U.S. ENVIRONMENTAL PROTECTION AGENCY NATIONAL EUTROPHICATION SURVEY WORKING PAPER SERIES PACIFIC NORTHWEST ENVIRONMENTAL RESEARCH LABORATORY An Associate Laboratory of the NATIONAL ENVIRONMENTAL RESEARCH CENTER - CORVALLIS, OREGON and NATIONAL ENVIRONMENTAL RESEARCH CENTER - LAS VEGAS, NEVADA Q 697-O32 ------- REPORT ON LAKECALHOUN HENNEPIN COUNTY MINNESOTA EPA REGION V WORKING PAPER No, 90 WITH THE COOPERATION OF THE MINNESOTA POLLUTION CONTROL AGENCY AND THE MINNESOTA NATIONAL GUARD JUNE, 1975 ------- •1 CONTENTS Page Foreword ii List of Minnesota Study Lakes iv, v Lake and Drainage Area Map vi Sections I. Introduction 1 II. Conclusions 1 III. Lake and Drainage Basin Characteristics 3 IV. Lake Water Quality Summary 4 V. Literature Reviewed 8 VI. Appendices 9 ------- 11 FOREWORD The National Eutrophication Survey was initiated in 1972 in response to an Administration commitment to investigate the nation- wide threat of accelerated eutrophication to fresh water lakes and reservoirs. OBJECTIVES The Survey was designed to develop, in conjunction with state environmental agencies, information on nutrient sources, concentrations, and impact on selected freshwater lakes as a basis for formulating comprehensive and coordinated national, regional, and state management practices relating to point-source discharge reduction and non-point source pollution abatement in lake watersheds. ANALYTIC APPROACH The mathematical and statistical procedures selected for the Survey’s eutrophication analysis are based on related concepts that: a. A generalized representation or model relating sources, concentrations, and impacts can be constructed. b. By applying measurements of relevant parameters associated with lake degradation, the generalized model can be transformed into an operational representation of a lake, its drainage basin, and related nutrients. c. With such a transformation, an assessment of the potential for eutrophication control can be made. LAKE ANALYSIS* In this report, the first stage of evaluation of lake and water- shed data collected from the study lake and its drainage basin is documented. The report is formatted to provide state environmental agencies with specific information for basin planning [ 3O3(e)], water quality criteria/standards review [ 3O3(c)], clean lakes [ 3l4(a,b)], and water quality monitoring [ lO6 and §305(b)] activities mandated by the Federal Water Pollution Control Act Amendments of 1972. * The lake discussed in this report was included in the National Eutrophication Survey as a water body of interest to the Minnesota Pollution Control Agency. This report relates only to the data obtained from lake sampling. ------- 111 Beyond the single lake analysis, broader based correlations between nutrient concentrations (and loading) and trophic condi- tion are being made to advance the rationale and data base for refinement of nutrient water quality criteria for the Nation’s fresh water lakes. Likewise, niultivariate evaluations for the relationships between land use, nutrient export, and trophic condition, by lake class or use, are being developed to assist in the formulation of planning guidelines and policies by EPA and to augment plans implementation by the states. ACKNOWLEDGMENT The staff of the National Eutrophication Survey (Office of Research & Development, U. S. Environmental Protection Agency) expresses sincere appreciation to the Minnesota Pollution Control Agency for professional