Synthetic Soil Matrix (Ssm-Sarm) User'S Manual


SYNTHETIC SOIL MATRIX
(SSM-SARM)
USER'S MANUAL
U.S. Environmental Protection Agency
Risk Reduction Engineering Laboratory
Releases Control Branch
Woodbridge Avenue
Edison, New Jersey 08837

December 1988

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TABLE OF CONTENTS
Page
1.0 Purpose of Manual	1
2.0 Synthetic Soil Composition	2
Table 1 - Target Contaminant Concentrations for Synthetic
Soil Matrix	4
3.0 Test Material Acquisition Procedure	5
Certification Form	6
4,0 Receiving Instructions	7
5.0 Handling and Storage	8
Synthetic Soil Matrix Material Safety Data Sheets	11
6.0 Waste/Residual Shipping and Disposal Procedures	15
7.0 Recording and Reporting of Results and Data	16
Appendix A Material Safety Data Sheets for Chemicals Added to
Synthetic Soil	A-l

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1.0 PURPOSE OF MANUAL
This manual provides specific information on the care and handling of spiked
synthetic soil samples prepared by the USEPA for use in evaluating the
performance of treatment technologies for contaminated soils. The synthetic soil
has been prepared from natural "uncontaminated" soil materials to which a
complement of chemical "contaminants" has been added. The chemicals chosen
were selected because of their common occurrence at hazardous waste sites.
Many of these chemicals possess toxic and/or hazardous properties that the user
should recognize prior to using this test material. This manual contains sections
addressing 1) Physical/Chemical Properties of Test Materials, 2) Test Material
Acquisition Procedure, 3) Test Material Receiving Instructions, 4) Handling and
Storage Instructions, 5) Waste/Residual Shipping and Disposal Procedures, 6)
Recording and Reporting of Results and Data, and Material Safety Data Sheets.
Users of the test material must read this manual, complete the Certification
Form in Section 3, and return the completed form to EPA before samples will be
sent. By signing and returning the Certification Form, the user certifies that he
or she has read the manual and understands the hazards associated with
handling the test material. Further, he or she certifies that all individuals using
and/or handling the material or residuals under their direction will first be made
aware of the hazards associated with the test material and that it will be handled
and disposed of appropriately.
Further information on this synthetic soil can be obtained by contacting:
The Synthetic Soil Matrix Hotline
U.S. Environmental Protection Agency
Releases Control Branch
Woodbridge Avenue (GSA Raritan Depot, Bldg. 209, Bay F)
Edison, N. J. 00037
Phone 201/321-4372
or
U. S. Environmental Protection Agency
Risk Reduction Engineering Laboratory
Releases Control Branch
Woodbridge Avenue
Edison, N.J. 08837
Phone 201/321-6627
8/340-6627 (FTS)
1

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2.0 SYNTHETIC SOIL COMPOSITION
The sample(s) that will be provided to you by the U.S. EPA were prepared by
blending together a clean synthetic soil and a select group of organic and
inorganic chemicals known to be widely occurring at uncontrolled hazardous
waste sites.
The stock of clean soil that was used to prepare the spiked sample you will receive
was blended from the following components:
Component	Weight %
Sand	31
Gravel No. 9	6
Silt	28
Topsoil	20
Clay	35
Montmorillonite (5%)
Kaolinite (10%)		
100
Standard sieve tests to determine the grain size distribution of the soil reported the
following weight percents:
Component	Weight %
Sand	56
Gravel	3
Silt	28
Clay	12
100%
The clean soil has been analyzed and found to be free of anthropogenic organic
contamination; its natural organic content produces a TOC (total organic carbon)
of 3-20 mg/kg. The cation exchange capacity of the soil averages 133 meq/100
grams, and its natural pH (before addition of chemicals) is 8-8.5. The soil
naturally contains small amounts (< 10 ppm) of arsenic, beryllium, cadmium,,
chromium, cobalt, copper, lead, nickel, and silver; other elements found to be
naturally present include aluminum (13,000 ppm), calcium (131,000 ppm), iron
(10,300 ppm), potassium (1220 ppm), sodium (198 ppm), and zinc (33 ppm).
Several chemicals were subsequently added to portions of the clean soil to produce
the synthetic soil sample(s) to be used for treatability testing. The chemicals were
added in various proportions to produce four (4) different sample types with high
and/or low levels of organic and inorganic contaminants for treatability testing.
The sample(s) you have been/will be sent are from one or more of the following
four synthetic soil sample types:
2

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I	High organics (20,800 ppm added volatiles plus 10,000 ppm added
semivolatiles) and low metals (1,000 ppm added metals)
II	Low organics (2,080 ppm added volatiles plus 1,000 ppm added
semivolatiles) and low metals (1,000 ppm added metals)
III	Low organics (2,080 ppm added volatiles plus 1,000 ppm added
semivolatiles) and high metals (50,000 ppm added metals)
IV	High organics (20,800 ppm added volatiles plus 10,000 ppm added
semivolatiles) and high metals (50,000 ppm added metals)
The chemicals added to the synthetic soil are listed below:
»Volatile nrgnnira
~Metals
Acetone
Chlorobenzene
1,2-Dichloroethane
Ethylbenzene
Styrene
Tetrachloroethylene
Xylene
•Semivolatile organics
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinn
Anthracene
Bis(2-ethylhexyl)phthalate
Pentachlorophenol (in SARM) or Hexachlorobenzene (in SSM)
The target concentrations for each chemical in the four soil sample types are
shown in Table 1. Please review this list carefully. Many of the chemicals added
are hazardous by virtue of their flammability or toxic properties. A Material
Safety Data Sheet (MSDS) describing the known or anticipated hazards of the
synthetic soil samples is included in Section 5, along with a general discussion of
health/safety concerns regarding the handling and use of this material. The
implications of this information should be understood and reviewed with all
personnel to be handling this material. In addition, MSDSs for each of the
chemicals added to the soil are included in Appendix A.
At the time of preparation of the batch from which your sample was taken, a
partial chemical analysis was completed to verify that the target contaminant
levels were achieved within an accepted range (typically ± 25-30 %). However, it
has been found that the measurable concentrations of these constituents may vary
from one container to another or with age. It is therefore recommended that
baseline analyses be performed by users of these materials as dictated by the
requirements of the individual research/demonstration to which they are being
applied.
3

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TABLE 1. TARGET CONTAINMENT CONCENTRATIONS
FOR SYNTHETIC SOIL MATRIX
(mg/kg)
(High organic, (Low organic, (Low organic, (High organic,
Analyte	low metal)	low metal) high metal) high metal)
Volatiles




Acetone
6,800
680
680
6,800
Chlorobenzene
400
40
40
400
1,2-Dichloroethane
600
60
60
600
Ethylbenzene
3,200
320
320
3,200
Styrene
1,000
100
100
1,000
Tetrachloroethylene
600
60
60
600
Xylene
8,200
820
820
8,200
Semivolatiles




Anthracene
6,500
650
650
6,500
Bis(2-ethylhexyl)phthalate
2,500
250
250
2,500
Pentachlorophenol or

•


hexachlorobenzene3
1,000
100
100
1,000
Inorganics*3




Arsenic
10
10
500
500
Cadmium
20
20
1,000
1,000
Chromium
30
30
1,500
1,500
Copper
190
190
9,500
9,500
Lead
280
280
14,000
14,000
Nickel
20
20
1,000
1,000
Zinc
450
450
22,500
22,500
a Pentachlorophenol used in SARM, hexachlorobenzene in SSM.
k Metals added as salts or oxides, see MSDS in appendices to determine form used in spiking.
4

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3.0 TEST MATERIAL ACQUISITION PROCEDURE
Having first read and understood Sections 1, 2, 4, 5, 6, and 7, and after accepting
the requirements and responsibilities set forth therein, certification (and
submission) of such on the following form is necessary prior to completing
arrangements for preparation/shipping of the requested test material.
It is recommended that written and/or verbal communication take place between
the requester and SSM/SARM RREL project representative prior to submitting
certification/request for material. This will assure the requester of the availability
and necessary amount of the desired formula.
Communications regarding SSM/SARM should be addressed as noted in Section 1
of this User's Manual.
5

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CERTIFICATION FORM
(name)	(title)
(company) (address)
	 Phone:	
certify that I have read the Synthetic Soil Matrix (SSM/SARM) User's Manual and
am aware of the hazardous nature of the material.	
(company)
takes full responsibility for the safe tianHling and proper disposal of the used
synthetic soil and/or contaminated materials.	
(company)
holds the U. S. Environmental Protection Agency harmless for. any hazards
associated with the use of these materials or any liability resulting from the
disposal of the synthetic soil and/or contaminated materials.
Signature:	 Date:	
Subscribed and sworn to before me this	dayof	, 19	
Notary Public in and for the State of
Notarial Seal
My Commission Expires		 19_
User: Read the Synthetic Soil User's Manual, complete the above Certification
Form and return it to the address below along with a letter describing which
SSM/SARM is requested, amount(s) needed and the intended use.
Mail to: U.S. Environmental Protection Agency
Releases Control Branch
GSA Raritan Depot, Bldg 10
Woodbridge Avenue
Edison, N.J. 08837
Attn: SSM/SARM Coordinator
6

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4.0 RECEIVING INSTRUCTIONS
After EPA has received the signed Certification Form, they will forward samples
of the synthetic soil to you for use in treatment technology experiments. Upon
receipt of the synthetic soil samples, check the labels on the container(s) you've
received against those indicated on the accompanying Chain of Custody Forms;
then complete the accompanying Chain of Custody Form, sign it, and return it to
the designated address by registered mail within 3 days of sample receipt. (See
example Chain of Custody Form below). Be sure to follow the safety instructions
outlined in Section 5 when opening the shipping container to inspect its contents.
If the sample container labels and chain of custody form do not match, or if a
sample container is punctured or broken, immediately place container in a well
ventilated, secure area while containing any release of contents and call the SSM
Hotline (201/321-4372) or the U.S. EPA Releases Control Branch in Edison, NJ.
(201/321-6677) for instructions.
SYNTHETIC SOIL MATRIX CHAIN OF CUSTODY FORM
Caution: This material is hazardous. Read all accompanying information and complete this form
before opening or using the contents.
SAMPT.E INFORMATION
Sample ID Number:
Date Shipped: : Date Received:
Shipped by: Received by;
(name & address) (name & address)
Condition of container and seal:
Contact the following person immediately if the sample container or seal is damaged or broken:
Attn: SSM/SARM Coordinator Commercial: (201) 321-6677
U.S. Environmental Protection Agency FTS: 8/340-6677
Releases Control Branch
GSA Raritan Depot, Bldg 10
Woodbridge Avenue
Edison, NJ 08837
I hereby acknowledge receipt of the synthetic soil samples . I am cognizant of its hazardous nature
and take full responsibility for its proper handling and disposal. I agree to report results of any tests
in a timely manner to EPA and to follow as closely as possible the recommendations set forth in the
handbook for its proper disposal.
Company Name:
Address: Phone:
Name & Title:
Signature:
7

