OVERVIEW SURVEY OF THE DRYCLEANING INDUSTRY PEDCo ENVIRONMENTAL ------- PEDCO ENVIRONMENTAL. INC. P.O BOX 2O337 DALLAS. TEXAS 7522O (214) 259-3577 TELEX (214) 254-4O21 OVERVIEW SURVEY OF THE DRYCLEANING INDUSTRY by PEDCo Environmental, Inc. Contract No. 68-01-4147 Task No. 101 John R. Busik, Project Officer Robert L. King, Task Manager Prepared for U.S. ENVIRONMENTAL PROTECTION AGENCY DIVISION OF STATIONARY SOURCE ENFORCEMENT WASHINGTON, D.C. 20460 March 1980 CORPORATE OFFICE 11499 CHESTER ROAD CINCINNATI OHIO 45246 (513)782 47OO CHESTER TOWERS ------- DISCLAIMER This report was furnished to the U.S. Environmental Protec- tion Agency by PEDC0 Environmental, Inc., in fulfillment of Contract No. 68-01-4147. The contents of this report are repro- duced herein as received from the contractor. The opinions, findings, and conclusions expressed are those of the author and not necessarily those of the U.S. Environmental Protection Agency. ii ------- CONTENTS Page Figures iv Tables v Acknowledgment V I. 1. Introduction 1 2. Industry Characterization S 3. Control Technology and Factors Affecting Its Enforcement 31 4. Methods of Identifying Sources and Quantifying Emissions 42 References 61 Appendix Inventories of coin-operated, commercial, and industrial drycleaning establishments and of • perc emissions 63 iii ------- FIGURES Number Page 2—1 Commercial Perc Drycleaning Plant Flow Diagram, With Paper Cartridge Filter and Carbon Adsorber 10 2—2 Flow Diagram Of Industrial Drycleaning Operation 12 4-1 Drycleaning Industry Data Sheet 44 4-2 Clothes Processed Versus Perc Consumed By Commercial Drycleaners In Dallas And Hamilton Counties (1 to 4 Employees) 56 4-3 Clothes Processed Versus Perc Consumed By Commercial Drycleaners In Dallas And Hamilton Counties (5 to 9 Employees) 57 4-4 Clothes Processed Versus Perc Consumed By Commercial Drycleaners In Dallas And Hamilton • Counties (10 to 19 Employees) 58 4-5 Clothes Processed Versus Perc Consumed By Commercial Drycleaners In Dallas And Hamilton Counties ( 20 Employees) 59 iv ------- TABLE S Number Page 2-1 Summary List: Coin-operated Laundries and Drycleaners In The United States, 1976 16 2-2 Summary List: Commercial Drycleaners In The United States, 1976 16 2—3 Summary List: Industrial Laundries and Drycleaners In The United States, 1976 17 2-4 Representative Emission Factors For commercial Drycleaners 21 2-5 Representative Weights of Clothing Cleaned By Commercial Drycleaners 22 2-6 Summary Of Emission Factors and Weight Of Clothing Cleaned Per Establishment 24 2-7 Summary Of Estimated 1976 Perc Emissions From Drycleaners (Mg) 26 2-8 Predicted Growth Patterns In The Drycleaning Industry To 1980 (Number of EstablishmentS) 27 2—9 Perc Emission Factors Before and After Applica- tion Of RACT, kg/100 kg Of Clothes 30 2—10 Projections of Controlled Perc Emissions (Mg) 30 4—1 Survey Of Dallas County Commercial Drycleaners Using Carbon Adsorbers 47 4-2 Commercial Drycleaners With 1 to 4 Employees 49 4-3 Commercial Drycleaners With 5 to 9 Employees 52 4-4 Commercial Drycleaners With 10 to 19 Employees 54 4-5 Commercial Drycleaners With 20 Employees 55 V ------- ACKNOWLEDGMENTS This report was prepared under the direction of Thomas C. Ponder, Jr., and Mazen Y. Anastas. Principal authors were Mazen Y. Anastas, Herbert J. Belknap, Jean E. Carruthers, Cynthia N. Harvey, K. Wade Mason, and Mary A. Taft. Task Manager for the U.S. Environmental Protection Agency was Mr. Robert L. King. vi ------- SECTION 1 INTRODUCTION BACKGROJJND The Clean Air Act Arnendn ents (CAAA) of 1977 required each state to report to the U.S. EnvironnLental Protection Agency (EPA) on all areas within the state as to the status of compliance with National Ambient Air Quality Standards (NAAQS). Attainment and nonattainment areas in each state with regard to the control of major pollutants were listed in the Federal Register on I’ arch 3, 1978. According to the 1977 CAAA, nonattainment areas must achieve compliance with NAAQS by December 31, 1982, with some possible extensions to 1987. In December 1978, a Control Technique Guideline (CTG)’ was published for control of Volatile Organic Compounds (VOC) from perchioroethylene (perc) drycleaning systems. Those industries in areas where standards covering a particular pollutant are not being met will be required to apply Reasonably Available Control Technology (RACT), which is discussed in the guideline publica- tion. Perc drycleaning systems constitute a significant VOC source in urban areas. On or before January 1, 1980, all states are required to submit to the EPA proposed revisions of the State Implementation Plan (SIP) reflecting RACT for perc drycleaning systems. Promul- gation of the regulations is required by July 1, 1980. The new regulations will involve state and local agencies with an indus- try that to date has been involved in little or no air pollution control enforcement. Previous state regulations pertaining to organic solvents, specifically Rule 66 of the Air Pollution Control District County of Los Angeles, California, and Part 205 1 ------- of the New York City Metropolitan Area, have always exempted perc from emission limitations. Part 212 of the New York City Metro- politan Area Regulations does provide some limitations to perc emissions from drycleaning facilities. PURPOSE AND SCOPE OF REPORT A current inventory of perc drycleaning establishments in the United States, and specifically in photochemical oxidant nonattainment areas, is needed for evaluation of the enforcement of RACT requirements, for long-range planning by EPA’S Division of Stationary Source Enforcement (DSSE), and for use in operation of regional and local programs. This report includes an inventory of all U.S. drycleaning establishments having Standard Industrial Classification (SIC) codes 7215, 7216, and 7218. These represent establishments with coin-operated facilities, commercial establishments, and indus- trial establishments, respectively, which together constitute the three major sections of the drycleaning industry. The inventory gives the status (attainment or nonattainrnent) for photochemical oxidants of each area. In addition to the demography, Section 2 includes a brief description of the industry, with definitions of each SIC code and typical modes of operation in the three indus- try sectors. The number of drycleaning plants and potential perc emissions are projected for the years 1980, 1985, and 1990 from base numbers. The base numbers were obtained from the 1976 County Business Pattern (CBP) publication 2 of the Bureau of Census; from PEDC0 surveys of drycleaning establishments in Dallas County, Texas, and Hamilton County, Ohio; and from the CTC. Section 3 describes the control technology for perc dry- cleaning facilities and the factors affecting enforcement of RACT. In addition, the enforcement aspects of the proposed model regulation are reviewed. This is a preliminary overview of the problems associated with application and compliance monitoring of 2 ------- RACT. More specific problems will be addressed in future phases of this study on perc drycleaners. Section 4 describes PEDC0’s methods of identifying emission sources and quantifying emissions. The sources of information are discussed, and results of the Dallas County and Hamilton County surveys are given. Recommendations for future demographic studies are also provided. S JNIV1ARY OF FINDINGS This survey indicates a total of 32,663 laundry and dry- cleaning establishments located in the United States as of 1976. Of the drycleaning establishments, the numbers using perc in the three industry sectors are as follows: 5,179 in the coin-op classification, 14,366 in the commercial classification, and 193 in the industrial classification. The total 1979 perc emissions from all perc drycleaning plants is estimated to be 158,000 Mg (174,000 tons). The number of drycleaners using other solvents is as follows: 133 coin-ops using freon, 4,789 commercials using naphtha, 798 commercials using freon, and 193 industrials using naphtha. The proposed regulations are intended to reduce vapor emis- sions from the dryer exhaust, to reduce perc emissions from leakage of liquids, and to reduce the perc content of waste materials. Control technology includes the use of a carbon adsorber or equally effective control device on the dryer ex- haust, increased maintenance for detection and immediate repair of leaks, and suitable operation of stills, muck cookers, and filter cartridges to reduce the perc content of the waste mate- rials before disposal. Coin-operated facilities and those with limited space or steam capacity are exempt from installation of the carbon adsorber. Enforcement of the proposed regulations pertaining to limit- ing the dryer exhaust emission may be difficult in the absence of a relatively inexpensive continuous monitor for perc in the concentration range of 10 to 200 ppm. Inspections for leakage 3 ------- and inspections to determine whether the operator is following proper procedures to reduce perc contents of wastes are time con- suming and may be impractical because the total number of sources is very large. The difficulties may be circumvented by specify- ing standards for each classification based on the rate of sol- vent consumption per weight of materials cleaned or per number of drycleaning cycles; such standards are referred to as “mileage” standards. 4 ------- SECTION 2 INDUSTRY CHARACTER I ZATION DESCRIPTION OF INDUSTRY The perc drycleaning facilities of concern for this study are three industries in the SIC Code 721 — Laundry, Cleaning, and Garment Services: o Coin-operated laundries and drycleaners (SIC code 7215) o Drycleaning plants, except rugcleaning (SIC code 7216) O Industrial launderers (SIC code 7218) The services provided by these industries include cleaning of apparel, household fabrics, and work uniforms. Coin-operated Laundries and Drycleaning Establishments ( SIC 7215 ) Coin-Operated laundries (coin-ops) are defined as follows in the Standard Industrial Classification Manual. 3 Establishments primarily engaged in the operation of coin- operated or similar self-service laundry and drycleaning equipment for use on the premises, or in apartments, dormi- tories, and similar locations. Coin-ops are distinguished from the commercial and industri- al drycleaners in that the drycleaning equipment is activated by the customer. Often the manager or attendant of the coin-op assists the customer in drycleaning the clothes. Coin-ops are normally part of a laundromat facility and can be operated on an independent or franchise basis. They provide a low cost [ approx- imately $1.10 per kg ($0.50 per ib) of clothes] 4 self-service type of cirycleaning without pressing, spotting, or other services provided by commercial drycleaners. A typical coin-operated S ------- drycleaning establishment processes approximately 9,050 kg (20,000 ib) of clothes per year, for an average annual gross income of $10,000 per year. 5 Coin-ops are located primarily in urban areas. Perc is the predominant drycleaning solvent used by the coin-ops, accounting for 97.5 percent of the drycleaning sy- stems. 1 Fluorocarbon solvents account for the remaining 2.5 percent of the coin-op systems; no coin-operated machines use petroleum solvents because of their flammability. The drycleaning units used in the typical coin-ops are predominantly self-contained and automatic. These units are commonly referred to as dry-to-dry machines. The units use cartridge-type filters; no distillation of the perc is performed at a typical coin-op. Cartridge filters being marketed for coin-ops include a fluted paper cartridge with or without a core consisting of acti- vated carbon, activated carbon and clay, or carbon. Activated carbon adsorbs the dyes from the perc and the clay adsorbs non- volatile residues. 6 Drycleaning Plants, Except Rugcleaning (SIC 7216 ) Establishments in this industry are often referred to as commercial drycleaners, defined in the SIC manual as follows: Plants primarily engaged in drycleaning or dyeing apparel and household fabrics other than rugs (Industry 7217). Press shops and agents for drycleaners are classified in Industry 7212. Establishments dyeing fabrics for the trade are classified in Major Group 22. These establishments include small neighborhood drycleaners operating independently, franchised shops, and specialty cleaners that clean leather and other fine goods. These cleaners typi- cally process about 17,700 kg (39,000 lb) of clothes per year. 5 The range is from less than 9,000 kg to greater than 45,000 kg (20,000 lb to greater than 100,000 lb) per year. Most of these plants have 1 to 15 employees; typically a plant has 4 to 6 employees. 