United States Air and Radiation EPA430/F-92/Q21 Environmental Protection (6204J) October 1992 Agency *>EPA Acid Rain Program Continuous Emission Monitoring (CEM) In order to reduce acid rain in the United States and Canada, Title IV of the Clean Air Act Amendments of 1990 established the Acid Rain Program. The program will cut sulfur dioxide emissions in half and substantially reduce nitrogen oxides emissions from electric aitility plants. This fact sheet discusses the continuous emission monitoring requirements of the Acid Rain Program and is one of a series containing information about the program. The overall goal of the Acid Rain Program is to achieve significant environmental bene- fits through reductions in emis- sions of sulfur dioxide (SO2) and nitrogen oxides (NOx), the pri- mary causes of acid rain. To achieve this goal at the lowest cost to society, the program employs both traditional and innovative, market-based ap- proaches for controlling air pollu- tion. In addition,, the program encourages energy efficiency and pollution prevention. Title IV of the Qean Air Act sets as its primary goal the reduction of annual SO2 emissions bv 10 million tons below 1980 levels. To achieve these reductions, the law requires a two-phase tightening of the restrictions placed on fossil fuel-fired power plants. Phase I begins in 1995 and affects 110 mostly coal-burning electric utility plants located in 21 eastern and midwestern states. Phase II, which begins in the year 2000, tightens the annual emis- sions limits imposed on these large, higher emitting plants and also sets restrictions on smaller, cleaner plants fired by coal, oil, and gas. The program affects ex- isting utility units with an output capacity of 25 megawatts or greater and new utility units under 25 megawatts that use fuel with a sulfur content greater than 0.05 percent. The Act also calls for a 2 mil- lion-ton reduction in NOx emis- sions by the year 2000. A significant portion of this reduc- tion will be achieved by coal-fired utility boilers that will be re- quired to install low NOx burner technologies and to meet new emissions standards. The innovative, market-based SO2 allowance trading compo- nent of the Acid Rain Program allows utilities to adopt the most cost-effective strategy to reduce SO2 emissions at units in their system. The Acid Rain Program operating permit outlines the specific program requirements and compliance options chosen by each source. Affected utilities also will be required to install systems that continuously moni- tor emissions of SO2, NOx, and other related pollutants in order to track progress, ensure compli- ance, and provide credibility to the trading component of the program. In any year that com- pliance is not achieved, excess emissions penalties will apply, and sources will be required to submit a plan to EPA that speci- fies how the excess SO2 emis- sions will be offset. Introduction Continuous emission monitor- ing (CEM) will be instrumental in ensuring that the mandated re- ductions of SO2 and NOx are achieved. While traditional emis- sions limitation programs have required facilities to meet specific emissions rates, the SO2 portions of the Acid Rain Program require an accounting of each ton of emis- sions from each regulated unit. Compliance is then determined through a direct comparison of total annual SO2 emissions re- ported by CEM and allowances neld for the unit. CEM is the measurement on a continuous basis of pollutants emitted into the atmosphere in exhaust gases from combustion processes or as the by-product of industrial processes. EPA has es- tablished requirements for the continuous monitoring of SO2, NOx, volumetric flow, opacity, and diluent for units regulated under Phase I and Phase II of the Acid Rain Program. In addition, procedures for monitoring or es- timating carbon dioxide (CO2) are specified. The rule also con- tains requirements for equipment performance specifications, certi- fication procedures, and record- keeping and reporting. Printed on paper that contains at least 50% recycled fiber. ------- Why Is CEM Necessary? The Acid Rain Program estab- lishes an allowance trading sys- tem as a market-based approach to reduce SO2 emissions in a cost- effective manner. (One allowance is an authorization to emit 1 ton of SO2 during or after a specified calendar year; a utility may buy, sell, or hold allowances as part of its compliance strategy.) Com- plete ana accurate emissions data are key to implementing this market-based approach. An essential feature of smoothly operating markets is a method for certifying the exist- ence of the commodity being traded. The CEM data will, in ef- fect, supply the "gold standard" to back up the paper current of emissions allowances. The CEM requirements, therefore, will in- still confidence in the market- based approach by certifying the existence and value of the traded commodity (the allowance). What Are the Monitoring Requirements? The owner or operator of a unit regulated under Phase I or Phase II and any new unit must install a CEM system on the unit unless otherwise specified in the regula- tion. A CEM system includes: • An SO2 pollutant concentra- tion monitor • A NOx pollutant concentra- tion monitor • A volumetric flow monitor • An opacity monitor • A diluent gas (oxygen or CO2) monitor • A data acquisition and handling system (computer- based) for recording and per- forming calculations with the data Table 1 summarizes the CEM requirements of the Acid Rain Program. In all cases, a data ac- quisition and handling system must be used to collect and report the data. TABLE 1. CEM MONITOR COMPONENTS REQUIRED FOR ACID RAIN MONITORING REGULATIONS Monitoring Requirement (units required) Required CEM Monitoring Component SO2 NOx Flow Opacity Diluent Gas Data Handling SO2 (Ibs/hr) Yes Yes Yes NO* (lbs/mmBtu)1 Yes Yes Yes Opacity (%) Yes Yes CO2 (ibs/hr)2 Yes Yes Yes 1Heat input in mmBtu/hr is also required. 