United Slates Environmental Protection Agency Office of Wastewater Enforcement and Compliance November 1991 U.S. EPANPDES BASIC PERMIT WRITERS COURSE WORKBOOK Prtnltd on rrcyclfd paptr ------- TABLE OF CONTENTS SECTION IIrLE I NPDES Program Overview/Background 2 The Application Process 3 Standard Permit Conditions 4 Effluent Limitations Guidelines-Based Limits 5 Overview of Variances to Effluent Guidelines 6 Best Professional Judgment-Based Limits 7 Water Quality Standards 8 Determining the Need for and Derivation of Water Quality-Based Limits 9 Monitoring Conditions and Analytical Methods 10 Municipal NPDES Permit Development 11 Municipal Sludge Permit Conditions 12 Storm Water Permitting 13 Combined Sewer Overflow (CSO) Permitting 14 Special Permit Conditions 15 Pollution Prevention 16 Permit Issuance Procedures 17 Compliance and Enforcement ------- COURSE ORGANIZATION The course is designed around the process of issuing a permit...from receipt of the application form, to the development of effluent limitations, monitoring conditions and special conditions and, ultimately, issuance of the permit. ------- PRIMARY COURSE REFERENCES • Text • Workbook • Code of Federal Regulations (CFR) • EPA Quality Criteria for Water 1986 (Gold Book) • EPA Technical Support Document (TSD) for Water Quality-Based Toxics Control • EPA Permit Writer’s Guide to Water Quality-Based Permitting for Toxic Pollutants • EPA Abstracts of Industrial NPDES Permits • EPA Treatability Manual • EPA NPDES Best Management Practices Guidance Document • EPA Case-by-Case Permitting of Municipal Sewage Sludge • Additional Miscellaneous Guidance • Practical Exercises ------- NPDES PROGRAM OVERVIEW! BACKGROUND ------- LEARNING OBJECTIVES • NPDES Program Overview • Statutory Evolution • NPDES Program Implementation NPDES STATUTORY FRAMEWORK • All “point sources” • “Discharging pollutants” • Into “waters of the States” must obtain an NPDES permit from EPA or an approved State OVERVIEW OF THE NPDES PROGRAM • What is a permit? • Universe of permittees • Contents of a permit • Methods for developing permit limits • Universe of regulated pollutants • Overview of the issuance process 1—1 ------- WHAT IS A PERMIT? • Itisalicense... • Issued by the government to persons conducting business in the United States • Granting permission to do something which would be illegal in the absence of the permit • There is no right to a permit and it is revocable for cause (noncompliance) • For our purposes, NPDES permit is license to discharge CLASSIFICATION OF NPDES FACILITIES • Municipals (POTWs) • Majors ( 1 MGD design flow) - Minors • Non-Municipal - Majors ( 80 points) - Minors NOTES: 1-2 ------- CLASSIFICATION OF MAJOR AND MINOR INDUSTRIAL PERMITS • Toxic pollutant potential • Flow/stream flow volume • Conventional pollutants • Public health impact • Water quality factors • Proximity to near coastal waters DISTRIBUTION OF DISCHARGERS TOTAL DISCHARGERS: 64,229 • Municipals (15,605) - Majors: 3,857 - Minors: 11,748 • Non-Municipal (48,624) - Majors: 3,275 - Minors: 45,349 • Percentage of permittees - Industrials: 76% - Municipals: 24% NOTES: 1-3 ------- CONTENTS OF THE PERMIT • Cover sheet • Effluent limitations • Monitoring requirements • Standard conditions • Special conditions METHODS TO DEVELOP EFFLUENT LIMITATIONS IN PERMITS • Effluent limitations guidelines • Water quality standards • Best professional judgment NOTES: 1-4 ------- CWA CLASSES OF POLLUTANTS Conventional pollutants - BOD - TSS - Oil and Grease - Fecal coliforms - pH Toxic pollutants - Heavy metals - Copper - Lead - Zinc - Nickel - Chromium - Etc. - Organic chemicals - Benzene - 1,2 - Dichlorobenzene - Carbon tetrachloride - Etc. • Nonconventional pollutants - Ammonia - Chlorine - Toxicity NOTES: 1-5 ------- PERMIT ISSUANCE PROCESS Permit Application Permit and fact sheet development • Effluent limits • Monitoring conditions • Standard conditions • Special conditions 1 Public notice and public comments 4 Administrative record 3 Final permit 3 Compliance 1-G ------- FWPCA - 1972 AMENDMENTS • Established NPDES and pretreatment programs • Incorporated permits from 1899 Act and standards from 1965 Water Quality Act • Dischargers must identify themselves • Permits are privilege - not a right • Effluent limits must be both technology based and water quality based • Compliance deadlines are specified - 7/1/77 for BPT and water quality standards, - 7/1/83 for BAT • Maximum duration is 5 years • States and public must be involved in issuance process • Established significant penalties for permit violations • Indicated that permit compliance is a shield • Provided for State programs • Established Construction Grants Program for POTWs NOTES: 1—7 ------- NRDC CONSENT DECREE - 1976 • EPA sued by the NRDC, and other environmental and industrial groups • Established the list of 129 (now 126) priority pollutants • Established 34 industrial categories to be regulated by NPDES and pretreatment • Required development of BAT effluent guidelines and categorical pretreatment standards by 1983 CLEAN WATER ACT AMENDMENTS - 1977 • Adopted the provisions of the NRDC consent decree, including “toxic” pollutants • Established BCT for conventional pollutants • Extended BAT/BCT compliance deadlines (7/1/84) • Clarified that Federal facilities are subject to State programs • Authorized EPA to approve local pretreatment programs • Required NPDES States to modify their programs to include pretreatment oversight NOTES: 1-8 ------- WATER QUALITY ACT - 1987 • Extends compliance deadline again (3/31/89) • Specifies storm water permitting requirements • Increases civil and criminal penalties and makes administrative fines available to EPA • Designates that Indian tribes be considered “States” • Creates the Federal sludge management program • Phases out construction grants program • Creates new programs for nonpoint sources (runoff) NPDES IMPLEMENTATION Before approval: • EPA issues permits • EPA conducts compliance and monitoring activities • EPA enforcement After approval: • States implement as above • EPA role = oversight - Grants - Administrative, technical and legal support training - Enforcement as necessary 1—9 ------- . NOTES: SNAPSHOT: NPDES PROGRAM APPROVALS Eligible jurisdiction* 57 NPDES approved 39 Pretreatment approved 27 Federal facility approved 34 General Permits approved 22 *Not including Indian tribes NPDES ACCOMPLISHMENTS TO DATE • $70 Billion - POTWs (1972) • 75% construction completed • 65,000 permits issued • 75% water - fish/swimmable • 361,000 + miles of streams and 12 million lake acres fully support their designated uses • Still experiencing 350 fish kills per year; fishing bans due to pollution in 21 States 1-10 ------- EPA ORGAMZATION: HEADQUARTERS • Compliance and Enforcement Policy • Inspections and Sampling • AdministrativelJudidal Case Review • Compliance/Enforcement Oversight • Data Management • Effluent Guidelines • Water Quality Standards • Pretreatment Standards • Sludge Standards • NPDES Permits Policy • State Programs Approval S S £ I a. atSi. aa. nIq.fl aLI aI Sludge Permits Policy 1—li ------- EPA ORGANIZATION: REGIONS Regional Admin&rator Lawyers Water Man Division Air Wade Drinking Water I I I I I I Groundwater Dredge and Waler Fill/Ocean Quality Dumping Standards Permits Enforcement 1—12 ------- NPDES TERN INOLOGY APPLICATION FORM — Any of the federal forms (or State forms) required to be filled out by a discharger prior to issuance of a permit. BAT — Best Available Technology Economically Achievable (applies to non—conventional and toxic pollutants) BCT — Best Conventional Pollutant Control Technology (applies to conventional pollutants) BPT — Best Practicable Control Technology Currently Available (generally applies to conventional pollutants and some metals) BMP — Best Management Practices; measures supplemental to numerical effluent limitations to control discharges from storage piles, spills, leaks, etc. Frequently, BMPS are procedural or qualitative rather than quantitative. BOD — Biochemical Oxygen Demand; a pollutant commonly limited in NPDES permits. BPJ — Best Professional Judgement; the broad authority of the Act authorizing the development of permits conditions on a case—by—case basis in the absence of national standards. CFR — Code of Federal Regulations where effluent limitations guidelines, the NPDES regulations etc. are found. CONVENTIONAL POLLUTANT(S) — BOD, TSS, fecal coliform, oil and grease, and pH. EFFLUENT LIMITATIONS — The limit (usually daily maximum and monthly average) on a pollutant required to be met by the permit expressed as mass (lbs/day) or concentration (mg/i). EFFLUENT LIMITATION GUIDELINE — A national standard prescribing a limit on specific pollutant (in lbs/day or mg/l) from point sources in a particular industrial category (e.g. textile mills). INDIRECT DISCHARGERS — those facilities which discharge waste water to receiving waters indirectly i.e. through a POTW (also termed ‘IUs ) 1-13 ------- MAJOR PERMIT - any perinit(ee) with a design flow of IMGD or greater (municipal) any permit(ee) which scores 80 or greater on the major/minor permit classification scale (industrial) MINOR PERMIT - any permit which is not a major permit. MIXING ZONE — an allocated impact area in a water body where numeric water quality criteria can be exceeded as long as acutely toxic conditions are prevented. NONCONVENTIONAL POLLUTANT — any pollutant which is neither a conventional nor a toxic pollutant (ex. manganese, ammonia, etc.) NPDES — The National Pollutant Discharge Elimination System prescribed by Section 402 of the Clean Water Act. NBDC CONSENT AGREEMENT — 1976 Settlement agreement between EPA and the National Resources Defense Council concerning the control of toxic pollutants through BAT effluent guideline and categorical pretreatment standards. NSPS — New Source Performance Standard pH — a measure of acidity or alkalinity (pH 7 is neutral) of a waste water; a common pollutant limited in NPDES permits. POINT SOURCE — a discrete conveyance such as a pipe, ditch, etc. contributing pollutants to the environment. POLLUTANT — a contaminant introduced into a receiving water which is subject to technology—based or water quality—based effluent limitations in the permit. POTW — Publicly Owned Treatment Works, usually consisting of primary and secondary (biological) treatment. PRIMARY INDUSTRY — an industry listed in the NRDC consent agreement (also in Appendix A of 4OCFR Part 122) PRETREATMENT — the treatment of Wastewater by contributors to a POTW before the wastewater reaches the POTW. 1-14 ------- PSES — Pretreatment Standards for Existing Sources PSNS — Pretreatment Standards for New Sources TOXIC POLLUTANT — Any of the 129 priority pollutants (organic chemicals, metals, etc.) which are neither conventional nor non—conventional. TOXICITY TEST — A measure of the toxicity of a chemical or an effluent using living organisms by determining the response (survival, reproduction, growth, etc.) of an exposed organism to the chemical or effluent. TSS — Total suspended solids; a pollutant commonly limited in NPDES permits. VARIANCE — A waiver establishing alternative limitations or time extensions for a specific facility. Several different variances and time extensions are available under the CWA upon satisfaction of very specific criteria. WATER QUALITY CRITERION — Elements of state water quality standards, expressed as concentrations, levels, or narrative statements representing a quality of water that supports a particular use (drinking, contact recreation, cold water fishery, etc.) WATER QUALITY STANDARD — Provisions of State or Federal law which consist of a designated use or uses for the water of the United State and water quality criteria for such waters based upon such uses. WATER OF THE U.S. — All waters which are used, were used, or may be used in interstate or foreign commerce, including all water subject to the ebb and flow of the tide and wetlands. 1—15 ------- THE APPLICATION PROCESS ------- LEARNING OBJECTIVES • Types of NPDES Application Forms • EPA Application Form 2C • Accuracy and Completeness The NPDES process is initiated when a point source files application forms requesting a permit. NOTES: 2—1 ------- EPA APPLICATION FORMS FOR NPDES PERMITS FORM TITLE/APPLICABILITY LAST REVISED REGULATION CITE 1 General information 1980 122.21(f) A New and existing major POTWs 1973* 122.21 (j) reserved A New and existing minor POTWs 1973 122.21(1) SHORT reserved 2B New and existing animal feeding 1980 122.21(I) operations and aquatic animal production facilities 2C Existing manufacturing, commercial, 1984 122.21(g) mining, and silvicultural discharges 2D New manufacturing, commercial, 1984 122.21(k) mining, and silvicultural discharges 2E Manufacturing, commercial, mining, 1986 122.21(h) and silvicultural facilities that discharge only non-process wastewater 2F Stormwater discharges associated with 1990 122.26(c) industrial activities NONE Stormwater discharges from 122.26(d) municipal separate storm sewers serving a population of greater than 100,000 *Currently being revised NOTES: 2-2 ------- KEY DEFINITIONS • New Discharger - Any building, structure, facility, or installation: - From which there is or may be a discharge of pollutants - That did not commence discharge at the site prior to August 13. 1979 - Which is not a “new source” - Which has never received a finally-effective NPDES permit • New Source - Any building, structure, facility, or installation from which there is or may be a discharge of pollutants, the construction of which commenced: - After promulgation of effluent limitations guidelines and standards applicable to such source, or - After proposal of effluent limitations guidelines and standards, but only if the standards are promulgated within 120 days of proposal • Existing Source - Any building, structure, facility, or installation from which there is a discharge of pollutants which is not a new discharger or new source. NOTES: 2-3 ------- MAJOR COMPONENTS OF FORM 2C Outfall location Flow, sources of pollution, treatment technologies Production information (if applicable) Improvements (if applicable) Intake and effluent characteristics Potential discharges not covered by analysis Biological testing data Contract analysis information Certification/signature I. II. In. IV. V. VI. VII. VIII. Ix. APPLICATION FORM: REVIEW FOR ACCURACY Most common mistakes: Guideline production and flow rates • Long term average, daily average, and daily maximum values • Decimal point errors • Wrong concentration units • Reported values are below known detection limits 2-4 ------- APPLICATION FORM: REVIEW FOR COMPLETENESS • Common omissions - Map required in Form 1 - Flow diagram required in Form 2C • Other omissions - Required metals - Required GC/MS fractions - Expected toxics - Production rates NOTES: 2-5 ------- PIATRIX OF POUJJIWTF RRE KE IN IMJ(STRJAL : I!! { .1 I I I I I a 8 a a I I a ‘ I I ’ hi 41 hi .1 — — — — — — — . . a U I a S . a. — S — S — — — — • S S S S • S S S — . —— — S S S • a • S S • S S S S S • . . S S S S • • • a S S • a . . . —— — — a IhuSc a — — — — — S S . a a 2 I S . • .I 2-.tky$besyI lp SkaSatS . . iIusoSStbiS — — — — — — IIIS.au.. .t .s .e S — S . S a S a j . . 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QUESTIONS : (1) Is this facility a POTW or does it have a concentrated animal feeding operat ion? (2) Who is Mr. Ceccarelli? _____________________________________________ (3) What does Luster Class Inc. make? _________________________________ (4) Did the proper official sign the application form? __________________ How do you know? __________________________________________________________ (5) To what body of water does Luster Glass Inc. discharge its process water? (6) How many outfalls are there at Luster Glass? _______________________ (7) Has the company collected any data on the toxicity of its wastewater? (8) Does Luster Glass Inc. have its own analytical laboratory for the analysis of priority pollutants? _________________________________________________ (9) Based on your cursory review of the application, which pollutants would you limit in a permit for Luster Glass Inc.? (10) Based on the water flow schematic included in the permit application, what wastewaters are treated at Luster Glass Inc.? What is the total treated wastewater flow? ______________________________________________________ (11) What is the wastewater flow after treatment shown on the water flow schematic? (12) Does wastewater flow into treatment equal wastewater flow out of treatment on the water flow schematic? 2-11 ------- 2—12 ------- Ph Form A ored 0MB No 20400086 Apoto ’v.I .u es 7-3? - INSTRUCTIONS: Complete A through J to detennrn. whither you need to sobmit any permit application form, to the EP& If you sn sr “yss to any qusetlons, you muat submit this form end the supplemental form listed in di. parenthesis following the quastion. Mart ‘X in the box in the third column if the supplemental form us attached. If you an sr “no” to such question, you need not uibmft any of these forms. You may sis er “no if your activity Ia excluded from permit requlrumensi; Section C of the instructions. See also, Section 0 of the inso’uctions for definitions of held-faced terms. SPECIFIC QUESTIONI A Is this facility • piublisfy ownud Deutn it whiCh retults in a d iargo to s of the U.S.? (FORM 2A) VS. i r SO LX’ •O. *flflCNUi SPECIFIC QUESTiONs B. DOSS or will this facility lefther ac ig orpg owrf i mC I lidS e ankiwi fang cpar.tjon or S uadc wilmel peodeedon facOity whlds results ma we slowee of ‘ S. AR SO : V. A I_ , C. Is this a facility which currently retulti in U.S.? (FORM 2B) - 0. Is this s progoa.d facility (oth.’ that thow to wetarl of di. U.S. Olhet than those dewib.d ‘fl j — In A or B tho ) wfiicls whO rssish m a dáth...,. to AorBsbo ie?(FpRM2C) ‘U- , te’aOfth.U ,5 ,?(FORM2p ) .u. ii F. Do you or will you mlsct St thit f.ølity Indu ,t,ial or E Does or will this facility n-em, score, or dispose of hezar ous wem? (FORM 3) municipul effluent below die lo inoat sttstum con. testing, within on. quarter mU. of the well bore. X — .1. uIbd. . und sou, of drinking teeter? (FORM 4) - - IL “ C Do you or will you un ect at this tecuirty any produced waler or Other fluidi which Sri .,_ H. Do you or Will you b1 ect at this facility fluids for sp.. In connection with conVentional oil or natural gsa pro’ c proc suds se mining of sulfur by the Fr.sch duction. un ect fluidi used for enhanced recovery of pro,,..., soksdon mining of mhiarel ., in thu combos. I tion of fosil fuel, or recovery of ..jlJ 1 ensvv? x Oil or natural gas, or inject fluids for Storage of liquid — (FORM 4) — — hydrocarbons? (FORM 4) I . ,, u. T is this facility a proposed Itetlo, y sourse which is — J, Is this facility a pro,.,,.ed sta&. wiwis which us on. of the 28 industj.al categories listed in the in. NOT one of the 25 lnduso ’Ii . 1 S ... —. listed m the ttrtsctuofl s and which will potentially smut 100 tom In uctjOIi. end which will potem 1y emit 250 tons per yser of any sir pollutant regulated under die pw’ y of any SW pollutant regulated under the Clean Clean Air Act end may affect or be located in an — Ai r Act and mey effect or be loceted us an s .. X — attauru wit arse? (FORMS) — .. .i — uve? (FORMS) . r IILNAM E OF FA C,Ll-ry UI 1 11 11 .g,,J J I I I I I I LUSTER GLASS INC. IV. FACILITY CONTACT - I. -t• is A. NAME ê TiTLE (lse& ii,. ?. A title) - ‘ S PHONE (area cod.A I I I I I I I I I I I I I I I I I I (I I I I - CECCARELLI IVO ENV. COORD. 312 834 4536 ii ii .. — . •5 II . I - ...L...... .1 ii V. FACILITY MAILING ADOREU . -.. I A STUIETONPO fox I p I I I I p p I - P0 BOX 319 Is’ - a. S. CITY OR TOWN C.STAYi 0 ZIP CODE I I I I I I I I I I I I I I I j I II I I I 4 - NQRRIS IL 60123 - - ‘ ‘ - VI. FACILITY LOCATION A aYutc’r. ROUTE NO OR OTHER SPECIFIC iDENTiFiER I I I I I I I I I I I I I I I I I I - .RIYER . RIDGE QRI ,VE ii ’ . I I I I I I I II I I I i • COUNTY NAME COQK 5• . 5• C CITY OR TOWN upc I F COUNTY CODE 1 - MORRIS -Ji lL 60123 , , ,1 , I I I I I I I I I I (tf sbdtum0 1 I .’ EPA Form 3510.1 (Rar. 10.80) CONTINUE ON REVERSE I PROTECTION SOENCY GENERAL IN FORMATION 5ROI )diSSd tin/O (Reed the •raj f -. FACILITY LOC AT ION IISTIcS If • pnsprlnt,d label Iset been provided, affix it In the deelgnst .,d speca Revises the inform. atlon ifully, If any of it us incorrect, a-ow through it and inter die correct data in tile spprop ,wh . fill—in ares below. Also, if any of the piwirintad Gate Is absent (di. awi to ) ilt of di. I I sp II, di. ,nfu,rn.vo., di .t d’soJj ’ ) pleas. provide .1 in tile proper fill—sn area g) b,l w If the label us cornpleta and correct, you need not comolrte ltarna I, III, V. and VI (&Ircspr VI-B NI mint he cosip )eas tsperdI ) Complete sil items if no label has been provided Refer to di. Instructions for detailed rtsm dan,p- dons and for the lagal authorizations un which this data is collected. 2-13 ------- EOflI.A THE FRONT — vu. sic ou 4 -dpt m o .’ c1pviw* I A PI SY • UCONO £4 I I I/specify , 4 l I (jpec ifr) 7 .32J1 GLASS MANUFACTURING 1 I. I i I i sk ip . I . C. THIRD 0 POUNTH £4 I (speafy) I I I (specify) - I I i . iii ,iIi, — i i VIII. OPERATOR INFORMATION C ITATUE or OPERATOR (Enter the .pprop,tate Letter bite the asir,wr box. df “Omer”. ec (J)’) C I I I I I I I F • FEDERAL - PUBLIC (Other than federal ornate) ( s p / f y) S — STATE 0 • OTHER (.peci ’y) A 312 834 4536 P—PRIVATE M II i• • H D•- ii I • U I. ITRECT OR P0 lOX I I I I Ii I I I I I I I II I I I I I I I II Ii P0 BOX 319 7• - • 5 F CITY OR TOWN Q.$TAT H. ZIP COOEIX. INDIAN LAND I I I I I I I I I I I I I I I I I I I I I I I I I I I I I !j,. MORRIS — IL 6?13. . usd l.f.cIiItyIo tldoflind1sn 1 1 1 ? C YES ( NO X. EXISTING ENVIRONMENTAL PERMITS - A NPOCI (DLeCIIargeJ to Siarfx . Water) e , I II I I II 9 N . ILoq65 3 I. 0. P$O (AL, Eml ciU fto.’i PPop $ ‘va ) C? • I I I I I I II I II I 9 P IS IS 77 IS .5 II I i U. UIC (Underivuw,dIflI(CtWM of FluLdsJ I I I I I. OTHER ( E ’) a. I I I I I I I I I I I I I a . I I I I 9U .. I. IS IT IS - II 9 IS Ii IT IS 5 • Attach to this application • topographic map of the area extending at Islet Ofli mii i beyond xu ifty boundenes. The map must sho. the outline of the facility, the location of each of ite existing and ropoied Inteks and discharge strucWres. sad of es hazardous waste treatment, storage, or disposal facilities, and each well wher, i -i Injscte fluide undergrowld. Include all spdngs . rivers and other surface water bodies in the map area. See inetructions for precise requirements. -______________________ AUTO TEMPERED AND AUTO LAMINATED GLASS MANUFACTURED I rr,fy under penalty of law that! lies, peiwnally exam inwi aid an fanliW with dse i,fwmat i *i nIttwi in this p!icatiOn and all attachments a id that, based on my inquirj of those psewi i,nm.dhafa !y , ovwibi. for obtakiAig dia Information onnta,ned in the epplication, I beI,e that the information is true, acwrete aid conw f 1. I yp awe that dsare are ifflcwt penalties for su rnWflQ false infosmanon, including the pouibiify of fine and impriwninent A NAME or pIclAl. TITLE (type 0, pant) VICE PRESIDENT JOHN BAKER COMMENTS FOR OFFICIAL USE ONLY I U. SIGNATURE I I I I 2/2/89 I I I I I I I I I I I Cl III IS £ I I I I I I S I I I I I I I I I I I I EPA Form 3510-1 (R.v. 10-801 R.ww 0 C S overnsens Prin 1 0 ui ‘ . Ii dW awn. II,t.d fr A NAME viii.a .i uw I I I I 1 I I I I I I S I I I I I S I I I I I n.I7 LUSTER GLASS INC. YES NO — I. I. II I i C. RCRA (Hezaidout WdItU) I. OTHER (spec (fy) 2-14 ------- 0 96 I GO CH(KATIC OF WAtER FLOW LUSTER OLASS INC 1RRI5. INDIANA 4 813 UGO (lIT WAlER v i 4 I) UC,O OUTFALL ••I 4 563 MGO 7 06 c(s 2 5 UGO R(CYCL(O PROCESS COOlING NATER t 0 45 UGt) (BLOWDOWN) 0 2S MOP AIMOSF’IIERE ------- Illinois River 001 DISCHARGE LUSTER GLASS, INC. Fjct1tj 5 Location N, LOCATION MAP SCALE 1:24000 ------- I- - - - - - . ‘ ‘ vt f *,I ’VAL P .J4I.fIlU C, t ’T N PO PERMIT TO D D4A GE $T WATIRZ - 2 £kII1I,I bI’ACTUfiING. COMMERCIAL MINING * 1W $ILV1CULTtJ AL OPERATIONS I. OU ’ff ALL LOCATION For e.th outf&I, rat the latitude end lonituds of ItS location to the nearest 15 seconds and the name of the receiving water A OUTFALL NUMSUR (lift S LATITUDE C LONGITUDE 0 RECEIVING WATER (heiR., I a.. a i. i sic I C i i 3 ‘ , I ,CC 001 42 36 98 30 ILLINOIS RIVER A Attach a line drawing showing the water flow through the facility Indicate wurces of intake water, operations contributing wasiewnter to the elf luCAt and treatment units labeled to correspond to the more detailed descriptions in Item B Construct a water balance on the line drawing by showing average flows bet en intakes, operations, treatment units, end outfalls If a water balance cannot be determined (..g., for cres,n mining ctsvif,es/ provice a pictorial deacnption of the nature and amount of any aourcea of water and any ccllection or treetm.nc m jrea. B For each outfall, provide a description of (1) All ooeretiorts contributing wastewater to the effluent, including process waiteweter, sanitary wastewater, cooling water, and storm water runoff. (21 The average flow contnbuted by each operation, and (3) The treatment received by the westewater Continue on additional sheets if necessary OPERATION(S) CONTRISUTINO PLOW 3 TREATMENT b AVERAGE FLOW OPERATION (list) (incj,,de Ia’ Iit,i — b LIST COOSS FROM a DESCRIPTION TABLE ZC I Lllç Ngif — Oil/Water Senarator Settling Basins i-ti B1owdo 0.45 MGD MIXING WITh OTHER SThEA S 1-0 . T . I : I , I I guid .linn iii b-ccteiones, EPA Form 3510.2C (Rev 2-851 PAGE 1 OF 4 Lur’IIINUE ON REVERSE Piseas pint or type fl the unshaded areas Only 4 c Oval •WIi•S 73? -88 2-17 ------- CONTINUED FROM THE FRONT A Does an •?fiueflt gu.oeine ,.mitasion oromulgatec by EPA unaer Sector. 304 of the Clean Water Act apply to your tlCii,tV’ CS ICO.iPh’ti (torn Ill B too t o to Section (V i B Are the Imitations in she applicadle effluent guideline espreased in terms of production (or o lir mm,,, of .fIr,pp) 1 YES co.npirte lien. 111 Ci too tie to Soc (ion I ’ ,) C If you answered yes to Item 11.8 lust the uanhuty which represents art actual meesurernentof your level of production expressed in the terms ar’c units used ri the applicable ef’huerut guideline, and indicate the effected oulfalls — 2 4 P5CTC0 OUTFALLS ‘Iii: ‘3ot(O4 ‘iio I •7i 5 QW*fllfl •5* 0* ’ b WSt OP e(01001 AVERAGE DAILY PRODUCTION C pl o ., 0000uc? *rSal*L. ( PC igpecify) 40.000 Ft 2 /DAY 275.000 Ft 2 /DAY AUTO TEMPERED GLASS AUTO LAMINATED GLASS A Aro rou ‘O.’ . reouroi.. o ederat Slate or local autho’ ‘v ‘ —tees any rnoiernentation schedule for the COrtS”uCtlOfl ungrac -: : , -alOr ’ : , ‘.aste aue ’ treatr,en eou,omen’ o’ practices or any oth ’ eriu,ror ’—en a orogrars wnicri may affect the aitchhrges oesc’bec ri n a:: ‘Co : Tri s -: Out 5 101 mISC to Oerm,i :onditions, adm.riistrat,ve or aror:er’ens 0 1c c-n enlo,cement compliance schedule ‘erers, sIpulat 0’S Co..’ :‘cers a’: ;rar t or loan ConditIons — — YES icornpI. ’ie rhe ‘o.l... . g roo.r, NO i,o to Ire,.. 4, I iocPo -ri.ICATIOPI OF CONDITION ,I * AFFECTED OUI’FALL S AGRECMCNT CrC • . so .ca . 3 •R 1EF DESCRIPTION or PROJECT 4 FiNAL COM P S. JARCC OATF I 00’ . ‘00’ OWISSO •Ct0 B OPTIONAL Y u may as,ac’, 400 11’C08l s”-els oesc 3 - ,. - c on ;enrre programs ‘or ems’ eneronmai, ’a :rO/ec’s - - . . - rec’ your 3lscnarpesl you rio nays un0!r ay or wncn ,‘o.i . ., ‘- -c Ca acn orogram •s no . urioerwav 0’ pailfleO - - 3’ olannec scneduies for Construction MARK K IF OCSCR 1PT1ON ORAl. CONTROL PROGRAMS 5 ATTACRCD PACE 2 OF J CONTINUE C. aAGE EPA Form 3510 2C (Rev 2-85) ‘ ‘E iiss for f n, . rvrsoff ‘TSsks. or Zla . WS 5 5W of ’ N ‘• ‘ us ) s fl. or B ; . tr YES (co’—DI.ga rho lOilO i.i toW,) NO (to to Secego,. til l 2 OPERATIONI ’ 5 1 4 FLOw N/A N/A N/A N/A N/A N/A N/A /A vA 001 001 2-18 ------- A ,O ed JEP* I 0 NUMSCR(COpY (‘am Item 1 of Fo,m , 0M8 Vs 7O4O. 86 CONTINUED FROM PAGE 2 I 2OD,O JIe,D,,eS 73? 88 V INTAKE AND EFFLUENT CNAAACTERISTICS A, B, & C See instruction, bet ore poceeding — Complete one set Of table, for each outfall — Annotate the outfall number in the provided NOTE Tables V-A, V.8. and V-C are included on separate sl eeu numbered V-t through V .9 0 Use the space below to l,n any of th. pollutants listed in Table 2c-3 of the instructions which you know or have reason tO believe is discharged or -flay be discharged from any outfall For ry pollutant you list briefly describe the reasons you believe it to be present and report any analytical data n rout possession I POL i.UTANT 2 SOURCC POLLUTANt ’ 2 SOUPCC N/A NIA N/A N/A VI POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-Ca substancoor a component of a substance which you currently useor manufacture as an intermediate or final product or byproduct? YES (list Ii such pOllutants belowi NO ‘go to tism yr B? ZINC EPA Form 3510-2C (Rev 2-85) PAGE 3 OF 4 CONTINUE O EVER 2-19 ------- cONTINUED FROM THE FRONT Whole Effluent Toxicity — Acute and chronic Whole Effluent Toxicity tests were conducted to satisfy an NPDES permit reguirement for biomonitoring. Initially, in February 1988, a sample was analyzed for acute and chronic toxicity using both Ceriodaphnia dubia and Pimephales promelas (Fathead minnows). The results indicated that Fathead minnows were the more sensitive of the two species and were used in subsequent tests. Chronic toxicity to Fathead minnows varied from 1.2% to 3.5% Acute toxicity varies from 3 to 24.8%. A total of 12 monthly samples were analyzed for acute and chronic toxicity over the course of one year. Results are presented in Table 3. Icervify under penalty c i I . wthat this document and.!! attachments were prepared under my direction or supervision in accordance with as esrem designed to assure that quahfiedpersonnelprcperiy gather nd evaluate the information submitted Based onmysnquiry of the person or persons who manage the system or those persons directly responsible for gathering the information the information sisbmifl d,z. to the be at 0/rn ykno wiedge andbelief true accurate and complete / am aware thit there are significant penalties lot submitting false information, including the poznbil,t’y of Fin. and imprisonment for no wing notations A NAME & OFFICIAL TITLE ii%p, On Dninr JOHN BAKER. VICE PRESIDENT B PHONE NO ‘urea 312-834-4536 C SIGNATUPE 4. L A 0 DATE SIGNED -/ rn Oo yo h or esesom fo that sy bIOIOgIad last for . cuse or cttr n Iosualy h bs s made on my of your 0’sct er es or on a k , , your dI.dlar9 . esth,n ds. fast 3 yes’s? v .a (Identify the teit iii and de,c’ibq thSIr purpO gf betawi “ ‘ NO (So to Section V I ! ! ) A NAME Were eny of the analyse, reVorted in lten V perform ed by a contraci laboratory Or consUlting firm? yes ‘list th . nwn,, addrui, and telephone numb., 01’, and pallutanta NO (to to Section IX) analyz.d by, each such laboratory or firm b iow) MEASUREMENT L.ABS B ADDRESS C TELEPHON (arva cod. & no I 113 RIVER PARKWAY 312-684-2121 CHICAGO, IL 60020 •ULLUTANTS ANALYZED U ’ 129 PRIORITY POLLUTANTS BOD, TOC, COD, TSS, ZN, CU, PHOSPHORUS, CADMIUM. LEAD EPA Form 351O- C (Rev 2-85) PAGE 4 OF 4 2-20 ------- PLEASE I’HIN I i )li 1 ’s I’i IN 1(11 IINSIIAOL I.) AIIIAS ONLY Yl,, lil, il. iIiIui SiliiiL II ,,ll I I I list illt(illil ,iiltill Iii SI khi ii, ,Iiei (list lilt Sd,Ilt? Io(iIl IjfJ iuisii’,il I II I ,liii Iiit iIIl’J hiLtS. ill Ji’S SLE INSTI 1ULI IoNS ONLJMOLN(lnIiIrIlllllIl ii I ,( 1;lll 1L0654321 I ,. , ,,. Aj , , , .! () t?1J N. .‘l)41) ‘IdE s / ii - OU1IALLP SO V INTAKE AND C FF LIJINT ChARACTERISTiCS 1.’ ,i ,iiut ii Ill 1i ,q , Jul h ,, ,i2( ’) PART A, YOu itiiiSl iiovuIv the IUSUIIS 01 at li-isi ibiii. _diidIySIt liii I VCIy iulluitiiit I II this Idlile Cuiiiijlele (she Idlife for racli outfall See Instructions for additional details _________— 2 EFFLUENT 3 UNITS 4 INTAI% ( ipIiuthaI ) I POLLUTANT • MAXIMUM DAILY VALUE b I WEti ? VAt F fl ALU I /V If hI,nk ) I I _______ —. i i ANALY5L . TISATION II MA 5 (I I — “a ANALYSES mg/i LBS • ulocisemc .i Oxygen Ds,nand ( IN)l)J h i Ch. ,rsicsl 0. ygan Osnssnd (Cot ’) C Tilol Osgsnic Carbon (IOC) ii Total Sisilnsiil,l SOlIds IS .5 )) a Ai ’si ’iOi’la ( III 1. I I Flow g T.mpsrsiura (lull Err) s TsmpsraiuII (auulmer) I pH 40.0 590.0 50.0 199.7 65.0 221.1 50.0 429.3 <0.11 <0.44 V ALII 1- 4.591 V A LUL — VALUE 28 MINIMUM MAXIMUM - VAL LIL - V ALUL V ALUL MINIMUM MAXIMUM 76 25.0 18.8 V A LIE 4.563 VALUE 237.0 290.9 VALUE 4 52 1 mg/i mg/i mg/i mg/i P 480 “C LBS LBS - -- - -- - - - LBS - -- -. - --- LBS oc STANDARD UNITS VALUE V A LU S. 52 V ALUL PART 8 . Mark X in column 2 a for each pollutant YOU know o, have reason to believe is present Mark ‘X’ in column 2-b for each pollutant you betueve to be absent If you mark column 2a for any pollutant which is limited eithe: diroclly.or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant For other pollutants for which you mait column 2a. you must provide quantitative data or en explanation of their presence in your discharge Complete one table for each outfall See the instructions lot additional details and requirements I POLLUT ANT AND CAS NO. (I( LualIobIe) 2 MANNA a.. b a, •V . L ,.x •..II xUIU X a Bromide (24959679) b Chiolin., Tot.l Residual x Coior a .1 F xc ii (, ii ,In r. i I x a F 1,0 1 hi. 1169944881 5 I NI.. .. NIu,II. (oa N) PA Fu,m 3610 2C fRey 1 86) “3 F u— i ------- ITEM V B CONTINUED FROM FRONT (1) AIph. , Total (21 Bits. Total I. POLLUT- ANANO (I1uuaaiable) MApI A 3 EFFLUENT t::., MAXIMUM OAILY VALUE b MA*I VALUE cLON Mft CLJ .L T. — 4 CONC N TRATlO UNITS S INTAKE f .pIso,i.dI ANAL A L PA Wt t ta O NltrOOsn , Total Organic (a N) 88 . , 12 39 YSES 4 I. ) vals It Oil and Orsas . I PhO ihOiui (a. P), Total (7723140) x 22 19 4 ib/d x I Radioactivity _____ (3) RadIum Total (4) Radium 226 Total k Sulfate 1 ’. • )ii I 14806 798) I Suit I d. (a. SI m SulfIti I . SOj ) 11426545 3) n Surtactant. 0 Aluminum, Total 11429905) p BarIum. Total (7440393) 8 A A A A A A B K A A A K A q Boron, Total (7440 428) , CObiR, Total (74.40484) Iron, Total (7430-896) t Magnasium, Total (7439 954) MOlybdanurn Total 7439 98 7) v Mangan.s. , Total I 43U 96 bI w tin Total (744031 6) I Ii I I p440 .1? I I A A A A PAGL V 2 F PA Fi utj 3h 10 ‘( ‘ (((fly 1 iIt) ( ON I iN liE tiN PA(,i V 3 ------- EPA I 0 NUMOER (copy from l1)-. , 1 of Form l)JOUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2 C 110654321 j 001 PART C ti you are a primary industry and this outfall contains process wastewater refer to Table 2c 2 in the instructions todetermine which of the GC/MS fractions you must test for Mark X in column 2-a for all suth GC/MS fractions that apply to your industry and for ALL tosic metals cyanides and totaiphenols If you are not required to mark column 2 a (secondary ,ndust ,es. nonproc.sa 4 wassawate, out/ails and non equired GC/MS fractions), mork X in column 2 b for each pollutant you know or have reason to believe is present Mark X in column 2 c for each pollutant you believe is absent If you mark column 281cr any polfutent. you must provide the results of at least one analysis for that pollutant If you mark column 2b for anypollutant you must provide the result. of at feast one analysiS for that pollutant ii you know or have reason to believe it will be discharged In Concentrations of 10 ppb or greater If you mark column 2b for acrolern, acrylonutrife, 2 4 ditritrophanol or 2 methyl 4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of lO0ppbor greater Othutwusa for polluiantsfor which you tnark column 2b. you must either submit at least one anafysisor briefly describe the reasons the pollutant is expected to be discharged Note that there are 7 pages to this part, please review each Carefully Complete one table (all 7 pages) for each outfall See instruCtions for additional details end requirements — I POLLUTANT’ 2 MANN 3 EFFLUENT *il l U..Jc...tS MAXIMUM DAILY VALUE b M AEiM)/M39g AY_VALUE 140_T _VALUE dillooF (Ii ai .uitabh) I ‘ I (.1 •t ’” i.t vses 4 UNITS 5 iNTAKE (upiiom.v17 a CONCEN TRATiON V, .T , 5 bNO* YSSk AVLKAc 1 ’t::: • ‘ .. METALS CYANIDE, AND TOTAL PHENOLS 1M Antimony Total 174403601 x x x x x x X a a 5 S 5 U 024 0.07 - - (J 018 ‘ 0 03 . I ) - - - 4 4 - - mg/i mg/I ---- - -- --- - - 3M A,sen,c Total (74403821 3M B ir y l i i i. ,. 101.1 74404) /1 4M C,.i..o.... Toi. .l 11440 4J .11 ‘it .1 Ciii u ui l (144041 , (( iM Co ipxi Tat*l 1440 5081 iN Laid total li 398 2 II 9M M*rcory Total (14399761 OM N(ck.i Total (74400201 1OM Selaniusi 1016117182 49 21 tiM Sil ai 101*1 1/4402241 I 2M Ti .all 101*1 l 44O 2H 01 13M Ziiic lolai ul44ouG&i 14M Cyniuu.Iu loivI It.) 12 t .l I 1 .M i’ho,,o 1 1 .1 1 . 1 --__ - - -- - - - - - —— - —- — - UIOXIN - - - - liii I ‘ ‘ I . , . Iii’.i lilt,. iai ’ilII5 i . 1 I I , ,. ii , a login Appived ()M8 No 1 (140 0086 A;ip,orali..pi,es / 37 88 EPA Fm,,i,s 3b10 Z(’ fIt.’., 2 H5 iA(.I V I Ll)NllN(It ON HLVtlt L ------- I POLLUTANTI - MAHI A ANDCAS F’ ’ r -— -- NUM8ER J ”• A MAXIMUM DAILY VALUE — IIIa t ’wlobt.t 1: .!: GCIMS FRACTION — VOLATILE COMPOUNDS 1V Acroluin (107 028) _______________ * 2V Acrylonitrile (107 13 I) 3V BInxsn. (71 432) — _______ A 4V 01. CIIICI- ,J mclhyl) Ether ( 54288 l) __ -. A ___ 5V 6,omoform (15252) 6V Carbon T.t,.chlo, do ( 66235) — - — 7V ChIorOb.ni.n. 11089071 x 8V Chtoroh h rOn ,O, ,,Othan o 9V CItIoroellieto 115 0031 ________ * %OV 2 Chluro athyloinyl E the, (110 ! 5 8 ) —— x liv ChIo,oIorn (67 663) __________________ x 12V Otchioro bromOm.th.ne ( 76274 ) x 13V DichIoro- d lfluoto,nsth.na ( 78 718 ) x 14V 1,1 DichIoro .th.ns (76 34 3) i SV 1,2 DichIoro •than. (10706 2) A 16v II DichIoro •thyl•I (16354) 17V 1.2 OrchIoro p.ojan.(78875 1 — - — _____ - _______- I SV I 3 0d4oro Droo$.n. (542 76 5) ID V I Ily Ito, eru (100414) J oy M iI.yI I t n ,. to 114 U I J) 2 1v M. .I. I I .. I I H I I CONTINUED FROM THE FRONT 3 EFFLUENT I , MI IMUM 39 PAY VALUE ( if .it-aiI , j9j j,, , , C LONG Y*$M AVI1O VALUE (U’ ,WeiInbk) .1 NC Ut AN AL Y bL 4 UNITS a CONCUr) IRATION I. MASS 5 INTAKE_(,pIImol) . )IONGTCRM _A.IUIM VAI.UC ANA _________ “I 1.1 ‘Form 3510 2C (Rev 2 85) PAGE V.4 C(WYINUE ON PAGE V) ------- LPA I I N JMULH ( .(.) (n... . Ii . ,, . I ( Foro, I, [ WFALL NUMBER ] U /041) (X1 O CONTINUED FROM PAGE V 4 II n ca i flfl l I / ‘ CLONGTMAVI4 VALUE (sf oUUIlobU) hi 1 NO 0 5 ANAL V SLS 4 UNITS CONC&N I.. MASS 1 RATION S INTAKE 1 ,pt o . . .d) I POLLUTANTI 2 MARK AND CAS h-r —i — NUMBER I .: J ‘-“ a MAaIMUM DAILY VALUL - ilo .u .IutI I : - [ : j • -- L’ [ ( ) .. . GCIMS FRACTION — VOLATILE COMPOUNDS j ,oI 1) 22 J M.th Isna Chin, Id. (75 09 2) 23V 1 1 2.2 Tetro ehIOloeIh aflo ( 79345) — 24V TOt ,aCI1IU,O •thyi.n . (127 18 4) 25V Toloene (10888 3) ______ - .x __ - - 26V 1.2 Trans D lchlo toethylene 6 ) x 21V 11.1 TIl chIO,o e lh.ne ( 71556 ) 28V 1,1 2 T’. chioroethane ( 79006 ) 29V TrichiorO ethylet,e (7901 6) 30V TrichIoro Iluorotneth ane ( 75694 ) - x 31V VIny) Chiotide (7501 4) C/MS FRACTION A 2 Chioropheno (557 8) C LONG TERM _A LL1iA . VALUL : —:: _i.) I. NO A N ALl VIE’ I EFFLUENT 1. MASISMUM 3Q p AV VALUE U, i i — AC 0 COP 2A 2 4 OIch)oro phanOl (120832) x POUt) 3A 2.4 Onnatityl phenOl (1056791 OS 4A 4 6 D,n,s,o 0 Cram) (634521) -& V 5A 2,4 DIn,t,o phenol (61 28 6) 6A 2 Nltrophenol (88 75 5) x 7A 4 N,trophenOl (100027) BA P CI,Ioto M C,esul i59 50 7) I ,., .,. 1,1 I II I ! III, lI lA I 1 11 )1 1) ISA 141, I . . .1.1 hu,,,,I x x x x ------- CONTINUED FROM THE FRONT I POLLUTANT AND CAS- . NUMBER (if a a,?ubi. I GCIMS FRACTION lB AC•fl.phth.n. (83 32 9) 2 MAO,. A I,.. I — BASE/NEUTRAl x 28 Ac•nSphtyIen. (208 968) x x x 38 Aolhr .c.n. (120127) 48 9 .nzIdln. (92875) SB B .nIo(o) An hr.c.n. (66863) 68 Bingo (a) Pyr.na (60 328) —— x x x x x 9 - — 9 9 78 3.4 8anao fluo,aii lh.n. (205992) - 98 R.nzo (gin) Pu Iu,ii (19 )242) -. 96 U.o2o(ii ) F h.o,inih.n. (207 - - 106 8’ . (2 ( .S ,(or,, g (I, , , . y) Muthun. 111911) lB 811(2 Chluru ffiyi ) EtIisr 111444) -— 211 8.12 Chlwa.so apy (Its., (102 601) 138 81.12 EffiyS huzyI) PhthuIat. 111781 7) 148 4Bromo ph.ny( PhsnyI Eth. , ) 10 1653) 1GB Butyl 8 .nayl Phthalat. (85 68 7 168 2Chloro - naphth.I .ns (91587) 118 4ChIorn iifl.nyl Plienyl Eth.r (700572 3) I S O Ch,y.sn. (218019) 190 OIL,.ngo (,, I.) Aflhtiv . i.st,s (53703) 20 )) I 2 D i , I i ), ,. ,, I,a,sionu ( ( lb bO I) 9 9 9 9 eMAA,MUMOAILV VALIJC - i cTTri COMPOUNDS I I I - I I.IJLNT UMAXIMIIM 30 PAY VALUE I I 4 (JNIIS .5 P4 55 or AvP : INATSON b MASS CLONGTJ M . 4 ç VALU [ (It Ui 2iIU(I3• I ___________ S IN T A K L f. ‘ ‘Ih .‘wI —— . i o,.r. icnu I. P50 0 -I. k... ANAL I.) —s.. 2Itj I 3 Olchloso I.*ni..,,* )tS4l Ii I A Form 3510 2C (Rev 2-85) PAGE V-S ------- CONTINUED FROM PAGE V 6 POLLUTANT I AND CAS I— —r- -i- NUMBER i:’i. -.. Iii rnjdijb), ) I I ‘. .V . OC/MS FRACTION — BASE/NEUTRAt 226 1,4 Dichloro b.nz.n. (106 467 x 236 3,3’ DichiorO b.niid lnl ( 91941 ) X 246 DI. )hyl PhIhala ls ( 84682 ) X 266 DImathyl PhthsI.tI ( 131113 ) X — 266 DI N -6U 1y 1 Phihilat . ( 84742 ) - X - - - 276 2,4 Oinlt’o toluena(12l 142) x 286 2.6 DinItlo tOluefla (60620 2) x 299 Di N Octyl Phth . Iate ( 117840 ) X - 308 1,2 Olpheoy ) hydrulns(a*AZo benaene) (122 667 116 Ftuoranthefle 208-440) 1 328 F luorsns 88737) x 330 HWC bS n ( 11 87 ’- ” x 346 Nsa. chIo,ObutSdIaflS ( 87 68 3 ) 358 Hsa.chIOrO cyc lop.ntad l .ns ( 77 47 4 ) 36B HSx.ch(QfO- •thsnl (67 72 1) x 37B Indino (1.2,3 cdl Pyr .ni ( 193396 ) 1 388 l.oDhorone (78691) x 396 NaphIheleflu 191203) X 4011 N lii UIi0 I, 010 i ONUbJ) I Iii N ti.I... ‘ ‘ ‘ I , , . , 47)) N NiI ,iod, P1 I’,,,i, via ,.uIiii, EPA I 0 NUMBER fcog’y (ro.r It.’,,, I of I L0654]21 i Err. ULNI SMA )IIMUM DAILY VALUL b M A Iifl M3 AY VALUE !_i - - ‘S - - COMPOUNDS (cunti,.ued’ / i s , , ,, ElM / i F .,, 11)4/) i/OAt, / ii 88 ------- CONTINUED FROM THE FRONT POLLUTANT z MAHK s FRACTION — BASE/NEUTRA I EF L UCNT C fi ± ANAL — .. I COMPOUNDS (c ,tuuu,d) - — - - - - . - —_. —— -_ . .__ — - - - - -- 4 UFISTS I MASS S INTAKE i.’pt una:i TRATION .— A - - — Phsnanlhren. - - - __ . I) — FRACTION - PESTICID . _ ES x DOT x x x x x x x DDE ODD Endo suIf.,i Endasut l.n Endotullin — 1) I I.IsCU, U I, x x x x x X - - Oj I PA I ,.i.ii .Ih II . ) JC (IIo ., 2 (15) IAL .L V U I CUNflNUE ONPAGEV9 ------- lap (834 PCB 1242 69 21 9) IØP (II PCB 1264 09769 I) 20P (Iii PCB 1221 04282) CONTINUED FHOM PACE V 8 I POLLUTANT i MAU A AND CAS 1 NUMOER MAX! IO LY ±LUE (.1 ,n. ,IohS. I • _______ _LU GCIMS FRACTION — PESTICIDES (co,iSinu t) liP H.ptschlor EpoAids ( 102457 3 ( 23P PCO 1260 (11098825) 24P PCB 1018 (12674 11 2) 25P Toitiphiol ‘8001 35 2) i EFILULNr t MAXIMUM 30 DAY VALUE - - - _W ’ P!cJ —— —— I., PA I 0 NUMOER ( ,og , from II. .,s I of Iurm I) OUTEALL. NUMBLI 110654321 001 eLONG TI fIM l(pG VALUE II ! ,, ,‘ ,,IIAL I.. 1.1 I .., ,. .1 04 18 No I )4U (N)80 / Ii 88 .1 M I) HI A N Al. v..ts 4 liNus a CONLtN I MA 1 RATION 2 1P PC8 1232 (11141 166) 22P PCS 1748 (12672298) x * x x x X * x S INTAKE .- :,;;- . TERM I , NO 0 - .AYEUft I VALUE ANAL (,) .... Y$t$ PAGE V9 ...flh1 IIl... I $11.1 ------- STANDARD PERMIT CONDITIONS ------- STANDARD CONDITIONS IN THE PERMIT • Standard conditions must appear in every NPDES permit. • Standard conditions may be placed in permits verbatim or incorporating them by reference.( 122.41) by TYPES OF STANDARD CONDITIONS • Responsibilities of permittee • Testing procedures • Records retention • Reporting requirements • Penalties for noncompliance LEARNING OBJECTIVES • Role of “boilerplate” • Methods for placing conditions in permits • Type of conditions NOTES: 3-1 ------- RESPONSIBILITIES OF PERMITTEE • Duty to comply • ProperO&M • Duty to mitigate • Need to halt or reduce activity not a defense • Duty to allow inspections/entry • Duty to reapply • Duty to provide information REPORTING REQUIREMENTS • More frequent monitoring • 24 hour report of endangerment • Changed circumstances - Plant alteration/addition - Changed pollutants/flow/production - Sludge use/disposal method • Anticipated noncompliance • Signatory/certification • Upset/bypass reports • Provide information as needed 3-2 ------- OTHER STANDARD CONDITIONS • Nontransferability • Enforcement penalties • Monitoring and records • Bypass • Upset • Permit actions • Property rights NOTES: 3-3 ------- 3-4 ------- PRACTICAL EXERCISE DIRECTIONS : Identifying Standard Conditions Applicable to All NPDES Permits Listed below are examples of standard conditions that apply to all NPDES permits. Using the Code of Federal Regulations, look up each standard condition and provide the proper regulatory citation and a brief description of the permittee’s obligation. (Hint: All standard conditions may be found in 40 CFR S122.41.) Group A (1) Duty to Reapply ( S ) 2) Bypass ( S (3) (4) Permit Transfers ( S Twenty—four Hour Reporting ( S ) (5) Duty to Mitigate ( S Group B (1) Inspection and Entry ( S (2) (3) Upset(S Planned Changes ( S 3-5 ------- (4) Permit Actions ( S ) (5) Need to Halt to Reduce Activity not a Defense ( S Group C (1) Duty to Comply ( S ) (2) Proper Operation and Maintenance ( S (3) (4) Monitoring Reports ( S Signatory Requirements C S (5) Monitoring and Records ( S 3-6 ------- EFFLUENT LIMITATIONS GUIDELINES-BASED LIMITS ------- LEARNING OBJECTIVES • What an effluent guideline is • How effluent guidelines are developed • What the relationship is between: - Effluent guidelines, SIC codes, industrial categories, industrial subcategories, and CFR subparts • How to calculate permit limits using an effluent guideline DEVELOPMENT OF EFFLUENT LIMITATIONS FOR NPDES PERMITS Develop Technology-Based Develop Water Quality-Based Limitations Limitations • Effluent Guidelines • Best Professional Judgment Compare Limitations Apply the Most Stringent 4-1 ------- EFFLUENT LIMITATIONS GUIDELINES Definition - Effluent limitations guidelines are National standards prescribing allowable discharges of pollutants from industrial point source categories corresponding to various levels of treatment or control technologies (BPT, BCT, BAT, PSES, PSNS and NSPS). • Scope - Guidelines are established for most primary and some secondary industries. • CWA Section 304(m) - Guidelines may be developed for new or additional industries, such as: - Solvent recyclers - Barrel reclaimers - Tank car/truck cleaners - Industrial laundries NOTES: 4-2 ------- EFFLUENT GUIDELINES DEVELOPMENT PROCESS • Define industry • Collect data - 308 questionnaire - Sampling and analysis program • Major regulatory tasks - Subcategorization - Select pollutant parameters - Assess representative treatment technologies - Compute effluent limits - Estimate compliance costs - Select option for guidelines • Produce development documents • Perform economic and environmental impact analysis - Assemble record - Promulgate effluent guidelines NOTES: 4-3 ------- Federal Register / Vol. 52. No. 214 / Thursday. November 5. 1987 / Rules and R uLations 4235 including the 5”prioriiy’ toxic pollutants and classes of pollutants. Under the Act, the EPA is required to establish several different kinds of effluent limitations guidelines and standards. They are summarized briefly belowi 1. Best Practicable Control Techno gy Currently Available (BPT ) BPT effluent limitations guidelines are generally based on the average of the best existing performance by plants of various sizes. ages. end unit processes within the category or subcategory for control of familiar (i.e.. conventional) pollutants. in establishing BPT effluent limitations guidelines, EPA considers the total cost in relation to the effluent reduction benefits, the age of equipment and facilIties involved, the processes employed, process changes required. engineering aspects of the control technologies. and non-water quality environmental impacts (including energy requirements). The Agency considers the category-wide or subcategory-wide cost of applying the technology in relation to the effluent reduction benefits. - 2. Best Available Technology £ mically Achievable (B. I ) BAT effluent limitations guidelines. in general. represent the best existing performance in the category or subcategory. The Act establishes BAT as the principal national means of controlling the direct discharge of toxic and nonconventional pollutants to navigable waters. 1 establishing BAT. the Agency considers the age of equipment and facilities involved, the processes employed, the engineering aspects of the control technologies, process changes. the cost of achieving such effluent reduction, and non-water quality environmental impacts. 