&EFA ENVIRONMENTAL REVIEW of SYNTHETIC FUELS INDUSTRIAL ENVIRONMENTAL RESEARCH LABORATORIES VOL. 3 NO. 1 MARCH 1980 RESEARCH TRIANGLE PARK, NC 27711 INTRODUCTION The Environmental Review of Synthetic Fuels is pre- pared as part of the Environmental Protection Agency's pro- gram to evaluate the environmental impacts of synthetic fuel processes. EPA's program was initiated In response to the shift in U.S. energy supply priorities from natural gas and oil to coal. It is directed by the Fuel Process Branch of EPA's Industrial Environmental Research Laboratory in Research Triangle Park, NC (IERL-RTP). The major objectives of the EPA Synthetic Fuels Envi- ronmental Assessment/Control Technology Development Program are 1) to define the environmental and health ef- fects of multimedia discharge streams, and 2) to define control technology needs for an environmentally sound syn- thetic fuels Industry. The synthetic fuels from coal technolo- gies being studied in this program include low/medium-Btu gasification, hlgh-Btu gasification, and liquefaction. To achieve the overall program goals, EPA has defined six major task areas: current process technology back- ground, environmental data acquisition, current environmen- tal background, environmental objectives development, control technology assessment, and impact analysis. The contractors involved in the program, their EPA Project Of- ficers, and the duration of each effort are tabulated on Page 6. This Issue of the Environmental Review of Synthetic Fuels summarizes recent activities In EPA's synthetic fuels program. Activities of EPA contractors are covered In sec- tions on current process technology background and envi- ronmental data acquisition. Highlights of technology and commercial developments, major symposia, a calendar of upcoming meetings, and a list of major publications provide up-to-date information on national and international development in synthetic fuels technology. Comments or suggestions which will improve the content or format of these Reviews are welcome. Such comments should be directed to the EPA or Radian Cor- poration personnel Identified on page 15 of this Review. CURRENT PROCESS TECHNOLOGY BACKGROUND General Topics Technology Assessment Report for Synthetic Fuels— Radian Corporation has completed a technology assessment report on the use of synthetic fuels produced from coal as precombustion emission controls for new industrial boilers. The report (EPA-600/7-79-178d, see "Recent Major Papers and Publications") is one in a series of technology assessment reports designed to aid EPA in determining the technological basis for developing New Source Performance Standards (NSPS) for Industrial boilers. The synthetic fuels technologies considered in the re- port were coal gasification (low-, medium-, and hlgh-Btu) and liquefaction. Major emphasis was placed on examining the reduction of SOX, NOX, and participate emissions in the industrial boiler flue gases. Based on detailed analyses of costs, energy, and en- vironmental Impacts, low-Btu coal gasification was selected as the "best synthetic fuels from coal" .emission control technique for industrial boilers. Two low-Btu gasification systems, the Wellman-Galusha gasif ier with either the Stretford (W-Q/S) or monoethanolamlne (W-Q/MEA) acid gas removal process, were selected for the detailed analyses. Two coal feedstocks (low-sulfur western and high-sulfur eastern) and five boiler capacities (8.8, 22, 44, 58.6, and 117 MW heat input) were also considered In performing the detailed analyses. All of the low-Btu gasification systems examined were capable of meeting the most stringent target NOX and participate emissions control levels considered (86 ng NOX/J and 4 ng partlculates/J heat input to the boiler). With respect to SOi emissions, the W-G/S systems using a low-sulfur coal feed could achieve a stringent target emission control level of 43 ng SOi/J heat Input. Using a high-sulfur coal feed, the W-G/S systems could achieve a moderate target control level of 150 ng SOa/J heat Input. The W-G/MEA systems were only considered for the high-sulfur coal cases and could be designed to achieve either the moderate or stringent target SOi control level. Cost analyses indicated that the annualized costs of the gasifIcatlon/low-Btu gas-fired boiler systems were ap- proximately 20 to 170 percent greater than the annualized costs of an equivalent capacity (on a boiler heat Input basis) direct coal-fired boiler without pollution controls. The per- centage increase In Incremental costs of pollution control varied indirectly with boiler capacity. For a given boiler capacity, the W-G/S system using low-sulfur coal had the lowest incremental costs, while the W-G/MEA system using high-sulfur coal had the highest incremental costs. All of the low-Btu gasification/boiler systems consume more energy (4045%) than equivalent capacity uncontrolled coal-fired boilers. The low-Btu gasification systems are also sources of gaseous, liquid, and solid discharges. However, there appear to be no uncontrollable adverse environmental impacts. ------- Environmental Review of Synthetic Fuels March 1979 Liquefaction Revision of Environmental Assessment Data Base Re- port—Hittman Associates, Inc., is updating a 1978 report, En- vironmental Assessment Data Base for Coal Liquefaction Technology. Volume I of this document (EPA-600/7-78-184a) includes process descriptions, efficiencies, and state-of-the- art summaries for 14 liquefaction processes. Volume II (EPA—60017-78-184b) is an environmental characterization re- port which focuses on the H—Coal, Exxon Donor Solvent (EDS), and Synthoil processes. Detailed estimates are given for the raw waste streams, treatment/control processes, treated waste stream discharges, and associated environ- mental effects. The revised report will examine the 14 original proc- esses, with particular emphasis on the most advanced direct liquefaction processes, for example, SRC—l, SRC-ll, H—Coal, and EDS. The revised Volume I will discuss: • Overall technology status. • Coal liquefaction process operations (coal pretreat- ment, coal liquefaction, separation, and product purifi- cation and upgrading). • Pollution control modules. • Technology assessment summary. In-depth evaluations of the system operations and pollution control modules will be presented in the revised Volume II. The revised report will be accompanied by an overview document summarizing the information on costs, efficien- cies, commercialization potential, environmental impacts, and discharge streams. The data base revision will be completed in the summer of 1980. For more information on the original report, see the Environmental Review of Synthetic Fuels, Vol. 1, No. 3 and Vol. 2, No. 2. ENVIRONMENTAL DATA ACQUISITION Gasification Source Test and Evaluation Programs—Source Test and Evaluation (STE) programs comprise a major portion of an environmental assessment of synthetic fuels technologies. The major goal of each STE program is to gather the data required for evaluating (1) the environmental and health effects of the multimedia waste streams at specific facilities and (2) the associated control technology. Radian Corporation has completed two STE programs, and the final reports are now available. The first STE report (EPA-600/7-79-185) concerns a facility which uses a Well- man-Galusha gasifier, and the second (EPA-600/7-78-202) deals with Chapman low .Btu gasification. (Some major conclusions from the first report are presented in the “Report Summary” section of this issue.) Radian is conducting additional STE programs at four other facilities. Three of these are U.S. sites incorporating Weilman-Galusha, Riley Morgan, and Foster Wheeler/Stoic gasifiers, respectively. The fourth is a Lurgi gasification facil- ity (Kosovo Kombine) at Obilic, Yugoslavia. Results from these efforts will be summarized in subsequent issues of the Environmental Review of Synthetic Fuels as the final reports become available. (For more information on the Kosovo program, see the Environmental Review of Synthetic Fuels, Vol. 2, No. 3. Also, Hittman Associates, Inc.’s STE’s of a SRC II pilot plant are described in Vol. 2, No. 4). Test Run Results Compared to Model Predictions for Fluidized Bed Gasifier—Preliminary test run results from the coal gasification and gas cleaning facility at North Carolina State University (NCSU) compare favorably with those pre- dicted by a kinetic model. The NCSU facility is providing environmental assessment data concerning both the gasification and gas clean-up processes, It incorporates a pressurized (0.8 MPa 1100 psig)) fluidized bed reactor capable of gasifying a 6.3-g/s (50-lblhr) coal feed stream. The raw product gas passes through a particulates, condensables, and solubles removal (PCS) system, which consists of a cyclone separator followed by a venturi scrubber. Acid gas removal occurs downstream from the venturi scrubber in two packed towers (an absorber and a stripper) separated