U.S. ENVIRONMENTAL PROTECTION AGENCY NATIONAL EUTROPHICATION SURVEY WORKING PAPER SERIES REPORT ON SILVER LAKE MCLEOD COUNTY MINNESOTA EPA REGION V WORKING PAPER No, J25 PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY An Associate Laboratory of the NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVALLIS, OREGON and NATIONAL ENVIRONMENTAL RESEARCH CENTER - LAS VEGAS, NEVADA 697.03Z ------- REPORT ON SILVER LAKE MCLEOD COUNTY MINNESOTA EPA REGION V WORKING PAPER No, 125 WITH THE COOPERATION OF THE MINNESOTA POLLUTION CONTROL AGENCY AND THE MINNESOTA NATIONAL GUARD NOVETCER, 1974 ------- •1 CONTENTS P age Foreword List of Minnesota Study Lakes iv, v Lake and Drainage Area Map vi Sections I. Conclusions 1 II. Lake and Drainage Basin Characteristics 3 III. Lake Water Quality Sumary 4 IV. u rient Loadings 8 V. Literature Reviewed 13 VI. Appendices 14 ------- 11 FOREWO RD The National Eutrophication Survey was initiated in 1972 in response to an Administration comniiUnent to investigate the nation- wide threat of accelerated eutrophication to fresh water lakes and reservoirs. OBJECTIVES The Survey was designed to develop, in conjunction with state environmental agencies, information on nutrient sources, concentrations, and impact on selected freshwater lakes as a basis for formulating comprehensive and coordinated national, regional, and state management practices relating to point-source discharge reduction and non-point source pollution abatement in lake watersheds. ANALYTIC APPROACH The mathematical and statistical procedures selected for the Survey’s eutrophication analysis are based on related concepts that: a. A generalized representation or model relating sources, concentrations, and impacts can be constructed. b. By applying measurements of relevant parameters associated with lake degradation, the generalized model can be transformed into an operational representation of a lake, its drainage basin, and related nutrients. c. With such a transformation, an assessment of the potential for eutrophication control can be made. LAKE ANALYSIS In this report, the first stage of evaluation of lake and water- shed data collected from the study lake and its drainage basin is documented. The report is formatted to provide state environmental agencies with specific information for basin planning [ 3O3(e)], water quality criteria/standards review [ 3O3(c)], clean lakes [ 3l4(a,b)], and water quality monitoring [ 1O6 and §305(b)] activities mandated by the Federal Water Pollution Control Act Amendments of 1972. ------- 111 Beyond the single lake analysis, broader based correlations between nutrient concentrations (and loading) and trophic condi- tion are being made to advance the rationale and data base for refinement of nutrient water quality criteria for the Nation’s fresh water lakes. Likewise, multivariate evaluations for the relationships between land use, nutrient export, and trophic condition, by lake class or use, are being developed to assist in the formulation of planning guidelines and policies by EPA and to augment plans implementation by the states. ACKNOWLEDGMENT The staff of the National Eutrophication Survey (Office of Research & Development, U. S. Environmental Protection