3. Best Conventional Pollutant Control f chnology (OCT ) The 1977 Amendments to the Clean Water Act added section 30t(bJ(2)(E), establishing “best conventional pollutant control technology” (BC!’) for the discharge of conventional pollutants from existing industrial point sources. Section 304(a)(4) designated the following as conventional pollutants: BOD. TSS. fecal coliform. pH. and any additional pollutants defined by the Administrator as conventional. The Administrator designated oil and grease a conventional pollutant on July 30. 1979 (44 FR 44501). BC!’ is not an additional Limitation but replaces BAT for the r.ontrol of conventIonal pollutants. BAT remain.s in effect tor the toxic and nonconventional pollutants. In addition to other factors specified in section 304(bJ(4J(B). the Act requires that the BCT effluent imitations guidelines be assessed in light of a two part “cost- reasonableness’ test. American Paper v. EPA. 680 F.2d 954 (4th CIr. 1981). The first test compares the cost for pnvate industry to reduce its discharge of conventional pollutants with the cost to publicly owned treotment works for similar levels of reduction in their discharge of these pollutant,. The second test examines the cost-effectiveness of additional industrial treatment beyond BPT. EPA must find that limitations are “reasonable” under both tests before establishing them as BCT. In no case may BCT be less stringent than BPT. EPA has promulgated a methodology for establishing BCT effluent limitations guidelines (51 FR 24974. July 8. 1986). 4 N w Source Performance Standards ( L NSPS are based on the performance of the best available demonstrated technology. New plants have the opportunity to install the best and most efficient production processes and wastewater treatment technologies. As a result, NSPS should represent the mast stringent numerical values attainable through the application of best eva ila tile demonstrated control technology for all pollutants (toxic. conventional and nonconventional). 5. Pretreatment Standards for E’cisting PSES are designed to prevent the discharge of pollutants that pass through. interfere with, or are otherwise incompatible with the operation of publicly owned treatment works (POTWs). The Clean Water Act requires pretreatment standards for pollutants that pass through POTWs or interfere with POTWs’ treatment processes or sludge disposal methods. The legislative history of the 1977 Act indicates that pretreatment standards are to be technology-based and analogous to the BAT effluent limitations gwdehnes for removal of toxic pollutants. For the purpose of determining whether to promulgate national category-wide pretreatment standards. EPA generally determines that there is pass through of a pollutant and thus a need for categorical standards if the nation-wide average percentage of a pollutant removed by well-operated P01W. achieving secondary treatment is less than the percent removed by the BAT model treatment system. The General Pretreatment Regulations. which s t forth the framework for categorical pretreatment standard,, are found at .1 ) CFR Part 403. (Those regulations contnil a definition of pass through that addresses localized rather than nati jnj1 instances of pass through and does nct use the percent removal comparison ‘est described above. See 32 FR l 86. January 14. 1987.) 6 Pre!reatme’it Standards for N w c i Lake PSES. PSNS are designed to prevent the discharge of pollutants that pass through. interfere with, or are otherwis, incompatible with the operation of a POTW. PSNS are to be issued at the same time as NSPS. New indirect dischargers. like new direct dischargers. have the opportunity to incorporate in their plant the best available demonstrated technologies The Agency considers the same fac:ors iii promulgating PSNS as it considers in promulgating NSPS. B. Overview of the !ndusrr-,’ The OCPSF industry is large and diverse, and many plants in the iridu’ y are highly complex. This industry manufactures over 23.000 d:fferent organic chemical,. plastics. and synthetic fibers. However, less than h. of these products are produced in e c .s of 1.000 pounds per year. The industr includes approximately 750 facilities whose principal or primary production activities are covered under the OCPSF SIC groups. There are approximatel ,‘ r other plants which are secondary producers of OCPSF products. i a., OCPSF prodi c:ion is ancillary to th ’r primary production aLtivltie3. (As discussed aoove in this preamble. !‘ms regulation covers OCPSF discha. ’ es from secondary producers. with cer diri exceptions.) This the total number of plants to be regulated totally or in part by the OCPSF industry regulation is approximately 1.000. Secondary OCPSF plants may be part of other chemical producing industries such as the petroleum refining, inorganic chemicals. pharmaceuticals. and pesticides industries as well as chemical formulation industries such as the adhesives and sealants, the paint ar d ink, and the plastics molding and forming industries. Some plants produce chemicals in large volumes while others produce only small volumes of “specialty” chemicals. Large volume production tends to use continuous processes. Continuous processes are generally more effic :e”.t than batch processes in minirnizin 4-4 ------- GUIDELINES AND STANDARDS DEVELOPMENT PROCESS Promulgation of Final Regulations Internal Rev e v Proposed Regulations I Public Cornment Technical Data Development LI ’ 7 • U • S I U • U I S • I I S • S Environmental Impact Assessment [ ] Final Development Review Document L ‘ ------- CONSIDERATIONS INVOLVED IN USE OF EFFLUENT GUIDELINES • Determination of proper category and subcategory • Proper use of applicable guidelines to the category or subcategory • Classification of plants which fall under more than one subcategory • Determination of appropriate measures of production or flow • Use of alternative limits • Application of mass vs. concentration limitations NOTES: 4-6 ------- Page No. 1 03/26/91 1972/ 1977 1987 SIC SIC Code Code 211 211 BEEF CATTLE FEEDLOTS 212 212 BEEF CATTLE, EXCEPT FEEDLOTS 213 213 HOGS 213 213 HOGS 214 214 SHEEP AND GOATS 214 214 SHEEP AND GOATS 219 219 GENERAL LIVESTOCK, NEC 241 241 DAIRY FARMS 241 DAIRY FARMS 251 251 BROILER, FRYER AND ROASTER CHICKENS 252 252 CHICKEN EGGS 253 253 TURKEY AND TURKEY EGGS 254 254 POULTRY HATCHERIES 259 259 POULTRY AND EGGS, NEC 259 259 POULTRY AND EGGS, NEC 271 271 FUR-BEARING ANIMALS AND RABBITS 272 272 HORSES AND OTHER EQUINES 279 273 ANIMAL AQUACULTURE 279 279 ANIMAL SPECIALTIES, NEC 291 291 GENERAL FARMS, PRIMARILY LIVESTOCK 721 721 CROP PLANTING & PROTECTION 72 T21 CROP PLANTING & PROTECTION 291 291 GENERAL FARMS, PRIMARILY LIVESTOCK 921 921 FISH HATCHERIES AND PRESERVES SIC Code Cross Reference and Coaparison of New Toxicity Nuthers with Old VaLues CFR EGO Sub-title Part Code ALL Feedlots Except Ducks Beef Cattle not in Feedtots All Feedlots Except Ducks Hogs not in FeedLots All Feedlots except Ducks Sheep and Goats not in Feedlots GeneraL Livestock Farms All Feedlots Except Ducks DAIRY CATTLE NOT CONFINED ALL FeedLots Except Ducks ALL Feedlots Except Ducks All Feedlots Except Ducks Hatcheries Without Poultry Feeding Ducks Other Poultry Farms Crop Dusting & Spraying Crop PLanting/Cultivation 4-7 1987 Title Old Tox. No. (converted) 412 A NR 412 A MR 412 A MR MR 412 A MR 412 A 412 A 412 A HR 412 8 MR MR MR NR MR MR MR MR MR MR New Toxicity Toxicity No. Murter Reference 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 6 2 1 2 1 2 1 2 ------- Page No. 2 03/ 26/91 1972/ 1977 1987 SIC SIC Code Code 1011 IRON ORES 1021 COPPER ORES 1031 LEAD AND ZINC ORES 1041 GOLD ORES 1041 GOLD ORES 1041. SILVER ORES 1099 METAL ORES, NEC 1061 FERROALLOY ORES, EXCEPT VANADIUM 1061 FERROALLOY ORES, EXCEPT VANADIUM 1061 FERROALLOY ORES, EXCEPT VANADIUM 1061 FERROALLOY ORES, EXCEPT VANAD IUM 1081 METAL MINING SERVICES 1099 METAL ORES, NEC 1094 URANIUM-RADIUM-VANADIUM ORES 1094 URANIUM-RADIUM-VANADIUM ORES 1099 METAL ORES. NEC 1099 METAL ORES, NEC 1099 METAL ORES, NEC 1099 METAL ORES, NEC 1231 ANTHRACITE MINING 1231 ANTHRACITE MINING 1231 ANTHRACITE MINING 1231 ANTHRACITE MINING SIC Code Cross Reference and Corparison of New Toxicity Ni.s±ers with OLd VaLues CFR EGD Sth-tit(e Part Code 440 A Iron Ore 440 J Cu, Pb, Zn, Ag, Au, Mo Ores 440 J Cu, Pb, Zn, Ag, Au, Mo Ores 440 J Cu, Pb, Zn, Ag, Au, Ho Ores 440 M GoLd Placer Mines 440 J Cu, Pb, Zn, Ag, Au, Mo Ores 440 B Aluninun Ore 440 F Tungsten Ore 440 G Nickel Ores 4.40 J Cu, Pb, Zn, Ag, Au, No Ores NR FerroaLLoy Ores, NEC HR Explorat ion/DeveLo nent 440 D Mercury Ores 440 C Uraniun-Radiun-Vanadiun Ores 440 H Variadiun Ore 440 E Titaniun Ores 440 I Antimony Ore 440 K Ptatinun Ores HR Metal Ore, NEC 434 B CoaL Preparation Plants 434 C Acid or Ferruginous Mine Drainage 434 D AlkaLine Mine Drainage 434 E Post Mining Areas I A ‘+ 0 1987 Title OLd Tax. No. (converted) 1011 1021 1031 1041 1041 1044 1051 1061 1061 1061 1061 1081 092 094 094 099 099 099 099 111 111 111 111 New Toxicity Toxicity No. Nuther Reference 7 1 10 1 10 1 10 1 5 7 10 1 10 1 6 1 8 2 7 1 8 2 8 2 8 2 9 1 8 2 4 1 8 2 8 2 8 2 6 2 5 2 5 2 5 2 ------- 42 I Federal Register I Vol. 52. No. 214 I Thursday. November 5. 1987 I Rules and Regulations X I I I. Vai4an s and Modificatiocs Once the OCPSP regulation is in effect. the numerical effi limitations for the appropriate subcata ry must be applied in all Federal and Stata NPDES permits thereafter assuad to O SF direct thschargers. The preuletm,nt standard, are directly applicable to indirect discharger. and become effective a. discuued in 414.12 of the regulation. For the BPT effluent linutations. the only exception to the Limitations contained in the regulation is EPA, “fundamentally different factors” variance. See £ 1. duPont di Nemours and Co. v. Train. 430 LI S. 112 (1977): Weyethoeuur Co. v Cost/a. supm. This variance recogiuzes factors concernings particular discharger that are fundamentally different from the factors considered in this nilemeking. However. the economic ability of the individual operator to meet the complianc, cost foe BPT standards is not a consideration for granting, variance. See Nottonoi Crvshed Stone Association v. £PA. 449 U.S. 86 (1980). Although this variance clause wu ori naUy set forth In EPA’s 1973—1975 categorical industry regulation... It is now included in the general NPDFS regulations and will not be included in the OC SF or other specific industry regulations. See 40 CFR Part 125. Subpart D. The BAT limitations in this regulation also are subject to EPA’s “fundamentally different factors” variance. However. section 305 of the Water Quality Act of 198? added a new section 301(n) to the Act which somewhat limits the availability of FDF variances from BAT effluent limitation. guidelines. An FDF application must be based solely on information end supporting data submitted to EPA during the rulemakuig establishing the limitations that discussed the fundamentally different factors. or oft information and supporting data that the applicant did not have a reuonabl. opportunity to submit during the rulemaking. The alternative requirement must be no less stringent than justified by the fundamental difference and must not result in markedly more advers. rion.water quality environmental impact. than those considered by EPA in establishing the guideline. Indirect dischargen subiect to PSES are also eligible for the “fundamentally different factors” variance. See 40 CFR 403.13. They are subject to essentially the same new statutory provisions for FDF vanance as discussed above for BAT. Readers should note that EPA has not yet amended its FDF variance regulation to conform to the provisions of the Water Quality Act of 1987. The regulation promulgated today refers to the existing regulatory secuona. However. EPA reco uzes that the new section 301(n) of the Act overrides the e’cisti.ng FDF regulation to the extent of any inconsistency, and EPA does intend to modify the FDF regulation to conform to the new statutory requirements. Indirect dischargers subject to PSES and PSNS are eligible for credit. for toxic pollutants removed by a POTW. See section 307(b) of the CWA and 40 CFR 403.7. The removal credits regulation was remanded to EPA LU .Vatw’nl Resources Defense Council v. EPA. 790 F 2d 289(3rd C It. 1986). The court held that some of the means by which EPA considered local POTW removal efficiencies were not sufficiently stringent and that credits far POTW removals may not be authorized until comprehensive regulation.. for the use and disposal of sludge are promulga ted under section 405(d) of the CWA. However, it should be noted that pretreatment standards for the OCPSP industry, like other categorical preneaunent standards. have been promulgated based upon the assumptions that indirect discharger, will be required to comply with the standards without removal credits, and thus that they are subject to the full costs of complying with PSES. XIV. Implementation of Iãmiiadoas and Standards A. Flow Basis The limitation., promulgated today are concentrauon .based and thus do not regulate flow. The permit writer must use a reasonabl, estimate of process wastewater flows and the concentration limitations to develop mau limitations for the NPDES permit. Process wastewater discharge is defined in the regulation (40 CFR 401.11) to include wastewaters resulting from manufacture of OCPSF products that come in direct contact with raw materials, intermediate products. or fin.eJ products. and surface runoff from the imniediate process area that has the potential to become contaminated. Noncontact cooling waters, utility wastewaters, general site surface runoff. ground waters, and other nonprocess waters generated on site are specifically excluded from the definition of process wastewater discharges. In cases where the process wastewater flow claimed by industry may be excessive, the permit writer may develop a more appropriate process wastewater flow for use in computing the mass effluent or internal plant limitations The following items should be considered in developing the more appropriate process wastewe tet flow 1. A review of the component flows to insure that the claimed flows are. in fact. process wastewater flows as defined by the regu1ation 2. A review of plant operations to insure that sound water conservation practices are being followed. Examples are: minimization of process water uses. cascading or countercurrent washes or rinses, where possible: reuse or recycle of intermediate process waters or treated wastewaters at the process area and in wastewater treatment operations (pump seals, equipment and area washdowns. etc.). 3. A review of barometric condenser uss at the process leveL Often. barometric condensers will generate relatively Large volumes of waler con’.”r’-.ted at low levels. Replacement of barometric condensers with surface condensers can reduce wastewater volumes siguificantly and result in collection of condensates that may be returned to the process. The final NPDES permit limitations will be the sum of the mass effluent limitations derived as described above and any mass effluent l i mitations developed on a case-by.case basis using best professional jud ent by the permit writer to take into account nonprocess wastewater discharges. B. Relationship to NPDES Permits The BPT and BAT limitations and NSPS in this regulation will be applied to individual OCPSF plants through NPDES permits issued by EPA or approved state agencies under section 402 of the Act. As discussed in the preceding section of this preamble. these irnutations must be applied in all new. modifIed and reissued Federal and State PDES permits except to the extent that variances are expressly authorized. Other aspects of the interaction between these limitations and NPDES permits are discussed below. One subject that has received different judicial rulings is the scope of NPDES permit proceedings when effluent limitations and standards do not exist. Under cw’rent EPA regulations. States and EPA regions that issue NPDES permits before regulations are promulgated must establish effluent limitations on a case.by.case basis This regulation provides a technical arid legal base for new or modified or reissued permits. One issue that warrants consideration is the effect of this regulation on the powers of NPDES permit issuing authorities. EPA has developed the limitations and standards in this 4-9 ------- 4-10 ------- FeduaJ Register I VoL 50, No. 183 / Friday. September 20, 1985 / Rules and Regulation . 38345 421.302 Effluent Ilmiladon. gwdeliztes represernirig the degre . of effluent reduction attainable by the application of the best practi cable control technology currently available. 421.303 Em . ent ( Imitation. guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable. 431.304 Standards of performance for new eoutc•& 421.301 Pretreatment sd_aids for existing sources. 421 5 Pretreetmues standards for new urcos. 421.3W IReservedi. 350. 421.310 Appllcabilhty- ds.alptlon of the — ninguen end cobalt subentegury. 421.3fl Specialized dofinltloes. 421.312 Effluent linutatlon. guidelines representing the degree of effluent reduction attainable by the appllcatlonjf the best practicable control technology nTontly available. 421 . 313 Effluent limitations guidelines Ua.utiog the degre. of affluent reduction attaInabl, by the appbcadou of the bees available technology l! lW fllCafly achievable. 421.314 Stand_aid, of puformanc, far new 421.315 Pveu’utmens standards for existing sources. 421.316 Preosatment standards for new 421.317 LReserv.d 3.0. 421.330 App4Icablhlty desaiptien of the secondaiy uranium eubcate . 431 .331 $py i.iI.s dsflnftloms. “ '-331 Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best precticabi. omtrol technology currently available. 421.331 Llfluent limitation. guidelines representing the degree of effluent reduction attainabl, by the application of the best available technology economically achievable. 421.324 Standards of performance for new sources. 431.325 (ReservedI. 421. Pretreatment standard_a for new ecureas. 421.W lRessrvedl, Subpart AE-Prlm.ry 31rcon lum and 3.0.- 421.330 Appllcabiliiy deia ptfon of the primary urconium and hafnium subcategory. 421.331 Specialized definitions. 421.332 Effluent limitations guideline, representing the degree of effluent reduction attainabl, by the appbcation of the best practicable control technology currently available. 421.333 Effluent llmitaUo a gwdellnes representing the degre, of effluent reduction attainable by the apphcauon of the bu, available technology economically achievabje. 4.31.334 Standards of performance for new sources. 421.335 (Ra.erv ,4 421.336 Pretreatment standards for new Sources.. 421 . 337 uswe4 1421.140 ta lI t1tQflO$thS — wml The provision. of this subpart are applicable to discharges resulting from the production of antimony at pronasy antimony facilities. f 421.141 SpIi zsd defligUona _ . For the purpoee of thi. subpart the general definitions, abbreviations, and method. of analysis set forth In 40 C ’R 401 shall apply to this subpart. f 431.143 £fl jsnt tit&liona guidelines roptewlb g lbs degree of sfmisnt roduc on afla& .ble by lbs s i..U- fien of lb. best pracliewle oiiUaI tactinuto 1 , 7 Except as provided in 40 R 125.30 through 125.32. any existing point source subject to this subpart shall achiev, the following effluent limitation. representing the degree of effluent reduction attainable by the application of the best practicable control technolvgy currently available (a) Sodium Antimonat. Autoclave Wutswi BPT LIMITATiONs FOR TWI PRIMARY ANTIMONY Su . reooey Rcue u. “iesm 0 WTWy ls5 m — esnes ,d 44sa some — xi.me 14 530 on Ton a_ , .j onm_ • en isa aaoeoo n leo • U I Ii, nigs 75 N 00 g eS. (b) Fouled anolyte. BPT .i&4ITATiOeis FOR ma PRIM* y ANT SUSCAT SQO RY aes*a weosp mgi q ttue on on inI mon soncso 0! - I .sioj soon iesso 4330 3 I Ton iser 640400 304 700 •I -H (cJ Cathode Antimony Wash Water. apr LIMITATIONS FOR TWE PRIMARY ANTIP.IONY e Doles M$ i I , .Q . i q ones on onesi 0 .- Anu H —I es eso 40000 e5. io ‘- Moni Ton .mveia an —I I 20.050 7.012 3125 ‘.ini on Vt 1421.143 Iffluent beWtetle gindith rep -Iu ,.U.9 the degra , of .lmi.m rsducttou, lUaL.dita by the application of lbs but avelimis tadinology SCOflomlOully Except as provided in 40 CFR 125.30 through 125.32. any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable: (a) Sodium Anttmo t. Autoclave Wastswats,. BAT Ul iTATi ,s on ma P iauay Asliwosy SUSCATnGORY Doles sonjii i ij m-, i AVIsub._. M.o#, ‘ ‘ !sl g waies on ion i con I a, . 0 bail nb. Ro .. I 301504 ,3 4 i 0 I 217201 9687 (b) Fouled Anolyte. 4-31 ------- 8348 - Federal Register / Vol. 50. No. 183 / Friday, September 20, 1985 I Rules arid Regulations or 0oA lI oroo?p “ ,WSr (c) Cathode Antimoay Wash Water BAT LIMITATORS FOR THE PRIMARY ANTIMONy Sua GoRY so# - one ‘Uiii ,ma!I , , , = g s 19 I Il — 61 d ,J I, .I—.-—--.v 90310 29.570 429 19.370 1557 1.57 , S4s , 421.144 Slanda.ds of psr omon o for new esuros Any new source subject to this subpart shall achieve the following new source performance standards: (a) Sodtnrn Antimonate Autoclave Wasteweter. NSPS FOR THE PRIMARY A rru 1 IoNv SUaCATEGORY Pe 8 or orops y -, I — —— ‘ — ‘V 6 1 — . 30150 13440 *nuruc I 1 tp 21720 2.344 29S. 9117 0.907 197.511 TaIM ....J.J s H ( ‘) (1) w v 75 too e m . (b) Fouled Anolyte. NSPS FOR THE PRIMARY ANTIMONY SUOCATEGORY or 1 -. W I 1 9w .. ‘ M oire w 0 “M61 o 19 D .,.—--.‘I M vaIp —- — 30150 13,440 21 720 9557 2341 0937 ToI 1 , ..4udm.....__ 234400 1575190 0.• ’---- - ( ‘I ( ‘ I NSP$ FOR THE PRiMARY ANTIMONY SUSCATIGORY or 990 M O20WU PVU - I 61 iC ‘w “ ‘ W I. W 0 I’11 orco.d re — I 43.430 15.370 n §421.145 (Ruarvsdl. o 421.144 PisUsalmant standarls for new Except as provided In 40 CFR 4032, any new source subject to this subpart which Introduces pollutants Into a publicly owned treatment works must comply with 40 CFR Part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants In primary antimony process wastewater Introduced into a POTW shall not exceed the following values: (a) Sodium Antimonete Autoclave Wastewater. PSNS FOR THE PRIMARY ANTIMONY Suecareoonv or oroo.’v MIm?u Il II61 M “ ‘ WIg (port 0 ms61 4 30190 13,110 21720 9117 2.344 OW PSNS FOR THE PRIMARY ANTIMONY SUSCATEGORY PcA i or P100 p Msmvig, , lor Mi ‘or lg/Ig (Pois o “ 0 mu ’. cl0 d b MU .. 50310 25570 -— 43430 ‘9370 M.u’, 4517 1575 §421.147 (Ru.r Isd3. Subpart 0—Primary Beryllium f 421.150 $‘cab’ ty description of the — —. The provisions of this subpart are applicable to discharges resulting from the production of beryllium by primary beryllium facilities processing beryllium ore concentrates or beryllium hydroxide raw materials. § 421.151 SpecIalized defInItions. For the purpose of this subpart the general definitions, abbreviations and methods of analysis set forth in 40 CFR 401 shall apply to this subpart. * 421.152 £flkisnt limitations guidelines rsplsunung the dsgrss of effluent reduction attain ls by thi application of the best pracUcai)Is COUtrIIPI technology cS.irwntiy avslibis. Except as provided In 40 CFR 125.30 through 125.32. any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent _______ reduction attainable by the applicatioii of the best practicable technology 9117 currently availabte ° (a) Solvent Extraction Raffinate from Bertrandlte Ore. BPT UMrTATONS FOR me PRIMARY BanYLIJUM SUCATEGORY or pvp.e ’ Msor’u ” ‘or . 90 14MM 0 bsrt rI CN o m or. bi’i . I- ” 2.753000 ‘.235000 959200 401 300 4.257000 2249000 Cv s 00’.I 65’ 300 258 300 259400000 131900000 ——__________ 78510000 44700000 To ’ . ....J..J . — 92.090 000 4 , 3 800 000 • 1 - I , II BAT IMITATIONS FOR THE PRIMARY ANTIMONY SUSCATE000Y “ ‘WI. ow 0 5ll61 ., mu’. Or — 20180 21720 2.344 till S 9.7 0007 iw 0 75 M 10u’ 10 s,l IM or x 5 01C90Rp 96 ”r ’ nMlWOr M W 8 ’ WIg poriMS ow 0 wr . , I’ M*lI . — 9103lS I 61150 21730 2 . 341 (b) Fouled Anolyte. PSNS FOR THE PRIMARY AN11MONY SIJICATEOCRY u’el..u”qs07SM I00 .d (c) Cathode Antimony Wash Water. (c) Cathode Antimony Washwater. , mu.w ’ .0 75 b $00 M 10 (b) Solvent Extraction Raffinate from Beryl Ore. 4-12 ------- TECHNOLOGY-BASED REQUIREMENTS OF THE CLEAN WATER ACT POLLUTANT LEVEL OF COMPLIANCE CATEGORY TREATMENT DEADLINE Conventional BPT July 1, 1977 Conventional BCT March 31, 1989 Non-conventional BPT July 1, 1977 Non-conventional BAT March 31, 1989 Toxic BPT July 1, 1977 Toxic BAT March 31, 1989 NOTES: 4-13 ------- INDUSTRIAL TECHNOLOGY DIVISiON TECHNICAL PUBLICATIONS AVAILABILITY REPORT JANUARY 1991 w w w w 1_ -U 11T:. _ - - - .... - I - S - . I. _ • - — — -- v- — -. - _________________ - ------- T(CHNICAL PUBLICATIONS AVAILABILITY IIEPORT National Industrial Effluent Guidelines. Limitations, and Standards Issued by IP )US1RIAL TECHNOLOGY DIVISION Office of Water and RegulatiOns Standards Office of Water U. S. Environmental Protection Agency U ’ JANUARY 1991 ------- ABSTRACT Directed by legislative and judicial mandates, EPA continues to ensure protection of the environment by abating and controlling pollution. The Industrial Technology Division’s (a.k.a. Effluent Guidelines Division) role is to provide technical expertise and assistance In the development and Implementation of national standards designe’ to eliminate pollutants being discharged from Industry and municipalities. This Includes establishing uniform national technology based regulations applicable to all facilities within a given industry, and maintaining current data bases for achieving industrial pollution control. Overall, these technology-based regulations are established to achieve effluent pollutant reduction attainable by waste treatment technologies actually employed within an industrial point source category. This report provides information about the technical publications currently available which support the Agency’s rulemaking activities for developing national Industrial point source effluent guideline;, limitations, and standards. The documents and studies listed provide additional background to specific industrial point source regulations codified in the U.S Code of Federal Regulations . Title 40, Parts 400 to 699. For your convienence, the categorical regulations in effect are listed In Attachment A. ------- I NSTRIJCT IONS This report provides a list of the technical publications and studies applicable to the national Industrial effluent discharge rulemaking activities which are currently available to review and distribution as follows: All publications are made available for review and Inspection at the following: 1. ENVIRONMENTAL PROTECTION AGENCY Public Information Center Waterside Mall, S.E., Garage Level 401 H. St., S.W. Washington, D.C. J46O Phone Number: 646-6410 (local), or 800-828-4445 (toll free) 2. Any (PA Regional Office library (Attachment C) 0 Publications can be purchased by subi,itting your request to the following: NATIONAL TECHNICAL INFORNATION SERVICE (NTIS) 5285 Port Royal Road Springfield, VA 22161 Order Desk Phone Nwither: (703) 487—4650 Note: NTIS Accession Number Is required when ordering Additionally, theIndustrial Technology Division projects and contacts for technc lal assistance ‘re listed on Attachment B. Requests for further program assistance, questions concerning the availablity of publications, or Inquiries about the status of rulemaking activities, may be directed to: ENVIRONMENTAL PROTECTION AGENCY Industrial Technology Division (101 552) Attn: Distribution Section 401 N. St., S.W. Washington, D.C. Phone Number: (21)2) 382-7113 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL POINT SOURCE C AT EG OR Y CFR SUBCATEGORY PART NUMBER ______________ EPA PUBLICATION DOCUMENT NUMBER ALCOHOL FOR FUEL (SY N FUELS) 472 • Multimedia Technical Support Document for Etha noI fur Fuel Industry EPA 440/1-861093 P 1386/177557/AS • Low BTU Gasifier • Battery Manufacturing (Proposed) • Battery Manufacturing (Final) EPA 440/1-84/067 Vol I Vol II P886/2454 38/AS NTIS ACCESSION NUMBER GPO STOCK NUMBER BATTERY MANUFACTURING ALUMINUM FORMING 467 • Aluminum Forming (Final) EPA 440/1-84/073 Vol I Vol II PBS4-244425 PBR4-244433 ---- ASBESTOS MANUFACTURING 427 • Building, Construction and Paper (Final) EPA 440/1-74/017-a PB238320 16 5501-00827 • Textile, Fnction Matenals & Sealing Devices (Final) EPA 440/1-74/035-a EPA 440/1-82/067-b PB240860/7 PBS3 . 197921 . ---- 461 P885- 121507 P1385-121515 ------- BUILDERS PAPER & BOARD MILLS • Builders Paper & Roofing • Board & Builders’ Paper & Board Mills (Proposed) EPA 440/I -80/025-b PB8 I-20 1535 • Pulp, Paper & P.ipcr- Board and Builders’ Paper & Board Mills (Final) EPA 440/1-82/025 PB83- 163949 I - . CANNED & PRESERVED 407 • Apple. Citrus & Potato EPA 44 0/I-741027-a PB23864918 5501-00790 FRUITS & Pnxessing VEGETABLES 431 430 EPA 44 0/I- 7 4/026-a PB238076/45 5501-00909 ------- INDUSTRIAL TECHNOLOGy DIVISION PUBLICATIONS SOURCES OF AVAILABILITY .1;- 1’., 0 INDUSTRIL POINT SOURCE CATEGORY CFR PART NUMBER EPA PUBLICATION DOCUMENT NUMBER SURCATEGORY NTIS ACCESSION NUMBER GPO STOCK NUMBER ALCOHOL FOR 472 • Multimedia Technical FUEL Support Document for 440/1-86/093 PB B6/I77557 1AS ---- (SYNFUELS) Ethanol for Fuel Industry • Low BTU Gasitier Wastewat r (1986) PB86/245438/AS - ALUMINUM 467 • Aluminum Forming FORMING (Final) 440/1-84/073 ASBESTOS 427 • Building, Construction I Volume II EPA 44 O/l-74/0 17-a PRX4-24442 5 PB84-244433 MANUFACTURING and Paper (Final) PB238320/6 5501-00827 S Textile, Fnction Materials & Sealing Devices (Final) EPA 44 O/l- 7 4/035-a PB24086017 ---- BArFEKY 461 5 Battery Manufacturing EPA 440/l-82/067-h PB83-I9792l MANUFACTURING (Proposed) - - -. S Battery Manufacturing (Final) EPA 440/l-84/067 Volume I Volume II PB85-I2 1501 PBS5- 12 15 15 ..-- -•-- ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL POINT SOURCE CATEGORY CFR PART NUMBFR SUBCATFGORY • Catfish, Crab, Shrimp (Final) • Fishineal, Salmon, Bottom Fish. Sardine, Herring, Clam, Oyster. Scallop, & Abalone (Final) • Report to Congress, Se iioii 74 Sealootl Processing Executive Summary (Volumes I-Ill) Processing Executive EPA 440/1-80/020 Volume I EPA 44011-80102Gb Volume II EPA 44 O/l-801020c Volume Ill P881- 182354 PB8I- 182370 P88 1-182388 ACCESSION S COCK BUILDERS PAPER & BOARD MILLS 431 430 • Builders Paper & Roofing EPA 440 / 1- 7 4 1 026-a P8238076/4 5501-00909 ‘ Board & Builders’ Paper & Board Mills (Proposed) EPA 440/ 1-80/025-h P881-201535 ---- • Pulp. Paper & Paper- Board and Builders’ Paper & Board Mills (Final) EPA 440/1-82/025 P883-163949 ---- CANNED & PRESERVED FRUITS & VEGETABLES 407 • Apple, Citrus & Potato Processing EPA 44 OIl- 7 4 1 027-a P8238649/8 5501-00790 408 CANNED & PRESERVED SEAFOOD PROCESSING EPA 44 O/I- 7 5/041-a P 82 56 840/0 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SUBCATEGORY • Cement Manufaciunng (Final) • Coal Mining (Proposed) • Coal Mining (Final) • Co)l Coating. Phase I (Final) • Coil Coaling, Phase II- Canmaking (Proposal) • Coil Coating. Phase II- Canmaking (Final) • Best Technology Available for the Location Design Construction & Capacity of Cooling Waler Intake Structures for Minimizing Adverse Environmental Impact (Final) • Copper (Final) • Dairy Products Processing (Final) INDUSTRIAL POINT SOURCE CATEGORY CEMENT MANUFACTURING COAL MINING CFR PART NUMBER 411 434 I ’- ) COIL COATING 465 EPA PUBLICATION DOCUMENT NUMBER EPA 44 O/I-741005-a EPA 440/1-81/057-b EPA 440/1-82/057 EPA 440/1-82 107 1 EPA 440/1-83/071 EPA 440/1-83/071 EPA 44 O/I-ló/OIS-a SOURCES OF AVAILABILITY NTIS GPO ACCESSION STOCK NUMBER NUMBER P13238610/0 5501-00866 P1381-229296 P1383/180422 P1383 -205542 PB83- 198598 P1384-198647 PB-253573,0 COOLING WATER 402 INTAKE STRUCTURES -h COPPER 468 FORM INC DAIRY PRODUCTS 405 PROCESSING EPA 440/1-84/074 PB84- 192459 ---- — ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SURCATEGORY DOCUMENT NUMBER NUMBER NUMBER DOMESTIC SEWAGE ---- • Report to Congress on EPA 530•SW-86-004 PB861 1840 171AS STUDY - the Discharge of hazardous Wastes Hazardous Wastes to PubhLly Owned Treatment Works (Final) DRUM RECONDITIONING ---- • Drum Reconditioning EPA 440/ 1 -89/10 1 ---- INDUSTRY ELECTRICAL 469 • Ekct,ical & Electronic EPA 440/1-82/075-h PB82-249673 & ELECTRONIC Phase I ( Proposed) COM PONENTS • Ekctri aI & Electronic Components Phase II (Proposed) EPA 440/1-83/015-b PB83- 199208 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SURCATEGORY DOCUMENT NUMBER NUMBER NUMBER ELECTROPLATING 413 • Copper, Nickel, Chrome EPA 440/I-74/003-a P11238834/AS 5501-00816 & METAL FINISHING & 433 & Zinc (Final) • Eleciroptating- EPA 440/1-79/003 P 1 180-I964 8 8 Pretreatment (Final) • MeldI Finishing EPA 440/ 1-82/09 1-h P1183- 102004 (Proposed) S Metal Finishing EPA 440/1-83/091 P1184-I 15989 (Final) • Guidance Manual for EPA 440/I-84/09 1g Electroplating and Metal Finishing Pretreatment Standards (February 1984) • Guidance Manual br Implementing Total Toaic Organic (TTO) Pretreatment Standards (September 1985) FEEDLOTS 412 • Feedlots (Final) EPA 440/1-74/004-a P1123851/AS 5501-00842 FERROALLOY 424 • Smelting& Slag EPA 440/1-74/008-a P11238650/AS 55OI-’J’ 78o MANUFACTURING ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS INDUSTRIAL POINT SOURCE CATEGORY FERTILIZER MANUFACTURING EPA PUBLICATION DOCUMENT NUMBER CFR PA RI NUMBER 418 CLASS 426 • MANUFACTURING . . GRAIN MILLS 406 S SUI3CATEGORY • Basic Fertilizer Chemicals (Final) • Formulated Fertilizer (Final) Pressed & Blown Glass (Final) lfl,Ul at ion Fiberglass (Final) Flat Glass (Final) Grain Processing (Final) Animal Feed, Break last Cereal & Wheat (Final) Ilu7lIrdnhis Waste Treatment SOURCES OF AVAILABILITY NTIS GPO ACCESSION STOCK NUMBER NUMBER PB23 8652/AS 5501-00969 PB240863/AS 5501-01006 PB2S6854/l 5501-01036 PB238078/0 550 1-00781 P1 3238-907/0 5501-00814 PB2383 16/4 5501-00844 PB24086 1/5 5501-01007 EPA 440/l-74/OlI-a EPA 44 O/l. 7 S/ 0 42-a EPA 440/I - 7 5 1 034-a EPA 440/1-74/001-b EPA 4 40/l-74/OOI-c EPA 44 O/I-74/028-a EPA 440/I -74/039-a • --- EPA 440/1-89/100 llA/LAKI)OIJS WAS II. 1 REATMENT INDUSTRY 1-IOSPITALS ---- • Hospitals EPA 440/1-89/060-N ---- IND(JS1 RIAI ---- • Industrial Laundries EPA 440/1-89/103 ---- LAUNDRII S ------- INDUSTRIAL TECHNOLOGy DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE, PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SUBCATEGORY DOCUMENT NUMBER NIJMBER NUMBER INORGANIC 415 • Major Inorganic EPA 44 O 1 I-?4/0O7-a P8238611/B 5502-00121 CHEMICALS Chemical Products MANUFACTURING (Final) • Inorganic EPA 440 11-80/007-b P881-122632 Chemicals Manufac- turing Phase II (Proposed) 0 ’ • Inorganic EPA 440/1-801103 Chemicals (Treat- ability Study) • Inorganic EPA 440/1-82/007 P882-2656,2 Chemicals Phase I (Final) • Inorganic EPA 440/1-84/007 PBSS-l56446/XAH Chemicals Phase II (Final) ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SUBCATEGORY DOCUMENT NUMBER NUMBER NUMBER IRON & STEEL 420 • Steel Making EPA 440 /I- 741 024-a P8238837/9 5501-00906 MANUFACTURING • Iron & Steel EPA 440/1-80/024-b *pflgl. 184384 (Proposed) Volume I P881-184392 Volume II PB8I- 184400 Volume III PB8I- 1844 18 Volume IV P881-184426 Volume V P881-184434 Volume VI P881-184442 (*Set of Volumes I thru VI) • Iron & Steel (Final) EPA 440/1-82/024 Volume I PB82-240425-a Volume II P882-240433-h Volume III P882-240441-c Volume IV P882-240458-ti Volume V PB82-240466-e Volume VI P882-240474-f • Guidance Manual f r Iron and Steel Pretreatment Standards, September 1985 LEAThER TANNING 425 • Leather Tanning & EPA 4 4 0/I-74/0l6-a P8238079/8 5501-00818 Finishing (Final) • Leather Tanning (Final) EPA 440/1-82/016 P883-172593 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL POINT SOURCE CATEGORY EPA PUBLICATION DOCUMENT NUMBER METAL MOLDING & CASTING (FOUNDRIES) CFR PART NUMBER SURCATEGORY I ’ . , NTIS ACCESSION NUMBER GPO STOCK NIJ M HER MACHINERY MANUFACTURING AND REBUILDING INDUSTRY --- S Machinery Manufacturing EPA 440/1-89/106 .-. MEAT PRODUCTS AND RENDERING 432 • Red Me ii Processing (Final) EPA 44 O/I- 7 4/O 12-a PB238836/As 5501-00843 METAL FINISHING 433 Renderer (Final) SEE ELECTROPLATING FOR LISTING EPA 440/I-74/03 1-d PH253572/2 ---. • Metal Molding & Casting Volumes I & II (Proposed) • Metal Molding & EPA 440/1-85/070 Casting (Final) PB86- 16 1452/XAB ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SUBCATEGORY DOCUMENT NUMBER NUMBER NUMBER MINERAL MINING & PROCESSING 436 • Minerals for the Construction Industry EPA 440/1-75/059 P0274593/3 ---- • Miner.d Mining (F,n I) EPA 440/I-76/059h P1380110299 ---- • Report to Congress The Etk .t of Di harges from Limestone Qudrrtes on W4te1 Quality and Aqu4tlc Biota (Final) EPA 440/1-82/059 P1382242207 ---- NONFERROUS METALS FORMINJO 471 • Nonferrous Metdls Forming (Final) EPA 440/1-84/0 19-b Volume I Volume II Volume III ---• PB83/228296 P083/228304 P883/228312 ---- NONFERROUS METALS MANUFACTURING 421 • Bauxite Refining- Aluminum Segmeiit (Fin iI) EPA 4 40/I-74/019-c P0238463/4 5501-001 16 • Primary Aluminum Smelting - Aluminum Segment (Final) EPA 440/l-74/0 19-d P13240859/9 5501-00817 • Secondary Aluminum Sincli ing — Aluminum Seguiient (Final) EPA 44 O/I- 7 4 1019-e P13238464/2 5501-00819 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SURCATEGORY • Onshore (Final) Includes Offshore • Oil & Gas Extraction (Proposed) • A’,sessmcnt ot Environmental Fate & Effects of Discharge from Offshore Oil and Gas Operations • Oil Reclamation • Ore Mining and Dressing Volume I (Proposed) • Ore Mining and Dressing Volume II (Proposed) • Ore Mining & Dressing (Proposed) • Ore Miniiig& Dressing (Final) • Gold Placer Mining Subcategory (Proposed) SOURCES OF AVAILABILITY NTIS GPO ACCESSION STOCK NUMBER NUMBER INDUSTRIAL POINT SOURCE CATEGORY CFR PART NUMBER 435 OIL & GAS EXTRACTION EPA PUBLICATION IDOCUMENT NUMBER 0 EPA 440/1-76/055-a -•-- ---- EPA 440/1-89/055 PB86- 1 14949/XAB --•- EPA 440/4-85/002 PB8o/I OIL RECLAMATION ---- ORE MINING 440 AND DRESSING PB2865201AS PB28652 I/AS PB82 -250952 EPA 440/1-89/014 EPA 440/I-78/06l-d EPA 440/l-78/06l-e EPA 440/1-82/061-h EPA 440/1-82/061 EPA 440/ 1-85/061-b ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SUBCATEGORY DOCUMENT NUMBER NUMBER NUMBER ORGANIC CHEMICALS, 414 • Major Organic Products EPA 440/1-74/009-a P824 1905/9 5001-008812 PLASTICS. AND &4I6 (Final) SYNTHETIC FIBERS MANUFACTURING • Organic Chemicals & EPA 440/ 1-83/009-h PB 3-205625 ’ Plastics & Synthetic Volume I P1183-205633 Fibers (Proposed) Volume II PB83-205633 Volume III P1183-205658 (‘Set ol Vol’s I thru III) • Synthetic Resins EPA 440/1-741010 PB2-3924 1/3 5501-00815 • Synthetic Polymers EPA 440/1-74/036 PB240862/3 550 1-01012 • Selected Summary of Information in Support of Organic Chemicals, Plastic & Synthetic Fibers. July 1985 PAINT FORMULATING ---- • Paint Formulating EPA 440/1-89/050 ------- INDUSTRIAL TECHNOLOGy DIVISION PUBLICATIONS SOURCES OF AYh LABILITY INDUSTRIAL POINT SOURCE CATEGORY CFR PART NUMBER PHOSPhATE MANUFACTURING Phosphorus Denved Chemicals (Final) • Other Nan-Fertilizer Chemicsls (Final) EPA 440/1-751043 SURCATECORY EPA NTIS GPO PUBLICATION ACCESSION DOCUMENT NUMBER NUMBER STOCK PESTICIDES 455 S Pesticides (Final) EPA 44 O/l- 7 8/060-e PB285480/0 S Pesticides (Proposed) EPA 44 O/l-89/060-e PB83- 153 17I • Test Methods for Non- Conventional Pesticides Chemical Analysis of Industrial & Municipal W sew at r EPA 440/ 1-82/079-c PB83- 176636 • Pcsiiude . (Final) NOTE FINAL REGULATION EPA 440/1-85/079 PB86-l5 0 042/XAB WAS WITHDRAWN 1986 -- a resiudy h s been initiated by the Agcn y PETROLEUM REFINING 419 S Peiiokum Refining (Final) EPA 44 O/l- 7 4/0 14-a P82386 1216 5SOI-Oo )l2 • Petroleum Refining (Proposed) EPA 440/1-79/014-b P881-118413 PIIARMACE(JTICAI S MANUFACTURING 439 • 5 Petroleum Refining (Fi,ial) Pliurinai.etitiial (Final) EPA 440/1-82/014 P883-172569 EPA 440/1-83/084 PB84- 180066 422 5 EPA 440/1-74/006-a PB24 10 18/I 5503-00078 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABIliTY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SUBCATEGORY DOCUMENT NUMBER NUMUER NUMBER PHOTOGRAPHIC 459 0 Guidance Document for EPA 440/1-81/082 PB82- 177643 ---- I ROCESSING the Control of Water Pollution in the Photographic Processing Industry PORCELAIN 466 • Porcelain Enameling EPA 440/l-8I/072-h PB8I-20 1527 ---- LNAMELING (Propo.ed) 0 Porcelain Enameling (Final) EPA 440/1-82/072 ---- ---- PUBLICLY OWNED • Fate of Priority EPA 440/1-82/303 TREATMENT WORKS Pollutants in Publicly Owned Treatment Works (Volumes I & II) Volume I Volume II PB83/ 122788 PB83- 122796 ---- ---- ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SURCATEGORY DOCUMENT NUMBER NUMBER NUMBER PULP. PAPER 430 • Unhleached Kraft and EPA 4 40/I-741025-a PB238833/AS AND PAPERBOARD Semi-chemical Pulp (Final) • Pulp. Paper & Paper- EPA 440/1-801025-b PB8I-20l535 Board and Builders’ Paper & Board Milk (Proposed) • Pulp. Paper & Paper- EPA 440/1-89/025 PB83- 163949 hoard and Builders’ Paper & Board Mills (Final) • Development Document EPA 440/1-86/025 P887-172243/AS for Best Conventional Pollutant Control Tethiiology Pulp. Paper, and Paperhoard RUBBER PROCESSING 428 • Tire & Synthetic (Final) EPA 44 O/l- 7 4/0 13-a P8238609/2 5501-00885 • Fabricated & Reclaimed Rubber (Final) EPA 440/1-74/030-a P8241916/6 5501-01016 SOAPS & 1)1 - rLR ;LNI FS 417 • Soaps & Detergents (I iiinl) EPA 440/1-74/018-a PB23X613/4 s5ol- x 7 ------- INDUSTRIAL TECHNOLOGY DIVISION PUBLICATIONS INDUSTRIAL POINT SOURCE CATEGORY SOLV ENT RECYCLING IN U STR V STEAM ELECTRIC POWER PLANTS EPA PUBLICATION DOCUMENT NUMBER SOURCES OF AVAILABILITY NTIS GPO ACCESSION STOCK NUMBER NUMBER CFR PART NUMBER SUBCATEGORY •Solvent Recycling L i i EPA 440/1-89/102 423 • • Steam EIe4Jrlc Power Generating (Final) Steam EIotrmL (Proposed) EPA 44Ofl-74/029-a EPA 440/1-80/029-h P8240853/2 P881-I 19075 5501-01001 ---- SUGAR PROCESSING 409 • • Beei Sugar (Final) Cane Sugar Refining (Final) EPA 440/1-74/002-b EPA 440/I-74/002-. P8238462/6 PB238 147/3 5501-00117 5501-00826 TEXTILE MILLS MANUFACTURING 410 • Textile Mills (Final) EPA 440/1-74/022-a P8238832/AS 5501-00903 • Textile Mills (Final) EPA 440/1-82/022 P 883-I 16871 ---- TIMBER PRODUCTS PROCESSING 429 • Wood Furniture and Fixtures (Final) EPA 440/1-74/033-a ---- ---- • Timber Products Processing (Proposed) EPA 440/1-79/023-b ---- ---- • I iiiilitj PioduLts ProLe sing (Final) EPA 440/1-81/023 PUHI-227282 ---- ------- INDUSTRIAL TECHNOLOGy DIVISION PUBLICATIONS SOURCES OF AVAILABILITY INDUSTRIAL CFR EPA NTIS GPO POINT SOURCE PART PUBLICATION ACCESSION STOCK CATEGORY NUMBER SURCATEGORY DOCUMENT NUMBER NUMBER NUMBER TRANSPORTATION • Transportation EPA 440/1-89/104 EQUIPMENT Equipment CLEANING Cleaning INDUSTRY C .’ ------- —, unus ’i uiv .. FA I ,wI NIN u—41 i __ U fli — S•in S..M ..I - — n.n.,,.. _ -, — - __ .. . _ _ ae.nns ___ t __ * __ -...-a— --r g, . *,sSu d IM W Ss . NS S o. S r i - — l ____ — - ss I_ a—w I d U a • I, IW dsI T L I ISdsS PUBLICATIONS AVAILML( FROM TIlE INDUSTRIAL TECHNOLOGY DIVISION (ANALYTICAL ItTIlOOS $ REFERENCES) ‘ 1 Nst od 1 113a ?.trs- Thro. Oot- 1ocI stsd Dtozt . . o1 tt1. orsato by 1sQ%iayis DIL stjosi tot 1.ct DILst1o . 1JC/. sv1 Lo. . . .m aszs 1vo1.t1i. y.ALo O 4J 3 by *.U SMI. t.nt Dtliitlo. , j m t o IllS I Oriao-b .L*dS N.tt0t . &1 1 . tnw*r . SasfotT flsIal• r.r.l. . P .—’ .rp-.c1d Uss toIs. by U1 S r taaMxe. * 1 -w. —i• esyllisry G . tOgZ j 1tb M1.otIv. 11 5 5 Ostoctots. J 1y 155 5. ____ LLst.t L$st./& to155 ot £s lptau s t ls S• Off Los N.tMd 11351 t1S by 1 LIVS1y C 1.d 51o Atoslo . . . .ysIst1... oss iaa1os $psatr.oso py aM Itosis Moorpitos spsctzusoopy iso.. 1 stt), S.pt .r 155*. 5a 1 1., P oos zo. aM Protoosi. toe t . es ’$aosl liMp. S rroy. — —i t I S I S. Note: Questions concerning the above reference .atertals should be addressed to: Willie. A. Telliard Industrial Technology Division (wH- b2) USEPA 401 N St. SW Washington, DC 20460 (202) 382-7131 ------- OWRJITD Preliminary Data SuTnmaries——1989 EPA 440/1-89/014—-Pr.liminary Data Summary for the Vied oil R.clamatiOn and Re-Refining Industry EPA 440/1-89/060n—-Pr.liminarY Data Summary for ths Hospitals Point Source Category EPA 440/l—89/060a-—Preliminary Data Summary for th. Pesticide Chemicals Point Source Category EPA 440/1-89/025—-Preliminary Data Summary for the Pulp, Paper and Paperboard Point Source Category EPA 440/1-89/050—-Preliminary Data Summary for the Paint Formulating Paint Source Category EPA 440/1-89/084——Preliminary Data Summary for the Pharmaceutical Manufacturing Point Source Cat.gory EPA 440/1-89/100——Preliminary Data Summary for the Hazardous Waite Treatment Industry EPA 440/1-89/101--preliminary Data S ary for the Drum Reconditioning Industry EPA 440/1-89/102--preliminary Data Summpry for the Solvent Recycling Industry EPA 440/1-89/1 03——Pr.liminary Data Summary for the Industrial Laundries EPA 440/1—89/104——Preliminary Data Summary for the Transportation Equipment Cleaning Industry EPA 440/1-89/105--Preliminary Data Summary for the Coastal, Onshore and Stripper Subcategories of the Oil Gas Extraction Point Source Category EPA 440/1089/106-—Preliminary Data Si ary for the Machinery xanufacturing and Rebuilding Industry 4-38 ------- INDUSTP2AL CATT.GOP. .tES SUBJECT TO NATIONAL EYTLUZ?rr LIMITATIONs AND STAJJ AJ S Z1IDUS RIAL II Q £ I M3ER A1umirn Terming 467 Asbestos Manufacturing 427 Battery Manufacturing 461 Builder’s Paper 431 Carbon Black Manufacturing 458 Cement Manufacturing 411 Coal Mining 434 Coil Coating (Phase I and II) 465 Copper Forming 468 Dairy Products Processing 405 Electroplating 413’ Electrical and Electronic Components (Phases I and II) 469 Explosives Manufacturing 457 Peedlots 412 Ferrealloy Manufacturing 424 Fertilizer Manufacturing 418 Fruits and Vegetables Processing Manufacturing 407 Glass Manufacturing 426 Grain Mills Manufacturing 406 Ot and Wood Chemicals 454 Bospitals 460 mu Formulating 447 Inorganic Chemicals (Phases I and I l) 415 Iron and Steel Manufacturing 420 Leather Tanning and Finishing 425 Meat Processing 432 Metal Finishing 433” Metal Molding and Casting 464 Mineral Mining 436 Nonferrous Metals Forming 471 Nonferrous Metals Manufacturing (Phases I and II) 421 Oil and Gas Extraction 435 Organic Chemicals and Plutics and Synthetic Fibers 414” Paint Formulating 446 Paving and Rooting (Tars and Asphalt) 443 Pesticides 455 Pstrole Refining 419 Pharmaceuticals 439 Phosphate Manufacturing 422 Photographic 459 Plastics Molding and Forming 463” Porcelain ling 466 Pulp and Paper 430 Rubber Processing 42$ Seafood Processing Manufacturing 40$ Soaps and Detugents Manufacturing 417 Steam Electric 423 Sugar Processing Manufacturing 409 Timber Exoducts Manufacturing 429 Textiles 410” Cross reference to Metal Finishing, Part 433 “Cress referenc: to Electroplating, Part 413. ““O’aai. Chemicals and Manufacturing” (40 CFR Part 414) had been combined with the Plastics and Synthetics” point source category (40 C l i Part 416): pretreatment standards for new sources are st li .n effect as previously identified under 40 Cli Part 414, Subpart 1. “Category is regulated only by the general pretreatment standards found in 40 CTR Part 403. 4-39 ------- RUERENCU POR WA$TEWAIIR PCWITANT PVO UATION -‘40 CP 401.15 T c PoII f1u L 66 p i *s d. .d pini ri to O n V ir d $i 1 307 i)(1) 40 R 401.16 Cwrd1oe J Po . : L 5 ooiwW poIi 1s dSv op.d piww to VA 304 a)(4). 40 R Pail 423, Pdodly Po ’ s dsr from 66 To P &aarts; 1 t i. Appsrd A O 4 a: Odgir&y o W d 1 pdbWls; i 17,40 and 50 ban d. .) Ni ndor P iW kduds. tw p &awts n uIU’1iI.d — oor *i dc idodt 1 p ,u. OTHER EFFLUENT OUIDEUNES CONTACTS a w i S port U T id. Sin I4w ak.r ( QIarnIG& T M hods) C R.rnIi*ç isry P sUnss U T.I*sd — Do u 1i_ Jo. Vk Eeonor* *, U N Pg AED) u 1 G Gu sn (CWA 304m Pun) Fud Si Td td Fo s £ kwsrago.-M c. Don Mdsraon H Gsorg. J L ITU GaaX gIon Si TdI d k w P.’ ’ At ys r Hiiuy I m ( AED ) $içsrfwd B*s Did*rgss ody Foul Watsr & Øy Don kdsruon 4-40 ------- OFFICE OF WATER REGULATIONS AND STANDARDS INDUSTRIAL TE INOLOGY DIVISION DECVIBER 1990 OFFICE OP TEN DIRE OR O ‘Farrell, Thomas Luttner, Mark Brooks, 7san Coughlin Harold Strassler, Eric Svann, Carol Thoapson, Marion AIALTTI AL ILWTEODB IThPP Telliard, Wi1lia Honak.r, Ben 382—7120 382—7120 382—7120 382—7192 382—7150 382—7120 382—7117 382—7131 382—2272 911C ET 913k ET 911 Bay ET 9l3D ET 911k ET 911 Bay ET 9113 ET 909B ET 9073 ET Anderson, Donald Dunnigan, Th.1 a Heath, G.orge Hund, Frank Smith, Wendy williaRs, Richard 382—7137 382—7137 381—73.65 382—7182 382—7184 382—7186 915k ET 915 Bay ET 9113 ET 909k ET 9llD ET 917k ET c ZgIcALB B kNCI Elvood Forsht DiCianna, Debra Jett, George 382—7190 382—7141 382—7151 9015 ET 913C ‘r 905k ET ENERGY BRAJICI Rubin, Marvin Fielding, Tho aa Goodwin, Janet Jordan, Ronald Kirby, Ronald Stallard, Linda Vitalis, Joseph Wise, Hugh 382—7124 382—7156 382—7152 382—7115 382—7168 382—7124 382—7172 382—7177 901C ET 917B ET 913E ET 913C ET 913B ET 901 Bay ET 908 ET 913B ET XZTALB URICI Hall, Ernst Jarrett, B. Matthew Lee, Barbara Rajvanshi, Sabita 382—7126 382—7164 382—7126 382—7153 905C ET 907k ET 905 B Y ET 905B ET 4-41 ------- 4-42 ------- PRACTICAL EXERCISE Calculating Daily Maximum and Monthly Average Permit Limits Using Effluent Guidelines SITUATION You are the permit writer responsible for drafting the permit for Luster Glass, Inc., a glass manufacturer in Morris, Illinois (1L0654321). After reviewing the application formB 1. and 2C and the effluent limitations guidelines and standards for the Glass Manufacturing point source category (40 CFR Part 426) you begin to develop the effluent limitations for the process wastewatere, to be included in the permit. DETERMINE : The daily maximum and monthly average effluent limitations for Oil and Grease, TSS, Phosphorus, and pH for the process wastewater contribution to Outfall 001 at Luster Glass. Show all calculations and assumptions. 4-43 ------- 4-44 ------- Part 426 TABLE OF STUDENTS t VALUES AT THE 99 PERCENT CONFIDENCE LEVEL N svtsr of reptc$tss Degrees . (n_I) 99) 7. . . 9 . 10 ... . 11.... .. 16 . . . ._.... 21... 26.. .. . 31 SI .. 6 7 8 9 10 15 20 25 30 80 3143 2996 2896 2821 2764 2.602 2.528 2485 2457 2390 2 326 (53 FR 9188, Mar. 21. 1988] PART 426—GLASS MANUFACTURING POINT SOURCE CATEGORY Subpart A—lnsulatlan Fiberglass Subcat.g.ry 8e 426.10 ApplicabilIty; description of the In- 8U]atlon fIberglaBs subcategory. 426.11 Special definitions. 426.12 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.13 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable. 426.14 (Reserved) 426.15 Standards of performance for new sources. 42616 Pretreatment standards for new sources. 428.17 Effluent limitations guidelines rep- resenting the degreee of effluent reduc- tion attainable by the application of the best conventional poliutant control technology (BCT). Sub zvt I—Sh..t Glass Monufoctw4ng Subuit.go y 426.20 ApplicabilIty; description of the 8heet glass manufacturing subcategory. 426.21 Specialized definitions. 426.22 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. Sec. 40 CFI C l i. I (7-1-19 EdItIon) 426.23 Effluent limitations guidelines rep- resenting the degree of effluent redUC tion attain&ble by the application of the best available technology economically achievable. 426.24 Pretreatment .ndards for existing sources. 426.25 Standards of performance for ne sources. 426.26 Pretreatment standards for new sources. 426.27 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control tech- nology. Subpart C—IoII.d Glass Manufactw4ng Sub .gory 426.30 Applicabllity description of the rolled glass manufacturing subcategory. 426.31 SpecIalized definitions. 426.32 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.33 Efflucnt limitations guidelines rep- resenting the degree of effluent reduc- tion attaInable by the application of the best avail tble technology economically achlevablt 426.34 Pretrtatment standards for existing sources. 426.35 Standards of performance for new sources. 426.36 Pretreatment standards for new sources. 426.37 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control tech- nology. Subpait D—Pl.t. Glass Manvf.ctu k g 426.40 ApplicabilIty; description of the plate glass manufacturing subcat.egory 426.41 SpecialIzed definitions. 426.42 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur. rently available. 426.43 (Reserved) 426.44 Pretreatment standards for existtn.g sources. 426.45 Standards of performance for new sources. 426.48 Pretreatment standards for new sources. S 4-45 ------- Envlronm.ntal Protctlon Ag.ncy Pas1 426 Sec. 42647 Effluent limitations guidelines rep- resenting the degreee of effluent reduc- tion attainable by the application of the best conventional pollutant control technology (BCT). Subpart E—Float Glass Manufadwing Subcat.gory 426.50 ApplicabilIty: description of the float glass manufacturing subcategory. 426.51 Specia.li.zed definitions. 426.52 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.53 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable. 426.54 (ReservedJ 428.55 Standards of performance for new sources. 426.58 Pretreatment standards for new sources. 426.57 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control technology. Subpart F—Automotlv. Glass T.mp.ring Subcat.gory 426.60 Applicability: description of the automotive glass tempering subcategory. 426 61 SpecialIzed definitions. 426.62 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.63 (Reserved] 428.64 Pretreatment standards for existing sources. 428.65 Standards of performance for new sources. 426.68 Pretreatment standards for new sources. 426.67 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control technology. Subpart G—Automotiv. Glass LamInating Subcatsgary 426.70 Applicability; description of the automotive glass laminating subcatego- ry. 426.11 Specialized definitions. Sec. 426.72 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.73 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available tecPinology economically achievable. 428.74 (Reservcd 426.75 Standards of performance for new sources. 426.76 Pretreatment standards for new sources. 426.77 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control technology. Subpart H—Glass Contaln.r Manufacturing Subcat.gory 426.80 Applicability: description of the glass container manufacturing subcate- gory. 428.81 SpecialIzed definitions. 426.82 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.83—426.84 (Reserved] 426.85 Standards of performance for new sources. 426.88 Pretreatment standards for new sources. 426.87 Effluent limitations guidelines rep- resenting the degree of eifluent reduc- tion attainable by the application of the best conventional poUutant control tech- nology. Subpart I—Mackin. Pracsd and blown Glass Manufacturing Subcat.gory t.s.rv.dI Subpart i—Glass Tubing (Dann. ) Manufacturing Subcat.gory 426.100 Applicability: description of the glass tubing (Danner) manufacturing subcategory. 428.101 Specialized definitions. 426.102 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 426.103—426.104 (Reserved] 426.105 Standards for performance for new sources. 426.106 Pretreatment standards for new sources. 4-46 ------- § 426.10 40 CFR Ch. I (7-1-89 Edition) Sec. 428.107 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control technology. Subpart K—T.i.vlslon Picture Tub. Env.lop. Manufacturing Subcat.gory 426.110 Applicability: description of the television picture tube envelope manu- facturing subcategory. 426.111 SpecialIzed definitions. 426.112 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rentLy available. 426.113 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable. 426.114 (Reserved] 426.115 Standards of performance for new sources. 426.116 Pretreatment standards for new sources. 426.117 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollutant control technology. Subpart L—Incond..c.n$ Lamp Env.Iop. Manufacturing Subca$.g.ry 426.120 Applicability; description of the In- candescent lamp envelope manufactur- ing subcategoi-y. 428.12 1 Specialized definitions. 426.122 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- 2-ently available. 426.123 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable. 426.124 (Reserved] 426.125 Stand -ds of performance for new sources. 428.126 Pretreatment stanciai-d.s for new Sources. 428.127 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best conventional pollu t control technology. Sec. Subpart M—Nond Prssud and hewn GlOSS Manufacturing Subcat.gory 428130 ApplicabilIty; description of the hand pressed and blown glass manufac. turing SUbcategory. 426.131 Specialized definitions. 426.132 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available. 428.133 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable. 426.134 (Reserved) 426.135 Standai-ds of performance for new sources. 426.136 Pretreatment standards for new sources. 426.137 (Reserved] Av ’rltoRrry: Sees. 301. 304 (b) and (C), 306 (b) and (C), 307(c), and 3 16(b) of the Federal Water Pollution Control Act, as amended; 33 U.S.C. 1251, 1311. 1314. 1316 (b) and (C). 1317(b); 86 Stat. 816 et seq.. Pub. L 92-500. 91 Stat. 1587, Pub. L. 95-217. SOuRcZ 39 FR 2585. Jan. 22, 1974. unless otherwise noted. Subpart A—Insulation Fiberglass Subcat.gory § 426.10 ApplicabilIty; description of the insulation fiberglass subcategory. The provisions of this subpart are applicable to discharges resulting from the production of insulation fiberglass in which molten glass Is either directly or indirectly made, continuously fiber- Ized and chemically bonded into a wool-like material. § 426.11 Specialized definitions. For the purpose of this subpart: (a) Except as provided below, the general definitions, abbreviations arid methods of analysis set forth in 40 CFR Part 401 shaii apply to this sub- part. (b) The term “cullet water” shall mean that water which is exclusively and directly applied to molten glass in order to solidify the glass. (C) The term “advanced air emission control devices” shall mean air pollu- tion control equipment, such as elec- trostatic precipitatox-s and high energy 4-47 ------- ii Prot.ction Ag.ncy § 426.62 licly owned treatment works (and which would be a new source subject to sectIon 306 of the Act, If it were to discharge pollutants to the navigable waters), shall be the standard set forth in 40 CFR Part 128. except that. for the purpose of this section. 40 CFR 128.133 shall be amended to read as follows: In addition to the prohibitions set forth in 40 CFR 128.131. the pretreatment standard for incompatible pollutants introduced Into a publicly owned treatment works shall be the standard of performance for new sources specified in 40 CFR 426.55 provIded that, if the publicly owned treatment works which receives the pollutants Is committed. in Its NPDES permit, to remove a specified percentage of any Incompatible pollutant. the pretreatment standard applicable to users of such treatment works shall, except in the case of standards providing for no dis- charge of pollutants, be correspondingly re- duced in stringency for that pollutant. § 426.57 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best conventional pollutant control technology. Except as provided in H 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limita- tions representing the degree of efflu- ent reduction attainable by the appli- cation of the best conventional pollut- ant control technology (BCT): The limitations shall be the same as those specified for conventional pollutants (which are defined in § 401.16) in * 426.52 of this subpart for the best practicable control technology cur- rently available (BPT). (51 FR 25000, July 9. 1986] Subpart F—Automotive Glass Temp.ring Subcategory Sornicx 39 FR 5714. Feb. 14, 1974. unless otherwise noted. § 426.60 Applicability; description of the automotive glass tempering subcatego- ry. The provisions of this subpart are applicable to discharges of pollutants resulting from the processes in which glass is cut and then passed through a series of processes that grind and polish the edges, bend the glass, and then temper the glass to produce side and back windows for automobiles. § 426.61 Specialized definitions. For the purpose of this subpart: (a) Except as provided below, the general definitions, abbreviations and methods of analysis set forth in 40 CFR Part 401 shall apply to this sub- part. (b) The term “tempering” shall mean the process whereby glass is heated near the melting point and then rapidly cooled to increase its me- chanical and thermal endurance. § 426.62 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best practicable control technology currently available. (a) In establishing the limitation set forth in this section, EPA took into ac- count all Information it was able to collect, develop and solicit with re- spect to factors (such as age and size of plant, raw materials, manufacturing processes, products produced, treat- ment technology available, energy re- quirements and costs) which can affect the industry subcategorization and effluent levels established. It Is, however, possible that data which would affect these limitations have not been available and, as a result, these limitations should be adjusted for certain plants in this industry. An individual discharger or other interest- ed person may submit evidence to the Regional Administrator (Or to the State, if the State has the authority to issue NPDES permits) that factors re- lating to the equipment or facilities in- volved, the process applied, or other such factors related to such discharger are fundamentallY different from the factors considered in the establish- ment of the guidelines. On the basis of such evidence or other available infor- mation, the Regional Administrator (or the State) will make a written find- ing that such factors are or are not fundamentally different for tha facil- Ity compared to those specified in the Development Document. If such fun- darnentally different factors are found to exist, the Regional Administrator 4-48 ------- § 426.64 40 CM Ch. I (7-149 EdItion) or the State shall establish for the dis- charger effluent limitations in the NPDES permit either more or less stringent than the limitations estab- lished herein, to the extent dictated by such fundamentally different fac- tors. Such limitations must be ap- proved by the Administrator of the Environmental Protection Agency. The Administrator may approve or disapprove such liniltations, specify other limitations, or Initiate proceed- ings to revise these regulations. (b) The following limitations estab- lish the quantity or quality of pollut- ants or pollutant properties, con- trolled by this section, which may be discharged by a point source subject to the provisions of this subpart after ap- plication of the best practicable con- trol technology currently available: Effluent characteristic Effluent limitations Average of daily Ma,amum values for 30 for any 1 nsicutive days day shall not exceed— 1 5$ Metric m (qIaQ m of product) 195 1.22 Cd.. . 064 64 pH (9 (I) English units (ron.o6o eq ft of 155 product) 040 025 Cd 013 13 p11 (9 (‘) &W(d.In the range 60 to 90 § 426.63 (Reserved] § 426.64 Pretreatment standards for exist- ing sources. The pretreatment standards under section 307th) of the Act for a source within the automotive glass tempering subcategory which is a user of a pub- licly owned treatment works and a major contributing industry as defined in 40 CFR Part 128 (and which would be an existing point source subject to section 301 of the Act, if it were to dis- charge pollutants to the navigable waters), shall be the standard set forth in 40 CFR Part 128. except that, for the purpose of this sectIon. 40 CFR 128.121, 128.122. 128.132. and 128.133 shall not apply. The following pre- treatment standard establishes the quantity or quality of pollutants or pollutant properties controlled by this section whIch may be discharged to a publicly owned treatment works by a point source subject to the provisions of this subpart. Pollutant or pollutant proQerty Pretreatment standarO p 1 1 Cd 1 5 $. . No limitation Do Do (40 FR 8444. Feb. 11. 1975) § 426.65 Standards of performance for new sources. The following standards of perform- ance establish the quantity or quality of pollutants or pollutant properties. controlled by this section, which may be discharged by a new source subject to the provisions of this subpart: Effluent hmitaDons Average of d&y Effluent characteristic Maximum values for 30 for any 1 consecutive days day shall not exceed— 155 Metric unitS (q/sq m of product) 024 024 Cd 049 ‘9 p 1 1 (9 I) English uruts (lb/I 000 sq ft ISS product) 005 005 C d 010 pH (9 9 ‘Within the range 60to90 § 426.66 Pretreatment sources. standards for new The pretreatment standards under section 307(c) of the Act for a source within the aut(motive glass tempering subcategory, which is a user of a pub- licly owned treatment works (and which would be a new source subject to section 306 of the Act, if It were to discharge pollutants to the navigable waters), shall be the standard set forth in 40 CFR Part 128. except that, for the purpose of this section. 40 CFR 4-49 ------- § 426.72 nvli ProtctIon Ag.ncy 128.133 shall be amended to read as follows: In addition to the prohibitions set forth in 40 CFR 128.131. the pretreatment standard for incompatible pollutants introduced into a publicly owned treatment works shall be the standard of performance for new sources specified In 40 CFR, 428.85: provided that, if the publicly owned treatment works which receives the pollutants is committed. in Its N’PDES permit, to remove a specified percentage of any incompatible pollutant. the pretreatment standard applicable to users of such treatment works shall, except in the case of standards providing for no dis- charge of pollutants, be correspondingly re duced In stringency for that poUutant. § 426.67 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best conventional pollutant control technology. Except as provided in H 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent Ilinita- tions representing the degree of efflu- ent reduction attainable by the appli- cation of the best conventional pollut- ant control technology (BCT): The limitations shall be the same as those specified for conventional pollutants (which are defined in § 401.16) In 426.62 of this subpart for the best practicable control technology cur• rently available (BPT). (51 FR 25000, July 9, 1988] Subpart G—Automotlv. Glass Laminating Subcat.gory SouRca: 39 FR 5714, Feb. 14, 1974, unless otherwise noted. 6426.70 Applicability; description of the automotive glass Laminating subcatego- ry. The provisions of this subpart are applicable to discharges of poUutants resulting from the processes which laminate a plastic sheet between two layers of glass, and which prepare the glass for lamination such as cutting, bending and washing, to produce auto- mobile windshields. § 426.71 SpecIalized definitions. For the purpose of this subpart: (a) Except as provided below, the general definitions, abbreviations and methods of analysis set forth in 40 CFR Part 401 shall apply to this sub- part. § 426.72 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best practicable control technology currently available. In establishing the limitations set forth In this section, EPA took into ac- count all information it was able to collect, develop and solicit with re- spect to factors (such as age and size of plant, raw materials, manufacturing processes, products produced, treat- ment technology available, energy re- quirements and costs) which can affect the industry subcategorlzation and effluent levels established. It Is, however, possible that data which would affect these limitations have not been available and, as a result, these limitations should be adjusted for certain plants in this industry. An Individual discharger or other interest- ed person may submit evIdence to the Regional Administrator (or to the State, if the State has the authority to Issue NPDES permits) that factors re- lating to the equipment or facilities in- volved, the process applied, or other such factors related to such discharger are fundamentally different from the factors considered in the establlsh ment of the guidelines. On the basis of such evidence or other available infor- mation, the Regional Administrator (or the State) will make a written find- trig that such factors are r are not fundamentally different for that facil- ity compared to those specified in the Development Document. U such fun- damentally different factors are found to exist, the Regional Administrator or the State shall establish for the dis- charger effluent limitations in the NPDES permit either more or less stringent than the limitations estab- lished herein, to the extent dictated by such fundamentally different fac- tors. Such limitations must be ap- proved by the Administrator of the Environmental Protection Agency. The Administrator may approve or disapprove such limitations, specify 4-50 ------- § 426.73 other limitations, or initiate proceed. IngE to revise these regulations. The following limitations establish the quantity or quality of pollutants or pollutant properties, controlled by this section, which may be discharged by a point source subject to the provisions of this subpart after appllcation of the best practicable control technology currently available: Effluent cI’iaraclensbc Effluent Imitat ions Average of daly Ma omum values for 30 for any 1 conse ye days day shaH riot m- TSS.. .. 01. Phoe horus ... oil . . .rss 0 1 Phosphorus pH Mevic ur ts (q/sq m of —) 440 440 176 176 1 07 1.07 (‘) (‘) EnØish units (bIl.000 sq ft of — 090 090 036 .38 0.22 .22 ( I ) ( I) Within the range 60 to o * 426.73 Emuent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best available technology economi- cally achievable. The following limitations establish the quantity or quality of pollutants or pollutant properties, controlled by this section, which may be discharged by a point source subject to the provi- sions of this subpart after application of the best available technology eco- flomically achievable: Effluent lvwtabons Effli A o y tOt $rP ’ conseojtivo days day “ ‘ts (Q/sq m of 030 40 CFR Ch.. I (7 - -e9 Edition) Effluent Charectenstic Effluent UrTVt* On5 Average of daly Maximum values for 30 t any I oonesaitrvo days day sni Sn o t exceed— Phoephorus Enghsii ixwtl (lb/I .000 sq ft of product) 006 06 (39 FR 5714, Feb. 14, 1974, as amended at 44 FR 50746, Aug. 29. 1979] § 426.74 [ Reserved] § 426.75 Standards of performance for new sources. The following standards of perform- ance establish the quantity or quality of pollutants or pollutant properties, controlled by this section, which may be discharged by a new point source subject to the provisions of this sub- part: Effluent characteristic Effluent tinvtabons Average of daily Ma amunI values for 30 for arty I consecutwe days day shall not exceed— Medic units (q/sq m of TSS.. . . . product) 088 088 Oil 178 178 Phosphorus 030 30 pH (9 (9 English units (lb/I,000 lb of TSS . . —) 018 018 Oil 036 36 Phosphorus 006 06 pH (9 (I) i Within the range 60 to 90 § 426.76 Pretreatment standards for new sources. The pretreatment standards under section 307(c) of the Act for a source within the automotive glass laminat- ing aubcategory, which is a user of a publicly owned treatment works (and which would be a new source subject to section 306 of the Act, If It were to discharge pollutants to the navigable Waters), shall be the standard set forth In 40 CFR p yt 128, except that, 4-51 ------- Environmintal Prot.ctlon Ag.ncy § 426.82 for the purpose of thLs section, 40 CFR 128.133 shall be amended to read as follows: In addition to the prohibitions set forth In 40 CFR 128.131. the pretreatment standard for Incompatible pollutants Introduced into a publicly owned treatment works shall be the standard of performance for new sources specified in 40 CPR 428.75. provided that. if the publicly owned treatment works which receives the pollutants is committed. in Its NPDES permit, to remove a specified percentage of any Incompatible pollutant. the pretreatment standard applicable to users of such treatment works shall, except in the case of standards providing for no dis- charge of pollutants, be correspondingly re- duced in stringency for that pollutant. § 426.77 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best conventional pollutant control technology. Except as provided In H 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limita- tions representing the degree of efflu- ent reduction attainable by the appli- cation of the best conventional pollut- ant control technology (BCT): The limitations shall be the same as those specified for conventional pollutants (which are defined In * 401.16) In § 426.72 of this subpart for the best practicable control technology cur- rently available (BPT). (51 FR 25000. July 9, 1988) Subpart H—Glass Contalnsr Manufaduring Subcategory Sowicz 40 FR 2956, Jan. 16, 1975, unless otherwise noted. 6 426.80 Applicability; description of the glass container manufacturing subcate- gory. The provisions of this subpart are applicable to discharges resulting from the process by which raw materials are melted in a furnace and mechani- cally processed Into glass containers. § 426.81 SpecialIzed definitions. For the purpose of this subpart: (a) Except as provided below, the general definitions, abbreviations and methods of analysis set forth In Part 401 of this chapter shall apply to this subpart. (b) The term “furnace pull” shall mean that amount of glass drawn from the glass furnace or furnaces. (C) The term “oil” shall mean those components of a waste water amena- ble to measurement by the technique or techniques described in the most recent addition of ‘Standard Meth- ods” for the analysis of grease in pol- luted waters, waste waters, arid ef- fluents, such as “Standard Methods.” 13th Edition, 2nd PrintIng, page 407. § 426.82 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best practicable control technology currently available. In establishing the limitations set forth in this section, EPA took into ac- count all information it was able to collect, develop and solicit with re- spect to factors (such as age and size of plant, raw materials, manufacturing processes, products produced, treat- ment technology available, energy re- quirements and costs) which can affect the industry subcategorizatton and effluent levels established. It is, however, possible that data which would affect these limitations have not been available and, as a result, these limitations should be adjusted for certain plants in this industry. An individual discharger or other interest- ed person may subrmt evidence to the Regional Administrator (or to the State, If the State has the authority to issue NPDES permits) that factors re- lating to the equipment or facilities in- volved, the process applied, or other such factors related to such discharger are fundamentally different from the factors considered in the establish- ment of the guidelines. On the basis of such evidence or other available in.for- mation, the Regional Administrator (or the State) will make a written find- ing that such factors are or are not fundamentally different for that facil- ity compared to those specified in the Development Document. If such fun- damentally different factors are fou.nd to exist, the Regional AdmirnstratOr or the State shall establish for the dis- charger effluent limitations in the 4 -52 ------- OVERVIEW OF VARIANCES TO EFFLUENT GUIDELINES ------- VARIANCE LEARNING OBJECTIVES • Role of variances • Types of variancesResponsibilities of permittee • Basic process to grant/deny TECHNOLOGY-BASED VARIANCES • Limited relief from effluent limits and compliance deadlines • Address exceptional circumstances • Ensure fairness of NPDES program • Only granted on rare occasions • Some may be granted by States, others require EPA approval NOTES: 5—1 ------- VARIANCES ARE FOR EXCEPTIONAL CIRCUMSTANCES APPROVAL CWA CITE TYPE 40 CFR CITE AUTHORITY 301 (c) Economic Part 125, Subpart E EPA - HQ [ Reserved] 301 (g) Water Quality Part 125, Subpart F EPA - Region [ Reserved] 301(h) Secondary Treatment Part 125, Subpart G EPA - HQ Waiver- Ocean Discharge ( 125.56. 125.67) (POTW) 301(i) Extension of Secondary Part 125, Subpart J NPDES State* Treatment Deadline ( 125.90 -125.97) (POTW) 301(k) Innovative Part 125, Subpart C NPDES State* Technology ( 125.20 - 125.27) 301(n) Fundamentally Different Part 125, Subpart D EPA - Regions Factors (FDFs) ( 125.30 - 125.32) 316(a) Thermal Discharges Part 125, Subpart H NPDES State* ( 125.70 - 125.73) -- Intake - Discharge §122.45(g) NPDES State* Net Basis (Net/Gross) *EPA Region in absence of approved State NPDES program. NOTES: 5-2 ------- BEST PROFESSIONAL JUDGMENT-BASED LIMITS ------- - - Compare Limitations Apply the Most Stringent LEARNING OBJECTIVES • Define Best Professional Judgment (BPJ) • Authority for BPJ • BPJ tools • Economic achievability protocol DEVELOPMENT OF EFFLUENT LIMITATIONS FOR NPDES PERMITS Develop Technology-Based Develop Water Quality-Based Limitations Limitations • Effluent Guidelines • Best Professional Judgment 6-1 ------- BPJ CANDIDATES • Combined sewer overflows • Hazardous waste treaters • Equipment manufacturers • Waste oil reclaimers • Industrial laundries • Paint and ink facilities • Pharmaceuticals • Barrel reclaimers • Transportation facilities • Mining operations • Water treatment plants • Petroleum industry NOTES: 6-2 ------- BPJ IS THE PERMIT WRITER’S OPINION • Technically based NPDES permit conditions, developed using all reasonable available and relevant data, examined and evaluated using a multidisciplined approach. • The multidisciplined approach includes perspectives of an engineer, economist, statistician, chemist, biologist, and attorney. BPJ FACTORS - DEFINITIONS • Age of equipment and facilities : age of the plant including manufacturing lines, sewer lines, and wastewater treatment system • Process employed ; the manufacturing process(es) used, andlor the wastewater treatment process employed • Engineering aspects of the application of various types of control techniques : the design, construction, cost, performance, reliability, etc. of the wastewater treatment processes • Process changes : the feasible manufacturing process changes such as raw material substitution or in-process design (i.e., chemical synthesis) • Cost of achievin2 the effluent reduction : the capital and operating cost of attaining a specified effluent quality • Non-water quality environmental impacts : the trade-offs associated with achieving a specified effluent quality including energy requirement, air pollution, hazardous waste generation, solid waste disposal, etc. • Other factors the Administrator deems appropriate : any other factor determined to be relevant to the facility’s ability to achieve a specified level of effluent quality 6-3 ------- BEST PROFESSIONAL JUDGMENT DEFENSIBILITY • Defensibility depends on reasonableness • Reasonableness demonstrated by documentation • Documentation should include: - What is being imposed? - Why is it being imposed? - How it was developed? NOTES: 6-4 ------- BPJ PERMITTING TOOLS • Abstracts of industrial NPDES permits • Treatability manual • NPDES best management practices guidance document • Technical support document for the development of water quality-based permit limitations for toxic pollutants • Economic achievability protocol • Report on specific facilities • Office of Research and Development - National Enforcement Investigations Center • Effluent guidelines data - Section 308 questionnaires - Screening and verification data - Development documents - Contractors reports - Proposed regulations • Other sources of information • Discharge monitoring reports - Compliance inspection reports - Industry teams/national experts NOTES: 6-5 ------- PERMIT ABSTRACTS Primary purpose: - To assist permit writers by providing rapid access to information in approximately 500 industrial NPDES permits in a standardized, cross-referenced and easy-to-read format. • Other purposes: - To answer inquiries from, and provide information to industry, academia, consultants and the public. NOTES: 6-6 ------- NUMBER OF ABSTRACTED PERMITS EFFLUENT GUIDELINES Ms fl None DssIqnot.d Psb’o1sur R.fb k’ q and Pop Board Plastic . & S vth.t1cs Textile wm. an and Industry Category 6-7 ‘I E I. . V a. 0 V E z 100 ’ 80’ 60 ’ 40 20 0 Region 60 50 40 5 I 20 10 0 ------- PERMITS WITH BMP PLANS 25 20 a, E Ii L. I, a. 15 _• _ __ 0 k __ ____ I I I UI IV V I IX X Region 6-8 ------- ECONOMIC ACHIEVABILITY PROTOCOL Definition - “Economically achievable” for the purpose of this protocol means that the cost of the pollution control device will not cause the plant to shut down • Purpose - To determine if a particular pollution control device is economically achievable • Scope - Applicable to “best professional judgments” about BAT - Typically requires use of “economic specialist” NOTES: 6-9 ------- 6-10 ------- PRACTICAL EXERCISE Best Professional Judgement (BPJ) GIVEN : (a) NPDES Application Forms 1 and 2C from Luster Glass, Inc. (b) 40 CFR Part 426 — Glass Manufacturing Point Source Category (C) 40 CFR Part 423 — Steam Electric Power Generating Point Source Category (d) Selected NPDES permit abstracts REQUIREMENT : Set a technology-based limit for zinc which is present in the cooling tower blowdown using your BPJ. QUESTIONS : (1) Does 40 CFR Part 426 — Glass Manufacturing Point Source Category regulations set an effluent limitation for zinc? ______________________ (2) Looking for reference limits for zinc in cooling tower blowdown, does 40 CFR Part 423 - Steam Electric Power Generating Point Source Category effluent guidelines, contain effluent limitations for zinc? _________ If 80, what are they? (3) Looking for reference limits for zinc in cooling tower blowdown, do other NPDES permits contain effluent limitations for zinc? (HINT: Use the Keyword Index in the EPA NPDES Industrial Permit Abstracts; only refer to facilities in Illinois (i.e., permit numbers beginning with IL) discharging cooling water blowdown)____________________________________ If so, which permit(s) and what limit(s) are used? __________________ (4) What other resources could be considered in setting a BPJ effluent limitation? (5) Using the information you have been given, what effluent limitation could be used as a basis for setting a limitation for zinc using BPJ?_________ (6) Should you establish concentration or mass limits for zinc at Outfall 001? Why? (7) At what alternative location(s) could zinc limits be applied in the permit? 6-11 ------- 6—12 ------- Environmental Protection Agency § 423.10 (Metnc units (Kg/kkg 01 product). English units (lb/I 000 lb of product)) Effluent chatactenstic Effluent limitations Maximum for any 1 day Average of daily values for 30 consecutive days shall not exceed— Total phos horus(asP) Ftuondo(asF) . 056 21 028 11 (44 FR 50744, Aug. 29. 1979] 8422.64 [ Reserved] § 422.65 Standards of performance for new sources. The following limitations establish the quantity or quality of pollutants or pollutant properties, controlled by this section, which may be discharged by a point source subject to the prom sloris of this subpart after application of the standards of performance for new sources: [ Me8 c units (kgIkkg of product). English units (tb/1.000 lb of product)] Effluent charactensbc Effluent limitations Maiamunt for any 1 day Average of daily values for 30 consecutive days shaJi not exceed— ISS . To taiphospflorus(asP) . Fluonde(asF) pH.. 0.35 56 21 (I) 018 28 11 (I) * Wittsn ti’e range 8.0 to 9.5 § 422.66 [ Reserved] § 422.67 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best conventional pollutant control technology. Except as provided In H 125.30 through 125.32, the following lim.ita- tions establish the quantity or quality of pollutants or pollutant properties. controlled by this section, which may be discharged by a point source sub- ject to the provisions of this subpart after application of the best conven- tional pollutant control technology: (Metric units (kglkkg of product). English unitS (lb/i 000 lb of product)] Effluent cfwactonsbc Effluent limitations Average of daily values Maximum for for 30 any I day conseculnie days sitail riot exceed— TSS pH 035) 018 ( I) ( I) I Within trio range 60 to 9 5 (51 FR 25000, July 9. 1986] PART 423—STEAM ELECTRIC POWER GENERATING POINT SOURCE CAT- EGORY Sec. 423.10 ApplicabilIty. 423.11 Specialized definitions. 423.12 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best practicable control technology cur- rently available (BFr). 423.13 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the application of the best available technology economically achievable (BAT). 423.14 Effluent limitations guidelines rep- resenting the degree of effluent reduc- tion attainable by the appl catlon of the best conventional pollutant control technology (BCT). (Reserved] 423.15 New source performance standards (NSPS). 423.16 Pretreatment standards for existing sources (PSES). 423.17 Pretreatment standards for new sources (PSNS). Aimnnx A—126 Pnxoarn’ Pou.umirrs AumoRirr Sees. 301; 304(b). (C), (e). and (g); 306(b) and (c); 307(b) and (C): and 501. Clean Water Act (Federal Water Poliution Control Act Amendments of 1972, as amend- ed by Clean Water Act of 1977) (the ‘Act”; 33 U.S.C. 1311; 1314(b). (C), (e). and (g): 1316(b) and (C); 1317(b) and (C); and 1361. 86 Stat. 816, Pub. L. 92-500; 91 Stat. 1567, Pub. L. 95-217). SovRct 47 FR 52304. Nov. 19, 1982, unless otherwise noted. § 423.10 Applicability. The provisions of this part are appli- cable to discharges resulting from the operation of a generating unit by an 40-149 O—90——24 6-13 ------- § 423.11 40 CFR C l i. I (7-1-90 Edition) establishment primarily engaged In the generation of electricity for distri- bution and sale which results primari- ly from a process utilizing fossil-type fuel (coal, oil, or gas) or nuclear fuel in conjunction with a thermal cycle em- ploying the steam water system as the thermodynamic medium. § 423.11 Specialized definitions. In addition to the definitions set forth In 40 CFR Part 401. the follow- ing definitions apply to this part: (a) The term “total residual chlo- rine” (or total residual oxidants for intake water with bromides) means the value obtained using the ampero- metric method for total residual chlo- rine described In 40 CFR Part 138. (b) The term “low volume waste sources” means, taken collectively as if from one source, wastewater from all sources except those for which specific limitations are otherwise established in this part. Low volume wastes sources Include, but are not limited to: wastewaters from wet scrubber air pol- lution control systems, ion exchange water treatment system, water treat- ment evaporator blowdown, laboratory and sampling streams, boiler blow- down, floor drains, cooling tower basin cleaning wastes, and recirculating house service water systems. Sanitary and air conditioning wastes are not In- cluded. (C) The term “chemical metal clean. Ing waste” means any wastewater re- sulting from the cleaning of any metal process equipment with chemical com- pounds, Including, but not limited to, boiler tube cleaning. Cd) The term “metal cleaning waste” means any wastewater resulting from cleaning (with or without chemical cleaning compounds] any metal proc- ess equipment Including, but not limit- ed to, boiler tube cleaning, boiler fire- side cleaning, and air preheater clean- ing. (e) The term “fly ash” means the ash that Is carried out of the furnace by the gas stream and collected by me- chanical precipitators, electrostatic precipitators, and/or fabric filters. Economizer ash Is included when it Is collected with fly ash. (f) The term “bottom ash” means the ash that drops out of the furnace gas stream In the furnace and In the economizer sections. EconomIzer ash is Included when It Is collected with bottom ash. (g) The term “once through cooling water” means water passed through the mR.Iri cooling condensers in one or two passes for the purpose of remov- ing waste heat. (h) The term “recirculated cooling water” means water which is passed through the main condensers for the purpose of removing waste heat, passed through a cooling device for the purpose of removing such heat from the water and then passed again, except for blowdown, through the msI condenser. (I) The term “10 year, 24/hour rain- fall event” means a rainfall event with a probable recurrence interval of once In ten years as defined by the National Weather Service In Technical Paper No. 40. “RaInfall Frequency Atlas of the United States,” May 1961 or equiv- alent regional rainfall probability In- formation developed therefrom. (j) The term “blowdown” means the minimum discharge of recirculating water for the purpose of discharging materials contained in the water, the further buildup of which would cause concentration In amounts exceeding limits established by best engineering practices. (k) The term “average concentra- tion” as it relates to chlorine discharge means the average of analyses made over a single period of chlorine release which does not exceed two hours. (1) The term “free available chlo- rine” shall mean the value obtained using the amperometric titration method for free available chlorine de- scribed In “Standard Methods for the Ex .niination of Water and Wastewater,” page 112 (13th edItion)- (m) The term “coal pile runoff” means the rainfall runoff from or through any coal storage pile. § 423.12 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best practicable control technology currently available (BPT). (a) In establishing the 1lxnltatiOI set forth in this section, EPA took Int o 6-14 ------- ii Protection Agency § 423.12 account all Information it was able to collect, develop and solicit with re- spect to factors (such as age and size of plant, utilization of facilities, raw materials, manufacturing processes, non-water quality environmental im- pacts, control and treatment technolo- gy available, energy requirements and costs) which can affect the industry subcategorization and effluent levels established. It Is, however, possible that data which would affect these limitations have not been available and, as a result, these limitations should be adjusted for certain plants In this Industry. An Individual dis- charger or other Interested person may submit evidence to the Regional Administrator (or to the State, if the State has the authority to Issue NPDES permits) that factors relating to the equipment or facilities Involved, the process applied, or other such fac- tors related to such discharger are fundamentally different from the fac- tors considered in the establishment of the guidelines. On the basis of such evidence or other available in.forma- tion, the Regional Administrator (or the State) will make a written finding that such factors are or are not funda- mentally different for that facility compared to those specified In the De- velopment Document. If such funda- mentally different factors are found to exist, the Regional Administrator or the State shall establish for the dis- charger effluent limitations in the NPDES Permit either more or less stringent than the limitations estab- lished herein, to the extent dictated by such fundamentally different fac- tors. Such limitations must be ap- proved by the Administrator of the Environmental Protection Agency. The Administrator may approve or disapprove such limitations, specify other limitations, or initiate proceed- ings to revise these regulations. The phrase “other such factors” appearing above may include significant cost dif- ferentials. In no event may a discharg- er’s Impact on receiving water quality be considered as a factor under this paragraph. (b) Any existing point source subject to this subpart must achieve the fol- lowing effluent limitations represent- ing the degree of effluent reduction by the application of the best practicable control technology currently available (1) The pH of all discharges, except once through cooling water, shall be within the range of 6.0-9.0. (2) There shall be no discharge of polychlorlnated biphenyl compoun such as those commonly used for transformer fluid. (3) The quantity of pollutants dis- charged from low volume wa.ste sources shall not exceed the quantity determined by multiplying the flow of low volume waste sources times the concentration Used in the following table: Pollutant or pollutant property 9p effluent hm4abona M&cmum for any I day (mg/I) Average of vabee for 30 COnSeCUbvO da i theft not exceed (mg/I) TSS Oil and greaae 1000 200 300 150 (4) The quantity of pollutants dis- charged in fly ash and bottom ash transport water shall not exceed the quantity determined by multiplying the flow of fly ash and bottom ash transport water times the concentra- tion listed in the following table: Pollutant or pollutant property BPT effluent bmnabons Max3rnum for any I day (mg/I) Average of daly values tor 30 cor eCuVve days shall not exceed (mg/I) rss . .. . 1000 200 300 150 (5) The quantity of pollutants d.is- charged In metal cleaning wastes shall not exceed the quantity determined by multiplying the flow of metal cleaning 6-15 ------- §423.12 40 CFR Ch. I (7.1-90 EditIon) wastes times the concentration listed In the following table: Pollutant or pollutant property BPT effluent limitations Maximum for any I day (mg/I) Average of daily vabee for 30 consecutive days shail not exceed (mg/I) TSS .... .... Oil and grease Copger.totai Iron,tcta l 100.0 20.0 10 10 30.0 150 10 1.0 (6) The quantity of pollutants dis- charged In once through cooling water shall not exceed the quantity deter- mined by multiplying the flow of once through cooling water sources times the concentation listed in the follow- Ing table: Pollutant or pollutant property BP effluent limitations Maximum conce hon (mg/I) Average concen hon (mg/I) Free available chlorine 0.5 0.2 (7) The quantity charged in cooling tower blowdown shall not exceed the quantity deter- mined by multiplying the flow of cool- ing tower blowdown sources times the concentration listed in the following table: Pollutant or pollutant property 9p effluent limitations Maximum Average cor’ ntia. concenua- ban (mg/I) hon (mg/f) Free available chlorine - 05 0.2 (8) Neither free available chlorine nor total residual chlorine may be dis- charged from any unit for more than two hours In any one day and not more than one unit in any plant may discharge free available or total resid- of pollutants dis- ual chlorine at any one time unless the utility can demonstrate to the Re- gional Administrator or State, If the State has NPDES permit issuing au- thority, that the unIts In a particular location cannot operate at or below this level or chlorination. (9) Subject to the provisions of para- graph (b)(10) of this section, the fol- lowing effluent limitations shall apply to the point source discharges of coal pile runoff: Pollutant or pollutant progeny BPT effluent limitations MB OI1UI coUabOfl for any time (mg/I) TSS. ..-...-. so (10) Any untreated overflow from fa- cilities designed, constructed, and op- erated to treat the volume of coal pile runoff which Is associated with a 10 year, 24 hour rainfall event shall not be subject to the limitations In para- graph (b)(9) of this section. (11) At the permitting authority’s discretion, the quantity of pollutant allowed to be discharged may be ex- pressed as a concentration limitation instead of the mass based limitations specified in paragraphs (b)(3) through (7) of this section. Concentration limi- tations shall be those concentrations specified In this section. (12) In the event that waste streams from various sources are combined for treatment or discharge, the quantity of each pollutant or pollutant proper- ty controlled in paragraphs (b)(1) through (11) of this section attributa- ble to each controlled waste source shall not exceed the specified limita- tions for that waste source. (The Information coUection requirements contained In paragraph (a) were approved by the Office of Management and Budget under control number 2000-0194) (47 FR 52304. Nov. 19. 1982. as amended at 48 FR 31404. July 8, 1983] 6-16 ------- Environmental Protection Agency § 423.13 § 423.13 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best available technology economi- cally achievable (BAT). Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this part must achieve the following effluent limita- tions representing the degree of efflu- ent reduction attainable by the appli- cation of the best available technology economically achievable (BAT). (a) There shall be no discharge of polychlorlnated biphenyl compounds such as those commonly used for transformer fluid. (b)(1) For any plant with a total rated electric generating capacity of 25 or more megawatts, the quantity of pollutants discharged In once through cooling water from each discharge point shall not exceed the quantity de- termined by multiplying the flow of once through cooling water from each discharge point times the concentra- tion listed in the following table: Poo )utant or poUtstaffl p 0pefty BAT Effluent LnTutations (mg/I) Total residual chtonne 020 (2) Total residual chlorine may not be discharged from any single generat- ing unit for more than two hours per day unless the discharger demon- strates to the permitting authority that discharge for more than two hours Is required for macroinverte- brate control. Simultaneous multi-unit chlorination Is permitted. (c)(1) For any plant with a total rated generating capacity of less than 25 megawatts, the quantity of pollut- ants discharged in once through cool- ing water shall not exceed the quanti- ty determined by multiplying the flow of once through cooling water sources tImes the concentration lIsted in the following table: BAT e Jsnt wtabona Poilutant or pollutant progeny Ma amuii Average concon concon Uon (mg/I) oon (mg/fl Free available chionne 05 02 (2) Neither free available chlorine nor total residual chlorine may be dis. charged from any unit for more than two hours In any one day and not more than one unit in any plant may discharge free available or total resid- ual chlorine at any one time unless the utility can demonstrate to the Re- gional Administrator or State. if the State has NPDES permit issuing au- thority, that the units in a particular location cannot operate at or below this level of chlorination. (d)(1) The quantity of pollutants dis- charged in cooling tower blowdown shall not exceed the quantity deter- mined by multiplying the flow of cool- ing tower blowdown times the concen- tration listed below: BAT effluent hmrtabora Pollutant or pollutant progeny Maximum Average concon a• concenSi- on (mg/I) ben (mg/I) Free available chlonne 05 02 Pollutant c i - pollutant progeny Maximum any I / ; g I Average ol days aftal flQf exceed =(mgI I) The 126 pnonty polkstanb (Ag. pendix A) contained CtIerT)- cats added for coot.ng W m a intenance O ronwm. total Zlnc.t otaI (I) 02 10 (I) 02 tO ‘No detectable jngiait (2) Neither free available chlorine nor total residual chlorine may be dis- charged from any unit for more than two hours in any one day and not more than one unit In any plant may discharge free available or total resid- 6-17 ------- § 423.14 ual chlorine at any one time unless the utility can demonstrate to the Re- gional AdniInb trator or State, if the State has NPDES permit issuing au- thority, that the units In a particular location cannot operate at or below this level of chlorination. (3) At the permitting authority’s dis- cretion, Instead of the monitoring specified In 40 CFR 122.11(b) cornpll- ance with the limitations for the 126 priority pollutants In paragraph (d)(1) of this section may be determined by engineering calculations which demon- strate that the regulated pollutants are not detectable In the final dis- charge by the analytical methods in 40 CFR Part 136. (e) The quantity of pollutants dis- charged in chemical metal cleaning wastes shall not exceed the quantity determined by multiplying the flow of chemical metal cleaning wastes times the concentration listed In the follow- ing table: Pollutant or pollutant property BAT effluent hmitaDons Malamunl for amy 1 day (mg/I) Averege of d y values for 30 COnsecutive days shall not exceed -(mg/I) Cooper. total .. Iron.to t aj 10 10 10 10 (f) [ Reserved—Nonchemjcaj Metal Cleaning Wastes]. (g) At the permitting authority’s dis- cretion, the quantity of pollutant al- lowed to be discharged may be ex- pressed as a concentration limitation Instead of the mass based limitations specified In paragraphs (b) through (e) of this section. Concentration limita- tions shall be those concentrations specified In this section. (h) In the event that waste streams from various sources are combined for treatment or discharge, the quantity of each poUutant or pollutant proper- ty controlled In paragraphs (a) through (g) of this section attributa- ble to each controlled waste source 40 CM Ch. I (7-1-90 Edition) shall not exceed the specified limita- tion for that waste source. (The information coUection requ1rement contained in paragraphs (c)(2) and (d)(2) were approved by the Office of Manage- ment and Budget under control number 2040-0040. The Information collection re- quirements contained in paragraph (d)(3 were approved under control number 2040- 0033.) (47 FR 52304. Nov. 19. 1982. as amended at 48 FR 31404. July 8. 1983) § 423.14 Effluent limitations guidelines representing the degree of effluent re- duction attainable by the application of the best conventional pollutant control technology (BCT). (Reserved] 8 423.15 New source performance stand- ards (NSPS). Any new source subject to this sub- part must achieve the following new source performance standards: (a) The pH of all discharges, except once through cooling water, shall be within the range of 6.0-9.0. (b) There shall be no discharge of polychiorinated biphenyl compounds such as those commonly used for transformer fluid. (C) The quantity of pollutant.s dis- charged from low volume waste sources shall not exceed the quantity determined by multiplying the flow of low volume waste sources tImes the concentration listed in the following table: Average o da va eS Pollutant or pollutant property Maxnm un for any 1 for 30 consecu day (mg/I) days shal l not exceed (mg/I) TSS - .... .. . ..... ... 1000 200 300 150 (d) The quantity of pollutants dls• charged In chemical metal cleaning wastes shaU not exceed the quantity determined by multiplying the flow of chemical metal cleaning wastes times 6-18 ------- Envlronm.ntal Prot.ctlon Ag.ncy the concenxration listed in the follow- ing table: Pollutant or pollutant property NSPS effluent kmfta1 ons Ma,atnum for any 1 day (mg/I) Average of daily values for 30 coneecutrve days ahd not exceed (mg/I) TSS... . .. OMand ea_io Co ppw.totai... . . . ... .. 1000 20.0 1.0 10 300 150 10 I C (e) (Reserved—Nonchem.lcal Metal Cleaning Wastes]. (f) The quantity of pollutants dis- charged in bottom ash transport water shall not exceed the quantity deter- mined by multiplying the flow of the bottom ash transport water times the concentration listed In the following table: Pollutant or pollutant property NSPS effluent ita oee Ma,amwn for any 1 day (mg/I) Average of daily velues for 30 coneecueve days shall not exceed (mg/I) TSS..... .. . . OUand eas.... 1000 200 300 150 (g) There shall be no discharge of wastewater pollutants from fly ash transport water. (h)(1) For any plant with a total rated electric generating capacity of 25 or more megawatts, the quantity of pollutants discharged in once through cooling water from each discharge point shall not exceed the quantity de- termined by multiplying the flow of once through cooling water from each discharge point times the concentra- tion listed in the following table: § 423.15 Pol jtari1 or pollutant properly NSPS ne —_.. (mg/ f ) Total reai iaJ chlonne . .. 020 (2) Total residual chlorine may not be discharged from any single generat- ing unit for more than two hours per day unless the discharger demon- strates to the permitting authority that discharge for more than two hours Is required for macroinverte- brate control. Simultaneous multi-unit chlorination is permitted. (1)(1) For any plant with a total rated generating capacity of less than 25 megawatts, the quantity of pollut- ants discharged in once through cool- ing water shall not exceed the quanti- ty determined by multiplying the flow of once through cooling water sources times the concentration listed In the following table: Pollutant of pollutant property NSPS eM vtasone Maionir flu ben (mg/f) Average ben (mg/f) Frosa lethlorUbe... . ... .. 05 02 (2) Neither free available chlorine nor total residual chlorine may be dis- charged from any unit for more than two hours in any one day and not more than one unit in any plant may discharge free available or total resid- ual chlorine at any one time unless the utility can demonstrate to the Re- gional Administrator or State, if the State has NPDES permit issuing au- thority, that the units In a particular location cannot operate at or below this level of chlorination. (J)(l) The quantity of pollutants dis- charged In cooling tower blowdown shall not exceed the quantity deter- mined by multiplying the flow of cool- ing tower blowdown times the concen- tration listed below: 6-19 ------- §423.16 Pollutant or pollutant 100541y NSPS effluent linetabons Ma nwn concen a- bon (mg/I) Average conceflea- son (mg/I) Free available chlorine . 0.5 02 PolMarti or pollutant property Maximum for arty 1 day (mg/I) Average of deify v uos for 30 conaeaJbve days ehafl not exced -(mg/fl The 126 prIority pollutanta (Ap- peridot A) contained in cherru- cals added Icr cooling tower meinlenance. except chromium, totai Zinc.totai.._ (l ) 0.2 10 ( ) 0.2 10 t No detectable 6mOuflt (2) Neither free available chlorine nor total residual chlorine may be dis- charged from any unit for more than two hours in any one day and not more than one unit In any plant may discharge free available or total resid- ual chlorine at any one time unless the utility can demonstrate to the Re- gional Administrator or State, If the State has NPDES permit Issuing au- thority, that the units in a particular location cannot operate at or below this level of chlorination. (3) At the permitting authority’s dis- cretion, Instead of the monitoring In 40 CFR 122.11(b), compliance with the limitations for the 126 priority pollut- ants in paragraph (j)(1) of this section may be determined by engineering cal- culation.s which demonstrate that the regulated pollutants are not detectable In the final discharge by the analytical methods in 40 CFR Part 136. (k) Subject to the provisions of § 423.15(1), the quantity or quality of pollutants or pollutant parameters dis- charged in coal pile runoff shall not exceed the limitations specified below: 40 CFR Ch. I (7-1-90 Edition) (1) Any untreated overflow from fa. duties designed. constructed, and op- erated to treat the coal pile runoff which results from a 10 year. 24 hour rainfall event shall not be subject to the limitations in § 423.15(k). (m) At the permitting authority’s discretion, the quantity of poUutant allowed to be discharged may be ex- pressed as a concentration limitation instead of the mass based limitation specified in paragraphs (c) through (j) of this section. Concentration limits shall be based on the concentrations specified in this section. (n) In the event that waste streams from various sources are combined for treatment or discharge, the quantity of each pollutant or pollutant proper- ty controlled In paragraphs (a) through (m) of this section attributa- ble to each controlled waste source shall not exceed the specified limita- tion for that waste source. (The Information collection requirements contained In paragraphs (h)(2). (I)(2). and (j)(2) were approved by the Office of Man- agement and Budget under control number 2040—0040. The information collection re- quirements contained In paragraph ( )(3) were approved under control number 2040- 0033.) (47 FR 52304. Nov. 19. 1982. as amended at 48 FR 31404. July 8, 1983) § 423.16 Pretreatment standards for exist- ing sources (PSES). Except as provided in 40 CFR 403.7 and 403.13. any existing source subject to this subpart which introduces pol- lutants into a publicly owned treat- ment works must comply with 40 CFR Part 403 and achieve the following pretreatment standards for existing sources (PSES) by July 1, 1984: (a) There shall be no discharge of polychlortnated biphenol compounds such as those used for transformer fluid. (b) The pollutants discharged in chemical metal cleaning wastes shall not exceed the concentration listed In the following table: 6-20 ------- Environm.ntal Prot.ctiori Agency Part 423, App. A Pollutant or pollutant property PSES pratment standards Maximum f r I day (mg/I) Copper, total 10 (C) (Reserved—Nonchemical Metal Cleaning Wastes]. (d)(1) The pollutants discharged in cooling tower blowdown shall not exceed the concentration listed in the following table: Pollutant cc pollutant property PSES pretreatment standards Ma3antum for any time (mg/I) The 126 pnonty pollutants (Ap- pendix A) contained in chemi- cals added for cooling tower maintenance, except Chromium, total Zlnc,totai (‘) 02 10 ‘No detectable amount (2) At the permitting authority’s dis- cretion. instead of the monitoring in 40 CFR 122.11(b). compliance with the limitations for the 126 priority pollut- ants in paragraph (d)(1) of this section may be determined by engineering cal- culations which demonstrate that the regulated pollutants are not detectable in the final discharge by the analytical methods in 40 CFR Part 136. § 423.17 Pretreatment standards for new sources (PSNS). Except as provided in 40 CFR 403.7, any new source subject to this subpart part which introduces pollutants into a publicly owned treatment works must comply with 40 CFR Part 403 and the following pretreatment stand- ards for new sources (PSNS). (a) There shall be no discharge of polychlorlnated biphenyl compounds such as those used for transformer fluid. (b) The pollutants discharged in chemical metal cleaning wastes shall not exceed the concentration listed in the following table: Pollutant or Pollutant property PSNS pretreatment standards (mg/I) Maximum for 1 day Copper lotal t 0 (C) (Reserved—Nonchemical Metal Cleaning Wastes]. (d)(1) The pollutants discharged in cooling tower blowdown shall not exceed the concentration listed in the following table: Pollutant or pollutant property PSNS pretreatment standards Maximum for any time (mg/I) The 126 pnonty pollutants (Ap- pendix A) contained in chemi- cals added for cooling tower maintenance, except Chromium, total Zir ic.total . . 02 10 (2) At the permitting authority’s dis- cretion, instead of the monitoring in 40 CFR 122.11(b), complIance with the limitations for the 126 priority pollut- ants In paragraph (d)(1) of this section may be determined by engineering cal- culations which demonstrate that the regulated pollutants are not detectable in the final discharge by the analytical methods In 40 CFR Part 136. (e) There shall be no discharge of wastewater poilutants from fly ash transport water. Ajp ix A—126 PRIORITY PoLL n i Ts 001 Acenaphthene 002 Acroletn 003 Acrylonltrtle 004 Benzene 005 Benzldine 006 Carbon tetrachioride methane) 007 Chlorobenzene 008 1,2,4-trichlorobenzene 009 Hexachlorobenzerie 010 1,2-dlchioroethane 011 1.1.1-trlchioreothane 012 Hexachloroethane 013 1.1-d.tchloroetha.ne 014 1.1,2-trichloroethane 015 1.1.2.2 -tetrach.loroethane ( JQyØ. 6-21 ------- 40 CFR Ch. I (7-1-90 Edition) Part 423, App. A (BHC-hexachioro- 016 Chioroethane 018 Bls(2-chloroethyl) ether 019 2-chloroethyl vinyl ether (mixed) 020 2.chloronaphthalene 021 2.4. 6.trlchlorophenol 022 Paracb.lorometa cresol 023 Chloroform (trichioromethane) 024 2-cbiorophenol 025 l,2-dlchlorobenzene 026 l,3-dichlorobenzene 027 1,4-dlchlorobenzene 028 3 ,3..dlchlorobenzldlne 029 1.1-dlchioroethylene 030 1,2-trans . .dlchloroethylene 031 24-dlchiorophenol 032 1,2-dlchioropropane 033 1,2 .dlchloropropylene (1,3-dichioropro- pene) 034 2,4-dlmethyiphenol 035 2,4-dlnitrotoluene 036 2,6 .dlnltrotoluene 037 1,2-dlphenythydrazlne 038 Ethylbenzene 039 Fluoranthene 040 4-chlorophenyl phenyl ether 041 4-bromophenyl phenyl ether 042 Bls(2-chlorot3opropyl) ether 043 Bts(2 .chloroethoxy) methane 044 Methylene chloride (dlchloromethane) 045 Methyl chloride (dlchloromethane) 046 Methyl bromide (bromomethane) 047 Bromoform (trlbromomethane) 048 Dlchlorobromomethane 051 Chlorodlbromomethane 052 Hexachiorobutadlene 053 Hexachloromyciopentadlene 054 Isophorone 055 Na.phthalene 056 Nltrobenzene 057 2-nltrophenol 058 4-nitrophenol 059 2,4-dlnitrophenol 060 4,6-dlnltro-o-cresol 061 N.n1trosod1methyl .rn1ne 062 N-nltrosod1pheny1 n’tne 063 N-nltrosodl-n-propylamln 064 Pentachiorophenol 065 Phenol 066 Bls(2 .ethylhexyl) phthalate 067 Butyl benzyl phthalate 068 DI-N-Butyl Phthalate 069 Dl-n-octyl phthalate 010 DIethyl Phthalate 071 Dlmethyl phthalate 072 1,2.benzanthracene (benzoa) a.nthra- cene 013 Benzo(a)pyrene (3,4-benzo-pyrene) 074 3,4-Benzofluoranthene (benzo(b) fluo- ranthene) 015 11,12-benzofluoranthene (benzo(b) flu- oranthene) 076 Chrysene 077 Acen&;hthylene 078 Anthracene 079 1,12-benzoperylene (benzo(ghl) pery- lene) 080 Fluorene 081 Phenanthrene 082 1 .2,5,6-d.lbenzanthracene (dlbenzo(.h) anthracene) 083 I.ndeno (.1.2,3-cd) pyrene (2.3-o-pheyn• ylene pyrene) 084 Pyrene 085 Tetrachloroethylene 086 Toluene 087 Trlchioroethylene 088 VInyl chloride (ch.loroethylene) 089 AIdrin 090 Dleldrln 091 Chiordane (technical mixture and me- tabolites) 092 4.4-DDT 093 4,4-DDE (p,p-DDX) 094 4.4-DDD (p ,p-TDE) 095 Alpha-endosulian 096 Beta-endosulf an 097 Endosulfan sulfate 098 Endrln 099 Endrln aldehyde 100 Heptachior 101 Heptachior epoxide cyclohexane) 102 Alpha-BHC 103 Beta-BHC 104 G*mma.BHC (lindane) 105 Delta-BHC (PCB-polychlorlnated bi- phenyls) 106 PCB—1242 (Arochlor 1242) 107 PCB—1254 (Arochior 1254) 108 PCB—1221 (ArochIor 1221) 109 PCB—1232 (Arochior 1232) 110 PCB—1248 (Arochior 1248) 111 PCB-1260 (Arochior 1260) 112 PCB—1016 (Arochior 1016) 113 Toxaphene 114 Antimony 115 ArsenIc 118 Asbestos 117 BeryllIum 118 Cadmium 119 ChromIum 120 Copper 121 CyanIde, Total 122 Lead 123 Mercury 124 NIckel 125 SelenIum 126 SIlver 127 Thallium 126 Silver 128 ZInc 129 2,3,7,8-tetrachloro-dlbenZO-P-dlOXlfl (TCDD) 6-22 ------- WATER QUALITY STANDARDS AND MODELING ------- LEARNING OBJECTIVES • Water quality standards • Beneficial uses • Water quality criteria • Antidegradation policy WATER QUALITY STANDARDS A water quality standard defines the water quality goals of a water body, or portion thereof, by designating the use or uses to be made of the water and by setting criteria necessary to protect the uses. (40 CFR Part 131) NOTES: 7—1 ------- ESTABLISHMENT OF WATER QUALITY STANDARDS • All “waters of the U.S.” have water quality standards • Water quality standards are adopted for each waterbody in a State - Segments of waterbodies • States are responsible for establishing water quality standards - Revised every 3 years - EPA has oversight BENEFICIAL USES • Common uses - Public water supply - Fish and wildlife propagation - Recreation - Primary - Secondary • Agricultural - Industrial • Navigation • Outstanding national resources water - National and State parks - Wildlife refuge - Ecologically unique water that need additional protection or are of special significance (i.e., swamps, hotsprings, etc.) NOTES: 7-2 ------- EPA WATER QUALITY CRITERIA • Scientifically derived ambient limits that are developed by EPA for various pollutants of concern 1968 Green 1973 Blue 1976 Red 1980 Toxics 1986 Gold • EPA develops 304(a) criteria goldbook STATE WATER QUALITY CRITERIA • Numeric criteria - Concentrations of chemicals • Narrative criteria - “Freefrom...” NOTES: 7—3 ------- ANTIDEGRADATION PLANS • Ensures that once a use is achieved it will be maintained • Each State is required to adopt an antidegradation policy and method of implementation • EPA reviews State antidegradation plans • Antidegradation plans are designed to minimize adverse effects on economic growth and development COMPONENTS OF THE ANTIDEGRADATION POLICY • Level of quality necessary to protect the existing uses of a water segment • Protection of actual water quality where water quality exceeds levels necessary to protect fish and wildlife propagation and recreation on and in the water • Special protection of waters designated as outstanding natural resource waters NOTES: 7-4 ------- BASIC CONCEPT Total Maximum Daily Load (TMDL) = Dilution x Criteria Waste Load Allocation (WLA) = Fraction of TMDL COMPONENTS OF TMDL NOTES: 7-5 ------- GENERAL MASS BALANCE FORMULA QdCd + QsCs = QrCr Qs, Cs Upstream Qd, Cd Discharge Qr, Cr Downstream Qd = Waste discharge flow (mgd or cfs) Cd = Pollutant concentration in waste discharge (mg/I) Qs = Stream flow (mgd or cfs) above discharge point Cs = Background instream pollutant concentration (mg/I) Qr = Stream flow after discharge (mgd or cfs) = Qd + Qs Cr = Instream pollutant concentration (mg/i) after complete mixing To determine pollutant concentration in the stream: Cr = QdCd + OsCs Qr NOTES: 7-6 ------- DILUTION FACTOR • Mass balance QrCr QdCd + QsCs (Receiving Stream) (Discharge) (Upstream) • Solve for Cr: Cr = QdCd + QsCs Qr • IfCs=O,then: Cr = QdCd Qr • Define Dilution Factor (DF) as Qr/Qd • Therefore: Cr = Cd/DF NOTES: 7—7 ------- EXAMPLE ABC, Inc. discharges treated wastewater from a zinc plating process. The only pollutant found in measurable amounts is zinc. What is the downstream receiving water concentration assuming zinc in the total form, complete mixing, and no settling or biological uptake? Cjnc. I I I I Qs = Upstream river flow = 1.2 cfs Qd = Discharge flow = 0.31 cfs Cs = Upstream river conc. = 0.8 mg/i Cd = Discharge concentration= 1.75 mg/i Cr = CdOd + CsOs Qr Cr — ( l.75)(031) + (O.8)(1 21 — (0.31+1.2) Cr= 1.0mg/I NOTES: 7-8 ------- SPECIFIC CONSIDERATIONS IN THE WATER QUALITY MODELING PROCESS • Conservative pollutants - Mitigated by natural stream dilution - Heavy metals • Non-conservative pollutants - Mitigated by natural stream dilution and biodegradation in the receiving stream - BOD 5 , ammonia, bacteria EXAMPLE MODEL INPUTS • Stream flow • Wastewater flow • Upstream concentration • Effluent concentration • Reaction rates • Mixing zones NOTES: 7-9 ------- DETERMINING THE NEED FOR AND DERIVATION OF WATER QUALITY. BASED LIMITS ------- -- Compare Limitations *, Apply the Most Stringent LEARNING OBJECTIVE • Determining when water quality-based limits are needed • Calculating water quality-based permit limits DEVELOPMENT OF EFFLUENT LIMITATIONS FOR NPDES PERMITS Develop Technology-Based Develop Water Quality-Based Limitations Limitations • Effluent Guidelines • Best Professional Judgment NOTES: 6-1 ------- PROTECTING WATER QUALITY STANDARDS • Getting data to make a decision - Permit application - Ask (308 authority) - Previous permit • Deciding to set limits - Follow 40 CFR § 122.44(d) - Options: 1) Set limit 2) Monitor and reopener 3) Monitor • Setting limits NOTES: 8-2 ------- USE OF WATER QUALITY-BASED LIMITS Water quality-based limitations are used when it has been determined that more stringent limits than technology-based effluent guidelines must be applied to a discharge in order to protect “designated use” of the receiving waters. (40 CFR §122.44(d)(1)) WATER QUALITY-BASED LIMITS Limitations must control all pollutants which will cause have the reasonable potential to cause , or contribute to an excursion above any State water quality standard. (40 CFR §122.44(d)(1)(i)) NOTES: 8-3 ------- WATER QUALITY-BASED LIMITS Limits must consider (40 CFR §122.44(d)(ii)): • Effluent variability • Existing controls on point and non point sources • The sensitivity of species to toxicity testing • Where appropriate, the dilution of the effluent WATER QUALITY-BASED LIMITS NUMERIC CRITERIA If it is determined that a discharge causes, has the reasonable potential to cause, or contributes to an in-stream excursion above the allowable ambient concentration of a State numeric criteria within a State water quality standard for: • An individual pollutant, then the permit must contain effluent limits for that pollutant. (40 CFR 122.44(d)(1)(iii)) • Whole effluent toxicity, then the permit must contain effluent limits for whole effluent toxicity. (40 CFR §122.44(d)(1)(iv)) NOTES: 8-4 ------- WATER QUALITY-BASED LIMITS NARRATIVE CRITERIA If it is determined that a discharge causes, has the reasonable potential to cause, or contributes to an in-stream excursion above a narrative criterion, the permit must contain effluent limits for whole effluent toxicity. (40 CFR §122.44(d)(1)(v)) WATER QUALITY-BASED LIMITS NARRATIVE CRITERIA • Where a State has not established a water quality criterion for a specific pollutant - Use numeric water quality criterion derived from proposed State criterion or State policy or regulations, supplemented as appropriate - Use EPA’s water quality criteria published under Section 307(a) of the CWA, supplemented as appropriate - Use an indicator parameter for the pollutant of concern (40 CFR §122.44(d)(1)(vi)) NOTES: 8-5 ------- EXAMPLE ABC, Inc. discharges treated wastewater from a zinc plating process. The only pollutant found in measurable amounts is zinc. What is the maximum allowable concentration in the effluent assuming zinc in the total form, complete mixing, and no settling or biological uptake. 4 ABC, Inc. Qs = Upstream river flow Qd = Discharge flow Cs = Upstream river conc. Cr = Water quality standard =1.2cfs = 0.31 cfs = 0.8 mg/I =1.0mg/I NOTES: Cd= Cr(Od+Os)-CsOs Cd= Cd= Qd ( 10)(0.31 + 1,2) - (0.8)(1.21 0.31 1.75 mg/I I I I I I I 8-6 ------- EPA TECHNICAL SUPPORT DOCUMENT FOR WATER QUALITY-BASED TOXICS CONTROL • Provides the most current procedural recommendations and guidance for identifying, analyzing, and controlling adverse water quality impacts caused by toxic discharges. • Provides support to States and Regions for supplementing their existing procedures. WHAT YOU MUST DO • Protect acute and chronic water quality standards ( and wasteload allocations) NOTES: • Write maximum daily and monthly average permit limits 8-7 ------- 8-8 ------- PRACTICAL EXERCISE DIRECTIONS : Determining the Need for Chemical—Specific Water Quality-Based Effluent Limitations You are a permit writer and have received a permit renewal application from a glass manufacturer, Luster Glass Inc. The previous permit was issued using effluent limits derived from technology—based effluent limitation guidelines and best professional judgement (BPJ). Since that time, the State has revised its water quality standards to ensure aquatic life protection. Therefore, you must determine whether water quality— based limits are needed. GIVEN : Cr = (Cd)(Qd) + (Cs)(Qs) (Qd + Qs) where Cr = the Cd = the Qd the Cs = the Qe = the receiving water concentration, effluent concentration, effluent flow, receiving water background concentration, and appropriate receiving water flow. Pollutant Lead Zinc Effluent Concentration (Cd)* (mg / 1 0.38 0.21 Receiving Water Background Concentration (Cs) (mg/i) 0 0.07 * — Maximum daily concentration as reported in the application Form 2C The State water quality regulations require that water quality standards be achieved under the following critical receiving water flow conditions: Chronic water quality standards: 7 day, 10 year return frequency flow (7QlO) Acute water quality standards: One—third (1/3) of the 7Q10 flow The 1Q10 for the Illinois River is 70.9 cubic feet per second (cfs) Qd = 7.06 cfs (1) Calculate the following receiving water concentrations (Cr) using the equation and data supplied above. (a) Zinc (acute) (b) Zinc (chronic) ________ (c) Lead (acute) (d) Lead (chronic) ________ 8-9 ------- (2) Compare each receiving water concentration calculated in question (1) with the State Water Quality Standard for aquatic life protection given in the table below. Which one is larger? What does this mean? For which pollutant(s) do you need to set a water quality-based limit?___________ STATE WATER QUALITY STANDARDS* Pollutant Acute Protection (up/i) Chronic Protection (uo/ i Lead 82 3.2 Zinc 120 110 * — All State standards are applied as “not to exceed” concentrations. (3) What effect would a stream flow (Qs) of 0 cfs have on the receiving water concentration? What about a stream flow of 500 cfs? __________________ (4) Are there other pollutants that are discharged that should be evaluated for chemical—specific water quality—based effluent limitations? _______ If yes, then list the pollutants and briefly explain why below:_________ 8-10 ------- PRACTICAL EXERCISE DIRECTIONS : Calculating Chemical Specific Water Quality-Based Limits Assuming there l .mitations for calculate the procedure. is a need lead and end—of -pi.pe water Luster using = waste load allocation, applicable water quality standard, effluent flow = 7.06 cfs, appropriate receiving water flow, and receiving water background concentration. Pollutant Lead Zinc Cr = Acute State Water Quality Standard 0.082 mg/i 0.12 mg/i Cs = Upstream Concentration 0 mg/i 0.07 mg/i Cr = Chronic State Water Pollutant Quality Standard ___________________ Qs 70.9 cfs (for chronic protection) Qs 23.6 cfs (for acute protection) (1) Calculate the waste load allocations for lead using the equation and data supplied above. (a) Lead (acute) __________ (b) Lead (chronic) __________ for chemi.cal specific zinc discharges from ef fluent limitations GIVEN : quality-based Glass, Inc., the following The following equation is used to calculate the effluent concentration (which is commonly referred to as the waste load allocation (WLA)J that will ensure protection of the water quality standard. Cd = WLA = Cr (Qd + Qe) — (Cs)(Qs) where Qd Cd WLA Cr = the Qd = the Qs = the Ce = the Lead Zinc 0.0032 mg/i 0.1]. mg/i Cs = Upstream Concentration 0 mg/i 0.07 mg/i 8-li ------- (2) Calculate the waste load allocations for zinc usl.ng the equation and data supplied above. (a) Zinc (acute) __________ (b) Zinc (chronic) __________ (3) Given that all State water quality standards are expressed as never to be exceeded (i.e., water quality—based limits must be protective of the most stringent waste load allocation), calculate a maximum daily limitation (MDL) and an average monthly limitation (AML) for lead and zinc using the waste load allocations calculated above. (Notes Assume a ratio of daily maximum to monthly average of 1.6 for lead and 1.0 for zinc based upon effluent guideline for BAT.] (4) Compare the chemical specific water quality—based limits calculated above with the technology—based effluent limLtations gi.ven below for Outfall 001. In which case(s) is (are) the water qual .ty based limit(s) less stringent? Technology-Based Effluent Limitations Pollutant Maximum Daily Average Monthly Lead 0.62 mg/i 0.38 mg/i Zinc 0.1 mg/i 0.1 mg/i 8-12 ------- WHOLE EFFLUENT TOXICITY (WET) The total toxic effect of an effluent measured directly with a toxicity test. DEFINITION OF LC 50 Concentration of a toxicant which is lethal to 50 percent of the exposed organism. Usually expressed in conjunction with the exposure duration, i.e., 48 hr LC 50 . DEFINITION OF NOEC No Observed Effect Concentration (NOEC) - the highest concentration of an effluent or a toxicant at which no adverse effects are observed on the aquatic test organisms. NOTES: 8-13 ------- EXAMPLES OF TOXIC UNITS (TU) Acute: 100 • TU= • LC 50 100 • TU= 28% • TU= 3.6 Chronic : • TU= NOEC 100 • TU :•• 10% • TU = 10 DEFINITION OF ACUTE-CHRONIC RATIO • Acute-chronic ratio (ACR) - the ratio of the acute toxicity of an effluent or a toxicant to its chronic toxicity. It is used as a factor for estimating chronic toxicity on the basis of acute toxicity data, or for estimating acute toxicity on the basis of chronic toxicity data. • Example: LC TU ACR = NOEC orIC = TU ACR- LC 50 28% - NOEC1O% ACR= 2.8 8-14 ------- PRACTICAL EXERCISE Whole Effluent Toxicity Water Quality—Based Effluent Limitations DIRECTIONS : Preliminary examination of toxicity testing data submitted by Luster Glass, Inc. indicates that toxicity is present in the effluent discharged to the Illinois River. Therefore, you must determine if there is a need for developing whole effluent toxicity (WET) effluent limitations for the Luster Glass permit. If you determine a need for WET effluent limitations, then calculate those limits. GIVEN : Cr = (Cd)(Qd) + (Cs)(Qs) (Qd + Qs) Where Cr = receiving water concentration Cd = effluent concentration Qd = effluent flow Cs = receiving water background concentration Qs = appropriate receiving water flow Toxicity Data (Fathead minnows) from Discharge Monitoring Reports: LC NOEC Acute to Chronic ( % effluent) ( % effluent) Ratio 58.0 50 1.16 25.2 3 8.40 55.0 10 5.50 46.3 30 1.54 44.8 25 1.79 5.9 1 5.90 67.8 10 6.78 3.9 1 3.90 50.1 30 1.67 52.0 10 5.20 32.1 3 10.70 41.7 30 1.39 Average 40.2 16 4.5 (1) Select the effluent concentrations (Cd) for acute (LC ) and chronic (NOEC) toxicity representing the most toxic concentration and convert into toxic units (TU). Acute Chronic 8-15 ------- (2) Calculate the receiving water concentration (Cr) in toxic units for both acute and chronic toxicity given the following: Cs = 0 = 23.6 cfs (for acute protection) Qs = 70.9 cfs (the 7Q10 for chronic protection) Qd = 7.06 cfs Acute Chronic (3) Determine the need for WET limitations by comparing each receiving water concentration calculated in question (2) with the State water quality standards for acute and chronic protection. Given that: State Water Quality Standard for Acute Protection = 0.3 TU 1 State Water Quality Standard for Chronic Protection = 1.0 TU Are WET effluent limitations necessary? Explain your answer. (4) If it was determined in question (3) above that WET limitations are needed, then calculate the waste load allocations for acute and chronic WET using the following equation: Cd = WLA = Cr (Qd + Qs) — (Cs)(Qs) Qd 8-16 ------- (5) Convert the acute WLA (in TU 1 ) to TU using the acute to chronic ratio (ACR) provided with the toxici.ty data. (6) Given that all State water quality standards are expressed as never to be exceeded (i.e., water quality-based limits must be protective of the most stringent waste load allocation), calculate a maximum daily limitation (MDL) and an average monthly limitation (AML) for WET using the waste load allocations calculated above. (Note: Assume a ratio of daily maximum to monthly average of 1.6 for WET.) 8-17 ------- MONITORING CONDITIONS AND ANALYTICAL METHODS ------- LEARNING OBJECTIVES • The who, what, where, when, and how of monitoring • Permit writer’s responsibility PURPOSE OF MONITORING • Determine compliance with permit conditions • Assess treatment efficiency • Establish a basis for enforcement actions NOTES: 9-1 ------- MONITORING TYPES • Self monitoring - Permittee performs sampling and analysis; submits results to regulatory authority on discharge monitoring report (DMR) • Compliance monitoring - Permitting authority, or a designated representative, performs a compliance inspection ELEMENTS OF MONITORING • Sample location • Sample frequency • Type of sample • Analytical methods • Reporting NOTES: 9-2 ------- SAMPLE LOCATION QUESTIONS • Is the sample point on the facility property? • Is the sample point accessible? • Will the results be representative? • Are monitoring internal points needed? FREQUENCY CONSIDERATIONS • Size of facility • Type of treatment • Location of discharge • Frequency of discharge • Compliance history Nature of pollutants NOTES: 9-3 ------- EXAMPLE: MONITORING FREQUENCY PLANT CAPACITY ( MGD) FLOW OTHER PARAMETERS o - 0.099 Weekly Quarterly 0.1 - 0.99 Daily Monthly 1.0 - 4.99 Record continuously Weekly report daily > 5.0 Record continuously Daily report daily TYPES OF SAMPLING • Grab • Composite - Time proportional - Flow proportional • Continuous NOTES: 9-4 ------- ANALYTICAL METHODS • What methods to use • Alternative methods • Indicator parameters • Financial considerations NOTES: 9-5 ------- ANALYTICAL COSTS Priority pollutants scan (8080, 8240, 8270, cyanide, total phenols, priority pollutant metals) Purgeable holocarbons and aromati cs Gasoline (BTX) Total organic carbon BOD 5 Metals (As, Cd, Pb, Se, Sb, Ti) (Ag, Ba, Be, Ca, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, V, Zn) Hex-chrome Cyanide (total) Phenols (total) PCP Pesticides Herbicides EP Toxicity (metals) Oil and grease Odor, color, turbidity Total suspended solids Volatile organics (VOA) Chlorinated pesticides and PCBs Polynuclear aromatic hydrocarbons (PAH) Fecal coliform NOTES: $1000 - $1500 $150 - $300 $50-$150 $40 - $75 $25 - $40 $10 - $20 each $10 - $20 each $25 - $50 $25 - $50 $40 - $75 $120 - $165 $100 - $200 $110 - $250 $125-$175 $25 - $50 $20 - $35 $10-$20 $200 - $300 $125 - $200 $150 - $200 $10-$25 9-6 ------- PERMIT ANALYTICAL COSTS (ANNUAL) PERMIT NO. 1 Times Unit Annual Per Year Cost(S) Cost(S ) BOD 5 104 30 3,120 TSS 104 15 1,560 Fecal Coliform 104 15 1,560 Oil and Grease 104 35 3,640 Total 9,880 PERMIT ANALYTICAL COSTS (ANNUAL) PERMIT NO. 2 Times Unit Annual Per Year Cost($) Cost(S ) Priority Pollutants 4 1,250 5,000 Phenols 52 50 2,600 BOD 5 156 30 4,680 TSS 156 15 2,340 BTX 52 100 2,340 Nickel 156 15 2,340 Chromium 156 15 2,340 Copper 156 15 2,340 Lead 156 15 2,340 Zinc 156 15 2,340 Cyanide 52 35 1,820 Hardness 156 15 2.340 Total 35,680 9-7 ------- REPORTING • What is reported • When is information reported • Who is responsible for reporting • What format is used for reporting RECORD KEEPING • How long are records kept • What kind of records • Where are the records maintained • Who keeps the records NOTES: 9-8 ------- LEARNING OBJECTIVES • Whole effluent toxicity definition • Types of toxicity tests • Toxicity endpoints • Quality assurance/quality control NOTES: 9-9 ------- WHOLE EFFLUENT TOXICITY (WET) • Aggregate toxic effect of an effluent measured directly with a toxicity test • A toxicity test measures a degree of response of an exposed test organism to a specific chemical or effluent U.S. District Court of Washington, DC in 1988 ruled that toxicity was a parameter. A parameter similar to BOD, TSS, etc., and therefore could be treated as such in a NPDES permit. NOTES: 9-10 ------- FRESHWATER FISH Fathead minnow: adult fecnale (left) and breeding male (right). SALTWATER FISH Silvers ide ( Menidia ) 9—11 ------- SALTWATER MYSID SHRIMP Lateral and dorsal view of a typical mysid. 9-12 ------- ACUTE TESTS • Endpoint: mortality • Capabilities - Standardized protocol - Rapid and inexpensive - Endpoint is easy to quantify • Limitations - Indicates only fatal concentrations • Works only for fast acting chemicals - May or may not reflect real-world exposure DEFINITION OF LC 50 Concentration of a toxicant which is lethal to 50 percent of the exposed organism. Usually expressed in conjunction with the exposure duration, i.e., 48 hr LC 50 . NOTES: 9-13 ------- 100% ______ 100 EXAMPLE OF ACUTE TEST DATA Effluent Concentration 25% _ 40 _ % Mortality 50% i80 12.5% i20 LC —30% 6.25% 100 z 0 z U z 0 U 1o -J LL. z U I U 0 20 40 60 80 PERCENT MORTALITY 100 9-14 ------- CHRONIC TESTS • Endpoint: mortality, growth, reproduction, etc.. • Capabilities - More sensitive than acute tests - Assesses parameters other than death • Limitations - Much more costly and time-intensive - Requires higher level of expertise to conduct test DEFINITION OF NOEC • No Observed Effect Concentration (NOEC) - the highest concentration of an effluent or a toxicant at which no adverse effects are observed on the aquatic test organisms. NOTES: 9-15 ------- DEFINITION OF LOEC • Lowest Observed Effect Concentration (LOEC) - the lowest concentration of an effluent or toxicant that results in observable adverse effects in the aquatic test population. DEFINITION OF IC 25 • Inhibition Concentration (IC) - the toxicant concentration that causes a 25 percent reduction in a non-lethal biological measurement of the test organisms, such as reproduction or growth. Determined using curve fitting with an assumption of a continuous dose-response relationship. NOTES: 9-16 ------- RESPONSE CURVE FOR CERIODAPHNIA QL!fflA CHRONIC TEST 35 0 > 25 0 20 E 15 D 0 100 1 10 NOTES: Percent effluent (log scaie) 9-17 ------- • Specific tests • Specify procedures • Use multiple species • Specify endpoints • Get QA/QC information QUALITY ASSURANCE/QUALITY CONTROL • Standard operating procedures manual • Standard test protocols • Reference toxicant testing • Chain-of-custody • Data logs • Laboratory certification TOXICITY MONITORING NOTES: 9-18 ------- MUNICIPAL NPDES PERMIT DEVELOPMENT ------- LEARNING OBJECTIVES • Permit applications • Development of effluent limits • Special conditions - Pretreatment - Sludge - Combined Sewer Overflows (CSOs) • Key responsibilities of the municipal permit writer SOURCES OF FACILITY INFORMATION • Application Form 1 and Form A (2A) • Supplemental information (sludge, toxicity, pretreatment, CSOs) • Construction grants - “NEEDS” • Solid waste agencies • Pretreatment program submission • Annual pretreatment performance report Pretreatment auditlPCl NOTES: 10—1 ------- TECHNOLOGY-BASED REQUIREMENTS FOR MUNICIPAL DISCHARGERS SECONDARY TREATMENT (40 CFR PART 133) 30 Day Avg. 7 Day Avg . 5 - Day BOD 30 mg/I 45 mg/I TSS 30 mg/ 45 mg/I pH 6-9 Removal 85% BOD 5 and TSS EXCEPTIONS/ALTERNATIVES TO SECONDARY TREATMENT REQUIREMENTS • Substitution of CBOD 5 for BOD 5 [ 133.102(a)(4))] • Substitution of COD or TOC for BOD 5 [ 133.104(b)] • Adjustments to reflect: - Combined sewers [ 133.103(a-e)1 - Industrial wastes - Waste stabilization ponds - Less concentrated influent for separate sewers - Less concentrated influent for combined sewers • Treatment Equivalent to Secondary [ 133.10S] • Waiver from secondary treatment for marine [ 125.56-125.67] discharges 10-2 ------- SPECIAL PERMIT CONDITIONS ------- EQUIVALENT TO SECONDARY • Must be trickling filter or lagoon • Biological treatment = 51+% treatment • Plant exceeds 30/30 with proper 0 & M • Water quality not adversely affected • E.T.S. limits: - Up to 45 mg/I (30 day average) - Up to 65 mg/I (7 day average) - Not less than 65% removal • Guidance distributed December 1985 PRETREATMENT PROGRAM REQUIREMENTS • What is pretreatment • Statutory authority • Role of the POTW • NPDES permit requirements NOTES: 10—3 ------- NATIONAL PRETREATMENT PROGRAM • Major goal is controlling discharges in order to: - Prevent interference with POTW processes - Prevent pass through of pollutants - Protect sludge management options • Additional programmatic goals - Encourage recycling and reclamation - Ensure POTW personnel health and safety NOTES: 10—4 ------- STATUTORY AUTHORITY - CLEAN WATER ACT Section 307(b) - National Pretreatment Standards - Basis for technology-based National pretreatment standards and general and specific prohibitions to prevent pass through and interference - Provision for adjustment of technology-based standards to account for POTW removal (through removal credits) Section 402(b)(8) - NPDES Permit Requirements - POTWs must identify indirect dischargers - POTWs must establish local programs to ensure compliance with pretreatment standards by indirect dischargers REGULATORY REQUIREMENTS - GENERAL PRETREATMENT REGULATIONS (40 CFR PART 403) • Objectives: - Prevent pass through - Prevent interference, including protection of sludge use and disposal - Promote reuse and reclamation of effluents and sludges • Elements: - National Pretreatment Standards - Requirements for POTW and State programs - Industrial and POTW reporting requirements • Effluent Limitations Guidelines (40 CFR 405-471) - Including categorical pretreatment standards 10—5 ------- NATIONAL PRETREATMENT STANDARDS • Prohibited discharge standards • National categorical pretreatment standards • Local limits PROHIBITED DISCHARGE STANDARDS • General prohibitions • Specific prohibitions NOTES: 10—6 ------- SPECIFIC PROHIBITED DISCHARGES [ 4O3.5(b)] • Fire/explosive hazard - Flashpoint less than 140°F/60°C • pH lower than 5.0 • Solid or viscous substances which obstruct flow to the POTW • Any pollutant (including BOD) at flow or concentration rate which interferes with the POTW • Thermal discharges causing headworks to exceed 104°F/40°C, unless POTW designed for such temperatures • Petroleumlmineral oils causing interference or pass through • Pollutants which create toxic gases/fumes causing worker health and safety problems • Trucked or hauled wastes except at points designated by the POTW • Generally, treatment cannot be achieved by dilution NOTES: 10—7 ------- NATIONAL CATEGORICAL PRETREATMENT STANDARDS • Uniform, technology-based requirements for industries in specific industrial categories LOCAL LIMITS • Locally established limits, designed to implement the and specific prohibitions and achieve environmental general objectives • Protection of water quality - Protection of sludge quality - Plant operations (e.g., inhibition) - Worker health and safety - Air emissions (future?) NOTES: 10—8 ------- OVERVIEW OF PRETREATMENT PROGRAM PROCESS Region/State P01W Notified, POTW Performs POTW Prepares and Submits identifies —9 Requirement in —a Developmental —9 POTW8 NPDES Permit Work Program Document Rejects Region/State 1 1 P01W Becomes Region/State Region/State Requires I Reviews P01W Performs 4_ implementation i Control 4Approves— Program PCI/Audit in NPDES Permit ] [ Authority Document NOTES: 10—9 ------- PRETREATMENT PROGRAM DEVELOPMENT • Who? - POTWs>5MGD - POTWs <5 MGD with past problems • What? - Legal authority - Industrial user survey - Individual control mechanisms for all SLUs - Compliance/enforcement - Resources - Data management NPDES PERMITS DRIVE THE PRETREATMENT PROGRAM BY REQUIRING: • Adequate legal authority • Maintain industrial user inventory • Develop/implement local limits • Issue individual control mechanisms to all SIUs • Conduct compliance monitoring activities • Take swift and effective enforcement • Perform data management and recordkeeping • Report to the approval authority (EPA or State) • Ensure public participation 10—10 ------- KEY RESPONSIBILITIES OF THE MUNICIPAL PERMIT WRITER • Write a good permit • Identify need for, and set where appropriate, water quality-based controls - Chemical-specific - WET • Incorporate pretreatment requirements • Incorporate sludge requirements • Incorporate CSO controls • Coordinate permit issuance with the pretreatment, sludge and CSO coordinator/expert NOTES: 10—11 ------- Organization of the Pretreatment Program and Summary of Responsibilities EPA Headquarters • Oversee Program implementation at All Levels • Develop and Modify Regulations for the Pretreatment Program • Develop Policies to Clarify and Further Define the Program • Develop Technical Guidance for Program Implementation • Initiate Enforcement Action as Appropriate EPA Regions • Fulfill Approval Authority Responsibilities for States without Program Delegation • Oversee Slate Program implementation • Initiate Enforcement Actions as Appropriate. Approval Authorities (NPDES States with Pretreatment Program Delegation) • Notify POTWs of Their Responsibilities • Review and Approve POTW Pretreatment Programs • Review Modifications to Categorical Pretreatment Standards • Oversee POTW Program Implementation • Provide Technical Guidance to PO1Ws • Regulate Industries in Nonpretreatnient Cities • initiate Enforcement Action Against Noncompliant POTWs or Industries. Control Authorities (POTWS with an Approved Pretreatment Program) • Develop and Maintain an Approved Pretreatment Program • Evaluate Compliance of Regulated Industrial Users • Initiate Enforcement Action Against Industries as Appropriate • Submit Reports to Approval Authority. • Develop Local Limits (or demonstrate that they arc not necessary) • Develop and Implement an Enforcement Response Plan Industrial Users • Comply with Applicable Pretreatment Standards: Prohibited Discharge Standards. Categorical Standards. State Requirements. and Local Limits • Comply with Federal and POTW Reporttng Requirements. 10—12 ------- PRESENTATION PREVIEW 1. What is hazardous waste? 