j SERA ASA AEPA o-EPA vvEPA &EPA SEPA v>EPA SEPA c/EPA oEPA oEPA Quality Assurance Materials Bank Analytical Reference Standards Fourth Edition: March 1985 U.S. Environmental Protection Agency Environmental Monitoring Systems Laboratory Quality Assurance Division Las Vegas, Nevada xv E i ------- SP-4170-85-10 MARCH 1985 Quality Assurance Materials Bank: Analytical Reference Standards Fourth Edition: March 1985 (This listing supercedes all previous editions.) Revised and Edited by: Patricia A. Wylie Northrop Services, Inc. Environmental Sciences Research Triangle Park, NC 27709 Under U.S. EPA Contract No. 68-03-3206 Approved for Publication by: Edward J. Kantor, Project Officer Quality Assurance Materials Bank U.S. Environmental Protection Agency Environmental Monitoring Systems Laboratory Quality Assurance Division Las Vegas, Nevada 89114 ------- Environmental Sciences SP-4170-85-10 PREFACE The Quality Assurance Materials Bank (QAMB) represents only one of several quality assurance programs included in the U.S. EPA Quality Assurance Reference Materials (QARM) project. These programs are listed below followed by a description of those laboratories eligible to receive associated Agency support services. Inquiries as to eligibility, description of services available, etc., should be directed to: Mr. Edward J. Kantor, Project Officer Quality Assurance Materials Bank Quality Assurance Division Environmental Monitoring Systems Laboratory P.O. Box 15027 Las Vegas, NV89114 (702) 798-2690 (FTS) 545-2690 Quality Assurance Materials Bank • CERCLA Organics Contract Laboratory Program EPA, EPA Regional Laboratories. EPA-CLP Contractors • CERCLA Inorganics Contract Laboratory Program EPA, EPA Regional Laboratories, EPA-CLP Contractors • CERCLA National Dioxin Monitoring Program EPA, EPA Regional Laboratories, EPA-CLP Contractors • RCRA Hazardous Waste Monitoring Program EPA, EPA Regional Laboratories, EPA-CLP Contractors Pesticides and Industrial Chemicals Repository • EPA Pesticides Program All monitoring and research laboratories worldwide • EPA Industrial Chemicals Program All monitoring and research laboratories worldwide • Federal Supplemental Program U.S. Government and Government Contractors Experimental Chemicals Program U.S. Government and Government Contract • National Pesticides Hazard Assessment Program U.S. Governmen' Laboratories ,v 0* HAP ------- Environmental Sciences SP-4170-85-10 Toxic and Hazardous Materials Repository Quality Assurance Branch Environmental Monitoring & Support Laboratory Cincinnati, OH 45268 (513) 684-7325 (FTS) 684-7325 All monitoring and research laboratories worldwide iii ------- Environmental Sciences SP-4170-85-10 TABLE OF CONTENTS SECTION PAGE PREFACE ii INTRODUCTION— v 1 Single Component Standards - Quality Assurance Materials Bank (EMSL/LV) — 1-1 2 Multicomponent Standards - Quality Assurance Materials Bank (EMSL/LV) 2-1 3 Single Component TCDD Standards - Quality Assurance Materials Bank (EMSL/LV) 3-1 4 Multicomponent TCDD Standards - Quality Assurance Materials Bank (EMSL/LV) 4-1 5 Single Component Standards - Toxic and Hazardous Materials Repository (EMSL/LV) 5-1 APPENDICES Organics Protocol Standards Hazardous Substance List Surrogate Standards Internal Standards IV ------- SP-4170-85-10 Environmental Sciences INTRODUCTION This publication contains listings of all those reference materials currently available in solution through the Quality Assurance Materials Bank (QAMB)/Environmental Monitoring Systems Laboratory-Las Vegas (EMSL-LV). This fourth edition of the QAMB Index supercedes the July 1984 edition and is formatted as follows: Section 1 - Single Component Standards QAMB/EMSL-LV Section 2 - Multicomponent Standards QAMB/EMSL-LV Section 3 - Single Component Dioxin Standards QAMB/EMSL-LV Section 4 - Multicomponent Dioxin Standards QAMB/EMSL-LV Section 5 - Single Component Standards Toxic and Harzardous Materials Repository (THMR) - Environmental Monitoring Support Laboratory - Cincinnati, OH (EMSL-CI) Appendices- Organics Protocol Standards Hazardous Substances List (HSL) Surrogate Standards Internal Standards REQUESTS FOR REFERENCE MATERIALS Due to the steadily increasing number of requests received for reference materials, all laboratories should attempt to identify their needs on a regular basis and submit routine requests such that a sufficient supply of standards can be maintained. While emergency requests for standards will, of course, be accepted and processed with as rapid a turn-around time as possible, such requests should be limited to legitimate emergency situations. It is mandatory that requests be signed by an official of the requesting laboratory and dated accordingly. Requests received without proper authorization will not be acknowledged. v ------- Environmental Sciences SP-4170-85-10 The telephone number to be used for requesting standards is (FTS) 629-2971 or (commercial) 919-541-2971. Telephone requests will be limited to a maximum of 10 items per week unless submitted through the QAMB Project Officer, Mr. Edward J. Kantor, EMSL-LV, at the following telephone number: (FTS) 545-2690 or (commercial) 702-798-2690. Larger requests must be submitted in writing. REQUEST FORMS Request forms are included with each shipment of standards. These forms or good photocopies thereof should always be used when requesting reference materials. Each request should include the full name of the requestor and COMPLETE facility mailing address. Although not required, including an appropriate telephone number is always recommended. Whenever possible, please indicate the five-digit "Laboratory Code