WATER POLLUTION CONTROL RESEARCH SERIES • 12060 EDK 08/71 Liquid Wastes From Canning and Freezing Fruits and Vegetables US FNVIRONMENTAL PROTECTION AGENCY ------- WATER POLLUTION CONTROL RESEARCH SERIES The Water Pollution Control Research Series describes the results and progress in the control and abatement of pollution in our Nation’s waters. They provide a central source of information on the research, develop- inent, and demonstration activities in the Environmental Protection Agency, through inhouse research and grants and contracts with Federal, State, and local agencies, research institutions, and industrial organizations. Inquiries pertaining to Water Pollution Control Research Reports should be directed to the Chief, Publications Branch, Research Information Division, Research and Monitoring, Environmental Protection Agency, Washington, D. C. 20460. ------- LIQUID WASTES FROM CANNING AND FREEZING FRUITS AND VEGETABLES by National Canners Association Western Research Laboratory Berkeley, California 94710 for the OFFICE OF RESEARCH & MONITORING ENVIRONMENTAL PROTECTION AGENCY Program Number 12060 EDK August 1971 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 - Price $1.50 ------- EPA Review Notice This report has been reviewed by the Environmental Protection Agency and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the Environmental Protection Agency, nor does mention of trade names or commercial products constitute endorsement or recom- mendation for use. 11 ------- ABSTRACT The size of the U. S. fruit and vegetable canning and freezing industry and estimates of its output of waste water, biochemical oxygen demand (BaD), suspended solids (SS), and solid residuals are presented. Typical processing operations and the sites of generation of wastes are outlined. Estimates are made of the proportions of waste loads generated at each of several processing steps for 15 commodities. The proportions of waste effluents treated and the the costs of liquid waste management in this industry are estimated. The generation of waste and factors influencing waste loads are dis- cussed; quantities of waste and its treatment and/or disposal costs are estimated. References are listed for operations important in p01- lution control such as: harvest and delivery, in-plant water uses, blanching, and peeling. Solid residuals and their use and disposal are discussed. Under liquid waste treatment, the separation of particulates, biologi- cal treatment, land disposal, and other methods are discussed. Treat- ment efficiency, important variables, costs, and references are given. Additional research is recommended in: determining the sources of waste, water conservation and reconditioning, blanching, peeling, solid residuals utilization, liquid waste treatment and pollution eval- uation. This report was submitted in fulfillment of Project Number 12060 EDK under the partial sponsorship of the Environmental Protection Agency. 111 ------- CONTENTS Section Page Summary i II Introduction 5 Scope and Problem 5 Total Waste Production 6 Current 6 Future 7 General Disposal Practices 8 III Harvest and Delivery 13 Mechanical Harvesting 13 In-field Processing 14 Soil Loads on Fruits and Vegetables 14 Hauling from Field to Plant 15 IV Processing Operations and Water Use 17 Unit Operations 17 In-plant Conveyance 19 Washing and Rinsing 19 Peeling 23 Blanching 23 In-plant Reuse of Water 24 V Waste Generation and Characteristics 27 Waste Generation by Unit Operations 27 Peeling 28 Blanching 28 Nutrient Losses 28 The pH of Processing Effluents 36 VI Treatment and Disposal of Solid and Liquid Waste 37 Solid Waste 37 Solids Separation 37 Screening 37 Sedimentation, settling and chemical precipitation 41 Vacuum filtration 44 Centrifugation 44 Flotation 45 Solids Disposal 46 V ------- Section Page VI Liquid Waste 48 (cont) Biological Treatment 48 Anaerobic ponds 49 Lagoons and stabilization basins 50 Aerated lagoons 54 Activated sludge 54 Trickling filters 54 City treatment 60 Other biological treatment 60 Land Disposal 61 Spray irrigation 62 Other irrigation systems 63 Other Treatment Systems 65 VII Costs of Liquid Waste Treatment and Disposal 67 Industry Waste Costs 67 Specific Systems Costs 69 Screening 69 Sedimentation 70 Lagoons 70 Aerated Lagoons 71 Activated Sludge 71 Trickling Filters 72 City Treatment 73 Spray Irrigation 73 VIII Research Needs 75 Waste Sources 75 Water Conservation 75 Reconditioning Water for Reuse 77 Blanching 77 Peeling and Solid Wastes 78 Liquid Waste Treatment 79 Waste Pollution Evaluation 80 IX Acknowledgements 83 X References 85 XI Glossary 141 XII Appendix 143 vi ------- FIGURES Number Page 1 The Use of Water and the Generation of Wastes in Typical Unit Operations 18 2 Change in Product Minerals, Protein and Solubles Concentration from Water and Steam Blanching 33 3 Losses in Vitamin Content of Fruits and Vegetables from Water and Steam Blanching 34 4 Losses in Soluble Solids and Ascorbic Acid from Experimental Methods of Blanching 35 vii ------- TABLES Number Page 1 Wastewater Flows and Disposal 9 2 Liquid Waste Disposal by Urban and Non- urban Plants 10 3 The Use of Wastewater Treatment Systems 11 4 The Use of Water in Washing Fruits and Vegetables 20 5 Removals by Washing 22 6 Characteristics of Wastewater from Peeling Fruits and Vegetables 29 7 Pollution Loads in Effluents from Water Blanching of Vegetables 31 8 Suspended and Total Solids in Blancher Effluents 32 9 The Performance of Screening Systems on Food Processing Effluents 39 10 Suspended Solids in Screened Effluents from Food Processing 40 11 Efficiency of Chemical Coagulation of Screened Effluents 42 12 Suspended Solids in Screened Fruit and Vege- table Effluents 43 13 Anaerobic Pond Performance on Screened Food Wastes 50 14 Typical Design Factors for Stabilization Lagoons 51 15 Stabilization Lagoon Land Area Requirements 52 16 Stabilization Lagoon Performance in Treating Food Processing Wastes 53 17 Aerated Lagoon Performance in Treating Food Processing Wastes 55 18 Activated Sludge Performance in Treating Food Processing Wastes 56 19 Trickling Filter Performance in Treating Food Processing Wastes 58 20 Spray Irrigation Performance in Disposing of Food Processing Wastes 64 21 Estimated Liquid Waste Costs 67 22 BOD Removals and Costs (1) 68 viii ------- Number Page 23 BOD Removals and Costs (2) 68 24 Costs of Sedimentation of Cannery Effluents 70 25 Costs of Lagoon Treatment 70 26 Costs of Activated Sludge Treatment 72 27 Costs of Trickling Filter Treatment 73 Al Total Wastes from Canned and Frozen Fruits and Vegetables 144 A2 Mechanical Harvesting of Fruits and Vege- tables 146 A3 In -field Processing of Fruits and Vegetables 148 A4 Hauling of Fruits and Vegetables from Field to Plant 149 A5 Transfer of Fruits and Vegetables during Processing 150 A6 Reuse of Water in Fruit and Vegetable Processing 151 A7 Treatment of Water for Reuse in Processing Operations 152 A8 Waste Generation from Unit Processing Operations on Fruits and Vegetables 154 A9 The pH of Fruit and Vegetable Effluents 157 AlO Peel Waste from Fruits and Vegetables 158 ix ------- SECTION I SUMMARY About 170, 000 persons work in about 1,800 plants in the canned and frozen fruits and vegetables industry in the United States. It is estimated that this industry annually: utilizes 26 million tons of raw product, discharges 83 billion gallons of waste water, generates 800 million pounds of biochemical oxygen demand (BOD) and 392 million pounds of suspended solids (SS), and produces 8 million tons of solid residuals. On the average the food industry utilizes more public treatment and ground disposal (mostly irrigation) for the ultimate disposal of its waste than do other U.S. manufacturers. Non-urban plants are much more likely to have their own treatment systems than are urban plants. Disposal methods for liquid wastes vary widely among commodities. Flow diagrams, typical of the industry’s commodities, are presented for peaches, peas, corn, beets and tomato products. Proportions of the total liquid waste flow, BOD, and SS from each of five or six processing steps for 15 commodities are estimated. Pollutional loads tend to concentrate in relatively little water at some of the steps (for example, peeling, blanching); relatively clean water is discharged from some operations (for example, washing some products, final canning and freezing operations). The effluent pH varies from less than 4. 0 to more than 12. 0 depending upon the commodity being pro- cessed and the specific type of unit operation utilized during process- ing. A trend toward increased mechanical harvesting of the industry’s crops is continuing with increased problems in product damage, soil, and loss in yields. Movements toward more in-field processing and improved transportation methods are noted. Water is used extensively for transporting commodities within the processing plant because it is a convenient transportation medium and helps maintain sanitary conditions. Water is necessary for cleaning raw commodities. However, solubles leached during trans- portation add to the organic load in the plant effluent. Water is ex- tensively recirculated within equipment and reused at upstream opera- tions in food processing, but additional water savings by reuse are possible and needed. Reconditioning of the water is sometimes necessary. —1— ------- Blanching is essential in the preparation of many vegetables for canning and freezing. High pollutional loads are generated by conven- tional blanching methods using steam and, especially, hot water. Nutrients and minerals are leached or destroyed to some degree during blanching. Peeling by some methods also produces strong pollutional loads. Mechanical peeling with dry-handling of the residuals is feasible for some commodities and minimizes water use and soluble pollutants. “Dry caustic” peeling, which reduces the pollution load in the liquid waste, is a proven process for potatoes and has been used success- fully on several other commodities in pilot plant experiments. The first and commonest step in treating liquid effluents from food processing plants is the separation of particulate matter. This step is generally accomplished by either screening or settling. Several types of stationary, vibrating, and rotary screens are used with a wide range of mesh sizes. Screening and/or settling equipment re- moves little of the BOD but if this equipment is adequately operated it will prevent further leaching of organic s (BOD) into the transport water. The efficiency of settling can be improved by flocculents. Air flotation has promise for removing fine solids from some kinds of waste streams. Solid residuals left from processing many fruits and vegetables have no ready use because they are: a) generated during a few months of the year, b) generated in small quantities by widely dispersed plants, c) not storable without expensive partial processing, and/or d) not as suitable as other raw products. However, the solid residuals from citrus, pineapples, and white potatoes are produced in large quantities over along campaign season. Corn processing also gener- ates large quantities of solids which may be stored. As a result, these residuals along with smaller quantities from many othei c mmodities are used as stockfeed. A number of other by-products are made from food processing residuals in small amounts. Biological processes are widely used to treat food processing waste effluents. These effluents often need added inorganic nutrients for efficient biological treatment. The sludge produced in biological treatment, largely cells of microorganisms, is usually separated by settling and disposed of by various methods. A number of systems for biological treatment have been developed. Some waste conversion occurs by natural flora during long periods -2-• ------- in holding ponds. Various methods of aerating the effluent and of recycling some or all of the sludge to the aerated or to an anaerobic section of the system improve the efficiency and shorten the time of treatment at increased costs. BOD and SS removals vary widely among and within the systems. Some biological systems are sensitive to shock loadings or pH changes, which, together with insufficient aeration, may reduce BOD removals and/or produce a sludge that is difficult to settle. Within the food processing industry the most common method of liquid waste disposal on the land is spray irrigation. The availability of suitable land, the characteristics of the soil, the cover crop, the waste water, and climatic conditions all affect this method of disposal. Some irrigation systems operate with little or no run-off and remove practically all of the pollutional load; even with run-off fairly high removals can be achieved. Such treatment methods as carbon adsorption, ultra-filtration, re- verse osmosis, and liquid incineration have been little used for food processing wastes except experimentally. Roughly half of the industry’s plants discharge their liquid wastes to municipal treatment. Liquid waste costs for a synthetic average plant in the industry are estimated at $18, 000 per year or $1. 30 per ton of raw product, in- cluding annual capital and operation and maintenance costs. Extensive research is needed in many phases of the industry’s waste problems: the sources, quantities, and characterization of waste loads during processing; water reconditioning, recirculation, and reuse in the plant; new, low-pollution methods of blanching and peel- ing; the operations of current treatment systems and explorations of new systems; improved monitoring methods; and cost estimates for all waste handling methods. -3-. ------- SECTION II INTRODUCTION SCOPE AND PROBLEM The effective minimizing of the pollutional loads developed in fruit and vegetable processing is important to both the economic and social status of the enterprise. It is the objective of this report to consoli- date and make available the substance and record of published infor- mation dealing with wastes generation during fruit and vegetable processing. Also, from this, to direct attention to potential areas for reducing the pollution loads through research, most of which will have economic advantages to the operation, and which will enable better meeting of the objectives in environmental protection programs. The data in this report were taken largely from the published litera- ture; more than 700 references are listed. During the past ZO years there has been a constant consolidation of smaller fruit and vegetable operations into larger, more centralized process operations, resulting in greater usage of water and more discharge of wastes per operation. Thus, during the highly seasonal periods of operation in the industry it is not unusual for a process operation to utilize much more water and to generate more waste than the community in which the operation is located. The waste loads in this industry are generated within a relatively small harvest period during the year; treatment systems must be geared to prevent pollution at periods when rainfall and stream flow are at a minimum. Further, where the wastes are channeled into municipal systems, often these are already overtaxed in capacity and inadequate for the community requirements. The solid wastes produced in processing many fruits and vegetables have relatively little economic value and are not marketable. Dis- posal may be by land fill or by spreading on land, and sometimes creates problems of pollution, hygiene or public annoyance. However, solid residual material from some products is specifically handled for stock feed. The waste in the effluents from canning and freezing plants are bio- degradable, but treatment costs are increasing, effluent discharge requirements are becoming more stringent, and urbanization in- creasingly limits the availability of land. -5- ------- Thus there are many problems to be dealt with in handling the industry’s waste. TOTAL WASTE PRODUCTION CURRENT - The fruit and vegetable canning and freezing industry in- cludes operations in 1,838 plants employing 167, 000 persons, result- ing in increased value to the raw crop of some $2. 2 billion. This industry utilizes an estimated 99 billion gallons of Intake water, re- circulates about 64% of it, and discharges about 96 billion gallons. The percentages of these values compared to those for all U. S. manufacturing and for all food and kindred products are, respectively: number of plants, 0. 6 and 5. 6% number of employees, 0.9 and 10.1% value added, 0. 8 and 8. 3% intake water, 0. 6 and 12. 2% recirculated water, 0. 3 and 12. 4% discharged water, 0. 7 and 12. 8% All of the figures above are from preliminary reports of the 1967 Census of Manufacturers, U. S. Department of Commerce, is sued in 1970. An independent estimate of the quantity of water discharged in canning and freezing fruits and vegetables made for this study is somewhate lower than the census value: 83 billion gallons, including a very small quantity used in dehydration plants and a substantial quantity used in types of manufacturing excluded from the census figures. The inde- pendent estimates are in the Appendix in Table Al. Table Al also gives estimates of raw product tonnages, and of BOD, SS and solid residuals generated. “Other fruit” and “other vegetables” include all those rot specifically listed. Estimated totals, for the United States in 1968, are: 26 million tons of raw product 83 billion gallons of wastewater discharged 800 million pounds of BOD generated 392 million pounds of SS generated 8 million tons of solid residuals. Citrus, tomatoes, corn, and white potatoes (excluding dehydrated potatoes) account for 67% of the raw tonnage, 57% of the waste water, 52% of the BOD, 62% of the SS, and 72% of the solid residuals. -6- ------- The raw tonnage estimates are believed to be the most precise. They are mostly from the U. S. Department of Agriculture Crop Reporting Service but some are National Canners Association estimates based on canned and frozen pack statistics. They are for 1968 except that tomato tonnage was reduced from 7 million to 5 million tons because 1968 was abnormally high for canning tomatoes. The other estimates are based on averages of widely varying figures per ton, mostly published in the l96Ots; some of the sources are unpublished data of the National Canners Association; most of the figures on BOD per ton and SS per ton are from reference 582. The varying estimates for a given product are partly the result of real plant to plant differ- ences. Data from many of the references were converted from values per case to values per ton using U. S. Department of Agriculture figures for average cases per ton (10). Missing data, in particular those for ‘ other fruitu and TTother egetables’, were estimated by comparison with data for the principal products. The numbers in the table are best estimates from currently available data. Estimates were made for the current survey of total solids in the wastewater generated by the industry. They were based on sparser data than were available for the other items and are therefore not listed in detail. The estimated total was 2. 