i Technology Support Center for Monitoring and Site Characterization / O J*™*-* ~chnolo^y a * o JMppWt . •» £- rroj«c( £ \ jF Of, Oaf®* ------- 5 5 7 8 10 11 12 14 14 16 18 20 21 22 23 23 25 27 28 30 32 34 34 36 37 38 39 39 40 41 43 44 44 46 47 47 49 49 51 52 53 55 57 59 60 60 Table of Contents Army Materials Technology Laboratory (AMTL) GE Housatonic •. Camp Edwards/Otis Air Force Base/MMR Dover Municipal Landfill Superfund Site - Statistical Advice Newport Naval ETC - Statistical Advice Olin Chemical Caldwell Trucking Chemical Leaman Tank Lines, Inc Hudson River PCBs Middlesex Sampling Plant Peter Cooper Corporation, Gowanda Site Shenandoah Road Groundwater Langley Air Force Base Occidental Chemical Ohio River Park Quantico, Marine Corps Combat and Development Command Sharon Steel Valmont TCE Site Distler Brickyard Mallory Capacitor Nocatee Hull Creosote Site ASARCO El Paso Lead Site Mountain Creek Lake Sediment Background Analysis Sol Lynn Industrial Transformer Texarkana ASARCO Lead Site Eagle-Picher Site .. Eureka Mills Aerojet General Corp Hayden Property #2, etc. (Region 9 Data Audits) McClellan Air Force Base Motorola PalosVerdes Shelf Site Phoenix 19th Ave Landfill Purity Oil - Audit of Analytical Data from EMAX Laboratories Camp Bonneville (UXO) ------- Superfund Short-Term Requests 62 Short-term Support - Provided by ESD Federal Staff 67 Issue Papers/Software 68 Miscellaneous Support 69 Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM) 69 Active Sites Funding History FY99 - FY03 70 ------- Technical Support Center Monitoring and Site Characterization Office of Research and Development National Exposure Research Laboratory Environmental Sciences Division, Las Vegas, NV Introduction: The United States Environmental Protection Agency's Office of Solid Waste and Emergency Response (OSWER), Regional Waste Management Offices, and the Office of Research and Development (ORD) established the Technical Support Project (TSP) in 1987 to provide technical assistance to Regional Project Managers, Corrective Action Staff, and On-Scene Coordinators. The Project consists of a network of Regional Forums and specialized Technical Support Centers (TSC) located in ORD and the Office of Radiation Programs (ORP) laboratories, and OSWER's Environmental Response Team. The objectives of the TSP are to network with other EPA programs and other Federal agencies. There are five Technical Support Centers, in five laboratories, operated by ORD. Each TSC is dedicated to serving the EPA by supplying high-quality, quick-response, technical support services when the technical requirements are beyond the Region's capability. The Environmental Sciences Division in Las Vegas has a very active TSC which provides the following specialized support: • Site characterization technologies such as field-portable X-ray fluorescence • Soil-gas Measurement • Geophysics • Special Analytical Services • Quality Assurance • GIS and data interpretation • Geostatistics, Statistical Design • Chemical Analysis • Site Characterization in Support of Bioremediation This document presents, by Region and Superfund Site, progress during the first three quarters of FY03 of the Environmental Sciences Division-Las Vegas, Technical Support Center for Monitoring and Site Characterization. During this quarter support was initiated at 8 new sites: Olin Chemical, Purity Oil, ASARCO-E1 Paso, Dover Municipal Landfill, Newport Naval, Middlesex Sampling, Peter Cooper Corporation Site, and the Palos Verdes Shelf site. The total Superfund resources expended in support of all ten Regions for this period was $103,000. Expenditures to date for FY03 were $373,768. A summary of the funding history for sites currently supported by the TSC from FY99 to FY03 is shown in the table at the end of this report. In addition, the TSC continued to support the distribution and use of a software package called ProUCL that is identified in an OSWER Directive and is recommended for use when calculating the Upper Confidence Limits needed for estimating the Exposure Point Concentration. The TSC 3 ------- also provides short-term (less than 8 hours) support to the Regions. Most of this support has been related to interpretation of the statistical outputs from ProUCL and general statistical support on determining the appropriate number of samples at a site and the statistics involved in comparing site samples of Contaminants of Concern with appropriate background samples for these same contaminants. The total expended for this area of support through the 3rd quarter is $7,350. The Office of Superfund Remediation and Technology Innovation (OSRTI) has also provided the TSC funding to functionally and technically upgrade the software package ProUCL. The status of this effort is described in the Issue Paper/Software section of this report. The total expended for the upgrade of ProUCL through the 3rd quarter is $22,710. 4 ------- Region 1 Major TSC technical support activities (>$1,000) in Region 1 during the first three quarters of FY03 are summarized on the following pages. No minor technical support activities (<$ 1,000) occurred in the Region during this quarter. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Army Materials Technology Laboratory (AMTL) Site Location: Watertown, MA Site Background: The U.S. Army initiated investigations into the nature and extent of site contamination in 1991 and 1992. A Record of Decision (ROD) for an area known as Area I was signed in June 1996. This ROD called for removal of contaminated soils and off site disposal. This action was completed in August 1996. A second ROD addressing contaminated soil of the remainder of the site was signed in September 1996. This ROD indicated that the groundwater beneath the site was not a media of concern. This ROD also selected soil excavation and off site disposal as the remediation action. Soil excavation on 36.5 acres of the facility has been completed. Soil excavation within the area known as River Park was completed in September 2001. Institutional controls will be developed and implemented for the River Park parcel prior to transfer of this parcel, which were expected to occur in July 2002. The 36.5 acre parcel where remediation has been completed was transferred from the Army to the Watertown Arsenal Redevelopment Corporation and the Town of Watertown in August 1998. A remedial investigation of the Charles River OU is ongoing. The 36.5 acre parcel that has been cleaned was deleted from the National Priorities List (NPL) in November 1999. Requested Technical Support: The Regional RPM requested that the ESD-LV TSC provide assistance in the statistical review of the Army's sampling and analysis plan for the subject site as part of the Baseline Ecological Risk Assessment (BERA). The sampling plan includes sediment sampling and analysis along the Charles River. Requested by: Kymberlee Keckler (617) 918-1345; Cornell Rosiu (617) 918-1385 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Support: TSC work on this site was initiated late in the fourth quarter so there is no previous progress. Summary of Activities During the First Quarter FY03: During this quarter the TSC commented on the statistical approaches proposed by the Army on the AMTL Superfiind site and provided a report titled: "Review of the Proposed Statistical Hypotheses Testing Approach for the Army Materials Testing Laboratory Superfiind Site in Watertown, MA." The TSC also delivered a report titled "A Review of Army's Sample Size Determination and Power Analysis Approach of Army Materials Testing Laboratory (AMTL) Site" to the Region. In December 2002, the TSC participated in a conference call with the Region and the Army to review our comments to their proposed approach and their response to them. 5 ------- Summary of Activities During the Second Quarter FY03: During this quarter the TSC participated in two conference calls to determine the number of samples to adequately address the power analysis for upstream, downstream, and adjacent areas for the AMTL Superfund Site (Charles River Baseline Ecological Risk Assessment Study). Participants included the TSC, Navy, EPA Region 1, and ENSR (consultant for the Navy) personnel. In the first conference call EPA comments and Navy's proposed approach (using Background Test Form 1 or Test Form 2 as alternative to Navy's two-tier approach) were discussed. In the second conference call, it was decided that the Navy would use Background Test Form 2 (instead of a two-tier approach used originally) to perform all the hypotheses testing to compare the upstream and downstream (and areas adjacent to the AMTL site) populations. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 6 ------- • Project Title: GE Housatonic Site Location: Housatonic River, Pittsfield, MA Site Background: The Housatonic River has been contaminated with PCBs from past GE operation and includes much of the River on its way to Long Island Sound. Substantial progress has been made over the past year on the cleanup of the Housatonic River. Much of the focus has been on removing PCB-contaminated river sediments and bank soils from the upper /4-mile reach of the Housatonic River in Pittsfield, MA. As of 2001, more than 10,700 cubic yards of contaminated river sediments and bank soils have been removed. The upper V2 mile cleanup is scheduled to be done by March 2002. Requested Technical Support: The Regional RPM requested that the ESD-LV TSC provide assistance in reviewing the statistical and data assessment procedures and methods that are being utilized by the PRP's to assess site data. Primary pollutants of concern are PCBs. Requested by: Margaret McDonough (617) 918-1276 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Technical Support: During FY02 a number of site documents were reviewed by the TSC and documented in a report titled "Review of Alternative Methods Proposed by GE for Calculating the Exposure Point Concentrations for the Housatonic River Site, Pittsfield, MA." Summary of Activities During the First Quarter FY03: During this quarter the TSC provided the Region a review of the statistical approaches used to compute the EPC terms for the Human Health and Risk Assessment (HHRA) for the Housatonic/GE River Site - Rest of River. The TSC also participated in a conference call with the Region and the PRP representatives to discuss the statistical portions of the HHRA. Summary of Activities During the Second Quarter FY03: During this period the TSC provided review comments on the statistical methods used for calculating the exposure point concentrations for the Housatonic River Site, Pittsfield Massachusetts. We also participated in a peer reviewers' conference call. Topics discussed included the use statistical of approaches as described in the Direct Contact Human Health Risk Assessment Study, GE/ Housatonic River Site. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 7 ------- • Project Title: Camp Edwards/Otis Air Force Base/MMR Site Location: Military Reservation, Cape Cod, MA Site Background: The Otis Air National Guard Base (NGB) and Camp Edwards cover approximately 3,900 acres on a 22,000-acre parcel of land, today known as the Massachusetts Military Reservation (MMR). There are three locations where the TSC is providing support: Landfill, Chemical Spill Area, and North Impact Area. In 1984, the U. S. Geological Survey detected contaminants in the monitoring wells down gradient of the plant. In 1983 and 1984, the Air Force detected volatile organic compounds (VOCs) in on-site monitoring wells near the Base Landfill and Current Fire Training Area. Monitoring by the Air National Guard and the State Department of Environmental Quality has detected VOCs in more than 200 private wells. Requested Technical Support: The Regional RPM requested that the ESD-LV TSC provide assistance in evaluating the feasibility of implementing natural attenuation as the remedial remedy for groundwater contamination at this site and to assist in the statistical evaluation of supplemental data. Task 1, Assessment of Natural Attenuation Requested by: Mike Jasinski (617) 918-1352, Paul Marchessault(617) 918-1388 T. Borci (617) 918- 1358 Lead Scientist: Bob Starr, ENEEL (208) 526-0174, Jeff Sondrup, ENEEL (208)526-8396, Art Rood, INEEL (208)526-1678 Task 2, Statistical Review Draft Supplemental Background Investigation Report Requested by: Sarah Levinson (617) 918-1380 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Support: Task 1, Assessment of Natural Attenuation. During the previous FYs the TSC provided a series of documents that described a groundwater remediation program at the INEEL Test Area North facility. The TSC reviewed the addendum to the focused feasibility study for Landfill-1 and participated in a number of conferences calls and meetings. The RPM provided the TSC with extraction/treatment system data for review. The TSC received a request to assist in the establishment of conservative soil concentration for explosive residues and other contaminants based on leaching to groundwater. An evaluation of the SESOIL Model was completed. In addition, a data report titled "Soil Action Levels for Massachusetts Military Reserve Northern Impact Area" was provided to the Region. The TSC was requested to review DoD's site specific fate and transport measurement Task 2000. The TSC completed a review of the modeling portion of the RI for the chemical spill-19 (CS-19) area. The TSC calculated some additional soil screening concentrations that were provided to the Region. TSC reviewed "Contaminant of Concern Identification Demolition Area 1" and the "Draft Modeling Strategy for the Camp Edwards Impact Area Groundwater Quality Study." The TSC responded to a request dealing with a fate and transport model and attenuation factors and provided the report titled "Contaminant of Concern Identification for Demolition Area 1 Soil Operable Unit of the Camp Edwards Impact Area, Massachusetts Military Reservation, Cape Cod, MA." In August 2002 the Region requested a second GWSCREEN calculation of the RDX soil clean-up levels. 8 ------- Task 2, Statistical Assessment of Background Data. During FY02, the TSC provided the Region a report titled "Review of the Draft Supplemental Background Investigation Report Camp Edwards Impact Area Groundwater Quality Study Massachusetts Military Reservation (MMR) Cape Cod, Massachusetts." Summary of Activities During the First Quarter FY03: Task 1, Assessment of Natural Attenuation. During this quarter the TSC provided the Region a set of independent calculations of RDX soil cleanup levels for the CS-10 site in a report titled "Calculation of RDX Soil Cleanup Levels for CS- 19 Site at the Massachusetts Military Reservation Using GSSCREEN." Task 2, Statistical Assessment of Background Data. During this quarter the TSC provided a report titled "Review of Responses (Dated 8-15-02) to EPA Comments (6/19/02) on the Draft Supplemental Background Investigation Report Camp Edwards Impact Area Groundwater Quality Study Massachusetts Military Reservation (MMR) Cape Cod, Massachusetts." Summary of Activities During the Second Quarter FY03: Task 1, Assessment of Natural Attenuation. No activity during this period. Task 2, Statistical Assessment of Background Data. During this quarter the TSC addressed a question posed by EPA representative regarding the analysis conducted for the site. Summary of Activities During the Third Quarter FY03: Task 1, Assessment of Natural Attenuation. There was minor follow-up activity on this task between the Region and the INEEL scientists related to interpretation of the model results. Task 2, Statistical Assessment of Background Data. No activity during this quarter. 9 ------- • Project Title: Dover Municipal Landfill Superfund Site - Statistical Advice Site Location: Dover, NH Site Background: For background data on this site, see: http://yosemite.epa.gov/rl/npl_pad.nsf/f52fa5c31fa8f5c885256adc0050b631/04BBF2F265D9290085 25690D00449687?OpenDocument. Requested Technical Support: RPM needs advice as to the application of Mann-Kendall statistics in evaluating trends in ground water contaminants. In particular, he needs to know if Mann-Kendall is appropriate for the data? Is a 90% CI appropriate? Was the method applied correctly in this case? What are the implications of their assumptions? Requested by: Darryl Luce, Region 1, 617 918-1336 Lead Scientist: Anita Singh, Lockheed Martin Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Third Quarter FY03: Mr. D. Luce of EPA Region 1 requested the assistance of the TSC in reviewing the statistical approaches used to perform trend analyses to evaluate the ground water quality at the Dover Municipal Landfill. A letter report summarizing review comments on the statistical approaches used to determine trends in arsenic and various VOCs in 41 groundwater monitoring wells within the vicinity of the Dover Landfill was developed and submitted to the Region. 