DEEP WELLS FOR INDUSTRIAL WASTE INJECTION IN THE UNITED STATES Summary of data U. S. DEPARTMENT OF THE INTERIOR Federal Wafer Pollution Control Adminisfrafion C/ncinnafi, Onio November 1967 WP- 20-10 ------- DEEP WELLS FOR INDUSTRIAL WASTE INJECTION IN THE UNITED STATKS Sunmary of Data Don L. Warner U. S. DEPARTMENT OF THE INTERIOR Federal Water Pollution Control Administration Cincinnati, Ohio November 1967 ------- In its assigned function as the Nation’s principal natural resource agency, the United States Department of the Interior bears a special obligation to ensure that our expendable resources are conserved, that renewable resources are managed to produce optimun yields, and that all resources contribute their full measure to the progress, prosperity, and security of America -- now and in the future. The WATER POLLtIFION CONTROL RESEAROI SERIES of reports was established to describe the results of research studies of water pollution. This SERIES provides a central source of information on the intramural research activities of the Federal Water Pollution Control Administration in the U. S. Department of the Interior and on the research program’s cooperative and contractual activities with Federal, State, and local agencies, research institutions, and industrial organizations. Reports in this Series will be distributed to requesters as supplies permit. Requests should be sent to the organizational unit identified on the title page or to the Publications Office, Ohio Basin Region, Federal Water Pollution Control Administration, Cincinnati, Ohio 45226. Water Pollution Control Research Series Publication No. WP-20-iO ------- OWFENTS Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Summary ...... •......................u................ 1 References •........ •s••I...,... •••••••.....••,.••,• 5 Injection Well I)ata . • • • . • . • . . . • •• . • . • . • . • . , • . . • • • . • , 8 i ------- I NTRODUCTION The use of deep wells for disposal of some concentrated, relatively untreatable liquid wastes has increased in recent years and it is expected that this method will be widely applied in the future as water pollution control is emphasized. It has come to our attention through our own research efforts and through contact with state agencies, industries, and individuals, that there is the lack of readily available current information regarding the location, design, and operating experience of existing industrial waste injection wells.. This publication lists 110 industrial waste injection wells and some of their characteristics. The data listed include: 1. Operator of well 2. Se11 location 3. 1)ate of initiation of operation 4. A. Total well depth B. Depth of injection horizon(s) C. Geologic formations used for injection - rock type - formation age 5. Chemical and physical character of waste 6. Injection rate 7. Injection pressure (well head) 8. Source(s) of information The information contained herein is believed to be generally accurate, but as indicated under sources of information, much of it was obtained indirectly and we have not yet, in most cases, attempted to verify it, Detailed data on aspects of design, construction, and operation can be obtained for a rn nnber of wells from the references that are cited. Such additional information can also be obtained through inquiries to the individual companies and the appropriate state and federal offices. SU!$IARY One hundred and ten industrial waste injection wells located in 16 states are described. Table 1 and Figure 1 summarize the con- tained information. The table shows that about 82 percent of the wells are used by chemical, petrochemical, and pharmaceutical product plants; refineries and natural gas plants; and metal product plants. ------- TABLE 1 STATISTICAL ANALYSIS OF INJECTION WELL DATA I)ISTRIBIJTION OF INJECTION WELLS BY INDUSTRY TYPE Type of Industry Percentage of Existing Wells Refineries and Natural Gas Plants 20% Chemical, petrochemical, and 55% pharmaceutical companies Metal products companies 7% Other 18% TOTAL DEPTh OF INJECTION WELLS Total Well I pth Percentage of Wells 0 - 1,000 feet 5% 1,001 - 2,000 feet 32% 2,001 - 4,000 feet 27% 4,001 - 6,000 feet 28 b,001 - 12,000 feet 6% over 12,000 feet 2% 1YPE OF ROCK USED FOR INJECTION Rock Type Percentage of Wells Sand 33% Sandstone 41% Limestone and dolomite 22% Other 4% 2 ------- TABLE 1 (CONTINUED) RATE OF INJECTION Injectiąn Rate Percentage of Wells 0- 5ogpm 23% 51- 100 gpm 11% 101 - 200 gpm 25% 201 - 400 gpm 19% 401 - 800 gpm 3% over 800 gpm 1% unknown 18% PRESSURE AT IVHIQ! WASTE IS INJECTED Injection Pressure Percentage of Wells Gravity flow 11% Gravity - 150 psi 19% 151 - 300 psi 15% 301 - 600 psi 6% 601 - 1,500 psi 13% over 1,500 psi 2% unknown 34% 3 ------- i2C 1 0 Wells commencing operation 100 — during 1967 and those drilled 0 but not yet in operation *; p oz / wo / -)— ZI- — / LJW 0 Q- a: / w mZ 60 w >_J I— .0 - 4 — JU) _j / ii — — — -. — _0 I I I 950 1955 1960 965 1970 (JANUARY I) 1967 YEAR (JANUARY I) Figure I. Number of injection wells placed in operation each year during the period January 1950 to January 1967. ------- Some of the remaining wells are operated by a paper mill, a uranium mill, an airlines maintenance facility, a nylon plant, a coking plant, an aerospace facility, and a photo processing facility. The wells range in total depth from a few hundred to over 12,000 feet, but 64 percent are less than 4,000 feet deep and 92 percent are less than 6,000 feet deep. Injection is into unlithified sands (33%), sandstones (41%), limestones and dolomites (22%) with the exception of five wells. The Rocky Mountain Arsenal well (Cl-i) is injecting into fractured Precambrian gneiss , one of the lianimermill Paper Company wells (P-3) is reportedly injecting into fractured or sheared Precambrian crystalline rocks as well as younger sandstone and carbonate reservoirs, and three wells (Ka-l, Mc-18, and Mc-19) are injecting into evaporite sequences. Available injection rate and pressure data are not considered particularly satisfactory, but they indicate the range within which existing wells are operating. Injection rates for a single well range from a few gallons per minute to over 900 gpm with 34 percent injecting less than 100 gpm and 78 percent injecting less than 400 gpin. Eleven percent of the wells are injecting by gravity flow and 51 percent are injecting at a well-head pressure of less than 600 psi. It is probable that most of the wells for which data are not available are injecting less than 400 gpm at a pressure of less than 600 psi. Figure 1 shows the number of injection wells placed in operation during each year from January 1950 to January 1967. More wells (46) were put into operation during the three-year period from January 1964 to January 1967, than during the previous 14-year period 1950-1963 (45 wells). This increase in rate of construction of injection wells can be attributed to increased emphasis on water pollution control and the more widespread accep- tance of this disposal method that has accompanied its successful use. The existing injection systems in the United States are heavily concentrated in the north-central and Gulf Coast areas. This distribution is a result of a combination of factors including favorable subsurface geology, heavy industrial concentration, and the attitude of the various states regarding the use of subsurface disposal systems. The cooperation of the various state agencies, industrial companies, and individuals who have supplied information contained herein is appreciatively acknowledged. 