4 billion pounds of total solids, a very high proportion coming from potato processing. Powers et al (521) gave 87 billion gallons of water discharged from canned and frozen fruits and vegetables in 1964; and for 1963 the same quantity of wastewater and also 1, 190 million pounds of BOD and 600 million pounds of SS generated from all canned and frozen foods. These figures are somewhate higher than the current study estimates and the additional products included in the earlier estimates do not seem to account for the differences in BOD and SS. Other estimates derived from reference 521 indicate that in 1963 all food and kindred products manufacturing was about 1/10 and the canned and frozen fruits and vegetables industry was about 1/100 of all U. S. manufacturing as measured by value added. These two segments of the economy used about 5.4 and 0. 5%, respectively, of the total water, but produced about 20% and 5%, respectively, of the total BOD. The comparisons reflect the relatively high strength wastewater discharged by food manufacturing. FUTURE - Other discharges estimated for canning and freezing fruits and vegetables were (584): -7- ------- 1963 estimate: 71 billion gallons wastewater; 660 million pounds BOD 1972 projection: 93. 5 billion gallons wastewater; 845 million pounds BOD. A 1967 publication (637) estimated for canned and frozen fruits and vegetables the following total waste loads, million pounds: Year 1963 1968 1972 1977 BOD 660 785 845 905 SS 750 890 960 1035 TDS* 710 845 910 980 *Total dissolved solids Projections of the U. S. per capita consumption of canned and frozen foods (10) and of the U. S. population indicate an increase by 1980 of about 30% in the production of these foods. Without changes in processing procedures the following totals would be estimated for 1980: 34 million tons of raw product 110 billion gallons of wastewater discharged 1000 million pounds of BOD and 500 million pounds of SS generated 10 million tons of solid residuals However, water conservation practices and improved procedures are certain to reduce both effluent flows and pollutional loads per unit of product in the next few years. GENERAL DISFOSAL PRACTICES All of the figures on wastes referred to above pertain to generated wastes. Large proportions of these are reduced by treatment b,efore final discharge. The 1963 Census of Manufacturers is the source of data in Table 1, which shows the totals and percentages of wastewater flows from plants discharging 20 million gallons per year or more. -8- ------- Table 1. Wastewater Flows and Disposal Total waste- Percent to: water flow, public surface billion gallons treatment ground water total* All U. S. manu- facturing 13, ZOO 7 1 90 98 Food and kindred products 688 35 11 51 97 Canned and frozen fruits and vege- tables 66 38 17 42 97 *The small quantities unaccounted for were transferred to other uses. The food industries discharged much higher proportions of their liquid wastes to public sewers and to land disposal than did manu- facturers as a whole. Discharges onto the land are principally by irrigation, mostly spray irrigation, but also by seepage from ponds and by pumping into non-productive wells. Ground disposal generally removes very high percentages of the pollutional load. The high degree of utilization of public treatment plants and ground discharge by food processors is partly explained by the need for reducing the relatively high strength of this industry 1 s wastes. Most industrial wastewater (including that from food processing) is used for cooling or for other relatively non-contaminating purposes. Added heat may be a problem, but not other types of pollution. Dis- charging this more-or-less clean water to surface water may be necessary to maintain stream flows and provide water for down- stream populations and industries. Wastewater disposed of in streams and lakes is often treated before discharge. A 1965 study (102) found the distribution of liquid waste disposal practices shown in Table 2 in 80 fruit and vegetable canneries, some of which were also freezers. -9- ------- Table 2. Liquid Waste Disposal by Urban and Non-urban Plants Percent of Plants : urban non-urban Discharge to: total City systems 100 9 47 Ponds 0 28 16 Spray irrigation 0 55 31 Surface water 0 9 5 Urban plants were defined as those located within cities; non-urban plants, those located in the country, in small towns, or on the out- skirts of cities. The contrast in disposal methods by the two groups reflects the availability of treatment plants in cities and the high cost of city land. Table 3, mostly 1969-1970 data from reference 471, shows the distribution of liquid waste disposal methods found in a study of all canned and frozen fruits and vegetables except pineapple. Some of these plants used more than one of the listed methods and a plant putting up more than one product was tallied under each corn- rnodity. ‘Holding” and T1 treatment” ponds were not strictly defined; generally the removal of pollution would be less in a holding than in a treatment pond. Some methods of treatment at the plant or of dis- posal were not included in the summary. For example, about half the citrus plants used additional methods, and the clarifiers which remove settleable material at most potato plants were omitted. Most reliance on city systems was by tomato, peach, pear, and mis- cellaneous fruit plants; on treatment ponds, by potato and apple plants; and on irrigation, by corn, apple, and pea plants. A survey in the western half of the United States reported in the same reference (471) found that plants farther away from open land were more likely to use city treatment and less likely to use their own treatment sys- tems for their liquid effluents. -10- ------- Table 3. The Use of Wastewater Treatment Systems Percent of plants using : city holding treatment Product systems ponds ponds irrigation citrus 12 10* 24 tomato 67 11 19 13 corn 40 12 28 44 potato 43 14 57 21 peach 83 3 11 11 apple 30 10 40 30 snapbean 58 6 24 27 pea 39 13 10 36 pear 92 4 8 8 other fruit 67 10 16 20 other vegetable 59 10 23 17 *Both types of ponds combined —11— ------- SECTION III HARVEST AND DELIVERY MECHANICAL HARVESTING Mechanical harvesting has been applied recently to many crops and further developments are to be expected. Certain crops such as: green peas; lima beans; bush, green, snap, and yellow wax beans; spinach; corn; tomatoes; lettuce; cranberries; cherries; potatoes; beets; carrots; rutabagas; and turnips are now mechanically harvest- ed. Formerly, certain wastes such as vines and stalk were accum- ulated during harvest and disposed of in one manner or other, prin- cipally as animal feed. Much of this material is still retained in the field and utilized by the grower for feed or as a soil additive. How- ever, other unusable parts of vegetables and fruits are not separated at the field or orchard (tomato, corn, cranberry, cucumber, cherry, grape, beet, potato, and carrot) but are transported to storage or factory. Separation of cull material by hand during mechanical harvesting is being done to some extent for tomatoes and potatoes. Table AZ (in the Appendix) is a compilation of references dealing with procedures and problems in the mechanical harvesting of fruits and vegetables. Mechanical harvesting, while beneficial economically and in other respects, may be accompanied by certain undesirable effects: 1. Greater physical damage to the crop, such as: split skins on tomatoes; bruises on apples, pears, peaches and cherries; broken ends of snap beans; smashed kernels of corn; and damage to plant or tree. 2. Inclusion of soil with the harvested crop, particularly with vegetables, and greater numbers of microbes adhering to the product surface. 3. Loss in yield and delivery of products at non-optimal maturity from non-selective harvesting. Physically damaged areas of products such as tomatoes frequently become focal points for lodging of soil, sand, and dust; and for growth of various types of organisms. Rotting may readily occur at the damaged areas. Such damage or infection can be held to be indicative of unsanitary practices, and can affect the quality grade of the harvested crop and degree of safety expected in thermal processes. -13-- ------- IN-FIELD PROCESSING In-field processing or preparation of the crop for subsequent pro- cessing has been used in one form or another for a considerable period. Peas were at one time harvested on the vine and transported to the canning plant where vining (or shelling) took place. In the past twenty years, the vining has been done at stationary viners within a 10 mile radius of the fields, and more recently, almost entirely with mobile viners. Developments have also included devices to assist in the removal of “trash ’ 1 (stems, sticks, leaves, soil) from various crops which have been mechanically harvested or mechanically loaded, such as citrus, apples, potatoes, tomatoes, cucumbers, and sugar cane. Some mechanical harvesting devices also sort the products according to size. Experimental systems for sorting tomatoes by color have been developed. More elaborate experiments (580a) have included ufield site” tomato processing, in which tomatoes are processed by an acid-hot break procedure into juice for transport in bulk tanks to the cannery. The concept of pre-washing and pre-sorting snap beans has been used in receiving stations to facilitate central process plant operations. There are several advantages to such in-field treatment, including prompt processing after harvest; elimination of much damage and loss of solids during transport of fresh fruit; and retention of wastes, culls, seed, peel, and soil near the points of production. Separated wastes can be retained for disposal in field soils. Table A3 is a compilation of references on in-field processing of fruits and vegetables. SOIL LOADS ON FRUITS AND VEGETABLES There is relatively little information available on the amount of soil included with various crops during harvest. A limited survey of pro- cessors of mechanically harvested root crops indicates that soil may range from 5 to 22% of the total harvest load weight, depending on the type of root, type of soil, and soil moisture (670). The handling of crops containing much soil may cause problems during processing, such as plugging of flumes, conveyors, and sewer lines due to settling of soil. The inclusion of soil in the harvested loads has other economic implications: the withdrawal of irreplacable top -14- ------- soii and wasteful transport of unusable material. The loss of soil from the land in the annual production of canned potatoes, carrots, and beets has been estimated at 27, 000 - 54, 000 tons (670). York, et al. (701) reported the soil loads on mechanically harvested tomatoes from different type soils to range from 0. 1 to 0. 37% of the weight of tomatoes. Mercer (424) reported as high as 1. 87%. Soil loads on potatoes and carrots have been reported to be 3 - 5% of load weights (387). On the basis of total production, this would result in the removal of a few hundred thousand tons of soil from the land each year. It would appear that increased mechanization of harvest has increased the quantity of soil on many crops hence the need for more thorough water washing or alternate systems. The increased soil loads can result in the presence of organisms with greater thermal resistance (424). Increased soil loads on tomatoes due to use of mechanical harvest has increased bacterial spore loads 10 - 200 times (424). HAULING FROM FIELD TO PLANT Approximately 14 million tons of vegetables and 12 million tons of fruit are harvested annually requiring transport to a treatment or pro- cess facility. In some instances multiple transportation is involved. The procedures in handling crops for transport have changed mater- ially in the last decade. A significant development has been the direct transfer from mechanical harvesters into dry bulk loading trucks (e.g. potatoes, beets, carrots, citrus, peas, corn, tomatoes, and beans), tote bins or boxes, eliminating the use of smaller containers such as sacks, baskets, hampers, or lug boxes. There has been some transport of crops such as cherries in water. Tomatoes and potatoes have been transported in water experimentally. Transport of crops in water is believed to provide possible economic advantages as well as such benefits as partial wash or soak, cooling, and ease of transfer through fluming at destination. However, the successful utilization of water as a transport medium for harvested crops depends on several factors: 1. The adaptability of the commodity to such treatment; tomatoes transported in water, for example, are subject to splitting. 2. The limitation of container size to that at which undesirable pressures on the product, which could cause bruising during handling, do not occur. -15- ------- 3. The availability of water. 4. The control of microbial growth. The new methods of transport have been applied for economy, im- provement in quality, and adaptation to other phases of the operations. The integration of mechanical harvesting with bulk transport facilities has decreased the delay between field and processing plant, and has permitted improved management of the harvesting and processing operations. Table A4 is a compilation of references on transport of fruit and vege- table crops in-field and from field to process plant. -16- ------- SECTION IV PROCESSING OPERATIONS AND WATER USE UNIT OPERATIONS Processing steps for five typical commodities are outlined in Figure 1: peaches to exemplify fruits; peas and corn, common vegetables; beets, peeled root crops; and tomato products, pulped commodities. The principal steps where water (Or steam) is used and where solid and dissolved residuals are generated are indicated. Some steps common to all products are omitted. Detailed flow diagrams and processing descriptions for many products are in references 471 and 582. Receiving is generally in 40 - 50 pound lug boxes, half-ton bins, or larger bulk loads. The containers are dumped into the first stage vasher or flume or onto belts. The product is conveyed by flumes, pipes, belts, elevators, or other convevors between processing steps. Fluming water, generally reused, and small flows of water to belts, graders, and other equipment for lubrication and sanitation are not noted in the flow diagrams. After the outlined processing operations, canned foods are filled into cans, brine or sirup may be added, and the cans may pass through an exhaust box (a steam chamber). Some spillage occurs in filling and in brining or siruping, and a small amount of steam condensate comes from exhausting. The cans are then sealed, cooked with steam, and cooled. Large amounts of cooling water are used; it is relatively uncontaminated and may be recirculated, sometimes after passing through a cooling tower, or reused for product washing or fluming. Because it is clean, cooling water may be reused or dis- charged separately from the rest of the plant effluent, into storm sewers or directly to a stream. Vegetables for freezing are water cooled after blanching, with the generation of soluble waste. The products may be frozen before or after packaging. Freezer condenser water is handled about the same as can cooling water. Overall, final freezing operations generate less pollutional load than do final canning operations. All food processing products, containers, supplies, and equipment must be kept in a sanitary condition. Product handling equipment is washed, commonly with chlorinated water and often by continuous spraying during operations. In any case, each piece of equipment is cleaned periodically during plant shut-downs, with scrubbing and -17- ------- Blanche r/ rinse Pulper/finisher Slicer/dicer Evaporator *Optional or alternative operations in (). *Relatively clean water • * Ope ration Peaches Peas Tomato Corn Beets products Type of Waste Generated Solid Soluble Soil Water - Dry dump Water dump Air cleaner Trash eliminator Husker X X X (X)* (X) X X X X x • • S • • • S Sorting/trimming Washer Grader/sizer Cutter Peeler/rinse X X X X X X X X X X X X X X X X X (X) • • • • • • • S S • OD x (X) (X) (X) (X) (X) (X) • (X) (X) S • • Figure 1. The Use of Water and the Generation of Wastes in Typical Unit Operations ------- disassembly if necessary. Plant clean-up water contains solid and dissolved residuals and often detergents which raise the pH. IN-PLANT CONVEYANCE - Various means have been adapted for conveying fruit or vegetable products at unloading docks into and through the process plant. These include fluming, elevating, vi- brating, screw conveyor, air propulsion, negative air, hydraulic flow, and jet or air blast. Water, in one way or another, has been extensively used in conveying products within plants because it has been economical in such use and because it serves not only as conveyance but also for washing and cooling. It has been traditional to consider water an economical means to transport fruits and vegetables within a plant and to assume there was some sanitary significance to such use, not only for the product, but also for the equipment. A significant disadvantage, however, may be leaching of solubles from the product, such as sugars and acids from cut fruit; and sugars and starch from cut corn, beets and carrots. Alternative systems to decrease such losses from water have been in- vestigated, such as osmotically equivalent fluid systems (Z98, 4Z6). Table A5 is a listing of recent publications on in-plant conveyance of fruits and vegetables. WASHING AND RINSING - Fruits and vegetables for fresh market may be and those for processing are washed and rinsed. These treatments are applied for a number of reasons: 1. Removal of soil, dust, pesticides, microbial contamination, insects, and their residuals. Z. Removal of adhering juices or exudate, products of respiration or of spoilage. 3. Removal of extraneous matter such as leaves, stems, dirt, stones, and silk. 4. Removal of occluded solubles or insolubles such as occur during cutting, coring, peeling, and blanching. 5. Cooling. 6. Extraction of solubles such as preservative salts or acids. —19- ------- Table 4. The Use of Water in Washing Fruits and Vegetables Effluent load Water Used BOD SS Product Function gal/ton gal/case** lbs/ton* lbs/ton* Ref. Beans, green wash 25.5 155 (two years) 20. 