by a rich solvent flash vessel. Table 1 shows results from one of the gasifier test runs, along with the model predictions for a fluidized bed gasifier. This particular test run involved steam-oxygen gasification of pretreated Western Kentucky #11 bituminous coal (10 x 80 mesh size). Only the gasifier and PCS system were used, without integration of the acid gas removal system. Coal was fed at an average rate of 3.2 g/s (25.6 lb/hr); the average bed temperature and pressure were 971 C (1780 F) and 0.8 MPa (100 psig), respectively. The comparison shown in Table 1 demonstrates a strong correlation between experimental results and model predictions. Both the actual carbon conversion in the reactor and the product gas flow rate were lower than predicted, and this may be attributable to imperfect mixing in the reactor and uncertainties in kinetic parameters. In addition, since the model is for an ideal adiabatic reactor, it predicted less 02 than was actually required. For more information on the NCSU facility, see the Environ- mental Review of Synthetic Fuels, Vol. 2, No. 4. TABLE 1. COMPARISON OF TEST RUN RESULTS WITH FLUIDIZED BED MODEL PREDICTIONS 5 Parameter Model Prediction Experimental Results Carbon Conversion, % 45 42 02 Required, Nm 3 /s 0.63 (1.40 scfm) 0.74 (1.65 scfm) Product Gas Rate Nm 3 /s, N 2 free 3.82 (8.5 scfm) 3.42 (7.6 scfm) Product Gas Composition % N 2 free basis H2 CO C02 CH 4 H 2 0 29 20 15 1 35 26 18 16 0.5 39 a Department of Energy, Coal Conversion Systems Data Book, Report HCP-12286-01, Washington, D.C., 1978. 2 ------- Environmental Review of Synthetic Fuels March 1979 TABLE 2. PNA HYDROCARBONS IN COAL GASIFICATIONb TAR Test Run Production Factor ( g/gC) illinois Montana Wyoming Western Kentucky North Dakota Compound No. 6 Rosebud Smith-Roland No. 9 Zap Lignite Naphthalene 570 440 160 930 37 Benzothiophene 120 30 12 48 5 C i & Ci—naphthaienes 410 550 550 370 140 Biphenyl Acenaphthylene d 72 360 51 320 43 49 60 200 15 22 Acenaphthened 89 73 93 13 Fluorened 180 220 84 180 28 Phenanthrene d 470 250 95 470 27 Anthracened 160 97 35 170 11 Fluoranthene° 260 130 32 160 9.4 Pyrened Benzo(a)anthracene d 190 92 110 120 26.0 5.2 110 78 3.8 0.72 Chrysened Benzo(b)fiuoranthoned Benzo(k)fluoranthened 80 59 30 3 44 21 7.4 1.6 1.2 93 33 21 0.71 0.22 0.14 Benzo(e)pyrene Benzo(a)pyrened indeno(1,2,3-cd)pyrene ’ 39 66 2.1 34 48 30 0.87 1.4 <0.29 27 39 9 0.072 0.12 <0.14 Dibenzo(a,h)anthracene’ 52 60 <0.29 12 <0.14 Benzo(g,h,i)perylened 36 48 <0.29 6 <0.14 Crude Tar 33000 18000 29000 30000 7300 a Determinations from gas chromatography-flame ionization detector. bFixorj bed gasification of 8 x 16 mesh coal at 1.4 MPa (200 psia). g product compoundlg coal loaded. EPA priority pollutant. Pollutants from Synthetic Fuels Production—Research Triangle institute (RTI) is conducting a project to measure the wide spectrum of pollutants generated by coal gasification under a variety of experimental conditions. Over 60 laboratory gasifier runs have been completed using nine different fuels, including peat, lignite, subbituminous coal, bituminous coat, and anthracite. Experimental variables include coat type, pretreatment condition, mesh size, reactor pressure, and temperature. Several gasifier effluent streams such as reactor residue, tar and water condensates, and prod. uct gas have been analyzed to determine the nature and concentrations of various species. Ames bioassay studies on the tars and their fractions have shown active mutagenicity, which is attributed largely to the presence of polynuclear aromatics (PNAs). The experimental procedure involves removing tar and aqueous condensates from the gasifier and separating them by filtration. The tar is then fractionated, and the various fractions are analyzed by gas chromatography and mass spectrometry. Table 2 presents typical values for PNA hydrocarbons in coal gasification tar and aqueous condensates. These results were obtained under similar gasification conditions for five U.S. coals, ranging from lignite to bituminous. Except for C 1 — and C 2 -naphthalenes (which have been grouped), the compounds are presented in order of increasing boiling point. All 16 of the EPA Consent Decree List PNAs were found in the tar. As shown in Table 2, large variations occur in the yield of PNA compounds from the various coats tested. The largest PNA yields are associated with the higher rank bitu. minous coals. The Montana Rosebud coal gave rise to relatively high levels of 5- and higher-ring PNAs. Future studies will identify and quantify the specific chemical species in gasifier tar which contain nitrogen, sul- fur, and oxygen. Studies will examine the toxic and mutagen- Ic properties of both the specific compounds and the fractions in which those compounds occur. For instance, the tar base fraction is known to exert a strong influence similar to that associated with PNAs. The specific compounds responsible for this effect will be explored by chemical analysis and bioassay testing of the tar base fraction. Results from RTI’s ongoing research will be reported in subsequent issues of the Environmental Review of Synthetic Fuels. (For information on earlier studies, see Vol. 1, Nos. 1, 2, and 3; and Vol. 2, Nos. 2, 3, and 4. See also the three final reports which are now available and are listed in “Recent Major Papers arid Publications” in this issue.) Sampling Completed at Koppers-Totzek Facility—TRW, mc., has completed a sampling program at the commercial Koppers-Totzek facility at Modderfontein, South Africa. The sampling program, conducted jointly with Krupp-Koppers of West Germany, represents a major internationally coordi- nated effort to obtain and analyze environmental data on the Koppers-Totzek gasification system. Results should aid greatly in determining the impact of similar commercial facil- ities in the U.S. Multimedia samples are being analyzed in South Africa at both the Modderfontein plant laboratory and the nearby MacLachlan and Lazar analytical laboratories. In addition, portions of the water samples were preserved and air- shipped to TRW for detailed Level 2 analyses. Results from these efforts will be published when availa- ble in subsequent issues of the Environmental Review of Synthetic Fuels. 3 ------- Environmental Review of Synthetic Fuels March 1979 SAC Production Costs May Double—The costs of two solvent refined coal (SRC) projects may be twice the amount estimated prior to preliminary design. One of the demonstration plants is to be built in Morgantown, WV, and involves an agreement between the United States, the Federal Republic of Germany, and Japan to share responsi- bility for financing the project. The Morgantown plant has been designed to produce liquid synthetic fuels roughly equivalent to 3180 m (2 x 10 bbls) per day. A similar fa- cility, planned for Newman, KY, will demonstrate coal con- version to solid fuels. The price for each of the two SRC plants, originally set at $700 million, Is now expected to exceed $1 billion. This means product cost may approach $220lm ($35/bbl). At first, DOE officials attributed the cost increases to Infla- tion, construction expenses, and extension of plant lifetime from 2 years to 5. Low coal reactivity, mountainous terrain, and plans for increased coal stockpiling are cited in a more recent DOE disclosure concerning additional costs at the Morgantown facility. Despite Increased costs, DOE and Congress have de- cided to continue their support of the two demonstration projects. The West German government has reinforced their commitment, and negotiations are reportedly un- derway to broaden support to Include research and com- mercialIzation costs. Japan Is expected to follow suit. The goal of the projects is to provide technical, economic, and environmental information to private Industry to aid in the development of a comprehensive synthetic fuels program. (For additional Information on the Morgantown project, see Environmental Review of Synthetic Fuels, Vol. 2, No. 2.) Callettsburg ProI.ct Recilvos More Funding—A desire to speed commercialization of a coal liquefaction process has prompted the Senate Appropriations Committee to Increase DOE’s 1980 H-Coal project budget by $7.5 million. The money would finance a 2-year commercialization study of the Catlettsburg, KY, H-Coal pilot plant operated by Ashland Oil. It is possible that plans for a demon- stration-sized facility would then be bypassed, and funding directed toward construction of a commercial-sized complex. If accelerated, the program could result in the operation of a facilIty capable of producing 3180 m (2 x 10 bbls) of synthetic fuel daily by 1985. (For additional in- formation on the Catlettsburg project, see Environmental Review of Synthetic Fuels, Vol. 1, No. 2, and Vol. 2, No. 1.) New Technique T.sted for in-Sftu Gasification— Hoe Creek, WY, was the test site for a new technique Involving in-situ coal gasification. Engineers from Lawrence Liver- more Laboratory linked vertical wells with a