t SUPERFUND Records Of Decision Update From: Hazardous Site Control Division February 20, 1987 To: EPA Regional Offices Vol. 3, No. 1 PEPPER'S STEEL AND ALLOYS (PSA) REGION IV DESCRIPTION OF REMEDY AND USE OF LEACH TESTS TO HELP ESTABLISH CLEAN- UP LEVELS Background The 30-acre PSA site is located on Northwest South River Drive in Medley, Florida. Business operations at the site have resulted in the contamination of soils that lie over the Biscayne aquifer. The endangerment assessment conducted for the PSA site identified PCBs, lead, and arsenic as present in soils at the site in concentrations high enough to pose a significant threat to public health or the environment. After various alternatives to pro- tect the aquifer from site con- tamination were evaluated, fixa- tion/solidification was selected as the best alternative to clean up the site. PCB-contaminated soils would be excavated and solidified; soils contaminated with heavy metals would be stabilized by chemical fixation. This would be accomplished by mixing soils with cement and fly ash to form a solid, concrete-like material (or monolith). Fieldwork and Results An extensive testing program was conducted by EPA and Florida Power and Light (FP&L) to determine if the stabilized/ solidified material would retain its structural integrity and re- main an effective remedy. Tests were conducted using actual soils from the site. These soils were "spiked" with extra con- tamination to be sure the tests were being conducted for the worst possible contamination at the site. Solidified cylindrical samples were created that mixed soils with fixing agents, and these were subjected to many tests. The fixing agent that met all requirements was a mix- ture of 40 percent Portland ce- ment (Type I) and 60 percent fly ash (Class F). The fixing agent was mixed with the soil at a 0.5 to 1 ratio on a dry weight basis. Leach Test The fixing agent selected (60 percent fly ash, 40 percent ce- ment) was designed to meet leaching performance criteria for lead and PCBs over a geologic time scale (periods greater than 100 years). The FP&L study incorporated three different leaching tests. Two of those tests were used to simulate the leaching scenario that might occur in the Medley area. The third (the EP Toxicity Test) was run to comply with EPA's request and is not con- sidered representative of the leaching processes that may oc- cur at the PSA site. Following are the three leaching procedures used in the FP&L study and their intended use: 1. Modified version of the MCC-1 Static Leach Test- used to determine the con- stituent concentrations as they approached equili- brium between the fixed soils and leachate, 2. Modified ANS 16.1 Multiple Extraction Procedure — used to measure the fractional release of a given component fromaspeci- men, and 3. EP Toxicity Test — used to determine whether or not a material is classified as EP toxic under RCRA hazar- dous waste rules (40 CFR 261). Residual Management The objectives of the monitoring program for the PSA site are to: 1. Establish baseline water- quality data on analytes of concern in the bedrock aquifer, prior to remediation; 2. Continue characterization of the flow field below the site; 3. Make a periodic assess- ment of water quality for lead and arsenic in the bedrock aquifer; and 4. Make a periodic assess- ment of PCBs below the monolith to test, the monolith's effectiveness. The monitoring program will be performed in three stages: ------- 1. Baseline monitoring, 2. Remediation monitoring, and 3. Post-remediation data monitoring. The monitored parameters of concern and field measure- ments are: 1. PCBs at 1.0 Mg/I detection limit, in monolith wells only, 2. Lead at 1.0 pg/l detection limit, 3. Arsenic at 1.0 jug/l detection limit, 4. pH measured in the field and checked in the lab, and 5. Specific conductance measured in the field and checked in the lab. The action levels established for the PSA remedy are: 1. PCBs at 7 hqI\ in monolith wells, 2. Lead at 50 iug/l in monitoring well series, and 3. Arsenic at 50 ^g/l in monitor- ing well series. If monitoring confirms that levels have been exceeded, then a review will be conducted to determine which, if any, re- medial measures need to be taken to address the situation. If monitoring does not confirm that levels have been exceeded, monitoring for water quality in the well in which the exceeding of levels may have occurred will be conducted on a quarterly basis for 1 year. The entire monitoring program will be re- assessed 3 years after remedia- tion is completed and/or if long- term changes in ground water flow directions are determined. Contact: • Region: John Kroske FTS 257-2643 ROD SUMMARIES VESTAL WATER SUPPLY WELL 1-1 REGION II NEW YORK (Approved 6/27/86) Description: • A chemical spill in 1978 pre- cipitated extensive testing of selected water supply wells in the city of Vestal, New York. Volatile organic compounds (VOCs) were found in two of the water supply wells, al- though it was determined that the VOCs probably did not result from the 1978 spill. The two wells were