FRANCONIA MANUFACTURING CORPORATION EAST BRANCH OF THE PEMIGEWASSET RIVER LINCOLN, NEW HAMPSHIRE APRIL 5, 1972 ------- I NTRODUCTION In July, 1971, the Franconia Manufacturing Corporation in Lincoln, New Hampshire, started operation of what was originally the Franconia Paper Company mill. Since that time, several fish kills have been re- ported downstream of the mill. The last Federal survey of the pollution problem in the East Branch of the Pemigewasset River was conducted between 1964 and 1966. Between 1966 and the present, the pulp and paper mill converted to an ainmonium based sulfite process with sulfur recovery using the Copeland Process and installed a white water treatment plant ( rP). In 1969, the town of Lincoln constructed a new water pollution control facility(WPCF). Because of the fish kills and the lack of current data on both the mill effluent and the stream conditions, Region I, Environmental Protection Agency, assisted by the New Hampshire Water Supply and Pollution Control Commission (NHWS & PCC),condücted a study of the mill’s WWTP, the town’s WPCF, and the East Branch of the Pemigewasset River. FRANCONIA MANUFACTURING CORPORATION Franconia Manufacturing Corporation, an ammonia based sulfite pulp and paper mill’, produces 110 tons of paper per day with a waste water discharge of approximately seven million gallons per day to the ast Branch of the Pemigewasset River. Raw materials used in the manufacture of paper include anhydrous ammonia and sulfur used to produce the axnmonium bisulfi cooking liquor, soft and hard-wood logs, ------- chlorine bleach, caustic soda, hypochiorite wash, clay, starches, rosin sizing, and dyes. The mill purchases approximately ten tons of pulp per day in addition to the ninety tons produced per day. Figure 1 shows the location of the mill. PULP MILL OPERATION The company trucks in both hard and soft wood logs, which are debarked and chipped for use in the sulfite pulp mill. The bark from the debarker drums is trucked away to a bark pile located just upstream of the mill proper. Some transport water is used to carry the logs to the chipper. ver-f lows and drains in the woodroom are connected to the WWTP. The mill burns sulfur to sulfur dioxide gas and absorbs it in an ammonium hydroxide and water mixture to produce the ammonium bisulfite cooking liquor. The chips and ammonium bisulfite are cooked in digesters for 6 hours at 130°C and 90 psi(pounds per square inch). At the end of that time the mixture is blown into blow tanks. The pulp is then passed through knotters where knots and other undigested particles are removed and trucked away to the bark pile after which the pulp is washed on drum washe s with a counter- -- current washwater flow. The spent sulfite it uà (SSL) is sent to the Copeland Process incinerator. After washing, the pulp is screened and sent to the three stage chlorine bleach, caustic extraction, and hypochiorite wash bleachery. All wastes from the screen room and bleachery are sent to the WWTP. The whitened pulp is conveyed to the paper mill. ------- See Fi ure 2 for a flow diagram of the pulp mill. PAPER MILL OPERATION Pulp is mixed with clay, starch, and rosin sizing in beaters and sent through cyclone cleaners to paper machine head boxes Waste- waters from the paper mill originate from cleaning the pulp, paper machine white water overflow, and washdown operations. These wastes are treated in the WWTP. Figure 3 shows a flow diagram of the paper mill. WHITE WATER TREATMENT PLANT All the waste flows from the Franconia Manufacturing Corporation, except sanitary waste