4 ------- RLFLRENCLS 1. Adinoff, J., 1955, 1)isposal of Organic Chemical Wastes to Underground Formations, in Ninth Indust. I%astc Conf. Proc., Purdue, 1954; Purdue Univ. Lxt. Ser No. 87, p. 32-38. 2. Arlin, Z. E., 1962, I’ cp-Wel1 Disposal of tJrani n Tailing Water, in, Proc. 2nd conf. on Ground 1)isposal of Radioactive Wastes,1halk River, Canada, Sept. 26-29, 1961: El. S. Atomic Lnergy Conmi. TIfl-7628, Book 2, p. 356-360. 3. Barraclough, J. ‘1., 1966, Waste Injection into a Deep Limestone in Northwestern florida: Ground Water, V. 4, No. 1, p. 22-25. 4. Batz, M. L., 1964, Deep Well Disposal of Nylon Waste Water: them. hng. Progress, V. 60, No. 10, p. 85-SM. 5. Brown, K. W., and Spalding, C. W., 1900, Deep-Well Disposal of Spent Hardwood Pulping Liquors: Water Pollution Control Federation Jour., V. 38, No. 12, p. 1910-1925. 6. Chemical Week, 1965, Learning to Whip Well Woes: Chemical Week, April 10, p. 113 and 115. 7. Civil Lnginecring, 1966, Production Waste Goes Underground at Ilolland-Suco: Civil Lnginecring, May, p. 92. 8. Dean, B. T., 1905, The Design and Operation of a Deep-Well Disposal System: Water Pollution Control }vcl. Jour., V. 37, No. 2, p. 245-254. 9. Denaldson, L. C., 1964, Subsurface Disposal of Industrial Wastes in tue United States: U. S. Bureau of Mines lnf. Circ. 8212, 34 p. 10. Lvans, I). M., 1966, Man-made 1.arthquakes in Denver: Geotimes, May-June, p. 11-18. 11. Graves, B. S., 1961, Underground Disposal of Sour Water, in 1 enty-fourth Ann. Short Course for Water and Sewerage Pi Iit Superintendents and Operators Proc.: Louisiana State Univ. Eng. Expt. Sta. Bull. No. 67, p. 74-80. 12. }lartman, C. D., 1966, Use of Deep Well Method For Waste Disposal at Midwest: Paper presented at Water Pollution Control Federal Meeting, Kansas City, Missouri, September 1966. 13. Ilenkel, II. 0., September 1953, Surface and Underground Disposa] of Chemical Wastes at Victoria, Texas: Sewage and Indus. Wastes, V. 25, No. 9, p. 1044-1049. 5 ------- 14. Henkel, H. 0., 1955, Deep-Well Disposal of chemical Wastes: them. Eng. Progress, V. 51, No. 12, p. 551-554. 15. Hough, L. W., 1963, Protection of Underground Fresh Water Sands in Louisiana: Paper presented to Research Committee of the Interstate Oil Compact Commission, June 1963, New Orleans, La. lb. Ilough, L. W., 1965, Salt Water and Waste Disposal Wells - State Regulations and Geological Problems: Louisiana Geological Survey, Baton Rouge, Louisiana, 10 p. 17. Ilundley, C. L., and Matulis, J. T., 1962, Deep Well Di3posal, in Seventeenth Indust. Waste Conf. Proc., Purdue, May 1961: Viirdue Univ. Engr. Ext. Ser. No. 112, p. 176-180. 18. llundley, C. L., and Matulis, J. 1., 1963, Deep Well 1)isposal: Ground Water, V. 1, No. 2, April, p. 15-17. 19. Jukkola, W. H. and Vajada, S., 1965, Deep Well Sulfuric Acid Waste I)isposal: Paper presented at Ohio Water Pollution Control Federation Conf., Akron, Ohio, June 17. 20. Luff, G. S., 1960, Underground Waste Disposal for American Airlines, Inc., in Proc. 11th Oklahoma Industrial Wastes Conf.: Oklahoma State tiiffv., Stiliwater, Oklahoma, p. 71-80. 21. Mechem, 0. E. , and Garrett, J. II., 1963, Deep Injection Disposal Well for Liquid Toxic Waste: Am. Soc. Civ. Engineers Proc. Jour. Construction Div., p. 111-121. 22. Moffett, J. G., Jr., 1960, Underground Disposal of Industrial Wastes, in Twenty-Third Ann. Short Course for Water and Sewage Plant Siij5 rintendents and Operators Proc.: Louisiana State Univ. Eng. Expt. St. Bull. No. 65, p. 155-162. 23. Paradiso, S. J., 1956, Disposal of Fine chemical Wastes, in Tenth Indust. Waste Conf. Proc.: Purdue Univ. Ext. Ser. N T 89, p. 49-60. 24. Polumbus, E. A., Jr. and Associates Inc., 1961, Rocky Mountain Arsenal Pressure Injection Well - Final Report on Drilling, 3 Vols.: li. A. Polumbus, Jr. and Associates, Inc., Denver, Colorado. 25. Sadow, R. D., 1963, How Monsanto Handles its Petrochemical Wastes: Wastes Eng., Dec., p. 640-644. 26. Sadow, R. 1)., 1966, Waste Treatment at a Large Petrochemical Plant: Water Pollution Control Federation Jour., V. 38, No. 3, p. 428-441. 6 ------- 27. Scopel, L. J., 1964, Pressure Injection L)isposal Well, Rocky Mountain Arsenal, Denver, Colorado: The Mountain Geologist, V. I, No. 1, Jan., p. 35—42. 28. Spalding, C. W., Ilakalo, 1). I ., and Carpenter, H. S., Jr., 1965, liecp Well Disposal of Spent Pumping Liquors: Tech. Assoc. of Pulp and Paper Industries, V. 48, No. 5, p. 68A-71A. 29. Water Well Jour., 19b5, Operation Deep Well: Water Well Jour., May, p. 28-29. 30. Wi nar, R. N., 1 96 , The Deepest Iinderg round Sewer in Michigan: Paper presented at the Spring Meeting of the Eastern District of Production American Petroleum Institute, April 27-29, 196b. 31. Woodlcy, R. A., and Moore, S. L., 196o, 1)ecp Well Disposal of Industrial Wastes in Indiana: Jour. Milk and Food Tech., V. 29, July, p. 211-213. 7 ------- INJECTION WELL DATA Ca-i 1. Aerojet General Corporation 2. Sacramento, California 3. January 1963 4. A. 1,564 ft. B. 970-1,564 ft. C. Sands interbedded with siltstone and mudstone - Tertiary age 5. Waste from nitroplasticizer plant total dissolved solids 48,000 ppm; Na 14,500 ppm; K 6,000 ppm; NO 2 2,100 ppm; SO 4 12,100 ppm; (:1 9,350 ppm; pH 6.2-12.2. 6. Variable - 30 gpm average 7. 50 psi maximun allowable 8. Written communication California State Water Quality Control Board and Aerojet General Corporation Ca- 2 1. Fairchild Space and Defense Systems Division, Photo Processing Plant 2. Beale Air Force Base, California near Marysville, California 3. 1966 4. A. 1,110 ft. plugged back to 1,071 ft. B. 989-1,070 ft. C. Wheatland (?) Formation - Sand - Eocene (?) age 5. Photo processing waste including developers, fix solutions, hardeners, bleaches, and wash waters from both color and black and white processes. The waste liquid contains dissolved silver that is removed by exchange with iron before injection. 7. 8. Written communication Fairchild Space and Defense Systems Ca- 3 1. Fairchild Space and Defense Systems I)ivision, Photo Processing Plant 2. Beale Air Force Base, California near Marysville, California 3. 1906 4. A. 1,304 ft. plugged back to 1,190 ft. B. 1,106-1,196 ft. C. Wheatland (?) Formation - Sand - Eocene (?) age 5. Photo processing waste including developers, fix solutions, hardeners, bleaches, and wash waters from both color and black and white processes. The waste liquid contains dissolved silver that is removed by exchange with iron before injection. 8 ------- Ca-3 (Continued) a. 7. 8. %ritten conununication Fairchild Space and Defense Systems Ca- 4 1. Fairchild Space and Defense Systems Division, Photo Processing Plant 2. Beale Air Force Base, California near Marysville, California 3. 1966 4. A. 1,289 ft. plugged back to 1,213 ft. B. 1,104 - 1,203 ft. C. Wheatland (?) Formation - Sand - Locenc (?) age 5. Photo processing waste including developers, fix solutions, hardeners, bleaches, and wash waters from both color and black and white processes. The waste liquid contains dissolved silver that is removed by exchange with iron before injection. 6. 7. 8. Written communication Fairchild Space and Defense Systems Cl -1 1. U. S. Anny Corps of Lngineers 2. Rocky Mountain Arsenal, 10 miles northeast of Denver, Colorado 3. March 1962 (operation suspended during February 1966)* 4. A. 12,045 ft. B. 11,975-12,045 ft. C. Fractured gnciss of Precambrian age 5. Analysis not available described as s]ightly basic (p11 8) and containing ammonia, nitrates, chlorides, chlorates, chlorinated hydrocarbons, and organic phosphorous compounds. 6. Variable about 200 gpin when operating 7. About 500 psi at an injection rate of 200 gprn. Ilaximum pressure about 1,01)0 psi. 8. Polumbus, E . A., and Associates, 1961 Mechem and Garrett, 1963 Scopel, 1964 Donaldson, 1964 *1 e1l operation was suspended because it was suggested that the well may have been associated with earthquakes that have occurred in the Denver area since 1962 (Evans, 1966). 