involvement and to the Minnesota National Guard for conducting the tributary sampling phase of the Survey. Grant J. Merritt, Director of the Minnesota Pollution Control Agency, John F. McGuire, Chief, and Joel G. Schilling, Biologist, of the Section of Surface and Groundwater, Division of Water Quality, provided invaluable lake documentation and counsel during the course of the Survey; and the staff of the Section of Municipal Works, Divi- sion of Water Quality, were most helpful in identifying point sources and soliciting municipal participation in the Survey. Major General Chester J. Moeglein, the Adjutant General of Minnesota, and Project Officer Major Adrian Beltrand, who directed the volunteer efforts of the Minnesota National Guardsmen, are also gratefully acknowledged for their assistance to the Survey. ------- iv NATIONAL EUTROPHICATION SURVEY STUDY LAKES STATE OF MINNESOTA LAKE NAME COUNTY Albert Lea Freeborn Andrusia Beltrami Badger Polk Bartlett Koochiching Bear Freeborn Bernidji Beltrami Big Stearr s Big Stone Big Stone, MN; Roberts, Grant, SD Birch Cass Blackduck Beltrami Blackhoof Crow Wing Budd Martin Buffalo Wright Calhoun Hennepin Carlos Douglas Carrigan Wright Cass Beltrami, Cass Clearwater Wright, Stearns Cokato Wright Cranberry Crow Wing Darling Douglas Elbow St. Louis Embarass St. Louis Fall Lake Forest Washington Green Kandlyohi Gull Cass Heron Jackson Leech Cass Le Homme Dieu Douglas Lily Blue Earth Little Grant Lost St. Louis ------- V LAKE NAME COUNTY Madison Blue Earth Malmedal Pope Mashkenode St. Louis McQuade St. Louis Minnetonka Hennepin Minnewaska Pope Mud Itasca Nest Kandiyohi Pelican St. Louis Pepin Goodhue, Wabasha, MN; Pierce, Pepin, WI Rabbit Crow Wing Sakatah Le Sueur Shagawa St. Louis Silver McLeod Six Mile St. Louis Spring Washington, Dakota St. Croix Washington, MN; St. Croix, Pierce, WI St. Louis Bay St. Louis, MN; Douglas, WI Superior Bay St. Louis, MN; Douglas, WI Swan Itasca Trace Todd Trout Itasca Wagonga Kandiyohi Walimark Chisago White Bear Washington Winona Douglas Wolf Beltrami, Hubbard Woodcock Kandiyohi Zumbro Olmstead, Wabasha ------- vi Map Location / ( LAKE CALHOUN \\. ® Tributary Sampling Site )( Lake Sampling Site Direct Drainage Area Limits ____________________ Ni. Scale X02 LAKE ç CALHOUN ) )co’ 930 19’ ) ) / 930 20’ / 56 L. r c 5 /7 /7 LAKE HARRIET ( ) 1’ ------- LAKE CALHOUN STORET NO. 27B6 I. INTRODUCTION Lake Calhoun was included in the National Eutrophication Survey as a water body of interest to the Minnesota Pollution Control Agency. No known wastewater treatment plants impact the lake, and tributary sampling was minimal because of lack of flows (the data obtained are given in Appendix C). Therefore, this report primarily relates to lake sampling data. II. CONCLUSIONS A. Trophic Condition: Survey data show that Lake Calhoun is eutrophic. Of the 60 Minnesota lakes on which sample was completed, 37 had less mean total phosphorus, 39 had less mean dissolved phosphorus, 44 had less mean inorganic nitrogen, 24 had less mean chlorophyll a, and 18 had greater mean Secchi disc transparency. This central Minneapolis lake is characterized by summer fish— kills and seasonal anaerobic bottom conditions with hydrogen sulfide formation. High nutrient levels with severe oxygen depression in the hypolimnion are indicative of excessive organic loadings to the lake. The lake has a record of high chloride input, including some storm water pollution (Schilling, 