5, EPA United States Environmental Protection Agency Office of Solid Waste and Emergency Response Office of Research and Development Washington, DC 20460 January 1995 PROGRAM FACT SHEET Demonstration of the EnviroMetal Technologies, Inc. Metal-Enhanced Abiotic Degradation Technology This fact sheet will tell you about.. ¦ The SITE demonstration of the metal-enhanced abiotic degrada- tion technology at the SGL site. ¦ A public Visitors' Day for the SITE demonstration, which is scheduled for February 8, 1995. To attend the Visitors' Day, complete the enclosed registration form. Introduction The U.S. Environmental Protection Agency (EPA) identifies new methods for hazardous waste cleanup through its Superfund Innovative Technology Evaluation (SITE) Program. Created in 1986, this program demonstrates and evaluates innovative treatment technologies that may significantly reduce the toxicity, mobility, or volume of hazardous waste. The SITE Program also generates reliable performance and cost information on the technologies for use in evaluating cleanup alternatives for similarly contaminated sites. The technology proposed for demonstration is the metal-enhanced abiotic degradation technology, developed by EnviroMetal Technologies, Inc. (ETI), of Ontario, Canada. The purpose of the demonstration is to evaluate the technology's effectiveness in reducing concentrations of trichloroethene (TCE), tetrachloroethene (PCE), dichloroethene isomers, and vinyl chloride found in groundwater at the SGL Printed Circuits (SGL) site in Wayne, New Jersey. EPA's SITE Program Each year, EPA solicits proposals from private technology developers to demonstrate innovative technologies under the SITE Program. For each technology selected, EPA does the following, often with input from state and regional agencies: Identifies a site with wastes suitable for treatment Prepares a technology quality assurance project plan (QAPP) Notifies appropriate agencies for intergovernmental and community reviews Prepares a fact sheet for the public, describing the site and the technology Prepares the demonstration site Conducts and audits field sampling and laboratory analyses Organizes a Visitors' Day for the public to view the technology demonstration Evaluates technology performance Prepares an Innovative Technology Evaluation Report (ITER) summarizing the demonstration results, as well as a Technology Capsule, Demonstration Bulletin, and a videotape Public Involvement During this SITE demonstration, the public is invited to attend a Visitors' Day scheduled for February 8, 1995. The Visitors' Day will enable the community to become familiar with the SITE Program, the SGL site, and the ETI technology. To attend the Visitors' Day, complete the enclosed registration form. This form may be reproduced for multiple registrations. Site History SGL manufactured printed circuit boards at the SGL site in Wayne, New Jersey until 1984. After selling the property in 1984, SGL changed its name to SL Industries, which is 1 ------- Figure 1: Layout of the SGL site currently involved with remedial investigation activities and cleanup of the site under an economic cleanup responsibility act plan administered by the New Jersey Department of Environmental Protection (NJDEP). Figure 1 shows the layout of the SGL site. The site.covers about-3.5 acres and contains three buildings, one storage yard, and two former drum storage areas (not shown). Chemicals commonly used on site to manufacture printed circuit boards included TCE, PCE, and other chlorinated compounds. The areas behind buildings 1 and 3 were used for drum storage, and spills or leaks may have occurred in these areas. In addition, an underground heating oil tank located behind building 2 leaked fuel hydrocarbons into the subsurface. Groundwater samples collected from on-site monitoring wells show elevated levels of TCE and PCE. Based on available data, the highest concentration of TCE was reported at 23,000 micrograms per liter (jxg/L) in February 1992; the highest concentration of PCE was reported at 120,000 fig/L in July 1992. Technology Description The metal-enhanced abiotic degradation technology is designed to dechlorinate organic compounds in groundwater. Before construction of a full-scale in situ reactive wall, an aboveground treatment reactor is sometimes installed and operated to allow for measurement, control, modification, and optimization of design and operating parameters. ETI claims that the reactor simulates the full-scale treatment process at the pilot-scale level or it may be used as a treatment unit itself. This SITE demonstration will evaluate the treatment reactor's effectiveness at removing contaminants from groundwater at the SGL site. In full-scale use of this technology, an in situ permeable reactive wall is constructed by filling a trench with granular iron and inert materials. Groundwater either moves naturally through the wall or is directed through the wall by one or more impermeable sheet piles or slurry walls built outward at the side of the trench. ETI will