6 ------- Perc is the predominant drycleaning solvent used by this group. Of all commercial drycleaners, 72 percent use perc, 24 percent use Stoddard solvent, and 4 percent use fluorocarbons. The process consists of three basic steps: washing, extrac- tion, and drying. In the washing step the clothes are washed in one of two types of machines, characterized as transfer or dry- to-dry machines. The transfer machines currently being manufac- tured carry out the washing and extraction steps and then the clothes are transferred to the dryer. The dry-to-dry machines perform all of the steps: washing, extraction, and drying. To date, the dry-to-dry machine has been used very little in commer- cial perc plants because machine utilization is only half that of the transfer machine, which allows simultaneous use of the washer and dryer. Interest in the dry-to-dry machine is increasing, however, because it can meet OSHA regulations more easily, and requires less attention during the cleaning cycle than the trans- fer type. Furthermore, the equipment manufacturers are increas- ing their efforts to improve and sell this type. Presently, about 25 percent of the commercial plants have dry-to-dry machines . The washing step may include one or two solvent baths, although most commercial cleaners use only one. The use of a two-bath system generally improves overall cleaning efficiency. To aid in removing water-soluble soils, small amounts of deter- gent (and sometimes water) are added to the solvent in the one- bath system. In the extraction step in both machines the solvent bath is drained, then the clothes are spun at a high speed to wring out excess solvent. Nost of the newer transfer machines are washer— extractor types; thus the washing and extraction steps are the same as in the dry-to-dry machines. After the extraction step the procedure differs with the two types of machines. With the transfer machines an operator trans- fers clothes to the dryer-reclaimer. Current OSHA regulations require that fresh air be blown across the operator when clothes 7 ------- are being transferred from the washer-extractor to the dryer. This is accomplished by an exhaust fan, which pulls air into the washer and dryer doors and away from the operator when the doors are open. All perc plants use a solvent-reclaiming dryer. Heated air is blown over the clothes in a closed, recirculating loop to vaporize the solvent, which is then recovered in a water-cooled condenser. After a timed drying step (usually 15 to 20 minutes), fresh air is blown over the clothes for approximately 5 minutes to complete the drying cycle and aerate the clothes. During this aeration portion of the drying cycle, the air stream and perc vapors are frequently vented to the atmosphere. Approximately 35 percent of the perc plants have added carbon adsorbers to the dryer exhausts to recover perc for economic reasons. During the washing cycle, perc is passed through a filter for removal of suspended matter and dyes. The filter may be either a paper cartridge type or regenerative type. The paper cartridge filter, usually containing some activated carbon for removal of dyes, is re-used for several wash cycles and is drain- ed before it is discarded. The regenerative filter is regener- ated by ba kwashing the filter powder precoat and adding a new precoat. The backwash contains diatomaceous earth, activated carbon, suspended matter removed from the perc, and a consider- able amount of perc that must be recovered. Perc recovery is usually accomplished in a muck cooker, which is a distillation unit with direct steam injection. Industry sources say the trend is toward more extensive use of cartridge type filters. Removal of nonvolatile residues, such as oils and fats, from the perc is accomplished in a unit that distills the perc from the impurities, which are discarded as still bottoms. Periodic distillation of all or part of the solvent is necessary to pre- vent buildup of these soluble impurities. A typical commercial perc plant would have one washer- extractor of 25- or 50-pound capacity, one or two reclaiming dryers of equivalent size, a solvent filter with disposable paper 8 ------- cartridges, and a distillation unit. Figure 2-1 is a process flow diagram of a typical commerical perc drycleaning plant. Industrial Launderers (SIC 7218 ) The definition of SIC code 7218 for establishments within this industry is as follows: 3 Establishments primarily engaged in supplying laundered or drycleaned work uniforms; laundered wiping towels; safety equipment (gloves, flame resistant clothing, etc.); dust control items, such as treated mats or rugs, mops, dust tool covers and clothes and other selected items to industrial or commercial users. These items may belong to the industrial launderers and be supplied to users on a rental basis, or they may be the customer’s own goods. Establishments in- cluded in this industry may or may not operate their own laundry or drycleaning facilities. Industrial launderers supply these textile goods to users in commerce, industry, and government. Their annual volume of business is currently about $1 billion. Work uniforms and execu- tive shirts and slacks are usually drycleaned (with either Stod- dard or perc solvent) because longer wear is achieved by dry- cleaning than by laundering, and the aggressive action of the solvents toward heavily greased items often produces superior re- sults. 7 ’ 8 Laundering, with water and detergent, is nonetheless indispensable in the removal of water-solubles such as perspira- tion odors. Some launderers commonly use a dual-phase cleaning process consisting of an initial water wash followed by a solvent wash and rinse. 7 ’ 8 Some industrial launderers provide various dust control items for use in the maintenance of machinery and its controls, in prevention of soiling of finished products, and in dust con- trol within working areas. These items include: o Wiping towels, which are a specially woven fabric, for use in applications where no lint or residues are tolerated. o Chemically treated wiping clothes and mops, which do not just “push dirt around” but actually pick it up. 9 ------- Figure 2-1. Commercial perc drycleaning plant flow diagram, with paper cartridge filter and carbon ad so rbe r. 0 ------- Chemically treated rugs, which remove and retain shoe— borne dust. These are typically used in such institu- tions as hospitals, schools, and retail shops. The dust control items may be either drycleaned or water- washed, depending on how they are used. As with uniforms, these dust control items may be either rented or owned by the customer. Industrial launderers with drycleaning facilities constitute about 42.5 percent of the total number of establishments. 5 About 27 percent of the total weight of uniforms, dust control items, etc., is drycleaned with either perc or Stoddard solvent, the split being roughly half and half. On the basis of number of machines, however, the breakdown is 60 percent perc and 40 per- cent Stoddard. Although industrial drycleaning operations vary in number and size of machines, a typical industrial system is a transfer type, consisting of a 113 kg (250 lb) washer/extractor and a matching dryer/reclaimer as described earlier. 5 Nultibath wash- ing is common; that is; the items to be cleaned are subjected to a water and detergent wash, a solvent wash, and a solvent rinse. Solvent filtration is seldom used. 9 Suspended matter and nonvol- atile resiaues are removed by distillation. The residue from distillation is further treated in a muck cooker for removal of solvent. A typical industrial drycleaning operation processes 470,000 kg (1,036,000 ib) of textile goods per year. A typical industrial drycleaning operation is shown schema- tically in Figure 2-2. The system consists of a washer/extrac- tor, dryer, carbon adsorber, distillation unit, and muck cooker. The plant handles 240,000 to 700,000 kg (600,000 to 1,500,000 ib) of clothes per year. The clothes (usually work • uniforms) can be heavily soiled with caked dirt and various oils and greases, including body oils. Shirts go through a water/ perc/perc (dual-phase) treatment, whereas pants are cleaned only by two perc baths. A water bath is used on shirts to remove water solubles, such as caked dirt and perspiration. 11 ------- 4 Legend CLEAN SOLVENT TAN K ______ LIQUID LINE GAS/VAPOR LINE 1 DISTILLATION UNIT FEED TANK 2 DECANTER 3 CHEMICAL 4 DECANTER 5 DECANTER CW CONDENSER WATER LS LIVE STEAM .1 SEPARATOR H 20 MUCK COOKI LS 1 RESIDUE DRY CLOTHES WET CLOTHES CLEAN CLOTHES Figure 2-2. Flow diagram of industrial drycleaning operation. ------- The perc washing and drying steps are similar to those in commercial drycleaning plants. The washer and dryer vents are connected to a carbon adsorber. Distillation of solvent is carried out continuously in the still. The solvent distillation rate is one bath per load. Solvent from the first perc bath is distilled, with steam as the heat source. The oil that accumu- lates in the still is pumped at the end of the day to the muck cooker, where live steam is injected directly into the oil sol- vent mixture (steam distillation) and indirect steam is the source of heat. The distillation is continued until a sharp rise in temperature of the outlet condenser cooling water is observed. This occurs because the oil that is volatized once all the perc has distilled over condenses at a much higher temperature. Since the flow of cooling water to the condenser remains constant, the outlet temperature of the cooling water rises. The condensed solvent/water mixture is sent to a separator, from which reclaim- ed solvent is sent to the still feed tank. A heavy black residue in the still must be disposed of. The vents from all solvent tanks, the still, and the muck cooker are connected by manifold to a single water-cooled condenser, which in turn is vented to the atmosphere. Residual water (about 200 ppm) in the perc from the various water separators is removed by passing the solvent solution through a bed of salt (baker’s salt). To minimize solvent loss in dual-phase operations, the washer/extractor and drains are flushed with a minimal amount of water. This solvent is sepa- rated in a two-stage process. DEMOGRAPHY OF ESTABLISHNENTS IN THE COIN-OPERATED, COMMERCIAL, AND INDUSTRIAL SECTORS Data on the distribution of the drycleaning establishments by State, EPA Region, and by nonattainment area were obtained from County Business Patterns (CBP) 1976, an annual publication of the Bureau of Census (BOC). 2 The detailed information is given in the Appendix. The data compiled and reported include 13 ------- total number of establishments in each industry (SIC codes 7215, 7216, and 7218), in each county, arid in each state plus the Dis- trict of Columbia. Data are also, given on independent cities (such as Baltimore, Maryland) that do not lie within counties. The independent cities within each state are listed in the World- wide Geographical Location Codes . 1 ° Data from CBP show the total number of establishments in each employment-size class, for each industry, and for each county and state. The employment-size classes are as follows: Employment-size class Number of employees 1 lto4 2 5to9 3 lOtol9 4 20to49 5 50to99 6 100 to 249 7 250 to 499 8 500 to 999 9 1000 or more As background for the pertinent demographic data, informa- tion is given on the sources of data in CBP. This information will aid the reader in understanding the limitations associated with use of these data for estimating potential emissions and identifying problem areas. Data for the 1976 CBP are extracted from the BOC Standard Statistical Establishment List. The Bureau updates these lists annually on the basis of information obtained from the Internal Revenue Service, the Social Security Administration, and the BOC data files. Employment information on single-establishment employers (or one-location employers) is obtained from the Social Security 1976 first-quarter Form 941 Schedule A. Employment information on multiestablishment (multilocation) employers is extracted from 1975 and 1976 Annual Organization Surveys con- ducted by the Bureau. 14 ------- Each legal entity (corporation, partnership, single proprie- torship, etc.) having paid employees is required to file a sepa- rate Employers’ Quarterly Federal Tax Return, Treasury Form 941, identified by an employer identification number. For single- location legal entities, each fourth quarter 941 report is count- ed as an establishment. For multilocation legal entities, each location is counted as one establishment if it is determined to have been active as of December 15, 1976. The determination is based on information from the 1976 Annual Company Organization Survey. Industry Classifications are based on the 1972 Edition of the Standard Industrial Classification Nanual. 3 The classifica- tion of an establishment is based on the principal product or group of products produced or distributed, or on the principal services rendered by the establishment. The term “principal” indicates that the establishment derives 50 percent or more of its revenue from the activities (or services) defined by the SIC code. This is the so-called “50 percent rule.” Data are not shown separately for any SIC having less than 50 employees in the county, state, or United States. Data on such establishments are reported, however, under the totals for the industry group. For example, if the total employment in all commercial drycleaning establishments (SIC 7216) in one county is less than 50, these establishments are not reported under SIC 7216. They are re- ported with the county totals for the major industry group 721. Data from CBP on the coin-op, commercial, and industrial launderers located in each EPA region and nonattainment area are summarized in Tables 2-1, 2-2, and 2—3. The totals reported for the coin-op sector (11,804) are far below the estimated 40,000 establishments reported by Ward Gill, President of the National Automatic Laundry and Cleaning Coun- cil. 11 This difference is partly accounted for by the fact that many of the coin-ops are owned by firms operating commercial drycleaning establishments (SIC 7216) and industrial laundries (SIC 7218). Since more than 50 percent of such a company’s 15 ------- TABLE 2-1. SUMMARY LIST: COIN-OPERATED LAUNDRIES AND DRYCLEANERS IN THE UNITED STATES, 1976 Region Total coin-ops Coin-ops attainment in areas Coin-ops nonattainment in areas I 558 128 430 II 1183 0 1183 III 1102 492 610 IV 2293 1618 675 V 2292 1444 1478 VI 1509 874 635 VII 697 558 139 VIII 361 281 80 I X 816 421 395 X 363 264 99 Total 11804 6080 5724 TABLE 2-2 SUMMARY LIST: COMMERCIAL DRYCLEANERS IN THE UNITED STATES, 1976 Region Total commercials Commercial attainment s in areas Commercials nonattainment in areas I 1092 72 1020 Ii 2920 0 2920 III 2115 501 1614 IV 3664 2255 1409 V 3680 1050 2630 V I 2292 1154 1138 VII 1000 631 369 VIII 579 274 305 IX 2049 590 1459 X 562 277 285 Total 19953 6804 13149 16 ------- TABLE 2-3. SUMMARY LIST: INDUSTRIAL LAUNDRIES AND DRYCLEANERS IN THE UNITED STATES, 1976 Region Total industrials Industria attainment is in areas Industrials nonattainment in areas I 40 2 38 II 91 0 91 III 83 28 55 IV 182 97 85 V 192 67 125 VI 112 53 59 VII 53 40 13 VIII 14 8 6 IX 118 37 81 X 21 15 6 Total 906 347 559 17 ------- income is probably derived from the commercial or industrial operations, they would be listed under those SIC codes. Also many coin-ops are operated by an owner who has no employees. The totals listed for the commercial and industrial sectors are more likely to be accurate. Classification of areas as nonattaininent with respect to photochemical oxidants for each state are from a recent PEDC0 compilation based on information in recent issues of the Federal Register.’ 