NEOPRENE( n) f4-Vinyl-1-cyclohexane nfl nfl nfl rr •Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. ------- Hydrocarbons (cont.) Aromatic (292) RR nfl rr nfl rr £4J. -J I Benzene NH nfl rr NH NN NN NH NN tIN NH nfl rr p-tert-Butyl Toluene 3-Ch loro-2—methylpropene m-Cresol : . Cresols n r r Cumene rr r Cymene r Diethyl Benzene r Diisopropyl Benzene (all isomers) r • Divinyl Benzene RR RR Ethyl Benzene n Gasoline nfl r rr N rr N N rr N N rr NH r nfl rr rr NN -I’ C ) 1.. — 4 . C) ‘3 , 1. -J - C., -.1 k3 EVA(NN) TEFLON(NN) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETIIANE( NH) NONWOVEN. PE(NN) SARANEX( NN) SBR( N) NEOP/NAT RUB(NN) PV ACETATE(rr) SILVERSHIELD( rr) SBR/NEOPRENE( n) SILVERSHIELD( rr) TEFLON( rr) NEOP+NAT RUB(nn) NEOP/NAT RUB(rr) n SARANEX(rr) n n n fl SILVERSHIELD( rr) n TEFLON( rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) POLYURETHANE( R) SBR( n) SBR/NEOPRENE( n) Note: Numbers in parentheses arechemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. r n RR NH rr rr rr NH nn n rr rr nn ------- C) . a. “I. -.1 -1 — .- , — •- ‘I . : Q -.1 0 C. ) -I C) Q 4. . ‘., S .’ ‘I U r co Kerosene d-L i monene Natural Gas, Liquified Ni t robe nzene Styrene 1,2,3,4-Tetrahydronaphtha lene 10$ uene - 1 . a. Ca. n n r nfl N rr rr nn rr nn r., .n NEOP+NAT RUB(nn) NEOPRENE+SBR( n) POLVURETHANE( r) SBR( n) SBR/NEOPRENE( n) rr r rr rr rr n r n N RR NN NN n NN RR N RR TEFLON(rr) NEOP+NAT RUB( n) NEOPRENE+SBR( r) POLVURETHANE( n) SBR( n) VIT/CLORBUTL( rr) SILVERSHIELD( rr) SBR/NEOPRENE( n) n rr r NN FIN NN NN NN rr NN r n TEFLON(rr) SARANEX( nfl) VIT/CLORBUTL( rr) r NN r rr NN FIN nfl NN NN NN NN nfl Hydrocarbons (cont.) Aromatic (cant.) (292) JP—4, Jet Fuel Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. TEFLON( rr) NEOP+NAT RUB( n) POLYURETHANE( r).. SARANEX(NN) SBR( N) VIT/CLOR8UTL( rr) NEOP/NAT RIJB(NN) SI LVERSH I ELD( rr) SBR/NEOPRENE( n) ------- Hydrocarbons (cont.) Aromatic (cont.) (292) Xylene , Q . -J -.1. .- — • . . . * . (4 q . 3d ? • -1 o . . — . , 4 ’ 0 1. 1 :9 > . n TEFLON(rr) NEOP+NAT RUB(NN) SBR( n) NEOP/NAT RUB(NN) m-Xylene NN nn nn rr RR o-Xylene nfl nn nfl rr • rr p—Xylene nfl nn . rr NN rr Note: Numbers in parentheses are chemical class codes -- see Table 8.1. and Appendix B. For explanation of recommendation codes (e.g. RR,H,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. S C -) n n r NN NN NN NN NN RR NN rr -J ‘I ------- Hyd roxyl Compounds Aliphatic & Alicyc/ic, Primary (311) Allyl Alcohol Amyl Alcohol Butyl Alcohol n—Butyl Carbitol Butyl Cellosolve ,— Carbitol Diacetiri 0 lethy lam I noethanol Ethanol, 30-70% Ethanol, >70% Ethanol amine RR rr rr rr R r rr RR ‘I / C, ‘ .1 ( TEFLON( rr) SARANEX( rr) NEOPRENE+SBR( A) POLVURETHANE( A) SBR( K) SBR/NEOPRENE( A) TEFLON( rr) NEOP+NAT RUB(nn) NEOPRENE+SBR( n) POLYURETHANE( r) SBR( n) SBR/NEOPRENE( n) n NAT+NEOP+NBR( r) rr rr rr r n KR RR KR rr rr n KR ,n n NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) rr r NN NN NN NN NN n NAT+NEOP+NBR( R) Note: Numbers in parentheses are chemical class codes -- see Table 8:1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. Ethyl Cellosolve rr nn NN rr rr r NN AR NN nn nn rr NN rr r nn KR nn RR RR nfl no r r r r NH rr rr r r r r no rr rr ------- -I Hydroxyl Compounds (cont. A/iphatic & A//cyclic, Primary (cont.) (311) Ethyl Alcohol R . 4. Q -.1 -J — — A2: . , ; — .-. * * 1 4. 31 ‘ () -.1 ‘. C ) • . 4. 4. . . . 0 — . 4 NN NN nfl RR NM rr NN r C, -.1 // Ethylene Chlorohydrin 2-Ethyl-1-Hexano l Glycols Hexyl Alcoho.l Isobutyl Alcohol Methanol r r r rr rr rr rr rr r nfl rr rr rr NM NM nfl NN rr rr n rr rr r r NN NN RR NM n NN rr r NEOP+NAT RIJB( r) SBR( r) nfl NN NN nfl rr TEFLON(rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( r) NAT+NEOP+NBR( r) POLYURETHANE( r) SARANEX( rr) SBR( R) VIT/CLORBUTL( rr) NEOP/NAT RUB(NN) PV ACETATE( rr) SBR/NEOPRENE( r) Methanol, <30% Methanol, >70% rr rr Note: Numbers in parentheses are chemical class codes see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. cZD TEFLON( rr) NEOP+NAT RUB(nn) NEOPRENE+SBR( r) POLYURETHANE( n) SBR( n) NEOP/NAT RUB(rr) SBR/NEOPRENE( r) ------- -I Hydroxyl Compounds (cont. Aliphatic & AIicycIic Primary (cont.) (311) Methyl Cellosolve rr 1 —Octanol r ,0 * d i j -J -I .- — .- -. * * n R r nn -I • .1 4. 4. 4.4; * S _ I C ) -.. . 4. . R r -I ‘I NEOP+NAT RUB(nn) NAT+NEOP+NBR( r) POLYLJRETHANE( n) S8R( n) SBR/NEOPRENE( n) Q n-Octariol r Propyl Alcohol r 2,2, 2-Trichloroethanol Tnt’ luo roe tha no Aliphatic & 4licyclic, Secondary (312) Cumene Cyci ohexano I 2—Furylmethanol Isopropyl Alcohol lsopropyl Chloride Lactic Acid r nn RR rr RR rr RR r. nn RR MN RR NN n nfl rr rr NN RR MN r POLYURETHANE( n) SBR( R) SBR/NEOPRENE( r) r r TEFLON(rr) NEOPRENE+SBR( r) POLYURETHANE( r) SBR( r) PV ACETATE( rr) SBR/NEOPRENE( r) SARANEX(nn) NEOP+NAT RUB( rr) NEOP/NAT RUB(rr) rr r n r r NN NN nfl RR rr RR rr RR r SILVERSHIELD(nr) n r rr rr r NM RR nfl RR MN nn r r CHLOROBUTVL( rr) TEFLON(RR) NEOP+NAT RUB(NN) NAT+NEOP+NBR( r) SBR( r) NEOP/NAT RUB(nn) r r R r r R R R R R r .r Note: Numbers in parentheses are chemical class codes -- see Table For explanation of recommendation codes (e.g. RR,R,NN, etc.) Source: Arthur D. Little, Inc. 8.1 and Appendix B. see Table 8.3. ------- Hydroxyl Compounds (cont.! Aliphatic & Al/cyclic, Tertiary (373) Lactic Acid, <30% Lactic Acid, >70% tert—Butanol rr Citric Acid r Citric Acid, <30% Diacetone Alcohol r Terpineol O Aliphatic & Al/cyclic, Polyols (314) Diethylene Glycol Di isopropy.l Ketone Ethylene Glycol Glycerol r Phenolphthalein Propylene Glycol 1 (5 , -I NN R -J -I — r r rr rr •rr rr rr rr rr r NN rr R. R R R rr rr rr rr rr nfl rr n r R r R r r n R r r RR rr RR RR RR rr nfl r r R r R r r rr rr rr rr rr rr RR rr r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. / r r -J ‘I NEOP+NAT RUB( NEOPRENE+SBR( P OLVURETHANE( SBR(, l )’ SBR/NEOPRENE( r POLYURETHANE( n) SBR( r) SBR/NEOPRENE( r) r) r) R) r) fl r n r r TEFLON(rr) NEOP+NAT RIJB(RR) NEOPRENE+SBR( n) POLYURETHANE( r) SBR( R) NEOP/NAT RUB(rr) SBR/NEOPRENE( r) r NEOP+NAT RUB( r) POLYURETHANE( n) SBR( R) SBR/NEOPRENE( r) NEOP/NAT RUB(rr) ------- a. i ’d -J -J — — , -.1 0 C.) -.1 w -. — * i’d a. . a. i ’d . a. (I rr r r R r r r r n r N rr r R rr nfl rr rr rr n r r nn r rr rr NN rr NN R nfl NN rin n NN rr nfl rr RR NN fin NN rr r. R R r R ‘4 , C -, — . a. . a C., -.1 ‘S R rr r POLVURETHANE( n) SBR( R) SBR/NEOPRENE( r) r r r rr r SBR( r) rr NN TEFLON(rr) NEOP+NAT RIJB(nn) NEOP/NAT RUB(rr) fl n SARANEX( rr) r rr NN n TEFLON(rr) NEOP+NAT RUB(rr) NAT+NEOP+NBR( r) POLYIJRETHANE( r.) SBR,( n) NEOP/NAT RUB(rr) SBR/NEOPRENE( r) NN RR n r r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. Hydroxyl Compounds (cont. Aromatic (316) Benzyl Alcohol Benzyl Benzoate n-Butyl Benzoate Creosote Creosote, Wood m-Cresol Creso Is Ethyl Benzoate I- . Nonylphenol Pentachloropheno I Phenol Phenol, <30% Phenol, >70% Picric Acid ------- Inorganic Acids Inorganic Acids (370) Boric Acid Chlorosulfonic Acid Chromic Acid Chronic Acid, <30% Chromic Acid, 30-70% Fluoroboric Acid Fluorosilicic Acid Hydrobromic Acid Hydrobrornic Acid, 30-70% Hydrochloric Acid Hydrochloric Acid, <30% rr rr -J S rr n rr n r NN N RR N rr RR r ‘4 , r rr 4. -.1 .- A. 4, 1. 4. A. 0 POLYURETHANE( n) SBR( r) SBR/NEOPRENE( r) CHLOROBUTYL( rr) TEFLON(nn) NEOP+NAT RUB(rr) NEOPRENE+SBR( n) NAT+NEOP+NBR( r) POLYCARBONAT( rr) POLYURETHANE( n) SARANEX( rr) SBR( r) NEOPRENE+PVC( rr) SBR/NEOPRENE( n) NEOP+NAT RUB(rr) SBR( r) NEOP/NAT RUB(rr) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN,, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. n n r n n nfl r r r r r R r R r r nfl rr rr rr RR RR rr NN rr rr r RR rr rr rr rr n rr r n n SARANEX(rr) NEOP+NAT RUB(rr) r ------- I Inorganic Acids (cont.) Inorganic Acids (cont.)(3?O) Hydrochloric Acid, 30-70% r Hydrochloric Acid, >70% Hydrofluoric \cid Hydrofluoric Acid, <30% Hydrof’Iuoric Acid, 30-70% 0 0 ’ Hydrofluoric Acid, >70% Iodine Pentafluoride Nitric Acid r RR RR n RR nn rr nn r rr N N n n rr r R r r RR rr NN nn rr rr n n rr rr n rr nfl n rr ‘I -1 , ; S. * ‘ () ..I Cj • . . q q , 0 ,. 5- . . C, ‘4 , S. 0 n fin rr r NEOP+NAT RUB(rr) SARANEX(rr) NEOP/NAT RUB(RR) S ILVERSHIELD(rr) NEOP+NAT RUB( rr) NEOP/NAT RUB( rr) MN rr rr NEOPRENE+SBR( n) POLYCARBONAT( rr) POLYURETHANE( n) SARANEX( rr) SBR( n) NEOPRENE+PVC( rr) SBR/NEOPRENE( n) NAT+NEOP+NBR( r) r r NEOP+NAT RUB(RR) SARANEX( nfl) SBR( ‘r) NEOP/NAT RUB(rr) NEOP+NAT RUB(rr) NEOP/NAT RUB( rr) n CHLOROBUTYL( rr’) TEFLON(nn) NEOP+NAT RUB( rr) NAT+NEOP+NBR( r) POLVURETHANE( n) SARANEX( rr) SBR( n) SILVERSHIELD( rr) NEOPRENE+PVC( rr) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. - r n nn NM rr rr ------- Inorganic Acids (cont.) Inorganic Acids (cont.) (370) Nitric Acid, <30% 0 -d I’ 1 -4 — * ‘4. I C) — 4. Nitric Acid, 30-70% rr n nn n rr r Nitric Acid, >70% n n on n NN nfl nn n NN rr Nitric Acid, Fuming Red no no rr ‘ rr rr NN NN rr Perch loric Acid r r N rr rr Perch loric Acid, 30—70% n rr r rr n rr Phosphoric Acid r rr rr rr rr rr n rr rr rr C. , -4 NEbP+NAT RUB(rr) NAT+NEOP+NBR( r) SBR( r) NEOP/NAT RUB(rr) NEOP+NAT RUB(rr) SARANEX( rr) NEOP/NAT RtJB(rr) SARANEX( rr) SBR( r) NEOP/NAT RUB(rr) CHLOROBIJTYL( rr) TEFL ON(nn) NEOP/NAT RUB(rr) SILVERSHIELD(nn) rr r r NEOPRENE+SBR( n) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) NE0PI NAT R1i ( r) NEOPRENE+SBR( n) NAT+NEOP+NBR( r) POLYLJRETHANE( n) SARANEX( rr) SBR( r) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. ‘For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table’ 8.3. Source: Arthur D. Little, Inc. ------- . ‘I -I — # ; — l id 4. -I 0 () -.j C, 4. 4. 4 0 . - ‘ . -. Inorganic Acids (cont.) Inorganic Acids (cont.)(370) Phosphoric Acid, <30% Phosphoric Acid, 30-70% Phosphoric Acid, >70% Phosphorus Oxychloride 0 cc ’ r r r r r r RR rr rr rr rr r r r rr r NN nfl nn NN nn Phosphorus Trichioride r Sulfuric Acid n RR rr N rr nfl n rr NN rr rr Sulfuric Acid, <30% r r r R rr R RR rr r Sulfuric Acid, 30—70% r rr rr rr rr rr rr r Sulfuric Acid, >70% r r n n nfl N RR n NN Sulfur Monochloride r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. rr r n NEOP+NAT RUB( rr) NEOP/NAT RUB( rr) NONWOVEN PE(NN) SARANEX( nfl) PV ACETATE(NN) CHLOROBUTYL( rr) TEFLON(nn) NEOP+NAT RUB(rr) NEOPRENE+SBR( n) NAT+NEOP+NBR( n) POLYURETHANE( n) NONWOVEN PE(NN) SARANEX( RR) SBR( n) VIT/CLORBUTL( rr) SILVERSHIELD( rr) NEOPRENE+PVC( rr) SBR/NEOPRENE( n) NEOP+NAT RUB( r) NAT+NEOP+NBR( r) NONWOVEN PE(nn) SARANEX( rr) SBR( r) NEOP+NAT RLJB(rr) NONWOVEN PE(NN) SARANEX( rr) NEOP/NAT RUB(rr) TEFLON( rr) NONWOVEN PE(NN) SARANEX( rr) SBR( r) NEOP/NAT RUB(rr) /.- -lii 4. -d I. -I ‘I ------- , 4. i — — 41 * * 4. ‘3 ’ ., . . 4. 0 . 4. ! - . , 4 ’ 0 ‘ > . Inorganic Bases Inorganic Bases (380) Ammonium Hydroxide Aminonium Hydroxide, <30% Ammonium Hydroxide, 30—70% Calcium Hydroxide Potassium Hydroxide r Potassium Hydroxide, <30% Potassium Hydroxide, 30-70% I- Sodium Hydroxide Sodium Hydroxide, <30% Sodium Hydroxide, 30-70% R r rr rr NN rr NN n NN r RR ‘RR RR NN rr rr rr r rr NN R r r R R r R R n r r r r r RR RR RR RR rr n RR n rr R R rr R rr rr rr rr r rr RR RR RR RR RR n RR RR rr Note: Numbers in parentheses are ôhemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, lnc ‘A 41 4. 0 C.., -.1 NEOP+NAT RUB(nn) NEOPRENE+SBR( r) POLYIJRETHANE( r) SBR( R) SBR/NEOPRENE( r) NEOPRENE+SBR( r) POLYURETI-IANL( n) SBR( r) SBR/NEOPRENE( r) r NEOP+NAT RIJB(rr) SBR( r) POLYIJRETHANE( r) SBR( r) VIT/CLORBUTL( rr) SILVERSHIELD( rr) SBR/NEOPRENE( r) NEOP+NAT RUB(rr) TEFLON( rr) NAT+NEOP+NBR( r) NONWOVEN PE(NN) SARANEX( RR) SBR( r) NEOP/NAT RUB(rr) NEOPRENE+PVC( rr) ------- , 4, -d .- , ; ‘41 •s * * 4, -I — 5. ‘4, ‘3’ 0 : Sd w . ‘ 41 ‘U n r NN n r rr n rr fl NN n r r rr r nfl NN r r n R r r r r r n nfl rr n .5, ‘5 ’. N. ‘4, 4.4; .4 - .5 . 4. . rr rr SARANEX(rr) R POLYURETHANE( 11) SBR( r) SBR/NEOPRENE( n) r n r •NN rr n f l nfl nfl r n r r r fl rr nn nn n CHLOROBtJTYL(rr) TEFLON( NN) CR 39(rr) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. Inorganic Gases Inorganic Cases (350) Ammonia Bromine Chlorine F I uo r ne Hydrocyanic Acid Hydrogen Phosphide Hydrogen Sulfide Nickel Carbonyl Nitric Oxide Nitrogen Dioxide Nitroger Tetroxide ------- Inorganic Salts Inorganic Salts (31,0) Ammonium Fluoride Ammonium Fluoride, 30-70% Ammonium Sulfate Arsenic Trichloride Bromine Trifluoride Calcium Chloride Calcium Hypochlorite r r r n n . 4. 1 L * 1 41 -J 4.. 4, .- * * l -.1 — . 2 -S £4 , ‘51 . 0 0 -I w . . rr rr R R .r r R R r r R R r r rr rr R R R n n 4 , * * 5> C) ‘ 4. . 4 POLYURETHANE( R) SBR( r) SBR/NEOPRENE( r) POLYURETHANE( SBR( r) SBR/NE OPRENE( POLYtJRETHANE( SBR( n) SBR/NEOPRENE( P OLYURETHANE( POLYURETHANE( SBR( r) POLYURETHANE( r) SBR( n) SBR/NEOPRENE( n) POLYURETHANE( r) SBR( n) SBR/NEOPRENE( n) POLYURETHANE( r) SBR( r) SBR/NEOPRENE( r) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g..RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. Copper Chloride n r r r Copper Sulfate n R r R Cupric Chloride r n R r R Cupric Sulfate r n R r r R Ferric Chloride r r R r R C, -I ‘I NEOP+NAT RUB( r) r) r) r). ti) r) r) ------- cJ_ . r r r r r . a. ‘V •.1 -.1 — 5- 5- , â S ., w i 4 . , a 0 . ! . > — . r r r n r rr rr rr rr rr r r r r r r R r R nn NN NN rr MN RR rr MN n rr rr RR nfl RR r S . , // Inorganic Salts (cont.) Inorganic Salts (cont.)(340) Potassium Dichromate r r R r R POLYURETHANE( ii) SBR( r) SBR/NEOPRENE( r) Potassium Bromide Potassium Chloride Potassium Cyanide Silver Nitrate Sodium Chloride Sodium Hypochlorite, 30-70% Sodium Silicate Sodium Sulfide Sodium Thiosulfate NJ Stannous Chloride Isocyanate (210) Methyl Isocyanate Toluene Di isocyanate Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. I socyanates. POLYURETIIANE( r) SBR( r) SBR/NEOPRENE( r) TEFLON(RR) SILVERSHIELD(RR) ------- -J - , -.. * ‘I 4. 1 0 C., -.1 .w • . 4. . a. * -.. . . , y 0 , . “.. , a . C .) RR NN NN NN nn NN NN NN NN NN rr n n nn r n r R r n n nn nn n rr NN rr RR RR n nfl n rr rr r 1 ‘I TEFLON( rr) NEOP+NAT RUB(NN) NEOPRENE+SBR( n) NAT+NEOP+NBR( r) POLVURETHANE( r) SARANEX( nn) SBR( n) VI T/CLORBLITL( nn) NEOP/NAT R(JB(NN) PV ACETATE( rr) SILVERSHIELD( rr) SBR/NEOPRENE( n) rr n nfl n NEOP+NAT RUB(nn) SILVERSHIELD( rr) R r POLYURETHANE( fi) SBR( r) SBR/NEOPRENE( r) RR S ILVERSH IELD(rr) rr rr nn N r r VIT/CLORBUTL( rr) n Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR ,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. a. -.1 / Ke tone s Aliphatic & Al/cyclic (391) Acetone Cyc lohexanone Diacetone Alcohol Diisobutyl Ketone Diisobutyl Ketone, >70% I sophorone Mesityl Oxide L4-Methoxy-4-methyl-2-pentanone Methyl n-Butyl Ketone ------- Ketones (cont.) Aliphatic &Aliöyclic(cont.)(39/) Methyl Ethyl Ketone Methyl Isobutyl Ketone Methyl-vinyl-ketone N-Methyl-2-pyrrol idone AI/cyl-AryI (393) Acetbphenone Lactones Lactones (1100) beta-Prop iolactone / 0 -1 - .1 w .- “ . . — 4. 4. 4. RR nfl MN NN NN MN NN MN nn MN NM NN MN n n NN •NN nfl NM NN rr nfl nfl nfl NN NM NN MN n rr nn nn nn MN nn nfl C, -.1• Q 0 CHLOROBUTYL( rr) TEFLON(nn) NEOP+NAT RUB( MN) NEOPRENE+SBR( n) POLYURETI-IANE( r) SARANEX( NM) SBR( r) VIT/CLORBUTL(nn) NEOP/NAT RUB(NN) SBR/NEOPREME( n) n TEFLON(rr) NEOP+NAT RUB( n) SBR( r) VIT/CLORBUTL( rr) r TEFLON(rr) POLYURETHAME( NM) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- Miscellaneous Miscellaneous (560) Aspha I t Mercury Mineral Oil 4. .J -.1 -S -S -4 -S • . 1 . . . .4. 4. r r r C I— . I-s Li ’ Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation 7 f recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. C, 0 -J .5 -S 4. . n r r n C) / ------- Nitri les Aliphatic & AIicyc/ic (1j31) Acetonitrile Bromoacetonitri le Chioroacetonitri le Ethyl Cyanide Isoamylnitrile °.‘ Methacrylonitrile Trichloroacetoni tn le Va leronitni le Aromatic (432) Benzonitni le Acrylonitri le ,... ‘I C., RR rr nfl NN NN n nfl N r n n NN NN NN nfl NN rr NN rr rr rr NN nfl rr NN nfl rr rr rr ‘4’ ...d ..- A2 S . £Q iS’ . C) ._/ .W . . .-. 4. .4. - q i 0 ; , . . 4) NN NN rr NN rr rr N n rr rr rr rr rr NN rr rr nfl NN rr rr rr rr nn ‘C-, -I SW -S 0 TEFLON( rr) NEOP+NAT RUB( r) SARANEX( rr) VIT/CLORBUTL( rr) SILVERSFIIELD( rr) TEFLON(nn) NEOPRENE+SBR( n) POLYURETHANE( r) SARANEX( nfl) SBR( n) SBR/NEOPRENE( n) Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. S 4. ¼ . -J / ------- . Q . - -J . ‘. o C., 4 ! ‘ Q . , 1’ c N .‘- o Nitro Compounds Unsubstituted (441) Nit robenzene rr rr NN NN n NN RR N RR Nitroethane rr n NN nn rr Nitroglycerine r r Nitromethane rr NN rr nfl rr UN n n Nitropropane RR n no NN UN NN NN on nn 1-Nitropropane rr • no rr I- -.j 2-Nitropropane - Nitrotoluene rr UN nn r rr r o-Nitrotoluene no . p-Nitrotoluene rr 2,4,6-Trinitrotoluene n • N N r R Substituted (442) 2-Chloro-2-nitropropane rr NN rr no n-Nitrosodimethylamine nn : Picric Acid r R R r. R n r r Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur 0. Little, Inc. TEFLON( rr) NEOP+NAT RtJB( n) NEOPRENE+SBR( r) POLYURETHANE( n) SBR( n) VIT/CLORBUTL( rr) S ILVERSHIELD(rr) SBR/NEOPRENE( n) r NEOP+NAT RUB( r) POLYURETIIANE( nn) SILVERSH IELD(rr) nn TEFLON(rr) POLYLJRETHANE( n) SBR( r) SBR/NEOPRENE( r) POLYCARBONAT( rr) POLYURETHANE( n) SBR( n) SBR/NEOPRENE( n) -.1 .4-. 4 ------- rr rr rr r (1 r r rr r r nfl nn r C) . 4. 1 ‘.1 -J — -. , -I 0 c C) Sd ‘ . — 5- * * ‘I 4. •. 4. rr n fl r r rr n rr RR rr rr r NEOPRENE+SBR( n) POLYIJR [ THANE( n) SBR(. n) SBR/NEOPRENE( r) r 1 ; IF Organic Salts Organic salts (.550) Benzethonium Chloride Organo-Metal I ic Compounds Organo-Metallic Compounds (461) Titanium Tetrachioride Triethyl Aluminum Trioctyl Phosphine Organo-Phosphorous Compounds • Organo-Phosphorous Compounds (460) Tributyl Phosphate Tricresyl Phosphate I- ’ Triisooctyl Phosphate Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and Appendix B. For explanation of’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- Perox ides . 41 -, - -. — ‘4 1 . 41 q .d , .-‘ : . Perox ides (300) a lpha,alpha-Dimethylbenzyl Hydroperoxide . Hydrogen Peroxide nn rr r r R r n Hydrogen Peroxide, <30% Hydrogen Peroxide, 30-70% RR NN rr rr n rr Hydrogen Peroxide, >70% r Methyl Ethyl Ketone Peroxide rr nn rr Quinones -. 4 ‘ O Quinones (490) Hydroquinone n R R rr r rr n rr Hydroquinone, <30% rr rr rr rr ‘I 4 . _i (1 — . . . -1 ‘I TEFLON( rr) nn r r TEFLON(rin) NEOP+NAT RUB( r) NEOPRENE+SBR( r) POLYURETHANE( r) SBR( r) SBR/NEOPRENE( r) CHLOROBUTYL( rr) NAT+NEOP+NBR( r) NEOP+NAT RUB( rr) POLYURETHANE( r) SBR( r) NEOP/NAT RIJB(rr) n rr r SBR( r) Note: Numbers in parentheses are chemical class codes -1— see. Table 8.1 and Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Source: Arthur D. Little, Inc. ------- .4-. ‘4I 0 nfl NN NN SI ‘ 41 -J 0 — w — ‘41 . n n r rr r N N fi NN NN RR N RR rr RR RR rr nn rr NN rr rr rr rr rr r n fl n r n I 0 Sulfur’ Compounds Thiols (501) tert-Butyl Mercaptan Ethyl Mercaptan Thionyl Chloride Th iophenol Sulffcles& Oisu/f’ides (502) Calcium Bisulfate, 30-70% Carbon Disulfide SuIf’oxides (503) Dimethyl Sulfoxide 0 Sulfonic Acids (504) Methanesulf’onic Acid p-Toluenesulfonic Acid Others (507) DisulfurDichioride Note: Numbers in parentheses are chemical class codes -- see Table 8.1 and’ Appendix B. For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. ‘0 Source: Arthur 0. Little, Inc. TEFLOt’l(nn) NEOP+NAT RUB(NN) POLYURETHANE( n) SBR( N) VI T/CLORBUTL( NN) SBR/NEOPRENE( n) ,VIT/CLORBUTL( rr) NEOP/NAT RUB(rr) 0 ------- MATRIX B RECOMMENDATIONS BY CHEMICAL CLASS 121 ------- Acids, Carboxylic, Aliphatic Unsubst I tuted Pa lybas Ic Al dehydes Am ides Aliphatic and Alicyclic Aromatic and Hetrocyci ic -J .4- . c? . — , .& - , . s ... c -.1 •* t Q 0 \ ‘ -.1 .- * -. 1 • S. ** rr ** rr NN rr rr rr rr RR NN r ** NN rr n nfl nfl ** ** ** p n rr nn NN ** NN NN ** fl nn NN rr N r r Cyan ides Am ides Amines, Aliphatic &Alicyclic Primary Secondary Tertiary Pot yam me Cyan ides Esters, Carboxyl ic 10 rma te S Aceta tes Higher Monobasic Potybas Ic Aromatic Phthalates Ethers Al iphatic nfl nn nn rr nn ** ** ** ** NN ** n ** ** ** ** rr nfl NN rr n nn nn NN nfl nn r ** ** ** ** ** ** NN NN ** NN rr NN rr nfl ** ** fl n ** ** r rr r ** Note: For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Class recommendations only for chemicals classes in which two or more chemicals have recommendations for a given material. Double asterisks (**) indicate a wide variation in ratings. Source: Arthur D. Little, Inc. R r r Si ‘I nfl ** rr ** nfl ** ** n NN ** ** n NN ** ** ** ** NN ** ** ** n NN fin nfl ** NN r r rr r ** r n ** rr ** NN ------- • . . ¼ . ..-. 0 â -I .- ... 0 -I w ... .,- . 41 I o 4. . Halogen Compounds Al iphatic, Unsubstituted Aliphatic, Substituted Aromatic, Unsubstituted Pal ynuc lear Vinyl Halides Heterocyci ic Compounds Epoxy Compounds Furan Derivatives Hyd raz i nes Hyd raz i nes Hyd roca rbons Aliphatic &Alicyclic Aromatic Hydroxyl Compounds Aliphatic & Alicyclic, Al iphat I C & Al icyclic, Al iphat ic & Al icyc I ic, Aliphatic & Alicyclic, Aromatic Primary Secondary Te rt i a ry Pa lyo Is no nfl r NN ** NN nfl nfl r N NN •nn NN rr NN NN nfl n nn NN NN ** NN ** NN N ** rr rr rr n rr ** nn no NN 3I no NN nn nn NN nn n nn n ** nn * fl N r r NN ** ** ** * NN RR n rr r NN NN NN ** NN NN RR RR rr r r ** rr rr no rr r ** ** nfl ** ** rr rr rr rr ** rr rr rr rr r ** ** ** ** ** ** rr ** rr ** rr r ** ** ** flfl ** rr r Inorganic Acids Inorganic Acids ** ** rr ** ** ** ** ** n. ** rr ** Note: For explanation of’ recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Class recommendations only for chemicals classes in which two or more chemicals have recommendations for a given material. Double asterisks (**) indicate awide variation in ratings. Source: Arthur D. Little, Inc. -1 -y ‘S n n ------- C., . . ‘ ‘I -J ‘.1 . ...I 0 c Cj -S -. , -S — . * a. S _ I C . a. •a. r r RR RR ** RR ** n ** rr r ‘ r n n r *4+ ** ** *4+ r n r r r R • NN n rr * NN n NN NN N ** NN * NN NN rr NN NN rr NN rr rr r NN *4+ *4+ *4+ *4+ r *4+ I., A. Inorganic Bases Inorganic Bases Inorganic Gases Inorganic Gases Inorganic Salts Inorganic Salts Isocyanates I socyanates Ketones, Al iphatic l(etones, Al iphatic Nitriles, Aliphatic Nitriles, Aliphatic Nitro Compounds tJnsubst i tuted Organo—Phosphorous Compounds Orgno-Phosphorous Compounds Peroxides Perox ides Sulfur Compounds Th 101 5 Note: For explanation of recommendation codes (e.g. RR,R,NN, etc.) see Table 8.3. Class recommendations only for chemicals classes in which two or more chemicals have recommendations fora givenmaterial. Doubleasterisks (*4+) indicateawidevariatiOfi in ratings. Source: Arthur D. Little, Inc. r r n ------- APPENDIX A GLOSSARY A-i ------- GLOSSARY -- Polymer.of acrylonitrile, butadiene, and styrene; a strong, rigid material used for structural components. Acetate - - Polymer of’ cellulose acetate; a clear, relatively inexpen- sive material used for face and eye protection. Acrylic -- Polymer of methyl methacrylate; clear plastic used for face and eye protection. Baypren -- See Neoprene. Blend -- An intimate mixture of two or more materials. Breakthrough Time - - The time elapsed between initial contact of a chemical with the outside surface of a protective clothing material and the time at which the chemical can be detected at the inside surface of the material.. Measured breakthrough times are dependent on the sensi- tivity of the analytical methods used to detect the chemical and the experimental procedures. Butyl Rubber - - Copolymer of isobutylene and a small amount. of isoprene. Material has good resistance to weathering and a wide variety of chemicals. Both supported and unsupported forms of butyl rubber are used as protective clothing. Cellulose Propionate - - Polymer; clear plastic used for face and eye protection. Chlorinated Polyethylene - - CPE, Chloropel . A polyethylene elastomer with a chlorine content of 36% to 45%. The material generally has better chemical resistance and physical properties than polyethylene. Chiorobutyl Rubber - - A chlorinated form of butyl rubber. Generally has better heat than butyl rubber. ‘ Chioroprene Rubber - - See Neoprene. Chiorosuiphonated Polyethylene - - See Hypalon . Contamination - - The presence of potentially harmful chemicals on the surface of or within the polymer of CPC. Copolymer - A long chain molecule synthesized by reaction of more than one monomer species with each other. Copolymérs often have cost and/or performance advantages over polymers produced from a single monomer species. A- 2 ------- CPE - - See Chlorinated Polyethylene. CR-39 -- Polymer of allyldiglycol carbonate. A clear, impact resis- tant plastic used for face and eye protection. Decontamination - - The removal of potentially harmful chemicals from the surface of and from within the polymer of CPC. Note surface decontamination does not necessarily remove absorbed chemical. Degradation - - The loss in physical properties of an item of protective clothing due to exposure to chemicals, use, or ambient conditions (e.g., sunlight). Ethylene Vinyl Alcohol - See EVOH. EVALN - - See EVOH. EVOH -- Polymer of ethylene vinyl alcohol. This polymer exhibits a high resistance to non-polar organic compounds. However since it is susceptible to attack by acids, bases and water, it is used as an internal layer in laminates. S FEP -- Polymer of fluorinated ethylene propylene. Polymer with exceptionally good chemical resistance with protective clothing appli- •cations in both film and coating form. Flock-lined or Flocked -- A layer Of fibers, typically cotton, adhered to the inside of rubber gloves. The lining absorbs perspiration and provides some insulating effect. Gore TexN Fabric - - A proprietary fabric in which microporous PTFE is laminated on one or both sides with a fabric. The fabric allows the transmittance of moisture vapor which reduces heat stress. It prevents penetration by many liquids and solids but does not provide vapor protection. Hypalon - - - Polymer produced by the post chlorination and sulfonation of polyethylene, thereby producing a rubbery material suitable for CPC. Laminated -- Joining two or more sheets or fabrics together by means of ieat or adhesive. Latex - - A stable dispersion of polymer or rubber particles in water. Latex gloves and coated fabrics are prepared by coagulating and cross- linking the particles Son a form or cloth substrate. Most natural rubber, neoprene, and nitrile gloves are prepared from. latices. - Latex-Dipped - - A glove prepared by dipping a glove form or a fabric glove into a rubber latex bath. In one dip, the entire amount of rubber that will form the glove is deposited. A- 3 ------- Natural Rubber -- Polyisoprene obtained from rubber plants. A highly flexible and conforming material used principally for gloves. High elasticity. Neotrene - - Polychloroprene. A synthetic rubber having chemical and wear resistance properties that are generally superior to those of natural rubber. NBR (Nitrile-Butadiene Rubber ) - - See Nitrile Rubber. Nitrile Rubber -- Copolymer of acrylonitrile and butadiene. Also known as acrylonitrile rubber, acrylonitrile-butadiene rubber, Buna-N, and nitrile-butadiene rubber (NBR). Trademark names include Hycar , Kyrnac tm , and ParacrilN. Used for supported and unsupported gloves and coated fabric. Nitrile rubbers are available in a wide range of acrylonitrile concentrations. In general, the higher the acrylonitrile concentration the better the chemical resistance. However, stiffness also increases at higher acrylonitrile concentrations. - - See Polyethylene. Penetration -- The movement of chemical through zippers, stitched seams or imperfections (e.g., pinholes) in a protective clothing material. Permeation - - The process by which a chemical dissolves in and moves through a protective clothing material on a molecular level. Permeation Rate - - The rate at which the chemical moves through the clothing material. This is expressed in terms of amount per unit area per unit time. ‘ Polycarbonate -- A hard, transparent plastic used for face and: eye protection. It has, exceptional impact resistance and good chemical resistance, and is commonly used as the lens of safety glasses. Polyester -- A family of polymers that finds application in fiber form as clothing and in film form as a clear material for face and eye protection. Polyethylene - - A fairly chemically resistant material that is used as a freestanding film (e.g., apron) or a fabric coating. Low density polyethylene is the most common form used in protective clothing. Polyurethane -- An extensive and multi-branched family’ of polymers based on isocyanates. As used in protective clothing, polyurethanes are rubbery polymers that are either coated onto fabrics or formed into boots. A- 4 ------- • Polyvinyl Alcohol - - A water-soluble polymer that, as long as it is dry, exhibits exceptional resistance to many organic solvents that rapidly permeate most rubbers. The material is somewhat stiff, thus limiting dexterity. PU - - See Polyurethane. - - See Polyvinyl Alcohol. - - See Polyvinyl Chloride. PVDC -- Polymer of polyvinylidene chloride. Polyvinyl Chloride -- A stiff polymer that is made suitable for protec- tive clothing applications by the addition of plasticizers. Used as a freestanding material for gloves, aprons, etc., as well as coatings for fabrics. Clear forms are also available as flexible face shields. Safeguard CPF -- A proprietary non-woven fabric for limited use (i.e., disposable) clothing. Saran - - See PVDC. Saranex® - - Multi-layer laminate of polyethylene and Saran . Solvent-DilDed - - A glove prepared by repeatedly dipping a glove form or glove substrate into a solution of the rubber in a solvent. The rubber is subsequently cured. Sontara® -. Proprietary spun-laced, limited use fabric. SBR (Styrene-Butadiene Rubber ) -- Also known as Buna-S. Trademark names include Solprene , Plioflex tm , and Stereon . Used for fabric coatings and boots. SupDorted - - Materials containing a substrate such as cotton, polyester or nylon fabric or scrim which is coated, laminated or impregnated with a polymer or rubber. TFE (PTFE ) - - Polytetrafluoroethylene. An example is Teflon®. Tyvek® - - A proprietary, porous non-woven fabric limited use (e.g., disposable) clothing.’ Tyvek® may be coated with polyethylene or Saranex film. Viton® - - A proprietary fluoroelastomer. Highly chemically resistant, but expensive synthetic elastonier. A-S ------- APPENDIX B CHEMICAL INDEX B—i ------- CHEMICAL NAMES AND SYNONYMS NAME: Acetaldehyde CASNO: 00075070 SYN: • . CLASS: 121 NAME: Acetainide CASNO: 00060355 SYN: CLASS: 132 NAME: Acetic Acid CASNO: 00064197 SYN: CLASS: 102 NAME: Acetic Acid, <30% CASNO: 00064197 SYN: . CLASS: 102 NAME: Acetic Acid, 30-70% . CASNO: 00064197 SYN: . CLASS: 102 NAME: Acetic Acid, >70% • CASNO: 00064197 SYN: CLASS: 102 NAME: Acetic Anhydride CASNO: 00108247 SYN: CLASS: 161 NAME: Acetone . CASNO: 00067641 SYN: • CLASS: 391 NAME: Acetone Cyanohydrin CASNO:. SYN: (See 2-Methylactonitrile) CLASS: NAME: Acetonitrile CASNO: 00075058 SYN: CLASS: 431 NAME: Acetophenone CASNO: 00098862 SYN: . CLASS: 393 NAME: Acetyl Bromide CASNO: 0050696.7 SYN: CLASS: 111 : NAME: ‘Acetyl Chloride CASNO: 00075365 SYN: CLASS: 111 NAME: Acetylene. CASNO: 00074862 SYN: CLASS: 291 B— 2 ------- CHEMICAL NAMES AND SYNONYMS NAME: Acrolein CASNO: 00107028 SYN: CLASS: 121 NAME: Acrylamide CASNO: 00079061 SYN: Propenearnide, 2 CLASS: 132 NAME: Acrylic Acid CASNO: 00079107 SYN: CLASS: 102 NAME: Acrylonitrile CASNO: 00107131 SYN; CLASS: 431 NAME: Adipic Acid CASNO: 00124049 SYN: Hexanedioic Acid CLASS: 104 NAME: Alkazene CASNO: 00093527 SYN: Dibromoethylbenzene CLASS: 262 NAME: Allyl Alcohol CASNO: 00107186 SYN: CLASS: 311 NAME: Allylamine CASNO: 00107119 SYN: CLASS: 141 NAME: Allyl Chloride CASNO: 00107051 SYN: CLASS: 261 NAME: Allyl Clycidyl Ether CASNO: 00106923 SYN: CLASS: 275 NAME: Aluminum Acetate CASNO: 08006131 SYN: Burow’s Solution CLASS: 222 NAME: Aluminum Chloride CASNO: 07446700 SYN: CLASS: 340 NAME: Aluminum Fluoride CASNO: 07784181 SYN: CLASS: 340 NAME: Aluminum Hydroxide CASNO: 21645512 SYN: CLASS: 340 B— 3 ------- CHEMICAL NAMES AND SYNONYMS NAME: Aluminum Nitrate CASNO: 13473900 SYN: CLASS: 340 NAME: Aluminum Phosphate CASNO: 07784307 SYN: CLASS: 340 NAME: Aluminum Sulfate CASNO: 10043013 SYN: CLASS: 340 NAME: Aminoethanol,2 CASNO: SYN: (See Ethanólamine) CLASS: NAME: Ammonia CASNO: 07664417 SYN: CLASS: 350 NAME: Ammonium Carbonate CASNO: 10361292 SYN: CLASS: 340 NAME: Ammonium Chloride CASNO: 12125029 SYN: CLASS: 340 NAME: Ammonium Fluoride CASNO: 12125018 SYN: CLASS: 340 NAME: Ammonium Fluoride, 30-70% CASNO: 12125018 SYN: CLASS: 340 NAME: Ammonium Hydroxide CASNO: 01336216 SYN: CLASS: 380 NAME: Ainmonium Hydroxide, <30% CASNO: 01336216 SYN: S CLASS: 380 NAME: Anmionium Hydroxide, 30-70% CASNO: 01336216 SYN: CLASS: 380 NAME: Animonium Hydroxide, >70% CASNO: 013362,16 SYN: CLASS: 380 NAME: Anmionium Nitrate CASNO: 06484522 SYN: CLASS: 340 B—4 ------- CHEMICAL NAMES AND SYNONYMS NAME: Ammonium Nitrate, <30% CASNO: 06484522 SYN: CLASS: 340 NAME:. Ammonium Persulfate CASNO: 07727540 SYN: CLASS: 340 NAME: Ammonium Phosphate • CASNO: 07722701 SYN: CLASS: 340 NAME: SYN: Animonium Phosphate, <30% . . . CASNO: CLASS: 07722701 340 NAME: Ainrnoniurn Sulfate CASNO: 07783202 SYN: . CLASS: 340 NAME: Anthionium Sulfide CASNO: 12135761 SYN: . . CLASS: 340 NAME: SYN: Amyl Acetate . Pentyl Acetate CASNO: CLASS: 00628637 222 NAME: Amyl Alcohol CASNO: 00071410 SYN: Pentanol CLASS: 311 NAME: Aniline . CASNO: 00062533 SYN: Benzainine CLASS: 145 NAME: Aniline, >70% CASNO: 00062533 SYN: . : CLASS: 145 NAME: Antimony Pentachioride CASNO: 07647189 SYN: . . CLASS: 370 NAME: Aroclor . CASNO: SYN: (See Polychiorinated Biphenyls (PCBs)) CLASS: . NAME: Arsenic Trichioride . CASNO: 07784341 SYN: CLASS: 340 NAME: Asphalt CASNO: 08052424 B—5 ------- CHEMICAL NAMES AND SYNONYMS NAME: Aziridine CASNO: SYN: (See Ethylenimine) CLASS: NAME: Benzal Chloride CASNO: SYN: (See Benzyl Dichloride) CLASS: NAME: Benzaldehyde CASNO: 00100527 SYN: CLASS: 122 NAME: Benzainine CASNO: SYN: (See Aniline) CLASS: NAME: Benzendiol,l,3 CASNO: SYN: (See Resorcinol) CLASS: NAME: Benzene CASNO; 00071432 SYN: CLASS: 292 NAME: Benzenesulfonic Acid CASNO: 00098679 SYN: CLASS: 106 NAME: Benzene’sulfonyl Chloride CASNO: 00098099 SYN: CLASS: 505 NAME: Benzenethjo]. CASNO:. SYN: (See Thiophenol) CLASS: NAME: Benzethoniuni Chloride CASNO: 00121540 SYN: CLASS: 550 NAME: Benzidine CASNO: 00092875 SYN: CLASS: 147 NAME: Benzonitrjle CASNO: 00100470 SYN: CLASS: 432 NAME: p-Benzoquinone CASNO: 00106514 SYN: CLASS: 490 NAME: Benzotrichlorjde CASNO: 00098077 SYN: Trichloromethyl-benzene CLASS: 263 B—6 ------- NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: CHEMICAL NAMES AND SYNONYMS 00098884 112 00100516 316 00120514 316 00100447 263 00098873 263 01464535 275 0011191,1 241 262 00542881. 262 241 00117817 226 10043353 370. 07726956 350 Benzoyl Chloride CASNO: .. CLASS: Benzyl Alcohol CASNO: . CLASS: Benzyl Benzoate . CASNO: CLASS: Benzyl Chloride CASNO: Chloromethyl Benzene CLASS: Benzyl Dichloride CASNO: .Benzal Chloride CLASS: 2,2 ’-Bioxirane . CASNO: Erythritol Anhydride CLASS: Bis(2-chloroethoxy) Methane CASNO: . CLASS: Bis(chloromethyl) Ether CASNO: Dichloromethyl Ether,sym- CLA$S: Bis (2- Ethyihexyl) Phthalate CASNO: CLASS: . Boric Acid CASNO: CLASS: Bromine CASNO:. CLASS: Bromine Cyanide . CASNO: (See Cyanogen Bromide) . CLASS: Bromine Trifluoride CASNO: 07787715 . CLASS: 340 Bromoacetonitrile CASNO: CLASS: 00590170 431 B— 7 ------- CHEMICAL NAMES AND SYNONYMS NAME: Bromobenzene CASNO: 00108861 SYN: CLASS: 263 NAME: Bromochioromethane CASNO: ‘00074975 SYN: CLASS: 263 NAME: 2-Bromoethanol CASNO: 00540512 SYN: ‘ CLASS: 262 NAME: Bromomethane CASNO: SYN: (See Methyl Bromide) CLASS: NAME: 4-Bromophenyl Phenyl’ Ether CASNO: 00101553 SYN: . ‘ CLASS: 242 265 NAME: l-Bromo-?-propanol CASNO: 19686738 SYN: CLASS: 262 NAME: 3-Bromo-1-.propanol CASNO: 00627189 SYN: . CLASS:, 262 NAME: Burow’s Solution ‘ CASNO: SYN: (See Aluminum Acetate) CLASS: NAME: Butadiene . CASNO: . 00106990 SYN: ‘ CLASS: 291 NAME: Butane CASN0 00106978 SYN: . CLASS: 291 NAME: Butanediol,l,3 . CASNO: SYN: (See 1,3-Butylene Glycol) CLASS: NAME: Butanethiol, 1 . CASNO: SYN: (See n-ButylMercaptan) CLASS:. NAME: Butanol, 1 ‘CASNÔ: SYN: ‘ (See Butyl Alcohol) , CLASS: NAME: tert-Butanol CASNO: 00075650 SYN: Methylpropanol, 2-,2- CLASS: 313 B—8 ------- CHEMICAL NAMES AND SYNONYMS 00123864 222 00141322 223 00Ô71363 311 00109739 141 00078819 141 13952846 142 00075649 143 00136607 316 00085687 226 00106989 291 NAME: Butanone,2 SYN: (See Methyl Ethyl Ketone) NAME: Butenal, trans-2 SYN:. (See Crotonaldehyde) NAME:. .Butene SYN: NAME: Butoxyethanol, 2 SYN: (See Butyl Cellosolve) NAME: .. Butoxyethylacetate, 2 SYN: (See Butyl Cellosolve Acetate) NAME: Butyl Acetate SYN: NAME: Butyl ‘Acrylate SYN: NAME: Butyl Alcohol SYN: Butanol, 1 NAME: Butylainine SYN: NAME:. iso-Butylamine SYN: •. Methylpropylamine, 2- NAME: sec-Butylamine SYN: NAME: tert-Butylamine SYN: NAME: n-Butyl Benzoate SYN: NAME: ,. Butyl Benzyl Phthalate SYN: CASNO: CLASS: CASNO: CLASS: •CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: .CLASS: CASNO: CLASS: CASNO:. CLASS: CASNO: CLASS:. CASNO: CLASS: CASNO: CLASS: CASNO: CLASS:• B— 9 ------- CHEMICAL NAMES AND SYNONYMS NAME: n-Butyl Carbitol CASNO: 00112345 SYN: CLASS: 311 NAME: Butyl Cellosolve CASNO: 00111762 SYN: Butoxyethanol, 2 CLASS: 241 311 NAME: Butyl Cellosolve Acetate CASNO:’ 00112072 SYN: Butoxyethylacetate, 2 CLASS: ‘222 241 NAME: n-Butyl Chloride CASNO: 00109693, SYN: Chlorobutane,1- CLASS: ‘ 261 NAME: Butylene CASNO 25167673 SYN: , . CLASS: 291 NAME: 1,3 -Butylene Glycol CASNO 00107880 SYN: Butanediol,1,3 CLASS: 314 NAME: n-Butyl Mercaptan CASNO: .00109795 SYN: Butanethiol, 1 CLASS: 501 NAME: tert-Butyl Mercaptan ‘ CASNO: 00075661 SYN: ‘ . . CLASS: 501 NAME: Buty1’ Oleate ‘ CASNO: 00142778 SYN: 0 ‘ CLASS: 223 NAME: n-Butyl Phthalate CASNO: ‘00084742 SYN: CLASS: ‘ 226 NAME: Butyl Stearate’ ‘ CASNO: 00123.955 SYN: CLASS: 223 NAME: p-tert-.Butyl•Toluene CASNO: 27130212 SYN: CLASS: 292 NAME: Butyraldehyde CASNO: 00123728 SYN: CLASS: 121 NAME: Butyric Acid’ CASNO: 00107926 SYN: CLASS: 102 NAME: Calcium Bisulfate, 30-70% CASNO: 13780035 SYN: . ‘ CLASS: 502 B— 10 ------- CHEMICAL NAMES AND SYNONYMS NAME: Calcium Chloride CASNO: 10043524 SYN: . CLASS: 340 NAME: SYN: Calcium Hydroxide . CASNO: CLASS: 01305620 380 NAME: Calcium Hydroxide, <30% CASNO: 01305620 SYN: CLASS: 380 NAME: Calcium Hypochiorite CASNO: 07778543 SYN: CLASS: 340 NAME: Calcium Hypochlorite, <30% CASNO: 07778543 SYN: CLASS: 340 NAME: Carbitol CASNO: 00111900 SYN: CLASS: 311 NAME: Carbolic Acid CASNO: SYN: (See Phenol) CLASS: NAME: Carbon Bisulfide CASNO: SYN: (See Carbon Disulfide) CLASS: • NAME: Carbon Disulfide CASNO: 00075150 SYN: Carbon Bisulfide CLASS: 502 NAME: Carbon Oxyfluoride. CASNO: 00353504 SYN: . CLASS: 350 . NAME: Carbontetrabromide CASNO:’ 00558134 SYN: Tetrabromomethane CLASS: 261 ‘NAME: Carbon Tetrachloride CASNO: 00056235 SYN: Tetrachloromethane CLASS: 261 NAME: Carbonyl Chloride CASNO: SYN: (See Phosgene) . CLASS: NAME: Cellosolve Acetate CASNO: SYN: (See 2-Ethoxyethyl Acetate) CLASS: B—il ------- CHEMICAL NAMES AND SYNONYMS NAME: Chloral CASNO: SYN: (See Trichloroacetaldehyde) CLASS: NAME: Chlorine CASNO: 07782505 SYN: CLASS: 350 NAME: Chlorine Cyanide CASNO: SYN: (See Cyanogen Chloride) CLASS: NAME: Chloroacetaldehyde CASNO: 00107200 SYN: CLASS: 121 262 NAME: Chioroacetic Acid - CASNO: 00079118 SYN: CLASS: 103 NAME: Chioroacetone CASNO: 00078955 SYN: CLASS: 262 NAME: Chloroacetonitrile CASNO: 00107142 SYN: CLASS: 262 431 N: NAME: p-Chloroaniline CASNO: 00106478 SYN: Chlorobenzaniine,4 CLASS: 145 264 NAME: Chlorobenzamine,4 CASNO: SYN: (See p-Chloroaniline) CLASS: NAME: Chlorobenzene CASNO: 00108907 SYN: CLASS: 263 NAME: 2-Chloro-1,3-butadiene CASNO: 00126998 SYN: Chloroprene CLASS: 261 NAME: Chlorobutane,l- CASNO: SYN: (See n-Butyl Chloride) CLASS: NAME: p-Chloro-m-cresol CASNO: 00059507 SYN: CLASS: 292 316 264 NAME: Chlorodibromomethane CASNO: 00124481 SYN: S CLASS: 261 B-i 2 ------- CHEMICAL NAMES AND SYNONYMS NAME: Chlorododecane CASNO: 00112527 SYN: CLASS: 261 NAME: SYN’: Chloroethane . CASNO: CLASS: 00075003 261 . NAME: SYN: Chloroethanol (See Ethylene Chiorohydrin) . . CASNO: CLASS: • NAME: Chloroethene CASNO: SYN: (See Vinyl Chloride) . CLASS: NAME: 2-Chlóroethyl Vinyl Ether CASNO: 00110758 SYN: • CLASS: 241 262 NAME: Chloroform . CASNO: 00067663 SYN: Trichloromethane CLASS: 261 NAME: Chloromethane CASNO: SYN: (See Methyl Chloride) S CLASS: • NAME: SYN: Chloromethyl Bènzene (See Benzyl Chloride) CASNO: CLASS: • NAME: Chloromethyl Methyl Ether CASNO: 00107302 SYN: . CLASS: 241 262 • NAME: 3-Chloro-2-methylpropene CASNO: 00563473 • SYN: . CLASS: 262 292 NAME: 2-Chlöronaphthalene . S CASNO: 00091587 SYN: CLASS: 265 NAME: SYN Chloronaphthalènes (all isomers) • CASNO: CLASS: 25586430 265 NAME: 2-Chloro-2-nitropropane CASNO: 00594718 SYN: • CLASS: 442 NAME: 2-Chiorophenol CASNO: 00095578 SYN: CLASS: 316 264 B—I 3 ------- CHEMICAL NAMES AND SYNONYMS NAME: 4-Chlorophenyl Phenyl Ether CASNO: 07005723 SYN: CLASS: 265 242 NAME: Chioroprene CASNO: SYN: (See 2-Chloro-1,3-butadiene) CLASS: NAME: Chloropropane CASNO: SYN: (See Isopropyl Chloride) CLASS: NAME: Chloropropane, 1 CASNO: • SYN: (See Propyl Chloride) CLASS: NAME: 1-Chloro-2-propanol CASNO: 00127004 SYN: CLASS: 262 NAME: 3-Chloro-l-propanol CASNO: 00627305 SYN: . CLASS: 262 NAME: 3-Chloropropionitrile CASNO: 00542767 SYN: CLASS.: 262 431 NAME: Chlorosülfonic Acid • CASNO: 07790945 SYN: CLASS: 370 NAME: o-Chlorotoluene CASNO:. 00095498 SYN: . CLASS: 263 NAME: p-Chlorotoluene CASNO: 00106434 SYN: CLASS: 263 NAME: Chromic Acid CASNO: 11115745 SYN: . CLASS: 370 NAME: Chromic Acid, <30% CASNO: 11115745 SYN: . CLASS: 370 NAME: Chromic Acid, 30-70% CASNO: 11115745 SYN: CLASS: 370 NAME: SYN: Chromic Acid, >70% . . CASNO: CLASS: 11115745 370 B— 14 ------- CHEMICAL NAMES AND SYNONYMS NAME: Citric Acid CASNO: 00077929 SYN: CLASS: 313 NAME: Citric Acid, <30% CASNO: 00077929 SYN: CLASS: 313 NAME:: Copper Chloride CASNO: 01344678 SYN: CLASS: 340 NAME:. Copper Sulfate CASNO: 01344736 SYN: CLASS: 340 NAME: Creosote CASNO: 08001589 SYN: CLASS: 316 NAME: Creosote, Wood CASNO: 08021394 SYN: CLASS: 316 NAME: m-Cresol CASNO: 00108394 SYN: CLASS: 292 316 NAME: Cresols CASNO: 01319773 SYN: CLASS: 292 316 NAME: Crotonaldehyde CASNO: 04170303 SYN: Butenal,trans-2 CLASS: 121 NAME: Cumene CASNO: 00098828 SYN: Methylethyl Benzene CLASS: 292 312 NAME: Cupric Chloride CASNO: 07447394 SYN: CLASS: 340 NAME: Cupric Chloride, <30% CASNO: 07447394 SYN; CLASS: 340 NAME: Cupric Nitrate CASNO: 03251238 SYN: CLASS: 340 NAME: Cupric Sulfate CASNO: 07758987 SYN: CLASS: 340 B— 15 ------- CHEMICAL NAMES AND SYNONYMS NAME: Cupric Sulfate, <30% CASNO:. 07758987 SYN: . . CLASS: 340 NAME: Cyanogen CASNO: 00460195 SYN: . . CLASS: 350 NAME: Cyanogen Bromide CASNO: 00506683 SYN: Bromine Cyanide . CLASS: 215 350 NAME: Cyanogen Chloride . CASNO: 00506774 SYN: Chlorine Cyanide CLASS: 215 350 NAME: Cyclohexane . CASNO: 00110827 SYN: . CLASS: 291 NAME: Cyclohexanol CASNO: 00108930 SYN: . CLASS: 312 NAME: Cyclohexanone CASNO: 00108941 SYN: CLASS: 391 NAME: \Cyclohexylamine CASNO: 00108918 SYN: CLASS: 141 NAME: Cymene CASNO: 25155151 SYN: .. CLASS: 292 NAME: Decahydronaphthalene CASNO: 00091178 SYN: CLASS:. 291 NAME: Decanal (all isomsers) CASNO: 00112312 SYN: CLASS: 121 NAME: Decane . CASNO: 00124185 SYN: CLASS: 291 NAME: Diacetin CASNO: 25395317 SYN: ‘Glycerol Diacetate CLASS: 311102 NAME: Diacetone Alcohol CASNO: 00123422 SYN: CLASS: 391 313 — 16 ------- CHEMICAL NAMES AND SYNONYMS NAME: Diallyamine CASNO: 00124027 SYN: . CLASS: 142 NAME: Dianiine CASNO: SYN: (See Hydrazine) CLASS: NAME: Diaminoethane,1,2 CASNO: SYN: (See Ethylenediamine) ‘CLASS: NAME: 1,3-Diaminopropane CASNO: 00109762 SYN:’ CLASS: 144 NAME: Di-n-amylamine CASNO: 02050922 SYN: • CLASS: 142 NAME: Dibenzyl Ether ‘ CASNO: 00103504 SYN: CLASS’: 241 ‘ NAME’: ‘ Dibenzyl Sebacate CASNO: 00140249 SYN: ‘ CLASS: 224 , NAME: 1,2-Dibronio-3-chloropropane CASNO: 00096128 SYN: ‘ ‘ CLASS: 262 ‘ NAME: Dibromoethane,1,2 CASNO: SYN: (See ‘Ethylene Dibroniide) , CLASS: ‘ NAME: Dibromoethy lbenzene CASNO: SYN: (See Alkazene) ‘ CLASS: NAME: Dibromomethane CASNO: SYN: ‘ (See Methy1ene Bromide) CLASS: Dibutylamine CASNO: 00111922 SYN: , ‘ CLASS: 142 NAME: Dibutylether ‘ CASNO: 00142961 SYN: , , ‘ CLASS: 241 NAME: Dibutyl Sebacate ‘ CASNO: 00109433 SYN: CLASS: 224 B—17 ------- CHEMICAL NAMES AND SYNONYMS NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: CASNO: CLASS: CASNO: CLASS.: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: 00156592 261 00540590 261 00156605 261 00079367 262 25321226 263 00095501 263 00541731 263 00106467 263 00075274 261 00110576 261 01300216 261 Dichloroacetyl Chloride Dichlorobenzene 1,2- Dichlorobenzene 1, 3-Dichlorobenzene 1, 4-Dichioroberizene Dich lorobronioniethane 1, 4-Dichioro- 2 -butene Dichloroe thane Dichloroethane, 1,1 (See Ethylidene Dichloride) Dichioroethane ,1,2 (See Ethylene .Dichloride) cis -Dichloroethylene Dichloroethylene, 1,1 (See Vinylidene Chloride) ‘1,2- Dichloroethylene trans-l , 2-Dichloroethylene B—I 8 ------- CHEMICAL NAMES AND SYNONYMS NAME: Dichioroethylene (all isomers) CASNO: 25323302 SYN: . . CLASS: 261 NAME: 2,2’-Dichloroethyl Ether CASNO: 00111444 SYN.: CLASS: 241 262 NAME: Dichloroisopropyl Ether CASNO: 00108601 SYN: . CLASS: 241 262 NAME: Dichioromethane CASNO: SYN: (See Methylene Chloride) CLASS: NAME: Dichloromethyl Ether,sym- CASNO: SYN: (See Bis(chloromethyl) Ether) CLASS: NAME: 2, 4-Dichlorophenol CASNO: .00120832 SYN: CLASS: 264 316 NAME: 2,6-Dichlorophenol CASNO:. 00087650 SYN: CLASS: 264 316 NAME: Dichlorophenylarsine CASNO: 00696286 SYN: Phenyl Dichioroarsine CLASS: 461 NAME: Dichloropropane 1,2 CASNO: SYN: (See Propylene Dichloride) CLASS: NAME: Dichloropropane (all isomers) CASNO: 26638197 SYN: CLASS: 261 NAME: Dichloropropane-Dichloropropene CASNO: 08003198 SYN: CLASS: 261 NAME: 2,3-Dichloro-1-propene CASNO: 00078886 SYN: . CLASS: 261 NAME: Dichloropropene(s) CASNO: 26952238 SYN: . CLASS: 261 NAME: 1, 3-Dichloropropene CASNO: 00542756 SYN: CLASS: 261 B— 19 ------- CHEMICAL NAMES AND SYNONYMS NAME: Dicyclohexylamine CASNO: 00101837 SYN: CLASS: 146 NAME: Diethanolamjne CASNO: 00111422 SYN: CLASS: 143 NAME: Diethylamine CASNO: 00109897 SYN: CLASS: 142 NAME: Diethy làmjnoethanol CASNO: 00100378 SYN: CLASS: 311 143 NAME: Diethylarsine CASNO: 00692422 SYN: CLASS: 461 NAME: Diethyl Benzene CASNO: 25340174 SYN: CLASS: 292 NAME: Diethylene Dioxide,1,4 CASNO: SYN: (See l,4-Dioxane) CLASS: NAME: Diethylene Clycol CASNO: 00111466 SYN: CLASS: 314 NAME: Diethylenetriamjne CASNO: 00111400 SYN: CLASS: 144 NAME: Di-( 2 -Ethylhexyl) Sebacate CASNO: 00122623 SYN: Dioctyl Sebacate CLASS: 224 NAME: l, 2 -Diethylhydrazjne CASNO: 01615801 SYN: CLASS: 280 NAME: 0,0-Diethyl S-Methyl Dithiophosphate CASNO: 03288582 SYN: CLASS: 460 NAME: .Diethyl-p-nitrophenyl Phosphate CASNO: 00311455 SYN: CLASS: 460 442 NAME: DiethylOxalate CASNO: 00095921 SYN: CLASS: 224 B— 20 ------- CHEMICAL NAMES AND SYNONYMS NAME: Diethyl Phthalate CASNO: 00084662 SYN: CLASS: 226 NAME: Diethyl Sebacate CASNO: 00110407 SYN: CLASS: 224 NAME: Diheptyl Phthalate CASNO: 03648213 SYN:. CLASS: 226 NAME: Dihydrosafrole CASNO: 00094586 SYN: CLASS: 278 NAME: Diisobutylainine CASNO: 00110963 SYN: CLASS: 142 NAME: Diisobutylene CASNO: 25167708 SYN: CLASS: 291 NAME: Diisobutyl Ketone CASNO: 00108838 SYN: CLASS: 391 NAME: Diisobutyl Ketone, >70% CASNO: •00108838 SYN: CLASS: 391 NAME: Diisobutyl Phthalate CASNO: 00084695 SYN: CLASS: 226 NAME: Diisoctyl Phthalate CASNO: 27554263 SYN: CLASS: 226 NAME: Diisodecyl Phthalate CASNO: 26761400 ‘-SYN: CLASS: 226 NAME: Diisononyl Phthalate CASNO: 28553120 SYN: . . CLASS: 226 NAME: Diisooctyl Sebacate CASNO: 27214900 .SYN: CLASS: 224 NAME: Diisopropylamine CASNO: 00108189 SYN: . CLASS:• 142 B—2 1. ------- CHEMICAL NAMES AND SYNONYMS NAME: Diisopropyl Benzene (all, isomers) CASNO: 25321099 SYN: CLASS: 292 NAME: Diisopropyl Fluorophosphate CASNO: 00055914 SYN: CLASS: 460 262 NAME: Diisopropyl Ketone CASNO:. 00565800 SYN: CLASS: 314 NAME: N, N-Dimethylacetamide CASNO: 00127195 SYN: CLASS:’ 132 NAME: Dimethylamine’ CASNO: 00124403 SYN: CLASS: 142 NAME: Dimethylaininopropylamine CASNO: 00109557 SYN: CLASS: 144 NAME: Dimethylanaline CASNO: 00121697 SYN: CLASS: 145 NAME: àlpha,alpha-Dimethylbenzyj. Hydroperoxide CASNO: 00080159 SYN: ‘ CLASS: 300 NAME: Dimethylbutylainine CASNO: 00108098 SYN: CLASS:’ 14.3 NAME: Dimethylethanolamine CASNO: 00108010 SYN: . CLASS: 142 NAME: Dimethylformamide . CASNO: 00068122 SYN: . CLASS: 132 NAME: Dimethylhydrazine,sym- CASNO: SYN: (See 1,2-Dimethylhydrazjne) CLASS: NAME: Dirnethylhydrazine ,unsym- . CASNO: SYN: (See 1,1-Dimethylhydrazine) CLASS: NAME: 1,1-Dimethyihydrazine CASNO: 00057147 SYN: Dimethylhydrazine,unsym- CLASS: 280 ------- CHEMICAL NAMES AND SYNONYMS NAME: 1,2-Dimethyihydrazine CASNO: 00540738 SYN: Dimethy lhydrazine,sym- CLASS: 280 NAME: a lpha,a lpha-Dimethylphenethylamine CASNO: 00122098 SYN CLASS: 141 145 NAME: 2,4-Dimethyiphenol CASNO: 00105679 SYN: CLASS: 316 NAME: Diniethyl Phthalate CASNO: 00131113 SYN: CLASS: 226 NAME: Dimethyl Sulfate CASNO: 00077781 SYN: CLASS: 507 NAME: Dimethyl Sulfoxide CASNO: 00067685 SYN: CLASS: 503 NAME: Dimethy lvinylchloride CASNO: 00513371 SYN: CLASS: 267 NAME: Dinonyl Phthalate CASNO: 00084764 SYN: CLASS: 226 NAME: Dioctyl Sebacate CASNO: SYN: (See Di-(2-Ethylhexyl)-Sebacate) CLASS: NAME: Di-n-octyl Phthalate CASNO: 00117840 SYN: CLASS:. 226 NAME: 1,4-Dioxane CASNO: 00123911 SYN: Diethylene Dioxide,l,4 CLASS: 278 NAME: 1,3-Dioxolane CASNO: 00646060 SYN: CLASS: 242 NAME: Dipentene CASNO: 00138863 SYN: CLASS: 291 NAME: Dipropylamine CASNO: 00142847 SYN: CLASS: 142 B— 23 ------- CHEMICAL NAMES AND SYNONYMS NAME: Di-Sec-Octyl Phthalate CASNO: 00131157 SYN: CLASS: 226 NAME: Disodium Phosphate CASNO: 07558794 SYN: CLASS: 330 NAME: Disulfür Dichioride CASNO: 10025679 SYN: CLASS: 507 NAME: Dithiophosphoric Acid CASNO: SYN: (See Tetraethyldithiopyrophosphate) CLASS: NAME: Diundecyl Phthalate CASNO: 03648202 SYN: CLASS: 226 NAME: Divinyl Benzene CASNO: 01321740 SYN: CLASS: 292 NAME: Epichiorohydrin CASNO: 00106898 SYN: S CLASS: 275 262 NAME: 1,2-Epoxybutane CASNO:. 00106887 SYN: CLASS: 275 NAME: Erythritol Anhydride CASNO: SYN: (See 2,2’-Bioxirane) CLASS: NAME: Ethane CASNO: 00074840 SYN: CLASS: 291 NAME: Ethanol CASNO: SYN: (See Ethyl Alcohol) CLASS: NAME: Ethanol, <30% CASNO: 00064175 SYN: CLASS: 311 NAME: Ethanol, 30-70% CASNO: 00064175 SYN: CLASS: 311 NAME: Ethanol, >70% CASNO: 00064175 SYN: CLASS: 311 B- 24 ------- CHEMICAL NAMES AND SYNONYMS NAME: CASNO: SYN: CLASS: NAME: CASNO: SYN:’ ‘CLASS: NAME: CASNO: SYN: CLASS: NAME’: CASNO: SYN:’ CLASS: NAME: CASNO: SYN: CLASS: NAME: CASNO: SYN: CLASS: NAME: CASNO: SYN: CLASS:’ NAME: CASNO: SYN: , CLASS: NAME: ‘ CASNO: SYN: , CLASS: NAME: CASNO: SYN: CLASS: NAME: ‘ CASNO: SYN: , CLASS: NAME: CASNO: SYN: CLASS: NAME: ‘ , CASNO: SYN: ‘ CLASS: ‘NAME: CASNO: SYN: , CLASS: Ethanolamine Aminoethanol, 2 Ethoxyethanol, 2 (See Ethyl ‘Cellosolve) 2-Ethoxyethyl Acetate Cellosolve Acetate Ethyl Acetate Ethyl Cellosolve Ethoxyethanol, 2 Ethyl Acetoacetate Ethyl Acrylate Ethyl Alcohol Ethanol Ethylainine Monoe thylamine Ethylamine, <30% Ethylamine, 30-70% Ethylamine, >70% Ethyl Benzene Ethyl Benzoate 00141435 141 311 00111159 222 241 00141786 222 ‘00110805 311 ‘241 00141979 222 00140885 223 00064175 311 00075047 141 00075047 141 00075047 • 141 00075047 141 00100414 292 00093890 316 B— 25 ------- CHEMICAL NAMES AND SYNONYMS NAME: Ethyl Bromide CASNO: 00074964 SYN: CLASS: 261 - NAME: Ethyl-n-butylamine CASNO: 13360639 SYN: CLASS: 142 NAME: Ethyl Chiorocarbonate CASNO: 00541413 SYN: . . CLASS: 111 NAME: Ethyl Cyanide CASNO: 00107120 SYN: Propionitrile CLASS: 431 NAME: Ethyldimethylmethane . CASNO: SYN: (See Isopentane) . - CLASS: NAME: Ethylene Acetate CASNO: 00111557 SYN: - CLASS: 221 NAME: Ethylene Chlorohydrin CASNO: 00107073 SYN: . Chloroethanol CLASS: 311 262 NAME: Ethylenediamine CASNO: 00107153 SYN: Dianiinoethane,1,2 CLASS: 144 NAME: Ethylene Dibromide CASNO: . 00106934 SYN: Dibrómoethane,1,2 CLASS: .261 NAME: Ethylene Dichioride CASNO: 00107062 SYN: Dichloroethane,1,2 CLASS: 261 NAME: Ethylene Clycol . CASNO: 00107211 SYN: . . CLASS: 314 NAME: Ethylene Glycol Monoacetate CASNO: 00524596 SYN: . CLASS: 103 314 313 NAME: Ethylene Oxide . CASNO: 00075218 SYN: Oxirane CLASS: 275 NAME: Ethylenimine CASNO: 00151564 SYN: Aziridine CLASS: 274 142 B— 26 ------- CHEMICAL NAMES AND SYNONYMS - NAME: Ethyl Ether CASNO: 00060297 SYN: CLASS: 241 NAME: Ethyl Formate ‘ CASNO: 00109944 ‘‘SYN: CLASS: 221 ‘NAME: , ‘2-Ethyihexanoic Acid CASNO: 00149575 SYN: CLASS: 102 NAME: 2-Ethyl-l-Hexanol CASNO: 00104767 SYN: ‘ CLASS: 311 NAME: Ethylidene Dichioride CASNO: 00075343 SYN: - Dichloroethane,l,l CLASS: 261 NAME: Ethyl Me’rcaptan CASNO: - 00075081 SYN: , ‘ CLASS: 501 NAME: Ethyl Methacrylate CASNO: ‘ 00097632 SYN: CLASS: 223 NAME: Ethyl Methanesulfonate •CASNO: 00062500 SYN: CLASS: 232 NAME: Ethyl Silicate CASNO: 00078104 SYN: ‘ ‘ CLASS: 233 291 NAME: Ferric Chloride CASNO: 07705080 SYN: CLASS: 340 ‘NAME: Ferrous Chloride CASNO: 07758943 SYN:’ , CLASS: 340 NAME: Fluorine CASNO: 07782414 SYN: ‘ ‘ ‘ CLASS: 350 NAME: Fluorobenzene CASNO: 00462066 ‘SYN: ‘ CLASS: 263 NAME: Fluoroboric Acid CASNO: , 16872110 SYN: Tetrafluoroboric Acid CLASS: 370 B—27 ------- CHEMICAL NAMES AND SYNONYMS NAME: Fluorosilicjc Acid CASNO: 16961834 SYN: CLASS: 370 NAME: Fluorosulfonic Acid CASNO: 07789211 SYN: CLASS: 504 NAME: Formaldehyde, <37% CASNO: 00050000 SYN: Fornialjn CLASS: 121 NAME: Forma].jn CASNO: SYN: (See Formaldehyde, <37%) CLASS: NAME: Formamide, 30% CASNO: 00075127 SYN: CLASS: 132 NAME: Formic Acid CASNO: 00064186 SYN: Methanoic Acid CLASS: 102 NAME: Formic Acid, <30% CASNO: 00064186 SYN: CLASS: 102 NAME: Formic Acid, 30-70% CASNO: 00064186 SYN: CLASS: 102 NAME: Formic Acid, >70% CASNO: 00064186 SYN: CLASS: 102 NAME: Freon 11 CASNO: 00075694 SYN: CLASS: 261 NAME: Freon 12 CASNO: 00075718 SYN: CLASS: 261 NAME: Freon 21 CASNO: 00075434 SYN: CLASS: 261 NAME: Freon 22 CASNO: 00075456 SYN: CLASS: 261 NAME: Freon 112 CASNO: 00076120 SYN: CLASS: 261 B—28 ------- CHEMICAL NAMES AND SYNONYMS NAME: Freon 114B2 CASNO: 00124732 SYN: CLASS: 261 NAME: Freon TF CASNO: 00076131 SYN: CLASS: 261 • NAME: Freon TMC CASNO: 57762319 SYN: CLASS: 261 NAME: Furan CASNO: 00110009 SYN: Furfuran CLASS: 277 NAME: Furfural CASNO: 00098011 SYN: CLASS: 122 NAME: Furfuran CASNO: SYN (See Furan) CLASS: NAME: 2 -Furylmethanol CASNO: 00098000 SYN: CLASS:. 312 NAME: Gasoline CASNO: 08006619 S’YN: CLASS: 291 292 NAME: Glutaraldehyde CASNO: 00111308 SYN: . CLASS: 121 NAME: Glycerin Triacetate . CASNO: 00102761 SYN: Triacetine CLASS: 102 222 NAME: Glycerol CASNO: 00056815 SYN: Propanetriol,l,2,3 CLASS: 314 NAME: Glycerol Diacetate CASNO: SYN: (See Diacetin) . CLASS: NAME: Glycidaldehyde CASNO: 00765344 SYN: . • CLASS: 275 122 NAME: Glycols CASNO: 68606213 SYN: CLASS: 311 B—29 ------- CHEMICAL NAMES AND SYNONYMS NAME: Halothane CASNO: 00151677 SYN: CLASS: 261 NAME:. Heptane CASNO: 00142825 SYN: CLASS: 291 NAME: Hexachlorobenzene CASNO: 00118741 SYN: CLASS: 263 NAME: Hexachiorobutadjene . CASNO: 00087683 SYN: . CLASS: 261 NAME: Hexachlorocyclopentadiene . CASNO: 00077474 SYN: . . CLASS: 261 NAME: Hexachioropropene CASNd’ - 01888717 SYN: CLASS: 261 NAME: Hexaethyltetraphosphate CASNO: 00757584 SYN: CLASS: 460 NAME: Hexamethyiphosphoamide CASNO: 00680319 SYN: . . CLASS: 132 NAME: Hexana]. . CASNO: 00066251 SYN: CLASS: 121 NAME: Hexane CASNO: 00110543 SYN: . CLASS: 291 NAME: Hexanedioic Acid CASNO: SYN: (See Adipic Acid) CLASS: NAME: Hexanol CASNO: SYN: - (See Hexyl Alcohol) CLASS: NAME: Hexanone, 2 . CASNO: SYN: (S e Methyl n-Butyl Ketone) CLASS: NAME: 1-Hexene CASNO: - 00592416 SYN: . CLASS: 291 B—3O ------- CHEMICAL NAMES AND SYNONYMS NAME: SYN: NAME: SYN:. NAME: SYN: NANE: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: 00111273 311 00302012 280 00302012 280 00302012 280 00302012 280 10035106 370 10035106 370 07647010 370 07647010 370 07647010 370 07647010 370 00074908 215 350 00074908 370 07664393 370 Hexyl Alcohol Hexanol Hydraz me Dianiine Hydrazine, <30% Hydrazine, 30-70% Hydrazine, >70% Hydrobromic Acid Hydrobromic Acid, .30-70% Hydrochloric Acid Hydrochloric Acid, <30% Hydrochloric Acjd, 30-70% Hydrochloric Acid, >70% Hydrocyanic Acid 1 -Lydrocyanic Acid, <30% Hydrofluoric Acid Hydrogen Fluoride CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: • CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO: CLASS: CASNO : CLASS: CASNO: CLASS: • CASNO: CLASS:• CASNO: CLASS:. CASNO: CLASS: B— 31 ------- CHEMICAL NAMES AND SYNONYMS NAME: Hydrofluoric Acid, <30% CASNO: 07664393 SYN: CLASS: 370 NAME: Hydrofluoric Acid, 30-70% CASNO: 07664393 SYN: CLASS: 370 NAME: Hydrofluoric Acid, >70% CASNO: 07664393 SYN: CLASS: 370 NAME: Hydrogen Fluoride CASNO: SYN: (See Hydrofluoric Acid) CLASS: NAME: Hydrogen Peroxide CASNO: 07722841 SYN: CLASS: 300 NAME: Hydrogen Peroxide, <30% CASNO: 07722841 SYN: CLASS: 300 NAME: Hydrogen Peroxide, 30-70% CASNO: 07722841 SYN: CLASS: 300 NAME: Hydrogen Peroxide, >70% CASNO: 07722841 SYN: CLASS: 300 NAME: Hydrogen Phosphide CASNO: 07803512 SYN: Phosphine CLASS: 350 NAME: Hydrogen Sulfide CASNO: 07783064 SYN: CLASS: 350 NAME: Hydroquinone CASNO: 00123319 SYN: CLASS: 490 NAME: Hydroquinone, <30% CASNO: 00123319 SYN: CLASS: 490 NAME: Hylene CASNO: 00101655 SYN: CLASS: 215 NAME: Iminobispropylamine CASNO: 00056188 SYN: CLASS: 144 B- 32 ------- CHEMICAL NAMES AND SYNONYMS NAME: Iodine Pentafluoride SYN: NAME: b-Ionone SYN: NAME: Isoamyl Acetate •SYN: NAME:. Isoamylnitrile SYN: CASNO: 07783666 CLASS: 370 CASNO: 14901076 CLASS: 291 CASNO: 00123922 CLASS: 222 CASNO: 00110463 CLASS: 431 NAME: Isobutene SYN: (See Isobutylene) NAME: Isobutyl Acrylate SYN: NAME: Isobutyl Alcohol SYN: NAME: Isobutylene SYN: Isobutene NAME: Isobutyl Nitrite SYN: NAME: Isobutyraldehyde SYN: NAME: Isooctane ‘SYN: NAME: Isopentane SYN: Ethyldimethylniethane NAME: Isophorone SYN: NAME: Isoprene SYN: CASNO: CLASS: CASNO: 00106638 CLASS: 223 CASNO: 00078831 CLASS: 311 CASNO: 00115117 CLASS: 291 CASNO: 00542563 CLASS: 233 CASNO: 00078842 CLASS: 121 • CASNO: 26635643 CLASS: 291 CASNO: 00078784 CLASS: 291 CASNO: 00078591 CLASS: 391 CASNO: 00078795. CLASS: 291 B— 33 ------- CHEMICAL NAMES AND SYNONYMS NAME: Isopropyl Acetate CASNO: 00108214 SYN: CLASS: 222 NAME: Isopropyl Alcohol CASNO: 00067630 SYN: Propanol, 2- CLASS: 312 NAME: Isopropylainine CASNO: 00075310 SYN: CLASS: 141, NAME: Isopropyl Chloride CASNO: 00075296 SYN: Chloropropane CLASS: 261 312 NAME: Isopropyl Ether CASNO: 00108203 SYN: CLASS: 241 NAME: ‘ Isopropylmethacrylate CASNO: ‘04655349 SYN: CLASS: 223 NAME: Isosafrole ‘ CASNO: 00120581 SYN: CLASS: 278 NAME: “JP-4, Jet Fuel CASNO: 99901291 SYN: CLASS: 291 292 NAME: Kerosene CASNO: 08008206 SYN: , CLASS: , 291 292 NAME: Lactic Acid CASNO: ‘00079334 SYN: CLASS: 103 312 NAME: Lactic Acid, <30% CASNO: 00079334 SYN: CLASS: 103 312 NAME: Lactic Acid, ‘>70% ‘ CASNO: OàO79334 SYN: ‘ CLASS: 103 312 NAME: Lauric Acid CASNO: 00143077 SYN: CLASS: 102 NAME: Laui ic Acid, 30-70% ‘ CASNO: 00143077 SYN: CLASS: 102 B—34 ------- CHEMICAL NAMES AND SYNONYMS NAME: Ligroine CASNO: SYN: (See Naphtha, V.M.& P) CLASS: NAME: d-Limonene CASNO: 05989275 SYN: Menthadiene CLASS: 292 NAME: Linoleic Acid CASNO: 00060333 SYN: CLASS’:, 102 NAME: Maleic Acid CASNO: 00110167 SYN: CLASS: 104 NAME: Maleic Acid, >70% CASNO:. 00110167 SYN: CLASS: 104 NAME: Malic Acid CASNO: 06915157 SYN: CLASS: 104 103 NAME: Malonitrile CASNO: 00109773 SYN: Propane Dinitrile CLASS: 431 NAME: Menthadiene CASNO:, SYN: (See d-Limonene) CLASS: NAME: Mercury CASNO: 07439976 SYN: CLASS: 560 NAME: Mesityl Oxide CASNO: 00141797 SYN: Methylpentenone, 4-,3-,2-. CLASS: 391 NAME: Methacrylonitrile CASNO: 00126987 SYN: CLASS: 431 NAME: Methane CASNO: 00074828 SYN: CLASS: 291 NAME: Methanesulfonic Acid CASNO: 00075752 SYN: CLASS: 504 NAME: Methanethiol CASNO: SYN: (See Methylmercaptan) CLASS: B—35 ------- CHEMICAL NAMES AND SYNONYMS NAME: Methanoic Acid CASNO: SYN: (See Formic Acid) CLASS: NAME: Methanol CASNO.: 00067561 SYN: Methyl Alcohol CLASS: 311 NAME: Methanol, <30% CASNO: 00067561 SYN: CLASS: 311 NAME: Methanol, 30-70% CASNO: 00067561 SYN: CLASS: 311 NAME: Methanol, >70% CASNO: 00067561 SYN: CLASS: 311 NAME: Methoxyethanol, 2 CASNO: SYN: (See Methyl Cellosolve) CLASS: NAME: 4-Methoxy-4-methyl-2-pentanone CASNO: 00107700 SYN: CLASS 391 NAME: Methyl Acetate CASNO: 00079209 SYN: CLASS: 222 NAME: Methyl Alcohol CASNO:’ SYN: (See Methanol) CLASS: NAME: Methyl Acrylate CASNO: 00096333 SYN: CLASS: 223 NAME: Methylacrylic Acid CASNO: 00079414 SYN: CLASS: 102 NAME: 2-Methylactonitrile CASNO: 00075865 SYN: Acetone Cyanohydrin CLASS’: 431 400 NAME: Methylamine CASNO: 00074895 SYN: Monomethylamine CLASS: 141 NAME: Methylamine, 30-70% CASNO: 00074895 SYN: CLASS: 141 B- 36 ------- CHEMICAL NAMES AND SYNONYMS NAME: 3-Methylaminopropylamine CASNO: 06291845 SYN: CLASS: 144 NAME: Methyl Aniline CASNO: 00100618 SYN: CLASS: 147 NAME: 2-Methylaziridine CASNO: 00075558 SYN: Propylenimine,i,2 CLASS: 274 142 NAME: Methyl Bromide CASNO: 00074839 SYN: Bromomethane CLASS: 261 NAME: Methylbutadiene,1 CASNO: SYN: (See 1,3-Pentadiene) CLASS: NAME: Methyl n-Butyl Ketone CASNO: 00591786 SYN: Hexanone, 2 CLASS: 391 NAME: Methyl Cellosolve CASNO: 00109864 SYN: Methoxyethanol, 2 CLASS: 311 241 NAME: Methyl Cellosolve Acetate CASNO; 00110496 SYN: CLASS: 241 222 NAME: Methyl Cellulose CASNO: 09004675 SYN: CLASS: 241 NAME: Methyl Chloride CASNO: 00074873 SYN: Chloromethane CLASS: 261 NAME: Methyl Chloroacetate CASNO: 00096344 SYN: CLASS: •222 NAME: Methyl Chloroform CASNO: 00071556 SYN: Trichloroethane,l,1,1 CLASS: 261 NAME: Methyl Chloroformate CASNO: 00079221 SYN: CLASS: 221 NAME: Methylcyclohexane CASNO: 00108872 SYN: CLASS: 291 B-3 7 ------- CHEMICAL NAMES AND SYNONYMS NAME: Methyl Cyclopentane CASNO: 00096377 SYN: CLASS: 291 NAME: Methylene Bromide CASNO: 00074953 SYN: Dibromomethane CLASS: 261 NAME: Methylene Chloride CASNO: 00075092 SYN: Dichioromethane CLASS: 261 NAME: 4 , 4 ’-Methylenedjanjljne CASNO: 00101779 SYN: CLASS: 147 NAME: n-Methylethanolamjne CASNO: 00109831 SYN: CLASS: 142 NAME: Methylethyl Benzene CASNO: SYN: (See Cumene) CLASS: NAME: Methyl Ethyl Ketone CASNO 00078933 SYN: Butanone,2 CLASS: 391 \ NAME: Methyl Ethyl Ketone Peroxide CASNO: 01338234 SYN: CLASS: 300 NAME: Methyl Formate CASNO: 00107313 SYN: CLASS: 221 NAME: Methylhydrazine CASNO: 00060344 SYN: CLASS: 280 NAME: Methyl Iodide CASNO: 00074884 SYN: CLASS: 261 NAME: Methyl Isobutyl Ketone CASNO: 00108101 SYN: Methylpentanone, 4-,2- CLASS: 391 NAME: Methyl Isocyanate. . CASNO: 00624839 SYN: CLASS: 210 NAME: l-Methyl.4-Isopropenylbenzene . CASNO: 01195320 SYN: . CLASS: 292 B—38 ------- CHEMICAL NAMES AND SYNONYMS NAME: Methylmercaptan CASNO: 00074931 SYN:’ Methanethiol CLASS: 7 501 NAME: Methyl Methacrylate CASNO: 00080626 SYN: CLASS: 223 NAME: Methyl Oleate CASNO: 00112629 SYN: CLASS: 223 NAME: Methyl Parathion CASNO: 00298000 SYN: CLASS: 460 442 NAME: Methylpentanone, 4-,2- CASNO: SYN: (See Methyl Isobutyl Ketone) CLASS: NAME: Methyipentenone, 4-,3-,2- CASNO: SYN: (See Mesityl Oxide) CLASS: NAME: Methyipropanol, 2-,2- CASNO: SYN: (See tert-Butanol) CLASS: NAME: Methylpropylamine, 2- CASNO:. SYN: (See. iso-Butylamine) CLASS: NAME: Methylpyridine,2 CASNO: SYN: (See aipha-Picoline) CLASS: NAME: Methyl Salicylate . . CASNO: 00119368 SYN: S CLASS: 226 NAME: Methyl-vinyl-ketone CASNO: 00078944 SYN: CLASS: 391 NAME: Mineral Oil CASNO: 08012951 SYN: ‘ CLASS: 560 NAME: Mineral Spirits CASNO: 08052413 SYN: . CLASS: 291 NAME: Monoethylamine CASNO: SYN: (See Ethylamine) CLASS: 8-39 ------- CHEMICAL NAMES AND SYNONYMS NAME: Monoisopropanolamine . CASNO: 00078966 SYN: CLASS: 141 NAME: Monomethylamine . CASNO: SYN: (See Methylamine) CLASS: NAME: Morpholine CASNO: 00110918 SYN: CLASS: 142 NAME: N-Methyl-2-pyrrolidone CASNO: 00872504 SYN: CLASS: 391 NAME: Naphtha, V.M.& P CASNO: 08032324 SYN: Ligroine. CLASS: 291 NAME: Napthalene CASNO: 00091203 SYN: CLASS: 293 NAME: Natural Gas, Liquified CASNO: 64741486 SYN: CLASS.: 292 NAME: Nickel Carbonyl CASNO: 13463393 SYN: . . CLASS: 350 NAME: Nickel Chloride CASNO:. 07718549 SYN: . CLASS: 340 NAME: Nitric Acid CASNO: 07697372 SYN: CLASS: 370 NAME: Nitric Acid, <30% CASNO: 07697372 SYN: . CLASS: 370 NAME: Nitric Acid, 30-70% CASNO: 07697372 SYN: . CLASS: 370 NAME: Nitric Acid, >70% CASNO: 07697372 SYN: CLASS: 370 NAME: Nitric Acid, Fuming Red CASNO: 08007587 SYN: CLASS: 370 B—40 ------- CHEMICAL NAMES AND SYNONYMS NAME: Nitric Oxide CASNO: 10102439 SYN: CLASS: 350 NAME: Nitrobenzene ‘CASNO: 00098953 SYN: CLASS: 441 292 NAME: Nitroethane CASNO: 00079243 SYN: . CLASS: 441 NAME: Nitrogen Dioxide • CASNO: 10102440 SYN: . CLASS: 350 NAME: Nitrogen Tetroxide CASNO: 10544726 SYN: CLASS: 350 NAME: Nitroglycerine • CASNO: 0O055630 • SYN: CLASS: 441 NAME: Nitromethane CASNO: 00075525 SYN: CLASS: 441. NAME: Nitropropane CASNO: 25322014 SYN: CLASS: 441 • NAME: 1 -Nitropropane CASNO: 00108032 SYN: CLASS: 441 NAME: 2-Nitropropane CASNO: 00079469 SYN: CLASS: 441 NAME: Nitropropane, >70% CASNO: 25322014 SYN: CLASS: 441 -NAME: n-Nitrosodiniethylamine CASNO: 00055185’ SYN: CLASS: 143 442 NAME: Nitrotoluene • CASNO: SYN: • • CLASS’: 441 NAME: , o-Nitrotoluene CASNO: 00088722 SYN: B—4 1 ------- CHEMICAL NAMES AND SYNONYMS NAME: p-Nitrotoluene CASNO: 00099990 SYN: cLAss: 441 NAME: Nonyiphenol CASNO: 25154523 SYN: CLASS: 316 NAME: Octadecane CASNO: 00593453 SYN: CLASS: 291 NAME: n-Octane CASNO: 00111659 SYN: CLASS: 291 NAME: 1-Octanol. CASNO: 00111875 SYN: CLASS: 311 NAME: n-Octano]. CASNO: 29063283 SYN: CLASS: 311 NAME: Oleic Acid CASNO: 00112801 SYN: CLASS: 102 NAME: Oxalic Acid CASNO: 00144627 SYN: CLASS: 104 NAME: Oxirane CASNO: SYN: (See Ethylene Oxide) CLASS: NAME: Palmitic Acid CASNO: 00057103 SYN: CLASS: 102 NAME: Paraldehyde . CASNO: 00123637. SYN: CLASS: 121 NAME: Pentachioroethane CASNO: 00076017 SYN:. CLASS: 261 NAME: Pentachloropheno]. CASNO: 00087865 SYN: CLASS: 264 316 NAME: l,3-Pentadiene CASNO:. 00504609 SYN: Methylbutadiene,l CLASS: 291 B—4 2 ------- CHEMICAL NAMES AND SYNONYMS NAME: Pentane CASNO: 00109660 SYN: CLASS: 291 NAME: Pentanol CASNO: SYN: . (See Amyl Alcohol) CLASS: NAME: . Pentene CASNO: 25377724 SYN: CLASS: 291 NAME: Pentyl Acetate CASNO: SYN: (See Amyl Acetate) CLASS: NAME: Perchioric Acid CASNO: 07601903 SYN: CLASS: 370 NAME:. Perchloric Acid, <30% CASNO: 07601903 SYN: CLASS: 370 NAME: Perchioric Acid, 30-70% CASNO: . 07601903 SYN: CLASS: 370 NAME: . Perchloroethylene CASNO: SYN: (See Tetrachloroethylene) CLASS: NAME: Phenetole . CASNO: SYN: (See Phenyl Ethyl Ether) CLASS: NAME: Phenol CASNO: 00108952 SYN: Carbolic Acid CLASS: 316 NAME: Phenol, <30% CASNO: 00108952 CLASS: 316 NAME: Phenol, 30-70% CASNO: 00108952 SYN: CLASS: 316’ .NAME: Phenol, >70% CASNO: 00108952 SYN: CLASS: 316 NAME: Phenolphthalein CASNO: 00077098 SYN: CLASS: 314 ------- CHEMICAL NAMES AND SYNONYMS NAME: Phenyl Dichloroarsine CASNO: SYN: (See Dichlorophenylarsine) CLASS: NAME: Phenylenediainine CASNO: 00108452 SYN: CLASS: 147 NAME: Pheny1 Ethyl Ether CASNO: - 00103731 SYN: Phenetole CLASS: 243 NAME: Phenyl Glycidyl Ether CASNO: 00122601 SYN: CLASS: 275 NAME: Phenyihydrazine CASNO: 00110063 SYN: CLASS: 280 NAME: Phosgene CASNO: 00075445 SYN: Carbonyl Chloride CLASS: 350 NAME: Phosphine CASNO: SYN: (See Hydrogen Phosphide) CLASS: NAME: Phosphoric Acid CASNO: 07664382 SYN: CLASS: 370 NAME: Phosphoric Acid, <30% CASNO: 07664382 .SYN: CLASS: 370 NAME: Phosphoric Acid, 30-70% CASNO: 07664382 SYN: CLASS: 370 NAME: Phosphoric Acid, >70% CASNO; 07664382 SYN: CLASS: 370 NAME: Phosphorus Oxychloride CASNO: 10025873 SYN: CLASS: 370 NAME: Phosphorus Trichloride CASNO: 07719122 SYN: CLASS: 370 NAME: 4-Pi coline CASNO: 00108894 SYN: CLASS: 271 B—44 ------- CHEMICAL NAMES AND SYNONYMS NAME: alpha-Picoline CASNO: 00109068 SYN: Methylpyridine,2 CLASS: 271 NAME: Picric Acid CASNO: 00088891 SYN:. Trinitrophenol,2,4,6 CLASS: 316 442 NAME: Pic.ric Acid, <30% CASNO: 00088891 SYN: CLASS: 316 442 NAME: Pinene (all isomers) CASNO: 25766181 SYN: CLASS: 291 • NAME: l-Ptperazineethanamine CASNO: 00140318 SYN: . CLASS: 146. NAME: Piperidine CASNO: 00110894 SYN: . CLASS: 274 NAME: Polychiorinated Biphenyis (PCBs) CASNO: 01336363 SYN: Aroclor CLASS: 265 NAME: Potassium Dichromate . CASNO: 07778509 SYN: CLASS: 340 NAME: Potassium Hydroxide CASNO: 01310583 SYN: CLASS: 380 NAME: Potassium Hydroxide; <30% CASNO: 01310583 SYN: • CLASS: 380 NAME: Potassium Hydroxide, 30-70% CASNO: 01310583 SYN: CLASS: 380 • NAME: Potassium Bromide CASNO: 07758023 • SYN: CLASS: 340 NAME: • Potassium Chloride CASNO: 03811049 SYN: CLASS: 340 • • NAME: Potassium Cyanide CASNO:+, 00151508 SYN: CLASS: 215 340 • B—45 ------- CHEMICAL NAMES AND SYNONYMS NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: 00058333 00074986 291 00057578 400 00123386 121 00079094 102 00123626 161 00109604 222 Promethazinehydrochloride CASNO: . CLASS: Propane CASNO: CLASS: Propane Dinitrile CASNO: (See Malonitrile) CLASS: Propane triol ,l,2, 3 CASNO: (See Glycerol) CLASS: Propanol CASNO: •(See Propyl Alcohol) CLASS: Propanol, 2- CASNO: (See Isopropyl Alcohol) CLASS: Propargyl Alcohol CASNO: CLASS: Propeneamide, 2 CASN0 (See Acrylamide) CLASS: beta-Propiolactone . CASNO: • . CLASS: Propionaldehyde • CASNO: CLASS: Propionic Acid CASNO: . CLASS: Propionic Anhydride CASNO: CLASS: Propionitrile CASNO: (See Ethyl Cyanide) CLASS: Propyl Acetate CASNO: 00107197 311 B—46 ------- CHEMICAL NAMES AND SYNONYMS NAME: Propyl Acetate, >70% CASNO: 00109604 SYN: CLASS: 222 NAME: Propyl Alcohol CASNO: 00071238 SYN: Propanol CLASS: 311 NAME: n-Propylani ine CASNO: 00107108 SYN: CLASS: 141 NAME: Propyl Chloride CASNO: 00540545 SYN:’ Chioropropane, 1 CLASS: 261 NAME: Propylenediamine CASNO: 00078900 SYN: CLASS: 144 NAME: Propylene Dichloride CASNO: 00078875 SYN: Dichlóropropane 1,2 CLASS: 261 NAME: Propylene Glycol CASNO: 00057556 SYN: CLASS: 314 NAME: Propylene Oxide CASNO: 00075569 SYN: CLASS: 275 NAME: 1,3-Propylene Oxide CASNO: 00503300 SYN: CLASS: 275 NAME: Propylenimine,1,2 CASNO: SYN: (See 2-Methylaziridine) CLASS: NAME: Propylmethacrylate CASNO: 02210288 SYN: CLASS: 223 -NAME: Pyrethrins CASNO: 00121299 SYN: CLASS: 223 NAME: Pyridine CASNO: 00110861 SYN: CLASS: 271 NAME: Pyrrole CASNO: 00109977 SYN: CLASS: 142 B- 47 ------- CHEMICAL NAMES AND SYNONYMS NAME: Quinoline CASNO: 00091225 SYN: CLASS: 272 NAME: Resorcinol CASNO: 00108463 SYN: Benzendiol,1,3 CLASS: 316 NAME: Safrole CASNO: 00094597 SYN: CLASS: 278 NAME: Silver Nitrate CASNO: 07761888 SYN: CLASS: 340 NAME: -S-odIum Chloride CASNO: 07647145 • SYN: CLASS: 340 NAME: Sodium Cyanide CASNO: 00143339 SYN: CLASS: 215 NAME: Sodium Cyanide, <30% CASNO:. 00143339 SYN: CLASS: 215 NAME: So4iuiu Cyanide, 30-70% CASNO: 00143339 SYN: CLASS: 215 NAME: Sodium Hydroxide • CASNO: 0l310732 SYN: CLASS: 380 NAME: Sodium Hydroxide, <30% CASNO: •0131Ô732 SYN: CLASS: 380 NAME: Sodium Hydroxide, 30-70% CASNO: 01310732 SYN: CLASS: 380 NAME: Sodium Hydroxide, >70% CASNO: 01310732 SYN: • CLASS: 380 NAME: Sodium Hypochlorite CASNO: 07681529 SYN: CLASS: 340 NAME: So4ium Hypochiorite, 30-70% CASNO: 07681529 SYN: CLASS: 340 B—48 ------- CHEMICAL NAMES AND SYNONYMS NAME’: Sodium Pentachlorophenate CASNO: 00131522 SYN: CLASS: 292 NAME: Sodiumpentachlorophenate, <30% CASNO: 00131522 SYN: , CLASS: 292 NAME: Sodium Silicate CASNO: 01344098 SYN: ‘ CLASS: 340 NAME’: Sodium Sulfate CASNO: 07681381 SYN: CLASS: 340 NAME: Sodium Sulfide CASNO: 01313822 SYN: ‘ CLASS: 340 NAME: ‘Sodium Thiosulfate CASNO: 07772987 SYN: , CLASS: 340 NAME: Stannous Chloride CASNO: 07772998 SYN: ‘ CLASS: , 340 NAME: Stearic Acid CASNO: 00057114 SYN: ‘ ‘ CLASS: 102 NAME: Styrene CASNO: 00100425 SYN’: ‘ ‘ CLASS: 292 NAME: Sulfuric Acid CASNO: 07664939 SYN: ; CLASS: 370 NAME: Sulfuric Acid, <30% CASNO: 07664939 SYN: CLASS: 370 NAME: Sulfuric Acid, 30-70% CASNO: 07664939 SYN: ‘ ‘ CLASS: 370 NAME: ‘ Sulfuric Acid, >70% CASNO: 07664939 SYN: ‘ CLASS: 370 NAME: Sulfur Monochloride CASNO: 12771083 SYN: CLASS: 370 B-4 9 ------- CHEMICAL NAMES AND SYNONYMS NAME: Sulfurus Acid CASNO: 07782992 SYN: CLASS: 370 NAME: TNT CASNO: SYN: (See 2,4,6-Trinitrotoluene) CLASS: NAME: Tannic Acid CASNO: 01401554 SYN: CLASS: 224 NAME: Tannic Acid, <30% CASNO: 01401554 SYN: CLASS: 224 NAME: Tannic Acid, 30-70% CASNO: 01401554 SYN: CLASS: 224 NAME: Tannic Acid, >70% CASNO: 01401554 SYN: CLASS: 224 NAME: Terpineol CASNO: 08000417 SYN: CLASS: 313 NAME: Tetrabromoniethane CASNO: SYN: (See Carbontetrabromide) CLASS: NAME: Tetrabutyl. Orthotitanate CASNO: 05593704 SYN: CLASS: 233 NAME: 1,2,4,5-Tetrachlorobenzene CASNO: 00095943 SYN: CLASS: 263 NAME: Tetrachlorodif].uoroethane CASNO: 28605745 SYN: CLASS: 261 NAME: 1,1,1,2-Tetrachioroethane CASNO: 00630206 SYN: CLASS: 261 NAME: 1, 1,2,2-Tetrachioroethane CASNO: 00079345 SYN: CLASS: 261 NAME: Tetrachioroethylene CASNO: 00127184 SYN: Perchioroethylene CLASS: 261 B-5O ------- CHEMICAL NAMES AND SYNONYMS NAME: Tetrachloromethane CASNO: SYN: (See Carbon Tetrachioride) CLASS: NAME: Tetraethyldithiopyrophosphate CASNO: 03689245 SYN: Dithiophosphoric Acid CLASS: 460 NAME: Tetraethy lenepentamine CASNO: 00112572 • SYN: . CLASS: 144 NAME:’ Tetraethyllead CASNO: 00078002 SYN:’ CLASS: 461 • NAME: Tetrafluoroboric Acid CASNO: SYN: •(.See Fluoroboric Acid) CLASS: NAME: Tetraflüoroethylene CASNO: .00116.143 SYN: “ CLASS: • 261 NAME: Tetrahydrofuran • CASNO: 00109999 SYN: CLASS: 277 NAME: 1, 2,3, 4-Tetrahydronaphthalene CASNO: 00119642 SYN: • Tetralin . CLASS: 292 NAME: Tetralin • CASNO: SYN: (See 1,2,3,4-Tetrahydronaphthalene) CLASS: NAME: N,N,N’,N’-Tetramethylenediaxnine • CASNO: 00110189 SYN: • ‘ • CLASS: 144 NAME: Tetranitroniethane ‘ CASNO: 00509148 SYN: ‘ CLASS: 441 NAME: Thionyl Chloride CASNO: 07719097 SYN: • • CLASS: 501 NAME: Thiophene • CASNO: 00110021 •SYN: , • ‘ CLASS: 502 279 NAME: Thiophenol CASNO: 00108985 SYN: Benzenethiol CLASS: 501 3-51 ------- CHEMICAL NAMES AND SYNONYMS NAME: Titanium Tetrachioride CASNO: 07550450 SYN: CLASS: 461 NAME: Toluene CASNO: 00108883 SYN: . . CLASS: 292 NAME: Toluene;Diisocyanate . cASNO: 26471625 SYN: CLASS: 210 NAME: p-Toluenesulfonic Acid CASNO: . 00104154 SYN: .: CLASS: ‘504 NAME: o-Toluidine CASNO: 00095534 SYN: CLASS: 146 NAME: Triacetine CASNO: SYN: (See Glycerin Triacetate) . CLASS: NAME: Triallylamine CASNO: 00102705 SYN: CLASS: 143 NAME: ‘Tributyl Phosphate ‘ CASNO: 00126738 SYN: CLASS: 460 NAME: TrichIoroacetaldehyde ‘ CASNO: 00075876 SYN: Ch lora l . CLASS: . 121 262. NAME: Trichloroacetic Acid CASNO: 00760390 SYN: CLASS: 103 NAME: Trichloroacetic Acid CASNO: 00076039 SYN: ‘ CLASS: 103 NAME: Trichioroacetonitrile . CASNO: 00545062 SYN: CLASS: 431 NAME: 1,2,4-Trichlorobenzene CASNO: . 00120821 SYN: ‘ CLASS: 263 NAME: 1,1,2-Trichioroethane CASNO: 00079005 SYN: CLASS: 261 B— 52 ------- CHEMICAL NAMES AND SYNONYMS NAME: Trichloroethane,1,1,1 CASNO: SYN: (See Methyl Chloroform) CLASS: NAME: 2,2,2-Trichioroethanol CASNO: 00115208 SYN: CLASS: 311 262 NAME: Trichioroethene .CASNO: SYN: (See Trichloroethylene) CLASS: NAME.: Trichioroethylene CASNO: 00079016 SYN: Trichioroethene CLASS: 261 NAME: Trichioromethane CASNO: SYN: (See Chloroform) CLASS: NAME: Trichioromethanethiol CASNO: 00075707 SYN: CLASS: 262 501 NAME: Trichloromethyl-benzene CASNO: SYN: (See Benzotrichloride) CLASS: NAME: 1,2, 3-Trichloropropane CASNO: 00096184 SYN: CLASS: 261 NAME: Tricresyl Phosphate CASNO: 01330785 SYN: Tritolyl Phosphate CLASS: 460 NAME: Triethanolamine CASNO: 00102716 SYN: CLASS: 143 NAME: Triethanolamine, >7C% CASNO: 00102716 SYN: S CLASS: 143 NAME: Triethyl Aluminum CASNO: 00097938 SYN: CLASS: 461 • NAME: Triethylamine S CASNO: 00121448 SYN: S CLASS: 143 NAME: • Trlethy lenetetraamine CASNO: 00112243 SYN • CLASS: 144 B—5 3 ------- CHEMICAL NAMES AND SYNONYMS NAME: Trifluoroethano]. CASNO: 00075898 SYN: CLASS: 311 262 NAME: Triisooctyl Phosphate CASNO: 25103122 SYN: CLASS: 233 460 NAME: Trimethylainine CASNO: 00075503 SYN: CLASS: 143 NAME: 2 ,2,4-Trimethylpentane CASNO: 00540841 SYN: CLASS: 291 NAME: 2 , 4 , 4 -Trimethyl-1-pentene CASNO: 00107391 SYN: CLASS: 291 NAME: Trinitrophenol,2,4,6 CASNO: SYN: (See Picric Acid) CLASS: NAME: 2 ,4,6-Trinitrotoluene CASNO: 00118967 SYN: TNT CLASS: 441 NAME: Trioctyl Phosphine CASNO: 04731537 SYN: CLASS: 461 NAME: Tri-n-propylamine CASNO: 00102692 SYN: CLASS: 143 NAME: Tris(2,3-dibromopropyl) Phosphate CASNO: 00126727 SYN: CLASS: 460 NAME: Tritolyl Phosphate CASNO: SYN: (See Tricresyl Phosphate) CLASS: NAME: Turpentine CASNO: 08006642 SYN: CLASS: 291 NAME: Urea CASNO: 00057136 SYN: CLASS: 1.32 NAME: Valeronitrile CASNO: 00110598 SYN: CLASS: 431 B—54 ------- CHEMICAL NAMES AND SYNONYMS NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: NAME: SYN: Vinyl Acetate CASNO: 00108054 . CLASS: 222 Vinyl Chloride CASNO: 00075014 Chioroethene CLASS: 267 .4-Vinyl -1- cyclohexane CASNO: 00100403 CLASS: 291 Vinylidene Chloride CASNO: 00075354 Dichloroethylene,l,l CLASS: 267 Vinylidene Fluoride CASNO: 00075387 . CLASS: 267 Water CASNO: 07732185 . CLASS: . 