9 ------- 1.—I 1. Chemstrand Company, I)ivision of Monsanto Company 2. Pensacola, Florida 3. July 19b3 4. A. 1,800 ft. B. l,400-l,bOO ft. C. Lower limestone of Floridan aquifer - limestone - Tertiary age 5. Variable waste from nylon plant composed of organic monohasic and diabasic acids, nitric acid, ammonia, adiponitrile, hexamethylene- diamine, sodium hydroxide, sodium carbonate, alcohols, and ketones. ‘lurbidity 35-95 ppm, p11 2.2-8.9. b. 2 8-l,l00 gpm 7. Injection pressure decreased during operation from an initial 288 gpm at 149 psi to 700 gpm at 137 psi during 19ö4. Decrease in injection pressure is attributed to dissolution of injection horizon by acid waste. 8. !3atz, 1964 Dean, 19O5 Barraclough, I 9( F- 2 1. Sugar Cane Growers Cooperative 2. Near Belle Glade, Florida 3. 1960 4. A. 1,900 ft. B C. cedar Keys Formation - limestone - Tertiary age 5. 1% acetic acid solution 6. 7. 8. Written communication Florida Geological Survey 11—1 1. Velsicol chemical Corporation 2. Near Marshall-Clark County, Illinois 3. March lYōb 4. A. 2,636 ft. B. 2,372-2,636 ft. C. Limestone of Devonian age 5. The waste is produced from the manufacture of thlordane and contains about 100,000 mg/i dissolved solids, primarily spertt sodium hypo- chlorite and sodium chloride, and 50 ppm suspended solids. The specific gravity is about 1.14 and the p11 is about 12.5 6. 00,000 gpd (42 gpm) 7. Gravity flow 8. Written communication illinois Sanitary Water Board and written and oral communication Velsicol Chemical Corporation 10 ------- 11-2 1. Cabot Carbon Corporation 2. Near Tuscola, Douglas County, Illinois 3. 1966 4. A. 5,317 ft. B. 4,898 ft. C. Eninence Dolomite - Cambrian age Potosi Dolomite - Cambrian age Franconia Formation - Cambrian age 5. Hydrochloric acid solution 6. 35,000 gpd maximum (25 gpm) 7. Gravity flow 8. Written communication Illinois Sanitary Water Board 11-3 1. Jones and Laughlin Steel Corporation 2. Near Ilennepin, Putnam County, Illinois 3. Not yet in operation March 1967 4. A. 4,868 ft. B. 3,144 to 4,868 ft. C. Mt. Simon Sandstone - Cambrian age 5. Hydrochloric and chromic acid solution 6. 130 gpm anticipated 7. 200 psi maximum allowable 8. Written communication Illinois Sanitary Water Board In-i 1. American Cyanamid Company 2. Michigan City, Indiana 3. 1951 4. A. 295 ft. B. 200 to 295 ft. C. Sandstone 5. Waste from preparation of aluminum oxide petroleum catalytic cracking catalyst. Waste contains 6,500 mg/i sodium sulfate, 5,000 mg/l ammonium sulfate, and 150 mg/i acidity. 6. 350 gpm 7. 50 psi 8. Donaldson, 1964 Written communication Indiana Stream Pollution Control Board 11 ------- In- 2 1. ,\merican Cyanarnid Company 2. Michigan City, Indiana 3. l95 4. A. 05() ft. B. 270 to b5() ft. C. Limestone and dolomite of Silurian and I)cvonian age 5. Waste from preparation of aluminum oxide petroleum catalytic cracking catalyst. V astc contains 6,500 mg/i sodium sulfate, 5,00(1 mg/I ammonium sulfate, and 150 mg/I acidity. 0. 35(1 gpm. Used alternately with In-i 7. 50 pSi t . Donaldson, 1964 Woodley and Moore, 1900 Written communication Indiana Stream Pollution Control Board In- 3 1. Indiana Farm Bureau Co-op Association, Inc. 2. Mt. Vernon, Indiana 3. 1959 4. A. 2,400 ft. II. 2,0(10 - 2,200 ft. C. hlardinshurg Formation - Sandstone - Mississippian age 5. Waste water containing 0.1 lb/gal, sulfides 6. 6,300 gallons/month 7. . Woodley and Moore, 1960 Written communication Indiana Stream Pollution Control Board In -4 1. FNC Corporation, Newport Army Ammunition Plant 2. Newport, Indiana 3. November 1960 ‘1. A. 6,luO ft. B. 5,450 - 0,160 ft. C. ‘It. Simon Sandstone - Sandstone - Cambrian age 5. highly toxic waste from chemical manufacture consisting in part of sodium hydroxide, phosphorous trichioride, methyldichioro- phosphine, ethanol, and alnmonium chloride. p11 greater than 10, suspended solids 0.1 - 0.2 percent. 6. 50 - 110 gpm when operating 7. 400 - 1,200 psi 8. Ilundley and Matulis, 1962 and 1963 Jbnaldson, 1964 Woodley and Moore, 1966 Written communication Indiana Stream Pollution Control Board — and oral communication FMC Corporation 12 ------- In-s 1. Bethlehem Steel Corporation 2. Chesterton, Indiana 3. 1964 4. A. 4,304 ft. B. 2,222 - 4,263 ft. C. Lau Claire and Mt. Simon Formations - Sandstones - Cambrian age 5. Steel pickling liquor, 6-10% sulfuric acid and 14-18% ferrous sulfate 6. 150 gpm 7. 700 psi 8. Written communication Indiana Stream Pollution Control Board and Indiana Geological Survey Woodley and Moore, 1966 In-6 1. Midwest Steel Division National Steel Corporation 2. Portage, Indiana 3. February 1965 4. A. 4,308 ft. B. 2,100 - 4,259 ft. C. l au Claire and Mt. Simon - Sandstones - Cambrian age 5. Steel pickling liquor, 6-10% sulfuric acid and 14-18% ferrous sulfate 6. 75 gpm 7. gravity flow 8. Written communication Indiana Stream Pollution Control Board and Indiana Geological Survey Woodley and Moore, 1966 Fiartman, 1960 In- 7 1. U. S. Steel Corporation 2. Gary, Indiana 3. Well completed 1965 not yet in operation January 1967 4. A. 4,303 B. 2,452 - 4,303 ft. C. Mt. Simon Sandstone - Sandstone - Cambrian age 5. Steel pickling liquor, 8-37% sulfuric acid, 18-25% ferrous sulfate, and 2-0% chromic acid 6. 6,500,000 gal/month (15 gpm on a 30 day basis) 7. 8. Written communication, Indiana Stream Pollution Control Board and Indiana Geological Survey Woodley and Moore, 1966 13 ------- In-8 I. (eneral Liectric company .!. Mt . Ve rnon, Indiaiia 3. 1900 4. A. 2,800 B. 2,700 — 2,800 ft. C. Bethel Formation - Sandstone - Mississippian age 5. Ui lute aqueous waste containing phenol and hydrochloric acid from manufacture of plastic. 0. Approximately 40 gpm 7. Up to 225 psi M. Oral coiruiunication private consultant In -9 1. Inland Steel company 2. East chicago, Indiana 3. 1907 4. A. ± 4,300 ft. B. *2,300-4,300 ft. C. Mt. Simon Formation - Sandstone - Cambrian age 5. Steel pickling liquor averaging 8% IIZSOf and .75% lId 0. Anticipated 120 gpm with a maximiin of 150 gpm 7. 8. Oral conirninication private consultant lo- 1 1. Quaker Oats Company 2. Cedar Rapids, Iowa 3. 1955 (not in use as of Nov. 19o5) 4. A. 2,525 ft. B. 2,010 - 2,525 ft. C. Mt. Simon Sandstone - Sandstone - Cambrian age 5. 1.5 solution of organic acetic acid 0. 7. 8. Written coninunication, Iowa Geological Survey Ku-i 1. Frontier Chemical Company 2. Wichita, Kansas 3. 1952 14 ------- Ka-1 (Continued) 4. A. 400 ft. B. 240 - 322 ft. C. Geuda salt section of the Wellington Formation - Permian age 5. Saturated hrines, lime sludge, and waste sodium hydroxide derived from production of chlorine, sodium hydroxide, and related products. Raw material is brine obtained from the Wellington Formation. 6. 100 - 200 gpm with maximum of about 350 gpm 7. Gravity flow 8. Donaldson, 1964 Written comunication, Kansas State Dopt. of Health Ka- 2 1. Frontier themical company 2. Wichita, Kansas 3. May 1961 (the original well, completed in 1956, was lost in 1961 when the well casing corroded through and collapsed in the well) 4. A. 4,125 ft. B. 3,927 - 4,125 ft. (perforated 3,990 - 4,115 ft.) C, Arbuckle Limestone - Limestone - Ordovician age 5. Unsaturated Ca and Mg brine solutions, impure bromine, chlor- inated organics, and hydrochloric acid. The p11 ranges from 1 to 9 during short periods. The waste is derived from pro- duction of chlorine, sodium chloride, and related products from brines in the Wellington Formation. 6. 200 - 400 gpm 7. Gravity flow 8. Donaldson, 1964 Written coninunication, Kansas State Board of Health L- 1 1. Universal Oil Products 2. Caddo Parish, Louisiana Sec. 29 T19N-RJ5IV 3. 