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5.0 HANDLING AND STORAGE
The synthetic soils contain a number of hazardous chemicals that require careful
handling to minimize the potential hazards associated with exposure to the
material. Components of the mixture include irritants, sensitizers,
photosensitizers, toxics and carcinogens that can adversely affect human health.
Care must be taken in handling and disposal to minimize exposure and release to
the environment. A Material Safety Data Sheet (MSDS) summarizing the health
hazards and safety measures needed for protecting users of the material is
included at the end of the section. MSDS's for these individual constituents are
included in Appendix A.
While handling containers of synthetic soil, care must be taken to assure both
sample container integrity and the safety of all personnel. Depending on the size
of the samples requested, the synthetic soil will be shipped in either half-gallon
glass jars, five-gallon metal pails, or 55-gallon steel drums. Although the outside
surfaces of all sample containers have been wiped clean with a solvent to remove
visible debris and contamination prior to shipment, personnel involved with
handling these containers should never assume them to be totally free of
contaminants on the outside surfaces. At a minimum, hand, eye and splash
protection should be worn while handling sample containers.
While in the process of checking in or moving the sample containers, note the
condition of the containers themselves. Full 55-gallon drums are easily
punctured if set on any hard, sharp object, such as a small stones, nails, or steel
bolts. Steel sample containers should be carefully inspected for punctures and
other signs of damage. Both 5-gallon and 55-gallon steel containers should be
placed on pallets.
The handling of the half-gallon glass containers requires more caution because
these containers are fragile and subject to breakage. These samples are packed in
coolers with shock-absorbing material to protect from breakage and insulate
during shipment. However, packaging techniques are not foolproof, and
handling in transit is often rough; as a result, glass sample containers may be
broken within the shipping coolers. This condition may cause a build up of
volatile organics within the cooler, which would be released upon opening. The
safest and simplest method of opening shipment coolers for the first time is
within a vented fume hood; by personnel wearing hand, eye and splash
protection. If a fume hood is not available, the cooler should be first opened in a
well ventilated area (preferably outdoors or on an open loading dock). In this
case, increased personal protection is recommended until the cooler has been
opened and the glass containers have been examined for possible breakage. If not
opening shipment coolers in a vented fume hood, the following level C protective
equipment is recommended:
•	Air purifying respirator with combination organic/HEPA filter cartridge(s)
•	lab coat or overalls
•	protective gloves; add Viton or butyl outer gloves if actual handling of
synthetic soil from broken containers is necessary
8

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In the event that any of the sample containers are found to be broken, place the
container and its contents plus any contaminated packing material in a suitable
container with a tight sealing lid, and immediately notify the SSM Hotline or the
U.S. EPA in Edison, NJ (see MSD sheet for phone numbers).
When opening sample containers for the actual removal and use of the synthetic
soil, personal protective equipment is required. Depending on the quantity of soil
being handled, a variety of potential exposure levels may be expected.
Modification of protective equipment to match these expected hazards is essential
for worker safety and comfort. The following are recommended levels of
protection under various usage conditions:
Small quantity usage, lab/bench scale (0.5 gallon containers)
•	properly vented fume hood, or air purirying respirator with combination
organic vapor/HEPA filter cartridges
•	lab coat or overall
•	protective gloves
•	Viton or butyl outer glove if direct contact is anticipated
Medium quantity usage, lab/bench scale (5 gallon containers)
•	properly vented fume hood, or air purifying respirator with combination
organic vapor/HEPA filter cartridges
•	lab coat or overall
•	protective gloves
•	Viton or butyl outer glove if direct contact is anticipated
•	air monitoring by direct reading general detector if operation cannot be
contained within a fume hood
•	if air monitoring readings exceed 5 ppm over background, all personnel in
area should don respiratory protection
•	if air monitoring readings exceed APR cartridge limits, use supplied air
Large quantity usage, pilot scale (55 gallon containers)
•	Air purifying respirator with combination organic vapor/HEPA filter
cartridges
•	safety face shield
•	coveralls or splash suit
•	disposable boot covers
•	protective inner gloves and Viton or butyl outer gloves
•	wrist and ankle joints taped
•	air monitoring (as noted above)
SSM/SARM materials should be stored in a manner similar to laboratory
reagents having similar properties. It is suggested that secure, ventilated storage
be provided all samples. Refrigeration (explosion-proof) is recommended,
although this may be unfeasible for 5- and 55-gallon containers. If refrigeration is
9

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unavailable, glass containers should be stored in a cool, dark place used solely for
the purpose of storing hazardous substances or environmental samples. It is
advisable to leave the glass containers in their coolers during storage. If
refrigerated space is not available, the coolers may be periodically charged with
frozen blue ice packages to keep the samples as cool as possible during storage. If
it is not possible to refrigerate the larger containers, they should at least be kept
dry and covered, out of direct sunlight, in a well-ventilated, secure area. These
containers should also be placed on pallets and bermed.
Prior to use, the synthetic soils may be stored as hazardous substances, however,
residuals from their use must be stored as hazardous waste (see Section 6) unless
a delisting petition is submitted and approved.
1°

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SYNTHETIC SOIL MATRIX MATERIAL SAFETY DATA SHEET
Page 1 of 4
SECTION 1 - SOURCE AND CONTACTS
Manufacturer's Name
Emergency Telephone Numbers
U. S. Environmental Protection Agency
CHEMTREC 1-800-424-9300
Address (Number, Street, City, State, and ZIP Code)
Telephone Numbers for Information
GSA Raritan Depot, Bldg. 10
U. S. EPA: (201) 321-6677
Woodbridge Avenue
FTS 8/340-6677
Edison, N.J. 08837
EPA SSM Hotline 201/321-4372
IDENTITY
Synthetic Soil Matrix I, II, III, or IV
Date Prepared
10-1-88	
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Contaminant
CAS No.
OSHA PEL
ACGIH TLV
NIOSH Limits(b)
Concentration(ppm)
Acetone
67-64-1
1000 ppm
750 ppm
250 ppm
680 to 6,800
Chlorobenzene
108-90-7
75 ppm
75 ppm

40 to 400
1,2-Dichloroethane
107-06-02
-
10 ppm

60 to 600
Ethylbenzene
100-41-4
100 ppm
100 ppm

320 to 3200
1,1,2,2-Tetrachloroethylene
127-18-4
100 ppm
50 ppm

60 to 600
Styrene
100-42-5
100 ppm
50 ppm

100 to 1000
Xylene
1330-20-7
100 ppm
100 ppm

820 to 8200
Anthracene
120-12-7
-
lowest possible(a)
0.1 mg/cu.m.
650 to 6500
Bis(2-ethylhexyl)phthalate
117-81-7
-
0.5 mg/cu.m.

250 to 2500
Pentachlorophenol
87-86-5
0.5 ppm
0.5 ppm

100 to 1000
or Hexachlorobenzene
1 18-74-1
-
lowest possible

100 to 1000
Arsenic
7440-38-2
10 ug/cu.m.
2 ug/cu.m.
10 ug/cu.m.
10 to 500
Cadmium
7440-43-9
0.2 mg/cu.m.
lowest possible
20 ppm
20 to 1000
Chromium
7440-47-3
0.5 mg/cu.m.
0.5 mg/cu.m.

30 to 1500
Copper
1 332-14-5
1 mg/cu.m.
1 mg/cu.m.
190 ppm
190 to 9500
Lead
7446-1 4-2
0.5 mg/cu.m.
0.15 mg/cu.m.
<0.1 mg/cu.m.
280 to 14000
Nickel
7440-02-0
1 mg/cu.m.
0.1 mg/cu.m.

30 to 1000
Zinc
1314-13-2
5 mg/cu.m.
10 mq/cu.m.
5 mq/cu.m.
450 to 22500 .
(a)	Suspected human carcinogen
(b)	Recommended 10-hr. TWA.

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SYNTHETIC SOIL MATRIX MATERIAL SAFETY DATA SHEET
Page 2 of 4
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point Solubility in water
Not applicable Not applicable
Evaporation Rate
Not Applicable
Vapor Pressure (mm Hg) Specific Gravity (Water=1)
Unknown for mixture of volatile constituents Approximately 2 (Water=1)
Melting Point
Not Applicable
Vapor Density (Air=1)
Unknown for mixture of volatile constituents

Appearance & Odor
Grayish brown soil, moist & plastic in consistency, strong, disagreeable odor

to
SECTION IV - FIRE AND EXPLOSION HAZARD DATA		
Flash Point (Method Used)	Flammable Limits	LEL	UEL
>160° F. (Setaflash Closed Cup)	unknown	unknown	unknown
Extinguishing Media
Foam or dry chemical
Special Fire Fighting Procedures
In case of fire, wear respiratory protection to prevent inhalation of smoke and fumes; apply liberal amounts of foam or dry chemical
to extinguish flame. Wear protective clothing to prevent skin contact with soil, smoke and fumes.
Unusual Fire and Explosion Hazards
Dichloroethane and tetrachloroethylene may release phosgene upon combustion.
Organic compounds may form other hazardous products of incomplete combustion.
In the presence of a strong base, tetrachloroethylene may decompose to form acetylene, which is both flammable and explosive.

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SYNTHETIC SOIL MATRIX MATERIAL SAFETY DATA SHEET
Page 3 of 4
SECTION V - REACTIVITY DATA
Stability Stable
X
Conditions to Avoid
Unstable

Some components of the mixture can be unstable if subjected to heat or to

strong oxidizers, however, reactions are not known at the concentrations present.
Incompatibility (Materials
to avoid)
Some components (dichloroethane, bis(2-ethylhexyl)phthalate, acetone, xylene, pentachlorophenol, hexachlorobenzene, and styrene)
are incompatible with strong oxidizers.
Hazardous Decomposition
or
Byproducts
Acetylene, phosgene

Hazardous Polymerization

will occur rn

Will not occur[XjSee conditions to avoid below
Conditions to Avoid

Not fully known. Contact with strong oxidizers may be hazardous since several constituents in the soil
are known or suspected to be reactive under such conditions.
£
SECTION VI ¦ HEALTH HAZARD DATA
Routes of Entry:
Skin Ingestion 0 Inhalation 0
Health Hazards (Acute and chronic):
Health hazards of the mixture not known. Individual components include irritants, sensitizers, photosensitizers, central nervous
system depressants, toxics, and carcinogens. Individually these may cause damage to the the gastrointestinal system, nervous system,
lungs, liver, kidneys, spleen, adrenals, and heart. The potentiation effects of the mixture of these constituents is suspected, but not
documented.
Carcinogenicity:
Several components are known (styrene) or suspected (1,2-dichloroethane, tetrachloroethylene, anthracene) carcinogens.
Signs and Symptoms of Exposure:
Symptoms of exposure to components may include headache, dizziness and nausea, shortness of breath, fatigue, as well as more serious,
potentially life-threatening conditions.
Medical Conditions Generally Aggravated by Exposure •
Unknown. Exposure to tetrachlorethylene can cause increased sensitivity of the heart to adrenalin.

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SYNTHETIC SOIL MATRIX MATERIAL SAFETY DATA SHEET
Page 4 of 4
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE	
Steps to be Taken in Case Material is Released or Spilled
Sweep up ail spills and seal in a hazardous waste drum or container
Waste Disposal Method
Dispose as a hazardous waste in accordance with all RCRA & DOT regulations and all applicable state and local regulations.
Precautions to be Taken in Handling and Storing
Handle as a hazardous material. Minimize exposure by storing in closed containers. Handle only with appropriate protection.
(See Section VIII below).	
£
SECTION VIII - CONTROL MEASURES	
Respiratory Protection (Specify Type)
Dual cartridge respirator with organic vapor and dust cartridges.
Ventilation
Use in hood or outdoors in a well-ventilated area
Protective Gloves	Eye Protection
Viton or butyl	Wear goggles or face shield
Other Protective Clothing or Equipment
Wear full protective suits with gloves, boots, and respirator.
Work/Hygienic Practices
Minimize exposure by use of gloves, boots, suits and face shields. Remove contaminated clothing before eating, drinking,
smoking, applying cosmetics, etc. or leaving the work area.