8 Beans, green tank & spray 52 425 flume 108 Beets primary wash flume 100 0.8 20. 0 673 Carrots primary wash flume 90 0. 5 2. 0 673 Corn spray 8-l8(gal/min) 203 cool 10-24(gal/min) Corn husked corn washer 103 2. 5 1. 0 673 washer & silker 212 15.0 4.0 Cranberry skimmer & washer 1440 36. 5 15. 0 379 Fruits spray 385 423 Peaches spray 3 6 0(gal/min) 487 Peaches lye peel rinser 707(gal/min) 494 flume l028(gal/min) Peas wash & flume 1200 357 Peas clipper mill & wash 706 12. 0 5. 5 673 wash 432 4. 0 0. 5 Potatoes spray 2500 20.0 30.0 258 Potatoes spray & soak 640 10.7 21.0 516 peel & wash 468 2. 2 2. 2 Potatoes spray 960 5. 1 2. 7 79 Potatoes (dehydr) slicer-washer 1540 40.0 49.7 158 Potatoes primary wash flume 70 0. 5 2. 0 673 ------- Table 4. (continued) N) Water Used gal/ton Effluent load BOD SS lbs/ton lbs/ton* Product Function gal/case Ref. Tomatoes wash 13Z0 4Z1 Tomatoes first wash second wash 1-ZO 2- 4 0. 8*** 203 Tomatoes rinse after dump lye peel removal 1186 504 494 Tomatoes spray lye peel rinse lye peel rinse 712 1374 790 599 Ton of raw product Case of finished product Pounds per case ------- Table 4 summarizes reports on the quantities and characteristics of water used for washing and rinsing fruits and vegetables. The quantity of water used in wash and rinse operations may be as much as 50% of the total usage in process operations. Examples of the effectiveness of washing to reduce contamination by extraneous matter are in Table 5. Table 5. Removals by Washing Reduction Product Function Item Ref. Potatoes (dehydr) presoak & surface contamin- wash ation 0.5-12 387 Tomatoes wash soil 33-80 429 organic debris 30-64 bacterial spores 6-79 Tomatoes wash Drosophila eggs 10-70 253 Tomatoes wash bacterial spores 75-95 701 lactic bacteria 75-96 mold 76-92 Tomatoes chlorinated wash bacteria 90 486 Tomatoes chlorinated wash spores 92 469 Microbial loads, where excessive, have been shown to affect the thermal process required for sterilizing canned foods (463a). The presence of excessive mold in tomato is considered to be indicative of unsanitary conditions, and regulatory standards for mold content have been estab- lished. The presence of non-hazardous but objectionable extraneous matter (skin, leaves, stems) is a factor affecting the market grade and economic value of the product. Limits have been established for the quantities of residual pesticides in fruits and vegetables. Thus on the one hand, water is essential to prepare fruits and vegetables for processing; yet on the other hand, it creates pollution loads in plant effluents. Procedures have been recommended for reuse of water in fruit and vegetable process systems based on reduction in bacterial loads and on beneficial effects in quality. -22- ------- PEELING - The quantity of peel on fruits and vegetables affects the yield of the processed product. Geneticists have expended much effort in the development of varieties (particularly vegetables) with thin, smooth skin, absence of rootlets, and other desired conforma- tion in order to reduce peeling losses. Peel can be removed from fruit or vegetables by one method or a combination of several methods including: hydraulic pressure, im- mersion in hot water or lye solution, exposure to steam, mechanical knives, mechanical abrasion, hot air blast, exposure to flame, and infra red radiation. The more extensively used procedures for peeling root crops include: steam/abrasion, immersion in lye solution/hy- draulic or abrasion, and abrasion. Frequently used procedures for peeling fruits include: mechanical knives, immersion in lye solution, and reamers and corer s. The separation of peel wastes is costly not only for the effort neces- sary to remove it, but also for the concomittant loss of edible material. Related costs include the economic wastes incurred in growing, transporting, and handling unusable material. The equivalent cost for lagoon treatment of liquid wastes from peeling for which estimates could be derived is at least two million dollars annually, and would be much greater than this if commodities for which information is unavailable were included (670). Dry caustic peeling of potatoes is reported to achieve removal of peel with less loss of product than by the more common liquid lye or abrasion procedures (255). The major portion of the peel and lye is withheld from the effluent waste stream. Similar results have been obtained in trial runs with apricots, peaches, pears, and beets (47 2a). BLANCHING - Blanching of vegetables for canning, freezing or de- hydration is done for one or more reasons: removal of air from tissues; removal of solubles which may affect clarity of brine or liquor; fixation of pigments; inactivation of enzymes; protection of flavor; leaching of undesirable flavors or components such as sugars; shrinking of tissue; and destruction of microorganisms. Vegetables are blanched either in water or in steam at various temp- eratures and times. Water blanching is generally used for canned vegetables and steam blanching for frozen or dehydrated vegetables. -23- ------- Vegetables are water blanched in order to remove air and to leach solubles for clarity of brine. These are factors in the USDA grades of canned vegetables. For freezing and dehydration, destruction of enzymes is important. Blanching in water removes more solubles, including minerals, sugars and vitamins, than does steam blanching. The pollution loads from blanching are a significant portion of the total pollution load in the effluent stream during the processing of certain vegetables. The national amortized annual treatment facility cost for the pollution from selected vegetable blanchers is estimated at 2.4 million dollars and the annual maintenance and operation cost, about 3 million dollars (670). Research to reduce such costs should be beneficial. IN-PLANT REUSE OF WATER Table A6 shows a compilation of studies dealing with the reuse of water in the various phases of processing fruits and vegetables. These studies were undertaken primarily to establish the feasibility of mul- tiple uses of water for conservation and economy and the acceptability of multiple uses. The acceptability of procedures for reuse of water in processing oper- ations requires such consideration as: 1. Water is an excellent solvent and vector, and is readily modified, chemically, physically, and microbiologically. Thus, one use may or may not render water suitable for upstream application, such as primary washing. Recovered downstream, the water may be suitable for further use only when given enough treat- ment to be considered potable. 2. The soil, organic, or heat loads in the used water may be such that considerable treatment is necessary to render it suitable for reuse. Perhaps the most extensive work on feasibility in reuse of water has been done with peas and tomatoes, primarily in “counter-current flow systems. Another example is the use of cooling water to wash products following blanching, and this water in turn used for initial washing of incoming raw product. Consideration has been given to segregation of various wastewaters in the process plant for immediate reuse or reuse after suitable treat- ment for certain operations. The treatments required for reuse of the -24- ------- water may be relatively simple, such as chlorination, or may become quite involved, requiring sedimentation, flocculation, and filtration or other unit operations. Multiple use of water is being applied in commercial processing of fruits and vegetables. This has unquestionably permitted conservation of water and greater efficiency in the treatment required for the total plant effluent. There are many reports and suggestions on procedures for cons erva— tion of water in fruit and vegetable process operations (422, 428, 429, 431, 433, 458, 465). Few of these cite values for the magnitude of reduction in water usage. Eckenf elder et al. (213) calculated the possible reduction in waste flows by use of conservation procedures from 134 to 81 gal. 1mm in the processing of tomatoes, and from 125 to 49 gal. 1mm in the processing of corn. Cook et al. (155) showed re- ductions of 18 and 25 respectively, in the quantity of water used in two different years in processing green snap beans. Mercer (425) cited procedures for recovery treatment of brines for olives. The treatment of water to condition it for reuse in processing fruits and vegetables has been given considerable attention. Table i 7 shows a compilation of reports on the treatment of water for reuse. Two aspects of such treatment are: 1. The economic factor, that is, the cost of fresh water vs the cost of treating and recirculating it for reuse, and the cost of disposal of wastewater following its use. 2. The acceptability of the treated water for its intended use. The costs for treatment of water depend on the condition of the water and the treatment required to recondition it. If the water has acquired salt, sugars, starch, acids, or other organic or suspended materials, extensive treatment may be necessary. On the other hand, such treat- ment may be necessary anyway to reduce the total effluent degradation, or because such effluent cannot be discharged into municipal or waste streams. Eckenfelder et al. (208) have cited the maximum effluent quality ex- pressed as BOD, COD, soluble solids, and nitrogen attainable by various recovery treatments, and have related the parameters for cost determination of such water treatments. -25- ------- Treatment methods which have been cited for the recovery of water to be reused are: carbon adsorption foam separation centrifugation freezing chemical precipitation ion exchange chlorination micro screening distillation ozonation electrodialysis reverse osmosis eutectic freezing screening filtration sedimentation flocculation solvent extraction flotation ultrafiltration -26- ------- SECTION V WASTE GENERATION AND CHARACTERISTICS WASTE GENERATION BY UNIT OPERATIONS Table A8 lists estimates of the wastewater quantities, BOD or COD, and SS from steps in processing fruits and vegetables as percentages of the total amounts generated (582). These data were estimated by experienced persons in the industry and are not carefully measured values. Estimates of all three parameters for the same operation often varied widely. Some of the differences are explained by differences in style of pack, but many must come from ranges in product maturity, trans- portation method, and other factors. In many instances a concentra- tion of pollutional load in relatively little wastewater is indicated; for example, apple peeling and pulping and cherry pitting. Examples of low pollutional load in relatively larger quantities of wastewater are in the final steps for canning. Freezing generally generated less waste load than did canning. Data such as those in Tables Al and A8 point out the principal sources of the industry’s wastewater flows and pollutional loads and therefore where the greatest potential reductions can be achieved by further research and development. Much of the total waste flows from many commodities, especially from citrus, come from relatively clean water used in cooling, con- densing, and concentrating. The segregation of this water for reuse is practiced to some extent and should become almost universal. Other large waste flows are from washing tomatoes (roughly 8 billion gallons per year), peeling potatoes, peeling peaches, washing potatoes (all three roughly 2 to 3 billion gallons), cutting corn, cutting and pitting peaches, washing corn, and blanching corn (all four roughly 1 to 2 billion gallons). Large quantities of BOD are generated in washing tomatoes, peeling potatoes (roughly, more than 50 million pounds per year from each), cutting corn (more than 40 million pounds), peeling peaches, blanch- ing corn, and cutting and pitting peaches (roughly 20 to 30 million pounds from each of the three operations). Citrus by-products re- covery also generates very large amounts of BOD and SS. Other large sources of SS are peeling potatoes (perhaps 70 million pounds -27- ------- per year), cutting corn (about 40 million pounds), and washing tomatoes (roughly 30 million pounds). PEELING - Peeling of fruits and vegetables results in large quantities of wastes. Table AlO shows estimated quantities of peel in various fruit and vegetable products. The peeling must be done in such a manner that the peeled product is attractive and free of blemish or peel residue. The presence of peel in canned and frozen products is a factor in its market grade (10). Table 6 shows a summary of estimated pollution loads in the effluent from peeling fruits and vegetables reported by various investigators. Studies other than these have been reported, but the data have not been covertible to quantitative values of pollution loads. Peel wastes comprise a high percentage of the total pollution loads in the effluent of fruit and vegetable plants. BLANCHING - Table 7 shows examples of losses from vegetables during blanching expressed in BOD, COD, and SS. Table 8 shows examples of the concentrations of suspended and of total solids in the effluents from water blanching of vegetables. It is the current practice to add this waste stream to the total plant efflu- ent. The volume of effluent from blanchers is generally relatively small) and the concentrations of suspended and total solids high. There are, therefore, potential gains in the isolation and separate treatment of the effluent from blanchers. It is reasonable to consider the appli- cation of sophisticated procedures, including concentration by evapora- tion, chemical precipitation, centrifugation, and filtration, in the treat- ment of the effluent from blanchers to reduce total pollutio.n loads. NUTRIENT LOSSES Figures Z and 3 show reported changes in the nutrient content of vege- tables from water and steam blanching; mostly the changes were losses but a few gains in nutrients occurred. Many of the points of these graphs are the highest and lowest reported losses from a series of data; the losses between the extremes are not graphed. Figure 4 shows losses in soluble solids and in ascorbic acid from several experimental blanching methods. Very wide ranges in retention have been reported for most nutrients and blanching methods. Steam blanching retained slightly to definitely more ascorbic acid, riboflavin, ash, and phosphorus than did water blanching. The two methods were about the same in retaining niacin, carotene, calcium, protein, and solubles. -28- ------- Table 6. Characteristics of Wastewater from Peeling Fruits and Vegetables BOD SS % of plant Product lbs/ton lbs/cs waste stream rate lbs/cs Ref. Apricots 5-10 470 Beets (blancher/peeler) 194 4.0 84 220 lb/hr 1.0 673 Carrots (blancher/peeler) 97 1.4 65 163 lb/hr .7 673 Peaches (rinse after peeling) 40 599 Peaches 60(COD) 10 lb/ton 472a Peaches 8-12 5-9 lb/ton 470 Pears 12-18 10-15 lb/ton 470 Potatoes (peeler) 20 90 lb/ton 258 Potatoes 37-79 75-108 lb/ton 236 Potatoes (peeler, chips) 2.3 4 lb/ton 516 Potatoes (peeler! dehydration 20 90 lb/ton 516 Potatoes 32 156 Potatoes (lye peel) 186 3. 1 89 .5 673 Potatoes (dry caustic peel) 26 80 255 Potatoes (lye peel) 376 681 Potatoes (infra red peel) 260 681 Potatoes (steam peel) 260 681 ------- Table 6. Characteristics of Wastewater from Peeling Fruits and Vegetables (continued) BOD SS % of plant Product lbs/ton lbs/cs waste stream rate lbs/cs Ref. Potatoes (irifra red peel) ZOO 681 Peach/tomato (flume after peel) 1 383 ppm 665 Peach! tomato (rinse after peel) 19 1230 ppm 665 Peach/tomato (rinse after peel) . 29 20 599 Tomato (scald/trim) . 16 213 Tomato (lye peel) 39 123 Tomato (lye peel) . 30 599 Tomato (lye peel) . 12 35 599 * Pounds of BOD or suspended solids per ton of raw product, per case of finished product, or per hour of operation. ------- Table 7. Pollution Loads in Effluents from Water Blanching of Vegetables Effluent flow BOD COD SS Vegetable gal/hr lbs/ton lbs/ton lbs/ton Ref. Beets ( & peeler) 13, 100 194 (85)* 323 (83) 239 (55) 673 Carrots (&peeler) 8,420 97.6 (65) 196 (67) 338 (64) 673 Corn 270 610 (lbs/day) 860 (lbs/day) 144 (lbs/day) 213 Corn 2,272 24.6 (16) 30.1 (18) 6.0 (12) 673 Peas 1, 280 3,500 ppm 386 in effluent Peas 1,280 3,500 ppm 492 in effluent Potatoes 2, 520 52 58 37 79 Potatoes 2,310 22 32 25 79 Potatoes (&peeler) 9,210 186 (89) 279 (86) 181 (37) 673 BOD, COD, and SS in pounds per ton of raw product except as noted. ** Percent of total effluent pollution load in ( ). ------- Table 8. Suspended and Total Solids in Blancher Effluents Effluent flow SS TS Vegetable gal/hr ppm lbs/hr lbs/hr Ref. Beets (& peeler) 13,100 (51)* 122 2,510 673 Carrots & peeler) 8, 420 (49) 104 478 673 Corn 2,272 (14) 28.2 206.4 673 Peas 1,114 120 Peas 3,244 120 Peas 4,360 (20) 10.8 262 673 Potatoes hotbianch 1,800 3,300 79 wet blanch 5, 400 195 37 (per ton) 79 Potatoes (& peeler) 9, 210 (44) 70. 1 3, 330 673 * Percent of total effluent in ( ). ------- w 40 20 To Loss 10 To Gain 20 40 60 Figure 2. Changes in Product Minerals, Protein and Soluble Con- centration from Water and Steam Blanching Ash Calcium Iron Potassium Phosphorous Protein Sugar or Solubles - 33 - ------- ..i__ • $1 • •• • ••I• • S S • • 5 S. S S ... • 5 S . * 5, • . • S I. S S •• . $ S S • . •5S • S ; S .. • 5 • 5 • • S •5 S •5 5 • S $ S. ..• • •Se S S. S 5•S 55 S •5 I 55 5 S • S . 5 S S S S. . :. • S S ,& S. •• •5 •.• S •• . S I £ • . S 5 • S S. E a) S.. S S S E D a) S S . E O — a) S.. . E ( c W S S ,_• S •5 • S . 