horizontal channel in a successful effort to control the direction of coal combustion. The new technique avoids problems incurred when gasification is attempted utilizing natural channels which may become blocked or may burn in unde- sired directions. Oxygen-enriched air was used to promote combustion and stabilize burn rates, thereby providing more consistent gas flows. Gas produced by the Hoe Creek project could be utilized for heating or may serve as raw material for the production of ammonia, methanol, or gasoline. It was esti- mated that over 4.5 Gg (5000 tons) of coal have been gasi- tied. First Eastern Coal Gasified Underground—For the first time, eastern coal has been successfully gasified in situ during a DOE test near Princeton, WV. Reverse combustion was accomplished via a technique involving ignition at the base of one borehole and the introduction of pressurized air into another borehole to direct the combustion path- way. Previous attempts to gasify eastern coal had been hampered by the tendency of the coal to swell and elimi- nate air pathways needed for continued combustion. The Princeton project was expected to convert about 907 Mg (1000 tons) of bituminous coal, and was reported to pro- duce over 28,000 m 3 (1 x 10 ft 3 ) of synthetic gas per day. The heating value of the gas synthesized was estimated to be 20 percent that of natural gas. IGY Promotes Synthetic Fuel Development—Institute of Gas Technology (IGT) president, Bernard S. Lee, recom- mends extensive proliferation of synthetic fuels production facilities. This suggestion was based on an IGT study indi- cating that synthetic fuels produced from domestic coal and mineral supplies are more economical than foreign oil sub- ject to inflation, U.S. currency devaluation, and supply incon- sistency. The proposed $90 billion expenditure would allow construction of plants capable of supplying the 400,000 m 3 (2.5 x 100 bbls) per day production goal set by President Carter for 1990. Economics of Alternative Fuels Discussed—At present, synthetic fuels produced by coal gasification and liquefaction are more expensive than natural oil and gas. This was the general consensus of attendants at the World Petroleum Congress held In Bucharest. Presentations and discussions focused on the costs, technology, and prac- ticality of synthetic fuel production. It was agreed that technology is available to produce synthetic fuels, but reductions in initial investment costs are needed to improve the competitive status of coal conversion. Another problem faced by the synthetic fuels industry is the low thermal efficiency of its primary products. The cost of refining coal is proportional to the quality of the product, so that gasoline from coal is very expensive. It is possible that cost inequi- ties may be overcome if oil and gas prices escalate more rapidly than the costs entailed by plant construction and synthetic fuels production. A few examples of alternative fuel sources which are ec- onomically attractive were cited. The SASOL plant in South Africa gasifies coal to obtain feedstocks for ammonia syn- thesis. Oil sands and oil shale deposits may also provide cost efficient alternative fuel sources. Great Canadian Oil Sands, a subsidiary of Syncrude Canada Ltd., produced 2,600,000 m 3 (16.4 x 10’ bbls) of synthetic crude oil in 1977 and 1978 at an average cost of $53.871m 3 ($8.S4Jbbl). Con- tinually increasing oil and gas prices justify further development of these resources. Response to DOE Low/Medium Btu Coal Gasification Program Continues—DOE is considering five new proposals received in response to announcement of its LowlMedium Btu Coal Gasification Program. Coal conversion technology and industrial utilization of low and medium Btu gas will be the subjects of DOE funded study. Eight contracts valued at over $1.8 million have already been granted since the program was initiated in March. Utilities and industries located in New Jersey, Mississippi, West Virginia, Missouri, and Illinois have submitted the five proposals, valued at $500,000, which are now receiving consideration. Further selection of a third set of proposals is expected to occur this year. (For additional information on the DOE program, see the Environmental Review of Synthetic Fuels, Vol. 2, No. 4.) TECHNOLOGY AND COMMERCIAL DEVELOPMENT 4 ------- Environmental Review of Synthetic Fuels March 1979 New Gasification Processes Increase Capacity— Krupp- Koppers GmbH (Essen, W. Germany) is testing a modifica- tion of the Koppers-Totzek process which allows coal gasif i- cation to proceed at twice original capacity by doubling the number of feed injectors on the gasifier unit. The modified Koppers-Totzek design replaces the standard two-headed gasifier with a four-headed system. Advantages attributed to the new unts include investment savings, lower specific heat losses, and a reduction in the amount of space needed for operation. Two 95 kg/s (900 ton/d) fertilizer plants in India will serve as sites for the initial commercialization of the system. A Brazilian company, Petrobas, also plans to operate a pair of four-headed gasifiers to supply synthesis gas for a 6.3 Kg/s (600 ton/d) ammonia plant. In addition, Shell Oil Company has assisted Krupp- Koppers in designing a high pressure gasification process which may increase operation capacity to 12 times the origi- nal Koppers-Totzek process. The standard Koppers-Totzek system is operated at atmospheric pressure, whereas the Shell Koppers process would be run at 3 MPa (30 atm), reducing the amount of compression synthesis gas must undergo prior to usage. A Shell Koppers demonstration plant in Germany is reported to synthesize gas which is 10 percent cheaper than raw gas obtained via the original process. BGC Lurgi Slagging Gasifier and Texaco Unit Team Up—The advantages of a SNG production process using two synergistic slagging gasifiers may promote its rapid commer- cialization. The Fluor combination coal gasification process utilizes a British Gas Company Lurgi slagging gasifier in conjunction with a Texaco gasification unit. Dual gasification equipment installed at the SNG plant chosen for study resulted in increased productivity and lowered costs in comparison to conventional Lurgi coal gasification facilities. Operation of the combined system is dependent on waste heat steam generation, eliminating the need for coal-fired boilers. Phenolic liquors produced in Lurgi gasification processes balance liquid requirements for Texaco slurry preparation. Costly treatment of process water to remove ammonia and phenols is unnecessary, and phenolic liquors no longer constitutue a disposal problem because they are gasified. The process also results in primary methane which can be used in methanation of the SNG product. One study presented cost comparisons between the combined gasifier system and a conventional Lurgi plant and indicated that $300 million in total plant capital could be saved by the combination system in the production of a given amount of SNG from a given amount of coal. Water Issue Provokes Controversy—Water availability may prove to be a major Issue in the future of a synthetic fuels program. The director of the U.S. Water Resources Council, Leo Eiset, claims that no comprehensive program exists to supply the needs of plants which must be built to meet President Carter’s synthetic fuels production goals. The economics of coal gasification and liquefaction are improved if plants are located near coal deposits. Northern plains states, which represent a significant proportion of coal-bearing areas in the United States, are concerned that water allocations for future synthetic fuels plants may threaten existing water users. Estimates of the volume of water to be consumed by commercial coal conversion facilities vary considerably. Anywhere from 15,000 to 235,000 m 3 (4 to 62 x 10’ gal) of water could be used daily by a commercial scale liquefaction plant. More information from demonstration-sized facilities is necessary to assess fully the influence that the water controversy may have on synthetic fuels industries. Nickel Catalyst Enhances Gasification and Liquefaction Processes—Researchers at Battelle Memorial Institute have developed a new solution that catalyzes coal conversion pro- cesses. The solution, which contains hydrogen and a dissolved transition metal catalyst, reacts more efficiently with coal than does molecular hydrogen alone. The nickel Ziegler catalyst is prepared by reacting nickel carboxylate with an aluminum alkyl in an organic solution. Hydrogen is then added to the product to form the catalytic solution. EPRI Spokesmen Testify Before Con g,ess—At recent congressional hearings EPRI division directors, Balzhiser and Spencer, nominated the electric utility industry as a primary market for synthetic fuels, and called for cooperation be. tween government and industry to develop, demonstrate, and commercialize a synthetic fuels program. Balzhiser con- tended that the requirements