which is treated at the municipal treatment facility and the spent sulfite liquor (SSL) which is treated separately, are treated at the white water treabnent plant (WWTP). The WWTP is located on town owned land within the Franconia Manufacturing Corporation mill area and operated by mill personnel. Treatment consists of flocculation and settling. The settled sludge is thickened, vacuum filtered and trucked to the bark pile dump area. Chemicals used in the treatment of a calculated 7 mgd(million gallons per day) care lime (CaO) for pH adjustment, followed by the addition of an alum (A1 2 0 3 ) solution for flocculation. Only one of the two clarifiers was in operation on the survey date. Refer to Figure 4 for a flow diagram of the WWTP and sampling locations. ------- FRANCONIA MANtJFAU’IUICIN(.i L,UitI’U1UtLiV1 WHITE WATER TREATMENT PLANT BASIC DESIGN DATA* Flow Average 10 MCD Maximum 14 MCD Mixing I Tank, 15 ft. X 15 ft. and 15 ft. deep. Detention Period: 2.5 minutes Flocculation and 2 clarifiers, each 110 ft. diameter and 10 ft. deep. Sedimentation Detention Periods: Flocculation zone 30 minutes settling zone 3 hours Sludge thickening I Unit, 80 ft. diameter and 13 ft. deep (Sludge quantity: 10 to 15 tons per day dry) Sludge Dewatering 2 rotary vacuum filters, each 8 ft. X 14 ft. each 350 sq. ft. (Loading: 3.55 lbs. minimum per sq. ft. per hour) * Data from publication by Camp, Dresser , & McKee UWater Pollution Control Facilities , Lincoln, N.H., Dec., 1969 ------- COPELAND INCINERATION PROCESS The spent sulfite cooking liquor (SSL) is being sent to the Copeland Incinerator Process which is located in the recovery plant building on town land within the mill yard and operated by mill personnel. In the process, the SSL is evaporated to 32 to 37 per- cent solids and burned in an atomized dispersion type fluidized bed incinerator. The steam generated is sufficient to run the evapora- tors and to supplement the pulp mill steam requirements. The combustion of SSL releases sulfur dioxide which is scrubbed from the exhaust gas by absorption in aminonium hydroxide. The re- sultant ammoniuin bisulfite is used to supplement the mill ‘a cooking liquor requirement. The two wastewater sources from this process are foul condensate and washwater from the cyclone containing fly ash. Both are sent to the JWTP for treatment prior to discharge. Figure 5 is a flow diagram of the incineration process published by the consultant engineers Camp, Dresser, and NcKee. POLLUTIONAL RIVER LOADINGS All process wastewater receives treatment in either the Copeland Incinerator or the WTJITP. The wastewaters from the incinerator are sent to the WWTP; the 1 1WTP effluent flows in a ditch for approxi- mately 200 yards before entering the river on the north bank. Also, yard and roof drains carry run-off from the WWTP area to the ditch. Another source of waste is the leachate and run-off from de- barking and sludge wastes dumped on the north bank of the river up- stream from the pulp and paper mill. ------- LINCOLN, NEW HAMPSHIRE The town of Lincoln, New Hampshire, is located on the 1 eadwaters of the Pemigewasset River. The town has an area of a pproximately 128 square miles with a highly variable population with a peak during the tourist season in the summer months. The population of Lincoln is concentratedin the southwest corner of the town along the East Branch of the Pemigewasset River about one mile upstream from its confluence with the North Branch of the river. Many summer homes, tourist cabins, and motels in Lincoln are located on Route 3 along the North