560 NAME: Xylene CASNO: 00133207 SYN: CLASS: 292 NAME: m-Xylene CASNO: 00108383 SYN: . . CLASS: 292 . NAME: o-Xylene . . CASNO: 00095476 SYN:. CLASS: 292 . NAME: p-Xylene . CASNO: 00106423 SYN: . CLASS: 292 B-55 ------- APPENDIX C PRODUCT INDEX c—i ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name ACRYLIC(002) Product: Acrylic, Face Shield and Lens 097 09 Leonard Safety Epuipment, Inc.(D) 097 09 Protech Safety Equipment Inc.(D) BUTYL(003) Product: Butyl Rubber Latex Glove, Unsupported 012 00 Direct Safety Conipany(D) 012 00 Hub Safety Equipment, Inc.(D) 012 00 Latex Glove Co., Inc(M) 012 00 Mine Safety Appliances Co.(M) 012 00 North Hand Protection(M) 012 00 Protech Safety Equipment Inc.(D) 012 00 Safeco Inc.(D) Product: Butyl Rubber Latex Glove, Supported 013 00 Latex Glove Co., Inc(M) 013 00 Mine Safety Appliances Co.(M) Product: Butyl Rubber Glove, Solvent Dipped, Unsupported 014 00 LRC Safety Products Co.(D) 014 00 North Hand Protection(M) Product: Butyl Rubber, Sheet 034 03 Record Industrial Co.(M) 034 05 Andover Industries, Inc.(M) 034 07 General Scientific Safety Equipment Company(D) 034 07 Safety Engineering & Supply Co.(D) 034 07 Tingley Rubber Corp.(M) Product: Butyl Rubber/Nylon 064 03 General Scientific Safety Equipment Company(D) • 064 03 Steel Grip Safety Apparel Co., Inc.(M) 064 05 Major Safety Service, Inc.(D) 064 06 United States Safety Service Co.(D) Product: Butyl Rubber, Boots 085 08 Tingley Rubbei Corp.(M) C— 2 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Butyl/Fabric/Butyl 130 05 Fyrepel Products Inc.(M) Product: Butyl/Nylon/Butyl 140 01 Record Industrial Co.(M) 140 04 Record Industrial Co.(M) 140 05 Coodall Rubber Company(M) 140 05 Trelleborg, Inc.(M) BUTYL/NEOPRENE (038) Product: Butyl/Polyester/Ch loroprene Rubber 110 05 Mine Safety Appliances Co.(M) CELLULOSE ACETATE(001) Product: Cellulose Acetate, Face Shield and Lens 099 09 Allied Glove & Safety Products Corp. (M) 099 09 Arbill Inc.(D) 099 09 Cesco Safety Products(M) 0.9 09 Direct Safety Company(D) 099 09 Eastco Industrial Safety Corp.(D) 099 09 Fisher Scientific Company(D) 099 09 General Scientific Safety Equipment Company(D) 099 09 Hub Safety Equipment, Inc.(D) 099 09 Inco Safety Products Co.(M) 099 09 Industrial Safety and Security Co.(D) 099 09 Latex Glove Co., Inc(M) 099 09 Leonard Safety Epuipnient, Inc.(D) 099 09 Magid Glove and Safety Mfg. Co.(M) 099 09 Masterman’s(D) 099 09 Protech Safety Equipment Inc.(D) 099 09 Pulmosan Safety Equipment Corp.(D) 099 09 Rockford Medical & Safety Co.(D) 099 09 The Sager Corporation(M) 099 09 Willson Safety Products(M) CELLULOSE PROPIONATE(0O5) Product: Cellulose Propionate, Face Shield and Lens 094 09 Eastco Industrial Safety Corp.(D) 094 09 Industrial Safety and Security Co.(D) 094 09 Interex Corp.(D) 094 09 Leonard Safety Epuipment, Inc.(D) 094 09 Rockford Medical & Safety Co.(D) 094 09 The Sager Corporation(M) 094 09 Wilison Safety Products(M) C— 3 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name CFILOROBUTYL(006) Product: Chiorobutyl Rubber/Nomex 052 05 ILC Dover(M) Product: Chlorobutyl/Nomex/Chlorobutyl 142 05 Arrowhead Products(M) CPE(007) Product: Chlorinated Polyethylene 060 01 ILC Dover(M) 060 01 Jones Safety Supply, Inc.(D) 060 01 Safety Engineering & Supply Co.(D) 060 01 Safety First Industries(M) 060 03 Safety First Industries(M) 060 04 ILC Dover(M) 060 04 Jones Safety Supply, Inc.(D) 060 04 Safety Engineering & Supply Co.(D) 060 04 Safety First Industries(M) 060 05 ILC Dover(M) 060 05 •Jones Safety Supply, Inc.(D) 060 05 Safety First Industries(M) 060 06 ILC Dóver(M) 060 06 Jones Safety Supply, Inc.(D) 060 06 Safety First Industries(M) CR 39(008) Product: Cr 39, Lens and Face Shield 095 09 PPG Industries, Inc.(S) 095 09 SCL Homalite Industries(S) GORE-TEX(0l8) Product: Microporous Teflon/Polyester 092 01 Coodall Rubber Company(M) 092 02 Body-Guard(M) 092 02 Goodall Rubber Conipany(M) 092 02 Vidaro Corp.(M) 092 04 Coodall Rubber Conipany(M) 092 06 Goodall Rubber Company(M) C— 4 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name NAT+NEOP+NBR(O19) Product: Natural Rubber+Chloroprene+Nitrile Glove, Unsupported 023 00 Allied Glove & Safety Products Corp.(M) 023 00 Industrial Safety and Security Co. (D) 023 00 Keystone Protection Corp.(D) 023 00 Leonard Safety Epuipmeñt, Inc.(D) 023 00 Pioneer Industrial Products Co.(M) NATURAL RUBBER(013) Product: Natural Rubber Latex Glove, Supported 001 00 Allied Glove & Safety Products Corp.(M) 001 00 Best Manufacturing Company(M) 001 00 Boss Manufacturing Company(M) 001 00 Comasec(M) 001 00 Eastco Industrial Safety Corp.(D) 001 00 .Edmont.Div. Becton, Dickinson & Co.(M) 001 00 General Scientific Safety Equipment Company(D) 001 00 Goodyear Rubber Products Corp.(S) 001 00 Granet(M), 001 00 Holland Safety Supply Co.(D) 001 00 IPESC0., Inc.(M) 001 00 Industrial Products Co., Inc.(D) 001 00 Industrial Safety and Security Co.(D) 001 00 Interéx Corp.(D) 001 00 Intermarket Latex, Inc.(M) 001 00 Keystone Protection Corp..(D) 001 00 Latex Glove Co., Inc(M) 001 00 Magid Glove and Safety Mfg. Co.(M) 001 00 Masterman’s(D) 001 00 Miller Products Co., Inc.(D) 001 00 Mine Safety Appliances Co.(M) 001 00 Monte Glove Company(M) 001 00 Protech Safety Equipment Inc.(D) 001 00 Safeco Inc.(D) 001 00 W.H. Salisbury & Co.(M) 001 00 Standard Glove & Safety Equip. Corp.(D) 001 00 Stauffer Manufacturing Company(M) 001 .00 H. Texier Glove Company Inc.(D) Product: Natural Rubber Clove, Solvent Dipped, Unsupported 015 00 Arbill Inc.(D) 015 00 North Hand Protection(M) C— 5 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Natural Rubber Latex Clove, Unsupported 017 00 Allied Glove & Safety Products Corp.(M) 017 00 Ansell Industrial Products(M) 017 00 Best Manufacturing Company(M) 017 00 Boss Manufacturing Company(M) 017 00 Comasec(M) 017 00 Dayton Flexible Products(M) 017 00 Defense Apparel(M) 017 00 Eastco Industrial Safety Corp.(D) 017 00 Edniont Div. Becton, Dickinson & Co.. (M) 017 00 General Scientific Safety Equipment Company(D) 017 00 Clover Latex, Inc.(M) 017 00 Goodyear Rubber Products Corp.(S) 017 00 Cranet(M) 017 00 Holland Safety Supply Co.(D) 017 00 .IPESCo., Inc.(M) 017 00 Industrial Products Co., Inc.(D) 017 00 Industrial Safety and Security Co.(D) 017 00 Interex Corp.(D) 017 00 Intermarket Latex, Inc.(M) 017 00 Keystone Protection Corp.(D) 017 00 LRC Safety Products Co.(D) 017 00 Latex Clove Co., Inc(M) 017 00 Leonard Safety Epuipment, Inc.(D) 017 00 Magid Clove and Safety Mfg. Co.(M) 017 00 Masterman’s(D) 017 00 Memphis Clove Company(M) 017 00 Miller Products Co., Inc.(D) 017 00 Mine Safety Appliances Co.(M) 017 00 North Hand Protection(M) 017 00 Pioneer Industrial Products Co.(M) - 017 00 Protech Safety Equipment Inc.(D) O17 00 Renco Corp(M) 017 00 Robar Protective Products(D) 017 00 Rockford Medical & Safety Co.(D) 017 00 Safeco Inc.(D) 017 00 W.H. Salisbury & Co.(M) 017 00 Standard Clove & Safety Equip. Corp.(D) 017 00 Stauffer Manufacturing Company(M) 017 00 H. Texier Clove Company Inc.(D) Product: Natural Rubber, Sheet 045 03 Masterman’s(D) 045 06 General Scientific Safety Equipment Company(D) 045 07 Allied Clove & Safety Products Corp.(M) 045 07 Arbill Inc.(D) 045 07 Boss Manufacturing Company(M) C— 6 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant - Material Code Type Vendor Name Product: Natural Rubber, Sheet (cont.) 045 07 Defense Apparel(M) 045 07 La Crosse Footwear, Inc.(M) 045 07 Latex Glove Co., Inc(M) 045 07 Lehigh Safety Shoe Co.(M) 045 07 Leonard Safety Epuipment, Inc.(D) 045 07 Magid Glove and Safety Mfg. Co.(M) 045 07 Ranger(M) 045 07 Record Industrial Co.(M) 045 07 Safety Engineering & Supply Co. (D) 045 07 Tingley Rubber Corp.(M) Product: Natural Rubber, Boots 080 08 Allied Glove & Safety Products Corp.(M) 080 08 Arbill Inc.(D) 080 08 Boss Manufacturing Company(M) 080 08 Direct Safety Company(D) 080 08. Eastco Industrial Safety Corp.(D) 080 08 Interex Corp.(D) 080 08 Iron Age Protective Company(M) 080 08 Jordan David Safety Products(M) 080 08 LaCrosse Footwear, Inc.(M) 080 08 Latex Glove Co., Inc(M) 080 08 Lehigh Safety Shoe Co.(M) 080 08 Leonard Safety Epuipment, Inc.(D) 080 08 Masterman’s(D) 080 08 Miller Products Co., Inc.(D) 080 08 Rainfair, Inc.(M) 080 08 Record Industrial Co.(M) 080 08 Robar Protective Products(D) 080 .08 Safety Engineering & Supply Co.(D) 080 08 Tingley Rubber Corp.(M) Product: Natural Rubber/Nylon 087 03 Frommelt Industries, Inc.(M) Product: Natural Rubber/Cotton 089 01 Boss Manufacturing Company(M) 089 01 Record Industrial Co.(M) 089 02 Boss Manufacturing Company(M) 089 03 Boss Manufacturing Company(M) 089 03 Direct Safety Company(D) 089 03 Fisher Scientific Conipany(D) 089 03 Protech Safety Equipment Inc.(D) 089 03 Rockford Medical & Safety Co.’(D) C— 7 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Natural Rubber/Polyester 136 01 Plastex Protective Products, Inc.(M) 136 03 Standard Glove & Safety Equip. Corp.(D) 136 04 Plastex Protective Products, Inc.(M) 136 06 Plastex Protective Products, Inc.(M) NEOP+NAT RUBBER(015) Product: Chloroprene+Natural Rubber Latex Glove, Unsupported 026 00 Ansell Industrial Products(M) 026 00 Arbill Inc.(D) 026 00 Clean Room Products, Inc.(M) 026 00 Eastco Industrial Safety Corp.(D) 026 00 Hub Safety Equipment, Inc.(D) 026 00 Industrial Products Co., Inc. (D) 026 00 Intermarket Latex, Inc.(M) 026 00 International Playtex, Inc.(M) 026 00 Keystone Prot ction Corp.(D) NEOP/NAT RUBBER(039) Product: Cloroprene/Natural Rubber Latex Glove, Unsupported 008 00 Ansell Industrial Products(M) 008 00 Industrial Products Co., Inc.(D) NEOPRENE(016) Product: Chloroprene Latex Clove, Supported 002 00 Allied Clove & Safety Products Corp.(M) 002 00 Arbill Inc.(D) 002 00 Best Manufacturing Company(M) 002 00 Boss Manufacturing Company(M) 002 00 Comasec(M) 002 00 Eastco Industrial Safety Corp.(D) 002 00 Edmont Div. Becton, Dickinson & Co.(M) 002 00 General Scientific Safety Equipment Company(D) 002 00 Goodyear Rubber Products Corp.(S) 002 00 Granet(M) 002 00 Holland Safety Supply Co.(D) 002 00 Hub Safety Equipment, Inc.(D) 002 00 IPESCo., Inc.(M) 002 00 Industrial Products Co., Inc.(D) 002 00 Industrial Safety and Security Co.(D) 002 00 Interex Corp.(D) 002 00 Intermarket Latex, Inc.(M) 002 00 Keystone Protection Corp.(D) 002 00 Latex Clove Co., Inc(M) 002 00 Leonard Safety Epuipment, Inc.(D) C— 8 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Chloroprene Latex Glove, Supported (cont.) 002 00 Magid Glove and Safety Mfg. Co.(M) 002 00 Major Safety Service, Inc.(D) 002 00 Masterman’s(D) 002 00 Miller Products Co., Inc.(D) 002 00 Mine Safety Appliances Co.(M) 002 00 Monte GloveCompany(M) 002 00 OKI Supply Co.(M) 002 00 Pioneer Industrial Products Co.(M) 002 00 Protech Safety Equipment Inc.(D) 002 00 Rockford Medical & Safety Co.(D) 002 00 Safeco Inc.(D) 002 00 Standard Glove & Safety Equip. Corp.(D) 002 00 Stauffer Manufacturing Company(M) 002 00 H. Texier Glove Company Inc.(D) 002 00 Trelleborg, Inc.(M) 002 00 Wheeler Protective Apparel, Inc.(M) Product: Chloroprene Milled/Chloroprene Latex Glove, Unsupported 010 00 AlliedGlove & Safety Products Corp.(M) 010 00 Arbill Inc. (D) 010 00 Boss Manufacturing Company(M) 010 00 Direct Safety Company(D) 010 00 Industrial Safety and Security Co.(D) 010 00 Keystone Protection Corp.(D) 010 00 Leonard Safety Epuipment, Inc.(D) 010 00 Pioneer Industrial Products Co.(M) Product: Chioroprene Rubber Latex (Baypren) Glove, Unsupported 011 00 Allied Glove & Safety Products Corp.(M) Oil 00 Best Manufacturing Company(M) 011 00 Direct Safety Company(D) 011 00 Eastco Industrial Safety Corp.(D) 011 00 Granet(M) 011 00 IPESCo., Inc.(M) 011 00 Interex Corp.(D) 011 00 Safeco Inc.(D) Product: Chloroprene Rubber Latex Glove, Unsupported 018 00 Allied Clove & Safety Products Corp.(M) 018 00 Ansell Industrial Products(M) 018 00 Best Manufacturing Company(M) 018 00 Eastco Industrial Safety Corp.(D) 018 00 Edmont Div. Becton,. Dickinson & Co.(M) 018 00 General Scientific Safety Equipment Company(D) 018 00 Goodyear Rubber Products Corp.(S) 018 00 Holland Safety Supply Co.(D) 018 00 Hub Safety Equipment, Inc.(D) C—9 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Chioroprene Rubber Latex Clove, Unsupported (cont.) 018 00 IPESCo., Inc.(M) 018 00 Industrial Products Co., Inc.(D) 018 00 Industrial Safety and Security Co.(D) 018 00 Interex Corp.(D) 018 00 Intermarket Latex, Inc.(M) 018 00 Keystone Protection Corp.(D) 018 00 LRC Safety Products Co.(D) 018 00 Latex Glove Co., Inc(M) 018 00 Leonard Safety Epuipment, Inc.(D) 018 00 Magid Glove and Safety Mfg. Co.(M) 018 00 Masterman’s(D) 018 00 Memphis Glove Company(M) 018 00 Mine Safety Appliances Co.(M) 018 00 Pioneer Industrial Products Co.(M) 018 00 Protech Safety Equipment Inc.(D) 018 00 Renco Corp(M) 018 00 Rockford Medical & Safety Co.(D) 018 00 Safeco Inc.(D) 018 00 Standard Glove & Safety Equip. Corp.(D) 018 00 Stauffer Manufacturing Company(M) 018 00 1-i. Texier Glove Company Inc.(D) Product: Chloroprene Rubber, Sheet 031 01 Miller Products Co., Inc.(D) 031 02 Miller Products Co., Inc.(D) 031 03 Acme Mills Company(M) 031 03 Arbill Inc.(D) 031 03 Boss Manufacturing Company(M) 031 03 Magid Glove and Safety Mfg. Co.(M) 031 03 Masterman’s(D) 031 04 Miller Products Co., Inc.(D) 031 05 Andover Industries, Inc.(M) 031 06 Miller Products Co., Inc.(D) 031 07 General Scientific Safety Equipment Company(D) 031 07 Ranger(M) 031 07 Record Industrial Co.(M) 031 07 Safety Engineering & Supply Co.(D) 031 07 Tingley Rubber Corp.(M) Product: Chloroprene Rubber/Polyester 051 02 Boss Manufacturing Company(M) 051 03 Fairway Products(M) 051 03 LRC Safety Products Co.(D) 051 03 Pulmosan Safety Equipment Corp.(D) 051 04 Boss Manufacturing .Company(M) 051 06 Boss Manufacturing Company(M) c—lU ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Chioroprene Rubber, Boots 081 08 Allied Clove & Safety Products Corp.(M) 081 08 Boss Mañufaëturing Company(M) 081 08 Eastco Industrial Safety Corp.(D) 081 08 General Scientific Safety Equipment Company(D) 081 08 Keystone ProtectionCorp.(D) 081 08 La Crosse Footwear, Inc.(M) 081 08 Latex Glove Co., Inc(M) 081 08 Lehigh Safety Shoe Co.(M) 081 08 Magid Glove and, Safety Mfg. Co.(M) 081 08 Masterman’s(D) 081 08 Protech Safety Equipment Inc. (D) 081 08 Rainfair, Inc.(M) 081 08 Record Industrial Co.(M) 081 08 Robar’ Protective Products(D) 081 08 Safety Engineering & Supply Co.(D) 081 08 Standard Safety Equipment Co.(M) 081 08 Ting1ey,P ubber Corp.(M) Product: Chioroprene Rubber/Nylon 093 01 Eastco Industrial Safety Corp.(D) 093 01 Encon Manufacturing Co.(M) 093 01 Keystone Protection Corp.(D) 093 01 Marathon Rubber(M) 093 01 Miller Products Co., Inc.(D) 093 01 Mine Safety Appliances ço.(M) 093 ‘ 01 National Safety Wear, Inc.(M) 093 01 . Protech Safety Equipment Inc.(D) 093 01 ‘ Protexall Company(M) 093 01 Rainfair, Inc.(M) 093 01 Record Industrial Co.(M) 093 01 Safeco Inc.(D) 093 01 Safety Engineering & Supply Co.(D) 093 01 Safety First Industries(M) 093 01 Sawyer-Tower(M) 093 01 Tingley Rubber Corp.(M) 093 02 ‘ Encon Manufacturing Co.(M) 093 02 Keystone Protection Corp.(D) 093 ‘02’ Marathon Rubber(M) 093 02 ‘ Miller Products Co., Inc.(D) 093 03 Enéon Manufacturing Co.(M) 093 03 Protexall Company(M) 093 03 Safety First Industries(M) 093 04 Eastco, Industrial Safety Corp.(D) 093 04 Encon Manufacturing Co.(M) 093 04 Keystone Protection Corp.(D) 093 04 Marathon Rubber(M) c—il ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Chioroprene Rubber/Nylon (cont.) 093 04 Miller Products Co., Inc.(D) 093 04 Mine Safety Appliances Co.(M) 093 04 National Safety Wear, Inc.(M) 093 04 Protech Safety Equipment Inc.(D) 093 04 Rainfair, Inc.(M) 093 04 Record Industrial Co.(M) 093 04 Safeco Inc.(D) 093 04 Safety Engineering & Supply Co.(D) 093 04 Sawyer-Tower(M) 093 04 Tingley Rubber Corp.(M) 093 05 National Draeger, Inc.(M) 093 06 Eastco Industrial Safety Corp.(D) 093 06 Encon Manufacturing Co.(M) 093 06 Keystone Protection Corp.(D) 093 06 National Safety Wear, Inc.(M) 093 06 Rainfair, Inc.(M) 093 06 United States Safety Service Co.(D) Product: Chloroprene Milled/Chioroprene Latex Glove, Supported 125 00 Direct Safety Company(D) 125 00 Miller Products Co.,, Inc.(D) Product: Chioroprene Rubber/Fabric 138 01 Safety Engineering & Supply Co.(D) 138 01 Safety First Industries(M) 138 01 Tingley Rubber Corp.(M) 138 01 Wheeler Protective Apparel, Inc.(M) 138 03 Protech Safety Equipment Inc.(D) 138 03 Safety First Industries(M) 138 04 Safety Engineering & Supply Co.(D) 138 04 Tingley Rubber Corp.(M) 138 04 Wheeler Protective Apparel, Inc.(M) 138 06 Wheeler Protective Apparel, Inc.(M) Product: Chloroprene/Fabric/Chloroprene 139 01 Eastco Industrial Safety Corp.(D) 139 01 Rainfair, Inc.(M) 139 01 Sawyer-Tower(M) 139 04 Eastcc Industrial Safety Corp.(D) 139 04 Rainfair, Inc.(M) 139 04 Sawyer-Tower(M) 139 06 Eastco Industrial Safety Corp.(D) 139 06 Rainfair, Inc.(M) Product: Chloroprene Rubber/Kevlar 141 01 Safety First Industries(M) 141 03 Safety First Industries(M) 141 04 Safety First Industfles(M) c—i 2 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name NEOPRENE+PVC (045) NEOPRENE+SBR RUBBER(017) 01 Direct Safety Company(D) 02 Direct Safety Company(D) 04 Direct Safety Company(D) 06 Direct Safety Comp’any(D) Product: Chioroprene (35%)+SBR(65%)/Nylon- -Tufflon 01 General Scientific Safety Equipment 01 Sawyer-Tower(M) 04 General Scientific Safety Equipment 04 Sawyer-Towe (M) Product: Chloroprene(15%)+SBR(85%)/Cotton- -Tuffprene 066 01 General Scientific Safety Equipment 066 01 Protech Safety Equipment Inc.(D) 066 01 Safeco Inc.(D) 066 01 .Sawyer-Tower(M) 066 04 General Scientific Safety Equipment 066 ‘04 Protech Safety Equipment Inc.(D) 066’ 04 Safeco Inc.(D) 066 04 Sawyer-Tower(M) 066 06 ‘General Scientific Safety Equipment 066 06 Protech Safety Equipment Inc.(D) 066 06 Safeco Inc.(D) 066 06 , Sawyer-Tower(M) 005 005 005 005 ‘005 005 005 005 005 00 00 00 00 ‘OO. 00 00 00 00 Company(D) Company(D) Company(D) Product: Chloroprene+PVC/Polyester 127 127 127 127 065 065 065 065 Company(D) Company(D) NITRILE(02l) Product: Nitrile Rubber Latex Glove, Supported 005 00 Allied Glove & Safety Products Corp.(M) Arbill Inc.(D) ‘Best Manufacturing Company(M) Boss Manufacturing Company(M) Comasec(M) ‘ Eastco Industrial Safety Corp.(D) Edmont Div. Becton, Dickinson & Co.(M) General’Scientific Safety Equipment Company(D) Goodyear Rubber Products Corp.(S) Granet(M) C—i 3 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Nitrile Rubber Latex Clove, Supported (cont.) 005. 00 Holland Safety Supply Co.(D) 005 00 IPESCo., Inc.(M) 005 00 Industrial Products Co., Inc.(D) 005 00 Industrial Safety and Security Co.(D) 005 00 Interex Corp.(D) 005 00 Intermarket Latex, Inc.(M) 005 00 Keystone Protection Corp.(D) 005 00 LRC Safety Products Co.(D) 005 00 Latex Clove Co., Inc(M) 005 00 Leonard Safety Epuipment, Inc.(D) 005 00 Magid Glove and Safety Mfg. Co.(M) 005 00 Masterman’s(D) 005 00 Miller Products Co., Inc.(D) 005 00 Monte Glove Cornpany(M) 005 00 North Hand Protection(M) 005 00 Pioneer Industrial Products Co.(M) 005 00 Protech Safety Equipment Inc.(D) 005 00 Robar Protective Products(D) 005 00 Safeco Inc.(D) 005 00 Standard Glove & Safety Equip. Corp.(D) 005 00 Stauffer Manufacturing Company(M) 005 00 H. Texier Glove Company Inc.(D) Product: Nitrile Rubber Latex Glove, Unsupported 019 00 Allied Glove & Safety Products Corp.(M) 019 00 Ansell Industrial Products(M) 019 00 Arbilllnc.(D) 019 00 Best Manufacturing Company(M) 019 00 Boss Manufacturing Company(M) 019 00 Clean Room Products, Inc.(M) 019 00 Direct Safety Company(D) 019 00 Eastco Industrial Safety Corp.(D) 019 00 Edmont Div. Becton, Dickinson & Co.(M) 019 00 General Scientific Safety Equipment Company(D) 019 00 Clover Latex, Inc.(M) 019 00 Goodyear Rubber Products Corp.(S) 019 00 Granet(M) 019 00 Holland Safety Supply Co.(D) 019 00 Hub Safety Equipment, Inc.(D) 019 00 IPESCo., Inc.(M) 019 00 Industrial Products Co., Inc.(D) 019 00 Industrial Safety and Security Co.(D) 019 00 Interex Corp.(D) 019 00 Intermarket Latex, Inc.(M) 019 00 Keystone Protection Corp.(D) 019 00 LRC Safety Products Ca.(D) 019 00 Latex Glove Co., Inc(M) 019 00 Leonard Safety-Epuipment, Inc.(D) 019 00 Magid Glove and Safety Mfg. Co.(M) C—14 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Nitrile Rubber Latex Glove, Unsupported (cont.) 019 00 Masterman’s(D) 019 00 Memphis Glove Coinpany(M) 019 00 North Hand Protection(M) 019 00 Pioneer Industrial Products Co.(M) 019 00 Protech Safety Equipment Inc.(D) 019 00 Renco Corp(M) 019 00 Rockford Medical & Safety Co.(D) 019 00 SafecoInc.(D) 019 00 Standard Glove & Safety Equip. Corp.(D) 019 00 Stauffer Manufacturing Company(M) 019 00 H. Texier Glove Company Inc.(D) Product: Nitrile Rubber Glove, Solvent Dipped, Unsupported 020 00 Ansell Industrial Products(M) 020 00 Industrial Products Co., Inc.(D) 020 00 Intermarket Latex, Inc.(M) 020 00 Keystone Protection Corp.(D) Product: Nitrile Rubber, Sheet 033 03 Boss Manufacturing Company’(M) 033 03 Record Industrial Co.(M) 033 03 Rockford Medical & Safety Co.(D) Product: Nitrile Rubber/Polyester 059 03 Protexall Company(M) Product: Nitrile Rubber/Nylon 078 03 Protech Safety Equipment Inc.(D) 078 03 Safeco Inc.(D) 078 03 Sawyer-Tower(M) Product: Nitrile Rubber, Boots 084 08 Eastco Industrial Safáty Corp.(D) 084 08 Magid Glove and Safety Mfg. Co.(M) 084 08 Rainfair, Inc.(M) Product: Nitrile/Fabric 132 01 General Scientific Safety Equipment Company(D) 132 03 Allied Glove & Safety Products Corp.(M) 132 03 Eastco Industrial Safety Corp.(D) 132 03 Edmont Div. Becton, Dickinson & Co.(M) 132 03 Goodyear Rubber Products Corp. (S) 132 03 Holland Safety Supply Co.(D) 132 03 Industrial Products Co., Inc.(D) C— 15 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Product: NITRILE±PVC(O2O) 132 132 132 132 132 132 132 132 132 132 Type Vendor Name Nitrile/Fabric (cont.) 03 Industrial Safety and Security Co.(D) O3 Interex Corp.(D) 03 Masterman’s(D) 03 Protech Safety Equipment Inc.(D) 03 Safeco Inc.(D) 03 Standard Glove & Safety Equip. Corp.(D) 03 Stauffer Manufacturing Company(M) 03 H. Texier’ Glove Company Inc.(D) 04 General Scientific Safety Equipment Company(D) 0.5 Eastco Industrial Safety Corp.(D) Product: Nitrile+PVC Glove, Supported 057 00 Barry Manufacturing Co. Ltd.(M) 057 00 Comasec(M) 057 00 North Hand Protection(M) Product: Nitrile+PVC/Fabric 058 058 058 058 058 058 058 058 058 • • 058 058 .058 058 058 058 058 058 058 058 058 058 058 .058 058 • • 058 058 058’. 058 058 01 01 01 01 01 01 01 01 01 01 01 01 01 01 01 02 02 02 02 02 02 02 02 02 02 02 03 04’ .04. Allied Glove & Safety Products Corp.(M) Eastco Industrial Safety Corp.(D) Edmont Div. Becton, Dickinson & Co.(M) Goodyear Rubber Products Corp.(S) Holland Safety Supply Co. (D) Industrial Products Co., Inc.(D) Industrial Safety and Security Co.(D) Interex Corp.(D) Masterman’ s (D) Protech Safety Equipment Inc.(D) Ràinfair, Inc.(M) Safeco Inc.(D) Standard Glove & Safety Equip. Corp.(D) Stauffer Manufacturing Compariy(M) H. Texier Glove Company Inc.(D) Edmont Div. Becton, Dickinson & Co.(M) Goodyear Rubber Products Corp.(S) Holland Safety Supply Co.(D) Industrial Products Co., Inc.(D) Industrial Safety and Security Co.(D) Interex Corp.(D) Masterman’s(D) Protech Safety Equipment Inc.(D) Standard Glove & Safety Equip. Corp.(D) Stauffer Manufacturing Company(M) H. Téxier Glov ’Company Inc.(D) Protexail. Coiñ any(M) ‘A1lied’ Glove & Safety Products Corp. (M) Eastco Industrial Safety’ Corp. (D) c—l6 ------- PRODUCT VENDORS BY .ESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Nitrile+PVC/Fabric (cont.) 058 04 Edmont Div. Becton, Dickinson & Co.(M) 058 04 Goodyear Rubber Products Corp.(S) 058 04 Industrial Products Co., Inc.(D) 058 04 Industrial Safety and Security Co.(D) 058 04 Interex Corp. (D) 058 04 Masterman’s(D) 058 04 Protech Safety Equipment Inc.(D) 058 04 Rainfair, Inc.(M) 058 04 Safeco Inc.(D) 058 04 Standard Glove & Safety Equip. Corp.(D) 058 04 Stauffer Manufacturing Company(M) 058 04 H. Texier Glove Company Inc.(D) 058 06 Allied Glove & Safety Products Corp.(M) 058 06 Eastco Industrial Safety Corp.(D) 058 06 Edinont Div. Becton, DickInson & Co.(M) 058 06 Goodyear Rubber Products Corp.(S) 058 06 Holland Safety Supply Co.(D) 058 06 . Industrial Products Co., Inc.(D) 058 06 Industrial Safet.y and Security Co.(D) 058 06 Interex Corp.(D) 058 06 Masterman’s(D) 058 06 Protech Safety. Equipment Inc.(D) 058 06 Rainfair, Inc.(M) 058 06 Safeco Inc.(D) 058 06 Standard Glove & Safety Equip. Corp.(D) 058 06 Stauffer Manufacturing Company(M) 058 06 H. Texier Glove Company Inc.(D) NONWOVEN FABRIC(024) Product: Sontara 025 01 Mar-Mac Manufacturing Co., Inc.(M) 025 01 Protech Safety Equipment Inc.(D) 025 02 Mar-Mac Manufacturing Co., Inc.(M) 025 02 Protech Safety Equipment Inc.(D) 025 03 Mar-Mac Manufacturing Co., Inc.(M) 025 03 Protech Safety Equipment Inc.(D) 025 04 Mar-Mac Manufacturing Co., Inc.(M) 025. 04 Protach Safety Equipment Inc.(D) 025 .05 Mar-Mac Manufacturing Co., Inc.(M) 025 06 Mar-Mac Manufacturing Co., Inc.(M) 025 06 Protech Safety Equipment Inc.(D) 025 07 Protech Safety Equipment Inc.(D) C— 17 ------- PRODUCT VENDORS BY RESISTANT-MATERIAL Resistant Material Code Type Vendor Name NONWOVEN PE(O3l) Product: Tyvek 071 01 Allied Clove & Safety Products Corp.(M) 071 01 American Scientific Products(D) 071 01 Arbill Inc.(D) 071 01 Charkate(M) 071 01 Clean Room Products, Inc.(M) 071 01 Coyne Safety Equipment, Inc.(D) 071 01 Daffin Disposables, Inc.(M) 071 01 Direct Safety Company(D) 071 01 Disposables Inc.(M), 071 01 Durafab Disposables, Inc.(M) 071 01 Eastco Industrial Safety Corp.(D) 071 01 Edmont Div. Becton, Dickinson & Co.(M) 071 01 Fisher Scientific Company(D) 071 01 Goodyear Rubber Products Corp.(S) 071 01 Holland Safety Supply Co.(D) 071 01 Hub Safety Equipment, Inc.(D) 071 01 IPESCo., Inc.(M) 071 01 Industrial Products Co., Inc.(D) 071 01 Industrial Safety and Security Co.(D) 071 01 Interex Corp.(D) 071 01 Kappler Disposables, Inc.(M) 071 01 Latex Glove Co., Inc(M) 071 01 Leonard Safety Epuipment, Inc.(D) 071 01 Magid Clove and Safety Mfg. Co.(M) 071 01 Mar-Mac Manufacturing Co., Inc.(M) 071 01 Masterman’s(D) 071 01 Melco,’ Inc.(M) 071 01 Mine Safety Appliances Co.(M) 071 01 Protech Safety Equipment Inc.(D) 071 01 Rockford Medical& Safety Co.(D) 071 01 Safeco Inc.(D) 071 01 Standard Glove & Safety Equip. Corp.(D) 071 01 Stauffer Manufacturing Company(M) 071 01 Superior Surgical Mfg. Co., Inc.(M) 071 01 H. Texier Clove Company Inc.(D) 071 01 United States Plastic Corp.(D) 071 02 Allied Glove & Safety Products Corp.(M) 071 02 American Scientific Products(D) 071 02 Arbill Inc.(D) 071 02 Boss Manufacturing Company(M) 071 02 Charkate(M) 071 02 Clean Room Products, Inc.(M) 071 02 Coyne Safety Equipment, Inc.(D) 071 02 Daffin Disposables, Inc.(M) 071 02 Direct Safety Conipany(D) 071 02 Disposables Inc.(M) 071 02 Durafab Disposables, Inc.(M) 071 02 Eastco Industrial Safety Corp.(D) 071 02 Edmont Div. Recton, Dickinson & Co.(M) 071 02 Fisher Scientific Company(D) 071 02 General Scientific Safety Equipment Company(D) c—i 8 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Tyvek(cont.) 071 02 Goodyear Rubber Products Corp.(S) 071 02 Holland Safety Supply Co.(D) 071 02 Hub Safety Equipment, Inc.(D) 071 02 IPESCo., Inc.(M) 071 02 Industrial Products Co., Inc.(D) 071 02 Industrial Safety and SecurityCo.(D) 071 02 Interex Corp.(D) 071 02 Kappler Disposables, Inc.(M) 071 02 Latex Glove Co., Inc(M) 071 02 Leonard Safety Epuipment, Inc.(D) 071 02 Magid Glove and Safety Mfg. Co.(M) 071 02 Mar-Mac Manufacturing Co., Inc.(M) 071 02 Masterman’s(D) 071 02 Melco, Inc.(M) 071 02 Mine Safety Appliances Co.(M) 071 02 Protech Safety Equipment Inc.(D) 071 02 Rockford Medical & Safety Co.(D) 071 02 Safeco Inc.(D) 071 02 Standard Clove & Safety Equip. Corp.(D) 071 02 Stauffer Manufacturing Company(M) 071 02 Superior Surgical Mfg. Co., Inc.(M) 071 02 H. Texier Clove Company Inc.(D) 071 02 United States Plastic Corp.(D) 071 03 Acme Mills Company(M) 071 03 Allied Clove & Safety Products Corp.(M) 071 03 Arbill Inc.(D) 071 03 Boss Manufacturing Company(M) 071 03 Clean Room Products, Inç.(M) 071 03 Coyne Safety Equipment, Inc.(D) 071 03 Daffin Disposables, Inc.(M) 071 03 Direct Safety Company(D) 071 03 Disposables Inc.(M) 071 03 Durafab Disposables, Inc.(M) 071 03 Latex Glove Co., Inc(M) 071 03 Leonard Safety Epuipment, Inc.(D) 071 03 Magid Clove and Safety Mfg. Co.(M) 071 03 Mar-Mac Manufacturing Co., Inc.(M) 071 03 Masterman’s(D) 071 03 Melco, Inc.(M) 071 03 Mine Safety Appliances Co.(M) 071 03 Protech Safety Equipment Inc.(D) 071 03 Rockford Medical & Safety Co.(D) 071 03 Superior Surgical Mfg. Co., Inc.(M) 071 03 United States Plastic Corp.(D) 071 04 Allied Clove & Safety Products Corp. (M) 071 04 Arbill Inc.(D) 071 04 Charkate(M) 071 04 Coyne Safety Equipment, Inc.(D) 071 04 Daffin Disposables, Inc.(M) 071 04 Direct Safety Company(D) C— 19 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Tyvek (cont.) 071 04 Disposables Inc.(M) 071 04 Durafab Disposables, Inc.(M) 071 04 Eastco Industrial Safety Corp.(D) 071 04 Edmont Div. Becton, Dickinson &Co.(M) 071 04 Goodyear Rubber Products Corp.(S) 071 04 Holland Safety Supply Co.(D) 071 04 Hub Safety Equipment, Inc.(D) 071 04 IPESCo., Inc.(M) 071 04 Industrial Products Co., Inc.(D) 071 04 Industrial Safety and Security Co.(D) 071 04 Interex Corp.(D) 071 04 Kappler Disposables, Inc.(M) 071 04 Latex Clove Co., Inc(M) 071 04 Leonard Safety Epuipment, Inc.(D) 071 04 Magid Glove and Safety Mfg. Co.(M) 071 04 Mar-Mac Manufacturing Co., Inc.(M) 071 04 Masterman’s(D) 071 04 Melco, Inc.(M) 071 04 Mine Safety Appliances Co.(M) 071 04 Protech Safety Equipment Inc.(D) 071 04 Rockford Medical & Safety Co.(D) 071 04 Safeco Inc.(D) 071 04 Standard Glove & Safety Equip. Corp.(D) 071 04 Stauffer Manufacturing Company(M) 071 04 Superior Surgical Mfg. Co., Inc.(M) 071 04 Fl. Texier Clove Company Inc.(D) 071 04 •United States Plastic Corp.(D) 071 05 Charkate(M) 071 05 Coyne Safety Equipment, Inc.(D) 071 05 Daffin Disposables, Inc.(M) 071 05 Direct Safety Company(D) 071 05 Disposables Inc.(M) 071 05 Durafab Disposables, Inc.(M) 071 05 Flub Safety Equipment, Inc.(D) 071 05 IPESCo., Inc.(M) 071 05 Industrial Products Co., Inc.(D) 071 05 Industrial Safety and Security Co.(D) 071 05 Kappler Disposables, Inc.(M) 071 05 Mar-Mac Manufacturing Co., Inc.(M) 071 05 Mine Safety Appliances Co.(M) 071 06 American Scientific Products(D) 071 06 E.D. Bullard Company(M) 071 06 Charkate(M) 071 06 Clean Room Products, Inc.(M) 071 06 Coyne Safety Equipment, Inc.(D) 071 06 Direct Safety Company(D) 071 06 Disposables Inc.(M) 071 06 Durafab Disposables, Inc.(M) 071 06 Eastco Industrial Safety Corp.(D) 071 06 Edmont Div. Becton, Dickinson & Co.(M) C— 20 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Tyvek (cont.) 071 06 General Scientific Safety Equipment Company(D) 071 06 Goodyear Rubber Products Corp.(S) 071 06 Holland Safety Supply Co.(D) 071 06 Industrial Products Co., Inc.(D) 071 06 Industrial Safety and Security Co.(D) 071 06 Interex Corp.(D) 071 06 Kappler Disposables, Inc.(M) 071 06 Mar-Mac Manufacturing Co., Inc.(M) 071 06 Masternian’s(D) 071 06 Melco, Inc.(M) 071 06 Mine Safety Appliances Co.(M) 071 06 Protech Safety Equipment Inc.(D) 071 06 Rockford Medical & Safety Co.(D) 071 06 Safeco Inc.(D) 071 06 Standard Glove & Safety Equip. Corp.(D) 071 06 Stauffer Manufacturing Company(M) 071 06 Superior Surgical Mfg. Co., Inc.(M) 071 06 H. Texier Glove Company Inc.(D) 071 06 United States Safety Service Co.(D) 071 07 Allied Glove & Safety Products Corp.(M) 071 07 American Scientific Products(D) 071 07 Arbill Inc.(D) 071 07 Charkate(M) 071 07 Clean Room Products, Inc.(M) 071 07 Coyne Safety Equipment, Inc.(D) 071 07 Daffin Disposables,Inc.(M) 071 07 Direct Safety Company(D) 071 07 Disposables Inc.(M) 071 07 Durafab Disposables, Inc.(M) 071 07 General Scientific Safety Equipment Company(D) 071 07 Hub Safety Equipment, Inc.(D) 071 07 Industrial Products Co., Inc.(D) 071 07 Industrial Safety and Security Co.(D) 071 07 Kappler Disposables, Inc.(M) 071 07 Leonard Safety Epuipment, Inc.(D) 071 07 Mar-Mac Manufacturing Co., Inc.(M) 071 07 Masternian’s(D) 071 07 Mine Safety Appliances Co.(M) 071 07 Rockford Medical & Safety Co.(D) 071 07 Superior Surgical Mfg. Co., Inc.(M) NONWOVEN PP(O23) Product: Polypropylene, Nonwoven 135 02 Kimberly-Clark Corp.(M) C— 21 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name PE(025) Product: Polyethylene Clove, Unsupported 006 00 Allied Clove & Safety Products Corp.(M) 006 00 Arbill Inc.(D) 006 00 Arinin Corporation(M) 006 00 Eastco Industrial Safety Corp.(D) 006 00 Edmont Div. Becton, Dickinson & Co.(M) 006 00 Ceneral Scientific Safety Equipment Company(D) 006 00 Goodyear Rubber Products Corp.(S) 006 00 Granet(M) 006 00 Holland Safety Supply Co.(D) 006 00 Industrial Products Co., Inc.(D) 006 00 Industrial Safety and Security Co.(D) 006 00 Interex Corp.(D) 006 00 Latex Glove Co., Inc(M) 006 00 Magid Glove and Safety Mfg. Co.(M) 006 00 Masterinan’s(D) 006 00 Protech Safety Equipment Inc.(D) 006 00 Protexall Company(M) 006 00 Rockford Medical & Safety Co.(D) 006 00 Safeco Inc.(D) 006 00 Standard Clove & Safety Equip. Corp.(D) 006 00 Stauffer Manufacturing Company(M) 006 00 H. Texier Clove Company Inc.(D) 006 00 United States Plastic Corp.(D) Product: Polyethylene, High Density, Film 041 01 Miller Products Co., Inc.(D) Product: Polyethylene, Medium Density, Film 042 03 Allied Clove & Safety Products Corp.(M) 042 03 Eastco Industrial Safety Corp.(D) 042 03 General Scientific Safety Equipment Company(D) 042 03 Keystone Protection Corp.(D) 042 03 Latex Glove Co., Inc(M) 042 03 Rockford Medical & Safety Co.(D) 042. 06 Magid Clove and Safety Mfg. Co.(M) 042 07 General Scientific Safety Equipment Company(D) 042 07 Interex Corp.(D) 042 07 Latex Clove Co., Inc(M) 042 07 Magid Glove and Safety Mfg. Co.(M) Product: Polyethylene, Low Density, Fi lm 048 03 Masterman’s(D) C— 22 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyethylene, Density Unknown, Film 056 03 American Scientific Products(D) 056 03 Armin Corporation(M) 056 03 Charkate(M) 056 03 Edmont Div. Becton, Dickinson & Co.(M) 056 03 Goodyear Rubber Products Corp.(S) 056 03 Granet(M) S 056 03 Holland Safety Supply Co.(D) 056 03 Industrial Products Co., Inc.(D) 056 03 Industrial Safety and Security Co.(D) 056 03 Interex Corp.(D) 056 03 Masterman’s(D) 056 03 Protech Safety Equipment Inc.(D) 056 03 Protexall Company(M) 056 03 Safeco Inc.(D) 056 03 Standard Glove & Safety Equip. Corp.(D) 056 03 Stauffer Manufacturing Company(M) 056 03 H. Texier Glove Company Inc.(D) Product: Polyethylene/Tyvek 076 01 Allied Glove & Safety Products Corp.(M) 076 01 Arbill Inc.(D) 076. 01 Daffin Disposables, Inc.(M) 076 01 Durafab Disposables, Inc.(M) 076 01 Eastco Industrial Safety Corp.(D) 076 01 Edrnont Div. Becton, Dickinson & Co.(M) 076 01 Goodyear Rubber Products Corp.(S) 076 01 Holland Safety Supply Co.(D) 076 01 Industrial Products Co., Inc.(D) 076 01 Industrial Safety and Security Co.(D) 076 01 Interex Corp.(D) 076 01 Kappler Disposables, Inc.(M) 076 01 Latex Glove Co., Inc(M) 076 01 Magid Glove and Safety Mfg. Co.(M) 076 01 Mar-Mac Manufacturing Co., Inc.(M) 076 01 Masterman’s(D) 076 01 Mine Safety Appliances Co.(M) 076 01 Protech Safety Equipment Inc.(D) 076 01 Rockford Medical & Safety Co.(D) 076 01 Safeco Inc.(D) 076 01 Standard Glove & Safety Equip. Corp.(D) 076 01 Stauffer Manufacturing Company(M) 076 01 B. Texier Glove Company Inc.(D) 076 02. Arbill Inc.(D) 076 02 Daffin Disposables, Inc.(M) 076 02 Disposables Inc.(M) 076 02 Durafab Disposables, Inc.(M) C— 23 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyethylene/Tyvek (cont.) 076 02 IPESCo., Inc.(M) 076 02 Industrial Products Co., Inc.(D) 076 02 Industrial Safety and Security Co.(D) 076 02 Kappler Disposabies, Inc.(M) 076 02 Latex Glove Co., Inc(M) 076 02 Magid Clove and Safety Mfg. Co.(M) 076 02 Mar-Mac Manufacturing Co., Inc.(M) 076 02 Melco, Inc.(M) 076 02 Mine Safety Appliances Co.(M) 076 02 Protech Safety Equipment Inc.(D) 076 02 Rockford Medical & Safety Co.(D) 076 03 Charkate(M) 076 03 Daffin Disposables, Inc.(M) 076 03 Durafab Disposables, Inc.(M) 076 03 Mar-Mac Manufacturing Co., Inc.(M) 076 03 Melco, .Inc.(M) 076 03 Mine Safety Appliances Co.(M) 076 03 Protech Safety Equipment Inc.(D) 076 03 Rockford Medical & Safety Co.(D) 076 04 AlliedGiove & Safety Products Corp.(M) 076 04 Arbill Inc.(D) 076 04 Durafab Disposables, Inc.(M) 076 04 Eastco Industrial Safety Corp.(D) 076 04 Edmont Div. Becton, Dickinson & Co.(M) 076 04 Goodyear Rubber Products Corp.(S) 076 04 Holland Safety Supply Co.(D) 076 04 Industrial Products Co., Inc.(D) 076 04 Industrial Safety and Security Co.(D) 076 04 Interex Corp.(D) 076 04 Kappler Disposables, Inc.(M) 076 04 Latex Glove Co., Inc(M) 076 04 Magid Clove and Safety Mfg. Co.(M) 076 04 Mar-Mac Manufacturing Co., Inc.(M) 076 04 Masterman’s(D) 076 04 Mine Safety Appliances Co.(M) 076 04 Protech Safety Equipment Inc.(D) 076 04 Rockford Medical & Safety Co.(D) 076 04 Safeco Inc.(D) 076 04 Standard Glove & Safety Equip. Corp.(D) 076 04 Stauffer Manufacturing Company(M) 076 04 H. Texier Clov Company Inc.(D) 076 05 Charkate(M) 076 05 Daffin Disposables, Inc.(M) 076 05 Disposables Inc.(M) 076 05 Durafab Disposables, Inc.(M) 076 05 Hub Safety Equipment, Inc.(D) 076 05 Industrial Products co., Inc.(D) 076 05 Industrial Safety and Security Co.(D) 076 05 Kappler Disposables, Inc.(M) 076 05 Mar-Mac Manufacturing Co., Inc.(M) c—24 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyethylene/Tyvek (cont.) 076 05 Rockford Medical & Safety Co.(D) 076 06 Charkate(M) 076 06 Durafab Disposables, Inc.(M) 076 06 Industrial Products Co.., Inc.(D) 076 06 Industrial Safety and Security Co.(D) 076 06 Kappler Disposables, Inc.(M) 076 06 Mar-Mac Manufacturing Co., Inc.(M) 076 06 Melco, Inc.(M) 076 06 Protech Safety Equipment Inc.(D) 076 07 Daffin Disposables, Inc.(M) 076 07 Durafab Disposables, Inc.(M) 076 07 Industrial Products Co., Inc.(D) 076 07 Industrial Safety and Security Co.(D) 076 07 Kappler Disposables, Inc.(M) 076 07 Mar-Mac Manufacturing Co., Inc.(M) 076 07 Protech Safety Equipment Inc.(D) Product: Polyethylene/Fabric 091 01 General Scientific Safety Equipment Company(D) 091 02 General Scientific Safety Equipment Company(D) 091 03 Fisher Scientific Company(D) 091 04 General Scientific Safety Equipment Company(D) 091 06 General Scientific Safety Equipment Company(D) Product: Polyethylene/Polyester 137 03 Protexall Company(M) POLYCARBONATE(026) Product: Polycarbonate, Lens and Face Shield 098 09 Arbill Inc.(D) .098 09 Eastco Industrial Safety Corp.(D) 098 09 Fisher Scientific Company(D) 098 09 Inco Safety Products Co.(M) 098 09 Industrial Safety and Security Co.(D) 098 09 Interex Corp.(D) 098 09 Magid Glove and Safety Mfg. Co.(M) 098 09 Rockford Medical & Safety Co.(D) 098 09 The Sager Corporation(M) POLYESTER(027) . Product: Polyester, Face Shield and Lens 096 09 SGL Homalite Industries(S) C— 25 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name POLYURETHANE(028) Product: Polyurethane Rubber, Unsupported 027 00 Colonial Glove & Garment Inc.(M) Product: Polyurethane Rubber/Nylon 050 01 Boss Manufacturing Company(M) 050 01 Eastco Industrial Safety Corp.(D) 050 01 Jordan David Safety Products(M) 050 01 Miller Products Co., Inc.(D) 050 01 Mine Safety Appliances Co.(M) 050 01 National Safety Wear, Inc.(M) 050 01 Rainfair, Inc.(M) 050 01 Rockford Medical & Safety Co.(D) 050 02 Boss Manufacturing Company(M) 050 02 Miller Products Co., Inc.(D) 050 04 Eastco Industrial Safety Corp.(D) 050 04 Jordan David Safety Products(M) 050 04 Miller Products Co., Inc.(D) 050 04 Mine Safety Appliances Co.(M) 050 04 National Safety Wear, Inc.(M) 050 04 Rainfair, Inc.(M) 050 04 Rockfbrd Medical & Safety Co.(D) 050 06 •Eastco Industrial Safety Corp.(D) 050 06 Rainfair, Inc.(M) Product: Polyurethane Rubber, Boots 082 08 Eastco Industrial Safety Corp.(D) 082 08 Jordan David Safety Products(M) 082 08 Rainfair, Inc.(M) PV ALCOHOL(029) Product: Polyvinyl Alcohol Glove, Supported 004 00 Arbill Inc.(D) 004 00 Eastco Industrial Safety Corp (D) 004 00 Edmont Div. Becton, Dickinson & Co.(M) 004 00 Goodyear Rubber Products Corp.(S) 004 00 Holland Safety Supply Co.(D) 004 00 Industrial Products Co., Inc. (D) 004 00 Industrial Safety and Security Co.(D) 004 00 Interex Corp.(D) 004 00. LRC Safety Products Co.(D) 004 00 Magid Glove and Safety Mfg. Co.(M) • 004 00 Major Safety Service, Inc.(D) 004 00 Masterman’s(D) 004 00 Protech Safety Equipment Inc.(D) C— 26 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Alcohol Glove, Supported (cont.) 004 00 Safeco Inc.(D) 004 00 Standard Glove & Safety Equip. Corp.(D) 004 00 Stauffer Manufacturing Company(M) 004 00 H. Texier Glove Company Inc.(D) Product: Polyvinyl Alcohol Glove, Unsupported 102 00 General Scientific Safety Equipment Company(D) PVC ( 030) Product: Polyvinyl Chloride Glove, Unsupported 003 00 Alliance Supply, Inc.(M) 003 00 Allied Glove & Safety Products Corp.(M) 003 00 Arbill Inc.(D) 003 00 Arniin Corporation(M) 003 00 Best Manufacturing Company(M) 003 00 Boss Manufacturing Company(M) 003 00 Clean Room Products, Inc.(M) 003 00 Dayton Flexible Products(M) 003 00 Defense Apparel(M) 003 00 Eastco Industrial Safety Corp.(D) 003 00 Edmont Div. Becton, Dickinson & Co. (M). 003 00 Goodyear Rubber Products Corp.(S) 003 00 Holland Safety Supply Co.(D) 003 00 Hub Safety Equipment, Inc.(D) 003 00 IPESCo., Inc.(M) 003 00 Industrial Products Co., Inc.(D) 003 00 Industrial Safety and Security Co(D) 003 00 Interex Corp.(D) 003 00 Intermarket Latex, Inc.(M) 003 00 Keystone Protection Corp.(D) 003 00 Latex Glove Co., Inc(M) 003 00 Leonard Safety Epuipment, Inc.(D) 003 00 Magid Glove and Safety Mfg. Co.(M) 003 00 Masterman’s(D) 003 00 Miller Products Co., Inc.(D) 003 00 Mine Safety Appliances Co.(M) 003 00 Monte Glove Company(M) 003 00 North Hand Protection(M) 003 00 OKI Supply Co.(M) 003 00 Oak Technical, Inc. (M) 003 00 Pioneer Industrial Products Co.(M) 003 00 Protech Safety Equipment Inc.(D) 003 00 Protexall Company(M) 003 00 Rockford Medical & Safety Co.(D) 003 00 Safeco Inc.(D) 003 00 Standard Glove & Safety Equip Corp.(D) 003 00 Stauffer Manufacturing Company(M) 003 00 H. Texier Glove Company Inc.(D) C— 27 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride, Sheet 049 04 Aramsco(M) 049 04 Coyne Safety Equipment, Inc.(D) 049 04 Falcon Industries, Inc.(M) 049 04 Latex Clove Co., Inc(M) 049 04 Leonard Safety Epuipment, Inc.(D) 049 04 Miller Products Co., Inc.(D) 049 04 Protech Safety Equipment Inc.(D) 049 04 Safeco Inc.(D) 049 04 Safety Engineering & Supply Co.(D) 049 04 Sawyer-Tower(M) 049 04 Standard Safety Equipment Co.(M) 049 05 Andover Industries, Inc.(M) 049 05 Direct Safety Company(D) 049 05 Mine Safety Appliances Co.(M) 049 06 Aramsco(M) 049 06 Coyne Safety Equipment, Inc.(D) 049 06 Direct Safety Company(D) 049 06 Falcon Industries, Inc.(M) 049 06 General Scientific Safety Equipment Company(D) 049 06 Leonard Safety Epuipment, Inc.(D) 049 06 Magid Glove and Safety Mfg. Co.(M) 049 06 Miller Products Co., Inc.(D) 049 06 Mine Safety Appliances Co.(M) 049 06 Plastex Protective Products, Inc.(M) 049 06 Protexall Company(M) 049 06 Steele & Associates, Inc.(M) 049 07 Arbill Inc.(D) 049 07 Armin Corporation(M) 049 07 Direct Safety Company(D) 049 07 Interex Corp.(D) ‘049 07 La Crosse Footwear, Inc.(M) 049 07 Protexall Company(M) 049 07 Ranger(M) 049 07 Standard Safety Equipment Co.(M) 049 07 Steele & Associates, Inc;(M) Product: Polyvinyl Chloride/Fabric 053 01 Allied Clove & Safety Products Corp.(M) 053 01 Aramsco(M) 053 01 Boss Manufacturing Company(M) 053 01 Durafab Disposables, Inc.(M) C— 28 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Fabric (cont.) 053 01 Jomac Products Inc.(M) 053 01 Jones Safety Supply, Inc.(D) 053 01 Jordan David Safety Products(M) 053 01 Keystone Protection Corp.(D) 053 01 Major Safety Service, Inc.(D) 053 01 Masterman’s(D) 053 01 Mine Safety Appliances Co.(M) 053 01 OKI Supply Co.(M) 053 01 Plastex Protective Products, Inc.(M) 053 01 Protech Safety Equipment Inc.(D) 053 01 Record Industrial Co.(M) 053 01 Robar Protective Products(D) 053 01 Safeco Inc.(D) 053 01 Safety Engineering & Supply Co.(D) 053 01 Sawyer-Tower(M) 053 01 Standard Safety Equipment Co.(M) 053 01 Tingley Rubber Corp.(M) 053 01 Wheeler Protective Apparel, Inc.(M) 053 02 Boss Manufacturing Company(M) 053 02 Durafab Disposables, Inc.(M) 053 02 Jomac Products Inc.(M) 053 02 Jones Safety Supply, Inc.(D) 053 02 Keystone Protection Corp.(D) 053 02 Major Safety Service, Inc.(D) 053 02 Standard Safety Equipment Co.(M) 053 03 Allied Glove & Safety Products Corp.(M) 053 03 Charkate(M) 053 03 Durafab Disposables, Inc.(M) 053 03 Eastco Industrial Safety Corp.(D) 053 03 Edmont Div. Becton, Dickinson & Co. (M) 053 03 Fisher Scientific Company(D) 053 03 Goodyear Rubber Products Corp.(S) 053 03 Holland Safety Supply Co.(D) 053 03 Industrial Products Co., Inc.(D) 053 03 Industrial Safety and Security Co.(D) 053 03 Interex Corp.(D) 053 03 Jomac Products Inc.(M) 053 03 Jones Safety Supply, Inc.(D) 053 03 Keystone Protection Corp.(D) 053 .03 Major Safety Service, Inc.(D) 053 03 Masterman’s(D) 053 03 Protech Safety Equipment Inc.(D) 053 03 Safeco Inc.(D) 053 03 Standard Glove & Safety Equip. Corp.(D) 053 03 Standard Safety Equipment Co.(M) 053 03 Stauffer Manufacturing Company(M) 053 03 H. Texier Glove Company Inc.(D) 053 03 Wheeler Protective Apparel, Inc.(M) 053 04 Jomac Products Inc.(M) 053 04 Jones Safety Supply, Inc.(D) C— 29 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Fabric (cont.) 053 . 04 Jordan David Safety Products(M) 053 04 Keystone. Protection Corp.(D) 053 04 Major Safety Service, Inc. (D) 053 04 Masterman’s(D) 053 04 Mine Safety Appliances Co.(M) 053 04 OKI Supply Co.(M) 053 04 Plastex Protective Products, Inc.(M) 053 04 Protech Safety Equipment Inc.(D) 053 04 Record Industrial Co.(M) 053 04 Robar Protective Products(D) 053 04 Safeco Inc.(D) 053 04 Safety Engineering & Supply Co.(D) 053 04 Sawyer-Tower(M) 053 04 Tingley Rubber Corp.(M) 053 04 Wheeler Protective Apparel, Inc.(M) 053 05 Major Safety Service, Inc.(.D) 053 05 Safety Engineering & Supply Co.(D) 053 05 Standard Safety Equipment Co.(M) 053 05 Wheeler Protective Apparel, Inc.(M) 053 06 Boss Manufacturing Company(M) 053 06 Jomac Products Inc.(M) 053 06 Jones Safety Supply, Inc.(D) 053 06 Major Safety Service, Inc.(D) 053 06 Plastex Protective Products, Inc.(M) 053 06 Pulmosan Safety Equipment Corp.(D) 053 06 Standard Safety Equipment Co.(M) 053 06 United States Safety Service Co.(D) 053 06 Wheeler Protective Apparel, Inc.°(M) Product: Polyvinyl Chloride, Film 054 01 Defense Apparel(M) 054 01 Durafab Disposables, Inc.(M) 054 01 OKI Supply Co.(M) 054 01 Plastimayd Corp.(M) 054 01 Robar Protective Products(D) 054 02 Defense Apparel(M) 054 02 Durafab Disposables, Inc.(M) 054 03 Durafab Disposables, Inc.(M) 054. 03 Fairway Products(M) 054 03 LRC Safety Products Co.(D) 054 03 Melco, Inc.(M) 054 03 OKI Supply Co.(M) 054 03 Plastimayd Corp.(M) 054 03 Pulmosan Safety Equipment Corp.(D) 054 03 Ronco Textile Products, Inc.(M) 054 04 Defense Apparel(M) 054 04 OKI Supply Co.(M) 054 04 Plastimayd Corp.(M 054 04 Robar Protective Products(D) C— 30 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride, Film (cont.) 054 06 General Scientific Safety Equipment Company(D) 054 06 Melco, Inc.(M) 054 06 Pulmosan Safety Equipment Corp. (D) 054 07 Allied Glove & Safety Products Corp.(M) 054 07 Defense Apparel(M) 054 07 Eastco Industrial Safety Corp.(D) 054 07 General Scientific Safety Equipment Company(D) 054 07 Interex Corp.(D) 054 07 Iron Age Protective Company(M) 054 07 Leonard Safety Epuipment, Inc.(D) 054 07 Melco, Inc.(M) 054 07 Plastex Protective Products, Inc.(M) 054 07 Pulmosan Safety Equipment Corp.(D) 054 07 United States Plastic Corp.(D) Product: Polyvinyl Chloride/Nylon 077 01 Allied Glove & Safety Products Corp.(M) 077 01 Aramsco(M) 077 01 Boss Manufacturing Company(M) 077 01 Direct Safety.Company(D) 077 01 Eastco Industrial Safety Corp.(D) 077 01 Edmont Div. Becton, Dickinson & Co.(M) 077 01 Goodyear Rubber Products Corp.(S) 077 01 Holland Safety Supply Co.(D) 077 01 Industrial Products Co., Inc.(D) 077 01 Industrial Safety and Security Co.(D) 077 01 Interex Corp.(D) 077 01 Jomac Products Inc.(M) 077 01 Jones Safety Supply, Inc.(D) 077 01 Jordan David Safety Products(M) 077 01 Masternian’s(D) 077 01 Miller Products Co., Inc.(D) 077 01 Mine Safety Appliances Co.(M) 077 01 National Safety Wear, Inc.(M) 077 01 01 (1 Supply Co.(M) 077 01 Plastex Protective Products, Inc.(M) 077 01 Protech Safety Equipment Inca (D) 077 01 Rainfair, Inc.(M) 077 01 Robar Protective Products(D) 077 01 Rockfórd Medical & Safety Co.(D) 077 .01 Safeco Inc.(D) 077 01 Safety Engineering & Supply Co.(D) 077 01 Sawyer-Tower(M) 077 01 Standard Glove & Safety Equip. Corp (D) 077 01 Stauffer Manufacturing Company(M) 077 01 H. Texier Glove Company Inc.(D) 077 01 Tingley Rubber Corp.(M) 077 02 Boss Manufacturing Company(M) 077 02 Jomac Products Inc.(M) C— 31 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Nylon (cont.) 077 02 Jones Safety Supply, Inc.(D) 077 02 Miller Products Co., Inc.(D) 077 02 Plastex Protective Products, Inc.(M) 077 03 Boss Manufacturing Company(M) 077 03 Frommelt Industries, Inc.(M) 077 03 Jomac Products Inc.(M) 077 03 Jones Safety Supply, Inc.(D) 077 03 01 (1 Supply Co.(M) 077 03 Plastex Protective Products, Inc.(M) 077 03 Protech Safety Equipment Inc.(D) 077 04 Allied Glove & Safety Products Corp.(M) 077 04 Direct Safety Company(D) 077 04 Eastco Industrial Safety Corp.(D) 077 04 Edmont Div. Becton, Dickinson & Co.(M) 077 04 Goodyear Rubber Products Corp.(S) 077 04 Holland Safety Supply Co.(D) 077 04 Industrial Products Co., Inc.(D) 077 04 Industrial Safety and Security Co.(D) 077 04 Interex Corp.(D) 077 04 Jomac Products Inc.(M) 077 04 Jones Safety Supply, Inc.(D) 077 04 Jordan David Safety Products(M) 077 04 Masterman’s(D) 077 04 Miller Products Co., Inc.(D) 077 04 Mine Safety Appliances Co.(M) 077 04 National Safety Wear, Inc.(M) 077 04 01(1 Supply Co.(M) 077 04 Plastex Protective Products, Inc.(M) 077 04 Protech Safety Equipment Inc.(D) 077 04 Rainfair, Inc.(M) 077 04 Robar Protective Products(D) 077 04 Rockford Medical & Safety Co.(D) 077 04 Safeco Inc.(D) 077 04 Safety Engineering & Supply Co.(D) 077 04 Sawyer-Tower(M) 077 04 Standard Glove & Safety Equip. Corp.(D) 077 04 Stauffer Manufacturing Company(M) 077 04 H. Texier Glove Company Inc.(D) 077 04 Tingley Rubber Corp.(M) 077 05 Mine Safety Appliances Co.(M) 077 06 Allied Clove & Safety Products Corp.(M) 077 06 Boss Manufacturing Company(M) 077 06 Colonial Glove & Garment Inc.(M) 077 06 Direct Safety Company(D) 077 06 Eastco Industrial Safety Corp.(D) 077 06 Edmont Div. Becton, Dickinson & Co.(M) 077 06 Falcon Industries, Inc.(M) 077 06 General Scientific Safety Equipment Company(D) 077 06 Goodyear Rubber Profucts Corp.(S) 077 06 Holland Safety Supply Co.(D) C— 32 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Nylon (cont.) 077 06 Industrial Products Co., Inc.(D) 077 06 Industrial Safety and Security Co.(D) 077 06 Interex Corp.(D) 077 06 Jomac Products Inc.(M) 077 06 Jones Safety Supply, Inc.(D) 077 06 Masterman’s(D) 077 06 Plastex Protective Products, Inc.(M) 077 06 Protech Safety Equipment Inc.(D) 077 06 Pulmosan Safety Equipment Corp.(D) 077 06 Rainfair, Inc.(M) 077 06 Robar Protective Products(D) 077 06 Safeco Inc.(D) 077 06 Standard Glove & Safety Equip. Corp.(D) 077 06 Stauffer Manufacturing Company(M) 077 06 H. Texier Glove CompanyInc.(D) Product: Polyvinyl Chloride, Boots 083 08 Allied Glove & Safety Products Corp.(M) 083 08 Boss Manufacturing Company(M) 083 08 Defense Apparel(M) 083 08 Direct Safety Company(D) 083 08 Eastcó Industrial Safety Corp.(D) 083 08 Interex Corp.(D) 083 08 Iron Age Protective Company(M) 083 08 Jordan David Safety Products(M) 083 08 La Crosse Footwear, Inc.(M) 083 08 Latex Glove Co., Inc(M) 083 08 Lehigh Safety Shoe Co.(M) 083 08 Masterman’s(D) 083 08 Miller Products Co., Inc..(D) 083 08 Protexall Company(M) 083 08 Rainfair, Inc.(M) 083 08 Standard Safety Equipment Co.(M) 083 08 Steele & Associates, Inc.(M) 083 08 Tingley Rubber Corp.(M) 083 08 The Tracies Co.(M) 083 08 Trelleborg, Inc.(M) 083 08 Wheeler Protective Apparel, Inc.(M) Product: Polyvinyl Chloride/Rayon 088 01 Direct Safety Company(D) 088 01 Jomac Products Inc.(M) 088 01 Jones Safety Supply, Inc.(D) 088 01 Protech Safety Equipment Inc.(D) 088 03 Joniac Products Inc.(M) 088 03 Jones Safety Supply, Inc.(D) 088 04 Direct Safety Company(D) 088 04 Jomac Products Inc.(M) C— 33 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Rayon (cont.) 088 04 Jones Safety Supply, Inc.(D) 088 06 Direct Safety Company(D) 088 06 Falcon Industries, Inc.(M) 088 06 Jomac Products Inc.(M) 088 06 Jones Safety Supply, Inc.(D) Product: Polyvinyl Chloride/Fabric/Polyvinyl Chloride 131 01 Eastco Industrial Safety Corp.(D) 131 01 Rainfair, Inc.(M) .131 01 Sawyer-Tower(M) 131 04 Eastco Industrial Safety Corp.(D) 131 04 Rainfair, Inc.(M) 131 04 Sawyer-Tower(M) 131 05 Fyrepel Products Inc.(M) 131 06 Eastco Industrial Safety Corp.(D) 131 06 . Rainfair, Inc.(M) Product: Polyvinyl Chloride/Nylon/Polyvinyl Chloride 133 01 Edmont Div. Becton, Dickinson & Co.(M) 133 01 Goodyear Rubber Products Corp.(S) 133 01 Holland Safety Supply Co.(D) 133 01 Industrial Products Co., Inc.(D) 133 01 Industrial Safety and Security Co.(D) 133 01 Interex Corp.(D) 133 . 01 Masterman’s(D) 133 Cl Plastex Protective Products, Inc.(M) 133 01 Protech Safety Equipment Inc.(D) 133 01 Safeco Inc.(D) 133 01 Standard Clove & Safety Equip. Corp.(D) 133 01 Stauffer Manufacturing Company(M) - 133 01 Superior Surgical Mfg. Co., Inc.(M) 133 01 H. Texier Clove Company Inc.(D) 133 02 . Superior Surgical Mfg. Co., Inc.(M) 133. 03 Edmont Div. Becton, Dickinson & Co.(M) 133 03 Goodyear Rubber Products Corp.(S) 133 03 Holland Safety Supply Co.(D) 133 03 Industrial Products Co., Inc.(D) 133 03 Industrial Safety and Security Co.(D) 133 03 Interex Corp.(D) 133 03 Masterman’s(D) 133 03 Protech Safety Equipment Inc.(D) 133 03 Standard Glove & Safety Equip. Corp.(D) 133 03 . Stauffer Manufacturing Company(M) 133 03, H. Texier Glove Company Inc.(D) 133 04 Edmont Div. Becton, Dickinson & Co.(M) 133. 04 Goodyear Rubber Products Corp. (S) 133 04 . Holland Safety Supply Co.(D) 133 04 Industrial Products Co., Inc.(D) C—34 ------- PRODUCT VENDORS BY. RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: Polyvinyl Chloride/Nylon/Polyvinyl Chloride (cont.) 133 04 Industrial Safety and Security Co.(D) 133 04 Interex Corp.(D) 133 04 Masterman’s(D) 133 04 Plastex Protective Products, Inc.(M) 133 04 Protech Safety Equipment Inc.(D) 133 04 Safeco Inc.(D) 133 04 Standard Glove & Safety Equip. Corp.(D) 133 04 Stauffer Manufacturing Company(M) 133 04 H. Texier Glove Company Inc.(D) 133 . 05 Coodall Rubber Company(M) 133 05 National Draeger, Inc.(M) 133 05 Trelleborg, Inc.(M) 133 06 Edmont Div. Becton, Dickinson & Co.(M) 133 06 Goodyear Rubber Products Corp.(S) 133 06 Holland Safety Supply Co.(D) 133 06 Industrial Products Co., Inc.(D) 133 06 Industrial Safety and Security Co.(D) 133 06 Interex Corp.(D) 133 06 Masterman’s(D) 133 06 Plastex Protective Products, Inc.(M) 133 .06 Protech Safety Equipment Inc.(D) 133 06 Safeco Inc.(D) 133 06 Standard Glove & Safety Equip. Corp.(D) 133 06 Stauffer Manufacturing Company(M) 133 06 H. Texier Glove Company Inc.(D) Product: Polyvinyl Chloride/Polyester .144 03 Steel Grip Safety Apparel Co., Inc.(M) SARANEX(032) Product: PE/Polyvinylidenechloride/PE/Tyvek 061 01 Magid Glove and Safety Mfg. Co.(M) 061 01 Mar-Mac Manufacturing Co., Inc.(M) 061 01 Protech Safety Equipment Inc.(D) 061 .01 Rockford Medical & Safety Co.(D) 061 02 Charkate(M) 061 02 Daffin Disposables, Inc.(M) 061 .02 Durafab Disposables, Inc.(M) 061 02 Industrial Products Co., Inc.(D) 061 02 Industrial Safety and Security Co.(D) 061 02 Kappler Disposables, Inc.(M) 061 02 Magid Glove and Safety Mfg. Co.(M) 061 02 Mar-Mac Manufacturing Co., Inc.(M) 061 02 Melco, Inc.(M) 061 02 Protech Safety Equipment Inc.(D) 061 03 Charkate(M) 061 03 Mar-Mac Manufacturing Co., Inc.(M) C— 35 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name Product: PE/Polyvinylidenechloride/PE/Tyvek (cont.) 061 03 Protech Safety Equipment Inc.(D) 061 04 Magid Glove and Safety Mfg. Co.(M) 061 04 Mar-Mac Manufacturing Co., Inc.(M) 061 04 Protech Safety Equipment Inc.(D) 061 04 Rockford Medical & Safety Co.(D) 061 05 Charkate(M) 061 05 Daffin Disposables, Inc.(M) 061 05 Durafab Disposables, Inc.(M) 061 05 Hub Safety Equipment, Inc.(D) 061 05 Leonard Safety Epuipment, Inc.(D) 061 05 Mar-Mac Manufacturing Co., Inc.(M) 061 05 Mar-Mac Manufacturing Co., Inc.(M) 061 05 Mine Safety Appliances Co.(M) 061 05 Rockford Medical & Safety Co.(D) 061 06 Industrial Products Co., Inc.(D) 061 06 Industrial Safety and Security Co.(D) 061 06 Kappler Disposables, Inc.(M) 061 06 Protech Safety Equipment Inc.(D) 061 07 Daffin Disposables, Inc.(M) 061 07 Industrial Products Co., Inc.(D) 061 07 Industrial Safety and Security Co.(D) 061 07 Kappler Disposables, Inc.(M) 061 07 Mar-Mac Manufacturing Co., Inc.(M) SBR (033) Product: Styrenebutadiene Rubber/Fabric 063 01 Eastco Industrial Safety Corp.(D) 063 01 Rainfair, Inc.(M) 063 01 Safety Engineering & Supply Co.(D) 063 01 Tingley Rubber Corp.(M) 063 03 Protexall Company(M) 063 04 Eastco Industrial Safety Corp.(D) 063 04 Rainfair, Inc.(M) 063 04 Safety Engineering & Supply Co.(D) 063 04 Tingley Rubber Corp.(M) 063 06 Eastco Industrial Safety Corp.(D) 063 06 Rainfair, Inc.(M) SBR/NEOPRENE (047) Product: Styrenebutadiene/Cotton/Chloroprene 149 03 Steel Grip Safety Apparel Co., Inc.(M) SILVER SHIELD(042) Product: Silver Shield (North Product), Glove 122 00 Arbill Inc.(D 122 00 North Hand Protection(M) C—36 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name TEFLON(014) Product: FEP Glove 036 00 Clean Room Products, Inc.(M) Product: TFE/Nomex/TFE 069 05 Chemical Fabrics Corporation(M) Product: TFE/Fibergiass/TFE 146 05 Chemical Fabrics Corporation(M) VITON(034) Product: Fluoroelastomer Clove, Solvent Dipped, Unsupported 009 00 Direct Safety Company(D) 009 00 Hub Safety Equipment, Inc.(D) 009 00 Latex Clove Co., Inc(M) 009 00 Mine Safety Appliances Co.(M) 009 00 North Hand Protection(M) 009 00 Protech Safety Equipment Inc.(D) 009 00 Safeco Inc.(D) Product: Fluoroelastomer, Sheet 032 01 Mine Safety Appliances Co.(M) 032 04 Mine Safety Appliances Co.(M) 032 05 Andover Industries, Inc.(M) Product: Fluoroelastomer/Fabric/Fluoroelastomer 129 05 Fyrepel Products Inc.(M) Product: Fluoroelastomer/Polyester/Fluoroelastomer 143 03 Steel Grip Safety Apparel Co., Inc.(M) 143 04 Superior Surgical Mfg. Co., Inc.(M) VITON/BUTYL(035) Product: Fluoroelastomer/Butyl/Nylon/Butyl 100 02 Trelleborg, Inc.(M) 100 05 Coodall Rubber Company(M) 100 05 Trelleborg, Inc.(M) C— 37 ------- PRODUCT VENDORS BY RESISTANT MATERIAL Resistant Material Code Type Vendor Name VITON/CHLOROBUTYL(036) Product: Fluoroelastomer/Noniex/Chlorobutyl 152 05 Andover Industries, Inc.(M) VITON/NEOPRENE (011) Product: F luoroe lastomer/Nylon/Ch loroprene 111 05 Mine Safety Appliances Co.(M) lii 05 National Draeger, Inc.(M) C—38 ------- APPENDIX D VENDOR DIRECTORY D- 1 ------- VENDOR DIRECTORY Ackwell Address not available. Acme Mills Company 5151 Loraine Detroit, MI 48208 313/894-7110 Alliance Supply, Inc. 3 Bridge Street Newton, MA 02158 617/244-2900 Allied Glove & Safety Products Corp. 325 E. Chicago Street Milwaukee, WI 53202 414/272-0302 American Scientific Products Division of American Hospital Suppl 1430 Waukegan Road McGaw Park, IL 60085 800/842-1208 Andover Industries, Inc. 15 Union Street Lawrence, MA 01840 617/794-1793 Angelica Uniform Group 700 Rosedale Avenue St. Louis, MO 63112 800/325-8032 D—2 ------- VENDOR. DIRECTORY Ansell Industrial Products Industrial Road P.O. Box 1252 Dothan, AL 36302 800/633-0909 Aramsco Thorofare, NJ 08086 800/257-8146 Arbill Inc. 2207 W. Glenwood Avenue Philadelphia, PA 19132 215/228-4011 Arniin Corporation One Penn Plaza New York, NY 10119 212/736-2201 Arrowhead Products 4411 Katella Avenue Los Alamitos, CA 90720 714/828-7770 Bard Parker Address not available. Barry Manufacturing Co. Ltd. 920 Lakeshore Road East Mississauga, ON CAN 416/274- 3691 D—3. ------- VENDOR DIRECTORY Bel-Art Products Industrial Road Pequannock, NJ 07440 201/694-0500 Best Manufacturing Company Edison Street Menlo, GA 30731 800/241-0323 Body-Guard Division of Lion Uniform Inc. P.O. Box 14343 Dayton, OH 45414 714/540-8010 Boss Manufacturing Company 221 W. First Street • Kewanee, IL 61443 309/852-2131 •Broner Glove Co. 359 Robbins Drive Troy, MI 48084 800/521-1318 •E.D. Bullard Company 2680 Bridgeway Sausalito, CA 94965 415/332-0410 California Safety Address not available. D—4 ------- VENDOR DIRECTORY Cesco Safety Products 1535 Walnut Steet Kansas City, MO 64108 816-842-8500 Charkate 130 West 10th Street Huntington Station, NY 11746 516/427-1802 Chemical Fabrics Corporation Daniel Webster Highway P.O. Box 1137 Merrimack, NH 03054 603/424-9000 Clean Room Products, Inc. 1800 Ocean Avenue Ronkonkoma, NY 11779 516/588-7000 Cofish International, Inc. P.O. Box 13 East Haddam, CT 06423 203/873-9500 Colonial Glove & Garment Inc. 1800 Ocean Avenue Ronkonkoma, NY 11779 516/588-6900 Comasec Drawer 10 Niblick Road Erifield, CT 06082 203/741-2207 D—5 ------- VENDOR DIRECTORY Converse Inc. 55 Fordham Road Wilmington, MA 01887 617/657-5500 Coyne Safety Equipment, Inc. 725 Route 113 P.O. Box 390 .Sellersvifle, PA 18960 215/723-0926 i affin Disposables, Inc. One Daff in Square Secretary, MD 21664 301/943-8777 Dayton Flexible Products Division of Baxter Travéno]. 2210 Arbor Boulevard Dayton, OH 45439 513/298-7511 Defense Apparel 247 Addison Road Windsor, CT 06095 800/243-3847 Direct Safety Company 7815 South 46th Street Phoenix, AZ 85044 800/528 - 7405 Disposablés Inc. 14 Locust Street Manhasset, NY 11030 516/627-4554 D—6 ------- VENDOR DIRECTORY Dorsey Safety Products Co. P.O. Box 23465 Chattanooga, TN 37422 615/894-7233 Dow Chemical Company 2020-T Dow Center Midland, MI 48640 517/636-1000 E.I. du Pont de Nemours & Co., Inc. Spunbonded Products Division Centre Road Building Wilmington, DE 19898 302/999-3095 E.I. du Pont de Nemours & Company Business and Marketing Service Elastomers Wilmington, DE 19898 800/441-7111 Durafab Disposables, Inc. Box 658 Cleburne, TX 76031 817/645-8851 Eastco Industrial Safety Corp. 130 West 10th Street Huntington Station, NY 11746 516 64427-1802 Edniont Div. Becton, Dickinson & Co. 1300 Walnut Street Coshocton, OH 43812 614/622-4201 D—7 ------- VENDOR DIRECTORY Elliott Glove Company, Inc. 504 Pecor Street Oconto, WI 54153 414/834-5622 Encon Manufacturing Co. 13333 Northwest Freeway P.O. Box 3826 Houston, TX 77253 713/462-4723 Erista Rex Gummiwarenfabrjc Gnibh D- 6102 Pfungstadt, FRG Exxon Chemical Company Polymers Group A Division of Exxon Corporation P.O. Box 3272 Houston, TX 77253 713/870-6546 Fairway Products 303 Arch Street Hilisdale, MI. 49242 517/439-9376 Falcon Industries, Inc. 401 Isom Road San Antonio,. TX 78216 512-344-3469 Fisher Scientific Company 711 Forbes Avenue Pittsburg, PA 15219 41.2/562-8300 D—8 ------- VENDOR, DIRECTORY Frommelt Industries, Inc. Safety Products Division 4343 Chavenelle Drive P .O. Box 658 Dubuque, IA 52004 800/553-5560 Fyrepel Products Inc. Box 518 Newark, OH 43055 614/344-0391 General Scientific Safety Equipment Company 1821 John F. Kennedy Boulevard Philadelphia, PA 19103 215/564-6366 Clover Latex, Inc. 514 S. Rose Street P.O. Box 167 Anaheim, CA 92805 714/535-8920 Coodall Rubber Company P.O. Box 8237 Trenton, NJ 08650 609/587-4000 Goodyear Rubber Products Corp. 329 McCarter Highway Newark, NJ 07114. 201/242-5550 Granet 25 Loring Drive P.O. Box 588 Framingham, MA 01701 617/875-3521 D-9 ------- VENDOR DIRECTORY Greene Rubber Co., Inc. 160 Second Street Cambridge, MA 02142 617/547-7655 Halprin Supply Co. 3804 S. Broadway P1. Los Angeles, CA 90037 213/232-3131 Handgards Inc. 901 Hawkins P.O. Box 27018 El Paso, TX 79926 915/779-6606 Holcomb Safety Garment Co. 4925 W. Grand Avenue Chicago, IL 60639 312/648- 1778 Holland Safety Supply Co. P.O. Box 645 208 Market Street Lexington, NC 27292 800/222-8133 Hub Safety Equipment, Inc. 121 Liberty Street P.O. Box 454 South Quincy, MA 02269 617-773-2487 Hy-Test Safety Shoes Div. International Shoe Company P.O. Box 14485 St. Louis, MO 63178 314/426- 1675 D—10 ------- VENDOR DIRECTORY ILC Dover P.O. Box 266 Frederica, DE 19946 302/335-3911 IPESCo.,; Inc. 1903 Sharon Forest Drive Charlotte, NC 28212 704/535-5550 Inco Safety Products Co. Box 1733 Reading, PA 19603 215/376-6161 Industrial. Products Co., Inc. 21 Cabot Blvd.. Langhorne, PA 19047 800/523-3944 Industrial Safety and Security Co. 1390 Newbrecht Road Lima, OH 45801 800/537-9721 Interex Corp. 3 Strathmore Rd. Natick, MA 01760 800/225-5910 Interniarket Latex, Inc. 213 Hanna Building Cleveland, OH 44115 800/824- 7419 D—11 ------- VENDOR. DIRECTORY, International Playtex, Inc. Glove Division 700 Fairfield Ave. Stamford, CT 06902 203/356-8000 Iron Age Protective Company 2406 Woodmere Drive Pittsburgh, PA 15205 412/922-7000 Jomac Products Inc. 863 Easton Road Warrington, PA 18976 215/343-0800 Jones Safety Supply, Inc. 719 Gainsboro Road, NW P.O. Box 111 Roanoke, VA 24002 703/982-8444 Jordan David Safety Products P.O. Box 400 Warrington, PA 18976 215/343-6470 KID AB S- 71100 Lindesberg, Sweden Kappler Disposables, Inc. P.O. Box 218 Guntersville, AL 35976 800/633-2410 D—12 ------- VENDOR. DIRECTORY Keller Clove Mfg. Co. Route 611 Plumsteadville, PA 18949 215/343-1135 Keystone Protection Corp. 520 E. Luzerne Street Philadelphia, PA 19124 215/426-3600 Kimberly-Clark Corp. Industrial Garments Fabrics 1400 Holcomb Bridge Road Roswell, GA 30076 404/587-8000 LRC Safety Products Co. Rt. 46 West Little Falls, NJ 07424 201/256-4100 La Crosse Footwear, Inc. P.O. Box 1328 La Crosse, WI 54602 608/782-3020 Lab Safety Supply Company Div. Science Related Materials, Inc. 3430 North Palmer Drive Janesville, WA 53547 608/754-2345 Latex Glove Co., Inc 318 Huehi Road Northbrook, IL 60062 800/323-8393 D—13 ------- VENDOR DIRECTORY Lehigh Safety Shoe Co. Division of Endicott Johnson 1100 E. Main Street Endicott, NY 13760 607/754-7980 Leonard Safety Epuipment, Inc. 253 Waterman Ave. P.O. Box 4344 E. Providence, RI 02914 800/556-7170 Lion Uniform, Inc. 2735 Kearns Avenue Dayton, OH 45414 513/278-6531 Magid Glove and Safety Mfg. Co. 2060 N. Kolmar Ave. • Chicago, IL 60639 312/384-2070 Major Safety Service, Inc. 4500 Patent Rd. Norfolk, VA 23502 800/446 - 8274, Mar-Mac Manufacturing Co., Inc. • P.O. Box 278 McBee, SC 29101 803/335-8211 Marathon Rubber 510 Sherman Street Wausau, WI 54401 715/845-6255 ------- VENDOR ’ DIRECTORY Masterman’s Auburn Industrial Park P.O. Box 224 Auburn, MA 01501 617/755-7861 Melco, Inc. 6603 Governor Printz Blvd. Wilmington, DE 19809 800/441-9749 Memphis Glove Company Division of Shelby Group, Inc. P.O. Box 171814 Memphis, TN 38187 ‘901/795-0672 Miller Products. Co., Inc. 29 Warren Street New York, NY 10007 212-267-5334 Mine Safety Appliances Co. 608 Penn Center Blvd. Pittsburgh, PA 15235 800/672-2222 Monte Glove Company Monte Lane Maben, MI 39750 601/263-5353 National Draeger, Inc. 101 Technology Drive P.O. Box 120 Pittsburgh,. PA 15230 412/787-8383 D- 15 ------- VENDOR; DIRECTORY National Safety Wear, Inc. 18 East Main St. Malone, NY 12953 518/483-7246 Neese Industries Inc. P.O. Box 628 Gonzales, LA 70737 .800/535-8042 Nolato Address not available. ‘North Hand Protection A Division of Siebe North,’ Inc. 4090 Azalea Drive P.O. Box 70729 Charleston, SC 29405 803/554-0660 OKI Supply Co. 7584 Reinhold Drive Cincinnati, OH 45237 513/761-9811 Oak Medical Supply Co. Subsidiary of The Oak Rubber Company 219 S. Sycamore Street Ravenna, OH 44266 216-296-3416 Oak Technical, Inc. 218 Sycamore Street Ravenna, OH 44266. ‘216/296-3416 D- 16 ------- VENDOR DIRECTORY PPG Industries, Inc. Optical Products, Chemical One PPG Place Pittsburgh, PA 15272 412/434-3751 Panelgraphic Corporation 10 Henderson Drive W. Caidwell, NJ 07006 800/222-0618 Pendergast Safety Equipment Co. 6900 Tulip St. Philadelphia, PA 19135 215/332- 1663 Pharmaseal Laboratories Inc. 1015 Grandview Avenue Glendale, CA 91201 213/240-8900 Pioneer Industrial Products Co. 512 East Tiffin Street Willard, OH 44890 419/933-2211 Plastex Protective Products, Inc. 9 Grand Street P.O. Box 57 Garfield, NJ 0702.6 201/779-4946 Plastimáyd Corp. . 2204 S.E. Seventh Avenue P.O. Box 14217 Portland, OR 97214 503/232- 5101 D—17 ------- VENDOR DIRECTORY Protech Safety Equipment Inc. P.O. Box 455 Linden, NJ 07036 201/862-1550 Protexall Company P.O. Box 307 Green Lake, WI 54941 414/294-6511 Pulmosan Safety Equipment Corp. 30-48 Linden Place Flushing, NY 11354 212/939-3200 Rainfair, Inc. P.O. Box 1647 Racine, WI 53401 800/558-5990 Ranger Division of Endicott Johnson 1100 E. Main St. Endicott, NY 13760 607/757-4260 Record Industrial Co. 1020 Eighth Avenue P.O. Box 407 King of Prussia, PA 19406 215/337-2500 Renco Corp 2060 Fairfax Avenue Cherry Hill, NJ 08003 609/424-5755 D-18 ------- VENDOR. DIRECTORY Rich Industries ‘Address not available. Robar Protective Products 2213 W. Glenwood Avenue Philadelphia, PA 19132 800/523-5367 Rockford Medical & Safety Co. 4620 Hydraulic Rd. P.O. Box 5166 Rockford, IL 61125 815/874-7891 Ronco Textile Products, Inc. 1405 East Lake Avenue Peoria Heights, IL 61614 309/685-7266 SGL Honialite Industries P.0 :. 3049 Wilmington, DL 19804 302/652-3686 Safeco Inc. 337 E. Center Street P.O. Box 28 Kingsport, TN 37660 615/246-3552 - Safety Engineering & Supply Co. P.O. Box 147 Deer Park, TX 77536 713/476-9118 D- 19 ------- VENDOR:. DIRECTORY Safety First Industries 4900 Campbell Road • Willoughby, OH 44094 216/946-1880 The Sager Corporation 65 E. Palatine Road ‘Prospect Heights, IL 60070 312/541-1361 W.H. Salisbury & Co. Box 1060 • 7520 N. Long Avenue Skokie, IL 60077 312/679-6700 Sawyer-Tower Division of Lion Uniform 2735 Kerns Avenue - Dayton, OH 45414 Seiberling Address not available. Shelby-Wolverine Glove Coi pany P.O. Box 8735 Grand Rapids, MI 49518 616/698-7220 Singer Safety Co. 3800 N. Milwaukee Ave. Chicago, IL 60641 312/286-1000 D-2O ------- VENDOR DIRECTORY Standard Glove & Safety Equip. Corp. 34300 Lakeland Boulevard Eastlake, OH 44094 216-951-7440 Standard Safety Equipment Co. P.O. Box 188 Palatine, IL 60078 312/359-1400 Stauffer Manufacturing Company P.O.. Box 45 6th Street Red Hill, PA 18076 215/679 -4446 Steel Grip Safety Apparel Co., Inc. 700 Garfield Street Danville, IL 61832 217/442-6240 Steele & Associates, Inc. P.O. Box 20368 Seattle, WA 98102 206/3 24- 9445 Superior Surgical Mfg. Co., Inc.. Superior Surgical Park Seminole Boulevard at 100th Terrace Seminole, FL 33542 813/397-9611 Surety-Sure Seal Address not available. D—21 ------- VENDOR DIRECTORY H. Texier Clove Company Inc. Highway 22 at Mountain Avenue North Plainfield, NJ 07061 201/757-0616 3M Company 3M Center Bldg. 220-7W St. Paul, MN 55144 612/733-6234 Tingley Rubber Corp. P.O. Box 100 South Plainfield, NJ 07080 201/757-7474 The Tracies Co. 102 Cabot St. Holyoke, MA 01040 413/533-7141 Trelleborg, Inc. 30700 Solon Industrial Parkway Solon, OH. 44139 216/248-8600 United States Plastic Corp. 1390 Neubrecht Road Lima, OH 45801 419/228-2242 United States Safety Service Co. 1535 Walnut St. P.O. Box 1237 Kansas City, MO 64141 816/842-8500 D—22 ------- VENDOR. DIRECTORY. Vidaro Corp. 333-T Martinel. Drive P.O. Box 535-T Kent, OH 44240 216/673-7413 Viny lprodukter S -261 23 Landskrôna, Sweden Wheeler Protective Apparel, Inc. 4330 W. Belmont Ave. Chicago, IL 60641 312/685- 5551 Wilison Safety Products P.O. Box 622 Reading, PA 19603 215/376- -6161 D—23 ------- APPENDIX E PRODUCT DESCRIPTION CODE E— 1 ------- PRODUCT DESCRIPTION CODES AND RESISTANT MATERIALS INDICATES A LAYERED (EITHER COATED OR LAMINATED) MATERIAL STRUCTURE. LAYERS ARE DESCRIBED BEGINING WITH THE EXTERIOR SURFACE. hI÷tt INDICATES A POLYMER BLEND. SUPPORTED: BARRIER MATERIAL IS COATED ONTO A CLOTH GLOVE. UNSUPPORTED: BARRIER MATERIAL IS PRESENT AS A FREE-STANDING OR FLOCKED MEMBRANE. NOTE: FABRICS SUCH AS DISPOSAGUARD, DURACUARD, GOR-TEX, SAFE-GUARD, SONTARA, AND TYVEK ARE NOT COATED AND, THEREFORE, ARE PERMEABLE TO AIR AND MORE COMFORTABLE TO WEAR. THEY ARE PRIMARILY RECOMMENDED AS BARRIERS TO PARTICULATES. CAUTION IS RECOMMENDED WHEN USING THESE FABRICS AS SPLASH PROTECTION SINCE THEY ARE RAPIDLY PENETRATED BY GASES AND MANY ORGANIC LIQUIDS. E- 2 ------- Product Description Codes and Resistant Materials (in numerical order - - alphabetical listing follows) Product Resistant Code Material Product Description 001 NATURAL RUBBER Natural Rubber Latex Glove, Supported 002 NEQPRENE Chloroprene Latex Glove, Supported 003. PVC Polyvinyl Chloride Glove, Unsupported 004 PV ALCOHOL Polyvinyl Alcohol Glove, Supported 005 NITRILE Nitrile Rubber Latex Glove, Supported 006 PE Polyethylene Glove, Unsupported 007 PVC Polyvinyl Chloride Glove, Supported 008 NEOP/NAT RUBBER Cloroprene/Natural Rubber Latex Glove, Unsupported 009 VITON Fluoroelastomer Glove, Solvent Dipped, Unsupported .010 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Unsupported 011 NEOPRENE . Chloroprene Rubber Latex (Baypren) Glove, Unsupported 012 BUTYL Butyl Rubber Latex Glove, Unsupported 013 BUTYL Butyl Rubber Latex Glove, Supported 014 BUTYL Butyl Rubber Glove, Solvent Dipped, Unsupported 015 NATURAL RUBBER Natural Rubber Glove, Solvent Dipped, Unsupported 016 BUTYL/NAT RUBBER Butyl/Natural Rubber Latex Glove, Supported 017 NATURAL RUBBER Natural Rubber Latex Glove, Unsupported 018 NEOPRENE . Chioroprene Rubber Latex Glove, -Unsupported 019 NITRILE Nitrile Rubber Latex Glove, Unsupported 020 NITRILE Nitrile Rubber Glove, Solvent Dipped, Unsuppor.ted 022 VITON/NEOPRENE Fluoroelastomer/Chloroprene Glove, Solv Dipped, Unsupp 023 NAT+NEOP+NBR Natural Rubber+Chloroprene+Nitrile Glove, Unsupported 025 NONWOVEN FABRIC Sontara 026 NEOP+NAT RUBBER Chloroprene+Natural Rubber Latex Glove, Unsupported 027 POLYURETHANE Polyurethane Rubber, Unsupported 028 PVC . Polyvinyl Chioride/Tyvek 029 PTX Polymethylpentane, Face Shield 030 PVC Polyvinyl Chloride, Face Shield 031 NEOPRENE Chloroprene Rubber, Sheet 032 VITON Fluoroelastomer, Sheet 033 NI.TRILE Nitrile Rubber, Sheet 034 BUTYL Butyl Rubber, Sheet 035 PVALCOHOL Polyvinyl Alcohol, Sheet 036 TEFLON FEP Glove 040 . POLYURETHANE Polyurethane Rubber/Polyester 041 PE Polyethylene, High Density, Film 042 FE Polyethylene, Medium Density, Film 044 TEFLON FEP Glove (Crumpled) 045 NATURAL RUBBER Natural Rubber, Sheet 046 BUTYL/NEOPRENE Butyl/Chloroprene Rubber, Boots 047 SBR . Styrenebutadiene Rubber Latex Glove .048 PE Polyethylene, Low Density, Film 049 PVC Polyvinyl Chloride, Sheet 050 POLYURETHANE Polyurethane Rubber/Nylon 051 NEOPRENE Chlor.oprene Rubber/Polyester 052 CHLOROBUTYL Chlorobutyl Rubber/Nomex .053 PVC Polyvinyl Chloride/Fabric 054 PVC Polyvinyl Chloride, Film 055 TEFLON FEP/Fiberglass 056 PE . Polyethylene, Density Unknown, Film 057 NITRILE+PVC Nitrile+PVC Glove, Supported E- 3 ------- 058 NITRILE+PVC 059 NITRILE 060 CPE 061 SARANEX 062 TEFLON 063 SBR 064 BUTYL 065 NEOPRENE+SBR RUBBER 0 6 NEOPRENE+SBR RUBBER 067 TEFLON 068 TEFLON 069 TEFLON 070 CPE 071 NONWOVEN PE 072 TEFLON 073 TEFLON 074 EVA 075 FE. 076 .PE 077 PVC 078 NITRILE 079 GORE -TEX 080 NATURAL RUBBER 081 NEOPRENE 082 POLYURETHANE 083 PVC 084 NITRILE 085 BUTYL 086 NONWOVEN PP 087 NATURAL RUBBER 088 PVC 089 NATURAL RUBBER 090 VITON. 