1952 4. A. 2,262 ft. B. 987 and 1,998 (formation tops) C. Nacatoch and Blossom Sands - Tertiary age 5. Waste water containing sodium, calcium, magnesium, chloride, sulfate, and organic chemicals. 6. 500 gpm into 4 wells (L1-L4) 7. 8. Written coniminication, Louisiana Geological Survey 15 ------- L- 2 1. Universal Oil Products 2. Caddo Parish, Louisiana Sec. 29 T19N-R15W 3. 1957 4. A. *2,100 ft. B. About the same as LI C. Nacatoch and Blossom Sands - Tertiary age S. Waste water containing sodium, calcium, magnesium, chloride, sulfate, and organic chemicals. 6. 500 gpm into 4 wells (Ll-L4) 7. 8. Written communication, Louisiana Geological Survey L- 3 1. Universal Oil Products 2. Caddo Parish, Louisiana Sec. 29 T19N-R]5W 3. 1961 4. A. 1,102 ft. 8. 984 ft. (top) C. Nacatoch Sand - Tertiary age 5. Waste water containing sodium, calcium, magnesium, chloride, sulfate, and organic chemicals. 6. 500 gpin into 4 wells (L1-L4) 7. 8. Written communication, Louisiana Geological Survey L-4 1. Universal Oil Products 2. Caddo Parish, Louisiana Sec. 29 TI9N-R15W 3. 1967 4. A. ± 1,100 ft. B. 975 ft. C. Nacatoch Sand - Tertiary age 5. Waste water containing sodium, calcium, magnesium, chloride, sulfate, and organic chemicals. 0. 500 gpm into 4 wells (Ll-L4) 7. 8. Written communication, Louisiana Geological Survey 16 ------- 1_s 1. Shell Chemical Company, Norco Plant 2. Norco, Louisiana, St. Charles Parish 3. 1956 4. A. 1,960 ft. B. 1,670 - 1,960 ft. C. Unconsolidated sand reported to he of Pleistocene age 5. Originally waste water containing calcium and sodium chlorides, dissolved organics, and suspended silica and calcium carbonate particles, with small amounts of chlorinated organics was injected intermittently. Most recently reported to be injecting waste water containing acrolein and derivatives of acrolein, toxic organic chemicals, diatomaccous earth, and aluminum hydroxide. 6. Up to 600 gpm before construction of L-6 7. 210 psi at 600 gpni 8. Moffett, 19b() 1)onaldson, 1964 Ilough, 1963 1 lough, 1965 L-ö 1. Shell Chemical Company, Norco Plant 2. Norco, Louisiana, L-5 and L-6 are only 30 ft. apart at the surface and 300 ft. apart at the bottom 3. 1959 4. A. ± 1,800 ft. B. 1,670 - 1,800 ft. C. Unconsolidated sand reported to be of Pleistocene age 5. Waste water containing acrolein and derivatives of acrolein, toxic organic chemicals, diatomaceous earth, and aluminum hydroxide. 6. 700 gpm into 2 wells (L-l and L-2) 7. 150 - 170 psi 8. Moffctt, 1960 I na1dson, 1964 llough, 1963 Ilough, 1965 L- 7 1. Shell Chemical Company, Norco Plant 2. Norco, Louisiana 3. 1966 4. A. 2,100 ft. B. 1,700 ft. (top) C. Sand - probably of Pliocene age 5. Similar to L-6 6. 7. 8. Written coniuunication Louisiana Geological Survey 17 ------- L- 8 1. Shell Chemical Company, Norco Plant 2. Norco, Louisiana Sec. 4 T12S-R8E 3. Not yet in operation 4. A. 2,000 ft. B. Not available C. Sand - probably of Pliocene age 5. 30% HC1 solution 6. Estimated to be about 30 gpm 7. 8. Written communication, Louisiana Geological Survey L-9 1. Shell Oil Company, Norco Refinery 2. Norco, Louisiana 3. 1959 4. A. 1,795 ft. 13. 1,700 - 1,900 ft. C. Unconsolidated sand reported to be of Pleistocene age 5. Refinery process water with 1,790 ppm sulfides, 165 ppm phenols, 38 ppm mercaptans, and 20 ppm suspended solids 6. 200 gpm 7. 30-90 psi 8. Graves, 1961 Donaldson, 1964 Hough, 1963, 1965 L- 10 1. Shell Oil Company 2. Norco, Louisiana Sec. U T12S-R8U 3. 1965 4. A. 1,954 ft. B. 1,848 ft. (top) C. Sand - probably of Pliocene age 5. Waste water containing sulfides, phenol, oil, and suspended solids 6. 187 gpn average 7. 8. Written communication, Louisiana Geological Survey 18 ------- L- 11 1. Shell Oil Company 2 Norco, Louisiana Sec. 6 T12S-R8E 3. l9 5 4. A. 1,997 ft. B. 1,858 ft. (top) C. Sand - probably of Pliocene age 5. I astc water containing sulfides, phenol, oil, and suspended solids 6. 110 gpm average 7. 8. Written communication, Louisiana Geological Survey L- 12 1. Shell Chemical Company, Geismar Chemical Plant 2. Geismar, Louisiana, Ascension Parish Sec. 14 T1OS-R2L 3. 1966 4. A. 1,980 ft. B. 1,970 - 1,975 ft. C. Sand of Tertiary (Pliocene or Miocene) age 5. 50 gpm of hydrochloric acid solution from plant operations 0. 7. 8. ltough, 1965 Written communication, Louisiana Geological Survey L- 13 1. Shell Chemical Company, Geismar Chemical Plant 2. Geismar, Louisiana Sec. 14 T1OS-R2E 3. 1907 4. A. 2,506 ft. B. 1,550 ft. C. Sand - probably of Pliocene age 5. Waste water 6. 7. 8. Written communication, Louisiana Geological Survey 19 ------- L- 14 1. Tenneco Oil Company, Chalmette Refinery 2. Chalmette, Louisiana, St. Bernard Parish Sec. 7 T13S-R12E 3. 1960 4. A. 1,980 ft. B. 1,944 - 1,968 ft. C. Unconsolidated Sand reported to be of Pleistocene age 5. Waste from catalytic cracker containing phenols, mercaptans, and sulfides, and brine from crude-oil desalting unit. 6. 100 gpm 7. 40-100 psi 8. Donaldson, 1964 llough, 1965 L- 15 1. Tenneco Oil Company, thalniette Refinery 2. Chalmette, Louisiana, St. Bernard Parish Sec. 7 T13S-R12E 3. 1963 4. A. 2,000 ft. B. 1,920 - 1,950 ft. C. Sand of Pleistocene or Pliocene age 5. 7 gpm of waste water from petroleum refining processes con- taining traces of phenol, hydrocarbons, and sulfides, pH 7.4. 6. 7gpm(?) 7. 8. Hough, 1965 Written communication, Louisiana Geological Survey L- 16 1. National Aeronautics and Space Administration 2. New Orleans, Louisiana, Orleans Parish 3. 1964 4. A. About 7,000 ft. B. About 6,000 ft. C. Sand of Tertiary (Miocene) age 5. Waste cleaning solutions and rinse water including acids, alkalis, and chromates from cleaning of rocket components. 6. 400,000 gpd (278 gpm) 7. 1,350 psi maximum 8. Chemical Week, 1965 Hough, 1965 20 ------- L- 17 1. Texaco, Inc., Louisiana Plant (refinery) 2. Convent, Louisiana, St. James Parish Sec. 12 T11S-R3E 3. 19b6 4. A. 2,201 ft. B. 1,840 ft. C. Sand of Tertiary (Pliocene or Miocene) age 5. 600 to 80() gpm of salt water from crude oil desalting and waste water from petroleum refining operations. Waste con- tains about 600 ppm dissolved solids, 70 ppm phenols, sulfides, and 10 ppm suspended solids and has a pH of b-S. 6. bOO to 800 gpm into two wells 7. 8. Hough, 1965 Written conmiunications, Louisiana Geological Survey and project consultant. L- 18 1. Texaco, Inc., Louisiana Plant 2. Convent, Louisiana, st. James Parish 3. 1966 4. A. 2,195 ft. B. 2,103 - 2,193 ft. C. Sand of Tertiary (Pliocene or Miocene) age 5. 600 to 800 gpm of salt water from crude oil desalting and waste water from petroleum refining operations. Waste con- tains about 6,000 ppm dissolved solids, 70 ppm phenols, sulfides, and 10 ppm suspended solids and has a p11 of 6-8. 6. 600-800 gpni into two wells 7. 8. Ilough, 1965 Written communications, Louisiana Geological Survey and project consultant. L- 19 1. American Cyanamid Company (chemical plant) 2. Avondale, Louisiana, Jefferson Parish 3. March 1966 4. A. 2,721 ft. B. 2,465 - 2,495 ft. C. Sand of Tertiary (Pliocene) age 5. 20 gpm waste water containing cyanides, sulfates, ammonia, and nitriles 6. 225 gpm into L-20 and L-21 7. 8. Ilough, 1965 Written communication, Louisiana Geological Survey 21 ------- L- 20 1. American Cyanamid Company 2. Avondale, Louisiana, Jefferson Parish 3. March 19b6 4. A. 3,302 ft. B. 3,145 - 3,200 ft. C. Sand of Tertiary (Pliocene) age 5. 20 gpm waste water containing cyanides, sulfates, ammonia, and nitriles 6. 225 gpm into L-20 and L-21 7. 8. Hough, 1965 Written communication, Louisiana Geological Survey L- 21 1. E. 1. DuPont de Nemours and Company 2. Ponchatrain, Louisiana, St. John The Baptist Parish Sec. 90 T11S-R7E 3. 