Branch of the Pemigewasset River. The principal industry in the town is the Franconia Manufacturing Corporation employing approximately 300 people. Sanitary wastes from the paper mill and part of the town are treated at the municipal water pollution control facility (WPCF). WATER POLLUTION CONTROL FACILITY The WPCF consists of approximately 10 acres of stabilization pond in two five acre cells, operating in series 0 Sewage flow is comminuted prior to entering the first cell which is aerated. The overflow from the second non-aerated cell is chlorinated to a five milligram per liter residual in a chlorine contact chamber having a designed detention time of fifteen minutes before discharged to the East Branch of the Pemigewasset River. Figure 6 is a flow diagram of the WPCF also showing sampling locations and Figure 1 shows the location of the facility. ------- TOWN OF LINCOLN, NEW HP 1 MPSHIRE WATER POLLUTION CONTROL FACILITY BASIC DESIGN DATA * Population served 2000 (Year 1985) Sewage flow (Year 2000) Average daily 0.74 mgd.- Peak 2.64 mgd. Comminution 1 Unit, capacity 2 rngd. Bypass bar racks provided Stabilization 2 ponds, each 5 acres. Operating depth: 3 to 5 Ft. Detention time: 30 days (Loading: 200 persons per acre) Chlorination 2 chiorinators, capacity: 200 lbs. per day each (Dosage: 20 mg/I) *Data from publication by Camp, Dressêi , & I fcKee ttwater Pollution Control Facilities”, Lincoln, N.H., Dec., 1969 PEMIGEWASSEr RIVER Figure 1 is a map of the general area and Table 1 locates and describes the sampling stations. The Pemigewasset River originates in Franconia and Lincoln, New Hampshire. It flows in a southerly direction through the towns of Woodstock, Thornton, Campton, Holderness, Plymouth, Ashland, Bridgewater, Bristol, New Hampton, Hill, Sanbornton, - and Frankj 1 ,in where it joins the Merrimack River. The length of the Pemigewasset River from the steel highway bridge on Route 3A in Lincoln, about one-half mile north of the Lincoln-Woodstock town line, to the highway bridge on Route 3 in Franklin, about 0.2 miles upstream from Merrimack River, is about 56 miles. ------- The I’r tuconia Mt nuCacturJng Corporation discharge is located approximately one mile upstream from the Route 3A bridge on the East Branch of the Pemigewasset River, an interstate body of water, as is the Pemigewasset River downstream from its confluence with the East Branch. The East Branch of the Pemigewasset River from the Franconia Manufacturing Corporation effluent discharge downstream to its confluence with the North Branch has been classified “C” by the N.H. WSPCC which was approved by the U.S. Department of Interior on December 1, 1970. SAMPLING INFORMATION Table 1 locates and describes the sampling locations. Most samples wer collected, preserved, and analyzed according to EPA Standard Methods for the Examination of Water and Wastewater where applicable. The only exception being the spent sulfite liquor anal- ysis by the Pearl-Benson Method recommended by the Technical Assoc- iation of the Pulp and Paper Industry. The EPA Region I chain of custody record system was used to safeguard the samples. RESULTS Tables 2 through 4 summarize the results of the laboratory analyses. An efflciencystudy is presented in Table 5 of the WWTP and WPCF which are the two main pollutionáliources the East Branch of the Pemigewasset River in Lincoln, New Hampshire. WHITE WATER TREATMENT PLANT (WWTP ) The WWTP was functioning fully during the survey, with the ex- ception of one of the two clarifiers. The company reported some problems with flocculation by liquid