WORKING PAPER NO. E.P.A.-910-8-77-100 WATER QUALITY INVESTIGATION RELATED TO SEAFOOD PROCESSING WASTEWATER DISCMARGES AT DUTCH HARBOR, ALASKA OCTOBER 1975 OCTOBER 1976 ENVIRONMENTAL PROTECTION AGENCY SURVEILLANCE AND ANALYSIS DIVISION SEATTLE, WASHINGTON REGION X ------- WATER QUALITY INVESTIGATION RELATED TO SEAFOOD PROCESSING WASTEWATER DISCHARGES AT DUTCH HARBOR, ALASKA October 1975 October 1976 Working Paper # EPA910/8-77-100 Prepared by: R. Keith Stewart Daniel R. Tangarone Region X, Environmental Protection Agency Alaska Operations Office, Anchorage Surveillance and Analysis Division, Seattle May 1977 ------- THIS DOCUMENT IS AVAILABLE TO THE PUBLIC IN LIMITED QUANTITIES THROUGH THE U.S. ENVIRONMENTAL PROTECTION AGENCY, REGION X, SURVEILLANCE & ANALYSIS DIVISION, SEATTLE, WASHINGTON. ii ------- TABLE OF CONTENTS Page Introduction and Purpose 1 Findings 4 Conclusions 7 Previous Studies .... 8 Description of Study Area 10 General . 10 Climate .......... 10 Oceanography 10 Water Quality Standards 12 Water Uses 13 Waste Sources 14 NPDES Permit Requirements 15 Survey Methods 16 Water Quality 16 Bottom Sediments 16 Diving Observations 17 Current Drogue Studies 17 Compliance Monitoring 18 Sample Shipment ..... . 18 Discussion of Results . 19 General 19 Temperature and Salinity 19 Dissolved Oxygen . 19 Nutrients 22 Bottom Sediments 23 References 25 Appendix 55 iii ------- 1 2 3 4 5 6 7 ฃ1 1 2 3 4 5 6 7 26 27 31 40 41 42 43 2 49 50 51 52 53 LIST OF TABLES 1968 Dissolved Oxygen Concentrations Analytical Results - 1975 Analytical Results - 1976 Bottom Sediment Sample Results - 1975 . . . . Bottom Sediment Sample Results - 1976 . . . . Effluent and Stream Sample Results - 1976 . . Current Studies Data - 1976 LIST OF FIGURES Location of Study Area Processor and Outfall Locations - 1976 . . . . Water Quality Station Locations Water Quality Station Locations Bottom Profile of Study Area Flood Tide Current Movements - 1976 Ebb Tide Current Movements - 1976 iv ------- INTRODUCTION AND PURPOSE One of the largest and oldest Industries in Alaska is the seafood processing industry. Hundreds of millions of pounds of fish and shellfish are processed each year. The industry is widely dispersed throughout the western and southern coastal reaches of the State. Several areas, hoi^ever, have significant concentrations of seafood processing facilities. The newest and most rapidly expanding of these areas is Dutch Harbor. Dutch Harbor, located about 740 air miles southwest of Anchorage on the Aleutian chain (Figure 1), has become the second largest, only exceeded by Kodiak, processing center of shellfish in Alaska. In 1970, the five facilities located at Dutch Harbor processed approximately 20 million pounds of shellfish. By 1976, this output by eleven processors had increased more than three times (Figure 2) to about 72 million pounds. Of the total harvest weight processed, an estimated two-thirds are waste materials which are discharged following grinding into the waters of the Dutch Harbor area. Development of an oil-staging area in the vicinity of Pacific Pearl Seafoods in Captains Bay is beginning to occur. Future buildup of activ- ity related to oil development and exploration in this area is very likely and may have adverse water quality effects. Additionally, development of a bottom fishery is also possible within the next few years. Should this occur, wastes discharged from the processing of these fish would have an additional impact on water quality. Because of the large volume of shellfish processed and associated wastes produced, it was determined that information on the water quality 1 ------- NORTH PACIFIC OCEAN 2 FIGURE 1 ------- effects of waste discharges and the compliance status of NPDES permits issued to seafood processors should be gathered. Additionally, this data would be of importance in the future National Pollutant Discharge Elimination System (NPDES) permitting actions to municipalities, oil facilities, and new seafood processors in the area. Due primarily to adverse weather conditions, a brief one-day survey was performed during October 1975. The data obtained were not adequate to meet total survey objectives and, therefore, a second more extensive survey effort was conducted during October 1976 for the purpose of deter- mining: 1. The effects of waste discharges on water quality 2. The extent of seafood waste sludge deposits 3. Water current movement patterns in the Dutch Harbor study area 4. Compliance status of seafood processors with NPDES permit requirements. 3 ------- FINDINGS 1. Dissolved oxygen concentrations below the Alaska water quality standard of 6 mg/1 were found at 5 locations during the 1975 survey and at 17 locations during the October 1976 survey. 2. Dissolved oxygen concentrations below 6 mg/1 were found primarily at the 25 meter or deeper depths and usually within close proximity of the bottom. The lowest value recorded (0.0 mg/1) during the October 1976 survey, however, was found at Station 20 at the bottom at 17 meters depth. 3. Dissolved oxygen concentrations below 6 mg/1 were found during both the flood and ebb tide stages on both days surveyed during October 1976. 4. Significantly increased levels of ammonia and total phosphorus concen- trations observed over those at stations used as control points, were found at most stations located in Iliuliuk Harbor, Iliuliuk Bay, and Dutch Harbor. 5. Ammonia concentrations found near the bottom for all 17 stations located in Iliuliuk Harbor, Iliuliuk Bay, and Dutch Harbor ranged from <.01 mg/1 to 3.8 mg/1 for samples collected during the October 1976 survey. The average concentration found at these stations was 0.60 mg/1, substantially greater than the background concentrations of <0.01 mg/1 found at the outer locations on the west side of Amaknak Island in Unalaska Bay and in outer Iliuliuk Bay. 6. Total phosphorus concentrations found near the bottom for all 17 stations located in Iliuliuk Harbor, Iliuliuk Bay, and Dutch Harbor ranged from 0.03 mg/1 to 1.6 mg/1 for samples collected during the 4 ------- 13. Accumulations of seafood waste solids in excess of 3 inches at the 30 meter radius from the end of the outfall pipe were found at the discharge locations of Easpoint Seafoods (M/V Eastpoint), Universal Seafoods (M/V Unisea), Vita Food Products (M/V Vita and M/V Viceroy), New England Fish Company (M/V Theresa Lee), and Sea Alaska Products (M/V Sea Alaska and M/V Sea Producer). 6 ------- CONCLUSIONS 1. Seafood processing waste discharges are primarily responsible for the observed depressed dissolved oxygen concentrations and increased nutrient concentrations particularly in Iliuliuk Harbor, inner Iliuliuk Bay, and in Dutch Harbor. 2. Water current movement in the vicinity of the existing outfall loca- tions on the west side of Amaknak Island and outfall locations within Dutch Harbor do not provide for adequate dispersion of discharged waste solids. 3. Seafood wastes have been responsible for old sludge deposits found at the abandoned submarine base repair dock and at locations within Iliuliuk Harbor and the inner reach of Iliuliuk Bay south of the sill. 4. Seafood waste discharges have been and continue to be largely respon- sible for the formation of sludge deposits in the Dutch Harbor embay- ment of the study area. 5. Seafood processing wastewaters, screened or unscreened, should not be discharged to Iliuliuk Harbor including the reaches associated with the sub-base embayment and Margaret Bay. 6. Seafood processing waste solids should not be discharged to Dutch Harbor, the reach of Iliuliuk Bay inland of the sill, and Captains Bay including the reach from Amaknak Rocks to Iliuliuk Harbor. 7. Sludges found at Station 18 in 1975 (the east arm of Captains Bay) were the result of waste discharges from floating processing ships which anchored in this area in this and other years. 8. Solids should be screened from all existing process waste streams discharging to the west side of Amaknak Island. The collected solids should then be disposed of in an acceptable manner. ------- PREVIOUS STUDIES A brief water quality survey was conducted by the University of Alaska during June 1968. The principal objective of this study was to obtain information on the fate of organic matter associated with seafood processing waste (2). Ammonia concentrations were found to be normal for seawater in areas little affected by seafood processing facilities. In Iliuliuk Harbor, however, high ammonia concentrations were found. Samples taken at several depths near the southern tip of Amaknak Island in Captains Bay were characteristic of non-enriched seawater with less than .015 mg/1 ammonia. At a station in the offshore waters of Unalaska Bay, the maximum ammonia concentrations diminished to less than .05 mg/1. Samples taken near the seafood processing facilities in Iliuliuk Bay at depths of 0, 5, and 10 meters, had concentrations of ammonia nitrogen of .072, .113, and .080 mg/1 respectively. At a station near the most upbay reach of Iliuliuk Bay, the concentrations of ammonia nitrogen ranged from .064 to .333 mg/1 between the 10 and 25 meter depths. The substantial increase in ammonia nitrogen found in the deeper waters of Iliuliuk Harbor and Bay was believed to be the result of decomposition of organic matter which had accumulated on the bottom. The same study also showed that the dissolved oxygen concentrations were lowered in the bottom waters. Because of the rapid buildup of processing facilities in the Dutch Harbor area and increased pollutional pressures imposed on receiving waters an October 1975 survey was performed by EPA during the peak of the seafood processing activity. All but one of the seven stations 3 ------- sampled during the 1968 study, a station in Unalaska Bay offshore of Iliuliuk Bay, were sampled during the October 9, 1975 survey. A total of 11 stations were sampled during the 1975 survey. The October 1975 survey included measurements for temperature, pH, conductivity, dissolved oxygen, ammonia nitrogen, and total phosphorus at the 1, 10, and 25 meter depths and just above the bottom. Bottom deposit samples were obtained for analysis of volatile solids, percent organic matter, and chemical oxygen demand, and for inspection of the occurrence of hydrogen sulfide odors and macroscopic marine life. Gen- erally poor water quality, described in more detail later in this report, was found during the 197 5 survey. 