5 S e. S... S S 1W 80 40 20 %Loss 1° To Gain 20 S S S Ascorbic Niacin Riboflavin Thiamin Carotene Acid Figure 3. Losses in Vitamin Content of Fruits and Vegetables from \Vater and Steam BlanchirL - 34 - ------- so Figure 4. Losses in Soluble Solids and Ascorbic Acid from Experi- mental Methods of Blanching x =Soluble Solids 0 =Ascorbic Acid x ‘I . , .3 A 60 40 20 0 x x x 0 0 0 0 0 x x oo p 0 0 0 0 0 0 Microwave Electronic Dialectric Dialectric- Dialectric- Dialectric Water Air Spray - 35 - ------- Sparse data on experimental methods showed no or only slight ascor- bic acid losses using microwave, electronic, and dialectic blanching; and no soluble solids losses by the last. The dialectric method com- bined with water, air, or spray brought about larger losses than dia- lectric alone. All three of these combined methods caused larger losses of soluble solids than did water or steam blanching. They retained ascorbic acid better than did water blanching; and were pro- bably better for ascorbic acid than steam blanching, especially the dialectric -air process. References for the three figures on blanching nutrient losses are: Figure 2: 2, 275, 297, 299, 330, 348, 365, 367, 388, and 671. Figure 3: 2, 183, 215, 225, 226, 263, 264, 281, 297, 298, 319, 354, 355, 365, 367, 419, 454, 455, 523, 622, and 657. Figure 4: 76, 77, 275, 330, 439, 440, 452, 454, and 523. THE pH OF PROCESSING EFFLUENTS The pH of processed fruit and vegatable effluents varies among pro- ducts, among plants, and from time to time within plants. Reported pH values of fruit and vegetable processing effluents are in Table A9. High pH accompanies lye peeling; fruit, tomato, and root crops peeled in other ways may yield an effluent with neutral or low pH. Drastic fluctuations in pH occur when lye peeling tanks are dumped periodically and smaller fluctuations may result from the caustic solutions used in plant clean-up. - 36 - ------- SECTION VI TREATMENT AND DISPOSAL OF SOLID AND LIQUID WASTE SOLID WASTE SOLIDS SEPARATION - The utilization, treatment and disposal of cannery and freezer effluent wastes involves, first, effective separa- tion and segregation of the solids in the effluent. Separation of the discrete fractions may be important in economic treatment of the wastes. The effective and efficient separation of discrete solids depends principally on the physical properties of the particles, including size, density, and concentration in the waste; and on the capability of the equipment for their separation. The decision to separate the smaller particles (colloidal or suspended) from the waste depends principally on: a) whether there is value in such wastes, b) whether such material may as readily and as economically be degraded by the usual disposal systems, such as land spray or lagoon treatments, c) the potential reuse of the water from the clarified wastes, and d) increased costs of liquid waste treatment if the particulates are not removed. The cost-size relationships of different disposal systems have been reviewed by Parker (504); see also reference 123. Screening - The separation of coarse discrete waste material from the total effluent is generally done with screens. The wastes in fruit and vegetable process effluent may contain some very large pieces of material several inches in size (whole fruit or vegetable) and other material ranging from smaller in size to colloidal. The separation of the larger material can be accomplished by steel bar screens separated 1/2 inch to 2 inches, and sloped at angles 30 to 60 degrees away from the direction of flow. The removal of the separated material may be done manually or mechanically. The removal of smaller but discrete pieces of material is effectively done by mechanical screens of various types. The Tyler Standard Screen Sieve is frequently used for dimension reference of wire screens, which are commonly referred to by their number of meshes per inch. Perforated screens also are employed for limited uses. - 37 - ------- The effectiveness of screening discrete fruit or vegetable material from the effluent is affected by a number of conditions, including: 1. Mechanical features: screen opening dimensions, screen porous area, screen motion, flow rate of effluent, and conditions of flow. 2. Properties of the effluent: concentration of discrete materials and of components such as fiber, and particle dimensions. Manufacturers of screening equipment provide data and recommen- dations for various devices for screening discrete material. Gener - ally the capability of the equipment is expressed in terms of the volume of the effluent per square foot of mesh dimension. Several types of screening systems are: Stationary screens Vibrating, gyrating, oscillating screens Rotary screens Endless belt screens Screens used for separating fruit and vegetable wastes range from several meshes per inch to 150 mesh wire cloth. Vibrating screens are by far the most commonly used type and 20 meshes per inch the most common size in fruit and vegetable processing (471). About one tenth of the fruit and vegetable processors reported using no screens. Typical screening loads of wastes vary from 18 to 66 Ibs/l000 gal. and the screened waste contains 70-96% moisture (213). The degree of screening necessary may be prescribed by the nature of subsequent treatments of the waste. For example, vacuum filtra- tion and centrifugal clarification require more complete pretreat- ment for particle separation. The efficiency of screening of fruit and vegetable process effluents depends upon the proportions of large and small particles present. A limiting factor in the efficiency of screening certain wastes such as pea and corn is that a high per- centage of the dispersed solids is suspended or colloidal and not readily affected even by 150 mesh screens. There can occur also some mechanical reduction in particle size during screening of the wet pulpy solids (467). It has been suggested that, although some solids are separated from corn and pea effluent by use of fine screens, no significantly measurable reduction in BOD loads were noted (670). - 38 - ------- In other studies, only slight reduction in BOlD loads in the effluent resulted from screening cannery wastes (104, 105, 213). Table 9 shows the performance reported for various screening sys - tems applied to process effluents. Table 9. The Performance of Screening Systems on Food Processing Effluents Screen Screen Input Waste type mesh Product Load Removed Ref. Oscillating Oscillating Oscillating Oscillating Oscillating Rotary Rotary Vibrating Vibrating Vibrating Vibrating Vibrating Vibrating Vibrating Vibrating Vibrating 100 Beet-carrot 24 Beet-carrot 60 Peas 24 Potato- carrot 50 Potato- carrot 28 Red beet 28 Tomato Beet 100 Beet-carrot 10 Beet-carrot 50 Peas 56% SS 79% SS 7-17% SS 2% SS 44% SS 400-600 lbs (135 lb/ft. 2 /hr.) 60% SS 13% TS, 35% settl. sol. z0% TS, 47% settl. sol. 32% SS Zl6a 216a 670 670 670 33 2% SS 670 0% SS 670 670 60% SS 670 21% SS 670 Vibrating 40 287 670 (8-12, 000 gal. /hr.) (975 gal. /ft. 2 /hr.) (500 gal. 1mm) 10 Potato- carrot 10 Potato- carrot 30 Peach 30 Pumpkin 48 Fruit- tomato 0% SS 670 420 420 467 - 39 - ------- Screening is an effective, economical procedure for removal of dis- crete material of particle sizes which may interfere with the treat- ment of liquid effluents in spray, lagoon, or municipal systems. The suitability of fine mesh screening for removal of material of lesser size depends on the capability of the screens, the concentra- tion of such solids in the effluent waste, and the costs of such removal. There is a lack of reliable information on the efficiency of the sim- pler screening systems for the removal of smaller dispersed mater- ial and on the physical characteristics of such material. The con- centrations of suspended solids in screened total process effluents are of relatively low order. Suspended solids in process effluents are reported in Table 10. Table 10. Suspended Solids in Screened Effluents from Food Processing Product % SS Total in Screened Effluent lbs SS per 1000 Cases Ref. — Apples 0.005 221 Beets 0. 10 53la Beets 1100 673 Carrots 0. 11 531a Carrots 708 673 Corn 0.16 531a Corn 220 673 Peas 0.04 531a Peas 0.003 221 Peas 800 637 Peach rinse 0.04-0.15 430 Peach 0.01-0.001 221 Pear 0.03 221 Potatoes 0. 10 531a Potatoes 530 673 Tomato 0.3-8.0 213 Tomato 0. 04-0. 10 430 One study indicated that single deck, circular, vibrating screens had twice the hydraulic capacity of table top screens with comparable mesh size and area; and that the hydraulic capacity was 50% greater in two deck than in single deck, circular, vibrating screens (467). - 40 - ------- Sedimentation, settling and chemical precipitation - Sedimentation is employed to remove suspended or settleable solids from fruit and vegetable process waste effluent. Sedimentation or settling of solids occurs in collecting ponds or lagoons. Separation of the solids from the effluent can be done in settling basins or tanks prior to the discharge of the wastes for further treatment. The basins or tanks are often equipped with overflow wiers and baffles for continuous operation and with means for addition of chemical agents to facili- tate flocculation of the particulate matter. Factors involved in the effectiveness of the systems are physical properties of the particle, viscosity, and turbulence. Parameters for conditions for removal of the suspended solids can be established from laboratory tests. The flocculation and settling of suspended material may be accele- rated by use of coagulants such as alum (aluminum sulfate), and ferric and ferrous sulfate (669), which react with hydroxyl ions to form hydrous oxides. The latter are relatively insoluble at normal pH values and tend to floc, coalesce, and settle. There is much greater potential in the application of procedures for the removal of coagulable and settleable solids from the effluent flow at various stages in the process line where the concentrations are greatest. The concentrations of settleable solids in tomato wastes and tomato-peach wastes were greatest at the skin peeling and removal areas (459). Similar concentrations were found in the processing of peas, corn, beets, carrots and potatoes (673). Pre- liminary trials have indicated such solids can be effectively removed by sedimentation and other procedures. There is need, however, for economic evaluation of such applications. The efficiency of removal of suspended matter from certain vege - table wastes by chemical coagulation and by primary settling is in the range of 60-80%. Table 11 shows the reduction in SS and in BOD by such treatment. However, since there is a very high level of total dissolved solids in such wastes, the net reduction in BOD in the effluent is frequently insufficient to permit its reuse for some purposes even after such clarification (669). Table 12 shows the concentrations of SS in typical cannery wastes, after screening. - 41 - ------- Table 11. Efficiency of Chemical Coagulation of Screened Effluents Coagulants BOD SS Removal Product p pm ppm ppm Effi. BOD Alum Lime Infl. Effi. Infi. SS Peas 44 266 68 39 95 18 42 81 Beets and corn 65 357 222 196 259 47 28 82 Lima beans 39 136 142 121 146 26 15 82 Lima beans and spinach 22 218 130 89 212 52 32 75 Reference 669. (Figures rounded) ------- Table 12. Suspended Solids in Screened Fruit and Vegetable Effluents SS Product % lb/Case Ref. Apples Apricots Asparagus Beans, baked Beans, green/wax Beans, kidney Beans, lima Beets Carrots Cherries Corn, cream style Corn, whole kernel Cranberries Peas Peaches Potatoes, sweet Potatoes, white Pumpkin Sauerkraut Spinach Tomatoes .03 -.06 .02-.04 .003-.018 • 02 •006-.015 .014 042 .074-. 22 • 18 .02-. 06 .03-.067 .03-.40 .01-. 25 .027-.04 .045-.75 .04-. 25 .09-. 118 .078-. 196 • 063 •009-.058 .019-. 20 0. 10-0.20 0. 14-0.25 0.02-0. 12 0.07 0. 02-0.04 0.02 0.02-1.02 0.05-1.0 0.04 0.05-0. 14 0.07-0. 17 0. 20-0.95 0. 02-0. 05 0. 06-0. 20 0. 024-0. 034 0.31-1.95 0. 38 I, I, Ten to 30% BOD removal and 50 to 80% SS removal by sedimentation of cannery waste effluents have been estimated (637). In potato plants sedimentation removes 41 to 70% of the BOD and 73 to 93% of the SS (186, 257, 351). A study has been reported (123) on a city treatment plant which received waste flows from 1’7 canneries with an aggregate of 583,000 tons of raw products per year, about half tomato. Primary treatment removed about 44% of the BOD and 74% of the SS during non-canning months, when the flow was 55 to 60 million gallons per day; and about 18% of the BOD and 62% of the SS during canning months, when the flow was 75 to 80 MGD. 637 ‘V ‘V ‘V ‘V ‘V ‘I ‘V 503 - 43 - ------- Eldridge (217) reported BOD removals of 33 to 75% in effluents from beet, tomato, pea, corn and kraut processing using lime, alum, iron sulfates and chloride, and zinc chloride in combinations at 700 to 2520 mg per liter. A BOD removal of 50% in tomato effluent with 40-50 mg/i of lime has been reported (592). BOD removals of 39 to 75% have been reported (637) from tomato, beet, corn, carrot, pea, and wax bean wastes flows using lime alone and in combination with alum or iron sulfate; with lime alone, 86 and 90% SS removals were reported for tomato and beet effluents, respectively. Poor removals of BOD and COD were observed in the laboratory using peach and tomato waste water treated with lime (123). BOD was oxidized from the waste at the rates of 1. 8 parts per part of potassium permangmate per hour, and 1 to 6 parts per part of chlorine (from NaOC1) per hour; these treatments were considered simple but expensive. Vacuum filtration - Vacuum filtration requires relatively heavy investments for the removal of solids and has had limited usage in the treatment of fruit and vegetable wastes. However, this method has been used in solids thickening and removal of starch in the pro- cessing of potatoes. There is little information available on its application to fruit and vegetable wastes, and parameters and po- tentials for vacuum filtration in reclaiming water for reuse are not known. Centrifugation - Centrifugation is used extensively to separate highly dispersed and suspended materials which have economic value. There are virtually no published data on its application for removal of SS from screened fruit and vegetable effluents. Pilot studies indi- cate that separation by centrifugation of such dispersed solids as corn, carrot, and beet (peeler effluent) is mechanically feasible (670). The concentration of suspended solids in the total effluent from the industry’s plants is relatively low. But concentrations are suffi- ciently great at certain stages in the process to warrant application of special procedures for removal, and to reclaim water. Probably the SS will have only low value, except where specific components may be isolated (starches, waxes, etc. ). There is little informa- tion on the economic appraisal in removal of SS from fruit and vege- table wastes, either for obtaining the solids, for reclaiming water - 44 - ------- for reuse, or for reducing BOD loads in the total effluent. The SS may be a problem in the formation of scum layers in lagoons and sewage treatment plants (230, 378). Eckenfelder (205) described the use of centrifugation for separating sludge at various stages in the treatment of paper, municipal, and other wastes. Flotation - SS may be removed from effluents by air flotation. The procedure starts by subjecting effluent waste to air pressure in pressure vessels. When the effluent, supersaturated with air, is released to atmospheric pressure, the excess dissolved air is re- leased as small bubbles to which suspended material becomes attached and separates as foam or float. The use of lime and alum to floc the suspended organic material aids in its separation. Nelson (478) reported 50-80% SS removal from peach and tomato waste water at flows to 7000 gallons/square foot/day by flotation. Pilot plant flotation treatment of peach and pumpkin effluents with air rates of 0. 46 to 0. 60 cubic feet/minute has been described (458). Influent BODs were about 2000-2400 ppm for peach and 2200-2600 ppm for pumpkin wastes; ingoing pH, around 10 for peach and 6.7 for pumpkin. Percent removals with peach and pumpkin wastes, respectively, were: BOD, 17 and 7; SS, 84 and 62; total solids (TS), 16 and 2; and settleable solids, 94 and 99. Sulfuric acid neutra- lization improved BOD and settleable solids removal from peach waste. Lime addition depressed SS removal from peach waste to 73%, resulted in no decrease in peach waste settleable solids, brought about increases in SS and settleable solids in pumpkin waste, but improved BOD removal to 30% in pumpkin waste. Dissolved solids removals were mostly poor, but reached 26% in the lime treated pumpkin waste. Pilot plant flotation studies were reported (467) on a two-stage pumping system with air injection between the two pumps and a short pressurized hold before release to the flotation tank. Ratios of raw waste flow to recycle were varied from 1:1 to 3:1; and solids loading from 0.3 to 2.2 lbs/hour/square foot for peaches and 9.7 to 19. 5 lbs/hour/square foot for tomatoes. With peach lye peel rinsewater the best SS removal was about 93% at a flow rate of 1. 0 gallon/minute/square foot; the poorest about 65% at 2. 6 and 2. 9 gpm/square foot. SS removals from tomato process water (which contained field soil) were 84% at 1. 0 gpm/square foot and 61% at 2. 9 gpm/square foot. - 45 - ------- The separation of SS (and minimizing formation of sludge) from fruit and vegetable effluents has been found feasible through use of vacuum flotation procedures. When aerated liquid is subjected to vacuum, minute bubbles are released and become attached to particles which migrate to the surface where they can be removed. Treatments of 0.025-0.05 cu.ft. air/gallon effluent/30 sec were effective. Remo- val of suspended solids from effluents of tomato, pear, asparagus, string bean, and spinach ranged from 77-98% (230, 378). SOLIDS DISPOSAL - Many recent changes in processing procedures affect the utilization of waste: 1. The scale of operations has increased in virtually all fruit and vegetable processing. Operations have been consolidated in fewer plants and within fewer management organizations. The quantities of product handled per hour are greater than before. 2. There has been sophistication in methods of separating wastes at the time of harvest (mobile mechanical harvest) and in pro- cess lines (improved separation devices). 3. Transport facilities (roads and trucks) have improved consider- ably in the past decade so that there can be and is more trans- shipment of unprocessed crop to plants for processing, and there exists better opportunity for withdrawal and consolidation of wastes for treatment. 4. There have been developments in preparing crops for ensiling preservation and utilization of plant leaf for proteins. 5. Animal and poultry feeding procedures have been sharply refined with better understanding of the nutritional requirements of these species. The growing of animals and fowl has been up- graded in scale. Feed cost/weight gain ratios are critical in successful feeding management practices. The acceptance of any livestock feed is affected by availability, cost, and perfor- mance. 6. There has been a continued increase in the utilization of canned and frozen food, accompanied by a decrease in utilization of - 46 - ------- fresh” product, in homes, restaurants, and institutions. This has increased the quantity of fruit and vegetable waste to be dis- posed of at processing plants and decreased the quantity dis- posed of, relatively, in community systems. 