U.S. ENVIRONMENTAL PROTECTION AGENCY NATIONAL EUTROPHICATION SURVEY WORKING PAPER SERIES REPORT ON WOLF LAKE BELTRAMI AND HUBBARD COUNTIES MINNESOTA EPA REGION V WORKING PAPER No, J36 PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY An Associate Laboratory of the NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVALLIS, OREGON and NATIONAL ENVIRONMENTAL RESEARCH CENTER - LAS VEGAS, NEVADA 697-032 ------- REPORT ON WOLF LAKE BELTRAMI AND HUBBARD COUNTIES MINNESOTA EPA REGION V WORKING PAPER No, 136 WITH THE COOPERATION OF THE MINNESOTA POLLUTION CONTROL AGENCY AND THE MINNESOTA NATIONAL GUARD NOVEMBER, 1974 ------- 1 CONTENTS Page Foreword ii List of Minnesota Study Lakes iv, v Lake and Drainage Area Maps vi , vii Sections I. Conclusions 1 II. Lake and Drainage Basin Characteristics 4 III. Lake Water Quality Summary 5 IV. Nutrient Loadings 10 V. Literature Reviewed 15 VI. Appendices 16 ------- ii FOREWORD The National Eutrophication Survey was initiated in 1972 in response to an Administration commitment to investigate the nation- wide threat of accelerated eutrophication to fresh water lakes and reservoirs. OBJECTIVES The Survey was designed to develop, in conjunction with state environmental agencies, information on nutrient sources, concentrations, and impact on selected freshwater lakes as a basis for formulating comprehensive and coordinated national, regional , and state management practices relating to point-source discharge reduction and non—point source pollution abatement in lake watersheds. ANALYTIC APPROACH The mathematical and statistical procedures selected for the Survey’s eutrophication analysis are based on related concepts that: a. A generalized representation or model relating sources, concentrations, and impacts can be constructed. b. By applying measurements of relevant parameters associated with lake degradation, the generalized model can be transformed into an operational representation of a lake, its drainage basin, and related nutrients. c. With such a transformation, an assessment of the potential for eutrophication control can be made. LAKE ANALYSIS In this report, the first stage of evaluation of lake and water- shed data collected from the study lake and its drainage basin is documented. The report is formatted to provide state environmental agencies with specific information for basin planning [ 3O3(e)], water quality criteria/standards review [ 3O3(c)], clean lakes [ 3l4(a,b)], and water quality monitoring [ 1O6 and §305(b)] activities mandated by the Federal Water Pollution Control Act Amendments of 1972. ------- 111 Beyond the single lake analysis, broader based correlations between nutrient concentrations (and loading) and trophic condi- tion are being made to advance the rationale and data base for refinement of nutrient water quality criteria for the Nation’s fresh water lakes. Likewise, multivariate evaluations for the relationships between land use, nutrient export, and trophic condition, by lake class or use, are being developed to assist in the formulation of planning guidelines and policies by EPA and to augment plans implementation by the states. ACKNOWLEDGMENT The staff of the National Eutrophication Survey (Office of Research & Development, U 0 S. Environmental Protection Agency) expresses sincere appreciation to the Minnesota Pollution Control Agency for professional involvement and to the Minnesota National Guard for conducting the tributary sampling phase of the Survey. Grant J. Merritt, Director of the Minnesota