alum addition which was started ------- on the survey date. The 1 WTP receives a calculated 7 mgd(inillion gallons per day) of process wastes containing 5800 pounds of suspended solids and 12,800 pounds of BUD 5 . It removes approximately l2L 0 ppd (pounds per day) or 21% of the suspended solids. However, the unit only removes 1360 ppd of 5-day biochemical oxygen demanding (BOD 5 ) material, or less than 11%. Analyses of the influent and effluent from the W ’ITP is given in Table 2. The WWTP effluent constituents are present in concentrations so as to create the foflowing pollution load on the river: Plant River Loading indicated by * Loading indicated by * Parameter _ grab sample analyses composite sample analyses BOD 5 11,500 ppd 13,1 00 ppd Suspended solids 1 6iO ppd 1. 300 ppd Settleable solids 1830 ppd 6L S ppd N}1 3 - N 1165 ppd 1980 ppd’ * Based on three grab sample analyses * Based on twelve hour composite sample analyses collected from 1730 hours, April L , to 01 30 hours, April 5, 1972 ------- The effluent also contained total coliform bacterial densities in excess of 3,000,000 per 100 milliliters and was highly turbid. The samplers noticed a strong odor from the effluent. Another outfall was observed to be discharging yard drainage from the vicinity of the WWTP. This yard is caked with lime due to sloppy feeding methods. The discharge, which was milky white in appearance, may contain large amounts of lime. WATER POLLUTION CONTROL FACILITY (wPCF ) Analyses of the influent and effluent from the WPCF is given in Table 3 • Based upon a calculated discharge rate of 200,000 gpd and measured effluent concentrations, the following pollutional loadings are placed on the East Branch of the Pemigewasset River: River Parameter Loading (ppd ) BOD 5 14.5 Suspended solids 13.5 Settleable solids 305 NH 3 -N 13.4 The effluent also contains a chlorine residual in excess of 4.5 milligrams per liter (mg/I) and a total coliform bacterial density of less than 1000 per 100 milliliters. The sampling crew observed a leak in the chlorine feed line inside the ‘contact chamber during the reconnaissance survey of March 29, 1972 and again on April 5, 1972 during the sampling survey. By comparing the WWTP and WPCF loading rates, it can be estab- - lished that the major pollutional source is that of the Franconia ------- Manufacturing Corporation WWTP discharge. EAST BRANCFI-PEMICEWASSET RIVER Analytical results generated from river sampling are given in Table 4. Upstream of Mill : The temperature in the river upstream of the mill(EBP1)ranged between 0.5 and 1.0°C. The level of turbidity was below 5 J.T.U. and the concentration of total nonfilterable residue (a measure of suspended solids) averaged approximately 3 mg/i. The dissolved oxygen content of the river at this location was near saturation. The average BOD 5 concentration was less than 1.2 mg/I. This is a normal background BOD 5 for waters caused by natural organics. Also,. a total coliform bacterial density upstream of the mill averaged 16/100 ml. In addition, analyses for ammonia-nitrogen (NH 3 -N) and spent sulfite liquor (S.S.L.) was accomplished in order to determine back- ground levels present upstream of the mill. The NH 3 -N concentration averaged 0.0]. mg/i; the S.S.L. concentration was less than 15 mg/i. Stream conditions at the time of the sampling were characterized as high flow, turbulence, and low temperature. Between WWTP effluent and WPCF effluent The concentrations of all measured constituents increased markedly between the mill and the WPCF (EBP2) as compared with the upstream