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6.0 WASTE/RESIDUAL SHIPPING AND DISPOSAL PROCEDURES
Used synthetic soil as well as leftover unused synthetic soil samples, residues
from treatment experiments, and contaminated materials or equipment that
cannot be decontaminated (i.e., disposable gloves, booties, etc.) must be handled
and disposed of as a hazardous waste, with the appropriate packaging, labeling,
manifests, and disposal.
Small quantities (100 kg. or less) of used synthetic soil and/or contaminated
materials can be disposed of in lab-packs with other small amounts of hazardous
wastes/materials. Larger quantities (>100 kg) must be packaged and transported
either in bulk or in individual containers and treated or disposed of at a RCRA-
permitted facility. If disposed of in drums, they must be appropriately labeled and
must conform to DOT requirements (see Department of Transportation
Regulations in 49 CFR Part 172 for further details of packaging and shipping
requirements). The materials must be manifested as a RCRA waste, with the
user listed as the generator. The U.S. DOT description is as follows:
Hazardous Waste, Solid, n.o.s.
ORM-E
NA9189
The materials can be shipped only by a RCRA permitted hazardous waste
transporter.
It is the responsibility of the user to properly package, manifest, ship and dispose
of the materials remaining from use of the synthetic soil. The user should
maintain records of the manifest. The user should use good judgement in
selecting a disposal firm, remembering that as generator, they are responsible for
proper disposal.
As with any hazardous waste stream, a petition to delist the material as a
hazardous waste is an option for treatment technology testing residuals. U. S.
EPA Guidance for preparing a hazardous waste delisting petition is available. It
should be noted, however, that this process is somewhat time and resource
consuming, and is therefore not recommended for lab/bench scale testing
residuals. Some net cost savings may be realized during pilot scale testing or
demonstration.
15

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7.0 RECORDING AND REPORTING OF RESULTS AND DATA
EPA has prepared the synthetic soil samples and provided them to interested
parties so that they can test the effectiveness of various treatment technologies.
Use of the same synthetic soil matrix in many treatment technology applications
allows a direct comparison of treatment effectiveness data among various new
technologies. Thus the results of any experiments using the synthetic soil
material is of great interest to EPA.
As soon as possible after the conclusion of any study using the synthetic soil
mixture, please prepare a written report describing the technology tested, the
experimental design, the results and any conclusions, observations or comments.
Include analytical test methods used and any quality assurance data obtained.
Include also, the method of generated hazardous waste treatment/disposal. The
written test results report should be sent to:
U.S. Environmental Protection Agency
Risk Reduction Engineering Laboratory
Releases Control Branch
GSA Raritan Depot, Building 10
Woodbridge Avenue
Edison, N.J. 08837
Attn: SSM/SARM Coordinator
16

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APPENDIX A
MATERIAL SAFETY DATA SHEETS FOR
CHEMICALS ADDED TO SYNTHETIC SOIL

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MSDS INDEX
Spike Compound
Acetone
Anthracene
Arsenic
Cadmium
Chlorobenzene
Chromium
Copper
Dichloroethane
Ethylbenzene
Hexachlorobenzene (75%)
Hexachlorobenzene (99%)
Lead
Nickel
Pentachlorophenol
Phthalate, Bis (2 ethylhexyl)
Styrene
Tetrachloroethylene
Xylenes
Zinc
Beginning page
A-3
A-6
A-9
A-12
A-15
A-18
A-21
A-24
A-28
A-31
A-34
A-37
A-41
A-44
A-47
A-50
A-54
A-58
A-61
A-2

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©chemists helping chemists in research & industry
aldrich chemical co.
P.O. Bom 355. Ullwiu*—. Witco/ti/n 53X1 USA
Telephone (414) 273-3890
TWX: (910) 262-3052 Alflricnem Ml
Titan: 26 843 Aldrich Ml
FAX: (414) 273-4879
ATTN: SAFETY 0IRECT0R
ENVIRESPONSE, INC '
GSA RARITAN 06P0T
W000BRIDGE AVE
EDISON	NJ
GARY SEIBEL
DATE: 09/19/88
OUST S 924807 P.O. 4
08837
MATERIAL
S A F e T Y
0 A T A
SHEET
PAGE
	 IDENTIFICATION
NAME: ACETONE, 99*X
PROOUCT ft 17997-3
CAS « 67-64-1
MF: C3HoO
SYNONYMS
ACETON (GERMAN, OUTCH, POLISH) • ACETONE (ACGIH.OOT) • CHEVRON
ACETONE • OIMETHYLFORMALuEHYOE • GIMETHYLKETAL • DIMETHYL KETONE *
KETONE, DIMETHYL « KETONE PROPANE • EETA-KETOPROPANE • METHYL KETONE
PROPANONE • 2-PRCPANONt ~ PYROACETIC ACID ~ PYROACETIC ETHER * RCRA
WASTE NUMBER U002 * UN 1090 (DOT) •
TOXICITY HAZAKDS
RTECS C AL3150000
ACETONE
IRRITATION OATA
6YE-HMN 500 PPM
SKN-RBT 395 MG OPEN MLO
SKN-R9T 500 MG/24H MLO
EYE-RBT 3950 UG ScV
EYE-RBT 20 MG/2<»H MUD
TOXICITY OATA
UNR-MAN LDLO: 1159 MG/KG
ORL-RAT LD50:5 800 MG/KG
IHL-RAT LC50:50100 MG/M3/eH
IVN-RAT LD50:5500 MG/KG
CRL-MUS LD50:3000 MG/KG
IPR-MUS LD50: 1297 Mv»/KG
CRL-RBT LC50 : 5340 MG/KG
SKN-RBT LD50:20 GM/KG
REVIEWS, STANDARDS, AND REGULATIONS
ACGIH TLV-TwA 750 PPM; STEL 1000 PPM 85INA3 5,6,86
MSHA STANOARD—AIR:TWA 1000 PPM (2400 MG/M3) CTLVS* 3,3,71
OSHA STANDARD-AIR: TWA 1000 PPM FEREAC 39,2354u,74
NIOSH REL TO KETONES-A IR:TWA 590 MG/M3 MMWR»« 34( IS )',20S,85 _
EPA GENETOX PROGRAM 1986, NtGATLVfc: iHfc-CLONAL ASSAY; CELL TRANSFORM.
MOUSE EMBRYO
EPA GENETOX PROGRAM 1986, NEGATIVE:
EMBRYO
EPA GENETOX PROGRAM 1986, NEGATIVE:
EPA GENETOX PROGRAM I960, NE GaTIV E:
VITRO SCE-NONHUMAN
EPA TSCA CHEMICAL INVENTORY, 1986
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, MARCH 1988
NIOSH ANALYTICAL MfeTHOOS: SEE KETONES I, 1300	„	„
NTP CARCINOGENESIS STUDIcSJON TEST (PRECHRONIC STUDIES), JANUARY JL988
MEETS CRITERIA FOR PROPOScC USHA .1EUICAL RECJROS RULE FEREAC 47,30420
32
TARGET ORGAN JATA	„ „ „ %
BRAIN ANO COVERINGS (RECORDINGS FROM SPECIFIC ARcAS OF CNS)
SENSE CRGAN3 ANS SPECIAL SENSfcS (OTHER OLFACTION EFFECTS)
SENSE ORGANS ANU SPfCUL SfcNSES (CCllN JUNCTIVA iRRlTATION)
BEHAVIORAL (MUSCLt CONTRACTION OR SPASTICITY)
LUNGS, THORAX CR RESPIRATION (KESPI®. AToRY OPPRESSION)
LUNGS, THORAX OR RESPIRATION. (OTHck CHANGES)
JIHTAB 25,282*43
UCOS»« 5/7/70
85JCAE -,280,86
AJUPAA 29,1363,46
85JCAE -,280,86
85DCAI 2,73,70
JTEHD6 15,609,85
AIHAAP 20,364*59
NPIRI• 1,1,74
PCJOAU 14,162*80
SCCUR* —,I,61
FAGNAU 48A,86,70
UCDS** 5/7/70
CELL TRANSFORM.-KLV F.344 RAT
IN VITRO CYTOGcNETICS-NONHUMAN
HlSTIOINfc REVERSION-AMES TEST;
IN
392

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m ¦ m chemists helping chemists in research & industry	T«ieohon«: (4n> 273-3950
W A ^ _ _ _ _	_	_	_	TWX: (910) 262-3092 Aldrichwn Ml
m aldrich chemical co.
p.o. Soi 394. Ullwtutm. Wltcontln SOOl USA
Talttx: 28 843 Aldriefi Ml
FAX: (414) 273-4979
MATERIAL SAFETY DATA SHEET	PAGE: 2
CATALOG » 17997-3	NAME: ACETONE. 99-t-*
EFFECTS ON FERTILITY (POST-IMPLANTATION MORTALITY)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS)
DATA IS PRESENTED HfcKE• SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATIC
HEALTH HA2AR0 DATA
ACUTE EFFECTS
MAY BE HARMFUL BY INHALATION* INGESTION. OR SKIN ABSORPTION.
CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES ANO UPPER
RESPIRATORY TRACT.
FIRST AID
IN CASE OF CONTACT. IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
ASSURE AOEdUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIJS
WITH FINGERS.
FLUSH SKIN WITH WATcR.
IF INHALED. REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT. GIVE OXYGEN.
CALL A PHYSICIAN.
REMOVE AND WASH CONTA.M INATeO CLOTHING PROMPTLY.
MELTING POINT: -9M	'»»»< n»
r— toot ww« rtm moan	twmiohimiii tm n>m>wo>a
FA1OTMM*	fu l«mi« tAM	»*¦
393
A-4

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m i m chemists helping chemists in research & industry	T«i«Ph0ne: i«i*i 273-3850
V A V _ _ _ _	_				_	TWX: (910) 263-3052 Aldricham Ml
m aldrlch chemical co.	sss -
P.O. 8013S5. Ullwtuln*. WttceoHn 53X1 USA
MATERIAL SAFETY DATA SHEET	PAGE:
CATALOG #"1799 7-3	NAME: ACETONE» 99+3J
HAZAROOUS COMBUSTION OR DECOMPOSITION PROOUCTS
TOXIC FUMES OF:
CARBON MONOXIOE• CARBON DIOXIDE
	 SPILL OR LEAK PROCEDURES
STEPS TO *E TAKEN IF MATERIAL IS RELEASED OR SPILLED
SHUT OFF ALL SOURCES OF IGNITION.
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS. RUBBER BOOTS AND HEAVY
RU6BEK GLOVES.
COVER WITH AN ACTIVATED CARSON AOSCRBENT. TAKE UP ANO PLACE IN CLOSED
CONTAINERS. TRANSPORT OUTDOORS.
VENTILATE AREA AND WASH SPILL SITE AFT EA MATERIAL PICKUP IS COMPLETE.
WASTE OISPOSAL METHOO
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER ANO
SCRUBBER BUT EXERT EXTRA CARE IN UNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE.
OBSERVE ALL FEDERAL* STATE & LOCAL LAWS.
	 PRECAUTIONS TO BE TAKEN IN HANOLING AND STORAGE 	
CHEMICAL SAFETY GOGGLES.
MECHANICAL EXHAUST REdUIREO.
SAFETY SHOWER ANO EYE EATh.
COMPATIBLE CHEMICAL-KfSISTANT GLOVES.
NIOSH/MSHA—APPROVED RESPIRATOR.
FACESHI ELD (8-INCH MINIMUM).
00 NOT BREATHE VAPOR.
00 NOT GET IN EYES. UN SKINt ON CLOTHING.
AVOID PROLONGED UK REPEATED EXPOSURE.
WASH THOROUGHLY AFTbK HANDLING.
SEVERE EVE IRRITANT.
KEEP TIGHTLY CLJSEO.
KEEP AwAY FROM riSA T» SPARKS* ANO OPEN FLAME.
STORE IN A COOL DRY PLACE.
	A001TIONAL PRECAUTIONS ANO COMMENTS	
NOT APPLICABLE
THE ABOVE INFORMATION IS EELIEVEC TO BE CORRECT BUT DOES NOT PURPORT
TO 3E ALL INCLUSIVE ANO SHALL BE USED ONLY AS A GUIDE. ALORICH SHALL
NOT BE HELD LIASLE FOR A NT OA HA lie SeSt/LfriYG r*G.«t HANDLING u* P#0*
CONTACT WITH THE ABOVE PRODUCT. SE: REVERSE SI06 OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TERMS ANO CONJIUCNS OF SALE.
39*
A-5