9 ------- DESCRIPTION OF STUDY AREA General The Dutch Harbor survey area (Figure 1) is located on the north or Bering Sea side of the Aleutian Islands west of the Alaska Peninsula. The survey area consists of Captains Bay, Dutch Harbor, Iliuliuk Bay, Iliuliuk Harbor, and portions of Unalaska Bay (Figure 2). Iliuliuk Harbor is a highly contorted embayment situated between Captains and Iliuliuk Bays. Captains Bay, Iliuliuk Harbor, Iliuliuk Bay, and Dutch Harbor have limited circulation patterns largely the result of sills (Figure 5) which form physical barriers to the circulation of deep water. Climate The Dutch Harbor area has a cold maritime climate with normal summer air temperatures ranging from 50 to 60 degrees Fahrenheit and normal winter temperatures ranging from 25 to 35 degrees Fahrenheit. High summer temper- atures may attain 85 degrees Fahrenheit for brief periods, and low winter temperatures may reach 10 degrees Fahrenheit. Inclement weather conditions are common, and are characterized by low cloud cover which often interferes with airline transportation to the area. Winds in winter and during storms are usually strong. Wind velocities of more than 100 knots are not uncom- mon. During brief periods of cold winter weather, ice up to two inches thick may be found on Iliuliuk Harbor, but the other bays in the area remain ice free throughout the year. Oceanography Two major freshwater streams enter the study area, the Shaishnikof River at the head of Captains Bay, and the Town River which drains Unalaska 10 ------- Lake on the east side of Iliuliuk Harbor. Both streams are utilized by salmon for spawning. Several smaller streams also flow into the general survey area. The total freshwater inflow to the area slightly dilutes the salinity of the surface waters in the area. The waters of the study area are decidedly marine rather than estu- arine. Salinities ranged from 20.5 to 32.0 parts per thousand during the 1975 survey and from 19.2 to 33.9 parts per thousand during 1976. Verti- cal and horizontal salinity gradients which cause stratification of marine waters undoubtedly occur but their intensity, duration, and diurnal and seasonal variations were not defined as a part of these surveys. It is evident from examination of U.S. Coast and Geodetic Survey maps that Captains Bay, Iliuliuk Harbor, and the Dutch Harbor-Iliuliuk Bay sys- tems are three distinct basins separated by sills (pronounced underwater elevated land across the bottom of a bay or other marine watercourse; see Figure 5). One of the sills is located near the mouth of Captains Bay. Two more, one at each end of Iliuliuk Harbor, separate this basin from Iliuliuk Bay and Captains Bay. The other sill is situated near the mouth of Iliuliuk Bay and separates the Iliuliuk Bay-Dutch Harbor basin from the open waters of Unalaska Bay and the Bering Sea. These sills hinder circu- lation of the deep water layers within the basins. The three basins thus form traps for settleable solids and nutrients introduced into these waters. Tides In the area are not great, having a maximum amplitude of near 10 feet. The mean tidal amplitude (mean high water to mean low water) is about four feet. 11 ------- Water Quality Standards The present Alaska Water Quality Standards (3) designate the marine waters of the State as Classes C, D, E, and G. The standard criteria asso- ciated with marine waters that are of particular interest in this report are those for dissolved oxygen, residues in the form of settleable solids and sludge deposits, and toxic substances. Of the various classifications, the following are the most stringent criteria. Dissolved Oxygen Class D - Greater than 6 mg/1 in salt water. Class E - Greater than 6 mg/1 in the larvae stage. Greater than 5 mg/1 in the adult stage. Residues, Including Oils, Floating Solids, Sludge Deposits, and Other Wastes Class D - "Residues may not make the receiving water unfit or unsafe for the uses of this classification; nor cause a film or sheen upon, or discoloration of, the sur- face of the water or adjoining shoreline; nor cause a sludge or emulsion to be deposited beneath or upon the surface of the water, within the water column, on the bottom or upon adjoining shorelines. Residues shall be less than those levels which cause tainting of fish or other organisms and less than acute or chronic problem levels as determined by bioassay." Class E - Same as Class D. 12 ------- Settleable Solids, Suspended Solids (includes sediment and dredge spoil and fill) Class C - No visible concentrations of sediment. Class D - No deposition which adversely affects fish and other aquatic life reproduction and habitat. Class E - No deposition which adversely affects growth and prop- agation of shellfish. Toxic Substances Class D - Concentrations shall be less than those levels which cause tainting of fish, less than acute or chronic problem levels as revealed by bioassay or other appro- priate methods and below concentrations affecting the ecological balance. Class E - Same as Class D. Water Uses Uses of the waters of the Dutch Harbor area as stipulated in the Alaska Water Quality Standards (3), consist of water contact recreation, growth and propagation of fish and other aquatic life (including water- fowl and furbearers), shellfish growth and propagation (including natural and commercial growing areas), and industrial water supply other than food processing. Of prime importance from a water quality viewpoint is the use of these waters for holding live crab. These waters miist be of sufficient quality to support the&e animals for periods up to two days. Live crab in the tanks of fishing vessels sometimes are held while in port for one 13 ------- or more days prior to offloading during peak crabbing periods. After being offloaded from the fishing boats, the live crabs are held over- board prior to processing. Additionally, the waters in the Dutch Harbor area constitute his- toric nursing and feeding grounds for young and adult crab. Waste Sources Processing and discharge locations for waste sources during the October 197 5 survey are shown in the following table: Processor Process Location Discharge Location M/V Sea Alaskan Dutch Harbor Dutch Harbor M/V Sea Producer Dutch Harbor Dutch Harbor M/V Theresa Lee Dutch Harbor Dutch Harbor Pan Alaska Fisheries Iliuliuk Harbor Iliuliuk Harbor M/V Royal Alaskan Captains Bay Captains Bay M/V Eastpoint Iliuliuk Harbor Iliuliuk Harbor Whitney Fidalgo 11iuliuk Harbor Iliuliuk Harbor M/V Vita Iliuliuk Harbor Unalaska Bay M/V Viceroy Iliuliuk Harbor Unalaska Bay M/V Unisea Iliuliuk Harbor Unalaska Bay Pacific Pearl Seafoods Captains Bay Captains Bay Waste sources and discharge locations as situated during the October 1976 survey are shown on Figure 2. Only Eastpoint Seafoods (M/V Eastpoint) was continuing to discharge processing wastes to Iliuliuk Harbor. 14 ------- NPDF.S permits issued to the seafood processors in the Dutch Harbor area all contained provisions which required that all seafood wastes be reduced to a diameter of 1.27 cm (0.5 inch) or less prior to discharge. The discharge of this waste was to be at least 13 meters (7 fathoms) below mean lower low water. Monitoring of bottom conditions is required by use of bottom cores to determine the amount of solids accumulation around the outfall. If more than 3 inches of waste solids is found, one year from that time the permittee is required to install a screening device equiva- lent to a tangential screen with a grid spacing of 1 mm (0.040 inch) or less. Seafood processing wastes which are retained on this screening system must be disposed of by 1) recovery, 2) other means approved by the Regional Administrator, or 3) transport (without loss of solids) to a specified deep water disposal site. Other than seafood processing wastes, there are currently no other existing significant industrial discharges in the Dutch Harbor area. Future development of the area, however, as related to oil development and explora- tion activities and the development of a bottom fishery is very likely and may have significant environmental impact. Other existing discharges are primarily treated domestic wastes from approximately 1000 employees associated with the seafood processing facil- ities, and from the villages of Dutch Harbor and Unalaska. These villages have a combined population near 350 people, and are partially sewered, but do not provide for treatment of domestic wastes. Except for bacteriological effects, domestic discharges are insignificant relative to the effect of seafood wastewater discharges. 