091. FE 092 ‘GORE-TEX 093 NEOPRENE 094 CE’LLULOSE 095 CR 39 096 POLYESTER 097 ACRYLIC 098 POLYCARBONATE 099 CELLULOSE ACETATE 100 VITON/BUTYL 101 VITON/NITRILE 102 PV ALCOHOL 103 EPDM/BUTYL 104 HYPALON/NEOPRENE 105 FE 106 PVC 107 BUTYL 108 HYPALON Product Resistant Code Material Product Description Codes and Resistant Materials (in numerical order - - alphabetical listing follows) Product Description Nitrile+FVC/Fabrjc Nitrile Rubber/Polyester Chlorinated Polyethylene FE/Polyvinyl idenechlor ide/PE/Tyvek FEP/Nylon Styrenebutadiene Rubber/Fabric Butyl Rubber/Nylon Chloroprene (35%)+SBR(65%)/Nylon- -Tufflon Chloroprene(15%)+SBR(85%)/Cotton- -Tuffprene TFE/Nomex FEP/Noniex TFE/Nomex/TFE Chlorinated Polyethylene/Nylon • Tyvek TFE/Nomex/TFE Glove FEP, Face Shield and Lens Ethylene(86%) Vinyl Acetate(14%)/Polyester • Polyethylene/Sontara P0 lye thylene/Tyvek Polyvinyl Chloride/Nylon Nitrile Rubber/Nylon Microporous Teflon/Noniex Natural Rubber, Boots Chlóroprene Rubber, Boots Polyurethane Rubber, Boots Polyvinyl Chloride, Boots Nitrile Rubber, Boots Butyl Rubber, Boots Safeguard, Duraguard, Corovin Natural Rubber/Nylon Polyvinyl Chloride/Rayon Natural Rubber/Cotton Fluoroelastomer/Fiberglass Polyethylene/Fabric Microporous Teflon/Polyester Chloroprene Rubber/Nylon Cellulose Propionate, Face Shield and Lens Cr 39, Lens and Face Shield Polyester, Face Shield and Lens Acrylic, Face Shield and Lens Polycarbonate, Lens and Face Shield Cellulose Acetate, Face Shield and Lens Fluoroelas torner/Butyl/Nylon/Butyl Fluoroelastomer/Nitrile Rubber Glove, Unsupported Polyvinyl Alcohol Glove, Unsupported Ethylenepropylene/Butyl Rubber Glove, Unsupported Chlorosulfonated Polyethylene/Chloroprene Cloy, Unsupp Polyethylene/Polypropylene Nonwoven • Polyvinyl Chloride Glove, Kid 490, Supported Butyl Rubber/Nomex Chiorosulfonated Polyethylene Rubber Glove, Unsupp PROPIONATE E-4 ------- 10 9 110 111 112 113 114 115 116 117 118 119 122 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 152 153 Product Description Codes and Resistant Materials (in numerical order - - alphabetical listing follows) Product Resistant Code Material PE/EVOH/PE • BIJTYL/NEOPRENE • VITON/NEOPRENE VITON/CHLOROBUTYL ECO/BUTYL VITON/BUTYL BIJTYL/NEOPRENE BUTYL/NEOPRENE HYPALON , •BUTYL HYPALON/NEOPRENE SILVER SHIELD PV ACETATE NEOPRENE NEOP+NAT RUBBER NEOPRENE+PVC ETHYLENE-METHYL ACRL VITON BUTYL PVC NITRILE PVC PE NONWOVEN PP NATURAL RUBBER PE NEOPRENE NEOPRENE BUTYL NEOPRENE CHLOROBUTYL VITON PVC VITON TEFLON NITRILE NEOPRENE SBR/NEOPRENE NITRILE+PVC NITRILE+PVC VITON/CHLOROBUTYL Product Description PE/Ethylene Vinyl Alcohol/PE Glove, Unsupported Butyl/Polyes ter/Chioroprene Rubber Fluoroelas tomer/Nylon/Chloroprene Fluoroelas tomer/Polyester/Chlorobutyl Epichiorohydrin/Butyl Rub Glove, Solv Dipped, Unsupp Fluoroelastomer/Butyl Glove, Solvent Dipped, Unsupported Butyl/Chloroprene Rubber Glove, Supported Butyl/Chloroprene Rubber Glove, Unsupported Hypalon/Po lyes ter/Hypalon Butyl/Polyester/Butyl Rubber Hypalon/Polyes ter/Chloroprene Silver Shield (North Product), Glove Polyvinyl Acetate, Sheet Chioroprene Milled/Chloroprene Latex Glove, Supported Chloroprene+Nat Rub/Chloroprene+Nat Rub, Unsupported Chloroprene+PVC/Pblyester Ethylene-methyl Acrylate Glove Fluoroelastomer/Fabric/Fluoroelas tomer Butyl/Fabric/Butyl Polyvinyl Chloride/Fabric/Polyvinyl Chloride Nitrile/Fabric Polyvinyl Chloride/Nylon/Polyvinyl Chloride Polyethylene/Nylon Polypropylene, Nonwoven Natural Rubber/Polyester Polyethylene/Polyester Chloroprene Rubber/Fabric Chloroprene/Fabr ic/Chloroprene Butyl/Nylon/Butyl Chloroprene Rubber/Keviar Chlorobutyl/Nomex/Chlorobutyl Fluoroelastomer/Polyester/Fluoroelas tomer Polyvinyl Chloride/Polyester Fluoroelastomer/Dacron TFE/Fiberglass/TFE Nitrile/Fabric/Nitrile Chloroprene/Cotton/Chloroprene S tyrenebutadiene/Cotton/Chloroprene Nitrile+PVC Boot Nitrile+PVC/Fabric/Nitrile+PVC Fluoroelas tomer/Nomex/Chlorobutyl E—5 ------- Product Description Codes and Resistant Materials (in alphabetical order of resistant material) Product Resistant Code Material Product Description 097 ACRYLIC Acrylic, Face Shield and Lens 012 BUTYL Butyl Rubber Latex Clove, Unsupported 013 BUTYL Butyl Rubber Latex Clove, Supported 014 BUTYL Butyl Rubber Clove, Solvent Dipped, Unsupported 034 BUTYL Butyl Rubber, Sheet ‘064 BUTYL Butyl Rubber/Nylon 085 BUTYL Butyl Rubber, Boots 107 BUTYL Butyl Rubber/Nomex 118 BUTYL Butyl/Polyester/Butyl Rubber 130 BUTYL Butyl/Fabric/Butyl 140 BIJTYL Butyl/Nylon/Butyl. 016 BUTYL/NAT RUBBER Butyl/Natural Rubber Latex Glove, Supported 046 BUTYL/NEOPRENE Butyl/Chloroprene Rubber, Boots 110 BUTYL/NEOPRENE Butyl/Polyester/Chloroprene Rubber 115 BUTYL/NEOPRENE Butyl/Chloroprene Rubber Clove, Supported 116 BUTYL/NEOPRENE Butyl/Chioroprene Rubber Glove, Unsupported 099 CELLULOSE ACETATE Cellulose Acetate, Face Shield and Lens 094, CELLULOSE PROPIONATE Cellulose Propionate, Face Shield and Lens 052’ .CHLOROBUTYL Chlorobutyl Rubber/Nomex 142 CHLOROBUTYL Chlorobutyl/Nomex/Chlorobutyl 060 CPE Chlorinated Polyethylene 070 ‘CPE Chlorinated Polyethylene/Nylon 095 CR 39 Cr 39, Lens and Face Shield 113 ECO/BUTYL Epichlorohydrin/Butyl R xb Glove, Solv Dipped, Unsupp 103 EPDM/BUTYL Ethylenepropylene/Butyl Rubber Clove, Unsupported 128 ETHYLENE-METHYL ACRL Ethylene-methyl Acrylate Glove 074 EVA Ethylene(86%) Vinyl Acetate(l4%)/Polyester 079 CORE-TEX Microporous Teflon/Nomex 092 CORE-TEX Microporous Teflon/Polyester 108 HYPALON Chlorosulfonated Polyethylene Rubber Glove, Unsupp 117 HYPALON Hypa lon/Polyester/Hypalon 104 HYPALON/NEOPRENE Chlorosulfonated Polyethylene/Chloroprene Cloy, Unsupp 119 HYPALON/NEOPRENE Hypalon/Po lyes ter/Chioroprene 023 •NAT+NEOP+NBR Natural Rubber+Chloroprene+Nitrile Glove, Unsupported 001 ‘NATURAL RUBBER Natural Rubber Latex Glove, Supported 015 NATURAL RUBBER Natural Rubber Glove, Solvent Dipped, Unsupported 017 NATURAL RUBBER Natural Rubber Latex Glove, Unsupported 045 NATURAL RUBBER Natural Rubber, Sheet 080 NATURAL RUBBER Natural Rubber, Boots 087 NATURAL RUBBER Natural Rubber/Nylon 089 NATURAL RUBBER Natural Rubber/Cotton 136 NATURAL RUBBER Natural Rubber/Polyester 026 NEOP+NAT RUBBER Chloroprene+Natural Rubber Latex Glove, Unsupported 126 NEOP+NAT RUBBER Chloroprene+Nat Rub/Chloroprene+Nat Rub, Unsupported 008 NEOP/NAT RUBBER Cloroprene/Natural Rubber Latex Glove, Unsupported 002 NEOPRENE Chloroprene ‘Latex Glove, Supported 010 NEOPRENE , Chloroprene Milled/Chloroprene Latex Glove, Unsupported 011 NEOPRENE Chloroprene Rubber Latex (Baypren) Glove, Unsupported 018 NEOPRENE Chioroprene Rubber Latex Glove,Unsupported 031 NEOPRENE Chloroprene Rubber, Sheet 051 NEOPRENE ‘ Chloroprene Rubber/Polyester E— 6 ------- Product Description Codes and Resistant Materials (in alphabetical order of resistant material) Product Description Unsupported Product Resistant Code Material 081 NEOPRENE Chloroprene Rubber, Boots • 093 NEOPRENE Chloroprene Rubber/Nylon 125 NEOPRENE Chloroprene Milled/Chloroprene Latex Glove, Support ..4 138 NEOPRENE Chloroprene Rubber/Fabric 139 NEOPRENE Chloroprene/Fabric/Chloroprene 141 NEOPRENE Chloroprene Rubber/Keviar , 148 NEOPRENE Chloroprene/Cotton/Chloroprene 127 NEOPRENE+PVC Chloroprene+PVC/Po lyester 065 NEOPRENE+SBR RUBBER Chioroprene (35%)±SBR(65%)/Nylon- -Tufflon 066 -NEOPRENE+SBR RUBBER Chloroprene(15%)+SBR(85%)/Cotton- -Tuffprene • 005 NITRILE Nitrile Rubber Latex Glove, Supported • 019 NITRILE Nitrile Rubber Latex Glove, Unsupported 020 NITRILE Nitrile Rubber Glove, Solvent Dipped, Unsupported 033 NITRILE Nitrile Rubber, Sheet Nitrile Rubber/Polyester 059 NITRILE 078 NITRILE Nitrile Rubber/Nylon 084 NITRILE Nitrile Rubber, Boots 132 NITRILE Nitrile/Fabric 147 NITRILE Nitrile/Fabric/Nitrile • 057 NITRILE+PVC Nitrile+PVC Glove, Su ported 058 NITRILE+PVC Nitrile+PVC/Fabric 150 NITRILE+PVC Nitrile+PVC Boot 152 NITRILE+PVC Nitrile+PVC/Fabric/Nitrile+PVC 025 NONWOVEN FABRIC Sontara 071 NONWOVEN PE Tyvek 086 NONWOVEN PP Safeguard, Duraguard, Corovin 135 NONWQVEN PP Polypropylene, Nonwoven 006 PE Polyethylene Glove, Unsupported 041 PE Polyethylene, High Density, Film 042 FE Polyethylene, Medium Density, Film 048 FE Polyethylene, Low Density, Film 056 PE . Polyethylene, Density Unknown, Film .075 FE Folyethylene/Sontara 076 FE’ Polyethylene/Tyvek 091 FE Polyethylene/Fabric 105 FE Polyethylene/Polypropylene Nonwoven • 134 PE Polyethylene/Nylon 137 PE Polyethylene/Polyester 109 PE/EVOH/PE FE/Ethylene Vinyl Alcohol/PE Glove, 098 POLYCARBONATE Polycarbonate, Lens and Face Shield 096 POLYESTER . Polyester, Face Shield and Lens 027 POLYURETHANE Polyurethane Rubber, Unsupported 040 POLYURETHANE Polyurethane Rubber/Polyester 050 POLYURETHANE Polyurethane Rubber/Nylon 082 POLYURETHANE Polyurethane Rubber, Boots 029 PTX Polymethylpentane, Face Shiel’d • 124 PV ACETATE . Polyvinyl Acetate, Sheet 004 FV ALCOHOL Polyvinyl Alcohol Glove, Supported 035 PV ALCOHOL Polyvinyl Alcohol, Sheet 102 PV ALCOHOL Polyvinyl Alcohol Glove, Unsupported 003 PVC Polyvinyl Chloride Glove, Unsupported F:- 7 ------- Product Description Codes and Resistant Materials (in alphabetical order of resistant material) Product Resistant Code Material Product Description 007 PVC Polyvinyl Chloride Glove, Supported 028 PVC Polyvinyl Chloride/Tyvek 030 PVC Polyvinyl Chloride, Face Shield 049 PVC Polyvinyl Chloride, Sheet 053 PVC Polyvinyl Chloride/Fabric 054 PVC Polyvinyl Chloride, Film 077 PVC Polyvinyl Chloride/Nylon 083 PVC Polyvinyl Chloride, Boots 088 PVC Polyvinyl Chloride/Rayon 106 PVC Polyvinyl Chloride Glove, Kid 490, Supported 131 PVC Polyvinyl Chloride/Fabric/Polyvinyl Chloride 133 PVC Polyvinyl Chloride/Nylon/Polyvinyl Chloride 144 PVC Polyvinyl Chloride/Polyester 061 SARANEX PE/Polyvinylidenechloride/PE/Tyvek 047 SBR Styrenebutadiene Rubber Latex Clove 063 SBR Styrenebutadiene Rubber/Fabric 149 SBR/NEOPRENE S tyrenebutadiene/Cotton/Chloroprene 122. SILVER SHIELD Silver Shield (North Product), Clove 036 TEFLON FEP Clove 044 TEFLON FEP Clove (Crumpled) 055 TEFLON FEP/Fiberglass 062 TEFLON FEP/Nylon 067 TEFLON TFE/Nomex 068 TEFLON FEP/Nomex 069 TEFLON TFE/Nomex/TFE 072 TEFLON TFE/Nomex/TFE Clove 073 TEFLON FEP, Face Shield and Lens 146 TEFLON ‘TFE/Fiberglass/TFE 009 VITON Fluoroelastomer Glove, Solvent Dipped, Unsupported 032 VITON Fluoroelastomer, Sheet 090 VITON Fluoroelastomer/Fiberglas S 129 VITON Fluoroelastomer/Fabric/Fluoroelastomer 143 .VITON Fluoroelastomer/Polyester/Fluoroelastomer 145 VITON Fluoroelastomer/Dacron 100 VITON/BUTYL Fluoroelas tomer/Butyl/Nylon/Butyl 114 VITON/BUTYL Fluoroelastomer/Butyl Clove, Solvent Dipped, Unsupported 112 VITON/CHLOROBUTYL Fluoroelastomer/Polyester/Chlorobutyl 153 VITON/CHLOROBUTYL Fluoroelas tomer/Nomex/Chiorobutyl 022 VITON/NEOPRENE Fluoroelastomer/Chloroprene Glove, Solv Dipped, Unsupp 111 VITON/NEOPRENE Fluoroelas tomer/Nylon/Chloroprene 101 VITON/NITRILE Fluoroelastomer/Nitrile Rubber Glove, Unsupported E—8 ------- APPENDIX F CLOTHING CLASSIFICATION CODE F-i ------- CLOTHING TYPE CODE ( Number corresponds to type shown in Appendix C. ) Coat, Jacket 01 Coveralls 02 ‘Apron 03 Pants, ib Overall 04 Full-body Encapsulating Suit 05 Hood 06 Shoe Cover 07 Boot 08. Face Shield . 09 Glove . 00 F—2 ------- APPENDIX G DATA SHEETS FOR ENCAPSULATING ENSEMBLES (For definitions of terms used in this appendix, ‘see Chapter 5 and Appendix A) G— 1 ------- MATERIAL Butyl / Nylon / Butyl PROTECTION LEVEL EPA: A (with emergency egress unit.) GARMENT SEAM Stitched, strapped with butyl. CLOSURE Pressure sealing zipper (Talon, Inc.). Teeth and slider: 67% copper, 12% nickel, 11% zinc. LOCATION: Front. LENGTH: 48 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: Yes. GLOVES TYPE: Integral gloves (optional). MATERIAL: Butyl. INTERFACE: Same as garment seam. TYPE: Detachable gloves (optional). MATERIAL: Butyl. INTERFACE: Inserts in glove and sleeve create compression seal or support ring in sleeve with glove clamp. BOOTS TYPE: Integral booties or overboots. MATERIAL: Butyl/nylon/butyl. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral (optional). MATERIAL: Polycarbonate with 2.5 mil FEP or 30 mil PVC splash visor. INTERFACE: No data. TYPE: Detachable (optional). MATERIAL: Polycarbonate/triacetate. INTERFACE: Chloroprene gasket. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder and leg areas. CRACKING PRESSURE: 1/2-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Umbilical feed. Hood accommodates face mask, suit accommodates internal, emergency egress unit. COOLING Air distribution system (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR LL-100 — Toxicological Butyl Andover Industries Inc. THICKNESS: 14 mils 15 Union Street MATERIAL WGT: 12 oz/sq yd Lawrence, MA 01840 ENSEMBLE WGT: No data (617) 794-1792 SIZES: No data G- .2 ------- MATERIAL Butyl/Nylon/Butyl PROTECTION LEVEL EPA: A (with emergency egress unit.) GARMENT SEAM Stitched, strapped with butyl. CLOSURE’. - Pressure sealing zipper (Talon, Inc.). Teeth and slider:’67% copper, 12% nickel, 11% zinc. LOCATION: Front. LENGTH: 48 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: Yes. GLOVES’ TYPE: Integral gloves (optional). MATERIAL: Butyl. INTERFACE: Same as garment seam. TYPE: Detachable gloves (optional). MATERIAL: Butyl. INTERFACE: Inserts in glove and sleeve create compression seal or support ring in sleeve with glove clamp. BOOTS TYPE: Integral booties or overboots. MATERIAL: Butyl/nylon/butyl. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral (optional). MATERIAL: Polycarbonate with 2.5 mil FEP or 30 mil PVC splash visor. INTERFACE: No data. TYPE: Detachable (optional). MATERIAL: Polycarbonate/triacetate. INTERFACE: Chloroprene gasket. EXHAUST VALVES ‘NUMBER: 4. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Umbilical feed. Hood accommodates face mask, suit accommodates internal, emergency egress unit. COOLING Air distribution system (optional). PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE - ‘ VENDOR LL-100 — Chemical Butyl Andover Industries Inc. THICKNESS: 15 mils 15 Union Street MATERIAL WGT: 11.5 oz/sq yd Lawrence, MA 01840 ENSEMBLE WGT: No data (617) 794-1792 S!ZES: No data FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. G- 3 ------- MATERIAL Butyl / Nylon / Butyl PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, strapped with butyl. CLOSURE Pressure sealing zipper. LOCATION: Back. LENGTH: 48 inches. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in glove and sleeve create. compression seal. BOOTS TYPE: Integral booties or boots. MATERIAL: Butyl/nylon/butyl. ‘INTERFACE: Same as garment seam. TYPE: Detachable boots. MA1:ERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl methacrylate). INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system or ice vest/jacket. FITTINGS AIRLINE: 1/4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR, 305 B/BA , Fyrepel Products Inc. THICKNESS: 14 mils Box 518 MATERIAL WGT: 14 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: 12 lbs (614) 344-0391 SIZES: S, M, L, XL (for heights 5’4” — 65”) , ‘ , - G —4 ------- MATERIAL PROTECTION LEVEL GARMENT SEAM Stitched, strapped with butyl. CLOSURE Pressure sealing zipper. LOCATION:. Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in glove and sleeve create compression seal. BOOTS TYPE: Integral booties or boots. MATERIAL: Butyl/nylon/butyl. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified ‘and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl methacrylate). INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data., SPLASH COVER: Yes. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance:’ No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Butyl/Nylon/Butyl EPA: A STYLE 0 VENDOR 306 B/BA Fyrepel Products Inc. THICKNESS: 14 mils Box 518 MATERIAL WGT: 14 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: 12 lbs (614) 344-0391 SIZES: 5, M, L, XL (for heights 5’4” — 6’5”) AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system or ice vest/jacket. FITTINGS AIRLINE: 1/4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. C- 5 ------- MATERIAL PROTECTION LEVEL GARMENT SEAM Double lapped, stitched, cemented, interior strapped with chloroprene, exterior strapped with butyl. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 53 inches. CLOSURE/SUIT SEAM: Same as garment seam. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or butyl. INTERFACE: Support ring in sleeve, elastic band. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene! polystryrene, rubber diaphragm. LOCATION: Hood area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system. FITTINGS BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Integral. MATERIAL: 80 mil PVC visor. INTERFACE: Adhesive bonded, interior strapped with butyl. AIRLINE: No data. COMMUNICATION: None. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM D-751), 110 lbs/inch. Tear Strength: (ASTM D-751), 10 lbs. Seam Strength: (ASTM D-1682), 110 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Butyl/Nylon/Butyl EPA: A STYLE VENDOR Trellchem, Butyl Extra Trelleborg, Inc. THICKNESS: 15-18 mils 30700 Solon Industrial Parkway MATERIAL WGT: 15 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 15 lbs (216) 248-8600 SIZES: S, M, L, XL G— 6 ------- MATERIAL Butyl /Nylon / Butyl PROTECTION LEVEL EPA:B GARMENT SEAM Double lapped, stitched, cemented, interior strapped with chloroprene, exterior strapped with butyl. CLOSURE -Pressure sealing zipper. LOCATION: Front. LENGTH: 41 inches. CLOSURE/SUIT SEAM: Same as garment seam. SPLASH COVER: Yes. GLOVES - TYPE: Detachable gloves. MATERIAL: Chloroprene or butyl. INTERFACE: Support ring in sleeve, elastic band. BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Detachable. MATERIAL: No data. INTERFACE: No data. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene/polystyrene, rubber diaphragm. LOCATION: Chest area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. PHYSICAL PROPERTIES (PRIMARY MATERiAL) Tensile Strength: (ASTM D-751), 110 lbs/in. Tear Strength: (ASTM D-751), 10 lbs. Seam Strength: (ASTM 0-1682), 110 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Trellchem, Butyl Trelleborg, Inc. THICKNESS: . 15-18 mils 30700 Solon Industrial Parkway MATERIAL WGT: 15 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 13 lbs (216) 248 8600 SIZES: S, M, L, XL AIR SUPPLY External back pack or umbilical feed. COOLING Air distribution system. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: Yes. G—7 ------- MATERIAL Butyl! Polyester! Chioroprene PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with chloroprene, exterior sealed with liquid butyl. CLOSURE Pressure sealing zipper (Dynat, Inc.), stainless steel teeth, brass slider, chloroprene backing. LOCATION: Front. LENGTH: 72 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or butyl. INTERFACE: Brass support ring in sleeve, stainless steel glove clamp, natural rubber glove ring sleeve. TYPE: Detachable overgloves. MATERIAL: Viton or butyl. INTERFACE: None. BOOTS EXHAUST VALVES NUMBER: 3. TYPE: Flapper valve. MATERIALS: Chioroprene valve cover, chloroprene and natural rubber valve disk, nylon valve seat, stainless steel slide ring, nylon threaded ring. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: None. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR. Chempruf II, Betex/SCBA Mine Safety Appliances Co. THICKNESS: 19 mils P.O. Box 426 MATERIAL WGT: 15.9 oz/sq yd Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 273-5000 SIZES: One size TYPE: Detachable booties. MATERIAL: Butyl/polyester/chloroprene. INTERFACE: None. TYPE: Detachable boots. MATERIAL: NBR + SBR + natural rubber. INTERFACE: Aluminum support ring in garment leg,’stainless steel boot clamp. VISOR TYPE: Detachable. . MATERIAL: 5/32-inch poly(methyl methacrylate) or 1/8-inch glass. INTERFACE: Natural rubber gasket. G—8 ------- MATERIAL Butyl/ Polyestert Chioroprene PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with chloropréne, exterior sealed with liquid butyl. CLOSU RE Pressure sealing zipper (Dynat, Inc.), stainless steel teeth, brass slider, chloroprene backing. LOCATION: Front. LENGTH: 72 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or butyl. INTERFACE: Brass support ring in sleeve, stainless steel glove clamp, natural rubber glove ring sleeve. TYPE: Detachable overgloves. MATERIAL: Butyl or Viton. INTERFACE: None. BOOTS TYPE: Detachable booties. MATERIAL: Butyl / polyester! chloroprene INTERFACE: None. TYPE: Detachable boots. MATERIAL: NBR + SBR + natural rubber. INTERFACE: Aluminum support ring in garment leg, stainless steel boot clamp. VISOR TYPE: Detachable. MATERIAL: 5/32-inch poly(methyl methacrylate) or 1/8-inch glass. INTERFACE: Natural rubber gasket. EXHAUST VALVES NUMBER: 3. TYPE: Flapper valve. MATERIALS: Chloroprene valve cover, chloroprene and natural rubber valve disk, nylon valve seat, stainless steel slide ring, nylon threaded ring. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: None. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS AIRLINE: Aluminum and vinyl washers, brass fittings, quick disconnect. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Chempruf II, Betex/DPBA Mine Safety Appliances Co. THICKNESS: 19 mils P.O. Box 426 MATERIAL WGT: 15.9 oz/sq yd Pittsburgh, PA 15230 •ENSEMBLE WGT: No data (412) 273-5000 SIZES: One size C— 9 ------- • MATERIAL Chlorinated Polyethylene PROTECTION LEVEL EPA: No Rating (See Section 5.B.8.) GARMENT SEAM Thermally welded. CLOSURE Inner restraint zipper with extruded chlorinated polyethylene sealing lips. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Molded ABS connect ring in sleeve, rubber connect ring in glove. BOOTS TYPE: Integral ‘booties. MATERIAL: Chlorinated polyethylene. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral. MATERIAL: Press-polished optical ‘grade 40 mil vinyl with polyester splash visors. INTERFACE: No data. EXHAUST VALVES NUMBER: 2. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Chemturion, Model 12 .‘ ILC Dover, Inc. THICKNESS: 20 mils ‘ P.O. Box 266 MATERIAL WGT: 19.7 oz/sq yd Frederica, DE 19946 ENSEMBLE WGT: 4 lbs (302) 335-3911 SIZES: L, XL (for heights 5’4” — 6’8”) AIR SUPPLY Umbilical feed. COOLING Air distribution system or liquid body cooling. FITTINGS AIRLINE: 1/4-inch NPT brass. COMMUNICATION: No data: COOLING: No data. INFLATION VALVE: No data. G- 10 ------- MATERIAL PROTECTION LEVEL GARMENT SEAM Thermally welded. CLOSURE Inner reétraint zipper with extruded chlorinated polyethylene sealing lips. LOCATION: Front. LENGTH: No data. CLOSU.REISUIT SEAM: Same as garment. SPLASH COVER: None. VISOR TYPE: Integral. MATERIAL: Press-polished optical grade 40 mil vinyl with polyester splash visors. INTERFACE: No data. EXHAUST VALVES NUMBER: 2. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Liquid body cooling (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Chlorinated Polyethylene EPA: A STYLE VENDOR Chemturion, Model 13 ILC Dover, Inc. THICKNESS: . 20 mils P.O. Box 266 MATERIAL WGT: 19.7 oz/sq yd Frederica, DE 19946 ENSEMBLE WGT: 4 lbs (302) 335-3911 SIZES: One size (for heights 5’4” — 6’4”) GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Molded ABS connect ring in sleeve, rubber connect ring in glove. BOOTS TYPE: Integral booties. MATERIAL: Chlorinated polyethylene. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied.. INTERFACE: Splash guards. c—il ------- • MATERIAL Chlorinated Polyethylene PROTECTION LEVEL EPA: A GARMENT SEAM Thermally welded. CLOSURE Inner restraint zipper with extruded chlorinated polyethylene sealing lips. LOCATION: Rear. LENGTH: No data. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Integral gloves. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. BOOTS TYPE: Integral booties. MATERIAL: Chlorinated polyethylene. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral. MATERIAL: Polycarbonate with antifog coating and splash visors. INTERFACE: No data. EXHAUST VALVES NUMBER: 4: TYPE: Spring operated. MATERIALS: No data. LOCATION: Legs and shoulder areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus (Bio-Marine Bio-Pak 60P’ rebreather). Hood accommodates face mask. COOLING Liquid body cooling. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: Standard tire valve. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Chemturion, Model 51 • ILC Dover, Inc. THICKNESS: 20 mils P.O. Box 266 MATERIAL WGT: 19.7 oz/sq yd Frederica, DE 19946 • ENSEMBLE WGT: 4 lbs (302) 335-3911 SIZES: S, M, L • (for heights 5’4” - 6’4”) G—12 ------- MATERIAL PROTECTION LEVEL Chiorobutyl / Nomex / Chiorobutyl EPA: No Rating (See Section 5.B.8.) GARMENT SEAM Cemented, strapped with butyl. CLOSURE Pressure sealing zipper (B.F. Goodrich), brass teeth and slider, chioroprene coated nylon filled cotton fabric. LOCATiON: Front. LENGTH: 45 or 50 in. CLOSURE/SUIT SEAM: Sewn in and overlaid with cement bonded suit material strapping. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Butyl. INTERFACE: Molded butyl connect ring in sleeve and glove with butyl roildown covers. BOOTS TYPE: Detachable boots. MATERIAL: PVC. INTERFACE: Molded butyl connect rings in garment leg and boot with butyl roildown covers. VISOR TYPE: Detachable MATERIAL: 25 mu modified acrylic. INTERFACE: Butyl rubber gasket. EXHAUST VALVES NUMBER: 3. TYPE: Flapper valve - Sierra Eng 50. MATERIALS: Aluminum housing and plate, butyl rubber antibackstreaming valve. LOCATION: Hip and hood areas. CRACKING PRESSURE: 0.5-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AiR SUPPLY Expanded back accommodates self-contained, 2-hour back pack, liquid air charged, 7.0 liters, or umbilical feed. COOLING Liquid air evaporation, air distribution system. Vortex cooling (optional). FITTINGS AIRLINE: Stainless steel quick disconnect for vortex cooling system. COMMUNICATION: Various types (optional). COOLING: See AIRLINE. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR SCAPE RFHCO Arrowhead Products THICKNESS: 19 mils 4411 Katella Avenue MATERIAL WGT: 17 oz/sq yd . Los Alamitos, CA 90720 ENSEMBLE WGT: No data (714) 828-7770 SIZES: Nine sizes G— 13 ------- MATERIAL Ch orobutyI/Nomex/Chlorobu l PROTECTION LEVEL EPA: No Rating (See Section 5,B.8.) GARMENT SEAM Nylon stitched, strapped with chlorobutyl (chloroprerie adhesive). CLOSURE Inner restraint zipper with extruded chlorinated polyethylene sealing lips. LOCATION: No data. LENGTH: No data. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Metal connect.rings in sleeve and glove. VISOR TYPE: Detachable. MATERIAL: Polycarbonate, INTERFACE No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Legs and shoulder areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE . VENDOR Propellant Handlers Ensemble . ILC Dover, Inc. THICKNESS: 20 mils P.O. Box 266 MATERIAL WGT: No data Frederica, DE 19946 ENSEMBLE WGT: No data (302) 335-3911 SIZES: No data AIR SUPPLY External back pack or umbilical feed. COOLING No data. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLiNG: No data. INFLATION VALVE: No data. BOOTS TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Metal cbnnect rings in garment leg and boot. G—14 ------- MATERIAL Chloroprene/ Nylon PROTECTION LEVEL EPA: B VISOR TYPE: Detachable. MATERIAL:’No data. INTERFACE: No data. EXHAUST VALVES NUMBER: None. TYPE: Not available. MATERIALS: Not available. LOCATION: Not available. CRACKING PRESSURE: Not available. MAX FLOW RATE: Not available. SPLASH COVER: Not available. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Type 500 CK National Draeger, Inc. THICKNESS: No data 101 Technology Drive MATERIAL WGT: No data Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 787-8383 SIZES: Above 5’l 1 • . ‘ Below 5’l 1” GARMENT SEAM Double stitched, exterior strapped with ch loroprene. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL:’ Viton. INTERFACE: Support ring in sleeve, steel glove clamp. AIR SUPPLY External back pack. Face mask incorporated in suit. COOLING None. FITTI NGS AfRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. BOOTS T TYPE: Detachable boots. ‘ MATERIAL: Chloroprene. INTERFACE: Support ring in garment leg, steel boot clamp. I- C— 15 ------- MATERIAL Ch loroprene/ Nylon PROTECTION LEVEL EPA: No.Rating (See Section 5.B.8.) GARMENT SEAM Double stitched, exterior strapped with chloroprene. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. BOOTS TYPE: Detachable boots. MATERIAL: Chloroprene. INTERFACE: Support ring in garment leg, steel ‘boot clamp. VISOR TYPE: Integral. MATERIAL: No data. INTERFACE: No data. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: No data. LOCATION: Chest area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Face mask incorporated in suit. COOLING None. FITTINGS AIRLiNE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiftness: No data. Flex Fatigue: No data. STYLE VENDOR Type 600 CK National Draeger, Inc. THICKNESS: No data ioi Technology Drive MATERIAL WGT: No data Pittsburgh, PA 15230 ENSEMBLE WGT: No data . (412) 787-8383 SIZES: One size G- 16 ------- MATERIAL PROTECTION LEVEL Polyvinyl Chloride/Nylon EPA: A (with emergency egress unit.) GARMENT SEAM Stitched, strapped with PVC. CLOSURE Pressure sealing zipper (Talon, Inc.). Teeth and slider: 67% copper, 12% nickel, 11% zinc. LOCATION: Front. LENGTH: 48 inches. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. VISOR TYPE: Integral (optional). MATERIAL: Polycarbonate with 2.5 mil FEP or 30 mil PVC splash visor. INTERFACE: No data. TYPE: Detachable (optional). MATERIAL: Polycarbonate/triacetate. INTERFACE: Chloroprene gasket. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Umbilical feed. Hood accommodates face mask,’ suit accommodates internal, emergency egress unit. COOLING Air distribution system (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR LL-100 — Polyvinyl Chloride Andover Industries Inc. THICKNESS: 15 mils 15 Union Street MATERIAL WGT: 10 oz/sq yd . Lawrence, MA 01840 ENSEMBLE WGT: No data (617) 794-1792 SIZES: No data GLOVES TYPE: Integral gloves (optional). MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. TYPE: Detachable gloves (optional). MATERIAL: Polyvinyl chloride. INTERFACE: Support ring in sleeve, stainless steel glove clamp. BOOTS TYPE: Integral booties. MATERIAL: PVC/nylon. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. C—17 ------- MATERIAL Polyvinyl Chloride/Polyester PROTECTION LEVEL EPA: No Rating (See Section 5.B.8.) GARMENT SEAM Stitched, strapped with PVC (welded). CLOSURE Pressure sealing zipper. LOCATION: Rear. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Polyvinyl chloride. INTERFACE: Inserts in glove and sleeve create compression seal. BOOTS TYPE: Integral overboots (optional). MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. TYPE: Detachable boots (optional). MATERIAL: Chloroprene. INTERFACE: Inserts in boot and garment leg create compression seal. VISOR TYPE: Integral. MATERIAL: 40 mil flexible vinyl; INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: ABS housing, natural rubber flapper. LOCATION: Back and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY External back pack or umbilical feed. Face mask incorporated in suit. COOLING Air distribution system or vortex cooling. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Stasafe, Accordion Standard Safety Equipment Co. THICKNESS: 28-30 mils P.O. Box 188 MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-01 88 ENSEMBLE WGT: No data (312) 359-1400 SIZES: No data c—i 8 ------- MATERIAL Polyvinyl Chloride/Polyester PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, strapped with PVC (welded). CLOSURE Pressure sealing zipper. LOCATION: Rear. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. BOOTS TYPE: Integral booties or overboots. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: Polyvinyl chloride. INTERFACE: PVC inserts in boot and garment leg create compression seal. VISOR TYPE: Integral. MATERIAL: 40 mil flexible PVC. INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: ABS housing, natural rubber flapper. LOCATION: Back and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system or vortex cooling. FITTINGS AIRLINE: No data. COMMUNICATJON No data. COOLING: No data, INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Stasafe, .Acidmaster Standard Safety Equipment Co. THICKNESS: 28-30 mils P.O. Box 188 MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-01 88 ENSEMBLE WGT: No data (312) 359-1400 SIZES: M, L, XL (for heights 5’8” — 6’5”) GLOVES •TYPE: Detachable gloves. MATERIAL: Polyvinyl chloride. INTERFACE: PVC inserts in glove and sleeve create compression seal. C— 19 ------- MATERIAL PROTECTION LEVEL Polyvinyl Chloride/Polyester EPA: A (with emergency egress unit.) GARMENT SEAM Stitched, strapped with PVC (welded). CLOSURE Standard zipper. Pressure sealing zipper optional. LOCATION: Rear. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. BOOTS TYPE: Integral overboots (optional). MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. TYPE: Detachable boots (optional). MATERIAL: Chioroprene. INTERFACE: PVC inserts in boot and garment leg create compression seal. VISOR TYPE: Integral. MATERIAL: 40 mil flexible PVC. INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve. MATERIALS: ABS housing, natural rubber flapper. LOCATION: Back and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Umbilical feed. Hood accommodates face mask. Egress bottle (optional). COOLING Air distribution system or vortex cooling. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR ‘Stasafe, Compressed Air ‘. Standard Safety Equipment Co. THICKNESS: 28-30 mils P.O. Box 188 MATERIAL WGT: 27 oz/sq yd Palatine, IL 60078-0188 ENSEMBLE WGT: No data (312) 359-1400 SIZES: One size GLOVES TYPE: Detachable gloves. MATERIAL: Polyvinyl chloride. INTERFACE: PVC inserts in glove and sleeve create compression seal. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. C— 20 ------- MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, strapped with PVC. CLOSURE Pressuresealing zipper. LOCATION: Back. LENGTH: 48 inches. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. BOOTS TYPE: Integral booties or boots. MATERIAL: PVC/nylon/PVC. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl inethacrylate). INTERFACE: No data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates tace mask. COOLING Air distribution system or ice vest/jacket. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR 305 PVC/BA - Fyrepel Products Inc. THICKNESS: No data Box 518 MATERIAL WGT: 10 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: No data (614) 344-0391 SIZES: S, M, L, XL (for heights 5’4” — 6’5”) GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in glove and sleeve create compression seal. FITTINGS AIRLINE: 1/4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. G—21 ------- MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, strapped with PVC CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in sleeve and glove create compression seal. BOOTS TYPE: Integral booties or boots. MATERIAL: PVC/nylon/PVC. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl methacrylate). INTERFACE: No data. NUMBER: 4. TYPE: .Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system or ice vest/jacket. FITTINGS AIRLINE: 1/4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resisténce: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR 306 PVC/BA Fyrepel Products Inc. THICKNESS: No data Box 518 MATERIAL WGT: 10 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: No data (614) 344-0391 SIZES: 5, M, L, XL (for heights 5’4” — 6’5”) EXHAUST VALVES G—22 ------- MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA: B GARMENT SEAM Double stitched, exterior strapped with PVC. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. BOOTS TYPE: Detachable boots. MATERIAL: Chloroprene. INTERFACE: Support ring in garment leg, steel boot clamp. VISOR TYPE: Detachable. MATERIAL: No data. INTERFACE: No data. EXHAUST VALVES NUMBER: None. TYPE: Not available. MATERIALS: Not available. LOCATION: Not available. CRACKING PRESSURE: Not available. MAX FLOW RATE: Not available. SPLASH COVER: Not available. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data.. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE S , VENDOR Type 500 PVC National Draeger, Inc. THICKNESS: No data 101 Technology Drive MATERIAL WGT: No data Pittsburgh, PA 15230 ENSEMBLE WGT: 13.2 lbs (412) 787-8383 SIZES: Above 5’ll” Below 5’ll” AIR SUPPLY External back pack. Face mask incorporated in suit. COOLING’ None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. G— 23 ------- MATERIAL PROTECTION LEVEL Polyvinyl Chloride (PVC)! Nylon / PVC EPA: No Rating (See Section 5.B.8.) CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. VISOR TYPE: Integral. MATERIAL: N.o data. INTERFACE: No data. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: No data. LOCATION: Chest area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Face mask incorporated in suit. COOLING None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE . VENDOR Type 600 PVC National Draeger, Inc. THICKNESS: No data. 101 Technology Drive MATERIAL WGT: No data. Pittsburgh, PA 15230 ENSEMBLE. WGT: 14.3 lbs (412) 787-8383 SIZES: One size GARMENT SEAM Double stitched, exterior strapped with PVC. BOOTS TYPE: Detachable boots. MATERIAL: Chloroprene. INTERFACE: Support ring in garment leg, steel boot clamp. G— 24 ------- MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA:A GARMENT SEAM Double stitched, exterior strapped with PVC. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. BOOTS TYPE: Detachable boots. MATERIAL: Chioroprerie. INTERFACE: Support ring in garment leg, steel boot clamp. VISOR TYPE: Detachable. MATERIAL: Polyvinyl chloride. INTERFACE: No data. EXHAUST VALVES NUMBER: 2. TYPE: No data. MATERIALS: No data. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Type 700 PVC . National Draeger, Inc. THICKNESS: No data ioi Technology Drive MATERIAL WGT: No data . Pittsburgh, PA 15230 ENSEMBLE WGT: 12.1 lbs (412) 787-8383 SIZES: One size G- 25 ------- MATERIAL PROTECTION LEVEL CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 41 inches. CLOSURE/SUIT SEAM: Stitched, cemented, interior and exterior strapped with PVC. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene. INTERFACE: Support ring in sleeve, elastic band. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene/polystyrene, rubber diaphragm: LOCATION: Chest area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Adhesive bonded. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Detachable. MATERIAL: No data. INTERFACE: No data. AIRLINE: No data. COMMUNICATION: None. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM 0-751), 110 bs/in. Tear Strength: (ASTM D-751), 10 lbs. Seam Strength: (ASTM D-1682), 110 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Polyvinyl Chloride (PVC)/Nylon/PVC ‘EPA: B STYLE VENDOR Trellchem, Light Trelleborg, Inc. THICKNESS: 15-18 mils 30700 Solon Industrial Parkway MATERIAL WGT: 14.5 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 12.5 lbs (216) 248-8600 SIZES: S, M, L, XL GARMENT SEAM ‘ - ____________________________ Double lapped, stitched, exterior welded. AIR SUPPLY External back pack or umbilical feed. COOLING Air distribution system. ‘FITTINGS G- 26 ------- GARMENT SEAM Double lapped, stitched, exterior weided CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 53 inches. CLOSURE/SUIT SEAM: Stitched, cemented, interior and exterior strapped with PVC. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene. INTERFACE: Support ring in sleeve, elastic band. BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Adhesive bonded. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Integral. MATERIAL: 80 mil PVC visor. INTERFACE: Adhesive bonded, interior strapped with PVC. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene/polystyrene, rubber diaphragm. LOCATION: Hood area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system. FITTINGS AIRLINE: No data. COMMUNICATION: None, COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM D-751), 110 lbs/in. Tear Strength: (ASTM D-751), 10 lbs. Seam Strength: (ASTM D-1682), 110 lbs/in. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. ‘Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA: A STYLE VENDOR Tréllchem, Light Extra Trelleborg, Inc. THICKNESS: 15-18 mils 30700 Solon Industrial Parkway MATERIAL WGT: 14.5 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 12.5 lbs (216) 248-8600 SIZES: S, M, L, XL C— 27 ------- MATERIAL Polyvinyl Chloride (PVC)/Nylon/PVC PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, thermally welded. CLOSURE Pressure sealing zipper. LOCATION: Rear. LENGTH: 44 inches. CLOSURE/SUtT SEAM: Stitched, thermally welded. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: PVC. INTERFACE: Support ring in sleeve, steel glove clamp.’ EXHAUST VALVES NUMBER: 2. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Shoulder and leg areas. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained back pack or umbilical feed. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS BOOTS TYPE: Detachable boots. MATERIAL: PVC. INTERFACE: Support ring in garment leg, steel boot clamp. VISOR TYPE: Integral (optional). MATERIAL: 40 mil PVC. INTERFACE: No data. TYPE: Detachable (optional). MATERIAL: 125 mil poly(methyl methacrylate). INTERFACE: No data. AIRLINE: 1/4-inch NPT. COMMUNICATION: No data. COOLING: 1/4-inch NPT or 3/4-inch GH thread. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (FTM 191A, 5100), 94.1 lbs (W), 100 lbs (F). Tear Strength: (ASTM 0-1117), 33.9 lbs (W), 24.4 lbs (F). Seam Strength: (ASTM 1683), 63 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: (FTM 191A, 5120), 21.2 lbs. Abrasion Resistance: (FTM 191A, 5306), 3,000 cyc, no wear. Flammability: (FTM 191A, 5903.2), pass. Stiffness: No data. Flex Fatigue: (U.S.T. Method), 1,000 cyc, no cracking. STYLE VENDOR Acid King Wheeler Protective Apparel, Inc. - THICKNESS: 20 mils 4330 West Belmont Avenue MATERIAL WGT: 14 oz/sq yd Chicago, IL 60641 ENSEMBLE WGT: No data (312) 685-5551 SIZES: Short, Regular, Long (for heights 5’4” — 6’6”) G—28 ------- MATERIAL Teflon/Fiberglass/Teflon PROTECTION LEVEL EPA:A GARMENT SEAM Welded half-inch lap seam, exterior strapped with Teflon tape. CLOSURE Pressure. sealing zipper (YKK, Inc.). Chloroprene tape, brass teeth and slider. LOCATION: Back. LENGTh: 36 inches. CLOSURE/SUIT SEAM: Fiberglass heat sealed to garment, zipper chloroprene tape bonded to fiberglass with toluene base adhesive. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: 10 mU Teflon. INTERFACE: Support ring in sleeve, stainless steel glove cIamp splash guard. TYPE: Detachable gloves. MATERIAL: 10 mil, solvent-dipped butyl. INTERFACE: Elastic butyl rubber band. BOOTS TYPE: Integral booties. MATERIAL: Teflon/fiberglass/Teflon. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral. MATERIAL: 10 mu FEP. INTERFACE: 5-6 mil Teflon tape heat sealed on both sides. EXHAUST VALVES NUMBER: 4. TYPE: Halkey Roberts 780-RPA.1. MATERIALS: Nylon housing, silicon rubber diaphragm, 304 stainless steel spring. LOCATION: Upper back. CRACKING PRESSURE: 2-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (FTM 191, 5102.2), 221 lbs/in (W), 192 lbs/in (F). Tear Strength: (FTM 191, 5134), 13.7 lbs (W), 9.0 lbs (F). Seam Strength: (ASTM 3786), 50 psi. Zipper Strength: (FTM 191, 5100.1), 70 ph. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: (FTM 191, 5302), 0.064 grams lost. Flammability: (ASTM D-568), non-burning. Stiffness: (FTM 191, 5200.1), 4.0 cm. Flex Fatigue: No data. STYLE VENDOR Challenge 5200 Chemical Fabrics Corporation THICKNESS: 10 mils P.O. Box 1137 MATERIAL WGT: 14.6 oz/sq yd Merrimack, NH 03054 ENSEMBLE WGT: 10 lbs (603) 424-9000 SIZES: No data G- 29 ------- MATERIAL Teflon / Nomex /Teflon PROTECTION LEVEL EPA: A GARMENT SEAM Stitched, interior and exterior strapped with Teflon tape (welded). CLOSURE Pressure sealing zipper (YKK, Inc.). Chloroprene tape, brass teeth and slider. LOCATION: Back. LENGTH: 36 inches. CLOSURE/SUIT SEAM: Fiberglass heat sealed to garment, zipper chloroprene tape bonded to fiberglass with toluene base adhesive. SPLASH COVER: Yes. GLOVES• TYPE: Integral gloves. MATERIAL: 4 mu Teflon. INTERFACE: Bonded at glove ring with toluene- based adhesive. TYPE: Detachable gloves. MATERIAL: 10 mU, solvent-dipped butyl. INTERFACE: Elastic butyl rubber band. BOOTS TYPE: Integral booties. MATERIAL: Teflon/Nomex/Teflon. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Integral. MATERIAL: 10 mil FEP. INTERFACE: 5-6 mil Teflon tape heat sealed on both sides. EXHAUST VALVES NUMBER: 2. TYPE: Stratotech, Part No. 739-1.5. MATERIALS: Aluminum housing, silicon rubber diaphragm, 304 stainless steel spring. LOCATION: Upper back. CRACKING PRESSURE: 1-to 1.5-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING External cooling ice pouch/heat exchanger interfaces with full body cooling garment and pouch which circulates water through garment. FITTINGS AIRLINE: None. COMMUNICATION: None. COOLING: No data. INFLATION VALVE: None. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM D-751), 113.7 lbs/in (W), 95.8 lbs/in (F). Tear Strength: (ASTM D-751), 21.0 lbs (W), 19.6 lbs (F). Seam Strength: (ASTM 3786), 50 psi. Zipper Strength: (FTM 191, 5100.1), 70 ph. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: (FTM 191, 5302), 0.656 grams lost. Flammability: (ASTM D-568), non-burning. Stiffness: (FTM 191, 5200.1), 4.5 cm. Flex Fatigue: No data. STYLE VENDOR Challenge 5100 Chemical Fabrics Corporation THICKNESS: 18 mils P.O. Box 1137 MATERIAL WGT: 13.9 oz/sq yd Merrimack, NH 03054 ENSEMBLE WGT: 14 lbs (603) 424-9000 SIZES: One (large) C—3D ------- MATERIAL Viton / Nomex/ Chiorobutyl PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with butyl, exterior strapped with Viton. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 60 inches. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Inserts in glove and sleeve create compression seal. BOOTS- TYPE: Integral booties. MATERIAL: Viton/Nomex/chlorobutyl. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable (optional). MATERIAL: Polycarbonate with FEP splash cover. INTERFACE: Chloroprene gasket. TYPE: Detachable (optional). MATERIAL: User specified. INTERFACE: Chloroprene gasket. EXHAUST VALVES NUMBER: 2. TYPE: Flapper valve. MATERIALS: No data. LOCATION: Chest and sleeve areas. CRACKING PRESSURE: 1/2-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Metro S.S. Andover Industries Inc. THICKNESS: 20 mils 15 Union Street MATERIAL WGT: 29 oz/sq yd Lawrence, MA 01840 ENSEMBLE WGT: No data (617) 794-1792 SIZES: S. M, L, XL, XXL (for heights 5’6” — 6’7”) C— 31 ------- MATERIAL Viton / Nylon / Chioroprene PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with chloroprene, exterior sealed with liquid Viton. CLOSURE Pressure sealing zipper (Dynat, Inc.), stainless steel teeth, brass slider, chloroprene backing. LOCATION: Front. LENGTH: 72 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or Viton. INTERFACE: Brass support ring in glove, stainless steel glove clamp, natural rubber glove ring sleeve. TYPE: Detachable overgloves. MATERIAL: Butyl or Viton. INTERFACE: None. BOOTS TYPE: Detachable booties. MATERIAL:Viton / nylon /chloroprene. INTERFACE: None. ‘TYPE: Detachable boots. MATERIAL: NBA + SBR + natural rubber. INTERFACE: Aluminum support ring in garment leg, stainless steel boot clamp. VISOR TYPE: Detachable. MATERIAL: 5/32-inch poly(methyl methacrylate) or 1/8-inch glass. INTERFACE: Natural rubber gasket. EXHAUST VALVES NUMBER:.3. TYPE: Flapper valve. MATERIALS: Chloroprene valve cover, chioroprene and natural rubber valve disk, nylon valve seat, stainless steel slide ring, nylon threaded ring. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: None. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Chempruf II, Vautex/SCBA Mine Safety Appliances Co. THICKNESS: 23 mils P.O. Box 426 MATERIAL WGT: 19.1 oz/sq yd Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 273-5000 SIZES: One size G— 32 ------- MATERIAL Viton / Nylon /Chloroprene PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with chioroprene, exterior sealed with liquid Viton. CLOSURE Pressure sealing zipper (Dynat, Inc.), stainless steel teeth, brass slider, chioroprene backing. LOCATION: Front. LENGTH: 72 inches. CLOSURE/SUIT SEAM: Same as garment. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or Viton. INTERFACE: Brass support ring in sleeve, stainless steel glove ring, natural rubber glove ring sleeve. TYPE: Detachable overgioves. MATERIAL: Butyl or Viton. INTERFACE: None. BOOTS TYPE: Detachable booties. MATERIAL: Viton/nylon/chioroprene. INTERFACE: None. TYPE: Detachable boots. MATERIAL: NBA + SBR + natural rubber. INTERFACE: Aluminum support ring in garment leg, stainless steel boot clamp. VISOR TYPE: Detachable. MATERIAL: 5/32-inch poly(methyl methacrylate) or 1/8-inch glass. INTERFACE: Natural rubber gasket. EXHAUST VALVES NUMBER: 3. TYPE: Flapper valve.. MATERIALS: Chloroprene valve cover, chloroprene and natural rubber valve disk, nylon valve seat, stainless steel slide ring, nylon threaded ring. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: None. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system (optional). FITTINGS AIRLINE: Aluminum and vinyl washers, brass fittings, quick disconnect. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE . VENDOR Chempruf II, Vautex/DPBA Mine Safety Appliances Co. THICKNESS: 23 mils P.O. Box 426 MATERIAL WGT: 19.1 oz/sq yd Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 273-5000 SIZES: One size C— 33 ------- MATERIAL Viton / Nylon/Chioroprene PROTECTION LEVEL EPA: B GARMENT SEAM Double stitched, interior strapped with chioroprene, exterior sealed with Viton sealing compound. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. BOOTS, TYPE: Detachable boots. MATERIAL: Chloroprene. INTERFACE: Support ring in garment leg, steel boot clamp. VISOR TYPE: Detachable. MATERIAL: No data. INTERFACE: No data. EXHAUST VALVES NUMBER: None. TYPE: Not available. MATERIALS: Not available. LOCATION: Not available. CRACKING PRESSURE: Not available. MAX FLOW RATE: Not available. SPLASH COVER: Not available. AIR SUPPLY External back pack. Face mask incorporated in suit. COOLING None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE , VENDOR Type 500 PF National Draeger, Inc. THICKNESS: No data 101 Technology Drive MATERiAL WGT: No data Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 787-8383 SIZES: ‘ ‘Above 5’ll” Below 5’ll” ‘ 0-34 ------- THIS PAGE LEFT INTENTIONALLY BLANK G-35 ------- MATERIAL Viton I Nylon / Chioroprene PROTECTION LEVEL EPA: A GARMENT SEAM Double stitched, interior strapped with chloroprene, exterior sealed with Viton sealing compound. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: None. GLOVES TYPE: Detachable gloves. MATERIAL: Viton. INTERFACE: Support ring in sleeve, steel glove clamp. BOOTS TYPE: Detachable boots. MATERIAL: Chioroprene. INTERFACE: Support ring in garment leg, steel boot clamp. VISOR TYPE: Detachable. MATERIAL: Polyvinyl chloride. INTERFACE: No data. EXHAUST VALVES NUMBER: 2: TYPE: No data. MATERIALS: No data. LOCATION: Hood area. CRACKING PRESSURE: No data. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING None. FITTINGS AIRLINE: No data. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Type 700 PF National Draeger, Inc. THICKNESS: No data 101 Technology Drive MATERIAL WGT: No data Pittsburgh, PA 15230 ENSEMBLE WGT: No data (412) 787-8383 SIZES: One size C— 36 ------- MATERIAL PROTECTION LEVEL STYLE VENDOR 305 V/BA Fyrepel Products Inc. THICKNESS: 8 mils Box 518 MATERIAL WGT: 2.5 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: No data (614) 344-0391 SIZES: S, M, L, XL (for heights 5’4” — 6’5”) GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in glove and sleeve create compression seal. NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed Hood accommodates face mask. BOOTS TYPE: Integral booties or boots. MATERIAL: Viton/polyester/Viton. INTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl methacrylate). INTERFACE: No data. AIRLINE: 1/4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data.. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Viton/Polyester/Viton EPA: A GARMENT SEAM Stitched, strapped with Viton. EXHAUST VALVES CLOSURE. Pressure sealing zipper. LOCATION: Back. LENGTH: 48 inches. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. COOLING Air distribution system or ice vest/jacket. FITTINGS G— 37 ------- MATERIAL Viton / Polyester! Viton PROTECTION LEVEL EPA: A CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: No data. CLOSURE/SUIT SEAM: No data. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: User specified and supplied. INTERFACE: Inserts in glove and sleeve create compression seal. BOOTS TYPE: Integral boots or booties. MATERIAL: Viton/polyester/Viton. iNTERFACE: Same as garment seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guards. VISOR TYPE: Detachable. MATERIAL: Poly(methyl methacrylate). INTERFACE: No ‘data. EXHAUST VALVES NUMBER: 4. TYPE: Flapper valve (Glendale, Inc.) MATERIALS: No data. LOCATION: Back of legs. CRACKING PRESSURE: 0.4 psi. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus or umbilical feed. Hood accommodates face mask. COOLING Air distribution system or ice vest/jacket. FITTINGS AIRLINE: 1 /4-inch brass. COMMUNICATION: No data. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: No data. Tear Strength: No data. Seam Strength: No data. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR 306 V/BA . Fyrepel Products Inc. THICKNESS: 8 mils Box 518 MATERIAL WGT: 2.5 oz/sq yd Newark, OH 43055 ENSEMBLE WGT: No data (614) 344-0391 SIZES: S, M, L XL (for heights 5’4” - 6 ’5”) GARMENT SEAM Stitched, strapped with Viton. C—38 ------- MATERIAL PROTECTION LEVEL STYLE VENDOR Trellchem, Super Trelleborg, Inc. THICKNESS: 15-18 mils 30700 Solon Industrial Parkway MATERIAL WGT: 16 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 13 lbs (216) 248-8600 SIZES: S, M, L, XL NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene/polystyrene, rubber diaphragm. LOCATION: Chest area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY External back pack or umbilical feed. .G LOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or Viton/butyl. INTERFACE: Support ring in sleeve, elastic band. COOLING Air distribution system. FITTINGS BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garmèht seam. TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Detachable. MATERIAL: No data. INTERFACE: No data. AIRLINE: No data. COMMUNICATION: None. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM D-751), 110 lbs/in. Tear Strength: (ASTM D-751), 10 lbs. St m Strength: (ASTM D-1682),110 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. Viton/Butyl/Nylon/Butyl EPA: B GARMENT SEAM Double lapped, stitched, cemented, interior strapped with chloroprene, exterior strapped with Viton. EXHAUST VALVES CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 41 inches. CLOSURE/SUIT SEAM: Same as garment seam. SPLASH COVER: Yes. C— 39 ------- MATERIAL Viton / Butyl/ Nylon / Butyl PROTECTION LEVEL EPA:A GARMENT SEAM Double lapped, stitched, cemented, interior strapped with chioroprene, exterior strapped with Viton. CLOSURE Pressure sealing zipper. LOCATION: Front. LENGTH: 53 inches. CLOSURE/SUIT SEAM: Same as garment seam. SPLASH COVER: Yes. GLOVES TYPE: Detachable gloves. MATERIAL: Chloroprene or Viton/butyl. INTERFACE: Support ring in sleeve, elastic band. EXHAUST VALVES NUMBER: 1. TYPE: No data. MATERIALS: Polyethylene/polystyrene, rubber diaphragm. - LOCATION: Hood area. CRACKING PRESSURE: 0.3-inch water. MAX FLOW RATE: No data. SPLASH COVER: Yes. AIR SUPPLY Expanded back accommodates self-contained breathing apparatus. Hood accommodates face mask. COOLING Air distribution system. BOOTS TYPE: Integral boots or booties. MATERIAL: Polyvinyl chloride. INTERFACE: Same as garment seam. -TYPE: Detachable boots. MATERIAL: User specified and supplied. INTERFACE: Splash guard. VISOR TYPE: Integral. MATERIAL: 80 mil PVC. INTERFACE: Adhesive bonded, interior strapped with Viton/butyl. AIRLINE: No data. COMMUNICATION: None. COOLING: No data. INFLATION VALVE: No data. PHYSICAL PROPERTIES (PRIMARY MATERIAL) Tensile Strength: (ASTM D-751), 110 lbs/in. Tear Strength: (ASTM D-751), 10 lbs. Seam Strength: (ASTM D-1682), 110 lbs. Zipper Strength: No data. Cut Resistance: No data. Puncture Resistance: No data. Abrasion Resistance: No data. Flammability: No data. Stiffness: No data. Flex Fatigue: No data. STYLE VENDOR Trellchem, Super Extra Trelleborg, Inc. THICKNESS: 15-18 mils - 30700 Solon Industrial Parkway MATERIAL WGT: 16 oz/sq yd Solon, OH 44139 ENSEMBLE WGT: 15 lbs (216) 248-8600 SIZES: S, M, L, XL FITTINGS G— 40 ------- APPENDIX H PRODUCT DESCRIPTIONS FOR SPLASH SUITS H-i ------- SPLASH SUITS VENDOR! STYLE PRIMARY MATERIAL DESCRIPTION BOSS MFG. CO. 3PC PVC/COTTON TYPES: JACKET, HOOD, PANTS, BIB OVERALL. 3PN PVC/NYLON 3PN PVC/NYLON/PVC FEATURES: PVC SEAMS SEWN AND THERMALY WELDED; 3NN CHLOROPRENE/NYLON CHLOROPRENE AND SBR SEAMS CEMENTED; 3RC SBR/COTTON BATWING OR RAGLAN SLEEVES; 3RC SBR/COTTON/SBR STORM FLY FRONT; NICKLE PLATED 3NP POLYURETHANE/NYLON SNAPS OR NON-CORROSIVE, NON-CONDUCTIVE 3PR PVC/POLYESTER PLASTIC SNAPS. 3PF UNSUPPORTED PVC DAFFIN DISPOSABLES PCT POLYETHYLENE/TYVEK TYPES: JACKET, PANTS, COVERALLS, SARANEX. SARANEX/TYVEK ENCAPSULATING SUIT. FEATURES: STORM FLY FRONT; ZIPPER CLOSURE; ELASTIC CUFFS ON SLEEVES AND LEGS; INTEGRAL OVERBOOTS ON SUITS; FOUND SEAMS;EXPANDED BACK ACCOMMODATES SELF CONTAINED AIR SUPPLY OR SUIT IS UMBILICALLY FED. DEFENSE APPAREL UNSUPPORTED PVC TYPES: JACKET, PANTS, BIB OVERALL, COVERALL. FEATURES: ZIPPER CLOSURES. DIRECT SAFETY COMPANY RAINMASTER SUPPORTED PVC TYPES: JACKET, PANTS, BIB OVERALLS. RAINMASTER UNSUPPORTED PVC PVC/NYLON/PVC FEATURES: NON-CONDUCTIVE SNAPS. DISPOSABLES INC. P.E. POLYETHYLENE/TYVEK TYPES: COVERALLS, ENCAPSULATING SUIT. FEATURES: STORM FLY FRONT; ELASTIC CUFFS ON SLEEVES; INTEGRAL OVERBOOTS ON SUITS; ZIPPER CLOSURE; MYLAR FACE SHIELD IN ENCAPSULATING SUIT; UMBILICALLY FED SUIT. H- 2 ------- VENDOR/ STYLE PRIMARY MATERIAL DESCRIPTION DURAFAB DISPOSABLES POLYLAMINATED TYVEK POLYETHYLENE/TYVEK TYPES: JACKET, HOOD, PANTS, COVERALL, SARANEX STYLE SARANEX/TYVEK ENCAPSULATING SUIT. FEATURES: STITCHED, BOUND, OR BOUND AND SEALED SEAMS; RAGLAN SLEEVES; SNAPS OR ZIPPER CLOSURE; ZIPPER CLOSURE ON SUIT; ELASTIC CUFFS ON SLEEVES AND LEGS; EXPANDED BACK ON ENCAPSULATING SUITS WILL ACCOMMODATE SELF CONTAINED AIR SUPPLY OR SUIT IS UMBILLICALLY FED. EDMONT • WET WEAR 500 PVC/NYLON/PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. • WET WEAR 550 SUPPORTED PVC WET WEAR 600 PVC/NYLON/PVC FEATURES: THERMALLY WELDED SEAMS; BATWING WET WEAR 700 NITRILE+PVC/NYLON • SLEEVES; NON-CORROSIVE, NON-CONDUCTING SNAPS. ENCON CHLOROPRENE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. FALCON PREMIUM GRADE - RAYON SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. • CONTRACT GRADE PVC-RAYON-PVC NYGRID PVC-NYLON-PVC FEATURES: LAPPED, DOUBLE-STITCHED, WELDED SEAMS; UNSUPPORTED PVC RAGLAN SLEEVES; NON-CONDUCTIVE SNAPS; SPLIT SNAPS TO PREVENT “FREEZING”; WAIST, WRIST, AND ANKLE TAKE UPS; DRAW-STRING COAT HEM; WELDED REINFORCEMENT IN CROTCH AND ARMPIT. KAPPLER P.E. POLYETHYLENE/TYVEK • TYPES: JACKET, PANTS, COVERALL, HOOD, SARANEX SARANEX/TYVEK ENCAPSULATING SUIT. FEATURES: BOUND OR WELDED SEAMS; ZIPPER CLOSURE; STORM FLY FRONT; ELASITIC CUFFS ON SLEEVES AND LEGS; INTEGRAL OVERBOOTS; EXPANDED BACK ACCOMMODATES SELF CONTAINED AIR SUPPLY OR SUIT IS UMBILLICALLY FED. MAG ID -STANDARD DUTY • SUPPORTED PVC TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. FEATURES: WELDED SEAMS; NON-METALIC SNAPS; STORM FLY FRONT. H-3 ------- VENDOR/ STYLE PRIMARY MATERIAL DESCRIPTION RAINFAIR POLYLON POLYURETHANE/NYLON TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. SUPER NYLO-GARD CHLOROPRENE/NYLON/CHLOROPRENE NYLO-GARD CHLOROPRENE/NYLON •FEATURES: STITCHED AND STRAPPED OR CEMENTED DOLPHIN POLYURETHANE/NYLON SEAMS; STORM FLY FRONT; BATWING ACID SUIT PVC/POLYESTER/PVC SLEEVES; REFLECTIVE TRIM. SUPER NEOTEX CHLOROPRENE/COTTON/CHLOROPRENE 0 SUPER NYLO-SEAL CHLOROPRENE/NYLON VULTEX . SBR/COTTON/CHLOROPRENE . CHEM-KING PVC/NYLON SBR YANKEE SBR/COTTON RECORD INDUSTRIAL CO. COATED CLOTHING BUTYL/NYLON/BUTYL TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. CHLOROPRENE/COTTON SUPPORTED PVC FEATURES: STORM FLY FRONT; RAGLAN SLEEVES; METAL OR PLASTIC SNAPS; WAIST ADJUSTERS. SIEBE NORTON. F .1OO CHLQROPRENE/NYLON/CHLOROPRENE TYPES: JACKET, HOOD, PANTS, BIB OVERALLS, COVERALL. TUFFLON CHLOROPRENE+SBR/NYLON SUPER TUFFPRENE CHLOROPRENE/COTTON/CHLOROPRENE FEATURES: LAP FRONT OR. STORM FLY FRONT; DOUBLE TUFFPRENE . CHLOROPRENE+SBR/COTTON . STITCHED SEAM W/SEALANT OR THERMALLY WELDED. NSPN CHLOROPRENE+SSR/COTTON BATWING OR RAGLAN SLEEVES; . SHIELD BRAND PVC/NYLON/PVC INNER CUFF IN SLEEVE.; TAKE-UP SNAPS. ON CUFF; IUFFGARD PVC/NYLON/PVC NON-CONDUCTIVE SNAPS. 006 1/2 H PVC/NYLON/PVC NSPVH PVC/NYLON/PVC. RAINMASTER SUPPORTED PVC RAINMASTER UNSUPPORTED PVC WHEELER 34 LINE FABRIC SUPPORTED CHLOROPRENE TYPES: JACKET, HOOD, PANTS, BIB OVERALLS. 36 LINE FABRIC SUPPORTED PVC 35 LINE FILM UNSUPPORTED PVC FEATURES: STITCHED AND THERMALLY WELDED SEAMS; STORM FLY FRONT; PLASTIC SNAPS. H-4 ------- APPENDIX I DEFINITION OF PROTECTION LEVELS (Excerpted from “Hazardous Materials Incident Response. Operations,” 1984, Office of Emergency and Remedial Response, Hazardous Response Support Division, U.S. Environmental Protection Agency) 1 ------- PART 5 SITE ENTRY - LEVELS OF PROTECTION I. INTRODUCTION Personnel must wear protective equipment when response activities involve known or suspected atmospheric contamination, when vapors, gases, or particulates may be generated by site activities, or when direct contact with skin-affecting substances may occur. Full face- p iece respirators protect lungs, ‘gastrointestinal tract, and eyes gainst airborne toxicants. Chemical—resistant clothing protects the skin from contact with skin—destructive and absorbable chemicals. Good personal hygiene limits or prevents ingestion of material. Equipment to protect the body against contact with known or antici- pated toxic chemicals has been divided into four categories according to the degree of protection afforded: — Level A : Should be worn when the highest level of respiratory, skin, and eye protection is needed. - Level B : Should be worn when the highest level of respiratory protection is needed, but a lesser level of skin protection. - Level C : Should be worn when the criteria for using air-purifying respirators are met. ‘ ‘ Level D : ‘ Should be worn only as a work uniform and not ‘on any site with respiratory or skin hazards. It provides no protection against chemical hazards. The Level of Protection selected should be based on: — Type and measured concentration of the chemical substance in the ambient atmosphere and its toxicity. — Potential for exposure to substances in air, splashes of liquids, or other direct contact with material due to work being done. In situations where the type of chemical , concentration, and possibilities of contact are not known, the appropriate Level of Protection must be selected based on professional experience and judgment until the hazards can be better identified. While personnel protective equipment reduces the potential for contact with toxic substances, ensuring the health and safety of responders requires, in addition, safe work practices, decontamination, site entry protocols, and other safety procedures. Together, these provide an integrated approach for reducing harm to workers. 1—2 ------- II. LEVELS OF PROTECTION A.’ Level A Protection ’ 1. Personnel protective equipment - Supplied-air respirator approved by the Mine Safety and Health Administration’ (MSHA) and National Institute for Occupational Safety and Health (NIOSH). Respirators may be: —— pressure—demand, self-contained breathing aaratus (SCBA) or pressure-demand, airline respirator (with escape bottle, for’ Immediately Dangerous to Life’ and Health (IDLH) or potential for IDLH atmosphere) — ‘ Fully encapsulating chemical—resistant suit — Covéralls* — Long cotton underwear* — Gloves (inner), chemical—resistant - Boots, chemical-resistant, steel toe and shank. (Depending on suit construction, worn over or under suit boot) — Hard hat* (under suit) - Disposable gloves and boot covers* (Worn over fully éncap— sulating suit) - Cooling unit* ‘2-Way radio communications* (inherently safe) 2. Criteria for selection Meeting any of these criteria warrants use of Level A Protection: — The chemical’ substance has been identified and requires the highest level of protection for skin, eyes, and the respiratory system based on: ‘ -- measured (Or potential for) high concentration of’ *Optjonal 1—3 ------- atmospheric vapors, gases, or particulates or —- site operations and work functions involves high potential for splash, immersion, or exposure to un- expected vapors, gases, or particulates of materials highly toxic to the skin. Substances with a high degree of hazard to the skin are known or suspected to be present, and skin contact i.s possible. Operations must be conducted in confined, poorly vent i- lated areas until the absence of substances requiring Level A protection is determined. Direct readings on field Flame Ionization Dectors (FID) or Photoionization Detectors (P lO) and similar instruments indicate high levels •of unidentified vapors and gases in t e air. (See Appendixes I and II.) 3. Guidance on selection a. Fully encapsulating suits are primarily designed to provide a gas or vapor tight barrier between the wearer and atmospheric contaminants. Therefore Level A is gen—’ erally worn when high concentrations of airborne sub- stances are known or thought to be present and these substances could severely effect the skin., Since Level A requires the use of a self-contained breathing apparatus, the eyes and respiratory system are also more protected. Until air surveillance data are available to assist in the selection of the appropriate Level of Protection, the use of Level A may have to be ‘based on’ indirect evidence of the. potential for atmospheric contamination or other means of skin contact with severe skin affecting substances. Conditions that may require Level A protection include: — Confined spaces: Enclosed, confined, or poorly ventilated areas are conducive to build up of toxic vapors, gases, or particulates. (Explosive or oxygen—deficient’ atmospheres’ also are more probable in confined spaces.) Confined space entry does not automatically warrant wearing Level A pro- tection’, but should serve as a cue to carefully consider and to justify a, lower Level of Protection. Suspected/known highly’ toxic substa,nces: Various sub- stances that a,re highly toxic especially through skin ‘—4 ------- absorption for example, fuming corrosives, cyanide com- pounds, concentrated pesticides, Department of Tran- sportatiori Poison ‘A’ materials, suspected carcinogens, and infectious substances may be known or suspected to be involved. Field instruments may not be available to detect or quantify air concentrations of these materials. Until these substances are identified and concentrations - measured, maximum protection may be necessary. - Visible emissions: Visible air emissions from leaking containers or railroad/vehicular tank cars, as well as smoke from chemical fires and others, indicate high potential for concentrations of substances that could be extreme respiratory or skin hazards. — Job functions: Initial site entries are generally walk- throughs in which instruments and visual observations are used to make a preliminary evaluation of the hazards. In initial site entries, Level A should be worn when: —- there is a probability for exposure to high con- centrations of vapors, gases, or particulates. -- substances are known or suspected of being extremely toxic directly to the skin or by being absorbed. Subsequent entries are to conduct the many activities needed to reduce the environmental impact of the incident. Levels of Protection for later operations are based not only on data obtained from the initial and subsequent environmental moni- toring, but also on the probability of contamination and ease of decontamination. Examples of situations where Level A has been worn are: - Excavating of soil to sample buried drums suspected of containing high concentrations of dioxin. - Entering a cloud of chlorine to repair a value broken in a railroad accident. - Handling and moving drums known to contain oleum. - Responding to accidents involving cyanide, arsenic, and un- diluted pesticides. b. The fully encapsulating suit provides the highest degree of protecti9n to skin, eyes, and respiratory system if the suit material resists chemicals during the time the suit is worn. While Level A provides maximum protection, all suit material • • may be rapidly permeated and degraded by certain chemicals 1—5 ------- from extremely high air concentrations, splashes, or immersion of boots or gloves in concentrated liquids or sludges. These limitations should be recognized when specifying the type of fully encapsulating suit. Whenever possible, the suit material should be matched with the substance it is used to protect against. B. Level B Protection 1. Personnel protective equipment — Supplied-air respirator (MSHA/NIOSH approved). • Respirators may be: pressure-demand, self—contained breathing apparatus or —- pressure-demand, airline respirator (with escape bottle for IDLH or potential for IDLH atmosphere) - Chemical-resistant clothing (overalls and long-sleeved jacket; hooded, one or two-piece chemical—splash suit; disposable chemical-resistant, one—piece suits) - Long cotton underwear* - Coveralls* — Gloves (outer), chemical-resistant — Gloves (inner), chemical-resistant - Boots (outer), chemical-resistant, steel toe and shank — Boot covers (outer), chemical-resistant (disposable)* — Hard hat (face shield)* — 2-Way radio communications* (intrinsically safe) 2. Criteria for selection Meeting any one of these criteria warrants use of Level B, protection: - The type and atmospheric concentration of toxic substances • • has been identified and requires a high level of respira- tory protection, but less skin protection than Level A.’ ‘These would be atmospheres: ‘ *Optjonal T— 6 ------- with concentrations Immediately Dangerous to Life and Health, but substance or concentration in the air does not represent a severe skin hazard or -- that do not meet the selection criteria permitting the use of air—purifying respirators. The atmosphere contains less than 19.5% oxygen. — It is highly unlikely that the work being done will generate high concentrations of vapors, gases or particulates, or splashes of material that will affect the skin of personnel wearing Level B protection. Atmospheric concentrations of unidentified vapors or gases are indicated by direct readings on instruments such as the FID or PID or similar instruments, but vapors and gases are not suspected of containing high levels of chemicals toxic to skin. (See Appendixes I and II.) 3. Guidance on selection a. Level B does not afford the maximum skin (and eye) pro- tection as does a fully encapsulating suit since the. chemical-resistant clothing is not considered gas, vapor, or particulate tight. However, a good quality, hooded, chemical-resistant, one-piece garment, with taped wrist, ankles, and hood does provides a reasonable degree of protection against splashes and to lower concentrations in air. At most abandoned hazardous waste sites, ambient atmospheric gas or vapor levels have not approached concen- trations sufficiently high to warrant Level A protection. In all but a few circumstances (where highly toxic mater- ials are suspected) Level B should provide the protection needed for initial entry. Subsequent operations at a site require a reevaluation of Level B protection based on the probability of being• splashed by chemicals, their effect on the skin, the presence of hard-to-detect air contaim— inants, or the generation of highly toxic gases, vapors, or particulates, due to the work being done. b. The chemical—resistant clothing required in Level B is available in a wide variety of styles, materials, construc-. tion detail, and permeability. One or two-piece garments are avallabl,e with or without hoods. Disposal suits with a variety of fabrics and design characteristics are also available. Taping joints between the gloves, boots and suit, and between hood and respirator reduces the pos- siblity for splash and vapor or gas penetration. These 1—7 ------- factors and other selection criteria all affect the degree of protection afforded. Therefore, a specialist should select the most effective chemical-resistant clothing based on the known or anticipated hazards and job function. Level B equipment does provides a high level of protection to the respiratory tract. Generally, if a self—contained breathing apparatus is required for respiratory protection, selecting chemical—resistant clothing (Level B) •rather than a fully encapsulating suit (Level A) is based on needing less protection against •known or anticipated substances affecting the skin. Level B skin protection is selected by: - Comparing the concentrations •of known or identified substances in air with skin toxicity data. - Determining the presence of substances that are destruc- tive to or readily absorbed through the ski n by liquid splashes, unexpected high levels of gases, vapor, or particulates, or other means of direct contact. — Assessing the effect of the. substance (at its measured air concentrations or potential for splashing) on the small areas left unprotected by chemical—resistant clothing. A hooded garment taped to the mask, and boots •and gloves taped to the suit further reduces area of exposure. c. For initial site entry and reconnaissance at an open site, approaching whenever possible from upwind, Level B protec- tion (with good quality, hooded, chemical—resistant cloth- ing) should protect response personnel, providing the conditions described in selecting Level A are known or judged to be absent. C. Level C Protection 1. Personnel protective equipment — Air-purifying respirator, full-face, canister-equipped (MSHA/NIOSH approved) Chemical—resistant clothing (coveralls; hooded, one-piece or two-piece chemical splash suit; chemical-resistant hood and apron; disposable chemical—resistant coveralls) — Coveralls* Long cotton underwear* — Gloves (outer), chemical-resistant 1—8 ------- — Gloves (inner), chemical_resistant* — Boots (outer), chemical-resistant, steel toe and shank - Boot covers (outer), chemical-resistant (disposable)* - Hard hat (face shield*) - Escape mask* — 2—Way radio communications* (inherently safe) 2. Criteria for selection Meeting all of these criteria permits use of Level C protec- tion: — Oxygen concentrations are not less than 19.5% by volume. — Measured air concentrations of identified substances will be reduced by the respirator below the substance’s thres- hold limit value (TLV) and the concentration is within the service limit of the canister. - Atmospheric contaminant concentrations do not exceed IDLH levels. - Atmospheric contaminants, liquid splashes, or other direct contact will not adversely affect any body area left unprotected by chemical—resistant clothing.. — Job functions do not require self—contained breathing apparatus. - Direct readings are a few ppms above background on in- struments such as the FID or PID. (See Appendices I and II.) . - 3. Guidance on selection a. Level C protection is distinguished from Level B by the equipment used to protect the respiratory system, assuming the same type of chemical-resistant clothing is used. The main selection criterion for Level C is that conditions permit wearing air-purifying respirators. The air-purifying device must be a full—face respirator (MSHA/NflJSH approved) equipped with a canister suspended from the chin or on a harness. Canisters must be able to *Optjonal 1—9 ------- remove the substances encountered. Quarter-or half-masks or cheekcartridge, full-face masks should be used only with the approval of a qualified individual. Iii addition, a full—face, ’air-purifying mask can be used only if: — Substance has adequate warning properties. — Individual passes a qualitative fit—test for the mask. - Appropriate cartridge/canister is used, and its service limit concentration is not exceeded. b. An air surveillance program is part of all response opera- tions when atmospheric contamination is known or suspected. It is particularly important that the air be thoroughly monitored when personnel are wearing air—purifying respira- tors. Periodic surveillance using direct—reading instru- ments and air sampling is needed to detect any changes in air quality necessitating a higher level of respiratory protection. c. Level C protection with a fUll-face, air-purifying respi- rator should be worn routinely in an atmosphere only after the type of air contaminant is identified, concentrations measured and the criteria for wearing air-purifying respi- rator met. To permit flexibility in precribing a Level of Protection at certain environmental incidents, a specialist could consider using air-purifying respirators in uniden- tified vapor/gas concentrations df a few.parts per million above background as indicated by a needle deflection on the FID or PID. However a needle deflection of a few parts per million above background should not be, the sole criterion for selecting Level C. Since the individual components may never be completely identified,, a decision on continuous wearing of Level C must be made after asses.sing all safety considerations, including: — The presence of (or potential for) organic or. inorganic vapors/gases against which .a canister is ineffective or ‘has a short service life. ‘ ‘ — The known ‘(or suspected) presence in air of. substances •with loW TLVs or IDLH levels. ‘ ‘ . ‘ ‘• ‘ - The presence of particulates in air. - ‘•The errors associated with both the instruments and monitoring procedures used. ‘ *Optj onal 1—10 ------- — The presence of (or potential for) substances in air which do not elicit a response on the instrument used. - The potential for higher concentrations in the ambient atmosphere or in the air adjacent to specific site operations. d. The continuous use of air-purifying respirators (Level C) must be based on the identification of the substances contributing to the total vapor or gas concentration and the application of published criteria for the routine use of air—purifying devices. Unidentified ambient concen- trations of organic vapors or gases in air approaching or exceeding a few ppm above background require, as a mini- mum, Level B protection. D. Level D Protection 1. Personnel protective equipment — Coveralls - Gloves* — Boots/shoes, leather or chemical-resistant, steel toe and shank Safety glasses or chemical splash goggles* — Hard hat (face shield)* 2. Criteria for selection Meeting any of these criteria allows use of Level D protection: — No contaminants are present. - Work functions preclude splashes, imersion, or potential for unexpected inhalation of any chemicals. Level 0 protection is primarily a work uniform. It can be worn only in areas where there is no possibility of contact with contamination. III. PROTECTION IN UNKNOWN ENVIRONMENTS • In all incident response, selecting the appropriate personnel pro- tection equipment is one of the first steps in reducing health effects from toxic substances. Until the toxics hazards at an environmental incident can be ident ified and personnel safety measures I—i I ------- commensurate with the hazards instituted, preliminary measures will have to be based on experience, judgment, and prdfessional, knowledge. One of the first concerns in evaluating an unknown situation is- atmospheric hazards. Toxic concentrations (or potential concentra- tions) of vapors, gases, and particulates; low oxygen content explo- sive potential and, to a.lesser degree, the possibility of radiation exposure all represent immediate atmospheric hazards. In addition to making air measurements to determine these hazards, visual observa- tion and review of existing data can help determine the potential risks from othermaterials. Once immediate hazards, other than toxic substances have been elimi- nated, the initial on-site survey and reconnaissance, which may consist of more than one entry, continues. Its purpose is to further characterize toxic hazards and, based on these findings, refine preliminary safety requirements. As data are obtained from the initial survey, the Level of Protection and other safety procedures are adjusted. Initial data also provide information on which to base further monitoring and sampling. No one method can determine a Level of Protection in all unknown environments. Each situation must be examined individually. 1—12 /t Arthur D. Little, Inc. ------- APPENDIX J DOFFING PROCEDURES (Excerpted from “Standard Operating Safety GuidelineS,” 1984, Office of Emergency and Remedial. Response, U.S. Environmental Protection Agency) J-1 ------- PART 7 SITE CONTROL - DECONTAMINATION I. INTRODUCTION Personnel responding to hazardous substance incidents may become contaminated in a number of ways including: — Contacting vapors, gases, mists, or particulates in the air. - Being splashed by materials while sampling or opening containers. — Walking through puddles of liquids or on contaminated soil. - Using contaminated instruments or equipment. Protective clothing and respirators help prevent the wearer from becoming contaminated or inhaling contaminants; while good work practices help reduce contamination on protective clothing, instru- ments, and equipment. Even with these safeguards, contamination may occur. Harmful mate- rials can be transferred into clean areas, exposi.ng unprotected personnel. In removing contaminated clothing, personnel may contact contaminants on the clothing or inhale them.. To prevent such occur- rences, methods to reduce contamination, and decontamination proced- ures must be developed and established before anyone enters a site and must continue (modified when necessary) throughout site opera- ti ons. Decontamination consists of physically removing contaminants or changing their chemical nature to innocuous substances. How extensive decontamination must be depends on a number of factors, the most important being the type of contaminants involved. The more harmful the contaminant, the more extensive and thorough decontamination must be. Less harmful contaminants may require less decontamination. Combining decontamination, the correct method of doffing personnel protective equpment, and the use of site work zones minimizes cross— contamination from protective clothing to wearer, equipment to personnel, and one area to another. Only general guidance can be given on methods and techniques for decontamination. The exact procedure to use must be determined after evaluating a number of factors specific to the incident. II. PRELIMINARY CONSIDERATIONS A. Initial Planning J—2 ------- The initial decontamination plan assumes all personnel and equip- ment leaving the Exclusion Zone (area of potential contamination) are grossly contaminated. A system is then set up for personnel decontamination to wash and rinse, at least once, all the pro- tective equipment worn. This Is done in combination with a sequential doffln,g of protective equipment, starting at the first station with the most heavily contaminated item and progressing to the last station with the least contaminated article. Each piece precedure requires a separate station. The spread of contaminants during the washing/doffing process Is further reduced by separating each decontamination station by a minimum of 3 feet. Ideally, contamination should decrease as a person moves from one station to another further along in the line. While planning site operations, methods should be developed to prevent the contamination of people and equipment. For example, using remote sampling techniques, not opening containers by hand, bagging monitoring Instruments, using drum grapplers, watering down dusty areas, and not walking through. areas of obvious con- tamination would reduce the probability of becoming contaminated and require a less elaborate decontamination procedure. The initial decontamination plan Is based on a worst—case situ- ation or assumes no information Is available about the incident. Specific conditions at the site are then evaluated, including: — Type of contaminant. - The amount of contamination. - Levels of protection required. -. Type of protective clothing worn. The initial decontamination plan is modified, eliminating unneces- sary stations or otherwise adapting it to site conditions. For instance, the initial plan might require a complete wash and rinse of chemical protective garments. If disposable garments are worn, the wash/rinse step could be omitted. Wearing dis- posable boot covers and gloves could eliminate washing and rinsing these items and reduce the number of stations ‘needed. B. Contamination Reduction Corridor An area within the Contamination Reduction Zone Is designated the Contamination Reduction Corridor (CRC). The CRC controls access into and out• of the Exclusion Zone and confines decontamination activities to a limited area. The size of the corridor depends on the number of stations in the decontamination procedure, J—3 ------- ± 0 <2o <0 ‘- ‘ U 0 z&.) 0 U OO 0 00—0—0—--— REDRESS AREA s I- CONTAMINATION REDUCTION ZONE LAYOUT FIGURE 7 -1 HEAVY EQUIPMENT I DECONTAMINATION p AREA I I EXCLUSION ZONE EXIT PATH —*.G - _ —x— x— ——— — — x- x — — —x — x —g............ )— X— 1 CONTAMINATION REDUCTION ZONE ). < UO -e----—p— _o. _e_e._e. _ ____ ___ _ L 9 EA LEGEND HOTLINE 0 CONTROL LINE ACCESS CONTROL ‘ POINT. EXTRANCE ACCESS CONTROL POINT. EXIT SUPPORT •ZONE ENTRY PATH J—4 ------- overall dimensions of work control zones, and amount of space available at the site. A corridor of 75 feet by 15 feet should be adequate for full decontamination. Whenever possible, it should be a straight path. The CRC boundaries should be conspicuously marked, with entry and exit restricted. The far end Is the hotline — the boundary between the Exclusion Zone and the Contamination Reduction Zone. Personnel exiting the Exclusion Zone must go through the CRC. Anyone in the CRC should be wearing the Level of Protection designated for the decontamination crew. Another corridor may be required for heavy equipment needing decontamination. Within the CRC, distinct areas are set aside for decontamination of person- nel, portable field equipment, removed clothing, etc. These areas should be marked and personnel restricted to those wearing the appropriate Level of Protection. All activities within the corridor are confined to decontamination. Personnel protective clothing, respirators,, monitoring equipment, and sampling supplies are all maintained outside of the CRC. ‘Personnel don their protective equipment away from the CRC and enter the Exclusion Zone through a separate access control point at the hotline. III. EXTENT OF DECONTPJIINATION REQUIRED A. Modifications of Initial Plan The original decontamination plan must be adapted to specific conditions found at incidents. These conditions may require more or less personnel decontamination than planned, depending on; a number of factors. 1. Type of Contaminant The extent of personnel decontamination depends on the effects the contaminants have on the body. Contaminants do not ex- hibit the same degree if toxicity (or other hazard). When- ever it is known or suspected that personnel can - become contaminated with highly toxic or skin—destructive substances, a full decontamination procedure should be followed. If less hazardous materials are involved, the procedure can be down- graded. 2. Amount of Contamination The amount of contamination on protective clothing is usually determined visually. If it is badly contaminated, a thorough decontamination is generally required. Gross material remain- ing on the protective clothing for any extended period of time may degrade or permeate it. This likelihood increases J—5 ------- with higher air concentrations and greater amounts of liquid contamination. Gross contamination also increases the proba- bility of personnel contact. Swipe•tests may help determine the type and quantity of surface contaminants. 3. Level of Protection The Level of Protection and specific pieces of clothing worn determine on a preliminary basis the layout of the decontamin- ation line. Each Level of Protection incorporates different problems in decontamination and doffing of the equipment. For example: decontamination of the harness straps and backpack assembly of the self—contained breathing apparatus is dif- ficult. A butyl rubber apron worn over the harness makes decontamination easier. Clothing variations and different Levels of Protection may require adding or deleting stations. in the original decontamination procedure. 4. Work Function - The work each person does determines the potential for contact with hazardous materials. In turn, this dictates the layout of the decontamination line. For example, observers, photo- graphers, operators of air samplers, or others in the Ex- clusion Zone performing tasks that will not bring them in contact with contaminants may not need to have their garments. washed and rinsed. Others in the Exclusion Zone with a potentiaLfor direct contact with the hazardous material .will require more thorough decontamination. Different decontamin- ation lines could be set up for different job functions, or certain stations In a line could be omitted for personnel performing certain tasks. 5. Location of Contamination Contamination on the upper areas of protective clothing poses a greater risk to the worker because volatile compounds may generate a hazardous breathing concentration both for the worker and for the decontamination personnel. There is also an increased probability of contact with skin when doffing the upper part of clothing. 6. Reason for Leaving Site The reasdn for leaving the Exclusion Zone also determines the neea and extent of decontamination. A worker leaving the Exclusion Zone to pick up or drop off tools or instruments and imediately returning may not require decontamination. A worker leaving to get a new air cylinder or to change a respirator or canister, however, may require some degree of decontamination. Individuals departing the CRC for a break, lunch, or at the end of day, must be thoroughly decontaminated. J—6 ------- B. Effectiveness of Decontamination There is no method to in nediately determine how effective decon- tamination Is in removing contaminants. Discolorations, stains, corrosive effects, and substances adhering to objects nay in- dicate contaminants have not been removed. However, observable effects only indicate surface contamination and not permeation (absorption) into clothing. Also many contaminants are not easily observed. A method for determining effectiveness of surface decontamination is swipe testing. Cloth or paper patches — swipes — are wiped over predetermined surfaces of the suspect object and analyzed in a laboratory. Both the inner and outer surfaces of protective clothing should be swipe tested. Positive indications of both sets of swipes would Indicate surface contamination has not been removed and substances have penetrated or permeated through the garment. Swipe tests can also be done on skin or inside clothing. Permeation of protective garments requires laboratory analysis of a piece of the material. Both swipe and permeation testing provide after—the—fact Information. Along with visual obser- vations, results of these tests can help evaluate the effec- tiveness of decontamination. C. Equipment Decontamination equipment, materials, and supplies are generally selected based on availability. Other considerations are ease of equipment decontamination or disposability. Most equipment and supplies can be easily procured. For example, soft—bristle scrub brushes or long—handle brushes are used to remove contaminants. Water in buckets or garden sprayers is used for rinsing. Large galvanized wash tubs or stock tanks can hold wash and rinse solutions. Children’s wading pools can also be used. Large plastic garbage cans or other similar containers lined with plastic bags store contaminated clothing and equipment. Contam- inated liquids can be stored .temporarlly in metal or plastic cans or drums. Other gear includes paper or cloth towels for drying protective clothing and equipment. D. Decontamination Solution Personnel protective equipment, sampling tools, and other equip- ment are usually decontaminated by scrubbing with detergent-water using a soft—bristle brush followed by rinsing with copious amounts of water. While this process may not be fully effective in removing some contaminants (or in a few cases, contaminants may react with water), it Is a relatively safe option compared with using a chemical decontaminating solution. This requires that the contaminant be identified. A decon chemical Is then needed that will change the contaminant into a less harmful substance. Especially troublesome are unknown substances or J— 7 ------- mixtures from a variety of known or unknown substances. The appropriate decontamination solution must be selected in consul- tation with an experienced chemist. E. Establishment of Procedures Once decontamination procedures have been established, all person- nel requiring decontamination must be given precise instructions (and practice, If necessary). Compliance must be frequently checked. The time it takes for decontamination must be ascer- tained. Personnel wearing SCBA’s must leave their work area with sufficient air to walk to CRC and go through decontamination. IV. DECONTAMINATION DURING MEDICAL EMERGENCIES A. Basic Considerations Part of overall planning for incident response is managing medical emergencies. The plan should provide for: - - Some response team members fully trained in first aid and CPR. — Arrangements with the nearest medical facility for transporta- tion and treatment of Injured, and for treatment of personnel suffering from exposure to chemicals. — Consultation services with a toxicologist. — Emergency ey.e washes, showers, and/or wash stations. — First aid kits, blankets, stretcher, and resuscitator. In addition, the plan should establish methods for decontaminating personnel with medical problems and injuries. There is the possibility that the decontamination may aggravate or cause more serious health effects. If prompt life—saving first aid and medical’ treatment is required, decontamination procedures should be omitted. Whenever possible, response personnel should accom- pany contaminated victims to the medical facility to advise on matters involving decontamination. B. Physical Injury Physical injuries can range from a sprained ankle to a compound fracture, from a minor cut to massive bleeding. Depending on the seriousness of the’injury, treatment may be given at the site by trained response personnel. For more serious injuries, additional assistance may be required ‘at the site or the victim may have to be treated at a medical facility. J—8 ------- Life-saving care should be instituted ir mediately without consid- ering decontamination. The outside garments can be removed (depending on the weather) if they do not cause delays, interfere with treatment, or aggravate the problem. Respirators and back- pack assemblies must always be removed. Fully encapsulating suits or chemical—resistant clothing can be cut away. If the outer contaminated garments cannot be safely removed, the individ- ual should be wrapped in plastic, rubber, or blankets to help prevent contaminating the inside of ambulances and medical person- nel. Outside garments are then removed at the medical facility. No attempt should be made to wash or rinse the victim at the site. One exception would be if it is known that the individual has been contaminated with an extremely toxic or corrosive material which could also cause severe Injury or loss of life. For minor medical problems or Injuries, the normal decontamination procedure should be followed. C. Heat Stress Heat—related Illnesses range from heat fatigue to heat stroke, the most serious. Heat stroke requires prompt treatment to prevent Irreversible damage or death. Protective clothing may have to be Cut off. Less serious forms of heat stress require prompt attention or they may lead to a heat stroke. Unless the victim Is obviously contaminated, decontamination should be omitted or minimized and treatment beguniniiiedlately. D. Chemical Exposure Exposure to chemicals can be divided Into two categories: — Injuries from direct contact, such as acid burns or Inhalation of toxic chemicals. — Potential injury due to gross contamination on clothing or • equipment. - For inhaled contaminants treatment can only. be by qualified physicians. If the contaminant is on the skin or in the eyes, ininediate measures must be taken to counteract the substance’s effect. First aid treatment usually is flooding the affected area with water; however, for a few chemicals, water may cause more severe problems. When protective clothing is grossly contaminated, contaminants may be transferred to treatment personnel or the wearer and cause injuries. Unless severe medical problems have occurred simultaneously with splashes, the protective clothing should be washed off as rapidly as possible and carefully removed. ------- V. PROTECTION FOR DECONTAMINATION WORKERS The Level of Protection worn by decontamination workers is determined by: - •Expected or visible contamination on workers. — Type of contaminant and associated respiratory and skin haiards. - Total vapor/gas concentrations In the CRC. — Particulates. and specific inorganic or organic vapors in the CRC. - Results of swipe tests. A. Level C Use Level C includes a full-face, cáhister—type air-purifying respirator, hard hat with face shield (if splash is a problem), chemical—resistant boots and gloves, and protective clothing. The body covering recomended Is chemical-resistant overalls with an apron, or chemical—resistant overalls and jacket. A face shield Is reconinended to protect against, splashes because respirators alone may not provide this protection. The respirator should have a canister approved for filtering, any specific known contaminants such as amonia, organic vapors, acid gases, and particulates. . - B. Level B Use In situations where site workers may be contaminated with un- knowns, highly volatile’ ‘ liquids, or highly toxic materials, decontamination workers should wear Level B protection. Level B protection includes SCBA, hard hat with face shield, ‘chemical—resistant gloves, and protective covering. The clothing suggested is chemical-resistant overalls, jacket, and a rubber apron. The rubber apron protects the SCBA harness assembly and regulator from, becoming contaminated. VI. DECONTAMINATION OF EQUIPMENT Insofar as possible, measures shoUld be taken to prevent contamination of sampling and monitoring equipment. Sampling devices become con- taminated, but monitoring instruments, unless they are splashed, usually do not. Once contaminated, instruments are difficult to clean without damaging them. Any delicate instrument which cannot be easily decontaminated should be protected while it is being used. It J— 10 ------- should be placed in a clear plastic bag, and the bag taped and secured around the instrument. Openings are made in the bag for sample intake. A. Decontamination Procedures 1. Sampling devices Sampling devices require special cleaning. The EPA Regional Laboratories can provide information on proper decontamination methods. 2. Tools Wooden tools. are difficult to decontaminate because they absorb chemicals. They should be kept on site and handled only by protected workers. At the end of the response,. wooden tools should be discarded. For decontaminating other tools, Regional Laboratories should be consulted. 3. Respirators - Certain parts of contaminated respirators, such as the harness assembly and leather or cloth components, are difficult to decontaminate. If grossly contaminated, they may have to be discarded. Rubber components can be soaked in soap and water and scrubbed with a brush. Regulators must be maintained ‘according to manufacturer’s recoimnendations. Persons respon- sible for decontaminating respirators should be thoroughly trained in respirator maintenance. 4. ‘Heavy Equipment Bulldozers, trucks, back—hoes, bulking chambers, and other -heavy equipment. are difficult to decontaminate. The method generally used is to wash them with water under high pressure and/or to scrub accessible parts with detergent/water solution under pressure, if possible. In some cases, shovels, scoops, and lifts have been sand blasted or steam cleaned. Particular care must be given to those components In direct contact with contaminants such as tires and scoops. Swipe tests should be utilized to measure effectiveness. B. Sanitizing of Personnel ProtectIve Equipment Respirators, reusable protective clothing, and other personal articles not only must be decontaminated before being reused, but also sanitized. The inside of masks and clothing becomes soiled due to exhalation, body oils, and perspiration. The manufac- turer’s instructions should be used to sanitize the respirator mask. If practical, protective clothing should be machine washed after a thorough decontamination; otherwise it must be cleaned by hand. j—l I ------- C. Persistent Contamination In some instances, clothing and equipment will become contamin— anted with substances that cannot be removed by normal decontamin- ation procedures. A solvent may be used to remove such contamin- ation from equipment if it does. not destroy or degrade the pro- tective material. If persistent contamination Is expected, disposable garments should be used. Testing for persistent contamination of protective clothing and appropriate decon- tamination must be done by qualified laboratory personnel. D. Disposal of Contaminated Materials •. All materials and equipment used for decontamination must be disposed of properly. Clothing, tools, buckets, brushes, and all other equipment that is contaminated must be secured in drums or other containers and labeled. Clothing not completely decon- taminated on-site should be secured in plastic bags before being removed from the site. Contaminated wash and rinse solutions should be contained by using step—in-containers (for example, child’s wading pool) to hold spent solutions. Another containment method is to dig a trench about 4 inches deep, and line with plastic. In both cases the spent solutions are transferred to drums, which are labeled and disposed of with other substances on site.. VII. ANNEXES Annex 1, 2, and 3 describe basic decontamination procedures for a worker wearing Level A, B, or C protection. The basic decontamination lines (Situation 1), consisting of approximately 19 stations, are almost identical except .for changes necessitated .by different pro- tective clothing or respirators. For each annex, three specific situations are described in which the basic (or full decontamination) procedure is changed to take into account differences in the extent of contamination, the accompanying changes in equipment worn, and other factors. The situations illustrate decontamination setups based on known or assumed conditions at an incident. Many other variations are possible. Annex 4 describes a minimum layout for Level A personnel decontamin- ation. The number of individual stations have been reduced. Although the decontaminationequiprnent and amount of space required is less than needed in the procedures previously described, there is also a much higher probability of cross—contamination. J—12 ------- ANNEX 1 LEVEL A DECONTAMINATION A. E JIPMENT WORN The full decontamination procedure outlined is forworkers wearing Level A protection (with taped joints between gloves, boots, and suit) consisting of: - Fully encapsulating suit. — Self-contained breathing apparatus. - Hard hat (optional). — Chemical—resistant, steel toe and shank boots. - Boot covers. — Inner and outer gloves. B. PROCEDURE FOR FULL DECONTAMINATION Station 1 : Segregated Equipment Drop Deposit equipment used on—site (tools,sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. Each will be contaminated to a different degree. Segregation at the drop reduces the probability of cross—contamination. Equipment: various size containers plastic liners plastic drop cloths Station 2: Boot Cover and Glove Wash Scrub outer boot covers and gloves with decon solution or detergent! water. Equipment: container (20—30 gallons) decon solution or detergent water 2-3 long—handle, soft—bristle scrub brushes J- 13 ------- Station 3 : Boot Cover and Glove Rinse Rinse off decon solution from Station 2 using copious amounts of water. Repeat as many times as necessary. Equipment: container (30—50 gallons) or high—pressure spray unit water 2—3 long—handle, soft-bristle scrub brushes Station 4 : Tape Removal Remove tape around boots and gloves, and deposit in container with plastic liner. Equipment: container (20—30 gallons) plastic liners Station 5 : Boot Cover Removal Remove boot covers and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners bench or stool Station 6 : Outer Glove Removal Remove outer’ gloves and deposit in container with plastic liner. Equipment: container (20—30 gallons) plastic liners Station 7 : Suit/Safety Boot Wash Thoroughly wash fully encapsulating suit and boots. Scrub suit and boots with long—handle, soft-bristle scrub brush and copious amounts of decon solution or detergent/water. Repeat as many’ ‘times as necessary. Equipment: container (30—50 gallons) decon solution or detergent/water 2—3 long—handle, soft-bristle scrub brushes’ j— 14 ------- Station 8 : Suit/Safety Boot Rinse Rinse off decon solution or detergent/water using copious amounts of water. Repeat as many times as necessary. Equipment: container (30—50 gallons) or high—pressure spray unit water 2-3 long handle, soft—bristle scrub brushes Station 9 : Tank Change If worker. leaves Exclusion Zone to change air tank, this is the last step in the decontamination procedure. Worker’s air tank is exchanged, new outer gloves and boots covers donned, and joints taped. Worker then returns to duty. Equipment: air tanks tape boot covers ,gloves Station 10 : Safety Boot Removal Remove safety boots and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners bench or stool boot jack Station 11 : Fully Encapsulating Suit and Hard Hat Removal With assistance of helper, remove fully encapsulating suit (and hard hat). Hang suits on rack or lay out on drop cloths. Equipment: rack drop cloths • . bench or stool. • Station 12 : SCBA Backpack Removal While still wearing facepiece, remove backpack and place on table. Disconnect hose from regulator valve and proceed to next station. Equipment: table J— 15 ------- Station 13 : Inner Glove Wash Wash with decon solution or detergent/water that will not harm skin. Repeat as many times as necessary. Equipment: basin or bucket decon solution or detergent/water small table Station 14 : Inner Glove Rinse Rinse with water. Repeat as many times as necessary. Equipment: water basin basin or bucket small table Station 15 : Facepiece Removal Remove faceplece. Deposit In container with plastic liner. Avoid touching face with fingers. Equipment: contaIner (30—50 gallons) plastic liners Station 16 : Inner Glove Removal Remove inner gloves and deposit in container with plastic liner. Equipment: container (20—30 gallons) plastic liners Station 17 : Inner Clothing Removal Remove clothing soaked with perspiration. Place in container with plastic liner. Inner clothing should be removed as soon as possible since there is a possibility that small amounts of contaminants might have been transferred In removing fully encapsulating suit. Equipment: container (30—50 gallons) plastic liners Station 18 : Field Wash Shower if highly toxic, skin—corrosive or skin—absorbable materials are known or suspected to be present. Wash hands and face if shower is not available. J— 16 ------- Equipment: water soap small table basin or bucket field showers towels Station 19 : Redress Put on clean clothes. A dressing trailer is needed in inclement weather. Equipment: tables chairs lockers clothes C. FULL DECONTAMINATION (SIT. 1) AND THREE MODIFICATIONS S I T • STATION NUMBER . 1 2 3 .4 5 6 I 7 8 9 10 11 12 13 14 . 15 16 17 18 19 1 X X X X X X X X X •X X X . X X X X . X X 2 X X X X X X X X X 3 X X X • X X X . X X X X 4 X X X X • Situation 1 : The individual entering the Contamination Reduction Corridor is observed to be grossly contaminated or extremely toxic substances are known or suspected tobe present. Situation 2 : Same as Situation 1 except individual needs new air tank and will return to Exclusion Zone. . J- 17 ------- Situation 3 : Individual entering the CRC is expected to be minimally contaminated. Extremely toxic or skin-corrosive materials are not present. No outer gloves or boot covers are worn. Inner gloves are not contaminated. Situation 4 : Same as Situation 3 except individual needs new air tank and will return to Exclusion Zone. J— 18 ------- ANNEX 2 LEVEL B DECONTAMINATION A. E JIPMENT WORN The full decontamination procedure outlined is for workers wearing Level B protection (with taped joints between gloves, boot, and suit) consisting of: - One—piece, hooded, chemical—resistant splash suit. — Self—contained breathing apparatus. — Hard hat. - Chemical-resistant, steel toe and shank boots. - Boot covers — Inner and outer gloves. B. PROCEDURE FOR FULL DECONTAMINATION Station 1 : Segregated Equipment Drop Deposit equipment used on—site (tools, sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. Each will be contaminated to a different degree. Segregation at the drop reduces the probability of cross—contamination. Equipment: various size containers plastic liners plastic drop cloths Station 2 : Boot Cover and Glove Wash Scrub outer boot covers and gloves with decon solution or detergent ! 1 water. Equipment: container (20—30 gallons) decon solution or detergent water 2—3 long-handle, soft-bristle scrub brushes J-. 1.9 ------- Station 3 : Boot Cover and Glove Rinse Rinse off decon solution from Statián 2 using copious amounts of water. Repeat as many times as necessary. Equipment: container (30—50 gallons). or high—pressure spray unit water 2—3 long—handle, soft-bristle scrub brushes Station 4 : Tape Removal Remove tape around boots and gloves and deposit in container with plastic liner. Equipment: container (20—30 gallons) plastic liners StatIon 5 : Boot Cover Removal Remove boot covers and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners bench or stool Station 6 : Outer Glove Removal Remove outer gloves and deposit in container with plasticliner. Equipment: container (20—30 gallons plastic liners Station 7 : Suit/Safety Boot Wash Thoroughly wash chemical-resistant splash suit, SCBA, gloves, and safety boots. Scrub with long—handle, soft-bristle scrub brush and copious amounts of decon solution or detergent/water. Wrap SCBA regulator (if belt-mounted type) with plastic to keepout water. Wash backpack assembly with sponges or cloths. Equipment: container (30—50 gallons) decon solution or detergent/water 2-3 long—handle, soft-bristle scrub brushes small buckets sponges or cloths J-2O ------- Station 8 : Suit/SCBA/Boot/Glove Rinse’ Rinse off decon solution or detergent/water using copious amounts ‘of water. Repeat as many times as necessary. Equipment: container (30—50 gallon’s) or high—pressure spray unit water small buckets 2-3 long—handle, soft—bristle scrub brushes sponges or cloths Station 9 : Tank Change If’ worker leaves Exclusion Zone to change air tank, this is the last step in the decontamination procedure. Worker’s air tank is exchanged, new outer gloves and boots covers donned, and joints taped. Worker returns to duty. Equipment: air tanks ‘tape boot’ covers gloves Station 10 : Safety Boot Removal Remove safety boots and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners bench or stool boot jack Station 11 : SCBA Backpack Removal While still wearing facepiece, remove backpack and place on table. Disconnect hose from regulator valve and proceed to next station. Equipment: table Station 12 : Splash Suit Removal With, assistance of helper, remove splash su’it. Deposit in container with plastic liner. ‘ Equipment: container (30—50 gallons) plastic liners bench or stool J—21 ------- Station 13 : Inner Glove Wash Wash inner gloves with decon solution or detergent/water that will not harm skin. Repeat as many times as necessary. Equipment: decon solution or detergent/water basin or bucket small table Station 14 : Inner Glove Rinse Rinse inner gloves with water. Repeat as many times as necessary. Equipment: water basin or bucket small table Station 15 : Facepiece Removal Remove facepiece. Avoid touching face with gloves. Deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners Station 16 : Inner Glove Removal Remove inner gloves and deposit In container with plastic liner. Equipment: contaIner (20—30 gallons) plastic liners Station 17 : Inner Clothing Removal Remove clothing soaked with perspiration. Place In container with plastic liner. Do not wear inner clothing off—site since there is a possibility small amounts of contaminants might have been transferred in removing fully encapsulating suit. Equipment: container (30—50 gal lons) plastic liners Statioi 18 : Field Wash Shower if highly toxic, skin—corrosive, or skin—absorbable materials are known or suspected to be present. Wash hands and face If shower is not available. -22 ------- Equipment: water soap small tables basins or buckets field showers Station 19 : Redress Put on clean clothes. A dressing trailer Is needed in inclement weather. Equipment: tables chairs lockers clothes C. FULL DECONTAMINATION (SIT. 1) AND THREE MODIFICATIONS •I T : STATION NUMBER 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 1 X X X X X •X X X X X .X X X X X X X X 2 X X X X X X X X X .. X . 3 X X X X X X X X X X 4 X X X X - Situation 1 : The individual entering the Contamination Reduction Corridor is observed to be grossly contaminated or extremely toxic substances are known or suspected to be present. Situation 2 : Same as Situation 1 except individual needs new,air tank and will return to Exclusion Zone. j—23 ------- SItuation 3 : Individual entering the CRC is expected to be minimally contaminated. Extremely toxic or skin—corrosive materials are, not present No outer gloves or boot covers are worn. Inner gloves are not contaminated. Sttuatlon4 : Same as Sltuatlon.3 except lndivlduaYneeds new air tank • and will. return to Exclusion Zone. ‘ ‘ ‘ J—24 ------- ANNEX 3 LEVEL C DECONTAMINATION A. EQUIPMENT WORN The full decontamination procedure’outlined is for workers wearing Level C protection (with taped joints between gloves, boots, and suit) consisting of: — One-piece, hooded, chemical-resistant splash suit. — Canister equipped, full—face mask. — Hard hat. • — Chemical—resistant, steel toe and shank boots. - Boot covers. - Inner and outer gloves. B. PROCEDURE FOR FULL DECONTAMINATION Station 1 : Segregated Equipment Drop Deposit equipment used on—site (tools, sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. Each will be: contaminated to a different degree. Segregation at the drop reduces the probability of cross—contamination. Equipment: various size containers plastic liners plastic drop cloths Station 2 : Boot Cover and Glove Wash Scrub outer boot covers and gloves with decon solution or detergent! wate r. Equipment: container (20—30 gallons) decon solution or detergent water 2-3 long-handle, soft-bri stle scrub brushes J— 25 ------- Station 3 : Boot Cover and Glove Rinse Rinse off decon solution from Station 2 using copious amounts of water. Repeat as many times as necessary. Equipment: container (30—50 gallons) or high—pressure spray unit water 2—3 long—handle, soft bristle scrub brushes Station 4 : Tape Removal Remove tape around boots and gloves and deposit In container with plastic liner. Equipment: container (20—30 gallons) plastic liners Station 5 : Boot Cover Removal Remove boot covers and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners bench or stool Station 6 : Outer Glove Removal Remove outer gloves and deposit in container with plastic liner. Equipment: container (20—30 gallons) plastic liners Station 7 : Suit/Safety Boot Wash Thoroughly wash splash suit and safety boots. Scrub with long— handle, soft—bristle scrub brush and copious amounts of decon solution or detergent/water. Repeat as many times as necessary. Equipment: container (30—50 gallons) decon solution or detergent/water 2-3 long—handle, soft-bristle scrub brushes Station 8 : Suit/Safety Boot Rinse ------- •Rinse off decon solution or detergent/water using copious amounts of water. Repeat as many times .as necessary. Equipment: container (30—50 gallons) • or high—pressure spray unit water 2—3 long—handle, soft—bristle scrub brushes Station 9 : Canister or Mask Change ‘If worker leaves Exclusion Zone to change canister (or mask), this isthe last step in the decontamination procedure. Worker s canister is exchanged, new outer gloves and boots covers donned, and joints taped. Worker returns to duty. Equipment: canister (or mask) tape boot covers gloves Station 10 : Safety Boot Removal Remove, safety boots and deposit in container with plastic liner. Equipment: container (30—50 gallons) plastic liners - bench or stool boot jack Station 11 : Splash Suit Removal With assistance of helper, remove splash suit. Deposit in container. ‘with plastic liner. Equipment: container (30—50 gallons) bench or stool, liner Station 12 : Inner Glove Wash Wash ‘inner gloves with decon solution or detergent/water that will not harm skin. Repeat as many times as necessary. Equipment’: decon solution • ‘ or detergent/water basin or bucket, ------- Station 13 : Inner Glove Rinse Rinse inner gloves with water. Repeat as many times as necessary. Equipment: water basin or bucket small table Station 14 : Facepiece Removal Remove facepiece. Avoid touching face with gloves. Deposit facepiece in container with plastic liner. Equipment: contaIner (30—50 gallons) plastic liners Station 15 : Inner Glove Removal Remove inner gloves and deposit in container with plastic liner. Equipment: container (20-30 gallons) plastic liners Station 16. : Inner Clothing Removal Remove clothingsoaked with perspiration. Place in container with plastic liner. Do not wear inner clothing off-site since there is a possibility small amounts of contaminants might have been transferred In removing splash suite. Equipment: container (30—50 gallons) plastic liners Station 17 : FIeld Wash Shower If highly toxic, skin—corrosive or skin—absorbable materials are known or suspected to be present. Wash hands and face if shower is not available. Equipment: water soap tables wash. basins/buckets field showers Station 18 : Redress Put on clean clothes. A dressing trailer Is needed in inclement weather. j—2S ------- Equipment: tables chai rs lockers clothes. C. . FULL DECONTAMINATION (SIT, 1) AND THREE MODIFICATIONS S I T . STATION NUMBER . 1 2 3 4 5 6 . 7 8 9 10 11 12 13 14 15 16 17 18 1 X X X X X X X X X X X X X X X X X X 2 X X X X X X X X • • . X • X X .X X .X X X X 4 X X X X Situation 1 : The individual entering the Contamination Reduction Corridor is observed to be grossly contaminated or extremely skin corrosive substances are known or suspected to be present. Situation 2 : Same as Situation 1 except individual needs new canister or mask and will return to Exclusion Zone. Situation 3 : Individual entering the CRC is expected to be minimally contaminated. Extremely skin—corrosive materials are not present. No outer gloves or boot covers are worn. Inner gloves are not, contaminated. Situation 4 : Same as Situation 3 except individual needs new canister or mask and will return to Exclusion Zone. j—29 ------- ANNEX 4 LEVEL A DECONTAMINATION, MINIMUM LAYOUT A. E .JIPMENT WORN The decontamination procedure outlined is for workers wearing Level A protection (with taped joints between gloves, boots, and suit) consisting of: — Fully encapsulating suit with integral boots and gloves. — Self-contained breathing apparatus. — Hard hat (optional). — Chemical—resistant, steel toe and shank boots. - Boot covers. — Inner and outer gloves. B. PROCEDURE FOR FULL DECONTAMINATION Station 1 : Segregated Equipment Drop Deposit equipment used on—site (tools, sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. Each will be contaminated to a different degree. S.egregation at the drop reduces the probability of cross—contamination. Equipment: various size containers plastic liners plastic drop clothes Station. 2 : Outer Garment, Boots, and Gloves Wash and Rinse Scrub outer boots, outer gloves, and fully-encapsulating suit with decon solution or detergent water. Rinse off using copious amounts of water. . Equipment: containers (30—50 gallons) decon solution or detergent water J—30 ------- rinse water 2—3 long—handle, soft—bristle scrub brushes Station 3 : Outer Boot and Glove Removal Remove outer boots and gloves. .Deposlt 1n container with plastic liner. Equipment: container (30—50 gallons) plastic liners. bench or stool Station 4 : Tank Change If worker leaves Exclusion Zone to change air tank, this Is the last step in the decontamination procedure. Worker’s air tank is exchanged, new outer gloves and boot covers dOnned, joInts taped, and work’er returns to duty. Equipment: air tanks tape boot covers gloves Station 5 : Boot, Gloves, and Outer Garment Removal Boots, fully-encapsulating suit, and inner gloves removed and deposited In separate containers lined with plastic. Equipment: containers (30—50 gallons) - plastic liners bench or stool StatIon 6 : SCBA Removal SCBA backpack and facepiece is removed. Hands and face are thoroughly washed. SCBA deposited on plastic sheets. Equipment: plastic sheets basin or bucket soap and towels bench Station 7 : FIeld Wash Thoroughly wash hands and face. Shower as soon as possible.. J—3 1 ------- Equipment: water soap tables wash basin/bucket J•-32 ------- Guidelines, for the Selection of Chemical Protective Clothing 3rd Edition A.D. Schwope, Arthur D. Little, Inc. P.P. Costas, Arthur D. Little, Inc. J.O. Jackson, Los Alamos National Laboratory J.O. StuII, U.S. Coast Guard D.J. Weitzman, U.S. Environmental Protection Agency February 1987 Office of Administration Volume II: Technical and Reference Manual Occupational Health and Safety Staff ------- DISCLAIMER Arthur D. Little, Inc., prepared this document with what it believes is the best currently available information. The document is subject to reVision’..a .add tio ’iáI knbwl’edge-.and experience are gained; Arthur D. Little cannot guarantee the accuracy of information used to deyelop° the chemical protective clothing recommendations contain d herein arid the mention of company names or products does not constitute endorsement by Arthur D. Little. Arthur D. Little accepts no responsibility for damages or liabilities of any kind which may be claimed to result from the use of this document. 1] ------- ACKNOWLEDGEMENTS This Guidelines for the Selection of Chemical Protective Clothing was prepared by Arthur D. Little, Inc. (Cambridge, Massachusetts), under subcontract to Los Alamos National Laboratory (New Mexico) for the U.S. Environmental Protection Agency (EPA) and the U.S. Coast Guard. Particularly helpful in the preparation of this, the third edition of the Guidelines were J.F. Stampfer.and H.J. Ettinger (Los Alamos National Laboratory) and Krister Forsberg. Mr. Forsberg of the Royal Institute of Technology (Stockholm) reviewed each line of data presented in Appendix A of Volume II for consistency with the original literature sources. We also thank Dr. Douglas Walters of the National Toxicology Program for contributing an extensive compilation of glove permeation data generated for the NTP by the Radian Corporation. The text, except for the addition of Chapter 5--Full-Body Protection to Volume I, remains essentially the same (although updated) as the first EPA and ACGIH editions for which we note the support and review comments of W. Aaroe, B.E. Benson, S.P. Berandinelli, R. Ellis, E.R. 1-loyle, K. Flunninen, R.F. Kent, W.F. Keffer, A.P. Nielson, R.C. Magor, M.D. Royer, A. Smith, R.S. Stricoff, F. Thompson, R.D. Turpin, L. Walz, and R.W. Weeks. In addition, we appreciate the assistance of encapsulating ensemble manufacturers in the preparation of Appendix C of Volume I. The authors also acknowledge the contributions of the Arthur D. Little project team which included William Hawes, whose programming skills greatly facilitated the information organization task and T. Carroll, C. Luciano, M. Rourke, and D. Ryan, who assisted us in gathering and inputing the information. Finally, we thank the typists and report production specialists who assembled the document. 111 ------- SPECIAL NOTE TO USERS This document contains comprehensive tables of recommendations to aid and facilitate the selection of chemical protective clothing (CPC). The recommendations are based on an extensive compilation and analysis of CPC vendors’ literature and experimentaltest data published in techni- cal journals and reports. It is imperative that users of the recommen- dation tables familiarize themselves with the background information that precedes and accompanies the. tables. The selection of CPC must take into account the potential hazard and the conditions of use- - • neither is considered in this document. The recommendations are not nor do they imply a guarantee of safety. Although every effort has been made to prepare this docum nt as accu- •rately as possible, errors can and do occur. Users of this document are asked to notify Lt. Jeffrey 0. Stull, Commandant (G-DMT-3), U.S. Coast Guard, 2100 Second Street, S.W., Washington, D.C. 20593 (202-267-0853), or Mr. David Weitzman, U.S. Environmental Protection Agency, Office of Occupational Health and Safety, Room 3503, Waterside Mall, 401 M Street, S.W., Washington, D.C. 20460 (202-382-3647) of errors so that they can be corrected. iv ------- TABLE OF CONTENTS VOLUME II Page CHAPTER 1 - OBJECTIVES, LIMITATIoNS AND ASSUMPTIONS FOR THE GUIDELINES 1 A; INTRODUCTION 1 B. OBJECTIVES 1 C. LIMITATIONS 2 D. ASSUMPTIONS 3 E. INSTRUCTIONS FOR GUIDELINES USE 3’ CHAPTER 2 - PERMEATION THEORY 4 A. INTRODUCTION 4 B. IDEAL PERMEATION 4 C. ANOMALOUS PERMEATION .8 D. PERSISTENT PERMEATION 9 E. CHEMICAL CLASSIFICATION AND 9 SOLUBILITY PARAMETER CHAPTER 3 - TEST METHODS 12 A. INTRODUCTION 12 B. SOLUBILITY 12 C. DEGRADATION 13 D. PERMEATION , 13 E. VISIBILITY . 16 F. PENETRATION . 16’ G. OTHER FACTORS 17 V ------- CHAPTER A. B. C. D. CHAPTER A. B. C. D.. BIBLIOGRAPHY APPENDICES - APPENDIX A APPENDIX B APPENDIX C APPENDIX D APPENDIX E APPENDIX F APPENDIX APPENDIX Page 20 20 20 23 24 25 25 25 26 26 28 63 A-i B-i C-i D-i E-i F-i •G-i H-i TABLE OF CONTENTS (CONTINUED) 4 - ANALYSIS OF THE VENDORS’ LITERATURE INTRODUCTION REVIEW OF VENDORS’ LITERATURE PERSPECTIVES ON VENDORS’ LITERATURE CONCLUS ION 5 - SOURCES OF CHEMICAL PROTECTIVE CLOTHING INFORMATION INDUSTRY GOVERNMENT PROFESSIONAL ORGANIZATIONS TECHNICAL LITERATURE DESCRIPTION OF COLUMN HEADINGS FOR APPENDICES A THROUGH E - - PERMEATION DATA - WEIGHT CHANGE DATA -. SWELLING DATA - DIFFUSION COEFFICIENTS - TENSILE DATA - PERMEATION DATA FOR MULTI-COMPONENT LIQUIDS G - VENDOR CODES FOR USE WITH DATA SUMMARIES IN APPENDICES A THROUGH E H - RATIONALE FOR RECOMMENDATIONS IN MATRIX A vi ------- CHAPTER 1 OBJECTIVES, LIMITATIONS AND ASSUMPTIONS FOR THE GUIDELINES A. INTRODUCTION The selection of the best chemical protective clothing (CPC) for use against a particular chemical can be a difficultand perplexing task. A principal reason for this situation is that the necessary information, if any is available, has not been organized. Vendors’ recommendations tables provide guidance but there is little or no basis on which to compare products. Technical reports of CPC performance have increased in number in recent years, but are scattered through the literature, and again, there is no standard format for reporting data. TheEPA’s Occupational Health and Safety staff has repeatedly faced this situation in its attempts to’ provide guidance to field personnel in- volved in the clean-up of hazardous waste sites. Furthermore, the U.S. Coast Guard has particular needs for consolidating information on full-body protective ensembles. We, therefore, have developed this two-volume Guidelines for the Selection of Chemical Protective Clothing. This third edition of the Guidelines has been completely updated from those of 1983 and 1985. The key objectives, limitations, assumptions, and instructions for use of this publication are described in the following paragraphs. B. OBJECTIVES The main objective of the Guidelines is that it be a concise, up-to-date source for information relative to selection of personal protective clothing. Its principal focus is clothing for protection against chemicals which are potentially harmful to humans. More specifically, the Guidelines addresses the chemical resistance of protective clothing materials and the design features of full-body protective ensembles and splash suits. The Guidelines is designed to: . Educate (or review for) the user the technical concepts associated with the chemical resistant clothing. The goal is to provide the Guidelines user the background necessary to make the best possible decisions relative to selecting and using CPC. s Bring together and compare the considerable amount of vendors’ chemical resistance information with data published in the technical literature pertinent to CPC performance. The goal is to provide consensus recommendations as to the most appro- priate clothing for the chemicals of interest. 1 ------- • Provide listings of CPC products and a directory of CPC vendors. • Provide specific, detailed information on full-body protective clothing. • Aid further study of CPC by inclusion of a comprehensive reference listing. • Be readily updateable as more information becomes available. C. LIMITATIONS The scope of the Guidelines is limited to gloves, garments, boots, and lenses and face shields. Respirators are not covered. The chemicals are principally liquids, but a small number of gases and some solids with high vapor pressures are included. The chemicals were selected from the listings of Clean Water Act (CWA) Sections 311 and 307a, Clean Air Act (CAA) ‘Section 112, and Resource Conservation and Recovery Act (RCRA) Sections P,’U, F, and K. Also addressed were any other chemicals for which there were CPC manufacturers’ or vendors’ recommendations or technical reports of permeation or compatibility test results. Regarding the CPC manufacturers and vendors referred to in the directo- ry, the listing is not, all inclusive. The objective, however, is to include ,at least one source for any given item of CPC. In other words, it is unlikely that all distributors of certain brands/lines of CPC are mentioned. The listing is designed such that it can be readily expanded to cover additional manufacturers or distributors as they become known. ‘The recommendations, which compose Matrices ‘A and B, Volume I, Chapter 8, are the result of comparative analysis of both the vendors’ and technical literature in combination with technical judgment. For many chemicals the information available was sufficient for there to be a high level of confidence in the recommendations; these recommendations are listed as’ double upper case letters in the Matrices. For other chemicals there was less information and the recommendations are listed in lower case. For many chemicals there was no information and no recommendation is given. ‘A further limitation is that the Guidelines does not address multi- component solutions in-depth. Such mixtures, especially where several organic solvents are involved can have greater permeation than any one. of the components alone. Special care must be taken when solutions are involved. Furthermore, the Guidelines does not consider all the possi- ble applications to which CPC will be put. 2 ------- D. ASSUMPTIONS The Guidelines is developed under three key assumptions: • Its users would have a background in the physical sciences and, specifically, chemistry. • Its users would have some information about the identity of the chemicals to which the CPC may be exposed. • Its users would have some information about the degree of hazard with which the worker may be faced. The Guidelines provides ratings of the expected performance of the materials of construction of CPC. The Guidelines does not prescribe the level of clothing necessary for a given task, although Appen- dix I of Volume I provides some assistance in this regard. E. INSTRUCTIONS FOR GUIDELINES USE The Guidelines is divided into two volumes. Volume I is directed more towards day-to-day field use, while Volume II is designed more as a reference manual. The individual responsible for selecting CPCat the hazardous waste site should be familiar with all. aspects of Volume I. It provides: • Basic discussions of chemical resistance and permeation of CPC materials. • Recommendations for CPC for. 509 chemicals or aqueous solu- tions. • Detailed descriptions of full-body encapsulating ensembles. • Sources for acquisition of recommended clothing. The responsible on-site individual should also be aware of Volume II and its contents. Volume II, however, was designed principally to be used by the occupational health and safety professional providing further guidance to field personnel. The volumes are in loose-leaf format -to allow for rapid update in response to additional information on CPC performance and user comments. In this regard, all Guidelines users are asked to inform Lt. Jeffrey 0. Stull, Commandant (G-DMT-3), U.S. Coast Guard, 2100 Second Street, S.W., Washington, D.C. 20593 (202-267-0853), or Mr. David Weitzman, U.S. Environmental Protection Agency, Office of Occupational Health and. Safety, Room 3503, Waterside Mall, 401 M Street, S.W., Washington, D.C. 20460 (202-382-3647) of problems in understanding or using the Guide- lines. ------- CHAPTER 2 PERMEATION THEORY A. INTRODUCTION The purpose of the Guidelines is to facilitate the selection of CPC on the basis of its effectiveness as a barrier to potentially hazardous chemicals. Since chemical resistance is the focus, it is appropriate to include a discussion of permeation theory. In Chapter 3, Volume I, a brief overview of the key aspects of the theory is presented. The present chapter contains a more in-depth discussion of the subject. In addition several other theoretical factors which were considered in developing the CPC recommendations are summarized. B. IDEAL PE NEATION Permeation of a chemical through a barrier is a three-step transport process involving (1) the sorption of molecules of the chemical at the contacted surface of the barrier, (2) the diffusion of the sorbed mole- cules through the barrier, and (3) the desorption of the molecules from the opposite surface of the barrier. 83 , 84 In cases involving direct liquid contact with a clothing material, the diffusion step is the rate controlling step in the permeation process and, therefore, is the topic of the remainder of the discussion. The rate of mass diffusion through a unit surface area of a clothing barrier (or membrane) is proportional to the concentration gradient of the chemical (perineant) across the barrier. This relationship is most often expressed by Fick’s Law: J=Dr (1) where J is the mass flux, zg/min/cm 2 ; D is the diffusion coefficient, cm 2 /min; c is the concentration in the membrane, ig/cm 3 ; and x is the distance, in cm, from the contacted membrane surface. The minus sign in the equation accounts for a decreasing c as x in- creases. Integration of equation (1) results in a relationship which, is useful for determining the diffusion coefficient from test data. Once D is known for a given chemical/material pair, then the chemical flux can be 4 ------- estimated over a wide range of thicknesses and challenge concentration conditions. Such a prediction is appropriate since permeation criteria for protective clothing might ultimately be specified as a maximum allowable flux rather than a breakthrough time, as is more commonly the case today. Where D is not a function of chemical concentration, membrane thickness; or contact time (such as during the steady-state permeation of a non- reactive gas), this integration is straightforward and yields equation (2): J=DC 1 G 2 (2) .2 where C 1 is the permeant concentration in the upstream (higher concentra- tion) surface of the membrane (at x = 0); C 2 is the permeant concentration in the downstream surface of the membrane (at x = .2); and Q is the membrane thickness. In cases where D is a function of concentration, an integral diffusion coefficient can be defined as: I. l 1 Ddc (3) Cl C 2 Gil Examples of as a function of concentration would include: D=D (l+f (c)) f () D=De 0 where D is the zero-concentration diffusion coefficient. Such a concen- tration 0 dependence may occur when organics, such as solvent liquids, diffuse through polymeric materials. The result of integrating equation (1) with an integral diffusion coefficient is Equation (5): C 1 - C 2 J=_ _____ (5) 5 ------- It should be noted here that many polymers swell- - thereby changing their thickness- -upon the invasion of a permeating chemical. Crank discusses this on page 28 of The Mathematics of Diffusion. 83 Conventional practice is to disregard this change in the above integration and subsequent calculation of D. D or D can be determined by measuring both C 1 and the permeation flux. C 2 is considered to be 0 when permeation tests are carried out such that downstream membrane surface (at x = .2) is continuously exposed to and flushed by a fluid in which the concentration of the pernieant is far below saturation. In the case of the diffusion of a neat chemical, C 1 is the solubility of the compound in the polymer (L e., C 1 = C) and can be determined by a separate, long-term immersion experiment. The rate of permeation is typically determined by analytical methods such as CC, IR, •UV, or scintillation counting (in the case that the permeant is radio- labeled) of a collecting fluid that contacts the downstream surface of the membrane. ASTM Method F739-85 is an appropriate procedure for such testing. A graphical, idealized representation of chemical permeation through a membrane is presented in Figure 1 in terms of measured concen- tration versus contact time. - In practice, the determination of the diffusion coefficient is not always straightforward. Consequently, techniques have been developed for estimating this parameter at particular stages of the permeation process. Of particular importance because of the relative ease of their determina- tion and their utility in predictive models are the steady-state diffu- sion coefficient, D, and the lag time diffusion coefficient, DL. In the following paragraphs, the significance of these diffusion coefficients and methods for their determination are described. Other, more complex, methods for estimating D are presented by Crank 83 and Crank and Park. 84 1. Steady-State Diffusion Coefficient (Do) In ideal diffusion, a constant concentration gradient develops across the membrane and the flux becomes constant (i.e., steady-state permeation) following the transition period after breakthrough. (In many cases involving CPC, non-ideal diffusion occurs and a steady state does not develop. 222 ) A steady-state diffusion coefficient, D, can be calculated directly from equation (6): • Ds= (6) Cl assuming C 2 is small compared to C 1 . The steady-state coefficient may be useful in the selection of clothing materials in cases where some limited exposure to a permeating chemical may be acceptable. 6 ------- Membrane Exposure Time, t FIGURE 1 IDEAL PERMEATION THROUGH A POLYMERIC MEMBRANE — FIXED COLLECTION VOLUME —4 C 0 I.- 4- . C a, U C 0 0 E a, I . 4- ’ (I, C 0 a Steady State Transition Break through 0• ------- 2. Lag Time Diffusion Coefficient (DL) Ancther technique for calculating a diffusion coefficient is the lag time method. The lag time coefficient, DL, is determined by extending the steady-state portion of the permeation curve (see Figure 1) to the time axis. The time, TL, at the intercept is substituted into equation (7): DL= — (7) 6 TL and D calculated. DL may then be used in equation (2), but this is strict T ly valid only for those barriers in which the diffusion coefficient is constant. In many cases, DL is a good approximation for D and in some cases a fair approximation to for those barriers in wriich the diffusion coefficient is variable. In conclusion, it must be noted that at present there is no overall theory that allows the prediction of the permeability of CPC. Some of the problems faced in developing predictive methods are discussed in the next paragraph. C. ANOMALOUS PERMEATION In the previous paragraph ideal permeation was described as a diffusion process in which the breakthrough time is followed by a period of smooth transition to a steady-state situation in which the permeation rate does not change with time. Ideal diffusion is likely to occur with many of the chemical/material pairs experienced on a hazardous waste site. It should be recognized, however, that deviations (i.e., anomalies) from the ideal may occur in a large fraction of the cases. As the name implies, anomalous permeation is not predictable. However, there are sev2ral general conditions under which the probability of non-ideal permeation is increased: . where there may be a reaction of the chemical with the plastic/ elastomer of the CPC or some other component of the material. In some cases the reaction will lengthen the breakthrough time and reduce permeation rate by consuming chemical. In other •cases the reaction will reduce the barrier effectiveness of the CPC by degrading its properties. . where the chemical, merely by its being absorbed, changes the properties of the CPC. Many organic liquids are known to craze (produce surface cracks) in the hard, clear plastics used for lenses and face shields. 8 ------- • where the chemical extracts components from the CPC materials. For example, leaching of plasticizer from PVC clothing will significantly affect its barrier as well as functional proper- ties. Nelson et al. 222 , Weeks et al. 326 , 327 , and Crank and Park 84 present additional discussions of this subject. D. PERSISTENT PERMEATION Once a chemical has begun to diffuse into a plastic/elastomer, it will continue to diffuse even after the chemical on the surface is removed. This is due to the concentration gradient that develops within the CPC and the natural tendency for a gradient to equilibrate with its surround- ings. This phenomenon has significant implications relative to decontam- ination and reuse of CPC. First, in the case of CPC which has not suffered chemical breakthrough but has absorbed some chemical before the chemical is removed from the surface, the chemical may eventually appear on its inside surface. The amount of chemical reaching the inside will be dependent upon the amount of chemical absorbed and its permeation rate. For example, where the absorbed amount is small and the rate slow, it is likely that a large fraction of the absorbed chemical will return to the outside surface where, if it is volatile, it will evaporate to the air, and little or no chemical will reach the inside surface. On the other hand where the permeation rate is fast, there is the potential that a large amount of chemical will appear on the inside surface, perhaps after overnight storage in a locker.’’ 6 Second, in order to achieve complete decontamination of the CPC, both surface and absorbed chemical must be removed. Since the absorbed chemical will leave the CPC only by a diffusional process, either very long times or conditions which accelerate diffusion are required. These would include high temperatures, vacuum, or perhaps a dry-cleaning process in which a chemical non-degrading to the CPC is used to extract the hazardous chemical. Because of this problem of persistent permëa- tion, extreme caution is advised when using CPC that has been exposed to highly toxic chemicals. In fact, where such chemicals are involved, it may be prudent practice to use disposable clothing. E. CHEMICAL CL1 SSIFICATION AND SOLUBILITY PARANETER The Guidelines provides CPC recommendations for 509 chemicals or aqueous solutions. For those chemical/material pairs for which no recommenda- tions are given, it is suggested that CPC can be selected on the basis of the family to which the chemicals belong. The premise, which is substan- tiated in permeation literature, is that chemicals of similar composition 9 ------- or functional groups tend to permeate a given material at relatively similar rates. - Extensions and refinements of this premise are that: 262 3 1 5 • higher molecular weight members of a homologous series of chemicals permeate at slower rates than lower molecular weight members. • pendant groups (which increase the size of a molecule) tend to slow the permeation rate relative to that of the simple mole-. cule. • permeation rate tends to decrease with increasing boiling point. • polar chemicals tend to permeate polar materials more rapidly than non-polar chemicals, and the converse is true. The 509 chemical or aqueous solutions were, categorized into 29 main classes and 67 subclasses according to structure and functional. groups. 177 For example, hydrocarbons is a main class which is divided into aliphatic, aromatic, and polynuclear aromatic subclasses. The classes are listed in Table 8.1, Chapter 8 of Volume I. The class into which each chemical was placed can. be determined from Appendix B of Volume I. Upon review of those classes which contain a sufficient number of chemi- cals on which to base a conclusion, the above generalizations relative to the chemical resistance of materials would appear to ‘apply for most of the chemical/material pairs addressed in this study. A second means for predicting the chemical resistance of CPC materials is through the use of solubility parameter theory. This theory attempts to quantify the qualitative nature of the above generalizations. According to the theory, the physical and chemical properties of a chemical can be combined mathematically to yield a parameter that is then compared to an empirically determined parameter for the plastic/elastomer. In cases where the parameter of the chemical approximates that of the material, the chemical is predicted to have a high solubility in, or dissolve the material. In other words “likes dissolve likes.” Extrapolation of this theory to CPC implies that a material is not likely to be resistant to a chemical having a similar solubility parameter. An especially attractive feature of the theory is that solübility parameters can be calculated for multi-component solutions by weighting the individual parameters accord- ing to the relative concentrations of each component in the solution. Consequently, there is the potential for making decisions relative to selecting CPC for the virtually limitless number of solutions that may be encountered. 10 ------- T5rpical variations of the theory relate to the factors that are included in the calculation of the solubility parameter and how these parameters are weighted. One of the more widely accepted concepts is the three- component parameter which combines factors for the hydrogen bonding, polarity and dispersion forces of the chemical to yield its overall solubility parameter. Other systems deal with two of these factors. Still other systems favor the single-component solubility parameter and then make adjustments for polarity or hydrogen bonding depending on the application. Similar considerations are also required for the plastic/ rubber of CPC. - The results of a limited number of tests of the theory relative to CPC materials show some promise for its application to CPC selection. 287 Henriksen has reviewed the theory in considerable detail, and applied it to the data of Nelson et al. and his own data for epoxy solutions. 147 Christensen 70 has also subjected the data of Nelson et al. to an analysis based on solubility parameter. The data of Nelson are particularly useful in this regard since they result from a large number of experi- ments with a broad variety of chemicals with well-specified CPC. How- ever, it is important to note that the theory is just that, “a theory,” and that there are many variations of the theory, several of which are reviewed by Barton 38 and more recently by L. Snyder. 283 , 284 Although solubility parameter theory offers promise for predicting CPC performance, the application of the theory to CPC is in its early stages. Significant problems must be solved before the theory can be applied to the confident selection of CPC. For example, methods must be developed for estimating the two- and/or three-component factors for chemicals other than relatively simple solvents. Similarly, methods are required for estimating the solubility parameters of CPC materials. Perkins et al. have estimated the solubility parameters of selected CPC materi- als. 235 However, solubility parameters of CPC materials may be strongly influenced by formulation. Finally, it must be remembered that solubil- ity parameter theory is an equilibrium concept. It does not take into account the dynamics of the permeation process. •Also needed are approaches to predicting the time-containing element of the permeation equation, i.e., the diffusion coefficient. 