Number" that has been assigned to your facility in all communications. Use of this number substantially expedites the processing of requests. Notification of any address, personnel, or organizational changes should be made as soon as possible. Requests forms should be mailed to the following address: Quality Assurance Materials Bank/NSI-ES 2 Triangle Drive/P.O. Box 12313 Research Triangle Park, NC 27709 Requests shipped by commercial carrier, i.e., Federal Express, should also be sent to this address. ACKNOWLEDGMENT CARDS Each dispatched parcel contains a self-addressed acknowledgment card. Since the return of this card is the only method to confirm that a shipment has reached its proper destination, it is requested that all cards be completed and returned promptly. The cards contain space for comments as well. As with requests, acknowledgments should always be signed and dated, as appropriate. SHIPMENTS Due to the excessive costs involved in preparation of certain reference standards, and therefore, their limited availability, the number of standards provided in response to particular requests may be reduced in order to optimize availability. Furthermore, requests for standards from depleted batches will be honored, but with standards from more recently prepared lots. When no exact replacement is available, the closest alternate standard will be shipped. If you wish to have reference materials shipped to you via Federal Express, please include your Federal Express account number on the request form. VI ------- Environmental Sciences SP-4170-85-10 SECTION 1 SINGLE COMPONENT STANDARDS Quality Assurance Materials Bank (EMSL-LV) 1-1 ------- SP-4170-85-10 \ Environmental Sciences - SINGLE COMPONENT STANDARDS Quality Assurance Materials Bank (EMSL-LV) NSI-ESCode Compound Name Solvent Cone. (ng/mL) EC-000001-01-05 Acenaphthene Methanol 5000 EC-000003-01-03 Acrylonitrile Methanol 10000 EC-000004-01-04 Benzidine Methanol 5000 EC-000006-01-05 Chlorobenzene Methanol 10000 EC-000007-01-05 1,2,4-Trichlorobenzene Methanol 5000 EC-000010-01-04 1,1,1-Trichloroethane Methanol 10000 EC-000014-01-04 1,1,2,2-Tetrachloroethane Methanol 10000 EC-000015-02-02 Chloroethane 2-Propanol 11000 EC-000017-01-04 2-Chloroethyl vinyl ether Methanol 1000 EC-000017-01-05 2-Chloroethyl vinyl ether Methanol 10000 EC-000017-01-07 2-Chloroethyl vinyl ether Methanol 5000 EC-000019-04-02 2,4,6-Trichlorophenol Methanol 5000 EC-000020-02-01 p-Chloro-m-cresol (4-Chloro-3-methyl phenol) Methanol 5000 EC-000022-03-02 2-Chlorophenol Methanol 5000 EC-000023-01-05 1,2-Dichlorobenzene Methanol 5000 EC-000025-01-05 1,4-Dichlorobenzene Methanol 5000 EC-000028-01-03 trans-\,2-Dichloroethylene Tetraglyme 5000 EC-000029-01-04 2,4-Dichlorophenol Methanol 5000 EC-000030-01-03 1,2-Dichloropropane Methanol 10000 EC-000033-02-02 2,4-Dinitrotoluene Methanol 5000 EC-000037-01-05 Fluoranthene Methanol 5000 EC-000039-01-03 4-Bromophenyl phenyl ether Methanol 5000 EC-000041-01-04 b/s(2-Chloroethoxy) methane Methanol 5000 EC-000043-01-03 Methyl chloride Tetraglyme 5000 EC-000044-01-03 Methyl bromide Tetraglyme 5000 EC-000046-01-02 Dichlorobromomethane Tetraglyme 5000 EC-000046-02-02 Dichlorobromomethane Methanol 10000 EC-000051-01-03 Hexachlorocydopentadiene Methanol 5000 1-2 ------- Environmental Sciences SP-4170-85-10 NSI-ESCode Compound Name Solvent Cone. (pg/mL) EC-000053-01-05 Naphthalene Methanol 5000 EC-000054-01-08 Nitrobenzene Methanol 5000 EC-000056-01-05 4-Nitrophenol Methanol 5000 EC-000057-01-07 2,4-Dinitrophenol Methanol 5000 EC-000060-01-04 N-Nitrosodiphenylamine CH2CI2 2000 EC-000063-01-05 Phenol Methanol 5000 EC-000066-01-05 Di-n-butyl phthalate Methanol 5000 EC-000067-01-03 Di-n-octyl phthalate Methanol 5000 EC-000068-01-05 Diethyl phthalate Methanol 5000 EC-000070-01-04 Benzo(a)anthracene Methanol 1000 EC-000071-01-03 Benzo(a)pyrene Acetone 1000 EC-000072-01-03 Benzo(b)fluoranthene Acetone 2500 EC-000073-01-03 Benzo(k)fluoranthene Acetone 1000 EC-000075-01-04 Acenaphthylene Methanol 5000 EC-000082-01-05 Pyrene Methanol 1000 EC-000083-01-03 Tetrachloroethylene Tetraglyme 5000 EC-000084-01-06 Toluene Methanol 10000 EC-000085-01-02 Trichloroethylene Tetraglyme 5000 EC-000085-01-03 Trichloroethylene Methanol 10000 EC-000085-01-06 Trichloroethylene Methanol 10000 EC-000089-01-03 Chlordane Hexane 5000 EC-000089-01-04 Chlordane Hexane 10000 EC-000091-01-03 4,4'-DDE Methanol 5000 EC-000096-01-04 Endrin Methanol 5000 EC-000097-01-03 Endrin aldehyde Methanol 5000 EC-000100-01-03 alpha-BHC Methanol 2500 EC-000103-02-02 delta-BHC Methanol 1000 EC-000104-01-03 PCB 1242 Hexane 5000 EC-000104-01-04 PCB 1242 Hexane 10000 EC-000105-01-03 PCB 1254 Hexane 5000 1-3 ------- SP-4170-85-10 1 Environmental Sciences MSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000107-01-03 PCB 1232 Hexane 5000 EC-000108-01-03 PCB 1248 Hexane 5000 EC-000108-01-04 PCB 1248 Hexane 10000 EC-000109-01-03 PCB 1260 Hexane 5000 EC-000110-01-03 PCB 1016 Hexane 10000 EC-000111-01-03 Toxaphene Hexane 5000 EC-000111-01-04 Toxaphene Hexane 10000 EC-000111-01-06 Toxaphene Methanol 5000 EC-000124-02-04 4,4'-DDT Methanol 5000 EC-000125-01-02 PCB 1016 Hexane 5000 EC-000126-01-02 PCB 1221 Hexane 5000 EV-000136-01-02 Bromochloromethane Methanol 5000 EV-000136-01-04 Bromochloromethane Methanol 10000 ES-000140-01-05 Naphthalene-ds CH2CI2 1000 ES-000140-01-06 Naphthalene-ds ch2ci2 1000 ES-000140-02-01 Naphthalene-dg ch2ci2 5000 ES-000142-01-04 Benzene-d6 Methanol 5000 ES-000142-01-05 Benzene-ds Methanol 5000 ES-000143-03-01 Toluene-ds Methanol 5000 ES-000144-01-04 Anthracene-dio CH2CI2 1000 ES-000144-01-05 Anthracene-dio ch2ci2 1000 