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m « m chemists helping chemists in research & industry
U aldrlch chemical co.
P.O. Box MS, Ullwtuk—. WlieorUn 53101 USA
Telepnone: (41«) 273-3840
TWX: (910) 262-3052 Aldnehem Ml
Telex: 26 643 Aldrich Ml
FAX: (414) 273-4979
ATTN: SAFETY OIRECTOR
ENVIRESPONSE» INC
GSA RARITAN 06POT
WOOOBRI0GE AVE
EOISON
GARY SEIBEL
DATE: 09/19/88
CUST s 92^807 P.O. S
NJ 09837
MATEKIAL
SAFETY
OATA SHEET
PAGE:
CaLEOQ *,333,78
PMRSOJ 1*682*81
CELL Tc;iNSFORM.—MOUSE EMBRYO
IN VIT- ' CYTOGcNETICS-NONHJMAN;
	 IDENTIFICATION 	
PRODUCT # A3921-9 NAME: ANTHRACENE* 90-95%
CAS S 120-12-7
MF: C1*»H10
SYNONYMS
ANTHRACEN (GERMAN) « ANThKACIN • GRcEN OIL • PARANAPHTHALENE * TETRA
OLIVE N2G •
RTECS 9 CA9350000
ANTHRACENE
IRRITATION OATA
SKN-MUS 116 UG MLO
TOXICITY DATA
I PR—MUS L050:*30 XG/KG
REVIEWS* STANDAROS* ANO REGULATIONS
EPA GENETCX PROGRAM 1986. NEGATIVE: CELL TKANSFORM.-BALB/C—3T3, SHE-
CLONAL ASSAY
EPA GENETOX PROGRAM I96c, NEGATIVE:
EPA GENETCX PRGiiRA* l-?c6» NEGATIVE:
COL I POLA WITH S9
EPA GENETOX PROGRAM 198a, .NEGATIVE: HISTIDP.c REVERSION-AMES TEST; IN
VIVO SCE-NONHUWAN
EPA GENETCX PROGRAM I96e>» NEGATIVE: SPERM ^.RPHQLCGY-MOUSE; IN VITRO
. UOS—HUMAN FIBROBLAST
EPA GENETOX PROGRAM 19d!>» NEGATIVE.: IN VITRO UUS IN RAT LIVER* S
CEREVISIAE-hOMOZYGOSIi
EPA GENETOX PROGRAM 1986* INCONCLUSIVt: CARCINOGENICITY-MOUSE/RAT
EPA GENETOX PRoiiSAM 1956, INCONCLUSIVE: CELL TRANSFORM.-RLV F3*<> RAT
EMBRYO
EPA GENETOX PROGRAM 1986* INCONCLUSIVE: HOST-McOIATEC ASSAY;
MAMMALIAN MlCRGNUCLEUS
EPA GENETOX PROGRAM 1986* INCONCLUSIVE: E CGLI POLA WITHOUT S9; IN
VITRO SCfc—NCNHUMAN
EPA TS.CA ChE.MICA.1. IN.VE.N.TGRY«. 19&6
EPA TSCA TEST SUBMISSION (TSCATS) UA TA 3ASE, MARCH 1783
NIOSH ANALYTICAL METHOOS: ice POLYhUCLcAK AROMATIC HYDROCARBONS (HPLC)
, 5506; (GC). 5515
MEETS CRITERIA FCK PROPGScC OSHA McOICAL RECORDS RULE Fc*EAC V7.30V20.
82
TARGET ORGAN OATA
TUMOR IGENIC (EQUIVOCAL TUMGRIGEM C AGENT SY RTECS CRITERIA)
TUMORIGENIC (TUMORS AT SITE OF APPLICATION)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS)
DATA IS PRESENTED HERC. Set ACTUAL ENTRY IN r.lfcCS FOR COMPLETE INFOKMATII
HEALTH HAZARO OATA
ACUTE EFFECTS
MAY BE HARMFUL bY INHAlA TI Q.N, INGESTION, OR SKIN ABSORPTION.
CAUSES EYE ANO SKIN IKkITaT I Of..
MATERIAL IS IRRITATING TO lUCCUS KcrtiiRANES ANJ UPPER
'AJfOtlM**
>u iMjrtim
».0. e- <««, nil
iM 'mi *"7M«v«*>0
M«C« CO
'mm tonm
>«*«» —»0
»** ion»i«r-»
*19
A-6

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m . m chemists helping chemists in research & industry	T»)epnon«: nm 273-M50
W M m a m m M_		m	m	TWX: (910) 262-3052 Aldrichem Ml
m aldrich chemical co.	saws*-
P.O. Bo13SS. UVMiftM, WIKontln 53201 USA
M A T £ RIAL SAFETY OATA SHEET	PAGE
CATALOG * A8921-9	NAME: ANTHRACENE. 90-95*
RESPIRATORY TRACT.
TC THE bEST OF OUR KNOWLEDGE, THE CHEMICAL. PHYSICAL. ANO
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
FIRST A10
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FCR AT LEAST 15 MINUTES.
IN CASE OF CONTACT. IMMEDIATELY WASH SKIN nITrt SOAP ANU COPIOUS
AMOUNTS OF WATER.
IF INHALEO. REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF 6REATHING IS DIFFICULT. GIVE OXYGEN.
CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING bfcFORE REUSE.
•PHYSICAL DATA
MELTING POINT: 212 C TO 2l<» C
BOILING POINT: 3<,0 C
VAPOR OENSITY: 6.15
VAPOR PRESSURE: 1.0 MM a) 1*5 C
FIRE AND EXPLOSION rIAZARO DATA	
AUTO IGNITION TEMP.: 100<» F
LOWER EXPLOSION LEVEL: .61
EXTINGUISHING MEDIA
WATER SPRAY.
CARSON DIOXIDE. DRY CHEMICAL POwOER, ALCOHOL UR POLYMER FOAM.
SPECIAL FIRE FIGHTING PROCEDURES
WEAR SELF-CONTAINfcO BR E A THIN5 APPARATUS Af.j PkUTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN ANO EYES.
UNUSUAL FIRE AND EXPLOSION FAZAROS
EMITS TOXIC FUMES UNDER r IRE CONDITIONS.
REACTIVITY DATA
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS C0M3USTI0N OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SPILL OR LEAK PROCEDURES
STEPS TO it TAK.EM l.F	RELEASE. OA iP I LL.EQ.
WEAR RESPIRATOR. CHEMICAL SAFETY GOGGLEj, RUSHER BOOTS ANO HfcAW
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG ANO HOLD FOR WASTE DISPOSAL.
AVOIO RAISING OUST.
VENTILATE AREA ANO WASH SPILL SITE AFTER MATEhIAL PICKUP IS COMPLETE.
WASTE DISPOSAL METHOO
OISSOLVE OR MIX THE MATERIAL WITH A COMBUST IBL E SOLVENT ANO BURN IN A
CHEMICAL INCINERATOR EQUIPPED wITh AS AFTERBURNER AND SCRUB3ER.
OBSERVE ALL FEDERAL, STATE i LOCAL LAwS.
	 PRECAUTIONS TO 3c TAKEN IN HANDLING AND STORAGE 	
CHEMICAL SAFETY GGG-iLc?".
CCMPATI6LE CHEMICAL-KfSISTANT GLOVES.
NIOSH/MSriA-APPROVED RESPIRATOR.
SAFETY SHOWER ANO EYE bATh.
MECHANICAL EXHAUST REQUIRED.
00 NOT 3REATHE DUST.
'U AIMM
AiOX*	CM
0<	»
Oenm Vtu.
'h»im •ourt.an
tm» «"n> tifcwo
»*« io:*r«> wt
<,20