of utility plants are flexible enough to allow them to serve as the initial market for a synthetic fuel industry. The possibility of this stable market represents a mutual advantage to synthetic fuel development in that capital investment risks are lessened. Spencer cites the 1978 power plant and utility Fuel Use Act (FUA) which should compel the electric utility industry to increase syn- thetic fuel utilization, and pointed out EPRI studies which indicate the economic attractiveness of coal gasification combined cycle power generation. SASOL Technology May Serve U.S. Needs—South African technological expertise in synthetic fuels manufacture is being marketed in the U.S. through an agreement between SASOL, Ltd. (Johannesburg, South Africa) and Fluor Engineers and Constructors, Inc. SASOL and Fluor are presently conducting a feasibility study for Texas Eastern Corp. Texas Eastern is considering an Ohio River Valley plant which would combine Lurgi gasification and Fischer Tropsch processes. SASOL uses similar indirect liquefaction processes to produce oil from coal and con- tends that direct liquefaction process technology may not be feasible in the near future. Fluor maintains that a SASOL- type plant completed in 1985 could result in synthetic fuel which would be competitive in price with fuels produced by conventional refineries using $300/rn 3 ($48/bbl) crude oil. (For more information on SASOL plants, see Environmental Review of Synthetic Fuels, Vol. 1, No. 3.) SASOL II Nears Completion—The Secunda, South Africa, SASOL II project is nearing construction completion and is ready to begin testing its Lurgi gasification equip- ment. The SASOL II plant will produce gasoline, fuel oil, and a variety of chemical feedstocks via a series of gasification, liquefaction, and refining techniques. It is expected that annual product yield will exceed 1.5 Tg (1.5 x 10’ metric tons). If all goes as planned, full production should be possible by the end of 1980. The SASOL II project will differ somewhat from a sibling project in Sasolburg, South Africa. Tailgas from the new plant will be recycled to optimize liquid fuel production rather than utilized for towngas production. This will result in a thermal efficiency rating which is lower (40 percent) than that of the older plant (60 percent). Federal Support Would Speed Commercialization of Over 30 GasifIcation Facilities—Continued governmental support of the synthetic fuels industry could result in com- mercialization of over 30 high Btu coal gasification facilities capable of producing 85 km 3 (3 x 10’ ft 3 ) of gas by the turn of the century. This was the opinion voiced by American Natural Resources Vice President, William T. McCormick, Jr., at the annual meeting of the Pacific Coast Gas Association. McCormick reviewed seven coal gasification projects which are in the design stage, emphasizing the Mercer County, ND, project which is closest to construction. The ND plant would utilize Lurgi gasification with methanation, as would the majority of the projects McCormick discussed. Federal support of these projects will increase the probability of commercial operation by the mid-1980’s. ------- Environmental Review of Synthetic Fuels March 1979 PROJECT TITLES, CONTRACTORS, AND EPA PROJECT OFFICERS IN EPA’S IERL-RTP SYNTHETIC FUEL ENVIRONMENTAL ASSESSMENT PROGRAM Project Title Contractor EPA Project Officer Environmental Assessment of Low Btu Gasification (March 1979-March 1982) James D. Kilgroe IERL-RTP Environmental Protection Agency Research Triangle Park, NC 27711 (919)541-2851 Environmental Assessment of HIgh-Btu Gasification (April 1977 -AprIl 1980) TRW, Inc. 1 Space Park Redondo Beach, CA 90278 (213)536-4105 (Chuck Murray) William J. Rhodes IERL-RTP Environmental Protection Agency Research Triangle Park, NC2771 1 (919)541-2851 Environmental Evaluation of Coal Liquefaction (July 1979-July 1982) Hlttman Associates, Inc. 9190 Red Branch Road Columbia, MD 21043 (301) 730-7800 (Jack Overman) D. Bruce Henschel IERL-RTP Environmental Protection Agency Research Triangle Park, NC 27711 (919) 541-2825 Acid Gas Cleaning Bench Scale Unit (October 1976-September 1981) (Grant) North Carolina State Univ. Department of Chemical Engineering Raleigh, NC 27807 (919) 737-2324 (James Ferrell) Robert A. McAllister IERL-RTP Environmental Protection Agency Research Triangle Park, NC 27711 (919) 541-2708 Water Treatment Bench Scale Unit (November 1976-October 1961) (Grant) Univ. of North Carolina Department of Environmental Sciences and Engineering School of Public Health Chapel Hilt, NC 27514 (919) 966-1023 (Philip Singer) Robert A. McAllister IERL-RTP Environmental Protection Agency Research Triangle Park, NC 27711 (919)541-2708 Pollutant Identification From a Bench Scale Unit (November 1976-October 1981) (Grant) Research Triangle Institute P.O. Box 12194 Research Triangle Park, NC 27709 (919)5416000 (Forest Mixon) N. Dean Smith IERL-RTP Environmental Protection Agency Research Triangle Park, NC 27711 (919) 541-2708 Radian Corporation 8500 Shoal Creek Blvd. Austin, TX 78766 (512) 454-4797 (Gordon C. Page) 6 ------- REPORT SUMMARY Environmental Assessment: Source Test and Evaluation Report — Weliman-Galusha (Glen-Gery) Low-Btu Gasification (EPA-60017-79-1 85) by W. C. Thomas, K. N. Trede, and G. C. Page Radian Corporation Environmental Review of Synthetic Fuels March 1979 The Wellman-Galusha gasification system is one of the few types of coal gasifiers applied commercially in the U.S. at this time. At the York, PA, plant of the Glen-Gery Brick Co., a Weliman-Galusha gasification system is used to convert anthracite coal into a low-Btu gas which is then used as a fuel for a brick kiln. This facility was selected for study in a Source Test and Evaluation (STE) program recently completed by Radi- an Corporation. The major goal of this STE program was to perform an environmental assessment of the waste streams from the gasification system. The Glen-Gery facility was selected for the STE program for several reasons. For one, it uses a com- mercially operating gasifier typical of those currently in service in the U.S. The Glen-Gery facility also affords an opportunity for significant contribution to the low-Btu gasification technology data base for systems using an- thracite. Such installations yield a raw product gas that is essentially tar- and oil-free. This feature simplifies the task of obtaining representative process and waste stream samples for environmental characterization. In addition, because this facility is part of the U.S. Department of Energy’s (DOE’s) Gasifiers in Industry Program, it includes special instrumentation that facilitates the collection of both process and environmental data. A complete environmental assessment of a process requires thorough examination of both the compositions and the flow rates of multimedia process and waste streams. Samples of 12 process and waste streams were obtained, as well as flow rate data and data for several operating parameters. The major results from these efforts are summarized below. Waste Stream Characterization The seven multimedia waste streams sampled at Glen- Gery were characterized through bioassay testing and SAM/lA (Source Analysis Model) evaluation. The SAM/IA evaluation, based on chemical analyses, provides a rapid screening technique for evaluating the pollution potential of multimedia waste streams. It is applied as part of EPA’s standardized methodology for interpreting results from environmental assessment test programs. Two evaluation indices are used in performing a SAM/IA evaluation: Discharge Severity (DS), and Weighted Discharge Severity (WDS). The individual DS values for components of a discharge stream may be summed to give the Total Discharge Severity (TDS) for that stream. (These terms are explained more fully in the Environmental Review c f Syn- thetic Fuels, Vol. 2, No. 4.) Bioassay analysis involved testing both health and ecological effects, as described in the EPA Level 1 Envi- ronmental Assessment Manual (EPA-600/2-76-160a). Figures 1 and 2 summarize the SAMIIA evaluation and bioassay test results for the seven multimedia waste streams sampled. As shown, all seven waste steams have a poten- tial for hazardous effects according to the SAM/IA evalu- ation. However, the TDS values reported for the Glen-Gery facility were, in general, lower by two orders of magnitude when compared to TDS values reported for a bituminous coal gasifier in a previous study (EPA-60017-78-202). Results of the bioassay screening tests also support the relatively low potential for harmful effects associated with the Glen-Gery waste streams. In addition, the harmful effects of the gaseous waste streams are reduced because of their low flow rates. Table 3 presents major conclusions and recom- mendations of the STE, based on SAMIIA and bioassay test results. Also shown are priorities, based on the SAM/IA evaluation, for future chemical analyses for each waste stream. Specific compounds should be identified where the worst case unidentified organics are the main contributors to the DS. •For a description of the current EPA methodology, see EPA-6OO/2-78 201. Ash Sluice Gasitier Ash Gasifier Ash Cyclone Dust Cyclone Dust Water Leachate Leachate Ash more toxic than cyclone dust in the soil microcosm test H: High Effects M: Moderate Effects L/ND: Low or Nondetectable Effects FIGURE 2. BIOASSAY TEST RESULTS FOR THE GLEN-GERY WELLMAN-GALUSHA WASTE STREAMS • HEALTH ECOLOGICAL H- M- L/ND- Poke Coal Ash Gasitier Gasif:er Cyclone Cyclone Raw Hole Hopper Sluice Ash Ash Dust Dust Product Gas Vent Water Leachate Leachale Gas FIGURE 1. TOTAL STREAM DISCHARGE SEVERITIES FOR THE GLEN-GERY WELLMAN-GALUSHA WASTE STREAMS 7 ------- Ei*smsntal ol Synthetic Fuels March 1979 TABLE 3. SUMMARY OF THE CHARACTERIZATION OF WASTE STREAMS FROM THE GLEN-GERY FACILITY Priority for Quantitative Chemical Analysis High Me&um Low Waste Stream (Tos, 102 +) (TDS, 10.10’) (lOS, 1-10) Conclusions Recommendations Pokehole Gas CO. NH As, COT, H S CH 4 , NHs, HCN, • potentially hazardous • better seals LI, Ni, SO according to SAMIIA evaluation • better maintenance low flow • ventilation injection of inert gas during poking operation Coal Hopper Gas CO. Fe(CO). 