10 ------- • Project Title: Newport Naval ETC - Statistical Advice Site Location: Newport, RI Site Background: See: http://yosemite.epa.gov/rl/npl_pad.nsf/f52fa5c31fa8f5c885256adc0050b631/A48C071B6A314ElC8 525691F0063 F6DD?OpenDocuraent Requested Technical Support: Review the statistical portion of the Navy's proposed sampling plan for determining background concentrations of compounds of potential concern to ascertain consistency with EPA's 2002 guidance on determining background concentrations. Requested by: Chau Vu, Region 1,617 918-1446 Lead Scientist: Anita Singh, Lockheed Martin Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Third Quarter FY03: The TSC reviewed the statistical approaches proposed by the Navy in their Work Plan for background soil investigation, NUWC Disposal Area, SA-08, Naval Station Newport, Rhode Island. A letter report summarizing the review comments on the statistical approaches proposed in Navy's Work Plan was submitted to the Region. 11 ------- • Project Title: Olin Chemical Site Location: Wilmington, MA Site Background: The Olin site in Wilmington, Massachusetts, is a former manufacturing facility for chemicals used in the rubber and plastics industry. There are many chemicals that were used during the 30+ years of operation, and wastewater for most of the operating history was discharged to unlined lagoons on the property. As a result, there is a significant groundwater plume which has migrated into the water supply aquifer for the Town of Wilmington. Requested Technical Support: The technical support requested is for help in identifying which chemicals formerly used and possibly discharged on-site should be included in the list of "contaminants of concern". Many of these chemicals are not on Hazardous Substance Lists, so the Massachusetts Department of Environmental Protection (MA DEP) has less familiarity with them. Moreover, we request technical support in identifying the proper analytical methods for assessing the presence of the recommended "contaminants of concern". Requested by: Steve Mangion, Region 1 HSTL 617 918-1452 State Contacts: Stephen M. Johnson, Chief, Site Management Section, MA DEP Tel: 978-661-7710 (direct) Fax: 978-661-7615 Email: Stephen.iohnson@state.ma.us and Chris Pyottof MA DEP Tel: 978-661-7739 Fax: 978-661-7615 Email: christopher.pvott@state.ma.us Lead Scientist: Tim Ehli, Lockheed Martin, Russ Plumb, Lockheed Martin, Wayne Sovocooi, NERL, ESD, Andy Grange, NERL, ESD. Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Third Quarter FY03: During this quarter a request was received from EPA Region 1 to review monitoring data from the Olin Chemical facility in Massachusetts and provide comments on the Chemicals of Concern (COC) list for the site. An alternative approach was suggested and accepted to identify the Contaminants of Concern based on the reported concentrations for each contaminant, the action limit for each contaminant, and the detection limit of the analytical method that was used. A report outlining this approach and other review comments was submitted to Region 1. The Olin contaminants have created a dense, inorganic ground-water plume. Because of the unique 12 ------- nature of the plume and its effect on method detection limits, it was also suggested that the COC assessment be repeated for each distinctive layer (dense layer, transition zone, and ground water). TSC is awaiting receipt of the Olin data that has been segregated into these three distinctive zones. The COC assessment will be repeated with each subset of the site data. The RPM also asked whether the high concentrations in the dense inorganic layer would favor the creation of other Tentatively Identified Compounds (TICs) that should be considered for inclusion on the COC list. Several TIC precursors were identified in the tabulated data and a GC/MS high resolution analysis on selected samples was recommended. This suggestion is being pursued through NERL-LV chemists. 13 ------- Region 2 Major TSC technical support activities (>$1,000) in Region 1 during the first three quarters ofFY03 are summarized on the following pages. Minor technical support (<$ 1,000) was provided at the following sites: Cornell Dubilier Electric, Hilliards Creek / Sherwin Williams, Liberty Industrial Finishing, and Stanton Cleaners. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Caldwell Trucking Site Location: Fairfield Township, NJ Site Background: This 11-acre site, located in Fairfield Township, N. J., is on an extensive 100-year flood plain of the Passaic River. From the 1950's to 1984 septic wastes were deposited in unlined lagoons and later in steel holding tanks. EPA investigations indicated on-site soil and a municipal well were contaminated with VOCs, PCBs, and metals. Groundwater remains contaminated because of a TCE-contaminated plume which extends 4,000 feet toward the river. A second remedial action addresses off-site groundwater contaminated with VOCs including TCE. The selected remedy includes pumping and treatment of off-site groundwater using air stripping with off-site discharge to the river; installation of a drainage system to eliminate surface exposure to contaminated groundwater; sealing groundwater wells; and groundwater monitoring. Requested Technical Support: The Regional RPM request support in the development of a sampling and analysis plan for the purpose of characterizing the site's potential for bioremediation. Requested by: Tom Porucznik, 212 637-4370 Lead Scientist: Kent Sorenson and Lance Peterson, North Wind (subcontractor to INEEL), 208 528- 8718 Summary of Previous Technical Support: During the fourth quarter FY02 TSC was requested to technically review a report titled "Pilot Test Report Accelerated Biological Treatment Cardwell Trucking Superfund Site Fairfield, NJ." On August 19, 2002, the TSC transmitted a preliminary report titled "Summary of Major Comments on the Pilot Test Report Accelerated Biological Treatment Cardwell Trucking Superfund Site Fairfield, NJ" to the Regional representative. Summary of Activities During the First Quarter FY03: No activity during the this quarter. Summary of Activities During the Second Quarter FY03\ During this quarter the TSC was requested to review the most current data set, compare it to the previous data, and determine if there have been any significant changes in biodegradation or if conditions for biodegradation have improved. Preliminary comments were sent to the Region RPM in mid March. The evaluation will be finalized during the next quarter. 14 ------- Summary of Activities During the Second Quarter FY03: There was minor follow-up activity on this site between the Regional and INEEL scientists. 15 ------- • Project Title: Chemical Leaman Tank Lines, Inc. Site Location: Logan Township, NJ Site Background: Chemical Leaman Tank Lines, Inc. (proposed for listing as Chemical Leaman Tank Liners, Inc.) has operated a tank-washing facility (including cleaning the interior and exterior of trailers) since 1960 on a 2-acre site in Bridgeport, New Jersey. The waste water generated was placed in a series of six lagoons and ultimately discharged to Moss Creek. In 1975, sludge in the settling lagoons was excavated and disposed of off-site. They were then filled in. The aeration lagoons were filled in, but no sludge was removed. In 1980-81, the State found carbon tetrachloride and other organics in ground water on the site, as well as in private wells. Requested Technical Support: Determine the appropriateness of use of the Bias Corrected Accelerated (BCA) Bootstrap Methods applied to data for the Chemical Leaman site. Assessment may require the analysis of site data and may require simulation experiments to determine the properties and behavior of the BCA bootstrap method on data with different data distributions. Requested by: Marian Olsen, Region 2, 212 637-4313 Lead Scientist: Anita Singh, Lockheed Martin, 702 897-1385; A.K. Singh, UNLV, 702 895-0364 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the second quarter of FY03. Summary of Activities During the Second Quarter FY03: Site data are being used to compare the performance of the bias-corrected accelerated (BCA) bootstrap method with the various other Upper Confidence Limit (UCL) computation methods as incorporated in the ProUCL Version 2.1 software. The comparison is being performed via Monte Carlo simulation experiments. Three distributions have been considered: normal, lognormal, and gamma. A simulation program was developed to perform the comparisons. Extensive simulation experiments were conducted for the three distributions. The results were graphed and a detailed report is being prepared summarizing the results and findings. It will be delivered early next quarter. For each of the three distributions considered, it was concluded that the BCA method is not any better than the methods (e.g., Bootstrap-t, Chebyshev UCL, etc.) which are currently contained in ProUCL. Summary of Activities During the Third Quarter FY03: During this quarter the TSC developed and delivered a report describing the results of simulations run for three contaminant distributions at the site: normal, lognormal, and gamma. Site data was used to compare the performance of the bias- corrected accelerated (BCA) bootstrap method with other UCL computation methods as incorporated in the ProUCL Version 2.1 software. The comparison was performed via Monte Carlo simulation experiments. A simulation program, MCBTEST was developed to perform the 16 ------- comparisons. Simulation experiments were conducted for the three distributions, the results were graphed and the results were summarized in the reports. For each of the three distributions considered, it is concluded that the BCA method is not any better than the methods (e.g., Bootstrap-t, Chebyshev UCL, etc.) which are contained in ProUCL. Comments from Dr. J. Carson were addressed regarding the bootstrap methods as described in the bootstrap report prepared for the Chemical Leaman site. 17 ------- • Project Title: Hudson River PCBs Site Location: Hudson River, NY Site Background: The Hudson River PCBs site includes the approximately 200-mile stretch of the Hudson River from Hudson Falls to the Battery in New York City. The Upper Hudson River, an approximately 40 mile reach of the river from Hudson Falls to Troy, in Washington, Saratoga and Rensselaer Counties, is the major focus of the investigations, and is the reach that is being considered for remediation. The General Electric Co. discharged between 209,000 and 1.3 million pounds of polychlorinated biphenyls (PCBs) into the river from two capacitor manufacturing plants located in Hudson Falls and Fort Edward. Previous studies identified 40 hot spots in the Upper Hudson, defined as sediments contaminated with greater than 50 parts per million (ppm) of PCBs. Also included in the site are five remnant deposits, which are river sediments that were exposed when the level of the river was lowered due to the removal of the Fort Edward Dam, in 1973. Requested Technical Support: The Region requested the assistance of the TSC in reviewing the statistical portions of the U.S. EPA's Preliminary Draft Engineering Performance Standards for the Hudson River PCBs Site. Requested by: Alison Hess, Region 2 Lead Scientist: Anita Singh, Lockheed Martin, 702 897-1385 Summary of Previous Technical Support: During the fourth quarter FY02 the TSC conducted an initial review of the "Hudson River Natural Resources Damage Assessment Floodplain Soil and Biota Screening Sampling Report" along with four data files. Several conference calls were held with the Region to define the scope of the floodplain sampling and map were reviewed to identify potential floodplain sampling areas downstream from the source location. Summary of Activities During the First Quarter FY03: No activity during this quarter. Summary of Activities During the Second Quarter FY03: On January 9, 2003, Ms. A. Hess, Region 2, requested the assistance of the TSC in reviewing the statistical portions of the U.S. EPA's Preliminary Draft Engineering Performance Standards for the Hudson River PCBs Site. A report was prepared that summarizes reviewer comments on the statistical portions in the first two volumes of the Draft Engineering Performance Standards for Hudson River PCB Site. The two volumes reviewed include: 1) Performance Standard for Dredging-Related Resuspension, and 2) Performance Standard for Dredging Residuals. Evaluated information provided for sampling the floodplain area downstream of Ft. Edwards. Requested detailed maps of the downstream area in order to develop a sampling plan for the floodplain. Summary of Activities During the Third Quarter FY03: During this quarter the TSC participated in a conference call with Mr. B. Conetta and Dr. M. Olsen of Region 2 to discuss the sampling plan for 18 ------- the 12 mile flood plain area stretching from Fort Edward to Schyulerville NY for the Hudson River Site. We developed and discussed sampling plan scenarios for various distances (50', 75', and 100') from the shoreline. 19 ------- Project Title: Middlesex Sampling Plant Upper Tolerance Limit Approach Site Location: Middlesex, NJ - Evaluation of the Army's Use of the Site Background: See: http://www.epa.gov/superfund/sites/npl/narl525.htm for information on the background of the site. Requested Technical Support: Review the statistical portion of the Army's proposed use of the Upper Tolerance Limit approach to determine whether chemicals are site related, or not, and to determine its appropriateness for the actual data. Requested by: Marian Olsen, Region 2, 212 637-4313 Lead Scientist: Anita Singh, Lockheed Martin Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter ofFY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter ofFY03. Summary of Activities During the Third Quarter FY03: The TSC evaluated the use of the Upper Tolerance Limit approach used by the U.S. Army (as described in the material faxed by Dr. Olsen on 5-7-03) to determine background level contaminant concentrations for the Middlesex Sampling Plant Site. A letter report summarizing review comments was submitted to the TSC. 20 ------- • Project Title: Peter Cooper Corporation, Gowanda Site - Statistical Analysis of Site Data to Determine Background Site Location: Gowanda, NY Site Background: See: http://www.epa.gov/superfund/sites/npl/narl550.htm for information on the background of the site where wastes from the Gowanda site were disposed. Requested Technical Support: Statistically analyze data provided by the Region for the Gowanda Site to determine if the arsenic levels are consistent with the USGS data for the Eastern US. Requested by: Marian Olsen, Region 2, 212 637-4313 Lead Scientist: Anita Singh, Lockheed Martin Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter ofFY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Third Quarter FY03: Dr. M. Olsen of Region 2 requested the assistance of the TSC to compare site arsenic concentrations with those of the background arsenic concentrations for the Peter Cooper Site. An Excel data file was provided that contains surface and subsurface soil data collected from the inactive landfill and the manufacturing plant. Upper tolerance limits were computed using this data file. A letter report that summarizes the upper tolerance limit computations and conclusions was developed and submitted to the Region. 