1966 4. A. 5,203 ft. B. 5,080 - 5,162 ft. C. Sand of Tertiary age 5. Brine solution 6. 30,000 pounds/hr. (about 60 gpm) 7. 130 psi 8. Oral communication, Louisiana Division of Oil and Gas L- 22 1. E. I. DuPont de Nemours and Company 2. Ponchatrain , Louisiana, St. John The Baptist Parish Sec. 90 T11S-R7E 3. 1966 .4 A + flA C . ‘t. t o J UU IL .. B. 5,050 - 5,090 ft. C. Sand of Tertiary age 5. Brine solution 6. 140,000 pounds/hr.- (about 280 gpm) 7. 225 psi 8. Oral communication, Louisiana Division of Oil and Gas 22 ------- I -23 1. L. I. DuPont de Nemours and Company 2. Ponchatrain, Louisiana, St. John The Baptist Parish Sec. 90 TI1S-R7E 3. Not yet in operation as of August 1967 4. A. 5,300 ft. B. 4,b33 - 4,()68 ft. and 5,080 - 5,090 ft. C. Sands of Miocene age 5. Brine solution b. 200 gpm 7. 8. Written communication, Louisiana Geological Survey L- 24 1. Perkins Glue Company 2. Alexandria, Louisiana Sec. 41 T3N-R1W 3. Not yet in operation as of August 1967 4. A. ± 3,000 ft. B. ± 3,000 ft. C. Cockficld Formation - Sand - Tertiary age 5. Caustic soda and phenol 6. 7. 8. Written communication, Louisiana Geological Survey Mc-1 1. Old Dutch Refining Company 2. Muskegon, Michigan Sec. 2h T ION-R1bW 3. September 1948 4. A. 2,346 ft. B. 1,758 ft. C. Dundee Formation and Detroit River Group - Limestone and Dolomite - [ )evonian age 5. Oil refinery effluent 6. 60-65 gpm est. 7. None recorded 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey Note: Well was plugged and abandoned April 12, 1951. No reasons were given. 23 ------- Mc- 2 1. Parke, Davis and Company 2. Holland, Michigan Sec. 20 T5N-R15W 3. May 1951 4. A. 1,635 ft. B. 1,424 ft. C. Traverse Group - Limestone and Dolomite - Devonian age 5. Sodium, acetate, chloride, ammonia, bromide, and unidentified organic compounds. Total dissolved solids 60,000 ppm; pH 3.7; intense reddish-brown color. Waste derived from manufacture of chioromycetin. 6. 1,252,056 gal. per month during 1966 pumped to two wells (about 30 gpm on a 30-day basis) 7. 200-400 psi, average about 280 psi 8. Adinoff, 1955 Written communication, Michigan Water Resources Commission and Michigan Geological Survey Note: This well is connected in series with another well (Mc-3). Waste fluids are punp d simultaneously to both wells. Records of quantities and pressures are for this combined system and not each well individually, Mc-3 1. Parke, Davis and Company 2. Holland, Michigan Sec. 20 T5N-R15W 3. October 1956 4. A. 1,946 ft. B. 1,649 ft. C. Detroit River Group - Dolomite and Limestone - Devonian age 5. Pharmaceutical process wastes 6. 1,252,056 gal. per month during 1966 pumped to two wells (about 30 gpm on a 30-day basis) 7. 200-400 psi, average about 280 psi 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey Note: This well was reported injecting in Traverse Group and Dundee Formation; however, there is no record of this. Records indicate the long string of casing was set at 1,649 feet. If the upper zones are open, the Company must have perforated them at a later date. 24 ------- Mc- 4 1. Hooker E.lectrochcmical Company 2. Montague, Michigan Sec. 30 T12N—RI7W 3. April 1953 4. A. 2,Oöb ft. 8. 1,703 ft. C. Traverse Group - Limestone - Devonian age 5. Sodium sulphate, sodium chloride, and calcium sulfate . No record 7. No record 8. Written communication, Michigan Water Resources Comission and Michigan Geological Survey Note: Reported November l9 5 that their wells (Mc-4 and Mc-5) had lugged with calcium sulfate. They may have reworked one or both of these wells hut the records do not indicate this. Mc -5 1. Hooker Llectrochemical Company 2. Montague, Michigan Sec. 31 T12N-RI7W 3. May E)5U 4. A. 2,033 ft. B. l,9b2—72 1,99o-2,068 ft. C. Traverse Group - Limestone - Devonian age 5. Sodium sulfate, sodium chloride, and calcium sulfate t. No record 7. No record 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey Mc -6 1. Reichhold (2icmicals, Inc. 2. Ferndale, Michigan Sec. 27 TiN-RilE 3. 1952 or 1953 4. A. 1,053 ft. B. 693 ft. C. Sylvania Formation - Dolomite and Sandstone - Devonian age 5. Phenols b. 3-1/2 gpm when in operation 7. 35 psi or less when in operation 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey 25 ------- Mc-6 (Continued) Note: Well accepted 1,764 gpm at 125 psi during testing. This well was plugged and abandoned in November 1957 with no reason given. Mc- 7 1. The Upjohn Company 2. Kalamazoo, Michigan 3, May 1954 4. A. 1,530 ft. B. 1,270 - 1,530 ft. C. Traverse, Dundee, and Detroit River Groups - Sandy Limestone, ndstone, and dolomite - Devonian age 5. Spent mineral acids and their salts, alcohols, chlorinated and unchiorinated hydrocarbons, organic acids, aldehydes, ketones, and steroids. Total dissolved solids 500-7,000 ppm; p11 2.0-8,0, but reported to be constantly at 4.0-4.5 as of 19b2. Waste derived from manufacture of cortical steroid products. 60 50-100 gpm injected into two wells (Mc-7 and Mc-8) 7. 500-990 psi 8, Paradiso, 1956 Donaldson, 1964 Written communication, Michigan Water Resources Commission Mc-8 1. The Upjohn Company 2. Kalamazoo, Michigan 3. May 1954 4. A. 1,475 ft. B. 1,276 - 1,475 ft. C. Traverse, Dundee, and Detroit River Groups - Sandy limestone, Sandstone, and L)olomite - Lbvonian age 5. Spent mineral acids and their salts, alcohols, chlorinated and unchiorinated hydrocarbons, organic acids, aldehydes, ketones, and steroids. Total dissolved solids 500-7,000 ppm; pH 2.0- 8.0, but reported to be constantly at 4.0-4.5 as of 1962. Waste derived from manufacture of cortical steroid products. 6. 50-100 gpm injected into two wells (Mc-7 and Mc-8) 7. 500-990 psi 8. Paradiso, 1956 Donaldson, 1964 Written communication, Michigan Water Resources Commission 26 ------- 1. 1)ow Chemical Company, Bay Refining Company 1)ivision 2. Bay City, Michigan 3. 1954 4. A. 4,710 ft. B. 4,026 ft. C. Lower Detroit River ( roup - Sandy limestone and Sandstone - Devonlan age 5. Waste water containing phenol, acid, and spent caustic. 6. About 45 gpm 7. 1,200 psi and greater 8. Written comunication, Michigan Water Resources commission Mc-1() 1. Dew Chemical Company, Bay Refining Company Division 2. Bay City, Michigan 3. September 1959 4. A. 4,605 ft. B. 4,497 ft. C. Sylvania Formation - Sandstone - Devonian age 5. Waste water containing phenol, acid, and spent caustic. 6. About 45 gpm when operating 7. Estimated to be 1,200 psi when operating 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey Note: Well Mc-10 is being used as a standby for well Mc-9. Mc- 11 1. Dow Chemical Company 2. Midland, Michigan 3. April 1960 (drilled May 1952) 4. A. 3,740 ft. B. 3,580 ft. C. I)indec Formation - Limestone - Devonian age 5. Organic wastes similar to phenol, brine, propylene oxide, methyl cellulose, and wash water containing small amounts of organic chemicals. Wastes are from oil refining and salt-mining operations. 6. No record 7. No record 8. Written communication, Michigan Water Resources Commission Donaldson, 1964 Note: This well is being used as a standby for wells Mc-12 and Mc-13. 27 ------- Mc - 12 1 • Dow Chemical Company 2. Midland 9 Michigan 3. July 1960 (drilled 1945) 4. A. B. 3,865 ft. C. Dundee Formation - Limestone - Devonian age 5. Organic wastes similar to phenol, brine, propylene oxide, methyl cellulose, and wash water containing small amounts of organic chemicals. Wastes are from oil refining and salt mining operations. 6. Approximately 200 gpm 7. 140 - 585 psi 8. Written conununication, Michigan Water Resources Commission Donaldson, 1964 Mc- 13 1. Dow Chemical Company 2. Midland, Michigan 3. July 1961 (drilled 1951) 4. A. 5,150 ft. B. 4,925 ft. C. Sylvania Formation - Sandstone - Devonian age 5. Organic wastes similar to phenol, brine, propylene oxide, methyl cellulose, and wash water containing small amounts of organic chemicals. Wastes are from oil refining and salt mining operations. 