7. There is greater emphasis both legal and political on the need to reduce pollution by all industrial organizations, including food processors. Residents of communities near food processing operations exert continued pressure to correct undesirable con- ditions, emphasizing the problems in waste disposal. Although the solid wastes from most commodities have little use and are disposed of mostly by filling or spreading on land, the residuals from some are used extensively for animal feed. Examples are citrus, corn, pineapple, and potato. These commodities are pro- duced in large tonnages for processing and are located in areas where cattle or other stock are available for feeding. Citrus, pine- apple, and potato are processed during most of the year and the silage from corn can be stored. Largely as a result of this use of these commodity residuals, about three-fourths of all residuals from fruit and vegetables processing are disposed of as by-products (47 1). Smaller quantities of residuals from many commodities are used for vinegar (33,000 tons), charcoal (30,000 tons), alcohol (18,000 tons), and other by-products (57, 000 tons). The figures in paren- theses are estimated total annual tons of residuals used for each purpose (471). Burch et al. (114a) have analyzed problems in handling food wastes: relative costs in disposal and utilization; marketing problems for derived materials; and research and development problems involved. They cite possible disposal procedures for food wastes including: municipal systems, dump disposal, lagooning, spray and furrow irrigation, and incineration. They stress the necessity of first knowing current costs of waste disposal for comparison with alter- native methods. Marketing problems in the utilization of wastes are most difficult to solve. Most cannery and freezer wastes have high moisture contents. Removal of the moisture may also remove carbohydrate solids, which are of low value commercially. Removal of extractives of some value may result in fibrous residuals of low value. - 47 - ------- Establishing the market position for many processed wastes requires establishing a competitive price principally on the basis of replace- ment. Factors affecting market acceptance for derived products are: 1. The adequacy of the supply, which may be serious in light of the seasonal operation of many food processing plants. 2. The perishable nature of the wastes, which require conversion. 3. The necessity of users to alter their formulations in order to utilize the processed wastes or derivatives. 4. The costs of additional handling and transport. 5. The low value of the wastes compared to other sources of nu- trients, oils, etc. Ben Gera and Kramer (87a) have presented an excellent review on the utilization of food industry wastes. It is evident that for some wastes in-depth appraisal has been made of the feasibility of their utilization. Some studies also include appraisal of the economic feasibility of utilization of the wastes. LIQUID WASTE BIOLOGICAL TREATMENT - Many types of microorganisms remove organic materials from liquid wastes. Those most commonly used in treatment systems are heterotrophs, which utilize organic carbon for their energy and growth. Some are aerobic and require molecu- lar oxygen for converting wastes to carbon dioxide and water. Others are anaerobic and grow without molecular oxygen. Anaerobic micro- organisms grow more slowly than aerobes and produce less sludge per unit of waste treated than do aerobic microorganisms. Anaerobes also release acids and methane, and their action on sulfur-containing wastes may create odor problems. Some microorganisms are facultative; that is, they can grow in either an aerobic or anaerobic environment. Added nutrients, most often nitrogen and sometimes phosphorous, may be required for efficient biological treatment of food processing wastes. - 48 - ------- The multiplying microorganisms produce a sludge, measured as volatile suspended solids (VSS), by conversion of the soluble organic waste materials to bacterial cells. The rate of sludge generation is constant for a given waste under steady state conditions. In aerobic systems, oxygen is needed for both conversion of organic matter to cellular material and for cell maintenance. The settling char acter- istics of the sludge are important in affecting the ease of its removal from the system. Sludge settling rates depend on the types of micro- organisms present and their growth conditions. Therefore, operating variables such as waste physical and chemical characteristics, waste loading rates, holding times, degrees of aeration, and propor - tions of sludge recirculat d in the system will affect sludge settle- ability. Eckenfelder (205) discussed and quantified the factors influencing biological waste treatment. Esvelt and Hart (223) studied their appli- cation to fruit processing wastes, and SCS Engineers (582) reported descriptions, advantages, and disadvantages of several biological (and other) treatment systems. Anaerobic ponds - In anaerobic ponds biological degradation of organic material occurs in the absence of dissolved oxygen. The ponds are typically deep and heavily loaded with waste, reducing the land require- ment per unit volume of effluent, and are used especially for stabi- lizing solids, including sludge from other types of treatment systems. In facultative ponds the anaerobic condition exists in strata of other- wise aerobic ponds. Under anaerobiosis, organic materials are con- verted to methane, hydrogen sulfide, ammonia, organic acids, and others, as well as to carbon dioxide and water. Conversions of 80 to 90% of the organic load may be achieved, at a slower rate and producing less sludge than in aerobic systems, but undesirable odors may be generated. Higher temperatures increase the efficiency of anaerobic systems except between 37 and 45, and above about 58 degrees C. (l87a). Some performance data on anaerobic ponds are in Table 13. - 49 - ------- Table 13. Anaerobic Pond Performance on Screened Food Wastes BOD lbs/l000cu ft/ Detention BOD, % Product ppm /day days removed Ref. Cannery 9.6-430 1/6-37 (pilot) 40-95 6 Citrus 4600 21.4 1.3* 87 411 Corn 70-104 6-11.3 25-69 135 70-104 6_ll.3* * 53 135 Fruit, sewage 360-1200 110-430 1/6-1/4 (lab) 50-70 484 Pea 81.5-159 2.8-3.9 22-29 135 81. 5-159 2.8-3. 9** 47-49 135 Pea blanch 30000 10 90+ 492 Tomato 550 7.5 7.4 80 288,289 5. 1 9.25 82 288, 289 86 37 98 288, 289 2.5-9.9 7.5-10 70 - 96, 600 Tomato, lirna 1975 2.53 40 126 * Contact anaerobic process With added sodium nitrate Lagoons and stabilization basins - Lagoons, ponds, or basins are extensively used for treating food processing wastes where land is available. Holding or storage ponds are large enough to accommo- date a whole season’s effluent for discharge when a receiving stream is at maximum flow or to land, or for dispersal by evaporation. Some waste conversion occurs during the holding period by settling of solids and by biological processes. Oxygen may be supplied for aerobic bacteria by algae in “aerobic or in Ifacultativeut ponds; the latter are partly aerobic and partly anaerobic in action. Odors and seepage to ground water may be problems; large land areas and insect controls are necessary; and the reduction of pollutional load may be low. Increasing urbanization, which increases land costs and odor annoy- ances, and increasingly strict discharge requirements on pollu- tional loads have led to developing more efficient lagoon operations, by nutrient additions and especially by aeration. Suggested design - 50 - ------- factors for various types of stabilization ponds are in Tables 14 and 15. The suitability of a lagoon or other biological waste treat- ment system is thus determined not only by cost, but also by such social factors as urbanization and pollution regulations. Table 14. Typical Design Factors for Stabilization Lagoons Aerobic Anaerobic Aerated Depth, ft. Detention, days BOD loading, lb/acre/day Percent BOD 0.6-3. 2-20 50-200 80-95 0 3-6 7-30 20-50 75-85 8-15 5-25 300-1000 50-70 6-15 2-10 55-90 removal Algae concentra- tion mg/liter 100 10-50 nil nil * Reference 532. - 51 - ------- Table 15. Stabilization Lagoon Land Area Requirements Facultative Ponds Aerobic- Aerated Anaerobic Aerobic (A) (B) algae lagoon pond Area 84 acres 73 acres 19 acres 2. 6 acres 2. 82 acres 42 acres Depth 6 feet 6 feet 1 foot 10 feet 6 feet 6 feet Retention time 82 days 72 days 6 days 4. 0 days 4. 60 days 41 days Loading 50 57 200 lbs BOD/acre/ day Reference 532. ------- Canham (135) reported that a pure culture innoculation failed to improve the perfirmance of lagoons and that enzymes and odor maskers in the lagoon were not proven to help. Porges (517) stated in 1963 that of 827 waste water lagoons in use in the United States, 238 were fir canning wastes. Data on the performance of lagoons are summarized in Table 16. Table 16. Stabilization Lagoon Performance in Treating Food Processing Wastes hOD, ppm hOD Detention BOD % Product in out lbs/acre/day days removed Ref . Apricot, peach 90 106 96 502 800 47 79 502 500 78 93 502 600 70 88 502 Cannery 4770 2.5 40 124 786 72 90 124 Citrus 200 120 83 324 Corn 2760 42 84 566 2760 40 95 566 2936 9.6 59 213 774-3700 11-56 (6 ponds 181 in series) Pea 1430 49 91 566 70 84 96 180 337-1050 17 58 (6 ponds 181 in series) Potato 1000 116 91 495 Tomato 628 17 74-81 502 396 26 80-81° 502 1800 42 93 566 Tomato, citrus 662 22 74-75° 502 135 17 85 88° 502 * With added nutrient - 53 - ------- Aerated lagoons - Several systems have been developed for mecha- nical transfer of oxygen to aerated lagoons, including surface mechanical aerators and pumped air injectors or diffusers. The achieved concentration of oxygen affects the efficiency of BOD con- version, and the oxygen transferred to the lagoon per horsepower- hour is an important factor in cost. Aerated lagoons resist upsets from organic load and pH shocks and can achieve good BOD reductions without odors. In this treatment system the biological solids (SS) remain in the treated effluent. Performance data on aerated lagoons are in Table 17. Activated sludge - An activated sludge system is one in which the solids from an aerated treatment system are settled and returned to the first treatment basin. Several modifications of this basic scheme are in use. Poor settling sludge is often associated with activated sludge treatment of food processing waste. This problem may be the result of: a) filmentous organisms which tend to outgrow other forms at concentrations of dissolved oxygen below 0. 5 ppm, or b) diffuse bacterial flocs which may form at high growth rates (205). The process can achieve 90% or higher reductions in BOD and in SS under good operating conditions. Jewell and Eckenfelder (322) reported experiments with pure oxygen for aeration in a pilot scale activated sludge unit, using brewery waste. The pure oxygen improved sludge settling characteristics at high mass loadings with 90% COD removal. Performance data are in Table 18. Trickling filters - A trickling filter is a porous bed with a bacterial slime growth. As liquid wastes are passed down through the bed, they are biologically oxidized by organisms in the slime film. The filter may be deep or shallow and the packing medium stone, wood, or plastic. Many modifications in the system are possible, including changes in dimensions, medium porosity, waste flow and its organic load, recycling, adjustments in nutrients, pH, or temperature, and aeration. In an ideal system the various factors are in balance for maximum degradation of the BOD input. Some of the factors can be monitored and controlled. Data on the performance of trickling filters are in Table 19. - 54 - ------- Table 17. Aerated Lagoon Performance in Treating Food Processing Wastes Influent BOD Detention BOD, % Product ppm days removed Ref. Beet 4236 1. 1 98 273 3830 .75 96 273 Cannery 360 4.5(17.2 C) 94 522 920 4.5( 6.3 C) 43 522 980 13 ( 8.5 C) 95 522 1650 (COD) 2-5 50-80 489 Carrot 1910 .37 86 273 Pea 535-1212 12 76-97 581 970 .39 94 273 578 . 23 93 273 820 5.6 78 187 3000-44o0 5.5 76 184 Pea,carrot 1260 .25 81 273 Peach 1650 . 16 54 420 1100 .6 60-70 545 Potato 1000 82 97 487 Pumpkin 1380 .35 60 420 6 77 198 6 85 198 6 88 198 2500 1.2 50-60 545 Tomato 5 68 213 1500 98 286 Tomato, corn 580 5 (lab.) 71 489 550 4 (lab.) 61-70 489 890 3 (lab.) 60 489 840 2 (lab.) 59 489 605 1 (lab.) 43 489 * Pounds/acre/day - 55 - ------- Table 18. Activated Sludge Performance in Treating Food Processing Wastes Influent BOD lbs/l000cuft Detention BOD, % Product ppm lbs/lb solids /day hours removed Ref. Apple 1200-1400 90-330 91-99+ 222,223 Bean,snap 140 2.4 101 35 96 Beet 4000 2.0 9.3 96 117 i i 3700 6. 6 (pilot) 82 309 it 4800 20 (pilot) 97 309 5300 4 0 (pilot) 98 309 Cannery, 50-70 6(# 6 sludge 90-95 484 sewage rearation) 200+ 70— 484 300-1600 .47 200 4.6 & 8 90 501 a’ “ .14 148 87 123 Citrus 1200 . 04-. 38 (pH adjusted) 98-99. 7 325 Food, sewage 100 4- . 1+ 97 254 Pea, carrot 1100 6. 6 (pi1ot) 89 309 1500 2.5 3. 1 H 95 117 Peach 3200 24 95 82 96 860-1800 70-120÷ 80-98 212,223 Peach, tomato . 12-. 65 (lab. ) — 93-98 123 i i i i 740 . 65 - ‘,- 1. 58 209 Pear 1600-2000 80-170÷ 99 222,223 Pimento 810 50 25 — 61 96 Potato 2100 20 129 74 96 138 20(pilot) 92 160 210 10(pilot) 86 160 480 1 + 10(pilot) 59 160 ------- Table 18. Activated Sludge Performance in Treating Food Processing Wastes (continued) Influent BOD Detention BO]J, % lbs/lUUUcu ft Product ppm lbs/lb solids /day hours removed Ref. Potato 500 1 + 6(pilot) 49 160 1000-2000 .3-.4+ 190-360 6(pilot) 98— 79 1000-2000 .3-.4÷ 190-360 .5+2(pi1ot) 50— 79 1000-2000 .3-.4-s- 190-360 1-1.5+6-8 80— 79 (pilot) 230-410 8 (lab.) 85-99÷ 601 65-280 12 98 601 Tomato 410 .8+1.6 ’ 85 209 U-’ — I , 540 .35 + 1. 84 209 Tomato, apple 490 1.0 + 2. 90 209 Vegetables 2-14 (COD) 4. 9 (high rate 33-99 607 unit) 36 (extend. 56-99 607 aer.) With added nutrients Aerate and clarify in the same unit Contact stabilization ------- Table 19. Trickling Filter Performance in Treating Food Processing Wastes Influent BOD ppm lbs/l000cu ft/day BOD, % P rn (‘ r ri P f 320 150 1200 500 1600 100 500-2000 500-2000 2300 (COD) 2300 (COD) 3400 (COD) 1100 1100 640 40 640 950 1200 1 600 50 gpm 100 gpm 150 gpm • 66 gal/sq ft/mm • 88 gal/sq ft/mm • 88 gal/sq ft/mm 1. 5 gal/sq ft/mm 15-20 mgd (1:10) (1:5) 150 gpm 100 gpm 150 gpm (1:1) (1:1) (1:1) (7:4) (1:4-5) pilot pilot pilot pilot 35 484 94- 278 94.- 278 46 432 50 432 33 432 53 467 20 467 39 467 26 467 14 366 78 366 25 549 25-37 593 Product Recycle Flow JR wxecvc1e I L I ’ 03 1-7 gpm 1-7 gpm 7-14 gpm 7-14 gpm Apricot Beet Cannery Cannery, sewage Corn ‘V Fruit Pea 60 80 100 140 to 150 to 110 34 87 80 50 80 77 -85 63 -78 50-68 35-57 549 549 549 549 148 484 484 484 484 l2ftdiarn l2ftdiarn 1 Zft diam pilot 180- 420 ------- Table 19. Trickling Filter Performance in Treating Food Processing Wastes (continued) Specialities Vegetables (500 lbs/acre- foot/day) (1000 H H (2000 H H (3000 H H 2-5 gpm 2-5 gpm 2-5 gpm 70 160 gal/sq ft/day 36 mgad .72 mgad 1.4 rngad 2.2 mgad 830 gal/sq ft/day .38 mgd pilot pilot pilot pilot pilot pilot pilot pilot pilot pilot pilot BOD, % Removed Ref . 50 702 41 549 45 593 90 702 33 549 29 432 44 432 24 432 23 432 85 432 75 161 49 161 35 161 90+ 122 94 601 92 601 77 601 55 601 53 142 69 149 Plastic medium With added nutrients Influent BOD Recycle ppm lbs/l000cu ft/day Flow (Raw:recycle) 220 250 52 Product Pea Pea, carrot Pea, sewage I, Peach I It U i ‘ .0 Potato ‘I I, 800 720 2700-4000 2700-4000 2700-4000 2700-4000 2700-4000 960 2300 2500 2900 2400 400 600 800 (1: 14) (3:14) (5:14) (7:7) (7:7) 14 gpm 15 gpm 14 gpm 600 145 2 stage filters ------- City treatment - Preliminary figures from reference 471 showed the following percentages of canners and freezers of the tabulated products disposing of effluents to city systems in the continental U.S. snap Product: citrus tomato corn potato peach apple bean pea pear 1* 67 40 43 83 30 58 39 92 other fruit other vegetable 67 59 Reference 232 The degree of purification at public treatment plants varies widely; estimates of their average removals are (637): 75% of the BOD, 85% of the SS, and 14% of the total dissolved solids (TDS). Other biological treatment - Yeast fermentation has been used for the production of alcohol and yeast and for treating food wastes simul- taneously. Torula yeast has been grown on waste from citrus (24), potato (539), and other wastes (63 6 a) but the process has not been widely adopted. Stricter waste effluent standards may make the me- thod more attractive. Strains of the fungus genus Imperfecti have been propogated on corn and soy bean wastes in pilot studies (151). Reductions in the COD of corn waste from 2, 500 to 100-400 mg/liter in 20 days and fungus mycelium yields of 1000 mg/liter have been reported. The prelimi- nary tests are promising and conditions for good growth of the fun- gus have been fairly well established. McCarty (401) has discussed results with a pilot scale anaerobic fil- ter, a medium something like a trickling filter but kept submerged and anaerobic by the effluent flowing upward through it. BOD removals of about 60% (at 4. 5 days detention) to about 98% (at 3 6-72 days detention) have been observed experimentally with strong wastes (750 ppm COD and higher). Relatively little sludge was produced and the filter responded well to intermittant operation. However, clogging with waste solids may be a problem and pH must be con- trolled. - 60 - ------- LAND DISPOSAL - The successful disposal of fruit and vegetable wastes onto land depends on a number of factors. Engineering aspects include infiltrative and percolative capacities of the soil, clogging, quality changes in the soil, and the engineering of soil systems (405). Other factors are the trans location of the underground water to springs and streams or through i aults to water supplies, evaporation, and transpiration through cover crop plant growth. The effects of disposal of wastes into the soil mantle are as complex as are the wastes. While many operations appear to be successful, the long term effects are less clearly understood. Several considera- tions are important for successful disposal of food wastes into the soil; they are: 1. Land area: sufficient land area must be available to handle the waste during peak operations without overloading. Some pro- visions should be made for land to accommodate expansion of operations. 2. Soil: the character of the soil is important to acceptability of land for irrigation. 3. Slope: some slope is desirable to minimize ponding of water which is followed by destruction of plants, bacterial decomposi- tion, and odor development. Too great a slope may result in excessive runoff. 4. Rest interval: the necessary rest interval depends on several factors, including BOD load during spraying, porosity of the soil, and the distribution of the effluent. 