15 ------- SURVEY METHODS Water Quality During the October 1975 survey, samples were collected by EPA per- sonnel typically at four depths during one flood and one ebb tide stage at 11 stations. Sampling started within two and one-half hours of the onset of each of the two tide stages, and was completed at all 11 stations before the termination of each tidal stage. During the October 1976 survey samples for chemical and physical analysis were collected jointly by the Alaska Department of Environmental Conservation (ADEC) and Environmental Protection Agency personnel from 32 stations (Figures 3 and 4). Dissolved oxygen, temperature, conductivity, and pH were determined with a Hydrolab Model 6D Surveyor Portable Water Monitor" for all stations sampled by EPA. A Martek Water Quality Analyzer" was utilized by the ADEC personnel during the 1976 survey. The dissolved oxygen probes of these instruments were calibrated daily in salt water by the standard Winkler method prior to each sampling run and each time a suspected erratic value for this parameter was obtained. Salinity determinations were measured directly with the Martek instru- ment and were calculated from the conductivity and temperature data obtained with the Hydrolab instrument. Bottom Sediments Bottom deposit samples were obtained at 11 stations by use of a small *Use of product and company names is for identification only and does not constitute endorsement by the U.S. Environmental Protection Agency. 16 ------- dredge during the 1975 study and at 7 stations during the 197 6 survey to determine the organic content and decomposition characteristics of the deposits; the presence of hydrogen sulfide by smell; and to obtain general information pertaining to the occurrence of macroscopic (readily visible) animals or plants associated with the bottom reaches of the study area. Chemical analyses of the bottom deposit samples were performed at the EPA, Region X laboratory. Samples for analysis were packed in ice after collection and shipped in ice filled chests. Diving Observations During the October 197 6 survey scuba-diving teams using "dry suit" SCUBA gear and composed of EPA Region X and NEIC-Denver personnel, inspected the outfall locations of seafood processing wastewater discharges, checked for line ruptures and determined the extent of seafood waste solids accu- mulations around the outfalls. EPA divers utilized measuring tapes and rods, calibrated lines, maps, and cameras to define and record waste dis- charge accumulations. Diving activities are detailed in Appendix A. Current Drogue Studies Water currents in the Dutch Harbor vicinity during the October 1976 survey were measured by use of drogues fabricated from 12 to 18 inch diam- eter plastic buoys, wooden warehouse pallets, nylon line, and small gunny sacks. The Alaska Department of Fish and Game courteously provided the gunny sacks as well as binoculars and spotting scopes to track the course of drogues. Fifteen to twenty pounds of rocks were placed in the sacks and one of these was tied to each pallet to assure that the pallets would be suspended at the selected depths. 17 ------- Drogue movement after the first day of observations was measured with the aid of radar on board a small fishing boat. A minimum of three bearings was taken to fix drogue locations during the tracking process. The courses of the drogues were plotted on Coast and Geodetic Survey maps. Tidal data from "Tide Tables 197 6 High and Low Water Predictions, West Coast of North and South America" (4) were used to determine the onset and duration of each tidal cycle and to determine periods of water sampling. Compliance Monitoring In-plant inspections were performed to determine compliance with NPDES permit conditions. During the 1976 survey, inspections were performed by both EPA and ADEC personnel. Samples of the effluent stream were obtained from most of the facilities for analysis of ammonia, total phosphorus, COD, total volatile solids, and total organic carbon (Table 6). Sample Shipment Samples were shipped in ice-packed containers, according to established chain-of-custody procedures, to the U.S. Environmental Protection Agency National Enforcement Investigations Center Laboratory at Denver, Colorado. Bottom sediment samples were shipped to the Region X, EPA Laboratory in Seattle, Washington. 18 ------- DISCUSSION OF RESULTS General Generally lowered water quality conditions were found in the Dutch Harbor study area during both the 1975 and 1976 surveys. Low dissolved oxygen concentrations near the bottom, increased nutrient concentrations within the bays, and decomposing sludge deposits of seafood wastes were encountered during both the 1975 and 1976 surveys. Temperature and Salinity Temperature and salinity data (Tables 2, 3, and 3A) were gathered during both surveys to calculate density values, and to correct for dis- solved oxygen values for saline waters. Calculations for density were based on values recorded in the Handbook of Oceanographic Tables (5). During the 1976 survey, salinity values ranged from 19.2 parts per thou- sand at the one meter depth in Iliuliuk Harbor to 33.9 parts per thousand at the near-bottom depths. Non-saline waters, primarily from the Unalaska and Shaishnikof Rivers measurably diluted the surface marine waters in the study area. The seaward reaches of both Captains Bay and Iliuliuk Bay were weakly stratified. Iliuliuk Bay was strongly stratified with a distinct layer of relatively warm, less dense lens of less saline surface and near- surface water overlaying deeper, cooler more saline and more dense waters. Dissolved Oxygen Dissolved oxygen concentrations at the 25 meter depth determined for selected stations during a June 1968 study (Table 1) conducted by the 19 ------- University of Alaska (2), were below the Alaska Water Quality Standards of 6 mg/1 (3) in the northeastern portion of Captains Bay and at 3 loca- tions in Iliuliuk Bay on the south side of a sill separating Iliuliuk Bay from the waters of Unalaska Bay. Low dissolved oxygen concentrations were again found in the deeper waters of these areas during the October 9, 1975 water quality monitoring investigation (Table 2). During the 1976 survey, dissolved oxygen data (Table 3 and 3A) were collected during ebb and flood tide stages on October 19 and October 24. Dissolved oxygen values below the Alaska Water Quality Standard of 6 mg/1 were recorded within one or more meters of the bottom at Stations 1, 3, 4, 7, 20, 23-29, and 32-36, located (Figure 3) as follows: Station General Location 1,3,4,7 Captains Bay 20 Old Submarine Repair Dock 23-29 Iliuliuk Bay 32-36 Dutch Harbor For the Captains Bay stations it is believed that the low dissolved oxygen values are primarily representative of natural conditions encoun- tered in a relatively deep fjord-type water body. However, for the other stations located in Iliuliuk Harbor (submarine dock), Iliuliuk Bay, and Dutch Harbor, the depressed bottom dissolved oxygen concentrations are primarily the result of the decomposition of organic matter in seafood processing wastes. While Iliuliuk Bay does not receive any direct 20 ------- discharge of processing wastes, wastes discharged within Dutch Harbor and at the entrance to Iliuliuk Bay from Iliuliuk Harbor by Eastpoint Seafoods and in the past by other processors within Iliuliuk Harbor, probably are transported to the deeper portions of Iliuliuk Bay. Station 20 located in quiescent waters on the south side of Expedition Island in the vicinity of the old subnarine base repair dry dock (Figure 4) yielded the lowest recorded dissolved oxygen value of 0.0 mg/1 during the 1976 study. Diving observations in this area confirmed the existence of extensive black decomposing sludge deposits. During the previous season (1975-1976) crab processing wastes had been discharged in this area which undoubtedly contributed to the formation of this sludge layer and asso- ciated depressed dissolved oxygen levels. Stations 23 through 29, located in the Iliuliuk Bay area, also showed depressed dissolved oxygen concentrations. These are located in the deeper portion of the bay (17 to 20 fathoms) and are on the Unalaska side (south) of a sill (7 to 8 fathoms) which restricts water movement in and out of Iliuliuk Bay and thus encourages the buildup of organic sediments from wastes discharged by the City of Unalaska, the processors within Iliuliuk Harbor (some domestic wastes), the M/V Eastpoint, and dischargers located in Dutch Harbor. Depressed oxygen levels were also observed in this area during the 1975 survey. Stations 32 through 36 are located within Dutch Harbor. Three pro- cessing facilities, the M/V Sea Alaska, M/V Sea Producer, and M/V Theresa Lee discharge process wastewaters into Dutch Harbor. Dissolved oxygen concentrations recorded at these stations during both 1975 and 1976 were also below the state standard of 6 mg/1. 