1974). ------- 2 B. Rate—Limiting Nutrient: The algal assay sampled collected by Survey limnologists in October, 1972, was lost in shipment to the laboratory. Personnel of the Minnesota Pollution Control Agency collected another assay sample on April 27, 1973 , during spring turnover. The results of the assay indicate Lake Calhoun was phosphorus limited at that time. The lake data obtained in 1972 indicate nitrogen limitation in July, September, and October. ------- 3 III. LAKE AND DRAINAGE BASIN CHARACTERISTICS A. Lake Morphometryt: 1. Surface area: 416 acres. 2. Mean depth: 34.8 feet. 3. Maximum depth: 90 feet. 4. Volume: 14,477 acre-feet. B. Tributary and Outlet: (See Appendix A for flow data) 1. Tributaries - Drainage Mean flow Name area (mi 2 )* ( cfs)* Lake of Isles outlet 4.4 1.1 Minor tributaries & immediate drainage - L . Totals 8.4 2.1 2. Outlet - Closed basin; no normal surface water overflow. C. Precipitation***: 1. Year of sampling: 27.5 inches. 2. Mean annual: 27.3 inches. t MN Dept. of Conservation lake survey map (1954). * Drainage areas are accurate within ±5%; mean daily flows are accurate within ±10%; and ungaged flows are accurate within ±10 to 25% for drainage areas greater than 10 mi 2 . ** Includes area of lake. See Working Paper No. 1, “Survey Methods, 1972”. t 1 S nvironniental rot C rv31IIs Env,ronmerit& Res aicb Li ” 200 S W 35ft Stree’ ., ‘330 ------- 4 IV. LAKE WATER QUALITY SUMMARY Lake Calhoun was sampled three times during the open—water season of 1972 by means of a pontoon-equipped Huey helicopter. Each time, samples for physical and chemical parameters were collected from two stations on the lake and from a number of depths at each station (see map, page vi). During each visit, a single depth—integrated (15 feet to surface) sample was composited from the stations for phytoplankton identification and enumeration; and during the last visit, a single five-gallon depth-integrated sample was composited for algal assays. Also each time, a depth-integrated sample was collected from each of the stations for chlorophyll a analysis. The maximum depths sampled were 65 feet at station 1 and 78 feet at station 2. The results obtained are presented in full in Appendix B, and the data for the fall sampling period, when the lake essentially was well- mixed, are summarized in the following table. Note, however, the Secchi disc summary is based on all values. For differences in the various parameters at the other sampling times, refer to Appendix B. ------- 5 A. Physical and chemical characteristics: FALL VALUES (10/27/72) Parameter Minimum Mean Median Maximum Temperature (Cent.) 9.3 9.5 9.5 9.6 Dissolved oxygen (mg/l) 7.9 9.0 8.7 10.2 Conductivity (pmhos) 460 476 480 480 pH (unIts) 7.4 7.7 7.7 7.9 Alkalinity (mg/i) 118 119 119 122 Total P (mg/i) 0.069 0.127 0.091 0.303 Dissolved P (mg/i) 0.057 0.104 0.073 0.240 NO 2 + NO 3 (mg/i) 0.070 0.075 0.070 0.100 Ammonia (mg/i) 0.630 0.658 0.650 0.740 ALL VALUES Secchi disc (inches) 50 72 63 119 ------- 6 B. Biological characteristics: 1. Phytoplankton - Sampling Dominant Number Date Genera per ml 07/07/72 1. Anabaena 3,297 2. Microcystis 1,739 3. Dinobryon 797 4. Chroococcus 652 5. Tabellaria 254 Other genera 1,015 Total 7,754 09/05/72 1. Anabaena 3,653 2. Flagellates 344 3. Aphanocapsa 271 4. Closterium 253 5. Dinobryon 235 Other genera 687 Total 5,443 10/27/72 1. Stichococcus 3,367 2. Flagellates 2,814 3. Oscillatoria 2,211 4. Dinobryon 854 5. Syriedra 402 