concentrations except for the dissolved oxygen level which decreased. A temperature rise of between 4 and 5 Centigrade degrees was ------- observed; the level of turbidity increased from an average 3 to 24 J.T.U.; suspended solids concentration rose to an average 15.5 mg/i; BOD 5 concentration increased to 47 mg/i; total coiiforrn density in- creased considerably to an average greater than 283,000/100 ml.; NH 3 -N concentration increased to 5.2 mg/i and S.S.L. concentration averaged 382 mg/i. All increases in concentrations are attributable to the type of waste being discharged from the Francoriia Manufacturing Corporation WWTP. The dissolved oxygen level decrease to 11.4 mg/i in the reach of the rivar between the mill and the WPCF is indic- ative of the deoxygenating potential of the WWTP effluent. Downstream of the WPCF Increased mixing and dilution resulted in lower concentrations downstream of the WPCF(EBP3) as compared with those in the river be- tween the mill and the WPCF, with the exception of dissolved oxygen content. However, the constituents present in the river downstream of the WPCF still combine to form an antagonistic environment for fish and other aquatic life. The temperature level decreased to approximately 1.7°C; tur- bidity to 10 J.T.U.; suspended solids to 4.3 mg/I; BOD 5 to 9.1 mg/i; to 1.0 mg/i; and S.S.L. to 83 mg/i. The dissolved oxygen level rose to an average 12.7 mg/i. The rise in D.0. is attributable to the reaeration potential of the river in this reach. The average coliform density downstream of the WPCF was 1,500,000/100 ml. The sampling crew observed an odor at this location similar to that noticed at the WWTP effluent. ------- DISCUSSION FRANCONIA MANUFACTURING CORPORATION Figures 2 and 3 are schematic diagrams of the pulp and paper mill processes. The washing process is the only opera ion in the pulp mill incorporating a countercurrent flow cycle. Significant water usage reduction methods using additional recycling and counter- current flow processes could possibly be proposed by a water management study. Such a study could show methods for reducing water consumption thus producing a lower volume but more concentrated waste which would be easier to treat. The Copeland Incineration Process appeared to be operating properly although a significant quantity of ammonia was present in the WWTP effluent. Facilities for ammonia removal should be incorp- orated into the WWTP. Such a system may be economically justified in that recovered ammonia can be used to supplement the cooking liquor requirements of the pulp mill. The bark pile is located above the mill on the bank of the East Branch of the Pemigewasset River in an area which was at one time, a pond. Bark and knots fromthe pulp mill and sludge from the WWTP are trucked to the dump. The bark pile should be eliminated since the leachate produced from the bark and sludge dumped in this area C&1 create a pollutional load on the river. The bark could be incinerated and the by-product steam could supplement the steam re- quirements of the mill. The possibility of burning ‘pludge should be investigated. If necessary, the sludge could be trucked to a properly operated sanitary landfill. ------- W1ilTE WATER TREATMENT PLANT Table 5 contains an efficiency study of the WWTP. Additional treatment is necessary to increase the efficiency of this facility. The lime cake on the ground in the vicinity of the WWTP should be eliminated. The yard drains in this area carry off the lime into the river creating another pollutional load on the East Branch of the Pemigewasset