EV-000145-01-02 2-Fluorophenol Methanol 5000 EV-000158-01-02 1,4-Dichlorobutane Methanol 1000 EV-000158-01-04 1,4-Dichlorobutane Methanol 5000 ES-000166-02-02 Nitrobenzene-ds Methanol 5000 EV-000169-02-02 Benzyl chloride CH3CN 5000 EV-000179-01-01 2,4,5-Trichlorophenol ch2ci2 1000 EV-000179-01-03 2,4,5-Trichlorophenol Methanol 5000 EV-000193-04-01 2-Fluorophenol Methanol 5000 1-4 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) EV-000194-03-01 2-Fluorobi phenyl Methanol 5000 EC-000200-01-03 Chlorodibromomethane Methanol 10000 E5-000213-01-01 Chloroform-d Methanol 10000 ES-000217-01-03 Pyrene-dio ch2ci2 1000 ES-000217-02-01 Pyrene-dio ch2ci2 1000 ES-000217-02-02 Pyrene-dio Methanol 5000 ES-000220-02-02 Aldrin Methanol 5000 ES-000229-03-01 Chrysene-di2 CH2LCI2 1000 ES-000230-01-03 Phenanthrene-dio ch2ci2 1000 EC-000232-01-02 Fluorobenzene Methanol 5000 EC-000233-01-03 4-Bromofluorobenzene Methanol 5000 EC-000238-01-03 n-Dodecane Hexadecane 5000 EC-000238-01-05 n-Dodecane Hexadecane 5000 EC-000250-01-01 o-Cresol CH2CI2 1000 EC-000252-01-02 p-Cresol ch2ci2 1000 EC-000257-01-01 Styrene Methanol 5000 EC-000257-01-02 Styrene Tetraglyme 5000 EC-000258-01-03 Epichlorohydrin CH3CN 5000 EC-000261-01-01 Dibenzofuran ch2ci2 1000 EC-000284-01-02 Acetone Tetraglyme 5000 EC-000284-01-03 Acetone Methanol 5000 EC-000286-01-03 1,2-Epoxybutane CH3CN 5000 EV-000305-01-02 4-Chloroaniline (p-Chloroaniline) Benzene 1000 EV-000305-01-04 4-Chloroaniline (p-Chloroaniline) Methanol 5000 EC-000311-01-02 Methyl ethyl ketone Tetraglyme 5000 EV-000324-01-02 o-Nitroaniline (2-Nitroaniline) Benzene 1000 EV-000325-01-02 m-Nitroaniline (3-Nitroaniline) Benzene 1000 EV-000326-01-01 Benzyl alcohol CH2CI2 1000 EV-000327-01-03 Vinyl acetate Dioxane 5000 1-5 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000330-02-02 2,4-Dichlorophenoxyacetic acid (2,4-D) CH3CN 5000 EV-000333-01-02 n-Nonane Isooctane 5000 EV-000333-01-03 n-Nonane Hexadecane 5000 EV-000333-01-04 n-Nonane Methanol 5000 EV-000336-01-01 2-Hexanone Methanol 5000 EV-000336-01-02 2-Hexanone Tetraglyme 5000 EV-000336-01-03 2-Hexanone Methanol 5000 EV-000342-01-02 p-Nitroaniline (4-Nitroaniline) Benzene 1000 EV-000342-01-04 p-Nitroaniline (4-Nitroaniline) Methanol 5000 EV-000346-01-01 Dichlorodifluoromethane Methanol 5000 EV-000346-01-02 Dichlorodifluoromethane Tetraglyme 5000 EV-000349-01-01 4-Methyl-2-pentanone Methanol 5000 EV-000349-01-02 4-Methyl-2-pentanone Tetraglyme 5000 EV-000363-01-01 Carbon disulfide Methanol 5000 EV-000363-01-02 Carbon disulfide Tetraglyme 5000 EV-000377-01-02 m-Bromobenzotrifluoride Methanol 5000 EV-000400-01-03 2-Fluoroaniline Benzene 5000 EV-000436-01-03 Decafl uorobi phenyl CH2CI2 5000 EV-000437-01-03 Pentafluorophenol Ch2CI2 5000 EV-000446-01-02 b/s(Perfluoroisopropyl) ketone Methanol 5000 EV-000463-01-05 1,2-Dibromo-1,1,2,2-tetrafluoroethane Methanol 5000 EV-000463-01-06 1,2-Dibromo-1,1,2,2-tetrafluoroethane Tetraglyme 5000 ES-000465-01-02 Bromobenzene-ds CH2CI2 1000 ES-000466-01-02 Biphenyl-dio ch2ci2 1000 ES-000466-01-03 Biphenyl-dio ch2ci2 1000 ES-000467-01-02 Acenaphthene-dio ch2ci2 1000 ES-000467-01-03 Acenaphthene-dio (84%-dio) Benzene 2000 ES-000508-01-01 Pyridine-ds Methanol 1000 ES-000511-01-01 Ethylbenzene Methanol 5000 1-6 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (lig/mL) EV-000520-01-01 c/s-1,3-Dichloropropene Methanol 5000 EV-000520-01-02 c/s-1,3-Dichloropropene Tetraglyme 5000 ES-000531 -05-01 Phenol-ds CH2CI2 5000 EV-000541-01-01 Benzoic acid ch2ci2 1000 EV-000542-01-02 Aniline Benzene 1000 EC-000552-02-02 Silvex CH3CN 5000 EV-000562-01-01 2-Methyl naphthalene ch2ci2 1000 ES-000571-01-01 Nitrobenzene-ds ch2ci2 5000 EC-000713-01-02 Pidoram ch3cn 5000 EV-000720-01-01 2-Bromo-1-chloropropane Methanol 1000 EV-000720-01-02 2-Bromo-1-chloropropane Tetraglyme 5000 EV-000720-01-03 2-Bromo-1 -chloropropane Methanol 5000 E5-000726-01-01 Phenol-d3 ch2ci2 2000 EV-000791-02-02 p-Difluorobenzene Methanol 10000 EV-000797-02-01 gamma-Chlordane Hexane 5000 EV-000798-01-01 Dibutyl chlorendate ch2ci2 5000 EV-000798-02-02 Dibutyl chlorendate Methanol 5000 EV-000875-01-02 2,4,6-Tribromophenol Methanol 5000 ES-000876-01-01 1,2-Dichloroethane-d4 Methanol 5000 ES-000876-02-03 1,2-Dichloroethane-d4 Methanol 5000 E5-000876-02-04 1,2-Dichloroethane-d4 Methanol 5000 ES-000897-01-01 1,4-Dichlorobenzene-d4 ch2ci2 5000 EV-000903-02-01 alpha-Chlordane Hexane 5000 ES-000909-01-04 p-Terphenyl-d14 THF 5000 EV-000952-02-04 p,p'-Methoxychlor Hexane 5000 E5-001006-01-01 Benzo(a)pyrene-di2 Benzene 5000 E5-001009-01-01 Perylene-di2 cs2 2000 EV-001010-01-01 DFTPP ch2ci2 1000 E5-001021-02-01 Chlorobenzene Methanol 5000 EV-001036-01-01 Endrin ketone Ethyl acetate 2000 1-7 ------- Environmental Sciences SP-4170-85-10 SECTION 2 MULTICOMPONENT STANDARDS Quality Assurance Materials Bank (EMSL-LV) 2-1 ------- ~08 SP-4170-85-10 Environmental Sciences. MULTICOMPONENT STANDARDS Quality Assurance Materials Bank (EMSL-LV) NSI-ES Code Compound Name Solvent Cone, (ng/mi) C-016 C-017 Mixed Acids 2-Chlorophenol 2,4-Dichlorophenol 2,4-Di methyl phenol 4,6-Dinitro-o-cresol 4-Nitrophenol 2,4,6-Trichlorophenol Mixed Pesticides gamma-BHC 4,4'-DDT Dieldrin Endrin Heptachlor Methylene- chloride Isooctane 1000 1000 1000 1000 1000 1000 5.0 20.3 10.5 20.9 5.1 C-020 C-024 Neutral Extractables Acenaphthene Anthracene Benzo(k)fluoranthene Dibenz(a,h)anthracene Dibenzofuran 1,2-Dichlorobenzene 1,4-Dichlorobenzene fa/s(2-Ethylhexyl) phthalate Fluorene Hexachlorobenzene Hexachlorocyclopentadiene Isophorone Nitrobenzene N-Nitrosodi-n-propylamine Pyrene Volatile Compounds III Benzene Ethylbenzene Styrene Toluene o-Xylene