6. Approximately 200 gpm 7. 350 - 965 psi 8. Written communication, Michigan Water Resources Commission Donaldson, 1964 Mc- 14 1. Dow Chemical Company 2. Midland, Michigan 3. June 1964 4. A. 3,930 ft. B. 3,915 ft. C. Dundee Formation - Limestone - Devonian age 5. Activated sludge produced as a by-product of waste treatment (3% organic solids). 6. Approximately 60 gpni 7. 1,725 - 2,850 psi 8. Written communication, Michigan Water Resources Commission 28 ------- Mc -15 1. Ford Motor Company 2. Dearborn, Michigan 3. 1956 4. A. 563 ft. B. 482 ft. C. Sylvania Formation - Sandstone - I)evonian age 5. Phenols and coke quench water from coke manufacture 6. Approximately 50,000 gpd (35 gpm) 7. 54 - (,63 psi 8. [ naldson, 1964 Written communication, Michigan Water Resources Commission Mc-lO 1. Leonard Refineries, Inc. 2. Alma, Michigan 3. June 1957 4. A. 1,244 ft. B. 1,030 ft. C. Marshall Formation - Sandstone - Mississippian age 5. Foul condensate and spent caustic solution from refinery operations. 6. 25-30 gpm 7. 550 - 940 pSi 8. Written communication, Michigan Water Resources Commission Mc-17 1. Ilolland-Suco Color Company, subsidiary of Chemetron Corporation 2. I o11and, Michigan 3. 1966 4. A. 5,895 ft. B. 4,608 - 5,895 ft. C. Franconia, Dresbach, Eau Claire, and Mt. Simon Formations - Sandstones - Cambrian age S. Contaminated dilute sulfuric acid from pigment nianufacturing 6. 25 gpm average - up to 120 gpm 7. 125 psi average - up to 275 psi 8. Winar, 1966 Civil Engineering, 1966 Written communication, Michigan Water Resources Commission 29 ------- Mc- 18 1. Wyandotte Chemicals Corporation 2. Wyandotte, Michigan 3. October 1966 4. A. 1,400 ft. estimated 13. 850 ft. C. Sauna Group - Evaporites - Silurian age 5. Process wastes containing 3% solids b. 375 - 1,075 gpm into two wells 7. Gravity 8. Written couununication, Michigan Water Resources Commission Note: This well is connected in series with another well (Mc-19). Waste fluids are pinnped simultaneously to both wells. Records of quantities are for this combined system and not each well individually. Wastes are injected into salt solution cavities. Mc-19 1. Wyandotte Chemicals Corporation 2. Wyandotte, Michigan Sec. 23 T12N-R2W 3. October 1966 4. A. 1,400 ft. est, B. 850 ft. C. Sauna Group - Evaporites - Silurian age 5. Process wastes containing 3% solids 6. 375 - 1,075 gpm into two wells 7. Gravity 8. Written communication, Michigan Water Resources Commission Mc-20 1. Blunk Laundromat 2. Union Lake, Michigan Sec. 35 T3N-R8E 3. March 1967 4. A. 1,840 ft. B. 1,774 ft. C. Sylvania Fo ation - Sandstone - I)evonian age 5. Laundromat wastes 6. Estimated 5-1/2 gpm 7. Gravity 8. Written communication, Michigan Water Resources Commission 30 ------- Mc-2 1 1. Michigan Chemical Corporation 2. St. Louis, Michigan 3. May 19ö7 4. A. 3,7b2 ft. B. 3,422 ft. C. Dundee Formation - Dolomite and Limestone - Devonian age 5. Waste brincs from processing of natural brine. 6. 200 gpin 7. Gravity 8. Written communication, Michigan Water Resources Commission and Michigan Geological Survey Mn-i 1. The Anaconda Company 2. Grants, New Mexico 3. December 1960 4. A. 2,511 ft. B. 950 - 1,450 ft. (approximately) C. Yeso Formation - Sandstone - Permian age 5. Mildly acid solution containing large amounts of manganese, iron and sulfate and chloride salts of sodium, calcium, and magnesium. Also contains small concentrations of uranium, Thorium-230, and Radium-226. Total dissolved solids 16,243 ppm; p112.8; waste from uranium ore proccssing. 6. 200 - 300 gpm 7. Gravity flow 8. Arlin, 1962 Donaldson, 1964 Written coimnunication, New Mexico Department of Public Health (inquiries may be directed to New Mexico Department of Public Health) 1. Armco Stcel Corporation 2. Middlctown, Ohio 3. Probably will not he put in operation until late 1968. 4. A. 3,297 ft. B. 2,922 - 3,235 ft. C. Mt. Simon Formation - Sandstone - Cambrian age 5. Steel pickling liquor maximum concentrations of 1% lId, 25% Fed 2 , and 1-1/2% FcCI 3 . 6. Lstimated 100 gpm 7. Estimated 450 psi 8. Oral communication, Armco Steel and project consultants 31 ------- Ok-i 1. American Airlines, inc. 2. Tulsa, Oklahoma 3. January 1960 4. A. 3,036 ft. B. 1,807 - 3,036 ft. C. Arbuckle - Limestone - Ordovician age 5. Complex mixture of rinse water and batch dumpings from electro- plating tanks, various organic solvents, cresols and phenols, detergents, paint removers, and oil. pH range 5.6-9.4. Waste from maintenance of aircraft. 6. 196,000 gpd during an 11 hour period (300 gpm while operating) 7. 300 psi 8. Luff, 1960 Denaldson, 19ö4 Written communication, Oklahoma State Department of health p-i 1. Jones and Laughlin Steel Corporation 2. Aliquippa, Pennsylvania 3. October 1964 4. A. 5,445 ft. B. 5,387 - 5,445 ft. C. Oriskany Formation - Sandstone - Devonian age 5. Sulfuric acid waste from steel pickling operations (10% H 2 S0 4 and 10% FCSO4) 6. 100 gpm 7. About 4,000 psi 8. Jukkola and Vajada, 1965 Written communication, Pennsylvania Department of health P- 2 1. Hammermill Paper Company 2. Erie, Pennsylvania 3. April 19b4 4. A. 2,302 ft. B. 1,610 - 1,688 ft. C. Bass Islands Dolomite - Lb lomite - Silurian age 5. Spent sulfite pulping liquor containing fibers, fiber fragments, paper filter materials such as clay and Ti02, and lignin-like compounds in the colloidal and semi-colloidal particle-size range. 6. 500,000 to b00,000 gpd into two wells (350 to 415 gpm) as of 1967 7. 1,100 - 1,300 psi 32 ------- P-2 (Continued) 8. Spalding and Others, 1965 Brown and Spalding, 1966 Water Well Journal, 1905 Written communication, Pennsylvania Department of Health P- 3 1. Hammei,nill Paper company 2. Eric, Pennsylvania 3. 1905 4. A. 5,972 ft. B. 1,658 - 1,732 ft. and 5,914 - 5,952 ft. C. Bass Islands I)olomite - Dolomite - Silurian age; Mt. Simon Formation - Sandstone - Cambrian age; sheared or fractured Precambrian basement rocks. 5. Spent sulfite pulping liquor containing fibers, fiber fragments, paper filler materials such as clay and hO 2 , and lignin-likc compounds in the colloidal and semi-colloidal particle-size range. 6. 500,000 to 600,000 gpd into two wells (350-415 gpm) as of 1967 7. 8. Spalding and Others, 1905 Brown and Spalding, 1906 Water Well Journal, 1965 Written conununication, Pennsylvania Department of Health p- 4 1. Gulf Research and Development Company 2. Colerain Township, Bedford County, Pennsylvania 6 miles south of Bedford, Pennsylvania 3. November 1964 4. A. 563 ft. B. 540 - 563 ft. C. Bellefonte !. lomitc - Dolomite - Ordovician age 5. Drilling mud produced for field experiments with oil-well drilling muds. 0. Used only periodically, 0 - 22,000 gpd 7. 1,000 - 1,300 psi 8. Written communication, Pennsylvania Department of Health 1 - 5 1. Bethlehem Steel Company 2. Franklin Boro, Cambria County, Pennsylvania northeast of Johnston, Pennsylvania 3. Reports indicate that this well was abandoned after initial injection testing in 1966. 33 ------- P-S (Continued) 4. A. B. 570 - 835 ft. C. Burgoon Sandstone (Pocono Formation ) - Sandstone - Mississippian age 5. Weak ammonia liquor 6. - - - 7. 8. Written communication, Pennsylvania Department of Health Tn-i 1. 13. I. DuPont de Nemours and Company Pigments Department 2. New Johnsonville, Tennessee 3. 1967 4. A. 6,734 ft. B. 3,010 - 6,734 ft. C. Knox Dolomite - Cambrian age 5. 13 - 15% aqueous ferric chloride solution. Specific gravity 1.1 pH 1.5-1.6. 6. 300 gpm anticipated 7. 250 psi anticipated 8. E. I. DuPont de Nemours and Company Tx-i and Tx 2* 1. Monsanto Chemical Company 2. chocolate Bayou (10 miles south of Alvin, Texas) 3. 