River. Due to a problem in the past with one of the two clarifiers, sludge was dumped on the ground at the periphery of the WWTP. This waste could also be carriedto the river through the yard drains by the spring runoff. WATER POLLUTION CONTROL FACILITY As can be seen from the analytical results given in Table 3, the influent to the WPCF can be categorized as weak. This indicates a high infiltration rate which should not be present in a new sewer system such as this. The WPCF may be overdesigned since the 10 acres of lagoons at this facility receive only 14 pounds BOD 5 per acre. The effluent is low in organic content and bacterial density. Table 5 shows the efficiency of the WPCF. EAST BRANCH-PEMIGEWASSET RIVER Analyses of samples taken in the river upstream of the mill indicate that the State-Federal water quality classification (Class B) is met. However, the river below the mill contains organic matter, bacteria, suspended solids, NH 3 -N, and S.S.L in concentrations above those which would be considered acceptable for the established use ------- classification (Class C) for this reach of the river. The BOD 5 concentrations in the river below the mill indicate a very strong deoxygenating waste being introduced, ,by the WWTP effluent and the leachat entering the river from the bark pile area. The decrease in BOD 5 concentrations between Stations EBP-2 and EBP-3 is attributable to increased dilutionb The effluent from the WWTP and the bark pile leachate, because of the organic content, will create an oxygen deficit in the river. During periods of low river flow and/or warm temperatures, low D.O. levels can inhibit the growth and activity of fish and other aquatic life. Because of the WWTP effluent suspended solids concentration, fish propagation may be diminished. Suspended solidsare iminical to aquatic life by causing abrasive injuries; by clogging the hills; and by blanketing the bottom thereby destroying spawning beds, kill- ing eggs,young,iand food organisms. In the presence of even low concentrations of toxic substances, fish may be so weakened that the abrasive and clogging actions of suspended solids become more effect- ive and dangerous, and even lethal. The WWTP effluent contains excessive NH 3 -N thereby creating an average concentration in the river between the mill and the WPCF of 5.2 rng/l. The effect of NH 3 -N at a concentration as low as 1.0 mg/i decreases the ability of hemoglobinto combine with oxygen resulting in suffo- cation of fish. The toxicity of NH 3 -N is markedly increased by.a reduced dissolved oxygen content in the water. ------- The S.S.L contains, in dissolved or very finely divided sus- pension, approximately half the weight of the wood used for pulp- ing and comprises fibre binding substances such as lignin, pectin, hemicei].u].oses, sulfur dioxide, sulfites, organic acids, and other organic and inorganic substances. Acid in reaction, the S.S.L is high in BOD and organic matter with a pungent odor and has a char- acteristic tendency to foam in receiving waters. S.S.L is inimical to fish and other aquatic life in that it results in oxygen depletion Exposures to S.S.L adversely affects the internal organs of fish at concentrations as low as 10 mg/i. Most of the S.S.L is incinerated in the Copeland Process. Flow- ever, some is carried in the stock past the brown stock washers. Any S.S.L which Is carried over is, when separated from the stock, sent to the WWTP and to the river. The knots and other undigested particles separated by the knotters are coated with S.S.L. This S.S.L. will be carried