A-18
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% chemises helping chemists in research & industry Telephoned4)273-3850
TWX: (910) 262-3052 Aldrichem Ml
j i ^ cnemists neiping cnemibts in researcn o inauswry
U aldrlch chemical co.
P.O. Box JS& M//wau«M. W/*C0A(M S3X1 USA
Tel ex: 26 843 Aldricn Ml
FAX: (414) 273-4979
MATERIAL SAFETY OATA SHEET PAGE:
CATALOG #~23925-9 NAME: CHROMIUM<1117 NITRATE~NONAHYORATE. 99%
SPECIAL FIRE FIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS ANO PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN ANO EYES.
STRONG OXIDIZER*
UNUSUAL FIRE ANO EXPLOSION HAZARDS
EMITS TCXIC FUMES UNOER FIRE CONDITIONS.
CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
CONTAINER EXPLOSION MAY OCCUR UNOER FIRE CONOITIONS.
MAY BE SHOCK-SENSITIVE.
REACTIVITY DATA
INCOMPATIBILITIES
HEAT
ORGANIC MATERIALS
REOUCING AGENTS
MAY EXPLODE WHEN HEATED.
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
NITROGEN OXIDES
SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
WEAR RESPIRATOR* CHEMICAL SAFETY GOGGLES. RUBBER BOOTS ANO HEAVY
RUBBER GLOVES.
SWEEP UP* PLACE IN A BAG ANO HOLO FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA ANO -ASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
wa$TtheImaterialEshould be oissolved in i) wat:-; 2) acio solution or 3)
OXIDIZED TO A WATEK-SOLUiJLE STATE. PRECIPITATE THE MATERIAL AS THE
SULFIDE. ADJUSTING ThE MH CF THE SOLUTION 7 TO COMPLETE PRE-
CIPITATION. FILTER THE INS0LU3LES ANO OISPUJc OF THEM IN A HAZAROOUS-
MASTE SITE. DESTROY ANY EXCESS SULFIDE *IT- SCDIJM HYPOCHLORITE.
NEUTRALIZE THE SOLUTION BEFORE FLUSHING DOWJs THE DRAIN.
OBSERVE ALL FEJERAL. STATE C LOCAL LAWS.
PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORAGE
CHEMICAL SAFETY GOGGLES.
COMPATIBLE CHEMICAL-RESISTANT GLOVES. „ „ =oo
NIOSH/MSHA-APPROVED RESPIRATOR IN NONVENTILLATEO AREAS AND/OR FOR
EXPO-SUB-E A.&O.V.E. THE. ACilH TLV-
SAFETY SHOWER ANO EYE 6ATH.
USE ONLY IN A CHEMICAL FUME HOOD.
DO NOT BREATHE OUST.
00 NOT GET IN EYES. ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
HARMFUL OUST•
DO NOT ST0RE*N6AR, NOR ALLOW CONTACT WITH, CLOTHING ANO OTHER
KEEPUAWAYLFR0MTC0M3USTIQLE MATERIALS. HEAT. SPARKS. AND OPEN FLAME.
STORE IN A COOL ORY PLACE.
ADDITIONAL PRECAUTIONS ANO COMMENTS
ADDITIONAL INFORMATION
USE POLYETHYLENE TOCLS.
ewlawwic*
«N*aM l^lWIaMa
c.n*«y tfl «* rmwrnm mriM
fi H»a»i lO'txmti Twm rMMMiO
»f«i«•<<«• 'MifmuMit »** ««»•»•»
wMMan »Aj«inijtj >u aiaM>u »** •«»«'•» im»
<~05
A-19
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0 . ^ chemists helping chemists in research & industry
U aldrich chemical co.
P.O. Bom 353. Ullwuk—. WiteonUn S3201 USA
Telephone: (414) 271-3850
TWX: (910) 282-3052 Aldriehem Ml
Telex: 26 S43 Aidrien Ml
FAX: (414) 273-4979
MATER
CATALOG «~2392S-9~
I A L SAFETY OATA SHEET PAGE:
NAME: CHROMIUM(III) NITRATE NONAHYDRATE. 99%
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT GOES NOT PURPORT
TO BE ALL INCLUSIVE ANO SHALL BE USEO ONLY AS A GUIOE. ALOKICH SHALL
NOT BE HELD LIABLE FOP. ANY OAMAGE RESULTING FROM HANDLING OR FROM
CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TERMS ANO CONDITIONS OF SALE.
V06
A-20
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©chemists helping chemists in research & industry
aldrich chemical co.
P.O. Boi 355. HUmtukm. Wlteon$ln 53101 USA
T«lepnon»: |«14) 273-MSO
TWX: (910) 262*3052 Aldrichem Ml
Tel««: 2« 343 Aldricn Ml
FAX: («1«) 275-4979
ATTN: SAFETY OIRECTOR
ENVI RE SPONSE » INC
GSA RARI TAN DEPOT
W000BRIOGE AVE
EDISON
GARY SEIBEL
CUST • 924807
NJ 08337
DATE:
P.O.
09/19/88
MATER I A L
SAFETY
0 A T A SHEET
PAGE:
IDENTIFICATION
PRODUCT u 20920-1 NAME: COPPER(II) SULFATE PENTAHYORATE, 98*
CAS * 7756-99-8
MF: CU04S
SYNONYMS
SLUE COPPER AS • BLUESTGNE • oLUE VITRIOL • COPPERFINE-ZINC • COPPER
SULFATE • CO PP6R(I I) SULFATE PENTAHYJkATE « C0PPER(2*) SULFATE
PENT AHYORA T E • COPPfc* SULPHATE • CSP • CUPRIC SULFATE PENTAHYORATE •
KUPFERSULFA T (GERMAN) « KUPrEk3ULFAT-PENTAHYORAT (GERMAN) •
KUPFERVITRIOL (GERMAN) « ROMAN VITRIOL • SALZBURG VITRIOL • SULFURIC
ACID, COPPER(2*) SALT, PENTAHYORATE • SJLFURIC ACIO COPPERUO SALT
(1:I)• PENTAHYORATE (dCI,9CI) • TRIANGLE •
TOXICITY HAZARDS
IPRAA8 18,807,65
85DCAI 2,73,70
8 5 ARAE 2,182,77
BCPCA6 14,289,65
FMCHA2 - ,C62,83
JANSAG 55,337,82
RTECS * GL8900000
COPPER (II) SULFATE PENTAHYORATE (1:1:5)
TOXICITY DATA
ORL-HMN LOLO: 106o MG/KG
UNR-MAN LOLO:221 »u/Ku
ORL-RAT LD50:300 MG/KG
I PR—MUS L050:3 3 MG/KG
ORL-MAM L050:470 MG/KG
I PR-MAM LU50 : 7500 UG/KG
REVIEWS, STANOARDS, AN0 REGULATIONS
ACGIH TLV-TwA 1 MG(CU)/*3 85INA8 5,146,86
MP CARC INUGENESIS S TUG I tS ; L AttOR A TORY ASSIG.-trO, JANUARY 1988
MEETS CRITERIA FOR PROPOiEG OSHA MEuICAL RECORDS RULE FEREAC *7,30420,
82
TARGET ORGAN DATA
BEHAVIORAL (SOMNOLENCE)
GASTROINTESTINAL (CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANOS)
GASTROINTESTINAL (NAUSEA OR VOMITING)
LIVER (JAUNDICE, HEPATOCELLULAR)
KIDNEY, URETER, BLADOER (OTHER CHANGES)
BLOaQ CiiTHER HEMQL.YS.LS WITH OR *IThOUT ANEMIA)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CnE.IICAL SU6STANCES (RTECS)
DATA IS PRESENTED HERE. SEE ACTUAL cNTKY IN RTECS FOR COMPLETE INFORMAT11
HEALTH HAZARO OATA
ACUTE EFFECTS
HARMFUL IF INHALED OR SHALLOWED.
CAUSES SKIN IRRITATION.
CAUSES SEVERE EYE IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MtMiRANES A'¦«* Co in
r"*0"o *
Om «y»w Do*** «.
^ ^ MM Tii—om
'uifllMII »u Miiifl 'ai tBi n*our ««< .gr«rt,jrf«
395
A-21
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m i m chemists helping chemists in research & industry T^iepnon* («>«) zrs-ieso
V A « _ _ . _ _ _ _ VHX. (910) 262-3052 Alonchom Ml
m aldrich chemical co.
P.O. Bet 345. UllmtuKM, Wltconttn 53201 USA
T«l«»: 26 643 Aldrich Ml
FAX: (414) 273-4979
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG 9 20920-1 NAME: COPPER(II) SULFATE PENT AH YLiR A T E , 98%
IN CASE OF CONTACT» IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
IF INHALED. RcMOVE TO FRESH AIR. IF NOT BKcATnlNG GIVE ARTIFICIAL
RESPIRATION. IF QR t A Th I Ni» IS DIFFICULT, GIVE OXYGEN.
CALL A PnYSIClAN.
REMOVE ANO HASH CONTAMINATED CLOTHING PROMPTLY.
PHYSICAL DATA
NO PHYSICAL OATA AVAILABLE
FIRE ANO EXPLOSION HAZARD DATA
EXTINGUISHING MEDIA
NONCOMbUSTIBLE.
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNOIN« FIRE CONDITIONS.
SPECIAL FIRE FIGHTING PROCEGUPcS
WEAR SELF-CONTAINED ftR £A THI * n*oi«i '•»» ~"»»«*c»o
•U IOMOB4 >U iKItim lfl8» NMltl •*« >»f«
396
A-22
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m « m chemists helping chemists in research & industry
U aldrlch chemical co.
P.O. Boi JSS. UllwuKm. Wlteontln S3X1 USA
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG 9 20920-1 NAME: COPPER(II) SULFATt PENTAHYDrtA TE » 98X
TOXIC*
SEVERE EYE IRRITANT.
KEEP TIGHTLY CLOSED.
EFFLORESCENT.
PROTECT FROM AIR
AOOITIONAL PRECAUTIONS ANO COMMENTS
NOT APPLICABLE
THE ABOVE INFORMATION IS BELIEVED TO PE CORRECT BUT DOES NOT PURPORT
TO BE ALL INCLUSIVE ANO SHALL bE USEO JNLY AS A GUIOE. ALOKICH SHALL .
NOT BE HELD LIABLE FOR ANY CAMAl»E RESULTING FROM HANDLING OR FROM
CONTACT WITH THE ABOVE PRGDUCT. SEE KEVfcRSe SIDE OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TERMS ANu CONDITIONS OF SALE.
Telephone (414) 273-38S0
TWX: (910) 262-3052 Aldrichem Ml
Tele*: 26 843 Aldrich Ml
FAX: (414) 273-4979
Mx^ClMaCt IN
*»• Oa ftxi've >mbIm
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chemists helping chemists in research & industry Tei«pnon«. (4i«) 2?3-j#so
a g ¦ TWX: (910) 262-3052 Aldncfwn Ml
aldrich chemical co.
*"• P.O. Box 333. Ulhnutm. Wlieoniln 33101 USA
-ATTN: SAFETY DIRECTOR
ENV IRE SPONSEt INC
6SA RARITAN OEPOT
W000BRIOGE AVE
EOI SON
GARY SEIBEL
DATt: 09/19/83
CUST * 92*807 P.O. *
NJ 08837
.MATERIAL
SAFETY
DATA SHEET
PAGE:
IDENTIFICATION
PROOUCT « 06156-3 NAME: It2-0ICHLOROETHANE» 99X
CAS * 10 7-06-2
MP: C2H*CL2
SYNONYMS
AETHYLENCHLORIO (GERMAN) • 1»2-61CHLOROETHANE • 3ICHLORURE METHYLENE
(FRENCH) • BORER SOL • ?RliCIDE • CHLORURE D'ETHYLENE (FRENCH) •
CLORURO 01 ETHENE (ITALIAN) « 1,2-OCE • 0E3TRUX0L BORER-SOL ~ U2-
OICHLOORETHAAN (OUTCH) « 1,2-OICHLOR-AETHAN (GERMAN) •
01CHLOREMULS ION * 112-'J ICHLGkETHANE • 01-CHLOK-MULS ION • DICHLORO-1,2-
ETHANE (FRENCH) • ALPHA,oETA-CICHLOROETHANE • SYM-0ICHLOROETHANE » 1,
2-OICHLOROETHANE • CICHLGRuETHYLENE • I.2-01CLOROETANO (ITALIAN) •
DUTCH LIOUIO • DUTCH OIL « EOC • ENT 1,656 • ETHANE OICHLORIDE •
ETHYLEENOICHLORIOE (DUTCH) • ETHYLENE CHLORIDE • ETHYLENE OICHLORIDE •
ETHYLENE OICHLORIDE (ACGIH,DOT) • 1,2-ETHYLENE OICHLORIDE * GLYCOL
DICHLORIOE • NCI-C00511 • RCRA WASTE NUMBER U077 • UN 118* (OOT) •
TOXICITY HAZARDS
RTECS « K105 25000
ETHANE, 1,2-0ICHLCRC-
IRRITATICN OATA
SKN-RBT 625 MG CPEN MLO
SKN-RBT 500 MG/2*H MLu
6YE-RBT 63 MG SEV
.EYE-RBT 500 MG/2*H MLD
TOXICITY OATA
ORL-HMN LDLO:286 MG/KG
ORL-MAN LOLO: 71* MG/KG
ORL-RAT LD50:670 MG/KG
IHL-RAT LC 50:1000 PPM/7H
IPR-RAT LD50:o07 MG/KG
SCU-RAT LU50:1 GM/KG
ORL-MUS L050:*09 MG/KG
I PR—MUS LD50:*70 MG/KG
ORL.-QaG LQ5Q^i70a MG/KG.
IHL-MKY LC50:3000 PPM/7H
ORL-RBT LD50:860 MG/KG
SKN-RBT L050:2800 MG/KG
REVIEWS, STANOARDS, AND REGUL
ACGIH TLV-TWA 10 PPM 35IN
MSHA STANOARD-AIR: Tw A 50
OSHA STANDARD-AIR:TWA 50
235*0,7*
NIQSH REL TO ETHYLENE CIC
3*(IS),loS,85
EPA GENETOX PROGRAM 1996,
TRANSFORM.-SA7/SHE
EPA GENETOX PROGRAM I9d6,
LOSS
EPA GENETOX PROGRAM
COLI POLA WITHOUT SV
EPA GENETCX PROGRAM 19e6,
EPA GENETOX PROGRAM 19SS,
EPA TSCA CHEMICAL IN V t N T
UCDS»« 3/23/70
85JCAE -,93,86
UCOS«* 3/23/70
85JCAE -,93,86
CLCEAL
KLWOAZ
FMCHA2
AMIHBC
STPZAtJ
FAO.NAU
T0XID9
ARZNAO
FAuNAU
d5JCAE
GUCHAZ
FAONAU
86,203,*7
*8,822 * 70
-»C99» 83
*,*82,51
26(*),26,82
*8A,91,70
I,26,81
II,902,61
*8A» 9 L,70
-,93,86
6,26*,73
*8 A , 91 , 70
A TIONS
Ao 5,252,86
PPM (200 MG/M3) OTLVS• 3,79,71
PPMJCL 100 PP.M;PK 200 PPM/5M/3H FEREAC 39,
HLORIDE-AIRtTWA 1 PPMJCL 2 PPM/15M MMWR»*
POSITIVE: carcinogfnicity-mouse/rat; CELL
POSITIVE: 0 MELAN0GASTER-WHOLE SfcX CHROrt.
P'jilTlVE: 0 MELAf;uGAST = R-NONOISJUNCTI3N; E
fCSITIvfc: MISTIOlNc PEVERSION-AMES TEST
roSITIVt: - MrLANOGASTcR SEX-LINKcO LETHAL
Y, HJo
*22
A-24
-------
chemists helping chemists in research & industry Tetepnon#:(4i*>273-3M0
rn —¦ 9 _ m m a m TWX: (910) 262-3052 Aldrichem Ml