2 Where the states reported nonattainment on the basis of Air Quality Control Regions (AQCR), or parts thereof, within the state, PEDC0 used the Federal Air Quality Control Regions Manual’ 3 to obtain a list of counties within the AQCR(s). Where counties lie only partially within an AQCR, the whole county is assumed to be nonattainment. The numbers of establishments in attainment areas were calculated as differences between the counts for a state and for nonattainment areas within the state. Drycleaning establishments are expected to be concentrated in highly populated areas. The tables indicate that most dry- cleaners are located in EPA Regions 2 through 6. Total percent- ages for these regions are as follows: coin-ops, 76 percent; commercials, 74 percent; and industrials, 73 percent. Percent- ages of establishments located in nonattainment areas are as follows: coin-ops, 48 percent; commercials, 66 percent; and industrials, 62 percent. POTENTIAL EMISSIONS Perc emission factors express the amount of perc used to clean a given weight of clothing. The smallest emission factor indicates the most efficient plant. Emission factors may be expressed in terms of individual emission sources or as overall plant emissions. They are usually reported as kilograms of solvent per 100 kilograms of clothing cleaned. When applied to the solvent loss from an overall plant operation and reported as weight of clothes cleaned per drum of solvent it is referred to in the industry as “mileage.” 18 ------- The following sections concern the sources of perc emissions and the associated emission factors. Total emissions based on these emission factors are estimated for each state, for each EPA region, and for each nonattainrnent and attainment area within each state. Sources of Perc Emissions and Emission Factors A typical coin-operated establishment with drycleaning facilities operates two 3.6 kg (8 ib) dry-to-dry perc drycleaning units. A typical coin-op processes approximately 9,050 kg (20,000 ib) of clothes per year. 5 Emissions of perc from the typical coin-op include evaporation losses during aeration or deodorization of the clothes and during filter disposal, and miscellaneous losses, mostly by leakage. A properly maintained and operated dry-to-dry coin-op unit vents to the atmosphere only during the deodorization cycle. Clothes contain 20 to 25 percent perc by weight after washing and extraction. After drying, and before aeration, the clothes contain approximately 3 to 6 percent perc by weight when the unit is operated properly. When it is operated improperly, the clothes can contain more than 3 to 6 percent perc and excessive perc emissions will occur during the deodorization cycle. Cartridge filters were originally introduced to the dry- cleaning industry on the coin-op machines which use this type of filter predominantly because it is a multicharge filter. Useful life of a cartridge filter averages 60 to 65 loads of clothes for a 3.6 kg (8 ib) capacity machine.’ 4 According to the CTG, car- tridge filters are confined and contained, and thus inherently hold the perc emissions to 1 kg of perc per 100 kg of clothes cleaned (corresponding to 1 percent perc by weight).’ 5 Some operators drain the filters in a double bucket arrangement. The filter is placed in a perforated bucket and the perc draining from the cartridge filter is collected in a second bucket under- neath the perforated bucket. It is not known what percentage of 19 ------- coin-ops actually drain the filters in the double bucket or in the filter housing. Miscellaneous sources include fugitive emissions due to poor maintenance of the drycleaning unit. Fugitive emissions include both liquid and vapor losses. It is estimated that a 20 to 30 percent reduction of perc emissions can be accomplished with good operation and maintenance of the coin-op drycleaning units. 3 Perc usage per pound of clothes drycleaned is higher for coin-ops than for the commercial or industrial plants. The primary reason for the higher emissions from the coin-operated unit is that five loads of clothes in the 3.6-kg (8-ib) capacity unit equals the weight of clothes processed in one load in a similar 18 kg (40-ib) capacity unit in a commercial or industrial application. Since each washing/drying cycle involves “fixed” solvent losses, the larger unit emits less perc per pound of clothes cleaned. Losses are exemplified by liquid leaks, vapor leaks, and machine venting losses in solvent charging and discharging opera- tions. Coin-operated units average as low as 1,500 lb of clothes per drum of solvent and very rarely exceed 5,000 lb of clothes per drum of solvent. For coin-op units, an emission factor of 35.1 kg perc per 100 kg clothes processed (2000 lb of clothes per drum of solvent) is based on a range of values in an EPA report.’ 6 For commercial drycleaners using no carbon adsorber, the aeration step is a major source of perc vapors to the atmosphere. Other sources of perc emissions are transfer operations; evapora- tion losses at the washer, dryer, and distillation unit; losses from pumps, valves, flanges, seals, and water separators; and losses from inefficient handling of solvent. In addition, signi- ficant amounts of liquid perc are lost in disposal of distil- lation and muck cooker residues and filter cartridges. Plant emission factors derived from the surveys of Dallas and Hamilton Counties (details in Section 4) include all plants with and without carbon adsorbers, as shown in Table 2-4. 20 ------- TABLE 2-4. REPRESENTATIVE EMISSION FACTORS FOR COMMERCIAL DRYCLEANERS Employment- size class Emission factors, kg perc/100 kg clothing Dallas County Hamilton County Both Counties 1-4 employees 5-9 employees 10-19 employees 2O employees All 19.8 ( 31 )a 14 (35) 10.2 (9) 11.8 (2) 16.2 (77) 22.1 (46) 19.4 (17) 22.7 (8) 15.6 (1) 21.4 (72) 21.5 (77) 15.8 (52) 16.1 (17) 13.1 (3) 18.7 (149) aNumbers in parentheses are the number of plants surveyed in each employment-size class. The emission factors above are arithmetic averages of values from the Dallas and Hamilton County surveys. A linear regression was performed on the data points; however, the correlation fac- tors ranged from below 10 percent to about 50 percent for the various employment-size classes. A correlation factor of at least 80 percent would be necessary for assumption of a linear fit of the data. The weights of clothing cleaned in each employment-size class, shown in Table 2-5, also result from the Dallas and Hamil- ton County surveys. The numbers shown are arithmetic averages of the reported amounts of clothing cleaned. These numbers are considerably higher than the 17,700 kg/yr (39,021 lb/yr) of clothing cleaned by a typical drycleaner, as reported following a survey conducted by the International Fabricare Institute (IFI) in 1975.16 The New Source Performance Standards (NSPS) Background Document 5 developed a model plant for commercial drycleaners, showing 28,175 kg/yr (62,115 lb/yr) of clothing cleaned. The significantly higher results of PEDC0’s Dallas and Hamilton County surveys conducted in 1979 reflect the expected increase in demand for drycleariing services, as discussed in the NSPS Back- ground Document. 5 21 ------- TABLE 2-5. REPRESENTATIVE WEIGHTS OF CLOTHING CLEANED BY COMMERCIAL DRYCLEANERS Employment- size class Clothing cleaned, kg/yr Dallas Hamilton Both Counties 1-4 employees 5-9 employees 10-19 employees 2O employees All (Weighted — average) 30,144 ( 31 )a 46,920 (35) 72,912 (9) 122,652 (2) 45,171 (77) 24,420 (46) 42,924 (17) 51,924 (8) 70,704 (1) 32,488 (72) 26,724 (77) 45,641 (52) 63,035 (17) 105,336 (3) 39,042 (149) aThe numbers in parentheses are the number of plants surveyed in each category. Dry-to-dry machines are used exclusively by the coin-ops, whereas they account for only 2.5 percent of drycleaning machines in the commercial sector. Transfer units predominate also in the industrial drycleaning plants, especially in the larger systems of 113 kg (250 lb) capacity or more. Dry-to-dry machines are, however, gaining acceptance in industrial operations because they minimize exposure of workers to perc fumes. The sources of emissions from industrial drycleaning systems are as follows: Improperly vented equipment Solvent retained in distillation residues Miscellaneous leaks of liquid and vapor caused by lack of proper maintenance Accidental losses and discharges of solvents Excess emissions take place when point sources within the system are not properly vented to a carbon adsorption system, as fol- lows: Perc-laden air vented during the 3- to 5-minute aeration cycle Vents from perc storage vessels Vents from the washer/extractor Ventilation hoods at pickup points such as the washer/ extractor door 22 ------- In tests conducted on behalf of EPA, losses from these point sources totalled 7 kg per 100 kg of clothes (7 lb per 100 ib) in the absence of a carbon adsorber.’ With a carbon adsorber, these losses may be reduced to 0.3 kg per 100 kg of clothes. Solvent retained in distillation residues is a potential source of emissions when it is disposed of in open dumps in containers that corrode readily or are easily punctured in han- dling and transportation or in earth-moving operations at the dump. Most industrial drycleaners do not purify the solvent by filtration, 9 but rather by distillation. Residue from the stills contains suspended matter and non-volatile residues. In tests conducted by IFI, the emissions from this source were estimated at 1.6 kg perc per 100 kg of clothes (1.6 lb perc per 100 lb).’ Miscellaneous losses usually occur in leakage of liquid and vapors. Liquids may leak because of defective gaskets on washing machine doors and button traps or defective seals on pumps, valves, and pipe fittings. Vapors may leak because of defective gaskets on dampers used to isolate the air recirculated during drying or because of tears, punctures, or other damage to air ducts to and from the dryer. The IFI and EPA estimates of these miscellaneous losses are 2 kg and 1 kg per 100 kg of clothes, respectively. These emission factors for industrial operations apply to well-operated systems. The total emission factor for systems without carbon adsorbers is 10.6 kg per 100 kg clothes, whereas that for systems with carbon adsorbers is 3.9 kg per 100 kg clothes. The latter value for well—operated systems has been substantiated in source field measurements and reported for others. 17 ’’ 8 ’’ 9 ’ 20 ’ 2 ’ At an industrial operation with a 136-kg (300 ib) machine, tests conducted on behalf of EPA showed an emission factor of 2.35 kg per 100 kg of clothes (2.35 lb per 100 lb).’ 7 ’ 21 At another industrial facility with two 113-kg (250-ib) machines the emission factor was 4.5 kg per 100 kg clothes. 23 ------- It is reported that 50 percent of all industrial drycleaning systems are fitted with carbon adsorption control devices. 5 This value yields a weighted emission factor of 7.25 kg per 100 kg of clothes for well-operated systems, but it is not known how many systems are well operated. Data on four industrial drycleaning operations obtained in the survey of Dallas County show that solvent consumption is higher than 7.25 kg per 100 kg (7.25 lb per 100 ib). Solvent loss in these plants averaged 15 kg per 100 kg of clothes (15 lb per 100 ib). Emission factors and assumptions used in calculating total perc emissions are summarized in Table 2—6. TABLE 2-6. SUMMARY OF EMISSION FACTORS AND WEIGHT OF CLOTHING CLEANED PER ESTABLISHMENT. Coin-Op Commercial Industrial Emission factor, kg perc 100 kg clothes cleaned per All Plants 1-4 employees 5-9 éthployees 10-19 employees 2O employees 35.1 21.5 15.8 16.1 13.1 15 Clothes processed per plant per year, kg All Plants 1-4 employees 5-9 employees 10-19 employees 2O employees 9050 26,724 45,641 63,035 105,336 470,000 Fraction of plants with drycleaning facilities 0.45 1.00 0.425 Fraction of plants using perc 0.975 0.72 0 50 24 ------- Total Emissions On the basis of the emission factors and representative weights of clothing cleaned per establishment, total perc emis- sions may be estimated. Table 2-7 summarizes these emissions by EPA region and by nonattainment areas within each region. The table shows that most perc emissions occur in the more densely populated areas. EPA Regions 2 through 6 account for 74 percent of the perc emissions. Nonattaininent areas account for 64 percent. Nationwide total perc emissions based on the 1976 CBP fig- ures for number of drycleaning establishments are 130,000 Mg (143,000 tons). Sources in industry indicate that the perc consumption is closer to 158,000 Mg (174,000 tons). A recent IFI newsletter estimates that 15,000 coin-ops are using perc, almost three times the number estimated by CBP. If it is assumed that the number of coin-ops is twice that reported by CBP, the total 1976 perc emissions would be 146,000 Mg (161,000 tons). This figure is within 10 percent of the reported consumption; the assumption that the number of coin-op plants is twice that re- ported in CBP is used in the following sections. GROWTH PATTERNS Patterns of growth in the three industry sectors to the year 1990 are discussed in this subsection and are summarized in Table 2-8. These predicted growth patterns provide the basis for projections of perc emissions over the same period. Coin-Operated Laundry and Drycleaning CBP reports the number of coin-operated laundries and dry- cleaners with payrolls. It is a reasonable assumption that these facilities with payrolls are the larger plants that operate drycleaning units. CBP data for 1976 show 11,804 coin-ops. On the assumptions of 23,608 coin-ops (twice the CEP value) and an 25 ------- TABLE 2-7. SUMMARY OF ESTIMATED 1976 PERC EMISSIONS FROM DRYCLEANERS (Mg) I II III IV V VI VII VIII Ix x Total 777.6 1,648 7 1,535 7 3,195 7 4,072.5 2,103.1 971.4 503.0 1,137.3 505.9 16,450.9 599. 3 1,648.7 850. 1 940.8 2,060.0 885. 1 193.7 111. 5 550. 5 138. 0 7,977.7 5,508.7 13,817.7 11,102.3 18,763.4 18,797.8 11,563.2 4,895.3 2,870.7 10,307.4 2,688.6 100,315.1 5,163.3 13,817.7 8,525.6 7,513.4 13,808.1 6,113.1 1,941.9 1,535.0 7,430.1 1,371.2 67,219.4 599.4 1,363.3 1,243.5 2,726.6 2,876.4 1,677.8 794. 1 209. 