Agency) expresses sincere appreciation to the Minnesota Pollution Control Agency for professional involvement and to the Minnesota National Guard for conducting the tributary sampling phase of the Survey. Grant J. Merritt, Director of the Minnesota Pollution Control Agency, John F. McGuire, Chief, and Joel G. Schilling, Biologist, of the Section of Surface and Groundwater, Division of Water Quality, provided invaluable lake documentation and counsel during the course of the Survey; and the staff of the Section of Municipal Works, Divi- sion of Water Quality, were most helpful in identifying point sources and soliciting municipal participation in the Survey. Major General Chester J. Moeglein, the Adjutant General of Minnesota, and Project Officer Major Adrian Beltrand, who directed the volunteer efforts of the Minnesota National Guardsmen, are also gratefully acknowledged for their assistance to the Survey. ------- iv NATIONAL EUTROPHICATION SURVEY STUDY LAKES STATE OF MINNESOTA LAKE NAME COUNTY Albert Lea Freeborn Andrusia Beltrami Badger Polk Bartlett Koochiching Bear Freeborn Bemidji Beltrami Big Stearns Big Stone Big Stone, MN; Roberts, Grant, SD Birch Cass Bl ackduck Bel trami Blackhoof Crow Wing Budd Martin Buffalo Wright Calhoun Hennepin Carlos Douglas Carrigan Wright Cass Beltrami, Cass Clearwater Wright, Stearns Cokato Wright Cranberry Crow Wing Darling Douglas Elbow St. Louis Enibarass St. Louis Fall Lake Forest Washington Green Kandiyohi Gull Cass Heron Jackson Leech Cass Le Homme Dieu Douglas Lily Blue Earth Little Grant Lost St. Louis ------- V LAKE NAME COUNTY Madison Mal medal Mas hkenode McQuade Mi nnetonka Mi nnewaska Mud Nest Pelican Pepin Rabbit Sakatah Shagawa Silver Six Mile Spring St. Croix St. Louis Bay Superior Bay Swan Trace Trout Wagonga Wall ma rk White Bear Wi nona Wol f Woodcock Zumbro Blue Earth Pope St. Louis St. Louis Hennepin Pope Itasca Kandiyoh I St. Louis Goodhue, Wabasha, MN; Pierce, Pepin, WI Crow Wing Le Sueur St. Louis McLeod St. Louis Washington, Washington, Pierce, WI St. Louis, St. Louis, Itasca Todd I tas ca Kandiyoh i Chi sago Was hi ngton Douglas Beltrami, Hubbard Kandiyoh i Olmstead, Wabasha Dakota MN; St. C ro ix, MN; Douglas, WI MN; Douglas, WI ------- SILVER LAKE ® Tributary Sampling Site X Lake Sampling Site j Direct Drainage Area Limits O ‘?Mi. Map Location ( C) 4A1 ) .- ..-..-... Scale ( ii / ------- SILVER LAKE STORET NO. 2782 I. CONCLUSIONS A. Trophic Condition: Survey data and the reports of others show that Silver Lake is eutrophic. Survey limnologists noted that the lake was ex- tremely turbid on all sampling dates (due in large part to the number of phytoplankton present; see page 6). In a 1952 report on a waterfowl and muskrat habitat survey, Minnesota Department of Conservation biologists noted that heavy algal growths were present (Johnson, 1952). Of the 60 Minnesota lakes sampled in the fall when essen- tially all were well-mixed, 48 had less mean total phosphorus, 43 had less mean dissolved phosphorus, and 38 had less mean inorganic nitrogen. For all 80 lakes sampled, 91% had less mean chlorophyll a, and 95% had greater mean Secchi disc trans- pa ren cy. Because of the inorphornetry of this water body, it is unlikely