Pollution Control Agency, John F. McGuire, Chief, and Joel G. Schilling, Biologist, of the Section of Surface and Groundwater, Division of Water Quality, provided invaluable lake documentation and counsel during the course of the Survey; and the staff of the Section of Municipal Works, Divi- sion of Water Quality, were most helpful in identifying point sources and soliciting municipal participation in the Survey. Major General Chester J. Moeglein, the Adjutant General of Minnesota, and Project Officer Major Adrian Beltrand, who directed the volunteer efforts of the Minnesota National Guardsmen, are also gratefully acknowledged for their assistance to the Survey. ------- iv NATIONAL EUTROPHICATION SURVEY STUDY LAKES STATE OF MINNESOTA LAKE NAME COUNTY Albert Lea Freeborn Andrusia Beltrami Badger Polk Bartlett Koochiching Bear Freeborn Bemidji Beltrami Big Stearns Big Stone Big Stone, MN; Roberts, Grant, SD Birch Cass Bl ackduck Bel trami Blackhoof Crow Wing Budd Martin Buffalo Wright Calhoun Hennepin Carlos Douglas Carrigan Wright Cass Beltrami, Cass Clearwater Wright, Stearns Cokato Wright Cranberry Crow Wing Darling Douglas Elbow St. Louis Embarass St. Louis Fall Lake Forest Washington Green Kandiyohi Gull Cass Heron Jackson Leech Cass Le Homme Dieu Douglas Lily Blue Earth Little Grant Lost St. Louis ------- V LAKE NAME COUNTY Madison Blue Earth Malmedal Pope Mashkenode St. Louis McQuade St. Louis Minnetonka Hennepin Minnewaska Pope Mud Itasca Nest Kandiyohi Pelican st. Louis Pepin Goodhue, Wabasha, MN; Pierce, Pepin, WI Rabbit Crow Wing Sakatah Le Sueur Shagawa St. Louis Silver McLeod Six Mile st. Louis Spring Washington, Dakota St. Croix Washington, MN; St. Croix, Pierce, WI St. Louis Bay st. Louis, MN; Douglas, WI Superior Bay st. Louis, MN; Douglas, WI Swan Itasca Trace Todd Trout Itasca Wagoriga Kandiyohi Walimark Chisago White Bear Washington Winona Douglas Wolf Beltrami, Hubbard Woodcock Kandiyohi Zumbro Olmstead, Wabasha ------- 940 4 Map Location Lav nia Q WOL. LAKE 274 BEMIDJI, WOLF, ANDRUSIA CASS LAKES Tributary Sampling Site Lake Sampling Site Sewage Treatment Facility ------- II.. , I.inId I 2 Map Location WOL LAKE )01 WOLF Tributary Sampling Si Lake Sampling Site vii ------- WOLF LAKE STORET NO. 27A2 I. CONCLUSIONS A. Trophic Condition: Survey data and the records of others (Lang, et al., 1969) show that Wolf Lake is eutrophic. Of the 60 Minnesota lakes sampled in the fall when essentially all were well-mixed, 35 had less mean total phosphorus, 29 had less mean dissolved phosphorus, but only six had less mean inorganic nitrogen. Of the 80 lakes studied, 55% had less mean chlorophyll a, and 49% had greater Secchi disc transparency. Marked depression of dissolved oxygen with depth occurred during the July sampling. Wolf Lake has been chemically treated a number of times for control of rooted aquatic vegetation and filamentous algae (Bonnema and Johnson, 1972). B. Rate-Limiting Nutrient: Algal assay results show nitrogen limitation at the time the sample was collected in October, 1972. The lake data indicate nitrogen limitation at the other sampling times as well. C. Nutrient Controllability: 1. Point sources—-The phosphorus removal facilities planned for the Bemidji wastewater treatment plant will meet ------- 2 a mean effluent limit of 1 mg/i (Schilling, 1974). When operational, these facilities will reduce the total phosphorus load to Wolf Lake by about 44%. This will reduce the loading rate from the present 57 lbs/acre/yr (6.4 g/m 2 /yr) to 32 lbs/ acre/yr or 3.6 g/m 2 /yr. The 3.6 g/m 2 /yr rate is still about twice the rate proposed by Vollenweider (in press) as a dangerous or eutrophic rate (see page 14). However, because of the proximity of the Wolf Lake outlet to the inlet (see map, page vii), it is believed a sub- stantial degree of short—circuiting of nutrients occurs; i.e., under most flow conditions, it is probable that much of the incoming water (with nutrients) flows more or less directly to the outlet. Note that only 12% of the phosphorus load and none of the nitrogen load was retained in the lake during the year. It is concluded that the degree of phosphorus removal to be instituted at the Bemidji waste treatment plant will result in improvement of the trophic condition of Wolf Lake. 2. Non-point sources-—It is noted that the total phosphorus load measured at the Wolf Lake inlet station (27A2A1) was about 26% greater than can be accounted for by upstream loads. During the year, the Bemidji STP discharged 29,720 lbs of phosphorus, and 16,290 lbs were measured in the Lake Bemidji outlet for a ------- total of 46,020 Ibs. Add to this the 1,520 Ibs expected from areal sources between the Lake Bemidj'1 outlet and the Wolf Lake inlet (38 mi2 at 40 Ibs/mi2/yr [the rate measured at the Lake Bemidji inlet]), and the expected load at the Wolf Lake inlet would be 47,540 Ibs for the year. However, the load measured at the Wolf Lake inlet was 59,710 Ibs of phosphorus or about 12,000 Ibs more than expected. Personnel of the Minnesota Pollution Control Agency know of no intervening point sources or nutrient sources such as feedlots, but they report an 8- to 12-foot fluctuation in water level at the Otter Tail Power Company hydroelectric dam at station 2715A3 (Schilling, op. cit.). This fluctuation may have resulted in resolubilization of previously sedimented phosphorus and thus the excess load at the Wolf Lake inlet station. The phosphorus exports in the Wolf Lake drainage were very similar to those of the drainages of the other lakes in this upper Mississippi River chain of lakes. The relatively low ex- ports probably result from the near-headwaters location of the lakes as well as land-use practices in this largely-forested area of Minnesota. In all, it is estimated that non-point sources contributed about 51% of the total phosphorus load reaching Wolf Lake during the sampling year. ------- 4 II. LAKE AND DRAINAGE BASIN CHARACTERISTICS A. Lake MorphometrY : 1. Surface area: 1,051 acres. 2. Mean depth: 28 feet. 3. Maximum depth: 58 feet. 4. Volume: 29,428 acre/feet. 5. Mean hydraulic retention time: 37 days. B. Tributary and Outlet: (See Appendix A for flow data) 1. Tributaries - Name Drainage area* Mean flow* Mississippi River 668.0 mi 2 396.2 cfs Little Wolf Lake outlet 10.7 mi 2 5.8 cfs Mud Lake outlet 0.6 mi 2 0.3 cfs Miri or tributaries & 2 immediate drainage - 4.8 ml 2.2 cfs Totals 684.0 mi 2 ** 404.5 cfs 2. Outlet - Mississippi River 684.0 mi 2 404.5 cfs C. PrecipitatiOfl*** 1. Year of sampling: 26.7 inches. 