7 1,767.8 314.6 13,573.2 569.4 1,363.3 824.0 1,273.6 1,872.7 883.9 194.8 89.9 1,213.5 89.9 8,375.0 Region Perc emission from Perc emissions from Perc emissions from coin-operated drycleaners commercial drycleaners industrial drycleaners Total Nonattainment areas Total Nonattainment areas Total Nonattainment areas ------- expected population growth rate of 0.9 percent, 5 the numbers of coin-operated plants can be estimated for 1979, 1980, 1985, and 1990, as shown in Table 2-8. TABLE 2-8. PREDICTED GROWTH PATTERNS IN THE DRYCLEANING INDUSTRY TO 1980 (Number of establishments) Year Coin-ops Commercial Industrial 1976 23,608 19,953 906 1979 24,251 20,497 931 1980 24,469 20,681 939 1985 25,591 21,629 982 1990 26,763 22,620 1,027 At the 1979 World Educational Congress for Laundering and Drycleaning, coin-op representatives advised fellow laundromat operators to stay away from the drycleaning business. The major reason cited for this was that the burning of perc fumes in combustion air for laundromat dryers produces a green residue on the burners, leading to reductions in dryer efficiency and in- creases in maintenance cost. At present, 97.5 percent of the coin-op drycleaning opera- tions use perc as the drycleaning solvent. Most industry sources agree that perc will continue to be the predominant solvent for coin-ops, although classification of perc as a carcinogen or hazardous pollutant may reverse the role of perc in the entire drycleaning industry. The use of closed systems with perc as a drycleaning solvent would be a viable alternative if this occurs, or other solvents believed to be nonphotochemically reactive, such as Freon (F-113), could be used in place of perc. There is some indication, however, that fluorocarbons such as F-113 may cause depletion of the upper atmospheric ozone layer. Growth Patterns for Commercial Drycleaners The number of commercial drycleaning establishments declined from 1967 through 1976, a period in which synthetic, washable fabrics were becoming more popular. Also, the demand for dry- cleaning.services decreases during times of adverse economic 27 ------- conditions, as occurred in 1974 and 1975. During that period the trend was toward fewer, larger establishments with larger ma- chines. In the past several years clothing stylists have begun to use more natural fabrics, a change that is expected to increase the demand for drycleaning in both the commercial and coin-oper- ated sectors. 5 There is no evidence to suggest whether consumers would switch from commercial drycleaning to the less expensive coin-operated units if a recession should occur. Industry sour- ces indicate that switching is unlikely, and that demand in both sectors should increase gradually during the next 5 to 10 years. This increase in demand is expected to be about equal to popula- tion growth or about 0.9 percent per year according to recent EPA-sponsored studies. 5 With the number of establishments in 1976 as the base num- ber, application of a growth factor of 0.9 percent per year yields the increase in number of establishments shown in Table 2—8. Growth Patterns in the Industrial Sector Recent trends in the industrial sector indicate a move toward fewer but larger plants. The total number of establish- ments has decreased between 1967 and l976. Although this sector is also affected by general economic trends, annual growth rates (both negative and positive) in number of establishments have been of the order of few percentage points. Since no general economic downturn took place between 1976 and the present time, a positive growth during that period may be assumed. Industry sources indicate that growth in weight of articles cleaned (both laundry and drycleaning) by the industrial sector usually paral- lels the growth in population. 8 ’ 9 Again, the EPA population growth rate of 0.9 percenL per year is used to predict the growth of industrial drycleaning sources to 1990. A large growth in perc drycleaning at the expense of water and detergent-based laundering has been anticipated, mostly 28 ------- because of the enactment of water pollution regulations affecting the use of detergents. 8 In addition, the rising sewerage rates levied by municipalities on the basis of total water used en- hanced the prospects for use of perc cleaning in lieu of water washing of some articles. The anticipated switch to perc has been limited, however, by current OSHA regulations limiting worker exposure to a total weighted average concentration of 100 ppm perc in the work environment and by pending EPA regula- tion of perc emissions from new and existing sources. Addi- tionally, EPA has determined that perc may be a carcinogen. If this is confirmed, the use of perc may be restricted. All these factors tend to create uncertainties in predicting future use. No new sources are expected to use petroleum solvents because of their higher cost and potential fire hazard. Existing perc systems are expected to be replaced by similar, but perhaps larger, perc-based systems. Therefore, the current estimated level of perc usage for 50 percent of all drycleaning is expected to hold throughout the period to 1990. Perc Emission Projections Current annual consumption of perc is reported at 158,000 Mg (174,000 tons). Estimated 1976 perc emissions, based on the number of drycleaning establishments given by CBP and an assump- tion that the number of coin-ops is twice that reported, are 146,000 Mg (161,000 tons); this figure is used in the emission projections. Until application of RACT, increases in perc emissions will match the rate of increase of number of establishments, or 0.9 percent per year. Perc emissions should then decrease with the application of RACT to the perc drycleaning industry. The main- tenance part of the proposed regulation is expected to become effective at the end of 1980. Full compliance (application of carbon adsorption or equivalent technology) should be achieved by the beginning of 1982. When application of RACT is complete, perc emissions will increase with population growth. 29 ------- The CTG and proposed standards background documents, give uncontrolled and controlled emission factors for the three indus- try sectors. This report indicates that the uncontrolled emis- sion factors are considerably higher, and hence that the con- trolled emission factors will also be higher. Table 2—9 presents the emissions factors from References 1 and 5 and those predicted in this study. The emission factors reported in these references were obtained from three carefully controlled emission tests. It is our opinion that emissions from actual operations will not be so low; however, the same percentage of emission reduction in each sector is probably achievable with application of RACT. TABLE 2-9. PERC EMISSION FACTORS BEFORE AND AFTER APPLICATION OF RACT, kg/lOO kg OF CLOTHES CTG emission factorsa,b PEOCo emission factors Uncontrolled Controlled Uncontrolled ControlledC Coin-op Commerical Industrial 20 12 12 15 5 5 35.1 18.7 15 26.3 7.8 6.2 aReference. 1, pp. 5-2, 5-3. bReference 5, p. 6-7. ccontrolled emission factors were obtained by multiplying PEDC0’s uncontrolled emission factors by percentage reduction predicted by EPA for each industry sector. Projections of controlled perc emissions for 1980, 1985, and 1990 are presented in Table 2—10. TABLE 2.10. PROJECTIONS OF CONTROLLED PERC EMiSSIONS (Mg) Year C1G PEDCO 1976 146,800 146,800 1980 152,200 152,200 1985 50,500 80,200 1990 52,900 83,900 30 ------- SECTION 3 CONTROL TECH1 4OLOGY AND FACTORS AFFECTING ENFORCEMENT In December 1978, the EPA Office of Air Quality Planning and Standards issued a CTG that specified means of controlling perc emissions from drycleaning systems in the coin-op 1 commercial, and industrial sectors. Regulations based on reasonably avail- able control technology are currently being formulated. This section briefly describes RACT and the factors affecting enforce- ment. SUMMARY OF REGULATIONS On the basis of the control technology specified in the CTG document, 1 regulations affecting existing sources of perc emis- sions from the three sectors of concern are to be issued shortly. The following paragraphs summarize the expected regulations. The regulations apply to all perc drycleaning systems in the coin-operated, commercial, and industrial sectors. The owner or operator of a drycleaning facility must accomplish the following: Vent the entire dryer exhaust through a properly func- tioning carbon adsorption system or equally effective control device; Emit no more than 100 ppm of volatile organic compounds from the dryer control device before dilution; Immediately repair all components found to be leaking liquid volatile organic compounds; Cook or treat all diatomaceous earth filters so that the residue contains 25 kg or less of volatile organic compounds per 100 kg of wet waste material; Reduce the volatile organic compounds from all solvent stills to 60 kg or less per 100 kg of wet waste mate- rial; 31 ------- Drain all filtration cartridges, in the filter housing, for at least 24 hours before discarding the cartridges; and When possible, dry all drained cartridges without emitting volatile organic compounds to the atmosphere. For systems where solvent purification is not done by dis- tillation, muck cooking, or filtration, the owner/operator must restrict wastes losses resulting from solvent purification to 1 kg per 100 kg clothes processed (1 lb per 100 ib). Demon- stration of these loss limits is also required. The following drycleaning systems will be exempted from the provisions pertaining to carbon adsorption and the associated 100 ppm emission limit: Coin-operated drycleaning systems. Other systems where space limitations prevent the installa- tion of a carbon adsorber and/or systems where steam re- quired for desorption of the carbon bed is not available. Compliance with regulations is expected to be monitored as follows: Compliance with items pertaining to the installation of a carbon adsorber and draining and drying of filter cartridges will be determined by visual inspection. Compliance with items pertaining to repair of system compo- nents found to be leaking will be determined by visual in- spection. Specifically the following components are includ- ed in this item covering liquid leaks: Hose connections, couplings, and valves. Machine door gaskets and seatings. Filter head gaskets and seatings. Pumps. Base tanks and storage containers. Water separators. Filter sludge recovery. Distillation unit. Diverter valves. Saturated lint from lint basket. Cartridge filters. 32 ------- Compliance with the 100 ppm emission standard will be deter- mined by: Tests methods outlined in EPA Guideline Series docu- ment, “Measurement of Volatile Organic Compounds,” EPA 450/2_78_041.22 Determination of the proper installation, operation, and maintenance of equipment that has been demonstrated to be adequate for meeting the specified emission limit. Compliance with items pertaining to limits on perc contents of residues from distillation and muck cooking operations will be determined by the American National Standards Institute standard procedure for determination of “Dilution of Gasoline Engine Crankcase Oils.” REASONABLY AVAILABLE CONTROL TECH1 OL0GY (RACT) FOR PERCHLOROETHYLENE DRYCLEANING SYSTEMS The regulations just described are based on control tech- niques specified in the CTG document.’ Briefly these techniques consist of (1) the use of activated carbon adsorption for control of emissions from air streams containing perc vapor and (2) the implementation of good housekeeping and equipment maintenance practices to control fugitive emissions, liquid leaks, and mis- cellaneous losses. Coin-operated systems are exempt from the use of activated carbon adsorption because such facilities may lack steam to desorb the carbon bed and/or lack the space needed for installation of an adsorption system. Activated carbon adsorption has been found effective in controlling typical vapor emissions from point sources in commer- cial and industrial drycleaning systems. In EPA tests, perc concentrations at the carbon bed inlet ranged from 540 to 6500 ppm. 19 ’ 20 ’ 21 Removal efficiencies were usually 95 percent or more, with outlet concentrations usually below 100 ppm. The latter is an emission requirement specified by regulations. Activated carbon suitable for adsorption of organic vapors is obtained from carbonization of organic materials (such as 33 ------- lignite, peat, and wood) and subsequent activation. The carbon- ization process produces a spongelike structure with a large internal surface area (500 to 1000 m 2 /g). Size of the pores within the carbon structure are on the order of the size of the molecules to be adsorbed. Size of the pores is not uniform, however, and the pores are thought to consist of voids between crystallites of carbon formed during carbonization. Activation of the carbonized material consists of subjecting it to steam and/or air at high temperatures to effect oxidation and to re- moval strongly adsorbed hydrocarbons. This exposes the surface area between the crystallites, which exert an attractive force on the species of interest with which they are brought into con- tact. 23 Beds of activated carbon suitable for use in adsorption of perchioroethylene vapors from drycleaning operations are designed according to the following criteria: 24 Space velocities of the order of 100 reciprocal minute. Space velocity is defined as the ratio of volumetric flow of treated gas to volume of bed. A ratio of volumetric flow rate to bed cross-sectional area of about 328 m 3 per minute per m 2 of cross sec- tional area (100 ft 3 per minute per ft 2 ). A bed working capacity of about 20 percent. That is the weight of perchioroethylene adsorbed (and also amenable to desorption) as a percentage of the total weight of activated carbon. Carbon bed depths range from 0.23 to 0.81 m (9 to 32 in.). The volumetric gas flow vented to the carbon bed during aeration is usually about 0.25 dry standard cubic meter per minute per kg of clothes dried (4 dscfm per ib). Temperatures of the bed inlet and outlet gas are about 43°C and 24°C (110°F and 75°F) respec- tively. Moisture contents are usually near 1 percent.’ 