aldrich chemical co.
Telex: 26 B43 Alarien Ml
FAX: («1«) 273-4979
* P.O. Bet 355 WltnuHm. Wtcontln S3X1 USA
MATERIAL SAFETY DATA SHEET PAGE: I
CATALOG » 06156-3 NAME: I,2-0ICHLOROETHANE, 99*
EPA TSCA SECTION 8(E) STATUS REPORT 3EH0-O979-O31O;8EH0-0778-O228
EPA TSCA TEST SUBMISSION (TSCATS) OATA BASE* MARCH 1988
NIOSH CURRENT INTELLIGENCE BULLETIN 25, 1978, ANO BULLETIN 27, 1978
NIOSH ANALYTICAL METHODS: SEE HYDROCARBONS, HALOGENATED, 1003
NCI CARCINOGENESIS BIOASSAY (GAVAGE)JCLEAR EV IOENCE:MOUSE,RAT NCITR«
NCI—TR-55.78
NTP FOURTH ANNUAL REPORT ON CARCINOGENS, 198*
NTP CARCINOGENESIS STUUIcS;ON TEST (PKECHRONIC STUDIES), JANUARY 1988
MEETS CRITERIA FOR PR0P0S60 OSHA MEDICAL RECORDS RULE FEREAC *7,30*20,
82
TARGET ORGAN OATA
SENSE ORGANS ANO SPECIAL SENSES
-------
chemists helping chemists in research & industry r.twon* <41*1 in-iaao
aldrich chemical co. —
P.O. Bci 355. WlmuMm. Wttcontin 53201 USA
26 0*3 AldriCh Ml
FAX: (414) 273-4079
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG « D6156-3 NAHE: I,2-0ICHL0R0ETHANEi 99*
•PHYSICAL OATA
MELTING POINT: -35 C
BOILING POINT: 81 C TO 35 C
SPECIFIC GRAVITY: 1,256
VAPOR 06NSITY: J.v
VAPOR PRESSURE : U7.0 MM A 25 C
FIRE AND EXPLOSION HAZARO OATA —
AUTO IGNITION TEMP.: 775 F
LOWER EXPLOSION LEVEL: 6.23!
UPPER EXPLOSION LEVEL: 15.64
FLASH POINT: 60 F
EXTINGUISHING MEDIA
Carbon oioxioe* dry chemical powder, alcohol or polymer foam.
WATER MAY BE EFFECTIVE FUR CGCLING, bUT MAY NOT EFFECT EXTINGUISHMENT.
SPECIAL FIRE FIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS ANO PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN ANO EYES.
UNUSUAL FIRE AND EXPLOSION riA ZAROS
FLAMMABLE LICUIO.
VAPOR KAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION ANO
FLASH BACK.
EMITS TOXIC FUMES UNDER FIRE CONOITIONS.
REACTIVITY DATA
INCOMPATIBILITIES
OXIDIZING AGENTS
ALUMINUM
HAZARDOUS COMbUSTION OR DfcCOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARSON MQNOXIDE« CARBCN DIOXIDE
HYOROGEN CHLORIDE GAS
PHOSGENE GAS
SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASEO OR SPILLED
EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
WEAR SELF—C0.NTAlN.6D aREATHING APPARATUS* RUbafcR bOCTS ANO HEAVY
RUBBER GLOVES.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
WASTE 01SPOSAL METHOD
BURN IN A CHEMICAL INCINERATOR EUUIPPED »ITH AN AFTERBURNER ANU
SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE.
OBSERVE ALL FEDERAL. STATE d LOCAL LAxS.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
WEAR APPROPRIATE MCSH/*SHA-APPRGVEO RESPIRATOR, CHEMICAL-AfcSISTANT
GLOVES• SAFETY TOGGLES. CThEK PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE bATH.
00 NOT tREATHE VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
, .CMN.n"
-
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-------
m i m chemists helping chemists in research & industry
U aldrlch chemical co.
P.O. Bex JSA UUmtukm. Wlteontln 5J207 USA
MATER I A L SAFETY OATA SHEET PAGE: <,
CATALOG #"06156-3 NAME: 1»2-DICHL0R0ETHANE» 99*
AVOIO PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANOLlNG.
IRRITANT.
CARCINOGEN.
MUTAGEN.
HARMFUL LIQUID.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM hEAT, SPARKS. ANO OPEN FLAME.
STORE UNDER NITROGEN*
STORE IN A COOL DRY PLACE.
— AOOITIONAL PRECAUTIONS ANO COMMENTS —
NOT APPLICABLE
THE AaOVE INFORMATION IS BELIEVED TO BE CORRECT BUT OOES NOT PURPORT
TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIOE. ALDRICH SHALL
NOT BE HELD LIABLE FOR ANY JAMAGE RESULTING FROM HANOLlNG OR FROM
CONTACT WITH THE ABOVE PRODUCT. SEE RtVEHSE SIDE OF INVOICE OR PACKING
SLIP FCR ADDITIONAL TERMS ANO CONDITIONS OF SALE.
Telephone: (414) 273-3890
TWX: (910) 262*3052 Aldnenem Ml
Tetex: 20 843 Aidrten Ml
FAX: (414) 273-4979
'U (01) MM tt
lOJitt»»«
iain»4iM 4
-------
©chemists helping chemists in research & industry
aldrich chemical co.
P.O. Bom JSi. UIImiiIm, WlteonUn S3101 USA
Tslephont: (414) 273-3450
TWX: (910) 202-3052 Aldricnam Ml
Talen: 26 843 Aldrich Ml
FAX: (414) 273-4979
ATTN: SAFETY 0IR6CT0R
ENVIRE SPONSE » INC
GS A RARI TAN OEPOT
W000BRIDGE AVE
E0IS0N NJ
GARY SEIBEL
OATE: 09/19/88
CUST * 924807 P.O. *
08837
MATERIAL
SAFETY
DATA
SHEET
PAGE:
IDENTIFICATION
NAME: ETHYLBENZENE, 99%
AIHAAP 23,95, 62
AJOPAA 29,1363•46
AMIHA8 14,307*56
ARTODN 58*106*85
FCTXAV 13.803,75
PROOUCT s El250—8
CAS * 100-41-4
MF: CdHlO
SYNONYMS
AETHYLBENZOL (GERMAN) • 68 • fcTHYLBENZcfcN (OUTCH) • ETHYL BENZENE *
ETHYL BENZENE (ACGIH.OCT) • ETHYLBENZCL • ETILBENZENE (ITALIAN) •
ETYLOBENZEN (POLISH) • NCI-C56393 • PHENYLETHANE ~ UN 1175 (DOT) •
TUXICITY HAZARDS
RTECS # DA0700000
BENZENE. ETHYL-
IRRITATION DATA
SKN-RBT 15 MG/24H OPEN MLO
EYE-RBT 100 MG
TOXICITY OATA
ORL-RAT LD50:3500 MG/KG
I PR—MUS L050J2272 MG/KG
SKN-RBT LD50:17800 MG/KG
REVIEWS. STANDARDS, AND REGULATIONS
ACGIH TLV-TWA 100 PPMJ STEL 125 PPM 85INA8 3,244*86
MSHA STANOARD-AIR: T'„A 100 PPM (<,35 MG/M3) LTLVS» 3*104*71
OSHA STANOARD-AIR:T*A 100 PPM (SKIN) FEREAC 39*23540*74
EPA GENETOX PROGRAM I9fa6. NEGATIVE: CELL TRANSFORM.-SA7/SH6
EPA TSCA CHEMICAL INVENTORY, 1986
EPA TSCA 8(A) PRELIMINARY ASSESSMENT INFORMATION, FINAL RULE FEREAC
47,26992,82
BP A TSCA SECTION 8(E) STATUS REPORT 8EH9-0680-0345;8EH3-1080-0368
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, MARCH 1988
NIOSH ANALYTICAL METHODS: SEE HYDROCARBONS, AROMATIC. 1501
NTP CARCINOGENESIS STUD IES5LABOKATORY ASSIGNED, JANUARY 1988
MEETS CRITERIA Fu« PrtOPOSEO CSHA MEDICAL RECOKOS RULE FEREAC 47,30420,
82
TARGET ORGAN DATA
SENSE ORGANS. AMI SPECIAL SENSES. COThER EYE EFFECTS)
BEHAVIORAL (SLEEP)
LUNGS* THORAX OR RESPIRATION (OTHER CHANGES)
EFFECTS ON FERTILITY (FEMALE FERTILITY INDEX)
EFFECTS ON FERTILITY (LITTER SIZE)
EFFECTS ON FERTILITY (ABORTION)
EFFECTS ON EMBRYO OK FETUS (FETOTOXICITY)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (MUSCULOSKELETAL SYSTEM)
ONLY SELECTED REGISTRY CF TOXIC EFFECTS CF CHEMICAL SUBSTANCES (RTECS)
DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATI
HEALTH HAZARD OATA
ACUTE EFFECTS
MAY BE HARMFUL iiY INHALATION, INGESTION, OR SKIN ABSORPTION.
CAUSES SKIN IKKITATION.
VAPOR OR MIST IS IRKlTATINi, TO THE EY = S» MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.

'•1 07010 Oi.aii I.. T«m
Thwi»»i i«i tm
»u lOHMili «u iQMrtiirr*
429
A-28
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^ i % chemists helping chemists in research & industry Telephone. <*i«> 273-mso
¦ 9 ¦ TWX: (910) 262-3052 Aldriehem Ml