2. Mean annual: 23.8 inches. t DNR lake survey map (1941); mean depth by random-dot method. * Drainage areas are accurate within ±5%; mean daily flow are accurate within ±10%; and ungaged flows are accurate within ±10 to 25% for drainage areas greater than 10 mid. ** Includes area of lake. *** See Working Paper No. 1, “Survey Methods”. ------- 5 III. LAKE WATER QUALITY SUMMARY Wolf Lake, one of a chain of upper Mississippi River lakes (see map, page vi), was sampled three times during the open-water season of 1972 by means of a pontoon-equipped Huey helicopter. Each time, samples for physical and chemical parameters were collected from a number of depths at the one station on the lake (see map, page vii). During each visit two depth-integrated (15 feet to surface) samples were collected for phytoplankton identification and enumeration and for chlorophyll a analysis; and during the last visit, a single five-gallon depth-integrated sample was collected for alqal assays. The maximum depth sampled was 28 feet. The results obtained are presented in full in Appendix B, and the data for the fall sampling period, when the lake was essentially well-mixed, are summarized below. Note, however, the Secchi disc summary is based on all values. For differences in the various parameters at the other sampling times, refer to Appendix B. ------- 6 A. Physical and chemical characteristics: FALL VALUES (10/21/72) Parameter Minimum Mean Median Maximum Temperature (Cent.) 6.1 6.2 6.3 6.3 Dissolved oxygen (mgll) 10.0 10.7 10.2 12.0 Conductivity ( mhos) 248 251 248 260 pH (units) 8.3 8.3 8.3 8.3 Alkalinity (mg/i) 143 146 146 147 Total P (mg/l) 0.050 0.063 0.061 0.080 Dissolved P (mg/i) 0.02i 0.026 0.025 0.034 NO + NO (mg/i) 0.020 0.032 0.030 0.050 Am onia mg/l) 0.040 0.052 0.055 0.060 ALL VALUES Secchi disc (inches) 33 47 60 ------- 7 B. Biological characteristics: 1. Phytoplankton — Sampling Dominant Number Date Genera per ml 07/11/72 1. Aphanotheca 8,986 2. Dinobryon 399 3. Anabaena 181 4. Fragilaria 109 5. Tabellaria 36 Other genera 72 Total 9,783 09/08/72 1. Anabaena 987 2. Microcystis 475 3. Flagellates 264 4. Oscillatoria 158 5. Melosira 128 Other genera 656 Total 2,668 10/21/72 1. Melosira 8,163 2. Fragilaria 1,566 3. Anabaena 1 ,144 4. Stephanodiscus 361 5. Flagellates 361 Other genera 935 Total 12,530 ------- 8 2. Chlorophyll a - (Because of instrumentation problems during the 1972 sampling, the following values may be in error by plus or minus 20 percent.) Sampling Station Chlorophyll a Date Number ( pg/i ) 07/11/72 01 09/08/72 01 10/21/72 01 25.8 C. Limiting Nutrient Study: 1. Autociaved, filtered, and nutrient spiked - Ortho P Inorganic N - . Conc. (mg/i) Conc. (mg/i ) _____________ 0.022 0.056 0.027 0.056 0.032 0.056 0.042 0.056 0.072 0.056 0.072 10.056 0.022 0.056 13.0 12.7 Maximum yield Spike (mg/i ) ___________ ___________ ( mg/i—dry wt. ) Control 1 .6 0.005 P 2.0 0.010 P 2.1 0.020 P 1.9 0.050 P 2.3 0.050 P + 10.0 N 26.4 ‘10.0 N” 1.7 2. Discussion — The control yield of the assay alga, Selenastrum capri- cornutum , indicates that the potential primary productivity was moderate at the time the sample was collected; however, there was a loss of 51 pg/i of inorganic nitrogen and 21 pg/i of dissolved phosphorus between the time the sample was collected and the assay was begun. Had this loss not occurred, the expected control yield would have been about 3 mg/i. ------- 9 The lack of significant yield response to increasing levels of orthophosphorus until nitrogen was also added shows that the lake was nitrogen limited when sampled. Through an oversight, rio nitrogen was added to the “10.0 N” flasks; and, therefore, the yield was the same as the control. The lake data indicate nitrogen limitation at all sampling times (the July N/P = 9/1; the September N/P = 12/1; and the October N/P = 3/1). ------- 10 IV. NUTRIENT LOADINGS (See Appendix C for data) For the determination of nutrient loadings, from October, 1972 through September, 1973, the Minnesota National Guard collected