11 ------- CHAPTER 3 TEST METHODS A. INTRODUCTION •The barrier effectiveness of a particular item of clothing to a particu- lair chemical/mixture is dependent on the specific interactions between the clothing material and the chemical/mixture. This in turn is deter- mined by the formulation of the clothing material, its method of manufac- ture, and its thickness. Temperature and other conditions of use also influence clothing barrier properties. Finally, the composition of the chemical/mixture is of major importance since relatively small percentag- es of a second, third, etc., component can drastically alter the way in which a chemical interacts with a material. With the above in mind it is highly desirable that protective clothing selection decisions be based on the results of testing of the chemi- cal/clothing material pair of nterést. The objective of such testing is to quantify the key parameters discussed in Chapter 2. Of particular concern are: • The solubilityof the chemical/mixture in the clothing material., f The breakthrough.time of the chemical for the material. • The permeation rate of the chemical through the material. B. SOLtJBILITY Solubility is the weight of chemical absorbed by a known weight of material. In general, chemicals having solubilities > 10% rapidly permeate the rubber or plastic. ASTM Method D471-79 and ISO Method 2025 (International Standards Organization) describe methods for determining solubility The procedure simply involves immersing the material in the chemical. In case of multi-layered clothing materials, only the normally outside surface should be exposed to chemical. If the solubility values are to be later used in calculating permeation rates, then each material of the multi-layer system should be tested separately. Periodically the material is removed, patted dry and weighed until a constant weight is obtained. In addition to noting weight changes, the chemical and the material should be inspected for discoloration, indicative of decomposi- tion of the clothing material. Also the clothing material should be examined for physical degradation using a knife, spatula, or other probe. Solubility testing is simple and can readily be performed wherever at. least a two decimal place balance is available. Multiple tests can be 12 ------- performed simultaneously using as little as 0.5 g and as much as 100 g of clothing material per test, depending on the sensitivity of the balance. Solubility testing represents the minimum level of evaluation that can be performed for any unknown or multi-component hazardous waste. C. DEGRADATION The physical and/or aesthetic qualities of CPC can be significantly and and undesirably changed due to exposure to chemicals. Chemical degrada- tion testing simply involves measuring the properties or qualities of interest before and after exposure to the chemical. The results are compared and the change, if there is any, judged as to its acceptability for the intended application of the item of clothing. ASTM Method D543 describes one such method for plastic materials. ASTM Committee F-23 is presently developing a method specifically focussed on clothing materi- als. Similar to solubility testing, degra&t’:ion can’ be performed in the field and can be used as a means for screening candidate clothing’materials prior to more involved and expensive testing such as the permeation test described below. D. PERMEATION Breakthrough time and permeation rate are determined by means of a permeation test. ASTM Method F739-85 was specifically developed for the evaluation of protective clothing’ materials. (‘A printed copy of this method is available from ASTM, 1916 Race Street, Philadelphia, PA 19103.) The method uses a test cell which is divided into two chambers at the midline by the clothing material to be tested. ‘(See Figure 2.) The potentially hazardous chemical is placed in one chamber and the other chamber (i.e., the collection chamber) is monitored for the chemical of interest. As shown, the cell is assembled for a liquid challenge chemi- cal. Gaseous chemicals can also be tested by forming the cell from two collection chambers. The test gas is then flowed continuously through the challenge chamber. Of interest are the time the chemical is first detected (i.e., breakthrough time) and the subsequent rate of permeation. Of critical importance in conducting the test is that the collecting medium not interact with the clothing material; air, nitrogen, helium, or water are preferred collection media. The detection of breakthrough is dependent on the sensitivity of the analytical method used for ‘measuring the chemical in the collection medium. Typical preferred analytical methods include gas, liquid and ion chromatography, analysis for total combustible organics, ultraviolet and infrared spectrophotometry, and radioanalysis. The properties of the chemical, the sensitivity requirements for the test, ‘and cost are the 13 ------- Challenge Chamber for - Test Chemical FIGURE 2. SKETCH OF ASTM F739-85 PERMEATION TEST CHAMBER Collection Chamber I. TF E-fluorocarbon Seal 14 ------- principal factors considered in selecting an analytical method. For relatively volatile chemicals, gas chromatography and infrared spectro- photometry are the preferred methods. Liquid chromatography is used for relatively nonvolatile organic compounds. Ion chromatography is particu- larly useful for inorganic acids and salts. Finally, radiolabelled compounds may be preferred where high sensitivity and specificity is required;. furthermore, if the compound of interest is readily, available in radiolabelled form, radiochemical methods may be significantly less costly than the development and use of the other techniques. Permeation testing of protective clothing materials has increased signif- icantly during the past five years. The Journal of the American Indus- trial Hygiene Association has become the principal vehicle for dissemina- tion of test findings. (See Bibliography.) Also of note is Standard Technical Publication 900 of the ASTM which contains several pertinent articles. 32 In addition permeation data are available from several clothing and clothing material vendors. 45 , 80 , 107 , 213 , 227 , 236 - The International Standards Organization (ISO) has promulgated two other methods for evaluating chemical protective clothing: • Method 6529 - Protective.Clothing Resistant to Penetration by Dangerous Liquid Chemicals. • Method 6530 - Clothing for Limited (ed.) Protection .Against Dangerous Liquid Chemicals. Neither method is recommended since the results are difficult to inter- pret relative to the’ selection of CPC. Presently ISO is in the final stages of developing a standard permeation test. This standard is analogous to .ASTM Method F739. A notable difference between the ASTM and ISO standards is the inclusion of clothing labelling (marking) instructions in the ISO method. The label must indicate the performance of the clothing material as a barrier to the test chemicals. Such labeling is an aid to those considering the use of the clothing much the same as fire extinguisher labels are. With the significant increase in permeation data in recent years, the need and opportunity for data interpretation and comparison have also increased. Permeation test results are highly dependent on the experi- mental procedure, generic material, cell configuration, and analytical sensitivity. ASTM Committee F-23 is presently developing a specification for data reporting that will facilitate interpretation and comparison of test results. This same committee has promulgated a list, of fifteen chemicals (ASTM FlOOl-86) that can serve as a standard battery for ranking clothing barrier properties. The fifteen chemicals represent a wide range of chemical families and are: acetone, acetonitrile, carbon disulphide, dichloromethane, diethylamine, dimethylforniami4e, ethyl 15 ------- acetate, n-hexane, methanol, nitrobenzene, 50% sodium hydroxide, sulfuric acid, tetrachioroethylene, tetrahydrofuran, and toluene. E. VISIBILITY Face shields and lenses, in addition to being chemical barriers, must provide clear, undistorted vision to the wearer. Hard, inflexible face shields and lenses may be subject to crazing (i.e., surface cracking) upon contact with certain chemicals. Crazing renders the surface foggy and can drastically reduce vision. Since chemical contact with the face shield or lens is more likely to occur in uncontrolled or emergency situations when reduced vision would be an additional severe hazard, shields and lens materials should be tested for resistance to chemical attack. Crazing can also reduce the impact strength of the material. ANSI/ASTM Method F484-77 describes a procedure for measuring stress crazing by chemicals. A method for assessing the effect of chemicals on clear plastics is by measuring the transparency of the plastic before and after exposure to the chemical; ASTM D1746 describes one such method. While both these methods will adequately show up potential incompatibili- ties, they require equipment that is not likely to be available in field or chemistry laboratories. A simpler test, which could be performed on site, requires only a placard on which are printed letters ranging from large to small in size. Analogous to a common vision test, the placard is read through an unexposed face shield or lens.material, with a dis- tance of 10 to 15 feet between the plastic and the placard. Note is made of the ease with which the letters can be read and the minimum size letter which can be read. The face shield or lens material is then swabbed or immersed in the chemical of interest for at least one hour. (Note, if the face shield or lens has different coatings or plastic layers on the inside and outside surfaces, only the outside surface should be exposed to the chemical.) Remove the material from the chemi- cal and allow to air dry. Inspect the material and repeat the placard reading test. F. PENETRATION In addition to permeation, which occurs by molecular diffusion, liquid chemicals can cross a CPC barrier by penetration. Penetration is the movement of chemical through holes such as at seams, zippers, and other closures as well as through flaws in the CPC. Penetration can also occur through porous woven and non-woven fabrics and through fabrics based on microporous films. Core-Tex is one brand of such nhicroporous film-based fabric. ASTM Committee F-23 has promulgated method F903-84 for the evaluation of the penetration resistance of CPC and its materials of construction. Briefly, a swatch of material or seam or closure is clamped in a two- 16 ------- chambered cell. The chemical of concern is charged to one chamber and pressure applied. The unexposed surface in the second chamber is ob- served for appearance of the chemical. G. OTHER FACTORS The focus of the Guidelines and the above discussion is chemical resis- tance of clothing materials. It is important to consider, however, that in the selection and use of protective clothing other factors may be of equal or greater importance. For example, gloves must provide the wearer some minimum level of dexterity, and the fabrics must have some level of tear resistance. The relative importance of the performance factors is largely dependent on the work tasks to be carried out. At present there is no standard, overall protocol for evaluating protec- tive clothing or clothing materials for all the performance parameters of importance to workers on hazardous waste sites. Instead, individual tests appropriate for the evaluation of specific parameters must be selected from the volumes of procedures promulgated by federal, military, and standards organizations. A 1978 NIOSH study addressed this problem •and resulted in a listing of test methods especially pertinent to protec- tive clothing. 78 That compilation has been expanded where appropriate and is presented herein as Table 3.1. For completeness, the chemical resistance methods mentioned above are included in the Table. In addi- tion to this listing, several tests specific to full-body protective clothing are disàussedin Chapter 5 of Volume I. 17 ------- TABLE 3.1 * TEST METHODS FOR CHEMICAL PROTECTIVE CLOTHING Characteristics Test A. Chemical Resistance 1. Permeation Resistance ASTMF739-81: Resistance of Protective Clothing Materials to Permeation by Hazardous Liquid • Chemicals 2. Swelling and Solubility ASTM D47l-79: Rubber.Property-- • Effects of Liquids 3. Strength Degradation ASTM D543: Resistance of Plastics to Chemical Reagents 4. Crazing ASTM F484-77: Stress Crazing of Acrylic Plastics in Contact With Liquid or Semi-Liquid Compounds 5. Transparency ASTM 1746-70: Trànsparencyof Plastic Sheeting 6. Penetration Resistance ASTM F9O3-84: Resistance of Protective Clothing Materials to Penetration by Liquids B. Strength 1. Tear Resistance ASTM D75l-73: Testing of Coated and Strength Fabrics - ASTM D412-75: Rubber Properties in Tension Fed. 191A-51O2 (ASTM Dl682): Strength and Elongation, Breaking of Woven Cloth: Cut Strip Method Fed. 191A-5l34 (ASTM D2261): Tearing Strength of Woven Fabrics by the Tongue Method 2. Puncture Resistance See Reference 78 3. Abrasion Resistance ASTM Dl175: Abrasion Resistance of Textile Fabrics 18 ------- TABLE 3.1 (Continued) *, TEST METHODS FOR CHEMICAL PROTECTIVE CLOTHING Characteristics Test C. Dexterity/Flexibility 1. . Dexterity (gloves only) See. References 78, 122, 289 2. Flexibility ASTM D1388: Stiffness of Fabrics, Cantilever Test Method D. Aging Resistance I. Ozone Resistance ASTM D3041-72: Coated Fabrics- - Ozone Cracking in a Chamber ASTM . Dll49 -64: Rubber Deterioration- - Dynamic Ozone Cracking in a Chamber 2. UV Resistance AS,.TM G27: Operating Xenon-Arc Type Apparatus for Light Exposure of Non-MetallIc Materials- -Method A--Continuous Exposure to Light * Physical property tests are listed in Tables 5.2 and 5.3 of Volume I. 19 ------- CHAPTER 4 ANALYSIS OF THE VENDORS’ LITERATURE A. INTRODUCTION Chapter’ 7 of Volume I contains an overview of the major strengths and weaknesses of the literature supplied by CPC vendors. The purpose and strength of this literature is to describe the composition, styles, and sizes of protective clothing. In recent years the literature of several clothing manufacturers has also become an important source of chemical resistance information, particularly permeation data. , However, much of the literature remains weak in its level of documentation as to the basis for the qualitative chemical resistance tables. As noted in Volume I, ratings tables are intended for and should, be used only for guidance in the selection of CPC. This chapter. extends the depth ‘of the ..Volume I discussion of the present vendors’ chemical resistance tables and discusses their future. B. REVIEW OF VENDORS’ LITERATURE The catalogues of 150 CPC vendors and materials suppliers were reviewed during the preparation of the Guidelines. Twenty-six of these documents included chemical resistance ratings charts for some or all of the products listed. These tables encompassed both qualitative and quantita- tive ratings. In only a few cases was the rationale for the qualitative ratings described in the catalogues. The rationale is necessary for any attempt to form conclusions regarding the expected performance of CPC and to compare products. Consequently, telephone interviews were conducted with the CPC vendors who provided qualitative ratings. The telephone interviews yielded little information that would further aid the utiliza- tion of the qualitative ratings. The overall impression was that most vendors are either not testing clothing or are not willing to share ‘their results. The situation is much different for the chemical resistance tables that are based on permeation test resuFts. Virtually all vendors who provide such data followed ASTM Method F739, or a similar procedure. 1. Per iieation Testing Permeation data are supplied or available on request from at least ten CPC vendors’ or materials suppliers. This number is up from six in 1985. Furthermore, the number of chemicals and range of products have increased significantly, and this increase can be expected to continue. CPC users have become more demanding of the vendors and the vendors have found that test data are useful as points of product differentiation. 20 ------- However, the increased availability of test results carries with it the problems associated with comparing and interpreting data. The vendors do not use a standard format for presenting the data and, as discussed earlier, the test results can be highly dependent on the testing proce- dure. In order to compare breakthrough times, it is necessary to know the sensitivity of the detector, the surface area of the clothing material, and the collection medium volume if the test is performed ma closed-loop mode or the collection medium flowrate if the test is performed in an open-loop mode. The following discussion provides some insights into reviewing and utilizing published breakthrough time and permeation rate data. Test results are available from the following vendors: Ansell, Best, ChemFab, Comasec, DuPont, Edmont, MSA, North, Pioneer, and Playtex. (see the Appendix D of Volume I for the complete corporate name and address.) All except Best provide breakthrough time data; Best ranks by break- through time the materials tested. All except MSA report permeation rate data 2 The units used by all except Edmont for permeation rate are mg/rn /s; Edmont reports values pg/cm /rnin, consistent with STM F739. Multiply the Edmont values by 0.167 to convert them to mg/m /s. Only Best and ChemFab report the sensitivity of the instrument used to detect breakthrough. Only MSA provides information on the mode of testing (open-loop) and’ the collection medium flowrate. Some of the others provide information on the mode of testing but not the collection medium volume or flowrate. Consequently, it is not possible to rigorously compare breakthrough time data from vendor to vendor. As suggested above and by the vendors themselves the data should be used for guidance only and imply no guarantee of protection. 2. Iliunersion Testing Most qualitative recommendations tables appear to be based on simple inunersion tests in which the material was merely observed after some time period. There is no standard time for immersion and, of course, the rating associated with any given test is likely to vary from observer to observer. Furthermore, in some cases materials that were swelled by chemicals may have been given an acceptable recommendation if upon drying they returned to their original size and appearance. Obviously a materi- al which is visibly swelled by a chemical will not be a barrier to that chemical and should be given a “not recommended” rating. At present there is no standard immersion test for CPC. ASTM Committee F-23 is considering several, but final acceptance is not expected before 1988. It is likely that the procedure will specify the immersion time and two or three properties to be measured before and after immersion. Initially a standard immersion test will be useful for identifying chemical/material pairs that are grossly incompatible. In time, once larger amounts of data become available from standard immersion and permeation tests, correlations may be developed that will allow more sensitive prediction of CPC performance from immersion test data alone. 21 ------- 3. Applicability of Ratings Tables The degree of applicability of some of the ratings tables to presently available CPC is somewhat limited by two factors: age and materials composition. Many of the tables are more than ten years old. Between the time that the tables were generated and now, it is ‘probable that the actual elastomer/plastic formulation used in the CPC has been changed. This may have resulted from a CPC manufacturer switching raw materials suppliers or modifying the formulation to meet changed processing, use or cost requirements. Changes to, for example, the plasticizer, lubricant, filler, and so forth, level in a elastomer/plastic formulation can in some cases significantly influence the chemical resistance of the final product. Significant differences exist between various vendors’ ratings for nominally the same CPC chemical/material pair. While this may be due to the subjectivity of the •test methods, there also may be real differences between products. The difference may in part be due to the fact that the different formulations of the same base elastomer/plastic material may perform differently, and in part due to the manufacturing methods. In other words, it is ‘possible for one supplier to have a more chemically resistant material (e.g., PVC or butyl rubber, etc.) than another supp]i- er. This point has been documented in the literature. 268 Similarly, most of the ratings charts appear to have been developed for a general class of material (for example, natural rubber or PVC) and not the specific formulations used for protective clothing. Thus, the ratings may or may not be directly applicable to CPC. The form of the elastomer/plastic can also influence the results on which recommendations may be based For example, a molded neoprene rubber can ‘have significantly different properties from those of a neoprene prepared from a latex. Within the realm of CPC, it has’ recently been suggested that gloves prepared by a latex process may perform differently from gloves prepared by a solvent-dip process, but that additional evaluation was required before definite conclusions could be reached. 326 It is not clear whether’ the recommendations of manufacturers which have switched from solvent t,o latex processing during the past 10 to 15 years have been modified to reflect any performance differences that may have resulted. The temperature range over which the ratings apply Is not generally stated. CPC users should note that there can be significant temperature effects on permeation over the temperature range likely to be encountered in the field. For example, the breakthrough times for benzene through a 0.08 cm neoprene were found to be 40 mm at 7°C, 24 mm at 22°C, and. 16 mm at 37°C. 78 ‘ Finally, the sensitivity, if any, of the ratings to lot-to-lot variations in the products are not provided. ‘Also some manufacturers rate several grades or thicknesses of a given CPC material as if they all performed 22 ------- similarly. In. these cases, the CPC user must carefully, scrutinize the catalogues in order to differentiate aiuong the products and make the best selection for the application at hand. 4. Multi-co nponent Solutions Multi-componet solutions represent a potentially large and difficult area for CPC selection and use. In. general, most vendors address only aqueous solutions in their ratings tables. ‘Several vendors are careful to ‘designate a concentration range for each reóoinmendation; many do not. Small fractions of particularly permeable chemicals in a solution can severely degrade clothing materials or can provide pathways for the movement of other components of the solutions. Furthermore, there is an unlimited number of solution compositions possible. Generally, the vendors recommend that the CPC buyer conduct his own tests with the specific solutions of concern. Multi-component solutions are of growing interest to the research community and others.’° 4 ,’ 24 , 278 , 302 5. Experience Several manufacturers reported that some of the recommendations appearing in their tables were based. on experience rather than testing.’ This ‘may or may not be appropriate depending on how the experience was judged. For example, in many cases,an item of CPC may be considered good for a particular application because it does not fall -apart or’ because it returns to its original shape/size upon evaporation of absorbed chemical.. Obviously such criteria are not appropriate if skin contact with the chemical is a primary concern. On the other hand, experience can be a suitable basis for a recommenda- tion- when’ it originates from careful observation of worker well-being. For example, a particular type of glove may. prevent contact dermatitis” where all other gloves fail. ‘ ‘ . . C. PERSPECTIVES ON VENDORS’ LITERATURE Although the above findings and comments can be rather perplexing, for those responsible for selecting CPC, the situation is changing rapidly for the better: • There is a growing general understanding among CPC buyers that chemicals can permeate CPC without there being any outward sign of degradation or swelling of the material. • There is growing technical/scientific interest in CPC perfor- mance. Many of the larger chemical companies, several indepen- dent testing laboratories, and some universities now have groups evaluating CPC materials. , Furthermore, the federal government has become keenly aware of the need for rigorous 23 ------- analysis of CPC performance, as evidenced by this publication and an increase in government sponsored research and develop- ment. • The general acceptance of a standard permeation test method. • Vendors are becoming more comfortable with the liability aspects of publishing test data. In fact publishing data obtained under well-specified conditions may be less risky than the promulgation of qualitative recommendations tables. Vendors routinely print disclaimers along with their test data which caution that they may not. apply to. the particular condi- tion to which the buyer intends to subject CPC. The buyer is also advised to perform his own testing with the actual chemi- cal/chemical mixtures at the use temperatures. D. CONCLUSION The primary sources of information pertinent to the chemical resistance of CPC are the CPC vendors and manufacturers. This is not likely to change in the near future. Users of the vendors’ recommendations and data tables must always bear in mind the limitations of the charts, as described above. The tables are for guidance only. That is the charts are a good place to start the CPC selection process, but they are not guarantees of safety. Whenever possible, the potential CPC user should evaluate candidate products against the particular chemicals and solu- tions of concern. Final selection must take into account the CPC appli- cation. During the next several years, other sources for CPC recommendations can be expected to increase. Such sources, of which this publication is an example, will be based on the compilation of both manufacturers’ recom- mendations and the scientific literature. It is reasonable to predict and it is hoped that the existence of one or more key secondary sources will stimulate more testing and quantitative reporting of CPC performance by both the vendors and the technical community at large. The result will be more firmly based CPC selection decisions. 24 ------- • CHAPTER 5 • SOURCES FOR CHEMICAL PROTECTIVE CLOTHING INFORMATION A. INDUSTRY By far the best source for information on CPC is the CPC vendors. The large, full-line vendors and the specialty products manufacturers gener- ally have tested their products against a wide range of chemicals. Furthermore, they have years of experience with their products, and typically have a very good understanding of the products’ capabilities and limitations. A listing of vendors is given in Volume I, Appendix D. A second source of information is the chemical manufacturers. These organizations provide clothing for their workers and often conduct their own analysis of protective clothing performance for their chemical products. B. GOVERNMENT Principal sources of CPC information within federal government agencies are: EPA - Office. of Occupational Health and Safety, Room 3503, Waterside Mall, 401 M Street, S.W., Washington, D.C. 20460. Telephone 202-382-3647 (David Weitzman). Federal Emergency Management Agency (FEMA) - United States Fire Administration, Office of Firefighter Health and Safety, 16825 South Seton Avenue, Emmitsburg, MD 21727. Telephone .301-447-1182 (Robert Mccarthy). OHSA - Technical Assistance, Room N3657, 200 Constitution Avenue, NW Washington, D.C. 20210. Telephone 202-523-7505 (Ching Bien). NIOSH - Division of Safety Research, Testing and Criteria Branch, ASI Section, 944 Chestnut Ridge Road, Morgantown, WV 26505. Tele- phone 304-291-4339 (Stephen Berardinelli). U.S. Coast Guard - Headquarters, Office of Research and Development, Commandant, C-DMT-3, 2100 Second Street, S.W. , Washington, D.C. 20593. Telephone 202-267-0853 (Lt. Jeffrey Stull). These agencies are involved in the study, development, and utilization of protective clothing. 25 ------- C. PROFESSIONAL ORGANIZATIONS In the United States, three professional organizations have committees directly foèused on protective clothing. ‘ASTM formed Committee F-23 in 1977 for the purpose of developing standard test methods for protective clothing. Subcommittees of F-23 are addressing the chemical resistance of clothing, the physical properties of clothing, clothing classification methods, and the performance of full-body protective ensembles. The committee is composed of industry, government, and general interest members. It meets twice a year and is a forum for discussing protective clothing test methods. In addition in 1984 and in 1987 Committee F-23 sponsored international symposia on all aspects of protective clothing. Proceedings of the symposia are published by ASTM as Standard Technical Publications. For further information, telephone AST 4 headquarters (215- 299-5579). The American Industrial Hygiene Association addresses CPC through its technical committee Personal Protective Devices (other than respirators). The committee meets once a year in coincidence with the American Indus- trial Hygiene Conference. This week-long conference typically includes one or two sessions devoted to protective clothing. At these sessions, technical papers are presented describing research, evaluationor use of protective clothing. Information on this and other Al l - iA activities may be obtained from AIHA headquarters (216-762-7924). The National Fire Protection Association (NFPA) formed a subcommittee on Hazardous Chemical Protective Clothing in 1986. This subcommittee was established under the NFPA Technical Committee on Protective Equipment for Firefighters. The subcommittee is engaged in writing performance oriented (manufacturing) standards on chemical protective suits for emergency response personnel. Its membership is composed of representatives from users, •manufacturers, testing laboratories, and government. It meets three times a year and plans to complete proposed standards for chemical pràtective suits by December 1987. For further information, contact Bruce Teele of the NFPA (617-770-3000). D. TECHNICAL LITERATURE In recent years, the principal sources of published teèhnical papers and reports on personal protective clothing have been the: • American Industrial -Hygiene Association Journal, a monthly publication. AIHA, 475 Wolf Ledges Park, Akron, OH 44311-1087. Telephone 216-762-7924. • National Technical Information Service (NTIS). -Essentially all federal government sponsored studies may be obtained through NTIS. NTIS, U.S. Department of Commerce, 5285 Port Royal Road, Springfield, VA 22161. Telephone 703-487-4650. 26 ------- A new journal, Applied Industrial Hygiene , has been started by the American Conference of Governmental Industrial Hygienist (ACGIH); 6500 Glenway Avenue, Bldg. D-7, Cincinnati, OH 45211. Telephone 513-661-7881. Also artictes on protective clothing are usually included in the proceed- ings of Hazardous Materials Management Conference (Tower Conference Management Company, Wheaton, IL 60187) andthe Hazardous Material Spills Conference (Government Industries, Inc., Rockville, MD 20850). A bibliography of publications related to chemical protective clothing follows. •27 ------- BIBLIOGRAPHY 28 ------- 1 Abernathy, R.N., R.B. Cohen, and J.J. Shirtz Measurements of Hypergolic Fuels and Oxidants Permeation Through Commercial Protective Materials--Part I: Inhibited Red Fuming Nitric Acid and Unsymmetrical Dimethylhydrazine Am. md. Hyg. Assoc. J. 44(7), pp.. 505-513 (1983) 2 Acme Mills Company Catalogue 1986 3 Aitken, A., and R.M. Barrer Transport and Solubility of Isomeric Paraffins in Rubber Trans. Faraday Soc. 51(385), pp. 116-130 (January 1955) 4 Algera, R. Development of a Hazardous Chemical Protective Ensemble: Phase I Interim Report This report available as: Stull, J., Early Development of a Hazardous Chemical Protective Ensemble, Final Report U.S. Coast Guard Contract DTCG23-8l-C-20003, AD A174 885 (October 1986) 5 Alliance Supply, Inc. Catalogue 1986 6 Allied Glove & Safecy Products Corp. Catalogue . 1986 7 American Scientific Products Catalogue 1984 8 Andover Industries, Inc. Catalog 1986 9 Angelica Uniform Group Catalogue 1986 10 Anon. Foot and .Leg Protection National Safety News, pp. 176-182 (March 1962) 29 ------- 11 Anon. A Summary of the Record of the NIOSH Open.Meeting on’ ChemicaiProtective Clothing Rockville, Maryland, (June 3,1981) 12 Anon. Balancing the Scales Between Protection and Economy National Safety News, pp. 36-39 (April 1982) 13 Anon. Protective Clothing Studies Reveal Wearer Preferences Agrichemical Age, (June .1981) 14 Anon. Protective Clothing for Chlorine, Edition 1 Chlorine Institute Pamphlet 65, The Chlorine Institute,’ Inc. New York, New York, (June 1978). 15 Anon. Best Safety Directory, Vol.. I A.M. Best Company, Oldwick, New Jersey 08858 16 Anon. Health and Safety Market Guide ‘82 Ayde Marketing Limited, 2 Castle Street, Aylesbury, Bucks HP2O 2ORF England 17 Anon. Industry’s Persistent Problem: Occupational Dermatitis National Safety News, pp. 33-37 (November 1982) 18 Anon. Dress Right for Safety: Foot Protection: Shoes National Safety News, pp. 66-67 (March 1983) 19 Anon. Dress Right for Safety: Hand Protection National Safety News, pp. 62-65 (March 1983) 20 Anon. Dress Right for Safety: General Body Protection National Safety News, pp. 54-57 (March 1983) 30 ------- 21 Anon. Dress Right for Safety: Disposable Apparel National Safety News, pp. 57-59 (March 1983) 22 Anon. Dress Right for Safety: Eye and Face Protection National Safety News, pp. 41-44 (March 1983) 23 Anon. A Shift.Toward Protective Gear Business Week, p. 56 (April13, 1981) 24 Anon. Safety Spinoffs From Space National Safety News, pp. 30-32 (February 1984) 25 Anon. Hazardous Waste Workers Are Seen Underprotected by Union, Congressmen, Chemical Marketing Reporter, pp. 5,40 (April 1, 1985) 26 Ansell Industrial Products Catalogue 1986 27 ARAMSCO Catalogue 1986 28 Arbill Inc. Catalogue 1986 29 Arn in Corp. Catalogue 1986 30 Arrowhead Products Catalogue 1986 31 Aydelotte, C.L. Consider Hazards Facing Worker in Making Proper Glove Selections, Occupational Health & Safety, pp. 54,56 31 ------- 32 Barker, R.L., and Coletta, G.C. Performance of Protective Clothing ASTM STP 900, ASTM PCN 04-900000-55, Philidelphia, PA (1986) 33 Barnes, J.D., G.M. Martin, and F.L. McCrackin Performance of Plastic Packaging for Hazardous Materials Transportation. IV NTIS Report No. DOT/MTB/OHMO-77/5, PB298047 (1979) 34 Barnhart, W.L., C.R. Tony, and L.A. Nicodemus Catalog of Available Protective Clothing Supplement to Final Report: ‘Protective Clothing - Assessment of Need’ NIOSH Publication PB-276344 (August 1974) 35 Barnhart, W.L., C.R. Toney, and L.A. Nicodemus Protective Clothing- -Assessment of Need, Vol. I Final Report prepared by Bendix Corporation, Launch Support Division under the United States Department of Health, Education, and Welfare - Public Health Service, Center for Disease Control, NIOSH-TR-75.Ol, PB24llO7 (August 1974) 36 Barrer, R.M., and R.R. Fergusson Diffusion of Benzene in Rubber and Polyethylene Trans. Faraday Soc., 54(427) pp. 989-1000 (1958) 37 Barry Manufacturing Co. Ltd. Catalogue 1986 38 Barton, A. M. Solubility Parameters Chemical Reviews, 75(6), pp. 731-749 (1975) 39 Barton, A.F.M. Handbook of Solubility Parameters and Other Cohesion Parameters CRC Press, Boca Raton, FL (1983) 40 Bel-Art Products Catalogue 1981 4lBerardinelli, S. Chemical Protective Clothing Standard Test Method Development Final Report No. 1: Penetration Test Method NIOSH Contract No. 200-84-2702 32 ------- 42 Berardinelli, S.P., R.L. Mickelsen, and M.M. Roder Chemical Protective Clothing:. A Comparison of Chemical Permeation Test Cells and Direct-Reading Instruments Ani. md. Hyg. Assoc. J. 44 (l 2 ),pp. 886-889 (1983) 43 Berardinelli, S.P., and R. Hall Site-Specific Whole Clove Chemical Permeation Am. md. Hyg. Assoc. J., 46, pp. .60-64, (February 1985) 44 Beret, S., and S.L. Hager Ethylene Solubility and Diffusionin Low Density Polyethylene and Ethylene.Polymers J. Appi. Poly. Sci., 24, pp. 1787-1796 (1979) 45 Best Manufacturing Company Catalogue 1986 46 Best, A.M., Company Best’s Safety Directory, 2 Volumes 24th Edition, 1984 47 Body-Guard Catalogue 1984 48 Boss Manufacturing Company Catalogue No. 20-4-81 1985 49 Bosserman, M.W How to Test Chemical-Resistance of Protective Clothing. National Safety News, pp. 51-53 (September 1979) 50 Brandrup, J. and E.H. Inmiergut Polymer Handbook John Wiley & Sons, New York (1966) 51 Broner Glove Company Catalogue 1983 52 Bush, D.C., L.E. Tersegno, J.E. Winter, and D.H. Schoch A Method for Testing Permeability of Protective.Clothing to Acids and Bases Industrial Hygiene Section Eastman Kodak Company Rochester, NY (June 1982) 33 ------- 53 Butt, L.T., J. Pacitti, and J.R. Scott Chemical Resistance Data Sheets, Vols. I and II Rubber and Plastics Research. Association (RAPRA), Shawbury, Shrewsbury, SY4 4NR England 54 Calingaert, C., and H. Shapiro Permeability of Protective Glove Materials to Tetraethyllead and Ethylene Bromide Industrial and Engineering Chemistry, 40(2), p. 332 (1948) 55 Calingaert, C., andH. ShapIro Permeability of Protective Glove Materials to Tetraethyllead and Ethylene Bromide IndustrIal and Engineering Chemistry, 40(2), pp. 332-335 (February 1948) 56 Cesco Safety Products Catalogue 1986 57 Charkate Catalogue 1986 58 Chemical Engineering New Wardrobe for CPI Workers pp. 14-15 (August 19, 1985) 59 Chemical Fabrics Corporation Catalogue 1986 60 Cheron,J. Resistance desCants de Protection aux Solvents Industriels - Resultats Obtenus Avec L’Acetone Sur Tine Centaine de Cants du Commerce Travail et Securite, No. 527, Oct. 1975, Institut National de Recherche et de Securite, 75680, Paris , Cedex 14 61 Cheron, J. Resistance des Gants de Protection Aux Solvants Industriels - Resultats Obtenus Avec le Trichiorethane Sur Une Centaine de Cants du Commerce Travail etSecurite, No. 502, Oct. 1973, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 34 ------- 62 Cheron, J. Resistance des Gants de Protection Aux Solvants Industriels - Resultats Obtenus Avec L’AcetateD’Ethyle Sur Une Centaine de Gants du Commerce Travail et Securite, No. 547, Sept. 1976, Institut National de Recherche et de Securite, 75680., Paris, Cedex 14 63 Cheron, J. Resistance des Cants de Protection Aux Solvants Industriels - Resultats Obtenus Avec L’Ethanol Sur Une Centaine de Gants du Commerce Travail et Securite, No. 550, Nov. 1976, Institut National de Recherche et de Securite, 75680, Paris, Cédex 14 64 Cheron, J. Resistance des Gants de Protection Aux Solvants Industriels - Resultats Obtenus Avec le Toluene Sur Une Centaine de Gants du Commerce Travail et Securite, No. 503, Jan. 1975, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 65 Cheron, J. Resistance des Gants ‘de Protection Aux Solvants Industriels - Resultats Obtenus Avec le Trichiorethylene Sur Une Centaine de Gants du Commerce Travail et Securite, No. 491, Oct. 1972, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 66 Cheron, J. Resistance des Gants de Protection Aux Solvants Industriels .- Resultats Obtenus Avec le Perchloréthylene Sur UneCentaine de Gants du Commerce Travail et Securite, No. 498, June 1973, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 67 Cheron, J. Resistance des Gants de Protection Aux Solvants Industriels - Resultats Obtenus Avec le Cyclohexane Sur Une Cent aine de Cants du Commerce Travail et Securite, No. 521, Jan. 1975, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 68 Cheron, J. ‘ Resistance des Gants de Protection Aux Solvants Industriels - Resultats Obtenus Avec lé White-Spirit Sur Une Centaine de Gants du Commerce Travail et Securite, No. 506, June 1974, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 35 ------- 69 Cheron, J., J.-P. Guenier, B. Moncelon and Lima Resistance des Gants de Protection Aux Solvants Industriels - Tableaux Recapitulatifs Travail et Securite, No.573, Dec. 1976, Institut National de Recherche et de Securite, 75680, Paris, Cedex 14 70 Christensen, U.L. Handsker - sikre/usiker (in Danish) English summary available from Institute of Work Environment, Denmark Institute of Technology, DK-2800 Lyngby (April 1983) 71 Clean Room Products, Inc. Catalogue 1986 72 Cofish International, Inc. Catalogue 1986 73 Coletta, G.C. Chemical Protective Clothing: Technology Will Shape the Future, Occupational Health & Safety, pp. 50-54 (September 1985) 74 Coletta, G.C. Chemical Protective Clothing: Determining Good Performance Occupational Health & Safety, pp. 20-22 (April 1985) 75 Coletta, C.C. Chemical Protective Clothing: Testing Strategy and Test Methods, Occupational Health & Safety, pp. 49-52 (May 1985) 76 Coletta, G.C. Chemical Protective Clothing: Laboratory vs. Field Performance, Occupational Health & Safety, pp. 85-87 (June 1985) 77 Coletta, G.C. Chemical Protective Clothing: The Influence of Federal Agencies, Occupational Health & Safety, pp. 27-29 (July 1985) 78 Coletta, G.C., A.D. Schwope, I. Arons, J. King, and A. Sivak Development of Performance Criteria for Protective Clothing Used Against Carcinogenic Liquids Arthur D. Little, Inc., Report to NIOSH under contract 210-76-0130 (October 1978) 36 ------- 79 Colonial Clove & Garment Inc. Catalogue 1986 80 Comasec, Inc. Catalogue 1986 81 Costello, R.J., and M.V. King Protecting Workers Who Clean Up Hazardous Waste Sites Am. md. Hyg. Assoc. J., 43, p. 12 (January 1982) 82 Coyne Safety Equipment, Inc. Catalogue 1986 83 Crank, J. Mathematics of Diffusion Second Edition, Claredon Press (1975) 84 Crank, J., ‘and C. Park Diffusion In Polymers Academic Press, N.Y. (1968) 85 Crowe, W.H., andA.M. Marysiuk HOw to Work Safely With HF Alkylation ‘Hydrocarbon Proc’., 44(5), p. 192 (1965) 86 Cullinane, J. Evaluation of the Permeation Resistance of Polymer Gloves to an Organophosphorus Pesticide and Pesticide Carrier Solvents IT Corporation, Report to EPA under contract 68-03-3069,. (May 1985) 87 Daffin Disposables, Inc. Catalogue 1986 88 Davis, S.L., C.E. Feigley, and C.A. Dwiggins Comparison of Two Methods Used to Measure Permeation of Glove Materials by a Complex Organic Mixture Performance of Protective Clothing, ASTM STP 900, R.L. Barker and G.C. Coletta, Eds., American Society for Testing and Materials, Philadelphia, pp. 7-21 (1986) 37 ------- 89 Dayton Flexible Products, Inc. Catalogue 1984 90 Defense Apparel, Inc. Catalogue 1986 91 Denney, D. ASTM Eyes Plans, Seeks Input for Protective Clothing Data File, Occupational Health & Safety, pp. 57-61 (July/August 1984) 92 Dickson, C.C. Chemical Protective Clothing Best’s Safety Directory 1984 A.M. Best Co., Oldwick, NJ 08858, pp. 392-394 93 Dillon, I.G. Permeation of Condensable Gases and Organic Liquids through Polymeric Materials National Aeronautics and Space Administration Contract No. NAC-l0-0001 Final Report 94 Dillon, I.C., and E. Obasuyi Permeation of Hexane Through Butyl Nomex Am. md. Hyg. Assoc. J., 46(5), pp. 233-235 (May 1985) 95 Dionne, E.D Specialized Protective Apparel - An Item to Fit Every Need National Safety News.; p. 51 (May 1982) 96 Dionne, E.D. A Clove Affair National Safety News, (September 1982) 97 Direct Safety Company, Inc. Catalogue 1986 98 Disposables Inc. Catalogue 19 86 38 ------- 99 Dorsey Safety Products Co. Catalog 1986 100 Dow Chemical Company Selection of Cloves for Use With Chlorinated Solvents Chlorinated Solvents InformatIon Midland, Michigan 48640 101 Duffy,R.M., A.R.Beer, and J.C. Sawicki U.S.Research in Depth on Protective Clothing Fire International, pp. 41-43 (August/September 1985) 102 Dunham, T.D., W.J. Astleford, R.L. Bessey, and J.J. Kulesz Recommended Standard for Occupational and Educational. Eye and Face Protection Final Report NIOSH Contract HSM-99-73-l7, SwRI Project 02-3703 103 E.D. Rullard Company Catalogue • 1986 104 E.I. du Pont de Nemours & Company Spunbonded Product Division Guide E-643l2 1986 105 E.I. du Pont de Nemours & Company Industrial and Speciality Polymers Catalogue E-26276 106 Eastco Industrial Safety Corp. Catalogue 1985 107 Edmont Division of Becton,. Dickinson Company Catalogue 1986 108 Elliott Glove Company.,. Inc. Catalogue 1986 109 Ellis, A.C. Hazardous Waste Site Clean-Up A ‘Hot’ Problem National Safety News, pp. 38-41 (July 1984.) 39 ------- 110 Encon Manufacturing Company Catalogue 1986 ill Engle, R.L., and V.A. Nusbatun Selecting Protective Cloves. The Importance of Chemical Permeation Testing Professional Safety, pp. 32-35 (September 1984) 112 Erista, Inc. Catalogue 113 Exxon Chemical Company Polymers Group Elastomers - Design Materials Catalogue SYN-75-1751, 1975 114 Fairway Products Catalogue 1984 115 Falcon Industries, Inc. Catalogue 1981 116 Feigley, C.E. Personal Communication Dept. of Envir. Health Sciences University of South Carolina Columbia, S.C. 29208 (October 1982) 117 Fels, M., and R.Y.M. Huang Diffusion Coefficients of Liquids in Polymer Membranes by a Desorption Method J. Appi. Poly. Sci., 14, pp. 523-536 (1970) 118 Ferguson,. J.S., and W.F Martin An Overview of Occupational Safet; and Health Guidelines for Superfund Sites, Am. md. Hyg. Assoc. J., 46(4), pp. 175-180 (1985) 119 Figard, William H. Permeation: An Important Factor in Hand Protection Selection Occupational Health and Safety (December 1982) 40 ------- 120 Fisher Scientific Company Catalogue 1981 121 Flynn, J.H. A Collection of Kinetic Data for the Diffusion of Organic Compounds in Polyolefins Polymer, 23, pp. 1325-1344 (August 1982) 122 Forsberg, K. Development of Safety Gloves. Gloves For Printers ERGOLAB Report S 81:10 Stockholm/Coteborg, Sweden (November 1981) 123 Forsberg, K., and K.G. Olsson Faststallande av riktlinjer for val av kemikal 1 e skyddshandskar ASF-kontrakt 83-0750 124 Forsberg,. K., and S. Faniadis The Permeation of Multi-Component Liquids Through New and Pre-Exposed Glove Materials Am. md. Hyg. Assoc. J., 47(3), pp. 189493 (March 1986) 125.Frederick, E.B., and M.C.Henry A Study of Seam Leakage in Coated Fabrics J. Coated Fibrous Materials, 1, p. 18 (1971) 126 Friel, J.V.,M.J. McGoff, and S.J. Rodgers Material Development Study for a Hazardous Chemical Protective Clothing Outfit MSA Research Corp. for United States Coast Guard Report No. CG-D-58-80 (August 1980) 127 Frommelt Industries, Inc. Catalogue 1986 - 128 Fyrepel Products, Inc. Catalogue 1986 129 Galic, George J. Polycarbonate Lenses- -New Technology in Eye Protection National Safety News July, 1981 41 ------- 130 Gallagher, R. Beat Corrosion With Rubber Hose Chem. Engr., p. 105 (September 8, 1980) 131 Garland, C.E. New Developments in Materials and Chemical Compatibilities Proceedings of The Fourth Annual Hazardous Materials Management Conference, Atlantic City, NJ (June 2-4, 1986) 132 Garland, C.E., L.E. Goldstein, and C. Gary Testing Fully Encapsulated Chemical Suits in a Simulated Work Environment Performance of Protective Clothing, ASTM STP 900, R.L. Barker and G.C. Coletta, Eds., American Society for Testing and Materials, Philadelphia, pp. 276-285 (1986) 133 General Scientific Safety Equipment Company Catalogue 1986 134 Clover Latex, Inc. Catalogue 1986 135 Gáldberg, H. M., and S. Herszenson Cutting Oil Dermatitis: Sharpening Worker Defenses Occupational Health and Safety, p. 30 (May 1982) 136 Goodall Rubber Company Catalogue 1986 137 Goodyear Rubber Products Corp. Catalogue 1985 138 Cough, T.A., K.S. Webb, and M.F. McPhail Diffusion of Nitrosamines through Protective Gloves Enviromental Aspects of N-Nitroso Compounds, (E.A. Walker M. Castegnaro, L. Griciute, and R.E. Lyle, eds.) pp. 531-534, Lyon International Agency for Research on Cancer (1978) 139 Granet, Inc. Catalogue 1982 42 ------- 140 Green, J., N.B. Levine, and R.C. Keller Elastomers for’ Liquid Rocket Fuel’ ‘and Oxidizer Application I&EC Product Research and Development, 2, p. 126 (1963) 141 Greene Rubber Company, Inc. Catalogue 1984 142 Haas, T.J., R.B. Gaines,, and K.J. Patterson Permeation Testing of Certain Personal Protective Clothing Materials by Hazardous Liquid Chemicals 1984 Hazardous Material’Spills Conference Proceedings, Nashville, TN, April 9-12 (1984) 143 Halprin Supply Co. Catalogue 1981 144 Hanuner, W.M., and K.R. Nicholson Survey of Personnel Protective Clothing and Respiratory’ Apparata for use by Coast Guard Personnel in Response to Discharges of Hazardous Chemicals Pollution Prevention Projects, Branch Office of Research and Development, U.S. Coa t Guard, Washington, D.C. 145 Hayes, M.J., and C.S. Park The Diffusion of Benzene in Rubber - Part I Trans. Faraday’Soc., 51(392), p. 1134 (1955) 146’Heck, W.B., and R.L. Johnson Aluminum Alkyls Safe Handling md. and Engr. Chem., 54(12), p. 35 (1962) 147 Henriksen, H. R. Selection of Materials for Protective Gloves. Polymer Membranes to Protect Against Contact With Epoxy Products Danish Directorate of Labor Inspection Services, Cophenhagen (1982) 148 Henry, N.W. III How Protective is Protective Clothing? Performance of Protective Clothing. ASTM STP 900, R.L. Barker and G.C. Coletta, Eds., American Society for Testing and Materials, Philadelphia, pp. 51-58 (1986) 149 Henry, N.W., and C.N. Schlatter The Development of a Standard Method for Evaluating Chemical Protective Clothing to Permeation by Liquids Am. md. Hyg. Assoc. J., 42, p. 202 (1981) 43 ------- 150 Henry, N.W., and J.F. Matheson Dupont Monograph: Gloves-Their Selection and Testing Haskell Laboratory for Toxicology and Industrial Medicine Dupont Company, Wilmington, DE. (August 12, 1980) 151 Hodgman, Inc. Catalogue 1986 152 Hogstedt, C., and R. Stahl Skin Absorption and Protective Gloves in Dynamite Work Am. md. Hyg. Assoc. J., 41, p. 367 (1980) 153 Holcomb Safety Garment Company • Catalogue 1984 154 Holland Safety Supply Company • Catalogue 1986 155 Hopfenburg, H.B. Permeability of Plastic Film and Coatings Plenum Press, N.Y. (1974) 156 Hub Safety Equipment, Inc. Catalogue 1985 15.7 Hy-Test Safety Shoes, Inc. Catalogue 1986 158 ILC Dover Division of ILC Industries, Inc. Data Sheet 1986 159 IPES Company, Inc. Catalogue 1986 160 Inco Safety Products Company Catalogue 1981 44 ------- 161 Industrial Products Company, Inc. Catalogue 1984 162 Industrial Safety and Security Company Catalogue 1986 163 Interex Corp. Catalogue 1986 164 Intermarket Latex, Inc. Catalogue 1985 165 International Playtex, Inc., Industrial Clove Division Catalogue • 1986. 166 Iron Age Protective Company • Catalogue 1986 167 Jaxco, Inc. C at a lo güe 1986 168 Johnson,K.E., and M.D. Lowish Protection Should Fit Worker, Job Occupational Health and Safety (August 1983) 169 Jomac Products, Inc. Catalogue 1985 170 Jones Safety Supply, Inc. Catalogue. 1986 171 Jordan David Safety Products Catalogue 1981 45 ------- 172 Kappler Disposables, Inc Catalogue 1984 173 Kashi, K.P., M. Muthu, andS.K.Majthnder Rapid Evaluation of Phosphine Permeability through Various Flexible Films and Coated Fabrics Pestic. Sci. , 8, PP. 492-496 (1977) 174 Keller Clove Manufacturing Company Catalogue 1982 175 Keystone Protection Corp. Catalogue 1986 176 Kimberly-Clark Corp. Catalogue 1985 177 Kodak Functional Croup Index of KODAK Laboratory Chemicals Kodak Publication No. JJ-lF (January 1981) 178 Kokes, R.J., and F.A. Long Diffusion of Organic Vapors into Polyvinyl Acetate J. Amer. Chem. Soc., 75, p. 6142 (1953) 179 LRC Safety Productsdompany Catalogue 1984 180 La Crosse Footwear, Inc. Catalogue 1986 181 Latex Clove Company, Inc. Catalogue 1986 182 Lehigh Safety Shoe Company Catalogue 1986 46 ------- 183 Leonard Safety Equipment, Inc. Catalogue 1986 184 Levine, S.F., andMartin, ‘W.F. Protecting Personnel at Hazardous Waste Sites Butterworth Publishers, Stoneham,’ MA, 1985 185 Lilani, H.N. Non-Asbestos Fabrics Perform Against Heat and Metal Splashes, Occupational Health & Safety, pp. 58-61 (January 1986) 186 Linnarson, A.’ Penetration of Solvents Through Plastic Material Lagersrapport, Forsvarets Forskningsanstalt, Stockholm pp. 17 (1977) 187 Linnarson, A., and K. Halvarson Study of Polymer Material Permeability for Organic Compounds FOA Report C-204l4-H2, Progress Report, Stockholm, 1981 188 Lion Uniform, Inc. Catalogue 1985 189 ‘Lloyd, G.A. Summarized Results of Permeation Tests on Protective Clothing Materials ,Ministry of Agriculture Fisheries and ‘Food, Operator Protection Research Group, Information Sheet No. 19, (June 1986) 190 Lldyd,.C.A. Efficiency of Protective Clothing for Pesticide Spraying Performance of Protective Clothing,’ ASTM STP’900, R.L. Barker and G.C. Coletta, Eds., American Society for Testing and Materials, Philadelphia, pp. 121-135 (1986) 191 Lynch, A.L. ‘ ‘ Protective Clothing in Handbook of Laboratory Safety 2nd Edition, N.y. Steeve editor CRC Press, Boca Raton, FL (1971) 192 Lynch, P. Matching Protective Clothing to Job Hazards Occupational Health and Safety, p. 30 (January 1980) 47 ------- 193 MacDonald, R.W., and R.Y.M. Huang - Permeation of Gases Through Modified Polymer Films V. Permeation and Diffusion of Helium, Nitrogen, Methane Ethane, and Propane through gamma-Ray Crosslinked Polyethylene J. Appl. Poly. Sci., 26, pp. 2239-2263 (1981) 194 Magid Glove and Safety Manufacturing Company Catalogue 1985 195 Major Safety Service, Inc. Catalogue 1984 196 Mar-Mac• Manufacturing Company, Inc. Catalogue 1986 .197 Marathon Rubber Catalogue 1986 198 Martone, J.A., and Bergen, G.A. A Rocket Propellant Handler’s Suit for Protection from Chlorine Trifluoride and Elemental Fluorine Technical Report AFRPL-TR-71-44 (August 197,1) NTIS AD731556 199 Masterman’s Catalogue 1986 200 ’Mathias, C.G.T., Managing Hand Dermatitis in the, Workplace Occupational Health and Safety, p. 46 (May 1982) 201 McFee, D.R. How Well Do Gloves Protect Hands Against Solvents A.S.S.E. Journal, 9, p. 11 (May 1964) 202 McGuffey, J.R., R. Paluzelle, and W.E. Muldrew Handling Gaseous Fluorine in Industry md. and Engr. Chem., 54(5), p. 46 (1962) 48 ------- 203 McNaughton, K.J. The ABCs of Occupational Skin Disease - Part II Chem. Engr., p. 149 (April 19, 1982) 204 Meade, J., W. Ellis, and J. Ludington Evaluation of the Resistance of a. Chlorinated Polyethylene Protective Garment Material to Permeation and Degradation by Liquid Chemicals ‘U.S. Environmental Protection Agency Contract No. 68-03-3113 (1985) 205 Meares, P. Transient Permeation of Organic Vapors through Polymer Membranes J. of Applied Polymer Science, 9, p. 917 (1965) 206 Melco, Inc. Catalogue 1986 207 Memphis Glove Company Catalogue 1986 208 Middleton, H. W. Glove Corrosive Liquid Immersion and P rmeability Study Report on U. S. Energy Research and Development Administration contract EY-76-C-04-0656 (August 1977) 209 Mihal, C.P., Jr. Effect of Heat Stress of Physiological Factors for Industrial Workers Performing Routine Work and Wearing Impermeable Vapor-Barrier Clothing Am. md. Hyg. Assoc. J., (February 1981) 210 Mikatavage, M., S.S. Que Hee, and H.E. Ayer Permeation of Chlorinated Aromatic Compounds Through Viton ‘and Nitrile Glove Materials Am. md. Hyg. Assoc. J., 45(9), pp. 617-621 (1984) Zll Mikkelson, T.J. , S. Watanabe, J.H. Rytting, and T. Higuchi Effect of Self-Association of Phenol on Its Transport, Across Polyethylene Film , J. Pharm. Sci., 69, p. 133 (1980) 212 Miller Products Company, Inc. Catalogue 1986 49 ------- 213 Mine Safety Appliances Company Data Sheets 13-00-07, 13-00-17, and 13-00-18 1986 214 Monte Glove Company Catalogue 1981 215 Morrow, R.W., and J.H. Hamilton Moca Permeation of Protective Clothing Prepared for Department of Energy Under U.S. Government Contract W-7405 eng. 26 • 216 Moursiden, J.T., and 0. Faber Penetration of Protective Clothing By Allergens and Irritants Trans. St. John’s Hosp. Derniatol. Soc., 59, p. 230 (1973) 217 Mueller, W.J. Permeability of Rubber to Organic Liquids - Rubber Age, p. 982 (September 1957) 218 National Draeger, Inc. Catalogue 1986 219 National Research Council Prudent Practices for Handling Hazardous Chemicals in Laboratories National Academy Press, Washington, DC (1981) 220 National Safety Wear, Inc. Catalogue 1984 221 National Tech. Info. Service Protective clothing: Industrial Environments. Protective Clothing for Industrial Atmospheres Including Protection from Explosive Materials and Fuels U.S. Department of Commerce, NTIS, PB83-804922 222 Nelson, G.O., B. Lum, C. Carison, C. Wong, and J. Johnson Glove Permeation by Organic Solvents • Am. md. Hyg. Assoc. J., 42(3), p. 217 (1981) 50 ------- 223 Nelson, G.O., G.J. Carison, and A.L. Buerer Clove Permeation by Shale Oil and Coal Tar Extract Lawrence Livermore Laboratory, UCRL 52893 (1980) 224 Nesse Industries, Inc. Catalogue 1984 225 Newns, A.C., and G.S. Park The Diffusion Coefficient of Benzene in a Variety of Elastomeric Polymers J. Polymer Sci. Part C, 22(2), pp. 927-937(1969) 226 Niles, H.M. Selecting Gloves for Handling Toxic Liquids Involves Several Factors, Occupational Health & Safety, pp. 34-36 (December 1985) 227 North Hand Protection, Div. of Siebe North, Inc. Catalogue 1986 228 O’Brien, J. Proper’Sole Selection Key to Safety Footwear Comfort, Protection, Occupational Health & Safety, pp. 52-53 (February 1986) 229 O.K.I. Supply Company Catalogue 1981 230 Oak Medical Supply Company Catalogue 1981 231 Oak Technical, Inc. Catalogue 1986 232 PPG Industries, Inc. Catalogue A-691-45C, 1OM, 179, 1986 233 Paneigraphic Corporation Catalogue 1986 51 ------- 234 Pendergast Safety Equipment Company Catalogue 1984 235 Perkins, J.L., and A.D. Tippit Use of Three-Dimensional Solubility Parameter to Predict Glove Permeation Am. md. Hyg. Assoc. J., 46, pp. 455-459 (August 1985) 236 Pioneer Industrial Products, Division of Brunswick Corp. Catalogue M-l04-l 1986 237 Plastex Protective Products, Inc. Catalogue 1986 238 Plastimayd Corp. Catalogue 1986 239 Podkowka, ‘J., and Puchalik, A. Comparative Evaluation of Diffusion Coefficients for Gases and Vapors of Organic Substances through Polyethylene Membranes Determined by Absorption and Desorption Upstream Time Lag Method J. Appl. Poly. Sd., 27, pp. 1471-1478 (1982) 240 Polakoff, P.L. Chemical Mixture Hazard Evaluation Differs from that of Single Substances, Occupational Health & Safety, pp. 55-56 (September 1985) 241 Prager, S., and F.A. Long Diffusion of Hydrocarbons in Polyisobutylene J. Amer. Chem. Soc., 73, p. 4072 (1951) 242 Protech Safety Equipment, Inc. Catalogue 1986 243 Protexall Company Catalogue 1986 244 Pulmosan Safety Equipment Corp. Catalogue 1984 52 ------- 245 Rainfair, Inc. Catalogue 1986 246 Ranger Catalogue 1985 247Record Industries Company Catalogue 1986 248 Renco Corp. Catalogue 1984 249 Richards, R.W. The Permeability of Polymers to Cases, Vapors and Liquids Tech. Report No. 135, Ministry of Defense Explosives Research and Development Establishment (March 1973) 250 Riley, M.W., D.J. Cochran, and C.A. Schanbacher Force Capability Differences Due to Cloves Ergonomics, 28(2) pp. 441-447 (1985) 251 Robar Protective Products Catalogue 1981 252 Rockford Medical & Safety Company Catalogue 1986 253 Rogers, C.E., V. Stannett, and M. Szwarc The Sorption, Diffusion, and Permeation of Organic Vapors in Polyethylene J. Poly. Sci., 45, pp. 61-82 (1960) 254 Ronco Textile Products, Inc. Catalogue 1986 255 Ronk, R., M.K. White, and H. Linn Personal Protective Equipment for Hazardous Materials Incidents: A Selection Guide, NIOSH, DHHS (NIOSH) Publication No. 84-114, (October 1984) 53 ------- 256 SGL }lomalite Division of SGL Industries, Inc. Catalogue 0776-5M 257 Safeco, Inc. Catalogue 1986 258 Safety Engineering & Supply Company Catalogue 1986 259 Safety First, Industries Catalogue 1986 260 Sager Corporation, Racine Glove Division Catalogue 1986 261 Salame, M., and S. Steingiser Barrier Polymers Presented at the Am. Chem. Soc. Symposium inNàw York City (May 1976) 262 Salame, S. The Prediction of Liquid Permeation in Polyethylene and Related Polymers SPE Transactions (October 1961) 263 Salisbury, W.H. & Company Catalogue 1986 264 Sansone, E.B. , and L.A ‘Jonas Resistance of Protective Clothing Materials to Permeation by Solvent “Splash” Environmental Res., 26, pp. 340-346 (1981) 265 Sansone, E.B., and L.A. Jonas The Effect of Exposure to Daylight and Dark Storage on Protective Clothing Material Permeability Am. md. Hyg. Assoc. J., 42(11), pp. 841-843 (1981) 266 Sansone, E.B., and Y.B. Tewari The Permeability of Laboratory Gloves to Selected Solvents Am. md. Hyg. Assoc. J., 39(2), p. 169 (1978) 54 ------- 267 Sansone, E.B., and Y.B. Tewari The Permeability of Laboratory Cloves to Selected Nitrosamines Environmental Aspects of N-Nitroso Compounds (E A. Walker M. Castegnaro, L. Criciute and R.E. Lyle, eds.), Lyon International Agency for Research on Cancer pp. 517-529 (1978) 268 S ansone, E.B., and Y.B. Tewari Differences in the ‘Extent of Solvent Penetration Through Natural Rubber and Nitrile Cloves From Various ‘Manufacturers Am. md. Hyg. Assoc. J., 41, pp 527-528 (July 1980) 269 Sansone, E.B., and Y.B. Tewari The Permeability of Protective Clothing Materials to Benzene Vapor Am. md. Hyg. Assoc. J., 41(3), pp. 170-174 (1980) 270 Sañsone, E.B., and Y.B. Tewari Penetration of Protective Clothing ‘Materials by 1,2-Dibromo- 3-Chloropropane, Ethylene Dibromide, and Acrylonitrile Am. md. Hyg. Assoc. J., 39, pp. 921-922 (November 1978) 271 Sawyer-Tower Catalogue 1986 272 Schlatter, C.N. Permeation Resi’stance of Cloves After Repeated Cleaning and Exposure to Liquid Chemicals Edmont Division, Becton, Dickinson ‘and Company 273 Schlatter, C.N., and D.J. Miller Influence of Film Thickness on the Permeation Resistance Properties of Unsupported Glove Films Performance of Protective Clothing, ASTM STP 900, R.L. Barker and G.C. Coletta, Eds., American Society for Te’sting and Materials, Philadelphia, pp. 75-81 (1986) 274 Schoch, D.H., L.K. Tersegno, J.E. Winter, D.C. Bush, and R.L. James Testing of “Impervious” Gloves for Permeation by Organic’ Solvents, American Industrial Hygiene Conference, Cincinnati, OH (June 6-11, 1982) ‘ 275 Schwope, A.D. , ‘ The Effectiveness of TYVEK Composites as Barriers To AROCLOR 1254 (PCB), Trichlorobenzene, and Mineral Spirts Report to Textile Fibers Dept., The Dupont Company from Arthur D. Little (1979), 55 ------- 276 Schwope, A.D., M.A. Randel, and M.C. Broome Dimethyl Sulfoxide Permeation through Clove Materials Am. m d. Hyg. Assoc. J., 42(10), pp. 722-725 (1981) 277 Shelby-Wolverine Clove Company Catalogue 1986 278 Silkowski, J.B., S.W. Horstman, and M.S. Morgan Permeation Through Five Commercially Available Clove Materials by Two Penachiorophenol Formulations Am. md. Hyg. Assoc. J., 45, pp. 501-504 (August 1984) 279 Singer Safety Company Catalogue 1985 280 Smith, I.D., and J. Roepke Personnel Protection Equipment for Use With Laser Chemicals NASA and LEMSCO, White Sands Test Facility, AD-P004-490 (May 1984) 281 Smolander, J., V. Louhevaara, and Korhonen, 0. Physiological Strain in Work with Cas Protective Clothing at Low Ambient Temperature, Am. md. Hyg. Assoc. J., 46, pp. 720-723 (December 1985) 282 Snyder, F.J., C.F. Macy, L.A. Spane, and V.D. lacono Protection Capability of U.S. Army’s POTMC Against Hazards Posed by 900 Hazardous Chemicals U.S. Army Natick R&D Command, 1976 283 Snyder, L. Solutions to Solution Problems- -l Chemtech (December 1979) 284 Snyder, L. Solutions to Solution Problems- -2 Chemtech (March 1980) 285 Soles, E., J.M. Smith, and W.R. Parrish Cas Transport through Polethylene Membranes AIChE Journal, 28(3), pp. 474-479 (1982) 56 ------- 286 Spain, W.H., and J.L. Burson Selective Protective Clothing with Six C’s Occupational Health and Safety, pp. 17-23 (September 1983) 287 Spence, M. W. Chemical Permeation through Protective Clothing Material: An Evaluation of Several Critical Variables Paper Presented at the American Industrial Hygiene Conference, Portland, OR (May 1981) 288 Spence, M.W. Glove Materials for Chlorinated Solvents: Permeation Resistance Comparison for Four Solvents American Industrial Hygiene Conference, Detroit, MI (May 21-25, 1984) 289 Sperling, L., B. Jonsson, I. Holmer, and T. Lewin Test Program for Work Gloves Department of Occupational Safety, Division for Occupational Medicine, Labor Physiology Unit in Umea, Sweden, Research Report 1980:18 (1980) (translated from Swedish) 290 Stampfer, J.F., M.J. McLeod, A.M. Martinez, M.R. Betts, and S.P. Berardinelli Permeation of Polychiorinated Biphenyls and Solutions of These Substances Through Selected Protective Clothing Materials Am. md. Hyg. Assoc. J., 45(9), pp. 634-641 (1984) 291 Stampfer, J.F., M.J. McLeod, M.R. Betts, A.M. Martinez, and S.P. Berardinelli The Permeation of Eleven Protective Garment Materials by Four Organic Solvents Am. md. Hyg. Assoc. J., 45, pp. 642-654 (1984) 292 Stampfer, J.F., M.J. McLeod, M.R. Betts, A.M. Martinez, and S.P. Berardinelli Chemical Permeation - A Summary Report of Recent NIOSH- Directed Studies at the Los Alamos National Laboratory Am. md. Hyg. Assoc. J., 45, pp. B-b to B-l2 (January 1984) 293 Stampfer, J.F., and R.J. Beckman A Screening Test for Selecting Chemical Protective Clothing Los Alamos National Laboratory, Los Alamos, NM 294 Standard Glove & Safety Equipment Corp. Catalogue 1986 57 ------- 295 Standard Safety Equipment Company Catalogue 1986 296 Stannett, V., and H. Yasuda Liquid Versus Vapor Permeation Through Polymer Films J. Poly. Sci. Part B, Poly. Letters, 1(6), pp. 289-293 (1963) 297 Stauffer Manufacturing Company Catalogue 1986 298 Steel Grip Safety Apparel Company, Inc. Catalogue 1986 299 Steele & Associates, Inc. Catalogue 1986 300 Stokoe, A.L., and K.J. Ledbury Permeability of Polymers to Organic Fluids Tech. Report No. 18, Ministry of Technology Explosives Research and Development Establishment Waltham Abby, Essex, England (February 1970) 301 Streng, D.R., W.F. Martin, L.P. Wallace, and G. Kleiner Hazardous Waste Sites and Hazardous Substance Emergencies Worker Bulletin DHHS (NIOSH) Publication No. 83-100 302 Stull, J.O., V.L. Man, V.A. Bastecki, and A.P. Bentz A Comprehensive Materials Evaluation Program’ to Support the - Development and Selection of Chemical Protective Clothing 1986 Hazardous Material SpillsConference Proceedings, St. Louis, Missouri (May 5-8, 1986) 303 Stull, Jeffrey Personal Communication. ‘ U.S. Department of Transportation, Coast Guard (August 1986) 304 Superior Surgical Manufacturing Company, Inc. Catalogue 1986 58 ------- 305 Sweeting, 0.J. (editor) The Science and Technology of Polymer Films Volume II, Wiley-Interscience, New York (1970) 306 Texier, H. Glove Company, Inc. Catalogue 1985 307 3M Company Catalogue 1986 308 Tingley Rubber Corp. Catalogue 1985 309 Tracies Co., The Catalogue 1986 310 Trelleborg, A.B. Resistance Table Trelleborg A.B. (Sweden) 311 Trelleborg, Inc. Catalogue 1986 312 United States Plastic Corp. Catalogue 1986 313 United.States Safety Service Company Catalogue 1986 314 Vaccari, J.A. Guide to Selecting Elastomers Product Engineering, p. 36 (July 1978) 315 Van Amerongen, G.J. ‘Diffusion in Elastomers Rubber and Chem. Tech. Rubber Reviews for 1964, 37(5), pp. 1065-1152 (1964) 59 ------- :316 Varos, J. Consider Abrasion Risk, Chemicals When Choosing Gloves Occupational Health & Safety, pp. 60,62 (March 1986) 317 Vidaro Corp. Catalogue 1981 318 Vrentas, J.S., H.T. Liu, and J.L. Duda Effect of Solvent Size on Diffusion in Polymer-Solvent Systems J. Appl. Poly. Sci., 25, pp. 1793-1797 (1980) 319 Vrentas, J.S., and J.L. Duda Diffusion of Large Penetrant Molecules in Amorphous Polymers J. Poly. Sci., Phys. Ed., 17, pp. 1085-1096 (1979) 320 Waack, R., N.H. Alex, H.L. Frisch, V. Stannett, and M.Szwarc Permeability of Polymer Films to Gases and Vapors md. and Engr. Chem., 47(12), pp. 2524-2527 (1955) 321 Wakefield, M.E., and M.S. Hall Development of a Specification for an Improved Ensemble for Propellant Handlers Final Report on NASA Contract NAS1O-97l4, MCR-80-647 (December 1980) 322 Walker, E.A., M. Castegnaro, L. Garren, and B. Pigna elli Limitations to the Protective Effect of Rubber Gloves for Handling Nitrosamines Environmental Aspects of •N-Nitrosainines Compounds (E.A. Walker, M. Castegnaro, L. Griciute, and R.E. Lyle, eds.), Lyon International Agency for Research on Cancer, pp. 535-542 (1978) 323 Walters, D. Personal Communication. National Toxicology Program Glove Performance Study Performed by Radian Corporation, Austin, Texas (June 1986) 324 Weaver, L.A. Hazardous Site Water Restrictions Pose Problem for Exposed Workers, Occupational Health & Safety, pp. 54-58 (May 1985) 325 Weeks, R.W., Jr., and B.J. Dean Permeation of Methanolic Aromatic Amine Solutions Through Commercially Available Glove Materials Am. md. Hyg. Assoc. J., 38, pp. 721-725 (1977) 60 ------- 326 Weeks, R.W., Jr., and M.J. McLeod Permeation of Protective Garment Material by Liquid Halogenated Ethanes and a Polychlorinated Biphenyl U.S. Dept. of Health & Human Services, NIOSH Publication No. 81-110 (January 1981) 327 Weeks, R.W., Jr., and M.J. McLeod Permeation of Protective Garment Material By Liquid Benzene and by Tritiated Water Am. md. ’ Hyg. Assoc. J., 43, pp. 201-211 (1982) 328 Weitzman, B., and L.C. Jonas Industrial Hygiene Program for Hazardous Waste Site Investigations Am. md. Hyg. Assoc. J.., 42, pp., 653-655 (1981) 329 Wells, Dr. J.W., Equipment Innovations Cut Risks for Divers in Polluted Waters, Sea Technology, p. 22 - 23 (December 1984) 330 Wheeler Protective Apparel, Inc. Catalogue G12, 1986 331 Wheeler, ‘C.P., and Goldberg, H.M. Hazard Education Must Overcome Generalities Occupational Health and Safety, pp. 31-34 (September 1983) 332 Wilcher, F.E. ISEA Forms Unit to Certify Personal Protective Equipment National Safety News, p. 36 (September 1981) 333 Williams, J.R. Permeation of Glove Materials by Physiologically Harmful Chemicals Am. md. Hyg. Assoc. J., 40(10), pp. 877-882 (1979) 334 Williams, J.R. Chemical Permeation of Protective Clothing Am. md. Hyg. Assoc. J., 41, pp. 884-887 (1980) 335 Williams, J.R. Evaluation of ‘Intact Gloves and Boots for Chemical Permeation, Am. md. Hyg. Assoc. J., 42, pp. 468-471 (1981) 61 ------- 336 Willson Safety Products. Catalogue 1985 337 Wittenberg, L.J. Experimental Verification of Tritium Control by Clove-Box Containment Nuclear Technology, 38., PP. 434-440 (May 1978) 338 Wolfe, P.R., and L.A. Rich FEMA’s Strategy for Emergency Response Chemical Week, p. 15 (July 3, 1985) 339 Worklon Catalogue 1981 ‘340 Zippler, D.B. Personal Protective Clothing . 1984 Occupational Health and Safety Symposium, Wilmington, DE (October 3-5, 1984) 62 ------- APPENDICES 63 ------- DESCRIPTION OF COLUMN HEADINGS FOR APPENDICES A THROUGH E Chemical Name: Alphabetical listing of chemicals as shown in Appendix B of Volume I. Synonym, if given, in parentheses. GAS No: - Chemical Abstract Service (GAS) Registry Number. Resistant Material: The normally outside material of the CPC (i.e., the chemical contact sur- face). See Appendix E of Volume I. ‘roduct Description: See column 1 of Appendix E in Volume I.’ Vendor: . See Appendix E of Volume II. UNK = Unknown. Breakthrough Time: See Appendix A of Volume I. Permeation Rate: See Appendix A of Volume I. Percent Weight Change/ Change in weight of CPC specimen Immersion Time: , due to immersion in chemical for time indicated. Percent Swell! ‘ Volume change due to immersion. ‘in Immersion Time: chemical for time indicated. Diffusion Coefficient: a x 10 b ‘cm 2 /sec. Temperature: Test temperature, ‘if reported; other- wise assumed to be 25°C. Thickness: Initial thickness of test specimen, if reported; otherwise no value is given. Ref Number: Source of data. See Bibliography. 64 ------- APPENDIX A PERMEATION DATA A-i ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO RESISTANT MATERIAL PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS PERMEATION RATE UG/CM**2/M IN TEMP THICKNESS REF DEGC CM NUM Acetic Acid 000641970 CPE 001 UNK 015 UNK. 017 100 102 121 008 102 UNK 002 100 210 018 100 UNK 005 210 019 100 UNK > 3.00 3.95 2.40 .68 .85 2.25 4.50 2.50 1.50 2.00 1.50 1.50 3.50 1.27 3.50 > 1.00 > 6.00 6.00 7.00 > 1.00 > 1.00 6.00 4.50 > 1.00 25. .07 302 23. .05 204 42.08 23. .05 204 23. 052 23. .04 052 23. .05 107 23. .05 026 23. .05 026 23. .05 026 23. .05 026 23. .06 026 23. .04 026 23. .05 026 96.19 23. .05 237 23. 026 23. 052 23. 107 23. 080 23. .04 107 23. .06 052 23. .09 052 .02 23. 080 23. .06 107 23. .05 052 Aceta dehyde 000750700 014. 118 060 113 UNK 001 103 017 100, 002 100 018 100 125 103 019 103 118 .40 23. .04 323 .40 23. 227 25. .07 302 9.58 9.60 .17 - .50 .66 .28 .12 .28 .20 .17 .01 .07 .05 .05 .27 .05 .08 > 6.00 > 3.00 .01 .50 . .66 > 3.00 23. 23. 48.10 23. 90.18 - 901.80 23. 901.80 . 9,018.00 23. 199.00 23. 901.80 . 9,018.00 23. 72.14 23. 529.06 23. 967.93 23. 967.93 23. 901.80 . 9,018.00 23. 901.80 - 9,018.00 23. 282.56 23. 264.53 23. 9.02 - 90.18 23. 901.80 - 9,018.00 23. 23. .02 ‘23. 1,694.78 23. 25. 23. 058 076 102 007 077 122 069 009 112 100 100 100 103 100 118 510 118 113 142 142 045 .05 107 107 .05 323 .04 107 045 045 .03 323 .04 227 107 •1 07 .03 323 045 107 107 .01 227 .05 303 .03 323 .04 302 142 B UT V L CPE NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC SILVER SHIELD TEFLON VITON VI TON/CHLOROBUTVL NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE UNK 060 113 026 102 A— 2 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 000641970 NITRILE+PVC 057 210 6.00 .02 23. 080 058 100 .27 23. 107 PE 076 100 .25 23. 107 127 ‘° 5.00 23. 104 PVC 003 UNK .08 . 23. .02 052 007 100 3.00 23. 107 210 4.00 12.02 23. ‘ 080 UNK 1.00 “ 23. 052 077 100 .75 23. 107 .10 23. 107 SARANEX 061 ‘127 > 66.67 23. 104 TEFLON 069 510 > 4.00 .02 25. .05 303 VITON 009 UNK > 1.00 23. .03 052 VITON/CHLOROBUTYL 112 113 > ‘3.00 ‘ 25. .04 302 Acetic Acid, >70% 000641973 NATURAL RUBBER 001 120 .35 18.04 23. .05 236 NITRILE 005 120 1.97. 1,328.65 23. .06 236 PVC 003 , 120 1.42 1.80 23. .08 .236 Acetic Anhydride . 001082470 BUTYL. 014 118 > ‘ 8.00 .02 23. .09 323 CPE 060 113 1.25 ‘ 23. .05 204 1.20 54.11 . 23. ‘ .05 204 NATURAL RUBBER 001 250 .05 10.02 20. ‘ .02 323 NEOPRENE 018 100 3.50 6.01 20. .05 323 Pvc 007 100 ‘ .07 ‘ 120.24 20. . .02 323 TEFLON 069 510 > 3.00 .02 23. .05 303 Acetone 000676410 BUTYL 014 118 > 20.33 23. .08. 323 > 17.00 23. .04 227 216 > 4.00 21. .07 124 CPE 060 113 .33 - .42 25. .07 302 .53 - .58 22. .07 302 .45 - .52 25. .07 302 .28 23. .05 204 .25 1,022.04 23. .05 204 NATURAL RUBBER ‘ 001 103 288’. 58 23. 045 210 .10 60.12 23. 080 UNK .23 ‘ 35.07 23. .12 274 017 100 . .09 110.22 ?5. .03 222 .17 90.18 - 901.80 23. .05 107 102 .13 4.81 23. .05 026 .17 9.02 23. .05 Q 6 .13 5.41 23. .05 026 .15 7.21 23. .05 026 120 .04 210.42 25. .02 222 502 .10 ‘ 82.16 ‘ 25. .05 222 504 .25 66.13 25. .05 222 .45 45.09 25. .06 222 UNK .10 > 140.28 23. .04 274 NEOP+NAT RUBBER 026 102 .08 100.20 25. .05 222 A- 3 ------- SUMMARY OF PERFORMANCE DETAIL TESTS V PERMEATION TEST > 8.00 > 8.00 > 8.00 23. .07 323 23. .04 227 23. .02 213 BREAKTHROUGH -TIME HOURS CHEMICAL NAME! RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE 000676410 NEOP+NAT RUBBER 026 -102 121 NEOP/NAT RUBBER 008 102 114 UNK NEOPRENE 002 100 120 210 018 100 PERMEATION RATE TEMP THICKNESS REF UG!CM**2!MIN DEG C CM’ NUM .12 8.42 23. .06 .08 - 12.63 23. .04 026 .13 4.81 23. .05 .05 126.25 23. .05 237 .13 4.81 23. .13 46.09 25. .05 222 13 > 150.30 23. .05 274 .17 90.18 - 901.80 23. 107 .04 .04 . 180.36 310.62 25. 25. .08 .07 222 222 .10 72.14 23. 080 .23 • 334.27 23. .05 323 .08 90.18 - 901.80 23. .04 107 .95 86.17 25. .08 .32 140.28 25. .05 222 > .53 .55 “.27 1.00 .43 .33 .09 .22 .08 .07 .05 .08 .10 .25 . < < > > 170.34 90.18 140.28 120.24 1,557.11 480.96 2,004.00 ‘ 801.60 801.60 801.60 1,503.00 150.30 110.22 312.62 25. 25. 25. 23. 23. 23. 23. 25. 25. 25. 25. 25. 23. 23. 23. .07 .05 .03 .09 O6 , .04 .06 .04 .03 .03 .05 .05 222 222 222 274 274 045 080 222 222 222 222 222 274 274 080 > 1.00 .07 .05 < 9.02 - 30.06 2.00 90.18 25. 25. 23. .01 .01 222 222 107 > 4.00 .50 .07 .30 > 60.12 - 13.83 541.08 21. 23. 23. 23. .12 .04 124 274 323 080 > > .15 .55 6.00 3.00 > < 140.28 19.84 .02 23. 23. 23. 23. .16 .01 .05 274 104 227 ‘303 > 3.50 .02 25. .05 303 < .01 4,843.87 23. .02 323 - - - .03 1.28 1.63 .88 > 150.30 23. 25. 20. 