that it would be considered anything but eutrophic regardless of cultural influences. The primary beneficial use of the lake has been as waterfowl and game habitat. B. Rate-Limiting Nutrient: The results of the algal assay indicate Silver Lake was nitrogen limited at the time the sample was collected. Lake data indicate nitrogen limitation at all sampling times. ------- 2 C. Nutrient Controllability: During the sampling year, Silver Lake received a total phosphorus load at a rate about four times the rate proposed by Vollenweider (in press) as “dangerous”; i.e., a eutrophic rate (see page 12). Of this load, it is estimated that the Village of Silver Lake contributed 87%. It is calculated that 80% removal of phosphorus at Silver Lake would result in a loading rate of 1.4 lbs/acre/yr or 0.16 g/m 2 /yr (the eutrophic rate is 0.14 g/m 2 /yr). While the reduced loading rate resulting from 80% phosphorus removal would just exceed the eutrophic rate, it is concluded that such a level of removal would improve the trophic condition of the lake and would significantly enhance the waterfowl and game habitat potential of Silver Lake. ------- 3 II. LAKE AND DRAINAGE BASIN CHARACTERISTICS A. Lake Morphometry*: 1. Surface area: 422 acres. 2. Mean depth: 4 feet. 3. Maximum depth: 7 feet. 4. Volume: 1,688 acre/feet. 5. Mean hydraulic retention time: 2.3 years. B. Tributary and Outlet: (See Appendix A for flow data) 1. Tributaries — Name Drainage areat Mean flowt None Minor tributaries & 2 immediate drainage - 1.5 mi 1.0 cfs Totals 1.5 mi 2 1.0 cfs 2. Outlet — .2tf 1.0 cfs Silver Lake Creek 2.2 nu C. Preci pitationttt: 1. Year of sampling: 32.9 inches. 2. Mean annual : 27.0 inches. * Anonymous, 1972. t Drainage areas are accurate within ±5%; mean daily flows are accurate within ±10%; and ungaged flows are accurate within ±10 to 25% for drainage areas greater than 10 mi 2 . tt Includes area of lake. ttt See Working Paper No. 1 , uSurvey Methods”. ------- 4 III LAKE WATER QUALITY SUI44ARY Silver Lake was sampled three times during the open—water season of 1972 by means of a pontoon-equipped Huey helicopter. Each time, samples for physical and chemical parameters were collected from one station on the lake and from one or n re depths (see map, page vi). During each visit, a single depth-integrated (near bottom to surface) sample was collected for phytoplankton identification and enumeration; and during the last visit, a single five-gallon depth-integrated sample was taken for algal assays. Also each time, a depth-integrated sample was collected for chlorophyll a analysis. The maximum depth sampled was 4 feet. The results obtained are presented in full in Appendix B, and the data for the fall sampling period, when the lake was essentially well- mixed, are summarized below. Note, however, the Secchi disc suiiniary is based on all values. For differences in the various parameters at the other sampling times, refer to Appendix B. ------- 5 A. Physical and chemical characteristics: FALL VALUES Parameter Minimum Mean Median Maximum Temperature (Cent.) 4.9 4.9 4.9 4.9 Dissolved oxygen (mg/i) 10.3 10.3 10.3 10.3 Conductivity ( ..imhos) 500 500 500 500 pH (units) 8.9 8.9 8.9 8.9 Alkalinity (mg/i) 186 188 188 