monthly near—surface grab samples from each of the tributary sites indicated on the map (page vii), except for the high runoff month of April, when two samples were collected, and the colder months when samples were omitted at most stations because of low flows. Through an interagency agreement, stream flow estimates for the year of sampling and a “normalized” or average year were provided by the Minne- sota District Office of the U.S. Geological Survey for the tributary sites nearest the lake. In this report, nutrient loads for sampled tributaries were determined by using a modification of a U.S. Geological Survey computer program for calculating stream loadings*. Nutrient loadings for unsampied “minor tributaries and immediate drainage” (“ZZ” of U.S.G.S.) were estimated by using the means of the nutrient loads, in ibs/mi 2 /year, in tributaries of nearby Leech Lake at stations 2746C-1 , D-l , F—i , G—i , H—l , and J-l and multiplying the means by the ZZ area in m1 2 . The operator of the Bemidji wastewater treatment plant provided monthly effluent samples and corresponding flow data. In this report it is assumed that all of the nutrients discharged at the Bemidji plant reached Wolf Lake. In the loading tables that follow, the loads attributed to the Mississ- ippi River inlet are those measured at station A—i minus the Bemidji loads (but see discussion on pages 2 and 3). * See Working Paper No. 1. ------- 11 A. Waste Sources: Known municipal - Pop. Mean Receiving Name Served* Treatment Flow (mgd) Water Bemidji 11,400 trickling 0.942 Mississippi filter River 2. Known industrial — None * 1970 Census. ------- 12 B. Annual Total Phosphorus Loading — Average Year: 1. Inputs — lbsP/ %of Source yr total a. Tributaries (non-point load) Mississippi River 29,980 49.7 Little Wolf Lake outlet 220 0.4 Mud Lake outlet 10 <0.1 b. Minor tributaries & immediate drainage (non-point load) — 130 0.2 c. Known municipal - Bemidji 29,730 49.3 d. Septic tanks* - 80 0.1 e. Known industrial - None - - f. Direct precipitation** - 160 0.3 Total 60,310 100.0 2. Outputs - Lake outlet - Mississippi River 52,790 3. Net annual P accumulation - 7,520 pounds * Estimated 74 dwellings, 4 resorts, and 1 camp on shoreline; see Working Paper No. 1. ** See Working Paper No. 1. ------- 13 C. Annual Total Nitrogen Loading - Average Year: 1. Inputs — lbs N/ % of Source yr total a. Tributaries (non-point load) Mississippi River 433,020 76.5 Little Wolf Lake outlet 8,320 1.5 Mud Lake outlet 600 0.1 b. Minor tributaries & immediate drainage (non-point load) - 6,000 1.1 c. Known municipal - Bemidji 105,010 18.6 d. Septic tanks* - 2,800 0.5 e. Known industrial - None - f. Direct precipitation** - 10,130 1.7 Total 565,880 100.0 2. Outputs - Lake outlet - Mississippi River 733,380 3. Net annual N loss - 167,500 pounds * Estimated 74 dwellings, 4 resorts, and 1 camp on shoreline; see Working Paper No. 1. ** See Working Paper No. 1. ------- 14 D. Mean Annual Non-point Nutrient Export by Sub-drainage Area: Tributary lbs P/mi 2 /yr lbs N/m1 2 /yr Mississippi River inlet 45 648 Little Wolf Lake outlet 21 778 Mud Lake outlet 17 1,000 E. Yearly Loading Rates: In the fol1owin j table, the existing phosphorus loading rates are compared to those proposed by Vollenweider (in press). Essentially, his “dangerous” rate is the rate at which the receiving waters would become eutrophic or remain eutrophic; his permissib1e rate is that which would result in the receiving water remaining oligotrophic or becoming oligo- trophic if