27. .03 .04 .04 .04 274 302 302 302 118 120 UNK 125 103 005 210 019 ‘ 100 181 503 UNK 057 - 210 006 100 505 076 100 004 100 UNK 102 100 007 210 UNK 061 127 122 118 069 510 009 118 UNK 112 113 014 118 064 117 NITRILE NITRILE+PVC PE PV ALCOHOL PVC SARANEX SILVER SHIELD TEFLON VITON VI TON/CHLOROBUTYL Acetonitrile 000750580 BUTYL .87 1.58 .72 .88 A- 4 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UGi CM**2/MIN DEC C CM NUM 000750580 BUTYL 064 117 . > 8.00 .23. .01 213 > 8.00 23. .02 213 BUTYL/NEOPRENE 110 117 > 8.00 23. .02 213 CPE 060 113 1.33 - 1.42 25. .07 302 NATURAL RUBBER 001 103 150.30 23. 045 506 .01 117.23 23. .01 323 NEOPRENE . 018 .100 1.27 10.82 23. .06 323 093 117 .18 23. .02 213 125 103 0 72.14 23.. 045 138 117 .58 23. .03 213 139 117 .83 23. .01 213 NITRILE 019 103 66.13 23. 045 PE 076 117 .01 23. .02 213 PV ALCOHOL 102 100 > 8.00 23. .04 323 PVC 007 103 66.13 23. 01.5 049 117 .05 23. .01 213 SARANEX 061 117 > 8.00 23. .01 213 SILVER SHIELD 122 1.18 > 8.00 23. .01 227 TEFLON 069 510 4.50 .02 25. .05 303 VITON 145 117 > 8.00 23. .01 213 VITON/CHLOROBUTYL 112 113 1 5O - 1.75 25. .04 302 VITON/NEOPRENE 111 117 .75 23. .02 213 Acetophenone 000988620 TEFLON . 069 510 > 92.00 .02 25. .05 303 AcetyL ChLoride 000753650 SARANEX 061 127 .62 1.10 23. 104 TEFLON 069 510 > 3.10 .02 23. .05 303 Acrotein 0 001070280 BUTYL 014 118 15.00 23. .06 323 CPE 060 UNK .13 23. 142 .92 23. 142 NITRILE 019 100 .07 966.13 23. .04 323 PV ALCOHOL 102 100 .25 3.01 23. .03 323 VITON 009 118 .01 432.86 23. .02 323 VITON/CHLOROBUTYL 112 UNK > 3.00 23. 142 AcryLic Acid 000791070 TEFLON 069 510 > 3.00 .02 23. .05 303 AcrytonitrUe . 001071310 CPE - 070 UNK .28 23. .05 004 PE 076 127 .08 .02 23. 104 SARANEX 061 127 .38 .02 23. 104 TEFLON 069 . 510 .90 .08 23. 303 ALLyL ALcohoL 001071860 BUTYL 014 UNK > 8.17 25. 287 064 117 > 8.00 23. .02 213 8.00 23. .01 213 > 8.00 23. .02 213 A-5 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL• NAME! RESISTANT CASNO MATERIAL bOl 071860 BUTYL/NEOPRENE CPE NEOPRENE Attytamine 001071190 AL.Lyt ChLoride PE PV ALCOHOL PVC SARANEX TEFLON VITON VI TON/NEOPRENE Arrmonium Hydroxide, <30% 1.25 1 .70 2.76 23. 23. 1.44 25. 23. 23. 23. 23. 33.07 25. 23. 23. 23. .02 23. 23. 23. .02 .05 213 004 287 .02 213 .03 213 .02 213 .01 213 287 .01 213 .01 213 .01 213 .05 303 .01 213 .02 213 23. .05 004 .02 •23. .05 303 .02 23. .05 303 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS 110 070 002 093 138 117 UNK UNK 117 117 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUN 139 117 076 004 049 077 061 069 145 111 117 UNK 117 117 117 510 117 117 > 8.00 2.00 2.35 1.58 6.08 3.42 1.67 .24 1.75 .08 8.00 > 3.10 > 8.00 > 8.00 3.92 .02 .20 .02 014 118 001 250 102 100 007 ‘100 070 UNK 069 510 70 A 4 6,633.24 12,114.18 9,829.62 BUTYL NATURAL RUBBER PV ALCOHOL PVC 001070510 CPE TEFLON Amonium FLuoride, 30-70% ‘121250182 NATURAL RUBBER NEOPRENE Aninonium Hydroxide 013362160 20. 20. 23. 20. .06 323 .01 323 .07 323 .02 .323 017 100 > 6.00 23. ‘, 23. .05 1O7 002 100 > 6.00 • ‘ 107 018 100 ‘ 6.00 ., , 23. .04 107 NITRILE 019 , 100 > 6.00 23. .06 107 PVC 007 100 > 6.00 23. , 107 NATURAL RUBBER ‘ 001 210 2.00 ‘ 23. 080 NEOP+NAT RUBBER 026 121 .45 ‘ 18.04 23. .05 237 NEOPRENE 002 210 ‘6.00 < .02 23. 080 NITRILE 005 210 6.00 < ‘ .02 23. 080 NITRILE+PVC 057 210 3.00 23. 080 . 058 100 .18 23. ‘107 PE 076 100 ‘.07 ‘ 23. 107 PVC 007 077 210 100 > .75 6.00 .30 23. 23. 23. 080 107 107 , NATURAL RUBBER .001 017 UNK 100 > 1.00 1.75 23. 23. , .05 052 107 NEOPRENE , 002 100 > 6.00 23. 107 ‘ 018 ‘ 100 > 6.00 23. .04 107 ‘ UNK > 1.00 23. .06 052 ‘ > 1.00 23. .09 052 NITRILE 019 ‘ 100 ‘ > 6.00 013362161 A- 6 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST VITON Amonium Hydroxide, 30-70% 013362162 PE PERMEATION RATE TEMP UG/CM**2/MIN DEG C THICKNESS REF CM HUM 052 052 107 052 CHEMICAL NAME/ CASNO RESt SlANT MATERIAL 013362161 NITRILE PVC PRODUCT VENDOR DESC CODE • BREAKTHROUGH TIME HOURS Amyt Acetate (PentyL Acetate) 006286370 NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC AmyL AIcohoL. (PentanoL) 000714100 BUTYL NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC VITON AniLine (Benzarnine) OOO6253 0 BUTYL BUTYL/NEOPRENE 019 UNK . 1.00 • 003 UNK 23. .05 007 100 . .02 4.00 23. .02 009 UNK > 1.00 23. 23. .03 076 127 < .02 10.32 23. 104 001 210 .20 002 . 210 60.12 23. 080 005 210 .25 .67 66.13 23. 080 019 • 100 1.00 • 30.06 23. 080 057 210 9.02 - 90.18 23. .06 107 076 . 100 .05 42.08 23. 080 004 100 6.00 9.02 - 90.18 23. 107 007 210 .50 .90 48.10 23. 23. 107 080 014 118 > 017 100 .12 .02 23. .07 323 002 .100 .90 - .02 23. .05 107 018 . 100 > 6.00 .90 23. 107 .90 23. .04 107 019 . • .100 5.35 .20 23. .05 323 > .8.00 .90 23. .06 107 058 100 .08 • .90 .02 23 • .04 323 076 100 • .20 . • 9.02 23. 107 004 • 100 3.50 .90 23. • 107 007 100 • • .20 .90 23. 107 077 009 . 100 118 .17 - • .54 < < .90 9.02 .90 .02 23. 23. • 23. 23. • O5 107 107 107 323 012 . UNK . > > > > > > > 6.50 6.50 22.00 22.00 7.00 7.00 23.00 23.00 7.00 7.00 8.00 < < < < < < < < 1.99 1.99 .02 .02 .02 .02 .02 .02 1.20 .02 .02 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. .04 .04 .06 .06 .04 .04 .06 .06 .04 .04 .06 273 273 273 273 273 273 273 273 273 273 273 014 118 > 8.00 8.00 .02 25. 23. • .06 .03 273 323 064 117 > > > 8.00 8.00 8.00 8.00 • 23. 23. 23. 23. .04 .02 .01 .02 227 213 213 213 .17 > 8.00 A- 7 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST BREAKTHROUGH TIME HOURS PRODUCT VENDOR DESC CODE 001 210 UNK 017 100 120 504 UNK PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM • 1.00 .53 > 1.00 .50 1.00• > 1.00 1.00 .90 6.01 23. 23. .12 < 40.08 25. .03 9.02 23. < 40.08 25. < 40.08 25. 080 274 222 CHEMICAL NAME/ RESISTANT CASNO MATERIAL 000625330 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC .05 107 .02 222 .05 222 < 40.08 25. .06 222 .50 > 10.02 23. .04 274 026 121 1.00 252.50 23. .05 237 008 114 .09 15.03 25. .05 222 UNK > 1.00 23. .05 274 002 100 3.00 .90 - 9.02 23. 107 120 > 1.00 < 40.08 25. .07 222 210 .50 12.02 23. 080 018 100 .58 .90 - 9.02 23. .04 107 120 > 1.00 < 40.08 25. .05 222 : • • > 1.00 1.00 < < 40.08 40.08 25. 25. .05 .03 222 •222 UNK > > • 1.00 1.00 .50 1.00 2.00 2.50 6.01 6.01 3.01 9.02 23. 23. 25. 25. 25. 25. .06 • .09 .04 • .04 .06 .06 274 •274 273 273 273 273 093 117 ‘ 1.73 23. .02 213 138 117 4.33 23. .03 213 139 • 117 2.75 23. .Ô2 213 005 210 . 2.50 30.06 23. 080 019 100 1.60 120.24 25. .04 222 118 1.05 1.10 270.54 270.54 23. 23.; .04 .04 323 227 503 .30 180.36 25. .03 222 UNK . > > 1.00 1.00 1.50 1.50 2.50 5.42 • • 3:01 3.01 3.01 3.01 23. .05 23. • .05 25. .04 25. .04 25. .06 25. :06 274 274 273 273 273 273 057 210 6.00 < .02 23. 080 058 • 100 .17 .90 - 9.02 23. 107 006 100 > 1.00 < 40.08 25. .01 222 505 .05 • 25. .01 222 076 100 .07 .90 - 9.02 23. 107 117 6.58 23. .01 213 004 100 1.50 .90 - 9.02 23. 107 UNK > 1.00 23. .12 274 102 100 16.00 23. .03 323 003 120 .05 180.36 25. .01 222 - .30 160.32 25. .03 222 • .15 160.32 25,. .02 222 007 100 3.00 .90 - 9.02 23. 107 210 4.00 8.42 23. 080 UNK > 1.00 23. .16 274 A-S ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM PRODUCT VENDOR DESC CODE 049 117 077 100 061 117 122 118 069 510 009 118 UNK 145 117 111 117 1.25 23. .33 .90 9.02 23. 213 107 .50 .90 9.02 23. 107 • > 8.00 23. .01 213 > 8.00 23. • .01 227 > 3.30 .10 < .02 112.42 23. 23. .05 .03 303 • .17 112.42 23. > 1 OO 23. .03 274 .83 23. > 8.00 23. .01 .02 213 213 > 9.00 .23 .65 .40 9.02 . 90.18 24.05 25.85 23. 23. 23. 23. .07 .05 .05 .03 323 107 323 323 .17 9.02 90.18 23. > 6.00 < .90 23. 107 107 > 16.00 23. .03 323 014 017 018 019 076 004 118 100 100 100 100 100 102 100 CHEMICAL NAME! RESISTANT CASNO MATERIAL 000625330 PVC SARANEX SILVER SHIELD TEFLON VITOM VI TON/NEOPRENE BenzaLdehyde 001005270 BUTYL NATURAL RUBBER NEOPRENE NITRILE PE PV ALCOHOL VITON Benzene 000714320 BUTYL BUTYL/NEOPRENE CPE EVA NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 118 9.93 118 .52 .52 194.19 194.19 23. 23. UNK .33 23. UNK 1.47 130.26 22. 117 009 014 034 064 110 070 074 001 017 026 008 002 507 UNK 117 UNK UNK 210 100 120 502 504 508 UNK 102 121 114 100 120 210 UNK > .08 .67 1 .00 .13 > 8.00 .43 .01 .18 .04 .03 .05 .06 .12 .03 .01 .02 .05 .05 .09 .05 .25 .02 .40 .25 .29 396.79 3,206.40 5,611.20 2,605.20 2,204.40 1,603.20 501 .00 .04 323 .04 227 .02 327 .08 078 .02 213 23. .01 213 .02 213 .06 078 .04 327 .02 213 .05 004 .02 327 080 .03 222 .02 222 .05 222 .05 222 .06 222 .03 078 .05 327 23. .02 327 25. .04 222 23. .05 237 25. .05 2 2 22. .05 078 22. .07 078 25. .08 222 25. .07 222 23. 080 22. .11 333 23. 90.18 22. 23. 23. 23. 23. 23. 25. 25. 25. 25. 25. 22. 23. 2,805.60 2,254.50 2,004.00 400.80 80. 16 951.90 300.60 559.12 517.03 A- 9 ------- • SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST NITRILE+PVC NONWOVEN PE PE POLYURETHANE PV ALCOHOL PRODUCT VENDOR DESC CODE 002 UNK 010 120 018 100 120 093 117 138 117 139 117 005 210 503 019 100 181 503 UNK 033 UNK 057 210 058 100 071 UNK 006 100 209 505 042 UNK 076 100 117 UNK 050 178 004 100 UNK 035 UNK 102 100 003 100 BREAKTHROUGH TIME HOURS .14 .11 .28 • .10 .19 .27 .27 08 .12 .10 .19 .33 3.10 1.00 .41 .27 .67 .40 .11 .08 .08 > 8.00 .33 .10 .32 1.05 .77 .32 .15 .07 .17 .23 • .32 .08 .75 .03 .01 .01 .02 .07 .03 .03 .08 .01 .02 .03 .12 .17 > 33.33 .33 .05 .82 .01 CHEMICAL NAME! RESISTANT CASNO MATERIAL 000714320 NEOPRENE NITRILE UNK 031 UNK • PERMEATION RATE TEMP THICKNESS REF UG/CM**2,MIN DEG C CM NUM 1,167.33 22. .08 333 521.04 22. .04 078 165.93 23. .05 ‘ 323 300.60 22. .04 078 1,002.00 25. .05 222 1,102.20 25. .07 222 801.60 25. .05 222 1,803.60 25. .03 222 22. .04 333 22. .05 333 1,893.78 22. .05 333 23. .06 327 50.10 22. .24 078 80.16 22. .16’ 078 • • • 230.46 22. .08 078 330.66. 37. .08 078 190.38’ 7. .08 078 230.46 22. .08.’ 078 501.00 22. O4 078 23. • .02 213 • 23. .03 213 23. .02 213 901.80 23. 080 501.00 ‘ 22. .02 078 .03 23. .04 323 400.80 25. .04 222 511.02 25. .06 222 851.70 25. • .05 222 1,102.20 25.’ .“ .03 222 1,302.60 25.; .03 222 23. .04 327 870.74 . 22. , .04 333 939.88 22. .04 333 501.00 22. .04 078 180.36 23. 080 901.80 9,018.00 23. 107 23. .01 327 250.50 25. .01 222 350.70 22. .01 078 50.10 25. .01 222 23. .01 327 90.18 . 901.80 23. 107 23. .01 213 23. .01 327 220.44 22. .01 078 110.22 22. .02 078 .90 23. 107 8.02 22. .02 078 22. .09 333 23. .02 327 39.08 22. .01 078 .02 23. .03 323 1,182.56 23. .02 323 PVC A- 10 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PROOUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM HUM 000714320 PVC 003 120 .01 3,507.00 25. .01 222 .01 4,108.20 25. .01 222 .04 1,503.00 25. .03 222 .04 1,603.20 25. .02 222 500 .01 4,709.40 25. .01 222 501 .01 3,607.20 25. ‘.01 222 .01 4,909.80 25. .02 222 UNK .02 23. .01 327 007 210 .50 240.48 23. 080 UNK .30 481.96 22. .10 333 .17 599.20 22. .11 333 .31 421.84 22. .11 333 049 117 .10 23. .01 213 077 117 .16 23. .01 213 168 .10 150.30; 22. .04 078 SARANEX 061 117 .25 23. .01 213 UNK .17 23. .01 327 SILVER SHIELD 122 118 > 8.00 23. .01 227 TEFLON 036 UNK .17 23. .01 327 069 510 > 3.20 .02 23. .05 303 > 3.00 .02 25. .05 303 VITON 009 118 5.93 .07 23. .02 323 6.00 .07 ‘ 23. .02 227 ‘UNK .50 23. .02 327 032 UNK 15.00 .50 22. .16 078 145 117 > 8.00 23. .01 213 VITON/NEOPRENE 111 117 3.50 23. .02 213 Benzenesutfonic Acid 000986790 NEOPRENE 018 100 > 20.00 ‘ 23. .05 123 NITRILE 020 216 > 4.00 23. .04’ 123 Benzethonium Chloride 001215400 BUTYL 014 118 > 8.00 .02 22. .06 323 NATURAL RUBBER 001 250 > 8.00 .02 21. .02 323 NEOPRENE 018 100 > 8.00 .02 19. .05 323 PVC 007 100 > 8.00 .02 19. .02 323 Benzonitrite - 001004700 BUTYL 014 118 8.00 23. .06 323 NATURAL RUBBER 001 ‘ 506 .01 24.05 23. .01 323 PV ALCOHOL 102 100 > 8.00 23. .03 323 VITON 009 118 .93 , 24.05 23. .03 323 Benzoyl Chloride 000988840 BUTYL 014 118 6.28 99.80 23. .06 323 HYPALON 108 210 .33 23. .06 123 NEOPRENE 018 100 .25 23. .05 123 PV ALCOHOL 102 100 , 8.00 23. .05 323 PVC 003 100 .01 596.39 23. .02 323 VITON ‘ 009 118 ‘ 8.00 23. .02 323 .75 ‘ 23. .03 123 A-Il ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO RESISTANT MATER IAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/M IN TEMP THICKNESS REF DEG C CM NUM Bromine 077269560 PE 2-Bromoethanol 005405120 014 118 001 250 003 100 009 118 > 8.00 .02 .03 > 8.00 23. .07 123 23. .03 123 23. .05 004 .02 23. .05 303 66.13 456.91 23. .09 323 23. .02 323 23. .02 323 23. .05 323 BUTYL NATURAL RUBBER PV ALCOHOL VITON 014 118 001 506 102 100 009 118 > 8.00 .02 > 8.00 > 8.00 Benzyt Alcohol 001005160 TEFLON Benzyl Chloride (ChLoromethyl Benzene) 001004470 CPE Bis(2-Ethylhexyl) Phthalate 001178170 BUTYL • NATURAL RUBBER NEOPRENE Boric Acid 100433530 BUTYL 014 216 > 4.00 VITON 009 118 > 20.00 070 UNK • .78 069 510 > 3 2O 014 118 > 8.00 23. .09 323 017 100 > 6.00 < .90 23. .05 107 002 100 2.00 < .90 23. 107 018 100 > 6.00 < .90 23. .04 107 NITRILE 019 100 > 6.00 4.33 < .90 12.02 23. 23. .06 .05 107 323 PV ALCOHOL :004 100 .50 90.18 - 901.80 23. 107 PVC 003 100 .03 12.02 23. .02. 323 VITON 009 118 > 8.00 23. .05 323 BUTYL 014 118 > 8.00 < .02 20. .07 323 NEOPRENE 018 100 > 8.00 < .02 19. .05 323 MITRILE 019 100 > 8.00 < .02 21. .04 323 VITON 009 118 > 8.00 < .02 20. .03 323 076 127 < .02 23. 104 BUTYL 014 118 > 8.00 23. .06 323 NATURAL RUBBER 001 506 < .01 57.11 23. .01 323 PV ALCOHOL 102 100 8.00 23. .03 323 VITON 009 118 > 8.00 23. .02 323 BUTYL 014 118 .53 239.28 23. .06 323 NITRILE 019 118 .22 54.71 23. .04 323 PV ALCOHOL 102 100 > 8.00 23. .02 323 VITON 009 118 > 8.00 23. .03 323 BUTYL NATURAL RUBBER PVC VITON Bromoacetonitri le 005901700 Bromàbenzene 001088610 1 -Broino2- propanol 196867380 23. .06 323 45.69 23. .01 323 - 23. .02 323 23. .02 323 A- 12 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG ,/CM**2 ,IMIN DEC C CM HUM tert-Butanot (Methytpropanot , 2- ,2-) 000756500 SUTYL NATURAL RUBBER NEOPRENE PVC 3-Bromo-1 -propanol 006271890 BUTYL NEOPRENE PV ALCOHOL VITON Butadi ene 001069900 BUTYL NATURAL RUBBER NEOPRENE PVC VI TON 014 118 018 100 102 100 009 118 014 118 001 250 018 100 003 100 009 118 > 8.00 > 8.00 > 8.00 >, 8.00 > 8.00 • .02 .78 .02 > 8.00 .06 23. .05 23. .03 23. .02 323 323 323 323 23. 637.27 23. 1.80 23. 126.25 23. 23. .07 323 .02 323 .05 323 .02 323 .05 323 • Butyt Acetate 001238640 .07 • 02 ‘.05 .02 323 323 323 323 014 118 > 8.00 001 250 .02 018 100 2.75 007 100 .08 014 118 1.90 1.53 001 210 .13 017 100 .07 102 .07 .07 .07 .07 120 .03 502 .11 504 .13 BUTYL NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE 23’. 18.04 ‘.23... .05 ‘ 23. 18.04 23. 45.76 23. .04 227 36.07 ‘23. .05 086 216.43 23.. 080 1,402.80 25. ‘ .03 222 72.14 23. .05 026 72.14 23. .05 026 72.14 23. ‘ .05 026 72.14 23. .05 026 2,905.80 25. .02 ‘ 222 941.88 25. .05 222 881.76 25. .05 222 .23 511.02 25. .06 222 .11 641.28 25. .05 222 .07 72.14 23. .06 026 .07 72.14 23. .04 026 .07 72.14 23. .05 026 .07 .15 72.14 23. ‘ 61.28 25,. .05 026 222 . .09 .06 • , 220.44 25., 320.64 25.. .08 .O7 222 ‘222 .25 72:14 23. 080 ‘ > .32 1.00 < 210.42 ‘ 23. 21.04, 25 , .06 ‘ .08 086. 222s .48 320.64 25. .05, 222’ ‘ .87 320.64 25. .07 222 > 1.00 < 21.04 25. .05 222 ‘ .18 831.66 25. .03 222 1.33 90.18 23. 080 .55 480.96 25. .04 222 1.25 90.18 - 901.80 23. .06 107 .97 250.50 25. .06 222 .67 450.90 ‘25. .04 026 102 008 102 114 002 ‘ ‘ ¶00 , • 120 210 018 100 118 120 005 210 019 100 A- 13 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Butyt Acrytate 001413220 TEFLON 069 510 BREAKTHROUGH’ TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM. CHEMICAL NAME/ RESISTANT CASNO MATERIAL 001238640 NITRILE NITRILE+PVC PE PV ALCOHOL PVC SILVER SHIELD TEFLON VITON PRODUCT ‘VENDOR DESC CODE 019 ‘ 100 118 120 503 020 503 057 210 006 100 505 512 076 100 004 100 003 120 500 501 007 210 122 118 069 510 009 ‘ 118 102.20 23. 327.05 23. 300.60 23. 217.10 23. 350.70 25. 150.30 23. 60.12 23. 20.04 25. 6.01 25. 66.13 23. 9.02 - 90.18 23. .90 23. 6,012.00 25. 6,913.80 25. 3;3O6.60 25. 4,308.60 25. 25. 6,412 8O 25. 4,108.20 25. 72.14 23. 23. .02 23. 318.97 23. 1.08 .48 .25 .53 .33 .32 .67 .03 .20 .03 .17 6.00 .02 .02 .04 .03 .01 .03 .03 .33 > 6.00 > 3.00 .23 > ‘‘ 3.00 2.00 .25 .58 > 8.00 6.00 4.00 6.00 > 6.00 6.00 .58 > 6.00 • 8.00 .50 > ‘ 8.00 > 4.00 3.00 2.00 .42 > 15.60 1.73 .50 1.00 .06 086 .04 “227 .04 ‘086 .05 086 .03 222 .04 086 080 .01 222 .01 222 .01 086 107 107 .01 222 .01 222 .03 222 .02 222 .01 . 222 .01 222 .02 222 080 .01’ 227 .05’ 303 .04 086 .05 303 080 .05 107 .05 237 107 080 .04 107 080 .06 107 080 107 107 104 107 123 124 107 080 107 107 .05 303 .10 323 142 142 Butyt ALcohoL (Butanot, 1) 000713630 NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NI TRI LE NITRILE+PVC PE PV ALCOHOL PVC TEFLON Butytamine 001097390 BUTYL CPE 001 210 017 100 026 121 002 100 210 018 100 005 210 019 100 057 210 058 100 076 100 127 004 100 007 100 210 077 100 069 510 014 118 060 UNK .02 23. 12.02 23.. 9.02 - 9018 23. 6.01 23. .90 23. .02 23. .90 - ‘ 9.O2 23. .02 23. .90 23. .02 23. .90 - 9.02 23. .90 23. < 30.06 23. 9.02 - 90.18 23. 23. 21. .90 - 9.02 23. ‘15.03 23. .90 23.’ .67 9.02 - 90.18 23. .02 23. 501.00 15. 23. 23. A- 14 ------- • SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST PRODUCT VENDOR DESC CODE RES I STANT MATERIAL CPE NATURAL RUBBER NEOPRENE PVC TEFLON VI TON/CHLOROBUTYL BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MIN TEMP THICKNESS REF DEG C CM HUM 7,745.46 2,474.94 5,531.04 .02 23. 20. 18. 18. 23. 23. .05 .02 .05 .02 .05 004 323 323 323 303 142 (Methytpropytamine, 2-) BUTYL CPE NEOPRENE PV ALCOHOL - PVC VITON/CHLOROBUTYL BUTYL NEOPRENE NITRILE PVC BUTYL NEOPRENE NITRILE 60.12 28. 23. 23. 889.78 26. 23. 835.67 :23. 3,432.85 28. 23. .09 323 142 142 .05 323 .03 213 .07 323 .02 323 142 CHEMICAL NAME! CASNO 001097390 iso-Butytamine 000788190 sec-Butylamine 139528460 tert-Butyt amine 000756490 PVC Butyt Cettosotve (Butoxyethanot, 2) 001117620 NITRILE PV ALCOHOL n-Butyt ChLoride (Chtorobutane,1-) 001096930 NITRILE • PV ALCOHOL • PVC • VITON n-Butyt Phthatate 000847420 BUTYL NATURAL RUBBER - NEOPRENE NITRILE 014 018 019 007 21. .09. 323 25. .05 323 14. .04 323 24. .02 323 180.36 1,402.80 1,482.96 4,529.04 .02 360.72 240.48 3,036.06 070 UNK .33 001 250 .02 . 018 : 100 .20 007 100 .02 069 510 . > • 3.00 112 UNK .50 014 118 3.70 060 UNK . 2.28 2.42 018 100 .32 138 117 < .08 102 100 .32 007 100 .02 112 • UNK 1.25 014 118 2.68 018 100 .27 019 100 .33 007 100 .01 118 100 100 100 > . 8.00 1.17 1.40 .03 • 019 100 . .45 . 118 : > .35 4.00 .15 . 004 100 > 18.00 019 100 .20 661.32 23.. .05 323 004 100 > 8.00 . < .02 23. .08 323 003 100 .20 2,278.55 23. .02 323 009 . 118 7.42 3.01 23. .05 323 014 118 > > 16.00 16.00 23. 23. .04 .04 323 227 017 100 .28 23. .05 107 002 100 - 5.00 .90 . 9.02 23. 107 018 100 • 2.00 < .90 23. .04 107 125 103 . < • .02 23. 045 019 100 103 118 • > > 6.00 16.00 16.00 • < < .90 23. .02. 23. 23. • 23. .06 .03 107 045 323 15. 23. 21. 20. .09 323 .05 323 .04 323 .02 • 323 37. .06 107 37. .06 107 22. .03 122 200.40 34. .04 122 22. .04 122 A- 15 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL. BREAKTHROUGH TIME HOURS PVC SILVER SHIELD VITON 058 100 076 100 004 . 100 102 100 077 100 122 118 009 118 > 6.00 > 6.00 > 6.00 > 16.00 > 6.00 > 6.00 > 6.00 > 8.00 > 8.00 23. 23. .90 23. 23. 23. 23. 23. 23. 23. 107. 107 107 .03 323 107 107 .01 227 .O3 323 .02 227 NEOPRENE. NI TR I LE PV ALCOHOL SILVER SHIELD VITON 1.78 1.70 1.22 > 6.00 7.00 > 8.00 > 8.00 > 8.00 48.10 23. 48.10 23. 421.44 23. 23. 23. 23. 23. 23 .06 323 .04 227 .05 323 .04 323 .03 323 .01 227 .02 .323 .02 227 Butyra Idehyde 001237280 Carbon Disutfide (Carbon Bisutfide) 000751500 BUTYL CPE NEOP+NAT RUBBER 014 118 018 100 102 100 069 510 009 118 NITRILE 019 23. .07 75.75 23. .05 .78 23. .03 .02 23. .05 54.11 23. .03 591.58 23. .06 323 588.24 23. .04 227 25. .07 302 23. .05 004 23. .05 237 23. .06 107 23. .04 323 23. .04 227 90.18 23. 107 .90 23. 107 23. .03 323 .05 23. .05 303 .07 23. .05 303 .05 23. .05 303 24. .05 303 24. .05 303 24. .05 303 24. .05 303 23. .03 323 23. .02 227 25. .04 302 Carbon Tetrachtoride (Tetrachlorornethane) 000562350 CPE 060 - 113 3.48 3.45 23. .05 - 204 78.16 23. .05 204 PRODUCT VENDOR DESC CODE 000847420 NITRILE+PVC PE PV ALCOHOL PERMEATION RATE TEMP THICKNESS REF UG/CM**2/M IN DEG C CM NUM p-tert-Butyt Totuene 271302120 BUTYL 014 . 118 018 100 019 100 102 100 122 118 009 118 BUTYL NEOPRENE PV ALCOHOL TEFLON VITON 323 323 323 303 323 .13 15.00 .73 .27 > 7.50 .90 014 118 .05 .12 060 113 070 UNK 026 121 . 100 118 PE , 076 100 > > .12 PV ALCOHOL 004 102 100 100 6.00 16.00 TEFLON . 069 510 .36 , . .34 .30 .22 .22 . VITON . VITON/CHLOROBUTYL 009 112 • , 118 113 > .18 . .60 .60 16.00 16.00 .25 .17 .13 .02 889.78 .50 90.18 901.80 .15 306.61 .22 306.61 9.02 A- 16 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 000562350 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE SILVER SHIELD TEFLON VITON PRODUCT VENDOR DESC CODE 017 100 120 502 504 026 102 008 114 002 100 120 UNK 018 : 118 120 UNK 118 181 503 UNK 058 100 006 100 505 076 100 004 100 UNK 102 100 003 120 .17 > 1.00 .57 .14 .32 .24 > 1.00 > 1.00 > 1.00 3.40 > 1.00 > 1.00 > 3.33 > 3.33 .05 .03 .13 .08 > 6.00 > 3.33 > 8.00 .01 .03 .14 .04 .02 .02 .02 .42 .22 .66 .51 .12 .25 > 6.00 > 3.00 > 13.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2!MIN DEG C CM NUM .03 222 .02 222 .05 222 .05 222 .06 222 .05 222 .05 222 .08 222 .07 222 .11 333 .08 333 .08 222 .05 222 .07 222 .05 222 .03 - 222 .05 333 .05 333 .04 333 .04 222 .06 107 .06 222 .04 222 .04 227 .03 222 .03 222 .04 333 .04 333• 107 .01 222 .01 222 107 107 .09 333 .04 323 .01 222 .01 222 .03 222 .02 222 .01 222 .01 222 .02 222 107 .11 333 .1•1 333 .10 333 107 107 .01 227 .05 303 .02 227 BREAKTHROUGH TIME HOURS 019 100 NITRILE NITRILE+PVC PE PV ALCOHOL PVC .06 1,603.20 25. .03 6,012.00 25. .08 5,110.20 . 25. .50 801.60 25. .18 1,603.20 25. .07 4,609.20 25. 17 3,106.20 25. .50 . 100.20 25. .08 501.00 25. .24 300.60 22. 619.24 22. 6.01 25. 801.60 25. .68 901.80 25. .38 901.80 25. .22 801.60 25. 2,244.48 22. 1,756.51 22. 1,997.99 22. 6.01 25. 2.50 9.02 . 90.18 23. < -1,669.98 25. 6.01 25. 30.06 23. 6.01 25. 6.01 25. 22. 22. 9.02 . 90.18 23. 501.00 25. 80.16 25. 9.02 - 90.18 23. .90 23. 3.01 22. 23. 1,002.00 25. 2,004.00 25. 601.20 25. 801.60 25. 2,104.20 25. 2,505.00 25. 2,004.00 25. 90.18 - 901.80 23. 496.99 22. 203.41 22. 250.50 22. 9.02 -. 90.18 23. 9.02 - 90.18 23. 23. .02 23. 23. 500 501 007 100 UNK 077 100 122 118 069 510 009 118 ChLorine A- 17 ------- SUMMARY. OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 077825050 .BUTYL BUTYL/NEOPRENE NEOPRENE PE PVC. SARANEX VITON VITON/NEOPRENE PRODUCT VENDOR DESC CODE 064 117 110 117 093 117 138 117 139 117 076 117 049 117 053 117 061 117 145 117 111 117 BREAKTHROUGH TIME HOURS 8.00 > 8.00 > 8.00 > 8.00 > 8.00 > 8.00 > 8.00 .08 .92 .08 .08 > 8.00 > 8.00 > 8.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 23. .02 213 23. .01 213 23. .02 213 23. .02 213 23. .02 213 23. .03 213 23. .02 213 23. .01 213 23. .01 213 23. .01 213 23. .02 213 23. .01 213 23. .01 213 23. .02 213 Chtoroacetic Acid 000791180 PE BUTYL NATURAL RUBBER PV ALCOHOL VITON NITRILE PV ALCOHOL PVC 002 UNK 018 UNK 019 UNK 004 UNK 007 UNK .10 .06 .12 16.67 .08 .09 .07 .08 333 .11 333 22. .04 333 22. .05 333 .05 333 .04 333 .04 333 .09 333 .11 333 .10 333 .11 333 SARANEX ChtoroacetonitriLe 001071420 Ch Lorobenzene 001089070 BUTYL . 014 NEOPRENE 002 NITRILE • 005 019 PE PV ALCOHOL 076 004 102 118 UNK 229 120 PVC 100 100 100 076 127 > 8.00 23. 104 .08 65. 104 061 127 1.00 65. 104 014 118 8.00 23. .06 323 001 506 < .01 75.75 23. .01 323 102 100 . 8.00 23. .03 323 009 118 8.00 23. .03 323 007 • 100 , . , .58 .18 .21 .25 . .07 .25 8.00 .03 90.18 9.02 . - - < 3,086.16 . 940.21 960.25 901.80 90.18 .02 3,757 5O 23. 23. 23. 23. 23. 23. 23. 23. .07 .05 .11 .04 .08 .02 323 186 210 210 107 107 323 323 UNK > > .15 .31 3.00 4.00 8.00 < < .02 .02 23. 23. 23. 23. 23. .05 .07 .05 .03 .03 186 186 303 210 323 1,764.52 783.56 22. 22. TEFLON 069 510 VITON 009 118 2-Chtoro-1,3-butadiene (Chioroprene) 001269980 NEOPRENE .05 .05 .07 .11 3,164.32 22. 2,329.65 22. 2,077.15 . 22. 22. 669.34 22. 851.70 22. 954.91 22. A- 18 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 3-Chtoro-2-methytpropene 3.27 .60 .03 > 8 0O Ch Lorodi bromomethane 001244810 BUTYL PV ALCOHOL -PVC VITON ChLoroform (Trichtoromethane) 000676630 CPE NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 149.75 23. .02 23. 1,106.21 ‘23. 23 .10 323 .07 323 .02 323 .04 323 031 NITRILE 019 .50 . 8 25. .07 302 .20 23. .05 004 .03 4,008.00 25. .03 222 .01 , 15,030.00 25. .02 222 .04 7,615.20 25. .05 222 .05 5,611.20 25. .05 222 • .05 7,014.00 25. .06 222 .05 .11 .O2 .01’ .36 .16 , ‘ 7,014.00 4,408.80 2,705.40 6,813.60, 2,004.00 3,206.40 2,805.60 2,505.00 4,408.80 •, 9,418.80 25. 25. 25. , 25. 25. 25. 25. 25. 25: 23. 25. , .05 .05 .08 .07 .08 .05 .07 .05 .03 ‘ .04 ‘ .04 222 222 222 222 222 222 222 222 222 187 222 .07 .16 .01 • 5,611.20 9,919.80 2,116.22 7,014.00’ 1,603.20 ‘25. 25. 23. 25. 23. 25. .06 .04 .04 ‘.03 .05 .01 222 222 227 222 187 222 .05 , 25. .01 222 UNK 100 012 118 004 100 003 100 009 118 060 113 070 UPIK 017 100 120 502 504 026 ‘102 008 114 002 100 120 018 118 120 118 503 033 UNK 006 100 505 056 UNK 076 100 127 004 100 102 100 003 120 500 501 049 UNK 061 127 122 , 118 069 510 009 118 112 113 .23 .17 .06 .20 .08 .21 .04 .07 PE PV ALCOHOL PVC SARANEX SILVER SHIELD TEFLON VITON VI TON/CHLOROBUTYL .07 .10 .02 > 6.00 > 8.00 .01 .01 .01 .01 .01 .01 .01 .14 .02 .17 >, 3.60 9.50 > 3.OO 23. p.01 187 9.02 - 90.18 23. 107 348.70 23. 104 .90 ‘ 23. S 107 23. .03 323 15,030.00 25. .01 222 > 16,699.98 25. ‘ .01 222 5,410.80 25. .03 222 11,022.00 25. .02 222 15,030.00 25. .01 222 12,024.00 ‘ 25. ‘ .01 222 13,026.00 25. .02 222 23. .03 187 201.40 23. ‘ 104 .05 23. .01 227 <‘ .0223. .05 303 2.77 23. .02 227 25. .04 302 A- 19 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 005634730 BUTYL 014 118 .50 120.24 23. .06 323 PV ALCOHOL 004 100 .03 80.16 23. . .04 .323 PVC 007 100 .01 120.24 23. .02 323 VITON 009 118 . 3.83 30.06 23. .03 323 ChLoronaphthatenes (aLL isomers) 255864300 NITRILE 019 118 2.90 7.93 23. .04 227 PV ALCOHOL 004 100 > 6.00 .90 23. 107 SILVER SHIELD 122 118 > 8.00 23. .01 227 VITON 009 118 > 16.00 < •1,669.98 23. .02 227 2-Chtoro-2-nitropropane 005947180 BUTYL 012 118 > 8.00 .02 23. .09 323 NATURAL RUBBER 017 506 .02 270.54 23. .02 323 PV ALCOHOL 004 100 > 8.00 .02 23. .07 323 VITON 009 . 118 2.05 120.24 23. .04 323 1Chtoro-2-propanot 001270040 BUTYL . 014 118 > 8.00 23. .06 323 NATURAL RUBBER 001 506 .01 23. .01 323 PVC . 003 100 .02 230.86 23. .02 323 VITON 009 118 > 8.00 23. .03 323 3-Chtoro-1-propanot 006273050 BUTYL 014 118 > 8.00 23. .06 323 PV ALCOHOL 102 100 .80 92.58 23. .04 323 PVC 003 100 .18 409.42 23. .02 323 VITON 009 118 > 8.00 23. .03 323 ChLorosutfonic Acid 077909450 PE 076 127 1.05 23. 104 SARANEX 061 127 5.83 23. 104 o-Chtorototuene 000954980 NITRILE 005 229 .29 1,163.99 23. .11 210 019 120 .88 988.64 23. .04 210 VITON 009 118 > 4.00 23. .03 210 p-Chtorototuene 001064340 NITRILE 005 229 .25 1,224.11 23. .11 210 019 120 .42 890.11 23. .04 210 VITON 009 118 > 4.00 23. .03 210 Chromic Acid 111157450 NATURAL RUBBER 001 210 1.17 23. .080 NEOPRENE 002 210 1.25 23. 08 NITRILE 005 210 6.00 .02 23. 080 NITRILE+PVC 057 210 6.00 .02 23. 080 058 100 6.00 23. 107 PE 076 100 > 6.00 23. 107 PVC 007 aio 6.00 .02 23. 080 077 100 > 6.00 23. 107 > 6.00 23. 107 A- 20 ------- Chromic Acid, 30-70% 111157452 SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL PRODUCT DESC CODE VENDOR BREAKTHROUGH HOURS TIME PERMEATION RATE TEMP UG/CM**2/MIN DEG C THICKNESS CM REF NUM Chromic Acid, <30% 111157451 NEOP+NAT RUBBER 026 121 > 8.00 < .02 23. .05 237 NITRILE 019 100 4.00 23. .06 107 PVC 007 100 > 6.00 23. 107 Citric Acid, <30% 000779291 NATURAL RUBBER 017 100 > 6.00 23. .05 107 NEOPRENE NITRILE 002 018 019 100 100 100 ‘> > > 6.00 6 00 6.00 23. 23. 23. .04 .06 107 107 107 NITRILE+PVC 058 100 > 6.00 • 23. 107 PE 076 100 > 6.00 23. 107 PV ALCOHOL 004 100 .83 23. 107 PVC 007. 077 100 100 > > > 6.00 6.00 6.00 23. 23. 23. 107 107 107 Creosote . . 080015890 BUTYL 034 UNK > 90.00 22. .08 078 NEOPRENE 031 UNK 4.50 22. .08 078 VITON 032 UNK > 96.00 . 22. .04 078 Creosote, Wood . 080213940 NEOPRENE 018 100 > 4.00 23. .05 123 VITON . 009 118 > 1900 23. .03 123 m-CresoL . 001083940 NATURAL RUBBER 017 100 120 502 504 > > .60 .23 .50 1.00 1.00 ‘ 15.03 2.00 1.00 1.00 25. 25. 25. 25. 25. .03 .02 .05 .05 .06 222 222 222 222 222 NEOP+NAT RUBBER 026 102 .50 2.00 25. .05 222 NEOP/NAT RUBBER 008 114 • > 1.00 1.00 25. .05 222 NEOPRENE 002 018 100 118 120 > > > > > > 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 25. 25. 25. 25. 25. 25.. .08 .08 .05 .07 .05 .03 222 222 222 222 222 222 NITRILE PE 019 . 006 100 503 100 505 > > > > > > 1.00 1.00 1.00 1.00 1.00 1.00 < 1.00 1.00 1.00 1.00 1.00 .10 25. 25. 25. 25. .25. 25. .04 .06 .04 .03 .01 .01 222 222 222 222 222 222 PVC 003 120 > .20 .23 1.00 .23 . . 67.13 59.12 1.00 63.13 25. 25. 25. 25. .01 .01 .03 .02 222 222 222 222 A- 21 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 001083940 PVC Cresots TEFLON PRODUCT VENDOR DESC CODE 003 500 069 501 510 BREAKTHROUGH TIME HOURS .13 .13 .12 > 4.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 44.09 25. .01 222 55.11 25. .01 222 56.11 25. .02 222 .02 23. .05 303 Crotonatdehyde (Butenat,trans-2) 041703030 BUTYL Cumene (Methytethyt Benzene) 000988280 CPE 070 .67 - 1.00 > 2.00 .40 23. .13 23. 013197730 PE SARANEX 076. 127 061 127 014 118 CPE NEOPRENE PV ALCOHOL TEFLON VITON 070 018 102 069 009 UNK ‘100 100 510 118 8.00 .63 .35 .01 > 3.10. .12 Cyc L ohexane 001108270 BUTYL NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC RE PV ALCOHOL PVC 104 23. .07 323 23. .05 004 < 209.22 23. .05 323 57.72 23. .03 323 .02 23. .05 303 313.83 23. .03 323 UPIK 1.30 23. . .05 004 . 1.15 1.10 122.04 122.04 23. 23. .07 .04 323 227 • > .10 .03 .13 .16 .30 .08 .16 .10 .95 1.00 .48 ‘1.20 6.00 • < . < 2,044.08 10.02 1,503.00 1,302.60 1,102.20 801.60 1,402.80 70.14 1,082.16 .18 10.02 100.20 100.20 .02 23. 25. 25. 25. 25. 25; 25. 25. 23. 23. 25. 25. 25. 23. .03 .02 .05 .05 .06 .05 .07 .04 .05 .05 .03 080 222 222 222 222 222 222 222 080 323 222 222 222 080 > > > > > 6.00 1.00 - ‘‘1.00 1.00 1.00 1.00 3.00 .03 < < < < < ‘ 10.02 1.00 1.00 1.00 10.02 12.02 100.20 23. 25. 25. 25. 25. 25. 23. 25. .04 .04 .06 .04 .03 .03 .01 323 222 222 222 222 222 080 222 .17 .78 < 28.06 .02 25. 23. .01 .03 222 323 .03 .06 .27 501.00 340.68 100.20 25. 25. 25. .01 .01 .03 222 222 222 .09 200.40 25. .02 222 500 .03 310.62 25. .01 222 501 .01 450.90 25. .01 222 014 118 001 210 017 100 120 502 504 026 102 002 120 210 018 100 120 005 210 019 100 181 503 057 ‘ 210 006 100 505 102 . 100 003 120 A- 22 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST NEOP+NAT RUBBER NITRILE PV ALCOHOL SILVER SHIELD VITON > 16.00 > 16.00 .28 .48 > 7.00 > 6.00 .48 23. .05 323 23. .04 227 132.26 23. .05 237 518.84 23. .03 227 23. .03 323 23. .01 227 518.84 23. .03 323 Decanat (aLL isomsers) 001123120 BUTYL 064 117 > 8.00 > 8.00 •> 8.00 23. .02 213 23. .01 213 23. .02 213 RESISTANT MATERIAL PVC SILVER SHIELD TEFLON VITON BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF HOURS UG/CM**2/MIN DEC C CM NUM PRODUCT VENDOR DESC CODE 003 501 007 210 122 118 069 510 009 118 014 118 BUTYL 300.60 25. 216.43 23. 23. .02 23. 23. 23. CHEMICAL NAME/ CASNO .001108270 Cyc I ohexano L 001089300 NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC SILVER SHIELD VITOM Cyc I ohexanone 001089410 BUTYL 017 100 002 100 210 018 100 UNK 031 511 005 210 019 100 118 .04 .55 > 6.00 > 3.40 7.00 > 7.00 > 11.00 > 11.00 .42 .25 9.02 3.00 • 3.00 2.50 .90 - ‘ 8.00 8.00 ******** 6.00 > 6.00 > 16.00 > 16.00 6.00 .25 .90 > 6.00 6.00 16.00 6.00 6.00 1.00 > 6.00 > 6.00 > 8.00 > 8.00 .O2 222 080 .01 227 .05 303 .02 323 .02 227 .07 323 .04 227 080 .05 107 107 080 .04 107 .08 323 .01 323 080 .06 107 .03 323 .04 227 080 107 107 107 .03 323 107 080 107 107 .01 227 .03 323 .02 • 227 72.14 90.18 .90 60.12 9.02 -1,669 .98 .02 .90 .02 9.02 .90 .90 9O .02 .90 .90 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. -23. 23. 23. 23. 23. 057 210 058 100 076 100 004 100 102 100 007 • 100 210 077 100 122 118 009 118 014 118 026 121 019 118 102 100 122 118 009 118 CycLohexytamine 001089180 • 118 2.93 290.58 20. .06 323 NATURAL RUBBER • 001 250 . .02 8,977.92 20. .02 323 NEOPRENE 018 100 .60 1,322.64 22. .05 323 NITRILE 019 100 • 1.02 A—23 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS. REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 001123120 BUTYL/NEOPRENE 110 117 2.50 23. .02 213 NEOPRENE 093 117 4.00 23. .02 213 138 117 > 8.00 23. .03 213 139 117 > 8.00 23. .02 213 PE 076 117 8.00 23. .01 213 PVC 049 117 .08 23. .01 213 SARANEX 061 117 > 8.00 23. .01 213 VITON 145 117 > 8.00 23. .01 213 VITON/NEOPRENE 111 117 > 8.00 23. .02 213 Diall.yamine 001240270 BUTYL 014 118 3.33 90.18 21. .09 323 PV ALCOHOL 004 100 7.08 20.04 23. .08 323 PVC 007 100 .02 2,364.72 22. .02 323 VITON 009 118 4.62 19. .03 323 1,3 -0 iaminopropane C01097620 BUTYL 014 118 8.00 .02 22. .06 323 NATURAL RUBBER 001 250 .05 440.88 25. .02 323 NEOPRENE 018 100 4.53 33.40 23. .05 323 PVC 007 100 .11 103.54 21. .02 323 Di -n-amyt amine 020509220 NEOPRENE 018 100 2.15 110.22 16. .05 323 NITRILE 019 100 8.00 .02 20. .04 323 PVC 007 100 .12 280.56 13. .02 323 VITON 009 118 > 8.00 .02 16. .03 323 Dibutylamine 001119220 NITRILE 019 100 > 8.00 .02 24. .04 323 PV ALCOHOL 102 100 8.00 .02 23. .08 323 PVC 007 100 .05 741.48 20. .02 323 VITON 009 118 8.00 .02 20. .03 323 DichLoroacetyl Chloride 000793670 BUTYL 014 118 3.92 72.14 23. .09 323 PV ALCOHOL 102 100 3.47 23. .07 323 PVC 003 100 .03 438.88 23. .02 323 VITON 009 118 > 8.00 23. .03 323 Di th orobenzene 253212260 CPE 070 UNK .65 23. .05 004 2D ich1o:abenzerie DCO 5 0i0 NITRILE 005 229 .33 1,015.36 23. .11 210 019 120 .63 1,140.61 23. .04 210 VITON 009 118 4.00 23. .03 210 - Ci .h orobenzene NITRILE 005 229 .28 1,130.59 23. .11 210 019 120 .50 1,157.31 23. .04 210 VITON 009 118 4.00 23. .03 210 A- 24 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM Dichtorobromomethane 000752740 BUTYL 014 118 .68 1,897.80 23. .07 323 PVC 007 100 .02 6,943.86 23. .02 323 VITON 009 118 7.83 .37 23. .03 323 VITON/BUTYL 100 102 1.78 .02 23. .08 323 1,4Dichtoro-2-butene 001105760 BUTYL 064 UNK > 24.00 23. .07 334 CPE 060 UNK .58 400.80 23. .05 334 070 UNK .75 23. .05 004 NEOPRENE 002 UNK 1.10 22. .12 333 .77 22. .10 333 .22 22. .08 333 .17 22. .07 333 .57 118.24 22. .11 333 .36 51.10 22. .08. 333 .45 31.06. 23. .10 335 .68 27.05 23. .12 335 .80 27.05 23. .14 335 018 UNK .49 126.25 22. .05 333 .37 22. .05 333 .35 22. .05 333 .26 22. .04 333 .23 41.08 22. .05 333 .30 38.08 23. .04 335 031 UNK 1.38 80.16 23. .14 334 .97 80.16 23. .13 334 1.23 121.24 23. .13 334 081 UNK 1.97 101.20 23. •15 335 3.35 40.08 23. .18 335 2.97 41.08 23. .20 335 1.60 121.24 23. .14 335 .92 113.23 23. .14 335 NITRILE 019 UNK .43 156.31 23. .04 335 .33 22. O4 333 .27 22. .04 333 .33 22. .04 333 .44 156.31 22. .04 333 078 UNK .04 330.66 23. .03 334 PE 006 . UNK > 24.00 23. .01 334 075 UNK .04 33.07 23. .03 334 076 127 1.25 23. 104 UNK > 24.00 23. .01 334 PV ALCOHOL 004 UNK 83.33 22. .09 333 PVC 007 UNK .37 22. .11 333 .58 72.14 22. .11 333 .52 108.22 22. .10 333 .58 87.17 22. .11 333 .60 22. .12 333 .58 31.06 23. .10 335 .50 30.06 23. .11 335 049 UNK .10 38ü.76 23. .05 3.4 A-25 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST cis-DichLoroethytene 001565920 BUTYL 1 ,2-Dichtoroethytene 005405900 NITRILE trans-1,2DichLoroethytene 001566050 BUTYL PV ALCOHOL > 5.70 > 3.00 .12 .23 .01 .95 781.56 29. .50 23. 841.68 23. 50.10 23. 23. .05 204 480.96 23. .05 204 23. .05 004 .02 23. .05 303 Dichtoropropane (aLL isomers) 266381970 CPE TEFLON 070 UNK 069 510 .60 > 3.10 23. .05 006 .02 23. .05 303 D ichLoropropane-D I chLoropropene 080031980 TEFLON 069 510 3.00 .02 23. .05 303 2,3 DichLoro1-propene 000788860 BUTYL PV ALCOHOL PVC VITON BREAKTHROUGH TIME HOURS CHEMICAL NAME! RESISTANT CASNO MATERIAL 001105760 PVC SARANEX VITON DichLoroethane 013002160 TEFLON PERMEATION RATE TEMP THICKNESS REF UG!CM**2,IMIN DEC C CM HUM .05 2.87 .06 .09 .13 .02 6.43 2.73 > ‘24.00 > 8.30 > 24.00 370.74 23. 144.29 23. 400.80 23. 250.50 23. 330.66 23. 430.86 23. 81.16 23. 122.24 23 23. 23. 23. .02 23. .02 25. 2,925.84 23. 3,547.08 23. 3,316.62 23. 30.06 23. PV ALCOHOL PVC VITON PRODUCT VENDOR DESC CODE 049 UNK 053 UNK 077 ‘‘ UNK 083 UNK 061 UNK 009 UNK 090 UNK 069 510 014 118 004 100 007 100 009 118 019 ‘ 100 004 100 007 ‘ 100 009 118 014 118 .13 004 100 ‘ 2.63 007 100 .02 009 118 1.18 060 113 1.20 1.45 070 LiNK 1.33 069 510 > 3.00 .32 .08 .02 1.68 .04 334 .20 334 .03 334 .05 334 .05 334 .02 334 .26 335 .20 335 .02 334 .03 335 .02 334 .05’ ‘ 303 .05 303 .07 323 .05 ‘ 323 .02 323 .03 323 .04 323 .04 323 .02 323 .03 323 .06 323 .09 323 .02 323 .03 323 PV ALCOHOL PVC VITON PVC VITON 2,2’-Dichtoroethyt Ether 001114440 CPE TEFLON 14,739.42 1,142.28 6,262.50 20.04 23. 23. 23. 23. 014 118 1.90 102 100 > 8.00 < .02 23. .09 323 007 ‘ 100 .02 5,330.64 23. .02 323 009 118 > 8.00 < .02 23. .03 323 A- 26 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST 014 118 019 118 102 100 009 118 > 8.00 8.00 > 8.00 > 8.00 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MI N TEMP THICKNESS REF DEG C CM NUM 320.64 .02 6,513.00 .02 23. 23. 23. 23. 014 102 007 009 014 018 019 069 009 014 001 125 019 .07 323 .07 323 .02 323 .03 323 118 100 100 118 118 100 100 510 118 118 103 103 100 1.30 > 8.00 .02 8.00 > 8.00 > 8.00 > 8.00 > 3.00 > 8.00 .78 24. .09 323 22. .05 323 26. .04 323 .02 23. .05 303 27. .03 323 .75 90.18 CHEMICAL NAME! RESISTANT CASNO MATERIAL 1,3-Dichtoropropene 005427560 BUTYL PV ALCOHOL PVC VITON Diethanotamine 001114220 BUTYL NEOPRENE NITRILE TEFLON VITON Diethytamine 001098970 BUTYL NATURAL RUBBER NEOPRENE NITRILE PE PVC SARANEX SILVER SHIELD VITON VITONICHLOROBUTYL DiethytaminoethanoL 001003780 BUTYL NITRILE PV ALCOHOL VITON Diethytenetriamine 001114000 BUTYL NEOPRENE PVC VITON Di isobutytamine 001109630 NEOPRENE NITRILE PV ALCOHOL VI TON Diisobutyl. Ketone 001088380 NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC .20 .08 .02 103 076 100 007 100. 103 061 127 122 118 009 118 112 113 460.92 23. .09 323 534.40 23. 045 396.79. 23. 045 • 901.80 23. .06 107 1,332.66 24. .04 323 583.16 23. 045 90.18 . 901.80 23. 107 3,707.40. .24. .02 323 414.83 23. 045 .73 38.08 23. 104 > 8.00 .58 8,537.04 23. 20. .01 .03 227 323 .45 - .50 25. .04 302 .02 22. .07 323 .02 22. .04 323 .02 23. .09 323 .02 22. .03 323 014 118 018 100 007 100 009 118 .02 .02 3.01 .02 24. .08 323 22. .05 323 22. .02 323 23. .03 323 018 019 102 009 001 002 005 019 057 > 8.00 > 8.00 .63 > 8.00 .87 > 8.00 > . 8.00 > 8.00 .25 .25 4.75 2.00 90.18 1.25 100 100 100 118 210 210 210 100 210 138.28 22. .05 323 20. .04 323 23. .08 323 22. .02 323 583.16 450.90 30.06 901.80. 3.01 23. 23. 23. 23. 23. 080 080 080 .06 107 080 A- 27 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM MUM 001088380 PE 076 100 .08 9.02 - 90.18 23. 107 PV ALCOHOL 004 100 > 6.00 .90 23. 107 PVC 007 210 1.00 8.42 23. 080 Diisobutyl Ketone, >70% 001088383 BUTYL 014 118 3.27 247.69 23. .04 323 3.30 247.69 23. .04 227 NITRILE 019 118 2.93 294.59 23. .03 323 3.00 293.99 23. .03 227 PV ALCOHOL 102 100 > 16.00 23. .03 323 SILVER SHIELD 122 118 > 6.00 23. .01 227 VITON 009 118 1.13 544.69 23. .03 323 1.20 544.69 23. .02 227 Diisopropylamine 001081890 NEOPRENE 018 100 .67 450.90 12. .05 323 NITRILE 019 100 3.25 90.18 10. .04 323 PvC 007 100 .03 1,322.64 11. .02 323 TEFLON 069 510 > 4.50 .02 24. .05 303 VITON 009 118 > 8.00 .02 12. .03 323 N,N-Dirnethy [ acetarnide 001271950 CPE 070 UNK .67 23. .05 004 SARANEX 061 127 1.07 2.00 23. 104 D methyLamine 001244030 BUTYL 014 118 > 8.00 .02 22. .06 323 NATURAL RUBBER 001 250 .03 80.16 20. .02 323 NEOPRENE 018 100 > 8.00 .02 22. .05 323 PV ALCOHOL 102 100 .28 40.08 23. .07 323 PVC 007 100 .10 20.04 20. .02 323 D irnethylaminopropytamine 001095570 BUTYL 014 118 > 8.00 .02 16. .09 323 NATURAL RUBBER 001 250 .01 2,114.22 16. .02 323 NEOPRENE 018 100 .48 470.94 20. .05 323 PVC 077 100 .03 2,189.37 20. .02 323 atpha,atpha-Dimethytbenzyl Hydroperoxide 000801590 TEFLON 069 510 > 3.50 .02 23. .05 303 Dimethylbutylamine 001080980 BUTYL 014 118 1.68 320.64 24. .06 323 NITRILE 019 100 1.35 711.42 19. .04 323 PV ALCOHOL 102 100 .33 140.28 23. .08 323 PVC 007 100 .05 2,575.14 21. .02 323 Dimethytethanotamine - 001080100 BUTYL 014 118 > 8.00 .02 12. .09 323 NATURAL RUBBER 001 250 .08 100.20 19. .02 323 NEOPRENE 018 100 3.92 30.06 21. .05 323 NITRILE 019 100 > 8.00 .02 9. .04 323 A- 28 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL .NAME/ RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM O imethytformarnide 000681220 BUTYL NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC 012 UNK 22.00 < .02 25. .04 273 23.00 < .02 . 25. .04 273 > 71.00 < .02 25. .06 273 > 71.00 < .02 25. .06 273 > 24.00 < .02 25. .04 273 > 24.00 < .02 25. .04 273 > 24.00 < .02 25. .06 273 > 24.00 < .02 25. .06 273 > 6.00 1.20 25. .04 273 > > > 6.00 7.00 7.00 - < < 1.20 -1,669.98 -1,669.98 25. 25. 25. .04 .06 .06 273 273 273 014 118 > 8.00 23. .04 323 > 8.00 23. .04 227 107 UNK > 8.00 25. .04 149 > > 8.00 8.00. • 25. 25. .04 .04 149 149 001 210 1.00 721.44 23. 080 017 100 .50 90.18 - 901.80 23. .05 107 026 121 .62 66.13 23. .05 237 002 100 1.00 9.02 . 90.18 23. 107 210 .13 96 19 23. 080 018 100 .85 66.13 23. .05 323 .17 9.02 . 90.18 23. .04 107 UNK 3.00 1.20 25. .04 273 > 3.50 5.50 < 1.20 .02 25. 25. .04 .06 273 273 > 6.00 < .02 25. .06 273 031 UNK .02 . 18.04 25. .04 149 .57 47.09 25. .04 149 1.10 74.15 25. .04 149 .10 20.04 25. .04 149 125 103 54.11 23. 045 005 120 .58 54.11 23. .06 236 210 1.00 120.24 23. 080 019 103 114.23 23. 045 118 .15 .22 > 90.18 90.18 23. 23. .04 .04 323 227 UNK 3.50 10.82 25. .04 273 3.50 12.02 25. .04 273 > 5.00 10.82 25. . .06 273 > 5.00 1.50 10.22 132.26 25. 23. .06 273 080 .50 < .90 23. 107 .08 .37 .33 900.80 1,057.78 48.10 25. 25. 25. .07 .07 .07 149 149 149 . .12 2,191.37 25. .07 149 102 100 .33 78.16 23. .04 323 .20 24.65 23. .03 323 007 210 1.00 138.28 23. 080 057 076 035 210 100 UNK A- 29 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 000681220 SILVER SHIELD TEFLON VITON VI TON/CHLOROBUTYL PRODUCT VENDOR DESC CODE 122 118 069 510 009 , 118 112 113 BREAKTHROUGH TIME HOURS > 8.00 > 11.20 .13 .13 > 3.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 23. .01 227 .02 23. .05 303 39.08 23. , .03 323 39.08 23. .02 227 25. .04 302 PV ALCOHOL PVC 034 LINK 052 .,, ,. 205 060 113 017 , 100 101 110 008 114 002 100 053 189 054 189 077 168 212 009 118 > 1.50 > 1.50’ 1.50 27.00 1.50 .50 .17 .23 .06 .18 .06 .10 .22 .03 .15 .15 1.12 > 1.50 - .63 .67 .15 .23 .10 .12, .13 .22 .68 .03 .47 .58 .28 .05 .16 .33 .53 .02 .17 .08 .20 23. .03 001 23. .04 001 23. .08 001 2.91 22. .08 078 23. .05 001 23. .05 001 23. .04 001 23. .05 001 .02 001 .04 001 .02 001 .05 001 .05 001 .04 001 .04 001 .04 001 .12 001 .13 001 .05 001 .08 078 .04 001 .04 001 .03 001 .03 001 .09 001 .05 001 .10 001 .03 001 .09 001 .11 001 .10 001 .06 001 .07 001 .05 001 .05 001 .05 001’ .04 078 .03 001’ .03 , 001 DimethyL Sulfoxide 000676850 CPE > 3.00 1.33 1.50 . 2.00 > 1.00 1.00 25. 721.44 23. 25. 10.02 25. .90 . 9.02 23. .07 302 080 .02 276 .03 222 .05 107 1,1-Dimethythydrazjrie (DimethyLhydrazine,unsym-) 000571470 BUTYL , 014 ‘118 CHLOROBUTYL CPE NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NI TR I LE 018 031 019 100 UNK 100 > 23.00 .42 - .08 118 004 - 100 003 120 007 100 23. 23. 23. 23. 23. 23. 23. 23. 23. 23.. 23. 450.90 22. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 190.38 22. 23. 23. VITON NATURAL RUBBER 060 113 001 210 - UNK 017 100 A-30 ------- D i -n-octyt Phthatate SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION T ST 058 100 076 100 077 100 • .42 .08 .42 > 6.00 23. 23. 23. .90 23. 1 ,4-Dioxane (Diethytene Dioxide,1,4) 001239110 BUTYL NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE .08 90.18 .04 .20 .17 107 107 107 107 23. .07 323 23. .04 227 420.84 25. .03 222 901.80 23. .05 107 801.60 25. .02 222 340;68 25. .05 222 280.56 25. .05 222 .06 222 .05 222 .05 222 .08 222 .07 222 .05 323 BREAKTHROUGH TIME HOURS > 1.00 > 1.00 1.00 4.00 > 8.00 PRODUCT VENDOR DESC. CODE 017 120 203 008 114 002 100 120 210 UNK 018 100 120 005 210 019 100 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM - NUM 10.02 25. .02 222 10.02 25. .05 222 10.02 25. .06 222 25. .05 276 25. .05 276 > 3.00 9.02 90.18 23. > 1.00 10.02 25. CHEMICAL NAME! RESISTANT CASNO MATERIAL 000676850 NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE VI TONICHLOROBUTYL DimethyLvinytchioride 005133710 . NITRILE PV ALCOHOL PVC VITON NITRILE+PVC PE PVC 057 006 003 191 210 100 120 107 .07 222 080 .05 186 .04 107 .05 222 .05 222 .03 222 080 .04 222 .04 276 .06 107 .03 222 080 .01 222 .01 222 .03 222 .02 222 107 6.00 1.77 > 6.00 > 1.00 1.00 > 1.00 4.33 > 1.00 2.00 . 3.00 > 4.00 .47 1.33 > 1.00 .05 .70 .57 1.17 .83 > 3.00 .15 1.18 .02 2.22 .02 23. 23. .90 23. 10.02 25. 10.02 25. 10.02 25. .5.41 23. 10.02 25. 25. .90 - 9.02 23. 350.70 25. 4.81 23. 10.02 25; 380.76 25. 300.60 25. 320.64 25. .90 • 9.02 23. 6.01 23. 354.71 23. 6.01 23.. 420.84 23.: 24.05 23. 007 100 210 112 113 019 100 004 100 003 100 009 118 080 25. .04 302 001178400 NITRILE+PVC PE PVC .05 323 .08 323 .02 323 .04 323 NATURAL RUBBER 014 118 20.00 > 20.00 017 100 • .15. 120 502 504 026 102 008 114 002 100 120 018 100 .45 .28 .30 .14 .09 .27 150.30 25. 340.68 25. 220.44 25. 220.44 25. 330.66 25. 560.92 23. A- 31 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Dipropytamine 001428470 TEFLON 1,430.86 1,430.86 2,703.60 23. .05 323 23. .04 227 23. .04 323 23. .03 323 23. .01 227 23. .02 323 23. .02 227 23. .04 291 23. .04 291 23. .04 291 23. .04 291 .07 323 .07 323 .08 078 .02 323 .02 323 BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM PRODUCT VENDOR DESC CODE 018 118 120 125 103 019 100 103 118 503 006 100 505 076 100 102 100 003 120 CHEMICAL NAME! RESISTANT CASNO MATERIAL 001239110 NEOPRENE NITRILE PE PV ALCOHOL PVC SARANEX SILVER SHIELD TEFLON VITON 150.30 25’. 300.60 25. 240.48 25. 370.74 25. 551.10 25. 360.72 23. 861.72 25. 3.01 25. 821.64 25. 2,068.13 23. 463.53 23. 463.53 23. 711.42 25. 300.60 25. 60.12 25. .90 ‘ 9.02 23. 23. 3,707.40 25. 4,008.00 25. 1,503.00 25. 1,102.20 25. 5,010.00 25 3,807.60 25. 4,008.00 25. 402.80 23. 17.43 23. 23. .02 23. 161.12 23. 161.12 23. .08 222 .05 222 .07 222 .05 222 .03 222 045 .04 222 .06 222 .04 222 045 .04 323 .04 227 .03 222 .01 222 .01 222 107 .03 323 .01 222 .01 222 .03 222 .02 222 .01 222 .01 222 .02 222 045 104 .01 227, .05 303 .03 323 .02 227 500 501 103 127 ‘118 510 118 510 007 061 122 ‘069 009 069 1.78 .73 .73 .47 .25 .42 1.05 .45 .40 .47 .28 .02 .17 .05 > 16.00 .03 .01 .11 .06 .02 .02 .02 .83 > 8.00 > 3.20 .38 .38 > 3.00 2.22 2.20 1.00 > 18.00 > 8.00 > 17.00 > 17.00 24.00 24.00 24.00 24.00 > 8.00 > 8.00’ 79.00 .02 .02 014 , 118 Divinyt Benzene 013217400 BUfl’L NITRILE PV ALCOHOL’ ‘SILVER SHIELD VITON Epichtorohydrin 001068980 BUTYL .02 23. .05 303 019 102 122 009’ 100 100 118 118 014 118 034 ‘ UNK NATURAL RUBBER 001 250 < -1,669.98 ‘ 23. < -1,669.98 23. .20 22. 5O4 34 23. 504.34 , 23. A- 32 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT. CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM Ethanotamine (Aminoethanot,2) 001414350 BUTYL NATURAL RUBBER NITRILE NITRILE+PVC PE PV ALCOHOL PVC 014 118 001 210 017 100 002 100 210 018 100 > 8.00 4.50 3.50 > 6.00 6.00 >• 6.00 > 8.00 6.00 > 6.00 5.00 > 6.00 > 6.00 2.50 > 6.00 > 8.00 2.00 > 6.00 > 6.00 •> . 8.00 .90 - .04 107 20. .05 323 080 .06 107 080 107 107 107 107 .02 323 7.82 23. 080 035 102 UNK 100 .08 .05 PV ALCOHOL SARANEX TEFLON VITON 001068980 NATURAL RUBBER 017 UNK .05 130.26 23. .02 291 .06 138.28 23. .02 291 NEOPRENE 018 100 .33 362.72 23. .04 291 : .25 314.63 23. .04 291 031 UNK 1.00 - 1.33 110.22 22. .08 078 NITRILE PE 020 006 503 100 . .42 .33 .05 .05 1,252.50 1,152.30 9.45 9.74 23. 23. 23. 23 .04 .04 .01 .01 291 291 291 291 130.26 22. .01 078 .02 127.25 105.21 23. .23. ..05 .05 291 291 5.82 .30 23. .07 323 5.82 .30 23. .07 323 061 127 1.00 1.00 3.32 3.44 23. 23. • .02 .02 291 291 . .95 7.00 52.30 .02 23. 23. . .01 104 291 7.00 .02 23. .01 291 > 3.40 < .02 23. .05 303 . 1.00 51.20 23. .02 291 1.00 51.90 23. .02 291 1.00 50.70 23. .02 291 2.05 2.05 6.13 6.13 23. 23. .03 .03 323 323 1,2-Epoxybutane 001068870 BUTYL 014 118 .75 20.04 23. .06 323 • NEOPRENE PV ALCOHOL VITON 018 004 009 100 100 118 .07 8.00 .03 < 20.04 .02 20.04 23. 23. 23. .05 .04 .03 323 323 323 036 069 009 214 510 118 NEOPRENE 26. 6.61 23. 9.02 23. .90 23. .02 23. 90 23. .07 323 080 .05 107 107 080 005 019 057 058 076 004 007 210 100 210 100 100 100 100 • .02 23. .90 23. 4.21 23. 23. 23. .90 - 9.02 23. .9O 23. 25. VITON 210 077 100 009 118 23. 107 23. • 107 22. .05 323 A- 33 ------- SUMMARYOF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO RESISTANT MATERIAL • PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MIN TEMP THICKNESS REF DEC C CM NUM Ethyt Acrytate 001408850 PE PV ALCOHOL PVC 110 117 060 113 UNK 070 UNK 093 117 138 117 139 117 076 117 102 100 003 100 049 , 117 .02 > 8.00 .67 .88 .67 1.00 1.08 - ‘1.17 .50 1.42 .40 .08 .08 .25 .08 > 8.00 .03 .05 23. 23.. 23. 23. 23. 23. 1,040.08 23. 23. .05 004 .02 213 .03 213 .02 213 .01 213 .08 323 .02 323 .01 213 EthyL Acetate 001417860 BUTYL 014 118 7.60 CPE 060 113’ .97 - 1.17 NATURAL RUBBER 001 210 .18 017 100 ‘ .08 NEOPRENE 002 100 .33 210 .20 ‘ 018 100 .25 NITRILE 005 210 .50 019 118 .13 NITRILE+PVC 057 210 .50 PE 076 100 .07 PV ALCOHOL 004 100 > 6.00 PVC 007 ‘ 210 .33 SARANEX 061 127 .60 , SILVER SHIELD TEFLON 122 069 118 510 > > 6.00 3.10 ‘ VITON/CHLOROBUTYL . 112 > .33 . 4.30 .66 EthyL Cettosotve’ (Ethoxyethanot, 2) 001108050 BUTYL .04 227 .07 302 080 ‘.05 107 107 080 .04 107 080 .04 227 080 107 ‘107 080 104 .01 227 .05 303 .05 303 .04 302 20.44 23. 25. 54.11 23. 9.02 . 90.18 23. 9.02 - 90.18 23. 48.10 23. 9.02 90.18 23. 66.13 23. 871.74 23 48.10 23. 9.02 - 90.18 23. .90 23. 78.16: 23. 6.61 23. 23. .02 23. .02 24. 25. 1.20 23. 72.14 23. 49.30 23. 18.64 23. 6.01 23. 56.51 23. 54.11 23. 132.26 23. 162.32 23. 6.01 23. 113 014 118 001 103 250 506 018 100 125 103 019 100 103 102 100 007 100 103 250 250 014 • 118 064 117 23. .06 323 23. .08 323 > 8.00 > 8.00 .02 .01 4.08 1.53 .05 .07 NATURAL RUBBER NEOPRENE NITRILE PV ALCOHOL PVC BUTYL BUTYL/NEOPRENE CPE NEOPRENE 045 .02 323 .01 323 .06 323 045 .04 323 045 .08 323 .02 323 045 1,040.08 23. .02 323 23. .09 323 23. .02 213 23. • .01 213 23. .02 213 23. .02 213 25. .07 302 23. 142 23. 142 A- 34 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 001408850 SARANEX 061 117 1.33 23. .01 213 TEFLON 069 510 > 17.00 .02 23. .05 303 VITON 145 117 .08 23. .01 213 VITON/CHLOROBUTYL 112 113 .23 - ‘.53 25. .04 302 UNK > 3.00 23. 142 VITON/NEOPRENE 111 117 .20 23. , .02 213 Ethyl Alcohol (EthanoL) 000641750 NATURAL RUBBER 001 210 1.50 6.01 23. 080 017 100 .47 4.01 25. .03 222 .50 .90 - 9.02 23. .05 107 120 .20 14.03 25. .02 222 • 502 1.00 4.01 25. .05 222 504 1.00 4.01 25. .05 222 • ‘ 1.00 4.01 25. .06 222 NEOP+NAT RUBBER 026 121 .37 .33 ‘ 23. .05 237 NEOP/NAT RUBBER 008 114 1.00 4.01 25. .05 222 NEOPRENE 002 100 3.00 .90 - ?.02 23. 107 1.00 4.01 25. .08 222 • 120 1.00 4.01 25. .07 ‘222 210 2.00 3.01 23. 080 018 100 1.50 .90 - 9.02 23. .04 107 118 1.00 • 4.01 25. .08 222 120 ‘ • > 1.00 4.01 25. .05 222 1.00 4.01 25. .07 222 1.00 4.01 25; .05 222 1.00 4.01 25. .03 222 031’ 511 - .82 - 1.80 23. 323 NITRILE ‘ 005 210 ‘ 6.00 .02 23. 080 019 100 1.00 4.01 25. .04 222 4.00 ‘.90 - 9 02 23. .06 107 1.00 4.01 25. .06 222 1.00 • 4.01’ 25. .04 222 503 1.00 4.01 25. .03 222 NITRILE+PVC 057 210 • 6.00 .02 23. 080 058 100 .25 .90 - 9.02 23. 107 PE 006 505 1.00 • 4.01 25. .01 222 076 100 .05 > 9,018.00 23. 107 PV ALCOHOL 004 100 1.67 55.11 23. 123 1.67 5.51 21. 124 PVC 003 120 .05 ‘ 43.09 25. .01 222 .08 37.07 25. ‘.01 222 .33 28.06 25.’ .03 222 .18 43.09 25. .02 222 500 .06 28.06 25. 01 222 501 .05 34.07 25. .01 222 .03 57.11 25. .02 222 007 100 1.00 .90 - 9.02 23. 107 210 2.50 6.01 23. 080 • 077 100 .25 .90 23. 107 .50 .90 - 9.02 23. , 107 TEFLON , 069 510 > 3.00 .02 23. .05 303 A - 35 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO RESISTANT MATER IAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/M IN TEMP THICKWESS REF DEG C CM NUM Ethyl Benzene 001004140 Ethyl n butyt amine 133606390 PVC VITON 019 100 102 100 007 100 009 118 1.22 6.72 .06 3.80 23. .08 323 .02 23. O5 303 24. ‘.04 323 23. .09 323 24. .02 323 23. .03 323 EthyL Cyanide (Propionitrite) 001071200 BUTYL NATURAL RUBBER PV ALCOHOL PVC 014 118 001 506 102 100 003 100 .40 .01 > 8.00 .01 .06 323 .01 323 .03 323 .02 323 Ethylene Chlorohydrin (Chtároethanol) 001070730 BUTYL NEOPRENE, PV ALCOHOL VITON (Diaminoethane,1,2) BUTYL CPE NATURAL RUBBER NEOPRENE PE PVC SARANEX TEFLON 014 118 060 113 001 250 018 100 076 127 007 100 061 127 069 510’ > 8 O0 2.00 2.67 .08 6.65 .25 .17 > 8.00 > 3.20 36.07 501.00 20.04 10.22 80.16 .02 .02 014 019 122 069 118 118 118 510 Ethylamine, 30-70% 000750472 BUTYL ‘WITRILE SILVER SHIELD TEFLON PV ALCOHOL TEFLON NEOPRENE PV ALCOHOL PVC VITON NITRILE PV ALCOHOL < -1,669.98 180.96’ 36.07 .02 Ethyl Bromide 000749640 102 100 069 510 23. .04 227 23. .04 227 23. .01 227 23. .05 303 > 12.00 •1.10 ‘.47 > 3.00 .55 > ‘3.00 .07 1.07 .02 1.43 018 102. 003 009 100 100 100 118 23. .04, 23. .08 23. .02 23. .04 323 323 323 323 1,322.64 .42 2,104.20 30.06 210.42 20.04 2,648.62 1,482.96 167.73 23. 79.36 23. 23. 18.04 23. 014 118 018 100 102 100 009 118 Ethylenediamine 001071530 > 8.00 ‘4.98 1.85 > 8.00 .02 .70 20.04 .112 23. .06 323 23. .05 323 23. .09 323 23. .05 323 Ethylene Dibromide (Dibromoethane,1,2) 001069340 BUTYL .02 18. .07 323 23. ‘, .05 204 23. .05 204 20. , .01 323 18. .05 323 23. 104 16. .02 323 23. 104 23. .05 303 014 118 064 117 1 .70 1 .83 3.33 .55 .38 .38 75.15 79.16 36.07 23. 23. 23. 23. 23. 23. .04 291 .04 291 .07 323 .02 213 .01 213 .02 213 A-36 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CPE NATURAL RUBBER UNK 064 UNK 070 UNK 001 250 017 100 • 120 502 504 UNK 026 102 008 114 002 100 120 018 118 120 2.98 2.90 2.33 1.17 .25 .01 .01 .02 .08 .06 .16 .03 .08 .01 .03 04 .70 .27 531.06 23. .06 •323 318.64 23. .04 227 23. .06 326 23. .04 326 .05 004 .02 323 .03 222 .02 222 .05 222 .05 222 .06 222, 23. ‘ .02 326 25. .05 222 25. .05 222 25. .08 222 25. .07 222 25. .08 222 25. .05 222 RESISTANT MATERIAL PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF DESC CODE HOURS UG/CM**2/MIN DEG C CM NUN CHEMICAL NAME! CASNO 001069340 EthyLene Dichtoride (Dichtoroethane,1,2) 001070620 BUTYL 014 BUTYL/NEOPRENE 110 117 23. .02 < .08 213 CPE 070 UNK .73 23. .05 004 NATURAL RUBBER 017 UNK < .02 > 731.46 23. .02 291 . . < .02 > 731.46 23. .02. 291 NEOPRENE 018 100 .13 > 731.46 23. .04 291 • .20 > 731.46 23. .04 291 093 117 < .33 23. .02 213 , 125 139 103 117 .08 354.71 23. 23. .02 045 213 NITRILE 019 103 583.16 23. 045 • 020 503 • .58 > 731.46 23. .04 291 .45 . > 731.46 23. .04 291 PE 006 100 < .03 158.32 23. .01 291 < .03 141.28 23. .01 291 076 117 .75 23. .01 213 PVALCOH OL 102 100 > 24.00 23. .05 291 > 24.00 23. .05 291 . > 8.00 23. .08 323 PVC 007 100 .03 1,406.81 23. .02 323 • 103 294.59 23. 045 SARANEX 049 061 117 117 .12 .55 . ‘ ‘ ‘23. 23. .01 .01 213 213 . 127 .17 49.10 ‘23. .02 291 . .13 49.10 23. .02 291’ TEFLON 036 214 1.00 23. .01 291 > 24.00 23. .01 291 . 069 510 > > 24.00 3.40 < • .02’ 23. 23. .01 .05 291 303 . VITON • , 009 118 . > > 24.00 24.00 23. 23. • .02 .02 291 ‘291 • > 8.00 23. .03 323 VITON/NEOPRENE 145. • 111 117 117 ‘ .58 1.08 • 23. 23. .01 .02 213 213 118 NEOP+NAT RUBBER WEOP/NAT RUBBER NEOPRENE 23. 350.70 23. 1,603.20 25. 3,106.20 25. 1,302.60 25. 2,505.00 25 801 .60 25. 1,302.60 1,302.60 701.40 801.60 • 501.00 701 .40 A- 37 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATER I AL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UGICM**2/MIN DEC C CM NUM 001070620 NEOPRENE SILVER SHIELD TEFLON NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE UNK 019 100 118 503 UNK 020 UNK 006 100 505 042 UNK 076 100 004 100 102 100 UNK 003 120 500 501 122 118 036 UNK 044 UNK 009 118 UNK 026 102 121 008 114 002 100 210 018 100 118 120 .47 .14 .06 .33 .11 .28 .12 .13 .08 .04 .04 .02 .09 .04 .05 > 3.00 > 8.00 > 8.00 5.50 .37 .01 .01 .03 .02 .01 .01 .01 > 6.00 > 24.00 1.50 6.90 > 8.00 13.67 6.00 1.00 > 6.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > 8.00 > 1.00 > 6.00 > 1.00 6.00 > 6.00 > 1.00 >• 1.00 > 1.00 > 1.00 .90 .90 - 3,807.60 2,605.20 3,907.80 1,869.73 3,907.80 23. 23. 23. • 11,022.00 25. 9,719.40 25. 4,509.00 25. 6,913.80 25. 25. 13,026.00 25. ‘7,815.60 25. 23. 23. 23. 4.88 23. .02 23. 23. .02 23. <• 10.02 25. .90 23. < 10.02 25. 10.02 25. 10.02 25. 10.02 25. 10.02 25. .02 23. 10.02 25. .90 23. 10.02 25. .02 23. .90 23. 10.02 25. 10.02 25. 10.02 25. 10.02 25. .02 227 .03 323 .03 326 080 .03 222 .05 107 .05 237 .05 222 107 .08 222 .04 .08 .07 222 .05 222 018 120 NITRILE PE PV ALCOHOL PVC 801.60 25. .07 222 1,002.00 25. .05 222 1,803.60 25. .03 222 23. .06 326 25. .04 222 25. .06 222 25. .04 222 23. .04 227 25. .03 222 23. .02 326 23. .03 326 10.02 25. .01 222 10.02 25. .01 222 23. .01 326 9.02 23. 107 9.02 23. 107 .02 23. .03 323 .04 323 .05 • 323 .04 326 .01 222 .01. 222 .03 222 .02 222 .01 222 .01 222 .02 222 .01 227 .01 326 .01 326 VITON Ethylene Glycot 001072110 NATURAL RUBBER 001 210 017 100 120 502 504 .02 .05 .05 .06 .05 222 222 222 222 222 080 107 222 222 A- 38 ------- Ethylene Oxide (Oxirane) 000752180 NITRILE SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ CASNO 001072110 BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM RESISTANT MATERIAL NEOPRENE NITRILE NI TR I LE+PVC PE PV ALCOHOL PVC TEFLON 25. 23. 25. 23. 25. 25. 23. 23. 25. 25. .23. 23. 25. 25. 25. 25. 25. 25. 25. 23. 23. 23. 23. 23. .03 222 080 .04 222 .06 107 .04 222 .03 222 080 107 .01 222 .01 222 107 107 .01 222 .01 222 .03 222 .02 222 .01 222 .01 222 .02 222 107 080 107 107 .05 303 PRODUCT VENDOR DESC CODE 018 120 005 210 019 100 503 057 210 058 100 006 100 505 076 100 004 100 003 120 500 501 007 100 210 077 100 069 510 019 103 034 UNK 010 - 120 014 118 001 210 002 100 210 018 100 125 103 005 210 019 100 103 118 057 210 076 100 004 100 102 100 007 210 122 118 069 510 009 118 10.02 .02 10.02 .90 10.02 10.02 .02 .90 10.02 .10 .90 .90 - 9.02 10.02 10.02 10.02 10.02 10.02 10.02 .90 .02 .90 - 9.02 .90 .02 554.31 1,563.12 9.02 - 90.18 1,232.46 9.02 - 90.18 330.66 84.17 9.02 - 90.18 264.53 131.06 1,863.72 90.18 . 901.80 .90 Ethylenimine 001515640 Ethyl Ether 000602970 > 1.00 6.00 > 1.00 > 6.00 > 1.00 > 1.00 6.00 > 6.00 >- 1.00 > 1.00• > 6.00 2.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > -1.00 > 6.00 6.00 .75 6.00 > 16.80 10.00 . 16.00 .08 .13 .17 .17 .20 .17 2.30 2.00 .23 .42 .03 > 6.00 8.00 .33 > 6.00 3.00 > 3.00 .20 .20 .37 23. 045 4.51 22. .08 078 22. .02 078 (Aziridine) BUTYL NEOPRENE BUTYL NATURAL RUBBER NEOPRENE MITRILE NITR I LE+PVC PE PV ALCOHOL PVC SILVER SHIELD TEFLON VITON 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 2,104.20 23. 23. 23. 23. 23. 23. .04 227 080 107 080 .04 107 045 080 .06 107 045 .04 227 p80 107 107 .04 323 080 .01 227 .05 303 .05 303 .03 323 .02 227- .02 .02 129.26 129.26 A-39 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 000602970 VITON/CHLOR OBUTYL PRODUCT VENDOR DESC CODE 112 113 BREAKTHROUGH TIME HOURS .02 - .17 PERMEATION RATE UG/CM**2/MIN 25. 2-Ethythexanoic Acid 001495750 PVC BUTYL NEOPRENE PV ALCOHOL VI TON 018 100 019 100 003 215 014 118 018 100 102 100 009 118 > 4.00 4.00 > 4.00 > 8.00 > 8.00 > 8.00 > 8.00 23. .05 123 23. .04 123 23. .04 123 23. .07 323 •23. .05 323 23. .09 323 23. .03 323 VI TON 186.37 23. .09 323 23. .08 323 1,902.46 23. .02 323 1,929.85 23. .02 323 36.07 23. .04 323 Ethyl Methacrylate 000976320 BUTYL CPE NITRILE PV ALCOHOL PVC Formaldehyde, <37% (Formalin) 000500000 BUTYL CPE NATURAL RUBBER NITRILE+PVC PE PVC SILVER SHIELD TEFLON VITON 014 118 070 UNK 001 506 017 100 UNK 002 100 018 100 125 103 019 100 103 118 UNK 058 100 076 100 127 003 100 007 100 103 077 100 122 118 069 510 009 118 > 16.00 > 16.00 > 3.00 .20 1.00 .10 2.00 2.00 > 21.00 > 21.00 > 6.00 .50 > 6.00 > 8.00 .07 1.33 -33 6.00 > 600 > 3.00 > 16.00 23. 23. 23. 26. 23. 23. 23. 23. 23. 23. 23. 26. 23. 23. 23. 23. 23. 23. 23. 23. 23. .02 23. 23. .05 004 .02 323 .05 107 .02 148 107 .04 107 045 .06 107 045 .04 323 .04 227 .03 148 107 107 104 .02 323 107 045 107 107 .01 227 .05 303 .02 323 NEOPRENE NITRILE TEMP THICKNESS REF DEG C CM MUM 2-Ethyl-i -Hexanol 001047670 .04 302 Ethyl idéne Dichloride (Dichtoroethane,1,1) 000753430 BUTYL 012 PV- ALCOHOL 004 PVC 003 118 1.52 100 273 100 .02 .03 009 118 2.43 014 118 070 UNK 019 100 102 100 003 100 6.57 .53 .38 > 8.00 .03 12.02 23. .09 323 23. .05 004 186.37 23. .05 323 23. .06 323 84.17 23. .02 323 23. .04 323 - 23. .04 227 NEOPRENE NITRILE .02 .90 - 9.02 3.34 .90 - 9.02 .90 .02 6.00 < .90 .02 .02 .90 - 9.02 .90 .02 .05 .90 - 9.02 .02 9.02 90.18 .90 9.02 A- .40 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Formic Acid (Methanoic Acid) 000641860 PE • PERMEATION RATE •TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 23. .02 227 CHEMICAL NAME/ CASNO RESI STANT MATERIAL 000500000 VITON BREAKTHROUGH TIME HOURS Formic Acid, >70% 000641863 Freon IF 000761310 PRODUCT VENDOR DESC CODE 009 118 > 16.00 076 127 .07 017 100 2.00 026 121 3.20. 002 100 > 6.00 018 100 > 6.00 019 100 4.00 058 100 .50 076 • 100 .20 007 100 > 6.00 077 100 .67 1.25 017 100 .03 23. 104 •23. 12.02 23. 23. 23. 23. • 23. 23. - 23. 23. 23. .05 107 .05 237 107 .04 107 .06 107 107 107 107 107 107 NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PVC NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC 026 008 002 102 121 114 100 120 .04 3,006.00 25. .02 222 502 • .28 821.64 25.. .05 222 504 .27 701.40 25. .05 222 .48 591.18 .25. .06 222 .27 701.40 25. .05 222 .27 474.95 23. .05 237 .27 791.58 25. .05 222 2.00 .90 - 9.02 .23. 107 > 1.00 < 10.02 25. .08 222 018 120 100 118 120 > > > > . > 3.00 4.00 • 1.00 1.00 1.00 1.00 1.00 . • < < < < < < 20.04 .90 10.02 10.02 • 10.02 10.02 10.02 25. 23. 25. 25. 25. 25. 25. .07 222 .04 107 .08 222 .05 .222 .07 222 .05 222 .03 222 . O19 058 006 . 100 503 100 100 505 . . > > > > > > 1.00 6.00 1.00 . 1.00 1.00 .25 .08 1.00 90.18 < < < < < - < 10.02 .90 10.02 10.02 10.02 901.80 10.02 1.00 . 25. 23. 25. 25. 25. 23. 25. 25. .04 222 .06 107 .06 222 .04 222 .03 222 . 107 .01 222 .01 222 076 100 .13 9.02 . 90.18 23. 107 004 100 .50 .90 - 9.02 23. 107 003 120 .04 3,406.80 25. .01 222 . .09 .18 .13 2,204.73 190.38 240.48 25. 25. 25. .01 222 .03 222 - .02 222. 077 500 501 100 .04 .04 .05 .30 9.02 - 2,605.20 3,006.00 1,903.80 90.18 25. 25. 25. 23. .01. 222 .01 222 .02 222 107 A- 41 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST BUTYL NEOPRENE PVC VITON 014 118 018 100 003 100 009 118 > 8.00 > 8.00 1.17 > 8.00 .02 .02 6.01 .02 23. .09 323 23. .05 323 23. .02 323 23. .04 323 CHEMICAL NAME! CASNO PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE DESC CODE HOURS UGJCM**2/MIN RESISTANT MATERIAL PVC NATURAL RUBBER NEOPRENE NITRILE PV ALCOHOL .17 .05 .17 > 6.00 901.80 90.18 901.80 901.80 - 9,018.00 - 901.80 9,018.00 - 9,018.00 .90 1.35 1.89 .02 .33 60.12 .08 2,951.89 138.28 000761310 Freon TMC 577623190 Furan (Furfuran) 001100090 Furfura 000980110 GasoLine 080066190 G Lutara Idehyde 001113080 210 018 005 019 100 210 118 077 100 TEMP DEG C 90.18 23. THICKNESS CM REF NUM 107 1.00 9.02 - 017 100 23.- .05 107 002 .100 23. 107 018 100 23. .04 107 019 100 23. .06 107 004 100 23. 107 BUTYL 014 118 23. .09 323 PV ALCOHOL 102 100 23. .09 323 PVC 003 100 . 23. .02 323 VITON 009 118 23. .05 323 BUTYL 014 118 > 16.00 23. .04 323 , > 16.00 23. .04 227 NATURAL RUBBER 001 210 .25 30.06 23. 080 017 100 . .25 9.02 - 90.18 23. .05 107 NEOPRENE 002 100 2.00 9.02 - 90.18 23. 107 . 18.04 . 23. 080 9.02 - 90.18 23. .04 107 NITRILE 156.31 23. 080 .47 1,591.38 23. 1,593.18 23. .03 .04 323 227 NITRILE+PVC 057 210 . .67 144.29 .23. 080 PE . 076 1.00 • .08 . < .90 23. 107 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 102 100 > 16.00 23. .03 323 PVC . 007 210 1.17 . 108.22 23. 080 SILVER SHIELD 122 118 > 8.00 23. .01 227 TEFLON 069 510 > 1.00 < .02 23. .05 303 VITON 009 118 3.50 88.98 23. .03 323 3.60 88.98 23. . .02 227 BUTYL 064 117 .58 23. .02 213 BPJTYL/NEOPRENE 110 117 .33 23. .02 213 NEOP+NAT RUBBER 026 121 .07 1,076.15 23. .05 237 NITRILE 019 100 > .6.00 < .90 23. .06 107 NITRILE+PVC 058 100 .08 90.18 - 901.80 23. . 107 PE 076 100 .05 90.18 - 901.80 23. 107 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 PVC 077 . 100 . .07 . .08 9.02 90.18 - - 90.18 23. 901.80 23. . 107 107 VITON/NEOPRENE 111 117 > 8.00 23. .02 213 .50 .33 .92 .40 A- 42 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF UGi CM**2!MIN DEG C CM NUM BUTYL NITRILE PE 034 UNK 1.00 - 033 UNK 1.00 - 006 209 .25 - 1.50 1.50 .42 • Hatothane 001516770 NATURAL RUBBER 001 210 UNK NEOP/NAT RUBBER NEOPRENE 017 UNK • 008 002 018 UNK 210 UNK Heptane 001428250 Hexach I orocyc I opentadi ene 000774740 BUTYL NITRILE .08 .75 > 1.00 005 210 019 UNK NITRILE+PVC PVC > 1.00 6.00 > 1.00 1.00 VITON 057 210 007 210 UNK 009 UNK 3.00 .50 .25 > 1.00 NITRILE PV ALCOHOL VITON 014 118 019 100 102 100 009 118 Hexamethy I phosphoami de 006803190 > 8.00 > 8.00 > 8.00 > 8.00 BUTYL 014 118 3.07 138.28 23. .09 323 PV ALCOHOL 102 100 > 8.00 23. .07 323 PVC 007 100 .03 4,064.11 23. .02 323 VITON 009 118 .62 432.86 23. .05 323 .10 703.07 23. 080 .02 > 521.04 23. .12 274 .03 > 531.06 23. .04 274 > 526.05 23. .05 274 • 499.00 23. 080 23. .06 274 . • 23. .09 274 < .02 23. 080 23. .05 • 274 • 23. :05 274 18.04 23. 080 180.36 23. • • 080 > 450.90 23. .16 274 23. .03 274 < • .02 23. .06 323 < .02 23. .04 323 < .02 23. .08 323 . < .02 23. .03 323 . .02 •22. .08 078 • . • 13.03 22. .09 078 4.01 22. .01 078 Hexane • 001105430 BUTYL CPE NATURAL NEOPRENE RUBBER 012 014 107 060 001 002 • UNK UNK UNK 113 210 100 > .13 .17 .33 .42 .03 .17 .50 .50 .12 .17 .33 .33 .04 .35 .17 3.00 .08 1.50 > > • > > • 9.02 - 2,344.68 1,923.84 1,833.66 1,238.47 2,344.68 2,314.62 1,370.74 1,226.45 2,344.68 2,344.68 1,172.34 1,490.98 256.11 751.50 90.18 25. 25. 25. 25. 25. 25. 25. 25. 25. • 25. 25. 25. 25. 23. 45. 25. 23. 23. .04 .04 .06 .06 .04 .04 .06 .06 .04 .04 .06 .06 .04 .04 .07 273 273 273 273 273 273 273 273 273 273 273 273 287 094 094 302 080 107 A- 43 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST 014 118 018 100 019 118 003 100 014 118 017 100 002 100 018 100 019 100 118 > 8.00 > 16.00 > 8.00 > 8.00 .02 23. .90 23. .90 23. .90 23. .90 23. <• .02 23. 323 323 323 323 .04 227 .05 107 107 .04 107 .06 107 .04 227 CHEMICAL CASNO 001105430 NAME/ RESISTANT MATERIAL NEOPRENE PRODUCT VENDOR DESC CODE 002 210 BREAKTHROUGH HOURS TIME PERMEATION RATE UG/CM**2/MIN TEMP DEG C 23. THICKNESS CM REF NUM .67 576.15 UNK .86 080 .06 23. .05 186 . 018 100 UNK .75 .75 1.00 1.00 1.00’ 90.18 - 27.66 .03 901.80 121.44 75.15 91.38 25. •23. 23. 25. 25. 25. .05 .04 .04 .04 287 323 107 273 273 . 031 125 UNK 103 1.00 .33 52.91 12.02 25. 37. 23. .06 .06 .04 273 273 187 ‘ NITRILE 005 210 6.00 • .02 23. 045 NITRILE+PVC 019 033 057 058 100 103 UNK UNK 210 100 > > > > > > 4.00 6.00 7.00 18.00 17.00 17.00 1.31 1.50 ‘ .07 < < < < < 90.18 - .90 6.01 .02 .02 .02 .02 42.08 901.80 23. 23. 23. 25. 25. 25. 25. 37. 23.. 23. .04 .06 .04 .04 .06 .06 .05 080 323 107 045 273 273 273 273 187 080 PE 056 UNK .07 37. 107 076 100 .01 90.18 - 901.80 23. .01 187 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 . PVC 102 007 UNK 100 103 > 8.17 14.00 90.18 25. 23. 23. .03 287 323 SILVER SHIELD 049 122 210 UNK UNK 118 ‘ > .42 .31 .62 .48 6.00 270.54 23. 23. 23. 37. .05 .07 .03 045 080 186 186 187 TEFLON 069 510 • > > 5.00 5.00 < .02 .02 23. .01 .05 227 303 VITON 009 118 > > 11.00 11.00 23. 23. .05 .02 303 323 VITON/CHLOROBIJTyL 112 113 > 3.00 25. .02 227 > 3.00 25. .04 .04 302 302 Hydrazine (Diamine) 003020120 BUTYL NEOPRENE .04 NITRILE 23. .05 • PVC 23. .03 Hydrazine, 30-70% 003020122 BUTYL - NATURAL RUBBER NEOPRENE NITRILE- > 8.00 > 6.00 > 6.00 > 6.00 >‘ 6.00 > ‘ 8.00 A-44 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Hydrochloric Acid, <30% 076470101 NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NI TRI LE NITRILE+PVC PE PVC 017 100 102 Hydrochloric Acid, 30:70% PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS 058 076 007 077 100 100 100 100 TEMP THICKNESS REF DEG C CM HUM 122 118 064 117 CHEMICAL NAME/ RESISTANT CASNO MATERIAL 003020122 NITRILE+PVC PE PVC SILVER SHIELD Hydrochloric Acid 076470100 BUTYL BUTYL/NEOPRENE CPE NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NEOPRENE+PVC NITRILE NITRILE+PVC PVC SARANEX VITON. VI TON/NEOPRENE 110 070 001 026 002 093 138 127 005 057 058 007 049 053 077 117 UNK 210 121 210 117 117 117 210 210 117 210 117 117 117 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 2.10 > 8.00 > 8.00 > 8.00 ‘ 8.00 > 3.00 6.00 4.42 6.00 8.00 > 8.00 > 8.00 6.00 6.00 1 .75 6.00 > 8.00 > 8.00 5.17 < 5.00 2.92 4.33 5.00 > 8.00 > 8.00 > 6.00 > 8.00 > 8.00 > 8.00 > 8.00 8. 00 > 8.00 > 8.00 >.. 8.00 >• 6.00 > 6.00 > 6.00 > 6.00, > 6.00 : > 6.00 >. 6.00 > 6.00 PERMEATION RATE UG/CM**2/MIN 23. 23. .90 23. 23. 23. 6.01 23. 23. 23. 23. 23. 23. .02 23. 12.02 23. .02 23. 23. 23. 23. < .02 23. .02 23. 23. .02 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 144 117 061 117 145 117 111 117 107 107 107 107 107 .01. 227 .02 213 .01 213 .02 213 .02 213 .05 004 080 .05 237 080 .02 213 .03 213 .02 213 080 080 •.O1 213 080 .01 213 .01 213 .02 213 .01 213 .01 213 .02 213 .01 213 .02 213 .02 213 .05 107 .05 026 .05 026 .05 026 .05 026 .06 026 .04 026 :05 ‘026 026 107 .04 107 .06 107 107 107 107 107 107 NEOP+NAT RUBBER O26 102. 008 002 018 019 058.. 076 007 077 102 100 100 100 100 100 100 100 A- 45 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Hydrochloric Acid, >70% 076470103 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER 017 102 026 102 008 102 > 6.00 5.50 > 6.00 5.50 > 2.50 5.50 > 6.00 > 6.00 23. .05 026 23. .05 026 23 .05 026 23; .05 026 • 23. .06 026 23. .04 026 23. .05 026 23. 026 Hydrocyanic Acid 000749080 034 UNK 076 UNK 049 UNK 1.00 1.00 .50 .02 .12 ***** .28 ***** .04 148 .02 148 .08 148 Hydrofluoric Acid (Hydrogen Fluoride) 076643930 BUTYL BUTYL/NEOPRENE. NEOPRENE NEOPRENE+PVC NITRILE+PVC PE PVC > 8.00 > 8.00 7.08 > 8.00 > 8.00 4.25 > 8.00 3.50 1 .08 1.50 > 8.00 2.17 CHEMICAL NAME! RESISTANT CASNO MATERIAL 076470102 NATURAL RUBBER PRODUCT DESC CODE 001 VENDOR UNK • BREAKTHROUGH HOURS TIME • PERMEATION RATE UG/CM**2/MIN TEMP DEG C 23. THICKNESS CM REF NUM 052 > 1.00 015 UNK > 1.00 23. .04 052 017 100 > 5.00 23. .05 107 102 > 8.00 23. .05 026 5.50 23. .05 026 > 8.00 23. .05 026 > 8.00 23. .05 026 NEOP+NAT RUBBER 026 102 > 2.50 • 23. .06 026 > 8.00 • 23. .04 026 > 8.00 . 23. .05 026 NEOP/NAT RUBBER 008 102 > 8.00 23. • 026 UNK > 1.00 ‘ 23. 052 NEOPRENE 002 100 > 6.00 • 23. 107 018 100 > 6.00 23. .04 107 UNK > 1.00 23. .06 052 NITRILE 019 100 . > 6.00 • 23. .06 107 UNK > . 1.00 23. .05 052 PE 076 127 • .58 • 23. • • .104 PVC 003 UNK .40 23. .02 052 007 100 > 5.00 23. 107 UNK > 1.00 . 23. 052 SARANEX 061 127 > 46.67 < .02 23. 104 SILVER SHIELD 122 118 > 6.00 23. .01 227 VITON 009 UNK > 1.00 23. BUTYL PE PVC 064 117 110 093 138 139 127 058 076 049 117 117 117 117 117 117 117 117 23. .02 23. .01 23. .02 23. .02 23. .02 23. .03 23. .02 23. . .02 23. .01 23. .01 23. .01 23. .01 213 213 213 213 213 213 213 213 213 213 213 213 A- 46 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG!CM**2!MIN TEMP THICKNESS REF DEG C CM HUM Hydroftuoric Acid, 30-70% 076643932 NATURAL RUBBER -NEOP/NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PVC 017 100 3.50 102 > 8.00 1.50 > 8.00 4.50 3.00 3.50 > 8.00 > 8.00 > 8.00 1 .25 1.00 2.00 .08 > 6.00 > .50 .67 2.00 1.50 > .50 23. .05 107 23. .05 026 23. .05 026 23. .05 026 23. .05 026 23. .06 026 23. .04 026 23. .05 026 .02 23. .05 237 23. 026 23. ‘107 23. .04 107 23. .06 107 23. 107 23. 107 .10 23 104 23. 107 23. 107 23., 107 .10 23. 104 076643930 PVC 053 077 117 ‘‘ 117 < 2.08 1.67 .08 23. 23. 23. :02 .02 .01 ‘213 213 213 ‘ , .92 23. .01 213 144 117 .42 23. .02 213 SARANEX 061 117 3.17 23. .01 213 VITON VITON/NEOPRENE 145 111 117 117 > -> 8.00 8.00 23. , 23. .01 ‘ 213 NEOP+NAT RUBBER 026 ‘ ‘ 102 008 002 018 019 058 076’ 121 102 100 100 100 100 100 127 007 100 077 100 061 127 SARANEX Hydroftuoric Acid, >70% 076643933 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER Hydrogen Peroxide, 30-70% 077228412 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 017 102. 4.00 23. .05’ 026 1.50 ‘ 23. .05 ‘ 026 4.00 23. .05 026 1.50 23. .05 026 026 102 , 1.50 23. .06 026 1.50 4.00 ‘ 23. 23. .04’ :05 026 026 008 102 4.00 - 23. ‘ 026 017’ ‘100 > 6.00 23. .05 107 102 > 8.00 23 .05 026 > 8.00 ‘ 23. .05 026 > 8.00 23. .05 026 > 8.00 • 23. .05 026 026 102 > 8.00 23. • .06 026 > 8.00 23. .04 026 > 8.00 23. .05 026 008 102 > 8.00 23. 026 002 100 .12 - 23. 107 018 100 .08 23. A- 47 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL 077228412 NITRILE 087 UNK 031 , UNK 093 UNK PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN ‘ DEG C CM ‘ NUM .02 23. .04 173 .02 23. .02 173 ‘.02 23. .02 173 Hydroquinone, <30% 017 100 002 100 018 100 019 100 007 100 > 6.00 > 6.00 > 6.00 6.00 > 6.00 .90 23. .05 107 .90 23. , 107 .90 23. .04 107 .90 23. .06 107 .90 23. 107 I minobi spropyt amine NEOP+NAT RUBBER NEOP/NAT RUBBER ‘NEOPRENE 107 120 108 120 017 100 502 504 026 102 008 114 002 100 120 018 , 118 120 019 100 1,903.80 25. .02 222 350.70 25. .05 222 1,102.20 25. .03 222 791.58 25. .05 222 661.32 25. .05 222 120.24 25. .07 222 25. .08 222 310.62 25. .05 222 541.08 25. .03 222 25. .04 222 25. .06 222 PRODUCT ‘ VENDOR DESC CODE 019 ‘ ‘ 100 007 , ‘ 100 BREAKTHROUGH TIME HOURS > 6.00 > 6.00 .50 .42 .17 ‘PVC Hydrogen Phosphide (Phosphine) 078035120 NATURAL RUBBER NEOPRENE PE PVC Hydroquinone 001233190 NITRILE+PVC PE PVC 23. .06 23. 107 107 091 UNK ‘ .33 .42 054 UNK ‘ 1.67 .67 .02 23. .02 ‘23. .02 23. .02 23. .05 173 .05 173 .03 173 .04 173 058 ‘ 100 076 100 077 100 001233191 NATURAL RUBBER NEOPRENE NITRILE PVC > 6.00 23. 107 > 6.00 23. 107 > 6.00 23. 107 > 6.00 23. 107 000561880 BUTYL 014 118 > 8.00 28. .09 323 NATURAL RUBBER • 001 250 .10 84.17 26. .02 323 NEOPRENE 018 100 > 8.00 ‘ 27. .05 323 VITON , 009 118 , > 8.00 ‘‘27.’ .04 323 b-Ionone ‘ ‘ 149010760 BUTYL 014 118 > 9.00 ‘ ‘ ‘ 23. .06 323 PV ALCOHOL 102 100 > 14.00 8.00 23. 23. .04 .03 323 323 118 > 8.00 • 23. .03 323 Isoamyt Acetate 001239220 BUTYL HYPALON NATURAL RUBBER .03 .50 .09 .16 .17 NITRILE .16 761.52 25. .05 222 .20 731.46 25. .05 222 .20 140.28 25. .08 222 .09 >, 1.00 .50 .27 > 1.00 > - 1.00 A- 48 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST NEOPRENE NITRILE PV ALCOHOL VITON 018 100 .78 019 100 2.93 102 100 > 8.00 009 118 1.13 224.25 23. .05 000 9.62 23. .04 323 23. .03 323 55.31 23. .02 323 Isobthyt Acrytatè 001066380 014 118 001 210 017 . 100 002 100 210 018 100 005 210 019 100 118 057 210 058 100 076 100 007 100 210 077 100 > 8.00 2.00 .42 > 6.00 6.00 .17 > 8.00 ..OO > 6.00 > 8.00 4.00 .12 - .05 .17 2.00 .50 2.00. .90 - > 8.00 .07 323 080 .05 107 107 • 080 .04 107 23. .05 323 .02 23. 080 .90 23. .06 107 23. .05 323 23. 080 23. 107 23.. 107 23. 107 4.51 23. 080 .90 23. 107 9.02 23. 107 23; .05 323 RESISTANT MATERIAL NITRILE PE PVC BREAKTHROUGH TIME HOURS CHEMICAL NAME! CASNO 001239220 Isoamytnitrite 001104630 ‘PERMEATION RATE UG/CM**2/M IN PRODUCT VENDOR DESC CODE 019 • 100 191 • 006’ 100 505 003 120 500 • 501 TEMP THICKNESS REF DEG C CM NUN 1.08 .70 .03 • 63.13 ‘ . 130.26 20.04 25. 25. 25. • .04 .03 .01 222 ‘ 222 222 • > 1.00 .02 < 10.02 3,306.60 25. 25. .01 .01 .222 222 .02 .08 ‘ ‘ 3,306.60 1,603.20 25 25. • .01 .03 .222 222 ;O6 2,505.00 4,509.00 2,104.20 25. 25 25. 25. .02 .01 .01 .02 222 222 222 222 .02 .02 .03 014 019 102 003 118 100 100 100 > 8.00 1.13’ > 8.00 .02 23. .09 •323 126.25 23. .05 323 23. .08 323 204.41 23. .02 323 BUTYL NITRILE PV ALCOHOL PVC BUTYL NATURAL RUBBER NEOPRENE NI TRI LE NITRILE+PVC PE PVC 23. 4.51 23. 9.02 . 90.18 23. .90 23. .02 23. .90’ 23. Isobutyt ALcohoL 000788310 IsobutyL Nitrite 005425630 I sobutyra Ldehyde 000788420 4.81 .90 9.02 .90 . 