Methylene- chloride Methanol 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 C-029 Chlorinated Aromatics I 1,4-Dichlorobenzene 1,2,4,5-Tetrachlorobenzene 1,2,4-Trichlorobenzene Methanol 1000 1000 1000 2-2 ------- Environmental Sciences SP-4170-85-10 NSI-ESCode Compound Name C-30 Chlorinated Aromatics III Methanol m-Chlorotoluene 1000 o-Chlorotoluene 1000 p-Chlorotoluene 1000 2,4-Dichlorotoluene 1000 Toluene 1000 alpha, alpha,2,6-Tetrachlorotoluene 1000 C-035 Volatile Compounds V Methanol Acetone 2000 Carbon disulfide 2000 2-Hexanone 2000 Methyl ethyl ketone 2000 4-Methyl-2-pentanone 2000 C-036 Volatile Compounds VI Methanol Benzene 2000 Ethylbenzene 2000 Styrene 2000 Toluene 2000 o-Xylene 2000 C-038 Volatile Compounds VIII Methanol Bromodichloromethane 2000 Dibromochloromethane 2000 1.2-Dichloroethane 2000 trans- 1,2-Dichloroethene 2000 c/s-1,3-Dichloropropene . 2000 frans-1,3-Dichloropropene 2000 Methylene chloride 2000 1,1,2,2-Tetrachloroethene 2000 1,1,1-Trichloroethne 2000 Vinyl chloride 2000 C-039 Neutral Extractables IV CH2CL2 Acenaphthylene 2000 Benzo(a)anthracene 2000 Benzo(b)fluoranthene 2000 Butyl benzyl phthalate 2000 b/s(2-Chloroethoxy) methane 2000 b/s(2-Chloroisopropyl) ether 2000 1.3-Dichlorobenzene 2000 2.4-Dinitrotoluene 2000 2,6-Dinitrotoluene 2000 Fluoranthene 2000 lndeno(1,2,3-c,d)pyrene 2000 2-Methylnaphthalene 2000 N-Nitrosodimethylamine 2000 Phenanthrene 2000 1,2,4-Trichlorobenzene 2000 2-3 ------- ig SP-4170-85-10 IUEnvironmental Sciences NSI-ESCode Compound Name Solvent (jig/ml) C-040 Neutral Extractables V Methylene Acenaphthene chloride 2000 Anthracene 2000 8enzo(k)fluoranthene 2000 Dibenz(a,h)anthracene 2000 Dibenzofuran 2000 1,2-Dichlorobenzene 2000 1,4-Dichlorobenzene 2000 b/s(2-Ethylhexyl) phthalate 2000 Fluorene 2000 Hexachlorobenzene 2000 Hexachlorocyclopentadiene 2000 Isophorone 2000 Nitrobenzene 2000 N-Nitrosodi-n-propylamine 2000 Pyrene 2000 C-041 Neutral Extractables VI Benzo(a)pyrene Methylenec 2000 Benzo(g,h,i)perylene hloride 2000 Benzyl alcohol 2000 4-Bromophenyl phenyl ether 2000 b/s(2-Chloroethyl) ether 2000 2-Chloronaphthalene 2000 4-Chlorophenyl phenyl ether 2000 Chrysene 2000 Diethyl phthalate 2000 Dimethyl phthalate 2000 Di-n-butyl phthalate 2000 Di-n-octyl phthalate 2000 Hexachlorobutadiene 2000 Hexachloroethane 2000 Naphthalene 2000 2-4 ------- SP-4170-85-10 J En vironmen tal Sciences NSI-ESCode Compound Name Solvent (jig/ml) C-043 Pesticides II Toluene/ Aldrin Hexane 1:1 2000 alpha-BHC 2000 beta-BHC 2000 gamma-BHC 2000 delta-BHC 2000 4,4'-DDD 2000 4,4'-DDE 2000 4,4'-DDT 2000 Dieldrin 2000 alpha-Endosulfan 2000 beta-Endosulfan 2000 Endosulfan sulfate 2000 Endrin 2000 Endrin aldehyde 2000 Heptachlor 2000 Heptachlor epoxide 2000 C-044 Acid Extractables II Methylene- Benzoic acid chloride 2000 p-Chloro-m-cresol 2000 2-Chlorophenol 2000 o-Cresol 2000 p-Cresol 2000 2,4-Dichlorophenol 2000 2,4-Dimethylphenol 2000 4,6-Dinitro-o-cresol 2000 2,4-Dinitrophenol 2000 2-Nitrophenol 2000 4-Nitrophenol 2000 Pentachlorophenol 2000 Phenol 2000 2.4.5-Trichlorophenol 2000 2.4.6-Trichlorophenol 2000 C-045 Volatile Compounds IX Methanol Bromodichloromethane 2000 Dibromochloromethane 2000 1,2-Dichloroethane 2000 trans- 1,2-Dichloropropene 2000 c/s-1,3-Dichloropropene 2000 trans-1,3-Dichloropropene 2000 Methylene chloride 2000 1,1,2,2-Tetrachloroethane 2000 1,1,1-Trichloroethane 2000 Trichlorofluoromethane 2000 Vinyl chloride 2000 2-5 ------- SP-4170-85-10 I Environmental Sciences NSI-ESCode Compound Name Solvent (jig/ml) C-046 Chlorinated Aromatics I Tetrahydro- Benzene furan 1000 Chlorobenzene 1000 Hexachlorobenzene 1000 Pentachlorobenzene 1000 C-047 PCB 1232 and PCB 1260 Hexane PCB 1232 10000 PCB 1260 10000 C-048 PCB 1221 and PCB 1254 Hexane PCB 1221 10000 PCB 1254 10000 C-050 Thioureas I Acetonitrile Ethylenethiourea 2-Propanol 1000 1-(1-Naphthyl)-2-thiourea 1:1 1000 n-Phenylthiourea 1000 6-N-Propyl-2-thiouracil 1000 Thioacetamide 1000 2-Thio-6-methyluracil 1000 Thiosemicarbazide 1000 Thiourea 1000 C-058 Carbamates Acetone Carbofuran 1000 Cydoate 1000 EPTC 1000 Diallate 1000 Molinate 1000 C-059 Metals I Water Aluminum 500 Arsenic 2 Lead 2 Selenium 1 C-060 Metals II Water Antimony 1 Arsenic 2 Boron 5 Cadmium 0.5 Chromium 0.1 Iron 1000 Vanadium 1000 2-6 ------- Environmental Sciences SP-4170-85-10 NSI-ESCode Compound Name Solvent Cone, (ng/ml) C-069 1.3-DichlorooroDvlene (c/s,fransmix) Methanol c/s-1,3-Dichloropropylene 5000 trans- 1,3-Dichloropropylene 5000 C-075 Basic Extractables Benzene Aniline 1000 4-Chloroaniline 1000 2-Nitroaniline 1000 3-Nitroaniline 1000 4-Nitroaniline 1000 C-083 Volatile Compounds X Methanol Acrolein 2000 Acrylonitrile 2000 Vinyl acetate 2000 2-7 ------- Environmental Sciences SP-4170-85-10 SECTION 3 SINGLE COMPONENT TCDD STANDARDS Quality Assurance Materials Bank (EMSL-LV) 3-1 ------- Environmental Sciences SP-4170-85-10 These standards are routinely available only to those laboratories directly involved in the CERCLA National Dioxin Monitoring Program. All requests for standards from other organizations must be approved by the QAMB Project Officer (EMSL-LV). TCDD SINGLE COMPONENT STANDARDS Quality Assurance Materials Bank (EMSL-LV) Code Compound Solvent Cone. (lig/mL) EC-000206-01-03 2,3,7,8-TCDD Isooctane 7.87 EV-000655-01-01 1,2,3,4-TCDD Benzene 200.00 EL-000812-01-01 i3C12-2,3,7,8-TCDD Isooctane 1.00 EL-000812-01-02 13C-| 2-2,3,7,8 - TCDD Benzene 200.00 The following materials, which will be shipped only at the request of the Director, Quality Assurance Division (EMSL-LV), are available for use as qualitative solutions at a nominal concentration of 100 ng/mL in