142 5 Cli ., C02 • potentially hazardous • collect and recycle to according toSAMIIA inlet air or vent evaluation to atmosphere • low flow • keep workers out of area Ash Sluice Water Fused Polycyclic Fe, Ti Phthalate • potentially hazardous • collect and reuse Hydrocarbons, Esters, Ba, Cd, according to SAMIIA as ash sluice water Alkenes, Cyclic Cr, Cu, CN, Fe, evaluation Alkenes, Dienes, La, LI, Ni, V and Nitrophenols • low potential for hazard according to bioassay tests • W.. and EC.. were above maximum dosages admini- stered • TDS, BOD, POI , and CN exceed the most stringent water effluent standards Ash Ba, Cr, Fe, Fused Poly. Alkenes, Cyclic • potentially hazardous • landfill is a possible U, Mn, Ni cyclic Hydro. Alkenes and according to SAMIIA drsposal technique carbons, Be, Dienes, Aromatic e” uation Co, Cu, Fe, Amines and Pb, Ni, Se, Diamines, Ring • bioassay tests indicate • further analyses for Th, V, Zr Substituted a low potential for unidentified organ ics Aromatics, Nitro- hazard and bioassay tests for phenols*, Phtha- ecological effects late Esters, Al, • W.. and ECs. were above As, Ba, Bi, Cd, maximum dosages admin- Ca, Cr, Hf, Pb, istered Li, Mg, Mn, Si, Ag, Sr, Ti, V, V 8 ------- Environmental Review of Synthetic Fuels March 1979 TABLE 3. SUMMARY OF THE CHARACTERIZATION OF WASTE STREAMS FROM THE GLEN-GERY FACILITY (CONTINUED) Priority High for Quantitative C Medium hemical Analysis Low Waste Stream (IDS, 102 4-) ifos, io-io (TDS, 1-10) Conclusions Recommendations Ash Leachate Fused Poly- Phthalate Cd, Ag • potentially hazardous • further analyses for cyclic Hydro- Esters, Zn according to SAMIIA unidentified organics carbons, evaluations and bioassay tests for Allcenes, ecological effects Cyclic Alkenes, • bioassay tests indicate Dienes, Aroma- low potential tic Amines and Diamines, • LD 3 , and EC o were above and Nitro- maximum dosages phenols administered • RCRA standards are not exceeded for trace elements Cyclone Dust Fused Poly- Alkenes, Cy- Phthalate • potentially hazardous • landfill may not cyclic Hydro- clic Alkenes, Esters, Al, according to SAM/IA be acceptable carbons, and Dienes, Sb, As, Ba, evaluation As, Ba, Cr, Aromatic Ca, Cr, Co, • incineration Fe, Pb, Li, Amines and Cu, F, Ga, • small flow rate Mn, Ni, Se Diamines, Ring- Hf, Li, Mg, Substituted Hg, Se, Si, • bioassay tests indicate Aromatics, Sr, TI, Ti, low potential for hazard Nitrophenols, V, Y, Zr Be, Cd, Fe, • LD5O and EC . were Pb, Mn, Ni, above maximum dosage Ag, Th, V, Zn administered Cyclone Dust Mn, Zn, Mn, Pb, Al, Cd, Co, • potentially hazardous • quantitative analysis Leachate Fused Poly- Alkenes, Cu, Fe, Pb, according to SAM/IA for Pb to determine cyclic Cyclic Alkenes, Li evaluation if Its concentration Hydro- Dienes, and actually exceeds carbons Nitrophenols • bioassay tests indicate RCRA guidelines low potential for hazard • F exceeds most strin- gent water effluent standards • Pb exceeds RCRA standards •These categories of organic compounds contain the worst case compounds which provide the largest potential discharge severity for the unidentified organics of each waste stream. The categories and their corresponding worst case compounds are listed below: Category Compound Fused Polycyclic Hydrocarbons 7, 12-Dimethylbenz(a)anthracene Alkenes, Cyclic Alkenes and Dienes Dicyclopentadiene Aromatic Amines and Diamines Amlnonaphthalenes Ring-Substituted Aromatics Dibromobenzene Nitrophenols Dinitrophenols 9 ------- Environmental Review 01 Synthetic Fuels March 1979 MEETING CALENDAR 2nd Annual Symposium on Industrial Energy Conservation Technology and Exhibition, April 13-16, 1980, Houston, TX. Contact: Milt Williams, 6203 B Shadow Valley Drive, Austin, TX 78731; telephone (512) 345-8052. 2nd Annual Symposium on industrial Coal Utilization, April 17-18, 1980, Charleston, SC. Contact: Dan Bienstock, PETC, 4800 Forbes Ave., Pittsburgh, PA 15213. 88th AIChE National Meeting and 2nd Chemical Plant Equipment ExposItion, June 8-12, 1980, Philadelphia, PA. Contact: Harold S. Kemp, DuPont Co., Engineering Dept. L—1257, Wilmington, DE 19898. 1980 Symposium on Instrumentation and Control for Fossil Energy Processes, June 9-11, 1980, Virginia Beach, VA. Contact: Richard Doering, Argonne National Lab, 9700 S. Cass Ave. Bldg. 316, Argonne, IL 60437; telephone (312) 972. 6086. 19th ASME-AIChE National Heat Transfer Conference—Heat Transfer in Coal Conversion, July 27-30, 1980, Orlando, FL. Contact: Professor Lawrence A. Kennedy, Dept. of Mechani- cal Engineering, 607 Furnas Hall, SUNY at Buffalo, Amherst, NY 14260; telephone (716) 636-2729. AIChE 72nd Annual Meeting RECENT MAJOR MEETINGS The American Institute of Chemical Engineers (AIChE) held their 72nd annual meeting in San Francisco, CA, on November 25-29, 1979. Panel discussions, symposia, and poster sessions covered a broad range of topics, including recent research and development in the field of coal con- version, gasification, and liquefaction. Several symposia included presentations on fluidization and fluid-particle systems. The results of research on bubble dynamics, magnetic stabilization, and particle deposition were reported. Papers dealing with physical properties of fluidization such as density, electrostatics, pressure fluctua- tions, heat transfer, and component velocities were also included. More specific presentations described fluidization and fluid particle systems in coal processing. Processes Such as elutriation and recycling of coal fines, ash agglomer- ation, and two-stage combustion appeared to result in emission reductions and greater combustion efficiency in experimental studies. In related sessions, papers focused on design and modeling of gas fluidized bed systems. Development of models has allowed study of the effects of coal feed velocity, jetting emulsion mass, attrition rates, and heat interchange on coal conversion. Experimental techniques for fluidized bed combustion (FBC) of coal char, high sulfur coal, and agglomerating bituminous coals were discussed. Several models were presented which may facilitate industri- al application of FBC experimental designs to generate steam and electrical power. Progress in the use of western coal to supply the needs of coal gasification, combined cycle power generation facilities was described in one symposium. Potential control technology costs and environmental assessment reports for low Btu gasification facilities and SRC-ll liquefaction operations were presented in two sessions on solid fossil fuel processes. One series of lectures on underground (In Situ) coal gasification included presentations on field results, computerized cost estimation, and commercialization possi- bilities. Several symposia on coal liquefaction techniques dealt with potential catalysts, free radical kinetics, and desulfurization compounds. One paper discussed the effect of aging on hydrotreating catalysts used in coal liquefaction. New data on rubidium- and iron-containing catalysts utilized in Fischer Tropsch s ñthesis reactions were presented. Further elucidation of free radical kinetics in the liquid phase reactions of coal conversion is possible via estimation meth- odology described by one author. Iron-containing com- pounds, including coal ash, were cited for their selectivity for hydrodesulfurization over hydrogenation, a characteristic which may prove valuable in development of future liquefaction processes. Multiphase reactors such as the H-Coal reactor and the Fischer Tropsch slurry reactor served as the topic for one session. Data obtained on phase dynamics and physical properties have allowed researchers to present models available for scaling up purposes. Several papers focused on thermodynamic analysis of synthetic fuel processing. The