morphometry permitted. A mesotrophic rate would be considered one between “dangerous” and “permissible”. Total Phosphorus Total Nitrogen Units Total Accumulated Total Accumulated 1bs/acr /yr 57.4 7.2 538.4 loss* grams/me/yr 6.43 0.80 60.3 - Vollenweider loading rates for phosphorus (g/m 2 /yr) based on mean depth and mean hydraulic retention time of Wolf Lake: “Dangerous” (eutrophic rate) 1.76 “Permissible” (oligotrophic rate) 0.88 * The apparent loss of nitrogen during the sampling year may have resulted from nitrogen fixation in the lake, solubilization of previously sedimented nitrogen, recharge with nitrogen-rich ground water, or insufficient samp- ling. However, a similar nitrogen loss has been observed at Shagawa Lake which has been studied intensively by EPA’s Eutrophication Research and Lake Restoration Branch. ------- 15 V. LITERATURE REVIEWED Anonymous, 1973. Wastewater disposal facilities inventory. MPCA, Minneapolis. Bonnema, Kenneth, and William G. Johnson, 1972. Control of aquatic vegetation, algae, leeches and swimmer’s itch in 1971. MN Dept. Nat. Resources, St. Paul. Hoekstra, Donald J., 1968. Nitrogen and phosphorus analysis of six Mississippi headwaters lakes. MS, N.S.F. Limnology Inst., Bemidji St. Col1. , Bemidji. Kahn, Joseph H., Lyle K. Krusemark, and John R., Oakley; 1968. A partial limnological survey of two Minnesota lakes. MS, N.S.F. Lirnnology Inst., Bemidji St. Coil., Bemidji. Lang, D. E., J. F. McGuire, and K. t’1. Bishop; 1969. Report on investigation of water quality of Wolf, Andrusia and Cass lakes. MPCA, Minneapolis. Schilling, Joel, 1974. Personal communication (lake map; treatment requirements at Bemidji SIP; operation of Otter Tail Power hydro dam). MPCA, Minneapolis. Vollenweider, Richard A., (in press). Input-output models. Schweiz. A. Hydrol. ------- VII. APPENDICES APPENDIX A TRIBUTARY FLOW DATA ------- TR1A1JTA Y FLOW INFORMATION FOR MINNESOTA 10/30/74 LA (E CODE 7762 WOLF LAKE TOTAL DRAINAGE ARLA OF LAI(F 694.00 TOTAL DRA!NAc,v AREA OF LAKE = SU 1 OF SUP—DRAINAGE APEAS = TRIRUTARY MONTH YEAR IEAN FLOW DAY FLOW DAY FLOW DAY FLOW 10 72 i i 72 I? 77 1 73 2 73 3 73 4 73 5 73 6 73 7 73 9 73 9 73 10 72 11 7’ 12 1 73 7 73 - 73 4 73 5 73 F, 73 7 73 9 71 9 71 ?48.C0 203.00 304.00 ?R0 .00 21 O.G0 647.00 ?‘O • 00 ?1 8.00 20?. 00 NQ. 00 213.00 Jsl S.00 ?53. 0O 208.00 3uP.00 780 • 00 21 2.00 6sc .,0 ? 39•fl () ??5.00 ‘11.00 193.00 232.00 100 .00 SUR—DRA LNAC’ TPTPUTAQY AREA JA FEP MAR AI R MAY NORMALIZED FLOWS JUN JUL AUG ?7A?A1 669.00 249.05 I9O.. 6 ?30. 54 910.48 936.74 699.40 199.43 404.32 ?7A2A? 684.00 ‘46.u7 192.4? ‘33.48 933.90 958.22 715.02 38O.3 218.88 286.01 268.49 3.99 2.56 2.25 5.82 ?7A?81 10.70 1.7w 1.16 ‘.41 13.20 15.80 12.80 6.10 2.71 5.10 0.09 0.08 0.28 274?C1 0.60 0.Oh 0.02 0.14 0.84 0.79 0.74 0.31 0.06 0.11 0.16 0.82 2.22 ?7A?ZZ 4.77 0.16 0.45 1.21 5.46 5.66 5.75 2.21 0.72 1.72 1.09 SEP OCT NOV DEC MEAN MEAN MONTHLY FLOWS AND DAILY FLOWS SUMMARY 694.00 FLOW OUT = 4848.50 684.07 276241 ?7A?A2 14 327.00 5 203.00 10 295.00 20 244.00 18 210.00 17 1941.00 1 233.00 19 201.00 8 168.00 II 213.00 16 365.00 14 334.00 S 208.00 10 299.00 ?0 244.00 212.00 17 1965.00 1 253.00 19 20 .OO 9 163.00 11 202.00 16 348.00 14 202.00 14 220.00 ------- I I — ii F LO ‘ ! N 0 ”’’ i 11 . F )_) I E SO F A 10/3 ( 1/14 LA(F C01 ’ )7’7 I ‘ F i ‘ i ) i —I_ Y L’ ‘- • (A 1 ‘ 1 rl j( ITA. y M01 1 V ‘1 : ‘A rt_(I.I ‘‘AT’ FL ( I ’ 77A I I) “ ‘ I’ . ‘4.’11} 11 7 — 2 , - ’ — I — / ‘ I’ 3. •1 1 . “• 1.7 ) 7 l.’. 1’ 1. ’1 - 7 17 6 4._ 3 I l 4’ 4.00 5 7 i 4•77 I 3.