isooctane: EV-001056-01-02 1,3,7,8-TCDD EV-001057-01-02 1,2,8,9-TCDD EV-001058-01-02 1,2,3,4-TCDD EV-001059-01-02 1,4,7,8-TCDD EV-001060-01-02 1,2,7,9-TCDDa EV-001061-01-02 1,3,6,9-TCDD EV-001062-01-02 1,2,6,8-TCDDb EV-001063-01-02 1,2,3,9-TCDD EV-001064-01-02 1,2,7,8-TCDDc EV-001065-01-02 1,2,3,6-TCDD 3-2 ------- ~00 Environmental Sciences. SP-4170-85-10 EV-001066-01-02 EV-001067-01-02 EV-001068-01-02 EV-001069-01-02 EV-001070-01-02 EV-001071-01-02 EV-001072-01-02 EV-001073-01-02 EV-001074-01-02 EV-001075-01-02 EV-001076-01-02 EV-001077-01-02 1,2,6,9-TCDD 1,4,6,9-TCDD 1.2.6.7-TCDD 1.3.6.8-TCDD 1.3.7.9-TCDD 1.2.3.7-TCDD 1.2.3.8-TCDD 1.2.4.6-TCDDd 1.2.4.9-TCDDe 1.2.4.7-TCDDf 1.2.4.8-TCDDg 2,3,7,8-TCDD ' Identification based on IR analysis. GC/MS does not resolve this isomer from 1 b Identification based on IR analysis. GC/MS does not resolve this isomer from 1 c Identification based on IR analysis. GC/MS does not resolve this isomer from I d Identification based on IR analysis. GC/MS does not resolve this isomer from 1 e Identification based on IR analysis. GC/MS does not resolve this isomer from 1 ' Identification based on IR analysis. GC/MS does not resolve this isomer from I 9 Identification based on IR analysis. GC/MS does not resolve this isomer from I 2,6,8-TCDD. 2.7.8-TCDD. 2.7.9-TCDD. 2,4,9-TCDD 2.4.6-TCDD. 2.4,8-TCDD. 2.4.7-TCDD. 3-3 ------- Environmental Sciences SP-4170-85-10 SECTION 4 MULTICOMPONENT TCDD STANDARDS Quality Assurance Materials Bank (EMSL-LV) 4-1 ------- riRR sp-4170-85-10 bJcJUfnv/ri I Environmental Sciences. These standards are routinely available only to those laboratories directly* involved in the CERCLA National Dioxin Monitoring Program. All requests for standards from other organizations must be approved by the QAMB Project Officer (EMSL-LV). NSI-ESCode Compound Name Solvent C-057 Dioxin Spikinq II i3C12-2,3(7,8-TCDD 37CU-2,3,7,8-TCDD Toluene 0.50 0.10 C-077 TCDD Calibration I 2,3,7,8-TCDD i3C12-2,3,7,8-TCDD 37CI4-2,3,7,8-TCDD Isooctane 0.2 1.0 0.06 C-078 TCDD Calibration II 2,3,7,8-TCDD 13C 12-2,3,7,8-TCDD 37CI4,-2,3,7,8-TCDD Isooctane 1.0 1.0 0.12 C-079 TCDD Calibration III 2,3,7,8-TCDD i3C12-2,3,7,8-TCDD 37CI4-2,3,7,8-TCDD Isooctane 5.0 1.0 0.20 C-080 TCDD Calibration IV 2,3,7,8-TCDD l3C12-2,3,7,8-TCDD Isooctane 20.0 1.0 C-081 TCDD Calibration V 2,3,7,8-TCDD i3C12-2,3,7,8-TCDD Isooctane 40.0 1.0 C-085 TCDD Soikinq I 2,3,7,8-TCDD i3C12-2,3,7,8-TCDD 37d4-2,3,7,8-TCDD Isooctane 0.10 ± 0.01 0.50 ± 0.05 0.10 ± 0.01 C-086 TCDD Soikinq II i3C12-2,3,7,8-TCDD 37Cla-2,3,7,8-TCDD Isooctane 0.50 ±0.05 0.10 ± 0.01 4-2 ------- Environmental Sciences SP-4170-85-10 SECTION 5 SINGLE COMPONENT STANDARDS Toxic and Hazardous Materials Repository (EMSL-CI) 5-1 ------- ~aa SP-4170-85-10 Environmental Sciences NSI-ES Code SINGLE COMPONENT STANDARDS Toxic and Hazardous Materials Repository (EMSL-CI) Compound Name Solvent Cone. (jig/mL) EC-000001-01-03 Acenaphthene Methanol 5000 EC-000001-01-04 Acenaphthene Methanol 5000 EC-000002-01-03 Acrolein Dioxane 10000 EC-000003-01-01 Acrylonitrile Methanol 10000 EC-000004-01-04 Benzene Methanol 10000 EC-000005-01-02 Benzidine Methanol 5000 EC-000006-01-04 Chlorobenzene Methanol 10000 EC-000007-01-04 1,2,4-Trichlorobenzene Methanol 5000 EC-000008-01-03 Hexachlorobenzene Acetone 1000 EC-000009-01-01 1,2-Dichloroethane Methanol 10000 EC-000009-01-02 1,2-Dichloroethane Methanol 10000 EC-000010-01-03 1,1,1-Trichloroethane Methanol 10000 EC-000011-01-02 Hexachloroethane Methanol 5000 EC-000012-01-03 1,1-Dichloroethane Methanol 10000 EC-000013-01-02 1,1,2-Trichloroethane Methanol 10000 EC-000014-01-03 1,1,2,2-Tetrachloroethane Methanol 10000 EC-000015-02-01 Chloroethane 2-Propanol 11000 EC-000016-01-01 b/s(2-Chloroethyl) ether Methanol 5000 EC-000017-01-03 2-Chloroethyl vinyl ether Methanol 10000 EC-000018-01-03 2-Chloronaphthalene Methanol 5000 EC-000019-01-02 2,4,6-Trichlorophenol Methanol 5000 EC-000019-04-01 2,4,6-Trichlorophenol Methanol 5000 EC-000020-01-04 p-Chloro-m-cresol (4-Chloro-3-methyl phenol) Methanol 5000 EC-000020-01-05 p-Chloro-m-cresol (4-Chloro-3-methyl phenol) Methanol 5000 EC-000021-01-03 Chloroform Methanol 10000 EC-000022-03-01 2-Chlorophenol Methanol 5000 5-2 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (jig/mL) EC-000023-01-03 1,2-Dichlorobenzene Methanol 5000 EC-000023-01-04 1,2-Dichlorobenzene Methanol 5000 EC-000025-01-03 1,4-Dichlorobenzene Methanol 5000 EC-000025-01-04 1,4-Dichlorobenzene Methanol 5000 EC-000026-01-02 3,3'-Dichlorobenzidine Methanol 5000 EC-000028-01-02 trans-1,2-Dichloroethylene Methanol 10000 EC-000029-01-02 2,4-Dichlorophenol Methanol 5000 EC-000029-01-03 2,4-Dichlorophenol Methanol 5000 EC-000030-01-01 1,2-Dichloropropane Methanol 10000 EC-000033-01-01 2,4-Dinitrotoluene Methanol 5000 EC-000033-02-01 2,4-Dinitrotoluene Methanol 5000 EC-000034-01-03 2,6-Dinitrotoluene Methanol 5000 EC-000036-01-02 Ethylbenzene Methanol 10000 EC-000037-01-03 Fluoranthene Methanol 5000 EC-000037-01-04 Fluoranthene Methanol 5000 EC-000038-01-01 4-Chlorophenyl phenyl ether Methanol 5000 EC-000039-01-01 4-Bromophenyl phenyl ether Methanol 5000 EC-000040-01-02 b/'s(2-Chloroisopropyl) ether Methanol 5000 EC-000041-01-02 b»s(2-Chloroethoxy) methane Methanol 5000 EC-000042-01-02 Methylene chloride Methanol 10000 EC-000042-01-03 Methylene chloride Methanol 10000 EC-000043-01-04 Methyl chloride 2-Propanol 4500 EC-000044-01-02 Methyl bromide 2-Propanol 9940 EC-000046-02-01 Dichlorobromomethane Methanol 10000 EC-000050-01-02 Hexachlorobutadiene Methanol 5000 EC-000051-01-01 Hexachlorocydopentadiene Methanol 5000 EC-000051-01-02 Hexachlorocydopentadiene Methanol 5000 