placed on the NPL as one site but were later separated when it was deter- mined that the probable sources of contamination for each well were different. The concentration of total VOCs in April 1985 was 241 ppb in Well 1-1. The City of Vestal re- ceived an NPDES permit to discharge the water from Well 1-1 directly into the Sus- quehanna River. No surface contamination was found at the site, although borings showed the possibility of a contaminant source at depths greater than 5 feet. Decision: • Construct a packed-column air stripping system on Well 1-1; treat water to 10~6 cancer risk for trichloroethene ex- posure; discharge treated water into water supply system. • Conduct a supplemental re- medial investigation/feasibil- ity study to determine the nature and extent of contami- nation in suspected source areas. Contacts: • Region: Ed Als FTS 264-0522 • Headquarters: Bob Quinn FTS 382-2350 (Also see "Onsite Insights") INDUSTRIAL LANE SITE REGION III PENNSYLVANIA (Approved 9/29/86) Description: • The site covers approximate- ly 2 square miles and in- cludes a state-permitted landfill, several existing and historic industrial sites, relic iron ore extraction areas, and residences. Some industrial operations at the site date from 1840. The area is geo- logically complex. Low-level ground water contamination was detected in 1980 in private wells. Further studi during the remedial in vestigation confirmed the existence of contamination including tetrachloro- ethene, trichloroethene, 1,1,1-trichloroethane, and chloroform up to a 2x10 5 cancer risk level. Decision: • Provide alternative water supply to affected residents by hooking up to local mu- nicipal water supply. • Seal private wells on an in- dividual basis if requested by owner. • Source and areawide ground water contamination will be addressed by PRPs in subse- quent operable units. Contacts: • Region: Lorna Shull FTS 597-6906 • Headquarters: Lisa Feldt FTS 475-8246 LIMESTONE ROAD REGION III MARYLAND (Approved 9/30/86) Description: • Two adjacent parcels totaling 210 acres were used for the disposal of both clean fill and hazardous wastes. Wastes were put in ravines and in an abandoned limestone quarry. One hundred and ten tons of sludge that contained chromium were disposed of at the site. Organics have also been found at the site. The 18 nearby residences all use ground water as a water sup- ply. The nature of the bedrock in the area creates the poten- tial for the potable ground water to become contarr* nated. Decision: • Cap site; contain soil onsite and fence. ------- • Complete studies including a chemical analysis of shale; continue monitoring surface water and shallow ground water; conduct historical review of geologic literature; reevaluate background con- trol points. Contacts: • Region: Stephany Del Re FTS 597-3161 • Headquarters: Lisa Feldt FTS 475-8246 DISTLER FARM REGION IV KENTUCKY (Approved 8/19/86) Description: • This 3-acre area was dis- covered in 1977 by EPA inves- tigators seeking locations used by a particular individual for chemical waste storage and burial. The site is farm- land and is adjacent to a creek. In 1978, the creek flooded, causing the drums stored on the surface to be strewn across the floodplain. Most of these were recovered, stored onsite, and later removed. The drums con- tained chemicals common to the paint and varnish industry. Four burial sites were identi- fied. No contamination was found in local private wells, although there was visible contamination of soils and a detectable "pool" of contami- nants in the ground water including chromium, lead, common VOCs, and base- neutrals. In February 1984, during the Rl process, an emergency response action was undertaken on the four burial sites. Following the re- moval of 120 drums and 2,620 smaller containers, the site was backfilled, graded, culti- vated, and seeded. Decision: » Excavate remaining contami- nated soil to background levels; backfill; dispose of ex- cavated soil in offsite ap- proved landfill; grade surface and revegetate. • Extract contaminated ground water pool; temporarily store onsite; transport to POTW. In- ject uncontaminated water back into aquifer. Continue process until background levels are reached. Contacts: • Region: Nancy Redgate FTS 257-2643 • Headquarters: Lisa Feldt FTS 475-8246 HIPPS ROAD REGION IV FLORIDA (Approved 9/3/86) Description: • A cypress swamp was filled in with a variety of wastes. The resulting upland area was subdivided and sold as lots. Three different sampl- ing events in 1983 confirmed the existence of a wide vari- ety of VOCs in the underly- ing aquifer, which was used as drinking water. Emer- gency bottled water was pro- vided by the local govern- ment, and city water lines were extended to the af- fected area in the same year. Decision: • Close landfill site in accor- dance with RCRA Subtitle D and Florida Administrative Code. • Relocate residents affected by site closure with the cooperation of FEMA. • Treat contaminated ground water to a 10-® cancer risk level. Use local POTW to treat to meet NPDES permit