aldrlch chemical co.
Telex: 26 843 Aldncn Ml
FAX: (414) 273-4979
• P.O. Bom 356, UUmtultm. W/«cwi*M 33X1 USA
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG •"II250-8 NAmI: ETHYlIInZENE* 99*
CAN CAUSE CNS DEPRESSION.
EXPOSURE CAN CAUSE:
NAUSEA. HEADACHE ANO VOMITING
FIRST A10
IN CASE OF CONTACT. IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
IF INHALED* REMOVE TO FRESH AIR.
CALL A PHYSICIAN.
WASH CGNTAMINATEO CLOTHING BEFORE REUSE.
MELTING POINT: -95 C
BOILING POINT: 136 C
SPECIFIC GRAVITY: 0.867
VAPCR DENSITY: 3.7
VAPOR PRESSURE: 10.0 MM < 20 C
FIRE ANO EXPLOSION HAZARD DATA
AUTO IGNITION TEMP.: 810 F
LCWER EXPLOSION LEVEL: IX
UPPER EXPLOSION LEVEL: o.7X
FLASH POINT: 72 F
EXTINGUISHING MEDIA
CARBON DIOXIDE. DRY CHEMICAL POWOER. ALCOHOL OR POLYMER FOAM.
WATER MAY BE EFFECTIVE FOR COOLING. BUT MAY NOT EFFECT EXTINGUISHMENT.
SPECIAL FIRE FIGHTING PROCEDURES
WEAR S EL F—CONT AINEO BREATHING APPARATUS AN_ PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
WARNING!
FLAMMABLE LIQUID.
UNUSUAL FIRE ANO EXPLOSION HAZARDS
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION ANO
FLASH BACK.
CONTAINER EXPLOSION MAY OCCUR UNOER FIRE CONDITIONS.
REACTIVITY OATA
INCOMPATIBILITIES
OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION FROOUCTS
rcrxrc fumes of-.
CARBON MONOXIOE. CARBON OIOXIDE
SPILL OR LiAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
WEAR SELF-CONTAINED BREATHING APPARATUS. RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
USE NONSPARKING TOOLS.
COVER WITH AN ACTIVATED CARBON AOSORUENT. TAKt UP ANO PLACE IN CLOSED
CONTAINERS. TRANSPORT GUTOCCRS.
VENTILATE AREA ANC pASh SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
fiaiiuM i mmwi Tmrnmmtarmtv+
TNNMiWMm ««pni«S)M Qua—«»- r«i>Ma*aiO
rMan«Mt 'u cm*tt-»
'umwi4 'u Miua «*« (OBtaMttr »*« to*4rti
*30
A-29
-------
m . m chemists helping chemises in research & industry
U aldrlch chemical co.
P.O. Sot 394. MUwukm. Wlieontlit 31301 USA
TtMpnonc (*i*l 273-3650
TWX: (910) 262-3092 Alflricnam Ml
Talsx: 24 843 Aldricn Ml
FAX: (414) 273-4979
MATER
CATALOG # E1250-8
A L SAFETY DATA
NAME: ETHYLBENZENE* 99*
SHEET
PAGE:
WASTE OISPOSAL METHOD
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER ANl)
SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE*
OBSERVE ALL FEDERAL. STATE i. LOCAL LAWS.
PRECAUTIONS TO BE TAKEN IN HANOLING AND STORAGE
CHEMICAL SAFETY GOGGLES.
SAFETY SHOWER ANO EYE BATH.
RUBBER GLOVES.
NIOSH/MSHA-APPROVED RESPIRATOR.
MECHANICAL EXHAUST REQUIRED.
DO NOT GET IN EYES• ON SKIN. ON CLOTHING.
00 NCT BREATHE VAPOR.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT, SPARKS. AND OPEN FLAME.
STORE IN A COOL ORY PLACE.
ADDITIONAL PRECAUTIONS ANO COMMENTS
NOT APPLICABLE
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT oUT OOES NOT PURPORT
TO BE ALL INCLUSIVE ANO SHALL BE USED ONLY AS A GUIDE. ALORICH SHALL
NOT BE HELD LlAtiLS FOR ANY DAMAGE RESULT l\ .• FROM HANOLING OR FROM
CONTACT WITH THE ABOVE PROOUCT. SEE REVEfiSc SIDE OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TERXS AND CONDITIONS Cf- SALE.
'U
*31
A-30
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0 . ^ chemists helping chemists in research & industry
U aldrlch chemical co.
P.O. Bet 355, UUmtukm. Wlteontln 33301 USA
Tckphonr. (414) 273-3850
TWX: (910) 262-3052 Aldrichem Ml
T««: 26 843 Aldrich Ml
FAX: (414) 273-4079
ATTN: SAFETY DIRECTOR
ENVI RESPONSEjr INC "
GSA RARITAN DEPOT
WOODBRIDGE AVE
60 I SON NJ
GARY SEIBEL
OATE: 09/19/88
CUST ft 92<»807 P.O. *
08837
MATERIAL SAFETY DATA S H E e T
PAGE:
IDENTIFICATION
PRODUCT tf 27672-3 NAME: HEXACHLQROBENZENE* TECH.. 75X
CAS 9 118-7V-1
MF: C6CL6
SYNONYMS
AMATIN • ANTICARIE • BUNT—CUKE • BUNT-NO—MORE • CO-OP HEXA •
ESACL0R0B6NZENE (ITALIAN) • GRANGX NM • HC3 • HEXA C.B. •
HEXACHLORBeNZOL (GERMAN) • rifcXACHLORObENZENE • H6XACHL0R08ENZENE (OOT)
• JUL IN • S CARBON CHLORIOE » NU BUNT • NO BUNT <>0 • NO BUNT 80 • NO
BUNT LIwUID * PfcNTACHLGRUPhENYL CHLORIDE • PERCHLOROBENZENE • PHENYL
P6RCHL0RYL • SANOCIDE • SMUT-GO » RCRA WASTE NUMBER U127 •
SAATBEIZFUNGIZID (GERMAN) • SANOCID • 5NIECI0T0X • UN 2729 (DOT) •
TOXICITY HAZARDS
650CAI 2,73,70
85GMAT -, 72 »82
85GMAT -,72.82
85GMAT -.72,82
85GMAT -.72.82
85SMAT -.72.82
85GMAT -.72,82
85GMAT -,72,82
NTIS«« P(3288—^16
PTECS * 0A2975000
BENZENE, HEXACHLORO-
TOXICITY DATA
UNR-MAN LOLO : 220 MG/*G
IHL-RAT LC50:3600 M«/M3
ORL-MUS L050S4 Gf/KG
IHL-MUS LC 50: <~ GM/M3
CRL-CAT LD50:1700 KG/KG
IHL-CAT LC 50: 1600 MG/M3
ORL-RBT LD5C:2bG0 MG/KG
IHL-RBT LC50: 1800 MG/M3
ORL-MAM LD50 :10<»7 MG/*.G
REVIEWS, STANDARDS, A\U kEGULATIONS
EPA GENETOX PROGRAM 1966, POSITIVE: CARC INOGENICITY-MOUSE/RAT
EPA GENETOX PROGRAM 1986, NEGATIVE: RODENT DOMINANT LETHAL
EPA TSCA CHEMICAL INVENTORY, 1986
EPA TSCA TEST SUBMISSION (TSCATS) OATA BASE, MAkCH 1988
NTP FOURTH ANNUAL REPORT ON CARCINOGENS, 198V
MEETS CRITERIA FCR PROPOSED OSHA MEDICAL RECORDS RULE FEREAC <»7,30^20,
82
TARGET ORGMi. QAXJt
BEHAVIORAL (SOMNOLENCE)
LIVER (TUMORS)
ENOOCRINE (THYROID TUMORS)
SPECIFIC DEVELOPMENTAL ABNORMALITIES (CRANIOFACIAL)
SPECIFIC DEVELOPMENTAL A3N0RMALIT16S (MUSCULOSKELETAL SYSTEM)
SPECIFIC DEVELOPMENTAL AoNORMALITIES (UROGENITAL SYSTEM)
EFFECTS ON NEWBORN (LIVE BIRTH INOtX)
EFFECTS ON NEWBORN (VIABILITY INDEX)
EFFECTS ON NEWBORN (WEANING OR LACTATION INDEX)
EFFECTS UN NEWBORN (GPdWTH STATISTICS)
EFFECTS GN NEwBORN OIOChEmICAL ANO METABOLIC)
TU*ORIGENIC (CARCINOGENIC BY RTECS CRITERIA)
TUMORIGENIC (NEOPLASTIC BY RTECS CRITERIA)
EIOCHEMICAL EFFECTS (PurPHYnlN INCLUDING BILE PIGMENTS)
ONLY SELfcCTEC REGISTRY f.F TOXIC EFFECTS UF CHEMICAL SUBSTANCES (RTfcC S)
DATA IS PRESENTED r>ERE. oEt ACTUAL cNTRY IN RTECS FOR COMPLETE INFQRMATIC
<~13
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g i m chemists helping chemists in research & industry T«t«phon« (*i*>2T3-jmo
A V m m m ¦_ m 9 m TWX: (910) 292-30S2 Aldnchem Ml

aldrlcti chemical co.
Tel#*: 28 843 Aldricn Ml
FAX: (414) 273-4979
• P.O. Be* 396. KIMUtM WlteontM 53301 USA
M A T E RIAL SAFETY OATA SHEET PAGE: i
CATALOG #*27672-3 NAME: HEXACHLOROBENZENE, TECH.# 75X
HEALTH HAZARD OATA
ACUTE EFFECTS „
HARMFUL IF SWALLGWEO, INHALED, OK ABSORBED THROUGH SKIN.
CAUSES EYE ANO SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES ANO UPPER
RESPIRATORY TRACT.
CHRONIC EFFECTS
CARCINOGEN.
FIRST AID
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF MATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING ANO SHOES.
IF INHALED* REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT* GIVE OXYGEN.
CALL A PHYSICIAN.
DISCARO CONTAMINATED CLOThING ANO SHOES.
PHYSICAL OATA
NO PHYSICAL DATA AVAILABLE
. FIRE AND EXPLOSION HAZARD OATA
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON OIGXIOE* DRY CHEMICAL POWOER, ALCOHOL OR POLYMER FOAM.
SPECIAL FIRE FIGHTING PROCEDURES
WEAR SELF—CON T A I Nt 0 6Rc A THING APPAhATUS a:,C PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN ANO EYES.
UNUSUAL FIRE ANO EXPLOSION HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
REACTIVITY DATA
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PROOUCTS
TOXIC FUMES OF:
CARBON MONOXIOE, CARBON OIOXIDE
HYDROGEN CHLORIDE GAS
SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED J* SPILLcO
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUtibcR 3U0TS ANO HEAVY
RUBBER GLOVES.
WEAR DISPOSABLE COVERALLS ANO OISCARj THE* AFTER USE.
SWEEP UP, PLACE IN A 6aG ANO HOLD FOR WASTE DISPOSAL.
VENTILATE AREA ANO WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
WASTE OISPOSAL METHOD
OISSOLVE OR MIX THE MATirtlAL WITH A COMBUST 13LE SOLVENT ANO tJURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERoURNEH ANO SCRUdBcR.
03SERVE ALL FEDERAL. STATE C LOCAL LAWS.
PRECAUTIONS TO 5t TAKEN IN HANDLING ANO STORAGE -
WEAR APPROPRIATE N IOSi-i/.'ISha-APPRJVsO RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOiGLcS, CiTHtR PRJTtCTIV; CLOThlNvi.
SAFETY SHOWER ANO cYfc tATn.
USE ONLY IN A CHEMICAL FUME HuCO.
;«*¦••<» Co itt >wp c
BmWIU r«MM
V* -OM'tntii rmm t
'mi nrr«t«*i 'u m
»M <®?4f#» W»

A-32
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m « m chemists helping chemists in research & industry Telephone. (4i«) 273.3850
_ _ _ TWX: (910) 2S2-30S2 Aldricnem Ml
0 aldrich chemical co.
P.O. Sox3S& UimuHm. WitetrntlnU301 USA
MATERIAL S A.F 6 T V DATA-SHEET PAGE:
CATALOG # 27672-3 NAME: HEXACHLOROBENZENE» TECH.* 75*
00 NOT BREATHE DUST.
AVOID ALL CONTACT.
MASH THOROUGHLY AFTER HANDLING.
CARCINOGEN.
HARMFUL SOLID.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
:— ADDITIONAL PRECAUTIONS AND COMMENTS
NOT APPLICABLE
THE ABOVE INFORMATION IS 3ELIEVED TO SE CORRECT BUT DOES NOT PURPORT
TO BE ALL INCLUSIVE AND SHALL oE USED UNLY AS A GUIOE. ALDRICH SHALL
NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANOLING OR FROM
CONTACT WITH THE ABOVE PRODUCT. SEE RcVERSt SIDE OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TER*S AND CONDITIONS OF SALE.
MS
A-33
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chemists helping chemists in research & industry Ttiserion.. («i4) 273-jaso