2. NPDES pretreatment implications 3. POTW RCRA permit -by-rule 4. Available guidance ONLY “SOLID” WASTES CAN BE HAZARDOUS WASTES • Solid wastes - any material which is: - Abandoned for disposal - Burned - Stored (even if to be reused later) - Treated/reconditioned - Accumulated for speculation • Exclusions - Wastes regulated by other Federal law - NPDES effluents - Radioactive materials - Sludge (depends on disposal practice) - Domestic sewage and any other wastes which mix with domestic sewage in sewer NOTES: 10—13 ------- RCRA REQUIREMENTS ASSUME THAT: • NPDES (secondary treatment) and pretreatment (local limits, categorical standards, and prohibited discharges) adequately address wastes being discharged to sewer systems SOLID WASTES ARE HAZARDOUS WASTES IF: • They exhibit hazardous characteristics - Ignitable (flashpoint <140°F) - Corrosive (pH <2.5 or >12.5) - Reactive (unstable in water) - Toxic (TCLP test - 40 substances) - Exclusion for household wastes and special recycled wastes: sludge conditioner or treatment aid at POTW • The waste/or process is listed in Federal or State regulations NOTES: 10—14 ------- FOUR TYPES OF LISTED WASTES 1. Generic industrial sources (21) 2. Specific industrial processes (88) 3. Acutely hazardous chemicals (204) 4. Toxic (known characteristic wastes) (454) PRESSURES TO DISPOSE OF HAZARDOUS WASTES AT POTWS • Land ban and RCRA closure requirements make self-disposal costly/impossible • Limited number of permitted TSDFs • Domestic sewage exclusion is attractive to generators • Increasing number of CERCLA cleanups approaching POTWs for partial treatment NOTES: 10—15 ------- NPDES PERMIT IMPLICATIONS OF ACCEPTING HAZARDOUS WASTES • Inhibition of biological treatment (permit violation) • Pass through (permit violation) • Sludge contamination (permit violation) • Possible worker health and safety effects • Increased self-monitoring • Report new/changed influent • NPDES permit modification PRETREATMENT IMPLICATIONS OF ACCEPTING HAZARDOUS WASTES • Local limits analysis needed to determine acceptability of waste • Local limits development • Designating and monitoring a receiving point for wastes • Treating the source as SIU: permitting, monitoring, tracking and enforcement • New multijurisdictional issues NOTES: 10—16 ------- RCRA IMPLICATIONS OF ACCEPTING HAZARDOUS WASTES • POTW has duty to inform potential generators of RCRA requirements for manifesting waste and proper disposal • Treating, storing, or disposing hazardous wastes requires RCRA permit • POTWs having releases of hazardous wastes or hazardous constituents may have to undertake corrective action • POTWs whose sludge is a characteristic waste must manifest and dispose at a TSD facility REQUIREMENTS FOR POTWs WITH RCRA PERMITS-BY-RULE • NPDES permit/compliance with permit conditions • Waste received by POTW must comply with all pretreatment requirements • EPA hazardous waste facility identification number • Hazardous waste manifest system and written operating record at facility • Biannual reports to State or EPA region waste management division NOTES: 10—17 ------- CONTENTS OF PERMIT-BY-RULE RIDER PERMITS • Reporting duties: - Sample wastes - Report findings • Corrective action duties: - Interim emergency measures - Provide data and facility access - Develop C.A. plan/reopener - Implement plan within date certain RIDER PERMIT ISSUANCE PROCESS • Duration - 10 years • Use RCRA procedures • Consolidate with NPDES when possible • Consolidation requires cooperation between programs • State program issuance complexities NOTES: 10—18 ------- AVAILABLE RCRA/CERCLA GUIDANCE • RCRA information on hazardous wastes for POTWs (9/85) • Guidance for the identification of hazardous wastes delivered to POTWs by truck, rail or dedicated pipe (6/87) • Guidance for implementing RCRA permit-by-rule requirements at POTWs (7/87) • Policy on the discharge of wastewater from CERCLA sites into POTWs (4/86) POTW AS A HAZARDOUS WASTE GENERATOR • Emuent or sludge is hazardous - Contains listed waste - Exhibits characteristics • POTWs must: - Manifest wastes - Send to permitted TSDF - Hold long-term liability NOTES: 10—19 ------- Revised 07/91 SUMMARY STATUS OF NATIONAL CATEGORICAL PRETREATMENT STANDARDS: MILESTONE DATES FINAL REGULATIONS Proposed PSES 90-Day 40 CFR New Source Promulgation Effective Compliance Compliance Report Industry Category Part Rule Date Date Date BMR Due Date Date Due Date Aluminum Forming 4672 11-22-82 10-24-83 12-07-83 06-04-84 10-24-86 01-22-87 Battery Manufacturing 461 11-10-82 03-09-84 04-23-84 10-20-84 03-09-87 06-07-87 Coil Coating (Phase I) 465 01-12-81 12-01-82 01-17-83 07-16-83 12-01-85 03-01-86 Coil Coating (Canmaking) 465 02-10-83 11-17-83 01-02-84 06-30-84 11-17-86 02-15-87 Copper Forming 468 11-12-82 08-15-83 09-26-83 03-25-84 08-15-86 11-13-86 Electrical and Electronic 469 08-24-82 04-08-83 05-19-83 11-15-83 07-01-84 (TrO)i 09-29-84 Components (Phase I) I 1-08-85(As) 02-06-86 Electrical and Electronic 469 03-09-83 12-14-83 01-27-84 07-25-84 07-14-86 10-12-86 Components (Phase II) Electroplating 413 07-03-80 01-28-81 03-30-81 09-26-81 (Non-integ) 04-27-84 (Non-intcg) 07-26-84 06-25-83 (Integrated) 06-30-84 (Integrated) 09-28-84 -- 07-15-83 08-29-83 02-25-84 (T1’O) 07-15-86 (T O) 10-13-86 Inorganic Chemicals 415 — 07-20-77 07-20-77 01-16-78 07-20-80 10-18-80 (Interim. Phase I, and 07-24-80 06-29-82 08-12-82 05-09-83 06-29-85 09-27-85 Phase II) 10-25-83 08-22-84 10-05-84 04-03-85 08-22-87 11-20-87 Iron and Steel 420 01-07-81 05-27-82 07-10-82 04-06-83 07-10-85 10-08-85 Leather Tanning and 425 07-02-79 11-23-82 01-06-83 07-05-83 11-25-85 02-23-86 Finishing 01-21-87 04-04-88 05-04-88 10-31-88 03-31-89 (Subpart C) 6 06-29-89 Metal Finishing 433 08-31-82 07-15-83 08-29-83 02-25-84 06-30-84 (Part 433, TTO)’ 09-28-84 07-10-85 (Part 420, TTO) 10-08-85 02-15-86 (Final) 05-16-86 Metal Molding and Casting 464 11-15-82 10-30-85 12-13-85 06-11-86 10-31-88 01-29-89 (Foundries) Nonferrous Metals Forming 471’ 03-05-84 08-23-85 10-07-85 04-05-86 08-23-88 11-21-88 and Metal Powders Nonferrous Metals Manufacturing 421 02-17-83 03-08-84 04-23-84 10-20-84 03-09-87 06-07-87 (Phase I) 012287 01-21-88 03-07-88 09-06-88 02-22-88 (Subpart J) 9 05-02-88 ------- Reviged 07191 SUMMARY STATUS OF NATIONAL CATEGORICAL PRETREATMENT STANDARDS: MILESTONE DATES FINAL REGULATIONS Proposed PSES 90-Day 40 CFR New Source Promulgation Effective Compliance Compliance Report Industry Category Part Rule Date’ Date Date BMR Due Date Date Due Date Nonferrous Metals Manufacturing 421 06-27-84 O 9 20- S 5 11-04-85 05-03-86 09-20-88 12-19-88 (Phase II) Organic Chemicals. Plastics. 414 03-21-83 11-05-87 12-21-87” 06-20-88 11-05-90 02 .0491 and Synthetic Fibers Pesticide Chemicals 455 11-30-82 10 O4 85 12 Petroleum Refining 419 12-21-79 10-18-82 12-01-82 05-30-83 12-01-85 03-01-85 Pharmaceuticals Manufacturing 439 11-26-82 10-27-83 12-12-83 06-09-84 10-27-86 01-25-87 Porcelain Enameling 466 02-27-81 11-24-82 01-07-83 07-06-83 11-25-85 02-23-86 Pulp. Paper, and Paperboard 430,431 01-06-81 1 1-18-82 01-03-83 07-02-83 07-01-84 09-29-84 Steam Electnc Power Generation 423 10-14-80 11-19-82 01-02-83 07-01-83 07-01-84 09-29-84 Timber Products Processing 429 10-31-79 01-26-81 03-30-81 09-26-81 01-26-84 04-25-84 Footnotes ‘The term “new source” means any building, structure, facility, or installation from which there is or may be a discharge of pollutants, the construction of which commenced after the publication of proposed pretreatment standards under Section 307(c) of the Clean Water Act which will be applicable to such source if such standards are thereafter promulgated in accordance with that section, provided that (1) the construction occurs at a new or “greenfield site, (2) the construction on an existing site “totally replaces” the process or production equipment causing the discharge, or (3) the construction is “substantially” independent of an existing source at the same site 2 The Aluminum Forming Categorical Pretreatment Standards were revised on 12/27/88, as issued in 53 FR 52366 These revisions include relaxed pretreatment standards for existing sources New discharge limits were set for oil and grease for all subparts and for chromium, cyanide (T), zinc, and Total Toxic Organics (T O) for the cleaning or etching rinse of Subparts C and D ‘The compliance date for ‘Tl’O for facilities subject to existing source Electrical and Electronic Components, Phase! regulations, is July 1, 1984 The compliance date for arsenic under this category is November 8, 1985 ‘The Electroplating proposed rule date is not used to dctermine the new source/existing source status of a facility The Metal Finishing proposed rule date is used to make this determination for all electroplating and metal finishing facilities ------- Revised 07/91 SUMMARY STATUS OF NATIONAL CATEGORICAL PRETREATMENT STANDARDS: MILESTONE DATES FINAL REGULATIONS Footnotes (Continued ) ‘The compliance date for Subparts A, B, 1, AL. AR, BA, and BC of the Inorganic Chemicals category is July 20, 1980 The compliance date for Subparts AJ, AU, BL, BM, BN, and BO (except discharges from copper sulfate or nickel sulfate processes) is August 22, 1987 The compliance date for copper sulfate or nickel sulfate processes and for all Subparts of Part 415 not listed above us June29, 1985 6 These dates apply only to Subpart C 7 Existing sources that are subject to the Metal Finishing standards in 40 CFR Part 433 must comply only with the interim limit for ‘ll’O by June 30, 1984. Plants also subject to the Iron and Steel Manufacturing standards in 40 CFR Part 420 must comply with the interim TFO limit by July 10, 1985 The compliance date for metals, cyanide, and final 11 ’O is February 15, 1986, for all sources 5 lhese regulatint crc revised on March 17, 1989, (54 FR 11346) to allow pollutant discharge from the tube reducing spent lubricant process of Subpart C and Subpart I provided nitrosaminc compound discharge limits arc met These dates arc for Subpart 3, tungsten category iO() April 26, 1989, a modification of some Nonferrous Metals Manufacturing regulations were proposed (54 FR 18411) D 3 Ii()fl June 29, 1989, part of the OCPSF regulations were remanded to EPA for additional consideration. ‘ On July 25, 1986, the Eleventh Circuit Court of Appeals remanded to the EPA the final regulation originally promulgated on October 4, 1985, for the Pesticide Chemicals category. EPA removed the regulation from the Code of Federal Regulations on December 15, 1986 (40 FR 44911) Note The compliance date for any discharge that is subject to Pretreatment Standards for New Source (PSNS) facilities is within 90 days of the date of the commencement of the discharge The Baseline Monitoring Report (BMR) for a new source is due 90 days prior to the commencement of discharge. ------- A/R6-36a/#2f DEVELOPMENT DOCUMENTS FOR EFFLUENT LIMITATIONS GUIDELINES AND STANDARDS FOR SPECIFIC INDUSTRtAL CATEGORIES CATEGORY OF BG() CFR PART NUMBER INDUSTRIAL STUDIES SUBCATEGORY SOD DOCUMENT NUMBER GPO STOCK NUMBER NTIS ACCESSION NUMBER 405 DaIry Products a) Dairy Products Processing EPA 440/1-14/0214 5501 .00898 PB238835/AS Processing (Draft) 406 Grain MIII . a) Grain Processing EPA 440/1-74/028-a 550100844 PB238316/AS (Draft) b) AnImal Feed, Beakfast Cereal & EPA 440/1-74/039-a 550101007 PB240861/AS Wheat (Draft) 407 Canned 8 Preserved a) Citrus. Apple & Potatoes (Draft) EPA 440/1-74/027-a 550 100790 P5238649/AS Fiults & Vegetables Procssalng 408 Canned 8 Preserved a) Catfish, Crab, Shrimp (Draft) EPA 440/1-74/020-a 5501-00920 P9238614/AS Seafood Processing b) Report to Congress. EPA 440/1-80/020 P9811 82354 SectIon 74 Seafood Processing Executive Summary- (Volumes I-Ill) 409 Sugar ProcessIng a) Beet (Final) EPA 440/1-74/002-b 5501.00117 P9238462/AS b) Cane EPA 440/1-74/002-c 5501-00826 PB238147/AS 410 TextIle Mills a) Textile Mills EPA 440/1-74/002-a 5501-00903 PB238832/AS b) Textile Mills (Final) EPA 440/1-82/0022 P583-I 15871 411 Cement Manufacturing a) Cement Manufacturing (Draft) EPA 440/1-74/005-a 5501-00866 PB238610/AS 412 Feedlots a) Feedlots (Draft) EPA 440/1.74/001-a 5501-00842 P8238651/AS 413 ElectroplatIng a) Copper, Nlclcel, Chrome and Zinc EPA 440/1-74/003-a 5501-00816 P8238834/AS (Draft) b) Electroplating Pretreatment (Anal) EPA 440/1-79/003 P880-196488 414 OrganIc Chemicals a) Major Organic Produclti (Draft) EPA 440/1-74/009-s 5001-008812 P8241906/AS Manufacturing b) Orcianlc Chemicals & EPA 440/1-83/009-b P883-205625 Plastics & Synthetic Fibers (Proposed) 415 ktOganIc Chemicals a) Major InorganIc Chemical Products EPA 440/1-74/007-a 5502.00121 PB23861 1/AS Manufacturing (Draft) b) Inorganic Chemicals (Proposed) EPA 440/1-80/007-b P881-122632 c) Inorganic Chemicals (Final) EPA 440/1-82/007 P882-265612 416 Plastic & Synthetic a) Synthetic Resins (Draft) EPA 440/1-74/010-a 5501-00815 P882-3924/AS b) Synthetic Polymers EPA 440/1-74/036 5501-01012 PB240862/AS c) Organic Chemucals/Placiic& EPA 440/1-83/009 b PB83 205625 Synthotic I iber (Piopo .od) ------- DEVELOPMENT DOCUMENTS FOR EFFLUENT UMITATIONS GUIDELINES AND STANDARDS FOR SPECIFIC INDUSTRIAL CATEGORIES (Continued) CATEGORY OF BGD CFR FART NUMBER INDUSTRIAL STUDIES SUSCATEGORY BGD DOCUMENT NUMBER GPO STOCK NUMBER NTIS ACCESSION NUMBER 417 Soaps & Detergents a) Soaps & Detergents (Draft) EPA 440/1-74/010-. 5501-00867 PB2S86 13/AS Manufacturing 418 Fertilizer a) Basic Fertilizer Chemicals (Draft) EPA 440/1.74/011- . 5501-00868 P8238652/AS b) Formulated Fertilizer (Draft) EPA 440/1-75/0424 5501-01006 P8240863/AS Petroleum Refining a) Petroleum Refining (Draft) EPA 440/1-74/014-a 5501-00912 PR a8612/AS b) Petroleum RefinIng (Proposed) EPA 440/1-79/014-b P88t-1 18413 c) Petroleum Refining (Final) EPA 440/1-82/014 PB83- 172569 420 Iron & Steel a) Steel MakIng (Draft) EPA 440/1.74/024-a 550100900 PB238837/AS b) Iron & Steel EPA 440/1.80/024-a P881-t84384 Volumes I-V C) Iron & Steel (Final) EPA 440/1-82/024 Volume I PB82-24 0425 Volume II P882-240433 Volume Ill P882-240441 Volume N P882-240458 Volume V P882-240466 Volume 1 P882-240484 421 Nonferrous Metals a) Bauxlts Refining EPA 440/1-74/0910 5501-00116 P8128463/AS Manufacturing b) Primary Aluminum Smelting EPA 440/1-74/019 -d 5501-00017 P8234859/AS C) Secondary AlumInum Smelting EPA 440/1.74/019-. 5501-00819 P8238464/AS 422 Phosphate a) Phosphorus DerIved Chemicals EPA 440/1-74/006-a 5503-00078 P8241018/AS Manufacturing (Draft) 423 Steam Electric a) Steam Electric Power EPA 440/1-74/029-a 5501-01001 P8230853/AS Powerplanti (Draft) b) Steam Electric (Proposed) EPA 440/1-80/029-b P881-I 19075 424 Ferroalloy a) Smelting & Slag Processing EPA 440/1-74/008-a 5501-00780 P8238650/AS (Draft) 425 Leather Tanning a) Leather Tanning (Draft) EPA 440/1-74/016-a 5501-00818 PB238648/AS b) Leather Tanning (Final) EPA 440/1-82/016 P883-172593 426 Glass Manufacturing a) Pressed & Blown Glass EPA 440/1-75/034-a 5501-01036 b) Insulation Fiberglass EPA 440/1-74/001-b 5501-00781 PB128078/AS c) Flat Glass EPA 440/1-74/001-C 5501-00814 -- 427 Asbestos a) Building, Construction EPA 440/1-74/017-a 5501-00827 P8238320/AS Manufacturing and Paper (Oral I) ------- A/I-4o-36a/# - DEVELOPMENT DOCUMENTS FOH EFFLUENT LiMITATIONS GUIDELINES - iD STANDARDS FOR SPECIFIC INDUSTRIAL CATEGORIES (Continued) CATEGORY OF BGD CFR PART NUMBER INDUSTRIAL STUDIES SUBCATEGORY ROt) DOCUMENT NUMBER GPO STOCK NUMBER NTIS ACCESSION NUMBER 429 Ribber Processing a) lit. & Synthetic EPA 440/1-74/0134 550100885 P8238609/AS b) Fabricated & Reclaimed EPA 440/1-74/030. 5501-01016 P8241916/AS Ribber 429 Timber Products a) Plywood & Wood (Draft) EPA 440/1-74/023-a 5501-00853 P624061 1/AS Processing b) Timber Products (Final) EPA 440/1-81/023 PB8 I-22728 430 Pulp, Paper and a) Unbiesehed Kraft and EPA 440/1-74/025-a P 823RA33/AS Paperboard Semi-chemical Pulp (Draft) b) Pulp & Paper & Paperboard and EPA 440/1-82/025 P881-163949 Builders Paper & Board Mills (Final) 0) Pulp. Paper & Paperboard and EPA 440/1-82/025 P683-163949 Bulldere Paper & Board Mills (Final) 431 BuIlder’s Paper & a) Builders Paper & Roofing (Draft) EPA 440/1-74/026-a 5501-00909 P8238076/AS Board Mills b) Pulp. Paper & Paperboard and EPA 440/1-82/025 P883-163949 Builder’s Paper & Board Mills (Final) 432 Meat Products and a) Red Meat Processing EPA 440/1-74/012-a 5501-00843 P8238076/AS Rendering b) Renderer EPA 440/1-74/031 P8238836/AS 433 Metal Finishing a) Metal FinIshIng (Proposed) EPA 440/1-82/091-b P883-102004 b) Metal Finishing (Anal) EPA 440/1-82/091 P834-115989 434 Coal Mining a) Coal Mining (Proposed) EPA 440/1-81/067-b P681119296 b) Coal Mining (Final) EPA 440/1-82/057 P683/108042 436 Mineral MinIng a) Repoit to Congress EPA 440/1-82/059 P682242207 & Processing The Effects of Discharges from Limestone Quarries on Water Quality and Aquatic Blota 440 Ore Mining a) Volume I EPA 440/1-78/0614 P8286520/AS and Dressing b) Volume I I EPA 440/1-78/0614 P8286521/AS c) Ore Mining & Dressing (Proposed) EPA 440/1-82/061-b PBS2-250952 455 Pesticides a) Pesticides EPA 440/1-76/OW-. PB285480/AS b) Pesticides (Poposod) EPA 440/1-82/079-b - PB&3-1 53 il l C) Test Methods for Non-Conventional EPA 440/1-82/079-c P883-176636 Pesticides Chemical Analysis ol lndustiial & Municipal Waste- ------- DEVELOPMENT DOCUMENTS FOR EFFLUENT LIMITATIONS GUIDEUNES AND STANDARDS FOR SPECIFIC INDUSTRIAL CATEGORIES (Continued) CATEGORY OF BGD CFR PART NUMBER INDUSTRIAL. STUDIES SUSCATEGORY ROD DOCUMENT NUMBER GPO STOCK NUMBER NTIS ACCESSION NUMBER 461 Battery Manufacturing a) Battery Manufacturing (Proposed) EPA 440/1.82/067-b P883-197921 463 PlastIc Processing a) Plastic Molding & Forming EPA 440/1-84/069-b P684-171578 (Proposed) 465 CoIl CoatIng a) Coil Coating (Final) EPA 440/1-82/071 P883-205542 b) CoB Coating Canmaking (Final) EPA 440/1-83/Oil P884-190847 466 Poros llin a) Poroelain (Proposed) EPA 440/1-80/012-b P881-201521 488 Copper Forming a) Copper (Final) EPA 440/1-84/074 P684-192459 469 EI.ctron lca a) EIecttlcal S Electronic EPA 440/1-82/015-b P882-249613 Components (Phrase I) ------- Approved State NPDES Pennit Program A roved State NPDES and Prcueauncnt Programs Figure 1-1. Status of State NPDES and Pretreatment Program Approvals, November 1990 Thirty-nine States and territories have federally approved NPDES programs. Twenty-seven States have federally approved pretreatment programs. I . t ) - .4 Source: “NatinnRl Pretreatment Program Report to Congress” (EPA; 21W-4004; July, 1991) ------- Source: “NatinnRl Pretreetment ProgrAm Report to Congress” (FPA: 21W—4004; July, 1991) Figure 1-2. Approved Local Pretreatment Programs Numbers 41 4TR1t-30 PtsiWs Ii, Appi.v.d I P a Plants hi She-Run “° • 1 2 3 4 5 6 7 8 9 10 78 79 133 405 327 124 78 54 121 43 82 178 174 537 382 252 128 57 163 62 93 — — 199 — — 22 — — — Total 1,442 2,015 314 F’., April 1990 D State-Run Programs ------- MUNICIPAL SLUDGE PERMIT CONDITIONS ------- LEARNING OBJECTIVES • Definition of sludge • Statutory requirements • Interim program • Implementation procedures • Long term program NOTES: 11—1 ------- DEFINITION OF SEWAGE SLUDGE Any solid, semisolid, or liquid residue removed during the treatment of municipal wastewater or domestic sewage. Sewage sludge includes, but is not limited to, solids removed during primary, secondary, or advanced wastewater treatment, scum, septage, portable toilet pumpings, type III marine sanitation device pumpings (33 CFR Part 159) and sewage sludge products. Sewage sludge does not include grit or screenings, or ash generated during the incineration of sewage sludge. 40 CFR 122.2 VOLUME OF SLUDGE PRODUCED IN THE U.S. NOTES: 11—2 ------- WATER QUALITY ACT OF 1987 SLUDGE USE AND DISPOSAL §405 • EPA will develop technical standards for proper use and disposal (expected January 1992) • Technical standards will be implemented primarily through NPDES program • Interim NPDES permit conditions will be based on case-by-case judgment of permit writer • Non-NPDES POTWs and other treatment works regulated through separate sludge-only permit SCOPE OF INTERIM PROGRAM • Permits for all NPDES POTWs issued after 2/4/87 will address sludge use and disposal • As needed to protect public health and the environment EPA may regulate - End users - Industrial facilities which treat domestic waste - Privately owned treatment works - Federal facilities • Class I sludge management facilities must receive special attention NOTES: 11-3 ------- ALL POTW PERMITS MUST CONTAIN: • Standard conditions ( 122.41) • Minimum monitoring and reporting ( 122.44) • Applicable existing sludge requirements - Landfill/land application - 40 CFR Part 257 - Incineration - 40 CFR Parts 60 and 61 - 40 CFR Part 761 CONDITIONS FOR ALL PERMITTED FACILITIES • General duty to comply with existing requirements/future Part 503 ( 122.41(a)(1)) • Reopener once Part 503 standards are promulgated ( 122.44(c)(4)) • Duty to mitigate ( 122.41(d)) • Records retention (5 years) ( 122.41(j)(2)) • Notification requirements for significant changes to use and disposal ( 122.41(l)(1)(iii)) • Reopener for changed conditions ( l22.62(a)(1)) • Analytical methods ( 122.41(j)(4)) NOTES: 11-4 ------- CLASS I SLUDGE MANAGEMENT FACILITIES • Any POTW required under 40 CFR 403.8(a) to have an approved pretreatment program, including POTWs covered under 403.10(e) State program • Any other treatment works treating domestic sewage which have been designated by EPA and approved State programs as priorities (e.g., POTWs which incinerate sludge) CLASS I FACILITY PERMITS MUST CONTAIN: • Standard conditions ( 122.41) • Applicable existing sludge requirements ( 122.44) • Other conditions necessary to protect health and the environment developed on a case-by-case basis - Regulate additional pollutants - Prescribe management practices/siting characteristics - More than minimum monitoring - Restrict public access - Ground-water protection measures NOTES: 11—5 ------- SELF-MONITORING AND REPORTING RECOMMENDATIONS • Non-Class L’no industry - Annual metals scan (Cd, Pb, Ni, Zn, Cr, Cu) • Non-Class I/industry - Priority scan at application - Annual 503 scan • Class I - Annual priority pollutant scan - 503 pollutants periodically SUPPLEMENTAL APPLICATION INFORMATION* • Sludge profile - quality and quantity • Other sludge permits held • Topographical map of sludge disposal sites • Narrative description of disposal practices • Identify other entities handling sludge * 12221(d)(3)(jjj) and §501.1S(a)(2) NOTES: 11-6 ------- SOURCES OF SLUDGE FACILITY INFORMATION • National survey - results released November 1990 (55 Fed. Reg. 47210) • Other Federal and State sludge/solid waste agencies • Pretreatment program submission and audit reports • Compliance inspection reports • Public health agencies • Construction grants database • Agricultural agencies • 208 basin plans • RCRA 4003 solid waste plan EPA/STATE INTERIM AGREEMENTS • All States may participate • Establishes responsibility for interim program implementation - Permitting - Compliance monitoring - Enforcement - Information exchange • EPA responsible for interim permitting in the absence of EPA/State agreements NOTES: 11—7 ------- STATE PERMIT ISSUANCE PROCEDURES • State permits must notice that conditions are Federally enforceable • Fact sheet must also note Federal enforceability • EPA reviews all Class I facility permits and affirmatively approves sludge conditions • Region must affirmatively approve the permit (letter or certification) EPA ALTERNATIVES FOR ISSUANCE IN NPDES STATES • Attach sludge-only “rider” conditions to State permits - Follows state process and procedures • Separate sludge permit - NPDES permit (402 and 405) - NPDES procedures NOTES: 11-6 ------- LONG TERM REGULATORY PROGRAM Part 503 - Sewage Sludge Technical Standards - Land application - Incineration • Monotills - Distribution and marketing - Surface disposal Due: April 1992 Part 258 - Municipal Solid Waste Landfills - Management practices - Financial responsibility - Siting criteria Promulgated: October 9, 1991 (56 FR 50977) NOTES: 11-9 ------- LONG TERM PROGRAM - PART 503 • Health/environ mental -based standards - Sludge quality - Management practices - Siting requirements - Implemented primarily through NPDES permits • Land application (42%) • Agricultural lands - Nonagricultural lands • Distribution and marketing (6%) • Incineration (14%) • Monofills and surface disposal (2%) • Domestic septage • Court ordered promulgation by January 1992 NOTES: 11-10 ------- PART 503 COMPLIANCE DEADLINES • Within 1 year of promulgation of the regulations • Within 2 years, if construction of new pollution control facilities is required TOOLS AVAILABLE TO ASSIST PERMIT WRITERS • NPDES/sludge permitting and State program regulations 54 Fed. Reg. 18716 (5/2/89) • Sludge permitting strategy, OW (9/89) • Case-by.case permitting guidance, OWEC (5/90) • Guidance on sampling and analysis of municipal sewage sludge, OWEC (8/89) • Proposed technical criteria 54 Fed. Reg. 5746 (2/6/89) NOTES: 11—11 ------- STORM WATER PERMITTING ------- LEARNING OBJECTIVES • Storm Water Program Overview • Industrial Requirements • Municipal Requirements NOTES: 12-1 ------- WATER QUALITY IMPACTS ATTRIBUTABLE TO STORM WATER • Naturally, pollution from diffuse sources such as runoff from agriculture and urban areas are the leading causes of water quality impairment • Diffuse pollution sources are increasingly important as controls for industrial process dischargers and POTWs are implemented • 38 States have reported urban runoff as a major cause of use impairment • 21 States report construction site runoff as a major cause of use impairment • In some municipalities, illicit connections to separate storm sewers have had a significant adverse impact. Removing illicit discharges presents opportunities for dramatic improvement in the quality of storm water discharges from urban areas. • One study showed that 14% of the buildings studied within a drainage basin had improper connections to storm sewers; connections approved when the structures were built. NOTES: 12-2 ------- CLEAN WATER ACT REQUIRES PHASED APPROACH FOR PERMITTING STORM WATER DISCHARGES • Prior to 10/1/92, storm water permits are only required for: - Storm water regulated under an existing permit - Storm water that is associated with an industrial activity - Storm water that is discharged from municipal separate storm sewers serving 100,000 or more persons - Administrator or State Director may designate, for permitting, storm water discharges contributing to a violation of water quality standards or which are significant contributors of pollutants • All other storm water discharges are the subject of 2 EPA studies, and subsequent regulation after 10/1/92 NOTES: 12-3 ------- STORM WATER DISCHARGE ASSOCIATED WITH INDUSTRIAL ACTIVITY • Discharge from any conveyance which is used for collecting and conveying storm water • Directly related to manufacturing, processing, or raw materials storage areas • Located at an industrial plant • Other industrial facilities and operations APPLICATION REQUIREMENTS FOR STORM WATER DISCHARGES ASSOCIATED WITH INDUSTRIAL ACTIVITY • Discharges of storm water associated with industrial activity are required to either: - Apply for an individual permit (Form 2F), - Apply for a permit through a group application, or - Seek coverage under a storm water general permit using notice of intent NOTES: 12-4 ------- Group: Part 1 September 30, 1991 Review Period Part 2 12 months after Part 1 approval 60 days Construction: 90 Days Prior to Initiation of Construction Estimated coverage: 100,000 facilities STATUTORY REQUIREMENTS FOR INDUSTRIAL STORM WATER PERMITS • Permits must require the achievement of CWA 301 [ effluent limitations (BAT/BCT)] and water quality-based limitations • Permitted industries must continue to meet all existing requirements of CWA 402 NOTES: 12-5 INDUSTRIAL STORM WATER PERMIT APPLICATION DEADLINES Individual: November 18, 1991 General 180 Days from Permit NOl: General Permit Issuance ------- Part 1 Review Period Part 2 Medium Municipalities May 18, 1992 90 Days May 17, 1993 Large Municipalities November 18, 1991 90 Days November 16, 1992 Estimated coverage: 173 Cities and 47 Counties NOTES: 12—6 MUNICIPAL SEPARATE STORM SEWER SYSTEMS • Large system - serving a population of 250,000 or more • Medium system - serving a population of 100,000 or more, but less than 250,000 MUNICIPAL PERMIT APPLICATION DEADLINES ------- STATUTORY REQUIREMENTS FOR MUNICIPAL SEPARATE STORM SEWER SYSTEM PERMITS • System or jurisdiction-wide permits allowed • Effectively prohibit non-storm water discharges into storm sewers • Controls to reduce discharge of pollutants to MAXIMUM EXTENT PRACTICABLE (MEP) NOTES: 12-7 ------- COMBINED SEWER OVERFLOW (CSO) PERMITTING ------- LEARNING OBJECTIVES • CSO Overview • Permitting Requirements NOTES: 13-1 ------- cso Definition CSOs are flows from a combined sewer in excess of the interceptor or regulator capacity that are discharged into a receiving water without going to a Publicly Owned Treatment Works (POTW). • CSOs point sources • CSOs are .gj bypasses • CSOs are jj. j subject to secondary treatment regulations • CSOs subject to BCT and BAT and State water quality standards NOTES: 13-2 ------- CSO URBANIZED AREAS 13-3 ------- CSO PERMIT APPLICATION FORMS • Form 2A - Permitted in conjunction with a POTW • Form 2C - Permitted separately’ from a POTW NOTES: 13-4 ------- THE CSO CONTROL STRATEGY REQUIRES • States to develop CSO permitting strategies by January 15, 1990 • Regions to approve State CSO permitting strategies by March 31, 1990 CSO PERMITS • Permit issuance • Minimum technology-based limitations • Additional CSO control measures • Monitoring NOTES: 13-5 ------- MINIMUM BCT/BAT LIMITATIONS • Prohibition of dry weather overflows; • Proper operation and regular maintenance programs for the sewer system and combined sewer overflow points; • Maximum use of the collection system for storage; • Maximization of flow to the POTW for treatment; • Review and modification of pretreatment programs to assure CSO impacts are minimized; and • Control of solid and floatable materials in CSO discharges. NOTES: 13-6 ------- LEARNING OBJECTIVES • Additional nonregulatory monitoring • Compliance schedules in permits • Best management practices ADDITIONAL NONREGULATORY MONITORING • Used to supplement controls • Used to collect data for future limit development NOTES: I — i ------- COMPLIANCE SCHEDULES • 40 CFR §122.47 - Allows for establishing schedules of compliance that lead to compliance with CWA and regulations - Interim dates if schedule exceeds 1 year from permit issuance - Reporting 14 days following each interim date NOTES: 14-2 ------- BEST MANAGEMENT PRACTICES LEGISLATIVE AUTHORITY Section 304(e) - The Administrator. . .may publish regulations supplemental to effluent limitations for a class or category of point sources for toxic or hazardous pollutants under Section 307(a) or 311 of the Act to control: - Plant site runoff - Spillage or leaks - Sludge or waste disposal - Drainage from raw material storage .which are associated with or ancillary to the industrial manufacturing or treatment process and may contribute significant amounts of such pollutants to navigable waters. Section 402(a)(1) - In the absence of BMPs promulgated for a category of point sources (such as steel mills, petroleum refiners, etc.) under authority of Section 304(e), permit writers may use the authority of Section 402(a)(1) to place BMPs in permits on a case-by-case basis NOTES: 14-3 ------- USE BMPs WHEN... • Numerical limits are infeasible • In lieu of chemical analysis • Where history of leaks and spills exists • Housekeeping is sloppy • Facility is complex and toxic pollutant data lacking • Other options are too expensive BMPs IN NPDES PERMITS • BMP plan • Site-specific BMPs - Facility-specific - Pollutant-specific NOTES: 14-4 ------- MINIMUM REQUIREMENTS OF A BMP PLAN • General requirements - Name and location of facility - Statement of BMP policy and objectives - Review by plant manager • Specific requirements - BMP committee - Risk identification and assessment - Reporting of BMP incidents - Materials compatibility - Good housekeeping - Preventive maintenance - Inspections and records - Security - Employee training BMPs ARE... • Flexible • Procedural • Qualitative Most effectively used in conjunction with effluent limitations in permits NOTES: 14-5 ------- PROCEDURAL • • • Conduct routine training Maintain maintenance logs Perform routine wall-thickness testing . QUALITATIVE • BMPs generally tell how or what, not how much BUT BMPS ALSO MAY BE: • Construction • Instrumentation • Monitoring ‘ Operation and maintenance NOTES: FLEXIBLE • Visual inspections, • Non-destructive testing, or • A dike or berm 14-6 ------- NOTES: BMPs SHOULD NOT : • Substitute for quantitative controls • Tell managers how to run their plants • Require costly methods when inexpensive ones will suffice GENERIC BMPs • Preventive maintenance • Water conservation/non-use • Secondary containment • Nondestructive testing • Materials engineering • Materials handling • Visual inspections • Covering • Sealing • Packaging • Waste stream segregation • Source elimination • Good housekeeping • Alarm systems • Diverting • Paving • Runoff control • Sludge management • Training • Monitoring • Security 14-7 ------- 160A/Disk #1 - 11/4/91 - 1:25 PM NPDES Best Management Practices GUIDANCE DOCUMENT U.S. Environmental Protection Agency Office of Water Enforcement and Permits NPDES Technical Support Branch June 1981 14$ ------- l6OAJDisk #1 - 11/4 1 - 1:26 PM PREFACE During the period June 13, 1978, to February 26, 1979, Hydroscience, Inc., under Contract No. 68-03-2568 to the Environmental Protection Agency (EPA), gathered information leading to the identification of best management practices (BMPs) currently used by industry. The result of the data gathering and analysis by Hydroscience, Inc. was a draft report entitled “NPDES Best Management Practices Guidance Document” EPA 600/9-79- 045. In response to keen public interest in the draft report, EPA made the report available to the public and provided a 45-day comment period. The comment period subsequently was extended twice, resulting in a total 120-day comment period on the report. After evaluating the comments received, EPA revised the draft report, and published the final document. This document supersedes the Hydroscience draft report dated December, 1979. 14-10 ------- 160A/Disk #1 - 10/18/91 1:21 PM ABSTRACT The purpose of this document is to assist National Pollutant Discharge Elimination System (NPDES) permitting authorities, compliance officers, and permit applicants to develop Best Management Practices (BMP) plans for industry. BMPs are authorized under the 1977 Clean Water Act for the control of discharges to receiving waters of significant amounts of any pollutant listed as hazardous under Section 311 of the Act or toxic under Section 307 of the Act from activities which are associated with or ancillary to industrial manufacturing or treatment processes. The general types of discharges to be controlled by BMPs are plant site runoff, spillage and leaks, sludge and waste disposal and drainage from material storage areas. This document provides a basis for developing BMP plans. The proper use of the document requires engineering experience with industrial manufacturing and treatment processes and knowledge of current laws and regulations applicable to NPDES permits, BMP plans, and Spill Prevention, Control, and Countermeasure (SPCC) plans. The guidance herein is based on a review by Hydroscience, Inc. (EPA Contract No. 68- 03-2568) of current practices used by industry to control the non-routine discharge of toxic pollutants and hazardous substances. Included in the review are published articles and reports, technical bulletins (also termed material safety data sheets) on specific compounds, and discussions with industry through telephone contacts, written questionnaires, and site ViSitS. 14-11 ------- 160A/Disk #1 - 1O/18 1 - 1:24 PM SECTION I INTRODUCTION BACKGROUND The Federal Water Pollution Control Act Amendments of 1972 established the objective of restoring and maintaining the chemical, physical, and biological integrity of the Nation’s waters. This objective has remained unchanged in the 1977 amendments to the Act, commonly referred to as the Clean Water Act of 1977, hereinafter “the Act.” To achieve this end, the Act sets forth a series of goals, including the goal of eliminating the discharge of pollutants into navigable waters by 1985. The principal mechanism for reducing the discharge of pollutants from point source is through implementation of the National Pollutant Discharge Elimination System (NPDES) established by Section 402 of the Act. At the time of first round NPDES permit issuance, conventional pollutants (BOD, pH, TSS, etc.) were considered the parameters which most urgently needed controls. In second round permitting, however, the Agency emphasis is shifting from the conventional pollutants to the control of toxic pollutants and hazardous substances. Traditionally, NPDES permits have contained chemical-specific numerical effluent limits. Effluent guidelines are not always available to prescribe these effluent limits nor to guarantee water quality sufficient for the protection of indigenous aquatic life. To improve water quality, the Act provides for water pollution controls supplemental to effluent limitations guidelines. Best Management Practices (BMPs) are one such supplemental control. Pursuant to sections 304 and 402 of the Act, BMPs may be incorporated as permit conditions. In the context of the NPDES program, BMPs are actions or procedures to prevent or minimize the potential for the release of toxic pollutants or hazardous substances in significant amounts to surface waters. BMPs, although normally qualitative, are expected to be most effective when used in conjunction with numerical effluent limits in NPDES permits. STATUTORY AUTHORITY Section 304(e) of the Act authorized the Administrator to publish regulations to control discharges of significant amounts of toxic pollutants listed under Section 307 or hazardous substances listed under Section 311 from activities which the Administrator determines are associated with or ancillary to industrial manufacturing or treatment processes. The discharges to be controlled by BMPs are plant site runoff, spillage or leaks, sludge or waste disposal, and drainage from raw material storage. 14-12 ------- 160A/Disk #1 - 10/18/91 - 1:24 PM Section 402(a)(1) of the Act allows the Administrator to prescribe conditions in a permit determined necessary to carry out the provisions of the Act. BMPs are one such condition. BMPs are intended to complement other regulatory requirements imposed by RCRA, OSHA, the Clean Air Act, and SPCC plans for hazardous substances under the Clean Water Act. Pursuant to Section 311 of the Act, EPA has proposed (40 CFR Part 151) requirements for SPCC plans to prevent discharges of hazardous substances from facilities subject to NPDES permitting requirements. The guidelines proposed for hazardous substances SPCC plans are very similar to those required for oil SPCC plans in the Oil Pollution Prevention Regulations, (40 CFR Part 112). Since the Agency has received favorable comments about the Oil Pollution Prevention Regulations, the NPDES BMP regulation has been structured to be similar to the oil SPCC regulation. BMP REGULATORY HISTORY On September 1, 1978, EPA proposed regulations (43 FR 39282) addressing the use of procedures to control discharges from activities associated with or ancillary to industrial manufacturing or treatment processes. The proposed rule indicated how best management practices would be imposed in NPDES permits to prevent the release of toxic and hazardous pollutants to surface waters. The proposed regulation was incorporated as “40 CFR Part 125, Subpart L - Criteria and Standards for Best Management Practices Authorized Under Section 304(e) of the Act” on the August 21, 1978, proposed NPDES regulations (43 FR 37078). A 60-day comment period on proposed Subpart L was provided. After evaluating the comments received on the proposed regulation, EPA revised Subpart L and promulgated the regulation as Subpart K (44 FR 32954-5) on June 7, 1979. Industries regulated by Subpart K were to develop a BMP program and submit the program with their permit application. Subpart K stated that information on the development of BMP programs was contained in a publication entitled “NPDES Best Management Practices Guidance Document.” Subpart K was to become effective on August 13, 1979. However, publication of the report was delayed beyond August 13, 1979. Therefore, on August 10, 1979, EPA deferred applicability of the BMP portions of the NPDES regulations until 60 days after publication in the Federal Register of a notice of availability of the final document (44 FR 47063). EPA announced on March 20, 1980 the availability of the draft report and provided a 45-day comment period (45 FR 17997), which subsequently was extended twice, resulting in a 120-day comment period on the report. Based on public comments on the draft report and 14-13 ------- 160A/Dtsk #1 - 1Of18 , 1 - 1:24 PM further discussion with industry, the Agency revised the draft report and published this guidance document. FINAL BMP REGULATION [ Reserved] FINAL GUIDANCE DOCUMENT [ Reserved] 14-14 ------- 160A/Disk #1 - 10/18/91 - 1:25 PM SECTION II USE OF THE GUIDANCE DOCUMENT This document should be used for guidance in developing BMP plans. The document is not intended to specify site-specific or pollutant-specific BMPs. As its name suggests, the NPDES Best Management Practices Guidance Document is to be considered guidance by NPDES permitting authorities, compliance officers, permit applicants and permittees and should be used in a flexible manner in the formulation of BMP plans. Consequently, the document identifies elements of each specific requirement that should be considered in the development of the BMP plan, but does not require that each element be included in every facility’s BMP plan. In utilizing this document to develop a BMP plan, the applica.nt/permittee is encouraged to use the most cost-effective and innovative techniques to fit the particular facility or circumstances. The format and content of a BMP plan may vary from site to site and industry to industry, depending upon the specific situation. In addition, an applicant/permittee may add, delete, or modify the elements of the specific requirements presented in the document where equivalent results can be attained. If an applicant/permittee needs assistance to develop a BMP plan, he or she may contact the appropriate permit issuing authority for advice. The permitting authority, as necessary, may seek assistance from the Technical Program Development Section of the NPDES Technical Support Branch in Washington, D.C. 14-15 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM SECTION III BMP PLANS SCOPE The activities which are associated with or ancillary to the industrial manufacturing or treatment process are subject to BMPs. For brevity, all such activities are referred to as “ancillary sources.” The ancillary sources at the plant should be examined to determine if there is a reasonable potential for equipment failure (e.g., spillage or leakage), natural conditions (e.g., plant site runoff or drainage from raw material storage), or other circumstances (e.g., sludge or waste disposal) which could result in the discharge of a significant amount of toxic pollutants or hazardous substances to receiving waters. The ancillary sources are divided for discussion in this document into five categories: material storage areas; loading and unloading areas; plant site runoff; in-plant transfer, process, and material handling areas; and sludge and hazardous waste disposal areas. Material storage areas include storage areas for toxic and hazardous chemicals as raw materials, intermediates, final products or byproducts. Included are: liquid storage vessels that range in size from large tanks to 55-gallon drums; dry storage in bags, piles, bins, silos, and boxes; and gas storage in tanks and vessels. Loading and unloading operations involve the transfer of materials to and from trucks or railcars but not in-plant transfers. These operations include pumping of liquids or gases from truck or railcar to a storage facility or vice versa, pneumatic transfer of dry chemicals to or from the loading or unloading vehicle, transfer by mechanical conveyor systems, and transfer of bags, boxes, drums, or other containers from vehicles by fork-lift trucks or other materials handling equipment. Plant runoff is generated principally from rainfall on a plant site. Runoff from material storage areas, in-plant transfer areas, loading and unloading areas, and sludge disposal sites potentially could become contaminated with toxic pollutants and hazardous substances. Heavy metals from sludge disposal sites are of special concern. Fallout, resulting from the plant air emissions which settle on the plant site, may also contribute to contaminated runoff. Contaminated runoff may reach a receiving body of water through overland flow, drainage ditches, storm or noncontact cooling water sewers, or overflows from combined sewer systems. 14-16 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM In-plant transfer areas, process areas, and material handling areas encompass all in- plant transfer operations from raw material to final product. Various operations could include: transfer of liquids or gases by pipelines with appurtenances such as pumps, valves, and fittings; movement of bulk materials by mechanical conveyor-belt systems; and fork-lift truck transport of bags, drums, and bins. All transfer operations within the process area with a potential for release of toxic pollutants and hazardous substances to other than the process waste water system are addressed in this grouping. Sludge and hazardous waste disposal areas are potential sources of contamination of receiving waters. These operations include landfills, pits, ponds, lagoons, and deep-well injection sites. Depending on the construction and operation of these sites there may be a potential for leachate containing toxic pollutants or hazardous substances to seep into groundwater, eventually reaching surface waters, or for liquids to overflow to surface waters from these disposal operations. BMP requirements are not intended to duplicate the requirements of RCRA. Actions taken for compliance with RCRA may be referenced in the BMP plan. MINIMUM REQUIREMENTS BMPs may include some of the same practices used by industry for pollution control, SPCC plans for oil and hazardous substances, safety programs, fire protection, protection against loss of valuable raw materials or products, insurance policy requirements or public relations. The minimum requirements of a BMP Plan are listed in Table 1 and are divided into two categories: general requirements and specific requirements. Table 1. Minimum Requirements of a BMP Plan A. General Requirements 1. Name and location of facility 2. Statement of BMP policy and objectives 3. Review by plant manager B. Specific Requirements 1. RMP Committee 2. Risk Identification and Assessment 3. Reporting of BMP Incidents 4. Materials Compatibility 5. Good Housekeeping 14-17 ------- 160A/Disk #1 - 1O/18, 1 - 1:51 PM 6. Preventive Maintenance 7. Inspections and Records 8. Security 9. Employee Training GENERAL REQUIREMENTS The BMP plan should be organized and described in an orderly narrative format and should be reviewed by the plant engineering staff and plant manager. A description of the facility, including the plant name, the type of plant, processes used, and the products manufactured should be included in the BMP plan. A map showing the location of the facility and the adjacent receiving waters also should be part of the plan. Specific objectives for the control of toxic pollutants and hazardous substances should be included in the statement of corporate policy. SPECIFIC REQUIREMENTS Each of the 9 specific requirements listed in Table 1 should be addressed in the BMP plan. The size and complexity of the BMP plan will vary with the corporate environmental policy, size, complexity, and location of the facility, among other factors. It is anticipated that the length and detail of the BMP plan will be commensurate with the quantity of toxic and hazardous chemicals onsite and their opportunity for discharge. A fundamental concept of the BMP plan is determining the potential for toxic and hazardous chemicals to reach receiving waters and taking appropriate preventive measures. Discussions of the specific requirements are presented on the following pages. Each specific requirement contains important elements that should be considered in developing a BMP plan. All elements may not be applicable to all facilities. Elements should be added, deleted, or modified to fit the needs of a particular facility. Permittees are encouraged to use innovative techniques to achieve equivalent results. 