1961 4. A. 6,330 ft. B. 6,045 - 6,294 ft. C. Unconsolidated sands of Miocene age 5. Phenol 1,000 - 2,000 mg/i Oil 150 mg/i chlorides 300 mg/i Sulfates 1,800 mg/i Total alkalinity (as CacO 3 ) 2,000 mg/l COD 10,000 mg/l pH 10.7 High-level waste from manufacture of ethylene, propylene, benzene, napthalene, butadiene, phenol, acrylonitriie, soft detergent bases, resins, and other related aromatics. b. 300 gpm 7. 1,000 psi *Second well drilled as a source of brine to mix with waste. Could be converted to an injection well. 34 ------- Tx-i and Tx-2 (Continued) 8. Sado, 1963, 1966 Written communication, Texas Water Development Board Tx -3 1. Potash Company of America 2. 5 miles north of Iknnas, Moore County, Texas 3. 1962 4. A. 1,265 ft. B. 1,131 - 1,23] ft. C. Glorietta Formation - Sandstone - Permian age 5. 31% waste hydrochloric acid from conversion of potassium chloride to potassium sulfate 6. Injection is intermittent with an anticipated maximum of 20,000 gpd (14 gpm) 7. Gravity injection 8. Donaldson, 1964 Written communication, Texas Water Development Board Tx- 4 1. Shamrock Oil and (“as Corporation, McKee Plant 2. Near Dumas, Moore County, Texas 3. 1958 4. A. ± 1,350 ft. B. 1,300 - 1,350 ft. C. Glorietta Formation - Sandstone - Permian age 5. Entire waste strean from petroleum refining operation including spent sulfuric acid from alkylation unit, spent caustic and brines from caustic scrubbers, cooling-tower blowdown water, etc. 0. 400 gpm (into two wells) 7. Upto7Opsi 8. Written communication, Texas Water Development Board Donaldson, 1964 Tx- 5 1. Shamrock Oil and Gas Corporation, McKee Plant 2. Near E)umas, Moore County, Texas 3. 1958 4. A. t 1,250 ft. B. 1,106 - 1,146 ft. C. Glorietta Formation - Sandstone - Permian age 5. Entire waste stream from petroleum refining operations including spent sulfuric acid from alkylation unit, spent caustic and brines from caustic scrubbers, cooling-tower hiowdown water, etc. 35 ------- Tx-S (Continued) 1. 2. 3. 4. 6. 400 gpm (into two wells) 7. Up to 7Opsi 8. Written communication, Texas Water Development Board Donaldson, 1964 Tx-6 Shamrock Oil and Gas Corporation, Sunray Plant Near flumas, Moore County, ‘lexas ± 1,250 ft. B. 1,138 - 1,158 ft. C. Glorietta Formation - Sandstone - Penmian age 5. Gasoline plant waste including cooling-tower blowdown water and stripping stream condensate which contains varying amounts of chromates, sulfates, sulfides, and oil. O. 50-70 gpm 7. 55-100 psi 8. Written communication, Texas Water Development Board Donaldson, 1964 Tx- 7 1. E. I. DuPont de Nemours and Company, Victoria Plant 2. 4 miles northwest of Bloomington, Victoria County, Texas 3. 1953 4. A. 4,877 ft. B. 4,000 - 4,680 ft. C. Lower Catahoula and Greta sands - Tertiary age - with upper Catahoula and Oakville sands for possible future use. 5. 18% sodium chloride with traces of metallic salts and organic compounds. Waste derived from manufacture of adiponitrile - an intermediate for nylon. 6. 100-200 gpm (wells Tx-7 and Tx-8 used alternately) 7. 50-200 psi 8. Henkel, 1953, 1955 Written communication, Texas Water Development Board Tx-8 1. 1.. I. DuPont de Nemours and Company 2. 4 miles northwest of Bloomington, Victoria County, Texas 3. 1954 4. A. 4,705 ft. B. 4,000 - 4,630 ft. C, Lower Catahoula and Greta sands - Tertiary age - with upper Catahoula and Oakville sands for possible future use. 36 ------- Tx-8 (Continued) 5. 18% sodium chloride with traces of metallic salts and organic compounds. Waste derived from manufacture of adiponitrile - an intermediate for nylon. 6. 100-200 gpm (wells Tx-7 and Tx-8 used alternately) 7. 50-200 psi 8. llenkel, 1953, 1955 Writtcn communication, Texas Water Development Board ix -9 1. L. 1. IkiPont de Nemours and Company, Victoria Plant 2. 4 miles northwest of Bloomington, Victoria County, Texas lx-9 is located midway between Tx-7 and Tx-8 and is generally similar to these wells. Tx -10 1. 1. I. ftiPont de Nemours and Company, Victoria Plant 2. 4 miles northwest of Bloomington, Victoria County, Texas 3. December 19b3 Tx-lO is located near Tx-8 and is generally similar to Tx-7, Tx-8, and Tx-9. b. 120 gpm average 7. 200 psi average 8. Written communication, Texas Water Development Board Tx -1] 1. Northern Natural Gas Company 2. 8 miles SE of Spearman, Ochiltrce county, Texas 3. January 1964 4. A. 4,057 ft. B. 3,722 - 4,016 ft. C. Brown Eblomite 5. Waste from natural gas compressor and purification plant Chloride (as Cl 2 ) 3,040 ppm Total hardness (as CaCO3) 1,089 ppm Total dissolved solids 12,804 ppm p11 7.9 6. 4-7 gpm 7. Gravity flow 8. Written comunication, Texas Water Development Board 37 ------- Dc-12 1. Pan American Petroleum Corporation, West Yantis Plant (gas) 2. 4-1/2 miles northwest of Yantis, Wood County, Texas 3. 1963 4. A. 5,231 ft. B. 4,775 - 5,160 ft. C. Woodbine Group - Sandstone - Cretaceous age 5. Cooling-tower blowdown water, plant process waste water, produced brine separated from natural gas. 6. 2-160 gpm,average 100 gpm 7. Gravity to 390 psi, average 145 psi 8. Written communication, Texas Water Development Board Tx- 13 1. Western M!nonia Corporation 2. 2 miles southeast of Dimmitt, Castro County, Texas 3. August 1964 4. A. 1,048 ft. 8. 951 - 980 ft. C. Santa Rosa Sandstone - Sandstone - Triassic age 5. Cooling-tower blowdown and water treating plant waste from production of anhydrous ammonia. Total dissolved solids 2,300 - 2,700 ppm Chloride 40 - 60 ppm Sulfate 800 - 1,500 ppm Sodium 280 - 400 ppm Nitrogen (as ammonia) 20 - 46 ppm Chromium 10 - 20 ppm pH 3.0 6. 30-5ogpm 7. Initially gravity injection, as of April 1965 average injection pressure about 270 psi. 8. Written communication, Texas Water Development Board Dc-14 1. Celanese Chemical Company 2. 7.5 miles southwest of Bay City, Matagorda County, Texas 3. 1964 4. A. 3,780 ft. B. 3,507 - 3,552 ft. C. Sand of Tertiary (Miocene) age 5. 0.3% acetic acid and chlorinated derivatives from production of acetaldehyde, butanol, and other organic acids by catalytic cracking of natural gas. 6. 200 gpm 7. 200 psi 8. Written communication, Texas Water Development Board Klotzman and Vier, 1966 38 ------- ‘lx-15 1. Atlantic Refining Company, ATRECO Refinery 2. 6 miles northeast of Port Arthur, Jefferson County, Texas 3. December 1964 (not in use as of January 1967) 4. A. 3,412 ft. 13. 2,758 - 2,834 ft. C. Sands of Miocene age 5. 32% hydrochloric acid solution containing benzene, chlori- nated hydrocarbons, etc. Waste generated during production of detergents. Total waste production estimated to initially be 35,000 gpcl increasing to a maximum of 53,000 gpd and remaining at this level. 6. Injection rate about 35 gpm in December 1964 7. Gravity flow 8. Written ccmnTiunication, Texas Water Development Board Tx -16 1. Pan 4jnerican Petroleum Corporation, Edgewood Gas Processing Plant 2. 3 miles east of Ldgewood, Van Zandt County, Texas 3. 1964 4. A. 4,862 ft. B. 4,652 - 4,828 ft. C. Woodbine Group - Sandstone - Cretaceous age 5. Cooling-tower and boiler blowdown water, process waste water and produced salt water separated from natural gas. 6. 25 - 205 gpm, average 130 gpm 7. 50 - 300 psi during 1965 and 1966 8. Written communication, Texas Water Development Board Tx-17 and Tx-l8 1. Service Pipe Line company 2. 6 miles southeast of Sundown, Hockley county, Texas 3. 1964 4. A. ± 2,150 ft. B. 1,700 - 2,150 ft. C. Santa Rosa Sandstone - Sandstone - Triassic age 5. Saturated brine created during “washing-out” of a cavity in the salt interval of the Salado Formation for underground liquid-petroleum-gas storage. Wells will only be used actively during washing out period, then will he used for emergencies or during creation of new activities. 