into the river by the leachate from the bark pile where the knots are dumped. The S.S.L concentration in the East Branch of the Pemigewasset River between the mill and the WPCF averaged 382 mg/i which reflects the type of waste discharged to the river by the Franconia Manufac- turing Corporation WWTP. Moreover, S.S.L imparts a definite taste to fish flesh. GENERAL ANALYSIS The water quality of the East Branch of the Pemigewasset River is degraded by the waste discharges from Franconia Manufacturing Corporation and the Lincoln municipal WPCF. ------- A marked increase in the river BOD, ba teria1 density, sus- pended solids, turbidity, ammonia-nitrogen, and spent sulfite liquor concentrations, and temperature level were.observed from above the mill to below the WPCF. This is the reach into which • Franconia Manufacturing Corporation and the WPCF discharge their wastes. These concentrations are considered to be above those which would be considered acceptable for the established use classifica- tion (Class C) for this reach of the river. ------- TABLE J SAMPLE STATION IDENTIFICATION STATION LATITUDE LONGITUDE DESCRIPTION 0 0 II (River) ERP 1 44 03 25 71 38 05 Pemigewasset River at Loon Mountain Bridge EJP2 44 02 05 71 40 22 Pemigewasset River 0.5 miles downstream from WWTP discharge EBP3 44 01,49 71 40 47 Pemigewasset River at I - 93 /construction crossing (WWTP) FMC1 44 02 25 71 40 06 WWTP influent FMC2 44 02 24 71 40 04 WWTP effluent to ditch (wPcF) LTP I 44 02 12 71 40 34 WPCF influent after comminutor LTPE 141402 10 71 40 37 WPCF effluent from chlorine contact chamber ------- LINCOLN. NEW HAMPskIR J&t?r PoUijt,c p.) Co,Jtro p - - Loo 5CF4LE - ______________________ a Ft —I v i ,1• Dv ip F Q A QF PIC i ‘ rcr 1 R’c’cc 4 FIGURE 1 ------- FRANCONIA MANUFACTURING CORPORATION PULP MILL FLOW DIAGRAM BARK! ,DRY TRANSP0RT I WATER TO BARK WWTP PILE ABSORPTION COLUMN 150 gpm J,FOUL W W TP AMMONIUM PA PER MILL FIGURE 2 ------- FRANCONIA MANUFACTURING CORPORATION PAPER MILL FROM PULP MILI BEATER SOT/D ROOM PURCHASED PULF $0 T/D FILLERS- CLAY STARCH & ROSIN SIZING CLEANERS T 1 REJE TS H O [ J PAPER TO ____ ____ HEA J ROLLERS f BOX MACHIrLES WHITE ) WWTP WATER CHEST FIGURE 3 ------- FRANCONIA WHITE MANUFACTURING CORPORATI ON WATER TREATMENT PLANT PH CONTRI (LIME OR SULFURIC ACID TO BARKPILE. BY TRUCK WATER 0 ITCH (ACTIVATED SILICA& ALUM) STATION FMC-2 FIGURE 4 ------- R JCON!A PAPER CORPORATION ACIE) RECO\/ER”? SYSTEM COPELAND PROCESS CORPORATION TO\VM of LIWCOLP J L COL , H& PS 4I!Z SULHTE L)QUOR DISPOSAL PLANT FIGURE 5 cop.Jc,GNse GPM I or2.A T Qc 5 CLW4 GA5 10 AXMO6. WATE. p oxyGr 44 h l00 U. XCI48. JGEfL 5CB! 4 L% UI ------- LINCOLN, NEW HAMPSHIRE WATER POLLUTION CONTROL BAR RACKS• FACILITY STATION LTPI CHLORINE CONTACT CHAMBER FIGURE 6 ------- SANPLE ANALYSES ABBREVIATIONS & UNITS OF MEASURE ANALYSI S Temp. pH D.O. (Probe) BOD5 Total Coliforms Fecal Coliforms NH3 - N S.S.L. Cl 2 Residual Turbidity Settleable Solids Total Residue Total N.F.Residue Fixed Residue Fixed N.F.Residue Letter Code: DESCRIPTION Temperature Hydrogen ion concentration Dissolved Oxygen 5 day biochemical oxygen demand Total Coliform bacteria Fecal Coliform bacteria Ammonia reported as Nitrogen Spent sulfite liquor Chlorine Residual Turbidity Weight of matter that mg/I settles out in one hour Total Solids mg/I Total non-filterable residue A measure of Suspended Solids) mg/I Fixed Solids — (A measure of inorganic Solid) mg/I Fixed non-filterable Solids (A measure of inorgani Suspended mg/I Solids) K - less than J - estimated value -L - greater than UNITS OF MEASURE 0 Degrees Centigrade C C) Standard Units (S.u.) mg/i (milligrams/liter) mg /1 per 100 milliliters(/IOO ml) (/100 ml) mg/I as nitrogen mg/i as sulfur mg / I J.T.U. (Jackson Candle Turbidity Uni ------- TABLE FRANCONIA MANUFACT “ IC CORPORATION _WFIITEJ1ATER TRE I1 ENT PLANT ANALYSES RESULTS APRIL 5. 