1. BMP Committee The BMP Committee is that group of individuals within the plant organization which is responsible for developing the BMP plan and assisting the plant management in its implementation, maintenance, and updating. Thus, the Committee’s functions are similar to those of a plant fire prevention or safety committee. 14-18 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM The scope of activities and responsibilities of the BMP Committee should include all aspects of the facility’s BMP plan, such as identification of toxic and hazardous materials handled in the plant; identification of potential spill sources; establishment of incident reporting procedures; development of BMP inspection and records procedures; review of environmental incidents to determine and implement necessary changes to the BMP plan; coordination of plant incident response, cleanup and notification of authorities; establishment of BMP training for plant personnel; and aiding interdepartmental coordination in carrying out the BMP plan. Other Committee duties could include review of new construction and changes in processes and procedures at the facility relative to spill prevention and control. The Committee can also periodically evaluate the effectiveness of the overall BMP plan and make recommendations to management on BMP-related matters. Plant management has overall responsibility for the BMP plan . The plan should contain a clear statement of the management’s policies and responsibilities related to BMPs. Authority and responsibility for immediate action in the event of a spill should be clearly established and documented in the BMP plan, with the Committee indirectly involved in that responsibility. The Committee should advise management on the technical aspects of environmental incident control, but should not impede the decisionmaking process for preventing or mitigating spills and incidents. The size and composition of the BMP Committee should be appropriate to the size and complexity of the plant and the specific toxic and hazardous chemicals handled at the plant. Facility personnel knowledgeable in spill control and waste treatment such as environmental specialists, production foreman, safety and health specialists, and treatment plant supervisor should be included. In some small plants, the Committee might consist of the one manager or engineer assigned responsibility for environmental control. For very small facilities, the Committee function might even have to be fulfilled by competent engineers or managers from the corporate staff or the nearest large plant. A list of personnel on the BMP Committee should be included in the BMP plan. The list should have the office and home telephone numbers of the Committee members and the names and phone numbers of backup or alternate people. 14-19 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM Elements of the “BMP Committee,” listed below, should be considered in developing a BMP plan: Inclusion of facility personnel knowledgeable in spill control, safety and health, and waste treatment such as environmental specialists, production foreman, occupational safety and health specialists, and treatment plant supervisor. Responsibility for: — Providing assistance to plant management for developing a BMP plan — Providing assistance to plant management in implementing, maintaining, and updating the BMP plan — Identifying toxic and hazardous substances — Identifying potential spill sources — Establishing BMP incident reporting procedures — Developing BMP inspections and records procedures — Reviewing environmental incidents — Coordinating plant incident response, cleanup, and notification procedures — Establishing BMP training for plant and contractor personnel — Providing assistance for interdepartmental coordination in carrying out the BMP plan — Reviewing new construction and changes in processes and procedures — Evaluating the effectiveness of the BMP plan — Making recommendations to management in support of corporate policy on BMP- related matters. 2. Risk Identification and Assessment The areas of the plant subject to BMP requirements should be identified by the BMP Committee, plant engineering group, environmental engineer, or others in the plant. Each area should be examined for the potential risks for discharges to receiving waters of toxic pollutants or hazardous substances from ancillary sources. Any existing physical means (dikes, diversion ditches, etc.) of controlling such discharges also should be identified. The areas described above should be clearly indicated on a plant plot plan or drawing. A simplified materials flowsheet showing major process operations can be used to indicate the direction and quantity of materials flowing from one area to another. The direction of flow of potential spills and surface runoff could also be estimated based on site topography and indicated on the plant site drawings. Dry chemicals which are toxic pollutants or hazardous substances should be evaluated if they have the potential to reach navigable waters in significant quantities via rainfall runoff, for example. 14-20 ------- l6OAJDisk #1 - 10/18/91 1:51 PM A hazardous substance and toxic chemical (materials) inventory should be developed as a part of the “Risk Identification and Assessment.” The detail of the materials inventory should be proportionate to the quantity of toxic pollutants and hazardous substances on site and their potential for reaching the receiving waters. For example: 1. The plant has determined that materials stored in bulk quantities at a tank farm have a high potential for reaching the receiving waters in the event of structural failure or overfills. Therefore, the materials inventory for the tank farm should be detailed, and should provide the identity, quantifies, and locations of each material. 2. The plant has determined that materials stored in small quantities at the research laboratory have a low potential for reaching the receiving waters. Therefore, the materials inventory for the laboratory could be minimally detailed, and may not include the identity, quantity, or location of each material but might include an estimate of the total quantity of toxic and hazardous materials stored and would provide the location of the laboratory. The rational for the “low risk” nature of the laboratory would be provided in this part of the BMP plan. 3. The plant has determined that materials used in a batch operation in the manufacturing process have a high potential for reaching the receiving water. The plant supplies a variety of products through the batch operation process to accommodate fluctuations in public demand. Consequently, the materials used for the batch process vary from week to week, oftentimes unexpectedly. Therefore, the materials inventory for the batch operation should be detailed but remain flexible. The inventory might include the identification of each material expected for use, and the maximum quantity of material that the batch process can handle. The materials inventory could be updated to include any material substitutions unanticipated at the time of the original inventory. The examples above illustrate the flexibility of the materials inventory. A materials inventory should be part of the “Risk Identification and Assessment” of every BMP plan but the detail of the inventory will vary with the size and complexity of the plant, the quantities of toxic and hazardous chemicals on site and the potential for those materials to reach surface waters. Determining the potential for incidents reaching receiving waters as well as the detail needed for the materials inventory requires sound engineering judgment. The materials inventory and other useful technical information should be made available to the BMP Committee but may require separate filing from the BMP plan documents to protect proprietary information or trade secrets. These data may include physical, chemical, toxicological, and health information (e.g., technical bulletins or material safety data sheets) on the toxic pollutants and hazardous substances handled; the quantities involved in various 14-2 ------- 160A/Disk#I - 10/18/91 - 1:51 PM operations or ancillary sources; and the prevention, containment, mitigation, and cleanup techniques that are used or would be used in the event of a discharge. Materials planned for future use in the plant should be evaluated for their potential to be discharged in significant amounts to receiving waters. Where the potential is high, the same type of technical data described above should be obtained. Elements of “Risk Identification and Assessment,” listed below, should be considered in developing a BMP plan: • Identification of areas of the plant subject to BMP requirements • Examination of identified areas for potential risks of BMP incidents reaching receiving waters • Identification of existing site-specific or pollutant-specific containment measures • Plant plot plans or drawings that clearly label the identified areas • Simplified flowsheet(s) of the major process operations • Estimation of the direction of flow of potential discharges toward navigable waters • Evaluation of the potential for materials planned for future use to be discharged to receiving waters in significant amounts. • Materials inventory system tailored to the need of the particular facility • Physical, chemical, toxicological, and health information on the toxic and hazardous chemicals on site. 3. Reporting of BMP Incidents A BMP incident reporting system is used to keep records of incidents such as spills, leaks, runoff, and other improper discharges for the purpose of minimizing recurrence, expediting mitigation or cleanup activities, and complying with legal requirements. Reporting procedures defined by the BMP Committee should include notification of a discharge to appropriate plant personnel to initiate immediate action; formal written reports for review and evaluation by management of the BMP incident and revisions to the BMP plan; and notification as required by law to governmental and environmental agencies in the event that a spill or other reportable discharge reaches the surface waters. The reporting system should designate the avenues of reporting and the responsible company and government officials to whom the incidents would be reported. A list of names, office telephone numbers, and residence telephone numbers of key employees in the order of 14-22 ------- 160A/Disk #1 - 1O/18 1 - 1:51 PM responsibility should be utilized when necessary for immediate reporting of BMP incidents to plant management for implementation of emergency response plans. A communications system should be designated and available for notification of an impending or actual BMP incident. Reliable communications with the person or persons directly responsible would expedite immediate action and countermeasures to prevent incidents or to contain and mitigate discharged chemicals. Such a communication system could include telephone or radio contact between transfer operations, and alarm systems that would signal the location of an incident. Provisions to maintain communications in the event of a power failure should be addressed. Written reports on all BMP incidents should be submitted to the plant’s BMP Committee and plant management for review. Written reports should include the date and time of the discharge, weather conditions, nature of the materials involved, duration, volume, cause, environmental problems, countermeasures taken, people and agencies notified, and recommended revisions, as appropriate, to the BMP plan, operating procedures, and/or equipment to prevent recurrence. Procedures and key data should be outlined for necessary reporting of BMP incidents to federal, state, and local regulatory authorities. In some circumstances, voluntary reporting to authorities such as municipal sewage treatment works, drinking water treatment plants, and fish and wildlife commissions may be desirable. The plant individuals responsible for notification should be listed. Pertinent telephone numbers should be listed for those individuals in the plant and those in the agencies to be notified. The phone numbers should be reviewed periodically for accuracy and might actually be used in the course of a “spill drill.” Elements of “Reporting of BMP Incidents,” listed below, should be considered in developing a BMP plan: • Maintenance of records of incidents through formal reports for internal review • Notification as required by law to governmental and environmental agencies should an incident occur • Procedures for notifying the appropriate plant personnel and taking preventive or mitigating actions • Identification of responsible company and government officials 14-23 ------- 160A/Disk #1 - 1O/18, 1 - 1:51 PM • A list of names, office telephone extensions, and residence telephone numbers of key personnel • A communications system for reporting incidents in-plant (i.e., telephone, alarms, radio, etc.). 4. Materials Compatibility Incompatibility of materials can cause equipment failure resulting from corrosion, fire, or explosion. Equipment failure can be prevented by ensuring that the materials of construction for containers handling hazardous substances or toxic pollutants are compatible with the containers’ contents and surrounding environment. Materials compatibility encompasses three aspects: compatibility of the chemicals being handled with the materials of construction of the container, compatibility of different chemicals upon mixing in a container, and compatibility of the container with its environment. The specific requirement of materials compatibility in the BMP plan should provide procedures to address these three aspects in the design and operation of the equipment on site handling toxic and hazardous materials. The BMP documentation on materials compatibility should recognize the engineering practices already used in the plant, and should summarize these existing practices with regard to corrosion and other aspects of material compatibility. Specific consideration should be given to procedures and practices delineating the mixing of chemicals and the prohibition of mixing of incompatible chemicals which might result in fire, explosion, or unusual corrosion. Thorough cleaning of storage vessels and equipment before being used for another chemical should be standard practice to ensure that there is no residual of a chemical that is incompatible with the second, or later, chemical to be used. Coatings or cathodic protection should be considered for protecting a buried pipeline or storage tank from corrosion. Where applicable, material testing procedures should be described. Proposed substitutions for currently used toxic or hazardous chemicals should be studied to determine whether the construction materials of the existing containers are compatible with the proposed new conditions. The procedures utilized by the plant or an outside contractor to perform the materials compatibility study should be documented. Materials compatibility aspects of waste disposal which are covered by the RCRA hazardous waste regulations should be referenced in the BMP plan. 14—24 ------- 160A/Disk #1 - 1O/18 1 - 1:51 PM Elements of “Materials Compatibility,” listed below, should be considered in developing a BMP plan: • Evaluation of process changes or revisions for materials compatibility • Incorporation of existing engineering practices for materials of construction, corrosion, and other aspects of materials compatibility • Evaluation of procedures for mixing of chemicals and of possible incompatibility with other chemicals present • Cleansing of vessels and transfer lines before they are used for another chemical • Use of proper coatings and cathodic protection on buried pipelines if required to prevent failure due to external corrosion. 5. Good Housekeeping Good housekeeping is essentially the maintenance of a clean, orderly work environment and contributes to the overall facility pollution control effort. Periodic training of employees on housekeeping techniques for those plant areas where the potential exists for BMP incidents reduces the possibility of incidents caused by mishandling of chemicals or equipment. Examples of good housekeeping include neat and orderly storage of bags, drums, and piles of chemicals; prompt cleanup of spilled liquids to prevent significant runoff to navigable waters, sweeping, vacuuming, or other cleanup of accumulations of dry chemicals as necessary to prevent them from reaching receiving waters; and provisions for storage of containers or drums to keep them from protruding into open walkways or pathways. Maintaining employee interest in good housekeeping is a vital part of the BMP plan. Methods for maintaining good housekeeping goals could include housekeeping inspections by supervisors and higher management; discussions of housekeeping at meetings; and publicity through posters, suggestion boxes, bulletin boards, slogans, incentive programs, and employee publications. Elements of “Good Housekeeping,” listed below, should be considered in developing a BMP plan: • Neat and orderly storage of chemicals • Prompt removal of spillage • Maintenance of dry and clean floors by use of brooms, vacuum cleaners, etc. 14-25 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM • Proper pathways and walkways and no containers and drums that protrude onto walkways • Minimum accumulation of liquid and solid chemicals on the ground or floor • Stimulation of employee interest in good housekeeping. 6. Preventive Maintenance An effective preventive maintenance (PM) program is important to prevent BMP incidents. A PM program involves inspection and testing of plant equipment and systems to uncover conditions which could cause breakdowns or failures with resultant significant discharges of chemicals to receiving waters. The program should prevent breakdowns and failures by adjustment, repair, or replacement of items. A PM program should include a suitable records system for scheduling tests and inspections, recording test results, and facilitating corrective action. Most plants have existing PM programs which provide a degree of environmental protection. It is not the intent of the BMP plan to require development of a redundant PM program. Instead, the objective is to have qualified plant personnel (e.g., BMP Committee, maintenance foreman, environmental engineer) evaluate the existing plant PM program and recommend to management those changes, if any, needed to address BMP requirements. A good PM program should include the following: (1) identification of equipment or systems to which the PM program should apply (2) periodic inspections or tests of identified equipment and systems; (3) appropriate adjustment, repair, or replacement of items; and (4) maintenance of complete PM records on the applicable equipment and systems. The BMP plan documentation on PM may include a list of procedures, examples of recordkeeping, a list of the principal systems to which the PM program is applicable, and directions for obtaining the records for any particular system included or referenced in the BMIP plan. In general, it will be adequate to reference in the BMP plan the scope and location of existing PM procedures and records applicable to the PM specific requirements. Elements of “Preventive Maintenance,” listed below, should be considered in developing a BMP plan: • Identification of equipment and systems to which the PM program should apply • Periodic inspections of identified equipment and systems • Periodic testing of such equipment and systems 14-2 ------- 160A/Disk#1 - 10/18/91 - 1:51 PM • Appropriate adjustment, repair, or replacement of parts • Maintenance of complete PM records on the applicable equipment and systems. 7. Inspections and Records The purpose of the inspection and records system is to detect actual or potential BMP incidents. The BMP plan should include written inspection procedures and optimum time intervals between inspections. Records to show the completion date and results of each inspection should be signed by the appropriate supervisor and maintained for a period of three years. A tracking (follow-up) procedure should be instituted to assure that adequate response and corrective action have been taken. The recordkeeping portion of this system can be combined with the existing spill reporting system in the plant. While plant security and other personnel may frequently and routinely inspect the plant for BMP incidents, these people are not necessarily capable of assessing the potential for such incidents. Thus certain inspections should be assigned to designated qualified individuals, such as maintenance personnel or engineering staff. The inspection and records system should include those equipment and plant areas identified in the “Risk Identification and Assessment” portion of the BMP plan as having the potential for significant discharges. To determine the inspection frequency and inspection procedures, competent environmental personnel should evaluate the causes of previous incidents, and assess the probable risks for incident occurrence. Furthermore, the nature of chemicals handled, materials of construction, and site-specific factors including age, inspection techniques, and cost effectiveness, should be considered. Qualified plant personnel should be identified to inspect designated equipment and plant areas. Typical inspections should include examination of pipes, pumps, tanks, supports, foundations, dikes, and drainage ditches. Records should be kept to determine if changes in preventive maintenance or good housekeeping procedures are necessary. Each of the ancillary sources should have “Inspection and Records” programs designed to meet the needs of the particular facility. Material storage areas for dry chemicals should be inspected for evidence of, or the potential for, windblowing which might result in significant discharges. Liquid storage areas should be inspected for leaks in tanks, for corrosion of tanks, for deterioration of foundations 14-27 ------- l6OAJDisk #1 - 10/18 /91 - 1:51 PM or supports, and for closure of drain valves in containment facilities. Inspections could include the examination of seams, rivets, nozzle connections, valves, and connecting pipelines. Storage tanks should be inspected for evidence of corrosion, pitting, cracks, abnormalities, and deformation and such evidence should then be evaluated. For in-plant transfer and materials handling of liquids, inspections should include visual examination for evidence of deterioration of pipelines, pumps, valves, seals, and fittings. The general condition of items such as flange and expansion joints, pipeline supports, locking valves, catch or drip pans, and metal surfaces, also should be assessed. For loading and unloading operations, inspections during transfer of materials would permit immediate response if an incident occurred. The conditions of pipelines, pumps, valves, and fittings for liquid transfer systems and pneumatic conveying systems used for transferring dry chemicals should be inspected. Inspections (together with monitoring) should be used to ensure that the transfer of material is complete before flexible or fixed transfer lines are disconnected prior to vehicular departure. Before any tank car or tank truck is filled, the lower-most drain valve and all outlets of such vehicles should be closely examined for evidence of leakage and, if necessary, tightened, adjusted, or replaced. Before departure, all tank cars or tank trucks should be closely examined to ensure that all transfer lines are disconnected and that there is no evidence of leakage from any outlet. For plant runoff, inspections should be used for examining the integrity of the stormwater collection system and the diversion or overflow structures, and for ensuring the drain valves and pumps for diked areas are properly closed. The plant sewer and storm sewer system should be periodically surveyed to ensure that toxic and hazardous pollutants are not discharged in significant amounts. Inspections also should include diked areas to ensure that hazardous and toxic chemicals are not discharged from inside diked areas to waterways. Any liquid, including rainwater, should be examined, and where necessary, analyzed, before being released from the diked areas to a receiving water. For sludge and hazardous waste disposal sites, visual inspections should include examinations for leaks, seepage, and overflows from land disposal sites such as pits, ponds, lagoons, and landfills. Other procedures and inspection techniques should be considered on a site-specific basis. Any inspections made or records kept to comply with RCRA may be included in the BMP plan by reference. 14-28 ------- 160A/Disk #1 - 10/18191 - 1:51 PM Elements of “Inspections and Records,” listed below, should be considered in developing BMP plan: Inspection of: — Storage facilities — Transfer pipelines — Loading and unloading areas — Pipes, pumps, valves, and fittings, tank corrosion (internal and external) — Windblowing of dry chemicals — Tank support or foundation deterioration — Seams along drainage ditches and old tanks — Deterioration of primary or secondary containment — Housekeeping — Drain valves on tanks — Damage to shipping containers — Conveying systems for dry chemicals — Integrity of stormwater collection system — Leaks, seepage, and overflows from sludge and waste disposal sites. • Records of all inspections • Tracking procedures to assure adequate response and corrective actions have been taken when inspections reveal deficiencies. 8. Security A security system is needed to prevent accidental or intentional entry to a plant which might result in vandalism, theft, sabotage, or other improper or illegal use of plant facilities that could possibly cause as BMP incident. Most plants have security systems to prevent unauthorized entry leading to theft, vandalism, sabotage, and the like. The BMP plan should describe those portions of the existing security system which ensure that the pertinent chemicals are not discharged to receiving waters in significant quantities. Documentation of the security system may require separate filing from the BMP plan documents to prevent unauthorized individuals from gaining access to confidential information. The BMP Committee, plant security manager, plant engineer, or other qualified plant personnel should evaluate the coverage of the existing security system for those areas of the plant and the equipment identified by the “Risk Identification and Assessment” specific requirement as having the potential for significant discharges. They should recommend to plant management any changes necessary to improve the security system. 14-29 ------- 160A/Disk #1 10/18/91 - 1:51 PM Examples of security measures include: routine patrol of the plant by security guards in vehicles or on foot; fencing to prevent intruders from entering the plant site; good lighting; vehicular traffic control; a guardhouse or main entrance gate, where all visitors are required to sign in and obtain a visitor’s pass; secure or locked entrances to the plant; locks on certain valves or pump starters; and television surveillance of appropriate plant sites, such as plant entrance, and loading and unloading areas. Whenever possible, security personnel should be instructed to observe leaks from tanks, valves, or pipelines while patrolling the plant and also be informed of the procedures to follow when a spill or other discharge is detected. Many plants use contractor or plant security personnel who may not be qualified or may not have time to carry Out such surveillance. In such cases, the surveillance can be incorporated in the “Inspection and Records” specific requirement and should be conducted by production or environmental staff. Elements of “Security,” listed below, should be considered in developing a BMP plan: • Routine patrols of plant by security personnel • Fencing • Good lighting • Vehicular traffic control • Controlled access at guardhouse or main entrance gate • Visitor passes • Locked entrances • Locks on certain drain valves and pump starters • Television monitoring. 9. Employee Training Employee training programs should instill in personnel, at all levels of responsibility, a complete understanding of the BMP plan, the processes and materials with which they are working, the safety hazards, the practices for preventing discharges, and the procedures for responding properly and rapidly to toxic and hazardous materials incidents. Employee training meetings should be conducted at least annually to assure adequate understanding of the objectives of the BMP plan and the individual responsibilities of each employee. Typically, these meetings could be a part of routine employee meetings for safety or fire protection. Such meetings should highlight previous spill events or failures, malfunctioning 14-30 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM equipment components, and recently developed BMP precautionary measures. Training sessions should review the BMP plan and associated procedures. Just as fire drills are used to improve the employee’s reaction to a fire emergency, spill or environmental incident drills may serve to improve the employee’s reactions to BMP incidents. Plants are encouraged to conduct spill drills on a quarterly or semi-annual basis. Spill drills serve to evaluate the employees’ knowledge of BMP-related procedures and are a fundamental part of employee training. Of particular importance is the strong commitment and periodic input from top management to the employee training program to create the necessary climate of concern for a successful program. A plant manger might accomplish more in a brief, face-to-face, appearance than an elaborate, impersonal training program would accomplish. Adequate training in a particular job and process operation is essential for understanding potential discharge problems. Knowledge of specific manufacturing operations and how discharges could occur, or have occurred in the past, is important in reducing human error that can lead to BMP incidents. The training program also should be aimed at maldng employees aware of the protocol used to report discharges and notifying the people responsible for response so that immediate countermeasures can be initiated. In addition, personnel involved in BMP-incident response would be trained to use cleanup materials such as sorbents, gelling agents, foams, and neutralizing agents. As appropriate, they should be educated in safety precautions, in the side effects of the chemicals they are working with, and in possible chemical reactions. Operating manuals and standard procedures for process operations should include appropriate sections of the BMP plan and the spill control program and should be readily available for reference. Spill response drills, suggestion boxes, posters, and incentive programs, can be used to motivate employees to be alert to the potential for discharges and to their prevention. The employee training program should include records of the frequency, and names and positions of the employees trained as well as the lesson plans, subject material covered, and instructors’ names and positions. BMP-related training may be combined with other forms of training, such as safety and fire prevention at the discretion of the plant. 14-31 ------- 160A/Disk #1 10/18/91 - 1:51 PM In addition to permanent personnel, contractors or temporary personnel should be trained in procedures for preventing BMP incidents since these individuals may be unfamiliar with the normal operating procedures or location of equipment (pipelines, tanks, etc.) at the facility. Adequate supervision of contractor maintenance personnel should be provided to minimize the possibility of BMP incidents resulting from damaging equipment such as buried pipelines. Elements of “Employee Training,” listed below, should be considered in developing the BMP plan: • Meetings held at least annually to assure adequate understanding of program goals and objectives • Environmental Incident (Spill) drills used at least semiannually • Periodic input from management • Adequate training in particular job and process operation and the effect on other operations • Transmission of knowledge of past incidents and causes • Making employees aware of BMP plans and incident reporting procedures • Training in the use of sorbents, gelling agents, foams, and neutralizing agents for cleanup or mitigation of incidents • Operating manuals and standard procedures • Making employees aware of health risks of chemicals handled through both the plant’s BMP plan and safety program • Motivating employees concerning incident prevention and control • Records of the personnel who were trained, and of the dates, instructors, subject matter, and lesson plans of the training sessions • Training and supervision of contractors and temporary personnel. 14-32 ------- 160A/Disk #1 - 10/18/91 - 1:51 PM BIBLIOGRAPHY TECHNICAL GUIDANCE ON BMPs IN THE NPDES PROGRAM Form of Guidance Title Date Technical Paper Best Management Practices for Control of Toxic and 5iW79 Hazardous Materials; Thron, H.M. et al., presented at the 34th Purdue Industrial Waste Conference, Lafayette, Indiana Report EPA No. NPDES Best Management Practices Guidance Document; 12/79 600/9-79-045 Hydroscience Inc., EPA Contract Number 68-03-2568 Report NPDES Best Management Practice Guidance Document 6/81 (Revised); NPDES Technical Support Branch Technical Paper Best Management Practices; Useful Tools for Cleaning Up, 4120/82 Thron, H.M. and Rogoshweski, P.J., presented at the 1982 Hazardous Material Spills Conference, Milwaukee, Wisconsin Case Histories NPDES Best Management Practices; Case Histories; JRS 1129/83 Associates, Inc., EPA Contract Number 68-01-5052 Technical Technical Guidance on Best Management Practices (BMPs) 4/15/83 Memorandum No. 1 in NPDES Permits; Jordan, J.W. to Regional Permit Branch Chiefs Technical Technical Guidance on Best Management Practices (BMPs) 3i23/84 Memorandum No. 2 in NPDES Permits; Jordan, J.W. to Regional Permit Branch Chiefs Information Best Management Practices (BMPs) in NPDES Permits; 6/3/85 Memorandum Grubs, Geoffrey to Regional Permit Branch Chiefs Information Best Management Practices (BMPs) in NPDES Permits; 8129/86 Memorandum Gallup, James to Regional Permit Branch Chiefs Information Best Management Practices (BMPs) in NPDES Permits; 8/11/87 Memorandum Gallup, James to Regional Permit Branch Chiefs Information Best Management Practices (BMPs) in NPDES Permits; 8/19/88 Memorandum Gallup, James to Regional Permit Branch Chiefs 14-33 ------- PART LV Permit No. VA 0005215 Page 1 of 3 BEST MANAGE NT PRACTICES CONDITIONS A. General Condjtjo 1. BMP Plan For purposes of this part, the terms “pollutant” or “pollutants” refer to any substance listed as toxic under Section 3 0 7 (a)(j) of the Clean Water Act, oil, as defined in Section 3 11(a)(1) of the Act, and any substance listed as hazardous under Section 311 of the Act. The permittee shall develop and implement a Best Management Practices (BMP) plan which prevents, or minimizes the Potential for, the release of pollutants from ancillary activities, including material storage areas; plant site runoff; in—plant transfer, process and material handling areas; loading and unloading operations, and sludge and waste disposal areas, to the waters of the United States through plant site runoff; spillage or leaks; sludge or waste disposal; or drainage from raw material storage. 2. Implementation The plan for General Conditions shall be developed within 12 months of the effective date of this permit. An approval plan for General Conditions shall be implemented within 24 months of the effective permit date. Specific Conditions of this plan shall be implemented within 24 months of the effective permit date. 3. General Requirements The BMP plan shall: a. Be doc .nnented in narrative form, and shall include any necessary plot plans, drawings or maps. b. Establish specific objectives for the control of pollutants. (1) Each facility component or system shall be examined for its potential for causing a release of significant amount of pollutants to waters of the United States due to equipment failure, improper operation, natural phenomena such as rain or snowfall, etc. (2) Where experience indicates a reasonable potential for equipment failure (e.g., a tank overlfow or leakage), natural condition (e.g., precipitation), or other circumstances to result in significant amounts of pollutants reaching surface waters, the plan should include a prediction of the direc- tion, rate of flow and total quantity of pollutants which could be discharged from the facility as a result of each condition of circumstance. c. Establish specific best management practices to meet the objectives identified under paragraph b of this section, 14-34 ------- PART IV Permit No. VA 0005215 Page 2 of 3 addressing each component or system capable of causing a release of significant amounts of pollutants to the waters of the United States, -and identifying specific preventative or remedial measures to be implemented. d. Include any special conditions established in Section B of this Part. e. Be reviewed by plant engineering staff and the plant manager. 4. Documentation The permittee shall maintain a description of the BMP plan at the facility and shall make the plan available to the permit is8uing authority upon request. 5. BlIP Plan Modification The perinittee shall amend the BlIP plan whenever there is a change in the facility or change in the operation of the facility which materially increases the potential for the ancillary activities to result in a discharge of significant amounts of pollutants. 6. Modification for Ineffectiveness If the BMP plan proves to be ineffective in achieving the general objective of preventing the release of significant amounts of pol- lutants to surface waters and the specific objectives and requirements under paragraphs b and c of Section 3, the permit and/or the BlIP plan shall be subject to modification to incorporate revised BlIP require- ments. B. Specific Conditions The following Specific Conditions shall be implemented within 12 months of the effective date of the permit. 1. Measures shall be taken to control potential discharges at the folloving sites: Building 1341 — Provide containment for freon and hydrochloric acid tanks Incinerator — Direct quench recycle overflow to a treatment facility Building 1329 — Control spills at the acid cleaning facility St. Juliens Building 332 — Control spills from drummed liquids. Implement controls to ensure proper operation of the oil transfer valve (Ply) 14-35 ------- 1 1 ------- PRACTICAL EXERCISE Best Management Practices (BMPs) (1) What are the two basic ways that BMPs appear in NPDES permits? (a) (2) What is the legal authority for imposing BMPs in permits considering the fact that no BMPs have been promulgated for specific .r dustries pursuant to Section 304(e) of the Clean Water Act? _____________________________ (3) GIVEN TUE FOLLOWING SITUATION : Luster Glass Inc. manufactures auto tempered and laminated glass in Morris, Illinois. A recent compliance inspection revealed storage tank number 42 containing 12,000 gallons of gasoline was leaking into the Illinois River. The State compliance inspector, I. M. Curious, also noticed generally poor housekeeping at Luster, including retired pumps and miscellaneous pipes and fittings scattered throughout the plant area, unidentified solid and liquid spills on roadways and a storage area near the stream bank consisting of about fifty, S5 gallon drums in various positions and states of deterioration. When questioned about the nature and contents of the drums by the State compliance inspector, the Luster plant manager, Wood U. Leave, replied, “They’re some old supplies we discontinued.., some contain.. . nitric acid or some other acid. . . (cough cough)... how about some lunch Mr. Curious?” As he was abruptly spun 180 degrees by Mr. Leave, Mr. Curious managed to scribble a note at the bottom of his inspection report “may be a candidate for BMPs in reissued permit.” DETERMINE : You are the permit writer assigned to draft Luster Glass Inc. s NPDES permit. After reading the compliance inspection report, you sketch your approach for using BMPs in the reissued permit: BMP Plan — Conditions at the facility, especially poor housekeeping, warrant a BMP plan to be developed within six months and implemented within twelve months of permit reissuance. The SM? ?lan should address each of the nine specific requirements described in the June 1981, N?DES BMP Guidance Document with emphasis on _________________________________ Site—Specific BMPs (1) Tank Number 42 : _______________ (2) Drum Storage Area : ____________ 14-37 ------- POLLUTION PREVENTION ------- LEARNING OBJECTIVES • Orientation to Pollution Prevention • Implementation • Tools and Resources NOTES: 15—1 ------- HIERARCHY OF ENVIRONMENTAL PROTECTION PRACTICES • Source reduction • Environmentally sound reuse and recycling • Treatment • Disposal NOTES: J 52 ------- POLLUTION PREVENTION ACT 1990 “Source reduction means any practice which reduces the amount of any hazardous substance, pollutant or contaminant entering any waste stream or released into the environment prior to recycling, treatment or disposal . . . EPA POLICY STATEMENT Pollution prevention is the “Use of processes, practices, or products that reduce or eliminate the generation of pollutants and wastes, including those that protect natural resources through conservation - or more efficient utilization.” NOTES: 15-3 ------- LEGISLATIVE AUTHORITIES AFFECTING THE LIFE CYCLE OF A CHEMICAL SARA SARA “CA ___ Fesdstocks — . - Underground — --- - (RCRA) W at — — —- -:_-_-_-_- _-_ 1 SDWA 1i Industrial Products OSHA, FIFRA Consumer Products (RCRA) CPSA, FFDCA, FIFRA (RCRA) ClssnAlrAct • Consumer Product Safety Act • Clean Water Act • Federal Food, Diug & Cosmetic Act Federal insecticide, Fungicide & Rodenticide Act • Hazardous Materials Trsnspoiiatlon Act • Occupational Safety & Heafth Act • Resource Sonservstlon & Recovery Act • Safe Drinking Water Act • Toxic Substances Conttol Act • Superfund Amendments & Reauthorization Act Tanks W W WdW CWA ______ •KEY. CAA cP$A CWA FFDCA F1FRA HUTA OSHA RCRA SDWA TSCA SARA 15-4 ------- POLLUTION PREVENTION OPPORTUNITIES IN THE NPDES PERMITTING PROCESS • Application review • Site visit • BMP plan requirement • Monitoring conditions NOTES: 15-5 ------- PERMIT ISSUANCE PROCEDURES ------- The issuance process Documenting development EPA/State coordination Public participation Permit appeals Modification/termination S LEARNING OBJECTIVES . S S S NOTES: 16-i ------- COMMON ELEMENTS OF THE ISSUANCE PROCESS Permit Application Filed _______1 Site Visit Conducted Permit Appealed H Judicial Review Permit Issued (Process Repeats Itself) Additional Data Requested Draft Permit Publicly Noticed Application Review for Completeness and Accuracy Permit Denied; or Permit Limits Drafted and Other Conditions Developed Draft Permit Reviewed by Applicant Comments Considered and Draft Permit Revised CompliancelMonitoring - Enforcement During Effective Period of Permit Permit Renewal Application Filed 16-2 ------- CONTENTS OF ADMINISTRATIVE RECORD • Application and supporting data • Draft permit • Statement of basis or fact sheet • Items cited in statement of basis or fact sheet • Other items supporting permit development NOTES: 16-3 ------- CONTENTS OF THE ADMINISTRATIVE RECORD A brief explanation follows of the xpress statutoiy or reguiatory precision on which permit requirements are based, induding appropriate supporting references to the Administrative Record reqwred by 40 CFR S 124.9: The following items are used to establish the basis of the draft permit: (1) NPDES Permit No. LA0002933, effective date 2/17/80, expiration date 3/31/81. (2) Consolidated Permit Application Forms No. 1 and 20 received 4/3/82. (3) Louisiana Water Quality Criteria, LSCC, 1977. 4) Louici np Water Quality Management Plan, Department of Natural Resources, induding Appendix D (Ponchartrain Basin) and Appendix F kci cc ppi River), Phase [ 1, Vols. 1. (5) 40 CFR Part 415 Subpart F, [ 47 28260, 6/29/83J. (6) 40 CFR Part 415.65(b) [ 39 f , X16, 3/12/74]. (7) Letter White (EPA) to Viacos (Vulcan) dated 3/29/76. (8) Letter White (EPA) to Campbell (Vulcan) DAted 6/9/76. (9) ROC Hale (EPA) to Leonard (Vulcan) dated 11/10/76. (10) 4OCFR Part 122.29 (d)(1) [ 48fE, 14146, 4/1/831. (11) Letters Gordon (Vulcan) to McHam (EPA) dated 5/17/82 and 7/19/82. (12) 40 CFR Part 401.17,6/4/82. (1.3) Letters Gordon (Vulcan) to Hale (EPA) dated 1/30/81. (14) Discharge Monitoring Reports 1980-1982. (15) 40 CFR Part 1.22.62(a)(3) [ 48 fE 14146,4/1/83]. (16) 40 CFR Part 122.44(1)(2)(1) [ 48 fE 1 14146, 4/1/83). (17) 40 CFR Part 413.65(b) [ 47 fE 28260,6/29/82). (18) 40 CFR Part 415.62(b) [ 47 f , 28260,6/29/82]. :19) Final Development Document for Inorganic Chemicals, EPA 440/1-82/0c17, June 1982. (20) Letter Gordon (Vulcan) to Ferguson (EPA) dated 10/30/79. (21) 40 CFR Part 125.3(a)(2)(v) [ 44 32948,6/7/89, as amended at 45EE, 33512, 5/19/80). (22) 40 CFR part 413.63(b) [ 47 f 28260,6/29/82). (23) 40 CFR Part 1.fl.29(d)(2) [ 48 EE 14146,4/1/83]. (24) 40 CFR Part 141.12 [ 40 fE, 59570,12/24/75, as amended at 44 f 68641, 11/29/79. (25) Preamble to Inorganic Chemical Effluent Limitations Guidelines 47 f 28263,6/29/82, Column 3]. (26) ROC McHam (EPA) to Gordon (Vulcan) dated 5/25/83. (27) EPA Treatability Manual, EPA 600/2-82/001, September 1982 (Revised). (28) Work Book for Determining Economic Achievabilitv for NPDES Permits : prepared for Hap Thron, Permits Division; prepared by Purn, m . Hayes & Bartlett; Inc . August 1982. (29) Moody’s Industrial Manual . 1982, pp. 4602-4605 (30) CE Plant Cost Index . Chemical Engineering Magazine, 6/1.3/83, page 7. 