21 ------- Nutrients Ammonia and total phosphorus concentrations obtained during the 1976 study for various depths during flood and ebb tide stages for water quality stations are presented in Tables 3 and 3A. Relatively low nutrient con- centrations were found in Captains Bay (1, 2, 4, and 7) and at stations used as control points (9, 16, and 17). Additionally, low concentrations were found at Stations 30 and 31, located on the seaward side of the sill in Iliuliuk Bay. Stations 18 and 19, located in a transitional zone between Captains Bay and Iliuliuk Harbor, showed a slight tendency towards increased nutrient concentrations. Stations 8 and 14, located in the vicinity of the outfalls on the west side of Amaknak Island, also showed slightly increased concentrations. Significantly higher levels of nutrient concentrations were found at Stations 22 through 29 (Iliuliuk Bay) and Stations 32 through 36 (Dutch Harbor). High levels of ammonia and total phosphorus were found to be localized in nature and attributable to the nutrients (both the solid and liquid por- tion of their waste streams) discharged to these waters from crab process- ing plants (Table 6), localized sludge deposits of new and old crab wastes, and domestic wastes discharged to the water from both the processing ves- sels and the City of Unalaska. There does not appear to be any indication that the observed high concentrations of nutrients in the fall are due to up-welling of nutrient-rich water from the deep offshore reaches of the Bering Sea. The control stations in marine waters are low in nutrients as are the freshwater streams (Table 6) which enter the study area. 22 ------- Bottom Sediments Analytical results of bottom sediment sample analyses are nresented in Tables 4 and 5. Samples obtained during 1975 and 1976 from Station 2 (Captains Bay) in the vicinity of the Pacific Pearl processing plant do not indicate recent organic waste deposits. Clean sand and gravel was found during 1975 and only 3.3 percent organic matter from the sample obtained in 1976 reflecting a Type I organic sediment classification (5) of "inorganic or aged, stabilized organic deposits". Relatively small amounts of crab processing wastes have been discharged to Captains Bay in this vicinity. During the 1974-1975 season, the M/V Royal Alaskan was moored between Stations 1 and 18 and discharged processing wastes at this location. A sediment sample from Station 18 shows evidence of organic deposits. Chem- ical analysis of the sample yielded an 11.6 percent volatile solids con- tent, 21.8 percent organic matter, and a chemical oxygen demand (COD) of 255 grams per kilogram (g/kg). Results of additional sediment samples obtained during the 1975 sur- vey indicate the same general locations of sludge deposits and organic sediments determined during the 1976 survey. Decomposing sludge with pieces of crab shells were found near the Royal Alaskan outfall which was discharging to Iliuliuk Harbor at that time. Evidence of past processing discharges to Iliuliuk Ilarbor is shown in the chemical analyses of bottom samples collected at Stations 21A, 21B, and 22A during the 1975 survey and at Station 20 during the 1976 survey. Sludge deposits were also found at stations located within Dutch Harbor. 23 ------- Analytical results of the 1976 bottom sediment samples (Table 5) obtained at Stations 1, 2, 4, 20, 21, 24, and 34 as well as results from the 1975 survey correlate well with the lowered dissolved oxygen obser- vations and locations of known waste discharge areas. Stations within Captains Bay (1, 2, and 4) show relatively low levels of organic matter in the sediments. Station 20, located in quiet waters where sludge beds were observed and where processing wastes were discharged in previous years, showed the highest levels of organic content, particularly percent organic matter. Stations 24 and 34 also had relatively high levels of COD, ammonia, volatile solids, and percent organic matter. It should be noted that, except for Station 2, a Type III classification"Nitrogenous, substantial nitrogen contribution, further stabilization likely" was found at all other sediment stations. Diving observations made in Dutch Harbor (Appendix A) confirmed the accumulation of seafood waste sludge deposits around the outfalls. Sedi- ment samples obtained from the Dutch Harbor stations (Table 5) indicate high organic content. Samples consisted of soft, foul-smelling sludge and supported primarily pollution-tolerant polychaete worms. Water current movement in Dutch Harbor is negligible as indicated by diving observations and current drogue observations shown on Figures 6 and 7. Waste solids discharged to this waterbody do not readily disperse. Decomposition of the accumulated wastes causes water quality degradation. 24 ------- REFERENCES 1. Rallinger, D.G. and G.D. McKee. "Chemical Characterization of Bottom Sediments." Journal of the Federal Water Pollution Control Federation, Vol. 43, No. 2, 1971. Pages 216-227. 2. Brickell, David C. and John J. Coering. "The Influence of Decomposing Salmon on Water Chemistry", University of Alaska, Institute of Hater Resources, Report IWR-12, College, Alaska, 1971. 3. State of Alaska, Department of Environmental Conservation, "Water Quality Standards", as revised October 1973. 4. Tide Tables 197 6 High and Low Water Predictions, West Coast of North and South America. 5. Bialek, Eugene L. "Handbook of Oceanographic Tables - Special Publi- cation No. 68", Marine Sciences Department, U.S. Naval Oceanographic Office, Washington, D.C., 1966. 427 pages. 25 ------- TABLE 1 Dissolved Oxygen Concentrations in ?liliigrains Per Lixer at Selected Sites and Depths in the Dutch Harbor Area (3) June 1968 Station Numbers Depth 1 21 24 27 28 30 0 7.9 6.8 8.0 8.1 7.9 7.9 5 8.0 7.2 8.0 8.1 8.3 8.0 10 7.7 7.4 7.8 3.1 7.5 7.6 15 6.9 7.3 7.8 7.4 7.3 20 7.1 25 4.3 4.8 5.5 30 6.8 40 5.6 ------- Station Time Depth^ (meters) ฐC Temp 0950 1 6.9 0952 10 6.4 0953 25 6.2 0956 (48) 4.0 1615 1 7.5 1617 10 7.2 1618 25 6.5 1620 (40) 5.4 1014 1 6.9 1015 10 6.4 1016 25 6.0 1017 (42) 5.6 1632 1 7.2 1633 10 6.6 1634 25 6.3 1637 (50) 4.6 1031- 1 7.4 1032 (10) 6.2 1647 1 8.0 1648 10 6.4 1649 (12) 6.3 1054 1 7.4 1055 10 7.0 1056 (12) 6.4 1655 1 8.1 1656 10 6.5 1657 (16) 6.3 TABLE 2 ANALYTICAL RESULTS : QUALITY SAMPLING STAT IONS DUTCH HARBOR , ALASKA OCTOBER 9 , 1975 Dissolved Ammonia Total Salinity Density Oxygen Nitrogen Phosphorus (ฐ/oo ) (at) mg/1 mg/1 mg/1 30.0 24.53 8.3 .03 .046 31-5 24.77 7.8 .04 .067 32.0 25.19 7.7 .06 .058 31.0 24.63 4.7 31.0 24.24 7.8 .04 .055 32.0 25.06 7.5 .05 .057 32.0 25.14 7.7 .04 .056 32.0 25.18 (6.3) 30.5 23.92 8.4 .03 .055 31.5 24.77 8.0 .05 .059 31.5 24.81 7.5 .02 .063 31.5 24.86 7.0 31.0 24.27 7.8 .02 .052 32.0 25.13 7.4 .05 .060 32.0 25.19 7.5 .05 .060 32.0 25.37 5.7 @ 42 25.5 19.94 8.7 .07 .052 31.5 24.79 7.4 .08 .065 24.0 18.70 9.2 .06 .055 32.0 25.17 7.4 . 06 .059 32.0 25.18 20.5 16.03 8.4 .08 .052 31.0 24.30 7.4 .09 .081 31.0 24.38 7.0 20.5 15.95 8.5 .04 .060 31.0 24.36 7.5 .08 .064 31.5 24.78 6.8 ------- TABLE Station 22 24 ho oo 27 35 Depthi/ ฐC Salinity Time (meters ) Temp (ฐ/oo ) 1104 1 6.9 28.0 1105 10 6.4 31.0 1106 (15) 6. 3 31.5 1709 1 7.2 28.0 1710 10 6.5 32.0 1711 (15) 6.3 32.0 1110 1 6.9 30.5 1111 10 6.3 31.5 1112 25 6.2 31.5 1115 (35) 6.0 27.0 1715 1 6.9 30.5 1716 10 6.3 32.0 1718 25 6.1 32.0 1720 (29) 6.0 32.0 1133 1 6.8 30.5 1134 10 6.5 31.5 1135 25 6.3 31.5 1137 (38) 5.6 31.5 1734 1 6.9 30.5 1735 10 6.3 31.0 1737 25 6.2 31.0 1738 (32) 5.8 31.0 1300 1 7.3 30.0 1302 10 6.5 31.5 1303 25 6.2 32.0 1305 (29) 6.1 32.0 1816 1 7.0 30.0 1817 10 6.4 31.0 1818 (25) 6.1 31.0 2 (cont.) Density (at) Dissolved Oxygen mg/1 Ammonia Nitrogen mg/1 Total Phosphorus mg/1 21.97 8.3 .04 .068 24.38 7.1 .15 .078 24.81 7.1 21.93 9.6 .18 .073 25.16 7.6 .14 .076 25.18 7.3 23.92 7.9 .08 .094 24.78 7.7 24.89 7.5 .18 .082 21.28 7.0 23.92 8.6 .06 .062 25.18 7.9 .12 .070 25.20 7.3 .20 .086 25.21 6.5 23.93 8.0 .10 .068 24.75 7.6 .12 .082 24.78 6.8 .10 .069 24.86 1.5 23.91 8.5 .09 .086 24.39 8.4 .08 .063 24.40 8.4 .10 .067 24.45 5.7 24.25 9.3 .05 .065 24.75 7.4 .17 .083 25.19 6.6 .31 .107 25.20 5.4 23.51 10.5 .020 .060 24.38 9.4 .160 .084 24.41 7.9 .150 .072 ------- TABLE 2 (cont.) Station Time Depthi/ (meters) ฐC Temp Salinity (ฐ/oo) Density (at) Dissolved Oxygen rag/1 Ammonia Nitrogen rag/1 Total Phosphorus mg/1 37 1331 1 7.1 30.5 23.89 9.3 . 06 .069 1333 10 6.2 32.0 25.19 6.5 .21 .091 1335 25 6.0 34.0 26.79 5.8 .20 .084 1336 (27) 5.8 31.0 4.2 1830 1 7.4 30.0 23.46 10.4 .05 .078 1831 10 6.2 32.0 25.19 6.9 .22 .094 1833 (25) 6.0 32.0 25.21 6.3 . 06 .051 (3.7)* 28 1147 1 6.8 30.0 23.54 8.4 .08 .067 1149 10 6.3 31.0 24.39 7.8 .10 .069 1150 25 6.2 31.5 24.79 8.4 .04 .055 1153 (35) 6.0 27.0 8.7 1746 1 6.6 31.0 24.38 8.4 .10 .067 1747 10 6.3 31.0 24.39 8.6 .04 .058 1748 25 6.1 32.0 25.20 8.7 .04 .054 1749 (35) 6.0 32.0 25.21 7.3 30 1235 1 7.0 30.5 23.90 8.0 .09 .064 1236 10 6.8 31.5 24.72 8.3 .03 .268 1237 (15) 6.3 31.5 24.78 8.6 .03 .026 1801 1 6.8 31.0 24.33 9.1 .06 .057 1802 10 6.3 32.0 25.18 9.1 .04 .052 1804 (12) 6.2 32.0 25.19 9.0 NOTE: Morning times were on ebbing tide. Afternoon times were on flooding tide. *This value obtained about 200 feet from Station #9 : in deeper water i/Depth to bottom may differ from the morning run to afternoon run because exact station location was not determined by use of radar. ------- TABLE 3 SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 19, 1976 -FLOODING TIDE >ฆ EBBING TIDE- Station JL/ ฐc Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 TP No. Time Depth temp (ฐ/oo) (at) mg/1 mg/1 mg/1 Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 rag/1 1 1325 1 6.1 23.6 18.67 12.2 <.01 .07 1720 1 6.2 20.5 16.25 12.4 <.01 . 02 10 6.2 32.8 25.82 10.4 <.01 .02 10 6.2 32.8 25.82 10.4 <.01 .08 25 6.1 33.2 26.14 9.5 <.01 .03 25 6.1 33.3 26.22 8.5 <.01 .04 50* 4.3 33.9 26.90 4.6 <.01 .08 46* 4.6 33.8 26.79 5.4 <ฆ01 .07 2 1251 1 6.1 22.2 17.51 12.2 <.01 .02 1700 1 6.1 14.0 11.03 13.0 .04 .03 10 6.2 32.7 25.74 10.4 <ฆ01 .02 10 6.2 32.7 25.74 10.3 < .01 .03 25 6.1 33.2 26.15 8.5 <.01 .04 25 6.2 33.2 26.13 8.6 .01 .06 43* 5.4 33.3 26.31 7.0 <.01 .06 30 6.0 33.3 26.23 8.3 .02 .08 3 1309 1 6.1 25.8 20.34 12.3 10 6.2 32.8 25.82 10.5 25 6.1 33.2 26.14 9.7 50 4.2 33.5 26.60 4.5 62* 3.5 33.4 26.60 3.3 4 1233 1 6.0 21.0 16.56 12.5 <.01 .01 1640 1 6.1 21.0 16.57 12.1 <.01 .01 10 6.2 32.7 25.74 10.6 <.01 .02 10 6.2 32.9 25.90 9.9 <.01 .03 25 6.0 33.2 26.15 9.2 <.01 .03 25 6.0 33.3 26.23 9.0 <01 .04 50 4.6 33.5 26.65 5.1 50 60 <.01 .10 60 3.8 33.6 26.48 3.9 <.01 .09 75 3.4 33.5 26.68 3.2 75 3.4 33.7 26.84 3.2 80* 3.1 33.3 26.55 3.1 80* 3.4 33.4 26.60 3.0 7 1208 1 6.1 26.6 20.97 12.7 <01 .01 1620 1 6.2 20.5 16.15 12.6 '.01 .01 10 6.2 32.6 25.67 10.9 <.01 .03 10 6.2 32.9 26.90 10.4 <.01 .03 25 6.0 33.1 26.39 9.6 <.01 .03 25 6.0 33.3 26.23 8.8 <01 .04 52 3.8 33.6 26.52 4.0 <.01 .09 60 3.6 33.6 26.74 3.7 <ฆ01 .09 75 3.5 33.3 26.52 3.6 75 3.5 33.5 26.68 3.4 100 3.2 33.3 26.54 2.8 10O 3.3 33.5 26.69 2.9 107 3.2 33.3 26.54 2.5 108 3.2 33.4 26.62 2.6 1/ Meters Depth to bottom ------- TABLE 3 (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 19, 1976 FLOODING TIDE EBBING TIDE tation ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. nh3 