methodology of first law (thermal) and second law (availability) analyses was reviewed in one presentation. COED, HYGAS, and SYNTHANE pro- cesses were thermodynamically analyzed in this symposium, as well as a developmental direct liquefaction technique. A symposium was held on new computer applications in design and analysis. Several presentations were related to coal conversion applicability. One paper described synergistic cascade refrigeration and liquefaction systems. Another presented a mathematical model for the expected performance of a HYGAS gasifier. A two-part symposium on the status of synthetic fuels projects focused on current gasification and liquefaction plants and process development. The proposed Memphis U-Gas demonstration plant and pilot coal gasification plants operated by North Carolina State University and Combustion Engineering were the topics of three papers. HYGAS and GEGAS gas production, catalytic coal gasification, and a Brazilian ammonia production plant served as subjects for other presentations. Process development in coal liquefac- tion was described in papers on flash hydropyrolysis, the Exxon donor solvent process, and SAC-I. One company reported on a project which produces gasoline from coal in a single step process involving molten zinc chloride hydro- cracking. Research and development, major projects, and fort h- coming programs in international synthetic fuels technology served as the emphasis for another symposium. West German, South African, and Australian progress reports were presented. Shell Koppers summarized pilot plant gasification attempts. The United Kingdom’s National Coal Board and the British Gas Corporation also reported on the status of pro- cesses which they are developing for commercialization. More information on the 72nd Annual Meeting of the American Institute of Chemical Engineers can be obtained from the AIChE Continuing Education Department. Copies of the papers presented may be requested by contacting the Engineering Societies Library, United Engineering Center, 345 East 47th Street, New York, NY, 10017. 10 ------- Environmental Review of Synthetic Fuels March 1979 RELEVANT 1979 EPAIFUEL PROCESS BRANCH PUBLICATIONS Agreda, V. H., R. M. Folder, and J. K. Ferrell, Devolatilization Kinetics and Elemental Release In the PyrOlysis of Pulverized Coal, North Carolina State University, Raleigh, NC, Report EPA-60017-79-241, November 1979. Bostwlck, L. E., M. R. Smith, 0.0. Moore, and D. K. Webber, Coal Conversion Control Technology Volume I. En- vironmental Regulations; Liquid Effluents, Pullman Kellogg, Houston, TX, Report EPA-60017-79-228a, October 1979. Bostwlck, L. E., M. R. Smith, 0.0. Moore, and 0. K. Webber, Coal Conversion Control Technology Volume I I. Gaseous Emissions; Solid Wastes, Pullman Kellogg, Houston, TX, Report EPA-600 17-79-228b, October 1979. Buddea K. G., and S. P. Subhash, Air Emissions From Combustion of Solvent Refined Coal, i-iittman Associates, Inc., Columbia, MD, Report EPA-600/7-79-004, (NTIS PB 290946), January 1979. Chsn, C., C. Korelalç and 1. Breltatein, Control Technologies for Particulate and Tar Emissions from Coal Converters, Dynalectron/Applied Research Division, Bethesda, MD, Report EPA-60017.79-170, (NTIS PB 80-108392), July 1979. Ferrell, J. R., R. W. Rousseau, and 0. G. Bass, The Solublllty of Acid Gases In Methanol, North Carolina State University, Dept. of Chemical Engineering, Raleigh, NC, Report EPA-600/7-79.097, (NTIS PB 296707), April 1979. Gangwal, S. K., P. M. Grohse, D. E. Wagoner, 0. J. Mlnick, C. M. Sparacino, and R. A. Zweidinger, Pollutants from Synthetic Fuels Production: Sampling and Analysis Methods for Coal Gasification, Research Triangle institute, Research Triangle Park, NC, Report EPA-600 17-79-201, (NTIS PB 80- 104656), August 1979. Ghass.ml, N., K. Crawford, and S. Oulnhlvan, Environmental Assessment Report Lurgi Coal Gasification Systems for SNG, TRW Environmental Engineering Division, Redondo Beach, CA, Report EPA-600 17-79-120, (NTIS PB 298109), May 1979. Greenwood, 0. H., G. 1. Kingsbury, and J. G. Cleland, A Handbook of Key Federal Regulations and Criteria for MultImedia Environmental Control, Research Triangle In- stitute, Research Triangle Park, NC, Report EPA-600/7-79- 175, (NTIS PB 80-107998), August 1979. Hicks, R. E., 0. J. Goldstein, F. B. Seufert, 1. W. Wel, Waste- water Treatment in Coal Conversion, Water Purification Associates, Cambridge, MA, Report EPA-60017-79-133, (NTIS PB 297587), June 1979. Hoffert, F. 0., W. V. Soung, S. E. Stover, Summary of Gas Stream Control Technology for Major Pollutants in Raw in- dustrial Fuel Gas, Hydrocarbon Research, Inc., Lawrence Township, NJ, Report EPA-600/7-79-171, (NTIS PB 80-108251), July 1979. Hossain, S. N., P. F. CIllone, A. B. Cherry, and W. J. Wasylenko, Jr., Applicability of Coke Plant Control Technolo- gies to Coal Conversion, Catalytic, Inc., Philadelphia, PA, Report EPA-600/7-79-184, (NTIS PB 80-108954), August 1979. Kingsbury, G. L., R. C. Sims, and J. B. White, Multimedia En vironmental Goals for Environmental Assessment; Volume Ill. MEG Charts and Background Information Summaries (Cat- egories 1-12), Research Triangle Institute, Research Triangle Park, NC, Report EPA- 600/7-79-176a, August 1979. Kingsbury, G. L., R. C. Sims, and J. B. White, Multimedia En- vironmental Goals for Environmental Assessment, Volume IV. MEG Charts and Background in formation Summaries (Categories 13.26), Research Triangle Institute, Research Triangle Park, NC, Report EPA-60017-79-176b, August 1979. Onursal, A. B., Hot Gas Cleanup Process, Dynalectron Corpo- rationlApplied Research Division, Bethesda, MD, Report EPA—60017-79-169, (NTIS PB 80-108467), July 1979. Sama, K. R., and D. T. O’Leary, Engineering Evaluation of Control Technology for the H-Coal and Exxon Donor Solvent Processes, Dynalectron Corporation/Applied Research Division, Bethesda, MD, Report EPA-600!7-79-168, (NTIS PB 80-108566), July 1979. ShIelds, K. J., H. T. Hopkins, E. E. Weir, and C. Thompson, Environmental Assessment Report Solvent Refined Coal (SAC) Systems, Hittman Associates, Inc., Columbia, MD, Re- port EPA-600/7-79-146, (NTIS PB 300383), June 1979. Thomas, W. C., Technology Assessment Report for industrial Boiler Applications: Synthetic Fuels, Radian Corporation, Austin, TX, Report EPA-600/7-79-178d, November 1979. Thomas, W. C., K. N. Trede, and G. C. Page, Environmental Assessment: Source Test and Evaluation Report—Wellman Galusha (Gien-Gery) Low Btu Gasification, Radian Corpora- tion, Austin, TX, Report EPA—60017-79-185, (NTIS PB 80. 102551), August 1979. United States Environmental Protection Agency, Symposium Proceedings: Environmental Aspects of Fuel Conversion Technology, IV, April 1979, Hollywood, FL, Research Triangle Institute, Research Triangle Park, NC, Report EPA-600!7-79- 217, September 1979. Webber, D. K. and 0. E. Whlttaker, Environmental Standards I or Coal Conversion Processes: Volume I. Most Stringent, Federa4 and Selected State Regulations, Pullman Kellogg, Houston, TX, Report EPA-60017-79-231a, October 1979. Webber, D. K. and D. E. Whittaker, Environmental Standards for Coal Conversion Processes: Volume II. Selected State, Mexican, and Canadian Regulations, Pullman Ke llogg, Houston, TX, Report EPA-60017-79-231b, October 1979. 11 ------- Environmental Review of Synthetic Fuels March 1979 RECENT MAJOR PAPERS AND PUBLICATIONS GASIFICATION TECHNOLOGY Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Quarterly Technical Progress Report., October 25, 1976 - January 28, 1977. Report FE-2416-8, Con- tract No. EX-76-C-01-2416. Cambridge, MA, 18 March 1977. Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Annual Report, July 16, 1976- July 29, 1977. Report FE-2416-16, Contract No. EX-76-C-01-2416. Cambridge, MA, 30 September1977. Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Executive Summary. Interim Final Report., July 16, 1976 - February 15, 1978. Report FE-2416-24, Contract No. EX-76-C-O1-2416. Cambridge, MA, February 1978. Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Volume I. Technical. Interim Final Report., July 16, 1976 - February 15, 1978. Report FE-2416-24 (Vol. 1), Contract No. EX-76-C-01-2416. Cambridge, MA, February 1978. Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Volume II. Commerical Plant Economic Analysis. Interim Final Report., July 16, 1976- February 15, 1978. Report FE-2416-24 (Vol. 2), Contract No. EX-76-C-O1-2416. Cam- bridge, MA, February 1978. Badger Plants, Inc., Conceptual Design of a Coal to Methanol Commercial Plant. Volume IVB. Interim Final Report., July 16, 1976- February 15, 1978. Report FE.2416-24 (Vol. 4B), Contract No. EX-76-C-01-2416. Cambridge, MA, February 1978. Bamhart, J. S., P. E. George, H. G. Huang, and N. M. Laurendeau, Gasification in Pulverized Coal Flames. Semi-Annual Progress Report, April 1978- December 1978. Report FE-2029-8, Contract No. EX-76-C-O1-2029. Lafayette, IN, Purdue University, School of Mechanicat Engineering, 1978. Battelle Columbus Labs, Agglomerating Burner Gasification Process: Design, Installation, and Operation of a 25-ton-a-day Process Development Unit. Volume II. Report FE-1513-T-4, Contract No. EX-75-C-O1 -1513. Columbus, OH, May 1978. Bechtel Corp., Analysis of Coal Hydrogasiticat ion Processes. Quarterly Technical Progress Report., December 1, 1977 - February 28, 1978. Report FE-2565-13, Contract No. EF.77-A-01- 2565. San Francisco, CA. April 1978. Bituminous Coal Research, Inc., Gas Generator Research and Development: Bi-Gas Process. 