5. Cover crop: this is essential for the spray irrigation method of soil waste disposal in order to increase absorption and transpira- tion, and to prevent soil settling and erosion. A dense cover crop protects the soil from physical change, increases transfer of water to soil through the root system, and from the soil to atmosphere by evapo-transpiration. 6. Waste: wastes vary considerably in characteristics such as pH, BOD, ratios of nutrients, SS, soluble solids, and salt concentra- tions which all affect the soil mantle. These, ultimately, affect degradation of the wastes. - 61 - ------- Spray irrigation - Spray irrigation consists of spraying screened liquid wastes from vegetable or fruit process operations onto land where it undergoes percolation into the soil and biodegradation. Spray irrigation of sewage wastes was practised as early as 1860- 1870 (579) and of cannery waste beginning at least in 1947 (574). A large variety of cover crops have been successfully used for spray irrigation fields. There is, however, a great difference in the capability of various crops to absorb and transpire water. Cover crops used include planted vegetable crops, grasses, stands of native bush, trees, and orchards. In many instances efforts are made to maintain stands of certain grasses while in others the prac — tice has been to let natural survival determine the stand. A dense growth will transpire 10-20 inches of water per season (110). Percolation studies of cannery wastes in lysimeters have been made (305, 546). Waste waters from process plants have been found to contain greater concentrations of sodium and chloride and were more acidic than fresh waters. Permanent pasture was affected adversely by spraying of blancher water (588). Hydraulic loading was a prime factor in disposal of plant effluent (199). Spraying on wooded waste- land over a period of three years resulted in gradual replacement of the natural stand with other plants (583). The parameters of water and waste disposal on land vary depending on the nature of the soil and land. Applications ranging from 0. 4 to 1. 0 in. /hr with suitable interval rests of six days have been cited (129, 437, 442). Lane (359) found feasible a precipitation of 87, 000 gal. /acre/day (absorbency of 3 inches/day), with rest intervals of 4-10 days. BOD applications have been reported up to 649 lbs /acre/ day and SS, 285/lbs/acre/day (99, 100). Spray irrigation on slopes draining to lagoons appears to be very successful and adaptable to soils which limit lateral movement of underground water (618); 99% reduction in BOD, total color removal, and 90% reduction in N and P may be expected. Comrninuted pea waste has been applied to soil by spraying an esti- mated 1000-1300 tons/acre at rates of 1 inch per acre/day, equiva- lent to an average of 0. 15 inch/day for the season (128). - 62 - ------- Monson (442) reported that 250 canneries used spray irrigation sys- tems in 1957. According to Ebbert (201), 50 out of 118 canneries in one midwestern state used spray irrigation in 1958; Zall Research Associates (547) found 4 out of 14 surveyed canners and freezers and 1 out of 23 surveyed dairies using spray irrigation in 1967; in addi- tion, three of the former and 10 of the latter were situated where they could have installed the system. Preliminary figures from reference 471 showed the following percen- tages of canners and freezers of the listed products disposing of effluents by irrigation in the continental U.S. Product: % citrus tomato 34 13 corn 44 potato peach 21 11 apple 30 snap bean 27 pea 36 pear 8 other fruit 20 other vegetable 17 * Referen ce 232 Bendixen et al. (89) estimated there were 2, 400 systems for disposing of effluents to the land in 1965 and that 900 of these were used by food processors. Performance data on spray irrigation are in Table 20. Other irrigation systems - The ditch and furrow system consists of developing shallow ditches in the land through which effluent is direct- ed. At intervals of use the land is permitted to dry, is disced, and refurrowed. It has been estimated in one operation that 46 inches of effluent were spread over 66 acres in 4 months operation, refurrow- ing after 18 inches. About 50% of the effluent was believed to eva- porate and the balance to percolate. All accumulated SS were disced into the soil. The estimated soil loading was 0. 124 lb of COD per square foot per day, based on 66 acres in use, 100 days operation, and 35, 600 lb daily COD load (13). - 63 - ------- Table 20. Spray Irrigation Performance in Disposing of Food Processing Wastes Flow Applied BOD 1000 gal/ inches! Product ppm lbs/acre/day acre/day day Crop Ref. Aspar.,bean 22 3.5 637 Cannery 9 1/3 alfalfa, cut, 180-day yr. 87 210 210 60-120 6.4 wooded, 8-month yr. 399, 667 210-1800 361 Cherry 810 3.6 637 Corn 860 3.4 637 20 pasture, wood 572 Dairy 140-680 2.1-5.4 mostly grasses 361 Lima 65 . 38 637 Pea 150 4.0 199 1200 5.9 . 16 grass, cut, inc. solid waste 132 Pea,corn .5 grass,cut 197 Potato (5-6 mil lbs organic solids) .35 grass, alfalfa, cut 268 Poultry 640 1- sandy over clay, drain pipes 248 Specialities 620 1/4-1/2 grass, cut, all yr. 249 Tomato 410 3.0 637 160 .7 637 (920, 000 lbs COD/season) 24 grass, 2-month yr. 89, 248 Tomato, fruit 1100 42 4.6 grass, honeysuckle 384 Vegetables 40 . 38 637 7-8 4-6 grass, pasture 199,442 ------- The ridge and furrow system was originally conceived as a system in which the waste overflowed furrows atop ridges on sloped land. Unabsorbed waste was collected in a furrow and directed for further disposal. Ridge and furrow irrigation now consists of confining the wastes to furrows several inches below the ridges. Vegetation may be grown on top of the ridges (99, 100, 578). A number of installations were made in the 1940-1960 period with some success. Generally, this system has been replaced by the spray system. OTHER TREATMENT SYSTEMS - Waste waters frequently contain, besides organic load, considerable amounts of polar material. Even when processed so as to reduce the organic load, the salinity may be too great to permit reuse. Ion exchange treatment may be used to desalinate the waste water and to improve it for reuse. The ion exchange process has been applied to pineapple press juice and to olive and pickle brines for reducing salt ion concentration (11, 39, 290, 641). The solids in fruit and vegetable process effluents may be separated by one or more treatments during the various steps of processing or from the final waste effluent. Methods for in-process separation of discrete and suspended solids have been cited previously. Separa- tion of the sedimentary or settleable solids called sludge, or acti- vated sludge, resulting from secondary or tertiary treatment of the wastes may be achieved by similar treatments, including sedimen- tation, chemical coagulation and precipitation, chemical oxidation, incineration, and land disposal (116, 208). The selection of a treat- ment for the wastes from various operations necessarily will be influenced by the type of wastes, their degree of degradation, and economics. Incineration is applied to the disposal of various industrial solid wastes. Solid wastes may undergo size reductions from which by- products may be extracted, and which may be disposed of by biolo- gical degradation or incineration. Solid wet wastes of various types can be incinerated by designed systems; in some cases the combus- tion is sustained by the wastes when the organic compounds have adequate heating values. Liquid wastes can be concentrated prior to incineration treatment. Thermal treatments generally operate at temperatures up to 2000°F; applications of temperatures to 4500°F for chemical processes indicate potentials in engineered sys - tems. - 65 - ------- Carbon adsorption is a process by which wastes are chemically clarified by granular carbon. The waste is pretreated with polymer and brought into contact with carbon, which is regenerated and recycled. Olive brines were successfully conditioned for reuse as storage brines, producing olives of good quality (425, 428, 472). Estimated costs of $36. 40 per 1000 gallons of brine might be reduced to about one-third by a centralized operation. Reverse osmosis is a process by which water is forced by pressure through a molecular selective membrane. The process is also des- cribed as molecular filtration. Separation of salts, acids, and other components is feasible. Variables in the process involve pres - sures, types of membranes, and their dimensions. Reverse osmo- sis has many potentials for separation of components of food process waste (sugar, acids, salts) and for reconditioning water for reuse in food processing operations (425). The rapid oxidation of organic substances can be achieved at a suitable catalytic electrode. A proposed system (387a) has porous electrodes with air and the liquid waste in alternate channels. Except for some of the solids separation procedures mentioned inci- dentally, none of the “other treatment” systems summarized here has had significant commercial use for treating wastes. Their appli- cation to wastes in the future depends on further development and on comparison of their costs to those of other treatment methods. - 66 - ------- SECTION VII COSTS OF LIQUID WASTE TREATMENT AND DISPOSAL INDUSTRY WASTE COSTS Preliminary data from reference 471, supplemented by references 102, 105, 460, 522, 644, and 645, are the bases of the estimated expenditures in Table 21 for an assumed average fruit and vegetable processing plant. Table 21. Estimated Liquid Waste Costs Item Item costs, $ Proportion Per plant cost, $ capital 0 & M of plants capital cap./vr 0 & M In-plant 42, 000 2, 000 all 42, 000 4, 200 2, 000 Primary treatment 7,000 5,000 1/4 500 50 350 Secondary treatment 20,000 12,000 1/6 3, 600 360 2, 200 Irrigation 17,000 4,500 1/5 3, 600 360 900 City treatment -- 15,000 1/2 -- -- 7, 500 Total $5,000 $13,000 The characteristics of an ‘!averagec! plant were estimated from data on apple, peach, pear, snap bean, corn, pea, and tomato processing. The following plant size and waste averages were assumed: 15, 000 tons of raw product in a 100-day season; 3,000 gal. /ton, or about 450,000 gpd, or 45 million gal. /year; 30 lbs BOD/ton of product, approximating 1000 ppm BOD; 10 lbs SS/ton of product, approxi- mating 400 ppm. Component costs from the cited references were estimated for a plant with these average’ characteristics; they were converted to 1970 dollars using reference 645 data. Some estimates were averages of figures that varied over a wide range. Capital costs per year were estimated as one-tenth of capital costs. f ln_plantit costs included expenses for waste flumes, piping, pumps, tanks, sumps, gutters, and screens. Primary and secondary treat- ment systems were not well or consistently defined in the references. - 67 - ------- Using unit costs per year as estimated above and the assumed BOD removals given in Table 22, overall costs for different treatment efficiencies were estimated for an “average’ plant; the in-plant costs were added to each of the other systems’ costs; see Table 22. Table 22. BOD Removals and Costs (1) BOD, % removed Treatment Cost per year In-plant Primary Secondary Irrigation City treatment 5 50 80 100 75 $ 6, 12, 20, 12, 21, 000 000 000 000 000 * Including in-plant costs SS would be removed in higher percentages than BOD by the simpler systems, which include settling. Irrigation costs could be much higher than shown in Table 22, depending on the availability of suitable land. Estimates derived from figures in reference 123 for a 0. 5 mgd plant were approximately (converted to 1970 costs and rounded) as in Table 23. Table 23. BOD Removals and Costs (2) BOD, % removed Cost per year capital Item O&M In-plant 0-10 $1,200 5,000 Sedimentation 10 4,200* 7,500* Aerobic pond 50 4, 700 * 9, 000 Aerated lagoon 80 8,700* 11,000* Irrigation 100 4,000* 12,000* Including in-plant costs - 68 - ------- In-plant costs included those for screening and for handling solid wastes; these in-plant costs were estimated to be required in all plants and have been added to the costs of the other systems. SPECIFIC SYSTEMS COSTS Estimated costs of specific waste treatment systems are presented in the following discussion. SCREENING - Boyle and Polkowski (104) estimated the following screening costs per case: Product capital 0 & M total peas and corn $. 0014 $. 0012 $. 0026 beets and carrots . 0022 . 0092 . 0114 Screening costs for a plant canning about 15, 000 cases of peaches and 57, 000 cases of tomatoes per day and discharging about 300, 000 gal. /hr were detailed as (123): capital $47, 000, at 10 year life and 6%, per year $ 6, 375 maintenance and repair 2, 170 attendant 3, 800 cleaning 700 power 1,250 annual total $14, 295 Hauling the 10, 140 yards of resulting solid waste cost an additional $12, 168. The cost per equivalent case of peach and tomato products combined was $. 0029 ($. 0054 including hauling). The same reference estimated the costs for a 300 days per year operation with a 40-mesh vibrating screen, conveyors, and hoppers to vary from (figures rounded) $9, 500 plus $3, 750 for a plant with 0.5 million gallons/day flow to $65, 500 plus $32, 900 for an 8 MGD plant (capital costs and operation and maintenance costs per year, respectively). - 69 - ------- SEDIMENTATION - Estimated costs of sedimentation of cannery effluents in 1965 for 1 and 3 hours detention, corresponding to about 9 and 14% BOD removal, are in Table 24 (123). Table 24. Costs of Sedimentation of Cannery Effluents Waste flow Acres Capital cost Annual 0 & M MGD required $1000 $1000 . 1. 2. 4. 8. 5 0 0 0 0 . . . . . 06-. 10-. 14-. 18-. 28-. 12 16 24 36 58 18-33 26-61 44-110 82-210 150-390 1. 3. 6. 12. 21. 9 4 3 0 0 Figures rounded LAGOONS - Lagooning costs for removing 80-90% of the BOD from screened effluents were estimated to be $. 0014 per case for pea and corn canning and $. 0022 per case for beet and carrot canning (105). The costs for various types of ponds for cannery effluents have been estimated assuming a 300 day operating year (123). Figures estimated for a plant discharging 8 million gallons per day are in Table 25. Table 25. Costs of Lagoon Treatment Annual Lagoon Depth BOD, % Capital 0 & M type feet Acres Removed $1000 $1000 aerobic 3 37-330 68-96 14-980 45 facultative 6 12-110 60-90 120-720 59 anaerobic 12 10-71 50-80 170-1100 56 evaporation, 6 -- all 2000 29 percolation * Figures rounded - 70 - ------- AERATED LAGOONS - Aeration equipment to remove 90-95% of the BOD from the effluent was estimated to cost $. 0227 per case of peas and corn or $. 092 per case of beets and carrots; costs of the lagoon, piping, etc. would be additional (105). Approximate costs were given by Esvelt (222) for removing about 80% of the BOD from flows of about 0.6 to 1. 4 million gallons per day from peach, pear and apple processing. Capital was estimated at $205, 000 and calculated at 7% interest and 20 years life. Item capital p er nutrients operationmaintenance other Annual cost,$ 19,400 7,000 10,500 6,000 1,500 4,500 Total costs came to $. 041 per pound of BOD removed. Aerated lagoon costs for a range of waste flows and BOD removals were estimated assuming a 300 day operating year (123). For 8 million gallons per day, capital costs were $61, 000 and $648, 000 plus .79 and 19.9 acres of land for 10 and 90% BOD removals, res- pectively; corresponding operation and maintenance costs were about $34, 000 and $68, 000 per year. Capital costs for a 1 mgd flow were estimated to be about one-fifth of these. Robe et al. (545) calculated a cost of $. 21 per 100 lbs oxygen added by surface aerators, compared to $4 to 5 for the same amount from sodium nitrate. Costs of an aeration system given by Lane (359) for treating 86. 2 million gallons of peach waste in 658 operating hours were $1, 128 for materials, $914 for electricity, and $295 for labor. For treating 38. 8 million gallons of pumpkin waste in 1028 operating hours the costs were, respectively, $1,673, $1,346, and $1,009; capital costs were additional. ACTIVATED SLUDGE - Costs were given for an activated sludge system handling 2.5 million gallons/day of mixed food processing and domestic wastes with a BOD of roughly 100 mg/i which worked well without primary clarification: construction, $506, 300; opera- tion and maintenance, $20/million gallons (254). These costs were much lower than for a conventional plant. - 71 - ------- Esvelt and Hart (222 and 223) described a treatment plant for fruit wastes with detailed costs; capital costs were given as (a) $470, 000 without and (b) $557, 000 with sludge re-aeration and were estimated at 7% interest and 20 year life. Item (a) (b) power nutrients operation maintenance other Annual cost, $1000 44.452.6 10. 0 10. 5 12. 5 2. 0 7. 5 At 95% BOD removal total costs would be (a) $. 061 and (b) $. 067/ pound of BOD removed. Activated sludge plant costs for a range of flow rates and purifica- tion efficiencies have been estimated (123). The 8 mgd plant esti- mates are in Table 26. Table 26. Costs of Activated Sludge Treatment BOD, % Acres Capital cost Annual 0 & M removal required $1000 $1000 60 2. 5 540 58 73 1. 9 450 58 90 3. 9 550 58 95 8. 8 700 58 Figures rounded TRICKLING FILTERS - The costs for trickling filter treatment of wastes with 300 ppm BOD were estimated over a range of conditions (123). Estimates for 0. 5 and 8 million gallons per day waste flows, respectively, including a two-hour detention in secondary clarifiers, are in Table 27. - 72 - ------- Table 27. Costs of Trickling Filter Treatment Assumed BOD Hydraulic Acres Capital 0 & M removal,% loading required $1000 $1000 34 2 . 09-. 63 78-360 3. 9-19 58 4 . 14 1. 6 120-640 3. 9-19 69 10 . 27 3. 8 94-1100 4. 0-29 76 30 . 51-7. 5 164-2000 4. 0-29 Figures rounded. Million gal. /acre/day. CITY TREATMENT - The costs of city collection and treatment of waste flows from a peach and tomato cannery in 1964 and 1965 were given as $. 0477 and $. 0406 per standard No. 2-1/2 case of product (123). Roughly half of the costs were for collection. Charges for a number of municipal treatment systems may be summarized as follows (470): Five cities charged from 15 to 75% of the plants water bill, with a median of 50%. Twelve cities charged from $0. 002 to $0. 15 per 100 to 120 cubic feet of waste volume, with a median of $0. 085. Some cities had added surcharges of $0. 0035 to $0. 005 per pound of BOD, generally for that BOD in excess of a given concentration (300 to 750 ppm). One city had an additional surcharge of $0. 