21 ------- • Project Title: Shenandoah Road Groundwater Site Location: East Fishkill, NY Site Background: The site is contaminated with PCE. The source of the PCE in the groundwater was a facility that handled computer parts and other electrical components. The waste PCE was discharged into an underground storage tank, which overflowed and leaked. The waste PCE persisted in the soil, as well as migrating to the fractured bedrock aquifer, where it ultimately showed up in residential wells. Due to the gross soil contamination in the source area, soil was removed and the area was backfilled with clean soils. Requested Technical Support: Conduct a technical review of the document, "Statistical Analysis and Risk Evaluation of Background Arsenic Concentrations." This document is a comparison of arsenic concentrations in soils at the source area with soils that were not impacted by the release of PCE. Conduct a review of the statistical evaluation used to compare the arsenic concentrations in various soils. Requested by: Michael Sivak, Region 2, 212 637-4310 Lead Scientist: Anita Singh, Lockheed Martin, 702 897-1385 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the second quarter of FY03. Summary of Activities During the Second Quarter FY03: A review was conducted of the statistical methods used for the evaluation of background arsenic concentrations at the 7 East Hook Road Property on the Shenandoah Road Groundwater Contamination Superfund Site. A review letter report was provided the Region titled "Review of the Statistical Analysis for Background Arsenic Concentrations Shenandoah Road Groundwater Contamination Superfund Site". All statistical methods used were adequate for the intended purpose of comparing arsenic concentrations in impacted areas and unimpacted areas of the site. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 22 ------- Region 3 Major TSC technical support activities (>$1,000) in Region 3 during the first three quarters of FY03 are summarized on the following pages. Minor technical support activities (<$ 1,000) occurred Letterkenny Army Depot. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Langley Air Force Base Site Location: Hampton, VA Site Background: Langley AFB (LAFB) located in Hampton, VA has been an airfield and aeronautical research center since 1917 and is the home base for the First Tactical Fighter Wing. NASA Langley uses a research facility that conducts 270 operations in 191 buildings and operates 40 wind tunnels. Wastes generated at LAFB and NASA Langley include waste solids, solvents, paint wastes, pesticide containers and rinse waters, photographic wastes, scrap metals, used batteries, and printed circuit board plating wastes. PCBs and polychlorinated terphenyls (PCT) were used in hydraulic systems, electrical equipment, compressors, and casting operations. Requested Technical Support: The Regional RPM requested that the TSC provide assistance in reviewing the long-term plan for Langley and the "Conceptual Work Plan for the Evaluation of Groundwater Data." These reviews were conducted via two separate tasks: Task 1, Statistical Evaluation and Task 2, Geochemical / Groundwater Evaluation. Requested by: Michelle Price-Fay, Region 3 RPM, (215) 814-3397, Stacie Driscoll (215) 814-3368, and Kathy Davies (215) 814-3315 Lead Scientists: Task 1, Anita Singh, Lockheed Martin (702) 897-3293; Task 2, Mike Roddy, INEEL (208) 526-8201 Carol Craiglow, INEEL (208) 526-3106 Summary of Previous Support: Task 1, Statistical Evaluation. During the previous fiscal year the TSC provided a report titled "Review of Regression Analysis for Surface Water vs Sediment Contaminants and Human Health Risk Assessment of Langley Air Force Base IRP Site OT-56 Arsenic and Old Wastes." Task 2, Geochemical / Groundwater Evaluation. During the previous fiscal year the TSC provided a report titled "Review Comments on Conceptual Work Plan for the Evaluation of Groundwater Data, Langley Air Force Base, Virginia." Following the PRP's revision of the conceptual work plan the TSC provided the Region with additional recommendations. Summary of Activities During the First Quarter FY03: Task 1, Statistical Evaluation. None. Task 2, Geochemical / Groundwater Evaluation. During this quarter the TSC provided the Region comments on "Draft Report for the Geochemical Evaluation of Groundwater Data for the ERP Site OT-64, Langley AFB." Follow-up conference calls were held to resolve some issues and clarify some of the comments on the draft report. 23 ------- Summary of Activities During the Second Quarter FY03: Task 1, Statistical Evaluation. None. Task 2, Geochemical / Groundwater Evaluation. In February the TSC received a request from Stacie Driscoll to review the "Response to Comments" she received from the Air Force regarding INEEL's comments on the Geochemical Evaluation Report. Comments on the report centered on issues of analyses of filtered versus unfiltered water samples and identification of the main purpose of the report. It appears that one more conference call may be necessary. Summary of Activities During the Third Quarter FY03: Task 1, Statistical Evaluation. During this quarter the TSC reviewed the background versus site comparison methods as described in the Draft Site Inspection Report for the three Environmental Restoration Program (ERP) sites: DP-66, DP-67, and DP-68, Langley Air Force Base, Virginia. A letter report summarizing review comments was submitted. We also participated in a call with the Region to discuss the statistical and geochemical methods as used in the Draft Site Inspection report. Task 2, Geochemical / Groundwater Evaluation. During April the TSC received a requests from the Region for another review concerning the Langley AFB Geochemical Evaluation of Groundwater Data. Comments on the "Draft Report for the Geochemical Evaluation of Groundwater Data ERP Site OT-64 Langley Air Force Base, Virginia July 2002" were provided in May 2003. On 13 May, the TSC received the document that the Region had put together to show the progression of comments and response to comments that have been generated for the OT-64 Geochemical report. Also included were EPA's comments on the 25 April 2003 RTCs, which were submitted for review. The TSC received the revised report on 9 June and provided comments by e-mail on June 12, 2003. We reviewed the introductory section, Section 1.0, and Table 2-2 of Shaw/AFB's rewrite of the methodology section for the OT-64 Geochemical report, and both were acceptable. Comments were provided on Section 2.2. There are no major disagreements, just some technical differences of opinion on the implications. On 20 June, 2003, we received the revised geochemistry sections of the report to review, and on the 23rd, received revisions to Chapters 2 and 5 and revisions to Table 2-3. Although it is not indicated in the report where the background locations are in respect to the site, it is quite possible that conditions reflecting sea water intrusion are absent from the background samples; therefore, direct comparisons of background to site data may not be appropriate. The Regional RPM called after receiving the review comments to discuss a path forward. It was suggested that all the analytical data be made available to the reviewers with a description of the sampling and analytical methods, the locations, and the time and date the samples were collected. Data should not be lumped together by location or any other parameter. 24 ------- • Project Title: Occidental Chemical Site Location: Pottstown, PA Site Background: Three consecutive owners disposed of industrial wastes at the Pottstown, PA 30- acre Occidental Chemical Corp/Firestone Tire & Rubber Co. site.. The groundwater is contaminated with volatile organic compounds (VOCs) including PVCs from former site manufacturing activities. Possible health threats include drinking the contaminated groundwater. Local agricultural lands depend on water from the Schuylkill River for irrigation; contaminated water use may therefore, threaten crops and livestock. Also, nearby wildlife and wetlands are threatened by the contamination from the site. Requested Technical Support: Determine if a statistical difference exists between the concentrations of compounds of potential concern (CPCs) in borings from four on site lagoons and site background values. RPM will provide the required data for the analysis and will designate the CPCs to be included in the statistical analyses. Requested by: Maria Garcia, Region 3 RPM, 215 814-3199 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3293 Summary of Previous Technical Support: In December of 2001 the Region requested the TSC to perform the Max Test for organic/inorganic contaminants using the composite samples collected from four lagoons. The TSC received site data and conducted the requested test. The TSC provided the Region with the report titled "Data Packing Analysis - Surface Soil Samples Occidental Superfund Site." The data used to perform the Max and CV test for metals and SVOAs for the four lagoons was sent to the RPM in May 2002. Summary of Activities During the First Quarter FY03: None, work on this most recent request was initiated during the second quarter FY03. Summary of Activities During the Second Quarter FY03: A review of background versus lagoon concentrations for 31 chemicals of potential concern (COPC) was performed. These chemicals were identified by the Region 3 requestor. The main objective of the review was to compare the background population with each of the four lagoons associated with the Site. Lagoon versus background comparisons were performed using a two sample parametric t-test as well as a non- parametric Wilcoxon Rank Sum Test. The level of significance was set at 0.05. The hypotheses tested were the null hypothesis, HO: Average (or median) lagoon concentration is equivalent to the background average (or median) concentration versus the alternative hypothesis, HI: Average (median) lagoon concentration is greater than the background average (median) concentration. If a null hypothesis was rejected using any of the two tests, it was concluded that the respective average (median) lagoon concentration was greater than the background average (median) concentration. It was observed that for most of the chemicals (except for some metals) of potential concern, the lagoon 25 ------- average (median) concentrations were significantly greater than the respective background average (median) concentrations. The statistical software package was used to perform background versus lagoon comparisons. A letter report summarizing all results, summary statistics, and conclusions was provided to the Region titled "Lagoons Versus Background Comparisons, Occidental Chemical". Summary of Activities During the Third Quarter FY03: During this quarter the Region requested the TSC to perform a comparison of background concentrations versus four lagoon concentrations for the two chemicals of potential concern (bis(2-ethylhexyl)phthalate and thallium) found at the Occidental Chemical Superfund Site. This comparison was performed using the statistical software package, MINITAB. A letter report summarizing the computations and conclusions was submitted. 26 ------- • Project Title: Ohio River Park Site Location: Newville Island, PA Site Background: The U.S. Environmental Protection Agency has determined that construction is complete at the Ohio River Park site. Neville Land Co., the Potentially Responsible Party (PRP), has installed a multilayer cap over an 11-acre area where hazardous waste was disposed, and covered the rest of the site with a soil cap. On top of the cap, Neville Land Company built the Island Sports Center, which, in November 1998, allowed school children to use two skating rinks for training. Work on the caps was completed in September 1999. Roads, parking, and an indoor golf driving range were opened to the public in November of 1999. In the Fall of 2000 the PRP opened a miniature golf course to the public, re-vegetated the site, and started long-term groundwater sampling. Requested Technical Support: The TSC was requested to review existing monitoring data to determine if natural attenuation was occurring at the site. Requested by: Romuald Roman, Region 3 RPM, 215 814-3212 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3293 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the second quarter of FY03. Summary of Activities During the Second Quarter FY03: Information provided by the RPM was reviewed and additional information was requested in order to develop trend analyses for the various contaminants of interest. Results of trend analyses will be used to determine natural attenuation (if any) at the site. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 27 ------- • Project Title: Quantico, Marine Corps Combat and Development Command Site Location: Quantico, VA Site Background: The Marine Corps Combat Development Command site (MCCDC) is a 56,000- acre military training facility that overlaps areas in Prince William, Northern Stafford, and Eastern Fauquier counties. The base is located in Quantico, Virginia, about 35 miles south of Washington, D.C. on the Potomac River. MCCDC is bordered by Prince William Forest Park to the north and the Potomac River to the east. The western and southern portions of the base include residential areas. Operations began at MCCDC in 1917, when the Department of Defense established a new Marine training camp. A large expansion in the size of the facility occurred in 1943. The MCCDC prepares Marine Corps officers for general combat by providing them with an understanding of technical operations and by performing research and development on military equipment. In February, 1999, EPA and the Navy entered into a Federal Facility Agreement to conduct studies and to examine ways to clean up at the Marine Corps Combat and Development Command. As a result, a total of 261 potential sites have been identified for further consideration, which starts with a Desktop Audit, with sampling as required. Currently, 138 are actively being investigated, in priority order, and 58 sites have been completed or deferred to another program. Requested Technical Support: TSC was requested to review the Feasibility Study for Site 4 - Old Landfill site at the Marine Corps Combat and Development Center. Requested by: Lisa Bradford (215) 814-3363 Lead Scientist: Jeff Sondrup, INEEL (208) 526-8396 Summary of Previous Technical Support: None Summary of Activities During the First Quarter FY03: During this quarter the TSC provide the Region their review of "Feasibility Study for Site 4 - Old Landfill site at the Marine Corps Combat and Development Center (MCCDC) Quantico, Virginia." The review focused on aspects of the report related to groundwater modeling. Summary of Activities During the Second Quarter FY03: During this quarter the TSC supported a team conference call. The purpose of the call was to review and resolve issues and TSC comments related to the Site 4 (Old Landfill) draft final Feasibility Study (FS) Report (dated September 2001), specifically those pertaining to modeling groundwater flow and seeps and the potential impacts to surface water and sediment in the Quantico Embayment/Potomac River. Several issues were identified and will be formally addressed in a Comment Resolution document, which will be prepared by Lisa next quarter. 28 ------- Summary of Activities During the Third Quarter FY03: In late June 2003 the TSC received a "Revision to the Site 5 Old Landfill Feasibility Study Report" from the Region requesting comments early the next quarter. 