16-4 ------- REASONS FOR GOOD DOCUMENTATION • Streamlines reissuance/compliance-monitoring process • Permanent record of the basis for the permit • Explanation of basis of permit for public, management, permittee, and attorneys, if appealed • Provide sound basis for modifications and future permits • Requires permit writer to be organized and logical, resulting in better permits ELEMENTS OF A GOOD FACT SHEET • Identify party being permitted • Bring forward background and history of permit • Develop rationale for all pertinent permit decisions • Display all calculations and document sources of data • Keep accessible to permitting authority personnel and the public NOTES: 16—5 ------- SUGGESTED OUTLINE FOR A FACT SHEET A. Reason for permit B. Basic facility information C. Draft permit effluent limitations and conditions 1. Specific comments: a. Discuss each pollutant limited by permit 1. Flow 2. BOD 5 3. pH 4. Ammonia 5. Metals 6. Others D. Monitoring conditions 1. Reason for type and frequency 2. Analytical methods 3. Reporting frequency E. Special conditions 1. Compliance schedules 2. Additional monitoring 3. BMP requirement NOTES: 16-6 ------- NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) PERMIT FACT SHEET Perinittee Name: Luster Glass, Inc. NPDES Permit Number: 1L0654321 Mailing Address: P.O. Box 319 Morris, IL 60123 Location: 1 River Ridge Drive Morris, IL 60123 Contact Person: Mr. John Baker, Vice President Telephone: (312) 834—4536 I. Status of Permit NPDES Permit No. 1L0654321 was issued on August 5, 1984, became effective on August 31, 1984, and expired on August 31, 1989. The permittee submitted art NPDES permit application for the renewal of the permit on March 1, 1989. II. Facility Description Luster Glass Inc. operates a manufacturing facility in Morris, IL. The facility specializes in manufacturing auto glass. On average, 40,000 sq. ft./day of auto tempered glass, and 275,000 sq. ft./day of auto laminated glass is produced at the facility. III. Description of Discharge All wastewater generated at this facility is discharged through Outfall 001 to the Illinois River. The primary waste streams discharged through Outfall 001 are process and rinse waters from the glass manufacturing processes and cooling tower blowdown. The glass manufacturing process wastewaters from auto glass tempering (cutting, grinding, polishing edges, bending, and tempering) and auto glass lamination (cutting, bending, washing, and laminating) are routed through a wastewater treatment system consisting of oil and water separators and settling basins. The cooling tower blowdown is not treated prior to discharge. IV. Receiving Water The receiving water for Outfall 001 is the Illinois River, Segment 16 of the Northern Illinois River Basin. Downstream of the facility, the Illinois River flows approximately 3 miles to Segment 15 of the Northern Illinois River Basin. Following is a summary of flow data for Segment 16 of the Illinois River: 16-7 ------- Fact Sheet Page 2 of 21 Average Flow - 446.7 cfs Harmonic Mean Flow — 245.5 cfs 7Q 10 — 70.9 cfs 1Q10 — 58.8 cfs The use designations for the Illinois River are given below: Indigenous Aquatic Life The applicable water quality standards to protect these uses are specified the State Water Pollution Control Rules in Part 302 (State Administrative Code, Title 35 — Environmental Protection; Subtitle C — Water Pollution, Chapter 1; adopted March 17, 1989). The effluent standards are found in Part 304. V. Description of Discharge a. Permit Application Summary The following table summarizes the discharge characteristics of Outfall 001 as reported in the NPDES permit application dated March 1, 1989: Long-Term Daily Parameter Average Maximum Flow (MCD) 4.563 4.591 TSS (mg/i) 18.8 50.0 COD (mg/i) ND 50.0 pH (S.U.) 6.6 mm. 9.0 max. Oil & Grease (mg/l) 12 22 Phosphorus (lbs/day) 19 29 Zinc (mg/i) 0.036 0.07 Lead (mg/i) 0.025 0.047 Note: Only data for parameters reported above detection limits are shown above. b. Discharge Monitoring Report (DMR) Data A summary of DMR data is given in Table 1. This data was taken from March 1988 through February 1989. Whole Effluent Toxicity (WET) testing performed during the last year of the permit term (March 1988 to February 1989) demonstrated acute toxicity at Outfall 001. Test results indicated a fathead minnow LC5O of 8 percent and a Ceriodaphnia LC5O of 15.8 percent. Chronic Toxicity tests also demonstrated toxicity at Outfall 001. Chronic toxicity test results indicated a fathead minnow NOEC of 1.3 percent and a Ceriodaphnia NOEC of 2.7 percent. A summary of WET data for Luster is also presented in Table 1. 16-8 ------- Fact Sheet Page 3 of 21 VI. Proposed Technology-Based Effluent Limitations Regulations promulgated at 40 CFR §122.44(a) require technology— based effluent limitations to be placed in NPDES permits based on National effluent limitations guidelines and standards, best professional judgement (BPJ), or a combination of the two. Discharges from Outfall 001 are subject to effluent limitations given in 40 CFR Part 426 for the Glass Manufacturing Point Source Category, and State effluent and water quality standards. Limits were developed for Luster Glass Inc. based on an evaluation of the permit application and DMRs. Lead and zinc were detected in significant concentrations in the discharge as reported in DMRs. While the previous permit did not contain limits for lead and zinc, monitoring was required. Thus, technology-based effluent limits were set for zinc found in the cooling tower blowdown. Technology— based limits were also established for lead which is found in the process wastewater, however water quality-based limits were found to be more limiting (see Section VII of this Fact Sheet). Effluent mass limits for total suspended solids (TSS), phosphorus, and oil and grease are based on the best practicable control technology currently available (BPT) limitations specified for the Automotive Glass Tempering Subcategory in 40 CFR S426.62 and for the Automotive Glass Laminating Subcategory in 40 CFR §426.72. These limitations are shown below: Automotive Glass Tempering Subcategory Effluent Limits Monthly Av . Daily Max. Pollutant ( lb/l000ft ) ( 1b/1000ft 2 TSS 0.25 0.40 Oil and Grease 0.13 0.13 pH shall be within the range of 6.0 to 9.0 standard units. Automotive Glass Laminating Subcategory Effluent Limits Monthly Avg. Daily Max. Pollutant ( lb/l000ft 2 ) ( lb/ l000ft 2 ) TSS 0.90 0.90 Oil and Grease 0.36 0.36 Phosphorus 0.22 0.22 pH shall be within the range of 6.0 to 9.0 standard units. 16-9 ------- Fact Sheet Page 4 of 21 Effluent limitations for oil and grease, TSS, phosphorus, and pH from the process wastewater contribution to Outfall ooi are calculated using the above effluent limits and the production rates of 40,000 square feet per day of tempered glass and 275,000 square feet per day of laminated glass. The TSS effluent limitations for cooling tower blowdown are based on State Effluent Standards for TSS in non-process wastewaters, including cooling tower blowdown. Calculations of the effluent limitations are shown below. It should be noted that both mass and concentration limits will be applied to Outfall 001 for oil and grease, TSS, and phosphorus. Oil and Grease Mass Limitations (Monthly Average and Daily Maximum) Oil & Grease = (40,000 ft 2 /day (tempered) x 0.13 lb/bOo ft 2 ) + (275,000 ft 2 /day (laminated) x 0.36 lb/boo ft 2 ) = 5.2 + 99 = 104.2 lbs/day Concentration Limitations - Outfall 001 (Monthly Average and Daily Maximum) Oil & Grease = (104.2 lbs/day) (454 g/ 1 lb) (1000 mg/ 1 g) (1 gal/ 3.785 1) (1 day/ 4.563 106 gal) = 2.74 mg/i TSs Mass Limitations - Process Wastewater (Monthly Average) T = [ (40,000 ft 2 /day (tempered) x 0.25 lb/bOO ft 2 ) + (275,000 ft’ ay (laminated) x 0.9 lb/bOO ft 2 )]/l000 = 257.5 lbs/day Mass Limitations — Process Wastewater (Daily Maximum) TSS = [ (40,000 ft 2 /day (tempered) x 0.4 lb/bOo ft 2 ) ÷ (275,000 ft 2 /day (laminated) x 0.9 lb/bOO ft 2 ))/1000 = 263.5 lbs/day Mass Limitations - Cooling Tower Blowdown (Monthly Average) TSS = (25 mg/i) (0.45 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 93.8 lbs/day Mass Limitations - Cooling Tower Slowdown (Daily Maximum) TSS = (50 mg/l) (0.45 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 187.6 lbs/day Mass Limitations - Outfall 001 (Monthly Average) TSS = 257.5 lbs/day + 93.8 lbs/day = 351.3 lbs/day 16-10 ------- Fact Sheet Page 5 of 21 Mass Limitations - Outfall 001 (Daily Maximum) TSS = 263.5 lbs/day + 187.6 lbs/day = 451.1 lbs/day Concentration Limitations - Outfall 001 (Monthly Average) TSS = (351.3 lbs/day) (454,000 mg/lb)(l gal/3.785 l)(day /4.563 106 gal) = 9.23 mg/i Concentration Limitations - Outfall 001 (Daily Maximum) TSS = (451.1 lbs/day) (454,000 mg/lb) (1 gal/3.785 1) (day /4.563 106 gal) = 11.86 mg/i PhosDhorus Mass Limitations — Outfall 001 (Monthly Average and Daily Maximum) Phosphorus = 275,000 ft 2 /day (laminated) x 0.06 lb/bOO ft 2 ) = 16.5 lbs/day - Concentration Limitations - Outfall 001 (Monthly Average and Daily Maximum) Phosphorus = (16.5 lbs/day)(454,000 mg/ib)(1 gal/3.785 1)(day /4.563 106 gal) = 0.43 mg/i pH limits are based on State effluent standards, as follows: State Effluent Standards Monthly Avg. Daily Max. Pollutant/Parameter Range ( mg/i) ( Tng/1 ) pH 6.0 — 9.0 N/A N/A 16-11 ------- Fact Sheet Page 6 of 21 Toxic Pollutants Zinc and lead were detected in the effluent discharge when the previous permit was issued. At that time no limits were set, but a requirement was made to monitor for zinc and lead. Significant concentrations of zinc (used as a corrosion inhibitor in cooling water) and lead (from lead soldering of products) have been found, as reported in DMRs. Therefore, technology—based effluent limitations are being established and will be included in the draft permit. Technology-based effluent limitations for the toxic pollutant zinc present in the cooling tower blowdown are based on the transfer of the best available technology economically achievable (BAT) limitations specified in the Steam Electric Effluent Guidelines and Standards at 40 CFR §423.13(d)(1). These limitations are shown below: BAT Effluent Limitations Monthly Avg. Daily Max. Pollutant ( mg/U ( mg/U Zinc (total) 1.0 1.0 Using the average blowdown flow from the cooling towers (0.45 mgd), monthly average and daily maximum mass limitations are calculated as follows: Zinc = (1.0 mg/i) (0.45 106 gal/day) (1 lb/454,000 xng)(3.785 1/gal) = 3.75 lbs/day Equivalent end-of-pipe concentration effluent limitations are also being established in the draft permit. Using the total Outfall 001 flow (4.563 mgd), monthly average and daily maximum concentration limitations are calculated as follows: Zinc = (3.75 lbs/day) (454,000 mg/lb) (1 gai/3.785 1) (day /4.563 106 gal) = 0.10 mg/i Technology-based effluent limitations for lead found in the process wastewaters are based on transfer of BAT limitations specified in the Metal Finishing Effluent Guidelines and Standards at 40 CFR §433.14(a). These limitations, which are based on the performance of lime precipitation and sedimentation, are shown below. BAT Effluent Limitations Monthly Avg. Daily Max. Pollutant ( mg/i) ( mg/i ) Lead (total) 0.43 0.69 16—12 ------- Fact Sheet Page 7 of 21 Due to the potential for dilution of the treated process wastewaters by the cooling tower blowdown wastewaters, both mass and concentration limitations are established. Using the average process flow (4.113 mgd), mass limitations are calculated as follows: Monthly Average Lead = (0.43 mg/i) (4.113 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 14.74 lbs/day Daily Maximum Lead = (0.69 mg/i) (4.113 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 23.66 lbs/day Equivalent end—of-pipe concentration effluent limitations are also being established in the draft permit. Using the total Outfall 001 flow (4.563 mgd), concentration limitations are calculated as follows: - Monthly Average Lead = (14.74 lbs/day) (454,000 rng/lb) (1 gal/3.785 1) (day /4.563 106 gal) = 0.38 mg/l Daily Maximum Lead = (23.66 lbs/day) (454,000 mg/lb) (1 gal/3.785 1) (day /4.563 106 gal) = 0.62 mg/l VII. Proposed Water Oualjty-Based Effluent Limitations The State water quality standards require that point source discharges shall not cause a violation of any applicable water quality standards nor interfere with the attainment or maintenance of that water quality which assures the protection and propagation of a balanced indigenous population of shellfish, fish, and wildlife and allows recreational activities in and on the water. In addition, a requirement of the State water quality standards is that no effluent shall, alone or in combination with other sources, cause a violation of any applicable water quality standard. Temperature Temperature limits are based on State water quality standards as follows: 16-13 ------- Fact Sheet Page 8 of 21 State Water quality Limits Pollutant/parameter Range Temperature Not greater than 2.8°C above ambient, or 1.7°C above the following maximum limits: in December through March, 16°C (60°F) and in April through November, 32°C (90°F) Toxic Pollutants Based on evaluation of the NPDES permit application and DMR data submitted by Luster Glass Inc., the following pollutants and parameters for which applicable State water quality standards are available are present in Outfall 001: lead and zinc. Based on the fact that no other toxic pollutants are expected to be present in Outfall 001 at significant concentrations, evaluation for compliance with water quality standards will only be performed for lead and zinc. The State water quality regulations require that water quality standards be achieved under the following critical receiving water flow conditions: Chronic water quality standards: 7 day, 10 year return frequency flow (7Q10) Acute water quality standards: One-third (1/3) of the 7Q] .0 flow The 7QlO for the Illinois River is 70.9 cubic feet per second (Cf s) The facility provided a study of the outfall which showed that the outfall quickly achieved complete mixing across the width of the river. Dilution at the edge of the mixing zone can therefore be characterized by the complete mixing equation: Cr = (Cd) (Qd) + (Cs) (Qs) (Qd + Qs) where Cr = the receiving water concentration, Cd = the effluent concentration, Qd = the effluent flow, Cs = the receiving water background concentration, and Qs = the appropriate receiving water flow. The receiving water concentrations (Cr) expected in the Illinois River are calculated using the equation described above, and the following data: 16-14 ------- Fact Sheet Page 9 of 21 Effluent Receiving Water Concentration (Cd)* Concentration (Cs)** Pollutant ( mg/i) ( mg/i ) Lead 0.38 0 Zinc 0.2]. 0.07 * - Maximum daily concentration reported in the application Form 2C ** - Source U.S.G.S. STORET For comparison with acute water quality standards, receiving water concentrations are calculated as follows: Cr (lead) = ((0.38 mg/i) (7.06 cfs) + (0mg/i) (23.6 cfs))/(7.06 cfs + 23.6 cfs) = 0.088 mg/i Cr (zinc) = ((0.21 mg/i) (7.06 cfs) + (0.07 mg/i) (23.6 cfs)]/(7.06 cfs + 23.6 cfs) = 0.102 mg/i For comparison with chronic water quality standards, receiving water concentrations are calculated as follows: Cr (lead) = ((0.38 mg/i) (7.06 cfs) + (0mg/i) (70.9 cfs))/(7.06 cfs + 70.9 cfs) = 0.034 mg/i Cr (zinc) = [ (0.21 mg/i) (7.06 cfs) + (0.07 mg/i) (70.9 cfs)]/(7.06 cfs + 70.9 cfs) = 0.083 mg/i The foliowing table compares each receiving water concentration calculated above with the State Water Quality Standard for aquatic life protection: State Receiving Water Standard Concentration Pollutant jjig/l) ( hg/i) Zinc Chronic 110 83 Acute 120 102 Lead Chronic 3.2 34 Acute 82 88 16—15 ------- Fact Sheet Page 10 of 21 Since the calculated receiving water concentrations are less than the criterion for zinc and greater than the criterion for lead, water quality limits will be necessary for lead, but not for zinc. It should be noted that the procedure used above does not account for the variability of the pollutant concentrations in the effluent. The EPA Technical Support Document for Water Quality- based Toxics Control recommends accounting for this variability by calculating the reasonable potential for pollutants to cause exceedances of water quality standards. Specifically, the reasonable potential is calculated using the maximum expected effluent concentration, which is estimated by using a multiplication factor (F) that incorporates both the coefficient of variation (CV) and the number of effluent samples collected. If this methodology were used with the existing data for Luster Glass, Inc., there would be a reasonable potential for the concentration of zinc in the discharge to exceed both the acute and chronic water quality standards, and thus water quality permit limits will also be calculated for zinc. The following equation is used to calculate the effluent concentrations [ which is commonly referred to as the waste load allocation (WLA)] for lead and zinc that will ensure protection of the State water quality standard. Cd = WLA = Cr (Qd + Qs) - (Cs) (Qs) Qd where Cd = WLA = waste load allocation Cr = the applicable water quality standard Qd = the effluent flow = 7.06 Cf s Qs = the appropriate receiving water flow Cs = the receiving water background concentration Based on the following information, the waste load allocations for lead and zinc are calculated. Cr = Acute State Water Cs Upstream Pollutant quality Standard Concentration Lead 0.082 mg/i o mg/i Zinc 0.12 mg/i 0.07 mg/i Cr = Chronic State Water Cs = Upstream Pollutant Quality Standard Concentration Lead 0.0032 mg/i 0 mg/l Zinc 0.11 mg/i 0.07 mg/l 16-16 ------- Fact Sheet Page 11 of 21 Lead (acute) Cd = [ (0.082 mg/l)(7.06 cfs + 23.6 cfs) — (0 mg/i) (23.6 cfs) ] / 7.06 cfs = 0.36 mg/i Lead (chronic) Cd = ((0.0032 mg/1)(7.06 cfs + 70.9 cfs) — (0 mg/i) (70.9 cfs)]/ 7.06 cfs = 0.04 mg/i Zinc (acute) Cd = ((0.12 lng/i)(7.06 cfs + 23.6 cfs) — (0.07 mg/i) (23.6 cfs)] / 7.06 cfs = 0.29 mg/i Zinc (chronic) Cd = ((0.11 mg/l)(7.06 cfs + 70.9 cfs) — (0.07 mg/i) (70.9 cfsfl/ 7.06 cfs = 0.51 mg/i Given that all State water quality standards are expressed as never to be exceeded (i.e., water quality-based limits must be protective of the most stringent waste load allocation), a maximum daily limitation (MDL) and a average monthly limitation (ANL) for lead and zinc are calculated using the waste load allocations calculated above. It should be noted that the ratio of daily maximum to monthly average for the technology-based effluent limitations for lead and zinc are used to derive the MDL and ANL. Specifically, these ratios are 1.6 for lead and 1.0 for zinc. Lead - Since the chronic WLA is more limiting than the acute WLA (i.e., 0.04 mg/i < 0.36 mg/i), it will be used as the basis for limitations. Since the chronic WLA can never be exceeded, 0.04 mg/i is used as the MDL. The AML is calculated as follows: 0.04 mg/i _________ = 0.03 mg/i 1.6 Zinc — Since the acute WLA is more limiting than the chronic WLA (i.e., 0.29 mg/i < 0.51 mg/i), it will be used as the basis for iimitatjons. Since the acute WLA can never be exceeded, 0.029 mg/i is used as the MDL. The ANL is calculated as follows: 0.29 mg/i __________ = 0.29 mg/i 1.0 Comparing the chemical specific water quality-based limits calculated above with the technology-based effluent limitations calculated for Outfall 001 (see Section VI above), the water quality-based limits for lead are more stringent than the technology—based limits, so they will be used as the basis for effluent limits in the permit. Since the technology—based effluent limits for zinc are more stringent than the water quality-based 16-17 ------- Fact Sheet Page 12 of 21 limits, the technology-based effluent limits will be used. Equivalent end—of—pipe mass effluent limitations are also being established in the draft permit. Using the total Outfall 001 flow (4.563 mgd), mass limitations for lead are calculated as follows: MDL = (0.04 mg/i) (4.563 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 1.52 lbs/day AML = (0.03 mg/i) (4.563 106 gal/day) (1 lb/454,000 mg) (3.785 1/gal) = 1.14 lbs/day Whole Effluent Toxicity The previous NPDES permit issued to the Luster Glass facility contained a requirement for conducting monthly acute and chronic toxicity tests during the fourth and fifth year of the permit (March 1988 through February 1989). The test species selected by the facility was the fathead minnow, based on an initial comparison of species sensitivity performed in February 1988. The results of these toxicity tests were reviewed to determine whether an effluent limit on toxicity should be developed for the permit. The concentration of acute and chronic toxicity in the receiving water is calculated and is then compared to the State water quality standards. The receiving water concentrations for acute and chronic toxicity were calculated using the following formula: Cr = (Cd) (Qd) + (Cs) (Qs) (Qd + Qs) Where Cr = receiving water concentration Cd = effluent concentration Qd = effluent flow Cs = receiving water background concentration Qs = appropriate receiving water flow The following summarizes the toxicity data submitted by Luster Glass for the period from March 1988 to February 1989: 16-18 ------- Fact Sheet Page 13 of 21 Toxicity Data (Fathead minnows) LC 50 NOEC (% effluent) (% effluent) 58.0 50 25.2 3 55.0 10 46.3 30 44.8 25 5.9 1 67.8 10 3.9 1 50.1 30 52.0 10 32.1 3 41.7 30 All toxicity testing by Luster Glass involved the use of upstream ambient water for the control and diluent, so that in all calculations, the upstream toxicity is assumed to be zero. The highest result of chronic toxicity measured was an NOEC equal to 1% effluent. By dividing 1 into 100, the NOEC is converted to chronic Toxic Units (TUe). Similarly for acute toxicity, the highest acute toxicity was measured at an LC 50 equal to 3.9 % which converts to 25.6 TU 1 . The resultant receiving water concentration (Cr) in toxic units for both acute and chronic toxicity are calculated using the following data: Cs = 0 Qs = 23.6 cf S (one third the 7QlO for acute protection) Qs = 70.9 cf S (the 7Ql0 for chronic protection) Qd = 7.06 cfs Acute Cr = (25.6 TU 1 ) (7.06 cfs)/(7.06 cfs + 23.6 cfs) = 5.9 TU Chronic Cr = (100 TUC) (7.06 cfs)/(7.06 cfs + 70.9 cfs) = 9.1 TU 16-19 ------- Fact Sheet Page 14 of 21 The State water quality standards for acute and chronic protection are summarized below: State Water Quality Standard for Acute Protection = 0.3 TU 1 State Water Quality Standard for Chronic Protection = 1.0 TU WET limits would be necessary since the calculated receiving water concentrations exceed the state water quality standards for both acute and chronic protection: For acute protection 5.9 TU 1 > 0.3 TU 1 For chronic protection 9.1 TU > 1.0 TTJC Using steady state assumptions, the WLAs were calculated using the following formula: Cd = [ Cr(Qd + Qs)-(Cs)(Qs)] / Qd where: Cd = Concentration of the pollutant in the discharge, or waste load allocation Cr = State Water Quality Standard for chronic protection = 1.0 TU for acute protection = 0.3 TU 1 Qd = Discharge flow = 7.06 cfs Qs = Appropriate receiving water flow chronic flow (7Q10) = 70.9 cfs acute flow = 23.6 cfs Cs = Receiving water or upstream concentration = 0 Assuming zero background toxicity, the limits are calculated as follows: WLA (acute) = [ (0.3 TU 1 ) (7.06 cfs + 23.6 cfs)] — ((0) (23.6 cfs)) 7.06 cfs = 1.3 TU 1 WLA (chronic) = [ (1.0 TUG) (7.06 cfs + 70.9 cfs)) — [ (O)(70.9 cfs)] 7.06 cfs = 11.0 TtJ An acute to chronic ratio (ACR) was calculated from the toxicity data by taking the average ACR from each data set as follows: 16—20 ------- Fact Sheet Page 15 of 21 LC 50 NOEC ( % effluent) ( % effluent ) ACP. 58.0 50 1.16 25.2 3 8.40 55.0 10 5.50 46.3 30 1.54 44.8 25 1.79 5.9 1 5.9 67.8 10 6.78 3.9 1 3.9 50.1 30 1.67 52.0 10 5.20 32.1 3 10.7 41.7 30 1.’39 Average 4.5 The acute WLA (in TU 1 ) are converted to TU using the acute to chronic ratio (ACR) as follows: WLA (in TUac) = 1.3 TU 1 * ACR = 1.3 TUa * 4 5 = 5.9 TU, Given that all State water quality standards are expressed as never to be exceeded (i.e., water quality-based limits must be protective of the most stringent waste load allocation), a maximum daily limitation (MDL) and a average monthly limitation (AML) for WET were calculated using the waste load allocations calculated above. A ratio of daily maximum to monthly average of 1.6 is assumed for WET based upon technolgy-based effluent limits for lead. Since the acute WLA is more limiting than the chronic WLA (i.e., 5.9 TUac < 11.0 TUC), it will be used as the basis for limitations. Since the acute WLA can never be exceeded, 5.9 TU is used as the MDL. The AML is calculated as follows: 5.9 TU 1 ________ = 3.7 TU 1.6 The permittee shall conduct chronic toxicity tests according to methods outlined in “Short Term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Waters to Freshwater Organisms” (EPA 600/4—89 001) 16-21 ------- Fact Sheet Page 16 of 21 VIII. Proposed Effluent Limitations Table 2 summarizes the proposed ffluent limitations for Outfall 001. Proposed effluent limitations for zinc are based on BPJ. The limitation for temperature is based on State water quality standards. The proposed limitations for lead were calculated above as chemical specific water quality-based limitations. The remainder of the effluent limitations are based on BPT/BAT effluent guidelines at 40 CFR Part 426 and State effluent standards. IX. Monitoring Reguirementg Monitoring for those pollutants expected to be present in Outfall 001 (i.e., TSS, oil and grease, phosphorus, lead, and zinc) will be required once per week. Except for oil and grease, for which a grab sample is required, 24—hour composite samples are required. Temperature is to be monitored continuously during discharge. Whole effluent toxicity testing for chronic toxicity shall be conducted 2/month on a 24-hour composite sample of the final effluent. X. Special Conditions Luster Glass Inc. will be required to update their existing Best Management Practices (BMP) plan to address the potential for leakage of gasoline from Tank Number 42 and nitric acid from the drum storage area. Specifically, Luster Glass Inc. should undertake the following two site-specific BMPs and incorporate them into their plan. First, remedial action must be taken on Tank Number 42 to repair the damaged tank. The gasoline must be transferred to another vessel (e.g., tank truck) while the tank is cleaned, repaired, welded or holes plugged. To prevent environmental damage at this site in the future, the following BMPs should be incorporated into the plan: visual inspection, secondary containment, preventative maintenance, or some combination thereof. Secondly, the drum storage area must be cleaned up by following procedures such as the following: inventory the drums to identify the contents and amounts of chemicals therein; inspect the drums for deterioration or leaks, and segregate and adequately dispose of the leaking or deteriorating drums; remove and adequately dispose of any contaminated soil; neatly stack the remaining drums in a manner to eliminate hazards to humans or the environment by isolating the drums from walkways or roadways, placing them on an impervious pad, covering the storage area, diking the area, moving the storage area away from the stream or some combination thereof. 16-22 ------- Fact Sheet Page 17 of 21 XI. Information Sources While developing effluent limitations, monitoring requirements, and special conditions for the draft permit, the following information sources were used: (1) EPA NPDES Application Forms 1 and 2C dated October 1980 and February 1985, respectively. (2) State Effluent Standards, Part 304 of the State Administrative Code, Title 35 — Environmental Protection; Subtitle C - Water Pollution, adopted March 17, 1980. (3) Division files related to the Luster Glass Inc. NPDES Permit No. 1L0654321. (4) State Water Quality Standards, Part 302 of the State Administrative Code, Title 35 — Environmental Protection; Subtitle C - Water Pollution, adopted March 17, 1980. (5) EPA Technical Support Document for Water Quality-Based Toxics Control. (6) 40 CFR Parts 423, 433, and 426. 16-23 ------- TABLE 1 DISCHARGE MONITORING REPORT LUSTER GLASS INC. March 1988 through February 1989 Fact Sheet Page 18 of 21 Date 03—88 Mon. 4.575 Flow Avg. (mgd) Daily Max. TSS ( lb/d) 180.4 Grease (lb/d) 19 Phosphorus ( lb/d) 14 4.583 04—88 4.554 4.567 05—88 4.552 4.569 06—88 4.568 4.573 245.2 27 18 07—88 4.585 4.589 08—88 4.588 4.591 09—88 4.571 4.581 429.3 88 29 10—88 4.568 4.572 11—88 4.553 4.573 12—88 4.551 4.541 308.7 22 15 01—89 4.550 4.561 02—89 4.560 4.570 16-24 ------- Fact Sheet Page 19 of 21 TABLE 1 (Continued) DISCHARGE MONITORING REPORT LUSTER GLASS INC. March 1988 through February 1989 pH Temperature Zinc Lead COD Date ( S.U.) ( degrees F) mg/i ) ( mg/i) 1mg/i ) 03—88 6.6 80 0.21 0.10 50 04—88 05—88 06—88 7.1 83 0.08 0.17 07—88 08—88 09—88 9.0 78 0.09 0.12 10—8 8 11—88 12—88 8.1 61 0.06 0.38 01—8 9 02—89 16-25 ------- Fact Sheet Page 20 of 21 TABLE 1 (Continued) DISCHARGE MONITORING REPORT LUSTER GLASS INC. March 1988 through February 1989 Toxicity Test Data: Unless otherwise indicated, acute toxicity tests were conducted using fathead minnow and reported as 48 hr. LC 50 ; chronic toxicity tests were conducted using fathead minnows and reported as 7 day NOEC. LC 50 NOEC DATE (% effluent) (% effluent) 3/88 58.0 50 4/88 25.2 3 5/88 55.0 10 6/88 46.3 30 7/88 44.8 25 8/88 5.9 1 9/88 67.8 10 10/88 3.9 1 11/88 50.1 30 12/88 52.0 10 1/89 32.1 3 2/89 41.7 30 * Toxicity tests using Ceriodaphnia dubia 48 hour survival (acute) and 7 day reproduction (chronic) 16-26 ------- Fact Sheet Page 21 of 21 TABLE 2 PROPOSED EFFLUENT LIMITATIONS NPDES PERMIT NO. 1L0654321 DAILY MAXIMUM MONTHLY AVERAGE PARAMETER LBS/DAY MG/L LBS/DAY MGIL Flow (mgd) Report Report TSS 451.1 11.86 351.3 9.23 Oil & Grease 104.2 2.74 104.2 2.74 Phosphorous 16.5 0.43 16.5 0.43 pH Temperature - Total Lead 1.52 0.04 1.14 0.03 Total Zinc 3.75 0.10 3.75 0.10 Whole Effluent Toxicity (WET) / pH shall be within the range of 6.0 — 9.0 standard units b/ Not greater than 2.8 degrees Centigrade above ambient, or 1.7 degrees Centigrade above the following maximum limits: December 1 through March 31 16 deg C (60 deg F) April 1 through November 30 32 deg C (90 deg F) g/ Discharges of effluent with toxicity greater than the following amounts are prohibited: Maximum Daily Chronic Toxicity of 5.9 TU, and Average Monthly Chronic Toxicity of 3.7 TUG. 16-2 7 ------- EPA REVIEW OF STATE PERMITS • Major municipal and industrials • General permits • Class I sludge facilities • Other (minor) permits which: - Discharge to territorial seas - Affect another State’s waters - Cooling water discharges> 500 MGD - Process discharges >0.5 MGD - Primary industry’s categories NOTES: 16-28 ------- PUBLIC NOTICE • Purpose of public notice • Types of actions requiring public notice - Tentative denial of application - Preparation of draft NPDES permit - Scheduling of hearing - Formal appeal of permit • Methods applicable to public notice process - Publication in newspaper - Direct mailing: who receives • Contents of public notice - Name and address of regulatory authority - Name and address of permittee - Brief description of facility - Name, address, and telephone number of contact - Additional information (EPA-issued permits) • Timing of public notice - After EPA/State review - EPA/State MOA should address • Significant comments must be responded to in writing • Public hearing is always optional NOTES: 16-29 ------- RESPONSE TO COMMENTS FINAL PERMIT DECISION This is our response to comments received on the subject draft permit Ln accordance with regulations promulgated at 40 CFR Part 124.17. Permit No. LA0006 181 Applicant: Allied Chemical Corporation P.O. Box 226 Geismar, Louisiana 70734 Issuing Office: U.S. Environmental Protection Agency Region 6 1445 Ross Avenue Dallas, Texas 75202-2733 Prepared By: Edward C. McHam, Engineer Industrial Permits Section (6W-PI) Permits Branch Water Management Division (214) 655-7180 Permit Action: Final permit decision and response to comments - received on the draft permit publicly noticed ott 7/7/84. Date Prepared: 9/5/84 Unless otherwise stated, citations to 40 CFR refer to promulgated regulacLons listed at Title 40, Code of Federal Regulations, revised as of 7/1/83. The following comments have been received on the draft permit: Letter Dessert (Allied) to Caldwe].l (EPA) dated 7/30/84 ISSUE NO. 1 The draft permit establishes biomonitorii -tg requirements at Outfall 004. The company requests deletion of these requirements. RESPONSE NO. 1 The request is denied. The permitte. states that biomonitoring will be duplicative and unnecessary because: (1) EPA has identified the toxic pollutants of concern. (2) The proposed permit places BAT limits and monitoring requirei’encs on these pollutants. 16-30 ------- PERMIT NO. LA0006181 RESPONSE TO COMMENTS (3) The BAT limits are more restrictive than water quality-based limitations. (4) Biomonitoring results could be distorted and masked by the osrnoti.c stress on test organisms exerted by the salts present in an rF plant effluent. The biomonitoring method is a standardized method used throughout EPA Regton 6 to measure the toxicity of various effluents which contain toxic componerts The test is not based on water quality impacts of a specific receiving stream Under Section 308 of the Clean Water Act, EPA Region 6 has the authority to require permittees to support development of data bases such as those associated with toxics. Therefore, biomonicoring requirements as establLshed in the draft permit are retained in the final permit. 16—31 ------- Chevron Chevron Chemical Company PO Boi 78 Si James LA 70086 • Phone i504| 473 7946 January 12, 1990 0 P Teichman "am Manager S. .ar.j PIJHI CERTIFIED MAIL - RETURN RECEIPT # P 965 729 397 Ms. Ellen Caldwell Permits Branch (6W-PS) U.S. EPA Region VI 1445 Ross Avenue Dallas, TX 75202-2733 SUBJECT: CHEVRON CHEMICAL COMMENTS NPDES PERMIT NO. LA0029963 Dear Ms. Caldwell: We have reviewed draft NPDES Permit No. LA0029963 for Chevron Chemical's St. James Plant issued for public comment by the EPA on December 16, 1989. We have the following comments: 1. As represented in the Fact Sheet (Part VIII.Section C 1) , we understand an administrative order will be issued concurrent with the final permit decision. We understand the administrative order will establish interim limits which will be in effect until 2/1/91, when our upgraded effluent treatment plant will be operational. As a result, we have not reviewed, and are not providing comments on the draft permit relative to it being in effect during the interim period (i.e. from final permit issuance to 2/1/91). 2. we want to clarify that the discharge description included in Part V of the Fact Sheet is representative of our current facility discharge. Following completion of our ongoing facility expansion, the concentration of pollutants in our discharge will significantly decrease and the discharge flowrate will increase from current levels. These changes to our discharge were detailed in our submittals to the EPA and have been properly recognized in development of the proposed permit limits. 3. We request that you change the pH of the Outfall 002 from 9.0 to 10.0. The plant's clarified water and firewater is purchased and is lime softened with a pH of 10. This water has a high pH but a low alkalinity and is not hazardous to personnel nor to the environment. In the last 6 months we have had 2 permit these water systems. In the first instance, b the paved areas of the plant with firewater, we u^ j:a- 'ashiTig ceeded the 9 . 0 pH limit. In the second instance, a number of clarified .water 16-32 ------- + and firewater lines failed due to the hard December freeze. This water overflowed the retention pond and again we had a permit exceedence. We have developed and have begun implementing a plan to eliminate continuous sources of high pH water currently discharged to our retention pond. This work will be completed by the 1/1/91. we therefore feel that a change of the pH limit on Outfall 002 from 9.0 to 10.0 would not endanger people nor the environment and would eliminate nuisance excursions. We appreciated receiving the well-organized and readable fact sheet which clearly established the basis for the permit requirements. Although the proposed permit limits are substantially lower than those in our previous permit, we expect to be able to achieve and maintain compliance once our upgraded effluent treatment plant is fully operational. If you have any questions or wish to discuss our comments further, please do not hesitate to contact me or my staff. Very truly yours, P. Teichman LLR/vho 16—33 ------- 16—34 ------- PRACTICAL EXERCISE The Administrative Process DIRECTIONS : You are a permit writer and have issued an NPDES permit for Luster Glass Inc., a glass manufacturer located on the Illinois River. Luster Glass Inc., unhappy with your work, seeks an administrative appeal of the permit and in so doing, raises the following issues: • The permit is improperly based on the provisions of 40 CFR Part 426 (Glass Manufacturing Point Source Category); • The effluent limitations for zinc and lead are calculated incorrectly; • Luster Glass Inc. s request to delete permit conditions requiring the company to comply with Coast Guard regulations regarding the transportation, handling and storage of pollutants was improperly ignored; • The weekly monitoring requirements for lead and zinc are excessive; and • The Agency violated its regulations and established policy by refusing to hold a hearing as requested by Luster Glass Inc. Q JEST IONS : (1) Assuming Luster Glass Inc. ’s appeal is granted, what effect will this have on the effectiveness of the NPDES permit? (2) What standard should the Hearing Officer use to evaluate the permit? (3) You have been called upon to testify on behalf of the Permit Authority. How do you respond to each of the issues raised by Luster Glass Inc.? (a) The improper use of regulations: (b) The calculation of limitations: (C) The use of the Coast Guard regulations: (d) The excessive monitoring requirements: (e) The failure to hold a hearing: (4) In addition to this logically organized and undeniably scientific testimony concerning your actions in developing this permit, what other assistance might you be asked to lend to your attorney? (5) Once the Hearing Officer has made a decision, what is the next step in the process of getting the Luster Glass permit final and effective? 16-35 ------- 16-36 ------- PERMIT WRITERS ON APPEAL • Witness for permit authority • Source of technical knowledge for attorney • Assist in developing cross-examination questions NOTES: 16—3 7 ------- MAJOR MODIFICATIONS 1. Reopener condition 2. Correct technical and legal mistakes 3. Failure to notify interested State 4. New information 5. Alterations justifying new/different conditions 6. New regulations 7. Modification of a compliance schedule (> 120 days) 8. Require POTW to develop pretreatment programs 9. Unsuccessful BPJ treatment installed 10. Address non-limited pollutants 11. Variance request 12. Adjust limits to reflect net pollutant treatment 13. Insert 307(a) toxic or Part 503 sludge use/disposal 14. Establish notification levels NOTES: 16-38 ------- MINOR MODIFICATIONS 1. Typographical errors 2. More frequent monitoring 3. Change in interim compliance date (<120 days) 4. Change in ownership 5. Change in construction schedule for new source 6. Deletion of point source outfall 7. Incorporate approved local pretreatment program PERMIT TERMINATIONS • Suspend effectiveness in emergency • Terminate for falsifications, recalcitrants or changed conditions • Must public notice intentions and offer permittee a hearing NOTES: 16-39 ------- APPLICABLE EFFLUENT STANDARDS REVIEW EXERCISE 1. Industrial facilities are subject to: _____________________________________ 2. POTWs are subject to: _________________________________________ 3. Federal facilities are subject to: ____________________________________ 4. Industrial storm water is subject to: ________________________________ 5. Municipal storm water is subject to: ________________________________ 6. Combined sewer overflows are subject to: _________________________ 7. New sources are subject to: 8. New dischargers are subject to: ____________________________________ NOTES: 16-40 ------- Permit No.: 1L0654321 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AUTHORIZATION TO DISCHARGE UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of the Clean Water Act, as amended, (33 U.S.C. S1251 et seq; the “Act”), LUSTER GLASS, INC. is authorized to discharge from a facility located in Morris, Illinoie to receiving waters named the Illinois River in accordance with discharge point(s), effluent limitations, monitoring requirements and other conditions set forth herein. Authorization for discharge is limited to those outfal].s specifically listed in the permit. This permit shall become effective August 31, 1989 This permit and the authorization to discharge shall expire at midnight, August 31, 1994. Signed this day of Authorized Permitting Official Director Water Management Division Title 16—41 ------- PART I Page 2 of 19 Permit No.: 1L065432]. TABLE OF CONTENTS Cover Sheet——Issuance and Expiration Dates I. Effluent Limitations and Monitoring Requirements A. Definitions B. Description of Discharge Points C. Specific Limitations and Self—Monitoring Requirements (Includes Compliance Schedules as Appropriate) II. Monitoring, Recording and Reporting Requirements A. Representative Sampling B. Monitoring Procedures C. Penalties for Tampering D. Reporting of Monitoring Results E. Compliance Schedules F. Additional Monitoring by the Permittee G. Records Contents H. Retention of Records I. Twenty—four Hour Notice of Noncompliance Reporting J. Other Noncompliance Reporting K. Inspection and Entry III. Compliance Responsibilities A. Duty to Comply B. Penalties for Violations of Permit Conditions C. Need to Halt or Reduce Activity not a Defense D. Duty to Mitigate E. Proper Operation and Maintenance F. Removed Substances G. Bypass of Treatment Facilities H. Upset Conditions I. Toxic Pollutants J. Changes in Discharge o.f Toxic Substances IV. General Requirements A. Planned Changes B. Anticipated Noncompliance C. Permit Actions D. Duty to Reapply E. Duty to Provide Information F. Other Information G. Signatory Requirements H. Penalties for Falsification of Reports I. Availability of Reports J. Oil and Hazardous Substance Liability K. Coast Guard L. Property Rights M. Severability N. Transfers 0. State Laws P. Water Quality Standard Requirements-Reopener Provision Q. Toxicity Reopener Provision V. Special Requirements A. Best Management Practices (BMP) Plan B. BMP Implementation C. Site—Specific BMPs 16-42 ------- k Ar(T I Page 3 of 19 Permit No.: 1L0654321 I. EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS A. Definitions . 1. The “30-day (and monthly) average,” other than for fecal coliform bacteria and total coliform bacteria, is the arithmetic average of all samples collected during a consecutive 30—day period or calendar month, whichever is applicable. Geometric means shall be calculated for fecal coliform bacteria and total coliform bacteria. The calendar month shall be used for purposes of reporting self—monitoring data on discharge monitoring report forms. 2. The “7—day (and weekly) average,” other than for fecal coliform bacteria and total coliform bacteria, is the arithmetic mean of all samples collected during a consecutive 7—day period or calendar week, whichever is applicable. Geometric means shall be calculated for fecal coliform bacteria and total coliform bacteria. The 7-day and weekly averages are applicable only to those effluent characteristics for which there are 7—day average effluent limitations. The calendar week which begins on Sunday and ends on Saturday, shall be used for purposes of reporting self-monitoring data on discharge monitoring report forms. Weekly averages shall be calculated for all calendar weeks with Saturdays in the month. If a calendar week overlaps two months (i.e., the Sunday is in one month and the Saturday in the following month), the weekly average calculated for that calendar week shall be included in the data for the month that contains the Saturday. 3. “Daily Maximum” (“Daily Max.”) is the maximum value allowable in any single sample or instantaneous measurement. 4. “Composite samples” shall be flow proportioned. The composite sample shall, as a minimum, contain at least four (4) samples collected over the compositing period. Unless otherwise specified, the time between the collection of the first sample and the last sample shall not be less than six (6) hours nor more than 24 hours. Acceptable methods for preparation of composite samples are as follows: a. Constant time interval between samples, sample volume proportional to flow rate at time of sampling; b. Constant time interval between samples, sample volume proportional to total flow (volume) since last sample. For the first sample, the flow rate at the time the sample was collected may be used; C. Constant sample volume, tune interval between samples proportional to flow (i.e., sample taken every “X” gallons of flow); and, d. Continuous collection of sample, with sample collection rate proportional to flow rate. 5. A “grab” sample, for monitoring requirements, is defined as a single “dip and take” sample collected at a representative point in the discharge stream. 16-43 ------- PART I Page 4 of 19 Permit No.: 1L0654321 6. An “instantaneous” measurement, for monitoring requirements, is defined as a Single reading, observation, or meaaurement. 7. “Upset” means an exceptional incident in which there is unintentional and temporary noncompliance with technology—based permit effluent limitations because of factors beyond the reasonable control of the permittee. An upset does not include noncompliance to the extent caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventive maintenance, or careless or improper operation. 8. “Bypass” means the intentional diversion of waste streams from any portion of a treatment facility. 9. “Severe property damage” means substantial physical damage to property, damage to the treatment facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass. Severe property damage does not mean economic loss caused by delays in production. 10. “Director” means Director of the United States Environmental Protection Agencys Water Management Division. 11. “EPA” means the United States Environmental Protection Agency. 12. ‘Sewage Sludge” is any solid, semi—solid or liquid residue that contains materials removed from domestic sewage during treatment. Sewage sludge includes, but is not limited to, primary and secondary solids and sewage sludge products. 13. “Acute Toxicity” occurs when 50 percent or more mortality is observed for either test species (See Part I.C.) at any effluent concentration. Mortality in the control must simultaneously be 10 percent or less for the effluent results to be considered valid. 14. “Chronic Toxicity” occurs when the survival., growth, or reproduction, as applicable, for either test species, at the effluent dilution(s) designated in this permit (see Part I.C.), is significantly less (at the 95 percent confidence level) than that observed for the control specimens. 16-44 ------- PART I Page 5 of 19 Permit No.: 1L0654321 B. Description of Discharge Points The authorization to discharge provided under this permit is limited to those outfalls specifically designated below as discharge locations. Discharges at any location not authorized under an NPDES permit is a violation of the Clean Water Act and could subject the person{o} responsible for such discharge to penalties under Section 309 of the Act. Knowingly discharging from an unauthorized location or failing to report an unauthorized discharge within a reasonable time from first learning of an unauthorized discharge could subject such person to criminal penalties as provided under the Clean Water Act. Outfall Serial Number Description of Discharge Point 001 Discharge of effluent from the wastewater treatment oil/water separator and settling basins, and cooling tower blowdown to the Illinois River. 16-45 ------- PART I Page 6 of 19 Permit No.: 1L06 54321 C. pecifjc Limitations and Self—Monitoring Regujremen g 1. Effluent Limitations (Outfall 00].) Effective immediately and lasting through the life of the permit, the permittee is authorized to discharge from Outfall. 001. Such discharges shall be limited by the permittee as specified below: Effluent 30—Day Daily / Parameter Average Maximum Flow, MGD N/A N/A Total Suspended Solids, lb/day 35 ] . 3 451.1 mg/i 9.23 11.86 Oil and Grease, lb/day 104.2 104.2 mg/i 2.74 2.74 Total Phosphorus, lb/day 16.5 16.5 mg/i 0.43 0.43 Total Zinc, lb/day 3.75 3.75 mg/i 0.1 0.1 Total Lead, lb/day 1.14 1.52 mg/i 0.03 0.04 Whole Effluent Toxicity (WE ), TU, / 3.7 5.9 pH, s.u. Temperature There shall be no discharge of floating solids or visible foam in other than trace am: ints. a, See Definitions, Part l.A. for definition of terms. / The perulittee shall demonstrate compliance with WET requirements specified in Part I.C.3 of this permit. c/ pH shall not be less than 6.0 s.u. nor greater than 9.0 s.u. d/ Temperature shall not be greater than 2.8 degrees Centigrade above ambient, or 1.7 degrees Centigrade above the following maximum limits: from December 1 through March 31, 16 degrees Centigrade (60 degrees Fahrenheit) and from April 1 through November 30, 32 degrees Centigrade (90 degrees Fahrenheit). 