United States Region VIII Environmental Protection 999 18th St., Suite 500 August 1987 Agency Denver, CO 80202-2405 Office of External Affairs &EPA Mining Wastes In the West Fact Sheet ------- Mining Wastes v>EPA In The West Region VIII Fact Sheet A hard rock mine usually leaves behind large amounts of wastes. In many cases, these wastes are harmless, whether they come from the mining operation directly or from the associated exploration, milling, smelting, or refining. Sometimes, however, they can harm the environment, damage industry, and present risks to human health. For example: • The California Gulch flows through Colorado's Leadville Mining District for about seven and a half miles before joining the Arkansas River. Located by the gulch are numerous abandoned mines, mill tailings piles, and slag piles left over from decades of silver, zinc, and gold mining, milling, smelting, and refining. The environment in the gulch has been seriously affected by contaminants in drainage from the old mines. It has also been affected by the erosion of wastes into surface water, as well as by rain and snow melt seeping through the wastes and running over slag piles. The flow of water from the Yak Tunnel to the gulch, for example, is acidic and contains dissolved iron, lead, manganese, and cadmium. These metals can have impacts on human health. The water also contains sulfates, calcium, and dissolved solids, which can damage the environment and limit downstream water use. Contamination from the gulch has killed fish in the Arkansas River. It threatens livestock and crops grown on land irrigated by river water. • At Smuggler Mountain, near Aspen, Colorado, there are many old silver and lead mines that were active mainly between 1879 and 1920. The mining wastes, mill tailings (400,000 cubic yards, scattered over 75 acres), and smelter by-products left behind at Smuggler Mountain contain high concentrations of lead and other metals potentially hazardous to human health. Some of these wastes have been used as fill material for building foundations and road construction. High concentrations of lead have been found in vegetables grown in soil from the site. • A lead and zinc smelter has operated in East Helena, Montana, since 1888. Throughout its Photograph: Yak Tunnel ------- history, the smelter emitted particles of lead, cadmium, and arsenic to the air. These particles contaminated the soil on which they landed over an area of 8.4 square miles. The contaminants may be swallowed by children playing on this soil, and they may also be eaten by livestock and absorbed by crops. In many cases, as noted, mining wastes do not cause these kinds of problems. People living nearby do not need to be concerned about their health. The mining wastes probably have some environmental effects, but not of great consequence. The purpose of this fact sheet is to explain what makes some mining wastes a problem, but not others. The fact sheet also explains what can be done to reduce or remedy the problems. There are many types of mining wastes, but the focus here is on wastes from mining for metals in the West, as in the three cases above. Surface mining for coal, for example, is not addressed directly here. Contamination of Streams, Ground water, Air — ¦ i i *•», 'r i- tny • ''""i i'i"rMnrTOJiii *)' ' People can breathe dust, drink polluted water, eat contaminated crops. They can also come into direct contact with wastes. WHY CAN MINING WASTES CAUSE PROBLEMS? Mining wastes can cause problems because they may contain metals such as cadmium, arsenic, or lead that can be harmful to human health. These and other contaminants in mining wastes may, in addition, affect the environment. They can cause damage over large areas, making streams and ground water unusable, harming wildlife and natural resources and, in turn, crippling fishing and agricultural industries. There is little risk to health so long as the metal traces and contaminants remain confined to the wastes and do not come into contact with people or the environment. Contaminated dust blown from a waste pile may, however, be breathed by people living nearby. Waste materials may be used in construction or carried to backyards and used in gardens and sandboxes, where children may swallow contaminants. Most important, water ------- from rain or snowmelt can seep through or run off a waste pile and carry contaminants to lakes, rivers, ground water, and pasture lands, damaging the environment and exposing people to hazardous substances through the water they drink (and, to a lesser extent, through the food they eat). Even if human health is not at risk, the ground water may become polluted by dissolved solids and chemicals used in processing. It is important to understand that you cannot tell just by looking at a waste pile or, in most cases, even by knowing its source whether water seeping through the waste is carrying off metals and other contaminants. An overburden pile, a tailings pile, a smelter slag heap or a pile of flue dust that is a problem, in this respect, will look no different from one that is harmless. The difference lies in chemical reactions that may or may not take place in a particular waste pile. Specifically, mining wastes often contain "pyritic" or sulfur-containing minerals (sometimes called "fools gold") that, when exposed to oxygen, water, and bacteria, can form acidic solutions. The acidic solution can mobilize metals remaining in the wastes, causing water flowing through the wastes to pick up higher concentrations of potentially hazardous metals. Depending on the exact chemical nature of a particular waste pile and the ground beneath the pile, however, acid may or may not form, and the waste may or may not present a problem. The way in which the wastes are handled may also be a factor. Sometimes acid can form but be neutralized before the solution presents a problem. There are two noteworthy consequences. First, a waste pile that has been harmless all along may, at some time, undergo changes that cause it to pose risks to human health or the environment. HOW CAN YOU PROTECT YOURSELF? It is easy to protect yourself and safeguard your health, even if you live close to a mining site that has been recognized as a source of contamination. 