29 ------- • Project Title: Sharon Steel Site Location: Mercer County, PA Site BackgroundThe Sharon Steel Corporation Farrell Works Disposal Area (the "site") is an area of about 400 acres located in Mercer County in Western Pennsylvania, within a few hundred feet of the Ohio/Pennsylvania border. The site is southwest of the former Sharon Steel Corporation Farrell Works, and is bordered on the east by the Shenango River. The Sharon Steel Corporation used the area to dispose of blast furnace slag, electric arc furnace slag, basic oxygen furnace slag, and sludge beginning about 1900. From 1949 to 1981, millions of gallons of spent pickle liquor acid were dumped over the slag. It was thought that the acid would partially evaporate and then be neutralized by the carbonates in the slag. In actuality, ground water contamination resulted. The site is located in the flood plain of the Shenango River, and there are several wetland areas on site. Requested Technical Support: The RPM requested that the TSC provide assistance in providing a systematic and standardized approach for computing the UCL-concentration term for risk assessments. This on-going effort involved the updating of the ProUCL program such as: including test of normal and lognormality, small samples - Shapiro Wilk's test/normal probability plot, large sample - Kolmogrov-Smirnov's test/normal probability plot, and for lognormally distributed data sets, include a 99% Chebychev inequality based upon minimum variance unbiased estimates. Requested by: Rashi Mathur (215) 814-5234 Jennifer Hubbard (215) 814-3328 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Technical Support: This program plus the "User's Guide Program ProUCL", "Background and a Brief Description of the Program ProUCL", and the "Installation Guide Program ProUCL" were provided to the Region. The TSC sent CD ROM's and copies of the documents to selected individuals for review. The TSC addressed a number of questions by the reviewers and made the necessary changes. ProUCL Version 2.0 was finalized. ProUCL Version 2.1 was peer reviewed and distributed and additional changes were made to the guidance document and additional CD produced and delivered. Summary of Activities During the First Quarter FY03: Additional copies of the ProUCL 2.1 were produced and distributed to the requesters from the States and Regions. Modifications were made to the labels indicating that the software may not function properly on Windows ME or XP. OSWER has included references to the software in their December 2002 guidance to the Regions "Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites, OSWER 9285.6-10." As a result we anticipate a significant increase in the requests for the software. Summary of Activities During the Second Quarter FY03: During this quarter the TSC responded to ProUCL user comments regarding ability to copy ProUCL and provided assistance to users that obtained unexpected results. Additional CDs of the latest version of ProUCL were generated and made available for distribution. 30 ------- Summary of Activities During the Third Quarter FY03: No activity during this quarter. 31 ------- • Project Title: Valmont TCE Site Site Location: West Hazleton, PA Site Background: The Valmont TCE site in Hazle Township and West Hazleton Borough, Luzerne County, Pennsylvania consists of the former Chromatex Plant #2, on Jaycee Dr. near Deer Run Rd., and contaminated ground water in the nearby residential neighborhood on Deer Run Rd., Bent Pine Trail/Rd., Twin Oaks Rd., and possibly Fawn Dr. The former Chromatex Plant #2 is located at the edge of a large industrial park, and the residential neighborhood is located approximately 100 feet northeast of its property boundary. Ground water contamination at the site was discovered in October 1987 when sampling of residential drinking water wells revealed the presence of trichloroethylene (TCE) and other volatile organic compounds (VOCs) in 23 residential wells and in the Chromatex facility well. EPA immediately provided bottled water and carbon filters to affected residences and subsequently oversaw the installation of public water supply lines into the neighborhood. The total population currently served by ground water wells within four miles of the site is over 26,000. Requested Technical Support: The TSC was requested to perform several tasks related to the site: 1) evaluate, compare, and analyze contaminate analytical data from underground (soil, soil gas, and ground water) and indoor air concentrations as a result of vapor intrusion into nearby residences, 2) review of statistical portions of a document prepared by NUS titled: "Engineering Evaluation / Cost Analysis for Contaminated VOC Soils, Valmont TCE Site, West Hazleton, PA, 3) review of discriminant analysis approach proposed by the State of PA, and 4) review of statistical portions of the site REFS when available. Requested by: Jennifer Hubbard, Region 3 Toxicologist, 215 814-3328, Romuald Roman, Region 3, RPM, 215 814-3212 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the second quarter of FY03. Summary of Activities During the Second Quarter FY03: During this quarter the TSC analyzed data provided by. the Region to evaluate the correlation of contaminants between soil gas data and indoor air data (measured as separate basement and first floor samples). A summary report titled "Correlation and Association Analyses for Soil Gas Versus Basement Air: Round 2 (PADEP) Data Soil Gas Versus Basement Air: Round 3 (EPA) Data First Floor Versus Basement Air: Round 3 (EPA) Data Valmont TCE Site, West Hazleton, Luzerne County, Pennsylvania" was developed and provided a to the Regions. The following analyses were conducted. Correlation and Association Analyses for Soil Gas Versus Basement Air: Round 2 (Pennsylvania 32 ------- Department of Environmental Protection (PADEP)) Data Soil Gas Versus Basement Air: Round 3 (EPA) Data • First Floor Versus Basement Air: Round 3 (EPA) Data • Relevant correlation and regression graphs for the various contaminants were supplied to the Region Reviewed statistical portions of the Tetra Tech NUS (TtNUS) document entitled,"Engineering Evaluation / Cost Analysis (EE/CA) for Contaminated VOC Soils, Valmont Site." Reviewed multivariate discriminant analysis approach proposed and used by the PADEP in the Dunmore Carbon Monoxide Site Background Investigation Report. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 33 ------- Region 4 Major TSC technical support activities (>$1,000) in Region 4 during the first three quarters of FY03 are summarized on the following pages. Minor technical support activities (<$ 1,000) occurred at the following sites: Distler Farm, Duracell Battery, FCX Statesville, and the Roanoke River Study site. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Distler Brickyard Site Location: Westpoint, KY Site Background: The 3-acre Distler Brickyard site in West Point, Kentucky is located on a 70-acre abandoned brick manufacturing plant property that operated from the late 1800s until the mid-1970s. In 1976 the property was leased by Kentucky Liquid Recycling Inc., which began transporting waste to the brickyard property. Waste disposal was contained at the site until 1979. There were approximately 2,300 drums on the site, 1,550 of which contained various liquids, sludges, and solids. Spillage from the deteriorated drums killed grass, trees, and birds on the site. A contaminated groundwater plume is located beneath the site and could threaten the city drinking water wells and the Ohio River. Specific contaminants detected in groundwater and on-site soils include various volatile organic compounds (VOCs) and heavy metals including lead from waste disposal activities. Potential health threats include direct contact with, or accidental ingestion of, contaminated soils and groundwater. Requested Technical Support: The Regional Remedial Project Manager (RPM) requested that the TSC provide assistance in reviewing the PRP's suggested hydrogeological groundwater remediation approaches. Requested by: Femi Akindele (404) 562-8809 Lead Scientists: Lance Peterson, North Wind (208) 526-8718x170, Jennifer Martin, North Wind, (208) 526-8718x147 and Kent Sorenson, North Wind (208) 526-8718x120 Summary of Previous Technical Support: The TSC received, and reviewed, three documents pertaining to groundwater remediation. Comments and recommendations were provided to the RPM.. The lead scientist participated in a technical meeting with the RPM, USGS, and Kentucky State personnel. It was agreed at the meeting that additional field data were required to fully evaluate potential biodegradation at the site. The TSC and USGS completed the draft "Field Sampling Plan for the Distler Brickyard". TSC and USGS prepared a status update on field activities for the RPM. The TSC completed and delivered the report titled "October 1999 Groundwater Sampling and Data Analysis Distler's Brickyard, Hardin County, Kentucky." The TSC provided the following documents to the Region: "Final Field Sampling Plan" and "Proposed Activities for Fine Grained 34 ------- Alluvium (FGA) Sampling." Following the collection and analysis of site samples and data the TSC provided the report titled "Summary of Groundwater and Soil Gas Collected June-August, 2000 Distler Brickyard Superflmd Site, Kentucky." The report titled "June-August 2000 Groundwater and Soil Gas Data Analysis, Distler Brickyard Site, Hardin County, Kentucky" was completed on November 30, 2000. A number of site and regional office visits were completed to plan, and initiate, the field work. Sampling was conducted at the site with the USGS providing equipment and lab space. Following an assessment of the sampling data the report titled "Summary of the Results of the Phase I Pilot-Scale Field Test of a Chitin-Fracing Technology Conducted at the Distler Brickyard Site, Hardin County, KY" was provided to the Region. During FY02 a collaborative sampling effort was conducted at the 5 wells in the chitin-fracing area using the Phase I list of analytes. Summary of Activity During the First Quarter FY03: During this quarter the TSC provided the Region a draft summary of the July 2002 sampling activities. Additional meetings with the Region and USGS were held to develop the sampling strategy and plan for the next round of monitoring at the site. A summary of activities at the site was provided to TIO for their newsletter, Technology News and Trends. Follow-on work on this site (Phase H) will be through an NSF grant for $500K. Summary of Activities During the Second Quarter FY03: During January, the Region was working on providing funding to support North Wind for the sampling event (~$4K) via the TSC. The sampling was originally scheduled for the week of 31 January; however, that was delayed by USGS until the week of 18 February because of weather and illness issues. A conference call was held on i 5 January with Femi, Ken Moor, Kent Sorenson, and Jennifer to discuss funding for the sampling. Because Femi said he had sent $4K to the TSC, Ken Moor authorized $4K to be sent to North Wind to allow Jennifer to prepare sampling guidance for the USGS. In preparation for the sampling, written guidance was prepared and transmitted on 24 January as an addendum to the USGS Work Plan to cover the specific sampling activities for long-term monitoring of the original chitin emplacement performed in October 2001. Discussions with USGS continued on the details of that guidance. During February, sampling at the site was postponed due to weather. The general schedule calls for field activities to begin in mid-April. The field activities are currently scheduled to begin 14 April 2003. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 35 ------- • Project Title: Mallory Capacitor Site Location: Waynesboro, TN Site Background: Electrical capacitors were manufactured on the 8 !4 acre Mallory Capacitor site, located in Waynesboro, TN, from 1969 to 1984. The operators first used polychlorinated biphenyls (PCBs) as the dielectric fluids in the capacitors, switching to a plastics chemical in 1978. The factory changed hands when Dart Industries purchased it in 1978. Dart later sold the property in 1980 to Emhart Industries, Inc. As part of the sales Agreement with Emhart, certain PCB wastes, a buried tank, and contaminated soil were removed from the site and sent to an approved PCB disposal facility. The plant continued to operate, but voluntarily closed in 1984 when PCBs were discovered throughout the site. Requested Technical Support: The Regional RPM requested that the TSC provide assistance in reviewing the efforts of the groundwater recovery system and to investigate other approaches for enhancing the recovery of PCB's and TCE in groundwater. Requested by: Lofton Carr (404) 562-8804 Lead Scientist: Jennifer Martin, North Wind (208) 528-8718 xl47 Summary of Previous Technical Support: A conference call with the Region provided an introduction to the site. A description of the remedial activities that have been conducted to date and areas were identified where the Region requires support. The major focus of this review is to evaluate the effectiveness of the groundwater treatment system. A review of the pump and treat system was provided to the Region in September 2002. Summary of Activities During the First Quarter FY03: During this quarter a report titled "Comments and Recommendations Regarding the Performance of Groundwater Remediation Activities at the Mallory Capacitor Site, Waynesboro, TN"'was delivered to the Region. Summary of Activities During the Second Quarter FY03: There was no activity on this site during this quarter. Summary of Activities During the Third Quarter FY03: There was no activity on this site during this quarter. 36 ------- • Project Title: Nocatee Hull Creosote Site Site Location: Hull, FL Site Background: The site is located about one hour NE of Ft. Myers, FL and is connected with the old Seaboard Railroad Site. It had been manufacturing creosote from 1912 to approximately 1955. This site is currently being cleaned up by the PRP but there are questions about its contribution to other off site contamination. Technical Support Requested: The Regional RPM requested that the TSC provide assistance in applying its "fingerprinting" technique to identify the source of contamination in the Oak Creek area adjacent to the Nocatee Hull Creosote Superfund Site. The focus with be on PAHs and dioxins and furans. Requested by: Bill Denman (404) 562-8939 Lead Scientist: Russ Plumb, Lockheed Martin (702) 897-3265 Summary of Previous Technical Support: None Summary of Activity During the First Quarter FY03: During this quarter the TSC worked on developing a manuscript for peer reviewed publication that documents the fingerprinting technique titled: "Fingerprint Analysis of Contaminant Data: A Forensic Tool for Evaluating Environmental Contamination." This should be an extremely useful document for the Regions and includes a description of four case histories where the technique has been used successfully. Summary of Activities During the Second Quarter FY03: During this period the TSC complete the draft final of the above issue paper and submitted it for external peer review. Summary of Activities During the Third Quarter FY03: During this quarter the TSC received a request to determine whether creosote contamination in an off-site area originated from a nearby facility that preserved railroad ties with creosote. Following a series of conference calls between Region 4, the EPA Technical Support Center-Las Vegas, Lockheed Martin, CSXT (property owner), and Gannett Fleming (CSXT consultant), a decision was reached to fingerprint the contamination using two techniques. Lockheed Martin would apply the FALCON technique and Gannett Fleming would apply a version of Principal Component Analysis to the same set of data. Existing sample analysis data was used to develop a Nocatee source fingerprint pattern with a reproducibility of 92 percent with the FALCON technique. Information from these samples have been provided to Gannett Fleming to compare the two fingerprinting techniques. The Lockheed Martin initial assessment indicates that a portion of the off-site creosote contamination may be attributed to past activities on the Nocatee site. A final report discussing the FALCON technique and the assessment of Nocatee site conditions will be developed by August 2003. 37 ------- Region 5 No major TSC technical support activities (>$1,000) occurred in Region 5 during the first three quarters of FY03. Minor technical support activity (<$ 1,000) did occur at the Fort Sheridan Landfill site. See the table at the end of the report for a funding history of sites currently being supported by the TSC. 38 ------- Region 6 Major TSC technical support activities (>$1,000) in Region 6 during the first three quarters of FY03 are summarized on the following pages. No minor technical support activities (<$1,000) occurred in the Region during this quarter. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: AS ARCO El Paso Lead Site - Kriging of Soil Sampling Data for Arsenic and Lead Site Location: El Paso, TX Site Background: See: http://oaspub.epa.gov/enviro/fii_query_dtl.disp_program_facility?pgm_sys_id_in=TX0000605388& pgm_sys_acrnm_in=CERCLIS for background data on this site. Requested Technical Support: Add additional lead and arsenic data to an existing set of data previous kriged and re-krig the data. Requested by: Jon G. Rinehart, Region 6,214 665-6789 Lead Scientist: Tim Ehli, Lockheed Martin, 702 897-3264 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03\ None, work was initiated during the third quarter ofFY03. Summary of Activities During the Third Quarter FY03: In April, 2003, an Excel spreadsheet consisting of 1,843 residential data points from the AS ARCO El Paso site was provided to the TSC by Mr. Jon Rinehart, EPA Region 6. The data set consists of analytical results for arsenic and lead from Phase III and Phase IV residential sampling efforts. This residential data set was used to perform geostatistical analysis. The ArcGIS Geostatistical Analyst software was used to perform geostatistical analysis on arsenic and lead data. A report summarizing the geostatistical results was submitted to the Region. 39 ------- • Project Title: Mountain Creek Lake Sediment Background Analysis Site Location: Dallas, TX Site Background: Mountain Creek Lake is 3.4 miles long and covers an area of 2,170 sq. acres. The reservoir was designed and completed in 1929 to provide cooling water for an adjacent Texas Utilities, oil fired electric generating facility. Mountain Creek Lake is surrounded by relatively undeveloped wooded land, and the urban, industrial, and residential developments of the cities of Grand Prairie and Duncanville. The lake is bordered on the north and northwest by industrial developments and buildings of the former Naval Air Station (NAS) and the Naval Weapons Industrial Reserve Plant (NWIRP) of Dallas. The lake actually consists of a small upper lake, formed when Cottonwood Creek was dammed, and the large portion of the lake abutting the main dam. The upper lake is referred to as Cottonwood Bay. The two lake portions are connected by a canal constructed to allow Cottonwood Creek to discharge to the lake. Requested Technical Support: The Region has asked the TSC to review and evaluate the approaches and statistical techniques used in the report "Technical Memorandum - Sediment Background Study for Mountain Creek Lake, Dallas, Texas." Requested by: Richard Mayer (214) 665-7442 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Technical Support: None Summary of Activities During the First Quarter FY03: During this quarter the TSC provided the Region a report titled "Review of the Statistical Approaches Used for Sediment Background Study for Mountain Creek Lake, Dallas, Texas." Several follow-up conference calls were held with the Region in addition to providing comments on the State of Texas' comments on the same document. Summary of Activities During the Second Quarter FY03: During this period the TSC provided review comments on the statistical approaches used by the Navy (prepared by consultant New Fields Inc.) for sediment background study for the Mountain Creek Lake Superfund Site. We also reviewed a document entitled, 'Technical Review of Sediment Background Study for Mountain Creek Lake (MCL)," prepared by Mr. Peter F. Lodde (State of Texas). TSC support staff attended a statistical meeting on March 6, 2003, in Austin Texas to resolve the various statistical issues in the sediment background analysis performed by the Navy. Summary of Activities During the Third Quarter FY03: In May 2003, Mr. R. Mayer, EPA Region 6 requested the assistance TSC in reviewing the revised report titled "Sediment Background Analysis (SBA) for the Mountain Creek Lake (MCL) Superfund Site". A letter report summarizing review comments on the statistical portions of the SBA report prepared by Newfields Inc. was submitted. 40 ------- • Project Title: Sol Lynn Industrial Transformer Site Location: Houston, TX Site Background: The area around this 0.75-acre site, located in Houston, Texas, is a mix of residential, commercial, and light industrial facilities. Approximately 2,000 residents and 100,000 other people move within a one-mile radius of the site on a daily basis due to recreational activities associated with the area. The site operated as an electrical transformer salvage and recycling company between 1971 and 1978, and as a chemical recycling and supply company from 1979 through 1980. The first documented investigation of this site took place during the fall of 1971 when the City of Houston Water Pollution Control Division noted that the workers at Industrial Transformers poured oil out of electrical transformers onto the ground during transformer dismantling. A technical assessment of the site, commencing in January 1986, indicated the presence of PCB contamination has been confined to the top two feet of soil. The highest concentrations of PCBs were found in the middle of the site. TCE has migrated deeper than the PCBs and away from the site. Residual TCE remaining in the surface soil will be remediated along with the PCB contaminated soils. Requested Technical Support: The RPM requested that the TSC provide assistance in reviewing site documents and possible modeling subsurface contaminants. Requested by: Ernest Franke (214) 665-8521 Lead Scientist: Lance Peterson, North Wind (208)528-8718x170, R. Arnett, INEEL (208) 526-8005, B. Starr, INEEL Summary of Previous Technical Support: In previous fiscal years the TSC reviewed a number of documents and provided initial comments and recommendations to the RPM. TSC personnel met with the RPM, and the State of Texas staff in Houston, TX for a site visit and a more definitive discussion as to what assistance the TSC will provide. Following the site visit, the TSC provided a list of technologies that may be useful at the Sol Lynn site and provided information about dissolved oxygen (DO) measurements. The TSC reviewed and provided comments on the amended work plan in particular to the fate and transport modeling issues. The TSC reviewed and provided comments and suggestions pertaining to the "Supplemental RI/FS Study" and provided information on the required groundwater modeling parameters. In addition, the TSC received, and reviewed, the "Field Sampling and the Data Management Plans." The TSC is currently doing the sub-surface modeling for the Region. Additional data (i.e., well survey and water level data) were received by the TSC and used to update the preliminary groundwater flow model. The TSC received a preliminary field data set which included an updated base map of the monitoring well network, well completion locations, data summary, boring logs and flow rate charts. The TSC performed a groundwater modeling analysis and transmitted a draft preliminary report on the Sol Lynn groundwater modeling results. 41 ------- Summary of Activities During the First Quarter FY03: During this quarter the final report on the Sol Lynn groundwater modeling analysis was provided to the Region for review and comment. Review comments are being incorporated into the final report. Summary of Activities During the Second Quarter FY03: During this period the Region wanted all review comments to be completed and returned on the Sol Lynn/Industrial Superfund Site's Draft Feasibility Study by 7 April 2003. We expected to meet the deadline. Summary of Activities During the Third Quarter FY03: Draft comments were provided to the Region by the requested data. A conference call was held with the Sol Lynn Feasibility Study reviewers on 30 April 2003 to discuss review comments. The discussions generally were on the presentation and organization of the treatment alternatives. A formal hard copy of the INEEL review of the Sol Lynn FS was transmitted to the Region in May 2003. 42 ------- • Project Title: Texarkana Site Location: Texarkana, TX Site Background: The 25-acre Texarkana Wood Preserving Company site is an abandoned wood- treating facility that operated under various owners from 1909 to 1984. Work has been conducted at the site for years and currently the EPA and State of Texas are working on a remedy which will address both soils and contaminated groundwater. Eight additional wells have been installed to better define the aquifer and aquitard properties to arrive at an effective remedy for the site. Requested Technical Support: The Region requested assistance from the TSC in evaluating the remedy proposed for the site and its associated monitoring program via groundwater modeling. Requested by: Glenn Celerier (214) 665-8523, Chris Villarreal (214) 665-6758, Charles Dave Abshire (214) 665-7188 Lead Scientist: Ron Arnett, INEEL (208) 526-8005 Summary of Previous Technical Support: The TSC has not provided any significant support to this site since 1999. At that time the TSC provided statistical support, groundwater plume modeling, spatial statistical support, and general monitoring support (assessment and design). Summary of Activities During the First Quarter FY03: During this quarter Dave Abshire, the new RPM for the Texarkana site, visited INEEL to obtain assistance with his groundwater model and analysis of the horizontal barrier remedy for the site. Summary of Activities During the Second Quarter FY03: No activity during this quarter. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 43 ------- Region 7 Major TSC technical support activities (>$1,000) in Region 7 during the first three quarters of FY03 are summarized on the following pages. No minor technical support activities (<$ 1,000) occurred in the Region during this quarter. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: ASARCO Lead Site Site Location: Omaha, NE Site Background: The ASARCO Omaha facility refined lead bullion and lead drosses. Refinement was achieved using traditional pyro-metallurgical processes including addition of metallic and non- metallic compounds to molten lead to remove impurities. The Omaha plant produces refined lead and speciality metal by-products including antimony-rich lead, bismuth, dore' (silver-rich material) and antimony oxide. Although fundamentally classified as a primary lead refinery (not lead smelter), the Omaha plant is the only facility in the United States, and one of only a few such facilities in the world, designed to process lead bullion containing recoverable amounts of several different metals. As a result, the facility employs a complex array of both traditional and unique pyrometallurgical processes which are carried out as batch operations. This facility was constructed in the early 1870s and is currently closed. Requested Technical Support: The RPM requested that the ESD-LV TSC provide assistance in modeling ground deposition rates relative to air contaminant concentrations. Requested by: Don Bahnke (913) 551-7747 Lead Scientists: Mike Abbott, INEEL (208) 526-8596, A. K. Singh, UNLV (702) 895-0364, Bill Cole, Lockheed Martin (702) 897-3255 Summary of Previous Technical Support: The TSC review of site and metallurgical data deposition was completed. Following this review an initial model was completed. This model included plots of relative annual wet and dry deposition rates from the 180' "Black Stack" covering the periods 1984 through 1990. The final report "Dispersion Modeling of Atmospheric Deposition Patters Around the ASARCO Omaha Lead Refinery" was completed and sent to the RPM. There was some follow-up work completed comparing the modeling results with a map of actual soil concentrations. The TSC was requested to provide geostatistical support by kriging soil lead concentrations on and in the vicinity of the smelter. The TSC completed the kriging and provided maps and associated overlays. In addition, the TSC provided recommendations for additional sampling locations that would improve the kriged results. Based on these maps the RPM requested assistance in identifying 44 ------- specific sampling locations. The TSC provided the Region an "all properties kriged map identifying six locations where additional samples should be collected." The TSC provided the Region with a table identifying properties on and near the site that exceeded 400 mg/kg of soil lead at one mile increments. The TSC received additional data, completed geostatistical analysis and provided the Region with kriged maps and overlay of soil lead concentration. The TSC evaluated arsenic soil data for possible kriging. The TSC provided some additional base maps showing more streets as requested by the RPM. Winter 2002 XRF data was QC reviewed and kriged; the data maps were provided to the RPM. Summary of Activities During the First Quarter FY03: During the this quarter the TSC combined new lead contamination data provided by the Region with historical data, conducted new kriging analyses on the new database, and generated and provided the Region and State of Nebraska new maps to display the results. Summary of Activities During the Second Quarter FY03: No activity during this period. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 45 ------- • Project Title: Eagle-Picher Site Site Location: Joplin, MO Site Background: The Eagle-Picher site is located in Joplin, Missouri. The issue at this site is whether fugitive dust and air discharges may potentially recontaminate surrounding residential properties which have already been cleaned up by Superfund. Investigations indicate that high levels of lead in surface soil and the facility has permitted air discharges from its lead smelting operations (secondary smelter of lead ingots to make leaded glass and paint). Requested Technical Support: The Regional RPM requested that the TSC provide assistance in modeling wind suspension and downwind transport of contamination from specific point sources. Requested by: Stephanie Doolan (913) 551-7719 Lead Scientist: Chris Staley, INEEL (208) 526-5687 Summary of Previous Technical Support: During FY02 INEEL staff visited the site and reviewed meteorological data and emission release points from the facility. Meteorological data for the site area were obtained from the National Climatic Data Center. Building and emissions data were run through the Building Profile Input Program (BPIP) which is a prerequisite for running the Industrial Source Code (ISC) program. Wet deposition data were also obtained from NOAA to calculate wet deposition rates. Summary of Activities During the First Quarter FY03: During this quarter the TSC completed the analysis from the site and provided the Region a preliminary progress report on the predicted patterns for a 1-year of release from the lead processing facility in Joplin, MO. Summary of Activities During the Second Quarter FY03: No activity during this period. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 46 ------- Region 8 The major TSC technical support activity (>$1,000) in Region 8 during the three quarters of FY03 is summarized below. No minor technical support activities (<$1,000) occurred in the Region during this quarter. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Eureka Mills Site Location: Eureka, UT Site Background: For more than 100 years, area miners took lead, silver, zinc and copper from mines in the District. Some historic mining facilities and waste piles that remain are located next to residential areas. Preliminary sampling conducted in July 2000 found high levels of lead and arsenic in area soils. The levels of lead found in outdoor residential areas range from as low as 35 ppm (parts per million) to as high as 22,000 ppm with an average of 1,472 ppm. Lead concentrations in the mine dumps and adjacent areas were fairly high, ranging from 2,000 ppm (parts per million) to over 51,000 ppm. In addition, blood-lead testing was done on 237 Eureka residents. The tests showed that 30 residents, mainly children, had blood-lead levels above the standard of 10 micrograms per deciliter. EPA believes exposure to high levels of lead and arsenic may pose a health risk to children and other sensitive people. At present, close to 50 children have been found with blood-lead concerns. Requested Technical Support: The RPM requested that the TSC provide assistance in utilizing XRF technologies for characterizing soils contaminated with lead and arsenic. Requested by: Paula Schmittdiel (303) 312-6861, Mary Goldade (303) 312-7024 Lead Scientist: Bill Cole, Lockheed Martin (702) 897-3255 Summary of Previous Technical Support: The TSC provided the Region with the draft report titled "Wavelength and Energy Dispersive X-Ray Fluorescence - A Brief Technology Comparison." The RPM and a TSC representative meet with Regional.personnel and Regional contractors at the site to discuss the use and application of the XRF technology. During this meeting it was decided that samples would be collected and sent to the TSC for sample preparation, and then sending aliquots to two different laboratories for analysis. The samples were mixed, containerized, and sent to the laboratories for analysis. The TSC will participate in data quality assessment of the XRF analysis and, in finalization of the wavelength and energy dispersive XRF report. Summary of Activities During the First Quarter FY03: During this quarter the TSC coordinated inquires from the WDXRF sample analysis participants and provided the status of the comparison study. The first participant has completed the analysis of samples and the information has been forwarded to the Region for review. The samples will be sent to the next participant once the Region has completed its review. Summary of Activities During the Second Quarter FY03: During this period the TSC reviewed and 47 ------- discussed analytical results of Wavelength Dispersive X-Ray Fluorescence (WDXRF) sample analyses with the RPM. Contacted the labs participating in the study regarding sample delivery and analysis schedules. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 48 ------- Region 9 Major TSC technical support activities (>$1,000) in Region 9 during the first three quarters of FY03 are summarized on the following pages. Minor technical support activities (<$ 1,000) occurred at the MGM Brakes site. See the table at the end of the report for a funding history of sites currently being supported by the TSC. • Project Title: Aerojet General Corp. Site Location: Rancho Cordora, CA Site Background: The Aerojet General Corp. covers 8,500 acres near Rancho Cordova, 15 miles east of Sacramento. Since 1953, Aerojet and its subsidiaries have manufactured liquid and solid propellant rocket engines for military and commercial applications and have formulated a number of chemicals, including rocket propellant agents, agricultural, pharmaceutical, and other industrial chemicals. In addition, the Cordova Chemical Company operated a chemical manufacturing facility on the Aerojet complex from 1973 to 1979. Both companies disposed of unknown quantities of hazardous waste chemicals, including TCE and other chemicals associated with rocket propellants, as well as various chemical processing wastes. Requested Technical Support: The Regional TPO requested that the ESD-LV TSC provide assistance in auditing GC and GC/MS laboratory data, and to provide analytical protocol assessments. An additional request was received in the 3rd quarter FY03 to review Aerojet analytical SOPs. Requested by: Steve Remaley (415) 972-3802, Charles Berrey (415) 972-3146, K. Mayer Lead Scientists: Tim Ehli, Lockheed Martin (702) 897-3279, Vicki Ecker, Lockheed Martin (702) 897-3233, Russell Plumb, Lockheed Martin Summary of Previous Technical Support: The initial effort by the TSC was to identify the contents of the provided tapes and disks. Following an assessment of the tapes and disks a letter report describing the contents was provided to the Region. Due to missing data the data audit was discontinued. The TPO then requested the TSC to provide available information pertaining to hydrazine in water. The TSC provided the Region with a report titled "Considerations on the Handling and Storage of Aqueous Samples to be Analyzed for Hydrazine." Additional assessment of Aerojet analytical protocols was accomplished. A report providing an assessment of perchlorate, hydrazine, and NDMA analytical protocols was provided to the Region. The TSC provided the RPM an assessment of 49 analytical SOPs that are being used to analyze samples. The TSC reviewed a revised SOP for hydrazine to identify inadequacies, determine if appropriate methods are being used, and to verify consistency with EPA and state guidance. Following the finalization of all SOP's by the PRP, the RPM requested the TSC to review them and identify any deficiencies. The TSC completed the review and provided comments and suggestions to the Region. The TSC received, reviewed, and provided the Region comments and suggestions pertaining to the analytical protocol titled "Determination of Base/Neutrals and Acids Revision 3." The TSC responded to a number of inquiries dealing with "NDMA" and provided the Region with the report titled "NDMA Detection Levels for the Aerojet Superfund Site." The TSC reviewed eight revised and one new laboratory 49 ------- analytical method and provided the Region with the report titled "Review of Analytical Methods Prepared/Revised by Aerojet Laboratories July 13,2001." The TSC reviewed a number of revised Aerojet laboratory analytical methods, and provided the Region with comments and suggestions. The TSC reviewed the revised NDMA analytical method and provided comments to the RPM. The TSC was requested to review "Acculabs, Inc., SOP and App. B. Determination of Perchlorate in Water and Solid Samples Using ESI/LC/MS/MS." The TSC reviewed eight additional Aerojet analytical standard operating procedures (SOPs) and submitted comments for their improvement to the Region. The TSC also reviewed Method PAL-ES-0042 for low levels of NDMA and provided an evaluation of method effectiveness. The TSC also agreed to accept water samples from the Salton Sea, spike them with a perchlorate standard, and send the samples to a number of laboratories for analysis. Samples were spiked and three full sets made. One was provided to the Region 9 laboratory, one to the Navy at Indian Head, MD, and one to a commercial laboratory. The Region has completed their analysis, the Navy has redirected its priorities, and the commercial laboratory has gone out of business. We are waiting for further direction from Region 9 on the disposition of the remaining samples. Summary of Activities During the First Quarter FY03: During this quarter the TSC reviewed results from another commercial laboratory to determine the validity of their NDMA analysis. We have requested additional information from the laboratory via the Region in order to calculate the method detection limit and the corresponding practical quantitation limit for NDMA in water. Summary of Activities During the Second Quarter FY03: During this period the TSC completed the review of analytical results from a commercial laboratory to determine the validity of NDMA analyses. The laboratory method detection limit (MDL) and the corresponding practical quantitation limit (PQL) for NDMA in a water matrix was calculated and the lab results were verified as acceptable. The laboratory reported several NDMA in the 5 parts-per-trillion range and these concentrations were determined to be accurate based on the method used to calculate the MDL and PQL. Summary of Activities During the Third Quarter FY03: During this quarter the TSC received a request to review revised Aerojet analytical SOPs. The review will be completed during the 4th quarter of FY03. 50 ------- • Project Title: Hayden Property #2, etc. (Region 9 Data Audits) Site Location: Culver City, CA Requested Technical Support: The Regional RPM requested that the TSC provide assistance in reviewing laboratory analytical documents and perform a data audit on GC and GC/MS data from a number of sites and laboratories from around the US to investigate potential fraud issues. Sites include: Conoco/Culver City (Hayden #2), Pemaco Maywood, Midway Village, Williams AFB, Eglin AFB, and Pukola Wood Treating. Requested by: Steve Remaley (415) 972-3802 Lead Scientist: Tim Ehli, Lockheed Martin (702) 897-3279 Summary of Previous Technical Support: Previously reviews of selected volatile organic compound (VOC) and Total Petroleum Hydrocarbon-Gasoline (TPH) files were conducted for a number of commercial laboratories at a variety of sites (see above). Comments and recommendations have been communicated to the Region. Summary of Activities During the First Quarter FY03: Additional data audits were conducted on both hard and electronic copies of analytical results provided by the Region. Analytical methods evaluated were: purge-and-trap for aqueous samples, closed-system purge-and-trap and extraction for volatiles in soil and waste samples, and halogenated volatile organics. Summary of Activities During the Second Quarter FY03: During this period the TSC responded to Regional requests to provide specific evidence related to the laboratories where the sample analyses were conducted. The data audit was delivered to the Region early in the quarter. Summary of Activities During the Third Quarter FY03: During this quarter the TSC delivered a letter report responding to comments from the CAS, Inc. Laboratory and their attorneys on findings in the Lockheed Martin December 2002 data audit report. The TSC also responded to an EPA request to review previous audit reports and corroborate EPA conclusions on the general performance of each of the three CAS laboratories (Canoga Park, Redding, and Kelso). 51 ------- • Project Title: McClellan Air Force Base Site Location: Sacramento, CA Site Background: McClellan Air Force Base occupies about 2,600 acres approximately 8 miles northeast of Sacramento, Sacramento County, California. The base uses organic solvents for maintenance, repair, and modification of aircraft. In its initial investigations, the Air Force identified 46 past waste storage and disposal areas covering 56 acres within the base. Based upon disposal practices, geography, and potential threat, the 36 widely distributed areas on the base are currently considered as one site. During the 1960s and early 1970s, the areas received wastes that included dewatered industrial sludge containing trichloroethylene (TCE), 1,1,1-trichloroethane, and 1,1- dichloroethylene. The Air Force has detected these solvents in monitoring wells and in public and private wells west of McClellan. Requested Technical Support: Region 9 requested a hard copy and data tape audit of data from the Sacramento Division of STL Laboratory (formerly Quanterra or Radian) in support of the OIG review of analytical samples collected at the McClellan AFB Site. Requested by: Steve Remaley, Region 9, (415) 972-3802 Lead Scientist: Tim Ehli, Lockheed Martin, (702) 897-3264 Summary of Previous Technical Support: This is a new request related to this site. Summary of Activities During the First Quarter FY03: None, work was initiated during the second quarter of FY03. Summary of Activities During the Second Quarter FY03: During this quarter the TSC evaluated a hard copy data package and one Zip disk of laboratory data. A preliminary review of the data for the two client samples, accompanying standards, and QC samples was performed to evaluate the hard copy and electronic data for completeness and to estimate the effort required to accomplish the audit. No electronic data files were provided for the tunes, calibration standards, or QC samples. This package does not appear to be associated with the McClellan data previously received. However, the electronic files could not be opened with the software programs (e.g., ChemStation, Target) routinely used in data audits. A letter report titled "Preliminary Assessment of Hard Copy and Electronic Data from Severn Trent Services/Los Angeles (formerly Quanterra Laboratories) for McClellan AFB Superfund Site, March 13, 2003". Summary of Activities During the Third Quarter FY03: No activity during this quarter. 52 ------- • Project Title: Motorola Site Location: Phoenix, AZ Site Background: This Phoenix, Arizona site is located in a mixed residential/commercial area, and is used as a manufacturing facility. The manufacturing operations required the use of solvents. Underground storage tanks were discovered to be leaking, which resulted in groundwater and soil contamination both on and off site. The selected remedy for this operable unit addresses groundwater contamination. The primary contaminant of concern is TCE. Operable Unit Two (OU-2) is an area of contaminated groundwater down gradient of Operable Unit One (OU-1). The selected remedy is an interim remedy designed to address groundwater that is contaminated with volatile organic compounds (VOCs). The major components of this remedy consist of extraction of groundwater in the vicinity of Interstate 10 and Van Buren Street, treatment of extracted water near extraction locations by either air stripping with off-gas treatment by synthetic resin adsorption, or advanced oxidation based on final design considerations, and injection of treated water back into the aquifer in locations allowing additional control of the contaminant plume. Requested Technical Support: The RPM requested that the ESD-LV TSC provide assistance in evaluating a soil gas monitoring effort by the PRP's and assistance in characterizing site organic contaminants. The RPM has requested that costs per OU-1, OU-2, and OU-3 be documented. Requested by: Nadia Hollan (415) 972-3187 Lead Scientists: L. Peterson, North Wind (208) 528-8718x170, K. Sorenson, North Wind (208) 528- 8718 xl20, Bob Starr, INEEL Summary of Previous Technical Support: The TSC reviewed a number of site documents and provided comments. The existing data presented in site reports were of high quality but several significant data gaps were identified. Recommendations were made for installation of at least two new groundwater monitoring wells with soil gas ports. A peer reviewed paper Design, Installation, and Uses of Combination Ground Water and Gas Sampling Wells (Hubble, Wood, and Higgs, 1998) published by INEEL scientists was provided as a recommendation to assist in collection of soil gas data with installation of new groundwater wells. The TSC provided review comments on The Soil Vapor Extraction System Evaluation Report. An independent technical memorandum produced by Golder Associates (GA) was also reviewed. The GA evaluation methodology was appropriate and the conclusion that the SVE system achieved the goals of the project was confirmed. The TSC provided the Region with comments and recommendations pertaining to the 521,1 Street soil gas data analysis. The TSC received a CD Rom of scanned site documents related to soil investigations and hard copies of related items. The TSC received the document titled "Characterization of Inorganic Constituents in Groundwater, 52rd Street Superfund Site for Motorola, Inc." dated July 1999 for review. Comments were provided to the Region. Two modeling reports were received titled: "Preliminary Review of Groundwater Flow Models at the Motorola 53rd Street Superfund Site" and "Summary of Preliminary Groundwater Flow and Contaminant Transport Simulations." The TSC briefly outlines an approach for correcting major deficiencies and resolving problems identified in these reports. The TSC provided written review 53 ------- comments in a report entitled "Review of Two Groundwater Flow and Contaminant Transport Model Reports for Motorola 52rd Street Superfiind Site, Phoenix, Arizona." The TSC received six additional documents for review. A review of these documents was completed. The TSC also participated in a conference call with the RPM and the Arizona State Attorney Generals Office. The TSC reviewed ADEQ calculations pertaining to soil vapor extraction mass removal analysis and provided some recalculations. The TSC also provided the following documents to the RPM: "Review of Summary of Preliminary Groundwater Flow and Contaminant Transport Simulations Reports for OU-2 System Phoenix, AZ. Draft Version 2.0," dated August 2000 and "Review of Revised Groundwater Modeling Report on the Motorola/Honeywell OU-2 System Superfiind Site" dated August 2000. The TSC also participated in a number of conference calls and meetings in San Francisco and Phoenix, AZ. TSC representatives attended a Honeywell site review. The TSC participated in an on-site technical working group. The report titled "Review of Potential Source Areas Investigation Work Plan Honeywell International, Inc. 52rd Street Facility" was provided to the Region. A number of site documents were received (i.e., Draft Five Year Review) by the TSC and were reviewed. A report identifying additional site characterization investigations at the Honeywell Street facility was received. The TSC continued to revise the site-wide schedule with the Region and continued to develop a strategy for integration of all three OUs. The TSC was requested to review the Motorola closeout report for the SWPL SVE system. The TSC received additional groundwater monitoring data to include as part of their review related to OU-2. Overall assessment is that the site is probably not a significant contributor to the groundwater contamination. Summary of Activities During the First Quarter FY03: Numerous calls and communications with the Regional RPM occurred during this quarter. Work slowed pending the receipt of the RI work plans for OU-3 which will include the installation of wells down gradient of OU-2. Summary of Activities During the Second Quarter FY03: No activity during this period. Summary of Activities During the Third Quarter FY03: No activity during this quarter. 