2Altemative methods may be used to monitor CO2. To monitor SO2 emissions us- ing a CEM system, a facility must use both an SO2 pollutant concen- tration monitor and a volumetric flow monitor to measure the emissions in pounds per hour. To measure NOx emissions, both a NOx pollutant concentra- tion monitor and a diluent gas monitor are required to calculate an emissions rate in pounds per million British thermal units (lbs/mmBtu). Opacity monitoring, which measures the percentage of light that can be seen through flue gas, requires only an opacity monitor. Under the CEM Rule gas-fired units that combust natural gas for at least 90 percent of their total heat input auring the 3 previous calendar years, and diesel and dual-fuel reciprocating internal combustion engine units are exempt from opacity monitoring requirements. The rule does not require a util- ity to use a CEM system to meas- ure CO2. If a utility chooses to use a CEM system, however, a CO2 diluent monitor plus a flow moni- tor would be used to compute emissions in pounds per hour. If a CEM system is installed in such a way that any portion of the flue gases from an affected unit can bypass the monitoring sys- tem, a separate CEM system is required on the bypass flue gas stream. All CEM systems must be in continuous operation and must be able to sample, analyze, and record data at least every 15 min- utes. All emissions and flow data will be reduced to 1-hour aver- ages. The rule specifies proce- dures for converting the hourly emissions data into tne appropri- ate units of measure. Who Do These Requirements Apply To? All units over 25 megawatts and new units under 25 mega- watts that use fuel with a sulmr content ereater than 0.05 percent by weight are required to meas- ure and report emissions under the Acid Rain Program. The new units under 25 megawatts using clean fuels are required to certify their eligibility for an exemption every 5 years. A unit that formally commits to retirement before December 31, 1994, will be ex- empt from the requirements of the rule. The following is a sum- mary of monitoring method re- quirements and options. • All existing coal-fired units greater than 25 megawatts and all new coal units must use CEM for SO2, NOx, flow, and opacity. • Units burning natural gas exclusively are exempt from SO2 monitoring require- ments. • Units burning oil may moni- tor SO2 mass emissions by one of the following three methods: (1) daily manual oil 2 ------- It s sampling and analysis plus oil now meter (to continu- ously monitor the amount of oil consumed), (2) automatic continuous oil sampling plus oil flow meter, or (3) SO2 and flow CEM. • Gas-fired and oil-fired base- loaded units must use NOx CEM. • Gas-fired peaking units and oil-fired peaking units may either estimate NOx emis- sions by using site-specific emission correlations and periodic stack testing to verify continued repre- sentativeness of the correla- tions, or use NOx CEM. • All gas-fired units using natural gas for at least 90 per- cent of their annual neat input, and diesel and duel- fuel reciprocating internal combustion engine units are exempt from opacity monitoring. • For CO2, all units can use either (1) a mass balance esti- mation, (2) CO2 CEM, or (3) oxygen CEM in order to esti- mate CO2 emissions. If a unif s utilization or fuel use changes so that excepted moni- toring methods no longer apply, the unit would become subject to CEM requirements in the follow- ing calendar year. How Will Emissions Be Calculated for Periods of Missing Data? Four or more data points are needed to compile a valid 1-hour average for emissions flow data, except during calibration, main- tenance, repair, or other required quality-assurance activity peri- ods, where two or more data ?oints may compose a valid hour, ailure ot the system to acquire the data points would result in the loss of data for the hour. The rule contains procedures for filling in data when no valid hour or hours of data have been re- corded by the SO2 monitor, the flow monitor, and the NOx CEM system consisting of the NOx monitor and the diluent gas monitor. The rule uses a conserva- tive approach to substituting for missing data. This offers an incen- tive to keep monitor down-time to a minimum, giving the most accurate and reliable results. The procedures are summarized in Table 2. What Are the Requirements for Units Using a Phase I Qualifying Technology? The CEM Rule specifies addi- tional monitoring requirements for units that are implementing an optional compliance method specified under tne Permits Rule that allows a unit to use a Phase I qualifying technology (a system that achieves a 90-percent reduc- tion in SO2 emissions). Each such unit must be equipped with pol- lutant and diluent gas monitors to measure SO2 emissions at the in- let to the control device, in addi- tion to the monitors required for measuring SO2 emissions dis- charged to the atmosphere. What Are the Requirements for Multiple Units with a Common Stack? If two or more units share a common stack, the CEM Rule allows the owner or operator to combine SO2 allowances accord- ing to the procedures outlined in the Allowance System Rule and to install one monitoring system. If a Phase I and Phase II unit share a common stack, the owner or TABLE 