9 ’ 20 ’ 2 ’ The adsorbed perc may be desorbed with steam at the rate of about 4 kg steam per kg of perc to be desorbed. All sources of vapor emissions may be vented to carbon adsorption systems: 34 ------- washer/extracter vents solvent tank vents floor pickup points vents from distillation units and muck cookers water separator vents air from the deodorization (or aeration) step. The regulations require good housekeeping and maintenance practices in all three sectors of the perc dry cleaning industry. Two types of perc losses are defined.’ The first pertains to “point” losses and the second to “fugitive” losses. These losses may be either in vapor or liquid form. Leakage of liquid is relatively easy to detect by visual inspection of piping, fittings, and solvent storage vessels. Leakage of vapor is more difficult to detect but can be detected by smell (at 50 to 200 ppm), by use of soap solution on piping ductwork and fittings, or by use of an organic vapor detector. The most common causes of solvent loss or emission, both in liquid and vapor form, are given below.’’ 25 Required inspection and/or maintenance procedures are discussed briefly. Hose onnections, unions, couplings and valves : These should be inspected at least monthly. They should be tightened, repaired or replaced if leaks develop. These are mainly sources of liquid leaks. Nachine door gaskets and seating : During the wash cycle an ill-fitting or damaged door gasket will cause solvent to leak. This could occur if the gasket is old and needs replacement. An old gasket usually develops cracks and/or feels hard. Faulty door gaskets may be sources of liquid and vapor leaks. Solvent filter gaskets and seatings : With frequent assembly and disassembly of solvent filters, the gaskets become damaged. This is especially true of paper cartridge filters, which are replaced periodically. Seals on button traps require similar maintenance. These are mainly sources of liquid leaks. Pumps : Pump seals should be inspected and properly maintained to prevent liquid leaks. 35 ------- Base tanks and solvent storage tanks : These should be properly vented to water-cooled condensers or prefer- ably to carbon adsorbers to prevent vapor leaks. Corrosion of tanks and fittings may lead to liquid leaks. Water separators : Solvent loss in a water separator may occur in the water layer as a result of a lint— clogged vent or corrosion in the line leading to the solvent tank. Liquid leaks and solvent loss may occur. Filter sludge recovery : The muck should be cooked down in such a way as to maximize perc recovery. The perc content should be determined according to the standard ANSI method for determination of dilution of gasoline engine crackcase 011.26 Distillation unit : The distillation unit should be properly operated and vented to a condenser or an activated carbon adsorption unit to prevent vapor leaks. The unit must be operated and maintained in such a way as to prevent liquid leaks and solvent loss. Diverter valves : These valves must be inspected and maintained to prevent liquid leaks. Saturated lint from lint basket : All lint traps should be inspected and cleaned out daily. Cartridge filters : Spent cartridge filters should be drained for 24 hours before disposal. They can be a source of liquid solvent loss. Lint accumulation at various points in the drycleaning system may cause undue loss of perc in vapor form. A clogged lint bag (used in removing lint from recirculating air during drying) reduces the air flow and the amount of solvent recovered. Lint should be removed from the bags twice daily, and the bags should be drycleaned twice monthly to remove grease buildup, which tends to mat the lint and cause undue resistance to air flow. 8 Lint buildup on condenser and heating units reduces the cooling and heating capacities of these units and thus reduces solvent recovery during the drying phase. Consequently, more perc is vented during aeration, and more is retained in the clothes. Condenser and heating units should be inspected, and lint buildup removed at least once every 6 months. Accumulation of lint at air inlet and outlet valves (dampers), may prevent 36 ------- them from seating properly during the drying cycle and thus cause vapor losses. FACTORS AFFECTING ENFORCEMENT OF REGULATIONS The CTG’ that specifies RACT for control of emissions from perc dry cleaning systems specifically recommends the use of activated carbon adsorption for control of perc in the dryer exhaust during the aeration cycle. The subsequently promulgated regulations have additionally allowed the use of “equally effec- tive control devices.” Although the CTG does not describe equal- ly effective control devices, some are mentioned here as an aid to EPA in investigations of the effectiveness of such devices. These systems utilize refrigeration to temperatures as low as —29°C (-20°F) as a means of condensing perc from the air stream recirculated during the aeration phase of the cleaning cycle. The manufacturers/distributors of these refrigeration systems are Spencer America Corporation and Kleen-Ri.te, Inc., both of St. Louis, Missouri. It is emphasized that, unlike carbon adsorption systems, these devices recirculate the air during aeration in refrigera- tion systems. In adsorption systems fresh air is blown through the clothes (once-through). This apparently renders carbon adsorption technically more versatile than refrigeration, espe- cially in transfer systems, because the adsorber can be used in recovery of perc from vents, distillation units, floor pickup points, etc. Conceptually, refrigeration systems may be used in these extended applications, but the technical and economic feasibility is yet to be determined. Perc concentrations in the air vented through well operated activated carbon systems during aeration have been consistently much lower than 100 ppm.’ 7 ’’ 8 ’ 19 ’ 20 ’ 21 The regulations specify a 100 ppm limit because enforcement officials regard it as ample indication of breakthrough. Although accurate methods are avail- able for determination of perc at the specified concentration, 37 ------- there are apparently no relatively inexpensive devices for deter- mination of continuous compliance with the standard. EPA is currently involved in development of a reference method for determination of perc in the concentration ranges of interest. The availability and cost of such a device will strongly affect future compliance monitoring activities. Although the currently available gas chromatographic methods are technically adequate for determination of initial and continuous compliance, the costs of operating such a monitoring device are burdensome to industri- al and commercial establishments. Furthermore, such establish- ments are not likely to employ persons capable of calibrating, operating, and maintaining such detection devices. For purposes of enforcement, it may be feasible to establish relatively simple “indicators” with which enforcement officials can determine whether the adsorbers are effective in removing perc vapors. Such indicators would be, for example, observation of the weight (or volume) of perc obtained after each desorption of the carbon bed. Such an observation, however, is an indicator only when all key maintenance and housekeeping practices are followed. For example, the volume of perc obtained after each desorption is not a true indicator when the air inlet and outlet dampers do not seat properly because of defective gaskets or lint accumulation. The regulations call for the immediate repair of all system components found to be leaking liquid perc. Compliance with this stipulation is generally easier for industrial sources than for commercial ones. The larger industrial establishments usually employ personnel who are trained in the maintenance of the dry- cleaning system. Commercial drycleaning systems are less likely to employ such personnel, and because their employees are usually involved chiefly in system operation they are more likely to emphasize “production” rather than maintenance. The allowable perc contents in residues from muck cooking and distillation operations are 25 and 60 kg perc per 100 kg of wet waste material, respectively. Although relatively few data are available on the perc separation and recovery capabilities of 38 ------- muck cookers and distillation units, measurements taken on behalf of EPA indicate that well operated systems can achieve much lower perc contents in the residues from these units. Perc contents of the order of a few percent are reported. 17 The regulations do not comment on residual perc in the carbon that is removed from a carbon adsorber and replaced. Activated carbon vendors all agree that the actual adsorption capacity of the carbon is 60 percent by weight; however, only 20 percent by weight is the useful capacity (that which can be desorbed). The implication, therefore, is that the carbon will contain 40 percent by weight, or 40 kg perc per 100 kg of carbon, at the time of disposal. It is estimated that the average ser- vice life of activated carbon is 3 to 5 years. It may be neces- sary to require disposal of the carbon in sealed containers to prevent release of perc to the atmosphere after disposal. The regulations call for draining of all filtration car- tridges in their housing for at least 24 hours to minimize the perc contents. Where multi-element solvent filtration systems are available (as is likely in commercial establishments) drain- ing of spent cartridges for 24 hours is feasible. Coin-operated filtration systems, however, are usually single—element systems, and the 24-hour drainage requirement may thus be a hardship. A double-bucket device with a lid may serve for drainage of the filter cartridges without unacceptable perc emissions. Further removal of perc from the cartridges may be effected by drying with hot air in an oven-type device that is marketed for this purpose. It is also feasible to use the tumbler of a dryer to dry the cartridges by holding the wheel stationary. The regulations do not specifically require the drying of cartridges, which is left to the discretion of the operator. Difficulties for enforcement officials could arise from the regulations pertaining to (1) use of a properly functioning carbon adsorber, (2) limit of emissions from the dryer control device to 100 ppm, (3) repair of all components found leaking liquid, and (4) draining and drying of filtration cartridges. 39 ------- Difficulties with the first two items are the lack of a rela- tively inexpensive continuous monitor of perc in the concentra- tion range of 10 to 200 ppm and the lack of a program for demon- stration of the adequency of control equipment. Difficulties with the latter two involve the time required for enforcement officials to identify leaky components and to determine that filtration cartridges are drained for 24 hours. Such enforcement actions may be impractical when the total number of sources is between 33,000 and 36,000 nationwide. The difficulties mentioned above may be circumvented by modifying the regulations to include a specified rate of solvent consumption (called a mileage standard). For industrial and commercial establishments the standards for rate of solvent consumption would be based on data obtained from well-operated systems with carbon adsorbers. Such rates, as given in the CTG, 1 are expected to be in the range of 2 to 5 kg perc per 100 kg clothes; the PEDC0 study, however indicates that emission rates from the well-operated plant may be as high as 8 kg perc per 100 kg clothes. For coin-operated establishments the performance standard would be in terms of kilograms of perc consumed in every 10 (or 100) cleaning cycles that the machine performs. For commercial and industrial establishments the reporting requirements with the “mileage standard would be a quarterly (or monthly) submittal of data on total weight of clothes cleaned and amount of perc consumed. For coin-operated systems the require- ments would be the same except that total nunibex f cycles (based on total receipts) would be reported instead of weight of cloth- ing. The reported data on solvent consumption could be verified by sales information from solvent manufacturers and distributors. Data on weight of clothing drycleaned could be verified by esti- mates of number of loads run in machines of given capacity. Although such estimates may not be accurate, approximate agree- ment with the reported value of clothes processed would enhance the credibility of the latter. 40 ------- Officials of the South Coast Air Quality Management District in Los Angeles indicate a preference for regulations based on mileage criteria. The California Air Resources Board, however, has stated that such a regulation is unenforceable because an establishment’s records cannot legally be used in citing the establishment for a violation. The legality of such use of records to enforce mileage criteria should be investigated. The regulation exempts from installing carbon adsorbers or equivalent technology any facilities that are coin-operated, have space limitations, or lack the steam capacity for desorption of the carbon adsorber. An alternative approach might be to cate- gorize drycleaning facilities into ranges of annual perc consump- tion. All drycleaners with annual consumption below a certain level would be exempt from installing a carbon adsorber. A similar approach has been used in California in enforcement of the petroleum solvent regulation. The advantage of such an approach is that it concentrates on the larger perc emission sources having substantial impact on the overall perc emissions and exempts the truly small sources, with probably insignificant perc emissions, for which installation of the required controls may be ecohomically prohibitive. 