54 ------- • Project Title: Palos Verdes Shelf Site - Angler Survey Site Location: Los Angeles, CA Site Background: The Palos Verdes Shelf site is a large area of contaminated sediment located on the continental shelf and adjacent slope off the coast of the Palos Verdes peninsula in the county of Los Angeles, California. The primary contaminants of concern ("COCs") in the sediment can be grouped into two categories: 1) dichloro-diphenyl-trichloroethane ("DDT") and its metabolites, and 2) polychlorinated biphenyls ("PCBs"). Between 1950 and 1972, the Montrose Chemical Corporation of California manufactured the organochlorine pesticide DDT at its Torrance plant and discharged wastewater containing DDT to the local sewers, where it was conveyed to the Joint Water Pollution Control Plant ("JWPCP") owned and operated by the County Sanitation Districts of Los Angeles County ("LACSD"). Other commercial and industrial facilities discharged PCBs to the sewer system feeding the JWPCP. Wastewater from the JWPCP is discharged to the Pacific Ocean through submarine outfalls located off White Point on the Palos Verdes peninsula. It is estimated that over 1,700 tons of DDT were discharged by the JWPCP from the late 1950s to the early 1970s. DDT & PCBs which passed through the JWPCP were discharged through the White Point sewer outfalls, resulting in a large "effluent-affected" (i.e., contaminated) sediment deposit on the continental shelf and slope. The DDT contamination on the Palos Verdes Shelf and in the Southern California Bight has been the subject of scientific studies since the early 1970s. In 1990, federal and state natural resource trustees (collectively referred to as the "Trustees"), filed a natural resource damage claim against Montrose and other parties and began an extensive site characterization as part of a natural resources damage assessment ("NRDA") under CERCLA. The resulting expert reports were issued in October 1994. In July 1996, following a 19-month review of the data and information regarding contamination on the Palos Verdes Shelf, EPA formally initiated an engineering evaluation/cost analysis (EE/CA) under the Superfund program to evaluate both risks to human health and the environment and possible response actions to address those risks. In March 2000, EPA issued a proposed plan that recommended the use of institutional controls (ICs) as an initial step to address the existing human health risks posed by the contaminated sediments at the site. The three components of the PVS ICs include increased enforcement of existing commercial and recreational fishing restrictions, public outreach and education, and monitoring. In order to design an effective outreach and education program that addresses the population at risk, EPA needs to gather updated fishing and fish consumption information. EPA and the Trustees are jointly undertaking an angler survey at fishing locations from Point Dume in Ventura County to Dana Point near Newport Beach. There are two phases of the Angler Survey. For the Phase 1, which was conducted in Fall 2002, 1181 surveys were completed at 24 fishing sites. 20 questions with sub- questions were asked in Phase 1 survey. EPA and the Trustees plan on conducting the Phase 2 survey in Summer 2003. For more detail see: http://ycsemjte.epa. EO>/r^/sfi]nii'o^erview.ri5C'5[nc94f73Qe0etf48B256958C05c(la5ffc'738f63d3SSS666f8B256(102Q[n5ccl4 ?OpenDocament for information on the background of the site. 55 ------- Requested Technical Support: EPA Region 9 seeks technical assistance in running cross tabs analysis of the survey results. For instance, fishing and consumption patterns for an ethnic angler community may be needed to better design and guide an effective public outreach program targeted for the group of interest. The statistical applications that have been used by the Region 9 contractor are SPSS (Statistical Package for the Social Sciences) and SAS. The Region 9 contractor will provide with the survey data in a format that can be analyzed by either the SPSS or SAS statistical tool. Requested by: Sharon Lin, Region 9, 415-972-3446; Mike Gill, HSTL Region 9,415-972-3054 Lead Scientist: Anita Singh, Lockheed Martin Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter ofFY03. Summary of Activities During the Third Quarter FY03: The TSC participated in a conference call with Sharon Lin, RPM EPA Region 9. We reviewed material related to the Angler Survey questionnaire, Power Point Document for Phase I Study and the SAS Phase 1 data base provided by the Region. 56 ------- • Project Title: Phoenix 19th Ave Landfill Site Location: Phoenix, AZ Site Background: This 213-acre site operated as a landfill between 1957 and 1979, during which about 9 million cubic yards of municipal refuse, solid and liquid industrial wastes, and some medical wastes were deposited. However, the site was closed in 1979 due to the threat of flooding from the Salt River Channel. This remedial action is designed to mitigate threats resulting from flooding. The primary contaminants of concern in the soil/refuse include VOCs such as toluene and xylenes. Requested Technical Support: The RPM requested that the ESD-LV TSC provide assistance in reviewing ambient air monitoring and monitoring plans. Requested by: Nadia Hollan (415) 744-2363 Lead Scientist: Mike Abbott, INEEL (208) 526-8596 Summary of Previous Technical Support: The TSC received three documents for review: The Ambient Air Monitoring Plan and two Ambient Air Monitoring reports. Following the review it was felt that the four landfill air sampling tests were well conducted and that the results showed differential concentrations that were well below levels of concern. However, the number of samples (total of 8 events per cell) was not adequate to draw the conclusion that long-term VOC emissions from the landfill are of no concern. The sampling experimental design (discrete 4-hour upwind/downwind samples) has two inherent and compounding limitations that cannot be overcome with a limited number of samples, therefore, some additional sampling was recommended. The TSC received a request from the RPM for information on Open Path Fourier Transform Infrared Spectrometry (FTIR), and whether it could be a useful tool at the landfill. The TSC responded with some background information on the technology and some experience at INEEL using this technology. The TSC believes that this technology would be a useful tool to address the landfill issues. The TSC received volumes 1 and 2 of the Ambient Air Monitoring Program Report and the Ambient Air Monitoring Plan for review. The review of these documents was completed and the report titled "INEEL Review Comments on the Ambient Air Monitoring Program Report for the 19th Avenue Landfill- Phase H" was provided. A number of conference calls with the RPM were completed. The TSC received information pertaining to the Region's review of the Phase II Ambient Air Report. The TSC completed the review of the "Phase II Report" and participated with the RPM and a Region 9 Toxicologist, in a review, and discussion of the Phase 2 Ambient Air Monitoring Program. Summary of Activity During the First Quarter FY03: During this quarter the Region requested the TSC to interpret the results of existing analytical results using 4 sets of assumptions concerning the concentrations of the compounds of concern. Progress is being made on this request and a report of results is anticipated early in the next quarter. Summary of Activity During the Second Quarter FY03: A draft report was completed in January, and a final letter report was delivered on 4 February. Summary of Activities During the Third Quarter FY03: Data and documents related to cost recovery 57 ------- efforts were provided this quarter. 58 ------- Project Title: Purity Oil - Audit of Analytical Data from EMAX Laboratories Site Location: Malaga, CA Site Background: See http://www.eDa.gov/superfund/sites/querv/rods/r0992086.htm for background data on the site. Requested Technical Support: The purpose of the audit is to assess the conformance of the data packages to the applicable methods and to good laboratory practices and commonly accepted standards of industry performance and protocols. Specifically, the audits should be focused to address possible laboratory causes or deficiencies that might account for wide divergences between reported data results and the data results that were expected at the site based on field tests and observations and also on previous sampling and analysis of collected. Requested by: Steve Remaley, Region 9, 415 972-3802 Lead Scientist: Tim Ehli, Lockheed Martin, 702 897-3264 Summary of Previous Technical Support: None, new site. Summary of Activities During the First Quarter FY03: None, work was initiated during the third quarter of FY03. Summary of Activities During the Second Quarter FY03: None, work was initiated during the third quarter ofFY03. Summary of Activities During the Third Quarter FY03: During this quarter the TSC provided a preliminary review of the data submitted by EMAX Laboratories. The review included the assessment of one volatile organic compound (VOC) and one polychlorinated biphenyl (PCB) data package to verify the presence and acceptability of calibration standards and QC samples, and the general evaluation of 33 data sets from 4 sample delivery groups (SDGs) to estimate the effort required to accomplish an audit of each SDG. The TSC delivered an audit report on mercury by Cold Vapor Atomic Absorption (CVAA), metals by Inductively Coupled Plasma Spectroscopy (ICP), and pH data from each of the four SDGs. The report included an overview of laboratory performance and primary findings as well as detailed audit comments by SDG and by analytical method. 59 ------- Region 10 The TSC technical support activity (>$1,000) in Region 10 during the first three quarters of FY03 is summarized below. No minor technical support activities (<$ 1,000) occurred in the Region during this quarter. See the table at the end of the report for a funding history of site currently being supported by the TSC. • Project Title: Camp Bonneville (UXO) Site Location: Clark County, WA Site Background: Camp Bonneville is a 3,839 acre located about 10 miles northeast of Vancouver, WA, that has been utilized by the Army and others for training exercises for about 85 years. Large residential developments, densely forested lands, and small farms bound the property on all sides. The Army used the site for live fire of small arms, assault weapons, artillery, and field and air defense artillery between 1910 and 1995. Since 1947 the site has also been used by the National Guard, Army Reserves, Air Force, and federal, state, and local law enforcement agencies. In 1995 the site was selected for closure. Requested Technical Support: The Region requested the TSC to provide assistance in reviewing the Unexploded Ordnance (UXO) Statistical Sampling and Risk Assessment Methodology. This methodology was developed for conducting engineering/cost analysis and UXO investigations for various ordnance and explosives located on Formerly Used Defense Sites (FUDS). Requested by: Harry Craig (503) 326-3689 Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 Summary of Previous Technical Support: The TSC provided reviews of a number of site documents and data and created a database for further analysis. A number of simulations for assessing the Army methodology/models (i.e., UXO Calculator) were completed. A report titled "Interim Evaluation of US Army Corps of Engineers Statistical UXO Sampling and Characterization Methodologies" was completed and delivered to the Region and OSWER. This report was prepare as a draft final and distributed for addition review. TSC personnel met with the USACE to discuss proposed improvements to their methodology. The TSC completed a number of statistical tests pertaining to the characterization of UXO. These results were delivered in two reports titled "Summary of Recent Results on Site Stats Evaluation Performed After the August 9-10 Partnership Meeting Between USACE and EPA NERL-Las Vegas" and "UXO Samples and Characterization Using Indicator Kriging - An Alternative Approach for Estimating Probabilities of Finding UXO Items." Summary of Activity During the First Quarter FY03: During this quarter Dr. Anita Singh, Lockheed Martin attended the UXO Technical Advisory Committee meeting in Washington, D.C., December 2002, at their request. The TSC also reviewed the status of the three ongoing projects to develop UXO distribution software. Summary of Activity During the Second Quarter FY03: No activity during this quarter. 60 ------- Summary of Activities During the Third Quarter FY03: No activity during this quarter. 61 ------- Superfund Short-Term Requests Short-term requests are those that can generally be completed within a 8-hour period. Projects may include: • Emergency Technical Advice - on-site field measurements, such as geophysics, soil gas, and XRF. • Emergency Technical Advice - laboratory support, such as the analysis of chemical and radiological contaminants. • Quick review of reports and work plans, sampling/monitoring protocols, and analytical protocols and approaches. • Quick review of techniques and methods used on site assessment and statistical methods proposed for data analysis/evaluation. • Providing expert testimony and/or contributing to the validity and authenticity of data used in cost recovery cases. • Support of the implementation of technologies, methodologies, and software developed by the TSC or others in the Office of Research and Development. The following table summarizes the short-term support requests received during the 3"1 quarter. REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST 3 April Chem-Solve D. Rossi 215-814-3228 Statistical Support 9 June Conoco/Hayden Steve Remaley 425-972-3802 Report TN June David Escew 865-220-9000 ProUCL Help June Charles Ake Method 1312 6 April Mt. Creek Lake Rich Mayer 214-665-7442 Statistical Support CA May M. Rodriquez 210-536-4755 ProUCL Help 2 June Hudson River Benny Conetta Statistical Help TN June David Eskew 856-220-9000 ProUCL Help June Russ Plumb 702-897-3265 Work Review CO June Rick Roberts 303-531-41101 ProUCL Help 1 April Caroline Casey 617-918-1368 ProUCL 62 ------- REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST 1 April Newport Naval Chau Vu 617-918-1446 Statistical Help 1 April Caroline Casey 617-918-1368 Statistical ? 