85th Monthly Progress Report, September 1978. Report FE-1207-52, Contract No. EX-76-C-01- 1207. Monroevitle, PA, October 1978. Brandt, H., Triaxial Tests of Coal Gasification Samples. Report UCRL--13968, Contract No. W-7405-ENG-48. Davis, CA, Univer- sity of California-Davis, Dept. of Mechanical Engineering, 1978. Brennan, J. A., Development Studies on Selected Conversion of Synthesis Gas from Coal to High Octane Gasoline. Quarterly Report, October - December 1977. Report FE-2276--18, Contract No. EX-76-C-01-2276. Paulsboro, NJ, Mobil Research and Development Corp., January 1978. Brown, Richard, and Alice Witter, Health and Environmental Effects of Coal Gasification and Liquefaction Technologies: AWorkshop &jthmir, and Panel Reports. Report MTR-79W00137. NTIS PB-297 618, DOEIHEW/EPA-03. Contract No. DE-ACO1- 79EV10018. McLean, VA. Mitre Corp., METREK Div.. May 1979. Cameron Engineers, Inc., Coal Gasification. Quarterly Report October- December 1977. Report DOEIET-002414, Contract No. EX-76-C-01 -2297. Denver, CO, May 1978. Cavagnaro, D. M., Coal Gasification and Liquefaction Tech- nology. Volume 3. June 1976 - April 1978 (A Bibliography with Abstracts). Springfield, VA, National Technical Information Service, April 1978. Chem Systems, Inc., Liquid Phase Methanation Pilot Plant Operation and Laboratory Support Work. Quarterly Report, January 1, 1978 - March 31, 1978. Report FE-2036-26, Contract No. EX-76-C-01 -2036. New York, NY, June 1978. Clark, F. R., C. M. Packer, and R. A. Perkins, Development of Coatings for Corrosion Erosion Protection of Internal Corn po- nents of Coal Gasification Vessels. Quarterly Report, April 1, 1978- June 30, 1978. Report FE-2592-9, Contract No. EF-77-C-01- 2592. Palo Alto, CA, Lockheed Palo Alto Research Labs., 1978. Combs, L. P., and M. I. Greene, Hydrogasifier Development for the Hydrane Process. Fifth Quarter Report, March - May 1978. Report FE-2518-21, Contract No. EF-77-C-01-2518. Canoga Park, CA, Rockwell International Corp., Rocketdyne Div., July 1978. Conoco Coal Development Co., CO 2 Acceptor Process Gasif i- cation Pilot Plant: Run Reports. Final Report, Volume 8: Books 1-6, Runs 1-47, January 1972 - October 1977. Report FE-I 734- 41. Contract No. EX-76-C-01 -I 734. Library, PA, 1973. Conoco Coal Development Co., CO 2 Acceptor Process Gasif i- cation Pilot Plant: Support Studies by South Dakota School of Mines and Technology. Final Report, Volume 9: Book I of 2, Reports, February 1971 - January 1978. Report FE-i 734-42(V.9) (Bk.1), Contract No. EX-76-C-01-1 734. Library, PA, 1978. Conoco Coal Development Co., CO 2 Acceptor Process Gasif i- cation Pilot Plant: Commercial Plant Conceptual Design and Cost Estimate. Final Report, Volume 10: Book 1 of 3, North Dakota Lignite Gasification, Economics and Description, August 1976 - December 1977. Report FE-1734-43(V.10)(Bk.1), Contract No. EX-76-C.01-1 734. Library, PA, 1977. Conoco Coal Development Co., CO 2 Acceptor Process Gasif i- cation Pilot Plant: Commercial Plant Conceptual Design and Cost Estimate. Final Report, Volume 10: Book 3 of 3, Texas Lig- nite Gasification, August 1976- December 1977. Report FE-1734- 43(V.10)(Bk.3), Contract No. EX-76-C-01 -1 734. Library, PA. 1977. Conoco Coal Development Co., CO 2 Acceptor Process Gasili cation Pilot Plant: Executive Summary Commercial Plant Con- ceptual Design and Cost Estimate. Final Report, Volume 13, August 1976 - December 1977. Report FE-1734-46(V.13), Con- tract No. EX-76-C-01 -1734. Library, PA, 1977. Curran, G. P., C. E. Fink, D. C. McCoy, I. L. Zuber, and J. D. Ryan, CO 2 Acceptor Process Gasification Pilot Plant: Opera- tions. Final Report. Volume 6: Book 1 of 2, January 1972 - June 1973. Report FE-1734.39(Vol.6)(Bk.1), Contract No. EX.76-C-01- 1734. Library, PA. 1973. Curran, G. P., C. E. Fink, D. C. McCoy, I. L. Zuber, and J. D. Ryan, CO 2 Acceptor Process Gasification Pilot Plant: Opera- tions. Final Report, Volume 6: Book 2 of 2, Appendices, January 1972 - June 1973. Report FE-1734-39(V.6)(Bk.2), Con- tract no. EX-76-C-01-1734. Library, PA, 1973. 12 ------- Environmental Review ot Synthetic Fuels March 1979 Curtiss.Wright Corp., High Temperature Turbine Technology Program Phase II. Technology Test and Support Studies. Tech- nical Progress Report, January 1, 1978- March 31, 1978. Report FE-2291-29, Contract No. EX-76-C-01-2291. Woodridge, NJ, May 1978. Danyluk, S., and G. M. Dragel, Taphole Cooling Coil Failure: Grand Forks Energy Technology Center Fixed-Bed S/a gging Gasifier Pilot Plant. Failure Analysis Report. Report ANLIMSDI FE-78-9, Contract No. W-31-109-ENG-38. Argonne. IL, Argonne National Lab., June 1978. Elrick and Lavidge, Inc., Commercialization Focus Group In- terview: Medium- and Low-Btu Coal Gasification. Report DOE! TIC -10029, Contract No. EV-78-C-01-6457. San Francisco, CA, August 1978. Elrick and Lavidge, Inc., High-Btu Coal Gasification. Report DOEITIC-10034, Contract No. EV-78-C-O1-6457. San Francisco, CA, August 1978. Foh, S. E., and J. S. Gahimer, Evaluation of Integrated Water- Splitting/Coal Gasification Processes. Report CON F-771 203. In: Proceedings of the Miami International Conference on Alternative Energy Sources, Miami Beach, FL, December 5, 1977. pp.147-149. Gangwal, S. K., P. M. Grohse, D. E. Wagoner, D. J. Minick, C. M. Sparacino, and R. A. Zweidinger, Pollutants from Synthe- tic Fuels Production: Sampling and Analysis Methods for Coal Gasification. Report EPA-60017-79-201, NTIS PB 80-104656, Grant No. R804979. Research Triangle Park, NC, Research Tri- angle Institute, August 1979. Graft, R. A., J. Yerushalmi, and A. Lacava, Improved Techniques for Gasifying Coal. Seventh Quarterly Report, January 1, 1978- March 31, 1978. Report FE-2340-7, Contract No. EX-76-S-01 -2340. New York, NY, City College, April 1978. Hill, R. W., Hoe Creek No. 3 Pre Operational Report. UCID- 18013, Contract No. W-7405-ENG-48. Livermore. CA, University of California, Lawrence Livermore Laboratory, December 29, 1978. Institute of Gas Technology, Pipeline Gas from Coal Hydroge- nation (!GT Hydrogasification Process). Project 9000 Quarterly Report No. 6, October 1, 1977- December 31, 1977. Report FE- 2434-25, Contract No. EX-76-C-O1 -2434. Chicago, IL, August 1978. Institute of Gas Technology, Pipeline Gas from Coal- Hydroge- nation (!GT Hydrogasificat ion Process). Project 9000 Quarterly Report No. 7, January 1, 1978- March 31, 1978. Report FE-2434- 29, Contract No. EX-76-C-01-2434. Chicago, IL, August 1978. Kam, A. Y., and W. Lee, Fluid Bed Process Studies on Selec- five Conversion of Methanol to High Octane Gasoline. Report FE-2490-15, Contract No. EX-76-C-01-2490. Paulsboro, NJ, Mobil Research and Development Corp., April 1978. Kennedy, C. R., P. Swaroop, D. J. Jones, R. J. Fousek, A. B. Poeppel, and D. Stahl. Evaluation of Ceramic Refractories for Siagging Gasitiers: Summary of Progress to Date. Report ANL- 78.61. Contract No. W-31 109-ENG-38. Argonne. IL. Argonne National Lab.. September 1978. i .ocn, B. J., Phase I: The Pipeline Gas Demonstration Plant. Market Study for Sale of the Coal Fines By-Product from a Coal Gasification Plant. Report FE-2542.8, Contract No. EF.77- C.01-2542. Stamford, CT, Continental Oil Co., 1977. Koppenaal, D. W., Trace Element Studies on Coal Gasification Process Streams. Report TID-290-22, Contract No. EY-76-C-05- 0033. Columbia, MO, University of Missouri, September 1978. Leaman, G. J., Jr., Editor, Phase I. The Pipeline Gas Demon- stration Plant. Site Selection Report. Report FE-2542-3, Con- tract No. EF-77-C-01-2542. Stamford, CT. Continental Oil Co., 1977. Lewandowskj, G. A., Safety Analysis and Hazards Evaluation for Ii. S. Bureau of Mines, Twin Cities, Minnesota, Wellman- Galusha Coal Gasifier. Report FE-3193-1. Contract No. ET-78- C-01-3193. Springfield, NJ, Vector Engineering Inc., November 10.1978. Lewandowski, G. A., University of Minnesota, Duluth Campus, Stoic Coal Gasifier Safety Analysis and Hazards Evaluation. Report FE-3014-T1, Contract No. ET-78-C-01-3014. Springfield, NJ, Vector Engineering, Inc., 1978. Luthy, R. G., Design of Treatability Studies on Hygas Coal Gasification Pilot Plant Wastewaters. Report FE-2496-13, Con- tract No. EX-76-S-01-2496. Pittsburgh, PA, Carnegie-Mellon Uni- versity, Dept. of Civil Engineering, July 1978. Luthy, P. G., Manual of Methods: Preservation and Analysis of Coal Gasification Wastewaters. Report FE-2496-16, Contract No. EX-76-S-01-2496. Pittsburgh, PA, Carnegie-Mellon Univer- sity, Environmental Studies Inst., July 1978. Massey, M. J., P. G. Luthy, and R. W. Dunlap, Status of C-MU Environmental Activities at the Hygas Pilot Plant. Second Quarterly Report. Report FE-2496-8, Contract No. EX-76-S-01- 2496. Pittsburgh, PA, Carnegie-Mellon University, Environmen- tal Studies Inst., January 1977. Staege. Hermann, “Entrained-Bed Coal Gasifiers Handle Double Throughput,” Chemical Eng. 86(191:106-107,1979. Thomas, W. C., Technology Assessment Report for Industrial Boiler Applications: Synthetic Fuels. Report EPA-600i7.79-178d. Contract No. 68-02-2608, Task No. 49. Austin, TX. Radian Corporation, November 1979. Thomas, W. C., K. N. Trede, and G. C. Page, Environmental Assessment: Source Test and Evaluation Report-- Weilman- Galusha (Glen Gery) Low-Btu Gasification. Report EPA-60017- 79-185, NTIS PB 80-102551. Contract No. 68-02-2147, Exhibit A. Austin, TX, Radian Corp., August 1979. Thorsness, C. B., and R. J. Cena, In Situ Coal Gasification Modeling, Report UCRL--82269, CON F--790405 3, Contract No. W-7405-ENG-48. Livermore, CA, University of California, Law- rence Livermore Lab.. February 2. 