-TO 7_• 7 1 )•‘ - , k 7T T.’- ii J . u C) / / .11 1 — 10 14 II /7 (“.I-+ — (,.1O 7 /2 . ‘, 1? 1 7 7 (.10 7 7i r ’.,7 I:i 0.0? u.3 17 1.IJ 4 7 , 1J. ’ 0.30 1’ 0.20 .- ‘ i- F 7 7 ‘.t’- 0.14 11 0.23 .4 7 1f V 1 . ) I’ 1.30 II 72 . ‘ I -J li 1.21 -S )( 7 7 ,,• /_ I 0.5 ’) - (‘1 3 ’ /’ ( 17 4 I ( 1. . 1 2.13 71 1-. 1.71 7 7_ ’ ).)‘ . 1.10 Ii 1.’ - - 11 1.7u 9 7 1. 4 1A 2.10 ------- APPENDIX B PHYSICAL and CHEMICAL DATA ------- STORET RETRIEVAL DATE 74/10/30 27A201 47 25 30.0 094 40 30.0 WOLF LAKE 27 MINNESOTA I1EPALES 2111202 4 0027 FEET DEPTH 00010 00300 00077 00094 00400 00410 00630 00610 00665 00666 DATE TIME DEPTH WATER DO TRANSP CNDUCTVY PH T ALK N02&N03 NH3—N PHOS—TOT PHOS—DIS FROM OF TEMP SECCHI FIELD CACO3 N—TOTAL TOTAL TO DAY FEET CENT “IG/L INCHES MICPOMHO SU MGIL MG/I MG/I MG/L P MG/I P 7?/07/11 17 30 0000 33 17 30 0004 24.3 13.0 270 8.70 137 0.070 0.080 0.038 0.023 17 30 0015 19.4 6.0 300 8.00 143 0.070 0.080 0.027 0.012 17 30 0020 17.0 7.0 340 7.40 164 0.050 0.100 0.042 0.017 17 30 0027 11.4 0.4 355 7.20 169 0.110 0.630 0.249 0.078 7.109/08 18 00 0000 60 280 8.10 139 0.060 0.150 0.047 0.018 18 (10 0004 18.4 6.7 280 8.10 139 0.060 0.140 0.050 0.018 18 00 0015 17.4 6.4 283 7.90 139 0.050 0.190 0.037 0.015 18 00 0020 17.’. 3.3 290 7.50 146 0.050 0.490 0.071 0.043 18 00 0027 16.6 5.7 293 7.50 148 0.050 0.490 0.075 0.045 72/10/21 11 40 0000 48 260 8.30 143 0.040 0.060 8.050 0.021 11 40 0004 6.3 12.0 248 8.30 145 0.050 0.060 0.066 0.025 11 40 0015 6.3 10.0 248 8,30 147 0.020 0.040 0.056 0.026 Ii 40 0028 6.1 10.2 248 8.30 147 0.020 0.050 0.080 0.034 3’217 DATE TIME DEPTH CHLRPI’YL FROM OF A TO DAY FF T UG/L 7?/07/11 ii 30 0000 13.OJ 7/09/08 18 00 0000 12.7 ) 72/10/21 11 40 0000 J VALUE KNOWN TO BE IN ERROR ------- APPENDIX C TRIBUTARY and WASTEWATER TREATMENT PLANT DATA ------- STO FT ETP!’VAI I)i T 7L 4 /10/. 0 274241 LS2742A) 47 ‘7 00.0 094 42 10.0 M ISSISSh -’PI 27 C D u’.. SHEET tsI 1/’ OLF LAKF CO riwY 2 N41 UPSTPEAfrIWOLF L4 cE 1IEPALES 2111204 4 0000 FEET DEPT-s °0 l0 0fl 71 DATE TIME ) TH ID7\ u3 Tut JF1 13—N PriOS—fliS PHOS—TOT OM OF —TOT 1 N T)IAI U’ TriO TO 1)A! FF T /L l ’,/L 1 /L MG/L MG/L r 77/10/it. 1210 ‘.0 ) 0.,S0 0.0J4 0.042 0.054 7?/fl/0’-’ 11 V 0 . ’ 0 (i.0 7 ) 0.053 0.0 2 71/03/1 1047 0.lfli D.0 2 0.072 O.10 73/04/01 I 40 .t )3I c.4Rrj .0i0 fl.012 73/04/14 ‘)O 8 0.01fl’ 0. ’ )flu 3.0 0.1)10 0.0 S 7 3 /Q 5/Jq 1 ’ 41 ).O10’ 0. -J9 c . ( ( sc 0.020 0.0 55 73/Q /l)1 10 C 1J.0lC c 0.— ’-’D 0.033 0.170 73/07/0 - l ) 50 1.010 0.7 ) 0.( 3? 0.0 6 o.075 71/0’ /11 )4 Tfl .01 -’ (‘. ) i.0?0 0.04 0.085 73/0’ /1 10 ‘5 ‘.O74 G. ’t) 1.06fl 0.055 0.085 K V”L(JE r. NOWN TO r E LF’ S THAN I’ !CATEfl ------- T’RT v e 7./1’iO 27CC 1 ‘7 30.0 J94 40 . O.0 ‘flVE1 CO 4, S-iF T 1 0/ OLF LAIc CO H ’Y - ‘J6 .75 I UPS1RMLI ANOPUSIA 11ET ’- ALES 2111204 4 U000 FEET DEPTH C 3 j ‘0 - ’ t u(-1’) Out 71 JAT F1 r - T--1 t) 1 ) 3 t’ r r j L - os—njc PH0S—1’)r ru- AL r TOT t L O THO T ) F F ‘ ‘‘/L 1 A/L 4h/L 1 M /L ,.) 7?/I)/1 . l7( O ‘.0 3’ G.O1 U.C5 7?/1I/O Ii ‘ .JI ). 1(. ‘.1?C 0.014 0.O3’ 7 /CI/2 1’) O ).P , C.O6 O.0 5 7 /j1/17 ,q .2 .t7’- ). ‘ 2 .14L, 7VU’4/0I 14 ‘C ).‘-‘(C ‘J.C0 73/ / i l, C4 0.00C 7 /N /03 10 fl .u1 c C.°3 i ‘).013 0.03’, 73/j7f0 .(,!j’ •‘.)Il O.tfl l ”(i - ”iI C .eI ).3 ’ ‘.! lC’ 0.fl ’T 0.07, 7 3/L /l 13 ?fl ‘.‘J1 l.0: .1I 0.0 0 i< VALIJi - r t’4 Lqf\J TO -3 L - SS F -V N I’J’)1Ct TFi) ------- STOQFT TR1 Vai 1 ATL 74/l(’/ O LS27A2B1 ‘+7 24 30.0 09’ 40 10.0 LITTLE WOLF LK/WOLF LK CONNECT CO *s29 T/ OLF LA,(E Ar ‘NO XING NEAR 0LF LAt(E SHOPE fl PALES 2111204 4 0000 FEET DEPTH 00610 00671 006b [ ATr Tj’i )E TH ‘ O’ ’O3 TOT V JEL (JH3—N PH()S—1)i Pt-iOS—TOT PO’ i or , —TorAL TOTAL OPTHO T3 flAY FEET /L ‘ U/L M ’/L Mr,/L P M(/L P 7?