16-46 ------- PART I Page 7 of 19 Permit No.: 1L0654321 C. Specific Limitations and Self-Monitoring Requirements (Cant. ) 2. Self—Monitoring Requirements (Outfall 001) As a minimum, upon the effective date of this permit, the following constituents shall be monitored at the frequency and with the type of measurement indicated; samples or measurements shall be representative of the volume and nature of the monitored discharge. If no discharge occurs during the entire monitoring period, it shall be stated on the Discharge Monitoring Report Form (EPA No. 3320—1) that no discharge or overflow occurred. Effluent Parameter Frequency Sample Type a/ Flow, MGD Daily Instantaneous or Continuous Temperature Daily Continuous Total Suspended Solids Weekly 24-Hour Composite Oil and Crease Weekly Grab Total Phosphorus Weekly 24-Hour Composite Total Zinc Weekly 24—Hour Composite Total Lead Weekly 24—Hour Composite Whole Effluent Toxicity (WET), Chronic 2/Month 24-Hour Composite pH Daily Continuous or Crab Sampling by the permittee for compliance with the monitoring requirements specified above shall be performed at the following locations(s): within 100 feet of Outfall 001 to the Illinois River. a/ See definitions, Part l.A. b/ Flow measurements of effluent volume shall be made in such a manner that the permittee can affirmatively demonstrate that representative values are being obtained. 16-4 7 ------- PA RT I Page 8 of 19 Permit No.: 11.0654321 C. Specific Limitations and Self—Monitoring Requiremen g (Cont. ) 3. Whole Effluent Toxicity Testing - Chronic Toxicity Starting the effective date of this permit, the permittee shall conduct biweekly chronic toxicity tests on a 24 hour composite sample of the final effluent. If chronic toxicity is detected, the permittee shall conduct a Toxicity Reduction Evaluation, according to specifications in Part I.C.4 of this permit. Test species shall consist of P.irnephales p.romelas (Fathead minnows). The chronic toxicity tests shall be conducted in general accordance with the procedures set out in the latest revision of “Short—Term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Waters to Freshwater Organisms”, EPA/600—4—89-O01. If control mortality exceeds 20 percent, the test shall be considered invalid. Chronic toxicity occurs when the No Observed Effect Concentrations (NOECB) (calculated within a 95 percent confidence interval) exceed(s) the permit limit(s). Test results shall be reported along with the Discharge Monitoring Report (DMR) submitted for the end of the calendar period during which the whole effluent test was run. The report shall include all the physical testing as specified and shall report test conditions, including temperature, pH, conductivity, mortality, total residual chlorine concentration, control mortality, and statistical methods used to calculate an NOEC. If the results for one year (26 consecutive weeks) of whole effluent testing indicate no chronic toxicity, the permittee may request. the permit issuing authority to allow the permittee to reduce testing frequency. The permit issuing authority may approve, partially approve, or deny the request based on results and other available information. 4. Toxicity Reduction Evaluation (TRE) If the permittee fails to meet toxicity requirements specified in this permit, the permit issuing authority shall determine that a TRE is necessary. The permittee shall be so notified and shall initiate a TRE immediately thereafter. The TRE shall include a TR.E Test Plan that must be submitted to the permitting authority within 60 days after notification of a TRE requirement. The permitting authority will then establish a deadline for compliance. The purpose of the TR.E will be to establish the cause of the toxicity, locate the source(s) of the toxicity, and control or provide treatment for the toxicity prior to the deadline. If acceptable to the permit issuing authority, this permit may be reopened and modified to incorporate any additional numerical limitations, a modified compliance schedule if judged necessary by the permit issuing authority, and/or a modified whole effluent protocol. Failure to conduct an adequate TRE, or failure to submit a plan or program as described above, or the submittal of a plan or program judged inadequate by the permit issuing authority, shall in no way relieve the permittee from the deadline for compliance contained n this permit. 16-48 ------- PART II Page 9 of 19 Permit No.: 1L065432 1 II. MONITORING, RECORDING AND REPORTING REQUIREMENTS A. Representative Sampling . Samples taken in compliance with the monitoring requirements established under Part I shall be collected from the effluent stream prior to discharge into the receiving waters. Samples and measurements shall be representative of the volume and nature of the monitored discharge. B. Monitoring Procedures . Monitoring must be conducted according to test procedures approved under 40 CFR Part 136, unless other test procedures have been specified in this permit. C. Penalties for Tampering . The Act provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this permit shall, upon conviction, be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. D. Reporting of Monitoring Results . Effluent monitoring results obtained during the previous month(s) shall be summarized for each month and reported on a Discharge Monitoring Report Form (EPA No. 3320—1), postmarked no later than the 28th day of the month following the completed reporting period. If no discharge occurs during the reporting period, “no discharge” shall be reported. Until further notice, sludge monitoring results may be reported in the testing laboratorys normal format (there is no EPA standard form at this time), but should be on letter size pages. Legible copies of these, and all other reports required herein, shall be signed and certified in accordance with the Signatory Requirements (see Part IV ) , and submitted to the Director, Water Management Division and the State water pollution control agency at the following addresses: original to: United States Environmental Protection Agency Attention: Water Management Division Compliance Branch copy to: State Department of Health Attention: Permits and Enforcement E. Compliance Schedules . Reports of compliance or noncompliance with, or any progress reports on interim and final requirements contained in any Compliance Schedule of this permit shall be submitted no later than 14 days following each schedule date. F. Additional Monitoring by the Permittee . If the permittee monitors any pollutant more frequently than required by this permit, using test procedures approved under 40 CFR 136 or as specified in this permit, the results of this monitoring shall be included in the calculation and reporting of the data submitted in the 0MB. Such increased frequency shall also be indicated. G. Records Contents . Records of monitoring information shall include: 1. The date, exact place, and time of sampling or measurements; 2. The initials or name(s) of the individual(s) who performed the sampling or measurements; 3. The date(s) analyses were performed; 4. The time(s) analyses were initiated; 16—49 ------- PART II Page 10 of 19 Permit No.: 1L0654321 5. The initials or name(s) of individual(s) who performed the analyses; 6. References and written procedures, when available, for the analytical techniques or methods used; and, 7. The results of such analyses, including the bench sheets, instrument readouts, computer disks or tapes, etc., used to determine these results. H. Retention of Records . The permittee shall retain records of all monitoring information, including all calibration and maintenance records and all original strip chart recordings for continuous monitoring instrumentation, copies of all reports required by this permit, and records of all data used to complete the application for this permit, for a period of at least three years from the date of the sample, measurement, report or application. This period may be extended by request of the Director at any time. Data collected on site, copies of Discharge Monitoring Reports, and a copy of this NPDES permit must be maintained on 8ite during the duration of activity at the permitted location. I. Twenty-four Hour Notice of Noncompliance Reporting . 1. The permittee shall report any noncompliance which may seriously endanger health or the environment as soon as possible, but no later than twenty—four (24) hours from the time the perrnittee first became aware of the circumstances. The report shall be made to the EPA Emergency Response Branch at (312) 293—1788 and the State at (312) 370—9395. 2. The following occurrences of noncompliance shall be reported by telephone to the EPA Compliance Branch at (312) 293—1589 and the State at (312) 331—4590 by the first workday (8:00 a.m. — 4:30 p.m.) following the day the permittee became aware of the circumstances: a. Any unanticipated bypass which exceeds any effluent limitation in the permit (See Part III.G.. Bypass of Treatment Facilities.) ; b. Any upset which exceeds any effluent limitation in the permit (See Part III.H.. Upset Conditions.) ; or, c. Violation of a maximum daily discharge limitation for any of the pollutants listed in the permit to be reported within 24 hours. 3. A written submission shall also be provided within five days of the time that the permi.ttee becomes aware of the circumstances. The written subm .ssion shall contain: a. A description of the noncompliance and its cause; b. The period of noncompliance, including exact dates and times; c. The estimated time noncompliance is expected to continue if it has not been corrected; and, d. Steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncompliance. 16-50 ------- PART II Page 11 of 19 Permit No.: 1L0654321 4. The Director may waive the written report on a ca8e—by—case basis if the oral report has been received within 24 hours by the Compliance Branch, Water Management Division by phone, (312) 293— 1589. 5. Reports shall be submitted to the addresses in Part II.D.. Reporting of Monitoring Results . J. Other Noncompliance Reporting . Instances of noncompliance not required to be reported within 24 hours shall be reported at the tune that monitoring reports for Part II.D. are submitted. The reports shall contain the information listed in Part 11.1.2. K. Inspection and Entry . The perrnittee Bhall allow the Director, or an authorized representative, upon the presentation of credentials and other documents as may be required by law, to: 1. Enter upon the permittees premises where a regulated facility or activity is located or conducted, or where records must be kept under the conditions of this permit; 2. Have access to and copy, at reasonable times, any records that must be kept under the conditions of this permit; 3. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this permit; and, 4. Sample or monitor at reasonable times, for the purpose of assuring permit compliance or as otherwise authorized by the Act, any substances or parameters at any location. 16-51 ------- PART III Page 12 of 19 Permit No.: IL065432l III. COMPLI CE RESPONSIBILITIES A. Duty to Comply . The permittee must comply with all conditions of this permit. Any permit noncompliance constitutes a violation of the Act and is grounds for- enforcement action; for permit termination, revocation and reissuance, or modification; or for denial of a permit renewal application. The permittee shall give the Director advance notice of any planned changes at the permitted facility or of an activity which may result in permit noncompliance. B. Penalties for Violations of Permit Conditions . The Act provides that any person who violates a permit condition implementing Sections 301, 302, 306, 307, 308, 318, or 405 of the Act is subject to a civil penalty not to exceed $25,000 per day of such violation. Any person who willfully or negligently violates permit conditions implementing Sections 301, 302, 306, 307, or 308 of the Act is subject to a fine of not less than $5,000, nor more than $50,000 per day of violation, or by imprisonment for not more than 3 years, or both. Except as provided in permit conditions in Part III.C., Bypass of Treatment Facilities and Part III.H., Upset Conditions , nothing in this permit shall be construed to relieve the permittee of the civil or criminal penalties for noncompliance. C. Need to Halt or Reduce Activity not a Defense . It shall not be a defense for a permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the conditions of this permit. D. Duty to Mitigate . The permittee shall take all reasonable steps to minimize or prevent any discharge in violation of this permit which has a reasonable likelihood of adversely affecting human health or the environment. E. Proper Operation and Maintenance . The permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the permi.ttee to achieve compliance with the conditions of this permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the operation of back-up or auxiliary facilities or similar systems which are installed by a permittee only when the operation is necessary to achieve compliance with the conditions of the permit. However, the permittee shall operate, as a minimum, one complete set of each main line unit treatment process whether or not this process is needed to achieve permit effluent compliance. F. Removed Substances . Collected screenings, grit, solids, sludges 4 or other pollutants removed in the course of treatment shall be buried or disposed of in such a manner so as to prevent any pollutant from entering any waters of the state or creating a health hazard. Filter backwash shall not be directly blended with or enter either the final plant discharge and/or waters of the United States. G. Bypass of Treatment Facilities : 1. Bypass not exceeding limitations. The permittee may allow any bypass to occur which does not cause effluent limitations to be exceeded, but only if it also is for essential maintenance to assure efficient operation. These bypasses are not subject to the provisions of paragraphs 2. and 3. of this section. 16-52 ------- PART III Page 13 of 19 Permit No.: 1L0654321 2. Notice: a. Anticipated bypass. If the permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least 60 days before the date of the bypass. b. Unanticipated bypass. The perniittee shall submit notice of an unanticipated bypass as required under Part 11.1.. Twenty—four Hour Reporting . 3. Prohibition of bypass. a. Bypass is prohibited and the Director may take enforcement action against a permittee for a bypass, unless: (1) The bypass was unavoidable to prevent loss of life, personal Injury, or severe property damage; (2) There were no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated wastes, or maintenance during normal periods of equipment downtime. Thie condition is not satisfied if adequate back—up equipment should have been installed in the exercise of reasonable engineering judgement to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance; and, - (3) The permittee submitted notices as required under paragraph 2. of this Section. b. The Director may approve an anticipated bypass, after considering its adverse effects, if the Director determines that it will meet the three conditions listed above in paragraph 3.a. of this section. H. Upset Conditions . 1. Effect of an upset. An upset constitutes an affirmative defense to an action brought for noncompliance with technology based permit effluent limitations if the requirements of paragraph 2. of this section are met. No determination made during administrative review of claims that noncompliance was caused by upset, and before an action for noncompliance, is final administrative action subject to judicial review (i.e., Permittees will have the opportunity for a judicial determination on any claim of upset only in an enforcement action brought for noncompliance with technology—based permit effluent limitations). 2. Conditions necessary for a demonstration of upset. .A permittee who wishes to establish the affirmative defense of upset shall demonstrate, through properly signed, contemporaneous operating logs, or other relevant evidence that: a. An upset occurred and that the permittee can identify the cause(s) of the upset; b. The permitted facility was at the time being properly operated; c. The permittee submitted notice of the upset as required under Part 11.1., Twenty—four Hour Notice of Noncompliance Reporting ; and, d. The permittee complied with any remedial measures required under Part III.D., Duty to Mitigate . 16-53 ------- PART III Page 14 of 19 Permit No.: 1L0654321 3. Burden of proof. In any enforcement proceeding, the permittee seeking to establish the occurrence of an upset has the burden of proof. I. Toxic Pollutants . The permittee shall comply with effluent standards or prohibitions established under Section 307(a) of the Act for toxic pollutants within the time provided in the regulations that establish those standards or prohibitions, even if the permit has not yet been modified to incorporate the requirement. J. Changes in Discharge of Toxic Substances . Notification shall be provided to the Director as soon as the permittee knows of, or has reason to believe: 1. That any activity has occurred or will occur which would result in the discharge, on a routine or frequent basis, of any toxic pollutant which is not limited in the permit, if that discharge will exceed the highest of the following “notification levels”: a. One hundred micrograms per liter (100 ug/L); b. Two hundred micrograms per liter (200 ug/L) for acrolein and acrylonitrile; five hundred micrograms per liter (500 ug/L) for 2,4-dinitrophenol and for 2-methyl-4, 6—dinitrophenol; and one milligram per liter (1 mg/L) for antimony; c. Five (5) times the maximum concentration value reported for that pollutant in the permit application in accordance iith 40 CFR 122.2l(g)(7); or, d. The level established by the Director in accordance with 40 CFR 122.44(f). 2. That any activity has occurred or will occur which would result in any discharge, on a non-routine or infrequent basis, of a toxic pollutant which is not limited in the permit, if that discharge will exceed the highest of the following “notification levels”: a. Five hundred micrograms per liter (500 ug/L.); b. One milligram per liter (1 mg/L) for antimony: c. Ten (10) times the maximum concentration value reported for that pollutant in the permit application in accordance with 40 CFR 122.21(g)(7); or, d. The level established by the Director in accordance with 40 CFR 122.44(f). 16-54 ------- PART LV Page 15 of 19 Permit No.: ILO65432j. IV. GENERAL REQUIREMENTS A. Planned Changes . The permittee shall give notice to the Director as soon as possi.ble of any planned physical alterations or additions to the permitted facility. Notice is required only when: 1. The alteration or addition to a permitted facility may meet one of the criteria for determining whether a facility is a new source as determined in 40 CFR 122.29(b); or 2. The alteration or addition could significantly change the nature or increase the quantity of pollutants discharged. This notification applies to pollutants which are subject neither to effluent limitations in the permit, nor to notification requirements under Part IV.A.l. B. Anticipated Noncompliance . The permittee shall give advance notice of any planned changes in the permitted facility or activity which may result in noncompliance with permit requirements. C. Permit Actions . This permit may be modified, revoked and reissued, or terminated for cause. The filing of a request by the permittee for a permit modification, revocation and reissuance, or termination, or a notification of planned changes or anticipated noncompliance, does not stay any permit condition. D. Duty to Reapp].y . If the permittee wishes to continue an activity regulated by this permit after the expiration date of this permit, the permittee must apply for and obtain a new permit. The application should be submitted at least 180 days before the expiration date of this permit. E. Duty to Provide Information . The permittee shall furnish to the Director, within a reasonable time, any information which the Director may request to determine whether cause exists for modifying, revoking and reissuing, or terminating this permit, or to determine compliance with this permit. The permittee shall also furnish to the Director, upon request, copies of records required to be kept by this permit. F. Other Information . When the permittee becomes aware that it failed to submit any relevant facts in a permit application, or submitted incorrect information in a permit application or any report to the Director, it shall promptly submit such facts or information. G. Signatory Requirements . All applications, reports or information submitted to the Director shall be signed and certified. 1. All permit applications shall be signed as follows: a. For a corporation: by a responsible corporate officer; b. For a partnership or sole proprietorship: by a general partner or the proprietor, respectively; c. For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official. 2. All reports required by the permit and other information requested by the Director shall be signed by a person described above or by a duly authorized representative of that person. A person is a duly authorized representative only if: a. The authorization is made in writing by a person described above and submitted to the Director, and, lE -55 ------- PART IV Page 16 of 19 Permit No.: 1L0654321 b. The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity, such as the position of plant manager, operator of a well or a well field, superintendent, position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.) 3. Changes to authorization. If an authorization under paragraph IV.G.2. is no longer accurate because a different individual or position has responsibility for the overall operation of the facility, a new authorization satisfying the requirements of paragraph IV.G.2. must be submitted to the Director prior to or together with any reports, information, or applications to be signed by an authorized representative. 4. Certification. Any person signing a document under this section shall make the following certification: “I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering. the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.” H. Penalties for Falsification of Reports . The Act provides that any person who knowingly makes any false statement, representation, or certification in any record or other document submitted or required to be maintained under this permit, including monitoring reports or reports of compliance or noncompliance shall, upon conviction be punished by a fine of not more than $10,000 per violation, or by imprisonment for not more than two years per violation, or by both. I. Availability of Reports . Except for data determined to be confidential under 40 CFR Part 2, all reports prepared in accordance with the terms of this permit shall be available for public inspection at the offices of the State water pollution control agency and the Director. As required by the Act, permit applications, permits and effluent data shall not be considered confidential. J. Oil and Hazardous Substance Liability . Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities, or penalties to which the permittee is or may be subject under Section 311 of the Act. K. Coast Guard . If the Permittee operates its facility at certain times as a means of transportation over water, the Permittee shall comply with any applicable regulations promulgated by the Secretary of the department in which the Coast Guard is operating, that establish specifications for safe transportation, handling, carriage, and storage of pollutants. L. Property RicThts . The issuance of this permit does not convey any property rights of any sort, or any exclusive privileges, nor does it authorize any injury to private property or any invasion of personal rights, nor any infringement of federal, state or local laws or regulations. 16-56 ------- P .RT IV Page 17 of 19 Permit No.: 1L065432 1 H. Severability . The provisions of this permit are severable, and if any provision of this permit, or the application of ar.y provision of this permit to any circumstance, is held invalid, the application of such provision to other circumstances, and the remainder of this permit, shall not be affected thereby. N. Transfers . This permit may be automatically transferred to a new permittee if: 1. The current permittee notifies the Director at least 30 days in advance of the proposed transfer date; 2. The notice includes a written agreement between the existing and new permittees containing a specific date for transfer of permit responsibility, coverage, and liability between them; and, 3. The Director does not notify the existing permittee and the proposed new permittee of his or her intent to modify, or revoke and reissue the permit. If this notice is not received, the transfer is effective on the date specified in the agreement mentioned in paragraph 2. above. 0. State Laws . Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the permittee from any responsibilities, liabilities, or penalties established pursuant to any applicable state law or regulation under authority preserved by Section 510 of the Act. P. Reopener Provision . This permit may be reopened and modified (following proper administrative procedures) to include the appropriate effluent limitations (and compliance schedule, if necessary), or other appropriate requirements if one or more of the following events occurs: 1. Water Quality Standards : The water quality standards of the receiving water(s) to which the perinittee discharges are modified in such a manner as to require different effluent limits than contained in this permit. 2. Wasteload Allocation : A wasteload allocation is developed and approved by the State and/or EPA for incorporation in this permit. 3. Water Quality Management Plan : A revision to the current water quality management plan is approved and adopted which calls for different effluent limitations than contained in this permit. 16-57 ------- PART IV Page 18 9 f 19 Permit No.: ILO65432l Q. Toxicity Limitation—Reopener Provision . This permit may be reopened and modified (following proper administrative procedures) to include a new compliance date, additional or modified numerical limitations, a new or different compliance schedule, a change in the whole effluent protocol, or any other conditions related to the control of toxicanta if one or more of the following events occur: 1. Toxicity was detected late in the life of the permit near or past the deadline for compliance. 2. The TRE results indicate that compliance with the toxic limits will require an implementation schedule past the date for compliance and the permit issuing authority agrees with the conclusion. 3. The TRE results indicate that the toxicant(s) represent pollutant(s) that may be controlled with specific numerical limits, and the permit issuing authority agrees that numerical controls are the most appropriate course of action. 4. Following the implementation of numerical controls on toxicante, the permit issuing authority agrees that a modified whole effluent protocol is necessary to compensate for those toxicants that are controlled numerically. 5. The TRE reveals other unique conditions or characteristics which, in the opinion of the permit issuing authority, justify the incorporation of unanticipated special conditions in the permit. 16-58 ------- PART V Page 19 of 19 Permit No.: 1 1 .065432 ]. V. SPECIAL REQUIREMENTS A. Best Management Practices (BMP) Plan A BMP plan shall be developed within six months of permit reissuance, addressing each of the nine specific requirements described in the June 1981 EPA document, NPDES BMP Guidance Document . Emphasis shall be placed on good housekeeping practices, visual inspection, and preventative maintenance. The BMP plan shall be written up and delivered to the U.S. Environmental Protection Agency no later than February 5, 1990. B. BMP Implementation The OMP plan shall be fully implemented within twelve months of permit reissuance. An implementation report shall be delivered to the U.S. Environmental Protection Agency no later than August 5, 1990. C. Site—Specific BMPs The following site—specific EMP8 shall be included: 1. Tank Number 42: Remedial action is required to repair the damaged tank. This shall include transfer of the contents to another vessel (e.g., tank truck), cleaning the tank, and repairing, welding, or plugging the hole. To prevent environmental damage in the future, secondary containment is required. Monthly visual inspections and/or preventative maintenance shall be conducted. 2. Drum Storage Area: The drums shall be inventoried to identify the contents and amounts of chemicals therein. The drums shall be inspected for deterioration or leaks. They shall be segregated and any leaking or deteriorating drums shall be disposed of or repaired. Any contaminated soil shall be removed and adequately disposed of. The remaining drums shall be neatly stacked in a manner to eliminate hazards to humane or the environment by isolating the drums from walkways or roadways, placing them on an impervious pad, covering the storage area, diking the area, moving the storage area away from the river, or some combination thereof. 16—59 ------- COMPLIANCE AND ENFORCEMENT ------- LEARNING OBJECTIVES • Common errors in permits • Data management considerations (PCS) • Enforcement tools and considerations • Citizens and enforcement COMMON ERRORS AND OMISSIONS Not: • Issuing permit to correct entity • Ensuring limits are defensible and compatible with PCS • Covering all outfalls • Imposing adequate monitoring or specifying type, frequency and location • Using special conditions • Requiring routine DMRs and specifying signatory • Including all standard conditions • Incorporating Federal Regulations without further explanation • Using precise language NOTES: 17—1 ------- PCS LEARNING OBJECTIVES • Basic understanding of PCS system - Development process - Data elements - Sources of assistance • Permit writer’s responsibilities PCS POLICY • Adopted - October 1985 • Designates PCS as the official NPDES data system • Requires EPA Regions to use Requires NPDES States to use or have interface capability NOTES: 17-2 ------- - The effluent record types exist on each of the 10 physical Regional files ------- PCS ASSISTANCE • Region/State experts • EPA HQ/PCS hotline [ (202) 260-8529] • PCS publications • Other methods PCS PUBLICATIONS • General retrieval manual • Inquiry user’s guide • Data element dictionary • Data entry/edit manual • Manager’s guide to PCS NOTES: 1 — j. ------- PERMIT OUALITY REVIEW CHECKLIST CHECKLIST A-i Procedural Requirements; ADMINISTRATIVE RECORDS Questjon 1. List any of the following items that have been omitted inappropriately from the file. a. Permit application and any supporting data furnished by applicant; b. Draft permit; c. Statement of basis or fact sheet; d. All documents cited in statement of basis or fact sheet; 5. If a new source, any environmental assessment, environmental impact statement, finding of no significant impact or environmental information document and any supplement to an EIS that was prepared; f. All comments received during public comment; g. Tape or transcript of any hearings held and any written materials submitted at hearing; h. Response to significant comments raised during comment period and/or hearing; 1. Final permit; j. Explanation of changes from draft to final permit; Jc. Where appropriate, materials relating to o Consistency determinations under the CZMA o Consultation under the Endangered Species Act o Determination under section 403(c) of the CWA 17-5 ------- CHECKLIST A-2 Procedural Requirements: PUBLIC NOTICE AND COMMENT u e St ion 1. Was a public notice issued of the preparation of draft permit and providing an opportunity for comment at least 30 days prior to final permit decision? 2. Was public hearing held? (If “no”, skip to #4) 3. Was a notice of public hearing issued at least 30 days prior to hearing? 4. Was a summary response to significant comments raised during comment period and/or hearing prepared and issued at time of final permit decision? CHECKLIST A—3 Procedural Requirements: S TATE CERTIFICATION Question 1. Was a state certification or waiver of state certification received? 2. List any conditions in the state certification not included in the permit. Indicate any reasons provided for omissions. ------- CHECKLIST A-4 Procedural Requirements: RECORDS OF MODIFICATION Question 1. Does the permit documentation indicate that the permit was modified, revoked or reissued? (If “no”, skip to Checklist A-5) 2. was the permit modified pursuant to 40 CFR 122.62(a)? If “yes”, specify the basis identified in the permit documentation: (alteration; new information; new regulations; compliance schedules; variance request; 307(a) toxic standard; net limits; reopener; nonlimited pollutants (level of discharge of any pollutant no limited in permit exceeds the level which can be achieved by technology-based treatment); use ore manufacture of toxics (permittee has begun or expects to begin to use or manufacture a toxic - pollutant); notification levels (permit has been modified to establish a “notification level”) 3. Did cause exist for modification or revocation and reissuance pursuant to 40 CFR 122.62(b)? Specify cause: a. Cause exists for termination, as provided in 40 CFR 122.64 (noncompliance: misrepresentation of or failure to disclose facts; endangerment to human health or environment; change in condition); b. Transfer of permit; c. Other (specify) 4. Does the permit documentation indicate that the procedures of 40 CFR 124.5 for permit modification, revocation and reissuance or termination were followed? CHECKLIST A-5 Procedural. Requirements: ENFORCEMENT CONSIDERATIONS 0ue St lOfl 1. Does the permit documentation indicate that any enforcement actions have been taken? Briefly describe (nature of action(s), date(s)): _________ 2. Did the Regional Counsel review or sign of f on the permit? 17—7 ------- CHECKLIST B-i Permit Conditions: BOILERPLATE Question 1. Identify whether the following general conditions have been incorporated into the permit, either directly or by reference to 40 CFR Part 122.41 (or, if permit was issued prior to April 1983, by reference to 40 CFR Parts 122.7 and 122.60). Identify any variation from the regulation language in 122.41. a. Duty to comply; b. Duty to reapply; c. Duty to halt or reduce activity; d. Duty to mitigate; e. Program operation and maintenance; f. Permit actions; g. Property rights; h. Duty to provide information; i. Inspection and entry; j. Monitoring and records; k. Signatory requirement; 1. Reporting requirements; m. Bypass; and n. Upset. 2. If the general Conditions are included by reference, is the CFR citation, date and copy of the regulations provided? If “no”, specify missing item(s): (Skip to #5) 3. Does the permit require notification to the Director as soon as the permittee knows or has reason to believe that any activity has occurred or will occur which would result in the discharge of any toxic pollutant, if that discharge will exceed the “notification levels”, specified in 40 CFR Part 122. 42 (a) ( 1) ? 4. Does the permit require notification to the Director as soon as the permittee knows or has reason to believe that it has begun or expects to begin to use or manufacture as an intermediate or final product or byproduct any toxic pollutant which was not reported in the permit application? 5. Is the permit effective for a fixed term which does not exceed 5 years from date of issuance? 17-8 ------- CHECKLIST B-2 Permit Conditions: PECIAL CONDITIONS Que St ion 1. Are any special conditions requiring kest manageinen rpctjces (BMPs) included in the permit? Identify and specify reason for inclusion (part of guideline, substitute for numeric limitations, etc.). 2. Does the permit application indicate that perniittee does or expects to use or manufacture any toxic Substance as an intermediate or final product or byproduct? (See Form 2C, Item VI—A.) Have any c nditjons for the substances so indicated been included in the permit? If not, does permit documentation explain the omission? 3. Does the permit application indicate that there are intermittent dischar es at the outfall? (See Form 2C, Item 11-C) Are they addressed in the permit? Identify any unexplained omissions. 4. Does the permit include any bio].ogjcp]. toxicity testjng requirements? Briefly describe the requirements and their basis. 5. Does the permit include any limitations or conditions for tnternaj waste -streams ? Describe the. limitations/conditions and the circumstances that make them necessary. 17-9 ------- CHECKLIST C-i Effluent Limitations: TRANSLATING THE PERMIT APPLICATION TO PERNITLIMITATIONS Introduction : Question #1 applies to all outfalls. For the remaing questions, complete one checklist for each individual outfall selected by the review team for review. Question 1. Have a set of effluent limitajons or conditions been included in the permit for every outfall? (See Form 2C, Iter Ill—B) 2. For which pollutants are limitations or conditions included in the permit for: (Identify in an attachment) a. BPT; b. BAT; and c. BCT? 3. Are there pollutants for which limitations or conditions are not included but which might be appropriate to limit? Identify the pollutants and the reasons for including limitations. CHECKLIST C-2 Effluent Limitations: BASIS FOR LIMITATIONS Introduction : Complete one checklist for each individual outfall selected by the review team for review. Question 1. Are the pollutant limitations based on any of the following: a. BPT; b. BCT; C. BAT: d. NSPS; e. Water quality standards? f. Previous permit g. Other (Specify) __________________________________ 2. Are limitations for all pollutants in continuous discharges expressed as both maximum daily values and average monthly values? (If “yes”, skip to #4) 3. List those pollutants for which either limit is omitted, where the omission is inappropriate. 4. List any pollutants limited by mass or concentration that should have been limited in the other form and indicate the reason it should have been listed in the other form. 17—10 ------- CHECKLIST C-3 Effluent Limitations: APPLICABLE EFFLUENT GUIDELINES Introduction : Complete one checklist for each individual outfall selected by the review team for review, if effluent guidelines are applicable. Que st ion 1. Were promulgated effluent guidelines applicable to the source category at the time permit was under consideration? (See Form 1, Items III and XII) (If “no”, skip to Checklist C-4) If not, does the permit contain a reopener clause? 2. WEre effluent guideline limitations used as a basis for permit effluent limitations at the outfall. 3. Did the permittee receive a variance based on the presence of “fundamentally different factors” from those on which- the guideline was based? (If “yes”, skip to Checklist C-4) 4. Are applicable effluent guidelines limitations based on production? (If “no”, skip to #9) 5. Was production basis in the permit a reasonable measure of average actual production, design production capacity? (See Form 2C, Items 111—B and C.) Specify production basis: a. Maximum production during high month of previous year; b. Monthly average for the highest of previous; C. Other: ____ 17—jj ------- CHECKLIST C-3 (continued) Effluent Limitations: APPLICABLE EFFLUENT GUIDELINES Question 6. Does the permit documentation indicate the means used to determine actual production? Specify: a. In permit application; b. Other: 7. Does the permit documentation indicate that the permit writer conducted any fellow-up activites to confirm production estimates? 8. Have alternate permit limitations been included to address different production levels? Specify the number of tiers of limits:___________________ 9. Are all pollutant limitations in the applicable guidelines included in the permit? List any that are not. 10. Was the adjustment formula for disposal to wells, POTW’s, or land application applicable (40 CFR 122.50)? (If “no”, go to C—4) Was it used? 17—12 ------- CHECKLIST C-4 Effluent Limitations: BEST PROFESSIONAL JUDGMENT Introduction : This checklist is intended to point review team inquiry toward those questions which can help in determining whether or not the BPJ analysis was “reasonable”. Review team should provide a qualitative explanation of the limitation development process on the evaluation form. Complete one checklist for each individual outfall selected by the review team for review. Question 1. Is a BPJ analysis (for BPT, BAT, or BCT) missing where it seems to be required? Identify the outfall, pollutant(s), and type of limitation. 2. Indicate which of the following sources were used in establishing any BPJ limitations: a. Promulgated Guideline b. Proposed Guideline - c. Development Document d. Treatability Manual e. Other (specify) 3. Identify any significant sources not used which should have been. 4. Indicate what method was used to establish BPJ/BCT for conventional pollutants. 5. - Bave effluent guidelines been promulgated since the time of permit issuance? If “yes”, indicate the relative stringency of guideline limitations in permit:________________________ (Note if unable to determine this.) 17—13 ------- CHECKLIST C-5 Effluent Limitations: WATER qUALITy BASED LIMITATIONS Introduction : This checklist is intended to point review team inquiry toward those questions which can help in determining whether or not the water quality analysis was “reasonable.” Review team should provide a qualitative explanation of the limitation development process on the evaluation form. Complete one checklist for each individual outfall selected by the review team for review. Quest ion 1. Is a water quality analysis missing where it seems to be required? Identify outfalls(s) and pollutants. 2. Identify type of water quality limitation in permit (:free from”, numerical, or both). 3. Is basis of the water quality based limitation identified in the permit file? Specify: a. State certification b. Water quality modeling c. Other: 4. Were water quality standards included in the permit in lieu of effluent limitations? 5. Have all applicable water quality standards toward which water quality-analysis is directed been clearly identified? 6. Are current water quality conditions clearly identified? If possible, specify basis: a. Actual water quality b. Estimated water quality 7. Does the permit document that water quality—based limitations are at least as stringent as BPT, BCT, or BAT standard? 8. Were water quality modeling and a mixing zone used in establishing the limitation? (If “no”, skip to #20) b. In uts to Ouantitptive Analysis : 9. Has the outfall discharge rate used in analysis been clearly identified? (See Form 2C, Item II) a. Average discharge rate b. Maximum discharge rate c. Other: 17—14 ------- CHECKLIST C-5 (Continued) Effluent Limitations: WATER OUALITY BASED LIMITATIONS 10. Has the stream flow rate used in the analysis been clearly identified? If possible, specify whether: a. Low flow rate (years of record) b. Average flow rate c. Other: ______ 11. was the analysis directed toward water quality within a mixing zone? (If “yes”, skip to #13) 12. Was the analysis directed toward water quality beyond the mixing zone (i.e., wasteload allocation modeling) (If “yes”, skip to #17) c. Ouantitptjve Analysis: Mixing Zone 13. Are the size and configuration of the mixing zone clearly identified? 14. Has the water quality model used been clearly identified? Specify: 15. Were the impacts of other major dischargerg taken into account in the analysis? 16. Does the permit documentation demonstrate that, based on modeling conclusions, applicable water quality standards were met in the mixing zone? (If “yes”, skip to #20) d. antitatiye Analysis: Wasteload Allocation 17. Has the water quality model used been clearly identified? Specify: 18. Were th. impacts of other major dischargers taken into account in the analysis? 19. Does the permit documentation indicate the level of discharges and limitations assumed for other major sources? 20. Does the permit documentation demonstrate that, based on modeling conclusions, applicable water quality standards are met? If not, does the permit documentation explain why the limitation was used in spite of modeling results? Specify:_________________________________ 17—15 ------- CHECKLIST D-1 Monitoring Requirements: DISCHARGE SAMPLING Introduction : Complete one checklist for each individual outfall selected by the review team for review. Question 1. Does the permit require monitoring for every pollutant for which limitations are included in the permit? List any inappropriate omissions. 2. Does the permit stipulate, either in the general conditions or in the permit limitations, that monitoring for all pollutants with limitations be conducted according to test procedures approved under 40 CFR Part 136? Identify any exceptions. 3. Does the permit require monitoring the volume of effluent discharged from the outfall? If not, is an explanation provided? 4. Are effluent sampling frequencies specified for every pollutant for which monitoring is require? Specify for each pollutant (e.g., daily, weekly, quarterly, etc.):_________ CHECKLIST D-2 Monitoring Requirements: DISCHARGE REPORTING Question 1. Are there any pollutants for which discharge monitoring reports are not required at least once a year? List them. 2. Is reporting on discharge monitoring report (DMR) forms required? 3. Specify discharge reporting frequency or frequencies required in permit for the outfall under review (e.g. 1 monthly, quarterly, etc.): I-, If .j_ F — 0 ------- CHECKLIST E-]. Compliance Schedules: INCLUSION IN PERNI Introduction : Complete one checklist for each individual outfall selected by the review team for review. Quest ion 1. Does the permit include a compliance schedule(s) for each outfall which is not in compliance with the limitations specified in the permit? 2. Does the permit documentation provide an explanation of why compliance schedules were not included where necessary? Identify if an explanation was not provided. CHECKLIST E-2 Compliance Schedules: INTERIM AND FINAL REOUIRENENTS Question 1.. Are distinct interim requirements -(milestones) with specific. - dates included in compliance schedule(s)? 2. Does the compliance schedule provide for compliance by ceasing the regulated activity? If so, is a date certain identified ’? 3. Does the compliance schedule include: a. A date certain for the permittee to decide whether or not to cease the regulated activity; b. A compliance schedule in the event that the decision is to continue the regulated activity, a c. A schedule for cessation of the regulated activity in the event that the decision is to cease the activity? 4. Is the time between each interim date in the compliance schedule(s) less than one year? If not, does the permit specify interim dates for submission of reports? 5. Does the compliance schedule provide for final compliance by the appropriate time? (7-1-84 in most cases) 6. Has the source received a section 301(k) (innovative technology) waiver to extend the compliance date up to 7—1—87? 7. Was an ECSL or Section 309(a) (5) (A) order with a compliance schedule ever issued? If so: a. Did the facility meet the criteria for issuance of the ECSL/ order? b. Was the facility in compliance with the ECSL/order? c. Was a subsequent enforcement action brought? 17—17 ------- TOOLS TO DETER VIOLATORS • Informal contacts • Notice of violation • Administrative orders • Civil suit • Criminal suit • Termination CITIZENS AND ENFORCEMENT • Section 505 allows citizen suits (civil action) after 60-day notice to EPA/States and permittee • Penalties to U.S. or State Treasury • Citizens can recover court costs • Supreme Court: Gwaltney decision NOTES: 17—18 ------- EPA ’s PRINCIPLE ENFORCEMENT ACTIONS (see § 122.41(a)) Administrative Order - Schedule for compliance - Interim Limits - APO Class I/il ($25,000/$10,000) Civil Action - Brought in U. S. District Court - Injunction - Judicially enforceable schedule - Civil penalties (up to $25,00 per day per violation) Criminal Action - Negligent violations* ($2,500 - $25,000 and 1 yr. imprisonment) - Knowing violations* ($5,000 - $50,000 and 3 yrs. imprisonment) • Imminent endangerment* ($250,000 and 15 yrs. imprisonment) Doubles for second or subsequent violations NOTES: 17—19 ------- |