41 ------- SECTION 4 METHODS OF IDENTIFYING EMISSION SOURCES AND QUANTIFYING EMISSIONS SOURCES OF INFORNATION After investigating a variety of data sources for demograph- ic information on coin-operated, commercial, and industrial drycleaners, we determined that a Bureau of Census (CBP) report 2 and the yellow pages of the telephone directory provided the most useful and complete information. Trade associations, government agencies, and professional business offices were also contacted. All drycleaners are required to report annually their number of employees. The CBP report presents, for each county, the total number of people employed in a given industry (by SIC code), the total payroll for the quarter and the year, and the number of establishments in various employment size catagories. Because the same information is available for every county in the United States, the report can be used to indicate the nationwide distribution of coin-operated, commercial, and industrial dry- cleaners. The CBP report does not provide names of drycleaning estab- lishments. We therefore contacted the Texas Laundry and Dry Cleaning Association, which receives information from the Inter- national Fabricare Institute, a trade association for dryclean— ers, which periodically provides each state association with a list of drycleaners in that state. The IFI list, however, is not available for public use. Moreover, because of the rapid turn- over in ownership of drycleaning establishments, it is not possi- ble for either the state or international association to maintain an up-to-date list. 42 ------- The most complete lists of drycleaners were obtained from two companies, R. L. Polk and National Business Lists, who specialize in publishing lists of businesses. Both companies use the yellow pages in compiling their lists, in which businesses are classified by SIC codes. National Business Lists states that they delete repetitive listings from their lists, and thus help the user to avoid duplication in contacting the businesses. A principal disadvantage in using either the yellow pages or busi- ness lists derived from them is that not all drycleaners have telephones, particularly coin-operated cleaners, and not all dry- cleaners who have a telephone list their business in the yellow pages. SURVEYS OF DALLAS AND HANILTON COUNTIES As the basis for a nationwide projection for the drycleaning industry, we studied in detail two metropolitan areas: Dallas County, Texas, and Hamilton County, Ohio. Names, addresses, and telephone numbers of drycleaners were obtained from the yellow pages. Coin-operated cleaners are listed under “Cleaners-Self Service”, and tlLaundriesself Service.” Commercial drycleaners generally appear under the heading “Cleaners.” Duplicate list- ings for some establishments are found under “Hat Cleaners,” “Leather Cleaning,” “Fur Cleaning,” or “Laundries.” Industrial cleaners are listed under “Uniform Rental,” or occasionally “Tuxedo Rental.” PEDC0 investigators telephoned the cleaners in Dallas and Hamilton Counties listed under each of these headings to ask whether they would supply information for the survey of dryclean- ers. Figure 4-1 illustrates the data sheet used in contacting each drycleaner by telephone. From the information on the data sheet, one can determine perc consumption per quantity of clothes cleaned (or mileage rates). In assessing preliminary responses to the survey, we decided to eliminate questions dealing with sales and payroll figures because these questions generally 43 ------- 1ame: ________________________________ Telephone No. ________________ Mdress: ______________________________ Manager/owner: — County: ______________________________ SIC: __________________________ Type of operation: ______Commercial ______Coin-operated Industrial Solvent used: Qty. of solvent used: _______gallons/day cIrums/rronth Solvent recovery equipment: ________yes no If yes, type No. of machines: Do you plan to increase or decrease the number of machines at your location? Capacity of machines: ___________________________________________ Pounds of clothes processed (per batch or day) _______________________ Process clothes onsite? ___________________________________________ No. of batches per day: No. of employees: — Operating schedule: ___________days/week __________weeks/year Sales: _______________________ Payroll: Comments: Figure 4-1. Drycleaning Industry Data Sheet. 44 ------- evoked a negative reaction. Drycleaners using perc in machines equipped with carbon adsorbers were asked additional questions. The survey of 129 coin-operated laundries and drycleaners showed tha 31 do not have drycleaning equipment. Of the 98 installations with drycleaning equipment, 17 percent reported use of perc ana 54 percent did not know or report the solvent used. These establishments are often attended by persons who are not involved in purchasing solvent or maintaining the machines; in some cases a customer answered the telephone and reported that no attendant was present. Among the drycleaners called, 2 percent use freon as solvent, 8 percent were out of business, 5 percent elected not to answer questions over the telephone, and 14 per- cent did not answer their telephone on several occasions; it is assumed the latter are unattended. With respect to enforcement, one should note also that it is generally not possible to main- tain records of the weight of clothing drycleaned in a given time period at a coin-operated facility. PEDC0 attempted to contact 581 commercial drycleaners listed in the yellow pages. Among these, 5 percent were no longer in business and another 17 percent refused to answer the survey questions bver the telephone. Approximately 21 percent of these commercial drycleaners are pickup stations for other commercial drycleaning plants; the survey questions do not apply to such operations. Eighteen percent of the commercial drycleaners listed in the yellow pages used solvents other than perc. The remaining 39 percent use perc, and of these, approximately 30 percent indicated that they are using a carbon adsorber; another 4 percent said they plan to add a carbon adsorber. The survey of industrial dr ycleaners showed a higher usage of carbon adsorbers. Of 16 industrial drycleaners contacted, 56 percent use perc and 67 percent of those using perc have a carbon adsorber. Of the remaining 44 percent of the industrial dry- cleaners surveyed, 31 percent use solvents other than perc (naph- tha) and 13 percent dealing primarily in laundry services send their drycleaning to a commercial drycleaner. 45 ------- Twenty-six commercial drycleaners in Dallas County using a carbon adsorber were asked additional questions regarding the life of the carbon bed. Results of these inquiries are presented in Table 4 -1. Five of the owners reported operating their ad- sorbers from 3 to 18 years without changing the carbon. Four owners reported changing the carbon every 1, 3, 5, and 10 years. Twelve owners reported that their adsorbers are less than 3 years old and the carbon has not been changed. Five did not give the age of their adsorbers nor indicate how often they change the carbon. None of the owners had tested their adsorbers to deter- mine outlet concentrations of perc. In addition to contacting drycleaners by telephone, we visited several commercial plants to verify data and gain know- ledge of the drycleaning process. RESULTS OF SURVEY Results of the telephone survey of the commercial sector are given in Tables 4-2 through 4-9, categorized in terms of four employment size classifications. An arithmetic average of the emission rate (kg of perc consumed per 100 kg of clothes cleaned) was calculated for each employee classification. These figures were used to calculate industry emissions from the commercial drycleaning sector, as given in Section 2. The survey data, plotted for each employment size category in Figures 4-2 through 4-5 show a wide scatter of the data points. In least-squares regression analysis of each classification, correlation factors ranged from 9 to 50 percent. Because of the poor correlation obtained for a linear fit, arithmetric averages of the emission factors and the clothes processed are reported. The arithmetic average equally weights each data point obtained in the survey. 46 ------- TABLE 4-1. SURVEY OF DALLAS COUNTY COMMERCIAL DRYCLEANERS USING CARBON ADSORBERS Manufacturer Age of Frequency of carbon Desorpti on schedule, times Basis of of adsorber adsorber, yr. replacement per week desorption schedule Hoyt <1 Never Daily Amount of perc recovered Hoyt NAa Never 2-3 Amount of clothes processed Vic 3 Never Daily Amount of perc recovered NAa 10 Once per Daily NAa year Hoyt <1 Never 3 Detection of perc by odor Hoyt <3 Never 2-3 Fogginess of filter gauge Vic >5 After 3 NAa NAa more years Hoyt <1 Never 2 Amount of clothes processed Hoyt 5 Never Daily Manufacturer’s recommendation Hoyt NA 3 Never Daily Manufacturer’s recommendati on Hoyt >5 After 5 Daily Manufacturer’s years recommendation Hoyt 4 Never Daily Manufacturer’s recommendati on Hoyt <1 Never NAa NA 3 Hoyt <1 Never 1 Detection of perc odor Hoyt 1.5 Never 3 Amount of perc recovered a Hoyt 1.5 Never 3 NA Hoyt NAa NA 3 NA 3 NA 3 Hoyt 1-2 Never 2-3 Amount of clothes processed (conti nued) 47 ------- TABLE 4-1. (continued) Desorpt ion Frequency schedule, Manufacturer Age of of carbon times Basis of of adsorber adsorber, yr. replacement per week desorption schedule Hoyt 8 Never 3-5 Amount of clothes processed Vic 1.5 Never Daily NA 3 Vic 1.8 Never 3 Amount of clothes processed Hoyt 0.5 Never Daily Amount of clothes processed Vic 1.5 After 10 years b Detection of perc odor Vic 2 Never Daily Detection of perc odor Hoyt NAa NA 3 NA 3 NA 3 Hoyt >30 NA 3 NA 3 — NA 3 aNA - not available. bReported desorption once per month but stated that it should be done every 2 weeks. 48 ------- TABLE 4-2. COMMERCIAL DRYCLEANERS WiTH 1 TO 4 EMPLOYEES Number employe of es Clothes processed per month Perc consumed per month kg lb kg lb Dallas County 1 1588 3500 612 1350 1 943 2080 319 703 2 2071 4566 246 542 2 1720 3792 383 844 2 4128 9100 747 1757 2 849 1872 214 472 2 1769 3900 246 542 2 3538 7800 201 443 2 3243 7150 663 1462 3 295 650 153 337 3 3243 7150 459 1012 3 1179 2600 338 745 3 1351 2979 93 205 3 2830 6240 307 677 3 1622 3575 367 809 3 2477 5460 612 1350 4 2973 6554 214 472 4 3240 7144 367 809 4 1179 2600 529 1166 4 5897 13000 134 295 4 5405 11916 306 675 4 2359 5200 306 675 4 2359 5200 536 1182 4 1474 3250 306 675 4 5897 13000 676 1490 4 1720 3792 918 2024 4 2654 5850 383 844 4 3928 8660 612 1350 4 2654 5850 918 2024 4 1179 2600 214 472 4 2108 4648 306 675 Total for all drycleaning 77872 171678 12735 28078 Average 2512 5538 411 906 Number of drycleaners surveyed: 31 Average emission rate 20.7 kg perc/100 kg clothes (continued) 49 ------- TABLE 4-2. (continued) Number of employees Clothes processed per month Perc consumed per month kg lb kg lb Hamilton County 1 1237 2728 459 1012 1 786 1732 399 880 1 589 1299 246 542 1 412 909 80 176 1 1768 3897 16 35 1 1178 2598 306 675 2 1768 3897 485 1070 2 707 1559 99 218 2 1178 2598 612 1350 2 3535 7794 102 225 2 3535 7794 306 675 2 2455 5413 918 2024 2 1866 4113 459 1012 2 831 1833 230 507 2 589 1299 159 350 2 2946 6495 306 675 3 1964 4330 204 450 3 1178 2598 338 745 3 1178 2598 319 703 3 3535 7794 319 703 3 2357 5196 121 267 3 2357 5196 214 472 3 471 1039 121 267 3 2357 5196 612 1350 3 1326 2923 612 1350 3 2848 6279 204 450 3 2357 5196 612 1350 3 1473 3248 246 542 4 3535 7794 612 1350 4 3241 7145 1276 2813 4 907 2000 612 1350 4 2946 6495 306 675 4 2062 4547 121 267 4 3064 6755 612 1350 4 2357 5196 239 527 4 982 2165 105 231 4 3142 6928 319 703 4 2946 6495 319 703 4 3339 7361 214 472 (continued) 50 ------- TABLE 4.2 (continued) Number of employees Clothes processed per month Perc consumed per month kg lb kg lb Dallas County 5 3361 7410 337 743 Hamilton County 4 4 4 4 4 4 4 1964 2357 2357 2946 1375 3534 1768 4330 5196 5196 6495 3031 7794 3897 319 159 319 121 928 1276 319 703 351 703 267 2046 2813 703 Total 93603 206371 17280 38102 Average 2035 4486 376 828 Number of drycleaners surveyed: 46 Average emission rate 22.1 kg perc/100 kg clothes Average emission rate for both counties: 21.5 kg perc/100 kg clothes 51 ------- TABLE 4-3. COMMERCIAL DRYCLEANERS WITH S to 9 EMPLOYEES Number of employees Clothes processed per month Perc consumed per month kg lb kg lb Dallas County 5 3361 7410 337 743 5 3241 7145 337 743 5 3241 7145 337 743 5 4717 10400 459 1012 5 3535 7794 612 1350 5 3402 7500 612 1350 5 3440 7584 306 675 5 4717 10400 338 745 5 2654 5850 491 1082 5 3685 8125 459 1012 5 3538 7800 319 703 6 2457 5417 430 948 6 3538 7800 663 1462 6 4128 9100 306 675 6 2359 5200 612 1350 6 3538 7800 1071 2361 6 2750 6062 399 880 7 4423 9750 1228 2707 7 5897 13000 459 1012 7 4128 9100 306 675 7 2064 4550 306 675 7 3440 7583 612 1350 7 5135 11320 918 2024 7 6486 14300 765 1682 7 2948 6500 459 1012 7 3243 7150 398 877 8 5897 13000 367 809 8 4177 9208 1212 2672 8 4717 10400 306 675 8 4717 10400 306 675 8 4717 10400 306 675 8 4717 10400 306 675 9 3784 8342 430 948 9 2160 4763 612 1350 9 5897 13000 612 1350 Total 136848 301698 17996 39677 Average 3910 8620 514 1134 Number of cleaners surveyed. 35 Average emission rate. 14.0 kg perc/100 kg clothes (continued) 52 ------- TABLE 4-3. (continued) Number of employees Clothes processed per month Perc consumed per month kg lb kg lb Hamilton -County 5 3928 8660 1228 2707 5 3241 7145 638 1407 5 4419 9743 1531 3375 5 1964 4330 338 745 5 707 1559 319 703 5 4125 9093 520 1146 5 2357 5196 59 130 5 1178 2598 459 1012 5 3928 8660 306 675 5 2946 6495 306 675 6 1768 3897 204 450 6 2946 6495 1001 2207 6 5892 12990 612 1350 6 2357 5196 338 745 6 1964 4330 612 1350 7 11784 25980 319 703 7 5303 11691 319 703 Total 60807 134058 9109 20083 Average 3577 886 536 1181 Number of drycleaners surveyed. 17 Average emisson rate: 19.4 kg perc/100 kg clothes Average emission rate for both counties: 15.8 kg perc/100 kg clothes 53 ------- TABLE 4-4. COMMERICAL DRYCLEANERS WITH 10 TO 19 EMPLOYEES Number of employees Clothes processed per month kg —— lb Perc consumed per month kg lb Dallas County 10 3784 8342 612 1349 10 5307 11700 612 1349 12 3784 8342 214 472 12 3784 8342 214 472 14 12383 27300 612 1349 14 4324 9533 612 1349 15 2457 5417 306 675 18 7076 15600 918 2024 19 11784 25980 995 2194 Total 54683 120556 5095 11233 Average 6076 13395 566 1248 Number of drycleaners surveyed: 9 Average emission rate: 10.2 kg perc/100 kg clothes Hamilton County 10 1178 2598 408 900 10 11784 25980 1062 2341 10 3388 7469 306 675 10 3535 7794 1276 2813 12 2946 6495 612 1350 12 1375 3031 612 1350 12 6481 14289 765 1687 13 3928 8660 612 1350 Total 34615 76316 5653 12466 Average 4327 9540 707 1558 Number of drycleaners surveyed: 8 Average emission rate: 22 7 kg perc/100 kg clothes Average emission rate for both counties: 16.1 kg perc/100 kg clothes 54 ------- TABLE 4-5. COMMERCIAL DRYCLEANERS WITH 2D EMPLOYEES Number of enipIoyees Clothes processed per month Perc consumed per month kg lb kg lb Dallas 33 40 County 16511 3931 36400 8666 689 765 1519 1687 Total 20442 45066 1454 3206 Average 10221 22533 727 1603 Number Average of drycleaners surveyed: 2 emission rate: 11.8 kg perc/100 kg clothes Dallas 24 County 5892 12990 918 2024 Average emission rate: 15.6 kg perc/100 kg clothes Average emission rate for both counties: 13.1 kg perc/100 kg clothes 55 ------- 0 0 0 0 0 0 0 o o 0 o 2 o0 0 0 0 0 0 0 0 o 0 00 0 0 2002 0 0 0 00 300 Fiaure ft-2. 