EC-000052-01-02 Isophorone Methanol 5000 EC-000053-01-03 Naphthalene Methanol 5000 5-3 ------- Environmental Sciences SP-4170-85-10 NSI-ESCode Compound Name Solvent Cone. (jig/mL) EC-000053-01-04 Naphthalene Methanol 5000 EC-000054-01-06 Nitrobenzene Methanol 5000 EC-000054-01-07 Nitrobenzene Methanol 5000 EC-000055-01-03 2-Nitrophenol Methanol 5000 EC-000056-01-03 4-Nitrophenol Methanol 5000 EC-000057-01-06 2,4-Dinitrophenol Methanol 5000 EC-000058-01-03 4,6-Dinitro-o-Cresol Methanol 5000 EC-000059-01-03 N-Nitrosodimethylamine Methanol 5000 EC-000060-01-03 N-Nitrosodiphenylamine Methanol 5000 EC-000061-01-04 N-Nitrosodi-n-Propylamine Methanol 5000 EC-000062-01-04 Pentachlorophenol Methanol 5000 EC-000063-01-04 Phenol Methanol 5000 EC-000064-01-03 b/s(2-Ethylhexyl) phthalate Methanol 5000 EC-000065-01-01 Butyl benzyl phthalate Methanol 5000 EC-000066-01-04 Di-n-butyl phthalate Methanol 5000 EC-000066-01-06 Di-n-butyl phthalate Methanol 5000 EC-000067-01-01 Di-n-octyl phthalate Methanol 5000 EC-000068-01-03 Diethyl phthalate Methanol 5000 EC-000069-01-03 Dimethyl phthalate Methanol 5000 EC-000070-01-02 Benzo(a)anthracene Methanol 1000 EC-000071 -01-01 Benzo(a)pyrene Acetone 1000 EC-000071 -01-02 Benzo(a)pyrene Acetone 1000 EC-000072-01-01 Benzo(b)fluoranthene Acetone 2500 EC-000072-01-02 Benzo(b)fluoranthene Acetone 2500 EC-000073-01-01 Benzo(k)fluoranthene Acetone 1000 EC-000073-01-02 Benzo(k)fluoranthene Acetone 1000 EC-000074-01-04 Chrysene Acetone 1000 EC-000075-01-02 Acenaphthylene Methanol 5000 EC-000075-01-03 Acenaphthylene Methanol 5000 EC-000076-01-03 Anthracene Acetone 1000 5-4 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000077-01-02 Benzo(g,h,i)perylene Dioxane 1000 EC-000078-01-03 Fluorene Methanol 5000 EC-000079-01-03 Phenanthrene Methanol 5000 EC-000081-01-01 lndeno(1,2,3-c,d)pyrene Acetone 500 EC-000082-01-04 Pyrene Methanol 1000 EC-000083-01-02 Tetrachloroethylene Methanol 10000 EC-000084-01-04 Toluene Methanol 10000 EC-000084-01-05 Toluene Methanol 10000 EC-000085-01-01 Trichloroethylene Methanol 10000 EC-000085-01-04 Trichloroethylene Methanol 10000 EC-000087-01-03 Endrin Methanol 5000 EC-000088-01-03 Oieldrin Methanol 5000 EC-000089-01-02 Chlordane Methanol 5000 EC-000091-01-02 4,4'-DDE Methanol 5000 EC-000092-01-02 4,4'-DDD Methanol 5000 EC-000092-01-03 4,4'-DDD Methanol 5000 EC-000093-01-04 alpha-Endosulfan Dioxane 5000 EC-000094-01-04 beta-Endosulfan sulfate Methanol 5000 EC-000095-01-02 Endosulfan sulfate Methanol 5000 EC-000096-01-03 Endrin Methanol 5000 EC-000097-01-02 Endrin aldehyde Methanol 5000 EC-000098-01-02 Heptachlor Methanol 5000 EC-000098-01-04 Heptachlor Methanol 5000 EC-000099-01-02 Heptachlor Epoxide Methanol 5000 EC-000100-01-01 alpha-BHC Methanol 2500 EC-000100-01-02 alpha-BHC Methanol 2500 EC-000101-01-03 beta-BHC Acetone 2500 EC-000102-01-03 gamma-BHC Methanol 5000 EC-000103-01-01 delta-BHC Methanol 5000 EC-000104-01-02 PCB 1242 Methanol 5000 5-5 ------- Environmental Sciences NSI-ESCode EC-000105-01-02 PCB 1254 Methanol 5000 EC-000107-01-02 PCB 1232 Methanol 5000 EC-000108-01-02 PCB 1248 Methanol 5000 EC-000109-01-02 PCB 1260 Methanol 5000 EC-000110-01-02 PCB 1016 Methanol 5000 EC-000111-01-05 Toxaphene Methanol 5000 EC-000124-02-03 4,4'-DDT Methanol 5000 EC-000125-01-01 PCB 1016 (Webb) Isooctane 1000 EC-000126-01-01 PCB 1221 Methanol 5000 EC-000129-01-01 PCB 1260 (Webb) Isooctane 1000 EC-000130-01-01 PCB 1262 Methanol 5000 EC-000131-01-01 PCB 1268 Acetone 2500 EC-000132-01-01 PCB 1242 (Webb) Isooctane 1000 EC-000135-01-01 PCB 1254 (Webb) Isooctane 1000 EV-000136-01-01 Bromochloromethane Methanol 10000 EV-000149-01-01 2,4-Dichlorotoluene Methanol 5000 EV-000150-01-01 o-Chlorotoluene Methanol 5000 EV-000151-01-01 m-Chlorotoluene Methanol 5000 EV-000152-01-01 p-Chlorotoluene Methanol 5000 EV-000153-01-01 4-Chlorobenzotrifluoride Methanol 5000 EV-000156-01-01 Pentachloronitrobenzene Methanol 5000 EV-000168-01-01 alpha, alpha, 2,6-Tetrachlorotoluene Methanol 5000 EV-000170-01-01 2,3-Dichloro-1-propene Methanol 10000 EV-000171-01-01 1,2-Dibromoethane Methanol 10000 EV-000173-01-03 c is-1,2-Dichloroethylene Methanol 10000 EV-000175-01-03 1,2,3-Trichlorobenzene Methanol 5000 EV-000176-01-03 1,3,5-Trichlorobenzene Methanol 5000 EV-000177-01-02 1,2,4,5-Tetrachlorobenzene Methanol 2500 EV-000180-01-02 2,4,6-Trichloroaniline Methanol 5000 EV-000182-01-03 3-Chlorophenol Methanol 5000 SP-4170-85-10 Compound Name Solvent (pg/mL) 5-6 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ug/mL) EV-000183-01-03 4-Chlorophenol Methanol 5000 EL-000188-01-02 Phenanthrene-dio Methanol 150 EL-000189-01-01 Phenol-ds Acetone 100 EL-000190-01-01 2,4-Dimethylphenol-3,516-d3 Acetone 100 EL-000191 -01-01 Pentachlorophenol-13Ce Acetone 100 EL-000192-01-01 Dimethyl phthalate-dg Acetone 150 EC-000193-01-01 2-Fluorophenol Acetone 100 EC-000194-01-01 2-Fluorobi phenyl Acetone 100 EC-000195-01-01 1-Fluoronaphthalene Acetone 100 EL-000196-01-01 1,4-Dichlorobutane-dg Methanol 150 EL-000197-01-01 2-Bromo-1-chloropropane-d6 Methanol 150 EL-000199-01-01 Benzo(g,h,i)perylene-13Ci2 Acetone 100 EC-000200-01-02 Chlorodibromomethane Methanol 10000 EV-000201-01-01 o-Xylene Methanol 5000 EV-000202-01-01 m-Xylene Methanol 5000 EV-000203-01-01 p-Xylene Methanol 5000 EV-000212-02-02 Bromoform Methanol 10000 EC-000214-01-02 1,3-Dichlorobenzene Methanol 5000 EC-000218-01-01 1,3-Dichloropropylene Methanol 10000 EC-000219-01-02 Mirex Acetone 1000 EC-000220-02-01 Aldrin Methanol 5000 EC-000222-01-01 2,3,5-Trichlorophenol Methanol 5000 EC-000224-02-01 2,4-Dimethylphenol Methanol 5000 EC-000225-01-01 1,2,3,4-Tetrachlorobenzene Methanol 