0072 per pound of BOD based on the pre- vious years maximum demand, and some cities added surcharges for SS. SPRAY IRRIGATION - The capital cost of a 40 acre spray irrigation system to handle 360, 000 gallons of waste per day, or 60 inches in a 180-day season, was given as $12, 000 (1953 cost) by Bell (87). Operation required one full-time man; the alfalfa crop returned $5000 per year. Lane (359) reported a spray irrigation cost of $.01 per No. 2 case, and at another plant canning 40,000 cases of tomatoes, a capital cost of $2, 030, both about 1954. Nelson (480) reported $.006/case; reference 51, $.01 to .05/case, for spray irrigation in the early 1950’s. For a 120 acre system with grass and alfalfa to handle 100 inches of waste per year, Haas (268) reported capital costs of $30, 000 (plus - 73 - ------- land) and annual operation and maintenance costs of $40, 000. The total costs of spray irrigation systems about 15 to 20 years ago were reported as: $15, 000 for 84 wooded acres, 5-10 mgd, 8 months operation per year (399, 667); $15, 000 for 48 acres in hay, 75, 000 gal. /day; $5, 200 for 100 acres in pasture, 80, 000 gal. /day; and $5, 000 for 40 acres in pasture, 400, 000 gal. Iday. The latter three were for dairy wastes (574). Lawton et al. (361) reported costs for five other dairy plant spray irrigation systems, excluding land costs, as $400 to $2, 300; the systems used 0. 018 to 1. 15 acres, mostly in grass cover crops, and handled 380 to 5, 900 gallons of effluent per day. - 74 - ------- SECTION VIII RESEARCH NEEDS WASTE SOURCES The capability of reducing the pollution load in the effluent from fruit and vegetable processing depends largely on knowing the point of origin of the wastes, the causes for their occurrence, and their magnitude and characterization. With such information means to correct malfunction or unsatisfactory operation may be applied, or efforts made to develop alternative systems which minimize the loss of extracted solids or leachate. More importantly, efforts toward reduction in pollution load can be directed to those phases of operation where the generation of pollution load is relatively great. Complementary to identifying the important sources of pollution load is the application of monitoring systems by which these operations can be better defined. Relatively few studies have been made on the magnitude and charac- terization of the wastes generated during specific processing steps; these include studies on apples, citrus, peaches, pears, beets, carrots, corn, peas, snap beans, and tomatoes. Additional infor - mation is needed on these crops and others. Examples of the poten- tial benefits of such studies have been the development of fruit peelers which are more efficient in the separation of peel and skin with less loss of solubles (apple, pear, tomato, beet, carrot, and potato); characterization of the losses of suspended and soluble materials during water blanching; improved container fillers; and isolation of waste streams for conditioning and reuse. Efforts in the characterization of in-plant wastes should be greatly intensified so that other alternative processes may be developed. WATER CONSERVATION A major problem in the conservation of water in many food process operations is that it is considered the cheapest commodity available, and hence readily expendable in comparison with investment in sophisticated equipment and in labor. Efforts to encourage conser- vation of water have not been wholly successful except where it is critical in supply or where economies are apparent in its conser- vation. - 75 - ------- The conservation of water in processing fruits and vegetables is important for several reasons; the volume of water used and dis - charged is directly related to capital and treatments costs for the effluent; water is a vector and extractant for solubles and suspended solids from products and from wastes; it is a vector for heat, which is relatively costly; and finally, it is costly per Se, contrary to the popular evaluation that it is not. Little data are available on the costs of water used in the processing of fruits and vegetables including not only the power and capital costs in making it available from wells, but also the costs of its distribu- tion through the factory and of its treatment; little information is available on the leaching effects resulting in greater pollution loads from the excessive uses of water. Studies should be undertaken to establish norms in the use of water for processing various fruit and egetable products, to establish means of conservation where such will be effective in reducing pollution loads, and to develop better understanding by management of the costs of water. Among subjects in need of study are the following: 1. Develop quantitative data on the loss of soil with various root crops during mechanical harvesting to focus attention on the magnitude of the problem and the necessity for engineering improvements in harvest machinery. 2. Develop experimental data on new concepts for field site wash stations to remove and recover soil from root and other crops, and on the related transport costs and product quality. 3. Develop quantitative data on water usage and costs, including energy and capital costs in water procurement and in its conve- yance throughout the plant. 4. Develop energy balances in water usage, including water trans - port, to evaluate better the costs of water uses. 5. Develop data on the costs of waste effluent disposal in terms of actual (uncontrolled) water usage and conservative (controlled) water usage. - 76 - ------- 6. Develop experimental data on new concepts for cleaning raw products, including soak and hydraulic systems, cavitation, detergent wash, air stream separation, mechanical abrasion, and osmotically balanced washing. 7. Develop improved and new procedures for treating water to per - mit greater multiple use for fruit and vegetable processing, and particularly to compare economic values in the use of fresh and treated water. Voluntary water conservation can best be implemented by establish- ing economic benefits. RECONDITIONING WATER FOR REUSE In addition to the conservation of water in processing fruits and vegetables, there is need for more reconditioning and reuse of water as a result of its decreasing availability and changes in its quality. A limited number of studies have been conducted, princi- pally on tomatoes, indicating the feasibility of water reuse. Clean and sterile retort water, for example, may be directed upstream; product rinse water may be directed upstream to product washing. A number of procedures are available for reconditioning water; ion exchange, reverse osmosis, filtration, sedimentation, floccu- lation, and centrifugation. These have been little used in fruit and vegetable processing primarily because water generally is readily available and because the total costs of water are not known. The potentials of reconditioning water have not been adequately determined. Studies are needed on the treatment of water from various in-process streams and on costs and efficiency. The hy- gienic acceptability of the conditioned waters must also be evaluated since this is an important criterion for foods. BLANCHING Blanching generates a significant pollution load and causes losses of nutrients and reductions in yield. The processes used for blanch- ing have not been adequately investigated to permit maximum correc- tion of the adverse effects. Determinative end points are not available to permit application of only the necessary degree of blanching (excessive blanching appears to be the rule), and possible - 77 - ------- alternative systems have not been adequately investigated. Among these may be cited the sequential timing of liquid and liquid/steam thermal processes; the use of osmotically balanced blanching media, hot air, infra red, and micro-wave; and sequences of these proce- dures. The relatively low volumes of effluents from water or steam blanch- ing have high concentrations of pollution load. These effluents can be separated from the total waste stream and treated by concentra- tion and drying or removal otherwise, thereby significantly reducing pollution loads. Studies are needed to reduce pollution from blanch- ing and to establish operational parameters in this process. PEELING AND SOLID WASTES Peel wastes are used to some extent; for example, in citrus, pine- apple, and apple processing. For many peel wastes, however, there appears to be no market and their disposa1 is an operational burden. At least two phases of research are needed to reduce the pollution loads involved in peeling fruits and vegetables: 1) develop- ment of alternative systems of solid waste separation to reduce concurrent losses in solubles and suspended solids and to increase product recovery; and 2) characterization and evaluation of the material for recovery of potentially useful materials. Traditional disposal of the separated wastes include use as feed for animal or fowl, and on land. The possible utilization of these wastes has not been given adequate consideration in the light of modern food pro— cessing operations. Conversion of the wastes into alternate physi- cal forms for use or disposal; extractants that may have market value as nutrients, chemicals, fertilizers, or other products; and consolidation of wastes from adjacent processing plants for econo- mies in conversion and marketing should all be studied. The recently developed dry caustic peeling of certain root crops appears to have benefits in minimizing the problem of liquid wastes and the concept should be extended; other procedures including comminution, concentration, and incineration should be evaluated to provide better disposal systems and reduce pollution loads in effluents. - 78 - ------- Because the soil and peel loads in certain crops are large, consi- deration should be given to in-field washing and peeling during har- vest; this would retain both soil and organic peel materials on the land. Although there appears to be objection to such concepts on hygienic grounds, these may be less serious than the problems in handling waste effluents. LIQUID WASTE TREATMENT There is a lack of information on the relative efficiency of simple screening and separation systems for the removal of colloidal and dispersed matter from effluents. The application of such procedures at various stages in the processing of fruits and vegetables is needed to reduce the pollution load in the plant effluent and permit reuse of the water. There are only limited published data on the use of screens, vacuum systems, centrifugal systems, and sedimentary systems for the treatment of selected effluent streams. There is considerable engineering information on the disposal of effluent wastes upon soil. Soil type, pollution load, application rate, soil cover, and other conditions vary widely; the results have de- pended upon the experience of the participants in the projects. There is a dearth of information on the potential effects of the applications on the character of the soil from chemical interactions. A compen- dium of information for land disposal systems is needed. There is a great need for information on establishing the optimum conditions for the biological degradation of the various types of effluents in lagoons to achieve maximum effect in the shortest time. The information should include flora, temperature, concentration, pH, nutrient supplement, and oxygen tension necessary to achieve maximum degradation. This information is needed to achieve effi- ciency in lagoon utilization and to minimize the hazard which may occur when the lagoons operate improperly. Lagoons are exten- sively used and are important tools in the treatment of wastes; the procedure is replete with problems in the light of increasing social and legal pressures. The relationship of the composition of the effluent to its biodegra- dability is not clearly established; for example, the rates of degra- dation of effluents bearing different types of organic solids, such as vegetable starches and fruit acids. - 79 - ------- The data should be implemented by information to attain complete and rapid biodegradation of the wastes to the point of permitting economic treatment and recycling/reuse of the water. New engineering con- cepts may be feasible in the use of waste energy from stack gases of thermal processes applied to specific wastes or to biodegrading sys - tern S. The processing of effluents by such systems as yeasts and fungi Imperfecti and by trickling filters should be further examined to determine potentials in sequential treatment. This information is needed for the different types of wastes derived in processing fruits and vegetables to assist engineers in designing treatment systems. WASTE POLLUTION EVALUATION The concentration of pollution loads in process wastes is measured by other than simple tests, such as chemical oxygen demand (COD), or biochemical oxygen demand (BOD). These are not simple in the sense that for reliability in the values obtained trained personnel must supervise their application. The COD test is the more quickly performed (several hours) and the BOD 5 test requires 5 days, each after procedures have been standardized. These tests are used as the basis of acceptability of effluents disposed into natural waterways and in part to determine sewer charges. A number of laboratory tests and instruments have been devised for quantifying the properties of waters and wastes. These range from sophisticated instruments for analysis for various components in water or wastes to gross or proximate measurement of floc or precipitate. Many procedures have been applied in technical studies to characterize wastes and their degradation. Instrument manufac- turers offer simplified forms of some tests to permit routine evalua- tion of some qualities of waters and wastes. For routine surveillance by fruit and vegetable processors of the pollution loads in various steps of processing, there is a great need for at least two sets of evaluation procedures. The first is the need for data on the characterization of pollution load equivalent wastes of specific product processes as measured or interpreted by regular employees. Among these may be cited values obtained through - 80 - ------- laboratory instruments such as turbidimeters, refractometers, centrifuges, conductivity meters, oxygen concentration meters, pH meters, etc. Establishing values from such instrument readings is highly desirable and presumably would be effective for supervision of pollution control. The second is the need for simplified quick and dirty” procedures for measuring with reasonable reliability directly or indirectly COD equivalents of waste effluent streams in various stages of processing. These should permit managers to monitor waste streams and treatments better than at present and should lead to better control of pollution problems. - 81 - ------- SECTION IX ACKNOWLEDGEMENTS This project was carried out with the partial sponsorship of a grant No. 12060 EDK from the U.S. Environmental Protection Agency, Industrial Pollution Control Program, under the direction of William J. Lacy and Mr. H. George Keeler, program manager. For the National Canners Association Research Foundation, the Project Director was Walter A. Nercer and the Principal Investigator was Walter W. Rose; Norman A. Olson made additional contributions. For the University of Wisconsin, Dr. Kenneth G. Wec1 el, under sub- contract from the National Canners Association, trovided a first draft of the report and most of the references. The Project Officer for the EPA, Kenneth A. Dostal, reviewed the report and was responsible for important additions as well as continuing guidance. The help of these persons and of others who furnished important but less extensive information is gratefully acknowledged. — 83 — ------- SECTION X REFERENC ES 1. Aceto, N. C., Edwards, P. W., Eskew, R. K., Redfield, C. S., Hurley, R.F., and Hoersch, A., Jr.,1950. Production of Leaf Meals from Vegetable Wastes in Rotary Alfalfa Driers. USDA Eastern Reg. Lab., AIC-266, Philadelphia, Penn. 2. Adam, W. B., Homer, G., and Stanworth, 3., 1942. Changes Oc- curring During the Blanching of Vegetables. Ind. Eng. Chem. 28, 595. 3. Adams, H. W., Hickey, F. D., and Willard, M. J., Jr., 1969. Lye- Pressure Steam Peeling of Potatoes and Other Products. Food Technol. 14, 1. 4. Adams, S. L., 1950, Tftiization of Cannery Fruit Waste by Con- tinuous Fermentation. Washington State Institute of Technology, Bull. No. 207. 5. Adrian, P.A., Fridley, R.B., and Claypool, L.L., 1968. Adapt- ing Shake-Catch Method of Harvesting to Cling Peaches, Paper No. 67-141, Transactions of the ASAE II, 159. 6. Agardy, F. 3., and Spicher, R. G., 1967. Anaerobic Treatment of Cannery Wastes - A Bench Scale Study. San Jose State Col- lege, San Jose, Calif. 7. Agardy, F.J., Spicher, R.G., andOrlob, G.T., 1967. Cannery Waste Treatment Part II. Treatability. 22nd md. Waste ConI., Purdue Univ., Lafayette, md. 8. Agen, J. R., Willis, R. L. and Robe, K., 1965. Peas by Bump Truck Big Savings. Food Processing 26. 9. Ahrens, G.G., 1969. Morrell Pioneers More Efficient Aeration. Food Eng. 41 (Aug.), 84. 10. Almanac of the Canning, Freezing, Preserving Industries, 1969. Edward Judge Publishing Co., Westminister, Md. 11. American Chemical Society, 1969. ?tCleaning Our Environment - The Chemical Basis for Action ’ t , p. 95. A Report by the Sub- committee on Environmental Improvement, Committee on Chem- istry and Public Affairs, Washington, D. C. - 85 - ------- 12. Ammerman, G.R., and Desrosier, N.W., 1958. Aeration Curbs Waste-DisposalOdors. Food Eng. 30 (Jan.), 115. 13. Anderson, D.R., Bishop, W.D., and Ludwig, H., 1966. Per- colation of Citrus Wastes Through Soil. 21st md. Waste Conf., Purdue Univ., Lafayette, md. 14. Angell, F. F., 1968. Tractor-Mounted Tomato Harvester. Maryland Processor’s Report 14 (2), 1., Univ. of Maryland, College Park, Md. 15. Anon. 1937. How to Treat Wastes. Food md. (Aug.), 430. 16. Anon. 1940. Treatment Methods for Waste From Citrus Juice Canning Plants. Public Works 71(8), 7. 17. Anon. 1944. Asparagus Waste Fed to Microbes. Food md. 16, 713. 18. Anon. 1944. Asparagus Waste By-Product. Food Packer 25, 63. 19. Anon. 1944. Corn Cannery Waste Effectively Disposed. Food Packer 25 (Feb.), 28. 20. Anon. 1944. Food Plant Wastes Used to Clean Metal. Food md. 16 (Jan.), 91. 21. Anon. 1944. Lab. Extracts Feed Yeast from Citrus Waste. Food [ nd. 16 (May), 644. 22. Anon. 1945. Use of Sodium Nitrate in Treating Cannery Wastes. Public Works 76 (Dec.), 48. 23. Anon. 1945. Vegetable Wastes by Dry Process. The Food Packer 26 (July), 32. 24. Anon. 1946. Citrus Processing Waste Used to Produce By- Product Feed Yeast. U. S. Dept. Ag. Report of Chief of Bureau of Ag. and hid. Chem., Ag. Res. Adm. p. 35. 25. Anon. 1947. Citrus Waste Disposal Gets Test in Florida. Food hid. 19 (Nov.), 130. 