0 0 0 0 500 700 900 PERC CONSUMED (kg/month) Clothes processed versus perc consumed by commerci0l drycleaners in Dallas and Hamilton Counties (1 to 4 employees). 0 0 0 7,000 6,000 5,000 L i 000 3,000 2,000 1,000 C 0 E w It ) w 0 0 I -n uJ I— 0 -j I -.) 0 0 0 0 0 00 0 0 0 0 0 0 0 0 1,100 56 ------- 11 ,78 I I I ’ I I 1— — I I I I I i 7,000 — U 6,000 — 00 0 0 0 5,000 — 4 0 0 — (1,531) 0 0 i,000 : 0 0 0 — ,ooo 0 0 2,000 0 0 0 1,000 — C I I I I I I I I I I I I 100 300 500 700 900 1,100 PERC CONSUMED (kglnonth) Figure 4-3. Clothes prc,cessed versus oerc consumed by commercial drycl aners in Odilas and Hamilton Counties (5 to 9 employees). 57 ------- 12,383 11,78 14 Figure 4-4. Clothes processed versus perc consumed by commercial drycleaning in Dallas and Hamilton Counties (10 to 19 employees). -c ‘-I C 0 E - C j w ‘I , 411 w a: I - f l w 0 -J 100 300 500 700 900 1,100 PERC CONSUtiED (kg/month) 58 ------- 17,500 I I I I I I 1 I 0 15,000 — 12,500 10,000 — w V) 1) 7,500 — 5;000 0 2,530 — I I I I 100 300 500 700 900 1,100 PERC CONSUMED (kg/month) Figure 4-5. Clothes processed versus perc consumed by commercial drycleaners in Dallas and Hamilton Counties ( 20 employees). 59 ------- RECOMNENDAT IONS In performing a demograhic study of an industry, PEDC0 recommends using the most recent issue of the CBP publication. The yellow’ pages of the telephone directory are for a list of local establishments in a particular industry. A list from an organization that compiles business lists provides the same information as the yellow pages but at an additional cost. The primary advantage of using a commercially generated business list is that is eliminates the risk of duplication in surveying. Two other possible survey techniques are canvassing local areas and mass mailing. Canvassing, however, requires personncl resources, and mass mailing may fail to elicit response from a significant number of establishments. Telephone contact, with followup correspondence as necessary, is the recommended method. 60 ------- REFERENCES 1. U.S. Environmental Protection Agency. Control of Volatile Organic Emissions from Perchioroethylene Dry Cleaning Sys- tems, Guideline Series. Office of Air Quality Planning and Standards. Research Triangle Park, N.C. EPA 450/2-78-050. December 1978. 2. U.S. Department of Commerce. County Business Patterns, 1976. Bureau of the Census, Washington, D.C. 1976. 3. Standard Industrial Classification Manual, 1977 Supplement, Executive Office of the President, Office of Management and Budget. U.S. Department of Commerce, Office of Federal Statistical Policy and Standards. 1972. 4. Gill, W., National Automatic Laundry and Cleaning Council, Chicago, Illinois, Telephone conversation with W. Mason. September 1979. 5. U.S. Environmental Protection Agency. Perchloroethylene Dry Cleaning. Background Information for Proposed Standards Office of Air Quality Planning and Standards. Research Triangle Park, N.C. EPA 450/3-79—029a. August 1979. 6. King,C. Kleen-Rite Inc., St. Louis, M.O. Telephone conver- sation with N. Anastas. September 17, 1979. 7. Personal communication to N. Anastas by an equipment manu- facturer. August 7, 1979. 8. Sluizer, N. Telephone conversation with N. Anastas. Sep- tember 28, 1979. 9. Stoddard, 3. Nultimatic Corp., Palisades Park, N.J. Tele- phone conversation with N. Anastas. October 4, 1979. 10. General Services Administration. Worldwide Geographical Location Codes. Office of Finance, Washington, D.C. Febru- ary 1972. 11. Gill, W. Announcement at NAPCTAC meeting. August 1979. 12. PEDC0 Environmental, Inc. National Ambient Air Quality Standards - States Attainment Status. unpublished survey, 1979. 13. U.S. Environmental Protection Agency. Federal Air Quality Control Regions. Office of Air Programs, Rockville, M.D. January 1972. 61 ------- 14. Moss, S., Miracle Core Chemical Industries, Inc., Telephone conversation with W. Mason. August 24, 1979. 15. Dow Chemical Company. What Every Drycleaner Should Know About Perchioroethylene. Form No. 100-5437-77. 1977. 16. Watt,’ IV, and W. F. Fisher. Results of Membership Survey of Dry Cleaning Operations. IFI Special Reporter No. 3-1, January-February 1975. EPA 450/3-79-029a. 1975. 17. Kleeburg, C. F. Letter to J. F. Durham. Dry Cleaning Plant Test at Texas Industrial Services, San Antonio, Tx. May 14, 1976. 18. Siu, R. Cintas Welcomes OSHA-EPA is Impressed. Textile Retail. July 1979. 19. U.S. Environmental Protection Agency. Air Pollution Emis- sion Test - Westwood Cleaners, Kalamazoo, M.I. Office of Air and Waste Management, Office of Air Quality Planning and Standards. Research Triangle Park, N.C. Report No. 76—DRY—3. June 25, 1976. 20. Air Pollution Emission Test - Hershey Drycleaners and Laun- dry, Hershey, P.A., Report No. 76-Dry-l, Contract No. 68—02—1400, Task No. 21. 21. Air Pollution Emission Test - Texas Industrial Services, San Antonio, Tx. Contract No. 68-02-1403, Task No. 21, June 25, 1976. 22. Measurement of Volatile Organic Compounds. Guideline Ser- vices No. 450/2—78041. 23. Mantell, C. L. Carbon and Graphite Handbook. Interscience Publishers, New York. 1968. 24. Richards, D. W., and K. S. Surprenant. Study to Support New Source Performance Standards for Solvent Metal Cleaning Operations. Prepared for U.S. Environmental Protection Agency. Office of Air Quality Planning, Contract No. 68-02-1329, Task No. 9. June 1976. 25. Causes of Excessive Loss of Perchioroethylene. Internation- al Fabricare Institute, Silver Spring, M.D. Bulletin No. 91, 1969. 26. Standard Method of Test for Dilution of Gasoline Engine Crankcase Oils. American National Standards Institute. 62 ------- APPENDIX A INVENTORIES OF COIN-OPERATED, COMNERCIAL AND INDUSTRIAL DRYCLEANING ESTABLISHMENTS AND OF PERC EMISSIONS A-i ------- TABLE A-i. COIN-OPERATED LAUNDRIES AND DRYCLEANERS (SIC 7215) BY EPA REGION 2 Number Number of establishments by employment-size class of . 250 to 499 estab- lish- ments 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 EPA Regions Region I Connecticut 125 113 11 1 Maine 73 66 7 Massachusetts 230 192 29 6 3 New Hampshire 41 37 4 Rhode Island 57 48 8 1 Vermont 32 30 2 Subtotal 558 486 61 7 4 Region II New Jersey 281 243 28 5 5 New York 902 819 51 25 6 Subtotal 1183 1062 79 30 11 Region III Delaware 24 14 5 4 1 District of Columbia 30 24 5 1 Maryland 217 177 31 3 3 3 Pennsylvania 442 361 63 11 6 Virginia 280 241 33 5 1 West Virginia 109 97 ii 1 Subtotal 1102 914 148 24 12 4 (conti nued) ------- TABLE A-i. (continued) EPA Regions Number of estab- lish- ments Number of establishments by employment-size class 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Region IV Alabama 206 183 iG 6 1 Florida 666 593 57 14 2 Georgia 229 199 25 2 3 Kentucky 265 233 29 i 1 Mississippi 148 141 6 1 North Carolina 331 298 25 5 1 2 South Carolina 168 150 13 4 1 Tennessee 280 255 19 5 1 Subtotal 2293 2052 190 38 9 1 3 Region V Illinois 794 622 149 15 7 1 Indiana 489 382 90 16 1 Michigan 592 425 140 24 3 Minnesota 148 121 19 6 2 Ohio 674 540 110 17 7 Wisconsin 225 187 30 5 2 1 Subtotal 2922 2277 538 83 22 2 Region VI Arkansas 146 139 7 Louisiana 132 115 13 2 2 New Mexico 96 72 17 7 Oklahoma 201 184 12 5 Texas 934 864 56 9 3 1 Subtotal 1509 1374 105 23 5 1 (conti nued) ------- TABLE A-i. (continued) Number of estab- lish- 1 to Number 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to 499 EPA Regions ments 19 49 99 249 Region VII Iowa 163 142 15 6 Kansas 169 143 21 5 Missouri 296 254 31 10 1 Nebraska 69 62 7 Subtotal 697 601 74 21 1 Region VIII Colorado 152 131 17 3 1 Montana 46 39 6 1 North Dakota 25 23 1 South Dakota 40 39 1 Utah 68 55 12 1 Wyoming 30 27 2 1 Subtotal 361 314 39 5 2 Region IX Arizona 119 103 12 2 2 California 614 484 91 28 9 Hawaii 38 34 4 Nevada 45 36 8 1 Subtotal 816 657 115 31 11 (continued) ------- TABLE A-i. (continued) EPA Regions Number of estab- lish- ments Number of establishments by employment-size class 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Region X Alaska Idaho Oregon Washington Subtotal Total United States 29 53 109 172 363 11804 17 44 87 137 285 10022 7 8 16 28 59 1408 2 1 5 6 14 276 3 1 4 81 1 1 10 6 1 U ’ ------- TABLE A-2. COMMERCIAL DRYCLEANING PLANTS (SIC 7216, EXCEPT RUGCLEANERS) BY EPA REGION 2 Number of estab- Number of establishments by employment size class 10 20 50 100 250 lish- 1 to 4 5 to 9 to to to to to EPA Regions ments 19 49 99 249 499 Region I Connecticut 346 208 81 45 12 Maine 50 36 4 7 3 Massachusetts 543 309 143 69 18 3 New Hampshire 47 29 10 7 1 Rhode Island 73 39 23 7 2 2 Vermont 33 16 7 8 2 Subtotal 1092 637 268 143 38 5 0• . Region II New Jersey 856 569 193 68 23 1 2 New York 2064 1450 424 145 33 8 4 Subtotal 2920 2019 617 213 56 9 6 Region III Delaware 53 30 11 9 3 District of Columbia 103 50 27 18 8 Maryland 351 145 110 68 28 Pennsylvania 928 510 250 113 48 7 Virginia 554 277 172 74 26 5 West Virginia 126 64 39 16 7 Subtotal 2115 1076 609 298 120 12 (conti nued) ------- TABLE A-2. (continued) EPA Regions Number of estab- lish- nients Number of establishments by employment-size class 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Region IV Alabama 400 238 98 47 14 2 1 Florida 661 347 201 82 28 2 1 Georgia 626 327 183 89 23 4 Kentucky 298 174 86 23 13 2 Mississippi 275 158 87 22 8 North Carolina 333 153 101 61 15 3 South Carolina 50 34 11 2 2 1 Tennessee 397 206 111 59 20 1 Subtotal 3040 1637 878 385 123 15 2 Region V Illinois 919 481 247 141 41 5 4 Indiana 440 268 101 51 16 2 2 Michigan 754 411 212 102 26 2 1 Minnesota 254 139 69 29 15 2 Ohio 977 555 246 118 51 6 1 Wisconsin 336 213 84 27 8 3 1 Subtotal 3680 2067 959 468 157 20 9 Region VI Arkansas 215 122 56 32 3 2 Louisiana 365 211 103 40 9 2 New Mexico 88 54 18 12 3 1 Oklahoma 264 180 51 20 9 3 1 Texas 1360 821 287 169 68 13 2 Subtotal 2292 1388 515 273 92 21 3 (continued) ------- TABLE A-2. (continued) EPA Regions Number of estab- lish- ments Number of establishments by employment-size class 1 ,to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 • 250 o 499 Region VII Iowa 206 134 42 20 9 1 Kansas 229 156 54 15 4 Missouri 432 258 114 45 14 1 Nebraska 133 82 32 11 7 Subtotal 1000 630 242 91 34 2 Region VIII Colorado 294 172 86 22 13 1 Montana 67 42 17 6 2 North Dakota 50 34 11 2 2 1 South Dakota 44 28 9 6 1 Utah 87 46 27 7 6 1 Wyoming 37 22 11 4 Subtotal 579 344 161 47 24 3 Region IX Arizona 134 80 25 17 10 2 California 1826 1081 481 200 54 8 2 Hawaii 37 15 10 5 5 1 Nevada 52 17 12 17 6 Subtotal 2049 1193 528 239 75 11 3 (continued) ------- TABLE A-2. (continued) EPA Regions Number{ of estab- lish- ments Number of establishments by erriployrnent-size class T 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 250 to to 249 499 Region X Alaska Idaho Oregon Washington Subtotal Total United States 17 61 175 309 562 - 19953 9 36 126 202 373 11616 2 20 33 75 130 5106 2 4 12 26 44 2284 1 1 4 5 11 755 2 1 3 106 -— 1 1 26 —- ‘ 0 ------- TABLE A-3. COIN-OPERATED LAUNDRIES AND DRYCLEANERS (SIC 7215) IN NONATTAINMENT AREAS BY STATE, 1 g 76 2 ’ 2 ’L3 Number of estab- lish- ments 1 to Number 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to 19 49 99 249 499 EPA Regions Region I Connecticut 10 1 1 2 2 3 1 Maine 2 1 1 Massachusetts 23 3 1 3 8 5 2 New Hampshire 2 2 Rhode Island 2 2 Vermont 1 1 Subtotal 40 4 2 6 12 12 3 Region II New Jersey 28 6 3 4 8 4 3 New York 63 11 9 7 19 15 2 Subtotal 91 17 12 11 27 19 5 Region III Delaware 1 1 District of Columbia Maryland 18 4 1 1 3 6 3 Pennsylvania 42 8 3 4 10 15 2 Virginia 18 2 2 4 3 4 3 West Virginia 4 1 1 2 Subtotal 83 15 6 9 17 28 8 (continued) ------- TABLE A-3. (continued) Number Number of establishments by employment-size class of estab- lish- ments 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 EPA Regions Region IV Alabama 16 2 3 7 3 1 Florida 35 2 4 5 9 9 6 Georgia 33 6 4 5 9 7 2 Kentucky 21 3 6 6 5 1 Mississippi 10 3 1 2 2 1 1 North Carolina 28 3 4 12 5 3 1 South Carolina 11 2 2 4 2 1 Tennessee 28 4 2 3 9 6 4 Subtotal 182 22 14 30 58 38 19 1 Region V Illinois 45 8 2 5 15 10 5 Indiana 25 2 5 4 8 3 2 1 Michigan 46 6 6 14 11 3 5 1 Minnesota 11 3 3 2 1 2 Ohio 54 8 9 9 10 8 10 Wisconsin 11 3 2 2 3 1 Subtotal 192 30 27 34 47 27 25 2 Region VI Arkansas 14 2 2 8 2 Louisiana 17 1 2 7 5 1 1 New Mexico 5 1 1 3 Oklahoma 14 1 2 2 5 4 Texas 62 5 5 5 22 18 6 1 Subtotal 112 9 8 11 43 32 7 2 (continued) ------- TABLE A-3. (continued) Number of estab- Number of establishments by employment-size class 10 20 50 100 250 lish- 1 to 4 5 to 9 to to to to to EPA Regions nients 19 49 99 249 499 Region VII Iowa 12 2 3 2 2 2 1 Kansas 15 2 5 2 2 4 Missouri 18 3 1 7 5 2 Nebraska 8 3 1 3 1 Subtotal 53 10 8 6 14 12 3 Region VIII Colorado 11 3 1 1 2 4 Montana North Dakota South Dakota Utah 3 1 1 1 Wyoming Subtotal 14 4 2 1 3 4 Region IX Arizona 10 2 1 3 3 1 California 103 16 3 12 34 24 14 Hawaii Nevada 5 1 1 3 Subtotal 118 19 4 40 27 13 15 ------- TABLE A-3. (conti ntied’) - EPA Regions Number of estab- lish- ments Number of establishments by employment-size class 1 to 4 , 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Region X Alaska Idaho Oregon Washington Subtotal Total United States 10 11 21 906 2 1 2 1 4 2 134 85 5 1 7 5 8 126 269 199 1 1 2 87 6 ------- TABLE A-4. TOTAL NUMBER COIN-OPERATED LAUNDRIES AND DRYCLEANERS (SIC 7215) IN NONATTAINMENT AREAS BY STATE, 1976 2 ’12 ’L3 Number of estab- lish- Number of establishments by employment-size class 1 to 4 5 to 9 10 to 20 to 50 to 100 to 250 to State ments 19 49 99 249 499 Alabama 69 54 11 4 Alaska Arizona 16 14 2 Arkansas California 342 252 59 23 7 Colorado 50 37 10 2 1 Connecticut 125 113 11 1 Delaware 12 4 4 