c/EPA Uniled States Environmental Protection Agency EP/V540/M5-89/003 April 1989 CIV SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION MMi Demonstration Bulletin In-Situ Vacuum Extraction Terra Vac, Inc. TECHNOLOGY DESCRIPTION: This in-situ vacuum extraction technology is a process for the removal and venting of volatile organic compounds (VOCs) from the vadose or unsaturated zone of soils. Often, these compounds can be removed from the vadose zone before they have a chance to con:aminate groundv/ater. In using this technology, subsurface organic contaminants are "vacuumed up" via a well, vapor/liquid separated, and then exposed to activated carbon before the "vapor" is allowed to be released into the atmosphere. The technology uses readily available components such as extraction and monitoring well(s), manifold piping, vapor/liquid separator, vacuum pump, and emission control equipment, such as activated carbon cansters. Once a contaminated area is completely defined, an extraction well (or wells) is installed (depending upon the extent of contamination) and is connected by piping :o a vapor/liquid separator device (Figure 1). A vacuum pump draws the subsurface contaminants through the well, separator device, and an activated carbon canister before discharge of the air streams is allowed to the atmosphere. Subsurface vacuum and soil vapor concentration are monitored via i/adose zone monitoring wells. The technology does not require highly trained operators or soil excavation, and it also is not depth limited. The technology works best when it is applied towards the remediation at s tes which are contaminated by liquids having high vapor pressures. However, the process is limited in applicability; diffusion rates through dense soils (such as compacted clays) are much lower than through sandy soils, and if activated carbon is used, then spent carbon must be processed. In addition, depending on the soil type and the depth to groundwater, the radius of influence of a single extraction well can range from tens to hundreds of feet. Typical contaminant recovery rates also range between 20 and 2500 pounds per day and are a function of volatility of the organic compound recovered. Therefore, the more volatile the organic compound, the faster the process works. The developer also states that the process is more cost effective where contaminated soils are predominantly above the water table, although systems have been designed for vapor and groundwater recovery. WASTE APPLICABILITY: This technology is applicable to organic compounds that are highly volatile at ambient temperatures in soils and groundwater. Vacuum Pump Skid Suck S«coiid*ry Activated Cartoo Canister 1 f Tank Truck Primary Activatr-d Carbon Canisters Figure 1. Process diagram for in-situ vacuur extraction. ------- Table 1. Reduction of Weighted Average TCE Levels in Soil TCE Concentrations (mg/kg) Extraction Well Pretreatment Posttreatment % Reduction e 1 33.98 - 29.31 13.74 2 3.38 2.36 30.18 3 6.89 6.30 8.56 4 96.10 4.19 95.64 e Monitoring Well I 1 1.10 0.34 69.09 2 14.75 8.98 39.12 e 3 227.31 84.50 62.83 4 0.87 1.05 - DEMONSTRATION RESULTS: The in-situ vacuum extraction demonstration occurred at the Groveland Wells Superfund Site in Groveland, Massachusetts. Four extraction wells were employed to pump contaminants to the process system. Four monitoring wells were utilized to measure the impact of treatment on site contamination. During the SITE demonstration, 1300 pounds of volatile organics, mainly TCE, were extracted during a 56-day operational period. The volatiles were removed from both highly permeable strata and low permability clays. The demonstration operated from December 1987 to April 1988. The process successfully removed: Trichloroethylene (all volatile compounds) Concentrations of volatile organic compounds in the soil gas were reduced 95% during the 56- day operational period. Contaminated water that is collected may require further treatment. Care must be taken during equipment design and set-up to correctly size the carbon collection canisters, insulate above-ground apparatus, and shield the vacuum blower. • The system runs with little operator attention. FOR FURTHER INFORMATION: EPA Project Manager: Mary K. Stinson U.S. EPA Risk Reduction Engineering Laboratory Woodbridge Avenue Edison, New Jersey 08837 201-321-6683 FTS: 340-6683 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 Official Business Penalty for Private Use $300 EPA/540/M5-89/003 ------- |