2. SUMMARY OF CEM SUBSTITUTION CRITERIA FOR ESTIMATING VALUES FOR MISSING DATA PERIODS Annual availability (%) of monitor or system1 Number of hours missing (N) Value substituted for each missing hour Greater than or equal to 95% N s 24 hours Average of the hour recorded before missing period and the hour recorded after missing period N £ 24 hours 90th percentile value recorded in previous 30 days of service or the before/after value, whichever is greater Less than 95% but greater than or equal to 90% Ni 8 hours Average of the hour recorded before missing period and the hour recorded after missing period N > 8 hours 95th percentile value recorded in previous 302 days of service or the before/after value, whichever is greater Less than 90% N > 0 hours Maximum value recorded in previous 30 days of service or the before/after value, whichever is greater SO2 and flow monitors are individually evaluated for missing data. For NOx, the NOx pollutant concentration monitor and diluent gas monitor are considered in combination. NOx and flow monitoring data are correlated to unit gross operating load before selecting the percentile values. 2NOx CEM systems review the previous 90 days of service. 3 ------- operator must either (1) install a separate CEM system in each duct leading to the stack, (2) de- clare the Phase II unit as a substi- tution unit in accordance with the requirements of the Permits Rule, or (3) obtain the Administrator's approval to differentiate between the units parametrically. If a regulated unit and a nonregulated unit share a com- mon stack, the owner or opera- tor must either (1) install a separate CEM system in the duct leading to the stack of each regu- lated unit, (2) declare the non- regulated unit as an opt-in unit under the Opt-in Rule, or (3) ob- tain the EPA Administrator's approval to differentiate the units parametrically. What Are the Certification Requirements? The Acid Rain Program re- quires the following performance certification tests for CEM sys- tems: • A 7-day calibration error test for each monitor • Alinearity check for each pol- lutant concentration monitor • A relative accuracy test audit (RATA) for each monitor • A bias test for each pollutant concentration monitor and flow monitor • A cycle time/response test for eacn pollutant concentration monitor The EPA Administrator must approve the CEM system before it can be used in the Acid Rain Pro- gram. The owner or operator of a unit must conduct a certification test and submit the results to the EPA Administrator. EPA will issue a notice approv- ing or disapproving the reouest for certification within 120 aays. If the proposed system is disap- proved, tne owner or operator must revise the equipment, pro- cedures, or methods as necessary and resubmit a request for certification. The operator also must per- form periodic performance evaluations of the equipment, including daily calibration error tests, daily interference tests for flow monitors, and semi-annual (or annual) RATA and bias tests. What Quality Assurance/ Quality Control Procedures Are Required? The owner or operator must develop and implement a written quality assurance/quality control plan for each system. The quality control plan must include com- plete, step-by-step procedures and operations for calibration checks, calibration adjustments, preventive maintenance, audits, and recordkeeping and reporting. The rule specifies procedures for assessment of calibration error, relative accuracy, and bias. The quality assurance plan must include relative accuracy test audits, calibration error tests, and bias tests. Are Alternative Monitoring Systems Allowed? The owner or operator of an affected unit may apply to the EPA Administrator for approval of an alternative monitoring sys- tem to determine hourly emis- sions data for SO2, NOx, and/or volumetric flow. An alternative system must provide the same or better precision, reliability, acces- sibiUtyand timeliness as a certi- fied CEM system. The owner or operator must submit substantial information and data to demon- strate that the alternative system meets these criteria. What Are the Recordkeeping, Reporting, and Notification Requirements? The CEM Rule indicates a num- ¦ ber of requirements for notifica- tion, recordkeeping, and reporting for the Acid Rain Program. The requirements include: • Submission of monitoring plans as part of the precer- tification testing form submittal • Written notifications of moni- tor certification tests • Report of certification test results in a "certification application" • Daily recording and main- taining of hourly emissions data, Tlow data, and other information • Quarterly reports of emis- sions, flow, unit operating status, and monitoring per- formance data The rule also requires the owner or operator to report the CEM data electronically. EPA will use this information to determine compliance with the emissions reductions mandated by the Clean Air Act. What Are the Deadlines for Compliance? All required equipment must b* installed, certified, and operational by November 15, ¦- 1993, for Phase I affected units, and by January 1,1995, for any Phase II units. A new unit (a unit that begins commercial operation on or after November 15,1990) must meet all require- ments no later than 90 days after commencing commercial operations. For More Information Write to: U.S. EPA Acid Rain Division (6204J) 401 M Street, SW. Washington, DC 20460 If you would like to receive other fact sheets on the Acid Rain Program, call the Acid Rain Hotline at 617-674-7377 or the EPA Public Information Center (PIC) at 202-260-2080. 4 ------- |