4 District of Columbia 30 24 5 1 Florida 387 340 39 6 2 Georgia 58 51 7 Hawai i Idaho Illinois 521 398 106 10 7 Indiana 198 140 48 9 1 Iowa 10 8 1 1 Kansas 32 28 1 3 Kentucky 39 29 9 Louisiana 22 20 2 Maine 18 14 4 (conti nued) ------- TABt E A-4. (continued) State Number of estab- lish- ments Number of establishments by employment-size class 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Maryland 86 66 15 1 2 2 Massachusetts 230 192 29 6 3 Michigan 390 272 95 20 3 Minnesota 27 13 8 4 2 Mississippi Missouri 97 78 11 8 Montana Nebraska Nevada 37 30 6 1 New Hampshire ui New Jersey 281 243 28 5 5 New Mexico 29 23 4 2 New York 902 819 51 25 6 North Carolina 21 18 1 2 North Dakota Ohio 303 224 60 14 5 Oklahoma 84 71 9 4 Oregon 29 19 7 2 Pennsylvania 442 361 63 11 6 Rhode Island 57 48 8 1 South Carolina 24 19 5 South Dakota Tennessee 77 65 9 3 Texas 500 454 35 6 3 Utah 30 24 6 (conti nued) ------- TABLE A-4. (continued) State Number of estab- lish- ments Number of establishments by employment-size class 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 27 70 13 39 5724 18 53 10 30 4676 7 10 2 6 792 1 1 6 1 1 3 188 59 5 3 1 ------- TABLE A-5. COMMERCIAL DRYCLEANING PLANTS (SIC 7216, EXCEPT RUGCLEANERS) IN NONATTAINMENT AREAS BY STATE 2 ’ 12 ’’ 3 Number of estab- lish- 1 to Number 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to State ments 19 49 99 249 Alabama 148 36 37 26 9 Alaska Arizona 30 19 5 3 3 Arkansas 40 10 14 11 3 2 California 1383 779 376 169 49 8 2 Colorado 220 123 71 16 9 1 Connecticut 346 208 81 45 12 Delaware 39 20 9 9 1 District of Columbia 103 50 27 18 8 Florida 434 220 135 53 23 2 Georgia 346 179 103 48 12 4 Hawaii Idaho Illinois 715 329 209 128 40 5 4 Indiana 200 112 44 32 8 2 2 Iowa 52 23 12 10 7 Kansas 95 53 30 11 1 Kentucky 130 61 45 12 11 1 Louisiana 201 108 58 28 5 2 Maine 15 8 2 3 2 (continued) ------- TABLE A-5. (continued) Number of estab- lish- 1 to Number 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to State ments 19 49 99 249 499 Maryland 217 78 73 46 20 Massachusetts 543 309 143 69 18 3 1 Michigan 614 320 181 88 22 2 1 Minnesota 154 65 54 22 11 2 Mississippi Missouri 179 88 54 27 9 1 Montana 17 12 4 1 Nebraska 43 25 6 7 4 1 Nevada 46 16 11 13 6 New Hampshire 29 16 6 6 1 New Jersey 856 569 193 68 23 1 2 New Mexico 31 15 8 7 1 New York 2064 1450 424 145 33 8 4 North Carolina 62 30 19 7 5 1 North Dakota Ohio 769 421 194 101 48 4 1 Oklahoma 109 56 30 11 8 3 1 Oregon 97 59 25 10 3 Pennsylvania 928 510 250 113 48 7 Rhode Island 73 39 23 7 2 2 (continued) ------- I- ’ TABLE A-5. (continued) State Number of estab- lish- ments Number of establishments by employment-size class • 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 South Carolina South Dakota Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 83 206 757 68 14 309 188 18 178 13149 16 87 392 31 5 149 123 3 110 7372 34 59 176 24 3 95 46 10 43 3446 24 42 121 7 5 46 16 1 15 1647 7 17 53 5 1 14 3 4 7 576 2 1 13 1 5 2 85 2 1 23 ------- Alabama Alaska Arizona Arkansas Cali fornia Colorado Connecticut Delaware District Florida Georgia Hawaii Idaho Illinois Indiana Iowa Kansas Kentucky Louisiana Maine TABLE A-6. INDUSTRIAL LAUNDERIES (SIC 7218) IN NONATTAINMENT AREAS BY STATE, 19762 12 13 5 11 8 1 3 3 3 1 Number of estab lish Number of establishments by employment size class 1 to 4 5 to 9 10 to 20 to 50 to 100 to 250 to State ments 19 49 99 249 499 0 of Columbia 8 1 4 77 4 10 1 29 12 32 8 2 2 22 1 3 1 9 4 10 2 13 1 1 1 2 6 1 3 1 3 3 1 1 1 2 9 2 4 2 1 3 1 4 2 18 2 2 7 1 8 3 1 4 1 1 12 1 5 2 5 1 1 1 1 (conti nued) ------- TABLE A-6. (continued) Number of estab- lish- Number of establishments by employment-size class • 1 to 4 5 to 9 10 to 20 to 50 to 100 to 250 to State ments 19 49 99 249 499 Maryland 5 2 2 1 Massachusetts 23 3 1 3 8 5 2 Michigan 32 4 3 8 9 2 5 Minnesota 5 2 1 2 Mississippi Missouri 6 1 1 3 1 Montana Nebraska 2 2 Nevada 3 3 New Hampshire 2 2 New Jersey 28 6 3 4 8 4 3 New Mexico 1 1 New York 63 11 9 7 19 15 2 North Carolina 5 2 1 1 1 North Dakota Ohio 44 6 5 7 9 1 10 Oklahoma 10 1 1 4 4 Oregon 5 1 2 1 1 Pennsylvania 42 8 3 4 10 15 2 Rhode Island 2 2 (conti nued) ------- TABLE A-6. (continued) F ’ ) F ’ ) State Number of estab- lish- ments Number of establishments by employment-size class — —_________ ito 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 South Carolina South Dakota Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 2 18 36 2 7 1 4 559 2 2 1 74 1 2 41 1 1 3 65 5 12 1 2 1 154 1 6 11 4 2 151 3 5 1 1 1 69 1 5 ------- TABLE A-7. COIN-OPERATED LAUNDRIES AND DRYCLEANERS (SIC 7215) IN ATTAINMENT AREAS BY STATE, 1976 Number of Number of establishments by ernpl oyment-s ize class 20 50 100 250 estab- to lish- 1 to 4 5 to 9 to to to State merits 19 49 99 249 499 Alabama 137 129 5 2 1 Alaska 29 17 7 2 3 Arizona 103 89 10 2 2 Arkansas 146 139 7 California 272 232 32 5 2 Colorado 102 94 7 1 Connecticut Delaware 12 10 1 1 District of Columbia Florida 279 253 18 8 Georgia 171 148 18 2 3 Hawaii 38 34 4 Idaho 53 44 8 1 Illinois 273 224 43 5 Indiana 291 242 42 7 Iowa 153 134 14 5 Kansas 137 115 20 2 Kentucky 226 204 20 1 Louisiana 110 95 13 2 Maine 55 52 3 (conti nued) ------- TABLE A-7. (continued) Number of estab- lish- Number of establishments by employment-size class 1 to 4 5 to 9 10 to 20 to 50 to 100 to 250 to State ments 19 49 99 249 499 Maryland 131 111 16 2 Massachusetts Michigan 202 153 45 4 Minnesota 121 108 11 2 Mississippi 148 141 6 1 Missouri 199 176 20 2 Montana 46 39 6 Nebraska 69 62 7 Nevada 8 6 2 New Hampshire 41 37 4 New Jersey New Mexico 67 49 13 5 New York North Carolina 310 280 24 3 1 2 North Dakota 25 23 1 Ohio 371 316 50 3 2 Oklahoma 117 113 3 1 Oregon 80 68 9 3 Pennsyl vani a Rhode Island (conti nued) ------- TABLE A-i. (continued) U, State Number of estab- lish- ments Number of establishments by employment-size class • 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 South Carolina South Dakota Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 144 40 203 434 38 32 253 102 96 186 30 6080 131 39 190 410 31 30 223 84 87 157 27 5346 8 1 10 21 6 2 26 18 9 24 2 616 4 2 3 1 4 2 1 88 1 1 2 22 1 5 3 ------- TABLE A-8. COMMERCIAL DRYCLEANERS (SIC 7216) IN ATTAINMENT AREAS BY STATE, 1976 Number of estab- lish- rnents 1 to Number 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to 19 49 99 249 499 State Alabama 252 162 61 21 5 2 Alaska 17 9 2 2 1 2 Arizona 104 61 20 14 7 2 Arkansas 175 112 42 21 California 443 302 105 31 5 Colorado 74 49 15 6 4 Connecti cut Delaware 14 10 2 2 District of Columbia Florida 227 127 66 29 5 Georgia 280 148 80 41 11 Hawaii 37 15 10 5 5 1 Idaho 61 36 20 4 1 Illinois 204 152 38 13 1 Indiana 240 156 57 19 8 Iowa 154 111 30 10 2 1 Kansas 134 103 24 4 3 Kentucky 168 113 41 11 2 1 Louisiana 164 103 45 12 4 Maine 35 28 2 4 1 (continued) ------- TABLE A-B. (continued) Number of estab- lish- Number of establishments by employment-size class 1 to 4 5 to 9 10 to 20 to 50 to 100 to 250 to State ments 19 49 99 249 499 Maryland 134 67 37 22 8 Massachusetts Michigan 140 91 31 14 4 Minnesota 100 74 15 7 4 Mississippi 275 158 87 22 8 Missouri 253 170 60 18 5 Montana 50 30 13 5 2 Nebraska 90 57 26 4 3 New Hampshire 18 13 4 1 New Jersey New Mexico 57 39 10 5 2 New York North Carolina 612 316 191 78 22 5 North Dakota 50 34 11 2 2 Ohio 208 134 52 17 3 2 Oklahoma 155 124 21 9 1 Oregon 78 67 8 2 1 Pennsylvani a Rhode Island (conti nued) ------- TABLE A-8. (continued) State Number of estab- lish- ments Number of establishments by employment-size class — 10 20 50 100 250 1 to 4 5 to 9 to to to to to 19 49 99 249 499 South Carolina South Dakota Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 250 44 191 603 19 19 245 121 108 158 37 6804 137 28 119 429 15 11 128 79 61 103 22 4304 67 9 52 111 3 4 77 29 29 41 11 1660 37 6 17 48 3 28 10 15 12 4 637 8 1 3 15 1 1 12 2 3 1 79 1 1 1 21 3 ------- TABLE A-9. INDUSTRIAL LAUNDERERS (SIC 7218) IN ATTAINMENT AREAS BY STATE, 1976 Number of estab- lish- 1 to Number I 4 5 to of establishments by employment-size class 10 20 50 100 250 9 to to to to to State ments 19 49 99 249 499 Alabama 8 2 1 3 1 Alaska Arizona 9 2 1 3 3 Arkansas 10 2 2 6 California 26 3 3 16 2 2 Colorado 7 2 1 1 3 Connecti cut Delaware District of Columbia Florida 6 1 1 1 2 Georgia 21 4 1 5 8 3 Hawaii Idaho Illinois 13 2 1 3 7 Indiana 17 2 4 3 5 1 2 Iowa 12 2 3 2 2 2 Kansas 10 2 4 2 1 1 Kentucky 10 3 3 2 2 Louisiana 9 1 6 2 Maine 1 1 (conti nued) ------- TABLE A-9. (continued) Number of estab- Number of establishments by employment-size class 10 20 50 100 250 lish- 1 to 4 5 to 9 to to to to to State ments 19 49 99 249 499 Maryland 13 4 1 1 1 4 2 Massachusetts Michigan 14 2 3 6 2 1 Minnesota 6 1 3 2 Mississippi 10 3 1 2 2 1 Missouri 12 2 1 6 2 Montana Nebraska 6 3 1 1 1 Nevada 2 1 1 New Hampshire 0 New Jersey New Mexico 4 1 1 2 New York North Carolina 23 1 4 11 4 2 North Dakota Ohio 10 2 4 2 1 1 Oklahoma 4 1 1 1 1 Oregon 5 1 1 3 Pennsyl vani a Rhode Island (conti nued) ------- TABLE A-9. (continued) State Number of estab- lish- ments Number of establishments by employment-size class I 1 to 4 5 to 9 10 to 19 20 to 49 50 to 99 100 to 249 250 to 499 Maryland South Carolina South Dakota Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming United States 13 9 10 26 1 1 11 10 4 7 347 4 2 2 3 2 2 1 3 60 1 1 3 1 2 1 2 44 1 1 2 2 4 61 1 4 4 10 1 7 1 1 115 4 1 7 1 2 1 48 2 1 1 1 2 18 1 ------- TABLE A-lU. 1976 PERC EMISSIONS BY EPA REGIONS (Mg) EPA Region Coin-op Commercial Industrial Region I Connecticut 174.2 1729.1 149.8 Maine 101.7 250.6 30.0 Massachusetts 320.6 2743.5 344.6 New Hampshire 57.1 233.0 30.0 Rhode Island 79.4 371.6 30.0 Vermont 44.6 180.9 15.0 Subtotal 777.6 5508.7 599.4 Region II New Jersey 391.6 4111.2 419.5 New York 1257.1 9706.5 943.8 Subtotal 1648.7 13817.7 1363.3 Region III Delaware 33.4 276.8 15.0 District of Columbia 41.8 558.0 Maryland 302.4 1946.1 269.7 Pennsylvania 616.0 4780.0 59.9 Virginia 390.2 2887.7 269.7 West Virginia 151.9 653.7 59.9 Subtotal 1535.7 11102.3 1243.5 Region IV Alabama 287.1 2005.7 239.7 Florida 928.2 3386.3 524.3 Georgia 319.2 3221.5 494.4 Kentucky 369.3 1483.4 314.5 Mississippi 206.3 1345.6 149.8 North Carolina 461.3 3470.7 419.5 South Carolina 234.1 1781.9 164.8 Tennessee 390.2 2068.3 419.5 Subtotal 3195.7 18763.4 2726.6 Region V Illinois 1106.6 4799.3 674.2 Indiana 681.5 2204.5 374.5 Michigan 825.1 3834.4 689.1 Minnesota 206.3 1314.1 164.8 Ohio 939.4 5011.7 809.0 Wisconsin 313.6 1633.8 164.8 Subtotal 4072.5 18797.8 2876.4 A-32 (conti nued) ------- TABLE A—1O. (continued) EPA Region Coin-•op Commercial Industrial Region VI Arkansas 203.5 1079.0 209.7 Louisiana 184.0 1809.2 254.7 New Mexico 133.8 444.3 74.9 Oklahoma 280.1 1284.7 209.7 Texas 1301.7 6946.0 928.8 Subtotal 2103.1 11563.2 1677.8 Region VII Iowa 227.2 1017.9 179.8 Kansas 235.5 1075.1 224.7 Missouri 412.5 2137.1 269.7 Nebraska 96.2 665.2 119.9 Subtotal 971.4 4895.3 794.1 Region Viii Colorado 211.8 1457.9 164.8 Montana 64.1 325.7 North Dakota 34.8 242.2 South Dakota 55.7 216.3 Utah 94.8 451.2 44.9 Wyoming 41.8 177.4 Subtotal 503.0 2870.7 209.7 Region IX Arizona 165.9 704.2 149.8 California 855.7 9066.6 1543.1 Hawaii 53.0 220.1 Nevada 62.7 316.5 74.9 Subtotal 1137.3 10307.4 1767.8 Region X Alaska 40.4 102.0 Idaho 73.9 291.9 Oregon 151.9 820.0 149.8 Washington 239.7 1474.7 164.8 Subtotal 505.9 2688.6 314.6 Total 16450.9 100315.1 13573.2 A-33 ------- TABLE A-il. 1976 PERC EMISSION iN NONATTAINMENT AREAS, METRIC TONS State Coin_opt Commercial Industrial Alabama 96.2 I 785.9 119.9 Alaska - — -- —- Arizona 22.3 156.3 15.0 California 476.6 6995.9 1153.6 Colorado 69.7 1093.7 59.9 Connecticut 174.2 1729.1 149.8 Delaware 16.7 205.2 15.0 District of Columbia 41.8 558.0 -- Florida 539.4 2256.6 434.5 Georgia 80.9 1785.0 179.8 Hawaii -- -- — - Idaho -- -- -- Illinois 726.1 3868.3 479.4 Indiana 276.0 1044.8 119.9 Iowa 13.9 300.1 -- Kansas 44.6 465.3 74.9 Kentucky 54.4 692.9 164.8 Louisiana 30.7 1022.1 119.9 Maine 25.1 85.3 15.0 Maryland 119.9 1236.5 74.9 Massachusetts 320.6 2743.5 344.6 1ichigan 543 6 3155.0 479.4 Minnesota 37 6 839.2 74.9 Mississippi -- -- -- Missouri 135.2 941.1 89.9 Montana -- 77.7 -- Nebraska -- 235 4 30.0 Nevada 51.6 277.9 44.9 New Hampshire -- 151.1 30.0 New Jersey 391.6 4111.2 419.5 New Mexico 40.4 164.7 15.0 New York 1257.1 9706.5 943.8 North Carolina 29.3 333.5 74.9 North Dakota -- -- —- Ohio 422.3 4013.5 659.2 Oklahoma 117.1 587.0 149 8 Oregon 40 4 476 8 74.9 Pennsylvania 616.0 4780.0 629.2 Rhode Island 79.4 371.6 30.0 A-i 4 ------- TABLE A-li. (continued) State Coin op Commercial Industrial South Carolina 33.4 507.5 30.0 South Dakota Tennessee 107.3 1152.0 269.7 Texas 696.9 4095.2 539.3 Utah 41.8 363.6 30.0 Vermont 82.7 Virginia 37.6 1634.5 104.9 Washington 97.6 894.4 15.0 West Virginia 18.1 111.4 Wisconsin 54.4 887.3 59.9 Wyoming United States 7977.7 67219.4 8375.0 ------- TABLE A-12. 1976 PERC EMISSIONS IN ATTAINMENT AREAS (Mg) State — Coin op Commercial Industrial Alabama 190.9 1219.8 119.8 Alaska 40.4 102.0 Arizona 143.6 547.9 134.8 Arkansas 203.5 834.9 149.8 California 379.1 2070.7 389.5 Colorado 142.1 364.2 104.9 Connecticut Delaware 16.7 71.6 District of Columbia Florida 388.8 1129.7 89.8 Georgia 238.4 1436.5 314.6 Hawaii 53.0 220.1 Idaho 73.9 291.9 Illinois 380.5 931.0 194.8 Indiana 405.5 1159.7 254.7 Iowa 213.3 717.8 179.8 Kansas 190.9 609.8 149.8 Kentucky 314.9 790.5 149.8 Louisiana 153 3 787.1 134.8 Maine 76.6 165.3 15.0 Maryland 182.5 709.6 194.8 NTa s sac h use t t s Michigan 281.5 679.4 209.7 Minnesota 168.7 474.9 89.9 Mississippi 206.3 1345.6 149.8 Missouri 277.3 1196.0 179.8 Montana 64 1 248.0 Nebraska 96.2 429.8 89.9 Nevada 11.1 38 6 30.0 New Hampshire 57.1 81.9 New Jersey New Mexico 93.4 279.6 59.9 New York North Carolina 432.0 3137.2 344.6 North Dakota 34.8 242.2 Ohio 517.1 998.2 149.8 Oklahoma 163.0 697.7 59.9 Oregon 111.5 343.2 74.9 Pennsylvania Rhode Island (conti nued) A-3G ------- TABLE A-12. (continued) State Coin op Commercial Industrial South Carolina 200.7 1274.4 134.8 South Dakota 55.7 216.3 Tennessee 282.9 916.3 149.8 Texas 604.8 2850.8 389.5 Utah 53.0 87.6 14.9 Vermont 44.6 98.2 15.0 Virginia 352.6 1253.2 164.8 Washington 142.1 580.3 149.8 West Virginia 133.8 542.3 59.9 Wisconsin 259.2 746.5 104.9 Wyoming 41.8 177.4 United States 8473.2 33095.7 5198.2 A-37 ------- |