9.02 .90 VITON • 009 118 BUTYL 014 118 1.30 132.26 23. • .04 323 NITRILE 019 100 1.63 6.01 23. .06 323 PVC ‘ 003 100 • .03 1,454.90 ‘ 23. .02 323 VITON 009 118 .33 619.24 • 23. ‘ .04 323 BUTYL 014 118 > 8.00 ‘ 23. .06 323 NEOPRENE 018 100 .42 48.70 23. .05 323 A- 49 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM 2/MIN DEG C CM HUM 000788420 PV ALCOHOL 102 100 .02 1.57 23. .04 323 VITON 009 118 .07 69.14 23. .03 323 Isooctane 266356430 NATURAL RUBBER 001 103 294.59 23. 045 NEOPRENE 002 100 6.00 .90 23. 107 018 100 1.00 9.02 - 90.18 23. .04 107 125 103 .02 23. 045 NITRILE 019 100 6.00 . .90 23. .06 107 103 .02 23. 045 NITRILE+PVC 058 100 .28 .90 . 9.02 23. 107 PE 076 100 .23 9.02 . 90.18 23. 107 PV ALCOHOL 004 100 .67 .90 . 9.02 23. 107 PVC 007 103 3.01 23. 045 077 100 .25 .90 . 9.02 23. 107 1.25 .90 - 9.02 23. 107 Isoprene 000787950 NEOPRENE 018 100 .27 192.38 23. .05 323 NITRILE 019 . 100 .87 27.66 23. .04 323 PV ALCOHOL 102 100 > 12.00 23. .03 323 VITON 009 118 6.20 . 1.14 23. .03 323 Isopropyt ALcohoL (PropanoL, 2-) 000676300 CPE 060 113 > 8.00 .05 204 NATURAL RUBBER 001 210 1.50 12.63 23. 080 017 100 .12 . .90 23. .05 107 102 .25 .12 23. .05 026 .17 1.80 23. .05 026 .25 .12 23. .05 026 .37 . 1.20 23. .05 026 NEOP+NAT RUBBER 026 102 .15 1.20 23. .06 026. .23 1.20 23. .04 026 .25 .12 23. .05 026 121 . .52 6.01 23. .05 237 NE9P/NAT RUBBER 008 102 .25 .12 23. 026 NEOPRENE 002 100 > 6.00 .90 23. 107 210 2.00 - 4.81 23. . 080 018 100 6.00 .90 23. .04 107 NITRILE 005 210 - 6.00 .02 23. 080 019 100 . 6.00 .90 23. .06 107 NITRILE+PVC . 057 210 6.00 .02 23. 080 058 100 .58 .90 - 9.02 23. 107 PE . 076 100 .17 .90 - 9.02 23. 107 PVC 007 100 2.50 .90 23. - 107 210 2.17 12.02 23. - 080 077 100 .50 .90 - 9.02 23. 107 .50 .90 - 9.02 23. 107 TEFLON 069 510 - 3.00 .02 23. .05 303 I sopropyL amine 000753100 BUTYL 014 118 4.08 36.07 24. .09 323 NEOPRENE 018 100 - .23 - - 913.82 21. .05 323 A- 50 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS 007 069 009 100 510 118 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEC C CM NUN 070 UNK 017 UNK 008 UNK 018 UNK 019 UNK 004 UNK 007 UNK 009 UNK 4,671.32 18. .02 323 < .02 23. .05 303 3,342.67 26. .04 323 > 480.96 23. 23. .05 .04 .004 274 > 501.00 23. 23. .05 .09 274 274 > 10.02 23. 23. .06 .05 274 274 23. .12 274 > 501.00 23. .16 274 23. .03 274 CHEMICAL NAME! RESISTANT CASNO MATERIAL 000753100 PVC TEFLON VITON IsopropyL Ether 001082030 CPE NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE PV ALCOHOL PVC VITON I sopropyLmethacryt ate 046553490 BUTYL NITRILE PV ALCOHOL PVC Kerosene 080082060 NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC Lactic Acid, >70% 000793343 NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC Lauric Acid, 30-70% 001430772 NATURAL RUBBER NEOPRENE NITRILE PVC 23. .09 323 36.07 23. .05 323 23. ‘ .09 323 354.71 23. .02 ‘ 323 014 019 102 003 017 026 002 018 019 058 076 004 007 077 118 100 100 100 100 121 100 100 100 100 100 100 100 100 .03 > 3.00 .18 > 3.00 .06 .12 > 1.00 .71 > 1.00 > 1.00 .25 > 1.00 > . 8.00 1.88 >‘ 8.00 .02 .50 .60 > 6.00 > 6.00 > 6.00 1.25 .20 > 6.00 > 6.00 .50 3.00 > 6.00 > . 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > ‘ 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 .25 .90 9.02 12.02 .90 .90 .90 9.02 - 90.18 9.02 . 90.18 .90 .90 9.02 90.18 9.02 - 90.18 23. 23. 23. 23. 23. 23. 23.’ 23. 23. 23. 23. 017 . 100 002 100 018 100 019 100 058 100 076 100 004 100 007 100 077 100 .05 , 107 .05 237 107 .04 107 .06 107 107 107 107 107 107 107 .05 107 107 .04 107 .06 107 107 107 107 107 107 .107 .05 107 107 .04 107 .06 107 107 .90 23. .90 23. .90 23. .90 23. .90 23. .90 23. .90 23. .90 23. .90 23. .90 23. 23. 23. 23. 23. 23; 017 002 018 019 007 100 100 100 100 100 A- 51 ------- d•Limonene (Menthadiene) 059892750 BUTYL NEOPRENE NITRILE PV ALCOHOL 014 118 018 100 019 100 102 100 Mesityt Oxide (Methytpentenone, 4-,3-,2-) 001417970 CPE 060 > 8.00 1.08 > 20.00 > 8.00 1 .83 .33 > 3.00 RE F HUM 23. .02 323 23. .05 323 23. .04 323 23. .03 323 Methacryloriitrite 001269870 MethanoL (MethyL ALcohoL) 000675610 BUTYL BUTYL/NEOPRENE CPE NATURAL RUBBER 014 118 001 250 102 100 003 100 110 117 060 113 001 210 017 100 102 120 502 504 UNK 026 102 > 8.00 > 8.00 > 8.00 >‘ 8.00 > 3.00 6.00 .33 .22 .25 .25 .25 .25 .03 > 1.00 .30 > 1.00 > 1.00 .25 t, 803.60 .48 1,142.28 23. 23. 23., 23. 25. .02 23. 8.02 25. 23. 23. 23. 23. 23. 25. 25. 25. 25. 23. 1.20 23. 23. .09 323 23. .02 323 23. .06 323 23. .02 323 .02 213 .01 213 .02 213 .02 213 .07 302 080 .03 222 .05 107 .05 026 .05 026 .05 026 .05 026 .02 222 .05 222 .05 222 .06 222 .04 274 .06 Q26 SUMMARY, OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM Mateic Acid, >70% 001101673 NATURAL RUBBER NEOPRENE NITRILE NITRI LE+PVC PE PVC 017 100 002 100 018 100 019 100 058 100 076 100 007 100 077 100. > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. UNK VITON/CHLOROBUTYL 112 UNK .05 107 107 .04 107 .06 107 107 107 107 107 107 142 142 142 BUTYL NATURAL RUBBER PV ALCOHOL PVC Acid NEOPRENE PVC MéthanesUtfonic 000757520 > 8.00 .02 .40 .03 > 4.00 > 4.00 018 100 003 ‘ 215 064 117 23. .05 123 23. .05 123 NEOP+NAT RUBBER .90 1.20 1.20 1.20 1.20 18.04 4.01 4.01 4.01 A-- 52 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS 049 117 UNK 077 100 .25 .30 .25 .40 > 1.00 .25 .29 .38 6.00 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 > 1.00 1 .03 5.92 5.00 > 8.00 6.00 1.15 .18 > 1.00 .90 .65 > 1.00 .91 6.00 .33 > 1.00 > 1.00 .22 > .8.00 .02 .02 .04 .03 .03 .05 .05 .03 .02 .04 .75 6.00 > 1.00 1.50 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEC C CM NUM 1.20 23. .05 026 6.01 23. .05 237. 1.20 23. . 026 4.01. 25. .05 222 23. .05 274 .90 23. 107 6.01 25. .08 222 5.01 25. .07 222 .02 23. 080 .90 23. .04 107 4.01 25. .08 222 4.01 . 25. .05 222 4.01 25. .07 222 4.01 25. .05 222 4.01 25. .03 222 23. .09 274 23. .06 274 23. .04 187 23. .02 213 23 .03 213 23. .02 213 .02 23. 080 23.05 25. .04 222 90.18 . 901.80 23. .06 107 4.01 25. . O6 222 36.07 25. .04 222 29.06 25. .03 222 23. .05 274 23. .05 187 .02 23. 080 9O 9.02 23. 107 4.01 25. .01 222 4.01 25. .01 222 .90 23. 107 23. .01 213 124.75 23. 123 124.75 21. 124 > 30.06 23. .12 274 36.07 25. .01 222 34.07 25. .01 222 18.04 25. .03 222 23.05 25. .02 222 34.07 25. .01 222 38.08 25. .01 222 30.06 25. .02 222 9.02 90.18 23. 107 .02 23. 080 23. .16 274 23. .07 186 • • 23. .05 186 23. .01 213 23. .03 187 .90 23. 107 CHEMICAL NAME/ RESISTANT CASNO MATERIAL 000675610 • NEOP+NAT RUBBER 026 102 . • 121 NEOP/NAT RUBBER 008 102 • 114 • UNK NEOPRENE 002 100 120 210 • 018 100 118 120 •UNK 031 UNK 093 117 138 117 139 117 NITRILE 005 210 019 100 503 UNK 033 UNK NITRILE+PVC 057 210 058 100 PE 006 100 • 505 076 100 117 PV ALCOHOL 004 100 UNK PVC 003 120 • 500 501 007 • 100 • 210 UNK .77 .83 .68 .17 A- 53 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2!MIN TEMP THICKNESS REF DEGC CM NUM 000675610 PVC SARANEX TEFLON VITON VI TON/CHLOROBUTYL VITON/NEOPRENE 077 100 117 061 117 069 510 009 UNK 145 117 112 113 111 117 5. .08 > 8.00 > 14.20 > 5.00 > 1.00 .83 > 3.00 > 8.00 9.02 90.18 23. 107 23. .01 213 23 .01 213 .02 23. .05 303 .02 24. .05 303 23. .03 274 23. .01 213 25. .04 302 23. .02 213 Methytamine (Monomethytamine) 000748950 NATURAL RUBBER NEOPRENE 23. .07 323 33.07 23. .05 323 23. .03 323 116.03 23. .03 323 9.02 . 90.18 23. .05 107 .90 23. 107 9.02 . 90.18 23. .04 107 .90 23. .06 107 90 9.02 23. 107 4-Methoxy-4-methyt -2-pentanone 001077000 BUTYL NEOPRENE PV ALCOHOL VITON Methyl Acetate 000792090 BUTYL NATURAL RUBBER PE PV ALCOHOL PVC Methyl Acrytate 000963330 BUTYL NATURAL RUBBER NEOPRENE PV ALCOHOL TEFLON 014 018 102 009 014 001 076 102 003 014 0o1 018 102 069 017 002 018 019 007 118 100 100 118 118 250 100 100 •100 118 250 100 100 510 100 100 100 100 100 . 23. .09 323 . 6,012.00 23. .02 323 .90 9.02 23. . 107 12.02 6,012.00 23. 23. • .07 02 323 323 • 625.25 3,168.32 1.80 23. 23. 23. 23. .09 .02 .05 .07 323 323 323 323 < .02 23. .05 303 > 13.00 1.65 > 14.00 .40 > 8.00 .02 .07 .68 .02 > 8.00 .02 .25 1.50 > 3.00 .42 6.00 4.50 > 6.00 2.25 > 15.00 > 8.00 .50 .17 .17 1.00 1.90 > 16.00 > 8.00 .05 1.05 .03 NITRILE PVC Methylamin , 30-70% 000748952 BUTYL NITRILE NITRI LE+PVC PE PVC SILVER SHIELD VITON 3-MethyL ami nopropytami ne 062918450 BUTYL NATURAL RUBBER NEOPRENE PVC 014 118 019 118 058 100 076 100 077 100 122 118 009 118 014 118 001 250 018 100 007 100 < .02 23. .04 227 • 23. .04 227. 9.02 - . 90.18 23. 107 9.02 - < 90.18 .90 23. 23. ‘ 107 107 .90 - < 9.02 12.02 02 23. 23. 23. • .01 .02 107 227 227 .02 731.46 160.32 671.34 20. .07 16. .02 16. .05 14. .02 323 323 323 323 A- 54 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Methyl Bromide (Bromomethane) 000748390 SARANEX Methyl Celtosolve (Methoxyethanol, 2) 001098640 BUTYL NEOP+NAT RUBBER NITRILE Methyl Chloroacetate 000963440 SARANEX 23. 104 CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE UG/CM**2/MIN DEG C CM NUM 061 127 > 8.00 014 118 > 20.00 23. .05 123 026 121 • .58 6.01 23. .05 237 019 100 .67 60.12 23. 123 061 .127 > 8.00 18.04 23. Methyl Chloroform (Trichtoroethane,1,1,1) 000715560 BUTYL 014 118 UNK .48 .48 064 UNK • • .42 NATURAL RUBBER 001 210 .13 017. 100 .06 120 .03 502 .12 504 .12 . NEOP+NAT RUBBER . 026 ‘ UNK 102 .22 .07 .13 NEOP/NAT RUBBER 008 114 .17 NEOPRENE . 002 010 018 100 120 210 100 100 120 . UNK , . .07 .04 .20 .40 .32 .32 .80 .42 .27 .40 .75 NITRILE 005 019 . 210 100 > 2.00 . .18 2.00 1.00 .93 . NITRILE+PVC . .. 020 057 058 . 118 181 503 UNK 100 210 100 . . . . • .62 .68 .60 .06 .50 .28 .28 .83 .15 .10 PE 006 100 .03 918.50 25. 91984 23. 25. 25. 901.80 23. 2,605.20 25. 5,711.40 25. 3,106.20 . 25. 1,803.60 25. 1,202.40 25. 25. 3,006.00 .25. 2,404.80 25. 1,002.00 25. 701.40 25. 781.56 23. 895.12 25. 745.49 23. 1,002.00 25. 801.60 25. 901.80 25. 1,002.00 25. 895.79 23. 25. 601.20 23. 4,108.20 25. 9,018.00 23. 10.02 25. 50.10 25. 459.32 23. 459.32 23. 25. 2,605.20 25. 25. 282.56 23. 282.23 25. 96.19 23. 901.80 23. 9,018.00 23. 130.26 25. .04 288 .04 100• .05 326 .04 326 080 .03 222 .02 . 222 .05 222 .05 222 .06 222 .02 326 .05 222 .05 . 222 .08 222 .07 222 080 .05 288 .05 323 .05 222 .07 222 .05 222 .03. 222 .05 100 .06 326 080 .04 222 .06 107 .06 222 .04 222 .04 323 .04 227 .03 222 .03 222 .02 .326 .03 . 100 .03 288 080 107 107 .01 222 901 .80 9O 18 - 901.80 - A—5 5 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP UG/CM**2/MIN DEG C THICKNESS REF CM HUM POLYURETHANE PV ALCOHOL SILVER SHIELD TEFLON VITON Methylene Bromide (Dibromomethane) 000749530 PE CPE NATURAL RUBBER UNK 050 UNK 004 100 102 100 UNK 003 118 500 501 UNK 210 100 UNK 118 510 118 014 118 UNK 060 113 001 210 UNK 017 100 120 502 504 .02 .05 .13 .02 .20 .03 1.00 > 8.00 6.00 > 8.00 .02 .01 .01 .02 .50 .10 .25 .03 .05 > 6.00 > 3.00 > 15.17 > 15.00 > 6.00 > 8.00 > 24.00 .17 .17 .42 .10 .03 .02 .01 .05 .03 .05 1,593.18 3,206.40 4,008.00 1,593.18 120.24 90.18 90.18 901.80 696.39 23. 25. 1,803.60 23. > 140.28 23. .01 288 .01 222 .01 100 .01 326 107 107 .01 326 107 .03 323 25. .05 288 23. .05 100 25. .01 288 25. .01 222 25. .02 222 23. .01 100 23. 080 23. 107 23. 107 23. 107 .04 100 .07 302 080 .12 274 000715560 PE 006 100 505 UNK 042 UNK 076 100 .02 .20 154.48 25. 30.06 25. 154.48 23. 25. 9.02 23. 901.80 23. 25. .90 23. 23. PVC 25. .01 326 .90 - 90.18 - 9.02 - 9.02 9O’.18 - 007 077 122 069 009 UNK 076 100 004 100 PV ALCOHOL Methylene Chloride (Dichtoromethane) 000750920 BUTYL 25. .03 326 23. .01 227 .02 23. .05 303 23. .03 323 23. .02 .227 25. .02 288 23. .02 100 25. .03 326 90.18 23. 107 .90 23. 107 698.06 25. .04 288 .03 .6.00 9.02 .25 - NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 8,216.40 25. .03 222 13,026.00 25. .02 222 4,308.60 25. .05 222 4,809.60 25. .05 222 3,807.60 25. .06 222 UNK .03 > 120.24 23. .04 274 026 102 .05 4,609.20 25. .05 222 121 .03 1,274.54 23. .05 237 008 114 .07 . 3,406.80 25. .05 222 UNK .03 > 160.32 23. .05 274 002 100 .13 1,102.20 25. .08 222 120 .01 2,805.60 25. .07 222 210 .08 1,803.60 23. 080 010 100 < .02 2,688.70 25. .05 288 A- 56 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 000750920 NEOPRENE 018 118 .22 2,004.00 25. .08 222 120 .07 3,507.00 25. .05 222 .15 2,605.20 25. .07 222 .11 2,805.60 25. .05 222 .03 4,809.60 25. .03 222 UNK .02 2,687.36 23. .05 100 .21 > 150.30 23. .09 274 .08 > 140.28 23. .06 274 125 103 1,881.76 - .02 .23. 045 NITRILE 005 210 3.00 5,410.80 23. 080 019 100 .04 12,024.00 25. .04 222 .11 8,216.40 25. .06 222 .04 13,026.00 25.. .04 222 103 4,016.02 23. 045 118 .07 4,605.19 23. .04 227 503 .03 1,903.80 25. .03 222 UNK .02 5,639.26 23. .03 100 .04 > 125.25 23. .05 274 .03 > 150.30 23. .05 274 020 100 .02 5,644.60 25. .03 288 NITRILE+PVC 057 210 .20 2,645.28 23. 080 PE 006 100 .01 300.60 25. .01 222 .02 420.84 25. .01 288 505 .03 100.20 25. .01 222 UNK .02 420.84 23. .01 100 076 100 .02 90.18 - 901.80 23. 107 PV ALCOHOL 004 100 .28 .90 23. 107 UNK 1.00 23. .12 274 102 100 8.00 23. .04 323 6.00 25. .05 288 UNK 8.00 23. .05 100 PVC 003 118 .02 . 25. .01 288 120 .01 25. .01 222 .01 > 16,699.98 25. .01 222 .02 12,024.00 .25. .03 222 .01 > 16,699.98 25. .02 222 500 .01 > 16,699.98 25. .01 222 501 .01 > 16,699.98 25. .01 222 .01 . > 16,699.98 25. .02 222 UNK .02 23. .01 100 007 103 2,555.10 23. 045 • 210 .10 3,486.96 23. 080 • UNK .17 > 150.30 23. .16 274 SILVER SHIELD • 122 118 1.90 .02 23. .01 227 TEFLON 069 510 . .78 .02 23. .05 303 .84 02 23. .05 303 .92 .02 23. .05 303 .62 24. .05 303 .62 . 24. .05 303 .58 24. .05 303 .75 24. .05 303 VIT0N 009 118 1.00 44.00 23. .02 227 1.38 23.38 25. .02 288 A- 57 ------- 009 UNK SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST 112 113 .42 - 1.03 - .30 .15 - n-MethyLethanotami ne 001098310 BUTYL CELLULOSE ACETATE NATURAL RUBBER NEOPRENE MethyL EthyL Ketone (Butanone 1 2) 000789330 BUTYL 014 118 216 064 117 210 250 017 100 120 502 504 026 102 121 008 114 002 100 093 117 125 103 138 117 139 117 005 210 019 100 103 .10 .02 .04 .27 .09 .08 .15 .28 .04 .12 .22 .65 .13 .45 .17 .07 .08 .08 .08 33 .11 .20 .10 .02 .19. .02 20. 150.30 20. .02 20. .06 323 .07 123 124 .02 213 .01 213 .02 213 .02 213 .07 302 045 045 080 .01 323 .03 222 .05 107 .02 222 .05 222 .05 222 .06 222 .05 222 .05 237 .05 222 .08 222 .07 222 080 .05 323 .08 222 25. .05 222 25. .07 222 25. .05 222 25. .03 222 23. .02 213 .60 23. 045 23. .03 . 213 23. .02 213 23. 080 25. .04 222 25. .06 222 25. .04 222 23. 045 CHEMICAL NAME! RESISTANT CASNO MATERIAL 000750920 VITON VI TON/CHLOROBUTYL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS • .1.38 22.85 23. .95 10.02 23. .60 1.12 .47 .23 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C . CM NUN .02 100 .03 274 25. .04 302 15. .04 302 25. .04 302 35. .04 302 014 099 001 018 118 118 250 100 > 8.00 > 8.00 .08 > 8.00 > 8.00 > 4.00 > 4.00 1.67 .07 .03 .02 .06 323 323 323 323 .02 23. 23. 21. 23. 110 060 001 117 113 103 .47 2.33 23. 2.00 23.. .08 23. .58 25. 925.85 23. 517.03 23. 1,022.04 23. 100.20 23. 601.20 25. .17 901.80 9,018.00 23.. .02 801.60 25. .12 320.64 25.. .13 400.80 25. BUTYL/NEOPRENE CPE NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE 120 210 018 100 - 118 120 200.40 . 25. 310.62 25. 1,004.00 23. 230.46 25. 200.40 25. 501.00 25. 721.44 23. 3,066.12 23. 230.46 25. 601.20 330.66 601.20 901.80 492.98 3,106.20 1,903.80 2,204.40 1.20 A- 58 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL 000789330 NITRILE NITRILE+PVC PE Pvc SARANEX TEFLON VITON VI TON/CHLOROBUTYL VI TON/NEOPRENE Methyl Ethyl Ketone Peroxide 013382340 BUTYL NATUR LL RUBBER NEOPRENE VITON PRODUCT VENDOR DESC CODE 019 ‘181 5O 057 210 006 100 505 076 100 117 004 100 102 100 007 103 210 049 117 061 117 127 510 117 113 117 BREAKTHROUGH TIME HOURS .06 .16 > .02 .05 .03 .50 5.37 .27 .08 .15 .48 > 3.00 .16 .42 . .66 07 25. 25. 23. 25. 25. 23. 23. 23. 23. 23. 23. 23. 23. 7.82 23. .02 23. 23. 25. 23. .03 222 .03 222 080 .01 222 .01 222 107 • .01 213 107 .07 323 045 080 .01 213 .01 213 104 .05 303 .01 213 .04 302 .02 213 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEC C CM NUM PV ALCOHOL .16 2,805.60 1,503.00 607.21 10.02, 3.01 9.02 - 90.18 9.02 - 90.18 .15 4.81 721.44 • 069 145 112 111 014 001 018 009 014 118 Methythydrazi ne 000603440 MethyL Iodide 000748840 BUTYL CHLOROBUTYL CPE CR 39 PVC TEFLON VITON BUTYL NATURAL RUBBER NEOP+NAT RUBBER . 118 250 > 4.00 .75 6.01 23. 23. .07 .02 323 323 • 100 118 > > 4.00 4.00 23. 23. .05 .04 323 323 ‘> 2.00 22. .23 321 . 064 085 052 113 211 205 • > • > 2.00 .01 2.00 2.00 22. 22. 22. 23. .04 .03 .11 .04 321 321 321 321 060 070 ‘095 113 113 122 • > .87 1.10 2.00 22. 22. 22. .05 .05 .17 321 321 321 003 103 .52 1.90 22. 22. .13 .13 .321 321 053 .126 > 2.00 22. .05 321 083 211 > 2.00 22. .20 321 055 210 < .01 22. .02 321 062 UNK < .01. 22. .02 321 067 UNK < .01 22. .02 321 068 • 069 UNK UNK • < < .01 .01 • • 22. 22., .02 .02 321 321 009 118 1.50 22. .05 321 014 118 • .92 492.98 23. .09 323 017 100 120 502, 504 • . .03 .03 .05 .04 .06 • 13,026.00 >‘ 16,699.98 8,116.20 9,218.40 6,913.80 25. 25. 25. 25. 25. .03 .02 .05 .05 .06 222 222 222 222 222 026 102 .03 8,917.80 25. A- 59 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST NI TRI LE+PVC PE 005 210 019 100 118 120 UNK BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP UG/CM**2/MIN DEG C THICKNESS REF CM NUM CHEMICAL NAME! RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE 000748840 NEOP/NAT RUBBER NEOPRENE ‘ 008 002 114 100 018 120 100 , 118 120 NITRILE 019 100 • 181 503 PE 006 100 505 PV ALCOHOL 102 100 VITON 009 118 Methyl Isobutyl 001081010 Ketone (Methylpentanone, 4-,2-) ‘ BUTYL 012 UNK > V .09 5,310.60 25. .05 222 .25 1,402.80 25. .08 222 .01 4,6Ô9.20 25. .07 222 .10 • 7,893.76 ‘23. .05 323 .28 2,905.80 25. .08 222 .07 6,312.60 25. .05 222 .20 3,707.40 25. .07 222 .07’ 5,611.20 25. .05 222 .04 7,915.80 25. .03 222 .01 6,613.20 25. .03 222 .13 8,016.00 25. .05 222 .09 6,012.00 25. .04 222 8,216.40 25. .03 222 .03 • 11,022.00 25. .03 222 .01 1,102.20 25. .01 222 .04’ 300.60 25. .01 222 8.00, 23. .07 323 6.35 4.21 23. .04 323 1.50 19.24 25. .04 2.67 , 5.00 52:30 25. ‘25. .04 273 .06 4.50 39.08 25. ‘ .06 273 1.50 36.07 25. .04 273 2.17 40.88 25. .04 273 5.00 4.81 ‘25. .06 273 ‘5.67 1.20 25. .06 273 .17 30.06 25. .04 273 .83 ‘ 70.34 25. .04’ 273 3.00 “ ‘ 16.83 25. .06 273 3.75 7.82 25. .06 273 014 118 4.07 6.01 23. .05 086 001 210 .25 420.84 23. 080 017 100 , .10 90.18 . 901.80 23. .05 107 002 210 .25 541.08 23. 080 010 120 .62 277.22 23. .06 086 018 • ‘ 100 UNK , ‘ V .47 .33 .33 .50 .53 1.67 .80 .20 .35 .50 .50 1.17 1.17 ‘ • 529.39 303.61 284.37 298.80 ‘ 277.75 841.68 402.47 492.65 848.36 304.81 ‘ 290.38 290.38 256.71 23. 25. 25. 25. 25. 23:’ 23. 23. 23. .25. 25. 25. 25. .06 086 .04 273 .04 273 .06 273 .06 273 , 080 .06 086 ;O4 086 .05 086 .04 273 .04 273 .06 273 .06 V 020 503 • .32 1,033.73 23. .04 086 057 . 210 .30 23. 006 512 .01 “ 781.56, ‘23. 080 NATURAL RUBBER NEOPRENE NITRILE A- 60 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Methyl-vinyt-ketone 000789440 CPE Monoi sopropanotami ne 000789660 VI TON/CHLOROBUTYL .72 1,012.00 .01 .02 .01 .02 > 8.00 > 8.00 .02 .07 .06 323 .07 323 .02 323 .01 323 20. .05 323 23. .04 323 23. .03 323 23. .05 323 21. .03 323 1,212.42 23. .03 323 CHEMICAL NAME! CASNO BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MI N TEMP THICKNESS REF DEG C CM NUM 9.02 .03 > 6.00 .50 > 3.00 .20 90.18 .90 991.98 .02 1,743.48 23. 23. 23. 23. 23. 10? 107 080 .05 303 .04 086 13. 90.18: 23.. 20. 10,641.24 23. 2,254.50 .02 .02 RESISTANT . PRODUCT VENDOR MATERIAL DESC CODE 001081010 PE 076 100 PV ALCOHOL 004 100 PVC 007 210 TEFLON 069 510 VITON 009 118 Methyl Isocyanate 006248390 BUTYL 014 118 NATURAL RUBBER 001 250 NEOPRENE 018 100 PV ALCOHOL 004 100 VITON 009 118 Methyl Methacrylate 000806260 BUTYL 014 118 NATURAL RUBBER 001 250 PE 076 100 PV ALCOHOL 004 100 102 100 PVC 003 100 TEFLON 069 510 060 UNK 112 UNK 026 121 002 100 018 100 019 100 058 100 076. 100 127 004 100 007 100 077 100 061 127 014 118 018 100 007’ 100 009 118 Mineral Spirits 080524130 23. 23. 23. 23. 23. 23. 23. 23. 23. .09 323 .02 323 107 107 .06 323 .02 323 .05 303 142 142 24.05 9,619.20 9.02 - 90.18 .90 9,619.20 .02 138.28 .90 .90 - 9.02 .90 9.02 - 90.18 9.02 - 90.18 7.01 .90 .90 - 9.02 .90 - 9.02 .9.02 . 90.18 23. 142 NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC SARANEX 4.98 .02 .03 > 6.00 > 8.00 .02 > 3.10 .50 1.67 > . 3.00 .22 6.00 1.50 > 6.00 .10 .10 .08 > 6.00 2.50 .10 .10 > .17 > 8.00 > 8.00 > 8.00 > 8.00 23. 23. 23. 23. 23. 23. 23. .05 237 107 .04 107 .06 107 107 107 104 107 107 107 107 104 BUTYL NEOPRENE ,PVc VI TON 23. 23. 23. 23. .20 23. Morpholine 25. .07 323 24. .05 323 25. .02 323 25. .04 323 A— 61 ------- Nitric Acid. SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST BREAKTHROUGH TIME HOURS PRODUCT VENDOR DESC CODE 014 118 017 100 019 118 004 100 102 100 122 118 009 118 001 125 019 007 070 026 002 018 019 058 076 004 007 077 CHEMICAL NAME/ RESISTANT CASNO MATERIAL 001109180 BUTYL NATURAL RUBBER NITRILE PV ALCOHOL SILVER SHIELD VITON • N-Methyt-2-pyrratidone 008725040 NATURAL RUBBER NEOPRENE NITRILE PVC Waphtha, V.M.& P (Ligroine) 080323240 CPE NEOP+NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL •PVC BUTYL BUTYL/NEOPRENE CPE NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NEOPRENE+PVC NI TRI LE NITRILE+PVC PE PVC 103 103 103 103 UNK 121 100 100 100 100 100 100 100 100 076973720 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM HUM. > 16.00 23. • .04 323 > 16.00 23. .04 227 .50 • .90 - 9.02 23. .05 107 .73 1,240.28 23. .03 323 .80 1,238.47 23. .04 227 3.00 .90 23. 107 6.17 25.25 23. .03 323 > 8.00 23. .01 227 1.80 581.36 23. .02 323 • 1.90 •,583.16 23. .92 227 3.61 23. 045 6.01 23. 045 24.05 23. 045 24.05 23. 045 > 3.00 23. .05 004 • .07 96.19 23. .05 237 > 6.00 .90 23. 107 .25 90.18 - 901.80 23. .04 107 • 6.00 .90 23. .06 107 .15 9.02 . 90.18 23. 107 • .05 90.18 - 901.80 23. —107 • 7.00 .90 23. 107 2.00 .90 23. 107 .08 .90 - 9.02 23. 107 .33 9.02 . 90.18 23. 107 8.00 23. .02 213 8.00 23. .01 213 8.00 23. .02 213 > 8.00 • 23. .02 213 • 3.00 23. • .05 004 2.00 23. 080 8.00 .02 23. .05 237 2.00 23. 080 2.67 23. .01 213 1.33 23. .03 213 3.08 • 23. .02 213 1.08 23. .02 213 4.00 23. 080 4.50 23. 080 .42 23. .01 213 8.00 23. .01 213 3.75 23. 080 3.00 • ?3 - .01 213 - .42 23. .01 213 .33 23. .02 213 < .08 23. .01 213 .75 23. .01 213 064 117 110 117 070 •, UNK 001 210 026 121 002 210 093 138 139 127 005 057 058 076 007 049 117 117 117 117 210 210 117 117 210 117 053 117 077, 117 A- 62 ------- SUMMARY OF PERFORMANCE DETAIL.TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT- • CASNO MATERIAL 076973720 PVC PRODUCT VENDOR DESC CODE 144 117 • BREAKTHROUGH HOURS TINE ‘ .58 PERMEATION RATE UG/CM**2/MIN TEMP DEG C 23. THICKNESS CM .02 REF NUM 213 • SARANEX 061 117 5.00 23. .01 213 - SILVER SHIELD 122 118 > 6.00 23. • .01 227 VITON 145 117 > 8.00 23. .01 213 VITON/NEOPRENE 111 117 > 8.00 23. .02 213 Nitric Acid, <30% - . 076973721 NATURAL RUBBER 017 100 > 6.00 23. .05 107 . 102 > 8.00. 23. .05 026 . > 8.00 ?3. .05 . > > 8.00 8.00 23. 23. .05 .05 026 026 NEOP+NAT RUBBER 026 - 102 > 8.00 23. .06 026 . > 8.00 23. .04 026 > 8.00 23. .05 026 NEOP/NAT RUBBER 008 102 > 8.00 23. 026 , NEOPRENE 002 100 > 6.00 23. 107 018 100 ‘ > 6.00 23. .04 107 NITRILE 019 100 > 6.00 23. .06 107 NITRILE+PVC 058 100 > 6.00 23. 107 PE 076 100 .75 23. 107 PVC 007 100 > 6.00 23. 107 . 077 100 > 6.00 4.75 23. 23. 107 107 Nitric Acid, 30-70% . . 076973722 NATURAL RUBBER 017 102 > 6.00 23. .05 026 3.00 23. .05 026 . > 5.50 8.00 23. 23. .05 .05 026 026 NEOP+NAT RUBBER 026 102 > 3.00 23. .06- 026 2.00 23. .04 026 . > - 6.00 23. .05 026 NEOP/NAT RUBBER 008 102 > 6.00 23. 026 NEOPRENE 002 100 > • - 6.00 . 23. . 018 100 2.33 23. .04 107 PE 076 127 .83 23. • 104 PVC 007 100 5.75 23. 107 SARANEX 061 127 46.67 < 02 23. 104 Nitric Acid, >70% 076973723 NATURAL RUBBER . 001 01-5 UNK UNK > > - 1.00 1.00 23. 23. .04 052 052 NEOP/NAT RUBBER • 008 UNK > 1.00 23. 052 NEOPRENE 018 UNK > > 1.00 LOD 23. 23. .09 .06 052, 052 NITRILE 019 UNK > 1.00 23. .05 052 NITRILE+PVC 058 100 .10 23. 107 PE 076 100 • .22 23. 107 PVC 003 - UNK 007 UNK > .10 1.O , 23. 23. .02 052 052 SARANEX 061 127 . - 1.78 23. VITON 009- - UNK > 1.00 ‘-23. 104 A- 63 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MIN TEMP THICKNESS REF DEGC CM HUM Nitric Acid, Fuming Red 080075870 BUTYL CHLOROBUTYL CPE NATURAL RUBBER PV ALCOHOL PVC SILVER SHIELD VITON 014 118 052 205 060 113 017 100 101 110 008 114 002 100 018 . 100 019 100 118 004 100 003 120 007 100 053. 189 054 189 077 212 122 118 009 118 > 1.50 1.50 >. 1.50 1.50 .45 > 1.50 > 1.50 - 1.50 > 1.50 1 5O > 1.50. > 1.50 1.50 1.50 > 1.50 > 1.50 > 1.50 > 1.50 > 1.50 1.50 .01• .20 .57 .07 .92 .67 .43 .37 .07 .25 .04 .01 .12 .58 > 1.50 23.. .03 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 001 23. .03 001 23. .03 001 23. .09 001 23. .05 001 23. .10 001 23. .03 001 23. .09 001’ 23. . .11 001 23. . .10 001 23. .07 001 23. .06 001 23. . .07 001 23. .05 001 NEOP/NAT RUBBER NEOPRENE NI TR I LE 23. .04 23. .08 23. .05 23. .05 23. .04 23. .05 23. .04 .23. .05 23. .05 23. .04 23. .04 23. .04 23. .13 23. .13 23. .05 23. . .04 23. .04 Ni trobenzene 000989530 23. .05 23. .03 23. .01 23. .03 001 001 227 •O01 BUTYL 014 . . 118 > > 23.00 . 23.00 . 23. 23. .06 4.00 323 - 227 064 . 117 . 8.00 23. .01 213 CPE NATURAL RUBBER NEOPRENE NITRILE 060 070 017 018 031 019 113 UNK 100 100 511 118 . 1.03 1.03 .08 .75 .67 .48 9.02 - . 90.18 1.14 132.26 10.22 25. 23. 23. 23. ? • 23. .07 .05 .05 .05 .04 302 004 107 323 323 323 PV ALCOHOL 004 102 100 100 > > .55 6.00 16.00 < 10.22 .90 23.. 23. 23. .04 .03 227 107 323 SILVER SHIELD -TEFLON 122 069 118 510 > 8.00 3.00 .02 .23. 23. .01 .05 227 A- 64 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST 069 510 009 118 > 112 113 2.83 - Nitrogen •Tetroxide 105447260 BUTYL 014 118 2.00 .68 064 113 .60 085 211 > 2.00 CHL OROBUTYL 052 205 > 2.00 CPE 060 113 1.15 070 113 1.25 CR 39 095 . 122 > 2.00 091 UNK 1.17 PVC 003 103 . .33 .20 053 126 .65 083 211 > 2.00 062 UNK .01 067 UNK .01 069 UNK .01 .01 009 118 .77 CHEMICAL NAME! CASNO RESISTANT MATER IAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MI N 000989530 TEFLON VITON VI TON/CHLOROBUTYL Nit roethane 000792430 BUTYL NATURAL RUBBER NEOPRENE PV ALCOHOL TEMP THICKNESS REF DEGC CM NUM .02 24. 23. 23. 25. 3.00 8.00 8.00 3.00 > 8.00 .03 .82 3.52 .05 .03 .02 .04 014 118 001 250 018 100 102 100 303 323 227 302 186.37 102.20 2.40 23. .09 323 23. .02 323 23. .04 323 23. .07 323 TEFLON VITON 22. .23 22. .05 22. .03 22. .11 23. .04 22. .05 22. .06 22. .17 22. .04 22. .13 22. .13 22. .05 22. .19 23. .02 23. .02 23. .02 23.. .02 22. .03 321 321 321 321 321 321 321 321 321 321 321 321 321 321 321 321 321 321 Ni tromethane 000755250 Ni tropropane 253220140 BUTYL 014 118 > 8.00 23. .09 323 NATURAL RUBBER 001 . 250 < .02 %.19 23. .02 323 017 ., 100 . .07 < .90 23. .05 107 NEOPRENE 002 018 100 100 1.50 1.00 .90 < . .90 9.02 23. 23. .04 107 107 . 1.07 3.01 23. .05 323 NITRILE 019 100 .50 90.18 . 901.80 23. Mo 107 PE . 076 100 > 6.00 < .90 23. 107 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 102 100 .17 30.06 23. .07 323 BUTYL 014 118 > 8.00 < .02 23. .04 227 034 UNK > 101.00 • 22. .08 078 NITRILE 019 033 118 UNK .42 . . .27 .83 177.35 . 200.40 23. 22. .04. .09 227 078 NITRILE+PVC • 058 100 < 08 9.02 . 90.18 23. 107 PE 076 100 .05 9.02 . 90.18 23. 107 PV ALCOHOL 035 UNK < .08 44.09 22. .02 078 SILVER SHIELD 122 118 > 8.00 23. .01 227 VITON 009 118 .35 73.41 23. 2.00 227 A- 65 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST n-Octanot 290632830 NATURAL RUBBER NITRILE NITRILE+PVC PV ALCOHOL PVC 210 018 100 005 210 019 100 057 210 004 100 007 100 210 6.00 7.00 6.00 > 6.00 6.00 4.00 > 6.00 6.00 CHEMICAL NAME! CASNO PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MIpl 014 019 102 069 009 TEMP THICKNESS REF DEG C CM NUM 118 118 100 510 118 23. 177.35 23. 23. .02 23. 156.91 23. RES I STANT MATERIAL 1-Nitropropane 001080320 BUTYL NITRILE PV ALCOHOL TEFLON VITON 2-Ni tropropane 000794690 BUTYL NATURAL RUBBER NEOPRENE PV ALCOHOL n-Ni trosodimethytamine 000551850 CPE NonyL henoL 251545230 NEOPRENE NITRILE n-Octane 001116590 ‘ NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PVC .04 323 .04 323 .03 323 .05 303 .03 323 014 118 001 250 018 100 102 100 060 113 > 8.00 .20 > 15.00 > 3.00 .28 > 8.00 .03’ .72 > 8.00 - so .70 > 20.00 > 4 O0 -33 7:00 6.00 4.75 92 .75 1.00 > 7.00 23. .08 323 192.38 23. .02 323 144.29 23. .04 323 23. .06 323 23. .05 204 438.88 23. .05 204 23. .05 123 23. .04 123 018 019 001 002 005 057 007 001 017 002 100 100 210 210 210 210 210 210 100 100 NEOPRENE Oteic Acid 001128010 120.24 216.43 .02 72.14 108.22 10.22 .90 .90 .02 .90 .02 .90 .02 .90 .90 .02 .90 - 9.02 .90 .90 - 9.02 .90 .90 .90 .90 .90 - 9.02 .90 .90 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 080 ‘080 080 080 080 080 .05 107 107 080 .04 107 080 .06 107 • 080 107 • 107 080 .05 107 107 .04 107 .06 107 107 .107 107 107 107 107 NEOPRENE 002 100 018 100 NITRILE 019 100 NITRILE+PVC 058 . 100 : PV ALCOHOL PVC 076 ‘004 007 077 100 100 100 .50 2.50 1.00 > 6.00 > 6.00 > 6.00 1.00 1.50 > 600 > 6.00 A- 66 ------- SUMMARY OF PERFoRMANcE DETAIL TESTS PERMEATION TEST Oxatic Acid 001446270 Pentach Lorophenot 000878650 NEOPRENE NITRILE PV ALCOHOL PVC 118 210 100 100 210 100 > 8.00 6.00 > 6.00 6.00 6.00 > 6.00 > 8.00 6.00 > 6.00 8.00 6.00 > 6.00 > 6.00 > 6.00 6.00 > 6.00 6.00 > 8.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM MUM .07 323 080 .05 107 107 080 .04 107 .05 323 080 .06 107 .02 19. .04 323 .02 23. 080 23. 107 23. 107 23. 107 .02 23. 080 23. 107 23. 107 .02 20. .03 323 CHEMICAL NAME! CASNO PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS 014 001 017 002 018 005 019 RESISTANT MATERIAL BUTYL NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PVC VITON NATURAL RUBBER NEOPRENE NITRILE PVC 210 100 .02 19. .02 23. 23. 23. .02 23. 23. .02 19. .02 23. 23. 057 210 • 058 100 076 100 007 100 210 077 100 009 118 Patmitic Acid 000571030 017 002 018 019 007 100 100 100 100 100 Pentane 001096600 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE .08 > 6.00 > 6.00 .50 1.25 .10 .10 6.00 .12 3.00 .05 .03 .01 .06 .06 .09 .07 .03 .75 .11 .11 50. .08 .50 > -1.00 1 .08 > 1.00 002 100 018 100 019 100 004 100 007 100 001 210 017 100 120 502 504 026 102 008 114 002 100 120 210 018 100 118 120 23. 23. 23. 23. 23. 23. 23.’ 23. 23. 23. 23. 25. 25. 25. 25. 25. 25. 25. 23. 25. 25. 23. 23. 23. 25. 25. 25. .05 107 107 .04 107 .06 107 107 107 .04 107 .06 107 107 107 080 .03 222 .02 222 .05 222 .05 222 .06 222 .05 222 .05 222 107 .08 222 .07 222 080 .05 000 .04 107 .08 222 .05 222 .07 222 .90 .90 .90 90.18 ‘ 90L80 .90 913.82 2,705.40 5,711.40 1,803.60 1,803.60 1,603.20 1,803.60 2,304.60 .90 - 9.02 25.05 24.05 667.33 .28 90.18 - 901.80 2.00 10.02 2.00 A- 67 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST SILVER SHIELD VITON NATURAL RUBBER NEOPRENE NITRILE NI TRI LE+PVC PE PVC 018 120 005 210 019 100 503 057 210 058 100 006 100 505 076 100 004 100 102 100 003 120 500 501 007 210 122 118 009 118 .63 .33 6.00 .03 > 1.00 > 6.00 > 01.00 > 1.00 .09 1.25 .18 .01 .05 .08 > 6.00 .25 .01 .01 .15 .04 .01 .01 .02 .33 >• 6.00 > 8.00 > 8.00 16.03 25. .05 222 21.04 25. .03 222 .02 23. 080 .02 23. .04 323 2.00 25. .04 222 .90 23. .06 107 2.00 25. .06 222 2.00 25. .04 222 10.02 25. .03 222 90.18 23. 080 90.18 23. 107 400.80 25. .01 222 70.14 25. .01 222 901.80 23. 107 .90 23. 107 .02 23. .03 0 323 1,102.20 25. .01. 222 811.62 25. 0 .01 222 100.20 25. 0 .03 222 250.50 25. .02 222 721.44 25. .01 222 1,603.20 25. .01 222 1,603.20 25. .02 222 210.42 23. 080 23. .01 227 23. .02 323 23. .02 227 23. 23. 23. 23. 23. 23. .02 23. • 23. 23. 080 080 080 080 107 107 080 107 107 .02 .02 .02 -.02 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF HOURS UG/CM**2/MIN DEG C • CM HUM 9.02 90.18 CHEMICAL NAME/ RESISTANT •CASNO MATERIAL 001096600 NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL Pvc Perchtoric Acid 076019030 Perchtoric Acid, 30-70% 076019032 • NATURAL RUBBER NEOPRENE NITRILE PVC PhenoL (CarboLic Acid) 001089520 CPE NATURAL RUBBER 001 002 005 057 058 076 007 077 017 002 018 019 007 210 210. 210 210 100 100 210 100 100 • 100 100 100 •100 6.00 6.00 6.00 6.00 > 6.00 > 6.00 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 > 6.00 3.40 2.92 .58 > 1.00 1.00 .27 060 • 113 001 210 017 100 120 23. 23. 23. 23. 23. 23. 60.12 23. 23. 3.01 25. 9.02 - 90.18 23. 15.03 25. .05 107 107 .04 107 .06 107 107 .05 204 .05 204 080 .03 222 .05 107 .02 222 A-6 8 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO 001089520 RESISTANT MATERIAL - NATURAL RUBBER PRODUCT VENDOR DESC CODE 017 502 BREAKTHROUGH HOURS TIME PERMEATION RATE UG/CM**2/MIN TEMP DEG C 25. THICKNESS CM .05 REF NUM 222 > 1.67 3.01 504 > 1.00 3.01 25. .05 222 . > 1.00 3.01 25. .06 222 NEOP+NAT RUBBER 026 102 > 1.00 3.01 25. .05 222 NEOP/NAT RUBBER 008 114 • > 1.00 3.01 25. .05 222 NEOPRENE 002 100 > 6.50 .90 - 23. 107 > 1.65 3.01 25. .08 222 210 .67 23. 080 018 100 3.00 9.02 . 90.18 23. . .04 107 118 > 1.00 3.01 25. .08 222 • 120 > 1.00 3.01 25. .05 222 > 1.00 3.01 25. .07 222 > 1.00 3.01 25. .05 222 > 1.00 3.01 25. .03 222 NITRILE 005 210 .67 23. 080 019 100 . .93 300.60 25. .04 222 > 1.00 3.01 25. .06 222 .53 300.60 25. .04 222 503 .60 > 250.50 25. .03 222 NITRILE+PVC 057 210 2.00 23. 080 .PE 006 100 > 1.00 3.01 25. .01 222 505 1.00 3.01 25. .01 222 PV ALCOHOL 004 100 .50 9.02 . 90.18 23. 107 PVC . 003 120 .05 190.38 25. .01 222 .13 120.24 25. .01 222 .53 77.15 25. .03 222 . .25 100.20 25. .02 222 500 .10 130.26 25; .01 222 501 .10 120.24 25. .01 222 . .06 120.24 25. .02 222 007 100 1.25 .90 . 9.02 23. 107 . TEFLON 069 210 510 > 1.33 3.00 .02 23. 23. .05 080 .303 PhenoL, >70% 001089523 BUTYL . NEOPRENE NITRILE NITRILE+PVC PE PVC 014 018 125 019 058 076 007 077 118 100 103 103 118 100 1.00 103 100 . > > > 20.00 20.00 10.67 .58 .65 .83 6.00 .50 .02 18.04 1,274.54 > 9,018.00 .90 - 9.02 .90 18.04 .90 - 9.02 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. .06 .04 .05 .03 .04 323 227 000 045 045 323 227 107 107 045. 107 VITON 009 118 > > 1.50 15.00 15.00 .90 . 9.02 .02 23. 23. . 23. .03 .02 107 323 227 Phenolphthatein . . 000770980 NATURAL RUBBER NEOPRENE 017 018 506 100 > > 8.00 8.00 23. 23. .02 .04 323 323 . A- 69 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG’C CM NUN Phosphorus Oxych toride 100258730 .CPE NEOPRENE NITRILE+PVC NONWOVEN PE PV ACETATE PVC SARANEX VITON 060 UNK 002 UNK 018 UNK 058 UNK 071 UNK 124 UNK 007 UNK 061 UNK 009 UNK .83 .01 > 1.00 .57 .48 .08 .03 .01 .84 .26 23. 052 23. 052 23. .09 052 23. .06 052 23. 052 23. 052 23. 052 23. 052 23. 052 23. .03 052 1 -Piperazineethanamine 001403180 BUTYL 014 118 4.00 24.00 > 24.00 > 3.00 1 .00 .08 > 24.00 23. .05 123 BREAKTHROUGH TIME HOURS CHEMICAL NAME! RESISTANT . PRODUCT VENDOR • CASNO MATERIAL DESC CODE 000770980 NITRILE 019 .100 . PVC , 003 100 Phosphoric Acid 076643820 NATURAL RUBBER NEOPRENE 001 002’ 210 210 NITRILE 005 210 NITRILE+PVC 057 210 PE PVC 076 007 127 210 SARANEX 061 127 Phosphoric Acid, >70% 076643823 NATURAL RUBBER 017 100 102 026 102 > 8.00 . • 23. .04 323 > 8.00 23. .02 323 6.00 . < . .02 23. 080 6.00 < .02 . 23. 080 6.00 < .02 23. • 080 6.00 .02 23. 080 > 14.00 23. 104 6.00 < .02 23. 080 > 14.00 23. 104 > 6.00 23. .05 107 > 6.00 23. .05 026 > 6.00 23. .05 026 > 6.00 23. .05. 026 > 6.00 . 23. .05 026 > 6.00 23. .06 026 > 6.00 23. • .04 026 > 6.00 23 .05 026 > 6.00 23. 026 > 6.00 23. 107 > 6.00 • • 23. .04 107 > 6.00 23. .06 107 > 6.00 23. 107 > 6.00 23. > 6.00 . 23. 107 107 > 6.00 23.. • 107 NEOP+NAT RUBBER NEOP/NAT RUBBER •NEOPRENE NI TR I LE NITRILE+PVC PE PVC 008 002 018 019 058 076 007 077 102 100 100 100. 100 100 100 100 Potychtorinated Biphenyts (PCBs) (Aroctor) 013363630 BUTYL 014 118 CPE 070 UNK NATURAL RUBBER 017 UNK NEOPRENE 010 UNK 23. .04 23. .04 23. .05 23. .02. 23. .02 23. .03 290 290 004 290 290 290 A— 70 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST Propionatdehyde 001233860 BUTYL 014 118 > 13.00 23. .06 323 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS ‘PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEGC CM ‘ NUM CHEMICAL NAME!. RESISTANT CASNO MATERIAL 013363630 NEOPRENE PE PV ALCOHOL SARANEX TEFLON yuaN Potassium Hydroxide, 30-70% 013105832 ‘ NATURAL RUBBER ‘ ‘ 010 UNK > 24.00 “ 23. .03 290 . > 24.00 . 23. .03 290 > 24.00 . ‘23. .03 290 018 100 24.00 23. .04 290 , > 24.00 . . 24.00 . 23. .04 290 .04 290 . 24.00 23. .04 290 006 100 1.00 23. .01 290 .1.00 23. .01 .290 076 127 < 1.00 < .02 23. : ‘ 104 102 100 > 24.00 23. .05 290 ‘ > 24.00 23. .05 290 061 127 1.00 . 2.00 ‘ < .02 23. ‘104 6.00 ‘ ‘23. , 7.00 ‘ 23. ‘ 290 .02 290 7.00 • 23. .02 290 036 ‘ UNK > 24.00 ‘ ‘ 23. .01 > ‘24.00 ‘ 23. 290. .01 290 > 24.00 23. . 009 118 ‘ > 24.00 23. .01 290 .02 290 > 24.00 23. ‘ .02 ‘290 > ‘ 24.00 . ‘ 23. .02 290 001 210 1.33 23. 080 017 100 > ‘ 6.00 , NEOP+NAT RUBBER ‘ 026 ‘ , 121 ‘ > 8.00 < .02 ‘23. .05 107 .05 237 NEOPRENE . 002 ., ‘100 210 > 6.00 ‘3.00 • 23. 23. 107 080 . ‘ 018 100 > , Qo 23. .04 107 NITRILE 005. 210 6.00 < .02 23. 080 . 019 100 ‘ > 6.00 23. .06 NITRILE+PVC PE • 057 058 076 ‘ 210 100 100 > > 6.00 6.00 6.00 < .02 23. 23. .23. 080 107 107 Pvc 007 077 • . 100 210 100 > ‘ > 6.00 6.00 6.00 ‘6.00 “ < .02 ‘23. 23. 23. 23. 107 080 107 107 . ‘ 014 018 019 . 118 ‘100 100 > > 8.00 ‘8.00 8.00 ‘ ‘ < < .02 .02 .02 19. 19. ‘22. .06’ 323 .02 323 ‘.02 PVC ,. 007 ‘100 ‘ > .8.00 , .02 20. .05 323 NATURAL RUBBER 017 508 .25 . .33 4.31 22. ,PE 006 209 .17 . .50 1.20 22. 078 .01078 POLYURETHANE 050 ‘ 178 ‘ Promethazinehydrochtoride 000583330 BUTYL NEOPRENE NITRILE beta-Propi otactone 000575780 A-71 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST 001 210 017 100 002 100 210 C18 100 005 210 019 100 057 210 058 100 076 100 007 100 210 077 100 069 510 1.17 .33 > 6.00 1.50 2.50 6.00 > 6.00 6.00 .05 .05 1.50 2.00 .33 .25 > 3.00 9.02 .90 9.02 .90 6.01 .90 .02 .90 .02 .90 9.02 .90 - 9.02 .90 9.02 • 9.02 .90 - 9.02 .90 - 9.02 .02 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/MIN TEMP THICKNESS REF DEG C CM NLJM 018 100 .20 • 67.94 23. .05 .323 102 100 < .01 27.05 23. .04 323 009 118 < .01 85.37 23. .03 323 076 127 .05 1.62 23. 104 069 510 > 3.00 < .02 23. .05 303 076 127 .08 76.35 23. 104 014, 118 ‘ 2.70 172O 23. .04 227 017 100 .08 90.18 . 901.80 23. .05 107 019 100 .33 9.02 . 90.18 23. .06 107 118 .28 435.87 23. .04 227 076 100 ‘ .05 : .90 - 9.02 23. ‘ 107 004 100 2.00 ‘ 9O - 9.02 23. 107 122 118 > 6.00 23. • .01 227 CHEMICAL NAME! RESISTANT CASNO MATERIAL 001233860 NEOPRENE • . PV ALCOHOL VITON Propionic Acid 000790940 PE TEFLON Propionic Anhydride 001236260 PE Propyl Acetate 001096040 BUTYL NATURAL RUBBER NITRILE PE PV ALCOHOL SILVER SHIELD Propyt Alcohol (Propanot) 000712380 NATURAL RUBBER NEOPRENE NITRILE NI TR I LE+PVC PE Pvç TEFLON n-PropyL amine 001071080 CPE TEFLON Propylenediamine 000789000 BUTYL NEOPRENE PVC VITON 23. 23. .23. 23. 23. 23. 23. 23. 23 23. 23. 23. 23. 23. 23. 080 .05 107 107 080 .04 107’ 080 .06 107 080 107 107 107 080 107 107 .05 303 070 069 014 018 007 009 UNK 510 118 100 100 118 23. .05 004 .02 23. .05 303 .15 > 10.20 > 8.00 > . 8.00 .30 > 8.00 2.15 > ‘8.00 .03 > 8.00 PropyLene Dichloride (Dichloropropane 1,2) 000788750 BUTYL 014 118 PV ALCOHOL 102 100 PVC 007 100 VITON 009 118 17. 24. 17. 25. .07 323 .05 323 .02 323 .02 323 .02 .02 9.02 .02 190.38 .02 11,452.86 .02 23. .08 23. .07 23. .02 23. ‘.03 323 323 323 323 A—72 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/M IN TEMP THICKNESS REF DEC C CM NUM 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. O6 086 .05 086 .06 086 107 .01 086 107 107 107 .06 323 .02 323 107 107 .03 323 .03 303 .05 303 .03 323 CHEMICAL NAME/ RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE Propylene GLycoL 000575560 NATURAL RUBBER 001 017 503 120 NEOP/NAT RUBBER 008 114 NITRILE+PVC 058 100 PE 006 512 . 076 100 PVC 077 100 Propylene Oxide 000755690 BUTYL 014 118 NATURAL RUBBER 001 506 . PE 076 100 PV ALCOHOL 004 100 TEFLON 102 100 069 510 VITON 009 118 1,3-Propylene Oxide 005033000 BUTYL 014 118 NATURAL RUBBER 001 250 PV ALCOHOL 004 100 VITON 009 118 Propylmethacrylate . 022102880 BUTYL 014 118 NITRILE 019 100 PV ALCOHOL 004 100 PVC 003 100 Pyridine 001108610 NATURAL RUBBER 017 • 100 120 502 504 NEOP+NAT RUBBER 026 102 NEOP/NAT RUBBER 008 114 NEOPRENE 002 100 • 018 . 120 118 120 NITRILE 019 100 > 3.00 > 3.00 > 3.00 > 6.00 > 3.00 > 6.00 > 6.00 > 6.00 2.20 < .05 .58 .07 2.28 2.83 .02 1.13 .01 .17 .03 6.83 1.00 > 8.00 .03 .04 .03 .13 .20 .43 .14 .23 .65 .03 .85 .33 .63 .43 .07 .18 .25 .16 .09 .17 42.08 1,973.14 9.02 . 90.18 9.02 90.18 .90 .02 .02 10,769.30 561.12 30.06 3.01 30.06 48.10 150.30 .02 462.92 701.40 1,202.40 400.80 501.00 300.60 400.80 300.60 200.40 701.40 400.80 901.80 601.20 701.40 1,703.40 3,206.40 3,006.00 3,507.00 4,008.00 2,404.80 23. .07 323 23. .02 323 23. .03 323 23. 03 323 23. .08 323 23. .04 323 23. .07 323 23. .02 323 25. .03 222 25. .02 222 25. .05 222 25. .05 222 25. .06 222 25. .05 222 25. .05 222 25. .08 222 25. .07 222 25. .08 222 25. .05 222 25. .07 222 25. .05 222 25. .03 222 25. .04 222 25. .06 222 25. .04 222 25. .03 222 25. .03 222 181 503 A-73 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST. RESISTANT MATERIAL PE PRODUCT VENDOR DESC CODE 006 100 505 BREAKTHROUGH TIME HOURS > 1.00 > 1.00 PERMEATION RATE UG/CM**2/M IN < 100.20 25. 10.02 25. .01 222 .01 222 Cyanide, 30-70% 001433392 PE 076 127 < 4.00 .02 70. 104 Sodium Hydroxide, <30% 013107321. NEOP+NAT RUBBER Sodium Hydroxide, 30-70% 013107322 BUTYL BUT.YL/NEOPRENE NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE 064 . •117 110 117 001 210 UNK 015 UNK 017 100 008 UNK 002 100 210 018 100 UNK 093 117 138 117 139 117 127 117 005 210 019 . . 100 UNK 057 210. 058 117 071 127 076 117 127 003 UNK 007 100 210 UNK 049 117 8.00 > . 8.00 > 8.00 6.00 1.00 > 1.00 > . 6.00 > 1.00 > •6.00 6.00 > 6.00 > 1.00 > 1.OO• > 8.00 > 8.00 > 8.00 8.00 6.00 > 6.00 > 1.00 6.00 > 8.00 .17 > 8.00 > 8.00 > 1.00 6.00 6.00 > 1.00 > 8.00 > 8.00 23. 23. 23. .02 23. 23. 23. 23. 23. 23. .02 23. 23. 23. 23. 23. 23. 23. 23. .02 23. 23. 23. .02 23. 23. .63 23. 23. .02 23. 23. 23. .02 23. 23. 23. 23. .02 213 .01 213 .02 213 080 052 .04 052 .05 107 052 107 080 .04 107 .09 052 .06 052 .02 213 .03 213 .01 213 .02 213 080 .06 107 .05 052 080 .01 213 104 .01 213 104 .02 052 107 080 052 .01 213 ..01 213 CHEMICAL NAME/ CASNO 001108610 Sodium Cyanide, <30% 001433391 PE 076 TEMP THICKNESS REF DEG C CM HUM 127 Sodium Hydroxide 013107320 6.00 .02 60. 104 CPE NITRILE+PVC PE PVC SILVER SHIELD VI TON/CHLOROBUTYL 060 113 058 100 076 100 077 100 122 118 112 113 026 121 > 3.00 > 6.00 6.00 > 6.00 > 6.00 > 6.00 > 3.00. > 8.00 25. .07 302 23. 107 23. 107 23. 107 23. 107 23. .01 227 25. .04 302 .02 23. .05 237 NE OPRENE+PVC NITRILE NITRILE+PVC NONWOVEN PE PE PVC A- 74 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST •CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP UG/CM**2/MIN DEG C THICKNESS REF CM NUM 013107322 PVC 053 117 > • 8.00 • 23. .02 213 . SARANEX 144 061 117 117 > > •. 8 OO 8.00 23. 23. .02 .01 213 213 TEFLON VITON 069 009 127 510 UNK > > 8.00 71.00 1.00 < .02 23. 16. 23. .05 .03 104 303 052 145 117 > 8.00 23. .01 213 VITON/NEOPRENE 111 117 > 8.00 • 23. .02 213 • Sodium Hypochtorite, 30-70% 076815292 NATURAL RUBBER NEOPRENE 001 002 210 210 6.00 6.00 < < .02 .02 23. 23. 080 080 NITRILE 005 210 6.00 < .02 23. 080 NITRILE+PVC 057 210 6.00 < .02 23. 080 PVC 007 210 6.00 < .02 23. 080 060 113 1.00 . 1.17 001 210 .17 .20 .50 Styrene 001004250 SuLfuric Acid 076649390 002 125 005 019 057 058 076 004 007 210 103 210 103 210 100 100 100 103 210 348.70 517.03 30.06 733.46 456.91 186.37 9.02 - 90.18 9.02 - 90.18 .90 156.31 216.43 69.74 .02 CPE NATURAL RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC. SARANEX TEFLON VI TON/CHLOROBUTYL BUTYL BUTYL/NEOPRENE CPE NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NEOPRENE+PVC -NITRILE -NITRILE+PVC NONWOVEN PE PE PVC 25. .07 302 23. 080 23. 080 23. - 045 23. 080 23. 045 23. 080 23. 107 + 23. 107 23. . 107 23. 045 23. 080 -23. 104 23. .05 303 25. .04 302 23. .02 213 23. .01 213 23. .02 213 23. .02 213 25. .07 302 23. . .05 004 23. 080 .05 237 080 .02 213 .03 213 .02 213 .02- 213 080 080 .01 213 104 .67 • .07 .17 > 6.00 .33 .72 > 4.00 3.00 > 8.00 > 8.00 > 8.00 > 8.00 > 3.00 > 3.00 1.33 1.53 2.50 1.17 2.25 3.67 1.33 6.00 4.00 .42 .08 8.00 1.75 061 127 069 510 112 113 064 - 117 110 117 060 113 070 UNK 001 210 026 121 002 - 210 093 117 138 117 139 117 127 117 005 210 057 210 058 117 071 . 127 076. - 117 007 210 462.92 23. 23. 23. 23. 23. 23. .02 23. 23. 23. 3,006.00 23. - 23 23. .01 213 080 A-75 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! CASNO RESISTANT MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE UG/CM**2/M IN TEMP THICKNESS REF DEGC CM NUM SARANEX SILVER SHIELD VITON VI TON/CHLOROBUTYL VI TON/NEOPRENE 1.33 .42 > 8.00 > 6.00 > 8.00 > 3.00 > 8.00 23. .01 213 23. .01 213 23. .02 213 23. .02 213 23. .01 213 23. .01 213 23. .02 213 23. .01 213 23. 104 23. .01 227 • 23. .01 213 25. .04 302 23. .02 213 Sulfuric Acid, <30% 076649391 NEOP/NAT RUBBER NONWOVEN PE PE SARANEX 058 100 071 127 076 100 127 077 100 061 127 2.00 .50 > 5.00 > 8.00 3.00 2. > 8.00 > 3.00 > 6.00 )‘ 6.00 > 6.00 -> 6.00 > 6.00 > 6.00 > 6.00 6.00 .10 > 8.00 > 8.00 23. .92 23. 23. .02 23. 23. 23. • .02 23. .23. 23. 23. 23. 23. 23. 23. 23. 23, 4.51 23. .02 23. .02 23. 107 104 107 104 107 107 104 .05 004 .05 026 .05 026 .05 026 .05 026 .06 026 .04 026 .05 026 026 104 104 104 Sulfuric Acid, >70% 076649393 NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NI TRI LE NITRILE+PVC NONWOVEN PE PE > • 1.00 > 1.00 .62 .08 > 6.00 > 8.00 > 2.00 23. 23. 23. 23. 23. 23. 052 .04 052 052 107 .04 107 .09 052 23. .06 052 23. .05 052 23. 107 38.38 23. 104 23. • 107 .02 23. 104 .02 65. 104 076649390 .PVC 049 • 117 053 117 077 117 144 061 .42 .42 .08 .33 .42 > 8.00 117 117 127 122 118 145 - 117 112 1.13 111 117 NITRILE+PVC NONWOVEN PE PE PVC SARANEX Sulfuric Acid, 30-70% 076649392 CPE NATURAL RUBBER NEOP+NAT RUBBER 070 017 UNK 102 026 102 008 071 076 061 102 127 127 127 001 . UNK 015 UNK 008 UNK 002 100 018 100 UNK > 1.00 > 1.00 > 1.00 > 6.00 3.00 > • 1.00 019 058 071 076 UNK 100 127 100 127 PVC 003 • UNK 007 - 100 .15 3.67 23. 23. .02 052 107 A-76 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM Tannic Acid, 30-70% 014015542 NATURAL RUBBER 017 100 002 100 018 100 019 100 007 100 6.00 > 6.00 6.00 6.OO 6.00 .90 23. .90 23. .90 23. .90 23. CHEMICAL NAME! CASNO RESISTANT MATERIAL BREAKTHROUGH TIME HOURS 076649393 PVC SARANEX TEFLON VITON Tannic Acid 014015540 NITRILE+PVC PE PVC PRODUCT VENDOR DESC CODE 007 UNK 077 100 061 127 069 510 009 UNK 058 100 076 100 077 100 > 1.00 .25 1.00 5.50 > 8.00 > 72.00 > 1.00 6.00 > 6.00 > 6.00 ‘ . 6.00 23. 23. 23. 65. .02 23. .0225. 23. 23. 23. 23. 23. 052 107 - 107 104 104 .05 303 .03 052 107 107 107 107 .90 23. .05 107 107 .01. 107 .06 107 107 NEOPRENE NITRILE PVC 1,1,1 2 - Tetrach Loroethane 006302060 BUTYL PV ALCOHOL PVC VITON 1,1 ,2,2-Tetrachtoroethane 000793450 BUTYL NATURAL RUBBER NEOP+NAT RUBBER NEOPRENE NITRILE PE 138.28 23. 23. 330.66 23. 23. 014 102 .007 009 014. 017 026 002 018 .07 323 .08 323 .02 323 .03 323 118 100 100 118 118 100 120 502 504 102 100 120 118 120 100 2.30 > 8.00 .05 > 8.00 4.60 .11 .03 .09 .17 .35 .15 .10 .09 1.07 .53 .83 .30 .16 .37 1 .23 .22 .32 .07 .31 > 1.00 > 8.00 .02 .02 .10 019 23. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 25. 70.14 2,605.20 5,611.20 2,905.80 1,402.80 1,302.60 3,206.40 501.00 601.20 20.04 1 ,1O2.20 1,002.00 1,402.80 2,204.40 3,206.40 > 300.60 3,106.20 2,204.40 10.02 1,402.80 2.00 .02 5,410.80 6,012.00 503 006 100 114 .07 .03 .02 .05 .04 .06 .05 .08 .07 .08 .05 .07 .05 .03 .04 .06 .04 .03 .01 .05. .01 .04 .01 .01 .03 323 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 222 323 222 222 22? . 505 PV ALCOHOL 004 100 PVC 003 120 25. 23. 25. 25: 2,505.00 25. A- 77 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST cHEMIcAL NAME! RESISTANT CASNO MATERIAL • PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS PERMEATION RATE TEMP THICKNESS REF UG!CM**2/MIN DEG C CM NUM TEFLON VITON UNK 005 210 019 100 118 UNK 020 :. 100 191 UNK 003 100 118 UNK 007 • . 210 061 127 .17 .17 .13 .13 1.07 .10 .02 .02 .05 .12 .20 .10 .13 20 4.00. 5.00 1 .28 1.30 3.52 3.52 7.25 5.33 6.20 .08 .02 .02 .02 .02 .08 5.00 > 16.00 .60 .35 .80 > . 6.00 > 8.00 .01 .02 .02 .75 .27 .08 .03 > 6.00 4,008.00 25. .02 222 25. .01 222 .01 222 .01 222 .02 323 .05 303 .03 323 > .751.50 23. 751.50 23. 895.12 25. 895.79 23. 23. 601.20 23. > 751.50 23. 751.50 23. 1,478.95 23. 571.14 23. 980.29 25. 641.28 23. 641.28 23. 979.96 23. 6.01 23. .90 - 9.02 23. 33.07 23. 33.07 23. 28.26 23. 28.22 . 25. 47.09 23. 41.08 23. 90.18 23. 901.80 23. 686.37 23. 686.37 23. 769.87 25. 769.54 23. 901.80 23. .90 23. 23. 2.00 23. 11.62 23. 1.20 23. 23. 180.96 23. 744.82 25. 745.49 23. 114.23 23. .1.14 23. 10.02 23. 20.04 23. 23. .04 291 .04 291 • .04 288 .04 100 .05 004 080 .02 291 .02 291 .05 237 080 .05 288 .04 291 .04 291 .05 100 080 .06 107 .04 323 .04 227 .03 100 .03 288 .04 291 .04 291 080. 107 .01 291 .01 291 .01 288 .01 100 107 107 .04 323 .05 291 .05 291 .05 291 25. .05 288 .05 100 .02 323 .01 288 .01 100 080 104 .02 291 .02 291 .01 • 227 000793450 PVC .04 - .01 .02 .03 .01 > . 15.20 > • 8.00 003 120 500 501 007 . 100 069 • 510 009 118 014 118 UNK Tetrachtoroethytene (Perchtoroethylene) 001271840 BUTYL 4,108.20 25. 3,106.20 25. 70.14 23. .02 .23. .02. 23. CPE 070 UNK NATURAL RUBBER 001 017 210 UNK • NEOP+NAT RUBBER 026 121 . NEOPRENE 002 010 018 210 100 100 057 058 006 210 100 100 NITRILE NITRILE+PVC PE PV ALCOHOL PVC SARANEX SILVER SHIELD 90.18 - > > UNK 076 100 004 . 100 102 -. 100 90.18 122 118 A- 78 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL 001271840 TEFLON PRODUCT VENDOR DESC CODE 036 214 .43 > 24.00 069 510 > 10.40 1.80 009 118 > 17.00 > 17.00 3.17 3.00 > 24.00 > 24.00 > 24.00 > 24.00 ,> 6.00 UNK 8.00 2.30 23. ‘.01 23. .01 .02 23. .05 .25. .05 23 .03 23. .02 .02 .02 .02 23. .02 10. .02 10. .02 25. .02 23. .02 BREAKTHROUGH TIME PERMEATION RATE TEMP TH!CK•NESS REF HOURS UG/CM**2/MIN DEG C CM NUM 4.21 45. 4.21 45. 23. 291 291 303 303 323 227 291 291 291 291 291 291 288 100 012 017 018 009 014 018 102 009 VITON Tetraethytenepentamine 001125720 BUTYL NATURAL RUBBER NEOPRENE VITON Tetraf tuoroethytene 001161430 BUTYL NEOPRENE PV ALCOHOL VITON Tetrahydrofurar , 001099990 BUTYL BUTYL/NEOpRENE CPE NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 118 506 100 118 118 100 100 118 .09 323 .02 323 .05 323 .04 323 .06 • .06 .03 .03 323 323 323 323 014 118 064 117 110 117 060 113 070 UNK 017 100 120 502 504 .45 - > 8.00 1.77 > 8.00 > ‘ 8.00 > 8.00 > 8.00 > ‘ 8.00 > 8.00 .45 .52 .12 .10 .08 .08 .05 .20 .04 .02 .06 .04 .11 .06 .02 .03 .02 .33 .09 .23 .08 .05 .03 .08 25. 12.02 28. 27. 23. 23. 23. 23 23. 671.54 23. 673.34 23. 23. 23. 23. 23. 25. 23. > 16,699.98 25. > 16,699.98 25. >‘ 16,699.98 25. 3,507.00 25. 2,404.80 25. > 16,699.98 25. 16,699.98 25. 8,016.00 25. 9,619.20 25. 9,018.00 25. 16,O32.OO 25. .11,022.00 25. 14,028.00 25. > 16,699.98 25. 23. 829.66 23. 23. 026 008 002 018 093 125 138 .07 323 .04 , 227 .02 213 .01 213 .02 213 .02 213 .07 302 .05 004 .03 222 .02 222 .05 222 .05 222 .06 222 .05 222 .05 222 .08 222 .07 222 .08’ 222 .05 222 .07 222 .05 222 .03 222 .02 213 045 .03 213 102 114 100 120 118 120 117 103 117 A-79 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 1.80 .03 .43 .43 PERMEATION RATE TEMP THICKNESS REF UG/CM**2.IMIN DEG C CM NUN 90.18 24. 1,923.84 23. 1,725.44 23. 1,725.44 24. .05 323 .02 323 .04 323 .04 323 PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS 139 117 019 100 .10 23. .02 213 .04 222 .06 222 103 118 503 006 100 505 076 100 .10 3,707.40 25. .10 2,705.40 25. .08 4,308.60 931.86 1,005.81 1,004.00 3,507.00 200.40 4.01 .90 - 9.02 25. 23. 23. 23. 25. 25. 25. 23. 001099990 NEOPRENE NI TR I LE PE PV ALCOHOL PVC SARANEX TEFLON VITON VI TON/CHIOROBUTYL VITON/NEOPRENE N,N,N’,N’-Tetramethytenediamine ‘001101890 BUTYL NITRILE PVC VITON Thiophenol (Benzenethiot) 001089850 BUTYL PV ALCOHOL Totuene 001088830 BUTYL .01 .07 .04 .01 .05 .25 .10 4.72 .01 .01 .03 .02 .01 .01 .16 .03 > 5.50 .01 .07 .08 .15 .18 .17 1.08 1.08 1.80 102 003 049 061 069 009 145 112 111 012 014 019 117 100 120 500 501 117 117 510 118 117 113 117 118 118 100 .04 222 045 .04 323 .04 227 .03 222 .01 222 .01 222 107 .01 213 .03 323 .01 222 .01 222 .03 222 .02 222 .01 222 .01 222 .01 213 .01 213 .05 303 .03 323 .02 227 .01 213 .04 302 .02 213 .07 323 .07 323 .05 323 23. 2.52 23. 25. 25. 25. 25. 25. 25. 23. 23. .02 25.’, 1,964.09 23. 1,965.92 23. 23. 25. 23. 48.10 20. 48.10 ‘ 23.’ 90.18 23. 003 100 009 118 014 118 004 100 012 UNK . .28 2,024.04 21. .05 124 > 4.00 21. 124 .17 273.55 25. .04 273 .33 254.31 25. .04 273 .50 277.75 25. .06 273 .50 276.55 25. .06 273 .17 267.53 25. .04 273 .25 304.81 25. .04 273 .50 281.36 25. .06 273 .67 251.30 25. .06 273 .17 . 245.29 25. .04 273 .17 253.71 25. .04 273 .33 . 300.60 25. .06 273 A- 80 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 001088830 BUTYL 060 113 001 210 UNK 017 100 120 502 504 UNK 008 114 UNK 002 100 120 210 UNK 018 100 118 120 .50 .35 .28 .15 .18 .47 .18 .15 .70. 1.15 - 1.25 .15 .01 .28 .30 .03 .01 .06 .05 .07 .01 .08 .07 .03 .02 .15 .21 .20 .53 .23 .43 .28 .07 .52 .46 .21 .08 .08 .25 .33 .08 .12 .02 .37 .12 .31 1.00 .38 .32 .45 .35 1 .20 > 1.00 281.36 25. .06 273 132.87: 23. .06 323 1,503.00 22. .05 122 37. .06 122 25. .04 149 25. .04 149 25. .04 149 25. .04 149 25. .04 149 .07 302 080 .12 274 .19 088 .24 088 .03 222 .02 222 .05 222 .05 222 .06 222 .04 274 .05 222 .05 274 .08 222 .07 222 080 .05 186 .05 323 .08 222 .05 222 .07 222 .05 222 .03 222 .09 122 .09 274 .06 274 .04 273 .04 273 .06 273 .06 273 .04 149 .04 149 .04 149 .04 149 .04 149 .04 187 080 .04 122 .04 222 .06 107 37. .06 122 37. .06 122 400.80 37. .06 122 < 300.60 25. .06 222 PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS 012 UNK 014 118 2.16 107 UNK PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 59.12 69.14 1,503.00 167.33 141.28 637.27 >, 521.04 649 .30 913.82 4,709.40 9,218.40 2,705.40 3,607.20 2,805.60. > 521.04 4,709.40 > 541.08 1,002.00 2,605.20 499.00 CPE NATURAL RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE 25. 23. 23. 25. 25. 25. 25. 25. 25. 25. 23. 25. 23. 25. 25. 23. 23. 23. 25. 25. 25. 25. 25. 22. 23. 531.06 23. 274.75 25. 240.48 25. 274.75 25. 235.67 25. 3,509.00 25. 767.53 25. 400.80 25. 2,143.28 25. 2,732.45 25. 131.06 701.40 1,402.80 1,302.60 901.80 2,505.00 > 1,503.00 > 526.05 509 UNK 031 UNK 005 210 019 100 23. 330.66 23. 300.60 22. 701.40 25. 23. .17 90.18 . 901.80 A- 81 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 001088830 NITRILE NITRILE+PVC PE 181 503 509 UNK UNK 033 UNK 057 210 006 100 505 056 UNK 076 100 127 004 100 UNK 035 UNK BREAKTHROUGH TIME HOURS .24 .25 .16 .60 .18 .25 • 13 .28 .17 .55 .36 > 1.00 .33 .33 .58 .67 .12 .10 .11 .68 .13 .13 .23 .67 .01 .03 .12 .02 .08 25.00 .25 > 1.00 1.02 2.30 .02 .02 .01 .01 .05 .06 .20 .01 .01 .01 .20 .13 .47 .13 .50 .23 .28 .14 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 200.40 34. 300.60 22. 37. 501.00 25. 409.42 23. 200.40 22. 37. 200.40 22. 400.80 25. 801.60 25. 300.60 22. > 526.05 23. 23. 260.32 25. 201.40 25. 211.62 25. 238.68 25. 601.20 22. 37. 701.40 34. 501.00 22. 1,184.36 25. 1,244.48 25. 23. 365.73 23. 2,204.40 25. 601.20 25. 23. .90 - 9.02 23. 165.33 23. 22. .90 - 9.02 23. 23. 11.02 25. 90.18 25. 4.01 25. 317.63 25. 8,817.60 25. 5,110.20 25. 2,104.20 25. 1,803.60 25. 1,503.00 22. 5,310.60 25. 5,911.80 25. 4,809.60 25. 37. 300.60 22. 200.40 22. 300.60 34. 426.85 23. > 526.05 23. 23. 23. PRODUCT VENDOR DESC CODE 019 100 118 020 216 PV ALCOHOL PVC .04 122 .04 122 .04 122 .04 222 .04 227 .03 122 .04 122 .04 122 .03 222 .03 222 .06 122 .05 274 .05 274 .04 273 .04 273 .06 273 .06 273 .03 122 .04 122 .04 122 .09 122 .03 088 .03 088 .05 187 080 .01 222 .01 222 .01 187 107 104 .04 122 107 .12 274 .07 149 .07 149 .07 149 .07 149 .01 222 .01 222 .03 222 .02 222 .06 122 .01 222 .01 222 .02 222 .05 122 .06 122 .07 122 .05 122 080 .16 274 .07 186 .05 186 003 120 215 500 501 007 129 210 UNK A- 82 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST SARANEX SILVER SHIELD TEFLON VITON VI TON/CHLOROBUTYL VI TON/NEOPRENE p-Totuenesutfonic Acid 001041540 CPE 007 UNK .15 .15 .09 .08 .38 .08 > 6.00 > 3.00 > 18.50 > 16.00 .58 > 3.30 > 4.50 > 7.00 UNK > 1.00 PERMEATION RATE •TEMP THICKNESS REF UG/CM**2/MIN DEG C CM NUM 829.66 25. .13 088 25. .13 088 25. .10 088 25. .11 088 23. .03 187 2O.O4 23. 104 23. .01 227 .02 23. .05 303 .02 25. .05 303. .02 23. .02 227 37. .02 122 34. .03 122 22. .03 122 22. .03 122 23. .03 274 25. .04 302 37. .06 122 200.40 22. .06 122 .02 23. .05 303 PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS 049 UNK 061 127 122 118 069 510 009 118 859.72 898.79 829.66 CHEMICAL NAME/ RESISTANT CASNO MATERIAL 001088830 PVC Totuene Di isocyanate 264716250 BUTYL CPE NATURAL RUBBER NITRILE PE PV ALCOHOL SILVER SHIELD TEFLON V I TON 112 022 014 070 017 005 019 076 004 102 122 069 009 070 018 003 .113 216 118 UNK 100 120 118 100 100 100 118 510 118 UNK 100 215 > 3.00 1.67 4.20 > 8.00 > 8.00 > 3.00 .12 > 8.00 3.86 3.70 1.00 > 6.00 > 16.00 > 8.00 > 3.30 > 16.00 > 16.00 > 3.00 > 4.00 > 4.00 23. 23. 23. 9.02 . 90.18 23. 23. 10.82 23. 10.82 23. .90 - 9.02 23. .90 23.. 23 23. .02 23. 23. 23. .04 323 .04 227 .05 004 .05 107 .06 236 .03 323 .04 227 107 107 .03 323 .01 227 .05 303 .03 323 .02 227 NEOPRENE PVC o- Tot uidine 000955340 TEFLON TriaL Lytamine 001027050 NEOPRENE NITRILE PVC VITON Trichtoroacetatdehyde (Chtorat) 000758760 BUTYL PV ALCOHOL PVC 069 510 > 3.30 23. .05 004 23. .05 123 23. O5 123 018 100 019 100 007 100 009 118 1.05 > 8.00 .08 > .8.00 3.32 > 8.00 .07 014 102 007 19. .05 22. .04 20. .02. 17. .03 118 100 100 323 323 323 323 561.12 .02 621.24 .02. 50.10 .02 2,845.68, 23. .07 323 23. .08 323 23. .02 323 A- 83 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG/CM**2/MIN DEG C CM NUM 000758760 VITOW 009 118 7.28 .02 23. .03 323 Trichioroacetonitrite 005450620 BUTYL 014 118 1.98 316.23 23. .06 323 NEOPRENE 018 100 1.12 927.65 23. .06 323 PV ALCOHOL 102 100 > 8.00 23. .06 323 VITON 009 118 1.00 184.57 23. .03 323 1 ,2,4 Trichtorobenzene - 001208210 BUTYL 014 UNK .08 23. .04 290 .08 23. .04 290 NATURAL RUBBER 017 UNK .08 23. .02 290 .08 23. .02 290 NEOPRENE 010 UNK 4.00 23. .03 290 5.00 23. .03 290 018 UNK 1.00 23. .04 290 PE 006 UNK .17 23. .01 290 .17 23. .01 290 076 127 .25 5.01 23. 104 PV ALCOHOL 102 UNK 1.00 23. .05 290 1.00 23. .05 290 SARANEX 061 127 .25 - 1.00 .10 23 104 UNK 1.00 23. .02 290 1.00 23. .02 290 TEFLON 036 UNK 1.00 - 23. .01 290 8.00 23. .01 290 VITON 009 UNK .17 23. .02 290 .17 23. .02 290 1 ,1,2-Trichtoroethane 000790050 BUTYL 014 118 5.78 42.08 23. .09 323 UNK .83 23. .06 326 064 UNK .75 23. .04 326 NATURAL RUBBER 017 UNK .02 23. .02 326 NEOPRENE 018 UNK .12 23. .06 326 NITRILE 019 UNK .03 23. .02 326 PE 042 UNK .06 23. .01 326 POLYURETHANE 050 UNK .02 23. .01 326 PV ALCOHOL 102 100 8.00 23. .0.7 323 UNK .25 23. .04 326 PVC 003 118 .03 1,238.47 23. .02 323 TEFLON 036 UNK > 24.00 - 23. .01 326 044 UNK 2.92 23. .01 326 VITON 009 118 > 8.00 23. .05 323 UNK > 24.00 23. .03 326 2,2,2Trfchtoroethanot 001152080 SARANEX 061 127 .32 13.23 23. 104 Trichioroethylene (TrichLbroethene) 000790160 BUTYL 014 118 .23 3,308.40 23. .06 323 .08 > 826.65 23. .04 291 .08 > 826.65 23. .04 291 A-84 ------- - SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PERMEATION RAT.E TEMP THICKNESS REF UG/CM**2!MIN DEG C CM HUM 2,037.40 25. .04 288 3,306.60 23. .04 227 2,044.08 23. .04 100 23. 1,262.52 23. 9,418.80 25. > 16,699.98 25. 7,615.20 25. 6,813.60 25. PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS 014 118 UNK 070 UNK 001 210 017 100 120 502 504 UNK 026 102 008 114 002 100 120 210 UNK 010 100 018 100 118 120 .08 .22 .08 .20 .10 .03 .01 • 05 .05 .08 .02 .02 .05 .08 .03 .03 .13, .23 .08 .05 <- .07 .38 .05 004 080 ‘.03 222 .02 222 .05 222 .05 222 222 291 291 222 222 222 222 080 .05 186 .05 288 .04 291 .04 291 .08 222 5,310.60 25. .06 > 656.31 23. .02 > 656.31 23. .02 7,314.60 25. ‘.05 5,911.80 25. .05 1,903.80 25. .08 1,803.60 25. .07 1,160.32 23. 23. 2,187.70 25. > 566.13 23. > 566.13 23. 1,302.60 25. 000790160 BUTYL CPE NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NI TR I LE’ NITRILE+PVC PE PV ALCOHOL UNK .78 UNK .25 103 210 100 .33 .15 .43 .16 103 118 503 UNK .07 .13 .13 .16 .14 2,304.60 25. .05 222 .25 2,104.20 25. .07 222 .20 1,903.80 25. ‘ .05 222 .06 . 4,208.40 25. .03 222 2,194.38 23. .05 100 031 .17 - 53.11 22. .08 078 125 823.64 23. , 045 005 - 1,106.21 23. 080 019 ‘ 2,004.00 25. .04 222 901.80 25. .06 222 2,104.20 1,791.58 25. 23. .04 222 045 - 1,701.40 23. .04 323 1,701.40 23. .04 227 1,603.20 25. .03 222 ‘ 1,647.29 23. .03 100 020 100 503 < .16 .25 > 1,646.62 826.65 25. 23. .03 .04 288 291 ‘ . .18 > 826.65 23. .04 291 033 UNK .17 - .25 60.12 22. - .09 078 057 210 .50 1,244.48 23. 080 058 - 100 .05 901.80 - 9,018.00 23. 107 006 100 < .02 > 657.31 23. .01. 291 < .02 - > 657.31 23. .01 291 - 076 UNK 100 - .01 .02 .08 9.02 - - 1,503.00 1,394.45 1,394.78 90.18 - 25. 25. 23. 23. .01 .01 .01 ‘ 222 288 100 107 004 100 .50 < .90 23. 107 035 UNK < .25 8.02 22. .01 078 102 100 > 16.00 23. .04 323 -- A-85 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL 000790160 PV ALCOHOL SARANEX SILVER SHIELD TEFLON VITON 1,2,3-Trichtoropropane 000961840 BUTYL NITRILE PV ALCOHOL VITON PRODUCT VENDOR DESC CODE 102 100 UNK 003 118 120 500 501 UNK 007 103 210 UNK 077 100 061 127 122 118 036 214 069 510 009 118 • BREAKTHROUGH TIME HOURS 24.00 24.00 24.00 24.00 24.00 24.00 > 6.00 8.00 .02 .01 .01 .05 .01 .01 .01 .01 .02 .33 .16 .08 .07 .05 .02 .02 > 6.00 > 24.00 >‘ 24.00 2.38 2.43 2.60 7.35 > 24.00 > 24.00 .80 .80 7.40 10.00 12.00 > 6 o0 > 8.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEGC CM NUM 23. .05 291 23. .05 291 10. .05 291 10. .05 291 45. .05 291 45. .05 291 25. .05 288 23. .05 100 25. .01 288 25. .01 222 25. .01 222 25. .03 222 25. .02 222 25. .01 222 25. .01 222 25. .02 222 .23. .01 100 23. 045. 23. 080 23. .07 186 23. .05 186 23. 107 23. . 107 23. .02 291 23. .02 291 23. .01 227 23. .01 291 23. .01 291 .03 23. .05 303 .03 23. .05 303 O3 23. .05 303 1.44 23. .03 323 10. .02 291 10. .02 291 23.05 45. .02 291 21.04 45. .02 291 1.40 23. .02 227 1.60 23. .02 291 1.70 23. .02 291 25. .02 288 23. .02 100 PVC 1 ,015.36 11,022.00 9,018.00 3,807.60 8, 216. 40 13,026.00 13,026.00 6, 212. 40 1,016.03 901.80 1,256.51 90.18 901.80 - > > 901.80 9,018.00 310.62 290.58 UNK 014 118 019 100 004 100 009 118 Tricresyt Phosphate (Tritotyt Phosphate) 013307850 BUTYL 012 NATURAL RUBBER 017 NEOPRENE 002 018 .02 20.04 .02 • .02 > 8.00 .35 > 8.00 > • 8.00 > 8.00 .75 > 6.00 > 6.00 23. 23. 23. 23. 118 100 100 100 .06 323 .04 323 .03 323 .03 323 .07 323 .05 107 107 .04 107 23. .90 23. .90 23. .90 23. A- 86 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT VENDOR DESC CODE BREAKTHROUGH TIME HOURS PERMEATION RATE TEMP. THICKNESS REF UG, CM**2/MIN DEG C CM HUM CPE NEOPRENE NITRILE PVC VITON Tn ethyL enetet raami ne 001122430 BUTYL NEOPRENE NITRILE VITON 070 UNK 018 100 019 118 020 216 007 100 009 118 > 3.00 .62 > 8.00 > 4.00 .07 > 8.00 > 8.00 > 8.00 > 8.00 > 8.00 013307850 Tniethanotamine 001027160 TriethanoLamine, 001027163 Tniethytamine 001214480 NITRILE 019 100 > 6.00 < .90 23. .06 107 NITRILE+PVC 058 - 100 > 6.00 . • :23.. 107 PE 076 100 > 6.00 23. 107 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 . . > 8.00 23. .08 323 PVC 003 100 > 8.00 23. .02 323 . 007 077 100 100 . > > > 6.00 6.00 6.00 . < .90 23. 23. 23. 107 107 107 VITON 009 - 118 > 8 OO 23. .04 323 NITRILE+PVC 058 100 > 6.00 23. 107 PE 076 100 > 6.00 23. 107 PVC 077 100 > > 6.00 6 OO 23. 23. 107 107 >70% • . . . . . NATURAL RUBBER 017 - 100 1.00 < :90 23. .05 107 NEOPRENE 002 100 > 6.00 < .90 23 107 . 018 100 > 6.00 < .90- 23. .04 107 NITRILE 019 100 > 6.00 < .90 23. .06 107 PV ALCOHOL 004 100 > 6.00 < .90 23. 107 PVC 007 100 > 6.00 . < .90- 23. -107 23. .05 004 811.62 20 .05 323 .02 19.L .04 323. 23. .04 123 290.58 20. .02 323 .02 24. .03 323 .02 20. - .06 323 • .02. 19. .05 323 .02 16. .04 323 .02 20. .03 323 TriftuoroethanoL 000758980 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE 014 118 018 100 019 100 009 118 017 100 120 502 504 026 102 008 114 002 100 - - 120 018 118 120 > 1.00 • < 4.01 25. .03 222 > 1.10 < 4.01 25. .02 222 > 1.33 < 4.01 25. .05 222 > 1.07 < 4.01 25. .05 222 > 1.65 < 4.01 25. .06 222 > 1.65 < 4.01 25. .05 222 > 1.02 < 4.01 25. .05 222 > 1.00 - < 4.01 25. .08 222 > 1.00 < 4.01 25. .07 • 222 > 1.00 < 4.01 25. .08 222 > 1.00 < 4.01 25. .05 222 > 1.00 < 4.01 25. - .07 222 > 1.00 < 4.01 25. .05 - 222 A- 87 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR BREAKTHROUGH TIME PERMEATION RATE TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS UG, CM**2/MIN DEG C CM NUM 000758980 NEOPRENE 018 120 1.00 4.01 25. .03 222 NITRILE 019 100 .33 1,903.80 25. .04 222 .97 1,102.20 25. .06 222 .28 2,304.60 25. .04 222 503 .12 3,106.20 25. .03 222 PE 006 100 1.00 4.01 25. .01 222 505 1.00 4.01. 25. .01 222 076 127 > 8.00 .02 23. 104 PVC 003 120 .08 1,202.40 25. .01 222 .12 1,903.80 25. .01 222 .25 1,302.60 25. .03 222 .11 1,102.20 25. .02 222 500 .04 1,002.00 25. .01 222 501 .07 300.60 25. .01 222 .05 901.80 25. .02 222 Tri-n propyLarnine 001026920 . NEOPRENE 018 100 > 8.00 23. .05 323 NITRILE 019 100 8.00 23. .04 323 PV ALCOHOL 102 100 > 8.00 23. .06 323 VITON 009 118 > 8.00 23. .04 323 Turpentine 080066420 NEOP+NAT RUBBER 026 121 . .07 264.53 23. .05 237 NITRILE 019 100 .50 .90 23. .06 107 PV ALCOHOL 004 100 6.00 .90 23. 107 TEFLON 069 510 3.60 .02 23. .05 303 VaLeronitrite 001105980 BUTYL 014 118 > 8.00 .02 23. .07 323 NATURAL RUBBER 017 506 .03 126.25 23. .02 323 NEOPRENE 018 100 .68 126.25 23. .05 323 PV ALCOHOL 004 100 > 8.00 - .02 23. .07 323 Vinyl Acetate 001080540 TEFLON 069 510 1.23 . .05 23. .05 303 2.28 .05 23. .05 303 Vinyl Chloride (Chloroethene) 000750149 CPE 070 UNK > 3.00 23. .05 004 NITRILE 019 103 .02 23. 045 118 5.70 .84 23. .04 227 SILVER SHIELD 122 118 6.00 23. .01 227 VITON 009 118 4.40 .58 23. .04 227 4-Vinyl-1-cyclohexane 001004030 BUTYL 012 118 .52 354.71 23. .07 323 NITRILE 019 100 6.53 1.20 23. .04 323 PV ALCOHOL 004 100 .90 23. .09 323 VITON 009 118 > 8.00 23. .04 323 Vinytidene FLuoride 000753870 BUTYL 014 UNK > 8.00 23. .07 323 A- 88 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 000753870 NATURAL RUBBER NEOPRENE PVC VITON PRODUCT VENDOR DESC CODE 001 250 018 100 BREAKTHROUGH TIME HOURS .02 > 5.00 .02 .02 > 8.00 PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM HUM .02 323 .05 323 .05 323 .02 323 .04 323 Xytene 001332070 NATURAL RUBBER NEOP+NAT RUBBER NEOP/NAT RUBBER NEOPRENE NITRILE NITRILE+PVC PE PV ALCOHOL PVC TEFLON VITON 6.01 .37 003 100 009 118 • . 23. 23. 001 210 .12 444.89 017 100 .04 3,406.80 23. 25. 080 120 .02 25. .03 222 502 .08 3,707.40 .02 222 504 .08 .13 2,805.60. 2,404.80 25. 25. .05 .05 222 222 026 102 .07 .07 30.06 23. .06 .06 222 026 008 102 .07 30.06 23. .05 026 114 .12 2,505.00 23. 026 002 100 .06 501.00 25. .05 222 120 .05 601.20 222 210 .13 408.82 25. .07 222 018 118 .73 . 701.40 080 120 .23 .30 .38 • 1,302.60 1,402.80 801.60 25. 25. 25. .08 .05 .07 222 222 222 .09 3,406.80 25. .05 222 031 511 . .27 - 492.98 .03 222 125 103 30.06 23. 323 005 210 1.67 300.60 045 019 100 > .80 1.25 1.00 .95 .45 100.20 90.18 - 901.80 . 50.10 100.20 168.34 23. 25. 23. 25. 25. .04 .06 .06 .04 080 222 107 222 222 103 84.17 .05 323 503 .47 300.60 23. 045 210 .75 330.66 .03 222 100 > .05 9.02 - 90.18 23. 23. 080 505 .07 107 • 100 .08 9.02 100.20 90.18 25. .01 222 100 > 6.00 .90 23. 23. 107 100 > 8.00 107 100 .02 23 .09 323 120 .03 .02 .08 192.38 3,006.00 3,507.00 23. 25. . 25. 25. .02 .01 .01 323 222 222 500 .01 4,509.00 25. .02 222 501 .01 .03 3,507.00 2,104.20 25. 25. . .01 .01 222 222 007 103 72.14 .02 222 210 .66 389.11 23. 045 069 510 > -3.00 .02 23. 080 009 .05 303 057 058 006 076 004 102 003 A- 89 ------- SUMMARY OF PERFORMANCE DETAIL TESTS PERMEATION TEST CHEMICAL NAME/ RESISTANT CASNO MATERIAL PRODUCT VENDOR BREAKTHROUGH TIME DESC CODE HOURS PERMEATION RATE TEMP THICKNESS REF UG/CM**2/MIN DEG C CM HUM NEOPRENE NITRILE PV ALCOHOL VITON 014 118 018 100 019 100 118 120 020 503 102 100 009 118 .17 .23 1 .03 1.62 .27 .65 .55 > 12.67 > 16.00 8.00 .06 323 .05 086 .06 086 .04 323 .06 086 .04 086 .05 086 .04 086 .03 323 .03 323 23. .04 086 m-XyLene 001083830 - BUTYL .65 87.78 23. 228.79 23. 198.55 23. 188.78 23. 72.14 23. 396.79 23. 198.73 •23. 180.36 23. 23. 23. o-Xytene 000954760 p-Xytene 001064230 014 118 060 113 019 100 102 100 009 118 BUTYL CPE NI ’TP.ILE PV ALCOHOL VITON BUTYL NITRILE PV ALCOHOL PVC VITON .87 1 .20 1.05 .20 > 12.67 > 8.00 .45 .87 > 14.00 .01 > 16.00 014 019 102 003 009 118 100 100 100 118 116.63 23. 23. 186.37 23. 179.76 23. 23. 23. 90.78 23. 85.97 23. 23. 185.17 23. 23. .07 323 .05 204 .05 204 .04 323 .03 323 .03 323 .07 323 .04 323 .03 323 .02 323 .03 323 A- 90 ------- APPENDIX B WEIGHT CHANGE DATA B—i ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! CASNO RESISTANT MATERIAL PRODUCT. VENDOR DESC CODE PERCENT WEIGHT CHANGE IMMERSION TIME HOURS TEMP THICKNESS REF DEG C CM NUM 076644171 PE Acetic Acid, <30% 000641971 PE 041 UNK 042 UNK 048 UNK .90 8,760.00 .80 8,760.00 .80 8,760.00 Acetic Acid 000641970 .01 8,760.00 .01 8;760.OO .01 8,760.00 041 UNK 042 UNK 048 UNK 060 113 001 UNK 002 UNK 005 UNK 27.00.. 28.00 31.00 -1.00 4.00 -2.00 24.00 24. oO 24.00 1.00 1 .00 1.00 23. 23. 23. 23. 23. 23. 25. 25. 25. 23. 23. 23. 305 305 305 .05 204 .05 204 .05 204 208 208 208 305 305 305 .05 •236 .05 236 .05 236 .05 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .08 236 .08 236 .08 236 .08 236 CPE NATURAL RUBBER NEOPRENE NITRILE Acetic Acid, 30-70% 000641972 NATURAL RUBBER NEOPRENE NITRILE PVC Acetic Anhydride 001082470 BUTIL CPE NATURAL RUBBER NEOPRENE PVC Acetone 000676410 BUTYL CPE NATURAL RUBBER 1 .00 4.00 .08 .50 23. .08 23. 23. 23. 23. .50 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. .08 23. 1.00 4.00 .08 .50 1.00 4.00 4.00 1.00 .50 001 120 010 120 005 120 003 120 014 118 060 113 001 250 018 100 007 100 014 UNK 060 113 001 120 1.00 .01 1.00 8.00 .01 2.00 .01 2.00 1.00 3.00 4.00 10.00 3.00 1.00 .01 1.00 1 .00 6.10 2.70 8.20 4.00 16.00 -12.00 .90 50.00 58.00 64.00 3.00 4.00 23. .09 323 23. .05 204 23. .05 204 23. .05 204 20. .02 323 20. .05 323 20. .02 323 8.00 24.00 24.00 24.00 8.00 8.00 8.00 24.00 .58 .25 .25 .08 .50 22.. 23. 23. 23. 23. 23. 201 .05 204 .05 204 .05 204 .05 236 .05 236 B— 2 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUM 000676410 NATURAL RUBBER 001 120 4.00 1.00 23. .05 236 3.00 4.00 23. .05 236 UNK -2.00 1.00 25. . 208 017 . UNK -2.00 24.00 22. 201 NEOPRENE 002 LINK -3.00 1.00 25. . 208 010 120 1.00 .08 23. .06 236 7.00. .50 23. . .06 236 8.00 1.00 23. .06 236 4.00 4.00 23. .06 236 018 UNK -1.40 24.00 22. 201 -.30 24.00 . 22. 201 -8.00 24.00 22. 201 -.70 24.00 22. 201 NITRILE 005 120 9.00 4.00 23. .06 236 55.00 1.00 23. .06 236 32.00 .50 23. .06 236 17.00 .08 .23. .06 236 UNK -3.00 1.00 25. 208 020 UNK 2.70 24.00 22. 201 PE 041 UNK 1.00 8,760.00 23. 305 042 UNK 1.20 8,760.00 23. 305 048 UNK 1.20 8,760.00 23. 305 PV ALCOHOL 102 UNK -15.70 24.00 22. 201 PVC 003 120 2.00 4.00 23. . .08 236 29.00 1.00 23. .08 236 30.00 .50 23. .08 236 14.00 .08 23. .08 236 UNK -16.10 24.00 22. 201 Acetonitrite . . 000750580 NEOPRENE 010 120 .01 .08 23. .06 236 1.00 .50 23. .06 236 .01 1.00 23. .06 236 1.00 4.00 23. .06 236 Attytamine 001071190 BUTYL 014 118 15.00 . 8.00 20. .06 323 NATURAL RUBBER 001 250 34.00 8.00 20. .01 323 PV ALCOHOL 102 100 14.00 8.00 23. .07 323 PVC 007 100 -6.00 8.00 20. .02 323 Attyt Gtycidyl Ether 001069230 . BUTYL 014 UNK 1.00 24.00 22. 201 NATURAL RUBBER 017 UNK 7.00 24.00 22. 201 NEOP/NAT RUBBER 008 UNK 9.40 24.00 22. 201 NEOPRENE 018’ LINK 1.40 24.00 22. 201 12.90 24.00 22. 201 - .50 .50 24.00 22. 201 NITRILE 020 UNK 3.20 24.00 22. 201 PV ALCOHOL 102 UNK 5.20 24.00 22. 201 PVC 003 UNK 6.40 24.00 22. 201 Amonium Hydroxide, <30% . . B—3 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO : MATERIAL DESC CODE HOURS DEG C CM NUM 013362161 NATURAL RUBBER 001 120 1.00 4.00 23. .05 236 1.00 1.00 23. .05 236 .01 .50 23. .05 236 .01 .08 23. .05 236 NEOPRENE 010 120 1.00 .08 23. .06 236 .01 .50 23. .06 236 1.00 1.00 23. .06 236 1.00 4.00 23. .06 236 NITRILE 005 120 2.00 4.00 23. .06 236 2.00 1.00 23. .06 236 1.00 .50 23. .06 236 1.00 .08 23. .06 236 PVC 003 120 .01 .08 23. .08 236 1.00 .50 23. .08 236 1.00 1.00 23. .08 236 • 1.00 4.00 23. .08 236 Amonium Hydroxide, 30-70% 013362162 NATURAL RUBBER 001 UNK -1.00 1.00 25. 208 NEOPRENE 002 UNK .01 1.00 25. 208 • NITRILE 005 UNK .01 1.00 25. 208 Amyt Acetate (Pentyt Acetate) 006286370 NATURAL RUBBER 001 UNK -2.00 1.00 25. 208 NEOPRENE 002 UNK -4.00 1.00 25. 208 .NITRILE 005 UNK -1.00 1.00 25. 208 Amyt ALcohoL (Pentanot) - 000714100 BUTYL 014 118 .40 8.00 23. • .07 323 NEOPRENE 018 100 4.00 8.00 23. .05 323 NITRILE • 019 100 9.00 8.00 23. .04 323 VITON 009 118 4.00 8.O 23. .05 323 AniLine (Benzamine) 000625330 NATURAL RUBBER 001 120 2.00 .50 23. .05 236 3.00 1.00 23. .05 236 5.00 •- 4.00 23. .05 236. 2.00 .08 23. .05 234 NEOPRENE 010 120 9.00 4.00 23. .06 236 5.00 1.00 23. .06 236 4.00 .50 23. .06 236 5.00 .08 23. .06 236 • NITRILE 005 • 120 38.00 1.00 23. .06 236 • 126.00 4.00 23. .06 236 • • 24.00 .50 23. .06 236 15.00 .08 23. .06 236 • PVC 003 - 120 4.00 .08 23. .08 236 12.00 1.00 23. .08 236 • 20.00 • 4.00 23. .08 236 - 10.00 • .50 23. .08 236 Benzene 000714320 BUTYL 014 118 117.00 168.00 23. •327 B— 4 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUN 000714320 BUTYL 034 UNK 60.00 168.00 22. 078 12.00 3.00 25. 126 064 UNK 55.50 168.00 23. 327 EVA 074 100 254.00 168.00 23. 327 NATURAL RUBBER 017 100 309.00 168.00 23. 327 310.00 168.00 23. 327 214 286.00 168.00 23. 327 508 320.00 168.00 22. 078 UNK 362.00 168.00 23. 327 351.00 168.00 23. 327 346.00 168.00 23. 327 NEOP/NAT RUBBER 008 114 280.00 168.00 22. 078 NEOPRENE 018 100 262.00 168.00 23. 327 120 190.00 168.00 23. 327 UNK 176.00 168.00 23. 327 031 LINK 90.00 168.00 22. 078 NITRILE 019 100 161.00 168.00 23. 327 120 150.00 168.00 23. 327 166 165.00 168.00 23. 327 020 LINK 104.00 168.00 23. 327 104.00 168.00 23. 327 033 UNK 110.00 168.00 22. 078 NONWOVEN PE 071 100 218.00 168.00 23. 327 UNK 162.00 168.00 23. 327 PE 006 209 30.00 168.00 22. 078 042 100 32.70 168.00 23. 327 113.00 168.00 23. 327 075 100 257.00 168.00 23. 327 POLYURETHANE 050 178 60.00 168.00 22 078 PV ALCOHOL 004 100 3.00 168.00 22. 078 PVC 003 100 -15.10 168.00 23. 327 120 -8.00 168.00 23. 327 -12.40 168.00 23. 327 -8.10 168.00 23. 327 214 - .50 168.00 23. 327 SARANEX 061 200 93.00 168.00 23. 327 TEFLON 036 214 4.90 168.00 23. 327 VITON 009 118 20.00 168.00 23. 327 032 LINK 4.00 168.00 22. 078 Boric Acid 100433530 BUTYL 014 118 2.00 8.00 20. .07 323 NEOPRENE 018 100 2.00 8.00 19. .05 323 NITRILE 019 100 2.00 8.00 21. .04 323 VITON 009 118 .20 8.00 20. .03 323 2-Bromoethanot 005405120 BUTYL 014 118 .20 8.00 23. .09 323 NATURAL RUBBER 001 250 2.00 8.00 23. .02 323 PVC 003 100 - .20 8.00 23. .02 323 VITON 009 118 .60 8.00 23. .05 323 Butyt Acetate B— 5 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST iso-Butytamine (Methytpropytamine, 2-) 000788190 BUTYL NEOPRENE PV ALCOHOL nButyl Chloride 001096930 PVC PVC VITON PERCENT WEIGHT CHANGE IMMERSION TIME HOURS TEMP THICKNESS REF DEG C CM NUM 23. .05 323 23. .80 323 23. .20 323 23. .05 323 CHEMICAL NAME! CASNO 001238640 Butylarnine 001097390 RESI STANT MATERIAL PE BUTYL NATURAL RUBBER NEOPRENE PVC sec-Butytamine 139528460 tert-Butylamine 000756490 23. 305 23. 305 23. 305 15. .10 323 20. .02 323 18. .05 323 18. .02 323 28. .09 323 26. .05 323 23. .07 323 28. .02 323 21.. .09 323 25. .05 323 14. .04 323 24. .02 323 15.. .09 323 23. .05 323 21.. .04 323 20. .