Other genera 2,864 Total 12,512 2. Chlorophyll a - (Because of instrumentation problems during the 1972 sampling, the following values may be in error by plus or minus 20 percent.) Sampling Station Chlorophyll a Date Number ( ig/1 ) 07/07/72 01 12.2 02 9.7 09/05/72 01 6.2 02 7.5 10/27/72 01 19.7 02 18.0 ------- 7 Maximum yield ( mall-dry wt. ) 4.3 9.5 13.2 17.5 20.5 26.4 3.8 C. Limiting Nutrient Study: 1. Autoclaved, filtered, and nutrient spiked - Ortho P Inorganic N Spike (mg/i) Conc. (mg/fl Conc. (mg/i ) _____________ Control 0.018 0.620 0.010 P 0.028 0.620 0.020 p 0.038 0.620 0.050 p 0.068 0.620 0.050 p + 5.0 N 0.068 1.120 0.050 P + 10.0 N 0.068 1.620 10.0 N 0.018 1.620 2. Discussion - The control yield of the assay alga, Selenastrum capri— cornutum , indicates that the potential primary productivity of Lake Calhoun was moderately high at the time the sample was taken (April 27, 1973) . Also, the increased yields with increased levels of orthophosphorus show the lake was phos- phorus limited at that time. The 1972 lake data indicate nitrogen limitation in July (N/P ratio = 8/1), September (N/P = 9/1), and October (N/P = 7/1). ------- 8 V. LITERATURE REVIEWED Schilling, Joel, 1974. Personal con iiunicatlon (compendium of information on Minnesota study lakes). MPCA, Minneapolis. ------- 9 VI APPENDICES APPENDIX A TRIBUTARY FLOW DATA ------- TRIBUTARY FLOW INFORMATION FOP MINNESOTA 10/30/74 LA’(E CODE 27B6 CALHOUN LAKE TOTAL DRAINAGE AREA OF LAKE 8.41 SUB—DRAINAGE NORMALIZED FLOWS TRIRUTARY AREA JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC MEAN 27B6A 1 4.36 0.06 0.09 0.64 2.89 2.52 3.15 1.36 0.45 0.48 0.87 0.43 0.15 1.09 27967 1 4.05 0.05 0.07 0.71 2.61 2.18 2.94 1.17 0.34 0.40 0.65 0.32 0.13 0.96 SUMMARY TOTAL DRAINAGE AREA OF LAKE = 8.41 TOTAL FLOW IN = 24.66 SUM OF SUB—DRAINAGE AREAS = 8.41 TOTAL FLOW OUT 0.0 NOTE *** THIS IS A CLOSED BASIN WITH NO NORMAL SURFACE WATER OUTFLOW MEAN MONTHLY FLOWS AND DAILY FLOWS TRIBUTARY MONTH YEAR MEAN FLOW DAY FLOW DAY FLOW DAY FLOW 2786*1 10 72 0.45 14 0.30 11 72 1.00 12 72 0.16 1 73 0.16 9 0.20 2 73 0.11 3 73 0.65 4 73 6.96 5 73 2.57 6 73 1.07 30 0.20 7 73 1.21 31 1.33 8 73 0.43 30 0.41 9 73 0.41 30 0.56 27B6Z7 10 72 0.34 14 0.30 11 7? 0.37 7? 0.14 1 73 0.13 9 0.20 2 73 0.OR 3 73 0.72 4 73 6.?9 5 73 2.22 6 73 1.00 30 0.20 7 73 1.04 31 1.14 B 73 0.33 31 0.29 9 73 Q .34 30 ------- APPENDIX B PHYSICAL and CHEMICAL DATA ------- STORET RETRIEVAL DATE 74/10/30 27H60 I 44 56 18.0 093 18 42.0 CALHOUN LAKE 27 MINNESOTA 1IEPALES 2111202 3 0034 FEET DEPTH 00010 00300 00077 00094 00400 00410 00630 00610 00665 00666 DATE TIME DEPTH WATER DO TRANSP CNDIJCTVY P 11 1 ALK N02&N03 NH3—N PHOS—TOT PHOS—DIS FROM 0 TEMP SECCHI FIELD CACO3 N—TOTAL TOTAL TO DAY FEET CENT MG/L INCHES MICROMHO SU MG/L MG/L MG/L MG/L P MG/L P 72/01/07 09 35 0000 58 430 8.50 94 0.070 0.130 0.021 0.012 09 35 0004 18.8 P.6 97 0.040 0.050 0.037 0.013 09 0015 12.0 8.4 430 8.40 98 0.040 0.050 0.027 0.014 09 35 0020 9.5 09 35 0025 500 7.30 - 09 35 0028 8.0 0.6 135 0.260 0.540 0.101 0.070 72/09/05 09 40 0000 50 460 8.25 116 0.060 0.210 0.067 0.023 09 40 0004 18.9 6.0 460 8.15 116 0.040 0.250 0.069 0.023 09 40 0015 18.6 3.6 458 7.75 116 0.030 0.380 0.063 0.031 09 40 0021 18.6 3.1 460 7.70 116 0.040 0.400 0.054 0.031 09 40 0027 18.5 2.5 460 7.68 115 0.050 0.460 0.065 0.028 12/10/27 08 45 0000 119 480 7.40 119 0.070 0.650 0.091 0.073 08 45 0004 9.5 7.9 460 7.60 119 0.070 0.650 0.116 0.092 08 45 0015 9.4 9.8 470 7.60 1)9 0.070 0.650 0.140 0.114 08 45 0030 9.4 8.4 470 7.60 119 0.070 0.650 0.141 0.126 08 45 0040 9.4 10.2 480 7.60 120 0.070 0.650 0.189 0.168 08 45 0050 9.4 8.6 480 7.70 120 0.080 0.670 0.303 0.240 08 45 0065 9.3 8.4 480 7.70 122 0.100 0.740 0.222 0.175 _____________ - 32217 DATE TIME DEPTH CHLRPHYL FROM OF A TO DAY FEET UG/L 72/07/07 09 35 0000 12.2J 72/09/05 09 40 0000 6.2J 72/10/27 08 45 0000 19.7J J VALUE KNOwN TO E !