189 Total P (mg/i) 0.284 0.310 0.310 0.336 Dissolved P (mg/i) 0.123 0.126 0.126 0.130 NO + NO (mg/i) 0.110 0.120 0.120 0.130 Arr onia mg/1) 0.250 0.255 0.255 0.260 ALL VALUES Secchi disc (inches) 6 10 12 ------- 6 B. Biological characteristics: 1 . Phytoplankton - Sampling Dominant Number Date Genera per nfl 07/03/72 1. Microcystis 29,189 2. Anabaena 21 ,982 3. Lyngbya 11,622 4. Merlsiropedia 7,387 5. Chroococcus 3,514 Other genera 9,099 Total 82,793 08/29/72 1. Oscillatoria 26,727 2. Lyngbya 22,727 3. Merisnopedia 9,091 4. Microcystis 5,636 5. Flagellates 4,909 Other genera 9 ,637 Total 78,727 10/26/72 1. Oscillatoria 25,714 2. Flagellates 8,797 3. Microcystis 2,256 4. Anabaena 526 5. Dinobryon 526 Other genera j 73O Total 39,549 ------- 7 Maximum yield ( mg/i-dry wt. ) 25.9 28.2 25.0 25.8 22.2 46.4 39.4 Chlorophyll a gJ1) - C. Limi 1. 2. Chlorophyll a- (Because of instrumentation problems during the 1972 sampling, the following values may be in error by plus or minus 20 percent.) Sampling Station Date Number ______________ 07/03/72 01 277.8 08/29/72 01 48.9 10/26/72 01 51.6 ting Nutrient Study: Autoclaved, filtered, and nutrient spiked - Ortho P Inorganic N pjke (mg/i) Conc. (mg/i) Conc. (mq/1 ) _____________ Control 0.066 0.864 0.005 P 0.071 0.864 0.010 P 0.076 0.864 0.020 P 0.086 0.864 0.050 P 0.116 0.864 0.050 P + 10.0 N 0.116 10.864 10.0 N 0.066 10.864 2. Discussion — The control yield of the assay alga, Selenastrum capri- cornutum , indicates that the potential primary productivity of Silver Lake was very high when the sample was taken. Also, the lack of significant change in yields with increased levels of orthophosphate, and the response to the addition of nitrogen alone, show that the lake was nitrogen limited. The lake data indicate nitrogen limitation at all sampling times (all N/P ratios were less than 3/1, and nitrogen limi- tation would be expected). ------- 8 IV. NUTRIENT LOADINGS (See Appendix C for data) For the determination of nutrient loadings, the Minnesota National Guard collected monthly near-surface grab samples from the tributary site indicated on the map (page vi), except for the colder months when ice cover and low flows prevented sampling. Sampling was begun in October, 1972, and was completed in September, 1973. Through an interagency agreement, stream flow estimates for the year of sampling and a “normalized” or average year were provided by the Minnesota District Office of the U.S. Geological Survey for the lake outlet. In this report, outlet nutrient loads were determined by using a modification of a U.S. Geological Survey computer program for calcu- lating stream loadings. Nutrient loadings for unsampled “minor tribu- taries and immediate drainage” (“ZZ” of U.S.G.S.) were estimated by using the nutrient loads, in lbs/mi 2 /year, in an unimpacted tributary of nearby Cokato Lake at station 2719C1 (126 lbs P and 2,924 lbs N/mi 2 /yr) and multiplying by the ZZ area in mi 2 . The Village of Silver Lake declined participation in the Survey, and nutrient loads were estimated at 2.5 lbs P and 7.5 lbs N/capita/year. ------- 9 A. Waste Sources: 1 . Known municipal - Pop. Mean Receiving Name Served Treatment Flow (mgd) Water Silver Lake 694* trickling O.070** Silver