1979. Zahl, R. K., and J. C. Nigro, “The Use of Low-Btu Gas for Iron Oxide Pellet Induration, An Interim Report,” In: Symposium Proceedings: Environmental Aspects of Fuel Conversion Technology, IV (April 1979. Hollywood, FL). Report EPA-600/7- 79-217. Research Triangle Park. NC. Research Triangle Institute, September 1979. 13 ------- Environmental Review of Synthetic Fuels March 1979 Liquefaction Technology Cochran, H. D., Jr., Hydrocarbonizaf ion, Report CONF--790211- 1, Contract No. W-7405-ENG-26. Oak Ridge, TN, Oak Ridge National Lab., 1979. Harris, L. A., and C. S. Yust, “SEM and EMA Studies of a Solvent Refined Coal Pilot Plant Carbonaceous Plug’ Scan- ning Electron Microsc. 1l(1):537-42, 1978 Heylin, Mike, ‘South Africa Commits to Oil-from-Coal Process,” Chem. Eng. News 57(38):13-16, 1979. Schreiner, Max, Research Guidance Studies to Assess Gaso- line from Coal by Met hanoi-to-Gasoline and Sasol-Type Fischer- Tropsch Technologies. Report FE-2447-13, Contract No. EF.77. C-01-2447. Princeton, NJ. Mobil Research and Development Corp., August 1978. Shields, K. J., H. 1. Hopkins, E. E. Weir, and C. Thompson, Environmental Assessment Report: Solvent Refined Coal (SRC) Systems. Final Report, May 1978 - May 1979. Report EPA-600/ 7.79.146, NTIS P8-300 383. Columbia, MD, Hittman Associates, Inc., June 1979. U. S. Department of Energy, Office of Integrative Analysis, Midterm Analysis Dlv., Analysis Report- Energy Supply and Demand in the Midterm: 1985, 1990, and 1995. Report ARIIAI79- 24, DOE/EIA-0102/52. Washington, DC, Energy Information Admin., Asst. Admin. for Applied Analysis, April 1979. Other Bruner, Fabrizio, Arnaldo Liberti, Massimiliano Possanzini, and Ivo Allegrini, “Improved Gas Chromatographic Method for the Determination of Sulfur Compounds at the PPB Level in Air, “Analytical Chem. 44(1 2):2070-2074, 1972. Calzonetti, F. J., Impacts of the Resource Conservation and Recovery Act on the Siting of Coal Conversion Energy Facilities in the United States. Report ORNUOEPA-12 1R1, Con- tract No. W-7405-ENG-26. Morgantown, WV, West Virginia Univ., Dept. of Geology and Geography, February 1979. CombIned.Cycle Using Gas from Coal Holds Promise for Electric Generation, Power 123(6):99-102, 1979. Costle, Douglas M. ANew Source Performance Standards for Coal-Fired Power Plants,” J. Air Pollut. Contr. Assoc. 29(7):690- 692, 1979. Deadmore, D. 1., and C. E. Lowell, Airfoil Cooling Hole Plugging by Combustion Gas Impurities of the Type Found in Coal De- rived Fuels. Report DOEINASAI2593-79l1, Contract No. EF-77- A-01-2593. Cleveland, OH, National Aeronautics and Space Admin., Lewis Research Center. February 1979. Duvel, William A., Jr., “Solid-Waste Disposal: Landfilling,” Chemical Eng. 86(14): 77-86. 1979. Ellingson, W. A., Materials Technology for Coal-Conversion Processes. Fifteenth Quarterly Report, July - September 1978. Report ANL-79-2, Contract No. W-31-109-ENG-38. Argonne, IL, Argonne National Lab., 1978. Elliott, G.R.B., and N. E. Vanderborgh, Laboratory Studies of Coal Drying, Pyrolysis, and Combustion for UCC. Report LA-UR-78-1 935, Contract No. W-7405-ENG-36. Los Alamos, NM, Los Alamos Scientific Lab., 1978. Ewing, R. A., B. W. Cornaby, P. V. Voris, J. C. Zuck, G. E. Raines, and S. Mm. Criteria for Assessment of Environmental Pollutants from Coal Cleaning Processes. Report EPA-600/7- 79-1 40. NTIS PB 80-102791, Contract No. 68-02-2163, Task 242. Columbus, OH, Battelle Columbus Labs.. June 1979. Folsom, B. A., T. L. Corley, M. H. Lobell, C. J. Kau, M. P. Heap, and T. J. Tyson, Evaluation of Combustor Design Concepts for Advanced Energy Conversion Systems. In: Proceedings of the Second Stationary Source Combustion Symposium. New Orleans, LA, August 29, 1977, Volume V. Report EPA-600/7-77- 073e, NTIS PB 274897, CONF-770885-P5. Research Triangle Park, NC, Industrial Environmental Research Lab., EPA, July 1977. Kingsbury, G. L., R. C. Sims, and J. B. White, Multimedia Envi- ronmental Goals for Environmental Assessment: Volume IV. MEG Charts and Background In formation Summaries (Cate- gories 13-26). Report EPA-600l7-79-176b, NTIS PB 80-115116, Contract No. 68-02-2612 (W.A. 72) and 68-02-3132. Research Triangle Park, NC, Research Triangle Inst., August 1979. Lemmon, A. W., G. L. Robinson, V. 0. Hale, and G. E. Raines, Environmental Assessment of Coal Cleaning Processes: First Annual Report; Volume I. Executive Summary. Report EPA-600/ 7.79-073b NTIS PB-300 671. Columbus OH, Battelle Columbus Labs.. Ju ne 1979. Lemmon. A. W., G. L. Robinson, V. 0. Hale, and G. E. Raines, Environmental Assessment of Coal Cleaning Processes: First Annual Report; Volume II. Detailed Report. Report EPA-600/ 7-79-073c, NTIS PB-300 672. Columbus, OH, Battelle Columbus Labs, June 1979. Lentzen, D. E., D. E. Wagoner, E. D. Estes, and W. F. Gutknecht, IERL-RTP Procedures Manual: Level 1 Environmental Assess- ment (Second Edition). Report EPA-600/7-78-201, NTIS PB 293795. Research Triangle Park, NC, Research Triangle Insti- tute, January 1979. Lesage, L. G., Instrumentation and Process Control for Coal Conversion. Report ANLJFE-49622-18, Contract No. W-31-109- ENG-38. Argonne, IL, Argonne National Lab., April 1978. Luthy, R. G., and S. G. Bruce, Analysis of GFERC Wastewater Samples, Run RA-16. Report FE-2496-15, Contract No. EX-76- S-01-2496. Pittsburgh, PA, Carnegie-Mellon University, Environ- mental Studies Inst., June 1977. Martin, G. Blair, and W. S. Lanier, “Combustion of Liquid Synfuels,” In: Symposium Proceedings: Environmental Aspects of Fuel Conversion Technology. IV (April 1979, Hollywood, FL). Report EPA-600 17-79-217. Research Triangle Park, NC, Research Triangle Institute, September 1979. Morris, S. C., “Coal Conversion Technologies: Some Health and Environmental Effects.” Science 206(441 9):654-662, 1979. O’Hara, J. B., Preliminary Design Services. Research and De- veloprnent Report No. 114. Report FE-1775-21, Contract No. EX-76-C-01-1 775. Pasadena, CA, Ralph M. Parsons Co., Novem- ber 1978. 14 ------- Environmental Review of Synthetic Fuels March 1979 O’Hara, J. B., and B. I. Loran, Environmental Factors for Oil- “Short-term Carcinogenicity Tests: Promising but not Without Gas Coal Conversion Technology. Prepared for the 69th AIChE Problems,” Chemical Week 124(24):31-32, 1979. Annual Meeting, Chicago, IL, November 28. 1976. Preprint No. 64D. Svarovsky, Ladislaw, “Advances in Solid Liquid Separation-I: Page, G. C., Environmental Assessment: Source Test and Filtration and Allied Operations,’ Chemical Eng. 86(14):62.76. Evaluation Report--Chapman Low-Btu Gasification. Report 1979. EPA-600/7-78-202, Contract No. 68-02-2147. Austin, TX, Radian Corporation, October 1978. U. S. Department of Energy, Pittsburgh Energy Technology Pojasek, Robert B., “Solid-Waste Disposal: Solidification.” Center, Clean Energy From Coal. Report PETC-1000. Pittsburgh. Chemical Eng. 86(17):141-145, 1979. PA, January 1979. Ross, Richard D., “The Burning Issue: Incineration of Hazardous Wojciechowski, B. W., “The Economics of Carbon Processing,” Wastes,” Pollution Eng. 11(8):25-28, 1979. Hydrocarbon Process. 58(7):105-110, 1979. fhe Environmental Review of Synthetic Fuels is prepared by Radian Corporation under EPA contract 68-02-3137. Each contractor listed In the table of contractors on page 6 contributed to this issue. The EPAJIERL-RTP Project Officer is William J. Rhodes, (919) 541-2851. The Radian Program Manager is Gordon C. Page, the Project Director is Elizabeth D. Gibson, and the Task Leader for preparation of this issue is Pamela K. Beekley, (512) 454-4797. Comments on this issue, topics for inclusion in future issues, and requests for sub- scriptions should be communicated to them. The views expressed in the Environmental Review of Synthetic Fuels do not necessarily reflect the views and policies of the Envi- ronmental Protection Agency. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by EPA. ------- |