TP No. Time Depth Temp (ฐ/oo) (ot) mg/1 mg/l mg/l Time Depth Temp (ฐ/oo) (ot) mg/l mg/l mg/l 8 1150 1 6.2 21.5 16.94 12.5 <.01 .03 1605 1 6.2 25.2 19.84 12.0 <.01 .01 10 6.2 32.8 25.72 10.7 .03 .07 10 6.2 33.0 25.98 10.6 <.01 .05 25 5.8 33.3 26.27 9.4 <.01 .17 28* 5.8 33.6 26.50 9.0 <01 .15 9 1125 1 6.0 23.5 18.53 12.4 <.01 .06 1540 1 6.0 23.8 17.77 12.3 <.01 .04 10 6.1 32.9 25.91 10.7 <01 .03 10 6.2 33.2 26.13 10.5 <.01 .07 25 6.0 33.2 26.18 9.9 <.01 .03 25 5.8 33.5 26.42 9.5 <01 .43 44 5.7 33.4 26.36 9.2 <.01 .07 80* 5.7 33.7 26.59 8.5 <.01 .03 11 1105 1 6.1 28.2 22.21 12.0 Sta. 1 6.2 24.6 19.37 12.5 10 6.1 32.8 25.83 10.1 12 10 6.2 33.0 25.98 10.8 25 6.1 33.1 26.07 10.0 e 25 5.8 33.5 26.42 9.5 50* 5.7 33.4 26.73 8.8 1520 48* 5.7 33.6 26.51 8.9 13 1055 1 5.9 25.6 20.18 11.9 1515 1 6.2 20.5 16.15 12.8 10 6.2 32.7 25.74 10.8 10 6.2 33.1 26.06 10.7 16* 6.2 32.9 25.90 10.5 22* 5.8 33.5 26.42 9.3 14 1030 1 6.0 25.8 20.34 11.4 .02 .03 1502 1 6.4 20.1 15.82 12.5 <.01 .03 10 6.2 32.6 25.66 10.7 <01 .03 10 6.2 33.2 26.15 10.1 .02 .07 14* 6.2 32.8 25.82 10.2 .12 .05 14* 6.2 33.2 26.15 9.8 .04 .04 16 1010 1 6.1 31.5 24.89 11.6 <.01 .03 1450 1 6.3 30.3 23.84 12.0 <.01 .04 10 6.1 33.1 26.05 10.7 .03 .03 10 6.2 33.0 25.98 10.9 <.01 .02 15* 6.1 33.5 26.39 10.2 <.01 .03 15* 6.1 33.2 26.14 10.4 <.01 .03 17 1245 1 5.8 32.8 25.87 10.5 <01 .03 1725 1 5.9 32.0 25.23 10.4 <.01 .02 10 5.8 32.8 25.87 10.6 <.01 .02 10 5.8 32.8 25.87 10.3 <.01 .02 25 5.7 32.8 25.88 10.7 <.01 .02 25 5.7 32.8 25.88 10.1 <.01 .03 42* 5.5 32.8 25.90 9.0 <.01 .02 42* 5.6 32.8 25.89 9.1 <ฆ01 .02 ------- TABLE 3 (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) in 00 n T nr. TIDE DUTCH HARBOR, OCTOBER 19, ALASKA 1976 TIDE :ation ฐC r x*\s\JU xii vt Salinity Density D.O. nh3 TP ฐC Salinity Density D.O. nh3 TP No. Time Depth Temp (ฐ/oo) (at) rag/1 tng/1 mg/1 Time Depth Temp (ฐ / 00) (at) mg/1 mg/1 mg/1 IB 0930 1 5.7 27.6 21.75 11.4 <.01 .02 1535 1 6.0 25.4 20.02 11.7 <.01 .02 10 5.9 32.5 25.62 10.4 <.01 .03 10 5.9 32.4 20.56 10.2 .01 .08 25 5.7 32.8 25.88 8.7 .02 .05 25 5.6 32.8 25.89 7.6 .02 .05 26* 5.5 32.8 25.90 7.2 .01 .06 33* 5.5 32.8 25.90 6.8 .03 .08 19 0950 1 5.7 27.6 21.77 11.6 <.01 .01 1550 1 6.0 28.3 22.30 11.2 <.01 .01 10 5.7 32.5 25.61 9.8 .01 .02 10* 5.9 32.0 25.23 9.8 .03 .03 12* 5.8 32.5 25.63 9.7 .03 .09 12* 5.9 32.8 25.87 8.2 .03 .04 20 0915 1 5.7 27.0 21.30 10.6 .02 .02 1520 1 6.0 19.2 23.01 11.4 <01 .01 10 5.9 32.0 25.23 10.3 .08 .03 10* 5.9 32.4 25.55 9.6 .15 .05 24* 6.0 32.a 25.84 3.7 .46 .09 16* 5.9 32.8 25.37 2.1 2.0 .31 21 1005 1 5.6 28.7 22.65 11.5 <.01 .02 1551 1 5.9 23.3 18.38 11.3 <01 .02 10 6.8 32.4 25.43 10.4 .02 .03 10 5.8 32.0 25.24 9.6 .03 .03 16* 5.8 32.4 25.55 9.7 .05 .06 15* 5.8 32.4 25.56 9.2 .04 .05 22 1010 1 5.9 31.3 24.68 10.8 .01 .02 1555 1 6.0 32.0 25.21 10.3 <ฆ01 .02 8* 5.9 32.4 25.55 10.0 . 10 .22 10* 5.9 32.4 25.55 9.6 .19 .29 23 1015 1 5.8 28.7 22.63 11.1 <.01 .02 1600 1 5.9 30.9 24.36 10.5 10 5.8 32.8 25.87 10.4 .02 .03 10 5.8 32.4 25.56 9.8 25* 5.7 32.8 25.88 4.5 .46 .15 25 5.7 32.8 25.88 7.8 28 5.7 32.8 25.88 4.2 27* 5.7 32.8 25.88 5.0 24 1035 1 5.6 30.9 24.38 10.9 .03 .03 1610 1 5.9 31.6 24.91 10.8 <01 .03 10 5.7 32.4 25.57 10.4 .02 .03 10 5.8 32.4 25.56 10.2 .02 .07 25 5.8 32.8 25.88 5.8 .29 .08 25 5.7 32.8 25.58 8.9 .02 .08 28* 5.7 32.8 25.87 4.0 .50 .31 31* 5.7 32.8 25.58 4.1 .41 .14 ------- TABLE 3 (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 19, 1976 -FLOODING TIDE EBBING TIDE- Station ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 TP No. Tine Depth Temp (ฐ/o 0) Cot) mg/1 mg/1 mg/1 Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 mg/ 25 1050 1 5.8 32.4 25.56 10.7 <.01 .03 1620 1 6.0 30.6 24.10 10.7 10 5.8 32.8 25.87 9.8 .03 .03 10 5.9 32.8 25.86 10.1 25 5.8 32.8 25.87 6.0 .31 .08 25 5.9 32.8 25.86 8.4 30* 5.7 32.8 25.88 5.1 2.0 1.6 31* 5.7 32.8 25.86 5.8 26 1105 1 5.8 31.6 24.92 10.8 <.01 .02 1622 1 6.0 29.8 23.48 11.0 10 5.9 32.8 25.86 10.7 .02 .03 10 5.9 32.4 25.55 10.2 25 5.9 32.8 25.86 7.2 .32 .09 25 5.7 32.8 25.88 7.6 36* 5.6 32.8 25.89 4.3 .47 .14 37* 5.7 32.8 25.88 3.6 27 1120 1 5.9 31.6 24.91 10.9 <.01 .02 1630 1 6.0 30.6 24.10 10.9 <.01 .02 10 5.8 32.4 25.56 10.4 .02 .04 10 5.9 32.4 25.55 10.2 .03 .03 25 5.8 32.8 25.87 7.3 .30 .08 25 5.7 32.8 25.88 9.4 .31 .10 40* 5.7 32.8 25.88 4.5 .46 .14 37 5.7 32.0 25.23 4.2 .49 .19 28 1145 1 5.9 26.9 21.20 11.2 <.01 .02 1645 1 6.0 32.0 25.21 10.8 <.01 .02 10 5.8 32.8 25.87 10.4 .03 .05 10 5.8 32.4 25.55 10.3 <01 .03 25 5.7 32.8 25.88 9.9 <.01 .03 25 5.8 32.8 25.87 9.0 .25 .08 38* 5.6 32.8 25.89 4.5 2.3 1.3 36* 5.7 32.8 25.88 4.4 .45 .14 29 1155 1 5.8 32.4 25.56 11.0 <.01 .02 1652 1 6.0 31.6 24.89 10.8 10 5.7 32.4 25.57 10.7 .01 .03 10 5.8 32.4 25.56 10.4 25 5.6 32.8 25.89 9.5 .30 .09 25* 5.8 32.8 25.87 6.0 34* 5.6 32.8 25.89 4.2 .56 .22 33* 5.7 32.8 25.88 4.2 30 1210 1 5.9 32.0 25.23 10.9 <.01 .02 1658 1 6.0 32.0 25.21 10.7 <.01 .02 10 5.8 32.8 25.87 10.1 <.01 .02 10 5.9 32.4 25.55 10.5 <01 .02 25* 5.6 32.8 25.89 9.7 <.01 .03 25* 5.7 32.8 25.88 9.6 <.01 .03 ------- TABLE 3 (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 19, 1976 -FLOODING TIDE- -EBBING TIDE- u> tatlon ฐC Salinity Density D.O. NH3 TP ฐc Salinity Density D.O. NH3 TP No. Time Depth Temp (ฐ/oo) (crt) mg/1 mg/1 mg/1 Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 mg/1 31 1225 1 5.9 31.6 24.91 10.9 <01 .02 1710 1 5.9 31.3 24.68 10.7 10 5.7 32.4 25.56 10.6 <.01 .02 10 5.8 32.4 25.56 10.6 20* 5.6 32.8 25.89 9.4 <01 .03 20 5.6 32.8 25.89 9.8 32 1305 1 5.8 32.0 25.40 10.8 <.01. .02 1745 1 5.9 32.0 25.23 10.8 10 5.8 32.4 25.55 10.5 .03 .04 10 5.9 32.4 25.55 10.3 25 5.6 32.8 25.89 9.6 <01 .03 25 5.7 32.8 25.88 9.3 34* 5.6 32.8 25.89 3.9 .40 .13 33* 5.7 32.8 25.88 5.1 33 1325 1 5.8 32.0 25.24 10.8 <.01 .02 1750 1 6.0 31.3 24.65 11.0 10 5.8 32.4 25.55 10.5 .02 .03 10 5.8 32.4 25.56 10.0 25 5.7 32.8 25.98 6.7 .30 .09 25 5.8 32.8 25.87 7.6 30* 5.7 32.8 25.98 4.3 .40 .13 30* 5.7 32.8 25.88 4.1 34 1340 1 5.9 32.4 25.55 10.8 <.01 .03 1800 1 6.0 32.4 25.21 10.6 <.01 .03 10 5.8 32.4 25.56 10.2 .02 .04 10 5.8 32.4 25.56 9.6 . 04 .04 25 5.8 32.8 25.87 9.5 .15 .06 25* 5.7 32.8 25.88 7.0 .06 .04 36* 5.7 32.8 25.88 3.9 .41 .16 34* 5.7 32.8 25.88 5.1 .39 .16 35 1350 1 6.0 32.4 25.52 10.2 .03 .10 1810 1 6.1 31.6 24. B8 10.0 .01 .04 10 5.8 32.4 25.56 9.9 .03 .04 10 5.8 32.4 25.56 9.4 .06 .06 24* 5.8 32.8 25.87 8.0 3.8 1.3 24* 5.8 32.8 25.87 7.2 .20 .14 36 1352 I 5.9 32.4 25.55 10.9 <.01 .04 1820 1 6.0 32.4 25.21 10.7 10 5.8 32.4 25.56 10.6 .03 .04 10 5.7 32.8 25.88 9.9 25 5.7 32.8 25.88 7.0 .21 .07 25 5.7 32.8 25.88 8.5 37* 5.7 32.8 25.88 4.5 .41 .13 36* 5.6 32.8 25.89 3.9 37 1359 1 5.9 31.3 25.68 10.0 .04 .07 1830 1 6.0 32.4 25.21 10.4 .05 .06 10 5.8 31.6 24.92 9.3 .05 .04 10 5.8 32.8 25.87 9.1 .09 .05 16* 5.7 32.8 25.88 8.5 .20 .20 16* 5.7 32.8 25.88 7.6 .24 .11 ------- TABLE 3A SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 24, 1976 -FLOODING TIDE -EBBING TIDE U> Ui Station 1/ ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 No. Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 mg/1 Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 1 1330 1 5.7 31.6 24.93 10.3 <.01 .02 0905 1 5.5 28.3 22.37 10.5 <.01 10 5.6 32.4 25.58 9.8 <.01 .02 10 5.8 32.8 25.87 9.7 <.01 25. 5.6 32.8 25.89 8.7 .02 .05 25 5.7 32.8 25.88 8.7 .03 55* 4.2 32.8 26.04 3.8 .04 .06 47* 4.7 32.8 25.99 5.8 .01 2 1315 1 5.7 30.9 24.38 10.3 <.01 .02 0855 1 5.9 32.0 25.23 10.2 <01 10 5.7 32.8 25.88 8.9 <.01 .02 10 5.8 32.8 25.87 9.4 <.01 3 20 5.6 32.8 25.89 8.6 , 23 .08 20 5.8 32.8 25.87 8.5 .23 ~ TP mg/1 .02 .02 .05 .06 .02 .02 .08 1300 1245 1 10 25 50 60 - 1 10 25 50 75 100 107 5.8 31.3 24.69 11.0 <.01 .02 5.7 32.8 25.88 10.0 <.01 .02 5.6 32.8 25.89 8.7 <.01 .03 3.5 32.8 26.12 3.0 <.01 CO ! =2 1 5.6 30.6 24.16 10.7 <.01 .01 5.7 32.8 25.88 9.9 <.01 .02 5.7 32.8 25.88 8.6 <.01 .04 4.5 32.8 26.01 <.01 .07 3.3 32.8 26.15 2.3 _ 0845 0820 1 10 25 50 60 75 80 1 10 25 50 75 100 107 5.7 31.3 24.70 10.8 <.01 .02 5.8 32.8 25.87 10.0 <.01 .02 5.7 32.8 25.88 8.8 <01 .04 <.01 .10 3.9 32.8 26.08 3.2 :: 5.8 31.3 24.69 10.6 <.01 .02 5.8 32.8 25.87 9.9 <.01 .02 5.7 32.8 25.88 8.6 <.01 .03 4.7 32.8 25.99 <.01 .10 3.1 32.8 26.16 2.3 1/ Meters * Depth to bottom ------- TABLE 3A (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMHONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 24, 1976 -FLOODING TIDE EBBING TIDE- Station ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 TP No. Time Depth Temp (ฐ/oo) (ot) rag/1 rag/1 mg/1 Time Depth Temp (ฐ/oo) (ot) mg/1 mg/1 mg/1 8 1240 1 5.6 29.8 23.51 10.6 .01 .02 0810 1 5.7 31.6 24.93 10.5 <.01 .02 10 5.7 32.4 25.57 10.2 <.01 .03 10 5.8 32.8 25.87 10.0 <.01 .02 17 5.7 32.8 25.88 9.4 20 5.8 32.8 25.87 9.4 <.01 .04 9 11 -- ~ -- 13 -- -- 14 1225 1 5.6 30.9 25.38 10.7 <.01 .01 0800 1 5.8 32.0 25.24 10.6 <.01 .02 10 5.7 32.8 25.88 10.0 <.01 .03 10 5.6 32.8 25.89 9.7 <.01 .03 14* 5.7 32.8 25.88 9.1 .06 .04 16 5.6 32.8 25.89 9.3 <.01 .02 16 1220 1 5.7 31.3 24.70 10.2 <.01 .01 0745 1 5.7 31.6 24.93 10.7 <.01 .01 10 5.7 32.4 25.57 10.2 <.01 .02 10 5.8 32.8 25.87 10.1 <.01 .02 20* 5.7 32.8 25.88 9.5 <01 .03 20* 5.8 32.8 25.87 9.4 <.01 .02 17 1540 1 5.7 32.4 25.58 10.4 <01 .01 1120 1 5.7 32.4 25.57 10.3 <ฆ01 .01 10 5.7 32.4 25.58 10.3 <.01 .02 10 5.7 32.4 25.57 10.3 <.01 .01 25 5.7 32.8 25.88 10.0 <.01 .03 25 5.7 32.8 25.88 9.9 <.01 .02 44* 5.7 32.8 25.88 9.3 <.01 .04 42* 5.6 32.8 25.89 8.9 <.01 .04 ------- TABLE 3A (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 24, 1976 tation No. Time Depth ฐc Temp FLOODING Salinity (ฐ/oo) TIDE Density (at) D.O. mg/1 nh3 mg/1 TP mg/1 Time Depth ฐc Temp EBBING Salinity (ฐ/oo) TIDE Density (ot) D.O. mg/1 nh3 mg/1 TP mg/1 18 1340 1 10 25* 5.5 5.6 5.6 29.8 32.4 32.8 23.55 25.58 25.89 9.8 9.5 7.2 .02 <.01 .21 .01 .03 .09 0920 1 10* 25 5.9 5.8 5.6 32.0 32.8 32.8 25.23 25.87 25.89 9.6 9.3 7.4 .09 <.01 .07 .04 .03 .06 19 1345 1 10* 5.6 5.8 31.3 32.8 24.71 25.87 9.1 8.8 .05 <.01 .03 .03 0940 1 10* 5.9 5.8 28.7 32.8 22.63 25.87 9.2 8.7 .04 .01 .03 .03 20 1350 1 10 17* 6.0 5.7 5.6 31.3 32.8 32.8 24.65 25.88 25.89 8.1 6.3 3.9 .12 .21 .42 .04 .06 .24 0945 1 10 17* 5.9 5.8 5.8 29.8 32.8 32.8 23.48 25.87 25.87 8.3 7.0 0.0 .15 .18 1.9 .03 .05 .23 21 1400 1 10* 25 5.8 5.7 5.6 32.0 32.4 32.8 25.24 25.57 25.89 8.9 8.1 7.8 .08 .03 .12 .04 .04 .09 0955 2*0* 5.7 5.8 5.7 30.2 32.8 32.8 23.83 25.87 25.88 9.3 8.7 7.8 .04 .04 .09 .03 .04 .05 22 23 1410 1 10* 5.7 5.7 31.3 32.8 24.70 25.88 8.9 7.8 .06 .38 .11 .05 1005 i* 5.7 5.7 31.6 32.0 24.93 25.25 9.2 8.4 .06 .20 .04 .08 24 1420 1 5.7 31.6 24.93 9.6 .02 .02 1010 1 5.7 32.0 25.25 10.1 .02 .02 10 5.7 32.8 25.88 9.2 <.01 .03 10 5.7 32.4 25.57 9.7 <.01 .03 25 5.6 32.8 25.89 7.8 .22 .07 25 5.6 32.8 25.58 8.0 .15 .06 33* 5.6 32.8 25.89 3.7 .41 .13 32* 5.6 32.8 25.58 3.5 .42 .11 ------- TABLE 3A (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 24, 1976 -FLOODING TIDE EBBING TIDE- Station ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 TP No. Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 mg/1 Time Depth Temp (ฐ/oo) (at) mg/1 mg/1 mg/1 25 26 27 1430 1 5.7 30.6 24.14 10.0 .03 .03 1025 1 5.6 31.3 24.71 10.2 .01 .02 10 5.7 32.4 25.24 9.7 .02 .05 10 5.7 32.4 25.67 10.0 .01 .03 25 5.7 32.8 25.88 8.1 .15 .06 25 5.6 32.8 25.89 7.8 .10 .05 38* 5.7 32.8 25.88 3.7 .41 .13 39* 5.6 32.8 25.89 4.0 .40 .14 28 1440 1 5.6 30.6 24.15 10.0 .05 .02 1035 1 5.5 31.3 24.72 10.2 .01 .02 10 5.6 32.4 25.89 10.1 <.01 .04 10 5.7 32.4 24.57 10.1 .01 .03 25 5.6 32.8 25.89 8.0 .16 .07 25 5.6 32.8 25.89 7.6 .10 .05 38* 5.6 32.8 25.89 3.9 .39 .13 39* 5.6 32.8 25.89 3.8 .40 .14 29 30 1525 1 5.7 32.0 25.25 10.2 <.01 .02 1105 1 5.5 31.6 24.95 10.4 <.01 .02 10^ 5.8 32.4 25.56 10.3 <.01 .02 10 5.7 32.4 25.57 10.2 .10 .05 25+ 5.8 32.8 25.87 8.2 <.01 .02 25* 5.6 32.8 25.89 9.5 <.01 .03 ------- TABLE 3A (cont.) SALINITY/DENSITY/DISSOLVED OXYGEN/AMMONIA NITROGEN (NH3-N)/TOTAL PHOSPHORUS (TP) DUTCH HARBOR, ALASKA OCTOBER 24, 1976 -FLOODING TIDE EBBING TIDE- Station ฐC Salinity Density D.O. NH3 TP ฐC Salinity Density D.O. NH3 TP No. Time Depth Tenp (ฐ/oo) (ot) mg/1 mg/1 rag/1 Time Depth Temp (ฐ/oo) (ot) mg/1 rag/1 mg/1 31 32 33 u> VO 34 1415 1 5.6 31.3 24.71 10.2 .04 .02 1045 1 5.5 31.3 24.72 9.6 .03 .02 10 5.7 32.4 25.58 10.0 <.01 .02 10 5.7 32.4 25.57 10.0 <.01 .02 5.6 32.8 25.89 8.4 .13 .05 25 5.6 32.8 25.89 8.0 .13 .05 30* 5.6 32.8 25.89 3.9 .50 .65 35* 5.6 32.8 25.89 3.8 2.2 .90 35 1455 1 5.8 31.6 24.92 9.5 .04 .04 1050 1 5.6 31.3 24.71 9.6 .25 .05 10* 5.7 32.4 25.58 9.3 .01 .03 10 5. 7 32.0 25.26 9.3 .03 .05 24* 5.6 32.8 25.89 5.1 .47 .17 24* 5.7 32.8 25.88 5.5 .96 .23 36 37 1505 1 5.8 31.6 24.92 9.2 .10 .08 10.ป 5.8 32.8 25.87 8.6 .06 .05 20* 5.8 32.8 25.87 6.7 .18 .08 ------- TABLE 4 ANALYTICAL RESULTS OF BOTTOM SEDIMENT SAMPLES DUTCH HARBOR, ALASKA OCTOBER 9, 1975 o Station 2 IS 21a 2 Lb 21c 22a 22 35 37 37a 37b 30 Location Captain's Bay Captain's Bay Iliuliuk Harbor Iliuliuk Harbor Iliuliuk Harbor Iliuliuk Harbor Iliuliuk Bay Dutch Harbor Dutch Harbor Dutch Harbor Dutch Harbor Iliuliuk Bay Unalaska Bay Lab Number Clean 41293 41200 41206 41208 41204 41209 41201 41202 41205 41203 Clean 41207 Percent Volatile Solids Sand ?: Gravel 11.6 16.6 15.5 6.9 10.1 3.4 8.4 12.1 11.3 4.4 Sand r- Gravel 55.6 Percent Organic Matter 21.8 20.4 16.4 2.2 8.8 1.3 5.7 10.8 11.1 A.5 73.5 Chemical Oxygen Demand g/kg 255 240 194 25 103 16 103 126 128 52 866 ------- TABLE 5 ANALYTICAL RESULTS OF BOTTOM SEDIMENT SAMPLES DUTCH HARBOR, ALASKA OCTOBER 1976 Water Quality Station No. Location Date Tine Lab No. COD g/kg dry vt. Total Organic Nitrogen mgjg dry Total Kjeldahl Nitrogen mn/n dry Ammonia NH3 ng/ft dry 4 Captain's Bay 10/27/76 1105 44204 62.6 2.6 2.6 .054 2 Captain's Bay 10/27/76 1130 44202 39.0 1.3 1.4 .095 1 Captain's Bay 10/27/76 1137 44201 88.2 3.2 3.2 .034 20 Sub-Base 10/27/76 0940 44220 171.5 5.8 6.5 .72 21 Iliulluk Harbor 10/27/76 1150 44221 76.8 2.6 2.7 .10 24 Illuliuk Bay 10/27/76 1203 44224 107.4 4.2 4.5 .30 -P> ป-* 34 Dutch Harbor 10/27/76 1215 44234 117.6 3.7 4.0 .32 *Type 1 - Inorganic or aged, stabilised organic deposits. Type 2 - High carbon, little nitrogen contribution, slow oxygen demand. Type 3 - Nitrogenous, substantial nitrogen contribution, further stabilization likely. Type 4 - Actively decomposing sediments, high potential nitrogen release, and high oxygen demand. Percent Solids Volatile Solids Percent Percent Organic Matter Organic* Sediment Classification 33.4 9.3 5.4 3 63.4 4.8 3.3 1 38.1 8.1 7.3 3 27.7 13.8 14.4 3 44.9 6.9 6.5 3 20.3 11.0 8.9 3 17.0 11.8 10.0 3 ------- TABLE 6 ANALYTICAL RESULTS OF EFFLUENT AND STREAM SAMPLES Source of Sample Date Time Ammonia Nitrogen mg/1 Total Phosphorus mg/1 COD mg/1 Total Volatile Solids mg/1 Total Organic Carbon mg/1 Pan Alaska Seafoods 10/22/76 1425 290 82 8,100 2,300 3,500 M/V Eastpoint 10/23/76 0905 52 110 6,800 4,400 1,400 M/V Theresa Lee 10/23/76 1500 1.8 9.5 2,600 1,100 300 M/V Sea Alaska 10/23/76 1345 1.4 9.4 1,700 4,600 380 M/V Sea Producer 10/23/76 1425 3.9 22 2,800 2,100 850 M/V Whitney 10/24/76 1045 1.7 9.5 1,300 3,200 160 M/V Unisea 10/24/76 1245 12 7 2 3,700 3,200 1,000 M/V Vita & Viceroy 10/24/76 1345 83 47 3,000 1,000 700 Shaishnikof River 10/25/76 A o <.01 Iliuliuk River 10/25/76 r1 o V <.01 ------- OCTOBER 1976 Station No. Date 16 10/22/76 Time 0900 to 1410 Elapsed Drogue Time Depth 5.16 10 Direction of Travel IINE Out of Unalaska B. 14 10/22/76 1024 to 1515 4.84 14 10/22/76 1024 to 1526 5.03 10 SSW 8 10/22/76 1015 to 1522 5.15 8 10/22/76 1015 to 1507 4.90 10 NNW 10/20/76 0920 to 1450 5.5 10/20/76 10/22/76 7 10/22/76 Lost 25 Meter Drogue 1035 to 1447 1005 to 1425 4.19 4.34 NNW NNW TABLE 7 DUTCH HARBOR CURRENT STUDIES FLOOD TIDES Distance Course rraveled Yards Distances Yds DIR Velocity Knots Overall Velocity Start Location End Location 2300 2300 Zฐ 0.22 0.22 53-54-32 166-33-21 53-55-38 166-32-45 1605 780 825 250ฐ 332ฐ 0.14 0.19 0.16 53-53-23 116-32-54 53-53-45 166-33-43 360 250 110 220ฐ 287ฐ 0.05 0.02 0.035 53-53-23 166-32-54 53-53-19 166-33-51 2260 300 1960 250ฐ 345ฐ 0.05 0.43 0.24 53-52-55 166-33-25 53-53-49 166-33-51 1070 240 830 2529 340ฐ 0.04 0.20 0.12 53-52-55 166-32-25 53-53-19 166-33-51 940 940 242ฐ 0.09 0.09 53-53-22 166-35-08 53-53-49 166-35-07 3245 1100 920 1225 338ฐ 359ฐ 325ฐ 0.37 0.33 0.47 0.39 53-53-26 166-34-39 53-54-07 166-35-43 2765 1695 1070 335ฐ 320ฐ 0.29 0.38 0.34 53-52-28 166-34-13 53-53-44 166-34-53 ------- TABLE 7 (cont.) OCTOBER 1976 DUTCH HARBOR CURRENT STUDIES FLOOD TIDES Station No. Date Time Elapsed Time Drogue Depth Direction of Travel Distance Traveled Yards Course Distances Yds DIR Velocity Knots Overal] Velocity Start Location End Location 7 10/22/76 1005 S 290 170ฐ 0. ,05 53-52-28 53-52-19 to 4.08 25 into Captains 350 60 192ฐ 0. .02 0.35 166-34-13 166-34-14 1410 Bay 1 10/20/76 0945 53-51-43 Same to 5.25 1 E 100 100 275ฐ <. 01 <01 166-33-14 Area 1400 1 10/20/76 Same 5.25 25 Circular 500 Circled < , 01 <.01 11 19 10/23/76 1055 South 260 172ฐ 0. 08 53-52-38 53-52-49 to 4.75 1 then 1010 470 190ฐ 0. .43 166-32-18 166-32-12 1540 North 100 87ฐ 0. ,04 0.16 180 4ฐ 0, .07 19 10/23/76 1055 North 30 355ฐ 0. .02 53-52-38 53-52-22 to 4.55 10 then Return 710 240 8ฐ 0, ,12 166-32-18 166-32-15 1528 South 240 327ฐ 0. .09 200 222ฐ 0. .08 0.08 24 10/23/76 1110 140 0ฐ 0, .07 53-52-47 53-53-24 to 4.62 1 NE 1540 525 20ฐ 0, .26 166-31-22 166-31-01 1547 525 25ฐ 0, .20 350 305ฐ 0. .14 0.17 24 10/23/76 1110 75 300ฐ 0, .04 53-52-47 53-52-55 to 4.8 25 NW 510 140 300ฐ 0, .06 166-31-22 166-31-38 1556 120 342ฐ 0, .05 175 269ฐ 0. .07 0.06 34 10/23/76 1119 360 341ฐ 0. .13 53-53-52 53-54-14 to 4.8 1 N 800 150 341ฐ 0. .10 166-31-20 166-31-32 1606 180 320ฐ 0, .07 110 275ฐ 0. .04 0.09 ------- OCTOBER 1976 Station Elapsed Drogue Direction Ho. Date Tine Time Depth of Travel 34 10/23/76 1119 to 4.8 25 N 1604 30 10/23/76 1135 to 4.9 1 NNE 1631 30 10/23/76 1135 to 4.9 25 NNE 1625 4S Ln TABLE 7 (cont.) DUTCH HARBOR CURRENT STUDIES FLOOD TIDES Distance Traveled Yards Course Distances Yds DIR Velocity Knots Overall Velocity Start Location End Location 800 360 347ฐ 0.13 53-53-52 53-54-08 240 67ฐ 0.16 166-31-20 166-31-14 170 302ฐ 0.07 30 338ฐ <.01 0.09 375 47ฐ 0.19 53-54-12 53-54-56 2010 875 293ฐ 0.32 166-29-11 166-29-21 370 2ฐ 0.16 390 352ฐ 0.14 0.20 340 47ฐ 0.17 53-54-12 53-54-39 1450 440 304ฐ 0.17 166-29-11 166-29-05 490 335ฐ 0.21 180 86ฐ 0.06 0.15 ------- TABLE 7 (cont.) OCTOBER 1976 DUTCH HARBOR CURRENT STUDIES EBB TIDE Station No. 16 16A 16A Date Time General Elapsed Drogue Direction of Distance Course Time Depth Travel Traveled Distances Hours Meters (Magnetic) Yards Yds DIR Velocity Knots Overall Velocity Knots Start Location 10/22/76 @ 1043 1200 0 345ฐ 0.41 0.46 53-54-32 to 2.73 1 351ฐ N 2,500 1350 0 357ฐ 0.52 166-33-25 10/22/76 0 1337 10/26/76 @ 0915 177ฐ S 1125 0 193ฐ 0.49 53-53-32 to 4.05 1 Into Captains 2,800 650 0 166ฐ 0.27 0.49 166-33-27 10/26/76 0 1318 Bay from 1020 0 166ฐ 0.71 UnalasUa Bay 10/26/76 0915 to 3.75 25 170ฐ S 1,200 360 0 267ฐ 0.16 53-53-32 1300 Towards Mouth 360 0 168ฐ 0.15 0.16 166-33-27 of Captains Bay 470 0 135ฐ 0.16 10/26/76 0900 SE 320 @ 169ฐ 0.14 53-53-16 to 3.7 1 Towards 1,360 430 0 120ฐ 0.17 0.18 166-35-06 1242 Captains Bay 610 0 108ฐ 0.23 10/26/76 0900 S 770 320 0 169ฐ 0.14 53-53-16 to 3.78 10 230 0 171ฐ 0.10 0.10 166-35-06 1247 220 0 260ฐ 0.06 10/26/76 0845 to 3.35 1 S 4,300 1320 0 190ฐ 0.62 53-52-17 1206 1100 0 164ฐ 0.52 0.63 166-34-13 1880 0 210ฐ 0.76 10/26/76 0845 to 3.7 10 SSW 1,215 480 0 188ฐ 0.21 53-52-17 1227 110 0 160ฐ 0.05 0.16 166-34-13 625 0 190ฐ 0.21 End Location 53-55-50 166-33-13 53-52-12 166-33-54 53-53-11 166-33-32 53-52-48 166-34-24 53-53-01 166-35-14 53-50-29 166-35-44 53-51-43 166-34-34 ------- OCTOBER 1976 Station No. Date Time 10/26/76 0835 to 1152 Elapsed Drogue Tine Depth tlours Meters 3.22 General Direction of Travel (Magnetic) SW 10/26/76 0835-0930 1038-1326 ซ4 19 10/25/76 1035 to 3.45 1402 Circular 10 Clockwise Vicinity Blakely Ledge N-S 1 Move Through Iliuliuk Harbor and Back -C- 19 10/25/76 1037 to 1442 4.08 10 Circular Pattern Inside Harbor 24 24 10/25/76 0940 to 3.25 1255 10/25/76 0940 to 3.92 1335 10 SSE Towards Shore @ Head of Iliuliuk Bay Curving West 34 10/25/76 0952 to 1427 i.32 E-W Back & Forth Across Entrance to Dutch Harbor TABLE 7 (cont.) 