Lake filter 2. Known industrial — None * Anoymous, 1973. ** Estimated at 100 gal/capita/day. ------- 10 B. Annual Total Phosphorus Loading - Average Year: 1 . Inputs — lbs P1 % of Source yr total a. Tributaries (non—point load) — None b. Minor tributaries & immediate drainage (non-point load) — 190 9.5 c. Known municipal - Silver Lake 1,740 87.0 d. Septic tanks - Unknown e. Known industrial — None - - f. Direct preclpitation* - 70 3.5 Total 2,000 100.0 2. Outputs — Lake outlet — Silver Lake 1,460 3. Net annual P accumulation — 540 pounds * See Working Paper No. 1. ------- 11 C. Annual Total Nitrogen Loading - Average Year: 1. Inputs — lbsN/ %Of Source yr total a. Tributaries (non—point load) - None b. Minor tributaries & iniiiediate drainage (non—point load) - 4,390 32.1 c. Known municipal — Silver Lake 5,200 38.1 d. Septic tanks - Unknown e. Known industrial - None f. Direct precipitation* - 4,070 29.8 Total 13,660 100.0 2. Outputs - Lake outlet - Silver Lake Creek 9,350 3. Net annual N accumulation - 4,310 pounds * See Working Paper No. 1. ------- 12 E. Yearly Loading Rates: In the following table, the existing phosphorus loading rates are compared to those proposed by Vollenweider (in press). Essentially, his “dangerous” rate is the rate at which the receiving waters would become eutrophic or remain eutrophic; his “permissible” rate is that which would result in the receiving water remaining oligotrophic or becoming oligotrophic if morphometry permitted. A rnesotrophic rate would be considered one between “dangerous” and “permissible”. Total Phosphorus Total Nitrogen Units Total Accumulated Total Accumulated 1bs/acr /yr 4.7 1.3 32.4 10.2 grams/rn /yr 0.53 0.14 3.6 1.1 Vollenweider loading rates for phosphorus (g/m 2 /yr) based on mean depth and mean hydraulic retention time of Silver Lake: “Dangerous” (eutrophic rate) 0.14 “Permissible” (oligotrophic rate) 0.07 ------- 13 V. LITERATURE REVIEWED AnonynDus, 1972. Survey questionnaire. MPCA, Minneapolis. Anonymous, 1973. Wastewater disposal facilities inventory. MPCA, Minneapolis. Johnson, Clare L., 1952. Waterfowl arid muskrat habitat survey-- Silver Lake, McLeod County. MN Dept. of Conservation, St. Paul. Schilling, Joel, 1974. Personal comunication (map and report). MPCA, Minneapolis. Vollenweider, Richard A., (in press). Input-output models. Schweiz. A. Hydrol. ------- VII. APPENDICES APPENDIX A TRIBUTARY FLOW DATA ------- IRIH(’TA9Y FLOW INFORMATION FOR MINNESOTA 10/30/74 LAKE CODE 278? SILVER IA’(E TOTAL F ’ AINAGE AP ft OF LAKE 5(JR—D RAINAI,E NORMALIZED FLOWS TPIRIJTA9Y APFA JAN FEN MAW ARM MAY JUN JUL AUG SEP OCT NOV DEC MEAN ?78?AI 7.1R 0.14 •‘() 0.41 1.15 2.27 2.73 1.81 0.73 1.41 0.46 0.30 0.33 1.02 ?78?Z7 2. 1W 0.43 0.24 0.5? 1.12 2.15 2.75 1.73 0.66 1.34 0.41 0.27 0.38 1.00 SUMMARY TOTAL DRAINAr,E AREA OF LAKE = 2.18 TOTAL FLOW IN = 12.00 SUM OF SUN—OPAINAGE AREAS = 2.18 TOTAL FLOW OUT = 12.16 MEAN MONTHLY FLOWS AND u)AILY FlOWS TRIROTAPY MONIr4 YEAR UEAN FLOW •)AY FLOW DAY FLOW DAY FLOW 278261 0 7? 1.24 15 1.20 II 77 I.?Q 1 1.50 1’ 7 ? I 71 I. ?’ 9 1.00 2 71 0.55 Il 1.30 1 73 1.70 28 2.50 4 73 ?.04 15 2.20 5 73 2.50 ?5 2.90 73 1.77 2 2.90 12 2.00 7 71 0. ’ 13 0.58 N 71 0. 6 11 0.50 9 73 0.73 778277 10 77 1.1 15 1.00 II 7? 