2500 EC-000231-01-02 Dibenz(a,h)anthracene Dioxane 1000 EC-000232-01-03 Fluorobenzene Methanol 150 EC-000233-01-01 4-Bromofluorobenzene Methanol 150 EC-000234-01-01 4,4'-Dibromooctafluorobiphenyl Acetone 100 EC-000236-01-01 n-Decane Methanol 5000 EC-000237-01-01 n-Undecane Methanol 5000 5-7 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (pg/mL) EC-000238-01-04 n-Dodecane Methanol 5000 EC-000239-01-01 n-Tridecane Methanol 5000 EC-000240-01-01 n-Tetradecane Methanol 5000 EC-000241 -01-01 n-Pentadecane Methanol 5000 EC-000242-01-01 n-Heptadecane Methanol 2500 EC-000244-01-03 n-Nonadecane Methanol 1000 EC-000246-01-02 n-Tetracosane Acetone 500 EC-000250-01-02 o-Cresol Methanol 5000 EC-000251-01-01 m-Cresol Methanol 5000 EC-000252-01-01 p-Cresol Methanol 5000 EC-000255-01-01 Di butyl ether Methanol 5000 EC-000257-01-03 Styrene Methanol 5000 EC-000260-01-01 Pentachlorobenzene Methanol 2500 EC-000261-01-02 Dibenzofuran Methanol 5000 EC-000262-01-01 Diphenyl ether Methanol 5000 EC-000263-01-01 Diphenylamine Methanol 5000 EC-000270-01-01 Acrylamide Methanol 10000 EC-000271-01-01 Pyridine Methanol 10000 EC-000282-01-01 Diisodecyl phthalate Methanol 5000 EC-000284-01-05 Acetone Methanol 5000 EC-000285-01-01 Diethyl ether Methanol 4500 EC-000311-01-01 Methyl ethyl ketone Methanol 10000 EV-000360-01-02 Carbon tetrachloride Methanol 10000 EC-000394-01-01 n-Tricosane Acetone 2500 EC-000470-01-01 Halowax 1099 Methanol 5000 EC-000471-01-01 Halowax 1001 Methanol 5000 EC-000472-01-01 Halowax 1000 Methanol 5000 EV-000480-01-01 p-Dioxane Methanol 10000 EC-000536-02-02 Vinyl chloride 2-Propanol 4500 EC-000548-01-01 N,N-Dimethylformamide Methanol 5000 5-8 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (jig/mL) EC-000662-01-01 3-Nitrophenol Methanol 5000 EC-000715-01-01 Carbofuran Methanol 5000 EC-000718-01-01 Dieldrin Methanol 5000 EL-000776-01-01 1,2-Dichlorobenzene-d4 Methanol 150 EC-000952-01-01 p,p'-Methoxychlor Methanol 5000 EC-000954-04-01 Aldicarb CH3CN 1000 EC-000993-01-01 1,2-Dibromo-3-chloropropane Methanol 5000 EC-00099 5-02-01 Aldicarb sulfone CH3CH 1000 EC-000996-02-01 Aldicarb sulfoxide ch3cn 1000 5-9 ------- SP-4170-85-10 Environmental Sciences APPENDICES ------- Environmental Sciences SP-4170-85-10 APPENDIX A ORGANICS PROTOCOL ------- SP-4170-85-10 Environmental Sciences STANDARD MATERIALS - ORGANICS PROTOCOL VOLATILES ANALYSIS PESTICIDE ANALYSIS Internal Standards Bromochloromethane 1,4-Diflurobenzene Chlorobenzene-ds Surrogates Toluene-de 4-Bromofluorobenzene 1,2-Dichloroethane-d4 Matrix Spiking Compounds Chlorobenzene Toluene Benzene 1,1-Dichloroethene(1,1-Dichloroethylene) Trichloroethene (Trichloroethylene) Internal standards None Surrogates Dibutyl chlorendate Matrix Spiking Compounds Lindane (gamma-BHC) Heptachlor Aldrin Dieldrin Endrin 4,4'-DDT SEMI-VOLATILES ANALYSIS Internal standards 1,4-Dichlorobenzene-da Naphthalene-d8 Acenaphthene-dio Phenanthrene-dio Chrysene-di2 Perylene-di2 Surrogates Phenol-d6 2,4,6-Tribromophenol 2-Fluorophenol Nitrobenzene-ds Terphenyl-du 2-Fluorobiphenyl Matrix spiking Compounds 1,2,4-Trichlorobenzene Acenaphthene Di-n-butyl phthalate Pyrene N-Nitrosodi propylamine 1,4-Dichlorobenzene Pentachlorophenol Phenol 2-Chlorophenol 4-Chloro-3-methyl phenol 4-Nitrophenol ------- Environmental Sciences SP-4170-85-10 APPENDIX B HAZARDOUS SUBSTANCES LIST ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) Volatiles EC-000043-01-04 EC-000044-01-02 EC-000536-02-03 EC-000015-02-02 EC-000042-01-02 EC-000284-01-03 EV-000363-01-01 EC-000027-02-02 EC-000012-01-03 EC-000028-01-02 EC-000021-01-03 EC-000009-01-01 EC-000311-01-01 EC-000010-01-04 EC-000360-01-02 EV-000327-01-03 EC-000046-01-02 EC-000014-01-04 EC-000030-01-03 EC-000085-01-03 EC-000200-01-03 EC-000013-01-02 EC-000004-01-03 EC-000017-01-05 EC-000212-02-01 EV-000336-01-01 Methyl chloride (Chloromethane) 2-Propanol Methyl bromide (Bromomethane) 2-Propanol Vinyl chloride 2-Propanol Chloroethane 2-Propanol Methylene chloride Methanol Acetone Methanol Carbon disulfide Methanol 1,1-Dichloroethylene p-Dioxane (1,1-Dichloroethene) 1.1-Dichloroethane Methanol trans- 1,2-Dichoroethylene Methanol Chloroform Methanol 1.2-Dichloroethane Methanol Methyl ethyl ketone (2-Butanone) Methanol 1.1.1-Trichloroethane Methanol Carbon tetrachloride Methanol Vinyl acetate p-Dioxane Dichlorobromomethane Methanol (Bromodichloromethane) 1,1,2,2-Tetrachloroethane Methanol 1,2-Dichloropropane Methanol Trichloroethylene (Trichloroethene) Methanol Chlorodibromomethane Methanol (Dibromochloromethane) 1.1.2-Trichloroethane Methanol Benzene Methanol 2-Chloroethyl vinyl ether Methanol Bromoform Methanol 2-Hexanone Methanol 10000 9940 4500 11000 10000 5000 5000 5000 10000 10000 10000 10000 10000 10000 10000 5000 10000 10000 10000 10000 10000 10000 10000 10000 10000 5000 ------- SP-4170-85-10 Environmental Sciences NSI-ESCode Compound Name Solvent EV-000349-01-01 4-Methyl-2-pentanone Methanol 5000 EC-000083-01-02 Tetrachloroethene (Tetrachloroethylene) Methanol 10000 EC-000084-01-06 Toluene Methanol 10000 EC-000006-01-05 Chlorobenzene Methanol 10000 EC-000036-01-02 Ethyl benzene Methanol 10000 EC-000257-01-01 Styrene Methanol 5000 EC-000201-01-01 o-Xylene Methanol 5000 EC-000202-01-01 m-Xylene Methanol 5000 EC-000203-01-01 p-Xylene Methanol 5000 C-069 c/s/trans-1,3-Dichloropropene Methanol Semi-volatiles EC-000059-01-03 N-Nitrosodimethylamine Methanol 5000 EC-000063-01-05 Phenol Methanol 5000 EV-000542-01-04 Aniline Methanol 5000 EC-000016-01-01 b/s(2-Chloroethyl)ether Methanol 5000 EC-000022-03-02 2-Chlorophenol Methanol 5000 EC-000214-01-02 1,3-Dichlorobenzene Methanol 5000 EC-000025-01-05 