26. Anon. 1948. Study Citrus Waste as Fuel Gas Source. Food hid. 20 (Mar.), 138. - 86 - ------- 27. Anon. 1949. Cannery Wastes Fermented by Continuous Process. Food md. 21 (Sept.), 1278. 28. Anon. 1952. Making Pear Waste Salable. Food Eng. 24 (Feb.), 136. 29. Anon. 1952. Plastic Pipe System Solves Cannery Water Dis- posal and Irrigation Problems. The Canner 115(23) , 22. 30. Anon. 1952. Tomato Waste Converted to Animal Feed. Canner 114 (June). 31. Anon. 1953. Citric Acid From Lemons. Food Eng. 25, (July), 162. 32. Anon. 1956-1963. Derived from Annual Reports, City of Stockton, Calif., Treatment Plant. 33. Anon. 1954. Vibrating Screen Solves Pollution Problem. Canner 118 (24), 23. 34. Anon. 1963. Spray Irrigation Disposal. Compost Sci. (Spring), 38. 35. Anon. 1963. Ion-Exchange Removal of Sodium Nitrate Chloride from Water With Calcium Hydroxide as Recoverable Regenerant. Science 141 , 1038. 36. Anon. 1963. Just How Effective are Lagoons. Compost Science 4 (Autumn), 25. 37. Anon. 1963. Ridge and Furrow Disposal Fields. Compost Science 4 (Spring), 39. 38. Anon. 1966. Harvesting, Hauling Costs. Amer. Fruit Grower 86 (Mar.), 29. 39. Anon. 1966. Water Re-Use, C&E Special Report. Chemical and Eng. News 44(12) . 91. 40. Anon. 1967. Destroys Fluidized Waste Without Pollution. Food Eng. 69 (May), 204. 41. Anon. 1967. Vine Cleaning. Hydraulics and Pneumatics 20, 26. - 87 - ------- 42. Anon. 1968. Fluid Bed Incinerators Studied for Solid Waste Disposal. Environmental Science and Tech. 2 (7), 495. 43. Anon. 1968. Improve Quality of Frozen Vegetables. Food Processing 29 (Oct.), 80. 44. Anon. 1968. Incineration - A Practical and Scientific Approach. Environmental Science and Tech. 3(7), 524. 45. Anon. 1968. Offers Complete, Smokeless Burning of Waste. Food Eng. 70 (Mar.), 185. 46. Anon. 1968. Tomato In-Field Washing 3 tations. National Canners Association, Research Information No. 134, Berkeley, Calif., Jan. 47. Anon. 1968. Unpublished Data of a Canning Industry Committee. 48. Anon. 1968. Washington Laboratory Research on Water Re-Use. National Canners Association, Research Information No. 141, Washington, D.C., Aug. 49. Anon. 1969. Carbon Makes Debut in Secondary Treatment. Environmental Science and Technology 3(9), 809. 50. Anon. 1969. Clear Water From Wastes. Agricultural Research 18 (6), 10. 51. Anon. 1969. 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Wastes Engineering 34 (May), 242. - 140 - ------- SECTION XI GLOSSARY BOD (1) Abbreviation for biochemical oxygen demand. The quantity of oxygen used in the biochemical oxidation of organic matter by bacteria in a speci- fied time (usually 5 days), at a specified tempera- ture (20°C), and under specified conditions. (2) A standard test used in assessing wastewater strength. By-product A useful product made from material that would otherwise be waste. Cs Abbreviation for ‘ 1 case”, a quantity of finished product containing a number (often 24) of consumer- size units. COD Abbreviation for chemical oxygen demand. A mea- sure of the oxygen-consuming capacity of inorganic and organic matter present in water or was tewater. It is expressed as the amount of oxygen consumed from a chemical oxidant in a specified test. It does not differentiate between stable and unstable organic matter and thus does not necessarily correlate with BOD. Also known as OC and DOC, oxygen consumed and dichromate oxygen consumed, respectively. O and M Abbreviation for ‘operation and maintenance’s; the annual costs of a facility excluding capital costs. pH The negative logarithm of the hydrogen ion content; a measure of the functional acidity or alkalinity of a liquid. Raw product The quantity of a commodity delivered to a food processor; also referred to as “raw tons”. Residual Material left over from processing a primary pro- duct; e used as a by-product or wasted. Settleable solids Insoluble rr rial measured by settling. — 1 I — ------- SS Abbreviation for suspended solids. Solids that either float on the surface of, or are in suspension in, water, wastewater, or other liquids, and which are largely removable by laboratory filtering. TDS Abbreviation for total dissolved solids. The total amount of soluble material, organic and inorganic, contained in water or wastewater. TS Abbreviation for total solids. The solids in waste- water, both suspended and dissolved. - 142 - ------- SECTION XII APPENDIX - 143 - ------- Table Al. Total Wastes from Canned and Frozen Fruits and Vegetables VEGETABLES Raw Product Wastewater BOD5 Suspended Solids Solids Residuals 1000 lO 3 gal mil. lbs mil. lbs mu. lbs 1000 tons /ton gal. * / ton lbs /ton lbs /ton tons FRUIT Apple 1,050 2.1 2,200 36 38 6 6 580 290 Apricot 120 8.7 1,000 71 9 16 2 240 16 Cherry 190 2. 4 400 26 5 5 1 280 26 Citrus 7,800 1.8 19,000 16 125 3 23 790 3,080 Peach 1, 100 5.6 6,200 62 68 13 14 530 290 Pear 410 3.0 1,200 42 17 12 5 660 140 Pineapple 900 0.5 500 20 18 8 7 890 400 Other fruit 460 8.0 3,700 20 9 10 5 -- 70 Fruit sub-total 12,030 34,200 289 63 4,312 Asparagus 120 13.3 1,300 7 1 8 1 700 42 Bean, lirna 120 9.0 1, 100 25 3 80 10 320 19 Bean, snap 630 7.6 4,800 22 14 15 9 420 130 Beet 270 3.8 1,000 135 36 53 14 670 90 Carrot 280 3.7 1,000 50 14 29 8 1,000 140 Corn 2,480 2.2 5,500 44 110 22 55 1,310 1,620 Pea 580 5.3 3,100 61 35 22 13 260 74 Pumpk,squash 220 1.5 300 41 9 11 2 500 55 Sauerkraut 230 0. 4 100 14 3 1 0 660 76 ------- Table Al. Total Wastes from Canned and Frozen Fruits and \Icgetables (continued) U i * Units are 1000 galiDns or pounds per ton of raw product Estimated total annual waste generation for the United States Raw Solids Residuals Product Wastewater BOD5 /ton* ga1. /ton lbs /ton lbs /ton* tons tons Spin.,greenS 240 8.4 2,000 28 7 18 4 280 33 98 15 39 6 (in other veg.) Sweet potato 150 2.6 14 70 7 35 180 400 Tomato 5,000 2.7 14, 110 53 130 760 910 White potato 2,400 3.4 8,200 60 84 30 42 -- 460 Other vegetables 1, 400 4 ..0 5,600 Vegetable 511 329 4,049 sub-total 14, 120 48,900 83, 100800 392 8, 361 Total 26, 150 ------- Table AZ. Mechanical Harvesting of Fruits and Vegetables Product Problem Ref. Apples Bruising 390 Apples Boom-shaker, conveyor 585 collection Apples Shaker - deceleration strip 392 damage Apples Shake-catch - effect on bruising 395,396 - economics Asparagus Snapping units - types - 345 comparisons Asparagus Selective - sensor - 447 compressed air - problems Asparagus Rotating knives - sort - 337 trim - uniform cut Celery Types - damage comparison 83, 84 requirements Cherries Catch frame -pruning - 391 stems - damage - efficiency Cherries Mechanization effect 687 Citrus Tree-shaker - tractor - 159 catch frame -performance Citrus Oscillating air blast - 328 fruit maturity - leaf damage Citrus Inertia-shaker - stem and 368 fruit removal Citrus Mass-harvest - injury 576 individual harvest - selection Fruit,tree Blueberry - plum -cherry 244 cost reduction Fruit,tree Harvester types - savings 331 problems Oranges Mechanical harvest - leaf and 402 twig loss - yield effect Peach Shake-catch - modify tree 381 production costs Cling peaches Shake-catch - selectivity - 5 percent bruise - yield - 146 - ------- Table AZ. Mechanical Harvesting of Fruits and Vegetables (continued) Product Problem Ref. Peas Harvester development - 538 design - damage - adaptation to crops Peas Methods - comparison - 688 costs - vining station Strawberries Mechanical stripping - 295 selective Tomatoes Once-over harvest - 610 yield - bruises Tomatoes Compare damage of hand 544 and mechanical Tomatoes Effect of field layout - 534 yields - damage Tomatoes Damage - dirt 506 Tomatoes Mechanical harvest - 701 microbial contamination - fruit condition Tomatoes Selective - color - 605 separation - shaking Tomatoes Damage - hand and mechanical 462 harvest - containers Tomatoes Effects on BOD quantities 665 Tomatoes Harvest whole plant - 335 sort belt Tomatoes Tractor -mount - pickup - 14 conveyor - fruit condition Tomatoes Bed shape - uniform stand 389 optimum conditions Tomatoes Large operator - speed - 53 clean fruit - less damage - color sort tree fruit Pneumatic - force required 526 physical character Tree crops Economics - fruit loss - harvest 238 rate - degree mechanization Vegetable Economic feasibility - once- 609 over harvest - multiple harvest - break-even yields - 147 - ------- Table A3. In-field Processing of Fruits and Vegetables Product Process system Ref. Citrus Trash eliminator - conveying 393 Peas Vining - conveying - on-stream 357 Peas Field and plant vining - costs 167 Peas Plot cleaner - trash removal 336 Sugar Cane Trash removal 153 Tomatoes Mechanical harvester - culls 109 in-field - grader Tomatoes Field grade - washing - 701 sanitation Tomatoes Vine cleaning - field disposal 41 Tomatoes Washing - spraying - sorting 424 damage - spore counts Tomatoes Harvester - color grading - 53 cull removal Tomatoes Acidified break - juice 59 extraction Tomatoes Acidified field break - 63, 580a efficiency Tomatoes Washing - damage - spores 468, 469 - 148 - ------- Table A4. Hauling of Fruits and Vegetables from Field to Plant Cherries Cherries Cherries Citrus Citrus Fruit Fruit Fruit Peas Tomatoes Tomatoes Tomatoes Tomatoes 243 55 38 393 563 485 93 8 157 624 544 486 Product Cherries Ref. 371 242 Water transport - comparison to lug Water transport - cost - simplifies - retains quality Water transport - weighing - weight change Pallet tanks - water - shrinkage Haul and loading costs Pick-up - conveyors - bins - trucks Efficiency - labor - equipment - comparisons Transport truck - vibrations - bruising Positive transfer - padded belts Dump truck Water handling Water - condition after haul Compare types of boxes Bulk - bin - water - storage effect - 149 - ------- Table A5. Transfer of Fruits and Vegetables during Processing Product Conveyance system Ref. Apricot Water - labor reduction - 380 system description Peas Fluming in reused water 423 Tomatoes Hydraulic conveying - bacteria count 422 Vegetable Pneumatics - frozen product - 143 (frozen) cost efficiency Vegetable Pneumatics - clumping 144 (frozen) prevention Vegetable Fluidized freezing - 43 (frozen) conveyor - less bacteria Vegetable Pneumatics 166 (fresh & frozen) Vegetable Pneumatics - 374 (fresh & frozen) negative air air conveyor - 150 - ------- Table A6. Reuse of Water in Fruit and Vegetable Processing Process Ref. Recirculation Reuse for drain flush 326 Conservation Cut usage in process 537 4 stage counter- In pea canneries 433 flow Recirculation Cool water for washing, 213 fluming, reuse screened flume water Recirculation 431 Conservation Tomato washing studies 433 Conservation Reduction in peeling, 503 washing, cleaning Recirculation Hydraulic system, bacteria 422 count Reuse Reuse refrigeration and un- 306 contaminated process water Reuse Can cooling and flume water 665 Recycling Process brine 515 Countercurrent Reuse in preceding wash 465 and flume Recycling Reuse for washing 155 Triple-loop water 363 economy circuit Reuse Lye rinse and process water 426 as makeup Counterfiow In tomato, sweet potato 300 processing Recirculated Reuse volume per year 471 - 151 - ------- Table A7. Treatment of Water for Reuse in Processing Operations Treatment Parameter studied Ref. Activated carbon Organic removal 290 adsorption Activated carbon Organic removal 332 adsorption Activated carbon Organic removal 641 adsorption Activated carbon Dissolved organics removal 11 Activated carbon Reconditioning brine 425 Activated carbon 290 adsorption Air stripping Ammonia removal 641 Biological Nutrient removal 641 denitrification Brine disposal 11 Chemical oxidation Refractory organic 290 materials removed Chemical oxidation 39 Chemical oxidation Dissolved inorganics 11 Chlorination 433 Chlorination 39 Coagulation- Suspended solids removal 11 sedimentation Coagulation- Suspended solids and dissolved 155 sedimentation solids removal Disinfection 11 Distillation Inorganic and organic removal 290 Distillation Inorganic removal 641 Electrodialysis 290 Electrodialjsis Demineralize secondary 112 effluent Electrodialysis Inorganic removal 641 Electrodialysis Dis solved inorganics removal 11 Freezing 290 Freezing Inorganic removal 641 Ion exchange 290 Ion exchange 39 - 152 - ------- Table A7. Treatment of Water for Reuse in Processing Operations (continued) Treatment Parameter studied Ref. Ion exchange 641 Ion exchange Dissolved inorganics removal 11 Ozone sterilization 363 Ozone treatment 302 Ozone treatment Reduction of COD 641 Precipitation Nutrient removal 641 Reverse osmosis 290 Reverse osmosis Inorganic removal 583 Reverse osmosis Dissolved inorganic removal 11 Reverse osmosis 426 Reverse osmosis 108 - 153 - ------- Table A8. Waste Generation (Percentages) from Unit Processing Operations on Fruits and Vegetables Fill,ht, Exhaust, Clean Peel Cut,pit Pulp syrup seal,cook Apple (4)** water 20_30*** 5-20 10-25 10 40-65 B/COD 5-20 10-40 5-40 70 10-80 SS 2-15 15-40 3-35 85 10-80 Apricot (3) water 20-95 - 5-40 - 15-15 25-40 B/COD 20-20 - 40-55 - 15-30 10-10 SS 30 40 - 20 10 Cherry (3) water 30-60 3-6 35-65 B/COD 10 80 10 SS 35 - 60 5 Peach (3) water 15-20 25-50 15-35 - 10 10-20 B/COD 5-10 35-50 30-50 - 5-10 2-5 SS 5-10 30-60 25-55 - 5 2-5 Pear (3) water 30-60 7-30 - 10-13 30-40 B/COD 50-78 10-40 - 5-10 2-5 SS 45-83 10-45 - 5-5 2-5 Fill,brine, Fill, Clean Peel Cut Blanch seal,cook freeze Asparagus (2) water 20-40 - 10-20 25-30 15-40 5 B/COD 20 - 10 60 10 5 SS 50 - 10 30 10 5 Beans, snap (4) water 30-40 - 0-40 10-45 20-50 5-10 B/COD 10-60 - 0-20 40-60 0-20 5 SS 30-80 - 0-30 20-30 0-10 5 Feet (2) water 10-30 30-40 20-26 20-24 B/COD 15-20 50-60 20-20 5-10 SS 15-30 50-70 10-20 0-5 - 154 - ------- Table A8. Waste Generation (Percentages) from Unit Processing Operations on Fruits and Vegetables * (continued) Fill, brine, Fill, Clean Peel Cut Blanch seal,cook freeze Carrot (2) water 12-30 30-40 20-28 0-5 15-20 B/COD 16-20 50-60 20-21 0-10 0-3 SS 10-18 40-65 15-40 0-10 0-2 Corn, canned (2) water 30-40 40-41 - zo- 29 B/COD 20-30 50-75 - 5-20 SS 10-15 70-80 Corn, frozen (2) water 19-40 26-30 25-50 - 5-5 B/COD 10-18 30-68 13-55 - 1-5 SS 10-15 70-80 5-15 - 0-5 Pea (3) water 50-60 - 10-30 20-40 5-10 B/COD 45-55 40-45 5-10 5 SS 55-65 - 30-35 5-10 5 Potato, sweet (1) water 30 35 15 B/COD 25 50 20 5 SS 25 40 30 5 Pumpkin, squash (1) water 10 20 * 20 20 30 - B/COD 15 3Q z* z 35 10 10 SS 10 25*** 50 10 5 Spinach, greens (4) water 20-60 - 0-10 10-40 15-55 5-10 B/COD 15-30 - 10-30 30-60 10-20 5 SS 30-60 - 10-40 20-20 10-10 5 Tomato, whole (2) water 50-80 i O-40 - - 10-10 B/COD 60 35 - - S SS 70 30 - 0 - 155 - ------- Table A8. Waste Generation (Percentages) from Unit Processing Operations on Fruits and Vegetables (continued) Fill, brine, Fill, Clean Peel Cut Blanch seal,cook freeze Tomato, pulped (3) water 30-85 5_3Q o - - 10-60 B/COD 95 5o z - 0 SS 95 - - 5 “Clean’ includes washing, sorting, shaking, blowing, etc. ; “peel” and blanch’ include related steps such as rinsing; “cut” includes slicing and dicing. Number of estimates in Q. Where two or more estimates were available, the highest and lowest are shown. Pulping operation (not peeling). - 156 - ------- Table A9. The pH of Fruit and Vegetable Effluents pH Product Range Median Ref. Apple 4.1-8.2 5.3 600 Cherry 5.2-7.9 6.4 600 Grape 5.2-9.5 7.2 600 Olive storage 4.0-4.3 4.2 428 Peach (6. 2)*_lO.6 9.6 420,421,432, 458 Bean,lima 5.7-7.0 5.9 507 Bean,snap 5.2-8.6 6.5 507,600 Beet 5.6-11.9 8.0 309,600 Carrot 7.4-10.6 8.2 600 Corn (3.9)-8.0 6.4 181,507,600 Pea 4.9-9.2 6.6 181, 184, 507, 600 Pumpkin,squash (4.2)-7.2 6.6 420,458,507, 600 Sauerkraut 3.6-6.8 5.0 600 Sweet potato 5. 8-11.4 10.5 507 White potato (3.6) -12.6 8.4 160,267,351, 507, 543, 601 Tomato 4.5-11.3 6.6 123,327,507, 600 In ( ), possibly not typical - 157 - ------- Table A10. Peel Waste from Fruits and Vegetables Peel waste, Product % of raw weight Ref. Apples (peel and core) 35 569 Apples (mechanical peel) 15-18 216 Apples (infra red peel) 2 75 Grapefruit 58 569 Grapefruit (peel and rag) 83 80 Orange (peel and rag) 74 569 Peaches (lye peel) 9-26 691 Pears (peel and core) 42 569 Potatoes (abrasion) 3-12 258 Potatoes (lye) 12-30 400 Potatoes (mechanical peel) 7-31 694 Potatoes (abrasion peel) 25 262 Potatoes (lye peel) 22 262 Potatoes (steam peel) 18 262 Potatoes (lye/steam peel) 15 3 Potatoes (abrasion peel) 14-25 192 . Potatoes (steam peel) 11-19 192 Potatoes (lye peel) 11-23 192 Potatoes (lye peel) 18 681 Potatoes (infra red peel) 13 681 Potatoes (steam peel) 10 681 Potatoes (infra red peel) 10 681 Sweet potatoes (lye peel) 10-29 691 Tomatoes (hot air blast) - - 509 Tomatoes (total waste) 25 569 Tomatoes (total waste) 8 471 - 158 - ------- Subje t F Aice ion WATER R ESOUR S ABSTRACTS INPUT TRANSACTION FORM w I Organization National Canners Association 1950 Sixth Street Berkeley, California 94710 o Title Liquid Wastes from Canning and Freezing Fruits and Vegetables 10 Author(s) — Mercer, Walter A. Rose, Walter W, Weckel, Kenneth C. Project De igna(ion EPA, 12060 EDK 21 lVote 22 Citation I Berkeley, California; National Canners Association, August, 1971; 158 pages; 4 figures; 37 tables; 714 references, D scriptors (Starred First) cannerie s, wastewater treatment, water pollution sources, costs, wastewater disposal, water reuse 251 J1eotjfteri (Starred First) i:IFreezing (food processing) 27 Abstract This study estimates that the 1800 plants in the U.S. canned and frozen fruits and vegetables industry annually utilize 26 million tons of raw product, discharge 83 billion gallons of water, and generate 800 million pounds of biochemical oxygen demand, 392 million pounds of suspended solids, and 8 million tons of solid residuals. Increased mechanical harvesting is increasing problems in product damage, soil, and loss in yields. Water is extensively recirculated in food processing plants but addi- tional water savings by reconditioning and reuse are needed, High pollutional loads are generated in blanching and peeling operations and large amounts of relatively clean water are discharged from cooling and condensing operations. Solids are com- monly removed from waste water by screening. The solid residuals from some commodities are used in large quantities for animal feed. Biological processes are widely used to treat food processing waste water. Anaerobic, aerobic, and aerated lagoons, activated sludge, trickling filter, and other treatment systems are discussed. Roughly half of the canning and freezing plants discharge their waste waters to city treatment systems and about one-fifth use spray irrigation for liquid waste disposal. Abstractor lr i i itiJr ion Norman A. Olson National Canners Association 5 :2 FEE JELY 912’ SEND. ,‘.Ti, COPy QF DOCUMENT, TO WSTER RESOUFCES SCENT:F:C ‘NFORMA ON CENTER s c U.S. DEPARTMENT OF THE NTER!OR ASkINGTON. 0. C 00240 SUS. GOVERNMENT PRINTING OFFICE: 1972 084-483/90 1—3 ------- |