1972 DEPTH TIME (FT.) pH PROBE D.O. (S.U.) (mg/i) BOD COLIFORMS (MF/100m1) (mg/i) Total Fecal TATION FMC 1 0630 - 0810 - 1000 FMC. 2 0630 - 0810 - 1000 - COMPOSITE (1730-0430) TATION TIME FMC.1 0630 - 0810 - 1000 FMC 2 0630 - 0810 - 1000 - COMPOSITE (1730-0430) 4.4 -- 230 K100 K100 3.0 -- 210 100 K100 302 220 200 K100 8.4 180 L3,000,000 KiOO 709 200 L3,000,000 K100 802 210 L3,000,000 K100 230 TEMP. (°c) 15,0 15.0 15.0 1500 1600 1600 Total (mg/i) 1053.2 1043.1 924.5 1329.7 1223.5 1221.5 1137.4 1.0 1.0 1 .0 1.0 100 1.0 100 Set .Solids (mg/I) iO7 3 _67 1 5202 1906 46 • 7 8.1 i4 5 7. 2 7.4 702 RESIDUE SERIES F ± xe d (mg / 1) 38709 610.6 54305 858.5 77305 78101 688.1 Total NP Fixed NP Turbidity NH 3 -N Cl 2 Residual (mg/i) (mg/i) (J 0 T.U .) (mg/l) (mg/i) 130.9 9105 7900 8309 85.9 68.5 7305 6004 38.2 21.0 3208 i6 i 22.1 1102 110 80 96 54 63 52 73 2700 1500 1500 3400 KO . I KU. 1 ------- TABLF 3 FRANCONIA MANIJFAC’ NC CORPORATION LINCOLN MUNICIPAL LREATMENT PLANT ANALYSES RESULTS APRIL 5, 1972 DEPTH TEMP. p 11 PROBE D.O. BOD5 COLIFORNS (MF/ lOOml) ATION TIME (FT.) (°C) (S.U.) (mg/i) (mg/i) Total Fecal TPI 0730 1.0 5.0 J 118 4,000,000 1,000,000 0900 1.0 4.0 6.4 J 70 11,000,000 190,000 1000 1.0 -- 6.6 J 66 11,000,000 480,000 TPE 0730 1.0 2.0 6 8 504 1100 Ki000 KiOO - 0900 1.0 1.0 - 6.2 7.3 K1000 K100 1030 1.0 1.0 6.8 7,4 7.6 Kl 000 K100 RESIDUE SERIES Set. Solids o al Fixed Total NF Fixed NF ‘urbidity Nh —N Cl 2 Residual ATION TIME (mg/i) mg/l) (mg/i) (rig/i) (mg/i) (J.T.U.) (mg/I) 0730 57.4 277.8 129.5 82.2 10,2 48 0900 13.7 230.2 141.6 29.4 0.8, 20 1000 25.6 241.8 139.9 42.8 40.5 27 TPE 0730 3.0 171.6 103.4 7.7 1,0 7.3 7,0 4.5 - 0900 0.0 i67 0 110.4 7.4 0.1 7 9.0 K5.O 1030 3.4 163.4 90.7 9.1 0,4 ii 7.0 4.5 ------- TABLI 4 FRANCONIA MANUFACTUR C CORPORATION EAST BRANCH-PEMICEWASSET RIVER ANALYSES RESULTS APRIL 5, 1972 DEPTH TEMP. PROBE D.O. STATION TIME (FT.) (°C) (mg/i) S.S.L. BOD COLIFORMS (MF/1oc ].) (mg/I) (mg/i) Total Fecal Cl 2 Residual (mg / 1) NH 3 - N (mg/I) E BP 1 E BP 2 E BP3 0630 0820 0930 0710 0845 0955 0740 0915 1015 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.5 1.0 1.0 5.0 5.0 6.0 1.0 2.0 2.0 K15 K15 Kl5 396 381 369 80 86 85 Kl.2 Kl .2 Kl.2 46 48 48 8.5 10.0 8.8 STATION TIME 12 30 L 350,000 L 200,000 L 300,000 1,800,000 1,500,000 1,200,000 K2 2 K2 K1O RiO Kl0 KiOO 1 (100 Kl00 13.4 14.0 11.4 11.4 11.3 13.1 12.7 12.3 Total (mg/i) 25.5 47.5 45.5 323.8 301.6 306.3 89.4 97.7 97.0 0 0 0 0 0.01 0.01 0.01 11.0 3.8 0.8 1.5 0.9 0.5 E BP 1 E BP2 E BP3 Set. Solids (mg/l) 2.4 2.3 5.9 4.1 3.0 1.7 0630 0820 0930 0710 0845 0955 0740 0915 1015 RESIDUE SERIES Fixed (mg/i) Total (mg/i) NF Fixed (mg/i) NF Turbidity (J.T.U.) 1.5 9.9 33 .0 214.3 178.7 188.5 51.5 60. 5 59.0 2.6 3.2 3.2 14.7 17.6 14.3 5.9 6.9 1.2 0.4 1.0 0.2 3.2 0.1 2.0 0.8 0.5 0.2 0.7 4 5 24 28 21 11 10 10 ------- TABLE 5 EFFICI ENCY WHITE WATER TREATMENT PLANT Parameter PPD In PPD Out Removal efficiency BOD 5 12,860 11,400 11% Suspended solids 5800 4610 2l7 Settleable solids 4300 1800 58% WATER POLLUTION CONTROL FACILITY Parameter PPD In PPD Out Removal efficiency BOD 5 J 142.0 14.4 J90% Suspended solids 86.0 13.5 85% Settleable solids 53.5 3.5 940/ ------- FRANCONIA MANUFACTURING CORPORATION EAST BRANCH OF THE PEMIGEWASSET RIVER LINCOLN, NEW HAMPSHIRE APRIL 5, 1972 ------- |