1,4-Dichlorobenzene Methanol 5000 EV-000326-01-01 Benzyl alcohol CH2CI2 1000 EC-000023-01-05 1,2-Dichlorobenzene Methanol 5000 EC-000250-01-02 2-Methyl phenol Methanol 5000 (o-Cresol) EC-000040-01-02 b/s(2-Chloroisopropyl)ether Methanol 5000 EC-000252-01-01 4-Methyl phenol Methanol 5000 (p-Cresol) EC-000061-01-04 N-Nitroso-di-n-propylamine Methanol 5000 EC-000011-01-02 Hexachloroethane Methanol 5000 EC-000054-01-08 Nitrobenzene Methanol 5000 ------- ~00 SP-4170-85-10 Environmental Sciences NSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000052-01-02 Isophorone Methanol 5000 EC-000055-01-03 2-Nitrophenol Methanol 5000 EC-000224-02-01 2,4-Dimethylphenol Methanol 5000 EV-000541-01-01 Benzoic acid CH2CI2 1000 EC-000041-01-02 b/s(2-Chloroethoxy)methane Methanol 5000 EC-000029-01-04 2,4-Dichlorophenol Methanol 5000 EC-000007-01-05 1,2,4-Trichlorobenzene Methanol 5000 EC-000053-01-05 Naphthalene Methanol 5000 EV-000305-01-04 4-Chloroaniline Methanol 5000 EC-000050-01-02 Hexachlorobutadiene Methanol 5000 EV-000020-02-01 4-Chloro-3-methyl phenol Methanol 5000 EV-000562-01-01 2-Methyl naphthalene ch2ci2 1000 EC-000051-01-03 Hexachlorocydopentadiene Methanol 5000 EC-000019-04-02 2,4,6-Trichlorophenol Methanol 5000 EV-000179-01-01 2,4,5-Trichlorophenol ch2ci2 1000 EC-000018-01-03 2-Chloroanaphthalene Methanol 5000 EV-000324-01-02 2-Nitroaniline Benzene 1000 EC-000069-01-03 Dimethyl phthalate Methanol 5000 EC-000075-01-04 Acenaphthalene Methanol 5000 EV-000325-01-02 3-Nitroaniline Benzene 1000 EC-000001-01-05 Acenaphthene Methanol 5000 EC-000057-01-07 2,4-Dinitrophenol Methanol 5000 EC-000056-01-05 4-Nitrophenol Methanol 5000 EC-000261-01-01 Dibenzofuran ch2ci2 1000 EC-000033-02-02 2,4-Dinitrotoluene Methanol 5000 EC-000034-01-03 2,6-Dinitrotoluene Methanol 5000 EC-000068-01-03 Diethyl phthalate Methanol 5000 EC-000038-01-01 4-Chlorophenyl phenyl ether Methanol 5000 EC-000078-01-03 Fluorene Methanol 5000 EV-000342-01-02 4-Nitroaniline Benzene 1000 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000058-01-03 EC-000060-01-04 EC-000039-01-03 EC-000008-01-03 EC-000062-01-04 EC-000079-01-03 EC-000076-01-03 EC-000066-01-05 EC-000037-01-05 EC-000005-01-02 EC-000082-01-05 EC-000065-01-01 EC-000026-01-02 EC-000070-01-04 EC-000064-01-03 EC-000074-01-04 EC-000067-01-03 EC-000072-01-03 EC-000073-01-03 EC-000071-01-03 EC-000081-01-01 EC-000231-01-02 EC-000077-01-02 4,6-Dinitro-2-methyl phenol (4,6-Dinitro-o-cresol) N-Nitrosodiphenylamine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-butyl phthalate Fluoranthene Benzidine Pyrene Butyl benzyl phthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene b/s(2-Ethylhexyl)phthalate Chrysene Di-n-octyl phthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene lndeno(1,2,3-c,d)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene Methanol CH2CI2 Methanol Acetone Methanol Methanol Acetone Methanol Methanol Methanol Methanol Methanol Methanol Methanol Methanol Acetone Methanol Acetone Acetone Aceone Acetone p-Dioxane p-Dioxane 5000 2000 5000 1000 5000 5000 1000 5000 5000 5000 1000 5000 5000 1000 5000 1000 5000 2500 1000 1000 500 1000 1000 Pesticides EC-000100-01-03 EC-000101-01-03 EC-000103-01-01 alpha-BHC beta-BHC delta-BHC Methanol Acetone Methanol 2500 2500 1000 ------- Environmental Sciences SP-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (ng/mL) EC-000102-01-03 gamma-BHC Methanol 5000 EC-000098-01-04 Heptachlor Methanol 5000 EC-000220-02-02 Aldr'in Methanol 5000 EC-000099-01-02 Heptachlor epoxide Methanol 5000 EC-000093-01-04 alpha-Endosulfan p-Dioxane 5000 EC-000718-01-01 Dieldrin Methanol 5000 EC-000091 -01 -03 4,4'-DDE Methanol 5000 EC-000096-01-04 Endrin Methanol 5000 EC-000094-01-04 beta-Endosulfan p-Dioxane 5000 EC-000092-01-03 4,4'-DDD Methanol 5000 EC-000097-01-03 Endrin aldehyde Methanol 5000 EC-000095-01-02 Endosulfan sulfate Methanol 5000 EC-000124-02-04 4,4'-DDT Methanol 5000 EV-001036-01-01 Endrin ketone Ethyl acetate 2000 EC-000952-02-04 p,p'-Methoxychlor Hexane 5000 EC-000089-01-04 Chlordane Hexane 10000 EC-000111-01-03 Toxaphene Hexane 5000 EC-000125-01-02 Aroclor 1016 Hexane 5000 EC-000126-01-02 Aroclor 1221 Hexane 5000 EC-000107-01-03 Aroclor 1232 Hexane 5000 EC-000104-01-03 Aroclor 1242 Hexane 5000 EC-000108-01-03 Aroclor 1248 Hexane 5000 EC-000105-01-03 Aroclor 1254 Hexane 5000 EC-000109-01-03 Aroclor 1260 Hexane 5000 ------- Environmental Sciences SP-4170-85-10 APPENDIX C SURROGATE STANDARDS ------- ~SB SP-4170-85-10 Environmental Sciences NSI-ES Code Compound Name Solvent Cone. (ng/mL) EV-000233-01-02 4-Bromofluorobenzene Methanol 5000 ES-000876-01-02 1,2-Dichloroethane-d4 Methanol 5000 ES-000143-03-01 Toluene-ds Methanol 5000 ES-000166-02-02 Nitrobenzene-ds Methanol 5000 EV-000194-03-01 2-Fluorobiphenyl Methanol 5000 EV-000193-04-01 2-Fluorophenol Methanol 5000 ES-000909-01-04 p-Terphenyl-di4 Tetrahydrofuran 5000 ES-000531-05-01 Phenol-ds ch2ci2 5000 EV-000875-01-01 2,4,6-Tribromophenol ch2ci2 5000 EV-000798-01-01 Dibutyl chlorendate ch2ci2 5000 ------- Environmental Sciences SP-4170-85-10 APPENDIX D INTERNAL STANDARDS ------- Environmental Sciences 5P-4170-85-10 NSI-ES Code Compound Name Solvent Cone. (jig/mL) EV-001010-01 -0 DFTPP ch2ci2 1000 EV-000136-01-01 Bromochloromethane Methanol 10000 EV-000791-02-02 1,4-Difluorobenzene Methanol 10000 ES-001021 -02-01 Chlorobenzene-ds CH2CI2 1000 ES-000140-02-01 Naphthalene-de ch2ci2 5000 ES-000230-01-03 Phenanthrene-dio ch2ci2 1000 ES-000897-01-01 1,4-Dichlorobenzene ch2ci2 5000 ES-000229-03-01 Chrysene-di2 ch2ci2 1000 ES-000467-01-03 Acenaphthene-dio Benzene 2000 ES-001009-01-01 Perylene-di2 cs2 2000 ------- |