‘ .02 323 PRODUCT VENDOR DESC CODE 041 UNK 042 UNK 048 UNK 014 118 001 250 018 100 007 100 014 118 018 100 102 100 007 100 BUTYL 014 118 NEOPRENE 018 100 NITRILE 019 100 PVC 007 100 BUTYL 014 118 NEOPRENE 018 100 NITRILE 019 100 PVC 007 100 (Chtorobutane, 1-) NITRILE 019 100 PV ALCOHOL 004 100 003 100 009 118 Butyra Idehyde 001237280 BUTYL 034 UNK Carbon Disutfide (Carbon Bisutfide) 000751500 BUTYL 034 UNK NITRILE 005 120 ..PE 041 UNK 042 UNK 048 UNK Carbon Tetrachioride (Tetrachtoromethane) 000562350 CPE 060 113 NEOPRENE 010 120 3.40 3.40 4.10 62.00 148.00 166.00 62.00 37.00 50.00 -8.00 13.00 83.00 122.00 108.00 -4.00 23.00 55.00 69.00 -20.00 100.00 -5.00 -11.00 6.00 7.70 12.50 74.00 7.00 21.00 16.00 8.00 12.90 21.40 36.80 107.00 116.00 106.00 38.00 8,760.00 8,760.00 8,760.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 3.00 20.00 3.00 4.00 1.00 .50 .08 8,760.00 8,760.00 8,760.00 1.83 1.83 1.83 1.00 25. 126 25. 126 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. 305 23. 305 23. 305 23. .05 204 23. .05 204 23. .05 204 23. .06 236 B— 6 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST Ch Lorodibromomethane 001244810 BUTYL PV ALCOHOL PVC VITON 23. .10 323 23. .07 323 23. .02 323 23. .04 323 28.00 13.00 18.00 21.00 11.00 5.00 3.00’ 16.30 22.80 37.90 .06 .06 .06 .06, .06 .06 .06 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 236 236 236 236 236 236 236 305 305 305 .08 8,760.00 8,760.00 8,760.00 CHEMICAL NAME! RESISTANT CASNO MATERIAL PRODUCT DESC CODE VENDOR ‘ PERCENT WEIGHT CHANGE IMMERSION TIME HOURS TEMP DEG C THICKNESS CM REF , 000562350 NEOPRENE 010 120 .50 ‘ .08 ‘ 4.00 NITRILE 005 120 4.00 ‘ . 1.00 .50 ‘ PE 041 UNK ‘ 042 UNK . 048 UNK ‘ Chtorobenzene . 001089070 BUTYL 014 118 169.00 8.00 23. .07 323 PV ALCOHOL 102 100 -4.00 8.00 23. .08 323 PVC 007 100 101.00 8.00 ‘ 23. .02 323 VITON 009 118 2.00, 8.00 23. .03 323 . 012 004 ‘ 003 118 100 100 382.00 -.30 385.00 8.00 8.00 ‘ 8.00 009 118 ‘ 1.00 8.00 , Chloroform (TrichLoromethane) . ‘ . 000676630 BUTYL 034 UNK 9.00 3.00 25. 126 NEOPRENE 010 120 23.00 .08 23. .06 236 ‘ 39.00 .50 23. .06 236 ‘ ‘ 110.00 1.00 23. .06 236 0 ‘ 35.00 4.00 23. .06 ‘ 236 PE 041 ‘ 042 UNK UNK 12.00 16.20 , 8,760.00 8,760.00 23. 23. 305 305 0 048 UNK 2510 8,760.00 23. 305 , 3-ChLoro2-methyLpropene 0 0 0 005634730 BUTYL ‘ 014 118 142.00 8.00 23. ‘ .06 323 PV ALCOHOL 004 100 , 28.00 8.00 ‘ 23. .04 323 PVC . 007 100 200 8.00 23. .02 323 VITON 009 118 7.00 , 8.00 23. .03 323 2-ChLoro-2-nitropropane 0 005947180 BUTYL 012 118 2.00 8.00 23. .09 323 ‘NATURAL RUBBER 017 506 . , 94.00 8.00 23. .02 323 PV ALCOHOL 004 100 -.80 8.00 23. .07 323. VITON 009 118 70.00 8.00 23. .04 323 Chromic Acid, 30-70% 111157452 NITRILE 005 120 . .01 .08 0 23. .06 236 236 4.00 .50 23. .06 0 - 3.00 1.00 23. .06 236 0 0 , 4.00 4.00 23. .06 236 PVC 003 120 18.00 4.00 23. .08 236 < 1.00 .01 1.00 .50 23. 23. .08 .08 236 236 B- 7 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUN 111157452 PVC 003 120 < .01 .08 23. .08 236 Citric Acid, <30% 000779291 PE 041 UNK < .01 8,760.00 23. 305 042 UNK < .01 8,760.00 23. 305 048 UNK < .01 8,760.00 23. 305 Cyctohexytamine 001089180 BUTYL 014 118 , 95.00 8.00 20. .06 323 NATURAL RUBBER 001 250 299.00 8.00 20. .02 323 NEOPRENE 018 100. 294.00 8.00 22. .05 323 NITRILE 019 100 247.00 8.00 24. .04 323 DiaL Lyamine 001240270 BUTYL 014 118 44.00 8.00 21. .09 323 PV ALCOHOL 004 100 -20.00 8.00 23. .08 323 PVC 007 100 -26.00 8.00 22. .02 323 VITON 009 118 4.00 8.00 19. .03 323 1,3-Diam inopropane 001097620 BUTYL 014 118 30.00 8.00 22. .06 323 NATURAL RUBBER 001 250 18.00 8.00 25. .02 323 NEOPRENE 018 100 22.00 8.00 23. .05 323 PVC 007 100 24.00 8.00 ‘21. .02 323 Di -n-amytamine 020509220 NEOPRENE 018 100 74.00 ‘ 8.00 16. .05 323 NITRILE 019 100 2.00 8.00 20. .04 323 PVC 007 100 -23.00 8.00 13. .02 323 VITON 009 118 .20 8.00 16. .03 323 Oichtoroacetyt ChLoride 000793670 BUTYL 014 118 164.00 8.00 23. .09 323 PV ALCOHOL 102 100 -8.00 8.00 23. .07 323 PVC 003 100 230.00 ‘ 8.00 23. .02 323 VITON 009 118 -9.00 8.00 •23. .03 323 DichLorobromomethane 000752740 BUTYL 014 118 347.00 8.00 23. .07 323 PVC 007 100 328.00 8.00 23. .02 323 VITON 009 118 2.00 8.00 ‘ 23. .03 323 VITON/BUTYL 100 102 -2.00 8.00 , 23. .08 323 1,4-Dichtoro-2-butene ‘ 001105760 BUTYL 034 UNK 19.00 20.00 25. 126 17.00 3.00 25. 126 cisoichtoroethyLene 001565920 BUTYL ‘ 014 118 198.00 8.00 23. .07 323 PV ALCOHOL ‘ 004 100 358.00 8.00 23. .05 323 VITON 009 , 118 9.00 8.00 23. .03 323 1 ,2-Dichtoroethytene B— 8 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST 23. .06 323 23. .09 323 23. .02 323 23. .03 323 8.00 8.00 8.00 8.00 20.00 3.00 .83 .83 .83 25. 25. 23. 23. 23. 126 126 204 204 204 .05 .05 .05 CHEMICAL NAME! RESISTANT CASNO MATERIAL 005405900 NITRILE PV ALCOHOL PRODUCT VENDOR DESC CODE 019 100 PERCENT WEIGHT CHANGE IMMERSION TiMEX HOURS 8.00 TEMP DEG C 29. THICKNESS CM .04 REF MUM 323 265.00 004 100 -29.00 8.00 23. .04 323 PVC VITON 007 100 .50 8.00 23. .02 323 009 118 9.00 8.00 23. .03 323 trans-1,2-Dichtoroethytene 001566050 BUTYL 014 118 3.00 PV ALCOHOL 004 100 -30.00 PVC 007 100 -7.00 . VITON 009 118 8.00 2,2’-DichLoroethyt Ether 001114440 BUTYL 034 UNK 11.00 3.80 CPE 060 113 129.00 125.00 123.00 2,3-Dichloro-1-propene 000788860 BUTYL 014 118 66.00 8.00 23. .09 323 PV ALCOHOL 102 100 2.00 8.00 23. .09 323 PVC 007 100 76.00 8.00 23. .02 323 VITON 009 118 4.00 8.00 23. .03 323 1,3-Dichtoropropene 005427560 BUTYL 014 118 65.00 . 8.00 23. .07 323 PV ALCOHOL 102 100 -2.00 8.00 23. .07 323 PVC 007 100 199.00 8.00 23. .02 323 VITON 009 118 3.00 8.00 23. .03 323 Diethanotamine . 001114220 BUTYL 016 118 2.00 8.00 24. .09 323 NEOPRENE • 018 100 5.00 8.00 22. .05 323 NITRILE 019 100 14.00 8.00 26. .04 323 VITON 009 118 3.00 8.00 27. .03 323 DiethyL mine 001098970 BUTYL 014 118 • 88.00 8.00 23. .09 323 NITRILE 019 100 55.00 8.00 24. .04 323 PVC 007 100 -26.00 8.00 24. .02 323 VITON 009 118 83.00 8.00 20. .03 323 Di ethyL ami noethanot 001003780 BUTYL 014 118 2.00 12.00 8.00 22. .07 323 NITRILE 019 118 8.00 22. .04 323 PV ALCOHOL 102 100 -19.00 8.00 23. .09 323 VITON 009 118 5.00 8.00 22. .03 323 Diethylenetriamine , 001114000 BUTYL 014 118 8.00 8.00 24. .08 323 NEOPRENE 018 100 12.00 8.00 22. .05 323 PVC 007 100 19.00 8.00 22. .02 323 VITON 009 118 8.00 8.00 23. .03 323 B—9 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! CASNO RESISTANT MATER JAL PRODUCT VENDOR DESC CODE PERCENT WEIGHT CHANGE IMMERSION TIME HOURS TEMP THICKNESS REF DEG C CM NUM N,N-Dimethytacetamide 001271950. NATURAL RUBBER O imethytethanotamine 001080100 BUTYL NATURAL RUBBER NEOPRENE NITRILE Dimethytformamide 23. .05 236 23. .05 236 23. .05 236 23. .05 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 Di isobutytamine 001109630 Di isopropytamine 001081890 NEOPRENE NITRILE PV ALCOHOL VITON NEOPRENE NI TRI LE PVC VITON 22. .05 323 20. .04 323 23. .08 323 22. .02 323 12. .05 323 10. .04 323 11. .02 323 12. .03 323 018 100 019 100 102 100 009 118 018 100 019 100 007 100 009 118 001 120 010 120 005 120 014 118 001 250 018 100 102 100 007 100 014 118 001 250 018 100 077 100 014 118 019 100 102 100 007 100 014 118 001 250 018 100 019 100 NEOPRENE NI TRI LE Dimethytamine 001244030 BUTYL MATURAL RUBBER NEOPRENE PV ALCOHOL - PVC O imethytami nopropytami ne 001095570 BUTYL NATURAL RUBBER NEOPRENE PVC Dimethy tbuty tani ine 001080980 BUTYL NITRILE PV ALCOHOL PVC 57.00 -1.00 4.00 -2.00 51.00 6.00 -23.00 1.00 18.00 15.00 21.00 32.00 36.00 12.00 12.00 5.00 18.00 53.00 21.00 186.00 .80 10.00 12.00 -6.00 3.00 22.00 114.00 184.00 126.00 67.00 76.00 -22.00 -3.00 .80 17.00 57.00 34.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 4.00 1.00 .50 .08 4.00 1.00 .50 .08 .08 .50 1.00 4.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 22. 20. 22. 23. 20. .06 323 .02 323 .05 323 .07 323 .02 323 16. .09 16. .02 20. .05 20. .02 323 323 323 323 24. .06 323 19. .04 323 23. .08 323 21. .02 323 12. O9 323 19. .02 323 21. .05 323 9. .04 323 B— 10 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST PRODUCT VENDOR DESC CODE 001 120 PERCENT WEIGHT CHANGE IMMERSION TIME HOURS CHEMICAL NAME! RESISTANT • CASNO MATERIAL 000681220 NATURAL RUBBER NEOPRENE 1,1-Dimethythydrazine (Dimethythydrazine,unsym-) 000571470 BUTYL 034 NEOPRENE 031 NITRILE 033 PVC 077 Dimethyt Sutfoxide 000676850 NATURAL RUBBER NEOPRENE NITRILE PVC Dimethytviny t .chtorjde 005133710 . NITRILE • “PV ALCOHOL • PVC VITON Dipropytamine • 001428470 BUTYL POLYCARBONATE Epichiorohydrin 001068980 BUTYL NATURAL RUBBER NEOPRENE .08 DEG C 23. CM NUM 1.00 2.00 .50 23. .05 .05 236 236 4.00 1.00 23. 4.00 4.00 23. .05 236 010 120 2.00 7.00 .08 .50 23. 23. .05 .06 236 236 9.00 1.00 23. 236 9.00 • 4.00 23. .06 .06 236 236 UNK 10.00 168.00 • 22. 078 LANK 30.00 168.00 22. UNK 38.00 168.00 22. 078 168 35.00 168.00 22. 078 078 001 120 2.00 4.00 23. 2.00 2.00 3.00 .08 .50 1.00 • 23. 23. 23. .05 .05 .05 236 236 236 010 120 1.00 .08 23. 236 • 1.00 .50 23. .06 236 • 1.00 1.00 23. .06 236 . 3.00 4.00 23. • .06 236 005 120 • 39.00 19.00 9.00 4.00 4.00 1.00 .50 .08 23. 23. 23. 23. .06 .06 .06 .06 236 236 236 236 003 120 14.00 12.00 4.00 1.00 23. 23. .06 .08 236 236 9.00 8.00 .50 23. .08 .08 236 236 • .08 23. .08 236 019 100 100.00 8.00 23. 004 100 -10.00 8.00 23. .05 323 003 100 -23.00 .08 323 Oó9 118 8.00 8.00 23. 23. .02 .04 323 323 034 UNK 61.00 3.00 25. 098 UNK -.10 126 25. 126 014 118 . 3.00 1.00 .1.00 24.00 8.00 • 8.00 23. 23. 23. .04 .07 291 323 034 UNK 5.00 168.00 22. 323 001 250 13.00 13.00 8.00 80O 23. 23. .02 • 078 323 017 UNK 30.00 24.00 23. .02 323 018 100 • 100.00 24.00 23. .02 291 031 UNK 291 B—il ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST Ethanot, >70% 000641753 PE 041 UNK 042 UNK 048 UNK .20 8,760.00 .20 8,760.00 .01 8,760.00 EthyL Acetate CHEMICAL NAME! RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE 001068980 NITRILE PERCENT WEIGHT CHANGE IMMERSION TIME 020 503 340.00 033 UNK 28.00 PE 006 • 100 209 < .01 12.00 POLYURETHANE 050 178 270.00 PV ALCOHOL 035 102 . UNK 100 < 1.00 -7.00 -3.00 -3.00 PVC 077 168 103.00 TEFLON 036 214 . < .01 VITON 009 . 032 118 UNK 20.00 16.00 16.00 42.00 BUTYL 50.00 NEOPRENE . 150.00 .PV ALCOHOL -3.00 VITON 94.00 TEMP THICKNESS REF DEG C. CM NUN 23. .04 291 22. 078 23. .01 291 22. 078 22. 078 22. 078 23. .05 291 23. .07 323 23. .07 323 22: - 078 23. .01 291 23. .02 291 23. . .03 323 23. .03 323 22. 078 HOURS 24.00 168.00 24.00 168.00 168.00 168.00 24.00 8.00 8.00 168.00 24.00 24.00 8.00 8.00 168.00 8.00 8.00 8.00 8.00 .1 ,2-Epoxybutane 001068870 Ethanol, 30-70% 000641752 PE 014 018 004 009 041 042 048 118 100 100 118 L iNK UNK UNK .10 8,760.00 .10 8,760.00 .10 8,760.00 23. .06 23. .05 23. .04 23. .03 23. 23. 23. 23.. 23.. 23. Ethanotamine (Aminoethanot,2) 001414350 323 323 323 323 305 305 305 305 305 305 BUTYL NEOPRENE 014 018 118 100 2.00 7.00 8.00 8.00 26. 20. .07 .05 323 323 PVC VITON 007 009 100 118 • 12.00 6.00 8.00 8.00 25. 22. .02 .05 323 323 2-Ethoxyethyt- Acetate (Cettosotve 001111590 NATURAL RUBBER Acetate) 001 120 12.00 4.00 23. .05 236 11.00 6.00 1.00 .50 23. 23. . .05 .05 236 236 S 5.00 .08 23. .05 236 NEOPRENE . 010 . 120 17.00 12 OO 4.00 3.00 4.00 1.00 .50 .08 23. 23. 23. 23. . .06 .06 .06 .06 236 236 236 236 NITRILE 005 120 . .10.00 .08 23. .06 236 16.00 .50 23. .06 236 23.00 .1.00 23. .06 236 36.00 4.00 23. .06 236 B— 12 ------- SUMMARY OF PERFORMANCE DETAIL TESTS’ IMMERSION WEIGHT CHANGE TEST PERCENT WEIGHT CHANGE IMMERSION TIME H CURS TEMP THICKNESS REF DEG C CM NUM 23. .04 323 23. .08 323 23. .02 323 23. .04 323 .06 .06 .06 06 23. 23. 23. 23. 23. 23. 23. 236 236 236 236 305 305 305 23: .08 323 23. .02 323 23. .08 323 23. .02 323 11.00 16.00 13.00 3.00 2.50 2.50 2.80. 7 17.00 -19.00 17.00 67.00 13.00 -9.00 74.00 1.00 .01 1.00 1.00 1.00 .01 .01 .01 2.00 4.00 8.00 3.00 1.00 4.00 •1.00 .50 .08 8,760.00 8,760.00 8,760.00 8.00 8 .O0 8.00 8.00 8.00 8.00 8.00 8.00 .08 .50 1.00 4.00 4.00 1.00 .50 .08 • .08 4.00 1.00 .50 .08 CHEMICAL NAME! RESISTANT CASNO. MATERIAL 001417860 NEOPRENE PE Ethyl Celtosolve (Ethoxyethanot, 2) 001108050 BUTYL NATURAL RUBBER PV ALCOHOL PVC Ethyl Acrytate 001408850 BUTYL PV ALCOHOL PVC Ethyl AlcohoL (Ethanol) 000641750 NATURAL RUBBER NEOPRENE NITRILE PVC Ethyl Benzene 001004140 PV ALCOHOL Ethyl Bromide 000749640 NEOPRENE PV ALCOHOL PVC VITON Ethyl-n-butylamine 133606390 NITRILE PV ALCOHOL PVC VITON PRODUCT. VENDOR DESC CODE 010 120 041 UNK 042 UNK 048 UNK 014 • 118 001 250 102 100 007 100 250 250 014 118 102 100 003 100 001 120 010 1 O 005 120 003 120 102 100 018 100 102 100 003 100 009 118 019 100 102 100 007 100 009 118 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. .02 323 .09 323 .08 323 .02 323 .05 236 .05. 236 .05 236 .05 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 • 236 .06 236 .08 236 .08 236 .08 236 .08 236 .01 .50 23. .08 323 1.00 1.00 .40 231.00 -14.00 132.00 13.00 36.00 -24.00 -3LOO 17.00 1.00 40O &OO 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 24. 23. 24. 23. .04 323 .09 323 O2 323 .03 323 B—13 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF HOURS DEG C CM’ NUM CHEMICAL NAME! CASNO RESI STANT MATER!AL PRODUCT VENDOR DESC CODE Ethytene’ChLorohydrin (Chioroethanot) 001070730 BUTYL NEOPRENE PV ALCOHOL VITON EthyLenediamine 001071530 (Diaminoethane, 1,2) BUTYL CPE NATURAL RUBBER NEOPRENE PVC Ethytene Dibromide (Dibromoethane,1,2) 001069340 BUTYL 014 018 102 009 014 060 001 018 007 014 . 118 - .10 8.00 23. .06 100 6.00 8.00 100 -.7.00 8.00 23. 23. .05 .09 323 118 .60 8.00 . 323 23. .05 323 118 2.00 8.00 18. .07 323 113 -5.00 24.00 23. . ‘ 13.00 • 24.00 23. .05 .05 204 . -6.40 24.00 23. .05 250 9.00 8.00 20. 100 9.00 8.00 18. .05 323 100 ‘ .80 8.00 , .02 323 118 65.00 24.00 23. .04 59.00 8.00 23. NATURAL RUBBER 017 UNK 480.00 323 NEOPRENE 018 100 500.00 24.00 24.00 23. 23. .02 .04 291 291 NITRILE 020 503 580.00 24.00 23. , PE 006 100 20.00 24.00 23. .04 .01 291 PV ALCOHOL 102 . 100 4.00 24.00 23. .05 291. . . . .80 8.00 23. .08 323 PVC 007 100 258.00 8.00 . 23. .02 . TEFLON 036 214 2.00 24.00 23. .01 323 VITON 009 118 3.00 24.00 . 23. 2.00 8.00 23. .03 291 323 EthyLene DichLoride (Dichtoroethane,1,2) 001070620 BUTYL 014 118 36.00 8.00 23. . UNK 34.00 34.00 24.00 168.00 23. .06 323 326 064 UNK 24.00 24.00 23. 326 ‘ . 27.00 . 326 NATURAL RUBBER 001 250 213.00 8.00 23. 23. .02 326 017 UNK 226.00 168.00 23. 323 . , 211.00 24.00 23. 326 NEOPRENE 018 UNK 1,90.00 168.00 ‘ 23. 326 182.00 24.00 23. NITRILE 019 UNK 655.00 24.00 23. . > 1,000.00 168.00 23. 326 020 UNK 440.00 168.00 23. . , 340.00 24.00 PE 041 UNK 5.00 ‘ 8,760.00 23. 23. 326 305 042 UNK 16.00 .20 5.40 168.00 24.00 8,760.00 23. 23. 23; ‘ 326 326’ 305 048 UNK 6.90 8,760.00 23. 305 076 UNK 74.00 24.00 23. • 326 100.00 . 168.00 23. 326 POLYURETHANE 050 UNK B— 14 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME/ RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE 001070620 POLYURETHANE 050 UNK PERCENT WEIGHT CHANGE • IMMERSION TIME : HOURS .. 168.00 . . TEMP DEG C 23. THICKNESS CM REF NUM 326 86.00 PV ALCOHOL 004 102 100 UNK .40 .30 8.00 24.00 23. 23. .03 • 323 326 PVC 077 TEFLON 036 UNK UNK .40 265.00 251.00 1.00 168.00 23. 168.00 23. 24.00 23. 168.00 23. • 326 326 326 326 VITON 009 . 118 UNK . .20 5.00 6.00. 24.00 . 8.00 . 168.00 23. 23. 23. .03 326 323 326 6.00 24.00 23. 326 Ethylene GlycoL 001072110 NATURAL RUBBER 001 120 . 1.00 .50 23. .05 236 1.00 .08 23. .05 236 2.00 1.00 23. .05 236 < .01 4.00 23. .05 .236 NEOPRENE 010 S 120 S < 1&OO .01 4.00 1.00 23. 23. .06 .06 236 236 6.00 .50 23. .06 236 < .01 .08 23. .06 236 NITRILE 005 120 2.00 4.00 23. .06 236 1.00 1.00 1.00 .50 23. 23. .06 .06 236 236 . PE 041 042 UNK UNK < < 1.00 .01 .01 .08 . 8,760.00 8,760.00 23. 23. 23. .06 236 305 305 048 PVC 003 UNK 120 < • - .01 3.00 2.00 8,760 OO 4.00 1.00 .23. 23. 23. .08 .08 305 236 236 . < 8.00 .01 .50 .08 23. 23. .08 .08 236 236 Ethylenimine (Aziridine) -001515640 BUTYL 034 NATURAL RUBBER 017 UNK 508 • . 14.00 15.00 . S 168.00 168.00 • 22. 22. , 078 078 2 -EthyL-1-HexanoL . S 001047670 BUTYL 014 118 4.00 8.00 23. .07 323 • NEOPRENE 018 PV ALCOHOL 102 100 100 3.00 - .30 8.00 . 8.00 23. 23. .05 .09 323 323 VITON 009 118 3.00 8.00 23. .03 323 Ethylidene Dichloride (Dichloroethane,1,1) 000753430 BUTYL 012 PV ALCOHOL 004 PVC 003 S . 118 100 100 . S • . 66.00 8.00 -5.00 8.00 65.00 8.00 3.00 8.00 . 23. 23. 23. 23. .09 .08 .02 .02 323 323 323 323 VITON . 009 118 12.00 - 8.00 23. .04 323 Ethyl Methacrylate 000976320 BUTYL 014 118 33.00 8.00 23. .09 323 NITRILE 019 100 109.00 8.00 23. .05 323 B— 15 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT CASNO MATERIAL 000976320 PV ALCOHOL GasoLine 080066190 NEOPRENE GtutaraLdehyde 001113080 BUTYL 2.00 8.00 7.00 9.00 1.00 2.00 2.00 4.00 .08 23. .50 23. 1.00 23. 4.00 23. .08 23. 23. 23. 23. .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06. 236 .06 236 305 •305 305 PERCENT WEIGHT CHANGE IMMERSION TIME HOURS -4.00 115.00 2.00 1.00 1.00 .01 2.00 2.00 2.00 1.00 2.00 2.00 1.00 2.00 8.00 8.00 4.00 1.00 .50 .08 .08 .50 1.00 4.00 1.00 .50 .08 4.00 FormaLdehyde, 000500000 Freon TF 000761310 Furan (Furfuran) 001100090 PVC <•37% (Formatin) NATURAL RUBBER NEOPRENE NITRILE PE PVC NEOPRENE NITRILE BUTYL PV ALCOHOL PVC VITOPI .10 8,760.00 TEMP THICKNESS REF DEG C CM NUM 23. .06 323 23. .02 323 23. .05 236 23. .05 236 23. .05 236 23. .05 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 2L 305 23. .08 236 23. .08 236 23. .08 236 23. .08 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23 . .06 236 23 ; .06 236 23. .06 236 23. .06 236 23. .09 323 23. .09 323 23. .02 323 23. .05 323 PRODUCT VENDOR DESC CODE 102 100 003 100 001 120 010 120 005 120 048 UNK 003 120 010 120 005 120 014 118 102 100 003 100 009 118 010 120 005 120 041 UNK 042 UNK 048 UNK 014 . 118 .01 17.00 1.00 2.00 4.00 1.00 .01 1.00 1.00 1.00 .01 1.00 46.00 -22.00 -49.00 17.00 .50 .08 1.00 4.00 4.00 1.00 .08 .50 4.00 1.00 .50 .08 8.00 8.00 8.00’ 8.00 NITRILE PE .50 1.00 4.00 6.70 8.80 13.50 8,760.00 8,760.00 8,760.00 23. 23. 23. 1.00 8.00 23. .09 323 B— 16 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUM 001113080 NEOPRENE 018 100 . 4.00 8.00 23. .05 323 PVC 003 100 7.00 8.00 23. .02 323 VITON 009 118 4.00 . 8.00 23. .04 323 Hat othane 001516770 BUTYL 014 118 210.00 8.00 23. .09 323 PV ALCOHOL 102 100 -22.00 8.00 23. .07 323 PVC 007 100 -35.00. 8.00 23. .02 323 VITON 009 118 81.00 8.00 23. .05 323 Heptane 001428250 PE 041 UNK .70 8,760.00 23. 305 042 UNK 6.90 8,760.00 23. 305 048 UNK 10.00 8,760.00 23. 305 Hexach I orocyc I opentadi ene 000774740 BUTYL 014 118 26.00 8.00 23. .06 323 NITRILE 019 100 19.00 8.00 . .23. .04 323 PV ALCOHOL 102 100 2.00 8.00 23. .08 323 VITON . 00? . 118 2.00 8.00 23. .03 323 Hexamethy tphosphoamide 006803190 BUTYL 034 UNK . 8.00 168.00 22. 078 NEOPRENE . 031 (iNK 272.00 168.00 22. 078 NITRILE 033 UNK 78.00 168.00 22. . 078 PE . 006 209 22.00 168.00 22. 078 POLYURETHANE 050 178 242.00 168.00 22. 078 VITON 032 UNK 250.00 168.00 22. 078 Hexane 001105430 NEOPRENE 010 120 4.00 4.00 23. .06 236 28.00 1.00 23. .06 236 1.00 .50 23. .06 236 1.00 .08 23. .06 236 NITRILE . 005 120 1.00 .08 23. .06 236 .01 .50 23. .06 236 .01 1.00 23. .06 236 1.00 4.00 23. .06 236 Hydrochloric Acid. 076470100 BUTYL 034 UNK 11.00 20.00 25. 126 .90 3.00 25. 126 POLYCARBONATE 098 UNK < .01 3.00 25. 126 .01 20.00 25. 126 HydrochLoric Acid, <30% 076470101 PE . 041 UNK < .01 8,760.00 23. 305 042 UNK < .01 8,760.00 23. 305 048 UNK .20 8,760.00 23. 305 Hydrochloric Acid, 30-70% 076470102 NATURAL RUBBER 001 120 1.00 .08 . 23. .05 236 2.00 .50 23. .05 236 3—17 ------- SUMMARY OF PERFORMANCEDETAIL TESTS IMMERSION WEIGHT CHANGE TEST Hydrogen Peroxide, 30-70% 077228412 PE 041 UNK 042 UNK 048 UNK 3.00 5.00 1.00 1.00 1.00 2.00 1.00 2.00 2.00 3.00 .01 1.00 4.00 .08 .50 1.00 4.00 .08 .50 1.00 4.00 .08 .05 .05 .06 .06 .06 .06 .06 .06 .06 .06 .08 .08 .08 .08 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 25. 25. 25. 1.00 1.00 2.00 236 236 236 236 236 236 236 236 236 236 236 236 236 236 126 126 126 .50 1.00 4.00 123.00 .30 1.00 3.00 3.00 20.00 : CHEMICAL NAME! CASNO 076470102: RESISTANT : MATERIAL NATURAL RUBBER PRODUCT DESC 001 CODE VENDOR 120 PERCENT WEIGHT CHANGE IMMERSION : HOURS TIME TEMP DEC C THICKNESS CM REF NUM NEOPRENE : 010 120 NITRILE 005 120 PVC 003 120: - Hydroftuoric Acid (Hydrogen Fluoride) . 076643930 BUTYL 034 UNK . : POLYCARBONATE 098 UNK . Hydroftuoric Acid, 30-70% 076643932 NATURAL RUBBER . . NEOPRENE : : NITRILE . PVC 001 010 005 003 120 120 120 120 : 4.00 8.00 2.00 6.00 : 7.00 1.00 4.00 08 .50 1.00 : 23. 23. 23. 23. 23. 23. : 23. 23. 23. 23. 23. 23. 23 23. 23. 23. .05 .05 .05 .05 .06 .06 .06 .06 .06 .06 .06 .06 .08 .08 .08 .08 236 236 236 236 236 236 236 236 236 236 236 236 236 236 236 236 23. 23. 23. 305 305 305 28. 26. 27. .09 .02 .05 323 323 323 < .01 .01 ‘1 .00 1.00 2.00 4.00 4.00 1.00 .50 .08 .08 .50 11 .00 1.00 2.00 2.00 2.00 4.00 .08 .50 1.00 4.00 Iminobispropytamine 000561880 .01 8,760.00 .10 8,760.00 .01 8,760.00 014 001 018 009 118 250 100 118 BUTYL NATURAL RUBBER NEOPRENE VITON BUTYL NITRILE PV ALCOHOL Isobutyt Acrylate 001066380 4.00 21.00 24.00 3.00 16.00 103.00 -2.00 014 118 019 100 102 100 8.00 8.00 8.00 8.00 8.00 8.00 8.00 23. .Ô9 : 23. .05 23. .08 323 323 323 B— 18 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT CASNO 001066380 MATERIAL PVC PRODUCT VENDOR DESC CODE 003 100 PERCENT. WEIGHT CHANGE 94.00 IMMERSION TIME HOURS 8.00 TEMP THICKNESS REF DEGC CM NUN •23. .02 323 Isopropytmethacrytate 23. .05 204 23. .05 204 23. .05 204 23. .05 236 .23. O5 236 23. .05 236 23. .05 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 ‘236 23. .06 236 23. .06 236 23. .06 236 23. .08 236 23. .08 236 23. .08 236 23. .08 236 23. .07 323 23. .05 323 23. .05 , 323’ 23. .05 323 23. .04 323 23. ‘ .06 323 23. .02 323 23. .04 323 Isobutyt ALcohoL 000788310 ‘ ‘ BUTYL NEOPRENE NITRILE VITON 014 018 019 009 118 100 118 118 .06 -3.00 7.00 ‘ .02 ‘ 8.00 8.00 8.00 8.00 Isobutyt ‘Nitrite ‘ 005425630 BUTYL . 014 118 81.00 8.00 ‘ NITRILE PVC VITON 019 003 009 100 100 118 ‘ 38.00 -31.00 50.00 8.00 8.00 8.00 Isopropyl ALcohoL 000676300 ‘ ‘ (Propanot , 2-) CPE ‘ ‘ 3.10 3.70 ‘ 24.00 24.00 ‘ NATURAL RUBBER 3.50 1.00 24.00 .08 ‘ ‘ 1.00 .50 1.00 1.00 . 1.00 4.00 < .01 .08 1.00 .50 < .01 1.00 ‘ ‘< .01 2.00 4.00 4.00 2.00 2.00 , 1.00 .50 < 1.00 .01 ‘ .08 4.00 < .01 1.00 . ‘1.00 .50 < .01 .08 Isopropytamine 000753100 060 113 001 120 010 120 005 120 003 120 NEOPRENE NITRILE PVC BUTYL NEOPRENE PVC VITON 014 018 007 009 118 100 100 118 046553490 ‘Kerosene 080082060 24. .09 21. .05 18. .02 26. .04 323 323 323’ 323 BUTYL NITRILE PV ALCOHOL P’JC NEOPRENE NITRILE 28.00 60.00 18.00 67.00 36.00 69.00 -3.00 63.00 1.00 1 .00 1.00 3.00 1.00 014 118 019 100 102 100 003 100 010 120 005 120 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 .08 .50 1.00 4.00 .08 23. .09 323 23. .05 323 23. .09 323 23. :02 323’ 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23 .06 236 B—19 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST MethyL Acrylate 000963330 BUTYL NATURAL RUBBER NEOPRENE 005 120 PERCENT WEIGHT CHANGE IMMERSION TIME HOURS 1.00 ‘. .50 .10 8,760.00 .10 8,760.00 .01 8,760.00 23. .09 323 23. .02 323 23. .05 323 • 23. .07 323 20. .07 323 16. .02 323 16. .05 323 14. .02 323 MethyL Chloroform (Trfchloroethane,1,1,1) • PRODUCT VENDOR DESC CODE DEG C CM NUM 23. .06 236 23. .06 236 23. .06 236 23. .09 323 23. .02 323 23. .06 323 23. .02 1.00 2.00 • -1.00 7.00 -6.00 10.00 1.00 2.00 2.00 1.00 .01 .01 1.00 1.00 7.00 6.00 3.00 3.00 CHEMICAL NAME! RESISTANT CASNO MATERIAL 080082060 NITRILE Methacrytonitrile 001269870 BUTYL NATURAL RUBBER PV ALCOHOL PVC Methanol (Methyl Alcohol) 000675610 NATURAL RUBBER NEOPRENE - NITRILE Methanol, <30% 000675611 PE MethanoL, >70% .000675613 PE MethyL Acetate 000792090 BUTYL NATURAL RUBBER PV ALCOHOL PVC 1.00 4.00 8.00 8.00 8.00 8.00 .08 1.00 4.00 .50 .08 .50 1.00 4.00 4.00 1.00 .50 .08 014 • 118 001 250 102 100 003 100 001 120 010 120 005 120 041 UNK 042 UNK 048 UNK 041 UNK 042 UNK 048 UNK 014 118 001 . 250 102 100 003 100 014 118 001 250 018 100 102 100 014 118 001 250 018 100 007 •• 100 .10 8,760.00 .01 8,760.00 .01 8,760.00 23. .05 .23. .05 23. .05 23. .05 23. .06. 23. .06 23. .06 23. .06 23. .06 23. .06 23. .06 23. .06 23. 23. 23. 23. 23. 23. 23. .09 23. .02 23. .07 23. .02 236 236 236 236 236 236 236 236 236 236 236 236 305 305 305 305 305 305 323 323 323 323 NATURAL RUBBER NEOPRENE •PV ALCOHOL 3-MethyL aminopropytamine 062918450 BUTYL 1.00 -20.00 -25.00 12.00 5.00 54.00 50.00 • . -4.00 5.00 30.00 70 .00 45.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 PVC B— 20 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST TEMP THICKNESS REF DEG C CM NUN . CHEMICAL NAME! .RESISTANT CASNO MATERIAL 000715560 BUTYL PRODUCT DESC CODE 014 VENDOR UNK • PERCENT WEIGHT CHANGE IMMERSION HOURS 168.00 TIME 80.00 80.00 24.00 5.50 24.00 064 UNK 47.00 24.00 : 49.00 168.00 NATURAL RUBBER 017 UNK 464.00 24.00 .30 24.00 4Th 0O 168.00 NEOP/NAT RUBBER 008 UNK - .30 - .30 24.00 NEOPRENE 010 120 21.00 .08 78.00 .50 . 86.00 1.00 92.00 4.00 291.00 168.00 290.00 24.00 15.50 24.00 - .50 - .50 24.00 . 2.80 24.00 NITRILE 36.00 4.00 82.00 1.00 62.00 .50 25.00 1,000.00 .08 > 24.00 . 2.50 24.00 PE 16.00 168.00 5.00 24.00 131.00 24.00 147.00 168.00 POLYURETHANE 58.00 24.00 . 79.00 168.00 PV ALCOHOL .80 24.00 6.90 24.00 .90 168.00 PVC -2.50 24.00 227.00 , 24.00 273.00 168.00 TEFLON .30 24.00 ‘ .40 168.00 VITON 4.00 24.00 5.00 • 25. • 25. 22. 25. 25. 25. 22. 25. 22. 23. .06 23. .06 23. .06 23. .06 25. 25. 22. 22. 22. 23. .06 23. .06 23. .06 23. .06 25. 22. 25.’ 25. 25. 25. 25. • 25. 25. 22. 25. 22. 25. 25. 25. 25. 25. 25. 326 326 201 326 326 326 201 326 201 236 236 236 236 326 326 201 201 201 236 236 236 236 326 201 326 326 326 326 326 326 326 201 326 201 326 326 326 326 326 326 126 126 018 UNK 005 120 019 UNK 020 UNK 042 UNK 076 UNK 050 UNK 102 UNK 003 UNK 077 UNK 036 009 UNK 034 UNK 001 UNK 002 UNK 010 120 005 UNK UNK MethyL Chtoroformate 000792210 BUTYL Methytene Chloride (Dichtoromethane) 000750920 NATURAL RUBBER’ NEOPRENE NITRILE 13.00 11.00 -3.00 -3.00 17.00 25.00 20.00 4.00 -3.00’ 20.00 3.00 1.00 1’.OO .08 .50 1.00 4.00 1.00 25. 25. 25. 25. 23. 23. 23. 23. 25. 208 208 .06 236 .06 236 .06 236 .06 236 208’ B —21 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM HUM n-MethyLethanoLamine 001098310 BUTYL 014 . 118 2.00 8.00 19. .07 323 CELLULOSE ACETATE 099 118 9.00 8.00 20. .03 323 NATURAL RUBBER 001 250 8.00 8.00 20. .02 323 NEOPRENE 018 100 4.00 8.00 20. .06 323 MethyL EthyL Ketone (Butanone,2) 000789330 BUTYL - 014 118 6.00 8.00 23. .06 323 NATURAL RUBBER 001 120 . 10.00 .50 23. .05 236 6.00 4.00 23. .05 236 8.00 .08 23. .05 236 12.00 1.00 23. . .05 236 250 37.00 8.00 23. .01 . 323 UNK -2.00 1.00 25. 208 NEOPRENE 002 UNK -3.00 1.00 25. 208 010 120 8.00 4.00 . 23. .06 236 16.00 1.00 23. .06. 236 14.00 .50 23. .06 236 5.00 .08 23. .06 236. 018 100 88.00 8.00 23. .05 323 NITRILE 005 UNK -2.00 1.00 25. 208 PV ALCOHOL 102 100’ -14.00 8.00 23. .07 323 Methythydrazine 000603440 BUTYL 034 UNK 6.70 20.00 25. 126 3.40 3.00 25. 126 MethyL Iodide . 000748840 BUTYL 014 118 208.00 8.00 23. .09 323 NEOPRENE 018 100 511.00 . 8.00 23. .05 323 PV ALCOHOL 102 100 -18.00 8.00 23. .07 323 VITON 009 118 4.00 8.00 23. .04 323 MethyL Isocyanate 006248390 BUTYL 014 118 32.00. 8.00 13. .06 323 32.00 8.00 23. .07 323 NATURAL RUBBER 001 250 49.00 8.00 20. .02 323 49.00 8.00 23. .01 323 NEOPRENE 018 100 90.00 8.00 20. .05 323 PV ALCOHOL 004 100 6.00 .OO 23. .03 323 VITON 009 118 74.00 8.00 21. . .03 323. 74.00 . 8.00 23. .03 323 MethyL Methacrytate 000806260 BUTYL 014 118 . 23.00 ‘ 800 . 23. .09 323 NATURAL RUBBER 001 250 112.00 8.00 23. .02 323 PV ALCOHOL 102 100 -7.00 8.00 23. .06 323 PVC 003 100 102.00 8.00 23. .02 323 Monoi sopropanot amine • 000789660 BUTYL 014 118 2.00 8.00 25. .07 . 323 NEOPRENE 018 100 6.00 8.00 24. .05 323 B—22 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST PRODUCT VENDOR DESC CODE 007 100 009 118 PERCENT WEIGHT CHANGE IMMERSION TIME HOURS 8.00 8.00 TEMP THICKNESS REF DEG C CM HUM 25. .02 323 25. .04 323 001 120 010 .120 005 120 041 UNK 062 UNK 048 UNK 003 120 .08 23. .05 236 1.00 23. .05 236 4.00 23. .05 236 . 08 23. .06 236 .50 23. .06 236 .1.00 23. .06 236 4.00 23. .06 236 .08 23. .06 236 .50 23. .06 1.00 23. .06 236 236 4.00 23. .06 236 8,760.00 23. 305 8,760.00 23.. 305 8,760.00 23. 305 8,760.00 23. 305 .08 23. .08 236 .50 23. .08 236 1.00 23. .08 236 4.00 23. .08 236 20.00 25. 126 3.00 25. CHEMICAL NAME/ RESISTANT CASNO MATERIAL OOO7 9660 PVC VITON - Nitric Acid, >70% 076973723 NATURAL RUBBER NEOPRENE NITRILE PE PVC Ni trobenzene. 000989530 . BUTYL Nitroethane 000792430 BUTYL NATURAL RUBBER NEOPRENE PV ALCOHOL Nit , omethane 000755250 BUTYL NATURAL RUBBER NEOPRENE PV ALCOHOL Nitropropane 253220140 BUTYL NEOPRENE NI TR I LE PE POLYURETHANE P.V ALCOHOL PVC V ITOH 2-Nitropropane 000794690 BUTYL 6.00 7.00 6.00 3.00 8.00 12.00 1.00 2.00 3.00 7.00 9.00 17.00 20.00 34.00 1.40 1.90 4.80 4.80 2.00 3.00 4.00 5.00 15.00 4.20 .30 2.00 23.00 -1.00 .50 -4.00 4.00 -2.00 2.00 23.00 72.00 7.00 99.00 1.00 42.00 107.00 .50 034 014 001 018 102 014 001 018 102 034 031 033 006 050 035 077 032 014 UNK 118 250 100 100 118 250 100 100 UNK UNK UNK 209 178 UNK 168 UNK 118 23. 09 323 23. .02 323 23. .04 323 23. .07 323 23. .09 323 23. .02 323 23. .05 323 23. .07 323 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 168.00 168.00 168.00 168.00 168.00 168 00 168.00 168.00 8.00 22. 22. 22. 22. 22. 22. 22. 22. 23: 078 078 078 078 078 078 078 078 .08 323 B— 23 ------- SUMMARY OF PERFORMANCE DETAIL TESTS • IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM HUM 000794690 NATURAL RUBBER 001 250 18.00 8.00 23. “.02 323 NEOPRENE 018 100 53.00 8.00 23. .04 323 PV ALCOHOL 102 100 -2.00 8.00 23. .06 323 n-Nitrosod imethytamine 000551850 CPE 060 113 115.00 .83 23. .05 204 112.00 .83 23. .05 204 109.00 .33 23. .05 204 o-Nitrototuene 000887220 BUTYL 034 UNK 15.20 20.00 25. 126 9.90 3.00 25. 126 p-Nitrototuene 000999900 BUTYL 034. UNK .10 3.00 25. 126 .20 20.00 25. 126 POLYCARBONATE 098 UNK .20 3.00 ‘ ‘ 25. 126 2.00 20.00 25. 126 Oteic Acid 001128010 PE 041 UNK 1.40 8,760.00 23. 305 042 UNK 1.70 8,760.00 23. ‘ 305 048 UNK 2.40 8,760.00 . 23. 305 Oxatic Acid 001446270 BUTYL 014 118 1.00 8.00 19 ‘.07 323 NEOPRENE 018 . 100 . 3.00 ‘ 800 19. .05 323 NITRILE 019 100 2.00 8.00 19. • .04 323 VITON 009 118 .90 8.00 20. .03 323 Phenol. (CarboLic Acid) 001089520 CPE 060 113 9.10 24.00., .23. .05 204 68.00 24.00 23. .05 204 25.00 , 2400 , 23. .05 204 - NATURAL RUBBER. 001 120 12.00 4.00 23. .05 236 2.00 . 1.00 23. .05 236 3.00 .50 23. .05 236 200 - .08 23. .05 236 NEOPRENE 010 120 5.00 4.00 23. .06 236 1.00 1.00 23. .06, 236 2.00 .50 23. .06 236 2.00 .08 23. .06 236 PhenoL, <30% . . 001089521 PE 041 UNK .20 8,760.00 23. 305 042 UNK .10 8,760.00 23. 305 048 • UNK .20 8,760.00 ‘ 21. ‘ 305 Phenyt Gtycidyt Ether 001226010 BUTYL . . 014 UNK .40 •. 24.00 , 22. 201 NATURAL RUBBER 017 UNK 6.00 24.00 22. 201 NEOP/NAT RUBBER ‘ 008 UNK 30.00 24.00 22. 201 NEOPRENE 018 UNK 37.70 24.00 22. 201 B—24 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM- NUM 001226010 NEOPRENE 018 LiNK 23.00 24.00 22. 201 33.10 24.00 22. 201 NITRILE 020 LiNK 103.50 24.00 22. 201 PV ALCOHOL 102 LiNK 3.80 24.00 ‘22. 201 PVC 003 : UNK 41.40 24.00 22. ‘ 201 Phosphoric Acid, >70% 076643823 ‘NATURAL RUBBER 001 120 3.00 4.00 23. .05 236 3.00 1.00 23. .05 236 2.00 , .50 23. .05 236 - 1.00 .08 23.. .05 236 NEOPRENE 010 120 .01 .08 23. .06 236 .01 .50 23.’ .06 236 .01 1.00 23. .06 236 .01 4.00 23. .06 236 NITRILE 005 120 .01 .08 23. .06 236’ 1.00 .50 ‘ 23. .06 236 4.00 1.00 23. .06 236 5.00 4.00 23. .06 236 PVC 003 120 ‘ 1.00 .08 23. .08 , 236 2.00 .50’ 23. .08 236 2.00 1.00 ,, 23. .08 , 236 2.00 4.00 23. ‘.08 236 Potassiun Hydroxide, 30-70% 013105832 NATURAL RUBBER 001 120 2.00 4.00 23. .05 236 2.00 1.00 23. .05 236 2.00 .50 23. .05 236 1.00 - .01 ‘ .08 23. .05 ‘ 236 NEOPRENE 010 120 .01 4.00, 23. .06 236 .01 1.00 23. .06 236 .01 , .50 23.’ .06 236 .01 .08 23. .06 236 NITRILE 005 120 1.00 .08 23. .06 236 1.00 .50 23. .06 ‘ 236 1.00 1.00 ‘23. .06 236 .01 4.00 , 23. .04 236 PVC 003 120 1.00 400 23. .08 236 .01 1.00 23. .08 236 1.00 ‘ .50 23. .08 236 1.00 .08 , 23. .08 236 beta-Propiotactone 000575780 BUTYL 034 LiNK 1.00 168.00’ 22. 078 NATURAL RUBBER 017 508 9.00 168.00 22. ‘ 078 NEOPRENE ‘ 031 LiNK 31.00 168.00 22. ‘ 078 NITRILE 033 UNK ‘29.00 16&O0 , ‘22. 078 PE 006 209 18.00 168.00 22. 078 POLYURETHANE 050 178 185.00 16&00 22. 078 PVC 077 168 15.00 168.00 22. 078 VITON 032 UNK , 69.00 16800 22. 078 n-Propytarnine B—25, ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST PropyLene Dfchtoride (Dichtoropropane 000788750 BUTYL PV ALCOHOL PVC VI TON 1,2) 014 102 007 009 PERCENT WEIGHT CHANGE IMMERSION TIME HOURS .10 8,760.00 .10 8,760.00 .01 8,760.00 .01 8,760.00 .01 8,760.00 .10 8,760.00 23. .08 323 23. .07 323 23. .02 323 23. .03 323 TEMP THICKNESS REF DEC C CM NUM 25. 25. 17. 24. 17. 25. 126 126 .07 323 .05 323 .02 323 .02 323 17.00 14.00 -3.00 1.00 5.00 8.00 70.00 -2.00 105.00 7.00 21.00 58.00 -9.00 94.00 38.00 152.00 - .60 106.00 20.00 3.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 CHEMICAL NAME! RESISTANT PRODUCT VENDOR • CASNO MATERIAL DESC CODE 001071080 BUTYL 034 UNK Propytenediamine . . 000789000 BUTYL 014 . 118 NEOPRENE 018 100 PVC 007 100 VITON 009 118 118 100 100 118 1,3-PropyLene Oxide 005033000 BUTYL 014 118 NATURAL RUBBER 001 250 PV ALCOHOL 004 100 VITON 009 118 PropytmethacryLate 022102880 BUTYL 014 118 NITRILE 019 100 PV ALCOHOL 004 100 PVC 003 100 Sodium Hydroxide, <30% 013107321 PE 041 UNK 042 UNK 048 UPIK Sodium Hydroxide, 30-70% 013107322 NATURAL RUBBER 001 120 UNK NEOPRENE 002 UNK 010 120 005 120 23. .07 323 •23. .02 323 23. .03 323 23. .03 323 23.. . .08 323 23. .04 323 23. .07 323 23. .02 • 323 23. 23. 23:. 23. 23. 23. 23. 23. 23. 23. 25. 25. 23. 23. 23. 23. 23. 23. 23. 23. 25. 23. 23. 2.00 1.00 2.00 2.00 -1 .00 -1.00 2.00 4.00. 3.00 1.00 2.00 7.00 3.00 3.00 1.00 8.00 6.00 305. 305 305 305 305 305 .05 236. .05 236 .05 236 .05 236 208 208 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 208 .08 236 .08 236 NI TRI LE . UNK PVC 003 120 4.00 •1.00 .50 .08 1.00 1.00 4.00 1.00 .50 .08 .08 .50 1.00 4.00 1.00 .08 .50. B— 26 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST PRODUCT VENDOR DESC CODE IMMERSION TIME HOURS TEMP THICKNESS REF DEG C CM HUM 013107322 PVC Tannic Acid, >70% 014015543 NATURAL RUBBER NEOPRENE NITRILE 1,1,1,2-Tetrachtoroethane 006302060 BUTYL PV ALCOHOL 1 ,1,2,2-Tetrachtoroethane 000793450 BUTYL PV ALCOHOL PVC 041 UNK 042 UNK 048 UNK .10 8,760.00 .01 8,760.00 .01 8,760.00 CHEMICAL NAME! CASNO RESISTANT MATERIAL PERCENT WEIGHT CHANGE 003 : 120 7.00 3.00 1.00 4.00 SuLfuric Acid, <30% 076649391 PE SuLfuric Acid, 30-70% 076649392 NATURAL RUBBER NEOPRENE NITRILE tE PVC 001 120 010 120 005 120 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 25. 25. 25. 041 042 048 003 .08 236 .08 236 305 305 305 .05 236 .05 236 .05 236 .05 236 .06 236 06 236 .06 236 .06 236 .06 236 .06 236 .06 236 .06 236 305 305 305 .08 236 .08 236 .08 236 .08 236 208 208 208 UNK UNK UNK 120 2.00 1.00 2.00 1.00 2.00 3.00 1.00 1.00 1.00 2.00 .01 1.00 .01 .01 .01 1.00 .01 1.00 1.00 10.00 7.00 56.00 128.00 -3.00 83.00 2.00 167.00 .10 247.00 4.00 1.00 .50 .08 .08 .50 1.00 4.00 .08 .50 1.00 4.00 8,760.00 8,760.00 8;760.O0 ‘.08 .50 1.Oo 4.00 1.00 1.00 1.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 PVC VITON 001 UNK 002 UNK 005 UNK 014 118 102 100 007 100 009 118 016 118 004 ‘ 100 007 ‘ 100. 009 118 014 118 017 UNK 018 100 005 120 VITON TetrachLoroethytene (PerchioroethyLene) 001271840 BUTYL NATURAL RUBBER NEOPRENE NITRILE, 23. .07 323 23. .08 323 23. .02 323 23. .03 323 23. .07 323 23. 04 323 23. .02 323 23. ‘ .03 323 .80 8.00 510.00 770.00 360.00 8.00 11 .00 11 .00 24.00 24.00 24 00 08 .50 1.00 23. 23. 23. 23. 23. 23. .04 291 .02 291 .04 291 .06 236 .06 236 .06 236 B— 27 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEGC CM NUM 001271840 NITRILE 005 120 22.00 4.00 23. .06 236 020 191 95.00 24.00 23. .04 291 PE 006 100 15.00 24.00 23. .01 291 PV ALCOHOL 102 100 -6.00 24.00 23. .05 291 TEFLON 036 214 .01 24.00 23. .01 291 VITON 009 118 ‘ 4.00 24.00 23. .02 291 TetraethyLenepentamine 001125720 BUTYL 012 118 3.00 8.00 25. .09 323 NATURAL RUBBER 017 506 17.00 .8.00 28. ‘.02 323 NEOPRENE 018 100 11.00 .8.00 27. .05 323 VITON 009 118 3.00 8.00 23. .04 323 N,N,N’,N’-TetramethyLenediamine 001101890 BUTYL 012 118 156.00 8.00 20. .07 323 014 118 156.00 8.00 23. .07 323 NITRILE 019 100 37.00 8.M0 23. .05 323 37.00 8.00 ‘ 24. .05 323 PVC 003 100 3.00 8.00 . 23. .02 .323 VITON ‘ 009 118 31.00 8.00 23. .04 323 31.00 8.00 24 ‘ .04 323 Totuene 001088830 BUTYL 014 UNK 2.00 24.00 22. 201 NATURAL RUBBER 001 UNK -2.00 1.00 25. 208 017 UNK .04 24.00 22. 201 NEOP/NAT RUBBER 008 UNK .04 24.00 22. 201 NEOPRENE. ‘ 002 UNK -3.00 1.00 25.’ 208 018 UNK .50 24.00 22’. 201 - .50 - .50 24.00 22. ‘ 201 .80 24.00’ . ‘.22. 201 NITRILE 005 120 25.00 1.00 ‘ 23. .06 236 33.00 .50 ‘ 23. .06 236 17.00 .08 23. .06 236 27.00 . 4.00 23. ‘• .06 236’ UNK -1.00 ‘ 1.00 “25. 208 020 UNK 2.50 24.00 ‘ 22. 201. PE , 041 UNK 7.50 8,760.00 23. 305 042 UNK 9.80 8,760.00 23. ‘ 305. 048 UNK 15.10 8,760.00 , 23. 305 PV ALCOHOL 102 UNK 10.50 24.00 ‘ 22. ‘ 201 PVC 003 UNK ‘ ‘ -29.00 24.00 ‘ 22. 201 Totuene Dilsocyanate 264716250 NATURAL RUBBER 001 120 25.00 4.00 23. .05 236 15.00 1.00 23.. .05 236 9.00 .50 ‘ 23. .05 236 ‘400 .08 23. .05 236 PVC 003 120 32.00 4.O ’ O’ 23. .08 236 26.00 1.00 23. .08 236, 14.00 .50 23. .08 236 6.00 .08 23. .08 236 B—28 ‘ ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST TEMP THICKNESS REF DEG C CM NUM 018 019 007 009 014 102 007 009 100 100 100 118 118 100 100 118 8.00 8.00 8.00 8.00 PVC VITON 31.00 4.00 -20.00 1.00 105.00 .30 125.00 19.00 19. .05 22. .04 20. .02 17. .03 • 323 323 323 323 23. .07 323 23. .08 323 23. .02 323 23. .03 323 CHEMICAL NAME! RESISTANT CASNO MATERIAL TriaL tytamine PRODUCT • VENDOR DESC CODE . PERCENT WEIGHT CHANGE IMMERSION TIME HOURS 001027050 NEOPRENE NI TR I LE PVC VITON Trichtoroacetatdehyde (Chtorat) 000758760 BUTYL 8.00 PV ALCOHOL - 8.00 . . 8.00 a.OO 1,1,2-Trichtoroethane 000790050 BUTYL 014 064 118 UNK UNK 80.00 80.00 80.00 49.00 8.00 24.00 168.00 168.00 . . 47.00 24.00 NATURAL RUBBER 001 UNK -2.00 1.00 . 017 UNK 473.00 •464.00 168.00 • 24.00 NEOPRENE 002 UNK -3.00 1.00 . 018 • UNK . 290.00 291.00 24.00 168.00 NITRILE 005 UNK -3.00 1.00. • 019 UNK > 1,000.00 • > 1,000.00 168.00 24.00 PE 042 UNK 5.00 24.00 . 076 • UNK 16.00 131.00 168.00 24.00 147.00 168.00 POLYURETHANE 050 • UNK 79.00 168.00 58.00 24.00 PV ALCOHOL 102 100 UNK -2.00 .80 • .90 8.00 24.00 168.00 PVC • 238.00 227.00 273.00 8.00 24.00 16&OO TEFLON 036 .40 .30 168 . 00 24.00 VITON 009 3.00 5.00 4.00 8.00 168.00 24.00 003 077 • 23. - -23. 23. 23. 23. 25. 23. 23. 25. 23. 23 25. 23. • 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. • 23. 23. 23. 23. 23. 23. • 23. •23 - - 22. 25. 23. 25. 23. .09 323 326 326 326 326 • - 208 326 326 208 • 326 - 326 • 208 326 326 326 326 326 326 326 326 .07 323 326 326 .02 323 326 326 326 326 .05 323 326 326 .04 291 078 208 .02 29.1 208 .04 291 118 UNK UNK 118 UNK 118 UNK UNK UNK UNK 100 Trichtoroethytene (Trich-Loroethene) 000790160 B IJTYL - NATURAL RUBBER NEOPRENE 014 034 001 017 002 018 440.00 148.00 -3.00 700.00 -3.00 400.00 24.00 168.00 1.00 24.00 1.00 24.00 B—2 9 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST •1,2,3-Trichtoropropane 000961840 SUTYL NITRILE PV ALCOHOL VI TON Tricresyt Phosphate (Tritotyt Phosphate) 013307850 BUTYL PVC VITON 1.00 3.00 4.00 10.00 .01 .08 .50 1.00 4.00 .08 23. .06 236 23. .06 236 23. .06 236 23. .06 236 23. .06 236 CHEMICAL NAME! CASNO 000790160 PRODUCT VENDOR DESC CODE 031 UNK 005 120 PERCENT WEIGHT CHANGE TEMP THICKNESS REF DEG C CM NUM RES I STANT MATERIAL NEOrRENE’ NITRILE PE POLYURETHANE PV ALCOHOL PVC TEFLON VITON 22. 23 23. 23. 23. 25. 23. 22. 23. 22. 22. 22. 23. 22. 23. 23. 22. 020 033 006 050 035 102 077 036 009 032 014 019 004 009 UNK 503 UNK 100 209 178 UNK 100 168 214 118 UNK 118 100 100 118 078 .06 236 .06 236 .06 236 .06 236 208 .04 291 078 .01 291 078 078 078 .05 291 078 .01 291 .02 291 078 118.M0 29.00 5LOO 58.00 40.00 -1.00 310 . 00 217.00 20.00 6.00 115.00 • 3.00 -2.00 14.00 .01 8.00 2.00 19.00 182.00 4.00 .50 1.00 .40 2.00 70.00 6.20 -2800 200 3.00 6.00 23.00 600 15.00 .70 -14.00 -1.00 IMMERSION TIME HOURS 168.00 4.00 1.00 .50 08 1.00 24.00 168.00 24.00 168.00 168.00 168.00 24.00 168.00 24.00 24.00 168.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 012 118 003 100 009 118 23. .06 323 23. .04 323 23. .03 323 23. .03 323 23 23. 23. • .07 323 .02 323 .04 323 018 019 007 009 014 018 019 009 018 019 102 009 Triethylamine 001214480 NEOPRENE NITRILE PVC VITON Tn ethyl enetet raami ne 001122430 BUTYL NEOPRENE NITRILE VITON Tn -n-propytamine 001026920 NEOPRENE N I TR I LE PV ALCOHOL VITON Turpentine 080066420 NEOPRENE NITRILE 20. .05 323 19. .04 323 20. .02 323 24. .03 323 100 118 100 118 118 100 100 118 100 100 100 118 20. 19. 16. 20. .06 323 .05 323 .04 323 .03 323 23. .05 323 23. .04 323 23. .06 323 23. .04 323 010 120 005 120 B— 30 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION WEIGHT CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT WEIGHT CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUN .080066420 NITRILE 005 120 1.00 .50 23. .06 236 1.00 1.00 23. .06 236 1.00 4.00 23. .06 236 PE 041 UNK 7.20 8,760.00 23. 305 042 UNK 9.10 8,760.00 23; 305 048 UNK 14.50 8,760.00 23. 305 Vateronitrite 001105980 BUTYL 014 118 .70 8.00 23. .07 323 NATURAL RUBBER 017 506 32.00 8.00 23. .02 323 NEOPRENE 018 100 58.00 8.00 23. .05 323 PV ALCOHOL 004 100 -4.00 8.00 23. .07 323 4-Vinyt-1-cyctohexane 001004030 BUTYL 012 118 102.00 8.00 23. .07 323 NITRILE 019 100 21.00 8.00 23. .04 323 PV ALCOHOL 004 100 -1.00 8.00 23. .09 323 VITON 009 118 .60 8.00 23. .04 323 Xytene 001332070 NITRILE 005 120 10.00 .08 23. .06 236 19.00 .50 23. .06 236 27.00 1.00 . 23. .06 236 35.00 4.00 23. .06 236 ó19 100 82.00 8.00 23. .05 323 PE 041 UNK 7.90 8,760.00 23. 305 042 UNK 10.30 8,760.00 23. 305 048 UNK 15.40 8,760.00 23. 305 PV ALCOHOL 102 100 4.OO 8.00 23. .09 323 PVC 003 100 -7.00 8.00 23. .02 323 VITON 009 118 1.00 800 23. .04 323 o-Xylene 000954760 CPE 060 113 116.00 .60 23. .05 204 112.00 .60 23. 05 204 109.00 .73 23. .05 204 B— 31 ------- APPENDIX C SWELLING DATA •c— 1 ------- EthyLene Dibromide (Dibromoethane,1,2) 001069340 BUTYL NATURAL RUBBER NEOPRENE NITRILE PE PV ALCOHOL TEFLON VITOtI SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION SWELLING TEST PRODUCT . VENDOR SWELL (PERCENT VOLUME) DESC CODE BUTYL NATURAL RUBBER IMMERSION TIME HOURS 014 UNK 064 UNK 017 UNK TEMP THICKNESS REF DEG C cM NUM CHEMICAL NAME! RESISTANT CASNO MATERIAL Benzene 000714320 Dibutytamine 001119220 Epich lorohydri’n 001068980 NEOPRENE. 018 UNK NITRILE 019 UNK NONWOVEN PE. PE . 071 042 076 UNK UNK UNK PVC 003 UNK SARANEX TEFLON 061 036 UNK UNK VITON 009 UNK NITRILE 019 100 PV ALCOHOL 102 100 PVC 007 100 VITON 009 118 23. 23. • 23. • 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 327 327 327 327 327 .327 327 327 327 327 327 327 327 24. .04 323 23. .08 323 20. .02 323 20. .03 323 BUTYL 014 118 NATURAL RUBBER 017 UNK NEOPRENE 018 100 NITRILE 020 503 PE 006 100 PV ALCOHOL 102 100 TEFLON 036. 214 VITON •. 009 118 124.00 82.00 377.00. 383 .00 284 .00 182.00 166.00 37.00 14.00 -18.00 71.00 6.40 18.00 28.00 -26.00 -26.00 .40 .01 • 30.00 120.00 240.00 15.00 •7.00 .01 35.00 30.00 240.00 > 1,000.00 2300O 35.00 .01 .01 .01 19.00 19.00 1900 25.00 25.00 25.00 118.00 124.00 118.00 141.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 8.00 8.00 8.00 8.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 4.00 1.00 24.00 4.00 1.00 1.00 24.00 4.00 4.00 23. .04 23. .02 23.. . .04 23. .04 23. .01 23. .05 23. .01 23. .02 291 291 291 291 291 291 291 291 014 118 017 UNK 018 100 020 503 006 100 102 100 036 214 009 118 UNK UNK UNK UNK 23. .04 291 23. .02 291 23. .04 291 23. .04 291 23. .01 291 23. .05. 291 23. .01 291 23. .02 291 EthyLene Dichtoride (DichLoroethane,1,2) 001070620 BUTYL 014 064 NATURAL RUBBER 017 NEOPRENE 018 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 326 326 326 326. 326 326 326 326 326 326 C— 2 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION SWELLING TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR CASNO MATERIAL DESC CODE 001070620 NEOPRENE 018 UNK . NITRILE 019 UNK SWELL (PERCENT VOLUME) IMMERSION TIME HOURS 020 UNK PE 042 UNK 076 UNK POLYURETHANE 050 UNK PV ALCOHOL 102 UNK PVC 077 UNK TEFLON 036 UNK VI TON 009 UNK MethyL ChLoroform (Trichtoroethane,1,1,1) 000715560 BUTYL 014 UNK 064 UNK NATURAL RUBBER 017 UNK NEOPRENE 018 UNK NITRILE 019 UNK PE 042 UNK 076; UNK POLYURETHANE 050 - UNK DEG C 23. CM NUM 326 142.00 24.00 123.00 .1.00 23. 326 275.00 4.00 23. • 326 286.00 24.00 23. 326 259.00 1.00 23. 326 252.00 1.00 23. 326 254.00 24.00 23. 326 252.00 4.00 23. 326 8.00 1.00 23. 326 20.00 24.00 23. 326 20.00 . 4.00 23. 326 4.30 1.00 23. 326 9.00 4.00 23. •326 9.00 24.00 23. • 326 < .01 24.00 23. 326 1.50 4.00 23. 326 .30 1.00 23. 326 .30 1.00 23. 326 1.50 4.00 23. 326 1.00 24.00 23. 326 > 1,000.00 1.00 23. 326 < .01 24.00 23. 326 < .01 1.00 23. 326 < .01 4.00 • 23. 326 9.00 4 00 • 23. 326 < .01 1.00 23. . 326 11.00 24.00 23. 326 249.00 1.00 25. 326 260.00 4.00 25. 326 263.00 24.00 25. 326 11.00 1.00 25. 326 153.00 4.00 25. 326 181.00 24.00 25. 326 334.00 1.00 25. 25. 326 429.00 4.00 326 425.00 24.00 25. 326 213.00 1.00 25. 326 239.00 4.00 25. 326 246.00 24.00 • 25. 326 182.00 1.00 25. 326 208.00 4.00 25. 326 214.00 24.00 25. 326 9.60 1.00 25. 326 9.60 4.00 25. 326 9.60 24.00 • 25. 326 -5.00 1.00 25. 326 13.30 4.00 25. 326 12.30 24.00 25. 326 14.30 1.00 25. 326 15.70 4.00 25. 326 13.70’: 24.00 25. C— 3 ------- Tetrachtoroethytene (PerchLoroethytene) 001271840 - BUTYL NATURAL RUBBER NEOPRENE NITRILE PE PV ALCOHOL TEFLON V TON SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION SWELLING TEST SWELL (PERCENT VOLUME) CHEMICAL NAME! RESISTANT CASNO MATERIAL 000715560 PV ALCOHOL PVC TEFLON VITON Potychiorinated BiphenyLs (PCBs) 013363630 ‘ BUTYL NATURAL RUBBER NEOPRENE PE PV ALCOHOL (Aroc I. or) 014 017 018 006 102 118 UNK 100 100 100 IMMERSION TIME TEMP THICKNESS REF HOURS DEG C CM NUN 1.00 25. 326 4.00 25. 326 24.00 25. 326 1.00 25. 326 4.00 ‘25. 326 24.00 25.’ 326 1.00’ 25. 326 4.00 25. 326 24.00 25. 326 1.00 25. 326 4.00 25. 326 24.00 25. 326 24.00 23 290 , 24.00 23. 290, 24.00 23. 290 24.00 ‘ 23. 290 24.00 23. , 290 ‘ 24.00 23. .04 291 .24.00 23. .02 291 24.00 • 23. ‘ .04 291 24.00 23. , .04 ‘291 24.00 23. .01 291 24.00 23. .05 291 24.00 23. . .01 291 24.00 ‘ 23. .02 ‘291 PRODUCT VENDOR DESC CODE 102 UNK 077 UNK 036 UNK 009 UNK 014 118 017 UNK 018 100 020 ‘ 191 006 100 102 100 036 214 009 118 014 UNK 064 UNK 017 UNK 018 UNK 019 UNK UNK UNK 050 ‘ UNK .01 3.00 4.00 .01 .01 22.00 .01 .01 .01 .01’ 8.60 20.50 14.00 200.00 10.00 ‘35.00 4.00 280.00 530.00 320.00 60.00 85.00 -12.00 .01 .01 -1.00 10.00 7.00 44.00 44.00 42.00 146.00 154.00 154.00 158.00 140.00 158.00 355.00 339.00 277.00 -16.00 -23.00 -20.00 -1.00 4.00 14.00 -5.00 1,1 ,2-TrichLoroethane 000790050 ‘ , BUTYL NATURAL RUBBER NEOPRENE NITRILE PE POLYURETHANE 042 24.00 1.00 4.00 24.00 4.00 1.00 1.00 2400 400 1 .00 4.00 24.00 24.00 400 1.00 4.00 ‘1.00 240O 24.00 4.00 1.00 4.00’ 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 2 . 23. 23. 23. 23. 23. 23. 23. 23. 23. 23. 326, 326 326 326 326 326 326 ‘326 326 326 326 326 326 326 326 326 326 326 326 326 326 326 076 C— 4 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION SWELLING TEST PRODUCT VENDOR DESC CODE 102 UNK 036 UNK 009 UNK TEMP THICKNESS REF • HOURS DEG C CM MUM 1.00 24.00 4.00 1.00 1.00 .01 1.00 .01 4.00 .01 24.00 -SWELL (PERCENT VOLUME).IMMERSION TIME 050 LINK -5.00 -5.00 5.00 .01 077 UNK > 1,000.00 5.00 24.00 CHEMICAL NAME! RESISTANT CASNO MATERIAL 000790050 POLYURETHANE PV ALCOHOL PVC TEFLON VITON Trichtoroethytene (Trichtoroethene) 000790160 BUTYL NATURAL RUBBER NEOPRENE NITRILE PE PV ALCOHOL TEFLON VI TON 23. 2L 23. 23. 23. 23. 23. 23. 23. 23. 23. 2L 326 326 326 326 326 326 326 326 326 326 326 326 014 017 018 020 006 102 036 009 16OO LOO 19.00 24.00 118 3200O 24.00 23. .04 291 LINK 5800O 24.00 23. .02 291 100 410.00 24.00 • 23. .04 503 220.00 24.00 23. .04 291 100 • 70.00 24.00 23. .01 291 100 -10.00 24.00 23. .05 291 214 .01 • 24.00 23. .01 291 118 20.00 23; • C— 5 ------- APPENDIX D DIFFUSION COEFFICIENTS D—1 ------- SUMMARY OF PERFORMANCE DETAIL TESTS DIFFUSION COEFFICIENTS CHEMICAL NAME! RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF CASNO MATERIAL DESC CODE a b DEG C CM NUM Acetone 000676410 PV ACETATE 124 UNK 1.30 -11.00 40. 178 ALLyI ChLoride 001070510 PV ACETATE 124 UNK 1.30 -11.00 40. 178 Benzene 000714320 BUTYL 014 UNK 4.33 -8.00 23. 327 064 pUNK 5.30 -7.00 23. 327 EVA 074 UNK 1.90 -6.00 23. 327 NATURAL RUBBER 017 UNK 1.45 -6.00 23. 327 1.60 -5.00 23. 327 045 UPIK 1.50 -7.00 25. .225 NEOPRENE 018 UNK 5.70 -7.00 23. 327 NITRILE 019 UNK 3.50 -7.00 23. 327 NONWOVEN PE 071 UNK 1.13 -6.00 23. 327 PE 042 UNK 8.33 9.00 23. 327 048 UNK 1.90 -9.00 0. 253 076 UNK 8.80 -7.00 23. 327 PV ACETATE 124 UNK 4.80 -13.00 40. 178 PV ALCOHOL 004 UNK 7.30 -7.00 23. 327 PVC 003 UNK 4.50 -7.00 23 327 SARANEX 061 UNK 1.67 -8.00 23. 327 TEFLON 036 UNK 6J7 -9.00 23. 327 VITON 009 UNK 6.00 -8.00 23. 327 Butyt CettosoLve (Butoxyethanot, 2) 001117620 NITRILE 019 100 3.45 -7.00 37. .06 107 2.57 -7.00 37. .06 107 PVC 007 129 7.00 -7.00 22. 122 Carbon Tetrachtoride (Tetrachtoromethane) 000562350 PV ACETATE 124 UNK 3.00 -16.00 40. 178 Chtorobenzene 001089070 NEOPRENE 002 UNK 6.61 -5.00 23. 186 PVC 007 LINK 7.36 -5.00 23. . 186 Dimethyt Sutfoxide . . 000676850 NEOPRENE 002 UNK 6.60 -4.00 23. 186 Ethane 000748400 PE 048 UNK 8.15 -8.00 25. 193 EthyLene Dichtoride (Dichtoroethane,1,2) 001070620 BUTYL 014 UNK 6.23 -8.00 23. 326 064 UNK 5.83 -8.00 23. 326 NATURAL RUBBER 017 UNK 7.50 -7.00 23. 326 NEOPRENE 018 UNK 4.67 -7.00 23. 326 NITRILE 019 UNK 4.50 -7.00 23. 326 020 LINK 1.00 -6.00 23. 326 PE 042 LINK 3.33 -8.00 23. 326 D-2 ------- SUMMARY OF PERFORMANCE DETAIL TESTS DIFFUSION COEFFICIENTS Methanol (MethyL ALcohoL) 000675610 PV ACETATE PRODUCT VENDOR DESC CODE 102 UNK 036 UNK’ 044 UNK 009 UNK 124 UNK 007 UNK 1.70 -12.00. PropyL ALcohoL (Propanot) 000712380 PV ACETATE 124 UNK 1.10 -12.00 40. 178 nPropyLamine DIFFUSION COEFFICIENT CM**2/SEC a b CHEMICAL NAME! RESISTANT CASNO MATERIAL 001070620 PV ALCOHOL TEFLON VITON Hexane 001105430 NEOPRENE PE PVC Isobutytene (Isobutene) 001151170 PE IsopropyLam ine 000753100 . PV ACETATE Methane 000748280 PE 002 UNK • 041 UNK 042 UNK 048 UNK 007 UNK 048 UNK 124 UNK • 048 UNK DEC C 23. CM NUN 326 1.83 -7.00 < 5.00 -8.00 23. 326 8.33 -10.00 23. 326 < 8.33 -11.00 23. 326 1.35 ‘-5.00 23. 186 7.50 -11.00 0. 253 1.50 1.20 -10.00 -9.00 • 0. 0. 253 253 2.50 3.68 -8.00 -5.00 30. 23. 253 186 4.70 -8.00 30. 253 3.10 -9.00 0. 253 1.25 -9.00 -8. 253 . 40. . 178 • 1.40 2.90 7.30 - 10.00 8.30 1.96 -7.00 1.40 -9.00 1.51 -5.00 PVC Methyl Bromide (Bromomethane) 000748390 PE . 041 UNK 042 UNK 048 UNK Methyl Chloroform (TrichLoroethane,1,1,’l) p0071 5560 BUTYL 014 -9.00 -8.00 -9.00 -8.00 1.45 -7.00 • 25. 40. • . ‘23. 0. 0. 0. 30. 25. 25. 25. 25. 25 25. 25. 25. 25. 25. 25. NATURAL RUBBER NEOPRENE NITRILE PE POLYURETHANE PVC. VITON PE 193 178 186 253 253 253 253 326 326 326 326 326 326 326 326 326 326 193. UNK 064 UNK 017 UNI( 018 UNK 019 UNK 042 UNK 076 UNK 050 UNK 077 UNK 009 UNK 048 UNK 1.67 2.78 2.08 3.67 2.33 3.83 1.38 6.33 Propane 000749860 -7.00 -7.00 -7.00 -8.00 -8.00 -8.00 -7.00 -7.00 1.17 -9.00 2.00 -8.00 D —3 ------- SUMMARY OF PERFORMANCE DETAIL TESTS DIFFUSION COEFFICIENTS CHEMICAL NAME! RESISTANT PRODUCT VENDOR DIFFUSION COEFFICIENT CM**2/SEC TEMP THICKNESS REF CASNO MATERIAL DESC CODE a b DEG C CM HUM 001071080 PV ACETATE 124 UNK 5.10 -12.00 40. 178 PropyL Chloride (ChLoropropane, 1) 005405450 PV ACETATE 124 UNK 1.30 -12.00 40. 178 ToLiiene 001088830 BUTYL 014 118 3.67 -7.00 22. 122 216 1.02 -6.00 37. 122 NEOPRENE 002 UNK 5.56 -5.00 23. 186 018 509 6.17 -7.00 22. 122 NITRILE 019 100 3.45 -7.00 37. .06 122 2.57 -7.00 37. .06 122 1.50 -7.00 22. . 122 2.95 -7.00 37. .04 122 118 1.17 -7.00 22. 122 4.15 -7.00 37. 122 1.67 -7.00 22. 122 509 2.67 -7.00 22. 122 020 216 3.50 -7.00 22. 122 6.95 -7.00 37. 122 5.17 -7.00 22. 122 PVC 003 215 5.50 -7.00 22. 122 007 129 3.33 -7.00 22. 122 3.27 -7.00 37: 122 UNK 8.10 -5.00 23. 186 VITON 009 118 2.33 -8.00 37. 122 VITON/NEOPRENE 022 216 333 -8.00 22. 122 517 -8.00 37. 122 1,1,2-Tr ich loroethane 000790050 BUTYL 014 UNK .. 1.67 -7.00 23. 326 064 UNK 8.33 -8.00 23. 326 NATURAL RUBBER 017 UNK 1.47 -6.00 23. 326 NEOPRENE 018 UNK 1.35 -6.00 23. 326 NITRILE 019 UNK 5.50 -7.00 23. 326 PE 042 UNK 2.00 -8.00 23. 326 POLYURETHANE 050 UNK > 2.83 -7.00 23. 326 PV ALCOHOL 102 UNK .2.67 -7.00 2L 326 TEFLON 036 UNK. < 4.83 -11.00 23. 326 044 UNK 4.00 -10.00 23. 326 VITON 009 UNK 1.20 -9.00 23. 326 Trichtoroethytene (Trichtoroethene) . . . . 000790160 NEOPRENE 002 UNK 5.03 -5.00 23. 186 PVC 007 UNK 1.45 -6.00 23. 186 D-4 ------- APPENDIX E TENSILE DATA E—]. ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION TENSILE STRENGTH CHANGE TEST -CHEMICAL NAME! CASNO RESISTANT’ MATER IAL PRODUCT VENDOR DESC CODE PERCENT TENSILE CHANGE IMMERSION TIME HOURS TEMP THICKNESS REF DEG C CM NUM Hydrogen Peroxide, <30% 077228411 CHLOROBUTYL 23. 1,1-DimethyLhydrazine (DimethyLhydrazine,unsym-) 000571470 BUTYL 064 113 < .01 .08 23. 321 085 211 , -13.64 .08 23. 321 CHLOROBUTYL 052 205 < .01 .08 23. 321 CPE 060 070 113 113 -20.63 -10.00 .08 .08 , 23. 23. ‘ 321 321 PVC 053 126 • 29.03 .08 23. 321 TEFLON 055 210 85.19 .08 23. 321 Freon TMC 577623190 BUTYL 064 085 113. 211 • 6.82 2.27 .08 .08 23. 23. 321 321 CHL OROBUTYL 052 205 8.38 .08 23. ‘ 321 CPE 060 113 -12.70 .08 23. 23. 321 ‘ 070 113 -20.00 .08 321 PVC 053 126 , 16.13 .08 23. 321 TEFLON 055 210 48.15 .08 23. 321 Hydrazine (Diamine) 003020120 BUTYL 064 085 113 211 -25.00 -15.91,, .08 .08 23. 23. 321 321 CHLOROBUTYL 052 205 ‘ -2.78 .08 23. 321 CPE PVC 060 0,70 053 113 113 126 < .01 -15.00 9.68 .08 .08 .08 23. 23. ‘ 23. ‘ ‘ ‘321 , 321 321’ TEFLON 055 210 166.67 .08 23. 321 HydrochLoric Acid 076470100 BUTYL , , 064 085 113 211 15.91 -4.55 , .08 .08 23. ‘ 23. 321 321 CHLOROBUTYL 052 205 -13.89 .08 23. 321 CPE 060 070 113 113 -11.11 -62.50 .08 .08 23. 23. 321 321 PVC 053 126 35.48 .08 ‘ 23. 321 TEFLON 055 210 174.07 .08 23. 321 Hydrogen Peroxide ‘077228410 BUTYL 064 ‘ 113 36.36 .08 23. ‘ 321 085 211 -4.55 .08 23. 321 CPE 060 070 113 113 ‘ -9.52 -45.00 .08 .08 23. ‘ 23. 321 321 ‘PVC 053 126 35.48 .08 23. 321 TEFLON 055 210 ‘ 29.63 .08 23. ‘ 321 052 205 2.78 .08 321 Isopropyt ALcohoL (PropanoL, 2-) . . . 000676300 BUTYL CHLOROBUTYL ‘ 064 085 052 113 211 205 < -2.27 M i -6.94 .08 .08, .08 23. 23. 23. ‘ 321 321 321 ‘ CPE 060 113 -1.59 .08 23. 321 E— 2 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION TENSILE STRENGTH CHANGE TEST CHEMICAL NANE/ RESISTANT PRODUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS ‘REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUM 0006763ÔO CPE 070 113 -10.00 .08 23. 321 PVC 053 126 12.90 .08 23. 321 TEFLON 055 210 129.63 .08 23. 321 MethyL EthyL Ketone (Butanone,2) 0O78933O BUTYL 064 113 6.82 .08 23. 321 085 211 -4.55 .08 23. 321 CHLOROBUTYL 052 205 5.56 .08 23. 321 CPE 060 113 -4.76 .08 23. 321 070 113 -20.00 .08 23. 321 PVC 053 126 -67.74 .08 23. 321 TEFLON 055 210 159.26 S .08 23. 321 Methythydrazine 000603440 BUTYL 064 113 ‘ -4.55 .08 23. 321 085 211 -4.55 .08 23. 321 CHLOROBUTYL 052 205 -11.11 .08 23. 321 CPE ‘ 060 113 -7.94 .08 23. 321 070 113 -12.50 .08 23. 321 PVC 053 126 -22.58 .08 23. 321 TEFLON 055 210 85.19 .08 23. 321 Nitric Acid 076973720 BUTYL 064 , 113 2.27 .08 23. 321 085 211 4.55 .08 23. 321 CHLOROBUTYL 052 205 -27.78 .08 23.’ 321 CPE 060 113 1.59 .08 23. 321 070 113 -40.00 .08 23. 321 PVC 053 126 ‘ -16.13 .08 23. 321 TEFLON 055 210 133.33 .08 23. 321 Nitric Acid, Fuming Red 080075870 BUTYL 064 113 25.00 .08 23. 321 085 211 -6.82 .08 23. 321 CHLOROBUTYL 052 205 -19.44 .08 23. 321 CPE 060 113 3.17 .08 23. 321 070 113 -62.50 .08 23. 321 PVC 053 126 16.13 .08 23. 321 TEFLON 055 210 ‘ 44.44 .08 23. ‘ 321 Nitrogen Tetroxide 105447260 BUTYL 064 113 36.36 .08 23. 321 085 211 -20.45 .08 23., 321 CHLOROBUTYL 052 205 -47.22 .08 23. 321 CPE 060 113 ‘ -26.98 .08 ‘ 23. 321 070 113 -52.50 .08 23. , 321 PVC 053 126 ‘ -19.35 .08 23. 321 TEFLON 055 210 207.41 .08 23. 321 SuLfuric Acid 076649390 BUTYL 064 113 2.27 .08 23. 321 085 211 -9.09 .08 23. 321 CHLOROBUTYL 052 205 -5.56 .08 , 23. 321 E—3 ------- SUMMARY OF PERFORMANCE DETAIL TESTS IMMERSION TENSILE STRENGTH CHANGE TEST CHEMICAL NAME! RESISTANT PRODUCT VENDOR PERCENT TENSILE CHANGE IMMERSION TIME TEMP THICKNESS REF CASNO MATERIAL DESC CODE HOURS DEG C CM NUN 076649390 CPE 060 113 6.35 .08 23. 321 070 113 -22.50 .08 23. 321 PVC 053 126 .01 .08 23. 321 TEFLON 055 210 92.59 .08 23. 321 E— 4 ------- APPENDIX F PERMEATION DATA FOR MULTI-COMPONENT LIQUIDS F—i ------- CROSS-REFERENCE OF CHEMICALS IN MIXTURES COMPONENT MIXTURE Acetone 000676410 000400029 000400079 000400169 000400179 000400189 000400199 000400209 000400219 000400229 Acétonitrj le 000750580 000400059 Atlox 3403F 000300060 000400339 000400399 Atlox 3404F 000300070 000400389 000400399 Butadiene 001069900 000400059 Butyl Acetate 001238640 000400089 000400109 Butyl Alcohol 000713630 000400089 000400109 Cyclohexanol 001089300 000400359 • 000400369 000400379 Diesel Oil 0003QO020 • 000400149 Epoxy Resin 000300010 000400079 000400099 Ethyl Acetate 001417860 000400019 000400029 000400109 F—2 ------- CROSS-REFERENCE OF CHEMICALS IN MIXTURES COMPONENT MIXTURE Ethyl Alcohol 000641750 000400019 000400029 000400039 000400089 000400299 000400309 000400319 000400329 000400339 000400349 000400359 000400369 000400379 Ethylene Glycol Monoacetate • 005245960 000400069 Hexane 001105430 000400169 000400179 000400189 000400199 000400209 000400219 000400229 000400239 Isobutyl Alcohol 000788310 000400049 Isopropyl Alcohol 000676300 000400049 000400059 000400069 Methanol 000675610 000400029 000400109 Methyl Acetate 000792090 000400039 Methyl Cellosolve 001098640 000400079 Methylene Chloride 000750920 000400139 00040023 9 000400249 F—3 ------- CROSS-REFERENCE OF CHEMICALS IN MIXTURES COMPONENT MIXTURE Methyl Ethyl Ketone 000789330 000400059 000400069 000400089 Methyl Isobutyl Ketone 001081010 000400049 000400059 000400069 000400099 000400119 000400129 Methyl Parathion 002980000 000400389 000400399 Nitrobenzene 000989530 000400329 000400339 000400349 Organophosphate 000300030 000400159 Pentachlorophenol 000878650 000400149 Phenol 001089520 000400139 Polyamide 000300000 000400049 Propylene Glycol 000575560 000400159 Sodium Hydroxide 013107320 000400289 Sodium Pentachiorophenate 001315220 000400289 Tenneco 590-100 000300050 000400389 000400399 F.— 4 ------- CROSS-REFERENCE OF CHEMICALS IN MIXTURES COMPONENT MIXTURE To luene 001088830 000400049 000400089 000400099 • 000400109 000400119 000400249 Water 077321850 000400389 Xylene 001332070 000400089 000400099 000400129 000400299 OO0400309 000400319 F— 5 ------- SUMMARY OF PERFORMANCE DETAIL FOR..M1XTURE COMPONENTS MIXTURE: 000400019 REFERENCE: 124 001417860 > 70% by vol Ethyl Acetate 000641750 Ethyl ALcohol PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM 2/MIN) (CM) BUTYL 000400019 014 21.00 > 4.00 .07 PV ALCOHOL 000400019 004 21.00 > 4.00 PVC 000400019 003 21.00 .03 1,102.20 . .05 V.1 TON/NEOPRENE 000400019 022 21.00 .13 280.56 . .05 MIXTURE: 000400029 REFERENCE: 124 001417860 70% by vol Ethyl Acetate 000676410 Acetone 000641750 Ethyl Alcohol 000675610 MethanoL PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM”2/MIN) (CM) BUTYL 000400029 014 21.00 > 4.00 .07 PV ALCOHOL 000400029 004 21.00 > 4.00 MIXTURE: 000400039 REFERENCE: 124 000792090 50% by voL Methyl Acetate OO0 4175O 50% by vol Ethyl Alcohol PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM 2/MIN) (CM) BUTYL 000400039 014 21.00 > 4.00 .04 NITRILE 000400039 019 21.00 .12 105.21 .03 VITON 000400039 009 21.00 .07 62.29 .03 F—6 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS MIXTURE: 000400049 REFERENCE: 124 000788310 30 - 70% by vol 000676300 < 30% by vol 001081010 < 30% by vol 001088830 <30% by voL 000300000 MIXTURE: 000400059 REFERENCE: 124 000789330 30 - 70% by vol 001081010 < 30% by vol OO0676300 < 30% by VOL :001069900 000750580 Isobutyl ALcohoL Isopropyt Alcohol MethyL IsobutyL Ketone ToLuene PoLyamide TEMP BREAKTHROUGH (C) (HOURS) 21.00 > 4.00 Methyl Ethyl Ketone MethyL, Isobutyt Ketone IsopropyL ALcohoL Butadiene Acetonitr ite PROD CODE TEMP BREAKTHROUGH (C) (HOURS) PERMEATION RATE (UG/CMA2/MIN) THICK (CM) 000400059 014 NITRILE 000400059 019 PVC 000400059 003 MIXTURE’: 000400069 REFERENCE: 124 000789330 30 70% by vol 005245960 30 70% by vol 001081010 < 30% by voL 000676300 < 30% by vol PROD CODE 21.00 > 4.00 21.00 .32 2100 .15 260.52 MethyL EthyL Ketone EthyLene GLycol Monoacetate MethyL IsobutyL Ketone IsopropyL ALcohoL .04 PROD CODE PV ALCOHOL 000400049 004 PERMEATION RATE (UG/CM”2/M I N) THICK (CM) BUTYL TEMP BREAKTHROUGH PERMEATION RATE THICK (C) (HOURS) (UG/cMA2/MIN) (CM) BUTYL 000400069 014 2100 > 4.00 ‘ .07 NATURAL RUBBER . 000400069 017 21.00 .33 • 24.05 ‘ ‘.05 •F— 7 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS. MIXTURE: 000400079 000676410 001098640 000300010 REFERENCE: 124 <30% by voL 30% by voL Acetone Methyl Cettosolve Epoxy Resin 000400079 PV ALCOHOL, 000400079 PVC PROD CODE TEMP BREAKTHROUGH PERMEATION RATE (C) (HOURS) cuG/C r2/MIN) 21.00 > 4.00 21.00 > 4.00 21.00 .02 THICK (CM) .07 MIXTURE: 000400089 001088830 000713630 001238640 000641750 000789330 001332070 REFERENCE: 124 5 - 2O%byvot 5 20%byvol 5 - 2OXbyvoL 5 20%byvot 5 20%byvot 5 20%byvol Totuene Butyl ALcohol Butyt Acetate Ethyl Alcohol Methyl. Ethyl Ketone Xylene NITRILE 000400089 000400089 PE/EVOH/PE 000400089 PV ALCOHOL 000400089 PROD CODE 000400089 009 TEMP BREAKTHROUGH• (C) (HOURS) 21.00 2.65 21.00 .08 PERMEATION RATE (UG/CM”2/M IN) 6.61 671.34 THICK (CM) .04 .04 • 04. .06 .03 BUTYL 014 004 000400079 003 1,490 .98 .05 BUTYL 000400089 014 21.00 21.00 019 020 109 004 .10 .23 PVC 000400089 003 VITON 21.00 .43 21.00 > 4.00 21.00 .07 916.83 842.68 410.82 855.71 .06 F- 8 ------- MIXTURE: 000400099 001088830 001081010 001332070 000300010 MIXTURE: 000400 09 REFERENCE: 124 001088830 30 - 70% by vol. 000713630 001238640 001417860 000675610 MIXTURE: 000400119 001088830 001081010 REFERENCE: 124 50% by vol. 50% by vol. Totuene MethyL Isobutyl. Ketone Xyl.ene Epoxy Resin TEMP BREAKTHROUGH (C) (HOURS) 21.00 •> 4.00 Tol.uene Butyl. ALcohol Butyt Acetate Ethyl. Acetate Methanol. TEMP BREAKTHROUGH (C) (HOURS) Totuene Methyl. :0 yl. Ketone . TEMP BREAKTHROUGH (C) (HOURS) 21.00 > 4.00 PERMEATION RATE (UG/CM ’2/MIN) SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE CO P0NENTS REFERENCE: 124 30 - 70% by vol. < 30% by vol. < 30% by vol. PROD CODE PV ALCOHOL 000400099 004 PERMEATION RATE (UG/CM 2/M IN) PERMEATION RATE (UG/CMA2/M IN) PROD CODE PV ALCOHOL , 000400109 004 21.00 .43 42.08 VI TON/NEOPRENE 000400109 022 21.00 .27 300.60 THICK (CM) THICK (CM) .05 THICK (CM) PROD CODE PV ALCOHOL 000400119 004 F— 9 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS MIXTURE: 000400129 REFERENCE: 124 001332070 50% by voL XyLene 001081010 50% by voL MethyL Isobutyt Ketone PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CN’2/MIN) (CM) NITRILE 000400129 019 21.00 .20 2,705.40 .03 VITON 000400129 009 21.00 .33 3,006.00 .03 MIXTURE: 000400139 REFERENCE: 124 000750920 .> 70% by voL MethyLene ChLoride 001089520 PhenoL PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM 2/MIN) (CM) NEOPRENE 000400139 018 21.00 .30 1.34 .1.1 PV ALCOHOL 000400139 004 21.00 > 4.00 MIXTURE: 000400149 REFERENCE: 278 000878650 4% by voL PentachLorophenoL 000300020 DieseL OiL PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM”2IMIN) (CM) NATURAL RUBBER 000400149 001 23.00 .01 .02 .16 NEOPRENE 000400149 018 23.00 1.00 1.35 .04 NITRILE 000400149 019 23.00 > 8.00 .06 PVC 000400149 003 23.00 .01 .27 .02 F— 10 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS MIXTURE: 000400169 REFERENCE: 302 • 000676410 95% by voL Acetone 001105430 5% by voL Hexane PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM”2/MIN) (CM) VITON/CHLOROBUTYL 000676410 112 25.00 .08 04 001105430 112 25.00 .08 .04 MIXTURE: 000400179 REFERENCE: 3à2 - 000676410 86% by voL Acetone 001105430 • 14% by voL Hexane PROD TEMP BREAKTHROUGH PERMEATIOM RATE THICK CODE (C) (HOURS) (UG/CN”2/MIN) (CM) VI TOP1/CHLOROBUTYL 000676410 112 25.00 .10 .04 O0i1O5430 112 25.00 .10 .18 .04 MIXTURE: 000400189 REFERENCE: 302 000676410 50% by voL Acetone 001105430 50% by voL Hexane • PROD TEMP • BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM”2/MII1) (CM) VITON/CHL OR OBUTYL • 000676410 112 25.00 .03 .10 .04 001105430 112 25.00 .03 .10 .04 F—il ------- SUMMARY OF PERFORMANCE DETAIL. FORJIIXTURE COMPONENTS MIXTURE: 000400199 REFERENCE: 302 000676410 35% by voL Acetone 001105430 65% by vol Hexane PROD - TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM 2/MIN) (CM) VITON/CHLOROBUTYL 000676410 112 25.00 .10 .04 001105430 112 25.00 .10 .04 MIXTURE: 000400209 REFERENCE: 302 000676410 15% by vol Acetone 001105430 85% by vol Hexane PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS)’ (UG/CM”2/MIN) (CM) VI TON/CHLOROBUTYL 000676410 112 25.00 .10 .18 .04 001105430 112 25.00 .10 - .18 .04 MIXTURE: 000400219 REFERENCE: 302 000676410 5% by voL Acetone 001105430 95% by voL Hexane PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM ” 2/MIN) (CM) VI TON/CHLOROBUTYL 000676410 112 25.00 .08 .04 - 001105430 112 25.00 .08 .O4 F—12 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS MIXTURE: 000400229 REFERENCE: 302 000676410 1% by voL ‘ Acetone 001105430 99% by voL Hexane PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE ‘ (C) (HOURS) (UG/CM 2/MIN) (CM) VI TON/CHLOROBUTYL 000676410 112 25.00 .08 .04 001105430 112 25.00 .08 ‘.04 MIXTURE: 000400239 REFERENCE: 302 001105430 50% by voL Hexane 000750920 50% by voL Methytene ChLoride PROD TEMP BREAKTHROUGH PERMEATION RATE THICK, CODE (C) (HOURS) (UG/CM”2/MIN) (CM) VI TON/CHLOROBUTYL 000750920 112 ‘ 25.00 .70 - .78 .04 .001105430 112 25.00 .95. - 1.03 , .04 MIXTURE: 000400249. REFERENCE: 302 000750920 50% by voL ‘ Hethytene ChLoride 001088830 50% by voL ‘ ToLuene PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CH 2/MIN) (CM) VI TON/CHLOROBUTYL 000750920 112 25.00 .75 - .92 .04 001088830 112 25.00 .97 - 1.10 .04 F—13 ------- SUMMARY OF PERFORMANCE DETAIL FOR MIXTURE COMPONENTS MIXTURE: 000400289 REFERENCE: 278 001315220 4% by voL Sodiun Pentachlorophenate 013107320 Sodiun Hydroxide PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM 2/MIN) (CM) NATURAL RUBBER 000400289 001 23.00 .01 .02 .16 NEOPRENE 000400289 018 23.00 > 7.50 .04 NITRILE 000400289 019 23.00 > 15.50 .06 PVC 000400289 003 23.00 > 5.00 .02 000400289 007 23.00 > 15.50 .11 MIXTURE: 000400389 REFERENCE: 104 002980000 10% by wt MethyL Parathion 000300050 6% by wt Tenneco 500-100 000300060 At Lox 3403F 000300070 Attox 3404F 077321850 83% by wt Water PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CPr2/MIN) (CM) NONWOVEN PE 002980000 071 23.00 < .08 20.04 - 60.12 PE 002980000 076 23.00 .50 - .75 .20 MIXTURE: 000400399 REFERENCE: 104 002980000 57% by wt MethyL Parathion 000300050 36% by wt Tenneco 500-100 000300060 5% by wt At Lox 3403F 000300070 2% by wt At Lox 3404F PROD TEMP BREAKTHROUGH PERMEATION RATE THICK CODE (C) (HOURS) (UG/CM”2/MIN) (CM) PE 002980000 076 23.00 .25 .08 SARANEX 002980000 061 23.00 2.00 - 3.OO .02 F—14 ------- APPENDIX G VENDOR CODES FOR USE WITH DATA SUMMARIES IN APPENDICES A THROUGH E G—1 ------- VENDOR CODES FOUND IN APPENDICES A THROUGH E VENDOR CODE VENDOR NAME 100 Edmont Div. Becton, Dthkirison& Co. 101 Granet 102 Ansell Industrial Products 103 Best Manufacturing Company 104 Boss Manufacti.iring Company.. 106 Disposables Inc. 107 Durafab Disposab1es, Inc. 108 Keystone ProtectIon Corp. 110 Clover Latex, Inc. 112 Greene Rubber Co., Inc. 113 ILC Dover 114 International Playtex, Inc. 115 Major Safety Service, Inc. 116 Melco, Inc. 117 Mine Safety ApplIances Co. 118 North Hand Protection 119 OKI Supply Co. 120 Pioneer Industrial Products Co. 121 Plastex Protective Products, Inc. 122 PPC Industries, Inc. 123 Protexall Company 124 Safety First Industries 125 SGL Homalite Industries 126 Wheeler Protective Apparel, mO. 127 E.I. du Pont de Nemours & Co., Inc. 128 Jordan. David Safety Products 129 KID AB 140 Allied Glove & Safety Products Corp. 141 The Sager Corporation 142 American Scientific Products 144 Arbill Inc. 145 Body-Guard 146 Cesco Safety Products 147 Charkate 150 Dayton Flexible Products 151 Defense Apparel 153 Direct Safety Company 155 Eastco Industrial Safety Corp. 156 Encon Manufacturing Co. 157 Fairway Products 158 General Scientific Safety Equipment Company 159 Froimnelt Industries, Inc. 160 Goodyear Rubber Products Corp. 162 Holcomb Safety Garment Co. 164 Industrial Products Co., Inc. 165 Industrial Safety and Security Co. 166 Interex Corp. 168 Jomac Products Inc. 169 Kappler Disposables, Inc. 170 Kimberly-Clark Corp. 172 Lehigh Safety Shoe Co. G- 2 ------- VENDOR CODES FOUND IN APPENDICES A THROUGH E VENDOR CODE VENDOR NAME 173 Magid Glove and Safety Mfg. Co. 174 Neese Industries Inc. 175 Pendergast Safety Equipment Co. 176 Plastimayd Corp. 177 Pulmosan Safety Equipment Corp. 178 Rainfair, Inc. 179 Ranger 180 Record Industrial Co. 181 Renco Corp 185 W.H. Salisbury & Co. 187 Singer Safety Co. 188 Standard Clove & Safety Equip. Corp. 189 Standard Safety Equipment Cc. 191 LRC Safety Products Co. 192 H. Texier Clove Company Inc. l9 3 Tingley Rubber Corp. 194 The Tracies Co. 196 United States Safety Service Co. 197 Angelica Uniform Croup 198 Vidaro Corp. 201 Falcon Industries, Inc. 202 Oak Medical Supply Co. 203 Colonial Glove & Garment Inc. 204 Monte Clove Company 205 Arrowhead Products 206 Hub Safety Equipment, Inc. 207 Miller Products Co., Inc. 208 Robar Protective Products 209 Fisher Scientific Company 210 Comasec 211 Barry Manufacturing Co. Ltd. 212 Rich Industries 214 Clean Room Products, Inc. 215 Vinylprodukter 216 Erista 220 National Draeger, Inc. 223 Bel-Art Products 225 Coyrie Safety Equipment, Inc. 227 Haiprin Supply Co. 229 Inco Safety Products Co. 231 Keller Clove Mfg. Co. 232 Latex Clove Co., Inc 233 Leonard Safety Epuipmertt, Inc. 234 Lion Uniform, Inc. 235 Mar-Mac Manufacturing Co., Inc. 236 National Safety Wear, Inc. 238 Rockford Medical & Safety Co. 239 Safety Engineering & Supply Co. 242 3M Company 244 Intermarket Latex, Inc. 245 Protech Safety Equipment Inc. G-3 ------- VENDOR CODES FOUND IN APPENDICES A THROUGH E VENDOR CODE VENDOR NAME 246 Broner Glove Co. 247 Trelleborg, Inc. 248 Masterinan’s 249 Goodall Rubber Company 500 Oak Technical, Inc. 501 Bard Parker 502 Seiberling 503 Surety-Sure Seal 504 California Safety 505 Handgards Inc. 506 Ackwell 507 Converse Inc. 508 Pharmasea]. Laboratories Inc. 509 Nolato 510 Chemical Fabrics Corporation 511 Dow Chemical Company 512 Lab Safety Supply’ Company 513 Andover Industries, Inc. 514 Acme Mills Company 515 E.D. Bullard Company 516 Cofish International, Inc. 517 Dorsey Safety Products Co. 518 Elliott Glove Company, Inc. 519 Exxon Chemical Company 520 ,Fyrepel Products Inc. 521. Ny-Test Safety Shoes 522 Iron Age. Protective Company 523 La Crosse Footwear, Inc. 524 Paneigraphic Corporation ,525 Shelby-Wolverine Clove Company 526 Steele & Associates, Inc. 527 Steel Grip Safety Apparel Co., Inc. 529 United States’ Plastic Corp. 531 Superior Surgical Mfg. Co., ‘Inc. ‘532 Willson Safety Products 534 Daffin Disposables, Inc. 535 Aramsco 536 Alliance Supply, Inc. 537 Holland Safety Supply Co. 538 Memphis Clove Company 539 Jones Safety Supply, Inc. 540 Ronco Textile Products, Inc. 541 Safeco Inc. 542 Armin Corporation 543 IPESCo., Inc. 544 Marathon Rubber 545 Stauffer Manufacturing Company 547 Sawyer-Tower 548 E.I. du Pont de Nemours & Company G-4 ------- APPENDIX. H RATIONALE FOR RECOMMENDATIONS IN MATRIX A H-i ------- 1. Overview CPC chemical resistance information was formed into two data bases: • Test data including breaktlirough times, permeation rates, percent swell, percent elongation, percent weight change and calculated diffusion coefficients from the technical literature and CF C vendors. • Qualitative ratings (e.g., “excellent,” “good,” etc.) from CPC vendors, raw materials suppliers and a variety of publications. There was a separate field for each test and each qualitative rating for each chemical/material pair. The total number of fields was about 10,000. Algorithms were developed to analyze the information in each data base separately. The results of the analyses were then combined by means of another algorithm to produce the recommendations in Matrix A. The algorithms for each analysis are summarized in the following paragraphs. 2. Test Data Five types of data were considered: breakthrough time, % swell (volume), % change in elongation, % change in weight due to immersion, and diffu- sion coefficient. The data were scanned and classified as follows: Breakthrough Time Good >1 hour Fair 0.2-1 hour Poor <0.2 hour % Swell (Volume) Good <10% Poor >10% % Elongation Change Good <20% Poor >20% % Weight Change Good <10% Poor >10% - -10 2 Diffusion Coefficient Good <1010 cm 2 /sec Poor >10 cm /sec Tensile Strength Good <10% Poor >10% On a resistant material by resistant material basis for each chemical, the number of individual products in each classification was totaled. (See Appendix E of Volume I fora listing of the resistant materials.) H- 2 ------- The totals in each classificationwere compared and the resistant material put. into one of the following four groups: I. Significant number ‘of test data indicating excellent resistance to the particular chemical. II. Relatively few test data showing excellent resistant, or many data indicating- good resistance. III. Many data indicating fair resistance, or a few data indicating poor resistance. IV. Significant number of test data indicating poor resistance. The criteria for Group I were at least two tests with breakthrough times greater than 1 hour; no breakthrough times less than 1 hour and no data indicating “poor” resistance in either swelling, weight change, elonga- tion, or diffusion coefficient. The criterion for Group II was one or more “good” and no “fair’! or “poor” in any of the five tests. Alternatively, the material would be put, in Group II if there were two breakthrough times greater than 1 hour (with none less than 1 hour)’and two or less “poor” in the other four tests. The’cr’iterion for Group III was one or more “fair” or “poor” test results. The criteria for Group IV were one or more breakthrough times less than 0.2 hour’ or two breakthrough times less than 1 hour. 3. Qualitative Information As described in Volume I, Chapter 7, Part 4, qualitative information was normalized to a four grade scale: A, B, C, D. “A” represented excellent resistance and “D” represented poor resistance. Similar to the test data base, the qualitative information was analyzed on a resistant material by resistant material basis for each chemical. The number of ratings in each grade were tabul&ted and compared in order to assign each chemi- cal/material pair to one of four groups with descriptions analogous to these given above for the test data. In this case, however, qualitative rather than quantitative information is of concern. The criteria for Group II were less than three A or B ratings and no C or D ratings. Alternatively, Group II conditions would be met by a total of three or more A or B or C ratings, the number of A plus B, ratings greater than the number of C ratings, and no D ratings. The criteria for Group III were less than a total of three C or D ratings or, alternatively, a total of three or more B, C or D ratings with the number of C plus D ratings greater than the number of B ratings. ------- The criterion for Group IV was a total of three or more C and D ratings. 4. Matrix A Recoimuendations The results of the activities described in the two preceding sections were combined to yield the overall recommendations listed in Matrix A of Volume I. The rationale for the combination is described in Volume 1, Chapter 7, Part B. H 4 GOVERNMENT PRINTING OFFICE: 1987—716-002/60724 ------- |