1 Do not allow your children to play around overburden piles, mill tailings piles, tailings ponds, flue dust piles, or slag heaps. 2 Do not bring tailings or other wastes back to your home to use in your garden or sandbox. 3 Do not grow fruits or vegetables in a garden already containing mining wastes. 4 Do not bring mining wastes back to your home to use as fill or for other construction projects. 5 If you have a well near a mining site, have your well water tested about every one to three years for contamination. If your water starts to become discolored 8 or to smell between tests, contact your local health department. Use good housekeeping practices: dust and vacuum often, remove dusty clothing, wash children's hands often. Consult your doctor if you have any suspicions about your or your children's health. Your doctor can tell you what symptoms are associated with exposure to mining wastes. Follow any additional recommendations provided for a specific site. Because it may be very difficult (and take a great deal of time) to remedy mining waste problems, the best way to be sure those problems do not have any effects on your health is to limit your exposure to the wastes by following these recommendations. ------- The changes may not be visible and their occurrence can be very difficult to predict. Second, the only way to determine whether the water running off a particular waste pile will be acidic and contain metallic contaminants is to examine carefully that waste pile and its runoff. That makes mining wastes different from typical industrial wastes. There are other differences as well. Some petrochemical wastes, for example, may be very hazardous to human health in small quantities, which is rarely true for mining wastes. The quantities of overburden, tailings, and slag produced in mining and ore processing, however, can be enormous. Thus, in short, whether mining wastes do or do not present problems depends on the type of waste, how it has been handled, the type of metal or mineral being mined, and the site of waste disposal. Mining wastes at each site must be judged individually to identify problems. Overall, there are probably no more than 1,500 mining waste sites in the U.S. that could present hazardous waste problems and 100 or so that may require remedial action. In the West, many of these sites are mostly located in unpopulated mountain areas. WHAT ARE THE RISKS TO HUMAN HEALTH AND THE ENVIRONMENT? Mining wastes consist mostly of rock, soil, and other inert materials that are not harmful in themselves to human health. As noted, however, they often do contain zinc, iron, cadmium, arsenic, lead, as well as copper, molybdenum, selenium, manganese, cadmium, mercury, and chromium, metals that may be toxic, that is, poisonous, to humans, animals, or plants. Some, such as lead, are poisonous to humans when inhaled or ingested (swallowed). Others, such as cadmium, arsenic, and some forms of chromium, are believed to cause or contribute to cancer when inhaled or ingested in small quantities over many years. Ground water contaminated by such metals, even if not a threat to human health, may be unusable for drinking or irrigation. The precise effects of exposure to the toxic contaminants released from mining wastes can vary greatly, depending on specific circumstances. By what means was someone exposed to the contaminants? How much, and for how long? Metals, for example, may be very toxic when inhaled and much less toxic when swallowed. Metals such as zinc are valuable or even necessary to human health in small quantities. In what physical condition was the person? Very old people, the very young, and those in poor health are likely to face greater health risks. Previous chemical exposures (or contact at the same time with hazardous substances from other sources) will also affect the health risks involved. Consequently, it is very difficult to predict the health effects of contact with air or water contaminated by toxic metals from mining wastes. There is a great deal of uncertainty in this area, and studies are still underway. The potential contribution of contamination from mining wastes to cancer and other serious human health effects is, however, cause for concern. The risks mining wastes pose to the environment come primarily from the dissolved metals, acid, and process reagents, as well as sulfates, dissolved solids, calcium, sodium, and other contaminants in water running off or draining from wastes. During the spring snowmelt, for example, large volumes of acidic, metal-contaminated runoff from tailings ponds and rock piles have contaminated pasture lands and streams, causing illness in cattle and sheep. Fish kills have been reported. In some cases, the combination of acidic water and silt carried along by mining waste runoff has destroyed the food supply for fish, making the water uninhabitable and driving fish from mountain streams for many miles. These effects may occur rapidly, or they may build up over a period of years. HOW CAN THE PROBLEMS BE REMEDIED? There is much that can be done to prevent mining wastes from turning into environmental problems. The mining industry is becoming ------- increasingly experienced in the careful handling of wastes. Once a problem has developed, however, it may be very difficult to remedy. There are several ways of stopping the leaking of contaminated water from an overburden or tailings pile. One is to haul all the wastes away from the site, along with any contaminated soil from underneath the wastes, and dispose of the wastes in a different, but safer, location. This can be a very expensive course of action because of the enormous quantity of wastes that may need to be removed. For example, there are about 7,000,000 tons of tailings at the Eagle Mine in Colorado. Another course of action is to push the wastes back into the mined-out area from which they came (when the wastes are located close enough to the pit), then cover the filled pit with soil, grade, and revegetate. An alternative is to use waste pile control measures. Dikes, dams, berms, or trenches can prevent surface runoff and run-on. Site drainage systems, pits, ponds, or lagoons can be used to collect runoff and run-on for treatment. Any of these actions may, however, be worse than simply leaving the wastes in place with controls to prevent erosion and water runoff. Moving and