1.14 19 1.10 I ? 7’ 1 71 l. 5 9 1.30 2 71 0.66 II 1.5’) 1 71 ?. 5 28 3.00 4 71 I.°8 15 2.10 5 71 ?.16 25 2.70 5 71 1.7 2 3.00 I? 2.00 7 73 0.50 13 0.56 H 71 0.51 11 0.45 9 7 0.13 ------- APPENDIX B PHYSICAL and CHEMICAL DATA ------- ST RET TPTEVAL DATE 74/ Ifl/30 278201 44 53 54.0 094 12 00.0 SILVER LAKE 27 MINNESOTA 1 IEPALES 2111202 3 0007 FEET DEPTH 00013 00300 00077 00094 00400 00410 00630 00610 00665 00666 DATE TIME 1W’ TI-4 WATER DO TRANSP CNOUCTVY PH 1 ALK N02&N03 NH3—N PHOS—TOT PHOS—DIS FROM OF TEUP SECCHI FIELD CACO3 N—TOTAL TOTAL TO DAY FEET CENT MG/L INCHES MICROMHO SU MG/L MG/L MG/L MG/I P MG/L P 7?f07/O3 17 40 000’) 23.) 9.5 12 410 9.00 173 0.140 0.130 0.600 0.310 7?/08#’29 18 09 0000 460 9.05 181 0.010K 0.070 0.690 0.700 18 09 0004 21.0 5.? 480 8.65 186 0.130 0.240 0.790 0.463 72/10/2 ’ 10 00 0000 1? 500 8.90 186 0.110 0.250 0.284 0.123 10 00 0004 4.9 10.3 500 8.90 189 0.130 0.260 0.336 0.130 3 717 DATE TIMF DE°TH C,-4L’ PI1YL FROM OF A TO DAY FEET IIG/L 72/07/03 17 40 0000 ‘77. J 72/08/29 18 09 0000 4 •QJ 7?/10/ )0 00 0000 j V LLIV .( tO. t T - I K VALUE KNOWN TO BE LESS TrIAN INDICATED ------- APPENDIX C TRIBUTARY DATA ------- STOPET RETRIEVAL D4T 74/10/30 2782A1 LS2782A1 44 53 00.0 094 13 00.0 UNNAMED OUTLET OF SILVER LAKE 27083 Co #43 O/SILVEi LAKE CO HWY 24 1 MI S .25 M I E SILVER LAKE 1 1EPALES 2111204 4 0000 FEET DEPTH 00630 00675 00610 00671 00665 DATE TIME OE TH t’1O2&NO1 TOT KJEL NH3—N PHOS—DIS PHOS—TOT FROM OF N-TOTAL N TOTAL ORTHO TO DAY FEET MG/L MG/L MG/L MG/L P MG/L P 72/10/15 15 00 0.890 2.500 0.210 0.210 0.315 72/i1/IQ 14 00 1.110 4.000 0.350 0.220 0.690 73/03/11 14 10 4.000 3.570 0.830 0.294 0.490 73/03/28 06 40 0.078 1.890 0.048 0.147 0.240 73/04/15 14 45 0.140 3.700 0.054 0.138 0.340 73/05/25 14 20 0.252 4.500 0.105 0.660 0.800 73/06/0? 14 30 0.270 2.800 0.068 0.650 0.820 73/07/13 16 50 0.430 4.400 0.710 1.100 1.300 73/08/11 14 40 O.8’ O 6.800 1.800 1.000 1.570 ------- sTOPET P r Fv ‘)AI ’ 74/10/30 278 51 TF278251 P000694 ‘i’. 57 00.0 094 13 00.0 SILVER LAKE 270Mg Co W43 0/SILVER LAKE SILVEP LAKE 1 IEPALES 2141204 4 0000 FEET DEPTH ‘ ‘)A1 1 O06 5 0)f’ IO 00671 00665 50051 50053 DATE T!Mr ‘)EPT-I ‘ O’ IO1 11)1 KJ L Nrtl—N P1-lOS-OhS l-’HOS--TOT FLOW CONDUIT FROM OF 1 -1—Tt)TAL N TOTAL OPTr-$O RATE FL0W4460 TO ThY FFET M(,/L 1(/L MG/L MG/L P N&/L P INST MGD MONTHLY 73/01/15 11 00 C {T)— ‘- -‘ 19.100 16.001) 71/0I/1 ’- 13 00 71/1)?/1S 11 00 CP(T} 3.1-), 6 5.uOO 7.000 7.100 13.500 71,fl?/I I I 00 71/03/1 It 01) CP(T ) 3.0)u ‘.‘1’)O 1.900 .4OO 4 . (0Q 71/03/1 5 13 10 73/04/16 11 10 1. ) ? • 0 ?.HOO 2. OO 5.000 71/O5/1 it no CP(T)— ‘ 1.1 5 43• 100 10.400 ‘..600 - 1.500 73/05/IS 13 1)0 71/06/IS Ii 0’) CP(T)— (‘.170 45.000 15.700 5.300 ‘i. 00 71/06/IS ii ‘ 0 7l/07/I’ 11 00 CPU)— 3.143 4P.)0O ?3.500 4.900 R.500 71/07/16 ‘3 1{j 71/OR/IS 11 ‘10 CP(T)— .01) 71.)OU ‘, .S 01) 4.100 11.500 71/OP/iS 1’ Of) 73/09/1w II CPU)— ... 0 29.400 11.500 5.900 7.000 71/09/17 11 00 71/10/1 11 00 CPU)— ‘.‘,Cii 1’.’-J’ 3.? 0 1.700 3.150 71/10/iS I l 111) 73/11/iS Ii CPU)— ( .?‘iI 3ô.C0U 14.000 2.900 .9on 7l/lI/1 Ii 00 71/17/17 11 co CPU)— 0.4’ .o ?4.’MO S. fl0 3. 151) b.000 73/17/17 1? 31 76/01/17 II ‘10 fP(T)— i.I’ ?i.”’v 1S. o0 6.600 ‘ 4.100 74/0 1/17 I I 00 ------- |