0. Up to 680 gpm for two wells 7. Up to 735 psi 8. Written communication, Texas Water Development Board 39 ------- Tx- 19 1 • E • I. D&ont de Neinours and Company, Sabine River Works 2. 2 miles south-southeast of West Orange, Orange County, Texas 3. 1965 (presently a standby well replaced in 1966 by Tx-32) 4. A. 5,252 ft. B. 2,240 - 2,920 ft. C. Sands of Pliocene - Miocene age 5. Waste water containing 0.7% nitric acid and 1.0% straight chain organic acids. Waste from production of polyethylene and related products. 6. 375 gpm 7. 350 psi 8. Written coimnunication, Texas Water Development Board Tx- 20 1. Monsanto Company 2. Near Alvin, Brazoria County, Texas 3. May 1965 4. A. 12,750 ft. (abandoned oil test completed as a waste injection well) B. 6,256 - 6,936 ft. C. Tertiary (Miocene) sands 5. Highly mineralized waste water from petrochemical manufacture containing significant amounts of organic nitrogen, nitriles, and other soluble organic chemicals. Weak radioactive waste added in 1966. 6. 600 gpm 7. 450 psi 8. Oral communication, Texas Water Development Board Tx- 21 1. Celanese chemical Company, Bay City Plant 2. 7.5 miles southwest of Bay City, Matagorda County, Texas (see Tx-14) 3. March 1965 4. A. 3,750 B. 3,520 - 3,550 ft. C. Sands of Tertiary (Miocene) age 5. Up to 200 gpm of liquid waste containing organic and inorganic chemicals. Waste derived fr an manufacture of acetaldehyde, adipic acid, butanol and other petrochemicals. 6. 150 gpm 7. 190 psi 8. Written ccimnunication, Texas Water Development Board 40 ------- I A 1. Mobil Oil company 2. Coyanosa area northwest of Fort Stockton, Pecos County, Tcxas 3. 1966 4. A. about 6,250 ft. B. about 5,192 - 6,230 ft. C. Delaware Mountain Group - Sandstones - Permian age 5. About 8,400 gpd of produced brine, boiler blowdown, water- softener regenerator blowdown, and a mine regenerator blowdown and waste chemicals from gas treating plant. Waste flow rate will eventually be 21,000-42,000 gpd. 6. 84,00() gpd (58 gpm) 7. 650-700 psi 8. Written communication, Texas Water Development Board T’ 1. 1:1 Paso Natural Gas Products Company, Odessa Petrochemical Complex (includes an olefin plant, a rubber plant, a butadiene plant, a styrene plant, a polyethylene plant, a chemical plant, a nylon plant, and an oil refinery). 2. 3 miles south of Odessa, Ector County, Texas 3. November 1965 4. A. 5,802 ft. 8. 4 ,900 - 5,800 ft. C. San Andreas Limestone - Limestone - Permian age 5. Up to 1,600,000 gpd (1,100 gpm) cooling-tower and boiler blowdown water, process waste water, washdown water, and rinse and regeneration water from ion exchange units. Chloride 3,000 ppm Bicarbonate i,ooo ppm Sodium z,soo ppm Magnesium 100 ppm Sulfate 1,300 ppm Thtal dissolved solids 8,000 ppm p11 8.5 6. 900 gpm average 1,230 gpm maximum 7. 840 psi average 900 psi maximum 8. Written conmunication, léxas Water Development Board Tx- 24 1. Gulf Oil corporation, Warren Petroleum Corporation, Como Gas Treating, Processing, and Sulfur Recovery Plant 2. (omo Oil Field Area, Hopkins County, Texas 3. May 1965 41 ------- Tx-24 (Continued) 4. A. 5,200 ft. B. 4,940 - 5440 ft. C. Woodbine Group - Sandstone - Cretaceous age 5. Cooling-tower and boiler blowdown water, other plant process waste water, and brine produced from formations other than the Woodbine. 6. 20-50 gpm 7. 310-797 psi 8. Written communication, Texas Water Development Board Tx- 25 1. Shell Oil Company, Northwest Ozona Gas Plant 2. 2 miles northwest of Ozona, Crockett County, Texas 3. May 1965 4. A. 1,750 ft. B. 1,094 - 1,750 ft. C. San Andres Limestone - Limestone - Permian age 5. Cooling-tower blowdown water, process waste water, and zeolite regenerating wash water. Combined waste is largely inorganic salts with traces of hydrocarbons and H 2 S. Total dissolved solids about 3,000 ppm, pH about 9. 6. 6-8 gpm 7. 300 psi 8. Written communication, Texas Water Development Board Tx- 26 1. Amarillo Oil Company, Pampa Gasoline Plant 2. 10 miles south of Pampa, Gray County, Texas 3. 1965 (?) 4. A. 1,000 ft. B. 925 - 1,000 ft. C. Glorietta Formation - Sandstone - Permian age 5. Near saturated brine solution derived during “washing-out” an LPG storage cavern in the Clearfork salt interval at a depth of about 2,000 ft. Total dissolved solids about 270,000 ppm, pH 7.1. Waste production anticipated as 200,000 gpd (139 gpm) during construction of cavity. 6. Total of less than 700,000 barrels of brine in life of project. 7. Up to 300 psi allowable. 8. Written communication, Texas Water Development Board 42 ------- •1• -, 1. Shamrock Oil and Gas corporation, McKee Plant Complex 2. Northeast of I)umas, Moore County, Texas (see Tx-4-6) 3. 19ö5 4. A. 1,620 ft. B. 1,116 - l,23( ft. C. Glorictta Formation - Sandstone - Permian age 5. Cooling-tower and boiler blowdown water and process waste water from oil refinery, gasoline plant, and petrochemical plant. 6. 500 gpm 7. 75 psi 8. Written coulnunication, Texas Water I vclopment Board Tx-28 1. Mobile chemical Company 2. 5 miles northwest of Port Acres, Jefferson County, Texas 3. 1965 4. A. U,000 ft. (plug set at 5,100 ft.) B. 4,690 - 5,016 ft. C. Tertiary sands 5. 104-208 gpm of cooling-tower and boiler blowdown water, water treatment plant blowdown, steam drain water, contaminated storm drainage, and spillage from manufacture of terephtalic acid. Waste includes various organic acids, other hydrocarbons, and inorganic salts. Total dissolved solids 2,000-3,000 ppm, p11 3.0-4.0. U. — 7. 275 psi at 210 gpm during testing 8. Written con1T unication, Texas Water Development Board Tx-29 .1. Shell Chemical Company 2. Deer Park, Texas 3. 1958 4. A. 7,U50 ft. B. 7,152 - 7,533 ft. C. Frio - Sandstone - Tertiary age 5. Waste by-products from manufacture of phenol and waste brine containing 15°c sodium chloride. U. 35 gpm 7. Up to 400 psi 8. I naldson, 1964 43 ------- Tx-30 and Tx-31 1. E. I. DuPont de Nemours and Company, Victoria Plant (see i’x-7-10) 2. 4 miles northwest of Bloomington, Victoria County, Texas 3. 1967 4. A. About 4,200 ft. B. C. Lower Catahoula Sand - Tertiary age 5. 6.t 7. Injection rates and pressure will probably be similar to Tx-7-l0. 8. Written communication, Texas Water I)evelopment Board Tx -32 1 • E. I. DuPont de Nemours and Company 2. 2 miles south-southeast of West Orange, Orange County, Texas 3. 4 4pril 1966 4. A. 5,230 ft. B. 4,550 - 4,660, 4,710 - 4,735 C. Sands of Pliocene - Miocene age 5. Waste water containing 1.0% nitric acid, 2.3% organic acids, and 0.01% heavy metal salts. 6. 340 gpm average 7. 195 psi average 8. Written communication, Texas Water Development Board WVa- 1 1. E. I. DuPont de Nemours and Company 2. Belle, West Virginia 3. Probably late 1967 4. A. 1,500 ft. B. C. Salt sand (Pottsville Group) - Sandstone - Pennsylvanian age 5. Waste containing 15 to 25% NaC1 and CaC].2 and up to 5,000 ppm soluble organic compounds. 6. Expected to be 80 gpm 7. Expected to be 200 psi 8. Written communication, West Virginia Department of Natural Resources Division of Water Resources 44 ------- WVa- 2 1. E. I. I)uPont de Nemours and Company, washington Works 2. Near Parkershurg, West Virginia 3. Not in operation January 1967 4. A. 1,682 plugged back to 1,490 B. 1,334 - 1,448 ft. C. Salt sand (Pottsville Group) - Sandstone - Pennsylvanian age 5. Waste from teflon manufacture containing to 15% hydrochloric acid, 100 ppm hydrofluoric acid, 2 to 5% fomic acid, and up to 10,000 ppm organic chemicals. 6. Lxpectcd to be 100 gpm 7. Expected to he 400 psi 8. Written communication, West Virginia I partmcnt of Natural Resources, flivision of Water Resources I. I. [ )uPont de Nemours and Company 45 ------- |