hauling wastes can raise dust full of contaminants, creating greater exposure risks than presented by the undisturbed wastes. Contaminated, acidic water leaking from old mines and mine tunnels may be especially difficult to address. One possibility is to collect the drainage and treat it to remove any contaminants. Sometimes, however, the flow of water from a mine may be too great to permit cost-effective treatment. An alternative is to try to plug the shafts and holes from which the water is escaping. Doing so, however, may cause the water to escape somewhere else. There may even be a blowout, quickly releasing a large amount of contaminated water. Plugging may also force some contaminants to flow out with ground water through the bedrock. Another alternative—but an expensive one—is to backfill a mine with alkaline material that can neutralize any acid formed. One way to limit the amount of contaminated water flowing from a mine is to prevent the water from getting into the mine from the surface. This approach may not be successful, because generally water enters a mine by seeping in from surrounding bedrock. In general, because each mining waste site is different, the choice of action depends on the specific nature of the site and the type and extent of its contamination. It may take some time to conduct careful studies of a site to identify the best course of action. ------- I I I $1 I Si I WHO CLEANS UP? If a mining, milling, or smelting site is old and long abandoned, but endangers hu- man health or the environment, who can clean it up? Congress has enacted a number of laws that authorize the federal government to take action, in certain circumstances, to remedy environmental problems connected with mines and mining wastes. States may have their own programs or can use the federal laws. One of the most important of these laws is Superfund. Under Super- fund, the U.S. Environmental Protection Agency (EPA) can study the extent of a mining waste problem and, so long as ac- tion is clearly necessary and the costs are not excessive, clean up the site, halt the spread of contamination, or otherwise remedy the problem. Alternatively, EPA can take legal action to compel the com- panies or individuals responsible to clean up the site. Not all mining waste sites may be eligible for Superfund acuon. Those that are, and that are relatively serious compared with hazardous waste sites elsewhere in the na- tion, are placed on the National Priorities List (NPL). In the 1986 Superfund Amendments, Congress directed EPA to revise its procedures under the Hazard Ranking System (HRS) for evaluating the threat to human health and the environ- ment posed by sites. EPA has 18 months to amend the HRS to assure that it accu- rately assesses the relative degree of risk posed by sites. While these procedures are being revised, EPA must consider some additional factors before facilities containing significant quan- tities of mining wastes can be listed on the NPL. The factors to be considered in- clude: the extent to which the mining waste affects the HRS score; available in- formation as to quantity, toxicity, and con- centration of the hazardous substances; the extent or poternal for release, expo- sure or potential exposure; and the degree of hazard posed by the hazardous con- stituents at such a facility. The three sites described at the beginning of this fact sheet are already on the NPL, along with other mine, mill, and smelter sites, and streams and a reservoir in which mill tailings have accumulated. Consider- able study may be required before the government can determine what type of action, if any, should be taken at a NPL site. A Superfund action may be paid for by private firms that, under the law, are re- sponsible for the sixe. For example, the company that owned or operated a mine in the past may still be liable for that mine, even if the mine is inactive and abandoned. Usually, a company can be linked to each major mining waste site. The companies mar even take the lead in cleaning up the site, under negotiated agreements enforced by EPA. As a re- sult, most Superfund actions at mining waste sites are expected to be joint efforts by the government and industry. ------- DEFINITIONS Mining wastes, in general, include wastes from the mining, milling, smelting, and refining of ores and minerals. Milling is the physical processing of raw ore by breaking, crushing, grinding, or flotation to concentrate the ore and make a product of a certain size for further processing. Smelting is the heat treatment of an ore to separate the metal portion from the waste slag. Refining is a separation process that removes waste from ore mixtures to yield a purified concentrated product. Metal refining can include physical and chemical processes. Overburden or spoil is the waste rock removed in exploration or mining to reach metallic ore. Tailings are waste materials separated from the mined ore by washing, crushing, and other processing in mills. Tailings are usually powdery or fine-grained and may contain residual process chemicals. They are discharged from mills, mixed with water, into large ponds, but when the ponds dry up, the tailings can be formed into piles. Slag is the waste removed from the ore in smelting. Slag piles may also contain dust and sludge removed from smelter smoke to reduce air pollution. Flue dust is the fine-grained airborne solid particles that come from the stack of a smelter. The chemical make-up of the dust is very site-specific and will depend mainly on the geochemical make-up of the ore body and the smelting process being used. Flue dust may contain large amounts of arsenic, copper, silver, and lead. Leach piles are piles of ore from which metals are extracted by dumping a chemical on the pile and letting it drain through the pile, leaching metal from the ore. The metal can then be recovered from the chemical solution. Process reagents are chemicals such as sulfuric acid or sodium cyanide that are used in processes such as leaching to aid in extracting metal from ores. Acid mine drainage is water issuing from a mine that has mineral acidity from oxidation of exposed metallic sulfides and dissolved metals. The source of the water can be seepage from ground water or surface runoff. a I U % it n i I n <4 & 5$ I GPO 854-627 ------- |