'CH HARBOR CURRENT STUDIES EBB TIDE Distance Course Overall Traveled Distances Velocity Velocity Start End Yards Yds DIR Knots Knots Location Location 3,485 1225 212ฐ 0.54 53-51-46 53-50-39 700 1? 208ฐ 0.36 0.53 166-33-37 166-35-38 1560 ra 225ฐ 0.69 180 182ฐ 0.09 53-51-46 53-51-35 430 70 171ฐ 0.03 0.06 166-33-37 166-33-28 180 @ 148ฐ 0.05 140 @ 044ฐ 0.06 53-52-39 53-52-38 775 265 4ฐ 0.13 166-32-43 166-32-41 160 @ 189ฐ 0.11 0.11 50 @ 224ฐ 0.03 160 @ 183ฐ 0.12 Circular 200 Buoy H2 <0.01 <0.01 330 123ฐ 0.16 53-52-52 53-52-38 620 290 (3 134ฐ 0.12 0.14 166-31-22 166-31-04 225 @ 172ฐ 0.11 53-52-52 53-52-35 700 275 & 166ฐ 0.11 0.09 166-31-22 166-31-14 75 137ฐ 0.06 125 80ฐ 0.06 225 85ฐ 0.11 53-53-51 53-53-53 775 290 @ 66ฐ 0.11 0.09 166-30-56 166-30-57 160 @ 246ฐ 0.08 100 I? 314ฐ 0.06 ------- TABLE 7 (cont.) OCTOBER 1976 DUTCH HARBOR CURRENT STUDIES EBB TIDE General Elapsed Drogue Direction of Distance Course Overall Station Time Depth Travel Traveled Distances Velocity Velocity Start No. Date Time Hours Meters (Magnetic) Yards Yds DIR Knots Knots Location 34 10/25/76 0952 SE-NE 190 @ 130ฐ 0.09 53-53-51 to 3.88 10 (*~) 1,130 500 0 124ฐ 0.20 0.09 166-30-56 1342 (Note Above) 390 @ 323ฐ 0.20 50 0 67ฐ 0.03 125 0 17ฐ 0.10 30 10/25/76 1004 E-W 540 0 116ฐ 0.29 53-54-17 to 2.18 1 Back & Forth 1,140 600 0 83ฐ 0.27 0.28 166-29-27 1215 Across Entrance to Iliuliuk Bay 30 10/25/76 1004 NW 230 0 342ฐ 0.11 53-54-17 to 2.25 10 Out of 460 230 0 303ฐ 0.09 0.10 166-29-27 End Location 53-54-08 166-29-45 53-54-30 166-29-27 1219 Bay 4> 00 ------- OCTOBER 1976 PROCESSOR LOCATION A OUTFALL LOCATION UNALASKA BAY WHITNEY FIDALGO OUTFALL PAN ALASKA - ROYAL ALASKAN OUTFALL VITA - VICEROY OUTFALL UNIVERSAL OUTFALL ILIULIUK BAY CAPTAINS BAY 1. 2. 3. 4. 5. 6. 7. 8. 9. UHALASKA LAKE M/V SEA ALASKA M/V SEA PRODUCER M/V THERESA LEE PAN ALASKA M/V ROYAL ALASKAN M/V EASTPOINT WHITNEY FIDALGO SEAFOODS VITA FOOD PRODUCTS M/V VICEROY UNIVERSAL SEAFOODS PACIFIC PEARL SHA r SHNT.KOF RIVER NAUTICAL MTL1-S 49 FIGURE 2 ------- 50 FIGURE 3 ------- WHITNEY FIDALGO OUTFALL PAN ALASKA - ROYAL ALASKAN OUTFALL ฉ WATER QUALITY STATION A WASTE OUTFALL LOCATION 51 FIGURE 4 ------- ILIULIUK HARBOR DUTCH HARBOR AND I I INNER ILIULIUK BAY OUTER CAPTAINS BAY I | ILIULIUK BAY f~ A ^Kp y 50" 100- u Ci-i M U < UJ u hJ 'wO G o in UJ < erf UJ <3 U H IT. cc > > > ฃ BOTTOM PROFILE ALONG TRANSECT FROI1 HEAD OF CAPTAINS BAY THROUGH ILIULIUK HARBOR AND ILIULIUK BAY TO OUTER ILIULIUK BAY. APPROXIMATE LOCATIONS OF SEAFOOD PROCESSING WASTE OUTFALLS ARE SHOWN. FIGURE 5 ------- 53 FIGURE 6 ------- 54 FIGURE 7 ------- APPENDIX 55 ------- ' ------- ENVIRONMENTAL PROTECTION AGENCY OFFICE OF ENFORCEMENT WASTE DISPOSAL PRACTICES OF CRAB PROCESSORS AT UNALASKA AND AMAKNAK ISLANDS, ALASKA NATIONAL ENFORCEMENT INVESTIGATIONS CENTER DENVER, COLORADO AND REGION X, SEATTLE, WASHINGTON January 1977 57 ------- WASTE DISPOSAL PRACTICES OF CRAB PROCESSORS AT UNALASKA AND AMAKNAK ISLANDS, ALASKA In compliance with the National Pollution Discharge Elimination System (NPDES), provisions of the Federal Water Pollution Control Act, as amended, (33 U.S.C. + 1251 et. seg.; the Act) the Environmental Protection Agency, Region X authorized, in April 1975, the seafood processing facil- ities in the vicinity of Unalaska and Amaknak Islands to discharge seafood wastes into the adjacent receiving waters. The seafood processing operations in the vicinity of Unalaska and Amaknak Islands are classified under the NPDES permit system as a "remote" area. The waste treatment requirement for this classification is to grind and discharge either directly into adjacent waters or by cross-island piping into less active areas. It has been observed through recent investigations by the EPA that water quality problems associated with seafood processing are a direct function of receiving water conditions.* In areas with high tidal ranges and strong currents, waste materials can be rapidly dispersed. In more quiescent waters, accumulations of waste materials often result in sludge banks, shell piles, dissolved oxygen depressions, and associated aesthetic problems. The waters separating Unalaska and Amaknak Islands can be classified as comparatively quiescent; tidal range is 1.13 m and the tidal current in Dutch Harbor is inappreciable. In Iliuliuk Harbor the current velocity does not exceed 1 knot.** Therefore, it was anticipated that solid wastes (sludge and shell) would, in all probability, accumulate in the receiving waters adjacent to the seafood processors in these harbors. A study to determine the extent of water quality problems and to obtain information supporting effluent limitations in the NPDES permits for the seafood processing operations at Unalaska and Amaknak Islands, Alaska, was conducted by Region X and National Enforcement Investigations Center (NEIC) personnel from October 20-27, 1976. The objective of the study was to evaluate permit conditions prohibiting more than 7.6 cm (3 inches) accumulation of seafood wastes at a 30 meter (98 ft) radius of each crab processing plant outfall. Observations of bottom conditions were made by SCUBA divers at all crab processing plant outfalls. At each location a team of divers examined the dispersion patterns of crab waste by conducting a general underwater reconnaissance of the bottom in the vicinity of the discharge. * Evaluation of Waste Disposal Practices of Alaska Seafood Processor, EPA, NEIC-D - Region X. December 1974. ** US Coast Pilot #9, Pacific and Arctic Coasts, Seventh (1964) Edition, US Department of Commerce, Coast and Geodetic Survey. 58 ------- Pertinent data collected relating to the discharge area concerned the location, depth, and direction of the discharge pipe as well as the general bottom topography and current features likely to disperse the ground crab waste. Following this preliminary investigation, core samples of crab processing wastes were collected at points 30 meters from the discharge. Later these core samples were examined and photographed to verify the actual depth of waste deposits. (Figures To supplement the observations made within the waste discharge area, additional diving examinations were conducted around, and in some cases under, the processing plant operation to ascertain possible alterations in the bottom conditions. (Figures These investigations indicated the heavy build-up of crab waste deposits was caused by an apparent lack of bottom scouring or dispersion by tidal currents. Sludge deposits were observed in areas where crab wastes were discharged, ground or unground, in quiescent and relatively shallow water. These conclusions are supported by visual observations of the dispersion patterns and their depth by biologically trained EPA SCUBA divers. In summary, NPDES permit violations occurred at the discharges from the following seafood processing operations: M/V EASTPOINT, M/V UNISEA, M/V VICE ROY, and BARGE VITA I, M/V THERESA LEE, M/V ALASKA and M/V SEA PRODUCER. (Table Presented below is a brief evaluation of conditions found at each of the crab processing plants. 59 ------- NORTH PACIFIC OCEAN 60 ------- NAUTICAL MILES I I 1 O 1 2 Amaknak and Unalaska Islands Alaska - Aleutian Islands October 1976 61 ------- 03 NAUTICAL MILES I I I O 1 2 01 - EASTPOINT 02 - UNISEA 03 - PACIFIC PEARL 04 - VICEROY and VITA 05 - PAN ALASKA - ROYAL ALASKA 06 - WHITNEY FIDAL60 07 - THERESA LEE 08 SEA ALASKA - SEA PRODUCER Crab Processing Plants Amaknak and Unalaska Islands Alaska - Aleutian Islands October 1976 62 ------- Crab Plant Discharges Amaknak and Unalaska Islands Alaska Aleutian Islands October 1976 63 ------- M/V EASTPOINT AK-002025-7 This is a floating crab processor docked on the northeast shore of Iliuliuk Harbor just inside the east entrance channel. The discharge of waste material is through a lightweight flexible rubber metal hose unattached to the bottom. Consequently, the final discharge point is dependent on the direction and force of the tidal current or the discharge pressure. About 30 meters from the point of discharge on the inside of the entrance channel waste deposits range from 25 to 36 cm in depth at water depths of 13 meters. In a south and southeast direction there are only traces of crab waste at a water depth of 30 meters. From the point of discharge to mid-channel the bottom falls off sharply to depths of 30 meters. In a southeast direction from the point of land the water remains relatively shallow to Iliuliuk Reef and beyond. Because of the narrow tidal range in this area the effect of tidal currents is negligible in the channel. --r- Current Flow /ฆ*>&ฆ& tV-.-vV . ',*>> v % ~ . v ,.<ซซ j: * j r-yx v f-. - 'iVc1 f 25 to 36cm Deposit's ฆ v.v7,ปv.'. -^vv,-'- v v <*c.- 5cm' V'.' V.". ^ Traces ฆ A'. A'/ *.