TWX: (910) 262-3052 Aldrichtm Ml
Tal«>: 28 843 Aldrich Ml
FAX: (414) 273-4979
* P.O. Bom JS& Ullmtuk—. Wlteentin S3301 USA
aldrich chemical co.
ATTN: SAFETY DIRECTOR
ENVI RESPONSE. INC
GSA RARITAN OEPOT
W000BRIOGE AVE
EOI SON NJ
GARY SEIB6L
0ATc: 09/19/88
CUST * 92<»8U7 P.O. e
08837
MATERIAL SAFETY
0 A T A
SHEET
PAGE
IDENTIFICATION
PRODUCT tf 17105-0
CAS » U3-7W
MF: C6CL6
SYNONYMS
AMATIN • ANTICARIE
NAME: HEXACHLORObfcNZENE. 99%
* BUNT-CURE • liUNT-NO-MORE • CO-OP HEX A •
ESACLOROBENZENE (ITALIAN) « SAANOX NM • HCb « HEXA C.B. •
HEXACHLORBENZOL (GERMAN) • HcXAChluROoE.NZENE • HEXACHL0R0B6NZENE (OOT)
• JUL IN'S C AR SON CHLOKIO& • NO bUNT « ,N0 dUNT *0 • NO BUNT 80 • NO
BUNT LIUUID • PENTACHLORUPHcNtL CHLORIOE « P6RCHL0R0BENZENE • PHENYL
PERCHLORYL • SANCCIOc • SMUT-GO • RCRA WASTE NUMBER U12 7 •
SAATBEIZFUNGIZ10 (GERMAN) • SANOCIO • SNIcCIOTOX • UN 2729 (OOT) •
TOXICITY HAZAROS —
RTECS J 0A2975000
BENZENE* HEXACHLUkO-
TOXICITY DATA
UNR-MAN LOLO:220 MG/KG
IHL-RAT LC50:3600 HG/M3
ORL-MUS LD 50: <~ GM/KG
IHL-MUS LC50:<* GM/M3
ORL-CAT LO50 : 1 700 .iG/KG
IHL—CAT LC SO: 160U MG/M3
ORL-RBT L050:2600 MG/nG
IHL-RBT LC50:1oOQ .«W<«3
ORL-MAM LC50 : 10<» 7 MG/KG
850CAI
85GMAT
•35GMAT
35GMAT
85GMAT
85GMAT
85GMAT
35GMAT
NTI
2.73.70
-.72.82
-.72,82
-.72,82
-.72.82
-.72.82
-.72.82
-.72.82
PB288—<~! 6
REVIEWS. STANDARDS. ANO REGULATIONS
EPA GENETOX PROGRAM 1986. POSITIVE: CARCINOGbNICITY-MOUSE/RAT
GEN6T0X PROGRAM 1986. NEGATIVE: RuOENT OOMINANT LETHAL
TSCA CHEMICAL INVENTORY. 1986
TSCA T5ST SUBMISSION (TSCATS) DATA SASH. MARCH 1988
FOURTH ANNUAL REPORT ON CARC I.NOGeNS. 192V
CRITERIA FOR PROPOSED OSHA MEuICAL RECOKOS RULE FEREAC
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A- m chemists helping chemists in research & industry Teieonon.: «i4) 273.3M0
^ ¦ ¦ 9 rnt _ TWX: (910) 202-3052 Aldrichwn Ml

aldrich chemical co.
Taltx: 20 643 Aldrtcn Ml
FAX: (414) 273-4979
'* P.O. Bet 336. V/ImMm WlteontUt SH01 USA
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG * 17105-0 NAME: HEXACHLOROBENZcNE* 99*
HEALTH HAZARD DATA
ACUTE EFFECTS
harmful if swallowed* inhaled* or absorbed through skin.
CAUSES EYE ANO SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
CHRONIC EFFECTS
CARCINOGEN.
FIRST AID
IN CASE OF CONTACT* IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING ANO SHOES.
IF INHALED* REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT* GIVE OXYGEN.
CALL A PHYSICIAN.
DISCARO CONTAMINATED CLOTHING ANO SHOES.

MELTING POINT: 227 C TCl 229 C
BOILING POINT: 323 C TO 326 C
— FIRE ANO EXPLOSION HAZARD DATA —
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE* ORY CHEMICAL POWDER* ALCOHOL OR POLYMER FOAM.
SPECIAL FIRE FIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS ANO PROTECTIVE CLOTHING TO
PREVENT CONTACT WITh SKIN ANO EYES.
UNUSUAL FIRE ANO EXPLOSION HAZARDS
EMITS.TOXIC FUMES UNDER FIRE CONDITIONS.
REACTIVITY DATA
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PROOUCTS
TOXIC FUMES OF:
CARBON MONOXIDE* CARBON DIOXIDE
HYOROGEN CHLORIDE GAS
SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED 3* SPILLED
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS* RU8t)Ek BOOTS ANO HEAVY
RUBBER GLOVES.
WEAR DISPOSABLE COVERALLS ANO DISCARD THEM AFTER USE.
SWEEP UP* PLACE IN A &mG AND HOLD FOR xASTe DISPOSAL.
VENTILATE AREA ANO wASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
WASTE DISPOSAL METHOD
OISSOLVE OR MIX THE MATrKlAL »ITH A COMBUSTIBLE SOLVENT AND SURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER ANO SCRU3SER.
OBSERVE ALL FEDERAL * STATE L LOCAL LAWS.
IM
rmtalKKM
0«r«vi«*
'iwi i
-------
©chemists helping chemists in research & industry
aldrich chemical co.
P.O. Bow 3S5. mwiuMm. Wlteonun 33101 USA
Telephone: (414) 273-3850
TWX: (910) 262-3052 AMncnam Ml
Tain*: 29 843 Aldrich Ml
FAX: (414) 273-4979
MATERIAL SAFETY DATA SHEET PAGE:
CATALOG 9 17l05-0~ NAME: HEXACHLOROBENifcNE, 99%
PRECAUTIONS TO BE TAKEN IN HANOLING AND STORAGE
HEAR APPROPRIATE N IOSH/MSHA-APPhOVED RESPIRATOR, CHEMICAL-KESISTANT
GLOVES, SAFE TY GOGGLES, OThfcK PROTcCTIVE CLOTHING.
SAFETY SHOWER ANO EYE BATH.
USE ONLY IN A CHEMICAL FUME HOOD.
00 NOT BREATHE OUST.
AVOID ALL CONTACT.
WASH THOROUGHLY AFTER HANOLING.
CARCINOGEN.
IRRITANT.
KEEP TIGHTLY CLOSED.
STORE IN A COOL ORY PLACE.
additional precautions ano comments ——
not applicable
THE A90VE¦INFORMATICN IS BELIEVED TO 3E CORRECT BUT OOES NOT PURPORT
TO BE ALL INCLUSIVE Amj .shall 3E USED ONLY AS A GUIOE. ALDHICH SHALL
NOT BE HELD LIABLE FOR ANY JAMAGE RESULTING FROM HANDLING OR FROM
CONTACT WITH THE AbOVE PRODUCT. SEfc REVERSE SIDE OF INVOICE OR PACKING
SLIP FOR ADDITIONAL TEK:MS AND CONDITIONS OF SALE.

391
***** Co im
WO>0 •»<•»•»• «¦•*«
Sor«l M *A
rMVM lO'llia"
•*< j;n

A-36
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EAGLE li^PICHER
MATERIAL SAFETY
DATA SHEET
A. GENERAL INFORMATION
I TKADE NAME (COMMON NAME OR SYNONYM)
Eagle-Picher Super Sublimed White Lead
I'RoiiLCT COOC •
#41
CHEMICAL NAME
Basic Sulfate White Lead
FORMULA
P6S0,.PbO
u
molecllar weight
526
| ADDRESS <\u . SIRFt I. Ill Y. STATE AND ZIP CODE)
j P.O. Box 5:.0
I Joplin, Missouri 66802
con tact
PHO^E NLM8ER
IbSL EU DATE
REVISED D \TE
Cagle-Picher Industries. Inc.
(417) 623-8000
11 /as
9/05
Chemicals Department
Emergencies: Call CHEMTREC (800) fc2t-9300
B. HAZARDOUS INGREDIENTS
r
MATERIA! OK COMPONENT
c*s -•
WT PERMISSIBLE AIR CONCENTRATION
Basic Sulfate unite Lead
7446-14-2
99.9
0.05 mg/m (0SHA)
0.15 mg/m (ACGIH)
~ OSHA ~ \CCIH
3 OTHER
C. FIRST AftrHteASVWO
If ingested, induce voniting and call a physician at once.
If inhaled and efTeeta of over-exposure are experienced, remove from exposure ana call a physician.
If eye irritation exists, flush thoroughly »ith plain »ater.
A-37
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D. HAZARDS INFORMATION
HEALTH
inhalation Oust, mist, vapor and/or fune may be irritating to the respiratory system, and can result in
both acute and chronic over-e*posure. (See Section K)
INGESTION Oust, mist, vapor and/or fune nay be absorbed by the digestive systen, and can result in both
acute and chronic over-e«posure. (See Section K)
SKIN Oust, aist, vapor and/or fuw nay cause aki'i irritation in sensitive individuals, but are not readily
absorbed through the shin.
TTTs ' ' ' 1 "—
Oust, mist, vapor and/or fume may cause eye irritation in some individuals.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED "
Anemia, kidney disease, pregnancy.
UNLSUAL CHRONIC TOXICITY Kidney damage may occur aithout aymptoms. Lead crosses the placenta, fertile
females should have exposure and biological specimens carefully monitored to sssure blood lead levels stay
¦ ithin CDC guidelines of 30 ua/IOOo of blood in order to protect the potential fetus.
FIRE AND EXPLOSION
FLASH POINT °C
Non-flammable
Q OPEN CUP 0 CLOSED CUP
AUTO IGNITION C
TEMPERATURE n/a
FLAMMABLE LIMITS IN AIR 8f \Ot. \
N/A
UNUSUAL FIRE AND EXPLOSION HAZARDS
None
•E. PRECAUTIONS/PROCEDURES
FIRE EXTINGUISHING AGENTS RECOMMENDED
As appropriate for surrounding material.
FIRE EXTINGUISHING AGENTS TO AVOID
None
SPECIAL FIRE FIGHTING PRECAUTIONS
Use a poaitive-pressure self-contained breathing apparatus with full facepiece.
ENGINEERING CONTROLS
Use mechanical containment and local exhaust ventilation to maintain airborne lead levels below the
OSHA PEL.
normal HaNOLING
Use »ork practices which minimize the generation of dust« mist, vapor, and/or fume.
See Section "F" - Personal Protective Coviioment.
STORAGE " : "
Keep dry in order to maintain product quality.
SPILL OR LEAK Avoid dry sleeping. Do not use compressed air to clean surfaces. Vacuuming or wet sweeping
is preferred. Wear respirator, protective clothing, and gloves. Return all material possible to container
for proper disposal.
Label tignal word: WARNING!
SPECIAL. PRECAUTIONS PROCEDlRES LABEL. INSTRUCTIONS Do not inhale or Swallow dust. When handling
contents, properly use N10SH approved respirators, clean protective clothing and gloves* Wash thoroughly
after handling and before eating, drinking, or smoking. Use with adequate ventilation*
PERSONAL HYGIENE Good personal hygiene is of utmost importance in controlling long tero exposure* wasn
thoroughly before eating, drinking, or smoking. If the PCL is exceeded or significant contact occurs,
thorough showering recommended before leaving work. Do not take contaminated clothing or shoes hone.
A-38
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. PERSONAL PROTECTIVE EQUIPMENT .
RESPIRATORY PROTECTION Respirators (re required «henever the PEL is exceeded. Respirators must Oe
NIOSH-HSHA approved for tonic dusts. High-efficiency (*PA) filters «re recommended.
See 29 CFR 1910.102S (f)(2)(l) Title II for respirator types required at varying exposure levels.
*YES and FACE *ile inorganic lead compounds are not readily absorbed through the eyes or face, dust,
mist vapor and/or fimm in high concentrations or combined «ith other substances during processing may cause
irritation, requiring eye or face protection.
(ANDS. ARMS. AND BODY Cloves are recommended ahen handling material,Clean protective clothing is re-
quired "hen the PEL is exceeded or significant contact occurs. Although skin contamination is not generally
a problem, it increases the possibility of ingestion through poor personal hygiene.
OTHER CLOTHING A.NO EQUIPMENT Personal clothing and shoes should be protected from contamination »itn
this product. Contaminated sork clothing and shoes should not be taken from the aorkplace.
;. PHYSICAL DATA
MATERIA!. IS 1 AT NORMAL CONDITIONSl
2 liquid E solid Ocas
-1
APPEARANCE ANOODOR
White powder, Non-detect«ble odor.
BOILING POINT fg/A
MELTING POINT 977°C
SPECfFIC GRAVITY

N/A