1 April R. Maddox 617-395-5511 ProUCL 1 April Newport Naval Chau Vu 617-918-1446 Statistical Help 1 April Newport Naval Chau Vu 617-918-1446 Statistical Update April Brian Megham 619-687-8717 ProUCL Help 1 April Newport Naval Chau Vu 617-918-1446 Statistical Update 6 April Mountain Creek Rich Mayer 214-665-7442 Information 3 April Chem-Solve D. Rossi 215-814-3228 Statistical Help 3 May Langley AFB Michelle Price 215-814-3397 Question 9 May McClellan AFB Kerry Gilmour 415-947-4506 Report Request TX May M. Rodriquez 210-536-4755 ProUCL 10 May B. Zavala 206-553-1562 Tech Information 9 May Conoco/Hayden S. Remaley 415-972-3802 Information DC June Linda Perry LAG Questions 9 June Purity Oil/EMAX Kerry Gilmour 415-947-4506 Audit Question TN June David Eskew 865-220-9000, ProUCL Help 1 June Hudson River Anita Singh 702-897-3234 Reg. 1 Request 8 May State of MT Laura Kuzel 404-444-1967 Help Inquiry 8 May Gilt Edge Ken Wangerud 303-312-6703 Support 3 May Todd Richardson 215-814-5264 Support 10 May Ken Marcy 206-553-2782 Support 7 April KC Plant Project Scott Marquess 913-551-7131 Mycelx 9 June A. Sheldon 213-996-2497 ProUCL FL June Bruce Tuovila 850-681-6894 Statistical Help TN June David Eskew 865-220-9000 ProUCL Problem 4 June Karen Martin 850-681-6894 Issue Paper 63 ------- REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST 7 April Scott Marquess 913-551-7131 Myclex Info. Ohio May D. Reisman 513-569-7588 Conference CO April Teresa Doegnes Issue Paper CO May Roger Goffredi 303-526-2674 Issue Paper IN June Brian Wolff Issue Paper CO May A. Pulley Issue Papers La June D. Dickey 225-292-9007 ProUCL MT June M. Canty 406-442-0205 ProUCL FL June C. Marcussen 352-692-2205 Problem ProUCL IL June D. Tiebout 312-578-9243 ProUCL VA June Kelly Hicks 804-474-5443 Problem ProUCL CA May Michele Amaral 703-834-0076 Problem ProUCL OR April Sue McMillan 971-544-2139 Problem ProUCL Australia April David Franklin ProUCL OR April H. Brunelle ProUCL Malaysia April Ng. Hon Seng ProUCL WI April M. Kierski ProUCL CT April K. Vetrano ProUCL CA April Boris Stolin ProUCL MA April Ruth Lyddy ProUCL Texas April K. Boyce ProUCL CA April Chih Lun Taso ProUCL Ohio April M. Shaskus ProUCL Ontario May Dan Clowater ProUCL CA May David Jeffrey ProUCL OR May J. Peterson ProUCL Brazil May M. Gallo ProUCL 64 ------- REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST CO May Dennis Smith ProUCL VA June D.Wilhelm ProUCL KY June W. P. Puckett ProUCL Utah April Rich White ProUCL NY April B. Yakubovich ProUCL ME April P. Gwinn ProUCL CA April H. Robles ProUCL KY April Jim Knauss ProUCL CA April Donald Clark ProUCL RI April P. Corcoran ProUCL CA April M. Bowland ProUCL GA April Dana McCue ProUCL CA April Mark Rigby ProUCL Australia April Martin Howell ProUCL Edinburgh April Jeremy Fox ProUCL MD April Rosa Gwinn ProUCL PA April Ann Baines ProUCL CA April Julio A. Salinas ProUCL CA April H. Singh ProUCL TX April M. McConnell ProUCL DE April T. Hassett ProUCL NY April Steve Shost ProUCL PA April H. Fazekas ProUCL IL April B. Snday - ProUCL CA May Carolyn Mann ProUCL SC May Peggy Zabel ProUCL MA May A. DiBenedetto ProUCL 65 ------- REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST TX May Mark Harris ProUCL CA May Cameron Tana ProUCL UT May C. Bittmer ProUCL TX May S. Trimble ProUCL Hawaii May Brenda Nuding ProUCL Australia May A. Simopolos ProUCL FL May Karen Martin ProUCL CA May Mark Jones ProUCL NM May Emily Day ProUCL IL May Stuart J. Cravens ProUCL CA May Susan Shiu ProUCL NJ May Steve Posten ProUCL DC May Davie Steckler ProUCL MA May Michael Bock ProUCL TN May Jon Lindberg ProUCL LA May Jason Kase ProUCL TX May M. Rodriguez ProUCL VA June C. Martins ProUCL TX June B. J. Lee ProUCL UT June J.Christensen ProUCL GA June Laura Smith ProUCL KY June Paul Puckett Dup. ProUCL CO June Rick Roberts ProUCL TN June Sara Mathews ProUCL CA June Chuck Lambert ProUCL PA June Daniel Smith ProUCL VA May Michael Ginevan Problem ProUCL 66 ------- REGION/ STATE DATE SITE REQUESTOR TELEPHONE NUMBER NATURE OF REQUEST FL June C. Marcussen Problem ProUCL NY June LMES Tim Ehli 702-897-3264 ProUCL CD OK TX M. Rodriquez Problem ProUCL Short-term Support - Provided bv ESP Federal Staff In addition to providing technical support via extramural vehicles, the TSC also provides support to the Regions with in-house technical staff when there is a technical match and the staff member has time available. The follow table summarizes the support provided by Federal ESD staff during the 3rd quarter FY03. REGION / OFFICE REQUESTOR SITE/ PROGRAM REQUESTED SUPPORT ESD SCIENTIST TOTAL HOURS Region 9 K. Kitchingman Casmalia, CA Application of Geophysical Tools Aldo Mazzella, Steve Gardner, Dale Werkema 9 Region 1 S. Levison Ft. Devens, MA Background Concentration Statistical Support Evan Englund 40 Region 1; State of PA S. Mangion, S. Johnson Olin Chemical, MA Expert Chemical Assessment and Advice G. Wayne Sovocool, Andy Grange 40 Region 9 M. GUI Rialto - Colton Perchlorate Expect Chemical Advice on Pyrotechnical Manufacturing Processes John Nocerino 1 Region 6 Rafael Casanova Many Diversified Interests, Inc., Houston, TX Assistance in determining source of lead contamination in an urban setting. Evan Englund Jeff van Ee Ed Heithmar 5 Total 95 67 ------- Issue Papers/Software Issue Papers None for this quarter. ProUCL Statistical Software Upgrades OSWER issued a guidance document titled "Calculating Upper Confidence Limits for Exposure Point Concentrations at Hazardous Waste Sites" that incorporates and recommends the use of the ProUCL software " ... for calculating UCLs, and are intended as tools to support risk assessment." As a result the TSC has received funding from OSRTI to functionally and technically upgrade ProUCL to incorporate a number of technical advances and to address some of the "install" issues that are occurring with some of the Windows operating systems. To date algorithms to compute the critical values of Kolmogorov-Smirnov test and the Anderson- Darling test to be used to perform the goodness-of-fit test for gamma distribution have been completed. A simulation program was wtitten to compute the critical values for these two test and will be incorporated into ProUCL. Requested by: Jayne Michaud, OSRTI Lead Scientist: Anita Singh, Lockheed Martin (702) 897-3234 68 ------- Miscellaneous Support • Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM) The Office of Radiation and Indoor Environments (R&IE) Project Officer requested that the ESD-LV provide assistance in supporting the development of sampling/monitoring approach for radiologically contaminated sites. R&IE has provided all funding resources for this project. The Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM) Workgroup has been meeting since January 1994 with the objective of developing principles and processes for conducting final site closure surveys at radiologically contaminated sites. The agencies involved are the Department of Defense, Nuclear Regulatory Commission, Environmental Protection Agency, and the Department of Energy. The MARSSIM was published in 1997, and is a consensus guidance manual for conducting Superfund and non-Superfund characterization, final status, and/or cleanup verification radiation surveys of surface soils (not more than 6 in. deep) and building surfaces. Having completed the surface soil manual, the MARSSIM Workgroup is expending their scope to add two supplements. The supplements will address 1) surveying contaminated materials and equipment for free release, and 2) cleanup verification surveys of the subsurface. NRC is taking the lead on the supplement for materials and equipment. The subsurface supplement is currently titled Multi-Agency Radiation Survey and Assessment of Subsurface Soils (MARSASS). The ENEEL will provide Subject Matter Experts (SMEs) in the area of monitoring, sampling and surveying of radioactive contaminants in subsurface soils (>6 in. beneath the surface). These SMEs will assist EPA (and the other MARSASS signatory agencies) in developing new state-of- the-science subsurface contamination characterization and cleanup methodologies. A number of meetings were attended by the lead scientist. During the first two quarters FY03 the TSC transmitted the literature review to Environmental Response Team - West (ERT-West) on 6 January 2003. ERT-West responded that they were not going to do much with it until after the work group has the consult with the EPA Science' Advisory Board (SAB). There was no activity on this task during the 3rd quarter of FY03. ERT- West has decided to continue the effort. We anticipate additional funding being made available during the 4th quarter. Requested by; Colleen Petullo, ERT-West (702) 798-2446 Lead Scientist: Larry Hull, INEEL (208) 526-1922 69 ------- Technical Support Center for Monitoring and Site Characterization - Las Vegas, NV Active Sites Funding History FY99 - FY03 ($K) Site FY99 FY00 FY01 FY02 FY03* Total I** L*** Total I L Total I L Total I L Total I L Total Region 1 Army Mat. Tech. Lab. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 16.4 16.4 16.4 GE Housatonic 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8.1 8.1 0.0 5.8 5.8 13.9 Loring Air Force Base 0.6 0.0 0.6 17.1 0.0 17.1 0.0 0.0 0.0 0.0 2.2 2.2 0.0 0.0 0.0 19.9 Camp Edwards / Otis MMR 15.5 0.0 15.5 24.0 0-0 24.0 19.8 0.0 19.8 0.0 4.6 4.6 2.2 3.8 6.0 69.9 Dover Municipal Landfill 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.6 0.6 0.6 Newport Naval ETC 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.0. 2.0 2.0 Olin Chemical 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.1 6.1 6.1 Savage Well OU1/2 39.0 0.0 39.0 3.8 0.0 3.8 4.6 0.0 4.6 20.9 0.0 20.9 0.0 0.0 0.0 68.3 South Weymouth NAS 0.0 4.9 4.9 0.0 15.5 15.5 0.0 0.0 0.0 0.0 4.6 4.6 0.0 0.0 0.0 25.0 Union Chemical 0.0 11.9 11.9 0.0 0.0 0.0 0.0 0.0 0.0 0.9 0.0 0.9 0.0 0.0 0.0 12.8 Totals 71.9 60.4 24.4 41.3 36.9 234.9 Region 2 Caldwell Trucking 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.1 0.0 2.1 2.4 0.0 2.4 4.5 Ciba-Geigy 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 4.1 4.1 0.0 0.0 0.0 4.1 70 ------- Site FY99 FY00 FY01 FY02 FY03* Total I** L*** Total I L Total I L Total I L Total I L Total Chemical Leaman Tank Lines 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 14.5 14.5 14.5 Cornell Dubilier Elect 0.0 0.0 0.0 0.0 0.0 0.0 0.0 7.7 7.7 0.0 22.0 22.0 0.0 0.8 0.8 30.5 Diamond Alkali 0.0 3.8 3.8 0.0 0.0 0.0 0.0 7.2 7.2 0.0 6.0 6.0 0.0 0.0 0.0 17.0 Hilliards Creek/ Sherwin Williams 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 7.3 7.3 0.0 0.3 0.3 7.6 Hooker Chem / Ruco 14.9 0.0 14.9 11.5 0.0 11.5 0.1 0.0 0.1 1.3 0.0 1.3 0.0 0.0 0.0 27.8 Hudson River PCBs 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.8 6.8 0.0 6.5 6.5 13.3 Liberty Ind. Finishing 0.0 0.0 0.0 21.0 0.0 21.0 9.3 0.0 9.3 2.0 0.0 2.0 0.3 0.0 0.3 32.6 Middlesex Sampling Plant 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.4 1.4 1.4 Peter Cooper Corp 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.5 2.5 2.5 Reich Farm 0.0 0.0 0.0 0.0 0.0 0.0 35.7 0.0 35.7 0.2 4.2 4.4 0.0 0.0 0.0 40.1 Rt 561 Dump / Sherwin Williams 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 9.0 9.0 0.0 0.0 0.0 9.0 Shenandoah Road Groundwater 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.1 2.1 2.1 Solvent Savers 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.1 0.0 3.1 0.0 0.0 0.0 3.1 Stanton Cleaners 0.0 0.0 0.0 21.0 0.0 21.0 11.6 0.0 11.6 1.5 0.0 1.5 0.3 0.0 0.3 34.4 US Ave Burn Site / Sherwin Williams 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.5 6.5 0.0 0.0 0.0 6.5 Vieques Island 0.0 0.0 0.0 0.0 0.0 0.0 0.0 4.6 4.6 0.0 0.9 0.9 0.0 0.0 0.0 5.5 Totals 18.7 53.5 76.2 77.0 31.1 256.5 71 ------- Site FY99 FY00 FY01 FY02 FY03* Total I** L*** Total I L Total I L Total I L Total I L Total Region 3 Big John Salvage 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.0 3.0 0.0 0.0 0.0 3.0 Chem Solve Inc 0.0 0.0 0.0 5.0 0.0 5.0 5.0 0.0 5.0 2.0 0.0 2.0 0.0 0.0 0.0 12.0 Fairmont Coke Works 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.3 3.3 0.0 0.0 0.0 3.3 Langley AFB 0.0 0.0 0.0 0.0 0.0 0.0 11.7 0.0 11.7 2.1 0.0 2.1 12.1 1.8 13.9 27.7 Letterkenny Army Depot 0.0 0.0 0.0 0.0 6.0 6.0 4.8 0.0 4.8 0.8 0.0 0.8 0.1 0.0 0.1 11.7 Md Sand Gravel & Stone 0.0 0.0 0.0 0.0 23.0 23.0 0.0 11.8 11.8 0.0 0.2 0.2 0.0 0.0 0.0 35.0 Navy Surf Warfare Center, White Oak 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 7.7 7.7 0.0 0.0 0.0 7.7 Norfolk Naval Shipyard 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 5.4 5.4 0.0 0.0 0.0 5.4 Occidental Chem / Firestone Tire 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.9 2.9 0.0 8.8 8.8 0.0 9.1 9.1 20.8 Ohio River Park 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.3 2.3 2.3 Quantico, MCCDC 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.8 0.0 1.8 13.1 0.0 13.1 14.9 Sharon Steel 0.0 0.0 0.0 0.0 47.2 47.2 5.9 72.9 78.8 0.0 24.1 24.1 0.1 3.9 4.0 154.1 Standard Chlorine of Delaware 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.7 6.7 0.0 0.0 0.0 6.7 Valmont TCE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 17.8 17.8 17.8 Totals 0.0 81.2 115.0 65.9 60.3 322.4 72 ------- Site FY99 FY00 FY01 FY02 FY03* Total I** L**» Total I L Total I L Total I L Total I L Total Region 4 Distler Brickyard 11.4 0.0 11.4 34.1 0.0 34.1 68.2 0.0 68.2 51.1 0.0 51.1 2.6 0.0 2.6 167.4 Distler Farm 0.0 0.0 0.0 0.0 0.0 0.0 2.9 0.0 2.9 27.8 0.0 27.8 0.1 0.0 0.1 30.8 Duracell Battery Tech 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 14.3 0.0 14.3 0.7 0.0 0.7 15.0 Estech Gen Chemicals 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.2 0.0 0.0 0.0 0.2 FCX Statesville Plant 0.0 0.0 0.0 13.0 0.0 13.0 0.0 0.0 0.0 1.2 0.0 1.2 0.3 0.0 0.3 14.5 Malloiy Capacitor 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.9 0.0 3.9 2.1 0.0 2.1 6.0 Nocatee Hull Creosote 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 22.3 22.3 22.3 Northeast Chemical 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.1 0.0 0.0 0.0 0.1 Roanoke River Study 0.0 0.0 0.0 0.0 0.0 0.0 0.0 44.7 44.7 0.0 19.4 19.4 0.0 0.9 0.9 65.0 Shuron Inc 0.0 0.0 0.0 4.5 0.0 4.5 7.4 0.0 7.4 1.7 0.0 1.7 0.0 0.0 0.0 13.6 Tower Chemical 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8.1 8.1 0.0 0.0 0.0 0.0 0.0 0.0 8.1 Totals 11.4 51.6 131.3 119.7 29.0 343.0 Region 5 Fort Sheridan Landfill 0.0 0.0 0.0 0.0 0.0 0.0 5.3 0.0 5.3 14.5 0.0 14.5 0.1 0.0 0.1 19.9 Jefferson Proving Grd 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.1 6.1 0.0 0.0 0.0 6.1 0.0 0.0 5.3 20.6 0.1 26.0 73 ------- Site FY99 FY00 FY01 FY02 FY03* Total I** L*** Total I L Total I L Total I L Total I L Total Region 6 ASARCO El Paso 0.0 0.0 0.0 0.0 0.0 0.0 0.0 26.7 26.7 0.0 9.6 9.6 0.0 6.4 6.4 42.7 Mountain Creek 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 14.3 14.3 14.3 Sol Lynn Indus Transf. 0.0 0.0 0.0 24.3 0.0 24.3 31.9 0.0 31.9 24.5 0.0 24.5 18.6 0.0 18.6 99.3 Texarkana 49.7 0.0 49.7 0.9 0.0 0.9 1.6 0.0 1.6 0.3 0.0 0.3 1.8 0.0 1.8 54.3 Totals 49.7 25.2 60.2 34.4 41.1 156.3 Region 7 ASARCO Lead Site 8.4 0.0 8.4 0.0 16.3 16.3 0.0 14.1 14.1 0.0 24.0 24.0 0.0 2.0 2.0 64.8 Big River / Herculaneum 0.0 26.4 26.4 0.0 17.3 17.3 0.0 19.1 19.1 48.8 9.4 58.2 0.0 0.0 0.0 121.0 Eagle-Pitcher Site 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 15.1 0.0 15.1 10.1 0.0 10.1 25.2 Oronogo-Duenweg Mining Belt 0.0 0.0 0.0 0.0 9.7 9.7 0.0 12.8 12.8 0.0 8.5 8.5 0.0 0.0 0.0 31.0 Totals 34.8 43.3 46.0 105.8 12.1 242.0 Region 8 Eureka Mills 0.0 0.0 0.0 0.0 0.0 0.0 0.0 16.0 16.0 0.0 25.6 25.6 0.0 8.1 8.1 49.7 Gilt Edge Mine 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 62.0 0.0 62.0 0.0 0.0 0.0 62.0 Lowry Landfill 0.0 0.0 0.0 19.2 27.4 46.6 5.5 0.0 5.5 0.1 0.0 0.1 0.0 0.0 0.0 52.2 Totals 0.0 46.6 21.5 87.7 8.1 163.9 74 ------- Site FY99 FY00 FY01 FY02 FY03* Total I** L*** Total I L Total I L Total I L Total I L Total Region 9 Aerojet General Corp 0.0 4.3 4.3 0.0 28.1 28.1 0.0 28.5 28.5 0.0 23.9 23.9 0.0 8.7 8.7 93.5 Casmalia Disposal Site 0.0 0.0 0.0 0.0 0.0 0.0 1.2 0.0 1.2 5.2 0.0 5.2 0.0 0.0 0.0 6.4 Fort ORD UXO 2.1 0.0 2.1 0.0 0.0 0.0 0.0 17.7 17.7 0.0 16.1 16.1 0.0 0.0 0.0 35.9 Hayden (Data Audits)**** 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 86.5 86.5 0.0 15.8 15.8 102.3 McClellan AFB 0.0 11.4 11.4 0.0 13.0 13.0 0.0 0.0 0.0 0.0 0.3 0.3 0.0 2.6 2.6 27.3 MGM Brakes 0.0 0.0 0.0 0.0 21.5 21.5 0.0 36.7 36.7 0.0 40.5 40.5 0.0 1.2 1.2 99.9 Motorola (All OUJs) 4.0 0.0 4.0 27.5 0.0 27.5 22.1 0.0 22.1 17.2 0.0 17.2 2.7 0.0 2.7 73.5 Palos Verdes Shelf 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.6 1.6 1.6 Phoenix 19th Ave Landfill 0.0 0.0 0.0 5.3 0.0 5.3 14.0 0.0 14.0 0.0 0.0 0.0 10.7 0.0 10.7 30.0 Purity Oil - EMAX 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 6.5 6.5 6.5 Totals 21.8 95.4 120.2 189.7 49.8 476.9 Region 10 Bunker Hill Mining 0.0 0.0 0.0 15.6 0.0 15.6 26.2 0.0 26.2 0.0 0.0 0.0 0.0 0.0 0.0 41.8 Camp Bonneville (UXO) 0.0 0.0 0.0 0.0 42.3 42.3 0.0 17.8 17.8 0.0 0.0 0.0 0.0 4.1 4.1 64.2 0.0 57.9 44.0 0.0 4.1 106.0 75 ------- * Costs, Year to Date ** I = Idaho National Environmental Engineering Laboratory via LAG with DOE *** L = Lockheed Martin via IAG with GSA **** Data Audits were conducted for Region 9 at the following sites: Conoco/Culver City (Hayden #2), Pemaco Maywood, Midway Village, Williams AFB; Eglin AFB, and Pukola Wood Treating. 76 ------- |