‘J ER U ------- STOPET PEIPIEVAL PATE 14/I /3C ‘7 60? 44 56 68.0 093 I 39.0 CALIOUN LAKE 21 MINNESOTA 1 IEPALES 3 2111202 0070 FEET DEPTN )03O0 00077 00 TRANSP SECCH I ‘lG/L INCHES 00096 CNI)UCTVY F I ELO MI CRONHO 00630 N02 NO3 N—TOTAL MG/L OOblO NH3-N TOTAL MG/L 7?/07/07 10 45 0000 10 45 0004 10 45 0015 10 45 0020 10 45 0025 10 45 0050 10 45 0077 72/09/05 10 10 0000 10 10 0004 10 10 0015 10 10 0022 10 10 0030 10 10 0060 10 10 0053 10 10 0065 10 10 007M 72/10/27 10 30 0000 10 30 0004 10 30 0015 10 30 00’S 10 30 0035 ID 30 0060 21.0 19 • 0 13.0 P.S 7.0 7.0 18.4 18.5 18.4 18.2 17.9 16.4 12.0 9.5 9.5 9.5 9.6 9.’. 9.6 bi 420 440 440 8 • 50 8.00 N. ID DATE TIME DE°TH FP0M OF TO DAY FEET 72/07/07 10 65 0000 10 45 0050 77/09/05 I) 10 000’) 77/10/27 10 10 3’fl 3?? I 7 CML PPMYL A UG/L 00010 DATE TIME DEPTH WATEP FROM OF TEMP TO DAY FEET CENT 00400 00410 P’-4 T ALK CACO3 Su MG/L 00665 00666 PHOS—TOl PHOS—DIS MG/L P MG/L P 97 0.050 97 0.040 106 0.050 130 0.150 10.4 5.0 1.1 1.6 0.4 0.0 4.9 4.0 4.2 3.2 ?.0 0.2 0.0 0.0 9.4 8.7 9.6 9.1 0.026 0.032 0.027 0.030 0.011 0.0 14 0.0 13 0.0 13 490 495 68 460 460 460 460 460 460 470 520 520 670 480 480 480 480 1.1*) 7 • 95 7.93 7 • 85 7 • 90 7 • 65 7 • 60 7 • 38 7.15 7.15 7 • $0 7 • 90 7 • 90 7 • 90 7 • 90 7 • 90 131 133 117 114 119 116 117 119 lie 119 143 120 120 121 118 118 lie 0.030 0 • 050 0 • 050 0.100 1.600 0.310 0 • 340 0.350 0.360 0.410 0 • 500 o • 650 0.810 2.540 0.650 0.640 0 • 630 0 • 650 0.680 0.650 0.100 0.070 0 • 040 0 • 040 0 • 040 0 • 040 0.040 0.030 0.030 0.080 0 • 130 0.070 0.0 70 0.070 0.070 0 • 090 0.070 0.281 0.251 0.069 0.024 0.065 0.024 0.061 0.026 0.058 0.030 0.068 0.031 0.072 0.040 0.092 0.056 0.640 0.033 0.558 0.562 0.069 0.060 0.076 0.062 0.076 0.057 0.081 0.061 0.077 0.067 0.073 0.060 9 • 7J 7.2 7. ‘J I . j r ; 1 f ) . • ) •- I ------- APPENDIX C TRIBUTARY DATA ------- STORET RETRIEVAL DATE 74/10/30 27 36A1 LS27E 641 44 57 00.0 093 18 30.0 LK OF THE ISLES/LK CALHOUN CONN 27 15 MINNEAPOLIS I/LAKE CALHOUN Us 212 BRDG NE CORNER LAKE CALHOUN 11EPALES 2111204 4 0000 FEET DEPTH 00630 00625 00610 00671 00665 DATE TIME DEPTH NO2 NO3 TOT KJEL NH3—N PHOS—DIS PHOS—TOT FROM OF N—TOTAL N TOTAL ORTHO TO DAY FEET MG/L MG/L MG/L MG/L P MG/L P 72/10/14 15 23 0.091 1.320 0.399 0.058 0.105 73/06/30 08 30 0.010K 1.680 0.042 0.021 0.060 73/07/31 07 30 0.010K 1.540 0.063 0.017 0.055 73/08/31 10 30 0.025 1.100 0.069 0.015 0.045 73/09/30 14 00 0.012 1.850 0.294 0.039 0.105 K VALUE KNOWN TO BE LESS THAN INDICATED ------- STORET RETRIEVAL DATE 7’.,1U/30 27 6’31 LS2786B1 44 56 (10.0 093 18 30.0 LK CALHOUN/LK hARRIET CONNECTION 27 15 ‘ 4INNEAPOLIS 0/LAKE CALHOUN CO P-tWY 20 XING SSE END NEAPRERPY PARK 1 IEPALES 2111204 4 0000 FEET DEPTrI 00 30 0062 00610 00671 00665 DATE TIME DEPTR NO2 NO3 TOT KJEL NH3—N PHOS—DIS PHOS—TOT FROM OF N-TOTAL N TOTAL UPTHO TO DAY FEET MG#’L MC,/L MG/L MG/L P MG/L P 73/06/30 08 00 0.010K 2.400 73/OR/31 10 45 0.010K 1.150 0.069 0.009 0.042 73/09/30 14 00 0.010K 1. ou 0.340 o.O3 0.100 K VALUE KNOWN TO BE LESS THAN INDICATED ------- |