\r -'v.v> s*'} V i- rป xVis>-- 1 tV '/Vป ฆ30m Wate Water Depc^ '"v S Effluent Pipa 64 r = 30 meters (98') 7.5 cm = 3 inche5 ------- M/V UNI SEA AK-002526-7 This is a floating crab processor docked on the north shore of Expedi- tion Island in Iliuliuk Harbor. Ground crab waste from this operation is transported through a cross-island pipe and discharged at a depth of 17 meters in Unalaska Bay on the west side of Amaknak Island. The end of the pipe is secured to a tripod about 2 meters above the bottom. At four points at a radius of 30 meters from the discharge pipe in a north to southwest zone, waste accumulations exceeded the limits prescribed by the NPDES permit. At the north point the accumulation was 8 to 10 cm, at the northwest point it was 23 to 25 cm, at the western point, at a water depth of 23 meters, it was 38 cm, and at the southwest point it was 8 to 10 cm. Directly west of the discharge pipe the crab wastes form a mound 13 meters long, 7 meters wide, and 4 meters high. Only traces of crab waste settled inshore of the discharge. Current flow appeared to be along the shoreline in a north-south direction depending on the tidal phase. The extent of the accumulated waste and the definite westerly settling patten was a strong indication that the bottom currents were negligible. N Current Flow 38cm Deposits Water Deptl 32m fluent Pipe 65 r a 30 meters (98') 7.5 cm * 3 Inches ------- PACIFIC PEARL AK-000125-2 This is a stationary crab processing operation located on the west side of Unalaska Island on the shore of Captain's Bay. The end of the discharge pipe is in a depth of 18 meters at the face of the loading dock. Crab waste from this facility accumulated to a depth of 13 to 15 cm in the immediate vicinity of the discharge. Further offshore, in a northwest direction, the deposits were 5 to 8 cm at a water depth of 19 meters. No significant accumulations were found at the 30 meter radius of the discharge. Large crab sections were evident among the deposit which indicates that the grinder, at times, was working inefficiently. Captain's Bay lies in a north-south direction at Unalaska Island and like the surrounding terrain is very sharp sided. The current flow, although not appreciable at the time of these observations, were apparently of sufficient magnitude to keep the deeper portions of the bottom adjacent to the outfall clear of heavy accumualtions of crab waste. Surface currents follow the contour of the shoreline and flow in a north-south direction. Current Flow Effluent Pipe 66 r = 30 meters (98') 7.5 cm = 3 inches ------- M/V VICEROY AK-000068-0 BAKtit VITA-I AK-000069-8 These operations are floating crab processors docked along the north- west shores of Iliuliuk Harbor. Combined crab waste from these two facilities is transported through a cross-island pipe and discharged tato Unalaska Bay on the west side of Amaknak Island. The discharge pipe terminates about 2 meters above bottom. From shore the combined waste is carried in a steel pipe and then a plastic pipe which is ruptured about 23 meters from the end. Observations at the 30 meter radius of the pipe rupture indicated heavy accumulations of crab waste in a north to southwest section. A sample taken at the southwest point, in a water depth of 18 meters, showed a deposit of waste more than 14 cm in depth. In a southeast direction the deposits fluctuated around 1 cm. Bottom topography in this area can be classified as sloping gradually. Current flow appears to follow the shoreline in a north-south direction depending on the phase of the tide. The amount of accumulated waste and the southwest settling pattern was an indication that the bottom currents are negligible. Current Flow >14cm Deposit lcm Deposit uent Pipe 67 r = 30 meters (98') 7.5 cm = 3 inches ------- PAN ALASKA AK-000027-2 W/V O.S. RUYAL ALASKAN AK-002493-7 The Pan Alaska operation is a stationary facility loqated at the end of a peninsula on Unalaska Island in the southeast sector',of Iliuliuk Harbor. Royal Alaskan is a floating crab processor located in the same general area and docked at a pier running parallel to the entrance channel to Iliuliuk Harbor. Combined crab waste from these two processors is transported through a cross-island pipe and discharged at a depth of 12 meters into Unalaska Bay on the west side of Amaknak Island. An underwater rupture appears in the pipe about 15 meters before it reaches the point of discharge. Heavier deposits from this discharge were within the 30 meter radius of the discharge point. Only light traces of the more finely ground waste were evident in the outer reaches. However, at this outer edge there were noticeable quantities of dead and dying shellfish under this light layer of crab waste. (Figure Bottom topography in this area is of a steady sloping type. Current flow appears to be along the shoreline in a north-south direction depending on the phase of the tide. The volume of accumulated waste and its general dispersion around the outfall indicate^ negMglDle current forces. ป. Dead Shellfish Current Flow Discharge wr Light\traces Gills1 etc: jr\ Effluent Pipe 68 r = 30 meters (98') 7.5 cm = 3 Inchฎ5 ------- figure Dead and dying shellfish in the discharge area of the PAN ALASKA and M/V 0. S. ROYAL ALASKAN. 69 ------- WHITNEY FIDALGO AK-002618-2 This is a floating crab processing facility docked on the north shore of Iliuliuk Harbor. The resulting crab waste from the operation is trans- ported through a cross-island pipe and discharged at a depth of 13 meters into Unalaska Bay on the west side of Amaknak Island. Observations made by SCUBA divers along the bottom in the general area of crab waste settling showed a relatively clean situation. This was apparently a result of the infrequent operation of this processing operation. Bottom topography in this area is a steady sloping type. Current flow appeared to be in a north-south direction and the force is negligible. {Figure r Current Flow 5Fs:?f^rge 27 m water depth / / Effluent Pipe 70 r = 30 meters OS') 7.5 cm - 3 1"c ------- Figure A sea anemone being buried by ground crab waste. 71 ------- M/V THERESA LEE AK-000062-1 This is a floating crab processor docked at a pier along the northwest shore of Dutch Harbor on Amaknak Island. Crab waste from ithis facility is discharged into Dutch Harbor through a flexible pipe tied to the anchor cable at a depth of 12 meters. This method of securing the pipe causes a whiplash effect during periods of discharge. (Figure Heavy deposits of crab waste from this operation have accumulated throughout the general area. At a point southeast of the discharge, at the 30 meter radius, deposited waste reached an approximate depth of 1.2 meters. The water depth at this point is 30 meters. Extensive patches of foam were evident in the immediate area of the discharge during time of processing. (Figure The bottom topography is typical of the adjoining land terrain and as such falls of rapidly. The heavy accumulation of crab waste and the general shape of the harbor would suggest that current forces are insufficient to scour the wastes from the bottom. Current Flow Effluent Pipe ^Deposit 30m Water Depth t ฆ'*- V' *S!> VwSSCfS* <' ?. 4- 72 r a 30 meters (98') 7.5 cm - 3 inches ------- Figure Discharge pipe of the M/V THERESA LEE secured to the anchor chain. ------- Figure Core sample taken at a point 30 meters from the discharqe of the M/V THERESA LEE. Backboard is marked in inches. 74 ------- M/V SPA ALASKA AK-002257-8 M/V Si.A PRODUCER AK-002250-1 These floating crab processors are docked at a pier in the northern sector of Dutch Harbor on the eastern shore of Amaknak Island. The combined crab waste from these two facilities is discharged into Dutch Harbor through a single pipe at a depth of 23 meters. Extremely heavy deposits of crab waste from these processors surround this outfall. Divers observations indicated a conical mound of waste approximately 8 meters high and 12 meters wide at the base, tapering off to about 1 meter in depth at an eastern point of the 30 meter radius of the discharge. (Figure These processors are located in a dead-end pocket of Dutch Harbor where there is apparently no current of any magnitude available to disperse the crab waste. Consequently an extreme build-up is expected to continue. ------- mf, | SEA KA PRODUCE). "V?3/76 Figure Core sample taken at a point 30 meters from the M/V SEA ALASKA and M/V SEA PRODUCER discharge. Backboard is marked in inches. 76 ------- Table CRAB WASTE DISPOSAL METHODS Processor NPDES Permit Type Location Disposal Method Remarks NPDES Compliance M/V EASTPOINT M/V UNI SEA PACIFIC PEARL M/V VICEROY Barge VITA I AK-002025-7 Floater AK-002525-7 Floater AK-000125-2 Stationary AK-000063-0 AK-000069-8 Floaters IIiuliuk Hb. Amaknak Is. IIiuliuk Hb. Amaknak Is. Captain's Bay Unalaska Is. IIiuliuk Hb. Amaknak Is. Ground waste discharged into IIiuliuk Hb. through flexible hose. Ground waste discharged cross-island into Unalaska Bay. Ground and unground waste discharged into Captain's Bay. Combined ground waste discharged into Unalaska Bay. Pipe not secured to No bottom. Discharge point dependent on tical phase. Deposits round 4 meters No high, 13 meters long and 7 reters wide in front of pipe. Indications of inefficient Yes grinder. Ruptured plastic pipe No before discharge point. Heavy deposits north and west. PAN ALASKA M/V ROYAL ALASKAN AK-000027-2 AK-002493-7 Stationary Floater WHITNEY FIDALGO AK-002613-2 Floater M/V THERESA LEE AK-000062-1 Floater IIiuliuk Hb. Amaknak Is. IIiuliuk Hb. Amaknak Is. Dutch Hb. Amaknak Is. Combined ground waste discharged into Unalaska Bay. Ground waste discharged into Unalaska Bay. Ground waste discharged into Dutch Hb. Pipe secured to anchor chain at 12 meters. Ruptured pipe before Yes discharge point. Dead and dying shellfish around perimeter of deposits. This processor not in Yes operation. Bottom fairly clean. Heavy deposits of waste No in southeast direction of discharge. M/V SEA ALASKA AK-002257-8 Floaters Dutch Hb. M/V SEA PRODUCER AK-002250-1 Amaknak Is. Combined ground waste discharged into Dutch Hb. Heavy deposits of waste around discharge point and at 3C meter radius. No ------- 78 6 U. S. GOVERNMENT PRINTING OFFICE I977--797.838< 135 REGION ------- |