/1O/1 ’ .03r ‘•4 fl 0.03 0.006 0.Q2 7?/lI/0S 11 SO ‘ ‘.O17 3.’ +0t) 0.073 0.010 0.O1.’ 73/0 Vii 10 0’. O.7 ,0 J.040 0. 005K 0.010 73/i ’/O1 14 40 1.3” 0.031 0.005K 0.005 < 71/C4/1’. 10 15 3.017 fl•44(J 0.009 0.00 5K 0.010 71/0c/1 i r,.o ls 0.4 O 0.007 0.005K 0.010 71/06/03 11 00 3.013K 0.660 0.017 0.00 5K 0.035 71/07/0 I I S t,.0 i- + 0.034 0.025 71/0 /1i oc 71 .01UK 0.70’ 0.030 0.007 0.030 71/rC /1A 10 ‘S U.0 ”D 0.340 0.035 0.011 0.02’) K V LU KNOWN TO r3E L S Trf N IN [ )ICATEI) ------- ST’)’ ET PETRIFVai OAEr 7’ /1)/i0 27A2C1 LS27A2C1 47 ?4 00.0 094 41 00.0 i1’’fl LK / WOLF LAKE CONNECTION 27 CO 13 T/. OLF LAKE AT SECONDARY ROAD CROSSING 1 IE°ALES 2111204 4 0000 FEET DEPTH C’ 63fl 00 ’5 00610 00611 00665 D TF TIMF rF0T- iO SNO3 TOT KJFL NH3-N PHOS—DIS PHOS—TOT FR JM f’J—T )TAL N TOTAL ORT-iO TO AY FFFT MG/L 1(,/L M(,/L HG/L ‘-‘ MG/L P 72/10/14 C,0’.’ Ø• 75 :i. 02 2 0.00 5K 0.O?1 7?/fl/0’, 11 45 0.319 0.470 0.0 4 0.00k 0.014 7?/1?/10 ii e0 0.01’)K 0.11i. 0.140 0.007 0.018 73/01/70 11 05 O.010 0.T?0 0.220 0.005K 7l/U2/1 i 13 10 u.027 I.RQO 0.300 0.007 0.025 71/01/17 tO ( 0 0.054 1.260 0.420 0.010 0.025 71/04/01 16 50 i .0 o O. 00 fl.13? o. 009 0.O?5 71/04/14 tO 10 ).0 6 O.LeMO 0.035 0.005K 0.015 71/0S/1 10 SM 0.01? 1.?O0 0.021 0.005K 0.025 71/06/01 10 0 0.010K ].031 0.005K 0.015 71/07/0U 11 00 0.014 ?. Ou 0. 3O 0.005K 0.035 74/0 /1l 0’3 20 0.03 ’ 0.540 0.037 0.008 0.030 71/09/16 10 30 0.05 ?.j O O 0.092 0.00 0.025 K V LUE r NOWN TO -3 LESS THAN INr)ICATrD ------- STORET RETRIEVAL DATE 741)0/30 27A25 1 TF27A251 P011490 47 29 30.0 094 50 00.0 BEMIDJI 27 Co #4 SHEET #1 T/WOLF LAKE MISSISSIPPI RIVER 1 1EPALES 2141204 4 0000 FEET DEPTH 00630 00625 00610 00671 00665 50051 50053 DATE TIME DEPTH NO? N03 TOT XJEL NN3-N PHOS—DIS PHOS—TOT FLOW CONDUIT FROM OF N—TOTAL N TOTAL ORTHO RATE FLOW—MGD TO DAY FEET MG/L MG/L MG/L MG/I P MG/L P INST MGD MONTHLY 73/01/29 11 00 CPU)— 1.250 39.900 22.000 5.400 8.400 0.785 0.984 73/01/29 13 00 73l02/28 10 30 CP(T)— 1.260 41.000 24.000 8.200 9.000 1.000 0.900 73/02/28 12 30 73/03/30 10 30 CP(T)— 2.300 26.000 11.600 9.200 9.600 0.900 0.866 73/03/30 13 00 73/04/30 1) 00 CPU)— 2.100 30.000 13.200 6.200 10.300 1.000 0.846 73/04/30 13 00 7 /05/31 11 00 CP(T)— 2.820 42.000 25.100 8.890 11.500 1.350 1.000 73/05/31 13 00 73/06/29 11 00 CPU)— 2.200 31.000 16.400 6.600 9.900 1.200 1.200 73/06/29 13 00 73/07/31 ii 00 CP(T)— 2.800 26.000 7.000 3.300 9.680 1.000 1.000 73/07/31 13 00 73/09/04 10 30 CP(T)— 2.0 0 28.600 8.100 1.200 1.000 73/09/04 12 30 73/10/01 ii 00 CP(T)— 1.050 31.500 20.000 7.000 10.500 0.925 0.900 73/10/01 13 00 73/10/31 1? 00 CPU)— 0.540 40.000 18.000 6.000 12.000 0.950 0.900 73/10/31 14 00 73/11/30 I I 00 CP(T)— 0.060 49.000 28.000 4.900 11.000 0.870 0.790 71/11/30 13 00 74/01/02 11 00 CP(T)— ‘.OOO 31.500 21.000 10.600 11.500 0.900 0.977 74/01/02 13 00 ------- ?7A?51 TF274251 P0114 90 ‘.7 ? 30.0 0 44 co 00.0 kE 1fl)JI 27 CO 4 S’-jEFT #1 J/qr) f LAKE- ‘ !ssIscI°P1 P V R 1 1Fj- ALES ‘4 74/J?/O ’ 10 00 CP (T) - 7 ’./0?/O 17 00 •37) 17.’00 ST’)’ ET PET ’ [ c VnI •)ATI: 7 ’/J ,/ju j1 ’• j O ) 10 0067) 00 -’ ’6 50051 50053 OATF T I - )E T-1 ‘JO7 NUj TJI JE1 rj-i3 — j P-iOS—OIS PHOS—TOT FLOw CONDUIT FQf) i o J—TUTAI J TOTAL OPTHO IRATE FLOW—MGO TO ). Y FRET M’/L ‘ 1r / 1f,/L 4C’/L P M(,/L P INST M ,D MONTHLY 2141204 0000 FEET DEPTH 1 7.&flO 12.500 U • 950 0 • 932 ------- |