demonstrate a pilot-scale, in situ treatment wall in spring 1995 at a site in upstate New York. Groundwater collection trenches and effluent injection wells support the aboveground treatment reactor. During the demonstration, groundwater is extracted from the overburden and shallow bedrock at the site by passive recovery techniques, using stone-filled collection trenches. Groundwater from two artesian wells is also fed into the collection trench. Then, groundwater flows through the collection trenches to a sump, where it is pumped to the aboveground treatment reactor. Groundwater from two deep wells on the north side of Sheffield Brook is also pumped to the reactor. The flow rate of groundwater pumped to the reactor is about 0.5 gallons per minute. Groundwater then passes through an influent line that contains an air eliminator, a 5-micron water filter, and a flow meter before entering the treatment reactor (see Figure 2). The air eliminator allows the passive release of excess air from the highest elevation of the influent line when atmospheric pressure is exceeded. The volume of air released is expected to be less than 100 cubic yards over the 3-month operation, and therefore will not be treated. 2 ------- Inside the reactor, about 5.5 feet of the reactive iron medium is placed on a 6-inch layer of well sand. The reactor drains through a collector line located in the well sand and then through the effluent line. The effluent line is plumbed so that about 1 foot of groundwater remains ponded above the reactive iron medium inside the reactor during the demonstration. Effluent will be returned to the aquifer through six on-site injection wells. Technology Demonstration The ETI demonstration began in November 1994 at the SGL site, and will be completed in February 1995. During this 3-month period, weekly samples will be collected from the following locations (see Figure 2): The influent sampling location (II), located in the influent line Five reactor sampling locations (R1 through R5), located within the reactor tank (R1 is located in the ponded water; R2 through R5 are located in the reactive medium.) • The effluent sampling location (E1), located in the effluent line Groundwater remains in the treatment reactor for about 1 day. After treatment, the groundwater is returned to the aquifer on site. During the demonstration, the ETI technology will treat about 65,000 gallons of water. Primary objectives for the demonstration are to determine: If the ETI technology reduces TCE and PCE concentrations in groundwater discharged from the treatment reactor to meet NJDEP discharge requirements Whether the treatment reactor's effectiveness at reducing TCE and PCE concentrations in ground- water is reduced over a 3-month operating period PROFILE Q -SampleLocation SOURCE: Modified from ETI 1903 Figure 2: Schematic drawing ofETI Metal-Enhanced Abiotic Degradation Technology to be Demonstrated MAILING LIST I If you would like to attend future SITE Visitors' Days or receive SITE publi- I cations, please complete this form, detach and mail to: | SITE Mailing List I do PRC Environmental Management, Inc. | 644 Linn Street, Suite 719 ¦ Cincinnati, Ohio 45203 I ~ Future SITE Visitors' Days ~ SITE Publications Name Company Address ' City State Zip J^Phone ( ) 3 ------- If the technology generates 1.1-dichloroethene, 1.2-dichloroethene isomers, chloroethene, 1,1-dichloroethane, 1,2-dichloroethane, and chloroethane as by-products Secondary objectives for the demonstration are to determine: The degradation rate of TCE and PCE in groundwater as it passes through the treatment reactor If the technology reduces contaminants otherthan TCE and PCE to meet NJDEP discharge requirements Geochemical changes in groundwater as it moves through the reactive media Operating and design parameters Treatment reactor air emissions for TCE and PCE EPA has prepared a detailed QAPP outlining methods and procedures for testing and evaluating the technology. When the demonstration is complete, the findings will be compiled and analyzed in an ITER, Technology Capsule, and Demonstration Bulletin. These documents will be used to evaluate alternatives for cleaning up sites with similar wastes across the country. Additional Information Questions or comments about the proposed demonstration or the SITE Program should be directed to: U.S. Environmental Protection Agency Dr. Chien Chen SITE Project Manager Risk Reduction Engineering Laboratory U.S. Environmental Protection Agency 2890 Woodbridge Avenue Building 10, MS-104 Edison, NJ 08837-3679 908-906-6985 Questions about the technology should be directed to: EnviroMetal Technologies, Inc. John Vogan EnviroMetal Technologies, Inc. 42 Arrow Road Guelph, Ontario, Canada N1K 1S6 519-824-0432 Questions about the SGL site should be directed to: SL Industries, Inc. Ted Taubeneck SL Industries, Inc. 520 Fellowship Road, Suite 306-C Mt. Laurel, NJ 08054 609-727-1500, ext. 210 5EPA U.S. Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, Ohio 45268 Attention: Chien Chen Photocopied on Recycled Paper ------- |