standards. • Implement institutional con- trols, including fencing the site. Contacts: • Region: Kristina Teepin FTS 257-2643 • Headquarters: Lisa Feldt FTS 475-8246 GENEVA INDUSTRIES REGION VI TEXAS (Approved 9/18/86) Description: • The site is a 13.5-acre aban- doned refinery within a floodplain just outside the city limits of Houston. A vari- ety of organic compounds were produced at the site from 1967 to the present, including biphenyl, PCBs, phenyl phenol, naphtha, and fuel oils. Other solvents and aromatic hydrocarbons were used dur- ing manufacturing. A planned removal removed all offsite soils containing greater than 50 ppm PCBs, and a cap was installed over onsite PCB- contaminated soils. Potable ground water is supplied by two aquifers in the area, one at a 30-foot depth and the other at a 100-foot depth. The aquifer at the 30-foot depth is contaminated with VOCs, as is a small portion of the aquifer at the 100-foot depth. Decision: • Remove and dispose of sur- face structures, excavated soils exceeding 100 ppm PCBs, and excavated drums offsite at an approved RCRA facility. • Construct a multilayered sur- face cap and a slurry wall around perimeter of site; con- nect wall to existing underly- ing clay layer. • Recover ground water con- taminated with greater than 1 ppb TCE from both the aqui- fers; treat with carbon adsorp- tion and discharge into floodplain. Contacts: • Region: Don Williams FTS 729-9742 • Headquarters: Debby Swichkow FTS 382-2453 ------- ODESSA CHROMIUM I and II REGION VI TEXAS (Approved 9/8/86) Description: • The Trinity Aquifer was the only source of potable ground water for a 500-acre area to the north and west of the City of Odessa, an area that in- cludes homes and commer- cial and industrial operations. Two metal plating operations — a radiator and supply busi- ness and a manufacturer of water coolant additives — are the suspected sources of chromium and metals conta- mination in the Trinity Aquifer. Many residents of the af- fected area use bottled water. The subject of two separate focused feasibility studies was the provision of potable water to currently conta- minated wells or those that could be contaminated within 24 months. Decision: • Negotiate agreements with the City of Odessa and con- sumers to extend city water system to affected con- sumers. • Construct an extension to water distribution system. Contacts: • Region: Paul Sieminski FTS 729-2738 • Headquarters: Debby Swichkow FTS 382-2453 SIKES DISPOSAL PITS REGION VI TEXAS (Approved 9/18/86) Description: • Sand pits on the site were used during the 1960s for the disposal of chemical wastes and sludges from area petro- chemical industries. One family lives onsite, and many other people visit areas near the site for recreation. Two underlying aquifers are sources of drinking water. The upper aquifer is contaminated with a wide variety of or- ganics; the lower aquifer is not. The site floods frequen* ly, and portions of it are within the 10- and 50-year floodplains of the San Jacinto River. This is one of the oldest NPL sites. Decision: • Incinerate sludges and conta- minated soils onsite; dispose of residue onsite. • Restrict use of upper aquifer onsite, allowing it to naturally attenuate to 10-5 risk level; monitor lower aquifer. • Discharge contaminated sur- face water to river; treat as necessary to meet state sur- face water criteria and other relevant criteria. Contacts: • Region: Marilyn Plitnik FTS 729-9745 • Headquarters: Debby Swichkow FTS 382-2453 ONSITE INSIGHTS _ SOIL VAPOR EXTRACTION REGION V An innovative technique for re- moving VOCs from soil will be under construction this summer at the Verona Well Field site. The technique, called "soil vapor extraction," uses vacuum wells installed in the unsaturated soil layer (the vadose zone) to re- move volatile contaminants either by capture on activated carbons or through thermal destruction. The site is highly contaminated, and this techni- que was chosen as the best way to minimize airborne con- taminants. The soil vapor extrac- tion system has been used suc- cessfully at several private in- dustry sites. At many Superfund sites, use of this system may necessitate supplemental air emission control. Contacts: • Region: John Tanaka FTS 353-9081 • Headquarters: Randy Kaltreider FTS 382-2448 A LINE ON RODS mm FY '87 RODS A ROD was signed in FY '87 for the Gurley Pit, AR, site, prior to the passage of SARA. This ROD was signed on October 6, 1986. Three RODS were signed in Region VI during the 30-day grandfather period after the new Superfund legislation became law (October 17, 1986): Site/State Date Signed Bayou Sorrel, LA 11/14/86 Hardage/Criner, OK 11/14/86 Mid-South, AR 11/14/86 The ROD for the Ottati and Goss, NH, site in Region I was signed on January 16,1987. This site represents the first ROD signed under SARA. NEW ROD COORDINATOR Debby Swichkow ha^ assumed Betsy Shaw's responsibilities as coordinator of Headquarters ROD activities, including the preparation of the ROD Update. Please contact Debby at FTS 382-2453 if you have any ques- tion or suggestions. ------- |